Pseudo-Polar Fourier Transform-Based Compressed Sensing MRI.
Yang, Yang; Liu, Feng; Li, Mingyan; Jin, Jin; Weber, Ewald; Liu, Qinghuo; Crozier, Stuart
2017-04-01
The use of radial k-space trajectories has drawn strong interest from researchers for their potential in developing fast imaging methods in magnetic resonance imaging (MRI). Compared with conventional Cartesian trajectories, radial sampling collects more data from the central k-space region and the radially sampled data are more incoherent. These properties are very suitable for compressed sensing (CS)-based fast imaging. When reconstructing under-sampled radial data with CS, regridding and inverse-regridding are needed to transfer data between the image and frequency domains. In each CS iteration, two-dimensional interpolations are implemented twice in the regridding and inverse-regridding, introducing errors and undermining reconstruction quality. To overcome these problems, a radial-like pseudo-polar (PP) trajectory is proposed for the CS MRI applications. The PP trajectory preserves all the essential features of radial trajectory and allows an image reconstruction with PP fast Fourier transform (PPFFT) instead of interpolations. This paper attempts to investigate the performance of PP trajectory-based CS-MRI. In CS-based image reconstruction, the transformation of PP-sampled k-space data into the image domain is realized through PPFFT, which is based on the standard one-dimensional FFT and the fractional Fourier transform. To evaluate the effectiveness of the proposed methods, both numerical and experimental data are used to compare the new methods with conventional approaches. The proposed method provided high-quality reconstruction of the MR images with over 2-dB gain in peak signal-to-noise ratio while keeping structural similarity over 0.88 in different situations. Compared with the conventional radial sampling-based CS MRI methods, the proposed method achieves a more accurate reconstruction with respect to image detail/edge preservation and artifact suppression. The successful implementation of the PP subsampling-based CS scheme provides a practical and
Nonlinear Fourier transform for dual-polarization optical communication system
DEFF Research Database (Denmark)
Gaiarin, Simone
communication is considered an emerging paradigm in fiber-optic communications that could potentially overcome these limitations. It relies on a mathematical technique called “inverse scattering transform” or “nonlinear Fourier transform (NFT)” to exploit the “hidden” linearity of the nonlinear Schrödinger...
Building a symbolic computer algebra toolbox to compute 2D Fourier transforms in polar coordinates.
Dovlo, Edem; Baddour, Natalie
2015-01-01
The development of a symbolic computer algebra toolbox for the computation of two dimensional (2D) Fourier transforms in polar coordinates is presented. Multidimensional Fourier transforms are widely used in image processing, tomographic reconstructions and in fact any application that requires a multidimensional convolution. By examining a function in the frequency domain, additional information and insights may be obtained. The advantages of our method include: •The implementation of the 2D Fourier transform in polar coordinates within the toolbox via the combination of two significantly simpler transforms.•The modular approach along with the idea of lookup tables implemented help avoid the issue of indeterminate results which may occur when attempting to directly evaluate the transform.•The concept also helps prevent unnecessary computation of already known transforms thereby saving memory and processing time.
An Image Matching Method Based on Fourier and LOG-Polar Transform
Directory of Open Access Journals (Sweden)
Zhijia Zhang
2014-04-01
Full Text Available This Traditional template matching methods are not appropriate for the situation of large angle rotation between two images in the online detection for industrial production. Aiming at this problem, Fourier transform algorithm was introduced to correct image rotation angle based on its rotatary invariance in time-frequency domain, orienting image under test in the same direction with reference image, and then match these images using matching algorithm based on log-polar transform. Compared with the current matching algorithms, experimental results show that the proposed algorithm can not only match two images with rotation of arbitrary angle, but also possess a high matching accuracy and applicability. In addition, the validity and reliability of algorithm was verified by simulated matching experiment targeting circular images.
Machine learning (ML)-guided OPC using basis functions of polar Fourier transform
Choi, Suhyeong; Shim, Seongbo; Shin, Youngsoo
2016-03-01
With shrinking feature size, runtime has become a limitation of model-based OPC (MB-OPC). A few machine learning-guided OPC (ML-OPC) have been studied as candidates for next-generation OPC, but they all employ too many parameters (e.g. local densities), which set their own limitations. We propose to use basis functions of polar Fourier transform (PFT) as parameters of ML-OPC. Since PFT functions are orthogonal each other and well reflect light phenomena, the number of parameters can significantly be reduced without loss of OPC accuracy. Experiments demonstrate that our new ML-OPC achieves 80% reduction in OPC time and 35% reduction in the error of predicted mask bias when compared to conventional ML-OPC.
DEFF Research Database (Denmark)
Hu, Hao; Kong, Deming; Palushani, Evarist
2013-01-01
320 Gb/s Nyquist-OTDM is generated by rectangular filtering with a bandwidth of 320 GHz and received by polarization-insensitive time-domain optical Fourier transformation (TD-OFT) followed by passive filtering. After the time-to-frequency mapping in the TD-OFT, the Nyquist-OTDM is converted...
Indian Academy of Sciences (India)
digital methods of spectrum estimation which influenced the research in almost every field of engineering and science. In this article, we will first introduce the conti- nuous-time Fourier transform (eFT), discrete-time Fourier transform and discrete Fourier transform (DFT) and then present an example to illustrate the relation ...
Alexandrov, Mikhail D.; Cairns, Brian; Mishchenko, Michael I.
2012-01-01
We present a novel technique for remote sensing of cloud droplet size distributions. Polarized reflectances in the scattering angle range between 135deg and 165deg exhibit a sharply defined rainbow structure, the shape of which is determined mostly by single scattering properties of cloud particles, and therefore, can be modeled using the Mie theory. Fitting the observed rainbow with such a model (computed for a parameterized family of particle size distributions) has been used for cloud droplet size retrievals. We discovered that the relationship between the rainbow structures and the corresponding particle size distributions is deeper than it had been commonly understood. In fact, the Mie theory-derived polarized reflectance as a function of reduced scattering angle (in the rainbow angular range) and the (monodisperse) particle radius appears to be a proxy to a kernel of an integral transform (similar to the sine Fourier transform on the positive semi-axis). This approach, called the rainbow Fourier transform (RFT), allows us to accurately retrieve the shape of the droplet size distribution by the application of the corresponding inverse transform to the observed polarized rainbow. While the basis functions of the proxy-transform are not exactly orthogonal in the finite angular range, this procedure needs to be complemented by a simple regression technique, which removes the retrieval artifacts. This non-parametric approach does not require any a priori knowledge of the droplet size distribution functional shape and is computationally fast (no look-up tables, no fitting, computations are the same as for the forward modeling).
Generalized Fourier transforms classes
DEFF Research Database (Denmark)
Berntsen, Svend; Møller, Steen
2002-01-01
The Fourier class of integral transforms with kernels $B(\\omega r)$ has by definition inverse transforms with kernel $B(-\\omega r)$. The space of such transforms is explicitly constructed. A slightly more general class of generalized Fourier transforms are introduced. From the general theory foll...... follows that integral transform with kernels which are products of a Bessel and a Hankel function or which is of a certain general hypergeometric type have inverse transforms of the same structure....
Dual-polarization nonlinear Fourier transform-based optical communication system
DEFF Research Database (Denmark)
Gaiarin, Simone; Perego, A. M.; da Silva, Edson Porto
2018-01-01
communication could potentially overcome these limitations. It relies on a mathematical technique called “nonlinear Fourier transform (NFT)” to exploit the “hidden” linearity of the nonlinear Schrödinger equation as the master model for signal propagation in an optical fiber. We present here the theoretical...
Fourier Transform Spectrometer
National Aeronautics and Space Administration — The Fourier Transform Spectrometer project demonstrates the efficacy of a miniaturized spectrometer for flight applications.A spectrometer is an instrument used to...
Fourier transformation for pedestrians
Butz, Tilman
2015-01-01
This book is an introduction to Fourier Transformation with a focus on signal analysis, based on the first edition. It is well suited for undergraduate students in physics, mathematics, electronic engineering as well as for scientists in research and development. It gives illustrations and recommendations when using existing Fourier programs and thus helps to avoid frustrations. Moreover, it is entertaining and you will learn a lot unconsciously. Fourier series as well as continuous and discrete Fourier transformation are discussed with particular emphasis on window functions. Filter effects of digital data processing are illustrated. Two new chapters are devoted to modern applications. The first deals with data streams and fractional delays and the second with the back-projection of filtered projections in tomography. There are many figures and mostly easy to solve exercises with solutions.
Fourier Transform Mass Spectrometry.
Gross, Michael L.; Rempel, Don L.
1984-01-01
Discusses the nature of Fourier transform mass spectrometry and its unique combination of high mass resolution, high upper mass limit, and multichannel advantage. Examines its operation, capabilities and limitations, applications (ion storage, ion manipulation, ion chemistry), and future applications and developments. (JN)
Directory of Open Access Journals (Sweden)
Hideaki Nakajima
2010-12-01
Full Text Available Polar stratospheric clouds (PSCs play an important role in ozone destruction via the occurrence of heterogeneous reactions on their surface that convert reservoir species of active chlorine and bromine (e.g., HCl, ClONO_2, HBr, or BrONO_2 into active Cl_2 or Br_2. However, a lack of direct measurements means that uncertainty remains regarding the characteristics, types, mixtures, and nature of PSCs. To address this problem, we conducted, for the first time, ground-based measurements of the features of PSCs using a low-resolution Fourier-transform infrared (FTIR spectrometer at Syowa Station, Antarctica, in 2007. Many PSCs were observed between July and August 2007. We succeeded in identifying the features of Ice (Type-II, NAD and or β-NAT (Type-Ia, and STS (Type-Ib PSCs in the zenith sky infrared spectra measured by FTIR.
Fourier transforms principles and applications
Hansen, Eric W
2014-01-01
Fourier Transforms: Principles and Applications explains transform methods and their applications to electrical systems from circuits, antennas, and signal processors-ably guiding readers from vector space concepts through the Discrete Fourier Transform (DFT), Fourier series, and Fourier transform to other related transform methods. Featuring chapter end summaries of key results, over two hundred examples and four hundred homework problems, and a Solutions Manual this book is perfect for graduate students in signal processing and communications as well as practicing engineers.
DEFF Research Database (Denmark)
Guan, P.; Mulvad, Hans Christian Hansen; Tomiyama, Y.
2010-01-01
A single-channel 1.28 Tbit/s transmission over 525 km is demonstrated for the first time with a single-polarization DQPSK signal. Ultrafast time-domain optical Fourier transformation is successfully applied to DQPSK signals and results in improved performance and increased system margin.......A single-channel 1.28 Tbit/s transmission over 525 km is demonstrated for the first time with a single-polarization DQPSK signal. Ultrafast time-domain optical Fourier transformation is successfully applied to DQPSK signals and results in improved performance and increased system margin....
Fourier transforms in spectroscopy
Kauppinen, Jyrki
2000-01-01
This modern approach to the subject is clearly and logically structured, and gives readers an understanding of the essence of Fourier transforms and their applications. All important aspects are included with respect to their use with optical spectroscopic data. Based on popular lectures, the authors provide the mathematical fundamentals and numerical applications which are essential in practical use. The main part of the book is dedicated to applications of FT in signal processing and spectroscopy, with IR and NIR, NMR and mass spectrometry dealt with both from a theoretical and practical poi
Fourier Transform Spectrometer System
Campbell, Joel F. (Inventor)
2014-01-01
A Fourier transform spectrometer (FTS) data acquisition system includes an FTS spectrometer that receives a spectral signal and a laser signal. The system further includes a wideband detector, which is in communication with the FTS spectrometer and receives the spectral signal and laser signal from the FTS spectrometer. The wideband detector produces a composite signal comprising the laser signal and the spectral signal. The system further comprises a converter in communication with the wideband detector to receive and digitize the composite signal. The system further includes a signal processing unit that receives the composite signal from the converter. The signal processing unit further filters the laser signal and the spectral signal from the composite signal and demodulates the laser signal, to produce velocity corrected spectral data.
Electro-optic imaging Fourier transform spectrometer
Chao, Tien-Hsin (Inventor); Znod, Hanying (Inventor)
2009-01-01
An Electro-Optic Imaging Fourier Transform Spectrometer (EOIFTS) for Hyperspectral Imaging is described. The EOIFTS includes an input polarizer, an output polarizer, and a plurality of birefringent phase elements. The relative orientations of the polarizers and birefringent phase elements can be changed mechanically or via a controller, using ferroelectric liquid crystals, to substantially measure the spectral Fourier components of light propagating through the EIOFTS. When achromatic switches are used as an integral part of the birefringent phase elements, the EIOFTS becomes suitable for broadband applications, with over 1 micron infrared bandwidth.
Fourier transform nuclear magnetic resonance
International Nuclear Information System (INIS)
Geick, R.
1981-01-01
This review starts with the basic principles of resonance phenomena in physical systems. Especially, the connection is shown between the properties of these systems and Fourier transforms. Next, we discuss the principles of nuclear magnetic resonance. Starting from the general properties of physical systems showing resonance phenomena and from the special properties of nuclear spin systems, the main part of this paper reviews pulse and Fourier methods in nuclear magnetic resonance. Among pulse methods, an introduction will be given to spin echoes, and, apart from the principle of Fourier transform nuclear magnetic resonance, an introduction to the technical problems of this method, e.g. resolution in the frequency domain, aliasing, phase and intensity errors, stationary state of the spin systems for repetitive measurements, proton decoupling, and application of Fourier methods to systems in a nonequilibrium state. The last section is devoted to special applications of Fourier methods and recent developments, e.g. measurement of relaxation times, solvent peak suppression, 'rapid scan'-method, methods for suppressing the effects of dipolar coupling in solids, two-dimensional Fourier transform nuclear magnetic resonance, and spin mapping or zeugmatography. (author)
Preston, Louisa J; Johnson, Diane; Cockell, Charles S; Grady, Monica M
2015-09-01
Cryptoendolithic lichen communities of the Dry Valleys, Antarctica, survive in an extremely inhospitable environment, finding refuge in microscopic niches where conditions suitable for life exist. Such "within-rock" communities may have evolved on Mars when conditions for life on the surface deteriorated to such an extent that they could no longer survive. Fourier transform infrared spectroscopy of unprepared whole-rock Antarctic Beacon sandstones was used to vertically profile molecular vibrations of fatty acids, proteins, and carboxylic acids created by endolithic communities. Spectral biosignatures were found localized to lichen-rich areas and were absent in crustal regions and the bulk rock substrate. These cryptoendolithic profiles will aid similar spectroscopic investigations of organic biosignatures during future Martian subsurface studies and will help in the identification of similar communities in other localities across the Earth.
General Correlation Theorem for Trinion Fourier Transform
Bahri, Mawardi
2017-01-01
- The trinion Fourier transform is an extension of the Fourier transform in the trinion numbers setting. In this work we derive the correlation theorem for the trinion Fourier transform by using the relation between trinion convolution and correlation definitions in the trinion Fourier transform domains.
FOURIER SERIES MODELS THROUGH TRANSFORMATION
African Journals Online (AJOL)
DEPT
This study considers the application of Fourier series analysis (FSA) to seasonal time series data. The ultimate objective of the study is to construct an FSA model that can lead to reliable forecast. Specifically, the study evaluates data for the assumptions of time series analysis; applies the necessary transformation to the ...
Synthetic Fourier transform light scattering.
Lee, Kyeoreh; Kim, Hyeon-Don; Kim, Kyoohyun; Kim, Youngchan; Hillman, Timothy R; Min, Bumki; Park, Yongkeun
2013-09-23
We present synthetic Fourier transform light scattering, a method for measuring extended angle-resolved light scattering (ARLS) from individual microscopic samples. By measuring the light fields scattered from the sample plane and numerically synthesizing them in Fourier space, the angle range of the ARLS patterns is extended up to twice the numerical aperture of the imaging system with unprecedented sensitivity and precision. Extended ARLS patterns of individual microscopic polystyrene beads, healthy human red blood cells (RBCs), and Plasmodium falciparum-parasitized RBCs are presented.
Debnath, Lokenath
2012-01-01
This article deals with a brief biographical sketch of Joseph Fourier, his first celebrated work on analytical theory of heat, his first great discovery of Fourier series and Fourier transforms. Included is a historical development of Fourier series and Fourier transforms with their properties, importance and applications. Special emphasis is made…
Jones matrix treatment for optical Fourier processors with structured polarization.
Moreno, Ignacio; Iemmi, Claudio; Campos, Juan; Yzuel, Maria J
2011-02-28
We present a Jones matrix method useful to analyze coherent optical Fourier processors employing structured polarization. The proposed method is a generalization of the standard classical optical Fourier transform processor, but considering vectorial spatial functions with two complex components corresponding to two orthogonal linear polarizations. As a result we derive a Jones matrix that describes the polarization output in terms of two vectorial functions defining respectively the structured polarization input and the generalized polarization impulse response. We apply the method to show and analyze an experiment in which a regular scalar diffraction grating is converted into equivalent polarization diffraction gratings by means of an appropriate polarization filtering. The technique is further demonstrated to generate arbitrary structured polarizations. Excellent experimental results are presented.
Jung, JaeHwang; Kim, Jinhyung; Seo, Min-Kyo; Park, YongKeun
2018-03-01
We present a method to measure the vector-field light scattering of individual microscopic objects. The polarization-dependent optical field images are measured with quantitative phase imaging at the sample plane, and then numerically propagated to the far-field plane. This approach allows the two-dimensional polarization-dependent angle-resolved light scattered patterns from individual object to be obtained with high precision and sensitivity. Using this method, we present the measurements of the polarization-dependent light scattering of a liquid crystal droplet and individual silver nanowires over scattering angles of 50{\\deg}. In addition, the spectroscopic extension of the polarization-dependent angle-resolved light scattering is demonstrated using wavelength-scanning illumination.
Improved Fourier-transform profilometry
International Nuclear Information System (INIS)
Mao Xianfu; Chen Wenjing; Su Xianyu
2007-01-01
An improved optical geometry of the projected-fringe profilometry technique, in which the exit pupil of the projecting lens and the entrance pupil of the imaging lens are neither at the same height above the reference plane nor coplanar, is discussed and used in Fourier-transform profilometry. Furthermore, an improved fringe-pattern description and phase-height mapping formula based on the improved geometrical generalization is deduced. Employing the new optical geometry, it is easier for us to obtain the full-field fringe by moving either the projector or the imaging device. Therefore the new method offers a flexible way to obtain reliable height distribution of a measured object
Fourier-transform optical microsystems
Collins, S. D.; Smith, R. L.; Gonzalez, C.; Stewart, K. P.; Hagopian, J. G.; Sirota, J. M.
1999-01-01
The design, fabrication, and initial characterization of a miniature single-pass Fourier-transform spectrometer (FTS) that has an optical bench that measures 1 cm x 5 cm x 10 cm is presented. The FTS is predicated on the classic Michelson interferometer design with a moving mirror. Precision translation of the mirror is accomplished by microfabrication of dovetailed bearing surfaces along single-crystal planes in silicon. Although it is miniaturized, the FTS maintains a relatively high spectral resolution, 0.1 cm-1, with adequate optical throughput.
Fourier Transform Methods. Chapter 4
Kaplan, Simon G.; Quijada, Manuel A.
2015-01-01
This chapter describes the use of Fourier transform spectrometers (FTS) for accurate spectrophotometry over a wide spectral range. After a brief exposition of the basic concepts of FTS operation, we discuss instrument designs and their advantages and disadvantages relative to dispersive spectrometers. We then examine how common sources of error in spectrophotometry manifest themselves when using an FTS and ways to reduce the magnitude of these errors. Examples are given of applications to both basic and derived spectrophotometric quantities. Finally, we give recommendations for choosing the right instrument for a specific application, and how to ensure the accuracy of the measurement results..
Tunable fractional-order Fourier transformer
International Nuclear Information System (INIS)
Malyutin, A A
2006-01-01
A fractional two-dimensional Fourier transformer whose orders are tuned by means of optical quadrupoles is described. It is shown that in the optical scheme considered, the Fourier-transform order a element of [0,1] in one of the mutually orthogonal planes corresponds to the transform order (2-a) in another plane, i.e., to inversion and inverse Fourier transform of the order a. (laser modes and beams)
Image reconstruction from pairs of Fourier-transform magnitude
International Nuclear Information System (INIS)
Hunt, B.R.; Overman, T.L.; Gough, P.
1998-01-01
The retrieval of phase information from only the magnitude of the Fourier transform of a signal remains an important problem for many applications. We present an algorithm for phase retrieval when there exist two related sets of Fourier-transform magnitude data. The data are assumed to come from a single object observed in two different polarizations through a distorting medium, so the phase component of the Fourier transform of the object is corrupted. Phase retrieval is accomplished by minimization of a suitable criterion function, which can take three different forms. copyright 1998 Optical Society of America
Applications of Fourier transforms to generalized functions
Rahman, M
2011-01-01
This book explains how Fourier transforms can be applied to generalized functions. The generalized function is one of the important branches of mathematics and is applicable in many practical fields. Its applications to the theory of distribution and signal processing are especially important. The Fourier transform is a mathematical procedure that can be thought of as transforming a function from its time domain to the frequency domain.The book contains six chapters and three appendices. Chapter 1 deals with preliminary remarks on Fourier series from a general point of view and also contains an introduction to the first generalized function. Chapter 2 is concerned with the generalized functions and their Fourier transforms. Chapter 3 contains the Fourier transforms of particular generalized functions. The author has stated and proved 18 formulas dealing with the Fourier transforms of generalized functions, and demonstrated some important problems of practical interest. Chapter 4 deals with the asymptotic esti...
Fourier Analysis and Structure Determination: Part I: Fourier Transforms.
Chesick, John P.
1989-01-01
Provides a brief introduction with some definitions and properties of Fourier transforms. Shows relations, ways of understanding the mathematics, and applications. Notes proofs are not included but references are given. First of three part series. (MVL)
Dual Comb Fourier Transform Spectroscopy
Hänsch, T. W.; Picqué, N.
2010-06-01
The advent of laser frequency combs a decade ago has already revolutionized optical frequency metrology and precision spectroscopy. Extensions of laser combs from the THz region to the extreme ultraviolet and soft x-ray frequencies are now under exploration. Such laser combs have become enabling tools for a growing tree of applications, from optical atomic clocks to attosecond science. Recently, the millions of precisely controlled laser comb lines that can be produced with a train of ultrashort laser pulses have been harnessed for highly multiplexed molecular spectroscopy. Fourier multi-heterodyne spectroscopy, dual comb spectroscopy, or asynchronous optical sampling spectroscopy with frequency combs are emerging as powerful new spectroscopic tools. Even the first proof-of-principle experiments have demonstrated a very exciting potential for ultra-rapid and ultra-sensitive recording of complex molecular spectra. Compared to conventional Fourier transform spectroscopy, recording times could be shortened from seconds to microseconds, with intriguing prospects for spectroscopy of short lived transient species. Longer recording times allow high resolution spectroscopy of molecules with extreme precision, since the absolute frequency of each laser comb line can be known with the accuracy of an atomic clock. The spectral structure of sharp lines of a laser comb can be very useful even in the recording of broadband spectra without sharp features, as they are e.g. encountered for molecular gases or in the liquid phase. A second frequency comb of different line spacing permits the generation of a comb of radio frequency beat notes, which effectively map the optical spectrum into the radio frequency regime, so that it can be recorded with a single fast photodetector, followed by digital signal analysis. In the time domain, a pulse train of a mode-locked femtosecond laser excites some molecular medium at regular time intervals. A second pulse train of different repetition
The Geostationary Fourier Transform Spectrometer
Key, Richard; Sander, Stanley; Eldering, Annmarie; Blavier, Jean-Francois; Bekker, Dmitriy; Manatt, Ken; Rider, David; Wu, Yen-Hung
2012-01-01
The Geostationary Fourier Transform Spectrometer (GeoFTS) is an imaging spectrometer designed for a geostationary orbit (GEO) earth science mission to measure key atmospheric trace gases and process tracers related to climate change and human activity. GEO allows GeoFTS to continuously stare at a region of the earth for frequent sampling to capture the variability of biogenic fluxes and anthropogenic emissions from city to continental spatial scales and temporal scales from diurnal, synoptic, seasonal to interannual. The measurement strategy provides a process based understanding of the carbon cycle from contiguous maps of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and chlorophyll fluorescence (CF) collected many times per day at high spatial resolution (2.7kmx2.7km at nadir). The CO2/CH4/CO/CF measurement suite in the near infrared spectral region provides the information needed to disentangle natural and anthropogenic contributions to atmospheric carbon concentrations and to minimize uncertainties in the flow of carbon between the atmosphere and surface. The half meter cube size GeoFTS instrument is based on a Michelson interferometer design that uses all high TRL components in a modular configuration to reduce complexity and cost. It is self-contained and as independent of the spacecraft as possible with simple spacecraft interfaces, making it ideal to be a "hosted" payload on a commercial communications satellite mission. The hosted payload approach for measuring the major carbon-containing gases in the atmosphere from the geostationary vantage point will affordably advance the scientific understating of carbon cycle processes and climate change.
Fourier series, Fourier transform and their applications to mathematical physics
Serov, Valery
2017-01-01
This text serves as an introduction to the modern theory of analysis and differential equations with applications in mathematical physics and engineering sciences. Having outgrown from a series of half-semester courses given at University of Oulu, this book consists of four self-contained parts. The first part, Fourier Series and the Discrete Fourier Transform, is devoted to the classical one-dimensional trigonometric Fourier series with some applications to PDEs and signal processing. The second part, Fourier Transform and Distributions, is concerned with distribution theory of L. Schwartz and its applications to the Schrödinger and magnetic Schrödinger operations. The third part, Operator Theory and Integral Equations, is devoted mostly to the self-adjoint but unbounded operators in Hilbert spaces and their applications to integral equations in such spaces. The fourth and final part, Introduction to Partial Differential Equations, serves as an introduction to modern methods for classical theory o...
Group-invariant finite Fourier transforms
International Nuclear Information System (INIS)
Shenefelt, M.H.
1988-01-01
The computation of the finite Fourier transform of functions is one of the most used computations in crystallography. Since the Fourier transform involved in 3-dimensional, the size of the computation becomes very large even for relatively few sample points along each edge. In this thesis, there is a family of algorithms that reduce the computation of Fourier transform of functions respecting the symmetries. Some properties of these algorithms are: (1) The algorithms make full use of the group of symmetries of a crystal. (2) The algorithms can be factored and combined according to the prime factorization of the number of points in the sample space. (3) The algorithms are organized into a family using the group structure of the crystallographic groups to make iterative procedures possible
Fourier transforms and convolutions for the experimentalist
Jennison, RC
1961-01-01
Fourier Transforms and Convolutions for the Experimentalist provides the experimentalist with a guide to the principles and practical uses of the Fourier transformation. It aims to bridge the gap between the more abstract account of a purely mathematical approach and the rule of thumb calculation and intuition of the practical worker. The monograph springs from a lecture course which the author has given in recent years and for which he has drawn upon a number of sources, including a set of notes compiled by the late Dr. I. C. Browne from a series of lectures given by Mr. J . A. Ratcliffe of t
Interferogram analysis using Fourier transform techniques
Roddier, Claude; Roddier, Francois
1987-01-01
A method of interferogram analysis is described in which Fourier transform techniques are used to map the complex fringe visibility in several types of interferograms. Algorithms are developed for estimation of both the amplitude and the phase of the fringes (yielding the modulus and the phase of the holographically recorded object Fourier transform). The algorithms were applied to the reduction of interferometric seeing measurements (i.e., the estimation of the fringe amplitude only), and the reduction of interferometric tests (i.e., estimation of the fringe phase only). The method was used to analyze scatter-plate interferograms obtained at NOAO.
An optical Fourier transform coprocessor with direct phase determination.
Macfaden, Alexander J; Gordon, George S D; Wilkinson, Timothy D
2017-10-20
The Fourier transform is a ubiquitous mathematical operation which arises naturally in optics. We propose and demonstrate a practical method to optically evaluate a complex-to-complex discrete Fourier transform. By implementing the Fourier transform optically we can overcome the limiting O(nlogn) complexity of fast Fourier transform algorithms. Efficiently extracting the phase from the well-known optical Fourier transform is challenging. By appropriately decomposing the input and exploiting symmetries of the Fourier transform we are able to determine the phase directly from straightforward intensity measurements, creating an optical Fourier transform with O(n) apparent complexity. Performing larger optical Fourier transforms requires higher resolution spatial light modulators, but the execution time remains unchanged. This method could unlock the potential of the optical Fourier transform to permit 2D complex-to-complex discrete Fourier transforms with a performance that is currently untenable, with applications across information processing and computational physics.
Clifford Fourier transform on vector fields.
Ebling, Julia; Scheuermann, Gerik
2005-01-01
Image processing and computer vision have robust methods for feature extraction and the computation of derivatives of scalar fields. Furthermore, interpolation and the effects of applying a filter can be analyzed in detail and can be advantages when applying these methods to vector fields to obtain a solid theoretical basis for feature extraction. We recently introduced the Clifford convolution, which is an extension of the classical convolution on scalar fields and provides a unified notation for the convolution of scalar and vector fields. It has attractive geometric properties that allow pattern matching on vector fields. In image processing, the convolution and the Fourier transform operators are closely related by the convolution theorem and, in this paper, we extend the Fourier transform to include general elements of Clifford Algebra, called multivectors, including scalars and vectors. The resulting convolution and derivative theorems are extensions of those for convolution and the Fourier transform on scalar fields. The Clifford Fourier transform allows a frequency analysis of vector fields and the behavior of vector-valued filters. In frequency space, vectors are transformed into general multivectors of the Clifford Algebra. Many basic vector-valued patterns, such as source, sink, saddle points, and potential vortices, can be described by a few multivectors in frequency space.
Implementation of quantum and classical discrete fractional Fourier transforms
Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N.; Szameit, Alexander
2016-01-01
Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools. PMID:27006089
Implementation of quantum and classical discrete fractional Fourier transforms.
Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N; Szameit, Alexander
2016-03-23
Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools.
An Uncertainty Principle for Quaternion Fourier Transform
BAHRI, Mawardi; HITZER, Eckhard S. M; HAYASHI, Akihisa; ASHINO, Ryuichi
2008-01-01
We review the quaternionic Fourier transform(QFT). Using the properties of the QFT we establish an uncertainty principle for the right-sided QFT.This uncertainty principle prescribes a lower bound on the product of the effective widths of quaternion-valued signals in the spatial and frequency domains. It is shown that only a Gaussian quaternion signal minimizes the uncertainty.
Fourier series models through transformation | Omekara | Global ...
African Journals Online (AJOL)
This study considers the application of Fourier series analysis (FSA) to seasonal time series data. The ultimate objective of the study is to construct an FSA model that can lead to reliable forecast. Specifically, the study evaluates data for the assumptions of time series analysis; applies the necessary transformation to the ...
Fast Fourier Transform Spectral Analysis Program
Daniel, J. A., Jr.; Graves, M. L.; Hovey, N. M.
1969-01-01
Fast Fourier Transform Spectral Analysis Program is used in frequency spectrum analysis of postflight, space vehicle telemetered trajectory data. This computer program with a digital algorithm can calculate power spectrum rms amplitudes and cross spectrum of sampled parameters at even time increments.
Fourier transforms on a semisimple symmetric space
Ban, E.P. van den; Schlichtkrull, H.
1994-01-01
Let G=H be a semisimple symmetric space, that is, G is a connected semisimple real Lie group with an involution ?, and H is an open subgroup of the group of xed points for ? in G. The main purpose of this paper is to study an explicit Fourier transform on G=H. In terms of general representation
Fourier transforms on a semisimple symmetric space
Ban, E.P. van den; Carmona, J.; Delorme, P.
1997-01-01
Let G=H be a semisimple symmetric space, that is, G is a connected semisimple real Lie group with an involution ?, and H is an open subgroup of the group of xed points for ? in G. The main purpose of this paper is to study an explicit Fourier transform on G=H. In terms of general representation
The PROSAIC Laplace and Fourier Transform
International Nuclear Information System (INIS)
Smith, G.A.
1994-01-01
Integral Transform methods play an extremely important role in many branches of science and engineering. The ease with which many problems may be solved using these techniques is well known. In Electrical Engineering especially, Laplace and Fourier Transforms have been used for a long time as a way to change the solution of differential equations into trivial algebraic manipulations or to provide alternate representations of signals and data. These techniques, while seemingly overshadowed by today's emphasis on digital analysis, still form an invaluable basis in the understanding of systems and circuits. A firm grasp of the practical aspects of these subjects provides valuable conceptual tools. This tutorial paper is a review of Laplace and Fourier Transforms from an applied perspective with an emphasis on engineering applications. The interrelationship of the time and frequency domains will be stressed, in an attempt to comfort those who, after living so much of their lives in the time domain, find thinking in the frequency domain disquieting
Complete way to fractionalize Fourier transform
Yeung, Daniel S.; Ran, Qiwen; Tsang, Eric C. C.; Teo, Kok Lay
2004-01-01
We propose a complete way to fractionalize Fourier transform. This fractionalization can perfectly extend the fractional Fourier transform (FRFT) defined in [C.C. Shih, Opt. Commun. 118 (1995) 495] to the original one in [V. Namias, J. Inst. Math. Appl. 25 (1980) 241]. The new FRFT proposed in this paper can have any integer M(⩾3)-periodic eigenvalues not only with respect to the order of Hermite-Gaussian functions but also to the order of the transform, and it will be reduced to the FRFT in [Namias, loc. cit.; Shih, loc. cit.; S. Liu, J. Jiang, Y. Zhang, J. Zhang, J. Phys. A: Math. Gen. 30 (1997) 973] at the three limits with M=+∞, M=4, M=4 k ( k is a natural number), respectively.
Generalized Fourier transforms Fk,a
DEFF Research Database (Denmark)
Salem, Ben Said; Kobayashi, Toshiyuki; Ørsted, Bent
2009-01-01
We construct a two-parameter family of actions ωk,a of the Lie algebra by differential-difference operators on . Here, k is a multiplicity-function for the Dunkl operators, and a>0 arises from the interpolation of the Weil representation and the minimal unitary representation of the conformal gro...... of our semigroup Ωk,a provides us with (k,a) -generalized Fourier transforms , which includes the Dunkl transform ( a=2 ) and a new unitary operator ( a=1 ) as a Dunkl-type generalization of the classical Hankel transform....
Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR.
Perkins, W. D.
1987-01-01
This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)
Realization of quantum Fourier transform over ZN
International Nuclear Information System (INIS)
Fu Xiang-Qun; Bao Wan-Su; Li Fa-Da; Zhang Yu-Chao
2014-01-01
Since the difficulty in preparing the equal superposition state of amplitude is 1/√N, we construct a quantile transform of quantum Fourier transform (QFT) over Z N based on the elementary transforms, such as Hadamard transform and Pauli transform. The QFT over Z N can then be realized by the quantile transform, and used to further design its quantum circuit and analyze the requirements for the quantum register and quantum gates. However, the transform needs considerable quantum computational resources and it is difficult to construct a high-dimensional quantum register. Hence, we investigate the design of t-bit quantile transform, and introduce the definition of t-bit semiclassical QFT over Z N . According to probability amplitude, we prove that the transform can be used to realize QFT over Z N and further design its quantum circuit. For this transform, the requirements for the quantum register, the one-qubit gate, and two-qubit gate reduce obviously when compared with those for the QFT over Z N . (general)
Fourier Transform Fabry-Perot Interferometer
Snell, Hilary E.; Hays, Paul B.
1992-01-01
We are developing a compact, rugged, high-resolution remote sensing instrument with wide spectral scanning capabilities. This relatively new type of instrument, which we have chosen to call the Fourier-Transform Fabry-Perot Interferometer (FT-FPI), is accomplished by mechanically scanning the etalon plates of a Fabry-Perot interferometer (FPI) through a large optical distance while examining the concomitant signal with a Fourier-transform analysis technique similar to that employed by the Michelson interferometer. The FT-FPI will be used initially as a ground-based instrument to study near-infrared atmospheric absorption lines of trace gases using the techniques of solar absorption spectroscopy. Future plans include modifications to allow for measurements of trace gases in the stratosphere using spectral lines at terahertz frequencies.
On nonlinear Fourier transform: towards the nonlinear superposition
Saksida, Pavle
2017-01-01
In the paper we consider the nonlinear Fourier transform associated to the AKNSZS systems. In particular, we discuss the construction of the nonlinear Fourier modes of this transform by means of a perturbation scheme. The linearization of the AKNS-ZS nonlinear Fourier transform is the usual, linear Fourier transform and the linearization of a nonlinear Fourier mode of frequency d is the linear Fourier mode of the same frequency. We show that the first non-trivial term in the perturbation expression of any nonlinear Fourier mode is given by the dilogarithm function.
Fourier Transform Spectrometer Controller for Partitioned Architectures
DEFF Research Database (Denmark)
Tamas-Selicean, Domitian; Keymeulen, D.; Berisford, D.
2013-01-01
The current trend in spacecraft computing is to integrate applications of different criticality levels on the same platform using no separation. This approach increases the complexity of the development, verification and integration processes, with an impact on the whole system life cycle. Resear......, such as avionics and automotive. In this paper we investigate the challenges of developing and the benefits of integrating a scientific instrument, namely a Fourier Transform Spectrometer, in such a partitioned architecture....
(Anti)symmetric multivariate exponential functions and corresponding Fourier transforms
International Nuclear Information System (INIS)
Klimyk, A U; Patera, J
2007-01-01
We define and study symmetrized and antisymmetrized multivariate exponential functions. They are defined as determinants and antideterminants of matrices whose entries are exponential functions of one variable. These functions are eigenfunctions of the Laplace operator on the corresponding fundamental domains satisfying certain boundary conditions. To symmetric and antisymmetric multivariate exponential functions there correspond Fourier transforms. There are three types of such Fourier transforms: expansions into the corresponding Fourier series, integral Fourier transforms and multivariate finite Fourier transforms. Eigenfunctions of the integral Fourier transforms are found
Fourier transform of momentum distribution in vanadium
International Nuclear Information System (INIS)
Singh, A.K.; Manuel, A.A.; Peter, M.; Singru, R.M.
1985-01-01
Experimental Compton profile and 2D-angular correlation of positron annihilation radiation data from vanadium are analyzed by the mean of their Fourier transform. They are compared with the functions calculated with the help of both the linear muffin-tin orbital and the Hubbard-Mijnarends band structure methods. The results show that the functions are influenced by the positron wave function, by the e + -e - many-body correlations and by the differences in the electron wave functions used for the band structure calculations. It is concluded that Fourier analysis is a sensitive approach to investigate the momentum distributions in transition metals and to understnad the effects of the positron. (Auth.)
Laser Field Imaging Through Fourier Transform Heterodyne
Energy Technology Data Exchange (ETDEWEB)
Cooke, B.J.; Laubscher, B.E.; Olivas, N.L.; Galbraith, A.E.; Strauss, C.E.; Grubler, A.C.
1999-04-05
The authors present a detection process capable of directly imaging the transverse amplitude, phase, and Doppler shift of coherent electromagnetic fields. Based on coherent detection principles governing conventional heterodyned RADAR/LADAR systems, Fourier Transform Heterodyne incorporates transverse spatial encoding of the reference local oscillator for image capture. Appropriate selection of spatial encoding functions allows image retrieval by way of classic Fourier manipulations. Of practical interest: (1) imaging may be accomplished with a single element detector/sensor requiring no additional scanning or moving components, (2) as detection is governed by heterodyne principles, near quantum limited performance is achievable, (3) a wide variety of appropriate spatial encoding functions exist that may be adaptively configured in real-time for applications requiring optimal detection, and (4) the concept is general with the applicable electromagnetic spectrum encompassing the RF through optical.
Fourier transform infrared spectroscopy of peptides.
Bakshi, Kunal; Liyanage, Mangala R; Volkin, David B; Middaugh, C Russell
2014-01-01
Fourier transform infrared (FTIR) spectroscopy provides data that are widely used for secondary structure characterization of peptides. A wide array of available sampling methods permits structural analysis of peptides in diverse environments such as aqueous solution (including optically turbid media), powders, detergent micelles, and lipid bilayers. In some cases, side chain vibrations can also be resolved and used for tertiary structure and chemical analysis. Data from several low-resolution spectroscopic techniques, including FTIR, can be combined to generate an empirical phase diagram, an overall picture of peptide structure as a function of environmental conditions that can aid in the global interpretation of large amounts of spectroscopic data.
Doppler-free Fourier transform spectroscopy.
Meek, Samuel A; Hipke, Arthur; Guelachvili, Guy; Hänsch, Theodor W; Picqué, Nathalie
2018-01-01
Sub-Doppler broadband multi-heterodyne spectroscopy is proposed and experimentally demonstrated. Using two laser frequency combs of slightly different repetition frequencies, we have recorded Doppler-free two-photon dual-comb spectra of atomic rubidium resonances of a width of 6 MHz, while simultaneously interrogating a spectral span of 10 THz. The atomic transitions are uniquely identified via the intensity modulation of the observed fluorescence radiation. To the best of our knowledge, these results represent the first demonstration of Doppler-free Fourier transform spectroscopy and extend the range of applications of broadband spectroscopy towards precision nonlinear spectroscopy.
Fourier transforms in the complex domain
Wiener, N
1934-01-01
With the aid of Fourier-Mellin transforms as a tool in analysis, the authors were able to attack such diverse analytic questions as those of quasi-analytic functions, Mercer's theorem on summability, Milne's integral equation of radiative equilibrium, the theorems of MÃ¼nz and SzÃ¡sz concerning the closure of sets of powers of an argument, Titchmarsh's theory of entire functions of semi-exponential type with real negative zeros, trigonometric interpolation and developments in polynomials of the form \\sum^N_1A_ne^{i\\lambda_nx}, lacunary series, generalized harmonic analysis in the complex domain,
Analysis method for Fourier transform spectroscopy
Park, J. H.
1983-01-01
A fast Fourier transform technique is given for the simulation of those distortion effects in the instrument line shape of the interferometric spectrum that are due to errors in the measured interferogram. The technique is applied to analyses of atmospheric absorption spectra and laboratory spectra. It is shown that the nonlinear least squares method can retrieve the correct information from the distorted spectrum. Analyses of HF absorption spectra obtained in a laboratory and solar CO absorption spectra gathered by a balloon-borne interferometer indicate that the retrieved amount of absorbing gas is less than the correct value in most cases, if the interferogram distortion effects are not included in the analysis.
Analog fourier transform channelizer and OFDM receiver
2007-01-01
An OFDM receiver having an analog multiplier based I-Q channelizing filter, samples and holds consecutive analog I-Q samples of an I-Q baseband, the I-Q basebands having OFDM sub-channels. A lattice of analog I-Q multipliers and analog I-Q summers concurrently receives the held analog I-Q samples, performs analog I-Q multiplications and analog I-Q additions to concurrently generate a plurality of analog I-Q output signals, representing an N-point discrete Fourier transform of the held analog ...
Alternating multivariate trigonometric functions and corresponding Fourier transforms
International Nuclear Information System (INIS)
Klimyk, A U; Patera, J
2008-01-01
We define and study multivariate sine and cosine functions, symmetric with respect to the alternating group A n , which is a subgroup of the permutation (symmetric) group S n . These functions are eigenfunctions of the Laplace operator. They determine Fourier-type transforms. There exist three types of such transforms: expansions into corresponding sine-Fourier and cosine-Fourier series, integral sine-Fourier and cosine-Fourier transforms, and multivariate finite sine and cosine transforms. In all these transforms, alternating multivariate sine and cosine functions are used as a kernel
Two-dimensional fourier transform spectrometer
DeFlores, Lauren; Tokmakoff, Andrei
2013-09-03
The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.
The Fourier transform of tubular densities
Prior, C B
2012-05-18
We consider the Fourier transform of tubular volume densities, with arbitrary axial geometry and (possibly) twisted internal structure. This density can be used to represent, among others, magnetic flux or the electron density of biopolymer molecules. We consider tubes of both finite radii and unrestricted radius. When there is overlap of the tube structure the net density is calculated using the super-position principle. The Fourier transform of this density is composed of two expressions, one for which the radius of the tube is less than the curvature of the axis and one for which the radius is greater (which must have density overlap). This expression can accommodate an asymmetric density distribution and a tube structure which has non-uniform twisting. In addition we give several simpler expressions for isotropic densities, densities of finite radius, densities which decay at a rate sufficient to minimize local overlap and finally individual surfaces of the tube manifold. These simplified cases can often be expressed as arclength integrals and can be evaluated using a system of first-order ODEs. © 2012 IOP Publishing Ltd.
Fourier Transforms Simplified: Computing an Infrared Spectrum from an Interferogram
Hanley, Quentin S.
2012-01-01
Fourier transforms are used widely in chemistry and allied sciences. Examples include infrared, nuclear magnetic resonance, and mass spectroscopies. A thorough understanding of Fourier methods assists the understanding of microscopy, X-ray diffraction, and diffraction gratings. The theory of Fourier transforms has been presented in this "Journal",…
Multicomplementary operators via finite Fourier transform
International Nuclear Information System (INIS)
Klimov, Andrei B; Sanchez-Soto, Luis L; Guise, Hubert de
2005-01-01
A complete set of d + 1 mutually unbiased bases exists in a Hilbert space of dimension d, whenever d is a power of a prime. We discuss a simple construction of d + 1 disjoint classes (each one having d - 1 commuting operators) such that the corresponding eigenstates form sets of unbiased bases. Such a construction works properly for prime dimension. We investigate an alternative construction in which the real numbers that label the classes are replaced by a finite field having d elements. One of these classes is diagonal, and can be mapped to cyclic operators by means of the finite Fourier transform, which allows one to understand complementarity in a similar way as for the position-momentum pair in standard quantum mechanics. The relevant examples of two and three qubits and two qutrits are discussed in detail
Ion cyclotron resonance spectrometer with fourier transformation
International Nuclear Information System (INIS)
Pikver, R.; Suurmaa, Eh.; Syugis, A.; Tammik, A.; Lippmaa, Eh.
1983-01-01
The ion cyclotron resonance spectrometer with Fourier transformation intended for investigating mass specta and chemical reaction kinetics in the gaseous phase is described. The mass-spectrum of CO and N 2 positive ions is shown. The spectrometer consists of an electromagnet with power supply, a vacuum system, a cell with electronic equipment and a minicomputer. In the vacuum system (5x10 -9 Torr) there is a cubic measuring cell heated up to 400 deg C. The spectrometer mass resolution is of the 10 5 order. The spectrometer is able to operate as a high-resolution analytical mass-spectrometer of positive and negative ions. The experience of the spectrometer operation confirms its effectiveness for investigating ion-molecular reactions, in particular, proton transfer reactions
Geometric interpretations of the Discrete Fourier Transform (DFT)
Campbell, C. W.
1984-01-01
One, two, and three dimensional Discrete Fourier Transforms (DFT) and geometric interpretations of their periodicities are presented. These operators are examined for their relationship with the two sided, continuous Fourier transform. Discrete or continuous transforms of real functions have certain symmetry properties. The symmetries are examined for the one, two, and three dimensional cases. Extension to higher dimension is straight forward.
Cornut, I.; Desbat, B.; Turlet, J.M.; Dufourcq, J.
1996-01-01
Free amphipathic peptides and peptides bound to dimyristoylphosphatidylcholine (DMPC) were studied directly at the air/water interface using polarization modulation infrared reflection absorption spectroscopy (PMIRRAS). Such differential reflectivity measurements proved to be a sensitive and efficient technique to investigate in situ the respective conformations and orientations of lipid and peptide molecules in pure and mixed films. Data obtained for melittin, a natural hemolytic peptide, ar...
Fourier transform and its application to 1D and 2D NMR
International Nuclear Information System (INIS)
Canet, D.
1988-01-01
In this review article, the following points are developed: Pulsed NMR and Fourier transform; Fourier transform and two-dimensional spectroscopy; Mathematical properties of Fourier transform; Fourier transform of a sine function- one dimensional NMR; Fourier transform of a product of sine functions - two-dimensional NMR; Data manipulations in the time domain; Numerical Fourier transform [fr
Fourier transform spectroscopy of semiconductor materials
International Nuclear Information System (INIS)
Jonak-Auer, I.
1996-11-01
In order to determine the type of charge carriers, i.e. electrons or holes, participating in optical transitions, cyclotron resonance experiments using circularly polarized radiation were performed on strained-layer [111]-oriented InGaAs/(Al)GaAs multiple quantum wells and on a [100]-oriented InAs/GaSb double-heterostructure. Because of the rather complicated band-structures of these samples it is a priori unknown which carriers take part in transitions. The measurements yield the surprising result, that for the InGaAs/GaAs multiple quantum well the experimentally observed cyclotron resonance appears in the electron-active polarization in the frequency-regime of the Far Infrared (FIR), but in the hole-active polarization in the range of millimeter waves, whereas for the InGaAs/AlGaAs sample the resonance is caused by holes also in the FIR. Since by theoretical considerations the possibility of electrons causing the FIR cyclotron resonance could be excluded, the measurements are interpreted as being caused by holes due to broken selection rules. In the InAs/GaSb sample hole cyclotron resonance could for the first time be measured on a double-heterostructure. As for the application oriented measurements, they comprised a study of the hydrogen content of amorphous silicon nitride layers, and were performed in collaboration with Austria Mikro Systeme International AG. Fourier spectroscopy is a fast and non-destructive means for determining impurity concentrations. Radiation in the Mid Infrared regime stimulates N-H and Si-H stretching vibrations which lead to absorption peaks and can directly be attributed to the hydrogen concentration via calibration factors taken from the literature. In comparison with recommended procedures in the literature, a much higher accuracy in determining the areas of the absorption peaks could be gained in the course of this thesis by a proper polynomial fit of the background spectrum outside the absorption lines. The hydrogen content of
Unsal, E; Nugay, I I; Offenbach, I; Gross, M; Manning, C; Cakmak, M
2013-07-01
The design and performance of a multisensory instrument to track physical and chemical changes of thin polymer films (typically 5 μm stretching direction, received by detector unit. This design allows to analyze both polarizations simultaneously wavenumbers in the range of 500 cm(-1)-4000 cm(-1). Controlled processing parameters include air speed, air temperature, stretching rate, stretching ratio, stretch cycling, and holding times; while simultaneously measuring optical retardation, sample width, temperature, load cell, and both parallel and perpendicular IR spectra. Calibration and performance of this instrument is demonstrated with several film samples. These are: A polystyrene standard, an atactic polystyrene (homo-polymer), a polyurethane (consists of hard and soft segments) for physical changes during uniaxial deformation, and a polyamic acid during imidization reaction. This measurement system is particularly useful in unraveling molecular level details of complex physical and chemical events that take place during very fast deformation schemes (uniaxial stretching, retraction, relaxation, annealing, etc.) relevant to industrial processes. These include specific orientation behavior of each phase, block or filler, crystallization, relaxation and orientation state. It is also suited to track reaction rates and products in polymers undergoing thermal or photo curing.
