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Sample records for pipes mechanical corrosion

  1. Mechanism of selective corrosion in electrical resistance seam welded carbon steel pipe

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Fajardo, Pedro; Godinez Salcedo, Jesus; Gonzalez Velasquez, Jorge L. [Instituto Politecnico Nacional, Mexico D.F., (Mexico). Escuela Superior de Ingenieria Quimica e Industrias Extractivas. Dept. de Ingenieria Metalurgica

    2009-07-01

    In this investigation the studies of the mechanism of selective corrosion in electrical resistance welded (ERW) carbon steel pipe was started. Metallographic characterizations and evaluations for inclusions were performed. The susceptibility of ERW pipe to selective corrosion in sea water (NACE 1D182, with O{sub 2} or CO{sub 2} + H{sub 2}S) was studied by the stepped potential Potentiostatic electrochemical test method in samples of 1 cm{sup 3} (ASTM G5) internal surface of the pipe (metal base-weld). The tests were looking for means for predicting the susceptibility of ERW pipe to selective corrosion, prior to placing the pipeline in service. Manganese sulfide inclusions are observed deformed by the welding process and they are close to the weld centerline. A slight decarburization at the weld line is observed, and a distinct out bent fiber pattern remains despite the post-weld seam annealing. The microstructure of the weld region consists of primarily polygonal ferrite grains mixed with small islands of pearlite. It is possible to observe the differences of sizes of grain of the present phases in the different zones. Finally, scanning electron microscopic observation revealed that the corrosion initiates with the dissolution of MnS inclusions and with small crack between the base metal and ZAC. (author)

  2. Corrosion behavior in heat pipe

    Directory of Open Access Journals (Sweden)

    Anurak Rodbumrung

    2016-01-01

    Full Text Available The aim of this study was to perform life testing and determine the effect of working fluid on the corrosion of a heat pipe with a sintered wick. The heat pipe was made from a copper tube. The inner heat pipe was filled with 99.97% pure copper powder as a dendritic for the sintering process. The heat pipe had an outer diameter of 6 mm with a length of 200 mm, and distilled water and ethanol were the working fluids. The operating temperature at the evaporator was 125°C. The analysis consisted of using a scanning electron microscope, energy dispersive X-ray spectrometry and atomic absorption spectroscopy. The results of the scanning electron microscope and energy dispersive X-ray spectrometry analysis showed that the corrosion of the heat pipe was uniform. The result of the atomic absorption spectroscopy indicated that the concentration of the copper in the ethanol as the working fluid was greater than in the distilled water as the working fluid, and the highest concentration of copper particles in the ethanol was 22.7499 ppm or 0.0409 mg after testing for 3000 h. The concentration of copper was higher when the length of the life test increased due to corrosion of the heat pipe.

  3. Analysis of corrosion failure of petrochemical pipe elbow

    Institute of Scientific and Technical Information of China (English)

    LI Xiao-yan; L(U) Tao

    2005-01-01

    Corrosive failure is frequently found in petrochemical pipelines which may lead to the leakage of the pipes and even the shutdown of the system. However, the corrosion mechanism is still not well understood due to the complex service environment, e.g. the corrosive fluids and the long term operation at higher temperature. The corrosion behaviour of a petrochemical pipe elbow was evaluated via visual examination and microanalysis with optical microscope and scanning electron microscope(SEM) together with energy dispersive analysis X-ray (EDAX). The corresponding corrosion mechanisms, the combination of grain boundary attach and the crevice attach together with the flow-accelerated corrosion, were proposed consequently.

  4. Geothermal drill pipe corrosion test plan

    Energy Technology Data Exchange (ETDEWEB)

    Caskey, B.C.; Copass, K.S.

    1980-12-01

    Plans are presented for conducting a field test of drill pipe corrosion, comparing air and nitrogen as drilling fluids. This test will provide data for evaluating the potential of reducing geothermal well drilling costs by extending drill pipe life and reducing corrosion control costs. The 10-day test will take place during fall 1980 at the Baca Location in Sandoval County, New Mexico.

  5. External Corrosion of Pipes in District Heating Systems; Utvaendig korrosion paa fjaerrvaermeroer

    Energy Technology Data Exchange (ETDEWEB)

    Sund, Goeran [Det Norske Veritas, Stockholm (Sweden)

    2002-07-01

    Corrosion damages of pipes in district heating systems can occur both external and internal. The aim with this work has been to clarify external corrosion damages of pipes, and try to correlate the damages to the corrosivity of different soils and waters. For the analysis the Swedish District Heating Association's district heating system statistics has been used. The district heating system statistics shows that the cost for corrosion damages is high, and pipes older than 20 years have increased risk for corrosion. The knowledge about corrosion concerning steel poles and water pipes in soils can not be applied to external corrosion of steel pipes in district heating systems. The corrosion rate of steel poles in soils is low. The corrosion of steel pipes in district heating systems can locally give high rates, up to 0,5 mm/year. The mechanism for this type of corrosion is different compared to the corrosion mechanism of poles in soils. The temperature is higher and aggressive water, with road-salt and chloride content, falls in drops on the steel pipe, and impurities evaporate on the steel surface. These factors increase the corrosion rate. If the material thickness is 5 mm, fracture can occur in the pipe within ten years. The number of copper pipe corrosion damage is limited. The most determining corrosion factors of copper pipes are pH-value and impurities as chloride and sulphate in the water. Stainless steel pipes of type 304 can not be used in soils due to the risk of local corrosion. Higher alloyed stainless steels, with molybdenum and higher chromium content should be used. It is concluded that failures can occur due to external corrosion of steel pipes. This failure is expensive and can lead to human damage. One way to eliminate failures of steel pipes is to carry out risk analysis.

  6. Flow accelerated corrosion study in feeder pipes

    Energy Technology Data Exchange (ETDEWEB)

    Goyal, P.; Verma, V.; Singh, R.K. [Bhabha Atomic Research Centre, Mumbai (India). Reactor Safety Div.

    2014-11-15

    The Indian Pressurized Heavy Water Reactor (PHWR) core consists of a number of horizontal channels containing nuclear fuel bundles. Parallel coolant channels are connected to Inlet and Outlet header through feeder pipes. Coolant from Reactor Inlet Header is distributed to the coolant channels and after removing heat combines at Reactor Outlet Header. Due to space constraints the feeder pipes are joined to the channel with one or two elbows close to the end fittings of the coolant channels. The carbon steel feeder pipes carry high temperature fluid at higher velocity and are liable to undergo Flow Accelerated Corrosion (FAC). In the recent inspection it has been found that feeders having double elbow are more susceptible to FAC on the intrados of second elbow. But it was found that in some of the elbows maximum thinning due to FAC was observed on the intrados of the first elbow. Hence to resolve this, effect of first bend orientation with respect of upstream direction has been studied. Two different approaches are used for predicting the FAC rate from calculated value of wall shear stress by CFD. One method is based on evaluating of wear rate using Colburn analogy and the other using an empirical equation between wear rate and shear stress. In Colburn analogy, mass transfer coefficient is evaluated by knowing shear stress and equilibrium concentration. For a case study, wall shear stress obtained from k-ε turbulence model was compared with k-ω SST turbulence model and no appreciable change in the wall shear stress has been found. Hence for subsequent analysis k-ε turbulence model was chosen because large mesh size near to the surface (first layer thickness) is permitted due to higher y{sup +} value.

  7. Mexssub responds to shallow pipe corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Cajiga, A.; Perez, V.

    1996-04-01

    Mexssub recently came to the aid of the Mexican state-owned oil company Pemex to repair corrosion problems on a 36-inch sour gas pipeline located in the Atasta-Ciudad Pemex corridor. Mexssub began development of a sleeve system in 1982 in an effort to develop solutions for risers located in the Campeche Bay area. High operating temperatures of these risers was causing failures of the protective coating and accelerated corrosion to the riser at the splash zone. The sleeve system and flexible habitat developed by Mexssub during this research program allowed the repair of these risers in situ and without suspending production. The sleeve system developed by Mexssub is a welded oversize sleeve with a specially formulated epoxy resin injected into the annular space. The epoxy resin completely integrates the sleeve and the pipe, providing structural reinforcement. This technology was demonstrated to Pemex at the Mexssub testing facility in Lerma, Mexico in 1986. In 1987 the Mexssub Sleeve System was approved by the Mexican Petroleum Institute and actual field repairs were initiated. To date, Mexssub has made in excess of 72 repairs in situ without suspending production on risers up to 36-inch diameter. Additionally, the sleeve system has been installed on 50 new risers prior to their installation in the field.

  8. Mitigation of stress corrosion cracking in pressurized water reactor (PWR) piping systems using the mechanical stress improvement process (MSIP{sup R)} or underwater laser beam welding

    Energy Technology Data Exchange (ETDEWEB)

    Rick, Grendys; Marc, Piccolino; Cunthia, Pezze [Westinghouse Electric Company, LLC, New York (United States); Badlani, Manu [Nu Vision Engineering, New York (United States)

    2009-04-15

    A current issue facing pressurized water reactors (PWRs) is primary water stress corrosion cracking (PWSCC) of bi metallic welds. PWSCC in a PWR requires the presence of a susceptible material, an aggressive environment and a tensile stress of significant magnitude. Reducing the potential for SCC can be accomplished by eliminating any of these three elements. In the U.S., mitigation of susceptible material in the pressurizer nozzle locations has largely been completed via the structural weld overlay (SWOL) process or NuVision Engineering's Mechanical Stress Improvement Process (MSIP{sup R)}, depending on inspectability. The next most susceptible locations in Westinghouse designed power plants are the Reactor Vessel (RV) hot leg nozzle welds. However, a full SWOL Process for RV nozzles is time consuming and has a high likelihood of in process weld repairs. Therefore, Westinghouse provides two distinctive methods to mitigate susceptible material for the RV nozzle locations depending on nozzle access and utility preference. These methods are the MSIP and the Underwater Laser Beam Welding (ULBW) process. MSIP applies a load to the outside diameter of the pipe adjacent to the weld, imposing plastic strains during compression that are not reversed after unloading, thus eliminating the tensile stress component of SCC. Recently, Westinghouse and NuVision successfully applied MSIP on all eight RV nozzles at the Salem Unit 1 power plant. Another option to mitigate SCC in RV nozzles is to place a barrier between the susceptible material and the aggressive environment. The ULBW process applies a weld inlay onto the inside pipe diameter. The deposited weld metal (Alloy 52M) is resistant to PWSCC and acts as a barrier to prevent primary water from contacting the susceptible material. This paper provides information on the approval and acceptance bases for MSIP, its recent application on RV nozzles and an update on ULBW development.

  9. Demonstration and Validation of Corrosion-Mitigation Technologies for Mechanical Room Utility Piping and Cooling-Tower Pumps

    Science.gov (United States)

    2015-05-01

    ready to install using standard scissors. TBD Manufactured from silicone impregnated woven fiberglass cloth. Fits standard pipe and tubing sizes...this project. Furthermore, less work is involved in cleaning and repainting joints than replacing them, which is now estimated at $6,000,000

  10. Review Applications to Prevent Corrosion Reducing Gas Pipe Line

    Directory of Open Access Journals (Sweden)

    Mehrdad Setoudeh

    2012-10-01

    Full Text Available Corrosion is one of the major problems in the oil and gas industry is one that automatically allocates huge sums annually. Including ways to reduce corrosion of corrosion inhibitors is. Inhibiting substance that low amount is added to the system to slow or stop the chemical reaction does. When inhibitors of corrosion medium are added, the speed of corrosion decreases to zero takes. For the first time a deterrent mineral called arsenate sodium for inhibition steels carbon in oil wells was used to corrosion of CO2 prevented, but due to low yield was not satisfactory and therefore the other inhibitors were used. In the years 1945 to 1950 properties, excellent composition polar chain long was discovered. The discovery process of experiments related to organic inhibitors used in wells and pipes and oil Garza changed. This article examines the use of inhibitors to reduce corrosion in gas wells deals.

  11. Study of biofilm influenced corrosion on cast iron pipes in reclaimed water

    Science.gov (United States)

    Zhang, Haiya; Tian, Yimei; Wan, Jianmei; Zhao, Peng

    2015-12-01

    Biofilm influenced corrosion on cast iron pipes in reclaimed water was systemically studied using the weight loss method and electrochemical impedance spectroscopy (EIS). The results demonstrated that compared to sterile water, the existence of the biofilm in reclaimed water promoted the corrosion process significantly. The characteristics of biofilm on cast iron coupons were examined by the surface profiler, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The bacterial counts in the biofilm were determined using the standard plate count method and the most probable number (MPN). The results demonstrated that the corrosion process was influenced by the settled bacteria, EPS, and corrosion products in the biofilm comprehensively. But, the corrosion mechanisms were different with respect to time and could be divided into three stages in our study. Furthermore, several corresponding corrosion mechanisms were proposed for different immersion times.

  12. A Corrosion Risk Assessment Model for Underground Piping

    Science.gov (United States)

    Datta, Koushik; Fraser, Douglas R.

    2009-01-01

    The Pressure Systems Manager at NASA Ames Research Center (ARC) has embarked on a project to collect data and develop risk assessment models to support risk-informed decision making regarding future inspections of underground pipes at ARC. This paper shows progress in one area of this project - a corrosion risk assessment model for the underground high-pressure air distribution piping system at ARC. It consists of a Corrosion Model of pipe-segments, a Pipe Wrap Protection Model; and a Pipe Stress Model for a pipe segment. A Monte Carlo simulation of the combined models provides a distribution of the failure probabilities. Sensitivity study results show that the model uncertainty, or lack of knowledge, is the dominant contributor to the calculated unreliability of the underground piping system. As a result, the Pressure Systems Manager may consider investing resources specifically focused on reducing these uncertainties. Future work includes completing the data collection effort for the existing ground based pressure systems and applying the risk models to risk-based inspection strategies of the underground pipes at ARC.

  13. EVALUATION OF THE FLOW ACCELERATED CORROSION OF COPPER PIPES

    OpenAIRE

    Tatiana Liptáková; Pavol Fajnor; Alexander Dodek

    2010-01-01

    Corrosion behavior of the Cu pipe system has been investigated by long term experiment. The two identical experimental systems were made and fulfilled by the solution of 3 % NaCl. The work medium in the first system was flowing eight hour in day and in the second the medium was stagnant. The systems were subjected eight hour in day to temperature of 80°C. After eleven month the experiment was finished and the corrosion attack and character of corrosion products in the systems have been invest...

  14. EVALUATION OF THE FLOW ACCELERATED CORROSION OF COPPER PIPES

    Directory of Open Access Journals (Sweden)

    Tatiana Liptáková

    2010-12-01

    Full Text Available Corrosion behavior of the Cu pipe system has been investigated by long term experiment. The two identical experimental systems were made and fulfilled by the solution of 3 % NaCl. The work medium in the first system was flowing eight hour in day and in the second the medium was stagnant. The systems were subjected eight hour in day to temperature of 80°C. After eleven month the experiment was finished and the corrosion attack and character of corrosion products in the systems have been investigated by light and SEM microscopy, EIS tests and visually too.

  15. Erosion/Corrosion-Induced Pipe Wall Thinning in U.S. Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Wu, P. C. [US Nuclear Regulatory Commission (NRC), Washington, DC (United States). Division of Engineering and Systems Technology

    1989-04-01

    Erosion/corrosion in single-phase piping systems was not clearly recognized as a potential safety issue before the pipe rupture incident at the Surry Power Station in December 1986. This incident reminded the nuclear industry and the regulators that neither the U.S. Nuclear Regulatory Commission (NRC) nor Section XI of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code require utilities to monitor erosion/corrosion in the secondary systems of nuclear power plants. This report provides a brief review of the erosion/corrosion phenomenon and its major occurrences in nuclear power plants. In addition, efforts by the NRC, the industry, and the ASME Section XI Committee to address this issue are described. Finally, results of the survey and plant audits conducted by the NRC to assess the extent of erosion/corrosion-induced piping degradation and the status of program implementation regarding erosion/corrosion monitoring are discussed. This report will support a staff recommendation for an additional regulatory requirement concerning erosion/corrosion monitoring.

  16. Numerical simulation and factor analysis of petrochemical pipe erosion-corrosion failure

    Science.gov (United States)

    XU, G. F.; OU, G. F.; Chen, T.; Li, P. X.; JIN, H. Z.

    2016-05-01

    Based on the behavior of carbon steel outlet tube in REAC pipes of Zhenhai Refining & Chemical Company, the mathematical model of fluid-solid interaction was established according to the mechanism of erosion-corrosion damage. The interaction between corrosion products protecting film and multiphase liquid was analyzed by numerical simulation method. The distribution of shearing stress on the inwall of elbow bend, and the distribution of principal displacement, stress and strain of corrosion products protecting film were disclosed, while the erosion-corrosion failure processes was studied. The simulation result coincides with that of the positioned thickness gauging which validated the reliability and feasibility of the finite element analysis software simulation method. The obtained results can be used in the erosion-corrosion failure analysis, structural optimization, in-service testing positioning, life prediction, risk assessment, safety and other security projects for multiphase flow pipeline.

  17. 49 CFR 195.561 - When must I inspect pipe coating used for external corrosion control?

    Science.gov (United States)

    2010-10-01

    ... corrosion control? 195.561 Section 195.561 Transportation Other Regulations Relating to Transportation...) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Corrosion Control § 195.561 When must I inspect pipe coating used for external corrosion control? (a) You must inspect all external pipe...

  18. Speciation and distribution of vanadium in drinking water iron pipe corrosion by-products.

    Science.gov (United States)

    Gerke, Tammie L; Scheckel, Kirk G; Maynard, J Barry

    2010-11-01

    Vanadium (V) when ingested from drinking water in high concentrations (>15 μg L(-1)) is a potential health risk and is on track to becoming a regulated contaminant. High concentrations of V have been documented in lead corrosion by-products as Pb(5)(V(5+)O(4))(3)Cl (vanadinite) which, in natural deposits is associated with iron oxides/oxyhydroxides, phases common in iron pipe corrosion by-products. The extent of potential reservoirs of V in iron corrosion by-products, its speciation, and mechanism of inclusion however are unknown. The aim of this study is to assess these parameters in iron corrosion by-products, implementing synchrotron-based μ-XRF mapping and μ-XANES along with traditional physiochemical characterization. The morphologies, mineralogies, and chemistry of the samples studied are superficially similar to typical iron corrosion by-products. However, we found V present as discrete grains of Pb(5)(V(5+)O(4))(3)Cl likely embedded in the surface regions of the iron corrosion by-products. Concentrations of V observed in bulk XRF analysis ranged from 35 to 899 mg kg(-1). We calculate that even in pipes with iron corrosion by-products with low V concentration, 100 mg kg(-1), as little as 0.0027% of a 0.1-cm thick X 100-cm long section of that corrosion by-product needs to be disturbed to increase V concentrations in the drinking water at the tap to levels well above the 15 μg L(-1) notification level set by the State of California and could adversely impact human health. In addition, it is likely that large reservoirs of V are associated with iron corrosion by-products in unlined cast iron mains and service branches in numerous drinking water distribution systems.

  19. Corrosion resistance of 15Mo3 in steam boiler pipe surfaced with Inconel 625 alloy

    Energy Technology Data Exchange (ETDEWEB)

    Aracic, S.; Samardzic, I.; Krumes, D. [Mechanical Engineering Faculty, Trg Ivane Brlic Mazuranic 18, HR-35000 Slavonski Brod (Croatia)

    2004-07-01

    This paper presents accelerated laboratory corrosion resistant investigation results made on steam boiler 15Mo3 steel pipes surfaced with alloy Inconel 625. Surfacing of 15Mo3 pipes was made due to pipes corrosion resistance increase in exploitation conditions which are present in fire box of trash burning plant. Corrosion resistance investigations were made in fire box simulated atmosphere and in salt spray chamber. (authors)

  20. Corrosion risk assessment and comprehensive evaluation of ship sea water pipe systems

    Directory of Open Access Journals (Sweden)

    YANG Guangfu

    2017-05-01

    Full Text Available In order to propose a comprehensive corrosion risk evaluation model based on an analysis of the corrosion risk of sea water pipe systems of ships in service,the modes of potential corrosion and their causes were first analyzed by identifying the origins of the inner and outer corrosion of the sea water pipe systems. In accordance with the matrixes of corrosion occurrence possibility and corrosion risk consequence,a corrosion risk matrix was established for a sea water pipe system. The method for the quantitative evaluation value of each mode of corrosion possibly occurring in a sea water pipe system was then presented. The comprehensive evaluation model of the corrosion was first built using the Analytical Hierarchy Process(AHP,which can be used for the comprehensive corrosion evaluation. The results show that the comprehensive evaluation value will be expressed as the corrosion risk level and corrosion-induced consequence of the sea water pipe system. This will be very useful for accurately protecting the sea water pipe systems of ships in service from corrosion,thereby attaining the goals of economy,rationality and timeliness.

  1. The corrosion and corrosion mechanical properties evaluation for the LBB concept in VVERs

    Energy Technology Data Exchange (ETDEWEB)

    Ruscak, M.; Chvatal, P.; Karnik, D.

    1997-04-01

    One of the conditions required for Leak Before Break application is the verification that the influence of corrosion environment on the material of the component can be neglected. Both the general corrosion and/or the initiation and, growth of corrosion-mechanical cracks must not cause the degradation. The primary piping in the VVER nuclear power plant is made from austenitic steels (VVER 440) and low alloy steels protected with the austenitic cladding (VVER 1000). Inspection of the base metal and heterogeneous weldments from the VVER 440 showed that the crack growth rates are below 10 m/s if a low oxygen level is kept in the primary environment. No intergranular cracking was observed in low and high oxygen water after any type of testing, with constant or periodic loading. In the framework of the LBB assessment of the VVER 1000, the corrosion and corrosion mechanical properties were also evaluated. The corrosion and corrosion mechanical testing was oriented predominantly to three types of tests: stress corrosion cracking tests corrosion fatigue tests evaluation of the resistance against corrosion damage. In this paper, the methods used for these tests are described and the materials are compared from the point of view of response on static and periodic mechanical stress on the low alloyed steel 10GN2WA and weld metal exposed in the primary circuit environment. The slow strain rate tests and static loading of both C-rings and CT specimens were performed in order to assess the stress corrosion cracking characteristics. Cyclic loading of CT specimens was done to evaluate the kinetics of the crack growth under periodical loading. Results are shown to illustrate the approaches used. The data obtained were evaluated also from the point of view of comparison of the influence of different structure on the stress corrosion cracking appearance. The results obtained for the base metal and weld metal of the piping are presented here.

  2. A Framework for Estimating Piping Reliability Subject to Corrosion Under Insulation

    Directory of Open Access Journals (Sweden)

    Mokhtar Ainul Akmar

    2014-07-01

    Full Text Available Corrosion under insulation (CUI is one of the serious damage mechanisms experienced by insulated piping systems. Optimizing the inspection schedule for insulated piping systems is a major challenge faced by inspection and corrosion engineers since CUI takes place beneath the insulation which makes the detection and prediction of the damage mechanism harder. In recent years, risk-based inspection (RBI approach has been adopted to optimize CUI inspection plan. RBI approach is based on risk, a product of the likelihood of a failure and the consequence of such failure. The likelihood analysis usually follows either the qualitative or the semi-qualitative methods, thus precluding it to be used for quantitative risk assessment. This paper presents a framework for estimating quantitatively the likelihood of failure due to CUI based on the type of data available.

  3. Fracture mechanics evaluation for at typical PWR primary coolant pipe

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T. [Kansai Electric Power Company, Osaka (Japan); Shimizu, S.; Ogata, Y. [Mitsubishi Heavy Industries, Ltd., Kobe (Japan)

    1997-04-01

    For the primary coolant piping of PWRs in Japan, cast duplex stainless steel which is excellent in terms of strength, corrosion resistance, and weldability has conventionally been used. The cast duplex stainless steel contains the ferrite phase in the austenite matrix and thermal aging after long term service is known to change its material characteristics. It is considered appropriate to apply the methodology of elastic plastic fracture mechanics for an evaluation of the integrity of the primary coolant piping after thermal aging. Therefore we evaluated the integrity of the primary coolant piping for an initial PWR plant in Japan by means of elastic plastic fracture mechanics. The evaluation results show that the crack will not grow into an unstable fracture and the integrity of the piping will be secured, even when such through wall crack length is assumed to equal the fatigue crack growth length for a service period of up to 60 years.

  4. Corrosion Resistance of Zn and Cu Coated Steel Pipes as a Substitute for Cu Pipe in an Air Conditioner System

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jae Gyeong; Park, Chan Jin; Hong, Sung Kil [Chonnam National University, Gwangju (Korea, Republic of)

    2009-02-15

    We investigated the corrosion resistance of Zn and Cu coated steel pipes as a substitute for Cu pipe in an air-conditioner system. In addition, the galvanic corrosion tendency between two dissimilar metal parts was studied. The corrosion resistance of the Cu electroplated steel was similar to that of Cu, while the corrosion rate of the Zn electro-galvanized and the galvalume (Zn-55 % Al) coated steels was much higher and not suitable for Cu substitute in artificial sea water and acidic rain environments. Furthermore, the galvanic difference between Cu electroplated steel and Cu was so small that the Cu coated steel pipe can be used as a substitute for Cu pipe in an air-conditioner system.

  5. X60管线钢在盐碱性土壤中的腐蚀行为与机理%Corrosion behaviors and mechanism of X60 pipe steel in saline and alkali soil

    Institute of Scientific and Technical Information of China (English)

    黄亮亮; 孟惠民; 黄晓林; 陈建民; 胡景克; 王育青

    2013-01-01

    基于土壤性质检测,室内模拟实验,实际管道防腐层绝缘性测试、杂散电流测试,爆管处腐蚀形貌比较,管道埋地实际状况分析,研究了X60管线钢在黄河下游冲击平原土壤中的腐蚀行为.结果表明:黄河下游冲击平原土壤具有强碱、高含盐(主要为高NaCl)、高腐蚀性质;X60管线钢均匀腐蚀轻微,但会发生严重的坑腐蚀,腐蚀过程是:X60管线钢在水含量高甚至饱和的高含NaCl土壤中发生Fe氧化腐蚀反应,钢表面先形成含水FeOOH内腐蚀产物膜,腐蚀产物膜虽对基体具有一定的保护作用,但因Cl-渗入内腐蚀产物膜产生局部破坏,导致严重的坑腐蚀,并可能发展为爆管破坏.%In this paper, the corrosion behavior of X60 pipe steel is studied in the soil of alluvial plain downstream of the Yellow River based on soil property test, indoor simulation experiment, actual pipeline coating insulation test, stray current test and comparison of corrosion morphology at pipe bursting location, and actual buried situation of pipeline. Results show that the soil of alluvial plain downstream of the Yellow River is strong basic, high salt content (mainly including NaCl) and highly corrosive soil. For X60 pipe steel, uniform corrosion is slight but pit corrosion is serious, the corrosion process is that X60 pipe steel undergoes iron oxidation reaction in the soil with high water content even saturated water content and high NaCl content, an FeOOH inner corrosion product film containing water will firstly form on the steel surface and have certain protective functions against base material, but local damage may occur for inner corrosion product film due to Cl-penetration, and thus resulting in serious pit corrosion, which may develop into pipe bursting damage.

  6. Demonstration and Validation of Stainless Steel Materials for Critical Above Grade Piping in Highly Corrosive Locations

    Science.gov (United States)

    2017-05-01

    Prepared for Office of the Secretary of Defense (OUSD(AT&L)) Washington, DC 20301-3090 Under Project F07-AR15, “ Advanced Corrosion-Resistant Steel for...world for steel infrastruc- ture . Highly corroded carbon steel pipes at the site were replaced with two grades of stainless steel, and minor corrosion...mitigation modifications were made to pipe supports. After the rehabilitated system was commis- sioned, the pipes were inspected and tested according

  7. The Electrochemical Investigation of the Corrosion Rates of Welded Pipe ASTM A106 Grade B

    Directory of Open Access Journals (Sweden)

    Trinet Yingsamphancharoen

    2016-08-01

    Full Text Available The aim of this work was to investigate the corrosion rate of welded carbon steel pipe (ASTM (American Society for Testing and Materials A106 Grade B by GTAW under the currents of 60, 70, and 80 A. All welded pipes satisfied weld procedure specifications and were verified by a procedure qualification record. The property of used materials was in agreement with the ASME standard: section IX. The welded pipe was used for schematic model corrosion measurements applied in 3.5 wt % NaCl at various flow rates and analyzed by using the electrochemical technique with Tafel’s equation. The results showed the correlation between the flow rate and the corrosion rate of the pipe; the greater the flow rate, the higher corrosion rate. Moreover, the welded pipe from the welding current of 70 A exhibited higher tensile strength and corrosion resistance than those from currents of 60 and 80 A. It indicated that the welding current of 70 A produced optimum heat for the welding of A106 pipe grade B. In addition, the microstructure of the welded pipe was observed by SEM. The phase transformation and crystallite size were analyzed by XRD and Sherrer’s equation. The results suggested that the welding current could change the microstructure and phase of the welded pipe causing change in the corrosion rate.

  8. Corrosion performance of martensitic stainless steel seamless pipe for linepipe application

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Mitsuo; Miyata, Yukio; Toyooka, Takaaki; Murase, Fumio [Kawasaki Steel Corp., Handa, Aichi (Japan)

    1999-11-01

    The corrosion performance of two types of weldable martensitic stainless steel seamless pipe for pipeline application is investigated. 11Cr steel pipe developed for sweet environment gives better resistance to CO{sub 2} corrosion than the 13Cr martensitic stainless steel for OCTG. 12Cr steel pipe developed for light sour environment shows good SSC resistance in a mild sour environment and superior CO{sub 2} corrosion resistance at high temperature and high CO{sub 2} partial pressure condition. The suitable condition for the 11Cr steel pipe and the 12Cr steel pipe in sweet environment, and the critical pH and H{sub 2}S partial pressure for the 12Cr steel pipe welded joint in sour environment are clarified. Both welded joints have superior resistance to hydrogen embrittlement under the cathodic protection condition in sea water.

  9. Reeling of tight fit pipe

    NARCIS (Netherlands)

    Focke, E.S.

    2007-01-01

    If it would be possible to install Tight Fit Pipe by means of reeling, it would be an attractive new option for the exploitation of offshore oil and gas fields containing corrosive hydrocarbons. Tight Fit Pipe is a mechanically bonded double walled pipe where a corrosion resistant alloy liner pipe

  10. Characterization of corrosion scale formed on stainless steel delivery pipe for reclaimed water treatment.

    Science.gov (United States)

    Cui, Yong; Liu, Shuming; Smith, Kate; Yu, Kanghua; Hu, Hongying; Jiang, Wei; Li, Yuhong

    2016-01-01

    To reveal corrosion behavior of stainless steel delivery pipe used in reclaimed water treatment, this research focused on the morphological, mineralogical and chemical characteristics of stainless steel corrosion scale and corroded passive film. Corrosion scale and coupon samples were taken from a type 304 pipe delivering reclaimed water to a clear well in service for more than 12 years. Stainless steel corrosion scales and four representative pipe coupons were investigated using mineralogy and material science research methods. The results showed corrosion scale was predominantly composed of goethite, lepidocrocite, hematite, magnetite, ferrous oxide, siderite, chrome green and chromite, the same as that of corroded pipe coupons. Hence, corrosion scale can be identified as podiform chromite deposit. The loss of chromium in passive film is a critical phenomenon when stainless steel passive film is damaged by localized corrosion. This may provide key insights toward improving a better comprehension of the formation of stainless steel corrosion scale and the process of localized corrosion. The localized corrosion behavior of stainless steel is directly connected with reclaimed water quality parameters such as residual chlorine, DO, Cl(-) and SO4(2-). In particular, when a certain amount of residual chlorine in reclaimed water is present as an oxidant, ferric iron is the main chemical state of iron minerals.

  11. Corrosive microenvironments at lead solder surfaces arising from galvanic corrosion with copper pipe.

    Science.gov (United States)

    Nguyen, Caroline K; Stone, Kendall R; Dudi, Abhijeet; Edwards, Marc A

    2010-09-15

    As stagnant water contacts copper pipe and lead solder (simulated soldered joints), a corrosion cell is formed between the metals in solder (Pb, Sn) and the copper. If the resulting galvanic current exceeds about 2 μA/cm(2), a highly corrosive microenvironment can form at the solder surface, with pH galvanic currents, preventing passivation of the solder surface, and contributing to lead contamination of potable water supplies. The total mass of lead corroded was consistent with predictions based on the galvanic current, and lead leaching to water was correlated with galvanic current. If the concentration of sulfate in the water increased relative to chloride, galvanic currents and associated lead contamination could be greatly reduced, and solder surfaces were readily passivated.

  12. The resistance of high frequency inductive welded pipe to grooving corrosion in salt water

    Energy Technology Data Exchange (ETDEWEB)

    Duran, C.; Triess, E.; Herbsleb, G.

    1986-09-01

    When exposed to neutral, salt-containing waters, electric resistant welded pipe in carbon and low alloy steels with increased sulfur contents may suffer preferential corrosion attack in the weld area. Because of its appearance, this type of corrosion is called grooving corrosion. The susceptibility to grooving corrosion may be determined and quantitatively described by means of an accelerated potentiostatic exposure test. The importance of type, concentration, and temperature of the electrolytic solution; potential; test duration; and the sulfur content of the steel in the accelerated corrosion test and the susceptibility of steels to grooving corrosion are described. Line pipe in high frequency inductive (HFI) welded carbon and low alloy steels are resistant to grooving corrosion particularly because of their low sulfur content.

  13. Development of Exterior Anti-corrosion Coating Production Line for Large Diameter Hot Bent Pipes

    Institute of Scientific and Technical Information of China (English)

    JiaoRuyi; ZhangYing

    2004-01-01

    The epoxy powder exterior anti-corrosion coating production line for bent pipes with a single (double) course production is a technologically advanced bent pipe anti-corrosion method with cost efficiency, environment friendliness and stable coating quality. The quality of the coating on the bent pipe fully meets the requirements of the current national and industrial standards. The application of the technology has filled the gap in the bent pipe anti-corrosion coating area of China, and leads the world technologically. With this technology the coating quality of the bent pipe has greatly improved, resulting in significant social and economic benefits. With the use of the technology in various large scale pipeline projects such as the “West to East Gas Pipeline Project”, it will exhibite a greater potential in the future pipeline projects with a broad application prospect.

  14. Mechanical Behaviour of Lined Pipe

    NARCIS (Netherlands)

    Hilberink, A.

    2011-01-01

    Installing lined pipe by means of the reeling installation method seems to be an attractive combination, because it provides the opportunity of eliminating the demanding welds from the critical time offshore and instead preparing them onshore. However, reeling of lined pipe is not yet proven

  15. Recognition and Analysis of Corrosion Failure Mechanisms

    Directory of Open Access Journals (Sweden)

    Steven Suess

    2006-02-01

    Full Text Available Corrosion has a vast impact on the global and domestic economy, and currently incurs losses of nearly $300 billion annually to the U.S. economy alone. Because of the huge impact of corrosion, it is imperative to have a systematic approach to recognizing and mitigating corrosion problems as soon as possible after they become apparent. A proper failure analysis includes collection of pertinent background data and service history, followed by visual inspection, photographic documentation, material evaluation, data review and conclusion procurement. In analyzing corrosion failures, one must recognize the wide range of common corrosion mechanisms. The features of any corrosion failure give strong clues as to the most likely cause of the corrosion. This article details a proven approach to properly determining the root cause of a failure, and includes pictographic illustrations of the most common corrosion mechanisms, including general corrosion, pitting, galvanic corrosion, dealloying, crevice corrosion, microbiologically-influenced corrosion (MIC, corrosion fatigue, stress corrosion cracking (SCC, intergranular corrosion, fretting, erosion corrosion and hydrogen damage.

  16. Erosion-Corrosion Behavior of Power Plant Pipe Caused by Hot Feed Water

    Energy Technology Data Exchange (ETDEWEB)

    Bang, Sungho; Lee, Jinwon; Kim, Taewon [Hanyang Univ., Seoul (Korea, Republic of)

    2013-06-15

    In this study, we tried to define the erosion-corrosion behavior together with the resulting effects on a pipe that is a part of a feed water circulation system according to the pipe size and hot feed water environment. An erosion corrosion analysis was performed through the Hayduk and Minas model based on the chemical reaction between iron and oxygen, an essential corrosive factor. The erosion-corrosion rate against the pipe diameter and feed water temperature was then evaluated by means of finite element analysis using Abacus. As shown in the results, the feed water temperature was the main factor influencing the erosion-corrosion rate; in particular, it was expected that the thickness of 316 stainless steel would decrease by 2.59 {mu}m every year in a hot water environment at 290 .deg. C.

  17. Development of a iron pipe corrosion simulation model for a water supply network

    Directory of Open Access Journals (Sweden)

    M. Bernats

    2012-04-01

    Full Text Available Corrosion in water supply networks is unwanted process that causes pipe material loss and subsequent pipe failures. Nowadays pipe replacing strategy most often is based on pipe age, which is not always the most important factor in pipe burst rate. In this study a methodology for developing a mathematical model to predict the decrease of pipe thickness in a large cast iron networks is presented. The quality of water, the temperature and the water flow regime were the main factors taken into account in the corrosion model. The water quality and flow rate effect were determined by measuring corrosion rate of metals coupons over the period of one year at different flow regimes. The obtained constants were then introduced in a calibrated hydraulic model (Epanet and the corrosion model was validated by measuring the decrease of wall thickness in the samples that were removed during the regular pipe replacing event. The validated model was run for 30 yr to simulate the water distribution system of Riga (Latvia. Corrosion rate in the first year was 8.0–9.5 times greater than in all the forthcoming years, an average decrease of pipe wall depth being 0.013/0.016 mm per year in long term. The optimal iron pipe exploitation period was concluded to be 30–35 yr (for pipe wall depth 5.50 mm and metal density 7.5 m3 t−1. The initial corrosion model and measurement error was 33%. After the validation of the model the error was reduced to below 15%.

  18. Fracture mechanics models developed for piping reliability assessment in light water reactors: piping reliability project

    Energy Technology Data Exchange (ETDEWEB)

    Harris, D.O.; Lim, E.Y.; Dedhia, D.D.; Woo, H.H.; Chou, C.K.

    1982-06-01

    The efforts concentrated on modifications of the stratified Monte Carlo code called PRAISE (Piping Reliability Analysis Including Seismic Events) to make it more widely applicable to probabilistic fracture mechanics analysis of nuclear reactor piping. Pipe failures are considered to occur as the result of crack-like defects introduced during fabrication, that escape detection during inspections. The code modifications allow the following factors in addition to those considered in earlier work to be treated: other materials, failure criteria and subcritical crack growth characteristic; welding residual and vibratory stresses; and longitudinal welds (the original version considered only circumferential welds). The fracture mechanics background for the code modifications is included, and details of the modifications themselves provided. Additionally, an updated version of the PRAISE user's manual is included. The revised code, known as PRAISE-B was then applied to a variety of piping problems, including various size lines subject to stress corrosion cracking and vibratory stresses. Analyses including residual stresses and longitudinal welds were also performed.

  19. Perforated mechanism of a water line outlet tee pipe for an oil well drilling rig

    Directory of Open Access Journals (Sweden)

    Peng Cheng-hong

    2015-10-01

    Full Text Available A corroded tee pipe belonging to a 10-in new separator water line outlet installed in an offshore oil well drilling rig was investigated. The configuration of the large corroded pit had the shape of an imperfect horse's hoof with a completely corroded interior and a honeycomb-like cavity. There is a badly corroded pit at the welded seam at the joint connecting the tee pipe and flange. The material strength of the tee pipe meets the requirement of ASTM-A234 Gr. WPR, but its chemical composition does not meet the stipulated requirements. A deformed streamline structure or twin crystal in the ferrite phase can be seen near the surface or sub-surface of the perforated corrosion puncture edge. The micro-hardness is also different from that of the original material. The SEM results show that the puncture appears to have been a mode of quasi-cleavage fractures with secondary cracks along the direction of the crystal grain; thus, the failure has the features of mechanical and chemical corrosion. The corroded surface contains high amounts of O, C, and N, as well as S, Cl, Si, Na, Mg, Al, K, Ti, etc., all of which are corrosion products caused by sea water. The penetrating puncture hole at the turn of the tee pipe is likely the result of cavitation erosion accompanied by chemical/electrochemical corrosion, and the corrosion on the seam connecting the tee pipe and flange is likely the result of electrochemical corrosion.

  20. Corrosion Control of Kunifer-5 Seawater Piping Systems of Naval Ships by Cathodic Protection Technique

    Directory of Open Access Journals (Sweden)

    M. B. Deshmukh

    1982-01-01

    Full Text Available The cause of premature corrosion of Kunifer-5(copper alloy containing Ni 5 per cent and Fe 1.35 per cent pipes used in seawater piping systems on board ships for feeding seawater to various units has been discussed. It has been shown that the Kunifer-5 alloys suffer from heavy corrosion-erosion attack at unavoidable bends and places where local seawater velocity exceeds the specified limit. The field observations as well as laboratory study have indicated that satisfactory protection of the pipes could be achieved by galvanic cathodic protection using aluminium alloy anodes.

  1. Investigation on Mechanical Property of Seamless Pipe

    Institute of Scientific and Technical Information of China (English)

    ZHAO Li-ming; YANG Xiao-yong; LIU Ye

    2004-01-01

    The mechanical properties of the steel pipe rolled with continuously casting round billet after determining the chemical composition in steel were studied. The results show that the total reduction ratio should be higher than 5.2 when the line pipes of grade B, grade 20 and other general seamless pipe were rolled with continuously casting round billet. And the total reduction ratio should be higher than 10.2 and the grain size should be controlled more than grade 7 for casing of oil countryside tubular goods (OCTG).

  2. Development of an electrochemistry-based corrosion sensor to monitor corrosion of boiler tubes, pipes, and painted structures

    Science.gov (United States)

    Davis, Guy D.; Dacres, C. M.; Shook, M. B.

    1998-03-01

    An electrochemical impedance spectroscopy (EIS)-based in-situ corrosion sensor has been adapted and evaluated for use with steel heat exchanger tubes in boilers, coated buried steel pipes, and painted steel structures. An excellent correlation was obtained between the algorithm of the ratio of the breakpoint frequencies, as measured by the sensor, and corrosion rate for the boiler tubes. Use of this sensor and appropriate electronics would allow the corrosion of the boiler tubes to be monitored in real time and the inhibitor concentration automatically controlled to prevent excessive corrosion. The EIS sensor is also sensitive to the quality of coating of a buried steel pipe with and without the application of cathodic protection. Similar results were obtained from a sensor attached to the pipe and from a separate electrode driven into the soil. A hand-held version of the EIS in-situ sensor is suitable for inspecting painted metal structures, such as storage tanks and locks and dams, under ambient, service conditions. An excellent correlation was obtained between the sensor measurements, and the amount of corrosion on test panels immersed for up to 28 years.

  3. MECHANICAL PROPERTIES OF LONGITUDINAL SUBMERGED ARC WELDED STEEL PIPES USED FOR GAS PIPELINE OF OFFSHORE OIL

    Institute of Scientific and Technical Information of China (English)

    Z.Z. Yang; W. Tian; Q.R. Ma; Y.L. Li; J.K. Li; J.Z. Gao; H.B. Zhang; Y.H. Yang

    2008-01-01

    Since the development of offshore oil and gas, increased submarine oil and gas pipelines were installed. All the early steel pipes of submarine pipelines depended on importing because of the strict requirements of comprehensive properties, such as,anti-corrosion, resistance to pressure and so on. To research and develop domestic steel pipes used for the submarine pipeline, the Longitudinal-seam Submerged Arc Welded (LSAW) pipes were made of steel plates cut from leveled hot rolled coils by both the JCOE and UOE (the forming process in which the plate like the letter "J", "C", "O" or "U" shape, then expansion) forming processes. Furthermore, the mechanical properties of the pipe base metal and weld metal were tested, and the results were in accordance with the corresponding pipe specification API SPEC 5L or DNV-OS-F101, which showed that domestic LSAW pipes could be used for submarine oil and gas pipelines.

  4. Risk evaluation on internal corrosion of a gas pipeline cut section based on metal mechanic tests and physiochemical analysis of the solids deposited in the pipes; Determinacion del riesgo por corrosion interna de un tramo cortado de una linea de transporte de gas natural a partir de ensayos metalmecanicos y del analisis fisicoquimico de los solidos depositados en la tuberia

    Energy Technology Data Exchange (ETDEWEB)

    Ditta Sarmiento, Johanna Milena [PETROBRAS International (BRASPETRO) (Colombia). Ingenieria de Corrosion DPSU

    2003-07-01

    After inspecting a one of the most important pipelines in Colombia, using intelligent tool, the pipe sections were selected that presented losses of thickness which probably they would be risking integrity of the same one and after, these sections were cut and replaced. To one of the cut sections a study with the objective was made him establish the present forms of corrosion and to determine the phenomena that influenced the presence of the damages. For this study were moderate thicknesses of the wall of the tube and was determined the criticality comparing it with its nominal thickness, according to Standard ASME B - 31G. Taking advantage of the presence solids in the surface, one became both, physical and chemical analysis, DRX and elementary analysis, with the objective to determine its origin and to correlate it with the types of corrosion that were in the line. The morphology that determined were Microbiological Influenced Corrosion, Erosion - Corrosion, Pitting and CO2 corrosion. Then, from all this information the analysis becomes of risks by internal corrosion in pipeline, the plan of mitigation and the plans of monitoring and inspection of the line to avoid the presence of anyone of these forms of corrosion in the future immediate. (author)

  5. Development and Testing of a Linear Polarization Resistance Corrosion Rate Probe for Ductile Iron Pipe (Web Report 4361)

    Science.gov (United States)

    The North American water and wastewater community has hundreds of millions of feet of ductile iron pipe in service. Only a portion of the inventory has any form of external corrosion control. Ductile iron pipe, in certain environments, is subject to external corrosion.Linear Pola...

  6. Internal corrosion of carbon steel piping in hot aquifers service

    Directory of Open Access Journals (Sweden)

    Simičić Miloš V.

    2011-01-01

    Full Text Available Internal corrosion of carbon steel pipelines is a major problem encountered in water service. In terms of prediction of the remaining lifetime for water pipelines based on the corrosion allowance, the three main approaches are corrosion modelling, corrosion inhibitor availability, and corrosion monitoring. In this study we used two theoretical corrosion models, CASSANDRA and NORSOK M-506 of quite different origin in order to predict uniform corrosivity of hot aquifers in eight different pipelines. Because of the varying calculation criteria for the different models, these can give very different corrosion rate predictions for the same data input. This is especially true under conditions where the formation of protective films may occur, such as at elevated temperatures. The evaluation of models was conducted by comparison using weight-loss coupons and three corrosion inhibitors were obtained from commercial suppliers. The tests were performed during the 60-day period. Even though inhibitors’ efficiencies of 98% had been achieved in laboratory testing, inhibitors’ availabilities of 85% have been used due to logistics problems and other issues. The results, given in mmpy, i.e. millimeter per year, are very consistent with NORSOK M-506 prediction. This is presumably because the model considers the effect of the formation of a passive iron carbonate film at temperatures above 80 °C and significant reduction in corrosion rate. Corrosion inhibitor A showed a better performance than inhibitors B and C in all cases but the target corrosion rates of less than 0.1 mmpy were achieved for all inhibitors. The chemical type of corrosion inhibitor A is based on quaternary amines mixed with methanol, isopropyl alcohol, xylene and ethylbenzene. Based on the obtained results the carbon steel lifetime of 30 years, provided proper inhibitors are present and 3mm corrosion allowance, can be achieved for hot aquifers service with presented water compositions.

  7. Influence of pipe material and surfaces on sulfide related odor and corrosion in sewers.

    Science.gov (United States)

    Nielsen, Asbjørn Haaning; Vollertsen, Jes; Jensen, Henriette Stokbro; Wium-Andersen, Tove; Hvitved-Jacobsen, Thorkild

    2008-09-01

    Hydrogen sulfide oxidation on sewer pipe surfaces was investigated in a pilot scale experimental setup. The experiments were aimed at replicating conditions in a gravity sewer located immediately downstream of a force main where sulfide related concrete corrosion and odor is often observed. During the experiments, hydrogen sulfide gas was injected intermittently into the headspace of partially filled concrete and plastic (PVC and HDPE) sewer pipes in concentrations of approximately 1,000 ppm(v). Between each injection, the hydrogen sulfide concentration was monitored while it decreased because of adsorption and subsequent oxidation on the pipe surfaces. The experiments showed that the rate of hydrogen sulfide oxidation was approximately two orders of magnitude faster on the concrete pipe surfaces than on the plastic pipe surfaces. Removal of the layer of reaction (corrosion) products from the concrete pipes was found to reduce the rate of hydrogen sulfide oxidation significantly. However, the rate of sulfide oxidation was restored to its background level within 10-20 days. A similar treatment had no observable effect on hydrogen sulfide removal in the plastic pipe reactors. The experimental results were used to model hydrogen sulfide oxidation under field conditions. This showed that the gas-phase hydrogen sulfide concentration in concrete sewers would typically amount to a few percent of the equilibrium concentration calculated from Henry's law. In the plastic pipe sewers, significantly higher concentrations were predicted because of the slower adsorption and oxidation kinetics on such surfaces.

  8. [Influence of EPS on silicate corrosion inhibition for copper pipe in soft water].

    Science.gov (United States)

    Li, Shi-Yin

    2008-10-01

    The effects of sodium alginate on silicate corrosion inhibition for copper pipe in simulated soft water were investigated. The results showed that more soluble copper release was occurred when low concentration sodium alginate was in presence. The 1 a aged copper pipe released more soluble copper than the 3 a and 10 a aged copper pipe. The sequence of concentration of soluble copper release was c 1 a > c 3 a, > c 10 a. However, compared to the low concentration sodium alginate, soluble copper released from the 1 a aged copper pipe increased, and the 3 a and 10 a aged copper pipe were inverse when high level sodium alginate was in presence. These phenomena showed that the effect of silicate corrosion inhibition decreased when extracellular polymer substances was dissolved in soft water. Under the conditions of pH 7.5 and sodium alginate 16 mg/L, soluble copper release tend was gradually increase-decrease-gradually run-up which due to the absorption of sodium alginate on the surface of copper surface and the complex interaction between sodium alginate, silicate and copper ions. When the initial pH value was low, compared to the system of no sodium alginate, the soluble copper release distinctly increased in the presence of sodium alginate. The amount of soluble copper released from 1 a copper pipe is higher than that from 3 a and 10 a aged copper pipe, which due to the different components of copper corrosion by-products on the surface of different aged copper pipes and the different solubility of different corrosion by-products.

  9. Numerical modeling of stray current corrosion of ductile iron pipe induced by foreign cathodic protection system

    Science.gov (United States)

    Li, SeonYeob; Kim, Young-Geun

    2013-07-01

    Stray current corrosion phenomena of ductile iron pipe (DIP) located in the vicinity of cathodically protected steel pipe was assessed using the boundary element method. When all joints in DIP were electrically connected, the maximum corrosion rate was 0.005 mm/y. However, when the joints were isolated, the corrosion rate increased due to the jumping effect of stray current at isolated joints, which resulted in the increase of maximum corrosion rate to 0.87 mm/y at the isolated point. Moreover, the electrical bonding between the DIP and steel pipe could not act effectively but showed an adverse effect of collecting more cathodic protection (CP) currents into the DIP, which eventually jumped out into the soil and resulted in larger amount of stray current corrosion. Therefore it is desirable to apply control methods from the design and construction stage, which include the increase of anodebed and the pipe distance, electrical connection of DIP joints, installation of sacrificial anode at isolated joints, or the application of CP on DIP, etc.

