WorldWideScience

Sample records for polaron band formation

  1. Variational energy band theory for polarons: Mapping polaron structure with the global-local method

    International Nuclear Information System (INIS)

    Brown, D.W.; Lindenberg, K.; Zhao, Y.

    1997-01-01

    In this paper we revisit from a contemporary perspective a classic problem of polaron theory in one dimension using a new variational approach generalizing that of Toyozawa, based on delocalized trial states including mixed gobal and local exciton-phonon correlations. Polaron structure is represented by variational surfaces giving the optimal values of the complete set of exciton and phonon amplitudes for every value of the joint exciton-phonon crystal momentum κ. Characteristic small polaron, large polaron, and nearly free phonon structures are identified, and the manner in which these compete and/or coexist is examined in detail. Through such examination, the parameter space of the problem is mapped, with particular attention given to problematic areas such as the highly quantum mechanical weak-coupling regime, the highly nonlinear intermediate-coupling regime, and to the self-trapping transition that may be said to mark the onset of the strong-coupling regime. Complete energy bands are presented in illustrative cases, and the principal trends in the ground-state energy, polaron bandwidth, and effective mass are identified. The internal structure of our variational Bloch states is examined for qualities that might reflect the typical characteristics of solitons, finding some intriguing qualitative comparisons, but little that bears close scrutiny. copyright 1997 American Institute of Physics

  2. Small-polaron formation and motion in magnetic semiconductors

    International Nuclear Information System (INIS)

    Emin, D.

    1979-01-01

    The fundamental physical processes associated with small-polaron formation are described with various magnetic semi-conductors being cited as examples. Attention is then directed toward the mechanisms of charge transfer and small-polaron hopping motion in magnetic semiconductors

  3. Study of spin-polaron formation in 1D systems

    Energy Technology Data Exchange (ETDEWEB)

    Arredondo, Y.; Navarro, O. [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Apartado Postal 70-360, 04510 México D.F. (Mexico); Vallejo, E. [Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Coahuila, Carretera Torreón-Matamoros Km. 7.5 Ciudad Universitaria, 27276 Torreón, Coahuila (Mexico)

    2014-05-15

    We study numerically the formation of spin-polarons in low-dimensional systems. We consider a ferromagnetic Kondo lattice model with Hund coupling J{sub H} and localized spins interacting antiferromagnetically with coupling constant J. We investigate the ground state phase diagram as a function of the exchange couplings J{sub H} and J and as a function of the band filling, since it has been observed that doping either on the ferromagnetic or antiferromagnetic regime lead to formation of magnetic domains [1]. We explore the quasi-particle formation and phase separation using the density-matrix renormalization group method, which is a highly efficient method to investigate quasi-one-dimensional strongly correlated systems.

  4. Time Domain View of Liquid-like Screening and Large Polaron Formation in Lead Halide Perovskites

    Science.gov (United States)

    Joshi, Prakriti Pradhan; Miyata, Kiyoshi; Trinh, M. Tuan; Zhu, Xiaoyang

    The structural softness and dynamic disorder of lead halide perovskites contributes to their remarkable optoelectronic properties through efficient charge screening and large polaron formation. Here we provide a direct time-domain view of the liquid-like structural dynamics and polaron formation in single crystal CH3NH3PbBr3 and CsPbBr3 using femtosecond optical Kerr effect spectroscopy in conjunction with transient reflectance spectroscopy. We investigate structural dynamics as function of pump energy, which enables us to examine the dynamics in the absence and presence of charge carriers. In the absence of charge carriers, structural dynamics are dominated by over-damped picosecond motions of the inorganic PbBr3- sub-lattice and these motions are strongly coupled to band-gap electronic transitions. Carrier injection from across-gap optical excitation triggers additional 0.26 ps dynamics in CH3NH3PbBr3 that can be attributed to the formation of large polarons. In comparison, large polaron formation is slower in CsPbBr3 with a time constant of 0.6 ps. We discuss how such dynamic screening protects charge carriers in lead halide perovskites. US Department of Energy, Office of Science - Basic Energy Sciences.

  5. Small polaron formation and motion of holes in a-SiO2

    International Nuclear Information System (INIS)

    Hughes, R.C.; Emin, D.

    1978-01-01

    X-ray generated holes in SiO 2 are observed to be reduced to low mobility in times of the order of vibrational periods, 10 -12 s. The temperature dependence, electric field dependence and magnitude of this mobility for times up to about 100 ns are consistent with those of hole-like small polarons. The circumstances which favor the occurrence of rapid small polaron formation are a large effective mass (narrow valence band), the presence of the long-range hole-lattice interaction characteristic of an ionic material and the presence of disorder, all of which are found in amorphous SiO 2 . An alternative explanation involving trapping requires an extremely large localized state density and fortuitous temperature and field dependences of the hopping rates

  6. Effect of defects on the small polaron formation and transport properties of hematite from first-principles calculations.

    Science.gov (United States)

    Smart, Tyler J; Ping, Yuan

    2017-10-04

    Hematite (α-Fe 2 O 3 ) is a promising candidate as a photoanode material for solar-to-fuel conversion due to its favorable band gap for visible light absorption, its stability in an aqueous environment and its relatively low cost in comparison to other prospective materials. However, the small polaron transport nature in α-Fe 2 O 3 results in low carrier mobility and conductivity, significantly lowering its efficiency from the theoretical limit. Experimentally, it has been found that the incorporation of oxygen vacancies and other dopants, such as Sn, into the material appreciably enhances its photo-to-current efficiency. Yet no quantitative explanation has been provided to understand the role of oxygen vacancy or Sn-doping in hematite. We employed density functional theory to probe the small polaron formation in oxygen deficient hematite, N-doped as well as Sn-doped hematite. We computed the charged defect formation energies, the small polaron formation energy and hopping activation energies to understand the effect of defects on carrier concentration and mobility. This work provides us with a fundamental understanding regarding the role of defects on small polaron formation and transport properties in hematite, offering key insights into the design of new dopants to further improve the efficiency of transition metal oxides for solar-to-fuel conversion.

  7. Conformation changes of polysilanes during the polaron formation

    Czech Academy of Sciences Publication Activity Database

    Toman, Petr; Nešpůrek, Stanislav; Jang, J. W.; Lee, C. E.

    2002-01-01

    Roč. 2, č. 4 (2002), s. 327-330 ISSN 1567-1739. [Multilateral Symposium between the Korean Academy of Science and Technology and the Foreign Academies. Seoul, 08.05.2002-10.05.2002] R&D Projects: GA ČR GA203/99/P009; GA AV ČR IAA1050901 Grant - others:GA-(PL) 4T09A 13222 Institutional research plan: CEZ:AV0Z4050913 Keywords : polaron * polysilane * quantum chemical calculation Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.117, year: 2002

  8. Formation time of a small electron polaron in LiNbO3: measurements and interpretation

    International Nuclear Information System (INIS)

    Qiu, Yong; Ucer, K.B.; Williams, R.T.

    2005-01-01

    Infrared optical absorption attributed to the electron polaron on a non-defective site in LiNbO 3 and KNbO 3 has previously been observed using pulsed electron and laser techniques. With subpicosecond laser excitation and spectroscopy, it is possible to measure a rise time of the infrared absorption, which may be interpreted as the time for a band-state conduction electron to cool by phonon scattering, collapse its wavefunction around a site made attractive by thermal disorder, and relax vibrationally to a small polaron. This is a process which is of fundamental interest, involving dynamics of self-localization from band states and vibrational relaxation of a localized electron in an otherwise non-defective lattice. For example, Gavartin and Shluger have recently performed calculations on the role of thermal fluctuations in self-trapping of holes in MgO. We report initial measurements on the rise time of infrared absorption at 0.95 eV (Mg-perturbed polaron) in LiNbO 3 :Mg to be τ R ∼230 fs at T=20 K and τ R ∼110 fs at T=296 K. We discuss 2 stages that together may account for the delay and its temperature dependence: free-electron cooling and vibrational relaxation of a ''defect'' (small polaron) in a host. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  9. Displacement of polarons by vibrational modes in doped conjugated polymers

    NARCIS (Netherlands)

    Anderson, M.; Ramanan, C.; Fontanesi, C.; Frick, A.; Surana, S.; Cheyns, D.; Furno, M.; Keller, T.; Allard, S.; Scherf, U.; Beljonne, D.; D'Avino, G.; von Hauff, E.; Da Como, E.

    2017-01-01

    Organic pi-conjugated polymers are deemed to be soft materials with strong electron-phonon coupling, which results in the formation of polarons, i.e., charge carriers dressed by self-localized distortion of the nuclei. Universal signatures for polarons are optical resonances below the band gap and

  10. Excitations partition into two distinct populations in bulk perovskites due to polaron formation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Lili; Brawand, Nicholas P.; Vörös, Márton; Dahlberg, Peter D.; Otto, John P.; Williams, Nicholas E.; Tiede, David M.; Galli, Giulia; Engel, Gregory S.

    2018-03-05

    Organolead halide perovskites convert optical excitations to charge carriers with remarkable efficiency in optoelectronic devices. Previous research predominantly documents dynamics in perovskite thin films; however, extensive disorder in this platform may obscure the observed carrier dynamics. Here, carrier dynamics in perovskite single-domain single crystals is examined by performing transient absorption spectroscopy in a transmissive geometry. Two distinct sets of carrier populations that coexist at the same radiation fluence, but display different decay dynamics, are observed: one dominated by second-order recombination and the other by third-order recombination. Based on ab initio simulations, this observation is found to be most consistent with the hypothesis that free carriers and localized carriers coexist due to polaron formation. The calculations suggest that polarons will form in both CH3NH3PbBr3 and CH3NH3PbI3 crystals, but that they are more pronounced in CH3NH3PbBr3. Single-crystal CH3NH3PbBr3 could represent the key to understanding the impact of polarons on the transport properties of perovskite optoelectronic devices.

  11. A variational study of the self-trapped magnetic polaron formation in double-exchange model

    International Nuclear Information System (INIS)

    Liu Tao; Feng Mang; Wang Kelin

    2005-01-01

    We study the formation of self-trapped magnetic polaron (STMP) in an antiferro/ferromagnetic double-exchange model semi-analytically by variational solutions. It is shown that the Jahn-Teller effect is not essential to the STMP formation and the STMP forms in the antiferromagnetic material within the region of the order of the lattice constant. We also confirm that no ground state STMP exists in the ferromagnetic background, but the ground state bound MP could appear due to the impurity potential

  12. Multiphonon generation during photodissociation of slow Landau-Pekar polarons

    International Nuclear Information System (INIS)

    Myasnikov, E. N.; Myasnikova, A. E.; Mastropas, Z. P.

    2006-01-01

    The spectra of the low-temperature photodissociation (photoionization) of Landau-Pekar polarons are calculated using the theory of quantum-coherent states and a new method of variation with respect to the parameters of phonon vacuum deformation. It is shown that the final polaron states upon photodissociation may have different numbers of phonons produced in a single dissociation event and different momenta of charge carriers. The spectrum of optical absorption related to the photodissociation of polarons exhibits a superposition of bands corresponding to various numbers of phonons formed as a result of dissociation of a single polaron. Due to a large width of the energy region corresponding to the final states of charge carriers, the halfwidth of each band is on the order of the energy of polaron coupling and is much greater than the phonon energy. For this reason, the individual phonon bands exhibit strong overlap. The very broad and, probably, structureless band formed as a result of the superposition of all these components begins at an energy equal to the sum of the polaron coupling energy (E p ) and the phonon energy. This band has a maximum at a frequency of about 5.6E p /ℎ and a halfwidth on the order of 5.6E p /ℎ at a unit effective mass (m* = m e ) of band electrons. For an effective charge carrier mass within m* = (1-3)m e , the energy of the polaron band maximum can be estimated as 5E p with an error of about 10%, and the halfwidth falls within 3.4E p 1/2 p . The multiphonon character of this band is related to a decay of the phonon condensate after the escape of charge carrier from a polaron. Such polarons are likely to be observed in the spectra of complex metal oxides, including high-temperature superconductors. Examples of such polaron bands in the reported absorption and photoconductivity spectra of nonstoichiometric cuprates, manganites, nickelates, and titanates are presented. A theory of the formation of Landau-Pekar polarons with the

  13. Energy versus wave vector for the conduction band of La-doped SrTiO{sub 3} interpreted by mixed-polaron theory

    Energy Technology Data Exchange (ETDEWEB)

    Eagles, D.M., E-mail: d.eagles@ic.ac.uk

    2015-01-15

    An unusual published energy versus wave vector curve extending to the zone edge determined by ARPES in 5% La-doped SrTiO{sub 3} is interpreted using mixed-polaron theory. After modification of the theory to permit tight-binding bare energy bands and anisotropy, a fit is made to the 24 points nearest to the Fermi energy, adding the constraints (a) that the Fermi volume is approximately equal to that determined from the carrier concentration and (b) that the transport mass from experiments is approximately twice the bare mass. In order to fit the remaining five of 29 observed points we empirically add the effect of a kink. The fit to all points is good. From the parameters of the fit to the 24 points it appears that (a) The energy overlap integral for the narrow band in the heavy direction has the opposite sign to that for the wide band, implying that it is energetically favorable for the nearly-small polaron to be centred in between two sites; and (b) The narrower energy band in the theory may be nearly-small-polaron-like in the heavy direction but large-polaron-like in the other two directions. A simpler energy versus wave vector curve for a 1% La-doped crystal is discussed more briefly.

  14. Spin-polarons and high-Tc superconductivity

    International Nuclear Information System (INIS)

    Wood, R.F.

    1994-03-01

    The spin-polaron concept is introduced in analogy to ionic and electronic polarons and the assumptions underlying the author's approach to spin-polaron mediated high-T c superconductivity are discussed. Elementary considerations about the spin-polaron formation energy are reviewed and the possible origin of the pairing mechanism illustrated schematically. The electronic structure of the CuO 2 planes is treated from the standpoint of antiferromagnetic band calculations that lead directly to the picture of holes predominantly on the oxygen sublattice in a Mott-Hubbard/charge transfer insulator. Assuming the holes to be described in a Bloch representation but with the effective mass renormalized by spin-polaron formation, equations for the superconducting gap, Δ, and transition temperature, T c , are developed and the symmetry of Δ discussed. After further simplifications, T c is calculated as a function of the carrier concentration, x. It is shown that the calculated behavior of T c (x) follows the experimental results closely and leads to a natural explanation of the effects of under- and over-doping. The paper concludes with a few remarks about the evidence for the carriers being fermions (polarons) or bosons (bipolarons)

  15. Angle-resolved photoemission studies of lattice polaron formation in the cuprate Ca2CuO2Cl2

    Energy Technology Data Exchange (ETDEWEB)

    Shen, K.M.

    2010-05-03

    To elucidate the nature of the single-particle excitations in the undoped parent cuprates, we have performed a detailed study of Ca{sub 2}CuO{sub 2}Cl{sub 2} using photoemission spectroscopy. The photoemission lineshapes of the lower Hubbard band are found to be well-described by a polaron model. By comparing the lineshape and temperature dependence of the lower Hubbard band with additional O 2p and Ca 3p states, we conclude that the dominant broadening mechanism arises from the interaction between the photohole and the lattice. The strength of this interaction was observed to be strongly anisotropic and may have important implications for the momentum dependence of the first doped hole states.

  16. Anomalous dispersion and band gap reduction in UO{sub 2+x} and its possible coupling to the coherent polaronic quantum state

    Energy Technology Data Exchange (ETDEWEB)

    Conradson, Steven D. [Synchrotron Soleil, Saint-Aubin BP-48, 91192 (France); Andersson, David A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bagus, Paul S. [University of North Texas, Denton, TX 76203 (United States); Boland, Kevin S.; Bradley, Joseph A.; Byler, Darrin D.; Clark, David L.; Conradson, Dylan R. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Espinosa-Faller, Francisco J. [Universidad Marista de Merida, Merida, Yucatan 97300 (Mexico); Lezama Pacheco, Juan S.; Martucci, Mary B. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Nordlund, Dennis [SLAC National Accelerator Laboratory, Menlo Park, CA 94025 (United States); Seidler, Gerald T. [University of Washington, Seattle, WA 98195 (United States); Valdez, James A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2016-05-01

    Hypervalent UO{sub 2}, UO{sub 2(+x)} formed by both addition of excess O and photoexcitation, exhibits a number of unusual or often unique properties that point to it hosting a polaronic Bose–Einstein(-Mott) condensate. A more thorough analysis of the O X-ray absorption spectra of UO{sub 2}, U{sub 4}O{sub 9}, and U{sub 3}O{sub 7} shows that the anomalous increase in the width of the spectral features assigned to predominantly U 5f and 6d final states that points to increased dispersion of these bands occurs on the low energy side corresponding to the upper edge of the gap bordered by the conduction or upper Hubbard band. The closing of the gap by 1.5 eV is more than twice as much as predicted by calculations, consistent with the dynamical polaron found by structural measurements. In addition to fostering the excitation that is the proposed mechanism for the coherence, the likely mirroring of this effect on the occupied, valence side of the gap below the Fermi level points to increased complexity of the electronic structure that could be associated with the Fermi topology of BEC–BCS crossover and two band superconductivity.

  17. Simulating Precambrian banded iron formation diagenesis

    DEFF Research Database (Denmark)

    Posth, Nicole R.; K??hler, Inga; D. Swanner, Elizabeth

    2013-01-01

    Post-depositional diagenetic alteration makes the accurate interpretation of key precipitation processes in ancient sediments, such as Precambrian banded iron formations (BIFs), difficult. While microorganisms are proposed as key contributors to BIF deposition, the diagenetic transformation...

  18. Microbiological processes in banded iron formation deposition

    DEFF Research Database (Denmark)

    Posth, Nicole R.; Konhauser, Kurt O.; Kappler, Andreas

    2013-01-01

    Banded iron formations have been studied for decades, particularly regarding their potential as archives of the Precambrian environment. In spite of this effort, the mechanism of their deposition and, specifically, the role that microbes played in the precipitation of banded iron formation minerals......, remains unresolved. Evidence of an anoxic Earth with only localized oxic areas until the Great Oxidation Event ca 2·45 to 2·32 Ga makes the investigation of O2-independent mechanisms for banded iron formation deposition relevant. Recent studies have explored the long-standing proposition that Archean...... banded iron formations may have been formed, and diagenetically modified, by anaerobic microbial metabolisms. These efforts encompass a wide array of approaches including isotope, ecophysiological and phylogeny studies, molecular and mineral marker analysis, and sedimentological reconstructions. Herein...

  19. Measurement of the resonant polaron effect in the Reststrahlen band of GaAs:Si using far-infrared two-photon excitation

    International Nuclear Information System (INIS)

    Wenckebach, W.Th.; Planken, P.C.M.; Son, P.C. van

    1995-01-01

    We present the results of photoconductivity measurements of the resonant electron-phonon interaction in the middle of the Reststrahlen band using two-photon excitation with intense picosecond pulses with frequency around 143 cm -1 (70 μm). We use two photons rather than a single photon for the excitation of the resonant-polaron to avoid the problems of strong reflection and dielectric artifacts encountered in direct single-photon excitation in the Reststrahlen band. The sample is a 10 μm thick Si-doped GaAs epitaxial layer on a 400 μm semi-insulating GaAs substrate. The electronic levels of the Si shallow donor can be tuned by the application of a magnetic field. Intense tunable picosecond pulses with a frequency of around 143 cm -1 from the Dutch free-electron laser FELIX are weakly focussed onto the sample, which is kept at 8 K. Electrons excited to the 3d +2 state via the electric-dipole allowed two-photon transition out of the 1s 0- ground state, decay to the conduction band and give rise to an increase in the photoconductivity. The figure shows the energy-peak position of the 3d +2 transition thus obtained as a function of the magnetic-field strength. The figure clearly shows the avoided crossing around the LO-phonon energy where the coupling shows the avoided crossing around the LO-phonon energy where the coupling between the 3d +2 state and the LO phonon is strongest. Note that the data between 267 cm -1 and 296 cm -1 are extremely difficult to obtain with single-photon excitation because of their position in the middle of the Reststrahlen band

  20. Large polarons in lead halide perovskites

    OpenAIRE

    Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan; Joshi, Prakriti P.; Mosconi, Edoardo; Jones, Skyler C.; De Angelis, Filippo; Zhu, X.-Y.

    2017-01-01

    Lead halide perovskites show marked defect tolerance responsible for their excellent optoelectronic properties. These properties might be explained by the formation of large polarons, but how they are formed and whether organic cations are essential remain open questions. We provide a direct time domain view of large polaron formation in single-crystal lead bromide perovskites CH3NH3PbBr3 and CsPbBr3. We found that large polaron forms predominantly from the deformation of the PbBr3 ? framewor...

  1. Spin-polaron theory of high-Tc superconductivity: I, spin polarons and high-Tc pairing

    International Nuclear Information System (INIS)

    Wood, R.F.

    1993-06-01

    The concept of a spin polaron is introduced and contrasted with the more familiar ionic polaron picture. A brief review of aspects of ionic bipolaronic superconductivity is given with particular emphasis on the real-space pairing and true Bose condensation characteristics. The formation energy of spin polarons is then calculated in analogy with ionic polarons. The spin-flip energy of a Cu spin in an antiferromagnetically aligned CuO 2 plane is discussed. It is shown that the introduction of holes into the CuO 2 planes will always lead to the destruction of long-range AF ordering due to the formation of spin polarons. The pairing of two spin polarons can be expected because of the reestablishment of local (short-range) AF ordering; the magnitude of the pairing energy is estimated using a simplified model. The paper closes with a brief discussion of the formal theory of spin polarons

  2. Polarons in advanced materials

    CERN Document Server

    Alexandrov, Alexandre Sergeevich

    2008-01-01

    Polarons in Advanced Materials will lead the reader from single-polaron problems to multi-polaron systems and finally to a description of many interesting phenomena in high-temperature superconductors, ferromagnetic oxides, conducting polymers and molecular nanowires. The book divides naturally into four parts. Part I introduces a single polaron and describes recent achievements in analytical and numerical studies of polaron properties in different electron-phonon models. Part II and Part III describe multi-polaron physics, and Part IV describes many key physical properties of high-temperature superconductors, colossal magnetoresistance oxides, conducting polymers and molecular nanowires, which were understood with polarons and bipolarons. The book is written in the form of self-consistent reviews authored by well-established researchers actively working in the field and will benefit scientists and postgraduate students with a background in condensed matter physics and materials sciences.

  3. Chemostratigraphy of Neoproterozoic Banded Iron Formation (BIF)

    DEFF Research Database (Denmark)

    Gaucher, Claudio; Sial, Alcides N.; Frei, Robert

    2015-01-01

    Neoproterozoic banded iron formations (BIFs) are not restricted to the middle Cryogenian, c. 715 Ma glaciation, occurring in Tonian, Cryogenian, and Ediacaran successions. Many Neoproterozoic BIFs were deposited in glacially influenced settings, such as the Rapitan Group (Canada), Jacadigo Group (W...... for the study of BIFs include rare earth element distribution, especially Eu and Ce normalized concentrations, iron speciation, and Nd and Cr isotopes (δ53Cr). Whereas Rapitan type BIFs exhibit no Eu or Ce anomalies, the Algoma-type Neoproterozoic BIFs show both. Positive δ53Cr values characterize glacially...

  4. Large polarons in lead halide perovskites

    Science.gov (United States)

    Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan; Joshi, Prakriti P.; Mosconi, Edoardo; Jones, Skyler C.; De Angelis, Filippo; Zhu, X.-Y.

    2017-01-01

    Lead halide perovskites show marked defect tolerance responsible for their excellent optoelectronic properties. These properties might be explained by the formation of large polarons, but how they are formed and whether organic cations are essential remain open questions. We provide a direct time domain view of large polaron formation in single-crystal lead bromide perovskites CH3NH3PbBr3 and CsPbBr3. We found that large polaron forms predominantly from the deformation of the PbBr3− frameworks, irrespective of the cation type. The difference lies in the polaron formation time, which, in CH3NH3PbBr3 (0.3 ps), is less than half of that in CsPbBr3 (0.7 ps). First-principles calculations confirm large polaron formation, identify the Pb-Br-Pb deformation modes as responsible, and explain quantitatively the rate difference between CH3NH3PbBr3 and CsPbBr3. The findings reveal the general advantage of the soft [PbX3]− sublattice in charge carrier protection and suggest that there is likely no mechanistic limitations in using all-inorganic or mixed-cation lead halide perovskites to overcome instability problems and to tune the balance between charge carrier protection and mobility. PMID:28819647

  5. Effects of interaction and disorder on polarons in colossal resistance manganite Pr0.68Ca0.32MnO3 thin films

    Science.gov (United States)

    Hoffmann, J.; Moschkau, P.; Mildner, S.; Norpoth, J.; Jooss, Ch; Wu, L.; Zhu, Y.

    2014-12-01

    The colossal magnetoresistance effect (CMR), the drop of the electric resistance by orders of magnitude in a strong magnetic field, is a fascinating property of strongly correlated electrons in doped manganites. Here, we present a detailed analysis of the magnetotransport properties of small polarons in thin films of the low bandwidth manganite Pr0.68Ca0.32MnO3 with different degrees of preparation-induced octahedral disorder. The crystal and defect structure is investigated by means of high-resolution transmission electron microscopy. We apply the small polaron theory developed by Firsov and Lang in order to study the hopping mobility in the paramagnetic phase and its changes due to the formation of the antiferromagnetic charge ordered (CO) and the ferromagnetic metallic phases. Although it represents a single particle theory, reasonable estimates of small polaron properties such as formation energy, activation energy and transfer integral are possible, if the effects of interactions and disorder are taken into account. Beyond the well-known effect of the magnetic double exchange on the transfer integral, we show that the emergence of band transport of small polarons in the CMR transition sensibly depends on the degree of octahedral disorder, the polaron-polaron interactions and the resulting long range order leading to a structural phase transition in the CO phase.

  6. Holstein polarons and triplet bipolarons with NNN hopping

    Science.gov (United States)

    Chakraborty, Monodeep; Taraphder, A.; Berciu, Mona

    2017-05-01

    We study the ground state of 1D Holstein single polaron with next nearest neighbour electron hopping (NNN), employing a variational approximation based on exact diagonalization. Our investigation reveals that, depending upon the sign and magnitude of the NNN hopping integral with respect to nearest neighbour hopping, the polaron band minima may occur at non-zero kGS. We compare the present scenario with the SSH polarons, where a similar feature is also observed, albeit, due to very different mechanism. Our initial investigation of triplet bipolarons, in presence of an attractive extended Hubbard interactions, further substantiates the differences between the present model and the SSH model.

  7. Small polarons in 2D perovskites

    KAUST Repository

    Cortecchia, Daniele

    2017-11-02

    We demonstrate that white light luminescence in two-dimensional (2D) perovskites stems from photoinduced formation of small polarons confined at specific sites of the inorganic framework in the form of self-trapped electrons and holes. We discuss their application in white light emitting devices and X-ray scintillators.

  8. Geochemistry of some banded iron-formations of the archean ...

    Indian Academy of Sciences (India)

    Banded iron-formations (BIF) form an important part of the Archean supracrustal belts of the. Jharkhand–Orissa region, India. Major, trace and REE chemistry of the banded iron-formation of the Gandhamardan, Deo Nala, Gorumahisani and Noamundi sections of the Jharkhand–Orissa region are utilized to explore the ...

  9. Geochemistry of some banded iron-formations of the archean ...

    Indian Academy of Sciences (India)

    Banded iron-formations (BIF) form an important part of the Archean supracrustal belts of the Jharkhand–Orissa region, India. Major, trace and REE chemistry of the banded iron-formation of the Gandhamardan, Deo Nala, Gorumahisani and Noamundi sections of the Jharkhand–Orissa region are utilized to explore the ...

  10. Formation of Degenerate Band Gaps in Layered Systems

    Directory of Open Access Journals (Sweden)

    Alexey P. Vinogradov

    2012-06-01

    Full Text Available In the review, peculiarities of spectra of one-dimensional photonic crystals made of anisotropic and/or magnetooptic materials are considered. The attention is focused on band gaps of a special type—the so called degenerate band gaps which are degenerate with respect to polarization. Mechanisms of formation and properties of these band gaps are analyzed. Peculiarities of spectra of photonic crystals that arise due to the linkage between band gaps are discussed. Particularly, it is shown that formation of a frozen mode is caused by linkage between Brillouin and degenerate band gaps. Also, existence of the optical Borrmann effect at the boundaries of degenerate band gaps and optical Tamm states at the frequencies of degenerate band gaps are analyzed.

  11. Polaronic transport in polysilanes

    Czech Academy of Sciences Publication Activity Database

    Nešpůrek, Stanislav; Nožár, Juraj; Kadashchuk, A.; Fishchuk, I. I.

    2009-01-01

    Roč. 193, č. 1 (2009), s. 1-4 ISSN 1742-6588. [International Conference on Electron Dynamics in Semiconductors, Optoelectronics and Nanostructures /16./. Montpellier, 24.08.2009-28.08.2009] R&D Projects: GA AV ČR IAA100100622; GA AV ČR KAN400720701 Institutional research plan: CEZ:AV0Z40500505 Keywords : polaronic transport * polysilanes * charge carrier mobility Subject RIV: CD - Macromolecular Chemistry

  12. Watching the coherent birth of polaron pairs in conjugated polymers

    OpenAIRE

    De Sio, Antonietta; Troiani, Filippo; Maiuri, Margherita; Réhault, Julien; Sommer, Ephraim; Lim, James; Huelga, Susana F.; Plenio, Martin B.; Rozzi, Carlo Andrea; Cerullo, Giulio; Molinari, Elisa; Lienau, Christoph

    2016-01-01

    Organic semiconductors have the remarkable property that their optical excitation not only generates charge-neutral electron-hole pairs (excitons) but also charge-separated polaron pairs with high yield. The microscopic mechanisms underlying this charge separation have been debated for many years. Here we use ultrafast two-dimensional electronic spectroscopy to study the dynamics of polaron pair formation in a prototypical polymer thin film on a sub-20-fs time scale. We observe multi-period p...

  13. Diagrams in the polaron model

    International Nuclear Information System (INIS)

    Smondyrev, M.A.

    1985-01-01

    The perturbation theory for the polaron energy is systematically treated on the diagrammatic basis. Feynman diagrams being constructed allow to calculate the polaron energy up to the third order in powers of the coupling constant. Similar calculations are performed for the average number of virtual phonons

  14. Magnon-polaron transport in magnetic insulators

    Science.gov (United States)

    Flebus, Benedetta; Shen, Ka; Kikkawa, Takashi; Uchida, Ken-ichi; Qiu, Zhiyong; Saitoh, Eiji; Duine, Rembert A.; Bauer, Gerrit E. W.

    2017-04-01

    We theoretically study the effects of strong magnetoelastic coupling on the transport properties of magnetic insulators. We develop a Boltzmann transport theory for the mixed magnon-phonon modes ("magnon polarons") and determine transport coefficients and the spin diffusion length. Magnon-polaron formation causes anomalous features in the magnetic field and temperature dependence of the spin Seebeck effect when the disorder scattering in the magnetic and elastic subsystems is sufficiently different. Experimental data by Kikkawa et al. [Phys. Rev. Lett. 117, 207203 (2016), 10.1103/PhysRevLett.117.207203] on yttrium iron garnet films can be explained by an acoustic quality that is much better than the magnetic quality of the material. We predict similar anomalous features in the spin and heat conductivity and nonlocal spin transport experiments.

  15. Strong impact of impurity bands on domain formation in superlattices

    DEFF Research Database (Denmark)

    Wacker, Andreas; Jauho, Antti-Pekka

    1998-01-01

    The formation of electric field domains in doped semiconductor superlattices is described within a microscopic model. Due to the presence of impurity bands in low-doped samples the current-voltage characteristic is essentially different compared to medium-doped samples. (C) 1998 Published by Else...... by Elsevier Science B.V. All rights reserved.......The formation of electric field domains in doped semiconductor superlattices is described within a microscopic model. Due to the presence of impurity bands in low-doped samples the current-voltage characteristic is essentially different compared to medium-doped samples. (C) 1998 Published...

  16. Experimental study of shear bands formation in a granular material

    Directory of Open Access Journals (Sweden)

    Nguyen Thai Binh

    2017-01-01

    Full Text Available We present an experimental investigation of the formation of shear bands in a granular sample submitted to a biaxial test. Our principal result is the direct observation of the bifurcation at the origin of the localization process in the material. At the bifurcation, the shear band is spatially extended: we observe a breaking of symmetry without any sudden localization of the deformation in a narrow band. Our work thus allows to clearly distinguish different phenomena: bifurcation which is a ponctual event which occurs before the peak, localization which is a process that covers a range of deformation of several percents during which the peak occurs and finally stationary shear bands which are well-defined permanent structures that can be observed at the end of the localization process, after the peak.

  17. Mineralogy and geochemistry of banded iron formation and iron ...

    Indian Academy of Sciences (India)

    The geological complexities of banded iron formation (BIF) and associated iron ores of Jilling–. Langalata iron ore deposits, Singhbhum–North Orissa Craton, belonging to Iron Ore Group (IOG) eastern India have been studied in detail along with the geochemical evaluation of different iron ores. The geochemical and ...

  18. Mineralogy and geochemistry of banded iron formation and iron ...

    Indian Academy of Sciences (India)

    The geological complexities of banded iron formation (BIF) and associated iron ores of Jilling–Langalata iron ore deposits, Singhbhum–North Orissa Craton, belonging to Iron Ore Group (IOG) eastern India have been studied in detail along with the geochemical evaluation of different iron ores. The geochemical and ...

  19. The geochemistry of banded iron formations in the sukumaland ...

    African Journals Online (AJOL)

    The geochemistry of banded iron formations in the sukumaland greenstone belt of Geita, northern Tanzania: evidence for mixing of hydrothermal and clastic ... the hydrothermal deposits have been contaminated, by up to 20% by weight, with detrital material having a composition similar to modern deep-sea pelagic clays.

  20. O{sup -} bound small polarons in oxide materials

    Energy Technology Data Exchange (ETDEWEB)

    Schirmer, O F [Department of Physics, University of Osnabrueck, D-49076 Osnabrueck (Germany)

    2006-11-01

    Holes bound to acceptor defects in oxide crystals are often localized by lattice distortion at just one of the equivalent oxygen ligands of the defect. Such holes thus form small polarons in symmetric clusters of a few oxygen ions. An overview on mainly the optical manifestations of those clusters is given. The article is essentially divided into two parts: the first one covers the basic features of the phenomena and their explanations, exemplified by several paradigmatic defects; in the second part numerous oxide materials are presented which exhibit bound small polaron optical properties. The first part starts with summaries on the production of bound hole polarons and the identification of their structure. It is demonstrated why they show strong, wide absorption bands, usually visible, based on polaron stabilization energies of typically 1 eV. The basic absorption process is detailed with a fictitious two-well system. Clusters with four, six and twelve equivalent ions are realized in various oxide compounds. In these cases several degenerate optically excited polaron states occur, leading to characteristic final state resonance splittings. The peak energies of the absorption bands as well as the sign of the transfer energy depend on the topology of the clusters. A special section is devoted to the distinction between interpolaron and intrapolaron optical transitions. The latter are usually comparatively weak. The oxide compounds exhibiting bound hole small polaron absorptions include the alkaline earth oxides (e.g. MgO), BeO and ZnO, the perovskites BaTiO{sub 3} and KTaO{sub 3}, quartz, the sillenites (e.g. Bi{sub 12}TiO{sub 20}), Al{sub 2}O{sub 3}, LiNbO{sub 3}, topaz and various other materials. There are indications that the magnetic crystals NiO, doped with Li, and LaMnO{sub 3}, doped with Sr, also show optical features caused by bound hole polarons. Beyond being elementary paradigms for the properties of small polarons in general, the defect species treated

  1. Involvement of membrane potential in alkaline band formation by internodal cells of Chara corallina.

    Science.gov (United States)

    Shimmen, Teruo; Wakabayashi, Akiko

    2008-10-01

    Internodal cells of Chara corallina form alkaline bands on their surface upon illumination via photosynthesis. In the present study, the effect of KCl on alkaline band formation was analyzed. When the extracellular KCl concentration was increased, alkaline band formation was extensively inhibited. Electrophysiological analysis unequivocally showed the need for inner negative membrane potential for alkaline band formation.

  2. Analyzing Shear Band Formation with High Resolution X-ray

    Energy Technology Data Exchange (ETDEWEB)

    Pagan, Darren C.; Obstalecki, Mark; Park, Jun-Sang; Miller, Matthew P.

    2018-04-01

    Localization of crystallographic slip into shear bands during uniaxial compression of a copper single crystal is studied using very far-field high-energy diffraction microscopy (vff-HEDM). Diffracted intensity was collected in-situ as the crystal deformed using a unique mobile detector stage that provided access to multiple diffraction peaks with high-angular resolution. From the diffraction data, single crystal orientation pole figures (SCPFs) were generated and are used to track the evolution of the distribution of lattice orientation that develops as slip localizes. To aid the identification of 'signatures' of shear band formation and analyze the SCPF data, a model of slip-driven lattice reorientation within shear bands is introduced. Confidence is built in conclusions drawn from the SCPF data about the character of internal slip localization through comparisons with strain fields on the sample surface measured simultaneously using digital image correlation. From the diffraction data, we find that the active slip direction and slip plane are not directly aligned with the orientation of the shear bands that formed. In fact, by extracting the underlying slip system activity from the SCPF data, we show that intersecting shear bands measured on the surface of the sample arise from slip primarily on the same underlying single slip system. These new vff-HEDM results raise significant questions on the use of surface measurements for slip system activity estimation. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  3. Density functional theory + U modeling of polarons in organohalide lead perovskites

    Directory of Open Access Journals (Sweden)

    Eric Welch

    2016-12-01

    Full Text Available We investigate the possible formation of polarons in four organic perovskites (CH3NH3PbI3, CH3NH3PbBr3, CH3NH3PbCl3, and CH3NH3PbI2Cl1 using a density functional theory (DFT calculations with local potentials and hybrid functionals. We show that DFT+U method with U = 8 eV predicts a correct band-gap and matches the forces on ions from hybrid calculations. We then use the DFT + U approach to study the effect of polarons, i.e. to search the configuration space and locate the lowest energy localized band gap state self-trapped hole (STH. STH configurations were found for three pure halides and one mixed halide system. Spin orbit coupling (SOC was also taken into account and the results may be found in the supplementary material. This study focuses on the +U method; however, SOC corrections added to the DFT+U calculations also resulted in STH states in all four systems.

  4. Many-body interferometry of magnetic polaron dynamics

    Science.gov (United States)

    Ashida, Yuto; Schmidt, Richard; Tarruell, Leticia; Demler, Eugene

    2018-02-01

    The physics of quantum impurities coupled to a many-body environment is among the most important paradigms of condensed-matter physics. In particular, the formation of polarons, quasiparticles dressed by the polarization cloud, is key to the understanding of transport, optical response, and induced interactions in a variety of materials. Despite recent remarkable developments in ultracold atoms and solid-state materials, the direct measurement of their ultimate building block, the polaron cloud, has remained a fundamental challenge. We propose and analyze a platform to probe time-resolved dynamics of polaron-cloud formation with an interferometric protocol. We consider an impurity atom immersed in a two-component Bose-Einstein condensate where the impurity generates spin-wave excitations that can be directly measured by the Ramsey interference of surrounding atoms. The dressing by spin waves leads to the formation of magnetic polarons and reveals a unique interplay between few- and many-body physics that is signified by single- and multi-frequency oscillatory dynamics corresponding to the formation of many-body bound states. Finally, we discuss concrete experimental implementations in ultracold atoms.

  5. Effect of interchain coupling on the excited polaron in conjugated polymers

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xiao-xue, E-mail: sps_lixx@ujn.edu.cn; Chen, Gang, E-mail: ss_cheng@ujn.edu.cn

    2017-02-05

    Based on the one-dimensional extended Su–Schrieffer–Heeger model, we theoretically investigate the effect of interchain coupling on the formation and polarization of the single-excited state of polaron in conjugated polymers. It is found that there exists a turnover value of the coupling strength, over which the excited polaron could not be formed in either of the two coupled chains. Instead, a polaron-like particle is localized at the center of each chain. In addition, we also find that the reverse polarization of the excited polaron could be enhanced for some cases in polymer when the interchain coupling becomes strong until it exceeds the critical value. - Highlights: • Effect of interchain coupling on the single-excited state of polaron is studied. • When coupling strength exceeds critical value, the excited polaron is dissociated. • Soliton pair could be dissociated into polaron-like particle with strong coupling. • Reverse polarization of excited polaron is enhanced by weak interchain coupling. • Reverse polarization is obtained more easily in solid film of polymer molecules.

  6. Observations of the initial stages of colloidal band formation

    Science.gov (United States)

    Li, Yanrong; Tagawa, Yoshiyuki; Yee, Andrew; Yoda, Minami

    2017-11-01

    A number of studies have shown that particles suspended in a conducting fluid near a wall are subject to wall-normal repulsive ``lift'' forces, even in the absence of interparticle interactions, in a flowing suspension. Evanescent-wave visualizations have shown that colloidal particles in a dilute (volume fractions channels by a pressure gradient and an electric field when the resulting combined Poiseuille and electroosmotic (EO) flow are in opposite direction, i.e., ``counterflow,'' although the particles and channel walls both have negative zeta-potentials. Above a minimum ``threshold'' electric field magnitude |Emin | , the particles assemble into dense ``bands'' with cross-sectional dimensions of a few μm and length comparable to that of the channel (i.e., a few cm). The results suggest that the threshold field |Emin | is large enough so that there is a region of ``reverse'' flow, along the direction of the EO flow, near the wall. Visualization of a large segment of the channel (>300 hydraulic diameters) at frame rates as great as 1 kHz is used to determine banding maps for a variety of dilute colloidal suspensions and to investigate the initial stages of band formation over a wide range of flow conditions. Supported by US Army Research Office.

  7. Observation of Spin-Polarons in a strongly interacting Fermi liquid

    Science.gov (United States)

    Zwierlein, Martin

    2009-03-01

    We have observed spin-polarons in a highly imbalanced mixture of fermionic atoms using tomographic RF spectroscopy. Feshbach resonances allow to freely tune the interactions between the two spin states involved. A single spin down atom immersed in a Fermi sea of spin up atoms can do one of two things: For strong attraction, it can form a molecule with exactly one spin up partner, but for weaker interaction it will spread its attraction and surround itself with a collection of majority atoms. This spin down atom ``dressed'' with a spin up cloud constitutes the spin-polaron. We have observed a striking spectroscopic signature of this quasi-particle for various interaction strengths, a narrow peak in the spin down spectrum that emerges above a broad background. The narrow width signals a long lifetime of the spin-polaron, much longer than the collision rate with spin up atoms, as it must be for a proper quasi-particle. The peak position allows to directly measure the polaron energy. The broad pedestal at high energies reveals physics at short distances and is thus ``molecule-like'': It is exactly matched by the spin up spectra. The comparison with the area under the polaron peak allows to directly obtain the quasi-particle weight Z. We observe a smooth transition from polarons to molecules. At a critical interaction strength of 1/kFa = 0.7, the polaron peak vanishes and spin up and spin down spectra exactly match, signalling the formation of molecules. This is the same critical interaction strength found earlier to separate a normal Fermi mixture from a superfluid molecular Bose-Einstein condensate. The spin-polarons determine the low-temperature phase diagram of imbalanced Fermi mixtures. In principle, polarons can interact with each other and should, at low enough temperatures, form a superfluid of p-wave pairs. We will present a first indication for interactions between polarons.

  8. Dynamics of photogenerated polarons and polaron pairs in P3HT thin films

    Science.gov (United States)

    Menšík, M.; Pfleger, J.; Toman, P.

    2017-06-01

    On the basis of the analysis of the experimental data of the transient absorption spectroscopy of thin films of regioregular poly(3-hexyl thiophene) we suggest a mechanism of the polaron pairs decay based on the coherent up and down conversion cycling between hot polaron pairs and free polarons. Compared to previously adopted models, based on single molecular processes or bimolecular collisions, the suggested model reproduced well both the polaron pairs and polaron population kinetics at short time after photoexcitation. For longer times, when the polaron pairs are already thermalized, they decay via 1-D diffusion limited bi-molecular collision processes.

  9. Excitonic and Polaronic Properties of 2D Hybrid Organic–Inorganic Perovskites

    KAUST Repository

    Yin, Jun

    2017-01-20

    We theoretically characterize the unusual white-light emission properties of two-dimensional (2D) hybrid organic inorganic perovskites with an APbX(4) structure (where A is a bidentate organic cation and X = Cl, Br). In addition to band structure calculations including corrections due to spin orbit couplings and electron hole interactions, a computationally intensive molecular cluster approach is exploited to describe the excitonic and polaronic properties of these 2D perovskites at the atomistic level. Upon adding or removing an electron from the neutral systems, we find that strongly localized small polarons form in the 2D clusters. The polaron charge density is distributed over just lattice sites, which is consistent with the calculated large polaron binding energies, on the order of similar to 0.4-1.2 eV.

  10. Structural mechanisms of formation of adiabatic shear bands

    Directory of Open Access Journals (Sweden)

    Mikhail Sokovikov

    2016-10-01

    Full Text Available The paper focuses on the experimental and theoretical study of plastic deformation instability and localization in materials subjected to dynamic loading and high-velocity perforation. We investigate the behavior of samples dynamically loaded during Hopkinson-Kolsky pressure bar tests in a regime close to simple shear conditions. Experiments were carried out using samples of a special shape and appropriate test rigging, which allowed us to realize a plane strain state. Also, the shear-compression specimens proposed in were investigated. The lateral surface of the samples was investigated in a real-time mode with the aid of a high-speed infra-red camera CEDIP Silver 450M. The temperature field distribution obtained at different time made it possible to trace the evolution of plastic strain localization. Use of a transmission electron microscope for studying the surface of samples showed that in the regions of strain localization there are parts taking the shape of bands and honeycomb structure in the deformed layer. The process of target perforation involving plug formation and ejection was investigated using a high-speed infra-red camera. A specially designed ballistic set-up for studying perforation was used to test samples in different impulse loading regimes followed by plastic flow instability and plug ejection. Changes in the velocity of the rear surface at different time of plug ejection were analyzed by Doppler interferometry techniques. The microstructure of tested samples was analyzed using an optical interferometer-profilometer and a scanning electron microscope. The subsequent processing of 3D deformation relief data enabled estimation of the distribution of plastic strain gradients at different time of plug formation and ejection. It has been found that in strain localization areas the subgrains are elongated taking the shape of bands and undergo fragmentation leading to the formation of super-microcrystalline structure, in which the

  11. Fossilized iron bacteria reveal a pathway to the biological origin of banded iron formation.

    Science.gov (United States)

    Chi Fru, Ernest; Ivarsson, Magnus; Kilias, Stephanos P; Bengtson, Stefan; Belivanova, Veneta; Marone, Federica; Fortin, Danielle; Broman, Curt; Stampanoni, Marco

    2013-01-01

    Debates on the formation of banded iron formations in ancient ferruginous oceans are dominated by a dichotomy between abiotic and biotic iron cycling. This is fuelled by difficulties in unravelling the exact processes involved in their formation. Here we provide fossil environmental evidence for anoxygenic photoferrotrophic deposition of analogue banded iron rocks in shallow marine waters associated with an Early Quaternary hydrothermal vent field on Milos Island, Greece. Trace metal, major and rare earth elemental compositions suggest that the deposited rocks closely resemble banded iron formations of Precambrian origin. Well-preserved microbial fossils in combination with chemical data imply that band formation was linked to periodic massive encrustation of anoxygenic phototrophic biofilms by iron oxyhydroxide alternating with abiotic silica precipitation. The data implicate cyclic anoxygenic photoferrotrophy and their fossilization mechanisms in the construction of microskeletal fabrics that result in the formation of characteristic banded iron formation bands of varying silica and iron oxide ratios.

  12. Optical Detection of Polarons in High - Tc Cuprate

    International Nuclear Information System (INIS)

    Calvani, P.; Capizzi, M.; Lupi, S.; Maselli, P.; Paolone, A.; Roy LURE, P.; Berger, H.

    1995-01-01

    The optical conductivity σ (ω) of slightly e-doped single-crystals of (Nd,Gd) 2 CuO 4-y shows local modes in the far-infrared as well as a broad infrared absorption centered at ∼ 0.1 eV (d-band). This latter shows a fine structure, in agreement with recent calculations of Alexandrov et al., which is made up by intense overtones of the local modes observed in the far-infrared. Similar polaronic structures are shown to exist in the normal metallic phase of Nd 2-x Ce x CuO 4-y and even in the σ (ω ) of YBCO crystals, measured by different authors. The present observations provide evidence for the existence of small polarons in all materials with a Cu-O plane

  13. Experimental neutron scattering evidence for proton polaron in hydrated metal oxide proton conductors

    Science.gov (United States)

    Braun, Artur; Chen, Qianli

    2017-06-01

    Hydration of oxygen-deficient metal oxides causes filling of oxygen vacancies and formation of hydroxyl groups with interstitial structural protons, rotating around the oxygen in localized motion. Thermal activation from 500 to 800 K triggers delocalization of the protons by jumping to adjacent oxygen ions, constituting proton conductivity. We report quantitative analyses of proton and lattice dynamics by neutron-scattering data, which reveal the interaction of protons with the crystal lattice and proton-phonon coupling. The motion for the proton trapped in the elastic crystal field yields Eigen frequencies and coupling constants, which satisfy Holstein's polaron model for electrons and thus constitutes first experimental evidence for a proton polaron at high temperature. Proton jump rates follow a polaron model for cerium-oxygen and hydroxyl stretching modes, which are thus vehicles for proton conductivity. This confirms that the polaron mechanism is not restricted to electrons, but a universal charge carrier transport process.

  14. Electron localization, polarons and clustered states in manganites

    International Nuclear Information System (INIS)

    Mannella, N.

    2004-01-01

    Full text: A recent multi-spectroscopic study of prototypical colossal magnetoresistance (CMR) compounds La 1-x Sr x MnO 3 (LSMO, x = 0.3, 0.4) using photoemission (PE), x-ray absorption (XAS), x-ray emission (XES) and extended x-ray absorption e structure (EXAFS) has exposed a dramatic change in the electronic structure on crossing the ferromagnetic-to-paramagnetic transition temperature (T C ). In particular, this investigation revealed an increase of the Mn magnetic moment by ca. 1 Bohr magneton and charge transfer to the Mn atom on crossing T C concomitant with the presence of Jahn-Teller distortions, thus providing direct evidence of lattice polaron formation. These results thus challenge the belief of some authors that the LSMO compounds are canonical double-exchange (DE) systems in which polaron formation is unimportant, and thus help to unify the theoretical description of the CMR oxides. The relationship of these data to other recent work suggesting electron localization, polarons and phase separation, along with additional measurements of magnetic susceptibility indicating the formation of ferromagnetic clusters in the metallic paramagnetic state above T C will be discussed

  15. f-f Magnetic polaron Wigner glass and anomalous superconductivity in U sub 1 sub - sub x Th sub x Be sub 1 sub 3

    CERN Document Server

    Kasuya, T

    2000-01-01

    Mechanisms of the anomalous properties in the heavy fermion superconductor UBe sub 1 sub 3 and its alloys, in particular for the Th dopings, are studied in detail based on the fundamental electronic states to be consistent with all the crucial experimental results. As the reference systems for the magnetic polaron formation, Ce monopnictides, as well as USb and UTe, are mentioned. From detailed systematic studies of the dilute alloy systems, it is postulated that the 5f states in UBe sub 1 sub 3 split into the well-localized core 5f GAMMA sup 2 sub 7 singlet state and other delocalized 5f states situated around the Fermi energy forming the f-f magnetic polarons through the strong intra-atomic ferromagnetic f-f exchange interaction. The accompanied lattice polarons are also shown to play important roles. In the p-d band states, the f-f exchange interaction and the intersite p-f mixing interactions for the p-f Kondo state are of nearly equal strengths causing a rich variety of delicately balanced states. For th...

  16. A Novel Approach for Controlling the Band Formation in Medium Mn Steels

    Science.gov (United States)

    Farahani, H.; Xu, W.; van der Zwaag, S.

    2018-03-01

    Formation of the microstructural ferrite/pearlite bands in medium Mn steels is an undesirable phenomenon commonly addressed through fast cooling treatments. In this study, a novel approach using the cyclic partial phase transformation concept is applied successfully to prevent microstructural band formation in a micro-chemically banded Fe-C-Mn-Si steel. The effectiveness of the new approach is assessed using the ASTM E1268-01 standard. The cyclic intercritical treatments lead to formation of isotropic microstructures even for cooling rates far below the critical one determined in conventional continuous cooling. In contrast, isothermal intercritical experiments have no effect on the critical cooling rate to suppress microstructural band formation. The origin of the suppression of band formation either by means of fast cooling or a cyclic partial phase transformation is investigated in detail. Theoretical modeling and microstructural observations confirm that band formation is suppressed only if the intercritical annealing treatment leads to partial reversion of the austenite-ferrite interfaces. The resulting interfacial Mn enrichment is responsible for suppression of the band formation upon final cooling at low cooling rates.

  17. Small polaron hopping in magnetic semiconductors

    International Nuclear Information System (INIS)

    Emin, D.; Liu, N.L.H.

    1978-01-01

    In a number of magnetic insulators it has been hypothesized that the charge carriers form small polarons. The transfer of an electron between magnetic sites and how the magnetic nature of the material affects the rate which characterizes small-polaron hops between magnetic sites were studied. The basic transfer processes are addressed from a many-electron point in which the itinerant electron is treated as indistinguishable from those which contribute unpaired spins at the magnetic sites

  18. Breakdown of the lattice polaron picture in La0.7Ca0.3MnO3 single crystals

    International Nuclear Information System (INIS)

    Chun, S. H.; Salamon, M. B.; Tomioka, Y.; Tokura, Y.

    2000-01-01

    When heated through the magnetic transition at T C , La 0.7 Ca 0.3 MnO 3 changes from a band metal to a polaronic insulator. The Hall constant R H , through its activated behavior and sign anomaly, provides key evidence for polaronic behavior. We use R H and the Hall mobility to demonstrate the breakdown of the polaron phase. Above 1.4T C , the polaron picture holds in detail, while below, the activation energies of both R H and the mobility deviate strongly from their polaronic values. These changes reflect the presence of metallic, ferromagnetic fluctuations, in the volume of which the Hall effect develops additional contributions tied to quantal phases. (c) 2000 The American Physical Society

  19. Changes in Gallbladder Motility and Gallstone Formation Following Laparoscopic Gastric Banding for Morbid Obesity

    Directory of Open Access Journals (Sweden)

    Bilal O Al-Jiffry

    2003-01-01

    Full Text Available Morbid obesity is associated with cholesterol gallstone formation, a risk compounded by rapid weight loss. Laparoscopic gastric banding allows for a measured rate of weight loss, but the subsequent risk for developing gallstones is unknown.

  20. Dynamics of photogenerated polarons and polaron pairs in P3HT thin films

    Czech Academy of Sciences Publication Activity Database

    Menšík, Miroslav; Pfleger, Jiří; Toman, Petr

    2017-01-01

    Roč. 677, 1 June (2017), s. 87-91 ISSN 0009-2614 R&D Projects: GA MŠk(CZ) LO1507 Institutional support: RVO:61389013 Keywords : poly(3-hexyl thiophene) * transient absorption spectroscopy * polaron and polaron pairs Subject RIV: CD - Macromolecular Chemistry OBOR OECD: Polymer science Impact factor: 1.815, year: 2016

  1. Dynamics of the optically-induced properties of a small-polaronic glass

    International Nuclear Information System (INIS)

    Emin, D.

    1979-01-01

    The relaxation and recombination of an electronic excitation created by the absorption of a super-band-gap photon is considered for a system in which excitons and charge carriers find it energetically favorable to self-trap. The notions of a barrier to self-trapping, a short-range repulsion between electrons and holes, and the electromodulation of the small-polaron absorption band play a central role in this discussion. The results are consistent with experiments on chalcogenide glasses

  2. Efficacy of the DFT + U formalism for modeling hole polarons in perovskite oxides

    Science.gov (United States)

    Erhart, Paul; Klein, Andreas; Åberg, Daniel; Sadigh, Babak

    2014-07-01

    We investigate the formation of self-trapped holes (STH) in three prototypical perovskites (SrTiO3, BaTiO3, PbTiO3) using a combination of density functional theory (DFT) calculations with local potentials and hybrid functionals. First we construct a local correction potential for polaronic configurations in SrTiO3 that is applied via the DFT + U method and matches the forces from hybrid calculations. We then use the DFT + U potential to search the configuration space and locate the lowest energy STH configuration. It is demonstrated that both the DFT + U potential and the hybrid functional yield a piecewise linear dependence of the total energy on the occupation of the STH level, suggesting that self-interaction effects have been properly removed. The DFT + U model is found to be transferable to BaTiO3 and PbTiO3, and STH formation energies from DFT + U and hybrid calculations are in close agreement for all three materials. STH formation is found to be energetically favorable in SrTiO3 and BaTiO3 but not in PbTiO3, which can be rationalized by considering the alignment of the valence band edges on an absolute energy scale. In the case of PbTiO3 the strong coupling between Pb 6s and O 2p states lifts the valence band minimum (VBM) compared to SrTiO3 and BaTiO3. This reduces the separation between VBM and STH level and renders the STH configuration metastable with respect to delocalization (band hole state). We expect that the present approach can be adapted to study STH formation also in oxides with different crystal structures and chemical compositions.

  3. Formation of banded vegetation patterns resulted from interactions between sediment deposition and vegetation growth.

    Science.gov (United States)

    Huang, Tousheng; Zhang, Huayong; Dai, Liming; Cong, Xuebing; Ma, Shengnan

    2018-03-01

    This research investigates the formation of banded vegetation patterns on hillslopes affected by interactions between sediment deposition and vegetation growth. The following two perspectives in the formation of these patterns are taken into consideration: (a) increased sediment deposition from plant interception, and (b) reduced plant biomass caused by sediment accumulation. A spatial model is proposed to describe how the interactions between sediment deposition and vegetation growth promote self-organization of banded vegetation patterns. Based on theoretical and numerical analyses of the proposed spatial model, vegetation bands can result from a Turing instability mechanism. The banded vegetation patterns obtained in this research resemble patterns reported in the literature. Moreover, measured by sediment dynamics, the variation of hillslope landform can be described. The model predicts how treads on hillslopes evolve with the banded patterns. Thus, we provide a quantitative interpretation for coevolution of vegetation patterns and landforms under effects of sediment redistribution. Copyright © 2018. Published by Elsevier Masson SAS.

  4. Visualizing the Efimov Correlation in Bose Polarons

    Science.gov (United States)

    Sun, Mingyuan; Zhai, Hui; Cui, Xiaoling

    2017-07-01

    The Bose polaron is a quasiparticle of an impurity dressed by surrounding bosons. In few-body physics, it is known that two identical bosons and a third distinguishable particle can form a sequence of Efimov bound states in the vicinity of interspecies scattering resonance. On the other hand, in the Bose polaron system with an impurity atom embedded in many bosons, no signature of Efimov physics has been reported in the existing spectroscopy measurements to date. In this Letter, we propose that a large mass imbalance between a light impurity and heavy bosons can help produce visible signatures of Efimov physics in such a spectroscopy measurement. Using the diagrammatic approach in the virial expansion to include three-body effects from pair-wise interactions, we determine the impurity self-energy and its spectral function. Taking the 6Li - 133Cs system as a concrete example, we find two visible Efimov branches in the polaron spectrum, as well as their hybridizations with the attractive polaron branch. We also discuss the general scenarios for observing the signature of Efimov physics in polaron systems. This work paves the way for experimentally exploring intriguing few-body correlations in a many-body system in the near future.

  5. Al-bound hole polarons in TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Stashans, Arvids, E-mail: arvids@utpl.edu.ec [Grupo de Fisicoquimica de Materiales, Instituto de Quimica Aplicada, Universidad Tecnica Particular de Loja, Apartado 11-01-608, Loja (Ecuador); Bermeo, Sthefano [Grupo de Fisicoquimica de Materiales, Instituto de Quimica Aplicada, Universidad Tecnica Particular de Loja, Apartado 11-01-608, Loja (Ecuador)] [Escuela de Electronica y Telecomunicaciones, Universidad Tecnica Particular de Loja, Apartado 11-01-608, Loja (Ecuador)

    2009-09-18

    Changes in the structural and electronic properties of TiO{sub 2} (anatase and rutile) due to the Al-doping are studied using a quantum-chemical approach based on the Hartree-Fock theory. The formation of hole polarons trapped at oxygen sites near the Al impurity has been discovered and their spatial configuration are discussed. The occurrence of well-localized one-center hole polarons in rutile may influence its photocatalytic activity. Optical absorption energy for this hole center is obtained, 0.4 eV, using the {Delta}SCF approach.

  6. Signatures of mesoscopic Jahn-Teller polaron inhomogeneities in high-temperature superconductors

    CERN Document Server

    Bishop, A R; Leon, J M D

    2003-01-01

    We analyse complementary experimental results in high-temperature superconducting cuprates from x-ray absorption fine structure (XAFS), inelastic neutron scattering (INS) and inelastic x-ray scattering (IXS), Raman spectroscopy (RS), infrared absorption spectroscopy and femtosecond optical spectroscopy in terms of the predictions of a specific fully quantum mechanical calculation of small polaron formation and internal dynamics (phonon-assisted local charge oscillations). These analyses support the scenario in which the pseudogap-associated temperature, T*, marks the onset of an inhomogeneous ground state with polarons, in agreement with several theoretical models which attempt to explain the origin of high-temperature superconductivity in doped cuprates. The change in dynamics, which is observed across the superconducting transition temperature, T sub c in XAFS, INS and RS, indicates an intimate link of the dynamics of these polarons with the mechanism of high-temperature superconductivity. (letter to the ed...