Fourier transform spectroscopy for future planetary missions
Brasunas, John C.; Hewagama, Tilak; Kolasinski, John R.; Kostiuk, Theodor
2015-11-01
Thermal-emission infrared spectroscopy is a powerful tool for exploring the composition, temperature structure, and dynamics of planetary atmospheres; and the temperature of solid surfaces. A host of Fourier transform spectrometers (FTS) such as Mariner IRIS, Voyager IRIS, and Cassini CIRS from NASA Goddard have made and continue to make important new discoveries throughout the solar system.Future FTS instruments will have to be more sensitive (when we concentrate on the colder, outer reaches of the solar system), and less massive and less power-hungry as we cope with decreasing resource allotments for future planetary science instruments. With this in mind, NASA Goddard was funded via the Planetary Instrument Definition and Development Progrem (PIDDP) to develop CIRS-lite, a smaller version of the CIRS FTS for future planetary missions. Following the initial validation of CIRS-lite operation in the laboratory, we have been acquiring atmospheric data in the 8-12 micron window at the 1.2 m telescope at the Goddard Geophysical and Astronomical Observatory (GGAO) in Greenbelt, MD. Targets so far have included Earth's atmosphere (in emission, and in absorption against the moon), and Venus.We will present the roadmap for making CIRS-lite a viable candidate for future planetary missions.
The Fourier Transform for Certain HyperKähler Fourfolds
Shen, M.; Vial, C.
2016-01-01
Using a codimension-1 algebraic cycle obtained from the Poincaré line bundle, Beauville defined the Fourier transform on the Chow groups of an abelian variety A and showed that the Fourier transform induces a decomposition of the Chow ring CH∗(A). By using a codimension-2 algebraic cycle
Fourier transform in multimode systems in the Bargmann representation
International Nuclear Information System (INIS)
Lei, C; Vourdas, A
2007-01-01
A Fourier transform in a multimode system is studied, using the Bargmann representation. The growth of a Bargmann function is shown to be related to the second-order correlation of the corresponding state. Both the total growth and the total second-order correlation remain unchanged under the Fourier transform. Examples with coherent states, squeezed states and Mittag-Leffler states are discussed
Fourier transform n.m.r. spectroscopy
International Nuclear Information System (INIS)
Shaw, D.
1976-01-01
This book is orientated to techniques rather than applications. The basic theory of n.m.r. is dealt with in a unified approach to the Fourier theory. The middle section of the book concentrates on the practical aspects of Fourier n.m.r., both instrumental and experimental. The final chapters briefly cover general application of n.m.r., but concentrate strongly on those areas where Fourier n.m.r. can give information which is not available by conventional techniques
The relationship between shock response spectrum and fast Fourier transform
International Nuclear Information System (INIS)
Zola, Maurizio
2001-01-01
In this paper the basic relationship between response spectrum and fast Fourier transform is laid down. Since a long time the response spectrum has been used by structural engineers in the seismic domain and nowadays it is going to be used to define transient motions. This way to define the excitation is more general and more real than the use of classical shape pulses for the reproduction of real environment. Nevertheless the response spectrum of a real excitation represents a loss of some information with respect to the Fourier transform. A useful discussion could arise from these observations. Appendix A gives the relationship between the mathematic Fourier transform and the digital Fourier transform given by computers, while Appendix B gives some examples of response spectra and Fourier transforms of simple functions. (author)
Cryogenic Scan Mechanism for Fourier Transform Spectrometer
Brasunas, John C.; Francis, John L.
2011-01-01
A compact and lightweight mechanism has been developed to accurately move a Fourier transform spectrometer (FTS) scan mirror (a cube corner) in a near-linear fashion with near constant speed at cryogenic temperatures. This innovation includes a slide mechanism to restrict motion to one dimension, an actuator to drive the motion, and a linear velocity transducer (LVT) to measure the speed. The cube corner mirror is double-passed in one arm of the FTS; double-passing is required to compensate for optical beam shear resulting from tilting of the moving cube corner. The slide, actuator, and LVT are off-the-shelf components that are capable of cryogenic vacuum operation. The actuator drives the slide for the required travel of 2.5 cm. The LVT measures translation speed. A proportional feedback loop compares the LVT voltage with the set voltage (speed) to derive an error signal to drive the actuator and achieve near constant speed. When the end of the scan is reached, a personal computer reverses the set voltage. The actuator and LVT have no moving parts in contact, and have magnetic properties consistent with cryogenic operation. The unlubricated slide restricts motion to linear travel, using crossed roller bearings consistent with 100-million- stroke operation. The mechanism tilts several arc seconds during transport of the FTS mirror, which would compromise optical fringe efficiency when using a flat mirror. Consequently, a cube corner mirror is used, which converts a tilt into a shear. The sheared beam strikes (at normal incidence) a flat mirror at the end of the FTS arm with the moving mechanism, thereby returning upon itself and compensating for the shear
Fourier Transform Mass Spectrometry: The Transformation of Modern Environmental Analyses
Directory of Open Access Journals (Sweden)
Lucy Lim
2016-01-01
Full Text Available Unknown compounds in environmental samples are difficult to identify using standard mass spectrometric methods. Fourier transform mass spectrometry (FTMS has revolutionized how environmental analyses are performed. With its unsurpassed mass accuracy, high resolution and sensitivity, researchers now have a tool for difficult and complex environmental analyses. Two features of FTMS are responsible for changing the face of how complex analyses are accomplished. First is the ability to quickly and with high mass accuracy determine the presence of unknown chemical residues in samples. For years, the field has been limited by mass spectrometric methods that were based on knowing what compounds of interest were. Secondly, by utilizing the high resolution capabilities coupled with the low detection limits of FTMS, analysts also could dilute the sample sufficiently to minimize the ionization changes from varied matrices.
Fourier Transform Mass Spectrometry: The Transformation of Modern Environmental Analyses
Lim, Lucy; Yan, Fangzhi; Bach, Stephen; Pihakari, Katianna; Klein, David
2016-01-01
Unknown compounds in environmental samples are difficult to identify using standard mass spectrometric methods. Fourier transform mass spectrometry (FTMS) has revolutionized how environmental analyses are performed. With its unsurpassed mass accuracy, high resolution and sensitivity, researchers now have a tool for difficult and complex environmental analyses. Two features of FTMS are responsible for changing the face of how complex analyses are accomplished. First is the ability to quickly and with high mass accuracy determine the presence of unknown chemical residues in samples. For years, the field has been limited by mass spectrometric methods that were based on knowing what compounds of interest were. Secondly, by utilizing the high resolution capabilities coupled with the low detection limits of FTMS, analysts also could dilute the sample sufficiently to minimize the ionization changes from varied matrices. PMID:26784175
A discrete Fourier transform for virtual memory machines
Galant, David C.
1992-01-01
An algebraic theory of the Discrete Fourier Transform is developed in great detail. Examination of the details of the theory leads to a computationally efficient fast Fourier transform for the use on computers with virtual memory. Such an algorithm is of great use on modern desktop machines. A FORTRAN coded version of the algorithm is given for the case when the sequence of numbers to be transformed is a power of two.
Two-photon polarization Fourier spectroscopy of metastable atomic hydrogen
International Nuclear Information System (INIS)
Duncan, A.J.; Beyer, H.-J.; Kleinpoppen, H.; Sheikh, Z.A,; B-Z Univ., Multan
1997-01-01
A novel Fourier-transform spectroscopic method using two-photon polarization to determine the spectral distribution of the two photons emitted in the spontaneous decay of metastable atomic hydrogen is described. The method uses birefringent retardation plates and takes advantage of the subtle interplay between the spectral properties and the entangled polarization properties of the radiation emitted in the decay. Assuming the validity of the theoretical spectral distribution, it is shown that the experimental results agree well with theory. On the other hand, success in solving the inverse problem of determining the spectral distribution from the experimental results is limited by the small number of experimental points. However, making reasonable assumptions it is deduced that the observed spectrum is characterized by a broadband signal of width (0.43 ± 0.06) x 10 16 rad s -1 and centre angular frequency (0.77 ± 0.03) x 10 16 rad s -1 in good agreement with the predictions of 0.489 x 10 16 rad s -1 and 0.775 x 10 16 rad s -1 , respectively, obtained from the theoretical spectral distribution modified to take account of the absorption of the two-photon radiation in air. The values of 1.5 fs for the coherence time and 440 nm for the coherence length for single photons of the two-photon pair which are obtained from the measured bandwidth imply that, in the ideal case, these values are determined by the essentially zero lifetime of the virtual intermediate state of the decay process rather than the long lifetime of the metastable state which, it is suggested, determines the coherence time and coherence length appropriate to certain types of fourth-order interference experiments. (Author)
The morphing of geographical features by Fourier transformation.
Li, Jingzhong; Liu, Pengcheng; Yu, Wenhao; Cheng, Xiaoqiang
2018-01-01
This paper presents a morphing model of vector geographical data based on Fourier transformation. This model involves three main steps. They are conversion from vector data to Fourier series, generation of intermediate function by combination of the two Fourier series concerning a large scale and a small scale, and reverse conversion from combination function to vector data. By mirror processing, the model can also be used for morphing of linear features. Experimental results show that this method is sensitive to scale variations and it can be used for vector map features' continuous scale transformation. The efficiency of this model is linearly related to the point number of shape boundary and the interceptive value n of Fourier expansion. The effect of morphing by Fourier transformation is plausible and the efficiency of the algorithm is acceptable.
High Speed Countercurrent Chromatography/Fourier Transform Infrared (HSCCC/FT-IR) Spectrometry
Romanach, Rodolfo J.; de Haseth, James A.
1985-12-01
High Speed Countercurrent Chromatography/Fourier transform infrared (HSCCC/FT-IR) spectrometry is present-ed. High solute-to-solvent ratios can be obtained in separations performed using HSCCC. At these high solute concentrations it is possible to obtain spectra of solutes without solvent elimination, even in the presence of polar solvents, such as water and methanol.
Fourier transforms of Dini-Lipschitz functions on Vilenkin groups
Directory of Open Access Journals (Sweden)
M. S. Younis
1992-01-01
Full Text Available In [4] we proved some theorems on the Fourier Transforms of functions satisfying conditions related to the Dini-Lipschitz conditions on the n-dimensional Euclidean space Rn and the torus group Tn. In this paper we extend those theorems for functions with Fourier series on Vilenkin groups.
Song, Xinbing; Sun, Yifan; Li, Pengyun; Qin, Hongwei; Zhang, Xiangdong
2015-01-01
We perform Bell’s measurement for the non-separable correlation between polarization and orbital angular momentum from the same classical vortex beam. The violation of Bell’s inequality for such a non-separable classical correlation has been demonstrated experimentally. Based on the classical vortex beam and non-quantum entanglement between the polarization and the orbital angular momentum, the Hadamard gates and conditional phase gates have been designed. Furthermore, a quantum Fourier transform has been implemented experimentally. PMID:26369424
Surface Fourier-transform lens using a metasurface
International Nuclear Information System (INIS)
Li, Yun Bo; Cai, Ben Geng; Cheng, Qiang; Cui, Tie Jun
2015-01-01
We propose a surface (or 2D) Fourier-transform lens using a gradient refractive index (GRIN) metasurface in the microwave band, which is composed of sub-wavelength quasi-periodical metallic patches on a grounded dielectric substrate. Such a metasurface supports the transverse magnetic (TM) modes of surface waves. To gradually change the size of textures, we obtain different surface refractive indices, which can be tailored to fit the required refractive-index profile of a surface Fourier-transform lens. According to the theory of spatial Fourier transformation, we make use of the proposed lens to realize surface plane-wave scanning under different feeding locations. The simulation and experimental results jointly confirm the validity of the surface Fourier-transform lens. The proposed method can also be extended to the terahertz frequency. (paper)
On the physical relevance of the discrete Fourier transform
CSIR Research Space (South Africa)
Greben, JM
1991-11-01
Full Text Available This paper originated from the author's dissatisfaction with the way the discrete Fourier transform is usually presented in the literature. Although mathematically correct, the physical meaning of the common representation is unsatisfactory...
Electro-Optic Imaging Fourier Transform Spectral Polarimeter, Phase I
National Aeronautics and Space Administration — Boulder Nonlinear Systems, Inc. (BNS) proposes to develop an Electro-Optic Imaging Fourier Transform Spectral Polarimeter (E-O IFTSP). The polarimetric system is...
A fourier transform quality measure for iris images
CSIR Research Space (South Africa)
Makinana, S
2014-08-01
Full Text Available to ensure that good quality images are selected for feature extraction, in order to improve iris recognition system. In addition, this research proposes a measure of iris image quality using a Fourier Transform. The experimental results demonstrate...
Simple optical setup implementation for digital Fourier transform holography
International Nuclear Information System (INIS)
De Oliveira, G N; Rodrigues, D M C; Dos Santos, P A M
2011-01-01
In the present work a simple implementation of Digital Fourier Transform Holography (DFTH) setup is discussed. This is obtained making a very simple modification in the classical setup arquiteture of the Fourier Transform holography. It is also demonstrated the easy and practical viability of the setup in an interferometric application for mechanical parameters determination. The work is also proposed as an interesting advanced introductory training for graduated students in digital holography.
Estimation of Large Scalings in Images Based on Multilayer Pseudopolar Fractional Fourier Transform
Directory of Open Access Journals (Sweden)
Zhenhong Li
2013-01-01
Full Text Available Accurate estimation of the Fourier transform in log-polar coordinates is a major challenge for phase-correlation based motion estimation. To acquire better image registration accuracy, a method is proposed to estimate the log-polar coordinates coefficients using multilayer pseudopolar fractional Fourier transform (MPFFT. The MPFFT approach encompasses pseudopolar and multilayer techniques and provides a grid which is geometrically similar to the log-polar grid. At low coordinates coefficients the multilayer pseudopolar grid is dense, and at high coordinates coefficients the grid is sparse. As a result, large scalings in images can be estimated, and better image registration accuracy can be achieved. Experimental results demonstrate the effectiveness of the presented method.
Birefringent static Fourier-transform spectrometer for flow cytometry and imaging spectroscopy.
Hegyi, Alex
2017-07-24
A new concept for a birefringent static Fourier-transform spectrometer, applicable to both spectral flow cytometry and hyperspectral imaging, is introduced. Biological particles or scenes in relative motion are imaged onto a polarization interferometer consisting of a calcite Wollaston prism between crossed polarizers, with polarization axes at 45° with respect to the optical axes of the Wollaston prism. Due to the position-dependent optical path delay of the interferometer, interferograms are generated by the relative motion. These interferograms are recorded either by a flow cytometer detector, or in the case of hyperspectral imaging, by a CMOS focal plane array. Fourier-transforming the interferograms with respect to time yields the optical spectrum of each particle or scene position. The concept has applicability to situations where linear motion is already present, including flow cytometers, conveyor belt systems, fixed-wing aircraft, and nanosatellites.
Properties of the Simpson discrete fourier transform | Singh ...
African Journals Online (AJOL)
The Simpson discrete Fourier transform (SDFT) and its inverse are transformations relating the time and frequency domains. In this paper we state and prove the important properties of shift, circular convolution, conjugation, time reversal and Plancherel's theorem. In addition, we provide an alternative representation of the ...
Fixed-point error analysis of Winograd Fourier transform algorithms
Patterson, R. W.; Mcclellan, J. H.
1978-01-01
The quantization error introduced by the Winograd Fourier transform algorithm (WFTA) when implemented in fixed-point arithmetic is studied and compared with that of the fast Fourier transform (FFT). The effect of ordering the computational modules and the relative contributions of data quantization error and coefficient quantization error are determined. In addition, the quantization error introduced by the Good-Winograd (GW) algorithm, which uses Good's prime-factor decomposition for the discrete Fourier transform (DFT) together with Winograd's short length DFT algorithms, is studied. Error introduced by the WFTA is, in all cases, worse than that of the FFT. In general, the WFTA requires one or two more bits for data representation to give an error similar to that of the FFT. Error introduced by the GW algorithm is approximately the same as that of the FFT.
Special affine Fourier transformation in frequency-domain
Cai, L. Z.
2000-11-01
Special affine Fourier transformation (SAFT) can be considered as an extension of the fractional Fourier transformation (FRT) and the most general linear mapping in phase space. A general formula for SAFT in frequency-domain is derived, which gives a direct relationship between the input and output spatial frequency spectra of a light field. It shows that the SAFT has similar and symmetric feature in both space- and frequency-domains. As its special cases, Collins formula in frequency-domain, the spatial frequency representations of the almost-FRT, almost-Fresnel and almost-Fourier transformations are explicitly obtained. These formulae may provide a tool for investigating the performance of a lossless optical system including small deformations in both domains in a unified way within the framework of linear theory.
International Nuclear Information System (INIS)
Rodriguez G, A.; Bowtell, R.; Mansfield, P.
1998-01-01
Velocity maps were studied combining Doyle and Mansfield method (1986) with each of the following transforms: Fourier, window Fourier and wavelet (Mexican hat). Continuous wavelet transform was compared against the two Fourier transform to determine which technique is best suited to study blood maps generated by Half Fourier Echo-Planar Imaging. Coefficient images were calculated and plots of the pixel intensity variation are presented. Finally, contour maps are shown to visualize the behavior of the blood flow in the cardiac chambers for the wavelet technique. (Author)
Energy Technology Data Exchange (ETDEWEB)
Rodriguez G, A.; Bowtell, R.; Mansfield, P. [Area de Procesamiento Digital de Senales e Imagenes Biomedicas. Universidad Autonoma Metropolitana Iztapalapa. Mexico D.F. 09340 Mexico (Mexico)
1998-12-31
Velocity maps were studied combining Doyle and Mansfield method (1986) with each of the following transforms: Fourier, window Fourier and wavelet (Mexican hat). Continuous wavelet transform was compared against the two Fourier transform to determine which technique is best suited to study blood maps generated by Half Fourier Echo-Planar Imaging. Coefficient images were calculated and plots of the pixel intensity variation are presented. Finally, contour maps are shown to visualize the behavior of the blood flow in the cardiac chambers for the wavelet technique. (Author)
Fourier transform infrared spectra applications to chemical systems
Ferraro, John R
1985-01-01
The final and largest volume to complete this four-volume treatise is published in response to the intense commercial and research interest in Fourier Transform Interferometry.Presenting current information from leading experts in the field, Volume 4 introduces new information on, for example, applications of Diffuse Reflectance Spectroscopy in the Far-Infrared Region. The editors place emphasis on surface studies and address advances in Capillary Gas Chromatography - Fourier Transform Interferometry.Volume 4 especially benefits spectroscopists and physicists, as well as researchers
Quantitative aspects of near-infrared Fourier transform Raman spectroscopy
Walder, F. T.; Smith, M. J.
Three fundamental behaviors of vibrational spectroscopy data manipulation routinely associated with Fourier transform infrared (FTIR) spectroscopy are evaluated for near-infrared (NIR) Fourier transform Raman spectroscopy. Spectral reproducibility, spectral subtraction and sensitivity are examined relative to the NIR FT-Raman experiment. Quantitative predictive ability is compared for identical sets of samples containing mixtures of the three xylene isomers. Partial least-squares analysis is used to compare predictive ability. IR performance is found to be better than Raman, though the potential for method development using NIR FT-Raman is shown to be quite promising.
Neural network signature verification using Haar wavelet and Fourier transforms
McCormack, Daniel K. R.; Brown, B. M.; Pedersen, John F.
1993-08-01
This paper discusses the use of neural network's for handwritten signature verification using the Fourier and Haar wavelet transforms as methods of encoding signature images. Results will be presented that discuss a neural network's ability to generalize to unseen signatures using wavelet encoded training data. These results will be discussed with reference to both Backpropagation networks and Cascade-Correlation networks. Backpropagation and Cascade- Correlation networks are used to compare and contrast the generalization ability of Haar wavelet and Fourier transform encoded signature data.
Fourier transform infrared spectra applications to chemical systems
Ferraro, John R
1978-01-01
Fourier Transform Infrared Spectroscopy: Applications to Chemical Systems presents the chemical applications of the Fourier transform interferometry (FT-IR).The book contains discussions on the applications of FT-IR in the fields of chromatography FT-IR, polymers and biological macromolecules, emission spectroscopy, matrix isolation, high-pressure interferometry, and far infrared interferometry. The final chapter is devoted to the presentation of the use of FT-IR in solving national technical problems such as air pollution, space exploration, and energy related subjects.Researc
Discrete Fourier Transform in a Complex Vector Space
Dean, Bruce H. (Inventor)
2015-01-01
An image-based phase retrieval technique has been developed that can be used on board a space based iterative transformation system. Image-based wavefront sensing is computationally demanding due to the floating-point nature of the process. The discrete Fourier transform (DFT) calculation is presented in "diagonal" form. By diagonal we mean that a transformation of basis is introduced by an application of the similarity transform of linear algebra. The current method exploits the diagonal structure of the DFT in a special way, particularly when parts of the calculation do not have to be repeated at each iteration to converge to an acceptable solution in order to focus an image.
Discrete Fourier Transform Analysis in a Complex Vector Space
Dean, Bruce H.
2009-01-01
Alternative computational strategies for the Discrete Fourier Transform (DFT) have been developed using analysis of geometric manifolds. This approach provides a general framework for performing DFT calculations, and suggests a more efficient implementation of the DFT for applications using iterative transform methods, particularly phase retrieval. The DFT can thus be implemented using fewer operations when compared to the usual DFT counterpart. The software decreases the run time of the DFT in certain applications such as phase retrieval that iteratively call the DFT function. The algorithm exploits a special computational approach based on analysis of the DFT as a transformation in a complex vector space. As such, this approach has the potential to realize a DFT computation that approaches N operations versus Nlog(N) operations for the equivalent Fast Fourier Transform (FFT) calculation.
Fourier transform distribution function of relaxation times; application and limitations
Boukamp, Bernard A.
2015-01-01
A simple Fourier transform (FT) method is presented for obtaining a Distribution Function of Relaxation Times (DFRT) for electrochemical impedance spectroscopy (EIS) data. By using a special data extension procedure the FT is performed over the range from -∞ ≤ lnω ≤ + ∞. The integration procedure is
Fourier transform infrared spectroscopic estimation of crystallinity in ...
Indian Academy of Sciences (India)
Wintec
quartz in rock samples and estimate the mining quality of quartz mineral, which is substantiated by calculating the crystallinity index. ... procedure which can be used to estimate the distribution of quartz in various rocks for mining purpose. ... coal was reported by several workers (Heaney et al. 1994). Fourier transform ...
Coupling of column liquid chromatography and Fourier transform infrared spectrometry
Somsen, G.W; Gooijer, C; Velthorst, N.H; Brinkman, U.A Th
1998-01-01
This paper provides an extensive overview of the literature on the coupling of column liquid chromatography (LC) and Fourier transform infrared spectrometry (FT-IR). Flow-cell-based FT-IR detection and early solvent-elimination interfaces for LC-FT-IR are discussed in brief. A comprehensive
Dual beam encoded extended fractional Fourier transform security ...
Indian Academy of Sciences (India)
This paper describes a simple method for making dual beam encoded extended fractional Fourier transform (EFRT) security holograms. The hologram possesses different stages of encoding so that security features are concealed and remain invisible to the counterfeiter. These concealed and encoded anticounterfeit ...
Application of Migration Velocity Using Fourier Transform Approach ...
African Journals Online (AJOL)
Application of velocity by Fourier transform to process 3-D unmigrated seismic sections has been carried out in Fabi Field, Niger Delta – Nigeria. Usually, all seismic events (sections) are characterized by spikes or noise (random or coherent), multiples and shear waves so that when a seismic bed is dipping, the apparent ...
Fourier transform infrared spectroscopic estimation of crystallinity in ...
Indian Academy of Sciences (India)
Wintec
Fourier transform infrared spectroscopic estimation of crystallinity in SiO2 based rocks. BHASKAR J SAIKIA. †. , G PARTHASARATHY* and N C SARMAH. †. National Geophysical Research Institute, Council of Scientific and Industrial Research, Hyderabad 500 007, India. †. Department of Physics, Dibrugarh University, ...
Fourier transformation methods in the field of gamma spectrometry
Indian Academy of Sciences (India)
The basic principles of a new version of Fourier transformation is presented. This new version was applied to solve some main problems such as smoothing, and denoising in gamma spectroscopy. The mathematical procedures were first tested by simulated data and then by actual experimental data.
Fourier transform infrared microspectroscopy as a diagnostic tool for ...
Indian Academy of Sciences (India)
Fourier transform infrared (FTIR) microspectroscopy can be considered to be a fast and non-invasive tool for distinguishing between normal and cancerous cells and tissues without the need for laborious and invasive sampling procedures. Gastric samples from four patients (age, 65±2 years) were analysed. Samples were ...
The RC Circuit: An Approach with Fourier Transforms
Indian Academy of Sciences (India)
In this article we shall mathematically analyse the Resistor-Capacitor (RC) circuit with the help of Fourier transforms(FT). This very general technique gives us a lot of insight intosolving first order differential equations with source terms dependingon time. In itself, the RC circuit is by far the mostcommonplace entity in modern ...
Fourier transform infrared spectrophotometry and X-ray powder ...
African Journals Online (AJOL)
This study aimed at demonstrating complementary roles offered by both Fourier transform infrared (FTIR) spectrophotometry and x-ray powder diffraction (XRPD) techniques in characterizing clay size fraction of kaolins. The clay size fraction of kaolin samples obtained from Kgwakgwe, Makoro, Lobatse and Serule kaolin ...
Fourier transform infrared (FTIR) spectroscopy for identification of ...
African Journals Online (AJOL)
Fourier transform infrared (FTIR) spectroscopy was used in this study to identify and determine spectral features of Chlorella vulgaris Beijerinck 1890 and Scenedesmus obliquus (Turpin) Kützing 1833. Two cultures were grown in a chemically-defined media under photoautotrophic culture conditions isolated from eutrophic ...
Fourier-transform Infrared Characterization of Kaolin, Granite ...
African Journals Online (AJOL)
Fourier-transform Infrared Characterization of Kaolin, Granite, Bentonite and Barite. ... Diazonium salts at the peak region frequency of 3200-3100cm-1, organic substance at peak region of 2900-2700cm-1, by comparing the spectra obtained with those ... Keywords: characterization; clays; infrared; minerals; spectroscopy ...
Dual beam encoded extended fractional Fourier transform security ...
Indian Academy of Sciences (India)
Holograms; security holograms; optical security; extended fractional Fourier transforms. PACS Nos 42.40.-i; 42.40. ... cost-effective scheme for the development of security hologram, we noticed that two reference beams holography [10] can ..... couragement, support and for permission to publish this work. They wish to thank.
Transformation of a Free-Wilson matrix into Fourier coefficients
Czech Academy of Sciences Publication Activity Database
Holík, M.; Halámek, Josef
2002-01-01
Roč. 20, - (2002), s. 422 - 428 ISSN 0931-8771 Institutional research plan: CEZ:AV0Z2065902 Keywords : Free-Wilson matrix * Fourier transform * multivariate regression Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering Impact factor: 1.558, year: 2002
Construction of a pulsed nozzle fourier transform microwave ...
Indian Academy of Sciences (India)
Administrator
Construction of a pulsed nozzle fourier transform microwave spectrometer to study the lithium bond. A P TIWARI 1, B J MUKKADA 1, E ARUNAN 1 and P C MATHIAS 2. 1Department of Inorganic and Physical Chemistry, Indian Institute of. Science, Bangalore 560 012, India. 2Sophisticated Instruments Facility, Indian Institute ...
HEART ABNORMALITY CLASSIFICATIONS USING FOURIER TRANSFORMS METHOD AND NEURAL NETWORKS
Directory of Open Access Journals (Sweden)
Endah Purwanti
2014-05-01
Full Text Available Health problems with cardiovascular system disorder are still ranked high globally. One way to detect abnormalities in the cardiovascular system especially in the heart is through the electrocardiogram (ECG reading. However, reading ECG recording needs experience and expertise, software-based neural networks has designed to help identify any abnormalities ofthe heart through electrocardiogram digital image. This image is processed using image processing methods to obtain ordinate chart which representing the heart’s electrical potential. Feature extraction using Fourier transforms which are divided into several numbers of coefficients. As the software input, Fourier transforms coefficient have been normalized. Output of this software is divided into three classes, namely heart with atrial fibrillation, coronary heart disease and normal. Maximum accuracy rate ofthis software is 95.45%, with the distribution of the Fourier transform coefficients 1/8 and number of nodes 5, while minimum accuracy rate of this software at least 68.18% by distribution of the Fourier transform coefficients 1/32 and the number of nodes 32. Overall result accuracy rate of this software has an average of86.05% and standard deviation of7.82.
Quaternion Fourier transforms for signal and image processing
Ell, Todd A; Sangwine, Stephen J
2014-01-01
Based on updates to signal and image processing technology made in the last two decades, this text examines the most recent research results pertaining to Quaternion Fourier Transforms. QFT is a central component of processing color images and complex valued signals. The book's attention to mathematical concepts, imaging applications, and Matlab compatibility render it an irreplaceable resource for students, scientists, researchers, and engineers.
A functional program for the Fast Fourier Transform
Vries, F.-J. de
This paper is written as a contribution to the Parallel Reduction Machine Project. Its purpose is to present a functional program for a well-known application of the fundamental algorithmic method Fast Fourier Transform for multiplication of polynomials. This in order to verify experimentally two
Dual beam encoded extended fractional Fourier transform security ...
Indian Academy of Sciences (India)
Abstract. This paper describes a simple method for making dual beam encoded ex- tended fractional Fourier transform (EFRT) security holograms. The hologram possesses different stages of encoding so that security features are concealed and remain invisible to the counterfeiter. These concealed and encoded ...
Discrete fourier transform (DFT) analysis for applications using iterative transform methods
Dean, Bruce H. (Inventor)
2012-01-01
According to various embodiments, a method is provided for determining aberration data for an optical system. The method comprises collecting a data signal, and generating a pre-transformation algorithm. The data is pre-transformed by multiplying the data with the pre-transformation algorithm. A discrete Fourier transform of the pre-transformed data is performed in an iterative loop. The method further comprises back-transforming the data to generate aberration data.
Spectrums Transform Operators in Bases of Fourier and Walsh Functions
Directory of Open Access Journals (Sweden)
V. V. Syuzev
2017-01-01
Full Text Available The problems of synthesis of the efficient algorithms for digital processing of discrete signals require transforming the signal spectra from one basis system into other. The rational solution to this problem is to construct the Fourier kernel, which is a spectrum of some basis functions, according to the system of functions of the other basis. However, Fourier kernel properties are not equally studied and described for all basis systems of practical importance. The article sets a task and presents an original way to solve the problem of mutual transformation of trigonometric Fourier spectrum into Walsh spectrum of different basis systems.The relevance of this theoretical and applied problem is stipulated, on the one hand, by the prevalence of trigonometric Fourier basis for harmonic representation of digital signals, and, on the other hand, by the fact that Walsh basis systems allow us to have efficient algorithms to simulate signals. The problem solution is achieved through building the Fourier kernel of a special structure that allows us to establish independent groups of Fourier and Walsh spectrum coefficients for further reducing the computational complexity of the transform algorithms.The article analyzes the properties of the system of trigonometric Fourier functions and shows its completeness. Considers the Walsh function basis systems in three versions, namely those of Hadamard, Paley, and Hartmut giving different ordering and analytical descriptions of the functions that make up the basis. Proves a completeness of these systems.Sequentially, for each of the three Walsh systems the analytical curves for the Fourier kernel components are obtained, and Fourier kernel themselves are built with binary rational number of samples of basis functions. The kernels are presented in matrix form and, as an example, recorded for a particular value of the discrete interval of N, equal to 8. The analysis spectral coefficients of the Fourier kernel
Grimm, C. A.
This document contains two units that examine integral transforms and series expansions. In the first module, the user is expected to learn how to use the unified method presented to obtain Laplace transforms, Fourier transforms, complex Fourier series, real Fourier series, and half-range sine series for given piecewise continuous functions. In…
On the finite Fourier transforms of functions with infinite discontinuities
Directory of Open Access Journals (Sweden)
Branko Saric
2002-01-01
Full Text Available The introductory part of the paper is provided to give a brief review of the stability theory of a matrix pencil for discrete linear time-invariant singular control systems, based on the causal relationship between Jordan's theorem from the theory of Fourier series and Laurent's theorem from the calculus of residues. The main part is concerned with the theory of the integral transforms, which has proved to be a powerful tool in the control systems theory. On the basis of a newly defined notion of the total value of improper integrals, throughout the main part of the paper, an attempt has been made to present the global theory of the integral transforms, which are slightly more general with respect to the Laplace and Fourier transforms. The paper ends with examples by which the results of the theory are verified.
Limitations on continuous variable quantum algorithms with Fourier transforms
International Nuclear Information System (INIS)
Adcock, Mark R A; Hoeyer, Peter; Sanders, Barry C
2009-01-01
We study quantum algorithms implemented within a single harmonic oscillator, or equivalently within a single mode of the electromagnetic field. Logical states correspond to functions of the canonical position, and the Fourier transform to canonical momentum serves as the analogue of the Hadamard transform for this implementation. This continuous variable version of quantum information processing has widespread appeal because of advanced quantum optics technology that can create, manipulate and read Gaussian states of light. We show that, contrary to a previous claim, this implementation of quantum information processing has limitations due to a position-momentum trade-off of the Fourier transform, analogous to the famous time-bandwidth theorem of signal processing.
An introduction to Laplace transforms and Fourier series
Dyke, Phil
2014-01-01
Laplace transforms continue to be a very important tool for the engineer, physicist and applied mathematician. They are also now useful to financial, economic and biological modellers as these disciplines become more quantitative. Any problem that has underlying linearity and with solution based on initial values can be expressed as an appropriate differential equation and hence be solved using Laplace transforms. In this book, there is a strong emphasis on application with the necessary mathematical grounding. There are plenty of worked examples with all solutions provided. This enlarged new edition includes generalised Fourier series and a completely new chapter on wavelets. Only knowledge of elementary trigonometry and calculus are required as prerequisites. An Introduction to Laplace Transforms and Fourier Series will be useful for second and third year undergraduate students in engineering, physics or mathematics, as well as for graduates in any discipline such as financial mathematics, econometrics and ...
Zhang, Fang; Zhu, Jing; Song, Qiang; Yue, Weirui; Liu, Jingdan; Wang, Jian; Situ, Guohai; Huang, Huijie
2015-10-20
In general, Fourier transform lenses are considered as ideal in the design algorithms of diffractive optical elements (DOEs). However, the inherent aberrations of a real Fourier transform lens disturb the far field pattern. The difference between the generated pattern and the expected design will impact the system performance. Therefore, a method for modifying the Fourier spectrum of DOEs without introducing other optical elements to reduce the aberration effect of the Fourier transform lens is proposed. By applying this method, beam shaping performance is improved markedly for the optical system with a real Fourier transform lens. The experiments carried out with a commercial Fourier transform lens give evidence for this method. The method is capable of reducing the system complexity as well as improving its performance.
Accelerating fourier volume rendering by polar coordinate data representation.
Liao, Jan-Ray; Lee, Shun-Zhi; Lee, Huai-Che
2012-12-01
Volume rendering is an important tool to visualize three-dimensional data in biomedicine by projecting the data to a two-dimensional plane. The projection is done by ray casting and its complexity is proportional to the number of three-dimensional data points. To reduce complexity, Fourier volume rendering (FVR) uses slice projection theorem to facilitate the integration of voxels along the ray casting path. In this paper, we proposed a new method for FVR that stored and processed the frequency domain data in polar coordinate. By exploiting three aspects of data processing which is previously impossible in rectilinear coordinate, our new method is much faster than the previous methods. The first aspect is data regularity. When data are stored in polar coordinate, extracting a slice involves accessing data stored in adjacent memory location. This regularity makes memory access more efficient. The second aspect is to utilize the high data density near the origin in polar coordinate. We can obtain two benefits from this aspect. The first allows us to extract a slice by nearest-neighbor interpolation instead of more complex interpolation but without sacrificing image quality. The second allows us to trade off between image quality and memory storage. The third aspect is to recognize that converting from rectilinear coordinate to polar coordinate is a one-time process. Therefore, we can use a better interpolation kernel with larger support in coordinate conversion. In turn, most of the computation is shifted to the preprocessing stage and interactive rendering can be made very fast. In the experiments, we show that the speed in interactive visualization for our new method is independent of the size of the interpolation kernel, therefore, achieving comparable image quality at a faster rate than previous methods. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.
Fractional Fourier Transform for Ultrasonic Chirplet Signal Decomposition
Directory of Open Access Journals (Sweden)
Yufeng Lu
2012-01-01
Full Text Available A fractional fourier transform (FrFT based chirplet signal decomposition (FrFT-CSD algorithm is proposed to analyze ultrasonic signals for NDE applications. Particularly, this method is utilized to isolate dominant chirplet echoes for successive steps in signal decomposition and parameter estimation. FrFT rotates the signal with an optimal transform order. The search of optimal transform order is conducted by determining the highest kurtosis value of the signal in the transformed domain. A simulation study reveals the relationship among the kurtosis, the transform order of FrFT, and the chirp rate parameter in the simulated ultrasonic echoes. Benchmark and ultrasonic experimental data are used to evaluate the FrFT-CSD algorithm. Signal processing results show that FrFT-CSD not only reconstructs signal successfully, but also characterizes echoes and estimates echo parameters accurately. This study has a broad range of applications of importance in signal detection, estimation, and pattern recognition.
Fourier analysis of polar cap electric field and current distributions
Barbosa, D. D.
1984-01-01
A theoretical study of high-latitude electric fields and currents, using analytic Fourier analysis methods, is conducted. A two-dimensional planar model of the ionosphere with an enhanced conductivity auroral belt and field-aligned currents at the edges is employed. Two separate topics are treated. A field-aligned current element near the cusp region of the polar cap is included to investigate the modifications to the convection pattern by the east-west component of the interplanetary magnetic field. It is shown that a sizable one-cell structure is induced near the cusp which diverts equipotential contours to the dawnside or duskside, depending on the sign of the cusp current. This produces characteristic dawn-dusk asymmetries to the electric field that have been previously observed over the polar cap. The second topic is concerned with the electric field configuration obtained in the limit of perfect shielding, where the field is totally excluded equatorward of the auroral oval. When realistic field-aligned current distributions are used, the result is to produce severely distorted, crescent-shaped equipotential contours over the cap. Exact, analytic formulae applicable to this case are also provided.
Matrix-Vector Based Fast Fourier Transformations on SDR Architectures
Directory of Open Access Journals (Sweden)
Y. He
2008-05-01
Full Text Available Today Discrete Fourier Transforms (DFTs are applied in various radio standards based on OFDM (Orthogonal Frequency Division Multiplex. It is important to gain a fast computational speed for the DFT, which is usually achieved by using specialized Fast Fourier Transform (FFT engines. However, in face of the Software Defined Radio (SDR development, more general (parallel processor architectures are often desirable, which are not tailored to FFT computations. Therefore, alternative approaches are required to reduce the complexity of the DFT. Starting from a matrix-vector based description of the FFT idea, we will present different factorizations of the DFT matrix, which allow a reduction of the complexity that lies between the original DFT and the minimum FFT complexity. The computational complexities of these factorizations and their suitability for implementation on different processor architectures are investigated.
Meso-optical Fourier transform microscope with double focusing
International Nuclear Information System (INIS)
Batusov, Yu.A.; Soroko, L.M.; Tereshchenko, V.V.
1992-01-01
The meso-optical Fourier transform microscope (MFTM) with double focusing for particle tracks of low ionization level in the nuclear emulsion is described. It is shown experimentally that this device enables one to get high concentration of information about the position of the particle track in the nuclear emulsion and thus to increase the signal-to-noise ratio. It is shown that spreading of the meso-optical image of the particle track in the sagittal section of the MFTM can be eliminated completely in the frame of the diffraction limit. The number of the additional degrees of freedom in this new MFTM system along depth coordinate is equal to 20 in comparison to single degree of freedom in the Fourier transform microscope of the direct observation. 10 refs.; 15 figs
Fourier transform digital holographic adaptive optics imaging system
Liu, Changgeng; Yu, Xiao; Kim, Myung K.
2013-01-01
A Fourier transform digital holographic adaptive optics imaging system and its basic principles are proposed. The CCD is put at the exact Fourier transform plane of the pupil of the eye lens. The spherical curvature introduced by the optics except the eye lens itself is eliminated. The CCD is also at image plane of the target. The point-spread function of the system is directly recorded, making it easier to determine the correct guide-star hologram. Also, the light signal will be stronger at the CCD, especially for phase-aberration sensing. Numerical propagation is avoided. The sensor aperture has nothing to do with the resolution and the possibility of using low coherence or incoherent illumination is opened. The system becomes more efficient and flexible. Although it is intended for ophthalmic use, it also shows potential application in microscopy. The robustness and feasibility of this compact system are demonstrated by simulations and experiments using scattering objects. PMID:23262541
Visible Imaging Fourier Transform Spectrometer: Design and Calibration
International Nuclear Information System (INIS)
Wishnow, E.H.; Wurtz, R.; Blais-Ouellette, S.; Cook, K.H.; Carr, D.; Lewis, I.; Grandmont, F.; Stubbs, C.W.
2002-01-01
We present details of the design, operation and calibration of an astronomical visible-band imaging Fourier transform spectrometer (IFTS). This type of instrument produces a spectrum for every pixel in the field of view where the spectral resolution is flexible. The instrument is a dual-input/dual-output Michelson interferometer coupled to the 3.5 meter telescope at the Apache Point Observatory. Imaging performance and interferograms and spectra from calibration sources and standard stars are discussed
10th International Conference on Progress in Fourier Transform Spectroscopy
Keresztury, Gábor; Kellner, Robert
1997-01-01
19 plenary lectures and 203 poster papers presented at the 10th International Conference of Fourier Transform Spectroscopy in Budapest 1995 give an overview on the state-of-the art of this technology and its wide range of applications. The reader will get information on any aspects of FTS including the latest instrumental developments, e.g. in diode array detection, time resolution FTS, microscopy and spectral mapping, double modulation and two-dimensional FTS.
FTIS compact Fourier transform imaging spectrometer for remote sensing
Posselt, W.; Holota, K.; Tittel, H. O.; Rost, M.; Harnisch, B.
2017-11-01
The feasibility of a compact Fourier-Transform-Imaging-Spectrometer (FTIS) for small satellite remote sensing missions is currently being studied under ESA contract. Compared to classical hyperspectral imagers using dispersive spectrometers the major advantages of the FTIS is the compact optics module and the tolerable higher detector temperature, thus easing the instrument thermal design. The feasibility of this instrument concept will be demonstrated by breadboarding.
Fast Fourier transform analysis of rotor-bearing systems
Choy, K. C.; Gunter, E. J.; Allaire, P. E.
1978-01-01
Nonlinear transient analysis of rotor-bearing systems is becoming increasingly important in the analysis of modern-day rotating machinery to model such phenomena as oil film whirl. This paper develops an analysis technique incorporating modal analysis and fast Fourier transform techniques to analyze rotors with residual shaft bow and realistic nonlinear bearings. The technique is demonstrated on single-mass and three-mass rotor examples. Comparisons of the theoretical results with experimental data give excellent agreement.
Fourier transform profilometry by using digital dc subtraction
Wongjarern, J.; Widjaja, J.; Sangpech, W.; Thongdee, N.; Santisoonthornwat, P.; Traisak, O.; Chuamchaitrakool, P.; Meemon, P.
2014-06-01
A new method for eliminating unwanted background of Fourier transform profilometry (FTP) by using simple dc bias and background eliminations from the deformed grating images is proposed. The proposed method has an advantage over a conventional FTP in that the 3-D object profile can be accurately measured although original fundamental spectra are corrupted by a zeroth-order spectrum. Experimental verifications of the proposed method are presented.
Solving singular convolution equations using the inverse fast Fourier transform
Czech Academy of Sciences Publication Activity Database
Krajník, E.; Montesinos, V.; Zizler, P.; Zizler, Václav
2012-01-01
Roč. 57, č. 5 (2012), s. 543-550 ISSN 0862-7940 R&D Projects: GA AV ČR IAA100190901 Institutional research plan: CEZ:AV0Z10190503 Keywords : singular convolution equations * fast Fourier transform * tempered distribution Subject RIV: BA - General Mathematics Impact factor: 0.222, year: 2012 http://www.springerlink.com/content/m8437t3563214048/
ISAR Image Formation Based on Minimum Entropy Criterion and Fractional Fourier Transform
Naghsh, Mohammad Mahdi; Modarres-Hashemi, Mahmood
Conventional radar imaging systems use Fourier transform for image formation, but due to the target's complicated motion the Doppler spectrum is time-varying and thus the reconstructed image becomes blurred even after applying standard motion compensation algorithms. Therefore, sophisticated algorithms such as polar reformatting are usually employed to produce clear images. Alternatively, Joint Time-Frequency (JTF) analysis can be used for image formation which produces clear image without using polar reformatting algorithm. In this paper, a new JTF-based method is proposed for image formation in inverse synthetic aperture radars (ISAR). This method uses minimum entropy criterion for optimum parameter adjustment of JTF algorithms. Short Time Fourier Transform (STFT) and Fractional Fourier Transform (FrFT) are applied as JTF for time-varying Doppler spectrum analysis. Both the width of Gaussian window of STFT and the order of FrFT, α, are adjusted using minimum entropy as local and total measures. Furthermore, a new statistical parameter, called normalized correlation, is defined for comparison of images reconstructed by different methods. Simulation results show that α-order FrFT with local adjustment has much better performance than the other methods in this category even in low SNR.
Fourier transform light scattering angular spectroscopy using digital inline holography.
Kim, Kyoohyun; Park, YongKeun
2012-10-01
A simple and practical method for measuring the angle-resolved light scattering (ARLS) from individual objects is reported. Employing the principle of inline holography and a Fourier transform light scattering technique, both the static and dynamic scattering patterns from individual micrometer-sized objects can be effectively and quantitatively obtained. First, the light scattering measurements were performed on individual polystyrene beads, from which the refractive index and diameter of each bead were retrieved. Also, the measurements of the static and dynamic light scattering from intact human red blood cells are demonstrated. Using the present method, an existing microscope can be directly transformed into a precise instrument for ARLS measurements.
International Nuclear Information System (INIS)
Tam, K.C.; Perez-Mendez, V.
1981-01-01
The principles of limited-angle reconstruction of space-limited objects using the concepts of allowed cone and missing cone in Fourier space are discussed. The distortion of a point source resulting from setting the Fourier components in the missing cone to zero has been calculated mathematically, and its bearing on the convergence of an iteration scheme involving Fourier transforms has been analyzed in detail. it was found that the convergence rate is fairly insensitive to the position of the point source within the boundary of the object, apart from an edge effect which tends to enhance some parts of the boundary in reconstructing the object. Another iteration scheme involving Radon transforms was introduced and compared to the Fourier transform method in such areas as root mean square error, stability with respect to noise, and computer reconstruction time
Limited-angle 3-D reconstructions using Fourier transform iterations and Radon transform iterations
International Nuclear Information System (INIS)
Tam, K.C.; Perez-Mendez, V.
1979-12-01
The principles of limited-angle reconstruction of space-limited objects using the concepts of allowed cone and missing cone in Fourier space are discussed. The distortion of a point source resulting from setting the Fourier components in the missing cone to zero was calculated mathematically, and its bearing on the convergence of an iteration scheme involving Fourier transforms was analyzed in detail. It was found that the convergence rate is fairly insensitive to the position of the point source within the boundary of the object, apart from an edge effect that tends to enhance some parts of the boundary in reconstructing the object. Another iteration scheme involving Radon transforms was introduced and compared to the Fourier transform method in such areas as root mean square error, stability with respect to noise, and computer reconstruction time. 8 figures, 2 tables
Kamnev, Alexander A.; Tugarova, Anna V.; Dyatlova, Yulia A.; Tarantilis, Petros A.; Grigoryeva, Olga P.; Fainleib, Alexander M.; De Luca, Stefania
2018-03-01
A set of experimental data obtained by Fourier transform infrared (FTIR) spectroscopy (involving the use of samples ground and pressed with KBr, i.e. in a polar halide matrix) and by matrix-free transmission FTIR or diffuse reflectance infrared Fourier transform (DRIFT) spectroscopic methodologies (involving measurements of thin films or pure powdered samples, respectively) were compared for several different biomacromolecular substances. The samples under study included poly-3-hydroxybutyrate (PHB) isolated from cell biomass of the rhizobacterium Azospirillum brasilense; dry PHB-containing A. brasilense biomass; pectin (natural carboxylated heteropolysaccharide of plant origin; obtained from apple peel) as well as its chemically modified derivatives obtained by partial esterification of its galacturonide-chain hydroxyl moieties with palmitic, oleic and linoleic acids. Significant shifts of some FTIR vibrational bands related to polar functional groups of all the biomacromolecules under study, induced by the halide matrix used for preparing the samples for spectroscopic measurements, were shown and discussed. A polar halide matrix used for preparing samples for FTIR measurements was shown to be likely to affect band positions not only per se, by affecting band energies or via ion exchange (e.g., with carboxylate moieties), but also by inducing crystallisation of metastable amorphous biopolymers (e.g., PHB of microbial origin). The results obtained have important implications for correct structural analyses of polar, H-bonded and/or amphiphilic biomacromolecular systems using different methodologies of FTIR spectroscopy.
Two-Dimensional Fourier Transform Analysis of Helicopter Flyover Noise
SantaMaria, Odilyn L.; Farassat, F.; Morris, Philip J.
1999-01-01
A method to separate main rotor and tail rotor noise from a helicopter in flight is explored. Being the sum of two periodic signals of disproportionate, or incommensurate frequencies, helicopter noise is neither periodic nor stationary. The single Fourier transform divides signal energy into frequency bins of equal size. Incommensurate frequencies are therefore not adequately represented by any one chosen data block size. A two-dimensional Fourier analysis method is used to separate main rotor and tail rotor noise. The two-dimensional spectral analysis method is first applied to simulated signals. This initial analysis gives an idea of the characteristics of the two-dimensional autocorrelations and spectra. Data from a helicopter flight test is analyzed in two dimensions. The test aircraft are a Boeing MD902 Explorer (no tail rotor) and a Sikorsky S-76 (4-bladed tail rotor). The results show that the main rotor and tail rotor signals can indeed be separated in the two-dimensional Fourier transform spectrum. The separation occurs along the diagonals associated with the frequencies of interest. These diagonals are individual spectra containing only information related to one particular frequency.
