WorldWideScience

Sample records for plasma thermal effects

  1. Interaction of electromagnetic and plasma waves in warm motional plasma: Density and thermal effects

    Science.gov (United States)

    Rashed-Mohassel, P.; Hasanbeigi, A.; Hajisharifi, K.

    2017-08-01

    In this paper, the electromagnetic-electrostatic coupling instability excited in the two-dimensional planar-layered plasma medium with median temperature (warm motional plasma beam) is investigated by applying the initial fluctuation propagating along the planar surfaces. The dielectric tensor, obtained by the Maxwell-fluid model, is used to find the dispersion relation (DR) and different excited modes in the system. Interacting modes are investigated, in detail, by focusing on the effect of temperature on the plasma beam instability aroused by coupling the thermal excited modes (thermal-extraordinary and electron plasma modes) in the systems with various amounts of beam density. The numerical analysis of the obtained DR shows that even though the temperature effect of the plasma beam has an important role on the suppression of streaming instabilities, it does not have a considerable effect on the behavior of the coupling instability in the fluid limitation.

  2. Effect of Plasma Pretreatment on Thermal Durability of Thermal Barrier Coatings in Cyclic Thermal Exposure

    Directory of Open Access Journals (Sweden)

    Sang-Won Myoung

    2014-01-01

    Full Text Available Plasma pretreatment on the top and bond coats was performed and its influence on the thermal durability of thermal barrier coating (TBC system was investigated through cyclic thermal exposure. Two types of bond coat were prepared by different methods, namely, air plasma spray (APS and high-velocity oxy-fuel (HVOF, and two kinds of feedstock powder were employed for preparing the top coat in APS process. The better thermal durability was achieved in the vertically cracked TBC with the surface modified bond coat or with the bond coat prepared by APS process. The hardness and fracture toughness values of TBCs increased because of densification of the top coat during cyclic thermal exposure, and the bond coat prepared by HVOF process showed higher values than that by APS process. The TBCs with the surface modified bond coat were more efficient in improving adhesive strength than those without plasma pretreatment on the bond coat. The relationship between microstructure evolution and thermomechanical characteristics of TBCs with plasma pretreatment was discussed in cyclic thermal exposure.

  3. The effect of thermal aging on the thermal conductivity of plasma sprayed and EB-PVD thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D. [Oak Ridge National Lab., TN (United States); Nagaraj, B.A. [General Electric Co., Cincinnati, OH (United States). Aircraft Engine Group

    1996-05-01

    Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.

  4. Electric field effects in combustion with non-thermal plasma

    Science.gov (United States)

    Casey, Tiernan Albert

    Chemically reacting zones such as flames act as sources of charged species and can thus be considered as weakly-ionized plasmas. As such, the action of an externally applied electric field has the potential to affect the dynamics of reaction zones by enhancing transport, altering the local chemical composition, activating reaction pathways, and by providing additional thermal energy through the interaction of electrons with neutral molecules. To investigate these effects, one-dimensional simulations of reacting flows are performed including the treatment of charged species transport and non-thermal electron chemistry using a modified reacting fluid solver. A particular area of interest is that of plasma assisted ignition, which is investigated in a canonical one-dimensional configuration. An incipient ignition kernel, formed by localized energy deposition into a lean mixture of methane and air at atmospheric pressure, is subjected to sub-breakdown electric fields by applied voltages across the domain, resulting in non-thermal behavior of the electron sub-fluid formed during the discharge. Strong electric fields cause charged species to be rapidly transported from the ignition zone across the domain in opposite directions as charge fronts, augmenting the magnitude of the electric field in the fresh gas during the pulse through a dynamic-electrode effect. This phenomenon results in an increase in the energy of the electrons in the fresh mixture with increasing time, accelerating electron impact dissociation processes. A semi-analytic model to represent this dynamic electrode effect is constructed to highlight the relative simplicity of the electrodynamic problem admitted by the far more detailed chemistry and transport. Enhanced fuel and oxidizer decomposition due to electron impact dissociation and interaction with excited neutrals generate a pool of radicals, mostly O and H, in the fresh gas ahead of the flame's preheat zone. The effect of nanosecond pulses are to

  5. Non-thermal Dupree diffusivity and shielding effects on atomic collisions in astrophysical turbulent plasmas

    Science.gov (United States)

    Lee, Myoung-Jae; Jung, Young-Dae

    2016-02-01

    The influence of non-thermal Dupree turbulence and the plasma shielding on the electron-ion collision is investigated in astrophysical non-thermal Lorentzian turbulent plasmas. The second-order eikonal analysis and the effective interaction potential including the Lorentzian far-field term are employed to obtain the eikonal scattering phase shift and the eikonal collision cross section as functions of the diffusion coefficient, impact parameter, collision energy, Debye length and spectral index of the astrophysical Lorentzian plasma. It is shown that the non-thermal effect suppresses the eikonal scattering phase shift. However, it enhances the eikonal collision cross section in astrophysical non-thermal turbulent plasmas. The effect of non-thermal turbulence on the eikonal atomic collision cross section is weakened with increasing collision energy. The variation of the atomic cross section due to the non-thermal Dupree turbulence is also discussed.

  6. Evaluation of non-thermal plasma-induced anticancer effects on human colon cancer cells

    Science.gov (United States)

    Choi, Jae-Sun; Kim, Jeongho; Hong, Young-Jun; Bae, Woom-Yee; Choi, Eun Ha; Jeong, Joo-Won; Park, Hun-Kuk

    2017-01-01

    Non-thermal atmospheric-pressure plasma has been introduced in various applications such as sterilization, wound healing, blood coagulation, and other biomedical applications. The most attractive application of non-thermal atmospheric-pressure plasma is in cancer treatment, where the plasma is used to produce reactive oxygen species (ROS) to facilitate cell apoptosis. We investigate the effects of different durations of exposure to dielectric-barrier discharge (DBD) plasma on colon cancer cells using measurement of cell viability and ROS levels, western blot, immunocytochemistry, and Raman spectroscopy. Our results suggest that different kinds of plasma-treated cells can be differentiated from control cells using the Raman data. PMID:28663896

  7. Non-thermal atmospheric pressure plasma activates lactate in Ringer's solution for anti-tumor effects.

    Science.gov (United States)

    Tanaka, Hiromasa; Nakamura, Kae; Mizuno, Masaaki; Ishikawa, Kenji; Takeda, Keigo; Kajiyama, Hiroaki; Utsumi, Fumi; Kikkawa, Fumitaka; Hori, Masaru

    2016-11-08

    Non-thermal atmospheric pressure plasma is a novel approach for wound healing, blood coagulation, and cancer therapy. A recent discovery in the field of plasma medicine is that non-thermal atmospheric pressure plasma not only directly but also indirectly affects cells via plasma-treated liquids. This discovery has led to the use of non-thermal atmospheric pressure plasma as a novel chemotherapy. We refer to these plasma-treated liquids as plasma-activated liquids. We chose Ringer's solutions to produce plasma-activated liquids for clinical applications. In vitro and in vivo experiments demonstrated that plasma-activated Ringer's lactate solution has anti-tumor effects, but of the four components in Ringer's lactate solution, only lactate exhibited anti-tumor effects through activation by non-thermal plasma. Nuclear magnetic resonance analyses indicate that plasma irradiation generates acetyl and pyruvic acid-like groups in Ringer's lactate solution. Overall, these results suggest that plasma-activated Ringer's lactate solution is promising for chemotherapy.

  8. Mitochondria-Mediated Anticancer Effects of Non-Thermal Atmospheric Plasma.

    Directory of Open Access Journals (Sweden)

    Aigul Zhunussova

    Full Text Available Non-thermal atmospheric pressure plasma has attracted great interest due to its multiple potential biomedical applications with cancer treatment being among the most urgent. To realize the clinical potential of non-thermal plasma, the exact cellular and molecular mechanisms of plasma effects must be understood. This work aimed at studying the prostate cancer specific mechanisms of non-thermal plasma effects on energy metabolism as a central regulator of cell homeostasis and proliferation. It was found that cancer cells with higher metabolic rate initially are more resistant to plasma treated phosphate-buffered saline (PBS since the respiratory and calcium sensitive signaling systems were not responsive to plasma exposure. However, dramatic decline of cancer oxidative phosphorylation developed over time resulted in significant progression of cell lethality. The normal prostate cells with low metabolic activity immediately responded to plasma treated PBS by suppression of respiratory functions and sustained elevation of cytosolic calcium. However, over time the normal cells start recovering their mitochondria functions, proliferate and restore the cell population. We found that the non-thermal plasma induced increase in intracellular ROS is of primarily non-mitochondrial origin. The discriminate non-thermal plasma effects hold a promise for clinical cancer intervention.

  9. Mitochondria-Mediated Anticancer Effects of Non-Thermal Atmospheric Plasma

    Science.gov (United States)

    Zhunussova, Aigul; Vitol, Elina A.; Polyak, Boris; Tuleukhanov, Sultan; Brooks, Ari D.; Sensenig, Richard; Friedman, Gary; Orynbayeva, Zulfiya

    2016-01-01

    Non-thermal atmospheric pressure plasma has attracted great interest due to its multiple potential biomedical applications with cancer treatment being among the most urgent. To realize the clinical potential of non-thermal plasma, the exact cellular and molecular mechanisms of plasma effects must be understood. This work aimed at studying the prostate cancer specific mechanisms of non-thermal plasma effects on energy metabolism as a central regulator of cell homeostasis and proliferation. It was found that cancer cells with higher metabolic rate initially are more resistant to plasma treated phosphate-buffered saline (PBS) since the respiratory and calcium sensitive signaling systems were not responsive to plasma exposure. However, dramatic decline of cancer oxidative phosphorylation developed over time resulted in significant progression of cell lethality. The normal prostate cells with low metabolic activity immediately responded to plasma treated PBS by suppression of respiratory functions and sustained elevation of cytosolic calcium. However, over time the normal cells start recovering their mitochondria functions, proliferate and restore the cell population. We found that the non-thermal plasma induced increase in intracellular ROS is of primarily non-mitochondrial origin. The discriminate non-thermal plasma effects hold a promise for clinical cancer intervention. PMID:27270230

  10. Sterilization effect of atmospheric pressure non-thermal air plasma on dental instruments

    National Research Council Canada - National Science Library

    Sung, Su-Jin; Huh, Jung-Bo; Yun, Mi-Jung; Chang, Brian Myung W; Jeong, Chang-Mo; Jeon, Young-Chan

    2013-01-01

    .... To develop a dental sterilizer which can sterilize most materials, such as metals, rubbers, and plastics, the sterilization effect of an atmospheric pressure non-thermal air plasma device was evaluated...

  11. Polarization of the Sunyaev-Zel'dovich effect: relativistic imprint of thermal and non-thermal plasma

    CERN Document Server

    Emritte, M S; Marchegiani, P

    2016-01-01

    [Abridged] Inverse Compton scattering of CMB fluctuations off cosmic electron plasma generates a polarization of the associated Sunyaev-Zel'dovich (SZ) effect. This signal has been studied so far mostly in the non-relativistic regime and for a thermal electron population and, as such, has limited astrophysical applications. Partial attempts to extend this calculation for a thermal electron plasma in the relativistic regime have been done but cannot be applied to a general relativistic electron distribution. Here we derive a general form of the SZ effect polarization valid in the full relativistic approach for both thermal and non-thermal electron plasmas, as well as for a generic combination of various electron population co-spatially distributed in the environments of galaxy clusters or radiogalaxy lobes. We derive the spectral shape of the Stokes parameters induced by the IC scattering of every CMB multipole, focusing on the CMB quadrupole and octupole that provide the largest detectable signals in galaxy c...

  12. Investigation of non-thermal plasma effects on lung cancer cells within 3D collagen matrices

    Science.gov (United States)

    Karki, Surya B.; Thapa Gupta, Tripti; Yildirim-Ayan, Eda; Eisenmann, Kathryn M.; Ayan, Halim

    2017-08-01

    Recent breakthroughs in plasma medicine have identified a potential application for the non-thermal plasma in cancer therapy. Most studies on the effects of non-thermal plasma on cancer cells have used traditional two-dimensional (2D) monolayer cell culture. However, very few studies are conducted employing non-thermal plasma in animal models. Two dimensional models do not fully mimic the three-dimensional (3D) tumor microenvironment and animal models are expensive and time-consuming. Therefore, we used 3D collagen matrices that closely resemble the native geometry of cancer tissues and provide more physiologically relevant results than 2D models, while providing a more cost effective and efficient precursor to animal studies. We previously demonstrated a role for non-thermal plasma application in promoting apoptotic cell death and reducing the viability of A549 lung adenocarcinoma epithelial cells cultured upon 2D matrices. In this study, we wished to determine the efficacy of non-thermal plasma application in driving apoptotic cell death of A549 lung cancer cells encapsulated within a 3D collagen matrix. The percentage of apoptosis increased as treatment time increased and was time dependent. In addition, the anti-viability effect of plasma was demonstrated. Twenty-four hours post-plasma treatment, 38% and 99% of cell death occurred with shortest (15 s) and longest treatment time (120 s) respectively at the plasma-treated region. We found that plasma has a greater effect on the viability of A549 lung cancer cells on the superficial surface of 3D matrices and has diminishing effects as it penetrates the 3D matrix. We also identified the nitrogen and oxygen species generated by plasma and characterized their penetration in vertical and lateral directions within the 3D matrix from the center of the plasma-treated region. Therefore, the utility of non-thermal dielectric barrier discharge plasma in driving apoptosis and reducing the viability of lung cancer cells

  13. Non-thermal Dupree diffusivity and shielding effects on atomic collisions in Lorentzian turbulent plasmas

    Science.gov (United States)

    Lee, Myoung-Jae; Jung, Young-Dae

    2016-05-01

    The influence of non-thermal Dupree turbulence and the plasma shielding on the electron-ion collision is investigated in Lorentzian turbulent plasmas. The second-order eikonal analysis and the effective interaction potential including the Lorentzian far-field term are employed to obtain the eikonal scattering phase shift and the eikonal collision cross section as functions of the diffusion coefficient, impact parameter, collision energy, Debye length and spectral index of the astrophysical Lorentzian plasma. It is shown that the non-thermal effect suppresses the eikonal scattering phase shift. However, it enhances the eikonal collision cross section in astrophysical non-thermal turbulent plasmas. The effect of non-thermal turbulence on the eikonal atomic collision cross section is weakened with increasing collision energy. The variation of the atomic cross section due to the non-thermal Dupree turbulence is also discussed. This research was supported by Nuclear Fusion Research Program through NRF funded by the Ministry of Science, ICT & Future Planning (Grant No. 2015M1A7A1A01002786).

  14. Effect of gasification parameter on coal gasification in thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Shen, S.; Pang, X.; Bao, W.; Lo, Y.; Zhu, S. [Taiyuan University of Technology, Taiyuan (China)

    2004-12-01

    The influence of several parameters such as the power input of plasma jet, vapor and air input etc on gas composition and carbon conversion from coal gasification in an air-steam plasma jet was studied. The main gaseous products are H{sub 2}, CO, CO{sub 2}, CH{sub 2}4 and tar was discovered. Results show that the concentration of H{sub 2}, CO and carbon conversion increases, and the concentration of CO{sub 2} significantly decreases, when the power input of plasma jet is raised. The concentration of H{sub 2} increases when the vapor flux is increased, but excessive steam can decrease carbon conversion. The carbon conversion is enhanced by decreasing feed rate. The air flux should be reduced to improve the quality of coal gas in a certain range. The carbon conversion of Datong coal can exceed 95% at appropriate condition. 18 refs., 4 figs., 2 tabs.

  15. Effect of low-temperature plasma treatment on tailorability and thermal properties of wool fabrics

    Indian Academy of Sciences (India)

    V S Goud; J S Udakhe

    2011-10-01

    Dielectric barrier discharge type of plasma reactor was used for the low-temperature plasma (LTP) treatment of the wool fabrics. Air was used as the non-polymerizing gas for the plasma treatment at different time intervals. Low-stress mechanical properties of the treated and untreated wool fabrics were evaluated using Siro-fast technique which revealed that the tensile, bending, compression, shear, dimensional stability and surface properties were altered after the LTP treatment. Other properties such as thermal conductivity, thermal resistance and pilling propensity were also evaluated. The surface topographical changes of the wool fibres after LTP treatment were analysed by scanning electron microscopy. The changes in these properties are supposed to be related closely to the interfibre and interyarn frictional force and increased surface area of the fibres induced by the etching effect of plasma.

  16. Selective cytotoxic effect of non-thermal micro-DBD plasma

    Science.gov (United States)

    Kwon, Byung-Su; Choi, Eun Ha; Chang, Boksoon; Choi, Jeong-Hyun; Kim, Kyung Sook; Park, Hun-Kuk

    2016-10-01

    Non-thermal plasma has been extensively researched as a new cancer treatment technology. We investigated the selective cytotoxic effects of non-thermal micro-dielectric barrier discharge (micro-DBD) plasma in cervical cancer cells. Two human cervical cancer cell lines (HeLa and SiHa) and one human fibroblast (HFB) cell line were treated with micro-DBD plasma. All cells underwent apoptotic death induced by plasma in a dose-dependent manner. The plasma showed selective inhibition of cell proliferation in cervical cancer cells compared to HFBs. The selective effects of the plasma were also observed between the different cervical cancer cell lines. Plasma treatment significantly inhibited the proliferation of SiHa cells in comparison to HeLa cells. The changes in gene expression were significant in the cervical cancer cells in comparison to HFBs. Among the cancer cells, apoptosis-related genes were significantly enriched in SiHa cells. These changes were consistent with the differential cytotoxic effects observed in different cell lines.

  17. SUPERFAST THERMALIZATION OF PLASMA

    Science.gov (United States)

    Chang, C.C.

    1962-06-12

    A method is given for the superfast thermalization of plasma by shock conversion of the kinetic energy stored in rotating plasma rings or plasmoids colliding at near supersonic speeds in a containment field to heat energy in the resultant confined plasma mass. The method includes means for generating rotating plasmoids at the opposite ends of a Pyrotron or Astron containment field. The plasmoids are magnetically accelerated towards each other into the opposite ends of time containment field. During acceleration of the plasmoids toward the center of the containment field, the intensity of the field is sequentially increased to adiabatically compress the plasmoids and increase the plasma energy. The plasmoids hence collide with a violent shock at the eenter of the containment field, causing the substantial kinetic energy stored in the plasmoids to be converted to heat in the resultant plasma mass. (AEC)

  18. Thermal-inertial effects on magnetic reconnection in relativistic pair plasmas.

    Science.gov (United States)

    Comisso, Luca; Asenjo, Felipe A

    2014-07-25

    The magnetic reconnection process is studied in relativistic pair plasmas when the thermal and inertial properties of the magnetohydrodynamical fluid are included. We find that in both Sweet-Parker and Petschek relativistic scenarios there is an increase of the reconnection rate owing to the thermal-inertial effects, both satisfying causality. To characterize the new effects we define a thermal-inertial number which is independent of the relativistic Lundquist number, implying that reconnection can be achieved even for vanishing resistivity as a result of only thermal-inertial effects. The current model has fundamental importance for relativistic collisionless reconnection, as it constitutes the simplest way to get reconnection rates faster than those accessible with the sole resistivity.

  19. Numerical Investigation of Thermal Effect in Plasma Electrode Pockels Cell for High Average Power

    Institute of Scientific and Technical Information of China (English)

    CAO Ding-Xiang; ZHANG Xiong-Jun; ZHENG Wan-Guo; HE Shao-Bo; SUI Zhan

    2006-01-01

    @@ The average power of a Pockels cell is limited by thermal effects arising from the optical absorption of the laser pulse. These thermal effects can be managed by configuring the switch as a plasma-electrode thin plate Pockels cell, which works under heat-capacity operation. Simulation results show that, based on KD*P (in thickness 0.5cm) at an average power loading of 1 kW, the aperture integrated depolarization loss at 1.06 um is less than 10% in 5min working time.

  20. Thermal effects in the dissipative instability of the electron beam-plasma systems

    Energy Technology Data Exchange (ETDEWEB)

    Shokri, B. [Physics Department and Laser-plasma Research Institute of Shahid Beheshti University, Tehran (Iran, Islamic Republic of) and Research Institute of Astronomy and Astrophysics of Maragha, PO Box 55134-44, Maragha (Iran, Islamic Republic of) and Institute for Studies in Theoretical Physics and Mathematics, PO Box 19395-1795, Tehran (Iran, Islamic Republic of)]. E-mail: b-shokri@cc.sbu.ac.ir; Khorashadizadeh, S.M. [Physics Department of Shahid Beheshti University, Tehran (Iran, Islamic Republic of); Physics Department of Birjand University, Birjand (Iran, Islamic Republic of)

    2006-04-10

    The effects of the thermal motion of the charged particles in the dissipative instability of the under and over-limiting currents of a relativistic electron beam in a fully magnetized beam-plasma waveguide is investigated. It is shown that by increasing the temperature of the plasma electrons, the resonant frequency of the waveguide slightly increases and the growth rates of the instability development decreases. In addition, an increase of the temperature of the plasma electron can change the dissipative hydrodynamic instability to the collisionless kinetic instability. Furthermore, the dissipative instability of the overlimiting electron beam is shown to be more sensitive with respect to the electron plasma temperature compared to the underlimiting electron beam case.

  1. Non-thermal atmospheric pressure plasma activates lactate in Ringer’s solution for anti-tumor effects

    Science.gov (United States)

    Tanaka, Hiromasa; Nakamura, Kae; Mizuno, Masaaki; Ishikawa, Kenji; Takeda, Keigo; Kajiyama, Hiroaki; Utsumi, Fumi; Kikkawa, Fumitaka; Hori, Masaru

    2016-11-01

    Non-thermal atmospheric pressure plasma is a novel approach for wound healing, blood coagulation, and cancer therapy. A recent discovery in the field of plasma medicine is that non-thermal atmospheric pressure plasma not only directly but also indirectly affects cells via plasma-treated liquids. This discovery has led to the use of non-thermal atmospheric pressure plasma as a novel chemotherapy. We refer to these plasma-treated liquids as plasma-activated liquids. We chose Ringer’s solutions to produce plasma-activated liquids for clinical applications. In vitro and in vivo experiments demonstrated that plasma-activated Ringer’s lactate solution has anti-tumor effects, but of the four components in Ringer’s lactate solution, only lactate exhibited anti-tumor effects through activation by non-thermal plasma. Nuclear magnetic resonance analyses indicate that plasma irradiation generates acetyl and pyruvic acid-like groups in Ringer’s lactate solution. Overall, these results suggest that plasma-activated Ringer’s lactate solution is promising for chemotherapy.

  2. Effective group index of refraction in non-thermal plasma photonic crystals

    Science.gov (United States)

    Mousavi, A.; Sadegzadeh, S.

    2015-11-01

    Plasma photonic crystals (PPCs) are periodic arrays that consist of alternate layers of micro-plasma and dielectric. These structures are used to control the propagation of electromagnetic waves. This paper presents a survey of research on the effect of non-thermal plasma with bi-Maxwellian distribution function on one dimensional PPC. A plasma with temperature anisotropy is not in thermodynamic equilibrium and can be described by the bi-Maxwellian distribution function. By using Kronig-Penny's model, the dispersion relation of electromagnetic modes in one dimensional non-thermal PPC (NPPC) is derived. The band structure, group velocity vg, and effective group index of refraction neff(g) of such NPPC structure with TeO2 as the material of dielectric layers have been studied. The concept of negative group velocity and negative neff(g), which indicates an anomalous behaviour of the PPCs, are also observed in the NPPC structures. Our numerical results provide confirmatory evidence that unlike PPCs there are finite group velocity and non-zero effective group indexes of refraction in photonic band gaps (PBGs) that lie in certain ranges of normalized frequency. In other words, inside the PBGs of NPPCs, neff(g) becomes non-zero and photons travel with a finite group velocity. In this special case, this velocity varies alternately between 20c and negative values of the order 103c (c is the speed of light in vacuum).

  3. Effect of oxygen plasma and thermal oxidation on shallow nitrogen-vacancy centers in diamond

    Energy Technology Data Exchange (ETDEWEB)

    Kim, M.; Rugar, D., E-mail: rugar@us.ibm.com [IBM Research Division, Almaden Research Center, San Jose, California 95120 (United States); Center for Probing the Nanoscale, Stanford University, Stanford, California 94305 (United States); Mamin, H. J.; Sherwood, M. H.; Rettner, C. T.; Frommer, J. [IBM Research Division, Almaden Research Center, San Jose, California 95120 (United States)

    2014-07-28

    We investigate the effect of two different surface treatments on shallow nitrogen-vacancy (NV) centers in diamond. Short duration oxygen plasma exposure is found to damage near-surface NV centers, resulting in their disappearance in fluorescence images. Subsequent annealing creates large numbers of new NV centers, attributed to plasma-induced vacancy creation. By tracking individual NV centers during thermal oxidation, we show that oxidation at 550 °C results in modest improvement of spin coherence. Higher temperature oxidations correlate with gradual decline in spin coherence and eventual instability of NV centers before ultimate disappearance. This is indicative of a reduction of the NV-to-surface distance due to oxidative etching. Thermal oxidation can offer controlled access to near-surface NV spins at the nanometer scale, an important requirement for many applications of NV-based nanomagnetometry.

  4. Differential effect of non-thermal atmospheric-pressure plasma on angiogenesis

    Directory of Open Access Journals (Sweden)

    Beate Haertel

    2014-06-01

    Full Text Available Angiogenesis is a special feature in wound healing and carcinogenesis. For improving wound healing angiogenesis should be promoted, whereas in treating tumors it should be inhibited.Depending on several factors physical non-thermal plasmas can stimulate or inhibit cellular processes and can, thereby, influence angiogenesis. This study focused on effects of plasma on angiogenesis in the chick embryo chorioallantoic membrane (CAM assay and rat aortic ring (AOR test, in which plasma-treated PBS or medium was applied. ImageJ was used to analyze vessel area and branching of vessels of CAM’s. Aortic rings (LEW.1W, WOK.W rats embedded in Matrigel were analyzed by a newly-developed semi-quantitative method to quantify vessel sprouting from aortic rings. In both models spontaneous vessel formation was detected. Vessel area and branching in CAM’s were significantly enhanced by 120-s-plasma-treated PBS compared to untreated controls. This result was comparable with the effect of the growth factor VEGF. No effect of plasma on vessel sprouting from AOR prepared from LEW.1W rats was detected, while it was significantly inhibited in rings of WOK.W rats. Dexamethasone inhibited vessel sprouting from AOR of both rat strains. In conclusion, angiogenic response to plasma was found to be differentially influenced, depending on the models used and on the rat strain in the AOR test. It will now be of importance to learn how plasma has to be designed for either pro- or anti-angiogenic responses.

  5. Ion thermal effects on slow mode solitary waves in plasmas with two adiabatic ion species

    Energy Technology Data Exchange (ETDEWEB)

    Nsengiyumva, F., E-mail: franco.nseng@gmail.com; Hellberg, M. A., E-mail: hellberg@ukzn.ac.za; Mace, R. L., E-mail: macer@ukzn.ac.za [School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa)

    2015-09-15

    Using both the Sagdeev and Korteweg-de Vries (KdV) methods, ion thermal effects on slow mode ion acoustic solitons and double layers are investigated in a plasma with two adiabatic positive ion species. It is found that reducing the gap between the two ion thermal speeds by increasing the relative temperature of the cool ions increases the typical soliton/double layer speeds for all values of the ion-ion density ratio and reduces the range in the density ratio that supports double layers. The effect of increasing the relative cool ion temperature on the soliton/double layer amplitudes depends on the relative densities. For lower values of the ion density ratio, an increase in cool ion temperature leads to a significant decrease in soliton/double layer amplitude, so one may find that solitons of all permissible speeds lie within the range of KdV theory.

  6. Effective group index of refraction in non-thermal plasma photonic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Mousavi, A.; Sadegzadeh, S., E-mail: sadegzadeh@azaruniv.edu [Physics Department, Azarbaijan Shahid Madani University, Tabriz (Iran, Islamic Republic of)

    2015-11-15

    Plasma photonic crystals (PPCs) are periodic arrays that consist of alternate layers of micro-plasma and dielectric. These structures are used to control the propagation of electromagnetic waves. This paper presents a survey of research on the effect of non-thermal plasma with bi-Maxwellian distribution function on one dimensional PPC. A plasma with temperature anisotropy is not in thermodynamic equilibrium and can be described by the bi-Maxwellian distribution function. By using Kronig-Penny's model, the dispersion relation of electromagnetic modes in one dimensional non-thermal PPC (NPPC) is derived. The band structure, group velocity v{sub g}, and effective group index of refraction n{sub eff}(g) of such NPPC structure with TeO{sub 2} as the material of dielectric layers have been studied. The concept of negative group velocity and negative n{sub eff}(g), which indicates an anomalous behaviour of the PPCs, are also observed in the NPPC structures. Our numerical results provide confirmatory evidence that unlike PPCs there are finite group velocity and non-zero effective group indexes of refraction in photonic band gaps (PBGs) that lie in certain ranges of normalized frequency. In other words, inside the PBGs of NPPCs, n{sub eff}(g) becomes non-zero and photons travel with a finite group velocity. In this special case, this velocity varies alternately between 20c and negative values of the order 10{sup 3}c (c is the speed of light in vacuum)

  7. Highly Segmented Thermal Barrier Coatings Deposited by Suspension Plasma Spray: Effects of Spray Process on Microstructure

    Science.gov (United States)

    Chen, Xiaolong; Honda, Hiroshi; Kuroda, Seiji; Araki, Hiroshi; Murakami, Hideyuki; Watanabe, Makoto; Sakka, Yoshio

    2016-12-01

    Effects of the ceramic powder size used for suspension as well as several processing parameters in suspension plasma spraying of YSZ were investigated experimentally, aiming to fabricate highly segmented microstructures for thermal barrier coating (TBC) applications. Particle image velocimetry (PIV) was used to observe the atomization process and the velocity distribution of atomized droplets and ceramic particles travelling toward the substrates. The tested parameters included the secondary plasma gas (He versus H2), suspension injection flow rate, and substrate surface roughness. Results indicated that a plasma jet with a relatively higher content of He or H2 as the secondary plasma gas was critical to produce highly segmented YSZ TBCs with a crack density up to 12 cracks/mm. The optimized suspension flow rate played an important role to realize coatings with a reduced porosity level and improved adhesion. An increased powder size and higher operation power level were beneficial for the formation of highly segmented coatings onto substrates with a wider range of surface roughness.

  8. Thermal effects on seeded finite ion temperature, high amplitude plasma blobs

    CERN Document Server

    Held, M; Madsen, J; Kendl, A

    2016-01-01

    Thermal effects on the perpendicular convection of seeded pressure blobs in the scrape-off layer of magnetised fusion plasmas are investigated. Our numerical study is based on a four field full-F gyrofluid model, which entails the consistent description of high fluctuation amplitudes and dynamic finite Larmor radius effects. We find that a temperature perturbation increases the maximal blob velocity and that a finite Larmor radius contributes to highly compact blob structures with finite poloidal motion. An extensive parameter study reveals that a smooth transition to this compact blob regime occurs when the finite Larmor radius effect strength, defined by the ratio of the ion diamagnetic to the perpendicular vorticity, exceeds unity. The maximal blob velocities excellently agree with the inertial velocity scaling law over more than an order of magnitude. We show that the finite Larmor radius effect strength affects the radial transport and verify the here presented empirical scaling law for the maximal radia...

  9. Effects of background fluid on the efficiency of inactivating yeast with non-thermal atmospheric pressure plasma.

    Directory of Open Access Journals (Sweden)

    Young-Hyo Ryu

    Full Text Available Non-thermal plasma at atmospheric pressure has been actively applied to sterilization. However, its efficiency for inactivating microorganisms often varies depending on microbial species and environments surrounding the microorganisms. We investigated the influence of environmental factors (surrounding media on the efficiency of microbial inactivation by plasma using an eukaryotic model microbe, Saccharomyces cerevisiae, to elucidate the mechanisms for differential efficiency of sterilization by plasma. Yeast cells treated with plasma in water showed the most severe damage in viability and cell morphology as well as damage to membrane lipids, and genomic DNA. Cells in saline were less damaged compared to those in water, and those in YPD (Yeast extract, Peptone, Dextrose were least impaired. HOG1 mitogen activated protein kinase was activated in cells exposed to plasma in water and saline. Inactivation of yeast cells in water and saline was due to the acidification of the solutions by plasma, but higher survival of yeast cells treated in saline may have resulted from the additional effect related to salt strength. Levels of hydroxyl radical (OH· produced by plasma were the highest in water and the lowest in YPD. This may have resulted in differential inactivation of yeast cells in water, saline, and YPD by plasma. Taken together, our data suggest that the surrounding media (environment can crucially affect the outcomes of yeast cell plasma treatment because plasma modulates vital properties of media, and the toxic nature of plasma can also be altered by the surrounding media.

  10. Effects of background fluid on the efficiency of inactivating yeast with non-thermal atmospheric pressure plasma.

    Science.gov (United States)

    Ryu, Young-Hyo; Kim, Yong-Hee; Lee, Jin-Young; Shim, Gun-Bo; Uhm, Han-Sup; Park, Gyungsoon; Choi, Eun Ha

    2013-01-01

    Non-thermal plasma at atmospheric pressure has been actively applied to sterilization. However, its efficiency for inactivating microorganisms often varies depending on microbial species and environments surrounding the microorganisms. We investigated the influence of environmental factors (surrounding media) on the efficiency of microbial inactivation by plasma using an eukaryotic model microbe, Saccharomyces cerevisiae, to elucidate the mechanisms for differential efficiency of sterilization by plasma. Yeast cells treated with plasma in water showed the most severe damage in viability and cell morphology as well as damage to membrane lipids, and genomic DNA. Cells in saline were less damaged compared to those in water, and those in YPD (Yeast extract, Peptone, Dextrose) were least impaired. HOG1 mitogen activated protein kinase was activated in cells exposed to plasma in water and saline. Inactivation of yeast cells in water and saline was due to the acidification of the solutions by plasma, but higher survival of yeast cells treated in saline may have resulted from the additional effect related to salt strength. Levels of hydroxyl radical (OH·) produced by plasma were the highest in water and the lowest in YPD. This may have resulted in differential inactivation of yeast cells in water, saline, and YPD by plasma. Taken together, our data suggest that the surrounding media (environment) can crucially affect the outcomes of yeast cell plasma treatment because plasma modulates vital properties of media, and the toxic nature of plasma can also be altered by the surrounding media.

  11. Effects of non-thermal atmospheric pressure pulsed plasma on the adhesion and durability of resin composite to dentin.

    Science.gov (United States)

    Han, Geum-Jun; Kim, Jae-Hoon; Chung, Sung-No; Chun, Bae-Hyeock; Kim, Chang-Keun; Seo, Deog-Gyu; Son, Ho-Hyun; Cho, Byeong-Hoon

    2014-12-01

    This study investigated the effect of low-power, non-thermal atmospheric pressure plasma (NT-APP) treatments, in pulsed and conventional modes, on the adhesion of resin composite to dentin and on the durability of the bond between resin composite and dentin. A pencil-type NT-APP jet was applied in pulsed and conventional modes to acid-etched dentin. The microtensile bond strength (MTBS) of resin composite to dentin was evaluated at 24 h and after thermocycling in one control group (no plasma) and in two experimental groups (pulsed plasma and conventional plasma groups) using the Scotchbond Multi-Purpose Plus Adhesive System. Data were analyzed using two-factor repeated-measures anova and Weibull statistics. Fractured surfaces and the bonded interfaces were evaluated using a field-emission scanning electron microscope. Although there were no significant differences between the plasma treatment groups, the plasma treatment improved the MTBS compared with the control group. After thermocycling, the MTBS did not decrease in the control or conventional plasma group but increased in the pulsed plasma group. Thermocycling increased the Weibull moduli of plasma-treated groups. In conclusion, plasma treatment using NT-APP improved the adhesion of resin composite to dentin. Using a pulsed energy source, the energy delivered to the dentin was effectively reduced without any reduction in bond strength or durability.

  12. Effects of atmospheric-pressure non-thermal bio-compatible plasma and plasma activated nitric oxide water on cervical cancer cells.

    Science.gov (United States)

    Li, Ying; Ho Kang, Min; Sup Uhm, Han; Joon Lee, Geon; Ha Choi, Eun; Han, Ihn

    2017-03-31

    Atmospheric-pressure non-thermal bio-compatible plasma is a partially ionized gas with electrically charged particles. Previous studies demonstrated that dielectric barrier discharge (DBD) plasma could induce apoptosis of various cancer cells, in particular demonstrating the selective cytotoxicity of cancer cells over normal cells. Therefore, DBD plasma can be considered as a potential cancer treatment method for clinical applications. We previously developed a microwave jet plasma system, producing nitric oxide called nitric oxide-plasma activated water (NO-PAW). In this study, we explored the effects of NO-PAW on a cervical cancer cell line, in comparison with DBD plasma. The cytotoxicity results showed that the treatment of HeLa cell with DBD for 4 minutes and 7 μM concentration of NO-PAW could reach almost IC60. For the apoptosis assay, 4 minutes treatment of DBD could induce 7% apoptotic effect, whereas 7 μM NO-PAW could induce 18% apoptotic effect. In addition, we assumed that both DBD plasma and NO-PAW could induce HeLa cell apoptosis by facilitating an accumulation of intracellular reactive oxygen and nitrogen species (RONS). Although further detail on the molecular signal pathway is still needed, DBD and NO-PAW could become promising applications for effective and safe clinical trials for cancer therapy.

  13. Effects of atmospheric-pressure non-thermal bio-compatible plasma and plasma activated nitric oxide water on cervical cancer cells

    Science.gov (United States)

    Li, Ying; Ho Kang, Min; Sup Uhm, Han; Joon Lee, Geon; Ha Choi, Eun; Han, Ihn

    2017-01-01

    Atmospheric-pressure non-thermal bio-compatible plasma is a partially ionized gas with electrically charged particles. Previous studies demonstrated that dielectric barrier discharge (DBD) plasma could induce apoptosis of various cancer cells, in particular demonstrating the selective cytotoxicity of cancer cells over normal cells. Therefore, DBD plasma can be considered as a potential cancer treatment method for clinical applications. We previously developed a microwave jet plasma system, producing nitric oxide called nitric oxide-plasma activated water (NO-PAW). In this study, we explored the effects of NO-PAW on a cervical cancer cell line, in comparison with DBD plasma. The cytotoxicity results showed that the treatment of HeLa cell with DBD for 4 minutes and 7 μM concentration of NO-PAW could reach almost IC60. For the apoptosis assay, 4 minutes treatment of DBD could induce 7% apoptotic effect, whereas 7 μM NO-PAW could induce 18% apoptotic effect. In addition, we assumed that both DBD plasma and NO-PAW could induce HeLa cell apoptosis by facilitating an accumulation of intracellular reactive oxygen and nitrogen species (RONS). Although further detail on the molecular signal pathway is still needed, DBD and NO-PAW could become promising applications for effective and safe clinical trials for cancer therapy. PMID:28361987

  14. Effects of non-thermal plasmas and electric field on hydrocarbon/air flames

    Science.gov (United States)

    Ganguly, Biswa

    2009-10-01

    Need to improve fuel efficiency, and reduce emission from hydrocarbon combustor in automotive and gas turbine engines have reinvigorated interest in reducing combustion instability of a lean flame. The heat generation rate in a binary reaction is HQ =N^2 c1c2 Q exp(-E/RT), where N is the density, c1 and c2 are mol fractions of the reactants, Q is the reaction heat release, E is the activation energy, R is the gas constant and T is the average temperature. For hydrocarbon-air reactions, the typical value of E/R ˜20, so most heat release reactions are confined to a thin reaction sheet at T >=1400 K. The lean flame burning condition is susceptible to combustion instability due to a critical balance between heat generation and heat loss rates, especially at high gas flow rate. Radical injection can increase flame speed by reducing the hydrocarbon oxidation reaction activation barrier and it can improve flame stability. Advances in nonequilibrium plasma generation at high pressure have prompted its application for energy efficient radical production to enhance hydrocarbon-air combustion. Dielectric barrier discharges and short pulse excited corona discharges have been used to enhance combustion stability. Direct electron impact dissociation of hydrocarbon and O2 produces radicals with lower fuel oxidation reaction activation barriers, initiating heat release reaction CnHm+O CnHm-1+ OH (and other similar sets of reactions with partially dissociated fuel) below the typical cross-over temperature. Also, N2 (A) produced in air discharge at a moderate E/n can dissociate O2 leading to oxidation of fuel at lower gas temperature. Low activation energy reactions are also possible by dissociation of hydrocarbon CnHm+e -> CnHm-2+H2+e, where a chain propagation reaction H2+ O OH+H can be initiated at lower gas temperature than possible under thermal equilibrium kinetics. Most of heat release comes from the reaction CO+OH-> CO2 +H, nonthermal OH production seem to improve

  15. The plasma scalpel: a new thermal knife.

    Science.gov (United States)

    Glover, J L; Bendick, P J; Link, W J; Plunkett, R J

    1982-01-01

    A new thermal knife, the plasma scalpel, capable of simultaneous division of tissue and coagulation of blood vessels, is described. A high temperature argon gas plasma (unrelated to blood plasma) is created by passing the gas through a direct current arc, ionizing the gas and elevating its temperature to 3000 degrees C. A small plasma cutting jet is formed by a nozzle at the tip of the handpiece. Liver resections and muscle transections performed in a canine model, and full thickness burn excisions in a pig skin model showed effective division of tissue and significantly less blood loss when compared to the steel scalpel. Wound healing studies of histologic comparisons and wound breaking strength were performed for steel, plasma, laser, and electrosurgical scalped incisions in the skin of mice and rats. All thermal knife wounds showed localized tissue damage at the edges of the incision, but the events of healing began at the same time. Compared to the steel scalpel, there was a three to six day delay in the onset of healing, but healing occurred in the normal fashion and all thermal knife wounds reached the same healed breaking strength as the steel scalpel wounds. Clinically, the plasma scalped has been used for 138 procedures in 96 patients. The majority of cases have been transection of muscle, hepatic resection or debridement, or soft tissue debridement. Muscle transection data for the plasma scalped compared to the electrosurgical scalpel has shown virtually no blood loss with a shorter time to hemostasis for the plasma scalpel. The plasma scalpel has proved to be an effective thermal knife, capable of simultaneous division and coagulation. Further development work and proof of its efficacy in the clinical setting are necessary to establish the plasma scalpel and adequately demonstrate its proper role in surgery.

  16. Thermal plasmas: fundamental aspects; Plasmas thermiques: aspects fondamentaux

    Energy Technology Data Exchange (ETDEWEB)

    Fauchais, P. [Limoges Univ. Faculte des Sciences, Lab. Science des Procedes Ceramiques et Traitements de Surface (SPCTS-UMR-6638-CNRS), 87 (France)

    2005-10-01

    This article treats of thermal plasmas, i.e. mainly produced by electric arcs and RF discharges. Their main characteristic is that they are generated at a pressure close to the atmospheric pressure (between 10{sup 4} and 10{sup 6} Pa) and refer to the classical kinetics of the Boltzmann equation. Because of the pressure, the collisions between particles are numerous and ionization is mainly due to a thermal effect. They correspond to electron densities between 10{sup 20} and 10{sup 24} m{sup -3} and temperatures between 6000 and 25000 K. In these plasmas, the electric fields and the average free trajectories are too weak to generate a ionization state by direct inelastic collision. Ionization is thus essentially a thermal phenomenon due to elastic collisions. This article presents: 1 - the particles present in a plasma: definition, energy states; 2 - characteristic data: collisions, average free path and collision cross-section, distribution function, ionization types, charged particles mobility inside an electric field, scattering, Debye length; 3 - plasmas at the thermodynamical equilibrium: conditions of equilibrium, calculation of composition, thermodynamic properties, transport properties, radiation; 4 - thermal plasmas away from equilibrium: conditions of non-equilibrium, calculation of plasma composition, calculation of transport properties, quenching phenomenon. (J.S.)

  17. Bactericial effect of a non-thermal plasma needle against Enterococcus faecalis biofilms

    Science.gov (United States)

    Jiang, Chunqi; Schaudinn, C.; Jaramillo, D. E.; Sedghizadeh, P. P.; Webster, P.; Costerton, J. W.

    2011-10-01

    Up to 3 cm long submillimeter-in-scale plasma needle was generated in ambient atmosphere for root canal disinfection. Powered with 1-2 kHz, multi-kilovolt nanosecond electric pulses, this He/(1%)O2 plasma jet consists of ionization fronts propagating at speeds of the order of 107 cm/s. Plasma treatment of Enterococcus faecalis biofilms on hydroxyapatite (HA) discs for 5 min resulted in severe damage of the bacterial cells and sterilized HA surfaces of more than 3 mm in diameter, observed by the scanning electron microscopy. With a curing dielectric microtube placed 1 cm or less below the nozzle, the plasma jet entered even at a sharp angle and followed the curvature of the tube, and reached the bottom of the tube. The bactericidal effect of the plasma needle against E. faecalis biofilm grown on the inner surfaces of the tube was demonstrated. However, the bactericidal effect weakens or diminishes for the bacteria grown deeper in the tube, indicating improvement of the plasma treatment scheme is needed. Mechanisms of the plasma bactericidal effects are discussed. Supported by the National Institute of Dental and Craniofacial Research and the Air Force Office of Scientific Research.

  18. Effects of non-thermal plasma on the electrical properties of an erythrocyte membrane

    Science.gov (United States)

    Lee, Jin Young; Baik, Ku Youn; Kim, Tae Soo; Lim, Jaekwan; Uhm, Han S.; Choi, Eun Ha

    2015-09-01

    Non-thermal plasma is used here for membrane oxidation and permeabilization in which the electrical properties of an erythrocyte membrane are investigated after treatments. The zeta potential as measured by electrophoresis shows the increased negativity of the membrane surface potential (Ψs). The secondary electron emission coefficient ( γ) measured by a focused ion beam shows a decrease in the dipole potential (Ψd) of lipid molecules. The voltage-sensitive fluorescent intensity as measured by flow cytometry shows a decrease in the trans-membrane potential (ΔΨ) through the lipid bilayer membrane. These results allow us to take a step forward to unveil the complex events occurring in plasma-treated cells.

  19. The effect of electron thermal conduction on plasma pressure gradient during reconnection of magnetic field lines

    Energy Technology Data Exchange (ETDEWEB)

    Chu, T.K.

    1987-12-01

    The interplay of electron cross-field thermal conduction and the reconnection of magnetic field lines around an m = 1 magnetic island prior to a sawtooth crash can generate a large pressure gradient in a boundary layer adjacent to the reconnecting surface, leading to an enhanced gradient of poloidal beta to satisfy the threshold condition for ideal MHD modes. This narrow boundary layer and the short onset time of a sawtooth crash can be supported by fine-grained turbulent processes in a tokamak plasma. 11 refs.

  20. THE EFFECT OF LASER GLAZING PROCESS ON MICROSTRUCTURE OF PLASMA SPRAYED THERMAL BARRIER COATINGS

    Directory of Open Access Journals (Sweden)

    Seyid Fehmi DİLTEMİZ

    2011-12-01

    Full Text Available Thermal barrier coatings (TBCs are widely used by aero and land based gas turbines to protect hot section parts from oxidation and reducing component temperature thereby increase life. TBCs aregenerally a combination of multiple layers of coating (usually two with each layer having a specific function [Aktaa et al., 2005]. In this study air plasma sprayed TBCs were deposited on 304 stainlesssteel substrates then ceramic surfaces were glazed using Nd-YAG laser. Both glazed and as-coated samples were subjected to metallographic examination to investigate microstructural changes inglazed ceramic layer. Laser glazing provides a remelting and subsequent solidification of the surface, resulting on new top layer microstructure.

  1. Effect of non-thermal air atmospheric pressure plasma jet treatment on gingival wound healing

    Science.gov (United States)

    Lee, Jung-Hwan; Choi, Eun-Ha; Kim, Kwang-Mahn; Kim, Kyoung-Nam

    2016-02-01

    Non-thermal atmospheric pressure plasmas have been applied in the biomedical field for the improvement of various cellular activities. In dentistry, the healing of gingival soft tissue plays an important role in health and aesthetic outcomes. While the biomedical application of plasma has been thoroughly studied in dentistry, a detailed investigation of plasma-mediated human gingival fibroblast (HGF) migration for wound healing and its underlying biological mechanism is still pending. Therefore, the aim of this study is to apply a non-thermal air atmospheric pressure plasma jet (NTAAPPJ) to HGF to measure the migration and to reveal the underlying biological mechanisms involved in the migration. After the characterization of NTAAPPJ by optical emission spectroscopy, the adherent HGF was treated with NTAAPPJ or air with a different flow rate. Cell viability, lipid peroxidation, migration, intracellular reactive oxygen species (ROS), and the expression of migration-related genes (EGFR, PAK1, and MAPK3) were investigated. The level of statistical significance was set at 0.05. NTAAPPJ and air treatment with a flow rate of 250-1000 standard cubic centimetres per minute (sccm) for up to 30 s did not induce significant decreases in cell viability or membrane damage. A significant increase in the migration of mitomycin C-treated HGF was observed after 30 s of NTAAPPJ treatment compared to 30 s air-only treatment, which was induced by high levels of intracellular reactive oxygen species (ROS). An increase in migration-related gene expression and EGFR activation was observed following NTAAPPJ treatment in an air flow rate-dependent manner. This is the first report that NTAAPPJ treatment induces an increase in HGF migration without changing cell viability or causing membrane damage. HGF migration was related to an increase in intracellular ROS, changes in the expression of three of the migration-related genes (EGFR, PAK1, and MAPK1), and EGFR activation. Therefore

  2. Therapeutic Non Thermal Plasma, Significance and Challenges

    Directory of Open Access Journals (Sweden)

    Wameath Sh. Abdul-Majeed

    2014-06-01

    Full Text Available Plasma is an electrically neutral, highly ionized gas that consists of several species (electrons, ions, reactive species, and UV light and classified into localized thermal equilibrium (LTE plasmas and non-localized thermal equilibrium (n-LTE plasmas. In LTE plasmas, the electron temperature exists in equilibrium with the gas temperature. In contrast, the electron temperature in (n- LTE plasmas can reach temperatures of 1-10 (eV while the gas temperature is kept as low as room temperature, which makes it useful for a wide range of industrial applications (e.g. ozone generation, surface treatment, .., etc. In the past decade, non thermal (cold atmospheric pressure plasmas were developed and emerged as a promising new tool for medical applications as it’s proved to be more selective in its application (e.g. selective killing of microbes. Accordingly, developments of cold atmospheric plasma devices led to the possibility to apply plasma species to heat-sensitive surfaces (e.g. human skin with precise tuning, controllability and without damage of surrounding tissue. On this basis, medical plasma proved effective for skin sterilization, wound healing and tissue regeneration, cancer treatment, malignant cell apoptosis and blood coagulation. Moreover, cold plasma is known to inactivate a wide range of pathogens such as bacteria, viruses, fungi, spores and biofilms. Therefore it has been considered a very efficient alternative to superficially applied antibiotics or disinfectants. It’s worth noting that histological evaluation for the skin treated with atmospheric cold plasma showed that no morphological changes and no significant degree of necrosis or apoptosis were detectable after plasma treatment. Other studies denoted that a limited increase in the number of DNA double-strand breaks was observed in plasma-treated excised human skin. However, varieties of a new generation handheld and battery-operated devices makes it difficult to interpret the

  3. Extension of operational regime in high-temperature plasmas and effect of ECRH on ion thermal transport in the LHD

    Science.gov (United States)

    Takahashi, H.; Nagaoka, K.; Murakami, S.; Osakabe, M.; Nakano, H.; Ida, K.; Tsujimura, T. I.; Kubo, S.; Kobayashi, T.; Tanaka, K.; Seki, R.; Takeiri, Y.; Yokoyama, M.; Maeta, S.; Nakata, M.; Yoshinuma, M.; Yamada, I.; Yasuhara, R.; Ido, T.; Shimizu, A.; Tsuchiya, H.; Tokuzawa, T.; Goto, M.; Oishi, T.; Morita, S.; Suzuki, C.; Emoto, M.; Tsumori, K.; Ikeda, K.; Kisaki, M.; Shimozuma, T.; Yoshimura, Y.; Igami, H.; Makino, R.; Seki, T.; Kasahara, H.; Saito, K.; Kamio, S.; Nagasaki, K.; Mutoh, T.; Kaneko, O.; Morisaki, T.; the LHD Experiment Group

    2017-08-01

    A simultaneous high ion temperature (T i) and high electron temperature (T e) regime was successfully extended due to an optimized heating scenario in the LHD. Such high-temperature plasmas were realized by the simultaneous formation of an electron internal transport barrier (ITB) and an ion ITB by the combination of high power NBI and ECRH. Although the ion thermal confinement was degraded in the plasma core with an increase of T e/T i by the on-axis ECRH, it was found that the ion thermal confinement was improved at the plasma edge. The normalized ion thermal diffusivity {χ\\text{i}}/T\\text{i}1.5 at the plasma edge was reduced by 70%. The improvement of the ion thermal confinement at the edge led to an increase in T i in the entire plasma region, even though the core transport was degraded.

  4. Effect of photodynamic therapy and non-thermal plasma on root canal filling: analysis of adhesion and sealer penetration

    OpenAIRE

    MENEZES,Marilia; PRADO,Maíra; Gomes,Brenda; Gusman, Heloisa; SIMÃO,Renata

    2017-01-01

    Abstract Objective The aim of this study was to evaluate the effect of photodynamic therapy (PDT) and non-thermal plasma (NTP) on adhesion and sealer penetration in root canals. Material and Methods Sixty single-rooted premolars were used. The teeth were prepared using a crown-down technique. NaOCl and EDTA were used for irrigation and smear layer removal, respectively. The root canals were divided into three groups: control, PDT, and NTP. After treatments, the roots were filled using gut...

  5. Disinfection effect of non-thermal atmospheric pressure plasma for foodborne bacteria

    Science.gov (United States)

    Pervez, Mohammad Rasel; Inomata, Takanori; Ishijima, Tatsuo; Kakikawa, Makiko; Uesugi, Yoshihiko; Tanaka, Yasunori; Yano, Toshihiro; Miwa, Shoji; Noguchi, Akinori

    2015-09-01

    Non-thermal atmospheric pressure plasma (NAPP) exposure can be a suitable alternative for bacteria inactivation in food processing industry. Specimen placed in the enclosure are exposed to various reactive radicals produced within the discharge chamber. It is also exposed to the periodic variation of the electric field strength in the chamber. Dielectric barrier discharge is produced by high voltage pulse (Vpp = 18 kV, pulse width 20 μs, repetition frequency 10 kHz) in a polypropylene box (volume = 350 cm3) using helium as main feed gas. Inactivation efficiency of NAPP depends on the duration of NAPP exposure, applied voltage pulse strength and type, pulse duration, electrode separation and feed gas composition. In this study we have investigated inactivation of Bacillus lichenformis spore as an example of food borne bacteria. Keeping applied voltage, electrode configuration and total gas flow rate constant, spores are exposed to direct NAPP for different time duration while O2 concentration in the feed gas composition is varied. 10 minutes NAPP exposure resulted in ~ 3 log reduction of Bacillus lichenformis spores for 1% O2concentration (initial concentration ~ 106 / specimen). This work is supported by research and development promotion grant provided by the Hokuriku Industrial Advancement Center.

  6. Expanding Thermal Plasma Deposition of Al-Doped ZnO: On the Effect of the Plasma Chemistry on Film Growth Mechanisms

    NARCIS (Netherlands)

    Williams, B. L.; Ponomarev, M. V.; Verheijen, M. A.; Knoops, H. C. M.; Chandramohan, A.; Duval, L.; van de Sanden, M. C. M.; Creatore, M.

    2016-01-01

    This work presents a review of expanding thermal plasma – chemical vapour deposition (ETP-CVD) of Al-doped ZnOtransparent conducting oxides (TCOs), alongside new results providing insights into the role of the plasma chemistry on film microstructure. Standard growth conditions generate high

  7. Expanding Thermal Plasma Deposition of Al-Doped ZnO: On the Effect of the Plasma Chemistry on Film Growth Mechanisms

    NARCIS (Netherlands)

    Williams, B. L.; Ponomarev, M. V.; Verheijen, M. A.; Knoops, H. C. M.; Chandramohan, A.; Duval, L.; van de Sanden, M. C. M.; Creatore, M.

    2016-01-01

    This work presents a review of expanding thermal plasma – chemical vapour deposition (ETP-CVD) of Al-doped ZnOtransparent conducting oxides (TCOs), alongside new results providing insights into the role of the plasma chemistry on film microstructure. Standard growth conditions generate high resistiv

  8. Initial thermal plasma observations from ISEE-1

    Science.gov (United States)

    Baugher, C. R.; Chappell, C. R.; Horwitz, J. L.; Shelley, E. G.; Young, D. T.

    1980-09-01

    The initial measurements of magnetospheric thermal ions by the Plasma Composition Experiment on ISEE-1 are presented to demonstrate the surprising variety in this plasma population. The data provide evidence that the adiabatic mapping of the high latitude ionosphere to the equatorial plasma trough provides an insufficient description of the origin, transport, and accumulation processes which supply low energy ions to the outer plasmasphere and plasma trough.

  9. Thermal conductivity of tungsten: Effects of plasma-related structural defects from molecular-dynamics simulations

    Science.gov (United States)

    Hu, Lin; Wirth, Brian D.; Maroudas, Dimitrios

    2017-08-01

    We report results on the lattice thermal conductivities of tungsten single crystals containing nanoscale-sized pores or voids and helium (He) nanobubbles as a function of void/bubble size and gas pressure in the He bubbles based on molecular-dynamics simulations. For reference, we calculated lattice thermal conductivities of perfect tungsten single crystals along different crystallographic directions at room temperature and found them to be about 10% of the overall thermal conductivity of tungsten with a weak dependence on the heat flux direction. The presence of nanoscale voids in the crystal causes a significant reduction in its lattice thermal conductivity, which decreases with increasing void size. Filling the voids with He to form He nanobubbles and increasing the bubble pressure leads to further significant reduction of the tungsten lattice thermal conductivity, down to ˜20% of that of the perfect crystal. The anisotropy in heat conduction remains weak for tungsten single crystals containing nanoscale-sized voids and He nanobubbles throughout the pressure range examined. Analysis of the pressure and atomic displacement fields in the crystalline region that surrounds the He nanobubbles reveals that the significant reduction of tungsten lattice thermal conductivity in this region is due to phonon scattering from the nanobubbles, as well as lattice deformation around the nanobubbles and formation of lattice imperfections at higher bubble pressure.

  10. Effect of a non-thermal, atmospheric-pressure, plasma brush on conversion of model self-etch adhesive formulations compared to conventional photo-polymerization

    Science.gov (United States)

    Chen, Mingsheng; Zhang, Ying; Yao, Xiaomei; Li, Hao; Yu, Qingsong; Wang, Yong

    2012-01-01

    Objective To determine the effectiveness and efficiency of non-thermal, atmospheric plasmas for inducing polymerization of model dental self-etch adhesives. Methods The monomer mixtures used were bis-[2-(methacryloyloxy)ethyl] phosphate (2MP) and 2-hydroxyethyl methacrylate (HEMA), with mass ratios of 70/30, 50/50 and 30/70. Water was added to the above formulations: 10–30 wt%. These monomer/water mixtures were treated steadily for 40 s under a non-thermal atmospheric plasma brush working at temperatures from 32° to 35°C. For comparison, photo-initiators were added to the above formulations for photo-polymerization studies, which were light-cured for 40 s. The degree of conversion (DC) of both the plasma- and light-cured samples was measured using FTIR spectroscopy with an attenuated total reflectance attachment. Results The non-thermal plasma brush was effective in inducing polymerization of the model self-etch adhesives. The presence of water did not negatively affect the DC of plasma-cured samples. Indeed, DC values slightly increased, with increasing water content in adhesives: from 58.3% to 68.7% when the water content increased from 10% to 30% in the adhesives with a 50/50 (2MP/HEMA) mass ratio. Conversion values of the plasma-cured groups were higher than those of light-cured samples with the same mass ratio and water content. Spectral differences between the plasma- and light-cured groups indicate subtle structural distinctions in the resultant polymer networks. Significance This research if the first to demonstrate that the non-thermal plasma brush induces polymerization of model adhesives under clinical settings by direct/indirect energy transfer. This device shows promise for polymerization of dental composite restorations having enhanced properties and performance. PMID:23018084

  11. Mixed Mode Fracture of Plasma Sprayed Thermal Barrier Coatings: Effects of Anisotropy and Heterogeneity

    Science.gov (United States)

    Zhu, Dongming; Choi, Sung R.; Ghosn, Louis L.

    2008-01-01

    The combined mode I-mode II fracture behavior of anisotropic ZrO2-8wt%Y2O3 thermal barrier coatings was determined in asymmetric flexure loading at both ambient and elevated temperatures. A fracture envelope of KI versus KII was determined for the coating material at ambient and elevated temperatures. Propagation angles of fracture as a function of KI/KII were also determined. The mixed-mode fracture behavior of the microsplat coating material was modeled using Finite Element approach to account for anisotropy and micro cracked structures, and predicted in terms of fracture envelope and propagation angle using mixed-mode fracture theories.

  12. Synthesis of functional nanocrystallites through reactive thermal plasma processing

    Directory of Open Access Journals (Sweden)

    Takamasa Ishigaki and Ji-Guang Li

    2007-01-01

    Full Text Available A method of synthesizing functional nanostructured powders through reactive thermal plasma processing has been developed. The synthesis of nanosized titanium oxide powders was performed by the oxidation of solid and liquid precursors. Quench gases, either injected from the shoulder of the reactor or injected counter to the plasma plume from the bottom of the reactor, were used to vary the quench rate, and therefore the particle size, of the resultant powders. The experimental results are well supported by numerical analysis on the effects of the quench gas on the flow pattern and temperature field of the thermal plasma as well as on the trajectory and temperature history of the particles. The plasma-synthesized TiO2 nanoparticles showed phase preferences different from those synthesized by conventional wet-chemical processes. Nanosized particles of high crystallinity and nonequilibrium chemical composition were formed in one step via reactive thermal plasma processing.

  13. Turbulence modelling of thermal plasma flows

    Science.gov (United States)

    Shigeta, Masaya

    2016-12-01

    This article presents a discussion of the ideas for modelling turbulent thermal plasma flows, reviewing the challenges, efforts, and state-of-the-art simulations. Demonstrative simulations are also performed to present the importance of numerical methods as well as physical models to express turbulent features. A large eddy simulation has been applied to turbulent thermal plasma flows to treat time-dependent and 3D motions of multi-scale eddies. Sub-grid scale models to be used should be able to express not only turbulent but also laminar states because both states co-exist in and around thermal plasmas which have large variations of density as well as transport properties under low Mach-number conditions. Suitable solution algorithms and differencing schemes must be chosen and combined appropriately to capture multi-scale eddies and steep gradients of temperature and chemical species, which are turbulent features of thermal plasma flows with locally variable Reynolds and Mach numbers. Several simulations using different methods under different conditions show commonly that high-temperature plasma regions exhibit less turbulent structures, with only large eddies, whereas low-temperature regions tend to be more turbulent, with numerous small eddies. These numerical results agree with both theoretical insight and photographs that show the characteristics of eddies. Results also show that a turbulence transition of a thermal plasma jet through a generation-breakup process of eddies in a torch is dominated by fluid dynamic instability after ejection rather than non-uniform or unsteady phenomena.

  14. Stability of thermal modes in cool prominence plasmas

    CERN Document Server

    Soler, Roberto; Parenti, Susanna

    2012-01-01

    Context: Magnetohydrodynamic thermal modes may play an important role in the formation, plasma condensation, and evolution of solar prominences. Unstable thermal modes due to unbalance between radiative losses and heating can lead to rapid plasma cooling and condensation. An accurate description of the radiative loss function is therefore crucial for this process. Aims: We study the stability of thermal modes in unbounded and uniform plasmas with properties akin to those in solar prominences. Effects due to partial ionization are taken into account. Three different parametrizations of the radiative loss function are used. Methods: By means of a normal mode analysis, we investigate linear nonadiabatic perturbations superimposed on the equilibrium state. We find an approximate instability criterion for thermal modes, while the exact linear growth rate is obtained by numerically solving the general dispersion relation. The stability of thermal disturbances is compared for the three different loss functions consi...

  15. Effect of Processing Conditions on the Anelastic Behavior of Plasma Sprayed Thermal Barrier Coatings

    Science.gov (United States)

    Viswanathan, Vaishak

    2011-12-01

    Plasma sprayed ceramic materials contain an assortment of micro-structural defects, including pores, cracks, and interfaces arising from the droplet based assemblage of the spray deposition technique. The defective architecture of the deposits introduces a novel "anelastic" response in the coatings comprising of their non-linear and hysteretic stress-strain relationship under mechanical loading. It has been established that this anelasticity can be attributed to the relative movement of the embedded defects under varying stresses. While the non-linear response of the coatings arises from the opening/closure of defects, hysteresis is produced by the frictional sliding among defect surfaces. Recent studies have indicated that anelastic behavior of coatings can be a unique descriptor of their mechanical behavior and related to the defect configuration. In this dissertation, a multi-variable study employing systematic processing strategies was conducted to augment the understanding on various aspects of the reported anelastic behavior. A bi-layer curvature measurement technique was adapted to measure the anelastic properties of plasma sprayed ceramic. The quantification of anelastic parameters was done using a non-linear model proposed by Nakamura et.al. An error analysis was conducted on the technique to know the available margins for both experimental as well as computational errors. The error analysis was extended to evaluate its sensitivity towards different coating microstructure. For this purpose, three coatings with significantly different microstructures were fabricated via tuning of process parameters. Later the three coatings were also subjected to different strain ranges systematically, in order to understand the origin and evolution of anelasticity on different microstructures. The last segment of this thesis attempts to capture the intricacies on the processing front and tries to evaluate and establish a correlation between them and the anelastic

  16. Effects of deposition parameters on microstructure and thermal conductivity of diamond films deposited by DC arc plasma jet chemical vapor deposition

    Institute of Scientific and Technical Information of China (English)

    QU Quan-yan; QIU Wan-qi; ZENG De-chang; LIU Zhong-wu; DAI Ming-jiang; ZHOU Ke-song

    2009-01-01

    The uniform diamond films with 60 mm in diameter were deposited by improved DC arc plasma jet chemical vapor deposition technique. The structure of the film was characterized by scanning electronic microcopy(SEM) and laser Raman spectrometry. The thermal conductivity was measured by a photo thermal deflection technique. The effects of main deposition parameters on microstructure and thermal conductivity of the films were investigated. The results show that high thermal conductivity, 10.0 W/(K-cm), can be obtained at a CH4 concentration of 1.5% (volume fraction) and the substrate temperatures of 880-920 ℃ due to the high density and high purity of the film. A low pressure difference between nozzle and vacuum chamber is also beneficial to the high thermal conductivity.

  17. Effect of Gd2O3 on the microstructure and thermal properties of nanostructured thermal barrier coatings fabricated by air plasma spraying

    Institute of Scientific and Technical Information of China (English)

    Yixiong Wang; Chungen Zhou

    2016-01-01

    The nanostructured 4–8 mol% Gd2O3-4.5 mol% Y2O3-ZrO2 (4–8 mol% GdYSZ) coatings were developed by the atmospheric plasma spraying technique. The microstructure and thermal properties of plasma-sprayed 4–8 mol%GdYSZ coatings were investigated. The experimental results indicate that typical mi-crostructure of the as-sprayed coatings were consisted of melted zones, nano-zones, splats, nano-pores, high-volume spheroidal pores and micro-cracks. The porosity of the 4, 6 and 8 mol%GdYSZ coatings was about 9.3%, 11.7%and 13.3%, respectively. It was observed that the addition of gadolinia to the nano-YSZ could significantly reduce the thermal conductivity of nano-YSZ. The thermal conductivity of GdYSZ decreased with increasing Gd2O3 addition. And the reduction in thermal conductivity is mainly attrib-uted to the addition of Gd2O3, which results in the increase in oxygen vacancies, lattice distortion and porosity.

  18. Effect of Gd2O3 on the microstructure and thermal properties of nanostructured thermal barrier coatings fabricated by air plasma spraying

    Directory of Open Access Journals (Sweden)

    Yixiong Wang

    2016-08-01

    Full Text Available The nanostructured 4–8 mol% Gd2O3−4.5 mol% Y2O3-ZrO2 (4–8 mol% GdYSZ coatings were developed by the atmospheric plasma spraying technique. The microstructure and thermal properties of plasma-sprayed 4–8 mol% GdYSZ coatings were investigated. The experimental results indicate that typical microstructure of the as-sprayed coatings were consisted of melted zones, nano-zones, splats, nano-pores, high-volume spheroidal pores and micro-cracks. The porosity of the 4, 6 and 8 mol% GdYSZ coatings was about 9.3%, 11.7% and 13.3%, respectively. It was observed that the addition of gadolinia to the nano-YSZ could significantly reduce the thermal conductivity of nano-YSZ. The thermal conductivity of GdYSZ decreased with increasing Gd2O3 addition. And the reduction in thermal conductivity is mainly attributed to the addition of Gd2O3, which results in the increase in oxygen vacancies, lattice distortion and porosity.

