WorldWideScience

Sample records for plate tin products

  1. 76 FR 14902 - Certain Tin Mill Products From Japan: Rescission of Antidumping Duty Administrative Review

    Science.gov (United States)

    2011-03-18

    ..., surface finish, temper, coating metal (tin, chromium, chromium oxide), reduction (single-or double-reduced... products that are coated or plated with tin, chromium or chromium oxides. Flat-rolled steel products coated with tin are known as tin plate. Flat-rolled steel products coated with chromium or chromium oxides...

  2. Development of tin-plated regenerator material

    Science.gov (United States)

    Xu, M. Y.; Morie, T.; Tsuchiya, A.

    2017-02-01

    To improve the efficiency of a cryocooler, it is vital to improve the regenerator. In general, the heat capacity of materials decreases as temperature decreases. Thus, when temperature is below 50 K, lead spheres are often used as a regenerator material. However, the pressure drop through a sphere regenerator is larger than that through a screen regenerator. To overcome this dilemma, a new, low pressure loss tin-plated screen is proposed. A comparison test was performed with a two-stage GM cryocooler by replacing part of the first stage regenerator material, bronze screens with tin-plated screens. Compared to a regenerator filled with bronze screens, the cooling capacity of the first stage increased by about 14% at 40 K and 90% at 30 K with such tin-plated screens. The ratio of the wire diameter before and after the deposition was also optimized. An optimum cooling capacity of 53.5 W at 40 K was obtained at a diameter ratio of about 1.4. The detailed experimental results are reported in this paper.

  3. Studies on Properties and Structure of Electroless Plating Tin Coating

    Institute of Scientific and Technical Information of China (English)

    XU Rui-dong; GUO Zhong-cheng; ZHU Xiao-yun

    2004-01-01

    The composition and structure of electroless tin coating were analyzed by SEM and X-ray diffraction. In the meantime, porosity, solderability and extensibility were determined by physical and chemical methods. The results showed that the porosity of the tin coating increases with the rise of bath temperature and decreases as the plating time rises. Solderability is improved with the rise of thickness of tin coating, and decreases when the tin deposit is heated at 180 ~ 200 ℃. The crystalline grain size becomes bigger and bigger with increasing plating time or bath temperature or coating thickness. X-ray diffraction indicates that only Cu and β-Sn phases show up in the diffraction patterns. Tin coating has a strong joint force with copper substrate and excellent function of electrochemical protection as anode coating.

  4. Influence of Fretting Wear on Lifetime of Tin Plated Connectors

    Science.gov (United States)

    Ikeda, Hirosaka; Ito, Tetsuya; Sawada, Shigeru; Hattori, Yasuhiro; Saitoh, Yasushi; Tamai, Terutaka; Iida, Kazuo

    Due to the recent increase in electronic devices mounted on automobiles, a large number of connectors, especially low-cost tin plated connectors are being used. As a result, their contact reliability has become problematic. Furthermore, for the connectors which are subjected to fretting wear caused by heat cycle and vibrations, the contact resistance increases because of wear of tin and deposition of oxides, which generates problems of poor contact. This study is intended to analyze the change in contact resistance of tin plated connectors from the start of fretting wear to the end of their lifetime from the viewpoint of practical reliability, and to observe the trace and the characteristics of fretting wear microscopically. This study found that wear and oxidation of tin plated connectors start immediately with fretting wear, and thus accumulation of abrasion powder on fretting areas causes connectors to reach to the end of their useful lifetime quickly. Especially, it was demonstrated that amplitude of fretting has a considerable influence on a connector's lifetime. It is made clear that air-tightness, so-called “gas-tight” of tin in a fretting area influences fretting wear considerably.

  5. Tin oxide coating of aluminous porcelain by reactive ion plating.

    Science.gov (United States)

    McCrory, P V; Tinston, S; Piddock, V; Kelly, P; Combe, E C; Arnell, R D

    1991-06-01

    Alumina reinforced dental porcelain has been coated directly with tin oxide by reactive ion plating. Samples were prepared at different distances from the tin source in the ion plating rig. Tensile bond strengths of treated and untreated porcelain discs to a commercially available phosphate-methacrylate based dental cement were determined. Bond strengths of certain coated samples were found to be in excess of the cohesive strength of the porcelain substrates (greater than 7.8 MPa), whereas untreated porcelain achieved an average bond strength of only 3.4 MPa. The microstructures of coatings produced under conditions similar to those which yielded the maximum bond strength were examined in a scanning electron microscope and were found to be approximately 0.5 microns thick. It is believed that ion plating has great potential for rendering inert ceramic surfaces capable of direct bonding to dental cements.

  6. Photoelectricalchemical characteristics of brush plated tin sulfide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Subramanian, B.; Jayachandran, M. [Central Electrochemical Research Inst., Karaikudi (India); Sanjeeviraja, C. [Alagappa Univ., Karaikudi (India). Dept. of Physics

    2003-08-01

    Thin films of tin sulfide find wide applications in optoelectronic devices and window materials for heterojunction solar cells. Thin films of p-SnS were brush plated onto tin oxide coated glass substrates from aqueous solution containing SnCl{sub 2} and Na{sub 2}S{sub 2}O{sub 3}. Deposits have been characterized with XRD and SEM for structural analysis. Hot probe method showed invariably p-type nature for all the brush plated SnS films. The variation of space charge capacitance, C{sub sc} with applied potential, V, was recorded for the PEC cell with p-SnS/Fe{sup 3+}, Fe{sup 2+}/Pt system. The spectral response of the PEC cell formed with SnS photoelectrode was studied and reported. (author)

  7. Photoelectrochemical characteristics of brush plated tin sulfide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Subramanian, B.; Jayachandran, M. [Central Electrochemical Research Institute, Karaikudi 630 006 (India); Sanjeeviraja, C. [Department of Physics, Alagappa University, Karaikudi 630 006 (India)

    2003-08-01

    Thin films of tin sulfide find wide applications in optoelectronic devices and window materials for heterojunction solar cells. Thin films of p-SnS were brush plated onto tin oxide coated glass substrates from aqueous solution containing SnCl{sub 2} and Na{sub 2}S{sub 2}O{sub 3}. Deposits have been characterized with XRD and SEM for structural analysis. Hot probe method showed invariably p-type nature for all the brush plated SnS films. The variation of space charge capacitance, C{sub sc}, with applied potential, V, was recorded for the PEC cell with p-SnS/Fe{sup 3+}, Fe{sup 2+}/Pt system. The spectral response of the PEC cell formed with SnS photoelectrode was studied and reported.

  8. Evaluation of tin plating systems for a high-noble alloy.

    Science.gov (United States)

    Imbery, T A; Davis, R D

    1993-01-01

    The tensile bond strength of Panavia EX to a high-noble alloy prepared by abrasive spraying and tin plating was measured. Two different intraoperatory tin plating systems were compared. Disk-shaped specimens were cast in type III gold, abrasive sprayed with aluminum oxide, and divided into three groups of 30 specimens each. Specimens in one group were tin plated by using a Kura Ace Mini unit, those in the second group were tin plated by using a Micro Tin unit, and those in the third group were not tin plated and served as the control group. Disks within each group were luted to each other with Panavia EX. The specimens were thermocycled and tested in tension. There was no significant difference between the two tin plated groups; however, the luting bond of both experimental groups was significantly stronger than was that of the control (P < .05).

  9. Underpotential deposition of tin(II) on a gold disc electrode and determination of tin in a tin plate sample.

    Science.gov (United States)

    Qiao, Zhiqing; Shang, Wei; Zhang, Xin; Wang, Chunming

    2005-04-01

    This work describes a study of the underpotential deposition (UPD) of Sn2+ on a polycrystalline gold disc electrode using cyclic voltammetry (CV) and chronocoulometry (CC). Sn2+ ions showed well-defined peaks from UPD and UPD stripping (UPD-S) in 1 mol/L HCl solutions, while bulk deposition (BD) and BD stripping (BD-S) of the ions were also observed. The measured UPD shifts, DeltaE(UPD), between the UPD-S and the BD-S peaks were more than 200 mV. The UPD charge and the surface coverage of tin were measured by CC. A new method for determining Sn2+ was therefore developed, based on the excellent electrochemical properties of the Au/Sn UPD system. A plot of the UPD-DPASV (differential pulse anodic stripping voltammetry) signal versus the Sn(II) concentration was obtained for [Sn(II)] of 1.98x10(-7) to 3.64x10(-5) M. The method developed here has been applied to determine the tin in a tin plate sample.

  10. CHARACTERISTICS OF LOW TEMPERATURE ION PLATING TiN COATINGS

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    The TiN coatings were deposited onto the low carbon steel substrates with different temperatures (150,250,350 and 450 ℃), using hollow cathode discharge (HCD) ion plating method. The measurements of the microhardness and wear resistance of the coatings show that the hardness value slowly increases and the wear resistance remains almost unchanged with increasing the substrate temperature from 150 ℃ to 450 ℃. The reason for effect of the substrate temperature on the properties and morphologies of the coatings was investigated by means of X-ray diffraction and scanning electron microscope (SEM).

  11. The bond strength of porcelain to Ni-Cr alloy--the influence of tin or chromium plating.

    Science.gov (United States)

    Inoue, K; Murakami, T; Terada, Y

    1992-01-01

    Nickel-chromium alloys were plated with tin and chromium to evaluate the effect on porcelain shear bond strength. Six plating methods were used. Additionally, the microstructure of the bond between the plated alloy and porcelain were studied using SEM and EPMA. Tin plating increased the bond strength of porcelain to a nickel-chromium alloy while chromium plating did not.

  12. Exploratory report Tin and tin compounds

    NARCIS (Netherlands)

    Slooff W; Bont PFH; Hesse JM; Annema JA

    1993-01-01

    In the Netherlands tin is produced from concentrate and secondary production (about 3,500 tonnes Sn per year), whereas about 5,000 tonnes Sn per year is applied. Of this amount about 4,200 tonnes is applied as inorganic tin (most for the manufacturing of tin plate) and about 800 tonnes Sn is applie

  13. Effects of tin plating on base metal alloy-ceramic bond strength.

    Science.gov (United States)

    Değer, S; Caniklioglu, M B

    1998-01-01

    This study investigated the metal-ceramic bonding of treated metal surfaces. The study was divided into two parts. In Part I, the depth of tin diffusion from a tin-plated bone metal alloy surface was measured using an energy-dispersive spectrometer. In Part II the metal-ceramic bond strength was determined using a shear test. The weakest bonding was observed in the directly tin-plated group, and the strongest metal-ceramic bonding was maintained in the tin-diffused group. A controlled oxidation produced the greatest bond strengths. With the base metal alloys tested, diffusion under the argon environment was conducive to a stronger metal-ceramic bond. The metal oxidation rate should approximate the ceramic vitrification rate, and the diffusion rate of the metal elements should be slower than the vitrification rate to obtain the strongest metal-ceramic bond.

  14. 浅谈硫酸盐镀锡%Introduction to stannous sulfate tin plating

    Institute of Scientific and Technical Information of China (English)

    李玉

    2014-01-01

    In circuit board plating process, due to the reason that management or maintenance does not reach the designated position, there often appear unhealthy phenomenon such as uneven tin, tin plating thickness cried, tin bath opacity, independent grommet with etched tin, which lead to scrap. This article focuses on the cause of the bad and the improving measures.%在电路板电镀生产过程中,由于疏于管理或保养不到位,常出现镀锡厚度不均匀、镀锡锡面发黑、镀锡槽液混浊、独立孔环被蚀刻等镀锡不良现象,造成报废。文章主要讨论引起上述不良的原因及改善办法。

  15. Tin

    NARCIS (Netherlands)

    Bulten, E.J.; Meinema, H.A.

    1991-01-01

    Tin is rather unique in the wide variety of its compounds and applications. Ever since the beginning of the bronze age the metal and its alloys have been of importance to mankind. When considering the impact of tin and its compounds on the environment, it has to be realized that no generalization ca

  16. [Study of TiN plating coat on increasing shear bond strength].

    Science.gov (United States)

    Yu, Shao-Bing; Guo, Tian-Wen; Yue, Ye; Yin, Lu

    2008-04-01

    To investigate the feasibility of increasing bond strength of polymer ceramic to titanium using TiN coating. Twelve pure titanium specimens were casted and divided into two groups randomly. In one group,the surface was processed with conventional handling,in the other group,the surface was coated with TiN. Then the specimens in each group was bonded with polymer ceramic material (Ceramage). The shear bond strength was measured using parallel interface shearing. The interface between polymer ceramic and titanium was observed under SEM. Two samples t test was conducted with SPSS11.0 software package. The shear bond strength of TiN plating coat group was (29.78+/-0.78)MPa, larger than that of the conventional handling group (25.73+/-0.37)MPa, the difference was significant (PTiN plating coat can effectively improve the shear bond strength.

  17. Preliminary evaluation of tin plating for extracoronal restorations: evaluation of marginal quality and retention.

    Science.gov (United States)

    Ayad, M F; Rosenstiel, S F

    1998-01-01

    The influence of tin plating on marginal seating and retention of complete cast crowns was evaluated. Thirty-six standardized gold-alloy complete crowns were made on extracted human molar teeth prepared with a modified milling machine using conventional laboratory techniques. The crowns were randomly assigned to two groups according to the treatment of the fitting surface (air abraded with 50-micron aluminum oxide for 10 seconds, or tin plated with a microtin system for 3 seconds), and luted with adhesive resin cement (Panavia-EX, J. Morita). Scanning electron microscopy was used to evaluate the variables for the cast alloy. Retention was measured with an instron testing machine after thermocycling (1,500 cycles between 5 degrees C and 55 degrees C with 1 minute dwell times). Marginal adaptation was measured with a Nikon microscope before and after cementation. Results were subjected to one-way analysis of variance and Student's t test. Retention was significantly different (P tin-plated crowns. Differences for marginal seating were not statistically significant. Tin plating after air abrasion was found to be a predictable and simple technique to roughen the casting surface, increase the surface area for bonding, and significantly improve the retention of cast crowns in vivo.

  18. Fretting Wear Behavior of Tin Plated Contacts:. Influence on Contact Resistance

    Science.gov (United States)

    Park, Young Woo; Sankara Narayanan, T. S. N.; Lee, Kang Yong

    The fretting wear behavior of tin plated copper alloy contacts and its influence on the contact resistance are addressed in this paper. Based on the change in the area of contact zone as well as the wear depth as a function of fretting cycles, a model was proposed to explain the observed low and stable contact resistance. The extent of wear of tin coating and the formation of wear debris as a function of fretting cycles were assessed by scanning electron microscopy (SEM). Energy dispersive X-ray line scanning (EDX), X-ray mapping, and EDX spot analysis were employed to characterize the nature of changes that occur at the contact zone. The study reveals that the fretted area increases linearly up to 8000 cycles due to the continuous removal of the tin coating and attains saturation when the fretting path length reaches a maximum. The observed low and stable contact resistance observed up to 8000 cycles is due to the common area of contact which provides an electrically conducting area. Surface analysis by SEM, EDX, and X-ray elemental mapping elucidate the nature of changes that occurred at the contact zone. Based on the change in contact resistance as a function of fretting cycles, the fretting wear and fretting corrosion dominant regimes are proposed. The interdependence of extent of wear and oxidation increases the complexity of the fretting corrosion behavior of tin plated contacts.

  19. Silver and tin plating as medieval techniques of producing counterfeit coins and their identification by means of micro-XRF

    Science.gov (United States)

    Hložek, M.; Trojek, T.

    2017-08-01

    Archaeological surveys and metal detector prospecting yield a great amount of coins from the medieval period. Naturally, some of these are counterfeit which an experienced numismatist can determine without using chemical methods. The production of counterfeit coins in the middle ages took place in castles, caves or other remote areas where waste from this activity can still be found today - copper sheets, technical ceramics and counterfeit coins. Until recently, it has been assumed that medieval counterfeit coins are made by silver-plating copper blanks using an amalgam. However, the performed analyses reveal that there are many more techniques of counterfeiting of coins. Other techniques were based on e.g. tin amalgam plating of the blanks or alloying so-called white metal with silver-like appearance from which the coins were minted. Current chemical analyses indicate that the coins were often tinned by hot dipping with no amalgamation. Micro-X-ray fluorescence analysis has been chosen as a suitable non-destructive method to identify present chemical elements in investigated artifacts and to quantify their concentrations. In addition, a quick technique telltale the plating was applied. This technique utilizes the detected fluorescence ratio Kα/Kβ of copper, which is the main ingredient of a lot of historical metallic materials.

  20. The anticorrosion ability of titanium nitride (TiN) plating on an orthodontic metal bracket and its biocompatibility.

    Science.gov (United States)

    Kao, Chia-Tze; Ding, Shinn-Jyh; Chen, Yu-Chih; Huang, Tsui-Hsien

    2002-01-01

    Typically, an orthodontic metal bracket is made from stainless steel. It has been shown that such metal may corrode in an acid- and chloride-rich environment. The purpose of the current study was to investigate a titanium nitride (TiN) ion-plated stainless steel orthodontic bracket's anticorrosion properties and compare its biocompatibility with that of non-TiN-plated brackets. The stainless-steel brackets studied here were tested in acidic artificial saliva. The plated metal bracket was produced by the titanium nitride (TiN) ion-plating method. The TiN-plating on the bracket surface was demonstrated to be successful by EDX analysis. The quantity of metallic-ion release under test immersion solutions was analyzed by atomic absorption spectrophotometry. Both TiN- and non-TiN-plated brackets may release detectable ions into the test solution, including nickel, chromium, manganese, copper, and iron (ferric). The anticorrosion ability of the plated bracket was analyzed by means of inductively coupled plasma atomic emission spectroscopy. The results revealed that the TiN-plated metal bracket did not increase the anticorrosion ability of the standard bracket. The biocompatibility of the TiN plating versus the standard bracket material resulting from bracket immersion in the test solution revealed no toxicity on U2OS cells using a methylthiazole tetrazolium (MTT) colorimetric assay. Clearly, the search for an improved technique for enhancing the anticorrosion ability of the normal metal orthodontic bracket should be continued. Copyright 2002 Wiley Periodicals, Inc.

  1. The effect of tin on the performance of positive plates in lead/acid batteries

    Science.gov (United States)

    Culpin, B.; Hollenkamp, A. F.; Rand, D. A. J.

    There are many reports that the use of non- or low-antimonial grids in lead/acid batteries can give rise to the development of a high-impedance 'passivation' layer at the grid/active-material interface. It is generally agreed that the layer has a duplex structure that comprises α-PbO deposited directly on the grid surface beneath a compact covering of PbSO 4; basic sulfates and α-PbO 2 may also be present. The development of this structure hinders recovery from prolonged deep discharge or self-discharge. Similar phenomena can be observed with dry-charged positive plates. Passivation can also occur during cycling and float operations but, in these duties, the formation of a non-conductive layer of PbSO 4 is thought to be the prime cause of the degradation in plate performance. The incorporation of tin in the positive grid (either in the alloy itself or as a surface layer) is found to reduce the level of α-PbO and greatly alleviate passivation problems relating to charge acceptance. Various mechanisms have been proposed for this tin effect and range from a semiconductor-type doping of α-PbO to changes in the porosity of the PbSO 4 layer and/or the reactivity of α-PbO towards oxidation. The benefits of tin in cycling and float duties are less obvious and it is probable that other features of cell design are more important determinants of battery performance. The action of tin when incorporated in the positive active material requires further exploration.

  2. Enhanced uniformity in arrays of electroless plated spherical gold nanoparticles using tin presensitization.

    Science.gov (United States)

    Blake, Phillip; Ahn, Wonmi; Roper, D Keith

    2010-02-02

    Gold nanoparticle arrays created with electroless gold plating provide a unique means of transforming nanocylinders usually formed in electron beam lithography to spherical nanoparticles. Alone, electroless gold plating is not selective to the substrate and results in the formation of a gold film on all exposed surfaces of an electron beam patterned sample, including the electron resist. Undesired gold plating occurred near patterned features on the substrate surface, which was reduced by increasing post-spin-coat cure time. When the electron resist is removed, some nanocylinders break off with the gold film, leaving partial cylinders or holes in the patterned elements. By presensitizing the substrate surface with tin, gold cylinders may be selectively deposited to the substrate surface without forming a film on the electron resist. Tin presensitized arrays were produced with 47.1 +/- 7.4 nm radius gold nanoparticles with an interparticle distance of 646.0 +/- 12.4 nm. Defects from sheared, missing, and redeposited Au particles associated with the resist removal were minimized, resulting in enhanced size and shape uniformity of pillars and arrays. Hollow particles were eliminated, and relative standard deviation in particle size was reduced by 7.4% on average, while elongation was reduced 12.3% when astigmatism was eliminated.

  3. 77 FR 5767 - Certain Tin Mill Products From Japan: Rescission of Antidumping Duty Administrative Review

    Science.gov (United States)

    2012-02-06

    ... International Trade Administration Certain Tin Mill Products From Japan: Rescission of Antidumping Duty...) initiated an administrative review of the antidumping duty order covering certain tin mill products from... antidumping duty order on certain tin mill products from Japan. See Antidumping or Countervailing Duty...

  4. 77 FR 34938 - Certain Tin Mill Products From Japan: Continuation of Antidumping Duty Order

    Science.gov (United States)

    2012-06-12

    ... International Trade Administration Certain Tin Mill Products From Japan: Continuation of Antidumping Duty Order... Trade Commission (USITC) that revocation of the antidumping duty order on certain tin mill products from... Department published the antidumping duty order on certain tin mill products from Japan.\\1\\ On June 1,...

  5. Thirteen years' experience with expanded leadcalciumtin grids for automotive battery plates

    Science.gov (United States)

    Clerici, G.

    During 1977 to 1979, Magneti Marelli decided to develop an in-house expanded-metal grid technology. The metallurgy of leadcalcium alloys for strip production was investigated extensively and a continuous system was developed. Production problems were solved with machinery of proprietary design and in 1979 about a hundred thousand Fiat cars were equipped with hybrid batteries. After about three years of labour and field tests on the integral use of leadcalciumtin expanded grids, it was decided to convert the whole production (about 3 million batteries/year) to this technology.

  6. Investigation on Behavior of Macro-Particles in TiN Film by Arc Ion Plating.

    Science.gov (United States)

    Lang, W C; Gao, B; Du, H; Xiao, J O; Li, M X; Wang, X H

    2015-09-01

    Macroparticle contamination deteriorates the qualities and performances of protective coatings by arc ion plating, resulting in a limitation in their applications. In this work, the effects of transverse magnetic field (TMF), pulsed bias, gas pressure, and substrate position on behavior of the macro-particles (MPs) in TiN films are quantitatively investigated. It is demonstrated that the key factor of the deposition process on the MPs behavior is magnetic field, which controls the movement of arc spot significantly. At relatively low magnetic field intensity, the MPs behavior is greatly influenced by the other three process parameters. The sensibilities of the three parameters on MPs behavior are decreased with the increasing magnetic field intensity. At high magnetic field intensity, the MPs distribution keeps almost the same even when the other parameters are varied.

  7. 从电子脚镀锡铜针中回收锡和铜%Recovery of Tin and Copper from Electronic Foot Tin Plated Copper Needle

    Institute of Scientific and Technical Information of China (English)

    陈亮; 王勇; 熊振坤; 陈斌

    2013-01-01

    The technical study and plant practice of recovery of tin and copper from electronic foot tin plated copper needle were introduced.Tin was separated by alkaline electrolysis at room temperature without heating and electrolyte circulating.The recovery rate of copper and tin is 99.7% and 94.5% respectively under the conditions including current density of 200 A/m2,cell voltage of 0.2~0.4 V,electrolyte composition of Sn of 8~15 g/L and NaOH of 60~120 g/L.Cathode copper according with the requirements of Cu-CATH-1 brand under GB/T467-2010 standards is directly electrolyzed from polished de-tinning copper needle under the electrolysis conditions including copper needle being 5 cm higher than electrolytic liquid level,current density of 200 A/m2,cell voltage of 0.7 V,electrolyte composition of Cu of 45~50 g/L and H2SO4 of 150~180 g/L.%介绍了从电子脚镀锡铜针中回收锡和铜的工艺研究及生产实践.采用常温碱性电解脱锡,电解液无须加热循环流动,控制电流密度200 A/m2、槽电压0.2~0.4V,电解液含Sn8~15 g/L、NaOH60~120 g/L时,铜、锡的直收率分别达到99.7%和94.5%.脱锡铜针抛光处理后可以直接电解生产符合GB/T467-2010标准中Cu-CATH-1要求的阴极铜,电解条件:装填光亮铜针高出电解液面5 cm以上,电流密度200 A/m2,槽电压0.7V,电解液含Cu45~50 g/L、H2SO4150~180 g/L.

  8. 76 FR 60001 - Certain Tin Mill Products From Japan; Final Results of the Second Expedited Sunset Review of the...

    Science.gov (United States)

    2011-09-28

    ... International Trade Administration Certain Tin Mill Products From Japan; Final Results of the Second Expedited...) initiated the second sunset review of the antidumping duty order on certain tin mill products from Japan... duty order on certain tin mill products from Japan pursuant to section 751(c) of the Act....

  9. Model kekuatan geser dan kekuatan tarik perlekatan copper alloy dengan resin akrilik setelah tin plating (Tensile strength and shear strength models bonds in between copper alloy and acrylic resin after tin plating

    Directory of Open Access Journals (Sweden)

    Endanus Harijanto

    2005-09-01

    Full Text Available Tooth crown restoration was made in a complex system consisting of several elements, namely tensile strength and shear strength bond between copper alloy and acrylic resin after tin plating. The aim of this exemination was to find a model representing connection between tensile strength and shear strength in between copper alloy with acrylic resin in statistic method. In conclusion, this exemination utilizing a strength model = 0.645 + 1.237 × tensile strength resulted shear strength exemination. On the other hand, the utilization of a strength = –0.506 + 0.808 × shear strength resulted tensile strength exemination.

  10. Sandblasting and tin-plating-surface treatments to improve bonding with resin cements.

    Science.gov (United States)

    McCaughey, A D

    1993-05-01

    The superior cementation strengths of the adhesive resin cements can now be used in the dental surgery for posts, crowns and bridges and for intra-oral repairs to fractured porcelain fused to metal crowns or bridges, thanks to the availability of miniature sandblasters and portable tin-platers. The author describes the techniques involved.

  11. Effect of deposition parameters on mechanical properties of TiN films coated on 2A12 aluminum alloys by arc ion plating (AIP)

    Institute of Scientific and Technical Information of China (English)

    AWAD Samir Hamid; QIAN Han-cheng

    2005-01-01

    TiN films were deposited on 2A12 aluminum alloy by arc ion plating (AIP). The Vickers hardness of the films deposited at different bias voltages and different nitrogen gas pressures, and that of the substrate were measured. The surface roughness of the TiN films diposited at -30 V and -80 V respectively and at different nitrogen gas pressure was measured also. The mass loss of TiN films deposited at 0 V, -30 V and -80 V respectively were analyzed in dry sand rubber wheel abrasive wear tests and wet ones in comparison with uncoated Al alloy and austenitic stainless steel (AISI 316L). It is revealed that the highest hardness of the TiN film is obtained at a bias voltage of -30 V and a N2 gas pressure of 0.5 Pa. The surface roughness of the film is larger at -80 V than that at -30 V and reduces as the increase of the N2 gas pressure. The mass loss of TiN-film coated 2A12 aluminum alloy is remarkably less than that of uncoated Al alloy and also that of AISI 316L, which indicates that the abrasive wear rate is greatly reduced by the application of TiN coating. TiN coating deposited by arc ion plating (AIP) technique on aluminum alloy can be a potential coating for machine parts requiring preciseness and lightness.

  12. PLATE: Product Lifetimes And The Environment Exhibition

    OpenAIRE

    Hanson, Maria

    2015-01-01

    The PLATE (Product Lifetimes And The Environment) Exhibition explored critical themes related to how long products last in contemporary society. The topic of product longevity is examined in innovative ways through prototypes, objects, artefacts, posters, photographs and films produced by designers, social businesses, artists, researchers, lecturers and students.\\ud \\ud Featuring household products, furniture, lighting, fashion, jewellery and artworks, this collection of visual work embraced ...

  13. 化学镀锡反应动力学特性研究%Dynamic Characteristics of Electroless Tin Plating Reaction

    Institute of Scientific and Technical Information of China (English)

    杨余芳; 衷明华; 黄俊生

    2014-01-01

    ABSTRACT:Objective To study the dynamic characteristics of electroless tin plating reaction. Methods Using sodium hypophos-phite as the reducing agent, and SnCl2 as the main salt, electroless Sn was deposited on copper in the thiourea-citric acid-tartaric acid trinary ligand system. Influences of temperature, as well as the concentrations of main salt, reducing agent, hydrogenion and complexing agents on the deposition rate were investigated, respectively. Results The reaction orders of Sn2+, sodium hypophos-phite and H+ were 0. 302, 0. 192 and 0. 21,and those of thiourea, citric acid and tartaric acid were 0. 237, 0. 213 and 0. 081, re-spectively. The rate constant was 0. 013, the total reaction order was 1. 235, and the apparent activation energy was 11. 184 kJ/mol. Conclusion The kinetic equation of electroless tin plating reaction was established, which provides reference for the technology se-lection and product control in electroless tin deposition technology.%目的研究化学镀锡反应过程的动力学特性。方法在硫脲鄄柠檬酸鄄酒石酸三元络合体系中,以次磷酸钠为还原剂,以SnCl2为主盐,在铜片上化学沉积锡镀层,研究温度、主盐、还原剂、H+和络合剂的浓度对沉积速度的影响规律。结果镀锡过程中,Sn2+,H+和次磷酸钠的反应级数分别为0.302,0.21和0.192;硫脲、柠檬酸和酒石酸的反应级数分别为0.237,0.213和0.081;速度常数为0.013,总反应级数为1.235级,表观活化能为11.184kJ/mol。结论建立了化学镀锡反应的动力学方程,对化学镀锡沉积工艺的选择和产物的控制具有一定的参考作用。

  14. Compressed Air System Improvements Increase Production at a Tin Mill (Weirton Plant)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2000-12-01

    In 1999, Weirton Steel completed a project in which the compressed air system at their tin mill in Weirton, West Virginia was completely overhauled. The installation of new compressors, the addition of air treatment equipment, and the repair of leaks significantly reduced compressor shutdowns, production downtime, and product rejects.

  15. Ion-chromatographic determination of chloride and fluoride in electrolyte from the halogen tin-plating process.

    Science.gov (United States)

    Korth, W; Ellis, J

    1984-06-01

    A simple and rapid procedure is proposed for the determination of chloride and free fluoride in tin electroplating fluid. Suppressor-column ion-chromatography is used after oxidation of hexafluorostannate(II) to hexafluorostannate(IV) with hydrogen peroxide. Concurrent determination of tin(II) and total tin then allows calculation of the concentrations of fluoride, hexafluorostannate(II) and hexafluorostannate(IV).

  16. Tensile bond strength of resin-modified glass-ionomer cement to microabraded and silica-coated or tin-plated high noble ceramic alloy.

    Science.gov (United States)

    Swartz, J M; Davis, R D; Overton, J D

    2000-12-01

    The purpose of this study was to evaluate the influence of alloy surface microabrasion, silica coating, or microabrasion plus tin plating on the tensile bond strengths between a resin-modified glass-ionomer luting cement and a high-noble alloy. Bond strength between the microabraded alloy specimens and conventional glass-ionomer cement or resin cement were included for comparison. One hundred twenty uniform size, disk-shaped specimens were cast in a noble metal alloy and divided into 6 groups (n = 10 pairs/group). The metal surfaces of the specimens in each group were treated and cemented as follows. Group 1: No surface treatment (as cast, control), cemented with a resin-modified glass-ionomer cement. Group 2: Microabrasion with 50-microm aluminum oxide particles, resin-modified glass-ionomer cement. Group 3: A laboratory microabrasion and silica coating system, resin-modified glass-ionomer cement. Group 4: Microabrasion and tin-plating, resin-modified glass-ionomer cement. Group 5: Microabrasion only, conventional glass-ionomer cement. Group 6: Microabrasion and tin-plating, conventional resin cement. The uniaxial tensile bond strength for each specimen pair was determined using an Instron Universal Testing Machine (Instron Corp, Canton, MA). Results were analyzed using a one-way analysis of variance (alpha = 0.05) and a Tukey post-hoc analysis. Mean bond strength: Group 1: 3.6 (+/- 1.5) MPa. Group 2: 4.2 (+/-0.5) MPa. Group 3: 6.7 (+/- 0.9) MPa. Group 4: 10.6 (+/- 1.8) MPa. Group 5: 1.1 (+/- 0.4) MPa. Group 6: 14.6 (+/- 2.3) MPa. Group 6 was significantly stronger than Group 4. The bond strength of specimens cemented with the resin-modified glass-ionomer cement using microabrasion and tin-plating (Group 4) was significantly stronger than all other groups except the resin cement with microabrasion and tin-plating (Group 6). Microabraded and tin-plated alloy specimens luted with the resin-modified glass-ionomer cement resulted in the greatest mean tensile strengths

  17. Application of a focused ion beam mill to the characterisation of a microstructure in tin plating on a Fe 42wt% Ni substrate.

    Science.gov (United States)

    Kuwano, Noriyuki; Jia-Yu; Tajima, Ryota; Koga, Shin-ichi; Tsukamoto, Shuya; Ohno, Yasuhide

    2004-01-01

    The application of a focused ion beam (FIB) mill equipped with a microsampling unit to a tin-plated specimen was reported briefly. Tin-plating has a serious problem: Whiskers are liable to grow on the surface of tinplates. In order to clarify the mechanism of the whisker growth, detail characterisation is conducted using transmission electron microscopy (TEM). However, it is difficult to prepare specimens for TEM observation without the influences of mechanical damages. It was demonstrated that FIB etching was successfully used to observe a three-dimensional microstructure by scanning ion microscopy (FIB-imaging) and to prepare thin films for TEM observation. The observation has revealed the formation of precipitates of Ni(3)Sn(4) that is considered to be strongly related to the whisker growth.

  18. The case of tin-plating of surface mounted glass diodes

    NARCIS (Netherlands)

    Wieringa, J.E.

    1998-01-01

    New product development is one of the most powerful but difficult activities in business. It is also a very important factor affecting final product quality. There are many techniques available for new product development. Experimental design is now regarded as one of the most significant

  19. The case of tin-plating of surface mounted glass diodes

    NARCIS (Netherlands)

    Wieringa, J.E.

    1998-01-01

    New product development is one of the most powerful but difficult activities in business. It is also a very important factor affecting final product quality. There are many techniques available for new product development. Experimental design is now regarded as one of the most significant techniques

  20. High-space resolution imaging plate analysis of extreme ultraviolet (EUV) light from tin laser-produced plasmas.

    Science.gov (United States)

    Musgrave, Christopher S A; Murakami, Takehiro; Ugomori, Teruyuki; Yoshida, Kensuke; Fujioka, Shinsuke; Nishimura, Hiroaki; Atarashi, Hironori; Iyoda, Tomokazu; Nagai, Keiji

    2017-03-01

    With the advent of high volume manufacturing capabilities by extreme ultraviolet lithography, constant improvements in light source design and cost-efficiency are required. Currently, light intensity and conversion efficiency (CE) measurments are obtained by charged couple devices, faraday cups etc, but also phoshpor imaging plates (IPs) (BaFBr:Eu). IPs are sensitive to light and high-energy species, which is ideal for studying extreme ultraviolet (EUV) light from laser produced plasmas (LPPs). In this work, we used IPs to observe a large angular distribution (10°-90°). We ablated a tin target by high-energy lasers (1064 nm Nd:YAG, 10(10) and 10(11) W/cm(2)) to generate the EUV light. The europium ions in the IP were trapped in a higher energy state from exposure to EUV light and high-energy species. The light intensity was angular dependent; therefore excitation of the IP depends on the angle, and so highly informative about the LPP. We obtained high-space resolution (345 μm, 0.2°) angular distribution and grazing spectrometer (5-20 nm grate) data simultaneously at different target to IP distances (103 mm and 200 mm). Two laser systems and IP types (BAS-TR and BAS-SR) were also compared. The cosine fitting values from the IP data were used to calculate the CE to be 1.6% (SD ± 0.2) at 13.5 nm 2% bandwidth. Finally, a practical assessment of IPs and a damage issue are disclosed.

  1. High-space resolution imaging plate analysis of extreme ultraviolet (EUV) light from tin laser-produced plasmas

    Science.gov (United States)

    Musgrave, Christopher S. A.; Murakami, Takehiro; Ugomori, Teruyuki; Yoshida, Kensuke; Fujioka, Shinsuke; Nishimura, Hiroaki; Atarashi, Hironori; Iyoda, Tomokazu; Nagai, Keiji

    2017-03-01

    With the advent of high volume manufacturing capabilities by extreme ultraviolet lithography, constant improvements in light source design and cost-efficiency are required. Currently, light intensity and conversion efficiency (CE) measurments are obtained by charged couple devices, faraday cups etc, but also phoshpor imaging plates (IPs) (BaFBr:Eu). IPs are sensitive to light and high-energy species, which is ideal for studying extreme ultraviolet (EUV) light from laser produced plasmas (LPPs). In this work, we used IPs to observe a large angular distribution (10°-90°). We ablated a tin target by high-energy lasers (1064 nm Nd:YAG, 1010 and 1011 W/cm2) to generate the EUV light. The europium ions in the IP were trapped in a higher energy state from exposure to EUV light and high-energy species. The light intensity was angular dependent; therefore excitation of the IP depends on the angle, and so highly informative about the LPP. We obtained high-space resolution (345 μm, 0.2°) angular distribution and grazing spectrometer (5-20 nm grate) data simultaneously at different target to IP distances (103 mm and 200 mm). Two laser systems and IP types (BAS-TR and BAS-SR) were also compared. The cosine fitting values from the IP data were used to calculate the CE to be 1.6% (SD ± 0.2) at 13.5 nm 2% bandwidth. Finally, a practical assessment of IPs and a damage issue are disclosed.

  2. Corrosion resistance of siloxane–poly(methyl methacrylate) hybrid films modified with acetic acid on tin plate substrates: Influence of tetraethoxysilane addition

    Energy Technology Data Exchange (ETDEWEB)

    Kunst, S.R.; Cardoso, H.R.P. [LAPEC, Federal University of Rio Grande do Sul – UFRGS, Avenida Bento Gonçalves, 9500 Porto Alegre, RS (Brazil); Oliveira, C.T. [ICET, University Feevale, RS-239, 2755 Novo Hamburgo, RS (Brazil); Santana, J.A.; Sarmento, V.H.V. [Department of Chemistry, Federal University of Sergipe – UFS, Av. Vereador Olímpio Grande s/n, Centro, Itabaiana, SE (Brazil); Muller, I.L. [LAPEC, Federal University of Rio Grande do Sul – UFRGS, Avenida Bento Gonçalves, 9500 Porto Alegre, RS (Brazil); Malfatti, C.F., E-mail: celia.malfatti@ufrgs.br [LAPEC, Federal University of Rio Grande do Sul – UFRGS, Avenida Bento Gonçalves, 9500 Porto Alegre, RS (Brazil)

    2014-04-01

    Highlights: • Siloxane–PMMA film was produced by dip-coating on tin plate substrate. • It was evaluated the influence of (TEOS) addition on siloxane–PMMA hybrid films. • Siloxane–PMMA films without TEOS presented a regular coverage and lowest roughness. • The TEOS addition decrease the corrosion resistance of siloxane–PMMA films. • Siloxane–PMMA without TEOS presented is higher durability in the film wear test. - Abstract: The aim of this paper is to study the corrosion resistance of hybrid films. Tin plate was coated with a siloxane–poly (methyl methacrylate) (PMMA) hybrid film prepared by sol–gel route with covalent bonds between the organic (PMMA) and inorganic (siloxane) phases obtained by hydrolysis and polycondensation of 3-(trimethoxysilylpropyl) methacrylate (TMSM) and polymerization of methyl methacrylate (MMA) using benzoyl peroxide (BPO) as a thermic initiator. Hydrolysis reactions were catalyzed by acetic acid solution avoiding the use of chlorine or stronger acids in the film preparation. The effect of the addition of tetraethoxysilane (TEOS) on the protective properties of the film was evaluated. The hydrophobicity of the film was determined by contact angle measurements, and the morphology was evaluated by scanning electron microscopy (SEM) and profilometry. The local nanostructure was investigated by Fourier transform infrared spectroscopy (FT-IR). The electrochemical behavior of the films was assessed by open circuit potential monitoring, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements in a 0.05 M NaCl solution. The mechanical behavior was evaluated by tribology. The results highlighted that the siloxane–PMMA hybrid films modified with acetic acid are promising anti-corrosive coatings that acts as an efficient diffusion barrier, protecting tin plates against corrosion. However, the coating properties were affected by the TEOS addition, which contributed for the thickness increase

  3. EXPERIMENTAL STUDY ON SUPERFICIAL COAT OF GEARS OF NITRIDED 32Cr2MoV COATED WITH TiN FILM BY MULTI-ARC ION PLATING

    Institute of Scientific and Technical Information of China (English)

    LI Hui; LI Runfang; XU Hongbin; ZHANG Jin

    2007-01-01

    After 32CrMoV is selected to manufacture nitrided gears coated with TiN by multi-arc ion plating, all of these uncoated gears and coated gears run in the gearbox under the same initial conditions so as to compare their difference concerning properties and microstructure. Experiment results indicate that tooth surface of the coated-TiN gears does not suffer surface abnormalities in meshed zone. Instead, the gears with nitrided case exhibit an abrasion mark on the meshed zone of tooth surface, which results in more weight loss of nitrided gears. The morphology of the surface suggests TiN film with more than 2000 HV is so dense and smooth that coated-TiN gears have higher wear resistance compared with the uncoated gears. The microstructure of coated-TiN gears is finer, hardness is higher and its distribution of coated-TiN gears is more reliable than uncoated ones, which makes nitride layer combined with TiN film tightly. Consequently, the wear-resistance of gears has been dramatically promoted.

  4. Corrosion resistance of siloxane-poly(methyl methacrylate) hybrid films modified with acetic acid on tin plate substrates: Influence of tetraethoxysilane addition

    Science.gov (United States)

    Kunst, S. R.; Cardoso, H. R. P.; Oliveira, C. T.; Santana, J. A.; Sarmento, V. H. V.; Muller, I. L.; Malfatti, C. F.

    2014-04-01

    The aim of this paper is to study the corrosion resistance of hybrid films. Tin plate was coated with a siloxane-poly (methyl methacrylate) (PMMA) hybrid film prepared by sol-gel route with covalent bonds between the organic (PMMA) and inorganic (siloxane) phases obtained by hydrolysis and polycondensation of 3-(trimethoxysilylpropyl) methacrylate (TMSM) and polymerization of methyl methacrylate (MMA) using benzoyl peroxide (BPO) as a thermic initiator. Hydrolysis reactions were catalyzed by acetic acid solution avoiding the use of chlorine or stronger acids in the film preparation. The effect of the addition of tetraethoxysilane (TEOS) on the protective properties of the film was evaluated. The hydrophobicity of the film was determined by contact angle measurements, and the morphology was evaluated by scanning electron microscopy (SEM) and profilometry. The local nanostructure was investigated by Fourier transform infrared spectroscopy (FT-IR). The electrochemical behavior of the films was assessed by open circuit potential monitoring, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements in a 0.05 M NaCl solution. The mechanical behavior was evaluated by tribology. The results highlighted that the siloxane-PMMA hybrid films modified with acetic acid are promising anti-corrosive coatings that acts as an efficient diffusion barrier, protecting tin plates against corrosion. However, the coating properties were affected by the TEOS addition, which contributed for the thickness increase and irregular surface coverage.

  5. Biodegradation of Tributyltin (TBT) by Extremophile Bacteria from Atacama Desert and Speciation of Tin By-products.

    Science.gov (United States)

    Yáñez, Jorge; Riffo, Paula; Santander, Paola; Mansilla, Héctor D; Mondaca, María Angélica; Campos, Víctor; Amarasiriwardena, Dulasiri

    2015-07-01

    Biodegradation of tributyltin (TBT) by four tin resistant Gram negative bacteria isolated from extremely contaminated river sediments in the Atacama Desert in Chile was studied. Moraxella osloensis showed the greatest resistance and degradation capability of TBT, producing less toxic by-products, such as dibutyltin (DBT) and inorganic tin. In 7 days, approximately 80 % of TBT degradation was achieved, generating close to 20 % of DBT as degradation product. The degradation rate constant (k) was 0.022 [day(-1)] and TBT half-life (t1/2) in culture was 4.3 days. Debutylation is stated a probable mechanism of TBT degradation.

  6. Influence of Direct Current Electric Field on Corrosion Behavior of Tin Under a Thin Electrolyte Layer

    Science.gov (United States)

    Huang, H. L.; Bu, F. R.; Tian, J.; Liu, D.

    2017-08-01

    The influence of a direct current electric field (DCEF) on corrosion behavior of tin under a thin electrolyte layer was investigated based on an array electrode technology by polarization, electrochemical impedance spectroscopy and surface analysis. The experimental results indicate that the corrosion rate of tin near the positive plate of DCEF increases with increased electric field intensity, which could be attributed to the acceleration of the migration of ions, the removal of corrosion products under DCEF and the damage of tin surface oxide film. Furthermore, tin at different positions in a DCEF exhibits different corrosion behavior, which could be ascribed to the difference of the local corrosion environment caused by the DCEF.

  7. Influence of current density on surface morphology and properties of pulse plated tin films from citrate electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ashutosh; Bhattacharya, Sumit; Das, Siddhartha; Das, Karabi, E-mail: karabi@metal.iitkgp.ernet.in

    2014-01-30

    Bulk polycrystalline tin films have been processed by pulse electrodeposition technique from a simple solution containing triammonium citrate and stannous chloride. The cathodic investigations have been carried out by galvanostatic methods. As deposited samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). XRD analysis of the deposited films shows microcrystalline grains having β-Sn form. The surface morphology is very rough at lower current density, but becomes smooth at higher current density, and exhibits pyramid type morphology at all the current densities. The effect of current density on microhardness, melting behavior, and electrical resistivity are also reported here.

  8. Conflict minerals in the compute sector: estimating extent of tin, tantalum, tungsten, and gold use in ICT products.

    Science.gov (United States)

    Fitzpatrick, Colin; Olivetti, Elsa; Miller, Reed; Roth, Richard; Kirchain, Randolph

    2015-01-20

    Recent legislation has focused attention on the supply chains of tin, tungsten, tantalum, and gold (3TG), specifically those originating from the eastern part of the Democratic Republic of Congo. The unique properties of these so-called “conflict minerals” lead to their use in many products, ranging from medical devices to industrial cutting tools. This paper calculates per product use of 3TG in several information, communication, and technology (ICT) products such as desktops, servers, laptops, smart phones, and tablets. By scaling up individual product estimates to global shipment figures, this work estimates the influence of the ICT sector on 3TG mining in covered countries. The model estimates the upper bound of tin, tungsten, tantalum, and gold use within ICT products to be 2%, 0.1%, 15%, and 3% of the 2013 market share, respectively. This result is projected into the future (2018) based on the anticipated increase in ICT device production.

  9. Effect of Sample Configuration on Droplet-Particles of TiN Films Deposited by Pulse Biased Arc Ion Plating

    Institute of Scientific and Technical Information of China (English)

    Yanhui Zhao; Guoqiang Lin; Jinquan Xiao; Chuang Dong; Lishi Wen

    2009-01-01

    Orthogonal experiments are used to design the pulsed bias related parameters, including bias magnitude, duty cycle and pulse frequency, during arc ion deposition of TiN films on stainless steel substrates in the case of samples placing normal to the plasma flux. The effect of these parameters on the amount and the size distribution of droplet-particles are investigated, and the results have provided sufficient evidence for the physical model, in which particles reduction is due to the case that the particles are negatively charged and repulsed from negative pulse electric field. The effect of sample configuration on amount and size distribution of the particles are analyzed. The results of the amount and size distribution of the particles are compared to those in the case of samples placing parallel to the plasma flux.

  10. 带钢镀锡生产中的电解酸洗%Study on Electrolytic Pickling Process for Strip Steel in Tin Plating

    Institute of Scientific and Technical Information of China (English)

    刘洪波; 吴健

    2012-01-01

    The mechanism of electrolytic pickling for strip steel in tin plating was analyzed, the factors of electro- lytic pickling such as electrolysis plate and electrolytic pickling process parameters were studied. The results indicated that increase of protection measures by Pb-Ca-Sn positive electrode, electrolyte temperature 40℃, sulfuric acid concentration70 g/l, and current density 10 c/dm2 conditions could gain better effects for electrolytic pickling.%在分析低碳冷轧带钢酸洗机理的基础上,研究了低碳带钢电解酸洗的影响因素(电解极板及电解工艺参数),研究表明:对Pb—Ca-Sn酸洗阳极增加保护措施及采用酸洗温度40℃、酸液浓度70g/L、电流密度10c/dm^2的电解工艺参数可得到较好的酸洗效果。

  11. Salmonella and eggs: from production to plate.

    Science.gov (United States)

    Whiley, Harriet; Ross, Kirstin

    2015-02-26

    Salmonella contamination of eggs and egg shells has been identified as a public health concern worldwide. A recent shift in consumer preferences has impacted on the egg industry, with a push for cage-free egg production methods. There has also been an increased desire from consumers for raw and unprocessed foods, potentially increasing the risk of salmonellosis. In response to these changes, this review explores the current literature regarding Salmonella contamination of eggs during the production processing through to food handling protocols. The contamination of eggs with Salmonella during the production process is a complex issue, influenced by many variables including flock size, flock age, stress, feed, vaccination, and cleaning routines. Currently there is no consensus regarding the impact of caged, barn and free range egg production has on Salmonella contamination of eggs. The literature regarding the management and control strategies post-collection, during storage, transport and food handling is also reviewed. Pasteurisation and irradiation were identified as the only certain methods for controlling Salmonella and are essential for the protection of high risk groups, whereas control of temperature and pH were identified as potential control methods to minimise the risk for foods containing raw eggs; however, further research is required to provide more detailed control protocols and education programs to reduce the risk of salmonellosis from egg consumption.

  12. Salmonella and Eggs: From Production to Plate

    Directory of Open Access Journals (Sweden)

    Harriet Whiley

    2015-02-01

    Full Text Available Salmonella contamination of eggs and egg shells has been identified as a public health concern worldwide. A recent shift in consumer preferences has impacted on the egg industry, with a push for cage-free egg production methods. There has also been an increased desire from consumers for raw and unprocessed foods, potentially increasing the risk of salmonellosis. In response to these changes, this review explores the current literature regarding Salmonella contamination of eggs during the production processing through to food handling protocols. The contamination of eggs with Salmonella during the production process is a complex issue, influenced by many variables including flock size, flock age, stress, feed, vaccination, and cleaning routines. Currently there is no consensus regarding the impact of caged, barn and free range egg production has on Salmonella contamination of eggs. The literature regarding the management and control strategies post-collection, during storage, transport and food handling is also reviewed. Pasteurisation and irradiation were identified as the only certain methods for controlling Salmonella and are essential for the protection of high risk groups, whereas control of temperature and pH were identified as potential control methods to minimise the risk for foods containing raw eggs; however, further research is required to provide more detailed control protocols and education programs to reduce the risk of salmonellosis from egg consumption.

  13. Study of arsenopyrite weathering products in mine wastes from abandoned tungsten and tin exploitations

    Energy Technology Data Exchange (ETDEWEB)

    Murciego, A. [Department of Geology, Plza. de los Caidos s/n. Salamanca University, 37008 Salamanca (Spain); Alvarez-Ayuso, E., E-mail: esther.alvarez@irnasa.csic.es [Department of Environmental Geochemistry, IRNASA (CSIC), Apdo. 257, 37071 Salamanca (Spain); Pellitero, E. [Department of Geology, Plza. de los Caidos s/n. Salamanca University, 37008 Salamanca (Spain); Rodriguez, M.A. [Faculty of Sciences, Crystallography and Mineralogy Area, Avd. Elvas s/n. Extremadura University, 06071 Badajoz (Spain); Garcia-Sanchez, A. [Department of Environmental Geochemistry, IRNASA (CSIC), Apdo. 257, 37071 Salamanca (Spain); Tamayo, A.; Rubio, J.; Rubio, F. [Ceramic and Glass Institute (CSIC), c/Kelsen, 5, 28049 Cantoblanco, Madrid (Spain); Rubin, J. [Material Science Institute of Aragon, CSIC-Zaragoza University, c/Maria de Luna 3, 50009 Zaragoza (Spain)

    2011-02-15

    Arsenopyrite-rich wastes from abandoned tungsten and tin exploitations were studied to determine the composition and characteristics of the secondary phases formed under natural weathering conditions so as to assess their potential environmental risk. Representative weathered arsenopyrite-bearing rock wastes collected from the mine dumps were analysed using the following techniques: X-ray powder diffraction (XRD) analysis, polarizing microscopy analysis, electron microprobe analysis (EMPA) and microRaman and Moessbauer spectroscopies. Scorodite, pharmacosiderite and amorphous ferric arsenates (AFA) with Fe/As molar ratios in the range 1.2-2.5 were identified as secondary arsenic products. The former showed to be the most abundant and present in the different studied mining areas. Its chemical composition showed to vary in function of the original surrounding rock mineralogy in such a way that phosphoscorodite was found as the mineral variety present in apatite-containing geoenvirons. Other ever-present weathering phases were goethite and hydrous ferric oxides (HFO), displaying, respectively, As retained amounts about 1 and 20% (expressed as As{sub 2}O{sub 5}). The low solubility of scorodite, the relatively low content of AFA and the formation of compounds of variable charge, mostly of amorphous nature, with high capacity to adsorb As attenuate importantly the dispersion of this element into the environment from these arsenopyrite-bearing wastes.

  14. The effect of urea on microstructures of tin dioxide grown on Ti plate and its supercapacitor performance

    Science.gov (United States)

    Jinlong, Lv; Meng, Yang; Miura, Hideo

    2017-02-01

    The effects of urea on microstructures of SnO2 during hydrothermal process and its supercapacitor performance were investigated. The sphere SnO2 was formed on Ti plate in hydrothermal solution without urea, while the SnO2 micro-flowers were assembled by numerous few-layered nanopetals due to adding to urea during hydrothermal process. The separated SnO2 nanopetals arrays showed better electrochemical performance than sphere SnO2. The gap between SnO2 nanopetals promoted penetration of the electrolyte and induced high supercapacitive performance.

  15. Plating procedure for the enumeration of coliforms from dairy products.

    Science.gov (United States)

    Ray, B; Speck, M L

    1978-04-01

    A "repair-detection" procedure consisting of pour plating of food samples with Trypticase soy agar, followed by 1-h repair incubation at room temperature and subsequent overlay with violet red bile agar, was found to be an effective method for the detection of injuried and uninjuried coliforms from dairy products. This method was relatively less effective for the detection of coliforms in many semipreserved foods as compared with dairy products, but more effective than the most-probable-number method.

  16. Pulmonary toxicity of indium-tin oxide production facility particles in rats

    Science.gov (United States)

    Badding, Melissa A.; Fix, Natalie R.; Orandle, Marlene S.; Barger, Mark W.; Dunnick, Katherine M.; Cummings, Kristin J.; Leonard, Stephen S.

    2016-01-01

    Indium-tin oxide (ITO) is used to make transparent conductive coatings for touch-screen and liquid crystal display electronics. Occupational exposures to potentially toxic particles generated during ITO production have increased in recent years as the demand for consumer electronics continues to rise. Previous studies have demonstrated cytotoxicity in vitro and animal models have shown pulmonary inflammation and injury in response to various indium-containing particles. In humans, pulmonary alveolar proteinosis (PAP) and fibrotic interstitial lung disease have been observed in ITO facility workers. However, which indium materials or specific processes in the workplace may be the most toxic to workers is unknown. Here we examined the pulmonary toxicity of three different particle samples that represent real-life worker exposures, as they were collected at various production stages throughout an ITO facility. Indium oxide (In2O3), sintered ITO (SITO) and ventilation dust (VD) particles each caused pulmonary inflammation and damage in rats over a time course (1, 7 and 90 days post-intratracheal instillation), but SITO and VD appeared to induce greater toxicity in rat lungs than In2O3 at a dose of 1 mg per rat. Downstream pathological changes such as PAP and fibrosis were observed in response to all three particles 90 days after treatment, with a trend towards greatest severity in animals exposed to VD when comparing animals that received the same dose. These findings may inform workplace exposure reduction efforts and provide a better understanding of the pathogenesis of an emerging occupational health issue. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. PMID:26472246

  17. Galvanic couples of 316L steel with Ti and ion plated Ti and TiN coatings in Ringer's solutions.

    Science.gov (United States)

    Gluszek, J; Jedrkowiak, J; Markowski, J; Masalski, J

    1990-07-01

    Steel 316L was coated with titanium or titanium nitride by ion plating. The tightness of the coatings was examined electro-chemically. The galvanic effects for the galvanic couples steel-titanium, steel-titanium-coated steel and steel-titanium nitride-coated steel were studied. It was found that both titanium and titanium nitride coatings were non-porous in Ringer's solution; titanium served as an anode in the couple steel-titanium; it was oxidized according to the logarithmic law. For the other two couples, the coatings were the cathodes. The rate of dissolution of steel in these couples, was however, smaller than expected, owing to a strong polarization of the coatings. The potential of the couple was similar to that of steel.

  18. 多弧离子镀TiN涂层的N2/Ar流量参数研究%Study on N2/Ar flow parameters of TiN coating deposited by multi-arc ion plating

    Institute of Scientific and Technical Information of China (English)

    陈昌浩; 金永中; 陈建; 蔡瑜; 余学金; 龙国俊

    2016-01-01

    TiN coating was deposited on the surface of cemented carbide substrate by multi-arc ion plating. The influ-ence of N2/Ar flow rate on the distribution of microparticles (MPs) and mechanical properties of TiN coating was stud-ied. The surface morphologies of TiN film were observed by scanning electron microscope. The amount and size of MPs were analyzed by ImageJ software. Scratch spectrometer and nanoindenter were used to evaluate mechanical properties of TiN coating. The results show that the maximum size and average diameter of MPs decrease with the increase of N2 flow,and the adhesion strength of TiN coating goes up,while the micro-hardness of TiN coating increases firstly and then decreases.%利用多弧离子镀在硬质合金基体上制备TiN涂层,研究了N2/Ar流量比对TiN涂层表面大颗粒分布与力学性能的影响。通过扫描电镜观察TiN涂层的表面形貌,并利用ImageJ图像处理软件对大颗粒的数量和尺寸进行了分析,通过自动划痕仪和纳米压痕仪对涂层的力学性能进行表征。结果表明:随着N2流量的增加,涂层表面沉积颗粒的最大直径和平均直径逐渐减小,涂层的附着力整体呈现增加趋势,显微硬度则先增大后减小。

  19. Photovoltaic semiconductor materials based on alloys of tin sulfide, and methods of production

    Energy Technology Data Exchange (ETDEWEB)

    Lany, Stephan

    2016-06-07

    Photovoltaic thin-film materials comprising crystalline tin sulfide alloys of the general formula Sn.sub.1-x(R).sub.xS, where R is selected from magnesium, calcium and strontium, as well as methods of producing the same, are disclosed.

  20. Kinetics study of Jatropha oil esterification with ethanol in the presence of tin (II) chloride catalyst for biodiesel production

    Science.gov (United States)

    Kusumaningtyas, Ratna Dewi; Ratrianti, Naomi; Purnamasari, Indah; Budiman, Arief

    2017-01-01

    Jatropha oil is one of the promising feedstocks for biodiesel production. Jatropha oil is non-edible oil hence utilization of this oil would not compete with the needs of food. However, crude jatropha oil usually has high free fatty acid (FFA) content. Due to this fact, direct alkaline-catalyzed transesterification of crude jatropha oil for biodiesel production cannot be performed. FFA in crude jatropha oil will react with a base catalyst, resulting in soap as by product and hindering methyl ester (biodiesel) production. Therefore, prior to a transesterification reaction, it is crucial to run a pretreatment step of jatropha oil which can lower the FFA content in the oil. In this work, the pretreatment process was conducted through the esterification reaction of FFA contained in crude jatropha oil with ethanol over tin (II) chloride catalyst to reduce the acid value of the feedstock. The feedstock was Indonesia crude jatropha oil containing 12.03% of FFA. The esterification reaction was carried out in a batch reactor with a molar ratio of FFA to ethanol was 1:60 and total reaction time was 180 minutes. Tin (II) chloride catalyst was varied at 2.5, 5, 7.5, and 10% wt, whereas the effect of the reaction temperature was studied at 35, 34, 55, and 65 °C. The best reaction conversion was 71.55%, achieved at the following condition: a reaction temperature of 65 °C, catalyst concentration of 10% wt, the reaction time of 180 min, and the molar ratio of FFA to ethanol was 1:60. Kinetics study was also conducted in this work. It was found that esterification reaction of jatropha oil FFA with ethanol catalyzed by tin(II) chloride fitted the first-order pseudo-homogeneous kinetics model. It was also revealed that the frequency factor (A) and the activation energy (Ea) were 4.3864 × 106 min-1 and 56.2513 kJ/mole, respectively.

  1. 78 FR 31577 - Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan

    Science.gov (United States)

    2013-05-24

    ...)] Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan Determination On the basis of the... reason of imports from Japan of diffusion-annealed, nickel-plated flat-rolled steel products, provided... diffusion-annealed, nickel-plated flat-rolled steel products from Japan. Accordingly, effective March...

  2. Production of amorphous tin oxide thin films and microstructural transformation induced by heat treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Z.W.; Lai, J.K.L.; Shek, C.H.; Chen, H.D. [City University of Hong Kong, Department of Physics and Materials Science, Kowloon Tong, Hong Kong (China)

    2005-10-01

    X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and high resolution transmission electron microscopy were used to study tin oxide thin films deposited on Si(100) substrates at room temperature using pulsed laser deposition techniques with a sintered cassiterite SnO{sub 2} target and subsequently heat-treated. X-ray diffraction and scanning electron microscopy results demonstrated that the as-prepared thin films consisted of an amorphous matrix as well as plume-like features, which are shown many micropores. The thin films that were heat treated for 2 h at 150 C had tetragonal rutile nanocrystalline SnO{sub 2} structures. The microstructural evolution of the tin oxide thin films during the heat treatment is discussed in the paper. (orig.)