  10. Cathodic corrosion protection of steel pipes; Kathodischer Korrosionsschutz von Rohrleitungsstaehlen

    Energy Technology Data Exchange (ETDEWEB)

    Buechler, Markus [SGK Schweizerische Gesellschaft fuer Korrosionsschutz, Zuerich (Switzerland); Schoeneich, Hanns-Georg [Open Grid Europe, Essen (Germany)

    2011-07-01

    The cathodic corrosion protection has been proven excellently in the practical use for buried steel pipelines. This is evidenced statistically by a significantly less frequency of loss compared to non-cathodically protected pipelines. Based on thermodynamic considerations, the authors of the contribution under consideration describe the operation of the cathodic corrosion protection and regular adjustment of the electrochemical potential at the interface steel / soil in practical use. Subsequently, the corrosion scenarios are discussed that may occur when an incorrect setting of the potential results from an operation over several decades. This incorrect setting also can be caused by the failure of individual components of the corrosion protection.

  11. [Corrosion of stainless steel 201, 304 and 316L in the simulated sewage pipes reactor].

    Science.gov (United States)

    Bao, Guo-Dong; Zuo, Jian-E; Wang, Ya-Jiao; Gan, Li-Li

    2014-08-01

    The corrosion behavior of stainless steel 201, 304 and 316L which would be used as sewer in-situ rehabilitation materials was studied in the simulated sewage pipes reactor. The corrosion potential and corrosion rate of these three materials were studied by potentiodynamic method on the 7th, 14th, 21st, 56th day under two different conditions which were full immersion condition or batch immersion condition with a 2-day cycle. The electrode process was studied by Electrochemical Impedance Spectroscopy (EIS) on the 56th day. The microstructure and composition of the corrosion pitting were analyzed by Scanning Electron Microscope (SEM) and Energy Dispersive Spectrometer (EDS) on the 56th day. The results showed that 304 and 316L had much better corrosion resistance than 201 under both conditions. 304 and 316L had much smaller corrosion rate than 201 under both conditions. The corrosion resistance of all three kinds of stainless steel under the batch immersion condition was much better than those under the full immersion condition. The corrosion rate of all three kinds of stainless steel under the batch immersion condition was much smaller than those under the full immersion condition. Point pitting corrosion was formed on the surfaces of 304 and 316L. In comparison, a large area of corrosion was formed in the surface of 201.

  12. Mechanisms of metal dusting corrosion

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo

    In this thesis the early stages of metal dusting corrosion is addressed; the development of carbon expanded austenite, C, and the decomposition hereof into carbides. Later stages of metal dusting corrosion are explored by a systematic study of stainless steel foils exposed to metal dusting...... influence of oxygen and carbon on the metal dusting corrosion is explored. The results indicate that exposure to metal dusting conditions have a detrimental effect on the resistance against oxidation and, conversely, that exposure to oxidation has a detrimental effect on the resistance towards metal dusting....... Consequently, a combination of carburizing and oxidizing conditions has a strong mutual catalyzing effect on the metal dusting corrosion....

  13. Corrosion in drinking water pipes: the importance of green rusts.

    Science.gov (United States)

    Swietlik, Joanna; Raczyk-Stanisławiak, Urszula; Piszora, Paweł; Nawrocki, Jacek

    2012-01-01

    Complex crystallographic composition of the corrosion products is studied by diffraction methods and results obtained after different pre-treatment of samples are compared. The green rusts are found to be much more abundant in corrosion scales than it has been assumed so far. The characteristic and crystallographic composition of corrosion scales and deposits suspended in steady waters were analyzed by X-ray diffraction (XRD). The necessity of the examination of corrosion products in the wet conditions is indicated. The drying of the samples before analysis is shown to substantially change the crystallographic phases originally present in corrosion products. On sample drying the unstable green rusts is converted into more stable phases such as goethite and lepidocrocite, while the content of magnetite and siderite decreases. Three types of green rusts in wet materials sampled from tubercles are identified. Unexpectedly, in almost all corrosion scale samples significant amounts of the least stable green rust in chloride form was detected. Analysis of corrosion products suspended in steady water, which remained between tubercles and possibly in their interiors, revealed complex crystallographic composition of the sampled material. Goethite, lepidocrocite and magnetite as well as low amounts of siderite and quartz were present in all samples. Six different forms of green rusts were identified in the deposits separated from steady waters and the most abundant was carbonate green rust GR(CO(3)(2-))(I).

  14. Analysis of a corrosion failure on a prestressed concrete cylinder pipe

    Energy Technology Data Exchange (ETDEWEB)

    Benedict, R.L. [Corrosion Consulting Service Corp., Fallbrook, CA (United States)

    1999-11-01

    In the arid or semi-arid western part of the United States, there are special parameters that may require investigation to determine whether the right-of-way soils are corrosive to cementitious-coated pipe. Cyclical wetting and drying, especially in arid environments, can cause an increase in chloride concentration in the capillary system of mortar by a factor of at least five. Under the right circumstances, with cyclical wetting and drying, a soil chloride content of 140 mg/kg will exceed the corrosion threshold of 700 mg/kg and initiate corrosion on prestress wire. Several actual field examples encountered in an investigation on a PCCP failure are described. Also included is a simple field test to quickly and economically determine which combinations of gravel, sand, and silty clay that are helpful in predicting both the likelihood and severity of cyclical wetting and drying stimulated corrosion on prestress concrete cylinder pipe. Other parameters examined were mortar properties of thickness, compressive strength, absorption, density, pH and total alkalinity vs. chloride penetration into the mortar, and degree of corrosion on prestress concrete cylinder pipe.

  15. Study of the Intercrystalline Corrosion in Pipes of Stainless Steel in a Combined Cycle

    Directory of Open Access Journals (Sweden)

    Raúl Andrés Montejo Serrano

    2014-09-01

    Full Text Available The present work is carried out with the purpose of giving answer to the possible presence ofintercrystalline corrosion and its future consequences in the built tubes of stainless steel 304L anddedicated to the conduction from the water to the boilers of a combined cycle of electricity production.The plant is these in this moments in installation of process investor and assembly and this study wasrequested since during the trial of installation of the pipes of stainless steel that will drive the watertried to the steam generators, they were detected on the part of the operatives some imperfections inthe material, what generated the doubt about the possibility of presence of intercrystalline corrosion orof another type in the pipes. After the realized rehearsals according to international norms and alsousing rehearsals metallography you concludes that the material employee is not sensitive to this typeof corrosion.

  16. Effect of Geopolymer filler in Glass Reinforced Epoxy (GRE) Pipe for Piping Application: Mechanical Properties

    Science.gov (United States)

    Firdaus Abu Hashim, Mohammad; Bakri Abdullah, Mohd Mustafa Al; Mohd Ruzaidi Ghazali, Che; Hussin, Kamarudin; Binhussain, Mohammed

    2016-06-01

    The present work is aimed to carry out the effect of geopolymer material which is fly ash as filler in the glass reinforced epoxy pipe on the micro structure of fly ash geopolymer, compression properties, and bulk density using the filament winding method. Conventional glass reinforced epoxy pipes has its own disadvantages such as high corrosion resistance at acidic environment and low strength which can be replaced by the composite pipes. Geopolymer is a type of amorphous alumino-silicate and can be synthesized by geopolymerization process. A series of glass reinforced epoxy pipe and glass reinforced epoxy pipe filled with 10 - 40 weight percentage geopolymer filler which is fly ash with 4 Molarity were prepared. Morphology of the raw material fly ash and fly ash based-geopolymer surface was characterized using scanning electron microscopy. It was found that the additions of fly ash at the beginning with 10 wt% are showing higher compressive strength than glass reinforced epoxy pipe without fly ash geopolymer filler. The compressive test of these series of samples was determined using Instron Universal Testing under compression mode. It was found that compressive strength for samples fly ash based-geopolymer filler are higher as compared to glass reinforced epoxy pipe without geopolymer filler. However, the compressive strength of glass reinforced epoxy pipe with fly ash geopolymer filler continues to decline when added to 20 wt% - 40 wt% of geopolymer filler loading. The results showed that the mixing of geopolymer materials in epoxy system can be obtained in this study.

  17. Microbiologically Influenced Corrosion in Copper and Nickel Seawater Piping Systems

    Science.gov (United States)

    1990-09-01

    169. London: Newnes-Butterworths. nickel alloys. Biologia Marina, Proceedings of 5th Interna- Southwell, C. R. and Alexander, A. L. 1967. Corrosion of...Sons Ltd. 441 pp. Quimica . Verink, E.D. and Pourbaix, M. 1971. Use of electrochemical Pope, D. H., Duquette, D. J., Johannes, A. H., and Wayner...Bacteria. 2nd Ed. Workshop on Biodeterioration (CONICET-NSF), pp. 43-63, 144pp. London: Cambridge University Press. Sao Paulo, Brazil: Aquatec Quimica . MTS Journal • Vol. 24, No. 3 • 17

  18. Characteristics of iron corrosion scales and water quality variations in drinking water distribution systems of different pipe materials.

    Science.gov (United States)

    Li, Manjie; Liu, Zhaowei; Chen, Yongcan; Hai, Yang

    2016-12-01

    Interaction between old, corroded iron pipe surfaces and bulk water is crucial to the water quality protection in drinking water distribution systems (WDS). Iron released from corrosion products will deteriorate water quality and lead to red water. This study attempted to understand the effects of pipe materials on corrosion scale characteristics and water quality variations in WDS. A more than 20-year-old hybrid pipe section assembled of unlined cast iron pipe (UCIP) and galvanized iron pipe (GIP) was selected to investigate physico-chemical characteristics of corrosion scales and their effects on water quality variations. Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectroscopy (EDS), Inductively Coupled Plasma (ICP) and X-ray Diffraction (XRD) were used to analyze micromorphology and chemical composition of corrosion scales. In bench testing, water quality parameters, such as pH, dissolved oxygen (DO), oxidation reduction potential (ORP), alkalinity, conductivity, turbidity, color, Fe(2+), Fe(3+) and Zn(2+), were determined. Scale analysis and bench-scale testing results demonstrated a significant effect of pipe materials on scale characteristics and thereby water quality variations in WDS. Characteristics of corrosion scales sampled from different pipe segments show obvious differences, both in physical and chemical aspects. Corrosion scales were found highly amorphous. Thanks to the protection of zinc coatings, GIP system was identified as the best water quality stability, in spite of high zinc release potential. It is deduced that the complicated composition of corrosion scales and structural break by the weld result in the diminished water quality stability in HP system. Measurement results showed that iron is released mainly in ferric particulate form. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Ultrasonic thickness structural health monitoring photoelastic visualization and measurement accuracy for internal pipe corrosion

    Science.gov (United States)

    Eason, Thomas J.; Bond, Leonard J.; Lozev, Mark G.

    2015-03-01

    Oil refinery production of fuels is becoming more challenging as a result of the changing world supply of crude oil towards properties of higher density, higher sulfur concentration, and higher acidity. One such production challenge is an increased risk of naphthenic acid corrosion that can result in various surface degradation profiles of uniform corrosion, non-uniform corrosion, and localized pitting in piping systems at temperatures between 150°C and 400°C. The irregular internal surface topology and high external surface temperature leads to a challenging in-service monitoring application for accurate pipe wall thickness measurements. Improved measurement technology is needed to continuously profile the local minimum thickness points of a non-uniformly corroding surface. The measurement accuracy and precision must be sufficient to provide a better understanding of the integrity risk associated with refining crude oils of higher acid concentration. This paper discusses potential technologies for measuring localized internal corrosion in high temperature steel piping and describes the approach under investigation to apply flexible ultrasonic thin-film piezoelectric transducer arrays fabricated by the sol-gel manufacturing process. Next, the elastic wave beam profile of a sol-gel transducer is characterized via photoelastic visualization. Finally, the variables that impact measurement accuracy and precision are discussed and a maximum likelihood statistical method is presented and demonstrated to quantify the measurement accuracy and precision of various time-of-flight thickness calculation methods in an ideal environment. The statistical method results in confidence values analogous to the a90 and a90/95 terminology used in Probability-of-Detection (POD) assessments.

  20. Structural health monitoring of localized internal corrosion in high temperature piping for oil industry

    Science.gov (United States)

    Eason, Thomas J.; Bond, Leonard J.; Lozev, Mark G.

    2015-03-01

    Crude oil is becoming more corrosive with higher sulfur concentration, chloride concentration, and acidity. The increasing presence of naphthenic acids in oils with various environmental conditions at temperatures between 150°C and 400°C can lead to different internal degradation morphologies in refineries that are uniform, non-uniform, or localized pitting. Improved corrosion measurement technology is needed to better quantify the integrity risk associated with refining crude oils of higher acid concentration. This paper first reports a consolidated review of corrosion inspection technology to establish the foundation for structural health monitoring of localized internal corrosion in high temperature piping. An approach under investigation is to employ flexible ultrasonic thin-film piezoelectric transducer arrays fabricated by the sol-gel manufacturing process for monitoring localized internal corrosion at temperatures up to 400°C. A statistical analysis of sol-gel transducer measurement accuracy using various time of flight thickness calculation algorithms on a flat calibration block is demonstrated.

  1. Corrosion by concentrated sulfuric acid in carbon steel pipes and tanks: state of the art

    Energy Technology Data Exchange (ETDEWEB)

    Panossian, Zehbour; Almeida, Neusvaldo Lira de; Sousa, Raquel Maria Ferreira de [Instituto de Pesquisas Tecnologicas (IPT), Sao Paulo, SP (Brazil); Pimenta, Gutemberg de Souza [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas e Desenvolvimento (CENPES); Marques, Leandro Bordalo Schmidt [PETROBRAS Engenharia, Rio de Janeiro, RJ (Brazil)

    2009-07-01

    PETROBRAS, allied to the policy of reduction of emission of pollutants, has been adjusting the processes of the new refineries to obtain products with lower sulfur content. Thus, the sulfur dioxide, extracted from the process gases of a new refinery to be built in the Northeast, will be used to produce sulfuric acid with concentration between (94-96) %. This acid will be stored in carbon steel tanks and transported through a buried 8-km carbon steel pipe from the refinery to a pier, where it will be loaded onto ships and sent to the consumer markets. Therefore, the corrosion resistance of carbon steel by concentrated acid will become a great concern for the mentioned storage and transportation. When the carbon steel comes into contact with concentrated sulfuric acid, there is an immediate acid attack with the formation of hydrogen gas and ferrous ions which, in turn, forms a protective layer of FeSO{sub 4} on the metallic surface. The durability of the tanks and pipes made of carbon steel will depend on the preservation of this protective layer. This work presents a review of the carbon steel corrosion in concentrated sulfuric acid and discusses the preventive methods against this corrosion, including anodic protection. (author)

  2. The Effect of Welding Residual Stress for Making Artificial Stress Corrosion Crack in the STS 304 Pipe

    Directory of Open Access Journals (Sweden)

    Jae-Seong Kim

    2015-01-01

    Full Text Available The stress corrosion crack is one of the fracture phenomena for the major structure components in nuclear power plant. During the operation of a power plant, stress corrosion cracks are initiated and grown especially in dissimilar weldment of primary loop components. In particular, stress corrosion crack usually occurs when the following three factors exist at the same time: susceptible material, corrosive environment, and tensile stress (residual stress included. Thus, residual stress becomes a critical factor for stress corrosion crack when it is difficult to improve the material corrosivity of the components and their environment under operating conditions. In this study, stress corrosion cracks were artificially produced on STS 304 pipe itself by control of welding residual stress. We used the instrumented indentation technique and 3D FEM analysis (using ANSYS 12 to evaluate the residual stress values in the GTAW area. We used the custom-made device for fabricating the stress corrosion crack in the inner STS 304 pipe wall. As the result of both FEM analysis and experiment, the stress corrosion crack was quickly generated and could be reproduced, and it could be controlled by welding residual stress.

  3. Fracture mechanics parameters of multilayer pipes

    Directory of Open Access Journals (Sweden)

    Šestáková L.

    2007-10-01

    Full Text Available Multilayer pipes consisting of different materials are frequently used in praxis because of partial improvement of the properties of pipe systems. To estimate lifetime of these pipes the basic fracture parameters have to be determined. In this work finite element calculations are applied in order to estimate the stress intensity factor K and T-stress values for a new type of non-homogenous C-shape specimen. The application of calculated K and T values to laboratory estimation of fracture toughness and its transferability to real pipe system is discussed.

  4. Hydrogen-related stress corrosion cracking in line pipe steel

    DEFF Research Database (Denmark)

    Nielsen, Lars Vendelbo

    1997-01-01

    A correlation between hydrogen concentration (C0) and the critical stress intensity factor for propagation of hydrogen-related cracks has been established by fracture mechanical testing of CT-specimens for the heat affected zone of an X-70 pipeline steel. This has been compared with field...

  5. Flow accelerated corrosion of carbon steel feeder pipes from pressurized heavy water reactors

    Science.gov (United States)

    Singh, J. L.; Kumar, Umesh; Kumawat, N.; Kumar, Sunil; Kain, Vivekanand; Anantharaman, S.; Sinha, A. K.

    2012-10-01

    Detailed investigation of a number of feeder pipes received from Rajasthan Atomic Power Station Unit 2 (RAPS#2) after en-masse feeder pipe replacement after 15.67 Effective Full Power Years (EFPYs) was carried out. Investigations included ultrasonic thickness measurement by ultrasonic testing, optical microscopy, scanning electron microscopy, chemical analysis and X-ray Diffraction (XRD). Results showed that maximum thickness reduction of the feeder had occurred downstream and close to the weld in 32 NB (1.25″/32.75 mm ID) elbows. Rate of Flow Accelerated Corrosion (FAC) was measured to be higher in the lower diameter feeder pipes due to high flow velocity and turbulence. Weld regions had thinned to a lower extent than the parent material due to higher chromium content in the weld. A weld protrusion has been shown to add to the thinning due to FAC and lead to faster thinning rate at localized regions. Surface morphology of inner surface of feeder had shown different size scallop pattern over the weld and parent material. Inter-granular cracks were also observed along the weld fusion line and in the parent material in 32 NB outlet feeder elbow.

  6. Study of pitting corrosion in line-pipe steel under the influence of remanent magnetization

    Energy Technology Data Exchange (ETDEWEB)

    Espina-Hernandez, J.H.; Caleyo, F.; Hallen, J.M. [Instituto Politecnico Nacional (IPN), Zacatenco (Mexico)

    2009-07-01

    The influence of remanent magnetization on pitting corrosion in line-pipe steels is studied. Pitting corrosion experiments have been carried out on samples of an API 5L grade 52 steel under a magnetization level of the same order of magnitude of the remanent magnetization in the pipeline wall after in-line inspection based on magnetic flux leakage. The samples were magnetized using rings of the same grade as the investigated steel. Immediately after magnetization, the investigated samples were subjected to pitting by immersing them in a solution containing dissolved Cl{sup -} and SO{sup 2-}{sub 4} and ions. The pitting experiments were conducted during a seven days period. The pit depth distribution and the maximum pit depth in each sample were recorded and used to conduct extreme value analyses of the pitting process in magnetized and non-magnetized control samples. The statistical assessment of the pitting corrosion data collected during this study shows that the magnetic field reduces the average depth of the pit population and also the extreme pit depth values that can be predicted from the maximum values observed in the magnetized samples in comparison with to the non-magnetized control samples. Scanning electron microscopy observations show that the magnetic field alters the pit morphology by increasing the pit mouth opening. (author)

  7. Study of pitting corrosion in line-pipe steel under the influence of remanent magnetization

    Energy Technology Data Exchange (ETDEWEB)

    Espina-Hernandez, J.H.; Caleyo, F.; Hallen, J.M. [Instituto Politecnico Nacional (IPN), Zacatenco (Mexico)

    2009-07-01

    The influence of remanent magnetization on pitting corrosion in line-pipe steels is studied. Pitting corrosion experiments have been carried out on samples of an API 5L grade 52 steel under a magnetization level of the same order of magnitude of the remanent magnetization in the pipeline wall after in-line inspection based on magnetic flux leakage. The samples were magnetized using rings of the same grade as the investigated steel. Immediately after magnetization, the investigated samples were subjected to pitting by immersing them in a solution containing dissolved Cl{sup -} and SO{sup 2-}{sub 4} and ions. The pitting experiments were conducted during a seven days period. The pit depth distribution and the maximum pit depth in each sample were recorded and used to conduct extreme value analyses of the pitting process in magnetized and non-magnetized control samples. The statistical assessment of the pitting corrosion data collected during this study shows that the magnetic field reduces the average depth of the pit population and also the extreme pit depth values that can be predicted from the maximum values observed in the magnetized samples in comparison with to the non-magnetized control samples. Scanning electron microscopy observations show that the magnetic field alters the pit morphology by increasing the pit mouth opening. (author)

  8. Effect of Thermal Shock During Legionella Bacteria Removal on the Corrosion Properties of Zinc-Coated Steel Pipes

    Science.gov (United States)

    Orlikowski, Juliusz; Ryl, Jacek; Jazdzewska, Agata; Krakowiak, Stefan

    2016-07-01

    The purpose of this investigation was to conduct the failure analysis of a water-supply system made from zinc-coated steel. The observed corrosion process had an intense and complex character. The brownish deposits and perforations were present after 2-3 years of exploitation. The electrochemical study based on the Tafel polarization, corrosion potential monitoring, and electrochemical impedance spectroscopy together with microscopic analysis via SEM and EDX were performed in order to identify the cause of such intense corrosion. The performed measurements allowed us to determine that thermal shock was the source of polarity-reversal phenomenon. This process had begun the corrosion of steel which later led to the formation of deposits and perforations in the pipes. The work includes appropriate action in order to efficiently identify the described corrosion threat.

  9. Intuitional experiment and numerical analysis of flow characteristics affected by flow accelerated corrosion in elbow pipe system

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyung Joon [School of Mechanical and Aerospace Engineering, Seoul National University, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Kim, Kyung Hoon, E-mail: kimkh@khu.ac.kr [Department of Mechanical Engineering, Kyung Hee University, Seochun 1, Yongin, Gyeonggi 446-701 (Korea, Republic of)

    2016-05-15

    Highlights: • Wall-thinning erosion of pipelines in plants leads to fatal accidents unexpectedly. • Flow Acceleration Corrosion (FAC) is a main reason of wall-thinning. • For industrial safety, it is necessary to verify the tendency of FAC. • We focused on local wall thinning by FAC with intuitional visualization experiment and numerical analysis in elbow pipe.

  10. Corrosion Failure of Bypass Pipe of Well F in Bohai Oilfield%渤海某油田F井旁路管腐蚀失效研究

    Institute of Scientific and Technical Information of China (English)

    王晓鹏; 王啸; 修海媚; 谭才渊; 杨进; 殷启帅

    2016-01-01

    ABSTRACT:Objective The phenomenon of bypass pipe corrosion failure occurs in Bohai Oilfield. Taking Well F in Bohai Oilfield as an example, this paper investigated the corrosion mechanism of bypass pipe to guide the selection of bypass pipe materi-al, and to determine the anticorrosive direction and measures of this oil field.MethodsBased on the preliminary analysis of pipe corrosion, using scanning electron microscope, tensile strength test machine, X ray diffraction instrument and so on, physical and chemical performance analysis, metallographic analysis, corrosion product XRD analysis and corrosion product spectrum analysis were carried out on corroded bypass pipe of well F.Results In the aspect of chemical composition, the original chemical compo-sition of the 1#, 2#, 3#bypass pipes met the requirements of Spec 5CT API. In the aspect of mechanical properties, the tensile strength and yield strength of 1# bypass pipe were slightly lower than the standard requirements, and the mechanical properties of the 2#, 3#bypass pipes met the requirements of Spec 5CT API. In the aspect of corrosion products, the corrosion products of the 1#, 2#, 3# bypass pipes were mainly composed of C, O, S, Fe, Ca and Mn. Iron oxide was the main product, followed by sulfide, in which C, Ca, O elements should be derived from environmental media, and a small amount of Ti element might be derived from the surrounding contact metal. In the aspect of compounds produced by corrosion, 1# bypass pipe mainly produced iron oxide, and it contained Ca2Fe2O5 which was inferred to be derived from the formation of sand or ore. 2#bypass pipe mainly produced typical rust components, mainly iron oxide, and a small amount of FeO(OH), which was unstable, and could easily produce iron oxide in the air. Conclusion The corrosion of well F was erosion-corrosion and galvanic corrosion.%目的:旁路管腐蚀现象在渤海油田时有发生,以渤海某油田F井为例,研究该油田旁路管腐蚀机理

  11. Corrosion potential analysis system

    Science.gov (United States)

    Kiefer, Karl F.

    1998-03-01

    Many cities in the northeastern U.S. transport electrical power from place to place via underground cables, which utilize voltages from 68 kv to 348 kv. These cables are placed in seamless steel pipe to protect the conductors. These buried pipe-type-cables (PTCs) are carefully designed and constantly pressurized with transformer oil to prevent any possible contamination. A protective coating placed on the outside diameter of the pipe during manufacture protects the steel pipe from the soil environment. Notwithstanding the protection mechanisms available, the pipes remain vulnerable to electrochemical corrosion processes. If undetected, corrosion can cause the pipes to leak transformer oil into the environment. These leaks can assume serious proportions due to the constant pressure on the inside of the pipe. A need exists for a detection system that can dynamically monitor the corrosive potential on the length of the pipe and dynamically adjust cathodic protection to counter local and global changes in the cathodic environment surrounding the pipes. The northeastern United States contains approximately 1000 miles of this pipe. This milage is critical to the transportation and distribution of power. So critical, that each of the pipe runs has a redundant double running parallel to it. Invocon, Inc. proposed and tested a technically unique and cost effective solution to detect critical corrosion potential and to communicate that information to a central data collection and analysis location. Invocon's solution utilizes the steel of the casing pipe as a communication medium. Each data gathering station on the pipe can act as a relay for information gathered elsewhere on the pipe. These stations must have 'smart' network configuration algorithms that constantly test various communication paths and determine the best and most power efficient route through which information should flow. Each network station also performs data acquisition and analysis tasks that ultimately

  12. Topical Report ''Corrosion Evaluation of LLW2 Skid-B Weld Failure Mechanisms (44139-92)

    Energy Technology Data Exchange (ETDEWEB)

    JI Young Chang

    2001-05-31

    An independent investigation of pipe welding leaks from the Low-Level Waste 2 (LLW2) Skid-B System for the possibilities of improper welding (IW), microbiologically influenced corrosion (MIC), sensitization, chloride pitting corrosion (CPC), and intergranular stress corrosion cracking (IGSCC) was conducted. The results show the prevailing mechanisms that caused the leaks are identified as IW, CPC, and the improper selection of weld filler material for the base metals in an environment of the North Plateau underground water. These is no evidence of MIC, sensitization, or IGSCC. The chloride pitting corrosion mechanism that took place at all the welds are also described. All the pipelines were replaced with polyvinyl chloride (PVC) for cost saving and the LLW2 Skid B System has been successfully operating since 1999. This report summarizes the findings and recommendations associated with preventive measures for future operations. The LLW2 Facility is a replacement for an existing waste treatment system. The Facility processes two different waste streams through two different ''skids.'' After seven months of operation, one of the two skids began to leak. Extensive evaluation of the corrosion mechanisms and the contributing factors are documented in this report. This report principally evaluates the physical and chemical configurations that led to the corrosion and leaks. Chloride pitting corrosion, exacerbated by weld defects, is the corrosion mechanism. The report also discusses fabrication and Quality Assurance (QA)/Quality Control (QC) actions that would have prevented their occurrence. It is believed that in the absence of either the defects or the chloride concentrations, corrosion would not have occurred. In developing the specification for processing skids to be used in the Facility, high chloride was not identified as a parameter of concern. As such, piping fabrication and inspection standards for the system did not identify more rigorous

  13. Corrosion Products and Formation Mechanism During Initial Stage of Atmospheric Corrosion of Carbon Steel

    Institute of Scientific and Technical Information of China (English)

    XIAO Kui; DONG Chao-fang; LI Xiao-gang; WANG Fu-ming

    2008-01-01

    The formation and development of corrosion products on carbon steel surface during the initial stage of atmospheric corrosion in a laboratory simulated environment have been studied by scanning electron microscopy (SEM)and Raman spectroscopy.The results showed that two different shapes of corrosion products,that is,ring and chain,were formed in the initial stage of corrosion.MnS clusters were found in the nuclei of corrosion products at the active local corrosion sites.The ring-shaped products were composed of lepidocrocite (γ-FeOOH) and maghemite(γ-Fe2 O3) transformed from lepidocrocite.The chain-type products were goethite (α-FeOOH).A formation mechanism of the corrosion products is proposed.

  14. Application of Nano-Structured Coatings for Mitigation of Flow-Accelerated Corrosion in Secondary Pipe Systems of Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seung Hyun; Kim, Jong Jin; Yoo, Seung Chang; Huh, Jae Hoon; Kim, Ji Hyun [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2014-05-15

    Flow-accelerated corrosion (FAC) is a complex corrosion process combined with mechanical reaction with fluid. There were lots of research to mitigate FAC such as controlling temperature or water chemistry but in this research, we adopt active coating techniques especially nano-particle reinforced coatings. One of the general characteristics of FAC and its mitigation is that surface friction due to surface morphology makes a significant effect on FAC. Therefore to form a uniform coating layers, nano-particles including TiO2, SiC, Fe-Cr-W and Graphene were utilized. Those materials are known as greatly improve the corrosion resistance of substrates such as carbon steels but their effects on mitigation of FAC are not revealed clearly. Therefore in this research, the FAC resistive performance of nano-structured coatings were tested by electrochemical impedance spectroscopy (EIS) in room temperature 15 wt% sulfuric acid. As the flow-accelerated corrosion inhibitors in secondary piping system of nuclear power plants, various kinds of nano-structured coatings were prepared and tested in room-temperature electrochemical cells. SHS7740 with two types of Densifiers, electroless nickel plating with TiO2 are prepared. Electropolarization curves shows the outstanding corrosion mitigation performance of SHS7740 but EIS results shows the promising potential of Ni-P and Ni-P-TiO2 electroless nickel plating. For future work, high-temperature electrochemical analysis system will be constructed and in secondary water chemistry will be simulated.

  15. Cost Optimal Reliability Based Inspection and Replacement Planning of Piping Subjected to CO2 Corrosion

    DEFF Research Database (Denmark)

    Hellevik, S. G.; Langen, I.; Sørensen, John Dalsgaard

    1999-01-01

    A methodology for cost optimal reliability based inspection and replacement planning of piping subjected to CO2 corrosion is described. Both initial (design phase) and in-service planning are dealt with. The methodology is based on the application of methods for structural reliability analysis...... within the framework of Bayesian decision theory. The planning problem is formulated as an optimization problem where the expected lifetime costs are minimized with a constraint on the minimum acceptable reliability level. The optimization parameters are the number of inspections in the expected lifetime......, the inspection times and methods. In the design phase the nominal design wall thickness is also treated as an optimization parameter. The most important benefits gained through the application of the methodology are consistent evaluation of the consequences of different inspection and replacement plans...

  16. Sulfate attack in sewer pipes: Derivation of a concrete corrosion model via two-scale convergence

    CERN Document Server

    Fatima, Tasnim

    2010-01-01

    We explore the homogenization limit and rigorously derive upscaled equations for a microscopic reaction-diffusion system modeling sulfate corrosion in sewer pipes made of concrete. The system, defined in a periodically-perforated domain, is semi-linear, partially dissipative and weakly coupled via a non-linear ordinary differential equation posed on the solid-water interface at the pore level. Firstly, we show the well-posedness of the microscopic model. We then apply homogenization techniques based on two-scale convergence for an uniformly periodic domain and derive upscaled equations together with explicit formulae for the effective diffusion coefficients and reaction constants. We use a boundary unfolding method to pass to the homogenization limit in the non-linear ordinary differential equation. Finally, besides giving its strong formulation, we also prove that the upscaled two-scale model admits a unique solution.

  17. Cost-effective solutions for corrosion-resistant expandable-screen base pipe in sour/brine service

    Energy Technology Data Exchange (ETDEWEB)

    Chitwood, G. [Halliburton Energy Services, Calgary, AB (Canada); Skogsberg, L. [Shell International E and P Inc., Calgary, AB (Canada)

    2004-07-01

    In order to remain competitive, oilfield operators use the lowest-cost materials that meet the technical needs of an operation. As field development expands into deeper and more corrosive environments, there is a greater demand for corrosion-resistant alloys. The main environmental factors that affect stress corrosion cracking (SCC) behaviour of S31603 are hydrogen sulphide (H{sub 2}S) content, acidity, chloride concentration, oxygen contamination and temperature. In expandable sand control systems, new technology must compete with existing non-expandable screens that are low-cost to manufacture. The first choice for a corrosion-resistant alloy for base pipe in conventional sand screens is the low cost 13Cr which provides corrosion resistance in mild H{sub 2}S situations under a range of chloride and temperature conditions. The material, however, lacks ductility needed for 25 per cent expansion. Another option is to use 316L (UNS S31603), an alloy with sufficient ductility and strength, but with questionable corrosion resistance when it comes to chloride SCC. The potential application of S31603 in several projects was presented along with data needed to establish a performance envelope for this material which has been shown to be a cost-effective material for base pipes in sand-control screens. 3 refs., 2 tabs., 3 figs.

  18. Probabilistic Risk Assessment: Piping Fragility due to Earthquake Fault Mechanisms

    Directory of Open Access Journals (Sweden)

    Bu Seog Ju

    2015-01-01

    Full Text Available A lifeline system, serving as an energy-supply system, is an essential component of urban infrastructure. In a hospital, for example, the piping system supplies elements essential for hospital operations, such as water and fire-suppression foam. Such nonstructural components, especially piping systems and their subcomponents, must remain operational and functional during earthquake-induced fires. But the behavior of piping systems as subjected to seismic ground motions is very complex, owing particularly to the nonlinearity affected by the existence of many connections such as T-joints and elbows. The present study carried out a probabilistic risk assessment on a hospital fire-protection piping system’s acceleration-sensitive 2-inch T-joint sprinkler components under seismic ground motions. Specifically, the system’s seismic capacity, using an experimental-test-based nonlinear finite element (FE model, was evaluated for the probability of failure under different earthquake-fault mechanisms including normal fault, reverse fault, strike-slip fault, and near-source ground motions. It was observed that the probabilistic failure of the T-joint of the fire-protection piping system varied significantly according to the fault mechanisms. The normal-fault mechanism led to a higher probability of system failure at locations 1 and 2. The strike-slip fault mechanism, contrastingly, affected the lowest fragility of the piping system at a higher PGA.

  19. Investigation of noninvasive healing of damaged piping system using electro-magneto-mechanical methods

    KAUST Repository

    Mukherjee, Debanjan

    2014-01-01

    Virtually all engineering applications involve the use of piping, conduits and channels. In the petroleum industry, piping systems are extensively employed in upstream and downstream processes. These piping systems often carry fluids that are corrosive, which leads to wear, cavitation and cracking. The replacement of damaged piping systems can be quite expensive, both in terms of capital costs, as well as in operational downtime. This motivates the present research on noninvasive healing of cracked piping systems. In this investigation, we propose to develop computational models for characterizing noninvasive repair strategies involving electromagnetically guided particles. The objective is to heal industrial-piping systems noninvasively, from the exterior of the system, during operation, resulting in no downtime, with minimal relative cost. The particle accumulation at a target location is controlled by external electro-magneto-mechanical means. There are two primary effects that play a role for guiding the particles to the solid-fluid interface/wall: mechanical shear due to the fluid flow, and an electrical or magnetic force. In this work we develop and study a relationship that characterizes contributions of both, and ascertain how this relationship scales with characteristic physical parameters. Characteristic non-dimensional parameters that describe system behavior are derived and their role in design is illustrated. A detailed, fully 3-dimensional discrete element simulation framework is presented, and illustrated using a model problem of magnetically guided particles. The detailed particle behavior is considered to be regulated by three effects: (1) the field strength (2) the mass flow rate and (3) the wall interactions.

  20. Corrosion of Steel in Concrete, Part I – Mechanisms

    DEFF Research Database (Denmark)

    Küter, André; Møller, Per; Geiker, Mette Rica

    2006-01-01

    prematurely. Reinforcement corrosion is identified to be the foremost cause of deterioration. Steel in concrete is normally protected by a passive layer due the high alkalinity of the concrete pore solution; corrosion is initiated by neutralization through atmospheric carbon dioxide and by ingress...... of depassivation ions, especially chloride ions. The background and consequences of deterioration of reinforced concrete structures caused by steel corrosion are summarized. Selected corrosion mechanisms postulated in the literature are briefly discussed and related to observations. The key factors controlling...... initiation and propagation of corrosion of steel in concrete are outlined....

  1. Corrosion Characteristics of Nano-structured Coatings for the Application in Secondary Piping System of Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeong Won; Kim, Seung Hyun; Kim, Ji Hyun [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2015-05-15

    Coating surface using less corrosive metal is one of methods that reduce electrochemical corrosion. And metal oxide like a TiO{sub 2} is studied because it is stable, insoluble when coating is exposed severe environment. Several coating technics are used for better corrosion resistance. Pysical vapor deposition(PVD), chemical vapor deposition(CVD), thermal spray, electroplating, electroless etc. But thermal spray coating makes thermal stress to substrates because its temperature are more than 3000K. And powder's deformation can occur. And CVD makes decarburization near interface between surface and coating layer. In addition, CVD and PVD needs vacuum chamber. Electroplating is chemical reaction at surface, but it needs electric power. On the other hands, electroless plating dosen't needs electric power and it's temperature is low than thermal spray. Also the pipe dipping into the chemically solution can proceed coating easily. To reduce FAC, we have experiment about corrosion resistance of electroless Ni-P coated carbon steel in room temperature. And it has possibility of reducing corrosion and addition of TiO{sub 2} nano particles in Ni-P coating layer makes having better corrosion resistance. And results give us a possibility that electroless Ni-P coating added TiO{sub 2} nano particle can have better corrosion resistance compared carbon steel. So it needs study about high temperature corrosion experiment of electroless Ni-P coating added TiO{sub 2} nano particle.

  2. Ultrasonic monitoring of erosion/corrosion thinning rates in industrial piping systems.

    Science.gov (United States)

    Honarvar, Farhang; Salehi, Farzaneh; Safavi, Vahid; Mokhtari, Arman; Sinclair, Anthony N

    2013-09-01

    Monitoring pipe wall erosion/corrosion thinning rates is an important issue in petrochemical and power generation industries. In this paper, two signal processing techniques are utilized for estimating the thinning rate based on ultrasonic pipe wall thickness data collected over a short period of time. The first is a combination of cross-correlation and polynomial curve fitting and the second is a model-based estimation (MBE) scheme. These techniques are applied to data collected from an accelerated thinning rate apparatus and both show that they are capable of estimating the thinning rates quickly in short time periods with good accuracy. In laboratory applications, thinning rates as low as 10 μm/year were measured within 15 days with an uncertainty of ±1.5 μm/year by both techniques. Although the MBE technique can yield marginally better accuracy, the greater stability and computational speed of the cross-correlation technique make it the preferred choice for industrial use.

  3. Slurry Chemical Corrosion and Galvanic Corrosion during Copper Chemical Mechanical Polishing

    Science.gov (United States)

    Kondo, Seiichi; Sakuma, Noriyuki; Homma, Yoshio; Ohashi, Naofumi

    2000-11-01

    Copper (Cu) corrosion during chemical mechanical polishing (CMP) was controlled in order to improve the Cu damascene interconnect process. Slurry chemical corrosion was found to be enhanced when the slurry was diluted by deionized (DI) water during rinsing just after CMP@. Since the corrosion inhibitor, benzotriazole (BTA), reduces the Cu removal rate, adding it to the rinse solution prevents chemical corrosion more effectively than adding it to the slurry. On the other hand, galvanic corrosion occurs at the interface between Cu and the barrier metal, and it can be prevented by selecting appropriate barrier metals. Because the difference between the electrochemical potentials of Cu and the barrier metal is small in the slurry, refractory metals such as Ta, TaN, and TiN were found to be appropriate barrier metals. On the other hand, W, WN, and Ti have large potential differences, so galvanic corrosion was clearly observed when Cu/W damascene interconnects were fabricated.

  4. Aspects and mechanisms of austenitic stainless steel corrosion in case of sodium leaks under mineral wool insulation

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, C.; Ardellier, A. [Commissariat a l`Energie Atomique, Saint-Paul-Lez-Durance (France)

    1996-10-01

    Sodium pipe rupture tests representative of Fast Reactors accidents have been carried out on austenitic stainless steel surfaces. These tests improve the authors knowledge of small sodium leakage propagation in mineral wool insulation. Furthermore, they explain the new and unexpected aspects of the crevice corrosion phenomenon which has been observed on austenitic stainless steel external pipe surfaces. Experimental results show that the corrosion is limited to a peripheral annular zone, which extends out in concentric waves. The diameter of this corrosion zone is practically constant. Furthermore, the tests show that sodium does not expand directly on the pipe surface. The sodium sprays through the mineral wool insulation, where chemical reactions between silica fibers, occluded oxygen and water vapor occur at the same time. Simultaneously, there is a diffusion phenomenon of liquid sodium droplets on the mineral wool fibers. The study allows to prove the electrochemical nature of the corrosion. The excess liquid sodium, spraying as droplets on the pipe surface, induces an anodic dissolution mechanism by differential aeration. This phenomenon explains the random microscopic and macroscopic aspects of material removal.

  5. Characterization of biofilm and corrosion of cast iron pipes in drinking water distribution system with UV/Cl2 disinfection.

    Science.gov (United States)

    Zhu, Ying; Wang, Haibo; Li, Xiaoxiao; Hu, Chun; Yang, Min; Qu, Jiuhui

    2014-09-01

    The effect of UV/Cl2 disinfection on the biofilm and corrosion of cast iron pipes in drinking water distribution system were studied using annular reactors (ARs). Passivation occurred more rapidly in the AR with UV/Cl2 than in the one with Cl2 alone, decreasing iron release for higher corrosivity of water. Based on functional gene, pyrosequencing assays and principal component analysis, UV disinfection not only reduced the required initial chlorine dose, but also enhanced denitrifying functional bacteria advantage in the biofilm of corrosion scales. The nitrate-reducing bacteria (NRB) Dechloromonas exhibited the greatest corrosion inhibition by inducing the redox cycling of iron to enhance the precipitation of iron oxides and formation of Fe3O4 in the AR with UV/Cl2, while the rhizobia Bradyrhizobium and Rhizobium, and the NRB Sphingomonas, Brucella producing siderophores had weaker corrosion-inhibition effect by capturing iron in the AR with Cl2. These results indicated that the microbial redox cycling of iron was possibly responsible for higher corrosion inhibition and lower effect of water Larson-Skold Index (LI) changes on corrosion. This finding could be applied toward the control of water quality in drinking water distribution systems. Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. Effects of disinfectant and biofilm on the corrosion of cast iron pipes in a reclaimed water distribution system.

    Science.gov (United States)

    Wang, Haibo; Hu, Chun; Hu, Xuexiang; Yang, Min; Qu, Jiuhui

    2012-03-15

    The effects of disinfection and biofilm on the corrosion of cast iron pipe in a model reclaimed water distribution system were studied using annular reactors (ARs). The corrosion scales formed under different conditions were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), and scanning electron microscopy (SEM), while the bacterial characteristics of biofilm on the surface were determined using several molecular methods. The corrosion scales from the ARs with chlorine included predominantly α-FeOOH and Fe2O3, while CaPO3(OH)·2H2O and α-FeOOH were the predominant phases after chloramines replaced chlorine. Studies of the consumption of chlorine and iron release indicated that the formation of dense oxide layers and biofilm inhibited iron corrosion, causing stable lower chlorine decay. It was verified that iron-oxidizing bacteria (IOB) such as Sediminibacterium sp., and iron-reducing bacteria (IRB) such as Shewanella sp., synergistically interacted with the corrosion product to prevent further corrosion. For the ARs without disinfection, α-FeOOH was the predominant phase at the primary stage, while CaCO3 and α-FeOOH were predominant with increasing time. The mixed corrosion-inducing bacteria, including the IRB Shewanella sp., the IOB Sediminibacterium sp., and the sulfur-oxidizing bacteria (SOB) Limnobacter thioxidans strain, promoted iron corrosion by synergistic interactions in the primary period, while anaerobic IRB became the predominant corrosion bacteria, preventing further corrosion via the formation of protective layers. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. Biofilm-growing bacteria involved in the corrosion of concrete wastewater pipes: protocols for comparative metagenomic analyses.

    Science.gov (United States)

    Gomez-Alvarez, Vicente

    2014-01-01

    Advances in high-throughput next-generation sequencing (NGS) technology for direct sequencing of environmental DNA (i.e., shotgun metagenomics) are transforming the field of microbiology. NGS technologies are now regularly being applied in comparative metagenomic studies, which provide the data for functional annotations, taxonomic comparisons, community profile, and metabolic reconstructions. For example, comparative metagenomic analysis of corroded pipes unveiled novel insights on the bacterial populations associated with the sulfur and nitrogen cycle, which may be directly or indirectly implicated in concrete wastewater pipe corrosion. The objective of this chapter is to describe the steps involved in the taxonomic and functional analysis of metagenome datasets from biofilm involved in microbial-induced concrete corrosion (MICC).

  8. Recognition and Analysis of Corrosion Failure Mechanisms

    OpenAIRE

    Steven Suess

    2006-01-01

    Corrosion has a vast impact on the global and domestic economy, and currently incurs losses of nearly $300 billion annually to the U.S. economy alone. Because of the huge impact of corrosion, it is imperative to have a systematic approach to recognizing and mitigating corrosion problems as soon as possible after they become apparent. A proper failure analysis includes collection of pertinent background data and service history, followed by visual inspection, photographic documentation, materi...

  9. Recognition and Analysis of Corrosion Failure Mechanisms

    OpenAIRE

    Steven Suess

    2006-01-01

    Corrosion has a vast impact on the global and domestic economy, and currently incurs losses of nearly $300 billion annually to the U.S. economy alone. Because of the huge impact of corrosion, it is imperative to have a systematic approach to recognizing and mitigating corrosion problems as soon as possible after they become apparent. A proper failure analysis includes collection of pertinent background data and service history, followed by visual inspection, photographic documentation, materi...

  10. Erosion-corrosion; Erosionkorrosion

    Energy Technology Data Exchange (ETDEWEB)

    Aghili, B

    1999-05-01

    A literature study on erosion-corrosion of pipings in the nuclear industry was performed. Occurred incidents are reviewed, and the mechanism driving the erosion-corrosion is described. Factors that influence the effect in negative or positive direction are treated, as well as programs for control and inspection. Finally, examples of failures from databases on erosion-corrosion are given in an attachment 32 refs, 16 figs, tabs

  11. Fluid-structure-interaction analysis for welded pipes with flow-accelerated corrosion wall thinning

    Energy Technology Data Exchange (ETDEWEB)

    Sun, L.; Ding, Y., E-mail: lan.sun@cnl.ca [Canadian Nuclear Laboratories, Chalk River, Ontario (Canada)

    2016-06-15

    The flow-accelerated corrosion (FAC) entrance effect results in enhanced wall thinning immediately downstream of a weld if the weld connects an upstream FAC-resistant material with a downstream less resistant material. The weld regions, especially those with local repairs, are susceptible to cracking due to the high residual stresses induced by fabrication. The combined effects of the FAC entrance effect and high stresses at a weld might compromise the structural integrity of the piping and lead to a failure. Weld degradation by FAC entrance effect has been observed at nuclear and fossil power plants. This paper describes an application using fluid-structure-interaction (FSI) modelling to study the combined effects of FAC wall thinning, weld residual stresses, and in-service loads on welded structures. Simplified cases analyzed were based on CANDU outlet feeder conditions. The analysis includes the flow and mass transfer modelling of the FAC entrance effect using computational fluid dynamics (CFD) and nonlinear structural analyses of the welded structures with wall thinning and an assumed weld residual stress and strain distribution. The FSI analyses were performed using ANSYS Workbench, an integrated platform that enables the coupling of CFD and structural analysis solutions. The obtained results show that the combination of FAC, weld residual stresses, in-service loads (including the internal pressure) and (or) extreme loads could cause high stresses and affect the integrity of the welded pipes. The present work demonstrated that the FSI modelling can be used as an effective approach to assess the integrity of welded structures. (author)

  12. HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPE SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, R

    2010-05-02

    Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions exist. Pipe ruptures at nuclear facilities were attributed to hydrogen explosions inside pipelines, in nuclear facilities, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents an ignition source for hydrogen was questionable, but these accidents, demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein.

  13. Report of the US Nuclear Regulatory Commission Piping Review Committee. Volume 1. Investigation and evaluation of stress corrosion cracking in piping of boiling water reactor plants

    Energy Technology Data Exchange (ETDEWEB)

    1984-08-01

    IGSCC in BWR piping is occurring owing to a combination of material, environment, and stress factors, each of which can affect both the initiation of a stress-corrosion crack and the rate of its subsequent propagation. In evaluating long-term solutions to the problem, one needs to consider the effects of each of the proposed remedial actions. Mitigating actions to control IGSCC in BWR piping must be designed to alleviate one or more of the three synergistic factors: sensitized material, the convention BWR environment, and high tensile stresses. Because mitigating actions addressing each of these factors may not be fully effective under all anticipated operating conditions, mitigating actions should address two and preferably all three of the causative factors; e.g., material plus some control of water chemistry, or stress reversal plus controlled water chemistry.

  14. Corrosion resistance of ERW (Electric Resistance Welded) seam welds as compared to metal base in API 5L steel pipes

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Velasquez, Jorge L.; Godinez Salcedo, Jesus G.; Lopez Fajardo, Pedro [Instituto Politecnico Nacional (IPN), Mexico D.F. (Mexico). Escuela Superior de Ingenieria Quimica e Industrias Extractivas (ESIQIE). Dept. de Ingenieria Metalurgica

    2009-07-01

    The corrosion resistance of ERW seam welds and the base metal in API 5L X70 steel pipes was evaluated by Tafel tests. The procedure was according to ASTM G3 standard. The study was completed with metallographic and chemical characterization of the tested zones, that is, the welded zone and the base metal away of the weld. All tests were made on the internal surface of the pipe in order to assess the internal corrosion of an in-service pipeline made of the API 5L X70 steel. The test solution was acid brine prepared according to NACE Publications 1D182 and 1D196. The results showed that the ERW seam weld corrodes as much as three times faster than the base material. This behavior is attributed to a more heterogeneous microstructure with higher internal energy in the ERW seam weld zone, as compared to the base metal, which is basically a ferrite pearlite microstructure in a normalized condition. This result also indicates that pipeline segments made of ERW steel pipe where the seam weld is located near or at the bottom of the pipe are prone to a highly localized attack that may form channels of metal loss if there is water accumulation at the bottom of the pipeline. (author)

  15. Macroscopic corrosion front computations of sulfate attack in sewer pipes based on a micro-macro reaction-diffusion model

    CERN Document Server

    Chalupecký, Vladimír; Kruschwitz, Jens; Muntean, Adrian

    2012-01-01

    We consider a two-scale reaction diffusion system able to capture the corrosion of concrete with sulfates. Our aim here is to define and compute two macroscopic corrosion indicators: typical pH drop and gypsum profiles. Mathematically, the system is coupled, endowed with micro-macro transmission conditions, and posed on two different spatially-separated scales: one microscopic (pore scale) and one macroscopic (sewer pipe scale). We use a logarithmic expression to compute values of pH from the volume averaged concentration of sulfuric acid which is obtained by resolving numerically the two-scale system (microscopic equations with direct feedback with the macroscopic diffusion of one of the reactants). Furthermore, we also evaluate the content of the main sulfatation reaction (corrosion) product---the gypsum---and point out numerically a persistent kink in gypsum's concentration profile. Finally, we illustrate numerically the position of the free boundary separating corroded from not-yet-corroded regions.

  16. Modelling on corrosion inhibitor kinetics in carbon steel pipe used in oil industry

    Science.gov (United States)

    Hasmi, A. N.; Nuraini, N.; Wahyuningrum, D.; Sumarti, N.; Bunjali, B.

    2014-02-01

    A model to explain the kinetics of corrosion inhibitor is proposed here. The model is based on Transition State Theory. Our model has many similarities with Michelis-Menten Kinetics. The kinetics difference between uninhibited corrosion and inhibited corrosion is presented. Our model showed the inhibitor could suppress the corrosion rate.