  19. Non-thermal plasma mills bacteria: Scanning electron microscopy observations

    Energy Technology Data Exchange (ETDEWEB)

    Lunov, O., E-mail: lunov@fzu.cz; Churpita, O.; Zablotskii, V.; Jäger, A.; Dejneka, A. [Institute of Physics AS CR, Prague 18221 (Czech Republic); Deyneka, I. G.; Meshkovskii, I. K. [St. Petersburg State University of Information Technologies, Mechanics and Optics, St. Petersburg 197101 (Russian Federation); Syková, E. [Institute of Experimental Medicine AS CR, Prague 14220 (Czech Republic); Kubinová, Š. [Institute of Physics AS CR, Prague 18221 (Czech Republic); Institute of Experimental Medicine AS CR, Prague 14220 (Czech Republic)

    2015-02-02

    Non-thermal plasmas hold great promise for a variety of biomedical applications. To ensure safe clinical application of plasma, a rigorous analysis of plasma-induced effects on cell functions is required. Yet mechanisms of bacteria deactivation by non-thermal plasma remain largely unknown. We therefore analyzed the influence of low-temperature atmospheric plasma on Gram-positive and Gram-negative bacteria. Using scanning electron microscopy, we demonstrate that both Gram-positive and Gram-negative bacteria strains in a minute were completely destroyed by helium plasma. In contrast, mesenchymal stem cells (MSCs) were not affected by the same treatment. Furthermore, histopathological analysis of hematoxylin and eosin–stained rat skin sections from plasma–treated animals did not reveal any abnormalities in comparison to control ones. We discuss possible physical mechanisms leading to the shred of bacteria under non-thermal plasma irradiation. Our findings disclose how helium plasma destroys bacteria and demonstrates the safe use of plasma treatment for MSCs and skin cells, highlighting the favorability of plasma applications for chronic wound therapy.

  20. Energy deposition and thermal effects of runaway electrons in ITER-FEAT plasma facing components

    Energy Technology Data Exchange (ETDEWEB)

    Maddaluno, G. E-mail: maddaluno@frascati.enea.it; Maruccia, G.; Merola, M.; Rollet, S

    2003-03-01

    The profile of energy deposited by runaway electrons (RAEs) of 10 or 50 MeV in International Thermonuclear Experimental Reactor-Fusion Energy Advanced Tokamak (ITER-FEAT) plasma facing components (PFCs) and the subsequent temperature pattern have been calculated by using the Monte Carlo code FLUKA and the finite element heat conduction code ANSYS. The RAE energy deposition density was assumed to be 50 MJ/m{sup 2} and both 10 and 100 ms deposition times were considered. Five different configurations of PFCs were investigated: primary first wall armoured with Be, with and without protecting CFC poloidal limiters, both port limiter first wall options (Be flat tile and CFC monoblock), divertor baffle first wall, armoured with W. The analysis has outlined that for all the configurations but one (port limiter with Be flat tile) the heat sink and the cooling tube beneath the armour are well protected for both RAE energies and for both energy deposition times. On the other hand large melting (W, Be) or sublimation (C) of the surface layer occurs, eventually affecting the PFCs lifetime.

  1. Plasma Treatment of Agave Fiber Powder and Its Effect on the Mechanical and Thermal Properties of Composites Based on Polyethylene

    Directory of Open Access Journals (Sweden)

    Florentino Soriano Corral

    2016-01-01

    Full Text Available Composites based on low-density polyethylene (LDPE were prepared with Agave fiber powder (AFP that was coated by plasma polymerization process using ethylene gas. Treated and pristine AFP were analyzed by infrared spectroscopy, scanning electron microscopy, and contact water angle for the assessment of surface properties. The polymer composites were prepared by melt mixing using 0, 5, 10, and 20 wt% of AFP and their mechanical and thermal properties were measured. Dispersion evaluation in water confirmed that the AFP treated changed from hydrophilic to hydrophobic behavior and it was also corroborated with water contact angle tests. The addition of treated and untreated AFP (200 mesh at 20 wt% promotes an increase of Young’s modulus of the composites of up to 60% and 32%, respectively, in relation to the neat matrix. Also, an increase of crystallinity of LDPE was observed by the addition of treated and untreated AFP; however no significant effect on the crystallization temperature was observed in LDPE containing AFP.

  2. Analytical method for thermal stress analysis of plasma facing materials

    Science.gov (United States)

    You, J. H.; Bolt, H.

    2001-10-01

    The thermo-mechanical response of plasma facing materials (PFMs) to heat loads from the fusion plasma is one of the crucial issues in fusion technology. In this work, a fully analytical description of the thermal stress distribution in armour tiles of plasma facing components is presented which is expected to occur under typical high heat flux (HHF) loads. The method of stress superposition is applied considering the temperature gradient and thermal expansion mismatch. Several combinations of PFMs and heat sink metals are analysed and compared. In the framework of the present theoretical model, plastic flow and the effect of residual stress can be quantitatively assessed. Possible failure features are discussed.

  3. The effect of non-thermal electrons on obliquely propagating electron acoustic waves in a magnetized plasma

    Science.gov (United States)

    Singh, Satyavir; Bharuthram, Ramashwar

    2016-07-01

    Small amplitude electron acoustic solitary waves are studied in a magnetized plasma consisting of hot electrons following Cairn's type non-thermal distribution function and fluid cool electrons, cool ions and an electron beam. Using reductive perturbation technique, the Korteweg-de-Vries-Zakharov-Kuznetsov (KdV-ZK) equation is derived to describe the nonlinear evolution of electron acoustic waves. It is observed that the presence of non-thermal electrons plays an important role in determining the existence region of solitary wave structures. Theoretical results of this work is used to model the electrostatic solitary structures observed by Viking satellite. Detailed investigation of physical parameters such as non-thermality of hot electrons, beam electron velocity and temperature, obliquity on the existence regime of solitons will be discussed.

  4. Biphasic effects of l-ascorbate on the tumoricidal activity of non-thermal plasma against malignant mesothelioma cells.

    Science.gov (United States)

    Shi, Lei; Wang, Yue; Ito, Fumiya; Okazaki, Yasumasa; Tanaka, Hiromasa; Mizuno, Masaaki; Hori, Masaru; Richardson, Des R; Toyokuni, Shinya

    2016-09-01

    Non-thermal plasma (NTP) is a recently developed technology that elicits a variety of biological effects. This includes cancer cell-specific cytotoxicity, which is mainly attributed to the regional generation of reactive oxygen species (ROS). We studied the effects of NTP on malignant mesothelioma (MM) and its modulation by l-ascorbate. l-ascorbate is a major water-soluble anti-oxidant in vivo, but its pro-oxidant activity in vitro has been well recognized. Thus, the effects of ascorbate on the efficacy of NTP is important to examine. NTP exposure dose-dependently killed MM cells, whereas MM cells tolerated 1 mM l-ascorbate. However, brief pre-treatment with a pharmacological dose (250-750 μM) of l-ascorbate immediately prior to NTP exposure significantly increased its cytotoxicity in a dose-dependent manner, which was inhibited by the iron chelator, deferoxamine. However, paradoxically, this potentiating effect of l-ascorbate was completely abolished by a prolonged 4 h pre-incubation with l-ascorbate (500 μM). MM cytotoxicity induced by NTP was associated with immediate oxidative stress evaluated by 2',7'-dichlorodihydrofluorecein diacetate, which was followed by an increase in the expression of the autophagosome marker, LC3B-II. In conclusion, MM can be a target for NTP treatment and l-ascorbate can increase or decrease its efficacy depending on the length of the pre-incubation period.

  5. Cytocompatibility of Plasma and Thermally Treated Biopolymers

    Directory of Open Access Journals (Sweden)

    Petr Slepička

    2013-01-01

    Full Text Available This paper is focused on the surface characterization of plasma and consequently thermally treated biocompatible polymers. PLLA (poly(L-lactide acid and PMP (poly-4-methyl-1-pentene are studied. The influence of Ar plasma treatment on the surface polarity of substrate measured immediately after treatment and during the polymer surface aging is studied. Surface roughness, morphology, wettability, and surface chemistry were determined. Plasma treatment leads to significant changes in PLLA surface morphology and chemistry, with the PMP being slightly affected. The higher resistance to plasma fluence results in smaller ablation of PMP than that of PLLA. The plasma treatment improves cell adhesion and proliferation on the PMP. Plasma treatment of PLLA influences mostly the homogeneity of adhered and proliferated VSMC.

  6. Effects of Surface Treatments on Nylon 6,6 via Non-thermal Atmospheric Plasma for Thermoplastic Adhesives

    Science.gov (United States)

    Wu, Chi-Chin; Bujanda, Andres; Demaree, John; Robinette, Jason; Weerasooriya, Amanda; Flanagan, David; ARL Plasma Group, CCEP, WMRD Team

    2015-03-01

    This work aims to modify the properties of Nylon 6,6 surfaces for attaining improved interfacial adhesion to thermoplastic composites utilizing atmospheric non-thermal plasma treatments followed by silane treatments using 3-aminopropyltriethoxysilane (APS) in some cases. An L-shaped dielectric barrier discharge configuration was employed to expose nylon substrates to oxygen-containing gas plasmas such as He/O2 and He/H2O, respectively, at room temperature. The chemically-modified surface of the substrate after plasma exposure was immediately examined by static water contact angle wettability measurements and X-ray photoelectron spectroscopy. It was found that the surface hydrophilicity was substantially enhanced and the amount of surface oxygen was significantly increased after a three-minute plasma exposure due to the increased surface energy and additional O-H bonds. The enhancements on interfacial adhesion were evaluated with lap shear tests using three types of adhesives: EPON 825/D230, EPON 825/D2000 and sikaflex252, respectively. The results of tensile tests on the adhesive joints showed an almost ~ 300% increase in interfacial adhesive strength for EPON 825/D230 bonds after plasma treatments. Finite element modeling of adhesive joints for bond strength is underway to compare with experimental results and study the quantitative relations between the mechanical properties within the bond and at interfaces.

  7. Effective degradation of organic water pollutants by atmospheric non-thermal plasma torch and analysis of degradation process.

    Science.gov (United States)

    Bansode, Avinash S; More, Supriya E; Siddiqui, Ejaz Ahmad; Satpute, Shruti; Ahmad, Absar; Bhoraskar, Sudha V; Mathe, Vikas L

    2017-01-01

    The paper reports the use of atmospheric non-thermal plasma torch as a catalyst for degradation of various organic pollutants dissolved in water. A flow of He mixed with air was used to produce the dielectric barrier discharge (DBD), at the tip of the torch, using pulsed electric excitation at 12 kV. The torch, operated at a power of 750 mW/mm(2), was seen to completely degrade the aqueous solutions of the pollutants namely methylene blue (MB), methyl orange (MO) and rhodamine-B (RB), at around 10(-4) M concentrations, the concentration of polluants is one order higher than of routinely used heterogeneous photocatalytic reactions, within 10 min of irradiation time at room temperature. UV Visible spectra of the organic dye molecules, monitored after different intervals of plasma-irradiation, ranging between 1 and 10 min, have been used as tools to quantify their sequential degradation. Further, instead of using He, only air was used to form plasma plume and used for degradation of organic dye which follow similar trend as that of He plasma. Further, Liquid Chromatography Mass Spectroscopy (LCMS) technique has been used to understand degradation pathway of methylene blue (MB) as a representative case. Total organic carbon (TOC) measurements indicates significant decrease in its content as a function of duration of plasma exposure onto methylene blue as a representative case. Toxicity studies were carried out onto Gram negative Escherichia coli. This indicated that methylene blue, without plasma treatment, shows growth inhibition, whereas with plasma treatment no inhibition was observed.

  8. Effect of Suspension Plasma-Sprayed YSZ Columnar Microstructure and Bond Coat Surface Preparation on Thermal Barrier Coating Properties

    Science.gov (United States)

    Bernard, Benjamin; Quet, Aurélie; Bianchi, Luc; Schick, Vincent; Joulia, Aurélien; Malié, André; Rémy, Benjamin

    2017-08-01

    Suspension plasma spraying (SPS) is identified as promising for the enhancement of thermal barrier coating (TBC) systems used in gas turbines. Particularly, the emerging columnar microstructure enabled by the SPS process is likely to bring about an interesting TBC lifetime. At the same time, the SPS process opens the way to a decrease in thermal conductivity, one of the main issues for the next generation of gas turbines, compared to the state-of-the-art deposition technique, so-called electron beam physical vapor deposition (EB-PVD). In this paper, yttria-stabilized zirconia (YSZ) coatings presenting columnar structures, performed using both SPS and EB-PVD processes, were studied. Depending on the columnar microstructure readily adaptable in the SPS process, low thermal conductivities can be obtained. At 1100 °C, a decrease from 1.3 W m-1 K-1 for EB-PVD YSZ coatings to about 0.7 W m-1 K-1 for SPS coatings was shown. The higher content of porosity in the case of SPS coatings increases the thermal resistance through the thickness and decreases thermal conductivity. The lifetime of SPS YSZ coatings was studied by isothermal cyclic tests, showing equivalent or even higher performances compared to EB-PVD ones. Tests were performed using classical bond coats used for EB-PVD TBC coatings. Thermal cyclic fatigue performance of the best SPS coating reached 1000 cycles to failure on AM1 substrates with a β-(Ni,Pt)Al bond coat. Tests were also performed on AM1 substrates with a Pt-diffused γ-Ni/γ'-Ni3Al bond coat for which more than 2000 cycles to failure were observed for columnar SPS YSZ coatings. The high thermal compliance offered by both the columnar structure and the porosity allowed the reaching of a high lifetime, promising for a TBC application.

  9. Transport of super-thermal particles and their effect on the stability of global modes in fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Schneller, Mirjam Simone

    2013-08-02

    In thermonuclear plasmas, a population of super-thermal particles generated by external heating methods or fusion reactions can lead to the excitation of global instabilities. The transport processes due to nonlinear wave-particle interactions and the consequential particle losses reduce the plasma heating and the efficiency of the fusion reaction rate. Furthermore, these energetic or fast particles may cause severe damages to the wall of the device. This thesis addresses the resonance mechanisms between these energetic particles and global MHD and kinetic MHD waves, employing the hybrid code HAGIS. A systematic investigation of energetic particles resonant with multiple modes (double-resonance) is presented for the first time. The double-resonant mode coupling is modeled for waves with different frequencies in various overlapping scenarios. It is found that, depending on the radial mode distance, double-resonance is able to significantly enhance, both the growth rates and the saturation amplitudes. Small radial mode distances, however can lead to strong nonlinear mode stabilization of a linear dominant mode. For the first time, simulations of experimental conditions in the ASDEX Upgrade fusion device are performed for different plasma equilibria (particularly for different q profiles). An understanding of fast particle behavior for non-monotonic q profiles is important for the development of advanced fusion scenarios. The numerical tool is the extended version of the HAGIS code, which computes the particle motion in the vacuum region between vessel wall in addition to the internal plasma volume. For this thesis, a consistent fast particle distribution function was implemented, to represent the fast particle population generated by the particular heating method (ICRH). Furthermore, HAGIS was extended to use more realistic eigenfunctions, calculated by the gyrokinetic eigenvalue solver LIGKA. One important aim of these simulations is to allow fast ion loss

  10. Effect of particle size on the microstructure and thermal conductivity of Al/diamond composites prepared by spark plasma sintering

    Institute of Scientific and Technical Information of China (English)

    CHU Ke; JIA Chengchang; LIANG Xuebing; CHEN Hui; GAO Wenjia

    2009-01-01

    Spark plasma sintering (SPS) was used to fabricate Al/diamond composites. The influence of diamond particle size on the microstrueture and thermal conductivity (TC) of composites was investigated by combining experimental results with model prediction. The results show that both composites with 40 μm particles and 70 μm particles exhibit high density and good TC, and the composite with 70 μm particles indi-cates an excellent TC of 325 W·m~(-1)·K~(-1). Their TCs lay between the theoretical estimated bounds. In contrast, the composite with 100 μm particles demonstrates low density as well as poor TC due to its high porosity and weak interfacial bonding. Its TC is even considerably less than the lower bound of the predicted value. Using larger diamond particles can further enhance thermal conductive performance only based on the premise that highly dense composites of strong interfacial bonding can be obtained.

  11. Effect of Hall Current and Finite Larmor Radius Corrections on Thermal Instability of Radiative Plasma for Star Formation in Interstellar Medium (ISM)

    Indian Academy of Sciences (India)

    Sachin Kaothekar

    2016-09-01

    The effects of finite ion Larmor radius (FLR) corrections, Hall current and radiative heat--loss function on the thermal instability of an infinite homogeneous, viscous plasma incorporating the effects of finite electrical resistivity, thermal conductivity and permeability for star formation in interstellar medium have been investigated. A general dispersion relation is derived using the normal mode analysis method with the help of relevant linearized perturbation equations of the problem. The wave propagation is discussed for longitudinal and transverse directions to the external magnetic field and the conditions of modified thermal instabilities and stabilities are discussed in different cases. We find that the thermal instability criterion gets modified into radiative instability criterion. The finite electrical resistivity removes the effect of magnetic field and the viscosity of the medium removes the effect of FLR from the condition of radiative instability. The Hall parameter affects only the longitudinal mode of propagation and it has no effect on the transverse mode of propagation. Numerical calculation shows stabilizing effect of viscosity, heat--loss function and FLR corrections, and destabilizing effect of finite resistivity and permeability on the thermal instability. The outcome of the problem discussed the formation of star in the interstellar medium.

  12. Processing Parameter Effects and Thermal Properties of Y2Si2O7 Nanostructured Environmental Barrier Coatings Synthesized by Solution Precursor Induction Plasma Spraying

    Science.gov (United States)

    Darthout, Émilien; Laduye, Guillaume; Gitzhofer, François

    2016-09-01

    The solution precursor plasma spray process, in which a solution of metal salts is axially injected into an induction thermal plasma, is suitable for deposition of nanostructured environmental barrier coatings. The effects of main processing parameters, namely the solution precursor concentration, spraying distance, reactor pressure, and atomization gas flow rate, have been analyzed using D-optimal design of experiments regarding the deposition rate and coating porosity responses. Among these four parameters, the solution precursor concentration had the greatest influent on the coating structure, followed by the spraying distance and reactor pressure, and finally the atomization gas flow rate with a small contribution. It is pointed out that the species that impact on the substrate are agglomerates of nanoparticles. The equivalent thermal conductivity of selected coatings was computed from experimental temperature evolution curves obtained by laser flash thermal diffusivity analysis, using two methods: a multilayer finite-element model with optimization, and a multilayer thermal diffusion model. The results of the two models agree, with coatings exhibiting low thermal conductivity between 0.7 and 1 W/(m K) at 800 °C.

  13. Processing Parameter Effects and Thermal Properties of Y2Si2O7 Nanostructured Environmental Barrier Coatings Synthesized by Solution Precursor Induction Plasma Spraying

    Science.gov (United States)

    Darthout, Émilien; Laduye, Guillaume; Gitzhofer, François

    2016-10-01

    The solution precursor plasma spray process, in which a solution of metal salts is axially injected into an induction thermal plasma, is suitable for deposition of nanostructured environmental barrier coatings. The effects of main processing parameters, namely the solution precursor concentration, spraying distance, reactor pressure, and atomization gas flow rate, have been analyzed using D-optimal design of experiments regarding the deposition rate and coating porosity responses. Among these four parameters, the solution precursor concentration had the greatest influent on the coating structure, followed by the spraying distance and reactor pressure, and finally the atomization gas flow rate with a small contribution. It is pointed out that the species that impact on the substrate are agglomerates of nanoparticles. The equivalent thermal conductivity of selected coatings was computed from experimental temperature evolution curves obtained by laser flash thermal diffusivity analysis, using two methods: a multilayer finite-element model with optimization, and a multilayer thermal diffusion model. The results of the two models agree, with coatings exhibiting low thermal conductivity between 0.7 and 1 W/(m K) at 800 °C.

  14. Effect of rapid thermal annealing and hydrogen plasma treatment on the microstructure and light-emission of silicon-rich oxide film

    CERN Document Server

    Wang Yong; Chen Chang Yong; Diao Hong Wei; Zhang Shi Bin; Xu Yan Yue; Kong Guang Lin; Liao Xian Bo

    2002-01-01

    Silicon-rich silicon oxide (SRSO) films are prepared by plasma-enhanced chemical vapor deposition method at the substrate temperature of 200 degree C. The effect of rapid thermal annealing and hydrogen plasma treatment on the microstructure and light-emission of SRSO films are investigated in detail using micro-Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy and photoluminescence (PL) spectra. It is found that the phase-separation degree of the films decreases with increasing annealing temperature from 300 to 600 degree C, which it increases with increasing annealing temperature from 600 to 900 degree C. The light-emission of the films are enhanced with increasing annealing temperature up to 500 degree C, while it is rapidly reduced when the annealing temperature exceeds 600 degree C. The peak position of the PL spectrum blue shifts by annealing at the temperature of 300 degree C, then it redshifts with further raising annealing temperature. The following hydrogen plasma treatment results i...

  15. Effects of a non thermal plasma treatment alone or in combination with gemcitabine in a MIA PaCa2-luc orthotopic pancreatic carcinoma model.

    Science.gov (United States)

    Brullé, Laura; Vandamme, Marc; Riès, Delphine; Martel, Eric; Robert, Eric; Lerondel, Stéphanie; Trichet, Valérie; Richard, Serge; Pouvesle, Jean-Michel; Le Pape, Alain

    2012-01-01

    Pancreatic tumors are the gastrointestinal cancer with the worst prognosis in humans and with a survival rate of 5% at 5 years. Nowadays, no chemotherapy has demonstrated efficacy in terms of survival for this cancer. Previous study focused on the development of a new therapy by non thermal plasma showed significant effects on tumor growth for colorectal carcinoma and glioblastoma. To allow targeted treatment, a fibered plasma (Plasma Gun) was developed and its evaluation was performed on an orthotopic mouse model of human pancreatic carcinoma using a MIA PaCa2-luc bioluminescent cell line. The aim of this study was to characterize this pancreatic carcinoma model and to determine the effects of Plasma Gun alone or in combination with gemcitabine. During a 36 days period, quantitative BLI could be used to follow the tumor progression and we demonstrated that plasma gun induced an inhibition of MIA PaCa2-luc cells proliferation in vitro and in vivo and that this effect could be improved by association with gemcitabine possibly thanks to its radiosensitizing properties.

  16. Effects of a non thermal plasma treatment alone or in combination with gemcitabine in a MIA PaCa2-luc orthotopic pancreatic carcinoma model.

    Directory of Open Access Journals (Sweden)

    Laura Brullé

    Full Text Available Pancreatic tumors are the gastrointestinal cancer with the worst prognosis in humans and with a survival rate of 5% at 5 years. Nowadays, no chemotherapy has demonstrated efficacy in terms of survival for this cancer. Previous study focused on the development of a new therapy by non thermal plasma showed significant effects on tumor growth for colorectal carcinoma and glioblastoma. To allow targeted treatment, a fibered plasma (Plasma Gun was developed and its evaluation was performed on an orthotopic mouse model of human pancreatic carcinoma using a MIA PaCa2-luc bioluminescent cell line. The aim of this study was to characterize this pancreatic carcinoma model and to determine the effects of Plasma Gun alone or in combination with gemcitabine. During a 36 days period, quantitative BLI could be used to follow the tumor progression and we demonstrated that plasma gun induced an inhibition of MIA PaCa2-luc cells proliferation in vitro and in vivo and that this effect could be improved by association with gemcitabine possibly thanks to its radiosensitizing properties.

  17. Evaluation of mechanism of non-thermal plasma effect on the surface of polypropylene films for enhancement of adhesive and hemo compatible properties

    Science.gov (United States)

    Navaneetha Pandiyaraj, K.; Deshmukh, R. R.; Arunkumar, A.; Ramkumar, M. C.; Ruzybayev, I.; Ismat Shah, S.; Su, Pi-Guey; Periayah, Mercy Halleluyah; Halim, A. S.

    2015-08-01

    The hydro-carbon based polymers have attracted attention of scientists for its use in bio-medical field as various implants due to inherent flexibility. However, they have poor surface properties; particularly they have low surface energy (SE). Hence, blood components (platelets, blood proteins, etc.)-polymer surface interaction is the major concern when it comes in contact with blood. Thus, surface modification is required to develop the perfect antithrombogenic property without affecting the materials bulk. The present study describes the improvement in adhesive and blood compatible properties of polypropylene (PP) by low temperature (non-thermal) plasma of various gases such as Ar, O2, air and Ar + O2 for biomedical applications. The changes in surface morphological, chemical and hydrophilic modification induced by the gaseous plasma treatment were analyzed by atomic force microscopy (AFM), X-ray photo electron spectroscopy (XPS), electron spin resonance (ESR) spectroscopy and contact angle measurements, respectively. Moreover, the stability of plasma effect was also studied for the different storage conditions. Variation in adhesive strength of the plasma treated PP film was studied by T-Peel and Lap-Shear strength tests. The blood compatibility of the surface modified PP films was investigated by in vitro analysis. It was found that gaseous plasma treatment improved the blood compatibility as well as adhesive strength of the PP films without affecting materials bulk which may be due to the significant morphological and chemical changes induced by the gaseous plasma treatment. Among the various gaseous plasma treatments, Ar + O2 mixture has provided remarkable physico-chemical changes compared with other plasma treatments studied.

  18. Effect of Sintering on Thermal Conductivity and Thermal Barrier Effects of Thermal Barrier Coatings

    Institute of Scientific and Technical Information of China (English)

    WANG Kai; PENG Hui; GUO Hongbo; GONG Shengkai

    2012-01-01

    Thermal barrier coatings (TBCs) are mostly applied to hot components of advanced turbine engines to insulate the components from hot gas.The effect of sintering on thermal conductivity and thermal barrier effects of conventional plasma sprayed and nanostructured yttria stabilized zirconia (YSZ) thermal barrier coatings (TBCs) are investigated.Remarkable increase in thermal conductivity occurs to both typical coatings after heat treatment.The change of porosity is just the opposite.The grain size of the nanostructured zirconia coating increases more drastically with annealing time compared to that of the conventional plasma sprayed coating,which indicates that coating sintering makes more contributions to the thermal conductivity of the nanostructured coating than that of the conventional coating.Thermal barrier effect tests using temperature difference technique are performed on both coatings.The thermal barrier effects decrease with the increase of thermal conductivity after heat treatment and the decline seems more drastic in low thermal conductivity range.The decline in thermal barrier effects is about 80 ℃for nanostructured coating after 100 h heat treatment,while the conventional coating reduces by less than 60 ℃ compared to the as-sprayed coating.

  19. Evaluation of mechanism of non-thermal plasma effect on the surface of polypropylene films for enhancement of adhesive and hemo compatible properties

    Energy Technology Data Exchange (ETDEWEB)

    Navaneetha Pandiyaraj, K., E-mail: dr.knpr@gmail.com [Surface Engineering Laboratory, Department of Physics, Sri Shakthi Institute of Engineering and Technology, L& T by pass, Chinniyam Palayam (post), Coimbatore-641062 (India); Deshmukh, R.R. [Department of Physics, Institute of Chemical Technology, Matunga, Mumbai-400 019 (India); Arunkumar, A.; Ramkumar, M.C. [Surface Engineering Laboratory, Department of Physics, Sri Shakthi Institute of Engineering and Technology, L& T by pass, Chinniyam Palayam (post), Coimbatore-641062 (India); Ruzybayev, I.; Ismat Shah, S. [Department of Physics and Astronomy, Department of Materials Science and Engineering, University of Delaware, 208 Dupont Hall, Newark (United States); Su, Pi-Guey [Department of Chemistry, Chinese Culture University, Taipei 111, Taiwan (China); Periayah, Mercy Halleluyah; Halim, A.S. [School of Medical Sciences, Health Campus, Universiti Sains Malaysia, 16150 Kubang Kerian, Kelantan (Malaysia)

    2015-08-30

    Highlights: • Investigated the mechanism of effect of various gaseous plasma treatments on the surface properties of Polypropylene (PP) films. • The improvement in surface energy is basically due to the incorporation of polar functional groups onto the PP films. • The extent of surface modification and hydrophobic recovery depends upon the type of plasma forming gas. • Due to the significant morphological and chemical changes induced by the gaseous plasma treatment, improved the blood compatibility as well as adhesive strength of the PP films. - Abstract: The hydro-carbon based polymers have attracted attention of scientists for its use in bio-medical field as various implants due to inherent flexibility. However, they have poor surface properties; particularly they have low surface energy (SE). Hence, blood components (platelets, blood proteins, etc.)-polymer surface interaction is the major concern when it comes in contact with blood. Thus, surface modification is required to develop the perfect antithrombogenic property without affecting the materials bulk. The present study describes the improvement in adhesive and blood compatible properties of polypropylene (PP) by low temperature (non-thermal) plasma of various gases such as Ar, O{sub 2}, air and Ar + O{sub 2} for biomedical applications. The changes in surface morphological, chemical and hydrophilic modification induced by the gaseous plasma treatment were analyzed by atomic force microscopy (AFM), X-ray photo electron spectroscopy (XPS), electron spin resonance (ESR) spectroscopy and contact angle measurements, respectively. Moreover, the stability of plasma effect was also studied for the different storage conditions. Variation in adhesive strength of the plasma treated PP film was studied by T-Peel and Lap-Shear strength tests. The blood compatibility of the surface modified PP films was investigated by in vitro analysis. It was found that gaseous plasma treatment improved the blood compatibility

  20. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Hiromasa [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Mizuno, Masaaki [Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Toyokuni, Shinya [Department of Pathology and Biological Responses, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Maruyama, Shoichi [Department of Nephrology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kodera, Yasuhiro [Department of Gastroenterological Surgery (Surgery II), Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Terasaki, Hiroko [Department of Ophthalmology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Adachi, Tetsuo [Laboratory of Clinical Pharmaceutics, Gifu Pharmaceutical University, 501-1196 Gifu (Japan); Kato, Masashi [Department of Occupational and Environmental Health, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kikkawa, Fumitaka [Department of Obstetrics and Gynecology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Hori, Masaru [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

    2015-12-15

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  1. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    Science.gov (United States)

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-12-01

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  2. Effect of neutral collision and radiative heat-loss function on self-gravitational instability of viscous thermally conducting partially-ionized plasma

    Directory of Open Access Journals (Sweden)

    Sachin Kaothekar

    2012-12-01

    Full Text Available The problem of thermal instability and gravitational instability is investigated for a partially ionized self-gravitating plasma which has connection in astrophysical condensations. We use normal mode analysis method in this problem. The general dispersion relation is derived using linearized perturbation equations of the problem. Effects of collisions with neutrals, radiative heat-loss function, viscosity, thermal conductivity and magnetic field strength, on the instability of the system are discussed. The conditions of instability are derived for a temperature-dependent and density-dependent heat-loss function with thermal conductivity. Numerical calculations have been performed to discuss the effect of various physical parameters on the growth rate of the gravitational instability. The temperature-dependent heat-loss function, thermal conductivity, viscosity, magnetic field and neutral collision have stabilizing effect, while density-dependent heat-loss function has a destabilizing effect on the growth rate of the gravitational instability. With the help of Routh-Hurwitz's criterion, the stability of the system is discussed.

  3. Electron thermal transport in tokamak plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Konings, J.A.

    1994-11-30

    The process of fusion of small nuclei thereby releasing energy, as it occurs continuously in the sun, is essential for the existence of mankind. The same process applied in a controlled way on earth would provide a clean and an abundant energy source, and be the long term solution of the energy problem. Nuclear fusion requires an extremely hot (10{sup 8} K) ionized gas, a plasma, that can only be maintained if it is kept insulated from any material wall. In the so called `tokamak` this is achieved by using magnetic fields. The termal insulation, which is essential if one wants to keep the plasma at the high `fusion` temperature, can be predicted using basic plasma therory. A comparison with experiments in tokamaks, however, showed that the electron enery losses are ten to hundred times larger than this theory predicts. This `anomalous transport` of thermal energy implies that, to reach the condition for nuclear fusion, a fusion reactor must have very large dimensions. This may put the economic feasibility of fusion power in jeopardy. Therefore, in a worldwide collaboration, physicists study tokamak plasmas in an attempt to understand and control the energy losses. From a scientific point of view, the mechanisms driving anomalous transport are one of the challenges in fudamental plasma physics. In Nieuwegein, a tokamak experiment (the Rijnhuizen Tokamak Project, RTP) is dedicated to the study of anomalous transport, in an international collaboration with other laboratories. (orig./WL).

  4. Cell death induced by ozone and various non-thermal plasmas: therapeutic perspectives and limitations

    Science.gov (United States)

    Lunov, Oleg; Zablotskii, Vitalii; Churpita, Olexander; Chánová, Eliška; Syková, Eva; Dejneka, Alexandr; Kubinová, Šárka

    2014-11-01

    Non-thermal plasma has been recognized as a promising tool across a vast variety of biomedical applications, with the potential to create novel therapeutic methods. However, the understanding of the molecular mechanisms behind non-thermal plasma cellular effects remains a significant challenge. In this study, we show how two types of different non-thermal plasmas induce cell death in mammalian cell cultures via the formation of multiple intracellular reactive oxygen/nitrogen species. Our results showed a discrepancy in the superoxide accumulation and lysosomal activity in response to air and helium plasma, suggesting that triggered signalling cascades might be grossly different between different plasmas. In addition, the effects of ozone, a considerable component of non-thermal plasma, have been simultaneously evaluated and have revealed much faster and higher cytotoxic effects. Our findings offer novel insight into plasma-induced cellular responses, and provide a basis for better controlled biomedical applications.

  5. Thermal behavior of bovine serum albumin after exposure to barrier discharge helium plasma jet

    Science.gov (United States)

    Jijie, R.; Pohoata, V.; Topala, I.

    2012-10-01

    Non-thermal plasma jets at atmospheric pressure are useful tools nowadays in plasma medicine. Various applications are tested such as cauterization, coagulation, wound healing, natural and artificial surfaces decontamination, and sterilization. In order to know more about the effects of gas plasma on biological supramolecules, we exposed protein powders to a barrier discharge helium plasma jet. Then, spectroscopic investigations were carried out in order to obtain information on protein secondary, tertiary, and quaternary structures. We obtained a reduction of the protein alpha-helix content after the plasma exposure and a different behavior, for both thermal denaturation/renaturation kinetics and thermal aggregation process.

  6. Manganese-cerium oxide catalysts prepared by non-thermal plasma for NO oxidation: Effect of O2 in discharge atmosphere

    Science.gov (United States)

    Liu, Lu; Zheng, Chenghang; Wu, Shenghao; Gao, Xiang; Ni, Mingjiang; Cen, Kefa

    2017-09-01

    Non-thermal plasma with different O2 concentration in discharge atmosphere was applied to synthesize manganese and cerium mixed-oxides catalysts, which were compared in NO oxidation activity. Discharge atmosphere displayed a crucial influence on the performance of the catalysts prepared by plasma. Relatively low O2 concentration in discharge atmosphere allows synthesizing manganese-cerium oxides catalysts in a moderate environment and therefore is favorable for better physicochemical properties which lead to superior catalytic behavior. The best catalyst was obtained by treatment with 10% O2/N2 plasma and presented over 80% NO conversion in the temperature range of 275-325 °C, whereas catalyst prepared in pure O2 discharge atmosphere had the same activity with a catalyst prepared by calcinations. A correlation between the surface properties of the plasma prepared catalysts and its catalytic activity in NO oxidation is proposed. The amount of the surface adsorbed oxygen has an obvious linear correlation with the amount of Ce3+, the H2 consumption at low temperatures and the catalytic performance. The superior catalytic performance is mainly attributed to the stronger interaction between manganese oxides and ceria, and the formation of poorly crystallized Mn-O-Ce phase in the catalyst which resulted from the slow decomposition of nitrates and organics during plasma treatment. Catalysts prepared in relatively low O2 concentration have large specific surface area and is abundant in Ce3+ species and active oxygen species. The study suggests that plasma treatment with proper discharge gas components is a promising method to prepare effective manganese- cerium oxides catalyst for NO oxidation.

  7. Effect of Liquid Feed-Stock Composition on the Morphology of Titanium Dioxide Films Deposited by Thermal Plasma Spray.

    Science.gov (United States)

    Adán, C; Marugán, J; van Grieken, R; Chien, K; Pershin, L; Coyle, T; Mostaghimi, J

    2015-09-01

    Titanium dioxide coatings were deposited on the surface of titanium foils by Thermal Plasma Spray (TPS) process. Three different TiO2 coatings were prepared using the commercial TiO2-P25 nanopowder and titanium isopropoxide precursor solution as feed-stocks. Structure and morphology of the TiO2-P25 powder and the plasma sprayed coatings were analyzed by X-ray diffraction (XRD), Raman spectroscopy, N2 adsorption-desorption isotherms, UV-visible spectroscopy and Scanning Electron Microscopy (SEM). XRD and Raman results indicate that the TiO2 coatings were composed of an anatase/rutile mixture that is conditioned by the suspension composition used to be sprayed. Coatings prepared from TiO2-P25 nanoparticles in water suspension (NW-P25) and titanium isopropoxide solution suspension (NSP-P25) are incorporated into the coatings without phase transformation and their anatase/rutile ratio percentage remains very similar to the starting TiO2-P25 powder. On the contrary, when titanium isopropoxide solution is used for spraying (SP), the amount of rutile increases in the final TiO2 coating. SEM analysis also reveals different microstructure morphology, coating thickness, density and porosity of the three TiO2 films that depend significantly on the type of feed-stock employed. Interestingly, we have observed the role of titanium isopropoxide in the formation of more porous and cohesive layers of TiO2. The NSP-P25 coating, prepared with a mix of titanium isopropoxide solution based on TiO2 nanoparticles, presents higher deposition efficiencies and higher coating thickness than the film prepared with nanoparticles suspended in water (NW-P25) or with titanium isopropoxide solutions (SP). This is due to the precursor solution is acting as the cement between TiO2 nanoparticles, improving the cohesive strength of the coating. In sum, NSP-P25 and NW-P25 coatings display a good photocatalytic potential, based on their light absorption properties and mechanical stability. Band gap of

  8. Thermal Expansion of Vacuum Plasma Sprayed Coatings

    Science.gov (United States)

    Raj, S V.; Palczer, A. R.

    2010-01-01

    Metallic Cu-8%Cr, Cu-26%Cr, Cu-8%Cr-1%Al, NiAl and NiCrAlY monolithic coatings were fabricated by vacuum plasma spray deposition processes for thermal expansion property measurements between 293 and 1223 K. The corrected thermal expansion, (DL/L(sub 0) varies with the absolute temperature, T, as (DL/L(sub 0) = A(T - 293)(sup 3) + BIT - 293)(sup 2) + C(T - 293) + D, where, A, B, C and D are thermal, regression constants. Excellent reproducibility was observed for all of the coatings except for data obtained on the Cu-8%Cr and Cu-26%Cr coatings in the first heat-up cycle, which deviated from those determined in the subsequent cycles. This deviation is attributed to the presence of residual stresses developed during the spraying of the coatings, which are relieved after the first heat-up cycle. In the cases of Cu-8%Cr and NiAl, the thermal expansion data were observed to be reproducible for three specimens. The linear expansion data for Cu-8% Cr and Cu-26%Cr agree extremely well with rule of mixture (ROM) predictions. Comparison of the data for the Cu-8%Cr coating with literature data for Cr and Cu revealed that the thermal expansion behavior of this alloy is determined by the Cu-rich matrix. The data for NiAl and NiCrAlY are in excellent agreement with published results irrespective of composition and the methods used for processing the materials. The implications of these results on coating GRCop-84 copper alloy combustor liners for reusable launch vehicles are discussed.

  9. Analysis of intermediate pressure SiH4/He capacitively coupled plasma for deposition of an amorphous hydrogenated silicon film in consideration of thermal diffusion effects

    Science.gov (United States)

    Kim, Ho Jun; Lee, Hae June

    2017-08-01

    To achieve rapid, uniform deposition of an amorphous hydrogenated silicon (a-Si:H) film, a capacitively coupled plasma (CCP) is often used at an intermediate pressure (>100 Pa), with a silane (SiH4)-based mixture. At these pressures, heavy particle interactions (such as ion-ion, ion-neutral, and neutral-neutral reactions) contribute significantly to the formation of precursor radicals. By adding a consideration of the thermal diffusion effects to the neutral transport equation, the chemical processes have been numerically analyzed with variation in the number fraction of SiH4 and electrode spacing using a two-dimensional fluid model of radio frequency discharges in a cylindrically symmetric CCP reactor. The non-uniformity of the deposition rate profiles increases consistently as electrode spacing increases, although the non-uniformity of the plasma parameters decreases with the increase of electrode spacing. The simulated deposition rate profiles match well with the experimental data for the change of electrode spacing. Based on the validation of our model, we propose predictive designs to potentially improve the reactor and process by modifying the thermal and electrical surface conditions.

  10. Thermal conduction in a mirror-unstable plasma

    Science.gov (United States)

    Komarov, S. V.; Churazov, E. M.; Kunz, M. W.; Schekochihin, A. A.

    2016-07-01

    The plasma of galaxy clusters is subject to firehose and mirror instabilities at scales of order the ion Larmor radius. The mirror instability generates fluctuations of magnetic-field strength δB/B ˜ 1. These fluctuations act as magnetic traps for the heat-conducting electrons, suppressing their transport. We calculate the effective parallel thermal conductivity in the ICM in the presence of the mirror fluctuations for different stages of the evolution of the instability. The mirror fluctuations are limited in amplitude by the maximum and minimum values of the field strength, with no large deviations from the mean value. This key property leads to a finite suppression of thermal conduction at large scales. We find suppression down to ≈0.2 of the Spitzer value for the secular phase of the perturbations' growth, and ≈0.3 for their saturated phase. The effect operates in addition to other suppression mechanisms and independently of them. Globally, fluctuations δB/B ˜ 1 can be present on much larger scales, of the order of the scale of turbulent motions. However, we do not expect large suppression of thermal conduction by these, because their scale is considerably larger than the collisional mean free path of the ICM electrons. The obtained suppression of thermal conduction by a factor of ˜5 appears to be characteristic and potentially universal for a weakly collisional mirror-unstable plasma.

  11. Mechanism of NO reduction with non-thermal plasma

    Institute of Scientific and Technical Information of China (English)

    YU Gang; YU Qi; JIANG Yan-long; ZENG Ke-si; GU Fan

    2005-01-01

    Non-thermal plasma has been proved to be an effective and competitive technology for removing NO in flue gas since 1970. In this paper, the NO reduction mechanism of the non-thermal plasma reaction in NO/N2/O2 system was investigated using the method of spectral analysis and quantum chemistry. By the establishment of NO reduction and gas discharge plasma emission spectrum measuring system, the NO reduction results, gas discharge emission spectra of NO/N2O2 and pure N2 were obtained, and then the model of molecular orbit of N2 either in ground state or its excited state was worked out using the method of molecular orbit Ab initio in SelfConsistent Field(SCF). It was found that NO reduction in NO/N2 gas discharge plasma was achieved mainly through a series of fast elementary reactions and the N(E6) at excited state was the base for NO reduction.

  12. Thermal Fatigue Behavior of Air-Plasma Sprayed Thermal Barrier Coating with Bond Coat Species in Cyclic Thermal Exposure

    Directory of Open Access Journals (Sweden)

    Ungyu Paik

    2013-08-01

    Full Text Available The effects of the bond coat species on the delamination or fracture behavior in thermal barrier coatings (TBCs was investigated using the yclic thermal fatigue and thermal-shock tests. The interface microstructures of each TBC showed a good condition without cracking or delamination after flame thermal fatigue (FTF for 1429 cycles. The TBC with the bond coat prepared by the air-plasma spray (APS method showed a good condition at the interface between the top and bond coats after cyclic furnace thermal fatigue (CFTF for 1429 cycles, whereas the TBCs with the bond coats prepared by the high-velocity oxygen fuel (HVOF and low-pressure plasma spray (LPPS methods showed a partial cracking (and/or delamination and a delamination after 780 cycles, respectively. The TBCs with the bond coats prepared by the APS, HVOF and LPPS methods were fully delaminated (>50% after 159, 36, and 46 cycles, respectively, during the thermal-shock tests. The TGO thickness in the TBCs was strongly dependent on the both exposure time and temperature difference tested. The hardness values were found to be increased only after the CFTF, and the TBC with the bond coat prepared by the APS showed the highest adhesive strength before and after the FTF.

  13. Neutron irradiation effects on plasma facing materials

    Science.gov (United States)

    Barabash, V.; Federici, G.; Rödig, M.; Snead, L. L.; Wu, C. H.

    2000-12-01

    This paper reviews the effects of neutron irradiation on thermal and mechanical properties and bulk tritium retention of armour materials (beryllium, tungsten and carbon). For each material, the main properties affected by neutron irradiation are described and the specific tests of neutron irradiated armour materials under thermal shock and disruption conditions are summarized. Based on current knowledge, the expected thermal and structural performance of neutron irradiated armour materials in the ITER plasma facing components are analysed.

  14. Properties of stable nonstoichiometric nanoceria produced by thermal plasma

    Science.gov (United States)

    Lan, Yuan-Pei; Sohn, Hong Yong; Mohassab, Yousef; Liu, Qingcai; Xu, Baoqiang

    2017-08-01

    Thermally stable blue nonstoichiometric nanoceria was produced by feeding nanoceria with an average size of 50 nm into a DC thermal plasma reactor. The effects of different plasma power levels and atmospheres were investigated. XRD results showed the ceria lattice parameter increased with plasma power. SEM and TEM results showed that the shape of nanoparticles changed after plasma treatment; the blue nonstoichiometric nanoceria had highly regular shapes such as triangular pyramids and polyhedral in contrast to the irregular shape of the raw nanoceria. Significant downshift was found in the Raman spectra of the plasma products, with a 7.9-cm-1 shift compared with raw nanoceria, which was explained by the reduction of Ce4+. X-ray photoelectron spectroscopy results showed that the Ce3+ fraction increased from 14% in the raw nanoceria to 38-39% for the product CeO2- x , indicating the high reduction state on the ceria surface. It was determined that this blue nonstoichiometric nanoceria was stable up to 400 °C in air, but the color changed to pale yellow after 4 h at 500 °C in air indicating oxidation to CeO2. Additionally, this novel stable nano-CeO2- x caused a red shift in the UV-visible absorption results; a 48-nm red shift occurred for the nonstoichiometric nanoceria produced at 15 kW compared with the raw nanoceria. The band gap was calculated to be 2.5 eV while it was 3.2 eV for the raw nanoceria, indicating that this novel stable blue nonstoichiometric nanoceria should be a promising material for optical application.

  15. Anisotropic Thermal Diffusivities of Plasma-Sprayed Thermal Barrier Coatings

    Science.gov (United States)

    Akoshima, Megumi; Takahashi, Satoru

    2017-09-01

    Thermal barrier coatings (TBCs) are used to shield the blades of gas turbines from heat and wear. There is a pressing need to evaluate the thermal conductivity of TBCs in the thermal design of advanced gas turbines with high energy efficiency. These TBCs consist of a ceramic-based top coat and a bond coat on a superalloy substrate. Usually, the focus is on the thermal conductivity in the thickness direction of the TBC because heat tends to diffuse from the surface of the top coat to the substrate. However, the in-plane thermal conductivity is also important in the thermal design of gas turbines because the temperature distribution within the turbine cannot be ignored. Accordingly, a method is developed in this study for measuring the in-plane thermal diffusivity of the top coat. Yttria-stabilized zirconia top coats are prepared by thermal spraying under different conditions. The in-plane and cross-plane thermal diffusivities of the top coats are measured by the flash method to investigate the anisotropy of thermal conduction in a TBC. It is found that the in-plane thermal diffusivity is higher than the cross-plane one for each top coat and that the top coats have significantly anisotropic thermal diffusivity. The cross-sectional and in-plane microstructures of the top coats are observed, from which their porosities are evaluated. The thermal diffusivity and its anisotropy are discussed in detail in relation to microstructure and porosity.

  16. Monoclinic zirconia distributions in plasma-sprayed thermal barrier coatings

    Science.gov (United States)

    Lance, M. J.; Haynes, J. A.; Ferber, M. K.; Cannon, W. R.

    2000-03-01

    Phase composition in an air plasma-sprayed Y2O3-stabilized ZrO2 (YSZ) top coating of a thermal barrier coating (TBC) system was characterized. Both the bulk phase content and localized pockets of monoclinic zirconia were measured with Raman spectroscopy. The starting powder consisted of ˜15 vol.% monoclinic zirconia, which decreased to ˜2 vol.% in the as-sprayed coating. Monoclinic zirconia was concentrated in porous pockets that were evenly distributed throughout the TBC. The pockets resulted from the presence of unmelted granules in the starting powder. The potential effect of the distributed monoclinic pockets on TBC performance is discussed.

  17. Laser Remelting of Plasma Sprayed Thermal Barrier Coatings

    Institute of Scientific and Technical Information of China (English)

    Gang ZHANG; Yong LIANG; Yingna WU; Zhongchao FENG; Bingchun ZHANG; Fangjun LIU

    2001-01-01

    A CO2 continuous wave laser with defocused beam was used for remelting the surface of plasma sprayed ZrO2-8 wt pct Y2O3 (8YSZ)/Ni22Cr10AlY thermal barrier coatings (TBCs) on GH536 superalloy substrate. Two main laser processing parameters, power and travel speed, were adopted to produce a completely remelted layer, and their effects on remelted appearance,remelting depth, density and diameter of depression, space of segment crack and remelted microstructure were evaluated. With energy of 4.0 to 8.0 J.mm-2, an appropriate laser processing for applicable remelted layer was suggested.

  18. Photon thermal Hall effect

    CERN Document Server

    Ben-Abdallah, Philippe

    2015-01-01

    A near-field thermal Hall effect (i.e.Righi-Leduc effect) in lattices of magneto-optical particles placed in a constant magnetic field is predicted. This effect is related to a symetry breaking in the system induced by the magnetic field which gives rise to preferential channels for the heat-transport by photon tunneling thanks to the particles anisotropy tuning.

  19. Non-Thermal Sanitation By Atmospheric Pressure Plasma Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC's Non-Thermal Sanitation by Atmospheric Pressure Plasma technology sanitizes fresh fruits and vegetables without the use of consumable chemicals and without...

  20. Non-Thermal Sanitation By Atmospheric Pressure Plasma Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC proposes to develop a non-thermal technology based on atmospheric-pressure (AP) cold plasma to sanitize foods, food packaging materials, and other hardware...

  1. Bilayer Suspension Plasma-Sprayed Thermal Barrier Coatings with Enhanced Thermal Cyclic Lifetime: Experiments and Modeling

    Science.gov (United States)

    Gupta, Mohit; Kumara, Chamara; Nylén, Per

    2017-08-01

    Suspension plasma spraying (SPS) has been shown as a promising process to produce porous columnar strain tolerant coatings for thermal barrier coatings (TBCs) in gas turbine engines. However, the highly porous structure is vulnerable to crack propagation, especially near the topcoat-bondcoat interface where high stresses are generated due to thermal cycling. A topcoat layer with high toughness near the topcoat-bondcoat interface could be beneficial to enhance thermal cyclic lifetime of SPS TBCs. In this work, a bilayer coating system consisting of first a dense layer near the topcoat-bondcoat interface followed by a porous columnar layer was fabricated by SPS using Yttria-stabilised zirconia suspension. The objective of this work was to investigate if the bilayer topcoat architecture could enhance the thermal cyclic lifetime of SPS TBCs through experiments and to understand the effect of the column gaps/vertical cracks and the dense layer on the generated stresses in the TBC during thermal cyclic loading through finite element modeling. The experimental results show that the bilayer TBC had significantly higher lifetime than the single-layer TBC. The modeling results show that the dense layer and vertical cracks are beneficial as they reduce the thermally induced stresses which thus increase the lifetime.

  2. Effects of Rapid Thermal Annealing on Optical Properties of GaInNAs/GaAs Single Quantum Well Grown by Plasma-Assisted Molecular Beam Epitaxy

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The effects of Rapid Thermal Annealing (RTA) on the optical properties of GaInNAs/GaAs Single Quantum Well (SQW) grown by plasma-assisted molecular beam epitaxy are investigated. Ion removal magnets were applied to reduce the ion damage during the growth process and the optical properties of GaInNAs/GaAs SQW are remarkably improved.RTA was carried out at 650℃ and its effect was studied by the comparising the roomtemperature PhotoLuminescence (PL) spectra for the non ion-removed (grown without magnets) sample with for the ion-removed (grown with magnets) one. The more significant improvement of PL characteristics for non ion-removed GaInNAs/GaAs SQW after annealing (compared with those for ion-removed) indicates that the nonradiative centers removed by RTA at 650℃ are mainly originated from ion damage. After annealing the PL blue shift for non ionremoved GaInNAs/GaAs SQW is much larger than those for InGaAs/GaAs and ion-removed GaInNAs/GaAs SQW. It is found that the larger PL blue shift of GaInNAs/GaAs SQW is due to the defect-assisted In-Ga interdiffusion rather than defect-assisted N-As interdiffusion.

  3. Monitoring system for thermal plasma; Sistema de monitoreo para plasma termico

    Energy Technology Data Exchange (ETDEWEB)

    Romero G, M.; Vilchis P, A.E. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    In the Thermal plasma applications laboratory it has been the degradation project of oils for isolation in transformers. These are a very hazardous residues and at this time in the country they are stored in metal barrels. It has been the intention to undergo the oils to plasma for degradate them to non-hazardous residues. The system behavior must be monitored to establish the thermal plasma behavior. (Author)

  4. Electrothermal efficiency, temperature and thermal conductivity of plasma jet in a DC plasma spray torch

    Indian Academy of Sciences (India)

    G Shanmugavelayutham; V Selvarajan

    2003-12-01

    A study was made to evaluate the electrothermal efficiency of a DC arc plasma torch and temperature and thermal conductivity of plasma jet in the torch. The torch was operated at power levels from 4 to 20 kW in non-transferred arc mode. The effect of nitrogen in combination with argon as plasma gas on the above properties was investigated. Calculations were made from experimental data. The electrothermal efficiency increased significantly with increase in nitrogen content. The plasma jet temperature and thermal conductivity exhibited a decrease with increase in nitrogen content. The experiment was done at different total gas flow rates. The results are explained on the basis of dissociation energy of nitrogen molecules and plasma jet energy loss to the cathode, anode and the walls of the torch.

  5. Effects of the electrical excitation signal parameters on the geometry of an argon-based non-thermal atmospheric pressure plasma jet.

    Science.gov (United States)

    Benabbas, Mohamed Tahar; Sahli, Salah; Benhamouda, Abdallah; Rebiai, Saida

    2014-12-01

    A non-thermal atmospheric pressure argon plasma jet for medical applications has been generated using a high-voltage pulse generator and a homemade dielectric barrier discharge (DBD) reactor with a cylindrical configuration. A plasma jet of about 6 cm of length has been created in argon gas at atmospheric pressure with an applied peak to peak voltage and a frequency of 10 kV and 50 kHz, respectively. The length and the shape of the created plasma jet were found to be strongly dependent on the electrode setup and the applied voltage and the signal frequency values. The length of the plasma jet increases when the applied voltage and/or its frequency increase, while the diameter at its end is significantly reduced when the applied signal frequency increases. For an applied voltage of 10 kV, the plasma jet diameter decreases from near 5 mm for a frequency of 10 kHz to less than 1 mm at a frequency of 50 kHz. This obtained size of the plasma jet diameter is very useful when the medical treatment must be processed in a reduced space. PACS 2008: 52.50.Dg; 52.70.-m; 52.80.-s.

  6. Removal of Pollutants by Atmospheric Non Thermal Plasmas

    CERN Document Server

    Khacef, Ahmed; Pouvesle, Jean Michel; Van, Tiep Le

    2008-01-01

    Results on the application of non thermal plasmas in two environmentally important fields: oxidative removal of VOC and NOx in excess of oxygen were presented. The synergetic application of a plasma-catalytic treatment of NOx in excess of oxygen is also described.

  7. Low Thermal Conductivity Yttria-Stabilized Zirconia Thermal Barrier Coatings Using the Solution Precursor Plasma Spray Process

    Science.gov (United States)

    Jordan, Eric H.; Jiang, Chen; Roth, Jeffrey; Gell, Maurice

    2014-06-01

    The primary function of thermal barrier coatings (TBCs) is to insulate the underlying metal from high temperature gases in gas turbine engines. As a consequence, low thermal conductivity and high durability are the primary properties of interest. In this work, the solution precursor plasma spray (SPPS) process was used to create layered porosity, called inter-pass boundaries, in yttria-stabilized zirconia (YSZ) TBCs. IPBs have been shown to be effective in reducing thermal conductivity. Optimization of the IPB microstructure by the SPPS process produced YSZ TBCs with a thermal conductivity of 0.6 W/mK, an approximately 50% reduction compared to standard air plasma sprayed (APS) coatings. In preliminary tests, SPPS YSZ with IPBs exhibited equal or greater furnace thermal cycles and erosion resistance compared to regular SPPS and commercially made APS YSZ TBCs.

  8. Hemorheological alterations of red blood cells induced by non-thermal dielectric barrier discharge plasma

    Science.gov (United States)

    Kim, Jeongho; Kim, Jae Hyung; Chang, Boksoon; Choi, Eun Ha; Park, Hun-Kuk

    2016-11-01

    Atmospheric pressure non-thermal plasma has been introduced in various applications such as wound healing, sterilization of infected tissues, blood coagulation, delicate surgeries, and so on. The non-thermal plasma generates reactive oxygen species (ROS), including ozone. Various groups have reported that the produced ROS influence proliferation and differentiation of cells, as well as apoptosis and growth arrest of tumor cells. In this study, we investigated the effects of non-thermal plasma on rheological characteristics of red blood cells (RBC). We experimentally measured the extent of hemolysis, deformability, and aggregation of red blood cells (RBC) with respect to exposure times of non-thermal plasma. RBC morphology was also examined using field-emission scanning electron microscopy. The absorbance of hemoglobin released from the RBCs increased with increasing exposure time of the non-thermal plasma. Values of the elongation index and aggregation index were shown to decrease significantly with increasing plasma exposure times. Therefore, hemorheological properties of RBCs could be utilized to assess the performance of various non-thermal plasmas.

  9. Effects of thermal regime on ovarian maturation and plasma sex steroids in farmed white sturgeon, Acipenser transmontanus

    Science.gov (United States)

    Webb, M.A.H.; Van Eenennaam, J. P.; Feist, G.W.; Linares-Casenave, J.; Fitzpatrick, M.S.; Schreck, C.B.; Doroshov, S.I.

    2001-01-01

    Recently, commercial aquaculture farms in Northern California have exposed gravid, cultured white sturgeon females to cold water (12 ?? 1??C) throughout the late phase of vitellogenesis and ovarian follicle maturation resulting in improved ovulation rates and egg quality. However, the optimum timing for transfer of broodfish to the cold water and the capacity of transferred broodfish to maintain reproductive competence over an extended time in cold water had not been evaluated. Gravid white sturgeon females that have been raised at water temperatures of 16-20??C were transported to either cold water (12 ?? 1??C; Group 1) in November 1997 or maintained in ambient water temperatures (10-19??C; Group 2) until early spring. In March 1998, half of the fish in Group 2 had regressed ovaries, but the remaining females had intact ovarian follicles and were transported to the cold water. Ovarian follicles and blood were collected from females until they reached the stage of spawning readiness (determined by germinal vesicle position and an oocyte maturation assay) or underwent ovarian regression. Exposure of gravid sturgeon females to ambient water temperatures (14.5 ?? 2.3??C, mean ?? S.D.) from October to March led to a decrease in plasma sex steroids and a high incidence of ovarian regression in fish with a more advanced stage of oocyte development. Transfer of females with intact ovarian follicles to cold water (12 ?? 1??C) in the fall or early spring resulted in normal ovarian development in the majority of females. Holding females in cold water does not seem to override their endogenous reproductive rhythms but extends their capacity to maintain oocyte maturational competence over a longer period of time. A temperature-sensitive phase in ovarian development may occur during the transition from vitellogenic growth to oocyte maturation, and the degree and timing of sensitivity to environmental temperature are dependent on the female's endogenous reproductive rhythm

  10. On thermalization of electron-positron-photon plasma

    Energy Technology Data Exchange (ETDEWEB)

    Siutsou, I. A., E-mail: siutsou@icranet.org [CAPES–ICRANet program, ICRANet–Rio, CBPF 22290-180, Rua Dr. Xavier Sigaud, 150, Urca, Rio de Janeiro, RJ (Brazil); Aksenov, A. G. [Institute for Computer-Aided Design, Russian Academy of Sciences 123056, 2nd Brestskaya st., 19/18, Moscow (Russian Federation); Vereshchagin, G. V. [ICRANet 65122, p.le della Republica, 10, Pescara (Italy)

    2015-12-17

    Recently a progress has been made in understanding thermalization mechanism of relativistic plasma starting from a non-equilibrium state. Relativistic Boltzmann equations were solved numerically for homogeneous isotropic plasma with collision integrals for two- and three-particle interactions calculated from the first principles by means of QED matrix elements. All particles were assumed to fulfill Boltzmann statistics. In this work we follow plasma thermalization by accounting for Bose enhancement and Pauli blocking in particle interactions. Our results show that particle in equilibrium reach Bose-Einstein distribution for photons, and Fermi-Dirac one for electrons, respectively.

  11. Turbulent thermalization of the Quark Gluon Plasma

    CERN Document Server

    Berges, J; Schlichting, S; Venugopalan, R

    2013-01-01

    Classical-statistical lattice gauge theory simulations are employed to demonstrate the existence of a nonthermal fixed point in the space-time evolution of heavy ion collisions at ultrarelativistic energies. After an initial transient regime dominated by plasma instabilities and free streaming, the ensuing overpopulated non-Abelian plasma exhibits the universal self-similar dynamics characteristic of wave turbulence observed in a large variety of physical systems across different energy scales.

  12. Preparation of thermal barrier coatings by ultrasonic plasma spraying

    Institute of Scientific and Technical Information of China (English)

    WEN Xiong-wei; LI Lu-ming; ZHANG Hua-tang; HAO Hong-wei; LU Zhi-qing

    2004-01-01

    Modulated plasma arc not only can heat the powder, but also can excite ultrasonic of different frequencies and different powers. The principles and characters of the plasma arc-excited ultrasonic were described, and the ultrasonic plasma spraying was compared with normal plasma spraying. Zirconia thermal barrier coatings (TBCs) were fabricated with two kinds of method. The TBCs were studied by the optical microscope observation, SEM observation and bonding strength experiment. The results show that suitable ultrasonic changes the performance and microstructure of TBCs in evidence. And the mechanism of ultrasonic influencing the TBCs was also discussed.

  13. Effects of O2 plasma post-treatment on ZnO: Ga thin films grown by H2O-thermal ALD

    Science.gov (United States)

    Lee, Yueh-Lin; Chuang, Jia-Hao; Huang, Tzu-Hsuan; Ho, Chong-Long; Wu, Meng-Chyi

    2013-03-01

    Transparent conducting oxides have been widely employed in optoelectronic devices using the various deposition methods such as sputtering, thermal evaporator, and e-gun evaporator technologies.1-3 In this work, gallium doped zinc oxide (ZnO:Ga) thin films were grown on glass substrates via H2O-thermal atomic layer deposition (ALD) at different deposition temperatures. ALD-GZO thin films were constituted as a layer-by-layer structure by stacking zinc oxides and gallium oxides. Diethylzinc (DEZ), triethylgallium (TEG) and H2O were used as zinc, gallium precursors and oxygen source, respectively. Furthermore, we investigated the influences of O2 plasma post-treatment power on the surface morphology, electrical and optical property of ZnO:Ga films. As the result of O2 plasma post-treatment, the characteristics of ZnO:Ga films exhibit a smooth surface, low resistivity, high carrier concentration, and high optical transmittance in the visible spectrum. However, the transmittance decreases with O2 plasma power in the near- and mid-infrared regions.

  14. Non-thermal atmospheric-pressure plasma possible application in wound healing.

    Science.gov (United States)

    Haertel, Beate; von Woedtke, Thomas; Weltmann, Klaus-Dieter; Lindequist, Ulrike

    2014-11-01

    Non-thermal atmospheric-pressure plasma, also named cold plasma, is defined as a partly ionized gas. Therefore, it cannot be equated with plasma from blood; it is not biological in nature. Non-thermal atmospheric-pressure plasma is a new innovative approach in medicine not only for the treatment of wounds, but with a wide-range of other applications, as e.g. topical treatment of other skin diseases with microbial involvement or treatment of cancer diseases. This review emphasizes plasma effects on wound healing. Non-thermal atmospheric-pressure plasma can support wound healing by its antiseptic effects, by stimulation of proliferation and migration of wound relating skin cells, by activation or inhibition of integrin receptors on the cell surface or by its pro-angiogenic effect. We summarize the effects of plasma on eukaryotic cells, especially on keratinocytes in terms of viability, proliferation, DNA, adhesion molecules and angiogenesis together with the role of reactive oxygen species and other components of plasma. The outcome of first clinical trials regarding wound healing is pointed out.

  15. Disinfection of Staphylococcus Aureus by pulsed non-thermal atmospheric plasma jet

    Science.gov (United States)

    Mirpour, Shahriar; Ghoranneviss, Mahmood; Shahgoli, Farhad

    2011-10-01

    The aim of this paper was to study the effect of low-temperature atmospheric plasma jet on non-pathogenic bacteria's colonies. In this regard, Germicidal effect of time and distance of ICP He and He/N2 plasma jet on Staphylococcus Aureus were reported. The gas discharges were generated by a 40 KHz high voltage power supply which led to the inductively coupled plasma. The results showed that He/N2 enhance the sterilization time in comparison of He plasma. To the best of our knowledge this is the first study which has compared the effect of sterilization of ICP Helium and Helium-Nitrogen plasma in listed conditions. Also, the distance dependence showed that the germicidal effect was not linear the distance of electrode and sample. The protein leakage test and SEM of bacteria morphology confirmed the sterilization effect of non-thermal atmospheric pressure plasma jet.

  16. Thermal diffusivity effect in opto-thermal skin measurements

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, P; Imhof, R E [Faculty of ESBE, London South Bank University, 103 Borough Road, London SE1 0AA (United Kingdom); Cui, Y [Sunrise Systems Limited, Flint Bridge Business Centre, Ely Road, Waterbeach, Cambridge CB5 9QZ (United Kingdom); Ciortea, L I; Berg, E P, E-mail: xiaop@lsbu.ac.u [Biox Systems Ltd, 103 Borough Road, London SE1 0AA (United Kingdom)

    2010-03-01

    We present our latest study on the thermal diffusivity effect in opto-thermal skin measurements. We discuss how thermal diffusivity affects the shape of opto-thermal signal, and how to measure thermal diffusivity in opto-thermal measurements of arbitrary sample surfaces. We also present a mathematical model for a thermally gradient material, and its corresponding opto-thermal signal. Finally, we show some of our latest experimental results of this thermal diffusivity effect study.

  17. Novel Prospects for Plasma Spray-Physical Vapor Deposition of Columnar Thermal Barrier Coatings

    Science.gov (United States)

    Anwaar, Aleem; Wei, Lianglinag; Guo, Qian; Zhang, Baopeng; Guo, Hongbo

    2017-09-01

    Plasma spray-physical vapor deposition (PS-PVD) is an emerging coating technique that can produce columnar thermal barrier coatings from vapor phase. Feedstock treatment at the start of its trajectory in the plasma torch nozzle is important for such vapor-phase deposition. This study describes the effects of the plasma composition (Ar/He) on the plasma characteristics, plasma-particle interaction, and particle dynamics at different points spatially distributed inside the plasma torch nozzle. The results of calculations show that increasing the fraction of argon in the plasma gas mixture enhances the momentum and heat flow between the plasma and injected feedstock. For the plasma gas combination of 45Ar/45He, the total enthalpy transferred to a representative powder particle inside the plasma torch nozzle is highest ( 9828 kJ/kg). Moreover, due to the properties of the plasma, the contribution of the cylindrical throat, i.e., from the feed injection point (FIP) to the start of divergence (SOD), to the total transferred energy is 69%. The carrier gas flow for different plasma gas mixtures was also investigated by optical emission spectroscopy (OES) measurements of zirconium emissions. Yttria-stabilized zirconia (YSZ) coating microstructures were produced when using selected plasma gas compositions and corresponding carrier gas flows; structural morphologies were found to be in good agreement with OES and theoretical predictions. Quasicolumnar microstructure was obtained with porosity of 15% when applying the plasma composition of 45Ar/45He.