A transformada de Fourier em basic The Fourier transform (FFT in basic
Directory of Open Access Journals (Sweden)
Mauricio Gomes Constantino
2000-06-01
Full Text Available In this paper we describe three computer programs in Basic language about the Fourier transform (FFT which are available in the Internet site http://artemis.ffclrp.usp.br/SoftwareE.htm (in English or http://artemis.ffclrp.usp.br/softwareP.htm (in Portuguese since October 1998. Those are addresses to the Web Page of our Laboratory of Organic Synthesis. The programs can be downloaded and used by anyone who is interested on the subject. The texts, menus and captions in the programs are written in English.
Fourier transform spectrometry for fiber-optic sensor systems
Beheim, Glenn; Tuma, Margaret L.; Sotomayor, Jorge L.; Flatico, Joseph M.
1993-01-01
An integrated-optic Mach-Zehnder interferometer is used as a Fourier transform spectrometer to analyze the input and output spectra of a temperature-sensing thin-film etalon. This type of spectrometer has an advantage over conventional grating spectrometers because it is better suited for use with time-division-multiplexed sensor networks. In addition, this spectrometer has the potential for low cost due to its use of a component that could be manufactured in large quantities for the optical communications industry.
Transfer Function Identification Using Orthogonal Fourier Transform Modeling Functions
Morelli, Eugene A.
2013-01-01
A method for transfer function identification, including both model structure determination and parameter estimation, was developed and demonstrated. The approach uses orthogonal modeling functions generated from frequency domain data obtained by Fourier transformation of time series data. The method was applied to simulation data to identify continuous-time transfer function models and unsteady aerodynamic models. Model fit error, estimated model parameters, and the associated uncertainties were used to show the effectiveness of the method for identifying accurate transfer function models from noisy data.
Optical Two Dimensional Fourier Transform Spectroscopy of Layered Metal Dichalcogenides
Dey, P.; Paul, J.; Stevens, C. E.; Kovalyuk, Z. D.; Kudrynskyi, Z. R.; Romero, A. H.; Cantarero, A.; Hilton, D. J.; Shan, J.; Karaiskaj, D.; Z. D. Kovalyuk; Z. R. Kudrynskyi Collaboration; A. H. Romero Collaboration; A. Cantarero Collaboration; D. J. Hilton Collaboration; J. Shan Collaboration
2015-03-01
Nonlinear two-dimensional Fourier transform (2DFT) measurements were used to study the mechanism of excitonic dephasing and probe the electronic structure of the excitonic ground state in layered metal dichalcogenides. Temperature-dependent 2DFT measurements were performed to probe exciton-phonon interactions. Excitation density dependent 2DFT measurements reveal exciton-exciton and exciton-carrier scattering, and the lower limit for the homogeneous linewidth of excitons on positively and negatively doped samples. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award DE-SC0012635.
The discrete Fourier transform theory, algorithms and applications
Sundaraajan, D
2001-01-01
This authoritative book provides comprehensive coverage of practical Fourier analysis. It develops the concepts right from the basics and gradually guides the reader to the advanced topics. It presents the latest and practically efficient DFT algorithms, as well as the computation of discrete cosine and Walsh-Hadamard transforms. The large number of visual aids such as figures, flow graphs and flow charts makes the mathematical topic easy to understand. In addition, the numerous examples and the set of C-language programs (a supplement to the book) help greatly in understanding the theory and
Fourier-transform Raman spectroscopic study of human hair
Akhtar, W.; Edwards, H. G. M.; Farwell, D. W.; Nutbrown, M.
1997-07-01
Fourier-transform Raman microscopic spectra of normal, untreated and bleached hair fibres are presented. Vibrational assignments are made and differences are ascribed to the production of cysteic acid from cysteine. Changes in conformation associated with the disulphide bond in the keratotic component are noted from the ν(CSSC) vibrational modes at wave numbers near 500 cm -1. Raman spectra of hair root ends have also been investigated with a diminution in cysteine content being observed. Application of the technique to the biomedical investigation of healthy and diseased hair is proposed.
Hochauflösende Fourier-Transform-Emissionsspektroskopie
Uibel, Christian
2000-01-01
Mittels hochauflösender Fourier-Transform-Infrarot-Emissionsspektroskopie wurden tiefliegende elektronische Anregungszustände der mittelschweren zweiatomigen Radikale As2, Sb2 und TeF untersucht. Dabei lag das Interesse vor allem bei den Emissionen nicht voll erlaubter Übergänge wie beispielsweise der 3Σ +u → 1Σ +g- bzw. (1u) → (0+g)-Übergänge bei den Stickstoff-Homologen. Dieses besondere Interesse an der genauen Analyse der 3Σ +u-Zustände liegt in ihrem metastab...
Particle field holography data reduction by Fourier transform analysis
Hess, Cecil F.; Trolinger, James D.
1987-01-01
The size distribution of a particle field hologram is obtained with a Fourier transformation of the Fraunhofer diffraction pattern of the reconstructed hologram. Off-axis absorption holograms of particle fields with known characteristics were obtained and analyzed with a commercially available instrument. The mean particle size of the reconstructed hologram was measured with an error of + or - 5 percent, while the distribution broadening was estimated within + or - 15 percent. Small sections of a pulsed laser hologram of a synthetic fuel spray were analyzed with this method thus yielding a spatially resolved size distribution. The method yields fast and accurate automated analysis of particle field holograms.
THREE-VARIABLE ALTERNATING TRIGONOMETRIC FUNCTIONS AND CORRESPONDING FOURIER TRANSFORMS
Directory of Open Access Journals (Sweden)
Agata Bezubik
2016-06-01
Full Text Available The common trigonometric functions admit generalizations to any higher dimension, the symmetric, antisymmetric and alternating ones. In this paper, we restrict ourselves to three dimensional generalization only, focusing on alternating case in detail. Many specific properties of this new class of special functions useful in applications are studied. Such are the orthogonalities, both the continuous one and the discrete one on the 3D lattice of any density, corresponding discrete and continuous Fourier transforms, and others. Rapidly increasing precision of the interpolation with increasing density of the 3D lattice is shown in an example.
Fourier Transform Infrared Spectroscopy of Trifluoroiodomethane ICP Discharge
Fagioli, Cassius; Urrabazo, David; Goeckner, Matthew
2012-10-01
Trifluoroiodomethane (CF3I) is an experimental gas that currently is being considered for semiconductor etching. We will report the breakdown characteristics of CF3I in an ICP plasma. In this study, the gas chemistry was examined through the use of Fourier transform infrared (FTIR) spectroscopy. This allowed us to identify the fraction of CF3I remaining in the discharge as well as some of the daughter species produced. Our results indicate that the major multi-atomic species found in the system include Tetrafluoromethane (CF4) and Trifluoromethyl (CF3). Mass balance examination also suggests the creation of atomic and molecular Iodide.
Fourier transform infrared studies in solid egg white lysozyme
International Nuclear Information System (INIS)
Rivzi, T.Z.
1994-12-01
Fourier Transform Infrared (FTIR) Spectroscopy is the most recent addition to the arsenal of bioanalytical techniques capable of providing information about the secondary structure of proteins in a variety of environments. FTIR spectra have been obtained in solid egg white lysozyme. The spectra display the usual amide I, II and III bands. Secondary structural information obtained from the spectra after applying resolution enhancement techniques to the amide I band has been found consistent with the x-ray crystallographic data of the protein and also to the spectroscopic data of the protein in aqueous solution. (author). 17 refs, 6 figs, 2 tabs
Directional short-time Fourier transform of distributions
Directory of Open Access Journals (Sweden)
Katerina Hadzi-Velkova Saneva
2016-04-01
Full Text Available Abstract In this paper we consider the directional short-time Fourier transform (DSTFT that was introduced and investigated in (Giv in J. Math. Anal. Appl. 399:100-107, 2013. We analyze the DSTFT and its transpose on test function spaces S ( R n $\\mathcal {S}(\\mathbb {R}^{n}$ and S ( Y 2 n $\\mathcal {S}(\\mathbb {Y}^{2n}$ , respectively, and prove the continuity theorems on these spaces. Then the obtained results are used to extend the DSTFT to spaces of distributions.
2D discrete Fourier transform on sliding windows.
Park, Chun-Su
2015-03-01
Discrete Fourier transform (DFT) is the most widely used method for determining the frequency spectra of digital signals. In this paper, a 2D sliding DFT (2D SDFT) algorithm is proposed for fast implementation of the DFT on 2D sliding windows. The proposed 2D SDFT algorithm directly computes the DFT bins of the current window using the precalculated bins of the previous window. Since the proposed algorithm is designed to accelerate the sliding transform process of a 2D input signal, it can be directly applied to computer vision and image processing applications. The theoretical analysis shows that the computational requirement of the proposed 2D SDFT algorithm is the lowest among existing 2D DFT algorithms. Moreover, the output of the 2D SDFT is mathematically equivalent to that of the traditional DFT at all pixel positions.
Quantum Fourier transform, Heisenberg groups and quasi-probability distributions
International Nuclear Information System (INIS)
Patra, Manas K; Braunstein, Samuel L
2011-01-01
This paper aims to explore the inherent connection between Heisenberg groups, quantum Fourier transform (QFT) and (quasi-probability) distribution functions. Distribution functions for continuous and finite quantum systems are examined from three perspectives and all of them lead to Weyl-Gabor-Heisenberg groups. The QFT appears as the intertwining operator of two equivalent representations arising out of an automorphism of the group. Distribution functions correspond to certain distinguished sets in the group algebra. The marginal properties of a particular class of distribution functions (Wigner distributions) arise from a class of automorphisms of the group algebra of the Heisenberg group. We then study the reconstruction of the Wigner function from the marginal distributions via inverse Radon transform giving explicit formulae. We consider some applications of our approach to quantum information processing and quantum process tomography.
A high-resolution Fourier Transform Spectrometer for planetary spectroscopy
Cruikshank, D. P.; Sinton, W. M.
1973-01-01
The employment of a high-resolution Fourier Transform Spectrometer (FTS) is described for planetary and other astronomical spectroscopy in conjunction with the 88-inch telescope at Mauna Kea Observatory. The FTS system is designed for a broad range of uses, including double-beam laboratory spectroscopy, infrared gas chromatography, and nuclear magnetic resonance spectroscopy. The data system is well-suited to astronomical applications because of its great speed in acquiring and transforming data, and because of the enormous storage capability of the magnetic tape unit supplied with the system. The basic instrument is outlined 2nd some of the initial results from the first attempted use on the Mauna Kea 88-inch telescope are reported.
Gas Measurement Using Static Fourier Transform Infrared Spectrometers.
Köhler, Michael H; Schardt, Michael; Rauscher, Markus S; Koch, Alexander W
2017-11-13
Online monitoring of gases in industrial processes is an ambitious task due to adverse conditions such as mechanical vibrations and temperature fluctuations. Whereas conventional Fourier transform infrared (FTIR) spectrometers use rather complex optical and mechanical designs to ensure stable operation, static FTIR spectrometers do not require moving parts and thus offer inherent stability at comparatively low costs. Therefore, we present a novel, compact gas measurement system using a static single-mirror Fourier transform spectrometer (sSMFTS). The system works in the mid-infrared range from 650 cm - 1 to 1250 cm - 1 and can be operated with a customized White cell, yielding optical path lengths of up to 120 cm for highly sensitive quantification of gas concentrations. To validate the system, we measure different concentrations of 1,1,1,2-Tetrafluoroethane (R134a) and perform a PLS regression analysis of the acquired infrared spectra. Thereby, the measured absorption spectra show good agreement with reference data. Since the system additionally permits measurement rates of up to 200 Hz and high signal-to-noise ratios, an application in process analysis appears promising.
Progress report of a static Fourier transform spectrometer breadboard
Rosak, A.; Tintó, F.
2017-11-01
MOLI instrument -for MOtionLess Interferometer- takes advantage of the new concept of static Fourier transform spectrometer. It is a high-resolution spectrometer working over a narrow bandwidth, which is adapted to a wide range of atmospheric sounding missions and compatible with micro-satellite platform. The core of this instrument is an echelette cube. Mirrors on the classical design are replaced by stepped mirrors -integrated into that interference cube- thus suppressing any moving part. The steps' directions being set over a perpendicular axis, the overlap of both stepped mirrors creates a cluster of so-called "echelettes", each one corresponding to a different optical path difference (OPD). Hence the Fourier transform of the incoming radiance is directly imaged on a CCD array in a single acquisition. The frequency domain of the measurements is selected by an interferential filter disposed on the incoming optical path. A rotating wheel equipped with several filters allows the successive measurement of spectra around some bands of interest, i.e. O2, CO2 and CO absorption bands.
Vector Radix 2 × 2 Sliding Fast Fourier Transform
Directory of Open Access Journals (Sweden)
Keun-Yung Byun
2016-01-01
Full Text Available The two-dimensional (2D discrete Fourier transform (DFT in the sliding window scenario has been successfully used for numerous applications requiring consecutive spectrum analysis of input signals. However, the results of conventional sliding DFT algorithms are potentially unstable because of the accumulated numerical errors caused by recursive strategy. In this letter, a stable 2D sliding fast Fourier transform (FFT algorithm based on the vector radix (VR 2 × 2 FFT is presented. In the VR-2 × 2 FFT algorithm, each 2D DFT bin is hierarchically decomposed into four sub-DFT bins until the size of the sub-DFT bins is reduced to 2 × 2; the output DFT bins are calculated using the linear combination of the sub-DFT bins. Because the sub-DFT bins for the overlapped input signals between the previous and current window are the same, the proposed algorithm reduces the computational complexity of the VR-2 × 2 FFT algorithm by reusing previously calculated sub-DFT bins in the sliding window scenario. Moreover, because the resultant DFT bins are identical to those of the VR-2 × 2 FFT algorithm, numerical errors do not arise; therefore, unconditional stability is guaranteed. Theoretical analysis shows that the proposed algorithm has the lowest computational requirements among the existing stable sliding DFT algorithms.
[Fourier Transform Spectrometer Based on Rotating Parallel-Mirror-Pair].
Zhao, Bao-wei; Xiangli, Bin; Cai, Qi-sheng; Lü, Qun-bo; Zhou, Jin-song
2015-11-01
In the temporally-modulated Fourier transform spectroscopy, the translational moving mirror is difficult to drive accurately, causing tilt and shear problems. While, a rotational moving mirror can solve these problems. A rotary Fourier transform spectrometer is recommanded in this paper. Its principle is analyzed and the optical path difference is deduced. Also, the constrains for engineering realization are presented. This spectrometer consists of one beamsplitter, two fixed mirrors, one rotating parallel mirror pair, a collimating lens, a collecting lens, and one detector. From it's principle, this spectrometer show a simple structure, and it is assembled and adjustmented easily because the two split light are interfered with each other after reflected through the same plane mirror; By calculating the expression of it's optical path difference, the spectrometer is easy to realize large optical path difference, meaning high spectral resolution; Through analyzing it's engineering design constraints and computer simulation, it is known that the spectrometer should get the high resolution sample by high-speed spinning motor, so it is easy to achieve precise motion control, good stability, fast measurement speed.
On integral and finite Fourier transforms of continuous q-Hermite polynomials
International Nuclear Information System (INIS)
Atakishiyeva, M. K.; Atakishiyev, N. M.
2009-01-01
We give an overview of the remarkably simple transformation properties of the continuous q-Hermite polynomials H n (x vertical bar q) of Rogers with respect to the classical Fourier integral transform. The behavior of the q-Hermite polynomials under the finite Fourier transform and an explicit form of the q-extended eigenfunctions of the finite Fourier transform, defined in terms of these polynomials, are also discussed.
Regularized spherical polar fourier diffusion MRI with optimal dictionary learning.
Cheng, Jian; Jiang, Tianzi; Deriche, Rachid; Shen, Dinggang; Yap, Pew-Thian
2013-01-01
Compressed Sensing (CS) takes advantage of signal sparsity or compressibility and allows superb signal reconstruction from relatively few measurements. Based on CS theory, a suitable dictionary for sparse representation of the signal is required. In diffusion MRI (dMRI), CS methods proposed for reconstruction of diffusion-weighted signal and the Ensemble Average Propagator (EAP) utilize two kinds of Dictionary Learning (DL) methods: 1) Discrete Representation DL (DR-DL), and 2) Continuous Representation DL (CR-DL). DR-DL is susceptible to numerical inaccuracy owing to interpolation and regridding errors in a discretized q-space. In this paper, we propose a novel CR-DL approach, called Dictionary Learning - Spherical Polar Fourier Imaging (DL-SPFI) for effective compressed-sensing reconstruction of the q-space diffusion-weighted signal and the EAP. In DL-SPFI, a dictionary that sparsifies the signal is learned from the space of continuous Gaussian diffusion signals. The learned dictionary is then adaptively applied to different voxels using a weighted LASSO framework for robust signal reconstruction. Compared with the start-of-the-art CR-DL and DR-DL methods proposed by Merlet et al. and Bilgic et al., respectively, our work offers the following advantages. First, the learned dictionary is proved to be optimal for Gaussian diffusion signals. Second, to our knowledge, this is the first work to learn a voxel-adaptive dictionary. The importance of the adaptive dictionary in EAP reconstruction will be demonstrated theoretically and empirically. Third, optimization in DL-SPFI is only performed in a small subspace resided by the SPF coefficients, as opposed to the q-space approach utilized by Merlet et al. We experimentally evaluated DL-SPFI with respect to L1-norm regularized SPFI (L1-SPFI), which uses the original SPF basis, and the DR-DL method proposed by Bilgic et al. The experiment results on synthetic and real data indicate that the learned dictionary produces
Yang, Lin; Guo, Peng; Yang, Aiying; Qiao, Yaojun
2018-02-01
In this paper, we propose a blind third-order dispersion estimation method based on fractional Fourier transformation (FrFT) in optical fiber communication system. By measuring the chromatic dispersion (CD) at different wavelengths, this method can estimation dispersion slope and further calculate the third-order dispersion. The simulation results demonstrate that the estimation error is less than 2 % in 28GBaud dual polarization quadrature phase-shift keying (DP-QPSK) and 28GBaud dual polarization 16 quadrature amplitude modulation (DP-16QAM) system. Through simulations, the proposed third-order dispersion estimation method is shown to be robust against nonlinear and amplified spontaneous emission (ASE) noise. In addition, to reduce the computational complexity, searching step with coarse and fine granularity is chosen to search optimal order of FrFT. The third-order dispersion estimation method based on FrFT can be used to monitor the third-order dispersion in optical fiber system.
Discrimination of different Chrysanthemums with Fourier transform infrared spectroscopy
Liu, Hong-xia; Zhou, Qun; Sun, Su-qin; Bao, Hong-juan
2008-07-01
Use Fourier transform infrared spectroscopy (FT-IR) to analyze simultaneously the main chemical constituents in different solvent extracts of seven kinds of Chrysanthemum samples of different regions. The findings indicate that different Chrysanthemum samples have dissimilar fingerprint characters in FT-IR spectra. Such spectral technique can provide substance structural information of the complicated test samples. According to these spectral fingerprint features, we cannot only identify the main components of different extracts, but also distinguish the origins of the Chrysanthemum samples from different regions easily, which is a troublesome work by existing analytical methods. FT-IR, with the characters of speediness, good repeatability and easy operation, can be used as an effective analytical means to study the complicated system, in our research, the tradition Chinese medicines.
Development of galvanostatic Fourier transform electrochemical impedance spectroscopy.
Nam, Kwang-Mo; Shin, Dong-Hyup; Jung, Namchul; Joo, Moon G; Jeon, Sangmin; Park, Su-Moon; Chang, Byoung-Yong
2013-02-19
Here, we report development of the galvanostatic Fourier transform electrochemical impedance spectroscopy (FTEIS), which monitors impedance of electrochemical reactions activated by current steps. We first derive relevant relations for potential change upon application of a step current, obtain impedances theoretically from the relations by simulation, and verify them with experimental results. The validity of the galvanostatic FTEIS technique is demonstrated by measuring impedances of a semiconductive silicon wafer using the conventional frequency response analysis (FRA), the potentiostatic FTEIS, and the galvanostatic FTEIS methods, and the results are in excellent agreement with each other. This work is significant in that the galvanostatic FTEIS would allow one to record impedance changes during charge/discharge cycles of secondary batteries and fuel cells as well as electrochemically irreversible systems which may produce noise level chronoamperometric currents by potentiostatic techniques.
Fourier transform microwave spectroscopy of the SiCl+ ion
Tanaka, Keiichi; Harada, Kensuke; Cabezas, Carlos; Endo, Yasuki
2018-03-01
Fourier transform microwave spectra for the J = 1 ← 0 and 2 ← 1 rotational transitions of the SiCl+ ion were observed for two isotopologues (35 Cl and 37 Cl) in the ground and the first excited vibrational states of the ground 1Σ+ electronic state. Thanks to the high resolution of the FTMW spectrometer, hyperfine structures due to the quadrupole moment of the chlorine nucleus and the nuclear spin-rotation interaction were fully resolved. The observed FTMW spectra were combined with previously reported MMW and diode laser spectra in an analysis to determine the mass-independent Dunham coefficients Uk,l as well as a mass scaling parameter Δ01Cl = - 0.856 (30) . The equilibrium bond length of SiCl+ determined is re = 1.9439729 (10) Å and the nuclear quadrupole coupling constant of Si35 Cl+ is eQqe = - 11.8788 (23) MHz.
Topography description of thin films by optical Fourier Transform
International Nuclear Information System (INIS)
Jaglarz, Janusz
2008-01-01
In this work, the main problems concerning the scattering of light by real surfaces and films are presented in view of results obtained with the bidirectional reflection distribution function (BRDF) method and optical profilometry (OP). The BRDF and OP studies, being complementary to the atomic force microscopy (AFM), allow one to get information about surface topography. From the optical data, the surface power spectral density (PSD) functions for absorbing and transparent rough films have been found. Both functions have been evaluated from the Fourier transform (FT) of the surface profiles. The usefulness of BRDF-and OP methods in characterization of real surfaces is demonstrated when analyzing the optical data obtained for metallic TiN-and organic PVK thin films deposited on various substrates
A rheumatoid arthritis study by Fourier transform infrared spectroscopy
Carvalho, Carolina S.; Silva, Ana Carla A.; Santos, Tatiano J. P. S.; Martin, Airton A.; dos Santos Fernandes, Ana Célia; Andrade, Luís E.; Raniero, Leandro
2012-01-01
Rheumatoid arthritis is a systemic inflammatory disease of unknown causes and a new methods to identify it in early stages are needed. The main purpose of this work is the biochemical differentiation of sera between normal and RA patients, through the establishment of a statistical method that can be appropriately used for serological analysis. The human sera from 39 healthy donors and 39 rheumatics donors were collected and analyzed by Fourier Transform Infrared Spectroscopy. The results show significant spectral variations with plipids and immunoglobulins. The technique of latex particles, coated with human IgG and monoclonal anti-CRP by indirect agglutination known as FR and CRP, was performed to confirm possible false-negative results within the groups, facilitating the statistical interpretation and validation of the technique.
Micro wishbone interferometer for Fourier transform infrared spectrometry
International Nuclear Information System (INIS)
Lee, Young-Min; Toda, Masaya; Ono, Takahito; Esashi, Masayoshi
2011-01-01
A miniature wishbone-type Si interferometer with electrically actuated rotary comb drive actuators is designed and fabricated to apply a Fourier transform infrared (FTIR) spectrometer. Corner cube mirrors are mounted on the end of the Si interferometer that is formed on a glass substrate. The total size of the interferometer is approximately 8 mm × 8 mm. The corner cube mirrors with sharp edges with a size of approximately 1 × 1 × 0.5 mm 3 are fabricated using an indentation technique. The rotation angle of rotary comb drive actuators is approximately 11° with an applied voltage of 180 V. Hereby, the maximum optical path difference of approximately 2640 µm is achieved, which corresponds to the highest resolution of ∼4 cm −1 as a spectrometer
High-Throughput Screening Using Fourier-Transform Infrared Imaging
Directory of Open Access Journals (Sweden)
Erdem Sasmaz
2015-06-01
Full Text Available Efficient parallel screening of combinatorial libraries is one of the most challenging aspects of the high-throughput (HT heterogeneous catalysis workflow. Today, a number of methods have been used in HT catalyst studies, including various optical, mass-spectrometry, and gas-chromatography techniques. Of these, rapid-scanning Fourier-transform infrared (FTIR imaging is one of the fastest and most versatile screening techniques. Here, the new design of the 16-channel HT reactor is presented and test results for its accuracy and reproducibility are shown. The performance of the system was evaluated through the oxidation of CO over commercial Pd/Al2O3 and cobalt oxide nanoparticles synthesized with different reducer-reductant molar ratios, surfactant types, metal and surfactant concentrations, synthesis temperatures, and ramp rates.
Using the fast fourier transform in binding free energy calculations.
Nguyen, Trung Hai; Zhou, Huan-Xiang; Minh, David D L
2018-04-30
According to implicit ligand theory, the standard binding free energy is an exponential average of the binding potential of mean force (BPMF), an exponential average of the interaction energy between the unbound ligand ensemble and a rigid receptor. Here, we use the fast Fourier transform (FFT) to efficiently evaluate BPMFs by calculating interaction energies when rigid ligand configurations from the unbound ensemble are discretely translated across rigid receptor conformations. Results for standard binding free energies between T4 lysozyme and 141 small organic molecules are in good agreement with previous alchemical calculations based on (1) a flexible complex ( R≈0.9 for 24 systems) and (2) flexible ligand with multiple rigid receptor configurations ( R≈0.8 for 141 systems). While the FFT is routinely used for molecular docking, to our knowledge this is the first time that the algorithm has been used for rigorous binding free energy calculations. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.
Analysis of far-infrared emission Fourier transform spectra
Park, J. H.; Carli, B.
1986-01-01
An analysis method that uses the nonlinear least-squares fit technique has been developed for emission spectra obtained with a Fourier transform spectrometer. This method is used for the analysis of submillimeter-region atmospheric emission spectra obtained with a balloon-borne FT spectrometer that was carried out as a correlative measurement for the Limb IR Monitor of the Stratosphere (LIMS) satellite experiment. The retrieved mixing ratios of H2O and O3 in the stratosphere from four spectral intervals have standard deviations of about 10 percent, and the average values agree to within 10 percent of corresponding results from the LIMS satellite experiment which used a broadband emission radiometer in the IR region.
Generation of Fourier-transform-limited heralded single photons
International Nuclear Information System (INIS)
U'Ren, Alfred B.; Jeronimo-Moreno, Yasser; Garcia-Gracia, Hipolito
2007-01-01
In this paper we study the spectral (temporal) properties of heralded single photon wave packets, triggered by the detection of an idler photon in the process of parametric down conversion. The generated single photons are studied within the framework of the chronocyclic Wigner function, from which the single photon spectral width and temporal duration can be computed. We derive specific conditions on the two-photon joint spectral amplitude which result in both pure and Fourier-transform-limited heralded single photons. Likewise, we present specific source geometries which lead to the fulfillment of these conditions and show that one of these geometries leads, for a given pump bandwidth, to the temporally shortest possible heralded single photon wave packets
Surface analysis by Fourier-transform infrared (FTIR) spectroscopy
International Nuclear Information System (INIS)
Powell, G.L.; Smyrl, N.R.; Fuller, E.L.
1981-01-01
A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400 0 C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures
Quantum copying and simplification of the quantum Fourier transform
Niu, Chi-Sheng
Theoretical studies of quantum computation and quantum information theory are presented in this thesis. Three topics are considered: simplification of the quantum Fourier transform in Shor's algorithm, optimal eavesdropping in the BB84 quantum cryptographic protocol, and quantum copying of one qubit. The quantum Fourier transform preceding the final measurement in Shor's algorithm is simplified by replacing a network of quantum gates with one that has fewer and simpler gates controlled by classical signals. This simplification results from an analysis of the network using the consistent history approach to quantum mechanics. The optimal amount of information which an eavesdropper can gain, for a given level of noise in the communication channel, is worked out for the BB84 quantum cryptographic protocol. The optimal eavesdropping strategy is expressed in terms of various quantum networks. A consistent history analysis of these networks using two conjugate quantum bases shows how the information gain in one basis influences the noise level in the conjugate basis. The no-cloning property of quantum systems, which is the physics behind quantum cryptography, is studied by considering copying machines that generate two imperfect copies of one qubit. The best qualities these copies can have are worked out with the help of the Bloch sphere representation for one qubit, and a quantum network is worked out for an optimal copying machine. If the copying machine does not have additional ancillary qubits, the copying process can be viewed using a 2-dimensional subspace in a product space of two qubits. A special representation of such a two-dimensional subspace makes possible a complete characterization of this type of copying. This characterization in turn leads to simplified eavesdropping strategies in the BB84 and the B92 quantum cryptographic protocols.
Fourier domain target transformation analysis in the thermal infrared
Anderson, D. L.
1993-01-01
Remote sensing uses of principal component analysis (PCA) of multispectral images include band selection and optimal color selection for display of information content. PCA has also been used for quantitative determination of mineral types and abundances given end member spectra. The preliminary results of the investigation of target transformation PCA (TTPCA) in the fourier domain to both identify end member spectra in an unknown spectrum, and to then calculate the relative concentrations of these selected end members are presented. Identification of endmember spectra in an unknown sample has previously been performed through bandmatching, expert systems, and binary classifiers. Both bandmatching and expert system techniques require the analyst to select bands or combinations of bands unique to each endmember. Thermal infrared mineral spectra have broad spectral features which vary subtly with composition. This makes identification of unique features difficult. Alternatively, whole spectra can be used in the classification process, in which case there is not need for an expert to identify unique spectra. Use of binary classifiers on whole spectra to identify endmember components has met with some success. These techniques can be used, along with a least squares fit approach on the endmembers identified, to derive compositional information. An alternative to the approach outlined above usese target transformation in conjunction with PCA to both identify and quantify the composition of unknown spectra. Preprocessing of the library and unknown spectra into the fourier domain, and using only a specific number of the components, allows for significant data volume reduction while maintaining a linear relationship in a Beer's Law sense. The approach taken here is to iteratively calculate concentrations, reducing the number of endmember components until only non-negative concentrations remain.
High Range Resolution Profile Construction Exploiting Modified Fractional Fourier Transformation
Directory of Open Access Journals (Sweden)
Feng Wang
2015-01-01
Full Text Available This paper addresses the discrimination of closely spaced high speed group targets with radar transmitting linear frequency modulation (LFM pulses. The high speed target motion leads to range migration and target dispersion and thereby the discriminating capability of the high range resolution profile (HRRP deteriorating significantly. An effective processing approach composed of stretch processing (SP, modified fractional Fourier transform (FrFT, and multiple signal classification (MUSIC algorithm is proposed to deal with this problem. Firstly, SP is adopted to transform the received LFM with Doppler distortions into narrow band LFM signals. Secondly, based on the two-dimensional range/velocity plane constructed by the modified FrFT, the velocity of the high speed group target is estimated and compensated with just one single pulse. After the compensation of range migration and target dispersion simultaneously, the resolution of the HRRP achieved by single pulse transmission improves significantly in the high speed group targets scenarios. Finally, MUSIC algorithm with superresolution capability is utilized to make a more explicit discrimination between the scatterers in comparison with the conventional SP method. Simulation results show the effectiveness of the proposed scheme.
TMS320C25 Digital Signal Processor For 2-Dimensional Fast Fourier Transform Computation
International Nuclear Information System (INIS)
Ardisasmita, M. Syamsa
1996-01-01
The Fourier transform is one of the most important mathematical tool in signal processing and analysis, which converts information from the time/spatial domain into the frequency domain. Even with implementation of the Fast Fourier Transform algorithms in imaging data, the discrete Fourier transform execution consume a lot of time. Digital signal processors are designed specifically to perform computation intensive digital signal processing algorithms. By taking advantage of the advanced architecture. parallel processing, and dedicated digital signal processing (DSP) instruction sets. This device can execute million of DSP operations per second. The device architecture, characteristics and feature suitable for fast Fourier transform application and speed-up are discussed
The use of Fourier reverse transforms in crystallographic phase refinement
Energy Technology Data Exchange (ETDEWEB)
Ringrose, Sharon [Iowa State Univ., Ames, IA (United States)
1997-10-08
Often a crystallographer obtains an electron density map which shows only part of the structure. In such cases, the phasing of the trial model is poor enough that the electron density map may show peaks in some of the atomic positions, but other atomic positions are not visible. There may also be extraneous peaks present which are not due to atomic positions. A method for determination of crystal structures that have resisted solution through normal crystallographic methods has been developed. PHASER is a series of FORTRAN programs which aids in the structure solution of poorly phased electron density maps by refining the crystallographic phases. It facilitates the refinement of such poorly phased electron density maps for difficult structures which might otherwise not be solvable. The trial model, which serves as the starting point for the phase refinement, may be acquired by several routes such as direct methods or Patterson methods. Modifications are made to the reverse transform process based on several assumptions. First, the starting electron density map is modified based on the fact that physically the electron density map must be non-negative at all points. In practice a small positive cutoff is used. A reverse Fourier transform is computed based on the modified electron density map. Secondly, the authors assume that a better electron density map will result by using the observed magnitudes of the structure factors combined with the phases calculated in the reverse transform. After convergence has been reached, more atomic positions and less extraneous peaks are observed in the refined electron density map. The starting model need not be very large to achieve success with PHASER; successful phase refinement has been achieved with a starting model that consists of only 5% of the total scattering power of the full molecule. The second part of the thesis discusses three crystal structure determinations.
Fourier transform spectrometer for Greenhouse Gases Observing Satellite (GOSAT)
Hamazaki, Takashi; Kaneko, Yutaka; Kuze, Akihiko; Kondo, Kayoko
2005-01-01
Global warming has become a very serious issue for human beings. In 1997, the Kyoto Protocol was adopted at the Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change (COP3), making it mandatory for developed nations to reduce carbon dioxide emissions by six (6) to eight (8) per cent of their total emissions in 1990, and to meet this goal sometime between 2008 and 2012. The Greenhouse gases Observing SATellite (GOSAT) is designed to monitor the global distribution of carbon dioxide (CO2) from the space. GOSAT is a joint project of Japan Aerospace Exploration Agency (JAXA), the Ministry of Environment (MOE), and the National Institute for Environmental Studies (NIES). JAXA is responsible for the satellite and instrument development, MOE is involved in the instrument development, and NIES is responsible for the satellite data retrieval. The satellite is scheduled to be launched in 2008. In order to detect the CO2 variation of boundary layers, both the technique to measure the column density and the retrieval algorithm to remove cloud and aerosol contamination are investigated. Main mission sensor of the GOSAT is a Fourier Transform Spectrometer with high optical throughput, spectral resolution and wide spectral coverage, and a cloud-aerosol detecting imager attached to the satellite. The paper presents the mission sensor system of the GOSAT together with the results of performance demonstration with proto-type instrument aboard an aircraft.
Fourier transform ion cyclotron resonance mass spectrometry: technique developments
Marshall, Alan G.; Schweikhard, Lutz
1992-09-01
In the three years since the 11th International Mass Spectrometry Conference, Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry has advanced both theoretically and experimentally with respect to ion formation and transfer to the ion trap, ion trap design and operation, ion excitation and detection, data reduction, and in chemical and analytical applications. In this short review, we shall describe several new ion sources for FT-ICR MS (e.g. high pressure, fast neutral beam, and continuous- flow atom bombardment), various new ion traps employing screens (e.g. for simultaneous trapping of positive and negative ions), guard wires (for improved isotopic abundance accuracy), and multiple sections. In addition, the ICR excitation and detection processes have recently been treated in quite full theoretical detail, leading to improved understanding of the origin and relative magnitudes of signals at multiples and combinations of the three fundamental ion frequencies: cyclotron, magnetron, and trapping. Recent chemical applications of FT-ICR MS have concentrated on ion/molecule chemistry (e.g. clusters, such as C60), whereas the primary analytical applications have come from laser desorption FT-ICR MS (e.g. polymers, surface analysis).
Ribosomal DNA Nanoprobes studied by Fourier Transform Infrared spectroscopy
Fagundes, Jaciara; Castilho, Maiara L.; Téllez Soto, Claudio A.; Vieira, Laís de Souza; Canevari, Renata A.; Fávero, Priscila P.; Martin, Airton A.; Raniero, Leandro
2014-01-01
Paracoccidioides brasiliensis (P. brasiliensis) is a thermo-dimorphic fungus that causes paracoccidioidomycosis. Brazil epidemiological data shows that endemic areas are the subtropical regions, especially where agricultural activities predominate such as the Southeast, South, and Midwest. There are several tests to diagnose paracoccidioidomycosis, but they have many limitations such as low sensitivity, high cost, and a cross-reacting problem. In this work, gold nanoprobes were used to identify P. brasiliensis as an alternative diagnostic technique, which is easier to apply, costs less, and has great potential for application. The specific Ribosomal sequence of P. brasiliensis DNA was amplified and used to design the nanoprobes using a thiol-modified oligonucleotide. The results of positive and negative tests were done by UV-visible and Fourier Transform Infrared (FT-IR) measurements. The deconvolution of FT-IR sample spectra showed differences in the vibrational modes from the hydrogen bridge NHN and NHO bands that form the double helix DNA for samples matching the DNA sequence of nanoprobes that could be used to classify the samples.
Adulteration identification in raw milk using Fourier transform infrared spectroscopy.
Coitinho, Tatiane Barbosa; Cassoli, Laerte Dagher; Cerqueira, Pedro Henrique Ramos; da Silva, Helen Krystine; Coitinho, Juliana Barbosa; Machado, Paulo Fernando
2017-07-01
Adulteration of milk is a common practice that concerns regulatory agencies, industry, and the population. Despite the growing need for checking adulteration, the current methods employed generally have low performance and are highly dependent on manual labor. This study aims to calibrate and validate a compact equipment (MilkoScan FT1) that adopts a Fourier transform infrared spectroscopy methodology to monitor adulteration in raw milk. Almost 2500 milk samples were used for reference spectrum construction and 1650 samples were used to validate the identification of the following five most commonly used adulterants (at three different concentrations each): (1) cornstarch, (2) sodium bicarbonate, (3) sodium citrate, (4) formaldehyde, and (5) saccharose, plus the additions of two levels of water or whey. To define the calibration with the best performance in milk adulteration identification, 12 calibrations involving 8, 10, 12, 14, 16, or 18 factors, with one or two outlier eliminations, were developed. The results of sensitivity and specificity analyses, as well as Kruskal-Wallis and Dunn multiple comparison tests, revealed that the calibration that best identified the adulterants was the one involving 14 factors, with a single elimination of outliers, exhibiting for all adulterants simultaneously, 84% sensitivity and 100% specificity. The calibration showed excellent sensitivity to cornstarch (>98%), sodium bicarbonate (100%), sodium citrate (99%), and formaldehyde (>84%), indicating that this calibration has good capacity for adulteration detection. Thus, this methodology is a viable option for the dairy industry to identify adulteration of raw milk.
Fourier Transform Infrared Spectroscopy and Photoacoustic Spectroscopy for Saliva Analysis.
Mikkonen, Jopi J W; Raittila, Jussi; Rieppo, Lassi; Lappalainen, Reijo; Kullaa, Arja M; Myllymaa, Sami
2016-09-01
Saliva provides a valuable tool for assessing oral and systemic diseases, but concentrations of salivary components are very small, calling the need for precise analysis methods. In this work, Fourier transform infrared (FT-IR) spectroscopy using transmission and photoacoustic (PA) modes were compared for quantitative analysis of saliva. The performance of these techniques was compared with a calibration series. The linearity of spectrum output was verified by using albumin-thiocyanate (SCN(-)) solution at different SCN(-) concentrations. Saliva samples used as a comparison were obtained from healthy subjects. Saliva droplets of 15 µL were applied on the silicon sample substrate, 6 drops for each specimen, and dried at 37 ℃ overnight. The measurements were carried out using an FT-IR spectrometer in conjunction with an accessory unit for PA measurements. The findings with both transmission and PA modes mirror each other. The major bands presented were 1500-1750 cm(-1) for proteins and 1050-1200 cm(-1) for carbohydrates. In addition, the distinct spectral band at 2050 cm(-1) derives from SCN(-) anions, which is converted by salivary peroxidases to hypothiocyanate (OSCN(-)). The correlation between the spectroscopic data with SCN(-) concentration (r > 0.990 for transmission and r = 0.967 for PA mode) was found to be significant (P < 0.01), thus promising to be utilized in future applications. © The Author(s) 2016.
Convergence and summability of Fourier transforms and Hardy spaces
Weisz, Ferenc
2017-01-01
This book investigates the convergence and summability of both one-dimensional and multi-dimensional Fourier transforms, as well as the theory of Hardy spaces. To do so, it studies a general summability method known as theta-summation, which encompasses all the well-known summability methods, such as the Fejér, Riesz, Weierstrass, Abel, Picard, Bessel and Rogosinski summations. Following on the classic books by Bary (1964) and Zygmund (1968), this is the first book that considers strong summability introduced by current methodology. A further unique aspect is that the Lebesgue points are also studied in the theory of multi-dimensional summability. In addition to classical results, results from the past 20-30 years – normally only found in scattered research papers – are also gathered and discussed, offering readers a convenient “one-stop” source to support their work. As such, the book will be useful for researchers, graduate and postgraduate students alike.
Correlation of portal images using fast fourier transform
International Nuclear Information System (INIS)
Scheffler, A.; Aletti, P.; Wolf, D.; Pennequin, J.C.; Diller, M.L.
1995-01-01
The checking of the patient's position in relation to the treatment unit is mandatory in external radiotherapy quality assurance programmes. One way of checking positions is the electronic portal imaging. An automatic control could be performed simultaneously by the correlation of a reference 256 grey levels image with the current image of the treatment field of the patient. The algorithm used to process this correlation must be fast for a practical use (a few seconds). To accelerate the computation, the cross-correlation is performed by the means of the Fast Fourier Transform as applied by Jones and Boyer. As a consequence, the calculation time is divided by three. The principle of correlation of both images consists in comparing a significant squared area in the first image to a greater squared area in the second image by point to point scanning. In order to improve the convergence of this algorithm, we have added an optimization method. Because these methods have limitations depending on the starting point, we have chosen a compromise leading to an efficient and robust detection procedure. Instead of simple point to point scanning in the reference image, a quick scanning is proposed to detect the most probable fitting area. Then, the correlation function is optimized to find corresponding points between both images. Several points allow to evaluate the displacement in pixels, in relation to the reference image. Converted into distance, this displacement translates the deviation of the positioning of the patient
Fourier-transform spatial modulation spectroscopy of single gold nanorods
Directory of Open Access Journals (Sweden)
Kollmann Heiko
2018-03-01
Full Text Available Sensing the scattered fields of single metallic nanostructures is a crucial step towards the applications of isolated plasmonic antennas, such as for the sensing of single molecules or nanoparticles. In the past, both near- and far-field spectroscopy methods have been applied to monitor single plasmonic resonances. So far, however, these spectral-domain techniques do not yet provide the femtosecond time resolution that is needed to probe the dynamics of plasmonic fields in the time domain. Here, we introduce a time-domain technique that combines broadband Fourier-transform spectroscopy and spatial modulation spectroscopy (FT-SMS to quantitatively measure the extinction spectra of the isolated gold nanorods with a nominal footprint of 41×10 nm2. Using a phase-stable pulse pair for excitation, the technique is capable of rejecting off-resonant stray fields and providing absolute measurements of the extinction cross section. Our results indicate that the method is well suited for measuring the optical response of strongly coupled hybrid systems with high signal-to-noise ratio. It may form the basis for new approaches towards time-domain spectroscopy of single nanoantennas with few-cycle time resolution.
First characterization of a static Fourier transform spectrometer
Lacan, A.; Bréon, F.-M.; Rosak, A.; Pierangelo, C.
2017-11-01
A new instrument concept for a Static Fourier Transform Spectrometer has been developed and characterized by CNES. This spectrometer is based on a Michelson interferometer concept, but a system of stepped mirrors generates all interference path differences simultaneously, without any moving parts. The instrument permits high spectral resolution measurements (≍0.1 cm-1) adapted to the sounding and the monitoring of atmospheric gases. Moreover, its overall dimensions are compatible with a micro satellite platform. The stepped mirrors are glued using a molecular bonding technique. An interference filter selects a waveband only a few nanometers wide. It limits the number of sampling points (and consequently the steps number) necessary to achieve the high resolution. The instrument concept can be optimized for the detection and the monitoring of various atmospheric constituents. CNES has developed a version whose measurements are centered on the CO2 absorption lines at 1573 nm (6357 cm-1). This model has a theoretical resolution of 40 pm (0.15 cm-1) within a 5 nm (22.5 cm-1) wide spectral window. It is aimed at the feasibility demonstration for atmospheric CO2 column measurements with a very demanding accuracy of better than 1%. Preliminary measurements indicate that, although high quality spectra are obtained, the theoretical performances are not yet achieved. We discuss the causes for the achieved performances and describe foreseen methods for their improvements.
Remote detection of organics using Fourier transform infrared spectroscopy
International Nuclear Information System (INIS)
Demirgian, J.C.; Spurgash, S.M.
1990-01-01
Fourier transform infrared (FTIR) spectroscopy is an ideal technique for remote detection of organic emissions. There is an atmospheric window in the 1200 to 800 cm -1 region, which corresponds to the ''fingerprint'' region for organic molecules. Virtually all organic molecules have a unique absorption/emission pattern in the fingerprint region. A remote-passive FTIR relies on ambient emission of infrared energy from organics to obtain spectra. The instrumentation consists of inlet optics, and interferometer, a mercury cadmium telluride (MCT) detector, and an on-board computer. The transportable unit measures 40 cm by 50 cm and has been used to collect data while mounted on a helicopter or ground vehicle. Through the use of this FTIR combined with least squares software, it is possible to analyze qualitatively and quantitatively for organic vapors from either the air or ground. The data presented will include quantitative releases of common organics present in incinerator stacks, hazardous wastes, and illegal laboratories. Data will be presented for pure compounds, mixtures, and target analytes in the presence of interfering compounds. The sensitivity, reproducibility, and the potential of the technique will be discussed. 1 ref., 8 figs., 6 tabs
Fourier transform infrared spectroscopy for analysis of kidney stones.
Khan, Aysha Habib; Imran, Sheharbano; Talati, Jamsheer; Jafri, Lena
2018-01-01
To compare the results of a chemical method of kidney stone analysis with the results of Fourier transform infrared (FT-IR) spectroscopy. Kidney stones collected between June and October 2015 were simultaneously analyzed by chemical and FT-IR methods. Kidney stones (n=449) were collected from patients from 1 to 81 years old. Most stones were from adults, with only 11.5% from children (aged 3-16 years) and 1.5% from children aged stone type, calcium oxalate monohydrate (COM, n=224), was the most common crystal, followed by uric acid and calcium oxalate dihydrate (COD, n=83). In children, the most frequently occurring type was predominantly COD (n=21), followed by COM (n=11), ammonium urate (n=10), carbonate apatite (n=6), uric acid (n=4), and cystine (n=1). Core composition in 22 stones showed ammonium urate (n=2), COM (n=2), and carbonate apatite (n=1) in five stones, while uric acid crystals were detected (n=13) by FT-IR. While chemical analysis identified 3 stones as uric acid and the rest as calcium oxalate only. Agreement between the two methods was moderate, with a kappa statistic of 0.57 (95% confidence interval, 0.5-0.64). Disagreement was noted in the analysis of 77 stones. FT-IR analysis of kidney stones can overcome many limitations associated with chemical analysis.
Chiral Process Monitoring Using Fourier Transform Microwave Spectroscopy
Neill, Justin L.; Muckle, Matt; Pate, Brooks
2017-06-01
We present the application of Fourier transform microwave (FTMW) spectroscopy in monitoring the chiral purity of components in a reaction mixture. This is of particular interest due to the increasing use of continuous pharmaceutical manufacturing processes, in which a number of attributes (including the chiral purity of the product) can change on short time scales. Therefore, new techniques that can accomplish this measurement rapidly are desired. The excellent specificity of FTMW spectroscopy, coupled with newly developed techniques for measuring enantiomeric excess in a mixture, have motivated this work. In collaboration with B. Frank Gupton (Virginia Commonwealth University), we are testing this application first with the synthesis of artemisinin. Artemisinin, a common drug for malaria treatment, is of high global health interest and subject to supply shortages, and therefore a strong candidate for continuous manufacturing. It also has moderately high molecular weight (282 amu) and seven chiral centers, making it a good candidate to test the capabilities of FTMW spectroscopy. Using a miniature cavity-enhanced FTMW spectrometer design, we aim to demonstrate selective component quantification in the reaction mixture. Future work that will be needed to fully realize this application will be discussed. R.D. Suenram, J.U. Grabow, A.Zuban, and I.Leonov, Rev. Sci. Instrum. 70, 2127 (1999).
The changes of fourier transform infrared spectrum in rat brain.
Ke, Yong; Li, Yang; Wang, Zhen-Yuan
2012-05-01
Estimation of the time since death (postmortem interval [PMI]) is one of the most difficult problems in forensic investigations, and many methods currently are utilized to estimate the PMI. The goal of this study was to investigate the changes of attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectra of rat brain from postmortem time 0-144 h. The intensity ratios of major absorbance bands were examined (I(1066)/I(1392), I(1168)/I(1392), I(1234)/I(1454), I(1301)/I(1392), I(1647)/I(2956), I(2921)/I(2850), and I(1647)/I(1539)). The spectra of rat brain displayed prominent changes with increasing PMI. The band at 2871 and 1737 per cm became weak with the time increasing and even disappeared at postmortem 96 and 72 h, respectively. A close linear correlation was shown between the relative absorption intensity and the PMI, and the I(1234) /I(1454) offered a stronger correlation (r = 0.973). Our results indicate that ATR-FTIR spectroscopy may be a useful technique for estimating the PMI. © 2011 American Academy of Forensic Sciences.
[The changes of Fourier transform infrared spectroscopy in rat's brain].
Ke, Yong; Zhang, Jian-Gang; Huang, Ping; Lu, Qing-Yang; Fan, Shuan-Liang; Xu, Yong-Cheng; Wang, Zhen-Yuan
2008-06-01
To apply Fourier transform infrared (FTIR) spectroscopy to study the process of postmortem degradation of the rat brain and to provide a new way for the estimation of postmortem interval (PMI). The rats were sacrificed by cervical dislocation and the bodies were kept in a controlled environmental chamber set at (30 +/- 2) degrees C. To measure the content of the chemical groups in postmortem rat brains at the different time points from 0 to 36 h using the FTIR spectrograph. With prolongation of PMI, the peak position of main absorbance bands in the FTIR spectra showed no significant changes, while the peak levels showed dramatic changes: (1) The relative peak intensity of 1080 cm(-1), 1238 cm(-1) (I1080/I1398, I1238/I1398) associated with nucleic acid decreased obviously; (2) The peak intensity ratio at Amide I, II (I1647/I1541) decreased; (3) The peak intensities at 1456 cm(-1) and 1398 cm(-1) showed a decreased and an increased trend, respectively; (4) Compared to the peak intensity of 1647 cm(-1), the peak intensities at 2852 cm(-1), 2871 cm(-1), 2923 cm(-1), and 2958 cm(-1) tended to increase, with only a slightly increased tendency in peak intensity of 2871 cm(-1). FTIR spectroscopy may be potentially used as an effective method for estimating the PMI in medicolegal practice using brain tissue sample.