  17. Comparative study on CO2 corrosion behavior of N80,P110,X52 and 13Cr pipe lines in simulated stratum water

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    To better understand the carbon dioxide (CO2) corrosion behavior of carbon steel and its influence on petroleum development (including drilling,production and transportation) in the Daqing Oilfield,CO2 corrosion behaviors of N80,P110,X52 and 13Cr pipe lines in simulated solution at high temperature and high pressure condition are investigated by dynamic corrosion experiments,scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) analyses.Results show that the corrosion rate of all pipe lines increases quickly when CO2 partial pressure increases from 0.5 to 1.5 MPa,but it slows down when CO2 partial pressure further increases from 1.5 to 4.5 MPa,during which localized corrosion is prevailing.When the experimental temperature ranges from 60 to 120°C,localized corrosion prevails.The corrosion rate of all pipe lines decreases sharply when the temperature changes from 60 to 100°C,and it becomes stable after the temperature is higher than 100°C.When the flow rate is in the range of 0–1.5 m/s,the corrosion rate of sample X52 remains unchanged,but localized corrosion gradually becomes very serious when the flow rate further increases.By analyzing the corrosion product scales of sample 13Cr,some remarkable phenomena are observed.At the temperature range of 60–100°C,the corrosion product scales are loose and thick,but become very compact when the temperature increases above 100°C.In the later case,localized corrosion is prevailing.The main components of the corrosion product scales are FeCO3 and Cr2O3.

  18. Mechanical characteristics of fused cast basalt tube encased in steel pipe for protecting steel surface

    Institute of Scientific and Technical Information of China (English)

    Jee-Seok WANG; Jong-Do KIM; Hee-Jong YOON

    2009-01-01

    Because of the various excellent characteristics of cast basalt materials, such as, anti-corrosion, anti-wearing, good hardness, high chemical stability, of which steel may not possess, the steel-basalt composite pipes are used in severe environments for compensating the defects of steel. The limit of bending moment with which steel-basalt composite pipe may safely endure was calculated and the limit curvature of the composite pipe in the safe range was presented. The application temperature of steel-basalt pipe was examined due to a different coefficient among basalt, mortar and mild steel.

  19. Aspects and mechanisms of austenitic stainless steel corrosion in case of sodium leaks under mineral wool insulation

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, C.; Ardellier, A.

    1996-12-31

    Sodium pipe rupture tests representative of Fast Reactors Accidents have been carried out on austenitic stainless steel surfaces. These tests improve our knowledge of small sodium leakage propagation in mineral wool insulation. They explain the new and unexpected aspects of the crevice corrosion phenomenon which has been observed on austenitic stainless steel pipe surfaces. Experimental results show that corrosion is limited to a peripheral annular zone, which extends out in concentric waves. The diameter of this corrosion zone is practically constant. Tests show that sodium does not expand directly on the pipe surface. Sodium sprays through mineral wool insulation, where chemical reaction between silica fibers, occluded oxygen and water vapor occur at the same time. Simultaneously, there is a diffusion phenomenon of liquid Na droplets on the mineral wool fibers. The study allows to prove the electrochemical nature of the corrosion. The excess liquid Na, spraying as droplets induces an anodic dissolution mechanism by differential aeration. This phenomenon explains the random microscopic and macroscopic aspects of material removal. (authors). 1 ref., 16 figs.

  20. Overview of piping issues and trends

    Energy Technology Data Exchange (ETDEWEB)

    Bush, S.H.

    1992-12-01

    A variety of failure mechanisms that have contributed to failures in nuclear reactor piping systems are discussed: these include general corrosion, intergranular stress corrosion, erosion-corrosion, mechanical fatigue, and thermal fatigue covering the spectrum from mixing-tee to stratification. Actions to minimize or eliminate these failure mechanisms are discussed where these actions are based on the experience amassed over the past three decades.

  1. Corrosion and erosion monitoring in plates and pipes using constant group velocity Lamb wave inspection.

    Science.gov (United States)

    Nagy, Peter B; Simonetti, Francesco; Instanes, Geir

    2014-09-01

    Recent improvements in tomographic reconstruction techniques generated a renewed interest in short-range ultrasonic guided wave inspection for real-time monitoring of internal corrosion and erosion in pipes and other plate-like structures. Emerging evidence suggests that in most cases the fundamental asymmetric A0 mode holds a distinct advantage over the earlier market leader fundamental symmetric S0 mode. Most existing A0 mode inspections operate at relatively low inspection frequencies where the mode is highly dispersive therefore very sensitive to variations in wall thickness. This paper examines the potential advantages of increasing the inspection frequency to the so-called constant group velocity (CGV) point where the group velocity remains essentially constant over a wide range of wall thickness variation, but the phase velocity is still dispersive enough to allow accurate wall thickness assessment from phase angle measurements. This paper shows that in the CGV region the crucial issue of temperature correction becomes especially simple, which is particularly beneficial when higher-order helical modes are also exploited for tomography. One disadvantage of working at such relatively high inspection frequency is that, as the slower A0 mode becomes faster and less dispersive, the competing faster S0 mode becomes slower and more dispersive. At higher inspection frequencies these modes cannot be separated any longer based on their vibration polarization only, which is mostly tangential for the S0 mode while mostly normal for the A0 at low frequencies, as the two modes become more similar as the frequency increases. Therefore, we propose a novel method for suppressing the unwanted S0 mode based on the Poisson effect of the material by optimizing the angle of inclination of the equivalent transduction force of the Electromagnetic Acoustic Transducers (EMATs) used for generation and detection purposes.

  2. Waste incineration corrosion processes: Oxidation mechanisms by electrochemical impedance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Perez, F.J.; Hierro, M.P.; Nieto, J. [Departamento de Ciencia de los Materiales. Facultad de Ciencias Quimicas, Grupo de Investigacion de Ingenieria de Superficies, Universidad Complutense de Madrid, 28040 Madrid (Spain)

    2008-07-15

    Molten chloride mixtures are formed in waste incineration plants during waste firing and energy production. These mixtures are responsible for degradation processes like hot corrosion. In order to evaluate the damage of molten salt mixtures in waste incineration environments, the alloys 625 and 617 were exposed beneath a molten KCl-ZnCl{sub 2} mixture at 650 C in air. The corrosion process was monitored by electrochemical impedance spectroscopy (EIS). An extensive microscopy analysis has been done in order to correlate the electrochemical results, and to establish an electrochemical mechanism for such high temperature corrosion processes. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

  3. Mechanism for Corrosion Prevention by a Mechanical Plating of Uniform Zinc-Iron Alloy

    Science.gov (United States)

    Kasai, Naoya; Kaku, Yoshihiko; Okazaki, Shinji; Hirai, Kuninori

    2016-09-01

    In situ electrochemical monitoring with a three-electrode cell was applied to investigate the anti-corrosion properties of a mechanical zinc-iron alloy plating. Several electron probe microanalyses were also conducted to identify the chemical elements in the plating. The results indicated the formation of a Zn-Fe intermetallic compound, which allowed a mechanism for corrosion prevention to be proposed. In the proposed mechanism, Zn(OH)2 plays a significant role in the corrosion prevention of steel alloys.

  4. Identifying thermal cycling mechanisms in PWR branch line piping

    Energy Technology Data Exchange (ETDEWEB)

    Rosinski, S.T. [EPRI, Charlotte, NC (United States); Keller, J.D.; Bilanin, A.J. [Continuum Dynamics, Inc., Ewing, NJ (United States)

    2002-07-01

    Predicting the onset and the characteristics of thermal cycling in pressurized water reactor (PWR) branch line piping systems is critical to formulation of thermal fatigue screening tools. The complex nature of the underlying thermal-hydraulic phenomena, however, significantly complicates prediction using analytical models or direct numerical simulations. Instead, it is necessary to perform scaled experiments to identify the physical mechanisms and to gather data for formulation of semi-empirical models for the thermal cycling phenomena. Through the EPRI Materials Reliability Program a test program is underway to identify and develop semi-empirical correlations for the physical thermalhydraulic mechanisms that cause thermal cycling in dead-ended PWR branch line piping systems. Three series of tests are being performed in this test program: configuration tests on a representative up-horizontal (UH) branch line piping geometry, configuration tests on a representative down-horizontal (DH) branch line piping geometry, and high Reynolds number tests to assess penetration of secondary flow structures into a dead-ended branch line. Results from UH and DH configuration tests indicate that random turbulence penetration is not sufficient for thermal cycling to occur. Rather a swirling flow structure, representative of a large, 'corkscrew' vortical structure, is required for thermal cycling. Scale tests on the UH configuration have simulated cycling phenomena observed in full-scale plant data and have been used to determine parametric sensitivities in formulating a predictive model for the thermal cycling. Data indicate that the mechanism for thermal cycling in UH configurations is stochastic but scales with the leak rate from the valve. The critical dependent variables are reduced to several non-dimensional scaling curves, resulting in a semiempirical predictive model. This paper discusses the test program and the results obtained to date. Application of these

  5. Interaction of sulfuric acid corrosion and mechanical wear of iron

    Science.gov (United States)

    Rengstorff, G. W. P.; Miyoshi, K.; Buckley, D. H.

    1986-01-01

    Friction and wear experiment were conducted with elemental iron sliding on aluminum oxide in aerated sulfuric acid at concentrations ranging from very dilute (0.00007 N; i.e., 4 ppm) to very concentrated (96 percent acid). Load and reciprocating sliding speed were kept constant. With the most dilute acid concentration of 0.00007 to 0.0002 N, a complex corrosion product formed that was friable and often increased friction and wear. At slightly higher concentrations of 0.001 N, metal losses were essentially by wear alone. Because no buildup of corrosion products occurred, this acid concentration became the standard from which to separate metal loss from direct corrosion and mechanical wear losses. When the acid concentration was increased to 5 percent (1 N), the well-established high corrosion rate of iron in sulfuric acid strongly dominated the total wear loss. This strong corrosion increased to 30 percent acid and decreased somewhat to 50 percent acid in accordance with expectations. However, the low corrosion of iron expected at acid concentrations of 65 to 96 percent was not observed in the wear area. It was apparent that the normal passivating film was being worn away and a galvanic cell established that rapidly attacked the wear area. Under the conditions where direct corrosion losses were highest, the coefficient of friction was the lowest.

  6. Real-time corrosion control system for cathodic protection of buried pipes for nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki Tae; Kim, Hae Woong; Kim, Young Sik [School of Materials Science and Engineering, Andong National University, Andong (Korea, Republic of); Chang, Hyun Young; Lim, Bu Taek; Park, Heung Bae [Power Engineering Research Institute, KEPCO Engineering and Construction Company, Seongnam (Korea, Republic of)

    2015-02-15

    Since the operation period of nuclear power plants has increased, the degradation of buried pipes gradually increases and recently it seems to be one of the emerging issues. Maintenance on buried pipes needs high quality of management system because outer surface of buried pipe contacts the various soils but inner surface reacts with various electrolytes of fluid. In the USA, USNRC and EPRI have tried to manage the degradation of buried pipes. However, there is little knowledge about the inspection procedure, test and manage program in the domestic nuclear power plants. This paper focuses on the development and build-up of real-time monitoring and control system of buried pipes. Pipes to be tested are tape-coated carbon steel pipe for primary component cooling water system, asphalt-coated cast iron pipe for fire protection system, and pre-stressed concrete cylinder pipe for sea water cooling system. A control system for cathodic protection was installed on each test pipe which has been monitored and controlled. For the calculation of protection range and optimization, computer simulation was performed using COMSOL Multiphysics (Altsoft co.)

  7. Evaluation of Neutron Elastic Scatter (NES) technique for detection of graphitic corrosion in gas cast iron pipe. Final report, March 1996-April 1997

    Energy Technology Data Exchange (ETDEWEB)

    Charatis, G.; Hugg, E.; McEllistrem, M.

    1997-04-01

    PENETRON, Inc., in two phases, demonstrated the effectiveness of its Neutron elastic Scatter (NES) techniques in detecting the change in the carbon weight percentage (CWt%) as a measure of corrosion in gray cast iron pipe. In Phase I, experiments were performed with synthetic standards supplied by IIT Research Institute (IITRI) to test the applicability of the NES techniques. Irradiation experiments performed at the University of Kentucky showed that CWt% could be detected, ranging from 1.6% to 13%, within an uncertainty of around 4%. In Phase II, experiments were performed on seven (7) corroded pipe sections supplied by MichCon. Tests were made on pipe sliced lengthwise into quarter sections, and in re-assembled whole pipe sections. X-ray films of the quarter sections indicated probable areas of corrosion for each quarter section.

  8. Corrosion

    Science.gov (United States)

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  9. Corrosion

    Science.gov (United States)

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  10. Microbiologically Influenced Corrosion: Global Phenomena, Local Mechanisms

    Science.gov (United States)

    2011-02-17

    because extent of ennoblement is affected by sample size. How rale and temperature (Little et al. 2008). Ennoblement has been measured for metals boldly...exposed, metals incorporated in crevice assemblies and polarized metals . The alloys tested include, but are not limited to: UNS S30400, S30403...fresh water, ennoblement can be the result of microbial deposition of manganese and localized corrosion has been related directly to the biomineralized

  11. Corrosion and mechanical behavior of materials for coal gasification applications

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K.

    1980-05-01

    A state-of-the-art review is presented on the corrosion and mechanical behavior of materials at elevated temperatures in coal-gasification environments. The gas atmosphere in coal-conversion processes are, in general, complex mixtures which contain sulfur-bearing components (H/sub 2/S, SO/sub 2/, and COS) as well as oxidants (CO/sub 2//CO and H/sub 2/O/H/sub 2/). The information developed over the last five years clearly shows sulfidation to be the major mode of material degradation in these environments. The corrosion behavior of structural materials in complex gas environments is examined to evaluate the interrelationships between gas chemistry, alloy chemistry, temperature, and pressure. Thermodynamic aspects of high-temperature corrosion processes that pertain to coal conversion are discussed, and kinetic data are used to compare the behavior of different commercial materials of interest. The influence of complex gas environments on the mechanical properties such as tensile, stress-rupture, and impact on selected alloys is presented. The data have been analyzed, wherever possible, to examine the role of environment on the property variation. The results from ongoing programs on char effects on corrosion and on alloy protection via coatings, cladding, and weld overlay are presented. Areas of additional research with particular emphasis on the development of a better understanding of corrosion processes in complex environments and on alloy design for improved corrosion resistance are discussed. 54 references, 65 figures, 24 tables.

  12. Effects of Induction Heat Bending and Heat Treatment on the Boric Acid Corrosion of Low Alloy Steel Pipe for Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki-Tae; Kim, Young-Sik [Andong National University, Gyeongbuk (Korea, Republic of); Chang, Hyun-Young; Park, Heung-Bae [KEPCO EandC, Gyeongbuk (Korea, Republic of); Sung, Gi-Ho; Shin, Min-Chul [Sungil SIM Co. Ltd, Busan (Korea, Republic of)

    2016-11-15

    In many plants, including nuclear power plants, pipelines are composed of numerous fittings such as elbows. When plants use these fittings, welding points need to be increased, and the number of inspections also then increases. As an alternative to welding, the pipe bending process forms bent pipe by applying strain at low or high temperatures. This work investigates how heat treatment affects on the boric acid corrosion of ASME SA335 Gr. P22 caused by the induction heat bending process. Microstructure analysis and immersion corrosion tests were performed. It was shown that every area of the induction heat bent pipe exhibited a high corrosion rate in the boric acid corrosion test. This behavior was due to the enrichment of phosphorous in the ferrite phase, which occurred during the induction heat bending process. This caused the ferrite phase to act as a corrosion initiation site. However, when re-heat treatment was applied after the bending process, it enhanced corrosion resistance. It was proved that this resistance was closely related to the degree of the phosphorus segregation in the ferrite phase.

  13. Analysis of mechanical behaviors of big pipe roof for shallow buried large-span tunnel

    Institute of Scientific and Technical Information of China (English)

    Li Jian; Tan Zhongsheng; Yu Yu; Guo Xiaohong

    2013-01-01

    A series of researches on mechanical behaviors of big pipe roof for shallow large-span loess tunnel were carried out based on the Wenxiang tunnel in Zhengzhou-Xi’an Special Passenger Railway. The longitudinal de-formations of the pipe roofs were monitored and the mechanical behaviors of the pipe roofs were analyzed at the test section. A new double-parameter elastic foundation beam model for pipe roof in shallow tunnels was put for-ward in Wenxiang tunnel. The measured values and the calculation results agreed well with each other,revealing the force-deformation law of big pipe roof in loess tunnel:At about 15 m in front of the excavating face,the pipe roof starts to bear the load;at about 15 m behind the excavating face,the force of the pipe roof tends to be stabi-lized;the longitudinal deformation of the whole pipe roofs is groove-shaped distribution,and the largest force of pipe roofs is at the excavating face. Simultaneously,the results also indicate that mechanical behaviors of pipe roof closely relate to the location of the excavation face,the footage of the tunnelling cycle and the mechanics pa-rameters of pipe roof and rock. The conclusions can be reference for the design parameter optimization and the con-struction scheme selection of pipe roofs,and have been verified by the result of numerical analysis software FLAC3D and deformation monitoring.

  14. Continuous Surveillance Technique for Flow Accelerated Corrosion of Pipe Wall Using Electromagnetic Acoustic Transducer

    Science.gov (United States)

    Kojima, F.; Kosaka, D.; Umetani, K.

    2011-06-01

    In this paper, we propose a on-line monitoring technique using electromagnetic acoustic transducer (EMAT). In the series of laboratory experiments, carbon steel pipes were used and each sample was fabricated to simulate FAC. Electromagnetic acoustic resonance method (EMAR) is successfully tested for pipe wall thickness measurements. The validity and the feasibility of our method are also demonstrated through the laboratory experiments.

  15. C10H18N2Na2O10 inhibition and adsorption mechanism on concrete steel-reinforcement corrosion in corrosive environments

    National Research Council Canada - National Science Library

    Okeniyi, Joshua Olusegun

    2016-01-01

    C10H18N2Na2O10 (ethylenediaminetetra-acetic acid disodium salt) inhibition and adsorption mechanism on the corrosion of steel-reinforcement corrosion in concrete immersed in corrosive environments were investigated in this paper...

  16. Corrosion of Mechanically Alloyed Nanostructured FeAl Intermetallic Powders

    Directory of Open Access Journals (Sweden)

    A. Torres-Islas

    2012-01-01

    Full Text Available The corrosion behavior of the Fe40Al60 nanostructured intermetallic composition was studied using electrochemical impedance spectroscopy (EIS and linear polarization resistance (LPR techniques with an innovative electrochemical cell arrangement. The Fe40Al60 (% at intermetallic composition was obtained by mechanical alloying using elemental powders of Fe (99.99% and Al (99.99%. All electrochemical testing was carried out in Fe40Al60 particles that were in water with different pH values. Temperature and test time were also varied. The experimental data was analyzed as an indicator of the monitoring of the particle corrosion current density icorr. Different oxide types that were formed at surface particle were found. These oxides promote two types of surface corrosion mechanisms: (i diffusion and (ii charge transfer mechanisms, which are a function of icorr behavior of the solution, pH, temperature, and test time. The intermetallic was characterized before and after each test by transmission electron microscopy. Furthermore, the results show that at the surface particles uniform corrosion takes place. These results confirm that it is possible to sense the nanoparticle corrosion behavior by EIS and LPR conventional electrochemical techniques.

  17. Corrosion of pipe steel in CO2 containing impurities and possible solutions

    NARCIS (Netherlands)

    Zhang, X.; Zevenbergen, J.F.; Spruijt, M.P.N.; Borys, M.

    2013-01-01

    CO2 flue gases acquired from different sources contain a significant amount of impurities and water, which are corrosive to the pipeline steel. To design the pipelines for large scale of CO2 flue gas transport, the corrosion of pipeline steels has to be investigated in the realistic conditions. In t

  18. Corrosion of pipe steel in CO2 containing impurities and possible solutions

    NARCIS (Netherlands)

    Zhang, X.; Zevenbergen, J.F.; Spruijt, M.P.N.; Borys, M.

    2013-01-01

    CO2 flue gases acquired from different sources contain a significant amount of impurities and water, which are corrosive to the pipeline steel. To design the pipelines for large scale of CO2 flue gas transport, the corrosion of pipeline steels has to be investigated in the realistic conditions. In

  19. Pure mechanical wear loss measurement in corrosive wear

    Indian Academy of Sciences (India)

    Yanliang Huang; Xiaoxia Jiang; Sizuo Li

    2000-12-01

    The method for the measurement of the pure mechanical wear loss for 321 stainless steel, 1045 steel and pure iron in the study of the synergy between corrosion and wear was studied. The methods studied included the measurement in distilled water, by cathodic protection and by adding inhibitor KI, and all were compared with the wear loss in air. The experiment showed that the pure mechanical wear losses and friction coefficients obtained by the three methods were close to each other and can be used to calculate the various wear components in the study of the interaction of corrosion and wear, but the measurements in distilled water for pure iron and 1045 steel are not recommended due to their corrosion.

  20. Research on H2S Corrosion Resistance Performance of X60 Helical Submerged Arc Welded(SAWH)Pipe%X60螺旋埋弧焊管抗H2S腐蚀性能研究

    Institute of Scientific and Technical Information of China (English)

    梁根选

    2011-01-01

    Regarding to great demand for steel pipe with resistance to corrosion in the oil and gas pipeline construction in China, this article introduced the research work to pipeline steel and steel pipe under the anti-H2S condition, through physical and chemical performance, hydrogen-inductive crack (HIC), sulfide stress cracking (SSC) and other tests, it carried out resistance to corrosion study to X60 pipeline steel and SAWH pipe, and achieved the following results. Through research and analysis on the resistance to H?5 corrosion welded pipe from the abroad, it put forward resistance to H2S corrosion technical requirements of X60 HRC and X60 SAWH pipe. It pointed out that metallurgy process, especially control the content of S and P, which is the critical factor to determine the material performance to resistance to H2S corrosion; In addition, the amounts, shape, distribution and non-metallic inclusions in steel, as well as, the type, configuration of microstructure also affected resistance to H2S corrosion. It conducted the tests of HIC and SSC under low and high stress conditions to X60 HRC and X60 SAWH pipe produced by optimized welding procedure. The test results showed that the mechanical performance of SAWH pipe and resistance to H2S performance indexes can meet the requirements of technical specification.The developed X60 resistance to H2S corrosion SAWH pipe is widely used in the domestic oil and gas pipelines, these pipelines are under good service.%针对我国油气输送管线建设中需要大量耐腐蚀钢管的需求,进行了耐H2S环境腐蚀下的管线钢及输送钢管的研究工作,通过理化性能、氢致开裂、硫化物应力开裂等试验对X60管线钢和螺旋埋弧焊管进行了耐蚀性研究,取得了以下结果:通过对国外抗H2S腐蚀焊管的技术条件分析研究,提出我国X60抗H2S卷板技术要求和X60螺旋埋弧焊管抗H2S腐蚀性能的要求,指出冶金工艺,尤其是S,P含量的控制是决定材料抗硫化

  1. State-of-the-art report on piping fracture mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Wilkowski, G.M.; Olson, R.J.; Scott, P.M. [Battelle, Columbus, OH (United States)

    1998-01-01

    This report is an in-depth summary of the state-of-the-art in nuclear piping fracture mechanics. It represents the culmination of 20 years of work done primarily in the US, but also attempts to include important aspects from other international efforts. Although the focus of this work was for the nuclear industry, the technology is also applicable in many cases to fossil plants, petrochemical/refinery plants, and the oil and gas industry. In compiling this detailed summary report, all of the equations and details of the analysis procedure or experimental results are not necessarily included. Rather, the report describes the important aspects and limitations, tells the reader where he can go for further information, and more importantly, describes the accuracy of the models. Nevertheless, the report still contains over 150 equations and over 400 references. The main sections of this report describe: (1) the evolution of piping fracture mechanics history relative to the developments of the nuclear industry, (2) technical developments in stress analyses, material property aspects, and fracture mechanics analyses, (3) unresolved issues and technically evolving areas, and (4) a summary of conclusions of major developments to date.

  2. Mechanical Properties and Corrosion Behavior of Low Carbon Steel Weldments

    Directory of Open Access Journals (Sweden)

    Mohamed Mahdy

    2013-01-01

    Full Text Available This research involves studying the mechanical properties and corrosion behavior of “low carbon steel” (0.077wt% C before and after welding using Arc, MIG and TIG welding. The mechanical properties include testing of microhardness, tensile strength, the results indicate that microhardness of TIG, MIG welding is more than arc welding, while tensile strength in arc welding more than TIG and MIG.The corrosion behavior of low carbon weldments was performed by potentiostat at scan rate 3mV.sec-1 in 3.5% NaCl to show the polarization resistance and calculate the corrosion rate from data of linear polarization by “Tafel extrapolation method”. The results indicate that the TIG welding increase the corrosion current density and anodic Tafel slop, while decrease the polarization resistance compared with unwelded low carbon steel. Cyclic polarization were measured to show resistance of specimens to pitting corrosion and to calculate the forward and reveres potentials. The results show shifting the forward, reverse and pitting potentials toward active direction for weldments samples compared with unwelded sample.

  3. Corrosion and cathodic protection of buried pipes: study, simulation and application of solar energy; Corrosion et protection cathodique des canalisations enterrees: etude, simulation et application de l energie solaire

    Energy Technology Data Exchange (ETDEWEB)

    Laoun, Brahim; Serir, Lazhar [Unite de Recherche Appliquee en Energies Renouvelables, URAER / Zone Industrielle Gaar Taam B.P. 88 - 47001, Ghardaia, (Algeria); Niboucha, Karima [Centre de Recherche Scientifique et Technique en Soudage et Controle, CSC / Route de Dely Brahim B.P. 64 - 16000, Cheraga, Alger, (Algeria)

    2006-07-01

    Cathodic protection is intensively used on steel pipes in petroleum and gas industries. It is a technique used to prevent corrosion which transforms the whole pipe into a cathode of a corrosion cell. Two types of cathodic protection systems are usually used: 1) the galvanic protection systems which use galvanic anodes, also called sacrificial anodes being electrochemically more electronegative than the structure to be protected and 2) the imposed current systems, which through a current generator will deliver a direct current from the anode to the structure to be protected. The aim of this work is to design a cathodic protection system of a pipe by imposed current with auxiliary electric solar energy. (O.M.)

  4. Evaluation of cold bending and mechanical properties of helical (SAWH) and longitudinal (SAWL) seam pipes

    Energy Technology Data Exchange (ETDEWEB)

    Batista, Gilmar Zacca; Sanandres, Simon Ricardo [PETROBRAS, Rio de Janeiro, RJ (Brazil). Pipeline Engineering Division; Pinto, Percy Saavedra; Mello, Marcelo [Tubos Soldados Atlantico, Sao Paulo, SP (Brazil)

    2009-07-01

    The present work is a part of a comprehensive program that aims to evaluate the helical seam pipe application in pipeline construction and compare with the traditional longitudinal seam pipe that have been used in Brazil. One of the biggest concerns is the cold bending process once the Brazilian land profile is very sinuous, different than other countries where helical seam pipes have been used successfully. At this work, two pipes were used, one helical seam and one longitudinal seam, both API 5L X70 with 28 inch of diameter and 0.469 inch wall thickness. The results of cold bending tests comparing both types of pipe and the mechanical properties from the straight pipe with the bend section are shown. The research methodology includes dimensional analysis, microstructural evaluation and mechanical tests that were performed on the straight pipe and bend areas. The cold bending parameters used to obtain a bend according the design and construction standards requirements are also presented. The results showed that the cold bending process produces a helical seam pipe bend with the most critical radius allowed by the standards, without presenting any evidence of wrinkles, out-of-roundness above the limits or any type of mechanical damage. Both pipes tested met the standards requirements in terms of bending and mechanical properties. The results of this study provide technical information for future helical seam pipe application in Brazil. (author)

  5. Chemical and mechanical control of corrosion product transport

    Energy Technology Data Exchange (ETDEWEB)

    Hede Larsen, O.; Blum, R. [I/S Fynsvaerket, Faelleskemikerne, Odense (Denmark); Daucik, K. [I/S Skaerbaekvaerket, Faelleskemikerne, Fredericia (Denmark)

    1996-12-01

    The corrosion products formed in the condensate and feedwater system of once-through boilers are precipitated and deposited inside the evaporator tubes mainly in the burner zone at the highest heat flux. Depositions lead to increased oxidation rate and increased metal temperature of the evaporator tubes, hereby decreasing tube lifetime. This effect is more important in the new high efficiency USC boilers due to increased feedwater temperature and hence higher thermal load on the evaporator tubes. The only way to reduce the load on the evaporator tubes is to minimise corrosion product transport to the boiler. Two general methods for minimising corrosion product transport to the boiler have been evaluated through measurement campaigns for Fe in the water/steam cycle in supercritical boilers within the ELSAM area. One method is to reduce corrosion in the low temperature condensate system by changing conditioning mode from alkaline volatile treatment (AVT) to oxygenated treatment (OT). The other method is to filtrate part of the condensate with a mechanical filter at the deaerator. The results show, that both methods are effective at minimising Fe-transport to the boiler, but changing to OT has the highest effect and should always be used, whenever high purity condensate is maintained. Whether mechanical filtration also is required, depends on the boiler, specifically the load on the evaporator. A simplified calculation model for lifetime evaluation of evaporator tubes has been developed. This model has been used for evaluating the effect of corrosion product transport to the boiler on evaporator tube lifetime. Conventional supercritical boilers generally can achieve sufficient lifetime by AVT and even better by OT, whereas all measures to reduce Fe-content of feedwater, including OT and mechanical filtration, should be taken, to ensure sufficient lifetime for the new boilers with advanced steam data - 290 bar/580 deg. C and above. (au)

  6. Modeling of hydrogen sulfide oxidation in concrete corrosion products from sewer pipes.

    Science.gov (United States)

    Jensen, Henriette Stokbro; Nielsen, Asbjørn Haaning; Hvitved-Jacobsen, Thorkild; Vollertsen, Jes

    2009-04-01

    Abiotic and biotic oxidation of hydrogen sulfide related to concrete corrosion was studied in corrosion products originating from a sewer manhole. The concrete corrosion products were suspended in an acidic solution, mimicking the conditions in the pore water of corroded concrete. The removal of hydrogen sulfide and dissolved oxygen was measured in parallel in the suspension, upon which the suspension was sterilized and the measurement repeated. The results revealed the biotic oxidation to be fast compared with the abiotic oxidation. The stoichiometry of the hydrogen sulfide oxidation was evaluated using the ratio between oxygen and hydrogen sulfide uptake. The ratio for the biotic oxidation pointed in the direction of elemental sulfur being formed as an intermediate in the oxidation of hydrogen sulfide to sulfuric acid. The experimental results were applied to suggest a hypothesis and a mathematical model describing the hydrogen sulfide oxidation pathway in a matrix of corroded concrete.

  7. Mechanism of non-axisymmetric pipe-wall thinning in pipeline with elbow and orifice under influence of swirling flow

    Energy Technology Data Exchange (ETDEWEB)

    Fujisawa, Nobuyuki, E-mail: fujisawa@eng.niigata-u.ac.jp [Visualization Research Center, Niigata University, Niigata (Japan); Kanatani, Nobuaki [Graduate School of Science and Technology, Niigata University, Niigata (Japan); Yamagata, Takayuki, E-mail: yamagata@eng.niigata-u.ac.jp [Visualization Research Center, Niigata University, Niigata (Japan); Takano, Tsuyoshi [Graduate School of Science and Technology, Niigata University, Niigata (Japan)

    2015-04-15

    Highlights: • Pipe-wall thinning due to flow accelerated corrosion is studied. • Pipeline geometry consists of elbow and orifice in swirling flow. • Velocity field and mass transfer rate are measured in pipeline. • Non-axisymmetric pipe-wall thinning occurs behind orifice. - Abstract: In this study, the mechanism of non-axisymmetric pipe-wall thinning that led to a pipeline break in the Mihama nuclear power plant in 2004 is evaluated in a scale-model experiment in a water tunnel having an elbow and orifice under the influence of swirling flow. The velocity fields are measured by stereo particle image velocimetry, and the mass transfer rate is measured by a benzoic acid dissolution method at Reynolds number Re = 3 × 10{sup 4} with and without swirling flow. The non-axisymmetric swirling flow is found to be generated behind the elbow, even when the axisymmetric swirling flow is supplied in the upstream of the elbow. The secondary flow generated in the elbow is not suppressed in the pipeline 10 diameters downstream of elbow in the swirling flow, and in this flow geometry, the non-axisymmetry of the flow is greatly magnified downstream of the orifice. The measured mass transfer rates downstream of the orifice under the influence of swirling flow indicate that the Sherwood number distribution on one side of the pipe is enhanced and that on the other side is reduced owing to the appearance of the non-axisymmetric swirling flow, which results in the occurrence of non-axisymmetric pipe-wall thinning downstream of the orifice.

  8. Corrosion risks with polyethylene pipes in district cooling systems; Korrosionsrisker vid anvaendning av polyetenroer i fjaerrkylesystem

    Energy Technology Data Exchange (ETDEWEB)

    Vinka, Tor-Gunnar; Almquist, Joergen; Gubner, Rolf [Swedish Corrosion Inst., Stockholm (Sweden)

    2005-06-01

    Field exposures of carbon steel and stainless steel test cylinders have been made in the district cooling system at Affaersverken Energi AB, Karlskrona, Sweden, as well as determinations of the amount of dissolved oxygen in the district cooling water. In the district cooling system tubes of polyethylene, carbon steel and stainless steel SS 2343 according to Swedish standard SS 14 23 43 are used. Karlskrona's drinking water, without deaeration, is used in the district cooling system. The polyethylene tubes with pressure number PN 10 are placed underground. The content of dissolved oxygen was very low in Karlskrona both before and after a period of 19 days with elevated oxygen content. During these 19 days the content of dissolved oxygen in the system increased without any apparent cause. The highest recorded oxygen content was 3.4 mg O{sub 2}/l. There are no obvious explanations for the increase of oxygen in the system. However, transport of oxygen into the system through the polyethylene tubes can be excluded as the source of the entering oxygen. The corrosion rate that was determined for freely exposed carbon steel in the district heating water in Karlskrona was low, 5 {mu}m/year. The corrosion attack was of a uniform nature (general corrosion) and there were no local corrosion attacks on the carbon steel cylinders. On connecting the carbon steel with stainless steel SS 23 43 with an area ratio of 1:1 the corrosion rate of the carbon steel increased by 2-3 times as compared to free exposure without electrical connection. On the stainless steel SS 2343 there was no corrosion damage either on the freely exposed stainless steel or on stainless steel that was connected to carbon steel. There were no signs of pitting corrosion or crevice corrosion on the stainless steel cylinders. The main corrosion risk for carbon steel at an elevated content of dissolved oxygen is bimetallic corrosion (galvanic corrosion) between carbon steel and copper and copper alloys, or

  9. Corrosion risks with polyethylene pipes in district cooling systems; Korrosionsrisker vid anvaendning av polyetenroer i fjaerrkylesystem

    Energy Technology Data Exchange (ETDEWEB)

    Vinka, Tor-Gunnar; Almquist, Joergen; Gubner, Rolf [Swedish Corrosion Inst., Stockholm (Sweden)

    2005-06-01

    Field exposures of carbon steel and stainless steel test cylinders have been made in the district cooling system at Affaersverken Energi AB, Karlskrona, Sweden, as well as determinations of the amount of dissolved oxygen in the district cooling water. In the district cooling system tubes of polyethylene, carbon steel and stainless steel SS 2343 according to Swedish standard SS 14 23 43 are used. Karlskrona's drinking water, without deaeration, is used in the district cooling system. The polyethylene tubes with pressure number PN 10 are placed underground. The content of dissolved oxygen was very low in Karlskrona both before and after a period of 19 days with elevated oxygen content. During these 19 days the content of dissolved oxygen in the system increased without any apparent cause. The highest recorded oxygen content was 3.4 mg O{sub 2}/l. There are no obvious explanations for the increase of oxygen in the system. However, transport of oxygen into the system through the polyethylene tubes can be excluded as the source of the entering oxygen. The corrosion rate that was determined for freely exposed carbon steel in the district heating water in Karlskrona was low, 5 {mu}m/year. The corrosion attack was of a uniform nature (general corrosion) and there were no local corrosion attacks on the carbon steel cylinders. On connecting the carbon steel with stainless steel SS 23 43 with an area ratio of 1:1 the corrosion rate of the carbon steel increased by 2-3 times as compared to free exposure without electrical connection. On the stainless steel SS 2343 there was no corrosion damage either on the freely exposed stainless steel or on stainless steel that was connected to carbon steel. There were no signs of pitting corrosion or crevice corrosion on the stainless steel cylinders. The main corrosion risk for carbon steel at an elevated content of dissolved oxygen is bimetallic corrosion (galvanic corrosion) between carbon steel and copper and copper alloys, or

  10. Research on Corrosion Inhibitor of Oil and Gas Pipe%油气管道腐蚀缓蚀剂的研究

    Institute of Scientific and Technical Information of China (English)

    曹登祥; 臧子璇; 张家兰; 彭晓青; 林玉梓

    2000-01-01

    根据缓蚀剂对金属腐蚀的机理,选用不同性能的缓蚀剂和表面活性剂进行复配,对模拟的油、气管道常规输送工况进行了静、动态对比试验。通过试验数据分析,寻求了最佳的缓蚀剂与表面活性剂的配比。%According to principle of corrosion inhibitor, by means of selecting different property corrosion inhibitors and surface active material to mix, comparing static with dynamic experiment was carried out in simulating conventional transfer condition of oil and gas pipe. The experiment results show that the correct and effective corrosion control is to find out the best mixed proportion of corrosion inhibitor and surface active material which can improve the corrosion inhibitor property and decrease preventing cost from corruptness of oil and gas pipe.

  11. Corrosion inhibitor mechanisms on reinforcing steel in Portland cement pastes

    Science.gov (United States)

    Martin, Farrel James

    2001-07-01

    The mechanisms of corrosion inhibitor interaction with reinforcing steel are investigated in the present work, with particular emphasis on effects associated with corrosion inhibitors admixed into Portland cement paste. The principal objective in reinforcing steel corrosion inhibition for Portland cement concrete is observed to be preservation of the naturally passive steel surface condition established by the alkaline environment. Introduction of chloride ions to the steel surface accelerates damage to the passive film. Excessive damage to the passive film leads to loss of passivity and a destabilization of conditions that facilitate repair of the passive film. Passive film preservation in presence of chloride ions is achieved either through stabilization of the passive film or by modification of the chemical environment near the steel surface. Availability of inhibitors to the steel surface and their tendency to stabilize passive film defects are observed to be of critical importance. Availability of admixed corrosion inhibitors to the passive film is affected by binding of inhibitors during cement paste hydration. It is determined that pore solution concentrations of inorganic admixed inhibitors tend to be lower than the admixed concentration, while pore solution concentrations of organic admixed inhibitors tend to be higher than the admixed concentration. A fundamental difference of inhibitor function is observed between film-forming and defect stabilizing corrosion inhibitors. Experiments are conducted using coupons of reinforcing steel that are exposed to environments simulating chloride-contaminated Portland cement concrete. A study of the steel/cement paste interface is also performed, and compounds forming at this interface are identified using X-Ray diffraction.

  12. Elevated temperature mechanical properties of line pipe steels

    Science.gov (United States)

    Jacobs, Taylor Roth

    strength and strain hardening occurred increased with increasing strain rate. Strain rate sensitivities were measured using flow stress data from multiple tensile tests and strain rate jump tests on single tensile samples. In flow stress strain rate sensitivity measurements, a transition from negative to positive strain rate sensitivity was observed in the X52 steel at approximately 275--300 °C, and negative strain rate sensitivity was observed at all elevated temperature testing conditions in the X70 steels. In jump test strain rate sensitivity measurements, all four steels exhibited a transition from negative to positive strain rate sensitivity at approximately 250--275 °C. Anisotropic deformation in the X70 steels was observed by measuring the geometry of the fracture surfaces of the tensile samples. The degree of anisotropy changed as a function of temperature and minima in the degree of anisotropy was observed at approximately 300 °C for all three X70 steels. DSA was verified as an active strengthening mechanism at elevated temperatures for all line pipe steels tested resulting in serrated yielding, a minimum in ductility as a function of temperature, a maximum in flow strength as a function of temperature, a maximum in average strain hardening rate as a function of temperature, and negative strain rate sensitivities. Mechanical properties of the X70 steels exhibited different functionality with respect to temperature compared to the X52 steels at temperatures greater than 250 ºC. Changes in the acicular ferrite microstructure during deformation such as precipitate coarsening, dynamic precipitation, tempering of martensite in martensite-austenite islands, or transformation of retained austenite could account for differences in tensile property functionality between the X52 and X70 steels. Long term aging under load (LTA) testing of the X70 steels resulted in increased yield strength compared to standard elevated temperature tensile tests at all temperatures as a

  13. Understanding Passive Layer Formation for Further Corrosion Management in Gas Production Pipes

    Science.gov (United States)

    Santoso, R. K.; Rahmawati, S. D.; Gadesa, A.; Wahyuningrum, D.

    2017-07-01

    Corrosion is a critical issue during the development of a gas field, especially wet gas or retrograde gas field. Corrosion affects the management system of a field and further impacts the amount of investment. Therefore, accurate prediction of corrosion rate is needed to plan an effective preventive action before going further to the development phase. One of the important parameters that should be noticed to create an accurate prediction is the formation of the passive layer. In CO2-H2S environment, there will be three possibilities of passive layer: FeS, FeCO3 or no passive layer. In this study, we create mathematical models to determine the formed passive layer in each segment of the gas production tubing and pipeline. The model is built using Faraday’s Law and Thermodynamic approach to account the passive layer formation at different temperature, pH, corrosion rate and partial pressure of CO2 and H2S. From the simulation, it was found that there were three boundary conditions: no scale-FeS boundary, no scale-FeCO3 boundary and FeS-FeCO3 boundary. The first two boundaries evolved over a time as the concentration of Fe2+ ions was increasing. However, FeS-FeCO3 boundary remained steady as it was not affected by the addition of Fe2+ ions. Using sample case study, few variations were noticed at production pipeline and tubing. It was caused by the gas composition, which contained high CO2 and very low H2S. Boundary conditions only changed slightly over two days period.

  14. Energy transfer mechanism and probability analysis of submarine pipe laterally impacted by dropped objects

    Science.gov (United States)

    Liang, Jing; Yu, Jian-xing; Yu, Yang; Lam, W.; Zhao, Yi-yu; Duan, Jing-hui

    2016-06-01

    Energy transfer ratio is the basic-factor affecting the level of pipe damage during the impact between dropped object and submarine pipe. For the purpose of studying energy transfer and damage mechanism of submarine pipe impacted by dropped objects, series of experiments are designed and carried out. The effective yield strength is deduced to make the quasi-static analysis more reliable, and the normal distribution of energy transfer ratio caused by lateral impact on pipes is presented by statistic analysis of experimental results based on the effective yield strength, which provides experimental and theoretical basis for the risk analysis of submarine pipe system impacted by dropped objects. Failure strains of pipe material are confirmed by comparing experimental results with finite element simulation. In addition, impact contact area and impact time are proved to be the major influence factors of energy transfer by sensitivity analysis of the finite element simulation.

  15. 接管腐蚀与贮罐风险防范%Risk Prevention of Storage Tank Caused by Pipe Corrosion

    Institute of Scientific and Technical Information of China (English)

    赵家福

    2016-01-01

    This paper introduced the regular inspection of the carbon dioxide storage tank. During the veriifcation of pressure gauge calibration, we found pipe corrosion and expansion of the pressure gauge on the top of the tank inadvertently. This article analyzed the status, the causes and dangers of the corrosion, and put forward the preventive measures. Our aim was to avoid nasty accidents on the tanks in our district, caused by small pipe.%本文介绍了在定期检验中发现二氧化碳贮罐罐顶压力表接管腐蚀膨胀,对该腐蚀的现状和产生的原因及危害性做了分析,提出了今后的防范措施,以避免小接管引发大事故。

  16. Nuclear Technology. Course 30: Mechanical Inspection. Module 30-4, Piping Inspection.

    Science.gov (United States)

    Kinne, Bruce

    This fourth in a series of eight modules for a course titled Mechanical Inspection describes the classifications of pipe and fittings, the types of connections used in the installation of piping systems, the typical marking schemes, the preinstallation and installation verifications, and the tests of the completed installation. The module follows…

  17. The Weakest Link: Spatial Variability in the Piping Failure Mechanism of Dikes

    NARCIS (Netherlands)

    Kanning, W.

    2012-01-01

    Piping is an important failure mechanism of flood defense structures. A dike fails due to piping when a head difference causes first the uplift of an inland blanket layer, and subsequently soil erosion due to a ground water flow. Spatial variability of subsoil parameters causes the probability of pi

  18. A Signal Processing Approach with a Smooth Empirical Mode Decomposition to Reveal Hidden Trace of Corrosion in Highly Contaminated Guided Wave Signals for Concrete-Covered Pipes

    Directory of Open Access Journals (Sweden)

    Javad Rostami

    2017-02-01

    Full Text Available Ultrasonic guided waves have been extensively applied for non-destructive testing of plate-like structures particularly pipes in past two decades. In this regard, if a structure has a simple geometry, obtained guided waves’ signals are easy to explain. However, any small degree of complexity in the geometry such as contacting with other materials may cause an extra amount of complication in the interpretation of guided wave signals. The problem deepens if defects have irregular shapes such as natural corrosion. Signal processing techniques that have been proposed for guided wave signals’ analysis are generally good for simple signals obtained in a highly controlled experimental environment. In fact, guided wave signals in a real situation such as the existence of natural corrosion in wall-covered pipes are much more complicated. Considering pipes in residential buildings that pass through concrete walls, in this paper we introduced Smooth Empirical Mode Decomposition (SEMD to efficiently separate overlapped guided waves. As empirical mode decomposition (EMD which is a good candidate for analyzing non-stationary signals, suffers from some shortcomings, wavelet transform was adopted in the sifting stage of EMD to improve its outcome in SEMD. However, selection of mother wavelet that suits best for our purpose plays an important role. Since in guided wave inspection, the incident waves are well known and are usually tone-burst signals, we tailored a complex tone-burst signal to be used as our mother wavelet. In the sifting stage of EMD, wavelet de-noising was applied to eliminate unwanted frequency components from each IMF. SEMD greatly enhances the performance of EMD in guided wave analysis for highly contaminated signals. In our experiment on concrete covered pipes with natural corrosion, this method not only separates the concrete wall indication clearly in time domain signal, a natural corrosion with complex geometry that was hidden and

  19. A Signal Processing Approach with a Smooth Empirical Mode Decomposition to Reveal Hidden Trace of Corrosion in Highly Contaminated Guided Wave Signals for Concrete-Covered Pipes.

    Science.gov (United States)

    Rostami, Javad; Chen, Jingming; Tse, Peter W

    2017-02-07

    Ultrasonic guided waves have been extensively applied for non-destructive testing of plate-like structures particularly pipes in past two decades. In this regard, if a structure has a simple geometry, obtained guided waves' signals are easy to explain. However, any small degree of complexity in the geometry such as contacting with other materials may cause an extra amount of complication in the interpretation of guided wave signals. The problem deepens if defects have irregular shapes such as natural corrosion. Signal processing techniques that have been proposed for guided wave signals' analysis are generally good for simple signals obtained in a highly controlled experimental environment. In fact, guided wave signals in a real situation such as the existence of natural corrosion in wall-covered pipes are much more complicated. Considering pipes in residential buildings that pass through concrete walls, in this paper we introduced Smooth Empirical Mode Decomposition (SEMD) to efficiently separate overlapped guided waves. As empirical mode decomposition (EMD) which is a good candidate for analyzing non-stationary signals, suffers from some shortcomings, wavelet transform was adopted in the sifting stage of EMD to improve its outcome in SEMD. However, selection of mother wavelet that suits best for our purpose plays an important role. Since in guided wave inspection, the incident waves are well known and are usually tone-burst signals, we tailored a complex tone-burst signal to be used as our mother wavelet. In the sifting stage of EMD, wavelet de-noising was applied to eliminate unwanted frequency components from each IMF. SEMD greatly enhances the performance of EMD in guided wave analysis for highly contaminated signals. In our experiment on concrete covered pipes with natural corrosion, this method not only separates the concrete wall indication clearly in time domain signal, a natural corrosion with complex geometry that was hidden and located inside the

  20. Demonstration and Validation of Controlled Low-Strength Materials for Corrosion Mitigation of Buried Steel Pipes: Final Report on Project F09-A17

    Science.gov (United States)

    2015-12-01

    812 Park Drive Warner Robins , GA 31088 James B. Bushman and Bopinder S. Phull Bushman and Associates P. O. Box 425 Medina, OH 44258 Final report...Under Project F09-AR17, “Dilute Flowable Backfill Validation for Corrosion Mitigation of Buried Piping at Fort Hood , TX” ERDC/CERL TR-15-33 ii...Appendix C: Fort Hood Demonstration Equipment and Materials for ROI Analysis

  1. Mechanism for in-pipe inspection; Dispositivo para inspecao de dutos

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, Gustavo Medeiros; Dutra, Max Suell [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil)

    2008-07-01

    The internal inspection of pipes is becoming a routine activity thanks to their importance on transportation of substances such as oil and natural gas. This paper addresses a mechanism capable of working inside pipes of different diameters that may present extreme curves and inclinations. The mechanism is composed of modules with devices that provide adjustable contact with the duct, using wheels on the contact points. The robot moves inside the pipe creating a virtual spindle. For that, two parts are used: the first one, guided along the pipe by a set of wheels, moves parallel to the axis of the pipe; the second part is attached to a motor. The motor rotation forces the mechanism to follow a helical motion, with tilted wheels rotating about the axis of the pipe. Each adjustable contact device works like a lever, pressing the wheel against the pipe. The base of the device can be actively rotated, modifying the angle of the wheel in relation to the pipe (equivalent to the step of the spindle), permitting the motion of the system in both directions, with specific velocity. According to the applied angle, the robot changes the relation between torque and displacement velocity. (author)

  2. ABSTRACTS WELDEL PIPE AND TUBE

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    article mainly analysis the weld character and the crack producing mechanism. Subject Terms: low alloy steel high strength brittleness crack weld seam HeHong,JiangXiuhan,LiLing (27) Technical Development of the Inner pipeline Corrosion Inspection Abroad This article introduces the technical development of the pipeline inner corrosion inspection abroad, and the advanced leak magnetic intelligent acrawl unit and the principle of ultrasonic intelligent acrawl machine to inspect the pipeline corrosion as well as the equipment of this intelligent acrawl machine. It points out that the gap of the pipeline corrosion inspection in China and the problems must be solved now. Subject Terms:long distance pipeline corrosion inspection ultrasonic leak magnetic intelligent acrawl machine Li Ye(32) The Development of the Large Sized Cold Bend Square Pipe Through reforming of the equipment and improving of the process of the cold bend steel unit, Han Kou Steel Rolling Plant of Wuhan Steel Group can produce large sized cold bend square pipe with the size of 300X300mm. This article introduces the establishment of the reforming project and the process of the reforming practice in details. Subject Terms:cold bend square pipe development standing roller width reform Yinguoyao,Huchengzhou,Zhangbinjie(35) The Application of Automation in Pipelines NorthWest Petroleum Bureau The automation system of Ku-Shan pipeline realizes the objective to transport oil safely. steadily and efficiently. The article introduces the components of the automation system in second-control center and station-control system. Through the examples of the control of pressure-reducing and non-heated oil transportation with the aid of additive, it also presents that automation plays an important role in the respects of managing production, reducing personnels and increasing profit. Subject Terms:long-distance transportation pipeline automatic control management Li Hongliang,Qian Wenxian,Qian Xiaolin,Qian Lezhong(37

  3. H2S Stress Corrosion Test Research of the Spiral Welded Pipe%螺旋焊管H2S应力腐蚀的试验研究

    Institute of Scientific and Technical Information of China (English)

    王树人

    2001-01-01

    Through the spiral welded pipe H2S stress corrosion testresearch, the article gives out H2S stress corrosion resistance methods of the spiral welded pipe, and proposes some suggestion on the development of China H2S stress corrosion.%通过对螺旋焊管H2S应力腐蚀试验研究,提出了螺旋焊管抗H2S应力腐蚀的几种途径,并对我国H2S应力腐蚀的发展提出了一些建议。

  4. RESEARCH ON DEGRADATION CORROSIVE ENVIRONMENT OF SOME STEELS USED IN MANUFACTURING MINING EQUIPMENT. MECHANICAL TESTS

    Directory of Open Access Journals (Sweden)

    Florin CIOFU

    2017-05-01

    Full Text Available Simultaneous action of mechanical stress variables and the corrosive environment leads to the deterioration of structures made of steel or of other metallic materials, a process called fatigue in corrosive environment or corrosion fatigue, which has causes and effects different from degradation under the singular action, either of mechanical strain or of corrosive environment. The aim of this paper is the study of the behavior,under fatigue conditions in corrosive environment of low alloy steels meant for the construction of mining equipment used in various mining operations in Gorj county. Based on experimental research regarding sustainability in fatigue corrosion, analyses of the interaction between the mechanical and the electrochemical factors as well as microscopic analyses of the structures we aim in this paper at deeply studying the performance of degradation processes that occur in the surface layers and lead to destruction by corrosion fatigue of the steels under study.