  18. Effects of SiO2 and TiO2 fillers on thermal and dielectric properties of eco-friendly bismuth glass microcomposites of plasma display panels

    Indian Academy of Sciences (India)

    Shiv Prakash Singh; Karan Pal; Anal Tarafder; Mousumi Das; Kalyandurg Annapurna; Basudeb Karmakar

    2010-02-01

    The effects of SiO2 (amorphous) and TiO2 (crystalline, rutile) fillers on softening point (s), glass transition temperature (g), coefficient of thermal expansion (CTE), and dielectric constant () of zinc bismuth borate, ZnO–Bi2O3–B2O3 (ZBIB) glass microcomposites have been investigated with a view to its use as the white back (rear glass dielectric layer) of plasma display panels (PDPs). The experimentally measured properties have also been compared with those of theoretically predicted values. Both the experimental and theoretical trends of these properties with added filler contents correlate very well. The interaction of fillers with glass which occurred during sintering at 560°C has also been monitored by XRD and FTIR spectroscopic analyses. The microstructures and distribution of fillers in the glass matrix have been analyzed by SEM images. It is observed that the fillers have partially dissolved in the glass at the firing temperature leaving some unreacted filler as residue which results in ceramic–glass microcomposites. In consideration of the desired properties of white back of PDPs, the addition of TiO2 filler to ZBIB glass is found to be more preferable than SiO2 filler. The addition of 10 wt% TiO2 filler yielded s, g, CTE and values of 560°C, 480°C, 82 × 10-7/K and 14.6 which are found to meet the desired values of < 580°C, < 500°C, < 83 × 10-7/K and < 15, respectively with respect to use of PD200 glass as substrate in PDP technology.

  19. Non-thermal Plasma Exposure Rapidly Attenuates Bacterial AHL-Dependent Quorum Sensing and Virulence

    Science.gov (United States)

    Flynn, Padrig B.; Busetti, Alessandro; Wielogorska, Ewa; Chevallier, Olivier P.; Elliott, Christopher T.; Laverty, Garry; Gorman, Sean P.; Graham, William G.; Gilmore, Brendan F.

    2016-01-01

    The antimicrobial activity of atmospheric pressure non-thermal plasma has been exhaustively characterised, however elucidation of the interactions between biomolecules produced and utilised by bacteria and short plasma exposures are required for optimisation and clinical translation of cold plasma technology. This study characterizes the effects of non-thermal plasma exposure on acyl homoserine lactone (AHL)-dependent quorum sensing (QS). Plasma exposure of AHLs reduced the ability of such molecules to elicit a QS response in bacterial reporter strains in a dose-dependent manner. Short exposures (30–60 s) produce of a series of secondary compounds capable of eliciting a QS response, followed by the complete loss of AHL-dependent signalling following longer exposures. UPLC-MS analysis confirmed the time-dependent degradation of AHL molecules and their conversion into a series of by-products. FT-IR analysis of plasma-exposed AHLs highlighted the appearance of an OH group. In vivo assessment of the exposure of AHLs to plasma was examined using a standard in vivo model. Lettuce leaves injected with the rhlI/lasI mutant PAO-MW1 alongside plasma treated N-butyryl-homoserine lactone and n-(3-oxo-dodecanoyl)-homoserine lactone, exhibited marked attenuation of virulence. This study highlights the capacity of atmospheric pressure non-thermal plasma to modify and degrade AHL autoinducers thereby attenuating QS-dependent virulence in P. aeruginosa. PMID:27242335

  20. Non-thermal Plasma Exposure Rapidly Attenuates Bacterial AHL-Dependent Quorum Sensing and Virulence.

    Science.gov (United States)

    Flynn, Padrig B; Busetti, Alessandro; Wielogorska, Ewa; Chevallier, Olivier P; Elliott, Christopher T; Laverty, Garry; Gorman, Sean P; Graham, William G; Gilmore, Brendan F

    2016-05-31

    The antimicrobial activity of atmospheric pressure non-thermal plasma has been exhaustively characterised, however elucidation of the interactions between biomolecules produced and utilised by bacteria and short plasma exposures are required for optimisation and clinical translation of cold plasma technology. This study characterizes the effects of non-thermal plasma exposure on acyl homoserine lactone (AHL)-dependent quorum sensing (QS). Plasma exposure of AHLs reduced the ability of such molecules to elicit a QS response in bacterial reporter strains in a dose-dependent manner. Short exposures (30-60 s) produce of a series of secondary compounds capable of eliciting a QS response, followed by the complete loss of AHL-dependent signalling following longer exposures. UPLC-MS analysis confirmed the time-dependent degradation of AHL molecules and their conversion into a series of by-products. FT-IR analysis of plasma-exposed AHLs highlighted the appearance of an OH group. In vivo assessment of the exposure of AHLs to plasma was examined using a standard in vivo model. Lettuce leaves injected with the rhlI/lasI mutant PAO-MW1 alongside plasma treated N-butyryl-homoserine lactone and n-(3-oxo-dodecanoyl)-homoserine lactone, exhibited marked attenuation of virulence. This study highlights the capacity of atmospheric pressure non-thermal plasma to modify and degrade AHL autoinducers thereby attenuating QS-dependent virulence in P. aeruginosa.

  1. EDITORIAL: Non-thermal plasma-assisted fuel conversion for green chemistry Non-thermal plasma-assisted fuel conversion for green chemistry

    Science.gov (United States)

    Nozaki, Tomohiro; Gutsol, Alexander

    2011-07-01

    -generated reactive species are used to initiate chemical reactions at unexpectedly lower temperatures than conventional thermochemical reactions, leading to non-equilibrium product distribution or creating unconventional reaction pathways. When non-thermal plasma is combined with catalysts, a synergistic effect is frequently observed. Such unique properties of non-thermal plasma are expected to contribute excellent control over process parameters that meet the need for energy saving, environment protection, and material preservation. This special issue consists of eleven peer-reviewed papers including two invited publications. Professors Alexander Fridman and Alexander Rabinovich from Drexel University, and Dr Gutsol from the Chevron Energy Technology Company present a critical review of various industry-oriented practical plasma fuel conversion processes. Professor Richard Mallinson from University of Oklahoma describes his recent project on E85 (85%-ethanol/15%-gasoline) upgrading using non-thermal plasma and catalyst hybrid reactor, and highlights the synergistic effect on fuel conversion processes. Other papers focus on plasma/catalyst hybrid reactions for methane dry (CO2) reforming, plasma synthesis of carbon suboxide polymer from CO, the gas-to-liquid (GTL) process using a non-thermal plasma-combined micro-chemical reactor, and molecular beam characterization of plasma-generated reactive species. Much research regarding plasma catalysis is ongoing worldwide, but there is plenty of room for further development of plasma fuel processing, which could eventually provide a viable and flexible solution in future energy and material use. Finally, we would like to thank all symposium participants for their active discussion. We appreciate the sponsorship of the Division of Fuel Chemistry of the American Chemical Society. We express special thanks to the program chair of the Fuel Chemistry Division, Professor Chang-jun Liu at Tianjin University, for his dedication to the success of

  2. Suppression of thermal conduction in a mirror-unstable plasma

    CERN Document Server

    Komarov, S V; Kunz, M W; Schekochihin, A A

    2016-01-01

    The ICM plasma is subject to firehose and mirror instabilities at scales of order the ion Larmor radius. The mirror instability generates fluctuations of magnetic-field strength $\\delta B / B \\sim 1$. These fluctuations act as magnetic traps for the heat-conducting electrons, suppressing their transport. We calculate the effective parallel thermal conductivity in the ICM in the presence of the mirror fluctuations for different stages of the evolution of the instability. The mirror fluctuations are limited in amplitude by the maximum and minimum values of the field strength, with no large deviations from the mean value. This key property leads to a finite suppression of thermal conduction at large scales. We find suppression down to $\\approx 0.2$ of the Spitzer value for the secular phase of the perturbations' growth, and $\\approx 0.3$ for their saturated phase. The effect operates in addition to other suppression mechanisms and independently of them. Globally, fluctuations $\\delta B / B \\sim 1$ can be present...

  3. Thermal condensation mode in a dusty plasma

    Indian Academy of Sciences (India)

    B P Pandey; J Vranješ; S Parhi

    2003-03-01

    In the present work, the radiative condensation instability is investigated in the presence of dust charge fluctuations. We find that the charge variability of the grain reduces the growth rate of radiative mode only for fluctuation wavelength smaller or of the order of the Debye length and this reduction is not very large. Far from the Debye sphere, radiative mode can damp due to thermal conduction of electrons and ions.

  4. Development of non-thermal atmospheric pressure plasma system for surface modification of polymeric materials

    Science.gov (United States)

    Kasih, T. P.

    2017-04-01

    Non-thermal plasma has become one of the new technologies which are highly developed now days. This happens because the cold plasma using the principle of generated reactive gases that have the ability to modify the surface properties of a material or product without changing the original characteristics of the material. The purpose of this study is to develop a cold plasma system that operates at atmospheric pressure and investigates the effect of cold plasma treatment to change the surface characteristics of the polymer material polyethylene (PE) at various time conditions. We are successfully developing a non-thermal plasma system that can operate at atmospheric pressure and can be run with Helium or Argon gas. The characteristics of plasma will be discussed from the view of its electrical property, plasma discharge regime andoperation temperature. Experiment results on plasma treatment on PE material shows the changes of surface properties of originally hydrophobic material PE becomes hydrophilic by only few seconds of plasma treatment and level of hydrophilicity become greater with increasing duration of plasma treatment. Confirmation of this is shown by the measurement of contact angle of droplets of water on the surface of PE are getting smaller.

  5. Non-thermal plasma treatment of hydrogen sulfide

    Energy Technology Data Exchange (ETDEWEB)

    Frost, L.J.; Hartvigsen, J.; Elangovan, S. [Ceramatec Inc., Salt Lake City, UT (United States)

    2009-07-01

    This paper described a non-thermal plasma reforming process to treat hydrogen sulfide (H{sub 2}S) in heavy hydrocarbons. H{sub 2}S is present in natural gas, petroleum, and various process gases. It is an unwanted compound that is generally removed using an amine extraction process followed by a Claus process. Ceramatec Inc. has developed a GlidArc plasma reformer to recover some of the hydrogen from the H{sub 2}S. Non-thermal plasma reforming breaks hydrogen sulfide into hydrogen and elemental sulphur. Ceramatec has established the catalytic nature of the non-thermal plasma generated by its GlidArc plasma reformer. This treatment process is still in the laboratory stage, but it offers the possibility of a new method to treat acid gas that will provide an opportunity to recover hydrogen that is currently burned to water during the Claus sulphur removal process. Ceramatec, in conjunction with Albin Czernichowski of ECP in France, has demonstrated the ability to reform a variety of hydrocarbons using the non-thermal plasma catalyzed reaction. The plasma reaction can be initiated in either a partial oxidation or steam reforming mode. Multiple hydrocarbons can be processed by the same unit with only control parameters changing to meet the requirements of the individual hydrocarbons being processed. Although a tested unit did not accomplish complete conversion, some additional options will be tested that are expected to increase the conversion under an existing program operated by the United States Department of Energy. 4 refs., 9 figs.

  6. Final treatment of spent batteries by thermal plasma.

    Science.gov (United States)

    Cubas, Anelise Leal Vieira; Machado, Marina de Medeiros; Machado, Marília de Medeiros; Dutra, Ana Regina de Aguiar; Moecke, Elisa Helena Siegel; Fiedler, Haidi D; Bueno, Priscila

    2015-08-15

    The growth in the use of wireless devices, notebooks and other electronic products has led to an ever increasing demand for batteries, leading to these products being commonly found in inappropriate locations, with adverse effects on the environment and human health. Due to political pressure and according to the environmental legislation which regulates the destination of spent batteries, in several countries the application of reverse logistics to hazardous waste is required. Thus, some processes have been developed with the aim of providing an appropriate destination for these products. In this context, a method for the treatment of spent batteries using thermal plasma technology is proposed herein. The efficiency of the method was tested through the determination of parameters, such as total organic carbon, moisture content and density, as well as analysis by atomic absorption spectrometry, scanning electron microscopy and X-ray fluorescence using samples before and after inertization. The value obtained for the density was 19.15%. The TOC results indicated 8.05% of C in the batteries prior to pyrolisis and according to the XRF analysis Fe, S, Mn and Zn were the most stable elements in the samples (highest peaks). The efficiency of the paste inertization was 97% for zinc and 99.74% for manganese. The results also showed that the most efficient reactor was that with the DC transferred arc plasma torch and quartzite sand positively influenced by the vitrification during the pyrolysis of the electrolyte paste obtain from batteries.

  7. Carbon Dioxide Reforming of Methane to Syngas by Thermal Plasma

    Institute of Scientific and Technical Information of China (English)

    孙艳朋; 聂勇; 吴昂山; 姬登祥; 于凤文; 计建炳

    2012-01-01

    Experiments were conducted on syngas preparation from dry reforming of methane by carbon dioxide with a DC arc plasma at atmospheric pressure. In all experiments, nitrogen gas was used as the working gas for thermal plasma to generate a high-temperature jet into a horizontal tube reactor. A mixture of methane and carbon dioxide was fed vertically into the jet. In order to obtain a higher conversion rate of methane and carbon dioxide, chemical energy efficiency and fuel production efficiency, parametric screening studies were conducted, in which the volume ratio of carbon dioxide to methane in fed gases and the total flux of fed gases were taken into account. Results showed that carbon dioxide reforming of methane to syngas by thermal plasma exhibited a larger processing capacity, higher conversion of methane and carbon dioxide and higher chemical energy efficiency and fuel production efficiency. In addition, thermodynamic simulation for the reforming process was conducted. Experimental data agreed well with the thermodynamic results, indicating that high thermal efficiency can be achieved with the thermal plasma reforming process.

  8. Thermal Plasma Synthesis of Superparamagnetic Iron Oxide Nanoparticles

    NARCIS (Netherlands)

    Lei, P.Y.; Boies, A.M.; Calder, S.A.; Girshick, S.L.

    2012-01-01

    Superparamagnetic iron oxide nanoparticles were synthesized by injecting ferrocene vapor and oxygen into an argon/helium DC thermal plasma. Size distributions of particles in the reactor exhaust were measured online using an aerosol extraction probe interfaced to a scanning mobility particle sizer,

  9. Evolution of the construction and performances in accordance to the applications of non-thermal plasma reactors

    Science.gov (United States)

    Hnatiuc, B.; Brisset, J. L.; Astanei, D.; Ursache, M.; Mares, M.; Hnatiuc, E.; Felea, C.

    2016-12-01

    This paper aims to present the evolution of the construction and performances of non-thermal plasma reactors, identifying specific requirements for various known applications, setting out quality indicators that would allow on the one hand comparing devices that use different kinds of electrical discharges but also their rigorous classification by identification of criteria in order to choose the correct cold plasma reactors for a specific application. It briefly comments the post-discharge effect but also the current dilemma on non-thermal plasma direct treatments versus indirect treatments, using plasma activated water (PAW) or plasma activated medium (PAM), promising in cancer treatment.

  10. Ion streaming instabilities in pair ion plasma and localized structure with non-thermal electrons

    Energy Technology Data Exchange (ETDEWEB)

    Khattak, M. Nasir; Qamar, A., E-mail: mnnasirphysics@gmail.com [Department of Physics, University of Peshawar (Pakistan); Mushtaq, A. [Department of Physics, Abdul Wali Khan University Mardan, National Center for Physics, Mardan (Pakistan)

    2015-12-15

    Pair ion plasma with a fraction of non-thermal electrons is considered. We investigate the effects of the streaming motion of ions on linear and nonlinear properties of unmagnetized, collisionless plasma by using the fluid model. A dispersion relation is derived, and the growth rate of streaming instabilities with effect of streaming motion of ions and non-thermal electrons is calculated. A quasi-potential approach is adopted to study the characteristics of ion acoustic solitons. An energy integral equation involving Sagdeev potential is derived during this process. The presence of the streaming term in the energy integral equation affects the structure of the solitary waves significantly along with non-thermal electrons. Possible application of the work to the space and laboratory plasmas are highlighted. (author)

  11. Antitumor action of non thermal plasma sources, DBD and Plasma Gun, alone or in combined protocols

    Science.gov (United States)

    Robert, Eric; Brullé, Laura; Vandamme, Marc; Riès, Delphine; Le Pape, Alain; Pouvesle, Jean-Michel

    2012-10-01

    The presentation deals with the assessment on two non thermal plasma sources developed and optimized for oncology applications. The first plasma source is a floating-electrode dielectric barrier discharge powered at a few hundreds of Hz which deliver air-plasma directly on the surface of cell culture medium in dishes or on the skin or organs of mice bearing cancer tumors. The second plasma source, so called Plasma Gun, is a plasma jet source triggered in noble gas, transferred in high aspect ratio and flexible capillaries, on targeting cells or tumors after plasma transfer in air through the ``plasma plume'' generated at the capillary outlet. In vitro evidence for massive cancer cell destruction and in vivo tumor activity and growth rate reductions have been measured with both plasma sources. DNA damages, cell cycle arrests and apoptosis induction were also demonstrated following the application of any of the two plasma source both in vitro and in vivo. The comparison of plasma treatment with state of the art chemotherapeutic alternatives has been performed and last but not least the benefit of combined protocols involving plasma and chemotherapeutic treatments has been evidenced for mice bearing orthotopic pancreas cancer and is under evaluation for the colon tumors.

  12. Preparation of spherical hollow alumina particles by thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Wonkyung [Department of Chemical Engineering, INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Regional Innovation Center for Environmental Technology of Thermal Plasma (RIC-ETTP), INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Choi, Sooseok [Center for Advance Research in Fusion Reactor Engineering, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151‐742 (Korea, Republic of); Oh, Seung-Min [Daejoo Electronic Materials Co., 1236‐10 Jeongwang-dong, Siheung-si, Kyunggi-do 429‐848 (Korea, Republic of); Park, Dong-Wha, E-mail: dwpark@inha.ac.kr [Department of Chemical Engineering, INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Regional Innovation Center for Environmental Technology of Thermal Plasma (RIC-ETTP), INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of)

    2013-02-01

    Spherical hollow particles were prepared from solid alumina powders using DC arc thermal plasma, and then spray coating was performed with the as-prepared particles. Operating variables for the hollow particle preparation process were additional plasma gas, input power, and carrier gas flow rate. The spherical hollow alumina particles were produced in the case of using additive gas of H{sub 2} or N{sub 2}, while alumina surface was hardly molten in the pure argon thermal plasma. In addition, the hollow particles were well produced in high power and low carrier gas conditions due to high melting point of alumina. Hollow structure was confirmed by focused ion beam-scanning electron microscopy analysis. Morphology and size distribution of the prepared particles that were examined by field emission-scanning electron microscopy and phase composition of the particles was characterized by X-ray diffraction. In the spray coating process, the as-prepared hollow particles showed higher deposition rate. - Highlights: ► Spherical hollow alumina powder was prepared by non-transferred DC arc plasma. ► Diatomic gasses were added in Ar plasma for high power. ► Prepared hollow alumina powder was efficient for the plasma spray coating.

  13. Analysis of Residual Thermal Stress in CVD-W Coating as Plasma Facing Material

    Institute of Scientific and Technical Information of China (English)

    朱大焕; 王坤; 王先平; 陈俊凌; 方前锋

    2012-01-01

    Chemical vapor deposition-tungsten (CVD-W) coating covering the surface of the plasma facing component (PFC) is an effective method to implement the tungsten material as plasma facing material (PFM) in fusion devices. Residual thermal stress in CVD-W coating due to thermal mismatch between coating and substrate was successfully simulated by using a finite element method (ANSYS 10.0 code). The deposition parametric effects, i.e., coating thickness and deposition temperature, and interlayer were investigated to get a description of the residual thermal stress in the CVD-W coating-substrate system. And the influence of the substrate materials on the generation of residual thermal stress in the CVD-W coating was analyzed with respect to the CVD-W coating application as PFM. This analysis is beneficial for the preparation and application of CVD-W coating.

  14. Analysis of Residual Thermal Stress in CVD-W Coating as Plasma Facing Material

    Science.gov (United States)

    Zhu, Dahuan; Wang, Kun; Wang, Xianping; Chen, Junling; Fang, Qianfeng

    2012-07-01

    Chemical vapor deposition-tungsten (CVD-W) coating covering the surface of the plasma facing component (PFC) is an effective method to implement the tungsten material as plasma facing material (PFM) in fusion devices. Residual thermal stress in CVD-W coating due to thermal mismatch between coating and substrate was successfully simulated by using a finite element method (ANSYS 10.0 code). The deposition parametric effects, i.e., coating thickness and deposition temperature, and interlayer were investigated to get a description of the residual thermal stress in the CVD-W coating-substrate system. And the influence of the substrate materials on the generation of residual thermal stress in the CVD-W coating was analyzed with respect to the CVD-W coating application as PFM. This analysis is beneficial for the preparation and application of CVD-W coating.

  15. Sterilization of Staphylococcus Aureus by an Atmospheric Non-Thermal Plasma Jet

    Science.gov (United States)

    Liu, Xiaohu; Hong, Feng; Guo, Ying; Zhang, Jing; Shi, Jianjun

    2013-05-01

    An atmospheric non-thermal plasma jet was developed for sterilizing the Staphylococcus aureus (S. aureus). The plasma jet was generated by dielectric barrier discharge (DBD), which was characterized by electrical and optical diagnostics. The survival curves of the bacteria showed that the plasma jet could effectively inactivate 106 cells of S. aureus within 120 seconds and the sterilizing efficiency depended critically on the discharge parameter of the applied voltage. It was further confirmed by scanning electron microscopy (SEM) that the cell morphology was seriously damaged by the plasma treatment. The plasma sterilization mechanism of S. aureus was attributed to the active species of OH, N2+ and O, which were generated abundantly in the plasma jet and characterized by OES. Our findings suggest a convenient and low-cost way for sterilization and inactivation of bacteria.

  16. Functionalization of alkyne-terminated thermally hydrocarbonized porous silicon nanoparticles with targeting peptides and antifouling polymers: effect on the human plasma protein adsorption.

    Science.gov (United States)

    Wang, Chang-Fang; Mäkilä, Ermei M; Bonduelle, Colin; Rytkönen, Jussi; Raula, Janne; Almeida, Sérgio; Närvänen, Ale; Salonen, Jarno J; Lecommandoux, Sebastien; Hirvonen, Jouni T; Santos, Hélder A

    2015-01-28

    Porous silicon (PSi) nanomaterials combine a high drug loading capacity and tunable surface chemistry with various surface modifications to meet the requirements for biomedical applications. In this work, alkyne-terminated thermally hydrocarbonized porous silicon (THCPSi) nanoparticles were fabricated and postmodified using five bioactive molecules (targeting peptides and antifouling polymers) via a single-step click chemistry to modulate the bioactivity of the THCPSi nanoparticles, such as enhancing the cellular uptake and reducing the plasma protein association. The size of the nanoparticles after modification was increased from 176 to 180-220 nm. Dextran 40 kDa modified THCPSi nanoparticles showed the highest stability in aqueous buffer. Both peptide- and polymer-functionalized THCPSi nanoparticles showed an extensive cellular uptake which was dependent on the functionalized moieties presented on the surface of the nanoparticles. The plasma protein adsorption study showed that the surface modification with different peptides or polymers induced different protein association profiles. Dextran 40 kDa functionalized THCPSi nanoparticles presented the least protein association. Overall, these results demonstrate that the "click" conjugation of the biomolecules onto the alkyne-terminated THCPSi nanoparticles is a versatile and simple approach to modulate the surface chemistry, which has high potential for biomedical applications.

  17. Plasma spray for forming nanostructured thermal barrier coatings

    Institute of Scientific and Technical Information of China (English)

    LIN; Feng; JIANG; Xian-liang; YU; Yue-guang; ZENG; Ke-li; REN; Xian-jing

    2005-01-01

    Nanocrystalline powders of yttrium partially stabilized zirconia (YPSZ) are reprocessed into agglomerated feedstocks for plasma spraying thermal barrier coatings (TBCs), using the methods of ball milling, slurry dispersion, spray drying, and heat treatment. Atmospheric plasma is used to spray the agglomerated nanocrystalline particle feedstocks and coatings were deposited on the substrate of Ni-based superalloy. Scanning electron microscopy (SEM) is used to examine the morphology and cross-section of the agglomerated feedstocks and the free-section and cross-section of the nanostructured TBCs. Experimental results show that the agglomerated nanocrystalline particles are spherical and dense. Unlike conventional plasma-sprayed coatings, the micron/nano/micron sandwich structure can be found in the nanostructured YPSZ coatings deposited by atmospheric plasma spraying.

  18. Optimization simulation of thermal plasma reactor for acetylene production from coal

    Energy Technology Data Exchange (ETDEWEB)

    Yang, J.; Yang, Y.; Bao, W.; Zhang, Y.; Kie, K. [Taiyuan University of Technology, Taiyuan (China)

    2007-07-01

    A heat-flow field mathematical model based on the computational; fluid dynamics (CFD) technique was developed for a thermal plasma reactor in order to optimize the reactor structure and operation conditions for the direct production of acetylene from coal. The simulation of the thermal plasma reactor with single inlet, double inlet and double inlet with protective gas was given; simulations of the heat-flow coupling field were carried out by using the method of Incomplete Cholesky Conjugate Gradient (ICCG). The optimization simulation results show that the load of the thermal plasma reactor with double inlet is increased, and the reactor wall surface coke is depressed. The anticoking effect is best under the gas flow rate of 50 m/s. 4 refs., 4 figs.

  19. Characterization of thermal and current quench of JET plasmas

    Science.gov (United States)

    Riccardo, V.; Barabaschi, P.; Loarte, A.; Sugihara, M.

    2004-11-01

    JET provides crucial scaling points and unique physics access for the extrapolation of disruptions to ITER. Disruption and ELM heat loads influence the selection of materials for plasma facing components (PFCs). Most JET thermal quenches occur when the plasma thermal energy is less than half that at full performance, suggesting a more optimistic life expectancy for ITER PFCs. The exceptions are ITB collapses and pure VDEs, which are also more likely to lead to the shortest thermal quenches. For the fast current quench disruptions, the EM load due to the induced eddy currents represent the most severe electromechanical design condition for in-vessel components. The minimum linear decay time normalised to the plasma cross section extrapolates to a 40 ms disruption for ITER, based on data from JET and most other tokamaks. Some very fast JET events are better fit by an exponential, with the minimum characteristic current decay time scaling to 35 ms for ITER. Contrary to expectations, the quench rate of high and low thermal energy disruptions does not vary substantially.

  20. Desorption of isopropyl alcohol from adsorbent with non-thermal plasma.

    Science.gov (United States)

    Shiau, Chen Han; Pan, Kuan Lun; Yu, Sheng Jen; Yan, Shaw Yi; Chang, Moo Been

    2016-11-24

    Effective desorption of isopropyl alcohol (IPA) from adsorbents with non-thermal plasma is developed. In this system, IPA is effectively adsorbed with activated carbon while dielectric barrier discharge is applied to replace the conventional thermal desorption process to achieve good desorption efficiency, making the treatment equipment smaller in size. Various adsorbents including molecular sieves and activated carbon are evaluated for IPA adsorption capacity. The results indicate that BAC has the highest IPA adsorption capacity (280.31 mg IPA/g) under the operating conditions of room temperature, IPA of 400 ppm, and residence time of 0.283 s among 5 adsorbents tested. For the plasma desorption process, the IPA selectivity of 89% is achieved with BAC as N2 is used as desorbing gas. In addition, as air or O2 is used as desorbing gas, the IPA desorption concentration is reduced, because air and O2 plasmas generate active species to oxidize IPA to form acetone, CO2, and even CO. Furthermore, the results of the durability test indicate that the amount of IPA desorbed increases with increasing desorption times and plasma desorption process has a higher energy efficiency if compared with thermal desorption. Overall, this study indicates that non-thermal plasma is a viable process for removing VOCs to regenerate adsorbent.

  1. Thermal cycling characteristics of plasma synthesized mullite films

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, O.R.; Hou, P.Y.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1997-12-01

    The authors have developed a plasma-based technique for the synthesis of mullite and mullite-like films on silicon carbide substrate material. The method, which they refer to as MePIIID (for Metal Plasma Immersion Ion Implantation and Deposition), uses two vacuum arc plasma sources and simultaneous pulse biasing of the substrate in a low pressure oxygen atmosphere. The Al:Si ratio can be controlled via the separate plasma guns, and the film adhesion, structure and morphology can be controlled via the ion energy which in turn is controlled by the pulse bias voltage. The films are amorphous as-deposited, and crystalline mullite is formed by subsequent annealing at 1000 C for 2 hours in air. Adhesion between the aluminum-silicon oxide film and the substrate increases after this first annealing. They have tested the behavior of films when subjected to repetitive thermal cycling between room temperature and 1100 C, and found that the films retain their adhesion and quality. Here they review the plasma synthesis technique and the characteristics of the mullite films prepared in this way, and summarize the status of the thermal cycling experiments.

  2. High Temperature Thermal Properties of Columnar Yttria Stabilized Zirconia Thermal Barrier Coating Performed by Suspension Plasma Spraying

    Science.gov (United States)

    Bernard, B.; Schick, V.; Remy, B.; Quet, A.; Bianchi, L.

    2016-09-01

    Performance enhancement of gas turbines is a main issue for the aircraft industry. Over many years, a large part of the effort has been focused on the development of more insulating Thermal Barrier Coatings (TBCs). In this study, Yttria Stabilized Zirconia (YSZ) columnar structures are processed by Suspension Plasma Spraying (SPS). These structures have already demonstrated abilities to get improved thermal lifetime, similarly to standard YSZ TBCs performed by EB-PVD. Thermal diffusivity measurements coupled with differential scanning calorimetry analysis are performed from room temperature up to 1100 °C, first, on HastelloyX substrates and then, on bilayers including a SPS YSZ coating. Results show an effective thermal conductivity for YSZ performed by SPS lower than 1 W.m-1K-1 whereas EB- PVD YSZ coatings exhibit a value of 1.5 W.m-1K-1.

  3. Experimental studies on removal of airborne haloanisoles by non-thermal plasma air purifiers

    DEFF Research Database (Denmark)

    Fang, Lei; Hallam, David; Bermúdez, Raúl

    2016-01-01

    A laboratory study was conducted to test the performance of non-thermal plasma air purifiers on its removal effectiveness of two haloanisoles – 2,4,6-trichloroanisole (TCA) and 2,4,6-Tribromoanisole (TBA). TCA and TBA are the two major compounds found in wine cellars that can contaminate wine...... to produce unpalatable mouldy and musty tastes. The test was first conducted in a climate chamber. The plasma air purifier was installed in a test rig developed for the testing and challenged by airflow with certain concentrations of TCA and TBA. Air samples upstream and downstream of the air purifier...... was collected by Tenax tubes and the concentration of TCA and TBA were analyzed by thermal desorption GC–MS. The results showed that the plasma air purifier was effective on removing TCA and TBA with a single pass efficiency of better than 82%. The effect was further validated in a wine cellar under a realistic...

  4. Relativistic self-focusing of intense laser beam in thermal collisionless quantum plasma with ramped density profile

    Science.gov (United States)

    Zare, S.; Yazdani, E.; Rezaee, S.; Anvari, A.; Sadighi-Bonabi, R.

    2015-04-01

    Propagation of a Gaussian x-ray laser beam has been analyzed in collisionless thermal quantum plasma with considering a ramped density profile. In this density profile due to the increase in the plasma density, an earlier and stronger self-focusing effect is noticed where the beam width oscillates with higher frequency and less amplitude. Moreover, the effect of the density profile slope and the initial plasma density on the laser propagation has been studied. It is found that, by increasing the initial density and the ramp slope, the laser beam focuses faster with less oscillation amplitude, smaller laser spot size and more oscillations. Furthermore, a comparison is made among the laser self-focusing in thermal quantum plasma, cold quantum plasma and classical plasma. It is realized that the laser self-focusing in the quantum plasma becomes stronger in comparison with the classical regime.

  5. EXAFS investigation of nanoparticles produced in a thermal plasma process

    Energy Technology Data Exchange (ETDEWEB)

    Luetzenkirchen-Hecht, D.; Frahm, R. [Heinrich-Heine-Univ. Duesseldorf, Inst. fuer Angewandte Physik (Germany); Buchner, P. [Heinrich-Heine-Univ. Duesseldorf, Inst. fuer Laser- und Plasmaphysik (Germany); Strehblow, H.H. [Heinrich-Heine-Univ., Inst. fuer Physikalische Chemie (Germany)

    1999-11-01

    Nanosized ceramic powders (Cu/SiC, Y{sub 2}O{sub 3}-stabilized cubic ZrO{sub 2}) were produced by evaporation of coarsely grained powders of the respective materials in an inductively coupled thermal plasma process and rapid quenching of the vapor. The atomic short range order of these nanoparticles with an average diameter of about 10 nm was investigated ex situ with EXAFS. The results are compared to crystalline reference materials. (au) 10 refs.

  6. Study of Purification Effects of Air Cleaners with Non-thermal Plasma on Indoor Particular Matter%含NTP技术净化器对室内颗粒物的净化效果

    Institute of Scientific and Technical Information of China (English)

    陆海全; 丁志威; 颜凯; 梅敏花; 郭婷; 钟依均; 谢云龙

    2015-01-01

    选择几款国内含有低温等离子体( Non-thermal plasma, NTP)技术的空气净化器( air cleaner)样机,以香烟烟雾为净化对象,研究其对室内空气中颗粒物的净化效果。结果表明,所选用空气净化器对100 nm以上颗粒物有一定的去除效果,对100 nm以下的颗粒物几乎没有净化效果;单一采用低温等离子体净化技术对颗粒物的去除不理想;高效粒子过滤器( HEPA, High efficiency particulate air Filter)对颗粒物的净化起着关键作用。%Using cigarette smoke as the purification target, the purification effects of several residential air cleaners containing non-thermal plasma ( NTP) technology on indoor particulate matter in air were studied. The results showed that the selected air cleaners had a certain effect on removal of particles above 100 nm while had few effects for particles below 100 nm. Single use of NTP purification technology was not effective to remove particulate matter. HEPA technology played a key role in eliminating the particulate matter.

  7. Removal NO with non-thermal plasma assisted catalyst modified activated carbon from coal

    Energy Technology Data Exchange (ETDEWEB)

    Chen, M.G. [Toyahashi Univ. of Technology, Toyohashi, Aichi (Japan). Dept. of Ecological Engineering; Anhui Univ. of Science and Technology, Huainan, Anhui (China). School of Chemical Engineering; Takashima, T.; Mizuno, A. [Toyahashi Univ. of Technology, Toyohashi, Aichi (Japan). Dept. of Ecological Engineering

    2010-07-01

    Non-thermal plasma can produce a significant number of free electrons, ions, reactive free radicals and a variety of free particles in excited states, containing a large number of active atomic oxygen (O) and higher activity energy so it can increase the chemical reaction rate. An effective way to generate the non-thermal plasma is through dielectric barrier discharge (DBD). There are three types of dielectric barrier discharge reactors: wire (or bar)-cylinder; wire-plate; and plate-plate structure. This paper examined the effect of gas concentration, space velocity, catalyst loading volume, and the input voltage on the removal ratio of nitric oxide (NO) in the process of non-thermal plasma assisted with modified activated carbon from coal. A form of bar-cylinder reactor was used and combined with a catalyst of modified activated carbon from coal. The catalyst was packed between the bar and the cylinder in the fixed bed reactor. It was concluded that a non-thermal plasma assisted catalyst which modifies activated carbon from coal is an effective way to remove NO, and the input voltage, gas concentration, gas space velocity and the catalyst packed weight has a certain degree of impact on the NO removal ratio. 17 refs., 7 figs.

  8. Ion acoustic solitary waves in plasmas with nonextensive distributed electrons, positrons and relativistic thermal ions

    Science.gov (United States)

    Hafez, M. G.; Talukder, M. R.; Sakthivel, R.

    2016-05-01

    The theoretical and numerical studies have been investigated on nonlinear propagation of weakly relativistic ion acoustic solitary waves in an unmagnetized plasma system consisting of nonextensive electrons, positrons and relativistic thermal ions. To study the characteristics of nonlinear propagation of the three-component plasma system, the reductive perturbation technique has been applied to derive the Korteweg-de Vries equation, which divulges the soliton-like solitary wave solution. The ansatz method is employed to carry out the integration of this equation. The effects of nonextensive electrons, positrons and relativistic thermal ions on phase velocity, amplitude and width of soliton and electrostatic nonlinear propagation of weakly relativistic ion acoustic solitary waves have been discussed taking different plasma parameters into consideration. The obtained results can be useful in understanding the features of small amplitude localized relativistic ion acoustic solitary waves in an unmagnetized three-component plasma system for hard thermal photon production with relativistic heavy ions collision in quark-gluon plasma as well as for astrophysical plasmas.

  9. Pre-treating water with non-thermal plasma

    Science.gov (United States)

    Cho, Young I.; Fridman, Alexander; Rabinovich, Alexander; Cho, Daniel J.

    2017-07-04

    The present invention consists of a method of pre-treatment of adulterated water for distillation, including adulterated water produced during hydraulic fracturing ("fracking") of shale rock during natural gas drilling. In particular, the invention is directed to a method of treating adulterated water, said adulterated water having an initial level of bicarbonate ion in a range of about 250 ppm to about 5000 ppm and an initial level of calcium ion in a range of about 500 ppm to about 50,000 ppm, said method comprising contacting the adulterated water with a non-thermal arc discharge plasma to produce plasma treated water having a level of bicarbonate ion of less than about 100 ppm. Optionally, the plasma treated water may be further distilled.

  10. Review of mercury removal from flue gas using non-thermal plasma technology

    Directory of Open Access Journals (Sweden)

    Tao Zhu

    2014-06-01

    Full Text Available Mercury with various constituents in flue gas produced by burning coal could be an attractive alternative to non-thermal plasma process for mercury control. The mechanism of removal for pollutants using non-thermal plasma technology and the electric discharge form of non-thermal plasma are introduced. Then, we summary the research progress of mercury removal by non-thermal plasma in recent years, especially focus on how to oxide the elemental mercury from flue gas. We hope the non-thermal plasma technology can be improved to apply in the industry in the near future.

  11. Porous materials produced from incineration ash using thermal plasma technology.

    Science.gov (United States)

    Yang, Sheng-Fu; Chiu, Wen-Tung; Wang, To-Mai; Chen, Ching-Ting; Tzeng, Chin-Ching

    2014-06-01

    This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9-1.2 g cm(-3) and 50-60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m(-1) K(-1). Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Alleviative effects of α-lipoic acid supplementation on acute heat stress-induced thermal panting and the level of plasma nonesterified fatty acids in hypothyroid broiler chickens.

    Science.gov (United States)

    Hamano, Y

    2012-01-01

    1. The present study was conducted to examine the effects of α-lipoic acid on hypothyroidism-induced negative growth performance and whether α-lipoic acid alleviates acute heat stress in relation to hypothyroid status. 2. Female broiler chickens (14 d-old) were fed diets supplemented with α-lipoic acid (100 mg/kg) and an antithyroid substance, propylthiouracil (200 mg/kg), for 20 d under thermoneutral conditions (25°C). At 42 d of age, chickens were exposed to a high ambient temperature (36°C, 60% RH) for 4 h. 3. Under the thermoneutral condition, propylthiouracil administration decreased feed efficiency and concomitantly increased adipose tissue and thyroid gland weights. Plasma nonesterified fatty acids and triacylglycerol were also increased by propylthiouracil administration. However, α-lipoic acid supplementation did not affect the hypothyroidism-induced effects. 4. In hypothyroid chickens, the rise in respiratory rate induced by heat exposure was greatly inhibited by α-lipoic acid administration at 1 h, but this effect had disappeared at 4 h. In addition, a similar inhibitory effect on the concentrations of plasma nonesterified fatty acids was subsequently observed at 4 h. 5. Therefore, the present study suggested that α-lipoic acid alleviates acute heat stress if chickens are in a hypothyroid status.

  13. Non-thermal atmospheric plasma brush induces HEMA grafting onto dentin collagen

    Science.gov (United States)

    Chen, Mingsheng; Zhang, Ying; Dusevich, Vladimir; Liu, Yi; Yu, Qingsong; Wang, Yong

    2014-01-01

    Objective Non-thermal atmospheric plasma (NTAP) brush has been regarded as a promising technique to enhance dental interfacial bonding. However, the principal enhancement mechanisms have not been well identified. In this study, the effect of non-thermal plasmas on grafting of HEMA, a typical dental monomer, onto dentin collagen thin films was investigated. Methods Human dentin was sectioned into 10-um-thick films. After total demineralization in 0.5 M EDTA solution for 30 min, the dentin collagen films were water-rinsed, air-dried, treated with 35 wt% HEMA aqueous solution. The films were then subject to plasma-exposure under a NTAP brush with different time (1–8 min) / input power (5–15 w). For comparison, the dentin collagen films were also treated with the above HEMA solution containing photo-initiators, then subject to light-curing. After plasma-exposure or light-curing, the HEMA-collagen films were rinsed in deionized water, and then examined by FTIR spectroscopy and TEM. Results The FITR results indicated that plasma-exposure could induce significant HEMA grafting onto dentin collagen thin films. In contrast, light-curing led to no detectable interaction of HEMA with dentin collagen. Quantitative IR spectral analysis (i.e., 1720/3075 or 749/3075, HEMA/collagen ratios) further suggested that the grafting efficacy of HEMA onto the plasma-exposed collagen thin films strongly depended on the treatment time and input power of plasmas. TEM results indicated that plasma treatment did not alter collagen’s banding structure. Significance The current study provides deeper insight into the mechanism of dental adhesion enhancement induced by non-thermal plasmas treatment. The NTAP brush could be a promising method to create chemical bond between resin monomers and dentin collagen. PMID:25458523

  14. Enhanced active aluminum content and thermal behaviour of nano-aluminum particles passivated during synthesis using thermal plasma route

    Science.gov (United States)

    Mathe, Vikas L.; Varma, Vijay; Raut, Suyog; Nandi, Amiya Kumar; Pant, Arti; Prasanth, Hima; Pandey, R. K.; Bhoraskar, Sudha V.; Das, Asoka K.

    2016-04-01

    Here, we report synthesis and in situ passivation of aluminum nanoparticles using thermal plasma reactor. Both air and palmitc acid passivation was carried out during the synthesis in the thermal plasma reactor. The passivated nanoparticles have been characterized for their structural and morphological properties using X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. In order to understand nature of passivation vibrational spectroscopic analysis have been carried out. The enhancement in active aluminum content and shelf life for a palmitic acid passivated nano-aluminum particles in comparison to the air passivated samples and commercially available nano Al powder (ALEX) has been observed. Thermo-gravimetric analysis was used to estimate active aluminum content of all the samples under investigation. In addition cerimetric back titration method was also used to estimate AAC and the shelf life of passivated aluminum particles. Structural, microstructural and thermogravomateric analysis of four year aged passivated sample also depicts effectiveness of palmitic acid passivation.

  15. Surface modification of several dental substrates by non-thermal, atmospheric plasma brush

    Science.gov (United States)

    Chen, Mingsheng; Zhang, Ying; Driver, M. Sky; Caruso, Anthony N.; Yu, Qingsong; Wang, Yong

    2013-01-01

    Objective The purpose of this study was to reveal the effectiveness of non-thermal atmospheric plasma brush in surface wettability and modification of four dental substrates. Methods Specimens of dental substrates including dentin, enamel, and two composites Filtek Z250, Filtek LS Silorane were prepared (~2 mm thick, ~10 mm diameter). The prepared surfaces were treated for 5–45 s with a non-thermal atmospheric plasma brush working at temperatures from 36 to 38 °C. The plasma-treatment effects on these surfaces were studied with contact-angle measurement, X-ray photoemission spectroscopy (XPS) and scanning electron microscopy (SEM). Results The non-thermal atmospheric argon plasma brush was very efficient in improving the surface hydrophilicity of four substrates studied. The results indicated that water contact angle values decreased considerably after only 5 s plasma treatment of all these substrates. After 30 s treatment, the values were further reduced to <5°, which was close to a value for super hydrophilic surfaces. XPS analysis indicated that the percent of elements associated with mineral in dentin/enamel or fillers in the composites increased. In addition, the percent of carbon (%C) decreased while %O increased for all four substrates. As a result, the O/C ratio increased dramatically, suggesting that new oxygen-containing polar moieties were formed on the surfaces after plasma treatment. SEM surface images indicated that no significant morphology change was induced on these dental substrates after exposure to plasmas. Significance Without affecting the bulk properties, a super-hydrophilic surface could be easily achieved by the plasma brush treatment regardless of original hydrophilicity/hydrophobicity of dental substrates tested. PMID:23755823

  16. Hall Effect in a Plasma.

    Science.gov (United States)

    Kunkel, W. B.

    1981-01-01

    Describes an apparatus and procedure for conducting an undergraduate laboratory experiment to quantitatively study the Hall effect in a plasma. Includes background information on the Hall effect and rationale for conducting the experiment. (JN)

  17. A thermally stable heating mechanism for the intracluster medium: turbulence, magnetic fields and plasma instabilities

    CERN Document Server

    Kunz, M W; Cowley, S C; Binney, J J; Sanders, J S

    2010-01-01

    We consider the problem of self-regulated heating and cooling in galaxy clusters and the implications for cluster magnetic fields and turbulence. Viscous heating of a weakly collisional magnetised plasma is regulated by the pressure anisotropy with respect to the local direction of the magnetic field. The intracluster medium is a high-beta plasma, where pressure anisotropies caused by the turbulent stresses and the consequent local changes in the magnetic field will trigger very fast microscale instabilities. We argue that the net effect of these instabilities will be to pin the pressure anisotropies at a marginal level, controlled by the plasma beta parameter. This gives rise to local heating rates that turn out to be comparable to the radiative cooling rates. Furthermore, we show that a balance between this heating and Bremsstrahlung cooling is thermally stable, unlike the often conjectured balance between cooling and thermal conduction. Given a sufficient (and probably self-regulating) supply of turbulent ...

  18. Temperature measurements in thermal plasmas; Mesures de temperatures dans les plasmas thermiques

    Energy Technology Data Exchange (ETDEWEB)

    Fauchais, P.; Coudert, J.F. [Limoges Univ., 87 (France)

    1996-05-01

    Thermal plasmas are characterized by a high pressure (10{sup 4} to 10{sup 6} Pa) and a high density of particles. Plasmas considered in this paper are produced by electric discharges, arcs, injection torches with cold or hot cathodes, water vortex torches, RF devices and are characterized by temperatures ranging from 6000 to 40000 K and ionization energies ranging from 13.5 and 16 eV (in argon, argon-hydrogen, nitrogen, nitrogen-hydrogen, argon-helium, air, oxygen, CO{sub 2} or water). Temperature measurements in thermal plasmas are difficult due to their extreme luminosity, flow rate and thermal flux, and to their temperature and flow rate gradients. The most common measurement methods are the emission spectroscopy, the laser scattering (Rayleigh, Thomson and coherent anti-Stokes Raman scattering) and the enthalpy probes. The first two methods are non-intrusive, while the last method is intrusive. This paper gives first some general remarks about the principles of each technique and focusses on the problem of fluctuations due to the plasma jet instabilities. Then, it describes briefly each technique and gives some examples of results. Finally, it compares the spectroscopic measurements with other measurements. (J.S.) 80 refs.

  19. MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    V.K. Mathur

    2003-02-01

    In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

  20. Nitrogen oxides and methane treatment by non-thermal plasma

    Science.gov (United States)

    Alva, E.; Pacheco, M.; Colín, A.; Sánchez, V.; Pacheco, J.; Valdivia, R.; Soria, G.

    2015-03-01

    Non thermal plasma was used to treat nitrogen oxides (NOx) and methane (CH4), since they are important constituents of hydrocarbon combustion emissions processes and, both gases, play a key role in the formation of tropospheric ozone. These gases are involved in environmental problems like acid rain and some diseases such as bronchitis and pneumonia. In the case of methane is widely known its importance in the global climate change, and currently accounts for 30% of global warming. There is a growing concern for methane leaks, associated with a rapid expansion of unconventional oil and gas extraction techniques as well as a large-scale methane release from Arctic because of ice melting and the subsequent methane production of decaying organic matter. Therefore, methane mitigation is a key to avoid dangerous levels of global warming. The research, here reported, deals about the generation of non-thermal plasma with a double dielectric barrier (2DBD) at atmospheric pressure with alternating current (AC) for NOx and CH4 treatment. The degradation efficiencies and their respective power consumption for different reactor configurations (cylindrical and planar) are also reported. Qualitative and quantitative analysis of gases degradation are reported before and after treatment with cold plasma. Experimental and theoretical results are compared obtaining good removal efficiencies, superior to 90% and to 20% respectively for NOx and CH4.

  1. LASER INDUCED THERMAL LENS EFFECT

    Institute of Scientific and Technical Information of China (English)

    沈俊; 黄孟才; 江景云; 施教芳

    1991-01-01

    The thermal lens effect has emerged in recent years as a novel ,highly sensitive tool for the study of the very weak molecular absorption of light energy,This paper discusses the theory and technique of the thermal lens measurement.Some opplications of the thermal lens measurement are described.A mode-mismatched dual-beam thermal lens experimental arragement with a modulated probe beam ,designed by the authors.for trace analysis is presented,and its detection limit was found to be 4.1×10-7 for Cu(Ⅱ) in ethanol and 80 mW excitation power.

  2. Preliminary Study of Thermal Treatment of Coke Wastewater Sludge Using Plasma Torch

    Science.gov (United States)

    Li, Mingshu; Li, Shengli; Sun, Demao; Liu, Xin; Feng, Qiubao

    2016-10-01

    Thermal plasma was applied for the treatment of coke wastewater sludge derived from the steel industry in order to investigate the feasibility of the safe treatment and energy recovery of the sludge. A 30 kW plasma torch system was applied to study the vitrification and gas production of coke wastewater sludge. Toxicity leaching results indicated that the sludge treated via the thermal plasma process converted into a vitrified slag which resisted the leaching of heavy metals. CO2 was utilized as working gas to study the production and heat energy of the syngas. The heating value of the gas products by thermal plasma achieved 8.43 kJ/L, indicating the further utilization of the gas products. Considering the utilization of the syngas and recovery heat from the gas products, the estimated treatment cost of coke wastewater sludge via plasma torch was about 0.98 CNY/kg sludge in the experiment. By preliminary economic analysis, the dehydration cost takes an important part of the total sludge treatment cost. The treatment cost of the coke wastewater sludge with 50 wt.% moisture was calculated to be about 1.45 CNY/kg sludge dry basis. The treatment cost of the coke wastewater sludge could be effectively controlled by decreasing the water content of the sludge. These findings suggest that an economic dewatering pretreatment method could be combined to cut the total treatment cost in an actual treatment process.

  3. Low temperature synthesis of silicon quantum dots with plasma chemistry control in dual frequency non-thermal plasmas.

    Science.gov (United States)

    Sahu, Bibhuti Bhusan; Yin, Yongyi; Han, Jeon Geon; Shiratani, Masaharu

    2016-06-21

    The advanced materials process by non-thermal plasmas with a high plasma density allows the synthesis of small-to-big sized Si quantum dots by combining low-temperature deposition with superior crystalline quality in the background of an amorphous hydrogenated silicon nitride matrix. Here, we make quantum dot thin films in a reactive mixture of ammonia/silane/hydrogen utilizing dual-frequency capacitively coupled plasmas with high atomic hydrogen and nitrogen radical densities. Systematic data analysis using different film and plasma characterization tools reveals that the quantum dots with different sizes exhibit size dependent film properties, which are sensitively dependent on plasma characteristics. These films exhibit intense photoluminescence in the visible range with violet to orange colors and with narrow to broad widths (∼0.3-0.9 eV). The observed luminescence behavior can come from the quantum confinement effect, quasi-direct band-to-band recombination, and variation of atomic hydrogen and nitrogen radicals in the film growth network. The high luminescence yields in the visible range of the spectrum and size-tunable low-temperature synthesis with plasma and radical control make these quantum dot films good candidates for light emitting applications.

  4. Enhanced active aluminum content and thermal behaviour of nano-aluminum particles passivated during synthesis using thermal plasma route

    Energy Technology Data Exchange (ETDEWEB)

    Mathe, Vikas L., E-mail: vlmathe@physics.unipune.ac.in [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Varma, Vijay; Raut, Suyog [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Nandi, Amiya Kumar; Pant, Arti; Prasanth, Hima; Pandey, R.K. [High Energy Materials Research Lab, Sutarwadi, Pune 411021, Maharashtra (India); Bhoraskar, Sudha V. [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Das, Asoka K. [Utkal University, VaniVihar, Bhubaneswar, Odisha 751004 (India)

    2016-04-15

    Graphical abstract: - Highlights: • Synthesis of nano crystalline Al (nAl) using DC thermal plasma reactor. • In situ passivation of nAl by palmitic acid and air. • Enhanced active aluminum content obtained for palmitic acid passivated nAl. • Palmitic acid passivated nAl are quite stable in humid atmospheres. - Abstract: Here, we report synthesis and in situ passivation of aluminum nanoparticles using thermal plasma reactor. Both air and palmitc acid passivation was carried out during the synthesis in the thermal plasma reactor. The passivated nanoparticles have been characterized for their structural and morphological properties using X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. In order to understand nature of passivation vibrational spectroscopic analysis have been carried out. The enhancement in active aluminum content and shelf life for a palmitic acid passivated nano-aluminum particles in comparison to the air passivated samples and commercially available nano Al powder (ALEX) has been observed. Thermo-gravimetric analysis was used to estimate active aluminum content of all the samples under investigation. In addition cerimetric back titration method was also used to estimate AAC and the shelf life of passivated aluminum particles. Structural, microstructural and thermogravomateric analysis of four year aged passivated sample also depicts effectiveness of palmitic acid passivation.

  5. Thermal Conductivity Analysis and Lifetime Testing of Suspension Plasma-Sprayed Thermal Barrier Coatings

    Directory of Open Access Journals (Sweden)

    Nicholas Curry

    2014-08-01

    Full Text Available Suspension plasma spraying (SPS has become an interesting method for the production of thermal barrier coatings for gas turbine components. The development of the SPS process has led to structures with segmented vertical cracks or column-like structures that can imitate strain-tolerant air plasma spraying (APS or electron beam physical vapor deposition (EB-PVD coatings. Additionally, SPS coatings can have lower thermal conductivity than EB-PVD coatings, while also being easier to produce. The combination of similar or improved properties with a potential for lower production costs makes SPS of great interest to the gas turbine industry. This study compares a number of SPS thermal barrier coatings (TBCs with vertical cracks or column-like structures with the reference of segmented APS coatings. The primary focus has been on lifetime testing of these new coating systems. Samples were tested in thermo-cyclic fatigue at temperatures of 1100 °C for 1 h cycles. Additional testing was performed to assess thermal shock performance and erosion resistance. Thermal conductivity was also assessed for samples in their as-sprayed state, and the microstructures were investigated using SEM.

  6. Surface modification of biphasic calcium phosphate scaffolds by non-thermal atmospheric pressure nitrogen and air plasma treatment for improving osteoblast attachment and proliferation

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Yu-Ri [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-752 (Korea, Republic of); Research Center for Orofacial Hard Tissue Regeneration, College of Dentistry, Yonsei University, Seoul 120-752 (Korea, Republic of); Kwon, Jae-Sung [Research Center for Orofacial Hard Tissue Regeneration, College of Dentistry, Yonsei University, Seoul 120-752 (Korea, Republic of); Song, Doo-Hoon [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-752 (Korea, Republic of); Research Center for Orofacial Hard Tissue Regeneration, College of Dentistry, Yonsei University, Seoul 120-752 (Korea, Republic of); Choi, Eun Ha [Plasma Bioscience Research Center Kwangwoon University, Seoul 139-701, 447-1 Wokgye-Dong, Nowon-Gu, Seoul (Korea, Republic of); Lee, Yong-Keun [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-752 (Korea, Republic of); Kim, Kyoung-Nam [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-752 (Korea, Republic of); Research Center for Orofacial Hard Tissue Regeneration, College of Dentistry, Yonsei University, Seoul 120-752 (Korea, Republic of); Kim, Kwang-Mahn, E-mail: kmkim@yuhs.ac [Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-752 (Korea, Republic of); Research Center for Orofacial Hard Tissue Regeneration, College of Dentistry, Yonsei University, Seoul 120-752 (Korea, Republic of)

    2013-11-29

    Surface modifications induced by non-thermal plasma have been used extensively in biomedical applications. The attachment and proliferation of osteoblast cells are important in bone tissue engineering using scaffolds. Hence the effect of non-thermal plasma on hydroxyapatite/β-tri-calcium phosphate (HA/β-TCP) scaffolds in terms of improving osteoblast attachment and proliferation was investigated. Experimental groups were treated with non-thermal plasma for 10 min and 20 min and a control group was not treated with non-thermal plasma. For surface chemistry analysis, X-ray photoelectron spectroscopy (XPS) analysis was carried out. The hydrophilicity was determined from contact angle measurement on the surface. Atomic force microscopy analysis (AFM) was used to test the change in surface roughness and cell attachment and proliferation were evaluated using MC3T3-E1 osteoblast cells. XPS spectra revealed a decreased amount of carbon on the surface of the plasma-treated sample. The contact angle was also decreased following plasma treatment, indicating improved hydrophilicity of plasma-treated surfaces compared to the untreated disc. A significant increase in MC3T3E-1 cell attachment and proliferation was noted on plasma-treated samples as compared to untreated specimens. The results suggest that non-thermal atmospheric pressure nitrogen and air plasma treatments provide beneficial surface characteristics on HA/β-TCP scaffolds. - Highlights: ► Non-thermal plasma increased OH- and decreased C on biphasic scaffold. ► Non-thermal plasma had no effect on surface roughness. ► Non-thermal plasma resulted in hydrophilic surface. ► Non-thermal plasma resulted in better cell attachment and proliferation. ► Non-thermal plasma treatment on biphasic scaffold is useful for tissue engineering.

  7. Treatment of Bone Waste Using Thermal Plasma Technology

    Institute of Scientific and Technical Information of China (English)

    KI Ho Beom; KIM Woo Hyung; KIM Bong Soo; K00 Hyung Joon; LI Mingwei; CHAE Jae Ou

    2007-01-01

    Daily meat consumption produces a lot of bone waste, and dumped bone waste without treatment would result in environmental hazards. Conventional treatment methods of waste bones have some disadvantages. Herein, an investigation of bone waste treated using thermal plasma technology is presented. A high-temperature plasma torch operated at 25.2 kW was used to treat bone waste for seven minutes. The bone waste was finally changed into vitric matter and lost 2/3 of its weight after the treatment. The process was highly efficient, economical, convenient, and fuel-free. This method could be used as an alternative for disposal of bone waste, small infectious animals, hazardous hospital waste, etc.

  8. Modeling ion interpenetration, stagnation, and thermalization in colliding plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Jones, M.E.; Winske, D.; Goldman, S.R.; Kopp, R.A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Rogatchev, V.G.; Belkov, S.A.; Gasparyan, P.D.; Dolgoleva, G.V.; Zhidkov, N.V.; Ivanov, N.V.; Kochubej, Y.K.; Nasyrov, G.F.; Pavlovskii, V.A.; Smirnov, V.V.; Romanov, Y.A. [All Russian Scientific Research Institute of Experimental Physics, Sarov (Arzamas 16), Nizhniy Novgorod Region, 607200 (Russia)

    1996-03-01

    Ion interpenetration, stagnation, and energization processes are studied in colliding laser-produced plasma configurations relevant to Trident [R. G. Watt, Rev. Sci. Instrum. {bold 64}, 1770 (1993)] experiments using four different numerical methods: one-dimensional Monte Carlo and Lagrangian multifluid codes, and one- and two-dimensional hybrid (particle ions, fluid electrons) and single-fluid Lagrangian codes. Results from the four methodologies are compared for plasmas generated with gold and deuterated polyethylene (CD{sub 2}) targets. Overall, the various codes give similar results concerning the initial expansion of the plasmas and their collisional interaction, the degree of stagnation, stagnation time, and amount of ion thermalization for gold targets, while multispecies techniques indicate a much softer stagnation for CD{sub 2} plasmas than the single-fluid model. Variations in the results of the calculations due to somewhat different initializations and parameters, as well as to different physics in the codes, are discussed. {copyright} {ital 1996 American Institute of Physics.}

  9. Thermomechanical behavior of plasma-sprayed zirconia thermal barrier coatings.

    Energy Technology Data Exchange (ETDEWEB)

    Singh, J. P.

    1998-04-01

    The effect of coating porosity and thickness on the resistance to damage of yttria stabilized zirconia thermal barrier coatings in an oxidizing environment by thermal cycling was evaluated. Hardness and elastic modulus of an as-processed porous coating were lower than those of a dense coating and the porous coating failed after fewer thermal cycles. Similarly, specimen with a thicker coating failed after fewer thermal cycles than specimen with a thinner coating. The earlier failure of the porous coating is due to lower fracture toughness and enhanced oxidation of the coating/substrate interface, whereas, the earlier failure of the thick coating is due to higher thermal transient stresses that developed in the coating during thermal cycling. Generally, an increase in coating density led to initial increase in both hardness and elastic modulus with increasing thermal cycles. However, hardness and density gradually decreased as the number of thermal cycles increase because of microcracks formation and growth. Microscopic observations indicated that the formation of multiple microcracks and their subsequent growth and coalescence led to final coating failure.

  10. Elastic behaviour of plasma sprayed thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Steinbrech, R.W.; Frahm, J.; Herzog, R.; Schubert, F. [Inst. for Materials and Processes in Energy Systems, Forschungszentrum Juelich GmbH, Juelich (Germany)

    2002-07-01

    The elastic behaviour of air plasma sprayed (APS) thermal barrier coatings (TBCs) of 8 wt.% yttria stabilised zirconia was studied using various mechanical tests with global and local resolution. Results are presented, which reveal the complex relationship between lamellar APS-microstructure and stiffness and illustrate scaling aspects. Also the influence of residual stresses is addressed. The obtained stiffness values for as-sprayed TBCs show a systematic variation between 10 and 100 GPa. Typically results from bending tests of free-standing TBCs are at the low end, whereas results from depth sensitive indentation tests with TBCs bonded to a substrate are found at the high end. When heat treated above 950 C the TBCs exhibit a rapid increase in stiffness which can be attributed to defect healing within the spraying lamellae. Discussion of the results focuses on the implications of a non-uniform stiffness modulus for the mechanical characterisation of thermal barrier systems. (orig.)

  11. Thermal Plasma Decomposition Of Nickel And Cobalt Compounds

    Directory of Open Access Journals (Sweden)

    Woch M.

    2015-06-01

    Full Text Available The paper presents the study on manufacturing of nickel and cobalt powders by thermal plasma decomposition of the carbonates of these metals. It was shown the dependence of process parameters and grain size of initial powder on the composition of final product which was ether metal powder, collected in the container as well as the nanopowder with crystallite size of 70 - 90 nm, collected on the inner wall of the reaction chamber. The occurrence of metal oxides in the final products was confirmed and discussed.

  12. Thermal effects in supercapacitors

    CERN Document Server

    Xiong, Guoping; Fisher, Timothy S

    2015-01-01

    This Brief reviews contemporary research conducted in university and industry laboratories on thermal management in electrochemical energy storage systems (capacitors and batteries) that have been widely used as power sources in many practical applications, such as automobiles, hybrid transport, renewable energy installations, power backup and electronic devices. Placing a particular emphasis on supercapacitors, the authors discuss how supercapacitors, or ultra capacitors, are complementing and  replacing, batteries because of their faster power delivery, longer life cycle and higher coulombic efficiency, while providing higher energy density than conventional electrolytic capacitors. Recent advances in both macro- and micro capacitor technologies are covered. The work facilitates systematic understanding of thermal transport in such devices that can help develop better power management systems.

  13. Effect of Composition of Bond Coating on the Durability of the Plasma Sprayed Zr O[sub 2]-Ce O[sub 2]-Y[sub 2] O[sub 3] Thermal Barrier Coating

    Energy Technology Data Exchange (ETDEWEB)

    Kim, H.S. (Korea Institute of Science and Technology, Seoul (Korea, Republic of)); Kim, B.H.; Suhr, D.S. (Chungnam National University, Taejon (Korea, Republic of))

    1999-01-01

    The effect of alloy compositions of the bond coating on the plasma sprayed-thermal barrier coatings was investigated. The performance of the coating composed of Rene 80/NiCrAl/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] and Rene 80/CoNiCrAlY/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] was evaluated by isothermal and thermal cyclic test in an ambient atmosphere at 1150 deg. C. The failure of Rene 80/NiCrAl/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] coatings was occurred at the bond coating/ceramic coating interface while Rene 80/CoNiCrAlY/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] coating was failed at the substrate/bond coating interface after thermal cyclic test. The lifetime of Rene 80/NiCrAl/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] coatings was longer than Rene 80/CoNiCrAlY/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] coating. The oxidation rate of the NiCrAl bond coating examined by TGA was lower than CoNiCrAlY bond coating. In summary, these results suggest that Rene 80/CoNiCrAlY/ZrO[sub 2]-CeO[sub 2]-Y[sub 2]O[sub 3] system as thermal barrier coating be not suitable considering the durability of the coating layer for high temperature oxidation and thermal stress. (author). 12 refs., 14 figs., 2 tabs.

  14. Effect of Composition of Bond Coating on the Durability of the Plasma Sprayed Zr O{sub 2}-Ce O{sub 2}-Y{sub 2} O{sub 3} Thermal Barrier Coating

    Energy Technology Data Exchange (ETDEWEB)

    Kim, H.S. [Korea Institute of Science and Technology, Seoul (Korea, Republic of); Kim, B.H.; Suhr, D.S. [Chungnam National University, Taejon (Korea, Republic of)

    1999-01-01

    The effect of alloy compositions of the bond coating on the plasma sprayed-thermal barrier coatings was investigated. The performance of the coating composed of Rene 80/NiCrAl/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} and Rene 80/CoNiCrAlY/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} was evaluated by isothermal and thermal cyclic test in an ambient atmosphere at 1150 deg. C. The failure of Rene 80/NiCrAl/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} coatings was occurred at the bond coating/ceramic coating interface while Rene 80/CoNiCrAlY/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} coating was failed at the substrate/bond coating interface after thermal cyclic test. The lifetime of Rene 80/NiCrAl/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} coatings was longer than Rene 80/CoNiCrAlY/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} coating. The oxidation rate of the NiCrAl bond coating examined by TGA was lower than CoNiCrAlY bond coating. In summary, these results suggest that Rene 80/CoNiCrAlY/ZrO{sub 2}-CeO{sub 2}-Y{sub 2}O{sub 3} system as thermal barrier coating be not suitable considering the durability of the coating layer for high temperature oxidation and thermal stress. (author). 12 refs., 14 figs., 2 tabs.

  15. Thermal charm and charmonium production in quark gluon plasma

    Directory of Open Access Journals (Sweden)

    Kai Zhou

    2016-07-01

    Full Text Available We study the effect of thermal charm production on charmonium regeneration in high energy nuclear collisions. By solving the kinetic equations for charm quark and charmonium distributions in Pb+Pb collisions, we calculate the global and differential nuclear modification factors RAA(Npart and RAA(pt for J/ψ s. Due to the thermal charm production in hot medium, the charmonium production source changes from the initially created charm quarks at SPS, RHIC and LHC to the thermally produced charm quarks at Future Circular Collider (FCC, and the J/ψ suppression (RAA1 at FCC at low transverse momentum.

  16. The Role of Higher-Order Modes on the Electromagnetic Whistler-Cyclotron Wave Fluctuations of Thermal and Non-Thermal Plasmas

    Science.gov (United States)

    Vinas, Adolfo F.; Moya, Pablo S.; Navarro, Roberto; Araneda, Jamie A.

    2014-01-01

    Two fundamental challenging problems of laboratory and astrophysical plasmas are the understanding of the relaxation of a collisionless plasmas with nearly isotropic velocity distribution functions and the resultant state of nearly equipartition energy density with electromagnetic plasma turbulence. Here, we present the results of a study which shows the role that higher-order-modes play in limiting the electromagnetic whistler-like fluctuations in a thermal and non-thermal plasma. Our main results show that for a thermal plasma the magnetic fluctuations are confined by regions that are bounded by the least-damped higher order modes. We further show that the zone where the whistler-cyclotron normal modes merges the electromagnetic fluctuations shifts to longer wavelengths as the beta(sub e) increases. This merging zone has been interpreted as the beginning of the region where the whistler-cyclotron waves losses their identity and become heavily damped while merging with the fluctuations. Our results further indicate that in the case of nonthermal plasmas, the higher-order modes do not confine the fluctuations due to the effective higher-temperature effects and the excess of suprathermal plasma particles. The analysis presented here considers the second-order theory of fluctuations and the dispersion relation of weakly transverse fluctuations, with wave vectors parallel to the uniform background magnetic field, in a finite temperature isotropic bi-Maxwellian and Tsallis-kappa-like magnetized electron-proton plasma. Our results indicate that the spontaneously emitted electromagnetic fluctuations are in fact enhanced over these quasi modes suggesting that such modes play an important role in the emission and absorption of electromagnetic fluctuations in thermal or quasi-thermal plasmas.