  7. Importance of polaron effects for charge carrier mobility above and ...

    Indian Academy of Sciences (India)

    Orifjon Ganiev

    2017-05-30

    May 30, 2017 ... It is shown that the scattering of polaronic charge carriers and bosonic Cooper pairs at acoustic and optical phonons are responsible for the charge carrier mobility above and below the PG temperature. We show that the energy scales of the binding energies of large polarons and polaronic Cooper pairs.

  8. Importance of polaron effects for charge carrier mobility above and ...

    Indian Academy of Sciences (India)

    It is shown that the scattering of polaronic charge carriers and bosonic Cooper pairs at acoustic and optical phonons are responsible for the charge carrier mobility above and below the PG temperature. We show that the energy scales of the binding energies of large polarons and polaronic Cooper pairs can be identified by ...

  9. Effects of texture on shear band formation in plane strain tension/compression and bending

    DEFF Research Database (Denmark)

    Kuroda, M.; Tvergaard, Viggo

    2007-01-01

    model analysis. Third, shear band developments in plane strain pure bending of a sheet specimen with the typical textures are studied. Regions near the surfaces in a bent sheet specimen are approximately subjected to plane strain tension or compression. From this viewpoint, the bendability of a sheet......In this study, effects of typical texture components observed in rolled aluminum alloy sheets on shear band formation in plane strain tension/compression and bending are systematically studied. The material response is described by a generalized Taylor-type polycrystal model, in which each grain...... are obtained: i.e. the critical strain at the onset of shear banding and the corresponding orientation of shear band. Second, the shear band development in plane strain tension/compression is analyzed by the finite element method. Predictability of the finite element analysis is compared to that of the simple...

  10. GPM GROUND VALIDATION NOAA S-BAND PROFILER RAW DATA NETCDF FORMAT MC3E V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The S-band Profiler Raw dataset was saved in two data formats: netCDF anda proprietary Vaisala SPC format. The numeric values in both formats are exactly the same....

  11. Closure of the Mott gap and formation of a superthermal metal in the Fröhlich-type nonequilibrium polaron Bose-Einstein condensate in UO2+x

    Energy Technology Data Exchange (ETDEWEB)

    Conradson, Steven D.; Andersson, David A.; Boland, Kevin S.; Bradley, Joseph A.; Byler, Darrin D.; Durakiewicz, Tomasz; Gilbertson, Steven M.; Kozimor, Stosh A.; Kvashnina, Kristina O.; Nordlund, Dennis; Rodriguez, George; Seidler, Gerald T.; Bagus, Paul S.; Butorin, Sergei M.; Conradson, Dylan R.; Espinosa-Faller, Francisco J.; Hess, Nancy J.; Kas, Joshua J.; Lezama-Pacheco, Juan S.; Martin, Philippe; Martucci, Mary B.; Rehr, John J.; Valdez, James A.; Bishop, Alan R.; Baldinozzi, Gianguido; Clark, David L.; Tayal, Akhil

    2017-09-01

    Mixed valence O-doped UO2+x and photoexcited UO2 containing transitory U3+ and U5+ host a coherent polaronic quantum phase (CPQP) that exhibits the characteristics of a Fröhlich-type, nonequilibrium, phonon-coupled Bose-Einstein condensate whose stability and coherence are amplified by collective, anharmonic motions of atoms and charges. Complementary to the available, detailed, real space information from scattering and EXAFS, an outstanding question is the electronic structure. Mapping the Mott gap in UO2, U4O9, and U3O7 with O XAS and NIXS and UM5 RIXS shows that O doping raises the peak of the U5f states of the valence band by ~0.4 eV relative to a calculated value of 0.25 eV. However, it lowers the edge of the conduction band by 1.5 eV vs the calculated 0.6 eV, a difference much larger than the experimental error. This 1.9 eV reduction in the gap width constitutes most of the 2–2.2 eV gap measured by optical absorption. In addition, the XAS spectra show a tail that will intersect the occupied U5f states and give a continuous density-of-states that increases rapidly above its constricted intersection. Femtosecond-resolved photoemission measurements of UO2, coincident with the excitation pulse with 4.7 eV excitation, show the unoccupied U5f states of UO2 and no hot electrons. 3.1 eV excitation, however, complements the O-doping results by giving a continuous population of electrons for several eV above the Fermi level. The CPQP in photoexcited UO2 therefore fulfills the criteria for a nonequilibrium condensate. The electron distributions resulting from both excitations persist for 5–10 ps, indicating that they are the final state that therefore forms without passing through the initial continuous distribution of nonthermal electrons observed for other materials. Three exceptional findings are: (1) the direct formation of both

  12. Band Formation in Mixtures of Oppositely Charged Colloids Driven by an ac Electric Field

    NARCIS (Netherlands)

    Vissers, T.; van Blaaderen, A.; Imhof, A.

    2011-01-01

    We present experiments on pattern formation in a Brownian system of oppositely charged colloids driven by an ac electric field. Using confocal laser scanning microscopy we observe complete segregation of the two particle species into bands perpendicular to a field of sufficient strength when the

  13. Trace-Element Analyses of Carbonate Minerals in the Gunflint Banded Iron Formation

    Science.gov (United States)

    Pun, Aurora; Papike, James J.; Shearer, C. K.

    2002-01-01

    We report on the petrography, mineralogy and trace-element abundances of individual carbonate grains in the Early Proterozoic Gunflint BIF (Banded Iron Formation). Trace-element data may be used as environmental recorders of the fluid evolution from which the various carbonate phases precipitated. Additional information is contained in the original extended abstract.

  14. Band registration of tuneable frame format hyperspectral UAV imagers in complex scenes

    Science.gov (United States)

    Honkavaara, Eija; Rosnell, Tomi; Oliveira, Raquel; Tommaselli, Antonio

    2017-12-01

    A recent revolution in miniaturised sensor technology has provided markets with novel hyperspectral imagers operating in the frame format principle. In the case of unmanned aerial vehicle (UAV) based remote sensing, the frame format technology is highly attractive in comparison to the commonly utilised pushbroom scanning technology, because it offers better stability and the possibility to capture stereoscopic data sets, bringing an opportunity for 3D hyperspectral object reconstruction. Tuneable filters are one of the approaches for capturing multi- or hyperspectral frame images. The individual bands are not aligned when operating a sensor based on tuneable filters from a mobile platform, such as UAV, because the full spectrum recording is carried out in the time-sequential principle. The objective of this investigation was to study the aspects of band registration of an imager based on tuneable filters and to develop a rigorous and efficient approach for band registration in complex 3D scenes, such as forests. The method first determines the orientations of selected reference bands and reconstructs the 3D scene using structure-from-motion and dense image matching technologies. The bands, without orientation, are then matched to the oriented bands accounting the 3D scene to provide exterior orientations, and afterwards, hyperspectral orthomosaics, or hyperspectral point clouds, are calculated. The uncertainty aspects of the novel approach were studied. An empirical assessment was carried out in a forested environment using hyperspectral images captured with a hyperspectral 2D frame format camera, based on a tuneable Fabry-Pérot interferometer (FPI) on board a multicopter and supported by a high spatial resolution consumer colour camera. A theoretical assessment showed that the method was capable of providing band registration accuracy better than 0.5-pixel size. The empirical assessment proved the performance and showed that, with the novel method, most parts of

  15. Experimental method for the evaluation of the susceptibility of materials to shear band formation

    Directory of Open Access Journals (Sweden)

    Tham R.

    2012-08-01

    Full Text Available In order to characterize materials with respect to their susceptibility to shear band formation at high strain rates, a modified Hopkinson pressure bar apparatus and hat-shaped steel specimens with a shear zone having a width significantly larger than the typical width of adiabatic bands are used. The sample is directly impacted by the striker. The force acting on the sample is measured with a PVDF-gauge between the sample and the output bar. The displacement is recorded with an electro-optical extensometer. The energy absorbed by the shearing process up to failure can be used as a reference for the susceptibility of materials to shear band formation. The method is demonstrated comparing the shear behavior of two high-strength steels with similar metallic structure and strength. Differences were found in the transition region between quasi-static and fully adiabatic shearing conditions where the energy up to rupture differs by 40 %. For fully adiabatic shear band formation, the deformation process of both materials equals. At extreme rates, shear processes are mainly governed by the thermodynamic properties of the materials. On the other hand, strength and structural properties play a role for low and intermediate rates where global and localized shear mechanisms occur in parallel.

  16. Mesoarchean Banded Iron Formation sequences in Dixon Island-Cleaverville Formation, Pilbara Australia: Oxygenic signal from DXCL project

    Science.gov (United States)

    Kiyokawa, S.; Ito, T.; Ikehara, M.; Yamaguchi, K. E.; Naraoka, H.; Onoue, T.; Horie, K.; Sakamoto, R.; Aihara, Y.; Miki, T.

    2013-12-01

    The 3.2-3.1 Ga Dixon island-Cleaverville formations are well-preserved Banded Iron Formation (BIF) within hydrothermal oceanic sequence at oceanic island arc setting (Kiyokawa et al., 2002, 2006, 2012). The stratigraphy of the Dixon Island (3195+15Ma) -Cleaverville (3108+13Ma) formations shows the well preserved environmental condition at the Mesoarchean ocean floor. The stratigraphy of these formations are formed about volcano-sedimentary sequences with hydrothermal chert, black shale and banded iron formation to the top. Based on the scientific drilling of DXCL project at 2007 and 2011, detail lithology between BIF sequence was clearly understood. Four drilling holes had been done at coastal sites; the Dixon Island Formation is DX site (100m) and the Cleaverville Formation is CL2 (40m), CL1 (60m) and CL3 (200m) sites and from stratigraphic bottom to top. Coarsening and thickening upward black shale-BIF sequences are well preserved of the stratigraphy form the core samples. The Dixon Island Formation consists komatiite-rhyolite sequences with many hydrothermal veins and very fine laminated cherty rocks above them. The Cleaverville Formation contains black shale, fragments-bearing pyroclastic beds, white chert, greenish shale and BIF. The CL3 core, which drilled through BIF, shows siderite-chert beds above black shale identified before magnetite lamination bed. U-Pb SHRIMP data of the tuff in lower Dixon Island Formation is 3195+15 Ma and the pyroclastic sequence below the Cleaverville BIF is 3108+13 Ma. Sedimentation rate of these sequence is 2-8 cm/ 1000year. The hole section of the organic carbon rich black shales below BIF are similar amount of organic content and 13C isotope (around -30per mill). There are very weak sulfur MIF signal (less 0.2%) in these black shale sequence. Our result show that thick organic rich sediments may be triggered to form iron rich siderite and magnetite iron beds. The stratigraphy in this sequence quite resemble to other Iron

  17. Magnetic polarons in a nonequilibrium polariton condensate

    Science.gov (United States)

    Mietki, Paweł; Matuszewski, Michał

    2017-09-01

    We consider a condensate of exciton polaritons in a diluted magnetic semiconductor microcavity. Such a system may exhibit magnetic self-trapping in the case of sufficiently strong coupling between polaritons and magnetic ions embedded in the semiconductor. We investigate the effect of the nonequilibrium nature of exciton polaritons on the physics of the resulting self-trapped magnetic polarons. We find that multiple polarons can exist at the same time, and we derive a critical condition for self-trapping that is different from the one predicted previously in the equilibrium case. Using the Bogoliubov-de Gennes approximation, we calculate the excitation spectrum and provide a physical explanation in terms of the effective magnetic attraction between polaritons, mediated by the ion subsystem.

  18. Mechanisms of bands and spirals formation during the drying of watery solutions of mercury (II) chloride with agar-agar

    Energy Technology Data Exchange (ETDEWEB)

    Suarez-DomInguez, Edgardo Jonathan; Betancourt-Mar, Juvencio Alberto [Laboratorio de Investigacion UNE-SAS, Universidad del Noreste, Prol. Av. Hidalgo 6315 Col. Nuevo Aeropuerto, Tampico, Tam., Mexico, C.P. 89337 (Mexico)

    2005-01-01

    It is proposed two mechanisms to explain the formation of periodic and non periodic bands and spirals as thin films of gelatinous aqueous solutions of mercury (II) chloride are dried. The first mechanism supposes an homogeneous drying, where the height of the film decreases at constant rate, forming Liesegang bands. The second mechanism implies a non homogeneous drying where an evaporation front drives the formation of periodic bands and spirals.

  19. Understanding Birnessite MnO2: Effects of Small Polaron and Local Dipole

    Science.gov (United States)

    Peng, Haowei; Perdew, John P.

    Birnessite MnO2, usually with cations like K and Na intercalated between layers, is a class of potential cheap oxygen evolution reaction (OER) catalyst. Using hybrid density functional calculations, we investigate the electronic structures of the layered MnO2 with the intercalated cation modelled as a defect. We found that an electron small polaron will form when an extra electron is doped in the pure MnO2, turning a Mn(IV) to a Mn(III) with a singly occupied eg orbital located within the band gap, and the resulting small-polaron hopping conduction explains the observed low electric conductivity. The inter-layer doped K atom will donate one electron to one Mn ion as expected, and also contributes to a local dipole forming between K and the Mn(III), raising the electrostatic potential of the specific layer. With a certain spatial distribution of such local dipoles, the small-polaron eg states become comparable in energy with the global conduction band minimum, and charge transfer occurs. This further results in a singly or partially occupied eg orbital near the Fermi level, which has been regarded as a signal for an excellent OER catalyst. Our calculation helps understanding several experimental observations. This work was supported as part of the CCDM-EFRC funded by the U.S. DOE, Office of Science, Basic Energy Sciences.

  20. Mobile Polaronic States in α-MoO3: An ab Initio Investigation of the Role of Oxygen Vacancies and Alkali Ions.

    Science.gov (United States)

    Tahini, Hassan A; Tan, Xin; Lou, Shi Nee; Scott, Jason; Amal, Rose; Ng, Yun Hau; Smith, Sean C

    2016-05-04

    Some oxides have the ability to trap excess electrons in the form of small polarons. Here, using first-principles techniques, we investigate the interaction of excess electrons with α-MoO3. Polarons are found to be about 0.6 eV more stable than delocalized electrons. They can propagate with a high degree of anisotropicity along different crystallographic directions with the lowest barrier found to be about 0.08 eV. In addition to the band gap photoexcited charge carriers that can populate such polaron states, we investigate the role of oxygen vacancies as an intrinsic source of electrons. We also investigate intercalated alkali ions that can form complexes with the created polarons in the lattice. The alkali-polaron complex (AxMoO6, A = alkali ion) binding energies are relatively low, making it easy for the complex to dissociate. This, coupled with the low polaron migration energies, can generate a non-negligible contribution to electronic conductivity even in the absence of illumination, which is experimentally verified. Combined, this light-induced intercalation of alkali ion in MoO3 and its subsequent deintercalation (complex dissociation) processes lead to a novel self-photocharghing phenomenon.

  1. Polarons in wide-band-gap molecular materials: Polysilanes

    Czech Academy of Sciences Publication Activity Database

    Nešpůrek, Stanislav; Schauer, F.; Kadashchuk, A.; Fishchuk, I. I.

    2007-01-01

    Roč. 353, 47-51 (2007), s. 4474-4478 ISSN 0022-3093. [Conference International Dielectric Society /4./ and International Conference Dielectric and Related Phenomena /9./. Poznan, 03.09.2006-07.09.2006] R&D Projects: GA AV ČR IAA100100622 Grant - others:GA AV ČR(CZ) KAN100400701 Program:KA Institutional research plan: CEZ:AV0Z40500505 Keywords : phonons * conductivity Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.319, year: 2007

  2. Polaron self-localization in white-light emitting hybrid perovskites

    KAUST Repository

    Cortecchia, Daniele

    2017-02-03

    Two-dimensional (2D) perovskites with the general formula APbX are attracting increasing interest as solution processable, white-light emissive materials. Recent studies have shown that their broadband emission is related to the formation of intra-gap colour centres. Here, we provide an in-depth description of the charge localization sites underlying the generation of such radiative centres and their corresponding decay dynamics, highlighting the formation of small polarons trapped within their lattice distortion field. Using a combination of spectroscopic techniques and first-principles calculations to study the white-light emitting 2D perovskites (EDBE)PbCl and (EDBE)PbBr, we infer the formation of Pb , Pb, and X (where X = Cl or Br) species confined within the inorganic perovskite framework. Due to strong Coulombic interactions, these species retain their original excitonic character and form self-trapped polaron-excitons acting as radiative colour centres. These findings are expected to be relevant for a broad class of white-light emitting perovskites with large polaron relaxation energy.

  3. Effect of packing fraction on shear band formation in a granular material forced by a penetrometer.

    Science.gov (United States)

    Tapia, Franco; Espíndola, David; Hamm, Eugenio; Melo, Francisco

    2013-01-01

    Granular ensembles subjected to confinement forces can reach metastable states that often break down via formation of shear bands for sufficiently high deviatoric stress. In this article we investigate the flow induced in a granular ensemble that is perturbed by a vertically moving finger in a quasiplanar geometry. The flow exhibits spiral-like shear bands and evolves discontinuously in time, in concert with an oscillating penetration force. We characterize the nature of this nucleation-relaxation type process for loose to dense packing fractions. The nucleation dynamics is reasonably well described by a simple Mohr-Coulomb failure criterium in which the friction coefficient is a function of packing fraction. We contrast our findings with the recent work of Gravish et al. [Phys. Rev. Lett. 105, 128301 (2010)].

  4. Creation of Rydberg Polarons in a Bose Gas

    Science.gov (United States)

    Schmidt, Richard

    2017-04-01

    In this talk we review the theory of various types of Bose polarons that can be realized in ultracold atomic systems. We then report the spectroscopic observation of Rydberg polarons in a Bose gas which is in excellent agreement with theoretical predictions. This novel type of polaron is created by excitation of Rydberg atoms in a strontium Bose-Einstein condensate and it is distinguished by the occupation of a large number bound molecular states. The cross-over from few-body bound molecular oligomers to many-body polaron features is described with a functional determinant theory that solves an extended Froehlich Hamiltonian for an impurity in a Bose gas. The detailed analysis of the red-detuned tail of the excitation spectrum describes the contribution from the region of highest density in the condensate and provides a clear signature of Rydberg polarons. This work has been performed in collaboration with groups at Rice University, Harvard University, and the TU Vienna.

  5. Properties of a Bound Polaron under a Perpendicular Magnetic Field

    International Nuclear Information System (INIS)

    Liu Jia; Chen Ziyu; Xiao Jinglin; Huo Shufen

    2007-01-01

    We investigate the influence of a perpendicular magnetic field on a bound polaron near the interface of a polar-polar semiconductor with Rashba effect. The external magnetic field strongly changes the ground state binding energy of the polaron and the Rashba spin-orbit (SO) interaction originating from the inversion asymmetry in the heterostructure splits the ground state binding energy of the bound polaron. In this paper, we have shown how the ground state binding energy will be with the change of the external magnetic field, the location of a single impurity, the wave vector of the electron and the electron areal density, taking into account the SO coupling. Due to the presence of the phonons, whose energy gives negative contribution to the polaron's, the spin-splitting states of the bound polaron are more stable, and we find that in the condition of week magnetic field, the Zeeaman effect can be neglected.

  6. Weak coupling polaron and Landau-Zener scenario: Qubits modeling

    Science.gov (United States)

    Jipdi, M. N.; Tchoffo, M.; Fokou, I. F.; Fai, L. C.; Ateuafack, M. E.

    2017-06-01

    The paper presents a weak coupling polaron in a spherical dot with magnetic impurities and investigates conditions for which the system mimics a qubit. Particularly, the work focuses on the Landau-Zener (LZ) scenario undergone by the polaron and derives transition coefficients (transition probabilities) as well as selection rules for polaron's transitions. It is proven that, the magnetic impurities drive the polaron to a two-state superposition leading to a qubit structure. We also showed that the symmetry deficiency induced by the magnetic impurities (strong magnetic field) yields to the banishment of transition coefficients with non-stacking states. However, the transition coefficients revived for large confinement frequency (or weak magnetic field) with the orbital quantum numbers escorting transitions. The polaron is then shown to map a qubit independently of the number of relevant states with the transition coefficients lifted as LZ probabilities and given as a function of the electron-phonon coupling constant (Fröhlich constant).

  7. Soliton and polaron generation in polyacetylene

    International Nuclear Information System (INIS)

    Su, Zhao-bin; Yu, Lu.

    1984-07-01

    The nonradiative decay of an e-h pair into soliton pair and that of an electron (hole) into polaron as well as the photoproduction of soliton pairs are considered using the lattice relaxation theory of multiphonon processes generalized to include the self-consistency of the multi-electron states with the lattice symmetry breaking. The selection rule which forbids the direct process of photogeneration for neutral pair is derived from the symmetry arguments. The branching ratio of the photogenerated neutral to charged soliton pairs is estimated. The recent related experiments are discussed. (author)

  8. Optical Characterization of the Hole Polaron in a Series of Diketopyrrolopyrrole Polymers Used for Organic Photovoltaics

    Directory of Open Access Journals (Sweden)

    Evan L. Williams

    2014-12-01

    Full Text Available A strategy that is often used for designing low band gap polymers involves the incorporation of electron-rich (donor and electron-deficient (acceptor conjugated segments within the polymer backbone. In this paper we investigate such a series of Diketopyrrolopyrrole (DPP-based co-polymers. The co-polymers consisted of a DPP unit attached to a phenylene, naphthalene, or anthracene unit. Additionally, polymers utilizing either the thiophene-flanked DPP or the furan-flanked DPP units paired with the naphthalene comonomer were compared. As these polymers have been used as donor materials and subsequent hole transporting materials in organic solar cells, we are specifically interested in characterizing the optical absorption of the hole polaron of these DPP based copolymers. We employ chemical doping, electrochemical doping, and photoinduced absorption (PIA studies to probe the hole polaron absorption spectra. While some donor-acceptor polymers have shown an appreciable capacity to generate free charge carriers upon photoexcitation, no polaron signal was observed in the PIA spectrum of the polymers in this study. The relations between molecular structure and optical properties are discussed.

  9. Magnetite: What it reveals about the origin of the banded iron formations. [Abstract only

    Science.gov (United States)

    Schwartz, D. E.; Mancinelli, R. L.; White, M. R.

    1994-01-01

    Magnetite, Fe3O4 is produced abiotically and biotically. Abiotically, magnetite is a late magmatic mineral and forms as a consequence of the cooling of iron rich magma. Biotically, magnetite is produced by several organisms, including magnetotactic bacteria. Hematite, Fe2O3, is also produced abiotically and biotically. Abiotically, hematite rarely occurs as a primary mineral in igneous rocks, but is common as an alteration product, fumarole deposit, and in some metamorphosed Fe-rich rocks. Biotically, hematite is produced by several types of microorganisms. Biologically-produced magnetite and hematite are formed under the control of the host organism, and consequently, have characteristics not found in abiotically produced magnetite and hematite crystals. To determine if the magnetite and hematite in the Banded Iron Formation was biologically or abiotically produced, the characteristics of biologically-produced magnetite and hematite (concentrated from Aquaspirillum magnetotacticum) and abiotically-produced magnetite and hematite obtained from Wards Scientific Supply Company, were compared with characteristics of magnetite and hematite concentrated from the Gunflint Banded Iron Formation (Ontario, Canada) using thermal and crystallographic analytical techniques. Whole rock analysis of the Gunflint Banded Iron Formation by x-ray diffraction (XRD) and differential thermal analysis (DTA) revealed the presence of quartz, hematite, siderite and dolomite as the major minerals, and magnetite, greenalite, pyrite, pyrrhotite and apatite as the minor minerals. Analysis of a crude magnetic fraction of the Gunflint showed the minerals quartz, hematite, siderite, dolomite, and magnetite. Analysis of the crude magnetic fraction from Aquaspirillum magnetotacticum revealed organic compounds plus hematite and magnetite. The mineral identification and particle size distribution data obtained from the DTA along with XRD data indicate that the magnetite and hematite from the Gunflint

  10. GPM GROUND VALIDATION NOAA S-BAND PROFILER RAW DATA NETCDF FORMAT MC3E V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The GPM Ground Validation NOAA S-Band Profiler Raw Data NetCDF Format MC3E dataset was gathered during the Midlatitude Continental Convective Clouds Experiment...

  11. Effects of hole self-trapping by polarons on transport and negative bias illumination stress in amorphous-IGZO

    Science.gov (United States)

    de Jamblinne de Meux, A.; Pourtois, G.; Genoe, J.; Heremans, P.

    2018-04-01

    The effects of hole injection in amorphous indium-gallium-zinc-oxide (a-IGZO) are analyzed by means of first-principles calculations. The injection of holes in the valence band tail states leads to their capture as a polaron, with high self-trapping energies (from 0.44 to 1.15 eV). Once formed, they mediate the formation of peroxides and remain localized close to the hole injection source due to the presence of a large diffusion energy barrier (of at least 0.6 eV). Their diffusion mechanism can be mediated by the presence of hydrogen. The capture of these holes is correlated with the low off-current observed for a-IGZO transistors, as well as with the difficulty to obtain a p-type conductivity. The results further support the formation of peroxides as being the root cause of Negative Bias Illumination Stress (NBIS). The strong self-trapping substantially reduces the injection of holes from the contact and limits the creation of peroxides from a direct hole injection. In the presence of light, the concentration of holes substantially rises and mediates the creation of peroxides, responsible for NBIS.

  12. Microstructural characterization and formation mechanism of abnormal segregation band of hot rolled ferrite/pearlite steel

    International Nuclear Information System (INIS)

    Feng, Rui; Li, Shengli; Zhu, Xinde; Ao, Qing

    2015-01-01

    In order to further reveal the microstructural characterization and formation mechanism of abnormal segregation band of hot rolled ferrite/pearlite steel, the microstructure of this type steel was intensively studied with Scanning Auger Microprobe (SAM), etc. The results show that severe C–Mn segregation exists in the abnormal segregation band region at the center of hot rolled ferrite/pearlite steel, which results from the Mn segregation during solidification process of the continuous casting slab. The C–Mn segregation causes relative displacement of pearlite transformation curve and bainite transformation curve of C curve in the corresponding region, leading to bay-like shaped C curve. The bay-like shaped C curve creates conditions for the transformation from supercooling austenite to bainite at relatively lower cooling rate in this region. The Fe–Mn–C Atomic Segregation Zone (FASZ) caused by C–Mn segregation can powerfully retard the atomic motion, and increase the lattice reconstruction resistance of austenite transformation. These two factors provide thermodynamic and kinetic conditions for the bainite transformation, and result in the emergence of granular bainitic abnormal segregation band at the center of steel plate, which leads to lower plasticity and toughness of this region, and induces the layered fracture. - Highlights: • Scanning Auger Microprobe (SAM) is applied in the fracture analysis. • The abnormal segregation band region appears obvious C–Mn segregation. • The C–Mn segregation leads to bay-like shaped C curve. • The C–Mn segregation leads to Fe–Mn–C Atomic Segregation Zone

  13. Spectral characteristics of banded iron formations in Singhbhum craton, eastern India: Implications for hematite deposits on Mars

    Directory of Open Access Journals (Sweden)

    Mahima Singh

    2016-11-01

    Full Text Available Banded iron formations (BIFs are major rock units having hematite layers intermittent with silica rich layers and formed by sedimentary processes during late Archean to mid Proterozoic time. In terrestrial environment, hematite deposits are mainly found associated with banded iron formations. The BIFs in Lake Superior (Canada and Carajas (Brazil have been studied by planetary scientists to trace the evolution of hematite deposits on Mars. Hematite deposits are extensively identified in Meridiani region on Mars. Many hypotheses have been proposed to decipher the mechanism for the formation of these deposits. On the basis of geomorphological and mineralogical studies, aqueous environment of deposition is found to be the most supportive mechanism for its secondary iron rich deposits. In the present study, we examined the spectral characteristics of banded iron formations of Joda and Daitari located in Singhbhum craton in eastern India to check its potentiality as an analog to the aqueous/marine environment on Mars. The prominent banding feature of banded iron formations is in the range of few millimeters to few centimeters in thickness. Fe rich bands are darker (gray in color compared to the light reddish jaspilitic chert bands. Thin quartz veins (<4 mm are occasionally observed in the hand-specimens of banded iron formations. Spectral investigations have been conducted in VIS/NIR region of electromagnetic spectrum in the laboratory conditions. Optimum absorption bands identified include 0.65, 0.86, 1.4 and 1.9 μm, in which 0.56 and 0.86 μm absorption bands are due to ferric iron and 1.4 and 1.9 μm bands are due to OH/H2O. To validate the mineralogical results obtained from VIS/NIR spectral radiometry, laser Raman and Fourier transform infrared spectroscopic techniques were utilized and the results were found to be similar. Goethite-hematite association in banded iron formation in Singhbhum craton suggests dehydration activity, which has

  14. Polaronic exciton behavior in gas-phase water

    Science.gov (United States)

    Udal'tsov, Alexander V.

    2018-03-01

    Features of the absorption spectrum of gas-phase water in the energy range 7-10 eV have been considered applying polaronic exciton theory. The interaction of the incident photon generating polaronic exciton in water is described taking into account angular momentum of the electron so that polaronic exciton radii have been estimated in dependence on spin-orbit coupling under proton sharing. The suggested approach admits an estimate of kinetic and rotation energies of the polaronic exciton. As a result sixteen steps of half Compton wavelength, λC/2 = h/(2mec) changing polaronic exciton radius were found consistent with local maxima and shoulders in the spectrum. Thus, the absorption of gas-phase water in the energy range 8.5-10 eV has been interpreted in terms of polaronic exciton rotation mainly coupled with the proton sharing. The incident photon interaction with water is also considered in terms of Compton interaction, when the rotation energy plays a role like the energy loss of the incident photon under Compton scattering. The found symmetry and the other evidence allowed to conclude about polaronic exciton migration under the interaction angle 90°.

  15. The Bogolubov Representation of the Polaron Model and Its Completely Integrable RPA-Approximation

    International Nuclear Information System (INIS)

    Bogolubov, Nikolai N. Jr.; Prykarpatsky, Yarema A.; Ghazaryan, Anna A.

    2009-12-01

    The polaron model in ionic crystal is studied in the N. Bogolubov representation using a special RPA-approximation. A new exactly solvable approximated polaron model is derived and described in detail. Its free energy at finite temperature is calculated analytically. The polaron free energy in the constant magnetic field at finite temperature is also discussed. Based on the structure of the N. Bogolubov unitary transformed polaron Hamiltonian a very important new result is stated: the full polaron model is exactly solvable. (author)

  16. Studies on alkaline band formation in Chara corallina: ameliorating effect of Ca2+ on inhibition induced by osmotic shock.

    Science.gov (United States)

    Shimmen, Teruo; Yonemura, Satoko; Negoro, Mio; Lucas, William J

    2003-09-01

    Although the decrease in cell turgor by application of sorbitol to the external medium did not inhibit the alkaline band formation in Chara corallina, recovery of normal turgor severely inhibited it. Alkaline-loading analysis suggested that the inhibition of alkaline band formation was caused by inhibition of HCO(3)(-) influx but not that of OH(-) efflux. In the presence of 10 mM CaCl(2), the capacity of alkaline band formation was maintained during osmotic treatment. Cells could not form alkaline bands, when plasmolysis was induced by application of sorbitol at a higher concentration. Addition of 10 mM CaCl(2) could ameliorate the inhibition caused by plasmolyis.

  17. Polaronic localisation of an electron in a magnetic field

    International Nuclear Information System (INIS)

    Aubry, S.

    1994-01-01

    When a uniform magnetic field is applied to a single electron in 2D and 3D continuous and elastically deformable medium, a polaronic self localisation occurs at any small coupling although it does not without magnetic field. In 3D, there is also a first order transition as a function of the magnetic field corresponding to the collapse of the large polaron into a small polaron. The discrete lattice effect were numerically investigated in 2D for completing this picture. It is suggested that strong anisotropies in real systems could brought these phenomena in the physically observable range. (author). 6 refs., 5 figs

  18. Inelastic scattering in a local polaron model with quadratic coupling to bosons

    DEFF Research Database (Denmark)

    Olsen, Thomas

    2009-01-01

    We calculate the inelastic scattering probabilities in the wide band limit of a local polaron model with quadratic coupling to bosons. The central object is a two-particle Green's function which is calculated exactly using a purely algebraic approach. Compared with the usual linear interaction term...... a quadratic interaction term gives higher probabilities for inelastic scattering involving a large number of bosons. As an application we consider the problem hot-electron-mediated energy transfer at surfaces and use the delta self-consistent field extension of density-functional theory to calculate...

  19. Bound magnetic polaron driven low-temperature ferromagnetism in Cu1-xMnxO compounds

    Science.gov (United States)

    Cai, J. Z.; Li, L.; Wang, S.; Zou, W. Q.; Wu, X. S.; Zhang, F. M.

    2013-09-01

    Partial Mn atoms have been confirmed to enter the CuO lattice and form the Cu1-xMnxO compounds in the case of doping with 0≤x≤0.2 by the sol-gel method. With increasing Mn content, magnetism is observed. The magnetic critical transition temperature increases with enhanced magnetism, which obeys the bound magnetic polaron theory. The electronic transportation shows an insulating behavior as the band-gap decreases. Our results may indicate that CuO may be used as a candidate of magnetic semiconductor.

  20. The effect of interface hopping on inelastic scattering of oppositely charged polarons in polymers

    International Nuclear Information System (INIS)

    Di Bing; Wang Ya-Dong; Zhang Ya-Lin; An Zhong

    2013-01-01

    The inelastic scattering of oppositely charge polarons in polymer heterojunctions is believed to be of fundamental importance for the light-emitting and transport properties of conjugated polymers. Based on the tight-binding SSH model, and by using a nonadiabatic molecular dynamic method, we investigate the effects of interface hopping on inelastic scattering of oppositely charged polarons in a polymer heterojunction. It is found that the scattering processes of the charge and lattice defect depend sensitively on the hopping integrals at the polymer/polymer interface when the interface potential barrier and applied electric field strength are constant. In particular, at an intermediate electric field, when the interface hopping integral of the polymer/polymer heterojunction material is increased beyond a critical value, two polarons can combine to become a lattice deformation in one of the two polymer chains, with the electron and the hole bound together, i.e., a self-trapped polaron—exciton. The yield of excitons then increases to a peak value. These results show that interface hopping is of fundamental importance and facilitates the formation of polaron—excitons

  1. Atomistic explanation of shear-induced amorphous band formation in boron carbide.

    Science.gov (United States)

    An, Qi; Goddard, William A; Cheng, Tao

    2014-08-29

    Boron carbide (B4C) is very hard, but its applications are hindered by stress-induced amorphous band formation. To explain this behavior, we used density function theory (Perdew-Burke-Ernzerhof flavor) to examine the response to shear along 11 plausible slip systems. We found that the (0111)/ slip system has the lowest shear strength (consistent with previous experimental studies) and that this slip leads to a unique plastic deformation before failure in which a boron-carbon bond between neighboring icosahedral clusters breaks to form a carbon lone pair (Lewis base) on the C within the icosahedron. Further shear then leads this Lewis base C to form a new bond with the Lewis acidic B in the middle of a CBC chain. This then initiates destruction of this icosahedron. The result is the amorphous structure observed experimentally. We suggest how this insight could be used to strengthen B4C.

  2. Spin polaron in the J1-J2 Heisenberg model

    Science.gov (United States)

    Hamad, I. J.; Trumper, A. E.; Feiguin, A. E.; Manuel, L. O.

    2008-01-01

    We have studied the validity of the spin-polaron picture in the frustrated J1-J2 Heisenberg model. For this purpose, we have computed the hole spectral functions for the Néel, collinear, and disordered phases of this model by means of the self-consistent Born approximation and Lanczos exact diagonalization on finite-size clusters. We have found that the spin-polaron quasiparticle excitation is always well defined for the magnetically ordered Néel and collinear phases, even in the vicinity of the magnetic quantum critical points, where the local magnetization vanishes. As a general feature, the effect of frustration is to increase the amplitude of the multimagnon states that build up the spin-polaron wave function, leading to the reduction of the quasiparticle coherence. Based on Lanczos results, we discuss the validity of the spin-polaron picture in the disordered phase.

  3. Importance of polaron effects for charge carrier mobility above and ...

    Indian Academy of Sciences (India)

    HTSCs) have been investigated theoretically. The appropriate Boltzmann transport equations under relaxation time approximation were used to calculate the mobility of polaronic charge carriers and bosonic Cooper pairs above and below the ...

  4. Polarons, free charge localisation and effective dielectric permittivity in oxides

    OpenAIRE

    Maglione, Mario

    2010-01-01

    This review will deal with several types of free charge localisation in oxides and their consequences on the effective dielectric spectra of such materials. The first one is the polaronic localisation at the unit cell scale on residual impurities in ferroelectric networks. The second one is the collective localisation of free charge at macroscopic interfaces like surfaces, electrodes and grain boundaries in ceramics. Polarons have been observed in many oxide perovskites mostly when cations ha...

  5. Effects of aluminum on plasma membrane as revealed by analysis of alkaline band formation in internodal cells of Chara corallina.

    Science.gov (United States)

    Takano, M; Shimmen, T

    1999-06-01

    To study the mechanism of aluminum toxicity in plant cells, the effects of aluminum on alkaline band formation were analyzed in the internodal cells of Chara. After cells were treated with AlCl3, they were examined for their capacity to develop alkaline bands. Treating cells with AlCl3 medium at pH 4.5 completely inhibited alkaline band formation. When either CaCl2 or malic acid was added to the AlCl3 medium (pH 4.5), it did not produce an ameliorative effect, whereas addition of both CaCl2 and malic acid induced a significant ameliorative effect. It was found that treatment at pH 4.5 in the absence of AlCl3 strongly inhibited alkaline band formation. This inhibition by the low pH (4.5) treatment was effectively ameliorated by CaCl2. At higher pH (5.0), malic acid alone produced a significant ameliorative effect on aluminum inhibition of alkaline band formation, but CaCl2 did not. Recovery from aluminum inhibition was also studied. When cells treated with AlCl3 at pH 4.5 were incubated in artificial pond water, they could not recover the capacity to develop alkaline band. When either malic acid or CaCl2 was added to artificial pond water, cells recovered their alkaline band formation. It was concluded that one of the primary targets of aluminum is the plasma membrane and that aluminum affects the plasma membrane from the cell exterior at the beginning of the treatment (within 24 h). It was also suggested that the aluminum treatment impairs the HCO3- influx mechanism but not the OH- efflux mechanism.

  6. Petrology and geochemistry of REE-rich Mafé banded iron formations (Bafia group, Cameroon)

    Science.gov (United States)

    Nkoumbou, Charles; Gentry, Fuh Calistus; Tchakounte Numbem, Jacqueline; Belle Ekwe Lobé, Yolande Vanessa; Nwagoum Keyamfé, Christin Steve

    2017-07-01

    Archaean-Paleoproterozoic foliated amphibole-gneisses and migmatites interstratified with amphibolites, pyroxeno-amphibolites and REE-rich banded-iron formations outcrop at Mafé, Ndikinimeki area. The foliation is nearly vertical due to tight folds. Flat-lying quartz-rich mica schists and quartzites, likely of Pan-African age, partly cover the formations. Among the Mafé BIFs, the oxide BIF facies shows white layers of quartz and black layers of magnetite and accessory hematite, whereas the silicate BIF facies is made up of thin discontinuous quartz layers alternating with larger garnet (almandine-spessartine) + chamosite + ilmenite ± Fe-talc layers. REE-rich oxide BIFs compositions are close to the East Pacific Rise (EPR) hydrothermal deposit; silicate BIFs plot midway between EPR and the associated amphibolite, accounting for a contamination by volcanic materials, in addition to the hydrothermal influence during their oceanic deposition. The association of an oceanic setting with alkaline and tholeiitic magmatism is typical of the Algoma-type BIF deposit. The REE-rich BIFs indices recorded at Mafé are interpreted as resulting from an Archaean-Paleoproterozoic mineralization.

  7. Role of Short-Range Order and Hyperuniformity in the Formation of Band Gaps in Disordered Photonic Materials.

    Science.gov (United States)

    Froufe-Pérez, Luis S; Engel, Michael; Damasceno, Pablo F; Muller, Nicolas; Haberko, Jakub; Glotzer, Sharon C; Scheffold, Frank

    2016-07-29

    We study photonic band gap formation in two-dimensional high-refractive-index disordered materials where the dielectric structure is derived from packing disks in real and reciprocal space. Numerical calculations of the photonic density of states demonstrate the presence of a band gap for all polarizations in both cases. We find that the band gap width is controlled by the increase in positional correlation inducing short-range order and hyperuniformity concurrently. Our findings suggest that the optimization of short-range order, in particular the tailoring of Bragg scattering at the isotropic Brillouin zone, are of key importance for designing disordered PBG materials.

  8. Polaron variable range hopping in TiO2-δ(-0.04=<δ=<0.2) thin films

    International Nuclear Information System (INIS)

    Heluani, S.P.; Comedi, D.; Villafuerte, M.; Juarez, G.

    2007-01-01

    The mechanisms of electrical conduction in TiO 2-δ (-0.04= 2 +Ar gas atmospheres where changes in δ and film structure had been achieved by varying the O 2 flow rate and the substrate temperature. The electrical transport properties of these samples were investigated by measuring the conductivity as a function of temperature between 17K and room temperature. At the temperature range between 200 and 290K the best fit to the experimental data was obtained assuming a dependence characteristic of adiabatic variable range hopping. At lower temperature the activation energy for the conductivity tends to zero. The results suggest that the conduction mechanism is adiabatic small polaron hopping, which switches to conduction in a polaron band at low temperatures

  9. Dilatant shear band formation and diagenesis in calcareous, arkosic sandstones, Vienna Basin (Austria)

    Science.gov (United States)

    Lommatzsch, Marco; Exner, Ulrike; Gier, Susanne; Grasemann, Bernhard

    2015-01-01

    The present study examines deformation bands in calcareous arkosic sands. The investigated units can be considered as an equivalent to the Matzen field in the Vienna Basin (Austria), which is one of the most productive oil reservoirs in central Europe. The outcrop exposes carbonate-free and carbonatic sediments of Badenian age separated by a normal fault. Carbonatic sediments in the hanging wall of the normal fault develop dilation bands with minor shear displacements (< 2 mm), whereas carbonate-free sediments in the footwall develop cataclastic shear bands with up to 70 cm displacement. The cataclastic shear bands show a permeability reduction up to 3 orders of magnitude and strong baffling effects in the vadose zone. Carbonatic dilation bands show a permeability reduction of 1-2 orders of magnitude and no baffling structures. We distinguished two types of deformation bands in the carbonatic units, which differ in deformation mechanisms, distribution and composition. Full-cemented bands form as dilation bands with an intense syn-kinematic calcite cementation, whereas the younger loose-cemented bands are dilatant shear bands cemented by patchy calcite and clay minerals. All analyzed bands are characterized by a porosity and permeability reduction caused by grain fracturing and cementation. The changed petrophysical properties and especially the porosity evolution are closely related to diagenetic processes driven by varying pore fluids in different diagenetic environments. The deformation band evolution and sealing capacity is controlled by the initial host rock composition. PMID:26300577

  10. Slip-band formation and dislocation kinetics in the stage I deformation of neutron-irradiated copper single crystals

    International Nuclear Information System (INIS)

    Kitajima, Sadakichi; Shinohara, Kazutoshi; Kutsuwada, Masanori

    1995-01-01

    The velocity of edge and screw dislocations moving in primary slip bands and the formation rate of primary slip bands were measured in stage I deformation of neutron-irradiated copper single crystals at different strain rates at room temperature using micro-cinematography and optical micrography. The average velocity of edge dislocations was larger at least by one order than that of screw ones, and that of screw dislocations did not depend so strongly on strain rate. The formation rate of primary slip bands was proportional to strain rate. From these results, it is concluded that (1) jogs produced on moving dislocations by cutting dislocation loops result in the difference in velocity between edge and screw dislocations and (2) the change in the density of mobile dislocations as well as velocity of dislocations is responsible for the change of plastic strain rate of a crystal. (author)

  11. Superconducting pairing of spin polarons in the t - J model

    International Nuclear Information System (INIS)

    Plakida, N.M.; Horsch, P.; Liechtenstein, A.; Oudovenko, V.S.

    1995-07-01

    A spin polaron model derived from the t - J model on a two-sublattice antiferromagnet is considered. The self-consistent Born approximation for the matrix Green functions for doped holes (spin polarons) and magnons is used to study temperature and doping dependence of the quasi-particle hole spectrum and superconducting pairing of two holes on different sublattices. A numerical solution of the self-consistent system of equations by the fast Fourier transformation method shows a strong renormalization of the quasi-particle hole spectrum due to spin fluctuations, and a singlet superconducting pairing of d-wave symmetry with maximal T c ∼ 0.01t around the hole concentration 0.25. We argue that the superconducting pairing of spin polarons for the model with strong electron correlations represents the mechanism of high-temperature superconductivity. (author). 26 refs, 10 figs

  12. Ni Isotope Signatures in Banded Iron Formations Before, During, and After the Great Oxidation Event

    Science.gov (United States)

    Wasylenki, L.; Wang, S.

    2016-12-01

    We have measured the Ni isotope compositions of banded iron formations (BIF) in an effort to test the hypothesis of Konhauser et al. that a decrease in supply of Ni to the Late Archean oceans may have triggered a decline in methanogen productivity [1,2]. These microorganisms are critically dependent on Ni, and their decline may have triggered a drop in atmospheric CH4 that allowed the first sustained rise of free O2 in the atmosphere at 2.4 Ga. While simultaneously considering other processes that may have controlled the Ni isotope composition of Precambrian seawater, and in turn the BIF, we are looking for a shift in δ60/58Ni over time that correlates with the decrease in BIF Ni/Fe ratios documented previously [1,2] and that possibly reflects a dramatic change in methanogen Ni status over that same time interval (2.7-2.4 Ga). Our preliminary results indicate that the ocean's Ni isotope composition has varied considerably over geologic time. Using results from an accompanying experimental study of Ni fractionation during incorporation into ferric oxyhydroxides/oxides, we can reconstruct the Ni isotope compositions of seawater from which BIF precipitated. We observe that Precambrian seawater was generally considerably enriched in light isotopes of Ni relative to modern seawater. So far we observe the widest range of δ60/58Ni values in those BIF samples aged 2.7-2.4 Ga, implying significant changes in the controls on δ60/58Ni in the Late Archean Eon and possibly much greater sensitivity of the biogeochemical cycle of Ni to perturbations in Ni sources, such as oxidative weathering of sulfides, input/output fluxes, or biological uptake. [1] Konhauser et al. (2009) Nature 458,750; [2] Konhauser et al. (2015) Astrobiology 15,804.

  13. Testing Timescales for Rhythms Recorded in the 2.5 Ga Banded Iron Formation of the Dales Gorge Member (Brockman Iron Formation, Hamersley Group, Australia)

    Science.gov (United States)

    Hinnov, L. A.; de Oliveira Carvalho Rodrigues, P.; Franco, D.

    2017-12-01

    The classic, Superior-type banded iron formation (BIF) of the Precambrian Dales Gorge Member (DGM) of the Brockman Iron Formation, Hamersley Basin, Western Australia consists of a succession of micro- (millimeter-scale) and meso- (centimeter to decimeter-scale) bands of primarily iron-silica chemical sediment alternations, separated into macro- (meter to decameter-scale) bands by shales (1). Here, we present a time-frequency analysis of a gray-scale scan of the DGM "type section core" Hole 47A with small contributions from Hole EC10 (1) to provide a comprehensive characterization of banding patterns and periodicity throughout the 140 m section. SHRIMP zircon ages (2) indicate that the DGM was deposited over approximately 30 myr during the Archean-Proterozoic transition just prior to the Great Oxidation Event. This suggests that the banding patterns recorded Milankovitch cycles, although with orbital-rotational parameters significantly different from present-day due to Earth's tidal dissipation and chaotic episodes in the Solar System since 2.5 Ga. Banding patterns change systematically within the formation in response to slowly varying environmental conditions, which have been interpreted previously to be related to sea level change and basin evolution (3). Researchers, including (2), have questioned the 30 myr duration, suggesting instead that the micro-bands may be annual in scale. This would indicate a much shorter duration of less than 150 kyr for the DGM. In an attempt to determine whether Milankovitch cycles could have generated the meso-band patterns, we present detailed studies of BIF0 and BIF12, which typify the marked changes in meso-banding along the section. Objective procedures are also applied, including ASM (4) and TIMEOPT (5) to test for a range of potential alternative timescales assuming orbital-rotational parameter values modeled for 2.5 Ga. References: (1) Trendall, A.K., Blockley, J.G., GSWA Ann. Rep. 1967, 48, 1968; (2) Trendall, A.K., et al

  14. Problems of linear electron (polaron) transport theory in semiconductors

    CERN Document Server

    Klinger, M I

    1979-01-01

    Problems of Linear Electron (Polaron) Transport Theory in Semiconductors summarizes and discusses the development of areas in electron transport theory in semiconductors, with emphasis on the fundamental aspects of the theory and the essential physical nature of the transport processes. The book is organized into three parts. Part I focuses on some general topics in the theory of transport phenomena: the general dynamical theory of linear transport in dissipative systems (Kubo formulae) and the phenomenological theory. Part II deals with the theory of polaron transport in a crystalline semicon

  15. A self-consistent theory of the magnetic polaron

    International Nuclear Information System (INIS)

    Marvakov, D.I.; Kuzemsky, A.L.; Vlahov, J.P.

    1984-10-01

    A finite temperature self-consistent theory of magnetic polaron in the s-f model of ferromagnetic semiconductors is developed. The calculations are based on the novel approach of the thermodynamic two-time Green function methods. This approach consists in the introduction of the ''irreducible'' Green functions (IGF) and derivation of the exact Dyson equation and exact self-energy operator. It is shown that IGF method gives a unified and natural approach for a calculation of the magnetic polaron states by taking explicitly into account the damping effects and finite lifetime. (author)

  16. Large Format Narrow Band High Throughput Optical Filters for 0.5-2.75 Project

    Data.gov (United States)

    National Aeronautics and Space Administration — One of the most efficient ways to create narrow band filter is the use of reflective Bragg gratings or which allow increasing of efficiency and decreasing of weight...

  17. Formation of systems of incompact bands parallel to the compression axis in the unconsolidated sedimentary rocks: A model

    Science.gov (United States)

    Mukhamediev, Sh. A.; Ul'Kin, D. A.

    2011-10-01

    Uniaxial compression of poorly lithified rocks leads to the formation of thin incompact layers (or bands, in the two-dimensional case) parallel to the compression axis, which are characterized by increased porosity. The standard model of the formation of such bands, as well as deformation bands of other types, associates them with the narrow zones of localization of plastic deformations. In the case of decompaction, it is assumed that transverse tensile deformations are localized within the band, which cause the band to dilate. Here, the formation of a band of localized deformations is treated as a loss-of-stability phenomenon. Based on observations, we propose a fundamentally different model of incompact bands formation, according to which the microdefects in sediment packing (pores) rather than the deformations are localized in the narrow zones. The localization of pores, which are initially randomly distributed in the medium, occurs as a result of their migration through the geomaterial. The migration and subsequent localization of pores are driven by a common mechanism, namely, a trend of a system to lower its total energy (small variations in total energy are equal to the increment of free energy minus the work of external forces). Migration of a single pore in a granular sedimentary rock is caused by the force f driving the defect. This force was introduced by J. Eshelby (1951; 1970). An important feature of our model is that the formation of an incompact band here does not have a sense of a loss of stability. Quite the contrary, the formation of incompact bands is treated as a gradual process spread over time. In this context, the origination of incompact band systems directly follows from our model itself, without any a priori assumptions postulating the existence of such systems and without any special tuning of the model parameters. Moreover, based on the proposed model, we can predict the incompact bands to always occur in the form of systems rather than

  18. Field investigation and spectral characterization of Banded Iron Formation, Odisha, India: Implications to hydration processes on Mars

    Science.gov (United States)

    Singh, M.; Singhal, J.; Rajesh, V. J.

    2015-10-01

    Banded iron formations are major rock units having hematite layers intermittent with silica rich layers and formed mainly by the sedimentary processes during Late-Archaean to Mid-Proterozoic time period. They found their significance as a major iron-ore deposits and the first terrestrial rock bodies with existing life signatures on Earth. Here, we propose Odisha BIFs as a probable analogue site to the martian layered hematite deposit and its implications in inferring the sedimentary processes,hydration and astrobiological activities on Mars. Hyperspectral analysis identifies the optimum bands for the identification of similar type of deposits on Mars. Odisha BIFs have been found well comparable with the existing analogue sites of Lake Superior and Carajas Formation, Brazil.

  19. Repulsive polarons and itinerant ferromagnetism in strongly polarized Fermi gases

    DEFF Research Database (Denmark)

    Massignan, Pietro; Bruun, Georg

    2011-01-01

    We analyze the properties of a single impurity immersed in a Fermi sea. At positive energy and scattering lengths, we show that the system possesses a well-defined but metastable excitation, the repulsive polaron, and we calculate its energy, quasiparticle residue and effective mass. From a therm...

  20. Transport through a vibrating quantum dot: Polaronic effects

    Czech Academy of Sciences Publication Activity Database

    Koch, T.; Loos, Jan; Alvermann, A.; Bishop, A. R.; Fehske, H.

    2010-01-01

    Roč. 220, č. 1 (2010), 012014/1-012014/9 ISSN 1742-6588 Institutional research plan: CEZ:AV0Z10100521 Keywords : quantum dot, * polaronic effects * low-temperature transport properties Subject RIV: BM - Solid Matter Physics ; Magnetism

  1. Numerical calculation of path integrals : The small-polaron model

    NARCIS (Netherlands)

    Raedt, Hans De; Lagendijk, Ad

    1983-01-01

    The thermodynamic properties of the small-polaron model are studied by means of a discrete version of the Feynman path-integral representation of the partition function. This lattice model describes a fermion interacting with a boson field. The bosons are treated analytically, the fermion

  2. Critical Quantum Fluctuations and Localization of the Small Polaron

    NARCIS (Netherlands)

    Raedt, Hans De; Lagendijk, Ad

    1982-01-01

    The first quantitative evidence of critical quantum fluctuations and superlocalization of the small polaron model in one, two, and three dimensions is presented. Starting from a discrete version of the Feynman path-integral representation of the partition function, the boson field is eliminated

  3. An acoustic analog for a quantum mechanical level-splitting route to band formation

    Science.gov (United States)

    D'Onofrio, Marissa; Crum, Mitchell; Hilbert, Shawn A.; Batelaan, Herman; Canalichio, Timothy; Bull, Tyler

    2016-11-01

    This paper explores band structure in a simple acoustic apparatus that acts as an analog to the quantum infinite square well with multiple delta-function perturbations. The apparatus can be used to visualize abstract quantum phenomena in a concrete and easily understandable way. It consists of regular sections of PVC pipes connected by variable aluminum diaphragms to allow coupling between the pipe sections. The equivalence between standing waves in the acoustic system and stationary states in the quantum system is examined for multiple-cavity situations. We show that the experimental results from the acoustic system and the analytic solutions of the quantum system demonstrate the same resonance structure. We also experimentally show that the acoustic system supports band structure and that the band width is dependent on the hole size of the diaphragms.

  4. Polarons and Mobile Impurities Near a Quantum Phase Transition

    Science.gov (United States)

    Shadkhoo, Shahriar

    This dissertation aims at improving the current understanding of the physics of mobile impurities in highly correlated liquid-like phases of matter. Impurity problems pose challenging and intricate questions in different realms of many-body physics. For instance, the problem of ''solvation'' of charged solutes in polar solvents, has been the subject of longstanding debates among chemical physicists. The significant role of quantum fluctuations of the solvent, as well as the break down of linear response theory, render the ordinary treatments intractable. Inspired by this complicated problem, we first attempt to understand the role of non-specific quantum fluctuations in the solvation process. To this end, we calculate the dynamic structure factor of a model polar liquid, using the classical Molecular Dynamics (MD) simulations. We verify the failure of linear response approximation in the vicinity of a hydrated electron, by comparing the outcomes of MD simulations with the predictions of linear response theory. This nonlinear behavior is associated with the pronounced peaks of the structure factor, which reflect the strong fluctuations of the local modes. A cavity picture is constructed based on heuristic arguments, which suggests that the electron, along with the surrounding polarization cloud, behave like a frozen sphere, for which the linear response theory is broken inside and valid outside. The inverse radius of the spherical region serves as a UV momentum cutoff for the linear response approximation to be applicable. The problem of mobile impurities in polar liquids can be also addressed in the framework of the ''polaron'' problem. Polaron is a quasiparticle that typically acquires an extended state at weak couplings, and crossovers to a self-trapped state at strong couplings. Using the analytical fits to the numerically obtained charge-charge structure factor, a phenomenological approach is proposed within the Leggett's influence functional formalism, which

  5. Measurements of electron avalanche formation time in W-band microwave air breakdown

    Science.gov (United States)

    Cook, Alan M.; Hummelt, Jason S.; Shapiro, Michael A.; Temkin, Richard J.

    2011-08-01

    We present measurements of formation times of electron avalanche ionization discharges induced by a focused 110 GHz millimeter-wave beam in atmospheric air. Discharges take place in a free volume of gas, with no nearby surfaces or objects. When the incident field amplitude is near the breakdown threshold for pulsed conditions, measured formation times are ˜0.1-2 μs over the pressure range 5-700 Torr. Combined with electric field breakdown threshold measurements, the formation time data shows the agreement of 110 GHz air breakdown with the similarity laws of gas discharges.

  6. Measurements of electron avalanche formation time in W-band microwave air breakdown

    International Nuclear Information System (INIS)

    Cook, Alan M.; Hummelt, Jason S.; Shapiro, Michael A.; Temkin, Richard J.

    2011-01-01

    We present measurements of formation times of electron avalanche ionization discharges induced by a focused 110 GHz millimeter-wave beam in atmospheric air. Discharges take place in a free volume of gas, with no nearby surfaces or objects. When the incident field amplitude is near the breakdown threshold for pulsed conditions, measured formation times are ∼0.1-2 μs over the pressure range 5-700 Torr. Combined with electric field breakdown threshold measurements, the formation time data shows the agreement of 110 GHz air breakdown with the similarity laws of gas discharges.

  7. Petrography and geochemistry of the Dales Gorge banded iron formation: Paragenetic sequence, source and implications for palaeo-ocean chemistry

    DEFF Research Database (Denmark)

    Pecoits, E.; Gingras, M. K.; Barley, M. E.

    2009-01-01

    Banded iron formations (BIFs) have long been considered marine chemical precipitates or, as more recently proposed, the result of episodic density flows. In this study, we examined the mineralogy, petrography and chemistry of the Dales Gorge BIF to evaluate the validity of these models. Microbands...... provenance. Nonetheless, when all the lithologies (i.e., source rocks, S and BIF macrobands) are evaluated together, continuous geochemical trends can be observed. This suggests that at least part of the precursor material of BIF macrobands was sourced from the same material that gave origin to the S...

  8. Charged Polaron Polaritons in an Organic Semiconductor Microcavity

    Science.gov (United States)

    Cheng, Chiao-Yu; Dhanker, Rijul; Gray, Christopher L.; Mukhopadhyay, Sukrit; Kennehan, Eric R.; Asbury, John B.; Sokolov, Anatoliy; Giebink, Noel C.

    2018-01-01

    We report strong coupling between light and polaron optical excitations in a doped organic semiconductor microcavity at room temperature. Codepositing MoO3 and the hole transport material 4, 4' -cyclohexylidenebis[N , N -bis(4-methylphenyl)benzenamine] introduces a large hole density with a narrow linewidth optical transition centered at 1.8 eV and an absorption coefficient exceeding 104 cm-1 . Coupling this transition to a Fabry-Pérot cavity mode yields upper and lower polaron polariton branches that are clearly resolved in angle-dependent reflectivity with a vacuum Rabi splitting ℏ ΩR>0.3 eV . This result establishes a path to electrically control polaritons in organic semiconductors and may lead to increased polariton-polariton Coulombic interactions that lower the threshold for nonlinear phenomena such as polariton condensation and lasing.

  9. Thermoelectric power of small polarons in magnetic semiconductors

    International Nuclear Information System (INIS)

    Liu, N.H.; Emin, D.

    1984-01-01

    The thermoelectric power (Seebeck coefficient) α of a small polaron in both ferromagnetic and antiferromagnetic semiconductors and insulators is calculated for the first time. In particular, we obtain the contribution to the Seebeck coefficient arising from exchange interactions between the severely localized carrier (i.e., small polaron) of charge q and the spins of the host lattice. In essence, we study the heat transported along with a carrier. This heat, the Peltier heat, Pi, is related to the Seebeck coefficient by the Kelvin relation: Pi = qTα, where T is the temperature. The heat per carrier is simply the product of the temperature and the change of the entropy of the system when a small polaron is added to it. The magnetic contribution to the Seebeck coefficient is therefore directly related to the change of the magnetic entropy of the system upon introduction of a charge carrier. We explicitly treat the intrasite and intersite exchange interactions between a small polaron and the spins of a spin-1/2 system. These magnetic interactions produce two competing contributions to the Seebeck coefficient. First, adding the carrier tends to provide extra spin freedom (e.g., spin up or spin down of the carrier). This effect augments the entropy of the system, thereby producing a positive contribution to the Peltier heat. Second, however, the additional exchange between the carrier and the sites about it enhances the exchange binding among these sites. This generally reduces the energetically allowable spin configurations. The concomitant reduction of the system's entropy provides a negative contribution to the Peltier heat. At the highest of temperatures, when kT exceeds the intrasite exchange energy, the first effect dominates. Then, the Peltier heat is simply augmented by kT ln2

  10. Absolute instability of polaron mode in semiconductor magnetoplasma

    Science.gov (United States)

    Paliwal, Ayushi; Dubey, Swati; Ghosh, S.