  3. Production of multifilamentary Nb/sub 3/Sn composites incorporating a high tin bronze

    Energy Technology Data Exchange (ETDEWEB)

    Petrovich, A.; Zeithlin, B.A.; Walker, M.S.

    1977-01-01

    The economics and processing methods have been examined for the fabrication of multifilamentary Nb/sub 3/Sn using a high tin bronze reactive matrix. Four conductor configurations utilizing the high tin bronze were compared with a conventional Cu-13 wt % Sn bronze. The most promising of these designs is potentially 40% lower in cost per ampere meter than the conventional composite. Large hydrostatic extrusion facilities, which are required for the high tin processing, are not presently available in this country but can be made by conversion of conventional presses. They exist in Europe. Experiments were conducted to investigate the applicability of hydrostatic extrusion, and billet components were successfully prepared using the hydrostatic extrusion technique. We have concluded that the economics, availability of facilities and initial fabrication results are favorable for this type of conductor and that the next stage in this program of scale up to extrusion and drawing of 2'' to 3'' diameter composite billets should be undertaken.

  4. Pilot Production of Large Area Microchannel Plates and Picosecond Photodetectors

    Science.gov (United States)

    Minot, M.; Adams, B.; Abiles, M.; Bond, J.; Craven, C.; Cremer, T.; Foley, M.; Lyashenko, A.; Popecki, M.; Stochaj, M.; Worstell, W.; Elam, J.; Mane, A.; Siegmund, O.; Ertley, C.

    2016-09-01

    Pilot production performance is reported for large area atomic layer deposition (ALD) coated microchannel plates (ALD-GCA-MCPs) and for Large Area Picosecond Photodetectors (LAPPD™) which incorporate them. "Hollowcore" glass capillary array (GCA) substrates are coated with ALD resistive and emissive layers to form the ALDGCA- MCPs, an approach that facilitates independent selection of glass substrates that are mechanically stronger and that have lower levels of radioactive alkali elements compared to conventional MCP lead glass, reducing background noise[1,2,3,4]. ALD-GCA-MCPs have competitive gain ( 104 each or 107 for a chevron pair ), enhanced lifetime and gain stability (7 C cm-2 of charge extraction), reduced background levels (0.028 events cm-2 sec-1) and low gamma-ray detection efficiency. They can be fabricated in large area (20cm X 20 cm) planar and curved formats suitable for use in high radiation environment applications, including astronomy, space instrumentation, and remote night time sensing. The LAPPD™ photodetector incorporates these ALD-GCA-MCPs in an all-glass hermetic package with top and bottom plates and sidewalls made of borosilicate float glass. Signals are generated by a bi-alkali Na2KSb photocathode, amplified with a stacked chevron pair of ALD-GCA-MCPs. Signals are collected on RF strip-line anodes integrated into to the bottom plates which exit the detector via pin-free hermetic seals under the side walls [5]. Tests show that LAPPDTMs have electron gains greater than 107, submillimeter spatial resolution for large (multiphoton) pulses and several mm for single photons, time resolution less than 50 picoseconds for single photons, predicted resolution less than 5 picoseconds for large pulses, high stability versus charge extraction[6], and good uniformity for applications including astrophysics, neutron detection, high energy physics Cherenkov light detection, and quantum-optical photon-correlation experiments.

  5. Construction of spongy antimony-doped tin oxide/graphene nanocomposites using commercially available products and its excellent electrochemical performance

    Science.gov (United States)

    Zhao, Xiaowei; Zhang, Jingwei; Zhang, Jiwei; Gong, Chunhong; Gu, Xiufang; Ma, Zhihua; Zhou, Jingfang; Yu, Laigui; Zhang, Zhijun

    2015-10-01

    We construct successfully a porous antimony-doped tin oxide (ATO)/nitrogen-doped graphene 3-dimensional (3D) frameworks (denoted as ATO/NG/TEPA; TEPA refers to tetraethylenepentamine) by a one-pot hydrothermal process, with which TEPA aqueous solution is adopted to easily re-disperse commercial ATO precursor forming a transparent hydrosol. The results show that TEPA plays a key role in the construction of ATO/NG/TEPA, not only acting as a peptization reagent to re-disperse ATO precursor nanoparticles, and as a linker to combine ATO with graphene sheets. The as-fabricated ATO/NG/TEPA hybrid as the negative electrode of lithium ion batteries exhibits excellent lithium storage capacity and cycling stability. With the advantage of easily re-dispersing commercial ATO, the present synthetic route may be put into use for the large-scale production of the titled nanocomposites as the anode material of lithium ion batteries.

  6. Size Effects on the Entropy Production in Oscillatory Flow between Parallel Plates

    Directory of Open Access Journals (Sweden)

    Sac Medina

    2011-02-01

    Full Text Available The heat transfer problem of a zero-mean oscillatory flow of a Maxwell fluid between infinite parallel plates with boundary conditions of the third kind is considered. The local and global time-averaged entropy production are computed, and the consequences of convective cooling of the plates are also assessed. It is found that the global entropy production is a minimum for certain suitable combination of the physical parameters and a discrete set of values of the separation between the parallel plates. The transferred heat at the plates also shows minima in the same discrete set of values of the plates separation.

  7. PLATE

    DEFF Research Database (Denmark)

    Kling, Joyce; Hjulmand, Lise-Lotte

    2008-01-01

    ’s level of English is sufficient for the increasing number of courses offered in English each semester. This paper addresses these concerns and describes a pilot project initiated in 2003 at CBS to gauge the overall English language proficiency of those teaching content courses in English. Through......Copenhagen Business School (CBS) finds itself needing to address the issue of English-medium instruction for its increasing number of foreign exchange and full degree students. With internationalisation as a main pillar of the institution’s agenda, there are concerns whether the teaching faculty...... the Project in Language Assessment for Teaching in English (PLATE) language professionals from CBS’s Language Center observe teachers and provide feedback using evaluation criteria from the Common European Framework for Reference (CEFR) supplemented by some additional criteria which take the LSP nature...

  8. PLATE

    DEFF Research Database (Denmark)

    Kling, Joyce; Hjulmand, Lise-Lotte

    2008-01-01

    Copenhagen Business School (CBS) finds itself needing to address the issue of English-medium instruction for its increasing number of foreign exchange and full degree students. With internationalisation as a main pillar of the institution’s agenda, there are concerns whether the teaching faculty......’s level of English is sufficient for the increasing number of courses offered in English each semester. This paper addresses these concerns and describes a pilot project initiated in 2003 at CBS to gauge the overall English language proficiency of those teaching content courses in English. Through...... the Project in Language Assessment for Teaching in English (PLATE) language professionals from CBS’s Language Center observe teachers and provide feedback using evaluation criteria from the Common European Framework for Reference (CEFR) supplemented by some additional criteria which take the LSP nature...

  9. Study on composition control and performance of brush plated copper-tin alloy deposits%电刷镀铜锡合金镀层成分控制与性能的研究

    Institute of Scientific and Technical Information of China (English)

    赵仲勋; 曾鹏; 谢光荣; 钟国明; 陈大川; 许小东

    2015-01-01

    采用碱性焦磷酸盐体系在45钢基体上电刷镀制备了铜锡合金镀层。考察了刷镀电压、刷镀液中氯化亚锡质量浓度、pH、刷镀时间等工艺参数对镀层的化学成分、物相结构、显微硬度和附着力的影响。结果表明:刷镀液pH为8.0~10.0时,随电压增大,镀层锡含量呈下降趋势。当氯化亚锡为9.0 g/L,pH为8.0~9.5时,刷镀液稳定,镀层主要由Cu20Sn6和Cu6Sn5构成,锡含量处于高锡水平(质量分数44.10%~57.40%),显微硬度较高。当pH为9.5~10.0时,刷镀液不稳定,镀层主要由Cu20Sn6和α-Cu构成,锡含量处于中锡水平(质量分数35.60%~44.50%),显微硬度较低。随刷镀时间延长,镀层的孔隙率显著下降,刷镀18 min所得镀层非常致密。刷镀电压为4 V时所得厚度为18.00~21.00μm的镀层的附着力在18~23 N之间。%Copper–tin alloy deposits were prepared using electro-brush plating with alkaline pyrophosphate bath on 45 steel substrate. The effects of process parameters such as plating voltage, mass concentration of stannous chloride in bath, pH, and brush plating time on composition, phase structure, microhardness, and adhesion strength of the deposits were studied. The results showed that the tin content of the deposit decline with the increasing of plating voltage at bath pH 8.0-10.0. The bath containing stannous chloride 9.0 g/L is stable at pH 8.0-9.5 and produces the deposits mainly composed of Cu20Sn6 and Cu6Sn5 with a high tin content (44.10wt% to 57.40wt%) and high microhardness, while is unstable at pH 9.5-10.0 and produces the deposits mainly composed of Cu20Sn6 andα-Cu with a medium tin content (35.60wt% to 44.50wt%) and relatively low microhardness. The porosity of the deposit is decreased significantly with the extending of brush plating time. The deposit obtained by brush plating for 18 min is very compact. The adhesion strength of the deposits having a thickness of 18.00-21.00μm obtained at

  10. 78 FR 69371 - Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan: Preliminary...

    Science.gov (United States)

    2013-11-19

    ... International Trade Administration Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan...-annealed, nickel-plated flat-rolled steel products (certain nickel-plated, flat-rolled steel) from Japan..., nickel-plated flat-rolled steel products included in this investigation are flat-rolled,...

  11. 78 FR 4385 - Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic of Korea: Preliminary...

    Science.gov (United States)

    2013-01-22

    ... International Trade Administration Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic...- length carbon-quality steel plate products (CTL plate) from the Republic of Korea (Korea). The period of... Review of the Antidumping Duty Order on Certain Cut-to- Length Carbon-Quality Steel Plate Products from...

  12. 75 FR 47777 - Certain Cut-to-Length Carbon-Quality Steel Plate Products From Italy: Final Results of...

    Science.gov (United States)

    2010-08-09

    ... International Trade Administration Certain Cut-to-Length Carbon-Quality Steel Plate Products From Italy: Final...-quality steel plate products from Italy. The review covers one manufacturer/exporter, Evraz Palini Bertoli... certain cut-to-length carbon-quality steel plate products (CTL plate) from Italy. See Certain Cut-to...

  13. Production of quartz plates for CMS-CASTOR Experiment

    CERN Document Server

    Adiguzel, Aytul; Ayhan, Aydin; Bakirci, Mustafa Numan; Basegmez, Suzan; Beaumont, Willem; Borras, Kerstin; Campbell, Alan; De Paula Carvalho, W; Çerçi, Salim; De Jesus Damiao, Dilson; Dogangün, O; Dumanoglu, Isa; d'Enterria, David; Erchov, Y; Eskut, Eda; Figueiredo, D; Girgis, Semiray; Göttlicher, P; Gouskos, Loukas; Gurpinar, Emine; Hos, Ilknur; Katkov, Igor; Katsas, Panagiotis; Khein, Lev; Knutsson, Albert; Kuznetsov, Andrey; Lebeau, Michel; Van Mechelen, Pierre; Muhl, Carsten; Musienko, Yuri; Ochesanu, Silvia; Onengüt, G; Onengut, G Jr; Ozdemir, Kadri; Panagiotou, Apostolos; Polatoz, A; Ripert, Marion; Shileev, K; Sogut, Kenan; Tiflov, B TaliV; Kayis-Topaksu, A; Uzun, Dilber

    2008-01-01

    Light transmission rate performance of $102$ irradiated quartz samples was measured to select the best quartz plates for CMS-CASTOR calorimeter. All the produced quartz plates were originally used in a previous CERN experiment, DELPHI. Three different doses of $^{60}$Co source were used with the collaboration of PSI (Paul Scherrer Institute, Villigen PSI, Switzerland.) to study the transmission rate performance of the quartz samples after irradiation for different incident light, ranging from $250$ to $700$ nm in $5$ nm increasing steps. All samples show different decrease in the rate with wavelength for different doses. Three different steps were followed before irradiation to find out the best way of cleaning the original DELPHI Cu/Cr tracks on the samples. Results of these measurements presented here correspond to the quartz plates that will be used in one hadronic sector of CASTOR calorimeter until end of 2008. For the full calorimeter new quartz plates will be installed. We also present the light transmi...

  14. International strategic minerals inventory summary report; tin

    Science.gov (United States)

    Sutphin, D.M.; Sabin, A.E.; Reed, B.L.

    1990-01-01

    The International Strategic Minerals Inventory tin inventory contains records for 56 major tin deposits and districts in 21 countries. These countries accounted for 98 percent of the 10 million metric tons of tin produced in the period 1934-87. Tin is a good alloying metal and is generally nontoxic, and its chief uses are as tinplate for tin cans and as solder in electronics. The 56 locations consist of 39 lode deposits and 17 placers and contain almost 7.5 million metric tons of tin in identified economic resources (R1E) and another 1.5 million metric tons of tin in other resource categories. Most of these resources are in major deposits that have been known for over a hundred years. Lode deposits account for 44 percent of the R1E and 87 percent of the resources in other categories. Placer deposits make up the remainder. Low-income and middle-income countries, including Bolivia and Brazil and countries along the Southeast Asian Tin Belt such as Malaysia, Thailand, and Indonesia account for 91 percent of the R1E resources of tin and for 61 percent of resources in other categories. The United States has less than 0.05 percent of the world's tin R1E in major deposits. Available data suggest that the Soviet Union may have about 4 percent of resources in this category. The industrial market economy countries of the United States, Japan, Federal Republic of Germany, and the United Kingdom are major consumers of tin, whereas the major tin-producing countries generally consume little tin. The Soviet Union and China are both major producers and consumers of tin. At the end of World War II, the four largest tin-producing countries (Bolivia, the Belgian Congo (Zaire), Nigeria, and Malaysia) produced over 80 percent of the world's tin. In 1986, the portion of production from the four largest producers (Malaysia, Brazil, Soviet Union, Indonesia) declined to about 55 percent, while the price of tin rose from about $1,500 to $18,000 per metric ton. In response to tin shortages

  15. Study of the Electroless Tin Plating Process on Cotton Fabric and Its Antibacterial Property%棉织物表面电镀锡及其抑菌性检测

    Institute of Scientific and Technical Information of China (English)

    张平; 赵旭堃; 佐同林; 杨召

    2016-01-01

    以平纹棉织物为基布,用含有氨基和氰基的高分子溶胶无钯活化法使棉织物表面形成活化中心,再对其进行化学镀铜和电镀锡。运用扫描电子显微镜比较观察电镀锡前后的表面形态。研究了电镀锡前后棉织物表面的增重率,并用8099大肠埃氏杆菌对其进行抑菌性检测,结果发现抑菌率与增重率之间存在一定的非线性关系,且抑菌率随增重率的增大呈增大的趋势,增重率最高可达4.53%,抑菌率最高可达96.60%,说明电镀锡棉织物抑菌性有效,满足一定的生产生活需要。%The cotton fabric was proceeded electroless copper plating and tin plating using amino and cyano polymer sol containing palladium free activation method to make the fabric surface form the activation center.The surface morphology of the fabric was ob-served by the scanning electron microscope (SEM).The weight gain rate of the surface of the cotton fabric before and after tin plating was studied.The antibacterial activity was detected with 8099 E.coli.The results showed that there was a certain nonlinear relation-ship between the inhibition rate and weight gain rate,and the inhibition rate increased with the increase of weight ratio.The weight gain rate was 4.53%,and the inhibition rate was 96.60%.

  16. 78 FR 50378 - Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan: Postponement of...

    Science.gov (United States)

    2013-08-19

    ... International Trade Administration Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan... Department) initiated the antidumping duty investigation of diffusion-annealed, nickel-plated flat-rolled steel products from Japan. See Diffusion- Annealed, Nickel-Plated Flat-Rolled Steel Products From...

  17. 77 FR 21527 - Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic of Korea: Final...

    Science.gov (United States)

    2012-04-10

    ... International Trade Administration Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic... certain cut-to-length carbon-quality steel plate products from the Republic of Korea. The review covers...-Quality Steel Plate Products From the Republic of Korea: Preliminary Results of Antidumping Duty...

  18. 75 FR 29976 - Certain Cut-to-Length Carbon-Quality Steel Plate Products From Italy: Extension of the Final...

    Science.gov (United States)

    2010-05-28

    ... International Trade Administration Certain Cut-to-Length Carbon-Quality Steel Plate Products From Italy... antidumping duty order on certain cut-to-length carbon-quality steel plate products from Italy. See Certain Cut-to-Length Carbon-Quality Steel Plate Products From Italy: Preliminary Results of Antidumping Duty...

  19. 78 FR 29113 - Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic of Korea: Final...

    Science.gov (United States)

    2013-05-17

    ... International Trade Administration Certain Cut-to-Length Carbon-Quality Steel Plate Products From the Republic... order on certain cut-to-length carbon-quality steel plate products from the Republic of Korea. For these...-quality steel plate products from the Republic of Korea (Korea).\\1\\ The period of review is February 1...

  20. EUV and debris characteristics of a laser-plasma tin-dioxide colloidal target

    Science.gov (United States)

    Kubodera, Shoichi; Kaku, Masanori; Touge, Shunsuke; Katto, Masahito

    2008-10-01

    Characteristics of extreme ultraviolet (EUV) and debris emissions as well as debris reduction have been investigated for a laser-produced plasma (LPP) EUV source by using a colloidal/liquid jet target containing tin dioxide nanoparticles and tin chloride. The amount of deposited debris on a silicon witness plate was determined by a total laser energy irradiated onto a target. Double-pulse laser irradiation was effective for improving the EUV conversion efficiency as a result of plasma regulation. It was, however, not effective for reducing the deposited debris from a colloidal target with nanoparticles. In situ low-temperature heating of the witness plate was effective to reduce the amount of deposited debris. Room-temperature photon processing using an incoherent vacuum ultraviolet excimer lamp at 126 nm deoxidized a deposited tin oxide layer. In addition to these active debris reduction methods, the use of a tin chloride liquid target at a certain concentration passively reduced the amount of deposited debris as a result of production of chlorine atoms that sputtered and/or etched deposition. The EUV CE of more than 1% was observed from a tin chloride target by using double-pulse laser irradiation.

  1. HF production in CMS-Resistive Plate Chambers

    Energy Technology Data Exchange (ETDEWEB)

    Abbrescia, M. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Colaleo, A. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Guida, R. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy)]. E-mail: Roberto.Guida@ba.infn.it; Iaselli, G. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Loddo, F. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Maggi, M. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Marangelli, B. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Natali, S. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Nuzzo, S. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Pugliese, G. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Ranieri, A. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Romano, F. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Trentadue, R. [Dipartimento interateneo di Fisica and sezione INFN, Bari (Italy); Cavallo, N. [Universita degli studi della Basilicata and Sezione INFN, Naples (Italy); Fabozzi, F. [Universita degli studi della Basilicata and Sezione INFN, Naples (Italy); Paolucci, P. [Dipartimento di Fisica and Sezione INFN, Naples (Italy); Piccolo, D.; Polese, G.; Sciacca, C. [Dipartimento di Fisica and Sezione INFN, Naples (Italy); Belli, G.; Necchi, M.; Ratti, S.; Riccardi, C.; Torre, P.; Vitulo, P. [Dipartimento di Fisica Nucleare e Teorica and Sezione INFN, Pavia (Italy); Anguelov, T.; Genchev, V.; Panev, B.; Piperov, S.; Sultanov, G.; Vankov, P. [INRNE, BAS, Soa (Bulgaria); Litov, L.; Pavlov, B.; Petkov, P. [University of Soa St. Kliment Ohridski (Bulgaria)

    2006-08-15

    The formation of highly reactive compounds in the gas mixture during Resistive Plate Chambers (RPCs) operation at the CERN Gamma Irradiation Facility (GIF) is studied. Results from two different types of chambers are discussed: 50 x 50 cm{sup 2} RPC prototypes and two final CMS-RB1 chambers. The RB1 detectors were also connected to a closed loop gas system. Gas composition, possible additional impurities as well as fluoride ions have been monitored in different gamma irradiation conditions both in open and closed loop mode. The chemical composition of the RPC electrode surface has also been analyzed using an electron microscope equipped with an EDS/X-ray.

  2. Scale-down of vinegar production into microtiter plates using a custom-made lid.

    Science.gov (United States)

    Schlepütz, Tino; Büchs, Jochen

    2014-04-01

    As an important food preservative and condiment, vinegar is widely produced in industry by submerged acetic acid bacteria cultures. Although vinegar production is established on the large scale, up to now suitable microscale cultivation methods, e.g. using microtiter plates, are missing to enable high-throughput cultivation and to optimize fermentation conditions. In order to minimize evaporation losses of ethanol and acetic acid in a 48-well microtiter plate during vinegar production a new custom-made lid was developed. A diffusion model was used to calculate the dimensions of a hole in the lid to guarantee a suitable oxygen supply and level of ventilation. Reference fermentation was conducted in a 9-L bioreactor to enable the calculation of the proper cultivation conditions in the microtiter plate. The minimum dissolved oxygen tensions in the microtiter plate were between 7.5% and 23% of air saturation and in the same range as in the 9-L bioreactor. Evaporation losses of ethanol and acetic acid were less than 5% after 47 h and considerably reduced compared to those of microtiter plate fermentations with a conventional gas-permeable seal. Furthermore, cultivation times in the microtiter plate were with about 40 h as long as in the 9-L bioreactor. In conclusion, microtiter plate cultivations with the new custom-made lid provide a platform for high-throughput studies on vinegar production. Results are comparable to those in the 9-L bioreactor.

  3. Experiments to investigate lift production mechanisms on pitching flat plates

    Science.gov (United States)

    Stevens, P. R. R. J.; Babinsky, H.

    2017-01-01

    Pitching flat plates are a useful simplification of flapping wings, and their study can provide useful insights into unsteady force generation. Non-circulatory and circulatory lift producing mechanisms for low Reynolds number pitching flat plates are investigated. A series of experiments are designed to measure forces and study the unsteady flowfield development. Two pitch axis positions are investigated, namely a leading edge and a mid-chord pitch axis. A novel PIV approach using twin laser lightsheets is shown to be effective at acquiring full field of view velocity data when an opaque wing model is used. Leading-edge vortex (LEV) circulations are extracted from velocity field data, using a Lamb-Oseen vortex fitting algorithm. LEV and trailing-edge vortex positions are also extracted. It is shown that the circulation of the LEV, as determined from PIV data, approximately matches the general trend of an unmodified Wagner function for a leading edge pitch axis and a modified Wagner function for a mid-chord pitch axis. Comparison of experimentally measured lift correlates well with the prediction of a reduced-order model for a LE pitch axis.

  4. 78 FR 23905 - Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan: Initiation of...

    Science.gov (United States)

    2013-04-23

    ... International Trade Administration Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan...'') petition concerning imports of diffusion-annealed, nickel-plated flat-rolled steel products from Japan (``certain nickel-plated, flat-rolled steel''), filed in proper form by Thomas Steel Strip...

  5. Evaluation of the Content of Lead, Cadmium, Mercury, Arsenic, Tin, Copper and Zinc during the Production Process Flow of Tomato Broth

    Directory of Open Access Journals (Sweden)

    Corina Andrei

    2013-11-01

    Full Text Available Heavy metals are among the largest contaminants of food products. Once metals are present in vegetables, their concentrations are rarely modified by industrial processing techniques, although in some cases washing may decrease the metal content. The main objective of this study was to quantify the effect of industrial processing on the content of lead, cadmium, mercury, arsenic, tin, copper and zinc in tomatoes and products resulting on flow technology of tomato broth. For the determination of essential elements and/or potentially toxic was use atomic absorption spectrometry. The analytical results for quantitative evaluation the concentrations of the investigated elements on the samples of tomatoes taken from the technological process of the production of tomato broth indicated the presence of Pb, Cd, Cu and Zn but with a level of concentration that significantly decreased in the finished product and the absence of metals Hg and As in all investigated samples. Effect of industrial processing on the content of tin in tomato samples analyzed was characterized by fluctuations in the residual content that led to a significant increase in concentration of 0.100 ± 0.041 mg kg-1 (tomatoes - unprocessed to 0.200 ± 0.041 mg kg-1 (tomato broth.

  6. Enhanced Freshwater Production Using Finned-Plate Air Gap Membrane Distillation (AGMD

    Directory of Open Access Journals (Sweden)

    Perves Bappy Mohammad Jabed

    2017-01-01

    Full Text Available Air Gap membrane distillation (AGMD, a special type of energy efficient membrane distillation process, is a technology for producing freshwater from waste water. Having some benefits over other traditional processes, this method has been able to draw attention of researchers working in the field of freshwater production technologies. In this study, a basic AGMD system with flat coolant plate has been modified using a specially designed channelled coolant plate of portable size to observe its effect over the production rate and performance of the system. Attempt has been made to increase the amount of distillate flux by using the “fin effect” of the channelled coolant plate. A finned plate have been used instead of a flat coolant plate and experiments were conducted to compare the effect. Coolant temperature and feed temperature of the system have been varied from 10°C to 25°C and 40°C to 70°C respectively. Comparing the data, around 50% to 58% distillate enhancement has been observed for channelled coolant plate. Also, it was seen that the enhancement was higher for higher feed temperatures and coolant temperatures. With these findings, a better performing AGMD module has been introduced to mitigate the scarcity of freshwater.

  7. 78 FR 75371 - Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan; Scheduling of the Final...

    Science.gov (United States)

    2013-12-11

    ... COMMISSION Diffusion-Annealed, Nickel-Plated Flat-Rolled Steel Products From Japan; Scheduling of the Final... of less-than-fair-value imports from Japan of diffusion-annealed, nickel- plated flat-rolled steel...; whether or not in coils; either plated or coated with nickel or nickel-based alloys and...

  8. Optimization of a flat plate glass reactor for mass production of Nannochloropsis sp. outdoors.

    Science.gov (United States)

    Richmond, A; Cheng-Wu, Z

    2001-02-23

    The relationships between areal (g m(-2) per day) and volumetric (g l(-1) per day) productivity of Nannochloropsis sp. as affected by the light-path (ranging from 1.3 to 17.0 cm) of a vertical flat plate glass photobioreactor were elucidated. In general, the shorter the length of the light-path (LP), the smaller the areal volume and the higher the volumetric productivity. The areal productivity in relation to the light-path, in contrast, yielded an optimum curve, the highest areal productivity was obtained in a 10 cm LP reactor, which is regarded, therefore, optimal for mass production of Nannochloropsis. An attempt was made to identify criteria by which to assess the efficiency of a photobioreactor in utilizing strong incident energy. Two basic factors which relate to reactor efficiency and its cost-effectiveness have been defined as (a) the total illuminated surface required to produce a set quantity of product and (b) culture volume required to produce that quantity. As a general guide line, the lower these values are, the more efficient and cost-effective the reactor would be. An interesting feature of this analysis rests with the fact that an open raceways is as effective in productivity per illuminated area as a flat-plate reactor with an optimal light path, both cultivation systems requiring ca. 85 m(2) of illuminated surface to produce 1 kg dry cell mass of Nannochloropsis sp. per day. The difference in light utilization efficiency between the two very different production systems involves three aspects - first, the open raceway requires ca. 6 times greater volume than the 10 cm flat plate reactor to produce the same quantity of cell-mass. Second, the total ground area (i.e. including the ground area between reactors) for the vertical flat plate reactor is less than one half of that occupied by an open raceway, indicating the former is more efficient, photosynthetically, compared with the latter. Finally, the harvested cell density is close to one order of

  9. Viscoelastic Effects on the Entropy Production in Oscillatory Flow between Parallel Plates with Convective Cooling

    Directory of Open Access Journals (Sweden)

    Federico Vázquez

    2008-12-01

    Full Text Available The heat transfer problem of a zero-mean oscillatory flow of a Maxwell fluid between infinite parallel plates with boundary conditions of the third kind is considered. With these conditions, the amount of heat entering or leaving the system depends on the external temperature as well as on the convective heat transfer coefficient. The local and global time-averaged entropy production are computed, and the consequences of convective cooling of the plates are also assessed. It is found that the global entropy production is a minimum for certain suitable combination of the physical parameters. For a discrete set of values of the oscillatory Reynolds number, the extracted heat from one of the plates shows maxima.

  10. Reductive spectrophotometry of divalent tin sensitization on soda lime glass

    Science.gov (United States)

    Bejugam, Vinith; Wei, Xingfei; Roper, D. Keith

    2016-07-01

    Rapid and facile evaluation of tin (II) sensitization could lead to improved understanding of metal deposition in electroless (EL) plating. This report used a balanced redox reaction between 3,3‧,5,5‧-tetramethylbenzidine dihydrochloride (TMB-HCL) and N-bromosuccinimide (NBS) to evaluate effects of sensitization conditions (i.e., sensitization time, analyte concentration, aqueous immersion, and acid content) on the accumulated mass of surface-associated divalent tin ion. The accumulated mass of tin (II) increased as the sensitization time increased up to 30 s in proportion to aqueous tin (II) chloride concentrations between 2.6 and 26 mM at a trifluoroacetic acid (TFA) content of 68 mM. The average mass peaked at 7.3 nanomoles (nmol) per cm2 after a 5 s aqueous immersion post-sensitization, and then decreased with increasing aqueous immersion post-sensitization. The total average tin (II) + tin (IV) accumulated on soda lime glass measured by inductively coupled plasma optical emission spectrometry (ICP-OES) was 17% higher at 30 s sensitization, suggesting a fraction of the tin (II) present may have oxidized to tin (IV). These results indicated that in situ spectrophotometric evaluation of tin (II) could support development of EL plating for electronics, catalysis, and solar cells.

  11. Production of fatty acids and protein by nannochloropsis in flat-plate photobioreactors

    NARCIS (Netherlands)

    Hulatt, Chris J.; Wijffels, René H.; Bolla, Sylvie; Kiron, Viswanath

    2017-01-01

    Nannochloropsis is an industrially-promising microalga that may be cultivated for alternative sources of nutrition due to its high productivity, protein content and lipid composition. We studied the growth and biochemical profile of Nannochloropsis 211/78 (CCAP) in optimized flat-plate photobioreact

  12. Reducing the variability of antibiotic production in Streptomyces by cultivation in 24-square deepwell plates

    DEFF Research Database (Denmark)

    Siebenberg, S.; Bapat, Prashant Madhusudhan; Eliasson Lantz, Anna

    2010-01-01

    of time. Originally, novobiocin titers in the deepwell plate (5-12 mg l(-1)) were lower than in Erlenmeyer flasks (24 mg Optimization of the inoculation procedure as well as addition of a siloxylated ethylene oxide/propylene oxide copolymer, acting as oxygen carrier, to the production medium increased...

  13. A Win for the Future of Tin

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Drinking that draft beer from a glass? Why not try tin products instead—they keep your beer cooler and more refreshing longer than glasses! In 1885, Yong Koon, a young man from Guangdong Province, traveled

  14. Places, Chains, and Plates: Governing Transitions in the Shrimp Aquaculture Production-Consumption System

    OpenAIRE

    Lebel, L.; Lebel, P; Garden, P.; Dao, H. G.; Khrutmuang, S.; Nakayama, S

    2008-01-01

    The shrimp production-consumption system is governed by a diverse and dynamic array of actors each drawing on institutions at various levels, from local through national to international. But, for the most part, the politics of consumption (plates), chains, and places are disconnected. Instead, shrimp producers face a myriad of institutional and consumer demands and the sustainability of the shrimp aquaculture production-consumption system is not merely a technical problem to be solved by bet...

  15. Recovery of Caprolactam from Waste Water in Caprolactam Production Using Pulsed—sieve—plate Extraction column

    Institute of Scientific and Technical Information of China (English)

    LIUJiangqing; XIEFangyou; 等

    2002-01-01

    Recovery of caprolactam from waste water of caprolactam production factory was investigated using benzence as solvent in a small-scale pulsed-sieve-plate column.First,liquid-liquid equilibrium (LLE) deta were measured,including water-caprolactam-benzene system at low caprolactam concentrations,and waste water-benzene system.Then,the operating regions and mass transfer of the pulsed-sieve-plate column were measured.Finally,the overall apparent heights of a transfer unit based on continuous phase are correlated in terms of the column operation variables.

  16. Mass production of spores of lactic acid-producing Rhizopus oryzae NBRC 5384 on agar plate.

    Science.gov (United States)

    Yamane, Tsuneo; Tanaka, Ryosuke

    2013-01-01

    Mass production of sporangiospores (spores) of Rhizopus oryzae NBRC 5384 (identical to NRRL 395 and ATCC 9363) on potato-dextrose-agar medium was studied aiming at starting its L(+)-lactic acid fermentation directly from spore inoculation. Various parameters including harvest time, sowed spore density, size of agar plate, height of air space, and incubation mode of plate (agar-on-bottom or agar-on-top) were studied. Ordinarily used shallow Petri dishes were found out to be unsuitable for the full growth of R. oryzae sporangiophores. In a very wide range of the sowed spore density, the smaller it was, the greater the number of the harvested spores was. It was also interesting to find out that R. oryzae grown downward vertically with a deep air space in an agar-on-top mode gave larger amount of spores than in an agar-on-bottom mode at 30°C for 7-day cultivation. Scale-up of the agar plate culture from 26.4 to 292 cm(2) was studied, resulting in the proportional relationship between the number of the harvested spores/plate and the plate area in the deep Petri dishes. The number of plates of 50 cm in diameter needed for 100 m(3) industrial submerged fermentation started directly from 2 × 10(5) spores/mL inoculum size was estimated as about 6, from which it was inferred that such a fermentation would be feasible. Designing a 50 cm plate and a method of spreading and collecting the spores were suggested. Bioprocess technological significance of the "full-scale industrial submerged fermentation started directly from spore inoculation omitting pre-culture" has been discussed.

  17. Waffle Production: Influence of Baking Plate Material on Sticking of Waffles.

    Science.gov (United States)

    Huber, Regina; Kalss, Georg; Schoenlechner, Regine

    2017-01-01

    Background of this study was to understand the factors that contribute to sticking of fresh egg waffles on baking plates. The aim of this study was to investigate the sticking (adhesion) behavior of waffles on 4 different baking plate materials (ductile iron, grey iron, low alloyed steel, and steel with titanium nitrite coating) at different baking parameters (temperature and time) and application of 3 different release agents (different fat compositions). Baking plates from ductile and grey iron showed lower release properties of waffles than the 2 steel baking plates. Baking parameters had to be high enough to allow rapid product crust formation but prevent burning, which again increases sticking behavior. Release agents based on short-chain fatty acids with higher degree of saturation provided better release behavior of waffles than those based on long-chain fatty acids or on emulsifier-acid combinations. Baking plates with increased hardness, good heat storage capacity, and smooth surface seemed to be best suitable. Further research on appropriate coating material might be promising for future. © 2016 Institute of Food Technologists®.

  18. Controls on hydrocarbon occurrence and productivity in the F6 reservoir, Tin Fouye-Tabankort area, NW Illizi Basin

    Energy Technology Data Exchange (ETDEWEB)

    Alem, N.; Assassi, S.; Benhebouche, S.; Kadi, B. [CDR-Sonatrach, Boumerdes (Algeria)

    1998-12-31

    Several oil accumulations of various sizes have been found within the F6 reservoir of Upper Silurian-Lower Devonian age in the Tin Fouye region of the Illizi Basin, about 1500 km from Algiers. Lithologically, the F6 consists of interbedded sandstones and shales and is subdivided into units: M1, M2, A, B1, B2, C1, C2 and C3, the upper units often being missing through erosion. These reservoirs, which were deposited in offshore coastal bars and tidal channels, show a high degree of lateral and vertical facies variation. Study of the hydrology of the F6 reservoir shows that connate water and oil have been frequently flushed by fresh water in the most permeable units, particularly C1 and B2. This finding is supported by hydrochemical data, by the inclination of oil-water contacts and by a high observed hydraulic gradient. (author)

  19. Production of normalized steel plate through normalizing rolling; Producao de chapas grossas normalizadas diretamente do calor de laminacao

    Energy Technology Data Exchange (ETDEWEB)

    Gorni, Antonio Augusto; Cavalcanti, Celso Gomes; Reis, Jackson Soares de Souza; Silveira, Jose Herbert Dolabela da [Companhia Siderurgica Paulista (COSIPA), SP (Brazil)

    1997-12-31

    Normalized plates can be got directly from the rolling heat through the use of a normalizing rolling process. In such way, an additional step of the conventional process of production of normalized plates - the normalizing heat treatment - can be suppressed, reducing the manufacturing cost of the product and shortening its production time. This relatively new production route is being used in several steelworks all over the world for many years. This work describes the implementation trials of normalizing rolling at COSIPA`s plate mill, using an alternative process of controlled rolling called recrystallization controlled rolling. The results got with new technique were successful, as it was able to produce plates with properties very similar to the conventionally normalized material, attending the requirements of the DIN 17100 RR 52-3N standard. This is one of many standards that permit the use of this new route of normalized steel plate production. (author) 14 refs., 8 figs., 2 tabs.

  20. 无氰铜锡合金仿金电镀添加剂的研究%Study on additives of cyanide-free gold-imitative copper-tin alloy plating

    Institute of Scientific and Technical Information of China (English)

    黄灵飞; 曾振欧; 谢金平; 范小玲

    2015-01-01

    The effects of different types of additives including H-3, DDS, and JZ-1 on the performances of gold-imitative copper–tin alloy coating electroplated from an aqueous pyrophosphate electrolyte was studied in Hull cell and square cell. The plating bath (pH 8.7) is basically composed of Cu2P2O7·3H2O 24 g/L, K4P2O7·3H2O 240 g/L, and Sn2P2O7 2.0 g/L. It is shown that imitation gold coating can be obtained from the pyrophosphate electrolyte only after adding some additive to it. The additive H-3 has a certain effect of leveling, grain refinement, and brightness enhancement. The cathodic current density range for preparation of imitation gold coating on copper alloys from the electrolyte containing H-3 2.8 mL/L is 0.29-2.25 A/cm2. Bright imitation gold coatings can be obtained by conducting the electroplating process in the pyrophosphate electrolyte with additive H-3 on some intermediate layers such as bright acid copper coating, bright nickel coating, and cyanide-free white copper–tin coating or directly on steel substrate.%通过赫尔槽试验和方槽试验研究了添加剂H-3、DDS和JZ-1对焦磷酸盐溶液体系电镀仿金铜锡合金性能的影响。基础镀液组成为:K4P2O7·3H2O 240 g/L,Sn2P2O72.0 g/L,Cu2P2O7·3H2O 24 g/L,pH 8.7。结果表明,采用焦磷酸盐溶液体系电镀铜锡合金时,只有用到添加剂方可得到仿金镀层。添加剂H-3具有一定的整平、细化晶粒和提高光亮度的作用。H-3的用量为2.8 mL/L时,在黄铜基体上获得仿金镀层的阴极电流密度范围为0.29~2.25 A/cm2。焦磷酸盐溶液体系使用添加剂H-3时,在光亮酸铜、光亮镍、无氰白铜锡中间层上和直接在钢铁基体上进行仿金电镀时,均可获得光亮的仿金镀层。

  1. A model for release of fission products from a breached fuel plate under wet storage

    Energy Technology Data Exchange (ETDEWEB)

    Terremoto, L.A.A.; Seerban, R.S.; Zeituni, C.A.; Silva, J.E.R. da; Silva, A.T. e; Castanheira, M.; Lucki, G.; Damy, M. de A.; Teodoro, C.A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mail: laaterre@ipen.br

    2007-07-01

    MTR fuel elements burned-up inside the core of nuclear research reactors are stored worldwide mainly under the water of storage pools. When cladding breach is present in one or more fuel plates of such elements, radioactive fission products are released into the storage pool water. This work proposes a model to describe the release mechanism considering the diffusion of nuclides of a radioactive fission product either through a postulated small cylindrical breach or directly from a large circular hole in the cladding. In each case, an analytical expression is obtained for the activity released into the water as a function of the total storage time of a breached fuel plate. Regarding sipping tests already performed at the IEA-R1 research reactor on breached MTR fuel elements, the proposed model correlates successfully the specific activity of {sup 137}Cs, measured as a function of time, with the evaluated size of the cladding breach. (author)

  2. Culture of isolated floor plate tissue and production of conditioned medium to assess functional properties of floor plate-released signals.

    Science.gov (United States)

    Charoy, Camille; Arbeille, Elise; Thoinet, Karine; Castellani, Valérie

    2014-02-11

    During development, progenitors and post-mitotic neurons receive signals from adjacent territories that regulate their fate. The floor-plate is a group of glial cells lining the ependymal canal at ventral position. The floor-plate expresses key morphogens contributing to the patterning of cell lineages in the spinal cord. At later developmental stages, the floor-plate regulates the navigation of axons in the spinal cord, acting as a barrier to prevent the crossing of ipsilateral axons and controlling midline crossing by commissural axons(1). These functions are achieved through the secretion of various guidance cues. Some of these cues act as attractants and repellents for the growing axons while others regulate guidance receptors and downstream signaling to modulate the sensitivity of the axons to the local guidance cues(2,3). Here we describe a method that allows investigating the properties of floor-plate derived signals in a variety of developmental contexts, based on the production of Floor-Plate conditioned medium (FP(cm))(4-6). We then exemplify the use of this FP(cm) in the context of axon guidance. First, the spinal cord is isolated from mouse embryo at E12.5 and the floor-plate is dissected out and cultivated in a plasma-thrombin matrix (Figure 1). Second two days later, commissural tissue are dissected out from E12.5 embryos, triturated and exposed to the FP(cm). Third, the tissue are processed for Western blot analysis of commissural markers.

  3. Study by XPS of the chlorination of proteins aggregated onto tin dioxide during electrochemical production of hypochlorous acid

    Science.gov (United States)

    Debiemme-Chouvy, Catherine; Haskouri, Sanae; Cachet, Hubert

    2007-04-01

    In solution, hypochlorous acid (HOCl) reacts with organic matter and notably with protein side-chains. In this study, HOCl was produced by an electrochemical way, by oxidation of chloride ions at a transparent tin dioxide electrode in the presence of a protein, the bovine serum albumin (BSA). A thick irregular layer is formed at the electrode when HOCl is produced at the SnO 2 surface. Indeed, SEM analyses show that an important deposit is formed during the anodic polarization of SnO 2 in the presence of chloride ions and proteins. Actually, two phenomena take place on the one hand the chlorination of the proteins due to the reaction of HOCl with some protein side-chains and on the other hand the aggregation of proteins onto the SnO 2 surface. The present X-ray photoelectron spectroscopy study points out the cross-linking of BSA molecules via formation of inter molecular sulfonamide groups. It also shows that the BSA chlorination is due on the one hand to the formation of sulfonyl chloride groups (-SO 2Cl) and on the other hand to formation of chloramine groups ( lbond2 N-Cl). The Cl2p and S2p photo-peak intensities allowed us to quantify the chloramines. It is found that, one BSA entity immobilized onto the SnO 2 surface contains about 50 chloramine groups.

  4. Study by XPS of the chlorination of proteins aggregated onto tin dioxide during electrochemical production of hypochlorous acid

    Energy Technology Data Exchange (ETDEWEB)

    Debiemme-Chouvy, Catherine [Laboratoire Interfaces et Systemes Electrochimiques, UPR 15 du CNRS, UPMC Case Courrier 133-4, Place Jussieu, 75252 Paris Cedex (France)]. E-mail: debiemme@ccr.jussieu.fr; Haskouri, Sanae [Laboratoire Interfaces et Systemes Electrochimiques, UPR 15 du CNRS, UPMC Case Courrier 133-4, Place Jussieu, 75252 Paris Cedex (France); Cachet, Hubert [Laboratoire Interfaces et Systemes Electrochimiques, UPR 15 du CNRS, UPMC Case Courrier 133-4, Place Jussieu, 75252 Paris Cedex (France)

    2007-04-15

    In solution, hypochlorous acid (HOCl) reacts with organic matter and notably with protein side-chains. In this study, HOCl was produced by an electrochemical way, by oxidation of chloride ions at a transparent tin dioxide electrode in the presence of a protein, the bovine serum albumin (BSA). A thick irregular layer is formed at the electrode when HOCl is produced at the SnO{sub 2} surface. Indeed, SEM analyses show that an important deposit is formed during the anodic polarization of SnO{sub 2} in the presence of chloride ions and proteins. Actually, two phenomena take place on the one hand the chlorination of the proteins due to the reaction of HOCl with some protein side-chains and on the other hand the aggregation of proteins onto the SnO{sub 2} surface. The present X-ray photoelectron spectroscopy study points out the cross-linking of BSA molecules via formation of inter molecular sulfonamide groups. It also shows that the BSA chlorination is due on the one hand to the formation of sulfonyl chloride groups (-SO{sub 2}Cl) and on the other hand to formation of chloramine groups ( N-Cl). The Cl2p and S2p photo-peak intensities allowed us to quantify the chloramines. It is found that, one BSA entity immobilized onto the SnO{sub 2} surface contains about 50 chloramine groups.

  5. Stress analysis and microstructure of PVD monolayer TiN and multilayer TiN/(Ti,Al)N coatings

    NARCIS (Netherlands)

    Carvalho, NJM; Zoestbergen, E; Kooi, BJ; De Hosson, JTM

    2003-01-01

    Two PVD titanium nitride based coatings; monolayer TiN and multilayer resulting from the stacking of TiN and (Ti,Al)N layers were evaluated with respect to their stress state and microstructure. The TiN was deposited by triode evaporation ion plating, whereas the TiN/(Ti,AI)N was deposited using a

  6. Stress analysis and microstructure of PVD monolayer TiN and multilayer TiN/(Ti,Al)N coatings

    NARCIS (Netherlands)

    Carvalho, NJM; Zoestbergen, E; Kooi, BJ; De Hosson, JTM

    2003-01-01

    Two PVD titanium nitride based coatings; monolayer TiN and multilayer resulting from the stacking of TiN and (Ti,Al)N layers were evaluated with respect to their stress state and microstructure. The TiN was deposited by triode evaporation ion plating, whereas the TiN/(Ti,AI)N was deposited using a r

  7. 78 FR 19734 - Diffusion-Annealed, Nickel-Plated Steel Flat-Rolled Products From Japan; Institution of...

    Science.gov (United States)

    2013-04-02

    ... From the Federal Register Online via the Government Publishing Office INTERNATIONAL TRADE COMMISSION Diffusion-Annealed, Nickel-Plated Steel Flat-Rolled Products From Japan; Institution of... retarded, by reason of imports from Japan of diffusion-annealed, nickel-plated steel flat-rolled...

  8. Modeling tin whisker growth.

    Energy Technology Data Exchange (ETDEWEB)

    Weinberger, Christopher Robert

    2013-08-01

    Tin, lead, and lead-tin solders are the most commonly used solders due to their low melting temperatures. However, due to the toxicity problems, lead must now be removed from solder materials. This has lead to the re-emergence of the issue of tin whisker growth. Tin whiskers are a microelectronic packaging issue because they can lead to shorts if they grow to sufficient length. However, the cause of tin whisker growth is still not well understood and there is lack of robust methods to determine when and if whiskering will be a problem. This report summarizes some of the leading theories on whisker growth and attempts to provide some ideas towards establishing the role microstructure plays in whisker growth.

  9. Modeling tin whisker growth.

    Energy Technology Data Exchange (ETDEWEB)

    Weinberger, Christopher Robert

    2013-08-01

    Tin, lead, and lead-tin solders are the most commonly used solders due to their low melting temperatures. However, due to the toxicity problems, lead must now be removed from solder materials. This has lead to the re-emergence of the issue of tin whisker growth. Tin whiskers are a microelectronic packaging issue because they can lead to shorts if they grow to sufficient length. However, the cause of tin whisker growth is still not well understood and there is lack of robust methods to determine when and if whiskering will be a problem. This report summarizes some of the leading theories on whisker growth and attempts to provide some ideas towards establishing the role microstructure plays in whisker growth.

  10. Production of Sn–Cu/MWCNT composite electrodes for Li-ion batteries by using electroless tin coating

    Energy Technology Data Exchange (ETDEWEB)

    Uysal, Mehmet, E-mail: mehmetu@sakarya.edu.tr; Cetinkaya, Tugrul; Kartal, Muhammet, E-mail: kartal@sakarya.edu.tr; Alp, Ahmet; Akbulut, Hatem

    2014-12-01

    Cycling stability of pure tin electrodes were aimed to improve by using a suitable combination of copper and multiwalled carbon nanotubes (MWCNTs). For this purpose, firstly Sn–Cu composite powders were produced using an electroless process. Then, Sn–Cu/MWCNT composite electrodes were prepared with dispersing different amounts of MWCNT (10 wt.%, 20 wt.%, 40 wt.%) by high energy mechanical milling method. The surface morphology of the produced Sn–Cu/MWCNT composite powders was characterized using scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) was used to determine the elemental surface composition of the composites. X-ray diffraction (XRD) analysis was performed to investigate the structure of the Sn–Cu/MWCNT composite powders. The electrochemical performance of Sn–Cu/MWCNT composite electrodes has been investigated by charge/discharge tests and cyclic voltammetry experiments. The cell discharge capacities were determined at a constant current in voltage range between 0.02 V and 1.5 V. AC Electrochemical Impedance Spectroscopy (EIS) analysis was also carried out to measure resistivity and Li-diffusion in the assembled cells. The amounts of MWCNTs were shown to be a crucial factor to improve Sn–Cu/MWCNT composite anodes for cyclability and reversible capacity. - Highlights: • Sn–Cu/MWCNT anodes were produced by high energy mechanical milling and electroless method. • MWCNT increases electronic contact between current collector and active material. • The discharge capacity of Sn–Cu/40MWCNT composite was found to be 439 mAh g{sup −1} even after 30 cycles.

  11. Magma production rate along the Ninetyeast Ridge and its relationship to Indian plate motion and Kerguelen hot spot activity

    Science.gov (United States)

    Sreejith, K. M.; Krishna, K. S.

    2015-02-01

    The Ninetyeast Ridge, a linear trace of the Kerguelen hot spot in the Indian Ocean, was emplaced on a rapidly drifting Indian plate. Magma production rates along the ridge track are computed using gravity-derived excess crustal thickness data. The production rates change between 2 and 15 m3/s over timescales of 3-16 Myr. Major variations in magma production rates are primarily associated with significant changes in the Indian plate velocity with low-production phases linked to high plate velocity periods. The lowest magma production rate (2 m3/s) at 62 Ma is associated with the rapid northward drift of Indian plate under the influence of the Reunion mantle plume. The contemporaneous slowing of the African plate coincides with increase in magma production rate along the Walvis Ridge in the Atlantic Ocean. The present study suggests that variations in the Indian plate motion and frequent ridge jumps have a major role in controlling the magma production, particularly on long-period cycles (~16 Myr). Short-period variations (~5 Myr) in magma productions may be associated with intrinsic changes in the plume, possibly due to the presence of solitary waves in the plume conduit.

  12. Magma production rate along the Ninetyeast Ridge and its relationship to Indian plate motion and Kerguelen hot spot activity

    Digital Repository Service at National Institute of Oceanography (India)

    Sreejith, K.M.; Krishna, K.S.

    The Ninetyeast Ridge, a linear trace of the Kerguelen hot spot in the Indian Ocean, was emplaced on a rapidly drifting Indian plate. Magma production rates along the ridge track are computed using gravity-derived excess crustal thickness data...

  13. Quantification of biofilm in microtiter plates: overview of testing conditions and practical recommendations for assessment of biofilm production by staphylococci.

    Science.gov (United States)

    Stepanović, Srdjan; Vuković, Dragana; Hola, Veronika; Di Bonaventura, Giovanni; Djukić, Slobodanka; Cirković, Ivana; Ruzicka, Filip

    2007-08-01

    The details of all steps involved in the quantification of biofilm formation in microtiter plates are described. The presented protocol incorporates information on assessment of biofilm production by staphylococci, gained both by direct experience as well as by analysis of methods for assaying biofilm production. The obtained results should simplify quantification of biofilm formation in microtiter plates, and make it more reliable and comparable among different laboratories.

  14. A new condensation product for zinc plating from non-cyanide alkaline bath

    Indian Academy of Sciences (India)

    Y Arthoba Naik; T V Venkatesha

    2005-08-01

    Zinc electroplating from non-cyanide alkaline solution is carried out in the presence of condensation product formed between DL-alanine (DLA) and glutaraldehyde. The bath constituents and bath variables are optimized through standard Hull cell experiments. The current efficiency and the throwing power are measured. High shift of potential towards more cathodic direction was observed in presence of addition agents. Corrosion resistance test reveals good protection of base metal by zinc coating obtained from the developed electrolyte. SEM photomicrographs show fine-grained deposit in the presence of condensation product. IR spectrum of the scraped deposit shows the inclusion of the condensation product in the deposit during plating. The consumption of brightener in the lab-scale is 6 mLL-1 for 1000 amp-hour.

  15. Improved detection of rhamnolipid production using agar plates containing methylene blue and cetyl trimethylammonium bromide.

    Science.gov (United States)

    Pinzon, Neissa M; Ju, Lu-Kwang

    2009-10-01

    Rhamnolipids, produced predominantly by Pseudomonas aeruginosa, are biosurfactants with important applications. For efficient culture screening according to rhamnolipid productivity, the method using agar plates containing methylene blue (MB) and cetyl trimethylammonium bromide (CTAB) was re-examined. An alternative set-up using a fixed underneath light source and image analysis software improved the detection of the circles formed due to complexation between anionic rhamnolipids and cationic MB/CTAB. The roles and effects of MB and CTAB concentrations and pH on the complexation phenomena are reported.

  16. Raman Scattering from Tin

    Science.gov (United States)

    2015-09-01

    and processing that will enable us to investigate the unique electronic states between topological insulators (TIs) and high- temperature... superconductors . TIs are electronic materials that have a bulk bandgap and gapless conducting surface states that are protected by the topological and...temperatures lower than 286 K and undergoes a phase transition at 286 K to metallic tin (β-Sn), the stable tin allotrope at temperatures above 286 K.4 High

  17. Hydrogen production by Rhodobacter sphaeroides O.U.001 in a flat plate solar bioreactor

    Energy Technology Data Exchange (ETDEWEB)

    Eroglu, Inci; Tabanoglu, Altan; Eroglu, Ela [Department of Chemical Engineering, Middle East Technical University, 06531 Ankara (Turkey); Guenduez, Ufuk; Yuecel, Meral [Department of Biology, Middle East Technical University, 06531 Ankara (Turkey)

    2008-01-15

    Rhodobacter sphaeroides O.U.001 can produce hydrogen under anaerobic conditions and illumination. The objective of this study was to investigate the performance of an 8 l flat plate solar bioreactor operating in outdoor conditions. Different organic acids were used as carbon sources (malate, lactate and acetate) and olive mill waste water was used as a sole substrate source. The consumption and the production of the organic acids were determined by HPLC. The accumulation of by-products, such as poly-{beta}-hydroxybutyrate (PHB) and carotenoid, throughout the course of hydrogen production was determined. The hydrogen production rate was highest (0.01 l/l/h) when malate was the carbon source. Formate was observed as the fermentation end product. Acetate resulted in low hydrogen gas production and high PHB accumulation. When acetate was used as the carbon source, butyrate was produced as a result of fermentation. Promising amounts of PHB and caretenoid were accumulated during hydrogen production from diluted olive mill wastewater. (author)

  18. Large-angle production of charged pions by 3 GeV/c - 12 GeV/c protons on carbon, copper and tin targets

    CERN Document Server

    Catanesi, M.G.; Ellis, Malcolm; Robbins, S.; Soler, F.J.P.; Gossling, C.; Bunyatov, S.; Krasnoperov, A.; Popov, B.; Serdiouk, V.; Tereschenko, V.; Di Capua, E.; Vidal-Sitjes, G.; Artamonov, A.; Arce, P.; Giani, S.; Gilardoni, S.; Gorbunov, P.; Grant, A.; Grossheim, A.; Gruber, P.; Ivanchenko, V.; Kayis-Topaksu, A.; Panman, J.; Papadopoulos, I.; Pasternak, J.; Tcherniaev, E.; Tsukerman, I.; Veenhof, R.; Wiebusch, C.; Zucchelli, P.; Blondel, A.; Borghi, S.; Campanelli, M.; Morone, M.C.; Prior, G.; Schroeter, R.; Engel, R.; Meurer, C.; Kato, I.; Gastaldi, U.; Mills, G.B.; Graulich, J.S.; Gregoire, G.; Bonesini, M.; Ferri, F.; Paganoni, M.; Paleari, F.; Kirsanov, M.; Bagulya, A.; Grichine, V.; Polukhina, M.; Palladino, V.; Coney, L.; Schmitz, D.; Barr, G.; De Santo, A.; Pattison, C.; Zuber, K.; Bobisut, F.; Gibin, D.; Guglielmi, A.; Mezzetto, M.; Dumarchez, J.; Vannucci, F.; Dore, U.; Orestano, D.; Pastore, F.; Tonazzo, A.; Tortora, L.; Booth, C.; Buttar, C.; Hodgson, P.; howlett, L.; Bogomilov, M.; Chizhov, M.; Kolev, D.; Tsenov, R.; Piperov, Stefan; Temnikov, P.; Apollonio, M.; Chimenti, P.; Giannini, G.; Santin, G.; Burguet-Castell, J.; Cervera-Villanueva, A.; Gomez-Cadenas, J.J.; Martin-Albo, J.; Novella, P.; Sorel, M.; Tornero, A.

    2008-01-01

    A measurement of the double-differential $\\pi^{\\pm}$ production cross-section in proton--carbon, proton--copper and proton--tin collisions in the range of pion momentum $100 \\MeVc \\leq p < 800 \\MeVc$ and angle $0.35 \\rad \\le \\theta <2.15 \\rad$ is presented. The data were taken with the HARP detector in the T9 beam line of the CERN PS. The pions were produced by proton beams in a momentum range from 3 \\GeVc to 12 \\GeVc hitting a target with a thickness of 5% of a nuclear interaction length. The tracking and identification of the produced particles was done using a small-radius cylindrical time projection chamber (TPC) placed in a solenoidal magnet. An elaborate system of detectors in the beam line ensured the identification of the incident particles. Results are shown for the double-differential cross-sections at four incident proton beam momenta (3 \\GeVc, 5 \\GeVc, 8 \\GeVc and 12 \\GeVc).

  19. Large-angle production of charged pions by 3 GeV/c - 12 GeV/c protons on carbon, copper and tin targets

    CERN Document Server

    Catanesi, M G; Edgecock, R; Ellis, M; Robbins, S; Soler, F J P; Gössling, C; Bunyatov, S; Krasnoperov, A; Popov, B; Serdiouk, V; Tereschenko, V; Di Capua, E; Vidal-Sitjes, G; Artamonov, A; Arce, P; Giani, S; Gilardoni, S; Gorbunov, P; Grant, A; Grossheim, A; Gruber, P; Ivanchenko, V; Kayis-Topaksu, A; Panman, J; Papadopoulos, I; Pasternak, J; Chernyaev, E; Tsukerman, I; Veenhof, R; Wiebusch, C; Zucchelli, P; Blondel, A; Borghi, S; Campanelli, M; Morone, M C; Prior, G; Schroeter, R; Engel, R; Meurer, C; Kato, I; Gastaldi, Ugo; Mills, G B; Graulich, J S; Grégoire, G; Bonesini, M; Ferri, F; Paganoni, M; Paleari, F; Kirsanov, M; Bagulya, A; Grichine, V; Polukhina, N; Palladino, V; Coney, L; Schmitz, D; Barr, G; De Santo, A; Pattison, C; Zuber, K; Bobisut, F; Gibin, D; Guglielmi, A; Mezzetto, M; Dumarchez, J; Vannucci, F; Dore, U; Orestano, D; Pastore, F; Tonazzo, A; Tortora, L; Booth, C; Buttar, C; Hodgson, P; Howlett, L; Bogomilov, M; Chizhov, M; Kolev, D; Tsenov, R; Piperov, S; Temnikov, P; Apollonio, M; Chimenti, P; Giannini, G; Santin, G; Burguet-Castell, J; Cervera-Villanueva, A; Gómez-Cadenas, J J; Martín-Albo, J; Novella, P; Sorel, M; Tornero, A

    2008-01-01

    A measurement of the double-differential $\\pi^{\\pm}$ production cross-section in proton--carbon, proton--copper and proton--tin collisions in the range of pion momentum $100 \\MeVc \\leq p < 800 \\MeVc$ and angle $0.35 \\rad \\le \\theta <2.15 \\rad$ is presented. The data were taken with the HARP detector in the T9 beam line of the CERN PS. The pions were produced by proton beams in a momentum range from 3 \\GeVc to 12 \\GeVc hitting a target with a thickness of 5% of a nuclear interaction length. The tracking and identification of the produced particles was done using a small-radius cylindrical time projection chamber (TPC) placed in a solenoidal magnet. An elaborate system of detectors in the beam line ensured the identification of the incident particles. Results are shown for the double-differential cross-sections at four incident proton beam momenta (3 \\GeVc, 5 \\GeVc, 8 \\GeVc and 12 \\GeVc).

  20. Portuguese tin-glazed earthenware from the 17th century. Part 2: A spectroscopic characterization of pigments, glazes and pastes of the three main production centers.

    Science.gov (United States)

    Vieira Ferreira, L F; Ferreira, D P; Conceição, D S; Santos, L F; Pereira, M F C; Casimiro, T M; Ferreira Machado, I

    2015-01-01

    Sherds representative of the three Portuguese faience production centers of the 17th century - Lisbon, Coimbra and Vila Nova were studied with the use of mostly non-invasive spectroscopies, namely: ground state diffuse reflectance absorption (GSDR), micro-Raman, Fourier-transform infrared (FT-IR) and proton induced X-ray (PIXE) or X-ray fluorescence emission (XRF). X-ray diffraction (XRD) experiments were also performed. The obtained results evidence a clear similarity in the pastes of the pottery produced Vila Nova and some of the ceramic pastes from Lisbon, in accordance with documental sources that described the use of Lisbon clays by Vila Nova potters, at least since mid 17th century. Quartz and Gehlenite are the main components of the Lisbon's pastes, but differences between the ceramic pastes were detected pointing out to the use of several clay sources. The spectroscopic trend exhibited Coimbra's pottery is remarkably different, Quartz and Diopside being the major components of these pastes, enabling one to well define a pattern for these ceramic bodies. The blue pigment from the Lisbon samples is a cobalt oxide that exists in the silicate glassy matrix, which enables the formation of detectable cobalt silicate microcrystals in most productions of the second half of the 17th century. No micro-Raman cobalt blue signature could be detected in the Vila Nova and Coimbra blue glazes. This is in accordance with the lower kiln temperatures in these two production centers and with Co(2+) ions dispersed in the silicate matrix. In all cases the white glaze is obtained with the use of tin oxide. Hausmannite was detected as the manganese oxide mineral used to produce the purple glaze (wine color "vinoso") in Lisbon.