  17. Thermal conductivity reduction of tungsten plasma facing material due to helium plasma irradiation in PISCES using the improved 3-omega method

    Science.gov (United States)

    Cui, Shuang; Simmonds, Michael; Qin, Wenjing; Ren, Feng; Tynan, George R.; Doerner, Russell P.; Chen, Renkun

    2017-04-01

    The near-surface region of plasma facing material (PFM) plays an important role in thermal management of fusion reactors. In this work, we measured thermal conductivity of tungsten (W) surface layers damaged by He plasma in PISCES at UCSD. We studied the damage effect on both bulk, and thin film, W. We observed that the surface morphology of both bulk and thin film was altered after exposure to He plasma with the fluence of 1 × 1026 m-2 (bulk) and 2 × 1024 m-2 (thin film). Transmission electron microscopy (TEM) analysis reveals that the depth of the irradiation damaged layer was approximately 20 nm on the bulk W exposed to He plasma at 773 K for 2000 s. In order to measure the thermal conductivity of this exceedingly thin damaged layer in the bulk W, we adopted the well-established '3-omega' method and employed novel nanofabrication techniques to improve the measurement sensitivity. For the damaged W thin film sample, we measured the reduction in electrical conductivity and used the Wiedemann-Franz (W-F) law to extract the thermal conductivity. Results from both measurements show that thermal conductivity in the damaged layers was reduced by at least ∼80% compared to that of undamaged W. This large reduction in thermal conductivity can be attributed to the scattering of electrons, the dominant heat carriers in W, caused by defects introduced by He plasma irradiation.

  18. Comparison of thermal shock behaviors between plasma-sprayed nanostructured and conventional zirconia thermal barrier coatings

    Institute of Scientific and Technical Information of China (English)

    LIU Chun-bo; ZHANG Zhi-min; JIANG Xian-liang; LIU Min; ZHU Zhao-hui

    2009-01-01

    NiCoCrAlTaY bond coat was deposited on pure nickel substrate by low pressure plasma spraying(LPPS), and ZrO2-8%Y2O3 (mass fraction) nanostructured and ZrO2-7%Y2O3 (mass fraction) conventional thermal barrier coatings(TBCs) were deposited by air plasma spraying(APS). The thermal shock behaviors of the nanostructured and conventional TBCs were investigated by quenching the coating samples in cold water from 1 150, 1 200 and 1 250 ℃, respectively. Scanning electron microscopy(SEM) was used to examine the microstructures of the samples after thermal shock testing. Energy dispersive analysis of X-ray(EDAX) was used to analyze the interface diffusion behavior of the bond coat elements. X-ray diffractometry(XRD) was used to analyze the constituent phases of the samples. Experimental results indicate that the nanostructured TBC is superior to the conventional TBC in thermal shock performance. Both the nanostructured and conventional TBCs fail along the bond coat/substrate interface. The constituent phase of the as-sprayed conventional TBC is diffusionless-transformed tetragonal(t′). However, the constituent phase of the as-sprayed nanostructured TBC is cubic(c). There is a difference in the crystal size at the spalled surfaces of the nanostructured and conventional TBCs. The constituent phases of the spalled surfaces are mainly composed of Ni2.88Cr1.12 and oxides of bond coat elements.

  19. The plasma physics of thermal conduction in the intracluster medium of galaxy clusters

    Science.gov (United States)

    Reynolds, Christopher

    Most of the baryons in a galaxy cluster reside in a hot (10-100 million K) and tenuous gaseous atmosphere confined by the gravitational potential of the cluster's dark matter halo. Understanding the microphysics of this intracluster medium (ICM), particularly the transport processes such as thermal conduction and viscosity, is important to any understanding of the thermodynamic state of ICM atmospheres. For example, the current paradigm is that radiative losses in the ICM core are offset by energy from a central jetted active galactic nucleus (AGN), preventing a cooling catastrophe in the cluster core. However, the mechanism by which the jet-injected energy is thermalized in the ICM is highly uncertain - the dissipation of waves or turbulence by thermal conduction or plasma viscosity is a leading contender. A knowledge of thermal conduction in the ICM is also important for any attempts to understand the global temperature profiles of clusters, with consequences for e.g. cosmological studies based on observations of the SunyaevZeldovich (SZ) effect. The basic physics of thermal conduction in the ICM is very poorly understood, however, leading to a huge uncertainty in the relevant coefficients. The ICM resides in a poorly studied regime of plasma physics - it is a highly magnetized (gyroradii path), high-beta (thermal pressure >> magnetic pressure), and weakly collisional (mean-free path only moderately less than global scale lengths) plasma. Thermal conduction will be strongly suppressed perpendicular to magnetic fields lines. But even along field lines, the growth of small scale and fast kinetic instabilities may strongly suppress thermal conduction. Hence the usual assumption, that conduction along the field has its classical Spitzer value, has a shaky theoretical basis and may well be wildly inaccurate. In this proposal, we use analytical theory and computer models to explore thermal conduction in ICM-like plasmas. Recently, we have found that a strong heat

  20. Non-thermal atmospheric pressure plasma jet and its application for polymer treatment

    OpenAIRE

    Sarani, Abdollah

    2010-01-01

    Non-thermal atmospheric pressure plasma jet is a suitable source for polymer treatment. The main characteristic of this plasma jet is the remote operation and its scalable dimension, thus, allowing local treatment of 3D surfaces. In this work an atmospheric pressure DBD plasma jet has been constructed and the application of the plasma jet for polymer treatment is investigated.

  1. Synthesis of low carbon boron carbide powder using a minimal time processing route: Thermal plasma

    Directory of Open Access Journals (Sweden)

    Avinna Mishra

    2015-12-01

    Full Text Available Boron carbide powder was synthesized by thermal plasma reduction of boric acid in presence of graphite with a very minimal processing time. Subsequently, the as-synthesized products were leached to minimize the impurities content. Based on the results of X-ray diffraction and Raman spectroscopy, the effect of leaching on phase purity and crystallinity was studied. X-ray photoelectron spectroscopy was performed to identify the chemical composition which highlighted the absence of the BO bonding in the deconvoluted B 1s core-level spectrum. Finally, the temperature dependent thermal conductivity behavior of the leached materials was analyzed and presented.

  2. Superior Thermal Barrier Coatings Using Solution Precursor Plasma Spray

    Science.gov (United States)

    Jordan, E. H.; Xie, L.; Gell, M.; Padture, N. P.; Cetegen, B.; Ozturk, A.; Ma, X.; Roth, J.; Xiao, T. D.; Bryant, P. E. C.

    2004-03-01

    A novel process, solution precursor plasma spray (SPPS), is presented for depositing thermal barrier coatings (TBCs), in which aqueous chemical precursors are injected into a standard direct current plasma spray system. The resulting coatings microstructure has three unique features: (1) ultra fine splats (1 µm), (2) nanometer and micron-sized interconnected porosity, and (3) closely spaced, through-thickness cracks. Coatings over 3 mm thick can be readily deposited using the SPPS process. Coating durability is excellent, with SPPS coatings showing, in furnace cycling tests, 2.5 times the spallation life of air plasma coatings (APS) and 1.5 times the life of electron beam physical vapor deposited (EB-PVD) coatings. The conductivity of SPPS coatings is lower than EB-PVD coatings and higher than the best APS coatings. Manufacturing cost is expected to be similar to APS coatings and much lower than EB-PVD coatings. The SPPS deposition process includes droplet break-up and material arriving at the deposition surface in various physical states ranging from aqueous solution, gel phase, to fully-molten ceramic. The relation between the arrival state of the material and the microstructure is described.

  3. Treatment and recycling of incinerated ash using thermal plasma technology.

    Science.gov (United States)

    Cheng, T W; Chu, J P; Tzeng, C C; Chen, Y S

    2002-01-01

    To treat incinerated ash is an important issue in Taiwan. Incinerated ashes contain a considerable amount of hazardous materials such as dioxins and heavy metals. If these hazardous materials are improperly treated or disposed of, they shall cause detrimental secondary contamination. Thermal plasma vitrification is a robust technology to treat and recycle the ash residues. Under the high temperature plasma environment, incinerated ashes are vitrified into benign slag with large volume reduction and extreme detoxification. Several one-step heat treatment processes are carried out at four temperatures (i.e. 850, 950, 1,050 and 1,150 degrees C) to obtain various "microstructure materials". The major phase to form these materials is a solid solution of gehlenite (Ca2Al2SiO7) and åkermanite (Ca2MgSi2O7) belonging to the melilite group. The physical and mechanical properties of the microstructure materials are improved by using one-step post-heat treatment process after plasma vitrification. These microstructure materials with good quality have great potential to serve as a viable alternative for construction applications.

  4. A PIC Simulation Study of Electron Viscosity and Thermal Conduction in Collisionless Plasmas

    Science.gov (United States)

    Riquelme, Mario; Quataert, Eliot; Verscharen, Daniel

    2016-10-01

    We use particle-in-cell (PIC) simulations to study the interplay between electron- and ion-scale velocity-space instabilities and their effect on electron pressure anisotropy, viscous heating, and thermal conduction. The adiabatic invariance of the magnetic moment in low-collisionality plasmas gives rise to pressure anisotropy, with p⊥ , j -p∥ , j > 0 ( | grows (decreases), where p⊥ , j and p∥ , j denote the pressure of species j [electron or ion] perpendicular and parallel to B-> . If the resulting anisotropy is large enough, it can trigger small-scale plasma instabilities. By imposing a shear in the plasma we either amplify or decrease the magnetic field | B-> | . When | B-> | is amplified, we explored the nonlinear regime of the mirror, ion-cyclotron, and electron whistler instabilities. When | B-> | is decreased, we studied the nonlinear regime of the ion- and electron-firehose instabilities. We discuss the implications of our results for electron heating and thermal conduction in low-collisionality accretion flows onto black holes, like Sgr A*. We also discuss the possible implications for the thermal conductivity of plasma in the outer parts of massive, hot, galaxy clusters.

  5. Some applications of thermal field theory to quark-gluon plasma

    Indian Academy of Sciences (India)

    Munshi G Mustafa

    2006-04-01

    We briefly introduce the thermal field theory within imaginary time formalism, the hard thermal loop perturbation theory and some of its applications to the physics of the quark-gluon plasma, possibly created in relativistic heavy-ion collisions.

  6. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    Energy Technology Data Exchange (ETDEWEB)

    Charles Mones

    2006-12-01

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the

  7. Polysilicon Prepared from SIC14 by Atmospheric-Pressure Non-Thermal Plasma%Polysilicon Prepared from SIC14 by Atmospheric-Pressure Non-Thermal Plasma

    Institute of Scientific and Technical Information of China (English)

    李小松; 王楠; 杨晋华; 王友年; 朱爱民

    2011-01-01

    Non-thermal plasma at atmospheric pressure was explored for the preparation of polysilicon from SiCl4. The power supply sources of positive pulse and alternating current (8 kHz and 100 kHz) were compared for polysilicon preparation. The samples prepared by using the 100 kHz power source were crystalline silicon. The effects of H2 and SiCl4 volume fractions were investigated. The optical emission spectra showed that silicon species played an important role in polysilicon deposition

  8. Utilizing the micron sized non-thermal atmospheric pressure plasma inside the animal body for the tumor treatment application.

    Science.gov (United States)

    Mirpour, Shahriar; Piroozmand, Somayeh; Soleimani, Neda; Jalali Faharani, Neda; Ghomi, Hamidreza; Fotovat Eskandari, Hoda; Sharifi, Ali Mohammad; Mirpour, Sahar; Eftekhari, Mohammad; Nikkhah, Maryam

    2016-07-07

    This study aimed to evaluate the effects of micron sized non-thermal atmospheric pressure plasma inside the animal body on breast cancer tumor. The μ-plasma jet consists of micron sized hollow tube in which pure helium gas is ionized by high voltage (4 kV) and high frequency (6 kHz). The efficiency of the plasma treatment in killing cancer cells was first investigated by cell viability measurements of treated 4T1 cells using flow cytometry and cell cycle analysis. For exploration of the in vivo effects of the plasma treatment, the BALB/c mice inoculated by 4T1 cell lines were exposed subcutaneously to plasma for 3 minutes. In addition, H&E staining, TUNEL and Western blotting assays were performed in order to observed the effects of the non-thermal plasma on the tumor cells. The results showed that the efficiency of the plasma in suppression of the tumor growth is comparable to that of a typical chemotherapy drug. Moreover, the results indicated that the plasma induces apoptosis in the tumor tissue and increases the ratio of the apoptotic to anti-apoptotic protein expression. We believe that these findings presented herein may extend our knowledge of the mechanisms by which the plasma exerts its promising anti-cancer effects.

  9. Destruction studies of hazardous wastes by thermal plasma; Estudios de degradacion de residuos peligrosos mediante plasma termico

    Energy Technology Data Exchange (ETDEWEB)

    Cota S, G

    1998-11-01

    Plasma technology appears promising because its high degree of controllability, capability to process waste without the adverse effects of combustion, and a very wide temperature range of operation. The goal of this work was to develop a process for a high throughput system to turn hazardous waste into inert stable products, which can be safely stored and to greatly reduce air pollution relative to incineration. The experiments have shown that the thermal plasma reactor can provide a high degree of decomposition of CCl{sub 4} , C{sub 6} H{sub 6}, C{sub 2} Cl{sub 4} and commercial oil at low gas input speeds, with modest power requirements. Decomposition of 99.9999 % has been obtained in our laboratory and all the organic components are decomposed in base molecules (C, CO, CO{sub 2}, H{sub 2}, HCl). The analysis of exhaust gases was made by using a mass filter quadrupole. The equipment consist of a cylindrical reactor hermetically sealed, double-walled and water-cooled container made of special steel, this container in halt the crucible which serves to receive the waste materials. The whole system is designed for a maximal internal temperature of 2000 Centigrade. The gaseous result components of the material are transferred to a scrubber unit through an exit arranged on the top of reactor. The thermal efficiency evaluation of the plasma torch was also realized, obtaining a reasonable agreement between measurements and predictions in temperature profiles. (Author)

  10. Simulations of planar non-thermal plasma assisted ignition at atmospheric pressure

    KAUST Repository

    Casey, Tiernan A.

    2016-10-21

    The opportunity for ignition assistance by a pulsed applied voltage is investigated in a canonical one-dimensional configuration. An incipient ignition kernel, formed by localized energy deposition into a lean mixture of methane and air at atmospheric pressure, is subjected to sub-breakdown electric fields (E/N ≈ 100 Td) by a DC potential applied across the domain, resulting in non-thermal behavior of the plasma formed during the discharge. A two-fluid approach is employed to couple thermal neutrals and ions to the non-thermal electrons. A two-temperature plasma mechanism describing gas phase combustion, excitation of neutral species, and high-energy electron kinetics is employed to account for non-thermal effects. Charged species transported from the ignition zone drift rapidly through the domain, augmenting the magnitude of the electric field in the fresh gas during the pulse through a dynamic-electrode effect, which results in an increase in the energy of the electrons in the fresh mixture with increasing time. Enhanced fuel and oxidizer decomposition due to electron impact dissociation and interaction with excited neutrals generate a pool of radicals, mostly O and H, in the fresh gas ahead of the flame\\'s preheat zone. In the configuration considered, the effect of the nanosecond pulse is to increase the mass of fuel burned at equivalent times relative to the unsupported ignition through enhanced radical generation, resulting in an increased heat release rate in the immediate aftermath of the pulse.

  11. The Thermal Sunyaev-Zeldovich Effect of Primordial Recombination Radiation

    CERN Document Server

    Kholupenko, E E; Ivanchik, A V; Varshalovich, D A

    2014-01-01

    It is well known that recombination radiation of primordial hydrogen-helium plasma leads to the distortions of the planckian spectrum shape of the cosmic microwave background radiation (CMB). We discuss the thermal Sunayev-Zeldovich (SZ) effect with taking into account primordial recombination radiation (PRR). Since in the thermal SZ effect the redistribution of the photons depends on the derivatives of the spectrum, the value of relative correction to SZ effect due to PRR significantly higher than relative corrections due to PRR in the initial spectrum. Calculations of corrections to the thermal SZ effect due to PRR show that depending on the cluster parameters: 1) in the range of frequencies $\

  12. Space Plasma Effects

    Directory of Open Access Journals (Sweden)

    Miguel Herraiz

    2009-06-01

    Full Text Available

    This paper summarizes the activities carried out by WP 3.1 of WG 3 of COST 296 action. The Work Package

    deals mostly with medium and large ionospheric structures that impacts on GNSS signals. In the research done

    by this European team, particular attention was given to the ionosphere/space weather monitoring, to the analysis

    of the variability of the ionospheric plasma during quiet and disturbed conditions and to the characterization

    of the behavior of low latitudes ionospheric depletions or bubbles and the spatial and temporal gradients of total electron contet.


  13. Non-thermal plasma technology for the development of antimicrobial surfaces: a review

    Science.gov (United States)

    Nikiforov, Anton; Deng, Xiaolong; Xiong, Qing; Cvelbar, U.; DeGeyter, N.; Morent, R.; Leys, Christophe

    2016-05-01

    Antimicrobial coatings are in high demand in many fields including the biomaterials and healthcare sectors. Within recent progress in nanoscience and engineering at the nanoscale, preparation of nanocomposite films containing metal nanoparticles (such as silver nanoparticles, copper nanoparticles, zinc oxide nanoparticles) is becoming an important step in manufacturing biomaterials with high antimicrobial activity. Controlled release of antibiotic agents and eliminating free nanoparticles are of equal importance for engineering antimicrobial nanocomposite materials. Compared to traditional chemical ‘wet’ methods, plasma deposition and plasma polymerization are promising approaches for the fabrication of nanocomposite films with the advantages of gas phase dry processes, effective use of chemicals and applicability to various substrates. In this article, we present a short overview of state-of-the-art engineering of antimicrobial materials based on the use of non-thermal plasmas at low and atmospheric pressure.

  14. Ion acoustic solitary waves in plasmas with nonextensive electrons, Boltzmann positrons and relativistic thermal ions

    Science.gov (United States)

    Hafez, M. G.; Talukder, M. R.

    2015-09-01

    This work investigates the theoretical and numerical studies on nonlinear propagation of ion acoustic solitary waves (IASWs) in an unmagnetized plasma consisting of nonextensive electrons, Boltzmann positrons and relativistic thermal ions. The Korteweg-de Vries (KdV) equation is derived by using the well known reductive perturbation method. This equation admits the soliton like solitary wave solution. The effects of phase velocity, amplitude of soliton, width of soliton and electrostatic nonlinear propagation of weakly relativistic ion-acoustic solitary waves have been discussed with graphical representation found in the variation of the plasma parameters. The obtained results can be helpful in understanding the features of small but finite amplitude localized relativistic ion-acoustic waves for an unmagnetized three component plasma system in astrophysical compact objects.

  15. Numerical modeling of disperse material evaporation in axisymmetric thermal plasma reactor

    Directory of Open Access Journals (Sweden)

    Stefanović Predrag Lj.

    2003-01-01

    Full Text Available A numerical 3D Euler-Lagrangian stochastic-deterministic (LSD model of two-phase flow laden with solid particles was developed. The model includes the relevant physical effects, namely phase interaction, panicle dispersion by turbulence, lift forces, particle-particle collisions, particle-wall collisions, heat and mass transfer between phases, melting and evaporation of particles, vapour diffusion in the gas flow. It was applied to simulate the processes in thermal plasma reactors, designed for the production of the ceramic powders. Paper presents results of extensive numerical simulation provided (a to determine critical mechanism of interphase heat and mass transfer in plasma flows, (b to show relative influence of some plasma reactor parameters on solid precursor evaporation efficiency: 1 - inlet plasma temperature, 2 - inlet plasma velocity, 3 - particle initial diameter, 4 - particle injection angle a, and 5 - reactor wall temperature, (c to analyze the possibilities for high evaporation efficiency of different starting solid precursors (Si, Al, Ti, and B2O3 powder, and (d to compare different plasma reactor configurations in conjunction with disperse material evaporation efficiency.

  16. Using plasma-fuel systems at Eurasian coal-fired thermal power stations

    Science.gov (United States)

    Karpenko, E. I.; Karpenko, Yu. E.; Messerle, V. E.; Ustimenko, A. B.

    2009-06-01

    The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

  17. Using plasma-fuel systems at Eurasian coal-fired thermal power stations

    Energy Technology Data Exchange (ETDEWEB)

    E.I. Karpenko; Y.E. Karpenko; V.E. Messerle; A.B. Ustimenko [RAO Unified Energy Systems of Russia, Gusinoozersk (Russian Federation). Russia Sectional Center for Plasma-Power Technologies

    2009-07-01

    The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

  18. Killing of adherent oral microbes by a non-thermal atmospheric plasma jet.

    Science.gov (United States)

    Rupf, Stefan; Lehmann, Antje; Hannig, Matthias; Schäfer, Barbara; Schubert, Andreas; Feldmann, Uwe; Schindler, Axel

    2010-02-01

    Atmospheric plasma jets are being intensively studied with respect to potential applications in medicine. The aim of this in vitro study was to test a microwave-powered non-thermal atmospheric plasma jet for its antimicrobial efficacy against adherent oral micro-organisms. Agar plates and dentin slices were inoculated with 6 log(10) c.f.u. cm(-2) of Lactobacillus casei, Streptococcus mutans and Candida albicans, with Escherichia coli as a control. Areas of 1 cm(2) on the agar plates or the complete dentin slices were irradiated with a helium plasma jet for 0.3, 0.6 or 0.9 s mm(-2), respectively. The agar plates were incubated at 37 degrees C, and dentin slices were vortexed in liquid media and suspensions were placed on agar plates. The killing efficacy of the plasma jet was assessed by counting the number of c.f.u. on the irradiated areas of the agar plates, as well as by determination of the number of c.f.u. recovered from dentin slices. A microbe-killing effect was found on the irradiated parts of the agar plates for L. casei, S. mutans, C. albicans and E. coli. The plasma-jet treatment reduced the c.f.u. by 3-4 log(10) intervals on the dentin slices in comparison to recovery rates from untreated controls. The microbe-killing effect was correlated with increasing irradiation times. Thus, non-thermal atmospheric plasma jets could be used for the disinfection of dental surfaces.

  19. Eradication of Pseudomonas aeruginosa biofilms by atmospheric pressure non-thermal plasma.

    Directory of Open Access Journals (Sweden)

    Mahmoud Y Alkawareek

    Full Text Available Bacteria exist, in most environments, as complex, organised communities of sessile cells embedded within a matrix of self-produced, hydrated extracellular polymeric substances known as biofilms. Bacterial biofilms represent a ubiquitous and predominant cause of both chronic infections and infections associated with the use of indwelling medical devices such as catheters and prostheses. Such infections typically exhibit significantly enhanced tolerance to antimicrobial, biocidal and immunological challenge. This renders them difficult, sometimes impossible, to treat using conventional chemotherapeutic agents. Effective alternative approaches for prevention and eradication of biofilm associated chronic and device-associated infections are therefore urgently required. Atmospheric pressure non-thermal plasmas are gaining increasing attention as a potential approach for the eradication and control of bacterial infection and contamination. To date, however, the majority of studies have been conducted with reference to planktonic bacteria and rather less attention has been directed towards bacteria in the biofilm mode of growth. In this study, the activity of a kilohertz-driven atmospheric pressure non-thermal plasma jet, operated in a helium oxygen mixture, against Pseudomonas aeruginosa in vitro biofilms was evaluated. Pseudomonas aeruginosa biofilms exhibit marked susceptibility to exposure of the plasma jet effluent, following even relatively short (≈ 10's s exposure times. Manipulation of plasma operating conditions, for example, plasma operating frequency, had a significant effect on the bacterial inactivation rate. Survival curves exhibit a rapid decline in the number of surviving cells in the first 60 seconds followed by slower rate of cell number reduction. Excellent anti-biofilm activity of the plasma jet was also demonstrated by both confocal scanning laser microscopy and metabolism of the tetrazolium salt, XTT, a measure of bactericidal

  20. Characteristics of NO reduction with non-thermal plasma

    Institute of Scientific and Technical Information of China (English)

    YU Gang; YU Qi; JIANG Yan-long; ZENG Ke-si

    2005-01-01

    As a new type of NO removal system, NO reduction in N2-NO plasma was applied to solve the difficulties in the traditional methods, such as higher energy-consumption, larger equipment size and high cost, and so on. Using the experimental NO reduction system with single-pair electrode tip discharge structure, the NO reduction characteristics of N2-NO system were revealed to guide the engineering practice; the results of NO reduction with single-pair electrode tip discharge plasma also have the same instructive meaning to the NO reduction with multi-pair electrode tip discharge plasma. The amount of both active N atom and NO removal rate increased with the distance /g increasing between the two electrode tips and then dropped when the distance exceeded a certain value. The NO removal rate increased while the voltage between two electrode tips or the resident time of gas flow increased. The distance is a key geometrical variable factor that can determine the intensity of electric field between two electrode tips and the resident time of gas. In this paper, the effects of the dielectric features on NO reduction using dielectric-barrier discharge plasma system were also studied. The results of NO removal rate with different dielectrics such as Al2 O3, CaO, MgO and glass showed that the electric field intensity is different with different dielectric, because it brings different energy to particles in discharge room and thus it causes different NO removal rate.

  1. Hollow silicon carbide nanoparticles from a non-thermal plasma process

    Science.gov (United States)

    Coleman, Devin; Lopez, Thomas; Yasar-Inceoglu, Ozgul; Mangolini, Lorenzo

    2015-05-01

    We demonstrate the synthesis of hollow silicon carbide nanoparticles via a two-step process involving the non-thermal plasma synthesis of silicon nanoparticles, followed by their in-flight carbonization, also initiated by a non-thermal plasma. Simple geometric considerations associated with the expansion of the silicon lattice upon carbonization, in combination of the spherical geometry of the system, explain the formation of hollow nanostructures. This is in contrast with previous reports that justify the formation of hollow particles by means of out-diffusion of the core element, i.e., by the Kirkendall nanoscale effect. A theoretical analysis of the diffusion kinetics indicates that interaction with the ionized gas induces significant nanoparticle heating, allowing for the fast transport of carbon into the silicon particle and for the subsequent nucleation of the beta-silicon carbide phase. This work confirms the potential of non-thermal plasma processes for the synthesis of nanostructures composed of high-melting point materials, and suggests that such processes can be tuned to achieve morphological control.

  2. Thermal photon anisotropic flow serves as a quark–gluon plasma viscometer

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Chun; Heinz, Ulrich [Department of Physics, The Ohio State University, Columbus, OH 43210-1117 (United States); Paquet, Jean-François; Gale, Charles [Department of Physics, McGill University, 3600 University Street, Montreal, Quebec, H3A 2T8 (Canada)

    2014-12-15

    Photons are a penetrating probe of the hot and dense medium created in heavy-ion collisions. We present state-of-the-art calculations of viscous photon emission from nuclear collisions at RHIC and LHC. Thermal photons' anisotropic flow coefficients v{sub n} are computed, both with and without accounting for viscous corrections to the standard thermal emission rates. These corrections are found to have a larger effect on the v{sub n} coefficients than the viscous suppression of hydrodynamic flow anisotropies. For thermal photons, the ratio v{sub 2}{SP}/v{sub 3}{SP} shows stronger sensitivity to the quark–gluon plasma (QGP) shear viscosity than for hadrons, and it can thus serve as a sensitive QGP viscometer.

  3. Effect of thermal stress on physiological parameters, feed intake and plasma thyroid hormones concentration in Alentejana, Mertolenga, Frisian and Limousine cattle breeds

    Science.gov (United States)

    Pereira, Alfredo M. F.; Baccari, Flávio; Titto, Evaldo A. L.; Almeida, J. A. Afonso

    2008-01-01

    The aim of the present study was to assess the heat tolerance of animals of two Portuguese (Alentejana and Mertolenga) and two exotic (Frisian and Limousine) cattle breeds, through the monitoring of physiological acclimatization reactions in different thermal situations characterized by alternate periods of thermoneutrality and heat stress simulated in climatic chambers. In the experiment, six heifers of the Alentejana, Frisian and Mertolenga breeds and four heifers of the Limousine breed were used. The increase in chamber temperatures had different consequences on the animals of each breed. When submitted to heat stress, the Frisian animals developed high thermal polypnea (more than 105 breath movements per minute), which did not prevent an increase in the rectal temperature (from 38.7°C to 40.0°C). However, only a slight depression in food intake and in blood thyroid hormone concentrations was observed under thermal stressful conditions. Under the thermal stressful conditions, Limousine animals decreased food intake by 11.4% and blood triiodothyronine (T3) hormone concentration decreased to 76% of the level observed in thermoneutral conditions. Alentejana animals had similar reactions. The Mertolenga cattle exhibited the highest capacity for maintaining homeothermy: under heat stressful conditions, the mean thermal polypnea increased twofold, but mean rectal temperature did not increase. Mean food intake decreased by only 2% and mean T3 blood concentration was lowered to 85,6% of the concentration observed under thermoneutral conditions. These results lead to the conclusion that the Frisian animals had more difficulty in tolerating high temperatures, the Limousine and Alentejana ones had an intermediate difficulty, and the Mertolenga animals were by far the most heat tolerant.

  4. Thermal plasma technology for the treatment of wastes: a critical review.

    Science.gov (United States)

    Gomez, E; Rani, D Amutha; Cheeseman, C R; Deegan, D; Wise, M; Boccaccini, A R

    2009-01-30

    This review describes the current status of waste treatment using thermal plasma technology. A comprehensive analysis of the available scientific and technical literature on waste plasma treatment is presented, including the treatment of a variety of hazardous wastes, such as residues from municipal solid waste incineration, slag and dust from steel production, asbestos-containing wastes, health care wastes and organic liquid wastes. The principles of thermal plasma generation and the technologies available are outlined, together with potential applications for plasma vitrified products. There have been continued advances in the application of plasma technology for waste treatment, and this is now a viable alternative to other potential treatment/disposal options. Regulatory, economic and socio-political drivers are promoting adoption of advanced thermal conversion techniques such as thermal plasma technology and these are expected to become increasingly commercially viable in the future.

  5. Spallation occurrence from polyamide materials irradiated by thermal plasma with water absorption

    Science.gov (United States)

    Nakano, Tomoyuki; Tanaka, Yasunori; Nakagawa, T.; Shinsei, N.; Uesugi, Y.; Ishijima, T.

    2016-09-01

    This paper first describes the effect of water absorption in polyamide material irradiated by thermal plasmas on the occurrence of spallation phenomena. The interaction between polyamide materials and arc plasmas occurs particularly in the low voltage circuit breaker and aerospace fields. Spallation phenomena are those in which polymer particles are ejected from polymer bulk materials irradiated by high heat flux. To confirm the effect of water absorption into the polyamide material on spallation phenomena, polyamide specimens with and without water absorption were irradiated by Ar inductively coupled thermal plasma. The results show that the polyamide specimen with water absorption ejected spallation particles, whereas the polyamide specimen without water absorption were only slightly ejected, indicating that water absorption promotes the occurrence of spallation. The cooling effects of the spallation polyamide 66 (PA66) particles ablation were also estimated in hot air to assess the arc quenching ability from the spallation particle inclusion. This estimation showed that 10 and more PA66 particles inclusion might decrease the air temperature by 3000 K effectively, which can be useful to enhance arc quenching in circuit breakers working in air.

  6. Thermal analysis of the in-vessel components of the ITER plasma-position reflectometry

    Energy Technology Data Exchange (ETDEWEB)

    Quental, P. B., E-mail: pquental@ipfn.tecnico.ulisboa.pt; Policarpo, H.; Luís, R.; Varela, P. [Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa (Portugal)

    2016-11-15

    The ITER plasma position reflectometry system measures the edge electron density profile of the plasma, providing real-time supplementary contribution to the magnetic measurements of the plasma-wall distance. Some of the system components will be in direct sight of the plasma and therefore subject to plasma and stray radiation, which may cause excessive temperatures and stresses. In this work, thermal finite element analysis of the antenna and adjacent waveguides is conducted with ANSYS V17 (ANSYS® Academic Research, Release 17.0, 2016). Results allow the identification of critical temperature points, and solutions are proposed to improve the thermal behavior of the system.

  7. Thermal analysis of the in-vessel components of the ITER plasma-position reflectometry

    Science.gov (United States)

    Quental, P. B.; Policarpo, H.; Luís, R.; Varela, P.

    2016-11-01

    The ITER plasma position reflectometry system measures the edge electron density profile of the plasma, providing real-time supplementary contribution to the magnetic measurements of the plasma-wall distance. Some of the system components will be in direct sight of the plasma and therefore subject to plasma and stray radiation, which may cause excessive temperatures and stresses. In this work, thermal finite element analysis of the antenna and adjacent waveguides is conducted with ANSYS V17 (ANSYS® Academic Research, Release 17.0, 2016). Results allow the identification of critical temperature points, and solutions are proposed to improve the thermal behavior of the system.

  8. Novel fragmentation model for pulverized coal particles gasification in low temperature air thermal plasma

    OpenAIRE

    Jovanović Rastko D.; Cvetinović Dejan B.; Stefanović Predrag Lj.; Škobalj Predrag D.; Marković Zoran J.

    2016-01-01

    New system for start-up and flame support based on coal gasification by low temperature air thermal plasma is planned to supplement current heavy oil system in Serbian thermal power plants in order to decrease air pollutions emission and operational costs. Locally introduced plasma thermal energy heats up and ignites entrained coal particles, thus starting chain process which releases heat energy from gasified coal particles inside burner channel. Important...

  9. Transport properties of multicomponent thermal plasmas: Grad method versus Chapman-Enskog method

    Energy Technology Data Exchange (ETDEWEB)

    Porytsky, P. [Institute for Nuclear Research, 03680 Kyiv (Ukraine); Krivtsun, I.; Demchenko, V. [Paton Welding Institute, 03680 Kyiv (Ukraine); Reisgen, U.; Mokrov, O.; Zabirov, A. [RWTH Aachen University, ISF-Welding and Joining Institute, 52062 Aachen (Germany); Gorchakov, S.; Timofeev, A.; Uhrlandt, D. [Leibniz Institute for Plasma Science and Technology (INP Greifswald), 17489 Greifswald (Germany)

    2013-02-15

    Transport properties (thermal conductivity, viscosity, and electrical conductivity) for multicomponent Ar-Fe thermal plasmas at atmospheric pressure have been determined by means of two different methods. The transport coefficients set based on Grad's method is compared with the data obtained when using the Chapman-Enskog's method. Results from both applied methods are in good agreement. It is shown that the Grad method is suitable for the determination of transport properties of the thermal plasmas.

  10. Thermal Hall Effect of Magnons

    Science.gov (United States)

    Murakami, Shuichi; Okamoto, Akihiro

    2017-01-01

    We review recent developments in theories and experiments on the magnon Hall effect. We derive the thermal Hall conductivity of magnons in terms of the Berry curvature of magnonic bands. In addition to the Dzyaloshinskii-Moriya interaction, we show that the dipolar interaction can make the Berry curvature nonzero. We mainly discuss theoretical aspects of the magnon Hall effect and related theoretical works. Experimental progress in this field is also mentioned.

  11. Study on structural, morphological and thermal properties of surface modified polyvinylchloride (PVC) film under air, argon and oxygen discharge plasma

    Science.gov (United States)

    Suganya, Arjunan; Shanmugavelayutham, Gurusamy; Serra Rodríguez, Carmen

    2016-09-01

    The effect of air, argon, oxygen DC glow discharge plasma on the polyvinylchloride (PVC) film synthesized by solution casting technique, were evaluated via changes in physio-chemical properties such as structural, morphological, crystalline, thermal properties. The PVC film was plasma treated as a function of exposure time and different plasma forming gases, while other operating parameters such as power and pressure remained constant at 100 W and 2 Pa respectively. The plasma treated PVC were characterized by static contact angle, ATR-FTIR, XPS, AFM and T-peel analysis. It was found that various gaseous plasma treatments have improved the polar components, surface roughness on the surface of PVC which was confirmed by XPS, AFM, resulting in highly enhanced wettability and adhesion. X-ray diffraction study showed that plasma treatment does not persuade considerable change, even though it vaguely induces the crystallinity. The thermal properties of plasma treated PVC were evaluated by Differential Scanning Calorimetry and it was observed that O2 plasma treatment gives higher glass transition temperature of 87.21 °C compared with the untreated one. The glass transition temperature slightly increased for Oxygen plasma treated material due to the presence of higher concentration of the polar functional groups on the PVC surface due to strong intramolecular bonding.

  12. Reactive Plasma-Sprayed Aluminum Nitride-Based Coating Thermal Conductivity

    Science.gov (United States)

    Shahien, Mohammed; Yamada, Motohiro; Fukumoto, Masahiro; Egota, Kazumi; Okamoto, Kenji

    2015-12-01

    Recently, thick aluminum nitride/alumina (AlN/Al2O3) composite coatings were successfully fabricated through the reactive plasma spraying of fine Al2O3/AlN mixture in the N2/H2 atmospheric plasma. The coatings consist of AlN, Al5O6N, γ-Al2O3, and α-Al2O3 phases. This study will evaluate the thermal conductivity of these complicated plasma-sprayed coatings and optimize the controlling aspects. Furthermore, the influence of the process parameters on the coatings thermal conductivity will be investigated. The fabricated coatings showed very low thermal conductivity (2.43 W/m K) compared to the AlN sintered compacts. It is attributed to the phase composition of the fabricated coatings, oxide content, and porosity. The presence of Al2O3, Al5O6N and the high coating porosity decreased its thermal conductivity. The presence of oxygen in the AlN lattice creates Al vacancies which lead to phonon scattering and therefore suppressed the thermal conductivity. The formation of γ-Al2O3 phase in the coating leads to further decrease in its conductivity, due to its lower density compared to the α-phase. Moreover, the high porosity of the coating strongly suppressed the conductivity. This is due to the complicated microstructure of plasma spray coatings (splats, porosity, and interfaces, particularly in case of reactive spray process), which obviously lowered the conductivity. Furthermore, the measured coating density was lower than the AlN value and suppressed the coating conductivity. In addition, the spraying parameter showed a varied effect on the coating phase composition, porosity, density, and therefore on its conductivity. Although the N2 gas flow improved the nitride content, it suppressed the thermal conductivity gradually. It is attributed to the further increase in the porosity and further decrease in the density of the coatings with the N2 gas. Furthermore, increasing the arc did not show a significant change on the coating thermal conductivity. On the other hand

  13. Gravitomagnetic Effects on Collective Plasma Oscillations in Compact Stars

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The effects of gravitomagnetic force on plasma oscillations are investigated using the kinetic theory of homogeneous electrically neutral plasma in the absence of external electric or magnetic field. The random phase assumption is employed neglecting the thermal motion of the electrons with respect to a fixed ion background. It is found that the gravitomagnetic force reduces the characteristic frequency of the plasma thus enhancing the refractive index of the medium. The estimates for the predicted effects are given for a typical white dwarf, pulsar, and neutron star.

  14. Radiative instabilities in plasmas: impurity motion and recombination effects

    Energy Technology Data Exchange (ETDEWEB)

    Morozov, D.K.; Herrera, J.J.E. [Instituto de Ciencias y Artes, Chiapas (Mexico). Escuela de Biologia

    1995-03-01

    Radiative instabilities in an impurity-seeded plasma are investigated when the plasma is supposed to be highly but partially ionized. Since in such plasmas radiative losses strongly depend on neutral and impurity densities, their dynamics are taken into account. As a result, a new radiative-recombination instability is found and described. We show that the influence of the ionization-recombination balance on plasma stability is sufficient for plasma densities above 10{sup 14} cm{sup -3}. The effects of a finite impurity Larmor radius are not small and play a stabilizing role as well as the thermal forces. On the other hand, compressibility of the magnetic field leads to plasma destabilization. We note that this radiative-recombination instability accumulates impurities in a cold zone while cleaning other regions. (Author).

  15. Thermal plasma treatment of cell-phone waste : preliminary result

    Energy Technology Data Exchange (ETDEWEB)

    Ruj, B. [Central Mechanical Engineering Research Inst., Durgapur (India). Thermal Engineering Group; Chang, J.S.; Li, O.L. [McMaster Univ., Hamilton, ON (Canada). Dept. of Engineering Physics; Pietsch, G. [RWTH Aachen Univ., Aachen (Germany)

    2010-07-01

    The cell phone is an indispensable service facilitator, however, the disposal and recycling of cell phones is a major problem. While the potential life span of a mobile phone, excluding batteries, is over 10 years, most of the users upgrade their phones approximately four times during this period. Cell phone waste is significantly more hazardous than many other municipal wastes as it contains thousands of components made of toxic chemicals and metals like lead, cadmium, chromium, mercury, polyvinyl chlorides (PVC), brominated flame retardants, beryllium, antimony and phthalates. Cell phones also use many expensive rare metals. Since cell phones are made up of plastics, metals, ceramics, and trace other substances, primitive recycling or disposal of cell phone waste to landfills and incinerators creates irreversible environmental damage by polluting water and soil, and contaminating air. In order to minimize releases into the environment and threat to human health, the disposal of cell phones needs to be managed in an environmentally friendly way. This paper discussed a safer method of reducing the generation of syngas and hydrocarbons and metal recovery through the treatment of cell phone wastes by a thermal plasma. The presentation discussed the experiment, with particular reference to sample preparation; experimental set-up; and results four samples with different experimental conditions. It was concluded that the plasma treatment of cell phone waste in reduced condition generates gaseous components such as hydrogen, carbon monoxide, and hydrocarbons which are combustible. Therefore, this system is an energy recovery system that contributes to resource conservation and reduction of climate change gases. 5 refs., 2 tabs., 2 figs.

  16. Potential cellular targets and antibacterial efficacy of atmospheric pressure non-thermal plasma.

    Science.gov (United States)

    Alkawareek, Mahmoud Y; Gorman, Sean P; Graham, William G; Gilmore, Brendan F

    2014-02-01

    Atmospheric pressure non-thermal plasma (APNTP) has been gaining increasing interest as a new alternative antibacterial approach. Although this approach has demonstrated promising antibacterial activity, its exact mechanism of action remains unclear. Mechanistic elucidation of the antimicrobial activity will facilitate development and rational optimisation of this approach for potential medical applications. In this study, the antibacterial efficacy of an in-house-built APNTP jet was evaluated alongside an investigation of the interactions between APNTP and major cellular components in order to identify the potential cellular targets involved in plasma-mediated bacterial destruction mechanisms. The investigated plasma jet exhibited excellent, rapid antibacterial activity against a selected panel of clinically significant bacterial species including Bacillus cereus, meticillin-resistant Staphylococcus aureus (MRSA), Escherichia coli and Pseudomonas aeruginosa, all of which were completely inactivated within 2 min of plasma exposure. Plasma-mediated damaging effects were observed, to varying degrees, on all of the investigated cellular components including DNA, a model protein enzyme, and lipid membrane integrity and permeability. The antibacterial efficacy of APNTP appears to involve a multiple-target mechanism, which potentially reduces the likelihood of emergence of microbial resistance towards this promising antimicrobial approach. However, cellular membrane damage and resulting permeability perturbation was found to be the most likely rate-determining step in this mechanism.

  17. Thermal transport properties of thermally sprayed coatings: An integrated study of materials, processing and microstructural effects

    Science.gov (United States)

    Chi, Weiguang

    The complex microstructures of thermally sprayed coatings are very sensitive to processing conditions and have a significant influence on the properties. The thermal transport property is a very important design parameter for thermally sprayed coatings. Despite considerable progress in this area, there is continued need to clarify the interrelationships among processing, microstructure and thermal transport properties. This has been enabled through continued advancements in processing science and control, enhancements in microstructural characterization and new methods of property characterization. The purpose of this research is to seek a successive pathway to prior efforts in understanding the effect of microstructural defects on the thermal transport property of thermally sprayed coatings. Relationship between microstructure and thermal conductivity is investigated for three sets of plasma sprayed yttria stabilized zirconia (YSZ) coating systems made using different morphology powders, different particle size distribution and controlled modification of particle states via plasma torch parameters. By integrating the results, maps of the thermal conductivity-porosity relationship have been established. Such maps highlight the role of splat thickness and interfaces in thermal conductivity. Furthermore, a new microstructural parameter termed "effective porosity" is proposed which considers the dominating role of interlamellar pores on through thickness thermal transport in thermally sprayed coatings. This effective porosity is rationalized based on the heat transport mechanism and enables better understanding of microstructure-thermal transport property correlation. An inverse linear model and a percolation model are established which can serve as predictive tools for understanding microstructure-thermal conductivity relationships. In addition, a systematic assessment of thermal conductivity anisotropy has been carried out for YSZ, Al2O 3 and several metallic

  18. PLASMA THERMAL BARRIER COATINGS BASED ON ZIRCONIUM DIOXIDE WITH HIGH THERMAL STABILITY

    Directory of Open Access Journals (Sweden)

    O. G. Devoino

    2015-01-01

    Full Text Available The paper presents optimization of  processes for obtaining maximum content of tetragonal phase in the initial material and thermal barrier coatings (TBC based on zirconium dioxide and hafnium oxide.  Results of the investigations on phase composition of oxide HfO2 – ZrO2 – Y2O3  system have been given in the paper. The system represents  a microstructure which is similar to  zirconia dioxide and  transformed for its application at 1300 °C. The paper explains a mechanism of hafnium oxide influence on formation of the given microstructure. The research methodology has been based on complex metallography, X – ray diffraction and electron microscopic investigations of  structural elements of the composite plasma coating HfO2 – ZrO2 – Y2O system.In order to stabilize zirconium dioxide  dopant oxide should not only have an appropriate size of  metal ion, but also form a solid solution with the zirconia. This condition severely limits the number of possible stabilizers. In fact, such stabilization is possible only with the help of rare earth oxides (Y2O3, Yb2O3, CeO2, HfO2. Chemical purity of the applied materials plays a significant role for obtaining high-quality thermal barrier coatings. Hafnium oxide has been selected as powder for thermal barrier coatings instead of zirconium dioxide due to their similarities in structural modification, grating, chemical and physical properties and its high temperature structural transformations. It has been established that plasma thermal barrier HfO2 – ZrO2 – Y2O3 coatings consist of  one tetragonal phase. This phase is equivalent to a non-equilibrium tetragonal t' phase in the “zirconium dioxide stabilized with yttrium oxide” system. Affinity of  Hf+4 and Zr+4 cations leads to the formation of identical metastable phases during rapid quenching.

  19. Collisional Thermalization of Hydrogen and Helium in Solar Wind Plasma

    CERN Document Server

    Maruca, Bennett A; Sorriso-Valvo, Luca; Kasper, Justin C; Stevens, Michael L

    2013-01-01

    In situ observations of the solar wind frequently show the temperature of $\\alpha$-particles (fully ionized helium), $T_\\alpha$, to significantly differ from that of protons (ionized hydrogen), $T_p$. Many heating processes in the plasma act preferentially on $\\alpha$-particles, even as collisions among ions act to gradually establish thermal equilibrium. Measurements from the $\\textit{Wind}$ spacecraft's Faraday cups reveal that, at $r=1.0\\ \\textrm{AU}$ from the Sun, the observed values of the $\\alpha$-proton temperature ratio, $\\theta_{\\alpha p} \\equiv T_\\alpha\\,/\\,T_p$ has a complex, bimodal distribution. This study applied a simple model for the radial evolution of $\\theta_{\\alpha p}$ to these data to compute expected values of $\\theta_{\\alpha p}$ at $r=0.1\\ \\textrm{AU}$. These inferred $\\theta_{\\alpha p}$-values have no trace of the bimodality seen in the $\\theta_{\\alpha p}$-values measured at $r=1.0\\ \\textrm{AU}$ but are instead consistent with the actions of the known mechanisms for $\\alpha$-particle p...

  20. Kinetic turbulence in relativistic plasma: from thermal bath to non-thermal continuum

    CERN Document Server

    Zhdankin, Vladimir; Uzdensky, Dmitri A; Begelman, Mitchell C

    2016-01-01

    We present results from particle-in-cell simulations of driven turbulence in collisionless, relativistic pair plasma. We find that turbulent fluctuations are consistent with the classical $k_\\perp^{-5/3}$ magnetic energy spectrum at fluid scales and a steeper $k_\\perp^{-4}$ spectrum at sub-Larmor scales, where $k_\\perp$ is the wavevector perpendicular to the mean field. We demonstrate the development of a non-thermal, power-law particle energy distribution, $f(E) \\sim E^{-\\alpha}$, with index well fit by $\\alpha \\sim 1 + C_0 (\\sigma \\rho_e/L)^{-1/2}$, where $C_0$ is a constant, $\\sigma$ is magnetization, and $\\rho_e/L$ is the ratio of characteristic Larmor radius to system size. In the absence of asymptotic system-size independent scalings, our results challenge the viability of turbulent particle acceleration in high-energy astrophysical systems such as pulsar wind nebulae.

  1. Gas Plasma Effects on Living Cells

    Science.gov (United States)

    Stoffels, E.; Sladek, R. E. J.; Kieft, I. E.

    This paper surveys the research activities at the Eindhoven University of Technology (The Netherlands) in the area of biomedical applications of gas discharge plasmas. A non-thermal atmospheric plasma source (the plasma needle) has been developed, and its interactions with living mammalian cells and bacteria are studied. It is concluded that plasma can efficiently kill bacteria without harming the cells, and also influence the cells without causing cell death (necrosis). In future it will lead to applications like skin (wound) and caries treatment.

  2. Performance evaluation of non-thermal plasma on particulate matter, ozone and CO2 correlation for diesel exhaust emission reduction

    DEFF Research Database (Denmark)

    Babaie, Meisam; Davari, Pooya; Talebizadeh, Poyan

    2015-01-01

    This study is seeking to investigate the effect of non-thermal plasma technology in the abatement of particulate matter (PM) from the actual diesel exhaust. Ozone (O3) strongly promotes PM oxidation, the main product of which is carbon dioxide (CO2). PM oxidation into the less harmful product (CO2...

  3. Realization of thermally durable close-packed 2D gold nanoparticle arrays using self-assembly and plasma etching.

    Science.gov (United States)

    Sivaraman, Sankar K; Santhanam, Venugopal

    2012-06-29

    Realization of thermally and chemically durable, ordered gold nanostructures using bottom-up self-assembly techniques are essential for applications in a wide range of areas including catalysis, energy generation, and sensing. Herein, we describe a modular process for realizing uniform arrays of gold nanoparticles, with interparticle spacings of 2 nm and above, by using RF plasma etching to remove ligands from self-assembled arrays of ligand-coated gold nanoparticles. Both nanoscale imaging and macroscale spectroscopic characterization techniques were used to determine the optimal conditions for plasma etching, namely RF power, operating pressure, duration of treatment, and type of gas. We then studied the effect of nanoparticle size, interparticle spacing, and type of substrate on the thermal durability of plasma-treated and untreated nanoparticle arrays. Plasma-treated arrays showed enhanced chemical and thermal durability, on account of the removal of ligands. To illustrate the application potential of the developed process, robust SERS (surface-enhanced Raman scattering) substrates were formed using plasma-treated arrays of silver-coated gold nanoparticles that had a silicon wafer or photopaper as the underlying support. The measured value of the average SERS enhancement factor (2 × 10(5)) was quantitatively reproducible on both silicon and paper substrates. The silicon substrates gave quantitatively reproducible results even after thermal annealing. The paper-based SERS substrate was also used to swab and detect probe molecules deposited on a solid surface.

  4. Realization of thermally durable close-packed 2D gold nanoparticle arrays using self-assembly and plasma etching

    Science.gov (United States)

    Sivaraman, Sankar K.; Santhanam, Venugopal

    2012-06-01

    Realization of thermally and chemically durable, ordered gold nanostructures using bottom-up self-assembly techniques are essential for applications in a wide range of areas including catalysis, energy generation, and sensing. Herein, we describe a modular process for realizing uniform arrays of gold nanoparticles, with interparticle spacings of 2 nm and above, by using RF plasma etching to remove ligands from self-assembled arrays of ligand-coated gold nanoparticles. Both nanoscale imaging and macroscale spectroscopic characterization techniques were used to determine the optimal conditions for plasma etching, namely RF power, operating pressure, duration of treatment, and type of gas. We then studied the effect of nanoparticle size, interparticle spacing, and type of substrate on the thermal durability of plasma-treated and untreated nanoparticle arrays. Plasma-treated arrays showed enhanced chemical and thermal durability, on account of the removal of ligands. To illustrate the application potential of the developed process, robust SERS (surface-enhanced Raman scattering) substrates were formed using plasma-treated arrays of silver-coated gold nanoparticles that had a silicon wafer or photopaper as the underlying support. The measured value of the average SERS enhancement factor (2 × 105) was quantitatively reproducible on both silicon and paper substrates. The silicon substrates gave quantitatively reproducible results even after thermal annealing. The paper-based SERS substrate was also used to swab and detect probe molecules deposited on a solid surface.

  5. Influence of coupling on thermal forces and dynamic friction in plasmas with multiple ion species

    CERN Document Server

    Kagan, Grigory; Daligault, Jerome

    2016-01-01

    The recently proposed effective potential theory [Phys. Rev. Lett. 110, 235001 (2013)] is used to investigate the influence of coupling on inter-ion-species diffusion and momentum exchange in multi-component plasmas. Thermo-diffusion and the thermal force are found to diminish rapidly as strong coupling onsets. For the same coupling parameters, the dynamic friction coefficient is found to tend to unity. These results provide an impetus for addressing the role of coupling on diffusive processes in inertial confinement fusion experiments.

  6. Molecular cloud formation via thermal instability of finite resistive viscous radiating plasma with finite Larmor radius corrections

    Science.gov (United States)

    Kaothekar, Sachin

    2017-06-01

    The effect of radiative heat-loss function and finite ion Larmor radius (FLR) corrections on the thermal instability of infinite homogeneous viscous plasma has been investigated incorporating the effects of thermal conductivity and finite electrical resistivity for the formation of a molecular cloud. The general dispersion relation is derived using the normal mode analysis method with the help of relevant linearized perturbation equations of the problem. Furthermore the wave propagation along and perpendicular to the direction of external magnetic field has been discussed. Stability of the medium is discussed by applying Routh Hurwitz's criterion and it is found that thermal instability criterion determines the stability of the medium. We find that the presence of radiative heat-loss function and thermal conductivity modify the fundamental criterion of thermal instability into radiatively driven thermal instability criterion. In longitudinal direction FLR corrections, viscosity, magnetic field and finite resistivity have no effect on thermal instability criterion. The presence of radiative heat-loss function and thermal conductivity modify the fundamental thermal instability criterion into radiatively driven thermal instability criterion. Also the FLR corrections modify the growth rate of the Alfven mode. For transverse wave propagation FLR corrections, radiative heat-loss function, magnetic field and thermal conductivity modify the thermal instability criterion. From the curves it is clear that heat-loss function, FLR corrections and viscosity have stabilizing effect, while finite resistivity has destabilizing effect on the thermal modes. Our results show that the FLR corrections and radiative heat-loss functions affect the evolution of interstellar molecular clouds and star formation.

  7. Equatorial Plasma Bubble Detection and Scintillation Specification by the Thermal Plasma Sensor (TPS) on NPOESS

    Science.gov (United States)

    Basu, S.; Groves, K.; Starks, M.; Rich, F.

    2005-12-01

    The thermal plasma sensor (TPS) on the National Polar-orbiting Operational Environmental Satellites System (NPOESS) will perform in-situ measurements of the total ion concentration, the ion concentration fluctuations and the ion temperature. The ion concentration measurements will have a range from less than 10e3 per c.c. to greater than 10e6 per c.c. The DMSP data is used to show that this range of total ion concentration measurements will be adequate to detect the smallest as well as the deepest equatorial plasma bubbles. The detection of deep plasma bubbles will indicate the disturbed state of the equatorial electrodynamics in the presence of much enhanced zonal electric fields. Furthermore, the bubbles generally indicate the presence of steep gradients in the total electron content of the ionosphere that may disable the GPS-based aircraft navigation systems currently undergoing development at equatorial latitudes. The TPS sensor will have the ability to measure the fluctuations in the electron concentration, DN/N, less than 0.1 per cent over distances of 25 km to as large as 50 per cent. These two bounds of DN/N in the equatorial region during the post-sunset hours correspond to weak VHF scintillations and saturated GHz scintillations respectively. It is well-known that with the 32 Hz sampling of the TPS data, the Fourier spectra of the ion concentration fluctuation data extends only to a Nyquist scale-length of 500 m. By using the high frequency comb filter outputs of the TPS sensor, the spectrum can, however, be extended to tens of meter scales, a decade smaller than the Fresnel dimension of GHz scintillation. It is shown that in the framework of radio wave diffraction theory, such data, in combination with the electron density profile measurements made by NPOESS can be used to specify scintillations in the range of VHF to GHz.

  8. The Effect of Core Configuration on Thermal Barrier Thermal Performance

    Science.gov (United States)

    DeMange, Jeffrey J.; Bott, Robert H.; Druesedow, Anne S.

    2015-01-01

    Thermal barriers and seals are integral components in the thermal protection systems (TPS) of nearly all aerospace vehicles. They are used to minimize heat transfer through interfaces and gaps and protect underlying temperature-sensitive components. The core insulation has a significant impact on both the thermal and mechanical properties of compliant thermal barriers. Proper selection of an appropriate core configuration to mitigate conductive, convective and radiative heat transfer through the thermal barrier is challenging. Additionally, optimization of the thermal barrier for thermal performance may have counteracting effects on mechanical performance. Experimental evaluations have been conducted to better understand the effect of insulation density on permeability and leakage performance, which can significantly impact the resistance to convective heat transfer. The effect of core density on mechanical performance was also previously investigated and will be reviewed. Simple thermal models were also developed to determine the impact of various core parameters on downstream temperatures. An extended understanding of these factors can improve the ability to design and implement these critical TPS components.

  9. Thermal effects and thermal compensation in the OSIRIS camera

    Science.gov (United States)

    González, J. Jesús; Tejada, Carlos; Farah, Alejandro; Rasilla, Jose L.; Fuentes, F. Javier

    2003-03-01

    Tight stability requirements for the imager/spectrograph OSIRIS (a Day One optical instrument for the GTC telescope) demand a careful treatment of thermal effects within the OSIRIS camera. Mostly due to the thermal response of refraction indices of its glasses (and not so much to curvature, spacing or thickness variations of the lenses), the camera optics alone degrades beyond requirements the image quality and plate scale under the expected ambient temperature variations (about 1.8 °C/hour). Thermal effects and thermal compensator studies of the OSIRIS camera are first summarized, before discussing how the motion (of a few microns per °C) of the 3rd camera doublet, as a sole compensator, practically eliminates thermal influences on both image quality and plate scale. A concept for the passive implementation of the compensator is also discussed.

  10. Non-thermal plasma ethanol reforming in bubbles immersed in liquids

    Science.gov (United States)

    Levko, Dmitry; Sharma, Ashish; Raja, Laxminarayan L.

    2017-03-01

    Ethanol reforming in non-thermal plasma generated in atmospheric-pressure argon bubbles immersed in liquid ethanol/water solution is studied using a self-consistent multi-species fluid model. The influence of the dielectric constant of the liquid on the plasma dynamics and its effect on the generation of active species is analyzed. Several modes of discharge are obtained for large liquid dielectric constant. In these modes, we obtain either an axial streamer or a combination of two simultaneous streamers propagating along the bubble axis and near the liquid wall. The influence of these modes on the production of active species is also studied. The main reactions responsible for the generation of molecular hydrogen and light hydrocarbon species are analyzed. A possible mechanism of hydrogen generation in liquid phase is discussed.

  11. Dispersion relations of externally and thermally excited dust lattice modes in 2D complex plasma crystals

    Energy Technology Data Exchange (ETDEWEB)

    Yang Xuefeng; Cui Jian; Zhang Yuan [School of Mathematical Sciences, Dalian University of Technology, Dalian 116024 (China); Liu Yue [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2012-07-15

    The dispersion relations of the externally and thermally (naturally) excited dust lattice modes (both longitudinal and transverse) in two-dimensional Debye-Yukawa complex plasma crystals are investigated. The dispersion relations are calculated numerically by taking the neutral gas damping effects into account and the numerical results are in agreement with the experimental data given by Nunomura et al.[Phys. Rev. E 65, 066402 (2002)]. It is found that for the mode excited by an external disturbance with a real frequency, the dispersion properties are changed at a critical frequency near where the group velocity of the mode goes to zero. Therefore, the high frequency branch with negative dispersion cannot be reached. In contrast, for the thermally excited mode, the dispersion curve can extend all the way to the negative dispersion region, while a 'cut-off' wave number exists at the long wavelength end of the dispersion in the transverse mode.

  12. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Part II: Analysis of ITER plasma facing components

    Science.gov (United States)

    Federici, Gianfranco; Raffray, A. René

    1997-04-01

    The transient thermal model RACLETTE (acronym of Rate Analysis Code for pLasma Energy Transfer Transient Evaluation) described in part I of this paper is applied here to analyse the heat transfer and erosion effects of various slow (100 ms-10 s) high power energy transients on the actively cooled plasma facing components (PFCs) of the International Thermonuclear Experimental Reactor (ITER). These have a strong bearing on the PFC design and need careful analysis. The relevant parameters affecting the heat transfer during the plasma excursions are established. The temperature variation with time and space is evaluated together with the extent of vaporisation and melting (the latter only for metals) for the different candidate armour materials considered for the design (i.e., Be for the primary first wall, Be and CFCs for the limiter, Be, W, and CFCs for the divertor plates) and including for certain cases low-density vapour shielding effects. The critical heat flux, the change of the coolant parameters and the possible severe degradation of the coolant heat removal capability that could result under certain conditions during these transients, for example for the limiter, are also evaluated. Based on the results, the design implications on the heat removal performance and erosion damage of the variuos ITER PFCs are critically discussed and some recommendations are made for the selection of the most adequate protection materials and optimum armour thickness.

  13. Self consistent thermal wave model description of the transverse dynamics for relativistic charged particle beams in magnetoactive plasmas

    CERN Document Server

    Fedele, Renato; De Nicola, Sergio; Shukla, P K; Jovanovic, Dusan

    2011-01-01

    Thermal Wave Model is used to study the strong self-consistent Plasma Wake Field interaction (transverse effects) between a strongly magnetized plasma and a relativistic electron/positron beam travelling along the external magnetic field, in the long beam limit, in terms of a nonlocal NLS equation and the virial equation. In the linear regime, vortices predicted in terms of Laguerre-Gauss beams characterized by non-zero orbital angular momentum (vortex charge). In the nonlinear regime, criteria for collapse and stable oscillations is established and the thin plasma lens mechanism is investigated, for beam size much greater than the plasma wavelength. The beam squeezing and the self-pinching equilibrium is predicted, for beam size much smaller than the plasma wavelength, taking the aberrationless solution of the nonlocal Nonlinear Schroeding equation.

  14. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Part I: Theory and description of model capabilities

    Science.gov (United States)

    Raffray, A. René; Federici, Gianfranco

    1997-04-01

    RACLETTE (Rate Analysis Code for pLasma Energy Transfer Transient Evaluation), a comprehensive but relatively simple and versatile model, was developed to help in the design analysis of plasma facing components (PFCs) under 'slow' high power transients, such as those associated with plasma vertical displacement events. The model includes all the key surface heat transfer processes such as evaporation, melting, and radiation, and their interaction with the PFC block thermal response and the coolant behaviour. This paper represents part I of two sister and complementary papers. It covers the model description, calibration and validation, and presents a number of parametric analyses shedding light on and identifying trends in the PFC armour block response to high plasma energy deposition transients. Parameters investigated include the plasma energy density and deposition time, the armour thickness and the presence of vapour shielding effects. Part II of the paper focuses on specific design analyses of ITER plasma facing components (divertor, limiter, primary first wall and baffle), including improvements in the thermal-hydraulic modeling required for better understanding the consequences of high energy deposition transients in particular for the ITER limiter case.

  15. Plasma diagnostic techniques in thermal-barrier tandem-mirror fusion experiments

    Energy Technology Data Exchange (ETDEWEB)

    Silver, E.H.; Clauser, J.F.; Carter, M.R.; Failor, B.H.; Foote, J.H.; Hornady, R.S.; James, R.A.; Lasnier, C.J.; Perkins, D.E.

    1986-08-29

    We review two classes of plasma diagnostic techniques used in thermal-barrier tandem-mirror fusion experiments. The emphasis of the first class is to study mirror-trapped electrons at the thermal-barrier location. The focus of the second class is to measure the spatial and temporal behavior of the plasma space potential at various axial locations. The design and operation of the instruments in these two categories are discussed and data that are representative of their performance is presented.

  16. Compressive and Rarefactive Waves in Dust Plasma with Non-thermal Ions

    Institute of Scientific and Technical Information of China (English)

    DUAN Wen-Shan; WANG Hong-Yan; John Parkes

    2006-01-01

    The governing equation of the dust fluid with non-thermal ions and variable dust charge on dust particles in hot dust plasmas is obtained. Both the compressive and rarefactive waves in this system are investigated. They can be determined by plasma parameters including the temperatures of dust fluid, ions and electrons, as well as the non-thermal parameter of ions, and the number densities of the dust particles, the ions and the electrons, etc.

  17. Electromagnetic field occupational exposure: non-thermal vs. thermal effects.

    Science.gov (United States)

    Israel, M; Zaryabova, V; Ivanova, M

    2013-06-01

    There are a variety of definitions for "non-thermal effects" included in different international standards. They start by the simple description that they are "effects of electromagnetic energy on a body that are not heat-related effects", passing through the very general definition related to low-level effects: "biological effects ascribed to exposure to low-level electric, magnetic and electromagnetic fields, i.e. at or below the corresponding dosimetric reference levels in the frequency range covered in this standard (0 Hz-300 GHz)", and going to the concrete definition of "the stimulation of muscles, nerves, or sensory organs, vertigo or phosfenes". Here, we discuss what kind of effect does the non-thermal one has on human body and give data of measurements in different occupations with low-frequency sources of electromagnetic field such as electric power distribution systems, transformers, MRI systems and : video display units (VDUs), whereas thermal effects should not be expected. In some of these workplaces, values above the exposure limits could be found, nevertheless that they are in the term "non-thermal effects" on human body. Examples are workplaces in MRI, also in some power plants. Here, we will not comment on non-thermal effects as a result of RF or microwave exposure because there are not proven evidence about the existance of such effects and mechanisms for them are not clear.

  18. Dentin surface treatment using a non-thermal argon plasma brush for interfacial bonding improvement in composite restoration

    Science.gov (United States)

    Ritts, Andy Charles; Li, Hao; Yu, Qingsong; Xu, Changqi; Yao, Xiaomei; Hong, Liang; Wang, Yong

    2010-01-01

    The objective of this study is to investigate the treatment effects of non-thermal atmospheric gas plasmas on dentin surfaces for composite restoration. Extracted unerupted human third molars were used by removing the crowns and etching the exposed dentin surfaces with 35% phosphoric acid gel. The dentin surfaces were treated by using a non-thermal atmospheric argon plasma brush for various durations. The molecular changes of the dentin surfaces were analyzed using FTIR/ATR and an increase in carbonyl groups on dentin surfaces was detected with plasma treated dentin. Adper Single Bond Plus adhesive and Filtek Z250 dental composite were applied as directed. To evaluate the dentin/composite interfacial bonding, the teeth thus prepared were sectioned into micro-bars as the specimens for tensile test. Student Newman Keuls tests showed that the bonding strength of the composite restoration to peripheral dentin was significantly increased (by 64%) after 30 s plasma treatment. However, the bonding strength to plasma treated inner dentin did not show any improvement. It was found that plasma treatment of peripheral dentin surface up to 100 s gave an increase in interfacial bonding strength, while a prolong plasma treatment of dentin surfaces, e.g., 5 min treatments, showed a decrease in interfacial bonding strength. PMID:20831586

  19. Intermittent thermal plasma acceleration linked to sporadic motions of the magnetopause, first Cluster results

    Directory of Open Access Journals (Sweden)

    J.-A. Sauvaud

    Full Text Available This paper presents the first observations with Cluster of a very dense population of thermal ionospheric ions (H+, He+, O+ locally "accelerated" perpendicularly to the local magnetic field in a region adjacent to the magnetopause and on its magnetospheric side. The observation periods follow a long period of very weak magnetic activity. Recurrent motions of the magnetopause are, in the presented cases, unexpectedly associated with the appearance inside closed field lines of recurrent energy structures of ionospheric ions with energies in the 5 eV to  ~1000 eV range. The heaviest ions were detected with the highest energies. Here, the ion behaviour is interpreted as resulting from local electric field enhancements/decreases which adiabatically enhance/lower the bulk energy of a local dense thermal ion population. This drift effect, which is directly linked to magnetopause motions caused by pressure changes, allows for the thermal ions to overcome the satellite potential and be detected by the suprathermal CIS Cluster experiment. When fast flowing, i.e. when detectable, the density (~ 1 cm-3 of these ions from a terrestrial origin is (in the cases presented here largely higher than the local density of ions from magnetospheric/plasma sheet origin which poses again the question of the relative importance of solar and ionospheric sources for the magnetospheric plasma even during very quiet magnetic conditions.

    Key words. Ionosphere (planetary ionosphere; plasma convection Magnetospheric physics (magnetopause, cusp and boundary layers

  20. Thermal Plasma Synthesis of Crystalline Gallium Nitride Nanopowder from Gallium Nitrate Hydrate and Melamine

    Directory of Open Access Journals (Sweden)

    Tae-Hee Kim

    2016-02-01

    Full Text Available Gallium nitride (GaN nanopowder used as a blue fluorescent material was synthesized by using a direct current (DC non-transferred arc plasma. Gallium nitrate hydrate (Ga(NO33∙xH2O was used as a raw material and NH3 gas was used as a nitridation source. Additionally, melamine (C3H6N6 powder was injected into the plasma flame to prevent the oxidation of gallium to gallium oxide (Ga2O3. Argon thermal plasma was applied to synthesize GaN nanopowder. The synthesized GaN nanopowder by thermal plasma has low crystallinity and purity. It was improved to relatively high crystallinity and purity by annealing. The crystallinity is enhanced by the thermal treatment and the purity was increased by the elimination of residual C3H6N6. The combined process of thermal plasma and annealing was appropriate for synthesizing crystalline GaN nanopowder. The annealing process after the plasma synthesis of GaN nanopowder eliminated residual contamination and enhanced the crystallinity of GaN nanopowder. As a result, crystalline GaN nanopowder which has an average particle size of 30 nm was synthesized by the combination of thermal plasma treatment and annealing.