  5. The Mechanism and Influencing Factors of Corrosion in a Gas Heating-Furnace

    Institute of Scientific and Technical Information of China (English)

    YANG Zhi-gang; ZHANG Ning-sheng; WU Xin-min

    2005-01-01

    Natural gas should be heated and throttled for the purpose of purification and transportation at the first gas production factory of the Changqing field. The safe use and heat-transfer efficiency of a heating-furnace affect the safe and smooth production of natural gas directly. At gas collecting stations now, no measures of anticorrosion have been adopted in heating furnaces which erode and scale badly.In order to solve the corrosive problem of heating-furnaces, prolong operating life of heating-furnaces,assure safe and smooth production of natural gas, the mechanism and influencing factors of corrosion of the heating-furnace were analyzed and some corresponding measures were brought forward based on a field investigation of usage behavior and present operational status of heating-furnaces at the first gas production factory. The results show that the corrosive ion and soluble CO2 and O2 in water erode metal badly at the condition of being heated. Corrosion of a heating-furnace are mostly oxygen corrosion, corrosive ion corrosion, acid corrosion, iron encrustation corrosion, dry and wet interface corrosion, caustic corrosion, etc; The influencing factors of corrosion mainly include soluble O2 and CO2 in water, pH value, heat loading, corrosive ion, soluble solid (salinity) and non-flowing character of water, etc.

  6. Corrosion Mechanism of Corrosion-Resistant Steel Developed for Bottom Plate of Cargo Oil Tanks

    Institute of Scientific and Technical Information of China (English)

    Feilong SUN; Xiaogang LI; Fan ZHANG; Xuequn CHENG; Cheng ZHOU; Nianchun WU; Yuqun YIN

    2013-01-01

    A new type of corrosion-resistant steel consisting of ferrite and bainite phases was developed for cargo oil tanks of crude oil tankers.The corrosion rate of this new steel was 0.22 mm/a,which was equivalent to ca.1/5 of the criterion (≤ 1 mm/a) for corrosion-resistant steels.The composition and element distribution of the corrosion products were investigated by micro-Raman spectrometry and energy dispersive spectrometer.The results demonstrated that the corrosion product was composed of α-FeOOH,Fe3O4 and a continuous Cu enrichment layer.This kind of corrosion product was protective to the steel matrix and accounted for the enhancement of the corrosion resistance of the new developed steel.

  7. Identified corrosion and erosion mechanisms in SCO2 Brayton Cycles.

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, Darryn D.; Kruizenga, Alan Michael

    2014-06-01

    Supercritical Carbon Dioxide (S-CO2) is an efficient and flexible working fluid for power production. Research to interface S-CO2 systems with nuclear, thermal solar, and fossil energy sources is currently underway. To proceed, we must address concerns regarding compatibility of materials, at high temperature, and compatibility between significantly different heat transfer fluids. Dry, pure S-CO2 is thought to be relatively inert [1], while the addition of ppm levels of water and oxygen result in formation of a protective chromia layer and iron oxide [2]. Thin oxides are favorable as diffusion barriers, and for their minimal impact on heat transfer. While S-CO2 is typically understood to be the secondary fluid, many varieties of primary fluids exist for nuclear applications. Molten salts, for use in the Molten Salt Reactor concept, are given as an example to contrast the materials requirements of primary and secondary fluids. Thin chromia layers are soluble in molten salt systems (nitrate, chloride, and fluoride based salts) [3-8], making materials selection for heat exchangers a precarious balancing act between high temperature oxidation (S-CO2) and metal dissolution (salt side of heat exchanger). Because concerns have been raised regarding component lifetimes, S-CO2 work has begun to characterize starting materials and to establish a baseline by analysis of 1) as-received stainless steel piping, and 2) piping exposed to S-CO2 under typical operating conditions with Sandia National Laboratories Brayton systems. A second issue discovered by SNL involves substantial erosion in the turbine blade and inlet nozzle. It is believed that this is caused by small particulates that originate from different materials around the loop that are entrained by the S-CO2 to the nozzle, where they impact the inlet nozzle vanes, causing erosion. We believe that, in some way, this is linked to the purity of the S-CO2, the corrosion contaminants, and the metal particulates that

  8. Research on Ultrasonic Phased Array Inspection of Corrosion Drill Pipe%腐蚀钻杆的超声相控阵检测研究

    Institute of Scientific and Technical Information of China (English)

    魏同锋

    2016-01-01

    钻杆是钻井平台的重要组成部分。为了对有缺陷的钻杆进行合理利用,提高其生产安全并降低成本,有必要对钻杆的人工缺陷和自然缺陷进行超声相控阵检测并分析比较。试验结果表明,使用SUPOR-32P超声成像检测仪和配有弧形楔块的128阵元相控阵探头,进行A+B+[C]成像,并结合实际自然缺陷样管检测,能够满足钻杆的腐蚀检测需求。%Drill pipe is an important part of the drilling platform. In order to rationally utilize the defective drill pipe, improve its production safety and reduce its cost, the researcher makes ultrasonic phased array inspection, analysis and comparison of drill pipe's artificial defects and natural defects. The experiment results show, it can meet the drill pipe's corrosion inspection requirements to use SUPOR-32P ultrasonic imaging detector, 128 element phased array probe equipped with arc wedge, and A+B+ [C] imaging mode, combining with the actual inspection effects of the sample pipe's natural defect.

  9. Effects of Induction Heat Bending Process on Microstructure and Corrosion Properties of ASME SA312 Gr.TP304 Stainless Steel Pipes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Nam In; Kim, Young Sik [Andong National University, Andong (Korea, Republic of); Kim, Kyung Soo; Chang, Hyun Young; Park, Heung Bae; Sung, Gi Ho [KEPCO Engineering and Construction Company, Seongnam (Korea, Republic of); Sung, Gi Ho [R and D Center, Busan (Korea, Republic of)

    2015-06-15

    The usage of bending products recently have increased since many industries such as automobile, aerospace, shipbuilding, and chemical plants need the application of pipings. Bending process is one of the inevitable steps to fabricate the facilities. Induction heat bending is composed of compressive bending process by local heating and cooling. This work focused on the effect of induction heat bending process on the properties of ASME SA312 Gr. TP304 stainless steel pipes. Tests were performed for base metal and bended area including extrados, intrados, crown up, and down parts. Microstructure was analyzed using an optical microscope and SEM. In order to determine intergranular corrosion resistance, Double Loop Electrochemical Potentiokinetic Reactivation (DL-EPR) test and ASTM A262 practice A and C tests were done. Every specimen revealed non-metallic inclusion free under the criteria of 1.5i of the standard and the induction heat bending process did not affect the non-metallic inclusion in the alloys. Also, all the bended specimens had finer grain size than ASTM grain size number 5 corresponding to the grain sizes of the base metal and thus the grain size of the pipe bended by induction heat bending process is acceptable. Hardness of transition start, bend, and transition end areas of ASME SA312 TP304 stainless steel was a little higher than that of base metal. Intergranular corrosion behavior was determined by ASTM A262 practice A and C and DL-EPR test, and respectively step structure, corrosion rate under 0.3 mm/y, and Degree of Sensitization (DOS) of 0.001 - 0.075 % were obtained. That is, the induction heat bending process didn't affect the intergranular corrosion behavior of ASME SA312 TP304 stainless steel.

  10. Synergic Mechanism of an Organic Corrosion Inhibitor for Preventing Carbon Steel Corrosion in Chloride Solution

    Institute of Scientific and Technical Information of China (English)

    LIU Zhiyong; YU Lei; LI Qingzhong

    2015-01-01

    The inhibition effect of dimethylethanolamine (DMEA) and its composite with carboxylic acid was studied with the electrochemical tests. The experimental results indicate that DMEA is not a good inhibitor but the composite of DMEA with caprylic acid exhibits excellent inhibiting efficiency. The synergic mechanism of the organic corrosion inhibitors (OCIs) was studied with quantum chemical calculations. It is found that the DMEA forms a quaternary ammonium salt with the proton in carboxylic acid, and a cyclic complex formed between the salt and Fe may be responsible for the enhancement of inhibiting efficiency. The possible hydrogen bond formed between DMEA and carboxylic acid is not enough for the inhibiting effect. This work is helpful to proposing theoretical interpretation as well as developing a functional organic inhibitor to improve the durability of reinforced concrete contaminated with chloride.

  11. Microstructure and Mechanical Properties of J55ERW Steel Pipe Processed by On-Line Spray Water Cooling

    Directory of Open Access Journals (Sweden)

    Zejun Chen

    2017-04-01

    Full Text Available An on-line spray water cooling (OSWC process for manufacturing electric resistance welded (ERW steel pipes is presented to enhance their mechanical properties and performances. This technique reduces the processing needed for the ERW pipe and overcomes the weakness of the conventional manufacturing technique. Industrial tests for J55 ERW steel pipe were carried out to validate the effectiveness of the OSWC process. The microstructure and mechanical properties of the J55 ERW steel pipe processed by the OSWC technology were investigated. The optimized OSWC technical parameters are presented based on the mechanical properties and impact the performance of steel pipes. The industrial tests show that the OSWC process can be used to efficiently control the microstructure, enhance mechanical properties, and improve production flexibility of steel pipes. The comprehensive mechanical properties of steel pipes processed by the OSWC are superior to those of other published J55 grade steels.

  12. Effects of microbial redox cycling of iron on cast iron pipe corrosion in drinking water distribution systems.

    Science.gov (United States)

    Wang, Haibo; Hu, Chun; Zhang, Lili; Li, Xiaoxiao; Zhang, Yu; Yang, Min

    2014-11-15

    Bacterial characteristics in corrosion products and their effect on the formation of dense corrosion scales on cast iron coupons were studied in drinking water, with sterile water acting as a reference. The corrosion process and corrosion scales were characterized by electrochemical and physico-chemical measurements. The results indicated that the corrosion was more rapidly inhibited and iron release was lower due to formation of more dense protective corrosion scales in drinking water than in sterile water. The microbial community and denitrifying functional genes were analyzed by pyrosequencing and quantitative polymerase chain reactions (qPCR), respectively. Principal component analysis (PCA) showed that the bacteria in corrosion products played an important role in the corrosion process in drinking water. Nitrate-reducing bacteria (NRB) Acidovorax and Hydrogenophaga enhanced iron corrosion before 6 days. After 20 days, the dominant bacteria became NRB Dechloromonas (40.08%) with the protective corrosion layer formation. The Dechloromonas exhibited the stronger corrosion inhibition by inducing the redox cycling of iron, to enhance the precipitation of iron oxides and formation of Fe3O4. Subsequently, other minor bacteria appeared in the corrosion scales, including iron-respiring bacteria and Rhizobium which captured iron by the produced siderophores, having a weaker corrosion-inhibition effect. Therefore, the microbially-driven redox cycling of iron with associated microbial capture of iron caused more compact corrosion scales formation and lower iron release.

  13. Phase change driving mechanism and modeling for heat pipe with porous wick

    Institute of Scientific and Technical Information of China (English)

    LIU Wei; LIU ZhiChun; YANG Kun; TU ZhengKai

    2009-01-01

    According to heat pipe theory,capillary force is the only driving force for the circle of working fluid in heat pipe with porous wick.By developing a simulating circuit of liquid and vapor flow in heat pipe with porous wick,this paper presents a new driving mechanism which is from phase change of fluid.Furthermore,by analyzing transport process of working fluid between evaporation and condensation in terfaces,a mathematical model is developed to describe this driving mechanism.Besides,calculating examples are given for heat pipe with water as working fluid to predict its driving force and flow resis tance.By applying the model presented in the paper,thermal design and calculation for heat pipe with porous wick,especially for miniature heat pipe,can be made correctly,and phase change driving me chanism of working fluid can be explained,which thereby leads to a better understanding of heat transfer limitation of heat pipe with porous wick.

  14. Galvanic Corrosion of Seawater Cooling Pipe Lined Copolymers%海水冷却管内衬共聚物后的电偶腐蚀

    Institute of Scientific and Technical Information of China (English)

    杨青松; 张波; 董彩常; 韩东锐

    2013-01-01

    采用海水浸泡、电偶腐蚀、模拟腐蚀和扫描电镜分析等方法,研究了脱氧铜(TUP)紫铜冷却水管内壁内衬共聚物后的电偶腐蚀性能.结果表明,内衬乙烯丙烯酸共聚物(EAA)或涂敷环氧玻璃鳞片后,TUP紫铜管与高电位金属连接引起的电偶腐蚀能够得到有效抑制,内衬EAA的性能优于涂敷环氧玻璃鳞片.%Galvanic corrosion of copper cooling pipes lined with copolymer were tested by seawater immersed test,galvanic corrosion test,simulated pipe test and scanning electron microscopy.The results showed that the galvanic corrosion between red copper and high potential metal was efficiently controlled by lining ethylene acrylic ocid (EAA)copolymer or overlaying epoxy glass flakes,the effect of lining ethylene acrylic acid (EAA) copolymer was more excellent than that of overlaying epoxy glass-flakes.

  15. Corroded scale analysis from water distribution pipes

    Directory of Open Access Journals (Sweden)

    Rajaković-Ognjanović Vladana N.

    2011-01-01

    both fluid and solid, relatively dense shell-like layer that covers the porous core and provides structural integrity to the scale, and surface layer that is present on top of the shell-like layer at scale-water interface and loosely attached to the shell-like layer. Iron(II deposits are formed under reducing conditions. The presence of relatively soluble Fe(II deposits such as siderite and ferrous hydroxide was confirmed by XRD and SEM analysis. In the presence of carbonic species, siderite (FeCO3 is prevailing ferrous deposit. Further studies are needed for obtaining greater knowledge on the mechanism of iron release from corroded pipes and the influence of water quality to iron corrosion.

  16. Probabilistic fracture mechanics analysis of thermally aged nuclear piping in a pressurized water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shuxiao; Zhang, Hailong; Li, Shilei; Wang, Yanli [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Xue, Fei [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Wang, Xitao, E-mail: xtwang@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China)

    2013-12-15

    Highlights: • Thermal aging embrittlement was considered in the PFM analysis of nuclear pipe. • Predicting program for pipe failure probability was developed based on thermal aging. • Cumulative failure probability is significantly affected by fracture toughness. • Cumulative failure probability is slightly affected by fatigue crack growth rate. • Tensile strength increase due to thermal aging slightly reduces pipe failure risk. - Abstract: A predicting program for pipe break probability based on thermal aging embrittlement was developed. In order for life prediction, evolutions of fracture toughness and tensile strength were estimated for a Z3CN20-09M piping steel using the Argonne National Laboratory (ANL) procedure. To understand the influence of thermal aging on failure probability, different evolutions of fracture toughness, tensile strength and fatigue crack growth rate were employed in the prediction of cumulative failure probability. The results show that the cumulative failure probability for 40-year thermal aging increases by almost four times compared to without consideration of fracture toughness degradation. The cumulative failure probability is slightly affected by fatigue crack growth rate. The increase of tensile strength due to thermal aging reduces the risk of pipe failure. This work demonstrates that the degradation of fracture toughness due to thermal aging should be fully considered in the probabilistic fracture mechanics analysis of nuclear pressure pipes.

  17. Mechanical and Corrosion Properties of Magnesium-Bioceramic Nanocomposites

    Directory of Open Access Journals (Sweden)

    Kowalski K.

    2016-09-01

    Full Text Available Magnesium alloys have recently attracted much attention as a new generation of biodegradable metallic materials. In this work, Mg1Mn1Zn0.3Zr-bioceramic nanocomposites and their scaffolds were synthesized using a combination of mechanical alloying and a space-holder sintering process. The phase and microstructure analysis was carried out using X-ray diffraction, scanning electron microscopy and the properties were measured using hardness and corrosion testing equipment. Nanostructured Mg-bioceramic composites with a grain sizes below 73 nm were synthesized. The Vickers hardnesses for the bulk nanostructured Mg-based composites are two times greater than that of pure microcrystalline Mg metal (50 HV0.3. Produced Mg-based bionanomaterials can be applied in medicine.

  18. Synthesis and application of hybrid polymer composites based on silver nanoparticles as corrosion protection for line pipe steel.

    Science.gov (United States)

    Atta, Ayman M; El-Mahdy, Gamal A; Al-Lohedan, Hamad A; Ezzat, Abdurrahman O

    2014-05-16

    A facile method was developed to synthesize in high yield dispersed silver nanoparticles (AgNPs) with small particle sizes of less than 10 nm. Silver nitrate was reduced to silver nanoparticles by p-chloroaniline in the presence of polyoxyethylene maleate 4-nonyl-2-propylene-phenol (NMA) as a stabilizer. The produced AgNPs were used to prepare hybrid polymer based on N-isopropylacrylamide (NIPAm), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), N,N-methylenebisacrylamide (MBA) and potassium persulfate (KPS) using a semi-batch solution polymerization method. The prepared AgNPs and hybrid polymer were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) patterns and transmission electron microscopy (TEM). The corrosion inhibition activity of the AgNPs and hybrid polymer towards steel corrosion in the presence of hydrochloric acid has been investigated by polarization and electrochemical impedance spectroscopy (EIS) methods. Polarization measurements indicate that the AgNPs and hybrid polymer acts as a mixed type-inhibitor and the inhibition efficiency increases with inhibitor concentration. The results of potentiodynamic polarization and EIS measurements clearly showed that the inhibition mechanism involves blocking of the steel surface by inhibitor molecules via adsorption.

  19. Effects of Variations in Salt-Spray Conditions on the Corrosion Mechanisms of an AE44 Magnesium Alloy

    Directory of Open Access Journals (Sweden)

    Holly J. Martin

    2010-01-01

    Full Text Available The understanding of how corrosion affects magnesium alloys is of utmost importance as the automotive and aerospace industries have become interested in the use of these lightweight alloys. However, the standardized salt-spray test does not produce adequate corrosion results when compared with field data, due to the lack of multiple exposure environments. This research explored four test combinations through three sets of cycles to determine how the corrosion mechanisms of pitting, intergranular corrosion, and general corrosion were affected by the environment. Of the four test combinations, Humidity-Drying was the least corrosive, while the most corrosive test condition was Salt Spray-Humidity-Drying. The differences in corrosivity of the test conditions are due to the various reactions needed to cause corrosion, including the presence of chloride ions to cause pit nucleation, the presence of humidity to cause galvanic corrosion, and the drying phase which trapped chloride ions beneath the corrosion by-products.

  20. INTERNAL CORROSION MONITORING IN OFFSHORE PLATFORMS

    Directory of Open Access Journals (Sweden)

    Fernando Benedicto Mainier

    2008-08-01

    Full Text Available Corrosion is one of the main causes of failures in equipment and pipes in off-shore oil production. These failures harm the process, slow the production operational chronogram, and generate high costs of maintenance, beyond generation risks to health and environment. Due to the fact that most of the equipment, tubing and pipes of production platforms are made of steel, in general, carbon steel, the industry of petroleum exploration will always coexist with the corrosive process. The use of a Corrosion Monitoring Plan to diagnostic, to control and to manage the evolution of corrosives process in off-shore oil platforms is the strategy proposed in this work to prevent problems as described above. The Internal Corrosion Monitoring Plan (ICMP, is based on lab analysis of the corrosively of fluids and residues showed periodically in off-shore operational platform; in the corrosion rate determined by the periodic use of test bodies installed inside off-shore oil platforms tubing systems, as mass loss coupons and electric resistance probes; and finally, in periodic operational data collect obtained during the off-shore oil platform systems operation. The ICMP will direct and manage the actions to be taken in case of aggravation of a corrosive process, quickly identifying to the corrosive mechanisms and its localization in the various systems of the platforms. The optimized use of the corrosion inhibitor and other chemical products are one of the main advantages of the ICMP.

  1. Localized corrosion mechanism associated with precipitates containing Mg in Al alloys

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    To clarify the localized corrosion mechanism associated with precipitates containing Mg in Al alloys, the simulated bulk precipitates of S and β were synthesized through melting and casting. Their electrochemical behaviors and coupling behaviors with α(Al) in NaCl solution were measured. Meanwhile, simulated Al alloys containing S and β particles were prepared and their corrosion morphologies were observed. It's found that there exist two kinds of corrosion mechanisms associated with precipitates containing Mg. The precipitate of β is anodic to the alloy base, resulting in its anodic dissolution and corrosion during the whole corrosion process. While, there exists a corrosion conversion mechanism associated with the S precipitate, which contains active element Mg and noble element Cu simultaneously. At an initial stage, S is anodic to the alloy matrix at its periphery and the corrosion occurs on its surface. However, during its corrosion process, Mg is preferentially dissolved and noble Cu is enriched in the remnants.This makes S become cathodic to α(Al) and leads to anodic dissolution and corrosion on the alloy base at its periphery at a later stage.

  2. A Hydrogen Ignition Mechanism for Explosions in Nuclear Facility Piping Systems

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, Robert A.

    2013-09-18

    Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein. Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions may occur. Pipe ruptures in nuclear reactor cooling systems were attributed to hydrogen explosions inside pipelines, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents, an ignition source for hydrogen was not clearly demonstrated, but these accidents demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. A new theory to identify an ignition source and explosion cause is presented here, and further research is recommended to fully understand this explosion mechanism.

  3. Surface destructive mechanism on high-temperature ablation, supersonic-erosion, dreg-adherence and corrosion

    Institute of Scientific and Technical Information of China (English)

    XIAO Jun; CHEN Jian-min; ZHOU Hui-di; LI Tie-hu; ZHANG Qiu-yu

    2004-01-01

    The exhaust and flame from a supersonic airborne missile high-energy smoke-born engine (SAMHSE) may lead to high-temperature ablation, supersonic-erosion, dreg-adherence (HTASED) and corrosion on the launcher slide track, causing serious problems to the operation and decreasing the lifetime of the launcher. Therefore, it is imperative to study the destructive mechanism so as to guarantee the smooth operation and increase the lifetime of military equipments. Accordingly, HTASED and corrosion were systematically observed and analyzed with the emphasis placed on the mechanism investigations making use of a series evaluation tests, typical missile engine simulation tests, national military standard methods, scanning electron microscopy and electrochemical corrosion tests. It is found that the thermal impact of high-temperature flame and supersonic erosion of corrosive melting particle jet of the SAMHSE lead to surface defects of micro-cracks, denudation and corrosive residue. Some defects reach to metal base becoming to "corrosive channels". Repetitive HTASED may cause ablation-adhesion fatigue stress, which enhances the surface corrosion and destruction. HTASED and corrosion are related to the type of a SAMHSE fuel and experience of the launcher. Surface destruction is related to synergistic effects of the HTASED. The ablated and failed Al or steel surface is liable to electrochemical corrosion characterized by pitting in humid and salt-spray environment.

  4. Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

    Institute of Scientific and Technical Information of China (English)

    Lefu ZHANG; Fawen ZHU; Rui TANG

    2009-01-01

    Nickel-based alloys, austenitic stainless steel, ferritic/martensitic heat-resistant steels, and oxide dispersion strengthened steel are presently considered to be the candidate structural or fuel-cladding materials for supercritical water-cooled reactor (SCWR), one of the promising generation IV reactor for large-scale electric power production. However, corrosion and stress corrosion cracking of these candidate alloys still remain to be a major problem in the selection of nuclear fuel cladding and other structural materials, such as water rod. Survey of literature and experimental results reveal that the general corrosion mechanism of those candidate materials exhibits quite complicated mechanism in high-temperature and high-pressure supercritical water. Formation of a stable protective oxide film is the key to the best corrosion-resistant alloys. This paper focuses on the mechanism of corrosion oxide film breakdown for SCWR candidate materials.

  5. Mechanism of Pitting Corrosion Protection of Metals and Alloys

    OpenAIRE

    Vladimir Alexandrovich Grachev; Andrei Evgenievich Rozen; Gennadii Vasilievich Kozlov; Andrei Andreievich Rozen

    2016-01-01

    In this article authors set out a principle of pitting corrosion protection, suggested a new class of multilayer materials with high corrosion resistance. They substantiated the choice of the layers for the multilayer material designed for exploitation in oxidizing and non-oxidizing environment. The sphere of application of the multilayer materials was defined.

  6. A Fracture Probability Competition Mechanism of Stress Corrosion Cracking

    Institute of Scientific and Technical Information of China (English)

    Yanliang HUANG

    2001-01-01

    The stress corrosion cracking (SCC) of austenitic stainless steel was studied via polarization,slow strain rate and scanning electron microscope (SEM) techniques. Many SCC mechanisms have been proposed in which hydrogen embrittlement and passive film rupture-repassivation theories are generally accepted, but they can hardly explain the SCC mechanism of austenitic stainless steel in acidic chloride solution adequately, because the steel is in active dissolution state and cathodic polarization can prevent it from occurring. Our experiment shows that the anodic current increases the creep rate and decreases the plastic strength of the material on single smooth specimen as well as at the SCC crack tip. The fractured surface was characterized as brittle cleavage, while the surface crack of smooth specimen was almost vertical to the tensile strength, which can confirm that the cracks were caused by tensile stresses. A fracture probability competition mechanism of SCC was proposed on the basis of the experimental results combined with the viewpoint of ductile-brittle fracture competition. When the anodic dissolution current is increased to a certain degree, the probability of fracture by tensile stress will exceed that by shear stress, and the brittle fracture will occur. The proposed SCC mechanism can not only explain the propagation of SCC cracks but can explain the crack initiation as well. The strain on the surface distributes unevenly when a smooth specimen is deformed, so does the anodic current distribution. The crack will initiate at a point where the anodic current density is large enough to cause the material at a specific point to fracture in brittle manner.

  7. Development of non-destructive diagnosis technology for pipe internal in thermal power plants based on robotics

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seungho; Kim, Changhoi; Seo, Yongchil; Lee, Sunguk; Jung, Seungho; Jung, Seyoung

    2011-11-15

    The Pipelines of power plants may have tiny crack by corrosion. Pipe safety inspection should be performed periodically and non-periodically to ensure their safety and integrity. It is difficult to inspection pipes inside defect since pipes of power plant is covered thermal insulation material. Normally pipes inspection was performed part of pipes on outside. A mobile robot was developed for the inspection of pipe of 100 mm inside diameter. The robot is adopted screw type drive mechanism in order to move vertical, horizontal pipes inside. The multi-laser and camera module, which is mounted in front of the robot, captures a sequence of 360 degree shapes of the inner surface of a pipe. The 3D inner shape of pipe is reconstructed from a multi laser triangulation techniques for the inspection of pipes.

  8. Three dimensional damage mechanics analysis of real life reactor piping components under various loading conditions

    Energy Technology Data Exchange (ETDEWEB)

    Durgaprasad, P.V.; Sahu, M.K.; Dutta, B.K. (Reactor Safety Division, Bhabha Atomic Research Centre Trombay, Mumbai (India)), e-mail: pvdp@barc.gov.in

    2009-07-01

    In this work, the Gurson-Tvergaard-Needleman (GTN) damage mechanics model is used for the crack growth analysis of real life reactor piping components. The paper also addresses the challenges involved in such analyses. As a part of component integrity testing, a comprehensive experimental program has been pursued to generate the fracture behavior of reactor piping components. Several real life pipes and elbows with various flaw sizes have been tested under different loading conditions like temperature, pressure, bending etc. In the present work, some of the selected components have been analyzed numerically by using parallel in-house finite element code 'MADAM' with GTN constitutive model. The strength of the micro mechanical models has been demonstrated by comparing the numerical results like load v/s. load-line displacements, J-R curves with the experimental data

  9. Fretting corrosion of CoCr alloy: Effect of load and displacement on the degradation mechanisms.

    Science.gov (United States)

    Bryant, Michael; Neville, Anne

    2017-02-01

    Fretting corrosion of medical devices is of growing concern, yet, the interactions between tribological and electrochemical parameters are not fully understood. Fretting corrosion of CoCr alloy was simulated, and the components of damage were monitored as a function of displacement and contact pressure. Free corrosion potential (Ecorr), intermittent linear polarisation resistance and cathodic potentiostatic methods were used to characterise the system. Interferometry was used to estimate material loss post rubbing. The fretting regime influenced the total material lost and the dominant degradation mechanism. At high contact pressures and low displacements, pure corrosion was dominant with wear and its synergies becoming more important as the contact pressure and displacement decreased and increased, respectively. In some cases, an antagonistic effect from the corrosion-enhanced wear contributor was observed suggesting that film formation and removal may be present. The relationship between slip mechanism and the contributors to tribocorrosion degradation is presented.

  10. Improvement in Mechanical Properties of SA508 Gr.1a Piping Material by Modifying Microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Weon; Choi, Myung Rak [Chosun Univ., Gwangju (Korea, Republic of); Oh, Young Jin; Park, Heung Bae; Kim, Kyung Su [KEPCO E-C, Yongin (Korea, Republic of)

    2014-10-15

    -received SA508 Gr.1a at RT. But, at 316 .deg. C J-R curve of modified SA508 Gr.1a is much higher than that of as-received SA508 Gr.1a piping material. This indicates that the mechanical properties of SA508 Gr.1a piping material at operating temperature of NPP are much improved by modifying microstructure that is simple achieved by heat-treatment.

  11. Steel fiber reinforced concrete pipes: part 1: technological analysis of the mechanical behavior

    Directory of Open Access Journals (Sweden)

    A. D. de Figueiredo

    Full Text Available This paper is the first part of an extensive work focusing the technological development of steel fiber reinforced concrete pipes (FRCP. Here is presented and discussed the experimental campaign focusing the test procedure and the mechanical behavior obtained for each of the dosages of fiber used. In the second part ("Steel fiber reinforced concrete pipes. Part 2: Numerical model to simulate the crushing test", the aspects of FRCP numerical modeling are presented and analyzed using the same experimental results in order to be validated. This study was carried out trying to reduce some uncertainties related to FRCP performance and provide a better condition to the use of these components. In this respect, an experimental study was carried out using sewage concrete pipes in full scale as specimens. The diameter of the specimens was 600 mm, and they had a length of 2500 mm. The pipes were reinforced with traditional bars and different contents of steel fibers in order to compare their performance through the crushing test. Two test procedures were used in that sense. In the 1st Series, the diameter displacement was monitored by the use of two LVDTs positioned at both extremities of the pipes. In the 2nd Series, just one LVDT is positioned at the spigot. The results shown a more rigidity response of the pipe during tests when the displacements were measured at the enlarged section of the socket. The fiber reinforcement was very effective, especially when low level of displacement was imposed to the FRCP. At this condition, the steel fibers showed an equivalent performance to superior class pipes made with traditional reinforced. The fiber content of 40 kg/m3 provided a hardening behavior for the FRCP, and could be considered as equivalent to the critical volume in this condition.

  12. Grooving corrosion of seam welded oil pipelines

    Directory of Open Access Journals (Sweden)

    Mohamed Hanafy El-Sayed

    2014-10-01

    Full Text Available 24” pipeline carrying oil was failed in the form of longitudinal crack at the 6 O’clock position resulting in oil spill. The failed pipe was investigated to reveal the main cause of its failure. The procedure of investigation was built on studying the intact pipe, rupture area, parent material, and intact weld. Results of chemical analysis, mechanical properties, and microstructure of the pipe material were confirmed with the specified standard. Cracks were originated from weld defected sites, initiated by grooving corrosion, propagated by inertia at the normal designed pressure condition, and stopped when stress relief is attained. It is recommended to use high quality ERW pipe, with its seam weld line positioned around the 12 O’clock during installation, to minimize and decelerate grooving corrosion. It is also important to perform regular or routine inspection, on suitable intervals, determined by past experience.

  13. Technical Letter Report - Analysis of Ultrasonic Data on Piping Cracks at Ignalina Nuclear Power Plant Before and After Applying a Mechanical Stress Improvement Process, JCN-N6319, Task 2

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Michael T.; Cumblidge, Stephen E.; Crawford, Susan L.

    2008-02-26

    Pacific Northwest National Laboratory (PNNL) is assisting the United States Nuclear Regulatory Commission (NRC) in developing a position on the management of primary water stress corrosion cracking (PWSCC) in piping systems previously analyzed for leak-before-break (LBB). Part of this work involves determining whether inspections alone are sufficient or if inspections plus mitigation techniques are needed. The work described in this report addresses the reliability of ultrasonic phased-array (PA) examinations for inspection of cracks that have been subjected to the mitigation method of mechanical stress improvement process (MSIP). It is believed that stresses imparted during MSIP may make ultrasonic crack responses in piping welds more difficult to detect and accurately characterize. To explore this issue, data were acquired, both before and after applying MSIP, and analyzed from cracked areas in piping at the Ignalina Nuclear Power Plant (INPP) in Lithuania. This work was performed under NRC Project JCN-N6319, PWSCC in Leak-Before-Break Systems.

  14. Effect on mechanical properties of glass reinforced epoxy (GRE) pipe filled with different geopolymer filler molarity for piping application

    Science.gov (United States)

    Hashim, M. F. Abu; Abdullah, M. M. A.; Ghazali, C. M. R.; Hussin, K.; Binhussain, M.

    2017-04-01

    This study investigated the use of a novel white clay geopolymer as a filler to produce high strength glass reinforced epoxy pipe. It was found that using white clay geopolymer as filler gives better compressive strength to the glass reinforced epoxy pipe. The disadvantages of current glass reinforced epoxy pipes such low compressive strength which can be replaced by the composite pipes. Geopolymerization is an innovative technology that can transform several aluminosilicate materials into useful products called geopolymers or inorganic polymers. A series of glass reinforced epoxy pipe and glass reinforced epoxy pipe filled with 10 - 40 weight percentages white clay geopolymer filler with 4 Molarity and 8 Molarity were prepared. Morphology of white clay geopolymer filler surface was indicates using scanning electron microscopy. The additions of white clay geopolymer filler for both 4 Molarity and 8 Molarity show higher compressive strength than glass reinforced epoxy pipe without any geopolymer filler. The compressive test of these epoxy geopolymer pipe samples was determined using Instron Universal Testing under compression mode. Nonetheless, the compressive strength of glass reinforced epoxy pipe with white clay geopolymer filler continues to drop when added to 40 wt% of the geopolymer filler loading for both 4 Molarity and 8 Molarity. These outcomes showed that the mixing of geopolymer materials in epoxy system can be attained in this research.

  15. Combined loading effects on the fracture mechanics behavior of line pipes

    Energy Technology Data Exchange (ETDEWEB)

    Bravo, R.E.; Cravero, S.; Ernst, H.A. [Tenaris Group, Campana (Argentina). SIDERCA R and D Center

    2009-12-19

    For certain applications, pipelines may be submitted to biaxial loading situations. In these cases, it is not clear the influence of the biaxial loading on the fracture mechanics behavior of cracked pipelines. For further understanding of biaxial loading effects, this work presents a numerical simulation of ductile tearing in a circumferentially surface cracked pipe under biaxial loading using the computational cell methodology. The model was adjusted with experimental results obtained in laboratory using single edge cracked under tension (SENT) specimens. These specimens appear as the better alternative to conventional fracture specimens to characterize fracture toughness of cracked pipes. The negligible effect of biaxial loadings on resistance curves was demonstrated. To guarantee the similarities of stress and strains fields between SENT specimens and cracked pipes subjected to biaxial loading, a constraint study using the J-Q methodology and the h parameter was used. The constraint study gives information about the characteristics of the crack-tip conditions. (author)

  16. Analytical approach and field monitoring for mechanical behaviors of pipe roof reinforcement

    Institute of Scientific and Technical Information of China (English)

    WANG Hai-tao; JIA Jin-qing; KANG Hai-gui

    2009-01-01

    Considering the delay effect of initial lining and revising the Winkler elastic foundation model, an analytical approach based on Pasternak elastic foundation beam theory for pipe roof reinforcement was put forward. With the example of a certain tunnel excavation, the comparison of the values of longitudinal strain of reinforcing pipe between field monitoring and analytical approach was made. The results indicate that Pasternak model, which considers a more realistic hypothesis in the elastic soil than Winkler model, gives more accurate calculation and agrees better with the result of field monitoring. The difference of calculation results between these two models is about 7%, and Pasternak model is proved to be a better way to study the reinforcement mechanism and improve design practice. The calculation results also reveal that the reinforcing pipes act as levers, which increases longitudinal load transfer to an unexcavated area, and consequently decreases deformation and increases face stability.

  17. Study on Microstructure and Slag Corrosion Mechanism of High Chrome Bricks for Gasifier

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Research was focused on slag corrosion mechanism of high chrome bricks used for different types of gasifier by comparing the structure of high chrome bricks for petroleum coke gasifier and water-coal slurry gasifier with slag corroded testing brick and water coal slurry gasifier through Scanning Electron Microscope (SEM) examination and X-ray diffraction. Results show that for high chrome brick used for petroleum coke gasifier, corrosion is mainly caused by Cr2O3 in the brick and V2O5 in molten slag and liquid phase generation at low temperature; for high chrome brick used for water-coal slurry gasifier, corrosion is caused by dissolution of Cr2O3 in molten slag and corrosion of ZrO2. For LIRR-HK95 brick, it performs better petroleum coke corrosion resistance than the others due to the optimal composition and structure.

  18. Microstructure and Mechanical Properties of the Butt Joint in High Density Polyethylene Pipe

    Directory of Open Access Journals (Sweden)

    Pashupati Pokharel

    2016-01-01

    Full Text Available The microstructure and mechanical properties of the butt joint in high density polyethylene (HDPE pipes were evaluated by preparing the joints with increasing the cooling time from 10 s to 70 s before pressure created for fusion of the pipes. Here, cold fusion flaws in HDPE butt joint were created with increasing the cooling time around 70 s caused by the close molecular contact followed by insufficient interdiffusion of chain segments back and forth across the wetted interface. The tensile failure mechanism of the welded pipes at different fusion time was projected based on the tensile test of dog-bone shaped, fully notched bar type as well as round U-notched specimens. The mechanical properties of the joints at different fusion time were correlated with the corresponding fracture surface morphology. The weld seam as well as tensile fracture surfaces were etched using strong oxidizing agents. The crystallinity of surface etched weld zone by potassium permanganate based etchant was found higher than unetched sample due to the higher susceptibility of amorphous phase of polyethylene with oxidizing agent. The U-notched tensile test of butt welded HDPE pipe and surface etching of the weldments provided clear delineation about the joint quality.

  19. Mechanical pipe couplings. The alternative jointing method for PE gas pipes up to 10 bar; Mechanische Rohrkupplungen. Die alternative Verbindung fuer PE-Gas-Rohre bis 10 bar

    Energy Technology Data Exchange (ETDEWEB)

    Kroeger, Axel; Johnson, Alexander [PSI Products GmbH, Moessingen (Germany)

    2010-11-15

    Increasing competition nowadays obliges natural gas suppliers to adopt continuous cost-optimization. Many utilities are therefore rethinking their existing methods for jointing of plastic pipes. Around the world, mechanical pipe couplings are becoming established in this field as a rational-cost, safe and easy-to-install alternative to conventional welding methods. For this project, PSI Products GmbH and Elster Perfection are pursuing new routes for the development of solutions to problems in plastic-pipe jointing technology. As a specialist in accessories for the field of pipeline engineering, PSI Products GmbH has now also unveiled, in the form of the Permasert {sup registered} and PermaLock {sup registered} pipe-coupling and jointing systems, a complete product range, with DVGW approval, for mechanical jointing of gas supply pipelines for the German natural gas market. This system has proven its capabilities since its market launch in the USA more than thirty years ago, and is now one of the world's most widely used mechanical PE-pipe jointing methods. Simple and fast installation is the basis of this success. More than 45 million Permasert {sup registered} couplings and PermaLock {sup registered} tapping valves are now in use under virtually all conceivable climatic and soil conditions, and not only in North America and Europe, but also in Asia, Australia, the Middle East, and Central and South America. (orig.)

  20. Corrosion resistant iron aluminides exhibiting improved mechanical properties and corrosion resistance

    Science.gov (United States)

    Liu, Chain T.; McKamey, Claudette G.; Tortorelli, Peter F.; David, Stan A.

    1994-01-01

    The specification discloses a corrosion-resistant intermetallic alloy comprising, in atomic percent, an FeAl iron aluminide containing from about 30 to about 40% aluminum alloyed with from about 0.01 to 0.4% zirconium and from 0.01 to about 0.8% boron. The alloy exhibits considerably improved room temperature ductility for enhanced usefulness in structural applications. The high temperature strength and fabricability is improved by alloying with molybdenum, carbon, chromium and vanadium.

  1. Effects of La2O3 on Mechanical Properties and Corrosion Resistance of H62 Brass

    Science.gov (United States)

    Wu, Xiangwei; Luo, Hong; Sheng, Meng; Liu, Huanchao; Xiao, Zhen; Geng, Haoran

    2017-02-01

    In this article, the effects of lanthanum oxide (La2O3) on the microstructure and mechanical properties of H62 brass were investigated by using the universal testing machine, Brinell hardness tester, optical microscope, and scanning electron microscope (SEM). Immersion corrosion and electrochemical measurements were carried out to identify the influence of La2O3 on the corrosion behavior of the H62 brass. The phase constitution, microstructure, and phase composition of the H62 brass were analyzed by x-ray diffraction, SEM, and energy-dispersive spectrometer, respectively. The results show that the microstructure of α phase changes from dendrite grains to equiaxed grains, and the content and distribution of β phase are improved significantly. When the La2O3 content reaches 0.8 wt.%, the H62 brass obtains favorable comprehensive mechanical properties and the strength and hardness decrease but elongation increases, which is conducive to plastic processing. In addition, under the optimum amount of 0.8 wt.% La2O3 content, the corrosion rate of immersion corrosion attains the minimum values: As 12.6 g m-2 h-1, it decreases by 24%; as the corrosion potential changes from -1.1327 V to -0.328 V, it increases by 70.9%; and as the corrosion current density decreases from -2.833 mA mm-2 to -3.28 mA mm-2 corrosion, it decreases by 15.78%, when compared with H62 brass.

  2. Testing the permeability and corrosion resistance of micro-mechanically interlocked joints

    DEFF Research Database (Denmark)

    Byskov-Nielsen, Jeppe; Holm, Allan Hjarbæk; Højsholt, Rune;

    2011-01-01

    Micro-mechanical interlocking (MMI) can be applied to create new and interesting composite materials. We have employed laser structuring to achieve MMI between stainless steel and plastic with extremely high joint strength. However, the water permeability and corrosion resistance of the joint must...... is conducted. The permeability seems to be consistent with the Hagen–Poiseuille equation independent of the laser structuring technique and is orders of magnitudes larger than the diffusion rate through the plastic. Two different types of corrosion tests have been undertaken, and we show that care must...... be taken in order not to degrade the corrosion resistance of the sample to an unacceptable level....

  3. Corrosion Mechanism of MgO-CaO Brick for AOD Furnace

    Institute of Scientific and Technical Information of China (English)

    WANG Jiandong; GE Changchun; SHEN Weiping

    2006-01-01

    Residual MgO-CaO brick after being used in AOD furnace was determined by OM, SEM and EDAX. Corrosion mechanism of MgO-CaO brick as furnace lining was studied. Results show that: The corrosion of MgOCaO brick is mainly attributed to the solution and infiltration of silicate liquid phase. Transverse cracks between reacted zone and original zone are parallel to the working face, which is an important factor for deteriorating the corrosion of MgO-CaO bricks.

  4. Mechanical Performance versus Corrosion Damage Indicators for Corroded Steel Reinforcing Bars

    Directory of Open Access Journals (Sweden)

    Silvia Caprili

    2015-01-01

    Full Text Available The experimental results of a testing campaign including tensile and low-cycle fatigue tests on different reinforcing steel bar types in the as-delivered and corroded condition are presented. Experimental data were statistically analyzed adopting ANOVA technique; Performance Indicators (PIs, describing the mechanical performance characteristics of reinforcements, and Corrosion Damage Indicators (CDIs, describing the detrimental effects of corrosion phenomena, were determined and correlated in order to evaluate the influence of corrosion on the behaviour of reinforcing steels, providing useful information for designers in addition to what is presented in current standards.

  5. Mechanical and corrosion behaviour of EUROFER 97 steel exposed to Pb-17Li

    Energy Technology Data Exchange (ETDEWEB)

    Benamati, G.; Fazio, C. E-mail: concetta@brasimone.enea.it; Ricapito, I

    2002-12-01

    Corrosion and tensile samples of the EUROFER 97 steel were exposed to Pb-17Li in the LIFUS II loop at 480 deg. C. The specimens were extracted after 1500, 3000 and 4500 h exposure. After extraction, weight change measurements and metallurgical analysis were performed on the corrosion specimens, while tensile tests were performed at 480 deg. C. The results showed that EUROFER 97 underwent uniform corrosion and the mechanical properties seem to be unaffected or only slightly affected by the liquid metal. In this paper, the results are reported and discussed also with reference to previous similar work.

  6. Characteristics and Corrosion Behavior of Pure Titanium Subjected to Surface Mechanical Attrition

    Science.gov (United States)

    Fu, Tianlin; Wang, Xiao; Liu, Jianxiong; Li, Li; Yu, Xiaohua; Zhan, Zhaolin

    2017-08-01

    A stable passive film exhibiting good corrosion resistance in a 3.5 wt.% NaCl solution was formed on the surface of pure titanium (Ti) subjected to a surface mechanical attrition treatment (SMAT). The corrosion potential (-0.21 V) of the film was significantly higher than that (-0.92 V) of the untreated sample. Moreover, the corrosion current density was an order of magnitude lower than that of the untreated sample. SMAT resulted in a decrease in the vacancy condensation in the TiO2 film, thereby inhibiting the invasion and diffusion of Cl- in the film.

  7. 内腐蚀缺陷尺寸对DN150承插管线承压能力的影响%Analysis of the Effects of Corrosion Defect Size on DN150 Socket Pipes Failure Pressure

    Institute of Scientific and Technical Information of China (English)

    李健健; 雍歧卫; 周仁; 林芳清

    2013-01-01

    为了科学地指导DN150承插管线的使用与管理,采用非线性有限元法对带内腐蚀缺陷的DN150承插管线进行了剩余强度的评估。通过分析和计算,研究了腐蚀缺陷宽度、长度和深度对管线极限承载能力的影响。结果表明:腐蚀缺陷宽度对DN150承插管线的承载能力影响很小,可忽略不计;随着腐蚀缺陷长度的增加,管线的承载能力略微减小,当缺陷长度达到150 mm,管道失效压力基本不变;随着腐蚀缺陷深度的增加,管道失效压力呈线性递减,其对管道失效压力的影响程度远远大于腐蚀缺陷长度。%In order to instruct the scientific use and management of DN150 socket pipes,non-linear finite element method is applied to evaluate the residual strength of DN150 socket pipes with internal corrosion defects. The effects of depth,length and width of corrosion defect on the pipe failure pressure is researched through computational analysis. The results show that the effect of corrosion defect width is minor and can be neglected. With the length of corrosion defects increasing,pipes failure pressure is de-creasing fractionally and remains fairly static when the length reaches 150 mm. With the depth of corrosion defects increasing,pipes failure pressure is decreasing linearly. The impact of corrosion defects depth on pipe failure pressure is considerably greater than that of corrosion defect length.

  8. Computational modeling of the mechanism of hydrogen embrittlement (HE) and stress corrosion cracking (SCC) in metals

    Science.gov (United States)

    Cendales, E. D.; Orjuela, F. A.; Chamarraví, O.

    2016-02-01

    In this article theoretical models and some existing data sets were examined in order to model the two main causes (hydrogen embrittlement and corrosion-cracking under stress) of the called environmentally assisted cracking phenomenon (EAC). Additionally, a computer simulation of flat metal plate subject to mechanical stress and cracking due both to hydrogen embrittlement and corrosion was developed. The computational simulation was oriented to evaluate the effect on the stress-strain behavior, elongation percent and the crack growth rate of AISI SAE 1040 steel due to three corrosive enviroments (H2 @ 0.06MPa; HCl, pH=1.0; HCl, pH=2.5). From the computer simulation we conclude that cracking due to internal corrosion of the material near to the crack tip limits affects more the residual strength of the flat plate than hydrogen embrittlement and generates a failure condition almost imminent of the mechanical structural element.

  9. Surface characteristics and mechanical properties of high-strength steel wires in corrosive conditions

    Science.gov (United States)

    Xu, Yang; Li, Shunlong; Li, Hui; Yan, Weiming

    2013-04-01

    Cables are always a critical and vulnerable type of structural components in a long-span cable-stayed bridge in normal operation conditions. This paper presents the surface characteristics and mechanical performance of high-strength steel wires in simulated corrosive conditions. Four stress level (0MPa, 300MPa, 400MPa and 500MPa) steel wires were placed under nine different corrosive exposure periods based on the Salt Spray Test Standards ISO 9227:1990. The geometric feathers of the corroded steel wire surface were illustrated by using fractal dimension analysis. The mechanical performance index including yielding strength, ultimate strength and elastic modulus at different periods and stress levels were tested. The uniform and pitting corrosion depth prediction model, strength degradation prediction model as well as the relationship between strength degradation probability distribution and corrosion crack depth would be established in this study.

  10. DEVELOPMENT OF PERMANENT MECHANICAL REPAIR SLEEVE FOR PLASTIC PIPE

    Energy Technology Data Exchange (ETDEWEB)

    Hitesh Patadia

    2004-09-30

    The report presents a comprehensive summary of the project status related to the development of a permanent mechanical repair fitting intended to be installed on damaged PE mains under blowing gas conditions. Specifically, the product definition has been developed taking into account relevant codes and standards and industry input. A conceptual design for the mechanical repair sleeve has been developed which meets the product definition.

  11. Corrosion and mechanical performance of AZ91 exposed to simulated inflammatory conditions.

    Science.gov (United States)

    Brooks, Emily K; Der, Stephanie; Ehrensberger, Mark T

    2016-03-01

    Magnesium (Mg) and its alloys, including Mg-9%Al-1%Zn (AZ91), are biodegradable metals with potential use as temporary orthopedic implants. Invasive orthopedic procedures can provoke an inflammatory response that produces hydrogen peroxide (H2O2) and an acidic environment near the implant. This study assessed the influence of inflammation on both the corrosion and mechanical properties of AZ91. The AZ91 samples in the inflammatory protocol were immersed for three days in a complex biologically relevant electrolyte (AMEM culture media) that contained serum proteins (FBS), 150 mM of H2O2, and was titrated to a pH of 5. The control protocol immersed AZ91 samples in the same biologically relevant electrolyte (AMEM & FBS) but without H2O2 and the acid titration. After 3 days all samples were switched into fresh AMEM & FBS for an additional 3-day immersion. During the initial immersion, inflammatory protocol samples showed increased corrosion rate determined by mass loss testing, increased Mg and Al ion released to solution, and a completely corroded surface morphology as compared to the control protocol. Although corrosion in both protocols slowed once the test electrolyte solution was replaced at 3 days, the samples originally exposed to the simulated inflammatory conditions continued to display enhanced corrosion rates as compared to the control protocol. These lingering effects may indicate the initial inflammatory corrosion processes modified components of the surface oxide and corrosion film or initiated aggressive localized processes that subsequently left the interface more vulnerable to continued enhanced corrosion. The electrochemical properties of the interfaces were also evaluated by EIS, which found that the corrosion characteristics of the AZ91 samples were potentially influenced by the role of intermediate adsorption layer processes. The increased corrosion observed for the inflammatory protocol did not affect the flexural mechanical properties of the AZ91

  12. Mechanical properties and corrosion resistance of some titanium alloys in marine environment

    Directory of Open Access Journals (Sweden)

    Dupuis Jennifer

    2013-11-01

    Full Text Available Titanium alloys are used in several fields such as aerospace industry or biomedical. They are increasingly used in marine applications, a highly corrosive environment. We chose titanium alloys for their good properties such as high mechanical strength, low density and excellent corrosion resistance. This study is focused on titanium alloys potentially interesting to be used in marine transports, and mainly for the boats fittings such as a winch for example.