  1. Development of High-Density U/Al Dispersion Plates For Mo-99 Production Using Atomized Uranium Powder

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Ho Jin [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Chang Kyu; Park, Jong Man [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Sim, Moon Soo; Lee, Jong Hyun [Chungnam National Univ., Daejeon (Korea, Republic of)

    2013-12-15

    Uranium metal particle dispersion plates have been proposed as targets for Molybdenum-99 (Mo-99) production to improve the radioisotope production efficiency of conventional low enriched uranium targets. In this study, uranium powder was produced by centrifugal atomization, and miniature target plates containing uranium particles in an aluminum matrix with uranium densities up to 9 g-U/cm{sup 3} were fabricated. Additional heat treatment was applied to convert the uranium particles into UAl{sub x} compounds by a chemical reaction of the uranium particles and aluminum matrix. Thus, these target plates can be treated with the same alkaline dissolution process that is used for conventional UAl{sub x} dispersion targets, while increasing the uranium density in the target plates.

  2. Determination of the elemental concentration of uranium and thorium in the products and by-products of amang tin tailings process

    Science.gov (United States)

    Alnour, I. A.; Wagiran, H.; Ibrahim, N.; Hamzah, S.; Elias, M. S.

    2017-01-01

    Amang or tin tailing is processed into concentrated ores and other economical valuable minerals such as monazite, zircon, xenotime, ilmenite etc. Besides that, the tailings from these ores may have a significant potential source of radiation exposure to amang plants' workers. This study was conducted to determine the elemental concentration of uranium and thorium in mineral samples collected from five amang tailing factories. The concentration of uranium and thorium was carried out by using instrumental neutron activation analysis (INAA) relative technique. The concentration of uranium and thorium in ppm obtained in this study are as follows: raw (189-1064) and (622-4965); monazite (1076-1988) and (3467-33578); xenotime 4053 and 5540; zircon (309-3090) and (387-6339); ilmenite (104-583) and (88-1205); rutile (212-889) and (44-1119); pyrite (7-43) and (9-132); and waste (5-338) and (9-1218) respectively. The analysis results shows that the monazite, xenotime and zircon have high content of uranium and thorium, whereas ilmenite, rutile, pyrite and waste have lower concentration compare with raw materials after tailing process. The highest values of uranium and thorium concentrations (4053 ± 428 ppm and 33578 ± 873 ppm, respectively) were observed in xenotime and monazite; whereas the lowest value was 5.48 ± 0.86 ppm of uranium recorded in waste (sand) and 9 ± 0.32 ppm of thorium for waste (sand) and pyrite.

  3. Electron Excitation of Tin and Tin ion

    Science.gov (United States)

    Sharma, Lalita; Srivastava, Rajesh

    2014-05-01

    There is a great requirement of accurate atomic data of tin and its ions to understand the properties of laser produced tin plasma, one of the sources of extreme ultraviolet (EUV) radiation. The constant efforts are being made under various international programs viz., International SEMATECH's EUV Source Program, Intel Lithography Roadmap etc., to improve the efficiency of the EUV sources which can meet the requirements of high volume manufacturing of commercial chips. For optimizing the efficiency of EUV device the plasma modeling should be accurate which in turn, would rely on the accuracy of atomic data used. In this connection we have undertaken the study of electron impact excitation of Sn and Sn+. Since the atomic number of Sn is 50, it is sufficiently heavy atom to manifest relativistic spin - orbit and exchange effects. Therefore, we have used a fully relativistic distorted wave (RDW) theory to calculate results for cross sections corresponding to various transitions as well as polarization of photons due to decay of excited states of Sn and Sn+ In our RDW theory wavefunctions for both, the target electrons and projectile electrons are obtained by solving Dirac equations. Thus the relativistic effects are incorporated in consistent manner to ensure the reliability of the cross section and polarization results which will be presented in detail at the conference. Department of Atomic Energy, Govt. of India (DAE-BRNS).

  4. Biodiesel production from marine cyanobacteria cultured in plate and tubular photobioreactors.

    Science.gov (United States)

    Selvan, B Karpanai; Revathi, M; Piriya, P Sobana; Vasan, P Thirumalai; Prabhu, D Immuanual Gilwax; Vennison, S John

    2013-03-01

    Carbon (neutral) based renewable liquid biofuels are alternative to petroleum derived transport fuels that contribute to global warming and are of a limited availability. Microalgae based biofuels are considered as promising source of energy. Lyngbya sp. and Synechococcus sp. were studied for the possibility of biodiesel production in different media such as ASNIII, sea water enrichment medium and BG11. The sea water enrichment medium was found superior in enhancing the growth rate of these microalgae. Nitrogen depletion has less effect in total chlorophyll a content, at the same time the lipid content was increased in both Lyngbya sp. and Synechococcus sp. by 1.4 and 1.2 % respectively. Increase in salinity from 0.5-1.0 M also showed an increase in the lipid content to 2.0 and 0.8 % in these strains; but a salinity of 1.5 M has a total inhibitory effect in the growth. The total biomass yield was comparatively higher in tubular LED photobioreactor than the fluorescent flat plated photobioreactor. Lipid extraction was obtained maximum at 60 degrees C in 1:10 sample: solvent ratio. GC-MS analysis of biodiesel showed high content of polyunsaturated fatty acids (PUFA; 4.86 %) than saturated fatty acid (SFA; 4.10 %). Biodiesel production was found maximum in Synechococcus sp. than Lyngbya sp. The viscosity of the biodiesel was closely related to conventional diesel. The results strongly suggest that marine microalgae could be used as a renewable energy source for biodiesel production.

  5. One Step Internal Tin Nb3Sn Superconductor Fabrication.

    Science.gov (United States)

    1985-03-01

    34" TABLE. OF CONTENTS SECTION PAGE I INTRODUCTION 1 11 TIN PLATING LINEI III RIBBON FABRICATION2 IV EXTRUSION2 V WIRE DRAWING VI HEAT TREATMENT VII...8217 "> >; i ; ,’’ \\>,/ ; -2 ; "--; i > . . .? :-. -. -. .-.- - .. . - I" SECTION V WIRE DRAWING The extruded rod was cut into approximately 15 cm long pieces

  6. TIN-X

    DEFF Research Database (Denmark)

    Cannon, Daniel C; Yang, Jeremy J; Mathias, Stephen L

    2017-01-01

    Motivation: The increasing amount of peer-reviewed manuscripts requires the development of specific mining tools to facilitate the visual exploration of evidence linking diseases and proteins. Results: We developed TIN-X, the Target Importance and Novelty eXplorer, to visualize the association be...

  7. Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe

    CERN Document Server

    Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

    2015-01-01

    TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

  8. Comparison of dry medium culture plates for mesophilic aerobic bacteria in milk, ice cream, ham, and codfish fillet products.

    Science.gov (United States)

    Park, Junghyun; Kim, Myunghee

    2013-12-01

    This study was performed to compare the performance of Sanita-Kun dry medium culture plate with those of traditional culture medium and Petrifilm dry medium culture plate for the enumeration of the mesophilic aerobic bacteria in milk, ice cream, ham, and codfish fillet. Mesophilic aerobic bacteria were comparatively evaluated in milk, ice cream, ham, and codfish fillet using Sanita-Kun aerobic count (SAC), Petrifilm aerobic count (PAC), and traditional plate count agar (PCA) media. According to the results, all methods showed high correlations of 0.989~1.000 and no significant differences were observed for enumerating the mesophilic aerobic bacteria in the tested food products. SAC method was easier to perform and count colonies efficiently as compared to the PCA and PAC methods. Therefore, we concluded that the SAC method offers an acceptable alternative to the PCA and PAC methods for counting the mesophilic aerobic bacteria in milk, ice cream, ham, and codfish fillet products.

  9. Production of Fatty Acids and Protein by Nannochloropsis in Flat-Plate Photobioreactors.

    Science.gov (United States)

    Hulatt, Chris J; Wijffels, René H; Bolla, Sylvie; Kiron, Viswanath

    2017-01-01

    Nannochloropsis is an industrially-promising microalga that may be cultivated for alternative sources of nutrition due to its high productivity, protein content and lipid composition. We studied the growth and biochemical profile of Nannochloropsis 211/78 (CCAP) in optimized flat-plate photobioreactors. Eighteen cultivations were performed at two nutrient concentrations. The fatty acid, protein content and calorific values were analyzed after 8, 12 and 16 days. Neutral lipids were separated and the changes in fatty acids in triglycerides (TAGs) during nutrient depletion were recorded. The maximum cell density reached 4.7 g∙L-1 and the maximum productivity was 0.51 g∙L-1∙d-1. During nutrient-replete conditions, eicosapentaneoic acid (EPA) and total protein concentrations measured 4.2-4.9% and 50-55% of the dry mass, respectively. Nutrient starvation induced the accumulation of fatty acids up to 28.3% of the cell dry weight, largely due to the incorporation of C16:0 and C16:1n-7 fatty acyl chains into neutral lipids. During nutrient starvation the total EPA content did not detectibly change, but up to 37% was transferred from polar membrane lipids to the neutral lipid fraction.

  10. Design of a novel flat-plate photobioreactor system for green algal hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Tamburic, B.; Zemichael, F.W.; Maitland, G.C.; Hellgardt, K. [Imperial College London (United Kingdom)

    2010-07-01

    Some unicellular green algae have the ability to photosynthetically produce molecular hydrogen using sunlight and water. This renewable, carbon-neutral process has the additional benefit of sequestering carbon dioxide during the algal growth phase. The main costs associated with this process result from building and operating a photobioreactor system. The challenge is to design an innovative and cost effective photobioreactor that meets the requirements of algal growth and sustainable hydrogen production. We document the details of a novel 1 litre vertical flat-plate photobioreactor that has been designed to accommodate green algal hydrogen production at the laboratory scale. Coherent, non-heating illumination is provided by a panel of cool white LEDs. The reactor body consists of two compartments constructed from transparent Perspex sheets. The primary compartment holds the algal culture, which is agitated by means of a recirculating gas flow. A secondary compartment is filled with water and used to control the temperature and wavelength of the system. The reactor is fitted with instruments that monitor the pH, pO{sub 2}, temperature and optical density of the culture. A membrane-inlet mass spectrometry system has been developed for hydrogen collection and in situ monitoring. The reactor is fully autoclaveable and the possibility of hydrogen leaks has been minimised. The modular nature of the reactor allows efficient cleaning and maintenance. (orig.)

  11. Enhancement of microalgae production by embedding hollow light guides to a flat-plate photobioreactor.

    Science.gov (United States)

    Sun, Yahui; Huang, Yun; Liao, Qiang; Fu, Qian; Zhu, Xun

    2016-05-01

    To offset the adverse effects of light attenuation on microalgae growth, hollow polymethyl methacrylate (PMMA) tubes were embedded into a flat-plate photobioreactor (PBR) as light guides. In this way, a fraction of incident light could be transmitted and emitted to the interior of the PBR, providing a secondary light source for cells in light-deficient regions. The average light intensity of interior regions 3-6cm from surfaces with 70μmolm(-2)s(-1) incident light was enhanced 2-6.5 times after 3.5days cultivation, resulting in a 23.42% increase in biomass production to that cultivated in PBR without PMMA tubes. The photosynthetic efficiency of microalgae in the proposed PBR was increased to 12.52%. Moreover, the installation of hollow PMMA tubes induced turbulent flow in the microalgae suspension, promoting microalgae suspension mixing. However, the enhanced biomass production was mainly attributed to the optimized light distribution in the PBR. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Production of Fatty Acids and Protein by Nannochloropsis in Flat-Plate Photobioreactors

    Science.gov (United States)

    Wijffels, René H.; Bolla, Sylvie; Kiron, Viswanath

    2017-01-01

    Nannochloropsis is an industrially-promising microalga that may be cultivated for alternative sources of nutrition due to its high productivity, protein content and lipid composition. We studied the growth and biochemical profile of Nannochloropsis 211/78 (CCAP) in optimized flat-plate photobioreactors. Eighteen cultivations were performed at two nutrient concentrations. The fatty acid, protein content and calorific values were analyzed after 8, 12 and 16 days. Neutral lipids were separated and the changes in fatty acids in triglycerides (TAGs) during nutrient depletion were recorded. The maximum cell density reached 4.7 g∙L-1 and the maximum productivity was 0.51 g∙L-1∙d-1. During nutrient-replete conditions, eicosapentaneoic acid (EPA) and total protein concentrations measured 4.2–4.9% and 50–55% of the dry mass, respectively. Nutrient starvation induced the accumulation of fatty acids up to 28.3% of the cell dry weight, largely due to the incorporation of C16:0 and C16:1n-7 fatty acyl chains into neutral lipids. During nutrient starvation the total EPA content did not detectibly change, but up to 37% was transferred from polar membrane lipids to the neutral lipid fraction. PMID:28103296

  13. Application of Microwave Melting for the Recovery of Tin Powder

    Directory of Open Access Journals (Sweden)

    Lei Xu

    2017-06-01

    Full Text Available The present work explores the application of microwave heating for the melting of powdered tin. The morphology and particle size of powdered tin prepared by the centrifugal atomization method were characterized. The tin particles were uniform and spherical in shape, with 90% of the particles in the size range of 38–75 μm. The microwave absorption characteristic of the tin powder was assessed by an estimation of the dielectric properties. Microwave penetration was found to have good volumetric heating on powdered tin. Conduction losses were the main loss mechanisms for powdered tin by microwave heating at temperatures above 150 °C. A 20 kW commercial-scale microwave tin-melting unit was designed, developed, and utilized for production. This unit achieved a heating rate that was at least 10 times higher than those of conventional methods, as well as a far shorter melting duration. The results suggest that microwave heating accelerates the heating rate and shortens the melting time. Tin recovery rate was 97.79%, with a slag ratio of only 1.65% and other losses accounting for less than 0.56%. The unit energy consumption was only 0.17 (kW·h·kg–1—far lower than the energy required by conventional melting methods. Thus, the microwave melting process improved heating efficiency and reduced energy consumption.

  14. Quantifying melt production and degassing rate at mid-ocean ridges from global mantle convection models with plate motion history

    Science.gov (United States)

    Li, Mingming; Black, Benjamin; Zhong, Shijie; Manga, Michael; Rudolph, Maxwell L.; Olson, Peter

    2016-07-01

    The Earth's surface volcanism exerts first-order controls on the composition of the atmosphere and the climate. On Earth, the majority of surface volcanism occurs at mid-ocean ridges. In this study, based on the dependence of melt fraction on temperature, pressure, and composition, we compute melt production and degassing rate at mid-ocean ridges from three-dimensional global mantle convection models with plate motion history as the surface velocity boundary condition. By incorporating melting in global mantle convection models, we connect deep mantle convection to surface volcanism, with deep and shallow mantle processes internally consistent. We compare two methods to compute melt production: a tracer method and an Eulerian method. Our results show that melt production at mid-ocean ridges is mainly controlled by surface plate motion history, and that changes in plate tectonic motion, including plate reorganizations, may lead to significant deviation of melt production from the expected scaling with seafloor production rate. We also find a good correlation between melt production and degassing rate beneath mid-ocean ridges. The calculated global melt production and CO2 degassing rate at mid-ocean ridges varies by as much as a factor of 3 over the past 200 Myr. We show that mid-ocean ridge melt production and degassing rate would be much larger in the Cretaceous, and reached maximum values at ˜150-120 Ma. Our results raise the possibility that warmer climate in the Cretaceous could be due in part to high magmatic productivity and correspondingly high outgassing rates at mid-ocean ridges during that time.

  15. The development of heavy plate production technology%厚板生产技术的发展

    Institute of Scientific and Technical Information of China (English)

    张燕燕; 曹建宁

    2001-01-01

    综述了厚板轧机的发展及其技术改造的特点;介绍了厚板生产TMCP技术的控制环节,立辊轧机的应用以及卷轧中板的生产工艺特点。%The development of heavy plate mill and the common characteristics of the mill revamping were summarized, and the production technologies, such as control links of TMCP, appliction of edger mill and the processing of Steckel mill for plate were introduced.

  16. Moessbauer spectra of tin in float glass

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, J.A. [Liverpool John Moores Univ. (United Kingdom). Sch. of the Built Environ.; Johnson, C.E. [Liverpool Univ. (United Kingdom). Dept. of Physics; Williams, K.F.E. [Liverpool Univ. (United Kingdom). Dept. of Physics; Holland, D. [Warwick Univ., Coventry (United Kingdom). Dept. of Physics; Karim, M.M. [Warwick Univ., Coventry (United Kingdom). Dept. of Physics

    1995-03-01

    Tin is not a major constituent of window glass, but is found at high concentrations in the lower surface of float glass which has been in contact with the molten tin bath. It does not extend far into the surface, but causes the physical and chemical behaviour to differ from that of the upper surface. It is important, therefore, to understand the structural role of tin in silicate glasses and thus its effect on various properties. Moessbauer spectra were taken of three series of glassy materials, namely binary glasses (SnO and SiO{sub 2}) in varying proportions, re-melted float glass containing tin, and float glass from a production plant. The binary glasses contained between 20 and 70% tin which was found to be mainly Sn{sup 2+}, with very small amounts of Sn{sup 4+} in some of them. The spectra showed a small decrease in isomer shift with increase in tine content, which is ascribed to the change in molar volume. The re-melted samples were float glass which was mixed with stannous oxalate in appropriate conditions to try and maintain tin in the 2+ state, and contained up to 15% tin by weight. The spectra show both Sn{sup 4+} and Sn{sup 2+} with rather more in the 4+ oxidation state. The change in the spectra as a function of temperature revealed a large difference in the f-factor (and hence the chemical binding) of the two states. A series of spectra was taken between 17.5 and 900 K for the sample containing 15% tin. From the absorption as a function of temperature the f-factor was determined for both oxidation states, and hence enabled the relative amounts of Sn{sup 4+} and Sn{sup 2+} present in each sample to be estimated. Measurements of the shift as a function of temperature were also made. The float samples were surface material produced by grinding away all but 0.1 mm of the lower surface of industrially produced float glass. The Moessbauer spectra showed them to be predominantly Sn{sup 2+}, as expected from the reducing atmosphere in the float plant.

  17. Enumeration of starter cultures during yogurt production using Petrifilm AC plates associated with acidified MRS and M17 broths.

    Science.gov (United States)

    Gonçalves, Marília M; Freitas, Rosangela; Nero, Luís A; Carvalho, Antônio F

    2009-05-01

    The efficiency of Petrifilm AC (3M Microbiology, St. Paul, MN, USA) associated with the broths M17 and de Mann-Rogosa-Sharpe (MRS) at pH 5.4 was evaluated to enumerate Streptococcus salivarius subsp. thermophilus and Lactobacillus delbrueckii subsp. bulgaricus during the yogurt production. Commercial and reference strains of these microorganisms were experimentally inoculated in nonfat milk and incubated at 42 degrees C for 4 h for yogurt production. At the moment of inoculation and after incubation, aliquots were collected, submitted to dilution using the broths M17 and MRS at pH 5.4, and plated for Strep. salivarius and Lb. bulgaricus enumeration according ISO 9232 and at Petrifilm AC plates, respectively. M17 plates were incubated at 42 degrees C, and MRS plates were incubated at 35 degrees C under anaerobiosis. After 48 h, the formed colonies were enumerated and the counts were compared by correlation and analysis of variance (Pyogurt production, with slight interferences due to the acidity of MRS at the moment of inoculation, and due to the acidity of yogurt at the end of fermentation process. It was also observed that the MRS at pH 5.4 was not sufficiently selective for Lb. delbrueckii enumeration, despite it is indicated by the official protocol from ISO 9232.

  18. Colorimetric visualization of tin corrosion: A method for early stage corrosion detection on printed circuit boards

    DEFF Research Database (Denmark)

    Verdingovas, Vadimas; Jellesen, Morten Stendahl; Ambat, Rajan

    2017-01-01

    A majority of printed circuit board surfaces are covered with tin, therefore tin corrosion under humid conditions and movement of tin ions under the influence of an electric field plays an important role in the corrosion failure development. Tracking tin corrosion products spread on the printed...... a colorimetric tin ion indicator applied as a gel. The examples provided in this paper include visualization of corrosion caused by weak organic acids found in solder fluxes, corrosion profiling on the PCBAs after climatic device level testing, and failure analysis of field returns....

  19. Influence of Negative Bias Voltage on Microparticles Morphology and Pixel Distribution of TiN Coatings Deposited by Multi-arc Ion Plating%负偏压对多弧离子镀TiN涂层大颗粒形貌及像素分布的影响

    Institute of Scientific and Technical Information of China (English)

    陈昌浩; 金永中; 刘东亮; 余学金

    2015-01-01

    Objective To analyze the microparticles ( MPs) morphology and pixel distribution of TiN coatings under different negative bias voltage (0, 100, 200, 300 and 400V), so as to provide basic data for industrial applications of multi-arc ion plating. Methods TiN coatings were deposited on hard alloy surface by multi-arc ion plating at different bias voltage. The surface morpholo- gy of TiN coatings was characterized by scanning electron microscope ( SEM) . At the same time, the amount and size of MPs were analyzed and the distribution of pixel was counted by ImageJ software. Results The amount of MPs on coating surface increased at first and then decreased with the increase of bias voltage. The maximum value was 1364 at 100 V and the minimum was 750 at 300 V. In addition, the area ratio of MPs on coating surface decreased gradually with the increase of bias voltage. The maximum value with worst mechanical properties was 6. 9% at 0 V and the minimum with best mechanical properties was 3. 3% at 400 V. The amount of light and dark pixel reached a maximum of 8302 at 300 V and a minimum of 4067 at 400 V. Conclusion The TiN coa-tings with best mechanical properties, low amount and small size of MPs were deposited at 400 V for 1 h with 30% duty cycle.%目的 分析不同负偏压下TiN涂层表面的大颗粒数量、尺寸和面积以及像素分布,为多弧离子镀技术的工业化应用提供基础数据. 方法 采用多弧离子镀膜技术,以脉冲负偏压为变量,在硬质合金表面沉积TiN涂层. 用扫描电子显微镜对涂层表面形貌进行表征,并利用ImageJ软件对表面大颗粒的数量和尺寸进行分析,对像素分布进行统计. 结果 随着负偏压的增加,涂层表面大颗粒的数量先增多,后减少. 负偏压为100 V时,大颗粒数量最多,为1364;负偏压为300 V时,大颗粒数量最少,为750. 此外随着负偏压的增加,大颗粒所占涂层面积比逐渐减小. 未加负偏压时,涂层表面大颗

  20. Temperature-independent pectin gel method for aerobic plate count in dairy and nondairy food products: collaborative study.

    Science.gov (United States)

    Roth, J N

    1988-01-01

    Ten laboratories participated in a collaborative study to compare the pectin-based plate count (PC) Redigel method with the aerobic plate count and standard plate count agar-based standard methods for the estimation of total bacterial counts in 9 different nondairy food and dairy food products. The foods were cream, homogenized milk, raw milk, cheese, raw chicken, raw oysters, frozen broccoli, flour, and spices. Each laboratory analyzed 6 samples (3 sample pairs) of each food group. Counts obtained by the pectin-based plate count and agar-based plate count methods differed significantly (P less than 0.05) only for homogenized milk, where the pectin gel method resulted in higher counts. The actual counts were higher in the pectin gel method in 8 of the 9 food groups. The log means for pectin gel and agar-based media, respectively, for the 9 food groups were: cream 8.106 and 7.844; homogenized milk 8.642 and 8.231; raw milk 8.711 and 8.423; chicken 7.654 and 7.645; oysters 7.201 and 7.180; broccoli 7.102 and 6.798; cheese 8.045 and 8.055; flour 4.112 and 3.988; spice 5.379 and 5.314. The repeatability standard deviations favored the pectin gel method in 6 of the 9 foods tested. The reproducibility standard deviations favored the pectin gel method in 7 of the 9 foods tested. These results strongly support the suitability of the pectin gel method as an alternative to agar-based plate count and other methods for total bacterial counts in nondairy and dairy food products. The pectin gel method has been adopted official first action.

  1. Hydrolysis of bis(dimethylamido)tin to tin (II) oxyhydroxide and its selective transformation into tin (II) or tin (IV) oxide

    KAUST Repository

    Khanderi, Jayaprakash

    2015-03-01

    Sn6O4(OH)4, a hydrolysis product of Sn(NMe2)2, is transformed to tin (II) or tin (IV) oxide by solid and solution phase processing. Tin (II) oxide is formed by heating Sn6O4(OH)4 at ≤200 °C in air or under inert atmosphere. Tin (IV) oxide nanoparticles are formed in the presence of a carboxylic acid and base in air at room temperature. IR spectroscopy, Raman spectroscopy, thermogravimetry (coupled with infrared spectroscopy), powder X-ray diffraction, high temperature X-ray diffraction, scanning electron and transmission electron microscopy are used for the characterization of Sn6O4(OH)4 and the investigation of its selective decomposition into SnO or SnO2. Spectroscopic and X-ray diffraction results indicate that SnO is formed by the removal of water from crystalline Sn6O4(OH)4. SEM shows octahedral morphology of the Sn6O4(OH)4, SnO and SnO2 with particle size from 400 nm-2 μm during solid state conversion. Solution phase transformation of Sn6O4(OH)4 to SnO2 occurs in the presence of potassium glutarate and oxygen. SnO2 particles are 15-20 nm in size.

  2. Highly conductive thermoplastic composites for rapid production of fuel cell bipolar plates

    Science.gov (United States)

    Huang, Jianhua [Blacksburg, VA; Baird, Donald G [Blacksburg, VA; McGrath, James E [Blacksburg, VA

    2008-04-29

    A low cost method of fabricating bipolar plates for use in fuel cells utilizes a wet lay process for combining graphite particles, thermoplastic fibers, and reinforcing fibers to produce a plurality of formable sheets. The formable sheets are then molded into a bipolar plates with features impressed therein via the molding process. The bipolar plates formed by the process have conductivity in excess of 150 S/cm and have sufficient mechanical strength to be used in fuel cells. The bipolar plates can be formed as a skin/core laminate where a second polymer material is used on the skin surface which provides for enhanced conductivity, chemical resistance, and resistance to gas permeation.

  3. Effects of Conformal Coat on Tin Whisker Growth

    Science.gov (United States)

    Kadesch, Jong S.; Leidecker, Henning; Day, John H. (Technical Monitor)

    2000-01-01

    A whisker from a tin plated part was blamed for the loss of a commercial spacecraft in 1998. Although pure tin finishes are prohibited by NASA, tin plated parts, such as hybrids, relays and commercial off the shelf (COTS) parts, are something discovered to have been installed in NASA spacecraft. Invariably, the assumption is that a conformal coat will prevent the growth of, or short circuits caused by, tin whiskers. This study measures the effect a Uralane coating has on the initiation and growth of tin whiskers, on the ability of this coating to prevent a tin whisker from emerging from the coating, and on the ability to prevent shorting. A sample of fourteen brass substrates (1 inch by 4 inches by 1/16 inch) were plated by two separate processes: half of the specimens were 'bright' tin plated directly over the brass substrate and half received a copper flash over the brass substrate prior to 'bright' tin plating. Each specimen was coated on one half of the substrate with three bi-directional sprays of Uralane 5750 to a nominal thickness of 25 to 75 micrometers (1 to 3 mils). Several specimens of both types, Cu and non-Cu flashed, were placed in an oven maintained at 50 C as others' work suggests that this is the optimal temperature for whisker formation. The remaining specimens were maintained at room ambient conditions. The surfaces of each specimen have been regularly inspected using both optical (15 to 400x power) and Scanning Electronic Microscopy (SEM). Many types of growths, including needle-like whiskers, first appeared approximately three months after plating on the non-conformally coated sides of all specimens. At four months, 4 to 5 times more growth sites were observed on the coated side; however, the density of growth sites on the non-conformally coated side has since increased rapidly, and now, at one year, is about the same for both sides. The density of growth sites is estimated at 90/sq mm with 30 percent of the sites growing whiskers (needle

  4. Three of a Kind: Genetically Similar Tsukamurella Phages TIN2, TIN3, and TIN4.

    Science.gov (United States)

    Dyson, Zoe A; Tucci, Joseph; Seviour, Robert J; Petrovski, Steve

    2015-10-01

    Three Tsukamurella phages, TIN2, TIN3, and TIN4, were isolated from activated sludge treatment plants located in Victoria, Australia, using conventional enrichment techniques. Illumina and 454 whole-genome sequencing of these Siphoviridae viruses revealed that they had similar genome sequences, ranging in size between 76,268 bp and 76,964 bp. All three phages shared 74% nucleotide sequence identity to the previously described Gordonia phage GTE7. Genome sequencing suggested that phage TIN3 had suffered a mutation in one of its lysis genes compared to the sequence of phage TIN4, to which it is genetically very similar. Mass spectroscopy data showed the unusual presence of a virion structural gene in the DNA replication module of phage TIN4, disrupting the characteristic modular genome architecture of Siphoviridae phages. All three phages appeared highly virulent on strains of Tsukamurella inchonensis and Tsukamurella paurometabola. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  5. Estimating the Probability of Electrical Short Circuits from Tin Whiskers. Part 2

    Science.gov (United States)

    Courey, Karim J.; Asfour, Shihab S.; Onar, Arzu; Bayliss, Jon A.; Ludwig, Larry L.; Wright, Maria C.

    2010-01-01

    To comply with lead-free legislation, many manufacturers have converted from tin-lead to pure tin finishes of electronic components. However, pure tin finishes have a greater propensity to grow tin whiskers than tin-lead finishes. Since tin whiskers present an electrical short circuit hazard in electronic components, simulations have been developed to quantify the risk of said short circuits occurring. Existing risk simulations make the assumption that when a free tin whisker has bridged two adjacent exposed electrical conductors, the result is an electrical short circuit. This conservative assumption is made because shorting is a random event that had an unknown probability associated with it. Note however that due to contact resistance electrical shorts may not occur at lower voltage levels. In our first article we developed an empirical probability model for tin whisker shorting. In this paper, we develop a more comprehensive empirical model using a refined experiment with a larger sample size, in which we studied the effect of varying voltage on the breakdown of the contact resistance which leads to a short circuit. From the resulting data we estimated the probability distribution of an electrical short, as a function of voltage. In addition, the unexpected polycrystalline structure seen in the focused ion beam (FIB) cross section in the first experiment was confirmed in this experiment using transmission electron microscopy (TEM). The FIB was also used to cross section two card guides to facilitate the measurement of the grain size of each card guide's tin plating to determine its finish .

  6. Production line of tempering tin bronze-plated bead wire%镀锡青铜回火胎圈钢丝生产线

    Institute of Scientific and Technical Information of China (English)

    滕留芝

    2002-01-01

    详细介绍了镀锡青铜回火胎圈钢丝生产线,包括镀前钢丝工艺和化镀锡青铜生产线的工艺流程、加工技术参数、设备组成及主要工序.采用此生产线生产的镀锡青铜回火胎圈钢丝性能优良,不仅具备在硫化过程中与轮胎橡胶整体达到良好粘合的优势,并且具有在轮胎使用中、后期钢丝与橡胶粘合力稳定的特点.

  7. Neutronic and thermal-hydraulic analysis of fission molybdenum-99 production at Tehran Research Reactor using LEU plate targets.

    Science.gov (United States)

    Abedi, Ebrahim; Ebrahimkhani, Marzieh; Davari, Amin; Mirvakili, Seyed Mohammad; Tabasi, Mohsen; Maragheh, Mohammad Ghannadi

    2016-12-01

    Efficient and safe production of molybdenum-99 ((99)Mo) radiopharmaceutical at Tehran Research Reactor (TRR) via fission of LEU targets is studied. Neutronic calculations are performed to evaluate produced (99)Mo activity, core neutronic safety parameters and also the power deposition values in target plates during a 7 days irradiation interval. Thermal-hydraulic analysis has been also carried out to obtain thermal behavior of these plates. Using Thermal-hydraulic analysis, it can be concluded that the safety parameters are satisfied in the current study. Consequently, the present neutronic and thermal-hydraulic calculations show efficient (99)Mo production is accessible at significant activity values in TRR current core configuration. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Safety assessment of Tin(IV) oxide as used in cosmetics.

    Science.gov (United States)

    Johnson, Wilbur; Bergfeld, Wilma F; Belsito, Donald V; Hill, Ronald A; Klaassen, Curtis D; Liebler, Daniel C; Marks, James G; Shank, Ronald C; Slaga, Thomas J; Snyder, Paul W; Andersen, F Alan

    2014-01-01

    Tin(IV) oxide functions as an abrasive, bulking, and opacifying agent in cosmetic products and is used at concentrations up to 0.4% in rinse-off products and up to 1.3% in leave-on products. The Cosmetic Ingredient Review Expert Panel (Panel) noted that tin(IV) oxide is a water-insoluble inorganic metal compound and should not be percutaneously absorbed; therefore, systemic exposure is not likely. Studies of dermal application of tin(IV) oxide were considered to determine toxicity at the site of application. The Panel concluded that tin(IV) oxide is safe in the present practices of use and concentration.

  9. EarthScope: Cyberinfrastructure to access Plate Boundary Observatory data products and services

    Science.gov (United States)

    Meertens, C. M.; Mattioli, G. S.; Miller, M.; Boler, F. M.; Crosby, C. J.; Mencin, D.; Phillips, D. A.; Snett, L.

    2013-12-01

    The wealth of data from geodetic observing systems, especially the Plate Boundary Observatory (PBO), presents major data management challenges. The challenges are driven by ingenious new uses of Global Positioning System (GPS) data, demands for higher-rate, lower latency data, the need for continued access and long term preservation of archival data, the expansion of data users into other science, engineering and commercial arenas, and the growth of enhanced products that expand the utility of the data. To meet these challenges, UNAVCO has established a comprehensive suite of data services encompassing sensor network data operations, data product generation (through the activities of partners at Massachusetts Institute of Technology, Central Washington University, New Mexico Institute of Mining and Technology, and the University of California, San Diego - UCSD), data management, access and archiving, and advanced cyberinfrastructure. PBO sensor systems include 1,100 continuously operating GPS stations, 79 borehole geophysical sites (with a combination of strainmeters, tiltmeters, seismometers, pore pressure gauges, and meteorological sensors), and 6 long baseline strainmeters. Imaging data acquired for EarthScope include large volumes of satellite synthetic aperture radar (SAR) and airborne LiDAR data. Core data products such as daily GPS position time series and derived crustal motion velocities have been augmented with real-time data streams and positions calculated every second from 367 PBO stations. Higher rate (5 Hz) data files are available for applications such as GPS seismology. Efforts are underway with UCSD to integrate GPS and accelerometers at a subset of PBO sites to increase the reliability and capability of the observations. These observations have utility for research and hazards mitigation. Ingenious methods of GPS data analysis, developed by the University of Colorado and the University Corporation for Atmospheric Research, measure snow depth

  10. Iron Documents. Interdisciplinary studies on the technology of late medieval european plate armour production between 1350 and 1500

    OpenAIRE

    Goll, Matthias

    2014-01-01

    Abstract The purpose of this study is to find out details on the production of late medieval European plate-armour for the field-use. Therefore, the author first collected thousands of extant objects in a database. With this stock of data he then was able to cluster and to structure the armour parts by various typological and technological aspects. To ease the access to the topic, the author defined an understandable and standardized terminology and typology for the different variations of...

  11. Correlation between Agar Plate Screening and Solid-State Fermentation for the Prediction of Cellulase Production by Trichoderma Strains

    Directory of Open Access Journals (Sweden)

    Camila Florencio

    2012-01-01

    Full Text Available The viability of converting biomass into biofuels and chemicals still requires further development towards the reduction of the enzyme production costs. Thus, there is a growing demand for the development of efficient procedures for selection of cellulase-producing microorganisms. This work correlates qualitative screening using agar plate assays with quantitative measurements of cellulase production during cultivation under solid-state fermentation (SSF. The initial screening step consisted of observation of the growth of 78 preselected strains of the genus Trichoderma on plates, using microcrystalline cellulose as carbon source. The 49 strains that were able to grow on this substrate were then subjected to a second screening step using the Congo red test. From this test it was possible to select 10 strains that presented the highest enzymatic indices (EI, with values ranging from 1.51 to 1.90. SSF cultivations using sugarcane bagasse and wheat bran as substrates were performed using selected strains. The CG 104NH strain presented the highest EGase activity (25.93 UI·g−1. The EI results obtained in the screening procedure using plates were compared with cellulase production under SSF. A correlation coefficient (R2 of 0.977 was obtained between the Congo red test and SSF, demonstrating that the two methodologies were in good agreement.

  12. Plate Boundary Observatory Infrastructure and Data Products in Education and Outreach

    Science.gov (United States)

    Eriksson, S. C.; Barbour, K.; Lee, E.

    2005-12-01

    As one of three major components of NSF's EarthScope program, the Plate Boundary Observatory (PBO) encourages the integration of research and education. Informing various communities about the current work of PBO and the scientific discoveries related to the use of this instrumentation has contributed to the success of PBO during the first two years of the EarthScope project. UNAVCO(PBO), IRIS (USArray), and the EarthScope project office work together to integrate Education and Outreach (E&O) opportunities into a program that is greater than the sum of its parts and yet maintains the identity of each organization. Building and maintaining the PBO website, documenting and archiving activities of PBO, providing short courses for professional development of scientists using EarthScope data, and developing higher level data products with an appropriate educational framework are a few of the activities that provide both challenges and opportunities. The internet, particularly the World Wide Web, has become the primary tool for disseminating information to various audiences. The primary goals of the PBO website are to provide current information on the progress of GPS and Strainmeter facility construction; to provide access to different levels of data products; and to facilitate networking with and among scientists. Challenges for the PBO website include publishing current stories on installation projects while coordinating with field engineers on a regular basis; providing near to real time updates and maintaining quality assurance processes; and defining personnel requirements for a maintaining a dynamic website. Currently, archived photographs, web diaries, and numerous web highlights document PBO's success and provide a visual record of PBO's accomplishments and behind-the-scene activities over the last two years. The community charged PBO with increasing the number of scientists using its data. UNAVCO does this by providing short courses for professional development

  13. Extraction and Separation of Tin from Tin-Bearing Secondary Resources: A Review

    Science.gov (United States)

    Su, Zijian; Zhang, Yuanbo; Liu, Bingbing; Lu, Manman; Li, Guanghui; Jiang, Tao

    2017-08-01

    The proven global tin reserves were reported to be approximately 4.7 million tons (Mts) in 2016, and among these resources, only approximately 2.2 Mts can be recovered economically. The original tin deposits will be exhausted in several years, therefore, tin-bearing secondary resources, such as tin alloy, tin anode slime, e-wastes, tin slag and tin-bearing tailings, will become the primary source from which tin can be extracted. Many investigations have been conducted on the recovery of tin from these tin-bearing materials. However, the separation and recovery approaches of tin vary significantly, since the content and phase compositions of tin are totally different in these secondary resources. This paper reviews these methods of extracting and separating tin from different kinds of tin-bearing secondary resources.

  14. NASA GSFC Tin Whisker Homepage http://nepp.nasa.gov/whisker

    Science.gov (United States)

    Shaw, Harry

    2000-01-01

    The NASA GSFC Tin Whisker Homepage provides general information and GSFC Code 562 experimentation results regarding the well known phenomenon of tin whisker formation from pure tin plated substrates. The objective of this www site is to provide a central repository for information pertaining to this phenomenon and to provide status of the GSFC experiments to understand the behavior of tin whiskers in space environments. The Tin Whisker www site is produced by Code 562. This www site does not provide information pertaining to patented or proprietary information. All of the information contained in this www site is at the level of that produced by industry and university researchers and is published at international conferences.

  15. NASA GSFC Tin Whisker Homepage http://nepp.nasa.gov/whisker

    Science.gov (United States)

    Shaw, Harry

    2000-01-01

    The NASA GSFC Tin Whisker Homepage provides general information and GSFC Code 562 experimentation results regarding the well known phenomenon of tin whisker formation from pure tin plated substrates. The objective of this www site is to provide a central repository for information pertaining to this phenomenon and to provide status of the GSFC experiments to understand the behavior of tin whiskers in space environments. The Tin Whisker www site is produced by Code 562. This www site does not provide information pertaining to patented or proprietary information. All of the information contained in this www site is at the level of that produced by industry and university researchers and is published at international conferences.

  16. Experiences With The Reactive Low Voltage Ion Plating In Optical Thin Film Production

    Science.gov (United States)

    Guertler, Karlheinz; Jeschkowski, Ulrich; Conrath, E.

    1989-02-01

    The transmission of interference filters consisting of Ta205, Ti02, Zr02 and Si02 layers were measured at temperatures between 25°C and 185°C. Some characteristic differences between filters produced by reactive evaporation and reactive ion plating are demonstrated and discussed.

  17. Tin-containing silicates

    DEFF Research Database (Denmark)

    Osmundsen, Christian M.; Holm, Martin Spangsberg; Dahl, Søren

    2012-01-01

    The selective conversion of biomass-derived substrates is one of the major challenges facing the chemical industry. Recently, stannosilicates have been employed as highly active and selective Lewis acid catalysts for a number of industrially relevant reactions. In the present work, four different...... stannosilicates have been investigated: Sn-BEA, Sn-MFI, Sn-MCM-41 and Sn-SBA-15. When comparing the properties of tin sites in the structures, substantial differences are observed. Sn-beta displays the highest Lewis acid strength, as measured by probe molecule studies using infrared spectroscopy, which gives...... it a significantly higher activity at low temperatures than the other structures investigated. Furthermore, the increased acid strength translates into large differences in selectivity between the catalysts, thus demonstrating the influence of the structure on the active site, and pointing the way forward...

  18. Continious production of exfoliated graphite composite compositions and flow field plates

    Science.gov (United States)

    Shi, Jinjun; Zhamu, Aruna; Jang, Bor Z.

    2010-07-20

    A process of continuously producing a more isotropic, electrically conductive composite composition is provided. The process comprises: (a) continuously supplying a compressible mixture comprising exfoliated graphite worms and a binder or matrix material, wherein the binder or matrix material is in an amount of between 3% and 60% by weight based on the total weight of the mixture; (b) continuously compressing the compressible mixture at a pressure within the range of from about 5 psi or 0.035 MPa to about 50,000 psi or 350 MPa in at least a first direction into a cohered graphite composite compact; and (c) continuously compressing the composite compact in a second direction, different from the first direction, to form the composite composition in a sheet or plate form. The process leads to composite plates with exceptionally high thickness-direction electrical conductivity.

  19. 电感耦合等离子体质谱法测定高纯镍板中砷锡锑铅铋%Determination of arsenic, tin, antimony, lead and bismuth in high-purity nickel plate by inductively coupled plasma mass spectrometry

    Institute of Scientific and Technical Information of China (English)

    赵琎; 胡建春

    2015-01-01

    采用10 mL硝酸(1+1)低温加热至沸溶解0.1000 g试样,在优化仪器参数的基础上,通过选择合适的同位素以避免质谱干扰和采用标准加入法绘制校准曲线以消除基体效应,建立了电感耦合等离子体质谱法( ICP-MS)测定高纯镍板中砷、锡、锑、铅、铋的方法。各元素校准曲线的相关系数为0.9992~0.9999,方法检出限为0.009~0.047μg/g。方法应用于高纯镍板实际样品分析,测得结果的相对标准偏差( RSD, n=9)为2.4%~5.4%,加标回收率为95%~106%。方法测定高纯镍板实际样品的结果与原子吸收光谱法( AAS)相吻合。%0. 100 0 g of sample was dissolved with 10 mL of nitric acid (1+1) by heating from low temperature to boiling. Based on the optimization of instrumental parameters, the mass spectrometry interference was avoided by selecting proper isotope, and the calibration curve was plotted by standard addition method to eliminate the matrix effect. Consequently, a determination method of arsenic, tin, antimony, lead and bismuth in high-purity nickel plate was established by inductively coupled plasma mass spectrometry ( ICP-MS ) . The correlation coefficient of calibration curve for each element was between 0. 999 2 and 0. 999 9 . The detection limit of method was 0. 009-0. 047 μg/g. The proposed method was applied to the analysis of high purity nickel plate actual sample. The rela-tive standard deviation (RSD, n=9) was 2. 4%-5. 4%, and the recoveries were between 95% and 106%. The determination results of high purity nickel plate actual sample were consistent with those obtained by atomic absorp-tion spectrometry ( AAS) .

  20. Ion-assisted sputtering on TiN films

    Energy Technology Data Exchange (ETDEWEB)

    Musil, J.; Kadlec, S. (Inst. of Physics, Czechoslovak Academy of Sciences, Prague (Czechoslovakia)); Valvoda, V.; Kuzel, R. Jr.; Cerny, R. (Dept. of Semiconductor Physics, Charles Univ., Prague (Czechoslovakia))

    1990-12-05

    Ion bombardment of growing films is one of the possible ways to produce films with specific properties. As yet there are no general rules for the production of these films. The quality of TiN films produced depends on the deposition conditions. A sharp transition from porous, black TiN films to compact, dense, bright gold TiN films is observed at a substrate bias U{sub s} of about -40 V. Recent experiments have indicated that the microstructure of TiN films and the transition mentioned above can be controlled by the ion energy delivered to the growing film per deposited particle E{sub p}=eU{sub s}{nu}{sub i}/{nu}{sub m}. This paper investigates the transition from porous, soft TiN films with a zone I microstructure to compact, hard TiN films with a zone T microstructure as a function of i{sub s}, U{sub s} and the deposition rate a{sub D} at constant temperature T{sub s}=350deg C and pressure p{sub T}=5 Pa. Correlations between the microhardness HV, the macrostress, {sigma}, the microstrain, e, the lattice parameters, the intensities of the X-ray reflections and the colour and appearance of the film are discussed. The zone I to zone T transition is observed at E{sub p}{approx equal}150 eV atom{sup -1}. (orig.).

  1. Determination of total tin in canned food using inductively coupled plasma atomic emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Perring, Loic; Basic-Dvorzak, Marija [Department of Quality and Safety Assurance, Nestle Research Centre, P.O. Box 44, Vers chez-les-Blanc, 1000, Lausanne (Switzerland)

    2002-09-01

    Tin is considered to be a priority contaminant by the Codex Alimentarius Commission. Tin can enter foods either from natural sources, environmental pollution, packaging material or pesticides. Higher concentrations are found in processed food and canned foods. Dissolution of the tinplate depends on the of food matrix, acidity, presence of oxidising reagents (anthocyanin, nitrate, iron and copper) presence of air (oxygen) in the headspace, time and storage temperature. To reduce corrosion and dissolution of tin, nowadays cans are usually lacquered, which gives a marked reduction of tin migration into the food product. Due to the lack of modern validated published methods for food products, an ICP-AES (Inductively coupled plasma-atomic emission spectroscopy) method has been developed and evaluated. This technique is available in many laboratories in the food industry and is more sensitive than atomic absorption. Conditions of sample preparation and spectroscopic parameters for tin measurement by axial ICP-AES were investigated for their ruggedness. Two methods of preparation involving high-pressure ashing or microwave digestion in volumetric flasks were evaluated. They gave complete recovery of tin with similar accuracy and precision. Recoveries of tin from spiked products with two levels of tin were in the range 99{+-}5%. Robust relative repeatabilities and intermediate reproducibilities were <5% for different food matrices containing >30 mg/kg of tin. Internal standard correction (indium or strontium) did not improve the method performance. Three emission lines for tin were tested (189.927, 283.998 and 235.485 nm) but only 189.927 nm was found to be robust enough with respect to interferences, especially at low tin concentrations. The LOQ (limit of quantification) was around 0.8 mg/kg at 189.927 nm. A survey of tin content in a range of canned foods is given. (orig.)

  2. Scalable Production of the Silicon-Tin Yin-Yang Hybrid Structure with Graphene Coating for High Performance Lithium-Ion Battery Anodes.

    Science.gov (United States)

    Jin, Yan; Tan, Yingling; Hu, Xiaozhen; Zhu, Bin; Zheng, Qinghui; Zhang, Zijiao; Zhu, Guoying; Yu, Qian; Jin, Zhong; Zhu, Jia

    2017-05-10

    Alloy anodes possessed of high theoretical capacity show great potential for next-generation advanced lithium-ion battery. Even though huge volume change during lithium insertion and extraction leads to severe problems, such as pulverization and an unstable solid-electrolyte interphase (SEI), various nanostructures including nanoparticles, nanowires, and porous networks can address related challenges to improve electrochemical performance. However, the complex and expensive fabrication process hinders the widespread application of nanostructured alloy anodes, which generate an urgent demand of low-cost and scalable processes to fabricate building blocks with fine controls of size, morphology, and porosity. Here, we demonstrate a scalable and low-cost process to produce a porous yin-yang hybrid composite anode with graphene coating through high energy ball-milling and selective chemical etching. With void space to buffer the expansion, the produced functional electrodes demonstrate stable cycling performance of 910 mAh g(-1) over 600 cycles at a rate of 0.5C for Si-graphene "yin" particles and 750 mAh g(-1) over 300 cycles at 0.2C for Sn-graphene "yang" particles. Therefore, we open up a new approach to fabricate alloy anode materials at low-cost, low-energy consumption, and large scale. This type of porous silicon or tin composite with graphene coating can also potentially play a significant role in thermoelectrics and optoelectronics applications.

  3. Production of furfural from xylose, water-insoluble hemicelluloses and water-soluble fraction of corncob via a tin-loaded montmorillonite solid acid catalyst.

    Science.gov (United States)

    Li, Huiling; Ren, Junli; Zhong, Linjie; Sun, Runcang; Liang, Lei

    2015-01-01

    The conversion of xylose, water-insoluble hemicelluloses (WIH) and water-soluble fraction (WSF) of corncob to furfural was performed using montmorillonite with tin ions (Sn-MMT) containing double acid sites as a solid acid catalyst. The co-existence of Lewis acids and Brønsted acids in Sn-MMT was shown to improve the furfural yield and selectivity. 76.79% furfural yield and 82.45% furfural selectivity were obtained from xylose using Sn-MMT as a catalyst in a biphasic system with 2-s-butylphenol (SBP) as the organic extracting layer and dimethyl sulfoxide (DMSO) as the co-solvent in contact with an aqueous phase saturated with NaCl (SBP/NaCl-DMSO) at 180°C for 30min. Furthermore, Sn-MMT also demonstrated the excellent catalytic performance in the conversion of pentose-rich materials of corncob and 39.56% and 54.15% furfural yields can be directly obtained from WIH and WSF in the SBP/NaCl-DMSO system, respectively.

  4. Production of Fission Product 99Mo using High-Enriched Uranium Plates in Polish Nuclear Research Reactor MARIA: Technology and Neutronic Analysis

    Directory of Open Access Journals (Sweden)

    Jaroszewicz Janusz

    2014-07-01

    Full Text Available The main objective of 235U irradiation is to obtain the 99mTc isotope, which is widely used in the domain of medical diagnostics. The decisive factor determining its availability, despite its short lifetime, is a reaction of radioactive decay of 99Mo into 99mTc. One of the possible sources of molybdenum can be achieved in course of the 235U fission reaction. The paper presents activities and the calculation results obtained upon the feasibility study on irradiation of 235U targets for production of 99Mo in the MARIA research reactor. Neutronic calculations and analyses were performed to estimate the fission products activity for uranium plates irradiated in the reactor. Results of dummy targets irradiation as well as irradiation uranium plates have been presented. The new technology obtaining 99Mo is based on irradiation of high-enriched uranium plates in standard reactor fuel channel and calculation of the current fission power generation. Measurements of temperatures and the coolant flow in the molybdenum installation carried out in reactor SAREMA system give online information about the current fission power generated in uranium targets. The corrective factors were taken into account as the heat generation from gamma radiation from neighbouring fuel elements as well as heat exchange between channels and the reactor pool. The factors were determined by calibration measurements conducted with aluminium mock-up of uranium plates. Calculations of fuel channel by means of REBUS code with fine mesh structure and libraries calculated by means of WIMS-ANL code were performed.

  5. Production of Copper-Plated Beamline Bellows and Spools for LCLS-II

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Katherine M. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Carpenter, Brian C. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Daly, Ed [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Huque, Naeem A. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Peshehonoff, Ted [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Arkan, Tug [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States); Lunin, A. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States); Premo, K. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States)

    2017-05-01

    The SLAC National Accelerator Laboratory is currently constructing a major upgrade to its accelerator, the Linac Coherent Light Source II (LCLS-II). Several Department of Energy national laboratories, including the Thomas Jefferson National Accelerator Facility (JLab) and Fermi National Accelerator Laboratory (FNAL), are participating in this project. The 1.3-GHz cryomodules for this project consist of eight cavities separated by bellows (expansion joints) and spools (tube sections), which are copper plated for RF conduction. JLab is responsible for procurement of these bellows and spools, which are delivered to JLab and FNAL for assembly into cryomodules. Achieving accelerator-grade copper plating is always a challenge and requires careful specification of requirements and application of quality control processes. Due to the demanding technical requirements of this part, JLab implemented procurement strategies to make the process more efficient as well as provide process redundancy. This paper discusses the manufacturing challenges that were encountered and resolved, as well as the strategies that were employed to minimize the impact of any technical issues.

  6. Proton transport properties of tin phosphate, chromotropic acid anchored onto tin phosphate and tin phenyl phosphonate

    Indian Academy of Sciences (India)

    Chithra Sumej; P P Sharmila; Nisha J Tharayil; S Suma

    2013-02-01

    Tin (IV) phosphates of the class of tetravalent metal acid (TMA) salts have been synthesized by sol–gel method. The functionalized materials of tin (IV) phosphate (SnP) like chromotropic acid anchored tin phosphate (SnPCA) and tin phenyl phosphonate (SnPP) were also synthesized. These materials have been characterized for elemental analysis (ICP–AES), thermal analysis, X-ray analysis and FTIR spectroscopy. Chemical resistivity of these materials has been accessed in acidic, basic and organic solvent media. The proton present in the structural hydroxyl groups indicates good potential for TMA salts to exhibit solid-state proton conduction. The transport properties of these materials have been explored by measuring specific proton conductance at different temperatures. Based on the specific conduction data and Arrhenius plots, a suitable mechanism has been proposed.

  7. Development of a brazing process for the production of water- cooled bipolar plates made of chromium-coated metal foils for PEM fuel cells

    Science.gov (United States)

    Mueller, M.; Hoehlich, D.; Scharf, I.; Lampke, T.; Hollaender, U.; Maier, H. J.

    2016-03-01

    Beside lithium batteries, PEM fuel cells are the most promising strategy as a power source to achieve the targets for introducing and increasing the usage of electric vehicles. Due to limited space and weight problems, water cooled, metallic bipolar plates in a fuel cell metal stack are preferred in motor vehicles. These plates are stamped metal sheets with a complex structure, interconnected media-tight. To meet the multiple tasks and requirements in use, complex and expensive combinations of materials are currently in use (carbon fiber composites, graphite, gold-plated nickel, stainless and acid resistant steel). The production of such plates is expensive as it is connected with considerable effort or the usage of precious metals. As an alternative, metalloid nitrides (CrN, VN, W2N, etc.) show a high chemical resistance, hardness and a good conductivity. So this material category meets the basic requirements of a top layer. However, the standard methods for their production (PVD, CVD) are expensive and have a slow deposition rate and a lower layer thicknesses. Because of these limitations, a full functionality over the life cycle of a bipolar plate is not guaranteed. The contribution shows the development and quantification of an alternative production process for bipolar plates. The expectation is to get significant advantages from the combination of chromium electrodeposition and thermochemical treatment to form chromium nitrides. Both processes are well researched and suitable for series production. The thermochemical treatment of the chromium layer also enables a process-integrated brazing.

  8. An optimized process for the production of advanced planar wire grid plates as detectors for high energy physics experiments

    CERN Document Server

    Iacopi, F; Pins, R; Van Hook, R I; Honore, M; Zhukov, V; Van Lancker, L; Van Doninck, W K; Beyne, E

    2001-01-01

    This paper introduces a novel production technique for the planar wire grid plates of microstrip gas chambers (MSGCs, gaseous particle detectors), taking advantage from the typical thin film metallization technologies. The aim of the work here presented has been to manufacture MSGC substrates which can meet the challenging requirements proper to particle tracking detectors in highly ionizing environments. These requirements are mainly represented by high reliability and robustness, since the devices are supposed to operate efficiently for at least 10 years in the extremely hostile conditions foreseen at the large hadron collider at CERN (CH). A detailed process description will be given and results will be analyzed both from the production point of view and from the application of the manufactured prototypes as detectors for high energy physics experiments. (7 refs).

  9. 卷轧中厚板生产工艺中的母板分离策略分析与探讨%Analysis and Discussion of Mother Plate Separation Strategy in Coil Plate Production Process

    Institute of Scientific and Technical Information of China (English)

    沈继刚

    2014-01-01

    在卷轧中厚板生产工艺的基础上,重点论述其核心工艺母板分离策略的具体实施办法,并对影响分离策略的工艺速度和工序间距两个主要因素进行了详细分析和探讨。%On the basis of coil plate production process,the paper describes the details of mother plate separation strategy,analyzes and discusses two major factors of process speed and procedure space affecting the separation strate-gy.

  10. Commerce Ministry Announced the Export Quotas for Zinc,Antimony,Tungsten,Tin and Silver

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正> The Ministry of Commerce recently announcedits decision on the export quotas for zinc,anti-mony,tungsten,tin and silver in 2004.Accord-ing to the data released,all the export quotasare reduced except for silver.Relevant peoplesay that the raw materials shortage is a majorissue for the production of antimony and tin,

  11. Developing an Empirical Model for Estimating the Probability of Electrical Short Circuits from Tin Whiskers. Part 2

    Science.gov (United States)

    Courey, Karim J.; Asfour, Shihab S.; Onar, Arzu; Bayliss, Jon A.; Ludwig, Larry L.; Wright, Maria C.

    2009-01-01

    To comply with lead-free legislation, many manufacturers have converted from tin-lead to pure tin finishes of electronic components. However, pure tin finishes have a greater propensity to grow tin whiskers than tin-lead finishes. Since tin whiskers present an electrical short circuit hazard in electronic components, simulations have been developed to quantify the risk of said short circuits occurring. Existing risk simulations make the assumption that when a free tin whisker has bridged two adjacent exposed electrical conductors, the result is an electrical short circuit. This conservative assumption is made because shorting is a random event that had an unknown probability associated with it. Note however that due to contact resistance electrical shorts may not occur at lower voltage levels. In our first article we developed an empirical probability model for tin whisker shorting. In this paper, we develop a more comprehensive empirical model using a refined experiment with a larger sample size, in which we studied the effect of varying voltage on the breakdown of the contact resistance which leads to a short circuit. From the resulting data we estimated the probability distribution of an electrical short, as a function of voltage. In addition, the unexpected polycrystalline structure seen in the focused ion beam (FIB) cross section in the first experiment was confirmed in this experiment using transmission electron microscopy (TEM). The FIB was also used to cross section two card guides to facilitate the measurement of the grain size of each card guide's tin plating to determine its finish.

  12. Tin-Silver Alloys for Flip-Chip Bonding Studied with a Rotating Cylinder Electrode

    DEFF Research Database (Denmark)

    Tang, Peter Torben; Pedersen, E.H.; Bech-Nielsen, G.

    1999-01-01

    below pure tin). Depositions on a rotating cylinder electrode (with current screen), followed by composition measurements, provided useful information on the relationship between current density and alloy composition. Preliminary experiments with alloy plating on silicon substrates, with and without......Electrodeposition of solder for flip-chip bonding is studied in the form of a pyrophosphate/iodide tin-silver alloy bath. The objective is to obtain a uniform alloy composition, with 3.8 At.% silver, over a larger area. This specific alloy will provide an eutectic solder melting at 221°C (or 10°C...... photoresist, have shown a stable and promising alternative to pure tin and tin-lead alloys for flip-chip bonding applications....

  13. Chalco’s 150,000-ton Aluminum Plate and Strip Project to Be Put into Production In the Second Half of This Year

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>According to Guiyang Municipal Government Office,with an investment of 712 million yuan,Chalco’s aluminum plate and strip project with an annual production capacity of 150,000 tons will be completed and put into production in the second half of this year.

  14. 中厚铝板表面处理及自动垛板生产线的研发%Research and development of aluminum plate surface treatment and automatic staking-plate production line

    Institute of Scientific and Technical Information of China (English)

    徐鸿钧; 葛延; 王廣收; 胡建华; 彭兵

    2011-01-01

    介绍了中国重型机械研究院为西南铝业有限公司中厚板车间设计成套的成品板材表面处理及真空吸附自动垛板生产线.该生产线采用了喷码机喷头防碰撞保护技术,板材运行纠偏技术,高精度的长、宽方向定位技术,高精度、高可靠性吸盘搬运装置、衬纸、覆膜技术等一系列新技术,具有对铝板表面进行自动清刷、喷码、对中、堆垛、衬纸等功能.基于PLC自动控制系统,采用集中监控管理,分散控制的多层次自动化系统,适用于实际生产中多规格的板材.生产线投产以来,运行稳定,性能指标达到设计要求.%The paper describes a complete set of finished aluminum plate surface treatment and vacuum absorption automatic plate staking-plate production line designed by China Heavy Machinery Research Institute for plate workshop of Southwest Aluminum(Group) Co. , Ltd.. This production line uses a series of new technologies such as anticollision protection for printers head, correcting a deviation in plate running, high-precision positioning for length and width, high-precision and high-reliability sucker handling device, paper backing and membrane-coveting. It has the functions of automatic cleaning, centering, stacking, and lining paper for aluminum plate surface. Based on PLC automatic control system, it uses the multi-level automation system of centralized monitoring management and decentralized control, which is suitable for plates of various sizes in the practical production. Since being put into production line, its operation is stable and all performance indexes are up to the design requirements.