    2018-01-01

    Using coupled mode theory under hydrodynamic regime, a compact dispersion relation is derived for polaron mode in semiconductor magnetoplasma. The propagation and amplification characteristics of the wave are explored in detail. The analysis deals with the behaviour of anomalous threshold and amplification derived from dispersion relation, as function of external parameters like doping concentration and applied magnetic field. The results of this investigation are hoped to be useful in understanding electron-longitudinal optical phonon interplay in polar n-type semiconductor plasmas under the influence of coupled collective cyclotron excitations. The best results in terms of smaller threshold and higher gain of polaron mode could be achieved by choosing moderate doping concentration in the medium at higher magnetic field. For numerical appreciation of the results, relevant data of III-V n-GaAs compound semiconductor at 77 K is used. Present study provides a qualitative picture of polaron mode in magnetized n-type polar semiconductor medium duly shined by a CO2 laser.

  11. Non-linear polaronic conduction in magnetite nanowires

    International Nuclear Information System (INIS)

    Singh, Pooja; Rout, P.K.; Husale, Sudhir; Gupta, Anurag; Singh, Manju; Rakshit, R.K.; Dogra, Anjana

    2016-01-01

    We report the temperature dependent current (I) – voltage (V) characteristics of Fe 3 O 4 nanowires with varying width (w) of 132, 358, and 709 nm. While the widest nanowire (w=709 nm) shows ohmic I (V) curves for all temperatures, those for w=132 and 358 nm show nonlinearity, which can be expressed by a combination of linear (V) and cubic (V 3 ) terms. The behaviour of conductance (linear bias component of current) and non-linearity in these nanowires is related to small polaron hopping related conduction. Moreover, we observed an anomalously large hopping lengths, which may be related to the size of percolation cluster and/or antiphase domain. Our study presents first experimental evidence for such non-linear polaronic conduction in magnetite nanowires. - Highlights: • Temperature dependent I–V measurements of FIB fabricated magnetite nanowires. • Small polaron based conduction in non-linear I–V curves. • Anomalously large hopping lengths due to percolation effect and/or antiphase domains.

  12. Axial-Compressive Behavior, Including Kink-Band Formation and Propagation, of Single p-Phenylene Terephthalamide (PPTA Fibers

    Directory of Open Access Journals (Sweden)

    M. Grujicic

    2013-01-01

    Full Text Available The mechanical response of p-phenylene terephthalamide (PPTA single fibers when subjected to uniaxial compression is investigated computationally using coarse-grained molecular statics/dynamics methods. In order to construct the coarse-grained PPTA model (specifically, in order to define the nature of the coarse-grained particles/beads and to parameterize various components of the bead/bead force-field functions, the results of an all-atom molecular-level computational investigation are used. In addition, the microstructure/topology of the fiber core, consisting of a number of coaxial crystalline fibrils, is taken into account. Also, following our prior work, various PPTA crystallographic/topological defects are introduced into the model (at concentrations consistent with the prototypical PPTA synthesis/processing conditions. The analysis carried out clearly revealed (a formation of the kink bands during axial compression; (b the role of defects in promoting the formation of kink bands; (c the stimulating effects of some defects on the fiber-fibrillation process; and (d the detrimental effect of the prior compression, associated with fiber fibrillation, on the residual longitudinal-tensile strength of the PPTA fibers.

  13. Source heterogeneity for the major components of ~3.7 Ga banded iron formations (Isua Greenstone Belt, Western Greenland)

    DEFF Research Database (Denmark)

    Frei, Robert; Polat, Ali

    2006-01-01

    We report trace element, samarium (Sm)-neodymium (Nd) and lead (Pb) isotopic data for individual micro-and mesobands of the Earth's oldest Banded Iron Formation (BIF) from the  3.7-3.8 Ga Isua Greenstone Belt (IGB, West Greenland) in an attempt to contribute to the characterization of the deposit......We report trace element, samarium (Sm)-neodymium (Nd) and lead (Pb) isotopic data for individual micro-and mesobands of the Earth's oldest Banded Iron Formation (BIF) from the  3.7-3.8 Ga Isua Greenstone Belt (IGB, West Greenland) in an attempt to contribute to the characterization......-Nd isotopic relations on a layer-by-layer basis point to two REE sources controlling the back-arc basin depositional environment of the BIF, one being seafloor-vented hydrothermal fluids (eNd (3.7 Ga)   + 3.1), the other being ambient surface seawater which reached its composition by erosion of parts...... of the protocrustal landmass (eNd(3.7 Ga)   + 1.6). The validity of two different and periodically interacting water masses (an essentially two-component mixing system) in the deposition of alternating iron- and silica-rich layers is also reflected by systematic trends in germanium (Ge)/silicon (Si) ratios...

  14. Diagnostics of fast formation of distributed plasma discharges using X-band microwaves

    Energy Technology Data Exchange (ETDEWEB)

    Xiang, X., E-mail: xxiang3@wisc.edu; Kupczyk, B.; Booske, J.; Scharer, J. [Department of Electrical and Computer Engineering, University of Wisconsin, Madison, Wisconsin 53705 (United States)

    2014-02-14

    We present measurements of high power (25.7 kW), pulsed (800 ns), X-band (9.382 GHz) microwave breakdown plasmas, including reflected power measurements, mixer reflected amplitude and phase measurements, optical emission spectroscopy (OES) measurements, and an analysis that estimates the average electron density and electron temperature. In addition, a six-region, 1-D model was used to determine plasma parameters and compare with the experimental results. The experimental results show that using a 43 Hz repetition rate with an 800 ns pulse, fast (<300 ns) breakdown occurs in neon measured between 50 Torr and 250 Torr, producing plasma that lasts for over 7 μs. It also leads to large microwave reflections (70%) and an on-axis transmission attenuation of −15 dB. Moreover, a comparison between a 1-D model and mixer measurements shows that at 100 Torr, the neon plasma electron density peaked at 2 × 10{sup 12} cm{sup −3}, and the electron temperature peaked at 2.5 eV assuming a Maxwellian distribution. The addition of 2% Ar in Ne reduced the breakdown time and allowed OES measurements to determine the effective electron temperature. OES measurements of mixed (Ne/Ar: 98/2) argon line ratios (420.1 nm/419.8 nm) were used to determine the average effective electron temperature T{sub e(eff)} = 1.2 eV, averaged over the entire 7μs plasma lifetime. They indicate that the electron energy distribution was not Maxwellian but, instead, tended towards a Druyvesteyn character.

  15. Asymptotic dependence of Gross–Tulub polaron ground-state energy in the strong coupling region

    Directory of Open Access Journals (Sweden)

    N.I. Kashirina

    2017-12-01

    Full Text Available The properties of translationally invariant polaron functional have been investigated in the region of strong and extremely strong coupling. It has been shown that the Gross–Tulub polaron functional obtained earlier using the methods of field theory was derived only for the region , where is the Fröhlich constant of the electron-phonon coupling. Various representations of exact and approximate polaron functionals have been considered. Asymptotic dependences of the polaron energy have been obtained using a functional extending the Gross–Tulub functional to the region of extremely strong coupling. The asymptotic dependence of polaron energies for an extremely strong coupling are (for the one-parameter variational function fk, and (for a two-parameter function . It has been shown that the virial theorem 1:3:4 holds for the two-parameter function . Minimization of the approximate functional obtained by expanding the exact Gross–Tulub functional in a series on leads to a quadratic dependence of the polaron energy. This approximation is justified for . For a two-parameter function , the corresponding dependence has the form . However, the use of approximate functionals, in contrast to the strict variational procedure, when the exact polaron functional varies, does not guarantee obtaining the upper limit for the polaron energy.

  16. Diagrammatic Monte Carlo method as applied to the polaron problem

    International Nuclear Information System (INIS)

    Mishchenko, A.S.

    2005-01-01

    Exact numerical solution methods for the problem of a few particles interacting with one another and with several bosonic excitation modes are presented. The diagrammatic Monte Carlo method allows the exact calculation of the Green function, and the stochastic optimization technique provides an analytic continuation. Results unobtainable by conventional methods are discussed, including the properties of excited states in the self-trapping phenomenon, the optical spectra of polarons in all coupling regimes, the validity analysis of the exciton models, and the photoemission spectra of a phonon-coupled hole [ru

  17. Peltier heat of a small polaron in a magnetic semiconductor

    International Nuclear Information System (INIS)

    Liu, N.H.; Emin, D.

    1985-01-01

    For the first time the heat transported with a small polaron in both antiferromagnetic and ferromagnetic semiconductors is calculated. This heat, the Peltier heat, π, is obtained from the change of the entropy of the total system upon introduction of a charge carrier. We explicitly consider both the intrasite and intersite exchange interactions between a small polaron and the interacting spins of a spin-1/2 magnet. There are two competing magnetic contributions to the Peltier heat. First, adding the carrier increases the spin entropy of the system. This provides a positive contribution to π. Second, the exchange between the carrier and the sites about it enhances the exchange binding between these sites. This reduces the energetically allowable spin configurations and provides a negative contribution to π. At extremely high temperatures when kT exceeds the intrasite exchange energy, the first effect dominates. Then π is simply augmented by kT ln 2. However, well below the magnetic transition temperature the second effect dominates. In the experimentally accessible range between these limits both effects are comparable and sizable. The net magnetic contribution to the Peltier heat rises with temperature. Thus, a carrier's interactions with its magnetic environment produces a significant and distinctive contribution to its Peltier heat

  18. Peltier heat of a small polaron in a magnetic semiconductor

    International Nuclear Information System (INIS)

    Liu, N.L.H.; Emin, D.

    1984-01-01

    The heat transported with a small polaron in both antiferromagnetic and ferromagnetic semiconductors is calculated. This heat, the Peltier heat, π, is obtained from the change of the entropy of the total system upon introduction of a charge carrier. We explicitly consider both the intrasite and intersite exchange interactions between a small polaron and the interacting spins of a spin-1/2 magnet. There are two competing magnetic contributions to the Peltier heat. First, adding the carrier increases the spin entropy of the system. This provides a positive contribution to π. Second, the exchange between the carrier and the sites about it enhances the exchange binding between these sites. This reduces the energetically allowable spin configurations and provides a negative contribution to π. At extremely high temperature when kT exceeds the intrasite exchange energy, the first effect dominates. Then π is simply augmented by kTln2. However, well below the magnetic transition temperature the second effect dominates. In the experimentally accessible range between these limits both effects are comparable and sizable. The net magnetic contribution to the Peltier heat rises with temperature. Thus, a carrier's interactions with its magnetic environment produces a significant and distinctive contribution to its Peltier heat

  19. Evidence for polaron conduction in nanostructured manganese ferrite

    International Nuclear Information System (INIS)

    Gopalan, E Veena; Anantharaman, M R; Malini, K A; Saravanan, S; Kumar, D Sakthi; Yoshida, Yasuhiko

    2008-01-01

    Nanoparticles of manganese ferrite were prepared by the chemical co-precipitation technique. The dielectric parameters, namely, real and imaginary dielectric permittivity (ε' and ε-prime), ac conductivity (σ ac ) and dielectric loss tangent (tanδ), were measured in the frequency range of 100 kHz-8 MHz at different temperatures. The variations of dielectric dispersion (ε') and dielectric absorption (ε-prime) with frequency and temperature were also investigated. The variation of dielectric permittivity with frequency and temperature followed the Maxwell-Wagner model based on interfacial polarization in consonance with Koops phenomenological theory. The dielectric loss tangent and hence ε-prime exhibited a relaxation at certain frequencies and at relatively higher temperatures. The dispersion of dielectric permittivity and broadening of the dielectric absorption suggest the possibility of a distribution of relaxation time and the existence of multiple equilibrium states in manganese ferrite. The activation energy estimated from the dielectric relaxation is found to be high and is characteristic of polaron conduction in the nanosized manganese ferrite. The ac conductivity followed a power law dependence σ ac = Bω n typical of charge transport assisted by a hopping or tunnelling process. The observed minimum in the temperature dependence of the frequency exponent n strongly suggests that tunnelling of the large polarons is the dominant transport process

  20. The role of deep acceptor centers in the oxidation of acceptor-doped wide-band-gap perovskites ABO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Putilov, L.P., E-mail: lev.putilov@gmail.com; Tsidilkovski, V.I.

    2017-03-15

    The impact of deep acceptor centers on defect thermodynamics and oxidation of wide-band-gap acceptor-doped perovskites without mixed-valence cations is studied. These deep centers are formed by the acceptor-bound small hole polarons whose stabilization energy can be high enough (significantly higher than the hole-acceptor Coulomb interaction energy). It is shown that the oxidation enthalpy ΔH{sub ox} of oxide is determined by the energy ε{sub A} of acceptor-bound states along with the formation energy E{sub V} of oxygen vacancies. The oxidation reaction is demonstrated to be either endothermic or exothermic, and the regions of ε{sub A} and E{sub V} values corresponding to the positive or negative ΔH{sub ox} are determined. The contribution of acceptor-bound holes to the defect thermodynamics strongly depends on the acceptor states depth ε{sub A}: it becomes negligible at ε{sub A} less than a certain value (at which the acceptor levels are still deep). With increasing ε{sub A}, the concentration of acceptor-bound small hole polarons can reach the values comparable to the dopant content. The results are illustrated with the acceptor-doped BaZrO{sub 3} as an example. It is shown that the experimental data on the bulk hole conductivity of barium zirconate can be described both in the band transport model and in the model of hopping small polarons localized on oxygen ions away from the acceptor centers. Depending on the ε{sub A} magnitude, the oxidation reaction can be either endothermic or exothermic for both mobility mechanisms.

  1. Updating the Geologic Barcodes for South China: Discovery of Late Archean Banded Iron Formations in the Yangtze Craton.

    Science.gov (United States)

    Ye, Hui; Wu, Chang-Zhi; Yang, Tao; Santosh, M; Yao, Xi-Zhu; Gao, Bing-Fei; Wang, Xiao-Lei; Li, Weiqiang

    2017-11-08

    Banded iron formations (BIFs) in Archean cratons provide important "geologic barcodes" for the global correlation of Precambrian sedimentary records. Here we report the first finding of late Archean BIFs from the Yangtze Craton, one of largest Precambrian blocks in East Asia with an evolutionary history of over 3.3 Ga. The Yingshan iron deposit at the northeastern margin of the Yangtze Craton, displays typical features of BIF, including: (i) alternating Si-rich and Fe-rich bands at sub-mm to meter scales; (ii) high SiO 2  + Fe 2 O 3total contents (average 90.6 wt.%) and Fe/Ti ratios (average 489); (iii) relative enrichment of heavy rare earth elements and positive Eu anomalies (average 1.42); (iv) and sedimentary Fe isotope compositions (δ 56 Fe IRMM-014 as low as -0.36‰). The depositional age of the BIF is constrained at ~2464 ± 24 Ma based on U-Pb dating of zircon grains from a migmatite sample of a volcanic protolith that conformably overlied the Yingshan BIF. The BIF was intruded by Neoproterozoic (805.9 ± 4.7 Ma) granitoids that are unique in the Yangtze Craton but absent in the North China Craton to the north. The discovery of the Yingshan BIF provides new constraints for the tectonic evolution of the Yangtze Craton and has important implications in the reconstruction of Pre-Nuna/Columbia supercontinent configurations.

  2. Large polaron tunneling, magnetic and impedance analysis of magnesium ferrite nanocrystallite

    Energy Technology Data Exchange (ETDEWEB)

    Mahato, Dev K., E-mail: drdevkumar@yahoo.com [Department of Physics, National Institute of Technology Patna, Patna 800 005 (India); Majumder, Sumit [Department of Physics, Jadavpur University, Kolkata 700032 (India); Surface Physics and Material Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India); Banerjee, S. [Surface Physics and Material Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India)

    2017-08-15

    Graphical abstract: The diffraction peaks corresponding to the planes (111), (220), (311), (222), (400), (422), (511), (440), (620), (533) and (444) provide a clear evidence for the formation of spinel structure of the ferrites. The lattice parameter ‘a’ determined as 8.392 Å matches well with JCPDS (73-2410) file for MgFe{sub 2}O{sub 4.} The volume of the unit cell is 591.012 Å{sup 3}. The crystallite size of the synthesized powder estimated from X-ray peak broadening of (311) highest intensity diffraction peak using Scherer formula was 56.4 nm. - Highlights: • Both the grain and grain boundaries contribution to conductivity of the Mg-ferrite has been observed. • Polydispersive nature of the material is checked using Cole – Cole relation. • The ac conductivity of magnesium ferrite followed σ{sub ac} ∝ ω{sup n} dependence. • The variation of the exponent ‘n’ with temperature suggests that overlapping large polaron tunnelling is the dominant conduction mechanism. • The superparamagnetic behavior of this Mg-ferrite has been observed for sample S1 annealed at 500 °C. - Abstract: Single phase MgFe{sub 2}O{sub 4} (MFO) ferrite was prepared through sol-gel auto-combustion route. The Rietveld analysis of X-ray patterns reveals that our samples are single phase. The increase in average particle size with annealing temperature and formation of nanoparticle agglomerates is observed in MgFe{sub 2}O{sub 4}. The structural morphology of the nanoparticles is studied using Scanning Electron Microscopy (SEM). Formation of spinel structure is confirmed using Fourier transform infrared spectroscopy (FTIR). The Zero-Field-Cooled (ZFC) and Field-Cooled (FC) magnetization measurements show the maximum irreversibility at 700 °C annealing temperature. The formation of a maximum at blocking temperature, T{sub B}∼ 180 K for sample annealed at 500 °C in the ZFC curve shows the superparamagnetic behavior of the sample. The increase of saturation magnetism (M

  3. Method of intermediate problems in the Fröhlich polaron model

    Directory of Open Access Journals (Sweden)

    A.V. Soldatov

    2009-01-01

    Full Text Available Method of intermediate problems in the theory of linear semi-bounded self-adjoint operators on rigged Hilbert space was applied to the investigation of the ground state energy of the Fröhlich polaron model. It was shown that various infinite sequences of non-decreasing improvable lower bound estimates for the polaron ground state energy can be derived for arbitrary values of the electron-phonon interaction constant. The proposed approach allows for explicit numerical evaluation of the thus obtained lower bound estimates at all orders and can be straightforwardly generalized for investigation of the low-lying branch of the slow-moving polaron excitation energy spectral curve adjacent to the ground state energy of the polaron at rest. In conjunction with numerous, already derived by multitudinous methods, well-known upper bound estimates for the energy spectral curve of the Fröhlich polaron as a function of the electron-phonon interaction constant and the polaron total momentum, the aforesaid improvable lower bound estimates might provide one with virtually precise magnitude for the energy of the slow-moving polaron.

  4. Banded Iron Formations

    DEFF Research Database (Denmark)

    Posth, Nicole R; Konhauser, Kurt O; Kappler, Andreas

    2011-01-01

    Sedimentary deposits of alternating iron-rich (20–40% Fe) and iron-poor, siliceous (40–50% SiO2) mineral layers that primarily precipitated throughout much of the late Archean (2.7–2.5 Ga) and Paleoproterozoic (2.5– 1.8 Ga), but then remerged in the Neoproterozoic (0.8 Ga).......Sedimentary deposits of alternating iron-rich (20–40% Fe) and iron-poor, siliceous (40–50% SiO2) mineral layers that primarily precipitated throughout much of the late Archean (2.7–2.5 Ga) and Paleoproterozoic (2.5– 1.8 Ga), but then remerged in the Neoproterozoic (0.8 Ga)....

  5. Banded Iron Formations

    DEFF Research Database (Denmark)

    Posth, Nicole R; Konhauser, Kurt O; Kappler, Andreas

    2011-01-01

    Sedimentary deposits of alternating iron-rich (20–40% Fe) and iron-poor, siliceous (40–50% SiO2) mineral layers that primarily precipitated throughout much of the late Archean (2.7–2.5 Ga) and Paleoproterozoic (2.5– 1.8 Ga), but then remerged in the Neoproterozoic (0.8 Ga)....

  6. Spin polaron in two-dimensional antiferromagnetics - from local singlet to compound quasi-particle

    CERN Document Server

    Barabanov, A F; Belemuk, A M

    2002-01-01

    The basic theoretical concepts, related to the spin polaron scenario for the charge excitations in the two-dimensional antiferromagnetics, are presented. The distinctive peculiarity of the developed approach consists in consideration of the local polaron as the zero approximation for the quasi-particles. On the following stage this excitation is coated into the antiferromagnetic spin waves and the radius intermediate polaron is formed. The method makes it possible to continuously describe the transition from the zero temperatures to the finite ones and to consider the wide doping range. The above approach explains basic results of the ARPES-experiments in the CuO sub 2 plane

  7. Bound magnetic polaron driven low-temperature ferromagnetism in Cu{sub 1−x}Mn{sub x}O compounds

    Energy Technology Data Exchange (ETDEWEB)

    Cai, J.Z.; Li, L.; Wang, S.; Zou, W.Q.; Wu, X.S., E-mail: xswu@nju.edu.cn; Zhang, F.M., E-mail: fmzhang@nju.edu.cn

    2013-09-01

    Partial Mn atoms have been confirmed to enter the CuO lattice and form the Cu{sub 1−x}Mn{sub x}O compounds in the case of doping with 0≤x≤0.2 by the sol–gel method. With increasing Mn content, magnetism is observed. The magnetic critical transition temperature increases with enhanced magnetism, which obeys the bound magnetic polaron theory. The electronic transportation shows an insulating behavior as the band-gap decreases. Our results may indicate that CuO may be used as a candidate of magnetic semiconductor.

  8. Direct Imaging of the Water Snow Line at the Time of Planet Formation using Two ALMA Continuum Bands

    Science.gov (United States)

    Banzatti, A.; Pinilla, P.; Ricci, L.; Pontoppidan, K. M.; Birnstiel, T.; Ciesla, F.

    2015-12-01

    Molecular snow lines in protoplanetary disks have been studied theoretically for decades because of their importance in shaping planetary architectures and compositions. The water snow line lies in the planet formation region at ≲10 AU, and so far its location has been estimated only indirectly from spatially unresolved spectroscopy. This work presents a proof-of-concept method to directly image the water snow line in protoplanetary disks through its physical and chemical imprint on the local dust properties. We adopt a physical disk model that includes dust coagulation, fragmentation, drift, and a change in fragmentation velocities of a factor of 10 between dry silicates and icy grains as found by laboratory work. We find that the presence of a water snow line leads to a sharp discontinuity in the radial profile of the dust emission spectral index αmm due to replenishment of small grains through fragmentation. We use the ALMA simulator to demonstrate that this effect can be observed in protoplanetary disks using spatially resolved ALMA images in two continuum bands. We explore the model dependence on the disk viscosity and find that the spectral index reveals the water snow line for a wide range of conditions, with opposite trends when the emission is optically thin rather than thick. If the disk viscosity is low (αvisc structure with a minimum at αmm ˜ 2 in the optically thick regime, possibly similar to what has been measured with ALMA in the innermost region of the HL Tau disk.

  9. DFT+U study of polaronic conduction in Li2O2 and Li2CO3

    DEFF Research Database (Denmark)

    García Lastra, Juan Maria; Myrdal, J.S.G.; Christensen, Rune

    2013-01-01

    The main discharge products formed at the cathode of nonaqueous Li-air batteries are known to be Li2O2 and residual Li2CO3. Recent experiments indicate that the charge transport through these materials is the main limiting factor for the battery performance. It has been also shown that the perfor......The main discharge products formed at the cathode of nonaqueous Li-air batteries are known to be Li2O2 and residual Li2CO3. Recent experiments indicate that the charge transport through these materials is the main limiting factor for the battery performance. It has been also shown...... that the performance of the battery decreases drastically when the amount of Li2CO3 at the cathode increases with respect to Li2O2. In this work, we study the formation and transport of hole and electron polarons in Li2O2 and Li2CO3 using density functional theory (DFT) within the PBE+U approximation. For both...... materials, we find that the formation of polarons (both hole and electron) is stabilized with respect to the delocalized states for all physically relevant values of U. We find a much higher mobility for hole polarons than for the electron polarons, and we show that the poor charge transport in Li2CO3...

  10. Thyroid Hormone-Dependent Formation of a Subcortical Band Heterotopia (SBH) in the Neonatal Brain is not Exacerbated Under Conditions of Low Dietary Iron

    Science.gov (United States)

    Thyroid hormones (TH) are critical for brain development. Modest TH insufficiency in pregnant rats induced by propylthiouracil (PTU) results in formation of a structural abnormality, a subcortical band heterotopia (SBH), in brains of offspring. PTU reduces TH by inhibiting the s...

  11. Preservation of carbohydrates through sulfurization in a Jurassic euxinic shelf sea: Examination of the Blackstone Band TOC-cycle in the Kimmeridge Clay Formation, UK

    NARCIS (Netherlands)

    Dongen, B.E. van; Schouten, S.; Sinninghe Damsté, J.S.

    2006-01-01

    A complete total organic carbon (TOC) cycle in the Upper Jurassic Kimmeridge Clay Formation (KCF) comprising the extremely TOC-rich (34%) Blackstone Band was studied to investigate the controlling factors on TOC accumulation. Compared with the under- and overlying strata, TOC in the Blackstone

  12. Stability of the two-dimensional Fermi polaron

    Science.gov (United States)

    Griesemer, Marcel; Linden, Ulrich

    2018-02-01

    A system composed of an ideal gas of N fermions interacting with an impurity particle in two space dimensions is considered. The interaction between impurity and fermions is given in terms of two-body point interactions whose strength is determined by the two-body binding energy, which is a free parameter of the model. If the mass of the impurity is 1.225 times larger than the mass of a fermion, it is shown that the energy is bounded below uniformly in the number N of fermions. This result improves previous, N-dependent lower bounds, and it complements a recent, similar bound for the Fermi polaron in three space dimensions.

  13. Diagrammatic Monte Carlo method as applied to the polaron problems

    International Nuclear Information System (INIS)

    Mishchenko, Andrei S

    2005-01-01

    Numerical methods whereby exact solutions to the problem of a few particles interacting with one another and with several bosonic excitation branches are presented. The diagrammatic Monte Carlo method allows the exact calculation of the Matsubara Green function, and the stochastic optimization technique provides an approximation-free analytic continuation. In this review, results unobtainable by conventional methods are discussed, including the properties of excited states in the self-trapping phenomenon, the optical spectra of polarons in all coupling regimes, the validity range analysis of the Frenkel and Wannier approximations relevant to the exciton, and the peculiarities of photoemission spectra of a lattice-coupled hole in a Mott insulator. (reviews of topical problems)

  14. Polarons induced electronic transport, dielectric relaxation and magnetodielectric coupling in spin frustrated Ba{sub 2}FeWO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Pezhumkattil Palakkal, Jasnamol [Academy of Scientific and Innovative Research (AcSIR), CSIR—National Institute for Interdisciplinary Science and Technology (CSIR-NIIST) Campus, Trivandrum 695 019 (India); Materials Science and Technology Division, National Institute for Interdisciplinary Science and Technology, CSIR, Trivandrum 695 019 (India); Lekshmi, P. Neenu; Thomas, Senoy [Materials Science and Technology Division, National Institute for Interdisciplinary Science and Technology, CSIR, Trivandrum 695 019 (India); Valant, Matjaz [Materials Research Laboratory, University of Nova Gorica, Nova Gorica 5000 (Slovenia); Suresh, K.G. [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400 076 (India); Varma, Manoj Raama, E-mail: manoj@niist.res.in [Academy of Scientific and Innovative Research (AcSIR), CSIR—National Institute for Interdisciplinary Science and Technology (CSIR-NIIST) Campus, Trivandrum 695 019 (India); Materials Science and Technology Division, National Institute for Interdisciplinary Science and Technology, CSIR, Trivandrum 695 019 (India)

    2016-04-15

    Highlights: • Ordered double perovskite Ba{sub 2}FeWO{sub 6} synthesized in reducing atmosphere possess a tetragonal I4/m crystal structure with mixed valent Fe/W cations. • Ba{sub 2}FeWO{sub 6} has an antiferromagnetic structure with T{sub N} at 19 K. • Insulating Ba{sub 2}FeWO{sub 6} shows different conducting mechanisms at different temperature regions and dielectric relaxation. • The polarons invoked by the mixed valence state of cations and their disordered arrangements are solely responsible for the various physical phenomena observed in Ba{sub 2}FeWO{sub 6}. - Abstract: Mixed valent double perovskite Ba{sub 2}FeWO{sub 6}, with tetragonal crystal structure, synthesized in a highly controlled reducing atmosphere, shows antiferromagnetic transition at T{sub N} = 19 K. A cluster glass-like transition is observed around 30 K arising from the competing interactions between inhomogeneous magnetic states. The structural distortion leads to the formation of polarons that are not contributing to DC conduction below charge ordering temperature, T{sub CO} = 279 K. Above T{sub CO}, small polarons will start to hop by exploiting thermal energy and participate in the conduction mechanism. The polarons are also responsible for the dielectric relaxor behavior, in which the dielectric relaxation time follows non-linearity in temperature as proposed by Fulcher. The material also exhibits a small room temperature magnetoresistance of 1.7% at 90 kOe. An intrinsic magnetodielectric coupling of ∼4% near room temperature and at lower temperatures, as well as an extrinsic magnetodielectric coupling change from +4% to −6% at around 210 K are reported.

  15. Polarons and excitons in insulators: insight from computer simulations

    Science.gov (United States)

    Shluger, Alexander

    2010-03-01

    Localization of electrons and holes as well as excitons in insulators is a ubiquitous phenomenon which controls carrier mobility, luminescence and radiation damage of many materials. When such localization takes place in a perfect lattice it is called self-trapping, however in many cases it is facilitated by perturbation induced by intrinsic defects and impurities. Whatever the mechanism, it is hard to prove experimentally and especially theoretically. I will first review briefly the established models of self-trapped polarons and excitons (STE) in alkali halides and cubic oxides and will demonstrate how they are linked to the mechanisms of photo-induced desorption of these materials [1]. I will then discuss the results of our modeling, which extend these models further to more complex oxides forming so called electrides -- materials where electrons serve as anions [2], and to a qualitatively new type of electron trapping at grain boundaries in polycrystalline materials with negative electron affinity [3]. Combining periodic and embedded cluster methods we can explain and sometimes predict the properties of polarons and excitons in a range of insulators, such as amorphous SiO2 [4], and polycrystalline HfO2 [5] and HfSiO4. I will discuss the applicability of different techniques to studying localization problems in insulators and will compare the predictions of periodic plane wave and embedded cluster DFT calculations. [4pt] [1] W. P. Hess, et al. J. Phys. Chem. B, 109, 19563 (2005) [0pt] [2] P. V. Sushko et al. J. Amer. Chem. Soc., 129, 942 (2007) [0pt] [3] K. P. McKenna and A. L. Shluger, Nature Materials, 7, 859 (2008) [0pt] [4] A. V. Kimmel, et al. J. Non-Cryst. Sol., 353, 599 (2007) [0pt] [5] D. Munoz Ramo, et al. Phys. Rev. Lett. 99, 155504 (2007)

  16. Neutral impurities in a Bose-Einstein condensate for simulation of the Froehlich-polaron

    Energy Technology Data Exchange (ETDEWEB)

    Hohmann, Michael; Kindermann, Farina; Gaenger, Benjamin; Lausch, Tobias [University of Kaiserslautern, Department of Physics and Research Center OPTIMAS, Kaiserslautern (Germany); Mayer, Daniel; Schmidt, Felix; Widera, Artur [University of Kaiserslautern, Department of Physics and Research Center OPTIMAS, Kaiserslautern (Germany); Graduate School Materials Science in Mainz, Kaiserslautern (Germany)

    2015-12-15

    We present an experimental system to study the Bose polaron by immersion of single, well-controllable neutral Cs impurities into a Rb Bose-Einstein condensate (BEC). We show that, by proper optical traps, independent control over impurity and BEC allows for precision relative positioning of the two sub-systems as well as for dynamical studies and independent read-out. We furthermore estimate that measuring the polaron binding energy of Froehlich-type Bose polarons in the low and intermediate coupling regime is feasible with our experimental constraints and limitations discussed, and we outline how a parameter regime can be reached to characterize differences between Froehlich and Bose-polaron in the strong coupling regime. (orig.)

  17. Comparative analysis of magnetic resonance in the polaron pair recombination and the triplet exciton-polaron quenching models

    Science.gov (United States)

    Mkhitaryan, V. V.; Danilović, D.; Hippola, C.; Raikh, M. E.; Shinar, J.

    2018-01-01

    We present a comparative theoretical study of magnetic resonance within the polaron pair recombination (PPR) and the triplet exciton-polaron quenching (TPQ) models. Both models have been invoked to interpret the photoluminescence detected magnetic resonance (PLDMR) results in π -conjugated materials and devices. We show that resonance line shapes calculated within the two models differ dramatically in several regards. First, in the PPR model, the line shape exhibits unusual behavior upon increasing the microwave power: it evolves from fully positive at weak power to fully negative at strong power. In contrast, in the TPQ model, the PLDMR is completely positive, showing a monotonic saturation. Second, the two models predict different dependencies of the resonance signal on the photoexcitation power, PL. At low PL, the resonance amplitude Δ I /I is ∝PL within the PPR model, while it is ∝PL2 crossing over to PL3 within the TPQ model. On the physical level, the differences stem from different underlying spin dynamics. Most prominently, a negative resonance within the PPR model has its origin in the microwave-induced spin-Dicke effect, leading to the resonant quenching of photoluminescence. The spin-Dicke effect results from the spin-selective recombination, leading to a highly correlated precession of the on-resonance pair partners under the strong microwave power. This effect is not relevant for TPQ mechanism, where the strong zero-field splitting renders the majority of triplets off resonance. On the technical level, the analytical evaluation of the line shapes for the two models is enabled by the fact that these shapes can be expressed via the eigenvalues of a complex Hamiltonian. This bypasses the necessity of solving the much larger complex linear system of the stochastic Liouville equations. Our findings pave the way towards a reliable discrimination between the two mechanisms via cw PLDMR.

  18. Crystallographic Fabrics, Grain Boundary Microstructure and Shape Preferred Orientation of Deformed Banded Iron Formations and their Significance for Deformation Interpretation

    Science.gov (United States)

    Ávila, Carlos Fernando; Graça, Leonardo; Lagoeiro, Leonardo; Ferreira, Filippe

    2016-04-01

    The characterization of grain boundaries and shapes along with crystallographic preferred orientations (CPOs) are a key aspect of investigations of rock microstructures for their correlation with deformation mechanisms. Rapid developments have occurred in the studying rock microstructures due to recent improvements in analytical techniques such as Electron Backscatter Diffraction (EBSD). EBSD technique allows quick automated microtextural characteritzation. The deformed banded iron formations (BIFs) occurring in the Quadrilátero Ferrífero (QF) province in Brazil have been studied extensively with EBSD. All studies have focused mainly in CPOs. The general agreement is that dislocation creep was the dominant process of deformation, for the strong c-axis fabric of hematite crystals. This idea is substantiated by viscoplastic self-consistent models for deformation of hematite. However there are limitations to analyzing natural CPOs alone, or those generated by deformation models. The strong c-axis fabric could be taken as equally powerful an evidence for other known deformation mechanisms. Some grain boundary types in BIFs of the QF are irregular and comprise equant grains in granoblastic texture (Figure 1a). CPOs for this kind are strong and consistent with a predominance of dislocation creep. Others are very regular and long parallel to basal planes of hematites forming large elongated crystals (lepidoblastic texture, Figure 1b). Such crystals are called specularite, and their formation has been previously attributed to dislocation creep. This is erroneous because of the high strains which would be required. Their shape must be due to anisotropic grain growth. Other types lie between the above end-textures. Both types of grain shape microstructures have the same core deformation mechanism. Describing their genetic differences is crucial, since specularite owe its shape to anisotropic grain growth. It is not possible yet to confirm that dislocation creep was the

  19. Enhancing the Efimov correlation in Bose polarons with large mass imbalance

    Science.gov (United States)

    Sun, Mingyuan; Cui, Xiaoling

    2017-08-01

    We study the effect of Efimov physics (in the few-body sector) on the spectral response of the Bose polaron, a many-body system consisting of an impurity immersed in a bath of bosonic atoms. We find that the Efimov correlation can be greatly enhanced by increasing the mass ratio between the bosons and the impurity, which results in visible signatures in the rf spectrum of the polaron. Using a diagrammatic approach up to the third-order virial expansion, we show how the mass imbalance and the enhanced three-body effect modify the line shape and linewidth of the polaron spectrum. Moreover, we study the effect of a finite boson-boson interaction on the spectrum. Taking the realistic system of Li impurities immersed in Cs bosons with a positive Cs-Cs scattering length, we find a visible Efimov branch, which is associated with the second lowest Efimov trimer, in the polaron spectrum. In particular, by adjusting the boson density the Efimov branch can greatly hybridize with the attractive polaron branch, leading to spectrum broadening near their avoided level crossing. Our results can be directly probed in the cold atoms experiments on Li-Cs and Li-Rb Bose polarons.

  20. The formation of α-phase SnS nanorods by PVP assisted polyol synthesis: Phase stability, micro structure, thermal stability and defects induced energy band transitions

    Energy Technology Data Exchange (ETDEWEB)

    Baby, Benjamin Hudson; Mohan, D. Bharathi, E-mail: d.bharathimohan@gmail.com

    2017-05-01

    We report the formation of single phase of SnS nanostructure through PVP assisted polyol synthesis by varying the source concentration ratio (Sn:S) from 1:1M to 1:12M. The effect of PVP concentration and reaction medium towards the preparation of SnS nanostructure is systematically studied through confocal Raman spectrometer, X-ray diffraction, thermogravimetry analysis, scanning electron microscope, transmission electron microscopy, X-ray photoelectron spectroscopy, UV–Vis–NIR absorption and fluorescence spectrophotometers. The surface morphology of SnS nanostructure changes from nanorods to spherical shape with increasing PVP concentration from 0.15M to 0.5M. Raman analysis corroborates that Raman active modes of different phases of Sn-S are highly active when Raman excitation energy is slightly greater than the energy band gap of the material. The presence of intrinsic defects and large number of grain boundaries resulted in an improved thermal stability of 20 °C during the phase transition of α-SnS. Band gap calculation from tauc plot showed the direct band gap of 1.5 eV which is attributed to the single phase of SnS, could directly meet the requirement of an absorber layer in thin film solar cells. Finally, we proposed an energy band diagram for as synthesized single phase SnS nanostructure based on the experimental results obtained from optical studies showing the energy transitions attributed to band edge transition and also due to the presence of intrinsic defects. - Highlights: • PVP stabilizes the orthorhombic (α) phase of SnS. • Optical band gap of P type SnS tuned by PVP for photovoltaic applications. • The formation of Sn rich SnS phase is investigated through XPS analysis. • Intrinsic defects enhance the thermal stability of α-SnS. • The feasibility of energy transition liable to point defects is discussed.

  1. Formation mechanism of the low-frequency locally resonant band gap in the two-dimensional ternary phononic crystals

    Science.gov (United States)

    Wang, Gang; Liu, Yao-Zong; Wen, Ji-Hong; Yu, Dian-Long

    2006-02-01

    The low-frequency band gap and the corresponding vibration modes in two-dimensional ternary locally resonant phononic crystals are restudied successfully with the lumped-mass method. Compared with the work of C. Goffaux and J. Sánchez-Dehesa (Phys. Rev. B 67 14 4301(2003)), it is shown that there exists an error of about 50% in their calculated results of the band structure and one band is missing in their results. Moreover, the in-plane modes shown in their paper are improper, which results in the wrong conclusion on the mechanism of the ternary locally resonant phononic crystals. Based on the lumped-mass method and better description of the vibration modes according to the band gaps, the locally resonant mechanism in forming the subfrequency gaps is thoroughly analysed. The rule used to judge whether a resonant mode in the phononic crystals can result in a corresponding subfrequency gap is also verified in this ternary case.

  2. Strong-coupling Bose polarons out of equilibrium: Dynamical renormalization-group approach

    Science.gov (United States)

    Grusdt, Fabian; Seetharam, Kushal; Shchadilova, Yulia; Demler, Eugene

    2018-03-01

    When a mobile impurity interacts with a surrounding bath of bosons, it forms a polaron. Numerous methods have been developed to calculate how the energy and the effective mass of the polaron are renormalized by the medium for equilibrium situations. Here, we address the much less studied nonequilibrium regime and investigate how polarons form dynamically in time. To this end, we develop a time-dependent renormalization-group approach which allows calculations of all dynamical properties of the system and takes into account the effects of quantum fluctuations in the polaron cloud. We apply this method to calculate trajectories of polarons following a sudden quench of the impurity-boson interaction strength, revealing how the polaronic cloud around the impurity forms in time. Such trajectories provide additional information about the polaron's properties which are challenging to extract directly from the spectral function measured experimentally using ultracold atoms. At strong couplings, our calculations predict the appearance of trajectories where the impurity wavers back at intermediate times as a result of quantum fluctuations. Our method is applicable to a broader class of nonequilibrium problems. As a check, we also apply it to calculate the spectral function and find good agreement with experimental results. At very strong couplings, we predict that quantum fluctuations lead to the appearance of a dark continuum with strongly suppressed spectral weight at low energies. While our calculations start from an effective Fröhlich Hamiltonian describing impurities in a three-dimensional Bose-Einstein condensate, we also calculate the effects of additional terms in the Hamiltonian beyond the Fröhlich paradigm. We demonstrate that the main effect of these additional terms on the attractive side of a Feshbach resonance is to renormalize the coupling strength of the effective Fröhlich model.

  3. Thermodynamics of the polaron master equation at finite bias

    International Nuclear Information System (INIS)

    Krause, Thilo; Brandes, Tobias; Schaller, Gernot; Esposito, Massimiliano

    2015-01-01

    We study coherent transport through a double quantum dot. Its two electronic leads induce electronic matter and energy transport and a phonon reservoir contributes further energy exchanges. By treating the system-lead couplings perturbatively, whereas the coupling to vibrations is treated non-perturbatively in a polaron-transformed frame, we derive a thermodynamic consistent low-dimensional master equation. When the number of phonon modes is finite, a Markovian description is only possible when these couple symmetrically to both quantum dots. For a continuum of phonon modes however, also asymmetric couplings can be described with a Markovian master equation. We compute the electronic current and dephasing rate. The electronic current enables transport spectroscopy of the phonon frequency and displays signatures of Franck-Condon blockade. For infinite external bias but finite tunneling bandwidths, we find oscillations in the current as a function of the internal bias due to the electron-phonon coupling. Furthermore, we derive the full fluctuation theorem and show its identity to the entropy production in the system

  4. Phosphogenesis in the 2460 and 2728 million-year-old banded iron formations as evidence for biological cycling of phosphate in the early biosphere.

    Science.gov (United States)

    Li, Yi-Liang; Sun, Si; Chan, Lung S

    2012-01-01

    The banded iron formation deposited during the first 2 billion years of Earth's history holds the key to understanding the interplay between the geosphere and the early biosphere at large geological timescales. The earliest ore-scale phosphorite depositions formed almost at ∼2.0-2.2 billion years ago bear evidence for the earliest bloom of aerobic life. The cycling of nutrient phosphorus and how it constrained primary productivity in the anaerobic world of Archean-Palaeoproterozoic eons are still open questions. The controversy centers about whether the precipitation of ultrafine ferric oxyhydroxide due to the microbial Fe(II) oxidation in oceans earlier than 1.9 billion years substantially sequestrated phosphate, and whether this process significantly limited the primary productivity of the early biosphere. In this study, we report apatite radial flowers of a few micrometers in the 2728 million-year-old Abitibi banded iron formation and the 2460 million-year-old Kuruman banded iron formation and their similarities to those in the 535 million-year-old Lower Cambrian phosphorite. The lithology of the 535 Million-year-old phosphorite as a biosignature bears abundant biomarkers that reveal the possible similar biogeochemical cycling of phosphorus in the Later Archean and Palaeoproterozoic oceans. These apatite radial flowers represent the primary precipitation of phosphate derived from the phytoplankton blooms in the euphotic zones of Neoarchean and Palaoeproterozoic oceans. The unbiased distributions of the apatite radial flowers within sub-millimeter bands do not support the idea of an Archean Crisis of Phosphate. This is the first report of the microbial mediated mineralization of phosphorus before the Great Oxidation Event when the whole biosphere was still dominated by anaerobic microorganisms.

  5. The elusive role of NbLi bound polaron energy in hopping charge transport in Fe: LiNbO3

    Science.gov (United States)

    Guilbert, Laurent; Vittadello, Laura; Bazzan, Marco; Mhaouech, Imed; Messerschmidt, Simon; Imlau, Mirco

    2018-03-01

    Charge transport due to small polarons hopping among defective (bound polarons) and regular (free polarons) sites is shown to depend in a non-trivial way on the value of the stabilization energy provided by the lattice distortion surrounding the charge carriers. This energy, normally not directly accessible for bound polarons using spectroscopic techniques, is determined here by a combination of experimental and numerical methods for the important case of small electron polarons bound to NbLi defects in the prototype ferroelectric oxide lithium niobate. Our findings provide an estimation of the NbLi polaron stabilization energy E_GP=(0.75+/-0.05)~eV and demonstrate that in lithium niobate both free and bound polarons contribute to charge transport at room temperature, explaining the fast decay of the light-induced bound polaron population observed by transient absorption spectroscopy.

  6. Intermediate band formation in a δ-doped like QW superlattices of GaAs/AlxGa1-xAs for solar cell design

    Science.gov (United States)

    Del Río-De Santiago, A.; Martínez-Orozco, J. C.; Rodríguez-Magdaleno, K. A.; Contreras-Solorio, D. A.; Rodríguez-Vargas, I.; Ungan, F.

    2018-03-01

    It is reported a numerical computation of the local density of states for a δ-doped like QW superlattices of AlxGa1-xAs, as a possible heterostructure that, being integrated into a solar cell device design, can provide an intermediate band of allowed states to assist the absorption of photons with lower energies than that of the energy gap of the solar-cell constituent materials. This work was performed using the nearest neighbors sp3s* tight-binding model including spin. The confining potential caused by the ionized donor impurities in δ-doped impurities seeding that was obtained analytically within the lines of the Thomas-Fermi approximation was reproduced here by the Al concentration x variation. This potential is considered as an external perturbation in the tight-binding methodology and it is included in the diagonal terms of the tight-binding Hamiltonian. Special attention is paid to the width of the intermediate band caused by the change in the considered aluminium concentration x, the inter-well distance between δ-doped like QW wells and the number of them in the superlattice. In general we can conclude that this kind of superlattices can be suitable for intermediate band formation for possible intermediate-band solar cell design.

  7. Exploring Polaronic, Excitonic Structures and Luminescence in Cs4PbBr6/CsPbBr3.

    Science.gov (United States)

    Kang, Byungkyun; Biswas, Koushik

    2018-02-15

    Among the important family of halide perovskites, one particular case of all-inorganic, 0-D Cs 4 PbBr 6 and 3-D CsPbBr 3 -based nanostructures and thin films is witnessing intense activity due to ultrafast luminescence with high quantum yield. To understand their emissive behavior, we use hybrid density functional calculations to first compare the ground-state electronic structure of the two prospective compounds. The dispersive band edges of CsPbBr 3 do not support self-trapped carriers, which agrees with reports of weak exciton binding energy and high photocurrent. The larger gap 0-D material Cs 4 PbBr 6 , however, reveals polaronic and excitonic features. We show that those lattice-coupled carriers are likely responsible for observed ultraviolet emission around ∼375 nm, reported in bulk Cs 4 PbBr 6 and Cs 4 PbBr 6 /CsPbBr 3 composites. Ionization potential calculations and estimates of type-I band alignment support the notion of quantum confinement leading to fast, green emission from CsPbBr 3 nanostructures embedded in Cs 4 PbBr 6 .

  8. Fingerprints of spin-orbital polarons and of their disorder in the photoemission spectra of doped Mott insulators with orbital degeneracy

    Science.gov (United States)

    Avella, Adolfo; Oleś, Andrzej M.; Horsch, Peter

    2018-04-01

    means of a complementary many-body polaron theory, which yields a similar robust spin and orbital order as the Hartree-Fock approximation. Using realistic parameters for the vanadium perovskite La1 -xCaxVO3 , we show that its soft gap is reproduced as well as the marginal doping dependence of the position of the chemical potential relative to the center of the lower Hubbard band. The present theory uncovers also the reasons why the d1→d0 satellite excitations, which directly probe the effect of the random defect fields on the polaron state, are not well resolved in the available experimental photoemission spectra for La1 -xCaxVO3 .

  9. Link between light-triggered Mg-banding and chamber formation in the planktic foraminifera Neogloboquadrina dutertrei

    Science.gov (United States)

    Fehrenbacher, Jennifer S.; Russell, Ann D.; Davis, Catherine V.; Gagnon, Alexander C.; Spero, Howard J.; Cliff, John B.; Zhu, Zihua; Martin, Pamela

    2017-05-01

    The relationship between seawater temperature and the average Mg/Ca ratios in planktic foraminifera is well established, providing an essential tool for reconstructing past ocean temperatures. However, many species display alternating high and low Mg-bands within their shell walls that cannot be explained by temperature alone. Recent experiments demonstrate that intrashell Mg variability in Orbulina universa, which forms a spherical terminal shell, is paced by the diurnal light/dark cycle. Whether Mg-heterogeneity is also diurnally paced in species with more complex shell morphologies is unknown. Here we show that high Mg/Ca-calcite forms at night in cultured specimens of the multi-chambered species Neogloboquadrina dutertrei. Our results demonstrate that N. dutertrei adds a significant amount of calcite, and nearly all Mg-bands, after the final chamber forms. These results have implications for interpreting patterns of calcification in N. dutertrei and suggest that diurnal Mg-banding is an intrinsic component of biomineralization in planktic foraminifera.

  10. Quantum Monte Carlo simulations of the Fermi-polaron problem and bosons with Gaussian interactions

    Energy Technology Data Exchange (ETDEWEB)

    Kroiss, Peter Michael

    2017-02-01

    This thesis deals with the application of current Quantum Monte Carlo algorithms to many-body systems of fermionic and bosonic species. The first part applies the diagrammatic Monte Carlo method to the Fermi polaron problem, a system of an impurity interacting resonantly with a homogeneous Fermi bath. It is numerically shown that the three particle-hole diagrams do not contribute significantly to the final answer in a quasi-two-dimensional setup, thus demonstrating a nearly perfect destructive interference of contributions in subspaces with higher-order particle-hole lines. Consequently, for strong-enough confinement in the third direction, the transition between the polaron and the molecule ground state is found to be in good agreement with the pure two-dimensional case and agrees very well with the one found by the wave-function approach in the two-particle-hole subspace. In three-dimensional Fermi-polaron systems with mass imbalance of impurity and bath atoms, polaron energy and quasiparticle residue can be accurately determined over a broad range of impurity masses. Furthermore, the spectral function of an imbalanced polaron demonstrates the stability of the quasiparticle and also allows us to locate the repulsive polaron as an excited state. The quantitative exactness of two-particle-hole wave functions is investigated, resulting in a relative lowering of polaronic energies in the mass-imbalance phase diagram. Tan's contact coefficient for the mass-balanced polaron system is found to be in good agreement with variational methods. Mass-imbalanced systems can be studied experimentally by ultracold atom mixtures such as {sup 6}Li-{sup 40}K. In the second part of the thesis, the ground state of a two-dimensional system of Bose particles of spin zero, interacting via a repulsive Gaussian-Core potential, is investigated by means of path integral Monte Carlo simulations. The quantum phase diagram is qualitatively identical to that of two-dimensional Yukawa

  11. The effects of temperature on the formation and stability of bipolarons in conjugated polymers

    Science.gov (United States)

    Meng, Yan; Guo, Guang-jie; Wang, Ya-dong; Li, Yin-feng; An, Zhong

    2017-04-01

    Within the one-dimensional tight-binding Su-Schrieffer-Heeger (SSH) model modified to include thermal effects and electron-electron interactions, the transition from polaron to bipolaron and the formation of bipolaron induced by injecting charges are separately simulated using a nonadiabatic evolution method. For the transition process, it is found that with the temperature effects taken into account, two separate polarons with the same charge and antiparallel spins can recombine into a bipolaron. The results show that with the temperature increasing, the time taken for the recombination of two polarons decreases. The effects of different distances between the polarons are also numerically simulated. For the bipolaron formation, we investigate the evolution of two charges injected into a polymer chain with the thermal effects. We find that the bipolaron is always quickly formed and its dynamical stability is less sensitive to the temperature change. Thermal effects can only affect the degree of the charges localization.

  12. Geochemical evolution of the banded iron formations of the Voronezh Crystalline Massif in the early Precambrian: Sources of matter and geochronological constraints

    Science.gov (United States)

    Savko, K. A.; Bazikov, N. S.; Artemenko, G. V.

    2015-09-01

    The banded iron formations (BIFs) of the Voronezh Crystalline Massif occur at three stratigraphic levels: Mesoarchean, Neoarchean, and Paleoproterozoic. In comparison with Paleoproterozoic BIFs, the Archean BIFs are enriched in TiO2, Al2O3, Cr, Ni, and REEs. All the BIFs are characterized by positive Eu anomalies, absence of Ce anomalies, and predominance of HREEs over LREEs. The Paleoproterozoic BIFs show no evidence of clastic or hydrothermal contamination. The low Ni/Fe ratios indicate that the BIFs are younger than 2.7 Ga and their formation was followed by a sharp drop of the level of the mantle Ni supply. On the other hand, very low (<1 ppm) U contents indicate the upper age of iron accumulation—no later than the Great Oxidation Event of ~2.47 Ga.

  13. Micro-scale characterization of iron ores from a banded iron formation in Yishui county, western Shandong province of North China Craton

    Science.gov (United States)

    Moon, I.; Lee, I.; Yang, X.

    2016-12-01

    Banded iron formations (BIFs) are widely distributed in North China Craton (NCC). Yishui BIF is located in Yishui county, western Shandong Province of NCC and is categorized as Algoma-type. The origin of iron and silica of BIFs in this region have been studied extensively for decades. The trace elemental concentrations of magnetite and hematite in iron ores from Yishui BIF are focused in this study to better understand the origins of BIF. To discuss micro-structural signatures of iron ores, X-ray diffraction (XRD), Raman spectrometer, electron microprobe (EPMA) and laser ablation inductively-coupled plasma mass spectrometer (LA-ICP-MS) were utilized. Overall geochemical data represents abundance of trace elements, oxygen fugacity (fO2) condition during the formation of iron oxides, depositional environment of Yishui BIF, implying the involvement of volcanic eruption and hydrothermal exhalation during the chemical deposition.

  14. Idetification of the chemical sedimentary protolish of the early Paleoproterozoic banded iron formation from Wuyang area, in the southern margin of the North China Craton

    Science.gov (United States)

    Lan, C.; Zhao, T.

    2016-12-01

    The Paleoproterozoic banded iron formation (BIF) from Wuyang area in the southern margin of the North China Craton (NCC) were metamorphosed under granulite facies, and are characterized with an assemblage of clinopyroxene, magnetite and orthopyroxene. Two types of iron ores can be identified on the basis of macro- and micro-textures: banded quartz-clinopyroxene (±othopyroxene) -magnetite ores and massive clinopyroxene-magnetite ores. Two-pyroxene geothermometry indicates that the primary counterparts of these ores have undergone metamorphism with a peak temperature of about 762±9°. Both the banded and massive ores have also similarly BIF-like REE+Y features, and thus are proposed to have all formed from chemical sediments. Similarly, clinopyroxenes from both types have BIF-like rare earth element compositions and are rich in Fe (16-23 wt.% FeOtotoal), further suggesting that they are primary Fe-Mg-Ca-rich chemical sediments during metamorphism. Slight enrichments of TiO2, Al2O3, Zr, Hf, Ta and Th of the Wuyang IF suggest relatively low detritus input. The massive ore have magnetite containing V, Cr and Ti much higher than those of the banded ores, suggesting that they may have undergone stronger secondary alteration possibly related to the intrusion of nearby pyroxenite plutons. Different ores have seawater-like REE+Y patterns with LREE depletions and positive anomalies of La, Eu, and Y, showing that granulite facies metamorphism did not essentially modify the primary compositions of the Wuyang IF deposited from paleo-seawater. Our results suggest less than 0.1% contribution from high-temperature hydrothermal fluids.

  15. Stability and Polaronic Motion of Self-Trapped Holes in Silver Halides

    DEFF Research Database (Denmark)

    Loftager, Simon; Garcia-Fernandez, P.; Aramburu, J. A.

    2016-01-01

    Polarons and their associated transport properties are a field of great current interest both in chemistry and physics. To further our understanding of these quasi-particles, we have carried out first-principles calculations of self-trapped holes (STHs) in the model compounds AgCl and AgBr, for w...

  16. Diagrammatic Monte Carlo study of Fröhlich polaron dispersion in two and three dimensions

    Science.gov (United States)

    Hahn, Thomas; Klimin, Sergei; Tempere, Jacques; Devreese, Jozef T.; Franchini, Cesare

    2018-04-01

    We present results for the solution of the large polaron Fröhlich Hamiltonian in 3 dimensions (3D) and 2 dimensions (2D) obtained via the diagrammatic Monte Carlo (DMC) method. Our implementation is based on the approach by Mishchenko [A. S. Mishchenko et al., Phys. Rev. B 62, 6317 (2000), 10.1103/PhysRevB.62.6317]. Polaron ground state energies and effective polaron masses are successfully benchmarked with data obtained using Feynman's path integral formalism. By comparing 3D and 2D data, we verify the analytically exact scaling relations for energies and effective masses from 3 D →2 D , which provides a stringent test for the quality of DMC predictions. The accuracy of our results is further proven by providing values for the exactly known coefficients in weak- and strong-coupling expansions. Moreover, we compute polaron dispersion curves which are validated with analytically known lower and upper limits in the small-coupling regime and verify the first-order expansion results for larger couplings, thus disproving previous critiques on the apparent incompatibility of DMC with analytical results and furnishing useful reference for a wide range of coupling strengths.

  17. Effect of doping Ca on polaron hopping in LaSr 2 Mn 2 O 7

    Indian Academy of Sciences (India)

    From the transport studies in the bilayer manganites LaSr2-CaMn2O7, we have found the variable-range hopping model proposed by Viret et al to be inadequate to describe the transport of charge in these materials. The polarons appear to hop to their nearest neighbors with an activation energy, which in part is ...

  18. Effect of doping Ca on polaron hopping in LaSr 2 Mn 2 O 7

    Indian Academy of Sciences (India)

    ... Lecture Workshops · Refresher Courses · Symposia · Live Streaming. Home; Journals; Pramana – Journal of Physics; Volume 58; Issue 5-6. Effect of doping Ca on polaron hopping in LaSr2Mn2O7. S N Bhatia Osama A Yassin. Colossal Magnetoresistance & Other Materials Volume 58 Issue 5-6 May-June 2002 pp 1061- ...

  19. VALES - IV. Exploring the transition of star formation efficiencies between normal and starburst galaxies using APEX/SEPIA Band-5 and ALMA at low redshift

    Science.gov (United States)

    Cheng, C.; Ibar, E.; Hughes, T. M.; Villanueva, V.; Leiton, R.; Orellana, G.; Muñoz Arancibia, A.; Lu, N.; Xu, C. K.; Willmer, C. N. A.; Huang, J.; Cao, T.; Yang, C.; Xue, Y. Q.; Torstensson, K.

    2018-03-01

    In this work, we present new the Swedish-ESO PI receiver for the Atacama Pathfinder Experiment APEX/SEPIA Band-5 observations targeting the CO (J = 2-1) emission line of 24 Herschel-detected galaxies at z = 0.1-0.2. Combining this sample with our recent new Valparaíso ALMA Line Emission Survey (VALES), we investigate the star formation efficiencies [SFEs = star formation rate (SFR)/M_H2] of galaxies at low redshift. We find the SFE of our sample bridges the gap between normal star-forming galaxies and Ultra-Luminous Infrared Galaxies (ULIRGs), which are thought to be triggered by different star formation modes. Considering the SFE΄ as the SFR and the L^' }_CO ratio, our data show a continuous and smooth increment as a function of infrared luminosity (or star formation rate) with a scatter about 0.5 dex, instead of a steep jump with a bimodal behaviour. This result is due to the use of a sample with a much larger range of sSFR/sSFRms using LIRGs, with luminosities covering the range between normal and ULIRGs. We conclude that the main parameters controlling the scatter of the SFE in star-forming galaxies are the systematic uncertainty of the αCO conversion factor, the gas fraction, and physical size.

  20. Molecular Tethering or Aggregation: Is the Existence of Charge-Transfer Bands Indicative of the Formation of Blue-Box/Tetrathiafulvalene Inclusion Complexes?

    Energy Technology Data Exchange (ETDEWEB)

    Tejerina, Baudilio; Gothard, Chris M.; Grzybowski, Bartosz A.