  13. Graphene coating for anti-corrosion and the investigation of failure mechanism

    Science.gov (United States)

    Zhu, Y. X.; Duan, C. Y.; Liu, H. Y.; Chen, Y. F.; Wang, Y.

    2017-03-01

    Graphene produced by chemical vapor deposition (CVD) methods has been considered as a promising corrosion prevention layer because of its exceptional structure and impermeability. However, the anti-corrosion performance and the failure mechanism are still controversial. In this study, graphene layers with different quality levels, crystallite sizes, and layer numbers were prepared on the surface of Cu by a CVD process. The effects of grain boundaries (GBs) on the failure of graphene layers to provide adequate protection were investigated in detail by combining graphene transfer techniques, computation, and anti-corrosion measurements. Our results reveal that corrosion rates decrease marginally upon the increase of graphene layer number, and this rather weak dependence on thickness likely arises from the aligned nature of the GBs in CVD-grown few-layer graphene. This problem can potentially be overcome by layer-by-layer graphene transfer technique, in which corrosion is found to be arrested locally when transferred graphene is present on top of the as-grown graphene. However, this advantage is not reflected in corrosion studies performed on large-scale samples, where cracks or imperfect interfaces could offset the advantages of GB misalignment. With improvements in technology, the layer-by-layer assembly technique could be used to develop an effective anti-corrosion barrier.

  14. Corrosion in systems for storage and transportation of petroleum products and biofuels identification, monitoring and solutions

    CERN Document Server

    Groysman, Alec

    2014-01-01

    This book treats corrosion as it occurs and affects processes in real-world situations, and thus points the way to practical solutions. Topics described include the conditions in which petroleum products are corrosive to metals; corrosion mechanisms of petroleum products; which parts of storage tanks containing crude oils and petroleum products undergo corrosion; dependence of corrosion in tanks on type of petroleum products; aggressiveness of petroleum products to polymeric material; how microorganisms take part in corrosion of tanks and pipes containing petroleum products; which corrosion monitoring methods are used in systems for storage and transportation of petroleum products; what corrosion control measures should be chosen; how to choose coatings for inner and outer surfaces of tanks containing petroleum products; and how different additives (oxygenates, aromatic solvents) to petroleum products and biofuels influence metallic and polymeric materials. The book is of interest to corrosion engineers, mat...

  15. Effect of Saturated CO2 on Corrosion Behavior of 13Cr Pipe Steel in High Chloride Environment%高氯环境中饱和CO2对13Cr油管钢腐蚀行为的影响

    Institute of Scientific and Technical Information of China (English)

    雷冰; 马元泰; 李瑛; 王福会; 常泽亮; 谢俊峰; 宋文文; 周理志

    2013-01-01

    The effect of saturated CO2 on corrosion behavior of 13Cr pipe steel in high concentration chloride environment was studied by EIS, polarization test, EN test and SEM. The results indicated that the corrosion rate and corrosion probability of 13Cr pipe steel were accelerated in high chloride environment with the presence of saturated CO2. The 13Cr pipe steel suffered from pitting corrosion in high chloride concentration environment, whilst, from uniform corrosion by the synergistic effect of Cl and CO2. The stability of the passive film of 13Cr pipe steel decreased in high concentration chloride environment with saturated CO2, which can be explained by the dehydroxylation of the outer part of the passive film by carbonic acid and the increase of ionic conductivity of the passive film in aqueous electrolytes.%采用电化学阻抗(EIS)、极化曲线、电化学噪声(EN)和扫描电子显微镜(SEM)研究了高氯环境中饱和CO2对13Cr油管钢腐蚀行为的影响.结果表明:饱和CO2加速材料的腐蚀,增大了腐蚀的发生频率,使材料的腐蚀由点蚀转变为均匀腐蚀.碳酸对钝化膜的去羟基化作用和增大钝化膜的导通率,是材料腐蚀行为变化的原因.

  16. Thermal protection mechanism of heat pipe in leading edge under hypersonic conditions

    OpenAIRE

    Peng Wengen; He Yurong; Wang Xinzhi; Zhu Jiaqi; Han Jiecai

    2015-01-01

    Sharp local structure, like the leading edge of hypersonic aircraft, confronts a severe aerodynamic heating environment at a Mach number greater than 5. To eliminate the danger of a material failure, a semi-active thermal protection system is proposed by integrating a metallic heat pipe into the structure of the leading edge. An analytical heat-balance model is established from traditional aerodynamic theories, and then thermal and mechanical characteristics of the structure are studied at Ma...

  17. Corrosion Mechanism of Ladle Furnace Refining Slag to Fired MgO-CaO Bricks

    Institute of Scientific and Technical Information of China (English)

    ZHU Boquan; FANG Binxiang; ZHANG Wenjie; LI Xiangcheng; WAN Hongbo

    2010-01-01

    Corrosion effect of ladle furnace(LF)refining slag on fired MgO-CaO bricks with about 34% CaO was studied by static crucible method,and corrosion mechanism was analyzed by techniques of scan electron micrograph,energy dispersive spectrometer,and X-ray dif-fraction.The results show that: MgO-CaO bricks exhibit excellent corrosion resistance but poor penetration in reaction zone results in volume expansion forming MgO-CaO bricks increases liquid phases which accelerates corrosion of the bricks; a protective layer of 2CaO·SiO2 formed on reaction interface prevents penetration of C2F to the bricks.

  18. Reducing And Analysizing of Flow Accelerated Corrosion at Thermal Power Plant, Heat Recovery Steam Generators

    OpenAIRE

    Akın Avşaroğlu; Suphi URAL

    2017-01-01

    The purpose of this study is to Reducing and Analysing of Flow Accelerated Corrosion in Thermal Plant Heat Recovery Steam Generators. All these studies have been performed in a new and 16 year-old established Combined Cycle Power Plants in Turkey. Corrosion cases have been investigated due to Mechanical Outage Reports at Power Plant in 2011-2015. Flow Accelerated Corrosion study has been based on specific zone related with Economizer Low Pressure connection pipings. It was issued a performanc...

  19. Development of WELDABLE12CR stainless steel seamless pipe with superior weldability and corrosion resistance for linepipe application; Yosetsusei oyobi taishokusei ni sugureta linepipe yo stainless keimokumukokan WELDABLE12CR no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Miyata, Y.; Kimura, M.; Toyooka, T.; Nakano, Y.; Murase, F. [Kawasaki Steel Corp., Tokyo (Japan)

    1998-06-20

    Severe corrosive circumstance of oil wells and gas wells including high temperature, high CO2 partial pressure, high chlorine ion concentration, and further H2S are becoming more and more serious in recent years. Measures to prevent CO2 corrosion and sulfide stress crack are necessary for pipelines called flowlines and gathering line for transporting oil or gas which has severe corrosivity before treatment. WELDABLE12CR steel pipe which is seamless martensite stainless steel with excellent weldability and corrosion resistance is developed by the present authors. There two kinds of such steel pipes, one is 11Cr steel (0.01C-11Cr-1.5Ni-0.5Cu-0.01N-based steel) that is superior in corrosion resistance to 13Cr steel for oil well so that it can be used in CO2 circumstance, and the other one is 12Cr steel (0.01C-12Cr-5Ni-2Mo-0.01N-based steel) that has excellent SSC-resistance thus being used in the circumstance containing CO2 and a trace quantity of H2S. 5 refs., 4 figs., 3 tabs.

  20. Accounting the mechanical resistance of testing device for straight-flow branch pipe in the transverse direction

    Science.gov (United States)

    Sitnikov, D. V.; Klishin, S. V.; Zubarev, A. V.; Shvarts, A. A.

    2017-06-01

    The flexible inserts as a rubber-cord branch pipe are used to reduce the vibrations distributed from units of a hydraulic system through the pipelines. The device with completely rigid elements is used for the experimental determination of the stiffness characteristics of the branch pipes that determine their anti-vibration properties. In the paper the study of the mechanical resistances of an experimental device construction is carried out by method of the harmonic analysis in a frequency range of 1 Hz to 1000 Hz. Then these mechanical resistances are compared with the mechanical resistance of the branch pipe with diameter 100 mm obtained experimentally. It is found as a result it is necessary to take into account the value of the device mechanical resistance when the stiffness characteristics of the rubber-cord branch pipes with diameter 100 mm in the transverse direction at frequencies above 735 Hz are determined experimentally.

  1. Investigation of the cold process pipe rupture mechanism

    CERN Document Server

    CERN. Geneva

    2016-01-01

    Cryogenic process pipelines are part of the basic subsystem used in installations for fundamental research in physics, as well as in industrial plants which use LNG or liquid nitrogen. The significant increase in importance of cryogenics entails the need to explore phenomena which have direct impact in the design process of cryogenic systems and their safety systems. These aspects are of high priority due to high investment costs, mainly because of safety issues and reliability. One of the issues which requires thorough investigation is the fracture mechanics of gas pipelines in cryogenic conditions. For this subject, importance is placed not only in when the cracks begin to appear, but also in how they form and how quickly they propagate. Currently, there is a lack of reliable research in the available literature in this area. This is often raised as a significant problem for designers, because knowledge in this topic should be reflected e.g., in the sizing calculations of safety valves for the vacuum syste...

  2. Predicting the long term corrosion behaviour of pipe steels used at the CCS-site Ketzin, Germany in laboratory CO{sub 2}-saturated saline aquifer CCS-environment

    Energy Technology Data Exchange (ETDEWEB)

    Pfennig, A.; Linke, B. [HTW Univ. of Applied Sciences Berlin, Berlin (Germany); Kranzmann, A. [Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin (Germany)

    2010-07-01

    During Carbon Capture and Storage (CCS) CO{sub 2}-corrosion of pipe steels is a relevant safety issue when emission gases are compressed in deep geological layers. The reliability of the steels 42CrMo4 (1.7225), X46Cr13 (1.4034), X20Cr13 (1.4021) and X35CrMo17 (1.4122) is demonstrated in laboratory experiments under an equivalent corrosive aquifer environment as found at the geological onshore CCS-site at Ketzin, Germany at the in-situ temperature 60 C. (orig.)

  3. 海洋腐蚀环境及船用不锈钢管选材备考(下)%Review on Stainless Steel Pipe Selecting Materials Used in Ocean Corrosion Environment and Ship(Ⅱ)

    Institute of Scientific and Technical Information of China (English)

    何德孚; 王晶滢

    2016-01-01

    The marine corrosion environment was analyzed from the composition of water and sea water corrosion factors. According to the standard of marine stainless steel pipe,it analyzed and assessed the material selection of stainless steel pipe used for ocean petroleum and petrochemical for different use and environment,and analyzed the application case of stainless steel pipe used for marine at home and abroad,finally,it discussed the development tendency of corrosion resistance alloy. The research results showed that Cl- pitting corrosion and crevice corrosion are the root cause of the marine environment corrosion hazard,304L steel is not with the ocean corrosion resistance performance,316L steel can only be used in water after deoxidization under a certain environment and temperature;Application of stainless steel pipe in natural seawater should adopt cathodic protection measures,it should consider the composition of internal oil and gas medium and corrosion characteristics in materials selecting for all kinds of pipeline in oil recovery platform production operation ship.%从海水的成分和海水腐蚀因素对海洋腐蚀环境进行了分析,根据海洋船舶不锈钢管材的标准,分析并评估了海洋石油石化用不锈钢管在不同用途和环境下的选材思路,列举并分析了国内外海洋用不锈钢管的应用案例,最后对船舶用耐蚀合金的发展趋势进行了讨论。研究结果表明, Cl-孔蚀和缝隙腐蚀是海洋环境腐蚀危害的根本原因,304L钢不具备耐海洋腐蚀的性能,316L钢只能在一定环境和温度下在脱氧后的海水中使用;在自然海水中应用不锈钢管必须采用阴极保护措施;采油平台等油气生产作业船舶中各类管道的选材应先考虑其内部的油气介质成分及其腐蚀特征。

  4. Review on Stainless Steel Pipe Selecting Materials Used in Ocean Corrosion Environment and Ship(Ⅰ)%海洋腐蚀环境及船用不锈钢管选材备考(上)

    Institute of Scientific and Technical Information of China (English)

    何德孚; 王晶滢

    2016-01-01

    从海水的成分和海水腐蚀因素对海洋腐蚀环境进行了分析,根据海洋船舶不锈钢管材标准,分析并评估了海洋石油石化用不锈钢管在不同用途和环境下的选材思路,列举并分析了国内外海洋用不锈钢管的应用案例,最后对船舶用耐蚀合金的发展趋势进行了讨论.研究结果表明,Cl-孔蚀和缝隙腐蚀是海洋环境腐蚀危害的根本原因,304L钢不具备耐海洋腐蚀的性能,316L钢只能在一定环境和温度下在脱氧后的海水中使用;在自然海水中应用不锈钢管必须采用阴极保护措施;采油平台等油气生产作业船舶中各类管道的选材应先考虑其内部的油气介质成分及其腐蚀特征.%The marine corrosion environment was analyzed from the composition of water and sea water corrosion factors. According to the standard of marine stainless steel pipe, it analyzed and assessed the material selection of stainless steel pipe used for ocean petroleum and petrochemical for different use and environment, and analyzed the application case of stainless steel pipe used for marine at home and abroad, finally, it discussed the development tendency of corrosion resistance alloy. The research results showed that Cl- pitting corrosion and crevice corrosion are the root cause of the marine environment corrosion hazard, 304L steel is not with the ocean corrosion resistance performance, 316L steel can only be used in water after deoxidization under a certain environment and temperature; Application of stainless steel pipe in natural seawater should adopt cathodic protection measures, it should consider the composition of internal oil and gas medium and corrosion characteristics in materials selecting for all kinds of pipeline in oil recovery platform production operation ship.

  5. Corrosion resistance of AISI 304 and 444 stainless steel pipes in sanitizing solutions of clean-in-place process

    OpenAIRE

    Lins,Vanessa de Freitas Cunha; Gonçalves,Giselle Aline dos Santos; Leão,Tiago Paschoalin; Soares,Renata Braga; Costa,Cíntia Gonçalves Fonseca; Viana,Adolfo Kalergis do Nascimento

    2016-01-01

    Stainless steel (SS) is successfully used in food industries due to the characteristics of its surface, which is essential for the maintenance of the properties of food. Tanks and stainless steel pipes, which come into direct contact with food and drink, undergo a process of cleaning and disinfecting called CIP (Clean-in-Place). This method consists of automatic recirculation of a detergent solution for a controlled time followed by a rinsing with water, and finally a cleaning and sanitizing ...

  6. Evaluation on mechanical and corrosion properties of steam generator tubing materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In Sup; Lee, Byong Whi; Lee, Sang Kyu; Lee, Young Ho; Kim, Jun Whan; Lee, Ju Seok; Kwon, Hyuk Sang; Kim, Su Jung [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)

    1998-06-15

    Steam generator is one of the major components of nuclear reactor pressure boundary. It's main function os transferring heat which generated in the reactor to turbine generator through steam generator tube. In these days, steam generator tubing materials of operating plant are used Inconel 600 alloys. But according to the operation time, there are many degradation phenomena which included mechanical damage due to flow induced vibration and corrosion damage due to PWSCC, IGA/SCC and pitting etc. Recently Inconel 690 alloys are selected as new and replacement steam generator tubes for domestic nuclear power plant. But there are few study about mechanical and corrosion properties of Inconel 600 and 690. The objectives of this study is to evaluate and compare mechanical and corrosion propertied of steam generator tube materials.

  7. The calculation of mechanical energy loss for incompressible steady pipe flow of homogeneous fluid

    Institute of Scientific and Technical Information of China (English)

    刘士和; 薛娇; 范敏

    2013-01-01

    The calculation of the mechanical energy loss is one of the fundamental problems in the field of Hydraulics and Enginee- ring Fluid Mechanics. However, for a non-uniform flow the relation between the mechanical energy loss in a volume of fluid and the kinematical and dynamical characteristics of the flow field is not clearly established. In this paper a new mechanical energy equation for the incompressible steady non-uniform pipe flow of homogeneous fluid is derived, which includes the variation of the mean tur- bulent kinetic energy, and the formula for the calculation of the mechanical energy transformation loss for the non-uniform flow bet- ween two cross sections is obtained based on this equation. This formula can be simplified to the Darcy-Weisbach formula for the uniform flow as widely used in Hydraulics. Furthermore, the contributions of the mechanical energy loss relative to the time avera- ged velocity gradient and the dissipation of the turbulent kinetic energy in the turbulent uniform pipe flow are discussed, and the con- tributions of the mechanical energy loss in the viscous sublayer, the buffer layer and the region above the buffer layer for the turbu- lent uniform flow are also analyzed.

  8. Development of the utilization of combustible gas produced in existing sanitary landfills: Effects of corrosion at the Mountain View, California landfill gas-recovery plant

    Science.gov (United States)

    1982-10-01

    Corrosion of equipment has occurred at the Mountain View, California Landfill Gas Recovery Plant. Corrosion is most severe on compressor valve seats and cages, tubes in the first and second stages of the interstage gas cooler, and first and second stage piping and liquid separators. Corrosion occurs because the raw landfill gas contains water, carbon dioxide, and oxygen. Some corrosion may also result from trace concentrations of organic acids present in the landfill gas. Corrosion of the third stage compressor, cooler, and piping does not occur because the gas is dehydrated immediately prior to the third stage. Controlling corrosion is necessary to maintain the mechanical integrity of the plant and to keep the cost of the gas competitive with natural gas. Attempts to reduce corrosion rates by injecting a chemical inhibitor have proved only partially successful. Recommendations for dealing with corrosion include earlier dehydration of the gas, selection of special alloys in critical locations, chemical inhibition, and regular plant inspections.

  9. Influence of CO2 corrosion on rock structure and its mechanical characteristics

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Influence of CO2 corrosion on reservoir mineralogical composition,pore structure and their mechanical characteristics was studied using XRD,SEM,rock tri-axial machine and core flow experimental equipment.It was found that the corrosion effect was mainly attributed to rock texture and structure,fluid composition and external dynamical conditions in the experimental conditions.For cores with bedding structures,their bedding surfaces were the preferential corrosion regions,because micro-cracks would evolve at these surfaces in the pressure-releasing process.However,for cores with massive structures controlled by stable water environment,the CO2 corrosion would result in pore enlargement and secondary pore formation.The gas velocity from outlet showed sharp increase in the injection process of CO2-H2O solution.This could be explained by two changes caused by corrosion.One was the opening and closure of micro-cracks.The other was particle migration.As the corrosion time increased,both tensile strength and compressive strength decreased,which confirmed decrease of cementation strength.It should also be noted that permeability increase and micro-cracks generation would pose damage to the capacity of CO2 geological storage.

  10. The intrinsically high pitting corrosion resistance of mechanically polished nitinol in simulated physiological solutions.

    Science.gov (United States)

    Bai, Zhijun; Rotermund, Harm H

    2011-10-01

    Nitinol wires have been widely used in many biomedical applications, such as cardiovascular stent due to their superelasticity and shape memory effect. However, their corrosion properties and the related biocompatibility are not well understood, and the reported results are controversial. In this study, we evaluate the pitting corrosion property of nitinol, titanium, nickel, and 316L stainless steel (316LSS) wires with different surface roughnesses in a saline solution at 37 °C. The cyclic potentiodynamic polarization results show that mechanically polished nitinol and Ti wires are highly resistant to pitting corrosion, while Ni and 316LSS wires are susceptible to pitting corrosion. Electrochemical impedance spectroscopy is used to study the interface of oxide film/solution and all mechanically polished nitinol wires are covered by 2-3 nm thick films formed under open circuit potential. Furthermore, the electronic structures and semiconducting properties of passive films on nitinol, Ti and Ni wires are studied by Mott-Schottky analysis. Passive films formed on nitinol and Ti exhibit n-type semiconducting characteristics, whereas films on Ni show p-type semiconducting characteristics. Scanning Kelvin Microscopy is used to measure the surface potential difference between common inclusions from the nitinol matrix and the results indicate that the inclusions are more electrochemically noble than the nitinol matrix. Band energy theory is used to model the electrochemical interface between the passive films of nitinol and the solution under different applied potential conditions. A mechanism for the strong pitting corrosion resistance of nitinol in saline solution is proposed.

  11. Photohole Induced Corrosion of Titanium Dioxide: Mechanism and Solutions.

    Science.gov (United States)

    Yang, Yi; Ling, Yichuan; Wang, Gongming; Liu, Tianyu; Wang, Fuxin; Zhai, Teng; Tong, Yexiang; Li, Yat

    2015-10-14

    Titanium dioxide (TiO2) has been extensively investigated as photoanode for water oxidation, as it is believed to be one of the most stable photoanode materials. Yet, we surprisingly found that TiO2 photoanodes (rutile nanowire, anatase nanotube, and P25 nanoparticle film) suffered from substantial photocurrent decay in neutral (Na2SO4) as well as basic (KOH) electrolyte solution. Photoelectrochemical measurements togehter with electron microscopy studies performed on rutile TiO2 nanowire photoanode show that the photocurrent decay is due to photohole induced corrosion, which competes with water oxidation reaction. Further studies reveal that photocurrent decay profile in neutral and basic solutions are fundamentally different. Notably, the structural reconstruction of nanowire surface occurs simultaneously with the corrosion of TiO2 in KOH solution resulting in the formation of an amorphous layer of titanium hydroxide, which slows down the photocorrosion. Based on this discovery, we demonstrate that the photoelectrochemical stability of TiO2 photoanode can be significantly improved by intentionally coating an amorphous layer of titanium hydroxide on the nanowire surface. The pretreated TiO2 photaonode exhibits an excellent photocurrent retention rate of 97% after testing in KOH solution for 72 h, while in comparison the untreated sample lost 10-20% of photocurrent in 12 h under the same measurement conditions. This work provides new insights in understanding of the photoelectrochemical stability of bare TiO2 photoanodes.

  12. Analysis of the mechanical properties of a reinforced thermoplastic pipe (RTP)

    NARCIS (Netherlands)

    Kruijer, M.P.; Warnet, Laurent; Akkerman, Remko

    2005-01-01

    This paper describes the analysis of a long length reinforced thermoplastic pipe. For this new class of pipe, which is constructed of a polyethylene liner pipe over wrapped with two layers of non-impregnated twisted aramid cords, peculiar deformation behaviour was observed when a pipe was

  13. ESTIMATION OF RESIDUAL CONTACT PRESSURE IN HYDRAULICALLY EXPANDED CRA-LINED PIPE

    Institute of Scientific and Technical Information of China (English)

    Wang Xuesheng; Li Peining; Wang Ruzhu

    2004-01-01

    The mechanically bonded CRA-lined pipe is developed to meet the need for corrosion-resistant alloy steel pipe. Residual contact pressure at the interface of lined pipe is important factor that governs the quality of lined pipe. A simplified theoretical method is presented to predict the residual contact pressure created by hydraulic pressure. The calculating equation related hydro-forming pressure to the residual contact pressure between two metal faces is derived. And the validation of the proposed equation is accomplished by comparing its result to those obtained by experimental investigation.

  14. Reactions of plutonium dioxide with water and oxygen-hydrogen mixtures: Mechanisms for corrosion of uranium and plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Haschke, John M.; Allen, Thomas H.; Morales, Luis A.

    1999-06-18

    Investigation of the interactions of plutonium dioxide with water vapor and with an oxygen-hydrogen mixture show that the oxide is both chemically reactive and catalytically active. Correspondence of the chemical behavior with that for oxidation of uranium in moist air suggests that similar catalytic processes participate in the mechanism of moisture-enhanced corrosion of uranium and plutonium. Evaluation of chemical and kinetic data for corrosion of the metals leads to a comprehensive mechanism for corrosion in dry air, water vapor, and moist air. Results are applied in confirming that the corrosion rate of Pu in water vapor decreases sharply between 100 and 200 degrees C.

  15. New corrosion issues in gas sweetening plants

    Energy Technology Data Exchange (ETDEWEB)

    Asperger, R.G. (CLI International and Asperger Technologies, Houston, TX (United States))

    Gas treating plants are experiencing corrosion problems which impact on efficiency and safety. While general corrosion is not particularly hazardous in the gas processing industry, local corrosion is very dangerous since it has several different mechanisms, all of which have dangerously high rates, and it occurs at locations which are hard to find and hard to predict. A newly discovered, velocity-dependent type of corrosion is reported. It is related to yet-undefined species which cause excessively high corrosion in areas of turbulence. This accelerated corrosion is not due to erosion or cavitation, but to a diffusion-limited reaction accelerated by turbulence. A full-flow test loop was built to evaluate the corrosiveness of gas plant solutions at their normal temperature and flow rates. Test runs were conducted with Co[sub 2]-loaded amine solutions for periods of 12 days. Carbon steel specimens mounted in the test loop were examined and corrosion rates calculated. Chromium alloys were shown to be attacked by corrodents in the low-velocity part of the loop and very aggressively attacked in the high-velocity part. The tests demonstrate the need for rigorous monitoring of corrosion in areas of higher velocity such as piping elbows and other points of turbulence. 5 refs., 2 figs., 3 tabs.

  16. Mechanism of intergranular corrosion of NiCu alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, W.; Zhang, J. [Univ. of Toronto, Dept. of Chemical Engineering and Applied Chemistry, Toronto, Ontario (Canada)

    2006-07-01

    The objective of this study is to simulate intergranular corrosion (or intergranular attack, IGA) of Monel 400 (70Ni-30Cu) tubes that occurs occasionally in practice. In general the hypothesized factors of IGA for Monel 400 tubing could be crevices, dissolved oxygen, low pH, reduced sulfur species, and precipitation of impurities at grain boundaries. Electrochemical techniques including cyclic polarization and long-term potentiostatic polarization were used to test two heats of Monel 400 tubing that had behaved differently in practice. To simulate the situation within a crevice or under a deposit, cupric ions were added to the base solution, which was either neutral or acidic in pH. The effect of thiourea as a representative reduced sulfur compound was investigated. The results show that in neutral solution IGA occurs with little sensitivity to metallurgy and does not require thiourea, but in acid solution it only occurs with thiourea addition, and particular grain boundary microstructures are more susceptible. (author)

  17. Corrosion mechanism of micro-arc oxidation treated biocompatible AZ31 magnesium alloy in simulated body fluid

    Directory of Open Access Journals (Sweden)

    Ying Li

    2014-10-01

    Full Text Available The rapid degradation of magnesium (Mg based alloys has prevented their further use in orthopedic trauma fixation and vascular intervention, and therefore it is essential to investigate the corrosion mechanism for improving the corrosion resistance of these alloys. In this work, the effect of applied voltage on the surface morphology and the corrosion behavior of micro-arc oxidation (MAO with different voltages were carried out to obtain biocompatible ceramic coatings on AZ31 Mg alloy. The effects of applied voltage on the surface morphology and the corrosion behavior of MAO samples in the simulated body fluid (SBF were studied systematically. Scanning electron microscope (SEM and X-ray diffractometer (XRD were employed to characterize the morphologies and phase compositions of coating before and after corrosion. The results showed that corrosion resistance of the MAO coating obtained at 250 V was better than the others in SBF. The dense layer of MAO coating and the corrosion precipitation were the key factors for corrosion behavior. The corrosion of precipitation Mg(OH2 and the calcium phosphate (Ca–P minerals on the surface of MAO coatings could enhance their corrosion resistance effectively. In addition, the mechanism of MAO coated Mg alloys was proposed.

  18. Corrosion mechanism of micro-arc oxidation treated biocompatible AZ31 magnesium alloy in simulated body fluid

    Institute of Scientific and Technical Information of China (English)

    Ying Lia; Fang Lu; Honglong Li; Wenjun Zhu; Haobo Pan; Guoxin Tand; Yonghua Lao; Chengyun Ning; Guoxin Ni

    2014-01-01

    The rapid degradation of magnesium (Mg) based alloys has prevented their further use in orthopedic trauma fixation and vascular intervention, and therefore it is essential to investigate the corrosion mechanism for improving the corrosion resistance of these alloys. In this work, the effect of applied voltage on the surface morphology and the corrosion behavior of micro-arc oxidation (MAO) with different voltages were carried out to obtain biocompatible ceramic coatings on AZ31 Mg alloy. The effects of applied voltage on the surface morphology and the corrosion behavior of MAO samples in the simulated body fluid (SBF) were studied systematically. Scanning electron microscope (SEM) and X-ray diffractometer (XRD) were employed to characterize the morphologies and phase compositions of coating before and after corrosion. The results showed that corrosion resistance of the MAO coating obtained at 250 V was better than the others in SBF. The dense layer of MAO coating and the corrosion precipitation were the key factors for corrosion behavior. The corrosion of precipitation Mg(OH)2 and the calcium phosphate (Ca–P) minerals on the surface of MAO coatings could enhance their corrosion resistance effectively. In addition, the mechanism of MAO coated Mg alloys was proposed.

  19. Development of a resilient mechanical sealing solution to resist electro corrosion in ultrapure feedwater applications

    Energy Technology Data Exchange (ETDEWEB)

    Loenhout, Gerard van [Flowservice Flow Solutions Division, Etten-Leur (Netherlands); Enders, Klaus; Schmerberg, Rainer [Vattenfall Europe Generation AG, Peitz (Germany)

    2012-11-01

    Ever since the introduction of mechanical seals on high speed boiler feed pumps in the sixties, mechanical seals have proven to be a reliable, cost effective sealing method. However, since the introduction of combined water treatment chemistry used in today's modern fossil-fuelled power stations, keeping mechanical seal reliability high, became a challenge. A pragmatic approach is presented. A resilient sealing solution was developed to resist electro corrosion for such critical feed water pumps. (orig.)

  20. The mechanism of corrosion-erosion in steam extraction lines of power stations

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Caldera, L.E.; Griffith, P.; Rabinowicz, E.

    1988-04-01

    Corrosion-erosion occurs in steam extraction piping made of low carbon steel that conveys wet steam. The rate of metal removal peaks at 150/sup 0/C and is most severe on the inside and outside of bends and in the vicinity of fittings. A theory is presented by which three processes are shown to give rise to the observed peak in the metal removal rate: (1) the oxidation reaction, (2) the mass transfer process, which governs at 150/sup 0/C, and (3) the diffusion resistance of the oxide layer, which governs at higher temperatures. The results of the derived model agree well with the available experimental data in predicting wear rates and in establishing the temperature and the location of maximum material removal.

  1. Influence of austempering heat treatment on mechanical and corrosion properties of ductile iron samples

    Directory of Open Access Journals (Sweden)

    M. Janjić

    2016-07-01

    Full Text Available Mechanical properties and corrosion resistance of metals are closely related to the microstructure characteristics of the material. The paper compares the results of these two sets of properties after investigating samples of base ductile iron and heat-treated samples of the base austempered ductile iron (ADI. The basic material is perlite ferritic iron alloyed with copper and nickel. To test the corrosion rate of the base material (ductile iron and the heattreated samples (ADI, electrochemical techniques of potentiostatic polarization were used (the technique of Tafel curves extrapolation and the potentiodynamic polarization technique.

  2. Corrosion mechanism of micro-arc oxidation treated biocompatible AZ31 magnesium alloy in simulated body fluid

    OpenAIRE

    Ying Li; Fang Lu; Honglong Li; Wenjun Zhu; Haobo Pan; Guoxin Tan; Yonghua Lao; Chengyun Ning; Guoxin Ni

    2014-01-01

    The rapid degradation of magnesium (Mg) based alloys has prevented their further use in orthopedic trauma fixation and vascular intervention, and therefore it is essential to investigate the corrosion mechanism for improving the corrosion resistance of these alloys. In this work, the effect of applied voltage on the surface morphology and the corrosion behavior of micro-arc oxidation (MAO) with different voltages were carried out to obtain biocompatible ceramic coatings on AZ31 Mg alloy. The ...

  3. Review of application code and standards for mechanical and piping design of HANARO fuel test loop

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J. Y.

    1998-02-01

    The design and installation of the irradiation test facility for verification test of the fuel performance are very important in connection with maximization of the utilization of HANARO. HANARO fuel test loop was designed in accordance with the same code and standards of nuclear power plant because HANARO FTL will be operated the high pressure and temperature same as nuclear power plant operation conditions. The objective of this study is to confirm the propriety of application code and standards for mechanical and piping of HANARO fuel test loop and to decide the technical specification of FTL systems. (author). 18 refs., 8 tabs., 6 figs.

  4. The mechanism of corrosion of palladium-silver binary alloys in artificial saliva.

    Science.gov (United States)

    Joska, L; Marek, M; Leitner, J

    2005-05-01

    Palladium dental casting alloys are alternatives to gold alloys. The aim of this study was to determine the electrochemical behaviour and the corrosion mechanism of binary silver-palladium alloys. Seven binary silver-palladium alloys and pure palladium and silver were tested in a model saliva solution. Electrochemical tests included corrosion potential, polarization resistance, and potentiodynamic polarization measurements. The corrosion products, which may be theoretically formed, were determined by thermodynamic calculation. The behaviour of silver and silver-rich alloys was dominated by the preferential formation of a thiocyanate surface layer, which controlled the free corrosion potential. Palladium dissolved in the form of a thiocyanate complex, but the surface became passivated by either palladium oxide or solid palladium thiocyanate layer, the thermodynamic calculations indicating preference for the oxide. Palladium-rich alloys showed evidence of silver depletion of the surface, resulting in behaviour similar to palladium. Examination of binary silver-palladium alloys has made possible determination of the role of the components of the alloys and model saliva in the corrosion behaviour. The findings are applicable to the more complex commercial dental alloys containing silver and palladium as major components.

  5. Fabrication, lattice strain, corrosion resistance and mechanical strength of nanocrystalline nickel films

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Nanocrystalline nickel films of 17-40 nm grain sizes were prepared using pulsejet electrodeposition. Structure, corrosion and lattice strain were analysed by transmission electron microscope, electrochemical workstation and X-ray diffraction, revealing that with decreasing of grain size, the lattice strain, corrosion rate of the films are enhanced. The observations can be consistently understood in terms of the bond-order-length-strength correlation mechanism indicating that the shortened and strengthened bonds between the under-coordinated atoms modify the energy density and the atomic cohesive energy in the surface skins of the grains.The surface energy density gain is responsible for the residual atomic cohesive energy for the activation energy of corrosion.Additionally, a novel algorithm was proposed to extract the elastic-plastic properties of nickel films and results that the nickel film has much higher yield strength than bulk nickel.

  6. Copper corrosion mechanism in the presence of formic acid vapor for short exposure times

    Energy Technology Data Exchange (ETDEWEB)

    Bastidas, J.M.; Lopez-Delgado, A.; Cano, E.; Polo, J.L.; Lopez, F.A.

    2000-03-01

    The rate of copper corrosion originated by the action of formic acid vapors at 100% relative humidity was studied. Five formic vapor concentration levels (10, 50, 100, 200, and 300 ppm) were used. A copper corrosion rate of up to 1,300 mg/m{sup 2} d was measured for a period of 21 days using a gravimetric method. The patina layers were characterized using cathodic reduction, X-ray powder diffraction. Fourier transform infrared spectrometry, and scanning electron microscopy techniques. Some of the components identified in the corrosion-product layers were cuprite (Cu{sub 2}O), cupric hydroxide hydrate [Cu(OH){sub 2}{sm_bullet}H{sub 2}O], and copper formate hydrate [Cu(HCOO){sub 2}{sm_bullet}4H{sub 2}O]. The latter was formed by both cupric hydroxide and formic acid-cuprous ion complex mechanisms.

  7. The influence of insulation materials on corrosion under insulation

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.; Evans, O. [Aspen Aerogels Inc., Northborough, MA (United States)

    2010-07-01

    This paper discussed the ways in which insulation materials influence corrosion under insulation (CUI) behaviour. Laboratory and field tests of 7 industrial insulation materials and 1 composite system were conducted to identify metrics for improving insulation system designs and determine insulation degradation mechanisms. The tested materials included calcium silicate; expanded perlite; cellular glass; mineral wool; and 2 types of aerogel blanket material. Twelve-week accelerated corrosion tests were conducted to gauge the level of corrosion that occurred beneath the materials on uncoated carbon steel pipe. Drying rate curves for porous materials were also established. A series of aqueous extraction studies was conducted to characterize the durability of various inhibitors on the pipe samples. Results of the study showed that the use of corrosion inhibitors and ensuring the thermal stability of hydrophobing agents will help to prevent CUI. 16 refs., 7 tabs., 17 figs.

  8. Mechanical, tribological and corrosion performance of WBN composite films deposited by reactive magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Lihua; Zhao, Hongjian; Xu, Junhua, E-mail: jhxu@just.edu.cn

    2014-10-01

    Highlights: • WBN composite films were deposited by reactive magnetron sputtering. • The WBN film which exhibited the highest hardness had best wear resistance at room and elevated temperature. • The corrosion resistance of the substrate which coated with W{sub 2}N films or WBN films was superior to the uncoated substrate. • The corrosion resistance of the substrate which coated with W{sub 2}N films was improved slightly by doping some boron content and the corrosion mechanism was discussed in the view of structure. - Abstract: WBN composite films with various boron contents ranging from 25.1 at.% to 46.5 at.% were deposited by a multi-target magnetron sputtering system. The microstructure, mechanical, tribological and corrosion behavior of films were studied using XRD, SEM, FTIR, HRTEM, nano-indentation, Ball-on-disc dry sliding wear tester, Bruker 3D Profiler and compared to W{sub 2}N. All the films exhibited face-centred cubic (fcc) structure W{sub 2}N; bcc α-W phases appeared as the B content was 25.1 at.% and amorphous BN appeared as the B content was 31.9 at.%. The hardness and compressive stress of WBN films first increased and then decreased with increasing the B content. As the B content was 38.1 at.%, they reached the maximum values of 36.1 GPa and 2.6 GPa, respectively. The best wear resistance at room and elevated temperature was found for the film which was shown to exhibit the highest hardness and compressive stress. The corrosion resistance of the substrate which coated with W{sub 2}N films or WBN films was superior to the uncoated substrate. The corrosion resistance of the substrate which coated with W{sub 2}N films was improved slightly by doping some boron content.

  9. Electrical, Corrosion, and Mechanical Properties of Aluminum-Copper Joints Produced by Explosive Welding

    Science.gov (United States)

    Acarer, Mustafa

    2012-11-01

    This study investigates the microstructure, electrical, corrosion, and mechanical properties of plate-shaped aluminum-copper couple produced using the explosive welding method. Mechanical tests, including hardness, tensile, tensile-shear, and impact test, concluded that the Al-Cu bimetal had an acceptable joint resistance. In this study, local intermetallic regions formed on the interface of the joint of the aluminum-copper bimetal, produced using the explosive welding technique. However, the formed intermetallic regions had no significant effect on the mechanical properties of the joint, except for increasing its hardness. According to electrical conductivity tests, the Al-Cu bimetal had an average electrical conductivity in comparison to the electrical conductivity of aluminum and copper, which were the original materials forming the joint. According to the results of electro-chemical corrosion test, during which galvanic corrosion formed, the Al side of the Al-Cu bimetal was more anodic due to its high electronegativity; as a result, it was exposed to more corrosion in comparison to the copper side.

  10. Mechanical properties and corrosion resistance of hot extruded Mg–2.5Zn–1Ca alloy

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Dexue, E-mail: dexeliu@hotmail.com [State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals, Lanzhou University of Technology, Lanzhou 730050 (China); Department of Mechanical and Aerospace Engineering, University of California, San Diego, CA 92093-0411 (United States); Guo, Chenggong; Chai, Liqiang [State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals, Lanzhou University of Technology, Lanzhou 730050 (China); Sherman, Vincent R. [Department of Mechanical and Aerospace Engineering, University of California, San Diego, CA 92093-0411 (United States); Qin, Xiaoqiong; Ding, Yutian [State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals, Lanzhou University of Technology, Lanzhou 730050 (China); Meyers, Marc A. [Department of Mechanical and Aerospace Engineering, University of California, San Diego, CA 92093-0411 (United States)

    2015-05-15

    Highlights: • MgZnCa alloy was extruded into precise microtube for resorbable stent applications. • Interconnection between micro-structure and corrosion properties was revealed. • Both strength and ductility were simultaneously improved by processing sequence. • Better corrosion resistance in PBS solution was achieved after grain refining. - Abstract: It is demonstrated that the mechanical properties and corrosion resistance of Mg–2.5 wt%Zn–1 wt%Ca alloy are enhanced by the microstructural changes imparted by hot extrusion. A processing procedure is developed to form hollow tubes with an outer diameter of ∼2.0 mm and wall thickness of ∼0.1 mm, which is well suited for subsequent stent manufacturing. The influence of thermal and mechanical processing on corrosion and plasticity was found to be associated with grain-size reduction and the redistribution of intermetallic particles within the microstructure, providing significant improvement of performance over the cast alloy. Observation of the fracture surfaces reveals a mode transition from brittle (cast) to ductile (processed). Enhanced mechanical properties and decreased resorption rate represent significantly improved performance of this alloy after the novel processing sequence. Based on the improved properties, the produced Mg alloy is more suitable for practical in vivo applications.

  11. Influence of silicon addition on the mechanical properties and corrosion resistance of low-alloy steel

    Indian Academy of Sciences (India)

    M Hebda; H Dębecka; J Kazior

    2015-12-01

    The addition of silicon to low-alloy steel allows to modify the materials' microstructure and thus to improve their corrosion resistance and mechanical properties. The influence of adding different amounts of silicon on the properties (density, transverse rupture strength, microhardness and corrosion resistance) and microstructure of low-alloy steel was investigated. Samples were prepared via the mechanical alloying process, which is the most useful method to homogeneously introduce silicon to low-alloy steel. Sintering was performed by using the spark plasma sintering (SPS) technique. After the SPS process, half of each of the obtained samples was heat-treated in a vacuum furnace. The results show that high-density materials were achieved, and a homogeneous and fine microstructure was obtained. The investigated compositions containing 1 wt% of silicon had better corrosion resistance than samples with 3 wt% of silicon addition. Furthermore, corrosion resistance as well as the mechanical and plastic properties of the samples with 1 wt% of silicon can be further improved by applying heat treatment.

  12. Polymer concrete composites for the production of high strength pipe and linings in high temperature corrosive environments

    Science.gov (United States)

    Zeldin, A.; Carciello, N.; Fontana, J.; Kukacka, L.

    High temperature corrosive resistant, non-aqueous polymer concrete composites are described. They comprise about 12 to 20% by weight of a water-insoluble polymer binder polymerized in situ from a liquid monomer mixture consisting essentially of about 40 to 70% by weight of styrene, about 25 to 45% by weight acrylonitrile and about 2.5 to 7.5% by weight acrylamide or methacrylamide and about 1 to 10% by weight of a crosslinking agent. This agent is selected from the group consisting of trimethylolpropane trimethacrylate and divinyl benzene; and about 80 to 88% by weight of an inert inorganic filler system containing silica sand and portland cement, and optionally Fe/sub 2/O/sub 3/ or carbon black or mica. A free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide, other organic peroxides and combinations thereof to initiate crosspolymerization of the monomer mixture in the presence of said inorganic filler.

  13. Initial phase hot corrosion mechanism of gas tunnel type plasma sprayed thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Yugeswaran, S. [Joining and Welding Research Institute, Osaka University, Osaka 567-0047 (Japan); Kobayashi, A., E-mail: kobayasi@jwri.osaka-u.ac.jp [Joining and Welding Research Institute, Osaka University, Osaka 567-0047 (Japan); Ananthapadmanabhan, P.V. [L and PT Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)

    2012-04-25

    Highlights: Black-Right-Pointing-Pointer Free standing TBC specimens were prepared by gas tunnel type plasma spraying with thickness of around 300-400 {mu}m. Black-Right-Pointing-Pointer 50%8YSZ + 50%La{sub 2}Zr{sub 2}O{sub 7} composite coating shows superior hot corrosion resistance. Black-Right-Pointing-Pointer Corrosive crystals structure and phase transformation was well controlled in this coating. - Abstract: The hot corrosion resistance of the top layer in TBC is one of the main constructive factors which determines the lifetime of the coatings under critical operating environments. In the present study, 8 wt% yttria stabilized zirconia (8YSZ), lanthanum zirconate (La{sub 2}Zr{sub 2}O{sub 7}) and equal weight percentage of its composite (50%8YSZ + 50% La{sub 2}Zr{sub 2}O{sub 7}) coatings were prepared by using gas tunnel type plasma spray torch at optimum spraying conditions. The hot corrosion performances of the above thermal barrier coatings were examined against 40 wt%V{sub 2}O{sub 5}-60 wt%Na{sub 2}SO{sub 4} corrosive ash at 1173 K for 5 h in open air atmosphere. After hot-corrosion testing, the coating surface was studied using a scanning electron microscope to observe the microstructure and X-ray diffraction techniques were used to identify the phase compositions. The results showed that LaVO{sub 4} and YVO{sub 4} are the main hot corrosion products along with the ZrO{sub 2} phase transformation from tetragonal to monoclinic phases in La{sub 2}Zr{sub 2}O{sub 7} and 8YSZ coatings respectively. The microstructure and phase formation mechanism of the hot corrosion products varied with each coating and among these, composition of 50%8YSZ + 50%La{sub 2}Zr{sub 2}O{sub 7} coating exhibited least degradation against V{sub 2}O{sub 5}-Na{sub 2}SO{sub 4} corrosive environment compared to the other coatings.

  14. Corrosion analysis of TP304L pipe used for ultra-supercritical boiler%超(超)临界火电机组用关键钢管TP304L腐蚀现象分析

    Institute of Scientific and Technical Information of China (English)

    李丹; 李冬升; 戴起勋; 王荣荣; 王国建; 刘瑜

    2013-01-01

    利用JSM-7001F扫描电子显微镜、Inca Energy350 X射线能谱仪等测试设备,对不合格的超(超)临界火电机组用TP304L钢管进行分析.结果表明,不合格的TP304L钢管内表面发生一定深度的腐蚀和沿晶腐蚀开裂.显微组织分析发现,管内表面晶界析出较多碳化物,而外表面很少,管心部组织也有少量碳化物.研究分析认为,出现沿晶腐蚀开裂和析出碳化物是由于在拉拔过程中发生高温快速渗碳的结果.%The unqualified TP304L pipes applied to ultra-supercritical thermal power units were analyzed by the JSM-7001F scanning electron microscope, Inca Energy350X energy spectrometer, etc. It is found a certain depth of corrosion occurred on the inside surface of the unqualified TP304L pipes in form of intergranular corrosion cracking. Microstructure analysis shows that there are more carbides precipitated at the grain boundaries on the inner surface of the pipes, and fewer on the outer surface or in the center of the pipes. It is considered that the intergranular corrosion cracking and carbide precipitation are due to high temperature and rapid carburizing during production.

  15. Mechanical, Spectroscopic and Micro-structural Characterization of Banana Particulate Reinforced PVC Composite as Piping Material

    Directory of Open Access Journals (Sweden)

    B. Dan-asabe

    2016-06-01

    Full Text Available A banana particulate reinforced polyvinyl chloride (PVC composite was developed with considerabley low cost materials having an overall light-weight and good mechanical properties for potential application as piping material. The specimen composite material was produced with the banana (stem particulate as reinforcement using compression molding. Results showed that density and elastic Modulus of the composite decreases and increases respectively with increasing weight fraction of the particulate reinforcement. The tensile strength increased to a maximum of 42 MPa and then decreased steadily. The composition with optimum mechanical property (42 MPa was determined at 8, 62 and 30 % formulation of banana stem particulates (reinforcement, PVC (matrix and Kankara clay (filler respectively with corresponding percentage water absorption of 0.79 %, Young’s Modulus of 1.3 GPa, flexural strength of 92 MPa and density of 1.24 g/cm3. Fourier Transform Infrared (FTIR analysis of the constituents showed identical bands within the range 4000–1000 cm-1 with renown research work. Scanning Electron Microscopy (SEM result showed fairly uniform distribution of constituents’ phases. X-Ray Fluorescence (XRF confirms the X-ray diffraction (XRD result of the presence of minerals of kaolinite, quartz, rutile and illite in the kaolin clay. Comparison with conventional piping materials showed the composite offered a price savings per meter length of 84 % and 25 % when compared with carbon steel and PVC material.

  16. Comparison of Mechanical Properties Between PE80 and PE100 Pipe Materials

    Science.gov (United States)

    Zhang, Yi; Jar, P.-Y. Ben

    2016-10-01

    Mechanical properties, including yield stress, relaxation behavior, moduli (elastic modulus at the strain of 0.5% and strain hardening modulus at strains above 70%), viscous stress, and quasi-static stress, are compared between polyethylene (PE) pipes that are made of PE80 and PE100 resins. The mechanical properties are measured using D-split tensile test on modified notched pipe ring specimens. The comparison includes the influence of strain rate (by the change of crosshead speed) on the yield strength and influence of pre-strain on the relaxation behavior and the modulus values. A two-stage approach is used to characterize the influence of pre-strain on the moduli, to ensure that viscous recovery from the first-stage of the test, to introduce the pre-strain, does not affect the modulus measurement from the second-stage test. The results show that elastic modulus, yield stress, strain hardening modulus, viscous stress, and quasi-static stress for PE100 are higher than those for PE80, but PE80 shows higher resistance to stress relaxation. The results also show that with the increase in the pre-strain level, the elastic modulus drops but the strain hardening modulus remains relatively constant.

  17. Mechanical and corrosion properties of biodegradable Mg-1.5Mn-1Ca-xSr alloys

    Science.gov (United States)

    Sun, X.; Sun, S. Y.; Ning, Y. H.; Ning, Y. T.

    2017-03-01

    The mechanical properties and corrosion mechanism of both as-cast and solution-naturally age (T4) treated Mg-1.5Mn-1Ca-xSr alloys were investigated. The results showed that Sr is helpful to decrease grain size and increase the strength. The corrosion process of alloys was mainly determined by the quantity and distribution of second phases. Mg17Sr2, α-Mn and Ca-Sr phases acted as cathodes accelerated the corrosion of Mg2Ca anodic phase and α-Mg matrix. However, continuous distributed Mg17Sr2 was beneficial to resist the happening of localized corrosion because of its barrier effect. T4 treatment could significantly improve the mechanical properties and corrosion resistance of Mg alloys because of the dissolution of Mg2Ca phase and the dispersive distribution of Mg17Sr2 and α-Mn phases.

  18. Effect of aging on mechanical properties and localized corrosion behaviors of Al-Cu-Li alloy

    Institute of Scientific and Technical Information of China (English)

    JIANG Na; LI Jin-feng; ZHENG Zi-qiao; WEI Xiu-yu; LI Yan-fen

    2005-01-01

    The effects of aging on mechanical properties,intergranular corrosion and exfoliation corrosion behaviors of a 2197 type A1-Li alloy were investigated,and the mechanisms were studied through microstructure observation and electrochemical measurement of simulated bulk phase.The main strengthening precipitates of the alloy aged at175 ℃ and 160 ℃ are δ' and T1.T1 precipitation in the alloy aged at 160 ℃ is delayed,which results in its slower age strengthening and over-aging behavior than the alloy aged at 175 ℃.Meanwhile,aging temperature of 160 ℃causes more uniform distribution and finer size of T1,resulting in its better strengthening effect.As aging time and aging temperature are increased,the size of T1 at grain boundaries and the width of PFZ along grain boundaries are increased,leading to an increase in the susceptibility to intergranular corrosion and exfoliation corrosion.It is suggested that better comprehensive properties can be obtained when the alloy is aged at 160 ℃.