Fourier transform nuclear magnetic resonance studies of 199Hg
International Nuclear Information System (INIS)
Krueger, H.; Lutz, O.; Nolle, A.; Schwenk, A.
1975-01-01
199 Hg Fourier Transform NMR studies of various solutions of diverse mercury salts in H 2 O and D 2 O or in the appropriate protonated and deuterated acids are reported for both Hg 2 ++ and Hg ++ . In the different solutions investigated the 199 Hg line positions depend on the concentration of the solution, on the solvents and their isotopic composition and on the temperature of the sample. A ratio of the Larmor frequency of 199 Hg and of 2 H in a Hg(NO 3 ) 2 solution in dilute DNO 3 is given. Using this ratio and the measured chemical shifts, a ratio of the Larmor frequencies of 199 Hg for infinite dilution relative to 2 H in pure D 2 O is given. From this a g 1 -factor for 199 Hg is derived and compared with the g 1 -factor of an optical pumping experiment. The resulting shielding constant is sigma (hydrated 199 Hg ++ versus 199 Hg atom) = -24.32(5) x 10 -4 . This yields an atomic reference scale for all measured NMR line shifts of mercury. (orig.) [de
Fourier Transform Infrared Imaging analysis of dental pulp inflammatory diseases.
Giorgini, E; Sabbatini, S; Conti, C; Rubini, C; Rocchetti, R; Fioroni, M; Memè, L; Orilisi, G
2017-05-01
Fourier Transform Infrared microspectroscopy let characterize the macromolecular composition and distribution of tissues and cells, by studying the interaction between infrared radiation and matter. Therefore, we hypothesize to exploit this analytical tool in the analysis of inflamed pulps, to detect the different biochemical features related to various degrees of inflammation. IR maps of 13 irreversible and 12 hyperplastic pulpitis, together with 10 normal pulps, were acquired, compared with histological findings and submitted to multivariate (HCA, PCA, SIMCA) and statistical (one-way ANOVA) analysis. The fit of convoluted bands let calculate meaningful band area ratios (means ± s.d., P infrared imaging analysis pin-pointed higher amounts of water and lower quantities of type I collagen in all inflamed pulps. Specific vibrational markers were defined for irreversible pulpitis (Lipids/Total Biomass, PhII/Total Biomass, CH 2 /CH 3 , and Ty/AII) and hyperplastic ones (OH/Total Biomass, Collagen/Total Biomass, and CH 3 Collagen/Total Biomass). The study confirmed that FTIR microspectroscopy let discriminate tissues' biological features. The infrared imaging analysis evidenced, in inflamed pulps, alterations in tissues' structure and composition. Changes in lipid metabolism, increasing amounts of tyrosine, and the occurrence of phosphorylative processes were highlighted in irreversible pulpitis, while high amounts of water and low quantities of type I collagen were detected in hyperplastic samples. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.
Toward a soft x-ray Fourier-transform spectrometer
International Nuclear Information System (INIS)
Howells, M.R.; Frank, K.; Hussain, Z.; Moler, E.J.; Reich, T.; Moeller, D.
1993-01-01
The use of Fourier transform spectroscopy (FTS) in the soft x-ray region is advocated as a possible route to spectral resolution superior to that attainable with a grating system. A technical plan is described for applying FTS to the study of the absorption spectrum of helium in the region of double ionization around 60--80 eV. The proposed scheme includes a Mach-Zehnder interferometer deformed into a rhombus shape to provide grazing incidence reflections. The path difference between the interfering beams is to be tuned by translation of a table carrying four mirrors over a range ±1 cm which, in the absence of errors generating relative tilts of the wave fronts, would provide a resolving power equal to the number of waves of path difference: half a million at 65 eV, for example. The signal-to-noise ratio of the spectrum is analyzed and for operation on an Advanced Light Source bending magnet beam line should be about 330
Large Molecule Structures by Broadband Fourier Transform Molecular Rotational Spectroscopy
Evangelisti, Luca; Seifert, Nathan A.; Spada, Lorenzo; Pate, Brooks
2016-06-01
Fourier transform molecular rotational resonance spectroscopy (FT-MRR) using pulsed jet molecular beam sources is a high-resolution spectroscopy technique that can be used for chiral analysis of molecules with multiple chiral centers. The sensitivity of the molecular rotational spectrum pattern to small changes in the three dimensional structure makes it possible to identify diastereomers without prior chemical separation. For larger molecules, there is the additional challenge that different conformations of each diastereomer may be present and these need to be differentiated from the diastereomers in the spectral analysis. Broadband rotational spectra of several larger molecules have been measured using a chirped-pulse FT-MRR spectrometer. Measurements of nootkatone (C15H22O), cedrol (C15H26O), ambroxide (C16H28O) and sclareolide (C16H26O2) are presented. These spectra are measured with high sensitivity (signal-to-noise ratio near 1,000:1) and permit structure determination of the most populated isomers using isotopic analysis of the 13C and 18O isotopologues in natural abundance. The accuracy of quantum chemistry calculations to identify diastereomers and conformers and to predict the dipole moment properties needed for three wave mixing measurements is examined.
Imaging properties of the mesooptical Fourier transform microscope for nuclear research emulsion
International Nuclear Information System (INIS)
Bencze, Gy.L.; Soroko, L.M.
1987-01-01
The optical signal transformation in the Mesooptical Fourier Transform Microscope (MFTM) for nuclear emulsion is treated in terms of Fourier Optics. A continuous conversion of the traditional optical microscope into the MFTM is followed. The images of dot-like and straight line objects given by the MFTM are discussed
International Nuclear Information System (INIS)
Raele, Marcus Paulo
2009-01-01
This study approached theoretical and experimental aspects related with the development of a polarization sensitive, Fourier domain, optical coherence tomography system (PS-FD-OCT) and its utilization on the Mueller Matrix determination. This work began with a bibliographic revision, which describes since the early studies to the actual state of the art of the technique. The mathematical formalism of Fourier domain low coherence interferometry and light polarization was performed as well. Studies based on numerical simulations, of three different algorithm types, responsible to recover the scattering profile, were done. The implemented algorithms were: Direct Fourier Transform, Interpolation and zero-filling. By the end of the simulation study, was possible to conclude that the algorithm zero-filling 2N presented better characteristics when compared with the others. In the experimental part, firstly different OCT setups were assembled and measurements were done in order to verify aspects related with the theory. Then, using a polymeric sample, birefringence images were performed, which allowed determining the sample birefringence quantitatively. Finally, images taken of different polarization states were collected, and through then images related with the Mueller Matrix elements were calculated, which were analyzed individually. (author)
Optimal Padding for the Two-Dimensional Fast Fourier Transform
Dean, Bruce H.; Aronstein, David L.; Smith, Jeffrey S.
2011-01-01
One-dimensional Fast Fourier Transform (FFT) operations work fastest on grids whose size is divisible by a power of two. Because of this, padding grids (that are not already sized to a power of two) so that their size is the next highest power of two can speed up operations. While this works well for one-dimensional grids, it does not work well for two-dimensional grids. For a two-dimensional grid, there are certain pad sizes that work better than others. Therefore, the need exists to generalize a strategy for determining optimal pad sizes. There are three steps in the FFT algorithm. The first is to perform a one-dimensional transform on each row in the grid. The second step is to transpose the resulting matrix. The third step is to perform a one-dimensional transform on each row in the resulting grid. Steps one and three both benefit from padding the row to the next highest power of two, but the second step needs a novel approach. An algorithm was developed that struck a balance between optimizing the grid pad size with prime factors that are small (which are optimal for one-dimensional operations), and with prime factors that are large (which are optimal for two-dimensional operations). This algorithm optimizes based on average run times, and is not fine-tuned for any specific application. It increases the amount of times that processor-requested data is found in the set-associative processor cache. Cache retrievals are 4-10 times faster than conventional memory retrievals. The tested implementation of the algorithm resulted in faster execution times on all platforms tested, but with varying sized grids. This is because various computer architectures process commands differently. The test grid was 512 512. Using a 540 540 grid on a Pentium V processor, the code ran 30 percent faster. On a PowerPC, a 256x256 grid worked best. A Core2Duo computer preferred either a 1040x1040 (15 percent faster) or a 1008x1008 (30 percent faster) grid. There are many industries that
Precise and fast spatial-frequency analysis using the iterative local Fourier transform.
Lee, Sukmock; Choi, Heejoo; Kim, Dae Wook
2016-09-19
The use of the discrete Fourier transform has decreased since the introduction of the fast Fourier transform (fFT), which is a numerically efficient computing process. This paper presents the iterative local Fourier transform (ilFT), a set of new processing algorithms that iteratively apply the discrete Fourier transform within a local and optimal frequency domain. The new technique achieves 210 times higher frequency resolution than the fFT within a comparable computation time. The method's superb computing efficiency, high resolution, spectrum zoom-in capability, and overall performance are evaluated and compared to other advanced high-resolution Fourier transform techniques, such as the fFT combined with several fitting methods. The effectiveness of the ilFT is demonstrated through the data analysis of a set of Talbot self-images (1280 × 1024 pixels) obtained with an experimental setup using grating in a diverging beam produced by a coherent point source.
Ogawa, Takahiro; Haseyama, Miki
2013-03-01
A missing texture reconstruction method based on an error reduction (ER) algorithm, including a novel estimation scheme of Fourier transform magnitudes is presented in this brief. In our method, Fourier transform magnitude is estimated for a target patch including missing areas, and the missing intensities are estimated by retrieving its phase based on the ER algorithm. Specifically, by monitoring errors converged in the ER algorithm, known patches whose Fourier transform magnitudes are similar to that of the target patch are selected from the target image. In the second approach, the Fourier transform magnitude of the target patch is estimated from those of the selected known patches and their corresponding errors. Consequently, by using the ER algorithm, we can estimate both the Fourier transform magnitudes and phases to reconstruct the missing areas.
International Nuclear Information System (INIS)
Tri Darwinto
2008-01-01
Methacryloyl-L-alanine methyl ester was synthesized by reacting methacrylic acid with L-alanine methyl ester hydrochloride in triethylamine at temperature of 90 o C. Hydrogel polymer of poly(methacryloyl-L-alanine methyl ester) was much used for diagnosis and therapy of vascular tumor. The molecular structure methacryloyl-L-alanine methyl ester analyzed by fourier transform nuclear magnetic resonance (FT-NMR) for analyzing of carbon atom ( 13 C) using Distortionless Enhancement by Polarization Transfer (DEPT) measurement mode with coupling as well as without coupling from proton atom ( 1 H). Molecular structure analysis result showed that DEPT FT-NMR measurement mode with coupling as well as without coupling from 1 H was very fast, exact and accurate method for molecular analysis of organic compound especially methacryloyl-L-alanine methyl ester. (author)
International Nuclear Information System (INIS)
Yamada, Yoshifumi; Liu, Na; Ito, Satoshi
2006-01-01
The signal in the Fresnel transform technique corresponds to a blurred one of the spin density image. Because the amplitudes of adjacent sampled signals have a high interrelation, the signal amplitude at a point between sampled points can be estimated with a high degree of accuracy even if the sampling is so coarse as to generate aliasing in the reconstructed images. In this report, we describe a new aliasless image reconstruction technique in the phase scrambling Fourier transform (PSFT) imaging technique in which the PSFT signals are converted to Fresnel transform signals by multiplying them by a quadratic phase term and are then interpolated using polynomial expressions to generate fully encoded signals. Numerical simulation using MR images showed that almost completely aliasless images are reconstructed by this technique. Experiments using ultra-low-field PSFT MRI were conducted, and aliasless images were reconstructed from coarsely sampled PSFT signals. (author)
Advanced multivariate data evaluation for Fourier transform infrared spectroscopy
International Nuclear Information System (INIS)
Diewok, J.
2002-12-01
The objective of the presented dissertation was the evaluation, application and further development of advanced multivariate data evaluation methods for qualitative and quantitative Fourier transform infrared (FT-IR) measurements, especially of aqueous samples. The focus was set on 'evolving systems'; i.e. chemical systems that change gradually with a master variable, such as pH, reaction time, elution time, etc. and that are increasingly encountered in analytical chemistry. FT-IR measurements on such systems yield 2-way and 3-way data sets, i.e. data matrices and cubes. The chemometric methods used were soft-modeling techniques, like multivariate curve resolution - alternating least squares (MCR-ALS) or principal component analysis (PCA), hard modeling of equilibrium systems and two-dimensional correlation spectroscopy (2D-CoS). The research results are presented in six publications and comprise: A new combination of FT-IR flow titrations and second-order calibration by MCR-ALS for the quantitative analysis of mixture samples of organic acids and sugars. A novel combination of MCR-ALS with a hard-modeled equilibrium constraint for second-order quantitation in pH-modulated samples where analytes and interferences show very similar acid-base behavior. A detailed study in which MCR-ALS and 2D-CoS are directly compared for the first time. From the analysis of simulated and experimental acid-base equilibrium systems, the performance and interpretability of the two methods is evaluated. Investigation of the binding process of vancomycin, an important antibiotic, to a cell wall analogue tripeptide by time-resolved FT-IR spectroscopy and detailed chemometric evaluation. Determination of red wine constituents by liquid chromatography with FT-IR detection and MCR-ALS for resolution of overlapped peaks. Classification of red wine cultivars from FT-IR spectroscopy of phenolic wine extracts with hierarchical clustering and soft independent modeling of class analogy (SIMCA
International Nuclear Information System (INIS)
Ji, X.; Chen, Y.M.
1989-01-01
The boundary element method (BEM) is developed from the boundary integral equation method and the discretization techniques. Compared with other numerical method, BEM has been shown to be a versatile and efficient method for a wide variety of engineering problems, including the wave propagation in elastic media. The first formulation and solution of the transient elastodynamic problem by combining BEM and Laplace transform is due to Cruse. Further improvement was achieved by introducing Durbin's method instead of Papoulis method of numerical Laplace inverse transform. However, a great deal of computer time is still needed for the inverse transformation. The alternative integral transform approach is BEM combining with Fourier transform. The numerical Fourier inverse transformation is also computer time consuming, even if the fast Fourier transform is used. In the present paper, the authors use BEM combining with Fourier transform and Fourier eigen transform (FET). The new approach is very attractive in saving on computer time. This paper illustrates the application of FET to BEM of 2-dimensional transient elastodynamic problem. The example of a half plane subjected to a discontinuous boundary load is solved on ELXSI 6400 computer. The CPU time is less than one minute. If Laplace or Fourier transform is adopted, the CPU time will be more than 10 minutes
Polar Wavelet Transform and the Associated Uncertainty Principles
Shah, Firdous A.; Tantary, Azhar Y.
2018-02-01
The polar wavelet transform- a generalized form of the classical wavelet transform has been extensively used in science and engineering for finding directional representations of signals in higher dimensions. The aim of this paper is to establish new uncertainty principles associated with the polar wavelet transforms in L2(R2). Firstly, we study some basic properties of the polar wavelet transform and then derive the associated generalized version of Heisenberg-Pauli-Weyl inequality. Finally, following the idea of Beckner (Proc. Amer. Math. Soc. 123, 1897-1905 1995), we drive the logarithmic version of uncertainty principle for the polar wavelet transforms in L2(R2).
Ma, Q.; Tipping, R. H.; Lavrentieva, N. N.
2012-01-01
By adopting a concept from signal processing, instead of starting from the correlation functions which are even, one considers the causal correlation functions whose Fourier transforms become complex. Their real and imaginary parts multiplied by 2 are the Fourier transforms of the original correlations and the subsequent Hilbert transforms, respectively. Thus, by taking this step one can complete the two previously needed transforms. However, to obviate performing the Cauchy principal integrations required in the Hilbert transforms is the greatest advantage. Meanwhile, because the causal correlations are well-bounded within the time domain and band limited in the frequency domain, one can replace their Fourier transforms by the discrete Fourier transforms and the latter can be carried out with the FFT algorithm. This replacement is justified by sampling theory because the Fourier transforms can be derived from the discrete Fourier transforms with the Nyquis rate without any distortions. We apply this method in calculating pressure induced shifts of H2O lines and obtain more reliable values. By comparing the calculated shifts with those in HITRAN 2008 and by screening both of them with the pair identity and the smooth variation rules, one can conclude many of shift values in HITRAN are not correct.
Space-charge calculations with the fast Fourier transform
International Nuclear Information System (INIS)
Vaughan, J.R.
1978-01-01
A method is described for calculating linear accelerator beam trajectories in traveling wave tubes. A grid is placed over the region of interest in which there is space charge. A matrix of the Fourier potential coefficients is obtained, and a straight Fourier synthesis is used to add these with the appropriate trigonometric multipliers to obtain the potential matrix. The pulses on a particle for the next trajectory step are found by interpolating and differencing the potentials on that matrix
Thyroid lesions diagnosis by Fourier transformed infrared absorption spectroscopy (FTIR)
International Nuclear Information System (INIS)
Albero, Felipe Guimaraes
2009-01-01
Thyroid nodules are a common disorder, with 4-7% of incidence in the Brazilian population. Although the fine needle aspiration (FNA) is an accurate method for thyroid tumors diagnosis, the discrimination between benign and malignant neoplasm is currently not possible in some cases with high incidence of false negative diagnosis, leading to a surgical intervention due to the risk of carcinomas. The aim of this study was to verify if the Fourier Transform infrared spectroscopy (FTIR) can contribute to the diagnosis of thyroid carcinomas and goiters, using samples of tissue and aspirates. Samples of FNA, homogenates and tissues of thyroid nodules with histopathological diagnosis were obtained and prepared for FTIR spectroscopy analysis. The FNA and homogenates samples were measured by μ-FTIR (between 950 . 1750 cm -1 ), at a nominal resolution of 4 cm -1 and 120 scans). Tissue samples were analyzed directly by ATR-FTIR technique, at a resolution 2 cm -1 , with 60 scans in the same region. All spectra were corrected by the baseline and normalized by amides area (1550-1640 cm -1 ) in order to minimize variations of sample homogeneity. Then, spectra were converted into second derivatives using the Savitzk-Golay algorithm with a 13 points window. The Ward's minimum variance algorithm and Euclidean distances among the points were used for cluster analysis. Some FNA samples showed complex spectral pattern. All samples showed some cell pellets and large amount of hormone, represented by the bands of 1545 and 1655 cm -1 . Bands in 1409, 1412, 1414, 1578 and 1579 cm -1 were also found, indicating possible presence of sugar, DNA, citric acid or metabolic products. In this study, it was obtained an excellent separation between goiter and malign lesion for the samples of tissues, with 100% of specificity in specific cluster and 67% sensibility and 50 of specificity. In homogenate and FNA samples this sensibility and specificity were lower, because among these samples, it were
Analysis of the physical simulation on Fourier transform infrared spectrometer
Yue, Peng-yuan; Wan, Yu-xi; Zhao, Zhen
2017-10-01
A kind of oscillating arm type Fourier Transform Infrared Spectrometer (FTS) which based on the corner cube retroreflector is presented, and its principle and properties are studied. It consists of a pair of corner cube retroreflector, beam splitter and compensator. The optical path difference(OPD) is created by oscillating reciprocating motion of the moving corner cube pair, and the OPD value is four times the physical shift value of the moving corner cube pair. Due to the basic property of corner cube retroreflector, the oscillating arm type FTS has no tilt problems. It is almost ideal for very high resolution infrared spectrometer. However, there are some factors to reduce the FTS capability. First, wavefront aberration due to the figures of these surfaces will reduce modulation of FTS system; second, corner cube retroreflector consist of three plane mirror, and orthogonal to each other. When there is a deviation from right angle, it will reduced the modulation of system; third, the apexes of corner cube retroreflector are symmetric about the surface of beam splitter, if one or both of the corner cube retroreflector is displaced laterally from its nominal position, phase of off-axis rays returning from the two arms were difference, this also contributes to loss of modulation of system. In order to solve these problems, this paper sets up a non-sequential interference model, and a small amount of oscillating arm rotation is set to realize the dynamic simulation process, the dynamic interference energy data were acquired at different times, and calculated the modulation of the FTS system. In the simulation, the influence of wedge error of beam splitter, compensator or between them were discussed; effects of oscillating arm shaft deviation from the coplanar of beam splitter was analyzed; and compensation effect of corner cube retroreflector alignment on beam splitter, oscillating arm rotary shaft alignment error is analyzed. In addition, the adjustment procedure
Optics based biometric encryption using log polar transform
Saini, Nirmala; Sinha, Aloka
2010-01-01
We propose an optics based biometric encryption technique using log polar transform. In this method, the key of the encryption process has been linked to the fingerprint of the enrolled person. The order of fractional Fourier transform and the seed values of the chaotic random phase masks in combination act as the key for the encryption process. In order to link the combined key to the fingerprint, a lookup table has been formed by the key and the log polar transform of the fingerprint. The linking algorithm not only encrypts the image of the enrolled person but also authenticates the input image. The main advantage of this method is its capability to retrieve the same key in the decryption process by using the live fingerprint. The key is not required to be communicated to the receiver side. The retrieval of the image is possible only when the live fingerprint of the enrolled person is presented at the decryption side. The real life fingerprints have been used to demonstrate the proposed technique. Simulations have been performed on the Matlab platform to validate the proposed technique. The signal to noise ratio and mean square error has been calculated in order to support the proposed technique. The effect of the rotation and the scaling of the fingerprints have been studied to check the key retrieval from the live fingerprint of the enrolled person. The study of the different whorl types of fingerprint of different persons has also been done to check the efficacy of the key retrieval from the whorl types of the live fingerprints of different person.
Xiao, Wei; Jones, Adele M; Collins, Richard N; Bligh, Mark W; Waite, T David
2017-12-01
The Fe(II)-catalyzed transformation of the poorly crystalline Fe(III) oxyhydroxide mineral, ferrihydrite (Fh), to more crystalline Fe(III) mineral species such as magnetite, goethite, and lepidocrocite has been quantitatively evaluated under various conditions using X-ray adsorption spectroscopy (XAS) and Fourier transform infrared (FTIR) spectroscopy. Using the peak height of signature FTIR peaks of sub-micron sized lepidocrocite and goethite references minerals, the FTIR results were comparable to the XAS results within experimental error. This was independent of whether the Fe(II)-catalyzed transformation was initiated by the Fe(III)-reducing bacterium Shewanella oneidensis MR-1 or by added ferrous ammonium sulfate in the presence or absence of lactate. Whilst the use of FTIR has not been previously employed to follow this transformation process, it has advantages relative to XAS including a lower sample requirement (approximately 30-fold lower), greater accessibility and greater safety of operation. Whilst problems with quantifying magnetite in the presence of lepidocrocite were identified in this study using reference Fe(III) oxyhydroxide suspensions, large amounts of magnetite were not produced during transformation under the conditions employed in this study. Reference spectra of lath-like nano-goethite particles (with dimensions of approx. 10 × 50nm) also resulted in higher IR absorbance and a slight red-shift in signature peak positions relative to sub-micron sized goethite particles with this shift potentially affecting the reliable quantification of samples of unknown size. Despite this, good agreement between the XAS and FTIR data for samples containing iron oxides undergoing continuous transformation was obtained suggesting that FTIR may be a convenient, inexpensive means of following such mineral transformations. Copyright © 2017 Elsevier B.V. All rights reserved.
The fractional Fourier transform as a simulation tool for lens-based X-ray microscopy
DEFF Research Database (Denmark)
Pedersen, Anders Filsøe; Simons, Hugh; Detlefs, Carsten
2018-01-01
The fractional Fourier transform (FrFT) is introduced as a tool for numerical simulations of X-ray wavefront propagation. By removing the strict sampling requirements encountered in typical Fourier optics, simulations using the FrFT can be carried out with much decreased detail, allowing...
Fourier transform of delayed fluorescence as an indicator of herbicide concentration.
Guo, Ya; Tan, Jinglu
2014-12-21
It is well known that delayed fluorescence (DF) from Photosystem II (PSII) of plant leaves can be potentially used to sense herbicide pollution and evaluate the effect of herbicides on plant leaves. The research of using DF as a measure of herbicides in the literature was mainly conducted in time domain and qualitative correlation was often obtained. Fourier transform is often used to analyze signals. Viewing DF signal in frequency domain through Fourier transform may allow separation of signal components and provide a quantitative method for sensing herbicides. However, there is a lack of an attempt to use Fourier transform of DF as an indicator of herbicide. In this work, the relationship between the Fourier transform of DF and herbicide concentration was theoretically modelled and analyzed, which immediately yielded a quantitative method to measure herbicide concentration in frequency domain. Experiments were performed to validate the developed method. Copyright © 2014 Elsevier Ltd. All rights reserved.
Implementation of Period-Finding Algorithm by Means of Simulating Quantum Fourier Transform
Directory of Open Access Journals (Sweden)
Zohreh Moghareh Abed
2010-01-01
Full Text Available In this paper, we introduce quantum fourier transform as a key ingredient for many useful algorithms. These algorithms make a solution for problems which is considered to be intractable problems on a classical computer. Quantum Fourier transform is propounded as a key for quantum phase estimation algorithm. In this paper our aim is the implementation of period-finding algorithm.Quantum computer solves this problem, exponentially faster than classical one. Quantum phase estimation algorithm is the key for the period-finding problem .Therefore, by means of simulating quantum Fourier transform, we are able to implement the period-finding algorithm. In this paper, the simulation of quantum Fourier transform is carried out by Matlab software.
Hill, John J.; Gennis, R. B.; Alben, James O.
1992-03-01
Photodissociation of heme-CO complexes in bacterial membranes was measured by Fourier transform infrared spectroscopy. Wavelength of the photodissociating light and selected cryogenic temperatures were used to distinguish multiple forms of respiratory enzymes (cytochromes).
Computational chemistry, in conjunction with gas chromatography/mass spectrometry/Fourier transform infrared spectrometry (GC/MS/FT-IR), was used to tentatively identify seven tetrachlorobutadiene (TCBD) isomers detected in an environmental sample. Computation of the TCBD infrare...
Improved method of generating bit reversed numbers for calculating fast fourier transform
Digital Repository Service at National Institute of Oceanography (India)
Suresh, T.
Fast Fourier Transform (FFT) is an important tool required for signal processing in defence applications. This paper reports an improved method for generating bit reversed numbers needed in calculating FFT using radix-2. The refined algorithm takes...
National Aeronautics and Space Administration — The Panchromatic Fourier Transform Spectrometer (PanFTS) is an imaging spectrometer that can measure pollutants, greenhouse gases, and aerosols as called for in the...
Scargle, Jeffrey D.; Way, M. J.; Gazis, P. G.
2017-01-01
We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform of finely binned galaxy positions. In both cases, deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fourier transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multipoint hierarchy. We identify some threads of modern large-scale inference methodology that will presumably yield detections in new wider and deeper surveys.
Fourier-transform infrared spectroscopic studies of dithia ...
Indian Academy of Sciences (India)
Unknown
limited region 1000–1150 cm–1.10 Therefore, in the present paper we report and analyse Fourier-trans- form infrared (FT-IR) spectra of S2TPP and its chemically prepared cation. 2. Experimental. Dithia tetraphenyl porphyrine was received from. Professor A L Verma as a gift and used without fur- ther purification. However ...
Static harmonization of dynamically harmonized Fourier transform ion cyclotron resonance cell.
Zhdanova, Ekaterina; Kostyukevich, Yury; Nikolaev, Eugene
2017-08-01
Static harmonization in the Fourier transform ion cyclotron resonance cell improves the resolving power of the cell and prevents dephasing of the ion cloud in the case of any trajectory of the charged particle, not necessarily axisymmetric cyclotron (as opposed to dynamic harmonization). We reveal that the Fourier transform ion cyclotron resonance cell with dynamic harmonization (paracell) is proved to be statically harmonized. The volume of the statically harmonized potential distribution increases with an increase in the number of trap segments.
Pulse shaping using the optical Fourier transform technique - for ultra-high-speed signal processing
DEFF Research Database (Denmark)
Palushani, Evarist; Oxenløwe, Leif Katsuo; Galili, Michael
2009-01-01
This paper reports on the generation of a 1.6 ps FWHM flat-top pulse using the optical Fourier transform technique. The pulse is validated in a 320 Gbit/s demultiplexing experiment.......This paper reports on the generation of a 1.6 ps FWHM flat-top pulse using the optical Fourier transform technique. The pulse is validated in a 320 Gbit/s demultiplexing experiment....
OTDM-to-WDM Conversion of Complex Modulation Formats by Time-Domain Optical Fourier Transformation
DEFF Research Database (Denmark)
Palushani, Evarist; Richter, T.; Ludwig, R.
2012-01-01
We demonstrate the utilization of the optical Fourier transform technique for serial-to-parallel conversion of 64×10-GBd OTDM data tributaries with complex modulation formats into 50-GHz DWDM grid without loss of phase and amplitude information.......We demonstrate the utilization of the optical Fourier transform technique for serial-to-parallel conversion of 64×10-GBd OTDM data tributaries with complex modulation formats into 50-GHz DWDM grid without loss of phase and amplitude information....
Time-Domain Optical Fourier Transformation for OTDM-DWDM and DWDM-OTDM Conversion
DEFF Research Database (Denmark)
Mulvad, Hans Christian Hansen; Palushani, Evarist; Galili, Michael
2011-01-01
Applications of time-domain optical Fourier transformation (OFT) in ultra-high-speed optical time-division multiplexed systems (OTDM) are reviewed, with emphasis on the recent demonstrations of OFT-based conversion between the OTDM and DWDM formats.......Applications of time-domain optical Fourier transformation (OFT) in ultra-high-speed optical time-division multiplexed systems (OTDM) are reviewed, with emphasis on the recent demonstrations of OFT-based conversion between the OTDM and DWDM formats....
Analysis and application of Fourier transform spectroscopy in atmospheric remote sensing
Park, J. H.
1984-01-01
An analysis method for Fourier transform spectroscopy is summarized with applications to various types of distortion in atmospheric absorption spectra. This analysis method includes the fast Fourier transform method for simulating the interferometric spectrum and the nonlinear least-squares method for retrieving the information from a measured spectrum. It is shown that spectral distortions can be simulated quite well and that the correct information can be retrieved from a distorted spectrum by this analysis technique.
Accelerating the Non-equispaced Fast Fourier Transform on Commodity Graphics Hardware
DEFF Research Database (Denmark)
Sørensen, Thomas Sangild; Schaeffter, Tobias; Noe, Karsten Østergaard
2008-01-01
We present a fast parallel algorithm to compute the Non-equispaced fast Fourier transform on commodity graphics hardware (the GPU). We focus particularly on a novel implementation of the convolution step in the transform, which was previously its most time consuming part. We describe the performa......We present a fast parallel algorithm to compute the Non-equispaced fast Fourier transform on commodity graphics hardware (the GPU). We focus particularly on a novel implementation of the convolution step in the transform, which was previously its most time consuming part. We describe...
Magneto-sensor circuit efficiency incremented by Fourier-transformation
Talukdar, Abdul Hafiz Ibne
2011-10-01
In this paper detection by recognized intelligent algorithm for different magnetic films with the aid of a cost-effective and simple high efficient circuit are realized. Well-known, magnetic films generate oscillating frequencies when they stay a part of an LC- oscillatory circuit. These frequencies can be further analyzed to gather information about their magnetic properties. For the first time in this work we apply the signal analysis in frequency domain to create the Fourier frequency spectra which was used to detect the sample properties and their recognition. In this paper we have summarized both the simulation and experimental results. © 2011 Elsevier Ltd. All rights reserved.
Generating bit reversed numbers for calculating fast fourier transform
Digital Repository Service at National Institute of Oceanography (India)
Suresh, T.
, National Institute of Oceanography for the encouragement and suggestions. I am also grateful to Mr. S. Jai Sankar for assistance in preparing the manuscript. REFERENCES Ahmed, N., and Rao, K. R., 1975, Orthogonal transforms for digital signal...
Nonlinear Fourier transforms for the sine-Gordon equation in the quarter plane
Huang, Lin; Lenells, Jonatan
2018-03-01
Using the Unified Transform, also known as the Fokas method, the solution of the sine-Gordon equation in the quarter plane can be expressed in terms of the solution of a matrix Riemann-Hilbert problem whose definition involves four spectral functions a , b , A , B. The functions a (k) and b (k) are defined via a nonlinear Fourier transform of the initial data, whereas A (k) and B (k) are defined via a nonlinear Fourier transform of the boundary values. In this paper, we provide an extensive study of these nonlinear Fourier transforms and the associated eigenfunctions under weak regularity and decay assumptions on the initial and boundary values. The results can be used to determine the long-time asymptotics of the sine-Gordon quarter-plane solution via nonlinear steepest descent techniques.
Does the Entorhinal Cortex use the Fourier Transform?
Directory of Open Access Journals (Sweden)
Jeff eOrchard
2013-12-01
Full Text Available Some neurons in the entorhinal cortex (EC fire bursts when the animal occupies locations organized in a hexagonal grid pattern in their spatial environment. Place cells have also been observed, firing bursts only when the animal occupies a particular region of the environment. Both of these types of cells exhibit theta-cycle modulation, firing bursts in the 4-12Hz range. Grid cells fire bursts of action potentials that precess with respect to the theta cycle, a phenomenon dubbed "theta precession". Various models have been proposed to explain these phenomena, and how they relate to navigation. Among the most promising are the oscillator interference models. The bank-of-oscillators model proposed by Welday et al. (2011 exhibits all these features. However, their simulations are based on theoretical oscillators, and not implemented entirely with spiking neurons. We extend their work in a number of ways. First, we place the oscillators in a frequency domain and reformulate the model in terms of Fourier theory. Second, this perspective suggests a division of labour for implementing spatial maps: position, versus map layout. The animal's position is encoded in the phases of the oscillators, while the spatial map shape is encoded implicitly in the weights of the connections between the oscillators and the read-out nodes. Third, it reveals that the oscillator phases all need to conform to a linear relationship across the frequency domain. Fourth, we implement a partial model of the EC using spiking leaky integrate-and-fire (LIF neurons. Fifth, we devise new coupling mechanisms, enlightened by the global phase constraint, and show they are capable of keeping spiking neural oscillators in consistent formation. Our model demonstrates place cells, grid cells, and phase precession. The Fourier model also gives direction for future investigations, such as integrating sensory feedback to combat drift, or explaining why grid cells exist at all.
Does the entorhinal cortex use the Fourier transform?
Orchard, Jeff; Yang, Hao; Ji, Xiang
2013-01-01
Some neurons in the entorhinal cortex (EC) fire bursts when the animal occupies locations organized in a hexagonal grid pattern in their spatial environment. Place cells have also been observed, firing bursts only when the animal occupies a particular region of the environment. Both of these types of cells exhibit theta-cycle modulation, firing bursts in the 4–12 Hz range. Grid cells fire bursts of action potentials that precess with respect to the theta cycle, a phenomenon dubbed “theta precession.” Various models have been proposed to explain these phenomena, and how they relate to navigation. Among the most promising are the oscillator interference models. The bank-of-oscillators model proposed by Welday et al. (2011) exhibits all these features. However, their simulations are based on theoretical oscillators, and not implemented entirely with spiking neurons. We extend their work in a number of ways. First, we place the oscillators in a frequency domain and reformulate the model in terms of Fourier theory. Second, this perspective suggests a division of labor for implementing spatial maps: position vs. map layout. The animal's position is encoded in the phases of the oscillators, while the spatial map shape is encoded implicitly in the weights of the connections between the oscillators and the read-out nodes. Third, it reveals that the oscillator phases all need to conform to a linear relationship across the frequency domain. Fourth, we implement a partial model of the EC using spiking leaky integrate-and-fire (LIF) neurons. Fifth, we devise new coupling mechanisms, enlightened by the global phase constraint, and show they are capable of keeping spiking neural oscillators in consistent formation. Our model demonstrates place cells, grid cells, and phase precession. The Fourier model also gives direction for future investigations, such as integrating sensory feedback to combat drift, or explaining why grid cells exist at all. PMID:24376415
Fourier transform and controlling of flux in scalar hysteresis measurement
International Nuclear Information System (INIS)
Kuczmann, Miklos
2008-01-01
The paper deals with a possible realization of eliminating the effect of noise in scalar hysteresis measurements. The measured signals have been transformed into the frequency domain, and, after applying digital filter, the spectrums of the filtered signals have been transformed back to the time domain. The proposed technique results in an accurate noise-removal algorithm. The paper illustrates a fast controlling algorithm applying the inverse of the actually measured hysteresis loop, and another proportional one to measure distorted flux pattern. By developing the mentioned algorithms, it aims at the controlling of a more complicated phenomena, i.e. measuring the vector hysteresis characteristics
Large quantum Fourier transforms are never exactly realized by braiding conformal blocks
International Nuclear Information System (INIS)
Freedman, Michael H.; Wang, Zhenghan
2007-01-01
Fourier transform is an essential ingredient in Shor's factoring algorithm. In the standard quantum circuit model with the gate set {U(2), controlled-NOT}, the discrete Fourier transforms F N =(ω ij ) NxN , i,j=0,1,...,N-1, ω=e 2πi at ∼sol∼ at N , can be realized exactly by quantum circuits of size O(n 2 ), n=ln N, and so can the discrete sine or cosine transforms. In topological quantum computing, the simplest universal topological quantum computer is based on the Fibonacci (2+1)-topological quantum field theory (TQFT), where the standard quantum circuits are replaced by unitary transformations realized by braiding conformal blocks. We report here that the large Fourier transforms F N and the discrete sine or cosine transforms can never be realized exactly by braiding conformal blocks for a fixed TQFT. It follows that an approximation is unavoidable in the implementation of Fourier transforms by braiding conformal blocks
Jiang, Hongzhen; Liu, Xu; Liu, Yong; Li, Dong; Chen, Zhu; Zheng, Fanglan; Yu, Deqiang
2017-10-01
An effective approach for reconstructing on-axis lensless Fourier Transform digital hologram by using the screen division method is proposed. Firstly, the on-axis Fourier Transform digital hologram is divided into sub-holograms. Then the reconstruction result of every sub-hologram is obtained according to the position of corresponding sub-hologram in the hologram reconstruction plane with Fourier transform operation. Finally, the reconstruction image of on-axis Fourier Transform digital hologram can be acquired by the superposition of the reconstruction result of sub-holograms. Compared with the traditional reconstruction method with the phase shifting technology, in which multiple digital holograms are required to record for obtaining the reconstruction image, this method can obtain the reconstruction image with only one digital hologram and therefore greatly simplify the recording and reconstruction process of on-axis lensless Fourier Transform digital holography. The effectiveness of the proposed method is well proved with the experimental results and it will have potential application foreground in the holographic measurement and display field.
Fourier analysis for rotating-element ellipsometers.
Cho, Yong Jai; Chegal, Won; Cho, Hyun Mo
2011-01-15
We introduce a Fourier analysis of the waveform of periodic light-irradiance variation to capture Fourier coefficients for multichannel rotating-element ellipsometers. In this analysis, the Fourier coefficients for a sample are obtained using a discrete Fourier transform on the exposures. The analysis gives a generic function that encompasses the discrete Fourier transform or the Hadamard transform, depending on the specific conditions. Unlike the Hadamard transform, a well-known data acquisition method that is used only for conventional multichannel rotating-element ellipsometers with line arrays with specific readout-mode timing, this Fourier analysis is applicable to various line arrays with either nonoverlap or overlap readout-mode timing. To assess the effects of the novel Fourier analysis, the Fourier coefficients for a sample were measured with a custom-built rotating-polarizer ellipsometer, using this Fourier analysis with various numbers of scans, integration times, and rotational speeds of the polarizer.
Method of local pointed function reduction of original shape in Fourier transformation
International Nuclear Information System (INIS)
Dosch, H.; Slavyanov, S.Yu.
2002-01-01
The method for analytical reduction of the original shape in the one-dimensional Fourier transformation by the fourier image modulus is proposed. The basic concept of the method consists in the presentation of the model shape in the form of the local peak functions sum. The eigenfunctions, generated by the linear differential equations with the polynomial coefficients, are selected as the latter ones. This provides for the possibility of managing the Fourier transformation without numerical integration. This reduces the reverse task to the nonlinear regression with a small number of the evaluated parameters and to the numerical or asymptotic study on the model peak functions - the eigenfunctions of the differential tasks and their fourier images [ru
Collisional Detachment of Anions using Fourier Transform Mass Spectrometry
1992-12-01
cross section. which itself may be the object of the measurement. Two pressure gauges are employed to monitor system pressure: a standard nude ion...Transform Ion Cyclotron Res- onance Mass Spectrometry: The Teen Years," Analytical Chemistry, 63:215A-229A (February 1991). 88. Marshall, Alan G., et al
Fourier-transform far-infrared spectroscopic ellipsometry for standoff material identification
Energy Technology Data Exchange (ETDEWEB)
Ortolani, Michele, E-mail: michele.ortolani@ifn.cnr.i [Consiglio Nazionale delle Ricerche, Istituto di Fotonica e Nanotecnologie, Via Cineto Romano 42, I-00156 Rome (Italy); Schade, Ulrich [Helmholtz Zentrum Berlin fuer Materialen und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin (Germany)
2010-11-11
The ellipsometry is an efficient method to determine the optical properties of matter. It has been largely employed with grating spectrometers in the visible, UV and near-infrared ranges for the characterization of thin films, surfaces and interfaces. In the mid- and far-infrared, where most substance-specific absorption lines are present, spectroscopic ellipsometry with Fourier-transform spectrometers is still not extended as a routine method. In particular, the lack of powerful sources in the far-infrared/terahertz range has prevented standoff application of this method. We will show that it is possible to measure the complex dielectric constant of a solid in the far-infrared and terahertz range by a reflection experiment with polarized light and ellipsometric analysis with a suitable calibration procedure. Extraction of terahertz synchrotron radiation from storage rings provides a suitable source for research-grade experiments. The optical constants determined by ellipsometry compare well with those obtained by Kramers-Kronig procedures, a method which, however, requires broader frequency range and absolute reflectance standard. We will present the case of remote spectroscopic identification of explosive materials, which is relevant for forthcoming security applications.
Li, Shi-Ying; Zou, Dong-Hua; Luo, Yi-Wen; Sun, Qi-Ran; Deng, Kai-Fei; Chen, Yi-Jiu; Huang, Ping
2014-01-01
This technical note describes a method for distinguishing normal skin tissue samples from those electrically injured by Fourier transform infrared microspectroscopy (FTIR MSP). Furthermore, the infrared spectral features of electrically injured cells and tissues were evaluated to identify molecular changes in epidermal cells. In the present study, 20 human hand tissue samples were evaluated macroscopically and histopathologically. The electrically injured skin samples were subdivided into 2 regions [normal cell regions (NCRs) and polarized cell regions (PCRs)] and 14 major spectral absorption bands were selected. The spectral results showed that the band absorbance at 1080, 1126, 1172, 1242, 1307, 1403, 1456, 1541, 2852, 2925, 2957, 3075, and 3300cm(-1) increased significantly both in the stratum and non-stratum corneum of the PCRs in electrically injured skin tissues samples. No significant difference was found between normal skin and the NCR of the electrically injured skin samples. The band absorbance ratios of A1172/A1126, A1456/A1403, and A2925/A2957 were significantly increased, whereas the A1652/A1541 ratio was decreased in the PCR of the stratum corneum and non-stratum corneum. Baseline changes from 4000 to near 1737cm(-1) were observed in the spectra of the electrically injured skin samples, which were interpreted in terms of the pathological process involved in electrical injury. FTIR-MSP presents a useful method to provide objective spectral markers for the assisted diagnosis of electrical marks. © 2013.
Directory of Open Access Journals (Sweden)
Bidthanapally Aruna
2008-10-01
Full Text Available Abstract Background Fourier Transform Infrared Imaging (FTIRI is used to investigate the amide anisotropies at different surfaces of a three-dimensional cartilage or tendon block. With the change in the polarization state of the incident infrared light, the resulting anisotropic behavior of the tissue structure is described here. Methods Thin sections (6 μm thick were obtained from three different surfaces of the canine tissue blocks and imaged at 6.25 μm pixel resolution. For each section, infrared imaging experiments were repeated thirteen times with the identical parameters except a 15° increment of the analyzer's angle in the 0° – 180° angular space. The anisotropies of amide I and amide II components were studied in order to probe the orientation of the collagen fibrils at different tissue surfaces. Results For tendon, the anisotropy of amide I and amide II components in parallel sections is comparable to that of regular sections; and tendon's cross sections show distinct, but weak anisotropic behavior for both the amide components. For articular cartilage, parallel sections in the superficial zone have the expected infrared anisotropy that is consistent with that of regular sections. The parallel sections in the radial zone, however, have a nearly isotropic amide II absorption and a distinct amide I anisotropy. Conclusion From the inconsistency in amide anisotropy between superficial to radial zone in parallel section results, a schematic model is used to explain the origins of these amide anisotropies in cartilage and tendon.
Grid-Based Fourier Transform Phase Contrast Imaging
Tahir, Sajjad
Low contrast in x-ray attenuation imaging between different materials of low electron density is a limitation of traditional x-ray radiography. Phase contrast imaging offers the potential to improve the contrast between such materials, but due to the requirements on the spatial coherence of the x-ray beam, practical implementation of such systems with tabletop (i.e. non-synchrotron) sources has been limited. One recently developed phase imaging technique employs multiple fine-pitched gratings. However, the strict manufacturing tolerances and precise alignment requirements have limited the widespread adoption of grating-based techniques. In this work, we have investigated a technique recently demonstrated by Bennett et al. that utilizes a single grid of much coarser pitch. Our system consisted of a low power 100 microm spot Mo source, a CCD with 22 microm pixel pitch, and either a focused mammography linear grid or a stainless steel woven mesh. Phase is extracted from a single image by windowing and comparing data localized about harmonics of the grid in the Fourier domain. A Matlab code was written to perform the image processing. For the first time, the effects on the diffraction phase contrast and scattering amplitude images of varying grid types and periods, and of varying the window function type used to separate the harmonics, and the window widths, were investigated. Using the wire mesh, derivatives of the phase along two orthogonal directions were obtained and new methods investigated to form improved phase contrast images.
van Agthoven, Maria A; Barrow, Mark P; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B
2015-12-01
Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules. Graphical Abstract ᅟ.
Functional differential equations for the q-Fourier transform of q-Gaussians
International Nuclear Information System (INIS)
Umarov, S; Queiros, S M Duarte
2010-01-01
In this paper the question 'is the q-Fourier transform of a q-Gaussian a q'-Gaussian (with some q') up to a constant factor?' is studied for the whole range of q in (- infty, 3). This question is connected with applicability of the q-Fourier transform in the study of limit processes in nonextensive statistical mechanics. Using the functional differential equation approach we prove that the answer is affirmative if and only if 1 ≤ q < 3, excluding two particular cases of q < 1, namely q=1/2 and q=2/3. Complementarily, we discuss some applications of the q-Fourier transform to nonlinear partial differential equations such as the porous medium equation.
Gong, Li-Hua; He, Xiang-Tao; Tan, Ru-Chao; Zhou, Zhi-Hong
2018-01-01
In order to obtain high-quality color images, it is important to keep the hue component unchanged while emphasize the intensity or saturation component. As a public color model, Hue-Saturation Intensity (HSI) model is commonly used in image processing. A new single channel quantum color image encryption algorithm based on HSI model and quantum Fourier transform (QFT) is investigated, where the color components of the original color image are converted to HSI and the logistic map is employed to diffuse the relationship of pixels in color components. Subsequently, quantum Fourier transform is exploited to fulfill the encryption. The cipher-text is a combination of a gray image and a phase matrix. Simulations and theoretical analyses demonstrate that the proposed single channel quantum color image encryption scheme based on the HSI model and quantum Fourier transform is secure and effective.
Munoz, R. M. (Inventor)
1974-01-01
An input analog signal to be frequency analyzed is separated into N number of simultaneous analog signal components each identical to the original but delayed relative to the original by a successively larger time delay. The separated and delayed analog components are combined together in a suitable number of adders and attenuators in accordance with at least one component product of the continuous Fourier transform and analog signal matrices to separate the analog input signal into at least one of its continuous analog frequency components of bandwidth 1/N times the bandwidth of the original input signal. The original analog input signal can be reconstituted by combining the separate analog frequency components in accordance with the component products of the continuous Fourier transform and analog frequency component matrices. The continuous Fourier transformation is useful for spectrum analysis, filtering, transfer function synthesis, and communications.
Fourier-transform spectroscopy: new methods and applications: introduction by the feature editors
Traub, Wesley A.; Winkel, Raymond J., Jr.; Goldman, Aaron
1996-06-01
We are pleased to introduce this special issue of papers on Fourier-transform spectroscopy, which grew out of a recent topical meeting sponsored by the Optical Society of America. The topical meeting welcomed all researchers who practice the art of Fourier-transform spectroscopy in the laboratory, in the atmosphere, and in space. The power and the wide applicability of Fourier-transform spectroscopy unite these fields with a common mathematical and instrumental bond. The meeting probed each of these areas in depth, bringing out new ideas for instrumentation, analysis, and applications. There was a strong sentiment at the meeting that the quality of papers and posters was exceptionally high and that it would be important for future progress in the field to have the results of this meeting captured in print. This special issue is the fruit of that effort.
Goodman, Roe W
2016-01-01
This textbook for undergraduate mathematics, science, and engineering students introduces the theory and applications of discrete Fourier and wavelet transforms using elementary linear algebra, without assuming prior knowledge of signal processing or advanced analysis.It explains how to use the Fourier matrix to extract frequency information from a digital signal and how to use circulant matrices to emphasize selected frequency ranges. It introduces discrete wavelet transforms for digital signals through the lifting method and illustrates through examples and computer explorations how these transforms are used in signal and image processing. Then the general theory of discrete wavelet transforms is developed via the matrix algebra of two-channel filter banks. Finally, wavelet transforms for analog signals are constructed based on filter bank results already presented, and the mathematical framework of multiresolution analysis is examined.
q-Extension of Mehta's eigenvectors of the finite Fourier transform for q, a root of unity
Atakishiyeva, M.K.; Atakishiyev, N.M.; Koornwinder, T.H.