    2012-03-27

    The interaction between tetrathiafulvalene and tetracation cyclobis(paraquat-p-phenylene) fragments—the key elements of many rotaxane systems—was investigated theoretically by using ab-initio second-order perturbation methods. In addition to the inclusion complex observed in the solid state, a thermodynamically stable “exterior” complex was identified. Calculation of the UV/Vis spectra for the inclusion and the exterior complexes indicated that the charge-transfer band that is often used to predict the formation of the inclusion complexes in solution is, in reality, due to the exterior mode of complexation. These results suggest that UV/Vis spectroscopy is not a reliable method for assigning the complexation modes in TTF:BB4+ rotaxanes and related systems.

  1. Effect of base-pair inhomogeneities on charge transport along the DNA molecule, mediated by twist and radial polarons

    International Nuclear Information System (INIS)

    Palmero, F; Archilla, J F R; Hennig, D; Romero, F R

    2004-01-01

    Some recent results for a three-dimensional, semi-classical, tight-binding model for DNA show that there are two types of polarons, namely radial and twist polarons, which can transport charge along the DNA molecule. However, the existence of two types of base pairs in real DNA makes it crucial to find out if charge transport also exists in DNA chains with different base pairs. In this paper, we address this problem in its simple case, a homogeneous chain except for a single different base pair, which we call a base-pair inhomogeneity, and its effect on charge transport. Radial polarons experience either reflection or trapping. However, twist polarons are good candidates for charge transport along real DNA. This transport is also very robust with respect to weak parametric and diagonal disorder

  2. Effect of base-pair inhomogeneities on charge transport along the DNA molecule, mediated by twist and radial polarons

    Energy Technology Data Exchange (ETDEWEB)

    Palmero, F [ETS IngenierIa Informatica, Universidad de Sevilla, Avda Reina Mercedes s/n, 41012-Sevilla (Spain); Archilla, J F R [ETS IngenierIa Informatica, Universidad de Sevilla, Avda Reina Mercedes s/n, 41012-Sevilla (Spain); Hennig, D [Freie Universitaet Berlin, Fachbereich Physik, Arnimallee 14, 14195-Berlin (Germany); Romero, F R [Facultad de FIsica, Universidad de Sevilla, Avda Reina Mercedes s/n, 41012-Sevilla (Spain)

    2004-02-01

    Some recent results for a three-dimensional, semi-classical, tight-binding model for DNA show that there are two types of polarons, namely radial and twist polarons, which can transport charge along the DNA molecule. However, the existence of two types of base pairs in real DNA makes it crucial to find out if charge transport also exists in DNA chains with different base pairs. In this paper, we address this problem in its simple case, a homogeneous chain except for a single different base pair, which we call a base-pair inhomogeneity, and its effect on charge transport. Radial polarons experience either reflection or trapping. However, twist polarons are good candidates for charge transport along real DNA. This transport is also very robust with respect to weak parametric and diagonal disorder.

  3. Renormalization group approach to the Fröhlich polaron model: application to impurity-BEC problem.

    Science.gov (United States)

    Grusdt, F; Shchadilova, Y E; Rubtsov, A N; Demler, E

    2015-07-17

    When a mobile impurity interacts with a many-body system, such as a phonon bath, a polaron is formed. Despite the importance of the polaron problem for a wide range of physical systems, a unified theoretical description valid for arbitrary coupling strengths is still lacking. Here we develop a renormalization group approach for analyzing a paradigmatic model of polarons, the so-called Fröhlich model, and apply it to a problem of impurity atoms immersed in a Bose-Einstein condensate of ultra cold atoms. Polaron energies obtained by our method are in excellent agreement with recent diagrammatic Monte Carlo calculations for a wide range of interaction strengths. They are found to be logarithmically divergent with the ultra-violet cut-off, but physically meaningful regularized polaron energies are also presented. Moreover, we calculate the effective mass of polarons and find a smooth crossover from weak to strong coupling regimes. Possible experimental tests of our results in current experiments with ultra cold atoms are discussed.

  4. Fractal dimension study of polaron effects in cylindrical GaAs/Al x Ga1- x As core-shell nanowires

    Science.gov (United States)

    Sun, Hui; Li, Hua; Tian, Qiang

    2018-04-01

    Polaron effects in cylindrical GaAs/Al x Ga1- x As core-shell nanowires are studied by applying the fractal dimension method. In this paper, the polaron properties of GaAs/Al x Ga1- x As core-shell nanowires with different core radii and aluminum concentrations are discussed. The polaron binding energy, polaron mass shift, and fractal dimension parameter are numerically determined as functions of shell width. The calculation results reveal that the binding energy and mass shift of the polaron first increase and then decrease as the shell width increases. A maximum value appears at a certain shell width for different aluminum concentrations and a given core radius. By using the fractal dimension method, polaron problems in cylindrical GaAs/Al x Ga1- x As core-shell nanowires are solved in a simple manner that avoids complex and lengthy calculations.

  5. Optical phonon modes and polaron related parameters in GaxIn1-xP

    Science.gov (United States)

    Bouarissa, N.; Algarni, H.; Al-Hagan, O. A.; Khan, M. A.; Alhuwaymel, T. F.

    2018-02-01

    Based on a pseudopotential approach under the virtual crystal approximation that includes the effect of compositional disorder, the optical lattice vibration frequencies and polaron related parameters in zinc-blende GaxIn1-xP have been studied. Our findings showed generally reasonably good accord with data in the literature. Other case, our results are predictions. The composition dependence of longitudinal optical (LO) and transverse optical (TO) phonon modes, LO-TO splittings, Frӧhlich coupling parameter, Debye temperature of LO phonon frequency, and polaron effective mass has been analyzed and discussed. While a non-monotonic behavior has been noticed for the LO and TO phonon frequencies versus Ga concentration x, a monotonic behavior has been observed for the rest of the features of interest. The information derived from this investigation may be useful for optoelectronic technological applications.

  6. Hall effect driven by non-collinear magnetic polarons in diluted magnetic semiconductors

    Science.gov (United States)

    Denisov, K. S.; Averkiev, N. S.

    2018-04-01

    In this letter, we develop the theory of Hall effect driven by non-collinear magnetic textures (topological Hall effect—THE) in diluted magnetic semiconductors (DMSs). We show that a carrier spin-orbit interaction induces a chiral magnetic ordering inside a bound magnetic polaron (BMP). The inner structure of non-collinear BMP is controlled by the type of spin-orbit coupling, allowing us to create skyrmion- (Rashba) or antiskyrmion-like (Dresselhaus) configurations. The asymmetric scattering of itinerant carriers on polarons leads to the Hall response which exists in weak external magnetic fields and at low temperatures. We point out that DMS-based systems allow one to investigate experimentally the dependence of THE both on a carrier spin polarization and on a non-collinear magnetic texture shape.

  7. Impact of morphology on polaron delocalization in a semicrystalline conjugated polymer

    KAUST Repository

    Steyrleuthner, Robert

    2016-12-20

    We investigate the delocalization of holes in the semicrystalline conjugated polymer poly(2,5-bis(3-alkylthiophene-2-yl)thieno[3,2-b]thiophene) (PBTTT) by directly measuring the hyperfine coupling between photogenerated polarons and bound nuclear spins using electron nuclear double resonance spectroscopy. An extrapolation of the corresponding oligomer spectra reveals that charges tend to delocalize over 4.0-4.8 nm with delocalization strongly dependent on molecular order and crystallinity of the PBTTT polymer thin films. Density functional theory calculations of hyperfine couplings confirm that long-range corrected functionals appropriately describe the change in coupling strength with increasing oligomer size and agree well with the experimentally measured polymer limit. Our discussion presents general guidelines illustrating the various pitfalls and opportunities when deducing polaron localization lengths from hyperfine coupling spectra of conjugated polymers.

  8. The role of hydrostatic pressure and temperature on bound polaron in semiconductor quantum dot

    International Nuclear Information System (INIS)

    El Moussaouy, A.; Ouchani, N.

    2014-01-01

    We studied theoretically the effects of hydrostatic pressure and temperature on the binding energy of shallow hydrogenic impurity in a cylindrical quantum dot (QD) using a variational approach within the effective mass approximation. The hydrostatic stress was applied along the QD growth axis. The interactions between the charge carriers and confined longitudinal optical (LO) phonon modes are taken into account. The numerical computation for GaAs/Ga 1−x Al x As QD has shown that the binding energy with and without the polaronic correction depends on the location of the impurity and the pressure effect and it is more pronounced for impurities in the QD center. Both the binding energy and the polaronic contribution increase linearly with increasing stress. For each pressure value, these energies are also found to decrease as the temperature increases. The results obtained show that in experimental studies of optical and electronic properties of QDs, the effects of pressure, temperature and polaronic correction on donor impurity binding energy should be taken into consideration

  9. Hartree-Fock treatment of Fermi polarons using the Lee-Low-Pine transformation

    Science.gov (United States)

    Kain, Ben; Ling, Hong Y.

    2017-09-01

    We consider the Fermi polaron problem at zero temperature, where a single impurity interacts with noninteracting host fermions. We approach the problem starting with a Fröhlich-like Hamiltonian where the impurity is described with canonical position and momentum operators. We apply the Lee-Low-Pine (LLP) transformation to change the fermionic Fröhlich Hamiltonian into the fermionic LLP Hamiltonian, which describes a many-body system containing host fermions only. We adapt the self-consistent Hartree-Fock (HF) approach, first proposed by Edwards, to the fermionic LLP Hamiltonian in which a pair of host fermions with momenta k and k' interact with a potential proportional to k .k' . We apply the HF theory, which has the advantage of not restricting the number of particle-hole pairs, to repulsive Fermi polarons in one dimension. When the impurity and host fermion masses are equal our variational ansatz, where HF orbitals are expanded in terms of free-particle states, produces results in excellent agreement with McGuire's exact analytical results based on the Bethe ansatz. This work raises the prospect of using the HF ansatz and its time-dependent generalization as building blocks for developing all-coupling theories for both equilibrium and nonequilibrium Fermi polarons in higher dimensions.

  10. GROUND-BASED Paα NARROW-BAND IMAGING OF LOCAL LUMINOUS INFRARED GALAXIES. I. STAR FORMATION RATES AND SURFACE DENSITIES

    Energy Technology Data Exchange (ETDEWEB)

    Tateuchi, Ken; Konishi, Masahiro; Motohara, Kentaro; Takahashi, Hidenori; Kato, Natsuko Mitani; Kitagawa, Yutaro; Todo, Soya; Toshikawa, Koji; Sako, Shigeyuki; Uchimoto, Yuka K.; Ohsawa, Ryou; Asano, Kentaro; Kamizuka, Takafumi; Nakamura, Tomohiko; Okada, Kazushi [Institute of Astronomy, Graduate School of Science, The University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Ita, Yoshifusa [Astronomical Institute, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578 (Japan); Komugi, Shinya [Division of Liberal Arts, Kogakuin University, 2665-1, Hachioji, Tokyo 192-0015 (Japan); Koshida, Shintaro [Subaru Telescope, National Astronomical Observatory of Japan, Hilo, HI 96720 (United States); Manabe, Sho [Department of Earth and Planetary Sciences, Kobe University, Kobe 657-8501 (Japan); Nakashima, Asami, E-mail: tateuchi@ioa.s.u-tokyo.ac.jp [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); and others

    2015-03-15

    Luminous infrared galaxies (LIRGs) are enshrouded by a large amount of dust produced by their active star formation, and it is difficult to measure their activity in optical wavelengths. We have carried out Paα narrow-band imaging observations of 38 nearby star forming galaxies including 33 LIRGs listed in the IRAS Revised Bright Galaxy Sample catalog with the Atacama Near InfraRed camera on the University of Tokyo Atacama Observatory (TAO) 1.0 m telescope (miniTAO). Star formation rates (SFRs) estimated from the Paα fluxes, corrected for dust extinction using the Balmer decrement method (typically A{sub V} ∼ 4.3 mag), show a good correlation with those from the bolometric infrared luminosity of the IRAS data within a scatter of 0.27 dex. This suggests that the correction of dust extinction for the Paα flux is sufficient in our sample. We measure the physical sizes and surface densities of infrared luminosities (Σ{sub L(IR)}) and the SFR (Σ{sub SFR}) of star forming regions for individual galaxies, and we find that most of the galaxies follow a sequence of local ultra-luminous or luminous infrared galaxies (U/LIRGs) on the L(IR)-Σ{sub L(IR)} and SFR-Σ{sub SFR} plane. We confirm that a transition of the sequence from normal galaxies to U/LIRGs is seen at L(IR) = 8 × 10{sup 10} L {sub ☉}. Also, we find that there is a large scatter in physical size, different from normal galaxies or ULIRGs. Considering the fact that most U/LIRGs are merging or interacting galaxies, this scatter may be caused by strong external factors or differences in their merging stages.

  11. A new model for the formation of a spaced crenulation (shear band) cleavage in the Dalradian rocks of the Tay Nappe, SW Highlands, Scotland

    Science.gov (United States)

    Geoff Tanner, P. W.

    2016-03-01

    The main conclusion of this study is that non-coaxial strain acting parallel to a flat-lying D1 spaced cleavage was responsible for the formation of the D2 spaced crenulation (shear band) cleavage in Dalradian rocks of Neoproterozoic-Lower Ordovician age in the SW Highlands, Scotland. The cm-dm-scale D2 microlithons are asymmetric; have a geometrically distinctive nose and tail; and show a thickened central portion resulting from back-rotation of the constituent D1 microlithons. The current terminology used to describe crenulation cleavages is reviewed and updated. Aided by exceptional 3D exposures, it is shown how embryonic D2 flexural-slip folds developed into a spaced cleavage comprising fold-pair domains wrapped by anastomosing cleavage seams. The bulk strain was partitioned into low-strain domains separated by zones of high non-coaxial strain. This new model provides a template for determining the sense of shear in both low-strain situations and in ductile, higher strain zones where other indicators, such as shear folds, give ambiguous results. Analogous structures include tectonic lozenges in shear zones, and flexural-slip duplexes. Disputes over the sense and direction of shear during emplacement of the Tay Nappe, and the apparently intractable conflict between minor fold asymmetry and shear sense, appear to be resolved.

  12. Large shift and small broadening of Br2 valence band upon dimer formation with H2O: an ab initio study.

    Science.gov (United States)

    Franklin-Mergarejo, Ricardo; Rubayo-Soneira, Jesus; Halberstadt, Nadine; Ayed, Tahra; Bernal-Uruchurtu, Margarita I; Hernández-Lamoneda, Ramón; Janda, Kenneth C

    2011-06-16

    Valence electronic excitation spectra are calculated for the H(2)O···Br(2) complex using highly correlated ab initio potentials for both the ground and the valence electronic excited states and a 2-D approximation for vibrational motion. Due to the strong interaction between the O-Br and the Br-Br stretching motions, inclusion of these vibrations is the minimum necessary for the spectrum calculation. A basis set calculation is performed to determine the vibrational wave functions for the ground electronic state and a wave packet simulation is conducted for the nuclear dynamics on the excited state surfaces. The effects of both the spin-orbit interaction and temperature on the spectra are explored. The interaction of Br(2) with a single water molecule induces nearly as large a shift in the spectrum as is observed for an aqueous solution. In contrast, complex formation has a remarkably small effect on the T = 0 K width of the valence bands due to the fast dissociation of the dihalogen bond upon excitation. We therefore conclude that the widths of the spectra in aqueous solution are mostly due to inhomogeneous broadening. © 2011 American Chemical Society

  13. Polaronic behavior in a weak-coupling superconductor.

    Science.gov (United States)

    Swartz, Adrian G; Inoue, Hisashi; Merz, Tyler A; Hikita, Yasuyuki; Raghu, Srinivas; Devereaux, Thomas P; Johnston, Steven; Hwang, Harold Y

    2018-02-13

    The nature of superconductivity in the dilute semiconductor SrTiO 3 has remained an open question for more than 50 y. The extremely low carrier densities ([Formula: see text]-[Formula: see text] cm -3 ) at which superconductivity occurs suggest an unconventional origin of superconductivity outside of the adiabatic limit on which the Bardeen-Cooper-Schrieffer (BCS) and Migdal-Eliashberg (ME) theories are based. We take advantage of a newly developed method for engineering band alignments at oxide interfaces and access the electronic structure of Nb-doped SrTiO 3 , using high-resolution tunneling spectroscopy. We observe strong coupling to the highest-energy longitudinal optic (LO) phonon branch and estimate the doping evolution of the dimensionless electron-phonon interaction strength ([Formula: see text]). Upon cooling below the superconducting transition temperature ([Formula: see text]), we observe a single superconducting gap corresponding to the weak-coupling limit of BCS theory, indicating an order of magnitude smaller coupling ([Formula: see text]). These results suggest that despite the strong normal state interaction with electrons, the highest LO phonon does not provide a dominant contribution to pairing. They further demonstrate that SrTiO 3 is an ideal system to probe superconductivity over a wide range of carrier density, adiabatic parameter, and electron-phonon coupling strength.

  14. Acceptor and Excitation Density Dependence of the Ultrafast Polaron Absorption Signal in Donor-Acceptor Organic Solar Cell Blends.

    Science.gov (United States)

    Zarrabi, Nasim; Burn, Paul L; Meredith, Paul; Shaw, Paul E

    2016-07-21

    Transient absorption spectroscopy on organic semiconductor blends for solar cells typically shows efficient charge generation within ∼100 fs, accounting for the majority of the charge carriers. In this Letter, we show using transient absorption spectroscopy on blends containing a broad range of acceptor content (0.01-50% by weight) that the rise of the polaron signal is dependent on the acceptor concentration. For low acceptor content (10%) most polarons are generated within 200 fs. The rise time in blends with low acceptor content was also found to be sensitive to the pump fluence, decreasing with increasing excitation density. These results indicate that the sub-100 fs rise of the polaron signal is a natural consequence of both the high acceptor concentrations in many donor-acceptor blends and the high excitation densities needed for transient absorption spectroscopy, which results in a short average distance between the exciton and the donor-acceptor interface.

  15. Polarons as stable solitary wave solutions to the Dirac-Coulomb system

    Science.gov (United States)

    Comech, Andrew; Zubkov, Mikhail

    2013-11-01

    We consider solitary wave solutions to the Dirac-Coulomb system both from physical and mathematical points of view. Fermions interacting with gravity in the Newtonian limit are described by the model of Dirac fermions with the Coulomb attraction. This model also appears in certain condensed matter systems with emergent Dirac fermions interacting via optical phonons. In this model, the classical soliton solutions of equations of motion describe the physical objects that may be called polarons, in analogy to the solutions of the Choquard equation. We develop analytical methods for the Dirac-Coulomb system, showing that the no-node gap solitons for sufficiently small values of charge are linearly (spectrally) stable.

  16. Simbol-X: a formation flight mission with an unprecedented imaging capability in the 0.5-80 keV energy band

    Science.gov (United States)

    Tagliaferri, Gianpiero; Ferrando, Philippe; Le Duigou, Jean-Michel; Pareschi, Giovanni; Laurent, Philippe; Malaguti, Giuseppe; Clédassou, Rodolphe; Piermaria, Mauro; La Marle, Olivier; Fiore, Fabrizio; Giommi, Paolo

    2017-11-01

    The discovery of X-ray emission from cosmic sources in the 1960s has opened a new powerful observing window on the Universe. In fact, the exploration of the X-ray sky during the 70s-90s has established X-ray astronomy as a fundamental field of astrophysics. Today, the emission from astrophysical sources is by large best known at energies below 10 keV. The main reason for this situation is purely technical since grazing incidence reflection has so far been limited to the soft X-ray band. Above 10 keV all the observations have been obtained with collimated detectors or coded mask instruments. To make a leap step forward in Xray astronomy above 10 keV it is necessary to extend the principle of focusing X ray optics to higher energies, up to 80 keV and beyond. To this end, ASI and CNES are presently studying the implementation of a X-ray mission called Simbol-X. Taking advantage of emerging technology in mirror manufacturing and spacecraft formation flying, Simbol-X will push grazing incidence imaging up to 80 keV and beyond, providing a strong improvement both in sensitivity and angular resolution compared to all instruments that have operated so far above 10 keV. This technological breakthrough will open a new highenergy window in astrophysics and cosmology. Here we will address the problematic of the development for such a distributed and deformable instrument. We will focus on the main performances of the telescope, like angular resolution, sensitivity and source localization. We will also describe the specificity of the calibration aspects of the payload distributed over two satellites and therefore in a not "frozen" configuration.

  17. Rainy Periods and Bottom Water Stagnation Initiating Brine Accumulation and Metal Concentrations, 2. Precambrian Gold-Uranium Ore Beds and Banded Iron Formations

    Science.gov (United States)

    Rossignol-Strick, Martine

    1987-08-01

    I previously suggested that heavy runoff during the 12,500-7000 years B.P. tropical pluvial period generated bottom water quiescence and reducing conditions making possible sapropel formation, accumulation of brine originating at the sea bottom, and long-term preservation of hydrothermal sulfides in the Red Sea Deeps. I hypothesized the same process to account for two Precambrian strata-bound ores. In the Upper Witwatersrand paleoplacers, South Africa, gold and uranium eroded by running water from upstream greenstones, reached highest concentrations in association with organic matter in carbonaceous seams, and deposited in the distal end of fluvial fans during transgressive phases. I propose that the deep waters over these fans became anoxic when large, sudden floods stratified the water column. The organic matter thus locally preserved concentrated gold and uranium from the partial dissolution of the detrital metallic grains. In the Hamersley basin of Western Australia, banded iron formations (BIF) of the Dales Gorge Member are a major source of iron ore. Regularly fluctuating environmental conditions are shown by repetitious BIF and black shale macrobands. I propose that they were deposited in a confined, silled, deep basin connected with the open ocean. Before initiation of the lowest BIF deposition the active regional thermohaline circulation flushing the deep waters under a rather arid climate diluted and oxidized the Fe2+-rich hydrothermal effluents exhaling from the basin floor. Then, during a strong wet period, heavy runoff scavenging volcanoclastics from the land surface lowered the basin surface water salinity and prevented deepwater renewal. The hydrothermal effluents began to accumulate and progressively concentrated in the quiescent and progressively oxygen-depleted deep water. During this wet initial phase, the massive black, organic-rich pyritic shale at the top of the Mount McRae Shale Member was deposited immediately and conformably underlying the

  18. Seeing through the magnetite: Reassessing Eoarchean atmosphere composition from Isua (Greenland ≥3.7 Ga banded iron formations

    Directory of Open Access Journals (Sweden)

    Allen P. Nutman

    2017-11-01

    Full Text Available Estimates of early atmosphere compositions from metamorphosed banded iron formations (BIFs including the well-studied ≥3.7 BIFs of the Isua supracrustal belt (Greenland are dependent on knowledge of primary versus secondary Fe-mineralogical assemblages. Using new observations from locally well preserved domains, we interpret that a previously assumed primary redox indicator mineral, magnetite, is secondary after sedimentary Fe-clays (probably greenalite ± carbonates. Within ∼3.7 Ga Isua BIF, pre-tectonic nodules of quartz + Fe-rich amphibole ± calcite reside in a fine-grained (≤100 μm quartz + magnetite matrix. We interpret the Isua nodule amphibole as the metamorphosed equivalent of primary Fe-rich clays, armoured from diagenetic oxidative reactions by early silica concretion. Additionally, in another low strain lacunae, ∼3.76 Ga BIF layering is not solid magnetite but instead fine-grained magnetite + quartz aggregates. These magnetite + quartz aggregates are interpreted as the metamorphosed equivalent of Fe-clay-rich layers that were oxidised during diagenesis, because they were not armoured by early silicification. In almost all Isua BIF exposures, this evidence has been destroyed by strong ductile deformation. The Fe-clays likely formed by abiotic reactions between aqueous Fe2+ and silica. These clays along with silica ± carbonate were deposited below an oceanic Fe-chemocline as the sedimentary precursors of BIF. Breakdown of the clays on the sea floor may have been by anaerobic oxidation of Fe2+, a mechanism compatible with iron isotopic data previously published on these rocks. The new determinations of the primary redox-sensitive Fe-mineralogy of BIF significantly revise estimates of early Earth atmospheric oxygen and CO2 content, with formation of protolith Fe-rich clays and carbonates compatible with an anoxic Eoarchean atmosphere with much higher CO2 levels than previously estimated for Isua and in the

  19. Molecular-weight dependence of interchain polaron delocalization and exciton bandwidth in high-mobility conjugated polymers

    DEFF Research Database (Denmark)

    Chang, J.F.; Clark, J.; Zhao, N.

    2006-01-01

    here a detailed study of interchain interaction effects on both charged polarons as well as neutral excitons in highly crystalline, high-mobility poly-3-hexylthiophene (P3HT) as a function of molecular weight. We find experimental evidence for reduced exciton bandwidth and increased polaron...... delocalization with increasing conjugation length and crystalline quality. From comparative studies of field-effect transistor characteristics, film morphology, and optical properties our study provides a microscopic understanding of the factors which limit the charge transport in P3HT to field-effect mobilities...

  20. Polaron pair mediated triplet generation in polymer/fullerene blends

    KAUST Repository

    Dimitrov, Stoichko D.

    2015-03-04

    Electron spin is a key consideration for the function of organic semiconductors in light-emitting diodes and solar cells, as well as spintronic applications relying on organic magnetoresistance. A mechanism for triplet excited state generation in such systems is by recombination of electron-hole pairs. However, the exact charge recombination mechanism, whether geminate or nongeminate and whether it involves spin-state mixing is not well understood. In this work, the dynamics of free charge separation competing with recombination to polymer triplet states is studied in two closely related polymer-fullerene blends with differing polymer fluorination and photovoltaic performance. Using time-resolved laser spectroscopic techniques and quantum chemical calculations, we show that lower charge separation in the fluorinated system is associated with the formation of bound electron-hole pairs, which undergo spin-state mixing on the nanosecond timescale and subsequent geminate recombination to triplet excitons. We find that these bound electron-hole pairs can be dissociated by electric fields.

  1. Ultrafast Charge and Triplet State Formation in Diketopyrrolopyrrole Low Band Gap Polymer/Fullerene Blends: Influence of Nanoscale Morphology of Organic Photovoltaic Materials on Charge Recombination to the Triplet State

    Directory of Open Access Journals (Sweden)

    René M. Williams

    2017-01-01

    Full Text Available Femtosecond transient absorption spectroscopy of thin films of two types of morphologies of diketopyrrolopyrrole low band gap polymer/fullerene-adduct blends is presented and indicates triplet state formation by charge recombination, an important loss channel in organic photovoltaic materials. At low laser fluence (approaching solar intensity charge formation characterized by a 1350 nm band (in ~250 fs dominates in the two PDPP-PCBM blends with different nanoscale morphologies and these charges recombine to form a local polymer-based triplet state on the sub-ns timescale (in ~300 and ~900 ps indicated by an 1100 nm absorption band. The rate of triplet state formation is influenced by the morphology. The slower rate of charge recombination to the triplet state (in ~900 ps belongs to a morphology that results in a higher power conversion efficiency in the corresponding device. Nanoscale morphology not only influences interfacial area and conduction of holes and electrons but also influences the mechanism of intersystem crossing (ISC. We present a model that correlates morphology to the exchange integral and fast and slow mechanisms for ISC (SOCT-ISC and H-HFI-ISC. For the pristine polymer, a flat and unstructured singlet-singlet absorption spectrum (between 900 and 1400 nm and a very minor triplet state formation (5% are observed at low laser fluence.

  2. Polaron effects on the dc- and ac-tunneling characteristics of molecular Josephson junctions

    Science.gov (United States)

    Wu, B. H.; Cao, J. C.; Timm, C.

    2012-07-01

    We study the interplay of polaronic effect and superconductivity in transport through molecular Josephson junctions. The tunneling rates of electrons are dominated by vibronic replicas of the superconducting gap, which show up as prominent features in the differential conductance for the dc and ac current. For relatively large molecule-lead coupling, a features that appears when the Josephson frequency matches the vibron frequency can be identified with an over-the-gap structure observed by Marchenkov [Nat. Nanotech. 1748-338710.1038/nnano.2007.2182, 481 (2007)]. However, we are more concerned with the weak-coupling limit, where resonant tunneling through the molecular level dominates. We find that certain features involving both Andreev reflection and vibron emission show an unusual shift of the bias voltage V at their maximum with the gate voltage Vg as V˜(2/3)Vg. Moreover, due to the polaronic effect, the ac Josephson current shows a phase shift of π when the bias eV is increased by one vibronic energy quantum ℏωv. This distinctive even-odd effect is explained in terms of the different sign of the coupling to vibrons of electrons and of Andreev-reflected holes.

  3. Appearance of small polaron hopping conduction in iron modified cobalt lithium bismuth borate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Dahiya, M. S.; Khasa, S., E-mail: skhasa@yahoo.com; Yadav, Arti [Physics Department, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, India-131039 (India); Agarwal, A. [Applied Physics Department, Guru Jambheshwara University of Science and Technology, Hisar, India-125001 (India)

    2016-05-23

    Lithium bismuth borate glasses containing different amounts of cobalt and iron oxides having chemical composition xFe{sub 2}O{sub 3}•(20-x)CoO•30Li{sub 2}O•10Bi{sub 2}O{sub 3}•40B{sub 2}O{sub 3} (x = 0, 5, 10, 15 and 20 mol% abbreviated as CFLBB1-5 respectively) prepared via melt quench technique have been investigated for their dc electrical conductivity. The amorphous nature of prepared glasses has been confirmed through X-ray diffraction measurements. The dc electrical conductivity has been analyzed by applying Mott’s small polaron hopping model. Activation energies corresponding to lower and higher temperature region have been evaluated. The iron ion concentration (N), mean spacing between iron ions (R) and polaron radius (R{sub p}) has been evaluated using the values of phonon radius (R{sub ph}) and Debye temperature (θ{sub D}). The glass sample without iron (CFLBB1) shows ionic conductivity but the incorporation of iron in the glass matrix results in the appearance of electronic conductivity.

  4. Multi-impurity polarons in a dilute Bose-Einstein condensate

    International Nuclear Information System (INIS)

    Santamore, D H; Timmermans, Eddy

    2011-01-01

    We describe the ground state of a large, dilute, neutral atom Bose-Einstein condensate (BEC) doped with N strongly coupled mutually indistinguishable, bosonic neutral atoms (referred to as ‘impurity’) in the polaron regime where the BEC density response to the impurity atoms remains significantly smaller than the average density of the surrounding BEC. We find that N impurity atoms with N ≠ 1 can self-localize at a lower value of the impurity-boson interaction strength than a single impurity atom. When the ‘bare’ short-range impurity-impurity repulsion does not play a significant role, the self-localization of multiple bosonic impurity atoms into the same single particle orbital (which we call co-self-localization) is the nucleation process of the phase separation transition. When the short-range impurity-impurity repulsion successfully competes with co-self-localization, the system may form a stable liquid of self-localized single impurity polarons. (paper)

  5. Observation of magnetic polarons in the magnetoresistive pyrochlore Lu2V2O7

    International Nuclear Information System (INIS)

    Storchak, Vyacheslav G; Brewer, Jess H; Eshchenko, Dmitry G; Mengyan, Patrick W; Zhou Haidong; Wiebe, Christopher R

    2013-01-01

    Materials that exhibit colossal magnetoresistance (CMR) have attracted much attention due to their potential technological applications. One particularly interesting model for the magnetoresistance of low-carrier-density ferromagnets involves mediation by magnetic polarons (MP)—electrons localized in nanoscale ferromagnetic ‘droplets’ by their exchange interaction. However, MP have not previously been directly detected and their size has been difficult to determine from macroscopic measurements. In order to provide this crucial information, we have carried out muon spin rotation measurements on the magnetoresistive semiconductor Lu 2 V 2 O 7 in the temperature range from 2 to 300 K and in magnetic fields up to 7 T. Magnetic polarons with characteristic radius R ≈ 0.4 nm are detected below about 100 K, where Lu 2 V 2 O 7 exhibits CMR; at higher temperature, where the magnetoresistance vanishes, these MP also disappear. This observation confirms the MP-mediated model of CMR and reveals the microscopic size of the MP in magnetoresistive pyrochlores. (paper)

  6. Morphologies of omega band auroras

    Science.gov (United States)

    Sato, Natsuo; Yukimatu, Akira Sessai; Tanaka, Yoshimasa; Hori, Tomoaki

    2017-08-01

    We examined the morphological signatures of 315 omega band aurora events observed using the Time History of Events and Macroscale Interactions during Substorm ground-based all-sky imager network over a period of 8 years. We find that omega bands can be classified into the following three subtypes: (1) classical (O-type) omega bands, (2) torch or tongue (T-type) omega bands, and (3) combinations of classical and torch or tongue (O/T-type) omega bands. The statistical results show that T-type bands occur the most frequently (45%), followed by O/T-type bands (35%) and O-type bands (18%). We also examined the morphologies of the omega bands during their formation, from the growth period to the declining period through the maximum period. Interestingly, the omega bands are not stable, but rather exhibit dynamic changes in shape, intensity, and motion. They grow from small-scale bumps (seeds) at the poleward boundary of preexisting east-west-aligned auroras, rather than via the rotation or shear motion of preexisting east-west-aligned auroras, and do not exhibit any shear motion during the periods of auroral activity growth. Furthermore, the auroral luminosity is observed to increase during the declining period, and the total time from the start of the growth period to the end of the declining period is found to be about 20 min. Such dynamical signatures may be important in determining the mechanism responsible for omega band formation.

  7. Parton Theory of Magnetic Polarons: Mesonic Resonances and Signatures in Dynamics

    Science.gov (United States)

    Grusdt, F.; Kánasz-Nagy, M.; Bohrdt, A.; Chiu, C. S.; Ji, G.; Greiner, M.; Greif, D.; Demler, E.

    2018-01-01

    When a mobile hole is moving in an antiferromagnet it distorts the surrounding Néel order and forms a magnetic polaron. Such interplay between hole motion and antiferromagnetism is believed to be at the heart of high-temperature superconductivity in cuprates. In this article, we study a single hole described by the t -Jz model with Ising interactions between the spins in two dimensions. This situation can be experimentally realized in quantum gas microscopes with Mott insulators of Rydberg-dressed bosons or fermions, or using polar molecules. We work at strong couplings, where hole hopping is much larger than couplings between the spins. In this regime we find strong theoretical evidence that magnetic polarons can be understood as bound states of two partons, a spinon and a holon carrying spin and charge quantum numbers, respectively. Starting from first principles, we introduce a microscopic parton description which is benchmarked by comparison with results from advanced numerical simulations. Using this parton theory, we predict a series of excited states that are invisible in the spectral function and correspond to rotational excitations of the spinon-holon pair. This is reminiscent of mesonic resonances observed in high-energy physics, which can be understood as rotating quark-antiquark pairs carrying orbital angular momentum. Moreover, we apply the strong-coupling parton theory to study far-from-equilibrium dynamics of magnetic polarons observable in current experiments with ultracold atoms. Our work supports earlier ideas that partons in a confining phase of matter represent a useful paradigm in condensed-matter physics and in the context of high-temperature superconductivity in particular. While direct observations of spinons and holons in real space are impossible in traditional solid-state experiments, quantum gas microscopes provide a new experimental toolbox. We show that, using this platform, direct observations of partons in and out of equilibrium are

  8. Anoxygenic growth of cyanobacteria on Fe(II) and their associated biosignatures: Implications for biotic contributions to Precambrian Banded Iron Formations

    Science.gov (United States)

    Parenteau, M.; Jahnke, L. L.; Cady, S. L.; Pierson, B.

    2011-12-01

    Banded Iron Formations (BIFs) are widespread Precambrian sedimentary deposits that accumulated in deep ocean basins or shallow platformal areas with inputs of reduced iron (Fe(II)) and silica from deep ocean hydrothermal activity. There is debate as to whether abiotic or biotic mechanisms were responsible for the oxidation of aqueous Fe(II) and the subsequent accumulation of ferric iron (Fe(III)) mineral assemblages in BIFs. Biotic Fe(II) oxidation could have occurred indirectly as a result of the photosynthetic production of oxygen by cyanobacteria, or could have been directly mediated by anoxygenic phototrophs or chemolithotrophs. The anoxygenic use of Fe(II) as an electron donor for photosynthesis has also been hypothesized in cyanobacteria, representing another biotic mechanism by which Fe(II) could be oxidized in BIFs. This type of photoferrotrophic metabolism may also represent a key step in the evolution of oxygenic photosynthesis. Members of our group have speculated that an intermediate reductant such as Fe(II) could have acted as a transitional electron donor before water. The widespread abundance of Fe(II) in Archean and Neoproterozoic ferruginous oceans would have made it particularly suitable as an electron donor for photosynthesis. We have been searching for modern descendants of such an ancestral "missing link" cyanobacterium in the phototrophic mats at Chocolate Pots, a hot spring in Yellowstone National Park with a constant outflow of anoxic Fe(II)-rich thermal water. Our physiological ecology study of the Synechococcus-Chloroflexi mat using C-14 bicarbonate uptake and autoradiography experiments revealed that the cyanobacteria grow anoxygenically using Fe(II) as an electron donor for photosynthesis in situ. An initial set of similar experiments substituting C-13 bicarbonate as the tracer was used to characterize labeling of the community lipid biomarker signature and confirm the C-14 results. Under light conditions with and without Fe(II), the C

  9. Characterization and component tracing of Banded Iron Formations deposited during the ~2.7 Ga superplume event: An example from the Tati Greenstone Belt, Northeastern Botswana

    Science.gov (United States)

    Døssing, L. N.; Frei, R.; Stendal, H.; Mapeo, R. B.

    2008-12-01

    Major and trace element, samarium (Sm)-neodymium (Nd) and lead (Pb) isotopic analyses of individual mesobands of five Banded Iron Formations (BIFs) and associated metavolcanic and metasedimentary rocks from the Neoarchean Tati Greenstone Belt (TGB, Northeastern Botswana) were conducted in order to characterize and determine the source(s) and depositional environment(s) of these chemical sediments and to compare their features with other Archean BIFs. Rare earth element (REE)-yttrium (Y) patterns of individual BIF mesobands from the TGB show features characteristic of other Archean BIFs; these are (relative to Post Archean Australian Shale (PAAS) normalization), LREE depletions relative to MREE and HREE, positive lanthanum La/La*PAAS, europium Eu/Eu*PAAS, and Y/holmium (Ho) ratios. The TGB BIFs also lack defined cerium Ce/Ce*PAAS anomalies. Generally, the REY patterns are similar to modern seawater and together with low concentrations of high-field strength elements these features are indicative of an essentially detritus-free precipitation. Uranogenic Pb isotope data for the BIFs define individual correlation lines with slopes corresponding to apparent ages of ~2.7 Ga, interpreted as closely reflecting the depositional time frames. An exception to this are the BIFs at Mupane mine in the central part of the TGB which exhibit disturbed U-Pb isotope systematics. They indicate a pronounced resetting around 2.0 Ga. This is also reflected by Pb isotope data of gold-bearing sulfides and Pb-stepwise leaching (PbSL) data of garnets from associated metasedimentary rocks at this location. The garnet PbSL data define a correlation line in uranogenic Pb isotope space with a slope corresponding to an apparent age of 1976±88 Ma. This age is interpreted as a metamorphic age that can be correlated with ~2.0 Ga tectono- metamorphic events within the adjacent Limpopo orogenic belt, and which apparently have, also affected parts of the adjacent Zimbabwe craton to the north. Elevated

  10. Hurricane Spiral Bands.

    Science.gov (United States)

    Guinn, Thomas A.; Schubert, Wayne H.

    1993-10-01

    The spiral bands that occur in tropical cyclones can be conveniently divided into two classes-outer bands and inner bands. Evidence is presented here that the outer bands form as the result of nonlinear effects during the breakdown of the intertropical convergence zone (ITCZ) through barotropic instability. In this process a zonal strip of high potential vorticity (the ITCZ shear zone or monsoon trough) begins to distort in a varicose fashion, with the potential vorticity (PV) becoming pooled in local regions that are connected by filaments of high PV. As the pooled regions become more axisymmetric, the filaments become thinner and begin to wrap around the PV centers.It is argued that inner bands form in a different manner. As a tropical cyclone intensifies due to latent heat release, the PV field becomes nearly circular with the highest values of PV in the cyclone center. The radial gradient of PV provides a state on which PV waves (the generalization of Rossby waves) can propagate. The nonlinear breaking of PV waves then leads to an irreversible distortion of the PV contours and a downgradient flux of PV. The continuation of this proem tends to erode the high PV core of the tropical cyclone, to produce a surrounding surf zone, and hence to spread the PV horizontally. In a similar fashion, inner bands can also form by the merger of a vortex with a patch of relatively high PV air. As the merger proem occurs the patch of PV is quickly elongated and wrapped around the vortex. The resulting vortex is generally larger in horizontal extent and exhibits a spiral band of PV.When the formation of outer and inner bands is interpreted in the context of a normal-mode spectral model, they emerge as slow manifold phenomena; that is, they have both rotational and (balanced or slaved) gravitational mode aspects. In this sense, regarding them as simply gravity waves leads to an incomplete dynamical picture.

  11. Femtosecond dynamics of excitons and hole-polarons in composite P3HT/PCBM nanoparticles.

    Science.gov (United States)

    Clafton, Scott N; Huang, David M; Massey, William R; Kee, Tak W

    2013-04-25

    The dynamics of charge separation in aqueous suspensions of regioregular P3HT nanoparticles containing PCBM were investigated for the first time using femtosecond transient absorption spectroscopy. This investigation is supported by the recently reported use of regioregular P3HT/PCBM nanoparticles as charge trapping and storage devices. In this study, the presence of excited-state and charge-separated species, including singlet excitons, polymer polarons and free charges, generated in rr-P3HT/PCBM nanoparticles was identified through visible pump and visible/near-infrared probe femtosecond transient absorption spectroscopy at a range of electron acceptor concentrations. The decrease of the singlet exciton lifetime by charge transfer to PCBM is well described by a one-dimensional diffusion model with a P3HT domain size of approximately 5 nm for 5-50 wt % PCBM. This model also indicates that bimolecular recombination is the dominant charge recombination mechanism at 20 wt % PCBM and above.

  12. L’impossible seconde vie ? Le poids des standards éditoriaux et la résistance de la bande dessinée franco-belge au format de poche

    Directory of Open Access Journals (Sweden)

    Sylvain Lesage

    2011-07-01

    Full Text Available Si le livre de poche a joué un rôle central dans la diffusion du patrimoine littéraire, la bande dessinée ne dispose pas de cet outil permettant la constitution d’un corpus de classiques aisément accessibles au plus grand nombre. En ceci, la bande dessinée constitue bien une véritable exception dans le champ éditorial français, par la quasi-absence de collections permettant de republier des classiques en format de poche. L’importance de l’image et l’impératif de lisibilité compliquent en effet le problème de l’adaptation du « grand format » vers le poche, mais demeurent insuffisants pour comprendre la réticence de la bande dessinée au poche. Le présent article propose un retour en arrière sur les expériences des années 1980-1990, afin de mieux cerner cette singularité éditoriale.

  13. When polarons meet polaritons: Exciton-vibration interactions in organic molecules strongly coupled to confined light fields

    Science.gov (United States)

    Wu, Ning; Feist, Johannes; Garcia-Vidal, Francisco J.

    2016-11-01

    We present a microscopic semianalytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing by employing a temperature-dependent variational approach. The interplay between strong exciton-vibration coupling and strong exciton-cavity coupling gives rise to a hybrid ground state, which we refer to as the lower polaron polariton. Explicit expressions for the ground-state wave function, the zero-temperature quasiparticle weight of the lower polaron polariton, the photoluminescence line strength, and the mean number of vibrational quanta are obtained in terms of the optimal variational parameters. The dependence of these quantities upon the exciton-cavity coupling strength reveals that strong cavity coupling leads to an enhanced vibrational dressing of the cavity mode, and at the same time a vibrational decoupling of the dark excitons, which in turn results in a lower polaron polariton resembling a single-mode dressed bare lower polariton in the strong-coupling regime. Thermal effects on several observables are briefly discussed.

  14. Polaronic and bipolaronic structures in the adiabatic Hubbard-Holstein model involving 2 electrons and its extensions

    International Nuclear Information System (INIS)

    Proville, L.

    1998-01-01

    This thesis brings its contribution to the bipolaronic theory which might explain the origin of superconductivity at high temperature. A polaron is a quasiparticle made up of a localized electron and a deformation in the crystal structure. 2 electrons in singlet states localized on the same site form a bipolaron. Whenever the Coulomb repulsion between the 2 electrons is too strong bipolaron turns into 2 no bound polarons. We study the existence and the mobility of bipolarons. We describe the electron-phonon interaction by the Holstein term and the Coulomb repulsion by the Hubbard term. 2 assumptions are made: - the local electron-phonon interaction is strong and opposes the Coulomb repulsion between Hubbard type electrons - the system is close to the adiabatic limit. The system is reduced to 2 electrons in order to allow an exact treatment and the investigation of some bipolaronic bound states. At 2-dimensions the existence of bipolarons requires a very strong coupling which forbids any classical mobility. In some cases an important tunneling effect appears and we show that mobile bipolarons exist in a particular parameter range. Near the adiabatic limit we prove that polaronic and bipolaronic structures exist for a great number of electrons. (A.C.)

  15. Spin dynamics and spin-dependent recombination of a polaron pair under a strong ac drive

    Science.gov (United States)

    Malla, Rajesh K.; Raikh, M. E.

    2017-08-01

    We study theoretically the recombination within a pair of two polarons in magnetic field subject to a strong linearly polarized ac drive. Strong drive implies that the Zeeman frequencies of the pair partners are much smaller than the Rabi frequency, so that the rotating wave approximation does not apply. What makes the recombination dynamics nontrivial is that the partners recombine only when they form a singlet S . By admixing singlet to triplets, the drive induces the triplet recombination as well. We calculate the effective decay rate of all four spin modes. Our main finding is that, under the strong drive, the major contribution to the decay of the modes comes from short time intervals when the driving field passes through zero. When the recombination time in the absence of drive is short, fast recombination from S leads to anomalously slow recombination from the other spin states of the pair. We show that, with strong drive, this recombination becomes even slower. The corresponding decay rate falls off as a power law with the amplitude of the drive.

  16. Energy levels of an anisotropic three-dimensional polaron in a magnetic field

    International Nuclear Information System (INIS)

    Brancus, D. E. N.; Stan, G.

    2001-01-01

    In the context of the improved Wigner-Brillouin theory, the energy levels are found of a Frohlich polaron in a uniaxial anisotropic polar semiconductor with complex structure, placed in a magnetic field directed either along the optical axis or orthogonal to it. All sources of anisotropy that are contained in the shape of constant-energy surfaces of the bare electron, the electron - optical-phonon interaction, and the frequency spectrum of the extraordinary phonon modes are considered. Analytical results for the electron-phonon interaction correction to the Landau levels below the optical-phonon continuum are given and, numerical results for the magnetic-field dependence of the cyclotron resonance frequency at low temperature are presented for the particular case of the layered semiconductors InSe and GaSe. Although the interaction between the bare electron and quasitransverse optical-phonon modes is weak, these modes play an important role in the pinning of Landau levels. The results given by Das Sarma for a two-dimensional isotropic magnetopolaron are generalized to the anisotropic uniaxial case by taking formally m # parallel→infinity# in the expression of the perturbed Landau levels found when the magnetic field is directed along the optical axis, m # parallel# being the component of the bare-electron effective-mass tensor along the optical axis

  17. Bound magnetic polaron in Zn-rich cobalt-doped ZnSe nanowires

    Science.gov (United States)

    Hou, Lipeng; Pan, Longfei; Liang, Bianbian; Liu, Yuting; Zhang, Li; Bukhtiar, Arfan; Shi, Lijie; Liu, Ruibin; Zou, Bingsuo

    2018-02-01

    The micro-luminescence spectra of the diluted magnetic semiconductor (DMS) can reflect the spin-exciton interaction and related relaxation process. Here the micro-photoluminescence (micro-PL) spectra and PL lifetime measurements have been done on an individual ferromagnetic (FM)-coupled cobalt (Co) doped zinc selenide (ZnSe) nanowire. There occurs a double-peak profile in its near bandedge emission spectrum: the first peak is from free exciton (FX) and the second comes from magnetic polaron (MP). In their temperature dependent PL spectra, the MP emission peak demonstrates obviously temperature-independent behavior, in contrast to the behaviors of FX and reported exciton MP in nanobelt. It is found that in this Co(II) doped ZnSe nanowires, this MP’s temperature-independent emission is related to the coupling between exciton and a FM nanocluster (↑↑↓). The nanocluster is likely due to the interaction of Se vacancies of the wide bandgap semiconductors with the antiferromagnetic (AFM) arrangement transition metal (TM) ions in these Se-deficient Co doped ZnSe nanowires. These results reflect that the AFM coupling TM ions pair can give rise to FM behavior with the involvement of positive charge defect, also indicating that the micro-luminescence detection can be used to study the magnetic coupling in DMS.

  18. Polaron theory of mid-infrared conductivity a numerical cluster solution

    Science.gov (United States)

    Alexandrov, A. S.; Kabanov, V. V.; Ray, D. K.

    1994-05-01

    Mid-infrared spectra are obtained with numerical calculations of the optical conductivity σ(ω) of a finite-size Holstein model. The results show that the analytic formula of Reik for the optical conductivity is valid only in a strong electron-phonon coupling regime. σ(ω) shows a number of peaks corresponding to the bound states of polarons with a different number of phonons. Calculation of σ(ω) has also been done in the adiabatic limit in the one-dimensional case. It is found that for intermediate coupling the peak in σ(ω) is strongly asymmetric. The optical conductivity of the two-site model in the presence of two electrons is studied. Numerical results show a shift of the peak in σ(ω) to the low-energy region with an increasing Hubbard U for the strong electron-phonon interaction (E p>U) whereas the peak moves to the high-energy region for U>E p high-energy region starts to develop in the large U limit in the presence of phonons. The significance of these calculations for the experimental observations of the mid-infrared spectra of high- Tc cuprates is discussed.

  19. Electron transport in pure and substituted iron oxyhydroxides by small-polaron migration

    Energy Technology Data Exchange (ETDEWEB)

    Alexandrov, Vitaly, E-mail: vitali.alexandrov@pnnl.gov; Rosso, Kevin M. [Physical Sciences Division, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

    2014-06-21

    Iron oxyhydroxides (FeOOH) are common crystalline forms of iron that play a critical role in technology and the natural environment via a variety of important reduction-oxidation reactions, including electrical semiconduction as an aspect. However, a basic understanding of the electron transport properties of these systems is still lacking. We examine the electron mobility in goethite (α-FeOOH), akaganéite (β-FeOOH), and lepidocrocite (γ-FeOOH) polymorphs by means of density functional theory based (DFT+U) calculations. We show that room temperature charge transport should be dominated by the small-polaron hopping type, and that the attendant mobility should be highest for pure goethite and akaganéite. Hopping pathways through the various lattices are discussed in terms of individual electron exchange steps and rates for each. Given the usual occurrence of compositional impurities in natural iron oxyhydroxides, we also investigate the effect of common stoichiometric defects on the electron hopping activation energies such as Al and Cr substitutional cations in goethite, and Cl anions in the channels of akaganéite.

  20. Nanophase Iron Oxides as an Ultraviolet Sunscreen for Ancient Photosynthetic Microbes: A Possible Link Between Early Organisms, Banded-Iron Formations, and the Oxygenation of the Atmosphere

    Science.gov (United States)

    Bishop, Janice L.; Rothschild, Lynn J.; Rothschild, Lynn J.; Rogoff, Dana A.

    2006-01-01

    We propose that nanophase iron oxide-bearing materials provided important niches for ancient photosynthetic microbes on the early Earth that ultimately led to the oxygenation of the Earth s atmosphere and the formation of iron oxide deposits. Atmospheric oxygen and ozone attenuate UV radiation on the Earth today providing substantial protection for photosynthetic organisms. With ultraviolet radiation fluxes likely to have been even higher on the early Earth than today, accessing solar radiation was particularly risky for early organisms. Yet, we know that photosynthesis arose then and played a critical role in subsequent evolution. Of primary importance was protection at approx.250-290 nm, where peak nucleic acid (approx.260 nm) and protein (approx.280 nm) absorptions occur. Nanophase ferric oxide/oxyhydroxide minerals absorb, and thus block, the lethal UV radiation, while transmitting light through much of the visible and near-infrared regions of interest to photosynthesis (400 to 1100 nm). Further, they were available in early environments, and are synthesized by many organisms. Based on ferric oxide/oxyhydroxide spectral properties, likely geologic processes, and the results of experiments with the photosynthetic organisms, Euglena sp. and Chlumydomonus reinhardtii, we propose a scenario where photosynthesis, and ultimately the oxygenation of the atmosphere, depended on the protection of early microbes by nanophase ferric oxides/oxyhydroxides. The results of this study are also applicable to other potentially habitable iron-bearing planetary bodies because of the evolutionary pressure to utilize solar radiation when available as an energy source.

  1. The effect of impurity on transition frequency of bound polaron in ...

    Indian Academy of Sciences (India)

    et al [16] used photoacoustic method to measure the optical absorption properties of as- prepared CdSe QRs. Employing scanning tunnelling microscopy technique, Talaat et al. [17] determined the energy band gap of a series of CdSe QR having different sizes at room temperature. Their results confirmed that the band ...

  2. New Kronig-Penney Equation Emphasizing the Band Edge Conditions

    Science.gov (United States)

    Szmulowicz, Frank

    2008-01-01

    The Kronig-Penney problem is a textbook example for discussing band dispersions and band gap formation in periodic layered media. For example, in photonic crystals, the behaviour of bands next to the band edges is important for further discussions of such effects as inhibited light emission, slow light and negative index of refraction. However,…

  3. Methodology for determination of trace elements in mineral phases of iron banded formation by LA-ICP-MS; Metodologia de determinacao de elementos-traco em fases minerais de formacoes ferriferas bandadas por LA-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Denise V.M. de; Nalini Junior, Herminio A.; Sampaio, Geraldo M.S.; Abreu, Adriana T. de; Lana, Cristiano de C., E-mail: deniseversiane2@yahoo.com.br, E-mail: nalini@degeo.ufop.br, E-mail: geraldomssampaio@gmail.com, E-mail: adrianatropia@gmail.com, E-mail: cristianodeclana@gmail.com [Universidade Federal de Ouro Preto (DEGEO/UFOP), Ouro Preto, MG (Brazil). Departamento de Geologia

    2015-07-01

    The study of the chemical composition of mineral phases of iron formation (FF), especially of trace elements, is an important tool in the understanding of the genesis of these rocks and the contribution of the phases in the composition of whole rock. Low mass fraction of such elements in the mineral phases present in this rock type requires a suitable analytical procedure. The laser ablation technique coupled with ICP-MS (LA-ICP-MS) has been widely used for determination of trace elements in geological samples. Thus, the aim of this study is to develop calibration curves for determination of trace elements (Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) in mineral phases of banded iron formations by LA-ICP-MS. Several certified reference materials (CRM) were used for calibrate the equipment. The analytical conditions were checked by CRM NIST SRM 614. The results were satisfactory, since the curves showed good linearity coefficients, good accuracy and precision of results. (author)

  4. HYBASE : HYperspectral BAnd SElection

    NARCIS (Netherlands)

    Schwering, P.B.W.; Bekman, H.H.P.T.; Seijen, H.H. van

    2009-01-01

    Band selection is essential in the design of multispectral sensor systems. This paper describes the TNO hyperspectral band selection tool HYBASE. It calculates the optimum band positions given the number of bands and the width of the spectral bands. HYBASE is used to assess the minimum number of

  5. Role of polaron hopping in leakage current behavior of a SrTiO{sub 3} single crystal

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Y., E-mail: yxc238@psu.edu; Randall, C. A.; Chen, L. Q. [Department of Materials Science and Engineering, Penn State University, University Park, Pennsylvania 16802 (United States); Bhattacharya, S. [Department of Materials Science and Engineering, Indian Institute of Technology Hyderabad, YM 502205 (India); Shen, J. [Department of Mathematics, Purdue University, West Lafayette, Indiana 47907 (United States)

    2013-12-14

    We studied the ionic/electronic transport and resistance degradation behavior of dielectric oxides by solving the electrochemical transport equations. Here, we took into account the non-periodical boundary conditions for the transport equations using the Chebyshev collocation algorithm. A sandwiched Ni|SrTiO{sub 3}|Ni capacitor is considered as an example under the condition of 1.0 V, 1.0 μm thickness for SrTiO{sub 3} layer, and a temperature of 150 °C. The applied voltage resulted in the migration of ionic defects (oxygen vacancies) from anode towards cathode. The simulated electric potential profile at steady state is in good agreement with the recent experimental observation. We introduced the possibility of polaron-hopping between Ti{sup 3+} and Ti{sup 4+} at the electrode interface. It is shown that both the oxygen vacancy transport and the polaron-hopping contribute to the resistance degradation of single crystal SrTiO{sub 3}, which is consistent with the experimental observations.

  6. Chemical fingerprint of iron oxides related to iron enrichment of banded iron formation from the Cauê Formation - Esperança Deposit, Quadrilátero Ferrífero, Brazil: a laser ablation ICP-MS study

    Directory of Open Access Journals (Sweden)

    Lucilia Aparecida Ramos de Oliveira

    Full Text Available Chemical signatures of iron oxides from dolomitic itabirite and high-grade iron ore from the Esperança deposit, located in the Quadrilátero Ferrífero, indicate that polycyclic processes involving changing of chemical and redox conditions are responsible for the iron enrichment on Cauê Formation from Minas Supergroup. Variations of Mn, Mg and Sr content in different generations of iron oxides from dolomitic itabirite, high-grade iron ore and syn-mineralization quartz-carbonate-hematite veins denote the close relationship between high-grade iron ore formation and carbonate alteration. This indicates that dolomitic itabirite is the main precursor of the iron ore in that deposit. Long-lasting percolation of hydrothermal fluids and shifts in the redox conditions have contributed to changes in the Y/Ho ratio, light/heavy rare earth elements ratio and Ce anomaly with successive iron oxide generations (martite-granular hematite, as well as lower abundance of trace elements including rare earth elements in the younger specularite generations.

  7. Ultrafast Dynamics of Localized and Delocalized Polaron Transitions in P3HT/PCBM Blend Materials: The Effects of PCBM Concentration

    Directory of Open Access Journals (Sweden)

    Alexandrou Ioannis

    2009-01-01

    Full Text Available Abstract Nowadays, organic solar cells have the interest of engineers for manufacturing flexible and low cost devices. The considerable progress of this nanotechnology area presents the possibility of investigating new effects from a fundamental science point of view. In this letter we highlight the influence of the concentration of fullerene molecules on the ultrafast transport properties of charged electrons and polarons in P3HT/PCBM blended materials which are crucial for the development of organic solar cells. Especially, we report on the femtosecond dynamics of localized (P2at 1.45 eV and delocalized (DP2at 1.76 eV polaron states of P3HT matrix with the addition of fullerene molecules as well as the free-electron relaxation dynamics of PCBM-related states. Our study shows that as PCBM concentration increases, the amplified exciton dissociation at bulk heterojunctions leads to increased polaron lifetimes. However, the increase in PCBM concentration can be directly related to the localization of polarons, creating thus two competing trends within the material. Our methodology shows that the effect of changes in structure and/or composition can be monitored at the fundamental level toward optimization of device efficiency.

  8. DFT+U study of self-trapping, trapping, and mobility of oxygen-type hole polarons in barium stannate

    Science.gov (United States)

    Geneste, Grégory; Amadon, Bernard; Torrent, Marc; Dezanneau, Guilhem

    2017-10-01

    The charge-transfer insulating perovskite oxides currently used as fuel cell electrolytes undergo, at high temperature, an oxidation reaction 1/2 O2(g ) +VO••→OOX+2 h• , that produces oxygen-type holes. Understanding the nature and mobility of these oxygen-type holes is an important step to improve the performance of devices, but presents a theoretical challenge since, in their localized form, they cannot be captured by standard density functional theory. Here, we employ the DFT+U formalism with a Hubbard correction on the p orbitals of oxygen to investigate several properties of these holes, in the particular case of BaSnO3. We describe the small oxygen-type hole polarons, the self-trapping at their origin, and their trapping by trivalent dopants (Ga, Sc, In, Lu, Y, Gd, La). Strong similarities with protonic defects are observed concerning the evolution of the trapping energy with ionic radius of the dopant. Moreover, we show that long-range diffusion of holes is a complex phenomenon, that proceeds by a succession of several mechanisms. However, the standard implementation of DFT+U within the projector augmented-wave (PAW) formalism leads to use very large, unphysical values of U for the O-p orbital. We propose here a slightly modified DFT+U scheme, that takes into account the fact that the O-p is truncated in usual DFT+U implementation in PAW. This scheme yields more physical values of U than the ones traditionally used in the literature, and describes well the properties of the hole polaron.

  9. Effect of doping Ca on polaron hopping in LaSr2Mn2O7

    Indian Academy of Sciences (India)

    S(=Um) between the localized t2g electrons (with spin S) and the spin (s) of the eg electrons form- ing the conduction band is responsible for this localization of the carriers. The temperature dependence of resistivity is predicted to be.