  19. Microstructural, mechanical, corrosion and cytotoxicity characterization of the hot forged FeMn30(wt.%) alloy.

    Science.gov (United States)

    Čapek, Jaroslav; Kubásek, Jiří; Vojtěch, Dalibor; Jablonská, Eva; Lipov, Jan; Ruml, Tomáš

    2016-01-01

    An interest in biodegradable metallic materials has been increasing in the last two decades. Besides magnesium based materials, iron-manganese alloys have been considered as possible candidates for fabrication of biodegradable stents and orthopedic implants. In this study, we prepared a hot forged FeMn30 (wt.%) alloy and investigated its microstructural, mechanical and corrosion characteristics as well as cytotoxicity towards mouse L 929 fibroblasts. The obtained results were compared with those of iron. The FeMn30 alloy was composed of antiferromagnetic γ-austenite and ε-martensite phases and possessed better mechanical properties than iron and even that of 316 L steel. The potentiodynamic measurements in simulated body fluids showed that alloying with manganese lowered the free corrosion potential and enhanced the corrosion rate, compared to iron. On the other hand, the corrosion rate of FeMn30 obtained by a semi-static immersion test was significantly lower than that of iron, most likely due to a higher degree of alkalization in sample surrounding. The presence of manganese in the alloy slightly enhanced toxicity towards the L 929 cells; however, the toxicity did not exceed the allowed limit and FeMn30 alloy fulfilled the requirements of the ISO 10993-5 standard.

  20. B Plant process piping replacement feasibility study

    Energy Technology Data Exchange (ETDEWEB)

    Howden, G.F.

    1996-02-07

    Reports on the feasibility of replacing existing embedded process piping with new more corrosion resistant piping between cells and between cells and a hot pipe trench of a Hanford Site style canyon facility. Provides concepts for replacement piping installation, and use of robotics to replace the use of the canyon crane as the primary means of performing/supporting facility modifications (eg, cell lining, pipe replacement, equipment reinstallation) and operational maintenenace.

  1. Inspection of thin-walled pipe welds using mechanized ultrasonic techniques

    Energy Technology Data Exchange (ETDEWEB)

    Lozev, M.; Spencer, R. [Edison Welding Inst., Columbus, OH (United States); Hodgkinson, D. [TransCanada PipeLines Ltd., Calgary, AB (Canada)

    2004-07-01

    This paper investigated applications of high-frequency single/multiprobe techniques and phased-array (PA) technology for the inspection of thin-walled pipes welds. Ultrasonic testing (UT), modeling and simulation was used as an effective way of determining that the desired calibration reflectors and flaws in thin-walled pipes can be accurately sized. A laboratory experiment was conducted in which simple or complex flaws were virtually split on several segments. Beam profile monitoring and automated ultrasonic testing was performed for non-focused 5, 10 and 15 MHz single elements, a variety of focused MHz elements, and a 10 MHz 32 element linear PA probe. A Mephisto model was used to examine the various echo-formation mechanisms. Beam interactions and connected planar flaws were examined. Two calibration targets were used: (1) a 1.5 mm diameter side-drilled hole; and (2) a 4 per cent deep notch. A thin-walled pipe sample was designed for the validation of modeling results. A commercially available PA system and computer software program was used to create focal laws, as well as to steer the beam, collect data, and perform the analysis. Results of the notch tilt models showed that inspection angles of approximately 58 to 68 degrees were the least sensitive to tilt. Signal amplitude losses of less than 10 decibels were observed when compared with the reference notch. The PA model for complex flaws showed that signal loss arising from tilt and skew stabilized at approximately 10 degrees due to a loss of amplitude. Larger sound beams resulted in a greater echo-dynamic that increased masking effects. It was concluded that the most accurate UT simulations were achieved using a 10 MHz, 32-element linear PA technology. 4 refs., 2 tabs., 8 figs.

  2. Research on a New Bilateral Self-locking Mechanism for an Inchworm Micro In-pipe Robot with Large Traction

    Directory of Open Access Journals (Sweden)

    Junhong Yang

    2014-10-01

    Full Text Available In this paper, we present an innovative bilaterally-controllable self-locking mechanism that can be applied to the micro in-pipe robot. The background and state of the art of the inchworm micro in-pipe robot is briefly described in the very beginning of the paper, where the main factors that influence the traction ability are also discussed. Afterwards, the micro in-pipe robots’ propulsion principle based on a unidirectional self- locking mechanism is discussed. Then, several kinds of self-locking mechanisms are compared, and a new bilaterally-controllable self-locking mechanism is proposed. By implementing the self-locking mechanism, the robot’s tractive force is no longer restricted by the friction force, and both two-way motion and position locking for the robot can be achieved. Finally, the traction experiment is conducted using a prototype robot with the new bilaterally-controllable self-locking mechanism. Test results show that this new self-locking mechanism can adapt itself to a diameter of Φ17~Φ20 mm and has a blocking force up to 25N, and the maximum tractive force of the in-pipe robot based on such a locking mechanism is 12N under the maximum velocity of 10mm/s.

  3. Research on a New Bilateral Self-locking Mechanism for an Inchworm Micro In-pipe Robot with Large Traction

    Directory of Open Access Journals (Sweden)

    Junhong Yang

    2014-10-01

    Full Text Available In this paper, we present an innovative bilaterally-controllable self-locking mechanism that can be applied to the micro in-pipe robot. The background and state of the art of the inchworm micro in-pipe robot is briefly described in the very beginning of the paper, where the main factors that influence the traction ability are also discussed. Afterwards, the micro in-pipe robots’ propulsion principle based on a unidirectional self-locking mechanism is discussed. Then, several kinds of self-locking mechanisms are compared, and a new bilaterally-controllable self-locking mechanism is proposed. By implementing the self-locking mechanism, the robot's tractive force is no longer restricted by the friction force, and both two-way motion and position locking for the robot can be achieved. Finally, the traction experiment is conducted using a prototype robot with the new bilaterally-controllable self-locking mechanism. Test results show that this new self-locking mechanism can adapt itself to a diameter of >17~>20 mm and has a blocking force up to 25N, and the maximum tractive force of the in-pipe robot based on such a locking mechanism is 12N under the maximum velocity of 10mm/s.

  4. IntegralitU Assessment for Corrosion Defects in Hot-bend Pipe for Natural Gas Transmission Pipelines%天然气输送管道热弯钢管腐蚀缺陷的完整性评价

    Institute of Scientific and Technical Information of China (English)

    张忠秀; 安立芬; 陶爱莲; 陈利华

    2011-01-01

    为了评价天然气输送管道热弯钢管腐蚀缺陷的完整性,分别对热弯钢管及含腐蚀热弯钢管进行了有限元分析(FEA).对热弯钢管有限元分析的结果表明,应变在拉伸区域轴向为正值,在压缩区域轴向为负值,而径向应变分布却与此相反,且钢管的壁厚和应变与弯曲角无关.通过对不同壁厚、平均壁厚、含对称腐蚀缺陷以及含非对称腐蚀缺陷热弯钢管爆破压力的预测及对比,得出了将弯曲系数和平均壁厚引入用于直钢管完整性评价的 PCORRC方程,可以合理预测出有腐蚀缺陷热弯钢管的爆破压力的结论.%In order to assess integrality of hot-bend pipe corrosion defects for natural gas transmission pipeline, finite element analysis (FEA) was separately performed to hot-bend pipe and corrosive hot-bend pipe. The results showed that strain value is positive in axial tensile area,it is negative in axial compress area,while longitudinal strain distribution is in contrast, and thickness is not relevant to strain and bending angle. Through prediction and contrast to 4 kinds of bursting pressure of hot-bend pipe, different thickness, average thickness, symmetry corrosive defects and asymmetry corrosive defects, it can obtain PCORIRC equation which applied bend coefficient and average wall thickness to straight steel pipe structural integrity assessment, and can get bursting pressure through reasonable prediction.

  5. New Mechanism on Synergistic Effect of Nitrite and Triethanolamine Addition on the Corrosion of Ductile Cast Iron

    Directory of Open Access Journals (Sweden)

    K. T. Kim

    2016-01-01

    Full Text Available In general, we compared the different inhibition mechanisms of organic inhibitor with that of anodic inhibitor. When triethanolamine or nitrite was added separately to tap water for inhibiting the corrosion of ductile cast iron, large amounts of inhibitor were needed. This is because the corrosion inhibitors had to overcome the galvanic corrosion that occurs between graphite and matrix. In this work, we investigated the corrosion of ductile cast iron in tap water with/without inhibitors. The corrosion rate was measured using chemical immersion test and electrochemical methods, including anodic polarization test. The inhibited surface was analyzed using EPMA and XPS. Test solutions were analyzed by performing FT-IR measurement. When triethanolamine and nitrite coexisted in tap water, synergistic effect built up, and the inhibition effect was ca. 30 times more effective than witnessed with single addition. This work focused on the synergistic effect brought about by nitrite and triethanolamine and its novel mechanism was also proposed.

  6. Simulation of Deposition the Corrosion Waste in a Water Distribution System

    Directory of Open Access Journals (Sweden)

    Peráčková Jana

    2013-04-01

    Full Text Available In water distribution systems can be found particles of rust and other mechanical contaminants. The particles are deposited in locations where the low velocity of water flow. Where a can cause the pitting corrosion. Is a concern in the systems made of galvanized steel pipes. The contribution deals with CFD (Computational Fluid Dynamics simulations of water flow and particles deposition in water distribution system. CFD Simulations were compared with the corrosive deposits in real pipeline. Corrosion is a spontaneous process of destruction of metal material due to electrochemical reactions of metal with the aggressive surrounding. Electrochemical corrosion is caused by the thermodynamic instability of metal and therefore can not be completely suppress, it can only influence the speed of corrosion. The requirement is to keep metal properties during the whole its lifetime. Requested service lifetime the water pipe according to EN 806-2 is 50 years.

  7. Electrofusion joining of polyethylene gas pipes: Evaluation of pipe preparation, joining conditions and mechanical performance. Final report, 1990-1995

    Energy Technology Data Exchange (ETDEWEB)

    Grigory, S.C.; Maguire, J.F.; Deviney, M.L.

    1996-04-01

    There were three specific objectives of this research. First, a short time acceptance test for EF (electrofusion) fittings that is fundamentally related to the long time field performance was to be developed that would permit the use of existing lifetime forecasting procedures to quantify joint lifetimes. The second objective was to determine the effects of the various design and installation variables such as power input, heating time, cool-down time, initial pipe-coupler clearance and ambient temperature on the service performance. The third objective was to investigate and quantify the effects of surface preparation and cleanliness on joint integrity. Four final reports have been published to cover the diversified technology developed in this research.

  8. Effect of Heat Treatment on Mechanical Properties and Corrosion Performance of Cold-Sprayed Tantalum Coatings

    Science.gov (United States)

    Kumar, S.; Vidyasagar, V.; Jyothirmayi, A.; Joshi, S. V.

    2016-04-01

    The cold-spray technique is of significant interest to deposit refractory metals with relatively high melting point for a variety of demanding applications. In the present study, mechanical properties of cold-sprayed tantalum coatings heat treated at different temperatures were investigated using microtensile testing, scratch testing, and nanoindentation. The corrosion performance of heat-treated coatings was also evaluated in 1 M KOH solution, and potentiodynamic polarization as well as impedance spectroscopy studies were carried out. Assessment of structure-property correlations was attempted based on microstructure, porosity, and intersplat bonding state, together with mechanical and corrosion properties of the heat-treated cold-sprayed tantalum coatings. Coatings annealed at 1500 °C, which is very close to the recrystallization temperature of tantalum, were found to perform almost as bulk tantalum, with exciting implications for various applications.

  9. Corrosion mechanism of 13Cr stainless steel in completion fluid of high temperature and high concentration bromine salt

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yan [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083 (China); Xu, Lining, E-mail: xulining@ustb.edu.cn [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083 (China); Lu, Minxu [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083 (China); Meng, Yao [Beijing Institute of Aeronautical Materials, Beijing 100095 (China); Zhu, Jinyang; Zhang, Lei [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083 (China)

    2014-09-30

    Highlights: • The corrosion behavior of 13Cr steel exposed to bromine salt completion fluid containing high concentration bromine ions was investigated. • There are passive circles around pits on the 13Cr steel surface after 7 d of exposure. • Macroscopic galvanic corrosion formed between the passive halo and the pit. • The mechanism of pitting corrosion on 13Cr stainless steel exposed to heavy bromine brine was established. - Abstract: A series of corrosion tests of 13Cr stainless steel were conducted in a simulated completion fluid environment of high temperature and high concentration bromine salt. Corrosion behavior of specimens and the component of corrosion products were investigated by means of scanning electron microscope (SEM), confocal laser scanning microscopy (CLSM) and X-ray photoelectron spectroscopy (XPS). The results indicate that 13Cr steel suffers from severe local corrosion and there is always a passive halo around every pit. The formation mechanism of the passive halo is established. OH{sup −} ligand generates and adsorbs in a certain scale because of abundant OH{sup −} on the surface around the pits. Passive film forms around each pit, which leads to the occurrence of passivation in a certain region. Finally, the dissimilarities in properties and morphologies of regions, namely the pit and its corresponding passive halo, can result in different corrosion sensitivities and may promote the formation of macroscopic galvanic pairs.

  10. Mechanical and corrosion resistance properties of TiO2 nanoparticles reinforced Ni coating by electrodeposition

    Science.gov (United States)

    Shao, W.; Nabb, D.; Renevier, N.; Sherrington, I.; Luo, J. K.

    2012-09-01

    Coatings have been widely used in engineering and decoration to protect components and products and enhance their life span. Nickel (Ni) is one of the most important hard coatings. Improvement in its tribological and mechanical properties would greatly enhance its use in industry. Nanocomposite coatings of metals with various reinforced nanoparticles have been developed in last few decades. Titania (TiO2) exhibit excellent mechanical properties. It is believed that TiO2 incorporation in Ni matrix will improve the properties of Ni coatings significantly. The main purpose of the current work is to investigate the mechanical and anti-corrosion properties of the electroplated nickel nanocomposite with a small percentage of TiO2. The surface morphology of nanocomposite coating was characterized by scanning electron microscopy (SEM). The hardness of the nanocoating was carried out using micromaterials nanoplatform. The sliding wear rate of the coating at room temperature in dry condition was assessed by a reciprocating ball-on-disk computer-controlled oscillating tribotester. The results showed the nanocomposite coatings have a smoother and more compact surface than the pure Ni layer and have higher hardness and lower wear rate than the pure Ni coating. The anti-corrosion property of nanocomposite coating was carried out in 3.5% NaCl and high concentrated 35% NaCl solution, respectively. The results also showed that the nanocomposite coating improves the corrosion resistance significantly. This present work reveals that incorporation of TiO2 in nickel nanocomposite coating can achieve improved corrosion resistance and mechanical properties of both hardness and wear resistance performances, and the improvement becomes stronger as the content of TiO2 is increased.

  11. On The Physico-Mechanics, Thermal and Microstructure Properties of Hybrid Composite Epoxy-Geopolymer for Geothermal Pipe Application

    Directory of Open Access Journals (Sweden)

    Firawati Ira

    2017-01-01

    Full Text Available The objective of this study is to determine the effect of epoxy resin on the physico-mechanics, thermal and microstructure properties of geopolymers hybrid composites for geothermal pipe application. Hybrid composite epoxy-geopolymers pipes were produced through alkali activation method of class-C fly ash and epoxy resin. The mass of epoxy-resin was varied relative to the mass of fly ash namely 0% (SPG01, 5% (SPG02, 10% (SPG03, 15% (SPG04, and 20% (SPG05. The resulting materials were stored in open air for 28 days before conducting any measurements. The densities of the product composites were measured before and after the samples immersed in boiling water for 3 hours. The mechanical strength of the resulting geothermal pipes was measured by using splitting tensile measurement. The thermal properties of the pipes were measured by means of thermal conductivity measurement, differential scanning calorimetry (DSC and fire resistance measurements. The chemical resistance was measured by immersing the samples into 1M H2SO4 solution for 4 days. The microstructure properties of the resulting materials were examined by using x-ray diffraction (XRD and Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS. The results of this study showed that hybrid composite epoxy-geopolymers SPG02 and SPG03 are suitable to be applied as geothermal pipes.

  12. Thermo-Mechanical Analysis of a Single-Pass Weld Overlay and Girth Welding in Lined Pipe

    Science.gov (United States)

    Obeid, Obeid; Alfano, Giulio; Bahai, Hamid

    2017-08-01

    The paper presents a nonlinear heat-transfer and mechanical finite-element (FE) analyses of a two-pass welding process of two segments of lined pipe made of a SUS304 stainless steel liner and a C-Mn steel pipe. The two passes consist of the single-pass overlay welding (inner lap weld) of the liner with the C-Mn steel pipe for each segment and the single-pass girth welding (outer butt weld) of the two segments. A distributed power density of the moving welding torch and a nonlinear heat-transfer coefficient accounting for both radiation and convection have been used in the analysis and implemented in user subroutines for the FE code ABAQUS. The modeling procedure has been validated against previously published experimental results for stainless steel and carbon steel welding separately. The model has been then used to determine the isotherms induced by the weld overlay and the girth welding and to clarify their influence on the transient temperature field and residual stress in the lined pipe. Furthermore, the influence of the cooling time between weld overlay and girth welding and of the welding speed have been examined thermally and mechanically as they are key factors that can affect the quality of lined pipe welding.

  13. Thermo-Mechanical Analysis of a Single-Pass Weld Overlay and Girth Welding in Lined Pipe

    Science.gov (United States)

    Obeid, Obeid; Alfano, Giulio; Bahai, Hamid

    2017-07-01

    The paper presents a nonlinear heat-transfer and mechanical finite-element (FE) analyses of a two-pass welding process of two segments of lined pipe made of a SUS304 stainless steel liner and a C-Mn steel pipe. The two passes consist of the single-pass overlay welding (inner lap weld) of the liner with the C-Mn steel pipe for each segment and the single-pass girth welding (outer butt weld) of the two segments. A distributed power density of the moving welding torch and a nonlinear heat-transfer coefficient accounting for both radiation and convection have been used in the analysis and implemented in user subroutines for the FE code ABAQUS. The modeling procedure has been validated against previously published experimental results for stainless steel and carbon steel welding separately. The model has been then used to determine the isotherms induced by the weld overlay and the girth welding and to clarify their influence on the transient temperature field and residual stress in the lined pipe. Furthermore, the influence of the cooling time between weld overlay and girth welding and of the welding speed have been examined thermally and mechanically as they are key factors that can affect the quality of lined pipe welding.

  14. Pipe drafting and design

    CERN Document Server

    Parisher, Roy A; Parisher

    2000-01-01

    Pipe designers and drafters provide thousands of piping drawings used in the layout of industrial and other facilities. The layouts must comply with safety codes, government standards, client specifications, budget, and start-up date. Pipe Drafting and Design, Second Edition provides step-by-step instructions to walk pipe designers and drafters and students in Engineering Design Graphics and Engineering Technology through the creation of piping arrangement and isometric drawings using symbols for fittings, flanges, valves, and mechanical equipment. The book is appropriate primarily for pipe

  15. Potential corrosion and degradation mechanisms of Zircaloy cladding on spent nuclear fuel in a tuff repository

    Energy Technology Data Exchange (ETDEWEB)

    Rothman, A.J.

    1984-09-01

    A literature review and analysis were made of corrosion and degradation processes applicable to Zircaloy cladding on spent nuclear fuel in a tuff repository. In particular, lifetime sought for the Zircaloy is 10,000 years. Among the potential failure mechanisms examined were: oxidation by steam, air, and water, including the effects of ions whose presence is anticipated in the water; mechanical overload; stress (creep) rupture; stress-corrosion cracking (SCC); and delayed failure due to hydride cracking. The conclusion is that failure due to oxidation is not credible, although a few experiments are suggested to confirm the effect of aqueous fluoride on the Zircaloy cladding. Mechanical overload is not a problem, and failure from stress-rupture does not appear likely based on a modified Larson-Miller analysis. Analysis shows that delayed hydride cracking is not anticipated for the bulk of spent fuel pins. However, for a minority of pins under high stress, there is some uncertainty in the analysis as a result of: (1) uncertainty about crack depths in spent fuel claddings and (2) the effect of slow cooling on the formation of radially oriented hydride precipitates. Experimental resolution is called for. Finally, insufficient information is currently available on stress-corrosion cracking. While evidence is presented that SCC failure is not likely to occur, it is difficult to demonstrate this conclusively because the process is not clearly understood and data are limited. Further experimental work on SCC susceptibility is especially needed.

  16. Chromium-modified a-C films with advanced structural, mechanical and corrosive-resistant characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Ming, Miao Yi [International Chinese-Belarusian scientific laboratory on vacuum-plasma technology, Nanjing University of Science and Technology, Nanjing 210094 (China); Francisk Skorina Gomel State University, Gomel 246019 (Belarus); Jiang, Xiaohong, E-mail: jxh0668@sina.com [International Chinese-Belarusian scientific laboratory on vacuum-plasma technology, Nanjing University of Science and Technology, Nanjing 210094 (China); Francisk Skorina Gomel State University, Gomel 246019 (Belarus); Piliptsou, D.G., E-mail: pdg_@mail.ru [International Chinese-Belarusian scientific laboratory on vacuum-plasma technology, Nanjing University of Science and Technology, Nanjing 210094 (China); Francisk Skorina Gomel State University, Gomel 246019 (Belarus); Zhuang, Yuzhao; Rogachev, A.V.; Rudenkov, A.S. [International Chinese-Belarusian scientific laboratory on vacuum-plasma technology, Nanjing University of Science and Technology, Nanjing 210094 (China); Francisk Skorina Gomel State University, Gomel 246019 (Belarus); Balmakou, A. [Faculty of Material Science and Technology, Slovak University of Technology, Trnava 91724 (Slovakia)

    2016-08-30

    Highlights: • Influence of the chromium interlayer on the structure and mechanical properties of a-C:Cr films. • Residual stress and wear of a-C:Cr and Cr/a-C varies due to their phase and surface morphology. • Chromium-modified a-C films with advanced structural, mechanical and corrosive-resistant characteristics. - Abstract: To improve structural, mechanical and chemical properties of diamond-like carbon films, we developed amorphous carbon chromium-modified composite films fabricated by means of cathode magnetic filtered arc deposition. The properties were analyzed by Raman spectroscopy, X-ray photoelectron spectroscopy and atomic force microscopy for the purpose of the structure characterization, elemental analysis and topology examination. Moreover, we also assessed residual stress, the coefficient of friction, hardness, the elastic modulus and corrosion parameters through X-ray double-crystal surface profilometry, tribo-testing, nanoindenter-testing, as well as contact angle measurements and potentiodynamic polarization analysis. As a result of a comparative analysis, we revealed a substantial improvement in the characteristics of developed composite films in comparison with amorphous carbon films. For example, Cr-modification is resulted, in greater integrated performance, toughness and corrosion resistance; the residual stress was reduced substantially.

  17. Corrosion and mechanical properties of AM50 magnesium alloy after being modified by 1 wt.% rare earth element gadolinium

    Institute of Scientific and Technical Information of China (English)

    杨淼; 刘耀辉; 刘家安; 宋雨来

    2014-01-01

    In order to improve the corrosion and mechanical properties of AM50 magnesium alloy, 1 wt.% Gd was used to modify the AM50 magnesium alloy. The microstructure, corrosion and mechanical properties were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), electrochemical and mechanical stretch methods. The results indicated that β-Mg17Al12 phase decreased and Al2Gd3 and Al0.4GdMn1.6 phase existed after Gd addition. Because of the Gd addition, the grain of AM50 magnesium alloy was refined significantly, which improved the tensile strength of AM50 magnesium al-loy. The decreasing ofβ phase improved the corrosion resistance of the magnesium alloy. The fracture mechanism of the Gd modified AM50 magnesium alloy was quasi-cleavage fracture. The corrosion residual strength (CRS) of AM50 magnesium alloy was im-proved after 1 wt.% Gd addition.

  18. Voltammetric current oscillations due to general and pitting corrosion of tantalum: Implications for electrochemical-mechanical planarization

    Energy Technology Data Exchange (ETDEWEB)

    Sulyma, Christopher M. [Department of Physics, Clarkson University, Potsdam, NY 13699-5820 (United States); Roy, Dipankar, E-mail: samoy@clarkson.ed [Department of Physics, Clarkson University, Potsdam, NY 13699-5820 (United States)

    2010-09-15

    Anodic corrosion of Ta is examined for potential applications in electrochemical-mechanical planarization (ECMP) of diffusion barriers. This strategy involves electro-oxidation of Ta in the presence of NO{sub 3}{sup -} (or Br{sup -}) to form mechanically weak surface-oxide films, followed by mechanical removal of the latter. The voltammetric currents exhibit oscillatory behaviour with frequencies that are signature attributes of localised pitting by Br{sup -} or general surface corrosion by NO{sub 3}{sup -}. SEM, voltammetry, and impedance spectroscopy are used to probe these corrosion mechanisms. Apart from their relevance for ECMP, the results also address certain fundamental aspects of pitting and general corrosion of valve metals.

  19. Coupled phenomenological and fracture mechanics approach to assess the fracture behaviour of TWC piping component

    Energy Technology Data Exchange (ETDEWEB)

    Saxena, Sanjeev, E-mail: san_bpl@yahoo.co [Advanced Materials and Processes Research Institute (AMPRI), CSIR Concern, Hoshangabad Road, Bhopal 462026 (India); Ramakrishnan, N. [Advanced Materials and Processes Research Institute (AMPRI), CSIR Concern, Hoshangabad Road, Bhopal 462026 (India); Chouhan, J.S. [Civil Engineering Department, Samrat Ashok Technological Institute, Vidisha (India)

    2010-04-15

    The present study demonstrates the numerical prediction of experimental specimen J-R curve using Gurson-Tvergaard-Needleman phenomenologically based material model. The predicted specimen J-R curve is used to determine the geometric independent initiation fracture toughness (J{sub SZWc}) value that compares well with experimental result. Using the experimentally determined and numerically predicted J{sub SZWc} values and specimen J-R curves, the accuracy of predicting the fracture behaviour of the cracked component is judged. Thus the present study proposed a coupled phenomenological and fracture mechanics approach to predict the crack initiation and instability stages in cracked piping components using numerically predicted specimen J-R curve obtained from tensile specimens testing data.

  20. Mechanical and Corrosion Behaviour of Zn-27Al Based Composites Reinforced with Groundnut Shell Ash and Silicon Carbide

    OpenAIRE

    K.K. Alaneme; B.O. Fatile; J.O. Borode

    2014-01-01

    The mechanical and corrosion behaviour of Zn-27Al alloy based composites reinforced with groundnut shell ash and silicon carbide was investigated. Experimental test composite samples were prepared by melting Zn-27Al alloy with pre-determined proportions of groundnut ash and silicon carbide as reinforcements using double stir casting. Microstructural examination, mechanical properties and corrosion behaviour were used to characterize the composites produced. The results show that hardness and ...

  1. Effect of manganese on the microstructure, mechanical properties and corrosion behavior of titanium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ji-Woo; Hwang, Moon-Jin; Han, Mi-Kyung [Department of Dental Materials and MRC for Biomineralization Disorders, School of Dentistry, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Kim, Yong-Geun [Department of Ophthalmic Optics, Dongkang College, Gwangju 500-714 (Korea, Republic of); Song, Ho-Jun [Department of Dental Materials and MRC for Biomineralization Disorders, School of Dentistry, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Park, Yeong-Joon, E-mail: yjpark@jnu.ac.kr [Department of Dental Materials and MRC for Biomineralization Disorders, School of Dentistry, Chonnam National University, Gwangju 500-757 (Korea, Republic of)

    2016-09-01

    The phase/microstructure, mechanical properties and corrosion behavior of a series of binary Ti−Mn alloys with 5, 10, 15 and 20 wt% Mn were investigated in order to understand the effects of Mn content on mechanical properties, oxidation behavior, and electrochemical corrosion properties of Ti−Mn alloys. The phase/microstructure of Ti-xMn alloys was analyzed using X-ray diffractometry, scanning electron microscopy, and transmission electron microscopy. All examined properties of the Ti−Mn alloys were sensitive to the Mn content. The tested Ti-xMn alloys had α-Ti, β-Ti, and α-TiMn phases. Ti−Mn alloy containing 5 wt% Mn composed of α-Ti, β-Ti, α-TiMn, and isothermal ω phases. The proportion of α-Ti phase decreased and precipitation of β-Ti phase increased with increasing wt% of Mn. Cast Ti−Mn exhibited higher hardness and better oxidation protection than commercially pure Ti (cp-Ti). The tested Ti-xMn alloys showed better corrosion resistance than the cp-Ti. Ti−Mn alloy containing 5 wt% Mn had the highest hardness and lowest modulus, and is a good candidate for dental implant alloy. - Highlights: • Mechanical properties of Ti−Mn alloys were sensitive to the content of Mn. • As Mn content increased, α-Ti phase decreased and β-Ti phase increased. • Ti−Mn exhibited higher hardness and better oxidation protection ability. • Ti−Mn displayed superior corrosion resistance than commercially pure Ti. • Ti−Mn alloy with 5 wt% Mn is a good candidate for dental casting alloy.

  2. Corrosion mechanism of 13Cr stainless steel in completion fluid of high temperature and high concentration bromine salt

    Science.gov (United States)

    Liu, Yan; Xu, Lining; Lu, Minxu; Meng, Yao; Zhu, Jinyang; Zhang, Lei

    2014-09-01

    A series of corrosion tests of 13Cr stainless steel were conducted in a simulated completion fluid environment of high temperature and high concentration bromine salt. Corrosion behavior of specimens and the component of corrosion products were investigated by means of scanning electron microscope (SEM), confocal laser scanning microscopy (CLSM) and X-ray photoelectron spectroscopy (XPS). The results indicate that 13Cr steel suffers from severe local corrosion and there is always a passive halo around every pit. The formation mechanism of the passive halo is established. OH- ligand generates and adsorbs in a certain scale because of abundant OH- on the surface around the pits. Passive film forms around each pit, which leads to the occurrence of passivation in a certain region. Finally, the dissimilarities in properties and morphologies of regions, namely the pit and its corresponding passive halo, can result in different corrosion sensitivities and may promote the formation of macroscopic galvanic pairs

  3. 14 CFR 29.1123 - Exhaust piping.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Exhaust piping. 29.1123 Section 29.1123... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Exhaust System § 29.1123 Exhaust piping. (a) Exhaust piping must be heat and corrosion resistant, and must have provisions to prevent failure due to...

  4. Research on mechanisms of stress corrosion cracking in Zircaloy

    Energy Technology Data Exchange (ETDEWEB)

    Knorr, D.B.; Pelloux, R.M.

    1981-06-01

    The results of internal gas pressurization tests, primarily at 320/sup 0/C, on cladding tubes from two suppliers, Supplier A and Supplier B, are presented. The two lots show a substantial difference in iodine SCC susceptibility so a test matrix is used to resolve the relative contributions of surface condition, residual stress, and texture. Additional tests with constant deflection split-ring specimens and with unstressed cladding segments are used to understand crack initiation and the early crack growth stages of SCC. The difference in SCC susceptibility is due to crystallographic texture. Other variables such as surface finish, stress relief temperature, and residual stress have little or no effect. Mechanical properties, crack initiation, and crack propagation all depend on texture. Both initiation and propagation features are analyzed by scanning electron microscopy. A mechanism for crack initiation consistent with most observations in this study and with the work of other investigators is proposed. At 320/sup 0/C, lifetime is crack initiation limited while several tests at 390/sup 0/C indicate that lifetime is less initiation limited at higher temperature. 31 figures, 9 tables.

  5. Effect of natural aging on the microstructural regions, mechanical properties, corrosion resistance and fracture in welded joints on API5L X52 steel pipeline

    Energy Technology Data Exchange (ETDEWEB)

    Vargas-Arista, B.; Albiter, A.; Garcia-Vazquez, F.; Mendoza-Camargo, O.; Hallen, J. M.

    2014-07-01

    A characterization study was done to analyze how microstructural regions affect the mechanical properties, corrosion and fractography of the Heat Affected Zone (HAZ), weld bead and base metal for pipe naturally aged for 21 years at 30 degree centigrade. Results showed that microstructures exhibited damage and consequently decrease in properties, resulting in over-aged due to service. SEM analysis showed that base metal presented coarse ferrite grain. Tensile test indicated that microstructures showed discontinuous yield. Higher tensile strength was obtained for weld bead, which exhibited a lower impact energy in comparison to that of HAZ and base metal associated with brittle fracture by trans-granular cleavage. The degradation of properties was associated with the coarsening of nano-carbides observed through TEM images analysis, which was confirmed by SEM fractography of tensile and impact fracture surfaces. The weld bead reached the largest void density and highest susceptibility to corrosion in H{sub 2}S media when compared to those of the HAZ and base metal. (Author)

  6. Cluster analysis of stress corrosion mechanisms for steel wires used in bridge cables through acoustic emission particle swarm optimization.

    Science.gov (United States)

    Li, Dongsheng; Yang, Wei; Zhang, Wenyao

    2017-01-18

    Stress corrosion is the major failure type of bridge cable damage. The acoustic emission (AE) technique was applied to monitor the stress corrosion process of steel wires used in bridge cable structures. The damage evolution of stress corrosion in bridge cables was obtained according to the AE characteristic parameter figure. A particle swarm optimization cluster method was developed to determine the relationship between the AE signal and stress corrosion mechanisms. Results indicate that the main AE sources of stress corrosion in bridge cables included four types: passive film breakdown and detachment of the corrosion product, crack initiation, crack extension, and cable fracture. By analyzing different types of clustering data, the mean value of each damage pattern's AE characteristic parameters was determined. Different corrosion damage source AE waveforms and the peak frequency were extracted. AE particle swarm optimization cluster analysis based on principal component analysis was also proposed. This method can completely distinguish the four types of damage sources and simplifies the determination of the evolution process of corrosion damage and broken wire signals.

  7. Effect of Indium Content on the Microstructure, Mechanical Properties and Corrosion Behavior of Titanium Alloys

    Directory of Open Access Journals (Sweden)

    Mi-Kyung Han

    2015-05-01

    Full Text Available Ti-xIn (x = 0, 5, 10, 15 and 20 wt% alloys were prepared to investigate the effect of indium on the microstructure, mechanical properties, and corrosion behavior of titanium with the aim of understanding the relationship between phase/microstructure and various properties of Ti-xIn alloys. The Ti-xIn alloys exhibited a lamellar α-Ti structure at an indium content of up to 20 wt%. High-resolution TEM images of the Ti-xIn alloys revealed that all the systems contained a fine, acicular martensitic phase, which showed compositional fluctuations at the nanoscopic level. The mechanical properties and corrosion behavior of Ti-xIn alloys were sensitive to the indium content. The Vickers hardness increased as the In content increased because of solid solution strengthening. The Ti-xIn alloys exhibited superior oxidation resistance compared to commercially pure Ti (cp-Ti. Electrochemical results showed that the Ti-xIn alloys exhibited a similar corrosion resistance to cp-Ti. Among the alloys tested, Ti-10In showed a potential for use as a dental material.

  8. Corrosion and Nano-mechanical Behaviors of Magnetron Sputtered Al-Mo Gradient Coated Steel

    Science.gov (United States)

    Venugopal, A.; Srinath, J.; Ramesh Narayanan, P.; Sharma, S. C.; Venkitakrishnan, P. V.

    2016-11-01

    A gradient three-layer Al-Mo coating was deposited on steel using magnetron sputtering method. The corrosion and nano-mechanical properties of the coating were examined by electrochemical impedance spectroscopy and nano-indentation tests and compared with the conventional electroplated cadmium and IVD aluminum coatings. Electrochemical impedance spectroscopy was performed by immersing the coated specimens in 3.5% NaCl solution, and the impedance behavior was recorded as a function of immersion time. The mechanical properties (hardness and elastic modulus) were obtained from each indentation as a function of the penetration depth across the coating cross section. The adhesion resistance of the coatings was evaluated by scratch tests on the coated surface using nano-indentation method. The results show that the gradient Al-Mo coating exhibits better corrosion resistance than the other coatings in view of the better microstructure. The impedance results were modeled using appropriate electrical equivalent circuits for all the coated systems. The uniform, smooth and dense Al-Mo coating obtained by magnetron sputtering exhibits good adhesion with the steel substrate as per scratch test method. The poor corrosion resistance of the later coatings was shown to be due to the defects/cracks as well as the lesser adhesion of the coatings with steel. The hardness and elastic modulus of the Al-Mo coating are found to be high when compared to the other coatings.

  9. Mechanical and Corrosive Properties of Two Magnesium Wires: Mg4Gd and Mg6Ag

    Science.gov (United States)

    Maier, Petra; Szakács, Gabor; Wala, Marcin; Hort, Norbert

    The mechanical and corrosive properties of two Magnesium wires are studied in the field of microhardness, tension-, compression-and 3-point-bending tests, corrosion and its influence on the mechanical properties. Due to recrystallization during their complex forming processes (casting, extrusion, wire drawing), both wires show a fine grained microstructure resulting in high strength and ductility. However, the ductility is mostly evaluated by 3-point bending and compression; due to the notch effect in the clamp area, the maximum tensile strength and elongation under tension cannot be measured. Both alloys show a tensile-compressive yield asymmetry. Even RE-elements are known to reduce this asymmetry, the Mg-Gd alloy shows 100 MPa higher strength in tension than compression. The asymmetry of the Mg-Ag wire is similar. Overall the wires show very high strength and hardness, Mg6Ag slightly higher compared to Mg4Gd. Strong pitting corrosion is found and reduces strongly the tensile and bending strength.

  10. Illustration of alkali corrosion mechanisms in high temperature thermal insulation materials

    Energy Technology Data Exchange (ETDEWEB)

    Aneziris, C.G.; Fischer, U.; Schlegel, E. [Technical Univ. of Freiberg (Germany)

    2007-07-01

    Alkali attack is a chronic problem in the most popular high temperature applications such as blast furnaces, gasifiers, glass furnaces and cement kilns. Especially in the last years the problem of alkali corrosion is dramatically increased due to the waste burning and the combustion of the so called secondary fuels in kilns at high temperature processes. The German cement industry uses up to 100 percent of secondary fuels - a little or no coal, oil or gas- but mainly burnable waste. According to the literature destruction of the refractory can occur by the formation of low-melting low-viscosity liquids, or, more usually by the formation of dry expansive alkali-aluminosilicate compounds that result to chemical spalling. This work explores due to laboratory experiments supported partially by post mortem industrial trials the chemical interactions between alkali species and established refractory materials and illustrates four main alkali corrosion mechanisms. (orig.)

  11. Chromium-modified a-C films with advanced structural, mechanical and corrosive-resistant characteristics

    Science.gov (United States)

    Ming, Miao Yi; Jiang, Xiaohong; Piliptsou, D. G.; Zhuang, Yuzhao; Rogachev, A. V.; Rudenkov, A. S.; Balmakou, A.

    2016-08-01

    To improve structural, mechanical and chemical properties of diamond-like carbon films, we developed amorphous carbon chromium-modified composite films fabricated by means of cathode magnetic filtered arc deposition. The properties were analyzed by Raman spectroscopy, X-ray photoelectron spectroscopy and atomic force microscopy for the purpose of the structure characterization, elemental analysis and topology examination. Moreover, we also assessed residual stress, the coefficient of friction, hardness, the elastic modulus and corrosion parameters through X-ray double-crystal surface profilometry, tribo-testing, nanoindenter-testing, as well as contact angle measurements and potentiodynamic polarization analysis. As a result of a comparative analysis, we revealed a substantial improvement in the characteristics of developed composite films in comparison with amorphous carbon films. For example, Cr-modification is resulted, in greater integrated performance, toughness and corrosion resistance; the residual stress was reduced substantially.

  12. Mechanical properties and corrosion resistance of low rigidity quaternary titanium alloy for biomedical applications

    Institute of Scientific and Technical Information of China (English)

    Han-Cheol CHOE; Viswanathan S. SAJI; Yeong-Mu KO

    2009-01-01

    Electrochemical corrosion of Ti-35Nb-5Ta-7Zr alloy fabricated by arc melting and heat treatment process was studied in 0.9% NaCl at (37±1) ℃. Phase and microstructure of the fabricated alloy were investigated using X-ray diffractometer and scanning electron microscope. Mechanical properties such as yield strength and elastic modulus of the alloy were determined by tensile test. Potentiodynamic polarization technique and impedance spectroscopy were employed to study the corrosion behavior. The results of the study were compared with those obtained for Ti-6Al-4V commercial alloy. The result of the study supports feasibility of Ti-35Nb-5Ta-7Zr alloy for implant applications.

  13. Corrosive inorganic contamination on wafer surfaces after nickel-iron electroplating formation mechanisms and prevention

    Energy Technology Data Exchange (ETDEWEB)

    Kritzer, P. [Freudenberg Nonwovens KG, Technical Nonwovens Div., Weinheim (Germany); Diel, W.; Barber, P.H. [IBM Speichersysteme Deutschland GmbH, Mainz (Germany); Romankiw, L.T. [IBM Watson Research Center, Yorktown Heights, NY (United States)

    2001-11-01

    Electroplating of Nickel-Iron alloys is widely used in the production of magnetic heads for storage systems. Usually, the plating process is performed in acidic, salt-containing solutions. After the plating step, a complete removal of the plating salts is necessary to receive a clean surface. In disadvantageous cases, a precipitation of sticky particles is observed that cannot be removed from the plated surface without damaging the surface. Some of these substances (esp. nickel sulfates) might lead to severe local corrosion and thus might act as ''time-bomb'' in the later product. Non-corrosive precipitations (i.e. nickel hydroxides) strongly hinder or even prevent the following production steps. In the present paper, the mechanisms of the origin of the different kinds of precipitation are described and the principle actions for their prevention are given. An outlook is given for other possible technical applications. (orig.)

  14. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    Directory of Open Access Journals (Sweden)

    Prabhu Paulraj

    2015-08-01

    Full Text Available Duplex Stainless Steels (DSS and Super Duplex Stainless Steel (SDSS have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic phases and their effects on corrosion and mechanical properties. First the effect of various alloying elements on DSS and SDSS has been discussed followed by formation of various intermetallic phases. The intermetallic phases affect impact toughness and corrosion resistance significantly. Their deleterious effect on weldments has also been reviewed.

  15. The Impact of Corrosion on the Mechanical Behavior of Welded Splices of Reinforcing Steel S400 and B500c

    Science.gov (United States)

    Apostolopoulos, Ch. Alk.; Michalopoulos, D.; Dimitrov, L.

    2008-02-01

    The reinforcing steel, used in concrete structures, when corroded causes reduction of the strength properties and especially drastic reduction of ductility. Steel corrosion constitutes an important factor of progressive devaluation of its mechanical properties and serious reduction of the integrity of structures. The problem becomes more evident specifically for structures near coastal areas where salt corrosion is predominant. Reinforced concrete columns and beams are quite often extended by welding new steel reinforcement to the already corroded existing steel. In the present article the impact of corrosion on the mechanical properties of welded splices of reinforcing Steel S400 and B500c is examined. An experimental investigation was conducted and tensile and compressive results are presented for welded precorroded S400 and noncorroded B500c steel splices. The mechanical behavior of welded splices in tension are different in compression and depend strongly on the level of corrosion of the S400 bars.

  16. Structure and mechanical properties of the three-layer material based on a vanadium alloy and corrosion-resistant steel

    Science.gov (United States)

    Nikulin, S. A.; Rozhnov, A. B.; Nechaikina, T. A.; Rogachev, S. O.; Zavodchikov, S. Yu.; Khatkevich, V. M.

    2014-10-01

    The quality of three-layer pipes has been studied; they are manufactured by hot pressing of a three-layer assembly of tubular billets followed by forging and cold rolling. The operating core is made from a V-4Ti-4Cr alloy. The protective claddings are made from corrosion-resistant steels of two grades, 08Kh17T and 20Kh13. The results of investigation into the structure and microhardness of the junction zone of steel and the vanadium alloy, which includes a contact zone and a transition diffusion layer, are reported. The 08Kh17T steel is shown to be a preferred cladding material.

  17. Corrosion evaluation technology

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Uh Chul; Han, Jeong Ho; Nho, Kye Ho; Lee, Eun Hee; Kim, Hong Pyo; Hwang, Seong Sik; Lee, Deok Hyun; Hur, Do Haeng; Kim, Kyung Mo

    1997-09-01

    A multifrequency ACPD system was assembled which can measure very small crack. Stress corrosion cracking test system with SSRT operating high temperature was installed. Stress corrosion cracking test of newly developed alloy 600 and existing alloy 600 was carried out in steam atmosphere of 400 deg C. No crack was observed in both materials within a test period of 2,000 hrs. Corrosion fatigue test system operating at high temperature was installed in which fatigue crack was measured by CDPD. Lead enhanced the SCC of the Alloy 600 in high temperature water, had a tendency to modify a cracking morphology from intergranular to transgranular. Pit initiation preferentially occurred at Ti-rich carbide. Resistance to pit initiation decreased with increasing temperature up to 300 deg C. Test loop for erosion corrosion was designed and fabricated. Thin layer activation technique was very effective in measuring erosion corrosion. Erosion corrosion of a part of secondary side pipe was evaluated by the Check Family Codes of EPRI. Calculated values of pipe thickness by Check Family Codes coincided with the pipe thickness measured by UT with an error of {+-} 20%. Literature review on turbine failure showed that failure usually occurred in low pressure turbine rotor disc and causes of failure are stress corrosion cracking and corrosion fatigue. (author). 12 refs., 20 tabs., 77 figs.

  18. Microstructure, mechanical and corrosion behavior of high strength AA7075 aluminium alloy friction stir welds – Effect of post weld heat treatment

    Directory of Open Access Journals (Sweden)

    P. Vijaya Kumar

    2015-12-01

    It was observed that the hardness and strength of weld were observed to be comparatively high in peak aged (T6 condition but the welds showed poor corrosion resistance. The resistance to pitting corrosion was improved and the mechanical properties were maintained by RRA treatment. The resistance to pitting corrosion was improved in RRA condition with the minimum loss of weld strength.

  19. Research of Mechanical Properties of Piping Yards in the Assessment of their Safe Operation

    Directory of Open Access Journals (Sweden)

    Trebuňa, F.

    2007-01-01

    Full Text Available Working life of piping yards of compressor stations is mainly influenced by material parameters of particular structural members. In the paper are given the results of static and dynamic tests of basic as well as welded joint material of pipe of compressor station for which were determined conditions for safe operation.

  20. Comparison of core sampling and visual inspection for assessment of sewer pipe condition

    NARCIS (Netherlands)

    Stanic, N.; Haan, C.; Tirion, M.; Langeveld, J.G.; Clemens, F.H.L.R.

    2012-01-01

    Sewer systems are costly to construct and even more costly to replace, requiring proper asset management Sewer asset management relies to a large extent on available information. In sewer systems where pipe corrosion is the dominant failure mechanism, visual inspection (CCTV) and core sampling are a

  1. Comparison of core sampling and visual inspection for assessment of sewer pipe condition

    NARCIS (Netherlands)

    Stanic, N.; Haan, C.; Tirion, M.; Langeveld, J.G.; Clemens, F.H.L.R.

    2012-01-01

    Sewer systems are costly to construct and even more costly to replace, requiring proper asset management Sewer asset management relies to a large extent on available information. In sewer systems where pipe corrosion is the dominant failure mechanism, visual inspection (CCTV) and core sampling are a

  2. Comparison of core sampling and visual inspection for assessment of sewer pipe condition

    NARCIS (Netherlands)

    Stanic, N.; Haan, C.; Tirion, M.; Langeveld, J.G.; Clemens, F.H.L.R.

    2012-01-01

    Sewer systems are costly to construct and even more costly to replace, requiring proper asset management Sewer asset management relies to a large extent on available information. In sewer systems where pipe corrosion is the dominant failure mechanism, visual inspection (CCTV) and core sampling are

  3. Analysis on Mechanism of Flowing Cooling Water on Ship Pipeline Accelerated Corrosion%流动冷却水对船舶管路的冲刷加速腐蚀机理

    Institute of Scientific and Technical Information of China (English)

    杨元龙

    2015-01-01

    为研究船舶冷却水管路流动冲蚀失效过程,明晰冷却水管路易发生腐蚀破损的薄弱部位,建立船舶冷却水系统管路数理模型,采用基于CFD数值模拟的方法研究冷却水管路系统压力场和流速场运行特性,结合引发流动冷却水冲蚀管道的机理,得到弯头、三通管等易损部位的流速、湍动能、剪切应力和压力的参数分布。分析冷却水管路内流场,判定三通管流出支管易遭受冲击腐蚀和冲刷腐蚀,三通管焊缝区域易遭受空泡腐蚀,弯管中游靠内壁区域受冲击腐蚀、冲刷腐蚀和空泡腐蚀。%For the study of ship cooling water flow erosion failure process, weak position coming from corrosion damages for cooling water pipe were cleared.The mathematical and physical models of ship cooling water pipeline are established.The opera-tion characteristics with pressure and velocity field for the cooling water pipeline are analyzed by using CFD simulation.Three mechanisms comprised impingement corrosion, brush corrosion and cavitation erosion, which could induce pipeline erosion by flowing cooling water are inserted.The key predicting parameter such as local velocity, turbulence kinetic energy, wall shears and pressure around T-junction and elbow regions are obtained.Based on the analysis of flow field within the cooling water pipe-line, the calculated results indicated that impingement corrosion and brush corrosion are easy to come up.Cavitation erosion is easy to take place at the region of weld joint for T-junction.All of impingement corrosion, brush corrosion and cavitation erosion can happen midstream elbow rely on inner wall region.

  4. In Vivo Corrosion of Two Novel Magnesium Alloys ZEK100 and AX30 and Their Mechanical Suitability as Biodegradable Implants

    Directory of Open Access Journals (Sweden)

    Andrea Meyer-Lindenberg

    2011-06-01

    Full Text Available In magnesium alloys, the components used modify the alloy properties. For magnesium implants in contact with bone, rare earths alloys are commonly examined. These were shown to have a higher corrosion resistance than other alloys and a high mechanical strength, but their exact composition is hard to predict. Therefore a reduction of their content could be favorable. The alloys ZEK100 and AX30 have a reduced content or contain no rare earths at all. The aim of the study was to investigate their in vivo degradation and to assess the suitability of the in vivo µCT for the examination of their corrosion. Implants were inserted in rabbit tibiae. Clinical examinations, X-rays and in vivo µCT scans were done regularly. Afterwards implants were analyzed with REM, electron dispersive X-ray (EDX, weighing and mechanical testing. The in vivo µCT is of great advantage, because it allows a quantification of the corrosion rate and qualitative 3D assessment of the corrosion morphology. The location of the implant has a remarkable effect on the corrosion rate. Due to its mechanical characteristics and its corrosion behavior, ZEK100 was judged to be suitable, while AX30, which displays favorable degradation behavior, has too little mechanical strength for applications in weight bearing bones.

  5. Mechanical Properties Variation of B500SD High Ductility Reinforcement Regarding its Corrosion Degree

    Directory of Open Access Journals (Sweden)

    Cobo, A.

    2011-12-01

    Full Text Available Corrosion effects on reinforcement become evident in the bar section reduction and in the variation of mechanical properties related to ductility. In this research work, 96 B500SD steel bars, previously subjected to different corrosion variables, have been tested. Results show that the elongation of the bars diminishes and the ratio between the maximum tensile stress and the elastic limit increases as the corrosion degree advances. These phenomena can be explained by studying the necking effect and the different steel composition through the manufacture process.

    Los efectos de la corrosión sobre las armaduras se manifiestan por la pérdida de sección y la variación de las propiedades mecánicas relacionadas con la ductilidad. En este trabajo se han ensayado a tracción 96 barras de acero B500SD que previamente se han sometido a niveles variables de corrosión. Los resultados muestran que los alargamientos de las barras disminuyen y el cociente entre la tensión máxima y el límite elástico aumenta conforme el nivel de corrosión avanza. A partir del estudio del efecto de entalla y de la distinta constitución metalográfica del acero a nivel de sección debido a su procedimiento de fabricación, se pueden explicar los fenómenos anteriores.