  1. Transition Region Emission and the Energy Input to Thermal Plasma in Solar Flares

    Science.gov (United States)

    Holman, Gordon D.; Holman, Gordon D.; Dennis, Brian R.; Haga, Leah; Raymond, John C.; Panasyuk, Alexander

    2005-01-01

    Understanding the energetics of solar flares depends on obtaining reliable determinations of the energy input to flare plasma. X-ray observations of the thermal bremsstrahlung from hot flare plasma provide temperatures and emission measures which, along with estimates of the plasma volume, allow the energy content of this hot plasma to be computed. However, if thermal energy losses are significant or if significant energy goes directly into cooler plasma, this is only a lower limit on the total energy injected into thermal plasma during the flare. We use SOHO UVCS observations of O VI flare emission scattered by coronal O VI ions to deduce the flare emission at transition region temperatures between 100,000 K and 1 MK for the 2002 July 23 and other flares. We find that the radiated energy at these temperatures significantly increases the deduced energy input to the thermal plasma, but by an amount that is less than the uncertainty in the computed energies. Comparisons of computed thermal and nonthermal electron energies deduced from RHESSI, GOES, and UVCS are shown.

  2. Influence of injected silver content on synthesis of silver coated nickel particles by DC thermal plasma

    Science.gov (United States)

    Park, Si Taek; Kim, Tae-Hee; Park, Dong-Wha

    2016-06-01

    Silver nanoparticle-coated spherical nickel particles were prepared from a mixture of micro-sized silver and nickel as raw materials by DC thermal plasma treatment. The mixture of micro-sized silver and nickel powders was injected into the high-temperature region of an argon thermal plasma jet. Although the silver, with its very high thermal conductivity and relatively low boiling point, was thoroughly evaporated by this process, nickel was not evaporated perfectly because of its comparatively low thermal conductivity and high boiling point. The rough nickel powder was spheroidized as it melted. Finally, silver evaporated by the thermal plasma quickly condensed into nanoparticles on the surfaces of the micro-sized spherical nickel particles, aided by the sharp temperature gradient of the thermal plasma jet. With varying the ratios of silver to nickel feedstock from 1:10 to 5:1, the products synthesized in each condition were examined by XRD, XPS, FE-SEM, and FE-TEM. More silver nanoparticles were attached on the nickel by increasing the injected feedstock to 9.8 at% silver. Meanwhile, a decrease of silver in the products was observed when larger amounts of silver were introduced to the thermal plasma jet. The exposed silver components decreased with greater proportions of silver feedstock because of the metal's dendritic structure and the formation of silver-coated silver particles.

  3. Thermal effects in radiation processing

    Energy Technology Data Exchange (ETDEWEB)

    Zagorski, Z.P.

    1984-10-21

    The balance of ionizing radiation energy incident on an object being processed is discussed in terms of energy losses, influencing the amount really absorbed. To obtain the amount of heat produced, the absorbed energy is corrected for the change in internal energy of the system and for the heat effect of secondary reactions developing after the initiation. The temperature of a processed object results from the heat evolved and from the specific heat of the material comprising the object. The specific heat of most materials is usually much lower than that of aqueous systems and therefore temperatures after irradiation are higher. The role of low specific heat in radiation processing at cryogenic conditions is stressed. Adiabatic conditions of accelerator irradiation are contrasted with the steady state thermal conditions prevailing in large gamma sources. Among specific questions discussed in the last part of the paper are: intermediate and final temperature of composite materials, measurement of real thermal effects in situ, neutralization of undesired warming experienced during radiation processing, processing at temperatures other than ambient and administration of very high doses of radiation.

  4. Development of innovative thermal plasma and particle diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Bachmann, Benjamin-Leon

    2013-09-24

    Three original plasma diagnostic systems have been developed to investigate transient three-dimensional plasma processes with high spatial and temporal resolution. The developed diagnostics have been analyzed and tested by increasing the complexity from a stationary free burning Argon arc to a dc pulsed process and finally to a transient gas metal arc including droplet transfer through the plasma. The transient plasma parameters that have been determined include three-dimensional axially symmetric plasma densities (n{sub e}, n{sub A}, n{sub A+}, n{sub A++}), electron temperatures (T{sub e}), electrical conductivities (σ{sub el}), magnetic flux densities (B) and current densities (j{sub el}). In the case of a droplet transfer through an arc consisting of an Iron/Argon plasma, the droplet density, surface tension, viscosity, and temperature have been determined.

  5. Collisional Thermalization in Strongly Coupled Ultracold Neutral Plasmas

    Science.gov (United States)

    2017-01-25

    ultracold neutral plasmas, which are formed by photoionizing laser cooled atoms. These are the coldest neutral plasmas every created, and they allow...and received the “Editors’ Suggestion” distinction. We also completed numerical modeling of laser cooling a neutral plasma and construction of the...We also had to install several laser systems for driving the laser - cooling transitions in the ions and for repumping atoms out of dark states

  6. Microstructural evolution and growth kinetics of thermally grown oxides in plasma sprayed thermal barrier coatings

    Directory of Open Access Journals (Sweden)

    Xiaoju Liu

    2016-02-01

    Full Text Available The formation of thermally grown oxide (TGO during high temperature is a key factor to the degradation of thermal barrier coatings (TBCs applied on hot section components. In the present study both the CoNiCrAlY bond coat and ZrO2-8 wt.% Y2O3 (8YSZ ceramic coat of TBCs were prepared by air plasma spraying (APS. The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy (SEM, energy dispersive spectroscopy (EDS and X-ray diffraction (XRD analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 °C for various times. The results showed that as-sprayed bond coat consisted of β and γ/γ′phases, β phase reducesd as the oxidation time increased. The TGO comprised α-Al2O3 formed in the first 2 h. CoO, NiO, Cr2O3 and spinel oxides appeared after 20 h of oxidation. Contents of CoO and NiO reduced while that of Cr2O3 and spinel oxides increased in the later oxidation stage. The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 μm/h0.5 for TBCs and 0.354 μm/h0.5 for pure BCs.

  7. Microstructural evolution and growth kinetics of thermally grown oxides in plasma sprayed thermal barrier coatings

    Institute of Scientific and Technical Information of China (English)

    Xiaoju Liu; Teng Wang; Caicai Li; Zhenhuan Zheng; Qiang Li

    2016-01-01

    The formation of thermally grown oxide (TGO) during high temperature is a key factor to the degradation of thermal barrier coatings (TBCs) applied on hot section components. In the present study both the CoNiCrAlY bond coat and ZrO2-8 wt.% Y2O3 (8YSZ) ceramic coat of TBCs were prepared by air plasma spraying (APS). The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 °C for various times. The results showed that as-sprayed bond coat consisted of β and γ/γ'phases,β phase reducesd as the oxidation time increased. The TGO comprised α-Al2O3 formed in the first 2 h. CoO, NiO, Cr2O3 and spinel oxides appeared after 20 h of oxidation. Contents of CoO and NiO reduced while that of Cr2O3 and spinel oxides increased in the later oxidation stage. The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 μm/h0.5 for TBCs and 0.354 μm/h0.5 for pure BCs.

  8. Fatigue testing of plasma-sprayed thermal barrier coatings, volume 2

    Science.gov (United States)

    Cruse, T. A.; Nagy, A.; Popelar, C. F.

    1990-01-01

    A plasma sprayed thermal barrier coating for diesel engines were fatigue tested. Candidate thermal barrier coating materials were fatigue screened and a data base was generated for the selected candidate material. Specimen configurations are given for the bend fatigue tests, along with test setup, specimen preparation, test matrix and procedure, and data analysis.

  9. Fatigue testing of plasma-sprayed thermal barrier coatings, Volume 2. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Cruse, T.A.; Nagy, A.; Popelar, C.F.

    1990-07-01

    A plasma sprayed thermal barrier coating for diesel engines were fatigue tested. Candidate thermal barrier coating materials were fatigue screened and a data base was generated for the selected candidate material. Specimen configurations are given for the bend fatigue tests, along with test setup, specimen preparation, test matrix and procedure, and data analysis.

  10. The Application of Thermal Plasma to Extraction Metallurgy and Related Fields

    Science.gov (United States)

    Akashi, K.

    1980-01-01

    Various applications of thermal plasma to extraction metallurgy and related fields are surveyed, chiefly on the basis of documents published during the past two or three years. Applications to melting and smelting, to thermal decomposition, to reduction, to manufacturing of inorganic compounds, and to other fields are considered.

  11. Dielectric effects on Thomson scattering in a relativistic magnetized plasma

    DEFF Research Database (Denmark)

    Bindslev, H.

    1991-01-01

    the absorption is small. Symmetry between variables relating to incident and scattered fields is demonstrated and shown to be in agreement with the reciprocity relation. Earlier results are confirmed in the cold plasma limit. Significant relativistic effects, of practical importance to the scattering......The effects of the dielectric properties of a relativistic magnetized plasma on the scattering of electromagnetic radiation by fluctuations in electron density are investigated. The origin of the density fluctuations is not considered. Expressions for the scattering cross-section and the scattered...... power accepted by the receiving antenna are derived for a plasma with spatial dispersion. The resulting expressions allow thermal motion to be included in the description of the plasma and remain valid for frequencies of the probing radiation in the region of omega(p) and omega(ce), provided...

  12. Thermal rho`s in the quark-gluon plasma

    Energy Technology Data Exchange (ETDEWEB)

    Pisarski, R.D.

    1995-03-01

    I discuss different models which predict changes in the mass of the thermal {rho} field. I emphasize that while the predictions are strongly model dependent, nevertheless substantial shifts in the thermal {rho} mass are expected to occur at the point of phase transition. As long as the thermal {rho} peak does not become too broad, this should provide a striking signature of the existence of a phase transition.

  13. Thermal $\\varrho$s in the quark-gluon plasma

    CERN Document Server

    Pisarski, R D

    1995-01-01

    I discuss different models which predict changes in the mass of the thermal \\rho field. I emphasize that while the predictions are strongly model dependent, nevertheless substantial shifts in the thermal \\rho mass are expected to occur at the point of phase transition. As long as the thermal \\rho peak does not become too broad, this should provide a striking signature of the existence of a phase transition. (Based upon a talk presented at Quark Matter '95, Monterey, CA, Jan., 1995.)

  14. Boundary Conditions at the Walls with Thermionic Electron Emission in Two Temperature Modeling of "Thermal" Plasmas

    CERN Document Server

    Pekker, Leonid

    2015-01-01

    In this paper we propose new boundary conditions at the hot walls with thermionic electron emission for two-temperature thermal arc models. In the derived boundary conditions the walls are assumed to be made from refractory metals and that the erosion of the wall is small and, therefore, is not taken into account in the model. In these boundary conditions the plasma sheath formed at the electrode is considered as the interface between the plasma and the wall. The derived boundary conditions allow the calculation of the heat flux to the walls from the plasma and consequently the thermionic electron current that makes the two temperature thermal model self consistent.

  15. Nonperturbative effects in a rapidly expanding quark gluon plasma

    CERN Document Server

    Mohanty, A K; Gleiser, Marcello; 10.1103/PhysRevC.65.034908

    2002-01-01

    Within first-order phase transitions, we investigate pretransitional effects due to the nonperturbative, large-amplitude thermal fluctuations which can promote phase mixing before the critical temperature is reached from above. In contrast with the cosmological quark-hadron transition, we find that the rapid cooling typical of the relativistic heavy ion collider and large hadron collider experiments and the fact that the quark-gluon plasma is chemically unsaturated suppress the role of nonperturbative effects at current collider energies. Significant supercooling is possible in a (nearly) homogeneous state of quark gluon plasma. (24 refs).

  16. Binary collision rates of relativistic thermal plasmas. I Theoretical framework

    Science.gov (United States)

    Dermer, C. D.

    1985-01-01

    Binary collision rates for arbitrary scattering cross sections are derived in the case of a beam of particles interacting with a Maxwell-Boltzmann (MB) plasma, or in the case of two MB plasmas interacting at generally different temperatures. The expressions are valid for all beam energies and plasma temperatures, from the nonrelativistic to the extreme relativistic limits. The calculated quantities include the reaction rate, the energy exchange rate, and the average rate of change of the squared transverse momentum component of a monoenergetic particle beam as a result of scatterings with particles of a MB plasma. Results are specialized to elastic scattering processes, two-temperature reaction rates, or the cold plasma limit, reproducing previous work.

  17. The physics of thermal plasma in the magnetosphere; Proceedings of Symposium 9 of the 26th COSPAR Plenary Meeting, Toulouse, France, June 30-July 11, 1986

    Science.gov (United States)

    Chappell, C. R. (Editor); Gringauz, K. I. (Editor)

    1986-01-01

    The conference presents papers on the shape, dynamics, and thermal structure of the plasmasphere and plasmapause; the ionosphere as a supplier of plasma to the earth's magnetosphere; the modeling and remote sensing of thermal plasma in the earth's magnetosphere; and magnetospheric cold plasmas as a medium for wave generation and propagation. Particular attention is given to whistler studies of plasmasphere shape and dynamics, plasmasphere thermal structure as measured by ISEE-1 and DE-1, low-energy ion flows into the magnetosphere, field-aligned flows of ionospheric plasma in the magnetosphere, and field-aligned plasmaspheric flows at moderate latitudes. Papers are also presented on the effects of a tailward stretching geomagnetic field on the drift motion of plasma particles in the magnetospheric equatorial plane, ion cyclotron waves observed near the plasmapause, and the response of energetic particles to nightside magnetic pulsations as seen by AMPTE/CCE.

  18. Star formation through thermal instability of radiative plasma with finite electron inertia and finite Larmor radius corrections

    Directory of Open Access Journals (Sweden)

    Sachin Kaothekar

    2016-08-01

    Full Text Available I have studied the effects of finite electron inertia, finite ion Larmor radius (FLR corrections, and radiative heat-loss function on the thermal instability of an infinite homogeneous, viscous plasma incorporating the effect of thermal conductivity for star formation in interstellar medium (ISM. A general dispersion relation is derived using the normal mode analysis method with the help of relevant linearized perturbation equations of the problem. The wave propagation is discussed for longitudinal and transverse directions to the external magnetic field and the conditions of modified thermal instabilities and stabilities are discussed in different cases. We find that the thermal instability criterion is get modified into radiative instability criterion by inclusion of radiative heat-loss functions with thermal conductivity. The viscosity of medium removes the effect of FLR corrections from the condition of radiative instability. Numerical calculation shows stabilizing effect of heat-loss function, viscosity and FLR corrections, and destabilizing effect of finite electron inertia on the thermal instability. Results carried out in this paper shows that stars are formed in interstellar medium mainly due to thermal instability.

  19. DC Thermal Plasma Design and Utilization for the Low Density Polyethylene to Diesel Oil Pyrolysis Reaction

    Directory of Open Access Journals (Sweden)

    Hossam A. Gabbar

    2017-06-01

    Full Text Available The exponential increase of plastic production produces 100 million tonnes of waste plastics annually which could be converted into hydrocarbon fuels in a thermal cracking process called pyrolysis. In this research work, a direct current (DC thermal plasma circuit is designed and used for conversion of low density polyethylene (LDPE into diesel oil in a laboratory scale pyrolysis reactor. The experimental setup uses a 270 W DC thermal plasma at operating temperatures in the range of 625 °C to 860 °C for a low density polyethylene (LDPE pyrolysis reaction at pressure = −0.95, temperature = 550 °C with τ = 30 min at a constant heating rate of 7.8 °C/min. The experimental setup consists of a vacuum pump, closed system vessel, direct current (DC plasma circuit, and a k-type thermocouple placed a few millimeters from the reactant sample. The hydrocarbon products are condensed to diesel oil and analyzed using flame ionization detector (FID gas chromatography. The analysis shows 87.5% diesel oil, 1,4-dichlorobenzene (Surr, benzene, ethylbenzene and traces of toluene and xylene. The direct current (DC thermal plasma achieves 56.9 wt. % of diesel range oil (DRO, 37.8 wt. % gaseous products and minimal tar production. The direct current (DC thermal plasma shows reliability, better temperature control, and high thermal performance as well as the ability to work for long operation periods.

  20. Influence of high flux hydrogen-plasma exposure on the thermal shock induced crack formation in tungsten

    NARCIS (Netherlands)

    Wirtz, M.; Linke, J.; Pintsuk, G.; Rapp, J.; Wright, G. M.

    2012-01-01

    The influence of high flux hydrogen-plasma on the thermal shock behaviour of tungsten was investigated in a combined experiment using the linear plasma device Pilot-PSI and the electron beam facility JUDITH 1. Tungsten targets were exposed to high flux hydrogen plasma, cyclic thermal shock tests and

  1. Electrochemical performance of Si-multiwall carbon nanotube nanocomposite anode synthesized by thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Na, Ye-Seul; Yoo, Hyeonseok; Kim, Tae-Hee; Choi, Jinsub; Lee, Wan In; Choi, Sooseok, E-mail: sooseok@jejunu.ac.kr; Park, Dong-Wha, E-mail: dwpark@inha.ac.kr

    2015-07-31

    Lithium-ion (Li-ion) batteries are widely used in electric devices and vehicles. Silicon is a promising material for the anode of Li-ion battery due to high theoretical specific capacity. However, it shows large volume changes during charge–discharge cycles leading to the pulverization of electrode. In order to improve such disadvantage, a multiwall carbon nanotube (MWCNT) has been used with silicon as composite material. In this work, Si-MWCNT nanocomposite was prepared in thermal plasma by attaching silicon nanoparticles to MWCNT column. Electrochemical tests for raw materials and synthesized nanocomposites were carried out. The discharge capacities of silicon, MWCNT, synthesized nanocomposites collected from a reaction tube, and a chamber were 4000, 310, 200, and 1447 mAh/g, respectively. - Highlights: • Si-Multiwall carbon nanotube nanocomposite was synthesized by thermal plasma. • The effect on the collection position of product after experiment was examined. • Cycle performance of electrodes was measured. • Product collected from chamber showed good electrochemical performance.

  2. Hydrogen and Carbon Black Production from the Degradation of Methane by Thermal Plasma

    Directory of Open Access Journals (Sweden)

    Leila Cottet

    2014-05-01

    Full Text Available Methane gas (CH4 is the main inducer of the so called greenhouse gases effect. Recent scientific research aims to minimize the accumulation of this gas in the atmosphere and to develop processes capable of producing stable materials with added value. Thermal plasma technology is a promising alternative to these applications, since it allows obtaining H2 and solid carbon from CH4, without the parallel formation of byproducts such as CO2 and NOx. In this work, CH4 was degraded by thermal plasma in order to produce hydrogen (H2 and carbon black. The degradation efficiency of CH4, selectivity for H2 production as well as the characterization of carbon black were studied. The best results were obtained in the CH4 flow rate of 5 L min-1 the degradation percentage and the selectivity for H2 production reached 98.8 % and 48.4 %, respectively. At flow rates of less than 5 L min-1 the selectivity for H2 production increases and reaches 91.9 %. The carbon black has obtained amorphous with hydrophobic characteristics and can be marketed to be used in composite material, and can also be activated chemically and/or physically and used as adsorbent material.

  3. Isothermal Oxidation Behavior of Supersonic Atmospheric Plasma-Sprayed Thermal Barrier Coating System

    Science.gov (United States)

    Bai, Yu; Ding, Chunhua; Li, Hongqiang; Han, Zhihai; Ding, Bingjun; Wang, Tiejun; Yu, Lie

    2013-10-01

    In this work, Y2O3 stabilized zirconia-based thermal barrier coatings (TBCs) were deposited by conventional atmospheric plasma spraying (APS) and high efficiency supersonic atmospheric plasma spraying (SAPS), respectively. The effect of Al2O3 layer stability on the isothermal growth behavior of thermally grown oxides (TGOs) was studied. The results revealed that the Al2O3 layer experienced a three-stage change process, i.e., (1) instantaneous growth stage, (2) steady-state growth stage, and (3) depletion stage. The thickness of Al2O3 scale was proved to be an important factor for the growth rate of TGOs. The SAPS-TBCs exhibited a higher Al2O3 stability and better oxidation resistance as compared with the APS-TBCs. Additionally, it was found that inner oxides, especially nucleated on the top of the crest, continually grew and swallowed the previously formed Al2O3 layer, leading to the granulation and disappearance of continuous Al2O3 scale, which was finally replaced by the mixed oxides and spinel.

  4. Modification of a metallic surface in a vacuum arc discharge plasma using thermally stimulated ion diffusion

    Science.gov (United States)

    Muboyadzhyan, S. A.

    2008-12-01

    A new process for modifying a metallic surface in a vacuum arc discharge plasma using thermally stimulated ion diffusion is considered. The effect of the bias voltage (negative substrate potential) on the processes that occur on the surface of a treated part is studied when the substrate material interacts with an accelerated metallic-ion flow. The phase and elemental compositions of the modified layer are studied for substrates made of nickel-based superalloys, austenitic and martensitic steels, and titanium-based alloys. The heat resistance, the salt corrosion resistance, and the corrosion cracking resistance of steels and titanium-based alloys are investigated after their modification in vacuum arc plasmas of pure metals (Ti, Zr, Al, Cr, Y) and related alloys. The surface modification caused by the thermally stimulated ion saturation of the surfaces of parts made from structural materials is shown to change the structural-phase states of their surfaces and, correspondingly, the properties of these materials in relation to the state of the surface.

  5. Indentations on Air Plasma Sprayed Thermal Barrier Coatings Prepared by Different Starting Granules

    Directory of Open Access Journals (Sweden)

    Yong Suk Heo

    2015-01-01

    Full Text Available The effect of starting granules on the indentation properties of air plasma sprayed thermal barrier coatings (TBCs is investigated in this paper. Various kinds of spray-dried granules are prepared from different processing conditions, especially varying solvent and dispersant, showing a deformed hollow-typed and a filled spherical-typed granule. The similar coating thicknesses are prepared by adjusting process parameters during air plasma spray. All XRD peaks in phase analysis are tetragonal and cubic phases without any monoclinic phase after the starting granules were heat-treated. A relatively porous microstructure of the coating layer could be obtained from the monodisperse granules, while a relatively dense microstructure resulted from the hollow-typed granules. The morphology and distribution of the granules crucially affect the microstructure of thermal barrier coatings and thus have influences on indentation properties such as indentation stress-strain curves, contact damage, and hardness. The implication concerning microstructure design of TBCs for gas turbine applications is considered.

  6. Energy recovery from waste glycerol by utilizing thermal water vapor plasma.

    Science.gov (United States)

    Tamošiūnas, Andrius; Valatkevičius, Pranas; Gimžauskaitė, Dovilė; Jeguirim, Mejdi; Mėčius, Vladas; Aikas, Mindaugas

    2017-04-01

    Glycerol, considered as a waste feedstock resulting from biodiesel production, has received much attention in recent years due to its properties, which offer to recover energy. The aim of this study was to investigate the use of a thermal water vapor plasma for waste (crude) glycerol conversion to synthesis gas, or syngas (H2 + CO). In parallel of crude glycerol, a pure glycerol (99.5%) was used as a reference material in order to compare the concentrations of the formed product gas. A direct current (DC) arc plasma torch stabilized by a mixture of argon/water vapor was utilized for the effective glycerol conversion to hydrogen-rich synthesis gas. It was found that after waste glycerol treatment, the main reaction products were gases with corresponding concentrations of H2 50.7%, CO 23.53%, CO2 11.45%, and CH4 3.82%, and traces of C2H2 and C2H6, which concentrations were below 0.5%. The comparable concentrations of the formed gas products were obtained after pure glycerol conversion-H2 46.4%, CO 26.25%, CO2 11.3%, and CH4 4.7%. The use of thermal water vapor plasma producing synthesis gas is an effective method to recover energy from both crude and pure glycerol. The performance of the glycerol conversion system was defined in terms of the produced gas yield, the carbon conversion efficiency, the cold gas efficiency, and the specific energy requirements.

  7. Thermal effects on fish ecology

    Science.gov (United States)

    Coutant, Charles C.

    1976-01-01

    Of all the environmental factors that influence aquatic organisms, temperature is the most all-pervasive. There is always an environmental temperature while other factors may or may not be present to exert their effects. Fish are, for all practical purposes, thermal conformers, or obligate poikilotherms. That is, they are able to exert little significant influence on maintaining a certain body temperature by specialized metabolic or behavioral means. Their body temperature thus fluctuates nearly in concert with the temperature of their aquatic medium (although particularly large, actively-moving fish such as tuna have deep muscle temperatures slightly higher than the water). Intimate contact at the gills of body fluids with the outside water and the high specific heat of water provide a very efficient heat exchanger that insures this near identity of internal and external temperatures.

  8. Thermal Bremsstrahlung Radiation in a Two-Temperature Plasma

    Institute of Scientific and Technical Information of China (English)

    Bin Luo; Shuang-Nan Zhang

    2004-01-01

    In normal one-temperature plasma the motion of ions is usually neglected when calculating the Bremsstrahlung radiation of the plasma.We calculate the Bremsstrahlung radiation of a two-temperature plasma by taking into account of the motion of ions.Our results show that the total radiation power is always lower if the motion of ions is considered.We also apply the two-temperature Bremsstrahlung radiation mechanism for an analytical Advection-Dominated Accretion Flow(ADAF)model:we find the two-temperature correction to the total Bremsstrahlung radiation for ADAF is negligible.

  9. Carbon dioxide dissociation in non-thermal radiofrequency and microwave plasma

    Science.gov (United States)

    Huang, Qiang; Zhang, Diyu; Wang, Dongping; Liu, Kezhao; Kleyn, Aart W.

    2017-07-01

    We have studied carbon dioxide dissociation in inductively coupled radiofrequency plasma and microwave plasma at low gas pressure. Both systems exhibit features of non-thermal plasma. The highest energy efficiency observed is 59.3% (2.13 mmol kJ-1), exceeding the maximum value of about 45% in case of thermodynamic equilibrium, and a maximum conversion of 80.6% is achieved. Different discharge conditions, such as the source frequency, discharge gas pressure and the addition of argon, will affect the plasma parameters, especially the electron energy distribution. This plays a great role in the energy transfer from non-thermal plasma to the molecular dissociation reaction channel by enabling the ladder climbing of the carbon dioxide molecular vibration. The results indicate the importance of ladder climbing.

  10. Cell death induced on cell cultures and nude mouse skin by non-thermal, nanosecond-pulsed generated plasma.

    Directory of Open Access Journals (Sweden)

    Arnaud Duval

    Full Text Available Non-thermal plasmas are gaseous mixtures of molecules, radicals, and excited species with a small proportion of ions and energetic electrons. Non-thermal plasmas can be generated with any high electro-magnetic field. We studied here the pathological effects, and in particular cell death, induced by nanosecond-pulsed high voltage generated plasmas homogeneously applied on cell cultures and nude mouse skin. In vitro, Jurkat cells and HMEC exhibited apoptosis and necrosis, in dose-dependent manner. In vivo, on nude mouse skin, cell death occurred for doses above 113 J/cm(2 for the epidermis, 281 J/cm(2 for the dermis, and 394 J/cm(2 for the hypodermis. Using electron microscopy, we characterized apoptosis for low doses and necrosis for high doses. We demonstrated that these effects were not related to thermal, photonic or pH variations, and were due to the production of free radicals. The ability of cold plasmas to generate apoptosis on cells in suspension and, without any sensitizer, on precise skin areas, opens new fields of application in dermatology for extracorporeal blood cell treatment and the eradication of superficial skin lesions.

  11. Thermal and electrical influences from bulk plasma in cathode heating modeling

    Science.gov (United States)

    Chen, Tang; Wang, Cheng; Zhang, Xiao-Ning; Zhang, Hao; Xia, Wei-Dong

    2017-02-01

    In this paper, a numerical calculation is performed for the purpose of estimating the thermal and electrical influences from bulk plasma in cathode heating modeling, in other words researching the necessity of a coupling bulk plasma in near-cathode layer modeling. The proposed model applied in the present work is an improved one from previous work. In this model, the near-cathode region is divided into two parts: the sheath and the ionization layer. The Schottky effect at the cathode surface is considered based on the analytic solution of a 1D sheath model. It is noted that the arc column is calculated simultaneously in the near-cathode region and the cathode bulk. An application is presented for an atmospheric free burning argon arc with arc currents of 50 A-600 A. The modeling results show three interesting points: (1) at the cathode surface, energy transport due to heat conduction of heavy particles and electrons is comparable to total heating flux, no matter whether the arc discharge is performed in a high (400 A) or low current (50 A) situation; (2) the electrical influence from bulk plasma on the cathode heating modeling becomes obvious in a high current situation (>400 A) for the spot mode; (3) the near-cathode layer voltage drop ({{U}\\text{tot}} ) is larger in the diffuse mode than in the spot mode for the same current, which is just the opposite to that for decoupled modeling.

  12. Non-thermal plasma-activated water inactivation of food-borne pathogen on fresh produce.

    Science.gov (United States)

    Ma, Ruonan; Wang, Guomin; Tian, Ying; Wang, Kaile; Zhang, Jue; Fang, Jing

    2015-12-30

    Non-thermal plasma has been widely considered to be an effective method for decontamination of foods. Recently, numerous studies report that plasma-activated water (PAW) also has outstanding antibacterial ability. This study presents the first report on the potential of PAW for the inactivation of Staphylococcus aureus (S. aureus) inoculated on strawberries. PAW treatments achieved a reduction of S. aureus ranging from 1.6 to 2.3 log at day-0 storage, while 1.7 to 3.4 log at day-4 storage. The inactivation efficiency depended on the plasma-activated time for PAW generation and PAW-treated time of strawberries inoculated with S. aureus. LIVE/DEAD staining and scanning electron microscopy results confirm that PAW could damage the bacterial cell wall. Moreover, optical emission spectra and oxidation reduction potential results demonstrate the inactivation is mainly attributed to oxidative stress induced by reactive oxygen species in PAW. In addition, no significant change was found in color, firmness and pH of the PAW treated strawberries. Thus, PAW can be a promising alternative to traditional sanitizers applied in the fresh produce industry.

  13. Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers

    Directory of Open Access Journals (Sweden)

    G. Kalacska

    2016-05-01

    Full Text Available Tribological performance of the materials greatly depends on the temperature of the contacting zones and surfaces and hence on the heat conducting behaviour of the materials. Heat conduction of polymers is, however, greatly affected even by a very narrow (few tens of nm modified layer formed on the surface after subjecting the polymer to plasma treatment. In this article the heat flow inhibiting properties of plasma modified surface layers were investigated on polyethylene terephthalate (PET and polyamide-6 (PA6 engineering polymers. Nitrogen Plasma Immersion Ion Implantation gave rise to compositional and structural changes of the polymers in a depth of 110 nm. It was found that even this thin layer exhibited significant heat flow inhibiting effect. The modified layer considerably decreased the thermal conductivity coefficient of the treated polymer and resulted in a reduced heat transmission for PET and PA6 by 33 and 28%, respectively. This new information supports and is in accordance with the former tribological results about extra friction heat generation experienced under NPIII surface layer of PA6 and PET during dry sliding.

  14. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling.

    Science.gov (United States)

    Lee, Hyo-Chang; Chung, Chin-Wook

    2015-10-20

    Hysteresis, which is the history dependence of physical systems, is one of the most important topics in physics. Interestingly, bi-stability of plasma with a huge hysteresis loop has been observed in inductive plasma discharges. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics.

  15. Course of organized structures in thermal plasma inside and outside argon plasma torch

    Science.gov (United States)

    Gruber, Jan; Sonsky, Jiri; Hlina, Jan

    2016-09-01

    Arc chamber of direct-current (dc) argon plasma torch and area just above the nozzle outside of this dc plasma torch were observed by hi-speed camera. System of reflecting mirrors and transparent silica arc chamber walls were used to obtain simultaneous records of both i) cathode area with electric arc inside the plasma torch and ii) nozzle exit with resulting plasma jet outside the plasma torch. Such experimental arrangement allowed us to track localized repeating patterns (organized structures) in the arc chamber and in the plasma flow. Identification of various organized structures - for different experimental conditions - according to their origin and typical development is presented in this paper. Impact of 300 Hz ripple in arc current was compared between different areas of the plasma. Additional simultaneous observation of plasma flow in the same system by series of photodiodes was used for verification of the results. The work was possible with institutional support RVO:61388998.

  16. Expanding Thermal Plasma Chemical Vapour Deposition of ZnO:Al Layers for CIGS Solar Cells

    Directory of Open Access Journals (Sweden)

    K. Sharma

    2014-01-01

    Full Text Available Aluminium-doped zinc oxide (ZnO:Al grown by expanding thermal plasma chemical vapour deposition (ETP-CVD has demonstrated excellent electrical and optical properties, which make it an attractive candidate as a transparent conductive oxide for photovoltaic applications. However, when depositing ZnO:Al on CIGS solar cell stacks, one should be aware that high substrate temperature processing (i.e., >200°C can damage the crucial underlying layers/interfaces (such as CIGS/CdS and CdS/i-ZnO. In this paper, the potential of adopting ETP-CVD ZnO:Al in CIGS solar cells is assessed: the effect of substrate temperature during film deposition on both the electrical properties of the ZnO:Al and the eventual performance of the CIGS solar cells was investigated. For ZnO:Al films grown using the high thermal budget (HTB condition, lower resistivities, ρ, were achievable (~5 × 10−4 Ω·cm than those grown using the low thermal budget (LTB conditions (~2 × 10−3 Ω·cm, whereas higher CIGS conversion efficiencies were obtained for the LTB condition (up to 10.9% than for the HTB condition (up to 9.0%. Whereas such temperature-dependence of CIGS device parameters has previously been linked with chemical migration between individual layers, we demonstrate that in this case it is primarily attributed to the prevalence of shunt currents.

  17. Thermal conductivities of nanostructured magnesium oxide coatings deposited on magnesium alloys by plasma electrolytic oxidation.

    Science.gov (United States)

    Shen, Xinwei; Nie, Xueyuan; Hu, Henry

    2014-10-01

    The resistances of magnesium alloys to wear, friction and corrosion can be effectively improved by depositing coatings on their surfaces. However, the coatings can also reduce the heat transfer from the coated components to the surroundings (e.g., coated cylinder bores for internal combustion of engine blocks). In this paper, nanostructured magnesium oxides were produced by plasma electrolytic oxidation (PEO) process on the magnesium alloy AJ62 under different current densities. The guarded comparative heat flow method was adopted to measure the thermal conductivities of such coatings which possess gradient nanoscale grain sizes. The aim of the paper is to explore how the current density in the PEO process affects the thermal conductivity of the nanostructured magnesium coatings. The experimental results show that, as the current density rises from 4 to 20 A/mm2, the thermal conductivity has a slight increase from 0.94 to 1.21 W/m x K, which is significantly smaller than that of the corresponding bulk magnesium oxide materials (29.4 W/m x K). This mostly attributed to the variation of the nanoscale grain sizes of the PEO coatings.

  18. Investigation on plasma-sprayed ZrO2 thermal barrier coating on nickel alloy substrate

    Institute of Scientific and Technical Information of China (English)

    卢安贤; 常鹰; 蔡小梅

    2002-01-01

    The thermal barrier coatings with NiCrAlY alloy bonding layer, NiCrAlY-Y2O3 stabilized ZrO2 transition layer and Y2O3 stabilized ZrO2 ceramic layer are prepared on nickel alloy substrates using the plasma spray technique. The relationship among the composition, structure and property of the coatings are investiga-ted by means of optical microscope, scanning electronic microscope and the experiments of thermal shock resistance cycling and high temperature oxidation resistance. The results show that the structure design of introdu-cing a transition layer between Ni alloy substrate and ZrO2 ceramic coating guarantees the high quality and properties of the coatings; ZrO2 coatings doped with a little SiO2 possesses better thermal shock resistance and more excellent hot corrosion resistance as compared with ZrO2 coating materials without SiO2 ;the improvement in performance of ZrO2 coating doped with SiO2 is due to forming more dense coating structure by self- closing effects of the flaws and pores in the ZrO2 coatings.

  19. Chlorobenzene degeradation by non-thermal plasma combined with EG-TiO{sub 2}/ZnO as a photocatalyst: Effect of photocatalyst on CO{sub 2} selectivity and byproducts reduction

    Energy Technology Data Exchange (ETDEWEB)

    Ghorbani Shahna, Farshid; Bahrami, Abdulrahman [Center of Excellence for Occupational Health and Research Center for Health Science, School of Public Health, Hamadan University of Medical Sciences, Hamadan (Iran, Islamic Republic of); Alimohammadi, Iraj; Yarahmadi, Rassuol [Department of Occupational Health, School of Public Health, Iran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Jaleh, Babak; Gandomi, Mastaneh [Faculty of Science, Physics Department, Bu-Ali Sina University, Hamedan (Iran, Islamic Republic of); Ebrahimi, Hossein, E-mail: hossein.ebrahimi@yahoo.com [Department of Occupational Health, School of Public Health, Iran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Ad-Din Abedi, Kamal [Department of Occupational Health Engineering, Faculty of Health, Kurdistan University of Medical sciences, Sanandaj (Iran, Islamic Republic of)

    2017-02-15

    Highlights: • TiO{sub 2} and ZnO Nano particles were coated on the surface of expanded graphite. • Expanded graphite-TiO{sub 2}/ZnO nano composite under UV light was placed downstream non-thermal plasma reactor. • Chlorobenzene removal and selectivity of CO{sub 2} were enhanced in combined system. • Produced harmful byproducts from plasma reactor were reduced dramatically in combined system. - Abstract: The non-thermal plasma (NTP) technique, which suffers from low selectivity in complete oxidation of volatile organic compounds to CO{sub 2} and H{sub 2}O, creates unwanted and harmful byproducts. NTP in concert with photocatalyst can resolve this limitation due to additional oxidation. TiO{sub 2} and ZnO nanoparticles were coated on the surface of the expanded graphite and placed downstream of the NTP reactor under UV light. In this study, to compare the performance of NTP and the combined system, chlorobenzene removal, selectivity of CO{sub 2} and byproducts formation were investigated. The results showed that the combined system enhanced both the removal efficiency and CO{sub 2} selectivity. The output gas of the NTP reactor contained chlorobenzene, phosgene, O{sub 3}, NO, NO{sub 2}, CO, CO{sub 2}, HCL and CL. The bulk of these byproducts was oxidized on the surface of the nanocomposite; as a result, the content of the byproducts in the output gas of the combined system decreased dramatically. The removal efficiency and CO{sub 2} selectivity increased by rising the applied voltage and residence time because the collision between active species and pollutant molecules increases. Based on these results, the combined system is preferred due to a higher performance and lower formation of harmful byproducts.

  20. Simultaneous Oxidization of NOx and 802 by a New Non-thermal Plasma Reactor Enhanced by Catalyst and Additive

    Institute of Scientific and Technical Information of China (English)

    Heejoon KIM; HAN Jun; Yuhei SAKAGUCHI; Wataru MINAMI

    2008-01-01

    The non-thermal plasma as one of the most promising technologies for removing NOx and SO2 has attracted much attention. In this study, a new plasma reactor combined with catalyst and additive was developed to effectively oxidize and remove NOx and SO2 in the flue gas. The experimental results showed that TiO2 could improve the oxidation efficiency of SO2 in the case of applying plasma while having a negative effect on the oxidation process of NO and NOx. With the addition of NH3, the oxidation rates of NOx, NO and SO2 were slightly increased. However, the effect of adding NH3 on NOx oxidation was negative when the temperature was above 200℃.

  1. Effective dose delivery in atmospheric pressure plasma jets for plasma medicine: a model predictive control approach

    Science.gov (United States)

    Gidon, Dogan; Graves, David B.; Mesbah, Ali

    2017-08-01

    Atmospheric pressure plasma jets (APPJs) have been identified as a promising tool for plasma medicine. This paper aims to demonstrate the importance of using model-based feedback control strategies for safe, reproducible, and therapeutically effective application of APPJs for dose delivery to a target substrate. Key challenges in model-based control of APPJs arise from: (i) the multivariable, nonlinear nature of system dynamics, (ii) the need for constraining the system operation within an operating region that ensures safe plasma treatment, and (iii) the cumulative, nondecreasing nature of dose metrics. To systematically address these challenges, we propose a model predictive control (MPC) strategy for real-time feedback control of a radio-frequency APPJ in argon. To this end, a lumped-parameter, physics-based model is developed for describing the jet dynamics. Cumulative dose metrics are defined for quantifying the thermal and nonthermal energy effects of the plasma on substrate. The closed-loop performance of the MPC strategy is compared to that of a basic proportional-integral control system. Simulation results indicate that the MPC stategy provides a versatile framework for dose delivery in the presence of disturbances, while the safety and practical constraints of the APPJ operation can be systematically handled. Model-based feedback control strategies can lead to unprecedented opportunities for effective dose delivery in plasma medicine.

  2. Studies of the influence of nonequilibrium plasma thermal exposure on the characteristics of the capillary-porous polymer material

    Science.gov (United States)

    Makhotkina, L. Yu; Khristoliubova, V. I.

    2017-01-01

    Capillary-porous materials, which include natural macromolecular tanning material, are exposed to a number of factors during the treatment by a nonequilibrium plasma. Plasma particles exchange the charge and energy with the atoms of the material during the interaction of the plasma with the surface. The results of treatment are desorption of atoms and molecules from the body surface, sputtering and evaporation of material’s particles, changes of the structure and phase state. In real terms during the modification of solids by nonequilibrium low-temperature plasma thermal effect influences the process. The energy supplied from the discharge during the process with low pressure, which is converted into heat, is significantly less than during the atmospheric pressure, but the thermal stability of high-molecular compounds used in the manufacture of materials and products of the tanning industry, is very limited and depends on the duration of the effect of temperature. Even short heating of hydrophilic polymers (proteins) (100-180 °C) causes a change in their properties. It decreases the collagen ability to absorb water vapor, to swell in water, acids, alkalis, and thus decreases their durability. Prolonged heating leads to a deterioration of the physical and mechanical properties. Higher heating temperatures it leads to the polymer degradation. The natural leather temperature during plasma exposure does not rise to a temperature of collagen degradation and does not result in changes of physical phase of the dermis. However, the thermal plasma exposure must be considered, since the high temperatures influence on physical and mechanical properties.

  3. Berry curvature and various thermal Hall effects

    Science.gov (United States)

    Zhang, Lifa

    2016-10-01

    Applying the approach of semiclassical wave packet dynamics, we study various thermal Hall effects where carriers can be electron, phonon, magnon, etc. A general formula of thermal Hall conductivity is obtained to provide an essential physics for various thermal Hall effects, where the Berry phase effect manifests naturally. All the formulas of electron thermal Hall effect, phonon Hall effect, and magnon Hall effect can be directly reproduced from the general formula. It is also found that the Strěda formula can not be directly applied to the thermal Hall effects, where only the edge magnetization contributes to the Hall effects. Furthermore, we obtain a combined formula for anomalous Hall conductivity, thermal Hall electronic conductivity and thermal Hall conductivity for electron systems, where the Berry curvature is weighted by a different function. Finally, we discuss particle magnetization and its relation to angular momentum of the carrier, change of which could induce a mechanical rotation; and possible experiments for thermal Hall effect associated with a mechanical rotation are also proposed.

  4. Vitrification of MSWI Fly Ash by Thermal Plasma Melting and Fate of Heavy Metals

    Institute of Scientific and Technical Information of China (English)

    倪国华; 赵鹏; 江贻满; 孟月东

    2012-01-01

    Municipal solid waste incinerator (MSWI) fly ash with high basicity (about 1.68) was vitrified in a thermal plasma melting furnace system. Through the thermal plasma treatment, the vitrified product (slag) with amorphous dark glassy structure was obtained, and the leachability of hazardous metals in slag was significantly reduced. Meanwhile, it was found that the cooling rate affects significantly the immobility of heavy metals in slag. The mass distribution of heavy metals (Zn, Cd, Cr, Pb, As, Hg) was investigated in residual products (slag, secondary residues and flue gas), in order to analyze the behavior of heavy metals in thermal plasma atmosphere. Heavy metal species with low boiling points accounting for the major fraction of their input-mass were adsorbed in secondary residues by pollution abatement devices, while those with high boiling points tended to be encapsulated in slag.

  5. Evaluation of Surface Cleaning Procedures in Terms of Gas Sensing Properties of Spray-Deposited CNT Film: Thermal- and O2 Plasma Treatments

    Directory of Open Access Journals (Sweden)

    Joon Hyub Kim

    2016-12-01

    Full Text Available The effect of cleaning the surface of single-walled carbon nanotube (SWNT networks by thermal and the O2 plasma treatments is presented in terms of NH3 gas sensing characteristics. The goal of this work is to determine the relationship between the physicochemical properties of the cleaned surface (including the chemical composition, crystal structure, hydrophilicity, and impurity content and the sensitivity of the SWNT network films to NH3 gas. The SWNT networks are spray-deposited on pre-patterned Pt electrodes, and are further functionalized by heating on a programmable hot plate or by O2 plasma treatment in a laboratory-prepared plasma chamber. Cyclic voltammetry was employed to semi-quantitatively evaluate each surface state of various plasma-treated SWNT-based electrodes. The results show that O2 plasma treatment can more effectively modify the SWNT network surface than thermal cleaning, and can provide a better conductive network surface due to the larger number of carbonyl/carboxyl groups, enabling a faster electron transfer rate, even though both the thermal cleaning and the O2 plasma cleaning methods can eliminate the organic solvent residues from the network surface. The NH3 sensors based on the O2 plasma-treated SWNT network exhibit higher sensitivity, shorter response time, and better recovery of the initial resistance than those prepared employing the thermally-cleaned SWNT networks.

  6. The degradation of oxadiazon by non-thermal plasma with a dielectric barrier configuration

    Science.gov (United States)

    Ying, ZHAO; Risheng, YAO; Yuedong, MENG; Jiaxing, LI; Yiman, JIANG; Longwei, CHEN

    2017-03-01

    To explore the feasibility of a degradation approach by non-thermal plasma and the corresponding degradation pathways, studies on the oxadiazon removal in synthetic wastewater by a dielectric barrier discharge plasma reactor were investigated. The loss of the nitro group, dechlorination and ring cleavage is mainly involved in the non-thermal plasma degradation pathways of oxadiazon in a solution based on the OES and LC-MS analysis. Detection of EC25 and the production of the chlorine ion and nitrate ion further demonstrate the feasibility and validity of the approach. The conditions with a proper applied voltage, solution flow rate, oxygen flow rate, and solution pH contribute to the plasma degradation processes with a degradation ratio of over 94%.

  7. The role of thermal energy accommodation and atomic recombination probabilities in low pressure oxygen plasmas

    Science.gov (United States)

    Gibson, Andrew Robert; Foucher, Mickaël; Marinov, Daniil; Chabert, Pascal; Gans, Timo; Kushner, Mark J.; Booth, Jean-Paul

    2017-02-01

    Surface interaction probabilities are critical parameters that determine the behaviour of low pressure plasmas and so are crucial input parameters for plasma simulations that play a key role in determining their accuracy. However, these parameters are difficult to estimate without in situ measurements. In this work, the role of two prominent surface interaction probabilities, the atomic oxygen recombination coefficient γ O and the thermal energy accommodation coefficient α E in determining the plasma properties of low pressure inductively coupled oxygen plasmas are investigated using two-dimensional fluid-kinetic simulations. These plasmas are the type used for semiconductor processing. It was found that α E plays a crucial role in determining the neutral gas temperature and neutral gas density. Through this dependency, the value of α E also determines a range of other plasma properties such as the atomic oxygen density, the plasma potential, the electron temperature, and ion bombardment energy and neutral-to-ion flux ratio at the wafer holder. The main role of γ O is in determining the atomic oxygen density and flux to the wafer holder along with the neutral-to-ion flux ratio. It was found that the plasma properties are most sensitive to each coefficient when the value of the coefficient is small causing the losses of atomic oxygen and thermal energy to be surface interaction limited rather than transport limited.

  8. Turbulent chromo-fields and thermal particle production in quark-gluon plasma medium

    CERN Document Server

    Chandra, Vinod

    2016-01-01

    The Weibel type instabilities appear in the expanding quark-gluon plasma (QGP) in relativistic heavy-ion collisions, due to the presence of momentum-space anisotropy, are responsible for the generation of the turbulent color fields. The ensemble averaged (ensemble of the turbulent fields) effective diffusive Vlasov equation, for the modified momentum distribution functions of the quarks and gluons encodes the physics of such instability and leads to the anomalous transport process in the QGP medium. In the present case, the solution of the linearized transport equation for the modified momentum distribution functions has been served as the modeling for the non-equilibrium momentum distribution functions for the QGP degrees of freedom. The strength of anisotropy has been related to a phenomenologically obtained jet-quenching parameter, $\\hat{q}$. We have computed the contribution of these anisotropic terms to the thermal dilepton production rates. The production rate has been seen to be appreciably sensitive t...

  9. Thermodynamic properties and transport coefficients of two-temperature helium thermal plasmas

    Science.gov (United States)

    Guo, Xiaoxue; Murphy, Anthony B.; Li, Xingwen

    2017-03-01

    Helium thermal plasmas are in widespread use in arc welding and many other industrial applications. Simulation of these processes relies on accurate plasma property data, such as plasma composition, thermodynamic properties and transport coefficients. Departures from LTE (local thermodynamic equilibrium) generally occur in some regions of helium plasmas. In this paper, properties are calculated allowing for different values of the electron temperature, T e, and heavy-species temperature, T h, at atmospheric pressure from 300 K to 30 000 K. The plasma composition is first calculated using the mass action law, and the two-temperature thermodynamic properties are then derived. The viscosity, diffusion coefficients, electrical conductivity and thermal conductivity of the two-temperature helium thermal plasma are obtained using a recently-developed method that retains coupling between electrons and heavy species by including the electron–heavy-species collision term in the heavy-species Boltzmann equation. It is shown that the viscosity and the diffusion coefficients strongly depend on non-equilibrium ratio θ (θ ={{T}\\text{e}}/{{T}\\text{h}} ), through the plasma composition and the collision integrals. The electrical conductivity, which depends on the electron number density and ordinary diffusion coefficients, and the thermal conductivity have similar dependencies. The choice of definition of the Debye length is shown to affect the electrical conductivity significantly for θ  >  1. By comparing with literature data, it is shown that the coupling between electrons and heavy species has a significant influence on the electrical conductivity, but not on the viscosity. Plasma properties are tabulated in the supplementary data.

  10. Effective Thermal Conductivity of Corrugated Insulating Materials

    Science.gov (United States)

    Yamada, Etsuro; Kato, Masayasu; Tomikawa, Takayuki; Takahashi, Kaneko

    The effective thermal conductivity of corrugated insulating materials which are made by polypropylene or polycarbonate have been measured by employing steady state comparison method for several specimen having various thickness and specific weight. The thermal conductivity of them evaluated are also by using the thermal resistance models, and are compared with above measured values and raw materials' conductivity. The main results obtained in this paper are as follows: (1) In regard to the specimen in this paper, the effective thermal conductivity increases with increasing temperature, but the increasing rate of them is small. (2) There are considerable differences between the measured values and the predicted ones that are estimated by using the thermal resistance model in which heat flow by conduction only. This differences increase with increasing specimens' thickness. This difference become extinct by considering the coexistence heat flow of conduction and radiation in the air phase of specimen. (3) The thermal resistance of specimen increases linearly with increasing specimens' thickness.

  11. Thermal shock behaviour of tungsten after high flux H-plasma loading

    Science.gov (United States)

    Wirtz, M.; Linke, J.; Pintsuk, G.; De Temmerman, G.; Wright, G. M.

    2013-11-01

    Previous studies have shown that transient thermal shock loads induce crack networks on tungsten samples especially at low base temperatures. To achieve test conditions which are more relevant for the performance of tungsten-armoured plasma facing components in next step thermonuclear fusion devices tungsten tiles were exposed to high flux hydrogen-plasma in the linear plasma generator Pilot-PSI and the high heat flux ion beam test facility MARION. Subsequently, the cyclic transient heat load tests were done in the electron beam facility JUDITH 1. The induced damages after these combined tests were examined by microscopically means, profilometry and metallography. The comparison of the obtained results and damage characteristics with those obtained after thermal shock loading show that the preloading of tungsten targets with high flux hydrogen-plasma has significant influence on the thermal shock behaviour of tungsten in terms of crack distance, width, and depth as well as cracked area. Furthermore the plasma parameters, in particular pulse duration and sample temperature during loading, have strong impact on the damage pattern after thermal shock loading.

  12. The relationship between the microstructure and thermal diffusivity of plasma-sprayed tungsten coatings

    Energy Technology Data Exchange (ETDEWEB)

    Moreau, C. [National Research Council Canada, Boucherville, Quebec (Canada); Boire-Lavigne, S.; Saint-Jacques, R.G. [INRS-Energie et Materiaux, Varennes, Quebec (Canada)

    1994-12-31

    Tungsten and tungsten alloy coatings are candidate materials for plasma facing components of divertor plates in future fusion reactors. In normal operation, the sprayed coatings will be submitted to intense heat fluxes and particle bombardment. This work intends to investigate the relationship between the microstructure of plasma-sprayed tungsten coatings and their thermal diffusivity as determined by the laser flash method. The microstructural investigation was carried out on copper-infiltrated coatings. Such a preparation technique permitted the measurement of the total real contact area between the lamellae within the tungsten coatings. The spraying atmosphere was found to strongly influence the interfacial contact between lamellae and coating thermal diffusivity.

  13. Synthesis of Fullerene by Pyrolysis of Acetylene in Thermal HF-Plasma

    Institute of Scientific and Technical Information of China (English)

    ZHU Yanjuan; ZHANG Guofu; ZHANG Wei; LIN Tianjin; XIE Hongbo; LIU Qiuxiang; ZHANG Haiyan

    2007-01-01

    Carbon soot containing fullerene was continuously produced in volume by pyrolyzing acetylene in thermal HF-Plasma. The characteristics of the carbon soot and C60 were analyzed by thtransmission electron microscopy, UV/visible, IR and Raman spectroscopy. The results show that the main ingredients of the carbon soot with size of about 25 nm are amorphous carbon, graphite and fullerene. The fullerene yield in carbon soot is about 2.5 g·h-1. Compared with the graphite arc discharge method, the acetylene thermal plasma method is a preferential one for synthesis of fullerene.

  14. Non-Thermal Equilibrium Atmospheric Pressure Glow-Like Discharge Plasma Jet

    Science.gov (United States)

    Chang, Zhengshi; Yao, Congwei; Zhang, Guanjun

    2016-01-01

    Non-thermal equilibrium atmospheric pressure plasma jet (APPJ) is a cold plasma source that promises various innovative applications, and the uniform APPJ is more favored. Glow discharge is one of the most effective methods to obtain the uniform discharge. Compared with the glow dielectric barrier discharge (DBD) in atmospheric pressure, pure helium APPJ shows partial characteristics of both the glow discharge and the streamer. In this paper, considering the influence of the Penning effect, the electrical and optical properties of He APPJ and Ar/NH3 APPJ were researched. A word “Glow-like APPJ” is used to characterize the uniformity of APPJ, and it was obtained that the basic characteristics of the glow-like APPJ are driven by the kHz AC high voltage. The results can provide a support for generating uniform APPJ, and lay a foundation for its applications. supported by National Natural Science Foundation of China (Nos. 51307133, 51125029, 51221005) and the Fundamental Research Funds for the Central Universities of China (Nos. xjj2012132, xkjc2013004)

  15. Physics of Nonmagnetic Relativistic Thermal Plasmas. Ph.D. Thesis - Calif. Univ., San Diego

    Science.gov (United States)

    Dermer, C. D.

    1984-01-01

    A detailed treatment of the kinematics of relativistic systems of particles and photons is presented. In the case of a relativistic Maxwell-Boltzmann distribution of particles, the reaction rate and luminosity are written as single integrals over the invariant cross section, and the production spectrum is written as a double integral over the cross section differential in the energy of the produced particles (or photons) in the center-of-momentum system of two colliding particles. The results are applied to the calculation of the annihilation spectrum of a thermal electron-positron plasma, confirming previous numerical and analytic results. Relativistic thermal electron-ion and electron-electron bremsstrahlung are calculated exactly to lowest order, and relativistic thermal electron-positron bremsstrahlung is calculated in an approximate fashion. An approximate treatment of relativistic Comptonization is developed. The question of thermalization of a relativistic plasma is considered. A formula for the energy loss or exchange rate from the interaction of two relativistic Maxwell-Boltzmann plasmas at different temperatures is derived. Application to a stable, uniform, nonmagnetic relativistic thermal plasma is made. Comparison is made with other studies.

  16. Effective Thermal Conductivity of Adsorbent Packed Beds

    Science.gov (United States)

    Mori, Hideo; Hamamoto, Yoshinori; Yoshida, Suguru

    The effective thermal conductivity of adsorbent packed beds of granular zeolite 13X and granular silica gel A in the presence of stagnant steam or air was measured under different conditions of the adsorbent bed temperature, particle size and filler-gas pressure. The measured effective thermal conductivity showed to become smaller with decreasing particle size or decreasing pressure, but it was nearly independent of the bed temperature. When steam was the filler-gas, the rise in the thermal conductivity of the adsorbent particles due to steam adsorption led to the increase in the effective thermal conductivity of the bed, and this effect was not negligible at high steam pressure for the bed of large particle size. It was found that both the predictions of the effective thermal conductivity by the Hayashi et al.'s model and the Bauer-Schlünder model generally agreed well with the measurements, by considering the particle thermal conductivity rise due to steam adsorption. The thermal conductivity of a consolidated bed of granular zeolite 13X was also measured, and it was found to be much larger than that of the packed bed especially at lower pressure. The above prediction models underestimated the effective thermal conductivity of the consolidated bed.

  17. Preparation of Al-SiC{sub p} composite coating by plasma thermal spray

    Energy Technology Data Exchange (ETDEWEB)

    Min, J.W. [Chungnam National University, Taejeon (Korea); Yoo, S.E. [Korea Automotive Technology Institute, Chonan (Korea); Kim, Y.J. [Sunmoon University, Asan (Korea); Kim, J.S.; Suhr, D.S. [Chungnam National University, Taejeon (Korea)

    2003-03-01

    Al-SiC{sub p} composite layer was prepared by plasma thermal spray on aluminum substrate using composite powder prepared by mechanical alloying. Mechanically alloyed powder was achieved after 24 h milling, which was used for thermal spray coating. The correlations between process conditions and thickness/porosity were analyzed, and increase of hardness was confirmed. The presence of Al-Si-C-O compound was detected by TEM analysis. (author). 16 refs., 6 tabs., 11 figs.

  18. Electrostatic envelope modes in multi-component non-thermal plasmas

    Science.gov (United States)

    Saiful Islam, Md; Sultana, Sharmin; Mamun, A. A.

    2016-07-01

    A theoretical study of envelope type solitary structures and their modulational instability has been made in a multi-component unmagnetized non-thermal plasma (consisting of negatively charged immobile heavy ions, inertial light ions and non-thermal electrons of two distinct temperatures). The cubic nonlinear Schrödinger equation (which describes the evolution of a slowly varying wave envelope with space and time) is derived by adopting the multiple scale (in space and time) perturbation technique. It is found that the plasma system under consideration supports two types (bright and dark) envelope solitons. It is also seen that the dark (bright) envelope solitons are modulationally stable (unstable). The variation of the growth rate of the unstable bright envelope solitons with various plasma parameters (e.g. wave number, temperature of plasma non-thermality, etc.) are found to be significant. The modulational instability criterions of the envelope modes are also seen to be influenced due to the variation of the intrinsic plasma parameters. This theoretical study may be useful in understanding the basic features of localized electrostatic structures in some space plasma systems (viz. Saturn's magnetosphere) where high energetic particles are available.

  19. Microstructural Evolution and Residual Stresses of Air-Plasma Sprayed Thermal Barrier Coatings Under Thermal Exposure

    Science.gov (United States)

    Kwon, Jae-Young; Kim, Jae-Hyoun; Lee, Sang-Yeop; Jung, Yeon-Gil; Cho, Hyun; Yi, Dong-Kee; Paik, Ungyu

    Microstructural evolution and fracture behavior of zirconia (ZrO2)-based thermal barrier coatings (TBCs) were investigated under thermal exposure. New ZrO2 granule with 8 wt.% yttria (Y2O3) with a deformed hollow morphology was developed through a spray drying process and employed to prepare TBCs. The thermal exposure tests were conducted at 1210°C with a dwell time of 100 h till 800 h. The residual stress at the interface between top coat and thermally grown oxide (TGO) layer was measured using a nanoindentation technique before and after thermal exposure. Vertical cracks on the top coat were newly formed and interlamellar cracks at the interface were enhanced after the thermal exposure of 800 h. Especially, partial delamination was observed at the interface after the thermal exposure of 800 h in TBC samples tested. The microstructural evolution in the top coat could be defined through load-displacement curves, showing a higher load or a less displacement after the thermal exposure of 800 h. The stress state was strongly dependent on the TGO geometry, resulting in the compressive stresses at the "valleys" or the "troughs," and the tensile stresses at the "crests" or peak areas, in the ranges of -500 to -75 MPa and of +168 to + 24 MPa, respectively. These stress terms incorporated with resintering during thermal exposure affected the mechanical properties such as hardness and elastic modulus of the top coat.

  20. Effects on plasma glucose and lactate.

    Science.gov (United States)

    Young, Andrew

    2005-01-01

    Injection of amylin or amylin agonists, including human and rat amylin, pramlintide, salmon calcitonin, and calcitonin gene-related peptide (CGRP), increases the plasma levels of lactate and glucose in non-diabetic fasting rats and mice. This response can be useful in identifying and defining amylin agonists (amylinomimetic agents) (Cooper et al.) and has been investigated in several studies. Increases in plasma glucose and lactate are not present in all species. In humans, for example, increases in lactate are observed at high pramlintide doses but not at doses that would be used to therapeutically regulate plasma glucose. In species where it occurs, the increase in plasma lactate with amylin is comparable to that observed with exercise or adrenergic agents, and it is distinguishable from the very high levels observed during lactic acidosis (as may occur with biguanides). In contrast to lactic acidosis, the plasma lactate with amylin is derived from skeletal muscle rather than liver. Increases in plasma lactate and glucose in some species may initially appear inconsistent with a glucose-lowering effect of amylin agonists. But glycemic effects are due to actions in skeletal muscle and are present only in some species, whereas glucose-lowering actions are attributable to effects in gastrointestinal systems and are present in all species studied to date. And while glycemic effects are most pronounced in the fasted state, glucose-lowering effects are most pronounced in the postprandial state. Since they were discovered first, effects of higher doses of amylin on plasma glucose, especially in the fasted state, are described first and are related to concomitant changes in plasma lactate. These effects are prominent in rodents but are barely discernible in humans. Effects of lower doses of pramlintide to suppress plasma glucose profiles in the postprandial period are also observable in normal and diabetic rats, however, and are covered here as well. The relationship

  1. Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling

    Science.gov (United States)

    DeVisscher, A.; Dewulf, J.; Van Durme, J.; Leys, C.; Morent, R.; Van Langenhove, H.

    2008-02-01

    Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

  2. Effect of Electron Energy Distribution on the Hysteresis of Plasma Discharge: Theory, Experiment, and Modeling

    Science.gov (United States)

    Lee, Hyo-Chang; Chung, Chin-Wook

    2016-09-01

    Hysteresis, which is the history dependence of physical systems, indicates that there are more-than-two stable points in a given condition, and it has been considered to one of the most important topics in fundamental physics. Recently, the hysteresis of plasma has become a focus of research because stable plasma operation is very important for fusion reactors, bio-medical plasmas, and industrial plasmas for nano-device fabrication process. Interestingly, the bi-stability characteristics of plasma with a huge hysteresis loop have been observed in inductive discharge plasmas Because hysteresis study in such plasmas can provide a universal understanding of plasma physics, many researchers have attempted experimental and theoretical studies. Despite long plasma research, how this plasma hysteresis occurs remains an unresolved question in plasma physics. Here, we report theory, experiment, and modeling of the hysteresis. It was found experimentally and theoretically that evolution of the electron energy distribution (EED) makes a strong plasma hysteresis. In Ramsauer and non-Ramsauer gas experiments, it was revealed that the plasma hysteresis is observed only at high pressure Ramsauer gas where the EED deviates considerably from a Maxwellian shape. This hysteresis was presented in the plasma balance model where the EED is considered. Because electrons in plasmas are usually not in a thermal equilibrium, this EED-effect can be regarded as a universal phenomenon in plasma physics. This research was partially supported by Korea Research Institute of Standard and Science.

  3. Thermal effects in supernova matter

    Science.gov (United States)

    Constantinou, Constantinos

    intermediate energy heavy-ion collisions. To explore the effect momentum-dependent interactions have on the thermal properties of dense matter we study a schematic model constructed by Welke et al. in which the appropriate momentum dependence that fits optical potential data is built through finite-range exchange forces of the Yukawa type. We look into the finite-temperature properties of this model in the context of infinite, isospin-symmetric nucleonic matter. The exact numerical results are compared to analytical ones in the quantum regime where we rely on Landau's Fermi-Liquid Theory, and in the classical regime where the state variables are obtained through a steepest descent calculation. Detailed comparisons with similarly calibrated Skyrme models are also performed. We find that the high-density behavior of the thermal pressure is once again a differentiating feature. We attribute this to the temperature dependence of the energy spectrum of the finite-range and the meson-exchange models which leads to a higher specific heat and thus a lower pressure.

  4. Thermal effects and component cooling in Magnum-PSI

    Energy Technology Data Exchange (ETDEWEB)

    Kruijt, O.G., E-mail: kruijt@rijnhuizen.nl [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster (Netherlands); Scholten, J.; Smeets, P.H.M.; Brons, S.; Eck, H.J.N. van; Al, R.S.; Berg, M.A. van den; Meiden, H.J. van der; Rooij, G.J. van; Zelijlmans van Emmichoven, P.A. [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster (Netherlands)

    2011-10-15

    Magnum-PSI is a linear plasma generator, built at the FOM-Institute for Plasma Physics Rijnhuizen. Subject of study will be the interaction of plasma with a diversity of surface materials. The machine is designed to provide an environment with a steady state high-flux plasma (up to 10{sup 24} H{sup +} ions/m{sup 2} s) in a 3 T magnetic field with an exposed surface of 80 cm{sup 2} up to 10 MW/m{sup 2}. Magnum-PSI will provide new insights in the complex physics and chemistry that will occur in the divertor region of the future experimental fusion reactor ITER and reactors beyond ITER. The conditions at the surface of the sample can be varied over a wide range, such as plasma temperature, beam diameter, particle flux, inclination angle of the target, background pressure and magnetic field. An important subject of attention in the design of the machine was thermal effects originating in the excess heat and gas flow from the plasma source and radiation from the target.

  5. Shock wave interaction with a thermal layer produced by a plasma sheet actuator

    Science.gov (United States)

    Koroteeva, E.; Znamenskaya, I.; Orlov, D.; Sysoev, N.

    2017-03-01

    This paper explores the phenomena associated with pulsed discharge energy deposition in the near-surface gas layer in front of a shock wave from the flow control perspective. The energy is deposited in 200 ns by a high-current distributed sliding discharge of a ‘plasma sheet’ type. The discharge, covering an area of 100× 30 mm2, is mounted on the top or bottom wall of a shock tube channel. In order to analyse the time scales of the pulsed discharge effect on an unsteady supersonic flow, we consider the propagation of a planar shock wave along the discharge surface area 50–500 μs after the discharge pulse. The processes in the discharge chamber are visualized experimentally using the shadowgraph method and modelled numerically using 2D/3D CFD simulations. The interaction between the planar shock wave and the discharge-induced thermal layer results in the formation of a lambda-shock configuration and the generation of vorticity in the flow behind the shock front. We determine the amount and spatial distribution of the electric energy rapidly transforming into heat by comparing the calculated flow patterns and the experimental shadow images. It is shown that the uniformity of the discharge energy distribution strongly affects the resulting flow dynamics. Regions of turbulent mixing in the near-surface gas are detected when the discharge energy is deposited non-uniformly along the plasma sheet. They account for the increase in the cooling rate of the discharge-induced thermal layer and significantly influence its interaction with an incident shock wave.

  6. Thermoelectric and Thermomagnetic Effects in Dilute Plasmas

    CERN Document Server

    García-Colin, L S; Sandoval-Villalbazo, A

    2006-01-01

    When an electrically charged system is subjected to the action of an electromagnetic field, it responds by generating an electrical current. In the case of a multicomponent plasma other effects, the so called cross effects, influence the flow of charge as well as the heat flow. In this paper we discuss these effects and their corresponding transport coefficients in a fully ionized plasma using Boltzmann's equation. Applications to non-confined plasmas, specially to those prevailing in astrophysical systems are highlighted. Also, a detailed comparison is given with other available results.