  15. Assessment of organotin and tin-free antifouling paints contamination in the Korean coastal area.

    Science.gov (United States)

    Lee, Mi-Ri-Nae; Kim, Un-Jung; Lee, In-Seok; Choi, Minkyu; Oh, Jeong-Eun

    2015-10-15

    Twelve organotins (methyl-, octyl-, butyl-, and phenyl-tin), and eight tin-free antifouling paints and their degradation products were measured in marine sediments from the Korean coastal area, and Busan and Ulsan bays, the largest harbor area in Korea. The total concentration of tin-free antifouling paints was two- to threefold higher than the total concentration of organotins. Principal component analysis was used to identify sites with relatively high levels of contamination in the inner bay area of Busan and Ulsan bays, which were separated from the coastal area. In Busan and Ulsan bays, chlorothalonil and DMSA were more dominant than in the coastal area. However, Sea-Nine 211 and total diurons, including their degradation products, were generally dominant in the Korean coastal area. The concentrations of tin and tin-free compounds were significantly different between the east and west coasts.

  16. Polymorphic transition of tin under shock wave compression: Experimental results

    Directory of Open Access Journals (Sweden)

    Sinatti F.

    2012-08-01

    Full Text Available In this work, the β-bct polymorphic transition in tin is investigated by means of plate impact experiments. The Sn target surface is observed in a partially released state obtained thanks to a transparent lithium fluoride (LiF anvil. We report both measurements of interface velocity and temperature obtained using Photon Doppler Velocimetry and IR optical pyrometer on shock-loaded tin from 8 to 16 GPa. We show that the Mabire Model EOS associated to the SCG plasticity model provides an overall good estimate of the velocity profiles. However, depnding on the shock amplitude, its prediction of the temperature profile may be less satisfactory, hence underlining the need for future improvements in terms of phase transition kinetics description.

  17. Evaluation of possibilities of using tetra - pak waste as a material to plate production for construction industry

    Directory of Open Access Journals (Sweden)

    K. Korniejenko

    2010-07-01

    Full Text Available Tetra-pak is a popular packing material, which is using as aseptic packaging of liquid food products, especially: fruit juice, beverages and milk. After single use a packing are throw out. Carton could not be reuse because the material has contact with food and must be aseptic. The paper describes the way of recycling tetra-pak waste in the world. It is focus on possibilities to optimize the mechanical properties of composite material and modifications of its property depending on the type and amount of added polyethylene and method of manufacture. Main physic-mechanical properties of plate made from tetra – pak waste are presented. This property can be interesting for the construction industry.

  18. Formation of orthorhombic tin dioxide from mechanically milled monoxide powders

    Science.gov (United States)

    Lamelas, F. J.

    2004-12-01

    X-ray scattering measurements are used to show that the metastable orthorhombic phase of tin dioxide is produced by the oxidation of mechanically milled litharge-phase tin monoxide. After milling to a grain size of approximately 20nm, followed by heating to 575°C, the fraction of the orthorhombic phase is approximately 80%. The orthorhombic phase was originally observed in high-pressure experiments, but more recently, it has been produced in a wide variety of thin-film and nanoparticle samples. The data presented here demonstrate the importance of small-grain-size tin monoxide as a precursor in the ambient-pressure synthesis of the orthorhombic phase. This result has practical importance in the production of tin dioxide gas sensors. A more fundamental observation is that the particle size of a precursor phase can have a marked effect on subsequent phases produced during oxidation. Lastly, a formula for determining the orthorhombic fraction in two-phase tin dioxide samples is developed using the method of standard additions.

  19. Stabilized tin-oxide-based oxidation/reduction catalysts

    Science.gov (United States)

    Jordan, Jeffrey D. (Inventor); Schryer, David R. (Inventor); Davis, Patricia P. (Inventor); Leighty, Bradley D. (Inventor); Watkins, Anthony Neal (Inventor); Schryer, Jacqueline L. (Inventor); Oglesby, Donald M. (Inventor); Gulati, Suresh T. (Inventor); Summers, Jerry C. (Inventor)

    2008-01-01

    The invention described herein involves a novel approach to the production of oxidation/reduction catalytic systems. The present invention serves to stabilize the tin oxide reducible metal-oxide coating by co-incorporating at least another metal-oxide species, such as zirconium. In one embodiment, a third metal-oxide species is incorporated, selected from the group consisting of cerium, lanthanum, hafnium, and ruthenium. The incorporation of the additional metal oxide components serves to stabilize the active tin-oxide layer in the catalytic process during high-temperature operation in a reducing environment (e.g., automobile exhaust). Moreover, the additional metal oxides are active components due to their oxygen-retention capabilities. Together, these features provide a mechanism to extend the range of operation of the tin-oxide-based catalyst system for automotive applications, while maintaining the existing advantages.

  20. Recovery of antimony-125 from tin-124 irradiated by neutrons

    Science.gov (United States)

    Baluev, A. V.; Mityakhina, V. S.; Krasnikov, L. V.; Galkin, B. Ya.; Besnosyuk, V. I.

    2003-01-01

    Separation of 125Sb from tin using highly basic, medium-basic, and weakly basic ion-exchangers was studied. The best results were obtained for AN-31 weakly basic anion exchanger. The yield of 125Sb was 95-98% of the initial activity, the yield of tin, 98±0.5% of the initial amount. The separation coefficient is 106-107 for one cycle. A procedure based on ion exchange was developed. Extraction procedures of separation of 125Sb from tin were studied. Isoamyl alcohol, ethyl acetate, and di- n-butyl ether were used as extracting agents. The most efficient extracting agent is di- n-butyl ether. Carrier-free radiochemically pure sample of 125Sb was produced. More than 20 mCi of the target product was recovered. The extraction recovery procedure of 125Sb has been developed.

  1. Tin Whisker Risk Assessment of TDRSS IV Transponder Units 101 and 102

    Science.gov (United States)

    Zellitti, Ron; Royse, Jeff; Jackson, Steve

    2000-01-01

    This report documents the plating requirements for the electrical and mechanical parts used in the TDRSS IV transponder manufactured by MOTOROLA, INC., SSG, SSSD. The intent of this report is to identify any electrical, electromechanical or mechanical part that does not have adequate requirements to prevent the use of a pure tin finish.

  2. Interfacial fatigue stress in PVD TiN coated tool steels under rolling contact fatigue conditions

    NARCIS (Netherlands)

    Carvalho, N.J.M.; Huis in 't Veld, A.J.; Hosson, J.T. de

    1998-01-01

    Titanium-nitrogen (TiN) films were Physical Vapour Deposited (PVD) on tool steel substrates with different hardness and surface roughness, in a Bai 640R unit using a triode ion plating (e-gun) with a high plasma density. The coated substrates were submitted to a rolling contact fatigue test

  3. Interfacial fatigue stress in PVD TiN coated tool steels under rolling contact fatigue conditions

    NARCIS (Netherlands)

    Carvalho, N.J.M.; Huis in ’t Veld, A.J.; Hosson, J.Th. De

    1998-01-01

    Titanium–nitrogen (TiN) films were Physical Vapour Deposited (PVD) on tool steel substrates with different hardness and surface roughness, in a Bai 640R unit using a triode ion plating (e-gun) with a high plasma density. The coated substrates were submitted to a rolling contact fatigue test techniqu

  4. Interfacial fatigue stress in PVD TiN coated tool steels under rolling contact fatigue conditions

    NARCIS (Netherlands)

    Carvalho, N.J.M.; Huis in 't Veld, A.J.; Hosson, J.T. de

    1998-01-01

    Titanium-nitrogen (TiN) films were Physical Vapour Deposited (PVD) on tool steel substrates with different hardness and surface roughness, in a Bai 640R unit using a triode ion plating (e-gun) with a high plasma density. The coated substrates were submitted to a rolling contact fatigue test techniqu

  5. Surface Plasmon Polariton Modulator with Periodic Patterning of Indium Tin Oxide Layers

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Lavrinenko, Andrei

    2011-01-01

    We study a metal-dielectric-metal waveguide as an absorption modulator. The system consists of an indium tin oxide (ITO) layer and silicon nitride (Si3N4) imbedded between two silver plates. We analyze the system and perform numerical simulations with the aim to increase transmittance and enhance...

  6. Surface Plasmon Polariton Modulator with Periodic Patterning of Indium Tin Oxide Layers

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Lavrinenko, Andrei

    2011-01-01

    We study a metal-dielectric-metal waveguide as an absorption modulator. The system consists of an indium tin oxide (ITO) layer and silicon nitride (Si3N4) imbedded between two silver plates. We analyze the system and perform numerical simulations with the aim to increase transmittance and enhance...

  7. Thermal Exposure Effects on Properties of Al-Li Alloy Plate Products

    Science.gov (United States)

    Shah, Sandeep; Wells, Douglas; Wagner, John; Babel, Henry

    2003-01-01

    The objective of this viewgraph representation is to evaluate the effects of thermal exposure on the mechanical properties of both production mature and developmental Al-Li alloys. The researchers find for these alloys, the data clearly shows that there is no deficit in mechanical properties at lower exposure temperatures in some cases, and a signficant deficit in mechanical properties at higher exposure temperatures in all cases. Topics considered include: Al-Li alloys composition, key characteristics of Al-Li alloys and thermal exposure matrix.

  8. Folate content in fresh-cut vegetable packed products by 96-well microtiter plate microbiological assay.

    Science.gov (United States)

    Fajardo, Violeta; Alonso-Aperte, Elena; Varela-Moreiras, Gregorio

    2015-02-15

    Ready-to-eat foods have nowadays become a significant portion of the diet. Accordingly, nutritional composition of these food categories should be well-known, in particular its folate content. However, there is a broad lack of folate data in food composition tables and databases. A total of 21 fresh-cut vegetable and fruit packed products were analysed for total folate (TF) content using a validated method that relies on the folate-dependent growth of chloramphenicol-resistant Lactobacillus casei subspecies rhamnosus (NCIMB 10463). Mean TF content ranged from 10.0 to 140.9μg/100g for the different matrices on a fresh weight basis. Higher TF quantity, 140.9-70.1μg/100g, was found in spinach, rocket, watercress, chard and broccoli. Significant differences were observed between available data for fresh vegetables and fruits from food composition tables or databases and the analysed results for fresh-cut packed products. Supplied data support the potential of folate-rich fresh-cut ready-to-eat vegetables to increase folate intake significantly. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Limiting Size of Fish Fillets at the Center of the Plate Improves the Sustainability of Aquaculture Production

    Directory of Open Access Journals (Sweden)

    Stephen F. Cross

    2011-07-01

    Full Text Available North American dining customers like to have a singular large piece of protein in the center of the plate. When fish is the protein of choice, the portion size from many species is limited by the overall size of the fish. Therefore, for these species, the means to achieve a singular larger portion of “center of the plate” protein is to grow a larger animal. However, fish become less efficient in converting feed to protein as they age. A second option would be to provide two smaller fillets originating from younger, more efficient fish. Here, the sustainability ramifications of these two protein provisioning strategies (single large or two small fillets are considered for three species of fish produced in aquaculture. Growth data for channel catfish (Ictalurus punctatus produced in ponds, rainbow trout (Oncorhynchus mykiss in raceways, and sablefish (Anoplopoma fimbria in marine net pens, were modeled to assess the total biomass and overall food conversion ratio for the production of small, medium or large fish. The production of small fish added an additional 50% or more biomass per year for trout, catfish, and sablefish compared to the production of large fish. Feed conversion ratios were also improved by nearly 10% for the smaller compared to larger fish of each species. Thus, even though all of these species tend to be considered aquaculture species of low environmental impact (and hence “green” or sustainable options, the product form requested by retailers and served by chefs can further increase the sustainability of these species.

  10. Project of Economically Profitable Technological Process of Production of Rotor and Stator Plates of Inductive Position Sensor by Blanking and Roll Bending

    Directory of Open Access Journals (Sweden)

    Radek ČADA

    2013-12-01

    Full Text Available Paper concerns innovation of production of rotor and stator plates of inductive position sensors which are used at automatization of production processes. Authors analyse possibility of efficiency improvement of production of these devices in joint-stock company TES VSETÍN and suggest concrete solving of new production technology. Composition of production line for blanking and roll bending of rotor and stator plates of inductive position sensor from individual technological devices was suggested: decoiler, straightening device, actuating belt feeder, pneumatic shears with inclined tools, belt conveyer and four cylinders bending rolls. Construction of production line was projected in order to its operation can be secured by one production workman, which controls and chooses operation of CNC programme, takes separate roll bended rotor and stator plates of inductive position sensor from bending rolls and according to required technological procedure he composes them to rotor and stator complexes. Construction of production line was projected so that it is possible to move it by crane without necessity to dismantle and subsequently to put together and adjust the line.

  11. An experimental study of tin partition between melt and aqueous fluid in F/CI-coexisting magma

    Institute of Scientific and Technical Information of China (English)

    HU XiaoYan; BI XianWu; SHANG LinBo; HU RuiZhong; CAI GuoSheng; CHEN YouWei

    2009-01-01

    In order to investigate the formation mechanism of tin ores associated with F-bearing granite, an experimental study of tin partition between F-bearing granitic melt and coexisting HCI-bearing aqueous fluid was conducted at 850"C and 100MPa with fo2 approaching NNO. Geochemical behavior of tin was traced by changes in starting solid materials with different alumina saturation index ASl, in F content and in starting fluids of various HCl concentrations. The results show that DSn increases with ASl of melt and peraluminous melt is favorable for tin partition into aqueous fluid in the F/Cl-coexisting system. Aqueous fluid of higher HCl concentrations is advantageous for enrichment of tin. Furthermore,chlorine contents in glass run products correlate positively with F and CI contents in the magma. In the F/Cl-coexisting system, granitic melts with high F contents (>~-1 wt%) could extract and enrich tin in the melt which can serve as a reservoir for the formation of tin ores. However, the partition coefficient of tin would increase significantly when F contents in the melt were below 1 wt%. Therefore, the decrease of F contents is favorable to the partition of tin into aqueous fluid with high HCI contents, thus promoting deposition of hydrothermal tin ores.

  12. Plate Boundary Observatory and related networks: GPS data analysis methods and geodetic products

    Science.gov (United States)

    Herring, Thomas A.; Melbourne, Timothy I.; Murray, Mark H.; Floyd, Michael A.; Szeliga, Walter M.; King, Robert W.; Phillips, David A.; Puskas, Christine M.; Santillan, Marcelo; Wang, Lei

    2016-12-01

    The Geodesy Advancing Geosciences and EarthScope (GAGE) Facility Global Positioning System (GPS) Data Analysis Centers produce position time series, velocities, and other parameters for approximately 2000 continuously operating GPS receivers spanning a quadrant of Earth's surface encompassing the high Arctic, North America, and Caribbean. The purpose of this review is to document the methodology for generating station positions and their evolution over time and to describe the requisite trade-offs involved with combination of results. GAGE GPS analysis involves formal merging within a Kalman filter of two independent, loosely constrained solutions: one is based on precise point positioning produced with the GIPSY/OASIS software at Central Washington University and the other is a network solution based on phase and range double-differencing produced with the GAMIT software at New Mexico Institute of Mining and Technology. The primary products generated are the position time series that show motions relative to a North America reference frame and secular motions of the stations represented in the velocity field. The position time series themselves contain a multitude of signals in addition to the secular motions. Coseismic and postseismic signals, seasonal signals from hydrology, and transient events, some understood and others not yet fully explained, are all evident in the time series and ready for further analysis and interpretation. We explore the impact of analysis assumptions on the reference frame realization and on the final solutions, and we compare within the GAGE solutions and with others.

  13. The application and research status of tin whisker formation in electric usage

    Science.gov (United States)

    Zhao, Heng; Liu, Qing-bin; Lan, Yuan-pei; Wang, Hua; Yao, Da-wei

    2017-05-01

    `Hair Like' crystalline structure grows from most pure tin or zinc finishes. Usually, the diameter of tin whisker is up to 10 mm and the length of tin whisker is typically 1 µm. In detail, the questions for tin whisker formation are classified into 6 categories: 1. Residual stress with in the tin plating; 2. Intermetallic Formation; 3. Externally Applied Compressive Stress; 4. Bending and Stretching; 5. Scratches and Nicks; 6. Coefficient of Thermal Expansion Mismatches. The result shows that, whisker formation could causes electrical short circuit (High current of whisker melting), debris contamination (Sensitive Optical and Micro Electrical Mechanical System) and metal vapor (Vaporize Damage). Thus, it is suggested that environmental tests and standards (Whisker Shape, Temperature, Pressure, Moisture, Thermal Cycling, and Electrical Field) are required for suppressing whisker formation. Nowadays, the new standards committee of Europe Union acts RoHS (Restriction of certain Hazardous Substances) and WEEE (Waste Electrical and Electronic Equipment) to restrict Pb usage. Thus, new compounds adding to alloys to suppress whiskers are required in electronic application area. In summary, the tin whisker formation is largely influenced by compositions and precipitations.

  14. The effect of different annealing temperatures on tin and cadmium telluride phases obtained by a modified chemical route

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Anderson Fuzer [Departamento de Química, CCE, Universidade Federal do Espírito Santo, Campus Goiabeiras, 29075-910 Vitória, Espírito Santo (Brazil); Porto, Arilza de Oliveira, E-mail: arilzaporto@yahoo.com.br [Departamento de Química, ICEx, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais (Brazil); Magela de Lima, Geraldo [Departamento de Química, ICEx, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais (Brazil); Paniago, Roberto [Departamento de Física, ICEx, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais (Brazil); Ardisson, José Domingos [Centro de Desenvolvimento da Tecnologia Nuclear, CDTN/CNEN, Belo Horizonte, Minas Gerais (Brazil)

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ► Synthesis of cadmium and tin telluride. ► Chemical route to obtain pure crystalline cadmium and tin telluride. ► Effect of the annealing temperature on the crystalline phases. ► Removal of tin oxide as side product through thermal treatment. -- Abstract: In this work tin and cadmium telluride were prepared by a modification of a chemical route reported in the literature to obtain metallacycles formed by oxidative addition of tin-tellurium bonds to platinum (II). Through this procedure it was possible to obtain tin and cadmium telluride. X-ray diffraction and X-ray photoelectron spectroscopy were used to identify the crystalline phases obtained as well as the presence of side products. In the case of tin telluride it was identified potassium chloride, metallic tellurium and tin oxide as contaminants. The tin oxidation states were also monitored by {sup 119}Sn Mössbauer spectroscopy. The annealing in hydrogen atmosphere was chosen as a strategy to reduce the tin oxide and promote its reaction with the excess of tellurium present in the medium. The evolution of this tin oxide phase was studied through the annealing of the sample at different temperatures. Cadmium telluride was obtained with high degree of purity (98.5% relative weight fraction) according to the Rietveld refinement of X-ray diffraction data. The modified procedure showed to be very effective to obtain amorphous tin and cadmium telluride and the annealing at 450 °C has proven to be useful to reduce the amount of oxide produced as side product.

  15. Thermal Exposure Effects on Properties of Al-Li Alloy Plate Products

    Science.gov (United States)

    Shah, Sandeep; Wells, Douglas; Wagner, John; Babel, Henry

    2002-01-01

    Aluminum-Lithium (AL-Li) alloys offer significant performance benefits for aerospace structural applications due to their higher specific properties compared with conventional aluminum alloys. For example, the application of an Al-Li alloy to the space shuttle external cryogenic fuel tank contributed to the weight savings that enabled successful deployment of International Space Station components. The composition and heat treatment of this alloy were optimized specifically for strength-toughness considerations for an expendable cryogenic tank. Time dependent properties related to reliability, such as thermal stability, fatigue, and corrosion, will be of significant interest when materials are evaluated for a reusable cryotank structure. As most aerospace structural hardware is weight sensitive, a reusable cryotank will be designed to the limits of the materials mechanical properties. Therefore, this effort was designed to establish the effects of thermal exposure on the mechanical properties and microstructure of one relatively production mature alloy and two developmental alloys C458 and L277. Tensile and fracture toughness behavior was evaluated after exposure to temperatures as high as 3oooF for up to IO00 hrs. Microstructural changes were also evaluated to correlate with the observed data trends. The ambient temperature parent metal data showed an increase in strength and reduction in elongation after exposure at lower temperatures. Strength reached a peak with intermediate temperature exposure followed by a decrease at highest exposure temperature. Characterizing the effect of thermal exposure on the properties of Al-Li alloys is important to defining a service limiting temperature, exposure time, and end-of-life properties.

  16. Studies on Cementation of Tin on Copper and Tin Stripping from Copper Substrate

    Directory of Open Access Journals (Sweden)

    Rudnik E.

    2016-06-01

    Full Text Available Cementation of tin on copper in acid chloride-thiourea solutions leads to the formation of porous layers with a thickness dependent on the immersion time. The process occurs via Sn(II-Cu(I mechanism. Chemical stripping of tin was carried out in alkaline and acid solutions in the presence of oxidizing agents. It resulted in the dissolution of metallic tin, but refractory Cu3Sn phase remained on the copper surface. Electrochemical tin stripping allows complete tin removal from the copper substrate, but porosity and complex phase composition of the tin coating do not allow monitoring the process in unambiguous way.

  17. Systematization of cross sections for the production of residual nuclei on separated tin isotopes in reactions induced by various-energy protons

    Energy Technology Data Exchange (ETDEWEB)

    Balabekyan, A. R., E-mail: balabekyan@ysu.am; Danagulyan, A. S. [Yerevan State University (Armenia); Drnoyan, J. R.; Demekhina, N. A. [Joint Institute for Nuclear Research (Russian Federation); Hovhannisyan, G. H.; Simonyan, A. E. [Yerevan State University (Armenia); Adam, J.; Solnishkin, A. A.; Tsoupko-Sytnikov, V. M. [Joint Institute for Nuclear Research (Russian Federation)

    2011-05-15

    Cross sections for the production of residual nuclei on the isotopes {sup 112,118,120,124}Sn irradiated with 0.66-, 1.0-, 3.65-, and 8.1-GeV proton beams were investigated. A ten-parameter semiempirical formula was used to systematize the cross sections in question. A comparative analysis of parameter values obtained at different proton energies was performed.

  18. Tin Whisker Electrical Short Circuit Characteristics. Part 2

    Science.gov (United States)

    Courey, Karim J.; Asfour, Shihab S.; Onar, Arzu; Bayliss, Jon A.; Ludwig, Lawrence L.; Wright, Maria C.

    2009-01-01

    Existing risk simulations make the assumption that when a free tin whisker has bridged two adjacent exposed electrical conductors, the result is an electrical short circuit. This conservative assumption is made because shorting is a random event that has an unknown probability associated with it. Note however that due to contact resistance electrical shorts may not occur at lower voltage levels. In our first article we developed an empirical probability model for tin whisker shorting. In this paper, we develop a more comprehensive empirical model using a refined experiment with a larger sample size, in which we studied the effect of varying voltage on the breakdown of the contact resistance which leads to a short circuit. From the resulting data we estimated the probability distribution of an electrical short, as a function of voltage. In addition, the unexpected polycrystalline structure seen in the focused ion beam (FIB) cross section in the first experiment was confirmed in this experiment using transmission electron microscopy (TEM). The FIB was also used to cross section two card guides to facilitate the measurement of the grain size of each card guide's tin plating to determine its finish.

  19. Sharp three sphere inequality for perturbations of a product of two second order elliptic operators and stability for the Cauchy problem for the anisotropic plate equation

    CERN Document Server

    Morassi, Antonino; Vessella, Sergio

    2010-01-01

    We prove a sharp three sphere inequality for solutions to third order perturbations of a product of two second order elliptic operators with real coefficients. Then we derive various kinds of quantitative estimates of unique continuation for the anisotropic plate equation. Among these, we prove a stability estimate for the Cauchy problem for such an equation and we illustrate some applications to the size estimates of an unknown inclusion made of different material that might be present in the plate. The paper is self-contained and the Carleman estimate, from which the sharp three sphere inequality is derived, is proved in an elementary and direct way based on standard integration by parts.

  20. UNAVCO Enhanced data products for the EarthScope Plate Boundary Observatory, COCONet, and other regional networks

    Science.gov (United States)

    Puskas, C. M.; Phillips, D. A.; Mattioli, G. S.; Meertens, C. M.; Herring, T.; Murray, M. H.; Melbourne, T. I.; Boler, F. M.; Blewitt, G.; Larson, K. M.; Feaux, K.; Braun, J. J.; Small, E. E.

    2012-12-01

    As part of an initiative to improve data services and support new research in the geodetic community, UNAVCO and its partners are expanding our supported data products and releasing new visualization tools. The enhanced data products, primarily associated with the UNAVCO-managed EarthScope Plate Boundary Observatory (PBO) and COCONet project, have open access and are archived at UNAVCO. UNAVCO manages community data services for a range of geodetic systems: GPS, borehole strainmeters, laser strainmeters, tiltmeters, pore pressure sensors, and geodetic imaging (InSAR, LIDAR, and terrestrial laser scanning). As part of the expansion, UNAVCO will incorporate data products submitted or downloaded from outside agencies. We focus here on the GPS products, which will include improved geodetic coverage in the western U.S. and expanded coverage in North America, access to new station quality parameters, information on site hydrologic conditions, and hydrologic loading models. Existing, open-access GPS stations from other networks are being incorporated into current 1112-station PBO processing stream to obtain station position time series and velocities for an additional 500+ stations. The primary data sources will be the Southern California Integrated GPS Network (SCIGN), the Scripps Orbit and Permanent Array Center (SOPAC), and the National Geodetic Survey's Continuously Operating Reference (NGS CORS) network. These additional stations will comprise a backbone network across continental North America to better resolve the surface velocity field in central and eastern U.S. and Canada, regions not presently covered by PBO. The expanded geographic coverage will address possible tectonic signals on a continental scale and will improve resolution of intraplate seismic zones and glacial-isostatic adjustments. The large data set will also have non-tectonic applications such as hydrologic studies, reference frame determination, and atmospheric studies. Station quality parameters

  1. Tin Whisker Testing and Modeling

    Science.gov (United States)

    2015-11-01

    contamination , and post-assembly contamination methods 40 5.2.3 Environmental exposure, whisker measurements and metallurgical analysis 42 5.3 Results and...The roughness is partly a result of the shrinkage of the liquid between the primary tin dendrites. The roughness tends to trap contamination , which...diameter, density, and distribution were measured. 5.2.3.3 Metallurgical analysis To examine contamination levels and distributions, as-received

  2. 陶瓷金属化化学镀镍原理和生产工艺综述%Ceramic metal electroless nickel plating the principles and Production Summary

    Institute of Scientific and Technical Information of China (English)

    卢玉厚; 金德明

    2012-01-01

    化学镀镍适合多品种、少批量产品镀镍,生产非常灵活,中小企业多采用化镀生产工艺,本文介绍了化学镀镍原理、镀液配制和化镀生产工艺,为企业加强工艺控制,提高产品质量提供参考。%Electroless nickel for many varieties, small batch products nickel plating, very flexible production, Production SMEs to use more of electroless nickel plating, electroless nickel plating principle, the preparation of chemical plating nickel plating bath and electroless nickel production process, provide reference for enterprises to enhance process control, improve product quality.

  3. Trace element analyses of melt inclusions as probes for the evolution of Bolivian tin porphyry deposits

    Energy Technology Data Exchange (ETDEWEB)

    Wallianos, A. E-mail: pixe@pluto.mpi-hd.mpg.de; Dietrich, A.; Lehmann, B.; Mosbah, M.; Traxel, K

    1999-09-02

    Micron-sized melt inclusions (MI), trapped in host quartz crystals from rocks of magmatic systems, probe the evolution of ore deposits. PIXE in combination with NRA of light element concentrations provide a nearly complete database for geochemical characterisation. Tin deposits are usually associated with highly fractionated granitic magmatism. The tin porphyry deposits of Bolivia however have only a moderately fractionated bulk rock geochemistry. The investigation of MI revealed high degrees of fractionation with compositions similar to tin granites. It is supposed that the bulk rock geochemistry must be interpreted as the product of magma mixing. Unexposed granitic portions, represented by MI, provide magmatic vapour phases for hydrothermal alteration and mineralisation.

  4. Tin Oxide Chemistry from Macquer (1758) to Mendeleeff (1891) as Revealed in the Textbooks and Other Literature of the Era

    Science.gov (United States)

    de Berg, Kevin C.

    2008-01-01

    Eight chemistry textbooks written from 1758 to 1891 have been analyzed for the way they present the chemistry of the oxides of tin. This analysis gives insight into the foundation of a number of chemical ideas such as nomenclature and composition used in modern chemistry. Four major preparation techniques for the production of tin oxides emerge…

  5. Electrochemical characterization of TiN coatings

    Energy Technology Data Exchange (ETDEWEB)

    Piippo, J. (Swiss Federal Inst. of Tech., Inst. of Materials Chemistry and Corrosion, Zuerich (Switzerland)); Elsener, B. (Swiss Federal Inst. of Tech., Inst. of Materials Chemistry and Corrosion, Zuerich (Switzerland)); Boehni, H. (Swiss Federal Inst. of Tech., Inst. of Materials Chemistry and Corrosion, Zuerich (Switzerland))

    1993-12-03

    The corrosion behaviour of titanium nitride (TiN) CVD coatings on AISI 316L stainless steel and on inert Si[sub 3]N[sub 4] in hydrochloric acid is studied with a.c. and d.c. electrochemical methods. The electrochemical behaviour of TiN on stainless steel can be divided into active and passive behaviour according to the state of the substrate. The measurements indicate that there is an oxide layer on TiN that is responsible for its noble electrochemical behaviour. A model that describes the formation of the oxide layer on TiN in an electrolyte is proposed. (orig.)

  6. A comparative parametric study of a catalytic plate methane reformer coated with segmented and continuous layers of combustion catalyst for hydrogen production

    Science.gov (United States)

    Mundhwa, Mayur; Parmar, Rajesh D.; Thurgood, Christopher P.

    2017-03-01

    A parametric comparison study is carried out between segmented and conventional continuous layer configurations of the coated combustion-catalyst to investigate their influence on the performance of methane steam reforming (MSR) for hydrogen production in a catalytic plate reactor (CPR). MSR is simulated on one side of a thin plate over a continuous layer of nickel-alumina catalyst by implementing an experimentally validated surface microkinetic model. Required thermal energy for the MSR reaction is supplied by simulating catalytic methane combustion (CMC) on the opposite side of the plate over segmented and continuous layer of a platinum-alumina catalyst by implementing power law rate model. The simulation results of both coating configurations of the combustion-catalyst are compared using the following parameters: (1) co-flow and counter-flow modes between CMC and MSR, (2) gas hourly space velocity and (3) reforming-catalyst thickness. The study explains why CPR designed with the segmented combustion-catalyst and co-flow mode shows superior performance not only in terms of high hydrogen production but also in terms of minimizing the maximum reactor plate temperature and thermal hot-spots. The study shows that the segmented coating requires 7% to 8% less combustion-side feed flow and 70% less combustion-catalyst to produce the required flow of hydrogen (29.80 mol/h) on the reforming-side to feed a 1 kW fuel-cell compared to the conventional continuous coating of the combustion-catalyst.

  7. Controlling Laminate Plate Elastic Behavior

    OpenAIRE

    Mareš, T.

    2004-01-01

    This paper aims to express the relation of a measure of laminate plate stiffness with respect to the fiber orientation of its plies. The inverse of the scalar product of the lateral displacement of the central plane and lateral loading of the plate is the measure of laminate plate stiffness. In the case of a simply supported rectangular laminate plate this measure of stiffness is maximized, and the optimum orientation of its plies is searched.

  8. Improve low tin tin system recovery%提高低锡系统锡的回收率

    Institute of Scientific and Technical Information of China (English)

    农志民

    2014-01-01

    This paper mainly describes Fenghuang Mining Branch’s production practice on re-scavenging of cleaning table tailings to recycle tinstone after the tailings’ enter into low tin system;it points out the problems that are not adapt to production requirements occur in the production process, and introduces some practices on technical reform of low tin system production, such practices achieve desired result that is the recovery ratio of tin has improved by 0.46%, realizing enterprise’s business philosophy of improving mineral dressing index.%文章主要阐述凤凰矿业分公司主选流程摇床尾矿进入低锡系统再次扫选进行回收锡石的生产实践,指出了在生产过程中出现的一些不适应生产要求的问题,并介绍了对该低锡系统生产进行的一些技术改造实践,达到了预期的效果,该系统锡的回收率提高了0.46个百分点,实现了提高企业选矿技术指标的经营理念。

  9. ORGANO—TIN POLYMERS:SYNTHESIS,PROPERTIES AND APPLICATION

    Institute of Scientific and Technical Information of China (English)

    WEIRongbao; CheRongrui; 等

    1993-01-01

    Through interfacial poly-condensation of R2SnCl2 (R=Me,Bu) with various diacids,diphenols (diols),diamines,amino-acids,hydroxyacids,urea,or thiourea,a series of organo-tin poly-esters,poly-ethers,poly-amines,poly-amine-esters,poly-ureas,poly-thioureas were prepared,and characterised altogether totalling 100 polymers,among which 91 are previously unreported.The synthesized polymers have a potential as a thermostabilizer in PVC products.

  10. Radioecological impacts of tin mining.

    Science.gov (United States)

    Aliyu, Abubakar Sadiq; Mousseau, Timothy Alexander; Ramli, Ahmad Termizi; Bununu, Yakubu Aliyu

    2015-12-01

    The tin mining activities in the suburbs of Jos, Plateau State, Nigeria, have resulted in technical enhancement of the natural background radiation as well as higher activity concentrations of primordial radionuclides in the topsoil of mining sites and their environs. Several studies have considered the radiological human health risks of the mining activity; however, to our knowledge no documented study has investigated the radiological impacts on biota. Hence, an attempt is made to assess potential hazards using published data from the literature and the ERICA Tool. This paper considers the effects of mining and milling on terrestrial organisms like shrubs, large mammals, small burrowing mammals, birds (duck), arthropods (earth worm), grasses, and herbs. The dose rates and risk quotients to these organisms are computed using conservative values for activity concentrations of natural radionuclides reported in Bitsichi and Bukuru mining areas. The results suggest that grasses, herbs, lichens, bryophytes and shrubs receive total dose rates that are of potential concern. The effects of dose rates to specific indicator species of interest are highlighted and discussed. We conclude that further investigation and proper regulations should be set in place in order to reduce the risk posed by the tin mining activity on biota. This paper also presents a brief overview of the impact of mineral mining on biota based on documented literature for other countries.

  11. Optimization of electrodeposition processes for tin coatings

    Science.gov (United States)

    Wen, Shixue

    The mechanism of nucleation and growth of tin electrodeposits was investigated. Also the influences of the operating parameters on the morphology, texture, and microstructure as well as the corrosion resistance of tin coatings were studied in order to propose optimum deposition conditions. Tin electrodeposition on glassy carbon and steel from acid sulfate electrolytes proceeds via the 3D (Volmer-Weber) mechanism. On low carbon steel substrates, 3D tin crystallites are initially formed preferentially on step edges, followed by fast deposition of other sites with much smaller and densely packed crystallites of about 150-180 nm in diameter. It was discovered that hydrogen co-evolution and gelatin have a synergy effect contributing to the fast and complete coverage of steel substrate with tin. The cathodic potential oscillation of tin (II) reduction in the tin electrolyte is attributed to the depletion and restoration of tin ions on the cathode surface. It has been found that an increase in current density improves the coverage of the substrate or the covering power. Without agitation, the deposits are powdery at high current densities. In order to obtain smooth and compact coatings, agitation is crucial when the applied current density is well above the limiting value. Tin coatings with two different fibre textures, (100) and (301) were produced by electrodeposition. At a lower current density of 100 A/m 2, (301) fibre was obtained. At the current densities of 100 and up to 400 A/m2, only (100) fibre texture was observed. An increase in current density leads to a decrease in grain size. At the same current density, the grain size of tin coatings increases with increased temperature. The influence of temperature (20, 40, 60 and 80°C) on texture is small. The corrosion resistance of tin coatings increases with a decrease in grain size. The corrosion resistance of tin coatings with (301) fibre was higher than that of the tin coating with (100) fibre texture. The optimum

  12. Development of plating thickness standards. Milestone report

    Energy Technology Data Exchange (ETDEWEB)

    Russell, R.J.

    1978-01-01

    Standards which are unavailable from the National Bureau of Standards were developed to support the nondestructive measurement of plating thickness. Their fabrication, measurement, certification, and calibration-recall schedule are discussed. Reference standards that have been put into service include aluminum/Kapton, silver/copper, tin/steel, gold/silver, cadmium/Kovar, silver/iron, rhodium/copper, and gold/ceramic. 6 figures, 3 tables.

  13. Heat loss coefficients and effective tau-alpha products for flat-plate collectors with diathermanous covers

    Science.gov (United States)

    Hollands, K. G. T.; Wright, J. L.

    1983-01-01

    This paper presents an efficient algorithm for solving the set of nonlinear equations governing the total heat transfer across an arbitrary number of parallel flat plate solar collector covers, each of which can be partly transparent to longwave thermal radiation. The governing equations are sufficiently general to permit each cover to have asymmetric radiative properties and to account for absorption of solar energy on the individual covers. This theory is shown to be in good agreement with the approximate equations of Whillier (provided certain interpretations are placed on his quantities) and with experiments using a plastic inner cover and bounding plates of various emissivities. Using this theory, it is demonstrated that if the absorber plate has a selective surface, an inner cover transparent to long wave radiation is to be preferred over one which is opaque.

  14. Nondestructive measurement of the residual stress TiN thin film coated on AISI 304 substrate by x-ray stress analyzer

    Science.gov (United States)

    Zhang, Y. K.; Feng, A. X.; Lu, J. Z.; Kong, D. J.; Tang, C. P.

    2006-01-01

    Titanium nitride films are deposited on AISI 304 steel with a hollow-cathode-discharge (HCD) ion-plating technique. The status of residual stresses in TiN thin film coated on AISI304 substrate by HCD is studied by x-ray diffraction stress analyzer. By analyzing morphology of the residual stress of TiN thin film at interface between TiN film and AISI 304 substrate, the adhering mechanism of TiN thin film is understood as follows: the mechanical interlocking had important contribution to the adhesion strength, the thermal stress is the major factor which resulting TiN thin film peeling off spontaneously. The results show that the value of thin film is -210MPa~-650Mpa, and the thermal stress is compressive, the intrinsic stress is tensile, origins of the residual stress are primarily discussed.

  15. Uranium in cassiterites of tin deposits

    Energy Technology Data Exchange (ETDEWEB)

    Zagruzina, I.A.; Pinskij, Eh.M.; Savinova, I.B.

    1986-01-01

    For the purpose of elucidation of physico-chemical features of uranium and tin behaviour in ore deposition zones uranium determinations (1000 determ) in cassiterite grains from 55 tin-ore deposits of different formation types of several separate regions are carried out by means of fission radiography. It is shown that uranium content in cassiterites is a genetic sign. Peculiarities of uranium concentration and migration in tin deposits permit to use them as prognostic radiogeochemical criteria. Radiogeochemical prognostic-search signs confirm the antagonism between uranium and tin deposits of cassiterite-silicate and cassiterite-sulfide formations and paragenetic of certain types of uranium hydrothermal deposits with tin deposits of cassiterite-quartz formation.

  16. Structural studies of supported tin catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Nava, Noel [Instituto Mexicano del Petroleo, Gerencia de Catalizadores (Mexico); Viveros, Tomas [Universidad Autonoma Metropolitana-Iztapalapa, Area de Ingenieria Quimica (Mexico)

    1999-11-15

    Tin oxide was supported on aluminium oxide, titanium oxide, magnesium oxide and silicon oxide, and the resulting interactions between the components in the prepared samples and after reduction were characterized by Moessbauer spectroscopy. It was observed that in the oxide state, tin is present as SnO{sub 2} on alumina, magnesia and silica, but on titania tin occupies Ti sites in the structure. After hydrogen treatment at high temperatures, tin is reduced from Sn(4) to Sn(2) on alumina and titania; it is reduced from Sn(4) to Sn(0) on silica, and is practically not reduced on magnesia. These results reveal the degree of interaction between tin and the different supports studied.

  17. Development and Production of High Performances Heavily Bruned Al2O3—C Slicde Plate

    Institute of Scientific and Technical Information of China (English)

    ZHANGChengtian; ZHAOChuanfa; 等

    1998-01-01

    The slide plate,made of sintered tabular corundum,reactive alumina ultr-fine powder with thermoplastic phenolic formaldehyde resin as cemedin and added 4%-6% quality scaled graphite ,special carbon and compound additive (A+B),has excellent performances such as lower thermal expansion,good thermal shock resistance,excellent erosion and corrosion resistance,and high strength,etc.All physical properties can meet the customers' needs,Afer being used in several steel plants in U.S.A.,this kind of slide plate received favorable comments with its easily open and close operation

  18. Corrosion inhibitors for mild steel; stannous tin (SnII) in ordinary portland cement

    Energy Technology Data Exchange (ETDEWEB)

    Sagoe-Crentsil, K.K.; Glasser, F.P.; Yilmaz, V.T. (Univ. of Aberdeen (United Kingdom). Dept. of Chemistry)

    1994-01-01

    Salts containing divalent tin (SnII) are shown to give a measure of corrosion protection to mild steel embedded in cement paste. Results of linear polarization measurements are shown for samples cured at 40[degree] for up to 240 days in pastes containing initially 0-1628mM/l chloride: Sn[sup 2+], but not Sn[sup 4+], is an effective inhibitor at an initial concentration of 200mM/l. However tin solubility in pore fluid is very low: less than 0.01mM/l at 60d. It is speculated that tin stabilizes the passivating layers although no direct evidence for the incorporation of tin in corrosion product was found by analytical electron microscopy. Other theories of inhibition are discussed.

  19. Experimental and Numerical Evaluation of the By-Pass Flow in a Catalytic Plate Reactor for Hydrogen Production

    DEFF Research Database (Denmark)

    Sigurdsson, Haftor Örn; Kær, Søren Knudsen

    2011-01-01

    Numerical and experimental study is performed to evaluate the reactant by-pass flow in a catalytic plate reactor with a coated wire mesh catalyst for steam reforming of methane for hydrogen generation. By-pass of unconverted methane is evaluated under different wire mesh catalyst width to reactor...

  20. Study of the temperature distribution on welded thin plates of duplex steel to be used for the external clad of a cask for transportation of radiopharmaceuticals products

    Energy Technology Data Exchange (ETDEWEB)

    Betini, Evandro G.; Ceoni, Francisco C.; Mucsi, Cristiano S.; Politano, Rodolfo; Rossi, Jesualdo L., E-mail: egbetini@ipen.br, E-mail: fceoni@hotmail.com, E-mail: csmucsi@ipen.br, E-mail: politano@ipen.br, E-mail: jelrossi@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Orlando, Marcos T.D., E-mail: mtdorlando@gmail.com [Universidade Federal do Espirito Santo (CCE/DFIS/UFES), Vitoria, ES (Brazil). Centro de Ciencias Exatas. Departamento de Fisica

    2015-07-01

    The clad material for a proprietary transport device for radiopharmaceutical products is the main focus of the present work. The production of {sup 99}Mo-{sup 99m}Tc transport cask requires a receptacle or cask where the UNS S32304 duplex steel sheet has shown that it meets high demands as the required mechanical strength and the spread of impact or shock waves mitigation. This work reports the experimental efforts in recording the thermal distribution on autogenous thin plates of UNS S32304 steel during welding. The UNS S32304 duplex steel is the most probable candidate for the external clad of the containment package for the transport of radioactive substances so it is highly relevant the understanding of all its physical parameters and its behavior under the thermal cycle imposed by a welding process. For the welding of the UNS S32304 autogenous plates the GTAW (gas tungsten arc welding) process was used with a pure argon arc protection atmosphere in order to simulate a butt joint weld on a thin duplex steel plate without filler metal. The thermal cycles were recorded by means of K-type thermocouples embedded by electrical spot welding near the weld region and connected to a multi-channel data acquisition system. The obtained results validate the reliability of the experimental apparatus for the future complete analysis of the welding experiment and further comparison to numerical analysis. (author)

  1. Plating of archaeological metallic objects - studies by differential PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Smit, Z. [University of Ljubljana, Faculty of Mathematics and Physics, Jadranska 19, SI-1000 Ljubljana (Slovenia); Jozef Stefan Institute, Jamova 39, P.O. Box 3000, SI-1001 Ljubljana (Slovenia)], E-mail: ziga.smit@fmf.uni-lj.si; Istenic, J.; Knific, T. [National Museum of Slovenia, Presernova 20, SI-1000 Ljubljana (Slovenia)

    2008-05-15

    The differential PIXE method using an external proton beam up to 3 MeV energy was applied to examine plated layers of tin, silver and gold on bronze, brass, iron and silver objects from Roman and Early Medieval period. The concentration profiles were deduced from the measurements by the method of virtual slicing the target into layers, and minimizing the differences between the measured and calculated X-ray yields. The tinned layers were usually thin (about 1 {mu}m), but the thickness of silver and gold layers was in several cases thicker and exceeded the proton range. The plating techniques were identified as application of the molten metal for tinning, and as fire gilding for the gilded objects.

  2. Plating of archaeological metallic objects studies by differential PIXE

    Science.gov (United States)

    Šmit, Ž.; Istenič, J.; Knific, T.

    2008-05-01

    The differential PIXE method using an external proton beam up to 3 MeV energy was applied to examine plated layers of tin, silver and gold on bronze, brass, iron and silver objects from Roman and Early Medieval period. The concentration profiles were deduced from the measurements by the method of virtual slicing the target into layers, and minimizing the differences between the measured and calculated X-ray yields. The tinned layers were usually thin (about 1 μm), but the thickness of silver and gold layers was in several cases thicker and exceeded the proton range. The plating techniques were identified as application of the molten metal for tinning, and as fire gilding for the gilded objects.

  3. Numerical modelling of ozone production in a wire-cylinder corona discharge and comparison with a wire-plate corona discharge

    Science.gov (United States)

    Wang, Pengxiang; Chen, Junhong

    2009-02-01

    The effect of electrode configuration on ozone production in the direct-current corona discharge of dry and humid air is studied by a numerical model that combines the electron distribution in the corona plasma, plasma chemistry and transport phenomena. Two electrode configurations are considered: wire-cylinder discharge with air flowing along the wire axis and wire-plate discharge with air flowing transverse to the wire. The ozone distributions in both types of discharges are compared. For both electrode configurations, the ozone production rate is higher in the negative corona than in the positive corona and it decreases with an increase in relative humidity. More importantly, the detailed ozone distribution in the neighbourhood of the discharge wire, together with the ozone kinetics, reveals the possible difference in the ozone production from the two discharges. With the same operating conditions and sufficiently short flow residence time, the ozone production rate is nearly the same for both electrode configurations. When the flow residence time is longer than the characteristic time for homogeneous ozone destruction, the net ozone production is higher in the wire-cylinder discharge than in the wire-plate discharge due to relatively less ozone destruction.

  4. Electronic structure of tin monosulfide

    Science.gov (United States)

    Bletskan, D. I.; Bletskan, M. M.; Glukhov, K. E.

    2017-01-01

    The band structure of three-dimensional and two-dimensional tin monosulfide was calculated by the density functional method in LDA and LDA+U approximations. Group-theoretical analysis of the electronic band structure of SnS crystallized in the orthorhombic structure with space group D2h16- Pcmn is carried out, the symmetry of wave functions of the valence band and the bottom of the conduction band is found. The selection rules for direct and indirect optical transitions at different incident light polarization are determined. The group-theoretical analysis of energy states of the three-dimensional and two-dimensional SnS structures explains the formation of the band structure including the Davydov splitting. The calculated total density of states is compared with the known experimental XPS and UPS spectra, providing the assignment of their main features.

  5. Tin compounds and insect fauna

    Energy Technology Data Exchange (ETDEWEB)

    Butovskiy, R.O.

    1985-03-01

    A review of the literature of tin compounds serving as pesticides has resulted in the identification of 11 widely used compounds, both organic and inorganic, with largely fungicidal activity. Organotin compounds seem to be limited in use to the control of insect pests, with the majority of the compounds consisting of Sn(IV) and falling into the following four categories: R/sub 4/Sn, R/sub 3/SNX, R/sub 2/SnX/sub 2/, and RSnX/sub 3/, where R = aliphatic or aromatic hydrocarbon radicals, and X = organic or inorganic substituent. The insecticidal activity of these compounds appears to rest on inhibition of ATPase and uncoupling of oxidative phosphorylation. As a result, these compounds act as larvicides, ovicides and imagocides. 77 references.

  6. Synthesis of tin-containing polyimide films

    Science.gov (United States)

    Ezzell, S. A.; Taylor, L. T.

    1984-01-01

    A series of tin-containing polyimide films derived from either 3,3',4,4'-benzophenone tetracarboxylic acid dianhydride or pyromellitic dianhydride and 4,4'-oxydianiline have been synthesized and their electrical properties examined. Highest quality materials (i.e., homogeneous, smooth surface, flexible) with the best electrical properties were doped with either SnCl2.2H2O or (n-Bu)2SnCl2. In all cases, extensive reactivity of the tin dopant with water, air or polyamic acid during imidization is observed. Lowered electrical surface resistivities appear to be correlatable with the presence of surface tin oxide on the film surface.

  7. A Study of the Effect of Gold Thickness Distribution in the Jet Plating Process to Optimize Gold Usage and Plating Voltage Using Design of Experiments

    OpenAIRE

    Aramphongphun Chuckaphun; Nampanya Chalermpol

    2016-01-01

    A gold plating process in the electronics industry can be classified as (i) all surface plating or (ii) selective plating. Selective plating is more widely used than all surface plating because it can save more gold used in the plating process and takes less plating time. In this research, the selective plating process called jet plating was studied. Factors that possibly affected the gold usage and plating voltage were also studied to reduce the production cost. These factors included (a) pl...

  8. Effect of microstructure on the breakage of tin bronze machining chips during pulverization via jet milling

    Science.gov (United States)

    Afshari, Elham; Ghambari, Mohammad; Farhangi, Hasan

    2016-11-01

    In this study, jet milling was used to recycle tin bronze machining chips into powder. The main purpose of this study was to assess the effect of the microstructure of tin bronze machining chips on their breakage behavior. An experimental target jet mill was used to pulverize machining chips of three different tin bronze alloys containing 7wt%, 10wt%, and 12wt% of tin. Optical and electron microscopy, as well as sieve analysis, were used to follow the trend of pulverization. Each alloy exhibited a distinct rate of size reduction, particle size distribution, and fracture surface appearance. The results showed that the degree of pulverization substantially increased with increasing tin content. This behavior was attributed to the higher number of machining cracks as well as the increased volume fraction of brittle δ phase in the alloys with higher tin contents. The δ phase was observed to strongly influence the creation of machining cracks as well as the nucleation and propagation of cracks during jet milling. In addition, a direct relationship was observed between the mean δ-phase spacing and the mean size of the jet-milled product; i.e., a decrease in the δ-phase spacing resulted in smaller particles.

  9. Application of electroless plating in electromagnetic shielding fabrics production%化学镀在电磁屏蔽织物制备中的应用

    Institute of Scientific and Technical Information of China (English)

    颜冬; 齐鲁

    2011-01-01

    The shielding principle of electromagnetic shielding fabrics was introduced, as were the principle and application of electroless plating in electromagnetic shielding fabrics. The shielding fabrics electroplating with silver, copper, nickel, copper/ nickel, nickel/copper/nickel, copper/nickel/silver and their production technologies were described emphatically. It was pointed out that the development trend of electroless plating shielding fabrics should focus on the environmental-friendly electroless plating technique and multilayer and composite electroplating fabrics.%介绍了电磁屏蔽材料的屏蔽原理、化学镀的原理及其在电磁屏蔽织物中的应用;重点慨述了镀银、镀铜、镀镍以及镀铜/镍、镀镍/铜/镍、镀铜/镍/银等主要化学镀电磁屏蔽织物及制备方法;提出开发具有环保的化学镀方法、多层镀及复合镀织物将是化学镀电磁屏蔽织物的发展方向.

  10. Investigation of fluoroethylene carbonate effects on tin-based lithium-ion battery electrodes.

    Science.gov (United States)

    Yang, Zhenzhen; Gewirth, Andrew A; Trahey, Lynn

    2015-04-01

    Electroless plating of tin on copper foil (2-D) and foams (3-D) was used to create carbon- and binder-free thin films for solid electrolyte interphase (SEI) property investigation. When electrochemically cycled vs lithium metal in coin cells, the foam electrodes exhibited better cycling performance than the planar electrodes due to electrode curvature. The effect of the additive/cosolvent fluoroethylene carbonate (FEC) was found to drastically improve the capacity retention and Coulombic efficiency of the cells. The additive amount of 2% FEC is enough to derive the benefits in the cells at a slow (C/9) cycling rate. The interfacial properties of Sn thin film electrodes in electrolyte with/without FEC additive were investigated using in situ electrochemical quartz crystal microbalance with dissipation (EQCM-D). The processes of the decomposition of the electrolyte on the electrode surface and Li alloying/dealloying with Sn were characterized quantitatively by surface mass change at the molecular level. FEC-containing electrolytes deposited less than electrolyte without FEC on the initial reduction sweep, yet increased the overall thickness/mass of SEI after several cyclic voltammetry cycles. EQCM-D studies demonstrate that the mass accumulated per mole of electrons (mpe) was varied in different voltage ranges, which reveals that the reduction products of the electrolyte with/without FEC are different.

  11. Mitigating tin whisker risks theory and practice

    CERN Document Server

    Handwerker, Carol A; Bath, Jasbir

    2016-01-01

    Discusses the growth mechanisms of tin whiskers and the effective mitigation strategies necessary to reduce whisker growth risks. This book covers key tin whisker topics, ranging from fundamental science to practical mitigation strategies. The text begins with a review of the characteristic properties of local microstructures around whisker and hillock grains to identify why these particular grains and locations become predisposed to forming whiskers and hillocks. The book discusses the basic properties of tin-based alloy finishes and the effects of various alloying elements on whisker formation, with a focus on potential mechanisms for whisker suppression or enhancement for each element. Tin whisker risk mitigation strategies for each tier of the supply chain for high reliability electronic systems are also described.

  12. Space Shuttle Program Tin Whisker Mitigation

    Science.gov (United States)

    Nishimi, Keith

    2007-01-01

    The discovery of tin whiskers (TW) on space shuttle hardware led to a program to investigate and removal and mitigation of the source of the tin whiskers. A Flight Control System (FCS) avionics box failed during vehicle testing, and was routed to the NASA Shuttle Logistics Depot for testing and disassembly. The internal inspection of the box revealed TW growth visible without magnification. The results of the Tiger Team that was assembled to investigate and develop recommendations are reviewed in this viewgraph presentation.

  13. 对某产品芯轴整体镀金工艺改进%To Improve a Product Core Shaft Overall Gold Plating Process

    Institute of Scientific and Technical Information of China (English)

    仲志新; 董铭江; 李建华; 范筱琳

    2015-01-01

    阐述了旋转开关式环位置传感器产品的芯轴在电镀过程中出现的问题及解决方法。为了起到良好的导电性和耐磨性,该部件要求在外圆金属表面进行 Cu/Ep·Ni1~3Au3~5hd 表面处理工艺。在实现这一表面处理过程中出现了很多的问题,电镀的合格率最初不足10%,且由于该部件要求导电环表面高出填料表面0~0.01 mm,给产品的电镀、退镀都造成了困难,废品率极高。通过过程监控,发现影响电镀质量的因素是前处理不到位。对电镀的前处理过程进行分析、改进,使部件生产过程及表面处理的前处理过程得到完善,从而提高镀层的外观与结合力,使该部件的电镀合格率由10%提升到80%,提高产品的合格率,完成产品节点交付。%This paper describes a core shaft similar to a rotary switch in a location sensor,de-scribes problems occurring in the product during the plating process and provides a solution to said problem.In order to improve conductibility and abrasion resistance,the part must have an exterior metal surface having a Cu/Ep ·Ni1 ~3Au3 ~5hd surface treatment.A number of problems emerged during surface treatment process,and the pass rate of plating was initially less than 10%.The high requirements for the filling surface of the conduct ring,between 0 and 0.01 mm,made it difficult to manufacture the plate and the back plate.As a re-sult,a high percentage of products were rejected. By conducting process monitoring,we found a key factor affecting the plating quality was insufficient pre treatment.By conducting analysis and impro-ving the plating pre treatment process,the parts manufacturing process and the surface treatment process was perfected.Thus the appearance and binding force of coating was improved,and the pass rate of plating parts increased from 10% to 80%,so that more products could be successfully delivered.

  14. Effect of TiN coating on microstructure of Tif/Al composite.

    Science.gov (United States)

    Xiu, Z Y; Chen, G Q; Wang, M; Hussain, Murid

    2013-02-01

    In the present work, Ti fibre reinforced Al matrix composites (Ti(f)/Al) were fabricated by pressure infiltration method. In order to suppress the severe Ti-Al reaction and reduce the formation of brittle TiAl(3) phase, a TiN layer was coated on Ti fibres by an arc ion plating method before composite preparation. A thin TiN layer was coated on the Ti fibre surface, and the maximum and minimum thickness values of layer were about 3.5 and 1μm, respectively. Prefer orientation of TiN on (111) and (200) was found by XRD analysis. A thin and uniform TiAl(3) layer was observed in Ti(f)/Al composite. However, after coated with TiN layer, no significant reaction layer was found in (Ti(f)+TiN)/Al composite. Segregation of Mg element was found in Ti(f)/Al composite, and the presence of TiN layer showed little effect on this behaviour. Due to the large CTE difference between Ti fibre and Al matrix, high density dislocations were observed in the Al matrix. Meanwhile, fine dispersed Mg(2)Al(3) phases were also found in Al matrix. Ti fibre is mainly composed of α- and β-Ti. Small discontinuous needle-like TiAl(3) phases were detected at TiN/Al interface, which implies that the presence of TiN layer between the Ti fibre and Al matrix could effectively hinder the formation of TiAl(3) phases. Copyright © 2012 Elsevier Ltd. All rights reserved.

  15. Current status of research and application of cyanide-free plating processes and related recommendations%无氰电镀工艺研究与应用现状及建议

    Institute of Scientific and Technical Information of China (English)

    徐金来; 赵国鹏; 胡耀红

    2012-01-01

    介绍了无氰浸锌,无氰镀铜,无氰镀锌,无氰镀铜锡合金,无氰镀黄铜或仿金,无氰镀银,无氰镀金等工艺的研究和应用现状,探讨了无氰电镀工艺的适用范围及特点,提出了改进的方向,为推进无氰电镀工艺的研究和应用,实现淘汰氰化物电镀工艺,促进电镀行业清洁生产实施提供参考.%The current research and application of cyanide-free processes for zinc immersion, copper plating, zinc plating, copper-tin alloy plating, brass or imitation gold plating, silver plating, and gold plating were introduced. Their characteristics and application scope were discussed. Some suggestions on development directions were given. This article serves as a reference for accelerating the research and application of cyanide-free plating processes, finding alternatives to cyanide plating, and promoting the implementation of cleaner production in electroplating industry.

  16. Fundamental studies of tin whiskering in microelectronics finishes

    Science.gov (United States)

    Pinol, Lesly Agnes

    Common electronics materials, such as tin, copper, steel, and brass, are ambient reactive under common use conditions, and as such are prone to corrosion. During the early 1940s, reports of failures due to electrical shorting of components caused by 'whisker' (i.e., filamentary surface protrusion) growth on many surface types---including the aforementioned metals---began to emerge. Lead alloying of tin (3--10% by weight, typically in the eutectic proportion) eliminated whiskering risk for decades, until the July 2006 adoption of the Restriction of Hazardous Substances (RoHS) directive was issued by the European Union. This directive, which has since been adopted by California and parts of China, severely restricted the use of lead (market, imposing the need for developing reliable new "lead-free" alternatives to SnPb. In spite of the abundance of modern-day anecdotes chronicling whisker-related failures in satellites, nuclear power stations, missiles, pacemakers, and spacecraft navigation equipment, pure tin finishes are still increasingly being employed today, and the root cause(s) of tin whiskering remains elusive. This work describes a series of structured experiments exploring the fundamental relationships between the incidence of tin whiskering (as dependent variable) and numerous independent variables. These variables included deposition method (electroplating, electroless plating, template-based electrochemical synthesis, and various physical vapor deposition techniques, including resistive evaporation, electron beam evaporation, and sputtering), the inclusion of microparticles and organic contamination, the effects of sample geometry, and nanostructuring. Key findings pertain to correlations between sample geometry and whisker propensity, and also to the stress evolution across a series of 4"-diameter silicon wafers of varying thicknesses with respect to the degree of post-metallization whiskering. Regarding sample geometry, it was found that smaller

  17. Plate tectonics conserves angular momentum

    Directory of Open Access Journals (Sweden)

    C. Bowin

    2009-03-01

    Full Text Available A new combined understanding of plate tectonics, Earth internal structure, and the role of impulse in deformation of the Earth's crust is presented. Plate accelerations and decelerations have been revealed by iterative filtering of the quaternion history for the Euler poles that define absolute plate motion history for the past 68 million years, and provide an unprecedented precision for plate angular rotation variations with time at 2-million year intervals. Stage poles represent the angular rotation of a plate's motion between adjacent Euler poles, and from which the maximum velocity vector for a plate can be determined. The consistent maximum velocity variations, in turn, yield consistent estimates of plate accelerations and decelerations. The fact that the Pacific plate was shown to accelerate and decelerate, implied that conservation of plate tectonic angular momentum must be globally conserved, and that is confirmed by the results shown here (total angular momentum ~1.4 E+27 kgm2s−1. Accordingly, if a plate decelerates, other plates must increase their angular momentums to compensate. In addition, the azimuth of the maximum velocity vectors yields clues as to why the "bend" in the Emperor-Hawaiian seamount trend occurred near 46 Myr. This report summarizes processing results for 12 of the 14 major tectonic plates of the Earth (except for the Juan de Fuca and Philippine plates. Plate accelerations support the contention that plate tectonics is a product of torques that most likely are sustained by the sinking of positive density anomalies due to phase changes in subducted gabbroic lithosphere at depth in the upper lower mantle (above 1200 km depth. The tectonic plates are pulled along by the sinking of these positive mass anomalies, rather than moving at near constant velocity on the crests of convection cells driven by rising heat. These results imply that spreading centers are primarily passive reactive

  18. Create Your Plate

    Medline Plus

    Full Text Available ... unsweetened tea or coffee. Featured Product Precise Portions® Go Healthy Travel Pack (4/Box) Taking the guesswork ... you are. Now, our best-selling, sectioned to-go plate with easy-sealing lid is offered in ...