  6. Microstructure, mechanical property, corrosion behavior, and in vitro biocompatibility of Zr-Mo alloys.

    Science.gov (United States)

    Zhou, F Y; Wang, B L; Qiu, K J; Li, L; Lin, J P; Li, H F; Zheng, Y F

    2013-02-01

    In this study, the microstructure, mechanical properties, corrosion behaviors, and in vitro biocompatibility of Zr-Mo alloys as a function of Mo content after solution treatment were systemically investigated to assess their potential use in biomedical application. The experimental results indicated that Zr-1Mo alloy mainly consisted of an acicular structure of α' phase, while ω phase formed in Zr-3Mo alloy. In Zr-5Mo alloy, retained β phase and a small amount of precipitated α phase were observed. Only the retained β phase was obtained in Zr-10Mo alloy. Zr-1Mo alloy exhibited the greatest hardness, bending strength, and modulus among all experimental Zr-Mo alloys, while β phase Zr-10Mo alloy had a low modulus. The results of electrochemical corrosion indicated that adding Mo into Zr improved its corrosion resistance which resulted in increasing the thermodynamic stability and passivity of zirconium. The cytotoxicity test suggested that the extracts of the studied Zr-Mo alloys produced no significant deleterious effect to fibroblast cells (L-929) and osteoblast cells (MG 63), indicating an excellent in vitro biocompatibility. Based on these facts, certain Zr-Mo alloys potentially suitable for different biomedical applications were proposed. Copyright © 2012 Wiley Periodicals, Inc.

  7. Effect of Aging Treatments on the Mechanical and Corrosive Behaviors of Spray-Formed 7075 Alloy

    Science.gov (United States)

    Su, Rui-ming; Qu, Ying-dong; Li, Rong-de

    2014-11-01

    Mechanical properties, microstructure, exfoliation corrosion (EXCO), and intergranular corrosion (IGC) behaviors of the spray-formed 7075 aluminum alloy after T6, T73, retrogression (R), and re-aging (RRA) treatment, respectively, were studied by using tensile tester, transmission electron microscope, and scanning electron microscope. The results show that the T6 process can increase the ultimate tensile strength (UTS) up to 760 MPa, while it decreases the elongation, the EXCO, and the IGC resistance of the alloy. The T73 process can improve elongation, the EXCO, and the IGC resistance of the alloy. The corrosion resistance of the alloy can also be improved by R and RRA processes with retrogression times increase. The tiny precipitated phases distributed homogeneously in the matrix can increase the UTS. The close-connected discrete grain boundary phases (GBP) and the narrow precipitate free zones (PFZ) will lower the elongation, the EXCO, and the IGC resistance of the alloy. Contrarily, the discrete GBP and wide PFZ can improve the elongation, the EXCO, and the IGC resistance of the alloy. The EXCO and the IGC behaviors for the spray-formed 7075 alloy after different aging treatments have been established according to the standards of ASTM G34-2001 (2007) and ASTM G110-1992 (2009).

  8. Mechanical and corrosion properties of Al/Ti film on magnesium alloy AZ31B

    Science.gov (United States)

    Zeng, Rong-Chang; Jiang, Ke; Li, Shuo-Qi; Zhang, Fen; Cui, Hong-Zhi; Han, En-Hou

    2015-03-01

    Preparation of titanium film on magnesium substrate faces a challenge due to non-Fickian inter-diffusion between titanium and magnesium. Aluminum can build a bridge between titanium and magnesium. Al/Ti duplex coatings were deposited on magnesium alloy AZ31B using magnetron sputtering (MS). The low temperature diffusion bonding behavior of the Mg/Al/Ti coating was investigated through SEM and its affiliated EDS. The phase structure and critical load of the coatings were examined by means of XRD and scratch tests, respectively. The results demonstrated that the bonding strength was significantly improved after a post heat treatment (HT) at a temperature of 210°C. The diffusion mechanism of the interfaces of Mg/Al and Al/Ti in the coating was discussed based on the analysis of formation energy of vacancies and diffusion rates. The Al/Ti dual layer enhanced the corrosion resistance of the alloy. And the HT process further increased the corrosion resistance of the coated alloy. This result implies that a post HTat a lower temperature after MS is an effective approach to enhance the bonding strength and corrosion resistance of the Al/Ti film on Mg alloys.

  9. An Evaluation of the Corrosion and Mechanical Performance of Interstitially Surface-Hardened Stainless Steel

    Science.gov (United States)

    Jones, Jennifer L.; Koul, Michelle G.; Schubbe, Joel J.

    2014-06-01

    A surface hardening technique called "interstitial hardening" is commercially available, whereby interstitial carbon atoms are introduced into stainless steel surfaces without the formation of carbides. Surface hardening of machine elements such as impellors or fasteners would improve performance regarding cavitation and galling resistance, and has intensified interest in this process. However, there remains a need to characterize and validate the specific performance characteristics of the hardened materials. This paper describes experimental testing conducted on 316L stainless steel that has been surface hardened using available commercial techniques, using carbon as the interstitial atom. The corrosion performance of the hardened surface is assessed using electrochemical potentiodynamic testing to determine the breakdown potential in 3.5 wt.% NaCl solution to identify the most promising method. The hardness and thickness of the surface-hardened layer is characterized and compared using metallography and microhardness profiling. Corrosion fatigue and slow strain rate testing of untreated, hardened, and damaged, hardened surfaces exposed to ASTM seawater is conducted. Finally, critical galling stresses are determined and compared. Post-test examination of damage attempts to identify mechanisms of material failure and characterize how corrosion-assisted cracks initiate and grow in surface-hardened materials.

  10. Simulation of Mechanical Stress on Stainless Steel for Pb-Bi Corrosion Test by Using ABAQUS

    Science.gov (United States)

    Irwanto, D.; Mustari, A. P. A.; Budiman, B. A.

    2017-03-01

    Pb-Bi eutectic with its advantageous is proposed to be utilized as a coolant in the GEN IV type of rSeactor. However, high temperature corrosion when contact with stainless steels is one of the issues of Pb-Bi eutectic utilization. It is known that in the environment of high temperature Pb-Bi, mechanical strength of stainless steel may decrease. Thus, simulation of mechanical stress working on stainless steel during in-situ bending test by using ABAQUS was conducted. Several bending degrees were simulated at high temperature to obtain the mechanical stress information. Temperature condition was strongly affect the stress vs. displacement profile. The reported mechanical strength reduction percentage was used to draw predicted mechanical stress under high temperature Pb-Bi environment.

  11. Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel

    Science.gov (United States)

    Zhang, Lei; Li, Hui-xin; Shi, Feng-xian; Yang, Jian-wei; Hu, Li-hua; Lu, Min-xu

    2017-04-01

    To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry.

  12. Assessment of Initial Test Conditions for Experiments to Assess Irradiation Assisted Stress Corrosion Cracking Mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Busby, Jeremy T [ORNL; Gussev, Maxim N [ORNL

    2011-04-01

    Irradiation-assisted stress corrosion cracking is a key materials degradation issue in today s nuclear power reactor fleet and affects critical structural components within the reactor core. The effects of increased exposure to irradiation, stress, and/or coolant can substantially increase susceptibility to stress-corrosion cracking of austenitic steels in high-temperature water environments. . Despite 30 years of experience, the underlying mechanisms of IASCC are unknown. Extended service conditions will increase the exposure to irradiation, stress, and corrosive environment for all core internal components. The objective of this effort within the Light Water Reactor Sustainability program is to evaluate the response and mechanisms of IASCC in austenitic stainless steels with single variable experiments. A series of high-value irradiated specimens has been acquired from the past international research programs, providing a valuable opportunity to examine the mechanisms of IASCC. This batch of irradiated specimens has been received and inventoried. In addition, visual examination and sample cleaning has been completed. Microhardness testing has been performed on these specimens. All samples show evidence of hardening, as expected, although the degree of hardening has saturated and no trend with dose is observed. Further, the change in hardening can be converted to changes in mechanical properties. The calculated yield stress is consistent with previous data from light water reactor conditions. In addition, some evidence of changes in deformation mode was identified via examination of the microhardness indents. This analysis may provide further insights into the deformation mode under larger scale tests. Finally, swelling analysis was performed using immersion density methods. Most alloys showed some evidence of swelling, consistent with the expected trends for this class of alloy. The Hf-doped alloy showed densification rather than swelling. This observation may be

  13. Characterization and corrosion behaviour of CoNi alloys obtained by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Olvera, S. [Instituto Politécnico Nacional, ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, México, D. F. (Mexico); Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain); Sánchez-Marcos, J. [Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain); Palomares, F.J. [Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC, Cantoblanco, 28049 Madrid (Spain); Salas, E. [Spline Spanish CRG Beamline at the European Synchrotron Radiation Facilities, ESRF, BP 220-38043, Grenoble Cedex (France); Arce, E.M. [Instituto Politécnico Nacional, ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, México, D. F. (Mexico); Herrasti, P., E-mail: pilar.herrasti@uam.es [Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain)

    2014-07-01

    CoNi alloys including Co{sub 30}Ni{sub 70}, Co{sub 50}Ni{sub 50} and Co{sub 70}Ni{sub 30} were prepared via mechanical alloying using Co and Ni powders. The crystallinity and short-range order were studied using X-ray diffraction and X-ray absorption spectroscopy. The results show that the milling process increases the number of vacancies, especially around the Co atoms, while the milling time decreases the crystalline size and enhances the crystallinity. X-ray photoelectron spectroscopy was used to characterise the chemical composition of the samples surface. The magnetic properties were analysed using zero-field cooling, field cooling and a magnetic hysteresis loops. The magnetic saturation moment is approximately 1.05 μ{sub B}/atom; this value decreases with the mechanical alloying time, and it is proportional to the cobalt concentration. The polarization and impedance curves in different media (NaCl, H{sub 2}SO{sub 4} and NaOH) showed similar corrosion resistance values. The corrosion resistance increased in the order NaCl, H{sub 2}SO{sub 4} and NaOH. A good passivation layer was formed in NaOH due to the cobalt and nickel oxides on the particle surfaces. - Highlights: • Ni{sub x}Co{sub 100-x} alloys were synthesized by mechanical alloying • Milling time decrease size and enhances crystallinity. • Oxygen is not present in a significant percentage in bulk but is detected on the surface. • Magnetic saturation moment is 1.05 mB/atom and decrease with mechanical allowing time • Corrosion resistance is higher in NaOH than in NaCl or HCl solutions.

  14. Corrosion behaviors of metal end of PHC pipe pile in simulated soil solutions%PHC管桩金属端头在土壤模拟液中的腐蚀行为

    Institute of Scientific and Technical Information of China (English)

    林碧兰; 路新瀛; 李龙

    2011-01-01

    通过自然浸泡、动电位极化、电化学阻抗谱测量、电偶腐蚀试验研究预应力高强混凝土(PHC)管桩金属端头处端板和主筋在氯盐土、盐碱土、中性草甸土和酸性土模拟液中的腐蚀速率、电化学腐蚀行为以及电偶腐蚀行为.研究结果表明:主筋的耐蚀性能比端板的差,盐渍土中主筋的耐蚀程度差;端板和主筋的阴极过程受氧扩散控制;盐渍土中端板和主筋的锈层不具保护作用;主筋与端板偶接时主筋为阳极,端板为阴极;主筋在酸性土中的电偶腐蚀效应最大,而在草甸土中最小.%The corrosion rate, electrochemical corrosion and galvanic corrosion behaviors of the end plate and the steel bar at metal end of prestressed high-strength concrete (PHC) pipe pile in simulated solutions of chloride salt soil, salina soil, neutral meadow soil and acid soil were investigated by natural immersion tests, potentiodynamic polarization and electrochemical impedance spectroscopy measurements and galvanic corrosion tests. The results show that the corrosion resistance of the end plate is inferior to that of the steel bar, and in saline soil the corrosion resistance grade of the steel bar is poor. The cathodic processes of the end plate and the steel bar in four simulated soil solutions are controlled by oxygen diffusion. The corrosion products on end plate and steel bar immersed in saline soil are hardly protective. Steel bar is anodic and end plate is cathodic when they were coupled and immersed in four solutions. The galvanic corrosion effect of stell bar in acid soil is maximal, while that in neutral meadow soil is minimal.

  15. 合水油田注水管网缓蚀剂 XD的开发优化与应用研究%Research on development and application of corrosion inhibitor XD for water injection pipe networks in Heshui Oilfield

    Institute of Scientific and Technical Information of China (English)

    吴大康; 范峥; 李稳宏; 马文军; 赵欢娟

    2016-01-01

    为了解决合水油田注水管网严重腐蚀这一问题,首先利用K‐均值聚类分析对在役586条注水管线进行研究,找出最具代表性的庄一注、庄二注、庄三注作为新型复配缓蚀剂XD的试验对象,然后通过对试片腐蚀形貌以及腐蚀产物组成、含量的检测来确定注水管网的腐蚀成因。最后,针对此问题合成了一种多位点吸附型咪唑啉季铵盐MIQAS ,以MIQAS为缓蚀剂,聚环氧琥珀酸钠(PEAS)为阻垢剂,1,2苯并异噻唑啉‐3‐酮(BIT)为杀菌剂进行复配,并借助单因素和多指标正交试验设计对MIQAS、PESA和BIT含量进行优化。结果表明,溶解氧、侵蚀性CO2、Cl-引起的吸氧腐蚀、CO2腐蚀和点蚀是导致注水管网腐蚀的主要原因,C a2+、细菌造成的结垢腐蚀和细菌腐蚀对其也有一定影响。当该复配缓蚀剂ρ(MIQAS)∶ρ(PESA)∶ρ(BIT)=120 mg/L∶65 mg/L∶50 mg/L时,XD对庄一注、庄二注和庄三注的缓蚀率分别高达98.24%、98.63%、99.17%,取得了良好的防腐效果。%In order to solve the severe corrosion of water injection pipe networks in Heshui Oilfield ,586 water injection pipelines in service were studied using K‐means clustering analysis . Zhuangyizhu ,Zhuangerzhu and Zhuangsanzhu were selected as representative experimental objects of new compound inhibitor XD .Micro‐morphology of steel sheet ,composition and content of corrosion products were determined and analyzed to find out the corrosion reason .A kind of multi‐adsorbed‐sites imidazoline quaternary ammonium salt MIQAS was synthesized aiming at above problems . Then ,single factor and multi‐target orthogonal design experiments were employed to optimize MIQAS ,PESA and BIT content . The results show that the main reasons of corrosion including oxygen absorption ,acid and pitting induced by dissolved oxygen ,erosive carbon dioxide and chloride . The fouling

  16. Corrosion mechanism of mechanically alloyed Mg50Ni50 and Mg45Cu5Ni50 alloys

    Institute of Scientific and Technical Information of China (English)

    张耀; 李寿权; 陈立新; 雷永泉; 王启东

    2002-01-01

    As the loss of active material Mg may affect electrode's discharge capacity and the cycling stability,a more refined mechanism study on cycling capacity degradation should be made.The present investigation is based on the supposition that the capacity degradation of the binary Mg50Ni50 alloy and ternary Mg45Cu5Ni50 alloy electrodes is solely due to the corrosion of Mg,the active hydrogen storage element.That means amount of capacity degradation is determined by the corrosion current time,which is also the time of operation.The corrosion current J corr dependence on cycling time was deduced.A mathematic relation between the cycling capacity retention CN / C 1 (%) and the duration of operation was also deduced.The data calculated from the equations deduced agree well with those of the experiment result.The loss of the active hydrogen-absorbing element Mg is proved to be the main cause for cycling capacity deterioration in the present investigation.

  17. 变电站接地装置的腐蚀机理及防腐措施研究%Research on Corrosion Mechanism and Anti-corrosion Measure for Grounding Deviee at Substations

    Institute of Scientific and Technical Information of China (English)

    欧洲华

    2009-01-01

    本文针对变电站接地装置的腐蚀问题,简单介绍了接地装置易发生腐蚀的部位和原因,分析了在土壤中发生化学腐蚀,电化学腐蚀、微生物腐蚀和杂散电流腐蚀的腐蚀机理,并对影响腐蚀速率的主要因素及相互关系作了说明.在此基础上,提出了如下防腐技术措施:采用耐蚀材料和金属镀层;使用导电防腐涂料;实施阴极保护;采用高效膨润土降阻防腐剂,以适应多种土壤腐蚀环境.%Aiming at the corrosion issues of grounding device used in substation,its corrosion position occurred frequently and corrosion reason are introduced briefly.Several types of corrosion mechanism are also analyzed,such as chemical corrosion,electrochemical corrosion,microbiological corrosion and stray current corrosion,when grounding device lie in soil and corrosion occurs.Furthermore,some main factors,which can influence on rate of corrosion,and their correlation are illustrated.On the basis of these analysis,several technology measures are put forward to avoid grounding device corrosion to fit many kinds of soil corrosion environment.They are:selecting corrosion resistant material and metal coating,employing anti-corrosive paint,carrying out cathodic protection and adopting high efficient bentonite resistance.

  18. Investigation of fatigue and mechanical properties of the pipe grade poly(vinyl chloride using recycled scraps

    Directory of Open Access Journals (Sweden)

    J-M. Lee

    2015-04-01

    Full Text Available In this paper, the effect of using pre-consumer PVC scraps on static and long-term mechanical properties is studied. The degradation characteristics of mixing virgin PVC with crushed pre-consumer and PVC pipe scraps are analyzed using various tools including Gel Permeation Chromatography (GPC, Thermogravimetric Analysis (TGA, X-ray fluorescence (XRF and Fourier Transform Infrared (FTIR spectroscopy. The variation of static mechanical properties as a function of adding pre-consumer PVC pipe scraps is investigated using the degradation analyses of recycled PVC scraps. In addition, fatigue tests are executed to evaluate the long-term durability of blending virgin PVC and recycled PVC scraps, and the fracture surface is investigated in detail to reveal the variation of the fracture mechanisms.

  19. Mechanical Response of Steel Wire Wound Reinforced Rubber Flexible Pipe under Internal Pressure

    Institute of Scientific and Technical Information of China (English)

    GU Fan; HUANG Cheng-kui; ZHOU Jing; LI Lin-pu

    2009-01-01

    Steel wire wound reinforced flexible pipe in this study mainly consists of multiple anisotropic steel wire wound reinforcement layers and multiple isotropic rubber layers. Based on 3D anisotropic elastic theory, the analytic solutions of stresses and elastic deformations of steel wire wound reinforced rubber flexible pipe under internal pressure are presented. As the adjacent reinforcement layers with wound angle have different radii, the single reinforcement layer shows the effect of tensile-shear coupling. Moreover, the static loading test results of steel wire wound reinforced rubber flexible pipe under internal pressure are basically coincided with the calculated values by present method.

  20. Refractory Corrosion Mechanisms in a Novel High Carbon Ferromanganese Production Furnace

    Science.gov (United States)

    Gregurek, D.; Wenzl, C.; Kreuzer, D.; Spanring, A.; Kirschen, M.; Zeelie, D.; Groenewald, J.

    2016-12-01

    The present paper presents the refractory design for a novel HCFeMn smelting furnace that, other than standard submerged arc furnaces, allows the processing of fine ores. A combination of basic and non-basic materials, comprising bricks, castables and ramming was chosen, under consideration of the unique furnace design and process conditions. Post-mortem investigations on refractory samples from the different furnace zones were carried out and provided information about the main wear mechanism. Additionally, investigations of the process slag and metal were carried out both practically and theoretically using thermodynamic calculations, to better understand the corrosion phenomena observed in the post mortem samples.

  1. Refractory Corrosion Mechanisms in a Novel High Carbon Ferromanganese Production Furnace

    Science.gov (United States)

    Gregurek, D.; Wenzl, C.; Kreuzer, D.; Spanring, A.; Kirschen, M.; Zeelie, D.; Groenewald, J.

    2016-09-01

    The present paper presents the refractory design for a novel HCFeMn smelting furnace that, other than standard submerged arc furnaces, allows the processing of fine ores. A combination of basic and non-basic materials, comprising bricks, castables and ramming was chosen, under consideration of the unique furnace design and process conditions. Post-mortem investigations on refractory samples from the different furnace zones were carried out and provided information about the main wear mechanism. Additionally, investigations of the process slag and metal were carried out both practically and theoretically using thermodynamic calculations, to better understand the corrosion phenomena observed in the post mortem samples.

  2. Effect of Chemical Corrosion on the Mechanical Characteristics of Parent Rocks for Nuclear Waste Storage

    Directory of Open Access Journals (Sweden)

    Tielin Han

    2016-01-01

    Full Text Available Long-term immersion was adopted to explore the damage deterioration and mechanical properties of granite under different chemical solutions. Here, granite was selected as the candidate of parent rocks for nuclear waste storage. The physical and mechanical properties of variation regularity immersed in various chemical solutions were analyzed. Meanwhile, the damage variable based on the variation in porosity was used in the quantitative analysis of chemical damage deterioration degree. Experimental results show that granite has a significant weakening tendency after chemical corrosion. The fracture toughness KIC, splitting tensile strength, and compressive strength all demonstrate the same deteriorating trend with chemical corrosion time. However, a difference exists in the deterioration degree of the mechanical parameters; that is, the deterioration degree of fracture toughness KIC is the greatest followed by those of splitting tensile strength and compressive strength, which are relatively smaller. Strong acid solutions may aggravate chemical damage deterioration in granite. By contrast, strong alkaline solutions have a certain inhibiting effect on chemical damage deterioration. The chemical solutions that feature various compositions may have different effects on chemical damage degree; that is, SO42- ions have a greater effect on the chemical damage in granite than HCO3- ions.

  3. Thermal protection mechanism of heat pipe in leading edge under hypersonic conditions

    Institute of Scientific and Technical Information of China (English)

    Peng Wengen; He Yurong; Wang Xinzhi; Zhu Jiaqi; Han Jiecai

    2015-01-01

    Sharp local structure, like the leading edge of hypersonic aircraft, confronts a severe aerodynamic heating environment at a Mach number greater than 5. To eliminate the danger of a material failure, a semi-active thermal protection system is proposed by integrating a metallic heat pipe into the structure of the leading edge. An analytical heat-balance model is established from tra-ditional aerodynamic theories, and then thermal and mechanical characteristics of the structure are studied at Mach number 6–8 for three refractory alloys, Inconel 625, C-103, and T-111. The feasi-bility of this simple analytical method as an initial design tool for hypersonic aircraft is assessed through numerical simulations using a finite element method. The results indicate that both the iso-thermal and the maximum temperatures fall but the von Mises stress increases with a longer design length of the leading edge. These two temperatures and the stress rise remarkably at a higher Mach number. Under all investigated hypersonic conditions, with a 3 mm leading edge radius and a 0.15 m design length, the maximum stress exceeds the yield strength of Inconel 625 at Mach num-bers greater than 6, which means a material failure. Moreover, both C-103 and T-111 meet all requirements at Mach number 6–8.

  4. Thermal protection mechanism of heat pipe in leading edge under hypersonic conditions

    Directory of Open Access Journals (Sweden)

    Peng Wengen

    2015-02-01

    Full Text Available Sharp local structure, like the leading edge of hypersonic aircraft, confronts a severe aerodynamic heating environment at a Mach number greater than 5. To eliminate the danger of a material failure, a semi-active thermal protection system is proposed by integrating a metallic heat pipe into the structure of the leading edge. An analytical heat-balance model is established from traditional aerodynamic theories, and then thermal and mechanical characteristics of the structure are studied at Mach number 6–8 for three refractory alloys, Inconel 625, C-103, and T-111. The feasibility of this simple analytical method as an initial design tool for hypersonic aircraft is assessed through numerical simulations using a finite element method. The results indicate that both the isothermal and the maximum temperatures fall but the von Mises stress increases with a longer design length of the leading edge. These two temperatures and the stress rise remarkably at a higher Mach number. Under all investigated hypersonic conditions, with a 3 mm leading edge radius and a 0.15 m design length, the maximum stress exceeds the yield strength of Inconel 625 at Mach numbers greater than 6, which means a material failure. Moreover, both C-103 and T-111 meet all requirements at Mach number 6–8.

  5. The Influence of Transition Metals Addition on the Corrosion Resistance of Nanocrystalline Al Alloys Produced by Mechanical Alloying

    Directory of Open Access Journals (Sweden)

    Asiful Hossain Seikh

    2016-06-01

    Full Text Available The corrosion resistance of nanocrystalline Al, Al-10 wt. % Fe and Al-10 wt. % Fe-5 wt. % Cr alloys was investigated in 3.5% NaCl solution using cyclic potentiodynamic polarization (CPP and electrochemical impedance spectroscopy (EIS techniques. The alloys were fabricated using mechanical alloying (MA and heat induction sintering. When compared with the corrosion resistance of pure Al, the experimental results indicated that the addition of 10 wt. % Fe and 10 wt. % Fe-5 wt. % Cr to pure Al has resulted in an enhancement in the corrosion resistance of these newly fabricated alloys. The resistance to corrosion is due to enhanced microstructural stability along with the formation of stable oxide layer.

  6. Effect of Multipass Friction Stir Processing on Mechanical and Corrosion Behavior of 2507 Super Duplex Stainless Steel

    Science.gov (United States)

    Mishra, M. K.; Gunasekaran, G.; Rao, A. G.; Kashyap, B. P.; Prabhu, N.

    2016-12-01

    The microstructure, mechanical properties, and corrosion behavior of 2507 super duplex stainless steel after multipass friction stir processing (FSP) were examined. A significant refinement in grain size of both ferrite and austenite was observed in stir zone resulting in improved yield and tensile strength. Electrochemical impedance spectroscopy and anodic polarization studies in 3.5 wt.% NaCl solution showed nobler corrosion characteristics with increasing number of FSP passes. This was evident from the decrease in corrosion current density, decrease in passive current density, and increase in polarization resistance. Also, the decrease in density of defects, based on Mott-Schottky analysis, further confirms the improvement in corrosion resistance of 2507 super duplex stainless steel after multipass FSP.

  7. Mechanical and Corrosion Behaviour of Zn-27Al Based Composites Reinforced with Groundnut Shell Ash and Silicon Carbide

    Directory of Open Access Journals (Sweden)

    K.K. Alaneme

    2014-06-01

    Full Text Available The mechanical and corrosion behaviour of Zn-27Al alloy based composites reinforced with groundnut shell ash and silicon carbide was investigated. Experimental test composite samples were prepared by melting Zn-27Al alloy with pre-determined proportions of groundnut ash and silicon carbide as reinforcements using double stir casting. Microstructural examination, mechanical properties and corrosion behaviour were used to characterize the composites produced. The results show that hardness and ultimate tensile strength of the hybrid composites decreased with increase in GSA content. Although the % Elongation somewhat decreased with increase the GSA content, the trend was not as consistent as that of hardness and tensile strength. The fracture toughness of the hybrid composites however, increased with increase in the GSA content of the composites. In 3.5 % NaCl solution, the composites were resistant to corrosion with some of the hybrid composite grades containing GSA exhibiting relatively superior corrosion resistance to the grades without GSA. In 0.3M H2SO4 solution, the composites were generally a bit more susceptible to corrosion (compared to 3.5 % NaCl solution, but the effect of GSA content on the corrosion resistance of the composites was not consistent for the Zn-27Al alloy based composites.

  8. Dissolution, corrosion and environmental issues in chemical mechanical planarization of copper

    Science.gov (United States)

    Tamilmani, Subramanian

    Chemical mechanical polishing (CMP) of dielectric and metal films has become a key process in manufacturing devices with ultra large scale integration (ULSI). In a CMP process, planarization is achieved by polishing a wafer with uneven topography using colloidal slurry consisting of sub-micron sized abrasive particles, oxidant and various additives. Hydrogen peroxide and hydroxylamine are commonly used oxidants in copper CMP process. To achieve planarization, the low lying areas have to be protected while the higher areas are polished away. This requires low static dissolution rate of copper in low areas. Another major issue in copper CMP is galvanic corrosion during barrier polishing step where both copper and the barrier metal are exposed to the slurry. The main goal of the research reported in this dissertation is to understand the dissolution and corrosion issues during the removal of copper in hydroxylamine based chemistries. Electrochemical and physical methods such as profilometry were used to obtain copper removal rates. Among the variety of organic compound tested, benzotriazole and salicylhydroxamic acid were identified as potential corrosion inhibitors for copper. The passive film formed on the copper surface by the addition of benzotriazole and salicylhydroxamic acid was characterized by X-ray photoelectron spectroscopy and atomic force microscopy. The passivation and repassivation kinetics were investigated in detail and a passivation mechanism for copper in hydroxylamine in the presence of benzotriazole and salicylhydroxamic acid chemistries is proposed. Copper removal experiments were performed on a specially designed electrochemical abrasion cell (EC-AC) in the presence and absence of inhibitors. The effect of anodic potentials on the dissolution of copper in various chemistries was studied to identify suitable conditions for electro-chemical mechanical planarization process. The extent of galvanic corrosion between copper and tantalum was estimated

  9. The effect of carbon content on mechanical properties, failure and corrosion resistance of deposited chromium metal

    Directory of Open Access Journals (Sweden)

    Леонід Кімович Лещинськiй

    2017-06-01

    Full Text Available It has been shown that if choosing a metal composition for surfacing rolls and rollers of continuous casting machines, both the carbon impact on the mechanical and functional properties and the critical values of the chromium concentration, which determine the corrosion resistance of the metal with regard to electrochemical corrosion theory, should be considered as well. The paper studied the effect of chromium and carbon steel the X5-X12 type on the structure, technological strength, mechanical properties, fracturing resistance and corrosion resistance of the weld metal. The composition of chromium tool steels (deposited metal (X5-used for the rolls of hot rolling mills and (X12-used for continuous casting machines rollers correspond to these values. The impact of carbon on the properties of the deposited metal containing chromium was considered by comparing the data for both types of the deposited metal. It was found that for both types of the deposited metal (X5 and X12, the limiting value of the carbon content, providing an optimal combination of strength, ductility, failure resistance is the same. If the carbon content is more than the limiting value – (0,25% the technological strength and failure resistance of the deposited metal significantly reduce. With increasing carbon content from 0,18 to 0,25% the martensite structure has a mixed morphology – lath and plate. The strength and toughness of the deposited metal grow. Of particular interest is simultaneous increase in the specific work of failure resulted from crack inhibition at the boundary with far less solid and more ductile ferrite. As for the 5% chromium metal, the X12 type composition with 0,25% C, is borderline. With a further increase in the carbon content of the metal both ductility and failure resistance sharply decrease and with 0,40% C the growth rate of fatigue crack increases by almost 1,5 times

  10. Corrosion monitoring as an integral component of an effective corrosion management program

    Energy Technology Data Exchange (ETDEWEB)

    Bich, N.N. [FORCE Technology Canada Inc., Calgary, AB (Canada)

    2004-07-01

    This paper presented 6 case studies of oil and sour gas transmission pipelines where the use of corrosion monitoring devices led to the early identification of ineffective mitigation measures. The field signature method inspection tool (FSM-IT) was used in all 6 cases. FSM-IT is a non-intrusive corrosion monitoring tool that consists of a geometric matrix of sensing pins that are permanently attached to an outer pipe wall. The sensing matrix wiring is coupled to a sensing matrix interface (SMI) to form an interface. With the occurrence of internal corrosion or erosion, the electrical field is changed and compared against the signature. Computer software is used to compare the new measurements against the original signature to produce metal loss values. The software is capable of trending the metal loss over time, calculating corrosion rates and creating 3D plots to illustrate accumulated wall loss over the whole matrix. The orientation of the corrosion can be determined from an evaluation of the plots. Case studies included details of pipeline length, corrosion mechanisms, and repair activities. Mitigation measures in the case studies included batching; continuous injection; and pigging. It was concluded that the FSM-IT corrosion mitigation tool is effective in monitoring mitigation effectiveness. 7 refs., 1 tab., 12 figs.

  11. Effect of Minor Zn Additions on the Mechanical and Corrosion Properties of Solution-Treated AM60-2%RE Magnesium Alloy

    Science.gov (United States)

    Liu, Z. L.; Liu, Y.; Liu, X. Q.; Wang, M. M.

    2016-07-01

    The microstructure, mechanical properties, and corrosion behaviors of solution-treated AM60-2%RE magnesium alloy containing 0.2-0.8% wt.% Zn were investigated. With the increase of Zn, the volume fraction of dispersed rod-like Al4RE and granular-like Al11RE3 phases of solution-treated AM60-2%RE + x%Zn increased, which improved the mechanical properties by dispersion strengthening. With increasing Zn content, the corrosion current density decreased, and the corrosion potential and electrochemical impedance of the alloys increased, and the corrosion resistance of solution-treated AM60-2%RE + x%Zn was improved. With the increase of Zn content, the leaf-like corrosion products of the alloy became smaller and more compact, and the content of Zn, Al, Ce, and La in corrosion products increased, which was beneficial to inhibit the corrosion progress.

  12. Microbiological Corrosion in Low Carbon Steels

    Directory of Open Access Journals (Sweden)

    O. Medina–Custodio

    2009-01-01

    Full Text Available The Microbiologically Induced Corrosion affects several industries, such as oil industry where it is estimated that 20% to 30% pipes failures are related with microorganism . The chemical reactions generate ions transfer, this validate the use of electrochemical techniques for its analysis. Coupons submerged in a nutritional medium with presence and absence of three different microorganisms during two periods, 48 hours and 28 days we restudied. Polarization resistance (Rp and Electrochemical Impedance Spectroscopy (EIS techniques we re applied to determine the corrosivity of the systems. The results show a greater corrosive effect of abiotic system, this indicates a microorganisms protection effect to the metal, opposite to the first hypothesis. This result was ratified observing surfaces coupons by using Scanning Electron Microscopy (SEM technique. A possible mechanism based on Evans – Tafel graph is proposed to explain inhibitor microorganism effect.

  13. A study of the effects of phosphates on copper corrosion in drinking water: Copper release, electrochemical, and surface analysis approach

    Science.gov (United States)

    Kang, Young C.

    The following work is the study to evaluate the impact of corrosion inhibitors on the copper metal in drinking water and to investigate the corrosion mechanism in the presence and absence of inhibitors. Electrochemical experiments were conducted to understand the effect of specific corrosion inhibitors in synthetic drinking water which was prepared with controlled specific water quality parameters. Water chemistry was studied by Inductively Coupled Plasma--Atomic Emission Spectroscopy (ICP--AES) to investigate the copper leaching rate with time. Surface morphology, crystallinity of corrosion products, copper oxidation status, and surface composition were characterized by various solid surface analysis methods, such as Scanning Electron Microscopy/Energy--Dispersive Spectrometry (SEM/EDS), Grazing-Incidence-angle X-ray Diffraction (GIXRD), X-ray Photoelectron Spectroscopy (XPS), and Time-of-Flight Secondary Ions Mass Spectrometry (ToF-SIMS). The purpose of the first set of experiments was to test various electrochemical techniques for copper corrosion for short term before studying a long term loop system. Surface analysis techniques were carried out to identify and study the corrosion products that form on the fresh copper metal surface when copper coupons were exposed to test solutions for 2 days of experiments time. The second phase of experiments was conducted with a copper pipe loop system in a synthetic tap water over an extended period of time, i.e., 4 months. Copper release and electrochemically measured corrosion activity profiles were monitored carefully with and without corrosion inhibitor, polyphosphate. A correlation between the copper released into the solution and the electrochemically measured corrosion activities was also attempted. To investigate corrosion products on the copper pipe samples, various surface analysis techniques were applied in this study. Especially, static mass spectra acquisition and element distribution mapping were carried out

  14. Study of mechanical, physical, and corrosion behavior of 0.5% cobalt alloyed austempered ductile iron

    Science.gov (United States)

    Abdullah, Bulan; Jaffar, Ahmed; Alias, Siti Khadijah; Ramli, Abdullah; Izham, Mohd Faizul

    2010-03-01

    Objectives: The purpose of this research was to determine the mechanical properties and corrosion behavior of 0.5% Co-DI before and after heat treatment and compare with commercial ductile iron. Methods: Molten metal of newly developed ductile iron which alloyed with 0.5% Cobalt produced through CO2 sand casting method. The specimens then performed preheat to 500°C in an hour then oil quenched. Specimens then performed annealing to 900°C in half an hour before oil quenched again. 500°C, 600°C and 700°C austempering temperature had been selected subjected to the specimens in half an hour before cooled to room temperature. The tests involved are microstructure analysis which included nodule count and phase analysis, polarization test, spectrometer test, density test, tensile test (ASTM E 8M), hardness test and impact test (ASTM A327) on as cast and austempered specimen. Results: 0.5% Cobalt alloyed austempered ductile iron with 500°C austempered temperature is the optimum temperature for 0.5% Co-ADI. It's not only increase the nodule count in the content, but also improve the mechanical properties such as impact toughness and tensile strength. Corrosion rate of 0.5% Co-DI also improved compare to unalloyed DI.

  15. Microstructures of corrosion layer of ACSR conductor in atmospheric corrosion and corrosion mechanism%钢芯铝绞导线大气腐蚀产物层的结构及腐蚀机理

    Institute of Scientific and Technical Information of China (English)

    张建堃; 陈国宏; 王家庆; 张涛; 王煦; 汤文明

    2011-01-01

    The dry/wet NaCl+NaHSO3 atmosphere-salt spraying experiment of the aluminum conductor steel reinforced (ACSR) conductor was carried out to study the phases and microstructures of corrosion products and the corrosion mechanism in simulated air corrosion condition. The results show that the ACSR conductor is mainly corroded by pitting corrosion. The corrosion layer mainly consists of hydroxides, sulfates and sulfate-chloride double salts and their hydrates of Zn and Al. At the initial corroding stage, the corrosion pits form on the Al strands and the galvanizing Zn layer, which are gradually replaced by the continuous corrosion layers as prolonging the spraying time. In the ACSR conductor, a primary cell is generated between the galvanizing Zn layer and the internal Al layer in the electrolyte. In the cell, as an anode, the galvanizing Zn layer is violently etched, contrarily, as a cathode, the internal Al layer is protected. In the ACSR conductor, the sequence of the corrosion rate from high to low is the galvanizing Zn layer, the external Al layer and the internal Al layer.%在模拟大气腐蚀环境中,采用干/湿NaHSO3+NaCl水溶液盐雾试验研究钢芯铝绞(ACSR)导线腐蚀产物的相组成及腐蚀层结构,讨论其腐蚀机理.结果表明:ACSR导线中单股铝线或镀锌钢芯线的腐蚀主要表现为点蚀,腐蚀产物组成复杂,主要为锌和铝的氢氧化物、硫酸盐与氯化物的复式盐;在腐蚀初期,内外层铝股线及钢芯线表面镀锌层开始形成点蚀坑,逐步形成连续的腐蚀层:由于镀锌层和内层铝股线之间构成原电池,因为牺牲阳极效应,镀锌层腐蚀速率最大;而内层铝股线受到保护,腐蚀速率最小,外层铝股线腐蚀速率居中.

  16. Comparative study of approaches to estimate pipe break frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Simola, K.; Pulkkinen, U.; Talja, H.; Saarenheimo, A.; Karjalainen-Roikonen, P. [VTT Industrial Systems (Finland)

    2002-12-01

    The report describes the comparative study of two approaches to estimate pipe leak and rupture frequencies for piping. One method is based on a probabilistic fracture mechanistic (PFM) model while the other one is based on statistical estimation of rupture frequencies from a large database. In order to be able to compare the approaches and their results, the rupture frequencies of some selected welds have been estimated using both of these methods. This paper highlights the differences both in methods, input data, need and use of plant specific information and need of expert judgement. The study focuses on one specific degradation mechanism, namely the intergranular stress corrosion cracking (IGSCC). This is the major degradation mechanism in old stainless steel piping in BWR environment, and its growth is influenced by material properties, stresses and water chemistry. (au)

  17. In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc-magnesium-aluminium (ZMA) alloys using novel time-lapse microscopy.

    Science.gov (United States)

    Sullivan, James; Cooze, Nathan; Gallagher, Callum; Lewis, Tom; Prosek, Tomas; Thierry, Dominique

    2015-01-01

    In situ time-lapse optical microscopy was used to examine the microstructural corrosion mechanisms in three zinc-magnesium-aluminium (ZMA) alloy coated steels immersed in 1% NaCl pH 7. Preferential corrosion of MgZn(2) lamellae within the eutectic phases was observed in all the ZMA alloys followed by subsequent dissolution of Zn rich phases. The total extent and rate of corrosion, measured using time-lapse image analysis and scanning vibrating electrode technique (SVET) estimated mass loss, decreased as Mg and Al alloying additions were increased up to a level of 3 wt% Mg and 3.7 wt% Al. This was probably due to the increased presence of MgO and Al(2)O(3) at the alloy surface retarding the kinetics of cathodic oxygen reduction. The addition of 1 × 10(-2) mol dm(-3) Na(3)PO(4) to 1% NaCl pH 7 had a dramatic influence on the corrosion mechanism for a ZMA with passivation of anodic sites through phosphate precipitation observed using time-lapse image analysis. Intriguing rapid precipitation of filamentous phosphate was also observed and it is postulated that these filaments nucleate and grow due to super saturation effects. Polarisation experiments showed that the addition of 1 × 10(-2) mol dm(-3) Na(3)PO(4) to the 1% NaCl electrolyte promoted an anodic shift of 50 mV in open circuit potential for the ZMA alloy with a reduction in anodic current of 2.5 orders of magnitude suggesting that it was acting primarily as an anodic inhibitor supporting the inferences from the time-lapse investigations. These phosphate additions resulted in a 98% reduction in estimated mass loss as measured by SVET demonstrating the effectiveness of phosphate inhibitors for this alloy system.

  18. 49 CFR 195.585 - What must I do to correct corroded pipe?

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false What must I do to correct corroded pipe? 195.585... pipe? (a) General corrosion. If you find pipe so generally corroded that the remaining wall thickness... pipe. However, you need not replace the pipe if you— (1) Reduce the maximum operating pressure...

  19. Study on Mechanism of Concrete Failure Induced by Steel Corrosion under Externally Applied Direct Current

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    With the combination of electrochemical corrosion due to straycurrent in running tunnels of metro, the formula to determine the corrosion products of rebars in reinforced concrete subjected to externally applied direct current is proposed, and the influence of corrosion on stress in concrete is also discussed. Meanwhile, the concept of corrosion stress field and its mathematical formula are presented in the paper. Finally the failure mode of concrete and its shortest breaking time are also analyzed.

  20. Ultrasonic Guided Wave Technology for Noninvasive Assessment of Corrosion-induced Damage in Piping for Pollution Prevention in DOD Fuel Storage Facilities

    Science.gov (United States)

    2011-09-01

    1  1.4  IMPLEMENTATION ISSUES .............................................................................. 2  2.0  INTRODUCTION ...3 2.0 INTRODUCTION The Oil Pollution Act (OPA) of 1990 sets up operational and maintenance requirements for DoD and civilian fuel/oil storage and... magnetostrictive metal strips to the pipe surface by room-temperature cured epoxy. This was preceded by the removal of protective coating from the pipe

  1. Microstructure, mechanical properties, bio-corrosion properties and antibacterial properties of Ti–Ag sintered alloys

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Mian [Key Lab. for Anisotropy and Texture of Materials, Education Ministry of China, Northeastern University, Shenyang 110819 (China); Zhang, Erlin, E-mail: zhangel@atm.neu.edu.cn [Key Lab. for Anisotropy and Texture of Materials, Education Ministry of China, Northeastern University, Shenyang 110819 (China); Zhang, Lan [State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China)

    2016-05-01

    In this research, Ag element was selected as an antibacterial agent to develop an antibacterial Ti–Ag alloy by a powder metallurgy. The microstructure, phase constitution, mechanical properties, corrosion resistance and antibacterial properties of the Ti–Ag sintered alloys have been systematically studied by X-ray diffraction (XRD), scanning electron microscope (SEM), compressive test, electrochemical measurements and antibacterial test. The effects of the Ag powder size and the Ag content on the antibacterial property and mechanical property as well as the anticorrosion property have been investigated. The microstructure results have shown that Ti–Ag phase, residual pure Ag and Ti were the mainly phases in Ti–Ag(S75) sintered alloy while Ti{sub 2}Ag was synthesized in Ti–Ag(S10) sintered alloy. The mechanical test indicated that Ti–Ag sintered alloy showed a much higher hardness and the compressive yield strength than cp-Ti but the mechanical properties were slightly reduced with the increase of Ag content. Electrochemical results showed that Ag powder size had a significant effect on the corrosion resistance of Ti–Ag sintered alloy. Ag content increased the corrosion resistance in a dose dependent way under a homogeneous microstructure. Antibacterial tests have demonstrated that antibacterial Ti–Ag alloy was successfully prepared. It was also shown that the Ag powder particle size and the Ag content influenced the antibacterial activity seriously. The reduction in the Ag powder size was benefit to the improvement in the antibacterial property and the Ag content has to be at least 3 wt.% in order to obtain a strong and stable antibacterial activity against Staphylococcus aureus bacteria. The bacterial mechanism was thought to be related to the Ti{sub 2}Ag and its distribution. - Highlights: • Ti–Ag alloy with up to 99% antibacterial rate was developed by powder metallurgy. • The effects of the Ag powder size and the Ag content on the

  2. Opportunities for permanent corrosion monitoring of pipelines using guided wave tomography

    NARCIS (Netherlands)

    Bloom, J.G.P.; Heerens, G.J.; Volker, A.W.F.; Mast, A.

    2009-01-01

    Corrosion and erosion are two major degradation mechanisms of piping systems and pipelines that both lead to wall thickness loss. To ensure sufficient integrity levels of these assets NDE is currently conducted at time based intervals often associated with shut downs. However, both economical and so

  3. 带包覆层铁磁性金属管道局部腐蚀的脉冲涡流检测%Detection of Localized Corrosion in Ferromagnetic Metal Pipe Under Insulation with Pulsed Eddy Current Testing

    Institute of Scientific and Technical Information of China (English)

    付跃文; 康小伟; 喻星星

    2013-01-01

    为提高脉冲涡流检测技术在检测包覆层下铁磁性金属管道局部腐蚀时的灵敏度,从仿真和实验两个方面对探头设计进行了研究.采用反向联接结构的双线圈作为激励源,达到线圈电流不过大而磁场能够在局部得到聚焦增强的目的.采用有限元仿真比较了单线圈和双线圈激励时磁场及涡流的分布情况和对局部腐蚀型缺陷的检测灵敏度,并进行了系列检测对比实验.仿真与实验结果相一致,表明使用反向联接双线圈激励探头对带包覆层管道局部腐蚀类缺陷进行脉冲涡流检测可以达到远高于单线圈激励检测的灵敏度.本研究可为带包覆层金属管道局部腐蚀的脉冲涡流检测探头设计提供参考.%Probe design was studied by simulation and experiments to improve detection sensitivity of localized corrosion in ferromagnetic metal pipe under insulation with pulsed eddy current(PEC) non-destructive testing.A reversely-connected dual coil was used as excitation source to produce a focused and intense magnetic field without the need of large current in the coil.Finite element method was used to simulate and compare the distribution of magnetic field and eddy current of single coil excitation and dual coil excitation,and a series of experiments were then performed.The experimental results agreed well with the simulation and showed that a much higher sensitivity was achieved using reversely-connected dual coil as excitation than using single coil excitation in the localized corrosion detection of ferromagnetic metal pipe under insulation with PEC testing.This research provides reference for probe design in the localized corrosion detection in metal pipe under insulation with PEC method.

  4. Mechanical factors in primary water stress corrosion cracking of cold-worked stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Hammadi, Rashid Al, E-mail: rashid.alhammadi@fanr.gov.ae [Nuclear Security Division, Federal Authority for Nuclear Regulation, Abu Dhabi (United Arab Emirates); Yi, Yongsun, E-mail: yongsun.yi@kustar.ac.ae [Department of Nuclear Engineering, Khalifa University, Abu Dhabi (United Arab Emirates); Zaki, Wael, E-mail: wael.zaki@kustar.ac.ae [Department of Mechanical Engineering, Khalifa University, Abu Dhabi (United Arab Emirates); Cho, Pyungyeon, E-mail: pyungyeon.cho@kustar.ac.ae [Department of Nuclear Engineering, Khalifa University, Abu Dhabi (United Arab Emirates); Jang, Changheui, E-mail: chjang@kaist.ac.kr [Nuclear and Quantum Engineering Department, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2016-05-15

    Highlights: • PWSCC of cold-worked austenitic stainless steel was studied. • Finite element analysis was performed on a compact tension specimen. • Mechanical fields near a crack tip were evaluated using FEA. • The dependence of mechanical factors on K{sub I} and yield stress was investigated. • The crack tip normal stress was identified as a main factor controlling PWSCC. - Abstract: Finite element analysis was performed on a compact tension specimen to determine the stress and strain distributions near a crack tip. Based on the results, the crack tip stain rates by crack advance and creep rates near crack tip were estimated. By comparing the dependence of the mechanical factors on the stress intensity factor and yield stress with that of the SCC crack growth rates, it was tried to identify the main mechanical factor for the primary water stress corrosion cracking (PWSCC) of cold-worked austenitic stainless steels. The analysis results showed that the crack tip normal stress could be the main mechanical factor controlling the PWSCC, suggesting that the internal oxidation mechanism might be the most probable PWSCC mechanism of cold-worked austenitic stainless steels.

  5. 超级13Cr 油钻杆与4145H 钻铤的电偶腐蚀测试%Galvanic corrosion test on super 13Cr oil drill pipe and 4145H drill collar

    Institute of Scientific and Technical Information of China (English)

    王春生; 曾德智; 施太和; 蔡光林; 张明辉; 陶赟

    2015-01-01

    With the galvanic corrosion problem in threaded connection of super 13Cr oil drill pipe and 4145H drill collar of nitrogen drilling and completion integration string in tight gas reservoir,threaded connection galvanic corrosion specimens of super 13Cr stainless steel and 4145H carbon steel were designed by simulating the practical engineering string structure.The high tempera-ture and high pressure (HTHP)corrosion test was conducted in the HTHP autoclave,where the simulated environment includes CO2 partial pressure of 1.75 MPa,total pressure of 35 MPa,and temperature of 90 ℃ and 110 ℃.Through corrosion weight loss,SEM and EDS analysis,galvanic corrosion characteristics were studied.The results show that,under the simulated envi-ronment,there is no obvious corrosion characteristics in super 13Cr steel after coupling corrosion.While in the junction,the cor-rosion of 4145H steel is accelerated due to the potential difference and gap.At 110 ℃,the corrosion rate of 4145H steel in the gas phase was 0.181 1 mm/a.Because of the large drill collar wall thickness and wide corrosion allowance,4145H carbon steel drill collar which has a good economic applicability can meet production demands.The research results have been applied in the design of nitrogen drilling and completion string in Tarim tight gas reservoir.%针对致密性气藏氮气钻完井一体化管柱中超级13Cr 油钻杆和4145H 钻铤螺纹连接的电偶腐蚀问题,模拟工程实际管柱结构,设计出超级13Cr 不锈钢和4145H 碳钢的螺纹连接电偶腐蚀试样,利用高温高压釜模拟井下腐蚀工况,在 CO2分压为1.75 MPa,总压为35 MPa,温度分别为90℃和110℃条件下进行了高温高压腐蚀测试。通过腐蚀失重、扫描电镜(SEM)和EDS 分析测试,得出了模拟井底工况下13Cr 油钻杆材质和4145H 钻铤材质螺纹连接后的电偶腐蚀情况。实验结果表明:模拟工况下,超级13Cr 和4145H 偶合腐蚀后,超级13Cr

  6. 3PP Corrosion Resistance Quality Control of Bimetal Composite Pipe Used for Submarine Pipeline%海底管线用双金属复合管3LPP防腐质量控制

    Institute of Scientific and Technical Information of China (English)

    卢卫卓; 刘迟; 魏亚秋

    2014-01-01

    According to the structural characteristics of bimetal composite pipe, maritime special welding conditions and high quality requirements for pipe ends, it respectively discussed corrosion resistance quality control from several aspects, such as anticorrosion preparation, coating, water cooling after coating, check lining and pipe end processing, and put forward effective measures for improving coating quality of bimetal composite pipe, that is adopting pipe end protection in whole coating process;subsection preheating, utilizing two or three Intermediate frequency heaters to make surface temperature achieve epoxy powder coating requirements, and as far as possible, make temperature change slowly to reduce loose and take off risks of lining tube and base tube; strict control water cooling time, temperature and water quantity; lining air drying by air compressor after coating, nominal diameter inspection, endoscope inspection, pipe end water-based anti-rust oil spraying and protective seal installation. The quality control measures were applied in bimetal composite pipe 3LPP corrosion resistance project(phase 1) in Pingbei Huangyan oil and gas group, and achieved satisfactory coating quality.%针对双金属复合管的结构特性、海上特殊施焊条件以及对管端的高质量要求,分别从双金属复合管3LPP防腐前准备、喷涂、防腐后水冷、内壁检查和管端处理等环节探讨了防腐质量的控制,并提出了提高双金属复合管防腐质量的有效措施,即:采用防腐全过程管端保护;分段预热、使用2个或3个中频加热器逐步使双金属复合管表面温度达到环氧粉末喷涂要求,尽可能使温度变化缓慢,降低内衬管与基管松脱风险;严控水冷时机、水冷温度及水量;防腐后内壁空压机风干、通径检验、内窥镜检验、管端水性防锈油喷涂及保护套安装密封。质量控制措施应用于平北黄岩油气田群一期双金属复合管3

  7. Evaluation of oxygen corrosion in waterflood and disposal water systems

    Energy Technology Data Exchange (ETDEWEB)

    Conger, H.C.