  10. Polygonal deformation bands in sandstone

    Science.gov (United States)

    Antonellini, Marco; Nella Mollema, Pauline

    2017-04-01

    We report for the first time the occurrence of polygonal faults in sandstone, which is compelling given that layer-bound polygonal fault systems have been observed so far only in fine-grained sediments such as clay and chalk. The polygonal faults are dm-wide zones of shear deformation bands that developed under shallow burial conditions in the lower portion of the Jurassic Entrada Fm (Utah, USA). The edges of the polygons are 1 to 5 meters long. The shear deformation bands are organized as conjugate faults along each edge of the polygon and form characteristic horst-like structures. The individual deformation bands have slip magnitudes ranging from a few mm to 1.5 cm; the cumulative average slip magnitude in a zone is up to 10 cm. The deformation bands heaves, in aggregate form, accommodate a small isotropic horizontal extension (strain Crosscutting relationships are rare. The interactions of the deformation bands are similar to those of mode I opening fractures. Density inversion, that takes place where under-compacted and over-pressurized layers (Carmel Fm) lay below normally compacted sediments (Entrada Sandstone), may be an important process for polygonal deformation bands formation. The gravitational sliding and soft sediment structures typically observed within the Carmel Fm support this hypothesis. Soft sediment deformation may induce polygonal faulting in the section of the Entrada Sandstone just above the Carmel Fm. The permeability of the polygonal deformation bands is approximately 10-14 to 10-13 m2, which is less than the permeability of the host, Entrada Sandstone (range 10-12 to 10-11 m2). The documented fault networks have important implications for evaluating the geometry of km-scale polygonal fault systems in the subsurface, top seal integrity, as well as constraining paleo-tectonic stress regimes.

  11. Band structure of semiconductors

    CERN Document Server

    Tsidilkovski, I M

    2013-01-01

    Band Structure of Semiconductors provides a review of the theoretical and experimental methods of investigating band structure and an analysis of the results of the developments in this field. The book presents the problems, methods, and applications in the study of band structure. Topics on the computational methods of band structure; band structures of important semiconducting materials; behavior of an electron in a perturbed periodic field; effective masses and g-factors for the most commonly encountered band structures; and the treatment of cyclotron resonance, Shubnikov-de Haas oscillatio

  12. The width of Liesegang bands: A study using moving boundary ...

    Indian Academy of Sciences (India)

    The pattern formation in reaction–diffusion systems was studied by invoking the provisions contained in the moving boundary model. The model claims that the phase separation mechanism is responsible for separating the colloidal phase of precipitants into band and non-band regions. The relation between the band ...

  13. Degradation Mechanisms in Blue Phosphorescent Organic Light-Emitting Devices by Exciton-Polaron Interactions: Loss in Quantum Yield versus Loss in Charge Balance.

    Science.gov (United States)

    Zhang, Yingjie; Aziz, Hany

    2017-01-11

    We study the relative importance of deterioration of material quantum yield and charge balance to the electroluminescence stability of PHOLEDs, with a special emphasis on blue devices. Investigations show that the quantum yields of both host and emitter in the emission layer degrade due to exciton-polaron interactions and that the deterioration in material quantum yield plays the primary role in device degradation under operation. On the other hand, the results show that the charge balance factor is also affected by exciton-polaron interactions but only plays a secondary role in determining device stability. Finally, we show that the degradation mechanisms in blue PHOLEDs are fundamentally the same as those in green PHOLEDs. The limited stability of the blue devices is a result of faster deterioration in the quantum yield of the emitter.

  14. Linear and non-linear infrared response of one-dimensional vibrational Holstein polarons in the anti-adiabatic limit: Optical and acoustical phonon models

    Science.gov (United States)

    Falvo, Cyril

    2018-02-01

    The theory of linear and non-linear infrared response of vibrational Holstein polarons in one-dimensional lattices is presented in order to identify the spectral signatures of self-trapping phenomena. Using a canonical transformation, the optical response is computed from the small polaron point of view which is valid in the anti-adiabatic limit. Two types of phonon baths are considered: optical phonons and acoustical phonons, and simple expressions are derived for the infrared response. It is shown that for the case of optical phonons, the linear response can directly probe the polaron density of states. The model is used to interpret the experimental spectrum of crystalline acetanilide in the C=O range. For the case of acoustical phonons, it is shown that two bound states can be observed in the two-dimensional infrared spectrum at low temperature. At high temperature, analysis of the time-dependence of the two-dimensional infrared spectrum indicates that bath mediated correlations slow down spectral diffusion. The model is used to interpret the experimental linear-spectroscopy of model α-helix and β-sheet polypeptides. This work shows that the Davydov Hamiltonian cannot explain the observations in the NH stretching range.

  15. Mobility balance in the light-emitting layer governs the polaron accumulation and operational stability of organic light-emitting diodes

    Science.gov (United States)

    Kim, Jae-Min; Lee, Chang-Heon; Kim, Jang-Joo

    2017-11-01

    Organic light-emitting diode (OLED) displays are lighter and more flexible, have a wider color gamut, and consume less power than conventional displays. Stable materials and the structural design of the device are important for OLED longevity. Control of charge transport and accumulation in the device is particularly important because the interaction of excitons and polarons results in material degradation. This research investigated the charge dynamics of OLEDs experimentally and by drift-diffusion modeling. Parallel capacitance-voltage measurements of devices provided knowledge of charge behavior at different driving voltages. A comparison of exciplex-forming co-host and single host structures established that the mobility balance in the emitting layers determined the amount of accumulated polarons in those layers. Consequently, an exciplex-forming co-host provides a superior structure in terms of device lifetime and efficiency because of its well-balanced mobility. Minimizing polaron accumulation is key to achieving long OLED device lifetimes. This is a crucial aspect of device physics that must be considered in the device design structure.

  16. Experimental study on the adiabatic shear bands

    International Nuclear Information System (INIS)

    Affouard, J.

    1984-07-01

    Four martensitic steels (Z50CDV5 steel, 28CND8 steel, 35NCDV16 steel and 4340 steel) with different hardness between 190 and 600 Hsub(B) (Brinell hardness), have been studied by means of dynamic compressive tests on split Hopkinson pressure bar. Microscopic observations show that the fracture are associated to the development of adiabatic shear bands (except 4340 steel with 190 Hsub(B) hardness). By means of tests for which the deformation is stopped at predetermined levels, the measurement of shear and hardness inside the band and the matrix indicates the chronology of this phenomenon: first the localization of shear, followed by the formation of adiabatic shear band and ultimatly crack initiation and propagation. These results correlated with few simulations by finite elements have permitted to suggest two mecanisms of deformation leading to the formation of adiabatic shear bands in this specific test [fr

  17. La fracturation et les bandes de déformation dans la région d’El Kohol (Atlas saharien central, Algérie: analyse fractale, lois d’échelles et modèle de réseaux de fractures discrètes

    Directory of Open Access Journals (Sweden)

    Zazoun, R. S.

    2015-12-01

    Full Text Available The aim of this paper is focused on the study of natural fractures and deformation bands in El Kohol structure, located in the Djebel Amour in the Central Saharan Atlas, Algeria. The field observations and measurements were performed through two localities on the forelimb and two others on the backlimb of the structure. The outcrop study has shown the existence of five fracture sets and three deformation bands sets. The spacing and length distribution models of the different fractures sets obey to a power law. The mechanical layer thickness analysis for the whole formations shows the existence of twelve mechanical units with a stratabound control. The deformation bands show an increasing in their numbers, and a decreasing in their spacing when they approach the major faults. The fractal analysis of faults and fractures, as well as the deformation bands show a fractal character of 2D dimension. A good correlation coefficients is obtained from the comparison between the density and the intensity parameters (Pxy calculated from the discrete fracture network (DFN modelling, and those from the outcrops. The model developed is discussed related to deformation events recognized in the area.[fr] Ce travail porte sur l’étude de la fracturation naturelle et les bandes de déformation dans la structure plicative d’El Kohol, du le Djebel Amour, dans l’Atlas saharien central. Les observations et les mesures ont été effectuées à travers deux stations sur le flanc court ou avant de la structure, et deux stations sur le flanc long ou arrière. L’étude a montré l’existence de cinq familles de fractures et de trois familles de bandes de déformation. Les modèles de distribution des espacements et des longueurs des différentes familles de fractures obéit à une loi de type puissance. L’analyse mécanostratigraphique montre une subdivision des formations étudiées en douze unités mécaniques. Les bandes de déformation montrent une

  18. Optimal Shell Thickness of Metal@Insulator Nanoparticles for Net Enhancement of Photogenerated Polarons in P3HT Films.

    Science.gov (United States)

    Goh, Wei-Peng; Williams, Evan L; Yang, Ren-Bin; Koh, Wee-Shing; Mhaisalkar, Subodh; Ooi, Zi-En

    2016-02-03

    Embedding metal nanoparticles in the active layer of organic solar cells has been explored as a route for improving charge carrier generation, with localized field enhancement as a proposed mechanism. However, embedded metal nanoparticles can also act as charge recombination sites. To suppress such recombination, the metal nanoparticles are commonly coated with a thin insulating shell. At the same time, this insulating shell limits the extent that the localized enhanced electric field influences charge generation in the organic medium. It is presumed that there is an optimal thickness which maximizes field enhancement effects while suppressing recombination. Atomic Layer Deposition (ALD) was used to deposit Al2O3 layers of different thicknesses onto silver nanoparticles (Ag NPs), in a thin film of P3HT. Photoinduced absorption (PIA) spectroscopy was used to study the dependence of the photogenerated P3HT(+) polaron population on the Al2O3 thickness. The optimal thickness was found to be 3-5 nm. This knowledge can be further applied in the design of metal nanoparticle-enhanced solar cells.

  19. Wide Band to ''Double Band'' upgrade

    International Nuclear Information System (INIS)

    Kasper, P.; Currier, R.; Garbincius, P.; Butler, J.

    1988-06-01

    The Wide Band beam currently uses electrons obtained from secondary photon conversions to produce the photon beam incident on the experimental targets. By transporting the positrons produced in these conversions as well as the electrons it is possible to almost double the number of photons delivered to the experiments per primary beam proton. 11 figs

  20. Band - Weg interactie

    NARCIS (Netherlands)

    de Boer, Andries; ter Huerne, Henderikus L.; Noordermeer, Jacobus W.M.; Schipper, Dirk J.; prof.dr.ir. Molenaar, A.A.A.

    2008-01-01

    De huidige infrastructuur van wegen waarover men zich snel en comfortabel kan verplaatsen is niet meer weg te denken uit onze maatschappij. Twee “componenten” die hierbij een belangrijke rol spelen zijn het wegdek en de band. Het contact tussen band en wegdek is mede bepalend voor de veiligheid. De

  1. Photonic band structure computations.

    Science.gov (United States)

    Hermann, D; Frank, M; Busch, K; Wolfle, P

    2001-01-29

    We introduce a novel algorithm for band structure computations based on multigrid methods. In addition, we demonstrate how the results of these band structure calculations may be used to compute group velocities and effective photon masses. The results are of direct relevance to studies of pulse propagation in such materials.

  2. ZEBRAFISH CHROMOSOME-BANDING

    NARCIS (Netherlands)

    PIJNACKER, LP; FERWERDA, MA

    1995-01-01

    Banding techniques were carried out on metaphase chromosomes of zebrafish (Danio rerio) embryos. The karyotypes with the longest chromosomes consist of 12 metacentrics, 26 submetacentrics, and 12 subtelocentrics (2n = 50). All centromeres are C-band positive. Eight chromosomes have a pericentric

  3. Band structures in fractal grading porous phononic crystals

    Science.gov (United States)

    Wang, Kai; Liu, Ying; Liang, Tianshu; Wang, Bin

    2018-05-01

    In this paper, a new grading porous structure is introduced based on a Sierpinski triangle routine, and wave propagation in this fractal grading porous phononic crystal is investigated. The influences of fractal hierarchy and porosity on the band structures in fractal graidng porous phononic crystals are clarified. Vibration modes of unit cell at absolute band gap edges are given to manifest formation mechanism of absolute band gaps. The results show that absolute band gaps are easy to form in fractal structures comparatively to the normal ones with the same porosity. Structures with higher fractal hierarchies benefit multiple wider absolute band gaps. This work provides useful guidance in design of fractal porous phononic crystals.

  4. Band parameters of phosphorene

    DEFF Research Database (Denmark)

    Lew Yan Voon, L. C.; Wang, J.; Zhang, Y.

    2015-01-01

    Phosphorene is a two-dimensional nanomaterial with a direct band-gap at the Brillouin zone center. In this paper, we present a recently derived effective-mass theory of the band structure in the presence of strain and electric field, based upon group theory. Band parameters for this theory...... are computed using a first-principles theory based upon the generalized-gradient approximation to the density-functional theory. These parameters and Hamiltonian will be useful for modeling physical properties of phosphorene....

  5. Electric field control of the small-polaron hopping conduction in spatial confined Pr0.7(Ca0.6Sr0.40.3MnO3/PMN-PT heterostructure

    Directory of Open Access Journals (Sweden)

    Hao Kuang

    2017-05-01

    Full Text Available The electric field dependent high-temperature small-polaron hopping conduction was investigated in patterned Pr0.7(Ca0.6Sr0.40.3MnO3 strips. The small-polaronic activation energy EA and the carrier localization were found to decrease with the reduction of the strip size. Meanwhile, a similar dependence on the strip size was also obtained for the calculated small-polaron coupling constants, which could be related to the strain relaxation in strips. These results indicate that the spatial confinement prefers to delocalize the carrier and reduce the electron-phonon interaction. Furthermore, opposite variation trends of EA under negative and positive electric field were found in the strips with small size, which could be attributed to the enhancement of polarization effect induced by the reduction of strip size.

  6. Laparoscopic gastric banding

    Science.gov (United States)

    ... eat by making you feel full after eating small amounts of food. After surgery, your doctor can adjust the band ... You will feel full after eating just a small amount of food. The food in the small upper pouch will ...

  7. Decay of superdeformed bands

    International Nuclear Information System (INIS)

    Carpenter, M.P.; Khoo, T.L.; Lauritsen, T.

    1995-01-01

    One of the major challenges in the study of superdeformation is to directly connect the large number of superdeformed bands now known to the yrast states. In this way, excitation energies, spins and parities can be assigned to the levels in the second well which is essential to establish the collective and single-particle components of these bands. This paper will review some of the progress which has been made to understand the decay of superdeformed bands using the new arrays including the measurement of the total decay spectrum and the establishment of direct one-step decays from the superdeformed band to the yrast line in 194 Hg. 42 refs., 5 figs

  8. Highly-efficient charge separation and polaron delocalization in polymer-fullerene bulk-heterojunctions: a comparative multi-frequency EPR and DFT study.

    Science.gov (United States)

    Niklas, Jens; Mardis, Kristy L; Banks, Brian P; Grooms, Gregory M; Sperlich, Andreas; Dyakonov, Vladimir; Beaupré, Serge; Leclerc, Mario; Xu, Tao; Yu, Luping; Poluektov, Oleg G

    2013-06-28

    The ongoing depletion of fossil fuels has led to an intensive search for additional renewable energy sources. Solar-based technologies could provide sufficient energy to satisfy the global economic demands in the near future. Photovoltaic (PV) cells are the most promising man-made devices for direct solar energy utilization. Understanding the charge separation and charge transport in PV materials at a molecular level is crucial for improving the efficiency of the solar cells. Here, we use light-induced EPR spectroscopy combined with DFT calculations to study the electronic structure of charge separated states in blends of polymers (P3HT, PCDTBT, and PTB7) and fullerene derivatives (C60-PCBM and C70-PCBM). Solar cells made with the same composites as active layers show power conversion efficiencies of 3.3% (P3HT), 6.1% (PCDTBT), and 7.3% (PTB7), respectively. Upon illumination of these composites, two paramagnetic species are formed due to photo-induced electron transfer between the conjugated polymer and the fullerene. They are the positive, P(+), and negative, P(-), polarons on the polymer backbone and fullerene cage, respectively, and correspond to radical cations and radical anions. Using the high spectral resolution of high-frequency EPR (130 GHz), the EPR spectra of these species were resolved and principal components of the g-tensors were assigned. Light-induced pulsed ENDOR spectroscopy allowed the determination of (1)H hyperfine coupling constants of photogenerated positive and negative polarons. The experimental results obtained for the different polymer-fullerene composites have been compared with DFT calculations, revealing that in all three systems the positive polaron is distributed over distances of 40-60 Å on the polymer chain. This corresponds to about 15 thiophene units for P3HT, approximately three units for PCDTBT, and about three to four units for PTB7. No spin density delocalization between neighboring fullerene molecules was detected by EPR

  9. Polaronic effects on the off-center donor impurity in AlAs/GaAs/SiO2 spherical core/shell quantum dots

    Science.gov (United States)

    El Haouari, M.; Feddi, E.; Dujardin, F.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.

    2017-11-01

    The ground state of a conduction electron coupled to an off-center impurity donor in a AlAS/GaAs spherical core/shell quantum dot is investigated theoretically. The image-charge effect and the influence of the electron-polar-LO-phonon interaction are considered. The electron-impurity binding energy is calculated via a variational procedure and is reported both as a function of the shell width and of the radial position of the donor atom. The polaronic effects on this quantity are particularly discussed.

  10. Highly-Efficient Charge Separation and Polaron Delocalization in Polymer-Fullerene Bulk-Heterojunctions: A Comparative Multi-Frequency EPR & DFT Study

    Science.gov (United States)

    Niklas, Jens; Mardis, Kristy L.; Banks, Brian P.; Grooms, Gregory M.; Sperlich, Andreas; Dyakonov, Vladimir; Beaupré, Serge; Leclerc, Mario; Xu, Tao; Yu, Luping; Poluektov, Oleg G.

    2016-01-01

    The ongoing depletion of fossil fuels has led to an intensive search for additional renewable energy sources. Solar-based technologies could provide sufficient energy to satisfy the global economic demands in the near future. Photovoltaic (PV) cells are the most promising man-made devices for direct solar energy utilization. Understanding the charge separation and charge transport in PV materials at a molecular level is crucial for improving the efficiency of the solar cells. Here, we use light-induced EPR spectroscopy combined with DFT calculations to study the electronic structure of charge separated states in blends of polymers (P3HT, PCDTBT, and PTB7) and fullerene derivatives (C60-PCBM and C70-PCBM). Solar cells made with the same composites as active layers show power conversion efficiencies of 3.3% (P3HT), 6.1% (PCDTBT), and 7.3% (PTB7), respectively. Under illumination of these composites, two paramagnetic species are formed due to photo-induced electron transfer between the conjugated polymer and the fullerene. They are the positive, P+, and negative, P-, polarons on the polymer backbone and fullerene cage, respectively, and correspond to radical cations and radical anions. Using the high spectral resolution of high-frequency EPR (130 GHz), the EPR spectra of these species were resolved and principal components of the g-tensors were assigned. Light-induced pulsed ENDOR spectroscopy allowed the determination of 1H hyperfine coupling constants of photogenerated positive and negative polarons. The experimental results obtained for the different polymer-fullerene composites have been compared with DFT calculations, revealing that in all three systems the positive polaron is distributed over distances of 40 - 60 Å on the polymer chain. This corresponds to about 15 thiophene units for P3HT, approximately three units PCDTBT, and about three to four units for PTB7. No spin density delocalization between neighboring fullerene molecules was detected by EPR. Strong

  11. HYBASE - HYperspectral BAnd SElection tool

    NARCIS (Netherlands)

    Schwering, P.B.W.; Bekman, H.H.P.T.; Seijen, H.H. van

    2008-01-01

    Band selection is essential in the design of multispectral sensor systems. This paper describes the TNO hyperspectral band selection tool HYBASE. It calculates the optimum band positions given the number of bands and the width of the spectral bands. HYBASE is used to calculate the minimum number of

  12. Atomic structure of amorphous shear bands in boron carbide.

    Science.gov (United States)

    Reddy, K Madhav; Liu, P; Hirata, A; Fujita, T; Chen, M W

    2013-01-01

    Amorphous shear bands are the main deformation and failure mode of super-hard boron carbide subjected to shock loading and high pressures at room temperature. Nevertheless, the formation mechanisms of the amorphous shear bands remain a long-standing scientific curiosity mainly because of the lack of experimental structure information of the disordered shear bands, comprising light elements of carbon and boron only. Here we report the atomic structure of the amorphous shear bands in boron carbide characterized by state-of-the-art aberration-corrected transmission electron microscopy. Distorted icosahedra, displaced from the crystalline matrix, were observed in nano-sized amorphous bands that produce dislocation-like local shear strains. These experimental results provide direct experimental evidence that the formation of amorphous shear bands in boron carbide results from the disassembly of the icosahedra, driven by shear stresses.

  13. Gastropericardial Fistula as a Late Complication of Laparoscopic Gastric Banding

    Directory of Open Access Journals (Sweden)

    Adam A Rudd

    2017-01-01

    Full Text Available Laparoscopic adjustable gastric banding (LAGB is a bariatric procedure that is being performed with increasing frequency as an alternative management option for morbid obesity. Several common complications have been reported including gastric band slippage and associated pouch dilatation, intragastric erosion of the band, gastric wall perforation, and abscess formation. We present a case of gastropericardial fistula occurring nine years after an LAGB. There have been no previous documented cases of the complication after this procedure.

  14. Ferritin associates with marginal band microtubules

    International Nuclear Information System (INIS)

    Infante, Anthony A.; Infante, Dzintra; Chan, M.-C.; How, P.-C.; Kutschera, Waltraud; Linhartova, Irena; Muellner, Ernst W.; Wiche, Gerhard; Propst, Friedrich

    2007-01-01

    We characterized chicken erythrocyte and human platelet ferritin by biochemical studies and immunofluorescence. Erythrocyte ferritin was found to be a homopolymer of H-ferritin subunits, resistant to proteinase K digestion, heat stable, and contained iron. In mature chicken erythrocytes and human platelets, ferritin was localized at the marginal band, a ring-shaped peripheral microtubule bundle, and displayed properties of bona fide microtubule-associated proteins such as tau. Red blood cell ferritin association with the marginal band was confirmed by temperature-induced disassembly-reassembly of microtubules. During erythrocyte differentiation, ferritin co-localized with coalescing microtubules during marginal band formation. In addition, ferritin was found in the nuclei of mature erythrocytes, but was not detectable in those of bone marrow erythrocyte precursors. These results suggest that ferritin has a function in marginal band formation and possibly in protection of the marginal band from damaging effects of reactive oxygen species by sequestering iron in the mature erythrocyte. Moreover, our data suggest that ferritin and syncolin, a previously identified erythrocyte microtubule-associated protein, are identical. Nuclear ferritin might contribute to transcriptional silencing or, alternatively, constitute a ferritin reservoir

  15. Photonic band gap materials

    Science.gov (United States)

    Cassagne, D.

    Photonic band gap materials Photonic band gap materials are periodic dielectric structures that control the propagation of electromagnetic waves. We describe the plane wave method, which allows to calculate the band structures of photonic crystals. By symmetry analysis and a perturbative approach, we predict the appearance of the low energy photonic band gaps of hexagonal structures. We propose new two-dimensional structures called graphite and boron nitride. Using a transfer matrix method, we calculate the transmission of the graphite structure and we show the crucial role of the coupling with external modes. We study the appearance of allowed modes in the photonic band gap by the introduction of localized defects in the periodicity. Finally, we discuss the properties of opals formed by self-organized silica microspheres, which are very promising for the fabrication of three-dimensional photonic crystals. Les matériaux à bandes interdites photoniques sont des structures diélectriques périodiques qui contrôlent la propagation des ondes électromagnétiques. Nous décrivons la méthode des ondes planes qui permet de calculer les structures de bandes des cristaux photoniques. Par une analyse de la symétrie et une approche perturbative, nous précisons les conditions d'existence des bandes interdites de basse énergie. Nous proposons de nouvelles structures bidimensionnelles appelées graphite et nitrure de bore. Grâce à une méthode de matrices de transfert, nous calculons la transmission de la structure graphite et nous mettons en évidence le rôle fondamental du couplage avec les modes extérieurs. Nous étudions l'apparition de modes permis dans la bande interdite grâce à l'introduction de défauts dans la périodicité. Enfin, nous discutons les propriétés des opales constituées de micro-billes de silice auto-organisées, qui sont très prometteuses pour la fabrication de cristaux photoniques tridimensionnels.

  16. Restrictive techniques: gastric banding

    Directory of Open Access Journals (Sweden)

    Katia Cristina da Cunha

    2006-03-01

    Full Text Available Surgery for the treatment of severe obesity has a definite role onthe therapeutic armamentarium all over the world. Initiated 40years ago, bariatric surgery has already a long way thanks tohundred of surgeons, who had constantly searched for the besttechnique for the adequate control of severe obesity. Among theimportant breakthroughs in obesity surgery there is theadjustable gastric band. It is a sylastic band, inflatable andadjustable, which is placed on the top of the stomach in order tocreate a 15-20 cc pouch, with an outlet of 1.3cm. The adjustablegastric band has also a subcutaneous reservoir through whichadjustments can be made, according to the patient evolution.The main feature of the adjustable gastric band is the fact thatis minimal invasive, reversible, adjustable and placedlaparoscopically. Then greatly diminishing the surgical traumato the severe obese patient. Belachew and Favretti’s techniqueof laparoscopic application of the adjustable gastric band isdescribed and the evolution of the technique during this years,as we has been practiced since 1998. The perioperative care ofthe patient is also described, as well as the follow-up and shortand long term controls.

  17. The effect of correlations on the non-ohmic behavior of the small-polaron hopping conductivity in 1D and 3D disordered systems

    International Nuclear Information System (INIS)

    Dimakogianni, M; Triberis, G P

    2010-01-01

    According to percolation theory the investigation of charge transport in disordered systems is equivalent to the study of the possibility of the passage of the carriers through a random network of impedances which interconnect the different lattice sites. When the site energies are not the same, the energy of a site affects the incoming as well as the outgoing impedances connected to the given site and this gives rise to correlations between neighboring impedances. This new condition characterizes the transport process and imposes the evaluation of the average number of sites accessible by a bond from a given site for all possible configurations of sites that satisfy the percolation condition. The generalized molecular crystal model, appropriate for the study of small-polaron hopping transport in disordered systems, and the Kubo formula permit the evaluation of these impedances. Taking correlations into account, theoretical percolation considerations applicable to one-dimensional and three-dimensional disordered systems, lead to analytical expressions for the temperature and electric field dependence of the DC conductivity at high (multi-phonon-assisted hopping) and low (few-phonon-assisted hopping) temperatures. The theoretical analysis reveals the effect of correlations on the non-ohmic behavior of the small-polaron hopping conductivity and permits the evaluation of the maximum hopping distance. Quantitative estimates of this effect are presented comparing the theoretical results, including correlations with those ignoring them, previously reported, applying them to recent experimental data for a wide temperature range and from low up to moderate electric fields.

  18. Small polaron hopping conduction in samples of ceramic La1.4Sr1.6Mn2O7.06

    International Nuclear Information System (INIS)

    Nakatsugawa, H.; Iguchi, E.; Jung, W.H.; Munakata, F.

    1999-01-01

    The ceramic sample of La 1.4 Sr 1.6 Mn 2 O 7.06 exhibits the metal-insulator transition and a negative magnetoresistance in the vicinity of the Curie temperature (T C ∼ 100 K). The dc magnetic susceptibility between 100 K and 280 K is nearly constant and decreases gradually with increasing temperature above 280 K. The measurements of dc resistivity and the thermoelectric power indicate that small polaron hopping conduction takes place at T > 280 K. The spin ordering due to the two-dimensional d x 2 -y 2 state occurring at T > 280 K is directly related to the hopping conduction above 280 K, although the spin ordering due to the one-dimensional d 3z 2 -r 2 state takes place at T > T C . The two-dimensional d x 2 -y 2 state extending within the MnO 2 sheets starts to narrow and leads to the carrier localisation at 280 K. The effective number of holes in this sample estimated from the thermoelectric power is considerably smaller than the nominal value. This indicates that the small polaron hopping conduction takes place predominantly within the in-plane MnO 2 sheets. A discussion is given of the experimental results of the ceramic sample of La 2/3 Ca 1/3 MnO 2.98 . Copyright (1999) CSIRO Australia

  19. Polaronic Nonmetal-Correlated Metal Crossover System β'-CuxV2O5 with Anharmonic Copper Oscillation and Thermoelectric Conversion Performance

    Science.gov (United States)

    Onoda, Masashige; Sato, Takuma

    2017-12-01

    The crystal structures and electronic properties of β'CuxV2O5 are explored through measurements of X-ray four-circle diffraction, electrical resistivity, thermoelectric power, thermal conductivity, magnetization, and electron paramagnetic resonance. For various compositions with 0.243 ≤ x ≤ 0.587, the crystal structures are redetermined through the anharmonic approach of the copper displacement factors, where the anharmonicity is reduced with increasing Cu concentration. The electron transport for x ≤ 0.45 is nonmetallic due to polaron hopping and the random potential of Cu ions, while for x = 0.60, a correlated Fermi-liquid state appears with a Wilson ratio of 1.3 and a Kadowaki-Woods ratio close to the universal value for heavy-fermion systems. At around x = 0.50, the polaronic bandwidth may broaden so that the Hubbard subbands caused by the electron correlation will overlap. The nonmetallic composition in the proximity of the nonmetal-metal crossover shows a dimensionless thermoelectric power factor of 10-2 at 300 K, partly due to the anharmonic copper oscillation.

  20. Ultra wide band antennas

    CERN Document Server

    Begaud, Xavier

    2013-01-01

    Ultra Wide Band Technology (UWB) has reached a level of maturity that allows us to offer wireless links with either high or low data rates. These wireless links are frequently associated with a location capability for which ultimate accuracy varies with the inverse of the frequency bandwidth. Using time or frequency domain waveforms, they are currently the subject of international standards facilitating their commercial implementation. Drawing up a complete state of the art, Ultra Wide Band Antennas is aimed at students, engineers and researchers and presents a summary of internationally recog

  1. Effect of different sulphur precursors on morphology and band-gap on the formation of Cu{sub 2}ZnSnS{sub 4} (CZTS) particles with microwave irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Patro, Bharati; Vijaylakshmi, S., E-mail: vlakshmi@iitb.ac.in [Centre for Research in Nanotechnology and Sciences, Indian Institute of Technology Bombay (India); Sharma, Pratibha [Department of Energy Sciences and Engineering, Indian Institute of Technology Bombay (India)

    2016-05-23

    Cu{sub 2}ZnSnS{sub 4} (CZTS) is a promising semiconductor material for ecological cost effective thin film Photovoltaic (PV) devices. As it contains earth abundant and non-toxic elements, it has the advantages over commercially available CIGS and CdTe thin film PV devices. In the present work, the pure phase Cu{sub 2}ZnSnS{sub 4} particles were successfully synthesised with microwave irradiation. The morphology and phase study was carried out for the samples prepared with two different sulphur precursors viz. thiourea and thioacetamide (TAA). CZTS particles with thiourea as sulphur precursor are more crystalline than CZTS particles with TAA. The band gap of 1.654 eV and 1.713 eV were calculated for the samples prepared with thiourea and TAA respectively.

  2. Band-notched spiral antenna

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Jae; Chang, John

    2018-03-13

    A band-notched spiral antenna having one or more spiral arms extending from a radially inner end to a radially outer end for transmitting or receiving electromagnetic radiation over a frequency range, and one or more resonance structures positioned adjacent one or more segments of the spiral arm associated with a notch frequency band or bands of the frequency range so as to resonate and suppress the transmission or reception of electromagnetic radiation over said notch frequency band or bands.

  3. Calculating the optical properties of defects and surfaces in wide band gap materials

    Science.gov (United States)

    Deák, Peter

    2018-04-01

    The optical properties of a material critically depend on its defects, and understanding that requires substantial and accurate input from theory. This paper describes recent developments in the electronic structure theory of defects in wide band gap materials, where the standard local or semi-local approximations of density functional theory fail. The success of the HSE06 screened hybrid functional is analyzed in case of Group-IV semiconductors and TiO2, and shown that it is the consequence of error compensation between semi-local and non-local exchange, resulting in a proper derivative discontinuity (reproduction of the band gap) and a total energy which is a linear function of the fractional occupation numbers (removing most of the electron self-interaction). This allows the calculation of electronic transitions with accuracy unseen before, as demonstrated on the single-photon emitter NV(-) center in diamond and on polaronic states in TiO2. Having a reliable tool for electronic structure calculations, theory can contribute to the understanding of complicated cases of light-matter interaction. Two examples are considered here: surface termination effects on the blinking and bleaching of the light-emission of the NV(-) center in diamond, and on the efficiency of photocatalytic water-splitting by TiO2. Finally, an outlook is presented for the application of hybrid functionals in other materials, as, e.g., ZnO, Ga2O3 or CuGaS2.

  4. W-Band Sheet Beam Klystron Design

    International Nuclear Information System (INIS)

    Scheitrum, G.; Caryotakis, G.; Burke, A.; Jensen, A.; Jongewaard, E.; Krasnykh, A.; Neubauer, M.; Phillips, R.; Rauenbuehler, K.

    2011-01-01

    Sheet beam devices provide important advantages for very high power, narrow bandwidth RF sources like accelerator klystrons (1). Reduced current density and increased surface area result in increased power capabi1ity, reduced magnetic fields for focusing and reduced cathode loading. These advantages are offset by increased complexity, beam formation and transport issues and potential for mode competition in the ovennoded cavities and drift tube. This paper will describe the design issues encountered in developing a 100 kW peak and 2 kW average power sheet beam k1ystron at W-band including beam formation, beam transport, circuit design, circuit fabrication and mode competition.

  5. Theoretical band alignment in an intermediate band chalcopyrite based material

    Science.gov (United States)

    Castellanos Águila, J. E.; Palacios, P.; Conesa, J. C.; Arriaga, J.; Wahnón, P.

    2017-12-01

    Band alignment is key to enhance the performance of heterojunction for chalcopyrite thin film solar cells. In this paper we report ab initio calculations of the electronic structures of CuGaS2:Cr with various Cr compositions, CuAlSe2 and ZnSe and the band alignment between their interfaces. We use density functional theory and the more accurate self-consistent GW scheme to obtain improved bulk band-gaps and band offsets. Band alignments of the interfacial region for CuGaS2:Cr/CuAlSe2 and CuGaS2:Cr/ZnSe systems were aligned with respect of an average electrostatic potential. Our results are in good agreement with experimental values for the bulk band-gaps. These theoretical band alignments show a characteristic staggered band alignment for the design of heterojunction devices in photovoltaic applications.

  6. Influence of polaron effects on superexchange interaction. Isotopic shifts of T sub N , T sub c and T* in laminated copper oxides

    CERN Document Server

    Eremin, M V; Larionov, I A; Terzi, A V

    2002-01-01

    The compact formula for the parameter for the magnetic ions superexchange interaction through intermediate anions with an account of the polaron effects both on the magnetic ions and intermediate anions is obtained. It is applied for the analysis of the basic peculiarities of these types of temperature in the layered cuprates on the HTSC basis: the Neel temperature (T sub N), critical temperatures of the transition into the superconducting state (T sub c) and characteristic temperatures of the normal phases pseudogap state (T*). The calculations are based on the scenario of competition of the superconducting phase with the charge-current waves phase. The agreement of the calculation with the experiment testifies to the benefit of the above scenario

  7. Quasi-one-dimensional polaronic states due to the preferential reduction in the Li sub 1 sub + sub x V sub 3 O sub 8 insertion electrode

    CERN Document Server

    Onoda, M

    2003-01-01

    The structural and electronic properties of the Li sub 1 sub + sub x V sub 3 O sub 8 insertion electrode, where 0 sup 0.1 with nearly stoichiometric oxygen atoms, small polarons exist without carrier-creation energy at high temperatures, while at low temperatures the conduction may be of variable-range hopping (VRH) type. For x > 0.2, one-dimensional magnetic properties appear due to sizable exchange couplings and order-disorder effects of additional Li ions may lead to significant change of transport properties. For the intermediate composition 0 < x sup<= 0.1, strong randomness of the Li doping and the congenital oxygen deficiency cause VRH states even at high temperatures.

  8. Quasi-one-dimensional polaronic states due to the preferential reduction in the Li1+xV3O8 insertion electrode

    Science.gov (United States)

    Onoda, Masashige; Amemiya, Isao

    2003-05-01

    The structural and electronic properties of the Li1+xV3O8 insertion electrode, where 0 leq x 0.1 with nearly stoichiometric oxygen atoms, small polarons exist without carrier-creation energy at high temperatures, while at low temperatures the conduction may be of variable-range hopping (VRH) type. For x > 0.2, one-dimensional magnetic properties appear due to sizable exchange couplings and order-disorder effects of additional Li ions may lead to significant change of transport properties. For the intermediate composition 0 < x leq 0.1, strong randomness of the Li doping and the congenital oxygen deficiency cause VRH states even at high temperatures.

  9. Optical tunability of magnetic polaron stability in single-Mn doped bulk GaAs and GaAs/AlGaAs quantum dots

    Science.gov (United States)

    Qu, Fanyao; Moura, Fábio Vieira; Alves, Fabrizio M.; Gargano, Ricardo

    2013-03-01

    Optical control of magnetic property of a magnetic polaron (MP) in Mn-doped bulk GaAs and GaAs/AlGaAs quantum dots (QDs) have been studied. We have developed basis optimization technique for the method of linear combination of atomic orbitals (LCAOs), which significantly improve the accuracy of the conventional LCAO calculation. We have demonstrated that a monochromatic, linearly polarized, intense pulsed laser field induces a collapse of the MP and an ionization of Mn-acceptor in Mn-doped GaAs materials due to a dichotomy of hole wave function. We find this optical tunability of MP stability can be adjusted by confinement introduced in GaAs QDs.

  10. Degradation of blue-phosphorescent organic light-emitting devices involves exciton-induced generation of polaron pair within emitting layers.

    Science.gov (United States)

    Kim, Sinheui; Bae, Hye Jin; Park, Sangho; Kim, Wook; Kim, Joonghyuk; Kim, Jong Soo; Jung, Yongsik; Sul, Soohwan; Ihn, Soo-Ghang; Noh, Changho; Kim, Sunghan; You, Youngmin

    2018-03-23

    Degradation of organic materials is responsible for the short operation lifetimes of organic light-emitting devices, but the mechanism by which such degradation is initiated has yet to be fully established. Here we report a new mechanism for degradation of emitting layers in blue-phosphorescent devices. We investigate binary mixtures of a wide bandgap host and a series of novel Ir(III) complex dopants having N-heterocyclocarbenic ligands. Our mechanistic study reveals the charge-neutral generation of polaron pairs (radical ion pairs) by electron transfer from the dopant to host excitons. Annihilation of the radical ion pair occurs by charge recombination, with such annihilation competing with bond scission. Device lifetime correlates linearly with the rate constant for the annihilation of the radical ion pair. Our findings demonstrate the importance of controlling exciton-induced electron transfer, and provide novel strategies to design materials for long-lifetime blue electrophosphorescence devices.

  11. Neither Goodenough ionic model nor Zener polaron model for Bi 0.5Ca 0.5Mn 1- xNi xO 3- δ system

    Science.gov (United States)

    Toulemonde, O.; Skovsen, I.; Mesguich, F.; Gaudin, E.

    2008-04-01

    The magnetic susceptibilities of three Bi 0.5Ca 0.5MnO 3- δ compounds synthesised by three different methods were characterised and analysed. Large magnetic Mn x clusters ( x ≥ 4) were considered to explain the high value of the Curie-Weiss constant. Unlike previous studies on similar systems, Goodenough ionic model or Zener polaron model is not suitable. In all cases, cluster behaviour is observed at low field and at low temperature. The influence of the oxygen stoichiometry and the homogeneity of the cation distribution depending on the method of the synthesis used is discussed. Finally, the effects of nickel doping on the magnetic properties were studied and the cluster behaviour was confirmed. The distribution in size of the clusters depends on the amount of nickel and it induces a glassy magnetic behaviour.

  12. Proxy magnetometry of the photosphere: why are G-band bright points so bright?

    NARCIS (Netherlands)

    Rutten, R.J.; Kiselman, Dan; Voort, Luc Rouppe van der; Plez, Bertrand

    2000-01-01

    We discuss the formation of G-band bright points in terms of standard uxtube modeling, in particular the 1D LTE models constructed by Solanki and coworkers. Combined with LTE spectral synthesis they explain observed G-band bright point contrasts quite well. The G-band contrast increase over the

  13. Semiconductors bonds and bands

    CERN Document Server

    Ferry, David K

    2013-01-01

    As we settle into this second decade of the twenty-first century, it is evident that the advances in micro-electronics have truly revolutionized our day-to-day lifestyle. The technology is built upon semiconductors, materials in which the band gap has been engineered for special values suitable to the particular application. This book, written specifically for a one semester course for graduate students, provides a thorough understanding of the key solid state physics of semiconductors. It describes how quantum mechanics gives semiconductors unique properties that enabled the micro-electronics revolution, and sustain the ever-growing importance of this revolution.

  14. Microstrip microwave band gap structures

    Indian Academy of Sciences (India)

    Microwave band gap structures exhibit certain stop band characteristics based on the periodicity, impedance contrast and effective refractive index contrast. These structures though formed in one-, two- and three-dimensional periodicity, are huge in size. In this paper, microstrip-based microwave band gap structures are ...

  15. Wide band ENDOR spectrometer

    International Nuclear Information System (INIS)

    Mendonca Filho, C.

    1973-01-01

    The construction of an ENDOR spectrometer operating from 0,5 to 75 MHz within a single band, with ore Klystron and homodine detection, and no fundamental changes on the electron spin resonance spectrometer was described. The ENDOR signal can be detected both by amplitude modulation of the frequency field, or direct detection of the ESR output, which is taken to a signal analyser. The signal-to-noise ratio is raised by averaging rather than filtering avoiding the use of long time constants, providing natural line widths. The experimental apparatus and the spectra obtained are described. A discussion, relating the ENDOR line amplitudes with the experimental conditions is done and ENDOR mechanism, in which there is a relevant presence of cross relaxation is proposed

  16. Wide Band Artificial Pulsar

    Science.gov (United States)

    Parsons, Zackary

    2017-01-01

    The Wide Band Artificial Pulsar (WBAP) is an instrument verification device designed and built by the National Radio Astronomy Observatory (NRAO) in Green Bank, West Virgina. The site currently operates the Green Bank Ultimate Pulsar Processing Instrument (GUPPI) and the Versatile Green Bank Astronomical Spectrometer (VEGAS) digital backends for their radio telescopes. The commissioning and continued support for these sophisticated backends has demonstrated a need for a device capable of producing an accurate artificial pulsar signal. The WBAP is designed to provide a very close approximation to an actual pulsar signal. This presentation is intended to provide an overview of the current hardware and software implementations and to also share the current results from testing using the WBAP.

  17. Designing broad phononic band gaps for in-plane modes

    Science.gov (United States)

    Li, Yang Fan; Meng, Fei; Li, Shuo; Jia, Baohua; Zhou, Shiwei; Huang, Xiaodong

    2018-03-01

    Phononic crystals are known as artificial materials that can manipulate the propagation of elastic waves, and one essential feature of phononic crystals is the existence of forbidden frequency range of traveling waves called band gaps. In this paper, we have proposed an easy way to design phononic crystals with large in-plane band gaps. We demonstrated that the gap between two arbitrarily appointed bands of in-plane mode can be formed by employing a certain number of solid or hollow circular rods embedded in a matrix material. Topology optimization has been applied to find the best material distributions within the primitive unit cell with maximal band gap width. Our results reveal that the centroids of optimized rods coincide with the point positions generated by Lloyd's algorithm, which deepens our understandings on the formation mechanism of phononic in-plane band gaps.

  18. Experimental manifestations of the Nb.sup.4+./sup.-O.sup.-./sup. polaronic excitons in KTa.sub.0.988./sub.Nb.sub.0.012./sub.O.sub.3./sub..

    Czech Academy of Sciences Publication Activity Database

    Yusupov, R.V.; Gracheva, I.N.; Rodionov, A.A.; Syrnikov, P. P.; Gubaev, A. I.; Dejneka, Alexandr; Jastrabík, Lubomír; Trepakov, V.A.; Salakhov, M.K.

    2011-01-01

    Roč. 84, č. 17 (2011), 174118/1-174118/7 ISSN 1098-0121 R&D Projects: GA MŠk(CZ) 1M06002 Institutional research plan: CEZ:AV0Z10100522 Keywords : photoinduced EPR * Nb 4+ -O - polaronic excitons * KTa 0.988 Nb 0.012 O 3 Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.691, year: 2011

  19. Polaronic and bipolaronic structures in the adiabatic Hubbard-Hostein model involving 2 electrons and in its extensions; Structures polaroniques et bipolaroniques dans le modele de hostein hubbard adiabatique a deux electrons et ses extensions

    Energy Technology Data Exchange (ETDEWEB)

    Proville, L

    1998-03-30

    This thesis brings its contribution to the bipolaronic theory which might explain the origin of superconductivity at high temperature. A polaron is a quasiparticle made up of a localized electron and a deformation in the crystal structure. 2 electrons in singlet states localized on the same site form a bipolaron. Whenever the Coulomb repulsion between the 2 electrons is too strong bipolaron turns into 2 no bound polarons. We study the existence and the mobility of bipolarons. We describe the electron-phonon interaction by the Holstein term and the Coulomb repulsion by the Hubbard term. 2 assumptions are made: - the local electron-phonon interaction is strong and opposes the Coulomb repulsion between Hubbard type electrons - the system is close to the adiabatic limit. The system is reduced to 2 electrons in order to allow an exact treatment and the investigation of some bipolaronic bound states. At 2-dimensions the existence of bipolarons requires a very strong coupling which forbids any classical mobility. In some cases an important tunneling effect appears and we show that mobile bipolarons exist in a particular parameter range. Near the adiabatic limit we prove that polaronic and bipolaronic structures exist for a great number of electrons. (A.C.) 33 refs.

  20. Dual-band infrared camera

    Science.gov (United States)

    Vogel, H.; Schlemmer, H.

    2005-10-01

    Every year, numerous accidents happen on European roads due to bad visibility (fog, night, heavy rain). Similarly, the dramatic aviation accidents of year 2001 in Milan and Zurich have reminded us that aviation safety is equally affected by reduced visibility. A dual-band thermal imager was developed in order to raise human situation awareness under conditions of reduced visibility especially in the automotive and aeronautical context but also for all transportation or surveillance tasks. The chosen wavelength bands are the Short Wave Infrared SWIR and the Long Wave Infrared LWIR band which are less obscured by reduced visibility conditions than the visible band. Furthermore, our field tests clearly show that the two different spectral bands very often contain complementary information. Pyramidal fusion is used to integrate complementary and redundant features of the multi-spectral images into a fused image which can be displayed on a monitor to provide more and better information for the driver or pilot.

  1. Monte Carlo study of efficiency roll-off of phosphorescent organic light-emitting diodes: Evidence for dominant role of triplet-polaron quenching

    Energy Technology Data Exchange (ETDEWEB)

    Eersel, H. van, E-mail: h.v.eersel@tue.nl; Coehoorn, R. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Philips Research Laboratories, High Tech Campus 4, 5656 AE Eindhoven (Netherlands); Bobbert, P. A.; Janssen, R. A. J. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2014-10-06

    We present an advanced molecular-scale organic light-emitting diode (OLED) model, integrating both electronic and excitonic processes. Using this model, we can reproduce the measured efficiency roll-off for prototypical phosphorescent OLED stacks based on the green dye tris[2-phenylpyridine]iridium (Ir(ppy){sub 3}) and the red dye octaethylporphine platinum (PtOEP) and study the cause of the roll-off as function of the current density. Both the voltage versus current density characteristics and roll-off agree well with experimental data. Surprisingly, the results of the simulations lead us to conclude that, contrary to what is often assumed, not triplet-triplet annihilation but triplet-polaron quenching is the dominant mechanism causing the roll-off under realistic operating conditions. Simulations for devices with an optimized recombination profile, achieved by carefully tuning the dye trap depth, show that it will be possible to fabricate OLEDs with a drastically reduced roll-off. It is envisaged that J{sub 90}, the current density at which the efficiency is reduced to 90%, can be increased by almost one order of magnitude as compared to the experimental state-of-the-art.

  2. Engineering intermediate-band photovoltaic material by heavily co-doping selenium and nitrogen in silicon

    Science.gov (United States)

    Dong, Xiao; Wang, Yongyong; Song, Xiaohui

    2018-01-01

    Among the various dimer configurations, the substitutional dimer exhibits the lowest formation energy and can form an impurity band that overlaps with the conduction band. The impurity band turns into an isolated and partially filled intermediate-band in the bandgap when the two impurity atoms are separated from a dimer to the remotest distance. The configurations with different impurity atom distances are stable in the Si material owing to their constant formation energy and can lead to a significant enhancement of the optical absorption in the infrared wavelength range.

  3. Electrophoretic formation of semiconductor layers with adjustable band gap

    Science.gov (United States)

    Shindrov, Alexander; Yuvchenko, Sergey; Vikulova, Maria; Tretyachenko, Elena; Zimnyakov, Dmitry; Gorokhovsky, Alexander

    2017-11-01

    The ceramic layers of the potassium polytitanates modified by transition metal salts were electrophoretically deposited onto the surface of glassy substrate coated with indium-tin oxide. The deposition allows obtaining a dense ceramic layer formed by composite agglomerates consisting of nanoscale particles with average size of 130-190 nm. The optical absorption spectra of the coatings modified in the mixtures of aqueous solutions of different transition metal salts were investigated. It was recognized that a bandgap value of these composites can be adjusted in a range from 1.4 to 2.3 eV depending the chemical composition of layered double hydroxide obtained during modification. This might be very promising for optoelectronic applications of such coatings due to an explicit control of optical properties.

  4. Mineralogy and geochemistry of banded iron formation and iron ...

    Indian Academy of Sciences (India)

    comparison with Krivoi Rog of Ukraine, and Nimba. Range, Liberia; Ore Geol. Rev. 9 311–324. Ghosh G and Mukhopadhyay J 2007 Reappraisal of the structure of the Western Iron Ore Group, Singhbhum craton, eastern India: Implications for the exploration of BIF-hosted iron ore deposits; Gondwana Res. 12. 525–532.

  5. SINGLE-BAND, TRIPLE-BAND, OR MULTIPLE-BAND HUBBARD MODELS

    NARCIS (Netherlands)

    ESKES, H; SAWATZKY, GA

    1991-01-01

    The relevance of different models, such as the one-band t-J model and the three-band Emery model, as a realistic description of the electronic structure of high-T(c) materials is discussed. Starting from a multiband approach using cluster calculations and an impurity approach, the following

  6. Band-notched ultrawide band antenna loaded with ferrite slab

    Science.gov (United States)

    Wang, Hao; Zong, Weihua; Sun, Nian X.; Lin, Hwaider; Li, Shandong

    2017-05-01

    In this paper, a novel technique to design a band-notched UWB antenna by using Yttrium Iron Garnet (YIG) ferrite is proposed. A printed slot UWB antenna with size of 21mm×26 mm×0.8 mm is adopted as a basic antenna. A piece of ferrite slab with size of 5 mm×10 mm×2 mm is attached on the feeding layer of the antenna to achieve band-notched characteristics. The measured -10 dB bandwidth of the antenna without ferrite slab is 2.91-10.98 GHz. With loading of ferrite slab, the bandwidth turns to 2.73-5.12 and 5.87-10.78 GHz. A band notch of 5.12- 5.87 GHz is achieved to filter WLAN 5 GHz (5.15-5.825 GHz) band. The proposed technique has virtue of easy fabrication and keeping antenna miniaturization.

  7. Band-to-Band Tunneling Transistors: Scalability and Circuit Performance

    Science.gov (United States)

    2013-05-01

    55* MEDICI ...3.2.1 Tunneling Theory 3.3 Simulation Methods 3.3.1 MEDICI 3.3.2 Sentaurus Local Tunneling 3.3.3 Sentaurus Nonlocal Tunneling 3.4 Sentaurus...tunneling current. 3.3.1 MEDICI MEDICI is a one and two-dimensional simulator created by Synopsys, Inc. [18]. It contains a band-to-band

  8. The width of Liesegang bands: A study using moving boundary ...

    Indian Academy of Sciences (India)

    Keywords. Reaction–diffusion systems; Liesegang bands; pattern formation; moving boundary; simulation. PACS Nos 64.75.Xc; 64.75.Yz. 1. Introduction. Nature has a wide storage of colourful patterns ..... This idea was sequentially developed to generate patterns in a Matlab program. The algorithm for this was prepared ...

  9. On the simulation of kink bands in fiber reinforced composites

    DEFF Research Database (Denmark)

    Sørensen, K.D.; Mikkelsen, Lars Pilgaard; Jensen, H.M.

    2007-01-01

    Simulations of kink band formation in fiber reinforced composites are carried out using the commercial finite element program ABAQUS. A smeared-out, plane constitutive model for fiber reinforced materials is implemented as a user subroutine, and effects of fiber misalignment on elastic and plastic...

  10. On the Simulation of Kink Bands in Fiber Reinforced Composites

    DEFF Research Database (Denmark)

    Sørensen, Kim Dalsten; Mikkelsen, Lars P.; Jensen, Henrik Myhre

    2007-01-01

    Simulations of kink band formation in fiber reinforced composites are carried out using the commercial finite element program ABAQUS. A smeared-out, plane constitutive model for fiber reinforced materials is implemented as a user subroutine, and effects of fiber misalignment on elastic and plastic...

  11. Intensity formulas for triplet bands

    Science.gov (United States)

    Budo, A.

    1982-01-01

    Previous work in this area is surveyed and the mathematics involved in determining the quantitative intensity measurements in triplet bands is presented. Explicit expressions for the intensity distribution in the branches of the 3 Sigma-3 Pi and 1 Sigma-3Pi bands valid for all values of the coupling constant Y of the 3 Pi terms are given. The intensity distribution calculated according to the formulas given is compared with measurements of PH, 3 Pi-3 Sigma. Good quantitative agreement is obtained.

  12. Real-time recursive hyperspectral sample and band processing algorithm architecture and implementation

    CERN Document Server

    Chang, Chein-I

    2017-01-01

    This book explores recursive architectures in designing progressive hyperspectral imaging algorithms. In particular, it makes progressive imaging algorithms recursive by introducing the concept of Kalman filtering in algorithm design so that hyperspectral imagery can be processed not only progressively sample by sample or band by band but also recursively via recursive equations. This book can be considered a companion book of author’s books, Real-Time Progressive Hyperspectral Image Processing, published by Springer in 2016. Explores recursive structures in algorithm architecture Implements algorithmic recursive architecture in conjunction with progressive sample and band processing Derives Recursive Hyperspectral Sample Processing (RHSP) techniques according to Band-Interleaved Sample/Pixel (BIS/BIP) acquisition format Develops Recursive Hyperspectral Band Processing (RHBP) techniques according to Band SeQuential (BSQ) acquisition format for hyperspectral data.

  13. Effect of Förster-mediated triplet-polaron quenching and triplet-triplet annihilation on the efficiency roll-off of organic light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Eersel, H. van [Simbeyond B.V., P.O. Box 513, NL-5600 MB Eindhoven (Netherlands); Bobbert, P. A.; Janssen, R. A. J.; Coehoorn, R., E-mail: r.coehoorn@tue.nl [Department of Applied Physics and Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, NL-5600 MB Eindhoven (Netherlands)

    2016-04-28

    We report the results of a systematic study of the interplay of triplet-polaron quenching (TPQ) and triplet-triplet annihilation (TTA) on the efficiency roll-off of organic light-emitting diodes (OLEDs) with increasing current density. First, we focus on OLEDs based on the green phosphorescent emitter tris[2-phenylpyridine]iridium(III) (Ir(ppy){sub 3}) and the red phosphorescent dye platinum octaethylporphyrin. It is found that the experimental data can be reproduced using kinetic Monte Carlo (kMC) simulations within which TPQ and TTA are due to a nearest-neighbor (NN) interaction, or due to a more long-range Förster-type process. Furthermore, we find a subtle interplay between TPQ and TTA: decreasing the contribution of one process can increase the contribution of the other process, so that the roll-off is not significantly reduced. Furthermore, we find that just analyzing the shape of the roll-off is insufficient for determining the relative role of TPQ and TTA. Subsequently, we investigate the wider validity of this picture using kMC simulations for idealized but realistic symmetric OLEDs, with an emissive layer containing a small concentration of phosphorescent dye molecules in a matrix material. Whereas for NN-interactions the roll-off can be reduced when the dye molecules act as shallow hole and electron traps, we find that such an approach becomes counterproductive for long-range TTA and TPQ. Developing well-founded OLED design rules will thus require that more quantitative information is available on the rate and detailed mechanism of the TPQ and TTA processes.

  14. Induction of a new alkaline band at a target position in internodal cells of Chara corallina.

    Science.gov (United States)

    Shimmen, Teruo; Yamamoto, Ako

    2002-09-01

    Characean cells develop alternating alkaline and acid bands on their surface upon illumination. However, the mechanism of band formation is not fully understood. In the present study, we succeeded in inducing a new alkaline band at an original acid band in internodal cells of Chara corallina. Chloroplasts in an acid band were locally removed by wounding the cell in the absence of the cell turgor pressure. The chloroplast-removed area was observed as a white belt in a green cylindrical internodal cell. This internodal cell developed a new alkaline band on the surface at the chloroplast-removed area. The narrower the chloroplast-removed area, the less significant the extent of OH(-) extrusion. This is the first success in inducing a new alkaline band at a target position in Characeae.

  15. William Band at Yenching University

    Science.gov (United States)

    Hu, Danian

    2008-04-01

    William Band (1906-1993) has been widely remembered by his American colleagues and students as ``a fine physicist and teacher,'' who taught at Washington State University in Pullman between 1949 and 1971 and authored Introduction to Quantum Statistics (1954) and Introduction to Mathematical Physics (1959). Not many, however, knew much about Band's early career, which was very ``uncommon and eventful.'' Born in England, Band graduated from University of Liverpool in 1927 with an MsSc degree in physics. Instead of pursuing his Ph.D. at Cambridge, he chose to teach physics at Yenching University, a prestigious Christian university in Beijing, China. Arriving in 1929, Band established his career at Yenching, where he taught and researched the theory of relativity and quantum mechanics, pioneered the study on low-temperature superconductivity in China, founded the country's first graduate program in physics, and chaired the Physics Department for 10 years until he fled from Yenching upon hearing of the attack on Pearl Harbor. It took him two years to cross Japanese occupied areas under the escort of the Communist force; he left China in early 1945. This presentation will explore Band's motivation to work in China and his contributions to the Chinese physics research and education.

  16. GPM GROUND VALIDATION NOAA S-BAND PROFILER MINUTE DATA MC3E V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The S-band Profiler Minute Dwell dataset in the netCDF format was gathered during the Midlatitude Continental Convective Clouds Experiment (MC3E) in Oklahoma...

  17. GPM GROUND VALIDATION NOAA S-BAND PROFILER ORIGINAL DWELL DATA MC3E V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The S-band Profiler Original Dwell dataset in the netCDF format was gathered during the Midlatitude Continental Convective Clouds Experiment (MC3E) in Oklahoma...

  18. SRTM mission-cross comparison of X adn C band data properties

    Science.gov (United States)

    Rosen, P.; Eineder, M.; Rabus, B.; Gurrola, E.; Hensley, S.; Knopfle, W.; Breit, H.; Roth, A.; Werner, M.

    2001-01-01

    This paper compares the specific properties of the X and C band data sets with respect to global coverage, height accuracy, sensor specific errors, product definition, product format and availability.

  19. Optical model with multiple band couplings using soft rotator structure

    Science.gov (United States)

    Martyanov, Dmitry; Soukhovitskii, Efrem; Capote, Roberto; Quesada, Jose Manuel; Chiba, Satoshi

    2017-09-01

    A new dispersive coupled-channel optical model (DCCOM) is derived that describes nucleon scattering on 238U and 232Th targets using a soft-rotator-model (SRM) description of the collective levels of the target nucleus. SRM Hamiltonian parameters are adjusted to the observed collective levels of the target nucleus. SRM nuclear wave functions (mixed in K quantum number) have been used to calculate coupling matrix elements of the generalized optical model. Five rotational bands are coupled: the ground-state band, β-, γ-, non-axial- bands, and a negative parity band. Such coupling scheme includes almost all levels below 1.2 MeV of excitation energy of targets. The "effective" deformations that define inter-band couplings are derived from SRM Hamiltonian parameters. Conservation of nuclear volume is enforced by introducing a monopolar deformed potential leading to additional couplings between rotational bands. The present DCCOM describes the total cross section differences between 238U and 232Th targets within experimental uncertainty from 50 keV up to 200 MeV of neutron incident energy. SRM couplings and volume conservation allow a precise calculation of the compound-nucleus (CN) formation cross sections, which is significantly different from the one calculated with rigid-rotor potentials with any number of coupled levels.

  20. Designing Phononic Crystals with Wide and Robust Band Gaps

    Science.gov (United States)

    Jia, Zian; Chen, Yanyu; Yang, Haoxiang; Wang, Lifeng

    2018-04-01

    Phononic crystals (PnCs) engineered to manipulate and control the propagation of mechanical waves have enabled the design of a range of novel devices, such as waveguides, frequency modulators, and acoustic cloaks, for which wide and robust phononic band gaps are highly preferable. While numerous PnCs have been designed in recent decades, to the best of our knowledge, PnCs that possess simultaneous wide and robust band gaps (to randomness and deformations) have not yet been reported. Here, we demonstrate that by combining the band-gap formation mechanisms of Bragg scattering and local resonances (the latter one is dominating), PnCs with wide and robust phononic band gaps can be established. The robustness of the phononic band gaps are then discussed from two aspects: robustness to geometric randomness (manufacture defects) and robustness to deformations (mechanical stimuli). Analytical formulations further predict the optimal design parameters, and an uncertainty analysis quantifies the randomness effect of each designing parameter. Moreover, we show that the deformation robustness originates from a local resonance-dominant mechanism together with the suppression of structural instability. Importantly, the proposed PnCs require only a small number of layers of elements (three unit cells) to obtain broad, robust, and strong attenuation bands, which offer great potential in designing flexible and deformable phononic devices.