2009-01-01
It is shown that the continuous q-Hermite polynomials for q, a root of unity, have simple transformation properties with respect to the classical Fourier transform. This result is then used to construct q-extended eigenvectors of the finite Fourier transform in terms of these polynomials.
Directory of Open Access Journals (Sweden)
Sarunya Kanjanawattana
2017-07-01
Full Text Available Image classification plays a vital role in many areas of study, such as data mining and image processing; however, serious problems collectively referred to as the course of dimensionality have been encountered in previous studies as factors that reduce system performance. Furthermore, we also confront the problem of different graph characteristics even if graphs belong to same types. In this study, we propose a novel method of graph-type classification. Using our approach, we open up a new solution of high-dimensional images and address problems of different characteristics by converting graph images to one dimension with a discrete Fourier transformation and creating numeric datasets using wavelet and Hough transformations. Moreover, we introduce a new classifier, which is a combination between artificial neuron networks (ANNs and support vector machines (SVMs, which we call ANNSVM, to enhance accuracy. The objectives of our study are to propose an effective graph-type classification method that includes finding a new data representative used for classification instead of two-dimensional images and to investigate what features make our data separable. To evaluate the method of our study, we conducted five experiments with different methods and datasets. The input dataset we focused on was a numeric dataset containing wavelet coefficients and outputs of a Hough transformation. From our experimental results, we observed that the highest accuracy was provided using our method with Coiflet 1, which achieved a 0.91 accuracy.
Linear and Nonlinear Crosstalk Evaluation in DWDM Networks Using Optical Fourier Transformers
Directory of Open Access Journals (Sweden)
J. Marti
2005-06-01
Full Text Available A novel DWDM channel monitoring technique based on the conversion from wavelength domain to time domain by performing a real-time optical Fourier transform over the whole DWDM system bandwidth is proposed and experimentally demonstrated. The use of chromatic dispersion-based optical Fourier transformers has been validated in the case of a spectrum comprising light from different uncorrelated sources. Linear and nonlinear crosstalks between the DWDM channels appear as amplitude noise at specific time positions. The correspondence of this amplitude noise with the crosstalk spectral distribution is evaluated theoretically and experimentally.
Dong, Jun; Jia, Shuhai; Jiang, Chao
2017-11-01
This paper presents a multi-illumination lensless Fourier transform digital holographic interferometry method for surface shape measurement. In this method, the interference phases with different effective synthetic wavelengths are obtained by tilting the illumination angle several times, and all are wrapped. A Fourier-transform demodulation algorithm employing all these wrapped phases simultaneously is used to determine the object surface shape. No phase unwrapping procedure is required, and the shape information of each point is calculated independently, thereby offering great flexibility for measuring objects with discontinuities surface, such as holes, steps and gaps. Experimental results demonstrate the validity of the principle.
DWDM-TO-OTDM Conversion by Time-Domain Optical Fourier Transformation
DEFF Research Database (Denmark)
Mulvad, Hans Christian Hansen; Hu, Hao; Galili, Michael
2011-01-01
We propose DWDM-OTDM conversion by time-domain optical Fourier transformation. Error-free conversion of a 16×10 Gbit/s 50 GHz-spacing DWDM data signal to a 160 Gbit/s OTDM signal with a 2.1 dB average penalty is demonstrated.......We propose DWDM-OTDM conversion by time-domain optical Fourier transformation. Error-free conversion of a 16×10 Gbit/s 50 GHz-spacing DWDM data signal to a 160 Gbit/s OTDM signal with a 2.1 dB average penalty is demonstrated....
OTDM-WDM Conversion Based on Time-Domain Optical Fourier Transformation with Spectral Compression
DEFF Research Database (Denmark)
Mulvad, Hans Christian Hansen; Palushani, Evarist; Galili, Michael
2011-01-01
We propose a scheme enabling direct serial-to-parallel conversion of OTDM data tributaries onto a WDM grid, based on optical Fourier transformation with spectral compression. Demonstrations on 320 Gbit/s and 640 Gbit/s OTDM data are shown.......We propose a scheme enabling direct serial-to-parallel conversion of OTDM data tributaries onto a WDM grid, based on optical Fourier transformation with spectral compression. Demonstrations on 320 Gbit/s and 640 Gbit/s OTDM data are shown....
Chen, Hang; Liu, Zhengjun; Chen, Qi; Blondel, Walter; Varis, Pierre
2018-05-01
In this letter, what we believe is a new technique for optical color image encryption by using Fresnel diffraction and a phase modulation in an extended fractional Fourier transform domain is proposed. Different from the RGB component separation based method, the color image is converted into one component by improved Chirikov mapping. The encryption system is addressed with Fresnel diffraction and phase modulation. A pair of lenses is placed into the fractional Fourier transform system for the modulation of beam propagation. The structure parameters of the optical system and parameters in Chirikov mapping serve as extra keys. Some numerical simulations are given to test the validity of the proposed cryptosystem.
Physiological response of Arundo donax to cadmium stress by Fourier transform infrared spectroscopy.
Yu, Shunhui; Sheng, Li; Zhang, Chunyan; Deng, Hongping
2018-06-05
The present paper deals with the physiological response of the changes in chemical contents of the root, stem and leaf of Arundo donax seedlings stressed by excess cadmium using Fourier transform infrared spectroscopy technique, cadmium accumulation in plant by atomic absorption spectroscopy were tested after different concentrations cadmium stress. The results showed that low cadmium concentrations (Fourier transform infrared spectroscopy technique for the non-invasive and rapid monitoring of the plants stressed with heavy metals, Arundo donax is suitable for phytoremediation of cadmium -contaminated wetland. Copyright © 2018 Elsevier B.V. All rights reserved.
International Nuclear Information System (INIS)
Underwood, D.
1986-01-01
Simple examples of finding tracks by Fourier transform with filter or correlation function are presented. Possibilities for using this method in more complicated real situations and the processing times which might be achieved are discussed. The method imitates the simplest examples in the literature on optical pattern recognition and optical processing. The possible benefits of the method are in speed of processing in the optical Fourier transform wherein an entire picture is processed simultaneously. The speed of a computer vector processor may be competitive with present electro-optical devices. 2 refs., 6 figs
The Fourier transform as a signature for chaos in nuclear energy levels
International Nuclear Information System (INIS)
Bybee, C.R.; Mitchell, G.E.; Shriner, J.F. Jr.
1996-01-01
The Fourier transform of the autocorrelation function is an alternative test to characterize level statistics. For GOE statistics there is a suppression of the Fourier transform near the origin; this correlation hole is absent for Poisson statistics. Numerical modeling has been used to quantify the method and determine the dependence of the correlation-hole area on number, density, sampling interval, and fraction of missing or spurious levels. For large N the normalized correlation-hole area is a nearly universal constant and insensitive to missing and spurious levels. However, for the smaller sample sizes typical of nuclear data, application of the FT method yields ambiguous results. (orig.)
DEFF Research Database (Denmark)
Guan, Pengyu; Da Ros, Francesco; Lillieholm, Mads
2016-01-01
We demonstrate simultaneous phase regeneration of 16-WDM DPSK channels using optical Fourier transformation and a single phase-sensitive amplifier. The BERs of 16-WDM×10-Gbit/s phase noise degraded DPSK signals are improved by 0.4-1.3 orders of magnitude......We demonstrate simultaneous phase regeneration of 16-WDM DPSK channels using optical Fourier transformation and a single phase-sensitive amplifier. The BERs of 16-WDM×10-Gbit/s phase noise degraded DPSK signals are improved by 0.4-1.3 orders of magnitude...
DEFF Research Database (Denmark)
Guan, Pengyu; Røge, Kasper Meldgaard; Kjøller, Niels-Kristian
2015-01-01
We propose a novel all-optical WDM regeneration scheme for DPSK signals based on optical Fourier transformation and phase sensitive amplification. Phase regeneration of a WDM signal consisting of 4x10-Gbit/s phase noise degraded DPSK channels is demonstrated for the first time.......We propose a novel all-optical WDM regeneration scheme for DPSK signals based on optical Fourier transformation and phase sensitive amplification. Phase regeneration of a WDM signal consisting of 4x10-Gbit/s phase noise degraded DPSK channels is demonstrated for the first time....
Deficiencies of the cryptography based on multiple-parameter fractional Fourier transform.
Ran, Qiwen; Zhang, Haiying; Zhang, Jin; Tan, Liying; Ma, Jing
2009-06-01
Methods of image encryption based on fractional Fourier transform have an incipient flaw in security. We show that the schemes have the deficiency that one group of encryption keys has many groups of keys to decrypt the encrypted image correctly for several reasons. In some schemes, many factors result in the deficiencies, such as the encryption scheme based on multiple-parameter fractional Fourier transform [Opt. Lett.33, 581 (2008)]. A modified method is proposed to avoid all the deficiencies. Security and reliability are greatly improved without increasing the complexity of the encryption process. (c) 2009 Optical Society of America.
National Aeronautics and Space Administration — Fourier transform spectroscopy (FTS) in infrared wavelength range is an effective measure for global greenhouse gas monitoring. However, conventional FTS instruments...
Novel Polynomial Basis with Fast Fourier Transform and Its Application to Reed-Solomon Erasure Codes
Lin, Sian-Jheng
2016-09-13
In this paper, we present a fast Fourier transform (FFT) algorithm over extension binary fields, where the polynomial is represented in a non-standard basis. The proposed Fourier-like transform requires O(h lg(h)) field operations, where h is the number of evaluation points. Based on the proposed Fourier-like algorithm, we then develop the encoding/ decoding algorithms for (n = 2m; k) Reed-Solomon erasure codes. The proposed encoding/erasure decoding algorithm requires O(n lg(n)), in both additive and multiplicative complexities. As the complexity leading factor is small, the proposed algorithms are advantageous in practical applications. Finally, the approaches to convert the basis between the monomial basis and the new basis are proposed.
Czech Academy of Sciences Publication Activity Database
Pivokonský, Radek; Filip, Petr; Zelenková, Jana
2016-01-01
Roč. 104, č. 8 (2016), s. 171-178 ISSN 0032-3861 Institutional support: RVO:67985874 Keywords : LAOS * fourier transform rheology * Giesekus model * PTT model * modified XPP model * poly( ethylene oxide ) Subject RIV: BK - Fluid Dynamics Impact factor: 3.684, year: 2016
Bronneberg, A. C.; Smets, A. H. M.; Creatore, M.; M. C. M. van de Sanden,
2011-01-01
Insight into the oxidation mechanism of microcrystalline silicon thin films has been obtained by means of Fourier transform infrared spectroscopy. The films were deposited by using the expanding thermal plasma and their oxidation upon air exposure was followed in time. Transmission spectra were
Our presentation will focus on continuing efforts to examine secondary cell wall development in cotton fibers using infrared Spectroscopy. Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-...
Nonuniform fast Fourier transform method for numerical diffraction simulation on tilted planes.
Xiao, Yu; Tang, Xiahui; Qin, Yingxiong; Peng, Hao; Wang, Wei; Zhong, Lijing
2016-10-01
The method, based on the rotation of the angular spectrum in the frequency domain, is generally used for the diffraction simulation between the tilted planes. Due to the rotation of the angular spectrum, the interval between the sampling points in the Fourier domain is not even. For the conventional fast Fourier transform (FFT)-based methods, a spectrum interpolation is needed to get the approximate sampling value on the equidistant sampling points. However, due to the numerical error caused by the spectrum interpolation, the calculation accuracy degrades very quickly as the rotation angle increases. Here, the diffraction propagation between the tilted planes is transformed into a problem about the discrete Fourier transform on the uneven sampling points, which can be evaluated effectively and precisely through the nonuniform fast Fourier transform method (NUFFT). The most important advantage of this method is that the conventional spectrum interpolation is avoided and the high calculation accuracy can be guaranteed for different rotation angles, even when the rotation angle is close to π/2. Also, its calculation efficiency is comparable with that of the conventional FFT-based methods. Numerical examples as well as a discussion about the calculation accuracy and the sampling method are presented.
On the Elliptic Nonabelian Fourier Transform for Unipotent Representations of p-Adic Groups
Ciubotaru, D.; Opdam, E.; Cogdell, J.; Kim, J.-L.; Zhu, C.-B.
2017-01-01
In this paper, we consider the relation between two nonabelian Fourier transforms. The first one is defined in terms of the Langlands-Kazhdan-Lusztig parameters for unipotent elliptic representations of a split p-adic group and the second is defined in terms of the pseudocoefficients of these
Fourier transform and the Verlinde formula for the quantum double of a finite group
Koornwinder, T.H.; Schroers, B.J.; Slingerland, J.K.; Bais, F.A.
1999-01-01
We define a Fourier transform $S$ for the quantum double $D(G)$ of a finite group $G$. Acting on characters of $D(G)$, $S$ and the central ribbon element of $D(G)$ generate a unitary matrix representation of the group $SL(2,Z)$. The characters form a ring over the integers under both the algebra
Soil science research is increasingly applying Fourier transform infrared (FTIR) spectroscopy for analysis of soil organic matter (SOM). However, the compositional complexity of soils and the dominance of the mineral component can limit spectroscopic resolution of SOM and other minor components. The...
Teaching Stable Two-Mirror Resonators through the Fractional Fourier Transform
Moreno, Ignacio; Garcia-Martinez, Pascuala; Ferreira, Carlos
2010-01-01
We analyse two-mirror resonators in terms of their fractional Fourier transform (FRFT) properties. We use the basic ABCD ray transfer matrix method to show how the resonator can be regarded as the cascade of two propagation-lens-propagation FRFT systems. Then, we present a connection between the geometric properties of the resonator (the g…
PARTICULATE MATTER MEASUREMENTS USING OPEN-PATH FOURIER TRANSFORM INFRARED SPECTROSCOPY
Open-path Fourier transform infrared (OP-FT1R) spectroscopy is an accepted technology for measuring gaseous air contaminants. OP-FT1R absorbance spectra acquired during changing aerosols conditions reveal related changes in very broad baseline features. Usually, this shearing of ...
3D spectral imaging with synchrotron Fourier transform infrared spectro-microtomography
Michael C. Martin; Charlotte Dabat-Blondeau; Miriam Unger; Julia Sedlmair; Dilworth Y. Parkinson; Hans A. Bechtel; Barbara Illman; Jonathan M. Castro; Marco Keiluweit; David Buschke; Brenda Ogle; Michael J. Nasse; Carol J. Hirschmugl
2013-01-01
We report Fourier transform infrared spectro-microtomography, a nondestructive three-dimensional imaging approach that reveals the distribution of distinctive chemical compositions throughout an intact biological or materials sample. The method combines mid-infrared absorption contrast with computed tomographic data acquisition and reconstruction to enhance chemical...
Phase retrieval from the magnitude of the Fourier transforms of nonperiodic objects
International Nuclear Information System (INIS)
Miao, J.; Sayre, D.; Chapman, H.N.
1998-01-01
It is suggested that, given the magnitude of Fourier transforms sampled at the Bragg density, the phase problem is underdetermined by a factor of 2 for 1D, 2D, and 3D objects. It is therefore unnecessary to oversample the magnitude of Fourier transforms by 2x in each dimension (i.e., oversampling by 4x for 2D and 8x for 3D) in retrieving the phase of 2D and 3D objects. Our computer phasing experiments accurately retrieved the phase from the magnitude of the Fourier transforms of 2D and 3D complex-valued objects by using positivity constraints on the imaginary part of the objects and loose supports, with the oversampling factor much less than 4 for 2D and 8 for 3D objects. Under the same conditions we also obtained reasonably good reconstructions of 2D and 3D complex-valued objects from the magnitude of their Fourier transforms with added noise and a central stop. copyright 1998 Optical Society of America
Vibrational analysis of Fourier transform spectrum of the B u )–X g ...
Indian Academy of Sciences (India)
improved by putting the wave number of band origins in Deslandre table. The vibrational analysis was supported by determining the Franck–Condon factor and r-centroid values. Keywords. Fourier transform spectroscopy; electronic spectrum of selenium dimer; vibrational analysis; Franck–Condon factor; r-centroid values.
Vibrational analysis of Fourier transform spectrum of the B 3− u (0
Indian Academy of Sciences (India)
... microwave, was recorded on BOMEM DA8 Fourier transform spectrometer at an apodized resolution of 0.035 cm-1. Vibrational constants were improved by putting the wave number of band origins in Deslandre table. The vibrational analysis was supported by determining the Franck–Condon factor and -centroid values.
Fourier-transform imaging of cotton and botanical and field trash mixtures
Botanical and field cotton trash comingled with cotton lint can greatly reduce the marketability and quality of cotton. Trash can be found comingled with cotton lint during harvesting, ginning, and processing, thus this study is of interest. Attenuated Total Reflectance-Fourier Transform Infrared (A...
Specification of the Fast Fourier Transform algorithm as a term rewriting system
Rodenburg, P.H.; Hoekzema, D.J.
1987-01-01
We specify an algorithm for multiplying polynomials with complex coefficients incorporating, the Fast Fourier Transform algorithm of Cooley and Tukey [CT]. The specification formalism we use is a variant of the formalism ASF described in. [BHK]. The difference with ASF is essentially a matter of
Dool, T.C. van den; Hamelinck, R.F.M.M.; Kruizinga, B.; Gielesen, W.L.M.; Braam, B.C.; Nijenhuis, J.R.; Loix, N.; Luyckx, S.; Loon, D. van; Kooijman, P.P.; Swinyard, B.M.
2010-01-01
TNO, together with its partners Micromega and SRON, have designed a cryogenic scanning mechanism for use in the SAFARI Fourier Transform Spectrometer (FTS) on board of the SPICA mission. The optics of the FTS scanning mechanism (FTSM) consists of two back-to-back cat's-eyes. The optics are mounted
Superexponentially damped Vlasov plasma oscillations in the Fourier transformed velocity space
International Nuclear Information System (INIS)
Sedlacek, Z.; Nocera, L.
2002-01-01
The Landau (exponentially) damped solutions of the Vlasov-Poisson equation Fourier transformed with respect to velocity are genuine eigenmodes corresponding to complex eigenvalues. In addition there exist solutions decaying faster than exponentially which exhibit no oscillatory behaviour. A new characterization is given of the initial conditions that give rise to these solutions together with a numerical demonstration
Refined fourier-transform method of analysis of full two-dimensional digitized interferograms.
Lovrić, Davorin; Vucić, Zlatko; Gladić, Jadranko; Demoli, Nazif; Mitrović, Slobodan; Milas, Mirko
2003-03-10
A refined Fourier-transform method of analysis of interference patterns is presented. The refinements include a method of automatic background subtraction and a way of treating the problem of heterodyning. The method proves particularly useful for analysis of long sequences of interferograms.
Analysis of Chaperone Complexes by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
Geels, R.B.J.
2008-01-01
Investigation of methodologies for analyses of noncovalently bound protein assemblies using Fourier transformation ion cyclotron resonance mass spectrometry (FT-ICR-MS) and quadrupole Time-of-Flight (qToF) mass spectrometry. Specifically, the co-chaperonins GroEL and gp31 are used to perform
Webb, John D.; Schissel, Paul; Czanderna, Alvin; Chughtai, Abdul R.; Smith, Dwight M.
1981-10-01
An experimental approach to the study of polymer film photodegradation by Fourier transform infrared (FT-IR) spectroscopy, with simultaneous UV irradiation under varying thermal and environmental parameters, has been developed. Reflection spectra from metal-backed polycarbonate films undergoing irradiation in a test chamber illustrate the system's capability. Early degradative events in polycarbonate are revealed by differences in these spectra.
A fast Fourier transform program for the deconvolution of IN10 data
International Nuclear Information System (INIS)
Howells, W.S.
1981-04-01
A deconvolution program based on the Fast Fourier Transform technique is described and some examples are presented to help users run the programs and interpret the results. Instructions are given for running the program on the RAL IBM 360/195 computer. (author)
Fourier transform infrared emission spectra of atomic rubidium: g- and h-states
Czech Academy of Sciences Publication Activity Database
Civiš, Svatopluk; Ferus, Martin; Kubelík, Petr; Chernov, Vladislav E.; Zanozina, Ekaterina M.
2012-01-01
Roč. 45, č. 17 (2012), s. 175002 ISSN 0953-4075 R&D Projects: GA AV ČR IAAX00100903 Institutional support: RVO:61388955 Keywords : Fourier transform infrared emission spectra * atomic rubidium * physical chemistry Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.031, year: 2012
Determination of Lamb wave dispersion curves by means of Fourier transform
Czech Academy of Sciences Publication Activity Database
Hora, Petr; Červená, Olga
2012-01-01
Roč. 6, č. 1 (2012), s. 5-16 ISSN 1802-680X R&D Projects: GA ČR GA101/09/1630 Institutional research plan: CEZ:AV0Z20760514 Keywords : Lamb wave * dispersion curves * Fourier transform * FEM Subject RIV: BI - Acoustics
A new chemometric method based on absorbance ratios from Fourier transform infrared spectra was devised to analyze multicomponent biodegradable plastics. The method uses the BeerLambert law to directly compute individual component concentrations and weight losses before and after biodegradation of c...
Design of a compact and ultrahigh-resolution Fourier-transform spectrometer
Akca, B. Imran
2017-01-01
In this work, a compact and ultrahigh-resolution Fourier-transform spectrometer design is presented which is in great demand in numerous areas. The spectrometer is formed by sequentially-activated 60 Mach-Zehnder interferometers that are connected to photodetectors through very-low-loss beam
The RC Circuit: An Approach with Fourier Transforms In this article ...
Indian Academy of Sciences (India)
we look at the methods employed to solve this differential equa- tion for different forms of the input voltage applied. 1. The RC Circuit and its Differential Equation. For the circuit shown in Figure 1, the differential equation for. Keywords. Fourier transforms, contour integration, circuit theory. charge q on the capacitor is given ...
Czech Academy of Sciences Publication Activity Database
Pivokonský, Radek; Filip, Petr; Zelenková, Jana
2016-01-01
Roč. 104, č. 8 (2016), s. 171-178 ISSN 0032-3861 Institutional support: RVO:67985874 Keywords : LAOS * fourier transform rheology * Giesekus model * PTT model * modified XPP model * poly(ethylene oxide) Subject RIV: BK - Fluid Dynamics Impact factor: 3.684, year: 2016
Prediction of beta-lactoglobulin genotypes based on milk Fourier transform infrared spectra
Rutten, M.J.M.; Bovenhuis, H.; Heck, J.M.L.; Arendonk, van J.A.M.
2011-01-01
ß-Lactoglobulin (ß-LG) genotypes are associated with differences in bovine milk protein composition. Therefore, ß-LG genotypes are of direct relevance for the dairy industry. In this study, we predicted ß-lactoglobulin genotypes based on routinely recorded milk Fourier transform infrared spectra
The RC Circuit: An Approach with Fourier Transforms In this article ...
Indian Academy of Sciences (India)
In this article we shall mathematically analyse the Resistor-. Capacitor (RC) circuit with the help of Fourier transforms. (FT). This very general technique gives us a lot of insight into solving first order differential equations with source terms de- pending on time. In itself, the RC circuit is by far the most commonplace entity in ...
Fourier-Laplace transform of irreducible regular differential systems on the Riemann sphere
International Nuclear Information System (INIS)
Sabbah, C
2004-01-01
It is shown that the Fourier-Laplace transform of an irreducible regular differential system on the Riemann sphere underlies a polarizable regular twistor D-module if one considers only the part at finite distance. The associated holomorphic bundle defined away from the origin of the complex plane is therefore equipped with a natural harmonic metric having a tame behaviour near the origin
some new estimates for the helgason fourier transform on rank 1 ...
Indian Academy of Sciences (India)
24
Key words: Symmetric space; Helgason Fourier transform; Spherical modulus of continuity; Generalized ... For the required properties of semisimple Lie groups and symmetric spaces, we refer the reader, e.g., to [3,4]. ..... f ∈ L2(X) that have gener- alized derivatives in the sense of distributions satisfying ∆rf ∈ L2(X). i.e.,. Wr.
Directory of Open Access Journals (Sweden)
Percival Almoro
1998-12-01
Full Text Available Microscopic deformations on the surface of a circular diaphragm were measured using double exposure holographic interferometry and Fourier transform method (FTM. The three-dimensional surface deformations were successfully visualized by applying FTM to holographic interferogram analysis. The minimum surface displacement measured was 0.317 µm. This was calibrated via the Michelson interferometry technique.
On Fast Fourier Transform-A Popular Tool for Spectrum Analysis
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 3; Issue 10. On Fast Fourier Transform - A Popular Tool for Spectrum Analysis. V Umapathi Reddy. General Article ... Author Affiliations. V Umapathi Reddy1. Electrical Communication Engineering, Indian Institute of Science, Bangalore 560012, India ...
Barbu, I.M.
2008-01-01
This thesis describes, the use of a Fourier Transform Ion Cyclotron (FTICR) mass spectrometer in the study of biological samples with, imaging mass spectrometry (MS). To achieve this goal experiments were performed on an in-house modified FTICR-MS instrument (for which special acquisition software
CIRS-lite, a Fourier Transform Spectrometer for Low-Cost Planetary Missions
Brasunas, J.; Bly, V.; Edgerton, M.; Gong, Q.; Hagopian, J.; Mamakos, W.; Morelli, A.; Pasquale, B.; Strojny, C.
2011-01-01
Passive spectroscopic remote sensing of planetary atmospheres and surfaces in the thermal infrared is a powerful tool for obtaining information about surface and atmospheric temperatures, composition, and dynamics (via the thermal wind equation). Due to its broad spectral coverage, the Fourier transform spectrometer (FTS) is particularly suited to the exploration and discovery of molecular species. NASA's Goddard Space Flight Center (GSFC) developed the CIRS (Composite Infrared Spectrometer) FTS for the NASA/ESA Cassini mission to the Saturnian system. CIRS observes Saturn, Titan, icy moons such as Enceladus, and the rings in thermal self-emission over the spectral range of 7 to 1000 ell11. CIRS has given us important new insights into stratospheric composition and jets on Jupiter and Saturn, the cryo-geyser and thermal stripes on Enceladus, and the winter polar vortex on Titan. CIRS has a mass of 43 kg, contrasted with the earlier GSFC FTS, pre-Voyager IRIS (14 kg). Future low-cost planetary missions will have very tight constraints on science payload mass, thus we must endeavor to return to IRIS-level mass while maintaining CIRS-level science capabilities ("do more with less"). CIRS-lite achieves this by pursuing: a) more sensitive infrared detectors (high Tc superconductor) to enable smaller optics. b) changed long wavelength limit from 1000 to 300 microns to reduce diffraction by smaller optics. c) CVD (chemical vapor deposition) diamond beam-splitter for broad spectral coverage. d) single FTS architecture instead of a dual FTS architecture. e) novel materials, such as single crystal silicon for the input telescope primary.
Singh, G.; McElroy, C. T.; Vaziri, Z.; Barton, D.; Blair, G.; Grandmont, F. J.
2017-12-01
The fifth assessment report (AR5) of the Intergovernmental Panel on Climate Change (IPCC) states that the warming of zonal mean surface temperature at higher latitudes exceeds the global average temperature change. This poses a great problem as the warming leads to the thawing of the permafrost in the Arctic region that acts as an envelope to trap greenhouse gases such as carbon dioxide and methane. Therefore, there is an urgent need to develop scientific instruments that can be flown in space over the Arctic to provide atmospheric information to quantify the evolution and transport of these gases. The Laboratory for Atmospheric Remote Sounding from Space (LARSS) at York University is developing an imaging Fourier transform spectrometer (IFTS) for climate observations by atmospheric sounding. The spectrometer has two individual channels, one centred at 1650 nm to measure the atmospheric column of carbon dioxide and methane, and another centred at 762 nm to measure the temperature-pressure profile by making measurements of the O2A band. A Commercial-Off-The-Shelf (COTS) modulator has been purchased from ABB Inc. of Quebec City. Interferometers are widely used in many scientific laboratories to measure concentrations of different constituents in a given sample. The performance of these instruments is highly dependent on environmental effects and various properties of the input beam such as coherence, polarity, etc. Thus, the use of such instruments to measure atmospheric concentration is complicated and challenging. The immediate goal of this project is to develop an IFTS system which can measure backscattered radiation in a laboratory environment and develop design elements that will make it operable in the space environment. Progress on the project and information concerning some of the issues listed above will be discussed. The developments which flow from this research project will support efforts by Environment and Climate Change Canada, the Canadian Space
Detecting of copy-move forgery in digital images using fractional Fourier transform
Yang, Renqing; Bai, Zhengyao; Yin, Liguo; Gao, Hao
2015-07-01
Copy-move forgery is one of the most simple and commonly used forging methods, where a part of image itself is copied and pasted on another part of the same image. This paper presents a new approach for copy-move forgery detection where fractional Fourier transform (FRFT) is used. First, the 1-level discrete wavelet transform (DWT) of the forged image is to reduce its dimension. Next, the low frequency the sub-band is divided into overlapped blocks of equal size. The fractional Fourier transform of each block is calculated and the vector of the coefficients is constructed. All feature vectors are sorted using lexicographical order. Finally, the difference of adjacent feature vectors is evaluated and employed to locate the duplicated regions which have the same feature vectors. Experimental results show that the proposed method is effective in detection of the copy-move forgery regions.
Application of the fractional Fourier transform to image reconstruction in MRI.
Parot, Vicente; Sing-Long, Carlos; Lizama, Carlos; Tejos, Cristian; Uribe, Sergio; Irarrazaval, Pablo
2012-07-01
The classic paradigm for MRI requires a homogeneous B(0) field in combination with linear encoding gradients. Distortions are produced when the B(0) is not homogeneous, and several postprocessing techniques have been developed to correct them. Field homogeneity is difficult to achieve, particularly for short-bore magnets and higher B(0) fields. Nonlinear magnetic components can also arise from concomitant fields, particularly in low-field imaging, or intentionally used for nonlinear encoding. In any of these situations, the second-order component is key, because it constitutes the first step to approximate higher-order fields. We propose to use the fractional Fourier transform for analyzing and reconstructing the object's magnetization under the presence of quadratic fields. The fractional fourier transform provides a precise theoretical framework for this. We show how it can be used for reconstruction and for gaining a better understanding of the quadratic field-induced distortions, including examples of reconstruction for simulated and in vivo data. The obtained images have improved quality compared with standard Fourier reconstructions. The fractional fourier transform opens a new paradigm for understanding the MR signal generated by an object under a quadratic main field or nonlinear encoding. Copyright © 2011 Wiley Periodicals, Inc.
Directory of Open Access Journals (Sweden)
Nicholas W. Landry
2015-09-01
Full Text Available Property closures are envelopes representing the complete set of theoretically feasible macroscopic property combinations for a given material system. In this paper, we present a computational procedure based on fast Fourier transforms (FFTs to delineation of elastic property closures for hexagonal close packed (HCP metals. The procedure consists of building a database of non-zero Fourier transforms for each component of the elastic stiffness tensor, calculating the Fourier transforms of orientation distribution functions (ODFs, and calculating the ODF-to-elastic property bounds in the Fourier space. In earlier studies, HCP closures were computed using the generalized spherical harmonics (GSH representation and an assumption of orthotropic sample symmetry; here, the FFT approach allowed us to successfully calculate the closures for a range of HCP metals without invoking any sample symmetry assumption. The methodology presented here facilitates for the first time computation of property closures involving normal-shear coupling stiffness coefficients. We found that the representation of these property linkages using FFTs need more terms compared to GSH representations. However, the use of FFT representations reduces the computational time involved in producing the property closures due to the use of fast FFT algorithms. Moreover, FFT algorithms are readily available as opposed to GSH codes.
DEFF Research Database (Denmark)
Clausen, Anders; Guan, Pengyu; Mulvad, Hans Christian Hansen
2014-01-01
All-optical time-domain Optical Fourier Transformation utilised for signal processing of ultra-high-speed OTDM signals and OFDM signals will be presented.......All-optical time-domain Optical Fourier Transformation utilised for signal processing of ultra-high-speed OTDM signals and OFDM signals will be presented....
DEFF Research Database (Denmark)
Galili, Michael; Guan, Pengyu; Lillieholm, Mads
2017-01-01
In the talk, we will review recent work on optical signal processing based on time lenses. Various applications of optical Fourier transformation for optical communications will be discussed.......In the talk, we will review recent work on optical signal processing based on time lenses. Various applications of optical Fourier transformation for optical communications will be discussed....
DEFF Research Database (Denmark)
Guan, Pengyu; Røge, Kasper Meldgaard; Lillieholm, Mads
2017-01-01
We review recent progress in the use of time lens based optical Fourier transformation for advanced all-optical signal processing. A novel time lens based complete optical Fourier transformation (OFT) technique is introduced. This complete OFT is based on two quadratic phase-modulation stages using...
A Wavelet Algorithm for Fourier-Bessel Transform Arising in Optics
Directory of Open Access Journals (Sweden)
Nagma Irfan
2015-01-01
Full Text Available The aim of the paper is to propose an efficient and stable algorithm that is quite accurate and fast for numerical evaluation of the Fourier-Bessel transform of order ν, ν>-1, using wavelets. The philosophy behind the proposed algorithm is to replace the part tf(t of the integral by its wavelet decomposition obtained by using CAS wavelets thus representing Fν(p as a Fourier-Bessel series with coefficients depending strongly on the input function tf(t. The wavelet method indicates that the approach is easy to implement and thus computationally very attractive.
Lu, Wenlong; Xie, Junwei; Wang, Heming; Sheng, Chuan
2016-01-01
Inspired by track-before-detection technology in radar, a novel time-frequency transform, namely polynomial chirping Fourier transform (PCFT), is exploited to extract components from noisy multicomponent signal. The PCFT combines advantages of Fourier transform and polynomial chirplet transform to accumulate component energy along a polynomial chirping curve in the time-frequency plane. The particle swarm optimization algorithm is employed to search optimal polynomial parameters with which the PCFT will achieve a most concentrated energy ridge in the time-frequency plane for the target component. The component can be well separated in the polynomial chirping Fourier domain with a narrow-band filter and then reconstructed by inverse PCFT. Furthermore, an iterative procedure, involving parameter estimation, PCFT, filtering and recovery, is introduced to extract components from a noisy multicomponent signal successively. The Simulations and experiments show that the proposed method has better performance in component extraction from noisy multicomponent signal as well as provides more time-frequency details about the analyzed signal than conventional methods.
Analysis of gamma-ray spectra by using fast Fourier transform
International Nuclear Information System (INIS)
Tominaga, Shoji; Nagata, Shojiro; Nayatani, Yoshinobu; Ueda, Isamu; Sasaki, Satoshi.
1977-01-01
In order to simplify the mass data processing in a response matrix method for γ-ray spectral analysis, a method using a Fast Fourier Transform devised. The validity of the method was confirmed by a computer simulation for spectra of a NaI detector. The method uses the fact that spectral data can be represented by Fourier series with reduced number of terms. The estimation of intensities of γ-ray components is performed by a matrix operation using the compressed data of an observation spectrum and standard spectra in Fourier coefficients. The identification of γ-ray energies is also easy. Several features in the method and a general problem to be solved in a response matrix method are described. (auth.)
Use of fast Fourier transform in gamma-ray spectral analysis
International Nuclear Information System (INIS)
Tominaga, Shoji; Nayatani, Yoshinobu; Nagata, Shojiro; Sasaki, Takashi; Ueda, Isamu.
1978-01-01
In order to simplify the mass data processing in a response matrix method for γ-ray spectral analysis, a method using a Fast Fourier Transform has been devised. The validity of the method has been confirmed by computer simulation for spectra of a NaI detector. First, it is shown that spectral data can be represented by Fourier series with a reduced number of terms. Then the estimation of intensities of γ-ray components is performed by a matrix operation using the compressed data of an observation spectrum and standard spectra in Fourier coefficients. The identification of γ-ray energies is also easy. Several features of the method and a general problem to be solved in relation to a response matrix method are described. (author)
Program for the analysis of time series. [by means of fast Fourier transform algorithm
Brown, T. J.; Brown, C. G.; Hardin, J. C.
1974-01-01
A digital computer program for the Fourier analysis of discrete time data is described. The program was designed to handle multiple channels of digitized data on general purpose computer systems. It is written, primarily, in a version of FORTRAN 2 currently in use on CDC 6000 series computers. Some small portions are written in CDC COMPASS, an assembler level code. However, functional descriptions of these portions are provided so that the program may be adapted for use on any facility possessing a FORTRAN compiler and random-access capability. Properly formatted digital data are windowed and analyzed by means of a fast Fourier transform algorithm to generate the following functions: (1) auto and/or cross power spectra, (2) autocorrelations and/or cross correlations, (3) Fourier coefficients, (4) coherence functions, (5) transfer functions, and (6) histograms.
Marto, J A; White, F M; Seldomridge, S; Marshall, A G
1995-11-01
Matrix-assisted laser desorption/ionization (MALDI) Fourier transform ion cyclotron resonance mass spectrometry provides for structural analysis of the principal biological phospholipids: glycerophosphatidylcholine, -ethanolamine, -serine, and -inositol. Both positive and negative molecular or quasimolecular ions are generated in high abundance. Isolated molecular ions may be collisionally activated in the source side of a dual trap mass analyzer, yielding fragments serving to identify the polar head group (positive ion mode) and fatty acid side chains (negative ion mode). Azimuthal quadrupolar excitation following collisionally activated dissociation refocuses productions close to the solenoid axis; subsequent transfer of product ions to the analyzer ion trap allows for high-resolution mass analysis. Cyro-cooling of the sample probe with liquid nitrogen greatly reduces matrix adduction encountered in the negative ion mode.
Coulomb Fourier transformation: A novel approach to three-body scattering with charged particles
International Nuclear Information System (INIS)
Alt, E.O.; Levin, S.B.; Yakovlev, S.L.
2004-01-01
A unitary transformation of the three-body Hamiltonian which describes a system of two charged and one neutral particles is constructed such that the Coulomb potential which acts between the charged particles is explicitly eliminated. The transformed Hamiltonian and, in particular, the transformed short-range pair interactions are worked out in detail. Thereby it is found that, after transformation, the short-range potentials acting between the neutral and either one of the charged particles become simply Fourier transformed but, in addition, multiplied by a function that represents the Coulombic three-body correlations originating from the action of the other charged particle on the considered pair. This function which is universal as it does not depend on any property of the short-range interaction is evaluated explicitly and its singularity structure is described in detail. In contrast, the short-range potential between the charged particles remains of two-body type but occurs now in the 'Coulomb representation'. Specific applications to Yukawa and Gaussian potentials are given. Since the Coulomb-Fourier-transformed Hamiltonian does no longer contain the Coulomb potential or any other effective interaction of long range, standard methods of short-range few-body scattering theory are applicable
Directory of Open Access Journals (Sweden)
Eduardo O. Cerqueira
2000-10-01
Full Text Available Instrumental data always present some noise. The analytical data information and instrumental noise generally has different frequencies. Thus is possible to remove the noise using a digital filter based on Fourier transform and inverse Fourier transform. This procedure enhance the signal/noise ratio and consecutively increase the detection limits on instrumental analysis. The basic principle of Fourier transform filter with modifications implemented to improve its performance is presented. A numerical example, as well as a real voltammetric example are showed to demonstrate the Fourier transform filter implementation. The programs to perform the Fourier transform filter, in Matlab and Visual Basic languages, are included as appendices
Sheng, Ming; Gorzsás, András; Tuck, Simon
2016-01-01
Changes in intermediary metabolism have profound effects on many aspects of C. elegans biology including growth, development and behavior. However, many traditional biochemical techniques for analyzing chemical composition require relatively large amounts of starting material precluding the analysis of mutants that cannot be grown in large amounts as homozygotes. Here we describe a technique for detecting changes in the chemical compositions of C. elegans worms by Fourier transform infrared microspectroscopy. We demonstrate that the technique can be used to detect changes in the relative levels of carbohydrates, proteins and lipids in one and the same worm. We suggest that Fourier transform infrared microspectroscopy represents a useful addition to the arsenal of techniques for metabolic studies of C. elegans worms.
High-speed spectral domain optical coherence tomography using non-uniform fast Fourier transform
Chan, Kenny K. H.; Tang, Shuo
2010-01-01
The useful imaging range in spectral domain optical coherence tomography (SD-OCT) is often limited by the depth dependent sensitivity fall-off. Processing SD-OCT data with the non-uniform fast Fourier transform (NFFT) can improve the sensitivity fall-off at maximum depth by greater than 5dB concurrently with a 30 fold decrease in processing time compared to the fast Fourier transform with cubic spline interpolation method. NFFT can also improve local signal to noise ratio (SNR) and reduce image artifacts introduced in post-processing. Combined with parallel processing, NFFT is shown to have the ability to process up to 90k A-lines per second. High-speed SD-OCT imaging is demonstrated at camera-limited 100 frames per second on an ex-vivo squid eye. PMID:21258551
Suppression law of quantum states in a 3D photonic fast Fourier transform chip
Crespi, Andrea; Osellame, Roberto; Ramponi, Roberta; Bentivegna, Marco; Flamini, Fulvio; Spagnolo, Nicolò; Viggianiello, Niko; Innocenti, Luca; Mataloni, Paolo; Sciarrino, Fabio
2016-01-01
The identification of phenomena able to pinpoint quantum interference is attracting large interest. Indeed, a generalization of the Hong–Ou–Mandel effect valid for any number of photons and optical modes would represent an important leap ahead both from a fundamental perspective and for practical applications, such as certification of photonic quantum devices, whose computational speedup is expected to depend critically on multi-particle interference. Quantum distinctive features have been predicted for many particles injected into multimode interferometers implementing the Fourier transform over the optical modes. Here we develop a scalable approach for the implementation of the fast Fourier transform algorithm using three-dimensional photonic integrated interferometers, fabricated via femtosecond laser writing technique. We observe the suppression law for a large number of output states with four- and eight-mode optical circuits: the experimental results demonstrate genuine quantum interference between the injected photons, thus offering a powerful tool for diagnostic of photonic platforms. PMID:26843135
Barnett, Patrick D; Strange, K Alicia; Angel, S Michael
2017-06-01
This work describes a method of applying the Fourier transform to the two-dimensional Fizeau fringe patterns generated by the spatial heterodyne Raman spectrometer (SHRS), a dispersive interferometer, to correct the effects of certain types of optical alignment errors. In the SHRS, certain types of optical misalignments result in wavelength-dependent and wavelength-independent rotations of the fringe pattern on the detector. We describe here a simple correction technique that can be used in post-processing, by applying the Fourier transform in a row-by-row manner. This allows the user to be more forgiving of fringe alignment and allows for a reduction in the mechanical complexity of the SHRS.
DEFF Research Database (Denmark)
Palushani, Evarist; Oxenløwe, Leif Katsuo; Galili, Michael
2009-01-01
This paper reports on the generation of 1.6-ps fullwidth at half-maximum flat-top pulses by the optical Fourier transform technique, and the utilization of these pulses in a 320-Gb/s demultiplexing experiment. It is demonstrated how a narrow pulse having a 15-nm wide third-order super-Gaussian sp......This paper reports on the generation of 1.6-ps fullwidth at half-maximum flat-top pulses by the optical Fourier transform technique, and the utilization of these pulses in a 320-Gb/s demultiplexing experiment. It is demonstrated how a narrow pulse having a 15-nm wide third-order super...
Directory of Open Access Journals (Sweden)
Zhen Cao
2014-01-01
Full Text Available Fourier transform infrared spectroscopy (FTIR technique was used to classify 16 species from three moss families (Mielichhoferiaceae, Bryaceae, and Mniaceae. The FTIR spectra ranging from 4000 cm−1 to 400 cm−1 of the 16 species were obtained. To group the spectra according to their spectral similarity in a dendrogram, cluster analysis and principal component analysis (PCA were performed. Cluster analysis combined with PCA was used to give a rough result of classification among the moss samples. However, some species belonging to the same genus exhibited very similar chemical components and similar FTIR spectra. Fourier self-deconvolution (FSD was used to enhance the differences of the spectra. Discrete wavelet transform (DWT was used to decompose the FTIR spectra of Mnium laevinerve and M. spinosum. Three scales were selected as the feature extracting space in the DWT domain. Results showed that FTIR spectroscopy combined with DWT was suitable for distinguishing different species of the same genus.
Advances in hyperspectral remote sensing I: The visible Fourier transform hyperspectral imager
Directory of Open Access Journals (Sweden)
J. Bruce Rafert
2015-05-01
Full Text Available We discuss early hyperspectral research and development activities during the 1990s that led to the deployment of aircraft and satellite payloads whose heritage was based on the use of visible, spatially modulated, imaging Fourier transform spectrometers, beginning with early experiments at the Florida Institute of Technology, through successful launch and deployment of the Visible Fourier Transform Hyperspectral Imager on MightySat II.1 on 19 July 2000. In addition to a brief chronological overview, we also discuss several of the most interesting optical engineering challenges that were addressed over this timeframe, present some as-yet un-exploited features of field-widened (slit-less SMIFTS instruments, and present some images from ground-based, aircraft-based and satellite-based instruments that helped provide the impetus for the proliferation and development of entire new families of instruments and countless new applications for hyperspectral imaging.
Simulation of micromechanical behavior of polycrystals: finite elements vs. fast Fourier transforms
Energy Technology Data Exchange (ETDEWEB)
Lebensohn, Ricardo A [Los Alamos National Laboratory; Prakash, Arun [IWM FREIBURG
2009-01-01
In this work, we compare finite element and fast Fourier transform approaches for the prediction of micromechanical behavior of polycrystals. Both approaches are full-field approaches and use the same visco-plastic single crystal constitutive law. We investigate the texture and the heterogeneity of the inter- and intragranular, stress and strain fields obtained from the two models. Additionally, we also look into their computational performance. Two cases - rolling of aluminium and wire drawing of tungsten - are used to evaluate the predictions of the two mode1s. Results from both the models are similar, when large grain distortions do not occur in the polycrystal. The finite element simulations were found to be highly computationally intensive, in comparison to the fast Fourier transform simulations.
Vladimirov, Gleb; Kostyukevich, Yury; Kharybin, Oleg; Nikolaev, Eugene
2017-08-01
Particle-in-cell-based realistic simulation of Fourier transform ion cyclotron resonance experiments could be used to generate ion trajectories and a signal induced on the detection electrodes. It has been shown recently that there is a modulation of "reduced" cyclotron frequencies in ion cyclotron resonance signal caused by Coulomb interaction of ion clouds. In this work it was proposed to use this modulation in order to determine frequency difference between an ion of known m/z and all other ions generating signal in ion cyclotron resonance cell. It is shown that with an increase of number of ions in ion cyclotron resonance trap, the modulation index increases, which lead to a decrease in the accuracy of determination of peak intensities by super Fourier transform resolution methods such as filter diagonalization method.
Seismology with a Fourier-transform spectrometer: applications to giant planets and stars.
Maillard, J P
1996-06-01
A method to detect the acoustic oscillation spectrum of giant planets and stars exploits the multiplex properties of a Fourier-transform spectrometer (FTS). It is based on measurement of the small Doppler shift related to the oscillation of the atmosphere measured from all the lines in a portion of the planetary or the stellar spectrum directly from the interferogram. The resulting amplitude modulation of the output signal is recorded continuously over several consecutive nights at a fixed path difference selected from criteria of optimum efficiency. Hence the Fourier transform of this signal yields the pressure-mode spectrum of the object. Applications to Jupiter, Saturn, and Procyon, observed in this mode with the step-scan FTS installed in the Canada-France-Hawaii Telescope, are presented. Future projects are discussed.
Gaseous effluent monitoring and identification using an imaging Fourier transform spectrometer
Energy Technology Data Exchange (ETDEWEB)
Carter, M.R.; Bennett, C.L.; Fields, D.J.; Hernandez, J.
1993-10-01
We are developing an imaging Fourier transform spectrometer for chemical effluent monitoring. The system consists of a 2-D infrared imaging array in the focal plane of a Michelson interferometer. Individual images are coordinated with the positioning of a moving mirror in the Michelson interferometer. A three dimensional data cube with two spatial dimensions and one interferogram dimension is then Fourier transformed to produce a hyperspectral data cube with one spectral dimension and two spatial dimensions. The spectral range of the instrument is determined by the choice of optical components and the spectral range of the focal plane array. Measurements in the near UV, visible, near IR, and mid-IR ranges are possible with the existing instrument. Gaseous effluent monitoring and identification measurements will be primarily in the ``fingerprint`` region of the spectrum, ({lambda} = 8 to 12 {mu}m). Initial measurements of effluent using this imaging interferometer in the mid-IR will be presented.
Fast data reconstructed method of Fourier transform imaging spectrometer based on multi-core CPU
Yu, Chunchao; Du, Debiao; Xia, Zongze; Song, Li; Zheng, Weijian; Yan, Min; Lei, Zhenggang
2017-10-01
Imaging spectrometer can gain two-dimensional space image and one-dimensional spectrum at the same time, which shows high utility in color and spectral measurements, the true color image synthesis, military reconnaissance and so on. In order to realize the fast reconstructed processing of the Fourier transform imaging spectrometer data, the paper designed the optimization reconstructed algorithm with OpenMP parallel calculating technology, which was further used for the optimization process for the HyperSpectral Imager of `HJ-1' Chinese satellite. The results show that the method based on multi-core parallel computing technology can control the multi-core CPU hardware resources competently and significantly enhance the calculation of the spectrum reconstruction processing efficiency. If the technology is applied to more cores workstation in parallel computing, it will be possible to complete Fourier transform imaging spectrometer real-time data processing with a single computer.
Tabletop single-shot extreme ultraviolet Fourier transform holography of an extended object.
Malm, Erik B; Monserud, Nils C; Brown, Christopher G; Wachulak, Przemyslaw W; Xu, Huiwen; Balakrishnan, Ganesh; Chao, Weilun; Anderson, Erik; Marconi, Mario C
2013-04-22
We demonstrate single and multi-shot Fourier transform holography with the use of a tabletop extreme ultraviolet laser. The reference wave was produced by a Fresnel zone plate with a central opening that allowed the incident beam to illuminate the sample directly. The high reference wave intensity allows for larger objects to be imaged compared to mask-based lensless Fourier transform holography techniques. We obtain a spatial resolution of 169 nm from a single laser pulse and a resolution of 128 nm from an accumulation of 20 laser pulses for an object ~11x11μm(2) in size. This experiment utilized a tabletop extreme ultraviolet laser that produces a highly coherent ~1.2 ns laser pulse at 46.9 nm wavelength.
Zhou, Chengfeng; Jiang, Wei; Cheng, Qingzheng; Via, Brian K.
2015-01-01
This research addressed a rapid method to monitor hardwood chemical composition by applying Fourier transform infrared (FT-IR) spectroscopy, with particular interest in model performance for interpretation and prediction. Partial least squares (PLS) and principal components regression (PCR) were chosen as the primary models for comparison. Standard laboratory chemistry methods were employed on a mixed genus/species hardwood sample set to collect the original data. PLS was found to provide bet...