  19. An Investigation of the Electrical Short Circuit Characteristics of Tin Whiskers

    Science.gov (United States)

    Courey, Karim J.

    2008-01-01

    Existing risk simulations make the assumption that when a free tin whisker has bridged two adjacent exposed electrical conductors, the result is an electrical short circuit. This conservative assumption is made because shorting is a random event that has a currently unknown probability associated with it. Due to contact resistance electrical shorts may not occur at lower voltage levels. In this experiment, we study the effect of varying voltage on the breakdown of the contact resistance which leads to a short circuit. From this data we can estimate the probability of an electrical short, as a function of voltage, given that a free tin whisker has bridged two adjacent exposed electrical conductors. Also, three tin whiskers grown from the same Space Shuttle Orbiter card guide used in the aforementioned experiment were cross-sectioned and studied using a focused ion beam (FIB). The rare polycrystalline structure seen in the FIB cross section was confirmed using transmission electron microscopy (TEM). The FIB was also used to cross section two card guides to facilitate the measurement of the grain size to determine that the tin plating on the card guides had a bright finish.

  20. Wear Behavior of the Lead-Free Tin Bronze Matrix Composite Reinforced by Carbon Nanotubes

    Science.gov (United States)

    Zeng, Jun; Fan, Huiqing; Wang, Yangli; Zhang, Siquan

    2011-12-01

    Copper-coated carbon nanotubes were prepared by the electroless plating route. The structure and component of copper/carbon tubes were characterized using a transmission electron microscope and energy dispersive spectrometer. The results show that the surface of the carbon tubes was covered by the copper particles. Copper/carbon tubes were used as the substitute of part of tin and all of lead in the tin bronze matrix, and the tribological properties of carbon nanotube-reinforced Cu-4 wt pct Sn-6 wt pct Zn composites were studied. The effects of the carbon nanotube volume fraction and sliding distance in unlubricated ball-on-disc wear test were investigated. The 3 vol pct carbon nanotube-reinforced Cu-4 wt pct Sn-6 wt pct Zn composite shows the Vickers hardness of 126.9, which is approximately 1.6 times higher than that of Cu-6 wt pct Sn-6 wt pct Zn-3 wt pct Pb tin bronze. The wear rate and average friction coefficients of 3 vol pct carbon nanotube-reinforced Cu-4 wt pct Sn-6 wt pct Zn composite were lower than those of the Cu-6 wt pct Sn-6 wt pct Zn-3 wt pct Pb tin bronze, respectively.

  1. For production of ceramic plates coating using waste kaolin, granite and marble; Caracterizacao de residuos de caulim, granito e marmore para uso em massas ceramicas

    Energy Technology Data Exchange (ETDEWEB)

    Sales, J.L.; Morais, C.R.S.; Lima, L.M.R.; Altidis, M.E.D., E-mail: josyanne27@yahoo.com.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2011-07-01

    The objective is to benefit and characterize waste from kaolin, marble and granite studying their thermal properties and spectroscopic in employment perspective on ceramic production of flooring boards. The residues were benefited through the process of dry grinding mill in greyhounds and passed through sieve 0.074 mm (ABNT No. 200), observing their suitability for the formulation of ceramic pastes. Tests were performed physicochemical characterization (particle size analysis, X-ray fluorescence and X-ray diffraction) and thermal (differential thermal analysis and thermogravimetry). The results showed that these residues showed satisfactory properties for the purpose for which it proposes, and contribute to reducing environmental impacts, allowing the reuse of the production of ceramic plates (author)

  2. IMPEDANCE SPECTROSCOPY OF POLYCRYSTALLINE TIN DIOXIDE FILMS

    Directory of Open Access Journals (Sweden)

    D. V. Adamchuck

    2016-01-01

    Full Text Available The aim of this work is the analysis of the influence of annealing in an inert atmosphere on the electrical properties and structure of non-stoichiometric tin dioxide films by means of impedance spectroscopy method. Non-stoichiometric tin dioxide films were fabricated by two-step oxidation of metallic tin deposited on the polycrystalline Al2O3 substrates by DC magnetron sputtering. In order to modify the structure and stoichiometric composition, the films were subjected to the high temperature annealing in argon atmosphere in temperature range 300–800 °С. AC-conductivity measurements of the films in the frequency range 20 Hz – 2 MHz were carried out. Variation in the frequency dependencies of the real and imaginary parts of the impedance of tin dioxide films was found to occur as a result of high-temperature annealing. Equivalent circuits for describing the properties of films with various structure and stoichiometric composition were proposed. Possibility of conductivity variation of the polycrystalline tin dioxide films as a result of аnnealing in an inert atmosphere was demonstrated by utilizing impedance spectroscopy. Annealing induces the recrystallization of the films, changing in their stoichiometry as well as increase of the sizes of SnO2 crystallites. Variation of electrical conductivity and structure of tin dioxide films as a result of annealing in inert atmosphere was confirmed by X-ray diffraction analysis. Analysis of the impedance diagrams of tin dioxide films was found to be a powerful tool to study their electrical properties. 

  3. Solid-phase plate-reader quantification of specific PCR products by measurement of band-specific ethidium bromide fluorescence.

    Science.gov (United States)

    McCarthy, Michael T; O'Callaghan, Christopher A

    2014-02-15

    Real-time PCR is widely employed to quantify PCR products across a range of applications. However, accurate real-time PCR is not always technically feasible, and alternative methods for PCR product quantification can be expensive and time consuming to validate. We have developed an inexpensive, rapid, and immediately accessible protocol to quantify PCR products, by measuring ethidium bromide fluorescence of PCR products excised from agarose gels. This protocol has relevance to a broad range of methods in molecular biology where quantification of PCR products is necessary.

  4. Tin in canned food: a review and understanding of occurrence and effect.

    Science.gov (United States)

    Blunden, Steve; Wallace, Tony

    2003-12-01

    Tinplate is light gauge, steel sheet or strip, coated on both sides with commercially pure tin and has been used for well over a hundred years as a robust form of food packaging. Altogether, about 25,000 million food cans are produced and filled in Europe per annum, about 20% of these having plain internal (unlacquered) tin-coated steel bodies. Worldwide, the total for food packaging is approximately 80,000 million cans. Tinplate is also extensively used for the production of beverage cans. Europe produces and fills over 15,000 million tinplate beverage cans per annum all of which are internally lacquered. The use of tinplate for food and beverage packaging, will result in some tin dissolving into the food content, particularly when plain uncoated internal surfaces are used. The Provisional Tolerable Weekly Intake for tin is 14 mg/kg body weight and recommended maximum permissible levels of tin in food are typically 250 mg/kg (200 mg/kg UK) for solid foods and 150 mg/kg for beverages. However, the question arises as to whether evidence exists that such elevated levels of tin in food in any way constitute a risk to human health. This review considers the factors affecting the dissolution of tin, the reported measurements/surveys of actual levels of tin in canned foods and the studies and reports of acute (short term) toxicity relating to the ingestion of elevated levels of tin in food products. Chronic studies are mentioned, but are not covered in detail, since the review is mainly concerned with possible effects from the ingestion of single high doses. From published data, there appears to be a small amount of evidence suggesting that consumption of food or beverages containing tin at concentrations at or below 200 ppm has caused adverse gastrointestinal effects in an unknown but possibly small proportion of those exposed. However, the evidence supporting this assertion is derived from reports of adverse effects which offer data that are limited, incomplete or of

  5. Lean Management of Storage for Finished Product of Heavy Plate%宽厚板产成品库存的精益管理实践

    Institute of Scientific and Technical Information of China (English)

    郑林红

    2015-01-01

    To the insufficiency capacity of finished products inventory buffer, overproduction, stock high at await check section, more user self extracting in Heavy Plate plant, this article gives a triune management model of"production- sale- quality testing". A series of Lean management were adopted, such as optimizing technology and production control, revising and perfecting the system, intensifying spot market exploiting, regulating shipment mode etc., the finished product in inventory was reduced 21 061 tons in the three production lines, and reduced 78.07 million Yuan of occupation of funds.%针对宽厚板厂产成品库存缓冲能力不足、超量生产、待验库存量偏高、用户自提比例较高等问题,确定了"生产—销售—质检"三位一体的联动管理模式,采取优化工艺排产、修订完善制度、强化现货市场开拓、调整发运方式等一系列精益管理措施,使三产线合计降低产成品库存21 061 t,减少资金占用7 807万元.

  6. The dysprosium-tin phase diagram

    Energy Technology Data Exchange (ETDEWEB)

    Eremenko, V.N.; Bulanova, M.V.; Martsenjuk, P.S. (I.N. Frantsevich Inst. for Problems of Materials Science, Kiev (Ukraine))

    1992-12-07

    The dysprosium-tin phase diagram was established by means of differential thermal, X-ray and microscopic analyses of 22 alloys. Seven intermetallic compounds were found to exist in the system. Dy[sub 5]Sn[sub 3] melts congruently at 1870 degC, and undergoes a polymorphous transformation at 1823 [+-] 6 degC. The intermetallics Dy[sub 5]Sn[sub 4], Dy[sub 11]Sn[sub 10], DySn, Dy[sub 4]Sn[sub 5], DySn[sub 2], DySn[sub 3] are formed peritectically at 1712 [+-]11, 1605 [+-]12, 1208 [+-]3, 1166 [+-]7, 1138 [+-]3 and 747 [+-]6 degC respectively. DySn[sub 3] exists in a narrow temperature range, in two polymorphous modifications. The transformation [beta]-DySn[sub 3] [yields] [alpha]-DySn[sub 3] occurs at 608 [+-] 12 degC, and at 499 [+-]2 degC [alpha]-DySn[sub 3] decomposes to DySn[sub 2] and the tin-rich melt. The dysprosium-rich eutectic crystallizes at 1204 [+-]10 degC and contains 13 at.% tin. The solid-state solubility of tin in dysprosium is about 3 at.%, and that of dysprosium in tin is negligible.

  7. Wear performance of self-mating contact pairs of TiN and TiAlN coatings on orthopedic grade Ti-6Al-4V.

    Science.gov (United States)

    Kim, H; Kim, C Y; Kim, D W; Lee, I S; Lee, G H; Park, J C; Lee, S J; Lee, K Y

    2010-08-01

    Both titanium nitride (TiN) and titanium aluminum nitride (TiAlN) have shown great wear resistance potential in metallic medical devices as protective, hard thin film coatings. In the present study, the effects of TiN and TiAlN coating layers on the wear performance of Ti-6Al-4V were compared and analyzed. TiN and TiAlN coatings with a thickness of 3 microm were deposited by a cathodic vacuum arc ion plating technique on the surface of Ti-6Al-4V. Wear tests were conducted by using a pin-on-disk-type tribotester with a point contact self-mating pair in a linear reciprocal motion. A sliding distance of 20 mm per cycle at 1 Hz was used under a load of 15 N under ambient conditions with no lubricant. The wear resistance of TiN and TiAlN coatings is superior to that of uncoated Ti-6Al-4V at the early stage of sliding contact. Until a measurable amount of wear was detected, the number of sliding cycles of the TiAlN coating pair was longer than TiN. After the first detection of wear from the coating layers, the rate of wear of the TiN coating pairs was significantly higher than that of TiAlN (p TiN from the viewpoint of wear resistance under the test conditions used in this study.

  8. 锡后处理对锡镀层性能的影响%Influence of tin post-processing on tin coating properties

    Institute of Scientific and Technical Information of China (English)

    欧爱良; 王英锋; 樊应县; 刘季超; 刘奕林

    2015-01-01

    The porosity, anti-tarnish property, soldering property, reflow soldering solderability and the tin whisker growth inhibition of the pure tin coating were tested after passivation treatment and metal protectant treatment, respectively. Test results show that the coating porosities of the pure tin layer to be treated by using passivation and metal protectant are reduced, and the anti-tarnish property is improved. The metal protectant coating can restrain the tin whisker from growth and extend the storage life of the products effectively, and it doesn’t affect the soldering performance. Comparatively, the passivation treatment growth soldering property of the tin layer and has no apparent affect on restraining the tin whisker from growth.%分别测试了纯锡镀层经钝化及金属保护剂处理后的孔隙率、防变色能力、可焊、回流焊性能及抑制锡须生长情况。试验结果表明:对纯锡层采用钝化和金属保护剂处理均能有效降低镀层的孔隙率,提高镀层的防变色能力。金属保护剂处理能有效防止锡层的氧化,延长产品的储存寿命,对焊接性能无影响,同时能有效抑制锡须生长;钝化处理降低了锡镀层的焊接性能,对抑制锡须生长作用不明显。

  9. Waffle production: influence of batter ingredients on sticking of fresh egg waffles at baking plates-Part I: effect of starch and sugar components.

    Science.gov (United States)

    Huber, Regina; Schoenlechner, Regine

    2017-05-01

    Fresh egg waffles are a sweet convenience product typically baked from eggs, water, sugar, flour, fat, leavening agents, emulsifiers, preservatives, and flavors. In industrial production, waffles are baked continuously in high amounts of up to 200 kg raw material per hour. Therefore, it is important that the waffles do not stick onto the baking plates, which can cause significant product loss and increased costs due to interruption of the baking process, required cleaning procedures, and restarting of the energy-consuming start-up phase. Sticking of waffles is greatly influenced not only by baking plate material, release agent, baking temperature, and time, but also by the batter ingredients. In this study, effects of different starches and sugar components were investigated. Within the selected starches, potato starch demonstrated the highest effects on increasing waffle stability and releasing properties compared to wheat and lupine flour (less than 7% sticking waffles). Rice flour performed worst, with almost 50% of sticking waffles. Most of these waffles were broken during take-off, due to their crumbly texture. Within the sugar components, glycerine was better suitable than sorbitol and crystal sugar was superior compared to powdered sugar. They required less take-off force. It could be demonstrated that waffles with increased stability and texture were those that showed the least number of sticking waffles, thus the main aim of batter ingredients was to improve waffle quality. Waffle quality was influenced by batter parameters, significant correlations could be found, for example, a positive correlation between pH- and L-value, negative correlations between pH- and a-value, or density and aw-value. This resulted in significant correlations with take-off-force, which was correlated with L*- and b*-value (negative) and positive to a*-value. Sticking behavior was strongly associated with b*-value (positive) and to a*-value (negative).

  10. Tin Whisker Growth and Mitigation with a Nanocrysytalline Nickel Coating

    Science.gov (United States)

    Janiuk, Szymon

    Tin whiskers are a problem in the electronics industry since the EU banned the use of lead in Pb-Sn solders as part of the Restriction of Hazardous Substances (RoHS). The biggest concern with Sn whiskers is their ability to short-circuit electronics. High reliability applications such as the aerospace, defense, healthcare, and automotive industries are at most risk. This project explores Sn whisker mitigation and prevention with the use of nanocrystalline nickel coating over Sn surfaces. Sn was plated onto a pure Cu substrate using electroplating. A high temperature and high humidity condition, at 85°C and 85% RH, was effective at growing whiskers. A nNi coating was plated over Sn/Cu coupons. After subjecting the nNi/ Sn/Cu samples through 85°C/85% RH testing conditions, no whiskers were observed penetrating the surface. These results make nNi a viable material to use as a coating to prevent the growth of Sn whiskers in electronic assemblies.

  11. Mixing in mantle convection models with self-consistent plate tectonics and melting and crustal production: Application to mixing in the early Earth

    Science.gov (United States)

    Tackley, Paul

    2016-04-01

    It is generally thought that the early Earth's mantle was hotter than today, which using conventional convective scalings should have led to vigorous convection and mixing. Geochemical observations, however, suggest that mixing was not as rapid as would be expected, leading to the suggestion that early Earth had stagnant lid convection (Debaille et al., EPSL 2013). Additionally, the mantle's thermal evolution is difficult to explain using conventional scalings because early heat loss would have been too rapid, which has led to the hypothesis that plate tectonics convection does not follow the conventional convective scalings (Korenaga, GRL 2003). One physical process that could be important in this context is partial melting leading to crustal production, which has been shown to have the major effects of buffering mantle temperature and carrying a significant fraction of the heat from hot mantle (Nakagawa and Tackley, EPSL 2012), making plate tectonics easier (Lourenco et al., submitted), and causing compositional differentiation of the mantle that can buffer core heat loss (Nakagawa and Tackley, GCubed 2010). Here, the influence of this process on mantle mixing is examined, using secular thermo-chemical models that simulate Earth's evolution over 4.5 billion years. Mixing is quantified both in terms of how rapidly stretching occurs, and in terms of dispersion: how rapidly initially close heterogeneities are dispersed horizontally and vertically through the mantle. These measures are quantified as a function of time through Earth's evolution. The results will then be related to geochemically-inferred mixing rates.

  12. On the correlation between force production and the flow field around a flapping flat-plate wing

    Science.gov (United States)

    Öz, Sören; Krishna, Swathi; Mulleners, Karen

    2015-11-01

    One of the several sophisticated flight skills that insects exhibit is hovering, which is accomplished largely by modulating the wing kinematics and thereby the flow field around the wings. Along with the prolonged attachment of the leading edge vortex, the wing reversal mechanisms form the basis by which insects regulate the magnitude and direction of forces produced. The duration and starting point of these directional flips are studied in the current experimental investigation. Particle image velocimetry is conducted to evaluate the flow features inherent to changes in wing reversal during the stroke of a flat plate, which is modelled based on hoverfly characteristics. The duration of rotation is one-third of the total time period. A +10% phase shift is used for delayed rotation, a -10% phase shift for advanced rotation. Phase-averaged data is analysed to understand the influence of a delayed or advanced rotation on the formation and evolution of large and small scale structures, their interactions with the wing, and disintegration. Additionally, force data is used to quantify the effects of phase-shift in terms of lift and drag variation and is correlated with the vortex dynamics.

  13. Quantifying Cutting and Wearing Behaviors of TiN- and CrNCoated AISI 1070 Steel

    Directory of Open Access Journals (Sweden)

    Ahmet Cakan

    2008-11-01

    Full Text Available Hard coatings such as titanium nitride (TiN and chromium nitride (CrN are widely used in cutting and forming tools against wear and corrosion. In the present study, hard coating films were deposited onto AISI 1070 steels by a cathodic arc evaporation plating (CAVP technique. These samples were subjected to wear in a conventional lathe for investigating the tribological behaviour of coating structure, and prenitrided subsurface composition was characterized using scanning electron microscopy (SEM, line scan analyses and X-ray diffraction (XRD. The wear properties of TiN- and CrNcoated samples were determined using an on-line monitoring system. The results show that TiN-coated samples demonstrate higher wear resistance than CrN-coated samples.

  14. Quantifying Cutting and Wearing Behaviors of TiN- and CrNCoated AISI 1070 Steel.

    Science.gov (United States)

    Cakan, Ahmet; Ozkaner, Vedat; Yildirim, Mustafa M

    2008-11-05

    Hard coatings such as titanium nitride (TiN) and chromium nitride (CrN) are widely used in cutting and forming tools against wear and corrosion. In the present study, hard coating films were deposited onto AISI 1070 steels by a cathodic arc evaporation plating (CAVP) technique. These samples were subjected to wear in a conventional lathe for investigating the tribological behaviour of coating structure, and prenitrided subsurface composition was characterized using scanning electron microscopy (SEM), line scan analyses and X-ray diffraction (XRD). The wear properties of TiN- and CrNcoated samples were determined using an on-line monitoring system. The results show that TiN-coated samples demonstrate higher wear resistance than CrN-coated samples.

  15. Study of optical characteristics of tin oxide thin film prepared by sol–gel method

    Indian Academy of Sciences (India)

    Sumanta Kumar Tripathy; Bhabani Prasad Hota; P V Rajeswari

    2013-12-01

    In this paper, we present details of preparation of tin oxide (SnO2) thin film by sol–gel process. The film was synthesized on a glass (Corning 7059) plate by dip coating method. Here, we used tin (II) chloride as precursor and methanol as solvent. Optical characteristics and physical properties like refractive index, absorption coefficient and thickness of thin film were calculated from the study of transmission spectrum (wavelength vs transmission curve) data given by UV/VIS Spectrophotometer. Effect of number of coatings on transmittance and refractive index was also examined. It was observed that refractive index decreases with the number of coating and transmission value was more than 80% at wavelength greater than 450 nm in all cases. Structural analysis was studied by XRD measurement by using diffractometer which confirms tetragonal rutile structure of SnO2. Surface morphology was analysed from SEM micrograph and change in morphology on number of coat was discussed.

  16. Electron beam induced growth of tin whiskers

    Energy Technology Data Exchange (ETDEWEB)

    Vasko, A. C.; Karpov, V. G. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Warrell, G. R.; Parsai, E. I.; Shvydka, Diana, E-mail: diana.shvydka@utoledo.edu [Department of Radiation Oncology, University of Toledo Health Science Campus, Toledo, Ohio 43614 (United States)

    2015-09-28

    We have investigated the influence of electron irradiation on tin whisker growth. Sputtered tin samples exposed to electron beam of 6 MeV energy exhibited fast whisker growth, while control samples did not grow any whiskers. The statistics of e-beam induced whiskers was found to follow the log-normal distribution. The observed accelerated whisker growth is attributed to electrostatic effects due to charges trapped in an insulating substrate. These results offer promise for establishing whisker-related accelerated life testing protocols.

  17. Evaluation of the performances of a biological treatment on tin-enriched bronze.

    Science.gov (United States)

    Albini, Monica; Chiavari, Cristina; Bernardi, Elena; Martini, Carla; Mathys, Lidia; Joseph, Edith

    2017-01-01

    Recently, research gives emphasis to eco-friendly and sustainable approaches for the preservation of cultural heritage that could offer advantages in terms of compatibility, durability and safety. Hence, a biological treatment, based on a specific fungal strain of Beauveria bassiana, is exploited for the stabilization of soluble and/or active bronze corrosion products, converting them into copper oxalates. The chemical stability of the latter represents a real improvement for the long-term preservation of bronze, especially in case of exposure to acid rain. However, the corrosion behaviour of bronze differs from that of pure copper due to the presence of additional alloying elements. In natural environments, the selective dissolution of copper leads to a relative tin-enrichment within the corrosion layers, mostly in unsheltered areas exposed to rainwater runoff. To understand the influence of tin-enrichment on the formation of oxalates, pure tin and artificially tin-enriched bronze coupons were treated with this novel biological system and, in the case of bronze coupons, exposed to accelerated ageing. Tin enrichment and accelerated ageing were performed through runoff tests. Before and after treatment and ageing, the sample surface was characterized through Fourier transform infrared (FTIR) and Raman spectroscopies, scanning electron microscopy coupled to energy dispersive spectroscopy (SEM-EDS). Metals released in the ageing solutions were analysed through atomic absorption spectrometry (AAS). The analytical results allowed to better understand the response of unsheltered areas from outdoor bronze monuments to the biological treatment proposed.

  18. Waffle production: influence of batter ingredients on sticking of waffles at baking plates-Part II: effect of fat, leavening agent, and water.

    Science.gov (United States)

    Huber, Regina; Schoenlechner, Regine

    2017-05-01

    Fresh egg waffles are continuously baked in tunnel baking ovens in industrial scale. Waffles that partly or fully stick to the baking plates cause significant product loss and increased costs. The aim of this study was, therefore, to investigate the effect of different recipe ingredients on the sticking behavior of waffles. In this second part, ingredients investigated were different leavening agents (sodium acid pyrophosphate, ammonium bicarbonate, magnesium hydroxide carbonate, or monocalcium phosphate), different fat sources (rapeseed oil, cocos fat, butter, or margarine), and different water sources (tap water 12°dH and distilled water). Within the different types of fats, solid fats with high amount of short-chain fatty acids (cocos fat or butter) decreased the number of sticking waffles compared to liquid oils (rapeseed oil). Regarding leavening agents, magnesium hydroxide carbonate and ammonium bicarbonate were superior to sodium acid pyrophosphate or monocalcium phosphate. Between the two water sources, effects were small.

  19. Degradation of some typical pharmaceuticals and personal care products with copper-plating iron doped Cu2O under visible light irradiation

    Institute of Scientific and Technical Information of China (English)

    Jing An; Qixing Zhou

    2012-01-01

    A mixture of five commonly used pharmaceuticals and personal care products (PPCPs) was degraded using a new combined catalyst under visible light irradiation.Scanning electron microscopy and X-ray diffraction analysis revealed that the combined catalyst was composed of copper-plating iron doped Cu2O (FeCu/Cu2O).Compared with the Fe/C inner micro-circuit,the electric currents flowing between Cu and Fe increase the speed of anodic Fe dissolution.Moreover,due to the photochemical properties,Cu2O can accelerate the PPCPs degradation processes under the irradiation of visible light.In addition,shaking increased the dissolved oxygen concentration in the solution,which not only preconditioned the photo-catalysis reaction,but also set the stage for Fe reduction.Aocording to the experimental results,we propose the possible reaction mechanism of the reaction.

  20. Lead dodecanoate coatings for the protection of lead and lead-tin alloy artifacts: Two examples

    Science.gov (United States)

    De Keersmaecker, Michel; Verbeken, Kim; Adriaens, Annemie

    2014-02-01

    In order to understand the corrosive and morphological characteristics of lead dodecanoate protective coatings on real samples, three pipe organ samples were studied using optical microscopy (OM), scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and electrochemical impedance spectroscopy (EIS). The corrosion products and elemental composition of the top layer of the different pipe organ samples were investigated. The results indicate that the three pipe organ samples are made of an alloy composed mainly of lead and tin. After immersion and the deposition of the protective coating, only lead and no tin is detected, which indicates the formation of a thick coating containing lead dodecanoate complexes.

  1. Dynamic modelling of high biomass density cultivation and biohydrogen production in different scales of flat plate photobioreactors.

    Science.gov (United States)

    Zhang, Dongda; Dechatiwongse, Pongsathorn; Del Rio-Chanona, Ehecatl Antonio; Maitland, Geoffrey C; Hellgardt, Klaus; Vassiliadis, Vassilios S

    2015-12-01

    This paper investigates the scaling-up of cyanobacterial biomass cultivation and biohydrogen production from laboratory to industrial scale. Two main aspects are investigated and presented, which to the best of our knowledge have never been addressed, namely the construction of an accurate dynamic model to simulate cyanobacterial photo-heterotrophic growth and biohydrogen production and the prediction of the maximum biomass and hydrogen production in different scales of photobioreactors. To achieve the current goals, experimental data obtained from a laboratory experimental setup are fitted by a dynamic model. Based on the current model, two key original findings are made in this work. First, it is found that selecting low-chlorophyll mutants is an efficient way to increase both biomass concentration and hydrogen production particularly in a large scale photobioreactor. Second, the current work proposes that the width of industrial scale photobioreactors should not exceed 0.20 m for biomass cultivation and 0.05 m for biohydrogen production, as severe light attenuation can be induced in the reactor beyond this threshold.

  2. 77 FR 54891 - Certain Corrosion-Resistant Carbon Steel Flat Products from the Republic of Korea: Preliminary...

    Science.gov (United States)

    2012-09-06

    ... such as zinc, aluminum, or zinc-, aluminum-, nickel- or iron-based alloys, whether or not corrugated or painted, varnished or coated with plastics or other nonmetallic substances in addition to the metallic... plated or coated with tin, lead, chromium, chromium oxides, both tin and lead (``terne plate''), or...

  3. Methodology for the effective stabilization of tin-oxide-based oxidation/reduction catalysts

    Science.gov (United States)

    Jordan, Jeffrey D. (Inventor); Schryer, David R. (Inventor); Davis, Patricia P. (Inventor); Leighty, Bradley D. (Inventor); Watkins, Anthony N. (Inventor); Schryer, Jacqueline L. (Inventor); Oglesby, Donald M. (Inventor); Gulati, Suresh T. (Inventor); Summers, Jerry C. (Inventor)

    2011-01-01

    The invention described herein involves a novel approach to the production of oxidation/reduction catalytic systems. The present invention serves to stabilize the tin oxide reducible metal-oxide coating by co-incorporating at least another metal-oxide species, such as zirconium. In one embodiment, a third metal-oxide species is incorporated, selected from the group consisting of cerium, lanthanum, hafnium, and ruthenium. The incorporation of the additional metal oxide components serves to stabilize the active tin-oxide layer in the catalytic process during high-temperature operation in a reducing environment (e.g., automobile exhaust). Moreover, the additional metal oxides are active components due to their oxygen-retention capabilities. Together, these features provide a mechanism to extend the range of operation of the tin-oxide-based catalyst system for automotive applications, while maintaining the existing advantages.

  4. Effects of electron beam irradiation on tin dioxide gas sensors

    Indian Academy of Sciences (India)

    Zheng Jiao; Xiaojuan Wan; Bing Zhao; Huijiao Guo; Tiebing Liu; Minghong Wu

    2008-02-01

    In this paper, the effects of electron beam irradiation on the gas sensing performance of tin dioxide thin films toward H2 are studied. The tin dioxide thin films were prepared by ultrasonic spray pyrolysis. The results show that the sensitivity increased after electron beam irradiation. The electron beam irradiation effects on tin dioxide thin films were simulated and the mechanism was discussed.

  5. Tin-Containing Silicates: Identification of a Glycolytic Pathway via 3-Deoxyglucosone

    DEFF Research Database (Denmark)

    Tolborg, Søren; Meier, Sebastian; Sádaba, I.;

    2016-01-01

    Inorganic glycolytic systems, capable of transforming glucose through a cascade of catalytic steps, can lead to efficient chemical processes utilising carbohydrates as feedstock. Tin-containing silicates, such as Sn-Beta, are showing potential for the production of lactates from sugars through a ...

  6. 30 CFR 22.10 - Approval plate.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Approval plate. 22.10 Section 22.10 Mineral... MINING PRODUCTS PORTABLE METHANE DETECTORS § 22.10 Approval plate. (a) Attachment to be made by manufacturers. (1) Manufacturers shall attach, stamp, or mold an approval plate on each permissible methane...

  7. 30 CFR 20.13 - Approval plate.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Approval plate. 20.13 Section 20.13 Mineral... MINING PRODUCTS ELECTRIC MINE LAMPS OTHER THAN STANDARD CAP LAMPS § 20.13 Approval plate. The manufacturer shall attach, stamp, or mold an approval plate on the battery container or housing of each...

  8. Create Your Plate

    Medline Plus

    Full Text Available ... A A A Listen En Español Create Your Plate Create Your Plate is a simple and effective ... and that your options are endless. Create Your Plate! Click on the plate sections below to add ...

  9. On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.

    Energy Technology Data Exchange (ETDEWEB)

    Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W. (PPF Industries, Pittsburgh, PA)

    2006-11-01

    Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are

  10. High-throughput system for screening of high L-lactic acid-productivity strains in deep-well microtiter plates.

    Science.gov (United States)

    Lv, Xiangyun; Song, Jiali; Yu, Bo; Liu, Huilan; Li, Chao; Zhuang, Yingping; Wang, Yonghong

    2016-11-01

    For strain improvement, robust and scalable high-throughput cultivation systems as well as simple and rapid high-throughput detection methods are crucial. However, most of the screening methods for lactic acid bacteria (LAB) strains were conducted in shake flasks and detected by high-performance liquid chromatography (HPLC), making the screening program laborious, time-consuming and costly. In this study, an integrated strategy for high-throughput screening of high L-lactic acid-productivity strains by Bacillus coagulans in deep-well microtiter plates (MTPs) was developed. The good agreement of fermentation results obtained in the MTPs platform with shake flasks confirmed that 24-well U-bottom MTPs could well alternate shake flasks for cell cultivation as a scale-down tool. The high-throughput pH indicator (bromocresol green) and L-lactate oxidase (LOD) assays were subsequently developed to qualitatively and quantitatively analyze L-lactic acid concentration. Together with the color halos method, the pH indicator assay and LOD assay, the newly developed three-step screening strategy has greatly accelerated the screening process for LAB strains with low cost. As a result, two high L-lactic acid-productivity mutants, IH6 and IIIB5, were successfully screened out, which presented, respectively, 42.75 and 46.10 % higher productivities than that of the parent strain in a 5-L bioreactor.

  11. Synthesising highly reactive tin oxide using Tin(II2- ethylhexanoate polynucleation as precursor

    Directory of Open Access Journals (Sweden)

    Alejandra Montenegro Hernández

    2010-05-01

    Full Text Available Tin oxide is a widely used compound in technological applications, particularity as a catalyst, gas sensor and in making varistors, transparent conductors, electrocatalytic electrodes and photovoltaic cells. An ethylhexanoate tin salt, a carboxylic acid and poly-esterification were used for synthesising highly reactive tin oxide in the present study. Synthesis was controlled by Fourier transform infrared (FTIR spectroscopy and recording changes in viscosity. The tin oxide characteristics so obtained were determined using FTIR spectroscopy, X-ray diffraction (XRD and scanning electron microscopy (SEM. The SnO2 dust synthesised and heat-treated at 550°C yielded high density aggregates, having greater than 50 μm particle size. This result demonstrates the high reactivity of the ceramic powders synthesised here.

  12. EUV and debris characteristics of a laser-plasma tin dioxide nano-particle colloidal jet target

    Science.gov (United States)

    Kaku, Masanori; Suetake, Sumihiro; Senba, Yusuke; Katto, Masahito; Kubodera, Shoichi

    2008-03-01

    Debris characteristics and its reduction have been investigated for a laser-produced plasma (LPP) extreme ultraviolet (EUV) source using a colloidal jet target containing tin dioxide nano-particles. Dominant deposited debris on a witness plate was found to have a form of oxidized tin (SnO x) originated from nano-particles. Quantitative debris amounts were determined by total laser energy irradiated onto a target, not by laser irradiation modes, such as single or double pulse irradiation. In-situ low-temperature (100°C) heating of a plate was effective to reduce the deposited debris amount, since colloidal debris was easily vaporized by the heat. Another approach to remove the deposited debris was roomtemperature photon processing using incoherent vacuum ultraviolet (VUV) emission at 126 nm. X-ray photoelectron spectroscopy (XPS) analysis has shown that the deposited SnOx debris layer was deoxidized by the 126 nm VUV photon energy.

  13. Leaching studies for tin recovery from waste e-scrap.

    Science.gov (United States)

    Jha, Manis Kumar; Choubey, Pankaj Kumar; Jha, Amrita Kumari; Kumari, Archana; Lee, Jae-Chun; Kumar, Vinay; Jeong, Jinki

    2012-10-01

    Printed circuit boards (PCBs) are the most essential components of all electrical and electronic equipments, which contain noteworthy quantity of metals, some of which are toxic to life and all of which are valuable resources. Therefore, recycling of PCBs is necessary for the safe disposal/utilization of these metals. Present paper is a part of developing Indo-Korean recycling technique consists of organic swelling pre-treatment technique for the liberation of thin layer of metallic sheet and the treatment of epoxy resin to remove/recover toxic soldering material. To optimize the parameters required for recovery of tin from waste PCBs, initially the bench scale studies were carried out using fresh solder (containing 52.6% Sn and 47.3% Pb) varying the acid concentration, temperature, mixing time and pulp density. The experimental data indicate that 95.79% of tin was leached out from solder material using 5.5M HCl at fixed pulp density 50 g/L and temperature 90°C in mixing time 165 min. Kinetic studies followed the chemical reaction controlled dense constant size cylindrical particles with activation energy of 117.68 kJ/mol. However, 97.79% of tin was found to be leached out from solder materials of liberated swelled epoxy resin using 4.5M HCl at 90°C, mixing time 60 min and pulp density 50 g/L. From the leach liquor of solder materials of epoxy resin, the precipitate of sodium stannate as value added product was obtained at pH 1.9. The Pb from the leach residue was removed by using 0.1M nitric acid at 90°C in mixing time 45 min and pulp density 10g/L. The metal free epoxy resin could be disposed-of safely/used as filling material without affecting the environment.

  14. Leaching studies for tin recovery from waste e-scrap

    Energy Technology Data Exchange (ETDEWEB)

    Jha, Manis Kumar, E-mail: maniskrjha@gmail.com [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Choubey, Pankaj Kumar; Jha, Amrita Kumari; Kumari, Archana [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Lee, Jae-chun, E-mail: jclee@kigam.re.kr [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of); Kumar, Vinay [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Jeong, Jinki [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of)

    2012-10-15

    Printed circuit boards (PCBs) are the most essential components of all electrical and electronic equipments, which contain noteworthy quantity of metals, some of which are toxic to life and all of which are valuable resources. Therefore, recycling of PCBs is necessary for the safe disposal/utilization of these metals. Present paper is a part of developing Indo-Korean recycling technique consists of organic swelling pre-treatment technique for the liberation of thin layer of metallic sheet and the treatment of epoxy resin to remove/recover toxic soldering material. To optimize the parameters required for recovery of tin from waste PCBs, initially the bench scale studies were carried out using fresh solder (containing 52.6% Sn and 47.3% Pb) varying the acid concentration, temperature, mixing time and pulp density. The experimental data indicate that 95.79% of tin was leached out from solder material using 5.5 M HCl at fixed pulp density 50 g/L and temperature 90 Degree-Sign C in mixing time 165 min. Kinetic studies followed the chemical reaction controlled dense constant size cylindrical particles with activation energy of 117.68 kJ/mol. However, 97.79% of tin was found to be leached out from solder materials of liberated swelled epoxy resin using 4.5 M HCl at 90 Degree-Sign C, mixing time 60 min and pulp density 50 g/L. From the leach liquor of solder materials of epoxy resin, the precipitate of sodium stannate as value added product was obtained at pH 1.9. The Pb from the leach residue was removed by using 0.1 M nitric acid at 90 Degree-Sign C in mixing time 45 min and pulp density 10 g/L. The metal free epoxy resin could be disposed-of safely/used as filling material without affecting the environment.

  15. Modeling the hydrodynamics of Phloem sieve plates

    DEFF Research Database (Denmark)

    Jensen, Kaare Hartvig; Mullendore, Daniel Leroy; Holbrook, Noel Michele;

    2012-01-01

    Sieve plates have an enormous impact on the efficiency of the phloem vascular system of plants, responsible for the distribution of photosynthetic products. These thin plates, which separate neighboring phloem cells, are perforated by a large number of tiny sieve pores and are believed to play...... are investigated. We find that the sieve plate resistance is correlated to the cell lumen resistance, and that the sieve plate and the lumen contribute almost equally to the total hydraulic resistance of the phloem translocation pathway....

  16. Growth of YBCO Thin Films on TiN(001) and CeO2-Coated TiN Surfaces

    Science.gov (United States)

    2012-02-01

    AFRL-RZ-WP-TP-2012-0102 GROWTH OF YBCO THIN FILMS ON TiN(001) AND CeO2-COATED TiN SURFACES (POSTPRINT) Paul N. Barnes, Rand Biggers...GROWTH OF YBCO THIN FILMS ON TiN(001) AND CeO2-COATED TiN SURFACES (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM...Number: ASC-01-1691; Clearance Date: 19 Nov 2002. This paper contains color 14. ABSTRACT Epitaxial growth of YBa2Cu3O7-x ( YBCO ) layers on TiN(0 0

  17. Co-production of lipids, eicosapentaenoic acid, fucoxanthin, and chrysolaminarin by Phaeodactylum tricornutum cultured in a flat-plate photobioreactor under varying nitrogen conditions

    Science.gov (United States)

    Gao, Baoyan; Chen, Ailing; Zhang, Wenyuan; Li, Aifen; Zhang, Chengwu

    2017-10-01

    The marine diatom Phaeodactylum tricornutum is a polymorphological, ecologically significant, and well-studied model of unicellular microalga. This diatom can accumulate diverse important metabolites. Herein, we cultured P. tricornutum in an internally installed tie-piece flat-plate photobioreactor under 14.5 m mol L-1 (high nitrogen, HN) and 2.9 m mol L-1 (low nitrogen, LN) of KNO3 and assessed its time-resolved changes in biochemical compositions. The results showed that HN was inductive to accumulate high biomass (4.1 g L-1). However, the LN condition could accelerate lipid accumulation in P. tricornutum. The maximum total lipid (TL) content under LN was up to 42.5% of biomass on day 12. Finally, neutral lipids (NLs) were 63.8% and 75.7% of TLs under HN and LN, respectively. The content of EPA ranged from 2.3% to 1.5% of dry weight during the growth period under the two culture conditions. Peak volumetric lipid productivity of 128.4 mg L-1d-1 was achieved in the HN group (on day 9). The highest volumetric productivity values of EPA, chrysolaminarin, and fucoxanthin were obtained in the exponential phase (on day 6) under HN, which were 9.6, 93.6, and 4.7 mg L-1d-1, respectively. In conclusion, extractable amounts of lipids, EPA, fucoxanthin, and chrysolaminarin could be obtained from P. tricornutum by regulating the culture conditions.

  18. Shear stress effects on production of exopolymeric substances and biofilm characteristics during phenol biodegradation by immobilized Pseudomonas desmolyticum (NCIM2112) cells in a pulsed plate bioreactor.

    Science.gov (United States)

    Veena, B R; Shetty K, Vidya; Saidutta, M B

    2016-07-03

    This article reports studies on a continuous pulsed plate bioreactor (PPBR) with the cells of Pseudomonas desmolyticum (NCIM2112) immobilized on granular activated carbon (GAC) used as a biofilm reactor for biodegradation of phenol. Almost complete removal of 200 ppm phenol could be achieved in this bioreactor. Biofilm structure and characteristics are influenced by hydrodynamic and shear conditions in bioreactors. In this article, the effect of shear stress induced by frequency of pulsation on biofilm characteristics during the startup period in the PPBR is reported. The startup time decreased with the increase in frequency of pulsation. The formation of biofilm in PPBR was found to have three phases: accumulation, compaction, and plateau. The effect of frequency on production of exoploymeric substances (EPS) such as, protein, carbohydrate, and humic substance is reported. An increase in shear stress induced by the frequency of pulsation increased the production of exopolymeric substances in the biofilm during startup of the bioreactor. Increase in shear stress caused a decrease in biofilm thickness and an increase in dry density of the biofilm. Increase in shear stress resulted in a smoother and thinner biofilm surface with more compact and dense structure.

  19. Interfacial fatigue stress in PVD TiN coated tool steels under rolling contact fatigue conditions

    OpenAIRE

    Carvalho, N. J. M.; Huis in ’t Veld, A.J.; Hosson, J.Th. De

    1998-01-01

    Titanium–nitrogen (TiN) films were Physical Vapour Deposited (PVD) on tool steel substrates with different hardness and surface roughness, in a Bai 640R unit using a triode ion plating (e-gun) with a high plasma density. The coated substrates were submitted to a rolling contact fatigue test technique (modified pin-on-ring test) to obtain some clarifications of the mechanism of interfacial failure. Tests were run using PVD-coated rings finished by polishing or grinding to produce different sur...

  20. Interfacial fatigue stress in PVD TiN coated tool steels under rolling contact fatigue conditions

    OpenAIRE

    Carvalho, N.J.M.; Huis in ’t Veld, A.J.; Hosson, J.Th. De

    1998-01-01

    Titanium–nitrogen (TiN) films were Physical Vapour Deposited (PVD) on tool steel substrates with different hardness and surface roughness, in a Bai 640R unit using a triode ion plating (e-gun) with a high plasma density. The coated substrates were submitted to a rolling contact fatigue test technique (modified pin-on-ring test) to obtain some clarifications of the mechanism of interfacial failure. Tests were run using PVD-coated rings finished by polishing or grinding to produce different sur...

  1. The PRESHOWER - a New Multichnnel Detector for the CDF. The Scintillator Plates of the New Detector: Design, Production, Quality Control

    CERN Document Server

    Artikov, A M; Chocheli, D; Danilov, V; Grinyov, B; Lebedev, V; Senchyshyn, V G

    2005-01-01

    To increase the CDF efficiency when studying heavy quark processes there was designed, constructed and put into operation a new multichannel detector --- the so called Central Preshower. It was positioned before the central electromagnetic calorimeter and increased the photon, lepton and hadron identification efficiency. JINR in cooperation with the Institute of Scintillating Materials (Kharkiv) has created a sensitive element of the new detector: about 2800 units of the scintillation tiles; the specially developed quality control procedure guaranteed the necessary high light yield for tiles mass production. The chosen tiles were equipped at FNAL by two loops (about 1 m long) of WLS fibers positioned inside the $\\Omega $-shape groove; it guaranteed a light yield of $\\sim$ 25--35 photoelectrons/MIP.

  2. A HIgh Current Density Low Cost Niobium 3 Tin Titanium Doped Conductor Utilizing A Novel Internal Tin Process

    Energy Technology Data Exchange (ETDEWEB)

    Bruce A Zeitlin

    2005-02-23

    An internal tin conductor has been developed using a Mono Element Internal Tin (MEIT) with an integral Nb barrier surrounding the Nb filaments. High current densities of 3000 A/mm2+ at 12 T and 1800 A/mm2 at 15 T have been achieved in conductors as small as 0.152 mm with the use of Nb7.5Ta filaments and Ti in the Sn core. In contrast, conductors with pure Nb and Ti in the Sn achieved 2700 A/mm2 at 12 T. Two internal fins, developed and patented on the project, were introduced into the filament array and reduced the effective filament diameter (Deff) by 38%. Additional fins will further reduce Deff The conductor was produced from 152.4 mm diameter billets to produce wire as small as 0.152 mm. The process promises be scaleable to 304 mm diameter billets yielding wire of 0.304 mm diameter. The MEIT process wire was easy to draw with relatively few breaks. The cost of this conductor in large production quantities based on the cost model presented could meet the 1.5 $/kilo amp meter(KAM) target of the HEP community

  3. Influence of current density on microstructure of pulse electrodeposited tin coatings

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ashutosh; Bhattacharya, Sumit; Sen, Ranjan; Reddy, B.S.B. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology-Kharagpur, Kharagpur-721302 (India); Fecht, H.-J. [Institut fuer Mikro- und Nanomaterialien, Universitaet Ulm, D-89081 Ulm (Germany); Das, Karabi, E-mail: karabi@metal.iitkgp.ernet.in [Department of Metallurgical and Materials Engineering, Indian Institute of Technology-Kharagpur, Kharagpur-721302 (India); Das, Siddhartha [Department of Metallurgical and Materials Engineering, Indian Institute of Technology-Kharagpur, Kharagpur-721302 (India)

    2012-06-15

    Pulse electrodeposited tin coatings on copper substrate have been synthesized from an aqueous solution containing sodium stannate (Na{sub 2}SnO{sub 3}.3H{sub 2}O) and sodium hydroxide (NaOH). The effect of current density on surface morphology of the deposits has been investigated. As deposited coatings are characterized by X-ray diffraction, scanning electron microscopy, electron backscatter diffraction, and line profile analysis. The X-ray diffraction analysis shows that the deposits consist of tetragonal ({beta}-Sn) structure with microcrystalline grains. The deposits plated at lower current density exhibit (110) texture which decreases with increasing current densities. The effects of current density on Cu-Sn diffusion and whisker growth of the electrodeposited tin coatings are also reported here. - Highlights: Black-Right-Pointing-Pointer Pulse electrodeposition of Sn from aqueous alkaline solution without adding any organic additive. Black-Right-Pointing-Pointer Effect of current density on morphology and whisker growth in tin coatings aged for 1 year. Black-Right-Pointing-Pointer Solution bath is stable and can be operated over a wide range of current density.

  4. The interfacial structure of plated copper alloy resistance spot welded joint

    Science.gov (United States)

    Wu, Jingwei; Zhai, Guofu; Chen, Qing; Wang, Jianqi; Ren, Gang

    2008-09-01

    Plated copper alloys are widely used in electron industry. The plating lay caused the farther decreasing of the welding property of copper alloys, whose intrinsic weldability was poor. In this paper, the bronze and brass specimens with nickel-tin double plating layer were joined by resistance spot welding method. The microstructure and peel strength of the joints were investigated. The experiment results show that a sandwich-like structure was obtained in the faying surface after welding, and the nickel plating layer thickness had severe effect on the reliability of the joints.

  5. The interfacial structure of plated copper alloy resistance spot welded joint

    Energy Technology Data Exchange (ETDEWEB)

    Wu Jingwei [Xiamen Hongfa Electroacoustic Co., Ltd, 361021 Xiamen (China); Harbin Institute of Technology, 150001 Harbin (China)], E-mail: jingweiwu.hit@gmail.com; Zhai Guofu [Harbin Institute of Technology, 150001 Harbin (China); Chen Qing; Wang Jianqi; Ren Gang [Xiamen Hongfa Electroacoustic Co., Ltd, 361021 Xiamen (China)

    2008-09-15

    Plated copper alloys are widely used in electron industry. The plating lay caused the farther decreasing of the welding property of copper alloys, whose intrinsic weldability was poor. In this paper, the bronze and brass specimens with nickel-tin double plating layer were joined by resistance spot welding method. The microstructure and peel strength of the joints were investigated. The experiment results show that a sandwich-like structure was obtained in the faying surface after welding, and the nickel plating layer thickness had severe effect on the reliability of the joints.

  6. Third-generation muffin–tin orbitals

    Indian Academy of Sciences (India)

    O K Andersen; T Saha-Dasgupta; S Ezhov

    2003-01-01

    By the example of $sp^3$-bonded semiconductors, we illustrate what 3rd-generation muffin–tin orbitals (MTOs) are. We demonstrate that they can be downfolded to smaller and smaller basis sets: $sp^3d^{10}, sp^3$, and bond orbitals. For isolated bands, it is possible to generate Wannier functions a priori. Also for bands, which overlap other bands, Wannier-like MTOs can be generated a priori. Hence, MTOs have a unique capability for providing chemical understanding.

  7. Analysis of bell materials: Tin bronzes

    Institute of Scientific and Technical Information of China (English)

    Jaromir Audy; Katarina Audy

    2008-01-01

    The present study was set up to examine the effect of alloying elements (including harmful elements) on metallurgical features (material properties and qualitative parameters) of tin bronzes, with particular reference to church bells from Middle Ages to Current times. A driving force of this study was to identify and demonstrate features related to the quality of church bells made in different centuries. The findings have been derived via metallographic and chemical analysis of specimens of bells from various parts of Australasia and Europe. The bell materials consisted of a mixture of the a phase and the (α+β) eutectoid essentially, in proportions determined by tin content and mould materials during casting. The samples from the 15th century to the one from the 20th century showed a progressive increase in hardness, ranging from the minimum of -280 VHM20g to a maximum of -470 VHM20g for the (α+β) eutectoid, and -160 VHM20g to -230 VHM20g for the a phase. The investigation also shows that the sound decay of the bell decreased with lowering the wt.% of tin and increasing the wt.% of lead and silver. This information is expected to provide an additional interesting knowledge into manufacturing practices and their significance in the quality of church bells over past centuries.

  8. Fission product release model for failed plate-type fuel element and storage under water; Modelo para liberacao de produtos de fissao por placa combustivel falhada e armazenada sob agua

    Energy Technology Data Exchange (ETDEWEB)

    Terremoto, L.A.A.; Zeituni, C.A.; Silva, J.E.R. da; Castanheira, M.; Lucki, G.; Silva, A.T. e; Teodoro, C.A.; Damy, M. de A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Centro de Engenharia Nuclear]. E-mail: laaterre@ipen.br

    2005-07-01

    Plate-type fuel elements burned-up inside the core of nuclear research reactors are stored mainly under deionized water of storage pools. When cladding failure occurs in such elements, radioactive fission products are released into the storage pool water. This work proposes a model to describe the release mechanism considering the diffusion through a postulated small cylindrical failure. As a consequence, an analytical expression is obtained for the activity released into the water as a function of the total storage time of a failed fuel plate. The proposed model reproduces the linear increasing of {sup 137}Cs specific activity observed in sipping tests already performed on failed plate-type fuel elements. (author)

  9. Anomalous infrared transmission of indium tin oxide thin films on two-dimensional nanosphere arrays.

    Science.gov (United States)

    Jiang, Hang; Zhou, Yuqin; Zhou, Yurong

    2016-04-15

    The excitation of surface plasmons was studied by nano-structural indium tin oxide (ITO) films in the infrared range using nano-imprint lithography (NIL). We investigated the effect of the diameter of silica spheres, thickness of ITO film, and ordering degree of the mask plate on the transmission spectra of structural ITO films by experiments and simulations. Increasing the diameter of silica spheres makes the transmission valley blueshift, while increasing the thickness of ITO film leads the transmission valley redshift. The transmission valley corresponds to the absorption band which results from the excitation of surface plasmons. The ordering degree and the surface coverage ratios of mask plate affect the transmission feature directly. An excitation of local surface plasmons may exist on the undulated ITO surface.

  10. Electrorheological fluids of polypyrrole-tin oxide nanocomposite particles

    Science.gov (United States)

    Kim, Young Dae; Yoon, Dae Jeon

    2016-11-01

    The electrorheological (ER) response of polypyrrole(PPy)-tin oxide nanocomposite ER fluids increased with the increase in the tin oxide/pyrrole weight ratio, particle volume fraction, and electric field strength. The dielectric properties and direct current (dc) conductivity of PPy-tin oxide nanocomposite particles and the dielectric properties of PPy-tin oxide nanocomposite ER fluids agreed with the ER behaviors. The ER behavior of PPy-tin oxide nanocomposite ER fluids was well fitted to τ = 0.0248 ϕE 1.5 and showed a transition from that of the polarization model ( τ ˜ E 2) to that of the conduction model ( τ ˜ E 1.5) depending on the tin oxide/pyrrole weight ratio.

  11. Thermodynamics of the incongruently subliming niobium-tin system

    Energy Technology Data Exchange (ETDEWEB)

    Schiffman, R.A.; Bailey, D.M.

    1982-01-01

    The niobium-tin system was investigated in the temperature range 1261-2076 K by measurement of tin vapor pressures with a simultaneous weight loss-mass-spectrometric technique. For the reaction Nb + 1/3Sn ..-->.. NbSn/sub 1///sub 3/, ..delta..H/sub f//sup 298/ was found to be -21.59 kJ/mol. The heat of solution of tin in niobium was determined as a function of composition. The temperature-composition diagram for the niobium-tin system above 1200/sup 0/C was constructed. The Nb/sub 3/Sn phase has a narrow homogeneity range from 25 to 28 at% tin below 1600 K that broadens to include 18 at% tin at 2076 K.

  12. Heat Resistance of TiN Coated HSS Tools

    Institute of Scientific and Technical Information of China (English)

    周兰英; 周焕雷; 贾庆莲

    2003-01-01

    The cutting friction, cutting deformation, producing heat, conducting heat, temperature field of TiN coated HSS tools in the cutting process are discussed profoundly. In order to make clear the heat property of TiN coated tools, from the micromechanism angle, the relationship of the heat property and the crystal structure of TiN compound is analyzed, and the regularity of TiN compound crystal structure changing with temperature rising is sought. The difference of the wear resistance and heat resistance of TiN coated tools deposited by c1 and c2 depositing techniques is proved by tests. The conclusions will offer the theoretical basis for correct design of geometrical parameters of TiN coated tools, rational selection of cutting regimes and optimization of the depositing technique.

  13. Indonesian Landforms and Plate Tectonics

    Directory of Open Access Journals (Sweden)

    Herman Th. Verstappen

    2014-06-01

    Full Text Available DOI: 10.17014/ijog.v5i3.103The horizontal configuration and vertical dimension of the landforms occurring in the tectonically unstable parts of Indonesia were resulted in the first place from plate tectonics. Most of them date from the Quaternary and endogenous forces are ongoing. Three major plates – the northward moving Indo-Australian Plate, the south-eastward moving SE-Asian Plate and the westward moving Pacific Plate - meet at a plate triple-junction situated in the south of New Guinea’s Bird’s Head. The narrow North-Moluccan plate is interposed between the Asia and Pacific. It tapers out northward in the Philippine Mobile Belt and is gradually disappearing. The greatest relief amplitudes occur near the plate boundaries: deep ocean trenches are associated with subduction zones and mountain ranges with collision belts. The landforms of the more stable areas of the plates date back to a more remote past and, where emerged, have a more subdued relief that is in the first place related to the resistance of the rocks to humid tropical weathering Rising mountain ranges and emerging island arcs are subjected to rapid humid-tropical river erosions and mass movements. The erosion products accumulate in adjacent sedimentary basins where their increasing weight causes subsidence by gravity and isostatic compensations. Living and raised coral reefs, volcanoes, and fault scarps are important geomorphic indicators of active plate tectonics. Compartmental faults may strongly affect island arcs stretching perpendicular to the plate movement. This is the case on Java. Transcurrent faults and related pull-apart basins are a leading factor where plates meet at an angle, such as on Sumatra. The most complicated situation exists near the triple-junction and in the Moluccas. Modern research methods, such as GPS measurements of plate movements and absolute dating of volcanic outbursts and raised coral reefs are important tools. The mega-landforms resulting

  14. Indonesian Landforms and Plate Tectonics

    Directory of Open Access Journals (Sweden)

    Herman Th. Verstappen

    2014-06-01

    Full Text Available DOI: 10.17014/ijog.v5i3.103The horizontal configuration and vertical dimension of the landforms occurring in the tectonically unstable parts of Indonesia were resulted in the first place from plate tectonics. Most of them date from the Quaternary and endogenous forces are ongoing. Three major plates – the northward moving Indo-Australian Plate, the south-eastward moving SE-Asian Plate and the westward moving Pacific Plate - meet at a plate triple-junction situated in the south of New Guinea’s Bird’s Head. The narrow North-Moluccan plate is interposed between the Asia and Pacific. It tapers out northward in the Philippine Mobile Belt and is gradually disappearing. The greatest relief amplitudes occur near the plate boundaries: deep ocean trenches are associated with subduction zones and mountain ranges with collision belts. The landforms of the more stable areas of the plates date back to a more remote past and, where emerged, have a more subdued relief that is in the first place related to the resistance of the rocks to humid tropical weathering Rising mountain ranges and emerging island arcs are subjected to rapid humid-tropical river erosions and mass movements. The erosion products accumulate in adjacent sedimentary basins where their increasing weight causes subsidence by gravity and isostatic compensations. Living and raised coral reefs, volcanoes, and fault scarps are important geomorphic indicators of active plate tectonics. Compartmental faults may strongly affect island arcs stretching perpendicular to the plate movement. This is the case on Java. Transcurrent faults and related pull-apart basins are a leading factor where plates meet at an angle, such as on Sumatra. The most complicated situation exists near the triple-junction and in the Moluccas. Modern research methods, such as GPS measurements of plate movements and absolute dating of volcanic outbursts and raised coral reefs are important tools. The mega-landforms resulting

  15. Characterization of tin dioxide nanoparticles synthesized by oxidation

    OpenAIRE

    Abruzzi,R. C.; B. A. Dedavid; Pires,M. J. R.

    2015-01-01

    AbstractTin dioxide (SnO2) is a promising material with great potential for applications such as gas sensors and catalysts. Nanostructures of this oxide exhibit greater activation efficiency given their larger effective surface. The present study presents results of the synthesis and characterization of tin dioxide under different conditions via oxidation of solid tin with nitric oxide. SnO2powder was characterized primarily by X-ray diffraction and scanning electron microscopy, as well as co...

  16. Optimization of infrared and magnetic shielding of superconducting TiN and Al coplanar microwave resonators

    Science.gov (United States)

    Kreikebaum, J. M.; Dove, A.; Livingston, W.; Kim, E.; Siddiqi, I.

    2016-10-01

    We present a systematic study of the effects of shielding on the internal quality factors ({Q}{{i}}) of Al and TiN microwave resonators designed for use in quantum coherent circuits. Measurements were performed in an adiabatic demagnetization refrigerator, where typical magnetic fields of 200 μT are present at the unshielded sample stage. Radiation shielding consisted of 100 and 500 mK Cu cans coated with infrared absorbing epoxy. Magnetic shields consisted of Cryoperm 10 and Sn plating of the Cu cans. A 2.7 K radiation can and coaxial thermalization filters were present in all measurements. TiN samples with {Q}{{i}}=1.3 × {10}6 at 100 mK exhibited no significant variation in quality factor when tested with limited shielding. In contrast, Al resonators showed improved {Q}{{i}} with successive shielding, with the largest gains obtained from the addition of the first radiation and magnetic shields and saturating before the addition of Sn plating infrared absorbing epoxy.

  17. Optimization of infrared and magnetic shielding of superconducting TiN and Al coplanar microwave resonators

    CERN Document Server

    Kreikebaum, John Mark; Livingston, William; Kim, Eunseong; Siddiqi, Irfan

    2016-01-01

    We present a systematic study of the effects of shielding on the internal quality factors (Qi) of Al and TiN microwave resonators designed for use in quantum coherent circuits. Measurements were performed in an adiabatic demagnetization refrigerator, where typical magnetic fields of 200 {\\mu}T are present at the unshielded sample stage. Radiation shielding consisted of 100 mK and 500 mK Cu cans coated with infrared absorbing epoxy. Magnetic shields consisted of Cryoperm 10 and Sn plating of the Cu cans. A 2.7 K radiation can and coaxial thermalization filters were present in all measurements. TiN samples with Qi = $1.3*10^6$ at 100 mK exhibited no significant variation in quality factor when tested with limited shielding. In contrast, Al resonators showed improved Qi with successive shielding, with the largest gains obtained from the addition of the first radiation and magnetic shields and saturating before the addition of Sn plating infrared absorbing epoxy.

  18. Silicon- and tin-based cuprates: now catalytic in copper!

    Science.gov (United States)

    Weickgenannt, Andreas; Oestreich, Martin

    2010-01-11

    Silicon- and tin-containing molecules are versatile building blocks in organic synthesis. A stalwart method for their preparation relies on the stoichiometric use of silicon- and tin-based cuprates, although a few copper(I)-catalyzed or even copper-free protocols have been known for decades. In this Concept, we describe our efforts towards copper(I)-catalyzed carbon--silicon and also carbon--tin bond formations using soft bis(triorganosilyl) and bis(triorganostannyl) zinc reagents as powerful sources of nucleophilic silicon and tin. Conjugate addition, allylic substitution, and carbon--carbon multiple bond functionalization is now catalytic in copper!