  1. Designing Phononic Crystals with Wide and Robust Band Gaps

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yanyu [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Jia, Zian [State University of New York at Stony Brook; Yang, Haoxiang [State University of New York at Stony Brook; Wang, Lifeng [State University of New York at Stony Brook

    2018-04-16

    Phononic crystals (PnCs) engineered to manipulate and control the propagation of mechanical waves have enabled the design of a range of novel devices, such as waveguides, frequency modulators, and acoustic cloaks, for which wide and robust phononic band gaps are highly preferable. While numerous PnCs have been designed in recent decades, to the best of our knowledge, PnCs that possess simultaneous wide and robust band gaps (to randomness and deformations) have not yet been reported. Here, we demonstrate that by combining the band-gap formation mechanisms of Bragg scattering and local resonances (the latter one is dominating), PnCs with wide and robust phononic band gaps can be established. The robustness of the phononic band gaps are then discussed from two aspects: robustness to geometric randomness (manufacture defects) and robustness to deformations (mechanical stimuli). Analytical formulations further predict the optimal design parameters, and an uncertainty analysis quantifies the randomness effect of each designing parameter. Moreover, we show that the deformation robustness originates from a local resonance-dominant mechanism together with the suppression of structural instability. Importantly, the proposed PnCs require only a small number of layers of elements (three unit cells) to obtain broad, robust, and strong attenuation bands, which offer great potential in designing flexible and deformable phononic devices.

  2. Porosity reduction within shear deformation bands in unconsolidated Pleistocene sediments

    Science.gov (United States)

    Brandes, Christian; Tanner, David

    2016-04-01

    Deformation bands are important structural elements that occur in the upper crust and develop in porous sandstones and even in unconsolidated sands. In contrast to discrete surfaces such as faults, deformation bands represent tabular zones of continuous displacement over several centimeters (Fossen et al., 2007). We present an outcrop-based study on the internal fabric of shear deformation bands that developed in Pleistocene unconsolidated sands in northern Germany. The deformation bands formed in an extensional stress regime, have a normal sense of displacement in a range of centimeters to decimeters, and form conjugate sets that intersect at angles between 70° and 90° (Brandes & Tanner, 2012). Due to their near-surface position, they are a perfect target for the study of deformation band formation prior to burial and diagenesis. Thin section analysis show a significant pore space reduction from the host sediment to the shear deformation band. The boundary between the host sediment and the shear deformation bands can be very sharp. The grains within the deformation band are of the same grain size as the host sediment. Grain shape varies from angular to well-rounded. Many elliptic grains have a long-axis orientation parallel to the trend of the deformation band. The grains in the analysed thin sections are all intact, i.e., there is no evidence for cataclasis. We believe the shear deformation bands are created by a grain-sliding process that decreases the porosity and leads to a denser packing of the sand. This is a porosity reduction mechanism in sandstone that occurs prior to burial without cataclasis. This can have an impact on fluid-flow in unconsolidated sediments in the near-surface. References: Brandes, C. & Tanner, D.C. (2012) Three-dimensional geometry and fabric of shear deformation bands in unconsolidated Pleistocene sediments. Tectonophysics, 518-521, 84-92. Fossen, H., Schultz, R.A., Shipton, Z.K., & Mair, K. (2007) Deformation bands in sandstone: a

  3. Photoionization bands of rubidium molecule

    Science.gov (United States)

    Rakić, M.; Pichler, G.

    2018-03-01

    We studied the absorption spectrum of dense rubidium vapor generated in a T-type sapphire cell with a special emphasis on the structured photoionization continuum observed in the 200-300 nm spectral region. The photoionization spectrum has a continuous atomic contribution with a pronounced Seaton-Cooper minimum at about 250 nm and a molecular photoionization contribution with many broad bands. We discuss the possible origin of the photoionization bands as stemming from the absorption from the ground state of the Rb2 molecule to excited states of Rb2+* and to doubly excited autoionizing states of Rb2** molecule. All these photoionization bands are located above the Rb+ and Rb2+ ionization limits.

  4. Band-in-band segregation of multidisperse granular mixtures

    NARCIS (Netherlands)

    Newey, M.; Ozik, J.; van der Meer, S.M.

    2004-01-01

    Radial and axial segregation is investigated experimentally in polydisperse mixtures of granular materials rotated in a long, partly filled, horizontal cylinder. Radial segregation by size is observed in all polydisperse mixtures. Axial segregation, with smaller-size particles forming bands within

  5. Radiology of vertical banded gastroplasty

    International Nuclear Information System (INIS)

    Leekam, R.N.; Deitel, M.; Shankar, L.; Salsberg, B.

    1987-01-01

    Vertical banded gastroplasty is now the most common procedure for the surgical treatment of obesity. In the past 4 years 120 patients have been referred for radiologic examination. This exhibit describes the normal and abnormal findings in many of these patients. The authors divided radiologic abnormalities into three groups: abnormalities of the partition, abnormalities of the banded channel, and ulcers and extragastric leaks. The authors' examination technique has been adapted from those described by others, our important addition being the preliminary precontrast film, on which the staple lines can be examined. This has proved most effective in the detection of partition defects

  6. Statistical Distribution Analysis of Lineated Bands on Europa

    Science.gov (United States)

    Chen, T.; Phillips, C. B.; Pappalardo, R. T.

    2016-12-01

    Tina Chen, Cynthia B. Phillips, Robert T. Pappalardo Europa's surface is covered with intriguing linear and disrupted features, including lineated bands that range in scale and size. Previous studies have shown the possibility of an icy shell at the surface that may be concealing a liquid ocean with the potential to harboring life (Pappalardo et al., 1999). Utilizing the high-resolution imaging data from the Galileo spacecraft, we examined bands through a morphometric and morphologic approach. Greeley et al. (2000) and Procktor et al. (2002) have defined bands as wide, hummocky to lineated features that have distinctive surface texture and albedo compared to its surrounding terrain. We took morphometric measurements of lineated bands to find correlations in properties such as size, location, and orientation, and to shed light on formation models. We will present our measurements of over 100 bands on Europa that was mapped on the USGS Europa Global Mosaic Base Map (2002). We also conducted a statistical analysis to understand the distribution of lineated bands globally, and whether the widths of the bands differ by location. Our preliminary analysis from our statistical distribution evaluation, combined with the morphometric measurements, supports a uniform ice shell thickness for Europa rather than one that varies geographically. References: Greeley, Ronald, et al. "Geologic mapping of Europa." Journal of Geophysical Research: Planets 105.E9 (2000): 22559-22578.; Pappalardo, R. T., et al. "Does Europa have a subsurface ocean? Evaluation of the geological evidence." Journal of Geophysical Research: Planets 104.E10 (1999): 24015-24055.; Prockter, Louise M., et al. "Morphology of Europan bands at high resolution: A mid-ocean ridge-type rift mechanism." Journal of Geophysical Research: Planets 107.E5 (2002).; U.S. Geological Survey, 2002, Controlled photomosaic map of Europa, Je 15M CMN: U.S. Geological Survey Geologic Investigations Series I-2757, available at http

  7. Band structure peculiarities of magnetic photonic crystals

    Science.gov (United States)

    Gevorgyan, A. H.; Golik, S. S.

    2017-10-01

    In this work we studied light diffraction in magneto-photonic crystals (MPC) having large magneto-optical activity and modulation large depth. The case of arbitrary angles between the direction of the external static magnetic field and the normal to the border of the MPC layer is considered. The problem is solved by Ambartsumian's modified layer addition method. It is found that there is a new type of non-reciprocity, namely, the relation R (α) ≠ R (- α) takes place, where R is the reflection coefficient, and α is the incidence angle. It is shown the formation of new photonic band gap (PBG) at oblique incidence of light, which is not selective for the polarization of the incident light, in the case when the external magnetic field is directed along the medium axis. Such a system can be used as: a tunable polarization filter, polarization mirror, circular (elliptical) polarizer, tunable optical diode, etc.

  8. Theory of Fermi Liquid with Flat Bands

    Science.gov (United States)

    Khodel, V. A.

    2018-04-01

    A self-consistent theory of Fermi systems hosting flat bands is developed. Compared with an original model of fermion condensation, its key point consists in proper accounting for mixing between condensate and non-condensate degrees of freedom that leads to formation of a non-BCS gap Υ (p) in the single-particle spectrum. The results obtained explain: (1) the two-gap structure of spectra of single-particle excitations of electron systems of copper oxides, revealed in ARPES studies, (2) the role of violation of the topological stability of the Landau state in the arrangement of the T-x phase diagram of this family of high-T_c superconductors, (3) the topological nature of a metal-insulator transition, discovered in homogeneous two-dimensional low-density electron liquid of MOSFETs more than 20 years ago.

  9. Theory of Fermi Liquid with Flat Bands

    Science.gov (United States)

    Khodel, V. A.

    2017-11-01

    A self-consistent theory of Fermi systems hosting flat bands is developed. Compared with an original model of fermion condensation, its key point consists in proper accounting for mixing between condensate and non-condensate degrees of freedom that leads to formation of a non-BCS gap Υ (p) in the single-particle spectrum. The results obtained explain: (1) the two-gap structure of spectra of single-particle excitations of electron systems of copper oxides, revealed in ARPES studies, (2) the role of violation of the topological stability of the Landau state in the arrangement of the T-x phase diagram of this family of high-T_c superconductors, (3) the topological nature of a metal-insulator transition, discovered in homogeneous two-dimensional low-density electron liquid of MOSFETs more than 20 years ago.

  10. Correlations in a band insulator

    Czech Academy of Sciences Publication Activity Database

    Sentef, M.; Kuneš, Jan; Werner, P.; Kampf, A. P.

    2009-01-01

    Roč. 80, č. 15 (2009), 155116/1-155116/7 ISSN 1098-0121 Institutional research plan: CEZ:AV0Z10100521 Keywords : electronic correlations * dynamical mean-field theory * band insulator Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.475, year: 2009

  11. Metaphyseal bands in osteogenesis imperfecta

    Directory of Open Access Journals (Sweden)

    Suresh S

    2010-01-01

    Full Text Available An increasing number of patients with osteogenesis imperfecta are undergoing pamidronate therapy to prevent the incidence of fragility fractures. The authors herein report a child aged 3 years who received five cycles of pamidronate, resulting in metaphyseal bands, known as "zebra lines."

  12. Singing in the Band Rehearsal.

    Science.gov (United States)

    Wolbers, Mark

    2002-01-01

    Explains how singing can be incorporated into the band rehearsal. Discusses how to improve student aural skills by including singing in the rehearsal and the benefits of having students sing. Describes how music teachers can use songs or chorales in the classroom. (CMK)

  13. Traveling bands for the Keller-Segel model with population growth.

    Science.gov (United States)

    Ai, Shangbing; Wang, Zhian

    2015-08-01

    This paper is concerned with the existence of the traveling bands to the Keller-Segel model with cell population growth in the form of a chemical uptake kinetics. We find that when the cell growth is considered, the profile of traveling bands, the minimum wave speed and the range of the chemical consumption rate for the existence of traveling wave solutions will change. Our results reveal that collective interaction of cell growth and chemical consumption rate plays an essential role in the generation of traveling bands. The research in the paper provides new insights into the mechanisms underlying the chemotactic pattern formation of wave bands.

  14. Development of banded microstructure in 34CrNiMo6 steel

    Directory of Open Access Journals (Sweden)

    A. Nagode

    2016-07-01

    Full Text Available In this paper the development of a banded microstructure in hot-rolled 34CrNiMo6 steel which consisted of bainitic and martensitic bands is explained. The chemical compositions of the bands were measured with energy dispersive x-ray spectroscopy (EDS, which showed that the martensitic bands contained more alloying elements (Mn, Cr, Mo, Si than bainitic bands. By using Oberhoffer reagent, the segregations of phosphorus were also revealed. These phosphorus segregations coincided with the positive segregations of the alloying elements. The continuous cooling transformation (CCT diagrams of steel were calculated. They confirmed the formation of martensite in positive segregations and the formation of bainite in negative segregations.

  15. Chemically induced compaction bands in geomaterials

    Science.gov (United States)

    Stefanou, Ioannis; Sulem, Jean

    2013-04-01

    Compaction bands play an important role in oil production and may provide useful information on various geological processes. Various mechanisms can be involved at different scales: the micro scale (e.g. the grain scale), the meso scale (e.g. the Representative Element Volume) and the macro scale (e.g. the structure). Moreover, hydro-chemo-mechanical couplings might play an important role in triggering instabilities in the form of compaction bands. Compaction bands can be seen as an instability of the underneath mathematical problem leading to localization of deformation [1,2,3]. Here we explore the conditions of compaction banding in quartz-based geomaterials by considering the effect of chemical dissolution and precipitation [4,5]. In due course of the loading process grain crushing affects the residual strength, the porosity and the permeability of the material. Moreover, at the micro-level, grain crushing results in an increase of the grain specific surface, which accelerates the dissolution [6]. Consequently, the silica is removed more rapidly from the grain skeleton and the overall mechanical properties are degraded due to chemical factors. The proposed model accounts for these phenomena. In particular, the diffusion of the diluted in the water silica is considered through the mass balance equation of the porous medium. The reduction of the mechanical strength of the material is described through a macroscopic failure criterion with chemical softening. The grain size reduction is related to the total energy input [7]. A grain size and porosity dependent permeability law is adopted. These degradation mechanisms are coupled with the dissolution/precipitation reaction kinetics. The obtained hydro-chemo-mechanical model is used to investigate the conditions, the material parameters and the chemical factors inducing compaction bands formation. References [1] J.W. Rudnicki, and J.R. Rice. "Conditions for the Localization of Deformation in Pressure

  16. Formation of radical cations and dose response of alpha-terthiophene-cellulose triacetate films irradiated by electrons and gamma rays

    CERN Document Server

    Emmi, S S; Ceroni, P; D'Angelantonio, M; Lavalle, M; Fuochi, P G; Kovács, A

    2002-01-01

    The radiation-induced UV-vis spectrum of alpha-terthiophene radical cation in solid is reported. The radical cation initiates an oligomerization in the CTA matrix producing permanently coloured conjugated polarons. The specific net absorbance at 465 nm is linearly related with dose up to 2x10 sup sup 6 sup sup G y, for electrons and gamma irradiation. The decrease of the UV typical absorption (355 nm) and of four IR bands of alpha-terthiophene is linear with dose, as well. Although sensitivity is influenced by dose rate, it turned out that a linear relationship holds between sensitivity and log dose rate, in the range from 2 to 10 sup sup 5 Gy, min. These findings suggest a potential application of the system for dosimetric purposes over a wide range of dose and dose rate.

  17. Wild Band Edges: The Role of Bandgap Grading and Band-Edge Fluctuations in High-Efficiency Chalcogenide Devices: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Repins, Ingrid; Mansfield, Lorelle; Kanevce, Ana; Jensen, Soren A.; Kuciauskas, Darius; Glynn, Stephen; Barnes, Teresa; Metzger, Wyatt; Burst, James; Jiang, Chun-Sheng; Dippo, Patricia; Harvey, Steve; Teeter, Glenn; Perkins, Craig; Egaas, Brian; Zakutayev, Andriy; Alsmeier, J.-H.; Lussky, T.; Korte, L.; Wilks, R. G.; Bar, M.; Yan, Y.; Lany, Stephan; Zawadzki, Pawel; Park, Ji-Sang; Wei, Suhuai

    2016-06-16

    Band-edge effects -- including grading, electrostatic fluctuations, bandgap fluctuations, and band tails -- affect chalcogenide device efficiency. These effects now require more careful consideration as efficiencies increase beyond 20%. Several aspects of the relationships between band-edge phenomena and device performance for NREL absorbers are examined. For Cu(In,Ga)Se2 devices, recent increases in diffusion length imply changes to optimum bandgap profile. The origin, impact, and modification of electrostatic and bandgap fluctuations are also discussed. The application of the same principles to devices based on CdTe, kesterites, and emerging absorbers (Cu2SnS3, CuSbS2), considering differences in materials properties and defect formation energies, is examined.

  18. Band Anticrossing in Highly Mismatched Compound Semiconductor Alloys

    Science.gov (United States)

    Yu, Kin Man; Wu, J.; Walukiewicz, W.; Ager, J. W.; Haller, E. E.; Miotkowski, I.; Su, Ching-Hua; Curreri, Peter A. (Technical Monitor)

    2001-01-01

    interaction between localized Se states and the conduction band. On the other hand we show that the large band gap reduction observed on the Se-rich side of the alloy system is a result of an interaction between the localized Te level and the valence bands. This interaction leads to the formation of a Te-like valence band edge that strongly interacts with the light hole valence band. Calculations based on a modified k(sup dot)p model account for the reduction of the band gap and the large increase of the spin-orbit splitting observed in Se-rich ZnSe(sub y)Te(sub 1-y) alloys. We will also discuss the importance of these new results for understanding of the electronic structure and band offsets in other highly mismatched alloy systems.

  19. Stellar formation

    CERN Document Server

    Reddish, V C

    1978-01-01

    Stellar Formation brings together knowledge about the formation of stars. In seeking to determine the conditions necessary for star formation, this book examines questions such as how, where, and why stars form, and at what rate and with what properties. This text also considers whether the formation of a star is an accident or an integral part of the physical properties of matter. This book consists of 13 chapters divided into two sections and begins with an overview of theories that explain star formation as well as the state of knowledge of star formation in comparison to stellar structure

  20. Linear methods in band theory

    DEFF Research Database (Denmark)

    Andersen, O. Krogh

    1975-01-01

    Two approximate methods for solving the band-structure problem in an efficient and physically transparent way are presented and discussed in detail. The variational principle for the one-electron Hamiltonian is used in both schemes, and the trial functions are linear combinations of energy......-independent augmented plane waves (APW) and muffin-tin orbitals (MTO), respectively. The secular equations are therefore eigenvalue equations, linear in energy. The trial functions are defined with respect to a muffin-tin (MT) potential and the energy bands depend on the potential in the spheres through potential...... parameters which describe the energy dependence of the logarithmic derivatives. Inside the spheres, the energy-independent APW is that linear combination of an exact solution, at the arbitrary but fixed energy Eν, and its energy derivative which matches continuously and differentiably onto the plane...

  1. NCenter wide band neutrino beam

    International Nuclear Information System (INIS)

    Stutte, L.G.

    1985-01-01

    This memo describes the physical properties of the currently operating N-Center wide band neutrino beam---commonly called the triplet train, following a past tradition of a triplet lens configuration. In reality, in order to gain a larger momentum acceptance and to minimize the angular divergence of the beam, a quadruplet beam (4 lenses) employing point-to-parallel optics at a central momentum of 300 GeV was built. 6 refs., 13 figs., 1 tab

  2. [Gastric band erosion: Alternative management].

    Science.gov (United States)

    Echaverry-Navarrete, Denis José; Maldonado-Vázquez, Angélica; Cortes-Romano, Pablo; Cabrera-Jardines, Ricardo; Mondragón-Pinzón, Erwin Eduardo; Castillo-González, Federico Armando

    2015-01-01

    Obesity is a public health problem, for which the prevalence has increased worldwide at an alarming rate, affecting 1.7 billion people in the world. To describe the technique employed in incomplete penetration of gastric band where endoscopic management and/or primary closure is not feasible. Laparoscopic removal of gastric band was performed in five patients with incomplete penetrance using Foley catheterization in the perforation site that could lead to the development of a gastro-cutaneous fistula. The cases presented include a leak that required surgical lavage with satisfactory outcome, and one patient developed stenosis 3 years after surgical management, which was resolved endoscopically. In all cases, the penetration site closed spontaneously. Gastric band erosion has been reported in 3.4% of cases. The reason for inserting a catheter is to create a controlled gastro-cutaneous fistula, allowing spontaneous closure. Various techniques have been described: the totally endoscopic, hybrid techniques (endoscopic/laparoscopic) and completely laparoscopic. A technique is described here that is useful and successful in cases where the above-described treatments are not viable. Copyright © 2015. Published by Masson Doyma México S.A.

  3. Single and multi-band electromagnetic induced transparency-like metamaterials with coupled split ring resonators

    Science.gov (United States)

    Bagci, Fulya; Akaoglu, Baris

    2017-08-01

    We present a metamaterial configuration exhibiting single and multi-band electromagnetic induced transparency (EIT)-like properties. The unit cell of the single band EIT-like metamaterial consists of a multi-split ring resonator surrounded by a split ring resonator. The multi-split ring resonator acts as a quasi-dark or dark resonator, depending on the polarization of the incident wave, and the split ring resonator serves as the bright resonator. Combination of these two resonators results in a single band EIT-like transmission inside the stop band. EIT-like transmission phenomenon is also clearly observed in the measured transmission spectrum at almost the same frequencies for vertical and horizontal polarized waves, and the numerical results are verified for normal incidence. Moreover, multi-band transmission windows are created within a wide band by combining the two slightly different single band EIT-like metamaterial unit cells that exhibit two different coupling strengths inside a supercell configuration. Group indices as high as 123 for single band and 488 for tri-band transmission, accompanying with high transmission rates (over 80%), are achieved, rendering the metamaterial very suitable for multi-band slow light applications. It is shown that the group delay of the propagating wave can be increased and dynamically controlled by changing the polarization angle. Multi-band EIT-like transmission is also verified experimentally, and a good agreement with simulations is obtained. The proposed novel methodology for obtaining multi-band EIT, which takes advantage of a supercell configuration by hosting slightly different configured unit cells, can be utilized for easily formation and manipulation of multi-band transmission windows inside a stop band.

  4. Soil formation.

    NARCIS (Netherlands)

    Breemen, van N.; Buurman, P.

    1998-01-01

    Soil Formation deals with qualitative and quantitative aspects of soil formation (or pedogenesis) and the underlying chemical, biological, and physical processes. The starting point of the text is the process - and not soil classification. Effects of weathering and new formation of minerals,

  5. More on Estimation of Banded and Banded Toeplitz Covariance Matrices

    OpenAIRE

    Berntsson, Fredrik; Ohlson, Martin

    2017-01-01

    In this paper we consider two different linear covariance structures, e.g., banded and bended Toeplitz, and how to estimate them using different methods, e.g., by minimizing different norms. One way to estimate the parameters in a linear covariance structure is to use tapering, which has been shown to be the solution to a universal least squares problem. We know that tapering not always guarantee the positive definite constraints on the estimated covariance matrix and may not be a suitable me...

  6. Deformation bands in porous sandstones their microstructure and petrophysical properties

    Energy Technology Data Exchange (ETDEWEB)

    Torabi, Anita

    2007-12-15

    Deformation bands are commonly thin tabular zones of crushed or reorganized grains that form in highly porous rocks and sediments. Unlike a fault, typically the slip is negligible in deformation bands. In this dissertation the microstructure and petrophysical properties of deformation bands have been investigated through microscopy and numerical analysis of experimental and natural examples. The experimental work consists of a series of ring-shear experiments performed on porous sand at 5 and 20 MPa normal stresses and followed by microscopic examination of thin sections from the sheared samples. The results of the ring-shear experiments and comparison of them to natural deformation bands reveals that burial depth (level of normal stress in the experiments) and the amount of shear displacement during deformation are the two significant factors influencing the mode in which grains break and the type of shear zone that forms. Two end-member types of experimental shear zones were identified: (a) Shear zones with diffuse boundaries, which formed at low levels of normal stress and/or shear displacement; and (b) Shear zones with sharp boundaries, which formed at higher levels of normal stress and/or shear displacement. Our interpretation is that with increasing burial depth (approximately more than one kilometer, simulated in the experiments by higher levels of normal stress), the predominant mode of grain fracturing changes from flaking to splitting; which facilitates the formation of sharp-boundary shear zones. This change to grain splitting increases the power law dimension of the grain size distribution (D is about 1.5 in sharp boundary shear zones). Based on our observations, initial grain size has no influence in the deformation behavior of the sand at 5 MPa normal stresses. A new type of cataclastic deformation band is described through outcrop and microscopic studies; here termed a 'slipped deformation band'. Whereas previously reported cataclastic

  7. Band Subset Selection for Hyperspectral Image Classification

    Directory of Open Access Journals (Sweden)

    Chunyan Yu

    2018-01-01

    Full Text Available This paper develops a new approach to band subset selection (BSS for hyperspectral image classification (HSIC which selects multiple bands simultaneously as a band subset, referred to as simultaneous multiple band selection (SMMBS, rather than one band at a time sequentially, referred to as sequential multiple band selection (SQMBS, as most traditional band selection methods do. In doing so, a criterion is particularly developed for BSS that can be used for HSIC. It is a linearly constrained minimum variance (LCMV derived from adaptive beamforming in array signal processing which can be used to model misclassification errors as the minimum variance. To avoid an exhaustive search for all possible band subsets, two numerical algorithms, referred to as sequential (SQ and successive (SC algorithms are also developed for LCMV-based SMMBS, called SQ LCMV-BSS and SC LCMV-BSS. Experimental results demonstrate that LCMV-based BSS has advantages over SQMBS.

  8. A PHOTONIC BAND GAP FIBRE

    DEFF Research Database (Denmark)

    1999-01-01

    An optical fibre having a periodicidal cladding structure provididing a photonic band gap structure with superior qualities. The periodical structure being one wherein high index areas are defined and wherein these are separated using a number of methods. One such method is the introduction...... of additional low index elements, another method is providing elongated elements deformed in relation to a circular cross section. Also described is a cladding structure comprising elongated elements of a material having an index of refraction higher than that of the material adjacent thereto. Using...

  9. Prenatal diagnosis of amniotic band syndrome

    Directory of Open Access Journals (Sweden)

    Laxmi Devi Padmanabhan

    2016-01-01

    Full Text Available Amniotic band can cause a broad spectrum of anomalies ranging from simple band constrictions to major craniofacial and visceral defects. It can cause significant neonatal morbidity. Accurate diagnosis will help in the management of the present pregnancy and in counseling with regard to future pregnancies. Here we report three cases of amniotic band syndrome detected in the prenatal period.

  10. High-energy band structure of gold

    DEFF Research Database (Denmark)

    Christensen, N. Egede

    1976-01-01

    The band structure of gold for energies far above the Fermi level has been calculated using the relativistic augmented-plane-wave method. The calculated f-band edge (Γ6-) lies 15.6 eV above the Fermi level is agreement with recent photoemission work. The band model is applied to interpret...

  11. Multi-band Modelling of Appearance

    DEFF Research Database (Denmark)

    Stegmann, Mikkel Bille; Larsen, Rasmus

    2002-01-01

    the appearance of both derived feature bands and an intensity band. As a special case of feature-band augmented appearance modelling we propose a dedicated representation with applications to face segmentation. The representation addresses a major problem within face recognition by lowering the sensitivity...

  12. Multi-band Modelling of Appearance

    DEFF Research Database (Denmark)

    Stegmann, Mikkel Bille; Larsen, Rasmus

    2003-01-01

    the appearance of both derived feature bands and an intensity band. As a special case of feature-band augmented appearance modelling we propose a dedicated representation with applications to face segmentation. The representation addresses a major problem within face recognition by lowering the sensitivity...

  13. Galaxy properties from J-PAS narrow-band photometry

    Science.gov (United States)

    Mejía-Narváez, A.; Bruzual, G.; Magris, C. G.; Alcaniz, J. S.; Benítez, N.; Carneiro, S.; Cenarro, A. J.; Cristóbal-Hornillos, D.; Dupke, R.; Ederoclite, A.; Marín-Franch, A.; de Oliveira, C. Mendes; Moles, M.; Sodre, L.; Taylor, K.; Varela, J.; Ramió, H. Vázquez

    2017-11-01

    We study the consistency of the physical properties of galaxies retrieved from spectral energy distribution (SED) fitting as a function of spectral resolution and signal-to-noise ratio (SNR). Using a selection of physically motivated star formation histories, we set up a control sample of mock galaxy spectra representing observations of the local Universe in high-resolution spectroscopy, and in 56 narrow-band and 5 broad-band photometry. We fit the SEDs at these spectral resolutions and compute their corresponding stellar mass, the mass- and luminosity-weighted age and metallicity, and the dust extinction. We study the biases, correlations and degeneracies affecting the retrieved parameters and explore the role of the spectral resolution and the SNR in regulating these degeneracies. We find that narrow-band photometry and spectroscopy yield similar trends in the physical properties derived, the former being considerably more precise. Using a galaxy sample from the Sloan Digital Sky Survey (SDSS), we compare more realistically the results obtained from high-resolution and narrow-band SEDs (synthesized from the same SDSS spectra) following the same spectral fitting procedures. We use results from the literature as a benchmark to our spectroscopic estimates and show that the prior probability distribution functions, commonly adopted in parametric methods, may introduce biases not accounted for in a Bayesian framework. We conclude that narrow-band photometry yields the same trend in the age-metallicity relation in the literature, provided it is affected by the same biases as spectroscopy, albeit the precision achieved with the latter is generally twice as large as with the narrow-band, at SNR values typical of the different kinds of data.

  14. Disentangling overlapping high-field EPR spectra of organic radicals: Identification of light-induced polarons in the record fullerene-free solar cell blend PBDB-T:ITIC

    Science.gov (United States)

    Van Landeghem, Melissa; Maes, Wouter; Goovaerts, Etienne; Van Doorslaer, Sabine

    2018-03-01

    We present a combined high-field EPR and DFT study of light-induced radicals in the bulk heterojunction blend of PBDB-T:ITIC, currently one of the highest efficiency non-fullerene donor:acceptor combinations in organic photovoltaics. We demonstrate two different approaches for disentangling the strongly overlapping high-field EPR spectra of the positive and negative polarons after charge separation: (1) relaxation-filtered field-swept EPR based on the difference in T1 spin-relaxation times and (2) field-swept EDNMR-induced EPR by exploiting the presence of 14N hyperfine couplings in only one of the radical species, the small molecule acceptor radical. The approach is validated by light-induced EPR spectra on related blends and the spectral assignment is underpinned by DFT computations. The broader applicability of the spectral disentangling methods is discussed.

  15. L-band brightness temperature disaggregation for use with S-band and C-band radiometer data for WCOM

    Science.gov (United States)

    Yao, P.; Shi, J.; Zhao, T.; Cosh, M. H.; Bindlish, R.

    2017-12-01

    There are two passive microwave sensors onboard the Water Cycle Observation Mission (WCOM), which includes a synthetic aperture radiometer operating at L-S-C bands and a scanning microwave radiometer operating from C- to W-bands. It provides a unique opportunity to disaggregate L-band brightness temperature (soil moisture) with S-band C-bands radiometer data. In this study, passive-only downscaling methodologies are developed and evaluated. Based on the radiative transfer modeling, it was found that the TBs (brightness temperature) between the L-band and S-band exhibit a linear relationship, and there is an exponential relationship between L-band and C-band. We carried out the downscaling results by two methods: (1) downscaling with L-S-C band passive measurements with the same incidence angle from payload IMI; (2) downscaling with L-C band passive measurements with different incidence angle from payloads IMI and PMI. The downscaling method with L-S bands with the same incident angle was first evaluated using SMEX02 data. The RMSE are 2.69 K and 1.52 K for H and V polarization respectively. The downscaling method with L-C bands is developed with different incident angles using SMEX03 data. The RMSE are 2.97 K and 2.68 K for H and V polarization respectively. These results showed that high-resolution L-band brightness temperature and soil moisture products could be generated from the future WCOM passive-only observations.

  16. Reconfigurable L-Band Radar

    Science.gov (United States)

    Rincon, Rafael F.

    2008-01-01

    The reconfigurable L-Band radar is an ongoing development at NASA/GSFC that exploits the capability inherently in phased array radar systems with a state-of-the-art data acquisition and real-time processor in order to enable multi-mode measurement techniques in a single radar architecture. The development leverages on the L-Band Imaging Scatterometer, a radar system designed for the development and testing of new radar techniques; and the custom-built DBSAR processor, a highly reconfigurable, high speed data acquisition and processing system. The radar modes currently implemented include scatterometer, synthetic aperture radar, and altimetry; and plans to add new modes such as radiometry and bi-static GNSS signals are being formulated. This development is aimed at enhancing the radar remote sensing capabilities for airborne and spaceborne applications in support of Earth Science and planetary exploration This paper describes the design of the radar and processor systems, explains the operational modes, and discusses preliminary measurements and future plans.

  17. Photonic Band Gap Accelerator Demonstration at Ku-Band.

    CERN Document Server

    Smirnova, Evgenya I; Edwards, Randall L; Kesar, Amit S; Mastovsky, Ivan; Shapiro, Michael A; Temkin, Richard J

    2005-01-01

    We report progress on the design and cold test of a metal Ku-band PBG accelerator structure. The 17.140 GHz 6-cell PBG accelerator structure with reduced long-range wakefields was designed for the experiment. The copper structure was electroformed and cold-tested. Tuning was performed through chemical etching of the rods. Final cold test measurements were found to be in very good agreement with the design. The structure will be installed on the beam line at the accelerator laboratory at Massachusetts Institute of Technology and will be powered with 3 MW of peak power from the Haimson 17.14 GHz klystron. Results of the design, fabrication, cold test and hot test on the Haimson accelerator will be presented.

  18. Interplay of cross-plane polaronic transport and resistive switching in Pt–Pr0.67Ca0.33MnO3–Pt heterostructures

    International Nuclear Information System (INIS)

    Scherff, M; Hoffmann, J; Meyer, B; Danz, Th; Jooss, Ch

    2013-01-01

    The identification of the cross-plane electric transport mechanisms in different resistance states of metal–oxide sandwich structures is essential for gaining insights into the mechanisms of resistive switching (RS). Here, we present a systematic study of cross-plane electric transport properties of Pr 0.67 Ca 0.33 MnO 3 (PCMO) thin films sandwiched by precious Pt metal electrodes. We observe three different transport regimes: ohmic, nonlinear and RS. The nonlinear regime is associated with colossal magneto-resistance (CMR) and colossal electro-resistance (CER) effects. In contrast to RS, the CMR and CER are volatile resistance effects which persist only during application of strong magnetic or electric fields and they are restricted to low temperatures. At low current densities, the device resistance is dominated by small polaron hopping transport of the PCMO film. At higher electric current densities near the switching threshold, the interface resistance starts to dominate and remarkably also exhibits thermally activated transport properties. Our studies also shed light onto the interplay of colossal resistance effects and RS: at low temperatures, RS can be only induced by reduction of the PCMO resistivity through CMR and CER. This clearly demonstrates the key role of the current density for controlling the amplitude of non-volatile resistive changes. Conversely, the CMR can be used as a probe for the switching induced changes in disorder and correlations. At small switching amplitudes, we observe slight changes in polaron activation energy which can be attributed to changes at the interface. If the switching amplitude exceeds 1000% and more, the CMR effect in the device can be reversibly changed. This indicates persistent changes in electronic or lattice structure of large regions within the PCMO film. (paper)

  19. Dust bands in the asteroid belt

    International Nuclear Information System (INIS)

    Sykes, M.V.; Greenberg, R.; Dermott, S.F.; Nicholson, P.D.; Burns, J.A.

    1989-01-01

    This paper describes the original IRAS observations leading to the discovery of the three dust bands in the asteroid belt and the analysis of data. Special attention is given to an analytical model of the dust band torus and to theories concerning the origin of the dust bands, with special attention given to the collisional equilibrium (asteroid family), the nonequilibrium (random collision), and the comet hypotheses of dust-band origin. It is noted that neither the equilibrium nor nonequilibrium models, as currently formulated, present a complete picture of the IRAS dust-band observations. 32 refs

  20. Optimization of spectral band utilization in gridless WDM optical network

    Science.gov (United States)

    Martins, Indayara B.; Aldaya, Ivan; Perez-Sanchez, G.; Gallion, Philippe

    2014-02-01

    In this paper, the effects of gridless spectrum allocation in Wavelength Division Multiplexed (WDM) optical networks are examined. The advanced modulation formats and multi-rate transmissions of the signals, which are key parameters in the optical system project, are taken into account. The consumed spectrum, as well as the impact of linear and nonlinear impairments on the signal transmission, are compared to WDM network adopting standard grid and gridless ITU. To analyze the influence of these physical effects, some key network design parameters are monitored and evaluated, such as the guard band size, the signal occupied bandwidth, the laser power and the quality of channels. The applied signal modulation formats were On/Off Keying (OOK), Quadrature Phase Shift keying (QPSK), and Dual Polarization State Phase Modulation (DP-QPSK), whereas the transmission rate per wavelength was varied from 10 Gb/s to 100Ghz. The guard band, signal band, and laser power were swept and the resulted Bit Error Rate (BER) was estimated from the eye-diagram. Analytical calculations and simulations are conducted in order to evaluate the impact of the gridless spectrum allocation on both the spectral consumption and the signal quality of transmission (QoT). Results reveal that a gridless transmission system reduces the spectral consumption while offering an acceptable QoT. This work was carried out with both analytical modeling and numerical calculation using the Optisystem as well as Matlab.

  1. Vowel categorization and the critical band.

    Science.gov (United States)

    Weitzman, R S

    1992-01-01

    Using the concept formation paradigm, two series of experiments were conducted to test the hypothesis that the critical band (CB) was a factor in learning to make absolute discriminations of vowels. The specific hypothesis being examined was that the CB is a psychoacoustic boundary in learning to make vowel categorizations, and that learning absolute discriminations of pairs of vowels that differ in one of their formants by one bark or more is significantly easier than learning absolute discriminations of vowels that differ by less than one bark. Subjects were given the task of learning to identify paired sets of synthesized vowels that differed in either F1 or F2 by 0.4, 0.6, 0.8, 1.0, or 1.2 bark. The results of these experiments suggest that the critical bandwidth is not a natural psychoacoustic boundary in the learning of vowel categories, and also that subjects seem better able to learn distinctions involving differences in F1 than distinctions involving differences in F2. The discussion raises the possibility that vowels that differ by less than one bark may not be perceptually viable because of such factors as ambient noise, articulatory constraints, and coarticulatory influences. Some evidence from Dutch and French is presented in support of this conjecture.

  2. Diffuse Interstellar Bands: Successes and Challenges

    Science.gov (United States)

    Sonnentrucker, Paule G.; York, Donald G.; Welty, Daniel E.; Hobbs, Lew M.; Fan, Haoyu; DIB Collaboration

    2018-01-01

    To-date, the spectroscopic signatures of over 170 molecular species have been positively identified in interstellar clouds. However, the number of unidentified features observed either in emission (UIB, ERE, AME) or in absorption (Diffuse Interstellar Bands, DIBs) points to the existence of a substantial reservoir of species in interstellar space that are unaccounted for in theories of interstellar clouds and of star and planet formation. The DIBs are a set of about 600 weak absorption features detected mostly in the optical/NIR (4400 to 12000 Å) that appear to be ubiquitous in the diffuse interstellar medium (ISM). The carriers of the DIBs are potentially the champion contributors, by number, to this pool of unidentified species. While the nature of the DIB carriers remains elusive to this day, our understanding of the DIB behavior has matured to a point at which some DIBs can be used as ISM diagnostics regardless of their true nature. I will briefly review progress made in understanding the DIB dependence on the local ISM physical conditions. I will also present recent results - and the challenges that emerged- from an optical survey tailored to characterize a subset of the DIB spectrum: the broadest (FWHM >6 Å) DIB features.

  3. Giemsa C-banding of Barley Chromosomes. I: Banding Pattern Polymorphism

    DEFF Research Database (Denmark)

    Linde-Laursen, Ib

    1978-01-01

    Twenty barley (Hordeum vulgare) lines studied had a common basic chromosome banding pattern. Most bands ranged from medium to very small in size. The most conspicuous banding occurred at or near the centromeres, in the proximal, intercalary parts of most chromosome arms and beside the secondary c...... 7. Seventeen differently banded karyotypes were found. Some banding pattern polymorphisms can be used in cytological and cytogenetic studies....

  4. Photonic band gap structure simulator

    Science.gov (United States)

    Chen, Chiping; Shapiro, Michael A.; Smirnova, Evgenya I.; Temkin, Richard J.; Sirigiri, Jagadishwar R.

    2006-10-03

    A system and method for designing photonic band gap structures. The system and method provide a user with the capability to produce a model of a two-dimensional array of conductors corresponding to a unit cell. The model involves a linear equation. Boundary conditions representative of conditions at the boundary of the unit cell are applied to a solution of the Helmholtz equation defined for the unit cell. The linear equation can be approximated by a Hermitian matrix. An eigenvalue of the Helmholtz equation is calculated. One computation approach involves calculating finite differences. The model can include a symmetry element, such as a center of inversion, a rotation axis, and a mirror plane. A graphical user interface is provided for the user's convenience. A display is provided to display to a user the calculated eigenvalue, corresponding to a photonic energy level in the Brilloin zone of the unit cell.

  5. Broad-band beam buncher

    International Nuclear Information System (INIS)

    Goldberg, D.A.; Flood, W.S.; Arthur, A.A.; Voelker, F.

    1986-01-01

    This patent describes a broad-band beam buncher. This beam buncher consists of: a housing adapted to be eacuated, an electron gun in the housing for producing a beam of electrons, buncher means in the housing forming a buncher cavity which has an entrance opening for receiving the electron beam and an exit opening through which the electron beam passes out of the buncher cavity, a drift tube electrode in the buncher cavity and disposed between the entrance opening and the exit opening with first and second gaps between the drift tube electrode and the entrance and exit openings, the drift tube electrode which has a first drift space through which the electron beam passes in traveling between the entrance and exit openings, modulating means for supplying an ultrahigh frequeny modulating signal to the drift tube electrode for producing velocity modulation of the electrons in the electron beam as the electrons pass through the buncher cavity and the drift tube electrode between the entrance opening and the exit opening, drift space means in the housing forming a second drift space for receiving the velocity modulated electron beam from the exit opening, the velocity modulated electron beam being bunched as it passes along the second drift space, the drift space means has a discharge opening through which the electron beam is discharged from the second drift space after being bunched therein, the modulating means containing a signal source for producing an ultrahigh frequency signal, a transmission line connected between the signal source and the drift tube electrode, and terminating means connected to the drift tube electrode for terminating the transmission line in approximately its characteristic impedance to afford a broad response band with minimum 6 variations therein

  6. On the Mott transition and the new metal-insulator transitions in doped covalent and polar crystals

    International Nuclear Information System (INIS)

    Dzhumanov, S.; Begimkulov, U.; Kurbanov, U.T.; Yavidov, B.Y.

    2001-10-01

    The Mott transition and new metal-insulator transitions (MIT's) and their distinctive features in doped covalent semiconductors and polar compounds are studied within the continuum model of extrinsic carrier self-trapping, the Hubbard impurity band model (with on-site Coulomb repulsion and screening effects) and the extrinsic (bi)polaronic band model (with short- and long-range carrier-impurity, impurity-phonon and carrier-phonon interactions and intercarrier correlation) using the appropriate tight-binding approximations and variational methods. We have shown the formation possibility of large-radius localized one- and two-carrier impurity (or defect) states and narrow impurity bands in the band gap and charge transfer gap of these carrier-doped systems. The extrinsic Mott-Hubbard and (bi)polaronic insulating gaps are calculated exactly. The proper criterions for Mott transition, extrinsic excitonic and (bi)polaronic MIT's are obtained. We have demonstrated that the Mott transition occurs in doped covalent semiconductors (i.e. Si and Ge) and some insulators with weak carrier-phonon coupling near the large-radius dopants. While, in doped polar compounds (e.g. oxide high-T c superconductors (HTSC) and related materials) the MIT's are new extrinsic (or intrinsic) (bi)polaronic MIT's. We have found that the anisotropy of the dielectric (or (bi)polaronic) properties of doped cuprate HTSC is responsible for smooth (or continuous) MIT's, stripe formation and suppression of high-T c superconductivity. Various experimental results on in-gap states, bands and MIT's in doped covalent semiconductors, oxide HTSC and related materials are in good agreement with the developed theory of Mott transition and new (bi)polaronic MIT's. (author)

  7. Liesegang bands in internally oxidized AgCd-based ternary alloys

    International Nuclear Information System (INIS)

    Van Rooijen, V.A.; Van Royen, E.W.; Vrijen, J.; Radelaar, S.

    1975-01-01

    The origin of the occurrence of Liesegang band formation (periodic precipitation) during internal oxidation of AgCd alloys containing concentrations of Be, Mg, Al, or Y were investigated both experimentally and theoretically. A simple model of internal oxidation of ternary alloys is presented. The theory predicts band spacing as a function of temperature, Cd concentration, and concentration of the third element in good agreement with experimental results. (U.S.)

  8. Ultra-broad band, low power, highly efficient coherent wavelength conversion in quantum dot SOA.

    Science.gov (United States)

    Contestabile, G; Yoshida, Y; Maruta, A; Kitayama, K

    2012-12-03

    We report broadband, all-optical wavelength conversion over 100 nm span, in full S- and C-band, with positive conversion efficiency with low optical input power exploiting dual pump Four-Wave-Mixing in a Quantum Dot Semiconductor Optical Amplifier (QD-SOA). We also demonstrate by Error Vector Magnitude analysis the full transparency of the conversion scheme for coherent modulation formats (QPSK, 8-PSK, 16-QAM, OFDM-16QAM) in the whole C-band.

  9. The dynamics of a shear band

    Science.gov (United States)

    Giarola, Diana; Capuani, Domenico; Bigoni, Davide

    2018-03-01

    A shear band of finite length, formed inside a ductile material at a certain stage of a continued homogeneous strain, provides a dynamic perturbation to an incident wave field, which strongly influences the dynamics of the material and affects its path to failure. The investigation of this perturbation is presented for a ductile metal, with reference to the incremental mechanics of a material obeying the J2-deformation theory of plasticity (a special form of prestressed, elastic, anisotropic, and incompressible solid). The treatment originates from the derivation of integral representations relating the incremental mechanical fields at every point of the medium to the incremental displacement jump across the shear band faces, generated by an impinging wave. The boundary integral equations (under the plane strain assumption) are numerically approached through a collocation technique, which keeps into account the singularity at the shear band tips and permits the analysis of an incident wave impinging a shear band. It is shown that the presence of the shear band induces a resonance, visible in the incremental displacement field and in the stress intensity factor at the shear band tips, which promotes shear band growth. Moreover, the waves scattered by the shear band are shown to generate a fine texture of vibrations, parallel to the shear band line and propagating at a long distance from it, but leaving a sort of conical shadow zone, which emanates from the tips of the shear band.

  10. Coupled polaritonic band gaps in the anisotropic piezoelectric superlattices

    Science.gov (United States)

    Tang, Zheng-Hua; Jiang, Zheng-Sheng; Chen, Tao; Jiang, Chun-Zhi; Lei, Da-Jun; Huang, Jian-Quan; Qiu, Feng; Yao, Min; Huang, Xiao-Yi

    2018-01-01

    Anisotropic piezoelectric superlattices (APSs) with the periodic arrangement of polarized anisotropic piezoelectric domains in a certain direction are presented, in which the coupled polaritonic band gaps (CPBGs) can be obtained in the whole Brillouin Zone and the maximum relative bandwidth (band-gap sizes divided by their midgap frequencies) of 5.1% can be achieved. The general characteristics of the APSs are similar to those of the phononic crystals composed of two types of materials, with the main difference being the formation mechanism of the CPBGs, which originate from the couplings between lattice vibrations along two different directions and electromagnetic waves rather than from the periodical modulation of density and elastic constants. In addition, there are no lattice mismatches because the APSs are made of the same material. Thus, the APSs can also be extended to the construction of novel acousto-optic devices.

  11. Band and percolation approaches to low temperature properties of manganites

    Energy Technology Data Exchange (ETDEWEB)

    Gor' kov, L.P. (Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. L.D. Landau Inst. for Theoretical Physics (Russian Federation)); Kresin, V.Z. (Lawrence Berkeley Lab., CA (United States))

    1998-12-20

    Properties of the parent compound, LaMnO[sub 3] are greatly affected by strong Hund's coupling. Assuming the antiferromagnetic ordering (with a low Neel temperature) along one of the cubic axes, this coupling would result in formation of disconnected ferromagnetic layers. Furthermore, in the presence of the cooperative Jahn-Teller effect the compound becomes a band insulator. At small doping (La[sub 1[minus]x]Ca[sub x]MnO[sub 3], x [much lt] 1) the band insulator phase coexists with the presence of localized holes. An insulator-ferromagnetic metal transition occurs at the percolation point x[sub c] = 0.16.

  12. Aerosol Properties From Combined Oxygen A Band Radiances and Lidar

    Science.gov (United States)

    Winker, Dave; Zhai, Peng-Wang; Hu, Yongxiang

    2015-01-01

    We have developed a new aerosol retrieval technique based on combing high-resolution A band spectra with lidar profiles. Our goal is the development of a technique to retrieve aerosol absorption, one of the critical parameters affecting the global radiation budget and one which is currently poorly constrained by satellite measurements. Our approach relies on two key factors: 1) the use of high spectral resolution (17,000:1) measurements which resolve the A-band line structure, and 2) the use of co-located lidar profile measurements to constrain the vertical distribution of scatterers in the forward model. The algorithm has been developed to be applied to observations from the CALIPSO and OCO-2 satellites, flying in formation as part of the A-train constellation. We describe the approach and present simulated retrievals to illustrate performance potential.

  13. NLTE ANALYSIS OF HIGH-RESOLUTION H -BAND SPECTRA. I. NEUTRAL SILICON

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Junbo; Shi, Jianrong; Liu, Chao [Key Laboratory of Optical Astronomy, National Astronomical Observatories, Chinese Academy of Sciences, A20 Datun Road, Chaoyang District, Beijing 100012 (China); Pan, Kaike [Apache Point Observatory and New Mexico State University, P.O. Box 59, Sunspot, NM, 88349-0059 (United States); Prieto, Carlos Allende, E-mail: sjr@bao.ac.cn [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2016-12-20

    We investigated the reliability of our silicon atomic model and the influence of non-local thermodynamical equilibrium (NLTE) on the formation of neutral silicon (Si i) lines in the near-infrared (near-IR) H -band. We derived the differential Si abundances for 13 sample stars with high-resolution H -band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE), as well as from optical spectra, both under local thermodynamical equilibrium (LTE) and NLTE conditions. We found that the differences between the Si abundances derived from the H -band and from optical lines for the same stars are less than 0.1 dex when the NLTE effects are included, and that NLTE reduces the line-to-line scatter in the H -band spectra for most sample stars. These results suggest that our Si atomic model is appropriate for studying the formation of H -band Si lines. Our calculations show that the NLTE corrections of the Si i H -band lines are negative, i.e., the final Si abundances will be overestimated in LTE. The corrections for strong lines depend on surface gravity, and tend to be larger for giants, reaching ∼−0.2 dex in our sample, and up to ∼−0.4 dex in extreme cases of APOGEE targets. Thus, the NLTE effects should be included in deriving silicon abundances from H -band Si i lines, especially for the cases where only strong lines are available.

  14. Adaptive Confidence Bands for Nonparametric Regression Functions.

    Science.gov (United States)

    Cai, T Tony; Low, Mark; Ma, Zongming

    2014-01-01

    A new formulation for the construction of adaptive confidence bands in non-parametric function estimation problems is proposed. Confidence bands are constructed which have size that adapts to the smoothness of the function while guaranteeing that both the relative excess mass of the function lying outside the band and the measure of the set of points where the function lies outside the band are small. It is shown that the bands adapt over a maximum range of Lipschitz classes. The adaptive confidence band can be easily implemented in standard statistical software with wavelet support. Numerical performance of the procedure is investigated using both simulated and real datasets. The numerical results agree well with the theoretical analysis. The procedure can be easily modified and used for other nonparametric function estimation models.

  15. X-BAND KLYSTRON DEVELOPMENT AT SLAC

    Energy Technology Data Exchange (ETDEWEB)

    Vlieks, Arnold E.; /SLAC

    2009-08-03

    The development of X-band klystrons at SLAC originated with the idea of building an X-band Linear Collider in the late 1980's. Since then much effort has been expended in developing a reliable X-band Power source capable of delivering >50 MW RF power in pulse widths >1.5 {micro}s. I will report on some of the technical issues and design strategies which have led to the current SLAC klystron designs.

  16. ANALISIS TIPOGRAFI PADA LOGOTYPE BAND FORGOTTEN

    OpenAIRE

    Atang Riyan Isnandar; wantoro wantoro wantoro

    2016-01-01

    Abstrak Forgotten merupakan band asal kota Bandung yang beraliran death metal. Band ini telah memiliki beberapa album yang cukup sukses. Salah satu faktor yang turut berperan penting dalam album-album Forgotten adalah desain sampul album. Sampul album merupakan identitas dan pesan dari musik yang dibawakan oleh Forgotten. Dalam sampul album, terdapat salah satu elemen visual yaitu Tipografi. Salah satu peran tipografi dalam sampul album Forgotten adalah sebagai logotype dari band. Yang menar...

  17. Computational Design of Flat-Band Material

    Science.gov (United States)

    Hase, I.; Yanagisawa, T.; Kawashima, K.

    2018-02-01

    Quantum mechanics states that hopping integral between local orbitals makes the energy band dispersive. However, in some special cases, there are bands with no dispersion due to quantum interference. These bands are called as flat band. Many models having flat band have been proposed, and many interesting physical properties are predicted. However, no real compound having flat band has been found yet despite the 25 years of vigorous researches. We have found that some pyrochlore oxides have quasi-flat band just below the Fermi level by first principles calculation. Moreover, their valence bands are well described by a tight-binding model of pyrochlore lattice with isotropic nearest neighbor hopping integral. This model belongs to a class of Mielke model, whose ground state is known to be ferromagnetic with appropriate carrier doping and on-site repulsive Coulomb interaction. We have also performed a spin-polarized band calculation for the hole-doped system from first principles and found that the ground state is ferromagnetic for some doping region. Interestingly, these compounds do not include magnetic element, such as transition metal and rare-earth elements.

  18. Computational Design of Flat-Band Material.

    Science.gov (United States)

    Hase, I; Yanagisawa, T; Kawashima, K

    2018-02-26

    Quantum mechanics states that hopping integral between local orbitals makes the energy band dispersive. However, in some special cases, there are bands with no dispersion due to quantum interference. These bands are called as flat band. Many models having flat band have been proposed, and many interesting physical properties are predicted. However, no real compound having flat band has been found yet despite the 25 years of vigorous researches. We have found that some pyrochlore oxides have quasi-flat band just below the Fermi level by first principles calculation. Moreover, their valence bands are well described by a tight-binding model of pyrochlore lattice with isotropic nearest neighbor hopping integral. This model belongs to a class of Mielke model, whose ground state is known to be ferromagnetic with appropriate carrier doping and on-site repulsive Coulomb interaction. We have also performed a spin-polarized band calculation for the hole-doped system from first principles and found that the ground state is ferromagnetic for some doping region. Interestingly, these compounds do not include magnetic element, such as transition metal and rare-earth elements.

  19. Microstructural evolution of a model, shear-banding micellar solution during shear startup and cessation.

    Science.gov (United States)

    López-Barrón, Carlos R; Gurnon, A Kate; Eberle, Aaron P R; Porcar, Lionel; Wagner, Norman J

    2014-04-01

    We present direct measurements of the evolution of the segmental-level microstructure of a stable shear-banding polymerlike micelle solution during flow startup and cessation in the plane of flow. These measurements provide a definitive, quantitative microstructural understanding of the stages observed during flow startup: an initial elastic response with limited alignment that yields with a large stress overshoot to a homogeneous flow with associated micellar alignment that persists for approximately three relaxation times. This transient is followed by a shear (kink) band formation with a flow-aligned low-viscosity band that exhibits shear-induced concentration fluctuations and coexists with a nearly isotropic band of homogenous, highly viscoelastic micellar solution. Stable, steady banding flow is achieved only after approximately two reptation times. Flow cessation from this shear-banded state is also found to be nontrivial, exhibiting an initial fast relaxation with only minor structural relaxation, followed by a slower relaxation of the aligned micellar fluid with the equilibrium fluid's characteristic relaxation time. These measurements resolve a controversy in the literature surrounding the mechanism of shear banding in entangled wormlike micelles and, by means of comparison to existing literature, provide further insights into the mechanisms driving shear-banding instabilities in related systems. The methods and instrumentation described should find broad use in exploring complex fluid rheology and testing microstructure-based constitutive equations.

  20. Electronic structure and band alignment at an epitaxial spinel/perovskite heterojunction.

    Science.gov (United States)

    Qiao, Liang; Li, Wei; Xiao, Haiyan; Meyer, Harry M; Liang, Xuelei; Nguyen, N V; Weber, William J; Biegalski, Michael D

    2014-08-27

    The electronic properties of solid-solid interfaces play critical roles in a variety of technological applications. Recent advances of film epitaxy and characterization techniques have demonstrated a wealth of exotic phenomena at interfaces of oxide materials, which are critically dependent on the alignment of their energy bands across the interface. Here we report a combined photoemission and electrical investigation of the electronic structures across a prototypical spinel/perovskite heterojunction. Energy-level band alignment at an epitaxial Co3O4/SrTiO3(001) heterointerface indicates a chemically abrupt, type I heterojunction without detectable band bending at both the film and substrate. The unexpected band alignment for this typical p-type semiconductor on SrTiO3 is attributed to its intrinsic d-d interband excitation, which significantly narrows the fundamental band gap between the top of the valence band and the bottom of the conduction band. The formation of the type I heterojunction with a flat-band state results in a simultaneous confinement of both electrons and holes inside the Co3O4 layer, thus rendering the epitaxial Co3O4/SrTiO3(001) heterostructure to be a very promising material for high-efficiency luminescence and optoelectronic device applications.

  1. Spontaneous reduction of the prolapsed stomach in a case of anterior band slippage after laparoscopic adjustable gastric banding.

    Science.gov (United States)

    Darius, T; Aelvoet, Ch; Tollens, T; Vanrykel, J P

    2007-01-01

    Band slippage is a common late complication after laparoscopic adjustable gastric banding. We present the first report in literature of a spontaneous reduction of the prolapsed stomach after band deflation in a case of anterior band slippage.

  2. Behaviour of hydrogen in wide band gap oxides

    Energy Technology Data Exchange (ETDEWEB)

    Li, H.; Robertson, J. [Department of Engineering, Cambridge University, Cambridge CB2 1PZ (United Kingdom)

    2014-05-28

    The defect formation energies and atomic geometries of interstitial hydrogen in its different charge states in a number of wide band gap oxides are calculated by the Heyd, Scuseria, Ernzerhof hybrid functional. As in semiconductors, two behaviours are found, it acts either as an amphoteric defect or as a shallow donor. There are large scale lattice relaxations between the different charge states for the case of the amphoteric defect. Interestingly, we find that the +/− transition level does have a good alignment below the vacuum level, as was found previously for tetrahedral semiconductors.

  3. Behaviour of hydrogen in wide band gap oxides

    Science.gov (United States)

    Li, H.; Robertson, J.

    2014-05-01

    The defect formation energies and atomic geometries of interstitial hydrogen in its different charge states in a number of wide band gap oxides are calculated by the Heyd, Scuseria, Ernzerhof hybrid functional. As in semiconductors, two behaviours are found, it acts either as an amphoteric defect or as a shallow donor. There are large scale lattice relaxations between the different charge states for the case of the amphoteric defect. Interestingly, we find that the +/- transition level does have a good alignment below the vacuum level, as was found previously for tetrahedral semiconductors.

  4. Strong energy-momentum dispersion of phonon-dressed carriers in the lightly doped band insulator SrTiO3

    International Nuclear Information System (INIS)

    Meevasana, W; Chen, C-C; He, R H; Mo, S-K; Shen, Z-X; Zhou, X J; Moritz, B; Lu, D H; Moore, R G; Devereaux, T P; Fujimori, S-I; Baumberger, F; Van der Marel, D; Nagaosa, N; Zaanen, J

    2010-01-01

    Much progress has been made recently in the study of the effects of electron-phonon (el-ph) coupling in doped insulators using angle-resolved photoemission (ARPES), yielding evidence for the dominant role of el-ph interactions in underdoped cuprates. As these studies have been limited to doped Mott insulators, the important question arises as to how this compares with doped band insulators where similar el-ph couplings should be at work. The archetypical case is that of perovskite SrTiO 3 (STO), well known for its giant dielectric constant of 10 000 at low temperatures, exceeding that of La 2 CuO 4 by a factor of 500. Based on this fact, it has been suggested that doped STO should be the archetypical bipolaron superconductor. Here we report an ARPES study from high-quality surfaces of lightly doped STO. In comparison to lightly doped Mott insulators, we find the signatures of only moderate el-ph coupling; a dispersion anomaly associated with the low-frequency optical phonon with a λ ' ∼0.3 and an overall bandwidth renormalization suggesting an overall λ ' ∼0.7 coming from the higher frequency phonons. Furthermore, we find no clear signatures of the large pseudogap or small-polaron phenomena. These findings demonstrate that a large dielectric constant itself is not a good indicator of el-ph coupling and highlight the unusually strong effects of the el-ph coupling in doped Mott insulators.

  5. Solid State KA-Band, Solid State W-Band and TWT Amplifiers, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Phase I of the proposal describes plans to develop a state of the art transmitter for the W-Band and KA -Band Cloud Radar system. Our focus will be concentrated in...