Kamnev, A. A.; Ristić, M.; Antonyuk, L. P.; Chernyshev, A. V.; Ignatov, V. V.
1997-06-01
The data of Fourier transform infrared (FTIR) spectroscopic measurements performed on intact cells of the soil nitrogen-fixing bacterium Azospirillum brasilense grown in a standard medium and under the conditions of an increased metal uptake are compared and discussed. The structural FTIR information obtained is considered together with atomic absorption spectrometry (AAS) data on the content of metal cations in the bacterial cells. Some methodological aspects concerning preparation of bacterial cell samples for FTIR measurements are also discussed.
2009-10-01
Hyperspectral Imagery (Imagerie hyperspectrale thermique ). Meeting Proceedings of Sensors and Electronics Panel (SET) Specialists Meeting held at the Belgian...Schäfer et al. use a more sophisticated radiative transfer model which takes into account temperature gradients and the effects of emission and self...Quantitative Spectroscopy and Radiative Transfer , 92, 447–455 (2005). Characterizing and Overcoming Spectral Artifacts in Imaging Fourier-Transform
International Nuclear Information System (INIS)
Joergensen, S.I.
1985-01-01
The subject of this thesis is gas phase ion/molecule reactions as studied by Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry (chapter 2 contains a short description of this method). Three chapters are mainly concerned with mechanistic aspects of gas phase ion/molecule reactions. An equally important aspect of the thesis is the stability and reactivity of α-thio carbanions, dipole stabilized carbanions and homoenolate anions, dealt with in the other four chapters. (Auth.)
The use of the Fourier Transform Infrared spectroscopy to determine adulterants in raw milk
Cassoli,Laerte Dagher; Sartori,Beatriz; Machado,Paulo Fernando
2011-01-01
The objective of this study was to develop calibrations to determine the concentration of some milk adulterants by using the automated methodology of Fourier Transform Infrared (FTIR). For construction of calibrations, samples were collected from 100 farms in the states of São Paulo and Minas Gerais. Samples were tainted with three different adulterants commonly used in the adulteration of raw milk: sodium bicarbonate (SB), sodium citrate (SC) and cheese whey (W). Each adulterant was used at ...
Mitchell, Jennifer K; Pitcher, Desley; McArdle, Bernadette M; Alnefelt, Terese; Duffy, Sandra; Avery, Vicky; Quinn, Ronald J
2007-12-01
Fourteen natural products, known to inhibit other proteins of the Zincin-like fold class, were screened for inhibition of the Zincin-like fold metalloprotease thermolysin using mass spectrometry. Fourier Transform Mass Spectrometry was successful in identifying actinonin, a known inhibitor of astacin and stromelysin, to be an inhibitor of thermolysin. Molecular modelling studies have shown that specificity within the Zincin-like fold is determined by Protein Fold Topology.
International Nuclear Information System (INIS)
Feit, M.D.; Fleck, J.A. Jr.
1989-01-01
We describe a spectral method for solving the paraxial wave equation in cylindrical geometry that is based on expansion of the exponential evolution operator in a Taylor series and use of fast Fourier transforms to evaluate derivatives. A fourth-order expansion gives excellent agreement with a two-transverse-dimensional split-operator calculation at a fraction of the cost in computation time per z step and at a considerable savings in storage
International Nuclear Information System (INIS)
Ibrahim, Amr; Predoi-Cross, Adriana; Teillet, Philippe M.
2010-01-01
Channel spectra are a big problem for those attempting to use synchrotron-based Fourier transform spectra for spectral lineshape studies. Due to the layout of the optical system at the CLS far-infrared beamline, the synchrotron beam undergoes unavoidable multiple reflections on the steering mirrors, beam splitter, several sets of windows, and filters. We present a method for eliminating channel spectra and compare the results of our technique with other methods available in the literature.
Pulsed jet Fourier transform microwave spectroscopy of the BF3-CO complex
Feng, Gang; Gou, Qian; Evangelisti, Luca; Grabow, Jens-Uwe; Caminati, Walther
2017-05-01
The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
Solution of the Doppler broadening function based on the fourier cosine transform
Energy Technology Data Exchange (ETDEWEB)
Goncalves, Alessandro da C [COPPE/UFRJ - Programa de Engenharia Nuclear, Universidade Federal do Rio de Janeiro, P.O. Box 68509, 21941-914 Rio de Janeiro, RJ (Brazil)], E-mail: agoncalves@con.ufrj.br; Martinez, Aquilino S.; Silva, Fernando C. da [COPPE/UFRJ - Programa de Engenharia Nuclear, Universidade Federal do Rio de Janeiro, P.O. Box 68509, 21941-914 Rio de Janeiro, RJ (Brazil)
2008-10-15
This paper provides a new integral representation for the Doppler broadening function {psi}({xi}, x), which is interpreted as being a Fourier cosine transform. This integral form allows the obtaining of an analytical solution in a simple and accurate functional manner as regards the elementary functions. The solution obtained through the new integral representation can be widely used in several applications such as the calculation of self-shielding factors and measurement corrections for the microscopic cross section through the activation technique.
Solution of the Doppler broadening function based on the fourier cosine transform
International Nuclear Information System (INIS)
Goncalves, Alessandro da C; Martinez, Aquilino S.; Silva, Fernando C. da
2008-01-01
This paper provides a new integral representation for the Doppler broadening function ψ(ξ, x), which is interpreted as being a Fourier cosine transform. This integral form allows the obtaining of an analytical solution in a simple and accurate functional manner as regards the elementary functions. The solution obtained through the new integral representation can be widely used in several applications such as the calculation of self-shielding factors and measurement corrections for the microscopic cross section through the activation technique
A Fast Fourier transform stochastic analysis of the contaminant transport problem
Deng, F.W.; Cushman, J.H.; Delleur, J.W.
1993-01-01
A three-dimensional stochastic analysis of the contaminant transport problem is developed in the spirit of Naff (1990). The new derivation is more general and simpler than previous analysis. The fast Fourier transformation is used extensively to obtain numerical estimates of the mean concentration and various spatial moments. Data from both the Borden and Cape Cod experiments are used to test the methodology. Results are comparable to results obtained by other methods, and to the experiments themselves.
Powers, E. J.; Kim, Y. C.; Hong, J. Y.; Roth, J. R.; Krawczonek, W. M.
1978-01-01
A diagnostic, based on fast Fourier-transform spectral analysis techniques, that provides experimental insight into the relationship between the experimentally observable spectral characteristics of the fluctuations and the fluctuation-induced plasma transport is described. The model upon which the diagnostic technique is based and its experimental implementation is discussed. Some characteristic results obtained during the course of an experimental study of fluctuation-induced transport in the electric field dominated NASA Lewis bumpy torus plasma are presented.
Broadband and High-Resolution Static Fourier Transform Spectrometer with Bandpass Sampling.
Özcan, Meriç; Sardari, Behzad
2018-01-01
In this study, experimental demonstration of a static Fourier transform spectrometer (static-FTS), based on division of the spectrum into multiple narrowband signals, is presented. The bandpass sampling technique used in this novel spectrometer solves the Nyquist sampling rate limitations and enables recording of wideband spectrum in high resolution. The proposed spectrometer not only has the potential of operating in a wide spectral range, but also has a resolution potential better than 2 cm -1 .
Nicolas, F; Coëtmellec, S; Brunel, M; Allano, D; Lebrun, D; Janssen, A J E M
2005-11-01
The authors have studied the diffraction pattern produced by a particle field illuminated by an elliptic and astigmatic Gaussian beam. They demonstrate that the bidimensional fractional Fourier transformation is a mathematically suitable tool to analyse the diffraction pattern generated not only by a collimated plane wave [J. Opt. Soc. Am A 19, 1537 (2002)], but also by an elliptic and astigmatic Gaussian beam when two different fractional orders are considered. Simulations and experimental results are presented.
Raman spectroscopy of gases with a Fourier transform spectrometer - The spectrum of D2
Jennings, D. E.; Weber, A.; Brault, J. W.
1986-01-01
Fourier transform spectrometry (FTS) is presently used to record the spontaneous incoherent laser Raman spectra of gases. The high resolution, sensitivity, calibration accuracy and spectral coverage achieved demonstrate the viability of FTS for Raman spectroscopy. Attention is given to the coefficients obtained by fitting measurements obtained from the spectrum of D2, containing both v = 0-0 and 1-0 transitions, to the Dunham (1932) expansion of the vibration-rotation energy levels.
Jelle, Bjørn Petter; Hovde, Per Jostein
2012-01-01
Material characterization may be carried out by the attenuated total reflectance (ATR) Fourier transform infrared (FTIR) radiation spectroscopical technique, which represents a powerful experimental tool. The ATR technique may be applied on both solid state materials, liquids, and gases with none or only minor sample preparations, also including materials which are nontransparent to IR radiation. This facilitation is made possible by pressing the sample directly onto various crystals, for exa...
Fourier Transform Infrared Spectroscopy as a Tool in Analysis of Proteus mirabilis Endotoxins.
Żarnowiec, Paulina; Czerwonka, Grzegorz; Kaca, Wiesław
2017-01-01
Fourier transform infrared spectroscopy (FT-IR) was used to scan whole bacterial cells as well as lipopolysaccharides (LPSs, endotoxins) isolated from them. Proteus mirabilis cells, with chemically defined LPSs, served as a model for the ATR FT-IR method. The paper focuses on three steps of infrared spectroscopy: (1) sample preparation, (2) IR scanning, and (3) multivariate analysis of IR data (principal component analysis, PCA).
Fourier transform infrared spectroscopy of dental unit water line biofilm bacteria
Liaqat, Iram
2009-01-01
Fourier transform-infrared (FT-IR) spectroscopy has become an important tool for rapid analysis of complex biological samples. The infrared absorbance spectrum could be regarded as a “fingerprint” which is a feature of biochemical substances. The FT-IR spectra of fresh and stored dried samples of six bacterial isolates (Klebsiella sp., Bacillus cereus, Bacillus subtilis, Pseudomonas aeruginosa, Achromobacter xylosoxidans and Achromobacter sp.) were observed by variation in sample preparation....
Single-channel color image encryption based on iterative fractional Fourier transform and chaos
Sui, Liansheng; Gao, Bo
2013-06-01
A single-channel color image encryption is proposed based on iterative fractional Fourier transform and two-coupled logistic map. Firstly, a gray scale image is constituted with three channels of the color image, and permuted by a sequence of chaotic pairs which is generated by two-coupled logistic map. Firstly, the permutation image is decomposed into three components again. Secondly, the first two components are encrypted into a single one based on iterative fractional Fourier transform. Similarly, the interim image and third component are encrypted into the final gray scale ciphertext with stationary white noise distribution, which has camouflage property to some extent. In the process of encryption and description, chaotic permutation makes the resulting image nonlinear and disorder both in spatial domain and frequency domain, and the proposed iterative fractional Fourier transform algorithm has faster convergent speed. Additionally, the encryption scheme enlarges the key space of the cryptosystem. Simulation results and security analysis verify the feasibility and effectiveness of this method.
International Nuclear Information System (INIS)
Humbert, Ph.
2005-01-01
In this paper we consider the probability distribution of neutrons in a multiplying assembly. The problem is studied using a space independent one group neutron point reactor model without delayed neutrons. We recall the generating function methodology and analytical results obtained by G.I. Bell when the c 2 approximation is used and we present numerical solutions in the general case, without this approximation. The neutron source induced distribution is calculated using the single initial neutron distribution which satisfies a master (Kolmogorov backward) equation. This equation is solved using the generating function method. The generating function satisfies a differential equation and the probability distribution is derived by inversion of the generating function. Numerical results are obtained using the same methodology where the generating function is the Fourier transform of the probability distribution. Discrete Fourier transforms are used to calculate the discrete time dependent distributions and continuous Fourier transforms are used to calculate the asymptotic continuous probability distributions. Numerical applications are presented to illustrate the method. (author)
[A novel spatial modulation Fourier transform spectrometer with adjustable spectral resolution].
Lian, Yu-Sheng; Liao, Ning-Fang; Lü, Hang; Wu, Wen-Min; Dong, Zhi-Gang
2014-11-01
In the premise of fulfilling the application requirement, the adjustment of spectral resolution can improve efficiency of data acquisition, data processing and data saving. So, by adjusting the spectral resolution, the performance of spectrometer can be improved, and its application range can be extended. To avoid the problems of the fixed spectral resolution of classical Fourier transform spectrometer, a novel type of spatial modulation Fourier transform spectrometer with adjustable spectral resolution is proposed in this paper. The principle of the novel spectrometer and its interferometer is described. The general expressions of the optical path difference and the lateral shear are induced by a ray tracing procedure. The equivalent model of the novel interferometer is analyzed. Meanwhile, the principle of the adjustment of spectral resolution is analyzed. The result shows that the novel spectrometer has the merits of adjustable spectral resolution, high stability, easy assemblage and adjustment etc. This theoretical study will provide the theoretical basis for the design of the spectrometer with adjustable spectral resolution and expand the application range of Fourier transform spectrometer.
Ramachandran, G N; Lakshminarayanan, A V
1971-09-01
A new technique is proposed for the mathematical process of reconstruction of a three-dimensional object from its transmission shadowgraphs; it uses convolutions with functions defined in the real space of the object, without using Fourier transforms. The object is rotated about an axis at right angles to the direction of a parallel beam of radiation, and sections of it normal to the axis are reconstructed from data obtained by scanning the corresponding linear strips in the shadowgraphs at different angular settings. Since the formulae in the convolution method involve only summations over one variable at a time, while a two-dimensional reconstruction with the Fourier transform technique requires double summations, the convolution method is much faster (typically by a factor of 30); the relative increase in speed is larger where greater resolution is required. Tests of the convolution method with computer-simulated shadowgraphs show that it is also more accurate than the Fourier transform method. It has good potentialities for application in electron microscopy and x-radiography. A new method of reconstructing helical structures by this technique is also suggested.
Principle and analysis of a rotational motion Fourier transform infrared spectrometer
Cai, Qisheng; Min, Huang; Han, Wei; Liu, Yixuan; Qian, Lulu; Lu, Xiangning
2017-09-01
Fourier transform infrared spectroscopy is an important technique in studying molecular energy levels, analyzing material compositions, and environmental pollutants detection. A novel rotational motion Fourier transform infrared spectrometer with high stability and ultra-rapid scanning characteristics is proposed in this paper. The basic principle, the optical path difference (OPD) calculations, and some tolerance analysis are elaborated. The OPD of this spectrometer is obtained by the continuously rotational motion of a pair of parallel mirrors instead of the translational motion in traditional Michelson interferometer. Because of the rotational motion, it avoids the tilt problems occurred in the translational motion Michelson interferometer. There is a cosine function relationship between the OPD and the rotating angle of the parallel mirrors. An optical model is setup in non-sequential mode of the ZEMAX software, and the interferogram of a monochromatic light is simulated using ray tracing method. The simulated interferogram is consistent with the theoretically calculated interferogram. As the rotating mirrors are the only moving elements in this spectrometer, the parallelism of the rotating mirrors and the vibration during the scan are analyzed. The vibration of the parallel mirrors is the main error during the rotation. This high stability and ultra-rapid scanning Fourier transform infrared spectrometer is a suitable candidate for airborne and space-borne remote sensing spectrometer.
Directory of Open Access Journals (Sweden)
Siesler H. W.
2006-11-01
Full Text Available The recent extension of the Fourier-Transform (FT technique to the Raman effect has launched Raman spectroscopy into a new era of polymer chemical and physical applications. Thus, the increase in signal-to-noise ratio and the improvement in time resolution have largely enhanced the potential of FT-Raman spectroscopy for analytical applications, the characterization of time-dependent phenomena and the on-line combination with other techniques. Primarily the suppression of fluorescence by shifting the excitation line to the near-infrared (NIR region has contributed to the fast acceptance as an industrial routine tool. Furthermore, the application of fiber optics has opened up the areas of process-control and remote sensing. Les applications de la spectroscopie Raman dans le domaine des polymères sont entrées dans une ère nouvelle, grâce aux récents développements de la technique à transformée de Fourier avec excitation dans le proche infrarouge. L'augmentation du rapport signal sur bruit et l'amélioration de la résolution temporelle ont fortement renforcé les potentialités de la technique en ce qui concerne les applications analytiques, la caractérisation de phénomènes qui dépendent du temps et le couplage en ligne avec d'autres techniques. La suppression du phénomène de fluorescence par déplacement de la longueur d'onde de l'excitatrice dans le proche infrarouge a contribué à l'intégration rapide de l'outil en site industriel. L'emploi de fibres optiques a permis l'accroissement des applications dans le domaine du contrôle des procédés et d'analyser à distance.
Directory of Open Access Journals (Sweden)
Abi Munajad
2018-02-01
Full Text Available Mineral oil is the most popular insulating liquid for high voltage transformers due to its function as a cooling liquid and an electrical insulator. Kraft paper has been widely used as transformer solid insulation for a long time already. The degradation process of transformer paper due to thermal aging in mineral oil can change the physical and chemical structure of the cellulose paper. Fourier transform infrared (FTIR spectroscopy analysis was used to identify changes in the chemical structure of transformer paper aged in mineral oil. FTIR results show that the intensity of the peak absorbance of the O–H functional group decreased with aging but the intensity of the peak absorbance of the C–H and C=O functional groups increased with aging. Changes in the chemical structure of the cellulose paper during thermal aging in mineral oil can be analyzed by an oxidation process of the cellulose paper and the reaction process between the carboxylic acids in the mineral oil and the hydroxyl groups on the cellulose. The correlation between the functional groups and the average number of chain scissions of transformer paper gives initial information that the transformer paper performance can be identified by using a spectroscopic technique as a non-destructive diagnostic technique.
International Nuclear Information System (INIS)
Eaker, C.W.; Schatz, G.C.; De Leon, N.; Heller, E.J.
1984-01-01
Two methods for calculating the good action variables and semiclassical eigenvalues for coupled oscillator systems are presented, both of which relate the actions to the coefficients appearing in the Fourier representation of the normal coordinates and momenta. The two methods differ in that one is based on the exact expression for the actions together with the EBK semiclassical quantization condition while the other is derived from the Sorbie--Handy (SH) approximation to the actions. However, they are also very similar in that the actions in both methods are related to the same set of Fourier coefficients and both require determining the perturbed frequencies in calculating actions. These frequencies are also determined from the Fourier representations, which means that the actions in both methods are determined from information entirely contained in the Fourier expansion of the coordinates and momenta. We show how these expansions can very conveniently be obtained from fast Fourier transform (FFT) methods and that numerical filtering methods can be used to remove spurious Fourier components associated with the finite trajectory integration duration. In the case of the SH based method, we find that the use of filtering enables us to relax the usual periodicity requirement on the calculated trajectory. Application to two standard Henon--Heiles models is considered and both are shown to give semiclassical eigenvalues in good agreement with previous calculations for nondegenerate and 1:1 resonant systems. In comparing the two methods, we find that although the exact method is quite general in its ability to be used for systems exhibiting complex resonant behavior, it converges more slowly with increasing trajectory integration duration and is more sensitive to the algorithm for choosing perturbed frequencies than the SH based method
FFT-BM, Code Accuracy Evaluations with the 1D Fast Fourier Transform (FFT) Methodology
International Nuclear Information System (INIS)
D'Auria, F.
2004-01-01
1 - Description of program or function: FFT-BM is an integrated version of the programs package performing code accuracy evaluations with the 1D Fast Fourier Transform (FFT) methodology. It contains two programs: - CASEM: Takes care of the complete manipulation of data in order to evaluate the quantities through which the FFT method quantifies the code accuracy. - AAWFTO completes the evaluation of the average accuracy (AA) and related weighted frequency (WF) values in order to obtain the AAtot and WFtot values characterising the global calculation performance. 2 - Methods: The Fast Fourier Transform, or FFT, which is based on the Fourier analysis method is an optimised method for calculating the amplitude Vs frequency, of functions or experimental or computed data. In order to apply this methodology, after selecting the parameters to be analyzed, it is necessary to choose the following parameters: - number of curves (exp + calc) to be analyzed; - number of time windows to be analyzed; - sampling frequency; - cut frequency; - time begin and time end of each time window. 3 - Restrictions on the complexity of the problem: Up to 30 curves (exp + calc) and 5 time windows may be analyzed
Izadi Najafabadi, Mohammad
2017-11-06
A relatively high level of stratification (qualitatively: lack of homogeneity) is one of the main advantages of partially premixed combustion over the homogeneous charge compression ignition concept. Stratification can smooth the heat release rate and improve the controllability of combustion. In order to compare stratification levels of different partially premixed combustion strategies or other combustion concepts, an objective and meaningful definition of “stratification level” is required. Such a definition is currently lacking; qualitative/quantitative definitions in the literature cannot properly distinguish various levels of stratification. The main purpose of this study is to objectively define combustion stratification (not to be confused with fuel stratification) based on high-speed OH* chemiluminescence imaging, which is assumed to provide spatial information regarding heat release. Stratification essentially being equivalent to spatial structure, we base our definition on two-dimensional Fourier transforms of photographs of OH* chemiluminescence. A light-duty optical diesel engine has been used to perform the OH* bandpass imaging on. Four experimental points are evaluated, with injection timings in the homogeneous regime as well as in the stratified partially premixed combustion regime. Two-dimensional Fourier transforms translate these chemiluminescence images into a range of spatial frequencies. The frequency information is used to define combustion stratification, using a novel normalization procedure. The results indicate that this new definition, based on Fourier analysis of OH* bandpass images, overcomes the drawbacks of previous definitions used in the literature and is a promising method to compare the level of combustion stratification between different experiments.
Stupin, Daniil D.; Koniakhin, Sergei V.; Verlov, Nikolay A.; Dubina, Michael V.
2017-05-01
The time-domain technique for impedance spectroscopy consists of computing the excitation voltage and current response Fourier images by fast or discrete Fourier transformation and calculating their relation. Here we propose an alternative method for excitation voltage and current response processing for deriving a system impedance spectrum based on a fast and flexible adaptive filtering method. We show the equivalence between the problem of adaptive filter learning and deriving the system impedance spectrum. To be specific, we express the impedance via the adaptive filter weight coefficients. The noise-canceling property of adaptive filtering is also justified. Using the RLC circuit as a model system, we experimentally show that adaptive filtering yields correct admittance spectra and elements ratings in the high-noise conditions when the Fourier-transform technique fails. Providing the additional sensitivity of impedance spectroscopy, adaptive filtering can be applied to otherwise impossible-to-interpret time-domain impedance data. The advantages of adaptive filtering are justified with practical living-cell impedance measurements.
Zarnowiec, Paulina; Lechowicz, Łukasz; Czerwonka, Grzegorz; Kaca, Wiesław
2015-01-01
Methods of human bacterial pathogen identification need to be fast, reliable, inexpensive, and time efficient. These requirements may be met by vibrational spectroscopic techniques. The method that is most often used for bacterial detection and identification is Fourier transform infrared spectroscopy (FTIR). It enables biochemical scans of whole bacterial cells or parts thereof at infrared frequencies (4,000-600 cm(-1)). The recorded spectra must be subsequently transformed in order to minimize data variability and to amplify the chemically-based spectral differences in order to facilitate spectra interpretation and analysis. In the next step, the transformed spectra are analyzed by data reduction tools, regression techniques, and classification methods. Chemometric analysis of FTIR spectra is a basic technique for discriminating between bacteria at the genus, species, and clonal levels. Examples of bacterial pathogen identification and methods of differentiation up to the clonal level, based on infrared spectroscopy, are presented below.
Simplification of gamma-ray spectral data by using Fourier transform
International Nuclear Information System (INIS)
Tominaga, Shoji; Nagata, Shojiro; Nayatani, Yoshinobu; Ueda, Isamu; Sasaki, Satoshi.
1977-01-01
A method is proposed to represent γ-ray response spectra by Fourier series for the purpose of compressing spectral data. The usefulness of the method was confirmed by applying it to a spectral library of a NaI detector. In the method, a response spectrum as a wave is described by superposition of sine (cosine) waves with low frequencies, whose coefficient parameters can be obtained by a Fast Fourier Transform program. The relation between the number of parameters and the fitting error is discussed, and as the result, it is shown that the number of parameters can be reduced to about a half. The merits and features are presented in practical application of the method to the analysis of γ-ray spectra. (auth.)
Double-resolution electron holography with simple Fourier transform of fringe-shifted holograms.
Volkov, V V; Han, M G; Zhu, Y
2013-11-01
We propose a fringe-shifting holographic method with an appropriate image wave recovery algorithm leading to exact solution of holographic equations. With this new method the complex object image wave recovered from holograms appears to have much less traditional artifacts caused by the autocorrelation band present practically in all Fourier transformed holograms. The new analytical solutions make possible a double-resolution electron holography free from autocorrelation band artifacts and thus push the limits for phase resolution. The new image wave recovery algorithm uses a popular Fourier solution of the side band-pass filter technique, while the fringe-shifting holographic method is simple to implement in practice. Published by Elsevier B.V.
Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...
VUV Fourier-Transform absorption study of the np pi (1)Pi(-)(u) nu,N
Glass-Maujean, M.; Jungen, C.; Dickenson, G.D.; Ubachs, W.M.G.; de Oliveira, N.; Joyeux, D.
2015-01-01
Abstract The DESIRS beamline of the SOLEIL synchrotron facility, equipped with a vacuum ultraviolet Fourier-Transform spectrometer has been used to measure Q(N″)(N-N″=0) absorption transitions of the D
Detailed analysis of evolution of the state of polarization in all-fiber polarization transformers.
Zhu, Xiushan; Jain, Ravinder K
2006-10-30
We present a detailed analysis of key attributes and performance characteristics of controllably-spun birefringent-fiber-based all-fiber waveplates or "all fiber polarization transformers" (AFPTs), first proposed and demonstrated by Huang [11]; these AFPTs consist essentially of a long carefully-designed "spin-twisted" high-birefringence fiber, fabricated by slowly varying the spin rate of a birefringent fiber preform (either from very fast to very slow or vice versa) while the fiber is being drawn. The evolution of the eigenstate from a linear polarization state to a circular polarization state, induced by slow variation of the intrinsic structure from linear anisotropy at the unspun end to circular anisotropy at the fast-spun end, enables the AFPT to behave like an all-fiber quarter-wave plate independent of the wavelength of operation. Power coupling between local eigenstates causes unique evolution of the polarization state along the fiber, and has been studied to gain insight into - as well as to understand detailed characteristics of -- the polarization transformation behavior. This has been graphically illustrated via plots of the relative power in these local eigenstates as a function of distance along the length of the fiber and plots of the extinction ratio of the output state of polarization (SOP) as a function of distance and the normalized spin rate. Deeper understanding of such polarization transformers has been further elucidated by quantitative calculations related to two crucial requirements for fabricating practical AFPT devices. Our calculations have also indicated that the polarization mode dispersion behaviour of the AFPT is much smaller than that of the original birefringent fiber. Finally, a specific AFPT was experimentally investigated at two widely-separated wavelengths (1310 nm and 1550 nm) of interest in telecommunications systems applications, further demonstrating and elucidating the broadband character of such AFPTs.
Gómora-Herrera, Diana; Navarrete Bolaños, Juan; Lijanova, Irina V; Olivares-Xometl, Octavio; Likhanova, Natalya V
2018-04-01
The effects exerted by the adsorption of vapors of a non-polar compound (deuterated benzene) and a polar compound (water) on the surface of Ottawa sand and a sample of reservoir sand (Channel), which was previously impregnated with silicon oil or two kinds of surfactants, (2-hydroxyethyl) trimethylammonium oleate (HETAO) and (2-hydroxyethyl)trimethylammonium azelate (HETAA), were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The surface chemistry of the sandstone rocks was elucidated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). Terminal surface groups such as hydroxyls can strongly adsorb molecules that interact with these surface groups (surfactants), resulting in a wettability change. The wettability change effect suffered by the surface after treating it with surfactants was possible to be detected by the DRIFTS technique, wherein it was observed that the surface became more hydrophobic after being treated with silicon oil and HETAO; the surface became more hydrophilic after treating it with HETAA.
DEFF Research Database (Denmark)
Guan, Pengyu; Røge, Kasper Meldgaard; Morioka, Toshio
2016-01-01
We review recent progress in the use of time lens based optical Fourier transformation for advanced optical signal processing, with focus on all-optical generation, detection and format conversion of spectrally-efficient OFDM and N-WDM signals.......We review recent progress in the use of time lens based optical Fourier transformation for advanced optical signal processing, with focus on all-optical generation, detection and format conversion of spectrally-efficient OFDM and N-WDM signals....
DEFF Research Database (Denmark)
Oxenløwe, Leif Katsuo; Galili, Michael; Clausen, A. T:
2006-01-01
A square spectrum is optically Fourier transformed into a square pulse in the time domain. This is used to demultiplex a 160 Gb/s data signal with a significant increase in jitter tolerance to 2.6 ps.......A square spectrum is optically Fourier transformed into a square pulse in the time domain. This is used to demultiplex a 160 Gb/s data signal with a significant increase in jitter tolerance to 2.6 ps....
Kamalian, Morteza; Prilepsky, Jaroslaw E; Le, Son Thai; Turitsyn, Sergei K
2016-08-08
In this work, we introduce the periodic nonlinear Fourier transform (PNFT) method as an alternative and efficacious tool for compensation of the nonlinear transmission effects in optical fiber links. In the Part I, we introduce the algorithmic platform of the technique, describing in details the direct and inverse PNFT operations, also known as the inverse scattering transform for periodic (in time variable) nonlinear Schrödinger equation (NLSE). We pay a special attention to explaining the potential advantages of the PNFT-based processing over the previously studied nonlinear Fourier transform (NFT) based methods. Further, we elucidate the issue of the numerical PNFT computation: we compare the performance of four known numerical methods applicable for the calculation of nonlinear spectral data (the direct PNFT), in particular, taking the main spectrum (utilized further in Part II for the modulation and transmission) associated with some simple example waveforms as the quality indicator for each method. We show that the Ablowitz-Ladik discretization approach for the direct PNFT provides the best performance in terms of the accuracy and computational time consumption.
Fractional Fourier plane image encryption technique using radial hilbert-, and Jigsaw transform
Joshi, Madhusudan; Shakher, Chandra; Singh, Kehar
2010-07-01
A new method for image encryption using integral order radial Hilbert transform (RHT) filter in the fractional Fourier transform (FRT) domain has been proposed. The technique is implemented using the popular double random phase encoding method in the fractional Fourier domain. The random phase masks (RPMs), integral orders of the RHT, fractional orders of FRT, and indices of the Jigsaw transform (JT) have been used as keys for encryption and decryption. Simulation results have been presented and the schematic representation for optical implementation has been proposed. The mean-square-error and signal-to-noise ratio between the decrypted image and the input image have been calculated for the correct as well as incorrect orders of the RHT. Effect of occlusion and noise on the performance of the proposed scheme has also been studied. The robustness of the technique has been verified against attack using partial windows of the correct random phase masks. Similar investigations have also been carried out for the chosen-, and the known-plain-text attacks.
Adaptive synchrosqueezing based on a quilted short-time Fourier transform
Berrian, Alexander; Saito, Naoki
2017-08-01
In recent years, the synchrosqueezing transform (SST) has gained popularity as a method for the analysis of signals that can be broken down into multiple components determined by instantaneous amplitudes and phases. One such version of SST, based on the short-time Fourier transform (STFT), enables the sharpening of instantaneous frequency (IF) information derived from the STFT, as well as the separation of amplitude-phase components corresponding to distinct IF curves. However, this SST is limited by the time-frequency resolution of the underlying window function, and may not resolve signals exhibiting diverse time-frequency behaviors with sufficient accuracy. In this work, we develop a framework for an SST based on a "quilted" short-time Fourier transform (SST-QSTFT), which allows adaptation to signal behavior in separate time-frequency regions through the use of multiple windows. This motivates us to introduce a discrete reassignment frequency formula based on a finite difference of the phase spectrum, ensuring computational accuracy for a wider variety of windows. We develop a theoretical framework for the SST-QSTFT in both the continuous and the discrete settings, and describe an algorithm for the automatic selection of optimal windows depending on the region of interest. Using synthetic data, we demonstrate the superior numerical performance of SST-QSTFT relative to other SST methods in a noisy context. Finally, we apply SST-QSTFT to audio recordings of animal calls to demonstrate the potential of our method for the analysis of real bioacoustic signals.
Directory of Open Access Journals (Sweden)
Rekha Gautam
Full Text Available Acetaminophen is a widely prescribed drug used to relieve pain and fever; however, it is a leading cause of drug-induced liver injury and a burden on public healthcare. In this study, hepatotoxicity in mice post oral dosing of acetaminophen was investigated using liver and sera samples with Fourier Transform Infrared microspectroscopy. The infrared spectra of acetaminophen treated livers in BALB/c mice show decrease in glycogen, increase in amounts of cholesteryl esters and DNA respectively. Rescue experiments using L-methionine demonstrate that depletion in glycogen and increase in DNA are abrogated with pre-treatment, but not post-treatment, with L-methionine. This indicates that changes in glycogen and DNA are more sensitive to the rapid depletion of glutathione. Importantly, analysis of sera identified lowering of glycogen and increase in DNA and chlolesteryl esters earlier than increase in alanine aminotransferase, which is routinely used to diagnose liver damage. In addition, these changes are also observed in C57BL/6 and Nos2(-/- mice. There is no difference in the kinetics of expression of these three molecules in both strains of mice, the extent of damage is similar and corroborated with ALT and histological analysis. Quantification of cytokines in sera showed increase upon APAP treatment. Although the levels of Tnfα and Ifnγ in sera are not significantly affected, Nos2(-/- mice display lower Il6 but higher Il10 levels during this acute model of hepatotoxicity. Overall, this study reinforces the growing potential of Fourier Transform Infrared microspectroscopy as a fast, highly sensitive and label-free technique for non-invasive diagnosis of liver damage. The combination of Fourier Transform Infrared microspectroscopy and cytokine analysis is a powerful tool to identify multiple biomarkers, understand differential host responses and evaluate therapeutic regimens during liver damage and, possibly, other diseases.
Beyond MOS and fibers: Optical Fourier-transform Imaging Unit for Cananea Observatory (OFIUCO)
Nieto-Suárez, M. A.; Rosales-Ortega, F. F.; Castillo, E.; García, P.; Escobedo, G.; Sánchez, S. F.; González, J.; Iglesias-Páramo, J.; Mollá, M.; Chávez, M.; Bertone, E.; et al.
2017-11-01
Many physical processes in astronomy are still hampered by the lack of spatial and spectral resolution, and also restricted to the field-of-view (FoV) of current 2D spectroscopy instruments available worldwide. It is due to that, many of the ongoing or proposed studies are based on large-scale imaging and/or spectroscopic surveys. Under this philosophy, large aperture telescopes are dedicated to the study of intrinsically faint and/or distance objects, covering small FoVs, with high spatial resolution, while smaller telescopes are devoted to wide-field explorations. However, future astronomical surveys, should be addressed by acquiring un-biases, spatially resolved, high-quality spectroscopic information for a wide FoV. Therefore, and in order to improve the current instrumental offer in the Observatorio Astrofísico Guillermo Haro (OAGH) in Cananea, Mexico (INAOE); and to explore a possible instrument for the future Telescopio San Pedro Mártir (6.5m), we are currently integrating at INAOE an instrument prototype that will provide us with un-biased wide-field (few arcmin) spectroscopic information, and with the flexibility of operating at different spectral resolutions (R 1-20000), with a spatial resolution limited by seeing, and therefore, to be used in a wide range of astronomical problems. This instrument called OFIUCO: Optical Fourier-transform Imaging Unit for Cananea Observatory, will make use of the Fourier Transform Spectroscopic technique, which has been proved to be feasible in the optical wavelength range (350-1000 nm) with designs such as SITELLE (CFHT). We describe here the basic technical description of a Fourier transform spectrograph with important modifications from previous astronomical versions, as well as the technical advantages and weakness, and the science cases in which this instrument can be implemented.
Applications of asynoptic space - Time Fourier transform methods to scanning satellite measurements
Lait, Leslie R.; Stanford, John L.
1988-01-01
A method proposed by Salby (1982) for computing the zonal space-time Fourier transform of asynoptically acquired satellite data is discussed. The method and its relationship to other techniques are briefly described, and possible problems in applying it to real data are outlined. Examples of results obtained using this technique are given which demonstrate its sensitivity to small-amplitude signals. A number of waves are found which have previously been observed as well as two not heretofore reported. A possible extension of the method which could increase temporal and longitudinal resolution is described.
Wave scattering theory a series approach based on the Fourier transformation
Eom, Hyo J
2001-01-01
The book provides a unified technique of Fourier transform to solve the wave scattering, diffraction, penetration, and radiation problems where the technique of separation of variables is applicable. The book discusses wave scattering from waveguide discontinuities, various apertures, and coupling structures, often encountered in electromagnetic, electrostatic, magnetostatic, and acoustic problems. A system of simultaneous equations for the modal coefficients is formulated and the rapidly-convergent series solutions amenable to numerical computation are presented. The series solutions find practical applications in the design of microwave/acoustic transmission lines, waveguide filters, antennas, and electromagnetic interference/compatibilty-related problems.
Analysis of the Interference Modulation Depth in the Fourier Transform Spectrometer
Directory of Open Access Journals (Sweden)
Rilong Liu
2015-01-01
Full Text Available Based on the principle of the Michelson interferometer, the paper briefly describes the theoretical significance and calculates and deduces three expressions of the interference modulation depth. The influence of the surface shape error of plane mirror on modulation depth is analyzed, and the tolerance of error is also pointed out. Moreover, the dependence of modulation depth on the reflectance change of beam splitter interface is also analyzed, and the curve is given. It is concluded that this paper is of general significance for the Fourier transform spectrometer based on the principle of the Michelson two-beam interference.
Parsons, C. L.; Gerlach, J. C.; Whitehurst, M.
1982-01-01
The development of a prototype, ground-based, Sun-pointed Michelson interferometric spectrometer is described. Its intended use is to measure the atmospheric amount of various gases which absorb in the near-infrared, visible, and near-ultraviolet portions of the electromagnetic spectrum. Preliminary spectra which contain the alpha, 0.8 micrometer, and rho sigma tau water vapor absorption bands in the near-infrared are presented to indicate the present capability of the system. Ultimately, the spectrometer can be used to explore the feasible applications of Fourier transform spectroscopy in the ultraviolet where grating spectrometers were used exclusively.
International Nuclear Information System (INIS)
Kyeremeh, P.O.
2011-01-01
Current-available brachytherapy dose computation algorithms ignore heterogeneities such as tissue-air interfaces, shielded gynaecological colpostats, and tissue-composition variations in source implants despite dose computation errors as large as 40%. A convolution kernel, which takes into consideration anisotropy of the dose distribution around a brachytherapy source, and to compute dose in the presence of tissue and applicator heterogeneities, has been established. Resulting from the convolution kernel are functions with polynomial and exponential terms. the solution to the convolution integral was represented by the Fast Fourier transform. The Fast Fourier transform has shown enough potency in accounting for errors due to these heterogeneities and the versatility of this Fast Fourier transform is evident from its capability of switching in between fields. Thus successful procedures in external beam could be adopted in brachytherapy to a yield similar effect. A dose deposition kernel was developed for a 64x64x64 matrix size with wrap around ordering and convoluted with the distribution of the sources in 3D. With MatLab's inverse Fast Fourier transform, dose rate distribution for a given array of interstitial sources, typical of brachytherapy was calculated. The shape of the dose rate distribution peaks appeared comparable with the output expected from computerized treatment planning systems for brachytherapy. Subsequently, the study confirmed the speed and accuracy of dose computation using the FFT convolution as well juxtaposed. Although, dose rate peaks from both the FFT convolution and the TPS(TG43) did not compare quantitatively, which was mainly due to the TPS(TG43) initiation computations from the origin (0,0,0) unlike the FFT convolution which uses sampling points; N=1,2,3..., there is a strong basis for establishing parity since the dose rate peaks compared qualitatively. With both modes compared, the discrepancies in the dose rates ranged between 3.6% to
A symplectic Poisson solver based on Fast Fourier Transformation. The first trial
Energy Technology Data Exchange (ETDEWEB)
Vorobiev, L.G. [Gosudarstvennyj Komitet po Ispol`zovaniyu Atomnoj Ehnergii SSSR, Moscow (Russian Federation). Inst. Teoreticheskoj i Ehksperimental`noj Fiziki; Hirata, Kohji
1995-11-01
A symplectic Poisson solver calculates numerically a potential and fields due to a 2D distribution of particles in a way that the symplecticity and smoothness are assured automatically. Such a code, based on Fast Fourier Transformation combined with Bicubic Interpolation, is developed for the use in multi-turn particle simulation in circular accelerators. Beside that, it may have a number of applications, where computations of space charge forces should obey a symplecticity criterion. Detailed computational schemes of all algorithms will be outlined to facilitate practical programming. (author).
First measurements using the ALS Soft X-ray Fourier Transform spectrometer
Energy Technology Data Exchange (ETDEWEB)
Moler, E.J.; Duarte, R.M.; Howells, M.R.; Hussain, Z.; Spring, J. [and others
1997-08-01
Commissioning of a Fourier Transform Soft X-ray spectrometer (FT-SX) is under way at the Advanced Light Source (ALS), Lawrence Berkeley National Laboratory, as a branch of beamline 9.3.2. The spectrometer is a novel soft x-ray interferometer designed for ultra-high resolution spectroscopy in the photon experimental results which sensitively test models of correlated electron processes in atomic and molecular physics. The design criteria and consequent technical challenges posed by the short wavelengths of x-rays and desired resolving power are discussed. The fundamental and practical aspects of soft x-ray interferometry are also explored.
A symplectic Poisson solver based on Fast Fourier Transformation. The first trial
International Nuclear Information System (INIS)
Vorobiev, L.G.; Hirata, Kohji.
1995-11-01
A symplectic Poisson solver calculates numerically a potential and fields due to a 2D distribution of particles in a way that the symplecticity and smoothness are assured automatically. Such a code, based on Fast Fourier Transformation combined with Bicubic Interpolation, is developed for the use in multi-turn particle simulation in circular accelerators. Beside that, it may have a number of applications, where computations of space charge forces should obey a symplecticity criterion. Detailed computational schemes of all algorithms will be outlined to facilitate practical programming. (author)
Fourier-transform microwave spectroscopy of a halogen substituted Criegee intermediate ClCHOO
Cabezas, Carlos; Guillemin, Jean-Claude; Endo, Yasuki
2016-11-01
Pure rotational spectra of the chloro-substituted Criegee intermediate (ClCHOO) were observed by Fourier-transform microwave spectroscopy. Two conformers (syn and anti) of the isolated molecule were identified from the rotational spectra of the parent and 37Cl and 13C isotopologues detected in natural abundance. Rotational constants, centrifugal distortion constants, and all components of the nuclear quadrupole coupling tensor were determined for both conformers. Structural features of the molecule have been rationalized with supporting ab initio calculations and the natural bond orbital analysis, which suggest that the conformational preferences are driven by hyperconjugative effects.
The application of Fast Fourier transforms to the primitive equations of Boussinesq convection
International Nuclear Information System (INIS)
Parrott, A.K.
1976-01-01
We have described a numerical scheme which is second-order in both space and time. The use of Fast Fourier Transform techniques for the solution of pressure equation guarantees accurate incompressibility at all time and enabled us to consider using iteration for part of this scheme. The iterations converge satisfactorily for values of the timestep of the order of one-half to one-quarter of the space step. Numerical calculations are being undertaken to clarify the range of Reynolds numbers and timestep over which the iteration converges. (orig.) [de
Beecken, Brian P.; Kleinman, Randall R.
2004-01-01
New developments in infrared sensor technology have potentially made possible a new space-based system which can measure far-infrared radiation at lower costs (mass, power and expense). The Stationary Imaging Fourier Transform Spectrometer (SIFTS) proposed by NASA Langley Research Center, makes use of new detector array technology. A mathematical model which simulates resolution and spectral range relationships has been developed for analyzing the utility of such a radically new approach to spectroscopy. Calculations with this forward model emulate the effects of a detector array on the ability to retrieve accurate spectral features. Initial computations indicate significant attenuation at high wavenumbers.
Almeida, Francylaine S; Lima, Sandro M; Andrade, Luis H C; Súarez, Yzel R
2012-07-01
Fourier transform infrared photoacoustic spectroscopy (FTIR-PAS) was applied to nineteen fish species in Brazil's Upper Paraná River basin to identify differences in the structural composition of their scales. To differentiate the species, a canonical discriminant analysis was used to indicate the most important absorption peaks in the mid-infrared region. Significant differences were found in the chemical composition of scales among the studied fish species, with Wilk's lambda = 5.2 × 10(-6), F((13,18,394)) = 37.57, and P absorbance is related to the biological traits of each species. This procedure can also be used to complement evolutionary studies.
Mastering the discrete Fourier transform in one, two or several dimensions pitfalls and artifacts
Amidror, Isaac
2013-01-01
The discrete Fourier transform (DFT) is an extremely useful tool that finds application in many different disciplines. However, its use requires caution. The aim of this book is to explain the DFT and its various artifacts and pitfalls and to show how to avoid these (whenever possible), or at least how to recognize them in order to avoid misinterpretations. This concentrated treatment of the DFT artifacts and pitfalls in a single volume is, indeed, new, and it makes this book a valuable source of information for the widest possible range of DFT users. Special attention is given to the one and
Assessment of fibre orientation in reinforced concrete using Fourier image transform.
Redon; Chermant; Chermant; Coster
1998-09-01
In this study, ribbon-shaped amorphous cast-iron fibres were used to reinforce a concrete matrix. X-ray photographs have been taken to detect fibres in situ. Their orientation has been investigated by automatic image analysis methods. However, this measurement should not be influenced by the digitization on the square frame of the analyser. For that purpose, the Fourier transform was used rather than the rose of direction method. This analysis revealed the transverse isotropic nature of the spatial arrangement of these fibres, whose axis of revolution corresponds to the concrete casting axis. Such a morphological characterization of the fibre-reinforced concrete reveals its mechanical behaviour.
Response of multiferroic composites inferred from a fast-Fourier-transform-based numerical scheme
International Nuclear Information System (INIS)
Brenner, Renald; Bravo-Castillero, Julián
2010-01-01
The effective response and the local fields within periodic magneto-electric multiferroic composites are investigated by means of a numerical scheme based on fast Fourier transforms. This computational framework relies on the iterative resolution of coupled series expansions for the magnetic, electric and strain fields. By using an augmented Lagrangian formulation, a simple and robust procedure which makes use of the uncoupled Green operators for the elastic, electrostatics and magnetostatics problems is proposed. Its accuracy is assessed in the cases of laminated and fibrous two-phase composites for which analytical solutions exist
Determination of precise X-ray diffraction angles by fast Fourier transform
International Nuclear Information System (INIS)
Tokita, S.; Kojima, T.
1987-01-01
A new analytical method is presented for the separation of two or more closely overlapping X-ray diffraction lines using the narrowly distributed Gaussian function and one-dimensional fast Fourier transform pair. To test the method, the diffraction lines associated with characteristic Kα 1 and Kα 2 rays are measured by an X-ray diffractometer using a Brazilian quartz powder as a standard sample. It is found that the observed diffraction lines can be completely separated into Kα 1 and Kα 2 lines and that the accuracy of those diffraction angles is better than 2x10 -4 . (orig.)
A compact, high numerical aperture imaging Fourier transform spectrometer and its application
Alcock, R. D.; Coupland, J. M.
2006-11-01
This paper describes a compact imaging Fourier transform spectrometer with high numerical aperture. In comparison with other optical arrangements in which extended interferometer paths are required for the inclusion of dispersion compensation optics, this technique utilizes a rudimentary cubic beam splitter based Michelson interferometer with minimal optical path so that the numerical aperture of the system is maximized. Mathematical modelling is presented showing that the fringe distortions caused by the dispersion in the cubic beam splitter can be entirely removed without any loss of the spectral information. An illustration of the power of the technique is given classifying between different plant foliage performed using a Fisher discriminant function based optimal linear filtering.
International Nuclear Information System (INIS)
Kleingeld, J.C.
1984-01-01
An important field in which Fourier-transform ion cyclotron resonance has useful applications is that of gas phase ion chemistry, the subject of this thesis. First, the general picture of ion-molecule reactions in the gas phase is discussed. Next, some positive ion-molecule reactions are described, whereas the remaining chapters deal with negative ion-molecule reactions. Most of these studies have been performed using the FT-ICR method. Reactions involving H 3 O - and NH 4 - ions are described whereas the other chapters deal with larger organic complexes. (Auth.)
International Nuclear Information System (INIS)
Marinescu, D.C.; Radulescu, T.G.
1977-06-01
The Integral Fourier Transform has a large range of applications in such areas as communication theory, circuit theory, physics, etc. In order to perform discrete Fourier Transform the Finite Fourier Transform is defined; it operates upon N samples of a uniformely sampled continuous function. All the properties known in the continuous case can be found in the discrete case also. The first part of the paper presents the relationship between the Finite Fourier Transform and the Integral one. The computing of a Finite Fourier Transform is a problem in itself since in order to transform a set of N data we have to perform N 2 ''operations'' if the transformation relations are used directly. An algorithm known as the Fast Fourier Transform (FFT) reduces this figure from N 2 to a more reasonable Nlog 2 N, when N is a power of two. The original Cooley and Tuckey algorithm for FFT can be further improved when higher basis are used. The price to be paid in this case is the increase in complexity of such algorithms. The recurrence relations and a comparation among such algorithms are presented. The key point in understanding the application of FFT resides in the convolution theorem which states that the convolution (an N 2 type procedure) of the primitive functions is equivalent to the ordinar multiplication of their transforms. Since filtering is actually a convolution process we present several procedures to perform digital filtering by means of FFT. The best is the one using the segmentation of records and the transformation of pairs of records. In the digital processing of signals, besides digital filtering a special attention is paid to the estimation of various statistical characteristics of a signal as: autocorrelation and correlation functions, periodiograms, density power sepctrum, etc. We give several algorithms for the consistent and unbiased estimation of such functions, by means of FFT. (author)
Hennelly, Bryan M.; Sheridan, John T.
2005-05-01
By use of matrix-based techniques it is shown how the space-bandwidth product (SBP) of a signal, as indicated by the location of the signal energy in the Wigner distribution function, can be tracked through any quadratic-phase optical system whose operation is described by the linear canonical transform. Then, applying the regular uniform sampling criteria imposed by the SBP and linking the criteria explicitly to a decomposition of the optical matrix of the system, it is shown how numerical algorithms (employing interpolation and decimation), which exhibit both invertibility and additivity, can be implemented. Algorithms appearing in the literature for a variety of transforms (Fresnel, fractional Fourier) are shown to be special cases of our general approach. The method is shown to allow the existing algorithms to be optimized and is also shown to permit the invention of many new algorithms.