  7. Synthesis and characterization of Nd2O3 nanoparticles in a radiofrequency thermal plasma reactor

    Science.gov (United States)

    Dhamale, G. D.; Mathe, V. L.; Bhoraskar, S. V.; Sahasrabudhe, S. N.; Dhole, S. D.; Ghorui, S.

    2016-02-01

    The synthesis of nanocrystalline Nd2O3 through an inductively coupled radiofrequency thermal plasma route is reported. Unlike in conventional synthesis processes, plasma-synthesized nanoparticles are directly obtained in a stable hexagonal crystal structure with a faceted morphology. The synthesized nanoparticles are highly uniform with an average size around 20 nm. The nanoparticles are characterized in terms of phase formation, crystallinity, morphology, size distribution, nature of chemical bonds and post-synthesis environmental effects using standard characterization techniques. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy are used for structural and morphological studies. The thermo-gravimetric technique, using a differential scanning calorimeter, is used to investigate the purity of phase. Fourier transform infrared spectroscopy is used to investigate the nature of existing bonds. The optical response of the nanoparticles is investigated through the electronic transition of Nd3+ ions in its crystalline structure via UV-visible spectroscopy. The presence of defect states and corresponding activation energies in the nanocrystalline Nd2O3 compared to those of the precursors are studied using thermoluminescence.

  8. Coal-derived carbon nanotubes by thermal plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Y.; Zhang, Y.L.; Wang, B.J.; Ji, W.J.; Zhang, Y.F.; Xie, K.C. [Nanjing University, Nanjing (China). Dept. of Physics

    2004-07-01

    A coal/arc-jet technique by directly and successively injecting coal fine particles into the arc plasma jet instead of arcing graphite or coal-based electrodes for producing carbon nanotubes (CNTs) from coal was developed. The derived carbon products by this technique were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), high-resolution TEM (HRTEM), X-ray energy dispersive spectrum (EDS), X-ray diffraction (XRD) and Raman spectrum. The experimental results clearly indicated that certain metal catalysts favored the growth of CNTs in the process, and the relevant growth mechanism was discussed in terms of the characterizations.

  9. Preparation of Ultra-fine Aluminum Nitride in Thermal Plasma

    Institute of Scientific and Technical Information of China (English)

    漆继红; 罗义文; 印永祥; 代晓雁

    2002-01-01

    Ultra-fine aluminum nitride has been synthesized by the evaporation of aluminum powder at atmospheric-pressure nitrogen plasma in a hot-wall reactor. The average size of aluminum nitride particle is 0.11μm measured by scanning electric mirror (SEM), and the purity is at least over 90% evaluated by X-Ray diffraction (XRD). The conversion of Al powder to aluminum nitride is strongly depended on the injection of NH3. Typical experimental parameters such as the feed rate of raw material, the flow rate of ammonia and the position of injecting aluminum powder into the reactor are given.

  10. Utilization of thermal effects for silicon photonics

    Science.gov (United States)

    Dai, Daoxin; Yu, Longhai; Chen, Sitao; Wu, Hao

    2015-08-01

    Thermal effect plays a key role and has been utilized for various photonic devices. For silicon photonics, the thermal effect is usually important because of the large thermo-optical coefficient of silicon material. This paper gives a review for the utilization of thermal effects for silicon photonics. First, the thermal effect is very beneficial to realize energy-efficient silicon photonic devices with tunability/switchability (including switches, variable optical attenuators, etc). Traditionally metal micro-heater sitting on a buried silicon-on-insulator (SOI) nanowire is used to introduce a phase shift for thermal tunability by injecting a electrical current. An effective way to improve the energy-efficiency of thermal tuning is reducing the volume of the optical waveguide as well as the micro-heater. Our recent work on silicon nanophotonic waveguides with novel nano-heaters based on metal wires as well as graphene ribbons will be summarized. Second, the thermal resistance effect of the metal strip on a hybrid plasmonic waveguide structure can be utilized to realize an ultra-small on-chip photodetector available for an ultra-broad band of wavelength, which will also be discussed.

  11. Effect of current-voltage characteristics on plasma reforming

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, N. [Univ. of Science and Technology, Daejeon (Korea, Republic of). Environmental System Engineering; Korea Inst. of Machinery and Materials, Daejeon (Korea, Republic of). Environmental System Research Division; Hur, M.; Kim, K.T.; Kim, S.J.; Song, Y.H. [Korea Inst. of Machinery and Materials, Daejeon (Korea, Republic of). Environmental System Research Division

    2010-07-01

    Studies have shown that the energy costs associated with plasma fuel reforming can vary depending on the type of plasma generation technique. The reasons for the different energy costs, however, are not yet clear, since different types of plasma reactor lead to not only different plasma conditions but also lead to different reaction conditions that is not relevant to plasma, such as gas residence time, heat and mass flow conditions. This paper presented the results of a parametric study on methane partial oxidation which was conducted to determine the optimal operating conditions and geometrical design of an arc jet plasma fuel reformer. The arc reactor used in this study was designed to control various operating parameters such as arc length, gas residence time, and gas mixing. Two different types of power supply were tested, notably one that produced high voltage with low current, and one that produced relatively low voltage and high current. The effects of these different voltage-current characteristics on gas reforming process were analyzed based on methane conversion rates, selectivity of products, and thermal efficiencies. The study showed that the input power but not the voltage plays an important role in the present partial oxidation process. The gas residence time was also found to be an important factor in controlling the reformer process. 10 refs., 8 figs.

  12. Characterization of Microstructure and Thermal Properties of YSZ Coatings Obtained by Axial Suspension Plasma Spraying (ASPS)

    Science.gov (United States)

    Ganvir, Ashish; Curry, Nicholas; Björklund, Stefan; Markocsan, Nicolaie; Nylén, Per

    2015-10-01

    The paper aims at demonstrating various microstructures which can be obtained using the suspension spraying technique and their respective significance in enhancing the thermal insulation property of a thermal barrier coating. Three different types of coating microstructures are discussed which were produced by the Axial Suspension Plasma Spraying. Detailed characterization of coatings was then performed. Optical and scanning electron microscopy were utilized for microstructure evaluations; x-ray diffraction for phase analysis; water impregnation, image analysis, and mercury intrusion porosimetry for porosity analysis, and laser flash analysis for thermal diffusivity measurements were used. The results showed that Axial Suspension Plasma Spraying can generate vertically cracked, porous, and feathery columnar-type microstructures. Pore size distribution was found in micron, submicron, and nanometer range. Higher overall porosity, the lower density of vertical cracks or inter-column spacing, and higher inter-pass porosity favored thermal insulation property of the coating. Significant increase in thermal diffusivity and conductivity was found at higher temperature, which is believed to be due to the pore rearrangement (sintering and pore coarsening). Thermal conductivity values for these coatings were also compared with electron beam physical vapor deposition (EBPVD) thermal barrier coatings from the literature and found to be much lower.

  13. Thermal Insulation and Thermal Shock Behavior of Conventional and Nanostructured Plasma-Sprayed TBCs

    Science.gov (United States)

    Tamaddon Masoule, S.; Valefi, Z.; Ehsani, N.; Qazi Lavasani, H.

    2016-12-01

    This study investigated the thermal insulation and thermal shock resistance behavior of nanostructured versus conventional yttria-stabilized zirconia (YSZ) thermal barrier coatings. To evaluate their coating performance in service conditions, samples were furnace sintered at 1150 °C for 100 h in ambient atmosphere. The results show that the nanostructured coatings exhibited better heat transfer resistance and thermal shock resistance compared with the conventional coating. In addition, the larger size of the initial agglomerates in the nanostructured coatings increased the percentage area of nanozones and decreased the heat transfer resistance. The thermal insulation behavior of the conventional coating was improved after heat treatment because of horizontal cracking. Disappearance of cracks, bridging between grains, and their growth by connecting with each other were observed in the conventional coating. However, in the nanostructured coatings, the nanoareas and their related properties disappeared. Microstructural and phase investigations were carried out by optical microscopy, field-emission scanning electron microscopy (FE-SEM), and x-ray diffraction (XRD) analysis. The thermal behavior was investigated by thermal insulation capability testing.

  14. Expanding thermal plasma chemical vapour deposition of ZnO:Al layers for CIGS solar cells

    NARCIS (Netherlands)

    Sharma, K.; Williams, B.L.; Mittal, A.; Knoops, H.C.M.; Kniknie, B.J.; Bakker, N.J.; Kessels, W.M.M.; Schropp, R.E.I.; Creatore, M.

    2014-01-01

    Aluminium-doped zinc oxide (ZnO:Al) grown by expanding thermal plasma chemical vapour deposition (ETP-CVD) has demonstrated excellent electrical and optical properties, which make it an attractive candidate as a transparent conductive oxide for photovoltaic applications. However, when depositing ZnO

  15. Efficient computation of electron-electron bremsstrahlung emission in a hot thermal plasma

    Science.gov (United States)

    Haug, E.

    1989-07-01

    A formula for the cross section of electron-electron bremsstrahlung (EEB) in the center-of-mass system is used to calculate the spectrum of EEB in a hot thermal plasma as well as the total rate of energy loss due to EEB with a minimum amount of computing time.

  16. Expanding thermal plasma chemical vapour deposition of ZnO:Al layers for CIGS solar cells

    NARCIS (Netherlands)

    Sharma, K.; Williams, B.L.; Mittal, A.; Knoops, H.C.M.; Kniknie, B.J.; Bakker, N.J.; Kessels, W.M.M.; Schropp, R.E.I.; Creatore, M.

    2014-01-01

    Aluminium-doped zinc oxide (ZnO:Al) grown by expanding thermal plasma chemical vapour deposition (ETP-CVD) has demonstrated excellent electrical and optical properties, which make it an attractive candidate as a transparent conductive oxide for photovoltaic applications. However, when depositing ZnO

  17. Thermal shock behaviour of tungsten after high flux H-plasma loading

    NARCIS (Netherlands)

    Wirtz, M.; Linke, J.; Pintsuk, G.; De Temmerman, G.; Wright, G. M.

    2013-01-01

    Previous studies have shown that transient thermal shock loads induce crack networks on tungsten samples especially at low base temperatures. To achieve test conditions which are more relevant for the performance of tungsten-armoured plasma facing components in next step thermonuclear fusion devices

  18. Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor

    NARCIS (Netherlands)

    Agiral, Anil; Nozaki, Tomohiro; Nakase, Masahiko; Yuzawa, Shuhei; Okazaki, Ken; Gardeniers, J.G.E. (Han)

    2011-01-01

    A multi-phase flow non-thermal plasma microreactor based on dielectric barrier discharge has been developed for partial oxidation of methane to liquid oxygenates at atmospheric pressure. A pulsed water injection method has been used to remove condensable liquid components from the active discharge r

  19. Global Time Variability in the Thermal Plasma Composition of the Saturnian Magnetosphere

    Science.gov (United States)

    Ip, W.

    2013-12-01

    The Saturnian magnetosphere is characterized by strong coupling between the charged particles and the neutral gas cloud emitted from Enceladus and the rings. Besides the mass-loading effect due to ionization of the water-group gas, the charge transfer process leading to the generation of energetic neutral atoms is a key process of particle loss and atmospheric precipitation. Detailed measurements by the plasma instruments like CAPS and MIMI have provided many insights to the magnetospheric composition and dynamics driven by such plasma-gas interaction. For example, a statistical study of the CAPS measurements by Thomsen et al. (2010) has shown the relative abundances and radial profiles of different ion species in the corotating thermal plasma disc. Another interesting result has to do with the seasonal variability of the suprathermal O2+ molecular ions detected by the CHEMS/MIMI experiment (Christon et al., 2013) which might have to do with the extended oxygen atmosphere of the ring system (Tseng et al., 2010). In this work, we will use a time-dependent radial diffusion transport model coupled with ion chemistry calculation (Ip, 2000) to simulate the global distributions of various ions (H+, H2+, O+, OH+, H2O+, H3O+, and O2+ )between the outer edge of the A ring to the orbit of Titan. Our parametric study will examine how the thermal ion composition of the Saturnian magnetosphere would be affected by solar cycle effect, seasonal variation of the ring atmosphere, and the suprathermal electron flux. Christon, S.P., Hamilton, D.C., DiFabio, R.D., Mitchell, D.G., Krimigis, S.M., and Jontof-Hutter, D.S., J. Geophys. Res., 118, 3446-3462, 2013. Ip, W.-H., Planet. Space Sci., 48, 775-783, 2000. Thomsen, M.F., Reisenfeld, D.B., Delapp, D.M., Tokar, R.C., Young, D.T., Crary, F.J., Sittler, E.C., McGraw, M.A., and Williams, J.D., J. Geophys. Res., 115, A10220, 2010. Tseng, W.-L., Ip, W.-H., Johnson, R.E., Cassidy, T.A., and Elrod, M.K., Icarus, 206, 382-389, 2010.

  20. Treatment of mixed wastes by thermal plasma discharges; Tratamiento de desechos mixtos por descargas de plasma termico

    Energy Technology Data Exchange (ETDEWEB)

    Diaz A, L.V.; Pacheco S, J.O.; Pacheco P, M.; Monroy G, F.; Emeterio H, M. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: lauradiazarch@yahoo.com.mx

    2007-07-01

    The National Institute of Nuclear Research (ININ) uses an ion exchange resin: IRN 150 (copolymer styrene Divynilbencene) in the TRIGA Mark III reactor to absorb polluted particles with heavy metals and radioactive particles of low level. Once the capacity of filtrate of the resin is exceeded, it is replaced and considered with a mixed waste. This work is based on taking advantage of the advantages of the technique of the thermal plasma in a unique process: (high energy density 105W/cm{sup 3} high enthalpy, high reactivity chemical, high operation temperatures 6000-11500K and quick quenching 106K/s) for the degradation and vitrification of the resin IRN 150. The reactor of plasma is compact and it works to atmospheric pressure and reduced thermal inertia. Therefore, the main parameters involved during the degradation tests and vitrification are: plasma current, voltage, gas flow and distance among the electrodes. The used vitreous matrix, is obtained from a ceramic clay composed by an oxides mixture which are characterized by their good resistance to mechanical impacts and erosion caused by the water. The ceramic clay and the resin IRN 150 were analyzed before the treatment by Scanning Electron Microscopy (MEB), X-ray Diffraction (DRX), Thermal gravimetry (TGA) once vitrified the materials were also analyzed by MEB and DRX. It is obtained as a result that the material more appropriate to be used as vitreous matrix it is a ceramic clay formed by several oxides, being operated the plasma system with a current of 115A, voltage of 25V, flow of the argon gas of 5 l/m and a distance among electrodes of 10mm. With the development of the proposed technology and the material for the vitreous matrix, be rotted to try in a future a great variety of mixed waste. (Author)

  1. Non-thermal plasma-activated water inactivation of food-borne pathogen on fresh produce

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Ruonan; Wang, Guomin; Tian, Ying; Wang, Kaile [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); Zhang, Jue, E-mail: zhangjue@pku.edu.cn [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China); Fang, Jing [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China)

    2015-12-30

    Highlights: • We propose a new approach to treat S. aureus inoculated on strawberries by PAW. • PAW could inactivate S. aureus on strawberries via the Log Reduction results, further confirmed by CLSM and SEM. • The short-lived ROS in PAW are considered the most important agents in inactivation process. • No significant change was found in color, firmness and pH of the PAW treated strawberries. - Abstract: Non-thermal plasma has been widely considered to be an effective method for decontamination of foods. Recently, numerous studies report that plasma-activated water (PAW) also has outstanding antibacterial ability. This study presents the first report on the potential of PAW for the inactivation of Staphylococcus aureus (S. aureus) inoculated on strawberries. PAW treatments achieved a reduction of S. aureus ranging from 1.6 to 2.3 log at day-0 storage, while 1.7 to 3.4 log at day-4 storage. The inactivation efficiency depended on the plasma-activated time for PAW generation and PAW-treated time of strawberries inoculated with S. aureus. LIVE/DEAD staining and scanning electron microscopy results confirm that PAW could damage the bacterial cell wall. Moreover, optical emission spectra and oxidation reduction potential results demonstrate the inactivation is mainly attributed to oxidative stress induced by reactive oxygen species in PAW. In addition, no significant change was found in color, firmness and pH of the PAW treated strawberries. Thus, PAW can be a promising alternative to traditional sanitizers applied in the fresh produce industry.

  2. Evaluation of Ash Toxicity Generated From the Thermal Plasma Pyrolysis of Used Automobile Tires

    Science.gov (United States)

    Chang, J. S.; Novog, D. R.; Jamal, S.

    1996-10-01

    The disposal of used tires represents a severe environmental problem. As the heat content of the rubber tires is even higher than that of coal it should be considered as a future source of alternate fuel for power generation. There have been attempts to burn old tires directly in cofired boilers for production of electricity. However, there are several environmental concerns since the combustion flue gas may contain a significant concentration heavy metals (Fe, Zn, Cd, As, etc.). One technique currently being developed is the pyrolyzation of rubber tires by a thermal plasma to produce combustible gases. In this work, ashes generated during the plasma pyrolysis of used automobile tires using a DC Argon thermal plasma were analyzed using Neutron Activation Analysis (NAA) and produced syngas composition was analyzed by FT-IR.. The gas analysis indicates a significant quantity of combustible gases (CH4, C2H2, C2H4, CO, H2 etc..) was produced from the thermal plasma pyrolysis of used tires. The results also indicate that a majority of the heavy metals present in used tires were concentrated in the ashes deposited in reaction chamber wall and in the two-stage filtering system. Furthermore the heavy metal concentration decreases significantly with increasing distance from the plasma torch. Toxic components such as Zn, As and Cl were also collected in the filtering process.

  3. Air plasma effect on dental disinfection

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, S.; Murata, R. M.; Saxena, D. [Department of Basic Sciences and Craniofacial Biology, College of Dentistry, New York University, New York, New York 10010 (United States); Kuo, S. P.; Chen, C. Y.; Huang, K. J. [Department of Electrical and Computer Engineering, Polytechnic Institute of New York University, Brooklyn, New York 11202 (United States); Popovic, S. [Department of Physics, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2011-07-15

    A nonthermal low temperature air plasma jet is characterized and applied to study the plasma effects on oral pathogens and biofilms. Experiments were performed on samples of six defined microorganisms' cultures, including those of gram-positive bacteria and fungi, and on a cultivating biofilm sample of Streptococcus mutans UA159. The results show that the plasma jet creates a zone of microbial growth inhibition in each treated sample; the zone increases with the plasma treatment time and expands beyond the entire region directly exposed to the plasma jet. With 30s plasma treatment twice daily during 5 days of biofilm cultivation, its formation was inhibited. The viability of S. mutans cells in the treated biofilms dropped to below the measurable level and the killed bacterial cells concentrated to local regions as manifested by the fluorescence microscopy via the environmental scanning electron microscope. The emission spectroscopy of the jet indicates that its plasma effluent carries an abundance of reactive atomic oxygen, providing catalyst for the observed plasma effect.

  4. Air plasma effect on dental disinfection

    Science.gov (United States)

    Duarte, S.; Kuo, S. P.; Murata, R. M.; Chen, C. Y.; Saxena, D.; Huang, K. J.; Popovic, S.

    2011-07-01

    A nonthermal low temperature air plasma jet is characterized and applied to study the plasma effects on oral pathogens and biofilms. Experiments were performed on samples of six defined microorganisms' cultures, including those of gram-positive bacteria and fungi, and on a cultivating biofilm sample of Streptococcus mutans UA159. The results show that the plasma jet creates a zone of microbial growth inhibition in each treated sample; the zone increases with the plasma treatment time and expands beyond the entire region directly exposed to the plasma jet. With 30s plasma treatment twice daily during 5 days of biofilm cultivation, its formation was inhibited. The viability of S. mutans cells in the treated biofilms dropped to below the measurable level and the killed bacterial cells concentrated to local regions as manifested by the fluorescence microscopy via the environmental scanning electron microscope. The emission spectroscopy of the jet indicates that its plasma effluent carries an abundance of reactive atomic oxygen, providing catalyst for the observed plasma effect.

  5. Plasma Reforming of Liquid Hydrocarbon Fuels in Non-Thermal Plasma-Liquid Systems

    Science.gov (United States)

    2010-04-30

    channel with liquid wall in the microporous media under the ultrasound cavitations has shown the following: · The action of the ultrasound field in the...microporous liquid which has a very large ratio of the plasma-liquid contact surface to the plasma volume. As is known the ultrasonic (US) cavitation is a very...2) and it ran over a flat dielectric surface of the magnetostrictive transmitter (5) which produced ultrasonic (US) cavitations , so the discharge

  6. Porous-Al2O3 thermal barrier coatings with dispersed Pt particles prepared by cathode plasma electrolytic deposition

    Institute of Scientific and Technical Information of China (English)

    Jin Zhang

    2016-01-01

    Porousa-Al2O3 thermal barrier coatings (TBCs) containing dispersed Pt particles were prepared by cathode plasma electrolytic deposition (CPED). The influence of the Pt particles on the microstructure of the coatings and the CPED process were studied. The prepared coatings were mainly composed ofα-Al2O3. The average thickness of the coatings was approximately 100μm. Such single-layer TBCs ex-hibited not only excellent high-temperature cyclic oxidation and spallation resistance, but also good thermal insulation properties. Porousa-Al2O3 TBCs inhibit further oxidation of alloy substrates because of their extremely low oxygen diffusion rate, provide good thermal insu-lation because of their porous structure, and exhibit excellent mechanical properties because of the toughening effect of the Pt particles and because of stress relaxation induced by deformation of the porous structure.

  7. Influence of metallic vapours on the properties of air thermal plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Cressault, Y; Hannachi, R; Teulet, Ph; Gleizes, A [LAPLACE - UMR CNRS 5213, Universite de Toulouse 3, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France); Gonnet, J-P; Battandier, J-Y [Schneider Electric, Innovation Division, 38TEC/T3 Plant, 37 Quai Paul-Louis Merlin F38000 Grenoble (France)], E-mail: yann.cressault@laplace.univ-tlse.fr

    2008-08-01

    This paper deals with properties of air thermal plasmas containing vapours of iron, silver or copper. The plasma is supposed to be in local thermodynamic equilibrium, for temperatures ranging from 2000 to 30 000 K. First, the equilibrium composition and thermodynamic properties are presented. Then, the radiative properties are calculated using the method of the net emission coefficient. Finally, the viscosity, electrical and thermal conductivities are calculated using the method of Chapman-Enskog. For all mixtures, mole fractions have been used. The results are computed for various values of pressure, plasma size and proportions of vapours. The influence of metallic vapour is important on the electrical conductivity and on the radiation, even at low concentration. All the metallic vapours present a similar behaviour except iron, which has a stronger radiation emission than the other components.

  8. Degradation of volatile organic compounds in a non-thermal plasma air purifier.

    Science.gov (United States)

    Schmid, Stefan; Jecklin, Matthias C; Zenobi, Renato

    2010-03-01

    The degradation of volatile organic compounds in a commercially available non-thermal plasma based air purifying system was investigated. Several studies exist that interrogate the degradation of VOCs in closed air systems using a non-thermal plasma combined with a heterogeneous catalyst. For the first time, however, our study was performed under realistic conditions (normal indoor air, 297.5K and 12.5 g m(-3) water content) on an open system, in the absence of an auxiliary catalyst, and using standard operating air flow rates (up to 320 L min(-1)). Cyclohexene, benzene, toluene, ethylbenzene and the xylene isomers were nebulized and guided through the plasma air purifier. The degradation products were trapped by activated charcoal tubes or silica gel tubes, and analyzed using gas chromatography mass spectrometry. Degradation efficiencies of 11+/-1.6% for cyclohexene, air purifier.

  9. Finite Element Thermal Study of the Linac4 Plasma Generatora

    CERN Document Server

    Faircloth, D; Kuchler, D; Lettry, L; Scrivens, R; CERN. Geneva. BE Department

    2010-01-01

    The temperature distribution and heat flow at equilibrium of the plasma generator of the RF-powered non-cesiated Linac4 H- ion source have been studied with a finite element model. It is shown that the equilibrium temperatures obtained in the Linac4 nominal operation mode (100 kW RF power, 2 Hz, 0.4 ms pulse duration) are within material specifications except for the magnet cage, where a redesign may be necessary. To assess the upgrade of the Linac4 source for operation in the high-power operation mode of SPL, an extrapolation of the heat load towards 100 kW RF power, 50 Hz repetition rate and 0.4 ms pulse duration has been performed. The results indicate that a significant improvement of the source cooling is required to allow for operation in HP-SPL.

  10. Thermalization of mini-jets in a quark-gluon plasma

    Directory of Open Access Journals (Sweden)

    Iancu Edmond

    2016-01-01

    Full Text Available We present the complete physical picture for the evolution of a high-energy jet propagating through a weakly-coupled quark-gluon plasma (QGP by analytical and numerical investigation of thermalization of the soft components of the jet. Our results support the following physical picture: the leading particle emits a significant number of mini-jets which promptly evolve via multiple branching and thus degrade into a myriad of soft gluons, with energies of the order of the medium temperature T. Via elastic collisions with the medium constituents, these soft gluons relax to local thermal equilibrium with the plasma over a time scale which is considerably shorter than the typical lifetime of the mini-jet. The thermalized gluons form a tail which lags behind the hard components of the jet. Together with the background QGP, they behave hydrodynamically.

  11. Thermalization of mini-jets in a quark–gluon plasma

    Energy Technology Data Exchange (ETDEWEB)

    Iancu, Edmond, E-mail: edmond.iancu@cea.fr; Wu, Bin, E-mail: bin.wu.phys@gmail.com [Institut de Physique Théorique, CEA Saclay, CNRS UMR 3681, F-91191 Gif-sur-Yvette (France); Department of Physics, The Ohio State University, Columbus, OH 43210 (United States)

    2016-12-15

    We present the complete physical picture for the evolution of a high-energy jet propagating through a weakly-coupled quark-gluon plasma (QGP) by analytical and numerical investigation of thermalization of the soft components of the jet. Our results support the following physical picture: the leading particle emits a significant number of mini-jets which promptly evolve via multiple branching and thus degrade into a myriad of soft gluons, with energies of the order of the medium temperature T. Via elastic collisions with the medium constituents, these soft gluons relax to local thermal equilibrium with the plasma over a time scale which is considerably shorter than the typical lifetime of the mini-jet. The thermalized gluons form a tail which lags behind the hard components of the jet. Together with the background QGP, they behave hydrodynamically.

  12. Nanocomposite Lanthanum Zirconate Thermal Barrier Coating Deposited by Suspension Plasma Spray Process

    Science.gov (United States)

    Wang, Chaohui; Wang, You; Wang, Liang; Hao, Guangzhao; Sun, Xiaoguang; Shan, Fan; Zou, Zhiwei

    2014-10-01

    This work seeks to develop an innovative nanocomposite thermal barrier coating (TBC) exhibiting low thermal conductivity and high durability compared with that of current TBCs. To achieve this objective, nanosized lanthanum zirconate particles were selected for the topcoat of the TBC system, and a new process—suspension plasma spray—was employed to produce desirable microstructural features: the nanocomposite lanthanum zirconate TBC contains ultrafine splats and high volume porosity, for lower thermal conductivity, and better durability. The parameters of plasma spray experiment included two main variables: (i) spray distance varying from 40 to 80 mm and (ii) the concentration of suspension 20, 25, and 30 wt.%, respectively. The microstructure of obtained coatings was characterized with scanning electron microscope and x-ray diffraction. The porosity of coatings is in the range of 6-10%, and the single phase in the as-sprayed coatings was pyrochlore lanthanum zirconate.

  13. Thermalization of mini-jets in a quark-gluon plasma

    Science.gov (United States)

    Iancu, Edmond; Wu, Bin

    2016-12-01

    We present the complete physical picture for the evolution of a high-energy jet propagating through a weakly-coupled quark-gluon plasma (QGP) by analytical and numerical investigation of thermalization of the soft components of the jet. Our results support the following physical picture: the leading particle emits a significant number of mini-jets which promptly evolve via multiple branching and thus degrade into a myriad of soft gluons, with energies of the order of the medium temperature T. Via elastic collisions with the medium constituents, these soft gluons relax to local thermal equilibrium with the plasma over a time scale which is considerably shorter than the typical lifetime of the mini-jet. The thermalized gluons form a tail which lags behind the hard components of the jet. Together with the background QGP, they behave hydrodynamically.

  14. Novel fragmentation model for pulverized coal particles gasification in low temperature air thermal plasma

    Directory of Open Access Journals (Sweden)

    Jovanović Rastko D.

    2016-01-01

    Full Text Available New system for start-up and flame support based on coal gasification by low temperature air thermal plasma is planned to supplement current heavy oil system in Serbian thermal power plants in order to decrease air pollutions emission and operational costs. Locally introduced plasma thermal energy heats up and ignites entrained coal particles, thus starting chain process which releases heat energy from gasified coal particles inside burner channel. Important stages during particle combustion, such as particle devolatilisation and char combustion, are described with satisfying accuracy in existing commercial CFD codes that are extensively used as powerful tool for pulverized coal combustion and gasification modeling. However, during plasma coal gasification, high plasma temperature induces strong thermal stresses inside interacting coal particles. These stresses lead to “thermal shock” and extensive particle fragmentation during which coal particles with initial size of 50-100 m disintegrate into fragments of at most 5-10 m. This intensifies volatile release by a factor 3-4 and substantially accelerates the oxidation of combustible matter. Particle fragmentation, due to its small size and thus limited influence on combustion process is commonly neglected in modelling. The main focus of this work is to suggest novel approach to pulverized coal gasification under high temperature conditions and to implement it into commercial comprehensive code ANSYS FLUENT 14.0. Proposed model was validated against experimental data obtained in newly built pilot scale D.C plasma burner test facility. Newly developed model showed very good agreement with experimental results with relative error less than 10%, while the standard built-in gasification model had error up to 25%.

  15. Effective attraction between oscillating electrons in plasma

    CERN Document Server

    Dvornikov, Maxim

    2011-01-01

    We consider the effective interaction between electrons due to the exchange of virtual acoustic waves in low temperature plasma. Electrons are supposed to participate in rapid oscillations and form a spherically symmetric soliton like structure. We show that under certain conditions this effective interaction can result in the attraction between oscillating electrons and can be important for the dynamics of a plasmoid. Some possible applications of the obtained results to the theory of natural long lived plasma structures are also discussed.

  16. Thermal Bridge Effects in Walls Separating Rowhouses

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures.......In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures....

  17. Thermal Bridge Effects in Walls Separating Rowhouses

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures.......In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures....

  18. Thermal Conductivity and Erosion Durability of Composite Two-Phase Air Plasma Sprayed Thermal Barrier Coatings

    Science.gov (United States)

    Schmitt, Michael P.; Rai, Amarendra K.; Zhu, Dongming; Dorfman, Mitchell R.; Wolfe, Douglas E.

    2015-01-01

    To enhance efficiency of gas turbines, new thermal barrier coatings (TBCs) must be designed which improve upon the thermal stability limit of 7 wt% yttria stabilized zirconia (7YSZ), approximately 1200 C. This tenant has led to the development of new TBC materials and microstructures capable of improved high temperature performance. This study focused on increasing the erosion durability of cubic zirconia based TBCs, traditionally less durable than the metastable t' zirconia based TBCs. Composite TBC microstructures composed of a low thermal conductivity/high temperature stable cubic Low-k matrix phase and a durable t' Low-k secondary phase were deposited via APS. Monolithic coatings composed of cubic Low-k and t' Low-k were also deposited, in addition to a 7YSZ benchmark. The thermal conductivity and erosion durability were then measured and it was found that both of the Low-k materials have significantly reduced thermal conductivities, with monolithic t' Low-k and cubic Low-k improving upon 7YSZ by approximately 13 and approximately 25%, respectively. The 40 wt% t' Low-k composite (40 wt% t' Low-k - 60 wt% cubic Low-k) showed a approximately 22% reduction in thermal conductivity over 7YSZ, indicating even at high levels, the t' Low-k secondary phase had a minimal impact on thermal in the composite coating. It was observed that a mere 20 wt% t' Low-k phase addition can reduce the erosion of a cubic Low-k matrix phase composite coating by over 37%. Various mixing rules were then investigated to assess this non-linear composite behavior and suggestions were made to further improve erosion durability.

  19. Thermal effects on parallel resonance energy of whistler mode wave

    Indian Academy of Sciences (India)

    Devendraa Siingh; Shubha Singh; R P Singh

    2006-02-01

    In this short communication, we have evaluated the effect of thermal velocity of the plasma particles on the energy of resonantly interacting energetic electrons with the propagating whistler mode waves as a function of wave frequency and -value for the normal and disturbed magnetospheric conditions. During the disturbed conditions when the magnetosphere is depleted in electron density, the resonance energy of the electron enhances by an order of magnitude at higher latitudes, whereas the effect is small at low latitudes. An attempt is made to explain the enhanced wave activity observed during magnetic storm periods.

  20. Magnetic fluctuations in anisotropic space plasmas: The effect of the plasma environment

    Science.gov (United States)

    Valdivia, J. A.; Toledo, B. A.; Gallo, N.; Muñoz, V.; Rogan, J.; Stepanova, M.; Moya, P. S.; Navarro, R. E.; Viñas, A. F.; Araneda, J.; López, R. A.; Díaz, M.

    2016-11-01

    The observations in the solar wind, which are usually organized in a beta-anisotropy diagram, seem to be constrained by linear instability thresholds. Unexpectedly, under these quasi-stable conditions, there is a finite level of electromagnetic fluctuations. A relevant component of these fluctuations can be understood in terms of the electromagnetic fields produced by the thermal motion of the charged particles. For the simple case of parallel propagating fields in an electron-proton plasma, we study the effect of the parameter ωpp /Ωc that characterizes the different space physics environments, and can affect the continuum spectrum produced by these fluctuations, which in turn may be used to understand the relevance of these processes occurring in a specific plasma environment.

  1. On the propagation of hydromagnetic waves in a plasma of thermal and suprathermal components

    Science.gov (United States)

    Kumar, Nagendra; Sikka, Himanshu

    2007-12-01

    The propagation of MHD waves is studied when two ideal fluids, thermal and suprathermal gases, coupled by magnetic field are moving with the steady flow velocity. The fluids move independently in a direction perpendicular to the magnetic field but gets coupled along the field. Due to the presence of flow in suprathermal and thermal fluids there appears forward and backward waves. All the forward and backward modes propagate in such a way that their rate of change of phase speed with the thermal Mach number is same. It is also found that besides the usual hydromagnetic modes there appears a suprathermal mode which propagates with faster speed. Surface waves are also examined on an interface formed with composite plasma (suprathermal and thermal gases) on one side and the other is a non-magnetized plasma. In this case, the modes obtained are two or three depending on whether the sound velocity in thermal gas is equal to or greater than the sound velocity in suprathermal gas. The results lead to the conclusion that the interaction of thermal and suprathermal components may lead to the occurrence of an additional mode called suprathermal mode whose phase velocity is higher than all the other modes.

  2. Nonextensivity effect on radio-wave transmission in plasma sheath

    Science.gov (United States)

    Mousavi, A.; Esfandiari-Kalejahi, A.; Akbari-Moghanjoughi, M.

    2016-04-01

    In this paper, new theoretical findings on the application of magnetic field in effective transmission of electromagnetic (EM) waves through a plasma sheath around a hypersonic vehicle are reported. The results are obtained by assuming the plasma sheath to consist of nonextensive electrons and thermal ions. The expressions for the electric field and effective collision frequency are derived analytically in the framework of nonextensive statistics. Examination of the reflection, transmission, and absorption coefficients regarding the strength of the ambient magnetic field shows the significance of q-nonextensive parameter effect on these entities. For small values of the magnetic field, the transmission coefficient increases to unity only in the range of - 1 hypersonic flights.

  3. An Experimental Study of the Drag Force on a Cylinder Exposed to an Argon Thermal Plasma Cross Flow

    Institute of Scientific and Technical Information of China (English)

    XinTao; XiChen; 等

    1992-01-01

    Experimental data are presented concerning the drag force on a cylinder exposed to an argon plasma cross flow with temperatures about 104 K and velocities about 102 m/s.Using a method of sweeping a cylindrical probe across an argon plasma jet,the total drag force on the cylinder can be measured as a function of the lateral distance of cylindrical probe with respect to the plasma-jet axis.Through the Abel inversion,the drag force for per unit of cylinderlength and thus the drag coefflcient of cylinder have been measured under plasma conditions and compared with the values obtained from the standard drag curve of the cylinder in an isothermal flow.Experimental results show that the measured grag forces are always less than their counterparts read from the standard drag curve with the smae Reynolds numbers based on the oncoming plasma properties.Thew drag force on the cylinder exoposed to a thermal plasma flow is shown to be approximately proportional to the square root of cylinder diameter in the present experiment and it increases slightly proportional to the square root of cylinder diameter in the present experiment and if increases slightly with increasing surface temperature of the cylinder,.It is also shown that applying a voltage between the drag prode and the anode of the plasma jet generator has little effect on the drag force of cylinder under the experimental conditions.The drag force on a cylinder with finite length exposed to an argon plasma with the axis parallel to the plams jet is independent of ration of cylinder length to its dismeter L/d for the cases when L/d≤1.

  4. Shukla-Spatschek diffusion effects on surface plasma waves in astrophysical turbulent plasmas

    Science.gov (United States)

    Lee, Myoung-Jae; Jung, Young-Dae

    2017-02-01

    The effects of Shukla-Spatschek turbulent diffusion on a temporal mode of surface waves propagating at the interface of an astrophysical turbulent plasma are investigated. The damping rates for high and low modes of surface wave are kinetically derived by employing the Vlasov-Poisson equation and the specular reflection boundary condition. We found that the diffusion caused by the fluctuating electric fields leads to damping for both high and low modes of surface waves. The high-mode damping is enhanced with an increase of the wavenumber and the diffusion coefficient, but suppressed by an increase of electron thermal energy. By contrast, the low-mode damping is suppressed as the wavenumber and the thermal energy increase although it is enhanced as the diffusion increases. The variation of the damping rate due to the Shukla-Spatschek turbulent diffusion is also discussed.

  5. Non-thermal plasma exhaust aftertreatment: Are all plasmas the same?

    Energy Technology Data Exchange (ETDEWEB)

    Whealton, J.H.; Hanson, G.R.; Storey, J.M.; Raridon, R.J.; Armfield, J.S.; Bigelow, T.S.; Graves, R.L. [Oak Ridge National Lab., TN (United States)

    1997-12-31

    The authors describe initial experiments employing 5.5 GHz pulsed microwave power, which should result in enhanced chemistry compared to present state-of-the-art plasma aftertreatments by; reducing plasma electric field shielding, increasing availability of atomic nitrogen, exploiting surface charging of dielectrics, avoiding (low field) threshold initiated discharges, and achieving a higher high energy tail on the electron distribution function. As an example, the authors decided to test for NO reduction in N{sub 2}. While this reaction is not a complete description of the exhaust issues by any means, they thought it would demonstrate the technology proposed.

  6. Thermal imaging of plasma with a phased array antenna in QUEST

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, Kishore, E-mail: mishra@triam.kyushu-u.ac.jp; Nagata, K.; Akimoto, R.; Banerjee, S. [IGSES, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Idei, H.; Zushi, H.; Hanada, K.; Hasegawa, M.; Nakamura, K.; Fujisawa, A.; Nagashima, Y.; Onchi, T.; Kuzmin, A. [RIAM, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Yamamoto, M. K. [Research Institute for Sustainable Humanosphere, Kyoto University, Uji 611-0011 (Japan)

    2014-11-15

    A thermal imaging system to measure plasma Electron Bernstein Emission (EBE) emanating from the mode conversion region in overdense plasma is discussed. Unlike conventional ECE/EBE imaging, this diagnostics does not employ any active mechanical scanning mirrors or focusing optics to scan for the emission cones in plasma. Instead, a standard 3 × 3 waveguide array antenna is used as a passive receiver to collect emission from plasma and imaging reconstruction is done by accurate measurements of phase and intensity of these signals by heterodyne detection technique. A broadband noise source simulating the EBE, is installed near the expected mode conversion region and its position is successfully reconstructed using phase array technique which is done in post processing.

  7. Recovery of Cu and valuable metals from E-waste using thermal plasma treatment

    Science.gov (United States)

    Mitrasinovic, Aleksandar; Pershin, Larry; Wen, John Z.; Mostaghimi, Javad

    2011-08-01

    A thermal plasma treatment was employed for economical recovery of valuable metals from e-waste. Cu-clad plates that simulated circuit boards were fed at the bottom of the reactor and treated with a plasma jet at temperatures between 385 and 840°C. Organic components of the Cu-clad plates were decomposed and contributed to the increased temperature of the offgas. Due to the low temperatures at the base of the reactor, the analyzed samples did not show losses characteristic for the plasma processes such as evaporation or metal oxidation. After plasma treatment, Cu foils were separated from the fiber glass and other solid residues allowing a complete recovery. Solid residues of the plates at the bottom of the reactor were crunched into small particles, allowing easy recycling or use as construction material.

  8. Application of CCD Cameras to Investigations of Mixing on Boundaries of a Thermal Plasma Jet

    Institute of Scientific and Technical Information of China (English)

    J.HLINA; J.(S)ONSKY; J.(S)LECHTA

    2007-01-01

    Mixing of a thermal plasma jet with the surrounding atmosphere was studied using two CCD cameras (PCO SensiCam) situated detecting simultaneously the radiation of argon and nitrogen.The evaluation of image differences between two records showed that the location of regions on plasma jet boundaries characterised by stronger nitrogen radiation changes with the plasma flow rate.Close-to-laminar flow results in a small mixing rate and consequently low nitrogen optical emission on plasma jet boundaries.The increase of the flow rate leads to the formation of a relatively thick and stable layer on the boundaries characterised by strong nitrogen radiation.Further enhancement of the flow rate results in the formation of unstable regions of excited nitrogen molecules moving along the jet.

  9. Magnetic Field Effects on Plasma Plumes

    Science.gov (United States)

    Ebersohn, F.; Shebalin, J.; Girimaji, S.; Staack, D.

    2012-01-01

    Here, we will discuss our numerical studies of plasma jets and loops, of basic interest for plasma propulsion and plasma astrophysics. Space plasma propulsion systems require strong guiding magnetic fields known as magnetic nozzles to control plasma flow and produce thrust. Propulsion methods currently being developed that require magnetic nozzles include the VAriable Specific Impulse Magnetoplasma Rocket (VASIMR) [1] and magnetoplasmadynamic thrusters. Magnetic nozzles are functionally similar to de Laval nozzles, but are inherently more complex due to electromagnetic field interactions. The two crucial physical phenomenon are thrust production and plasma detachment. Thrust production encompasses the energy conversion within the nozzle and momentum transfer to a spacecraft. Plasma detachment through magnetic reconnection addresses the problem of the fluid separating efficiently from the magnetic field lines to produce maximum thrust. Plasma jets similar to those of VASIMR will be studied with particular interest in dual jet configurations, which begin as a plasma loops between two nozzles. This research strives to fulfill a need for computational study of these systems and should culminate with a greater understanding of the crucial physics of magnetic nozzles with dual jet plasma thrusters, as well as astrophysics problems such as magnetic reconnection and dynamics of coronal loops.[2] To study this problem a novel, hybrid kinetic theory and single fluid magnetohydrodynamic (MHD) solver known as the Magneto-Gas Kinetic Method is used.[3] The solver is comprised of a "hydrodynamic" portion based on the Gas Kinetic Method and a "magnetic" portion that accounts for the electromagnetic behaviour of the fluid through source terms based on the resistive MHD equations. This method is being further developed to include additional physics such as the Hall effect. Here, we will discuss the current level of code development, as well as numerical simulation results

  10. Non-thermal atmospheric plasmas in dental restoration: improved resin adhesive penetration.

    Science.gov (United States)

    Zhang, Ying; Yu, Qingsong; Wang, Yong

    2014-08-01

    To investigate the influence of non-thermal plasma treatment on the penetration of a model dental adhesive into the demineralized dentine. Prepared dentine surfaces were conditioned with Scotchbond Universal etchant for 15s and sectioned equally perpendicular to the etched surfaces. The separated halves were randomly selected for treatment with an argon plasma brush (input current 6mA, treatment time 30s) or gentle argon air blowing (treatment time 30s, as control). The plasma-treated specimens and control specimens were applied with a model adhesive containing 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy) phenyl]-propane (BisGMA) and 2-hydroxyethyl methacrylate (HEMA) (mass ratio of 30/70), gently air-dried for 5s, and light-cured for 20s. Cross-sectional specimens were characterized using micro-Raman spectral mapping across the dentine, adhesive/dentine interface, and adhesive layer at 1-μm spatial resolution. SEM was also employed to examine the adhesive/dentine interfacial morphology. The micro-Raman result disclosed that plasma treatment significantly improved the penetration of the adhesive, evidenced by the apparently higher content of the adhesive at the adhesive/dentine interface as compared to the control. Specifically, the improvement of the adhesive penetration using plasma technique was achieved by dramatically enhancing the penetration of hydrophilic monomer (HEMA), while maintaining the penetration of hydrophobic monomer (BisGMA). Morphological observation at the adhesive/dentine interface using SEM also confirmed the improved adhesive penetration. The results further suggested that plasma treatment could benefit polymerization of the adhesive, especially in the interface region. The significant role of the non-thermal plasma brush in improving the adhesive penetration into demineralized dentine has been demonstrated. The results obtained may offer a better prospect of using plasma in dental restoration to optimize adhesion between tooth substrate and

  11. Non-Thermal Electron Energization from Magnetic Reconnection in Laser-Driven Plasmas

    CERN Document Server

    Totorica, Samuel; Fiuza, Frederico

    2016-01-01

    The possibility of studying non-thermal electron energization in laser-driven plasma experiments of magnetic reconnection is studied using two- and three-dimensional particle-in-cell simulations. It is demonstrated that non-thermal electrons with energies more than an order of magnitude larger than the initial thermal energy can be produced in plasma conditions currently accessible in the laboratory. Electrons are accelerated by the reconnection electric field, being injected at varied distances from the X-points, and in some cases trapped in plasmoids, before escaping the finite-sized system. Trapped electrons can be further energized by the electric field arising from the motion of the plasmoid. This acceleration gives rise to a non-thermal electron component that resembles a power-law spectrum, containing up to ~ 8% of the initial energy of the interacting electrons and ~ 24 % of the initial magnetic energy. Estimates of the maximum electron energy and of the plasma conditions required to observe suprather...

  12. Analysis of Plasma-Sprayed Thermal Barrier Coatings With Homogeneous and Heterogeneous Bond Coats Under Spatially Uniform Cyclic Thermal Loading

    Science.gov (United States)

    Arnold, Steven M.; Pindera, Marek-Jerzy; Aboudi, Jacob

    2003-01-01

    This report summarizes the results of a numerical investigation into the spallation mechanism in plasma-sprayed thermal barrier coatings observed under spatially-uniform cyclic thermal loading. The analysis focuses on the evolution of local stress and inelastic strain fields in the vicinity of the rough top/bond coat interface during thermal cycling, and how these fields are influenced by the presence of an oxide film and spatially uniform and graded distributions of alumina particles in the metallic bond coat aimed at reducing the top/bond coat thermal expansion mismatch. The impact of these factors on the potential growth of a local horizontal delamination at the rough interface's crest is included. The analysis is conducted using the Higher-Order Theory for Functionally Graded Materials with creep/relaxation constituent modeling capabilities. For two-phase bond coat microstructures, both the actual and homogenized properties are employed in the analysis. The results reveal the important contributions of both the normal and shear stress components to the delamination growth potential in the presence of an oxide film, and suggest mixed-mode crack propagation. The use of bond coats with uniform or graded microstructures is shown to increase the potential for delamination growth by increasing the magnitude of the crack-tip shear stress component.

  13. Spark plasma sintering and thermal conductivity of carbon nanotube bulk materials

    Science.gov (United States)

    Zhang, H. L.; Li, J.-F.; Yao, K. F.; Chen, L. D.

    2005-06-01

    Carbon nanotube (CNT) bulk samples were fabricated by spark plasma sintering (SPS), which, as a rapid consolidation technique, preserved the phase structure and diameter of cylindrical tubules of the CNTs even at high temperatures of up to 2000°C. The thermal conductivity of the resultant bulk samples was measured by the conventional laser-flash method, and the corresponding thermal conductivity was found to be as low as 4.2W/m/K at room temperature. This low thermal conductivity of the CNT bulk materials was explained on the basis of multiple physical elements including intensive tube-tube interactions. CNT bulk materials may find potential applications as thermoelectric materials that require low thermal conductivity, but high electrical conductivity.

  14. Electromagnetic effects on explosive reaction and plasma

    Energy Technology Data Exchange (ETDEWEB)

    Tasker, Douglas G [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Mace, Jonathan L [Los Alamos National Laboratory; Pemberton, Steven J [Los Alamos National Laboratory; Sandoval, Thomas D [Los Alamos National Laboratory; Lee, Richard J [INDIAN HEAD DIVISION

    2010-01-01

    A number of studies have reported that electric fields can have quantifiable effects on the initiation and growth of detonation, yet the mechanisms of these effects are not clear. Candidates include Joule heating of the reaction zone, perturbations to the activation energy for chemical reaction, reduction of the Peierls energy barrier that facilitates dislocation motion, and acceleration of plasma projected from the reaction zone. In this study the possible role of plasma in the initiation and growth of explosive reaction is investigated. The effects of magnetic and electric field effects on reaction growth will be reviewed and recent experiments reported.

  15. Coating effects on thermal properties of carbon carbon and carbon silicon carbide composites for space thermal protection systems

    Science.gov (United States)

    Albano, M.; Morles, R. B.; Cioeta, F.; Marchetti, M.

    2014-06-01

    Many are the materials for hot structures, but the most promising one are the carbon based composites nowadays. This is because they have good characteristics with a high stability at high temperatures, preserving their mechanical properties. Unfortunately, carbon reacts rapidly with oxygen and the composites are subjected to oxidation degradation. From this point of view CC has to be modified in order to improve its thermal and oxidative resistance. The most common solutions are the use of silicon carbide into the carbon composites matrix (SiC composites) to make the thermal properties increase and the use of coating on the surface in order to protect the composite from the space plasma effects. Here is presented an experimental study on coating effects on these composites. Thermal properties of coated and non coated materials have been studied and the thermal impact on the matrix and surface degradation is analyzed by a SEM analysis.

  16. Kinetic study on non-thermal volumetric plasma decay in the early afterglow of air discharge generated by a short pulse microwave or laser

    Science.gov (United States)

    Yang, Wei; Zhou, Qianhong; Dong, Zhiwei

    2016-08-01

    This paper reports a kinetic study on non-thermal plasma decay in the early afterglow of air discharge generated by short pulse microwave or laser. A global self-consistent model is based on the particle balance of complex plasma chemistry, electron energy equation, and gas thermal balance equation. Electron-ion Coulomb collision is included in the steady state Boltzmann equation solver to accurately describe the electron mobility and other transport coefficients. The model is used to simulate the afterglow of microsecond to nanosecond pulse microwave discharge in N2, O2, and air, as well as femtosecond laser filament discharge in dry and humid air. The simulated results for electron density decay are in quantitative agreement with the available measured ones. The evolution of plasma decay under an external electric field is also investigated, and the effect of gas heating is considered. The underlying mechanism of plasma density decay is unveiled through the above kinetic modeling.

  17. Dimensionless factors for an alternating-current non-thermal arc plasma

    Science.gov (United States)

    Zhang, Si-Yuan; Li, Xiao-Song; Liu, Jin-Bao; Liu, Jing-Lin; Li, He-Ping; Zhu, Ai-Min

    2016-12-01

    A gliding arc discharge, as a source of warm plasma combining advantages of both thermal and cold plasmas, would have promising application prospects in the fields of fuel conversion, combustion enhancement, material synthesis, surface modifications, pollution control, etc. In order to gain insight into the features of an alternating-current gliding arc discharge plasma, three dimensionless factors, i.e., the extinction span (ψ), current lag (δ), and heating lag (χ) factors are proposed in this letter based on the measured waveforms of the discharge voltage and current in an AC gliding arc discharge plasma. The influences of the driving frequency of the power supply (f) on these three dimensionless parameters are investigated experimentally with the explanations on the physical meanings of these factors. The experimental results show that a higher value of f would lead to the lower values of ψ and δ, as well as a higher value of χ. These experimental phenomena indicate a lower threshold ignition voltage of the discharges, a lower current-growth inertia of the gliding arcs and a larger relative thermal inertia of the plasmas with increase the driving frequency of the power supply in the operating parameter range studied in this letter.

  18. Application of the thermal plasma technique in the treatment of stone surfaces; Aplicacion de la tecnica de plasmas termicos en el tratamiento de superficies petreas

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez A, Z.I

    2000-07-01

    The stone materials which form part of the cultural heritage of Mexico, are degraded under the united action of water, atmospheric gases, air pollution, temperature changes and the microorganisms action; provoking on the stone: fissures, crevices, scalings, fragmentations, pulverizations, etc. Therefore, the purpose of this work is to study the possibilities to apply a protective coating on the stone surfaces, previously clean and consolidated, through the thermal plasma technique. The purpose is to analyse the physical and chemical properties of three types of stone materials: quarry, tezontle and chiluca, usually used in constructions of cultural interest such as: historical monuments, churches, sculptures, etc., before and after to be submitted to the action of thermal plasma in order to examine the feasibility in the use of this coating technique in this type of applications. The application of conventional techniques to determine: porosity, density, absorption, low pressure water absorption and crystallization by total immersion of nuclear techniques such as: neutron activation analysis, x-ray diffraction and scanning electron microscopy as well as of instrumental techniques: optical microscopy, mechanical assays of compression, flexure and surface area calculations, allowed to know the chemical and physical properties of the stone material before and after to be treated through the thermal plasma technique, projecting quartz on the stones surface at different distances and current intensity and showing the effect caused by the modifications or surface alterations present by cause of the application of that coating. the obtained results provide a general panorama of the application of this technique as an alternative to the maintenance of the architectural inheritance built in stone. (Author)

  19. Thermodynamical consideration of the synthesis of solid AlN from thermal plasma

    Directory of Open Access Journals (Sweden)

    NIKOLA PEKAS

    2001-08-01

    Full Text Available The synthesis process of solid AlN in thermal plasmas was investigated theoretically by computing the equilibrium composition of the gas mixture involving nitrogen and various amounts of aluminum, oxygen and hydrogen for the temperature range between 1000 and 5500 K. The results obtained by treating the plasma as a single-gas system were combined with those which take into account the presence of solid AlN and liquid Al, to find the optimal conditions for the deposition of solid AlN. The factors determining the efficiency of this process are discussed.

  20. On the conical refraction of hydromagnetic waves in plasma with anisotropic thermal pressure general consideration

    CERN Document Server

    Tsiklauri, D

    1996-01-01

    A phenomenon analogous to the conical refraction well-known in the crystalooptics and crystaloacoustics is considered for the magnetohydrodynamical waves in a collisionless plasma with anisotropic thermal pressure. Imposing the most general (generalization of Tsiklauri, 1996, Phys. Plasmas, 3, 800) condition for the existence of the phenomenon, angle of the conical refraction is calculated which appeared to be dependent on the ratio of the Alfven velocity and sound speed measured in the perpendicular direction in respect to the external magnetic field. Feasible ways of experimental demonstration of the phenomenon are discussed and a novelty brought by the general consideration is outlined.

  1. The thermalization of soft modes in non-expanding isotropic quark gluon plasmas

    CERN Document Server

    Blaizot, Jean-Paul; Mehtar-Tani, Yacine

    2016-01-01

    We discuss the role of elastic and inelastic collisions and their interplay in the thermalization of the quark-gluon plasma. We consider a simplified situation of a static plasma, spatially uniform and isotropic in momentum space. We focus on the small momentum region, which equilibrates first, and on a short time scale. We obtain a simple kinetic equation that allows for an analytic description of the most important regimes. The present analysis suggests that the formation of a Bose condensate, expected when only elastic collisions are present, is strongly hindered by the inelastic, radiative, processes.

  2. The thermalization of soft modes in non-expanding isotropic quark gluon plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Blaizot, Jean-Paul, E-mail: jean-paul.blaizot@cea.fr [Institut de Physique Théorique, CNRS/UMR 3681, CEA Saclay, F-91191 Gif-sur-Yvette (France); Liao, Jinfeng [Physics Department and Center for Exploration of Energy and Matter, Indiana University, 2401 N Milo B. Sampson Lane, Bloomington, IN 47408 (United States); RIKEN BNL Research Center, Bldg. 510A, Brookhaven National Laboratory, Upton, NY 11973 (United States); Mehtar-Tani, Yacine [Institute for Nuclear Theory, University of Washington, Seattle, WA 98195-1550 (United States)

    2017-05-15

    We discuss the role of elastic and inelastic collisions and their interplay in the thermalization of the quark–gluon plasma. We consider a simplified situation of a static plasma, spatially uniform and isotropic in momentum space. We focus on the small momentum region, which equilibrates first, and on a short time scale. We obtain a simple kinetic equation that allows for an analytic description of the most important regimes. The present analysis suggests that the formation of a Bose condensate, expected when only elastic collisions are present, is strongly hindered by the inelastic, radiative, processes.

  3. Small scale experiment on the plasma assisted thermal chemical preparation and combustion of pulverized coal

    Energy Technology Data Exchange (ETDEWEB)

    Masaya, Sugimoto; Koichi, Takeda [Akita Prefectural University (Japan); Solonenko, O.P. [Institute of Theoretical and Applied Mechanics, Novosibirsk (Russian Federation); Sakashita, M.; Nakamura, M. [Japan Technical Information Service, Tokyo (Japan)

    2001-07-01

    Ignition and stable combustion of pulverized coal with Nitrogen and Air plasmas are investigated experimentally for some different types of coal. The experimental results show that air plasma has strong effect for ignition and stabilization of coal combustion. In addition, suppression of NO{sub x} production could be possible even in air plasma. It is possible to ignite and burn stably for the inferior coal that contains volatile matter in the ratio of only 10% of dry total mass. (authors)

  4. Dodick laser phacolysis: thermal effects.

    Science.gov (United States)

    Alzner, E; Grabner, G

    1999-06-01

    To gather experimental data on whether Dodick laser phacolysis leads to corneal or scleral burns. The Eye Department, County Hospital Salzburg, Salzburg, Austria. The study was done using a pulsed neodymium:YAG (Nd:YAG) laser with a wavelength of 1064 nm; energy, 10 mJ; and duration of pulses, 14 ns. The light pulse is carried by a 400 microns quartz fiber to the laser phacolysis probe. The laser light hits a titanium target inside the tip, causing an optical breakdown and thus a shock wave. The generation of both plasma and the shock disrupt the nuclear material. The temperature at the ultrasonic phaco and laser phacolysis tip was measured under air and balanced salt solution (BSS) in a test chamber and in the anterior chambers of eye-bank eyes. Ultrasonic phacoemulsification led to a difference in temperature up to 55.3 degrees C under air, 12 degrees C in BSS, and 10.9 degrees C in the anterior chamber. There was no clinical significant heat generated by the laser phacolysis tip. This initial in vitro study demonstrates that the well-known risk of the tissue heating (i.e., phaco burn) does not occur with Dodick laser phacolysis, even when the irrigation flow is slow or discontinued.

  5. Remelting of metallurgical fines using thermal plasma; Refusao de finos metalurgicos via plasma termico

    Energy Technology Data Exchange (ETDEWEB)

    Vicente, L.C.; Neto F, J.B.F.; Bender, O.W.; Collares, M.P

    1992-12-31

    A plasma furnace was developed for remelting of ferro alloys and silicon fines. The furnace capacity was about 4 Kg of silicon and power about 50 kW. The fine (20 to 100 mesh) was fed into the furnace directly at the high temperature zone. This system was tested for remelting silicon fines and the results in the recovery of silicon was about 95% and it took place a refine of aluminium and calcium. (author) 10 refs., 4 figs., 2 tabs.

  6. Thermally enhanced formation of photon-induced damage on GaN films in Cl2 plasma

    Science.gov (United States)

    Liu, Zecheng; Asano, Atsuki; Imamura, Masato; Ishikawa, Kenji; Takeda, Keigo; Kondo, Hiroki; Oda, Osamu; Sekine, Makoto; Hori, Masaru

    2017-09-01

    Deep ultraviolet (UV) photons emitted from Cl2 plasmas become a critical cause of degradation in both photoluminescence (PL) properties and surface stoichiometry as a result of plasma-induced damage on GaN films in Cl2 plasma etching at high temperatures. The damages were formed thermally by photon-irradiations of plasma UV emissions with wavelengths of ˜258-306 nm from Cl2 plasma at temperatures greater than 500 °C. The damage were observed with a depth of approximately 3.2 nm. The PL property degraded by the UV emission-induced damage at an early period of plasma etching and reached a constant value.

  7. Biomolecular Effects of Cold Plasma Exposure

    Science.gov (United States)

    Mogul, Rakesh; Bolshakov, Alexander A.; Chan, Suzanne L.; Stevens, Ramsey D.; Khare, Bishun N.; Meyyappan, M.; Trent, Jonathan D.; DeVincenzi, D. (Technical Monitor)

    2002-01-01

    The effects of cold plasma exposure on Deinococcus radiodurans, plasmid DNA and model proteins were assessed using microbiological, spectrometric and biochemical techniques. Exposure of D. radiodurans, an extremely radiation resistant microbe, to O2 plasma (less than or equal to 25 W, approx. 45 mTorr, 90 min) yielded a approx. 99.999 % sterilization and the sterilization rate was increased approx. 10-fold at 100 W and 500 mTorr. AFM images shows that the exposed cells are significantly deformed and possess 50-70 nm concavities. IR analysis indicates the chemical degradation of lipids, proteins and carotenoids of the cell wall and membrane. Intracellular damage was indicated by major absorbance loss at 1245, 1651 and 1538/cm corresponding to degradation of DNA and proteins, respectively. Biochemical experiments demonstrate that plasmas induce strand scissions and crosslinking of plasmid DNA, and reduction of enzyme activity; the degradation is power dependent with total sample loss occurring in 60 s at 200 W and 500 mTorr. Emission spectroscopy shows that D. radiodurans is volatilized into CO2, CO, N2 and H2O confirming the removal of biological matter from contaminated surfaces. The O2 plasma impacts several cellular components predominantly through chemical degradation by atomic oxygen. A CO2, plasma, however, was not effective at degrading D. radiodurans, revealing the importance of plasma composition, which has implications for planetary protection and the contamination of Mars.

  8. Conversion of carbon disulfide in air by non-thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Xiao; Sun, Yifei [School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Zhu, Tianle, E-mail: zhutl@buaa.edu.cn [School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Fan, Xing [College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124 (China)

    2013-10-15

    Highlights: • The behavior of NTP for CS{sub 2} conversion in air was investigated. • CS{sub 2} conversion increase with the increase of specific input energy. • Short-living species are more important in CS{sub 2} conversion than long-living species. • The main gaseous products of CS{sub 2} conversion are CO, CO{sub 2}, OCS, SO{sub 2}, SO{sub 3} and H{sub 2}SO{sub 4}. • Y{sub CO{sub 2}} and Y{sub CO} increase, Y{sub SO{sub 3+H{sub 2SO{sub 4}}}} remains constant, and Y{sub SO{sub 2}} and Y{sub OCS} follow bell curves as SIE increases. -- Abstract: Carbon disulfide (CS{sub 2}), a typical odorous organic sulfur compound, has adverse effects on human health and is a potential threat to the environment. In the present study, CS{sub 2} conversion in air by non-thermal plasma (NTP) was systematically investigated using a link tooth wheel-cylinder plasma reactor energized by a DC power supply. The results show that corona discharge is effective in removing CS{sub 2}. The CS{sub 2} conversion increases with the increase of specific input energy (SIE). Both short-living (e.g. ·O, ·OH radicals) and long-living species contribute to the CS{sub 2} conversion, but the short-living species play a more important role. Both gaseous and solid products are formed during the conversion of CS{sub 2}. Gaseous products mainly include CO, CO{sub 2}, OCS, SO{sub 2}, SO{sub 3} and H{sub 2}SO{sub 4}. The yields of CO and CO{sub 2} increase, the yields of OCS and SO{sub 2} follow bell curves while the sum yield of SO{sub 3} and H{sub 2}SO{sub 4} remains constant as SIE increases. The solid products, consisting of CO{sub 3}{sup 2−}, SO{sub 4}{sup 2−} and possible polymeric sulfur, deposit on the inner wall and electrodes of the plasma reactor.

  9. Synthesis of Magnesium Oxide Nanopowder by Thermal Plasma Using Magnesium Nitrate Hexahydrate

    Directory of Open Access Journals (Sweden)

    V. Sirota

    2016-01-01

    Full Text Available Magnesium oxide (MgO nanopowder was synthesized by thermal plasma in a novel thermal DC plasma torch using magnesium nitrate hexahydrate. Magnesium nitrate hexahydrate (Mg(NO32·6H2O was obtained from serpentinite (Mg3Si2O5(OH4; lizardite (Halilovskiy array, Orenburg region, Russia. The synthesized samples were characterized by analytical techniques including X-ray diffraction (XRD and transmission electron microscopy (TEM. XRD and TEM characterization studies confirmed that MgO nanopowder obtained has periclase structure with high purity, and the particle sizes vary within the range of 100 nm to 150 nm. We believe that the present work will promote further experimental studies on the physical properties and the applications of MgO nanopowders in the fields such as high-densed ceramics, additives in bactericide, and refractory products.

  10. Drift Mode Growth Rate and Associated Ion Thermal Transport in Reversed Magnetic Shear Tokamak Plasma

    Institute of Scientific and Technical Information of China (English)

    WANG Ai-Ke; QIU Xiao-Ming

    2001-01-01

    Drift mode linear growth rate and quasi-linear ion thermal transport in the reversed magnetic shear plasma are investigated by using the two-fluid theory, previously developed by Weiland and the Chalmers group [J. Nucl.Fusion, 29 (1989) 1810; ibid. 30 (1990) 983]. The theory is here extended to include both the radial electrical field shear (dEr/dr) and the electron fluid velocity (Ve) in the sheared coordinate system. Here, Ve describes the coupling between the safety factor q and the Er × B velocity V E. Their influences on the growth rate and associated ion thermal transport are obtained numerically. In addition, the ion heat pinch in the reversed shear plasma is observed. Qualitatively, the present conclusions are in good agreement with the experimental results.

  11. Plasma-thermal electric furnace for gasification of carbon-containing waste

    Directory of Open Access Journals (Sweden)

    Anshakov A.S.

    2017-01-01

    Full Text Available The plasma-thermal electric furnace for gasification of various carbonaceous wastes (domestic, biological, agricultural, and other organic waste has been created for the first time. Its constituent parts are: hydraulic drive for supplying the packed waste into the reaction zone; gas burner with the thermal power of 42 kW; electric-arc plasmatron with a power of 50 kW; chamber for ash residue melting. The test operation of the electric furnace showed that plasma gasification of carbon-containing materials produces synthesis gas suitable for the needs of heat and electric power industry. The results of thermodynamic calculations are in satisfactory agreement with the experimental data.

  12. Comparative Study of Decomposition of CCl4 in Different Atmosphere Thermal Plasmas

    Institute of Scientific and Technical Information of China (English)

    HUANG Jianjun; GUO Wenkang; XU Ping

    2007-01-01

    Decomposition of carbon tetrachloride was studied theoretically in the most commonly used thermal plasma atmosphere such as H2, N2, O2 and water steam. A code developed by the National Aeronautics and Space Administration (NASA) was adopted to calculate the chemical equilibrium distribution and energy consumption of the decomposition of CCl4 in the H2, N2, O2 and water steam atmosphere thermal plasma respectively, with a temperature range of 500 K to 5000 K. In the neutral condition (H2, N2, atmosphere) formation of solid carbon was observed and in the oxygen-atmosphere (O2 and water steam) solid carbon formation disappeared through controlling the ratio of C/O. This indicates that the formation of polycyclic aromatic hydrocarbons (PAHs) is impossible theoretically. The energy consumption in the N2 atmosphere was much higher than that in the H2, O2 and water steam atmosphere at 1500 K.

  13. Production of coloured glass-ceramics from incinerator ash using thermal plasma technology.

    Science.gov (United States)

    Cheng, T W; Huang, M Z; Tzeng, C C; Cheng, K B; Ueng, T H

    2007-08-01

    Incineration is a major treatment process for municipal solid waste in Taiwan. It is estimated that over 1.5 Mt of incinerator ash are produced annually. This study proposes using thermal plasma technology to treat incinerator ash. Sintered glass-ceramics were produced using quenched vitrified slag with colouring agents added. The experimental results showed that the major crystalline phases developed in the sintered glass-ceramics were gehlenite and wollastonite, but many other secondary phases also appeared depending on the colouring agents added. The physical/mechanical properties, chemical resistance and toxicity characteristic leaching procedure of the coloured glass-ceramics were satisfactory. The glass-ceramic products obtained from incinerator ash treated with thermal plasma technology have great potential for building applications.