  6. Effect of band gap engineering in anionic-doped TiO2 photocatalyst

    International Nuclear Information System (INIS)

    Samsudin, Emy Marlina; Abd Hamid, Sharifah Bee

    2017-01-01

    Highlights: • Band gap engineering using anion dopants. • Mid band energy level. • Ti 3+ and oxygen vacancies as impurities states. • Valence band tail extension due to doping. • Wider solar light absorption. - Abstract: A simple yet promising strategy to modify TiO 2 band gap was achieved via dopants incorporation which influences the photo-responsiveness of the photocatalyst. The mesoporous TiO 2 was successfully mono-doped and co-doped with nitrogen and fluorine dopants. The results indicate that band gap engineering does not necessarily requires oxygen substitution with nitrogen or/and fluorine, but from the formation of additional mid band and Ti 3+ impurities states. The formation of oxygen vacancies as a result of modified color centres and Ti 3+ ions facilitates solar light absorption and influences the transfer, migration and trapping of the photo-excited charge carriers. The synergy of dopants in co-doped TiO 2 shows better optical properties relative to single N and F doped TiO 2 with c.a 0.95 eV band gap reduction. Evidenced from XPS, the synergy between N and F in the co-doped TiO 2 uplifts the valence band towards the conduction band. However, the photoluminescence data reveals poorer electrons and holes separation as compared to F-doped TiO 2 . This observation suggests that efficient solar light harvesting was achievable via N and F co-doping, but excessive defects could act as charge carriers trapping sites.

  7. Effect of band gap engineering in anionic-doped TiO{sub 2} photocatalyst

    Energy Technology Data Exchange (ETDEWEB)

    Samsudin, Emy Marlina; Abd Hamid, Sharifah Bee, E-mail: sharifahbee@um.edu.my

    2017-01-01

    Highlights: • Band gap engineering using anion dopants. • Mid band energy level. • Ti{sup 3+} and oxygen vacancies as impurities states. • Valence band tail extension due to doping. • Wider solar light absorption. - Abstract: A simple yet promising strategy to modify TiO{sub 2} band gap was achieved via dopants incorporation which influences the photo-responsiveness of the photocatalyst. The mesoporous TiO{sub 2} was successfully mono-doped and co-doped with nitrogen and fluorine dopants. The results indicate that band gap engineering does not necessarily requires oxygen substitution with nitrogen or/and fluorine, but from the formation of additional mid band and Ti{sup 3+} impurities states. The formation of oxygen vacancies as a result of modified color centres and Ti{sup 3+} ions facilitates solar light absorption and influences the transfer, migration and trapping of the photo-excited charge carriers. The synergy of dopants in co-doped TiO{sub 2} shows better optical properties relative to single N and F doped TiO{sub 2} with c.a 0.95 eV band gap reduction. Evidenced from XPS, the synergy between N and F in the co-doped TiO{sub 2} uplifts the valence band towards the conduction band. However, the photoluminescence data reveals poorer electrons and holes separation as compared to F-doped TiO{sub 2}. This observation suggests that efficient solar light harvesting was achievable via N and F co-doping, but excessive defects could act as charge carriers trapping sites.

  8. Maximizing band gaps in plate structures

    DEFF Research Database (Denmark)

    Halkjær, Søren; Sigmund, Ole; Jensen, Jakob Søndergaard

    2006-01-01

    Band gaps, i.e., frequency ranges in which waves cannot propagate, can be found in elastic structures for which there is a certain periodic modulation of the material properties or structure. In this paper, we maximize the band gap size for bending waves in a Mindlin plate. We analyze an infinite...

  9. Link adaptation in unlicensed radio bands

    NARCIS (Netherlands)

    Haartsen, J.C.; Schutter, George B.W.

    2005-01-01

    This paper presents a new collaborative mechanism for efficient coordination of radio communication devices, in particular addressing the unlicensed ISM band at 2.4 GHz. As the traffic in the ISM band is increasing tremendously, the potential for interference between uncoordinated devices is

  10. Symptomatic mesodiverticular bands in children | Bertozzi | Annals ...

    African Journals Online (AJOL)

    Symptomatic mesodiverticular bands in children. ... Abstract. Objective: The aim of this study was to review the English literature about a rare condition such as symptomatic mesodiverticular bands (MDBs) in children. Background: The MDB is an ... All cases reported an intestinal occlusion as clinical picture. Internal hernia ...

  11. Concert Band Instrumentation: Realities and Remedies.

    Science.gov (United States)

    Rogers, George L.

    1991-01-01

    Suggests ways to solve problems resulting from imbalanced instrumentation in school concert bands. Identifies sources of imbalance. Encourages band directors to plan for correct instrumentation, to match students' characteristics and abilities to instruments, and to recruit students to play needed instruments. Discusses the benefits of balanced…

  12. Low band gap polymers for organic photovoltaics

    DEFF Research Database (Denmark)

    Bundgaard, Eva; Krebs, Frederik C

    2007-01-01

    Low band gap polymer materials and their application in organic photovoltaics (OPV) are reviewed. We detail the synthetic approaches to low band gap polymer materials starting from the early methodologies employing quinoid homopolymer structures to the current state of the art that relies...... in photovoltaic applications and give a tabular overview of rarely applied materials....

  13. Complex band structure and electronic transmission eigenchannels

    DEFF Research Database (Denmark)

    Jensen, Anders; Strange, Mikkel; Smidstrup, Soren

    2017-01-01

    molecular junctions. The molecular junctions show that both the length dependence of the total transmission and the individual transmission eigenvalues can be, almost always, found through the complex band structure. The complex band structure of the semi-conducting material, however, does not predict...

  14. Stop! Look! Listen! for Effective Band Rehearsals.

    Science.gov (United States)

    Townsend, Alfred S.

    2003-01-01

    Discusses how band conductors can develop student skills in three areas: (1) when the conductor stops the band; (2) teaching the students to pay attention and watch the conductor; and (3) improving the student listening skills. Includes information on instructing students to play chorales. (CMK)

  15. Conduction bands in classical periodic potentials

    Indian Academy of Sciences (India)

    a quantum particle in a conduction band and drift at a constant average velocity through the potential as if it were undergoing resonant tunnelling. The classical conduction bands for this potential are determined numerically with high precision. Keywords. PT symmetry; complex trajectories; complex classical mechanics; ...

  16. Artificial Oxide Heterostructures with Tunable Band Gap

    Science.gov (United States)

    2016-12-20

    tunable band gap and band structures in epitaxial grown CaMnO3. The efforts have been devoted to (1) the thin film growth; (2) the tunable optical...plan to pursue a claim for personal or organizational intellectual property? Changes in research objectives (if any): Change in AFOSR Program Officer

  17. Error Analysis of Band Matrix Method

    OpenAIRE

    Taniguchi, Takeo; Soga, Akira

    1984-01-01

    Numerical error in the solution of the band matrix method based on the elimination method in single precision is investigated theoretically and experimentally, and the behaviour of the truncation error and the roundoff error is clarified. Some important suggestions for the useful application of the band solver are proposed by using the results of above error analysis.

  18. Low-Noise Band-Pass Amplifier

    Science.gov (United States)

    Kleinberg, L.

    1982-01-01

    Circuit uses standard components to overcome common limitation of JFET amplifiers. Low-noise band-pass amplifier employs JFET and operational amplifier. High gain and band-pass characteristics are achieved with suitable choice of resistances and capacitances. Circuit should find use as low-noise amplifier, for example as first stage instrumentation systems.

  19. Deformed configurations, band structures and spectroscopic ...

    Indian Academy of Sciences (India)

    2014-03-20

    Mar 20, 2014 ... nuclei, e.g., in 16O (Z = N = 8) [12,13] and 56Ni (Z = N = 28) [14–16], coexisting with the spherical ground configuration. Recently, Hwang et al [2] have observed deformed rotational bands in 82Ge. To our knowledge, these deformed rotational bands have not been studied theoretically so far though there ...

  20. Star formation

    International Nuclear Information System (INIS)

    Woodward, P.R.

    1978-01-01

    Theoretical models of star formation are discussed beginning with the earliest stages and ending in the formation of rotating, self-gravitating disks or rings. First a model of the implosion of very diffuse gas clouds is presented which relies upon a shock at the edge of a galactic spiral arm to drive the implosion. Second, models are presented for the formation of a second generation of massive stars in such a cloud once a first generation has formed. These models rely on the ionizing radiation from massive stars or on the supernova shocks produced when these stars explode. Finally, calculations of the gravitational collapse of rotating clouds are discussed with special focus on the question of whether rotating disks or rings are the result of such a collapse. 65 references

  1. Galaxy Formation

    DEFF Research Database (Denmark)

    Sparre, Martin

    Galaxy formation is an enormously complex discipline due to the many physical processes that play a role in shaping galaxies. The objective of this thesis is to study galaxy formation with two different approaches: First, numerical simulations are used to study the structure of dark matter and how...... galaxies form stars throughout the history of the Universe, and secondly it is shown that observations of gamma-ray bursts (GRBs) can be used to probe galaxies with active star formation in the early Universe. A conclusion from the hydrodynamical simulations is that the galaxies from the stateof...... is important, since it helps constraining chemical evolution models at high redshift. A new project studying how the population of galaxies hosting GRBs relate to other galaxy population is outlined in the conclusion of this thesis. The core of this project will be to quantify how the stellar mass function...

  2. Star formation

    Energy Technology Data Exchange (ETDEWEB)

    Woodward, P.R.

    1978-09-27

    Theoretical models of star formation are discussed beginning with the earliest stages and ending in the formation of rotating, self-gravitating disks or rings. First a model of the implosion of very diffuse gas clouds is presented which relies upon a shock at the edge of a galactic spiral arm to drive the implosion. Second, models are presented for the formation of a second generation of massive stars in such a cloud once a first generation has formed. These models rely on the ionizing radiation from massive stars or on the supernova shocks produced when these stars explode. Finally, calculations of the gravitational collapse of rotating clouds are discussed with special focus on the question of whether rotating disks or rings are the result of such a collapse. 65 references.

  3. Atomic-Monolayer MoS2 Band-to-Band Tunneling Field-Effect Transistor

    KAUST Repository

    Lan, Yann Wen

    2016-09-05

    The experimental observation of band-to-band tunneling in novel tunneling field-effect transistors utilizing a monolayer of MoS2 as the conducting channel is demonstrated. Our results indicate that the strong gate-coupling efficiency enabled by two-dimensional materials, such as monolayer MoS2, results in the direct manifestation of a band-to-band tunneling current and an ambipolar transport.

  4. Strong Energy-momentum Dispersion of Phonon Dressed Carriers in the Lightly Doped Band Insulator SrTiO3

    Energy Technology Data Exchange (ETDEWEB)

    Meevasana, Warawat

    2010-05-26

    Much progress has been made recently in the study of the effects of electron-phonon (el-ph) coupling in doped insulators using angle resolved photoemission (ARPES), yielding evidence for the dominant role of el-ph interactions in underdoped cuprates. As these studies have been limited to doped Mott insulators, the important question arises how this compares with doped band insulators where similar el-ph couplings should be at work. The archetypical case is the perovskite SrTiO{sub 3} (STO), well known for its giant dielectric constant of 10000 at low temperature, exceeding that of La{sub 2}CuO{sub 4} by a factor of 500. Based on this fact, it has been suggested that doped STO should be the archetypical bipolaron superconductor. Here we report an ARPES study from high-quality surfaces of lightly doped SrTiO{sub 3}. Comparing to lightly doped Mott insulators, we find the signatures of only moderate electron-phonon coupling: a dispersion anomaly associated with the low frequency optical phonon with a {lambda}{prime} {approx} 0.3 and an overall bandwidth renormalization suggesting an overall {lambda}{prime} {approx} 0.7 coming from the higher frequency phonons. Further, we find no clear signatures of the large pseudogap or small polaron phenomena. These findings demonstrate that a large dielectric constant itself is not a good indicator of el-ph coupling and highlight the unusually strong effects of the el-ph coupling in doped Mott insulators.

  5. Band-type microelectrodes for amperometric immunoassays

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ga-Yeon; Chang, Young Wook; Ko, Hyuk [Department of Materials Science and Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-gu, Seoul, 120-749 (Korea, Republic of); Kang, Min-Jung [Korea Institute of Science and Technology (KIST), Seoul (Korea, Republic of); Pyun, Jae-Chul, E-mail: jcpyun@yonsei.ac.kr [Department of Materials Science and Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-gu, Seoul, 120-749 (Korea, Republic of)

    2016-07-20

    A band-type microelectrode was made using a parylene-N film as a passivation layer. A circular-type, mm-scale electrode with the same diameter as the band-type microelectrode was also made with an electrode area that was 5000 times larger than the band-type microelectrode. By comparing the amperometric signals of 3,5,3′,5′-tetramethylbenzidine (TMB) samples at different optical density (OD) values, the band-type microelectrode was determined to be 9 times more sensitive than the circular-type electrode. The properties of the circular-type and the band-type electrodes (e.g., the shape of their cyclic voltammograms, the type of diffusion layer used, and the diffusion layer thickness per unit electrode area) were characterized according to their electrode area using the COMSOL Multiphysics software. From these simulations, the band-type electrode was estimated to have the conventional microelectrode properties, even when the electrode area was 100 times larger than a conventional circular-type electrode. These results show that both the geometry and the area of an electrode can influence the properties of the electrode. Finally, amperometric analysis based on a band-type electrode was applied to commercial ELISA kits to analyze human hepatitis B surface antigen (hHBsAg) and human immunodeficiency virus (HIV) antibodies. - Highlights: • A band-type microelectrode was made using a parylene-N film as a passivation layer. • The band-type microelectrode was 14-times more sensitive than circular-type electrode. • The influence of geometry on microelectrode properties was simulated using COMSOL. • The band-type electrode was applied to ELISA kits for hHBsAg and hHIV-antibodies.

  6. Selective Area Band Engineering of Graphene using Cobalt-Mediated Oxidation.

    Science.gov (United States)

    Bazylewski, Paul F; Nguyen, Van Luan; Bauer, Robert P C; Hunt, Adrian H; McDermott, Eamon J G; Leedahl, Brett D; Kukharenko, Andrey I; Cholakh, Seif O; Kurmaev, Ernst Z; Blaha, Peter; Moewes, Alexander; Lee, Young Hee; Chang, Gap Soo

    2015-10-21

    This study reports a scalable and economical method to open a band gap in single layer graphene by deposition of cobalt metal on its surface using physical vapor deposition in high vacuum. At low cobalt thickness, clusters form at impurity sites on the graphene without etching or damaging the graphene. When exposed to oxygen at room temperature, oxygen functional groups form in proportion to the cobalt thickness that modify the graphene band structure. Cobalt/Graphene resulting from this treatment can support a band gap of 0.30 eV, while remaining largely undamaged to preserve its structural and electrical properties. A mechanism of cobalt-mediated band opening is proposed as a two-step process starting with charge transfer from metal to graphene, followed by formation of oxides where cobalt has been deposited. Contributions from the formation of both CoO and oxygen functional groups on graphene affect the electronic structure to open a band gap. This study demonstrates that cobalt-mediated oxidation is a viable method to introduce a band gap into graphene at room temperature that could be applicable in electronics applications.

  7. Molecularly based criteria for shear banding in transient flow of entangled polymeric fluids.

    Science.gov (United States)

    Mohagheghi, Mouge; Khomami, Bamin

    2016-06-01

    Dissipative particle dynamics simulations of polymeric melts in a start-up of shear flow as a function of ramp time to its steady state value is studied. Herein, we report the molecular findings showing the effect of ramp time on the formation of shear banded structures and chain relaxation behavior. Specifically, it is shown that shear banding emerges at a rapid start-up; however, homogeneous shear prevails when the deformation rate ramp time is sufficiently slow. This finding is in full consistency with prior continuum level linear stability analysis of shear banding in start-up of shear flows as well as experimental observations of entangled DNA and polymer solutions. Further, it has been revealed that the ratio of the longest chain orientation relaxation time to that of the time for the imposed deformation rate to reach its steady state value plays a central role in determining whether local strain inhomogeneities that lead to the formation of shear banded flow structures are created. In addition, we have shown that the gradient of the number of entanglements along the velocity gradient direction should reach a critical value for the creation of localized strain inhomogeneity. Moreover, the relation between the local process leading to shear banded flows and the relaxation mechanism of the chain is discussed. Overall, a molecular picture for the interrelation between the longest chain orientation and stress relaxation time, local inhomogeneities, and shear banding has been proposed and corroborated with extensive analysis.

  8. On what controls the spacing of spontaneous adiabatic shear bands in collapsing thick-walled cylinders

    Directory of Open Access Journals (Sweden)

    Lovinger Zev

    2015-01-01

    Full Text Available Shear bands formation in collapsing thick walled cylinders occurs in a spontaneous manner. The advantage of examining spontaneous, as opposed to forced shear localization, is that it highlights the inherent susceptibility of the material to adiabatic shear banding without prescribed geometrical constraints. The Thick-Walled Cylinder technique (TWC provides a controllable and repeatable technique to create and study multiple adiabatic shear bands. The technique, reported in the literature uses an explosive cylinder to create the driving force, collapsing the cylindrical sample. Recently, we developed an electro-magnetic set-up using a pulsed current generator to provide the collapsing force, replacing the use of explosives. Using this platform we examined the shear band evolution at different stages of formation in 7 metallic alloys, spanning a wide range of strength and failure properties. We examined the number of shear bands and spacing between them for the different materials to try and figure out what controls these parameters. The examination of the different materials enabled us to better comprehend the mechanisms which control the spatial distribution of multiple shear bands in this geometry. The results of these tests are discussed and compared to explosively driven collapsing TWC results in the literature and to existing analytical models for spontaneous adiabatic shear localization.

  9. Selective Area Band Engineering of Graphene using Cobalt-Mediated Oxidation

    Science.gov (United States)

    Bazylewski, Paul F.; Nguyen, Van Luan; Bauer, Robert P.C.; Hunt, Adrian H.; McDermott, Eamon J. G.; Leedahl, Brett D.; Kukharenko, Andrey I.; Cholakh, Seif O.; Kurmaev, Ernst Z.; Blaha, Peter; Moewes, Alexander; Lee, Young Hee; Chang, Gap Soo

    2015-01-01

    This study reports a scalable and economical method to open a band gap in single layer graphene by deposition of cobalt metal on its surface using physical vapor deposition in high vacuum. At low cobalt thickness, clusters form at impurity sites on the graphene without etching or damaging the graphene. When exposed to oxygen at room temperature, oxygen functional groups form in proportion to the cobalt thickness that modify the graphene band structure. Cobalt/Graphene resulting from this treatment can support a band gap of 0.30 eV, while remaining largely undamaged to preserve its structural and electrical properties. A mechanism of cobalt-mediated band opening is proposed as a two-step process starting with charge transfer from metal to graphene, followed by formation of oxides where cobalt has been deposited. Contributions from the formation of both CoO and oxygen functional groups on graphene affect the electronic structure to open a band gap. This study demonstrates that cobalt-mediated oxidation is a viable method to introduce a band gap into graphene at room temperature that could be applicable in electronics applications. PMID:26486966

  10. NLTE ANALYSIS OF HIGH-RESOLUTION H -BAND SPECTRA. II. NEUTRAL MAGNESIUM

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Junbo; Shi, Jianrong; Liu, Chao [Key Laboratory of Optical Astronomy, National Astronomical Observatories, Chinese Academy of Sciences, A20 Datun Road, Chaoyang District, Beijing 100012 (China); Pan, Kaike [Apache Point Observatory and New Mexico State University, P.O. Box 59, Sunspot, NM 88349-0059 (United States); Prieto, Carlos Allende, E-mail: sjr@bao.ac.cn [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2017-01-20

    Aiming at testing the validity of our magnesium atomic model and investigating the effects of non-local thermodynamical equilibrium (NLTE) on the formation of the H -band neutral magnesium lines, we derive the differential Mg abundances from selected transitions for 13 stars either adopting or relaxing the assumption of local thermodynamical equilibrium (LTE). Our analysis is based on high-resolution and high signal-to-noise ratio H -band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and optical spectra from several instruments. The absolute differences between the Mg abundances derived from the two wavelength bands are always less than 0.1 dex in the NLTE analysis, while they are slightly larger for the LTE case. This suggests that our Mg atomic model is appropriate for investigating the NLTE formation of the H -band Mg lines. The NLTE corrections for the Mg i H -band lines are sensitive to the surface gravity, becoming larger for smaller log g values, and strong lines are more susceptible to departures from LTE. For cool giants, NLTE corrections tend to be negative, and for the strong line at 15765 Å they reach −0.14 dex in our sample, and up to −0.22 dex for other APOGEE stars. Our results suggest that it is important to include NLTE corrections in determining Mg abundances from the H -band Mg i transitions, especially when strong lines are used.

  11. Effect of band gap engineering in anionic-doped TiO2 photocatalyst

    Science.gov (United States)

    Samsudin, Emy Marlina; Abd Hamid, Sharifah Bee

    2017-01-01

    A simple yet promising strategy to modify TiO2 band gap was achieved via dopants incorporation which influences the photo-responsiveness of the photocatalyst. The mesoporous TiO2 was successfully mono-doped and co-doped with nitrogen and fluorine dopants. The results indicate that band gap engineering does not necessarily requires oxygen substitution with nitrogen or/and fluorine, but from the formation of additional mid band and Ti3+ impurities states. The formation of oxygen vacancies as a result of modified color centres and Ti3+ ions facilitates solar light absorption and influences the transfer, migration and trapping of the photo-excited charge carriers. The synergy of dopants in co-doped TiO2 shows better optical properties relative to single N and F doped TiO2 with c.a 0.95 eV band gap reduction. Evidenced from XPS, the synergy between N and F in the co-doped TiO2 uplifts the valence band towards the conduction band. However, the photoluminescence data reveals poorer electrons and holes separation as compared to F-doped TiO2. This observation suggests that efficient solar light harvesting was achievable via N and F co-doping, but excessive defects could act as charge carriers trapping sites.

  12. Geomechanical Modeling of Deformation Banding in the Navajo Sandstone, San Rafael Monocline, Utah

    Science.gov (United States)

    Gutierrez, M.; Sundal, A.; Petrie, E. S.

    2017-12-01

    Deformation bands are ubiquitous geological features in many types of rocks. Depending on their micro-structure, they can act either as conduits or barriers to fluid flow. Given the significant roles deformation bands play in fluid flow and chemical transport in rocks, it is important to develop fundamental understanding of their origin, and their characteristics as they relate with the host rock properties and their depositional and structural-geological history. We present a forward-modeling technique based on the geomechanical Bifurcation Theory (BT) to predict the formation of deformation bands in sandstone. According to BT, the formation of deformation bands is a result of strain location, which in turn stems from instability in the stress-strain response of materials during loading. Due to bifurcation, a material which undergoes homogeneous deformation can reach a point at which the material experiences instability and deformation starts to become non-homogenous. We implemented BT in the commercially-available geomechanical code FLAC (Fast Langragian Analysis of Continua) and applied it in the field-scale modeling of deformation banding in the Navajo Sandstone in the San Rafael Monocline in Utah induced by fault propagation folding. The results show that geomechanical modeling using BT has a powerful potential to simulate the physical processes in the formation of deformation banding in rocks. Predicted deformation bands, specifically the pervasive bedding-parallel bands in the Navajo sandstone formation, normal faulting in the upper limb and reverse faulting in the lower limb, are generally in agreement with field observations. Predictions indicate that the pervasive bedding-parallel bands in the Navajo Sandstone are transitional compaction-shear bands with alternating zones of volumetric compaction and dilation. These predictions are consistent with petrographic analysis of thin sections of rock samples from the Navajo Sandstone. The most important

  13. Band Jahn-Teller structural phase transition in Y2In

    Science.gov (United States)

    Svanidze, E.; Georgen, C.; Hallas, A. M.; Huang, Q.; Santiago, J. M.; Lynn, J. W.; Morosan, E.

    2018-02-01

    The number of paramagnetic materials that undergo a structural phase transition is rather small, which can perhaps explain the limited understanding of the band Jahn-Teller mechanism responsible for this effect. Here we present a structural phase transition observed in paramagnetic Y2In at temperature T0=250 ±5 K. Below T0, the high-temperature hexagonal P 63/m m c phase transforms into the low-temperature orthorhombic P n m a phase. This transition is accompanied by an unambiguous thermal hysteresis of about 10 K, observed in both magnetic susceptibility M /H (T ) and resistivity ρ (T ) , indicating a first-order transition. Band structure calculations suggest a band Jahn-Teller mechanism, during which the degeneracy of electron bands close to the Fermi energy is broken. We establish that this structural phase transition does not have a magnetic component; however, the possibility of a charge density wave formation has not been eliminated.

  14. Graphene-induced band gap renormalization in polythiophene: a many-body perturbation study

    Science.gov (United States)

    Marsusi, F.; Fedorov, I. A.; Gerivani, S.

    2018-01-01

    Density functional theory and many-body perturbation theory at the G0W0 level are employed to study the electronic properties of polythiophene (PT) adsorbed on the graphene surface. Analysis of the charge density difference shows that substrate-adsorbate interaction leads to a strong physisorption and interfacial electric dipole moment formation. The electrostatic potential displays a  -0.19 eV shift in the graphene work function from its initial value of 4.53 eV, as the result of the interaction. The LDA band gap of the polymer does not show any change. However, the band structure exhibits weak orbital hybridizations resulting from slight overlapping between the polymer and graphene states wave functions. The interfacial polarization effects on the band gap and levels alignment are investigated at the G0W0 level and show a notable reduction of PT band gap compared to that of the isolated chain.

  15. DISCOVERY OF SiO BAND EMISSION FROM GALACTIC B[e] SUPERGIANTS

    Energy Technology Data Exchange (ETDEWEB)

    Kraus, M. [Astronomický ústav, Akademie věd České republiky, Fričova 298, 251 65 Ondřejov (Czech Republic); Oksala, M. E. [LESIA, Observatoire de Paris, CNRS UMR 8109, UPMC, Université Paris Diderot, 5 place Jules Janssen, F-92190, Meudon (France); Cidale, L. S.; Arias, M. L.; Torres, A. F. [Departamento de Espectroscopía Estelar, Facultad de Ciencias Astronómicas y Geofísicas, Universidad Nacional de La Plata (Argentina); Fernandes, M. Borges, E-mail: michaela.kraus@asu.cas.cz [Observatório Nacional, Rua General José Cristino 77, 20921-400 São Cristovão, Rio de Janeiro (Brazil)

    2015-02-20

    B[e] supergiants (B[e]SGs) are evolved massive stars in a short-lived transition phase. During this phase, these objects eject large amounts of material, which accumulate in a circumstellar disk-like structure. The expelled material is typically dense and cool, providing the cradle for molecule and dust condensation and for a rich, ongoing chemistry. Very little is known about the chemical composition of these disks, beyond the emission from dust and CO revolving around the star on Keplerian orbits. As massive stars preserve an oxygen-rich surface composition throughout their life, other oxygen-based molecules can be expected to form. As SiO is the second most stable oxygen compound, we initiated an observing campaign to search for first-overtone SiO emission bands. We obtained high-resolution near-infrared L-band spectra for a sample of Galactic B[e]SGs with reported CO band emission. We clearly detect emission from the SiO first-overtone bands in CPD-52 9243 and indications for faint emission in HD 62623, HD 327083, and CPD-57 2874. From model fits, we find that in all these stars the SiO bands are rotationally broadened with a velocity lower than observed in the CO band forming regions, suggesting that SiO forms at larger distances from the star. Hence, searching for and analyzing these bands is crucial for studying the structure and kinematics of circumstellar disks, because they trace complementary regions to the CO band formation zone. Moreover, since SiO molecules are the building blocks for silicate dust, their study might provide insight in the early stage of dust formation.

  16. Temperature and composition dependent density of states extracted using overlapping large polaron tunnelling model in MnxCo1-xFe2O4 (x=0.25, 0.5, 0.75) nanoparticles

    Science.gov (United States)

    Jamil, Arifa; Afsar, M. F.; Sher, F.; Rafiq, M. A.

    2017-03-01

    We report detailed ac electrical and structural characterization of manganese cobalt ferrite nanoparticles, prepared by coprecipitation technique. X-ray diffraction (XRD) confirmed single-phase cubic spinel structure of the nanoparticles. Tetrahedral (A) and octahedral (B) group complexes were present in the spinel lattice as determined by Fourier Transform Infrared Spectroscopy (FTIR). Scanning Electron Microscope (SEM) images revealed presence of spherical shape nanoparticles having an average diameter 50-80 nm. Composition, temperature and frequency dependent ac electrical study of prepared nanoparticles interpreted the role of cationic distribution between A and B sites. Overlapping large polaron tunnelling (OLPT) conduction mechanism was observed from 290 to 200 K. Frequency exponent s was fitted theoretically using OLPT model. High values of Density of States (DOS) of the order of 1022-1024 eV-1 cm-3 were extracted from ac conductivity for different compositions. We found that DOS was dependent on distribution of cations in the tunnel-type cavities along the a and b axis.

  17. [Spectral power of theta and alpha EEG-bands in preschool children with different level of set plasticity].

    Science.gov (United States)

    Ashkinazi, M L

    2010-01-01

    Spectral power of theta and alpha EEG-bands at different stages of visual set was studied in 5-7-year-old children. Children with a plastic set had greater alpha-band spectral power values than children with a rigid set. At set formation stage children with a rigid set displayed an increase of theta-band EEG-power, which is a manifestation of "immature" arousal reaction. Children with a plastic set displayed at set formation stage an increase of alpha-band spectral power in bilateral occipital brain areas. Dynamics of EEG spectral power differed in children before and after 6 years of age. At set formation stage 5-6-year-olds displayed an above-mentioned "immature" arousal reaction, and 6-7-year-olds--an increase of alpha-band spectral power in occipital brain areas. At set actualization stage 6-7-year-olds displayed an increase of alpha-band spectral power in right posterior brain areas. At set extinction in this group a bilateral decrease of alpha-band spectral power in mid-frontal areas was observed. An importance for a quick set-shifting of certain brain areas' involvement in the process of visual perception is discussed.

  18. The Novel Microwave Stop-Band Filter

    Directory of Open Access Journals (Sweden)

    R. E. Chernobrovkin

    2008-01-01

    Full Text Available The stop-band filter with the new band-rejection element is proposed. The element is a coaxial waveguide with the slot in the centre conductor. In the frame of this research, the numerical and experimental investigations of the amplitude-frequency characteristics of the filter are carried out. It is noted that according to the slot parameters the two typical resonances (half-wave and quarter-wave can be excited. The rejection band of the single element is defined by the width, depth, and dielectric filling of the slot. Fifth-order Chebyshev filter utilizing the aforementioned element is also synthesized, manufactured, and tested. The measured and simulated results are in good agreement. The experimental filter prototype exhibits the rejection band 0.86 GHz at the level −40 dB.

  19. Deployable Ka-Band Reflectarray, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Tyvak, in collaboration with UCLA, proposes a novel approach to the challenge of creating a large reflector for Ka-band high data rate links. We propose to attach...

  20. Full L-S Band Telemetry System

    National Research Council Canada - National Science Library

    Jensen, Michael

    2001-01-01

    Recent changes in spectrum availability as well as higher demands for spectrum have motivated the development of telemetry transmit systems capable of fully operating over both L and S telemetry bands...

  1. Full L-S Band Telemetry System

    National Research Council Canada - National Science Library

    Jensen, Michael

    2003-01-01

    Recent changes in spectrum availability as well as higher demands for spectrum have motivated the development of telemetry transmit systems capable of fully operating over both L and S telemetry bands...

  2. Full L-S Band Telemetry System

    National Research Council Canada - National Science Library

    Jensen, Michael

    2002-01-01

    Recent changes in spectrum availability as well as higher demands for spectrum have motivated the development of telemetry transmit systems capable of fully operating over both L and S telemetry bands...

  3. Confidence bands for inverse regression models

    International Nuclear Information System (INIS)

    Birke, Melanie; Bissantz, Nicolai; Holzmann, Hajo

    2010-01-01

    We construct uniform confidence bands for the regression function in inverse, homoscedastic regression models with convolution-type operators. Here, the convolution is between two non-periodic functions on the whole real line rather than between two periodic functions on a compact interval, since the former situation arguably arises more often in applications. First, following Bickel and Rosenblatt (1973 Ann. Stat. 1 1071–95) we construct asymptotic confidence bands which are based on strong approximations and on a limit theorem for the supremum of a stationary Gaussian process. Further, we propose bootstrap confidence bands based on the residual bootstrap and prove consistency of the bootstrap procedure. A simulation study shows that the bootstrap confidence bands perform reasonably well for moderate sample sizes. Finally, we apply our method to data from a gel electrophoresis experiment with genetically engineered neuronal receptor subunits incubated with rat brain extract

  4. The role of deformation bands controlling reservoir quality in a salt-walled mini-basin, Central North Sea, UK

    Science.gov (United States)

    Davies, Philip; Jones, Stuart; Imber, Jonathan

    2017-04-01

    At shallow burial depths, sediments are typically poorly consolidated and subject to low confining pressure and differential stress. Fractures that form in poorly consolidated and therefore non-lithified sediments would be unable to remain open. However, the large amount of pore space present would allow for processes such as grain sliding and grain rolling, resulting in the formation of deformation bands. The structure and style of the resulting deformation bands would depend on the size, shape and sorting of the grains, as well as early cementation, porosity and the orientation and magnitude of the local stresses. Previous studies on deformation bands in general have shown that they produce an anisotropy that can affect fluid flow. Early deformation band formation near the surface may also influence later diagenesis at greater burial depths, and thus have a further impact on fluid flow in sandstone. Dilatant (deformation) bands are commonly reported for poorly consolidated sandstones at surface or near-surface conditions (fractures, faults and deformation bands create a complex system of permeable fluid pathways and cemented baffles at deeper burial. The results presented highlight the importance of constraining the occurrence of dilation and dilatant shear bands along the margins of salt-walled mini-basins to better understand the kinematics of the salt movement and additional loading on adjacent sediments. Furthermore, this research identifies the importance of early formed deformation bands in controlling meteoric water influx and governing later reservoir quality for spatially and temporally complex sedimentary fills of salt-walled mini-basins.

  5. Intraluminal penetration of the band in patients with adjustable silicone gastric banding: radiological findings

    Energy Technology Data Exchange (ETDEWEB)

    Pretolesi, F.; Derchi, L.E. [Cattedra di Radiologia R, Univ. di Genova (Italy); Camerini, G.; Gianetta, E.; Marinari, G.M.; Scopinaro, N. [Semeiotica Chirurgica R, Univ. di Genova (Italy)

    2001-03-01

    The aim of this study was to analyse radiological findings in patients surgically treated for adjustable silicone gastric banding (ASGB) for morbid obesity complicated by band penetration into the gastric lumen. We reviewed the records of four patients with surgically confirmed penetration of gastric band into the gastric lumen; three had preoperative opaque meal, one only a plain abdominal film. Vomiting was the presenting symptom in two cases, whereas others had new weight gain and loss of early satiety. Two patients had normally closed bands: radiography showed that their position had changed from previous controls and the barium meal had passed out of their lumen. Two patients had an open band. One patient had the band at the duodeno-jejunal junction, and the tube connecting the band to the subcutaneous port presented a winding course suggesting the duodenum. In the other case, both plain film and barium studies failed to demonstrate with certainty the intragastric position of the band. As ASGB is becoming widely used, radiologists need to be familiar with its appearances and its complications. Band penetration into the stomach is a serious complication which needs band removal. Patients with this problem, often with non-specific symptoms and even those who are asymptomatic, are encountered during radiographic examinations requested either for gastric problems or follow-up purposes, and have to be properly diagnosed. (orig.)

  6. C-band Scatterometers and Their Applications

    OpenAIRE

    Naeimi, Vahid; Wagner, Wolfgang

    2010-01-01

    C-band scatterometers have demonstrated to be valuable sensors for large-scale observation of the Earth's surface in a variety of disciplines. High temporal sampling in all weather conditions, multi-viewing capability and availability of long-term measurements make the European C-band scatterometers excellent Earth observation tools. Scatterometer data are used to extract geophysical parameters such as wind speed and direction, surface soil moisture, seasonal dynamics of vegetation, spatial a...

  7. Electron correlations in narrow band systems

    International Nuclear Information System (INIS)

    Kishore, R.

    1983-01-01

    The effect of the electron correlations in narrow bands, such as d(f) bands in the transition (rare earth) metals and their compounds and the impurity bands in doped semiconductors is studied. The narrow band systems is described, by the Hubbard Hamiltonian. By proposing a local self-energy for the interacting electron, it is found that the results are exact in both atomic and band limits and reduce to the Hartree Fock results for U/Δ → 0, where U is the intra-atomic Coulomb interaction and Δ is the bandwidth of the noninteracting electrons. For the Lorentzian form of the density of states of the noninteracting electrons, this approximation turns out to be equivalent to the third Hubbard approximation. A simple argument, based on the mean free path obtained from the imaginary part of the self energy, shows how the electron correlations can give rise to a discontinous metal-nonmetal transition as proposed by Mott. The band narrowing and the existence of the satellite below the Fermi energy in Ni, found in photoemission experiments, can also be understood. (Author) [pt

  8. Cement Formation

    DEFF Research Database (Denmark)

    Telschow, Samira; Jappe Frandsen, Flemming; Theisen, Kirsten

    2012-01-01

    Cement production has been subject to several technological changes, each of which requires detailed knowledge about the high multiplicity of processes, especially the high temperature process involved in the rotary kiln. This article gives an introduction to the topic of cement, including...... an overview of cement production, selected cement properties, and clinker phase relations. An extended summary of laboratory-scale investigations on clinkerization reactions, the most important reactions in cement production, is provided. Clinker formations by solid state reactions, solid−liquid and liquid...

  9. Digtets formater

    DEFF Research Database (Denmark)

    Schmidt, Michael Kallesøe; Rasmussen, Krista Stinne Greve; Skriver, Svend

    2017-01-01

    definition of text and work can be supplemented by a hermeneutical dimension, thus taking various versions of works and the influence of their respective media (blog, book etc.) on the percipient into account. In connection with the theoretical considerations, a handful of recent works by Lea Marie...... Løppenthin, Olga Ravn, Mikkel Thykier, Caspar Eric, and Simon Grotrian are discussed. By using the format as a point of departure rather than applying a more conventional practice of close reading, the authors argue for a broad-spectred approach to literary analysis which focuses on aspects of the conception...

  10. ISM band to U-NII band frequency transverter and method of frequency transversion

    Science.gov (United States)

    Stepp, Jeffrey David [Grandview, MO; Hensley, Dale [Grandview, MO

    2006-09-12

    A frequency transverter (10) and method for enabling bi-frequency dual-directional transfer of digitally encoded data on an RF carrier by translating between a crowded or otherwise undesirable first frequency band, such as the 2.4 GHz ISM band, and a less-crowded or otherwise desirable second frequency band, such as the 5.0 GHz 6.0 GHz U-NII band. In a preferred embodiment, the transverter (10) connects between an existing data radio (11) and its existing antenna (30), and comprises a bandswitch (12); an input RF isolating device (14); a transmuter (16); a converter (18); a dual output local oscillator (20); an output RF isolating device (22); and an antenna (24) tuned to the second frequency band. The bandswitch (12) allows for bypassing the transverter (10), thereby facilitating its use with legacy systems. The transmuter (14) and converter (16) are adapted to convert to and from, respectively, the second frequency band.

  11. Shear band formation and mechanical properties of Zr{sub 38}Ti{sub 17}Cu{sub 10.5}Co{sub 12}Be{sub 22.5} bulk metallic glass/porous tungsten phase composite by hydrostatic extrusion

    Energy Technology Data Exchange (ETDEWEB)

    Xue, Y.F., E-mail: xueyunfei@bit.edu.cn [School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Wang, L.; Cheng, H.W.; Wang, F.C. [School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Zhang, H.F. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2010-08-20

    Zr{sub 38}Ti{sub 17}Cu{sub 10.5}Co{sub 12}Be{sub 22.5} bulk metallic glass/porous tungsten phase composites were prepared via a method by combining infiltrating the molten alloy into the reinforcement with hydrostatic extrusion. The deformation and failure behavior of the as-extruded composite were investigated at room temperature under quasistatic compression. Compared to the as-cast composite, the as-extruded composite presented greater flow stress and lower fracture strain. Different from the fracture mode of multiple macro shear bands for the as-cast composite, fractrographic analysis revealed that the specimen for the as-extruded composite fractured by a mixture of shearing and axial splitting. It is suggested that the increase in flow stress for the as-extruded composite is attributed to the extrusion process which introduced hardened condition in the tungsten phase. The fracture strain of the as-extruded composite decreased by comparison with the as-cast composite is proposed to result from the joint effects of the employed extrusion process sacrificed part of the plasticity, relatively high flow stress exceeded the fracture stress of the pure metallic glass, and the elongated grain structure resulted in splitting mode for the as-extruded composite.

  12. Effects of band-tails on the subthreshold characteristics of nanowire band-to-band tunneling transistors

    Science.gov (United States)

    Khayer, M. Abul; Lake, Roger K.

    2011-10-01

    High source doping is required to support the high electric fields necessary to provide sufficient drive currents in interband tunnel field effect transistors (TFETs). High doping is associated with band-tails in the density of states that decay exponentially into the bandgap with decay constants that can be comparable to the room temperature thermal energy kBT. This compromises the core operational principal of a TFET of a hard energy cut-off to the injected channel carrier distribution provided by the source valence band edge. If the band-tails are limited to the source region, they have minimal effect for short channels ≤10 nm, since the leakage current is dominated by direct, coherent tunneling through the channel. For longer 20 nm channels, source band-tails can double the inverse subthreshold slope but still leave it below the ideal 60 mV/decade value with on-off current ratios greater than 106 using a supply voltage of 0.4 V. Band-tails both in the source and channel are more detrimental for both 10 and 20 nm channels. On-off current ratios are reduced to ≥103 and ≥104 for the 10 nm and 20 nm channel devices, respectively.

  13. Airborne Multi-Band SAR in the Arctic

    Science.gov (United States)

    Gardner, J. M.; Brozena, J. M.; Liang, R.; Ball, D.; Holt, B.; Thomson, J.

    2016-12-01

    As one component of the Office of Naval Research supported Sea State Departmental Research Initiative during October of 2015 the Naval Research Laboratory flew an ultrawide-band, low-frequency, polarimetric SAR over the southward advancing sea ice in Beaufort Sea. The flights were coordinated with the research team aboard the R/V Sikuliaq working near and in the advancing pack ice. The majority of the SAR data were collected with the L-Band sensor (1000-1500 MHz) from an altitude of 10,000', providing a useful swath 6 km wide with 75o and 25 o angles of incidence at the inner and outer edge of the swath respectively. Some data were also collected with the P-Band SAR (215-915 MHz). The extremely large bandwidths allowed for formation of image pixels as small as 30 cm, however, we selected 60 cm pixel size to reduce image speckle. The separate polarimetric images are calibrated to one pixel to allow for calculations such as polarimetric decompositions that require the images to be well aligned. Both frequencies are useful particularly for the detection of ridges and areas of deformed ice. There are advantages and disadvantages to airborne SAR imagery compared to satellites. The chief advantages being the enormous allowable bandwidth leading to very fine range resolution, and the ability to fly arbitrary trajectories on demand. The latter permits specific areas to be imaged at a given time with a specified illumination direction. An area can even be illuminated from all directions by flying a circular trajectory around the target area. This captures ice features that are sensitive to illumination direction such as cracks, sastrugi orientation, and ridges. The disadvantages include variation of intensity across the swath with range and incidence angle. In addition to the SAR data, we collected photogrammetric imagery from a DSS-439, scanning lidar from a Riegl Q560 and surface brightness temperatures from a KT-19. However, since all of these sensors are nadir pointing

  14. An ice-rich flow origin for the banded terrain in the Hellas basin, Mars

    Science.gov (United States)

    Diot, X.; El-Maarry, M. R.; Guallini, L.; Schlunegger, F.; Norton, K. P.; Thomas, N.; Sutton, S.; Grindrod, P. M.

    2015-12-01

    The interior of Hellas Basin displays a complex landscape and a variety of geomorphological domains. One of these domains, the enigmatic banded terrain covers much of the northwestern part of the basin. We use high-resolution (Context Camera and High-Resolution Imaging Science Experiment) Digital Terrain Models to show that most of the complex viscous flowing behavior exhibited by the banded terrain is controlled by topography and flow-like interactions between neighboring banded terrain. Furthermore, the interior of the basin hosts several landforms suggestive of the presence of near-surface ice, which include polygonal patterns with elongated pits, scalloped depressions, isolated mounds, and collapse structures. We suggest that thermal contraction cracking and sublimation of near-surface ice are responsible for the formation and the development of most of the ice-related landforms documented in Hellas. The relatively pristine form, lack of superposed craters, and strong association with the banded terrain, suggest an Amazonian (<3 Ga) age of formation for these landforms. Finally, relatively high surface pressures (above the triple point of water) expected in Hellas and summertime temperatures often exceeding the melting point of water ice suggest that the basin may have recorded relatively "temperate" climatic conditions compared to other places on Mars. Therefore, the potentially ice-rich banded terrain may have deformed with lower viscosity and stresses compared to other locations on Mars, which may account for its unique morphology.

  15. Visualizing shear bands in 3-D using axisymmetric sample: An experimental study

    Directory of Open Access Journals (Sweden)

    W. Khraisat

    2017-07-01

    Full Text Available In this study a qualitative description of the occurrence of shear bands produced by a sudden impact on an axisymmetric specimen made of medium carbon steel 0.45% C is given. A simple experiment was developed aimed at producing a pinch shear stress in the front side of the test sample in order to visualize shear bands in 3-D. Curve fitting using MATLAB was employed based on the points taken from the images of the front section of the test sample. The predictions of the curve fitting suggests a hyperbolic section leading to the conclusion that within the sample there is a double cone region of material where the shear band region is located on its outer surface. The formation of the shear band is explained by the fact that the interaction of the stress wave front with the free surface of the test sample produces reflection waves that attenuate the incoming stress wave inwards leading to a stress gradient in the plane of the front side of the specimen that causes shear localization. Also, the progressively increasing cross sectional area of the test sample causes the expansion of the wave front, which also results in a stress gradient in the normal direction of the front side of the specimen. So the formation of shear bands depends not only on the impact momentum and strain rates but also on the sample’s geometry.

  16. Galaxy Formation

    CERN Document Server

    Longair, Malcolm S

    2008-01-01

    This second edition of Galaxy Formation is an up-to-date text on astrophysical cosmology, expounding the structure of the classical cosmological models from a contemporary viewpoint. This forms the background to a detailed study of the origin of structure and galaxies in the Universe. The derivations of many of the most important results are derived by simple physical arguments which illuminate the results of more advanced treatments. A very wide range of observational data is brought to bear upon these problems, including the most recent results from WMAP, the Hubble Space Telescope, galaxy surveys like the Sloan Digital Sky Survey and the 2dF Galaxy Redshift Survey, studies of Type 1a supernovae, and many other observations.

  17. Automated coregistration of MTI spectral bands.

    Energy Technology Data Exchange (ETDEWEB)

    Theiler, J. P. (James P.); Galbraith, A. E. (Amy E.); Pope, P. A. (Paul A.); Ramsey, K. A. (Keri A.); Szymanski, J. J. (John J.)

    2002-01-01

    In the focal plane of a pushbroom imager, a linear array of pixels is scanned across the scene, building up the image one row at a time. For the Multispectral Thermal Imager (MTI), each of fifteen different spectral bands has its own linear array. These arrays are pushed across the scene together, but since each band's array is at a different position on the focal plane, a separate image is produced for each band. The standard MTI data products resample these separate images to a common grid and produce coregistered multispectral image cubes. The coregistration software employs a direct 'dead reckoning' approach. Every pixel in the calibrated image is mapped to an absolute position on the surface of the earth, and these are resampled to produce an undistorted coregistered image of the scene. To do this requires extensive information regarding the satellite position and pointing as a function of time, the precise configuration of the focal plane, and the distortion due to the optics. These must be combined with knowledge about the position and altitude of the target on the rotating ellipsoidal earth. We will discuss the direct approach to MTI coregistration, as well as more recent attempts to 'tweak' the precision of the band-to-band registration using correlations in the imagery itself.

  18. Excited negative parity bands in 160Yb

    Science.gov (United States)

    Saha, A.; Bhattacharjee, T.; Curien, D.; Dedes, I.; Mazurek, K.; Banerjee, S. R.; Rajbanshi, S.; Bisoi, A.; de Angelis, G.; Bhattacharya, Soumik; Bhattacharyya, S.; Biswas, S.; Chakraborty, A.; Das Gupta, S.; Dey, B.; Goswami, A.; Mondal, D.; Pandit, D.; Palit, R.; Roy, T.; Singh, R. P.; Saha Sarkar, M.; Saha, S.; Sethi, J.

    2018-03-01

    Negative parity rotational bands in {} 70160Yb{}90 nucleus have been studied. They were populated in the 148Sm(16O, 4n)160Yb reaction at 90 MeV. The gamma-coincidence data have been collected using Indian National Gamma Array composed of twenty Compton suppressed clover germanium (Ge) detectors. Double gating on triple gamma coincidence data were selectively used to develop the decay scheme for these negative parity bands by identifying and taking care of the multiplet transitions. The even- and odd-spin negative parity bands in 160Yb have been studied by comparing the reduced transition probability ratios with the similar bands in neighbouring even-even rare earth nuclei. It is concluded that the concerned odd-spin and even-spin bands are not signature partners and that their structures are compatible with those of the ‘pear-shape’ and ‘pyramid-shape’ oscillations, respectively, the octupole shapes superposed with the quadrupole shape of the ground-state.

  19. Mesoscopic colonization of a spectral band

    International Nuclear Information System (INIS)

    Bertola, M; Lee, S Y; Mo, M Y

    2009-01-01

    We consider the unitary matrix model in the limit where the size of the matrices becomes infinite and in the critical situation when a new spectral band is about to emerge. In previous works, the number of expected eigenvalues in the neighborhood of the band was fixed and finite, a situation that was termed 'birth of a cut' or 'first colonization'. We now consider the transitional regime where this microscopic population in the new band grows without bounds but at a slower rate than the size of the matrix. The local population in the new band organizes in a 'mesoscopic' regime, in between the macroscopic behavior of the full system and the previously studied microscopic one. The mesoscopic colony may form a finite number of new bands, with a maximum number dictated by the degree of criticality of the original potential. We describe the delicate scaling limit that realizes and controls the mesoscopic colony. The method we use is the steepest descent analysis of the Riemann-Hilbert problem that is satisfied by the associated orthogonal polynomials.

  20. Percutaneous tension band wiring for patellar fractures.

    Science.gov (United States)

    Rathi, Akhilesh; Swamy, M K S; Prasantha, I; Consul, Ashu; Bansal, Abhishek; Bahl, Vibhu

    2012-08-01

    To evaluate outcome of percutaneous tension band wiring for transverse fractures of the patella. 16 men and 7 women aged 27 to 65 (mean, 40) years underwent percutaneous tension band wiring for transverse fractures of the patella with a displacement of >3 mm. Pain, operating time, mobility, functional score, and complications were evaluated. 20 patients underwent successful percutaneous tension band wiring. The remaining 3 patients in whom closed reduction failed underwent open reduction and tension band wiring. The mean operating time was 46 (range, 28-62) minutes. The mean follow-up period was 20 (range, 15-30) months. At the latest follow-up, all patients had regained full extension. The objective score was excellent in 20 patients and good in 3, whereas the subjective score was excellent in 17, good in 5, and fair in one. All patients had radiological union at week 8. One patient had patellofemoral arthritis (secondary to a postoperative articular step). Two patients developed superficial infections, which resolved after antibiotic therapy. Mean thigh muscle wasting was 0.7 (range, 0.4-1) cm. Three patients encountered hardware problems (impingement/irritation of the skin over the knee) necessitating implant removal. Percutaneous tension band wiring is a viable option for transverse fractures of the patella.

  1. The dilemma of the wedding band.

    Science.gov (United States)

    Stein, Daniel T; Pankovich-Wargula, Alanna L

    2009-02-01

    The postoperative infection rate in procedures where no ring is worn, and those where a plain metal wedding band is worn under the glove was studied retrospectively. From January 1998 through June 2002, 2127 surgeries were performed by the lead author (D.T.S.), the first 2 years without a wedding band and the next 2 years with a simple platinum wedding band worn under the glove. Attention was paid to sliding the ring proximal and distal on the finger, ensuring scrub solution was under the ring and that the area of skin below the ring was cleansed. Twenty-two postoperative infections were recorded in 2127 surgeries. This is a postoperative infection rate of 1.0%, and wedding ring worn, nor do they demonstrate an increased infection rate with wearing jewelry. This study suggests that there is no correlation between wearing a plain wedding band under the surgical glove and an increase in postoperative infections. The crevices and cuticle of the fingers and nails may provide more significant infection risk than a plain metal wedding band. This is a level III retrospective cohort study.

  2. Band warping, band non-parabolicity, and Dirac points in electronic and lattice structures

    Science.gov (United States)

    Resca, Lorenzo; Mecholsky, Nicholas A.; Pegg, Ian L.

    2017-10-01

    We illustrate at a fundamental level the physical and mathematical origins of band warping and band non-parabolicity in electronic and vibrational structures. We point out a robust presence of pairs of topologically induced Dirac points in a primitive-rectangular lattice using a p-type tight-binding approximation. We analyze two-dimensional primitive-rectangular and square Bravais lattices with implications that are expected to generalize to more complex structures. Band warping is shown to arise at the onset of a singular transition to a crystal lattice with a larger symmetry group, which allows the possibility of irreducible representations of higher dimensions, hence band degeneracy, at special symmetry points in reciprocal space. Band warping is incompatible with a multi-dimensional Taylor series expansion, whereas band non-parabolicities are associated with multi-dimensional Taylor series expansions to all orders. Still band non-parabolicities may merge into band warping at the onset of a larger symmetry group. Remarkably, while still maintaining a clear connection with that merging, band non-parabolicities may produce pairs of conical intersections at relatively low-symmetry points. Apparently, such conical intersections are robustly maintained by global topology requirements, rather than any local symmetry protection. For two p-type tight-binding bands, we find such pairs of conical intersections drifting along the edges of restricted Brillouin zones of primitive-rectangular Bravais lattices as lattice constants vary relatively to each other, until these conical intersections merge into degenerate warped bands at high-symmetry points at the onset of a square lattice. The conical intersections that we found appear to have similar topological characteristics as Dirac points extensively studied in graphene and other topological insulators, even though our conical intersections have none of the symmetry complexity and protection afforded by the latter more

  3. The study of adiabatic shear band instability in a pearlitic 4340 steel using a dynamic punch test

    Science.gov (United States)

    Zurek, Anna K.

    1994-11-01

    The formation of adiabatic shear band instabilities in a pearlitic 4340 steel using a dynamic punch test has been studied. The dynamic punch-impact test produced white-etching adiabatic shear bands. The average strain of 0.5 was sufficient to produce adiabatic shear bands in this steel at an average strain rate of 18,000 s-1. Nanohardness variations found across the adiabatic shear band are thought to be caused by the fragmentation and spheroidization of the Fe3C and the overall deformation and work hardening of the pearlitic microstructure. The cracks formed at the termination of the adiabatic shear band caused the sample to fracture in a ductile mode.

  4. Prediction of Accumulation of Technological Stresses in a Pipeline Upon its Repair by a Composite Band

    Science.gov (United States)

    Altenbach, H.; Naumenko, K.; L'vov, G.; Sukiasov, V.; Podgorny, A.

    2015-05-01

    The problem on the formation of stress fields in a pipeline with a repair composite band during the solidification of the polymer resin is considered. Heating of the composite material due to the heat release during the polymerization reaction is modeled. Two-dimensional pictures of location of the glass transition front during cooling are obtained. A numerical analysis of the stress state of a fragment of the pipeline and the composite band during the cooling process is performed. The effect of matrix shrinkage during its glass transition on the level of the technological stresses is analyzed.

  5. Defect-band mediated ferromagnetism in Gd-doped ZnO thin films

    KAUST Repository

    Venkatesh, S.

    2015-01-07

    Gd-doped ZnO thin films prepared by pulsed laser deposition with Gd concentrations varying from 0.02–0.45 atomic percent (at. %) showed deposition oxygen pressure controlled ferromagnetism. Thin films prepared with Gd dopant levels (band formed due to oxygen deficiency related defect complexes. Mott\\'s theory of variable range of hopping conduction confirms the formation of the impurity/defect band near the Fermi level.

  6. Obituary: David L. Band (1957-2009)

    Science.gov (United States)

    Cominsky, Lynn

    2011-12-01

    David L. Band, of Potomac Maryland, died on March 16, 2009 succumbing to a long battle with spinal cord cancer. His death at the age of 52 came as a shock to his many friends and colleagues in the physics and astronomy community. Band showed an early interest and exceptional aptitude for physics, leading to his acceptance at the Massachusetts Institute of Technology as an undergraduate student in 1975. After graduating from MIT with an undergraduate degree in Physics, Band continued as a graduate student in Physics at Harvard University. His emerging interest in Astrophysics led him to the Astronomy Department at the Harvard Smithsonian Center for Astrophysics (CfA), where he did his dissertation work with Jonathan Grindlay. His dissertation (1985) entitled "Non-thermal Radiation Mechanisms and Processes in SS433 and Active Galactic Nuclei" was "pioneering work on the physics of jets arising from black holes and models for their emission, including self-absorption, which previewed much to come, and even David's own later work on Gamma-ray Bursts," according to Grindlay who remained a personal friend and colleague of Band's. Following graduate school, Band held postdoctoral positions at the Lawrence Livermore Laboratory, the University of California at Berkeley and the Center for Astronomy and Space Sciences at the University of California San Diego where he worked on the BATSE experiment that was part of the Compton Gamma Ray Observatory (CGRO), launched in 1991. BATSE had as its main objective the study of cosmic gamma-ray bursts (GRBs) and made significant advances in this area of research. Band became a world-renowned figure in the emerging field of GRB studies. He is best known for his widely-used analytic form of gamma-ray burst spectra known as the "Band Function." After the CGRO mission ended, Band moved to the Los Alamos National Laboratory where he worked mainly on classified research but continued to work on GRB energetics and spectra. When NASA planned

  7. Simplicial band depth for multivariate functional data

    KAUST Repository

    López-Pintado, Sara

    2014-03-05

    We propose notions of simplicial band depth for multivariate functional data that extend the univariate functional band depth. The proposed simplicial band depths provide simple and natural criteria to measure the centrality of a trajectory within a sample of curves. Based on these depths, a sample of multivariate curves can be ordered from the center outward and order statistics can be defined. Properties of the proposed depths, such as invariance and consistency, can be established. A simulation study shows the robustness of this new definition of depth and the advantages of using a multivariate depth versus the marginal depths for detecting outliers. Real data examples from growth curves and signature data are used to illustrate the performance and usefulness of the proposed depths. © 2014 Springer-Verlag Berlin Heidelberg.

  8. Propionaldehyde infrared cross-sections and band strengths

    International Nuclear Information System (INIS)

    Köroğlu, Batikan; Loparo, Zachary; Nath, Janardan; Peale, Robert E.; Vasu, Subith S.

    2015-01-01

    The use of oxygenated biofuels reduces the greenhouse gas emissions; however, they also result in increased toxic aldehyde by-products, mainly formaldehyde, acetaldehyde, acrolein, and propionaldehyde. These aldehydes are carcinogenic and/or toxic and therefore it is important to understand their formation and destruction pathways in combustion and atmospheric systems. Accurate information about their infrared cross-sections and integrated strengths are crucially needed for development of quantitative detection schemes and modeling tools. Critical to the development of such diagnostics are accurate characterization of the absorption features of these species. In this study, the gas phase infrared spectra of propionaldehyde (also called propanal, CH 3 –CH 2 –CHO), a saturated three carbon aldehyde found in the exhaust emissions of biodiesel or diesel fuels, was studied using high resolution Fourier Transform Infrared (FTIR) spectroscopy over the wavenumber range of 750−3300 cm −1 and at room temperature 295 K. The absorption cross sections of propionaldehyde were recorded at resolutions of 0.08 and 0.096 cm −1 and at seven different pressures (4−33 Torr). The calculated band-strengths were reported and the integrated band intensity results were compared with values taken from the Pacific Northwest National Laboratory (PNNL) database (showing less than 2% discrepancy). The peak positions of the 19 different vibrational bands of propionaldehyde were also compared with previous studies taken at a lower resolution of 1 cm −1 . To the best of our knowledge, the current FTIR measurements provide the first highest resolution infrared cross section data for propionaldehyde. - Highlights: • High resolution IR spectra of propionaldehyde were measured by FTIR spectrometer. • The discrepancy between the present study and PNNL database was less than 2%. • The fundamental vibrational frequencies were reported at high resolution. • The rovibrational Q

  9. Propionaldehyde infrared cross-sections and band strengths

    Science.gov (United States)

    Köroğlu, Batikan; Loparo, Zachary; Nath, Janardan; Peale, Robert E.; Vasu, Subith S.