Hu, Yong; Peng, Silong; Bi, Yiming; Tang, Liang
2012-12-21
A traditional multivariate calibration transfer method such as piecewise direct standardization (PDS) is usually applied to quantitative analysis. To make the method apply to qualitative analysis of Fourier Transform Infrared spectroscopy (FTIR), we propose an improved calibration transfer method based on the maximum margin criterion (CTMMC). The new method not only considers the spectral changes under different conditions, but also takes into account the geometric characteristics of spectra from different classes, so the transformed spectra from different classes will be separated as far as possible, and this will improve the performance of the follow-up qualitative analysis. A comparative study is provided between the proposed method CTMMC and other traditional calibration transfer methods on two data sets. Experimental results show that the proposed method can achieve better performance than previous methods.
Source brightness fluctuation correction of solar absorption fourier transform mid infrared spectra
Directory of Open Access Journals (Sweden)
T. Ridder
2011-06-01
Full Text Available The precision and accuracy of trace gas observations using solar absorption Fourier Transform infrared spectrometry depend on the stability of the light source. Fluctuations in the source brightness, however, cannot always be avoided. Current correction schemes, which calculate a corrected interferogram as the ratio of the raw DC interferogram and a smoothed DC interferogram, are applicable only to near infrared measurements. Spectra in the mid infrared spectral region below 2000 cm^{−1} are generally considered uncorrectable, if they are measured with a MCT detector. Such measurements introduce an unknown offset to MCT interferograms, which prevents the established source brightness fluctuation correction. This problem can be overcome by a determination of the offset using the modulation efficiency of the instrument. With known modulation efficiency the offset can be calculated, and the source brightness correction can be performed on the basis of offset-corrected interferograms. We present a source brightness fluctuation correction method which performs the smoothing of the raw DC interferogram in the interferogram domain by an application of a running mean instead of high-pass filtering the corresponding spectrum after Fourier transformation of the raw DC interferogram. This smoothing can be performed with the onboard software of commercial instruments. The improvement of MCT spectra and subsequent ozone profile and total column retrievals is demonstrated. Application to InSb interferograms in the near infrared spectral region proves the equivalence with the established correction scheme.
Directory of Open Access Journals (Sweden)
Qiu Bo
2008-01-01
Full Text Available Binaural cue coding (BCC is an efficient technique for spatial audio rendering by using the side information such as interchannel level difference (ICLD, interchannel time difference (ICTD, and interchannel correlation (ICC. Of the side information, the ICTD plays an important role to the auditory spatial image. However, inaccurate estimation of the ICTD may lead to the audio quality degradation. In this paper, we develop a novel ICTD estimation algorithm based on the nonuniform discrete Fourier transform (NDFT and integrate it with the BCC approach to improve the decoded auditory image. Furthermore, a new subjective assessment method is proposed for the evaluation of auditory image widths of decoded signals. The test results demonstrate that the NDFT-based scheme can achieve much wider and more externalized auditory image than the existing BCC scheme based on the discrete Fourier transform (DFT. It is found that the present technique, regardless of the image width, does not deteriorate the sound quality at the decoder compared to the traditional scheme without ICTD estimation.
Brauns, Eric B; Dyer, R Brian
2006-08-01
The work presented in this paper details the design and performance characteristics of a new hyperspectral visible imaging technique. Rather than using optical filters or a dispersing element, this design implements Fourier transform spectroscopy to achieve spectral discrimination. One potentially powerful application of this new technology is the non-destructive analysis and authentication of written and printed documents. Document samples were prepared using red, blue, and black inks. The samples were later altered using a different ink of the same color. While the alterations are undetectable to the naked eye, the alterations involving the blue and black inks were easily detected when the spectrally resolved images were viewed. Analysis of the sample using the red inks was unsuccessful. A 2004 series 20 US dollars bill was imaged to demonstrate the application to document authentication. The results argue that counterfeit detection and quality control during printing are plausible applications of Fourier transform hyperspectral visible imaging. All of the images were subjected to fuzzy c-means cluster analysis in an effort to objectively analyze and automate image analysis. Our results show that cluster analysis can distinguish image features that have remarkably similar visible transmission spectra.
High-speed fan-beam reconstruction using direct two-dimensional Fourier transform method
International Nuclear Information System (INIS)
Niki, Noboru; Mizutani, Toshio; Takahashi, Yoshizo; Inouye, Tamon.
1984-01-01
Since the first development of X-ray computer tomography (CT), various efforts have been made to obtain high quality of high-speed image. However, the development of high resolution CT and the ultra-high speed CT to be applied to hearts is still desired. The X-ray beam scanning method was already changed from the parallel beam system to the fan-beam system in order to greatly shorten the scanning time. Also, the filtered back projection (DFBP) method has been employed to directly processing fan-beam projection data as reconstruction method. Although the two-dimensional Fourier transform (TFT) method significantly faster than FBP method was proposed, it has not been sufficiently examined for fan-beam projection data. Thus, the ITFT method was investigated, which first executes rebinning algorithm to convert the fan-beam projection data to the parallel beam projection data, thereafter, uses two-dimensional Fourier transform. By this method, although high speed is expected, the reconstructed images might be degraded due to the adoption of rebinning algorithm. Therefore, the effect of the interpolation error of rebinning algorithm on the reconstructed images has been analyzed theoretically, and finally, the result of the employment of spline interpolation which allows the acquisition of high quality images with less errors has been shown by the numerical and visual evaluation based on simulation and actual data. Computation time was reduced to 1/15 for the image matrix of 512 and to 1/30 for doubled matrix. (Wakatsuki, Y.)
Fourier Transform Ultrasound Spectroscopy for the determination of wave propagation parameters.
Pal, Barnana
2017-01-01
The reported results for ultrasonic wave attenuation constant (α) in pure water show noticeable inconsistency in magnitude. A "Propagating-Wave" model analysis of the most popular pulse-echo technique indicates that this is a consequence of the inherent wave propagation characteristics in a bounded medium. In the present work Fourier Transform Ultrasound Spectroscopy (FTUS) is adopted to determine ultrasonic wave propagation parameters, the wave number (k) and attenuation constant (α) at 1MHz frequency in tri-distilled water at room temperature (25°C). Pulse-echo signals obtained under same experimental conditions regarding the exciting input signal and reflecting boundary wall of the water container for various lengths of water columns are captured. The Fast Fourier Transform (FFT) components of the echo signals are taken to compute k, α and r, the reflection constant at the boundary, using Oak Ridge and Oxford method. The results are compared with existing literature values. Copyright © 2016 Elsevier B.V. All rights reserved.
D'Alessandro, Maria Michela; Gennaro, Giuseppe; Tralongo, Pietro; Maringhini, Silvio
2017-05-01
Prevalence of urinary calculi in children has been increasing in the past years. We performed an analysis of the chemical composition of stones formers of the pediatric population in our geographical area over the years 2005 to 2013. Fourier transform infrared spectroscopy was employed for the determination of the calculus composition of a group of Sicilian children, and metabolic studies were performed to formulate the correct diagnosis and establish therapy. The prevalence of stone formation was much higher for boys than for girls, with a sex ratio of 1.9:1. The single most frequent component was found to be calcium oxalate monohydrate, and calcium oxalates (pure or mixed calculi) were the overall most frequent components. Calcium phosphates ranked 2nd for frequency, most often in mixed calculi, while urates ranked 3rd. The metabolic disorder most often associated with pure calcium oxalate monohydrate calculi was hypocitraturia, while hyperoxaluria was predominantly associated with calcium oxalate dihydrate calculi. Mixed calculi had the highest prevalence in our pediatric population. Our data showed that Fourier transform infrared spectroscopy was a useful tool for the determination of the calculi composition.
A fractional Fourier transform analysis of the scattering of ultrasonic waves
Tant, Katherine M.M.; Mulholland, Anthony J.; Langer, Matthias; Gachagan, Anthony
2015-01-01
Many safety critical structures, such as those found in nuclear plants, oil pipelines and in the aerospace industry, rely on key components that are constructed from heterogeneous materials. Ultrasonic non-destructive testing (NDT) uses high-frequency mechanical waves to inspect these parts, ensuring they operate reliably without compromising their integrity. It is possible to employ mathematical models to develop a deeper understanding of the acquired ultrasonic data and enhance defect imaging algorithms. In this paper, a model for the scattering of ultrasonic waves by a crack is derived in the time–frequency domain. The fractional Fourier transform (FrFT) is applied to an inhomogeneous wave equation where the forcing function is prescribed as a linear chirp, modulated by a Gaussian envelope. The homogeneous solution is found via the Born approximation which encapsulates information regarding the flaw geometry. The inhomogeneous solution is obtained via the inverse Fourier transform of a Gaussian-windowed linear chirp excitation. It is observed that, although the scattering profile of the flaw does not change, it is amplified. Thus, the theory demonstrates the enhanced signal-to-noise ratio permitted by the use of coded excitation, as well as establishing a time–frequency domain framework to assist in flaw identification and classification. PMID:25792967
Hewagama, TIlak; Aslam, Shahid; Talabac, Stephen; Allen, John E., Jr.; Annen, John N.; Jennings, Donald E.
2011-01-01
Fourier transform spectrometers have a venerable heritage as flight instruments. However, obtaining an accurate spectrum exacts a penalty in instrument mass and power requirements. Recent advances in a broad class of non-scanning Fourier transform spectrometer (FTS) devices, generally called spatial heterodyne spectrometers, offer distinct advantages as flight optimized systems. We are developing a miniaturized system that employs photonics lightwave circuit principles and functions as an FTS operating in the 7-14 micrometer spectral region. The inteferogram is constructed from an ensemble of Mach-Zehnder interferometers with path length differences calibrated to mimic scan mirror sample positions of a classic Michelson type FTS. One potential long-term application of this technology in low cost planetary missions is the concept of a self-contained sensor system. We are developing a systems architecture concept for wide area in situ and remote monitoring of characteristic properties that are of scientific interest. The system will be based on wavelength- and resolution-independent spectroscopic sensors for studying atmospheric and surface chemistry, physics, and mineralogy. The self-contained sensor network is based on our concept of an Addressable Photonics Cube (APC) which has real-time flexibility and broad science applications. It is envisaged that a spatially distributed autonomous sensor web concept that integrates multiple APCs will be reactive and dynamically driven. The network is designed to respond in an event- or model-driven manner or reconfigured as needed.
Fourier Transform Surface Plasmon Resonance of Nanodisks Embedded in Magnetic Nanorods.
Jung, Insub; Ih, Seongkeun; Yoo, Haneul; Hong, Seunghun; Park, Sungho
2018-03-14
In this study, we demonstrate the synthesis and application of magnetic plasmonic gyro-nanodisks (GNDs) for Fourier transform surface plasmon resonance based biodetection. Plasmonically active and magnetically responsive gyro-nanodisks were synthesized using electrochemical methods with anodized aluminum templates. Due to the unique properties of GNDs (magnetic responsiveness and surface plasmon bands), periodic extinction signals were generated under an external rotating magnetic field, which is, in turn, converted into frequency domains using Fourier transformation. After the binding of a target on GNDs, an increase in the shear force causes a shift in the frequency domain, which allows us to investigate biodetection for HA1 (the influenza virus). Most importantly, by modulating the number and the location of plasmonic nanodisks (a method for controlling the hydrodynamic forces by rationally designing the nanomaterial architecture), we achieved enhanced biodetection sensitivity. We expect that our results will contribute to improved sensing module performance, as well as a better understanding of dynamic nanoparticle systems, by harnessing the perturbed periodic fluctuation of surface plasmon bands under the modulated magnetic field.
Algorithm, applications and evaluation for protein comparison by Ramanujan Fourier transform.
Zhao, Jian; Wang, Jiasong; Hua, Wei; Ouyang, Pingkai
2015-12-01
The amino acid sequence of a protein determines its chemical properties, chain conformation and biological functions. Protein sequence comparison is of great importance to identify similarities of protein structures and infer their functions. Many properties of a protein correspond to the low-frequency signals within the sequence. Low frequency modes in protein sequences are linked to the secondary structures, membrane protein types, and sub-cellular localizations of the proteins. In this paper, we present Ramanujan Fourier transform (RFT) with a fast algorithm to analyze the low-frequency signals of protein sequences. The RFT method is applied to similarity analysis of protein sequences with the Resonant Recognition Model (RRM). The results show that the proposed fast RFT method on protein comparison is more efficient than commonly used discrete Fourier transform (DFT). RFT can detect common frequencies as significant feature for specific protein families, and the RFT spectrum heat-map of protein sequences demonstrates the information conservation in the sequence comparison. The proposed method offers a new tool for pattern recognition, feature extraction and structural analysis on protein sequences. Copyright © 2015 Elsevier Ltd. All rights reserved.
Chen, Huipeng; Li, Mengyuan; Zhang, Yi; Xie, Huikai; Chen, Chang; Peng, Zhangming; Su, Shaohui
2018-02-08
Incorporating linear-scanning micro-electro-mechanical systems (MEMS) micromirrors into Fourier transform spectral acquisition systems can greatly reduce the size of the spectrometer equipment, making portable Fourier transform spectrometers (FTS) possible. How to minimize the tilting of the MEMS mirror plate during its large linear scan is a major problem in this application. In this work, an FTS system has been constructed based on a biaxial MEMS micromirror with a large-piston displacement of 180 μm, and a biaxial H∞ robust controller is designed. Compared with open-loop control and proportional-integral-derivative (PID) closed-loop control, H∞ robust control has good stability and robustness. The experimental results show that the stable scanning displacement reaches 110.9 μm under the H∞ robust control, and the tilting angle of the MEMS mirror plate in that full scanning range falls within ±0.0014°. Without control, the FTS system cannot generate meaningful spectra. In contrast, the FTS yields a clean spectrum with a full width at half maximum (FWHM) spectral linewidth of 96 cm -1 under the H∞ robust control. Moreover, the FTS system can maintain good stability and robustness under various driving conditions.
Monitoring wine aging with Fourier transform infrared spectroscopy (FT-IR
Directory of Open Access Journals (Sweden)
Basalekou Marianthi
2015-01-01
Full Text Available Oak wood has commonly been used in wine aging but recently other wood types such as Acacia and Chestnut, have attracted the interest of the researchers due to their possible positive contribution to wine quality. However, only the use of oak and chestnut woods is approved by the International Enological Codex of the International Organisation of Vine and Wine. In this study Fourier Transform (FT-mid-infrared spectroscopy combined with Discriminant Analysis was used to differentiate wines aged in barrels made from French oak, American oak, Acacia and Chestnut and in tanks with oak chips, over a period of 12 months. Two red (Mandilaria, Kotsifali and two white (Vilana, Dafni native Greek grape varieties where used to produce four wines. The Fourier Transform Infrared (FT-IR spectra of the samples were recorded on a Zinc Selenide (ZnSe window after incubation at 40 °C for 30 min. A complete differentiation of the samples according to both the type of wood used and the contact time was achieved based on their FT-IR spectra.
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Muthuramalingam Uthaya Siva
2013-10-01
Full Text Available Objective: To investigate functional groups of toxic spines in stingray by Fourier transform infrared spectroscopic analysis. Methods: The venom extract of Himantura gerrardi, Himantura imbricata and Pastinachus sephen were centrifuged at 6 000 r/min for 10 min. The supernatant was collected and preserved separately in methanol, ethanol, chloroform, acetone (1:2 and then soaked in the mentioned solvents for 48 h. Then extracts were filtered and used for Fourier transform infrared spectroscopic analysis. Results: The results identified that the presence of free amino acids and protein having β-sheet and random coiled secondary structure. The presence of O-H stretch, C=O stretch, C-H stretch, N-H deformation, O-H deformation and C-O stretch in the sample aligned with standard bovine serum albumin. The influence of functional groups within the molecule was because of the impact of preferred spatial orientation, chemical and physical interaction on the molecule. In conclusion, compared to bovine serum albumin, Himantura imbricata consists of two C=O stretch, are involved in the hydrogen bonding that takes place between the different elements of secondary structure. Conclusions: The venom of poisonous animals has been extensively studied, since standard medicine not available for treatment against injuries causing stingray. Therefore, it's the baseline study, to motivate further process and produce effective antibiotics.
A prototype stationary Fourier transform spectrometer for near-infrared absorption spectroscopy.
Li, Jinyang; Lu, Dan-feng; Qi, Zhi-mei
2015-09-01
A prototype stationary Fourier transform spectrometer (FTS) was constructed with a fiber-coupled lithium niobate (LiNbO3) waveguide Mach-Zehnder interferometer (MZI) for the purpose of rapid on-site spectroscopy of biological and chemical measurands. The MZI contains push-pull electrodes for electro-optic modulation, and its interferogram as a plot of intensity against voltage was obtained by scanning the modulating voltage from -60 to +60 V in 50 ms. The power spectrum of input signal was retrieved by Fourier transform processing of the interferogram combined with the wavelength dispersion of half-wave voltage determined for the MZI used. The prototype FTS operates in the single-mode wavelength range from 1200 to 1700 nm and allows for reproducible spectroscopy. A linear concentration dependence of the absorbance at λmax = 1451 nm for water in ethanolic solution was obtained using the prototype FTS. The near-infrared spectroscopy of solid samples was also implemented, and the different spectra obtained with different materials evidenced the chemical recognition capability of the prototype FTS. To make this prototype FTS practically applicable, work on improving its spectral resolution by increasing the maximum optical path length difference is in progress.
Li, Mengyuan; Zhang, Yi; Chen, Chang; Peng, Zhangming; Su, Shaohui
2018-01-01
Incorporating linear-scanning micro-electro-mechanical systems (MEMS) micromirrors into Fourier transform spectral acquisition systems can greatly reduce the size of the spectrometer equipment, making portable Fourier transform spectrometers (FTS) possible. How to minimize the tilting of the MEMS mirror plate during its large linear scan is a major problem in this application. In this work, an FTS system has been constructed based on a biaxial MEMS micromirror with a large-piston displacement of 180 μm, and a biaxial H∞ robust controller is designed. Compared with open-loop control and proportional-integral-derivative (PID) closed-loop control, H∞ robust control has good stability and robustness. The experimental results show that the stable scanning displacement reaches 110.9 μm under the H∞ robust control, and the tilting angle of the MEMS mirror plate in that full scanning range falls within ±0.0014°. Without control, the FTS system cannot generate meaningful spectra. In contrast, the FTS yields a clean spectrum with a full width at half maximum (FWHM) spectral linewidth of 96 cm−1 under the H∞ robust control. Moreover, the FTS system can maintain good stability and robustness under various driving conditions. PMID:29419765
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Huipeng Chen
2018-02-01
Full Text Available Incorporating linear-scanning micro-electro-mechanical systems (MEMS micromirrors into Fourier transform spectral acquisition systems can greatly reduce the size of the spectrometer equipment, making portable Fourier transform spectrometers (FTS possible. How to minimize the tilting of the MEMS mirror plate during its large linear scan is a major problem in this application. In this work, an FTS system has been constructed based on a biaxial MEMS micromirror with a large-piston displacement of 180 μm, and a biaxial H∞ robust controller is designed. Compared with open-loop control and proportional-integral-derivative (PID closed-loop control, H∞ robust control has good stability and robustness. The experimental results show that the stable scanning displacement reaches 110.9 μm under the H∞ robust control, and the tilting angle of the MEMS mirror plate in that full scanning range falls within ±0.0014°. Without control, the FTS system cannot generate meaningful spectra. In contrast, the FTS yields a clean spectrum with a full width at half maximum (FWHM spectral linewidth of 96 cm−1 under the H∞ robust control. Moreover, the FTS system can maintain good stability and robustness under various driving conditions.
[Application of Fourier transform infrared spectroscopy in identification of wine spoilage].
Zhao, Xian-De; Dong, Da-Ming; Zheng, Wen-Gang; Jiao, Lei-Zi; Lang, Yun
2014-10-01
In the present work, fresh and spoiled wine samples from three wines produced by different companies were studied u- sing Fourier transform infrared (FTIR) spectroscopy. We analyzed the physicochemical property change in the process of spoil- age, and then, gave out the attribution of some main FTIR absorption peaks. A novel determination method was explored based on the comparisons of some absorbance ratios at different wavebands although the absorbance ratios in this method were relative. Through the compare of the wine spectra before and after spoiled, the authors found that they were informative at the bands of 3,020~2,790, 1,760~1,620 and 1,550~800 cm(-1). In order to find the relation between these informative spectral bands and the wine deterioration and achieve the discriminant analysis, chemometrics methods were introduced. Principal compounds analysis (PCA) and soft independent modeling of class analogy (SIMCA) were used for classifying different-quality wines. And partial least squares discriminant analysis (PLS-DA) was applied to identify spoiled wines and good wines. Results showed that FTIR technique combined with chemometrics methods could effectively distinguish spoiled wines from fresh samples. The effect of classification at the wave band of 1 550-800 cm(-1) was the best. The recognition rate of SIMCA and PLSDA were respectively 94% and 100%. This study demonstrates that Fourier transform infrared spectroscopy is an effective tool for monitoring red wine's spoilage and provides theoretical support for developing early-warning equipments.
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ATUS BUKU
2017-02-01
Full Text Available The aim of this study is to identify the value of compounds contained in liquid coal by using Fourier Transform Infra-Red (FTIR and Differential Scanning Calorimeter (DSC. FTIR was used to analyse the components contained in liquid coal, while the DSC is done to observe the heat reaction to the environment. Based on the Fourier Transform Infra-Red (FTIR test results it is shown that the compound contained in the liquid Coal consisting of alkanes, alkenes and alkyne. These compounds are similar compounds. The alkanes, alkenes and alkynes compounds undergo complete combustion reaction with oxygen and would produce CO2 and water vapour [H2O (g]. If incomplete combustion occurs, the reaction proceeds in the form of Carbon Monoxide CO gas or solid carbon andH2O. Combustion reaction that occurs in all these three compounds also produces a number of considerable energy. And if it has higher value of Carbon then the boiling point would be higher. From the Differential Scanning Calorimetric (DSC test results obtained some of the factors that affect the reaction speed, which are the temperature, the reaction mixture composition, and pressure. Temperature has a profound influence in coal liquefaction, because if liquid coal heated with high pressure, the carbon chain would break down into smaller chains consisting of aromatic chain, hydro-aromatic, or aliphatic. This then triggers a reaction between oil formation and polymerization reactions to form solids (char.
Eltagoury, Yomna M.; Sabry, Yasser M.; Khalil, Diaa A.
2016-03-01
In this work, we present a novel architecture for Fourier transform spectrometers based on cascaded low-finesse FP interferometers. One of the interferometers has fixed path length while the second is a scanning one using a relatively large stroke electrostatic comb-drive actuator. The fixed interferometer results in a spectrum modulation and, hence, a shifted version of the interferogram away from the point of the zero spacing between the two mirrors. The shifted interferogram can then be used with the Fourier transform algorithm to obtain the spectrum of the measured light. This cascaded FP configuration results in a simple arrangement of mirrors on a line, which makes it much tolerant to misalignment errors. The proposed configuration is implemented using the MEMS DRIE technology on an SOI wafer with a simple MEMS process flow without metallization or dielectric coating of the vertical optical surface. The fabricated compact structure is measured with both a laser source with narrow spectrum at 1550 nm and a wide spectrum source composed of an SLED and the ASE of a semiconductor optical amplifier source. The obtained results validate the concept of the new configuration.
Hébert, Philippe; Pierangelo, Clémence; Rosak, Alain; Cansot, Elodie; Bernard, Frédéric; Camy-Peyret, Claude
2017-11-01
The concept of static Fourier transform interferometry at thermal infrared wavelengths is well suited in the case of narrow spectral bands that are looked at for targeted molecular species as CO and O3 for pollution and air quality monitoring, or H20 and CO2 for weather forecast, down to the troposphere. It permits a high spectral resolution and a very good radiometric performance, with the advantage of a static interferometer, including no moving part. Along with other molecules sounded in the UV-VIS domain, as for instance in the TRAQ mission, SIFTI will provide scientists with a complete set for pollution measurements and air quality survey. Our paper presents the principles of static Fourier transform spectrometry, the work led on the instrument performance model and our study of the SIFTI instrument. We describe the instrument, its main dimensions and characteristics, and its architecture and major subsystems. We eventually make a preliminary survey of the SIFTI performance budget items. As a conclusion, we introduce the future CNES phase A study of this instrument that is started in 2006
Teaching stable two-mirror resonators through the fractional Fourier transform
International Nuclear Information System (INIS)
Moreno, Ignacio; Garcia-Martinez, Pascuala; Ferreira, Carlos
2010-01-01
We analyse two-mirror resonators in terms of their fractional Fourier transform (FRFT) properties. We use the basic ABCD ray transfer matrix method to show how the resonator can be regarded as the cascade of two propagation-lens-propagation FRFT systems. Then, we present a connection between the geometric properties of the resonator (the g parameters) and those of the equivalent FRFT systems (the FRFT order and scaling parameters). Expressions connecting Gaussian beam q-transformation with FRFT parameters are derived. In particular, we show that the beam waist of the resonator's mode is located at the plane leading to two FRFT subsystems with equal scaling parameter which, moreover, coincides with the mode Rayleigh range. Finally we analyse the resonator's stability diagram in terms of the fractional orders of each FRFT subsystem, and the round trip propagation. The presented analysis represents an interesting link between two topics (optical resonators and Fourier optics) usually covered in optics and photonics courses at university level, which can be useful to teach and connect the principles of these subjects.
International Nuclear Information System (INIS)
Vieira, Fabio P.B.; Bevilacqua, Joyce S.
2014-01-01
The use of electron paramagnetic resonance spectrometers - EPR - in radiation dosimetry is known for more than four decades. It is an important tool in the retrospective determination of doses absorbed. To estimate the dose absorbed by the sample, it is necessary to know the amplitude of the peak to peak signature of the substance in its EPR spectrum. This information can be compromised by the presence of spurious information: noise - of random and low intensity nature; and the behavior of the baseline - coming from the coupling between the resonator tube and the sample analyzed. Due to the intrinsic characteristics of the three main components of the signal, i.e. signature, noise, and baseline - the analysis in the frequency domain allows, through post-processing techniques to filter spurious information. In this work, an algorithm that retrieves the signature of a substance has been implemented. The Discrete Fourier Transform is applied to the signal and without user intervention, the noise is filtered. From the filtered signal, recovers the signature by Inverse Discrete Fourier Transform. The peak to peak amplitude, and the absorbed dose is calculated with an error of less than 1% for signals wherein the base line is linearized. Some more general cases are under investigation and with little user intervention, you can get the same error
Gorzsás, András; Sundberg, Björn
2014-01-01
Fourier transform infrared (FT-IR) spectroscopy is a fast, sensitive, inexpensive, and nondestructive technique for chemical profiling of plant materials. In this chapter we discuss the instrumental setup, the basic principles of analysis, and the possibilities for and limitations of obtaining qualitative and semiquantitative information by FT-IR spectroscopy. We provide detailed protocols for four fully customizable techniques: (1) Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS): a sensitive and high-throughput technique for powders; (2) attenuated total reflectance (ATR) spectroscopy: a technique that requires no sample preparation and can be used for solid samples as well as for cell cultures; (3) microspectroscopy using a single element (SE) detector: a technique used for analyzing sections at low spatial resolution; and (4) microspectroscopy using a focal plane array (FPA) detector: a technique for rapid chemical profiling of plant sections at cellular resolution. Sample preparation, measurement, and data analysis steps are listed for each of the techniques to help the user collect the best quality spectra and prepare them for subsequent multivariate analysis.
Paul, Jagannath
Advent of ultrashort lasers made it possible to probe various scattering phenomena in materials that occur in a time scale on the order of few femtoseconds to several tens of picoseconds. Nonlinear optical spectroscopy techniques, such as pump-probe, transient four wave mixing (TFWM), etc., are very common to study the carrier dynamics in various material systems. In time domain, the transient FWM uses several ultrashort pulses separated by time delays to obtain the information of dephasing and population relaxation times, which are very important parameters that govern the carrier dynamics of materials. A recently developed multidimensional nonlinear optical spectroscopy is an enhanced version of TFWM which keeps track of two time delays simultaneously and correlate them in the frequency domain with the aid of Fourier transform in a two dimensional map. Using this technique, the nonlinear complex signal field is characterized both in amplitude and phase. Furthermore, this technique allows us to identify the coupling between resonances which are rather difficult to interpret from time domain measurements. This work focuses on the study of the coherent response of a two dimensional electron gas formed in a modulation doped GaAs/AlGaAs quantum well both at zero and at high magnetic fields. In modulation doped quantum wells, the excitons are formed as a result of the inter- actions of the charged holes with the electrons at the Fermi edge in the conduction band, leading to the formation of Mahan excitons, which is also referred to as Fermi edge singularity (FES). Polarization and temperature dependent rephasing 2DFT spectra in combination with TI-FWM measurements, provides insight into the dephasing mechanism of the heavy hole (HH) Mahan exciton. In addition to that strong quantum coherence between the HH and LH Mahan excitons is observed, which is rather surprising at this high doping concentration. The binding energy of Mahan excitons is expected to be greatly
International Nuclear Information System (INIS)
Dixon, M.; Wright, A.C.; Hutchinson, P.
1977-01-01
The application of fast Fourier transformation techniques to the analysis of experimental X-ray and neutron diffraction patterns from amorphous materials is discussed and compared with conventional techniques using Filon's quadrature. The fast Fourier transform package described also includes cubic spline smoothing and has been extensively tested, using model data to which statistical errors have been added by means of a pseudo-random number generator with Gaussian shaper. Neither cubic spline nor hand smoothing has much effect on the resulting transform since the noise removed is of too high a frequency. (Auth.)
Classification of footwear outsole patterns using Fourier transform and local interest points.
Richetelli, Nicole; Lee, Mackenzie C; Lasky, Carleen A; Gump, Madison E; Speir, Jacqueline A
2017-06-01
Successful classification of questioned footwear has tremendous evidentiary value; the result can minimize the potential suspect pool and link a suspect to a victim, a crime scene, or even multiple crime scenes to each other. With this in mind, several different automated and semi-automated classification models have been applied to the forensic footwear recognition problem, with superior performance commonly associated with two different approaches: correlation of image power (magnitude) or phase, and the use of local interest points transformed using the Scale Invariant Feature Transform (SIFT) and compared using Random Sample Consensus (RANSAC). Despite the distinction associated with each of these methods, all three have not been cross-compared using a single dataset, of limited quality (i.e., characteristic of crime scene-like imagery), and created using a wide combination of image inputs. To address this question, the research presented here examines the classification performance of the Fourier-Mellin transform (FMT), phase-only correlation (POC), and local interest points (transformed using SIFT and compared using RANSAC), as a function of inputs that include mixed media (blood and dust), transfer mechanisms (gel lifters), enhancement techniques (digital and chemical) and variations in print substrate (ceramic tiles, vinyl tiles and paper). Results indicate that POC outperforms both FMT and SIFT+RANSAC, regardless of image input (type, quality and totality), and that the difference in stochastic dominance detected for POC is significant across all image comparison scenarios evaluated in this study. Copyright © 2017 Elsevier B.V. All rights reserved.
Bohlin, Alexis; Patterson, Brian D.; Kliewer, Christopher J.
2017-11-01
In many fields of study, from coherent Raman microscopy on living cells to time-resolved coherent Raman spectroscopy of gas-phase turbulence and combustion reaction dynamics, the need for the capability to time-resolve fast dynamical and nonrepetitive processes has led to the continued development of high-speed coherent Raman methods and new high-repetition rate laser sources, such as pulse-burst laser systems. However, much less emphasis has been placed on our ability to detect shot to shot coherent Raman spectra at equivalently high scan rates, across the kilohertz to megahertz regime. This is beyond the capability of modern scientific charge coupled device (CCD) cameras, for instance, as would be employed with a Czerny-Turner type spectrograph. As an alternative detection strategy with megahertz spectral detection rate, we demonstrate dispersive Fourier transformation detection of pulsed (∼90 ps) coherent Raman signals in the time-domain. Instead of reading the frequency domain signal out using a spectrometer and CCD, the signal is transformed into a time-domain waveform through dispersive Fourier transformation in a long single-mode fiber and read-out with a fast sampling photodiode and oscilloscope. Molecular O- and S-branch rotational sideband spectra from both N2 and H2 were acquired employing this scheme, and the waveform is fitted to show highly quantitative agreement with a molecular model. The total detection time for the rotational spectrum was 20 ns, indicating an upper limit to the detection frequency of ∼50 MHz, significantly faster than any other reported spectrally-resolved coherent anti-Stokes Raman detection strategy to date.
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Pudji Astuti
2014-05-01
Full Text Available Stress in animal is a condition of nonspesific discomfort which cause of non-specific immune defects,failure of reproduction, and decreased of meat carcass until the death of animals. To determine stress ofcattle, it will be invented stress detector using a non-invasive method based on the spectroscopy FourierTransform Infrared (FTIR. Basically, FTIR will detect component in compound of cathecolamine andcortisol as ketone (= O and methyl (= CH 3. Furthermore, each group of components will be detected indifferent of absorbant and wavelength. The results showed that average level of cortisol in female beefcattle durimg resting eriod was 38,48±21,53 ng/dL, on time of slaughtering were 116,88±112,59 ng/dL. Forbull, which were resting 20,42±9,25 ng/dL; when animal was slaughtered level of cortisol was 67,61±41,62ng/dL. Using FTIR, it was showed that compound of metil was absorbed well. Animals with udder stresscondition have been recorded on the wave lenght of 2777-3456 nm. It has been concluded level of cortisolon cattle which were resting is significantly different from animal which were slaughtering P(< 0.05,where cortisol would increase drastically. Using Calibration of FTIR indicated resting animals only havefewer value of absorbance than animals which slaughtered. FTIR is a very prospect method for makingstress indicator.
Zhang, Mingjing; Wen, Ming; Zhang, Zhi-Min; Lu, Hongmei; Liang, Yizeng; Zhan, Dejian
2015-03-01
Retention time shift is one of the most challenging problems during the preprocessing of massive chromatographic datasets. Here, an improved version of the moving window fast Fourier transform cross-correlation algorithm is presented to perform nonlinear and robust alignment of chromatograms by analyzing the shifts matrix generated by moving window procedure. The shifts matrix in retention time can be estimated by fast Fourier transform cross-correlation with a moving window procedure. The refined shift of each scan point can be obtained by calculating the mode of corresponding column of the shifts matrix. This version is simple, but more effective and robust than the previously published moving window fast Fourier transform cross-correlation method. It can handle nonlinear retention time shift robustly if proper window size has been selected. The window size is the only one parameter needed to adjust and optimize. The properties of the proposed method are investigated by comparison with the previous moving window fast Fourier transform cross-correlation and recursive alignment by fast Fourier transform using chromatographic datasets. The pattern recognition results of a gas chromatography mass spectrometry dataset of metabolic syndrome can be improved significantly after preprocessing by this method. Furthermore, the proposed method is available as an open source package at https://github.com/zmzhang/MWFFT2. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
International Nuclear Information System (INIS)
Schaffer, J.P.; Shaughnessy, E.J.; Jones, P.L.
1984-01-01
A deconvolution procedure which corrects Doppler-broadened positron annihilation spectra for instrument resolution is described. The method employs fast Fourier transforms, is model independent, and does not require iteration. The mathematical difficulties associated with the incorrectly posed first order Fredholm integral equation are overcome by using power spectral analysis to select a limited number of low frequency Fourier coefficients. The FFT/power spectrum method is then demonstrated for an irradiated high purity single crystal sapphire sample. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Bobbitt, Jonathan M [Ames Laboratory; Weibel, Stephen C [GWC Technologies Inc; Elshobaki, Moneim [Iowa State University; Chaudhary, Sumit [Iowa State University; Smith, Emily A [Ames Laboratory
2014-12-16
Fourier transform (FT)-plasmon waveguide resonance (PWR) spectroscopy measures light reflectivity at a waveguide interface as the incident frequency and angle are scanned. Under conditions of total internal reflection, the reflected light intensity is attenuated when the incident frequency and angle satisfy conditions for exciting surface plasmon modes in the metal as well as guided modes within the waveguide. Expanding upon the concept of two-frequency surface plasmon resonance developed by Peterlinz and Georgiadis [ Opt. Commun. 1996, 130, 260], the apparent index of refraction and the thickness of a waveguide can be measured precisely and simultaneously by FT-PWR with an average percent relative error of 0.4%. Measuring reflectivity for a range of frequencies extends the analysis to a wide variety of sample compositions and thicknesses since frequencies with the maximum attenuation can be selected to optimize the analysis. Additionally, the ability to measure reflectivity curves with both p- and s-polarized light provides anisotropic indices of refraction. FT-PWR is demonstrated using polystyrene waveguides of varying thickness, and the validity of FT-PWR measurements are verified by comparing the results to data from profilometry and atomic force microscopy (AFM).
Polynomial Phase Estimation Based on Adaptive Short-Time Fourier Transform.
Jing, Fulong; Zhang, Chunjie; Si, Weijian; Wang, Yu; Jiao, Shuhong
2018-02-13
Polynomial phase signals (PPSs) have numerous applications in many fields including radar, sonar, geophysics, and radio communication systems. Therefore, estimation of PPS coefficients is very important. In this paper, a novel approach for PPS parameters estimation based on adaptive short-time Fourier transform (ASTFT), called the PPS-ASTFT estimator, is proposed. Using the PPS-ASTFT estimator, both one-dimensional and multi-dimensional searches and error propagation problems, which widely exist in PPSs field, are avoided. In the proposed algorithm, the instantaneous frequency (IF) is estimated by S-transform (ST), which can preserve information on signal phase and provide a variable resolution similar to the wavelet transform (WT). The width of the ASTFT analysis window is equal to the local stationary length, which is measured by the instantaneous frequency gradient (IFG). The IFG is calculated by the principal component analysis (PCA), which is robust to the noise. Moreover, to improve estimation accuracy, a refinement strategy is presented to estimate signal parameters. Since the PPS-ASTFT avoids parameter search, the proposed algorithm can be computed in a reasonable amount of time. The estimation performance, computational cost, and implementation of the PPS-ASTFT are also analyzed. The conducted numerical simulations support our theoretical results and demonstrate an excellent statistical performance of the proposed algorithm.
International Nuclear Information System (INIS)
Bangalore, Arjun S.; Demirgian, Jack C.; Boparai, Amrit S.; Small, Gary W.
1999-01-01
The Fourier transform infrared (FT-IR) spectral data of two nerve agent simulants, diisopropyl methyl phosphonate (DIMP) and dimethyl methyl phosphonate (DMMP), are used as test cases to determine the spectral resolution that gives optimal pattern recognition performance. DIMP is used as the target analyte for detection, while DMMP is used to test the ability of the automated pattern recognition methodology to detect the analyte selectively. Interferogram data are collected by using a Midac passive FT-IR instrument. The methodology is based on the application of pattern recognition techniques to short segments of single-beam spectra obtained by Fourier processing the collected interferogram data. The work described in this article evaluates the effect of varying spectral resolution on the pattern recognition results. The objective is to determine the optimal spectral resolution to be used for data collection. The results of this study indicate that the data with a nominal spectral resolution of 16 cm -1 provide sufficient selectivity to give pattern recognition results comparable to that obtained by using higher resolution data. We found that, while higher resolution does not increase selectivity sufficiently to provide better pattern recognition results, lower resolution decreases selectivity and degrades the pattern recognition results. These results can be used as guidelines to maximize detection sensitivity, to minimize the time needed for data collection, and to reduce data storage requirements. (c) 2000 Society for Applied Spectroscopy
Fourier transform IR studies on the interaction of selected chemicals with isolated cuticles
International Nuclear Information System (INIS)
Luque, P.; Ramirez, F.J.; Heredia, A.; Bukovac, M.J.
1994-01-01
It is known that the plant cuticle represents the first barrier that must be overcome by any chemical reaching the plant surface from the atmosphere before entering the plant. Because of the importance of the cuticle as a barrier to penetration of a wide variety of compounds, its morphology, chemistry, and permeability have been extensively studied. However, only limited information is available on the nature of functional chemical groups present and their interaction and role during the penetration process. The usefulness of in situ Fourier transform infrared spectroscopy studies in identifying functional groups present in isolated cuticles is described and their relationships to the structure of the cuticular membrane are discussed. Applications of infrared spectroscopy on the presence and role of phenolics in the cuticle structure and during the cuticle development, nitrogen oxide binding to isolated cuticles, and the interactions between selected chemical probes during sorption by the cuticle are also described. (orig.)
Blind detection of isolated astrophysical pulses in the spatial Fourier transform domain
Schmid, Natalia A.; Prestage, Richard M.
2018-04-01
We present a novel approach for the detection of isolated transients in pulsar surveys and fast radio transient observations. Rather than the conventional approach of performing a computationally expensive blind DM search, we take the spatial Fourier transform (SFT) of short (˜ few seconds) sections of data. A transient will have a characteristic signature in the SFT domain, and we present a blind statistic which may be used to detect this signature at an empirical zero False Alarm Rate (FAR). The method has been evaluated using simulations, and also applied to two fast radio burst observations. In addition to its use for current observations, we expect this method will be extremely beneficial for future multi-beam observations made by telescopes equipped with phased array feeds.
Lagubeau, Guillaume; Cobelli, Pablo; Bobinski, Tomasz; Maurel, Agnes; Pagneux, Vincent; Petitjeans, Philippe
2015-11-01
Fringe projection profilometry is an instrument of choice for the instantaneous measurement of the full height map of a free-surface. It is useful to capture interfacial phenomena such as droplet impact and propagation of water waves. We present the Empirical Mode Decomposition Profilometry (EMDP) for the analysis of fringe projection profilometry images. It is based on an iterative filter, using empirical mode decomposition, that is free of spatial filtering and adapted for surfaces characterized by a broadband spectrum of deformation. Examples of such surfaces can be found in nonlinear wave interaction regimes such as wave turbulence in gravity-capillary water waves. We show both numerically and experimentally that using EMDP improves strongly the profilometry small scale capabilities compared to traditionally used Fourier Transform Profilometry. Moreover, the height reconstruction distortion is much lower: the reconstructed height field is now both spectrally and statistically accurate.
DEFF Research Database (Denmark)
Bruun, Susanne Wrang; Kohler, Achim; Adt, Isabelle
2006-01-01
Fourier transform infrared (FT-IR) spectroscopy is a valuable technique for characterization of biological samples, providing a detailed fingerprint of the major chemical constituents. However, water vapor and CO(2) in the beam path often cause interferences in the spectra, which can hamper...... the data analysis and interpretation of results. In this paper we present a new method for removal of the spectral contributions due to atmospheric water and CO(2) from attenuated total reflection (ATR)-FT-IR spectra. In the IR spectrum, four separate wavenumber regions were defined, each containing...... of the growing yeast biofilm, the gas correction revealed otherwise hidden variations of relevance for modeling the growth dynamics. As the presented method improved the interpretation of the principle component analysis (PCA) models, it has proven to be a valuable tool for filtering atmospheric variation in ATR...
Relative-coordinate determination for visual double stars by applying Fourier transforms
Directory of Open Access Journals (Sweden)
Radović Viktor
2013-01-01
Full Text Available We discuss the software developed for the purpose of determining the relative coordinates (position angle θ and separation ρ for visual double or multiple stars. It is based on application of Fourier transforms in treating CCD frames of these systems. The objective was to determine the relative coordinates automatically to an extent as large as possible. In this way the time needed for the reduction of many CCD frames becomes shorter. The capabilities and limitations of the software are examined. Besides, the possibility of improving is also considered. The software has been tested and checked on a sample consisting of CCD frames of 165 double or multiple stars obtained with the 2m telescope at NAO Rozhen in Bulgaria in October 2011. The results have been compared with the corresponding results obtained by applying different software and the agreement is found to be very good.
Detection of Left-Sided and Right-Sided Hearing Loss via Fractional Fourier Transform
Directory of Open Access Journals (Sweden)
Shuihua Wang
2016-05-01
Full Text Available In order to detect hearing loss more efficiently and accurately, this study proposed a new method based on fractional Fourier transform (FRFT. Three-dimensional volumetric magnetic resonance images were obtained from 15 patients with left-sided hearing loss (LHL, 20 healthy controls (HC, and 14 patients with right-sided hearing loss (RHL. Twenty-five FRFT spectrums were reduced by principal component analysis with thresholds of 90%, 95%, and 98%, respectively. The classifier is the single-hidden-layer feed-forward neural network (SFN trained by the Levenberg–Marquardt algorithm. The results showed that the accuracies of all three classes are higher than 95%. In all, our method is promising and may raise interest from other researchers.
Castilho, Maiara L.; Campos, Claudia B. L.; Matos, Tatiana G. F.; de Abreu, Geraldo M. A.; Martin, Airton A.; Raniero, Leandro
2012-01-01
Paracoccidioides brasiliensis the etiological agent of paracoccidioidomycosis, is a dimorphic fungus existing as mycelia in the environment (or at 25 °C in vitro) and as yeast cells in the human host (or at 37°C in vitro). The most prominent difference between both forms is probably the cell wall polysaccharide, being 1,3-β-glucan usually found in mycelia and 1,3-α-glucan found in yeasts, but a plethora of other differences have already been described. In this work, we performed a Fourier Transform Infrared Spectroscopy analysis to compare the yeast and mycelia forms of P. brasiliensis and found additional biochemical differences. The analysis of the spectra showed that differences were distributed in chemical bonds of proteins, lipids and carbohydrates.
Label-free identification of individual bacteria using Fourier transform light scattering.
Jo, YoungJu; Jung, JaeHwang; Kim, Min-Hyeok; Park, HyunJoo; Kang, Suk-Jo; Park, YongKeun
2015-06-15
Rapid identification of bacterial species is crucial in medicine and food hygiene. In order to achieve rapid and label-free identification of bacterial species at the single bacterium level, we propose and experimentally demonstrate an optical method based on Fourier transform light scattering (FTLS) measurements and statistical classification. For individual rod-shaped bacteria belonging to four bacterial species (Listeria monocytogenes, Escherichia coli, Lactobacillus casei, and Bacillus subtilis), two-dimensional angle-resolved light scattering maps are precisely measured using FTLS technique. The scattering maps are then systematically analyzed, employing statistical classification in order to extract the unique fingerprint patterns for each species, so that a new unidentified bacterium can be identified by a single light scattering measurement. The single-bacterial and label-free nature of our method suggests wide applicability for rapid point-of-care bacterial diagnosis.
Nam, Yun Sik; Park, Jin Sook; Kim, Nak-Kyoon; Lee, Yeonhee; Lee, Kang-Bong
2014-07-01
Seals are traditionally used in the Far East Asia to stamp an impression on a document in place of a signature. In this study, an accuser claimed that a personal contract regarding mining development rights acquired by a defendant was devolved to the accuser because the defendant stamped the devolvement contract in the presence of the accuser and a witness. The accuser further stated that the seal ink stamped on the devolvement contract was the same as that stamped on the development rights application document. To verify this, the seals used in two documents were analyzed using micro-attenuated total reflectance Fourier transform infrared spectroscopy and infrared spectra. The findings revealed that the seals originated from different manufacturers. Thus, the accuser's claim on the existence of a devolvement contract was proved to be false. © 2014 American Academy of Forensic Sciences.
International Nuclear Information System (INIS)
Leone, S.R.
1990-01-01
Recent progress is described resulting from the past three years of DOE support for studies of combustion-related photofragmentation dynamics, energy transfer, and reaction processes using a time-resolved Fourier transform infrared (FTIR) emission technique. The FTIR is coupled to a high repetition rate excimer laser which produces radicals by photolysis to obtain novel, high resolution measurements on vibrational and rotational state dynamics. The results are important for the study of numerous radical species relevant to combustion processes. The method has been applied to the detailed study of photofragmentation dynamics in systems such as acetylene, which produces C 2 H; chlorofluoroethylene to study the HF product channel; vinyl chloride and dichloroethylene, which produce HCl; acetone, which produces CO and CH 3 ; and ammonia, which produces NH 2 . In addition, we have recently demonstrated use of the FTIR technique for preliminary studies of energy transfer events under near single collision conditions, radical-radical reactions, and laser-initiated chain reaction processes
Discrete Fourier transformation processor based on complex radix (−1 + j number system
Directory of Open Access Journals (Sweden)
Anidaphi Shadap
2017-02-01
Full Text Available Complex radix (−1 + j allows the arithmetic operations of complex numbers to be done without treating the divide and conquer rules, which offers the significant speed improvement of complex numbers computation circuitry. Design and hardware implementation of complex radix (−1 + j converter has been introduced in this paper. Extensive simulation results have been incorporated and an application of this converter towards the implementation of discrete Fourier transformation (DFT processor has been presented. The functionality of the DFT processor have been verified in Xilinx ISE design suite version 14.7 and performance parameters like propagation delay and dynamic switching power consumption have been calculated by Virtuoso platform in Cadence. The proposed DFT processor has been implemented through conversion, multiplication and addition. The performance parameter matrix in terms of delay and power consumption offered a significant improvement over other traditional implementation of DFT processor.
Laser Mode Behavior of the Cassini CIRS Fourier Transform Spectrometer at Saturn
Brasunas, John C.
2012-01-01
The CIRS Fourier transform spectrometer aboard the NASA/ESA/ASI Cassini orbiter has been acquiring spectra of the Saturnian system since 2004. The CIRS reference interferometer employs a laser diode to trigger the interferogram sampling. Although the control of laser diode drive current and operating temperature are stringent enough to restrict laser wavelength variation to a small fraction of CIRS finest resolution element, the CIRS instrument does need to be restarted every year or two, at which time it may start in a new laser mode. By monitoring the Mylar absorption features in uncalibrated spectra due to the beam splitter Mylar substrate, it can be shown that these jumps are to adjacent modes and that most of the eight-year operation so far is restricted to three adjacent modes. For a given mode, the wavelength stability appears consistent with the stability of the laser diode drive curren.t and operating temperature.
X-ray Fourier transform holography by amplitude-division-type Fresnel zone plate interferometer.
Balyan, Minas; Haroutunyan, Levon
2018-01-01
A two-block X-ray Fresnel zone plate system forms two-beams - a plane wave and a spherical wave - which interfere at the focal distance of the virtual source of the spherical wave. An object placed in the path of the plane wave forms an object wave and the spherical wave is the reference wave. The recorded intensity distribution is the Fourier transform hologram of the object. Analytical and numerical calculations show the possibilities of this scheme to record the hologram and reconstruct the object image. Examples of recording holograms of a one-dimensional cosine-like grating and a two-dimensional grid object as well as reconstruction of the images are considered.