  19. Atomic dynamics of tin nanoparticles embedded into porous glass

    Energy Technology Data Exchange (ETDEWEB)

    Parshin, P. P.; Zemlyanov, M. G., E-mail: zeml@isssph.kiae.ru; Panova, G. Kh.; Shikov, A. A. [Russian Research Centre Kurchatov Institute (Russian Federation); Kumzerov, Yu. A.; Naberezhnov, A. A. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation); Sergueev, I.; Crichton, W. [European Synchrotron Radiation Facility (France); Chumakov, A. I. [Russian Research Centre Kurchatov Institute (Russian Federation); Rueffer, R. [European Synchrotron Radiation Facility (France)

    2012-03-15

    The method of resonant nuclear inelastic absorption of synchrotron radiation has been used to study the phonon spectrum for tin nanoparticles (with a natural isotope mixture) embedded into a porous glassy (silica) matrix with an average pore diameter of 7 nm in comparison to the analogous spectrum of bulk tin enriched with {sup 119}Sn isotope. Differences between the spectra have been observed, which are related to both the dimensional effects and specific structural features of the porous glass-tin nanocomposite. Peculiarities in the dynamics of tin atoms embedded into nanopores of glass are interpreted in terms of a qualitative model of the nanocomposite structure.

  20. Development of microtitre plates for electrokinetic assays

    Science.gov (United States)

    Burt, J. P. H.; Goater, A. D.; Menachery, A.; Pethig, R.; Rizvi, N. H.

    2007-02-01

    Electrokinetic processes have wide ranging applications in microsystems technology. Their optimum performance at micro and nano dimensions allows their use both as characterization and diagnostic tools and as a means of general particle manipulation. Within analytical studies, measurement of the electrokinesis of biological cells has the sensitivity and selectivity to distinguish subtle differences between cell types and cells undergoing changes and is gaining acceptance as a diagnostic tool in high throughput screening for drug discovery applications. In this work the development and manufacture of an electrokinetic-based microtitre plate is described. The plate is intended to be compatible with automated sample loading and handling systems. Manufacturing of the microtitre plate, which employs indium tin oxide microelectrodes, has been entirely undertaken using excimer and ultra-fast pulsed laser micromachining due to its flexibility in materials processing and accuracy in microstructuring. Laser micromachining has the ability to rapidly realize iterations in device prototype design while also having the capability to be scaled up for large scale manufacture. Device verification is achieved by the measurement of the electrorotation and dielectrophoretic properties of yeast cells while the flexibility of the developed microtitre plate is demonstrated by the selective separation of live yeast from polystyrene microbeads.

  1. Comparative evaluation of direct plating and most probable number for enumeration of low levels of Listeria monocytogenes in naturally contaminated ice cream products.

    Science.gov (United States)

    Chen, Yi; Pouillot, Régis; S Burall, Laurel; Strain, Errol A; Van Doren, Jane M; De Jesus, Antonio J; Laasri, Anna; Wang, Hua; Ali, Laila; Tatavarthy, Aparna; Zhang, Guodong; Hu, Lijun; Day, James; Sheth, Ishani; Kang, Jihun; Sahu, Surasri; Srinivasan, Devayani; Brown, Eric W; Parish, Mickey; Zink, Donald L; Datta, Atin R; Hammack, Thomas S; Macarisin, Dumitru

    2017-01-16

    A precise and accurate method for enumeration of low level of Listeria monocytogenes in foods is critical to a variety of studies. In this study, paired comparison of most probable number (MPN) and direct plating enumeration of L. monocytogenes was conducted on a total of 1730 outbreak-associated ice cream samples that were naturally contaminated with low level of L. monocytogenes. MPN was performed on all 1730 samples. Direct plating was performed on all samples using the RAPID'L.mono (RLM) agar (1600 samples) and agar Listeria Ottaviani and Agosti (ALOA; 130 samples). Probabilistic analysis with Bayesian inference model was used to compare paired direct plating and MPN estimates of L. monocytogenes in ice cream samples because assumptions implicit in ordinary least squares (OLS) linear regression analyses were not met for such a comparison. The probabilistic analysis revealed good agreement between the MPN and direct plating estimates, and this agreement showed that the MPN schemes and direct plating schemes using ALOA or RLM evaluated in the present study were suitable for enumerating low levels of L. monocytogenes in these ice cream samples. The statistical analysis further revealed that OLS linear regression analyses of direct plating and MPN data did introduce bias that incorrectly characterized systematic differences between estimates from the two methods.

  2. Synthesis of tin and tin oxide nanoparticles of low size dispersity for application in gas sensing.

    Science.gov (United States)

    Nayral, C; Viala, E; Fau, P; Senocq, F; Jumas, J C; Maisonnat, A; Chaudret, B

    2000-11-17

    Nanocomposite core-shell particles that consist of a Sn0 core surrounded by a thin layer of tin oxides have been prepared by thermolysis of [(Sn(NMe2)2)2] in anisole that contains small, controlled amounts of water. The particles were characterized by means of electronic microscopies (TEM, HRTEM, SEM), X-ray diffraction (XRD) studies, photoelectron spectroscopy (XPS), and Mossbauer spectroscopy. The TEM micrographs show spherical nanoparticles, the size and size distribution of which depends on the initial experimental conditions of temperature, time, water concentration, and tin precursor concentration. Nanoparticles of 19 nm median size and displaying a narrow size distribution have been obtained with excellent yield in the optimized conditions. HRTEM, XPS, XRD and Mossbauer studies indicate the composite nature of the particles that consist of a well-crystallized tin beta core of approximately equals 11 nm covered with a layer of approximately equals 4 nm of amorphous tin dioxide and which also contain quadratic tin monoxide crystallites. The thermal oxidation of this nanocomposite yields well-crystallized nanoparticles of SnO2* without coalescence or size change. XRD patterns show that the powder consists of a mixture of two phases: the tetragonal cassiterite phase, which is the most abundant, and an orthorhombic phase. In agreement with the small SnO2 particle size, the relative intensity of the adsorbed dioxygen peak observed on the XPS spectrum is remarkable, when compared with that observed in the case of larger SnO2 particles. This is consistent with electrical conductivity measurements, which demonstrate that this material is highly sensitive to the presence of a reducing gas such as carbon monoxide.

  3. Processless offset printing plates

    Directory of Open Access Journals (Sweden)

    Sanja Mahović Poljaček

    2015-06-01

    Full Text Available With the implementation of platesetters in the offset printing plate making process, imaging of the printing plate became more stable and ensured increase of the printing plate quality. But as the chemical processing of the printing plates still highly influences the plate making process and the graphic reproduction workflow, development of printing plates that do not require chemical processing for offset printing technique has been one of the top interests in graphic technology in the last few years. The main reason for that came from the user experience, where majority of the problems with plate making process could be connected with the chemical processing of the printing plate. Furthermore, increased environmental standards lead to reducing of the chemicals used in the industrial processes. Considering these facts, different types of offset printing plates have been introduced to the market today. This paper presents some of the processless printing plates.

  4. Synthesis and Characterization of Tin(IV) Oxide Obtained by Chemical Vapor Deposition Method

    Science.gov (United States)

    Nagirnyak, Svitlana V.; Lutz, Victoriya A.; Dontsova, Tatiana A.; Astrelin, Igor M.

    2016-07-01

    The effect of precursors on the characteristics of tin oxide obtained by chemical vapor deposition (CVD) method was investigated. The synthesis of nanosized tin(IV) oxide was carried out with the use of two different precursors: tin(II) oxalate obtained using tin chloride(II) and oxalic acid; tin(II) oxalate obtained using tin chloride(II); and ammonium oxalate. The synthesized tin(IV) oxide samples were studied by electron microscopy, X-ray diffraction and optical spectra. The lattice parameters of tin(IV) oxide samples were defined, the bandgap of samples were calculated.

  5. 辊底式淬火炉在铝合金中厚板生产中的应用%Application of Roller-hearth Quenching Furnace in Production of Aluminum Alloy Plate

    Institute of Scientific and Technical Information of China (English)

    李志刚

    2015-01-01

    This paper reviewed the application and development of rol er-hearth quenching furnace in the production of aluminum al oy plate,and it il ustrated structural features and technical characteristics of the furnace.%介绍了辊底式淬火炉在铝合金中厚板生产中的应用情况,详细描述了辊底式淬火炉的结构特点和技术性能。

  6. Quantifying Cutting and Wearing Behaviors of TiN- and CrN-Coated AISI 1070 Steel

    Science.gov (United States)

    Cakan, Ahmet; Ozkaner, Vedat; Yildirim, Mustafa M.

    2008-01-01

    Hard coatings such as titanium nitride (TiN) and chromium nitride (CrN) are widely used in cutting and forming tools against wear and corrosion. In the present study, hard coating films were deposited onto AISI 1070 steels by a cathodic arc evaporation plating (CAVP) technique. These samples were subjected to wear in a conventional lathe for investigating the tribological behaviour of coating structure, and prenitrided subsurface composition was characterized using scanning electron microscopy (SEM), line scan analyses and X-ray diffraction (XRD). The wear properties of TiN- and CrN-coated samples were determined using an on-line monitoring system. The results show that TiN-coated samples demonstrate higher wear resistance than CrN-coated samples. PMID:27873912

  7. Tin cans and refuse incineration: upgrading the scrap

    NARCIS (Netherlands)

    Dapper, G.; Dijkstra, S.J.; Loon, van A.P.M.

    1978-01-01

    In the series of investigations whether and how it is possible to reclaim the iron and tin constituents after incineration, several experiments were performed with the refuse incinerator of Amsterdam. The operating conditions were varied and the influence on the behaviour of the tin cans were determ

  8. Solution of a tinned iron purchasing problem by Lagrangean relaxation

    NARCIS (Netherlands)

    Dorhout, B.

    1995-01-01

    A tin factory obtains its material from steel works. This consists of sheets of tinned iron which may have very diverging specifications with respect to length, width, thickness, and thicknesses of tinfoils. Prices per unit of volume vary with width and thickness. For large quantities of the same si

  9. Mechanical Properties of Glass Surfaces Coated with Tin Oxide

    DEFF Research Database (Denmark)

    Swindlehurst, W. E.; Cantor, B.

    1978-01-01

    of tin tetrachloride on industrial soda glass at ~800K to thicknesses of ~3×10-8 and 3×10 -7 m, commercially by the `titanising' process on industrial soda glass at ~800K to a thickness of ~3.10-9 m, and in the laboratory by radio frequency sputtering from tin oxide powder over a range of glass...

  10. Metallic tin-based nanoparticles synthesis by laser pyrolysis: Parametric studies focused on the decreasing of the crystallite size

    Energy Technology Data Exchange (ETDEWEB)

    Dutu, E. [National Institute for Lasers, Plasma and Radiation Physics, Lasers Dept, Bucharest—Magurele, 409, Atomistilor Street, 077125 (Romania); Dumitrache, F., E-mail: dumitracheflorian@yahoo.com [National Institute for Lasers, Plasma and Radiation Physics, Lasers Dept, Bucharest—Magurele, 409, Atomistilor Street, 077125 (Romania); “Politehnica” University of Bucharest, Physics Department, Independentei 313, Bucharest (Romania); Fleaca, C.T. [National Institute for Lasers, Plasma and Radiation Physics, Lasers Dept, Bucharest—Magurele, 409, Atomistilor Street, 077125 (Romania); “Politehnica” University of Bucharest, Physics Department, Independentei 313, Bucharest (Romania); Morjan, I.; Gavrila-Florescu, L.; Morjan, I.P.; Sandu, I.; Scarisoreanu, M.; Luculescu, C.; Niculescu, A.-M. [National Institute for Lasers, Plasma and Radiation Physics, Lasers Dept, Bucharest—Magurele, 409, Atomistilor Street, 077125 (Romania); Vasile, E. [“Politehnica” University of Bucharest, Faculty of Applied Chemistry and Material Science, Dept. of Oxide Materials and Nanomaterials, 1-7, Gh. Polizu Street, 011061 Bucharest (Romania)

    2015-05-01

    Highlights: • Metallic tin-based nanoparticles were synthesized using laser pyrolysis technique. • Tetramethyltin was used as precursors whereas ethylene was the sensitizer. • The nanoparticles where covered with a tin oxidized/carbonaceous shell. • Their size where decreased by diminishing the laser beam residence time. - Abstract: Due to their characteristic to allow a continuous, one-step nanosize particles production, the laser pyrolysis technique was employed to synthesize metallic Sn-based nanoparticles using tetramethyltin vapors as precursors and ethylene as laser energy transfer agent (sensitizer). Small size of tin particles is a requirement for their use as anodes in lithium ion batteries. In order to decrease the particle size, some experimental parameters were varied, allowing the control of the crystallite size down to 30 nm. The diminishing diameter of the reactive flow injection nozzle as well as the increasing of the tin precursor vapor flow enhance the gas velocity and the decrease the reactive species residence time in the laser beam, resulting smaller tin nanodroplets which forms solid nanoparticles after rapid cooling. XRD, TEM, EDX and SAED analysis point to the formation of nanosize β-Sn particles accompanied by various amount of disordered carbon as coating provided by ethylene decomposition (associated with their polymerization/dehydrogenation) in the presence of methyl radicals from Sn(CH{sub 3}){sub 4}.

  11. Performance evaluation of reactive direct current unbalanced magnetron sputter deposited nanostructured TiN coated high-speed steel drill bits

    Indian Academy of Sciences (India)

    Harish C Barshilia; K S Rajam

    2007-12-01

    The stainless steels, in general, are considered to be difficult-to-machine materials. In order to machine these materials the surface of the tool is generally coated with physical vapour deposition (PVD) hard coatings such as titanium nitride (TiN), titanium aluminum nitride (TiAlN), etc. The adhesion is of vital importance for the performance of tools coated with PVD coatings. Proper surface treatments (in situ and ex situ) are required to achieve highly adherent PVD coatings on tools. We have deposited nanostructured TiN coatings on high-speed steel (HSS) drill bits and mild steel substrates using an indigenously built semi-industrial fourcathode reactive direct current (d.c.) unbalanced magnetron sputtering system. Various treatments have been given to the substrates for improved adhesion of the TiN coatings. The process parameters have been optimized to achieve highly adherent thick good quality TiN coatings. These coatings have been characterized using X-ray diffraction, nanoindentation and atomic force microscopy techniques. The performance of the coated HSS drill bits is evaluated by drilling a 13 mm thick 304 stainless steel plate under wet conditions. The results show significant improvement in the performance of the TiN coated HSS drill bits.

  12. Fabrication of graded TiN coatings on nitinol occluders and effects on in vivo nickel release.

    Science.gov (United States)

    Zhang, Deyuan; Zhang, Zhiwei; Zi, Zhenjun; Zhang, Yanhong; Zeng, Weijun; Chu, Paul K

    2008-01-01

    A nano-structured TiN/Ti coating with a total thickness of 0.9 mum was deposited on nitinol cardiac occluders using the filtered multi-arc vacuum ion plating technique at less than 300 degrees C. The coating was composed of laminated TiN/Ti layers with thickness of about 100 nm. The cardiac occluders made of a nitinol mesh with and without a graded nano-structured titanium nitride (TiN) coating were implanted into the hearts of rams. The nickel concentration of the whole blood of the animals were measured one week, one month, three months, and six months after implantation and compared to that before operation. The nickel concentration in the neo-endocardium covered occluders was also measured using graphite furnace atomic absorption spectrophotometry. After one week, the nickel content in the blood increased by a factor of three compared to the level before operation and decreased afterwards returning to the normal level after six months when endothelialization was complete. Statistical analyses showed that the TiN coating could mitigate nickel release into blood (PTiN coated occluder after 7 days. The nickel concentration in the neo-endocardium covered and TiN coated occluders reached 17.0+/-8.05 microg/kg in two months after implantation. In comparison, it was 31.0+/-5.72 microg/kg for the occluder without the TiN coating. While normal concentration of nickel in endocardium is also 2.6+/-1.09 microg/kg. Our results demonstrate that the graded TiN coating can significantly reduce nickel release into the endocardium (P<0.01) under in vivo conditions.

  13. Safety and efficacy of nano lamellar TiN coatings on nitinol atrial septal defect occluders in vivo

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhi xiong, E-mail: Top5460@163.com [Research Institute of Peking University in Shenzhen, Shenzhen 518057 (China); Fu, Bu fang, E-mail: fubnicpbp@163.com [National Institutes for Food and Drug Control, Beijing (China); Zhang, De yuan, E-mail: Deyuanzhangcn@yahoo.com.cn [Lifetech Scientific (Shenzhen) Co., Ltd., Shenzhen (China); Zhang, Zhi wei, E-mail: Zhzhx65@163.com [Guangdong Cardiovascular Institute, Guangzhou (China); Cheng, Yan, E-mail: chengyan@pku.edu.cn [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing (China); Sheng, Li yuan, E-mail: lysheng@yeah.net [Research Institute of Peking University in Shenzhen, Shenzhen 518057 (China); Lai, Chen, E-mail: laichen1110@163.com [Research Institute of Peking University in Shenzhen, Shenzhen 518057 (China); Xi, Ting fei, E-mail: Xitingfie@pku.edu.cn [Research Institute of Peking University in Shenzhen, Shenzhen 518057 (China); Academy for Advanced Interdisciplinary Studies, Peking University, Beijing (China)

    2013-04-01

    Atrial septal defect (ASD) occlusion devices made of nickel–titanium (NiTi) have a major shortcoming in that they release nickel into the body. We modified NiTi occluders using Arc Ion Plating technology. Nano lamellar titanium–nitrogen (TiN) coatings were formed on the surfaces of the occluders. The safety and efficacy of the modified NiTi occluders were evaluated in animal model. The results showed that 38 out of 39 rams (97%) survived at the end of the experiment. Fibrous capsules formed on the surfaces of the devices. Gradual endothelialization took place through the attachment of endothelial progenitor cells from the blood and the migration of endothelial cells from adjacent endocardium. The neo-endocardium formed more quickly in the coated group than in the uncoated group, as indicated by the evaluation of the six month study group. After TiN coating, there was no significant difference in endothelial cell cycle. TiN coating significantly reduced the release of nickel in both in vivo and in vitro indicating an improved biocompatibility of the nitinol ASD occluders. Superior and modified ASD occluders may provide a good choice for people with nickel allergies after sFDA registration, which is expected in one to two years. - Highlights: ► The nano lamella TiN coating did not change the shape-memory behavior and flexibility of the nitinol occluder. ► Nano lamella TiN coating modifications significantly reduced nickel release from nitinol ASD occluder. ► The new ASD occluder was found to be superior to nitinol ASD occluder with respect to both safety and efficacy.

  14. Een verkeerde loop in ’t vuur: an initial investigation into what Dutch archival sources can tell us about techniques and problems in the production of 17th and 18th century Dutch tin-glaze tiles

    NARCIS (Netherlands)

    van Lookeren Campagne, K.; Delgado Rodrigues, J.; Mimoso, J.M.

    2016-01-01

    Technical art-historical archival sources can be invaluable for our knowledge and understanding of the origin and preparation of materials as well as the production techniques used to make ceramic objects. The information provided could also aid our understanding of the factors that influence suscep

  15. Een verkeerde loop in ’t vuur: an initial investigation into what Dutch archival sources can tell us about techniques and problems in the production of 17th and 18th century Dutch tin-glaze tiles

    NARCIS (Netherlands)

    van Lookeren Campagne, K.; Delgado Rodrigues, J.; Mimoso, J.M.

    2016-01-01

    Technical art-historical archival sources can be invaluable for our knowledge and understanding of the origin and preparation of materials as well as the production techniques used to make ceramic objects. The information provided could also aid our understanding of the factors that influence

  16. Les peintures marines antisalissures à base de polymères organostanniques Antifouling Marine Paints Containing Organo-Tin Polymers

    Directory of Open Access Journals (Sweden)

    Dawans F.

    2006-11-01

    Full Text Available Le dépôt des salissures marines sur les ouvrages immergés est influencé par plusieurs facteurs et il entraîne des conséquences néfastes, en particulier pour la maintenance des supports de plates-formes de production du pétrole en mer et pour la consommation d'énergie requise pour la propulsion des navires. Divers moyens de lutte antisalissure ont été envisagés parmi lesquels les peintures marines antisalissures occupent une place de choix. Ces peintures contiennent, en général, un composé métallique toxique envers les organismes marins d'origine animale ou végétale et différents mécanismes d'action ont été proposés. Les dérivés organostanniques sont des agents biocides très efficaces et lorsqu'ils sont liés chimiquement sur un polymère, en particulier sous forme de greffons, on obtient un contrôle amélioré de leur lixiviation dans la phase aqueuse et par conséquent la durée de vie du revêtement antisalissure est prolongée. La synthèse de polymères comportant un cation organostannique toxique peut être effectuée, soit par la polymérisation ou la copolymérisation de monomères insaturés organostanniques, soit par la réaction chimique de composés organostanniques avec un substrat polymère comportant des groupes fonctionnels appropriés. Les avantages et les inconvénients de diverses formulations de peintures à base de dérivés organostanniques sont discutés. Marine fouling deposits on submerged structures are influenced by several factors and bring about harmful consequences, especially with regard to offshore oil-production platform structures and for the energy consumption required for ship propulsion. Various antifouling methods have been considered, including antifouling marine coatings in particular. Such paints generally contain a metallic compound which is toxic with regard to marine organisms of animal or vegetable origin, and various action mechanisms have been proposed. Organo-tin

  17. Xenon behavior in TiN: A coupled XAS/TEM study

    Science.gov (United States)

    Bès, R.; Gaillard, C.; Millard-Pinard, N.; Gavarini, S.; Martin, P.; Cardinal, S.; Esnouf, C.; Malchère, A.; Perrat-Mabilon, A.

    2013-03-01

    Titanium nitride is a refractory material that is being considered as an inert matrix in future Generation IV nuclear reactors, in particular in relation to the Gas-cooled Fast Reactor. The main role of this matrix would be to act as a barrier against the release of fission products, in particular gaseous ones like xenon. This release phenomenon will be enhanced by high temperatures expected in the fuel vicinity: 1200 °C under normal conditions, and up to 1800 °C under accidental conditions. It is therefore necessary to investigate the behavior of volatile fission products in TiN under high temperature and irradiation. Indeed, these basic data are very useful to predict the volatile fission products released under these extreme conditions. Our previous work has shown that Xe introduced by ion implantation in sintered TiN tends to be released as a result of annealing, due to a transport mechanism towards the sample surface. The aim of the present work is to determine under which physical state Xe is in TiN. Xenon was first introduced using ion implantation at 800 keV in TiN samples obtained by hot pressing at several concentrations ranging from 0.4 to 8 at.%. Secondly, samples were annealed at high temperature, from 1000 °C to 1500 °C. Xe was then characterized by X-ray Absorption Spectroscopy and Transmission Electron Microscopy. The formation of intragranular xenon bubbles was demonstrated, and the xenon concentration which is sufficient to form bubbles is found to be lower than 0.4 at.% under our experimental conditions. These bubbles were found unpressurised at 15 K. Their size increases with the temperature and the local xenon concentration. For the highest xenon concentrations, a mechanism involving the formation of a Xe interconnected bubble network is proposed to explain Xe massive release observed by Rutherford Backscattering Spectrometry experiments.

  18. Crane Scheduling for a Plate Storage

    DEFF Research Database (Denmark)

    Hansen, Jesper; Clausen, Jens

    2002-01-01

    Odense Steel Shipyard produces the worlds largest container ships. The first process of producing the steel ships is handling arrival and storage of steel plates until they are needed in production. This paper considers the problem of scheduling two cranes that carry out the movements of plates...

  19. Quality Assurance of Process Free Thermal Plates

    Directory of Open Access Journals (Sweden)

    Thomas Hoffmann-Walbeck

    2015-09-01

    Full Text Available In this paper a method for manual processing of process free printing plates is defined which ensures reproducible results. This decoating procedure can help print service providers with certain quality checks (like linearization that are otherwise more expensive or even not feasible altogether for such plates. This method holds for quality assurance only and is not suitable for the actual production.

  20. Effect of Surface Properties of Tinplating Product on Finishing%镀锡板表面特性对涂饰性的影响研究

    Institute of Scientific and Technical Information of China (English)

    魏烈省; 李秀军; 韦晓

    2014-01-01

    镀锡板在食品包装领域有着广泛的应用。本文采用电子扫描电镜、电化学分析和划痕分析方法,研究了镀锡表面性能对涂饰性的影响。结果表明,镀锡板表面钝化膜含铬量对涂饰性有着重要的影响。当钝化膜含铬量控制10~20 mg/m2范围内,镀锡板表面具有较好的涂饰性。烘烤温度和烘烤时间对镀锡板表面形貌和耐蚀性无明显影响,但对涂饰性有着明显影响。烘烤时间为15 min ,烘烤温度在200℃左右,镀锡板表面与漆膜具有较好的结合力。%Tin plate in the field of food packaging has been widely used . In this paper , effect of the surface properties of tinplating product on finishing is studied by means of scanning electron microscopy ( SEM) , electrochemistry and scratch methods . The results showed that tin plate surface passivation film of chromium coating has an important impact on the finishing properties . When the amount of chromium passivation film containing is fixed at the range of 10mg/m2~ 20mg/m2 , tin plate has a better finishing of the surface . Baking temperature and baking time had no significant effect on the tin plate surface morphology and corrosion resistance , but has a significant effect on the coating properties . When baking time was of 15min and the baking temperature at 200 ℃ , tin plate surface and the film has good adhesion .

  1. Ti-N films created in close vicinity of transition from. alpha. -Ti(N) to. delta. -TiN sub x phase

    Energy Technology Data Exchange (ETDEWEB)

    Poulek, V.; Musil, J. (Inst. of Physics, Czechoslovak Academy of Sciences, Prague (Czechoslovakia)); Valvoda, V.; Dobiasova, L. (Charles Univ., Prague (Czechoslovakia))

    1991-07-07

    Ti-N films with nitrogen content ranging from 20 to 40 at.% are multiphase films which can contain {alpha}-Ti(N)+{delta}-TiN{sub x}, {alpha}-Ti(N)+{epsilon}-Ti{sub 2}N or {alpha}-Ti(N)+{epsilon}-Ti{sub 2}N+{delta}-TiN{sub x} phases. Mixed phase films exhibit some extraordinary properties in comparison with single-phase films. It was found that growth of the {epsilon}-Ti{sub 2}N phase is very sensitive to changes of some deposition parameters, especially the substrate surface temperature T{sub s}, the substrate ion current density i{sub s}, the ion energy E{sub i} and the deposition rate a{sub D}. The growth can be controlled not only by the substrate temperature T{sub s} under equilibrium conditions but also by the energy density S{sub E}=i{sub s}E{sub i}/a{sub D} delivered to the growing film. Special attention is devoted to films produced at surface temperatures T{sub s} lower than that necessary for the production of films containing the {epsilon}-Ti{sub 2}N phase. These films have a milky appearance and exhibit ''large'' (1-5 {mu}m) hexagonal {alpha}-Ti(N) crystallites. Conditions under which these films can be prepared are discussed in detail. (orig.).

  2. Electrochemical behavior of tin(II at the electrodeposition tin sulfide on Mo-electrode

    Directory of Open Access Journals (Sweden)

    Kazhmukhan Urazov

    2015-03-01

    Full Text Available The electrochemical behavior of tin ions (II and thiosulfate ions (S2O32- on the Mo electrode in various concentrations and potential scan rate was studied by voltammetric method. Dependence of oxidation and reduction currents from concentrations of tin (II ions and scan rate was obtained. It was showed the diffusion nature of the limiting stage of reduction. It was determined the different voltammograms’s character with a sweep potential to E = -1300mV or -1500mV for simultaneous reduction ions Sn (II and (S2O32- from 0,2 M sodium citrate on molybdenum electrode. Nanocrystalline films SnS with a thickness of 1 µ were obtained by the electrodeposition on glass/SnO2.

  3. Palladium-tin catalysts for the direct synthesis of H₂O₂ with high selectivity.

    Science.gov (United States)

    Freakley, Simon J; He, Qian; Harrhy, Jonathan H; Lu, Li; Crole, David A; Morgan, David J; Ntainjua, Edwin N; Edwards, Jennifer K; Carley, Albert F; Borisevich, Albina Y; Kiely, Christopher J; Hutchings, Graham J

    2016-02-26

    The direct synthesis of hydrogen peroxide (H2O2) from H2 and O2 represents a potentially atom-efficient alternative to the current industrial indirect process. We show that the addition of tin to palladium catalysts coupled with an appropriate heat treatment cycle switches off the sequential hydrogenation and decomposition reactions, enabling selectivities of >95% toward H2O2. This effect arises from a tin oxide surface layer that encapsulates small Pd-rich particles while leaving larger Pd-Sn alloy particles exposed. We show that this effect is a general feature for oxide-supported Pd catalysts containing an appropriate second metal oxide component, and we set out the design principles for producing high-selectivity Pd-based catalysts for direct H2O2 production that do not contain gold.

  4. Solderability perservative coatings: Electroless tin vs. organic azoles

    Energy Technology Data Exchange (ETDEWEB)

    Artaki, I.; Ray, U.; Jackson, A.M.; Gordon, H.M. [AT and T Bell Labs., Princeton, NJ (United States); Vianco, P.T. [Sandia National Labs., Albuquerque, NM (United States)

    1993-07-01

    This paper compares the solderability performance and corrosions ion protection effectiveness of electroless tin coatings versus organic azole films after exposure to a series of humidity and thermal (lead-free solders) cycling conditions. The solderability of immersion tin is directly related to the tin oxide growth on the surface and is not affected by the formation of Sn-Cu intermetallic phases as long as the intermetallic phase is protected by a Sn layer. For a nominal tin thickness of 60{mu}inches, the typical thermal excursions associated with assembly are not sufficient to cause the intermetallic phase to consume the entire tin layer. Exposure to humidity at moderate to elevated temperatures promotes heavy tin oxide formation which leads to solderability loss. In contrast, thin azole films are more robust to humidity exposure; however upon heating in the presence of oxygen, they decompose and lead to severe solderability degradation. Evaluations of lead-free solder pastes for surface mount assembly applications indicate that immersion tin significantly improves the spreading of Sn:Ag and Sn:Bi alloys as compared to azole surface finishes.

  5. Tin LPP plasma control in the argon cusp source

    Science.gov (United States)

    McGeoch, Malcolm W.

    2016-03-01

    The argon cusp plasma has been introduced [1,2] for 500W class tin LPP exhaust control in view of its high power handling, predicted low tin back-scatter from a beam dump, and avoidance of hydrogen usage. The physics of tin ion control by a plasma is first discussed. Experimentally, cusp stability and exhaust disc geometry have previously been proved at full scale [2], the equivalent of 300W-500W usable EUV. Here we verify operation of the plasma barrier that maintains a high argon density next to the collector, for its protection, and a low density in the long path toward the intermediate focus, for efficiency. A pressure differential of 2Pa has been demonstrated in initial work. Other aspects of tin LPP plasma control by the cusp have now been demonstrated using tin ions from a low Hz 130mJ CO2 laser pulse onto a solid tin surface at the cusp center. Plasma is rejected at the design to match a specified exhaust power is discussed. In view of this work, argon cusp exhaust control appears to be very promising for 500W class tin LPP sources.

  6. (n,{gamma}) Experiments on tin isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Baramsai, B.; Mitchell, G. E.; Walker, C. L.; Rusev, G. [North Carolina State University, Raleigh, NC 27695, USA and Triangle Universities Nuclear Laboratory, Durham, NC 27708 (United States); Bredeweg, T. A.; Couture, A.; Haight, R. C.; Jandel, M.; Mosby, S.; O' Donnell, J. M.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); Becvar, F.; Krticka, M.; Kroll, J. [Charles University of Prague, V Holesovickach 2, 180 00 Prague 8 (Czech Republic); Agvaanluvsan, U.; Dashdorj, D.; Erdenehuluun, B.; Tsend-Ayush, T. [MonAme Scientific Research Center, Ulaanbaatar (Mongolia)

    2013-04-19

    Neutron capture experiments on highly enriched {sup 117,119}Sn isotopes were performed with the DANCE detector array located at the Los Alamos Neutron Science Center. The DANCE detector provides detailed information about the multi-step {gamma}-ray cascade following neutron capture. Analysis of the experimental data provides important information to improve understanding of the neutron capture reaction, including a test of the statistical model, the assignment of spins and parities of neutron resonances, and information concerning the Photon Strength Function (PSF) and Level Density (LD) below the neutron separation energy. Preliminary results for the (n,{gamma}) reaction on {sup 117,119}Sn are presented. Resonance spins of the odd-A tin isotopes were almost completely unknown. Resonance spins and parities have been assigned via analysis of the multi-step {gamma}-ray spectra and directional correlations.

  7. Collaborative study comparing the spiral plate and aerobic plate count methods.

    Science.gov (United States)

    Gilchrist, J E; Donnelly, C B; Peeler, J T; Campbell, J E

    1977-07-01

    The spiral plate count method is a semiautomated plating technique that greatly reduces manpower and material costs normally associated with the pour plating technique. In this collaborative study, 8 laboratories compared the spiral and pour plating techniques, using 4 samples each of 3 products: frozen pumpkin pie, frozen chicken pot pie, and shampoo. The results show that 10 of the 12 comparisons of means of the pour and spiral methods were not significantly different; 2 values were significant at alpha = 0.01. Overall, the components of variance were less than that of the current milk standard, and the replicate per cent coefficient of variation was satisfactory. This study indicates that the spiral plate method is an acceptable alternative to the pour plate method; the spiral plate method has been adopted as official first action.

  8. Create Your Plate

    Medline Plus

    Full Text Available ... steps to get started: Using your dinner plate, put a line down the middle of the plate. ... vegetables . Now in one of the small sections, put grains and starchy foods. See this list of ...

  9. Create Your Plate

    Medline Plus

    Full Text Available ... Your Plate It's simple and effective for both managing diabetes and losing weight. Creating your plate lets ... 2016 Articles from Diabetes Forecast® magazine: wcie-meal-planning, In this section Food Planning Meals Diabetes Meal ...

  10. Create Your Plate

    Medline Plus

    Full Text Available ... Your Plate Gluten Free Diets Meal Planning for Vegetarian Diets Cook with Heart-Healthy Foods Holiday Meal ... Healthy Diet Create Your Plate Meal Planning for Vegetarian Diets Gluten Free Diets Holiday Meal Planning Cook ...

  11. Food guide plate

    Science.gov (United States)

    ... chips or cookies. VEGETABLES: MAKE HALF OF YOUR PLATE FRUITS AND VEGETABLES Vegetables can be raw, fresh, ... as a snack. FRUITS: MAKE HALF OF YOUR PLATE FRUITS AND VEGETABLES Fruits can be fresh, canned, ...

  12. Growth Plate Fractures

    Science.gov (United States)

    ... the most widely used by doctors is the Salter-Harris system, described below. Type I Fractures These ... incidence of growth plate fractures peaks in adolescence. Salter-Harris classification of growth plate fractures. AAOS does ...

  13. Create Your Plate

    Medline Plus

    Full Text Available ... Planning Meals Diabetes Meal Plans Create Your Plate Gluten Free Diets Meal Planning for Vegetarian Diets Cook ... Create Your Plate Meal Planning for Vegetarian Diets Gluten Free Diets Holiday Meal Planning Cook with Heart- ...

  14. Create Your Plate

    Medline Plus

    Full Text Available ... Planning Meals Diabetes Meal Plans Create Your Plate Gluten Free Diets Meal Planning for Vegetarian Diets Cook ... Create Your Plate Meal Planning for Vegetarian Diets Gluten Free Diets Holiday Meal Planning Cook with Heart- ...

  15. Create Your Plate

    Medline Plus

    Full Text Available ... Your Plate It's simple and effective for both managing diabetes and losing weight. Creating your plate lets you still choose the foods you want, but changes the portion sizes so you are getting larger ...

  16. Create Your Plate

    Medline Plus

    Full Text Available ... Your Plate It's simple and effective for both managing diabetes and losing weight. Creating your plate lets ... Sleeve Custom jerseys for your Tour de Cure team benefits the cause. Ask the Experts: Learn to ...

  17. Well-plate freeze-drying

    DEFF Research Database (Denmark)

    Trnka, Hjalte; Rantanen, Jukka; Grohganz, Holger

    2015-01-01

    due to increasing amount of amorphous matter in the samples was observed in both vials and well plates. Cake collapse was found to be representative in well plates and could be effectively quantified using image analysis. Reconstitution time was also found to be equal in all three platforms. Finally......Abstract Context: Freeze-drying in presence of excipients is a common practice to stabilize biomacromolecular formulations. The composition of this formulation is known to affect the quality of the final product. Objective: The aim of this study was to evaluate freeze-drying in well-plates...... as a high throughput platform for formulation screening of freeze-dried products. Methods: Model formulations consisting of mannitol, sucrose and bovine serum albumin were freeze-dried in brass well plates, plastic well plates and vials. Physical properties investigated were solid form, residual moisture...

  18. Accelerated plate tectonics.

    Science.gov (United States)

    Anderson, D L

    1975-03-21

    The concept of a stressed elastic lithospheric plate riding on a viscous asthenosphere is used to calculate the recurrence interval of great earthquakes at convergent plate boundaries, the separation of decoupling and lithospheric earthquakes, and the migration pattern of large earthquakes along an arc. It is proposed that plate motions accelerate after great decoupling earthquakes and that most of the observed plate motions occur during short periods of time, separated by periods of relative quiescence.

  19. Tin-phosphate glass anode for sodium ion batteries

    Directory of Open Access Journals (Sweden)

    Tsuyoshi Honma

    2013-11-01

    Full Text Available The electrochemical property of tin-phosphate (designate as GSPO glass anode for the sodium ion battery was studied. During the first charge process, sodium ion diffused into GSPO glass matrix and due to the reduction of Sn2+ to Sn0 state sodiated tin metal nano-size particles are formed in oxide glass matrix. After the second cycle, we confirmed the steady reversible reaction ∼320 mAh/g at 0–1 V cutoff voltage condition by alloying process in NaxSn4. The tin-phosphate glass is a promising candidate of new anode active material that realizes high energy density sodium ion batteries.

  20. In-vivo behavior of tin-radiopharmaceuticals

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Tin is an essential ingredient of most technetium-99m radiopharmaceuticals but its in-vivo distribution and long-term fate are not well understood. This work describes distribution in mice of several tin-117m labeled compounds. The results indicate that stannic-HEDTMP appears to be the best overall bone localizing agent with very low blood, muscle, kidney, or liver uptake, and its binding to bone is higher than that of tin-117m-DTPA, which make it potentially useful as an agent for skeletal scintigraphy and radiotherapy of bone tumors.

  1. Mechanical Properties of Glass Surfaces Coated with Tin Oxide

    DEFF Research Database (Denmark)

    Swindlehurst, W. E.; Cantor, B.

    1978-01-01

    of tin tetrachloride on industrial soda glass at ~800K to thicknesses of ~3×10-8 and 3×10 -7 m, commercially by the `titanising' process on industrial soda glass at ~800K to a thickness of ~3.10-9 m, and in the laboratory by radio frequency sputtering from tin oxide powder over a range of glass......The effect of tin oxide coatings on the coefficient of friction and fracture strength of glass surfaces is studied. Experiments were performed partly on commercially treated glass bottles and partly on laboratory prepared microscope slides. Coatings were applied in the laboratory by decomposition...

  2. Depósito de TiN sobre herramientas de corte para uso industrial

    Directory of Open Access Journals (Sweden)

    Auger, M. A.

    2004-04-01

    Full Text Available TiN coatings on stainless steel blades for glass fibre cutting have been investigated in this work. The aim was to improve their mechanical properties and increase the tool time life, decreasing in this way the production stops. Reactive magnetron sputtering has been the deposition technique. TiN films chemical composition has been determined by AES (Auger Electron Spectroscopy, RBS (Rutherford Backscattering Spectroscopy and XANES (X-Ray Spectroscopy Near the Absorption Edge, and it has been correlated to the gas mixture composition in the vacuum chamber. Crystalline structure has been determined by X-Ray Diffraction, and the films morphology has been observed by SEM (Scanning Electron Microscopy. The hardness coating has been extracted from nanoindentation measurements, giving a 21.54±1.04 GPa hardness value, typical for TiN in the literature. Factory proofs for coated cutting blades show a 67% lifetime increase.

    En este trabajo se han estudiado láminas de TiN crecidas sobre cuchillas de acero inoxidable empleadas en el corte de fibra de vidrio, para mejorar sus propiedades mecánicas y aumentar el tiempo de vida de la herramienta, reduciendo de este modo las paradas de producción. La técnica de depósito utilizada ha sido la de sputtering magnetrón reactivo. La composición química de las capas de TiN ha sido determinada mediante medidas de Espectroscopía Auger, RBS (Rutherford Backscattering Spectroscopy y XANES (X-Ray Spectroscopy Near the Absorption Edge y se ha relacionado con la composición de la mezcla gaseosa presente en la cámara de reacción. La estructura cristalina se ha determinado mediante Difracción de Rayos X, y mediante la técnica de SEM (Scanning Electron Microscopy se ha observado la morfología de las capas. La dureza del recubrimiento se ha calculado a partir de medidas de nanoindentación, obteniéndose un valor de 21.54±1.04 GPa, típico en la literatura para el TiN. Los resultados de la prueba en f

  3. Create Your Plate

    Medline Plus

    Full Text Available ... Reset Plate Share Create Your Plate ! Share: Seven Simple Steps to Create Your Plate It's simple and effective for both managing diabetes and losing ... en.html Have Type 2 Diabetes? Our free program will help you live well. More from diabetes. ...

  4. Obliquity along plate boundaries

    Science.gov (United States)

    Philippon, Mélody; Corti, Giacomo

    2016-12-01

    Most of the plate boundaries are activated obliquely with respect to the direction of far field stresses, as roughly only 8% of the plate boundaries total length shows a very low obliquity (ranging from 0 to 10°, sub-orthogonal to the plate displacement). The obliquity along plate boundaries is controlled by (i) lateral rheological variations within the lithosphere and (ii) consistency with the global plate circuit. Indeed, plate tectonics and magmatism drive rheological changes within the lithosphere and consequently influence strain localization. Geodynamical evolution controls large-scale mantle convection and plate formation, consumption, and re-organization, thus triggering plate kinematics variations, and the adjustment and re-orientation of far field stresses. These geological processes may thus result in plate boundaries that are not perpendicular but oblique to the direction of far field stresses. This paper reviews the global patterns of obliquity along plate boundaries. Using GPlate, we provide a statistical analysis of present-day obliquity along plate boundaries. Within this framework, by comparing natural examples and geological models, we discuss deformation patterns and kinematics recorded along oblique plate boundaries.

  5. Diffusion Coefficient of Tin(II) Methanesulfonate in Ionic Liquid and Methane Sulfonic Acid (MSA) Solvent

    Science.gov (United States)

    Yang, Kok Kee; Mahmoudian, M. R.; Ebadi, Mehdi; Koay, Hun Lee; Basirun, Wan Jeffrey

    2011-12-01

    Voltammetry and chronoamperometry for the electrodeposition of tin from Tin(II) methane sulfonate mixed with ionic liquid and methane sulfonate acid at room temperature was studied. Cyclic voltammetry shows redox waves of Tin(II), which proves that the electrodeposition of tin from Tin(II) methane sulfonate is a diffusion-controlled process. The diffusion coefficient of Tin(II) ions in the solvent mixture showed good agreement from both voltammetry and chronoamperometry results. The diffusion coefficient of Tin(II) in the mixture was much smaller than in aqueous solution, and it depends on the anion of the ionic liquid.

  6. Synthesis and Characterization of Tin(IV) Oxide Obtained by Chemical Vapor Deposition Method

    OpenAIRE

    Nagirnyak, Svitlana V.; Lutz, Victoriya A.; Dontsova, Tatiana A.; Astrelin, Igor M.

    2016-01-01

    The effect of precursors on the characteristics of tin oxide obtained by chemical vapor deposition (CVD) method was investigated. The synthesis of nanosized tin(IV) oxide was carried out with the use of two different precursors: tin(II) oxalate obtained using tin chloride(II) and oxalic acid; tin(II) oxalate obtained using tin chloride(II); and ammonium oxalate. The synthesized tin(IV) oxide samples were studied by electron microscopy, X-ray diffraction and optical spectra. The lattice parame...

  7. Tin and Tin Compounds for Sodium Ion Battery Anodes: Phase Transformations and Performance.

    Science.gov (United States)

    Li, Zhi; Ding, Jia; Mitlin, David

    2015-06-16

    Sodium ion batteries (NIB, NAB, SIB) are attracting interest as a potentially lower cost alternative to lithium ion batteries (LIB), with readily available and geographically democratic reserves of the metal. Tin is one of most promising SIB anode materials, which alloys with up to 3.75 Na, leading to a charge storage capacity of 847 mAh g(-1). In this Account, we outline the state-of-the-art understanding regarding the sodiation-induced phase transformations and the associated performance in a range of Sn-based systems, treating metallic Sn and its alloys, tin oxide (SnO2), tin sulfide (SnS2/SnS), and tin phosphide (Sn4P3). We first detail what is known about the sodiation sequence in metallic Sn, highlighting the most recent insight into the reactions prior to the terminal equilibrium Na15Sn4 intermetallic. We explain why researchers argue that the equilibrium (phase diagram) series of phase transitions does not occur in this system, and rather why sodiation/desodiation proceeds through a series of metastable crystalline and amorphous structures. We also outline the recent modeling-based insight regarding how this phase transition profoundly influences the mechanical properties of the alloy, progressively changing the bonding and the near neighbor arrangement from "Sn-like" to "Na-like" in the process. We then go on to discuss the sodiation reactions in SnO2. We argue that while a substantial amount of experimental work already exists where the focus is on synthesis and testing of tin oxide-based nanocomposites, the exact sodiation sequence is just beginning to be understood. Unlike in Sn and Sn alloys, where capacities near the theoretical are reached at least early during cycling, SnO2 never quite achieves anything close to the 1398 mAh g(-1) that would be possible with a combination of fully reversible conversion and alloying reactions. We highlight recent work demonstrating that contrary to general expectations, it is the Sn to Na15Sn4 alloying reaction that

  8. Mechanical properties of Indonesian-made narrow dynamic compression plate.

    Science.gov (United States)

    Dewo, P; van der Houwen, E B; Sharma, P K; Magetsari, R; Bor, T C; Vargas-Llona, L D; van Horn, J R; Busscher, H J; Verkerke, G J

    2012-09-01

    Osteosynthesis plates are clinically used to fixate and position a fractured bone. They should have the ability to withstand cyclic loads produced by muscle contractions and total body weight. The very high demand for osteosynthesis plates in developing countries in general and in Indonesia in particular necessitates the utilisation of local products. In this paper, we investigated the mechanical properties, i.e. proportional limit and fatigue strength of Indonesian-made Narrow Dynamic Compression Plates (Narrow DCP) as one of the most frequently used osteosynthesis plates, in comparison to the European AO standard plate, and its relationship to geometry, micro structural features and surface defects of the plates. All Indonesian-made plates appeared to be weaker than the standard Narrow DCP because they consistently failed at lower stresses. Surface defects did not play a major role in this, although the polishing of the Indonesian Narrow DCP was found to be poor. The standard plate showed indications of cold deformation from the production process in contrast to the Indonesian plates, which might be the first reason for the differences in strength. This is confirmed by hardness measurements. A second reason could be the use of an inferior version of stainless steel. The Indonesian plates showed lower mechanical behaviour compared to the AO-plates. These findings could initiate the development of improved Indonesian manufactured DCP-plates with properties comparable to commonly used plates, such as the standard European AO-plates.

  9. Oxidation of H2 and CO in a fuel cell with a Platinum-tin Anode

    Directory of Open Access Journals (Sweden)

    Javier González

    2010-06-01

    Full Text Available This report describes the construction and evolution of a fuel cell with a bi-metallic anode of Pt-Sn supported on carbon, as catalysts for oxidation of pure hydrogen, pure CO and a 2% CO in H2 mixture. Both, cathode and anode were made with a structure composed by a diffusive layer and a catalytic layer. The diffusive layer was made with a carbon cloth while the catalytic layer contained the platinum and tin supported on carbon. To test the performance of the catalytic mixture, a proton exchange membrane fuel cell (PEMFC was developed with an original design for the gas distributation plates. The reactants were feed to ambient temperature and 3 psig in the anode side, while 5 psig pure oxygen was used in the cathode. The anode catalytic load was 0.57 mg/cm2 of platinum and 0.08 mg/cm2 of tin. The catalytic load in cathode was 0.85 mg/cm2 of pure platinum. It was found that this caralytic mixture is tolerant to CO presence.

  10. Niobium carbide and tin precipitation in continuously cast microalloyed steels

    Science.gov (United States)

    Stock, Julian

    With high yield strength, toughness and good weldability, microalloyed steels are widely used in the automotive, pipeline and transportation industries. Microalloying elements such as niobium (Nb), titanium (Ti) and vanadium (V) in concentrations of less than 0.1 wt. pct. are typical. For optimal benefits in the final product, it is usually desired for Ti to form fine precipitates during and after solidification and for Nb to be in solution prior to hot-rolling. Vanadium precipitates at lower temperatures and is less involved in the solidification/casting process. In one aspect of the investigation, the effects of cooling rate on the titanium nitride (TiN) precipitation size distribution were investigated in a Ti-added low-carbon steel. Prior research reported an inverse relationship between the average TiN precipitation size and the post-solidification cooling rate and the present work was undertaken to examine this behavior over a wider range of cooling rates. Using the GleebleRTM 3500's casting simulation capabilities along with controlled cooling rates, the TiN precipitation behavior in thick-slab, thin-slab and thin-strip material was simulated using a commercially produced 0.04C, 1.23Mn steel with near-stoichiometric Ti and N levels. Transmission electron microscopy (TEM) investigation of carbon extraction replicas was carried out to characterize the influence of cooling rates on precipitate size distributions. Decreasing particle sizes with increasing cooling rates were found. Average particle sizes as low as 6.7 nm were present in thin-strip simulations and might be of interest, as fine particles could contribute to strengthening of rapidly cooled steels. In a second aspect of the investigation, niobium carbide (NbC) precipitation during the compact strip production (CSP) process was investigated in two Nb-added low-carbon steels. Instead of industrial sampling, the GleebleRTM was used for casting simulations using two CMn(Nb) steels with high and low- Nb

  11. Angular shear plate

    Science.gov (United States)

    Ruda, Mitchell C [Tucson, AZ; Greynolds, Alan W [Tucson, AZ; Stuhlinger, Tilman W [Tucson, AZ

    2009-07-14

    One or more disc-shaped angular shear plates each include a region thereon having a thickness that varies with a nonlinear function. For the case of two such shear plates, they are positioned in a facing relationship and rotated relative to each other. Light passing through the variable thickness regions in the angular plates is refracted. By properly timing the relative rotation of the plates and by the use of an appropriate polynomial function for the thickness of the shear plate, light passing therethrough can be focused at variable positions.

  12. Indium Tin Oxide-Free Polymer Solar Cells: Toward Commercial Reality

    DEFF Research Database (Denmark)

    Angmo, Dechan; Espinosa Martinez, Nieves; Krebs, Frederik C

    2014-01-01

    Polymer solar cell (PSC) is the latest of all photovoltaic technologies which currently lies at the brink of commercialization. The impetus for its rapid progress in the last decade has come from low-cost high throughput production possibility which in turn relies on the use of low-cost materials...... and vacuum-free manufacture. Indium tin oxide (ITO), the commonly used transparent conductor, imposes the majority of the cost of production of PSCs, limits flexibility, and is feared to create bottleneck in the dawning industry due to indium scarcity and the resulting large price fluctuations. As such...

  13. Sources and historical record of tin and butyl-tin species in a Mediterranean bay (Toulon Bay, France).

    Science.gov (United States)

    Pougnet, Frédérique; Schäfer, Jörg; Dutruch, Lionel; Garnier, Cédric; Tessier, Erwan; Dang, Duc Huy; Lanceleur, Laurent; Mullot, Jean-Ulrich; Lenoble, Véronique; Blanc, Gérard

    2014-05-01

    Concentrations of inorganic tin (Sn(inorg)), tributyltin (TBT) and its degradation products dibutyltin (DBT) and monobutyltin (MBT) were measured in surface sediments and in two cores from the Toulon Bay, hosting the major French military harbour. Anticipating planned dredging, the aim of the present work is to map and evaluate for the first time the recent and historic contamination of these sediments by inorganic and organic Sn species derived from antifouling paints used for various naval domains including military, trade, tourism and leisure. Tin and butyl-Sn concentrations in the bay varied strongly (4 orders of magnitude), depending on the site, showing maximum values near the shipyards. The concentrations of total Sn (1.3-112 μg g(-1)), TBT (<0.5-2,700 ng g(-1)), DBT (<0.5-1,800 ng g(-1)) and MBT (0.5-1,000 ng g(-1)) generally decreased towards the open sea, i.e. as a function of both distance from the presumed main source and bottom currents. Progressive degradation state of the butyl-Sn species according to the same spatial scheme and the enrichment factors support the scenario of a strongly polluted bay with exportation of polluted sediment to the open Mediterranean. Low degradation and the historical records of butyl-Sn species in two (210)Pb-dated sediment cores, representative of the Northern Bay, are consistent with the relatively recent use of TBT by military shipyards and confirm maximum pollution during the 1970s, which will persist in the anoxic sediments for several centuries. The results show that (a) degradation kinetics of butyl-Sn species depend on environmental conditions, (b) the final degradation product Sn(inorgBT) is by far the dominant species after 10-12 half-life periods and (c) using recent data to reliably assess former TBT contamination requires the use of a modified butyl-Sn degradation index BDI(mod). Resuspension of extremely contaminated subsurface sediments by the scheduled dredging will probably result in mobilization of

  14. Surface tension of molten tin investigated with sessile drop method

    Institute of Scientific and Technical Information of China (English)

    LI Jing; YUAN Zhang-fu; FAN Jian-feng; KE Jia-jun

    2005-01-01

    The surface tension of molten tin was determined by a set of self-developed digital equipment with sessile drop method at oxygen partial pressure of 1.0 × 10-6 MPa under different temperatures, and the dependence of surface tension of molten tin on temperature was also discussed. The emphasis was placed on the comparison of surface tension of the same molten tin sample measured by using different equipments with sessile drop method. Results of the comparison indicate that the measurement results with sessile drop method under the approximate experimental conditions are coincident, and the self-developed digital equipment for surface tension measurement has higher stability and accuracy. The relationships of surface tension of molten tin and its temperature coefficient with temperature and oxygen partial pressure were also elucidated from the thermodynamic equilibrium analysis.

  15. Platinum-Catalyzed Selective Tin-Carbon Bond Formation

    NARCIS (Netherlands)

    Thoonen, Sander Hendrikus Lambertus

    2003-01-01

    In conclusion, two improved methods for the selective synthesis of monoorganotin trihalides were developed. The platinum-catalyzed Kocheshkov redistribution reaction of dialkyltin dichlorides with tin tetrachloride is the most interesting. Contrary to the other two methods described (the direct

  16. Land Elevation TINs (Triangulated Irregular Networks) for Jefferson County, WI

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Land Elevation TINs (Triangulated Irregular Networks) in this directory are generated from 2 foot contour lines from Jefferson County. Little is known about the...

  17. Method of manufacturing tin-doped indium oxide nanofibers

    Energy Technology Data Exchange (ETDEWEB)

    Ozcan, Soydan; Naskar, Amit K

    2017-06-06

    A method of making indium tin oxide nanofibers includes the step of mixing indium and tin precursor compounds with a binder polymer to form a nanofiber precursor composition. The nanofiber precursor composition is co-formed with a supporting polymer to form a composite nanofiber having a precursor composition nanofiber completely surrounded by the supporting polymer composition. The supporting polymer composition is removed from the composite nanofiber to expose the precursor composition nanofiber. The precursor composition nanofiber is then heated in the presence of oxygen such as O.sub.2 to form indium tin oxide and to remove the binder polymer to form an indium tin oxide nanofiber. A method of making metal oxide nanofibers is also disclosed.

  18. Characterization of tin dioxide nanoparticles synthesized by oxidation

    Directory of Open Access Journals (Sweden)

    R. C. Abruzzi

    2015-09-01

    Full Text Available AbstractTin dioxide (SnO2 is a promising material with great potential for applications such as gas sensors and catalysts. Nanostructures of this oxide exhibit greater activation efficiency given their larger effective surface. The present study presents results of the synthesis and characterization of tin dioxide under different conditions via oxidation of solid tin with nitric oxide. SnO2powder was characterized primarily by X-ray diffraction and scanning electron microscopy, as well as complementary techniques such as energy-dispersive X-ray spectroscopy, dynamic light scattering and Fourier transform infrared spectroscopy. The results indicated that the established synthesis conditions were suitable for obtaining rutile tin dioxide nanoparticles with a tetragonal crystal structure.

  19. Magnesium-doped zinc oxide electrochemically grown on fluorine-doped tin oxide substrate.

    Science.gov (United States)

    Han, Q F; Jeong, Y I; Heo, J H; Shin, C M; Ryu, H; Park, M S; Lee, W J; Yoon, J H; Yang, J E; Choi, H

    2012-04-01

    Nanostructures of magnesium (Mg) doped Zinc oxide (ZnO) were successfully deposited on conducting fluorine-doped tin oxide (FTO) coated glass plates by cathodic electrochemical deposition method at different potentials and temperature conditions. The deposited samples were characterized by XRD and SEM techniques to confirm their structures, morphologies and optical properties. These measurements show that Mg doped ZnO has a wurtzite structure and that the strongest intensity of the (002) peak is found at 60 degrees C and -1.0 V. Tunable transmittance of Mg doped ZnO has a band gap energy from 3.45 eV to 3.82 eV, which is the direct evidence of doping.

  20. Modifying the Casimir force between indium tin oxide film and Au sphere

    CERN Document Server

    Banishev, A A; Castillo-Garza, R; Klimchitskaya, G L; Mostepanenko, V M; Mohideen, U; 10.1103/PhysRevB.85.045436

    2012-01-01

    We present complete results of the experiment on measuring the Casimir force between an Au-coated sphere and an untreated or, alternatively, UV-treated indium tin oxide film deposited on a quartz substrate. Measurements were performed using an atomic force microscope in a high vacuum chamber. The measurement system was calibrated electrostatically. Special analysis of the systematic deviations is performed, and respective corrections in the calibration parameters are introduced. The corrected parameters are free from anomalies discussed in the literature. The experimental data for the Casimir force from two measurement sets for both untreated and UV-treated samples are presented. The experimental errors are determined at a 95% confidence level. It is demonstrated that the UV treatment of an I TO plate results in a significant decrease in the magnitude of the Casimir force (from 21% to 35% depending on separation). However, ellipsometry measurements of the imaginary parts of dielectric permittivities of the un...

  1. Void formation in Nb3Sn-Cu superconducting wire produced by the external tin process

    Science.gov (United States)

    Verhoeven, J. D.; Efron, A.; Gibson, E. D.; Cheng, C. C.

    1986-03-01

    The tin (Sn) diffusion step for producing Nb3Sn-Cu superconducting wire by the external Sn process was modeled in experiments where either pure Sn or a Cu-Sn alloy was plated on sheets of either pure Cu or a Cu-Sn bronze. Each stage of the three-stage solid-state diffusion process was evaluated and it was found that rows of voids are produced in stage I of the process. These voids coarsen in stages II and III and in the worst case they are observed to coalesce and cause complete spalling away of the Sn-rich diffusion layers. Methods for minimizing void formation and possible causes of the void formation are discussed.

  2. Gas Sensors Based on Tin Oxide Nanoparticles Synthesized from a Mini-Arc Plasma Source

    Directory of Open Access Journals (Sweden)

    Ganhua Lu

    2006-01-01

    Full Text Available Miniaturized gas sensors or electronic noses to rapidly detect and differentiate trace amount of chemical agents are extremely attractive. In this paper, we report on the fabrication and characterization of a functional tin oxide nanoparticle gas sensor. Tin oxide nanoparticles are first synthesized using a convenient and low-cost mini-arc plasma source. The nanoparticle size distribution is measured online using a scanning electrical mobility spectrometer (SEMS. The product nanoparticles are analyzed ex-situ by high resolution transmission electron microscopy (HRTEM for morphology and defects, energy dispersive X-ray (EDX spectroscopy for elemental composition, electron diffraction for crystal structure, and X-ray photoelectron spectroscopy (XPS for surface composition. Nonagglomerated rutile tin oxide (SnO2 nanoparticles as small as a few nm have been produced. Larger particles bear a core-shell structure with a metallic core and an oxide shell. The nanoparticles are then assembled onto an e-beam lithographically patterned interdigitated electrode using electrostatic force to fabricate the gas sensor. The nanoparticle sensor exhibits a fast response and a good sensitivity when exposed to 100 ppm ethanol vapor in air.

  3. Synthesis and properties of nanosized tin-zinc composite oxides as lithium storage materials

    Institute of Scientific and Technical Information of China (English)

    YUAN Zhengyong; YUAN Liangjie; SUN Jutang

    2007-01-01

    After preparing the precursor by a liquid precipitation method,a series of tin-zinc composite oxides with different components and structures were synthesized as the anode materials for lithium ion batteries when the precursor was pyrolyzed at different temperatures.The products were characterized by X-ray diffraction (XRD),transmission electron microscopy (TEM),and electrochemical measurements.The reversible capacity of amorphous ZnSnO3 is 844 mA.h/g in the first cycle and the charge capacity is 695 mA-h/g in the tenth cycle.The reversible capacity of ZnO.SnO2 is 845 mA.h/g in the first cycle and the charge capacity is 508 mA.h/g in the tenth cycle.The reversible capacity of SnO2-Zn2SnO4 is 758 mA.h/g in the first cycle and the charge capacity is 455 mA.h/g in the tenth cycle.Results show that amorphous ZnSnO3 exhibits the best electrochemical property among all of the tin-zinc composite oxides.With the formation of crystallites in the samples,the electrochemical property of the tin-zinc composite oxides decreases.