    2015-02-01

    The use of oxygenated biofuels reduces the greenhouse gas emissions; however, they also result in increased toxic aldehyde by-products, mainly formaldehyde, acetaldehyde, acrolein, and propionaldehyde. These aldehydes are carcinogenic and/or toxic and therefore it is important to understand their formation and destruction pathways in combustion and atmospheric systems. Accurate information about their infrared cross-sections and integrated strengths are crucially needed for development of quantitative detection schemes and modeling tools. Critical to the development of such diagnostics are accurate characterization of the absorption features of these species. In this study, the gas phase infrared spectra of propionaldehyde (also called propanal, CH3-CH2-CHO), a saturated three carbon aldehyde found in the exhaust emissions of biodiesel or diesel fuels, was studied using high resolution Fourier Transform Infrared (FTIR) spectroscopy over the wavenumber range of 750-3300 cm-1 and at room temperature 295 K. The absorption cross sections of propionaldehyde were recorded at resolutions of 0.08 and 0.096 cm-1 and at seven different pressures (4-33 Torr). The calculated band-strengths were reported and the integrated band intensity results were compared with values taken from the Pacific Northwest National Laboratory (PNNL) database (showing less than 2% discrepancy). The peak positions of the 19 different vibrational bands of propionaldehyde were also compared with previous studies taken at a lower resolution of 1 cm-1. To the best of our knowledge, the current FTIR measurements provide the first highest resolution infrared cross section data for propionaldehyde.

  10. Band Edge Dynamics and Multiexciton Generation in Narrow Band Gap HgTe Nanocrystals.

    Science.gov (United States)

    Livache, Clément; Goubet, Nicolas; Martinez, Bertille; Jagtap, Amardeep; Qu, Junling; Ithurria, Sandrine; Silly, Mathieu G; Dubertret, Benoit; Lhuillier, Emmanuel

    2018-04-02

    Mercury chalcogenide nanocrystals and especially HgTe appear as an interesting platform for the design of low cost mid-infrared (mid-IR) detectors. Nevertheless, their electronic structure and transport properties remain poorly understood, and some critical aspects such as the carrier relaxation dynamics at the band edge have been pushed under the rug. Some of the previous reports on dynamics are setup-limited, and all of them have been obtained using photon energy far above the band edge. These observations raise two main questions: (i) what are the carrier dynamics at the band edge and (ii) should we expect some additional effect (multiexciton generation (MEG)) as such narrow band gap materials are excited far above the band edge? To answer these questions, we developed a high-bandwidth setup that allows us to understand and compare the carrier dynamics resonantly pumped at the band edge in the mid-IR and far above the band edge. We demonstrate that fast (>50 MHz) photoresponse can be obtained even in the mid-IR and that MEG is occurring in HgTe nanocrystal arrays with a threshold around 3 times the band edge energy. Furthermore, the photoresponse can be effectively tuned in magnitude and sign using a phototransistor configuration.

  11. S-band active array filtenna with enhanced X-band spurious interference suppression

    NARCIS (Netherlands)

    Cifola, L.; Gerini, G.; Berg, S. van den; Water, F. van de

    2014-01-01

    In the present work, the design of an S-band active array antenna with inherent frequency selectivity properties is described. The radiating element, based on a stacked-patch configuration, is characterized by an operational bandwidth of [2.8-3.4] GHz. In-band frequency selectivity is performed by a

  12. Fuzzy Riesz subspaces, fuzzy ideals, fuzzy bands and fuzzy band projections

    OpenAIRE

    Hong, Liang

    2015-01-01

    Fuzzy ordered linear spaces, Riesz spaces, fuzzy Archimedean spaces and $\\sigma$-complete fuzzy Riesz spaces were defined and studied in several works. Following the efforts along this line, we define fuzzy Riesz subspaces, fuzzy ideals, fuzzy bands and fuzzy band projections and establish their fundamental properties.

  13. Band-gap and band-edge engineering of multicomponent garnet scintillators from first principles

    Czech Academy of Sciences Publication Activity Database

    Yadav, S.K.; Uberuaga, B.P.; Nikl, Martin; Jiang, C.; Stanek, C.R.

    2015-01-01

    Roč. 4, č. 5 (2015), "054012-1"-"054012-9" ISSN 2331-7019 R&D Projects: GA ČR GAP204/12/0805 Institutional support: RVO:68378271 Keywords : scintillator * electronic band gap structure * garnets * band gap engineering Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 4.061, year: 2015

  14. Utilization of surface Plasmon resonance band of silver nanoparticles for determination of critical micelle concentration of cationic surfactants

    Science.gov (United States)

    Salem, Jamil K.; El-Nahhal, Issa M.; Najri, Bassam A.; Hammad, Talaat M.

    2016-11-01

    We have utilized surface Plasmon resonance (SPR) band sensitivity to surfactant concentration to investigate the critical micelle concentration (cmc) of CTAB, HY and CPB. The process is based upon an in situ formation of silver nanoparticles (AgNPs) through the reduction of silver ions (Ag+) by diethylene triamine (DETA) at 25 °C. In the presence of cationic surfactants, Ag+ ions can be reduced to AgNPs in a few minutes, accompanied by changes in intensity and wavelength of the SPR band. The spectral shifts of SPR band and the change of color have been used to determine CMC values of cationic surfactants.

  15. Development of cataclastic foliation in deformation bands in feldspar-rich conglomerates of the Rio do Peixe Basin, NE Brazil

    Science.gov (United States)

    Nicchio, Matheus A.; Nogueira, Francisco C. C.; Balsamo, Fabrizio; Souza, Jorge A. B.; Carvalho, Bruno R. B. M.; Bezerra, Francisco H. R.

    2018-02-01

    In this work we describe the deformation mechanisms and processes that occurred during the evolution of cataclastic deformation bands developed in the feldspar-rich conglomerates of the Rio do Peixe Basin, NE Brazil. We studied bands with different deformation intensities, ranging from single cm-thick tabular bands to more evolved clustering zones. The chemical identification of cataclastic material within deformation bands was performed using compositional mapping in SEM images, EDX and XRD analyses. Deformation processes were identified by microstructural analysis and by the quantification of comminution intensity, performed using digital image processing. The deformation bands are internally non homogeneous and developed during five evolutionary stages: (1) moderate grain size reduction, grain rotation and grain border comminution; (2) intense grain size reduction with preferential feldspar fragmentation; (3) formation of subparallel C-type slip zones; (4) formation of S-type structures, generating S-C-like fabric; and (5) formation of C‧-type slip zones, generating well-developed foliation that resembles S-C-C‧-type structures in a ductile environment. Such deformation fabric is mostly imparted by the preferential alignment of intensely comminuted feldspar fragments along thin slip zones developed within deformation bands. These processes were purely mechanical (i.e., grain crushing and reorientation). No clays or fluids were involved in such processes.

  16. Electron currents associated with an auroral band

    Science.gov (United States)

    Spiger, R. J.; Anderson, H. R.

    1975-01-01

    Measurements of electron pitch angle distributions and energy spectra over a broad auroral band were used to calculate net electric current carried by auroral electrons in the vicinity of the band. The particle energy spectrometers were carried by a Nike-Tomahawk rocket launched from Poker Flat, Alaska, at 0722 UT on February 25, 1972. Data are presented which indicate the existence of upward field-aligned currents of electrons in the energy range 0.5-20 keV. The spatial relationship of these currents to visual structure of the auroral arc and the characteristics of the electrons carrying the currents are discussed.

  17. Itinerant ferromagnetism in the narrow band limit

    CERN Document Server

    Liu, S H

    2000-01-01

    It is shown that in the narrow band, strong interaction limit the paramagnetic state of an itinerant ferromagnet is described by the disordered local moment state. As a result, the Curie temperature is orders of magnitude lower than what is expected from the large exchange splitting of the spin bands. An approximate analysis has also been carried out for the partially ordered state, and the result explains the temperature evolvement of the magnetic contributions to the resistivity and low-energy optical conductivity of CrO sub 2.

  18. Banding of connection standards for distributed generation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-05-04

    This report presents the views of distributed network operators (DNOs), developers, equipment manufacturers and consultants on the current banding of distributed generation in terms of connection standards and recommendations. The Documents ER G59/1, ER G75/1, ER G83/1 and ETR 113/1 covering recommendations for the connection of embedded generating plant to distribution systems and guidance notes for the protection of embedded generating plant are examined. The way in which the recommendations are applied in practice is investigated. Multiple distribution generator installations, fault ride through, and banding are considered as well as both protection required and maximum generator sizes at respective voltage levels.

  19. Band theory of metals the elements

    CERN Document Server

    Altmann, Simon L

    1970-01-01

    Band Theory of Metals: The Elements focuses on the band theory of solids. The book first discusses revision of quantum mechanics. Topics include Heisenberg's uncertainty principle, normalization, stationary states, wave and group velocities, mean values, and variational method. The text takes a look at the free-electron theory of metals, including heat capacities, density of states, Fermi energy, core and metal electrons, and eigenfunctions in three dimensions. The book also reviews the effects of crystal fields in one dimension. The eigenfunctions of the translations; symmetry operations of t

  20. Proximal iliotibial band syndrome: case report

    Directory of Open Access Journals (Sweden)

    Guilherme Guadagnini Falotico

    2013-08-01

    Full Text Available OBJECTIVE: The overuse injuries in the hip joint occur commonly in sports practitioners and currently due to technical advances in diagnostic imaging, especially magnetic resonance imaging (MRI, are often misdiagnosed. Recently, a group of people were reported, all female, with pain and swelling in the pelvic region.T2-weighted MRI showed increased signal in the enthesis of the iliotibial band (ITB along the lower border of the iliac tubercle. We report a case of a 34 year old woman, non-professional runner, with pain at the iliac crest with no history of trauma and whose MRI was compatible with the proximal iliotibial band syndrome.

  1. Ka-band waveguide rotary joint

    KAUST Repository

    Yevdokymov, Anatoliy

    2013-04-11

    The authors present a design of a waveguide rotary joint operating in Ka-band with central frequency of 33 GHz, which also acts as an antenna mount. The main unit consists of two flanges with a clearance between them; one of the flanges has three circular choke grooves. Utilisation of three choke grooves allows larger operating clearance. Two prototypes of the rotary joint have been manufactured and experimentally studied. The observed loss is from 0.4 to 0.8 dB in 1.5 GHz band.

  2. Radiology of vertical-banded gastroplasty

    International Nuclear Information System (INIS)

    Leekam, R.N.; Deitel, M.; Shankar, L.; Salsberg, B.B.

    1987-01-01

    Vertical banded gastroplasty is the most frequently performed operation for the treatment of morbid obesity. More than 550 such procedures have been done at our hospital over the past 4 years. This presentation describes the postoperative radiographic findings in many of these patients. Normal and abnormal appearances on plain films and on contrast agent-enhanced examinations are discussed. The authors found it useful to divide abnormal findings into three groups: abnormalities of the partition, abnormalities of the banded channel, and ulcers and extragastric leaks

  3. ANALISIS TIPOGRAFI PADA LOGOTYPE BAND FORGOTTEN

    Directory of Open Access Journals (Sweden)

    Atang Riyan Isnandar

    2016-12-01

    Full Text Available Abstrak Forgotten merupakan band asal kota Bandung yang beraliran death metal. Band ini telah memiliki beberapa album yang cukup sukses. Salah satu faktor yang turut berperan penting dalam album-album Forgotten adalah desain sampul album. Sampul album merupakan identitas dan pesan dari musik yang dibawakan oleh Forgotten. Dalam sampul album, terdapat salah satu elemen visual yaitu Tipografi. Salah satu peran tipografi dalam sampul album Forgotten adalah sebagai logotype dari band. Yang menarik, dari lima album yang telah dirilis Forgotten yaitu “Future Syndrome” (1997, “Obsesi Mati” (2000, “Tuhan Telah Mati” (2001, “Tiga Angka Enam” (2003 dan “Laras Perlaya” (2011 adalah tampilan logotype band yang selalu berbeda. Perubahan logotype Forgotten disebabkan oleh beberapa faktor seperti adanya perubahan selera, transformasi musik dan pergantian personil yang dialami oleh band Forgotten. Perubahan ini berakibat pada munculnya kesan visual yang berbeda-beda dari masing-masing logotype di setiap sampul albumnya. Apalagi logotype band dengan genre death metal memiliki kecendrungan yang unik, dekoratif, bahkan sulit untuk dibaca. Oleh karena itu untuk mengetahui kesan visual yang dimunculkan oleh setiap logotype akan dilakukan penelitian dengan pendekatan tipografi. Tujuan dari penelitian ini adalah selain untuk mengetahui perubahan logotype dari kelima sampul album yang telah dirilis oleh Forgotten juga ingin mengetahui kesan visual terhadap tipografi terkait dengan prinsip kejelasan (legibility, keterbacaan (readability dan kemampuannya untuk dilihat pada jarak tertentu (visibility. Kata Kunci: Sampul Album, Tipografi, Logotype, Forgotten Abstract Forgotten is a band from Bandung, the death metal genre. The band has had some fairly successful album. One of important factor in albums Forgotten is the album cover design. The album cover are the identity and the message of the music performed by the Forgotten. In the cover of the album

  4. 47 CFR 15.714 - TV bands database administration fees.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false TV bands database administration fees. 15.714 Section 15.714 Telecommunication FEDERAL COMMUNICATIONS COMMISSION GENERAL RADIO FREQUENCY DEVICES Television Band Devices § 15.714 TV bands database administration fees. (a) A TV bands database administrator...

  5. 47 CFR 15.715 - TV bands database administrator.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false TV bands database administrator. 15.715 Section... Band Devices § 15.715 TV bands database administrator. The Commission will designate one or more entities to administer a TV bands database. Each database administrator shall: (a) Maintain a database that...

  6. Predicting superdeformed rotational band-head spin in A∼ 190 ...

    Indian Academy of Sciences (India)

    The band-head spin (0) of superdeformed (SD) rotational bands in ∼ 190 mass region is predicted using the variable moment of inertia (VMI) model for 66 SD rotational bands. The superdeformed rotational bands exhibited considerably good rotational property and rigid behaviour. The transition energies were ...

  7. Effect of mixing Ce{sup 3+} and Nd{sup 3+} ions in equimolar ratio on structural, optical and dielectric properties on pure cerium orthovanadate and neodymium orthovanadate

    Energy Technology Data Exchange (ETDEWEB)

    Verma, Seema; Gupta, Rashmi; Bamzai, K.K., E-mail: kkbamz@yahoo.com

    2016-09-15

    Highlights: • CeV, NdV and mixed CeNdV nanoparticle prepared by chemical co precipitation method. • With mixing of Ce{sup 3+} and Nd{sup 3+} morphology is totally changed in mixed CeNdV. • Optical band energy of CeV, NdV and CeNdV shows good photocatalyst under UV light. • Conduction mechanism in CeV due to large polaron and small polaron in CeNdV. - Abstract: Cerium orthovanadate, neodymium orthovanadate and mixed cerium neodymium orthovanadate nanoparticles was prepared by co-precipitation method. Powder X-ray diffraction reveals tetragonal zircon structure. Slight increase in lattice parameter, volume and decrease in X-ray density inferred that Ce{sup 3+} and Nd{sup 3+} ion replaces each other. Transmission electron microscopy suggests change in morphology with the effect of mixing and validates formation of nanocrystalline material. The infrared transmittance spectrum confirmed the presence of various functional groups. Dielectric properties as function of frequency show dielectric constant and loss tangent decreases with increase in frequency which is due to Maxwell–Wagner type interfacial polarization. The variation of AC conductivity measurement with frequency suggests conduction mechanism due to large polaron hopping in CeV whereas small polaron in mixed CeNdV. The activation energy decreases with rising frequency indicates the conduction mechanism is based on polaron hopping between localized states in disordered manner.

  8. Conduction mechanism in Polyaniline-flyash composite material for shielding against electromagnetic radiation in X-band & Ku band

    Directory of Open Access Journals (Sweden)

    Avanish Pratap Singh

    2011-06-01

    Full Text Available β–Naphthalene sulphonic acid (β–NSA doped polyaniline (PANI–flyash (FA composites have been prepared by chemical oxidative polymerization route whose conductivity lies in the range 2.37–21.49 S/cm. The temperature dependence of electrical conductivity has also been recorded which shows that composites follow Mott's 3D–VRH model. SEM images demonstrate that β–NSA leads to the formation of the tubular structure with incorporated flyash phase. TGA studies show the improvement in thermal stability of composites with increase in loading level of flyash. Complex parameters i.e. permittivity (ɛ* = ɛ′- iɛ″ and permeability (μ*=μ′- iμ″ of PANI-FA composites have been calculated from experimental scattering parameters (S11 & S21 using theoretical calculations given in Nicholson–Ross and Weir algorithms. The microwave absorption properties of the composites have been studied in X-band (8.2 – 12.4 GHz & Ku–Band (12.4 – 18 GHz frequency range. The maximum shielding effectiveness observed was 32dB, which strongly depends on dielectric loss and volume fraction of flyash in PANI matrix.

  9. Statistical study of auroral omega bands

    Directory of Open Access Journals (Sweden)

    N. Partamies

    2017-09-01

    Full Text Available The presence of very few statistical studies on auroral omega bands motivated us to test-use a semi-automatic method for identifying large-scale undulations of the diffuse aurora boundary and to investigate their occurrence. Five identical all-sky cameras with overlapping fields of view provided data for 438 auroral omega-like structures over Fennoscandian Lapland from 1996 to 2007. The results from this set of omega band events agree remarkably well with previous observations of omega band occurrence in magnetic local time (MLT, lifetime, location between the region 1 and 2 field-aligned currents, as well as current density estimates. The average peak emission height of omega forms corresponds to the estimated precipitation energies of a few keV, which experienced no significant change during the events. Analysis of both local and global magnetic indices demonstrates that omega bands are observed during substorm expansion and recovery phases that are more intense than average substorm expansion and recovery phases in the same region. The omega occurrence with respect to the substorm expansion and recovery phases is in a very good agreement with an earlier observed distribution of fast earthward flows in the plasma sheet during expansion and recovery phases. These findings support the theory that omegas are produced by fast earthward flows and auroral streamers, despite the rarity of good conjugate observations.

  10. S-Band Doppler Wave Radar System

    Directory of Open Access Journals (Sweden)

    Zezong Chen

    2017-12-01

    Full Text Available In this paper, a novel shore-based S-band microwave Doppler coherent wave radar (Microwave Ocean Remote SEnsor (MORSE is designed to improve wave measurements. Marine radars, which operate in the X band, have been widely used for ocean monitoring because of their low cost, small size and flexibility. However, because of the non-coherent measurements and strong absorption of X-band radio waves by rain, these radar systems suffer considerable performance loss in moist weather. Furthermore, frequent calibrations to modify the modulation transfer function are required. To overcome these shortcomings, MORSE, which operates in the S band, was developed by Wuhan University. Because of the coherent measurements of this sensor, it is able to measure the radial velocity of water particles via the Doppler effect. Then the relation between the velocity spectrum and wave height spectrum can be used to obtain the wave height spectra. Finally, wave parameters are estimated from the wave height spectra by the spectrum moment method. Comparisons between MORSE and Waverider MKIII are conducted in this study, and the results, including the non-directional wave height spectra, significant wave height and average wave period, are calculated and displayed. The correlation coefficient of the significant wave height is larger than 0.9, whereas that of the average wave period is approximately 0.4, demonstrating the effectiveness of MORSE for the continuous monitoring of ocean areas with high accuracy.

  11. Deformed configurations, band structures and spectroscopic ...

    Indian Academy of Sciences (India)

    2014-03-20

    Mar 20, 2014 ... The deformed configurations and rotational band structures in =50 Ge and Se nuclei are studied by deformed Hartree–Fock with quadrupole constraint and angular momentum projection. Apart from the `almost' spherical HF solution, a well-deformed configuration occurs at low excitation. A deformed ...

  12. Deformed configurations, band structures and spectroscopic ...

    Indian Academy of Sciences (India)

    2014-03-20

    Mar 20, 2014 ... Here, we study theoretically the low-lying as well as the excited deformed bands and their electromagnetic properties to search for various structures, spherical and deformed, of the exotic nuclei 82Ge and 84Se by employing the deformed Hartree–Fock (HF) and angular momentum (J) projection method ...

  13. Energy bands and gaps near an impurity

    Czech Academy of Sciences Publication Activity Database

    Mihóková, Eva; Schulman, L. S.

    2016-01-01

    Roč. 380, č. 41 (2016), s. 3430-3433 ISSN 0375-9601 R&D Projects: GA ČR GA13-09876S Institutional support: RVO:68378271 Keywords : crystal structure * impurity * modeling * energy bands Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.772, year: 2016

  14. Teaching Strategies for High School Band.

    Science.gov (United States)

    Teaching Music, 1999

    1999-01-01

    Provides a strategy, from the book entitled "Strategies for Teaching High School Band," that addresses Standard 8B of the National Standards for Music Education. Explains that students will discover relationships among music, visual art, and architecture of the Classical period. (CMK)

  15. Radio Band Observations of Blazar Variability

    Indian Academy of Sciences (India)

    2016-01-27

    Jan 27, 2016 ... The properties of blazar variability in the radio band are studied using the unique combination of temporal resolution from single dish monitoring and spatial resolution from VLBA imaging. Such measurements now available in all four Stokes parameters, together with theoretical simulations, identify the ...

  16. Electron band theory 1952-1962

    International Nuclear Information System (INIS)

    Lomer, W.M.

    1980-01-01

    Work undertaken by the Theoretical Physics Division between 1952 and 1965 to obtain an understanding of electrons in metals, with uranium and the actinides and the structurally-important transition metals as the main targets is examined. A main result of that period was a conviction that the majority of the physical properties of all metals, except the 4f rare-earth series and the actinides beyond uranium, were dominated by band effects which could be described well enough for most purposes by simple one-electron calculations with simple self-consistent fields. The period from 1960 on showed increasingly clearly the necessity of incorporating relativistic spin-orbit coupling terms in the heavy metals, and some 'local exchange field' correction to the fields close to nuclei. The problems of the non-local interaction of spins - highly important for alloy theory and for antiferromagnetic instability -required the evolution of computers large enough to produce wave-functions at all wave-vectors for all bands so that the susceptibility at arbitrary wave-vector could be computed. This work has not proved to be very illuminating so far, and much interest again focusses today on heuristic arguments that give qualitative descriptions of band structures, such as canonical d-bands to account for crystal structure. (UK)

  17. The end of the unique myocardial band

    DEFF Research Database (Denmark)

    MacIver, David H; Partridge, John B; Agger, Peter

    2018-01-01

    Two of the leading concepts of mural ventricular architecture are the unique myocardial band and the myocardial mesh model. We have described, in an accompanying article published in this journal, how the anatomical, histological and high-resolution computed tomographic studies strongly favour...

  18. Faraday Rotation and L Band Oceanographic Measurements

    DEFF Research Database (Denmark)

    Skou, Niels

    2003-01-01

    Spaceborne radiometric measurements of the L band brightness temperature over the oceans make it possible to estimate sea surface salinity. However, Faraday rotation in the ionosphere disturbs the signals and must be corrected. Two different ways of assessing the disturbance directly from...

  19. Fluorescence bands and chlorophyll a forms

    NARCIS (Netherlands)

    Goedheer, J.C.

    1964-01-01

    Fluorescence spectra were determined at temperatures between 20° and −196° for a number of photosynthetic organisms. Below −90° the single fluorescence maximum around 685 mμ was replaced by a system of three bands, at 686, 696 and 717–720 mμ in algal cells. Cooling usually resulted in a decrease of

  20. Phononic band gap structures as optimal designs

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Sigmund, Ole

    2003-01-01

    In this paper we use topology optimization to design phononic band gap structures. We consider 2D structures subjected to periodic loading and obtain the distribution of two materials with high contrast in material properties that gives the minimal vibrational response of the structure. Both in...

  1. Conduction bands in classical periodic potentials

    Indian Academy of Sciences (India)

    The particle may hop from classically allowed site to nearest-neighbour classically allowed site in the potential, behaving as if it were a quantum particle in an energy gap and undergoing repeated tunnelling processes or; the particle may behave as a quantum particle in a conduction band and drift at a constant average ...

  2. PHARUS: A C-band Airborne SAR

    NARCIS (Netherlands)

    Hoogeboom, P.; Koomen, P.J.; Pouwels, H.; Snoeij, P.

    1990-01-01

    In The Netherlands a plan to design aircraft and build a polarimetric C-band SAR system of a novel design, called PHARUS (PHased Array Universal SAR) is carried out by three institutes. These institutes are the Physics and Electronics Laboratory TNO in The Hague (prime contractor and project

  3. Superdeformed rotational bands in Pu-240

    NARCIS (Netherlands)

    Hunyadi, M; Gassmann, D; Krasznahorkay, A; Habs, D; Csatlos, M; Eisermann, Y; Faestermann, T; Graw, G; Gulyas, J; Hertenberger, R; Maier, HJ; Mate, Z; Metz, A; Thirolf, P; Chromik, M; van der Werf, SY

    The intermediate structure of the fission resonances has been observed in Pu-240. A resonance structure found around the excitation energy of 4.5 MeV was interpreted as a group of K-pi = 0(+) superdeformed rotational bands. The moments of inertia and level density distributions were also deduced for

  4. Band-Structure of Thallium by the LMTO Method

    DEFF Research Database (Denmark)

    Holtham, P. M.; Jan, J. P.; Skriver, Hans Lomholt

    1977-01-01

    The relativistic band structure of thallium has been calculated using the linear muffin-tin orbital (LMTO) method. The positions and extents of the bands were found to follow the Wigner-Seitz rule approximately, and the origin of the dispersion of the bands was established from the canonical s...... and p bands for the HCP structure. Energy bands have been evaluated both with and without spin-orbit coupling which is particularly large in thallium. Energy bands close to the Fermi level were found to be mainly 6p like in character. The 6s states lay below the 6p bands and were separated from them...

  5. Effect of Radiographic Contrast Media on the Spectrin/Band3-Network of the Membrane Skeleton of Erythrocytes

    Science.gov (United States)

    Franke, Ralf-Peter; Scharnweber, Tim; Fuhrmann, Rosemarie; Wenzel, Folker; Krüger, Anne; Mrowietz, Christof; Jung, Friedrich

    2014-01-01

    The membrane of red blood cells consists of a phospholipid bilayer with embedded membrane proteins and is associated on the cytoplasmatic side with a network of proteins, the membrane skeleton. Band3 has an important role as centre of the functional complexes e.g. gas exchange complex and as element of attachment for the membrane skeleton maintaining membrane stability and flexibility. Up to now it is unclear if band3 is involved in the morphology change of red blood cells after contact with radiographic contrast media. The study revealed for the first time that Iopromide induced markedly more severe alterations of the membrane skeleton compared to Iodixanol whose effects were similar to erythrocytes suspended in autologous plasma. A remarkable clustering of band3 was found associated with an accumulation of band3 in spicules and also a sequestration of band3 to the extracellular space. This was evidently accompanied by a gross reduction of functional band3 complexes combined with a dissociation of spectrin from band3 leading to a loss of homogeneity of the spectrin network. It could be demonstrated for the first time that RCM not only induced echinocyte formation but also exocytosis of particles at least coated with band3. PMID:24586837

  6. Effect of radiographic contrast media on the spectrin/band3-network of the membrane skeleton of erythrocytes.

    Directory of Open Access Journals (Sweden)

    Ralf-Peter Franke

    Full Text Available The membrane of red blood cells consists of a phospholipid bilayer with embedded membrane proteins and is associated on the cytoplasmatic side with a network of proteins, the membrane skeleton. Band3 has an important role as centre of the functional complexes e.g. gas exchange complex and as element of attachment for the membrane skeleton maintaining membrane stability and flexibility. Up to now it is unclear if band3 is involved in the morphology change of red blood cells after contact with radiographic contrast media. The study revealed for the first time that Iopromide induced markedly more severe alterations of the membrane skeleton compared to Iodixanol whose effects were similar to erythrocytes suspended in autologous plasma. A remarkable clustering of band3 was found associated with an accumulation of band3 in spicules and also a sequestration of band3 to the extracellular space. This was evidently accompanied by a gross reduction of functional band3 complexes combined with a dissociation of spectrin from band3 leading to a loss of homogeneity of the spectrin network. It could be demonstrated for the first time that RCM not only induced echinocyte formation but also exocytosis of particles at least coated with band3.

  7. Adiabatic shear bands as predictors of strain rate in high speed machining of ramax-2

    International Nuclear Information System (INIS)

    Zeb, M.A.; Irfan, M.A.; Velduis, A.C.

    2008-01-01

    Shear band formation was studied in the chips obtained by turning of stainless steel- Ramax-2 (AISI 420F). The machining was performed on a CNC lathe using a PVD (Physical Vapor Deposition) cutting tool insert. The cutting speeds ranged from 50 m/ min to 250 m/min. Dry cutting conditions were employed. At cutting speeds higher than 30 m/mill, the chip did not remain intact with the workpiece using quick stop device. It was difficult to get the chip root SEM (Scanning Electron Microscope) micrographs at further higher speeds. Therefore, the width of the shear bands was used as the predictor of the strain rates involved at various cutting speeds. The results showed that the strain rates are quite in agreement with the amount of strain rate found during machining of such types of stainless steels. It was also observed that shear band density increased with increasing cutting speed. (author)

  8. A Continuum Damage Mechanics Model to Predict Kink-Band Propagation Using Deformation Gradient Tensor Decomposition

    Science.gov (United States)

    Bergan, Andrew C.; Leone, Frank A., Jr.

    2016-01-01

    A new model is proposed that represents the kinematics of kink-band formation and propagation within the framework of a mesoscale continuum damage mechanics (CDM) model. The model uses the recently proposed deformation gradient decomposition approach to represent a kink band as a displacement jump via a cohesive interface that is embedded in an elastic bulk material. The model is capable of representing the combination of matrix failure in the frame of a misaligned fiber and instability due to shear nonlinearity. In contrast to conventional linear or bilinear strain softening laws used in most mesoscale CDM models for longitudinal compression, the constitutive response of the proposed model includes features predicted by detailed micromechanical models. These features include: 1) the rotational kinematics of the kink band, 2) an instability when the peak load is reached, and 3) a nonzero plateau stress under large strains.

  9. Inflation rates, rifts, and bands in a pāhoehoe sheet flow

    Science.gov (United States)

    Hoblitt, Richard P.; Orr, Tim R.; Heliker, Christina; Denlinger, Roger P.; Hon, Ken; Cervelli, Peter F.

    2012-01-01

    The margins of sheet flows—pāhoehoe lavas emplaced on surfaces sloping Inflation and rift-band formation is probably cyclic, because the pattern we observed suggests episodic or crude cyclic behavior. Furthermore, some inflation rifts contain numerous bands whose spacing and general appearances are remarkably similar. We propose a conceptual model wherein the inferred cyclicity is due to the competition between the fluid pressure in the flow's liquid core and the tensile strength of the viscoelastic layer where it is weakest—in inflation rifts. The viscoelastic layer consists of lava that has cooled to temperatures between 800 and 1070 °C. This layer is the key parameter in our model because, in its absence, rift banding and stepwise changes in the flow height would not occur.

  10. Band profiles of Mott-insulator/band-insulator heterointerfaces revealed by photocurrent and electromodulation spectroscopies

    Science.gov (United States)

    Nakamura, Masao

    2011-03-01

    Heterointerfaces of Mott insulators provide a good laboratory to explore unprecedented electronic states induced by the strong electron correlation. Although a number of intriguing phenomena have been reported so far, their fundamental origins have not been fully addressed yet. This is partly because the interface band profile, which is one of the most basic knowledge to understand the interface electronic states, is still left to be unveiled. In this study, we have investigated in detail the interface band profiles of Mott insulators employing photocurrent and electromodulation spectroscopies as well as the conventional current-voltage and capacitance-voltage characterizations. We chose p -type (LaMn O3 and La 2 Cu O4) and n -type (SrMn O3 and Sm 2 Cu O4) as the Mott insulators and these are epitaxially connected to Nb doped SrTi O3 (electron-doped band insulator). The photocurrent action spectra for these heterojunctions showed negligibly-small band reconstruction as well as the existence of band bending and discontinuity in the Mott insulators, which are of no salient discrepancy with the rigid-band picture valid in the interface of conventional semiconductors~. However, the electromodulation spectra clearly indicate the band reconstruction in the Mott insulators~. The results mean that the rigid-band picture is valid in the low carrier-density regime even in Mott-insulator/band-insulator interfaces, but the intentional charge modulation leads the electron correlation effect in the Mott insulators. This work was done in collaboration with A. Sawa, J. Fujioka, M. Kawasaki and Y. Tokura. I acknowledge the support from Japan Society for the Promotion of Science (JSPS) through its ``Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program)''.

  11. UWB Filtering Power Divider with Two Narrow Notch-bands and Wide Stop-band

    Science.gov (United States)

    Wei, Feng; Wang, Xin-Yi; Zou, Xin Tong; Shi, Xiao Wei

    2017-12-01

    A compact filtering ultra-wideband (UWB) microstrip power divider (PD) with two sharply rejected notch-bands and wide stopband is analyzed and designed in this paper. The proposed UWB PD is based on a conventional Wilkinson power divider, while two stub loaded resonators (SLRs) are coupled into two symmetrical output ports to achieve a bandpass filtering response. The simplified composite right/left-handed (SCRLH) resonators are employed to generate the dual notched bands. Defected ground structure (DGS) is introduced to improve the passband performance. Good insertion/return losses, isolation and notch-band rejection are achieved as demonstrated in both simulation and experiment.

  12. The marginal band system in nymphalid butterfly wings.

    Science.gov (United States)

    Taira, Wataru; Kinjo, Seira; Otaki, Joji M

    2015-01-01

    Butterfly wing color patterns are highly complex and diverse, but they are believed to be derived from the nymphalid groundplan, which is composed of several color pattern systems. Among these pattern systems, the marginal band system, including marginal and submarginal bands, has rarely been studied. Here, we examined the color pattern diversity of the marginal band system among nymphalid butterflies. Marginal and submarginal bands are usually expressed as a pair of linear bands aligned with the wing margin. However, a submarginal band can be expressed as a broken band, an elongated oval, or a single dot. The marginal focus, usually a white dot at the middle of a wing compartment along the wing edge, corresponds to the pupal edge spot, one of the pupal cuticle spots that signify the locations of color pattern organizing centers. A marginal band can be expressed as a semicircle, an elongated oval, or a pair of eyespot-like structures, which suggest the organizing activity of the marginal focus. Physical damage at the pupal edge spot leads to distal dislocation of the submarginal band in Junonia almana and in Vanessa indica, suggesting that the marginal focus functions as an organizing center for the marginal band system. Taken together, we conclude that the marginal band system is developmentally equivalent to other symmetry systems. Additionally, the marginal band is likely a core element and the submarginal band a paracore element of the marginal band system, and both bands are primarily specified by the marginal focus organizing center.

  13. Band head spin assignment of superdeformed bands in 133Pr using two-parameter formulae

    Science.gov (United States)

    Sharma, Honey; Mittal, H. M.

    2018-03-01

    The two-parameter formulae viz. the power index formula, the nuclear softness formula and the VMI model are adopted to accredit the band head spin (I0) of four superdeformed rotational bands in 133Pr. The technique of least square fitting is used to accredit the band head spin for four superdeformed rotational bands in 133Pr. The root mean deviation among the computed transition energies and well-known experimental transition energies are attained by extracting the model parameters from the two-parameter formulae. The determined transition energies are in excellent agreement with the experimental transition energies, whenever exact spins are accredited. The power index formula coincides well with the experimental data and provides minimum root mean deviation. So, the power index formula is more efficient tool than the nuclear softness formula and the VMI model. The deviation of dynamic moment of inertia J(2) against the rotational frequency is also examined.

  14. Band connectivity for topological quantum chemistry: Band structures as a graph theory problem

    Science.gov (United States)

    Bradlyn, Barry; Elcoro, L.; Vergniory, M. G.; Cano, Jennifer; Wang, Zhijun; Felser, C.; Aroyo, M. I.; Bernevig, B. Andrei

    2018-01-01

    The conventional theory of solids is well suited to describing band structures locally near isolated points in momentum space, but struggles to capture the full, global picture necessary for understanding topological phenomena. In part of a recent paper [B. Bradlyn et al., Nature (London) 547, 298 (2017), 10.1038/nature23268], we have introduced the way to overcome this difficulty by formulating the problem of sewing together many disconnected local k .p band structures across the Brillouin zone in terms of graph theory. In this paper, we give the details of our full theoretical construction. We show that crystal symmetries strongly constrain the allowed connectivities of energy bands, and we employ graph theoretic techniques such as graph connectivity to enumerate all the solutions to these constraints. The tools of graph theory allow us to identify disconnected groups of bands in these solutions, and so identify topologically distinct insulating phases.

  15. Diagnosis and management of early gastric band slip after laparoscopic adjustable gastric banding

    Directory of Open Access Journals (Sweden)

    Mehmet Sertkaya

    2016-05-01

    Full Text Available Laparoscopic adjustable gastric banding (LAGB used to be a very popular bariatric procedure at a certain time for the treatment of obesity as it has many advantages and is associated with low morbidity and mortality rates. Complications are often late and are rarely seen by general surgeons due to the limited number of patients, and physicians should be aware of the symptoms. We present a case of a 40-year-old female patient who underwent LAGB and was admitted for a huge gastric pouch dilatation on postoperative day 5. She had a history of food consumption on the fourth day after surgery. She was diagnosed with early gastric band slippage (EGBS. The band was repositioned and gastrogastric sutures were placed to prevent reprolapse of the band. The EGBS is an immediate postoperative complication. Diagnosis of EGBS can be made with oral contrast X-ray studies, and surgical intervention is necessary.

  16. Electronic pairing mechanism due to band modification in a two-band model: Tc evaluation

    International Nuclear Information System (INIS)

    Mizia, J.; Gorski, G.; Traa, M.R.M.J.

    1997-01-01

    Following the electronic model developed by us previously (Mizia and Romanowski, Mizia) we estimate the superconducting transition temperature in a simple electronic two-band model for materials characterized by a broad superconducting band and a narrow level within the same energy range. A large electron deformation coupling constant and large electron correlation effects are assumed. It is shown that high-temperature superconductivity is entirely possible within a range of reasonable electronic parameters. This model does not assume any artificial interactions to obtain a negative pairing potential. Instead, the negative part of the electronic interaction potential comes from the modification of the electron dispersion relation with growing number of superconducting pairs. Such a modification is possible in soft electronic systems, i.e. in systems partial to band modification due to large internal stresses, strong electronic correlation effects and broad band narrow level charge transfer during the superconducting transition. (orig.)

  17. Periodic dielectric structure for production of photonic band gap and method for fabricating the same

    Science.gov (United States)

    Ozbay, Ekmel; Tuttle, Gary; Michel, Erick; Ho, Kai-Ming; Biswas, Rana; Chan, Che-Ting; Soukoulis, Costas

    1995-01-01

    A method for fabricating a periodic dielectric structure which exhibits a photonic band gap. Alignment holes are formed in a wafer of dielectric material having a given crystal orientation. A planar layer of elongate rods is then formed in a section of the wafer. The formation of the rods includes the step of selectively removing the dielectric material of the wafer between the rods. The formation of alignment holes and layers of elongate rods and wafers is then repeated to form a plurality of patterned wafers. A stack of patterned wafers is then formed by rotating each successive wafer with respect to the next-previous wafer, and then placing the successive wafer on the stack. This stacking results in a stack of patterned wafers having a four-layer periodicity exhibiting a photonic band gap.

  18. Bicarbonate adsorption band of the chromatography for carbon isotope separation using anion exchangers

    International Nuclear Information System (INIS)

    Takeda, Kunihiko; Obanawa, Heiichiro; Hata, Masahisa; Sato, Katsuya

    1985-01-01

    The equilibria of bicarbonate ion between two phases were studied for the carbon isotope separation using anion exchangers. The condition of the formation of a bicarbonate adsorption band was quantitatively discussed. The formation of the adsorption band depends on the difference of S-potential which is the sum of the standard redection chemical potentials and L-potential which is the sum of the reduction chemical potential. The isotopic separation factor observed was about 1.012, independent of the concentrations of acid and alkali in the solutions. The isotopic separation factor was considered to be determined by the reaction of bicarbonate ion on anion exchangers and carbon dioxide dissolved in solutions. The enriched carbon isotope whose isotopic abundance ratio ( 13 C/ 12 C) was 1.258 was obtained with the column packed with anion exchangers. (author)

  19. Assessment of S-NPP VIIRS band-to-band registration using Earth-scene features

    Science.gov (United States)

    Link, Daniel; Wang, Zhipeng; Xiong, Xiaoxiong

    2017-09-01

    The Visible Infrared Imaging Radiometer Suite (VIIRS) is currently operating onboard the Suomi National Polarorbiting Partnership (S-NPP) spacecraft. VIIRS records Earth imagery with spectral bands ranging from 0.4 to 12.2 micrometers at a combination of resolutions. Five imaging bands (I1-5) have a 375 m spatial resolution at nadir, which is half of the 750 m resolution of the 16 moderate resolution bands (M1-16). These bands are mounted according to their wavelengths at three separate Focal Plane Assemblies (FPA). The proper spatial registration among imaging bands is required to create multi-spectral images and analyses. Measurement of the band-to-band registration (BBR) is a determination of how well these bands are coincident. Using an external target such as the moon has proven to be a valid method and has been thoroughly investigated using VIIRS raw data record (RDR). Calibrated VIIRS radiometric data has been investigated using normalized mutual information (NMI) for BBR and shown stable results, by focusing on high-contrast shoreline sites. However, these results focus on a relatively small number of observations. We have previously reported analyses using earth-scene targets to determine BBR for MODIS instruments. This approach focuses on an African Desert site with high contrast spots generated through agricultural pivot irrigation. Using the near-daily observations provided by the VIIRS instrument, we investigate a large data set and track the BBR stability over the VIIRS mission. We discuss our results and compare them with prelaunch measurements and design specifications.

  20. Transport in bilayer and trilayer graphene: band gap engineering and band structure tuning

    Science.gov (United States)

    Zhu, Jun

    2014-03-01

    Controlling the stacking order of atomically thin 2D materials offers a powerful tool to control their properties. Linearly dispersed bands become hyperbolic in Bernal (AB) stacked bilayer graphene (BLG). Both Bernal (ABA) and rhombohedral (ABC) stacking occur in trilayer graphene (TLG), producing distinct band structures and electronic properties. A symmetry-breaking electric field perpendicular to the sample plane can further modify the band structures of BLG and TLG. In this talk, I will describe our experimental effort in these directions using dual-gated devices. Using thin HfO2 film deposited by ALD as gate dielectric, we are able to apply large displacement fields D > 6 V/nm and observe the opening and saturation of the field-induced band gap Eg in bilayer and ABC-stacked trilayer graphene, where the conduction in the mid gap changes by more than six decades. Its field and temperature dependence highlights the crucial role played by Coulomb disorder in facilitating hopping conduction and suppressing the effect of Eg in the tens of meV regime. In contrast, mid-gap conduction decreases with increasing D much more rapidly in clean h-BN dual-gated devices. Our studies also show the evolution of the band structure in ABA-stacked TLG, in particular the splitting of the Dirac-like bands in large D field and the signatures of two-band transport at high carrier densities. Comparison to theory reveals the need for more sophisticated treatment of electronic screening beyond self-consistent Hartree calculations to accurately predict the band structures of trilayer graphene and graphenic materials in general.

  1. The Origin of Lueders's Bands in Deformed Rock

    Energy Technology Data Exchange (ETDEWEB)

    Olsson, W.A.

    1999-03-31

    Lueders' bands are shear deformation features commonly observed in rock specimens that have been deformed experimentally in the brittle-ductile transition regime. For specimens that contain both faults (shear fractures that separate the specimen) and bands, the bands form earlier in the deformation history and their orientations are often different from the fault These differences pose the question of the relationship between these two structures. Understanding the origin of these features may shed light on the genesis of apparent natural analogues, and on the general process of rock deformation and fracture in the laboratory. This paper presents a hypothesis for the formation of Lueders' bands in laboratory specimens based on deformation localization theory considered in the context of the nonuniform stress distribution of the conventional triaxial experiment Lueders' bands and faults appear to be equivalent reflections of the localization process as it is controlled by nonuniform distributions of stress and evolution of incremental constitutive parameters resulting from increasing damage. To relate conditions for localization in laboratory specimens to natural settings, it will be necessary to design new experiments that create uniform stress and deformation fields, or to extract constitutive data indirectly from standard experiments using computational means.

  2. Development of softcopy environment for primary color banding visibility assessment

    Science.gov (United States)

    Min, Byungseok; Pizlo, Zygmunt; Allebach, Jan P.

    2008-01-01

    Fine-pitch banding is one of the most unwanted artifacts in laser electrophotographic (EP) printers. It is perceived as a quasiperiodic fluctuation in the process direction. Therefore, it is essential for printer vendors to know how banding is perceived by humans in order to improve print quality. Monochrome banding has been analyzed and assessed by many researchers; but there is no literature that deals with the banding of color laser printers as measured from actual prints. The study of color banding is complicated by the fact that the color banding signal is physically defined in a three-dimensional color space, while banding perception is described in a one-dimensional sense such as more banding or less banding. In addition, the color banding signal arises from the independent contributions of the four primary colorant banding signals. It is not known how these four distinct signals combine to give rise to the perception of color banding. In this paper, we develop a methodology to assess the banding visibility of the primary colorant cyan based on human visual perception. This is our first step toward studying the more general problem of color banding in combinations of two or more colorants. According to our method, we print and scan the cyan test patch, and extract the banding profile as a one dimensional signal so that we can freely adjust the intensity of banding. Thereafter, by exploiting the pulse width modulation capability of the laser printer, the extracted banding profile is used to modulate a pattern consisting of periodic lines oriented in the process direction, to generate extrinsic banding. This avoids the effect of the halftoning algorithm on the banding. Furthermore, to conduct various banding assessments more efficiently, we also develop a softcopy environment that emulates a hardcopy image on a calibrated monitor, which requires highly accurate device calibration throughout the whole system. To achieve the same color appearance as the hardcopy

  3. A Compact Tri-Band Bandpass Filter with High Out-of-Band Rejection

    Directory of Open Access Journals (Sweden)

    M. Abdul-Niby

    2017-08-01

    Full Text Available This paper presents a planar tri-band bandpass filter with high out-of-band rejection over a wide band. The filter is based on two pairs of λ/4 resonators embedded inside an open loop ring resonator without any size increase, where each pair of resonators are electromagnetically coupled to each other and the feedlines. This results in the excitations of passbands, where the first passband is generated by the open loop resonators. The second and the third passbands are excited by λ/4 resonators. The proposed technique provides sufficient degrees of freedom to control the center frequency and bandwidth of the three passbands independently. In addition, the six transmission zeros created around the passbands results in a tri-band filter with high selectivity, sharp 3 dB cut-off frequency, high isolation, low passband insertion-loss and high out-of-band harmonic rejection across an ultra-broadband frequency range up to 17 GHz. The proposed technique has the ability to switch from triple to dual band by removing one pair of the inner resonators. Design methodology and simulation results of the filter are provided.

  4. Wide band interferometry for thickness measurement

    Science.gov (United States)

    Costantino, Santiago; Martinez, Oscar E.; Torga, Jorge R.

    2003-04-01

    In this work we present the concept of wide band interferometry as opposed to white-light interferometry to introduce a thickness measurement method that gains precision when the bandwidth is reduced to an adequate compromise in order to avoid the distortions arising from the material dispersion. The use of the widest possible band is a well established dogma when the highest resolution is desired in distance measurements with white-light interferometry. We will show that the dogma falls when thickness measurements must be carried out due to material dispersion. In fact the precise knowledge of the frequency dependence of the refractive index is essential for adequate thickness retrieval from the optical experiments. The device we present is also useful to obtain the group refractive index that is necessary to calculate the absolute thickness value. As an example, we show the spreading of a silicone oil on a reference surface in real time.

  5. Strongly coupled band in 140Gd

    International Nuclear Information System (INIS)

    Falla-Sotelo, F.; Oliveira, J.R.B.; Rao, M.N.

    2005-01-01

    Several high-K states are known to exist in the mass 130-140 region. For the N=74 even-even isotopes, Kπ = 8 - isomers, with lifetimes ranging from ns to ms, are known in 128 Xe, 130 Ba, 132 Ce, 134 Nd, 136 Sm, and 138 Gd[. In 140 Gd, we have observed for the first time a band also based on an Iπ = 8 - state. This could be the first case of a Kπ = 8 - state observed in an N=76 even-even isotope. The systematics of the Kπ = 8 - isomeric states in N=74 isotopes has been studied by A.M. Bruce et al. These states decay towards the K = 0 ground state band, and the transitions are K-forbidden. The 140 Gd case presents strong similarities but also some significant differences with relation to the N=74 isotopes. We propose the same configuration but with larger deformation in 140 Gd

  6. L-Band RFI in Japan

    Science.gov (United States)

    Soldo, Yan; de Matthaeis, Paolo; Le Vine, David M.

    2016-01-01

    In recent years, three instruments have been launched into orbit with the aim of producing global maps of sea surface salinity and soil moisture using the 1400-1427 MHz band: SMOS, Aquarius and SMAP. Although this frequency band is allocated to passive measurements only, RFI (Radio-Frequency Interference) is present in the data of all three missions. On a global scale, the three sensors have observed approximately the same distribution of RFI. Japan is an important exception that has implications for the design of RFI detection algorithms. RFI in Japan is caused by a large number of emitters belonging to the same system (TV receivers) and for this reason some traditional RFI detection strategies detect little to no RFI over Japan. The study of this case has led to an improvement of the approach to detect RFI in Aquarius data.

  7. X-Band RF Gun Development

    International Nuclear Information System (INIS)

    Vlieks, A.E.

    2012-01-01

    In support of the MEGa-ray program at LLNL and the High Gradient research program at SLAC, a new X-band multi-cell RF gun is being developed. This gun, similar to earlier guns developed at SLAC for Compton X-ray source program, will be a standing wave structure made of 5.5 cells operating in the pi mode with copper cathode. This gun was designed following criteria used to build SLAC X-band high gradient accelerating structures. It is anticipated that this gun will operate with surface electric fields on the cathode of 200 MeV/m with low breakdown rate. RF will be coupled into the structure through a final cell with symmetric duel feeds and with a shape optimized to minimize quadrupole field components. In addition, geometry changes to the original gun, operated with Compton X-ray source, will include a wider RF mode separation, reduced surface electric and magnetic fields.

  8. High resolution color band pyrometer ratioing

    Science.gov (United States)

    Bickler, Donald B. (Inventor); Henry, Paul K. (Inventor); LoGiurato, D. Daniel (Inventor)

    1989-01-01

    The sensing head of a two-color band ratioing pyrometer of a known type using a fiber optic cable to couple radiation to dual detector photodiodes is improved to have high spatial resolution by focusing the radiation received through an objective lens (i.e., by focusing the image of a target area) onto an opaque sheet spaced in front of the input end of the fiber optic cable. A two-mil hole in that sheet then passes radiation to the input end of the cable. The detector has two channels, one for each color band, with an electronic-chopper stabilized current amplifier as the input stage followed by an electronic-chopper stabilized voltage amplifier.

  9. Design of an Electronic Chest-Band

    Science.gov (United States)

    Atakan, R.; Acikgoz Tufan, H.; Baskan, H.; Eryuruk, S. H.; Akalin, N.; Kose, H.; Li, Y.; Kursun Bahadir, S.; Kalaoglu, F.

    2017-10-01

    In this study, an electronic chest strap prototype was designed for measuring fitness level, performance optimization, mobility and fall detection. Knitting technology is used for production by using highly elastic nylon yarn. In order to evaluate comfort performance of the garment, yarn strength and elongation, air permeability, moisture management and FAST tests (Fabric Assurance Fabric Testing) were carried out, respectively. After testing of textile part of the chest band, IMU sensors were integrated onto the garment by means of conductive yarns. Electrical conductivity of the circuit was also assessed at the end. Results indicated that the weight and the thickness of the product are relatively high for sports uses and it has a negative impact on comfort properties. However, it is highly stretchable and moisture management properties are still in acceptable values. From the perspective of possible application areas, developed smart chest band in this research could be used in sports facilities as well as health care applications for elderly and disabled people.

  10. Large Aperture, Scanning, L-Band SAR

    Science.gov (United States)

    Moussessian, Alina; DelCastillo, Linda; Bach, Vinh; Grando, Maurio; Quijano, Ubaldo; Smith, Phil; Zawadzki, Mark

    2011-01-01

    We have developed the first L-band membrane-based active phased array. The antenna is a 16x16 element patch array with dimensions of 2.3mx2.6m. The array uses membrane-compatible Transmit/Receive (T/R) modules for electronic beam steering. We will discuss the antenna design, the fabrication of this large array, the T/R module development, the signal distribution approach and the measured results of the array

  11. Ku-Band Data-Communication Adapter

    Science.gov (United States)

    Schadelbauer, Steve

    1995-01-01

    Data-communication adapter circuit on single printed-circuit board serves as general-purpose interface between personal computer and satellite communication system. Designed as direct interface with Ku-band data-communication system for payloads on space shuttle, also used with any radio-frequency transmission systems. Readily installed in almost any personal computer via widely used Industry Standard Architecture (ISA) bus.

  12. Staggered broad-band reflecting multilayers.

    Science.gov (United States)

    Heavens, O S; Liddell, H M

    1966-03-01

    Considerable broadening of the reflectance band of a multilayer stack may be obtained by staggering the layer thicknesses in such a way that they form either an arithmetic or geometric progression. Results are shown for asymmetric and symmetric filters of 15, 25, and 35 layers. The presence of the narrowband transmission peaks exhibited by the symmetric filters is explained, and the advantages of the use of this type of filter as an interference filter is discussed.

  13. ''Identical'' bands in normally-deformed nuclei

    International Nuclear Information System (INIS)

    Garrett, J.D.; Baktash, C.; Yu, C.H.

    1990-01-01

    Gamma-ray transitions energies in neighboring odd- and even-mass nuclei for normally-deformed nuclear configurations are analyzed in a manner similar to recent analyses for superdeformed states. The moment of inertia is shown to depend on pair correlations and the aligned angular momentum of the odd nucleon. The implications of this analysis for ''identical'' super-deformed bands are discussed. 26 refs., 9 figs

  14. Surface band structures on Nb(001)

    International Nuclear Information System (INIS)

    Fang, B.; Lo, W.; Chien, T.; Leung, T.C.; Lue, C.Y.; Chan, C.T.; Ho, K.M.

    1994-01-01

    We report the joint studies of experimental and theoretical surface band structures of Nb(001). Angle-resolved photoelectron spectroscopy was used to determine surface-state dispersions along three high-symmetry axes bar Γ bar M, bar Γ bar X, and bar M bar X in the surface Brillouin zone. Ten surface bands have been identified. The experimental data are compared to self-consistent pseudopotential calculations for the 11-layer Nb(001) slabs that are either bulk terminated or fully relaxed (with a 12% contraction for the first interlayer spacing). The band calculations for a 12% surface-contracted slab are in better agreement with the experimental results than those for a bulk-terminated slab, except for a surface resonance near the Fermi level, which is related to the spin-orbit interaction. The charge profiles for all surface states or resonances have been calculated. Surface contraction effects on the charge-density distribution and the energy position of surface states and resonances will also be discussed

  15. Topological transitions in multi-band superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Continentino, Mucio A., E-mail: mucio@cbpf.br [Centro Brasileiro de Pesquisas Físicas, Rua Dr. Xavier Sigaud, 150, Urca 22290-180, Rio de Janeiro, RJ (Brazil); Deus, Fernanda, E-mail: fernanda@cbpf.br [Centro Brasileiro de Pesquisas Físicas, Rua Dr. Xavier Sigaud, 150, Urca 22290-180, Rio de Janeiro, RJ (Brazil); Padilha, Igor T., E-mail: igorfis@ufam.edu.br [Universidade Federal do Amazonas, Campus Capital, 69077-070, Manaus, AM (Brazil); Caldas, Heron, E-mail: hcaldas@ufsj.edu.br [Departamento de Ciências Naturais, Universidade Federal de São João Del Rei, 36301-000, São João Del Rei, MG (Brazil)

    2014-09-15

    The search for Majorana fermions has been concentrated in topological insulators or superconductors. In general, the existence of these modes requires the presence of spin–orbit interactions and of an external magnetic field. The former implies in having systems with broken inversion symmetry, while the latter breaks time reversal invariance. In a recent paper, we have shown that a two-band metal with an attractive inter-band interaction has non-trivial superconducting properties, if the k-dependent hybridization is anti-symmetric in the wave-vector. This is the case, if the crystalline potential mixes states with different parities as for orbitals with angular momentum l and l+1. In this paper we take into account the effect of an external magnetic field, not considered in the previous investigation, in a two-band metal and show how it modifies the topological properties of its superconducting state. We also discuss the conditions for the appearance of Majorana fermions in this system.

  16. Topological magnon bands in ferromagnetic star lattice

    Science.gov (United States)

    Owerre, S. A.

    2017-05-01

    The experimental observation of topological magnon bands and thermal Hall effect in a kagomé lattice ferromagnet Cu(1-3, bdc) has inspired the search for topological magnon effects in various insulating ferromagnets that lack an inversion center allowing a Dzyaloshinskii-Moriya (DM) spin-orbit interaction. The star lattice (also known as the decorated honeycomb lattice) ferromagnet is an ideal candidate for this purpose because it is a variant of the kagomé lattice with additional links that connect the up-pointing and down-pointing triangles. This gives rise to twice the unit cell of the kagomé lattice, and hence more interesting topological magnon effects. In particular, the triangular bridges on the star lattice can be coupled either ferromagnetically or antiferromagnetically which is not possible on the kagomé lattice ferromagnets. Here, we study DM-induced topological magnon bands, chiral edge modes, and thermal magnon Hall effect on the star lattice ferromagnet in different parameter regimes. The star lattice can also be visualized as the parent material from which topological magnon bands can be realized for the kagomé and honeycomb lattices in some limiting cases.

  17. Frequency Arrangement For 700 MHz Band

    Directory of Open Access Journals (Sweden)

    Ancans G.

    2015-02-01

    Full Text Available The 694-790 MHz (700 MHz band was allocated by the 2012 World Radiocommunication Conference (WRC-12 in ITU Region 1 (Europe included, to the mobile service on a co-primary basis with other services to which this band was allocated on the primary basis and identified for the International Mobile Telecommunications (IMT. At the same time, the countries of Region 1 will be able also to continue using these frequencies for their broadcasting services if necessary. This allocation will be effective immediately after 2015 World Radiocommunication Conference (WRC-15. In order to make the best possible use of this frequency band for mobile service, a worldwide harmonized frequency arrangement is to be prepared to allow for large economies of scale and international roaming as well as utilizing the available spectrum in the best possible way, minimizing possible interference between services, facilitating deployment and cross-border coordination. The authors analyze different possible frequency arrangements and conclude on the frequency arrangement most suitable for Europe.

  18. On the persistence of adiabatic shear bands

    Directory of Open Access Journals (Sweden)

    Bassim M.N.

    2012-08-01

    Full Text Available It is generally agreed that the initiation and development of adiabatic shear bands (ASBs are manifestations of damage in metallic materials subjected to high strain rates and large strains as those due to impact in a Hopkinson Bar system. Models for evolution of these bands have been described in the literature. One question that has not received attention is how persistent these bands are and whether their presence and effect can be reversed or eliminated by using a process of thermal (heat treatment or thermo-mechanical treatment that would relieve the material from the high strain associated with ASBs and their role as precursors to crack initiation and subsequent failure. Since ASBs are more prevalent and more defined in BCC metals including steels, a study was conducted to investigate the best conditions of generating ASBs in a heat treatable steel, followed by determining the best conditions for heat treatment of specimens already damaged by the presence of ASBs in order to relieve the strains due to ASBs and restore the material to an apparent microstructure without the “scars” due to the previous presence of ASBs. It was found that heat treatment achieves the curing from ASBs. This presentation documents the process undertaken to achieve this objective.

  19. Wakefield Band Partitioning in LINAC Structures

    International Nuclear Information System (INIS)

    Jones, Roger M

    2003-01-01

    In the NLC project multiple bunches of electrons and positrons will be accelerated initially to a centre of mass of 500 GeV and later to 1 TeV or more. In the process of accelerating 192 bunches within a pulse train, wakefields are excited which kick the trailing bunches off axis and can cause luminosity dilution and BBU (Beam Break Up). Several structures to damp the wakefield have been designed and tested at SLAC and KEK and these have been found to successfully damp the wakefield [1]. However, these 2π/3 structures suffered from electrical breakdown and this has prompted us to explore lower group velocity structures operating at higher fundamental mode phase advances. The wakefield partitioning amongst the bands has been found to change markedly with increased phase advance. Here we report on general trends in the kick factor and associated wakefield band partitioning in dipole bands as a function of phase advance of the synchronous mode in linacs. These results are applicable to both TW (travelling wave) and SW (standing wave) structures

  20. Cluster rotational bands in 11B

    Directory of Open Access Journals (Sweden)

    Danilov A.N.

    2016-01-01

    Full Text Available Differential cross-sections of 11B+α inelastic scattering at E(α =65 MeV leading to most of the known 11B states at excitation energies up to 14 MeV were measured [1]. The data analysis was done using Modified diffraction model (MDM [2] allowing determining radii of excited states. Radii of the states with excitation energies less than ∼ 7 MeV coincide with the radius of the ground state with an accuracy not less than 0.1 - 0.15 fm. This result is consistent with traditional view on shell structure of low-lying states in 11B. Most of the observed high-energy excited states are distributed among four rotational bands. Moments of inertia of band states are close to the moment of inertia of the Hoyle state of 12C. The calculated radii, related to these bands, are 0.7 - 1.0 fm larger than the radius of the ground state, and are close to the Hoyle state radius. These results are in agreement with existing predictions about various cluster structure of 11B at high excitation energies.