Suppressing carrier removal error in the Fourier transform method for interferogram analysis
International Nuclear Information System (INIS)
Fan, Qi; Yang, Hongru; Li, Gaoping; Zhao, Jianlin
2010-01-01
A new carrier removal method for interferogram analysis using the Fourier transform is presented. The proposed method can be used to suppress the carrier removal error as well as the spectral leakage error. First, the carrier frequencies are estimated with the spectral centroid of the up sidelobe of the apodized interferogram, and then the up sidelobe can be shifted to the origin in the frequency domain by multiplying the original interferogram by a constructed plane reference wave. The influence of the carrier frequencies without an integer multiple of the frequency interval and the window function for apodization of the interferogram can be avoided in our work. The simulation and experimental results show that this method is effective for phase measurement with a high accuracy from a single interferogram
International Nuclear Information System (INIS)
Ibrahim, Amr; PredoiCross, Adriana; Teillet, P. M.
2010-01-01
Seven different techniques in dealing the problem of channel spectra in Fourier transform Spectroscopy utilizing synchrotron source were examined and compared. Five of these techniques deal with the artifacts (spikes) in the recorded interferogram which in turn result in channel spectra within the spectral domain. Such interferogram editing method include replacing these spikes with zeros, straight line, fitted polynomial curve, rescaled spike and spike reduced with Gauss Function. Another two techniques try to target this issue in the spectral domain instead by either generating a synthetic background simulating the channels or measuring the channels parameters (amplitude, spacing and phase) to use in the spectral fitting program. Results showed spectral domain techniques produces higher quality results in terms of signal to noise and fitting residual. The effect of each method on the line parameters such as position, intensity are air broadening are also measured and discussed.
Imaging open-path Fourier transform infrared spectrometer for 3D cloud profiling
Rentz Dupuis, Julia; Mansur, David J.; Vaillancourt, Robert; Carlson, David; Evans, Thomas; Schundler, Elizabeth; Todd, Lori; Mottus, Kathleen
2010-04-01
OPTRA has developed an imaging open-path Fourier transform infrared (I-OP-FTIR) spectrometer for 3D profiling of chemical and biological agent simulant plumes released into test ranges and chambers. An array of I-OP-FTIR instruments positioned around the perimeter of the test site, in concert with advanced spectroscopic algorithms, enables real time tomographic reconstruction of the plume. The approach is intended as a referee measurement for test ranges and chambers. This Small Business Technology Transfer (STTR) effort combines the instrumentation and spectroscopic capabilities of OPTRA, Inc. with the computed tomographic expertise of the University of North Carolina, Chapel Hill. In this paper, we summarize the design and build and detail system characterization and test of a prototype I-OP-FTIR instrument. System characterization includes radiometric performance and spectral resolution. Results from a series of tomographic reconstructions of sulfur hexafluoride plumes in a laboratory setting are also presented.
Photoacoustic detection of blood in dental pulp by using short-time Fourier transform
Yamada, Azusa; Kakino, Satoko; Matsuura, Yuji
2016-03-01
A method based on photoacoustic analysis is proposed to diagnose dental pulp vitality. Photoacoustic analysis enables to get signal from deeper tissues than other optical analyses and therefore, signal detection from root canal of thick dental tissues such as molar teeth is expected. As a light source for excitation of photoacoustic waves, a microchip Q-switched YAG laser with a wavelength of 1064 nm was used and owing to large penetration depth of the near infrared laser, photoacoustic signals from dental root were successfully obtained. It was found that the photoacoustic signals from the teeth containing hemoglobin solution in the pulp cavity provide vibration in high frequency region. It was also shown that the intensities of the high frequency component have correlation with the hemoglobin concentration of solution. We applied short-time Fourier transform for evaluation of photoacoustic signals and this analysis clearly showed photoacoustic signals from dental root.
Li, Chao; Yang, Sheng-Chao; Guo, Qiao-Sheng; Zheng, Kai-Yan; Wang, Ping-Li; Meng, Zhen-Gui
2016-01-05
A combination of Fourier transform infrared spectroscopy with chemometrics tools provided an approach for studying Marsdenia tenacissima according to its geographical origin. A total of 128 M. tenacissima samples from four provinces in China were analyzed with FTIR spectroscopy. Six pattern recognition methods were used to construct the discrimination models: support vector machine-genetic algorithms, support vector machine-particle swarm optimization, K-nearest neighbors, radial basis function neural network, random forest and support vector machine-grid search. Experimental results showed that K-nearest neighbors was superior to other mathematical algorithms after data were preprocessed with wavelet de-noising, with a discrimination rate of 100% in both the training and prediction sets. This study demonstrated that FTIR spectroscopy coupled with K-nearest neighbors could be successfully applied to determine the geographical origins of M. tenacissima samples, thereby providing reliable authentication in a rapid, cheap and noninvasive way. Copyright © 2015 Elsevier B.V. All rights reserved.
Directory of Open Access Journals (Sweden)
Jinsoo Park
2014-01-01
Full Text Available A new voice activity detector for noisy environments is proposed. In conventional algorithms, the endpoint of speech is found by applying an edge detection filter that finds the abrupt changing point in a feature domain. However, since the frame energy feature is unstable in noisy environments, it is difficult to accurately find the endpoint of speech. Therefore, a novel feature extraction algorithm based on the double-combined Fourier transform and envelope line fitting is proposed. It is combined with an edge detection filter for effective detection of endpoints. Effectiveness of the proposed algorithm is evaluated and compared to other VAD algorithms using two different databases, which are AURORA 2.0 database and SITEC database. Experimental results show that the proposed algorithm performs well under a variety of noisy conditions.
Park, Jinsoo; Kim, Wooil; Han, David K; Ko, Hanseok
2014-01-01
A new voice activity detector for noisy environments is proposed. In conventional algorithms, the endpoint of speech is found by applying an edge detection filter that finds the abrupt changing point in a feature domain. However, since the frame energy feature is unstable in noisy environments, it is difficult to accurately find the endpoint of speech. Therefore, a novel feature extraction algorithm based on the double-combined Fourier transform and envelope line fitting is proposed. It is combined with an edge detection filter for effective detection of endpoints. Effectiveness of the proposed algorithm is evaluated and compared to other VAD algorithms using two different databases, which are AURORA 2.0 database and SITEC database. Experimental results show that the proposed algorithm performs well under a variety of noisy conditions.
Supercontinuum Fourier transform spectrometry with balanced detection on a single photodiode
International Nuclear Information System (INIS)
Goncharov, Vasily V.; Hall, Gregory E.
2016-01-01
We demonstrate a method of combining a supercontinuum light source with a commercial Fourier transform spectrometer, using a novel approach to dual-beam balanced detection, implemented with phase-sensitive detection on a single light detector. A 40 dB reduction in the relative intensity noise is achieved for broadband light, analogous to conventional balanced detection methods using two matched photodetectors. Unlike conventional balanced detection, however, this method exploits the time structure of the broadband source to interleave signal and reference pulse trains in the time domain, recording the broadband differential signal at the fundamental pulse repetition frequency of the supercontinuum. The method is capable of real-time correction for instability in the supercontinuum spectral structure over a broad range of wavelengths and is compatible with commercially designed spectrometers. A proof-of-principle experimental setup is demonstrated for weak absorption in the 1500-1600 nm region.
Meso-optical Fourier transform microscope - a new device for high energy physics
International Nuclear Information System (INIS)
Astakhov, A.Ya.; Batusov, Yu.A.; Bencze, G.L.; Farago, I.; Kisvaradi, A.; Molnar, L.; Soroko, L.M.; Vegh, J.
1989-01-01
A new device for high energy physics, the Meso-optical Fourier Transform Microscope (MFTM), designed for observation fo straight line particle tracks in nuclear research emulsion is described. The MFTM works without any mechanical or electronical depth scanning and can be considered as a selectivity viewing 'eye'. The computer controlled system containing MFTM as its main unit is given. This system can be used for a fast search for particle tracks and events produced by high energy neutrinos from particle accelerators. The results of the first experimental test of the computer controlled MFTM are presented. The performance of this system is described and discussed. It is shown that the angular resolution of the MFTM is 1 angular minute and the measurement time is equal to 30 ms per image. As all operations in the MFTM proceed without any depth scanning, this new evaluation system works at least two orders of magnitude faster than any known system with a traditional optical microscope. (orig.)
Directory of Open Access Journals (Sweden)
Kevin D. Quinn
2012-01-01
Full Text Available Paper Spray Ionization is an atmospheric pressure ionization technique that utilizes an offline electro-osmotic flow to generate ions off a paper medium. This technique can be performed on a Bruker SolariX Fourier transform ion cyclotron resonance mass spectrometer by modifying the existing nanospray source. High-resolution paper spray spectra were obtained for both organic and biological samples to demonstrate the benefit of linking the technique with a high-resolution mass analyzer. Error values in the range 0.23 to 2.14 ppm were obtained for calf lung surfactant extract with broadband mass resolving power (m/Δm50% above 60,000 utilizing an external calibration standard.
Lin, Mengshi; Al-Holy, Murad; Al-Qadiri, Hamzah; Kang, Dong-Hyun; Cavinato, Anna G; Huang, Yiqun; Rasco, Barbara A
2004-09-22
Fourier transform infrared spectroscopy (FT-IR, 4000-600 cm(-)(1)) was used to discriminate between intact and sonication-injured Listeria monocytogenes ATCC 19114 and to distinguish this strain from other selected Listeria strains (L. innocua ATCC 51742, L. innocua ATCC 33090, and L. monocytogenes ATCC 7644). FT-IR vibrational overtone and combination bands from mid-IR active components of intact and injured bacterial cells produced distinctive "fingerprints" at wavenumbers between 1500 and 800 cm(-)(1). Spectral data were analyzed by principal component analysis. Clear segregations of different intact and injured strains of Listeria were observed, suggesting that FT-IR can detect biochemical differences between intact and injured bacterial cells. This technique may provide a tool for the rapid assessment of cell viability and thereby the control of foodborne pathogens.
Matching-pursuit/split-operator Fourier-transform simulations of nonadiabatic quantum dynamics
Wu, Yinghua; Herman, Michael F.; Batista, Victor S.
2005-03-01
A rigorous and practical approach for simulations of nonadiabatic quantum dynamics is introduced. The algorithm involves a natural extension of the matching-pursuit/split-operator Fourier-transform (MP/SOFT) method [Y. Wu and V. S. Batista, J. Chem. Phys. 121, 1676 (2004)] recently developed for simulations of adiabatic quantum dynamics in multidimensional systems. The MP/SOFT propagation scheme, extended to nonadiabatic dynamics, recursively applies the time-evolution operator as defined by the standard perturbation expansion to first-, or second-order, accuracy. The expansion is implemented in dynamically adaptive coherent-state representations, generated by an approach that combines the matching-pursuit algorithm with a gradient-based optimization method. The accuracy and efficiency of the resulting propagation method are demonstrated as applied to the canonical model systems introduced by Tully for testing simulations of dual curve-crossing nonadiabatic dynamics.
Multi-correlation Fourier transform spectroscopy with the resolved modes of a frequency comb laser
Energy Technology Data Exchange (ETDEWEB)
Zeitouny, Mounir; Horsten, Ronald C.; Urbach, H. Paul; Bhattacharya, Nandini [Technische Universiteit Delft (Netherlands); Balling, Petr; Kren, Petr; Masika, Pavel [Czech Metrology Institute, Laboratories of Fundamental Metrology, Prague (Czech Republic); Persijn, Stefan T. [VSL, Delft (Netherlands)
2013-06-15
An instrument achieving 100 KHz spectral precision using multiple correlation Fourier transform spectroscopy has been demonstrated. The instrument can measure the individual frequency comb modes of 100 MHz frequency comb lasers in air. The experiments show {proportional_to}400,000 resolved modes at linewidths of 85 MHz in the region of 829 nm and {proportional_to} 182,000 resolved modes at linewidths of 28 MHz in the region of 1.5 {mu}m, with a recording time of few minutes. The precision of the instrument, defined by the frequency positioning, attains sub-MHz even when the scan is performed in air. (copyright 2013 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Quatrevalet, Mathieu; Aminou, Donny; Bézy, Jean-Loup
2017-11-01
Sounding measurements with high spatial resolution (better than 10 km horizontal and 1 km vertical) and repeat cycles better than an hour over the full Earth disk will enhance the ability of National Meteorological Services to initialise models of observations of temperature, moisture and winds. To meet those needs, trade-off's were performed during the Meteosat Third Generation (MTG) mission study (2003-2005) where preliminary instrument concepts for the Infra-Red Sounding (IRS) mission were investigated allowing at the same time to consolidate the technical requirements for the overall system study. The trade-off's demonstrated that two types of instrument could fulfill the requirements: a Fourier Transform Spectrometer and a Dispersive Spectrometer. This paper aims at comparing these two MTG-IRS sensor concepts by highlighting the differences in the constraints imposed on the characteristics and required performance at hardware level. In addition, technology criticalities and some other aspects are discussed qualitatively.
Horikiri, Fumimasa; Narita, Yoshinobu; Yoshida, Takehiro
2017-12-01
In vertical devices containing GaN homoepitaxial layers on GaN substrates, the layer thickness is a key parameter that needs to be clarified before starting the device process. We applied Fourier transform infrared spectroscopy (FT-IR) to a homoepitaxially grown GaN film that consisted of an n--GaN layer. The estimated film thickness from the FT-IR spectrum agreed well with the results of cross-sectional scanning electron microscope cathodoluminescence images. This is the first report of nondestructive film thickness measurements for homoepitaxially grown GaN and indicates the applicability of FT-IR to the nondestructive inspection of vertical GaN power devices.
Govaert, Filip; Bernard, Magali
2004-02-10
Red spray paints from different European suppliers were characterised to determine the discriminating power of a sequence of analysing techniques. A total of 51 red spray paints were analysed with the help of three techniques: (1) optical microscopy, (2) Fourier transform infrared spectrometry and (3) X-ray fluorescence. Infrared spectra were classified according to binder type, filler and pigment composition and a searchable spectral library was created. Due to the difference in the elemental composition of spray paints, a further discrimination was possible. The microscopic analysis was not taken into consideration for classification purposes. The structure of the substrate under a paint coating strongly affects the surface characteristics of this spray paint. Together with the spectral library, a database of information of spray paints was build.
Fourier transform infrared spectroscopic study of gamma irradiated SiO2 nanoparticles
Huseynov, Elchin; Garibov, Adil; Mehdiyeva, Ravan; Huseynova, Efsane
2018-03-01
In the present work, nano SiO2 particles are investigated before and after gamma irradiation (25, 50, 75, 100 and 200 kGy) using Fourier transform infrared (FTIR) spectroscopy method for the wavenumber between 400-4000 cm-1. It is found that as a result of spectroscopic analysis, five new peaks have appeared after gamma radiation. Two of new obtained peaks (which are located at 687 cm-1 and 2357 cm-1 of wavenumber) were formed as a result of gamma radiation interaction with Si-O bonds. Another three new peaks (peaks appropriate to 941, 2052 and 2357 cm-1 values of wavenumber) appear as a result of interaction of water with nano SiO2 particles after gamma irradiation. It has been defined as asymmetrical bending vibration, symmetrical bending vibration, symmetrical stretching vibration and asymmetrical stretching vibration of Si-O bonds appropriate to peaks.
Directory of Open Access Journals (Sweden)
Hsiu-An eChu
2013-05-01
Full Text Available The photosystem II reaction center mediates the light-induced transfer of electrons from water to plastoquinone, with concomitant production of O2. Water oxidation chemistry occurs in the oxygen-evolving complex (OEC, which consists of an inorganic Mn4CaO5 cluster and its surrounding protein matrix. Light-induced Fourier transform infrared (FTIR difference spectroscopy has been successfully used to study the molecular mechanism of photosynthetic water oxidation. This powerful technique has enabled the characterization of the dynamic structural changes in active water molecules, the Mn4CaO5 cluster, and its surrounding protein matrix during the catalytic cycle. This mini-review presents an overview of recent important progress in FTIR studies of the OEC and implications for revealing the molecular mechanism of photosynthetic water oxidation.
Tang, Chen; Wang, Zhifang; Wang, Linlin; Wu, Jian; Gao, Tao; Yan, Si
2010-02-01
Fringe orientation represents an important property of fringes. The estimation of orientation from a poor quality fringe image is still a challenging problem faced in this area. This paper introduces a new approach for estimating optical fringe orientation with a poor quality image. This approach is based on the power spectrum analysis of the Fourier transform. We evaluate the performance of this algorithm via application to a variety of test cases and comparison with the widely used gradient-based method and accumulate-differences method. The experimental results show that our method is capable of calculating fringe orientation robustly even when the quality of fringe images is considerably low because of high or low density, high noise, and low contrast. Under the same conditions, our accuracy is even better than that obtained with the gradient-based and accumulate-differences methods, especially for fringe images with poor quality.
Multi-dimensional quantum state sharing based on quantum Fourier transform
Qin, Huawang; Tso, Raylin; Dai, Yuewei
2018-03-01
A scheme of multi-dimensional quantum state sharing is proposed. The dealer performs the quantum SUM gate and the quantum Fourier transform to encode a multi-dimensional quantum state into an entanglement state. Then the dealer distributes each participant a particle of the entanglement state, to share the quantum state among n participants. In the recovery, n-1 participants measure their particles and supply their measurement results; the last participant performs the unitary operation on his particle according to these measurement results and can reconstruct the initial quantum state. The proposed scheme has two merits: It can share the multi-dimensional quantum state and it does not need the entanglement measurement.
The calculation of site-dependent earthquake motions -3. The method of fast fourier transform
International Nuclear Information System (INIS)
Simpson, I.C.
1976-10-01
The method of Fast Fourier transform (FFT) is applied to the problem of the determination of site-dependent earthquake motions, which takes account of local geological effects. A program, VELAY 1, which uses the FFT method has been written and is described in this report. The assumptions of horizontally stratified, homogeneous, isotropic, linearly viscoelastic layers and a normally incident plane seismic wave are made. Several examples are given, using VELAY 1, of modified surface acceleration-time histories obtained using a selected input acceleration-time history and a representative system of soil layers. There is a discussion concerning the soil properties that need to be measured in order to use VELAY 1 (and similar programs described in previous reports) and hence generate site-dependent ground motions suitable for aseismic design of a nuclear power plant at a given site. (author)
Differentiation of mycobacterial species by FT-IR (Fourier transform infrared spectroscopy)
International Nuclear Information System (INIS)
Cuellar Gil, Jorge Andres; Coronado Rios, Sandra Milena; Arrubla, Roberto Carlos
2011-01-01
Spectroscopy Fourier transform infrared (FT-IR) was used to differentiate 10 species of mycobacteria. Mycobacterium intracellulare and M. fortuitum (ATCC). M. flavensces, M. smegmatis, M. chelone, M. gordonae, M. triviale, M. vaccae, M. terrae and M. nonchromogenicum (IP). For gender differentiation staphylococcus aureus, streptococcus viridans and streptococcus pyogenes, klebsiella pneumoniae y escherichia coli were included as controls, each species was run for triplicate in KBr and ATR. The spectra were analyzed with the method of principal components to make the first derivatives of first order (D1) in the transmission mode using KBR pellet and ATR base, and a spectral library of the first derivative of ATR was kept. The detection sensitivity was 100% with KBr and the level of differentiation was 100% in three of the four samples problems.
A new expression for doppler broadening function based on Fourier Cosine Transform
Energy Technology Data Exchange (ETDEWEB)
Goncalves, Alessandro da C.; Martinez, Aquilino S.; Silva, Fernando C. da [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear]. E-mails: agoncalves@con.ufrj.br; aquilino@lmp.ufrj.br; fernando@con.ufrj.br
2007-07-01
The main objective of this paper consists of the derivation of an analytical solution for the Doppler broadening function {psi} ({xi}, x). The analytical solution is derived from a new integral expression for the {psi} ({xi}, x) function, which can be interpreted as a Fourier cosine transform. The expression obtained for {psi} ({xi}, x) in terms of elementary functions, proved quite simple and accurate, leading to a similar solution obtained through the differential equation for the {psi} ({xi}, x) function, using the methods of Frobenius and of parameter variation. The Doppler broadening function is widely used in applications related to the treatment of nuclear resonances, calculations of multigroup parameters and resonance self-shielding factors, and to correct microscopic cross section measurements through the activation technique. (author)
A new expression for doppler broadening function based on Fourier Cosine Transform
International Nuclear Information System (INIS)
Goncalves, Alessandro da C.; Martinez, Aquilino S.; Silva, Fernando C. da
2007-01-01
The main objective of this paper consists of the derivation of an analytical solution for the Doppler broadening function Ψ (ξ, x). The analytical solution is derived from a new integral expression for the Ψ (ξ, x) function, which can be interpreted as a Fourier cosine transform. The expression obtained for Ψ (ξ, x) in terms of elementary functions, proved quite simple and accurate, leading to a similar solution obtained through the differential equation for the Ψ (ξ, x) function, using the methods of Frobenius and of parameter variation. The Doppler broadening function is widely used in applications related to the treatment of nuclear resonances, calculations of multigroup parameters and resonance self-shielding factors, and to correct microscopic cross section measurements through the activation technique. (author)
Yang, Wenming; Liao, Ningfang; Cheng, Haobo; Li, Yasheng; Bai, Xueqiong; Deng, Chengyang
2018-01-01
In this paper, we reported the laboratory spectral calibration of an ultraviolet (UV) Fourier transform imaging spectrometer (FTIS). A short overview of the designed UV-FTIS, which feature with a Cassegrain objective, an Offner relay optics system and a spatial-and-temporal modulation Michelson structure, is given. The experimental setup of spectral calibration is described, including details of the light source and integrating sphere. A high pressure mercury lamp was used to acquire reference spectrum. We calculated the all optical path difference (OPD) to achieve spectral response of every wavelength sample and divided the position of reference peak to subpixel to increase the precision of spectral calibration. The spectrum of spectral calibration show two weakly responded peaks, which was validated by reference spectrum of fiber optic spectrometer. The deviation of wavelength calibration is low to establish a best spectrometer resolution. The results of spectral calibration can meet the requirements of the UV-FTIS application.
Energy Technology Data Exchange (ETDEWEB)
Diehl, J.W.; Finkbeiner, J.W.; DiSanzo, F.P. (Mobil Research and Development Corp., Paulsboro, NJ (United States))
1992-12-15
In response to clean fuel legislation, research is underway in the petroleum industry to develop fuels which reduce vehicle exhaust emissions. Part of this effort is the addition of certain ethers and alcohols such as methyl tert-butyl ether (MTBE) and ethanol to gasolines. The capability of accurately measuring these compounds is important in maintaining minimum levels prescribed by law as well as optimum levels for engine performance. GC/Fourier transform infrared (FTIR) spectroscopy has already been demonstrated as a good quantitative tool for organic acids and various pollutants. GC/FTIR is definitely a precise and accurate technique for measuring C1-C4 alcohols and C5 and C6 ethers in gasolines. The use of the correct absorbance reconstruction frequencies gives good selectivity over hydrocarbons as well as very linear and stable calibration curves. 8 refs., 5 figs.
Singular Spectrum Analysis: A Note on Data Processing for Fourier Transform Hyperspectral Imagers.
Rafert, J Bruce; Zabalza, Jaime; Marshall, Stephen; Ren, Jinchang
2016-09-01
Hyperspectral remote sensing is experiencing a dazzling proliferation of new sensors, platforms, systems, and applications with the introduction of novel, low-cost, low-weight sensors. Curiously, relatively little development is now occurring in the use of Fourier transform (FT) systems, which have the potential to operate at extremely high throughput without use of a slit or reductions in both spatial and spectral resolution that thin film based mosaic sensors introduce. This study introduces a new physics-based analytical framework called singular spectrum analysis (SSA) to process raw hyperspectral imagery collected with FT imagers that addresses some of the data processing issues associated with the use of the inverse FT. Synthetic interferogram data are analyzed using SSA, which adaptively decomposes the original synthetic interferogram into several independent components associated with the signal, photon and system noise, and the field illumination pattern. © The Author(s) 2016.
Choi, Heejin; Wadduwage, Dushan; Matsudaira, Paul T.; So, Peter T.C.
2014-01-01
A depth resolved hyperspectral imaging spectrometer can provide depth resolved imaging both in the spatial and the spectral domain. Images acquired through a standard imaging Fourier transform spectrometer do not have the depth-resolution. By post processing the spectral cubes (x, y, λ) obtained through a Sagnac interferometer under uniform illumination and structured illumination, spectrally resolved images with depth resolution can be recovered using structured light illumination algorithms such as the HiLo method. The proposed scheme is validated with in vitro specimens including fluorescent solution and fluorescent beads with known spectra. The system is further demonstrated in quantifying spectra from 3D resolved features in biological specimens. The system has demonstrated depth resolution of 1.8 μm and spectral resolution of 7 nm respectively. PMID:25360367
Emotion recognition based on multiple order features using fractional Fourier transform
Ren, Bo; Liu, Deyin; Qi, Lin
2017-07-01
In order to deal with the insufficiency of recently algorithms based on Two Dimensions Fractional Fourier Transform (2D-FrFT), this paper proposes a multiple order features based method for emotion recognition. Most existing methods utilize the feature of single order or a couple of orders of 2D-FrFT. However, different orders of 2D-FrFT have different contributions on the feature extraction of emotion recognition. Combination of these features can enhance the performance of an emotion recognition system. The proposed approach obtains numerous features that extracted in different orders of 2D-FrFT in the directions of x-axis and y-axis, and uses the statistical magnitudes as the final feature vectors for recognition. The Support Vector Machine (SVM) is utilized for the classification and RML Emotion database and Cohn-Kanade (CK) database are used for the experiment. The experimental results demonstrate the effectiveness of the proposed method.
Propagation of a general-type beam through a truncated fractional Fourier transform optical system.
Zhao, Chengliang; Cai, Yangjian
2010-03-01
Paraxial propagation of a general-type beam through a truncated fractional Fourier transform (FRT) optical system is investigated. Analytical formulas for the electric field and effective beam width of a general-type beam in the FRT plane are derived based on the Collins formula. Our formulas can be used to study the propagation of a variety of laser beams--such as Gaussian, cos-Gaussian, cosh-Gaussian, sine-Gaussian, sinh-Gaussian, flat-topped, Hermite-cosh-Gaussian, Hermite-sine-Gaussian, higher-order annular Gaussian, Hermite-sinh-Gaussian and Hermite-cos-Gaussian beams--through a FRT optical system with or without truncation. The propagation properties of a Hermite-cos-Gaussian beam passing through a rectangularly truncated FRT optical system are studied as a numerical example. Our results clearly show that the truncated FRT optical system provides a convenient way for laser beam shaping.
Mesooptical Fourier transform microscope - a new device for high energy physics
International Nuclear Information System (INIS)
Astakhov, A.Ya.; Batusov, Yu.A.; Bencze, Gy.L.; Farago, I.; Kisvaradi, A.; Molnar, L.; Soroko, L.M.; Vegh, J.
1988-01-01
A new device for high energy physics, Mesooptical Fourier Transform Microscope (MFTM), designed for observation of straight-line particle tracks in nuclear emulsion is described. The MFTM works without any mechanical or electronical depth scanning and can be considered as a selectively viewing eye. The computer controlled system containing MFTM as the main unit is given. This system can be used for fast search particle tracks and events produced by high energy neutrinos from accelerators. The results of the first experimental test of the computer controlled MFTM are presented. The performances of this system are described and discussed. It is shown that the angular resolution of the MFTM is 1 angular minute and the measurement time is equal to 30 ms. As all operations in the MFTM go without any depth scanning this new system works at least two orders of magnitude faster than any known system with a traditional optical microscope
Hirota, Eizi; Kawasima, Yoshiyuki; Ajiki, Ken
2017-12-01
Trifluoromethylsulfur pentafluoride CF3SF5, which has been attracting much attention because of its unusually large global warming potential, was investigated by Fourier transform microwave spectroscopy in order to determine the twelve-fold potential barrier to internal rotation in this molecule. We have found the V12 value to be close to zero. Relaxation among internal-rotation and overall-rotation levels was found inhomogeneous, resulting in distributions quite different from thermal in low-temperature molecular beam, which might affect significantly thermodynamic properties of the molecule. Rotational spectra of the 13C species and the 34S species were also observed in natural abundance, leading to the rs Csbnd S bond length of 1.8808 (7) Å.
Li, Xiao-Wei; Lee, In-Kwon
2015-03-01
In this paper, we propose an image encryption technique to simultaneously encrypt double or multiple images into one encrypted image using computational integral imaging (CII) and fractional Fourier transform (FrFT). In the encryption, each of the input plane images are located at different positions along a pickup plane, and simultaneously recorded in the form of an elemental image array (EIA) through a lenslet array. The recorded EIA to be encrypted is multiplied by FrFT with two different fractional orders. In order to mitigate the drawbacks of occlusion noise in computational integral imaging reconstruction (CIIR), the plane images can be reconstructed using a modified CIIR technique. To further improve the solution of the reconstructed plane images, a block matching algorithm is also introduced. Numerical simulation results verify the feasibility and effectiveness of the proposed method.
International Nuclear Information System (INIS)
Demirgian, J.C.; Mao, Zhouxiong; MacIntosh, M.; Wentz, C.A.
1991-01-01
The requirements of the Clean Air Act Amendments of 1990 and public concern about the safety of air emissions from incineration necessitate the development of continuous emission monitors for on-line determination of both the destruction removal efficiency (DRE) of hazardous wastes and the emission products of incomplete combustion (PICs). This paper describes a Fourier transform infrared (FTIR) spectroscopic method that has been developed for this purpose. A laboratory-scale hazardous waste incinerator was coupled directly, via heated sampling lines, to a heated long-path cell (LPC) combined with an FTIR analyzer. The DRE and PIC emission levels were measured, on-line, for toluene incineration. Thus, this new LPC/FTIR system has been demonstrated as an effective continuous emissions monitor. Further experimental work with other hydrocarbons is now underway using the FTIR system. 8 figs., 4 tabs
Niece, Krista L; Akers, Kevin S
2015-09-01
Colistin use has increased in response to the advent of infections caused by multidrug-resistant organisms. It is administered parenterally as an inactive prodrug, colistin methanesulfonate (CMS). Various formulations of CMS and labeling conventions can lead to confusion about colistin dosing, and questions remain about the pharmacokinetics of CMS. Since CMS does not have strong UV absorbance, current methods employ a laborious process of chemical conversion to colistin followed by precolumn derivatization to detect formed colistin by high-performance liquid chromatography. Here, we report a method for direct quantification of colistin methanesulfonate by attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR). Copyright © 2015, American Society for Microbiology. All Rights Reserved.
Prepreg cure monitoring using diffuse reflectance-FTIR. [Fourier Transform Infrared Technique
Young, P. R.; Chang, A. C.
1984-01-01
An in situ diffuse reflectance-Fourier transform infrared technique was developed to determine infrared spectra of graphite fiber prepregs as they were being cured. A bismaleimide, an epoxy, and addition polyimide matrix resin prepregs were studied. An experimental polyimide adhesive was also examined. Samples were positioned on a small heater at the focal point of diffuse reflectance optics and programmed at 15 F/min while FTIR spectra were being scanned, averaged, and stored. An analysis of the resulting spectra provided basic insights into changes in matrix resin molecular structure which accompanied reactions such as imidization and crosslinking. An endo-exothermal isomerization involving reactive end-caps was confirmed for the addition polyimide prepregs. The results of this study contribute to a fundamental understanding of the processing of composites and adhesives. Such understanding will promote the development of more efficient cure cycles.
Tieng, S. M.; Lai, W. Z.
Because of the importance of the temperature scalar measurements in combination diagonostics, application of phase shift holographic interferometry to temperature measurement of an axisymmetrically premixed flame was experimentally investigated. The test apparatus is an axisymmetric Bunsen burner. Propane of 99 percent purity is used as the gaseous fuel. A fast Fourier transform, a more efficient and accurate approach for Abel inversion, is used for reconstructed the axisymmetric temperature field from the interferometric data. The temperature distribution is compared with the thermocouple-measured values. The comparison shows that the proposed technique is satisfactory. The result errors are analyzed in detail. It is shown that this technique overcomes most of the earlier problems and limitations detrimental to the conventional holographic interferometry.
Directory of Open Access Journals (Sweden)
Zeyu Lin
2017-01-01
Full Text Available In this paper, the authors presented a study on the discrimination of handlebar grip samples, to provide effective forensic science service for hit and run traffic cases. 50 bicycle handlebar grip samples, 49 electric bike handlebar grip samples, and 96 motorcycle handlebar grip samples have been randomly collected by the local police in Beijing (China. Fourier transform infrared microspectroscopy (FTIR was utilized as analytical technology. Then, target absorption selection, data pretreatment, and discrimination of linked samples and unlinked samples were chosen as three steps to improve the discrimination of FTIR spectrums collected from different handlebar grip samples. Principal component analysis and receiver operating characteristic curve were utilized to evaluate different data selection methods and different data pretreatment methods, respectively. It is possible to explore the evidential value of handlebar grip residue evidence through instrumental analysis and statistical treatments. It will provide a universal discrimination method for other forensic science samples as well.
Speeding-up exchange-mediated saturation transfer experiments by Fourier transform
International Nuclear Information System (INIS)
Carneiro, Marta G.; Reddy, Jithender G.; Griesinger, Christian; Lee, Donghan
2015-01-01
Protein motions over various time scales are crucial for protein function. NMR relaxation dispersion experiments play a key role in explaining these motions. However, the study of slow conformational changes with lowly populated states remained elusive. The recently developed exchange-mediated saturation transfer experiments allow the detection and characterization of such motions, but require extensive measurement time. Here we show that, by making use of Fourier transform, the total acquisition time required to measure an exchange-mediated saturation transfer profile can be reduced by twofold in case that one applies linear prediction. In addition, we demonstrate that the analytical solution for R 1 ρ experiments can be used for fitting the exchange-mediated saturation transfer profile. Furthermore, we show that simultaneous analysis of exchange-mediated saturation transfer profiles with two different radio-frequency field strengths is required for accurate and precise characterization of the exchange process and the exchanging states
DEFF Research Database (Denmark)
Uceda Otero, E. P.; Eliel, G. S. N.; Fonseca, E. J. S.
2013-01-01
In this work we have used Fourier transform infrared (FTIR) / vibrational absorption (VA) spectroscopy to study two cancer cell lines: the Henrietta Lacks (HeLa) human cervix carcinoma and 5637 human bladder carcinoma cell lines. Our goal is to experimentally investigate biochemical changes...... and differences in these cells lines utilizing FTIR spectroscopy. We have used the chemometrical and statistical method principal component analysis (PCA) to investigate the spectral differences. We have been able to identify certain bands in the spectra which are so-called biomarkers for two types of cell lines......, three groups for the 5637 human bladder carcinoma cell line (5637A, 5637B and 5637C), and another one for the HeLa human cervix carcinoma cell line. The vibrational modes can be assigned to specific bands involving characteristic motions of the protein backbone. This work shows that infrared vibrational...
Energy Technology Data Exchange (ETDEWEB)
Buseck, P.R.; Epelboin, Y.; Rimsky, A.
1988-11-01
Interpretation of images obtained by high-resolution transmission electron microscopy (HRTEM) can be aided by the use of processed signals. Images are recorded digitally or are digitized from a photograph, and then these data are Fourier transformed and treated. The low- and high-frequency signals are removed, and a variety of circular and elliptical (anisotropic) apertures or screens are applied to explore and highlight features of special interest. A minicomputer can be used to perform such image processing rapidly, interactively, and with high precision. Elliptical filters are of special interest for the examination of linear or planar features such as the distribution of stacking faults or the presence and distribution of superstructures. Some superstructures themselves contain defects, and these can similarly be highlighted and examined. The uses of processing for examining HRTEM images of layering in a complex sheet silicate mineral and dislocation cores in grossular garnet are illustrated.
Zimmerman, G. A.; Gulkis, S.
1991-01-01
The sensitivity of a matched filter-detection system to a finite-duration continuous wave (CW) tone is compared with the sensitivities of a windowed discrete Fourier transform (DFT) system and an ideal bandpass filter-bank system. These comparisons are made in the context of the NASA Search for Extraterrestrial Intelligence (SETI) microwave observing project (MOP) sky survey. A review of the theory of polyphase-DFT filter banks and its relationship to the well-known windowed-DFT process is presented. The polyphase-DFT system approximates the ideal bandpass filter bank by using as few as eight filter taps per polyphase branch. An improvement in sensitivity of approx. 3 dB over a windowed-DFT system can be obtained by using the polyphase-DFT approach. Sidelobe rejection of the polyphase-DFT system is vastly superior to the windowed-DFT system, thereby improving its performance in the presence of radio frequency interference (RFI).
Hyperfine-structure measurements in bismuth using a Fourier-transform spectrometer
International Nuclear Information System (INIS)
George, S.; Munsee, J.H.; Verges, J.
1985-01-01
The spectrum of neutral bismuth has been studied in the infrared region by means of the Fourier-transform spectrometer at the Laboratoire Aime Cotton, Orsay, France. A microwave-excited discharge tube containing bismuth iodide was used as the light source. A total of 37 hyperfine structures was studied. Precise measurements of the center of gravity of the structures give energy levels with an error less than 0.005 m -1 . Complete analysis of these hyperfine structures resulted in the determination of the magnetic-dipole and the electric-quadrupole interaction constants for 10 even and 12 odd levels. The present results have increased the number of newly classified lines to 78, as compared with 28 reported in our earlier work [J. Opt. Soc. Am. 72, 589 (1982)]. The analysis has also resulted in the confirmation an the assignment of many J values, improved values of energy levels, and two new levels
Nejadriahi, Hani
This thesis explores fundamentals of optical computing by means of fast Fourier transform Integration on Silicon On Insulator chip technology toward its implementation in analog and temporal domain. This is done by cascading (N - 2) stages of delayed interferometers (couplers and phase shifters) where a parallel set of N time samples are taken and using the delay lines and phase of the optical components (constructive/deconstructive interference) the DFT is computed. Hence it is important to understand the behavior and the quality of the Optical Fast Fourier Transform (OFFT) and its sensitivity due to the important role of phase, time delay, and power to overcome the system of delayed interferometers to become unstable. This was done by analyzing the characteristics of the extinction ratio of the OFFT as a function of the phase, time delay, and power. The OFFT design was built on passive components (2 x 2 couplers : cascaded Mach Zehnder Inteferometer) used for addition and subtraction through optical interference, waveguides with short path differences are used for phase shifting and waveguides with long path differences are used for signal delay based on the needed number of outputs. While in principal an OFFT network could be created with perfect phase alignment, in practice active phase calibration at a specific temperature is required to compensate for fabrication variance. This phase calibration was accomplished with a heating element placed along on one of the waveguide paths of the cascaded interferometers. Since the OFFT is a system of imbalanced interferometers, there are additional bends designed to compensate for the difference in power ratios of the arms. Alongside the fabrication and sensitivity analysis of the OFFT, its individual components such as grating coupler, 2 x 2 (star) coupler, y branch, straight, and spiral waveguides and their characteristics were studied. The individuals' contribution to loss and power consumption of the entire system
Kaneko, T.; Grainge, K.
2008-10-01
Context: Fourier transform (or lag) correlators in radio interferometers can serve as an efficient means of synthesising spectral channels. However aliasing corrupts the edge channels so they usually have to be excluded from the data set. In systems with around 10 channels, the loss in sensitivity can be significant. In addition, the low level of residual aliasing in the remaining channels may cause systematic errors. Moreover, delay errors have been widely reported in implementations of broadband analogue correlators and simulations have shown that delay errors exasperate the effects of aliasing. Aims: We describe a software-based approach that suppresses aliasing by oversampling the cross-correlation function. This method can be applied to interferometers with individually-tracking antennas equipped with a discrete path compensator system. It is based on the well-known property of interferometers where the drift scan response is the Fourier transform of the source's band-limited spectrum. Methods: In this paper, we simulate a single baseline interferometer, both for a real and a complex correlator. Fringe-rotation usually compensates for the phase of the fringes to bring the phase centre in line with the tracking centre. Instead, a modified fringe-rotation is applied. This enables an oversampled cross-correlation function to be reconstructed by gathering successive time samples. Results: Simulations show that the oversampling method can synthesise the cross-power spectrum while avoiding aliasing and works robustly in the presence of noise. An important side benefit is that it naturally accounts for delay errors in the correlator and the resulting spectral channels are regularly gridded
Fourier-based quantification of renal glomeruli size using Hough transform and shape descriptors.
Najafian, Sohrab; Beigzadeh, Borhan; Riahi, Mohammad; Khadir Chamazkoti, Fatemeh; Pouramir, Mahdi
2017-11-01
Analysis of glomeruli geometry is important in histopathological evaluation of renal microscopic images. Due to the shape and size disparity of even glomeruli of same kidney, automatic detection of these renal objects is not an easy task. Although manual measurements are time consuming and at times are not very accurate, it is commonly used in medical centers. In this paper, a new method based on Fourier transform following usage of some shape descriptors is proposed to detect these objects and their geometrical parameters. Reaching the goal, a database of 400 regions are selected randomly. 200 regions of which are part of glomeruli and the other 200 regions are not belong to renal corpuscles. ROC curve is used to decide which descriptor could classify two groups better. f_measure, which is a combination of both tpr (true positive rate) and fpr (false positive rate), is also proposed to select optimal threshold for descriptors. Combination of three parameters (solidity, eccentricity, and also mean squared error of fitted ellipse) provided better result in terms of f_measure to distinguish desired regions. Then, Fourier transform of outer edges is calculated to form a complete curve out of separated region(s). The generality of proposed model is verified by use of cross validation method, which resulted tpr of 94%, and fpr of 5%. Calculation of glomerulus' and Bowman's space with use of the algorithm are also compared with a non-automatic measurement done by a renal pathologist, and errors of 5.9%, 5.4%, and 6.26% are resulted in calculation of Capsule area, Bowman space, and glomeruli area, respectively. Having tested different glomeruli with various shapes, the experimental consequences show robustness and reliability of our method. Therefore, it could be used to illustrate renal diseases and glomerular disorders by measuring the morphological changes accurately and expeditiously. Copyright © 2017 Elsevier B.V. All rights reserved.
Directory of Open Access Journals (Sweden)
Ichwana Ichwana
2017-04-01
The Application of Fourier Transform Infrared Photoacoustics Spectroscopy (FTIR-PAS for Rapid Soil Quality Evaluation Abstract. The major function of soil is to provide fundamental natural resources for survival of plants, animals, and the human race. Soil functions depend on the balances of its structure and composition, well as the chemical, biological, and physical properties. It is become one important key aspect and routine activity in crop management system. To monitor and determine soil quality properties, several methods were already widely used in which most of them are based on solvent extraction followed by other laboratory procedures. However, these methods often require laborious and complicated processing for samples. They are time consuming and destructive. In last few decades, the application of infrared spectroscopy as non-destructive technique in determining soil quality properties (C, N, P and K rapidly and simultaneously. Fourier transform infrared spectrum (FTIR were acquired in wavelength range from 1000 to 2500 nm with applying photo-acoustic spectroscopy (PAS. Least square-support vector machine regression (LS-SVM approach was then applied to predict soil quality properties. The results showed that C and N can be predicted accurately using FTIR-PAS whilst other parameters (P, K, Mg, Ca, S can be predicted with maximum RPD index is 1.9. Moreover, soil clay, moisture and soil microbes were feasible to be detected by using FTIR-PAS combining with discriminant analysis (LS-DA or cluster analysis (CA. It may conclude that FTIR-PAS technology can be used as a real time method in monitoring soil quality and fertility properties.
Nikzad-Langerodi, Ramin; Arth, Katharina; Klatte-Asselmeyer, Valerie; Bressler, Sabine; Saukel, Johannes; Reznicek, Gottfried; Dobeš, Christoph
2017-11-09
(Acetoxy-)valerenic acid and total essential oil content are important quality attributes of pharmacy grade valerian root (Valerianae radix). Traditional analysis of these quantities is time-consuming and necessitates (harmful) solvents. Here we investigated an application of attenuated total reflection Fourier transform infrared spectroscopy for extractionless analysis of these quality attributes on a representative sample comprising 260 wild-crafted individuals covering the Central European taxonomic diversity of the Valeriana officinalis L. s. l. species aggregate with its three major ploidy cytotypes (i.e., di-, tetra- and octoploid). Calibration models were built by orthogonal partial least squares regression for quantitative analysis of (acetoxy-)valerenic acid and total essential oil content. For the latter, we propose a simplistic protocol involving apolar extraction followed by gas chromatography as a reference method for multivariate calibration in order to handle the analysis of samples taken from individual plants. We found good predictive ability of chemometric models for quantification of valerenic acid, acetoxyvalerenic acid, total sesquiterpenoid acid, and essential oil content with a root mean squared error of cross-validation of 0.064, 0.043, and 0.09 and root mean squared error of prediction of 0.066, 0.057, and 0.09 (% content), respectively. Orthogonal partial least squares discriminant analysis revealed good discriminability between the most productive phenotype (i.e., the octoploid cytotype) in terms of sesquiterpenoid acids, and the less productive ones (i.e., di- and tetraploid). All in all, our results demonstrate the application of attenuated total reflection Fourier transform infrared spectroscopy for rapid, extractionless estimation of the most important quality attributes of valerian root and minimally invasive identification of the most productive phenotype in terms of sesquiterpenoid acids. Georg Thieme Verlag KG Stuttgart · New
Performance evaluation of fast Fourier-transform continuous cyclic-voltammetry pesticide biosensor
International Nuclear Information System (INIS)
Ebrahimi, Bahman; Shojaosadati, Seyed Abbas; Daneshgar, Parandis; Norouzi, Parviz; Mousavi, Seyyed Mohammad
2011-01-01
In this work, a method for the fast monitoring of OPs in flow-injection systems was evaluated. The fast Fourier transform continuous cyclic-voltammetry (FFTCCV) at the carbon-paste electrode in a flowing solution system was used for determination of OPs. In this method the S/N ratio is enhanced by using of fast Fourier transform of the analyte and signal integration. FFTCCV can be considered as a new sensitive, accurate and fast method for determination of drugs and some pesticides. However, in order to obtain better sensitivity for a specific target, experimental parameters should be optimized. Response surface methodology (RSM) was applied to optimize three effective parameters (enzyme activity, multiwall carbon nanotube quantity and acidic sol-gel quantity). The optimum values for the tested parameters were enzyme amount H0.169 U cm -2 , multiwall carbon nanotube (MWCNT) 0.607 mL and acidic sol-gel 1.012 mL. The optimum feed pH, feed flow rate, ATChCl concentration and sweeping-rate were found to be 7.4, 0.34 mL min -1 , 0.750 mM and 10 V s -1 , respectively. The long-term stability of this flow-through system was 80% of its initial response after 120 days. Based on an incubation time of 12 min, it was found that the detection limit for paraoxon was equal to 1.7 x 10 -7 mg L -1 (6.2 x 10 -13 M). The developed biosensor exhibited good repeatability and reproducibility. This study provides a new, modern, sensitive tool for the analysis of organophosphate pesticides.
Performance evaluation of fast Fourier-transform continuous cyclic-voltammetry pesticide biosensor
Energy Technology Data Exchange (ETDEWEB)
Ebrahimi, Bahman [Biotechnology Group, Chemical Engineering Department, Faculty of Engineering, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Shojaosadati, Seyed Abbas, E-mail: shoja_sa@modares.ac.ir [Biotechnology Group, Chemical Engineering Department, Faculty of Engineering, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Daneshgar, Parandis [Institute of Biochemistry and Biophysic, University of Tehran, Tehran (Iran, Islamic Republic of); Norouzi, Parviz [Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran (Iran, Islamic Republic of); Mousavi, Seyyed Mohammad [Biotechnology Group, Chemical Engineering Department, Faculty of Engineering, Tarbiat Modares University, Tehran (Iran, Islamic Republic of)
2011-02-21
In this work, a method for the fast monitoring of OPs in flow-injection systems was evaluated. The fast Fourier transform continuous cyclic-voltammetry (FFTCCV) at the carbon-paste electrode in a flowing solution system was used for determination of OPs. In this method the S/N ratio is enhanced by using of fast Fourier transform of the analyte and signal integration. FFTCCV can be considered as a new sensitive, accurate and fast method for determination of drugs and some pesticides. However, in order to obtain better sensitivity for a specific target, experimental parameters should be optimized. Response surface methodology (RSM) was applied to optimize three effective parameters (enzyme activity, multiwall carbon nanotube quantity and acidic sol-gel quantity). The optimum values for the tested parameters were enzyme amount H0.169 U cm{sup -2}, multiwall carbon nanotube (MWCNT) 0.607 mL and acidic sol-gel 1.012 mL. The optimum feed pH, feed flow rate, ATChCl concentration and sweeping-rate were found to be 7.4, 0.34 mL min{sup -1}, 0.750 mM and 10 V s{sup -1}, respectively. The long-term stability of this flow-through system was 80% of its initial response after 120 days. Based on an incubation time of 12 min, it was found that the detection limit for paraoxon was equal to 1.7 x 10{sup -7} mg L{sup -1} (6.2 x 10{sup -13} M). The developed biosensor exhibited good repeatability and reproducibility. This study provides a new, modern, sensitive tool for the analysis of organophosphate pesticides.
Dziekonski, Eric T; Johnson, Joshua T; McLuckey, Scott A
2017-04-18
Mass resolution (M/ΔM fwhm) is observed to linearly increase with harmonic order in a Fourier transform electrostatic linear ion trap (ELIT) mass spectrometer. This behavior was predicted by Grosshans and Marshall for frequency-multiple detection in a Fourier transform ion cyclotron resonance mass spectrometer only for situations when the prominent mechanism for signal decay is ion ejection from the trap. As the analyzer pressure in our ELIT chamber is relatively high, such that collisional scattering and collision-induced dissociation are expected to underlie much of the ion loss, we sought to explore the relationship between harmonic order and mass resolution. Mass resolutions of 36 900 (fundamental), 75 850 (2nd harmonic), and 108 200 (3rd harmonic) were obtained for GdO + (avg. m/z 173.919) with a transient length of 300 ms. To demonstrate that the mass resolution was truly increasing with harmonic order, the unresolved isotopes at the fundamental distribution of cytochrome c +8 (m/z ∼ 1549) were nearly baseline, resolved at the third harmonic (mass resolution ≈ 23 000) with a transient length of only 200 ms. This experiment demonstrates that, when the ion density is sufficiently low, ions with frequency differences of less than 4 Hz remain uncoalesced. Higher harmonics can be used to increase the effective mass resolution for a fixed transient length and thereby may enable the resolution of closely spaced masses, determination of a protein ion's charge state, and study of the onset of peak coalescence when the resolution at the fundamental frequency is insufficient.