  4. Control of the precipitation of TiN inclusions in gear steels

    Institute of Scientific and Technical Information of China (English)

    Wen-jun Ma; Yan-ping Bao; Li-hua Zhao; Min Wang

    2014-01-01

    In the 20CrMnTi steel production process, the nitrogen content increased by 19 × 10-6 and 29 × 10-6, respectively, during ladle furnace (LF) refining and during the casting process from ladle to tundish. The protective casting is the key to decrease the N content. The results of thermodynamic calculations and a growth kinetics investigation show that TiN formation occurs only when the solidification frac-tion is greater than 0.533 under the controlled conditions used in this study for the manufacture of 20CrMnTi steel;the radius of TiN particles decreases as the Ti and N contents decrease and as the cooling rate increases. Furthermore, the theory of austenite grains controlled by sec-ond-phase particles was analyzed. The elemental analysis results showed that the Ti content was controlled at 0.04wt%-0.06wt%and the N content decreased to 0.005wt%, which satisfy the requirements for grain refinement but can also effectively prevent the precipitation of TiN inclusions in 20CrMnTi steel.

  5. Safety and efficacy of nano lamellar TiN coatings on nitinol atrial septal defect occluders in vivo.

    Science.gov (United States)

    Zhang, Zhi xiong; Fu, Bu fang; Zhang, De yuan; Zhang, Zhi wei; Cheng, Yan; Sheng, Li yuan; Lai, Chen; Xi, Ting fei

    2013-04-01

    Atrial septal defect (ASD) occlusion devices made of nickel-titanium (NiTi) have a major shortcoming in that they release nickel into the body. We modified NiTi occluders using Arc Ion Plating technology. Nano lamellar titanium-nitrogen (TiN) coatings were formed on the surfaces of the occluders. The safety and efficacy of the modified NiTi occluders were evaluated in animal model. The results showed that 38 out of 39 rams (97%) survived at the end of the experiment. Fibrous capsules formed on the surfaces of the devices. Gradual endothelialization took place through the attachment of endothelial progenitor cells from the blood and the migration of endothelial cells from adjacent endocardium. The neo-endocardium formed more quickly in the coated group than in the uncoated group, as indicated by the evaluation of the six month study group. After TiN coating, there was no significant difference in endothelial cell cycle. TiN coating significantly reduced the release of nickel in both in vivo and in vitro indicating an improved biocompatibility of the nitinol ASD occluders. Superior and modified ASD occluders may provide a good choice for people with nickel allergies after sFDA registration, which is expected in one to two years. Copyright © 2012 Elsevier B.V. All rights reserved.

  6. Triangulated Irregular Networks (TIN), TIN raster file obtained from DASC, Published in unknown, 1:24000 (1in=2000ft) scale, Reno County.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Triangulated Irregular Networks (TIN) dataset, published at 1:24000 (1in=2000ft) scale as of unknown. It is described as 'TIN raster file obtained from DASC'....

  7. Triangulated Irregular Networks (TIN), Compiled a TIN baed our LIDARD data through ArcGIS tools, Published in unknown, Johnson County AIMS.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Triangulated Irregular Networks (TIN) dataset, was produced all or in part from LIDAR information as of unknown. It is described as 'Compiled a TIN baed our...

  8. Failure Mechanism of Reflow Conductor Roll of Electroplating Tinning Line

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The surface roughness of reflow conductor roll was checked on membrane sample. The surface morphology of conductor roll was observed by microscope, and the composition of adhered layer on conductor roll surface was analyzed by X-ray spectroscope. The results show that tin adhesion is the main reason for failure of conductor roll, and the failure of conductor roll is accelerated by wear. The measures to decrease tin adhesion and improve wear resistance were put forward.

  9. Study on Systemic Separation of Palladium, Silver, Cadmium and Tin

    Institute of Scientific and Technical Information of China (English)

    YU; Zhen-hua; HUANG; Kun

    2013-01-01

    To accurately measure the yields of palladium,silver,cadmium and tin that generated from the fission of plutonium,radiochemical method is needed because there is much interference in using directγ-spectroscopy measurements.Usually,we want to get as much as possible the experiment data from one target,so it is required systemic separation of palladium,silver,cadmium and tin.Considering the

  10. Electroless Plating on Plastic Induced by Selective Laser Activation

    DEFF Research Database (Denmark)

    Zhang, Yang; Tang, Peter Torben; Hansen, Hans Nørgaard

    2009-01-01

    This paper presents a new method for selective micro metallization of polymers. A Nd:YAG laser is employed to draw patterns on polymer surfaces that are submerged in a liquid (usually water). After subsequent activation with palladium chloride and followed by auto-catalytic electroless plating...... in width with 50μm between two tracks, but further optimization is expected in this field. Due to the porous and rough structure of the laser track, excellent adhesion between metallization and substrate is obtained. On top of the first copper layer, additional metal such as nickel, gold, palladium or tin...

  11. Trial Production of QSn4-4-2.5 Bronze Plates for Auto Parts%汽车青铜QSn4-4-2.5板材的试制

    Institute of Scientific and Technical Information of China (English)

    张文芹

    2001-01-01

    The technology for producing QSn4-4-2.5 bronze plates for auto parts is explored with reference to the influence of the production program on the properties of the plates.%本文依据国内某用户的要求,对QSn4-4-2.5板材生产从锭坯的熔铸工艺和加工工艺进行探索,并论述了该合金板材生产的工艺制度对其产品性能的影响。

  12. Vacuum Carbothermal Reduction for Treating Tin Anode Slime

    Science.gov (United States)

    Li, Wei; Guo, Weizhong; Qiu, Keqiang

    2013-11-01

    In this work, a process of vacuum carbothermal reduction was proposed for treating tin anode slime containing antimony and lead. During vacuum carbothermal reduction, the antimony and lead were selectively removed simultaneously by reducing and decomposing the less volatile mixed oxide of lead and antimony into the more volatile Sb2O3 and PbO. Then the tin was enriched in the distilland and primarily present as SnO2. Crude tin was obtained via vacuum reduction of the residual SnO2. The results showed that 92.85% by weight of antimony and 99.58% by weight of lead could be removed at 850°C for 60 min with 4 wt.% of reductant and air flow rate at 400 mL/min corresponding to the residual gas pressure of 40 Pa-150 Pa. Under these conditions, an evaporation ratio of 52.7% was achieved. Crude tin with a tin content of 94.22 wt.% was obtained at temperature of 900°C, reduction time of 60 min, reductant dosage of 12.5 wt.%, and a residual gas pressure of 40 Pa-400 Pa. Correspondingly, the direct recovery of tin was 94.35%.

  13. Combustion synthesis of tin dioxide nanocomposites for gas sensing applications

    Science.gov (United States)

    Bakrania, Smitesh Dhirajlal

    The current work focuses on understanding the mechanisms controlling tin dioxide (SnO2) nanoparticle morphology in combustion synthesis systems and how nanoarchitecture affects performance of solid-state gas sensors. A range of analytical methods (including transmission and scanning electron microscopy, x-ray diffraction, nitrogen absorption, and XEDS) were used to characterize the materials properties as a function of the combustion synthesis conditions. A novel method of generating tin dioxide materials was developed which provides a new degree of control over SnO2 morphology; including spherical, nanorod and encapsulated particle architectures. A simplified model for particle formation based on characteristic times was developed to identify the physical and chemical processes affecting the morphologies observed using transmission electron microscope imaging. The SnO2 nanoparticles evolve from primary particles sizes of 7 nm to 14 nm through the synthesis region, and the results indicate interparticle collision and sintering are the dominant mechanisms in determining particle size and morphology for the flame conditions studied. Metal acetates were used to create metal/SnO 2 nanocomposite materials, and the processes controlling gold acetate decomposition in particular were explored. The results of the studies suggest a relationship between the precursor crystallite size and the product nanoparticles. The well-characterized SnO2 particles were evaluated as the active materials for gas-sensing. Sensor sensitivity and time response to carbon monoxide in dry air was used to investigate microstructure-performance links. Excellent sensitivity (3 7, based on the ratio of the resistance of the sensor in air to the resistance in the target gas) and time response (4--20 seconds) were demonstrated for the thin film gas sensors. Fabrication studies demonstrated the sensor performance was a strong function of the film deposition method. A novel method for manufacturing

  14. Studies in group IV organometallic chemistry XXX. Synthesis of compounds containing tin---titanium and tin---zirconium bonds

    NARCIS (Netherlands)

    Creemers, H.M.J.C.; Verbeek, F.; Noltes, J.G.

    1968-01-01

    Starting from the tetrakis(diethylamino) derivatives of titanium and zirconium and pheyltin hydrides six intermetalic compounds contianing up to nine tin and titanium(or zirconium) atoms have been obtained by hydrostannolysis type reactions.

  15. Triangulated Irregular Networks (TIN), TIN Bayfield County, Published in 2008, 1:24000 (1in=2000ft) scale, Bayfield County.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Triangulated Irregular Networks (TIN) dataset, published at 1:24000 (1in=2000ft) scale, was produced all or in part from Orthoimagery information as of 2008....

  16. Studies in group IV organometallic chemistry XXX. Synthesis of compounds containing tin---titanium and tin---zirconium bonds

    NARCIS (Netherlands)

    Creemers, H.M.J.C.; Verbeek, F.; Noltes, J.G.

    Starting from the tetrakis(diethylamino) derivatives of titanium and zirconium and pheyltin hydrides six intermetalic compounds contianing up to nine tin and titanium(or zirconium) atoms have been obtained by hydrostannolysis type reactions.

  17. Search for technetium in natural tin metallurgical residues

    Energy Technology Data Exchange (ETDEWEB)

    Parker, C.W.

    1996-07-01

    Possible instability of baryons inside the nuclei might result in accumulation of rare isotopes in natural ores. In this respect, isotopes of technetium have certain advantages that can be useful in the search for technetium in nonradioactive ores by chemical methods. In this paper, we review the history of technetium research and discuss a new approach to the search for natural technetium associated with tin ores which appears to offer a rare possibility of discovering a smelting operation by-product such as flue dust, in which the volatile technetium heptoxide (Tc{sub 2}O{sub 7}), like rhenium heptoxide (Re{sub 2}O{sub 7}), would be expected to concentrate. Our concept of a search for technetium in these materials would be based on the assumption that traces of rhenium could occur in the ore and could be traced most easily by neutron activation of small samples. Such a procedure would confirm that an enrichment from the ore to the flue dust actually occurs with the rhenium and therefore should occur with technetium. Furthermore, this occurrence should identify the best location to search for technetium.

  18. Suppressing tin whisker growth in lead-free solders and platings

    Science.gov (United States)

    Hoffman, Elizabeth N; Lam, Poh-Sang

    2014-04-29

    A process of irradiation Sn containing Pb-free solder to mitigate whisker formation and growth thereon is provided. The use of gamma radiation such as cobalt-60 has been applied to a substrate of Sn on copper has been found to change the morphology of the crystalline whisker growth to a more truncated hillock pattern. The change in morphology greatly reduces the tendency of whiskers to contribute to electrical short-circuits being used as a Pb-free solder system on a copper substrate.

  19. Electrochemical Behavior of Ion-Plated TiN and Cu-Cr Coatings

    Science.gov (United States)

    1993-09-01

    results show that Cu-Cr alloys containing up to about 25 atomic percent CR consist of single phase FCC structure . The alloys containing more than 60...19), curve 4 for CuCr(40), and curve 5 for Cu-Cr(85)]. Note that Curves 1, 2, and 3 are from FCC structure , curve 4 from dual-phase structure, and

  20. Electroless metal plating of plastics

    Science.gov (United States)

    Krause, Lawrence J.

    1984-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  1. Precipitation in a lead calcium tin anode

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Gonzalez, Francisco A., E-mail: fco.aurelio@inbox.com [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico); Camurri, Carlos G., E-mail: ccamurri@udec.cl [Departamento de Ingenieria de Materiales, Universidad de Concepcion (Chile); Carrasco, Claudia A., E-mail: ccarrascoc@udec.cl [Departamento de Ingenieria de Materiales, Universidad de Concepcion (Chile); Colas, Rafael, E-mail: rafael.colas@uanl.edu.mx [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico)

    2012-02-15

    Samples from a hot rolled sheet of a tin and calcium bearing lead alloy were solution heat treated at 300 Degree-Sign C and cooled down to room temperature at different rates; these samples were left at room temperature to study natural precipitation of CaSn{sub 3} particles. The samples were aged for 45 days before analysing their microstructure, which was carried out in a scanning electron microscope using secondary and backscattered electron detectors. Selected X-ray spectra analyses were conducted to verify the nature of the precipitates. Images were taken at different magnifications in both modes of observation to locate the precipitates and record their position within the images and calculate the distance between them. Differential scanning calorimeter analyses were conducted on selected samples. It was found that the mechanical properties of the material correlate with the minimum average distance between precipitates, which is related to the average cooling rate from solution heat treatment. - Highlights: Black-Right-Pointing-Pointer The distance between precipitates in a lead alloy is recorded. Black-Right-Pointing-Pointer The relationship between the distance and the cooling rate is established. Black-Right-Pointing-Pointer It is found that the strengthening of the alloy depends on the distance between precipitates.

  2. Tin oxide dependence of the CO2 reduction efficiency on tin electrodes and enhanced activity for tin/tin oxide thin-film catalysts.

    Science.gov (United States)

    Chen, Yihong; Kanan, Matthew W

    2012-02-01

    The importance of tin oxide (SnO(x)) to the efficiency of CO(2) reduction on Sn was evaluated by comparing the activity of Sn electrodes that had been subjected to different pre-electrolysis treatments. In aqueous NaHCO(3) solution saturated with CO(2), a Sn electrode with a native SnO(x) layer exhibited potential-dependent CO(2) reduction activity consistent with previously reported activity. In contrast, an electrode etched to expose fresh Sn(0) surface exhibited higher overall current densities but almost exclusive H(2) evolution over the entire 0.5 V range of potentials examined. Subsequently, a thin-film catalyst was prepared by simultaneous electrodeposition of Sn(0) and SnO(x) on a Ti electrode. This catalyst exhibited up to 8-fold higher partial current density and 4-fold higher faradaic efficiency for CO(2) reduction than a Sn electrode with a native SnO(x) layer. Our results implicate the participation of SnO(x) in the CO(2) reduction pathway on Sn electrodes and suggest that metal/metal oxide composite materials are promising catalysts for sustainable fuel synthesis.

  3. A Study of the Effect of Gold Thickness Distribution in the Jet Plating Process to Optimize Gold Usage and Plating Voltage Using Design of Experiments

    Directory of Open Access Journals (Sweden)

    Aramphongphun Chuckaphun

    2016-01-01

    Full Text Available A gold plating process in the electronics industry can be classified as (i all surface plating or (ii selective plating. Selective plating is more widely used than all surface plating because it can save more gold used in the plating process and takes less plating time. In this research, the selective plating process called jet plating was studied. Factors that possibly affected the gold usage and plating voltage were also studied to reduce the production cost. These factors included (a plating temperature, (b crystal (inhibitor amount, (c distance between workpiece and anode, (d plating current and (e plating speed. A two-level Full Factorial design with center points was first performed to screen the factors. A Central Composite Design (CCD was then employed to optimize the factors in jet plating. The amount of gold usage should be reduced to 0.366 g / 10,000 pieces, the plating speed should be increased to 4 m/min and the plating voltage should not exceed 8.0 V. According to the analysis, the optimal settings should be as follows: the plating temperature at 55.5 deg C, the crystal amount at 90%, the distance at 0.5 mm, the plating current at 2.8 A, and the plating speed at 4.5 m/min. This optimal setting led to gold usage of 0.350 g / 10,000 pieces and a plating voltage of 7.16 V. Confirmation runs of 30 experiments at the optimal conditions were then performed. It was found that the gold usage and the plating voltage of the confirmation runs were not different from the optimized gold usage and plating voltage. The optimal condition was then applied in production, which could reduce the gold usage by 4.5% and increase the plating speed by 12.5% while the plating voltage did not exceed the limit.

  4. Incomplete elimination of precursor ligands during atomic layer deposition of zinc-oxide, tin-oxide, and zinc-tin-oxide

    Science.gov (United States)

    Mackus, Adriaan J. M.; MacIsaac, Callisto; Kim, Woo-Hee; Bent, Stacey F.

    2017-02-01

    For atomic layer deposition (ALD) of doped, ternary, and quaternary materials achieved by combining multiple binary ALD processes, it is often difficult to correlate the material properties and growth characteristics with the process parameters due to a limited understanding of the underlying surface chemistry. In this work, in situ Fourier transform infrared (FTIR) spectroscopy was employed during ALD of zinc-oxide, tin-oxide, and zinc-tin-oxide (ZTO) with the precursors diethylzinc (DEZ), tetrakis(dimethylamino)tin (TDMASn), and H2O. The main aim was to investigate the molecular basis for the nucleation delay during ALD of ZTO, observed when ZnO ALD is carried out after SnO2 ALD. Gas-phase FTIR spectroscopy showed that dimethylamine, the main reaction product of the SnO2 ALD process, is released not only during SnO2 ALD but also when depositing ZnO after SnO2, indicating incomplete removal of the ligands of the TDMASn precursor from the surface. Transmission FTIR spectroscopy performed during ALD on SiO2 powder revealed that a significant fraction of the ligands persist during both SnO2 and ZnO ALD. These observations provide experimental evidence for a recently proposed mechanism, based on theoretical calculations, suggesting that the elimination of precursor ligands is often not complete. In addition, it was found that the removal of precursor ligands by H2O exposure is even less effective when ZnO ALD is carried out after SnO2 ALD, which likely causes the nucleation delay in ZnO ALD during the deposition of ZTO. The underlying mechanisms and the consequences of the incomplete elimination of precursor ligands are discussed.

  5. Effect of TiN particulate reinforcement on corrosive behaviour of aluminium 6061 composites in chloride medium

    Indian Academy of Sciences (India)

    H C Ananda Murthy; V Bheema Raju; C Shivakumara

    2013-11-01

    In the present investigation, the corrosive behaviour of Al 6061–TiN particulate composites prepared by liquidmetallurgy has been studied in chloride medium using electroanalytical techniques such as Tafel, cyclic polarization and electrochemical impedance spectroscopy (EIS). Surface morphology of the sample electrodes was examined using scanning electron micrography and energy dispersive X-ray methods. X-ray diffraction technique was used to confirm inclusion of TiN particulates in the matrix alloy and identify the alloying elements and intermetallic compounds in the Al 6061 composites. Polarization studies indicate an increase in the corrosion resistance in composites compared to the matrix alloy. EIS study reveals that the polarization resistance (p) increases with increase in TiN content in composites, thus confirming improved corrosion resistance in composites. The observed decrease in corrosion rate in the case of composites is due to decoupling between TiN particles and Al 6061 alloy. It is understood that after the initiation of corrosion, interfacial corrosion products may have decoupled the conducting ceramic TiN from Al 6061 matrix alloy thus eliminating the galvanic effect between them.

  6. Generalized Fibonacci zone plates

    CERN Document Server

    Ke, Jie; Zhu, Jianqiang

    2015-01-01

    We propose a family of zone plates which are produced by the generalized Fibonacci sequences and their axial focusing properties are analyzed in detail. Compared with traditional Fresnel zone plates, the generalized Fibonacci zone plates present two axial foci with equal intensity. Besides, we propose an approach to adjust the axial locations of the two foci by means of different optical path difference, and further give the deterministic ratio of the two focal distances which attributes to their own generalized Fibonacci sequences. The generalized Fibonacci zone plates may allow for new applications in micro and nanophotonics.

  7. Tin( ii ) ketoacidoximates: synthesis, X-ray structures and processing to tin( ii ) oxide

    KAUST Repository

    Khanderi, Jayaprakash

    2015-10-21

    Tin(ii) ketoacidoximates of the type [HONCRCOO]Sn (R = Me 1, CHPh 2) and (MeONCMeCOO)Sn] NH·2HO 3 were synthesized by reacting pyruvate- and hydroxyl- or methoxylamine RONH (R = H, Me) with tin(ii) chloride dihydrate SnCl·2HO. The single crystal X-ray structure reveals that the geometry at the Sn atom is trigonal bipyramidal in 1, 2 and trigonal pyramidal in 3. Inter- or intramolecular hydrogen bonding is observed in 1-3. Thermogravimetric (TG) analysis shows that the decomposition of 1-3 to SnO occurs at ca. 160 °C. The evolved gas analysis during TG indicates complete loss of the oximato ligand in one step for 1 whereas a small organic residue is additionally removed at temperatures >400 °C for 2. Above 140 °C, [HONC(Me)COO]Sn (1) decomposes in air to spherical SnO particles of size 10-500 nm. Spin coating of 1 on Si or a glass substrate followed by heating at 200 °C results in a uniform film of SnO. The band gap of the produced SnO film and nanomaterial was determined by diffuse reflectance spectroscopy to be in the range of 3.0-3.3 eV. X-ray photoelectron spectroscopy indicates surface oxidation of the SnO film to SnO in ambient atmosphere.

  8. Surface free energy of non-stick coatings deposited using closed field unbalanced magnetron sputter ion plating

    Energy Technology Data Exchange (ETDEWEB)

    Sun, C.-C. [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan (China); Lee, S.-C. [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan (China); Dai, S.-B. [Center of General Studies, National Kaohsiung Marine University, Nan-Tzu, Kaohsiung, Taiwan (China); Nano-Win Technology Co. Ltd., Tainan, Taiwan (China); Tien, S.-L. [Department of Physics, National Cheng Kung University, 701 Tainan, Taiwan (China); Chang, C.-C. [Department of Physics, R.O.C. Military Academy, 830 Kaohsiung, Taiwan (China); Fu, Y.-S. [Department of Environment and Energy, National University of Tainan, Tainan, Taiwan (China)]. E-mail: ysfu@mail.nutn.edu.tw

    2007-02-15

    Semiconductor IC packaging molding dies require wear resistance, corrosion resistance and non-sticking (with a low surface free energy). The molding releasing capability and performance are directly associated with the surface free energy between the coating and product material. The serious sticking problem reduces productivity and reliability. Depositing TiN, TiMoS, ZrN, CrC, CrN, NiCr, NiCrN, CrTiAlN and CrNiTiAlN coatings using closed field unbalanced magnetron sputter ion plating, and characterizing their surface free energy are the main object in developing a non-stick coating system for semiconductor IC molding tools. The contact angle of water, diiodomethane and ethylene glycol on the coated surfaces were measured at temperature in 20 deg. C using a Dataphysics OCA-20 contact angle analyzer. The surface free energy of the coatings and their components (dispersion and polar) were calculated using the Owens-Wendt geometric mean approach. The surface roughness was investigated by atomic force microscopy (AFM). The adhesion force of these coatings was measured using direct tensile pull-off test apparatus. The experimental results showed that NiCrN, CrN and NiCrTiAlN coatings outperformed TiN, ZrN, NiCr, CiTiAlN, CrC and TiMoS coatings in terms of non-sticking, and thus have the potential as working layers for injection molding industrial equipment, especially in semiconductor IC packaging molding applications.

  9. Detection of genes encoding for enterotoxins and determination of the production of enterotoxins by HBL blood plates and immunoassays of psychrotrophic strains of Bacillus cereus isolated from pasteurised milk.

    Science.gov (United States)

    in't Veld, P H; Ritmeester, W S; Delfgou-van Asch, E H; Dufrenne, J B; Wernars, K; Smit, E; van Leusden, F M

    2001-02-28

    The presence of genes for the production of the three components of the HBL enterotoxin complex and enterotoxin-T in Bacillus cereus was evaluated by PCR tests for strains isolated from milk. In addition enterotoxin production of B. cereus was evaluated by means of the HBL blood agar plate and two commercially available toxin tests. All three genes for the HBL enterotoxin complex were detected in 55% of the 86 strains tested, the enterotoxin-T gene was detected in 62% of the strains. A few strains showed a weak reaction in the PCR tests for the L1 or L2 components of the HBL enterotoxin complex. Many strains that were found to contain the genes for the HBL complex gave negative or doubtful results in the HBL blood agar plate test. All strains that contain the L2 part of the HBL complex showed a titer of at least 8 in the Oxoid RPLA test. Two strains that did not contain the L2 part of the HBL enterotoxin complex gave high titers (= 64) in the RPLA test.

  10. Replacement for Cadmium Plating and Hexavalent Chromium on Fasteners and Electrical Connectors

    Science.gov (United States)

    2010-02-10

    radioactive materials, hexavalent chromium, (electroplating and coatings), cadmium (electroplating), mercury, or other highly toxic or carcinogenic...eliminate both UNCLASSIFIED: Dist A. Approved for public release Background - Alternative Choices • Numerous alternatives – Zinc nickel (Zn/Ni) – Tin...Plating • Aluminum Corrosion Performance –equivalent at same thickness • Heat Resistance – Trivalent Chrome protects up to about 400 F; Hexavalent

  11. Total tin and organotin speciation in historic layers of antifouling paint on leisure boat hulls.

    Science.gov (United States)

    Lagerström, Maria; Strand, Jakob; Eklund, Britta; Ytreberg, Erik

    2017-01-01

    Despite their ban on small vessels in 1989 in the EU, organotin compounds (OTCs) are still being released into the environment due to their presence in historic paint layers on leisure boats. 23 paint samples scraped from recreational boats from three countries around the Baltic Sea were analyzed for total tin (Sn) and OTCs. Two antifouling paint products were also subjected to the same analyses. A new method for the detection of Sn in paint flake samples was developed and found to yield more accurate results compared to four different acid digestion methods. A new method was also developed for the extraction of OTCs from ground paint flakes. This endeavor revealed that existing methods for organotin analysis of sediment may not have full recoveries of OTCs if paint flakes are present in the sample. The hull paint samples had Sn concentrations ranging from 25 to 18,000 mg/kg paint and results showed that tributyltin (TBT) was detected in all samples with concentrations as high as 4.7 g (as Sn)/kg paint. TBT was however not always the major OTC. Triphenyltin (TPhT) was abundant in many samples, especially in those originating from Finland. Several other compounds such as monobutyltin (MBT), dibutyltin (DBT), tetrabutyltin (TeBT), monophenyltin (MPhT) and diphenyltin (DPhT) were also detected. These could be the result of degradation occurring on the hull or of impurities in the paint products as they were also identified in the two analyzed paint products. A linear correlation (r(2) = 0.934) was found between the total tin content and the sum of all detected OTCs. The detection of tin can therefore be used to indicate the presence of OTCs on leisure boats. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  12. Rapid synthesis of tin oxide nanostructures by microwave-assisted thermal oxidation for sensor applications

    Science.gov (United States)

    Phadungdhitidhada, S.; Ruankham, P.; Gardchareon, A.; Wongratanaphisan, D.; Choopun, S.

    2017-09-01

    In the present work nanostructures of tin oxides were synthesized by a microwave-assisted thermal oxidation. Tin precursor powder was loaded into a cylindrical quartz tube and further radiated in a microwave oven. The as-synthesized products were characterized by scanning electron microscope, transmission electron microscope, and x-ray diffractometer. The results showed that two different morphologies of SnO2 microwires (MWs) and nanoparticles (NPs) were obtained in one minute of microwave radiation under atmospheric ambient. A few tens of the SnO2 MWs with the length of 10-50 µm were found. Some parts of the MWs were decorated with the SnO2 NPs. However, most of the products were SnO2 NPs with the diameter ranging from 30-200 nm. Preparation under loosely closed system lead to mixed phase SnO-SnO2 NPs with diameter of 30-200 nm. The single-phase of SnO2 could be obtained by mixing the Sn precursor powders with CuO2. The products were mostly found to be SnO2 nanowires (NWs) and MWs. The diameter of SnO2 NWs was less than 50 nm. The SnO2 NPs, MWs, and NWs were in the cassiterite rutile structure phase. The SnO NPs was in the tetragonal structure phase. The growth direction of the SnO2 NWs was observed in (1 1 0) and (2 2 1) direction. The ethanol sensor performance of these tin oxide nanostructures showed that the SnO-SnO2 NPs exhibited extremely high sensitivity. Invited talk at 5th Thailand International Nanotechnology Conference (Nano Thailand-2016), 27-29 November 2016, Nakhon Ratchasima, Thailand.

  13. Numerical analysis of cross shear plate rolling

    DEFF Research Database (Denmark)

    Zhang, Wenqi; Bay, Niels

    1997-01-01

    The rolling process is widely applied for industrial production of metal plates. In conventional plate rolling the two work rolls are rotating at the same peripheral speed. By introducing a specific difference in the speed of the two work rolls, cross shear rolling is introduced forming a central...... are in the roll gap, the position and the size of the shear zone and the rolling load are calculated. Experimental results are presented verifying the calculations. The numerical analysis facilitates a better understanding of the mechanics in cross shear plate rolling....

  14. Electroless Nickel Plating and Electroplating on FBG Temperature Sensor

    Institute of Scientific and Technical Information of China (English)

    SHEN Ren-sheng; TENG Rui; LI Xiang-ping; ZHANG Jin; XIA Dao-cheng; FAN Zhao-qi; YU Yong-sen; ZHANG Yu-shu; DU Guo-tong

    2008-01-01

    Metal-coated fiber Bragg grating(FBG) temperature sensors were prepared via electroless nickel(EN) plating and tin electroplating methods on the surface of normal bare FBG.The surface morphologies of the metal-coated layers were observed under a metallographic microscope.The effects of pretreatment sequence,pH value of EN plating solution and current density of electroplating on the performance of the metal-coated layers were analyzed.Meanwhile,the Bragg wavelength shift induced by temperature was monitored by an optical spectrum analyzer.Sensitivity of the metal-coated FBG(MFBG) sensor was almost two times that of normal bare FBG sensor.The measuring temperature of the MFBG sensor could be up to 280 ℃,which was much better than that of conventional FBG sensor.

  15. Crane Scheduling on a Plate Storage

    DEFF Research Database (Denmark)

    Hansen, Jesper

    2002-01-01

    OSS produces the worlds largest container ships. The first process of producing the steel ships is handling arrival and storage of steel plates until they are needed in production. Two gantry cranes carry out this task. The planning task is now to create a schedule of movements for the 2 cranes...... without collision, that delivers the plates needed for the given day and minimizes costs....

  16. Shape-selective Valorization of Biomass-derived Glycolaldehyde using Tin-containing Zeolites

    DEFF Research Database (Denmark)

    Tolborg, Søren; Meier, Sebastian; Shunmugavel, Saravanamurugan

    2016-01-01

    A highly selective self-condensation of glycolaldehyde to different C4 molecules has been achieved using Lewis acidic stannosilicate catalysts in water at moderate temperatures (40–100 °C). The medium-sized zeolite pores (10-membered ring framework) in Sn-MFI facilitate the formation of tetrose...... sugars while hindering consecutive aldol reactions leading to hexose sugars. High yields of tetrose sugars (74 %) with minor amounts of vinyl glycolic acid (VGA), an α-hydroxyacid, are obtained using Sn-MFI with selectivities towards C4 products reaching 97 %. Tin catalysts having large pores or no pore...

  17. DEM Based Modeling: Grid or TIN? The Answer Depends

    Science.gov (United States)

    Ogden, F. L.; Moreno, H. A.

    2015-12-01

    The availability of petascale supercomputing power has enabled process-based hydrological simulations on large watersheds and two-way coupling with mesoscale atmospheric models. Of course with increasing watershed scale come corresponding increases in watershed complexity, including wide ranging water management infrastructure and objectives, and ever increasing demands for forcing data. Simulations of large watersheds using grid-based models apply a fixed resolution over the entire watershed. In large watersheds, this means an enormous number of grids, or coarsening of the grid resolution to reduce memory requirements. One alternative to grid-based methods is the triangular irregular network (TIN) approach. TINs provide the flexibility of variable resolution, which allows optimization of computational resources by providing high resolution where necessary and low resolution elsewhere. TINs also increase required effort in model setup, parameter estimation, and coupling with forcing data which are often gridded. This presentation discusses the costs and benefits of the use of TINs compared to grid-based methods, in the context of large watershed simulations within the traditional gridded WRF-HYDRO framework and the new TIN-based ADHydro high performance computing watershed simulator.

  18. Properties of tin oxides prepared by ion-beam-sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Becker, Martin; Hamann, Robert; Polity, Angelika; Feili, Davar; Meyer, Bruno K. [I. Physikalisches Institut, Justus-Liebig-Universitaet Giessen, Heinrich-Buff-Ring 16, 35392 Giessen (Germany)

    2013-07-01

    The success of n-type oxide semiconductors and its application in oxide-based electronic devices has motivated the interest in p-type oxide based semiconductors. Therefore synthesis of tin monoxide (SnO) recently has received increasing attention. Another phase of this binary system, SnO{sub 2}, is of great technological interest in manifold applications, such as transparent electrodes, heat-reflecting filters and gas sensing. The preparation of tin oxide thin films has been performed by many different procedures such as sol/gel, epitaxial procedures or methods working under vacuum conditions like sputtering techniques. Radio-Frequency-Ion-Thrusters, as designed for propulsion applications, are also qualified for thin film deposition and surface etching if utilized as ion source. Tin oxide thin films were grown by ion-beam sputtering using a 3 inch metallic tin target. Different aspects of growth and properties of the tin oxide phases were investigated in relation to growth parameters such as substrate temperature or flux of oxygen. Structural, optical and electrical properties of the films are discussed.

  19. Synthesis, characterization and photoluminescence of tin oxide nanoribbons and nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Duraia, El-Shazly M.A., E-mail: duraia_physics@yahoo.co [Suez Canal University, Faculty of Science, Physics Department, Ismailia (Egypt); Al-Farabi Kazakh National University, Almaty (Kazakhstan); Institute of Physics and Technology, 11 Ibragimov Street, 050032 Almaty (Kazakhstan); Mansorov, Z.A. [Al-Farabi Kazakh National University, Almaty (Kazakhstan); Tokmolden, S. [Institute of Physics and Technology, 11 Ibragimov Street, 050032 Almaty (Kazakhstan)

    2009-11-15

    In this work we report the successful formation of tin oxide nanowires and tin oxide nanoribbons with high yield and by using simple cheap method. We also report the formation of curved nanoribbon, wedge-like tin oxide nanowires and star-like nanowires. The growth mechanism of these structures has been studied. Scanning electron microscope was used in the analysis and the EDX analysis showed that our samples is purely Sn and O with ratio 1:2. X-ray analysis was also used in the characterization of the tin oxide nanowire and showed the high crystallinity of our nanowires. The mechanism of the growth of our1D nanostructures is closely related to the vapor-liquid-solid (VLS) process. The photoluminescence PL measurements for the tin oxide nanowires indicated that there are three stable emission peaks centered at wavelengths 630, 565 and 395 nm. The nature of the transition may be attributed to nanocrystals inside the nanobelts or to Sn or O vacancies occurring during the growth which can induce trapped states in the band gap.

  20. Antimony Doped Tin Oxide Thin Films: Co Gas Sensor

    Directory of Open Access Journals (Sweden)

    P.S. Joshi

    2011-01-01

    Full Text Available Tin dioxide (SnO2 serves as an important base material in a variety of resistive type gas sensors. The widespread applicability of this semicoducting oxide is related both to its range of conductance variability and to the fact that it responds to both oxidising and reducing gases. The antimony doped tin-oxide films were prepared by spray pyrolysis method. The as-deposited films are blackish in colour. Addition of antimony impurity showed little increase in the thickness. The X-ray diffraction pattern shows characteristic tin oxide peaks with tetragonal structure. As the doping concentration of antimony was increased, new peak corresponding to Sb was observed. The intensity of this peak found to be increased when the Sb concentration was increased from 0.01 % to the 1 % which indicates the antimony was incorporated into the tin oxide. For gas sensing studies ohmic contacts were preferred to ensure the changes in resistance of sensor is due to only adsorption of gas molecule. The graph of I-V shows a straight line in nature which indicates the ohmic contact. The sensitivity of the sensor for CO gas was tested. The sensitivity of antimony doped tin oxide found to be increased with increasing Sb concentration. The maximum sensitivity was observed for Sb = 1 % at a working temperature of 250 °C.

  1. Investigation of Surface Phenomena in Shocked Tin in Converging Geometry

    Energy Technology Data Exchange (ETDEWEB)

    Rousculp, Christopher L. [Los Alamos National Laboratory; Oro, David Michael [Los Alamos National Laboratory; Griego, Jeffrey Randall [Los Alamos National Laboratory; Turchi, Peter John [Los Alamos National Laboratory; Reinovsky, Robert Emil [Los Alamos National Laboratory; Bradley, Joseph Thomas [Los Alamos National Laboratory; Cheng, Baolian [Los Alamos National Laboratory; Freeman, Matthew Stouten [Los Alamos National Laboratory; Patten, Austin Randall [Los Alamos National Laboratory

    2016-03-21

    There is great interest in the behavior of the free surface of tin under shock loading. While it is known that meso-scale surface imperfections can seed the Richtmyer- Meshkov Instability (RMI) for a surface that is melted on release, much less is known about a tin surface that is solid, but plastically deforming. Here material properties such as shear and yield strength come into play especially in converging geometry. Previous experiments have been driven by direct contact HE. Usually a thin, flat target coupon is fielded with various single-mode, sinusoidal, machined, profiles on the free surface. The free surface is adjacent to either vacuum or an inert receiver gas. Most of these previous driver/target configurations have been nominal planer geometry. With modern HE it has been straightforward to shock tin into melt on release. However it has been challenging to achieve a low enough pressure for solid state on release. Here we propose to extend the existing base of knowledge to include the behavior of the free surface of tin in cylindrical converging geometry. By shock loading a cylindrical tin shell with a magnetically driven cylindrical liner impactor, the free surface evolution can be diagnosed with proton radiography. With the PHELIX capacitor bank, the drive can easily be varied to span the pressure range to achieve solid, mixed, and liquid states on release. A conceptual cylindrical liner and target is shown in Figure 1.

  2. Investigation of Surface Phenomena in Shocked Tin in Converging Geometry

    Energy Technology Data Exchange (ETDEWEB)

    Rousculp, Christopher L. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oro, David Michael [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Margolin, Len G. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Griego, Jeffrey Randall [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Reinovsky, Robert Emil [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Turchi, Peter John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-08-06

    There is great interest in the behavior of the free surface of tin under shock loading. While it is known that meso-scale surface imperfections can seed the Richtmyer-Meshkov Instability (RMI) for a surface that is melted on release, much less is known about a tin surface that is solid, but plastically deforming. Here material properties such as shear and yield strength come into play especially in converging geometry. Previous experiments have been driven by direct contact HE. Usually a thin, flat target coupon is fielded with various single-mode, sinusoidal, machined, profiles on the free surface. The free surface is adjacent to either vacuum or an inert receiver gas. Most of these previous driver/target configurations have been nominal planer geometry. With modern HE it has been straightforward to shock tin into melt on release. However it has been challenging to achieve a low enough pressure for solid state on release. Here we propose to extend the existing base of knowledge to include the behavior of the free surface of tin in cylindrical converging geometry. By shock loading a cylindrical tin shell with a magnetically driven cylindrical liner impactor, the free surface evolution can be diagnosed with proton radiography. With the PHELIX capacitor bank, the drive can easily be varied to span the pressure range to achieve solid, mixed, and liquid states on release.

  3. Blue Willow Story Plates

    Science.gov (United States)

    Fontes, Kris

    2009-01-01

    In the December 1997 issue of "SchoolArts" is a lesson titled "Blue Willow Story Plates" by Susan Striker. In this article, the author shares how she used this lesson with her middle-school students many times over the years. Here, she describes a Blue Willow plate painting project that her students made.

  4. Create Your Plate

    Medline Plus

    Full Text Available ... In Memory In Honor Become a Member En Español Type 1 Type 2 About Us Online Community ... Page Text Size: A A A Listen En Español Create Your Plate Create Your Plate is a ...

  5. Create Your Plate

    Medline Plus

    Full Text Available ... Diabetes Meal Plans Create Your Plate Gluten Free Diets Meal Planning for Vegetarian Diets Cook with Heart-Healthy Foods Holiday Meal Planning ... Planning Meals Diabetes Meal Plans and a Healthy Diet Create Your Plate Meal Planning for Vegetarian Diets ...

  6. Strategies to Reduce Tin and Other Metals in Electronic Cigarette Aerosol.

    Directory of Open Access Journals (Sweden)

    Monique Williams

    Full Text Available Metals are present in electronic cigarette (EC fluid and aerosol and may present health risks to users.The objective of this study was to measure the amounts of tin, copper, zinc, silver, nickel and chromium in the aerosol from four brands of EC and to identify the sources of these metals by examining the elemental composition of the atomizer components.Four brands of popular EC were dissected and the cartomizers were examined microscopically. Elemental composition of cartomizer components was determined using integrated energy dispersive X-ray microanalysis, and the concentrations of the tin, copper, zinc silver, nickel, and chromium in the aerosol were determined for each brand using inductively coupled plasma optical emission spectroscopy.All filaments were made of nickel and chromium. Thick wires were copper coated with either tin or silver. Wires were joined to each other by tin solder, brazing, or by brass clamps. High concentrations of tin were detected in the aerosol when tin solder joints were friable. Tin coating on copper wires also contributed to tin in the aerosol.Tin concentrations in EC aerosols varied both within and between brands. Tin in aerosol was reduced by coating the thick wire with silver rather than tin, placing stable tin solder joints outside the atomizing chamber, joining wires with brass clamps or by brazing rather than soldering wires. These data demonstrate the feasibility of removing tin and other unwanted metals from EC aerosol by altering designs and using materials of suitable quality.

  7. Mathematical methods for elastic plates

    CERN Document Server

    Constanda, Christian

    2014-01-01

    Mathematical models of deformation of elastic plates are used by applied mathematicians and engineers in connection with a wide range of practical applications, from microchip production to the construction of skyscrapers and aircraft. This book employs two important analytic techniques to solve the fundamental boundary value problems for the theory of plates with transverse shear deformation, which offers a more complete picture of the physical process of bending than Kirchhoff’s classical one.   The first method transfers the ellipticity of the governing system to the boundary, leading to singular integral equations on the contour of the domain. These equations, established on the basis of the properties of suitable layer potentials, are then solved in spaces of smooth (Hölder continuous and Hölder continuously differentiable) functions.   The second technique rewrites the differential system in terms of complex variables and fully integrates it, expressing the solution as a combination of complex ana...

  8. High Quality Heavy Plate Production and Control for Offshore Wind Power Piles%海上风塔管桩用高质量特厚钢板的生产与质量控制

    Institute of Scientific and Technical Information of China (English)

    王彦锋; 杨永达; 李春智; 姜中行; 郑会平

    2013-01-01

    Demand for clean energy and reserves in the offshore wind resources,which have greatly promoted the development of offshore wind power projects to stimulate the demand for offshore wind power engineering structures with heavy plate.The steel is serviced in the special conditions,with-60℃ core part and horizontal low temperature impact toughness,low-carbon equivalent easy welding performance.In this work,the development of offshore wind power for the 355MPa heavy plate in normalizing with high toughness of low carbon equivalent,by 400mm thickness continues casting slab,the composition design of low-carbon with copper and the heavy plate rolling process technology,and achieve mass production and offshore wind power project applications.%清洁能源需求和蕴藏在近海丰富的风能资源极大地推动了海上风电项目的发展,刺激了近海风电工程结构用特厚钢板的需求.由于该钢种的特殊服役条件,要求其具有-60℃芯部和横向低温冲击韧性、低碳当量易焊接性能、抗层状撕裂性能等,本文采用400mm特厚连铸板坯、低碳含铜成分设计、特厚板轧制工艺等技术,开发了355MPa级海上风电用低碳当量高韧性正火态特厚钢板,并实现了批量生产和海上风电工程的应用.

  9. Other Oxides Pre-removed from Bangka Tin Slag to Produce a High Grade Tantalum and Niobium Oxides Concentrate

    Science.gov (United States)

    Permana, S.; Soedarsono, J. W.; Rustandi, A.; Maksum, A.

    2016-05-01

    Indonesia, as the second largest tin producer in the world, has a byproduct from the production of tin. This byproduct is in the forms of tin slag containing tantalum pentoxide (Ta2O5) and niobium pentoxide (Nb2O5). This study focuses on the recovery of tantalum pentoxide and niobium pentoxide from the tin slag. In the process, one part of the tin slag sample was sieved only (BTS), and the other was roasted at 900°C, water quenched and then sieved (BTS-RQS). Samples BTS and BTS-RQS were characterized by thermo gravimetric analysis (TGA) and X-ray flourence (XRF). One part of BTS-RQS sample was dissolved in hydrofluoric acid (HF) and the other was dissolved in hydrochloric acid (HCl), washed with distilled water, then dissolved into sodium hydroxide (NaOH). Each sample was characterized by using XRF. The BTS sample produced the highest recovery of 0.3807 and 0.6978% for Ta2O5 and Nb2O5, respectively, from the particle size of -1.00+0.71 and a fraction of 47.29%, while BTS-RQS produced the highest recovery of 0.3931 and 0.8994% for Ta2O5 and Nb2O5, respectively, on the particle size of -0.71+0350 and a fraction of 21%. BTS-RQS, dissolved with 8% hydro fluoride acid, yields tantalum pentoxide and niobium pentoxide with a ratio of 2.01 and 2.09, respectively. For the sample BTS-RQS dissolve first with 6M hydrochloric acid, washed with distilled water, then dissolved with sodium hydroxide 10M, the yield ratios are 1.60 and 1.84 for tantalum pentoxide and niobium pentoxide, respectively. In this study, it is found that the dissolution by using hydrofluoric acid 8% yields the best ratio.

  10. Indium Tin Oxide@Carbon Core–Shell Nanowire and Jagged Indium Tin Oxide Nanowire

    Directory of Open Access Journals (Sweden)

    Wang Yong

    2010-01-01

    Full Text Available Abstract This paper reports two new indium tin oxide (ITO-based nanostructures, namely ITO@carbon core–shell nanowire and jagged ITO nanowire. The ITO@carbon core–shell nanowires (~50 nm in diameter, 1–5 μm in length, were prepared by a chemical vapor deposition process from commercial ITO nanoparticles. A carbon overlayer (~5–10 in thickness was observed around ITO nanowire core, which was in situ formed by the catalytic decomposition of acetylene gas. This carbon overlayer could be easily removed after calcination in air at an elevated temperature of 700°C, thus forming jagged ITO nanowires (~40–45 nm in diameter. The growth mechanisms of ITO@carbon core–shell nanowire and jagged ITO nanowire were also suggested.

  11. Physicochemical characteristics of fluorine doped tin oxide films

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, A I [Electronics Department, National Institute for Astrophysics, Optics, and Electronics (INAOE), Luis E Erro No.1, 72000 Tonantzintla, Puebla (Mexico); Huerta, L [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, AP 70-360, 04510 Mexico DF (Mexico); Leon, J M O- Rueda de [Institute of Physics, National Autonomous University of Mexico, 04510 Mexico DF (Mexico); Acosta, D [Institute of Physics, National Autonomous University of Mexico, 04510 Mexico DF (Mexico); Malik, O [Electronics Department, National Institute for Astrophysics, Optics, and Electronics (INAOE), Luis E Erro No.1, 72000 Tonantzintla, Puebla (Mexico); Aguilar, M [Institute of Physics, National Autonomous University of Mexico, 04510 Mexico DF (Mexico)

    2006-12-07

    In this work, relationships between chemical and physical properties of fluorine doped tin oxide films prepared by the chemical spray pyrolysis technique have been studied. Changes in the structural, optical and electrical properties of these films in relation to their doping concentrations determined by the resonant nuclear reaction analysis and x-ray photoelectron spectroscopy (XPS) techniques have been correlated. By XPS measurements, it was found that the fluorine content in the tin oxide films does not induce any chemical shift of the Sn and O core levels. At the same time, XPS measurements are carried out at low binding energy, shown that the valence band of heavy doped tin oxide changes with respect to that determined in SnO{sub 2} powder, due to the influence of the fluorine doping. In addition, it was shown that the formation of F-Sn complexes provides a decrease in both the concentration and mobility of the carriers.

  12. Tin - an unlikely ally for silicon field effect transistors?

    KAUST Repository

    Hussain, Aftab M.

    2014-01-13

    We explore the effectiveness of tin (Sn), by alloying it with silicon, to use SiSn as a channel material to extend the performance of silicon based complementary metal oxide semiconductors. Our density functional theory based simulation shows that incorporation of tin reduces the band gap of Si(Sn). We fabricated our device with SiSn channel material using a low cost and scalable thermal diffusion process of tin into silicon. Our high-κ/metal gate based multi-gate-field-effect-transistors using SiSn as channel material show performance enhancement, which is in accordance with the theoretical analysis. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Modified solid electrodes for stripping voltammetric determination of tin

    Energy Technology Data Exchange (ETDEWEB)

    Faller, C. [Kaiserslautern Univ. (Germany). Fachbereich Chemie]|[Univ. Trier (Germany). Abt. Anorganische und Analytische Chemie; Henze, G. [Kaiserslautern Univ. (Germany). Fachbereich Chemie]|[Univ. Trier (Germany). Abt. Anorganische und Analytische Chemie; Stojko, N. [Ural State Economic University, 8th of March Street 62, 620219 Ekaterinburg (Russian Federation); Saraeva, S. [Ural State Economic University, 8th of March Street 62, 620219 Ekaterinburg (Russian Federation); Brainina, K. [Ural State Economic University, 8th of March Street 62, 620219 Ekaterinburg (Russian Federation)

    1997-07-01

    The paper describes the determination of tin by ASV using modified thick film electrodes. Three different types of electrodes were developed: One modified with a mixture of Nafion and mercury(II)acetate, one modified with diethyldithiocarbamate (DDC) or pyrrolidinedithiocarbamate (PDC) and mercury(II)acetate, and one modified with calomel. The analyte was accumulated on the electrode surface after special electrochemical pretreatment of the modified electrode. After recording the voltammogram the electrodes were electrochemically regenerated. By virtue of their lifetime and their measurement reproducibility, we preferred the DDC and PDC modified electrodes. They can be used for months without changing their chemical characteristics. The linear range for tin determination with these electrodes is between 1 and 100 {mu}g/L; the detection limit was calculated as 0.9 {mu}g/L. The electrodes were applied to the direct determination of tin in different canned fruit juices without special sample pretreatment. (orig.). With 10 figs., 4 tabs.

  14. Properties of Polydisperse Tin-doped Dysprosium and Indium Oxides

    Directory of Open Access Journals (Sweden)

    Malinovskaya Tatyana

    2017-01-01

    Full Text Available The results of investigations of the complex permittivity, diffuse-reflectance, and characteristics of crystal lattices of tin-doped indium and dysprosium oxides are presented. Using the methods of spectroscopy and X-ray diffraction analysis, it is shown that doping of indium oxide with tin results in a significant increase of the components of the indium oxide complex permittivity and an appearance of the plasma resonance in its diffuse-reflectance spectra. This indicates the appearance of charge carriers with the concentration of more than 1021 cm−3 in the materials. On the other hand, doping of the dysprosium oxide with the same amount of tin has no effect on its optical and electromagnetic properties.

  15. Tin(II) ketoacidoximates: synthesis, X-ray structures and processing to tin(II) oxide.

    Science.gov (United States)

    Khanderi, Jayaprakash; Davaasuren, Bambar; Alshankiti, Buthainah Ameen; Rothenberger, Alexander

    2015-12-14

    Tin(II) ketoacidoximates of the type [HON=CRCOO]2Sn (R = Me 1, CH2Ph 2) and (MeON=CMeCOO)3Sn](-) NH4(+)·2H2O 3 were synthesized by reacting pyruvate- and hydroxyl- or methoxylamine RONH2 (R = H, Me) with tin(II) chloride dihydrate SnCl2·2H2O. The single crystal X-ray structure reveals that the geometry at the Sn atom is trigonal bipyramidal in 1, 2 and trigonal pyramidal in 3. Inter- or intramolecular hydrogen bonding is observed in 1-3. Thermogravimetric (TG) analysis shows that the decomposition of 1-3 to SnO occurs at ca. 160 °C. The evolved gas analysis during TG indicates complete loss of the oximato ligand in one step for 1 whereas a small organic residue is additionally removed at temperatures >400 °C for 2. Above 140 °C, [HON=C(Me)COO]2Sn (1) decomposes in air to spherical SnO particles of size 10-500 nm. Spin coating of 1 on Si or a glass substrate followed by heating at 200 °C results in a uniform film of SnO. The band gap of the produced SnO film and nanomaterial was determined by diffuse reflectance spectroscopy to be in the range of 3.0-3.3 eV. X-ray photoelectron spectroscopy indicates surface oxidation of the SnO film to SnO2 in ambient atmosphere.

  16. Low-temperature Synthesis of Tin(II) Oxide From Tin(II) ketoacidoximate Precursor

    KAUST Repository

    Alshankiti, Buthainah

    2015-04-01

    Sn (II) oxide finds numerous applications in different fields such as thin film transistors1, solar cells2 and sensors.3 In this study we present the fabrication of tin monoxide SnO by using Sn (II) ketoacid oximate complexes as precursors. Tin (II) ketoacidoximates of the type [HON=CRCOO]2Sn where R= Me 1, R= CH2Ph 2, and [(MeON=CMeCOO)3Sn]- NH4 +.2H2O 3 were synthesized by in situ formation of the ketoacid oximate ligand. The crystal structures were determined via single crystal X- ray diffraction of the complexes 1-3 revealed square planar and square pyramidal coordination environments for the Sn atom. Intramolecular hydrogen bonding is observed in all the complexes. Furthermore, the complexes were characterized by Infrared (IR), Nuclear Magnetic Resonance (NMR) and elemental analysis. From thermogravimetric analysis of 1-3, it was found that the complexes decomposed in the range of 160 – 165 oC. Analysis of the gases evolved during decomposition indicated complete loss of the oximato ligand in one step and the formation of SnO. Spin coating of 1 on silicon or glass substrate show uniform coating of SnO. Band gaps of SnO films were measured and found to be in the range of 3.0 – 3.3 eV by UV-Vis spectroscopy. X-ray photoelectron spectroscopy indicated surface oxidation of the SnO film. Heating 1 above 140 oC in air gives SnO of size ranging from 10 – 500 nm and is spherical in shape. The SnO nanomaterial is characterized by powder X-ray diffraction(XRD), Raman spectroscopy, Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM).

  17. Surface wear of TiN coated nickel tool during the injection moulding of polymer micro Fresnel lenses

    DEFF Research Database (Denmark)

    Tosello, Guido; Hansen, Hans Nørgaard; Gasparin, Stefania

    2012-01-01

    Limited tool life of nickel mould inserts represents an issue for the mass-production of polymer optics with complex micro three-dimensional geometries by injection moulding. TiN coating was applied to a nickel insert for the injection moulding of polycarbonate micro Fresnel lenses. Surface wear ...... cycles the measured height reduction of 23μm high ribs was on the order of 400–1000nm....

  18. Extracellular electron transfer mechanism in Shewanella loihica PV- 4 biofilms formed at indium tin oxide and graphite electrodes

    OpenAIRE

    2013-01-01

    Electroactive biofilms are capable of extracellular electron transfer to insoluble metal oxides and electrodes; such biofilms are relevant to biogeochemistry, bioremediation, and bioelectricity production. We investigated the extracellular electron transfer mechanisms in Shewanella loihica PV-4 viable biofilms grown at indium tin oxide (ITO) and graphite electrodes in potentiostat-controlled electrochemical cells poised at 0.2 V vs. Ag/AgCl. Chronoamperometry and confocal microscopy showed hi...

  19. Laser scribing of fluorine doped tin oxide for serial interconnection of CdS/CdTe solar cells

    OpenAIRE

    2015-01-01

    In thin film PV-module production the scribing of transparent conducting oxides, like fluorine doped tin oxides thin films, is performed with serial interconnection of solar cells without the use of external wires. This scribing is usually carried out with infrared and ultraviolet lasers, while for the other films that complete the solar cell structure, the scribing is performed with visible laser light. Thus, the use of only one laser in all scribing steps in the monolithic interconnection p...

  20. Electrical Properties of Electrospun Sb-Doped Tin Oxide Nanofibers

    Science.gov (United States)

    León-Brito, Neliza; Melendez, Anamaris; Ramos, Idalia; Pinto, Nicholas J.; Santiago-Aviles, Jorge J.

    2007-03-01

    Transparent and conducting tin oxide fibers are of considerable interest for solar energy conversion, sensors and in various electrode applications. Appropriate doping can further enhance the conductivity of the fibers without loosing optical transparency. Undoped and antimony-doped tin oxide fibers have been synthesized by our group in previous work using electrospinning and metallorganic decomposition techniques. The undoped tin oxide fibers were obtained using a mixture of pure tin oxide sol made from tin (IV) chloride : water : propanol : isopropanol at a molar ratio of 1:9:9:6, and a viscous solution made from poly(ethylene oxide) (PEO) and chloroform at a ratio of 200 mg PEO/10 mL chloroform. In this work, antimony doped fibers were obtained by adding a dopant solution of antimony trichloride and isopropanol at a ratio of 2.2812 g antimony trichloride/10 ml isopropanol to the original tin oxide precursor solution. The Sb concentration in the precursor solution is 1.5%. After deposition, the fibers were sintered 600°C in air for two hours. The electrical conductivity of single fibers measured at room temperature increases by up to three orders of magnitude when compared to undoped fibers prepared using the same method. The resistivity change as a function of the annealing temperature can be attributed to the thermally activated formation of a nearly stoichoimetric solid. The resistivity of the fibers changes monotonically with temperature from 714Ω-cm at 2 K to 0.1Ω-cm at 300 K. In the temperature range from 2 to 8 K the fibers have a positive magnetoresistance (MR) with the highest value of 155 % at 2 K and ±9 T. At temperatures of 10 and 12 K the sign of MR changes to negative values for low magnetic fields and positive for high magnetic fields. For higher temperatures (15 K and above) the MR becomes negative and its magnitude decreases with temperature.

  1. Charge transport in a single superconducting tin nanowire encapsulated in a multiwalled carbon nanotube

    NARCIS (Netherlands)

    Tombros, Nikolaos; Buit, Luuk; Arfaoui, Imad; Tsoufis, Theodoros; Gournis, Dimitrios; Trikalitis, Pantelis N.; van der Molen, Sense Jan; Rudolf, Petra; van Wees, Bart J.

    2008-01-01

    The charge transport properties of single superconducting tin nanowires encapsulated by multiwalled carbon nanotubes have been investigated by multiprobe measurements. The multiwalled carbon nanotube protects the tin nanowire from oxidation and shape fragmentation and therefore allows us to investig

  2. Transition metal catalysed Grignard-like allylic activation across tetragonal tin(II) oxide

    Indian Academy of Sciences (India)

    Pradipta Sinha; Moloy Banerjee; Abhijit Kundu; Sujit Roy

    2002-08-01

    The reaction of allyl halide and a carbonyl compound under the aegis of tetragonal tin(II) oxide and catalytic 8, 10 metal complexes provides the corresponding homoallylic alcohol, via a novel allyl tin intermediate.

  3. Structural and microstructural characterization of tin(II oxide useful as anode material in lithium rechargeable batteries obtained from a different synthesis route at room temperature

    Directory of Open Access Journals (Sweden)

    Mario Alberto Macías

    2011-01-01

    Full Text Available Tin (II oxide has been proposed as potential anode material in lithium rechargeable batteries. Different methods to obtain such compound have been developed with relative difficulty due to the fact that Sn(II is easily oxidized to Sn(IV. We have applied a different methodology to synthesize SnO-romarchite by modifying the solvent nature of the controlled precipitation route using acetic acid and not water. Although the formation of Sn(IV oxide could not be completely avoided, X-ray diffraction analysis confirmed the synthesis of metastable tin(II oxide as major phase at room temperature. In depth analysis using Popa's model for Rietveld refinement allows to precise that the material corresponds to small and distorted crystallites, very anisotropic in size. SEM technique confirmed the microstructure is build of flower-like agglomerates of ~15 µm, in turn made of plate-like individual grains that remind the crystallite structure anisotropy.

  4. Pixelated neutron image plates

    Science.gov (United States)

    Schlapp, M.; Conrad, H.; von Seggern, H.

    2004-09-01

    Neutron image plates (NIPs) have found widespread application as neutron detectors for single-crystal and powder diffraction, small-angle scattering and tomography. After neutron exposure, the image plate can be read out by scanning with a laser. Commercially available NIPs consist of a powder mixture of BaFBr : Eu2+ and Gd2O3 dispersed in a polymer matrix and supported by a flexible polymer sheet. Since BaFBr : Eu2+ is an excellent x-ray storage phosphor, these NIPs are particularly sensitive to ggr-radiation, which is always present as a background radiation in neutron experiments. In this work we present results on NIPs consisting of KCl : Eu2+ and LiF that were fabricated into ceramic image plates in which the alkali halides act as a self-supporting matrix without the necessity for using a polymeric binder. An advantage of this type of NIP is the significantly reduced ggr-sensitivity. However, the much lower neutron absorption cross section of LiF compared with Gd2O3 demands a thicker image plate for obtaining comparable neutron absorption. The greater thickness of the NIP inevitably leads to a loss in spatial resolution of the image plate. However, this reduction in resolution can be restricted by a novel image plate concept in which a ceramic structure with square cells (referred to as a 'honeycomb') is embedded in the NIP, resulting in a pixelated image plate. In such a NIP the read-out light is confined to the particular illuminated pixel, decoupling the spatial resolution from the optical properties of the image plate material and morphology. In this work, a comparison of experimentally determined and simulated spatial resolutions of pixelated and unstructured image plates for a fixed read-out laser intensity is presented, as well as simulations of the properties of these NIPs at higher laser powers.

  5. Design features of internal tin superconductors for ITER magnetic system

    Energy Technology Data Exchange (ETDEWEB)

    Pantsyrnyi, V.I.; Shikov, A.K.; Nikulin, A.D.; Silaev, A.G.; Bel`akov, N.A.; Vdovin, V.F.; Semin, M.J. [Bochvar All-Russia Inst. of Inorganic Materials, Moscow (Russian Federation)

    1996-07-01

    The influence of parameters of internal tin superconductor design on the main working characteristics such as critical current density and hysteresis losses were analyzed. It was shown that having the value of hysteresis losses at the acceptable level of 400--600 mJ/cm{sup 3} the critical current density 20--30% higher than the value typical for bronze route processed superconductors was attainable in principle. The results of experimental work on the design of new types of internal tin superconductors for ITER magnetic system are given.