  14. Propinquity of current and vortex structures: effects on collisionless plasma heating

    CERN Document Server

    Parashar, Tulasi N

    2016-01-01

    Intermittency of heating in weakly collisional plasma turbulence is an active subject of research, with significant potential impact on understanding of the solar wind, solar corona and astrophysical plasmas. Recent studies suggest a role of vorticity in plasma heating. In magnetohydrodynamics small scale vorticity is generated near current sheets and this effect persists in kinetic plasma, as demonstrated here with hybrid and fully kinetic Particle-In-Cell (PIC) simulations. Furthermore, vorticity enhances local kinetic effects, with a generalized resonance condition selecting sign-dependent enhancements or reductions of proton heating and thermal anisotropy. In such plasmas heating is correlated with vorticity and current density, but more strongly with vorticity. These results help explain several prior results that find kinetic effects and energization near to, but not centered on, current sheets. Evidently intermittency in kinetic plasma involves multiple physical quantities, and the associated coherent ...

  15. Unfiltered Diesel Engine Exhaust Treatment by Discharge Plasma:Effect of Soot Oxidation

    Institute of Scientific and Technical Information of China (English)

    B. S. Rajanikanth; Subhankar Das; A. D. Srinivasan

    2004-01-01

    A cascaded system of electrical discharges (Non-thermal plasma), catalyst and adsorption process was investigated for the removal of oxides of nitrogen (NO x) and carbon monoxide (CO) from a Diesel engine raw exhaust. The three processes were separately studied first, and then the cascaded processes, namely plasma-catalyst and plasma-adsorbent, were investigated. In this paper main emphasis was laid on the effect of carbonaceous soot oxidation on the plasma treatment process. While the cascaded plasma-catalyst process exhibits a higher CO removal, the cascaded plasma-adsorbent process exhibits a higher NO x removal. The experiments were conducted under no-load. The plasma and adsorbent reactors were kept at room temperature throughout the experiment while the catalyst reactor was kept at 200oC / 300oC.

  16. Magnetohydrodynamic-Particle-in-Cell Method for Coupling Cosmic Rays with a Thermal Plasma: Application to Non-relativistic Shocks

    CERN Document Server

    Bai, Xue-Ning; Sironi, Lorenzo; Spitkovsky, Anatoly

    2014-01-01

    We formulate a magnetohydrodynamic-particle-in-cell (MHD-PIC) method for describing the interaction between collisionless cosmic ray (CR) particles and a thermal plasma. The thermal plasma is treated as a fluid, obeying equations of ideal MHD, while CRs are treated as relativistic Lagrangian particles subject to the Lorentz force. Backreaction from CRs to the gas is included in the form of momentum and energy feedback. In addition, we include the electromagnetic feedback due to CR-induced Hall effect that becomes important when the electron-ion drift velocity of the background plasma induced by CRs approaches the Alfv\\'en velocity. Our method is applicable on scales much larger than the ion inertial length, bypassing the microscopic scales that must be resolved in conventional PIC methods, while retaining the full kinetic nature of the CRs. We have implemented and tested this method in the Athena MHD code, where the overall scheme is second-order accurate and fully conservative. As a first application, we des...

  17. Non-thermal plasma based technologies for the after-treatment of automotive exhaust particulates and marine diesel exhaust NOx

    Energy Technology Data Exchange (ETDEWEB)

    McAdams, R; Beech, P; Gillespie, R; Guy, C; Jones,S; Liddell, T; Morgan, R; Shawcross, J; Weeks, D; Hughes, D; Oesterle, J; Eberspdcher,

    2003-08-24

    The trend in environmental legislation is such that primary engine modifications will not be sufficient to meet all future emissions requirements and exhaust aftertreatment technologies will need to be employed. One potential solution that is well placed to meet those requirements is non-thermal plasma technology. This paper will describe our work with some of our partners in the development of a plasma based diesel particulate filter (DPF) and plasma assisted catalytic reduction (PACR) for NOx removal. This paper describes the development of non-thermal plasma technology for the aftertreatment of particulates from a passenger car engine and NOx from a marine diesel exhaust application.

  18. Effects of magnetic fields on the quark–gluon plasma

    Energy Technology Data Exchange (ETDEWEB)

    Bali, G.S. [Institute for Theoretical Physics, Universität Regensburg, D-93040 Regensburg (Germany); Tata Institute of Fundamental Research, Homi Bhabha Road, Mumbai 400005 (India); Bruckmann, F. [Institute for Theoretical Physics, Universität Regensburg, D-93040 Regensburg (Germany); Endrődi, G., E-mail: gergely.endrodi@physik.uni-r.de [Institute for Theoretical Physics, Universität Regensburg, D-93040 Regensburg (Germany); Fodor, Z. [Eötvös University, Theoretical Physics, Pázmány P. s 1/A, H-1117, Budapest (Hungary); Bergische Universität Wuppertal, Theoretical Physics, 42119 Wuppertal (Germany); Jülich Supercomputing Centre, Forschungszentrum Jülich, D-52425 Jülich (Germany); Katz, S.D. [Eötvös University, Theoretical Physics, Pázmány P. s 1/A, H-1117, Budapest (Hungary); MTA-ELTE Lendület Lattice Gauge Theory Research Group (Hungary); Schäfer, A. [Institute for Theoretical Physics, Universität Regensburg, D-93040 Regensburg (Germany)

    2014-11-15

    In this talk, the response of the thermal QCD medium to external (electro)magnetic fields is studied using continuum extrapolated lattice results at physical quark masses. The magnetic susceptibility of QCD is calculated, revealing a strong paramagnetic response at high temperatures. This paramagnetism is shown to result in an anisotropic squeezing of the quark–gluon plasma in non-central heavy-ion collisions, implying a sizeable contribution to the elliptic flow. Another aspect is the magnetic response of topologically non-trivial domains to the magnetic field. We quantify this effect on the lattice and compare the results to a simple model estimate.

  19. Evaluation of Residence Time on Nitrogen Oxides Removal in Non-Thermal Plasma Reactor

    OpenAIRE

    2015-01-01

    Non-thermal plasma (NTP) has been introduced over the last few years as a promising after- treatment system for nitrogen oxides and particulate matter removal from diesel exhaust. NTP technology has not been commercialised as yet, due to its high rate of energy consumption. Therefore, it is important to seek out new methods to improve NTP performance. Residence time is a crucial parameter in engine\\ud exhaust emissions treatment. In this paper, different electrode shapes are analysed and the ...

  20. Direct Synthesis of Porous Multilayer Graphene Materials Using Thermal Plasma at Low Pressure

    Directory of Open Access Journals (Sweden)

    Ravil Amirov

    2015-01-01

    Full Text Available Porous multilayer graphenes have been synthesized by decomposition of hydrocarbons in a thermal plasma jet. Products of synthesis were characterized by electron microscopy, thermogravimetry, Raman spectroscopy, and X-ray diffraction. Possibility of producing a wide range of graphene materials with different morphology and structure has been shown. Influence of the experimental conditions on mesopores structure of the synthesis products has been investigated using the method of “limited evaporation.”

  1. Thermal distortion and birefringence in repetition-rate plasma electrode Pockels cell for high average power

    Institute of Scientific and Technical Information of China (English)

    Dingxiang Cao; Xiongjun Zhang; Wanguo Zheng; Shaobo He; Zhan Sui

    2007-01-01

    We numerically study thermally induced birefringence and distortion in plasma electrode Pockels cell based on KD*P as the electro-optic material. This device can repetitively operate under the heat capacity mode.Simulation results indicate that the excellent switching performances and low wave-front distortion are achieved within several tens seconds working time at average power in excess of 1 kW.

  2. Analysis of the step responses of laminar premixed flames to forcing by non-thermal plasma

    KAUST Repository

    Lacoste, Deanna A.

    2016-07-16

    The step responses of lean methane-air flames to non-thermal plasma forcing is reported. The experimental setup consists of an axisymmetric burner, with a nozzle made of a quartz tube. The equivalence ratio is 0.95, allowing stabilization of the flame in a V-shape or an M-shape geometry, over a central stainless steel rod. The plasma is produced by short pulses of 10-ns duration, 8-kV maximum voltage amplitude, applied at 10 kHz. The central rod is used as a cathode, while the anode is a stainless steel ring, fixed on the outer surface of the quartz tube. Plasma forcing is produced by positive or negative steps of plasma. The step response of the flame is investigated through heat release rate (HRR) fluctuations, to facilitate comparisons with flame response to acoustic perturbations. The chemiluminescence of CH* between two consecutive pulses was recorded using an intensified camera equipped with an optical filter to estimate the HRR fluctuations. First, the results show that the flame does not respond to each single plasma pulse, but is affected only by the average plasma power, confirming the step nature of the forcing. The temporal evolutions of HRR are analyzed and the flame transfer functions are determined. A forcing mechanism, as a local increase in the reactivity of the fluid close to the rod, is proposed and compared with numerical simulations. Experiments and numerical simulations are in good qualitative agreement. © 2016.

  3. Thermal shock behaviour of blisters on W surface during combined steady-state/pulsed plasma loading

    Science.gov (United States)

    Jia, Y. Z.; Liu, W.; Xu, B.; Luo, G.-N.; Li, C.; Qu, S. L.; Morgan, T. W.; De Temmerman, G.

    2015-09-01

    The thermal shock behaviour of blister-covered W surfaces during combined steady-state/pulsed plasma loading was studied by scanning electron microscopy and electron backscatter diffraction. The W samples were first exposed to steady-state D plasma to induce blisters on the surface, and then the blistered surfaces were exposed to steady-state/pulsed plasma. Growth and cracking of blisters were observed after the exposure to the steady-state/pulsed plasma, while no obvious damage occurred on the surface area not covered with blisters. The results confirm that blisters induced by D plasma might represent weak spots on the W surface when exposed to transient heat load of ELMs. The cracks on blisters were different from the cracks due to the transient heat loads reported before, and they were assumed to be caused by stress and strain due to the gas expansion inside the blisters during the plasma pulses. Moreover, most of cracks were found to appear on the blisters formed on grains with surface orientation near [1 1 1].

  4. Thermal Structure and Dynamics in Supra-arcade Downflows and Flare Plasma Sheets

    Science.gov (United States)

    Reeves, K.; Hanneman, W.; Freed, M.; McKenzie, D. E.

    2014-12-01

    During a long duration solar flare, a hot plasma sheet is commonly formed above the flare loops. Often produced within this sheet are down-flowing voids referred to as supra-arcade downflows, thought to be the products of a patchy reconnection process. Models differ on the question of whether the downflows should be hotter than the surrounding plasma or not. We use imaging data from Hinode/XRT and SDO/AIA to determine the thermal structure of the plasma sheet and downflows. We find that the temperatures of the plasma within the downflows are either roughly the same as or lower than the surrounding fan plasma. This result implies that a mechanism for forming the voids that involves a sunward directed hydrodynamic shock pattern combined with perpendicular magnetic shock is unlikely. Additionally, we use the high cadence AIA data to trace the velocity fields in these regions through the use of a local correlation tracking algorithm. Through these measurements, we can determine areas of diverging velocity fields, as well as velocity shear fields and correlate them with temperature changes in order to understand the heating mechanisms in the plasma sheet. This work is supported by under contract SP02H1701R from Lockheed-Martin to SAO, contract NNM07AB07C from NASA to SAO and NASA grant numbers NNX13AG54G and NNX14AD43G

  5. Advanced WC-Co cermet composites with reinforcement of TiCN prepared by extended thermal plasma route

    Energy Technology Data Exchange (ETDEWEB)

    Mondal, B. [Centre for Advanced Materials Processing, Central Mechanical Engineering Research Institute, Mahatma Gandhi Avenue, Durgapur 713 209, West Bengal (India)], E-mail: bnmondal@rediffmail.com; Das, P.K. [Central Glass and Ceramic Research Institute, Kolkata (India); Singh, S.K. [Institute of Minerals and Materials Technology (IIMT), Bhubeneswar (India)

    2008-12-20

    The synthesis of titanium carbonitride (TiCN) powders by thermal plasma using extended arc thermal plasma reactor and the effect of TiCN reinforcement for the development of advanced WC-Co cermets has been studied with respect to hardness and fracture toughness. These classes of materials are being investigated for future application in wear-resistant seals, cutting tools, etc. Metallurgical reactions and microstructural developments during sintering of cermets and functionally graded cemented carbonitrides are being investigated by analytical methods such as differential thermal analysis/thermo-gravimetric analysis, X-ray diffraction and analytical Scanning electron microscopy with energy dispersive X-ray spectroscopy. By an in-depth understanding of the complex phase reactions and the mechanisms that govern the sintering process and metallurgical reactions, new cermets and different types of functionally graded cemented carbonitrides with desired microstructures and properties have been attempted to develop. The significant improvement of micro-hardness was observed with optimal concentration of TiCN reinforcement addition in WC-Co system without sacrificing much fracture toughness value of the composite cermets.

  6. A novel approach to the pacemaker infection with non-thermal atmospheric pressure plasma

    Science.gov (United States)

    Zhang, Yuchen; Li, Yu; Li, Yinglong; Yu, Shuang; Li, Haiyan; Zhang, Jue

    2017-08-01

    Although the pacemaker (PM) is a key cardiac implantable electrical device for life-threatening arrhythmias treatment, the related infection is a challenge. Thus, the aim of this study is to validate cold plasma as a potential technology for the disinfection of infected pacemakers. Fifty donated PMs were cleaned and sterilized before use and then infected with Staphylococcus aureus ( S. aureus). Then, each experimental group was treated with cold plasma treatment for 1 min, 3 min, 5 min and 7 min, while the control group was immersed with sterilized water. Effectiveness of disinfection was evaluated by using CFU counting method and confocal laser scanning microscopy (CLSM). The physicochemical properties of water treated with cold plasma at different time were evaluated, including water temperature change and oxidation reduction potential (ORP). The major reactive species generated by the cold plasma equipment during cold plasma were analyzed with optical emission spectroscopy (OES). No live bacteria were detected with CFU counting method after 7 min of cold plasma treatment, which matches with the CLSM results. The ORP value of water and H2O2 concentration changed significantly after treating with cold plasma. Furthermore, reactive oxygen species (ROS) and reactive nitrogen species (RNS), especially NO, O (777 nm) and O (844 nm) were probably key inactivation agents in cold plasma treatment. These results indicate that cold plasma could be an effective technology for the disinfection of implantable devices.

  7. Synthesis of ZnO nanopowders by DC thermal plasma for dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Soo-Jung; Choi, Jinsub [Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Dong-Wha, E-mail: dwpark@inha.ac.kr [Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751 (Korea, Republic of)

    2013-05-01

    Highlights: ► ZnO nanopowders were synthesized using DC thermal plasma process. ► Type and flow rate of reaction gas were controlled as experimental variables. ► Various morphologies were identified by changing the reaction gas. ► The photovoltaic performances were promoted by removing the unreacted precursors. ► DSSCs based on 1D nanostructure ZnO show the enhanced energy conversion efficiency. -- Abstract: Zinc oxide (ZnO) nanopowders were synthesized from commercially available micro-sized zinc powders (Aldrich Co., 98%, 10 μm) by a DC thermal plasma process at atmospheric pressure. The micro-sized zinc powders were vaporized in the plasma region, after which the plasma processing equipment was rapidly quenched, resulting in the formation of ZnO nanopowders with a size of less than 300 nm. Two different reaction gases of oxygen and carbon dioxide were used as the oxygen source and each gas flow rate was controlled as a process variable. The obtained ZnO nanopowders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). All synthesized ZnO nanopowders showed high crystalline wurtzite structures and the differences in their morphologies were strongly dependent on the operating variables. The photocurrent–voltage (J–V) curve of the ZnO nanopowders with a dye of ruthenium (II) 535 bis-TBA (N719, Solaronix) in redox electrolyte showed an overall energy conversion efficiency (η) of 2.54%, demonstrating that the application of the mass-producible ZnO nanopowders by thermal plasma processing to DSSC was feasible.

  8. Effect of plasma processing reactor circuitry on plasma characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Rauf, S.; Kushner, M.J. [Univ. of Illinois, Urbana, IL (United States). Dept. of Electrical and Computer Engineering

    1997-12-31

    It is well known that external circuitry greatly influences the performance of plasma processing reactors. Simulation of external circuits difficult since the time in which the external circuit attains the steady-state is several orders of magnitude longer than typical plasma simulation time scales. In this paper, the authors present a technique to simulate the external circuit concurrently with the plasma, and implement it into the Hybrid Plasma Equipment Model (HPEM). The resulting model is used to investigate the influence of external circuitry on plasma behavior.

  9. Enhancement of Limb Growth by Non-Thermal Plasma Generated Reactive Species

    Science.gov (United States)

    Shainsky, N.; Steinbeck, M.; Fridman, G.; Fridman, A.; Friedman, G.; Freeman, T.

    2013-09-01

    Introduction: The goal of this investigation was to examine the effect of Dielectric Barrier Discharge plasma on mouse autopod differentiation and growth. In this study we hypothesized that NT-plasma can be used to promote redox dependent changes in differentiation pathways and enhance developmental signaling? Methods: Approximately 1 hour after isolation, NT-plasma or sham plasma treatment was applied to the right or left limb, respectively. The medium was changed daily thereafter for the 4-6 days of culture. NT-plasma treatment: pulsed (1000 Hz) voltage of 17 - 25 kV magnitude (peak to peak), a 1 μs pulse width and a rise time of 5 V/ns between the quartz-insulated high voltage electrode and the sample undergoing treatment. Results: A single 10 second NT-plasma treatment promoted development of mouse autopods as compared to the sham control contralateral limb. NT-plasma accelerated digit growth in both E14.5 and E12.5 autopods. Inhibitors were used to determine the role of ROS and RNS in mediating NT-plasma accelerated autopod development. Treatment with these agents stunted autopod morphogenesis NT-plasma treatment partially rescued development. Discussion: Our findings highlight the capability of NT-plasma to activate ROS-dependent cell signaling cascades within developing autopod tissue. In fact, the effect of NT-plasma may indeed extend beyond ROS sensitive signaling as NT-plasma exposure seems to stimulate some growth even in the presence of antioxidant induced stunting. This work was supported by NIH Grants 1 R01 EB 013011 - 01 (Freeman and G. Fridman).

  10. Residual stress analysis of the thermal barrier coating system by considering the plasma spraying process

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Myung Jae; Lee, Byung Chai [KAIST, Daejeon (Korea, Republic of); Lim, Jang Gyun; Kim, Moon Ki [Sungkyunkwan University, Suwon (Korea, Republic of)

    2014-06-15

    The residual stress is the key factor causing the reliability problem of thermal barrier coating (TBC). The failure of plasma spray coatings due to residual stresses is a serious and recurring problem of TBC. The difference of thermal expansion coefficient between the substrate and each coating combined with temperature evolution and temperature gradients during deposition process determine the residual stress for the whole TBC system. The magnitudes and distributions of the residual stresses are affected by deposition process and deposition characteristics. Most of FEA (finite element analysis) has been performed under the assumption that the multilayer coating system is stacked at once without considering the deposition process during plasma spraying. In this research, FEA for a coupled heat transfer and elastic-plastic thermal stress was performed to obtain the more detailed and reliable result of residual stress of the TBC system using the element activation/deactivation technique. The residual stress variation from the start of plasma spraying to cooling stage with room temperature was obtained systematically considering the deposition process. It can be used as reference data to improve the performance of TBC. In addition, the relationship between residual stress and coating conditions such as cooling rate and time is also examined thoroughly.

  11. Thermal Barrier Coatings Made by the Solution Precursor Plasma Spray Process

    Science.gov (United States)

    Gell, Maurice; Jordan, Eric H.; Teicholz, Matthew; Cetegen, Baki M.; Padture, Nitin P.; Xie, Liangde; Chen, Dianying; Ma, Xinqing; Roth, Jeffrey

    2008-03-01

    The solution precursor plasma spray (SPPS) process is a relatively new and flexible thermal spray process that can produce a wide variety of novel materials, including some with superior properties. The SPPS process involves injecting atomized droplets of a precursor solution into the plasma. The properties of resultant deposits depend on the time-temperature history of the droplets in the plasma, ranging from ultra-fine splats to unmelted crystalline particles to unpyrolized particles. By controlling the volume fraction of these three different constituents, a variety of coatings can be produced, all with a nanograin size. In this article, we will be reviewing research related to thermal barrier coatings, emphasizing the processing conditions necessary to obtain a range of microstructures and associated properties. The SPPS process produces a unique strain-tolerant, low-thermal conductivity microstructure consisting of (i) three-dimensional micrometer and nanometer pores, (ii) through-coating thickness (vertical) cracks, (iii) ultra-fine splats, and (iv) inter-pass boundaries. Both thin (0.12 mm) and thick (4 mm) coatings have been fabricated. The volume fraction of porosity can be varied from 10% to 40% while retaining the characteristic microstructure of vertical cracks and ultra-fine splats. The mechanism of vertical crack formation will be described.

  12. Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air%Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air

    Institute of Scientific and Technical Information of China (English)

    杨国清; 张冠军; 张文元

    2011-01-01

    Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectric barrier discharge generator in atmospheric air. The electrical parameters including discharging power, peak and density of micro-discharge current were calculated, and the electron energy was estimated. Surface treatment experiments of polytetrafluoroethylene films were conducted for both different applied voltages and different treating durations. Results show that the surface energy of polytetrafluoroethylene film could be improved to 40 mJ/m2 or more by plasma treatment. Surface roughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that there are chemical etching and implantation of polar oxygen groups in the sample surface treating process, resulting in the improvement of the sample surface energy. Compared with an AC source of 50 Hz, the dielectric barrier discharges generated by a repetitive pulsed source could provide higher peak power, lower mean power, larger micro-discharge current density and higher electron energy. Therefore, with the same applied peak voltage and treating duration, the improvement of polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective, and the plasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thus feasible and applicable.

  13. Thermal plasma processed ferro-magnetically ordered face-centered cubic iron at room temperature

    Science.gov (United States)

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Das, A. K.; Mathe, V. L.

    2014-10-01

    Here, we report tailor made phase of iron nanoparticles using homogeneous gas phase condensation process via thermal plasma route. It was observed that crystal lattice of nano-crystalline iron changes as a function of operating parameters of the plasma reactor. In the present investigation iron nanoparticles have been synthesized in presence of argon at operating pressures of 125-1000 Torr and fixed plasma input DC power of 6 kW. It was possible to obtain pure fcc, pure bcc as well as the mixed phases for iron nanoparticles in powder form as a function of operating pressure. The as synthesized product was characterized for understanding the structural and magnetic properties by using X-ray diffraction, vibrating sample magnetometer, and Mössbauer spectroscopy. The data reveal that fcc phase is ferromagnetically ordered with high spin state, which is unusual whereas bcc phase is found to be ferromagnetic as usual. Finally, the structural and magnetic properties are co-related.

  14. Prediction of the cathodic arc root behaviour in a hollow cathode thermal plasma torch

    Energy Technology Data Exchange (ETDEWEB)

    Freton, Pierre; Gonzalez, Jean-Jacques; Escalier, Gaelle, E-mail: pierre.freton@laplace.univ-tlse.f [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d' Energie), 118 route de Narbonne, F-31062 Toulouse cedex 9 (France)

    2009-10-07

    The upper part of a well type cathode (WTC) plasma torch is modelled for several conditions in an air medium in the presence of an electric arc. The plasma flow created by the electric arc is described and the results compared with the data from the literature. Special attention is paid to the description of arc root attachment and to its movement due to the balance of forces. A fine description of the magnetic field produced by the external solenoid is reported. The model is based on the Fluent software implemented with specific developments to be adapted to the thermal plasma domain. The paper shows the necessity to provide an accurate description of the external magnetic field due to the strong influence of the radial magnetic field component. Overall, we propose an original approach for arc root movement description which contributes to the understanding of the flow behaviour in the WTC torch.

  15. Finite Element Simulation Code for Computing Thermal Radiation from a Plasma

    Science.gov (United States)

    Nguyen, C. N.; Rappaport, H. L.

    2004-11-01

    A finite element code, ``THERMRAD,'' for computing thermal radiation from a plasma is under development. Radiation from plasma test particles is found in cylindrical geometry. Although the plasma equilibrium is assumed axisymmetric individual test particle excitation produces a non-axisymmetric electromagnetic response. Specially designed Whitney class basis functions are to be used to allow the solution to be solved on a two-dimensional grid. The basis functions enforce both a vanishing of the divergence of the electric field within grid elements where the complex index of refraction is assumed constant and continuity of tangential electric field across grid elements while allowing the normal component of the electric field to be discontinuous. An appropriate variational principle which incorporates the Sommerfeld radiation condition on the simulation boundary, as well as its discretization by the Rayleigh-Ritz technique is given. 1. ``Finte Element Method for Electromagnetics Problems,'' Volakis et al., Wiley, 1998.

  16. Calculation of transport coefficients of air-water vapor mixtures thermal plasmas used in circuit breakers

    Directory of Open Access Journals (Sweden)

    KOHIO Niéssan

    2014-12-01

    Full Text Available In this paper we calculate the transport coefficients of plasmas formed by air and water vapor mixtures. The calculation, which assume local thermodynamic equilibrium (LTE are performed in the temperature range from 500 to 12000 K. We use the Gibbs free energy minimization method to determine the equilibrium composition of the plasmas, which is necessary to calculate the transport coefficients. We use the Chapman-Enskog method to calculate the transport coefficients. The results are presented and discussed according to the rate of water vapor. The results of the total thermal conductivity and electrical conductivity show in particular that the increasing of the rate of water vapor in air can be interesting for power cut. This could be improve the performance of plasma during current breaking in air contaminate by the water vapor.

  17. Degradation of pharmaceutical compounds in water by non-thermal plasma treatment.

    Science.gov (United States)

    Magureanu, Monica; Mandache, Nicolae Bogdan; Parvulescu, Vasile I

    2015-09-15

    Pharmaceutical compounds became an important class of water pollutants due to their increasing consumption over the last years, as well as due to their persistence in the environment. Since conventional waste water treatment plants are unable to remove certain non-biodegradable pharmaceuticals, advanced oxidation processes was extensively studied for this purpose. Among them, non-thermal plasma was also recently investigated and promising results were obtained. This work reviews the recent research on the oxidative degradation of pharmaceuticals using non-thermal plasma in contact with liquid. As target compounds, several drugs belonging to different therapeutic groups were selected: antibiotics, anticonvulsants, anxiolytics, lipid regulators, vasodilatators, contrast media, antihypertensives and analgesics. It was found that these compounds were removed from water relatively fast, partly degraded, and partly even mineralized. In order to ensure the effluent is environmentally safe it is important to identify the degradation intermediates and to follow their evolution during treatment, which requires complex chemical analysis of the solutions. Based on this analysis, degradation pathways of the investigated pharmaceuticals under plasma conditions were suggested. After sufficient plasma treatment the final organic by-products present in the solutions were mainly small molecules in an advanced oxidation state. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Seasonal and radial trends in Saturn's thermal plasma between the main rings and enceladus

    CERN Document Server

    Elrod, Meredith K; Woodson, Adam K; Johnson, Robert E

    2013-01-01

    A goal of Cassini's extended mission has been to examine the seasonal variations of Saturn's magnetosphere, moons, and rings. Recently we showed that the magnetospheric plasma between the main rings and Enceladus exhibited a time dependence that we attributed to a seasonally variable source of oxygen from the main rings (Elrod et al., 2012). Such a temporal variation was subsequently seen in the energetic ion composition (Christon et al., 2013). Here we include the most recent measurements by the Cassini Plasma Spectrometer (CAPS) in our analysis (Elrod et al., 2012) and modeling (Tseng et al., 2013a) of the temporal and radial dependence of the thermal plasma in the region between the main rings and the orbit of Enceladus. Data taken in 2012, well past equinox for which the northern side of the main rings were illuminated, appear consistent with a seasonal variation. Although the thermal plasma in this region comes from two sources, the extended ring atmosphere and the Enceladus torus that have very differen...

  19. Dynamical Screening Effect on $\\alpha$-$\\alpha$ Resonant Scattering and Thermal Nuclear Scattering Rate

    CERN Document Server

    Yao, Xiaojun; Müller, Berndt

    2016-01-01

    We study the dynamical screening effect in the QED plasma on the $\\alpha$-$\\alpha$ scattering at the $^8$Be resonance. Dynamical screening leads to an imaginary part of the potential which results in a thermal width for the resonance and dominates over the previously considered static screening effect. As a result, both the resonance energy and width increase with the plasma temperature. Furthermore, dynamical screening can have a huge impact on the $\\alpha$-$\\alpha$ thermal nuclear scattering rate. For example, when the temperature is around $10$ keV, the rate is suppressed by a factor of about $900$. We expect similar thermal suppressions of nuclear reaction rates to occur in nuclear reactions dominated by an above threshold resonance with a thermal energy. Dynamical screening effects on nuclear reactions can be relevant to cosmology and astrophysics.

  20. Are direct photons a clean signal of a thermalized quark gluon plasma?

    CERN Document Server

    Boyanovsky, D

    2003-01-01

    Direct photon production from a quark gluon plasma (QGP) in thermal equilibrium is studied directly in real time. In contrast to the usual S-matrix calculations, the real time approach is valid for a QGP that formed and reached LTE a short time after a collision and of finite lifetime ($\\sim 10-20 \\mathrm{fm}/c$ as expected at RHIC or LHC). We point out that during such finite QGP lifetime the spectrum of emitted photons carries information on the initial state. There is an inherent ambiguity in separating the virtual from the observable photons during the transient evolution of the QGP. We propose a real time formulation to extract the photon yield which includes the initial stage of formation of the QGP parametrized by an effective time scale of formation $\\Gamma^{-1}$. This formulation coincides with the S-matrix approach in the infinite lifetime limit. It allows to separate the virtual cloud as well as the observable photons emitted during the pre- equilibrium stage from the yield during the QGP lifetime....

  1. Experimental investigation of a non-thermal atmospheric pressure plasma jet

    Science.gov (United States)

    Begum, Asma

    The main objective of this dissertation is to understand the formation of the plasma jet from the plasma pencil, and the propagation of the plasma jet in the ambient atmosphere where the effect of the external electric field is almost zero. Before investigating the formation and propagation phenomenon of the plasma jet, common physical properties of plasma jets are determined by using the imaging technique and optical emission spectroscopy. The first goal of this dissertation is to establish the laminar helium gas flow channel through a plasma pencil. The formation position, formation time, and the criterion of the plasma jet formation from the discharge chamber of a plasma pencil are investigated by imaging technique, optical emission spectroscopy, and electrical measurement technique. It shows that the plasma jet forms at the surface of the grounded dielectric as a positive plasma front. The formation time of the plasma jet decreases with applied voltage. The maximum power, total power, and average energy to the system and to the discharge are calculated from the total current, discharge current, input potential, and gap potential of the plasma pencil. The calculated average input power with applied voltage to the discharge shows that 56% of the input power is used in the discharge. The total charge in the discharge chamber is calculated by integrating the discharge current waveform. The critical charge in the discharge chamber required to generate a plasma jet is also determined. The propagation phenomenon of the plasma bullet in the ambient atmosphere has been investigated from the velocity curves of the plasma bullet along the jet axis for different applied voltages, pulse widths, and feed gas flow rates. The plasma bullet's velocity is measured by using two different techniques: (i) imaging technique and (ii) electrical technique. In imaging technique, ultra-fast ICCD images of the plasma jet have been taken at different times and positions, and from the

  2. Nano-droplet ejection and nucleation of materials submitted to non-thermal plasma filaments

    Science.gov (United States)

    Borra, J.-P.; Jidenko, N.; Dutouquet, C.; Aguerre, O.; Hou, J.; Weber, A.

    2011-11-01

    Methods to induce non-thermal atmospheric pressure plasma filaments are presented with related properties for micro, streamer and prevented spark discharges, respectively, induced in planar Dielectric Barrier Discharges with one electrode covered by dielectric material (mono-DBD) or point-to-plane Corona. Two mechanisms of nano-particles formation are depicted from aerosol size distributions and TEM analysis. 0.1-10 mJ prevented spark discharges produce 10-100 nm droplets ejected from melted craters as well as nucleated primary particles and subsequent 10-100 nm agglomerates, by nucleation and coagulation in expanding vapor jets. With smaller energy per filament, 0.1-10 μJ micro-discharges and 0.1-100 μJ streamers, the initial local vapor fluxes emitted from spots of interaction between plasma filaments and electrodes are reduced. Subsequent smaller primary particle density limits the local coagulation in the vapor plume since 2-10 nm non-agglomerated crystalline metal nano-particles are produced in mono-DBD with Au, Ag and Cu electrode. Besides, the evolution of the aerosol size from primary nano-particles to agglomerates with transit time suggests slow coagulation of these primary metal particles in mono-DBD. Aerosol properties depend on the energy per filament and on the electrode. The final size is controlled by plasma parameters and transit time in and after the plasma. The aim is to underline emerging applications of atmospheric pressure plasmas for the production of tailored particles with tunable size, composition and structure with non-thermal plasma filaments to control the resulting properties of nano-powders and materials. Production rates and related energetic yields are compared.

  3. Disinfection of Streptococcus mutans biofilm by a non-thermal atmospheric plasma brush

    Science.gov (United States)

    Hong, Qing; Dong, Xiaoqing; Chen, Meng; Xu, Yuanxi; Sun, Hongmin; Hong, Liang; Wang, Yong; Yu, Qingsong

    2016-07-01

    This study investigated the argon plasma treatment effect on disinfecting dental biofilm by using an atmospheric pressure plasma brush. Streptococcus mutans biofilms were developed for 3 days on the surfaces of hydroxyapatite (HA) discs, which were used to simulate human tooth enamel. After plasma treatment, cell viability in the S. mutans biofilms was characterized by using 3-(4,5-dimethylazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) assay and confocal laser scanning microscopy (CLSM). Compared with the untreated control group, about 90% bacterial reduction in the biofilms was observed after 1 min plasma treatment. Scanning electron microscopy (SEM) examination indicated severe cell damages occurred on the top surface of the plasma treated biofilms. Confocal laser scanning microscopy (CLSM) showed that plasma treatment was effective as deep as 20 µm into the biofilms. When combined with antibiotic treatment using 0.2% chlorhexidine digluconate solution, the plasma treatment became more effective and over 96% bacterial reduction was observed with 1 min plasma treatment.

  4. Thermal Design of a Bitter-Type Electromagnet for Dusty Plasma Experiments: Prototype Design and Construction

    Science.gov (United States)

    Birmingham, W. J.; Bates, E. M.; Romero-Talamás, Carlos; Rivera, W. F.

    2015-11-01

    For the purpose of analyzing magnetized dusty plasma at the University of Maryland Baltimore County (UMBC) Dusty Plasma Laboratory, we are designing a resistive water cooled Bitter-Type electromagnet. When completed, the magnet will be programmable to generate fields of up to 10 T for at least 10 seconds and up to several minutes. An analytic thermal design method was developed for establishing the location of elongated axial cooling passages. Comparisons with finite element analysis (FEA) data reveals that the thermal design method was capable of generating cooling channel patterns which establish manageable temperature profiles within the magnet. With our analytic method, cooling hole patterns can be generated in seconds instead of hours with FEA software. To further validate our thermal analysis as well as manufacturing techniques of our magnet design, we are now constructing a prototype electromagnet. The prototype is designed to operate continuously at 1 T with a current of 750 A, and has four diagnostic ports that can accommodate thermocouples and optical access to the water flow. A 1.25 inch diameter bore allows for axial field measurements and provides space for small scale experiments. Thermal analysis and specifics of the electromagnet design are presented.

  5. Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying

    Energy Technology Data Exchange (ETDEWEB)

    Helminiak, M.A.; Yanar, N.M.; Pettit, F.S.; Meier, G.H. [National Energy Technology Laboratory, Pittsburgh, PA 15236 (United States); Department of Mechanical Engineering and Materials Science, University of Pittsburgh, 636 Benedum Hall, 3700 O& #x27; Hara Street, Pittsburgh, PA 15261 (United States); Taylor, T.A. [Praxair Surface Technologies, Inc., 1400 Polco Street, Indianapolis, IN 46224 (United States)

    2012-10-15

    The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  6. Performance Testing of Suspension Plasma Sprayed Thermal Barrier Coatings Produced with Varied Suspension Parameters

    Directory of Open Access Journals (Sweden)

    Nicholas Curry

    2015-07-01

    Full Text Available Suspension plasma spraying has become an emerging technology for the production of thermal barrier coatings for the gas turbine industry. Presently, though commercial systems for coating production are available, coatings remain in the development stage. Suitable suspension parameters for coating production remain an outstanding question and the influence of suspension properties on the final coatings is not well known. For this study, a number of suspensions were produced with varied solid loadings, powder size distributions and solvents. Suspensions were sprayed onto superalloy substrates coated with high velocity air fuel (HVAF -sprayed bond coats. Plasma spray parameters were selected to generate columnar structures based on previous experiments and were maintained at constant to discover the influence of the suspension behavior on coating microstructures. Testing of the produced thermal barrier coating (TBC systems has included thermal cyclic fatigue testing and thermal conductivity analysis. Pore size distribution has been characterized by mercury infiltration porosimetry. Results show a strong influence of suspension viscosity and surface tension on the microstructure of the produced coatings.

  7. Stress Analysis and Failure Mechanisms of Plasma-Sprayed Thermal Barrier Coatings

    Science.gov (United States)

    Yang, Jiasheng; Wang, Liang; Li, Dachuan; Zhong, Xinghua; Zhao, Huayu; Tao, Shunyan

    2017-06-01

    Yttria-stabilized zirconia coatings were deposited by plasma spraying and heat-treated at 1100 °C for 50, 100, 150, and 200 h in air, respectively. Mechanical properties including microhardness and Young's modulus were evaluated using the nanoindentation test. Residual stresses in the ceramic topcoat and the thermally grown oxide (TGO) layer were measured using Raman spectroscopy and photoluminescence piezo-spectroscopy (PLPS) techniques, respectively. The results showed that both the modulus and hardness increased with the thermal exposure time up to 100 h and then gradually decreased. The accumulated tensile stress in the as-sprayed topcoat changed to compressive stress after thermal exposure, and the compressive stress in the topcoat increased with an increase of thermal exposure time up to 150 h. The average compressive stresses in the TGO layer were higher than that of the cross-sectional topcoat, and the measured in-plane compressive stress increased firstly and then gradually decreased with increasing exposure time. The local interface geometry strongly affect the nature and evolution of hydrostatic stresses in the TGO. Finally, the crack initiation and propagation at the topcoat/TGO/bondcoat interface has been discussed with respect to the residual stresses in the plasma-sprayed TBC system.

  8. Pion interferometry at RHIC: porobing a thermalized quark-gluon plasma?

    Science.gov (United States)

    Soff, S; Bass, S A; Dumitru, A

    2001-04-30

    We calculate the Gaussian radius parameters of the pion-emitting source in high-energy heavy-ion collisions, assuming a first-order phase transition from a thermalized quark-gluon plasma (QGP) to a gas of hadrons. Such a model leads to a very long-lived dissipative hadronic rescattering phase which dominates the properties of the two-pion correlation functions. The radii are found to depend only weakly on the thermalization time tau(i), the critical temperature Tc (and thus the latent heat), and the specific entropy of the QGP. The model calculations suggest a rapid increase of R(out)/R(side) as a function of KT if a thermalized QGP were formed.

  9. A real-time lattice simulation of the thermalization of a gluon plasma: first results

    CERN Document Server

    Attems, Maximilian; Schäfer, Christian; Wagenbach, Björn; Zafeiropoulos, Savvas

    2016-01-01

    To achieve an understanding of the thermalization of a quark-gluon plasma, starting from QCD without using model assumptions, is a formidable task. We study the early stage dynamics of a relativistic heavy ion collision in the framework of real time simulations of classical Yang-Mills theory in a static box with the color glass condensate as initial condition. Our study generalizes a previous one by Fukushima and Gelis from SU(2) to the realistic case of SU(3). We calculate the chromo-electric and chromo-magnetic energy densities as well as the ratio of longitudinal and transverse pressure as a function of time as probes for thermalization. Our preliminary results on coarse lattices show the occurrence of Weibel instabilities prior to thermalization.

  10. Life Prediction of Atmospheric Plasma-Sprayed Thermal Barrier Coatings Using Temperature-Dependent Model Parameters

    Science.gov (United States)

    Zhang, B.; Chen, Kuiying; Baddour, N.; Patnaik, P. C.

    2017-06-01

    The failure analysis and life prediction of atmospheric plasma-sprayed thermal barrier coatings (APS-TBCs) were carried out for a thermal cyclic process. A residual stress model for the top coat of APS-TBC was proposed and then applied to life prediction. This residual stress model shows an inversion characteristic versus thickness of thermally grown oxide. The capability of the life model was demonstrated using temperature-dependent model parameters. Using existing life data, a comparison of fitting approaches of life model parameters was performed. A larger discrepancy was found for the life predicted using linearized fitting parameters versus temperature compared to those using non-linear fitting parameters. A method for integrating the residual stress was proposed by using the critical time of stress inversion. The role of the residual stresses distributed at each individual coating layer was explored and their interplay on the coating's delamination was analyzed.

  11. Effective Two-loop Thermodynamic Potential with Fermions in the real-time formalism of thermal field theory

    CERN Document Server

    Xin, W; Xin, Wang; Jiarong, Li

    2000-01-01

    Within the real-time formalism (RTF) of thermal field theory,we apply the hard thermal loop (HTL) resummation technique to calculating effective two-loop thermodynamic potential in quark-gluon plasma (QGP) and its renormalization. The result with collective effects is obtained, which is valid for an arbitrary number of quark flavors with masses.

  12. Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen

    Energy Technology Data Exchange (ETDEWEB)

    Marković, Marijana [Center of Chemistry, Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Studentski trg 12-16, 11000 Belgrade (Serbia); Jović, Milica; Stanković, Dalibor [Innovation Center, Faculty of Chemistry, University of Belgrade, P.O. Box 51, 11058 Belgrade 118 (Serbia); Kovačević, Vesna [Faculty of Physics, University of Belgrade, P.O. Box 44, 11000 Belgrade (Serbia); Roglić, Goran [Faculty of Chemistry, University of Belgrade, P.O. Box 51, 11058 Belgrade 118 (Serbia); Gojgić-Cvijović, Gordana [Center of Chemistry, Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Studentski trg 12-16, 11000 Belgrade (Serbia); Manojlović, Dragan, E-mail: manojlo@chem.bg.ac.rs [Faculty of Chemistry, University of Belgrade, P.O. Box 51, 11058 Belgrade 118 (Serbia)

    2015-02-01

    Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe{sup 2+}). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC–MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. - Highlights: • Twelve ibuprofen degradation products were identified in total. • The degradation percentage differed between treatments (DBD/Fe{sup 2+} was 99%). • In DBD/Fe{sup 2+} only aliphatic degradation products were identified. • V. fischeri was sensitive to ibuprofen solution after the Fenton treatment. • A. salina showed no toxic effect when exposed to all post treatment solutions.

  13. Analysis of the thermal response of plasma facing components during a runaway electron impact

    Science.gov (United States)

    Ward, Robert Cameron

    The generation of runaway electrons during a thermal plasma disruption is a concern for the safe and economical operation of a tokamak power system. Runaway electrons have high energy, 10--300 MeV, and may potentially cause extensive damage to plasma facing components through large temperature increases, melting of metallic components, surface erosion, and possible burnout of coolant tubes. The EPQ code system was developed to simulate the thermal response of plasma facing components to a runaway electron impact. The EPQ code system consists of several parts: UNIX scripts which control the operation of an electron-photon monte carlo code to calculate the interaction of the runaway electrons with the plasma facing materials; a finite difference code to calculate the thermal response, melting, and surface erosion of the materials using the modified heat conduction equation; a code to process, scale, transform, and convert the electron monte carlo data to volumetric heating rates for use in the thermal code; and several minor and auxiliary codes for the manipulation and post-processing of the data. The electron-photon monte carlo code used was the Electron-Gamma-Shower (EGS) code, developed and maintained by the National Research Center of Canada. The other codes were written in C++ for this study. The thermal code, called QTTN, solves the two-dimensional cylindrical modified heat conduction equation using the Quickest third-order accurate and stable explicit finite difference method and is capable of tracking melting or surface erosion. The EPQ code system was validated using a series of analytical solutions and simulations of experiments. QTTN and EPQ was verified and validated as able to calculate the temperature distribution, phase change, and surface erosion successfully. EPQ was then employed in a parametric study to simulate a typical runaway electron disruption impact on the FIRE design's plasma facing components. The results of the FIRE parametric study

  14. Influence of atomic kinetics in the simulation of plasma microscopic properties and thermal instabilities for radiative bow shock experiments

    Science.gov (United States)

    Espinosa, G.; Rodríguez, R.; Gil, J. M.; Suzuki-Vidal, F.; Lebedev, S. V.; Ciardi, A.; Rubiano, J. G.; Martel, P.

    2017-03-01

    Numerical simulations of laboratory astrophysics experiments on plasma flows require plasma microscopic properties that are obtained by means of an atomic kinetic model. This fact implies a careful choice of the most suitable model for the experiment under analysis. Otherwise, the calculations could lead to inaccurate results and inappropriate conclusions. First, a study of the validity of the local thermodynamic equilibrium in the calculation of the average ionization, mean radiative properties, and cooling times of argon plasmas in a range of plasma conditions of interest in laboratory astrophysics experiments on radiative shocks is performed in this work. In the second part, we have made an analysis of the influence of the atomic kinetic model used to calculate plasma microscopic properties of experiments carried out on magpie on radiative bow shocks propagating in argon. The models considered were developed assuming both local and nonlocal thermodynamic equilibrium and, for the latter situation, we have considered in the kinetic model different effects such as external radiation field and plasma mixture. The microscopic properties studied were the average ionization, the charge state distributions, the monochromatic opacities and emissivities, the Planck mean opacity, and the radiative power loss. The microscopic study was made as a postprocess of a radiative-hydrodynamic simulation of the experiment. We have also performed a theoretical analysis of the influence of these atomic kinetic models in the criteria for the onset possibility of thermal instabilities due to radiative cooling in those experiments in which small structures were experimentally observed in the bow shock that could be due to this kind of instability.

  15. The Technology of Non-thermal Plasma Assisted NH3-SCR Reduce Marine Diesel Emission and Aldehydes Byproducts Formation

    Directory of Open Access Journals (Sweden)

    Lei Jiang

    2013-12-01

    Full Text Available This study describes briefly various after-treatment technologies in marine diesel engines and application difficulties of DPF and SCR are included. An experiment has been conducted using non-thermal plasma generated by Dielectric Barrier Discharge (DBD process assisted NH3-SCR catalyst to reduce the nitrogen oxides (NOx from diesel engine exhaust. The formation mechanism of byproducts-type such as HCHO and CH3CHO in the non-thermal plasma assisted NH3-SCR hybrid system.

  16. Thermal barrier ZrO2 - Y2O3 obtained by plasma spraying method and laser melting

    OpenAIRE

    2006-01-01

    Purpose: The aim of the paper is to determine the influence of laser melting upon the selected physical properties of ZrO2 - Y2O3 ceramic coatings deposited by APS (Air Plasma Spraying) method on super-alloys which function as TBC (Thermal Barriers Coatings).Design/methodology/approach: Laser melting which helps eliminate pores and other structural defects of coatings deposited by plasma spraying method should contribute to the improvement of their density and durability as thermal barriers. ...

  17. Design and optimization of coating structure for the thermal barrier coatings fabricated by atmospheric plasma spraying via finite element method

    Directory of Open Access Journals (Sweden)

    L. Wang

    2014-06-01

    Full Text Available The first prerequisite for fabricating the thermal barrier coatings (TBCs with excellent performance is to find an optimized coating structure with high thermal insulation effect and low residual stress. This paper discusses the design and optimization of a suitable coating structure for the TBCs prepared by atmospheric plasma spraying (APS using the finite element method. The design and optimization processes comply with the rules step by step, as the structure develops from a simple to a complex one. The research results indicate that the suitable thicknesses of the bond-coating and top-coating are 60–120 μm and 300–420 μm, respectively, for the single ceramic layer YSZ/NiCoCrAlY APS-TBC. The embedded interlayer (50 wt.%YSZ + 50 wt.%NiCoCrAlY will further reduce the residual stress without sacrificing the thermal insulation effect. The double ceramic layer was further considered which was based on the single ceramic layer TBC. The embedded interlayer and the upper additional ceramic layer will have a best match between the low residual stress and high thermal insulation effect. Finally, the optimized coating structure was obtained, i.e., the La2Ce2O7(LC/YSZ/Interlayer/NiCoCrAlY coating structure with appropriate layer thickness is the best choice. The effective thermal conductivity of this optimized LC/YSZ/IL/BL TBC is 13.2% lower than that of the typical single ceramic layer YSZ/BL TBC.

  18. Autonomous Method and System for Minimizing the Magnitude of Plasma Discharge Current Oscillations in a Hall Effect Plasma Device

    Science.gov (United States)

    Hruby, Vladimir (Inventor); Demmons, Nathaniel (Inventor); Ehrbar, Eric (Inventor); Pote, Bruce (Inventor); Rosenblad, Nathan (Inventor)

    2014-01-01

    An autonomous method for minimizing the magnitude of plasma discharge current oscillations in a Hall effect plasma device includes iteratively measuring plasma discharge current oscillations of the plasma device and iteratively adjusting the magnet current delivered to the plasma device in response to measured plasma discharge current oscillations to reduce the magnitude of the plasma discharge current oscillations.

  19. Non-thermal plasma with 2-deoxy-D-glucose synergistically induces cell death by targeting glycolysis in blood cancer cells

    Science.gov (United States)

    Kaushik, Neha; Lee, Su Jae; Choi, Tae Gyu; Baik, Ku Youn; Uhm, Han Sup; Kim, Chung Hyeok; Kaushik, Nagendra Kumar; Choi, Eun Ha

    2015-03-01

    In this study, we show the selective and efficient anti-cancer effects of plasma (at a low dose) when cell metabolic modifiers are also included. 2-deoxy-D-glucose (2-DG), a glycolytic inhibitor, was used with effective doses of non-thermal plasma, synergistically attenuating cell metabolic viability and inducing caspase-dependent and independent cell death. The combination treatment decreased the intracellular ATP and lactate production in various types of blood cancer cells in vitro. Taken together, our findings suggest that 2-DG enhances the efficacy and selectivity of plasma and induces the synergistic inhibition of cancer cell growth by targeting glycolysis and apoptosis. Specifically, this treatment strategy demonstrated an enhanced growth inhibitory effect of plasma in the presence of a metabolic modifier that was selective against cancer cells, not non-malignant cells. This is the first study to report the advantage of combining plasma with 2-DG to eradicate blood cancer cells. Finally, we conclude that 2-DG with non-thermal plasma may be used as a combination treatment against blood cancer cells.

  20. Photon trapping effects in DEMO divertor plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hoshino, K.; Tokunaga, S.; Asakura, N. [Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Sawada, K.; Idei, R. [Faculty of Engineering, Shinshu Univ., Nagano (Japan); Shimizu, K. [Japan Atomic Energy Agency, Naka, Ibaraki (Japan); Ohno, N. [Graduate School of Engineering, Nagoya Univ, Aichi (Japan)

    2016-08-15

    In the DEMO divertor, the neutral density becomes high to produce the full detachment and therefore the photon trapping can become important. In this paper, effects of the photon trapping on the DEMO divertor plasma has been studied. The pre-evaluation of the photon trapping effects on the fixed background plasma profile was carried out by using an iterative self-consistent collisional radiative model. The recombining plasma near the inner target and the private region changed to the ionizing plasma by the photon-excitation. Based on the preevaluation result, the database of the effective ionization rate coefficient including the photon transport inside a 2 mm sphere. Advantage of the 2 mm sphere approximation is that the extra calculation cost is not necessary. Iterative calculation of the SONIC including the photon trapping effects was carried out. While the electron density increased and the neutral density decreased in the wide region, the electron density decreases close to the inner strike point. This may be due to decrease in the ionization rate by decrease in the neutral density. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Thermal Bridge Effects in Window Grooves

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report thermal bridge effects in window grooves are analyzed. The analysis is performed using different thicknesses of the window groove insulation, to evaluate what the optimal solution is.All analysis in the report is performed using both 2- and 3-dimensional numerical analysis....

  2. Thermal imaging of spin Peltier effect

    Science.gov (United States)

    Daimon, Shunsuke; Iguchi, Ryo; Hioki, Tomosato; Saitoh, Eiji; Uchida, Ken-Ichi

    2016-12-01

    The Peltier effect modulates the temperature of a junction comprising two different conductors in response to charge currents across the junction, which is used in solid-state heat pumps and temperature controllers in electronics. Recently, in spintronics, a spin counterpart of the Peltier effect was observed. The `spin Peltier effect' modulates the temperature of a magnetic junction in response to spin currents. Here we report thermal imaging of the spin Peltier effect; using active thermography technique, we visualize the temperature modulation induced by spin currents injected into a magnetic insulator from an adjacent metal. The thermal images reveal characteristic distribution of spin-current-induced heat sources, resulting in the temperature change confined only in the vicinity of the metal/insulator interface. This finding allows us to estimate the actual magnitude of the temperature modulation induced by the spin Peltier effect, which is more than one order of magnitude greater than previously believed.

  3. Power dissipated in a non-thermal atmospheric pressure plasma jet measured by miniaturized electrical probes

    Science.gov (United States)

    Golda, Judith; Schulz-von der Gathen, Volker

    2016-09-01

    Non-thermal atmospheric pressure plasma jets are used in bio-medicine, because they generate reactive species at a low gas temperature. Knowledge and control of plasma parameters is required for stable and reliable operation. Therefore, measuring dissipated power in these plasmas is necessary. However, this is challenging because the delivered sender power is often orders of magnitudes higher than the power dissipated in the discharge itself. To measure this dissipated power, we built miniaturized electrical probes directly attached to the jet device. We observed that the dissipated power is a more comprehensive parameter than the common parameter voltage: For example, gas temperature and emission line intensities rose exponentially with increasing voltage but linearly with increasing power. Our analyses further revealed that a substantial proportion of the dissipated power is transformed into heat. In conclusion, miniaturized electrical probes give a fundamental insight into the energy balance of atmospheric pressure plasmas. In the future, these probes can also be adapted to different types of atmospheric pressure plasmas. This work was supported by DFG within the frameworks of the Package Project PAK 816.

  4. Development of plasma assisted thermal vapor deposition technique for high-quality thin film

    Science.gov (United States)

    Lee, Kang-Il; Choi, Yong Sup; Park, Hyun Jae

    2016-12-01

    The novel technique of Plasma-Assisted Vapor Deposition (PAVD) is developed as a new deposition method for thin metal films. The PAVD technique yields a high-quality thin film without any heating of the substrate because evaporated particles acquire energy from plasma that is confined to the inside of the evaporation source. Experiments of silver thin film deposition have been carried out in conditions of pressure lower than 10-3 Pa. Pure silver plasma generation is verified by the measurement of the Ag-I peak using optical emission spectroscopy. A four point probe and a UV-VIS spectrophotometer are used to measure the electrical and optical properties of the silver film that is deposited by PAVD. For an ultra-thin silver film with a thickness of 6.5 nm, we obtain the result of high-performance silver film properties, including a sheet resistance 75%. The PAVD-film properties show a low sheet resistance of 30% and the same transmittance with conventional thermal evaporation film. In the PAVD source, highly energetic particles and UV from plasma do not reach the substrate because the plasma is completely shielded by the optimized nozzle of the crucible. This new PAVD technique could be a realistic solution to improve the qualities of transparent electrodes for organic light emission device fabrication without causing damage to the organic layers.

  5. Separation method in the problem of a beam-plasma interaction in bounded warm plasma under the effect of HF electric field

    CERN Document Server

    Ei-Shorbagy, K H

    2002-01-01

    The stabilization effect of a strong HP electric field on beam-plasma instability in a cylindrical warm plasma waveguide is discussed. A new mathematical technique 'separation method' which has been applied to the two-fluid plasma model to separate the equations, which describe the system, into two parts, temporal and space parts. Plasma electrons are considered to have a thermal velocity. It is shown that a HF electric field has no essential influence on dispersion characteristics of unstable surface waves excited in a warm plasma waveguide by a low-density electron beam. The region of instability only slightly narrowing and the growth rate decreases by a small parameter and this result has been reduced compared to cold plasma. Also, it is found that the plasma electrons have not affected the solution of the space part of the problem.

  6. Effects of Perpendicular Thermal Velocities on the Transverse Instability in Electron Phase Space Holes

    Institute of Scientific and Technical Information of China (English)

    WU Ming-Yu; WU Hong; LU Quan-Ming; XUE Bing-Sen

    2010-01-01

    @@ A multi-dimensional electron phase-space hole(electron hole)is considered to be unstable to the transverse instability.We perform two-dimensional(219)particle-in-cell(PIC)simulations to study the evolutions of electron holes in weakly magnetized plasma(Ωe < ωpe,where Ωe and ωpe are the electron gyrofrequency and plasma frequency,respectively),and the effects of perpendicular thermal velocities on the transverse instability are investigated.

  7. Optimizing Compliance and Thermal Conductivity of Plasma Sprayed Thermal Barrier Coatings via Controlled Powders and Processing Strategies

    Science.gov (United States)

    Tan, Yang; Srinivasan, Vasudevan; Nakamura, Toshio; Sampath, Sanjay; Bertrand, Pierre; Bertrand, Ghislaine

    2012-09-01

    The properties and performance of plasma-sprayed thermal barrier coatings (TBCs) are strongly dependent on the microstructural defects, which are affected by starting powder morphology and processing conditions. Of particular interest is the use of hollow powders which not only allow for efficient melting of zirconia ceramics but also produce lower conductivity and more compliant coatings. Typical industrial hollow spray powders have an assortment of densities resulting in masking potential advantages of the hollow morphology. In this study, we have conducted process mapping strategies using a novel uniform shell thickness hollow powder to control the defect microstructure and properties. Correlations among coating properties, microstructure, and processing reveal feasibility to produce highly compliant and low conductivity TBC through a combination of optimized feedstock and processing conditions. The results are presented through the framework of process maps establishing correlations among process, microstructure, and properties and providing opportunities for optimization of TBCs.

  8. Plasma heating effects during laser welding

    Science.gov (United States)

    Lewis, G. K.; Dixon, R. D.

    Laser welding is a relatively low heat input process used in joining precisely machined components with minimum distortion and heat affects to surrounding material. The CO2 (10.6 (MU)m) and Nd-YAG (1.06 (MU)m) lasers are the primary lasers used for welding in industry today. Average powers range up to 20 kW for CO2 and 400 W for Nd-YAG with pulse lengths of milliseconds to continuous wave. Control of the process depends on an understanding of the laser-plasma-material interaction and characterization of the laser beam being used. Inherent plasma formation above the material surface and subsequent modulation of the incident laser radiation directly affect the energy transfer to the target material. The temporal and spatial characteristics of the laser beam affect the available power density incident on the target, which is important in achieving repeatability in the process. Other factors such as surface texture, surface contaminants, surface chemistry, and welding environment affect plasma formation which determines the weld penetration. This work involves studies of the laser-plasma-material interaction process and particularly the effect of the plasma on the coupling of laser energy to a material during welding. A pulsed Nd-YAG laser was used with maximum average power of 400 W.

  9. Double-Layer Gadolinium Zirconate/Yttria-Stabilized Zirconia Thermal Barrier Coatings Deposited by the Solution Precursor Plasma Spray Process

    Science.gov (United States)

    Jiang, Chen; Jordan, Eric H.; Harris, Alan B.; Gell, Maurice; Roth, Jeffrey

    2015-08-01

    Advanced thermal barrier coatings (TBCs) with lower thermal conductivity, increased resistance to calcium-magnesium-aluminosilicate (CMAS), and improved high-temperature capability, compared to traditional yttria-stabilized zirconia (YSZ) TBCs, are essential to higher efficiency in next generation gas turbine engines. Double-layer rare-earth zirconate/YSZ TBCs are a promising solution. From a processing perspective, solution precursor plasma spray (SPPS) process with its unique and beneficial microstructural features can be an effective approach to obtaining the double-layer microstructure. Previously durable low-thermal-conductivity YSZ TBCs with optimized layered porosity, called the inter-pass boundaries (IPBs) were produced using the SPPS process. In this study, an SPPS gadolinium zirconate (GZO) protective surface layer was successfully added. These SPPS double-layer TBCs not only retained good cyclic durability and low thermal conductivity, but also demonstrated favorable phase stability and increased surface temperature capabilities. The CMAS resistance was evaluated with both accumulative and single applications of simulated CMAS in isothermal furnaces. The double-layer YSZ/GZO exhibited dramatic improvement in the single application, but not in the continuous one. In addition, to explore their potential application in integrated gasification combined cycle environments, double-layer TBCs were tested under high-temperature humidity and encouraging performance was recorded.

  10. Effects of thermal water on skin regeneration.

    Science.gov (United States)

    Faga, Angela; Nicoletti, Giovanni; Gregotti, Cesarina; Finotti, Valentina; Nitto, Agnese; Gioglio, Luciana

    2012-05-01

    An experimental study was carried out in an animal (New Zealand white rabbit) wound model to evaluate any effects of a hypotonic, bicarbonate-calcium-magnesium mineral water (Comano thermal water) on skin regeneration, comparing the healing rate of split-thickness skin graft donor sites treated with the thermal water wet dressing versus a standard petrolatum gauze dressing versus a saline solution wet dressing. The study was performed in two steps; an overall of 22 animals were enrolled in the study. The wound healing progress was evaluated both by the surgeons and by the histologists. Sixty-four punch biopsies were examined in all. The histological samples were examined after staining with haematoxylin and eosin, Masson's and orcein staining and under a transmission electron microscope. The data were statistically analysed. The Comano thermal water proved to improve skin regeneration, not only by increasing keratinocyte proliferation and migration but also favourably modulating the regenerated collagen and elastic fibres in the dermis. We propose that the results of the topical treatment with the thermal water could be due to the favourable combination of a local wet environment with an anti-inflammatory action and that the regenerative properties of Comano thermal water observed in rabbits could also be applied for human use.

  11. Dielectric Properties of Thermal and Plasma-Assisted Atomic Layer Deposited Al2O3 Thin Films

    NARCIS (Netherlands)

    Jinesh, K. B.; van Hemmen, J. L.; M. C. M. van de Sanden,; Roozeboom, F.; Klootwijk, J. H.; Besling, W. F. A.; Kessels, W. M. M.

    2011-01-01

    A comparative electrical characterization study of aluminum oxide (Al2O3) deposited by thermal and plasma-assisted atomic layer depositions (ALDs) in a single reactor is presented. Capacitance and leakage current measurements show that the Al2O3 deposited by the plasma-assisted ALD shows excellent d

  12. Toluene degradation by non-thermal plasma combined with a ferroelectric catalyst.

    Science.gov (United States)

    Liang, Wen-Jun; Ma, Lin; Liu, Huan; Li, Jian

    2013-08-01

    Degradation of toluene in a gas by non-thermal plasma with a ferroelectric catalyst was studied at normal temperature and atmospheric pressure. Spontaneous polarization material (BaTiO3) and photocatalyst (TiO2) were added into plasma system simultively. Toluene degradation efficiency and specific energy density during the discharge process were investigated. Furthermore, byproducts and degradation mechanisms of toluene were also investigated. The toluene degradation efficiency increased when non-thermal plasma technology was combined with the catalyst. The toluene degradation efficiencies of the different catalysts tested were in the following order: BaTiO3/TiO2>BaTiO3>TiO2>no catalyst. A mass ratio of 2.38:1 was optimum for the BaTiO3 and TiO2 catalyst. The outlet gas was analyzed by gas chromatography and Fourier transform infrared spectroscopy, and the main compounds detected were CO2, H2O, O3 and benzene ring derivatives. Copyright © 2013 Elsevier Ltd. All rights reserved.

  13. Liquid Feedstock Plasma Spraying: An Emerging Process for Advanced Thermal Barrier Coatings

    Science.gov (United States)

    Markocsan, Nicolaie; Gupta, Mohit; Joshi, Shrikant; Nylén, Per; Li, Xin-Hai; Wigren, Jan

    2017-08-01

    Liquid feedstock plasma spraying (LFPS) involves deposition of ultrafine droplets of suspensions or solution precursors (typically ranging from nano- to submicron size) and permits production of coatings with unique microstructures that are promising for advanced thermal barrier coating (TBC) applications. This paper reviews the recent progress arising from efforts devoted to development of high-performance TBCs using the LFPS approach. Advancements in both suspension plasma spraying and solution precursor plasma spraying, which constitute the two main variants of LFPS, are presented. Results illustrating the different types of the microstructures that can be realized in LFPS through appropriate process parameter control, model-assisted assessment of influence of coating defects on thermo-mechanical properties and the complex interplay between pore coarsening, sintering and crystallite growth in governing thermal conductivity are summarized. The enhancement in functional performances/lifetime possible in LFPS TBCs with multilayered architectures and by incorporating new pyrochlore chemistries such as gadolinium zirconate, besides the conventional single 8 wt.% yttria-stabilized zirconia insulating ceramic layer, is specifically highlighted.

  14. Ceramic Top Coats of Plasma-Sprayed Thermal Barrier Coatings: Materials, Processes, and Properties

    Science.gov (United States)

    Bakan, Emine; Vaßen, Robert

    2017-08-01

    The ceramic top coat has a major influence on the performance of the thermal barrier coating systems (TBCs). Yttria-partially-stabilized zirconia (YSZ) is the top coat material frequently used, and the major deposition processes of the YSZ top coat are atmospheric plasma spraying and electron beam physical vapor deposition. Recently, also new thermal spray processes such as suspension plasma spraying or plasma spray-physical vapor deposition have been intensively investigated for TBC top coat deposition. These new processes and particularly the different coating microstructures that can be deposited with them will be reviewed in this article. Furthermore, the properties and the intrinsic-extrinsic degradation mechanisms of the YSZ will be discussed. Following the TBC deposition processes and standard YSZ material, alternative ceramic materials such as perovskites and hexaaluminates will be summarized, while properties of pyrochlores with regard to their crystal structure will be discussed more in detail. The merits of the pyrochlores such as good CMAS resistance as well as their weaknesses, e.g., low fracture toughness, processability issues, will be outlined.

  15. Modified Korteweg–de Vries equation in a negative ion rich hot adiabatic dusty plasma with non-thermal ion and trapped electron

    Energy Technology Data Exchange (ETDEWEB)

    Adhikary, N. C., E-mail: nirab-iasst@yahoo.co.in [Physical Sciences Division, Institute of Advanced Study in Science and Technology, Vigyan Path, Paschim Boragaon, Garchuk, Guwahati 781035, Assam (India); Deka, M. K. [Centre of Plasma Physics, Tepesia, Sonapur, Assam (India); Dev, A. N. [Department of Science and Humanities, College of Science and Technology, Rinchending, Phuentsholing (Bhutan); Department of Mathematics, R. G. Baruah College, Guwahati 781025, Assam (India); Sarmah, J. [Department of Mathematics, R. G. Baruah College, Guwahati 781025, Assam (India)

    2014-08-15

    In this report, the investigation of the properties of dust acoustic (DA) solitary wave propagation in an adiabatic dusty plasma including the effect of the non-thermal ions and trapped electrons is presented. The reductive perturbation method has been employed to derive the modified Korteweg–de Vries (mK-dV) equation for dust acoustic solitary waves in a homogeneous, unmagnetized, and collisionless plasma whose constituents are electrons, singly charged positive ions, singly charged negative ions, and massive charged dust particles. The stationary analytical solution of the mK-dV equation is numerically analyzed and where the effect of various dusty plasma constituents DA solitary wave propagation is taken into account. It is observed that both the ions in dusty plasma play as a key role for the formation of both rarefactive as well as the compressive DA solitary waves and also the ion concentration controls the transformation of negative to positive potentials of the waves.

  16. Effects of Dressing Poses on Clothing Thermal Insulation

    Institute of Scientific and Technical Information of China (English)

    李俊; 刘岩; 张渭源

    2004-01-01

    With a thermal manikin, the effects of dressing poses on clothing thermal insulation are studied. It is found that the thermal insulation of still air layer over human body has not been influenced by the dressing poses, but the dressing poses have effects on the thermal insulation of clothing system.

  17. Preparation of SrZrO3 Thermal Barrier Coating by Solution Precursor Plasma Spray

    Science.gov (United States)

    Li, Xinhui; Ma, Wen; Wen, Jing; Bai, Yu; Sun, Li; Chen, Baodong; Dong, Hongying; Shuang, Yingchai

    2017-02-01

    The solution precursor plasma spray (SPPS) process is capable of depositing highly durable thermal barrier coatings (TBCs). In this study, an aqueous chemical precursor feedstock was injected into the plasma jet to deposit SrZrO3 thermal barrier coating on metal substrate. Taguchi design of experiments was employed to optimize the SPPS process. The thermal characteristics and phase evolution of the SrZrO3 precursor, as well as the influence of various spray parameters on the coating deposition rate, microhardness, microstructure, and phase stability, were investigated. The experimental results showed that, at given spray distance, feedstock flow rate, and atomization pressure, the optimized spray parameters were arc current of 600 A, argon flow rate of 40 L/min, and hydrogen flow rate of 10 L/min. The SrZrO3 coating prepared using the optimized spray parameters had single-pass thickness of 6.0 μm, porosity of 18%, and microhardness of 6.8 ± 0.1 GPa. Phase stability studies indicated that the as-sprayed SrZrO3 coating had good phase stability in the temperature range from room temperature to 1400 °C, gradually exhibiting a phase transition from t'-ZrO2 to m-ZrO2 in the SrZrO3 coating at 1450 °C with increasing time, while the SrZrO3 phase did not change.