  6. The first barium tin(II) bromide fluoride

    Science.gov (United States)

    Dénès, Georges; Merazig, Hocine; Muntasar, Abdualhafeed; Porterfield, Robyn

    2014-04-01

    In an effort to prepare barium tin(II) bromide fluorides for the first time, possibly similar to the chloride fluorides obtained earlier in our laboratory, precipitation reactions were carried out by mixing aqueous solutions of SnF2 and of BaBr2.2H2O. In contrast with the chloride fluoride system, a single powdered phase was obtained throughout the SnF2 - BaBr2 system, with the yield being maximum at X ≈ 0.25, where X is the molar fraction of barium bromide in the reaction mixture. Phase identification with the JCPDS database failed to produce a match, confirming that a new phase had been produced. The exact chemical composition of the new compound has not been obtained yet. Based on the X value for the maximum yield, the Sn/Ba ratio is likely to be 3/1 or 2/1. The Mössbauer spectrum at ambient conditions shows that bonding to tin(II) is covalent, therefore with the tin lone pair being stereoactive. The Mössbauer parameters ( δ = 3.68 mm/s, Δ = 0.99 mm/s) are similar to those of SnBrF and of Sn2BrF5, thereby showing that tin is bonded to both fluorine and bromine. The larger isomer shift and lower quadrupole splitting than in tin(II) fluorides show that the stereoactivity of the tin lone pair is lower than in the fluorides. The Mössbauer parameters fit well the linear correlation of the quadrupole splitting versus the isomer shift" that has been shown to be present in other series of tin(II) compounds. The linear decrease on this correlation shows that the contribution of non-spherical orbitals ( p and d) to the lone pair is a much larger contributor to the quadrupole splitting than lattice distortions. The structure is likely made of Ba2+ cations and tin(II) fluoride bromide polyatomic anions, with covalent bonding withinthe anions.

  7. Plate removal following orthognathic surgery.

    Science.gov (United States)

    Little, Mhairi; Langford, Richard Julian; Bhanji, Adam; Farr, David

    2015-11-01

    The objectives of this study are to determine the removal rates of orthognathic plates used during orthognathic surgery at James Cook University Hospital and describe the reasons for plate removal. 202 consecutive orthognathic cases were identified between July 2004 and July 2012. Demographics and procedure details were collected for these patients. Patients from this group who returned to theatre for plate removal between July 2004 and November 2012 were identified and their notes were analysed for data including reason for plate removal, age, smoking status, sex and time to plate removal. 3.2% of plates were removed with proportionally more plates removed from the mandible than the maxilla. 10.4% of patients required removal of one or more plate. Most plates were removed within the first post-operative year. The commonest reasons for plate removal were plate exposure and infection. The plate removal rates in our study are comparable to those seen in the literature.

  8. Anisotropic elastic plates

    CERN Document Server

    Hwu, Chyanbin

    2010-01-01

    As structural elements, anisotropic elastic plates find wide applications in modern technology. The plates here are considered to be subjected to not only in plane load but also transverse load. In other words, both plane and plate bending problems as well as the stretching-bending coupling problems are all explained in this book. In addition to the introduction of the theory of anisotropic elasticity, several important subjects have are discussed in this book such as interfaces, cracks, holes, inclusions, contact problems, piezoelectric materials, thermoelastic problems and boundary element a

  9. Plating in Top Agar

    OpenAIRE

    sprotocols

    2014-01-01

    1. Warm plates to room temperature before use. Cold plates causes the top agar to solidify irregularly. DO not warm plates to 37° as the top agar will take forever to solidify. - Prepare top agar as the appropriate liquid medium with 0.7% agar. Keeping 100 mL bottles is convenient. For phages, use λ top agar, which is less rich and yields bigger plaques. - Melt top agar in the microwave completely. Allow the agar to boil after liquification; incompletely melted agar looks liquid, but is...

  10. A coupled model of TiN inclusion growth in GCr15SiMn during solidification in the electroslag remelting process

    Institute of Scientific and Technical Information of China (English)

    Liang Yang; Guo-guang Cheng; Shi-jian Li; Min Zhao; Gui-ping Feng; Tao Li

    2015-01-01

    TiN inclusions observed in an ingot produced by electroslag remelting (ESR) are extremely harmful to GCr15SiMn steel. There-fore, accurate predictions of the growth size of these inclusions during steel solidification are significant for clean ESR ingot production. On the basis of our previous work, a coupled model of solute microsegregation and TiN inclusion growth during solidification has been estab-lished. The results demonstrate that compared to a non-coupled model, the coupled model predictions of the size of TiN inclusions are in good agreement with experimental results using scanning electron microscopy with energy disperse spectroscopy (SEM-EDS). Because of high cooling rate, the sizes of TiN inclusions in the edge area of the ingots are relatively small compared to the sizes in the center area. Dur-ing the ESR process, controlling the content of Ti in the steel is a feasible and effective method of decreasing the sizes of TiN inclusions.

  11. Determination of toxic elements (mercury, cadmium, lead, tin and arsenic) in fish and shellfish samples. Risk assessment for the consumers.

    Science.gov (United States)

    Olmedo, P; Pla, A; Hernández, A F; Barbier, F; Ayouni, L; Gil, F

    2013-09-01

    Although fish intake has potential health benefits, the presence of metal contamination in seafood has raised public health concerns. In this study, levels of mercury, cadmium, lead, tin and arsenic have been determined in fresh, canned and frozen fish and shellfish products and compared with the maximum levels currently in force. In a further step, potential human health risks for the consumers were assessed. A total of 485 samples of the 43 most frequently consumed fish and shellfish species in Andalusia (Southern Spain) were analyzed for their toxic elements content. High mercury concentrations were found in some predatory species (blue shark, cat shark, swordfish and tuna), although they were below the regulatory maximum levels. In the case of cadmium, bivalve mollusks such as canned clams and mussels presented higher concentrations than fish, but almost none of the samples analyzed exceeded the maximum levels. Lead concentrations were almost negligible with the exception of frozen common sole, which showed median levels above the legal limit. Tin levels in canned products were far below the maximum regulatory limit, indicating that no significant tin was transferred from the can. Arsenic concentrations were higher in crustaceans such as fresh and frozen shrimps. The risk assessment performed indicated that fish and shellfish products were safe for the average consumer, although a potential risk cannot be dismissed for regular or excessive consumers of particular fish species, such as tuna, swordfish, blue shark and cat shark (for mercury) and common sole (for lead).

  12. An Empirical Model for Estimating the Probability of Electrical Short Circuits from Tin Whiskers. Part 2

    Science.gov (United States)

    Courey, Karim; Wright, Clara; Asfour, Shihab; Onar, Arzu; Bayliss, Jon; Ludwig, Larry

    2009-01-01

    In this experiment, an empirical model to quantify the probability of occurrence of an electrical short circuit from tin whiskers as a function of voltage was developed. This empirical model can be used to improve existing risk simulation models. FIB and TEM images of a tin whisker confirm the rare polycrystalline structure on one of the three whiskers studied. FIB cross-section of the card guides verified that the tin finish was bright tin.

  13. Conversion of Molybdenum-99 production process to low enriched uranium: Neutronic and thermal hydraulic analyses of HEU and LEU target plates for irradiation in Pakistan Research Reactor-1

    Science.gov (United States)

    Mushtaq, Ahmad; Iqbal, Masood; Bokhari, Ishtiaq Hussain; Mahmood, Tayyab; Muhammad, Atta

    2012-09-01

    Technetium-99m, the daughter product of Molybdenum-99 is the most widely needed radionuclide for diagnostic studies in Pakistan. Molybdenum-99 Production Facility has been established at PINSTECH. Highly enriched uranium (93% 235U) U/Al alloy targets have been irradiated in Pakistan Research Reactor-1 (PARR-1) for the generation of fission Mo-99, while basic dissolution technique is used for separation of Mo-99 from target matrix activity. In line with the international objective of minimizing and eventually eliminating the use of HEU in civil commerce, national and international efforts have been underway to shift the production of medical isotopes from HEU to LEU (LEU; uranium is needed. LEU aluminum uranium dispersion target has been developed, which may replace existing HEU aluminum/uranium alloy targets for production of 99Mo using basic dissolution technique. Neutronic and thermal hydraulic calculations were performed for safe irradiation of targets in the core of PARR-1.

  14. EVALUATION OF APPLICATION OF COAGULANTS CONTAINING DIVALENT AND TRIVALENT IRON TO ENHANCE REMOVAL OF ORGANIC COMPOUNDS AND COMPLEXED COPPER AND TIN IONS FROM INDUSTRIAL EFFLUENTS

    Directory of Open Access Journals (Sweden)

    Maciej Thomas

    2014-10-01

    Full Text Available The article presents the issues concerning physical and chemical parameters of raw sewage from the production of printed circuit boards and the composition of the bath used technology in terms of meeting the requirements for the introduction of treated wastewater into surface waters, ground or the municipal sewage system. Showed test results for the removal of organic compounds and ions complexed copper (II and tin (II and (IV using coagulants containing ions of Fe (II and Fe (III. The studies showed the high efficiency of removal of organic compounds and tin compounds. Explained the possible causes of the difficulties of precipitation complexed copper ions (II.

  15. Tin nanoparticles encapsulated in porous multichannel carbon microtubes: preparation by single-nozzle electrospinning and application as anode material for high-performance Li-based batteries.

    Science.gov (United States)

    Yu, Yan; Gu, Lin; Zhu, Changbao; van Aken, Peter A; Maier, Joachim

    2009-11-11

    Tin nanoparticles encapsulated in porous multichannel carbon microtubes (denoted as SPMCTs) were prepared by carbonization of electrospun PAN-PMMA-tin octoate nanofibers fabricated using a single-nozzle electrospinning technique. This material exhibited excellent characteristics for lithium ion battery anode applications in terms of reversible capacities, cycling performance, and rate capability. Undertaking such a production configuration allows the long-existing problem of obtaining a high packing density of tin particles while retaining sufficient spare space to buffer the volume variation during lithium alloying and dealloying processes to be properly addressed. Furthermore, the porous carbon shell preserves both the mechanical and chemical stability of the function-active Sn metal, which also serves as a highly conductive medium allowing Li(+) to access.

  16. NASA Goddard Space Flight Center Tin Whisker (and Other Metal Whisker) Homepage

    Science.gov (United States)

    Brusse, Jay; Sampson, Mike; Leidecker, Henning; Kadesch, Jong

    2004-01-01

    This website provides information about tin whiskers and related research. The independent research performed during the past 50+ years is so vast that it is impractical to cover all aspects of tin whiskers in this one resource. Therefore, the absence of information in this website about a particular aspect of tin whiskers should NOT be construed as evidence of absence.

  17. NASA Goddard Space Flight Center Tin Whisker (and Other Metal Whisker) Homepage

    Science.gov (United States)

    Brusse, Jay; Sampson, Mike; Leidecker, Henning; Kadesch, Jong

    2004-01-01

    This website provides information about tin whiskers and related research. The independent research performed during the past 50+ years is so vast that it is impractical to cover all aspects of tin whiskers in this one resource. Therefore, the absence of information in this website about a particular aspect of tin whiskers should NOT be construed as evidence of absence.

  18. Thermal and plasma-enhanced oxidation of ALD TiN

    NARCIS (Netherlands)

    Groenland, A.W.; Brunets, I.; Boogaard, A.; Aarnink, A.A.I.; Kovalgin, A.Y.; Schmitz, J.

    2008-01-01

    Despite its high chemical stability, sputtered stoichiometric TiN can still be oxidized at temperatures below 400 ºC, whereas a non-stoichiometric TiN is known to oxidize even at room temperature. In this work, the oxidation behaviour of thin TiN layers, realized via atomic layer deposition (ALD), i

  19. Telomere dysfunction and cell survival: roles for distinctTIN2-containing complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sahn-Ho; Davalos, Albert R.; Heo, Seok-Jin; Rodier, Francis; Beausejour, Christian; Kaminker, Patrick; Campisi, Judith

    2006-11-07

    Telomeres are maintained by three DNA binding proteins, TRF1, TRF2 and POT1, and several associated factors. One factor, TIN2, binds TRF1 and TRF2 directly and POT1 indirectly. These and two other proteins form a soluble complex that may be the core telomere-maintenance complex. It is not clear whether subcomplexes exist or function in vivo. Here, we provide evidence for two TIN2 subcomplexes with distinct functions in human cells. TIN2 ablation by RNA interference caused telomere uncapping and p53-independent cell death in all cells tested. However, we isolated two TIN2 complexes from cell lysates, each selectively sensitive to a TIN2 mutant (TIN2-13, TIN2-15C). In cells with wild-type p53 function, TIN2-15C was more potent than TIN2-13 in causing telomere uncapping and eventual growth arrest. In cells lacking p53 function, TIN215C more than TIN2-13 caused genomic instability and cell death. Thus, TIN2 subcomplexes likely have distinct functions in telomere maintenance, and may provide selective targets for eliminating cells with mutant p53.

  20. Telomere dysfunction and cell survival: Roles for distinct TIN2-containing complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sahn-ho; Davalos, Albert R.; Heo, Seok-Jin; Rodier, Francis; Zou, Ying; Beausejour, Christian; Kaminker, Patrick; Yannone, Steven M.; Campisi, Judith

    2007-10-02

    Telomeres are maintained by three DNA binding proteins (TRF1, TRF2 and POT1), and several associated factors. One factor, TIN2, binds TRF1 and TRF2 directly and POT1 indirectly. Along with two other proteins, TPP1 and hRap1, these form a soluble complex that may be the core telomere maintenance complex. It is not clear whether sub-complexes also exist in vivo. We provide evidence for two TIN2 sub-complexes with distinct functions in human cells. We isolated these two TIN2 sub-complexes from nuclear lysates of unperturbed cells and cells expressing TIN2 mutants TIN2-13, TIN2-15C, which cannot bind TRF2 or TRF1, respectively. In cells with wild-type p53 function, TIN2-15C was more potent than TIN2-13 in causing telomere uncapping and eventual growth arrest. In cells lacking p53 function, TIN2-15C was more potent than TIN2-13 in causing telomere dysfunction and cell death. Our findings suggest that distinct TIN2 complexes exist, and that TIN2-15C-sensitive subcomplexes are particularly important for cell survival in the absence of functional p53.

  1. 40 CFR 721.10140 - Phosphoric acid, tin (2+) salt (2:3).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Phosphoric acid, tin (2+) salt (2:3... Specific Chemical Substances § 721.10140 Phosphoric acid, tin (2+) salt (2:3). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as phosphoric acid, tin...

  2. A Brief Analysis of Continuous Spray Pickling Process in Austenitic Stainless Medium and Heavy Plate Production%奥氏体不锈钢中厚板连续喷淋酸洗工艺浅析

    Institute of Scientific and Technical Information of China (English)

    沈继刚; 闫君

    2015-01-01

    论述了奥氏体不锈钢中厚板连续喷淋酸洗工艺的技术特征,并对典型的卧式、立式连续喷淋酸洗机组设备组成和生产工艺加以分析和对比。介绍了连续喷淋酸洗技术在国内不锈钢中厚板生产厂的实际应用情况。%The paper introduces the technical features of continuous spray pickling process,makes analysis and comparison on equipment configuration and production process of horizontal and vertical type continuous spray pickling lines,describes the actual applications of the pickling technique in domestic steel works of stainless steel medium and heavy plate.

  3. Highly conductive composites for fuel cell flow field plates and bipolar plates

    Science.gov (United States)

    Jang, Bor Z; Zhamu, Aruna; Song, Lulu

    2014-10-21

    This invention provides a fuel cell flow field plate or bipolar plate having flow channels on faces of the plate, comprising an electrically conductive polymer composite. The composite is composed of (A) at least 50% by weight of a conductive filler, comprising at least 5% by weight reinforcement fibers, expanded graphite platelets, graphitic nano-fibers, and/or carbon nano-tubes; (B) polymer matrix material at 1 to 49.9% by weight; and (C) a polymer binder at 0.1 to 10% by weight; wherein the sum of the conductive filler weight %, polymer matrix weight % and polymer binder weight % equals 100% and the bulk electrical conductivity of the flow field or bipolar plate is at least 100 S/cm. The invention also provides a continuous process for cost-effective mass production of the conductive composite-based flow field or bipolar plate.

  4. Create Your Plate

    Medline Plus

    Full Text Available ... blood glucose levels and lose weight. With this method, you fill your plate with more non-starchy ... but changes the portion sizes so you are getting larger portions of non-starchy vegetables and a ...

  5. Create Your Plate

    Medline Plus

    Full Text Available ... blood glucose levels and lose weight. With this method, you fill your plate with more non-starchy ... 4/Box) Taking the guesswork out of portion control has never been easier. It can be a ...

  6. Tectonic Plate Movement.

    Science.gov (United States)

    Landalf, Helen

    1998-01-01

    Presents an activity that employs movement to enable students to understand concepts related to plate tectonics. Argues that movement brings topics to life in a concrete way and helps children retain knowledge. (DDR)

  7. MyPlate

    Science.gov (United States)

    ... our stage of life, situations, preferences, access to food, culture, traditions, and the personal decisions we make over time. All your food and beverage choices count. MyPlate offers ideas and ...

  8. Create Your Plate

    Medline Plus

    Full Text Available ... blood glucose levels and lose weight. With this method, you fill your plate with more non-starchy ... you have an easy portion control solution that works. Last Reviewed: October 8, 2015 Last Edited: September ...

  9. Designing Assemblies Of Plates

    Science.gov (United States)

    Williams, F. W.; Kennedy, D.; Butler, R.; Aston, G.; Anderson, M. S.

    1992-01-01

    VICONOPT calculates vibrations and instabilities of assemblies of prismatic plates. Designed for efficient, accurate analysis of buckling and vibration, and for optimum design of panels of composite materials. Written in FORTRAN 77.

  10. Create Your Plate

    Medline Plus

    Full Text Available ... Your Plate Gluten Free Diets Meal Planning for Vegetarian Diets Cook with Heart-Healthy Foods Holiday Meal Planning What Can I Eat? Making Healthy Food Choices Diabetes Superfoods Non-starchy Vegetables Grains and Starchy Vegetables ...

  11. Create Your Plate

    Medline Plus

    Full Text Available ... Recipes Association Cookbook Recipes Planning Meals Diabetes Meal Plans Create Your Plate Gluten Free Diets Meal Planning ... serving of dairy or both as your meal plan allows. Choose healthy fats in small amounts. For ...

  12. Create Your Plate

    Medline Plus

    Full Text Available ... 1 Diabetes Get Started Safely Get And Stay Fit Types of Activity Weight Loss Assess Your Lifestyle ... manage portion control wherever you are. Now, our best-selling, sectioned to-go plate with easy-sealing ...

  13. Create Your Plate

    Medline Plus

    Full Text Available ... Plate is a simple and effective way to manage your blood glucose levels and lose weight. With ... been easier. It can be a challenge to manage portion control wherever you are. Now, our best- ...

  14. Tectonic Plate Movement.

    Science.gov (United States)

    Landalf, Helen

    1998-01-01

    Presents an activity that employs movement to enable students to understand concepts related to plate tectonics. Argues that movement brings topics to life in a concrete way and helps children retain knowledge. (DDR)

  15. Create Your Plate

    Medline Plus

    Full Text Available ... Carbohydrates Carbohydrate Counting Make Your Carbs Count Glycemic ... to manage portion control wherever you are. Now, our best-selling, sectioned to-go plate with easy-sealing ...

  16. Bone acidic glycoprotein-75 is a major synthetic product of osteoblastic cells and localized as 75- and/or 50-kDa forms in mineralized phases of bone and growth plate and in serum.

    Science.gov (United States)

    Gorski, J P; Griffin, D; Dudley, G; Stanford, C; Thomas, R; Huang, C; Lai, E; Karr, B; Solursh, M

    1990-09-05

    Anti-peptide and anti-protein antisera were produced which both recognize bone acidic glycoprotein-75 (Mr = 75,000) and an apparent fragment or biosynthetic intermediate (Mr = 50,000) in calcified tissues and/or serum. A fragment-precursor relationship is suggested from the fact that closely spaced doublet polypeptides of Mr = 50,000 could be produced by proteolysis of the purified protein upon long term storage. No reactivity was detected with osteopontin, bone sialoprotein, or small bone proteoglycans. Bone acidic glycoprotein-75 represents 0.5-1% of the total radiolabeled proteins synthesized by explant cultures of neonatal calvaria or growth plate, by calvarial outgrowth cultures, and by rat osteosarcoma cells. Amounts produced by explant cultures and calvarial outgrowth cultures were similar to that for osteopontin, a major product of osteoblasts. In osteosarcoma cultures, 80% of labeled antigens were associated with the cell layer fraction wherein specific immunoprecipitation pelleted Mr = 50,000 and 75,000 sized antigens. Bone acidic glycoprotein-75 (Mr = 75,000) is enriched in 4 M guanidine HCl/0.5 EDTA extracts of neonatal rat bone and growth plate tissues, whereas largely absent from heart, lung, spleen, liver, brain, and kidney. Explant cultures of these noncalcifying tissues also synthesized bone acidic glycoprotein-75 antigen, but the quantities produced were only 5% or less that obtained with calvaria. By immunohistochemistry, antigenicity is associated with the bony shaft and calcified cartilage of long bones, but is absent from associated soft tissues. These finding demonstrate that bone acidic glycoprotein-75 is antigenically distinct, predominantly localized to calcified tissues, represents a major product of normal osteoblastic cells and may undergo a characteristic fragmentation in vivo and in vitro.

  17. Growth sensitivity in the epiphyseal growth plate, liver and muscle of SD rats is significantly enhanced by treatment with a fermented soybean product (cheonggukjang) through stimulation of growth hormone secretion.

    Science.gov (United States)

    Hwang, In Sik; Kim, Ji Eun; Lee, Young Ju; Kwak, Mun Hwa; Lee, Hong Gu; Kim, Hye Sung; Lee, Hee Seob; Hwang, Dae Youn

    2014-01-01

    Cheonggukjang (CKJ), a fermented soybean product, has been reported to have beneficial effects on various chronic diseases, including cardiovascular disease, cancer and immune diseases. To investigate whether CKJ induces growth sensitivity in mammals, alterations of key parameters related to their growth were analyzed. Sprague‑Dawley (SD) rats were treated with a high concentration of CKJ (H‑CKJ) or a low concentration of CKJ (L‑CKJ) for 10 days, and compared with vehicle-treated rats. The CKJ contained a high concentration of total flavonoids, phenolic compounds, daidzein and genistein, compared with the non-fermented soybean product. Body weight was higher in the H‑CKJ‑treated group compared with that in the vehicle‑ and L‑CKJ‑treated groups, whereas the weights of three organs (the brain, liver and kidney) were higher in the L‑CKJ‑treated group compared with the remaining two groups. However, no significant differences in femur length and weight were detected between the CKJ‑ and vehicle‑treated groups. The thickness of the epiphyseal growth plate in proximal femoral epiphysis was broadest in the H‑CKJ‑treated group compared with the vehicle- and L‑CKJ‑treated groups. Furthermore, the level of growth hormone (GH) was highest in the serum of the L‑CKJ‑treated group, although that of the H‑CKJ‑treated group was lower compared with that in the L‑CKJ group. Moreover, the expression levels of the GH receptor increased in the liver tissue, but not in the muscle tissue, of the L‑CKJ‑ and H‑CKJ‑treated groups. In the downstream signaling pathway of the GH receptor, the phosphorylation levels of Akt and Erk were differentially regulated between the liver and muscle. These results suggest that CKJ extract may enhance the sensitivity of the femur, liver and muscle epiphyseal growth plate in SD rats, through the upregulation of GH secretion.

  18. Origami - Folded Plate Structures

    OpenAIRE

    Buri, Hans Ulrich

    2010-01-01

    This research investigates new methods of designing folded plate structures that can be built with cross-laminated timber panels. Folded plate structures are attractive to both architects and engineers for their structural, spatial, and plastic qualities. Thin surfaces can be stiffened by a series of folds, and thus not only cover space, but also act as load bearing elements. The variation of light and shadow along the folded faces emphasizes the plas...

  19. Fractal multifiber microchannel plates

    Science.gov (United States)

    Cook, Lee M.; Feller, W. B.; Kenter, Almus T.; Chappell, Jon H.

    1992-01-01

    The construction and performance of microchannel plates (MCPs) made using fractal tiling mehtods are reviewed. MCPs with 40 mm active areas having near-perfect channel ordering were produced. These plates demonstrated electrical performance characteristics equivalent to conventionally constructed MCPs. These apparently are the first MCPs which have a sufficiently high degree of order to permit single channel addressability. Potential applications for these devices and the prospects for further development are discussed.

  20. The Optimization Program of Steel Plate Feeding Device for LASW Pipe Production Line%直缝埋弧焊管生产线钢板上料装置优选方案

    Institute of Scientific and Technical Information of China (English)

    李钢; 张增全; 韩保材; 汤跃先; 汤圣先

    2015-01-01

    In this article, it described the main structure and constitute of 3 kinds of commonly used feeding device of JCOE/UOE LSAW pipe production line, including the combined converyor of roller and chain, chain conveyor and vacuum suction cups hanging conveyer, and compared the main structure and constitute with several aspects, such as equipment structure and operation, operation and maintenance workload, equipment investment, installed capacity, production running cost, plate scratch, etc. The results indicated that vacuum suction cups hanging conveyer device is with some advantages, such as simple structure, easy operation, low workload for operation and maintenance, small investment, small installed capacity, low production running cost, and production rhythm can completely meet the design requirements, which is the best optimization program for LASW pipe production line steel plate feeding device.%对JCOE/UOE直缝埋弧焊管生产线上通常采用的三种上料装置, 即平辊和链条组合输送装置、 链条输送装置以及真空吸盘吊输送装置的主要结构和组成进行了描述, 并从设备结构与操作、运行与维护工作量、 设备投资、 装机容量、 生产运行成本、 钢板划伤等主要方面进行了对比. 结果表明, 采用真空吸盘吊输送装置具有设备结构简单、 操作方便、 运行与维护的工作量相对较低、 资金投入相对较少、 装机容量小、 生产运行成本低、 生产节奏完全能满足设计要求等优点, 是直缝埋弧焊管生产线钢板上料的最佳优选方案.

  1. 钢板压力淬火生产线控制系统%Control System of Armor Plate Press Quenching Production Line

    Institute of Scientific and Technical Information of China (English)

    王以琦; 施建华; 彭光宇; 王克伟; 马丹; 李超

    2012-01-01

    A set of control system was developed, which realized all kinds of precise control to press quenching produc-tion line, and met the requirement s of process of a variety of production. The production line requires high precise control, and the temperature levelling of furnace can reach between -10℃ and +10℃ , it is rarely seen in domestic heat treatment furnace. Moreover, it has the characteristics such as automation, high producing efficiency, low energy costs, good operat-ing environment, low intensity of labour and so on, the level of technology are advanced compared with other congeneric production lines in domestic. After large -scale production, the results showed that all kinds of production showed high quality.%开发了一套控制系统,实现了对压力淬火生产线的各种精确控制,满足了多品种工艺生产要求.该控制系统控制精度高,可保证生产线中燃气辊底炉炉温均匀性达到±10℃以内.经实践验证,该生产线生产效率高,能耗小,操作环境好,劳动强度低,技术水平在国内同类生产线中居领先地位.规模生产结果表明,各品种规格的产品均满足质量要求.

  2. High mobility tin oxide deposition with methanol addition

    NARCIS (Netherlands)

    Deelen, J. van; Volintiru, I.; Graaf, A. de; Poodt, P.W.G.

    2011-01-01

    SnO 2 coated glass is widely used in thin film PV. Atmospheric pressure chemical vapor deposition (APCVD) is the most common method of deposition and apart from a tin precursor and oxygen precursor, other additives can improve the layer quality. In this contribution, the beneficial effect of methano

  3. Geochemistry of the Panasqueira tungsten-tin deposit, Portugal

    NARCIS (Netherlands)

    Bussink, R.W.

    1984-01-01

    Major tin-tungsten deposits in Portugal are related to intrusions of the Younger Series (300-280 Ma) of Hercynian granitoids. Mineralized granites are 'specialized' by a specific increase or decrease of major, minor and trace element contents in comparison with non-mineralized occurrences. Component

  4. Geochemistry of the Panasqueira tungsten-tin deposit, Portugal

    NARCIS (Netherlands)

    Bussink, R.W.

    1984-01-01

    Major tin-tungsten deposits in Portugal are related to intrusions of the Younger Series (300-280 Ma) of Hercynian granitoids. Mineralized granites are 'specialized' by a specific increase or decrease of major, minor and trace element contents in comparison with non-mineralized occurrences.

  5. Electronegativity-dependent tin etching from thin films

    NARCIS (Netherlands)

    Pachecka, M.; Sturm, J.M.; Kruijs, van de R.W.E.; Lee, C.J.; Bijkerk, F.

    2016-01-01

    The influence of a thin film substrate material on the etching of a thin layer of deposited tin (Sn) by hydrogen radicals was studied. The amount of remaining Sn was quantified for materials that cover a range of electronegativities. We show that, for metals, etching depends on the relative electron

  6. Geochemistry of the Panasqueira tungsten-tin deposit, Portugal

    NARCIS (Netherlands)

    Bussink, R.W.

    1984-01-01

    Major tin-tungsten deposits in Portugal are related to intrusions of the Younger Series (300-280 Ma) of Hercynian granitoids. Mineralized granites are 'specialized' by a specific increase or decrease of major, minor and trace element contents in comparison with non-mineralized occurrences. Component

  7. On the low-lying states of TiN

    Science.gov (United States)

    Bauschlicher, C. W., Jr.

    1983-01-01

    A series of CAS SCF and multi-reference CI calculations are used to describe the lowest states of TiN. The bonding in all states is described as a triple bond involving the Ti 3d orbitals. The system has some ionic character as seen from both population analysis and dipole moment. The origins of the excited states are discussed.

  8. A CityGML Extension for Handling Very Large Tins

    Science.gov (United States)

    Kumar, K.; Ledoux, H.; Stoter, J.

    2016-10-01

    In addition to buildings, the terrain forms an important part of a 3D city model. Although in GIS terrains are usually represented with 2D grids, TINs are also increasingly being used in practice. One example is 3DTOP10NL, the 3D city model covering the whole of the Netherlands, which stores the relief with a constrained TIN containing more than 1 billion triangles. Due to the massive size of such datasets, the main problem that arises is: how to efficiently store and maintain them? While CityGML supports the storage of TINs, we argue in this paper that the current solution is not adequate. For instance, the 1 billion+ triangles of 3DTOP10NL require 686 GB of storage space with CityGML. Furthermore, the current solution does not store the topological relationships of the triangles, and also there are no clear mechanisms to handle several LODs. We propose in this paper a CityGML extension for the compact representation of terrains. We describe our abstract and implementation specifications (modelled in UML), and our prototype implementation to convert TINs to our CityGML structure. It increases the topological relationships that are explicitly represented, and allows us to compress up to a factor of ∼ 25 in our experiments with massive real-world terrains (more than 1 billion triangles).

  9. Geology,Geochemistry and Genesis of Yinyan Porphyry Tin Deposit

    Institute of Scientific and Technical Information of China (English)

    朱正书; 朱金初; 等

    1989-01-01

    The Yinyan porphyry tin deposit is a blind deposit associated with a small granite porphyry stock.The petrology and geochemistry of the Yinyan granite porphyry suggest that it is genetically of the transfor-mation type,emplaced at the late stage of fractional crystallization within a high-level magma chamber.Ore-forming fluids are derived predominantly from the granitic magma and they interact with the wall rocks intensely when finding their way upwards through the granite porphyry.From the lower part of the porphyry upwards the following alteration zones can be distinguished(a)slightly altered granite porphyry (with weak potash feldspathization),(b)protolithionite-quartz greisenization zone,(c)to-paz-quartz greisenization zone,(d)senicite-quartz sericitization zone,and (e)silicification zone (quartz core at the surface).Tin mineralization is related to greisenization,especially to topaz-quartz greisenization.Rock and ore-forming temperatures and oxygen fugacities are estimated,respectively.There are significant differences in many aspects between the Yinyan porphyry tin deposit and volcan-ic-subvolcanic porphyry tin deposits.

  10. Burden of injuries and diseases in Yunnan Tin Miners

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    @@ The burden of injuries is underestimated to an even greater extent in developing countries than in industrialized countries. The objective of this paper is to analyze injuries and diseases in the monitored work place of the world's largest tin mining operation in Yunnan, South China.

  11. Chemical vapor deposition of tin oxide: fundamentals and applications

    NARCIS (Netherlands)

    Mol, A.M.B. van; Chae, Y.; McDaniel, A.H.; Allendorf, M.D.

    2006-01-01

    Tin oxide thin layers have very beneficial properties such as a high transparency for visible light and electrical conductivity making these coatings suitable for a wide variety of applications, such as solar cells, and low-emissivity coatings for architectural glass windows. Each application

  12. Recent results on neutron rich tin isotopes by laser spectroscopy

    CERN Document Server

    Roussière, B; Crawford, J E; Essabaa, S; Fedosseev, V; Geithner, W; Genevey, J; Girod, M; Huber, G; Horn, R; Kappertz, S; Lassen, J; Le Blanc, F; Lee, J K P; Le Scornet, G; Lettry, Jacques; Mishin, V I; Neugart, R; Obert, J; Oms, J; Ouchrif, A; Peru, S; Pinard, J; Ravn, H L; Sauvage, J; Verney, D

    2001-01-01

    Laser spectroscopy measurements have been performed on neutron rich tin isotopes using the COMPLIS experimental setup. The nuclear charge radii of the even-even isotopes from A=108 to 132 are compared to the results of macroscopic and microscopic calculations. The improvements and optimizations needed to perform the isotope shift measurement on $^{134}$Sn are presented.

  13. On the electrochemical migration mechanism of tin in electronics

    DEFF Research Database (Denmark)

    Minzari, Daniel; Jellesen, Morten Stendahl; Møller, Per

    2011-01-01

    Electrochemical migration (ECM) of tin can result in the growth of a metal deposit with a dendritic structure from cathode to anode. In electronics, such growth can lead to short circuit of biased electrodes, potentially leading to intermittent or complete failure of an electronic device...

  14. Vibration and Buckling of Web Plate of the Plate Girder

    OpenAIRE

    高橋, 和雄; 呉, 明強; 中澤, 聡志; 筑紫, 宏之

    1998-01-01

    The vibration and buckling of the web of the plate girder are studied in this paper. The small deflection theory of the thin plate is used. The finite strip method is employed to solve vibration and buckling of the plate girder. Natural frequenies of buckling properties are shown for various plate girder bridges.

  15. Micro/nano-scale investigation on tin alloys and tin dioxide nanowires

    Science.gov (United States)

    Sun, Yong

    Tin (Sn) and its alloys have been at people's service since 3000 BC when bronze (alloy of tin and copper) was produced in large scale. They have unique properties and find applications in various engineering fields. Correspondingly, there is abundant information waiting to be clarified surrounding these Sn-related materials. As the key element used for solder alloys, the properties of Sn alloys have been of great interest to the electronic packaging community. At the same time, the intriguing phenomenon of spontaneous Sn whisker growth from Sn / Sn-alloy thin films have bothered, yet also inspired materials scientists for over 60 years. The most commonly seen Sn-containing compound, SnO 2, is in high demand as well due to its exceptional electronic and chemical properties. In addition, nanostructures of SnO2 are intensively studied for their potential applications as solid-state sensors, transparent conducting materials, lithium-ion batteries, high-efficiency solar cell and recently, supercapacitors. The objective of this proposed research is to explore the amazing properties of Sn and Sn-alloys from several different perspectives. Firstly, ever since the banish of lead in solder alloys, lead-free alloys such as Sn-Ag-Cu (SAC) has been put under the spotlight. We intend to use our expertise in nanomechanics to give an in-depth and thorough investigation on a popular SAC387 alloy. The mechanical properties of each phase and the local deformation mechanisms have been considered. Secondly, the Sn whisker growth phenomenon is to be re-visited. With the aid of digital image correlation (DIC) techniques, it was found that magnitude of the strain gradient plays an important role in whisker growth. Moreover, DIC helps to visualize the dynamic growth process in which the alteration of strain field has been identified to cause growth of subsequent whiskers. Last but not least, the performance of SnO2 nanowires is to be evaluated in several aspects including mechanical

  16. Proton microprobe study of tin-polymetallic deposits

    Energy Technology Data Exchange (ETDEWEB)

    Murao, S. [Geological Survey of Japan, Tsukuba, Ibaraki (Japan); Sie, S.H.; Suter, G.F. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience

    1996-12-31

    Tin-polymetallic vein type deposits are a complex mixture of cassiterite and sulfides and they are the main source of technologically important rare metals such as indium and bismuth. Constituent minerals are usually fine grained having wide range of chemical composition and often the elements of interest occur as trace elements not amenable to electron microprobe analysis. PIXE with a proton microprobe can be an effective tool to study such deposits by delineating the distribution of trace elements among carrier minerals. Two representative indium-bearing deposits of tin- polymetallic type, Tosham of India (Cu-ln-Bi-Sn-W-Ag), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), were studied to delineate the distribution of medical/high-tech rare metals and to examine the effectiveness of the proton probe analysis of such ore. One of the results of the study indicated that indium and bismuth are present in chalcopyrite in the deposits. In addition to these important rare metals, zinc, copper, arsenic, antimony, selenium, and tin are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are richer in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is related to S-type granite, while Mount Pleasant to A-type. It appears that petrographic character of the source magma is one of the factors to determine the trace element distribution in tin-polymetallic deposit. 6 refs., 2 figs.

  17. Bending and stretching of plates

    CERN Document Server

    Mansfield, E H; Hemp, W S

    1964-01-01

    The Bending and Stretching of Plates deals with elastic plate theory, particularly on small- and large-deflexion theory. Small-deflexion theory concerns derivation of basic equations, rectangular plates, plates of various shapes, plates whose boundaries are amenable to conformal transformation, plates with variable rigidity, and approximate methods. Large-deflexion theory includes general equations and some exact solutions, approximate methods in large-deflexion theory, asymptotic large-deflexion theories for very thin plates. Asymptotic theories covers membrane theory, tension field theory, a

  18. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

    Science.gov (United States)

    Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi

    2016-09-01

    Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.

  19. Effect of Graphene Addition on Mechanical Properties of TiN

    Energy Technology Data Exchange (ETDEWEB)

    Shon, In-Jin [Chonbuk National University, Jeonju (Korea, Republic of); Yoon, Jin-Kook; Hong, Kyung-Tae [Korea Institute of Science and Technology, Seoul (Korea, Republic of)

    2017-03-15

    Despite of many attractive properties of TiN, the current concern about the TiN focuses on its low fracture toughness below the ductile-brittle transition temperature. To improve its mechanical properties, the approach generally utilized has been the addition of a second phase to form composites and to make nanostructured materials. In this respect, highly dense nanostructured TiN and TiN-graphene composites were obtained within two min at 1250 ℃. The grain size of TiN was reduced remarkably by the addition of graphene. The addition of graphene to TiN simultaneously improved the fracture toughness and hardness of TiN-graphene composite due to refinement of TiN and deterring crack propagation by graphene. This study demonstrates that the graphene can be an effective reinforcing agent for improved hardness and fracture toughness of TiN composites.

  20. Modeling the hydrodynamics of phloem sieve plates

    Directory of Open Access Journals (Sweden)

    Kaare Hartvig Jensen

    2012-07-01

    Full Text Available Sieve plates have an enormous impact on the efficiency of the phloem vascular system of plants, responsible for the distribution of photosynthetic products. These thin plates, which separate neighboring phloem cells, are perforated by a large number of tiny sieve pores and are believed to play a crucial role in protecting the phloem sap from intruding animals by blocking flow when the phloem cell is damaged. The resistance to the flow of viscous sap in the phloem vascular system is strongly affected by the presence of the sieve plates, but the hydrodynamics of the flow through them remains poorly understood. We propose a theoretical model for quantifying the effect of sieve plates on the phloem in the plant, thus unifying and improving previous work in the field. Numerical simulations of the flow in real and idealized phloem channels verify our model, and anatomical data from 19 plant species are investigated. We find that the sieve plate resistance is correlated to the cell lumen resistance, and that the sieve plate and the lumen contribute almost equally to the total hydraulic resistance of the phloem translocation pathway.

  1. Synthesis of Submicron Hexagonal Plate-Type SnS2 and Band Gap-Tuned Sn1−xTixS2 Materials and Their Hydrogen Production Abilities on Methanol/Water Photosplitting

    Directory of Open Access Journals (Sweden)

    Kang Min Kim

    2014-01-01

    Full Text Available SnS2 and Sn1−xTixS2 (x = 0, 0.1, 0.3, 0.5, and 0.7 mol materials were designed using solvothermal method with the aim to enhance hydrogen production from water/methanol water photosplitting. Scanning electron microscopy revealed hexagonal plates with one side, 3.0 μm in length, in the SnS2 materials. Pure SnS2 showed absorption band edges of above 660 nm, and the absorption was shifted to low wavelengths with the insertion of Ti ions. The evolution of H2 from MeOH/H2O (1 : 1 photosplitting over SnS2 hexagonal plates in the photocatalytic liquid system was 0.016 mL h−1 g−1, and the evolutions were enhanced in Sn1−xTixS2. In particular, 0.049 mL h−1 g−1 of H2 gas was produced in Sn0.7Ti0.3S2 without electrolytes and it increased significantly to more than 90.6% (0.47 mL h−1 g−1 evolutions at higher pH using 0.1 M of KOH. Based on the UV-visible absorption spectra, the high photocatalytic activity of Sn1−xTixS2 was attributed to the existence of an appropriate band-gap state that retarded recombination between the electrons and holes.

  2. Effects of grid alloy on the properties of positive-plate corrosion layers in lead/acid batteries. Implications for premature capacity loss under repetitive deep-discharge cycling service

    Science.gov (United States)

    Hollenkamp, A. F.; Constanti, K. K.; Koop, M. J.; Apateanu, L.; Calabek, M.; Micka, K.

    1994-02-01

    Premature capacity loss (PCL) has been demonstrated consistently by the deep-discharge cycling of three-plate lead/acid cells configured with an excess of electrolyte. A capacity loss of approximately 2% per cycle was observed with cells based on tin-free, lead-calcium positive grids, under both constant-current and constant-voltage charging. The current that flows during constant-voltage charging decreases markedly within the first few cycles. This coincides with the establishment of an appreciable corrosion layer on the grid, and also with the onset of severe capacity loss. Significantly, there is no corresponding build-up of lead sulfate within the porous mass. With constant-current charging, a change in the overcharge factor, from 1.1 to 1.2, approximately doubles the rate of capacity loss. The corrosion products in lead-calcium plates exhibit a bi-layered structure: an outer corrosion layer of PbO2 and an inner layer in which the composition approaches PbO. These materials are prone to fracture and separation, especially between the two layers. Cells based on lead-antimony positive grids also suffer PCL, but the rate of capacity loss (approximately 1% per cycle) is less than that observed for the lead-calcium analogues. The current under constant-voltage charging of lead-antimony cells also decreases during the first few charge/discharge cycles, yet, this effect is over-shadowed by an increase in current due to the effects of antimony migration. Increasing the level of overcharge under constant-current charging produces only a slight reduction in cycle life. In regions close to the grid, PbO-like material is much less abundant than in lead-calcium plates. The corrosion products are composed mainly of PbO2, and are more coherent under stress. Resistance at the grid/porous material interface, measured in situ, increases greatly during discharge for plates based on lead-calcium grids, but much less for the corresponding lead-antimony plates. This tends to

  3. Anterior cervical plating

    Directory of Open Access Journals (Sweden)

    Gonugunta V

    2005-01-01

    Full Text Available Although anterior cervical instrumentation was initially used in cervical trauma, because of obvious benefits, indications for its use have been expanded over time to degenerative cases as well as tumor and infection of the cervical spine. Along with a threefold increase in incidence of cervical fusion surgery, implant designs have evolved over the last three decades. Observation of graft subsidence and phenomenon of stress shielding led to the development of the new generation dynamic anterior cervical plating systems. Anterior cervical plating does not conclusively improve clinical outcome of the patients, but certainly enhances the efficacy of autograft and allograft fusion and lessens the rate of pseudoarthrosis and kyphosis after multilevel discectomy and fusions. A review of biomechanics, surgical technique, indications, complications and results of various anterior cervical plating systems is presented here to enable clinicians to select the appropriate construct design.

  4. Room temperature ferromagnetism of tin oxide nanocrystal based on synthesis methods

    Energy Technology Data Exchange (ETDEWEB)

    Sakthiraj, K.; Hema, M. [Department of Physics, Kamaraj College of Engineering and Technology, Virudhunagar 626001, Tamil Nadu (India); Balachandrakumar, K. [Department of Physics, Raja Doraisingam Government Arts College, Sivagangai 630561, Tamil Nadu (India)

    2016-04-15

    The experimental conditions used in the preparation of nanocrystalline oxide materials play an important role in the room temperature ferromagnetism of the product. In the present work, a comparison was made between sol–gel, microwave assisted sol–gel and hydrothermal methods for preparing tin oxide nanocrystal. X-ray diffraction analysis indicates the formation of tetragonal rutile phase structure for all the samples. The crystallite size was estimated from the HRTEM images and it is around 6–12 nm. Using optical absorbance measurement, the band gap energy value of the samples has been calculated. It reveals the existence of quantum confinement effect in all the prepared samples. Photoluminescence (PL) spectra confirms that the luminescence process originates from the structural defects such as oxygen vacancies present in the samples. Room temperature hysteresis loop was clearly observed in M–H curve of all the samples. But the sol–gel derived sample shows the higher values of saturation magnetization (M{sub s}) and remanence (M{sub r}) than other two samples. This study reveals that the sol–gel method is superior to the other two methods for producing room temperature ferromagnetism in tin oxide nanocrystal.

  5. Vinegar Classification Based on Feature Extraction and Selection From Tin Oxide Gas Sensor Array Data

    Directory of Open Access Journals (Sweden)

    Huang Xingyi

    2003-03-01

    Full Text Available Tin oxide gas sensor array based devices were often cited in publications dealing with food products. However, during the process of using a tin oxide gas sensor array to analysis and identify different gas, the most important and difficult was how to get useful parameters from the sensors and how to optimize the parameters. Which can make the sensor array can identify the gas rapidly and accuracy, and there was not a comfortable method. For this reason we developed a device which satisfied the gas sensor array act with the gas from vinegar. The parameters of the sensor act with gas were picked up after getting the whole acting process data. In order to assure whether the feature parameter was optimum or not, in this paper a new method called “distinguish index”(DI has been proposed. Thus we can assure the feature parameter was useful in the later pattern recognition process. Principal component analysis (PCA and artificial neural network (ANN were used to combine the optimum feature parameters. Good separation among the gases with different vinegar is obtained using principal component analysis. The recognition probability of the ANN is 98 %. The new method can also be applied to other pattern recognition problems.

  6. Allocation of potential value socio-ecology post tin mining Kolong in Bangka Island

    Directory of Open Access Journals (Sweden)

    Himawan Wahyudi

    2017-01-01

    Full Text Available Kolong is a water basin as an impact of post tin mining in Bangka Island. Kolong should be managed properly to minimize some impacts, improve the quality of socio-ecological, and the income of local citizen. The purpose of this study was to analyze the potential allocation of socio-ecology value of the post tin mining. The case studies are Kolong in the Central Bangka Regency. This research was used resources valuation methodology, ABAD model classification, and observations. To determine the relationship of social ecology of the Kolong using SEM WarpPLS. The result shows that revenue of economic value of kolong in Bangka Island is IDR 17.9 Billion/year from utilization of Water Supply System, raw water and aquaculture. The diversity Kolong utilization as production tool of social needed in Bangka Island are 6 % as Water Supply System, 9 % as aquaculture, 0.2 % as tourism, and almost 84.8 % unused and owned by local government and private companies. The changing of kolong system influence the changing of social systems. The social variables that are most affected are the technology and local population. Utilization of Kolong as the economic value depends on its classification which based on the ABAD model.

  7. Modulation of electronic properties of tin oxide nanobelts via thermal control of surface oxygen defects

    Science.gov (United States)

    Keiper, Timothy D.; Barreda, Jorge L.; Zheng, Jim P.; Xiong, Peng

    2017-02-01

    Nanomaterials made from binary metal oxides are of increasing interest because of their versatility in applications from flexible electronics to portable chemical and biological sensors. Controlling the electrical properties of these materials is the first step in device implementation. Tin dioxide (SnO2) nanobelts (NB) synthesized by the vapor-liquid-solid mechanism have shown much promise in this regard. We explore the modification of devices prepared with single crystalline NBs by thermal annealing in vacuum and oxygen, resulting in a viable field-effect transistor (FET) for numerous applications at ambient temperature. An oxygen annealing step initially increases the device conductance by up to a factor of 105, likely through the modification of the surface defects of the NB, leading to Schottky barrier limited devices. A multi-step annealing procedure leads to further increase of the conductance by approximately 350% and optimization of the electronic properties. The effects of each step is investigated systematically on a single NB. The optimization of the electrical properties of the NBs makes possible the consistent production of channel-limited FETs and control of the device performance. Understanding these improvements on the electrical properties over the as-grown materials provides a pathway to enhance and tailor the functionalities of tin oxide nanostructures for a wide variety of optical, electronic, optoelectronic, and sensing applications that operate at room temperature.

  8. Investigation of the altered layer on ancient Chinese bronze mirrors and model high-tin bronzes

    Energy Technology Data Exchange (ETDEWEB)

    Taube, M. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Material Science and Engineering]|[Brookhaven National Lab., Upton, NY (United States); King, A.H. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Materials Science and Engineering; Chase, T.C. III [Smithsonian Institution, Washington, DC (United States)

    1996-12-31

    Many ancient Chinese bronze mirrors have a smooth patina. An ingress of corrosion to a depth of approximately 100 {mu}m is found beneath the patina. The corrosion selectively replaces the Cu-rich {alpha} phase leaving the Sn-rich {delta} phase intact. Previous work by x-ray diffraction has shown that the {alpha}-phase replacement product is poorly crystallized or nanocrystalline SnO{sub 2}. Transmission electron microscopy was employed to further characterize the replacement product in both ancient mirror and replication samples. Nanocrystalline SnO{sub 2} in the form of small spheroids has been found. Remnants of an original alloy phase appear to be interspersed with the tin oxide.

  9. Large Deflections of Elastic Rectangular Plates

    Science.gov (United States)

    Razdolsky, A. G.

    2015-11-01

    It is known that elastic large deflections of thin plates are governed by von Karman nonlinear equations. The analytical solution of these equations in the general case is unfeasible. Samuel Levy, in 1942, showed that large deflections of the rectangular plate can be expressed as a double series of sine-shaped harmonics (deflection harmonics). However, this method gave no way of creating the computer algorithm of solving the problem. The stress function expression taken in the Levy's method must be revised to find the approach that takes into account of all possible products of deflection coefficients. The algorithm of solving the problem for the rectangular plate with an arbitrary aspect ratio under the action of the lateral distributed load is reported in this paper. The approximation of the plate deflection is taken in the form of double series proposed by Samuel Levy. However, the expression for the stress function is presented in the form that incorporates products of deflection coefficients in the explicit form in distinction to the Levy's expression. The number of harmonics in the deflection expression may be arbitrary. The algorithm provides composing the system of governing cubic equations, which includes the deflection coefficients in the explicit form. Solving the equation system is based on using the principle of minimum potential energy. A method of the gradient descent is applied to find the equilibrium state of the plate as the minimum point of the potential energy. A computer program is developed on the basis of the present algorithm. Numerical examples carried out for the plate model with 16 deflection harmonics illustrate the potentialities of the program. The results of solving the examples are presented in the graphical form for the plates with a different aspect ratio and may be used under designing thin-walled elements of airplane and ship structures.

  10. License plate detection algorithm

    Science.gov (United States)

    Broitman, Michael; Klopovsky, Yuri; Silinskis, Normunds

    2013-12-01

    A novel algorithm for vehicle license plates localization is proposed. The algorithm is based on pixel intensity transition gradient analysis. Near to 2500 natural-scene gray-level vehicle images of different backgrounds and ambient illumination was tested. The best set of algorithm's parameters produces detection rate up to 0.94. Taking into account abnormal camera location during our tests and therefore geometrical distortion and troubles from trees this result could be considered as passable. Correlation between source data, such as license Plate dimensions and texture, cameras location and others, and parameters of algorithm were also defined.

  11. 金银合金板杂质控制的生产实践%The production practice of Gold and Silver alloy plate material control

    Institute of Scientific and Technical Information of China (English)

    李志; 杨其壬; 童章启

    2016-01-01

    silver electrolysis is strict to the requirement of impurities on the alloy board, silver smelting furnace of traditional method for impurity control poor Cu, Bi-impurities Cu is difficult to reduce , impurity Bi prone to"return". Therefore, through the consult literature material, and through analyzing the production process, use A metal to achieve the goal of stable except Cu Bi.%银电解对于合金板杂质的要求比较严格,分银炉传统火法冶炼对于杂质Cu、Bi的控制较差——杂质Cu难以降低,杂质Bi容易出现“返弹”。因此,通过查阅文献资料以及生产过程进行研究分析,采用金属A来实现除Cu稳Bi的目的。

  12. Spring-forward in composite plate elements

    NARCIS (Netherlands)

    Wijskamp, Sebastiaan; Lamers, E.A.D.; Akkerman, Remko; Banabic, D.

    2005-01-01

    Spring-forward is a distortion of corner sections in continuous fibre reinforced composite products. The linear thermoelastic prediction for the spring-forward of single curved geometries is incorporated in a FE formulation for plate elements in order to simulate the spring-forward of doubly curved

  13. Spring-forward in composite plate elements

    NARCIS (Netherlands)

    Wijskamp, S.; Lamers, E.A.D.; Akkerman, R.

    2005-01-01

    Spring-forward is a distortion of corner sections in continuous fibre reinforced composite products. The linear thermoelastic prediction for the spring-forward of single curved geometries is incorporated in a FE formulation for plate elements in order to simulate the spring-forward of doubly curved

  14. Casimir force between metal plate and dielectric plate

    Institute of Scientific and Technical Information of China (English)

    刘中柱; 邵成刚; 罗俊

    1999-01-01

    The Casimir effect between metal plate and dielectric plate is discussed with 1+1-dimensional potential model without using cut-off method. Calculation shows that the Casimir force between metal plate and dielectric plate is determined not only by the potential V0, the dielectric thickness and the distance α between the metal plate and dielectric plate, but also by the dimension of the vessel. When α is far less than the dimension of the vessel, the Casimir force Fc∝α(-1); conversely Fc∝α-2. This result is significant for Casimir force experiment.

  15. A Win for the Future of Tin

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    @@ Drinking that draft beer ttom a glass? Why not try tun products instead- they keep your beer cooler and more retreshing longer than glasses! In 1885, Yong Koon, a young man from Guangdong Province, traveled to Malaysia and established a pewter factory. One hundred and twenty five years later, the factorynow named Royal Selangor--is the world's biggest pewter manufacturer.

  16. Corrosion of steels in molten gallium (Ga), tin (Sn) and tin lithium alloy (Sn–20Li)

    Energy Technology Data Exchange (ETDEWEB)

    Kondo, Masatoshi, E-mail: kondo.masatoshi@nr.titech.ac.jp [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8550 (Japan); Ishii, Masaomi [Department of Nuclear Engineering, School of Engineering, Tokai University, 4-1-1 Kitakaname, Hiratsuka-shi, Kanagawa 259-1292 (Japan); Muroga, Takeo [Department of Helical Plasma Research, National Institute for Fusion Science, Toki, Gifu 502-5292 (Japan)

    2015-10-15

    Graphical abstract: Corrosion of RAFM steel, JLF-1, in liquid Sn–20Li was caused by the formation of Fe-Sn alloyed layer. - Highlights: • The corrosion tests were performed for the reduced activation ferritic martensitic steel JLF-1 and the austenitic steel SUS316 in liquid Ga, Sn and Sn-20Li at 873 K up to 750 h. • The weight loss of the specimens exposed to liquid Ga, Sn and Sn-20Li was evaluated. • The corrosion of the steels in liquid Ga was caused by the alloying reaction between Ga and Fe on the steel surface. • The corrosion of the steels in liquid Sn was caused by the alloying reaction between Sn and Fe on the steel surface. • The corrosion of the steels in liquid Sn-20Li was caused by the formation of the Fe-Sn alloyed layer and the diffusion of Sn and Li into the steel matrix. - Abstract: The compatibility of steels in liquid gallium (Ga), tin (Sn) and tin lithium alloy (Sn–20Li) was investigated by means of static corrosion tests. The corrosion tests were performed for reduced activation ferritic martensitic steel JLF-1 (JOYO-HEAT, Fe–9Cr–2W–0.1C) and austenitic steel SUS316 (Fe–18Cr–12Ni–2Mo). The test temperature was 873 K, and the exposure time was 250 and 750 h. The corrosion of these steels in liquid Ga, Sn and Sn–20Li alloy was commonly caused by the formation of a reaction layer and the dissolution of the steel elements into the melts. The reaction layer formed in liquid Ga was identified as Fe{sub 3}Ga from the results of metallurgical analysis and the phase diagram. The growth rate of the reaction layer on the JLF-1 steel showed a parabolic rate law, and this trend indicated that the corrosion could be controlled by the diffusion process through the layer. The reaction layer formed in liquid Sn and Sn–20Li was identified as FeSn. The growth rate had a linear function with exposure time. The corrosion in Sn and Sn–20Li could be controlled by the interface reaction on the layer. The growth rate of the layer formed

  17. Epitaxial NbN/AlN/NbN tunnel junctions on Si substrates with TiN buffer layers

    Directory of Open Access Journals (Sweden)

    Rui Sun

    2016-06-01

    Full Text Available We have developed epitaxial NbN/AlN/NbN tunnel junctions on Si (100 substrates with a TiN buffer layer. A 50-nm-thick (200-oriented TiN thin film was introduced as the buffer layer for epitaxial growth of NbN/AlN/NbN trilayers on Si substrates. The fabricated NbN/AlN/NbN junctions demonstrated excellent tunneling properties with a high gap voltage of 5.5 mV, a large IcRN product of 3.8 mV, a sharp quasiparticle current rise with a ΔVg of 0.4 mV, and a small subgap leakage current. The junction quality factor Rsg/RN was about 23 for the junction with a Jc of 47 A/cm2 and was about 6 for the junction with a Jc of 3.0 kA/cm2. X-ray diffraction and transmission electron microscopy observations showed that the NbN/AlN/NbN trilayers were grown epitaxially on the (200-orientated TiN buffer layer and had a highly crystalline structure with the (200 orientation.

  18. Evaluation of potential dietary toxicity of heavy metals in some common Nigerian beverages: A look at antimony, tin and mercury

    Directory of Open Access Journals (Sweden)

    I.I. Roberts

    2011-11-01

    Full Text Available There is currently little information on the composition of heavy metals in beverages imported and locally produced in Nigeria. The study quantitatively determined the composition of antimony (Sb, tin (Sn and mercury (Hg in 50 different beverage samples and evaluated the extent of violation of guideline values. Analysis of the beverage samples for the presence of Sb, Sn, and Hg was carried out using an atomic absorption spectrophotometer (AAS 929. The mean values detected for mercury, tin and antimony (±SE in fruit juices and soft drinks were 2.39±0.25, 3.66±0.22 and 0.49±0.048 μg/l; 2.93±0.34, 3.60±0.46 and 0.49±0.10 μg/l in dairy drinks and 0.94±0.02, 4.34±0.48 and 0.48±0.05 μg/l in bottled water samples respectively. While antimony detected in all products was below guideline values, mercury and tin were above the acceptable levels established by the World Health Organization, United States Environmental Protection Agency and European Union in most samples tested.

  19. In Situ Synthesis of Titanium Nickel Intermetallic Compounds Layer and TiN Coating By Laser Cladding

    Institute of Scientific and Technical Information of China (English)

    ZHANG Cui-hong; YANG Yong-qiang; XU Wei-hong

    2006-01-01

    Laser cladding,together with laser nitriding was used to synthesize a titanium nickel intermetallic compound layer on the nickel substrate and a TiN coating on the cladding layer. During the laser cladding, Ti and Ni powders were blown into the melting pool by a six-hole coaxial nozzle powder injection system. Exothermic reactions between Ti and Ni took place in the melting pool, and a cladding layer of titanium nickel intermetallic compounds was produced. Laser nitriding in a nitrogen-rich atmosphere followed the production of the cladding layer, and formed a golden yellow TiN layer over it. An optical and a scanning electron microscope were used to investigate the microstructures and measure the thicknesses of the cladding layer and the TiN layer. Phase identification was carried out by XRD. For the nitriding sample, the microhardness profile of the clad layer was tested. The optimal process parameters of the in situ synthesis of titanium nickel intermetallic compounds were obtained.

  20. Metallic tin-based nanoparticles synthesis by laser pyrolysis: Parametric studies focused on the decreasing of the crystallite size

    Science.gov (United States)

    Dutu, E.; Dumitrache, F.; Fleaca, C. T.; Morjan, I.; Gavrila-Florescu, L.; Morjan, I. P.; Sandu, I.; Scarisoreanu, M.; Luculescu, C.; Niculescu, A.-M.; Vasile, E.

    2015-05-01

    Due to their characteristic to allow a continuous, one-step nanosize particles production, the laser pyrolysis technique was employed to synthesize metallic Sn-based nanoparticles using tetramethyltin vapors as precursors and ethylene as laser energy transfer agent (sensitizer). Small size of tin particles is a requirement for their use as anodes in lithium ion batteries. In order to decrease the particle size, some experimental parameters were varied, allowing the control of the crystallite size down to 30 nm. The diminishing diameter of the reactive flow injection nozzle as well as the increasing of the tin precursor vapor flow enhance the gas velocity and the decrease the reactive species residence time in the laser beam, resulting smaller tin nanodroplets which forms solid nanoparticles after rapid cooling. XRD, TEM, EDX and SAED analysis point to the formation of nanosize β-Sn particles accompanied by various amount of disordered carbon as coating provided by ethylene decomposition (associated with their polymerization/dehydrogenation) in the presence of methyl radicals from Sn(CH3)4.