  18. Atmospheric Plasma Spraying of Single Phase Lanthanum Zirconate Thermal Barrier Coatings with Optimized Porosity

    Directory of Open Access Journals (Sweden)

    Georg Mauer

    2016-10-01

    Full Text Available The shortcomings at elevated operation temperatures of the standard material yttria-stabilized zirconia (YSZ for thermal barrier coatings (TBCs have initiated many research activities seeking alternatives. One candidate is the pyrochlore lanthanum zirconate La2Zr2O7 (LZ, which is phase-stable to its melting point. At the same time, it shows a lower thermal conductivity and a lower sintering tendency when compared to YSZ. Because of its low thermal expansion coefficient and poor toughness, it is applied in combination with YSZ in double layer TBC systems. It is the current state of knowledge that LZ is prone to lanthanum depletion if processed by plasma spraying. The process conditions have to be selected carefully to avoid this. Furthermore, the amount and morphology of the coating porosity is essential for a good thermo-mechanical performance. In this work, the development and testing of LZ/YSZ double layer TBC systems is described. Initially, suitable basic parameters (torch, plasma gas composition, and power were tested with respect to coating stoichiometry. Then, microstructures were optimized by adjusting feed rate, spray distance, and by selecting a more appropriate feedstock. Powder particles and coatings were characterized by digital image analysis.

  19. Thermal resistance matrix representation of thermal effects and thermal design in multi-finger power heterojunction bipolar transistors

    Institute of Scientific and Technical Information of China (English)

    Jin Dong-Yue; Zhang Wan-Rong; Chen Liang; Fu Qiang; Xiao Ying; Wang Ren-Qing; Zhao Xin

    2011-01-01

    The thermal resistance matrix including self-heating thermal resistance and thermal coupling resistance is presented to describe the thermal effects of multi-finger power heterojunction bipolar transistors. The dependence of thermal resistance matrix on finger spacing is also investigated. It is shown that both self-heating thermal resistance and thermal coupling resistance are lowered by increasing the finger spacing, in which the downward dissipated heat path is widened and the heat flow from adjacent fingers is effectively suppressed. The decrease of self-heating thermal resistance and thermal coupling resistance is helpful for improving the thermal stability of power devices. Furthermore, with the aid of the thermal resistance matrix, a 10-finger power heterojunction bipolar transistor (HBT) with non-uniform finger spacing is designed for high thermal stability. The optimized structure can effectively lower the peak temperature while maintaining a uniformity of the temperature profile at various biases and thus the device effectively may operate at a higher power level.

  20. Microstructure and properties of in-flight rare-earth doped thermal barrier coatings prepared by suspension plasma spray

    Science.gov (United States)

    Gong, Stephanie

    Thermal barrier coatings with lower thermal conductivity improve the efficiency of gas turbine engines by allowing higher operating temperatures. Recent studies were shown that coatings containing a pair of rare-earth oxides with equal molar ratio have lower thermal conductivity and improved sintering resistance compared to the undoped 4-4.5 mol.% yttria-stabilized zirconia (YSZ). In the present work, rare-earth doped coatings were fabricated via suspension plasma spray by spraying YSZ powder-ethanol suspensions that contained dissolved rare-earth nitrates. The compositions of the coatings determined by inductively coupled plasma mass spectroscopy verified that 68 +/- 8% of the rare-earth nitrates added into the suspension was incorporated into the coatings. Two coatings containing different concentrations of the same dopant pair (Nd2O3/Yb2O3), and three coatings having similar concentrations of different dopant pairs (Nd 2O3/Yb2O3, Nd2O3/Gd 2O3, and Gd2O3/Yb2O 3) were produced and compared. The effect of dopant concentration and dopant pair type on the microstructure and properties of the coatings in the as-sprayed and heat treated conditions were investigated using XRD, SEM, TEM, STEM-EDX, and the laser flash method. The cross-sectional morphology of all coatings displayed columnar structure. The porosity content of the coating was found to increase with increasing dopant concentration, but did not significantly change with dopant pairs. Similarly, increasing the Nd2O3/Yb2O 3 concentration lowered the thermal conductivity of the as-sprayed coatings. Although the effect of changing dopant pair type is not as significant as increasing the dopant concentration, the coating that contained Gd2O 3/Yb2O3 exhibited the lowest conductivity compared to coatings that had other dopant pairs. Thermal conductivity measurement performed on the heat treated coatings indicated a larger conductivity increase for the rare-earth doped coatings. A detailed study on the

  1. Guanfacine in essential hypertension: Effect on blood pressure, plasma noradrenaline concentration and plasma renin activity

    OpenAIRE

    Schoeppe, W.; Brecht, H. M.

    1980-01-01

    1 The acute and chronic effects of guanfacine on blood pressure, plasma noradrenaline concentration and plasma renin activity were investigated in 23 patients (15 males, 8 females) with essential hypertension (WHO grade I-II).

  2. Production of stable, non-thermal atmospheric pressure rf capacitive plasmas using gases other than helium or neon

    Science.gov (United States)

    Park, Jaeyoung; Henins, Ivars

    2005-06-21

    The present invention enables the production of stable, steady state, non-thermal atmospheric pressure rf capacitive .alpha.-mode plasmas using gases other than helium and neon. In particular, the current invention generates and maintains stable, steady-state, non-thermal atmospheric pressure rf .alpha.-mode plasmas using pure argon or argon with reactive gas mixtures, pure oxygen or air. By replacing rare and expensive helium with more readily available gases, this invention makes it more economical to use atmospheric pressure rf .alpha.-mode plasmas for various materials processing applications.

  3. Changing the surface properties on naval steel as result of non-thermal plasma treatment

    Science.gov (United States)

    Hnatiuc, B.; Sabău, A.; Dumitrache, C. L.; Hnatiuc, M.; Crețu, M.; Astanei, D.

    2016-08-01

    The problem of corrosion, related to Biofouling formation, is an issue with very high importance in the maritime domain. According to new rules, the paints and all the technologies for the conditioning of naval materials must fulfil more restrictive environmental conditions. In order to solve this issue, different new clean technologies have been proposed. Among them, the use of non-thermal plasmas produced at atmospheric pressure plays a very important role. This study concerns the opportunity of plasma treatment for preparation or conditioning of naval steel OL36 type. The plasma reactors chosen for the experiments can operate at atmospheric pressure and are easy to use in industrial conditions. They are based on electrical discharges GlidArc and Spark, which already proved their efficiency for the surface activation or even for coatings of the surface. The non-thermal character of the plasma is ensured by a gas flow blown through the electrical discharges. One power supply has been used for reactors that provide a 5 kV voltage and a maximum current of 100 mA. The modifications of the surface properties and composition have been studied by XPS technique (X-ray Photoelectron Spectroscopy). There were taken into consideration 5 samples: 4 of them undergoing a Mini-torch plasma, a Gliding Spark, a GlidArc with dry air and a GlidArc with CO2, respectively the fifth sample which is the untreated witness. Before the plasma treatment, samples of naval steel were processed in order to obtain mechanical gloss. The time of treatment was chosen to 12 minutes. In the spectroscopic analysis, done on a ULVAC-PHI, Inc. PHI 5000 Versa Probe scanning XPS microprobe, a monocromated Al Kα X-ray source with a spot size of 100 μm2 was used to scan each sample while the photoelectrons were collected at a 45-degree take-off angle. Differences were found between atomic concentrations in each individual case, which proves that the active species produced by each type of plasma affects

  4. Atmospheric effects on the mapping of Martian thermal inertia and thermally derived albedo

    Science.gov (United States)

    Hayashi, Joan N.; Jakosky, Bruce M.; Haberle, Robert M.

    1995-01-01

    We examine the effects of a dusty CO2 atmosphere on the thermal inertia and thermally derived albedo of Mars and we present a new map of thermal inertias. This new map was produced using a coupled surface atmosphere (CSA) model, dust opacities from Viking infrared thermal mapper (IRTM) data, and CO2 columns based on topography. The CSA model thermal inertias are smaller than the 2% model thermal inertias, with the difference largest at large thermal inertia. Although the difference between the thermal inertias obtained with the two models is moderate for much of the region studied, it is largest in regions of either high dust opacity or of topographic lows, including the Viking Lander 1 site and some geologically interesting regions. The CSA model thermally derived albedos do not acurately predict the IRTM measured albedos and are very similar to the thermally derived albedos obtained with models making the 2% assumption.

  5. Plasma effect on weld pool surface reconstruction by shape-from-polarization analysis

    Energy Technology Data Exchange (ETDEWEB)

    Coniglio, N.; Mathieu, A., E-mail: alexandre.mathieu@u-bourgogne.fr [Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB), UMR 6303 CNRS/Université de Bourgogne, 12 rue de la Fonderie, 71200 Le Creusot (France); Aubreton, O.; Stolz, C. [Université de Bourgogne Laboratoire Le2i UMR CNRS 6306, allée Alain Savary, 21000 Dijon (France)

    2014-03-31

    The polarimetric state of the thermal radiations emitted by the weld metal contains geometric information about the emitting surface. Even though the analysed thermal radiation has a wavelength corresponding to a blind spectral window of the arc plasma, the physical presence of the arc plasma itself interferes with the rays radiated by the weld pool surface before attaining the polarimeter, thus modifying the geometric information transported by the ray. In the present work, the effect of the arc plasma-surrounding zone on the polarimetric state and propagation direction of the radiated ray is analyzed. The interaction with the arc plasma zone induces a drop in ray intensity and a refraction of ray optical path.

  6. Treatment of gastric cancer cells with non-thermal atmospheric plasma generated in water

    CERN Document Server

    Chen, Zhitong; Cheng, Xiaoqian; Gjika, Eda; Keidar, Michael

    2016-01-01

    Non-thermal atmospheric plasma (NTAP) can be applied to living tissues and cells as a novel technology for cancer therapy. Even though studies report on the successful use of NTAP to directly irradiate cancer cells, this technology can cause cell death only in the upper 3-5 cell layers. We report on a NTAP argon solution generated in DI water for treating human gastric cancer cells (NCl-N87). Our findings showed that the plasma generated in DI water during a 30-minute treatment had the strongest affect in inducing apoptosis in cultured human gastric cancer cells. This result can be attributed to presence of reactive oxygen species (ROS) and reactive nitrogen species (RNS) produced in water during treatment. Furthermore, the data showed that elevated levels of RNS may play an even more significant role than ROS in the rate of apoptosis in gastric cancer cells.

  7. Fabrication of Nanosized Lanthanum Zirconate Powder and Deposition of Thermal Barrier Coating by Plasma Spray Process

    Science.gov (United States)

    Mishra, S. K.; Jagdeesh, N.; Pathak, L. C.

    2016-07-01

    The present manuscript discusses our findings on fabrication of nanosized lanthanum zirconate powder for thermal barrier coating application and its coating by plasma spray on nickel-based superalloy substrate. Single-phase La2Zr2O7 coating of thickness of the order of 45 µm on the Ni-Cr-Al bond coat coated Ni-based superalloy substrate was deposited by plasma spray process. The layers at the interface did not show spallation and inter diffusion was very less. The microstructure, interface, porosity, and mechanical properties of different layers are investigated. The lanthanum zirconate hardness and modulus were 10.5 and 277 GPa, respectively. The load depth curve for lanthanum zirconate showed good elastic recovery around 74%.

  8. Thermal Structure of Supra-Arcade Plasma in Two Solar Flares

    Science.gov (United States)

    Reeves, Katharine K.; Savage, Sabrina; McKenzie, David E.; Weber, Mark A.

    2012-01-01

    In this work, we use Hinode/XRT and SDO/AIA data to determine the thermal structure of supra-arcade plasma in two solar flares. The first flare is a Ml.2 flare that occurred on November 5, 2010 on the east limb. This flare was one of a series of flares from AR 11121, published in Reeves & Golub (2011). The second flare is an XI.7 flare that occurred on January 27, 2012 on the west limb. This flare exhibits visible supra-arcade downflows (SADs), where the November 2010 flare does not. For these two flares we combine XRT and AlA data to calculate DEMs of each pixel in the supra-arcade plasma, giving insight into the temperature and density structures in the fan of plasma above the post-flare arcade. We find in each case that the supra-arcade plasma is around 10 MK, and there is a marked decrease in the emission measure in the SADs. We also compare the DEMs calculated with the combined AIA/XRT dataset to those calculated using AIA alone.

  9. A new concept of high flow rate non-thermal plasma reactor for air treatment

    Energy Technology Data Exchange (ETDEWEB)

    Goujard, V.; Tatibouet, J.M. [Univ. de Poitiers, Poitiers (France). Centre national de la recherche scientifique, Laboratoire de Catalyse en Chimie Organique

    2010-07-01

    Although several non-thermal plasma reactors have been tested for air treatment at the laboratory scale, up-scaling to pilot or industrial scale remains a challenge because several parameters must be considered, such as hydrodynamic behaviour, maximum voltage in an industrial environment, and maintenance of the system. This paper presented a newly developed reactor which consists to a DBD plasma generated on individual supports that could be directly inserted in gas pipes where air flow must be treated. Elimination of 40 percent of 15 ppm of propene was obtained with a energy density as low as 10 J/L. The propene conversion increased when a manganese oxide based catalyst was used because the ozone produced by the plasma was used as an as an oxidant. A simple model of the plasma-catalyst reactor behaviour showed that more than 90 percent of propene conversion can be expected for an input energy density of 10 J/L and residual ozone concentration less than 100 ppb.

  10. Scaling thermal effects in radial flow

    Science.gov (United States)

    Hudspeth, R. T.; Guenther, R. B.; Roley, K. L.; McDougal, W. G.

    To adequately evaluate the environmental impact of siting nuclear waste repositories in basalt aquicludes, it is essential to know the effects on parameter identification algorithms of thermal gradients that exist in these basaltic aquicludes. Temperatures of approximately 60°C and pressures of approximately 150 atm can be expected at potential repository sites located at depths of approximately 1000 m. The phenomenon of over-recovery has been observed in some pumping tests conducted at the Hanford Nuclear Reservation located in the Pasco Basin adjacent to the Columbia River in the state of Washington, USA. This over-recovery phenomenon may possibly be due to variations in the fluid density caused by thermal gradients. To assess the potential effects of these thermal gradients on indirect parameter identification algorithms, a systematic scaling of the governing field equations is required in order to obtain dimensionless equations based on the principle of similarity. The constitutive relationships for the specific weight of the fluid and for the porosity of the aquiclude are shown to be exponentially dependent on the pressure gradient. The dynamic pressure is converted to the piezometric head and the flow equation for the piezometric head is then scaled in radial coordinates. Order-of-magnitude estimates are made for all variables in unsteady flow for a typical well test in a basaltic aquiclude. Retaining all nonlinear terms, the parametric dependency of the flow equation on the classical dimensionless thermal and hydraulic parameters is demonstrated. These classical parameters include the Batchelor, Fourier, Froude, Grashof, and Reynolds Numbers associated with thermal flows. The flow equation is linearized from order-of-magnitude estimates based on these classical parameters for application in parameter identification algorithms.

  11. Non-thermal dielectric-barrier discharge plasma damages human keratinocytes by inducing oxidative stress

    Science.gov (United States)

    KIM, KI CHEON; PIAO, MEI JING; HEWAGE, SUSARA RUWAN KUMARA MADDUMA; HAN, XIA; KANG, KYOUNG AH; JO, JIN OH; MOK, YOUNG SUN; SHIN, JENNIFER H.; PARK, YEUNSOO; YOO, SUK JAE; HYUN, JIN WON

    2016-01-01

    The aim of this study was to identify the mechanisms through which dielectric-barrier discharge plasma damages human keratinocytes (HaCaT cells) through the induction of oxidative stress. For this purpose, the cells were exposed to surface dielectric-barrier discharge plasma in 70% oxygen and 30% argon. We noted that cell viability was decreased following exposure of the cells to plasma in a time-dependent manner, as shown by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay. The levels of intracellular reactive oxygen species (ROS) were determined using 2′,7′-dichlorodihydro-fluorescein diacetate and dihydroethidium was used to monitor superoxide anion production. Plasma induced the generation of ROS, including superoxide anions, hydrogen peroxide and hydroxyl radicals. N-acetyl cysteine, which is an antioxidant, prevented the decrease in cell viability caused by exposure to plasma. ROS generated by exposure to plasma resulted in damage to various cellular components, including lipid membrane peroxidation, DNA breaks and protein carbonylation, which was detected by measuring the levels of 8-isoprostane and diphenyl-1-pyrenylphosphine assay, comet assay and protein carbonyl formation. These results suggest that plasma exerts cytotoxic effects by causing oxidative stress-induced damage to cellular components. PMID:26573561

  12. Pyrite-enhanced methylene blue degradation in non-thermal plasma water treatment reactor.

    Science.gov (United States)

    Benetoli, Luís Otávio de Brito; Cadorin, Bruno Mena; Baldissarelli, Vanessa Zanon; Geremias, Reginaldo; de Souza, Ivan Gonçalvez; Debacher, Nito Angelo

    2012-10-30

    In this study, methylene blue (MB) removal from an aqueous phase by electrical discharge non-thermal plasma (NTP) over water was investigated using three different feed gases: N(2), Ar, and O(2). The results showed that the dye removal rate was not strongly dependent on the feed gas when the electrical current was kept the same for all gases. The hydrogen peroxide generation in the water varied according to the feed gas (N(2)degradation occurs via high energy electron impact as well as successive hydroxylation in the benzene rings of the dye molecules.

  13. Modeling and experimental validation of TCE abatement and ozone formation with non thermal plasma

    OpenAIRE

    Vandenbroucke, Arne; Aerts, Robby; Morent, Rino; De Geyter, Nathalie; Bogaerts, Annemie; Leys, Christophe

    2012-01-01

    In this study, the formation of ozone and the abatement of trichloroethylene (TCE) with non thermal plasma was experimentally and theoretically investigated. The model predicts that the ozone formation increases with the energy deposition and decreases with the relative humidity (RH) of the air, which is qualitatively in agreement with experimental data. For an energy deposition of 0.136 J/cm³, the abatement of 1000 ppm TCE in air with 5 % RH is dominated by atomic oxygen and to a lesser exte...

  14. Spraying of Super Fine Powders With HVOF and Axial Plasma Thermal Spray Systems

    Institute of Scientific and Technical Information of China (English)

    Alan Burgess; G(o)tz Matth(a)us

    2004-01-01

    The use of fine powders in thermal spray can lead to many advantages. These advantages include denser coatings, coatings with increased wear resistance, coatings with smoother surface finish, coatings that can be applied to internal surfaces, less expensive coatings. The use of fine powders also has an disadvantage that th ey can have poor flow characteristics. The paper will discuss a feeder that is able to feed fine powders to overcome this difficulty and the coating equipment, both axial plasma and HVOF systems, used to deposit these materials to produce smooth dense coatings.

  15. Modeling and experimental validation of TCE abatement and ozone formation with non thermal plasma

    OpenAIRE

    Vandenbroucke, Arne; Aerts, Robby; Morent, Rino; De Geyter, Nathalie; Bogaerts, Annemie; Leys, Christophe

    2012-01-01

    In this study, the formation of ozone and the abatement of trichloroethylene (TCE) with non thermal plasma was experimentally and theoretically investigated. The model predicts that the ozone formation increases with the energy deposition and decreases with the relative humidity (RH) of the air, which is qualitatively in agreement with experimental data. For an energy deposition of 0.136 J/cm³, the abatement of 1000 ppm TCE in air with 5 % RH is dominated by atomic oxygen and to a lesser exte...

  16. Treatment of the oily waste sludges through thermal plasma in absence of oxygen

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda J, G.; Pacheco S, J. [Instituto Nacional de Investigaciones Nucleares. Laboratorio de Aplicaciones de Plasmas Termicos. Apdo. Postal 18-1027. C.P. 11801 Mexico D.F. (Mexico)

    2001-07-01

    The thermal plasma process in absence of oxygen for the degradation of oily waste sludges was evaluated. These residues are commonly generated in the petrochemical industry and are considered hazardous wastes according to the present environmental regulations. The process was operated using difference residence times and the characteristics of the gaseous by products and residual soils were determined. The efficiency of organic matter degradation was 99.99%. The attained volume reduction, under the best conditions was 95.5%. The residual soils were composed of carbon and clays. The residual gases have low molecular weight. The resulting final wastes were non-hazardous and could be disposed of in landfills. (Author)

  17. Non-thermal atmospheric pressure plasma functionalized dental implant for enhancement of bacterial resistance and osseointegration.

    Science.gov (United States)

    Lee, Jung-Hwan; Jeong, Won-Seok; Seo, Seog-Jin; Kim, Hae-Won; Kim, Kyoung-Nam; Choi, Eun-Ha; Kim, Kwang-Mahn

    2017-03-01

    Even though roughened titanium (Ti) and Ti alloys have been clinically used as dental implant, they encourage bacterial adhesion, leading to failure of the initial stability. Here, the non-thermal atmospheric pressure plasma jet (NTAPPJ) functionalized Ti and Ti alloy were investigated to promote cellular activities but inhibit the initial attachment of the adherent pioneer bacterium, Streptococcus sanguinis, without topographical changes. After the produced radicals from NTAPPJ were characterized, bacterial adhesion to specimens was assessed by PrestoBlue assay and live-dead staining with or without the NTAPPJ functionalizing. After the surface was characterized using optical profilometry, X-ray photoelectron spectroscopy and contact angle analysis, the ions released from the specimens were investigated. In vitro initial cell attachment (4h or 24h) with adhesion images and alkaline phosphatase activity (ALP, 14 days) measurements were performed using rat bone marrow-derived mesenchymal stem cells. The initial bacterial adhesion to the Ti and Ti alloy was significantly inhibited after NTAPPJ functionalizing (padhesion-resistance effect was induced by carbon cleaning, which was dependent on the working gas used on the Ti specimens (nitrogen>ammonia and air, padhesion with well-developed vinculin localization and consequent ALP activity at 14days to the NTAPPJ-functionalized specimens were superior to the non-treated specimens. For the promising success of dental implants, NTAPPJ functionalizing is suggested as a novel surface modification technique; this technique can help ensure the success of integration between the dental implants and bone tissues with less concern of inflammation. Copyright © 2016 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  18. Thermal effects on bluegill hematology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Murray, S.A.

    1983-03-01

    Temperature effects on hematological responses of adult bluegill were examined for constant vs fluctuating temperature regimes, for ambient vs high temperature, and for intake vs discharge at an operating power plant. Multivariate statistical methods were used to determine temperature effects. An increased erythrocyte fragility was associated with fluctuating temperature regimes as well as with the suboptimal temperature regime. Thrombocytosis with a concomitant leukopenia was observed for the higher fluctuating and higher acclimating temperatures. Reduced erythrocytic sedimentation rates were observed for the higher temperatures. Although hematology may vary depending on fish size, good hematological indicators of potential thermal stress were associated with red blood cell morphology, particularly cell size and/or shape. However, in situ hematological responses of bluegill at an operating power plant were apparently not affected by the associated thermal gradients.

  19. Plasma effect of the Houston horse

    Science.gov (United States)

    Pavlov, V. A.; Tryaskin, Ya. V.

    2015-05-01

    The effect of a strong shock wave on a weakly ionized collisional plasma was studied. The structure of the ion-acoustic perturbation caused by the shock wave was numerically investigated. The effect of the nonlinearity, dispersion, and dissipation on the formation of an oscillating wave profile was shown. It is found that in some modes, an increase in the shock wave velocity leads to a sharp increase in the concentration of charged particles and a reduction in the number of perturbation maxima. This change of the flow structure can be preceded by the formation of localized regions with an increased degree of plasma ionization. It is shown that the presence of plasmoids can lead to a strong influence of charges on the neutral component.

  20. Investigation of mechanical properties of thermal coatings obtained during plasma spraying of powder zirconium dioxide

    Science.gov (United States)

    Ibragimov, A. R.; Ilinkova, T. A.; Shafigullin, L. N.; Saifutdinov, A. I.

    2017-01-01

    Thermal coatings of zirconia partially stabilized with yttrium, deposited by low-temperature plasma, are the basis for the thermal protection of aircraft engine. At the same time there is an actual problem of selection of coating systems “ceramic layer - underlayer” of great thickness, providing better thermal protection, but having low strength characteristics due to the accumulation of internal stresses. To determine the optimal thickness of the test method used in the 4-point bending to allow the surface coating to explore in the elastic-plastic behavior of the field of coatings and strength. Based on the experimental results established the role of underlayer in the formation of the complex mechanical properties of thermal barrier coatings. With a well formed underlayer (PVNH16U6) system becomes sensitive to a change in thickness of the coating, to optimize the response on the strength and deformation criteria. According to the results the optimum ratio of the thickness of the ceramic layer and the underlayer should be regarded as the ratio of 3-5 for which the highest strength values were obtained for all the test coating systems.

  1. Improved energy confinement with nonlinear isotope effects in magnetically confined plasmas

    CERN Document Server

    Garcia, J; Jenko, F

    2016-01-01

    The efficient production of electricity from nuclear fusion in magnetically confined plasmas relies on a good confinement of the thermal energy. For more than thirty years, the observation that such confinement depends on the mass of the plasma isotope and its interaction with apparently unrelated plasma conditions has remained largely unexplained and it has become one of the main unsolved issues. By means of numerical studies based on the gyrokinetic theory, we quantitatively show how the plasma microturbulence depends on the isotope mass through nonlinear multiscale microturbulence effects involving the interplay between zonal flows, electromagnetic effects and the torque applied. This finding has crucial consequences for the design of future reactors since, in spite of the fact that they will be composed by multiple ion species, their extrapolation from present day experiments heavily relies on the knowledge obtained from a long experimental tradition based in single isotope plasmas.

  2. ISEE 1 observations of thermal plasma in the vicinity of the plasmasphere during periods of quieting magnetic activity

    Science.gov (United States)

    Horwitz, J. L.; Baugher, C. R.; Chappell, C. R.; Shelley, E. G.; Young, D. T.; Anderson, R. R.

    1981-11-01

    An investigation of thermal plasma behavior in the vicinity of the plasmasphere during periods of quieting magnetic activity was conducted by combining thermal ion observations made with the plasma composition experiment on ISEE 1 with plasma density profiles obtained from plasma frequency measurements made with the same satellite's plasma wave experiment. During periods in which the magnetic activity quiets, the two regions characterized by H(+):He(+):O(+) (isotropic) and H(+):O(+):He(+) (field-aligned) ion species distributions (in order of dominance) are separated by a new region in which low-energy H(+) and He(+) are found flowing along the magnetic field lines. At other times, following quieting magnetic activity, distributions having peak fluxes at 90 deg pitch angle are observed in this region.

  3. Quantum effects in beam-plasma instabilities

    CERN Document Server

    Bret, A

    2015-01-01

    Among the numerous works on quantum effects that have been published in recent years, streaming instabilities in plasma have also been revisited. Both the fluid quantum and the kinetic Wigner-Maxwell models have been used to explore quantum effects on the Weibel, Filamentation and Two-Stream instabilities. While quantum effects usually tend to reduce the instabilities, they can also spur new unstable branches. A number of theoretical results will be reviewed together with the implications to one physical setting, namely the electron driven fast ignition scenario.

  4. Application of Non-Thermal Plasma to the Treatment of Effluent Discharged Into River Choumlou in Bafoussam, West Cameroon

    Directory of Open Access Journals (Sweden)

    Estella T. Njoyim

    2016-07-01

    Full Text Available Most rivers in urban areas of developing countries are the of effluents discharged from industries. This is the case of River Choumlou (in Bafoussam-West Region, Cameroon which receives all discharges from “Brasseries du Cameroun”, Bafoussam branch. The objective of this work was to determine the level of organic contaminants in water samples and to treat the polluted samples using the non-thermal gliding arc plasma. Nonthermal plasma consists of charged particles, radicals and excited molecules. The aim was to show the interest of such a process for cleaning up of surface waters (real effluent and to cope with the protection of our environment. Due to the fact that pollution of streams and rivers from the discharge of sewage and industrial wastes poses a major problem to the environment, the researchers were particularly interested in investigating the oxidizing and acidifying properties of non-thermal plasma on polluted surface water. Samples were collected upstream and downstream from the brewery’s effluent outlet. Samples taken at the point R1 (downstream were first analyzed by volumetric and instrumental methods in order to determine the organoleptic, physico-chemical and organic parameters. These samples were then exposed to the gliding discharge in humid air for a time period of between 3-30 minutes. After 30 minutes of exposure, a decrease in turbidity (24.09%, BOD5 (44.93% and COD (48.92% were observed resulting in transparency apparition; with a decrease in pH (7.9 to 3 due to the formation of acidifying species in solution. These results reflect a considerable reduction in the pollution load of the water collected at R1. This work shows that the effectiveness of the Gliding Arc in wastewater treatment is attributed to the oxidizing power of the hydroxyl radical and acidifying power of the nitrogen monoxide radical formed in the plasma. Despite the low rate of reduction of COD and BOD5 in 30 min, it can be said that the plasma

  5. The Alpha Dynamo Effects in Laboratory Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Hantao Ji; Stewart C. Prager

    2001-10-16

    A concise review of observations of the alpha dynamo effect in laboratory plasmas is given. Unlike many astrophysical systems, the laboratory pinch plasmas are driven magnetically. When the system is overdriven, the resultant instabilities cause magnetic and flow fields to fluctuate, and their correlation induces electromotive forces along the mean magnetic field. This alpha-effect drives mean parallel electric current, which, in turn, modifies the initial background mean magnetic structure towards the stable regime. This drive-and-relax cycle, or the so-called self-organization process, happens in magnetized plasmas in a timescale much shorter than resistive diffusion time, thus it is a fast and unquenched dynamo process. The observed alpha-effect redistributes magnetic helicity (a measure of twistedness and knottedness of magnetic field lines) but conserves its total value. It can be shown that fast and unquenched dynamos are natural consequences of a driven system where fluctuations are statistically either not stationary in time or not homogeneous in space, or both. Implications to astrophysical phenomena will be discussed.

  6. Dimension effects in plasma immersion ion implantation of cylindrical bore

    CERN Document Server

    Tian Xiu Bo; Tong Hong Hui; Chu, P K

    2002-01-01

    Plasma immersion ion implantation is a new technique pertaining to ion implantation. Different from the case of exterior surface treatment, plasma immersion ion implantation of interior surface possesses dimension effects. Consequently it is a challenge to implant the inner wall of a cylindrical bore due to this finite dimension.The ion energy cannot be linearly changed with applied voltage and there exists a saturation value due to overlap effect of plasma sheath. The plasma in the bore may rapidly be depleted, which is attributed to finite plasma volume and plasma-sheath con-flowing effect. For instance the plasma depletion time is about 0.55 mu s when a bore with a diameter of 20 cm is treated under conditions of applied voltage of 30 kV and plasma density of 2 x 10 sup 1 sup 5 ions/cm sup 3. Interior plasma-source hardware may be an effective solution

  7. Death from thermal effects and burns.

    Science.gov (United States)

    Gerling, I; Meissner, C; Reiter, A; Oehmichen, M

    2001-01-01

    One hundred and fifteen unselected autopsy cases of death from thermal effects and/or fire between 1990 and 1999 were analyzed with regard to time of death, signs of vitality at the scene of the fire, the manner and cause of death, and the extent of soft tissue loss. The cases represented approximately 6% of all autopsy cases at the Institute of Legal Medicine responsible for a catchment area with approximately 700,000 inhabitants. In 23 victims suffering burn injuries, death occurred during initial medical care or clinical treatment. The causes of death were primary respiratory arrest due to smoke poisoning or delayed shock caused by thermal injuries to the skin. Death occurred at the scene of the fatal event in 85 cases: eight cases exhibited no thermal effects; the cause of death in one of these cases was polytrauma incurred in a leap from a height; in seven cases there was poisoning due to smoke inhalation. The remaining 77 cases were characterized by signs of intensive thermal and/or fire effects. Clear signs of vitality (carboxyhemoglobin (COHb) in blood, inhalation and/or swallowing of soot) were found in 84.7% of the victims dying at the site of the fatal event. Of the 13 victims showing no signs of vitality at the scene, a cause of death could be determined in only seven cases; death in the other six cases remains unexplained. Quantification of the soft tissue loss revealed a possible correlation with the temperature and time course of heat exposure.

  8. Method and Process Development of Advanced Atmospheric Plasma Spraying for Thermal Barrier Coatings

    Science.gov (United States)

    Mihm, Sebastian; Duda, Thomas; Gruner, Heiko; Thomas, Georg; Dzur, Birger

    2012-06-01

    Over the last few years, global economic growth has triggered a dramatic increase in the demand for resources, resulting in steady rise in prices for energy and raw materials. In the gas turbine manufacturing sector, process optimizations of cost-intensive production steps involve a heightened potential of savings and form the basis for securing future competitive advantages in the market. In this context, the atmospheric plasma spraying (APS) process for thermal barrier coatings (TBC) has been optimized. A constraint for the optimization of the APS coating process is the use of the existing coating equipment. Furthermore, the current coating quality and characteristics must not change so as to avoid new qualification and testing. Using experience in APS and empirically gained data, the process optimization plan included the variation of e.g. the plasma gas composition and flow-rate, the electrical power, the arrangement and angle of the powder injectors in relation to the plasma jet, the grain size distribution of the spray powder and the plasma torch movement procedures such as spray distance, offset and iteration. In particular, plasma properties (enthalpy, velocity and temperature), powder injection conditions (injection point, injection speed, grain size and distribution) and the coating lamination (coating pattern and spraying distance) are examined. The optimized process and resulting coating were compared to the current situation using several diagnostic methods. The improved process significantly reduces costs and achieves the requirement of comparable coating quality. Furthermore, a contribution was made towards better comprehension of the APS of ceramics and the definition of a better method for future process developments.

  9. APPLICATION OF THERMAL PLASMA FOR INERTIZATION OF SLUDGE PRODUCED DURING TREATMENT OF LANDFILL LEACHATE

    Directory of Open Access Journals (Sweden)

    Anelise Leal Vieira Cubas

    Full Text Available One of the outstanding issues of concern by governments and society in general relates to the final destination of solid waste, which can bring severe impacts on social, political, economic and environmental dimensions. The sustainable development of enterprises and industries goes for the care of the planet, thus ensuring the quality of life for future generations and the planet. The disposal of municipal waste in landfills is the technique most commonly employed for the remediation of solid residues. The residues undergo decomposition beneath the soil and in the presence of water this generates leachate, which percolates down to the bottom of the landfill through drainage. This drained liquid is collected from the landfill installations and subjected to treatment, which involves physico-chemical and biological processes. Landfill leachate commonly contains heavy metals due to the incorrect disposal of products such as fluorescent bulbs and batteries. In this context, a method for the treatment of sludge originating from the physicochemical remediation of leachate using thermal plasma is proposed in this paper. The efficiency of the method was verified by monitoring the total organic carbon content, water content and density of the sludge. The quantity of metals present in the samples was determined before and after pyrolysis by thermal plasma using flame atomic absorption spectroscopy (FAAS, scanning electron microscopy (SEM and X-ray fluorescence (XRF spectrometry techniques. The results show that the leachate treatment method used was efficient, presenting the best results for the samples of iron and zinc.

  10. Non-thermal plasma as preparative technique to evaluate olive oil adulteration.

    Science.gov (United States)

    Van Durme, Jim; Vandamme, Jeroen

    2016-10-01

    In recent years adulteration of pure extra virgin olive oil (EVOO) with other types of vegetable oils has become an important issue. In this study, non-thermal plasma (NTP) is investigated as an innovative preparative analytical technique enabling classification of adulterated olive oil from an ascertained authentic batch of olive oil in a more sensitive manner. Non-thermal plasma discharges are a source of highly oxidative species such as singlet oxygen, and atomic oxygen. It was assumed that NTP-induced oxidation triggers unique lipid oxidation mechanisms depending on the specific composition of the oil matrix and minor constituents. In this work EVOO samples were adulterated with sunflower oil (1-3%) and submitted to NTP treatment. Results showed that while untreated samples could not be classified from the authentic olive oil reference, NTP treatments of 60min (Ar/O2 0.1%) on the oil batches resulted in the formation of a unique set of secondary volatile lipid oxidation products enabling classification of adulterated oil samples.

  11. Synthesis and Characterization of Titanium Slag from Ilmenite by Thermal Plasma Processing

    Science.gov (United States)

    Samal, Sneha

    2016-09-01

    Titanium rich slag has emerged as a raw material for alternative titanium source. Ilmenite contains 42-50% TiO2 as the mineralogical composition depending on the geographical resources. Application of titanium in paper, plastic, pigment and other various industries is increasing day by day. Due to the scarcity of natural raw mineral rutile (TiO2), ilmenite is considered as precursor for the extraction of TiO2. Ilmenite is reduced at the initial stage for the conversion of complex iron oxide into simpler form. Therefore, pre-reduction of ilmenite concentrate is essential to minimize the energy consumption during thermal plasma process. Thermal plasma processing of ilmenite for the production of titania rich slag is considered to be the direct route to meet the current demand of industrial needs of titanium. Titania rich slag contains 70-80% TiO2 as the major component with some other minor impurities, like oxide phases of Si, Al, Cr, Mg, Mn, Ca, etc. Usually titanium is present in tetravalent forms with globular metallic iron in the slag. Titania rich slag undergoes leaching for the removal of iron and transforming the slag into synthetic rutile having 85-95% of TiO2.

  12. Kinetic study of solid phase crystallisation of expanding thermal plasma deposited a-Si:H

    Energy Technology Data Exchange (ETDEWEB)

    Law, F., E-mail: felixlaw@nus.edu.sg [Solar Energy Research Institute of Singapore (SERIS), National University of Singapore (Singapore); Department of Materials Science and Engineering, Faculty of Engineering, National University of Singapore (Singapore); Hoex, B. [Solar Energy Research Institute of Singapore (SERIS), National University of Singapore (Singapore); Wang, J. [Department of Materials Science and Engineering, Faculty of Engineering, National University of Singapore (Singapore); Luther, J. [Solar Energy Research Institute of Singapore (SERIS), National University of Singapore (Singapore); Department of Materials Science and Engineering, Faculty of Engineering, National University of Singapore (Singapore); Sharma, K.; Creatore, M.; Van de Sanden, M.C.M. [Department of Applied Physics, Eindhoven University of Technology, Eindhoven (Netherlands)

    2012-06-30

    In-situ X-ray diffraction was used to study the dynamics of the solid phase crystallisation (SPC) of hydrogenated amorphous silicon (a-Si:H) films deposited by expanding thermal plasma technique. The Johnson-Mehl-Avrami-Kolmogorov model was used for the analysis of the dynamic data and the activation energy associated with the SPC process was 2.9 eV, which was lower than a-Si:H films deposited by other techniques. Relationships between the Avrami exponent n, the SPC process stability and the subsequent grain structure were demonstrated. Under certain conditions, the films exhibited columnar grain structure with indications of good grain quality, suggesting that these films are suitable to be further developed into solar cell devices. Structure of the grains and the SPC dynamics in this work lend support to prior work that vacancies decorated by hydrogen clusters are related to nucleation sites. - Highlights: Black-Right-Pointing-Pointer The crystallisation of expanding thermal plasma (ETP) deposited a-Si:H was studied. Black-Right-Pointing-Pointer Johnson-Mehl-Avrami-Kolmogorov model was used to model the crystallisation process. Black-Right-Pointing-Pointer Activation energy of the solid phase crystallisation process was 2.9 eV. Black-Right-Pointing-Pointer Vacancies decorated by hydrogen clusters are suggested nucleation sites. Black-Right-Pointing-Pointer ETP is promising in the fabrication process of pc-Si thin film solar cells.

  13. Calculation of thermodynamic and transport properties of thermal plasmas based on the Cantera software toolkit

    Science.gov (United States)

    Doiron, Charles; Hencken, Kai

    2013-09-01

    Computational fluid-dynamic simulations nowadays play a central role in the development of new gas circuit breakers. For these simulations to be reliable, a good knowledge of the pressure and temperature-dependence of the thermodynamic and transport properties of ionized gases is required. A key ingredient in the calculation of thermodynamic properties of thermal plasmas is the calculation of the chemical equilibrium composition of the gas. The general-purpose, open-source software toolkit Cantera provides most functionality required to carry out such thermodynamic calculations. In this contribution, we explain how we tailored Cantera specifically to calculate material properties of plasmas. The highly modular architecture of this framework made it possible to add support for Debye-Hückel non-ideality corrections in the calculation of the chemical equilibrium mixture, as well as to enable the calculation of the key transport parameters needed in CFD-based electric arc simulations: electrical and thermal conductivity, viscosity, and diffusion coefficients. As an example, we discuss the thermodynamic and transport properties of mixtures of carbon dioxide and copper vapor.

  14. Artificial Retina Project: Electromagnetic and Thermal Effects

    Energy Technology Data Exchange (ETDEWEB)

    Lazzi, Gianluca

    2014-08-29

    This award supported the investigation on electromagnetic and thermal effects associated with the artificial retina, designed in collaboration with national laboratories, universities, and private companies. Our work over the two years of support under this award has focused mainly on 1) Design of new telemetry coils for optimal power and data transfer between the implant and the external device while achieving a significant size reduction with respect to currently used coils; 2) feasibility study of the virtual electrode configuration 3) study the effect of pulse shape and duration on the stimulation efficacy.

  15. Fetal thermal effects of diagnostic ultrasound.

    Science.gov (United States)

    Abramowicz, Jacques S; Barnett, Stanley B; Duck, Francis A; Edmonds, Peter D; Hynynen, Kullervo H; Ziskin, Marvin C

    2008-04-01

    Processes that can produce a biological effect with some degree of heating (ie, about 1 degrees C above the physiologic temperature) act via a thermal mechanism. Investigations with laboratory animals have documented that pulsed ultrasound can produce elevations of temperature and damage in biological tissues in vivo, particularly in the presence of bone (intracranial temperature elevation). Acoustic outputs used to induce these adverse bioeffects are within the diagnostic range, although exposure times are usually considerably longer than in clinical practice. Conditions present in early pregnancy, such as lack of perfusion, may favor bioeffects. Thermally induced teratogenesis has been shown in many animal studies, as well as several controlled human studies; however, human studies have not shown a causal relationship between diagnostic ultrasound exposure during pregnancy and adverse biological effects to the fetus. All human epidemiologic studies, however, were conducted with commercially available devices predating 1992, that is, with acoustic outputs not exceeding a spatial-peak temporal-average intensity of 94 mW/cm2. Current limits in the United States allow a spatial-peak temporal-average intensity of 720 mW/cm2 for fetal applications. The synergistic effect of a raised body temperature (febrile status) and ultrasound insonation has not been examined in depth. Available evidence, experimental or epidemiologic, is insufficient to conclude that there is a causal relationship between obstetric diagnostic ultrasound exposure and obvious adverse thermal effects to the fetus. However, very subtle effects cannot be ruled out and indicate a need for further research, although research in humans may be extremely difficult to realize.

  16. PIC Simulations of the Effect of Velocity Space Instabilities on Electron Viscosity and Thermal Conduction

    Science.gov (United States)

    Riquelme, Mario A.; Quataert, Eliot; Verscharen, Daniel

    2016-06-01

    In low-collisionality plasmas, velocity-space instabilities are a key mechanism providing an effective collisionality for the plasma. We use particle-in-cell (PIC) simulations to study the interplay between electron- and ion-scale velocity-space instabilities and their effect on electron pressure anisotropy, viscous heating, and thermal conduction. The adiabatic invariance of the magnetic moment in low-collisionality plasmas leads to pressure anisotropy, {{Δ }}{p}j\\equiv {p}\\perp ,j-{p}\\parallel ,j\\gt 0, if the magnetic field {\\boldsymbol{B}} is amplified ({p}\\perp ,j and {p}\\parallel ,j denote the pressure of species j (electron, ion) perpendicular and parallel to {\\boldsymbol{B}}). If the resulting anisotropy is large enough, it can in turn trigger small-scale plasma instabilities. Our PIC simulations explore the nonlinear regime of the mirror, IC, and electron whistler instabilities, through continuous amplification of the magnetic field | {\\boldsymbol{B}}| by an imposed shear in the plasma. In the regime 1≲ {β }j≲ 20 ({β }j\\equiv 8π {p}j/| {\\boldsymbol{B}}{| }2), the saturated electron pressure anisotropy, {{Δ }}{p}{{e}}/{p}\\parallel ,{{e}}, is determined mainly by the (electron-lengthscale) whistler marginal stability condition, with a modest factor of ˜1.5-2 decrease due to the trapping of electrons into ion-lengthscale mirrors. We explicitly calculate the mean free path of the electrons and ions along the mean magnetic field and provide a simple physical prescription for the mean free path and thermal conductivity in low-collisionality β j ≳ 1 plasmas. Our results imply that velocity-space instabilities likely decrease the thermal conductivity of plasma in the outer parts of massive, hot, galaxy clusters. We also discuss the implications of our results for electron heating and thermal conduction in low-collisionality accretion flows onto black holes, including Sgr A* in the Galactic Center.

  17. Study on the effects of physical plasma on in-vitro cultivates cells; Untersuchungen zum Einfluss von physikalischem Plasma auf in vitro kultivierte Zellen

    Energy Technology Data Exchange (ETDEWEB)

    Strassenburg, Susanne

    2014-03-15

    This study focused on the interactions of non thermal atmospheric pressure plasma on in vitro cultured keratinocytes (HaCaT keratinocytes) and melanoma cells (MV3). Three different plasma sources were used: a plasma jet (kINPen 09), a surface DBD (dielectric barrier discharge) and a volume DBD. For analyzing basic effects of plasma on cells, influence of physical plasma on viability, on DNA and on induction of ROS were investigated. Following assays were used: -- Viability: - neutral red uptake assay, cell counting (number of viable cells, cell integrity) - BrdU assay (proliferation) - Annexin V and propidium iodide staining, flow cytometry (induction of apoptosis), -- DNA: - alkaline comet assay (detection of DNA damage) - staining of DNA with propidium iodide, flow cytometry (cell cycle analysis), -- ROS: - H2DCFDA assay, flow cytometry (detection of ROS-positive cells). In addition to the effects which where induced by the plasma sources, the influence of the plasma treatment regime (direct, indirect and direct with medium exchange), the working gas (argon, air) and the surrounding liquids (cell culture medium: RPMI, IMDM; buffer solutions: HBSS, PBS) on the extent of the plasma cell effects were investigated. All plasma sources induced treatment time-dependent effects in HaCaT keratinocytes and melanoma cells (MV3): - loss of viable cells and reduced proliferation - induction of apoptosis after the longest treatment times - DNA damage 1 h after plasma treatment, 24 h after plasma treatment DNA damage was present only after the longest treatment times, evidence for DNA damage repair - due to accumulation of cells in G2/M phase, cell count in G1 phase (24 h) is lower - increase of ROS-positive cells 1 h and 24 h after plasma treatment. It was shown that cells which were cultured in RPMI showed stronger effects (stronger loss of viability and more DNA damage) than cells which were cultured in IMDM. Also plasma-treated buffer solutions (HBSS, PBS) induced DNA

  18. Pyrite-enhanced methylene blue degradation in non-thermal plasma water treatment reactor

    Energy Technology Data Exchange (ETDEWEB)

    Benetoli, Luis Otavio de Brito, E-mail: luskywalcker@yahoo.com.br [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Cadorin, Bruno Mena; Baldissarelli, Vanessa Zanon [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Geremias, Reginaldo [Departamento de Ciencias Rurais, Universidade Federal de Santa Catarina (UFSC), Curitibanos, SC (Brazil); Goncalvez de Souza, Ivan [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Debacher, Nito Angelo, E-mail: debacher@qmc.ufsc.br [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2012-10-30

    Highlights: Black-Right-Pointing-Pointer We use O{sub 2} as the feed gas and pyrite was added to the non-thermal plasma reactor. Black-Right-Pointing-Pointer The methylene blue removal by NTP increased in the presence of pyrite. Black-Right-Pointing-Pointer The total organic carbon content decreased substantially. Black-Right-Pointing-Pointer The acute toxicity test showed that the treated solution is not toxic. Black-Right-Pointing-Pointer The dye degradation occurs via electron impact as well as successive hydroxylation. - Abstract: In this study, methylene blue (MB) removal from an aqueous phase by electrical discharge non-thermal plasma (NTP) over water was investigated using three different feed gases: N{sub 2}, Ar, and O{sub 2}. The results showed that the dye removal rate was not strongly dependent on the feed gas when the electrical current was kept the same for all gases. The hydrogen peroxide generation in the water varied according to the feed gas (N{sub 2} < Ar < O{sub 2}). Using O{sub 2} as the feed gas, pyrite was added to the reactor in acid medium resulting in an accentuated increase in the dye removal, which suggests that pyrite acts as a Fenton-like catalyst. The total organic carbon (TOC) content of the dye solution decreased slightly as the plasma treatment time increased, but in the presence of the pyrite catalyst the TOC removal increased substantially. The acute toxicity test using Artemia sp. microcrustaceans showed that the treated solution is not toxic when Ar, O{sub 2} or O{sub 2}-pyrite is employed. Electrospray ionization mass spectrometry analysis (ESI-MS) of the treated samples indicated that the dye degradation occurs via high energy electron impact as well as successive hydroxylation in the benzene rings of the dye molecules.

  19. Mathematical analysis of thermoelastic characteristics in plasma-sprayed thermal barrier coatings.

    Science.gov (United States)

    Go, Jaegwi; Jungo, Yeon-Gil; Kim, Seokchan; Ali, Md Afsar; Paik, Ungyu

    2012-02-01

    The thermoelastic characteristics of plasma-sprayed thermal barrier coatings (TBCs) have been analyzed using mathematical modeling. Two types of TBC model, cylinder and circular disk which are commercial plasma-sprayed TBCs, subjecting to symmetric temperature distribution to the radial and longitudinal directions, respectively, were taken into consideration. Based on the thermoelastic theories, a second order ordinary differential equation was derived for the cylinder model and a pair of partial differential equations were set up for the circular disk model. The analytic solution was obtained from the ordinary differential equation, while a finite volume method was developed for numerical solutions to the pair of partial differential equations due to the complexity of governing equations. The thermoelastic characteristics of TBC models, such as temperature distributions, displacements, and stresses, were displayed according to the obtained solutions. The rate of heat conduction in the section of the top coat is relatively slow in comparison with the substrate, and no profound difference appears in the temperature distribution between two TBC models. The highest longitudinal tensile stress is expressed at the bond coat of both models, and the substrate is under the compressive stresses to the circumferential direction. While the cylinder expands to the positive longitudinal direction only, the expansion in the circular disk occurs to both the positive and negative longitudinal directions. Relatively large displacement and stresses exhibit in the cylinder as compared with the circular disk. In the circular disk, the stresses to the radial direction undulate at each section, and the displacement profile displays that the width of the circular disk is slightly narrowed. The results demonstrate that the mechanical and thermal properties of the top and bond coats are the crucial factors to be considered in controlling the thermoelastic characteristics of plasma

  20. Negative ion beam formation using thermal contact ionization type plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Fukuura, Yoshiyuki; Murakami, Kazutugu; Masuoka, Toshio; Katsumata, Itsuo [Osaka City Univ. (Japan). Faculty of Engineering

    1997-02-01

    The small ion sources utilizing thermal ionization have been already developed, and at present, in order to increase ion yield, that being developed to the cylindrical plasma prototype having the inner surface of a Re foil cylinder as the ionization surface, and stably functioning at 3,000 K has been developed, and by using this plasma source, the research on the formation of various ions has been carried out. At present, the research on the formation of Li negative ion beam is carried out. The separation of negative ions from electrons is performed with the locally limited magnetic field using a small iron core electromagnet placed behind the electrostatic accelerating lens system. So for, the formation of about 2 {mu}A at maximum of negative ions was confirmed. It was decided to identify the kinds of ions by time of flight (TOF) process, and the various improvements for this purpose were carried out. The experimental setup, the structure of the plasma source, the circuits for TOF measurement and so on are explained. The experimental results are reported. The problems are the possibility of the formation of alkali metals, the resolution of the time axis of the TOF system and so on. (K.I.)

  1. Thermal plasma processed ferro-magnetically ordered face-centered cubic iron at room temperature

    Energy Technology Data Exchange (ETDEWEB)

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Mathe, V. L., E-mail: vlmathe@physics.unipune.ac.in [Department of Physics, Savitribai Phule Pune University, Pune 411007 (India); Das, A. K. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)

    2014-10-28

    Here, we report tailor made phase of iron nanoparticles using homogeneous gas phase condensation process via thermal plasma route. It was observed that crystal lattice of nano-crystalline iron changes as a function of operating parameters of the plasma reactor. In the present investigation iron nanoparticles have been synthesized in presence of argon at operating pressures of 125–1000 Torr and fixed plasma input DC power of 6 kW. It was possible to obtain pure fcc, pure bcc as well as the mixed phases for iron nanoparticles in powder form as a function of operating pressure. The as synthesized product was characterized for understanding the structural and magnetic properties by using X-ray diffraction, vibrating sample magnetometer, and Mössbauer spectroscopy. The data reveal that fcc phase is ferromagnetically ordered with high spin state, which is unusual whereas bcc phase is found to be ferromagnetic as usual. Finally, the structural and magnetic properties are co-related.

  2. Physical effects of thermal pollution in lakes

    Science.gov (United States)

    Râman Vinnâ, Love; Wüest, Alfred; Bouffard, Damien

    2017-05-01

    Anthropogenic heat emissions into inland waters influence water temperature and affect stratification, heat and nutrient fluxes, deep water renewal, and biota. Given the increased thermal stress on these systems by growing cooling demands of riparian/coastal infrastructures in combination with climate warming, the question arises on how to best monitor and manage these systems. In this study, we investigate local and system-wide physical effects on the medium-sized perialpine Lake Biel (Switzerland), influenced by point-source cooling water emission from an upstream nuclear power plant (heat emission ˜700 MW, ˜18 W m-2 lake wide). We use one-dimensional (SIMSTRAT) and three-dimensional (Delft3D-Flow) hydrodynamic numerical simulations and provide model resolution guidelines for future studies of thermal pollution. The effects on Lake Biel by the emitted excess heat are summarized as: (i) clear seasonal trend in temperature increase, locally up to 3.4°C and system-wide volume mean ˜0.3°C, which corresponds to one decade of regional surface water climate warming; (ii) the majority of supplied thermal pollution (˜60%) leaves this short residence time (˜58 days) system via the main outlet, whereas the remaining heat exits to the atmosphere; (iii) increased length of stratified period due to the stabilizing effects of additional heat; (iv) system-wide effects such as warmer temperature, prolonged stratified period, and river-caused epilimnion flushing are resolved by both models whereas local raised temperature and river short circuiting was only identifiable with the three-dimensional model approach. This model-based method provides an ideal tool to assess man-made impacts on lakes and their downstream outflows.

  3. Effect of wave localization on plasma instabilities

    Energy Technology Data Exchange (ETDEWEB)

    Levedahl, W.K.

    1987-01-01

    The Anderson model of wave localization in random media is invoked to study the effect of solar-wind density turbulence on plasma processes associated with the solar type-III radio burst. ISEE-3 satellite data indicate that a possible model for the type-III process is the parametric decay of Langmuir waves excited by solar-flare electron streams into daughter electromagnetic and ion-acoustic waves. The threshold for this instability, however, is much higher than observed Langmuir-wave levels because of rapid wave convection of the transverse electromagnetic daughter wave in the case where the solar wind is assumed homogeneous. Langmuir and transverse waves near critical density satisfy the Ioffe-Riegel criteria for wave localization in the solar wind with observed density fluctuations {approximately}1%. Computer simulations using a linearized hybrid code show that an electron beam will excite localized Langmuir waves in a plasma with density turbulence. An action-principle approach is used to develop a theory of nonlinear wave processes when waves are localized. A theory of resonant particles diffusion by localized waves is developed to explain the saturation of the beam-plasma instability.

  4. Effects of dietary turmeric supplementation on plasma lipoproteins ...

    African Journals Online (AJOL)

    Effects of dietary turmeric supplementation on plasma lipoproteins, meat quality and fatty acid composition in broilers. ... dietary supplementation of turmeric rhizome powder (TRP) on plasma lipoprotein concentrations, and the ... Article Metrics.

  5. Experimental Validation of an Electromagnet Thermal Design Methodology for Magnetized Dusty Plasma Research

    Science.gov (United States)

    Birmingham, W. J.; Bates, E. M.; Romero-Talamás, C. A.; Rivera, W. F.

    2016-10-01

    An analytic thermal design method developed to aid in the engineering design of Bitter-type magnets, as well as finite element calculations of heat transfer, are compared against experimental measurements of temperature evolution in a prototype magnet designed to operate continuously at 1 T fields while dissipating 9 kW of heat. The analytic thermal design method is used to explore a variety of configurations of cooling holes in the Bitter plates, including their geometry and radial placement. The prototype has diagnostic ports that can accommodate thermocouples, pressure sensors, and optical access to measure the water flow. We present temperature and pressure sensor data from the prototype compared to the analytic thermal model and finite element calculations. The data is being used to guide the design of a 10 T Bitter magnet capable of sustained fields of up to 10 T for at least 10 seconds, which will be used in dusty plasma experiments at the University of Maryland Baltimore County. Preliminary design plans and progress towards the construction of the 10 T electromagnet are also presented.

  6. Quark production, Bose-Einstein condensates and thermalization of the quark-gluon plasma

    CERN Document Server

    Blaizot, Jean-Paul; Yan, Li

    2014-01-01

    In this paper, we study the thermalization of gluons and N_f flavors of massless quarks and antiquarks in a spatially homogeneous system. First, two coupled transport equations for gluons and quarks (and antiquarks) are derived within the diffusion approximation of the Boltzmann equation, with only 2 2 processes included in the collision term. Then, these transport equations are solved numerically in order to study the thermalization of the quark-gluon plasma. At initial time, we assume that no quarks or antiquarks are present and we choose the gluon distribution in the form f = f_0 theta (1-p/Q_s) with Q_s the saturation momentum and f_0 a constant. The subsequent evolution of systems may, or may not, lead to the formation of a (transient) Bose condensate, depending on the value of f_0. In fact, we observe, depending on the value of f_0, three different patterns: (a) thermalization without gluon Bose-Einstein condensate (BEC) for f_0 1 > f_{0c}, the onset of BEC occurs at a finite time t_c ~ 1/((alpha_s f_0...

  7. Weak phonon scattering effect of twin boundaries on thermal transmission.

    Science.gov (United States)

    Dong, Huicong; Xiao, Jianwei; Melnik, Roderick; Wen, Bin

    2016-01-29

    To study the effect of twin boundaries on thermal transmission, thermal conductivities of twinned diamond with different twin thicknesses have been studied by NEMD simulation. Results indicate that twin boundaries show a weak phonon scattering effect on thermal transmission, which is only caused by the additional twin boundaries' thermal resistance. Moreover, according to phonon kinetic theory, this weak phonon scattering effect of twin boundaries is mainly caused by a slightly reduced average group velocity.

  8. Weak phonon scattering effect of twin boundaries on thermal transmission

    OpenAIRE

    Huicong Dong; Jianwei Xiao; Roderick Melnik; Bin Wen

    2016-01-01

    To study the effect of twin boundaries on thermal transmission, thermal conductivities of twinned diamond with different twin thicknesses have been studied by NEMD simulation. Results indicate that twin boundaries show a weak phonon scattering effect on thermal transmission, which is only caused by the additional twin boundaries’ thermal resistance. Moreover, according to phonon kinetic theory, this weak phonon scattering effect of twin boundaries is mainly caused by a slightly reduced averag...

  9. Seed disinfection effect of atmospheric pressure plasma and low pressure plasma on Rhizoctonia solani.

    Science.gov (United States)

    Nishioka, Terumi; Takai, Yuichiro; Kawaradani, Mitsuo; Okada, Kiyotsugu; Tanimoto, Hideo; Misawa, Tatsuya; Kusakari, Shinichi

    2014-01-01

    Gas plasma generated and applied under two different systems, atmospheric pressure plasma and low pressure plasma, was used to investigate the inactivation efficacy on the seedborne pathogenic fungus, Rhizoctonia solani, which had been artificially introduced to brassicaceous seeds. Treatment with atmospheric plasma for 10 min markedly reduced the R. solani survival rate from 100% to 3% but delayed seed germination. The low pressure plasma treatment reduced the fungal survival rate from 83% to 1.7% after 10 min and the inactivation effect was dependent on the treatment time. The seed germination rate after treatment with the low pressure plasma was not significantly different from that of untreated seeds. The air temperature around the seeds in the low pressure system was lower than that of the atmospheric system. These results suggested that gas plasma treatment under low pressure could be effective in disinfecting the seeds without damaging them.

  10. Temperature diagnostics of a non-thermal plasma jet at atmospheric pressure

    Science.gov (United States)

    Schäfer, Jan

    2013-09-01

    The study reflects the concept of the temperature as a physical quantity resulting from the second thermodynamic law. The reliability of different approaches of the temperature diagnostics of open non-equilibrium systems is discussed using examples of low temperature atmospheric pressure discharges. The focus of this work is a miniaturized non-thermal atmospheric pressure plasma jet for local surface treatment at ambient atmosphere. The micro-discharge is driven with a capacitively coupled radio frequency electric field at 27.12 MHz and fed with argon at rates of about 1 slm through the capillary with an inner diameter of 4 mm. The discharge consists of several contracted filaments with diameter around 300 μm which are rotating azimuthally in the capillary in a self-organized manner. While the measured temperatures of the filament core exceed 700 K, the heat impact on a target below the plasma jet remains limited leading to target temperatures below 400 K. Different kinds of temperatures and energy transport processes are proposed and experimentally investigated. Nevertheless, a reliable and detailed temperature diagnostics is a challenge. We report on a novel diagnostics approach for the spatially and temporally resolved measurement of the gas temperature based on the optical properties of the plasma. Laser Schlieren Deflectometry is adapted to explore temperature profiles of filaments and their behaviour. In parallel, the method demonstrates a fundamental Fermat's principle of minimal energy. Information acquired with this method plays an important role for the optimization of local thin film deposition and surface functionalization by means of the atmospheric pressure plasma jet. The work was supported in part by the Deutsche Forschungsgemeinschaft within SFB-TR 24.

  11. EDITORIAL: Atmospheric pressure non-thermal plasmas for processing and other applications

    Science.gov (United States)

    Massines, Françoise

    2005-02-01

    Interest has grown over the past few years in applying atmospheric pressure plasmas to plasma processing for the benefits this can offer to existing and potential new processes, because they do not require expensive vacuum systems and batch processing. There have been considerable efforts to efficiently generate large volumes of homogeneous atmospheric pressure non-thermal plasmas to develop environmentally friendly alternatives for surface treatment, thin film coating, sterilization, decontamination, etc. Many interesting questions have arisen that are related to both fundamental and applied research in this field. Many concern the generation of a large volume discharge which remains stable and uniform at atmospheric pressure. At this pressure, depending on the experimental conditions, either streamer or Townsend breakdown may occur. They respectively lead to micro-discharges or to one large radius discharge, Townsend or glow. However, the complexity arises from the formation of large radius streamers due to avalanche coupling and from the constriction of the glow discharge due to too low a current. Another difficulty is to visually distinguish many micro-discharges from one large radius discharge. Other questions relate to key chemical reactions in the plasma and at the surface. Experimental characterization and modelling also need to be developed to answer these questions. This cluster collects up-to-date research results related to the understanding of different discharges working at atmospheric pressure and the application to polymer surface activation and thin film coating. It presents different solutions for generating and sustaining diffuse discharges at atmospheric pressure. DC, low-frequency and radio-frequency excitations are considered in noble gases, nitrogen or air. Two specific methods developed to understand the transition from Townsend to streamer breakdown are also presented. They are based on the cross-correlation spectroscopy and an electrical

  12. Monitoring Delamination of Plasma-Sprayed Thermal Barrier Coatings by Reflectance-Enhanced Luminescence

    Science.gov (United States)

    Eldridge, Jeffrey I.; Bencic, Timothy J.

    2006-01-01

    Highly scattering plasma-sprayed thermal barrier coatings (TBCs) present a challenge for optical diagnostic methods to monitor TBC delamination because scattering attenuates light transmitted through the TBC and usually degrades contrast between attached and delaminated regions of the TBC. This paper presents a new approach where reflectance-enhanced luminescence from a luminescent sublayer incorporated along the bottom of the TBC is used to identify regions of TBC delamination. Because of the higher survival rate of luminescence reflecting off the back surface of a delaminated TBC, the strong scattering exhibited by plasma-sprayed TBCs actually accentuates contrast between attached and delaminated regions by making it more likely that multiple reflections of luminescence off the back surface occur before exiting the top surface of the TBC. A freestanding coating containing sections designed to model an attached or delaminated TBC was prepared by depositing a luminescent Eu-doped or Er-doped yttria-stabilized zirconia (YSZ) luminescent layer below a plasma-sprayed undoped YSZ layer and utilizing a NiCr backing layer to represent an attached substrate. For specimens with a Eu-doped YSZ luminescent sublayer, luminescence intensity maps showed excellent contrast between unbacked and NiCr-backed sections even at a plasma-sprayed overlayer thickness of 300 m. Discernable contrast between unbacked and NiCr-backed sections was not observed for specimens with a Er-doped YSZ luminescent sublayer because luminescence from Er impurities in the undoped YSZ layer overwhelmed luminescence originating form the Er-doped YSZ sublayer.

  13. Mobile setup for synchrotron based in situ characterization during thermal and plasma-enhanced atomic layer deposition

    Science.gov (United States)

    Dendooven, Jolien; Solano, Eduardo; Minjauw, Matthias M.; Van de Kerckhove, Kevin; Coati, Alessandro; Fonda, Emiliano; Portale, Giuseppe; Garreau, Yves; Detavernier, Christophe

    2016-11-01

    We report the design of a mobile setup for synchrotron based in situ studies during atomic layer processing. The system was designed to facilitate in situ grazing incidence small angle x-ray scattering (GISAXS), x-ray fluorescence (XRF), and x-ray absorption spectroscopy measurements at synchrotron facilities. The setup consists of a compact high vacuum pump-type reactor for atomic layer deposition (ALD). The presence of a remote radio frequency plasma source enables in situ experiments during both thermal as well as plasma-enhanced ALD. The system has been successfully installed at different beam line end stations at the European Synchrotron Radiation Facility and SOLEIL synchrotrons. Examples are discussed of in situ GISAXS and XRF measurements during thermal and plasma-enhanced ALD growth of ruthenium from RuO4 (ToRuS™, Air Liquide) and H2 or H2 plasma, providing insights in the nucleation behavior of these processes.

  14. Comparison of CO{2} laser and atmospheric plasma treatments on thermal stability and structural modifications of microporous poly(vinyl chloride)/Silica composites

    Science.gov (United States)

    Becker, C.; Etienne, S.; Bour, J.; Ruch, D.; Aubriet, F.

    2008-09-01

    Several ways using surface modification are commonly used to enhance thermal stability of polymer matrices. In this study, Continuous-Wave carbon dioxide (CW CO{2}) laser irradiation and atmospheric pressure non-thermal He plasma treatment on microporous poly(vinyl chlo-ride)/Silica composite have been investigated and compared. On one hand the alternative was based on the efficiency of the thermal energy afforded by CW CO{2} laser irradiation and induced photodegradation processes to release HCl and form polyene sequences under well-controlled condition. On the other hand atmospheric plasma treatment involved surface modification by formation of unstable radicals, inducing crosslinking and dehydrochlorination. In both cases a global thermal stabilization of the composite was noticed by partial dehydrochlorination of PVC, even for short exposure time. The main effects observed after laser irradiation were related to the formation of a very dense structure on surface with very low chlorine content and an important chlorine atoms in-depth gradient on the cross section up to 150 μm in thickness; whereas atmospheric He plasma treatment led to a homogeneous decrease of the chlorine in-depth content due to the plasma interpenetration in the porous microstructure. Structural and chemical modifications both on extreme surface and in the thickness have been investigated respectively by Environmental Scanning Electron Microscope (ESEM) coupled with an Energy Dispersive X-ray analysis (EDX) and X-ray Photoelectron Spectroscopy (XPS). Composites thermal stability and investigation on chlorine release have been evaluated by Thermo Gravimetric Analysis (TGA) coupled with Mass Spectrometry (MS).

  15. Tungsten Micropowder/Copper Nanoparticle Core/Shell-Structured Composite Powder Synthesized by Inductively Coupled Thermal Plasma Process

    Science.gov (United States)

    Kim, Kyou-Hyun; Choi, Hanshin; Han, Chulwoong

    2017-01-01

    We here synthesized a Cu nanoparticle-coated W micropowder using in-situ reactive radio frequency thermal plasma with a blended feedstock of tungsten (W) and copper oxide micropowder. The spherical W micropowder improves the packing density and uniformity of the compacted body. On the other hand, the Cu nanoparticles coated on the W micropowder allow the spherical W powders to be compacted by rigid-die compaction only at 400 MPa. Moreover, homogeneous sintering in both solid state and liquid state occurs even at low Cu contents of 5 wt pct due to the uniformly coated Cu nanoparticles. The effect of W/Cu core/shell structure on the physical properties of sintered W-5 wt pct Cu composite is investigated based on the density, resistivity, and hardness. The results show that homogeneously sintered W-5 wt pct Cu composite well agree with the theoretical values calculated from the rule of mixture.