    1967-01-01

    The case histories presented illustrate how specially polished pipe nipples have been used and examined in the field to evaluate the seriousness of an oxygen corrosion problem. The case histories also illustrate how these test pipe nipples have been used to evaluate actual, not relative, effectiveness of a chemical treatment program to control oxygen corrosion. Data are presented and discussed showing the relationship between corrosion rates of test pipe nipples and actual in-service equipment. The case histories show how corrosion rates based on pipe test nipple data were used to project equipment life under no chemical treatment vs. chemical treatment. A comparative study of corrosion rates between the use of pipe nipples and coupons as a means of measuring oxygen corrosion is discussed. A further comparative study is made between coupon corrosion rates based on weight loss and pit depth penetration.

  8. Study of Mechanical Properties and Characterization of Pipe Steel welded by Hybrid (Friction Stir Weld + Root Arc Weld) Approach

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Yong Chae [ORNL; Sanderson, Samuel [MegaStir Technologies LLC; Mahoney, Murray [Consultant; Wasson, Andrew J [ExxonMobil, Upstream Research Company (URC); Fairchild, Doug P [ExxonMobil, Upstream Research Company (URC); Wang, Yanli [ORNL; Feng, Zhili [ORNL

    2015-01-01

    Friction stir welding (FSW) has recently attracted attention as an alternative construction process for gas/oil transportation applications due to advantages compared to fusion welding techniques. A significant advantage is the ability of FSW to weld the entire or nearly the entire wall thickness in a single pass, while fusion welding requires multiple passes. However, when FSW is applied to a pipe or tube geometry, an internal back support anvil is required to resist the plunging forces exerted during FSW. Unfortunately, it may not be convenient or economical to use internal backing support due to limited access for some applications. To overcome this issue, ExxonMobil recently developed a new concept, combining root arc welding and FSW. That is, a root arc weld is made prior to FSW that supports the normal loads associated with FSW. In the present work, mechanical properties of a FSW + root arc welded pipe steel are reported including microstructure and microhardness.

  9. Corrosion Inhibition Mechanism of Rare Earth Metal on LC4 Al Alloy with Spilt Cell Technique

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A new method of studying the corrosion inhibition mechanism of rare earth metal(REM) on LC4 Al alloy with the spilt cell technique was studied. The principle and experimental method of the spilt cell technique were analyzed. By measuring the change of net-electric current between the two electrodes caused by the change of the amount of oxygen in the solution and the addition of CeCl3, the influence of corrosive performance of CeCl3 on LC4 super-power aluminum alloy in the 0.1 mol*L-1 NaCl solution was investigated. Meanwhile, the conditional changes of pH values, CeCl3 solution, additire and time of performance were also studied. Finally, the features of electrode surface were revealed by using SEM and X-ray energy-dispersive spectrometry (EDS). By combining these with other electric chemical techniques, such as potential-time curve, polarization curve et al.

  10. Friction Stir Welding of Al Alloy 2219-T8: Part II-Mechanical and Corrosion

    Science.gov (United States)

    Kang, Ju; Feng, Zhi-Cao; Li, Ji-Chao; Frankel, G. S.; Wang, Guo-Qing; Wu, Ai-Ping

    2016-09-01

    In Part I of this series, abnormal agglomerations of θ particles with size of about 100 to 1000 µm were observed in friction stir welded AA2219-T8 joints. In this work, the effects of these agglomerated θ particles on the mechanical and corrosion properties of the joints are studied. Tensile testing with in situ SEM imaging was utilized to monitor crack initiation and propagation in base metal and weld nugget zone (WNZ) samples. These tests showed that cracks initiated in the θ particles and at the θ/matrix interfaces, but not in the matrix. The WNZ samples containing abnormal agglomerated θ particles had a similar ultimate tensile stress but 3 pct less elongation than other WNZ samples with only normal θ particles. Measurements using the microcell technique indicated that the agglomerated θ particles acted as a cathode causing the dissolution of adjacent matrix. The abnormal θ particle agglomerations led to more severe localized attack due to the large cathode/anode ratio. Al preferential dissolution occurred in the abnormal θ particle agglomerations, which was different from the corrosion behavior of normal size θ particles.

  11. Corrosion action and passivation mechanism of magnesium alloy in fluoride solution

    Institute of Scientific and Technical Information of China (English)

    LI Jian-zhong; HUANG Jiu-gui; TIAN Yan-wen; LIU Chang-sheng

    2009-01-01

    Corrosion action and passive mechanism of magnesium alloy in the fluoride solution were studied by means of scanning electron microscopy(SEM), energy dispersive X-ray spectroscopy(EDS), and electrochemistry methods. The results show that an insoluble MgF2 film is generated on the surface of magnesium alloy activated in the hydrofluoric acid. And the mass of the deposited MgF2 film may reach a constant value, when the mass ratio of Mg/F on the magnesium alloy surface is fixed at 11.3-1. The activated magnesium alloy gains a 'passivation state' in a mixture of sulfuric acid and hydrofluoric acid at a volume ratio of less than 1.2. At the same time the mass of magnesium alloy is maintained as a function of the time. When the ratio is above 1.4, the mass of magnesium alloy rapidly decreases. The passive film formed through adsorption of HF2- (or H2F3-, H3F4-) ions by the deposited MgF2 film can protect the magnesium alloy from corrosion in fluoride solution, but not in non-fluoride solutions. The passive state is maintained for activated magnesium alloy in an acidic sulfuric nickel solution with added fluoride. If fluoride and carbonate are added to the acidic sulfuric nickel solution, a replacement reaction between magnesium alloy and solution takes place.

  12. Influence of thermo-mechanical processing on microstructure, mechanical properties and corrosion behavior of a new metastable -titanium biomedical alloy

    Indian Academy of Sciences (India)

    Mohsin Talib Mohammed; Zahid A Khan; M Geetha; Arshad N Siddiquee; Prabhash Mishra

    2015-02-01

    This paper presents the results on the influence of different thermo-mechanical processing (TMP) on themechanical properties and electrochemical behavior of newmetastable -alloy Ti–20.6Nb–13.6Zr–0.5V (TNZV). TMP included hot working in below -transus, solution heat treatments at same temperature in different cooling rates in addition to aging. Depending upon the TMP conditions, a wide range of microstructures with varying spatial distributions and morphologies of equiaxed/elongated , phases were attained, allowing for a wide range of mechanical and electrochemical properties to be achieved. The corrosion behavior of studied alloy was evaluated in Ringer’s solution at 37°C using open-circuit potential-time and potentiodynamic polarization measurements.

  13. Long term corrosion of iron in concrete and in atmospheric conditions: a contribution of archaeological analogues to mechanism comprehension

    Energy Technology Data Exchange (ETDEWEB)

    Burger, E.; Demoulin, A.; Dillman, Ph.; Neff, D.; Berge, P. [CEA Saclay, DSM/IRAMIS, Lab. Pierre Sue, 91 - Gif-sur-Yvette (France); Burger, E.; Perrin, St. [CEA Saclay, DEN/DPC/SCCME, Lab. d' Etude de la Corrosion Aqueuse, 91 - Gif-sur-Yvette (France); L' hostis, V. [CEA Saclay, DEN/DPC/SCCME, Lab. d' Etude du Comportement des Betons et Argiles, 91 - Gif-sur-Yvette (France); Dillman, Ph. [IRAMAT-CNRS UMR 5060, 33 - Pessac (France); Millard, A. [CEA Saclay, DEN/DM2S/SEMT, Lab. de Mecanique Systemes et Simulation, 91 - Gif-sur-Yvette (France)

    2009-07-01

    Full text of publication follows: The prediction of iron (or low alloy steel) corrosion on very long term period is necessary in two different purposes: (i) the preservation and conservation of cultural heritage and (ii) the French storage and repository concept for the radioactive wastes. In order to determine the evolution of corrosion processes for very long period, mechanistic models have been developed. In these models that are based on a phenomenological approach to evaluate the average corrosion rates, two different environments are considered: concrete (steel reinforcements) and atmospheric. The study of archaeological analogues is a very pertinent tool for the validation of these models. First, physico-chemical analysis on old corrosion layers lead to a precise localisation and identification of the phases present in the corrosion system. Moreover, experimental reinduced corrosions of ancient samples under controlled parameters (temperature, relative humidity) bring new insight on the mechanisms involved. In particular, one crucial question related to the wet-dry cycle is the localisation of oxygen reduction sites in the rust layer. For this purpose, specific experiments have been set up to re-corrode the ancient samples in marked medium (using {sup 18}O{sub 2}). Samples were exposed to cycling between high and low relative humidity, produced by saline saturated solutions. Then cross-sections of samples obtained were investigated by nuclear reaction analysis (NRA) {sup 18}O(p,{alpha}){sup 15}N on the Pierre Sue Laboratory nuclear microprobe. In this presentation the {sup 18}O distribution profiles are discussed and interpreted in order to bring new insight on corrosion mechanisms. A comparative interpretation is made for each medium (concrete and atmosphere)

  14. Mechanized ultrasonic inspection of austenitic pipe systems; Mechanisierte Ultraschallpruefung von austenitischen Rohrleitungen

    Energy Technology Data Exchange (ETDEWEB)

    Dressler, K.; Luecking, J.; Medenbach, S. [ABB ZAQ GmbH, Essen (Germany)

    1999-08-01

    The contribution explains the system of standard testing methods elaborated by ABB ZAQ GmbH for inspection of austenitic plant components. The inspection tasks explained in greater detail are basic materials testing (straight pipes, bends, and pipe specials), and inspection of welds and dissimilar welds. The techniques discussed in detail are those for detection and sizing of defects. (orig./CB) [Deutsch] Das Ziel dieses Beitrages ist die Vorstellung der von der ABB ZAQ GmbH eingesetzten Standardprueftechniken fuer die Pruefung austenitischer Anlagenkomponenten. Im einzelnen wird die Grundwerkstoffpruefung (Rohre, Boegen, Formstuecke), die Schweissnahtpruefung und die Mischnahtpruefung angesprochen. Es werden dabei die Techniken fuer `Detection` und `Sizing` differenziert betrachtet und erlaeutert. (orig.)

  15. Reducing And Analysizing of Flow Accelerated Corrosion at Thermal Power Plant, Heat Recovery Steam Generators

    Directory of Open Access Journals (Sweden)

    Akın Avşaroğlu

    2017-01-01

    Full Text Available The purpose of this study is to Reducing and Analysing of Flow Accelerated Corrosion in Thermal Plant Heat Recovery Steam Generators. All these studies have been performed in a new and 16 year-old established Combined Cycle Power Plants in Turkey. Corrosion cases have been investigated due to Mechanical Outage Reports at Power Plant in 2011-2015. Flow Accelerated Corrosion study has been based on specific zone related with Economizer Low Pressure connection pipings. It was issued a performance report. Results and lessons learnt from these studies will be used as a preventive action manner in all similar Plants.

  16. Corrosion inhibition mechanisms of aluminum alloy 2024-T3 by selected non-chromate inhibitors

    Science.gov (United States)

    Lopez-Garrity, Omar A.

    The pursuit to find a chromate-alternative has led to the development of several chromate-free aerospace primers and coating systems that offer good protection. However, fundamental understanding of the functionality of the chromate-free pigments that are embedded within these coating systems is lacking. The objective of this study was to understand the fundamental mechanism of corrosion inhibition of aluminum alloy 2024-T3 by molybdate (MoO 42-), silicate (SiO32-), and praseodymium (Pr3+) with the goal of developing the kind of understanding that was accomplished for chromate. Furthermore, since most inhibiting conversion coatings and pigments act by releasing soluble species into the local environment, it was of interest to understand the mechanism of inhibition in aqueous 0.1 M NaCl solution. The mechanism of inhibition of AA2024-T3 by the select non-chromate inhibitors was investigated using various electrochemical, microscopic and spectroscopic techniques. Naturally aerated polarization curves showed that molybdate provided mixed inhibition in near-neutral pH and at a threshold concentration of 0.1 M. The largest effect was a 250 mV increase in the breakdown potential associated with pitting and a 350 mV decrease in the open-circuit potential (OCP). In addition, electrochemical impedance indicated that the corrosion inhibition mechanism is oxygen-dependent owing to the protection afforded by Mo(VI) species. It was proposed that the corrosion inhibition of AA2024-T3 by molybdate may occur following a two-step process whereby molybdate is rapidly reduced to MoO.(OH)2 over the intermetallic particles and is subsequently oxidized to intermediate molybdenum oxides (e.g. Mo4O11) in the presence of oxygen which is reduced. This in turn may lead to a local acidification, promoting the condensation and polymerization of molybdate species in solution to form polymolybdate species (Mo7O24 6- and Mo8O264-). Furthermore, S-phase particle dissolution is decreased

  17. Microstructures, mechanical properties and corrosion resistance of the Zr−xTi (Ag) alloys for dental implant application

    Energy Technology Data Exchange (ETDEWEB)

    Cui, W.F., E-mail: cuiwf@atm.neu.edu.cn; Liu, N.; Qin, G.W.

    2016-06-15

    The Zr−xTi (Ag) alloys were designed for the application of dental implants. The microstructures of Zr−20Ti and Zr−40Ti alloy were observed using optical microscope and transmission electronic microscope. The hardness and compressive tests were performed to evaluate the mechanical properties of the Zr−xTi alloys. The electrochemical behavior of the Zr−xTi alloys with and without 6% Ag was investigated in the acidified artificial saliva containing 0.1% NaF (pH = 4). For comparison, the electrochemical behavior of cp Ti was examined in the same condition. The results show that the quenched Zr−20Ti and Zr−40Ti alloy exhibit acicular martensite microstructures containing twin substructure. They display good mechanical properties with the hardness of ∼330HV, the yield strength of ∼1000 MPa and the strain to fracture of ∼25% at room temperature. Adding 6% Ag to Zr−20Ti alloy enhances the passivity breakdown potential and the self-corrosion potential, but hardly affects the corrosion current density and the impedance modulus. 6% Ag in Zr−40Ti alloy distinctly increases pitting corrosion resistance, which is attributed the formation of thick, dense and stable passive film under the joint action of titanium and silver. In comparison with cp Ti, Zr−40Ti−6Ag alloy possesses the same good corrosion resistance in the rigorous oral environment as well as the superior mechanical properties. - Highlights: • The quenched Zr20Ti and Zr40Ti obtain acicular martensite microstructure. • Zr20Ti and Zr40Ti possess high hardness, strength and strain to fracture. • Increasing Ti content decreases corrosion current density. • Adding Ag enhances passivation breakdown potentials of Zr20Ti and Zr40Ti. • Zr40Ti6Ag has optimum mechanical properties and pitting corrosion resistance.

  18. Microstructures, mechanical and corrosion properties and biocompatibility of as extruded Mg–Mn–Zn–Nd alloys for biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Ying-Long, E-mail: ylzhou@fosu.edu.cn [Department of Mechatronics Engineering, Foshan University, Foshan 528000, Guangdong (China); Li, Yuncang [Institute for Frontier Materials, Deakin University, Victoria 3217 (Australia); Luo, Dong-Mei [Department of Civil Engineering, Foshan University, Foshan 528000, Guangdong (China); Ding, Yunfei; Hodgson, Peter [Institute for Frontier Materials, Deakin University, Victoria 3217 (Australia)

    2015-04-01

    Extruded Mg–1Mn–2Zn–xNd alloys (x = 0.5, 1.0, 1.5 mass %) have been developed for their potential use as biomaterials. The extrusion on the alloys was performed at temperature of 623 K with an extrusion ratio of 14.7 under an average extrusion speed of 4 mm/s. The microstructure, mechanical property, corrosion behavior and biocompatibility of the extruded Mg–Mn–Zn–Nd alloys have been investigated in this study. The microstructure was examined using X-ray diffraction analysis and optical microscopy. The mechanical properties were determined from uniaxial tensile and compressive tests. The corrosion behavior was investigated using electrochemical measurement. The biocompatibility was evaluated using osteoblast-like SaOS2 cells. The experimental results indicate that all extruded Mg–1Mn–2Zn–xNd alloys are composed of both α phase of Mg and a compound of Mg{sub 7}Zn{sub 3} with very fine microstructures, and show good ductility and much higher mechanical strength than that of cast pure Mg and natural bone. The tensile strength and elongation of the extruded alloys increase with an increase in neodymium content. Their compressive strength does not change significantly with an increase in neodymium content. The extruded alloys show good biocompatibility and much higher corrosion resistance than that of cast pure Mg. The extruded Mg–1Mn–2Zn–1.0Nd alloy shows a great potential for biomedical applications due to the combination of enhanced mechanical properties, high corrosion resistance and good biocompatibility. - Highlights: • Extruded Mg–1Mn–2Zn–xNd alloys exhibit very fine microstructures. • Extrusion greatly improves the tensile property and corrosion behavior of alloys. • Tensile strength and ductility of the extruded alloys increase with Nd content. • Increase of Nd does not significantly alter the corrosion resistance. • Mg–1Mn–2Zn–1Nd alloy shows a great potential for biomedical applications.

  19. Crack shape developments and leak rates for circumferential complex-cracked pipes

    Energy Technology Data Exchange (ETDEWEB)

    Brickstad, B.; Bergman, M. [SAQ Inspection Ltd., Stockholm (Sweden)

    1997-04-01

    A computerized procedure has been developed that predicts the growth of an initial circumferential surface crack through a pipe and further on to failure. The crack growth mechanism can either be fatigue or stress corrosion. Consideration is taken to complex crack shapes and for the through-wall cracks, crack opening areas and leak rates are also calculated. The procedure is based on a large number of three-dimensional finite element calculations of cracked pipes. The results from these calculations are stored in a database from which the PC-program, denoted LBBPIPE, reads all necessary information. In this paper, a sensitivity analysis is presented for cracked pipes subjected to both stress corrosion and vibration fatigue.

  20. Impact of chlorinated disinfection on copper corrosion in hot water systems

    Energy Technology Data Exchange (ETDEWEB)

    Montes, J. Castillo [Centre Scientifique et Technique du Bâtiment Nantes, 11 rue Henri Picherit, BP 82341, 44323 Nantes Cedex 03 (France); Laboratoire des Sciences de l’Ingénieur pour l’Environnement, UMR-CNRS 7356, Université de La Rochelle, Avenue Michel Crépeau, 17042 La Rochelle Cedex 1 (France); Hamdani, F. [Laboratoire des Sciences de l’Ingénieur pour l’Environnement, UMR-CNRS 7356, Université de La Rochelle, Avenue Michel Crépeau, 17042 La Rochelle Cedex 1 (France); Creus, J., E-mail: jcreus@univ-lr.fr [Laboratoire des Sciences de l’Ingénieur pour l’Environnement, UMR-CNRS 7356, Université de La Rochelle, Avenue Michel Crépeau, 17042 La Rochelle Cedex 1 (France); Touzain, S. [Laboratoire des Sciences de l’Ingénieur pour l’Environnement, UMR-CNRS 7356, Université de La Rochelle, Avenue Michel Crépeau, 17042 La Rochelle Cedex 1 (France); Correc, O. [Centre Scientifique et Technique du Bâtiment Nantes, 11 rue Henri Picherit, BP 82341, 44323 Nantes Cedex 03 (France)

    2014-09-30

    Highlights: • Impact of disinfectant treatment on the durability of copper pipes. • Synergy between disinfectant concentration and temperature. • Pitting corrosion of copper associated to the corrosion products formation on copper. - Abstract: In France, hot water quality control inside buildings is occasionally ensured by disinfection treatments using temperature increases or addition of sodium hypochlorite (between 0.5 ppm and 1 ppm residual free chlorine). This disinfectant is a strong oxidiser and it could interact with metallic pipes usually used in hot water systems. This work deals with the study of the impact of these treatments on the durability of copper pipes. The objective of this work was to investigate the influence of sodium hypochlorite concentration and temperature on the copper corrosion mechanism. Copper samples were tested under dynamic and static conditions of ageing with sodium hypochlorite solutions ranging from 0 to 100 ppm with temperature at 50 °C and 70 °C. The efficiency of a corrosion inhibitor was investigated in dynamic conditions. Visual observations and analytical analyses of the internal surface of samples was studied at different ageing duration. Corrosion products were characterised by X-ray diffraction and Raman spectroscopy. Temperature and disinfectant were found to considerably affect the copper corrosion mechanism. Surprisingly, the corrosiveness of the solution was higher at lower temperatures. The temperature influences the nature of corrosion products. The protection efficiency is then strongly depend on the nature of the corrosion products formed at the surface of copper samples exposed to the aggressive solutions containing different concentration of disinfectant.

  1. effect of municipal liquid waste on corrosion susceptibility of ...

    African Journals Online (AJOL)

    DR. AMINU

    The corrosion rate of the galvanized steel pipe was measured using the gravimetric technique. ... three stagnant liquid waste samples collected outside the city (SLW4,SLW5, and ... increased exposure time, a layer of protective corrosion ...

  2. Pulse Eddy Current Detection Simulation of the Pipe Corrosion with Insulation Layer%带保温层管道腐蚀缺陷的脉冲涡流检测技术仿真

    Institute of Scientific and Technical Information of China (English)

    辛伟; 丁克勤; 黄冬林; 梁丽红

    2009-01-01

    Pulsed eddy current (PEC) testing is a new type of nondestructive measurement technology developed in recent years, mainly used in the detection of metal pipes and metal plates containing some inner corrosion. An inner corrosion of low-carbon seamless steel pipe was as a detection target, ANSYS finite element simulation model for pulsed eddy current detection was built up, the theoretical basis of the magnetic field simulation was analyzed,and the specific steps of the simulation was set up. These have provided some reference for the application of ANSYS finite element simulation software in the pulsed eddy current detection, and some bases for the research of pulsed eddy current testing equipment.%脉冲涡流检测技术是近几年发展起来的一种新型无损检测技术,可以应用于金属管道和金属板的内腐蚀检测.以低碳无缝钢管的内壁腐蚀作为检测对象,建立了针对脉冲涡流检测的ANSYS有限元仿真模型,分析了磁场仿真的理论基础,列出了仿真分析的具体步骤.为ANSYS有限元仿真软件在脉冲涡流检测中的应用提供了参考,为脉冲涡流检测设备的研制提供了依据.

  3. Dissolution Condensation Mechanism of Stress Corrosion Cracking in Liquid Metals: Driving Force and Crack Kinetics

    Science.gov (United States)

    Glickman, Evgeny E.

    2011-02-01

    Stress corrosion cracking (SCC) in aqueous solution is driven by exothermic reactions of metal oxidation. This stimulus, as well as classical mechanisms of SCC, does not apply to SCC in liquid metals (LMs). In the framework of the dissolution-condensation mechanism (DCM), we analyzed the driving force and crack kinetics for this nonelectrochemical mode of SCC that is loosely called "liquid metal embrittlement" (LME). According to DCM, a stress-induced increase in chemical potential at the crack tip acts as the driving force for out-of-the-tip diffusion mass transfer that is fast because diffusion in LMs is very fast and surface energy at the solid-liquid interface is small. In this article, we review two versions of DCM mechanism, discuss the major physics behind them, and develop DCM further. The refined mechanism is applied then to the experimental data on crack velocity V vs stress intensity factor, the activation energy of LME, and alloying effects. It is concluded that DCM provides a good conceptual framework for analysis of a unified kinetic mechanism of LME and may also contribute to SCC in aqueous solutions.

  4. In vivo oxide-induced stress corrosion cracking of Ti-6Al-4V in a neck-stem modular taper: Emergent behavior in a new mechanism of in vivo corrosion.

    Science.gov (United States)

    Gilbert, Jeremy L; Mali, Sachin; Urban, Robert M; Silverton, Craig D; Jacobs, Joshua J

    2012-02-01

    In vivo modular taper corrosion in orthopedic total joint replacements has been documented to occur for head-neck tapers, modular-body tapers, and neck-stem tapers. While the fretting corrosion mechanism by which this corrosion occurs has been described in the literature, this report shows new and as yet unreported mechanisms at play. A retrieved Ti-6Al-4V/Ti-6Al-4V neck-stem taper interface, implanted for 6 years is subjected to failure analysis to document taper corrosion processes that lead to oxide driven crack formation on the medial side of the taper. Metallurgical sectioning techniques and scanning electron microscopy analysis are used to document the taper corrosion processes. The results show large penetrating pitting attack of both sides of the taper interface where corrosion selectively attacks the beta phase of the microstructure and eventually consumes the alpha phase. The pitting attack evolves into plunging pits that ultimately develop into cracks where the crack propagation process is one of corrosion resulting in oxide formation and subsequent reorganization. This process drives open the crack and advances the front by a combination of oxide-driven crack opening stresses and corrosion attack at the tip. The oxide that forms has a complex evolving structure including a network of transport channels that provide access of fluid to the crack tip. This emergent behavior does not appear to require continued fretting corrosion to propagate the pitting and cracking. This new mechanism is similar to stress corrosion cracking where the crack tip stresses arise from the oxide formation in the crack and not externally applied tensile stresses.

  5. Corrosion and mechanical performance of reinforced mortar and concrete made with MSWI bottom ash

    Directory of Open Access Journals (Sweden)

    Rita Ávila

    2017-07-01

    Full Text Available Electrochemical monitoring was performed to evaluate the influence of municipal solid waste incineration residues (MSWI made concrete, on reinforcement corrosion, using four different steel reinforce-ments grades, traditional carbon steel B-500-SD and three stainless steels, the austenite AISI 304, duplex AISI 2304, and lean-duplex AISI 2001, embedded in mortars manufactured using bottom ash as aggregates from the incineration of municipal solid waste (MSW, in partial and total substitution of natural aggregate. In addition, it has been studied the mechanical behaviour of the mortar and concrete matrix in the presence of MSWI aggre-gates. The use of MSWI bottom ash as an aggregate, results in a notable improvement of the resistance charac-teristics of conventional mortar and concrete, made out only of natural aggregate. Moreover, electrochemical measures show that the steels remain in passive state throughout all the exposure period (3 years.

  6. Nickel-Titanium Alloys: Corrosion "Proof" Alloys for Space Bearing, Components and Mechanism Applications

    Science.gov (United States)

    DellaCorte, Christopher

    2010-01-01

    An intermetallic nickel-titanium alloy, 60NiTi (60 wt% Ni, 40 wt% Ti), is shown to be a promising candidate tribological material for space mechanisms. 60NiTi offers a broad combination of physical properties that make it unique among bearing materials. 60NiTi is hard, electrically conductive, highly corrosion resistant, readily machined prior to final heat treatment, and is non-magnetic. Despite its high Ti content, 60NiTi is non-galling even under dry sliding. No other bearing alloy, metallic or ceramic, encompasses all of these attributes. Since 60NiTi contains such a high proportion of Ti and possesses many metallic properties, it was expected to exhibit poor tribological performance typical of Ti alloys, namely galling type behavior and rapid lubricant degradation. In this poster-paper, the oil-lubricated behavior of 60NiTi is presented.

  7. Modelling of Corrosion Cracks

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    Modelling of corrosion cracking of reinforced concrete structures is complicated as a great number of uncertain factors are involved. To get a reliable modelling a physical and mechanical understanding of the process behind corrosion in needed.......Modelling of corrosion cracking of reinforced concrete structures is complicated as a great number of uncertain factors are involved. To get a reliable modelling a physical and mechanical understanding of the process behind corrosion in needed....

  8. Analysis on Corrosion Mechanism of Rolling Bearings%滚动轴承锈蚀机理分析

    Institute of Scientific and Technical Information of China (English)

    王子君

    2012-01-01

    重点探讨了金属在大气环境的电化学腐蚀机理,分析了影响轴承锈蚀的主要因素,提出了轴承防锈的基本思路和方法.大气环境中轴承的锈蚀主要是由电化学腐蚀产生,偶然伴随化学腐蚀反应.提高轴承材料的防腐性能,利用可靠的防锈材料在轴承表面形成完整致密的保护膜,严格控制工作环境的温湿度及其变化,可以有效保证轴承在生产和使用中不发生锈蚀.%The electrochemical corrosion mechanism of metal in the atmospheric environment is mainly discussed, the main factors influencing bearing corrosion are analyzed, and the basic idea and rust - resistance method are put forward for bearing. The bearing corrosion in the atmospheric environment is mainly induced by electrochemical corrosion, accidentally followed along with chemical corrosion. The corrosion prevention in the bearing production and use is guaranteed by improving the anti - corrosion property of bearing material, using reliable rust - resisting material which can form a complete and compact protective film in the bearing surface, strictly controlling the temperature and humidity of the work environment and their variations.

  9. Impact of chlorinated disinfection on copper corrosion in hot water systems

    Science.gov (United States)

    Montes, J. Castillo; Hamdani, F.; Creus, J.; Touzain, S.; Correc, O.

    2014-09-01

    In France, hot water quality control inside buildings is occasionally ensured by disinfection treatments using temperature increases or addition of sodium hypochlorite (between 0.5 ppm and 1 ppm residual free chlorine). This disinfectant is a strong oxidiser and it could interact with metallic pipes usually used in hot water systems. This work deals with the study of the impact of these treatments on the durability of copper pipes. The objective of this work was to investigate the influence of sodium hypochlorite concentration and temperature on the copper corrosion mechanism. Copper samples were tested under dynamic and static conditions of ageing with sodium hypochlorite solutions ranging from 0 to 100 ppm with temperature at 50 °C and 70 °C. The efficiency of a corrosion inhibitor was investigated in dynamic conditions. Visual observations and analytical analyses of the internal surface of samples was studied at different ageing duration. Corrosion products were characterised by X-ray diffraction and Raman spectroscopy. Temperature and disinfectant were found to considerably affect the copper corrosion mechanism. Surprisingly, the corrosiveness of the solution was higher at lower temperatures. The temperature influences the nature of corrosion products. The protection efficiency is then strongly depend on the nature of the corrosion products formed at the surface of copper samples exposed to the aggressive solutions containing different concentration of disinfectant.

  10. 孔板管道下游流动加速腐蚀速率数值模拟研究%Numerical Simulation Study of Flow Accelerated Corrosion in Downstream of Orifice Pipe

    Institute of Scientific and Technical Information of China (English)

    彭翊; 韩睿璇; 陈耀东

    2015-01-01

    采用计算流体力学方法中的 k‐ε模型模拟了孔板管道下游管壁与流体间的传质系数分布,并利用Sanchez‐Caldera流动加速速率预测模型计算了孔板管道下游的流动加速腐蚀速率分布。结果表明,孔径比的减小会导致流动加速腐蚀敏感部位向孔板下游移动,入口流速的增大对孔板下游流动加速腐蚀敏感部位的位置无明显影响,pH值的增大能有效减小流动加速腐蚀速率。%The mass transfer coefficient distribution between the pipe wall and fluid was simulated by the k‐εmodel of computational fluid dynamic method .The distributions of flow accelerated corrosion (FAC) rate in downstream of orifice pipe were calculated by Sanchez‐Caldera model .T he results show that the sensitive position of FAC moves to downstream as decreasing orifice diameter ratio .However ,the increase of inlet velocity has no significant influence on sensitive position of FAC .The FAC rate can be effective‐ly reduced with increasing pH value .

  11. Toughening mechanism of lined Al2O3-ZrO2 multiphase ceramics in SHS composite pipes

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Hypoeutectic and hypereutectic Al2O3-ZrO2 multiphase ceramics-lined composite pipes were produced by using the gravitational separation self-propagate high-temperature synthesis (SHS) process.The microstructure of the ceramics was observed by means of SEM and EPMA.The fracture toughness of the multiphase ceramics was tested by using the Vickers indentation method.The ceramics is 15.23 Mpa.m1/2.The toughening mechanisms were systematically investigated by means of SEM and XRD.The results show that the bridging toughening mechanism, stress induced ZrO2 transformation toughening mechanism, and microcrack toughening mechanism are the predominant toughening mechanism.

  12. 49 CFR 192.475 - Internal corrosion control: General.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control: General. 192.475... Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by... taken to minimize internal corrosion. (b) Whenever any pipe is removed from a pipeline for any...

  13. Naphthenic corrosion resistance, mechanical properties and microstructure evolution of experimental Cr-Mo steels with high Mo content

    Directory of Open Access Journals (Sweden)

    Lorena Braga Moura

    2012-04-01

    Full Text Available One method to face the effects of naphthenic acid corrosion in petroleun refining plants is to use alloys with good resistance to this kind of corrosion. For this purpose, molybdenum additions to chromium containing steels are specially recommended. In this work, experimental Fe-9Cr-xMo (x = 5, 7 and 9 wt. (% ingots were cast, forged and hot rolled before being tested in a naphthenic acid environment. Evolution of the mechanical properties with composition is presented. The precipitation and dissolution of phases were investigated with the help of Thermocalc and electron backscattered diffraction (EBSD.

  14. Finite Element Analysis of Residual Strength of Pipe with Hemispheric Corrosion Defect%含半球形腐蚀缺陷钢管剩余强度的有限元分析

    Institute of Scientific and Technical Information of China (English)

    杨专钊; 刘道新; 张晓化

    2013-01-01

    通过有限元方法分析了含单个不同深度半球形腐蚀缺陷钢管,在不同服役条件(压力状态)下的应力和应变状态,即缺陷深度和半径分别为1/8,1/4和1/2钢管公称壁厚时,得出不同状态下von Mises等效应力和von Mises等效应变分布情况.同时计算了含不同深度半球形缺陷管道的剩余强度,并给出剩余强度随缺陷深度的经验公式,结果显示含半球形缺陷管道剩余强度随缺陷深度的增加而线性降低.%The situation of stress and strain was analyzed by Finite Element Analysis (FEA) for the corroded line pipe by deferent inner pressures and with single hemispheric corrosion defects,of which the radius and depth were set as t/8,t/4 and t/2 (t,the pipe wall thickness) respectively.Meanwhile,the residual strength of the pipes with corresponding defects were calculated respectively,as well as the empirical equation that relates to the residual strength and depth-thickness ratio d/t,was established,which shown that the residual strength decreased linearly with the increasing d/t.

  15. Mechanical, tribological and corrosion properties of CrBN films deposited by combined direct current and radio frequency magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Jahodova, Vera [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, 638075 (Singapore); Koszalin University of Technology, Sniadeckich 2, 75-0453 Koszalin (Poland); Technical University of Liberec, Studentska 1402/2, 461 17 Liberec1 (Czech Republic); Ding, Xing-zhao, E-mail: xzding@SIMTech.a-star.edu.sg [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, 638075 (Singapore); Seng, Debbie H.L. [Institute of Materials Research and Engineering, 3 Research Link, 117602 (Singapore); Gulbinski, W. [Koszalin University of Technology, Sniadeckich 2, 75-0453 Koszalin (Poland); Louda, P. [Technical University of Liberec, Studentska 1402/2, 461 17 Liberec1 (Czech Republic)

    2013-10-01

    Cr–B–N films were deposited on stainless steel substrates by a combined direct current and radio frequency (RF) reactive unbalanced magnetron sputtering process using two elemental Cr and one compound BN targets. Boron content in the as-deposited films was qualitatively analyzed by time-of-flight secondary ion mass spectroscopy. Films' microstructure, mechanical and tribological properties were characterized by X-ray diffraction, nanoindentation and pin-on-disk tribometer experiments. Corrosion behavior of the Cr–B–N films was evaluated by electrochemical potentiodynamic polarization method in a 3 wt.% NaCl solution. All the films were crystallized into a NaCl-type cubic structure. At lower RF power applied on the BN target (≤ 600 W), films are relatively randomly oriented, and films' crystallinity increased with increasing RF power. With increasing RF power further (≥ 800 W), films became (200) preferentially oriented, and films' crystallinity decreased gradually. With incorporation of a small amount of boron atoms into the CrN films, hardness, wear- and corrosion-resistance were all improved evidently. The best wear and corrosion resistance was obtained for the film deposited with 600 W RF power applied on the BN target. - Highlights: • CrBN films deposited by direct current and radio frequency magnetron sputtering. • CrBN exhibited higher hardness, wear- and corrosion-resistance than pure CrN. • The best wear- and corrosion-resistant film was deposited with 600 W RF power.

  16. Study on the Effects of Corrosion Inhibitor According to the Functional Groups for Cu Chemical Mechanical Polishing in Neutral Environment

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sang Won; Kim, Jae Jeong [Institute of Chemical Process, Seoul National University, Seoul (Korea, Republic of)

    2015-08-15

    As the aluminum (Al) metallization process was replaced with copper (Cu), the damascene process was introduced, which required the planarization step to eliminate over-deposited Cu with Chemical Mechanical Polishing (CMP) process. In this study, the verification of the corrosion inhibitors, one of the Cu CMP slurry components, was conducted to find out the tendency regarding the carboxyl and amino functional group in neutral environment. Through the results of etch rate, removal rate, and chemical ability of corrosion inhibitors based on 1H-1,2,4-triazole as the base corrosion inhibitor, while the amine functional group presents high Cu etching ability, carboxyl functional group shows lower Cu etching ability than base-corrosion inhibitor which means that it increases passivation effect by making strong passivation layer. It implies that the corrosion inhibitor with amine functional group was proper to apply for 1st Cu CMP slurry owing to the high etch rate and with carboxyl functional group was favorable for the 2nd Cu CMP slurry due to the high Cu removal rate/dissolution rate ratio.

  17. Anti-corrosion mechanism of epoxy-resin and different content Fe2O3 coatings on magnesium alloy

    Science.gov (United States)

    Jin, Tao; Kong, Fan-mei; Bai, Rui-qin; Zhang, Ru-liang

    2016-10-01

    In this study, anti-corrosion coatings were prepared and coated successfully on magnesium alloy substrates by mixing nanopowders, solvent, curing agent with epoxy resin. The effect of the amount of iron trioxide (Fe2O3) on the adhesion strength and corrosion resistance on magnesium alloy was investigated with standard protocols, and electrochemical measurements were also made in 3.5 wt.% NaCl solutions. The surface morphology and corrosion mechanism after corrosion tests was characterized using FESEM analysis. Nanoparticles in matrix acted as filler, and interstitial cross-linked spaces and other coating artifacts regions (micro cracks and voids) would all affect the anti-corrosion properties of coating. The results showed the proper powder content not only provided adhesion strength to these coatings but also improved obviously their anticorrosion. Hydrogen bound to the amine nitrogen (1N) could take part in the curing process rather than hydrogen of the amide site due to the smaller ΔG and the more stable configuration.

  18. Corrosion Inhibiting Mechanism of Nitrite Ion on the Passivation of Carbon Steel and Ductile Cast Iron for Nuclear Power Plants

    Directory of Open Access Journals (Sweden)

    K. T. Kim

    2015-01-01

    Full Text Available While NaNO2 addition can greatly inhibit the corrosion of carbon steel and ductile cast iron, in order to improve the similar corrosion resistance, ca. 100 times more NaNO2 addition is needed for ductile cast iron compared to carbon steel. A corrosion and inhibition mechanism is proposed whereby NO2- ion is added to oxidize. The NO2- ion can be reduced to nitrogen compounds and these compounds may be absorbed on the surface of graphite. Therefore, since nitrite ion needs to oxidize the surface of matrix and needs to passivate the galvanic corroded area and since it is absorbed on the surface of graphite, a greater amount of corrosion inhibitor needs to be added to ductile cast iron compared to carbon steel. The passive film of carbon steel and ductile cast iron, formed by NaNO2 addition showed N-type semiconductive properties and its resistance, is increased; the passive current density is thus decreased and the corrosion rate is then lowered. In addition, the film is mainly composed of iron oxide due to the oxidation by NO2- ion; however, regardless of the alloys, nitrogen compounds (not nitrite were detected at the outermost surface but were not incorporated in the inner oxide.

  19. Fitness for service assessment of degraded CANDU feeder piping-Canadian regulatory expectations

    Energy Technology Data Exchange (ETDEWEB)

    Jin, John C., E-mail: john.jin@cnsc-ccsn.gc.c [Operational Engineering Assessment Div., Canadian Nuclear Safety Commission (Canada); Awad, Raoul [Operational Engineering Assessment Div., Canadian Nuclear Safety Commission (Canada)

    2011-03-15

    Allowance for the continued operation of feeder piping at some Canadian CANDU stations, which is experiencing active degradation mechanisms, has been based primarily on augmented inspection practices and conservative fitness for service assessments. The major degradation mechanisms identified to date are: pipe wall thinning due to Flow Accelerated Corrosion (FAC) and service induced cracking due to Intergranular Cracking due to Stress Corrosion Cracking (SCC) and potentially Low Temperature Creep Cracking (LTCC) mechanisms. Given that currently available industry codes and standards do not provide sufficient guidelines/criteria for assessing the degradation of feeder pipes, the Canadian Nuclear Safety Commission (CNSC) has asked the utilities to establish feeder pipe specific procedures to provide reasonable assurance that the risk associated with the feeder degradation is maintained at an acceptably low level. In response to this requirement, the Canadian CANDU industry has developed and continued to update feeder fitness for service guidelines to provide evaluation procedures and industry standard acceptance criteria for assessing the structural integrity of the feeder pipes. The scope and frequency of inspections are determined based on the results of the fitness for service assessments taking into account the relative susceptibility of feeder pipes to each specific degradation mechanism. While industry practices for the management of degraded feeder pipes have, in general, been complied with the regulatory expectations, outstanding issues still remain. Major regulatory concerns include uncertainties associated with limitations in both the inspection techniques and the mechanistic understanding of the degradation processes, which can impede inspection planning and fitness for service assessments. This paper presents the regulator's view of the current situation with respect to degradation of feeder piping, its implications for nuclear safety and the

  20. Developing a program to identify and track corrosion in nuclear plant raw water systems

    Energy Technology Data Exchange (ETDEWEB)

    Spires PE, G.V. [KTA - Tator Inc., Pittsburgh, Pennsylvania (United States); Pickles PE, S.B. [Senior Engineer, Ontario Power Generation, Ontario (Canada)

    2001-07-01

    Findings derived from a comprehensive plant performance survey at Ontario Power Generation's (OPG) nuclear units convinced management that it would be prudent to expand the ongoing power piping Flow Accelerated Corrosion (FAC) induced wall thinning base-lining and tracking program to encompass the raw cooling water systems as well. Such systems are subject to a distinctly different class of pipe wall thinning (PWT) mechanisms than the FAC that degrades high-energy power piping. This paper describes the PWT corrosion assessment and tracking program that has been developed and is currently being implemented by OPG for the raw cooling water (i.e., Service Water) systems within it's nuclear generating stations. Interim databases are used prior to initial inspection rounds to catalogue the prospective locations. For each piping system being surveyed, these interim databases include physical coordinates for the candidate locations, the type and wall thickness of the components comprising each location, ranking indications and recommended NDE methodologies as a function of the anticipated corrosion mechanisms. Rationales for assessing corrosion susceptibility and ranking prospective inspection sites are expounded by way of notations built into the database. (authors)

  1. Mechanism of protective film formation during CO2 corrosion of X65 pipeline steel

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Electrochemical techniques,X-ray diffraction (XRD),and scanning electron microscopy (SEM) were applied to study the corrosion behaviors of X65 steel in static solution with carbon dioxide (CO2 at 65℃.The results show that iron carbonate (FeCO3deposits on the steel surface as a corrosion product scale.This iron carbonate scale acts as a barrier to CO2 corrosion,and can reduce the general corrosion rate.The protection ability of the scale is closely related to the scale morphological characteristics.

  2. Evaluation of the bactericidal characteristics of nano-copper oxide or functionalized zeolite coating for bio-corrosion control in concrete sewer pipes

    Energy Technology Data Exchange (ETDEWEB)

    Haile, T. [Department of Civil and Environmental Engineering, University of Western Ontario, 1151 Richmond Street, London, Ont., N6A 5B8 (Canada); Materials Technology Laboratory Branch, Natural Resources Canada, 562 Booth Street, Ottawa, Ont., K1A 0G1 (Canada)], E-mail: thaile@uwo.ca; Nakhla, G. [Department of Chemical and Biochemical Engineering, University of Western Ontario, 1151 Richmond Street, London, Ont., N6A 5B8 (Canada)], E-mail: gnakhla@eng.uwo.ca; Allouche, E. [Trenchless Technology Centre, Louisiana Tech University, 600 W. Arizona, Engr. Annex, P.O. Box 10348, Ruston, LA 71272 (United States)], E-mail: allouche@LaTech.edu; Vaidya, S. [Trenchless Technology Centre, Louisiana Tech University, 600 W. Arizona, Engr. Annex, P.O. Box 10348, Ruston, LA 71272 (United States)], E-mail: sva008@LaTech.edu

    2010-01-15

    The bactericidal characteristics of nano-copper oxide or functionalized zeolite coated concrete pipes against Acidithiobacillus thiooxidans were studied by measuring the temporal variation of bacterial dry cell weight measurement, cellular Adenosine Triphosphate production, as well as oxygen uptake rate of the aforementioned bacterium. Uncorroded (UC), severely corroded (SC), and moderately corroded (MC) concrete pipes were electrochemically coated with a nano-copper oxide, while another uncorroded concrete pipe was used to apply functionalized zeolite coating (Z2). Specimens were characterized by field emission-scanning electron microscopy, and optical microscopy. Oxygen uptake rate of the bacterium was the highest in UC followed by the MC. Oxygen uptake rate and cellular Adenosine Triphosphate decreased progressively in Z2 and SC throughout the duration of the experiment due to decline in live bacterial cell. The maximum bacterial specific growth rate was 1.1 x 10{sup -2} day{sup -1} for both UC and MC, with a decay rates varying from 1.4 x 10{sup -2} to 2.6 x 10{sup -2} day{sup -1}. The minimum concentration limits for the inhibition of the bacterium in the nano-copper oxide coated concrete pipes ranged from 2.3 mg to 2.6 mg Cu per mg dry cell weight.

  3. Ultrasonic Guided Wave Technology for Non-Invasive Assessment of Corrosion-Induced Damage in Piping for Pollution Prevention in DOD Fuel Storage Facilities

    Science.gov (United States)

    2011-08-01

    put on in a three step process per manufacturer’s recommendation. A relatively thin coat of bitumen mastic was applied to the entire pipe surface...Figure. Summary of Ultrasonic Guided Wave Results The Signal peak height from each data trace was extracted and then plotted versus percent CSAL in

  4. Structure, mechanical property and corrosion behaviors of (HA+β-TCP)/Mg-5Sn composite with interpenetrating networks.

    Science.gov (United States)

    Wang, X; Li, J T; Xie, M Y; Qu, L J; Zhang, P; Li, X L

    2015-11-01

    In this paper, a novel (Hydroxyapatite+β-tricalcium phosphate)/Mg-5Sn ((HA+β-TCP)/Mg-5Sn) composite with interpenetrating networks was fabricated by infiltrating Mg-5Sn alloy into porous HA+β-TCP using suction casting technique. The structure, mechanical property and corrosion behaviors of the composite have been evaluated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), mechanical testing, electrochemical and immersion test. It is shown that the molten Mg-5Sn alloy has infiltrated not only into the pores but also into the struts of the HA+β-TCP scaffold to forming a compact composite. The microstructure observation also shows that the Mg alloy contacts to the HA+β-TCP closely, and no reaction layer can be found between Mg-5Sn alloy and scaffold. The ultimate compressive strength of the composite is as high as 176MPa, which is about four fifths of the strength of the Mg-5Sn bulk alloy. The electrochemical and immersion tests indicate that the corrosion resistance of the composite is better than that of the Mg-5Sn bulk alloy. The corrosion products on the composite surface are mainly Mg(OH)2, Ca3(PO4)2 and HA. Appropriate mechanical and corrosion properties of the (HA+β-TCP)/Mg-5Sn composite indicate its possibility for new bone tissue implant materials.

  5. Effect of Nb on the Microstructure, Mechanical Properties, Corrosion Behavior, and Cytotoxicity of Ti-Nb Alloys

    Directory of Open Access Journals (Sweden)

    Mi-Kyung Han

    2015-09-01

    Full Text Available In this paper, the effects of Nb addition (5–20 wt % on the microstructure, mechanical properties, corrosion behavior, and cytotoxicity of Ti-Nb alloys were investigated with the aim of understanding the relationship between phase/microstructure and various properties of Ti-xNb alloys. Phase/microstructure was analyzed using X-ray diffraction (XRD, SEM, and TEM. The results indicated that the Ti-xNb alloys (x = 10, 15, and 20 wt % were mainly composed of α + β phases with precipitation of the isothermal ω phase. The volume percentage of the ω phase increased with increasing Nb content. We also investigated the effects of the alloying element Nb on the mechanical properties (including Vickers hardness and elastic modulus, oxidation protection ability, and corrosion behavior of Ti-xNb binary alloys. The mechanical properties and corrosion behavior of Ti-xNb alloys were found to be sensitive to Nb content. These experimental results indicated that the addition of Nb contributed to the hardening of cp-Ti and to the improvement of its oxidation resistance. Electrochemical experiments showed that the Ti-xNb alloys exhibited superior corrosion resistance to that of cp-Ti. The cytotoxicities of the Ti-xNb alloys were similar to that of pure titanium.

  6. Bending of pipes with inconel cladding; Curvamento de tubos revestidos com inconel

    Energy Technology Data Exchange (ETDEWEB)

    Nachpitz, Leonardo; Menezes, Carlos Eduardo B.; Vieira, Carlos R. Tavares [PROTUBO, Macae, RJ (Brazil)

    2008-07-01

    The pipes used in offshore equipment, such as wet Christmas trees, sub sea manifolds and rigid platform risers, as well as some pipes for refineries and ships, must have mechanical resistance to high pressure and also be resistant to corrosion from acids. Some special materials, such as stainless steel, duplex and super duplex steel are used to resolve this problem, but the cost is very high. Besides the problem of cost, these materials have other drawbacks, such as the difficulty of welding them, a technology mastered in few countries. As a better alternative, the use has been increasing of carbon steel and API pipes coated internally with inconel by welding deposition. This groundbreaking technology, of proven efficiency, has a far superior cost-benefit relation. Carbon steel and API pipes, besides having better mechanical resistance to high pressure and corrosion resistance, can be fabricated with technology mastered worldwide. Nickel alloys, such as inconel, are highly resistant to corrosion and temperature, and in these aspects are better than stainless steels. The pipes for transportation equipment and for refining hydrocarbons, as mentioned above, require various turns and special geometries, which generally are solved by the use of bends and spools made by high-frequency induction. This technology, already well established for various carbon and stainless steels, was developed to work with pipes coated internally with inconel (inconel cladding). Therefore, our work describes the process of fabricating bends from API steel pipes with inconel cladding, demonstrating the efficacy of this technology along with its quality gains and cost reduction. (author)

  7. Effects of Pressure Fluctuation on Flow-Accelerated Corrosion in the Downstream of Orifice Nozzle

    Science.gov (United States)

    Shakouchi, Toshihiko; Suzuki, Takayuki; Kugimoto, Mitsuo; Tsujimoto, Koichi; Ando, Toshitake

    In the piping system of power plants, pipe wall thinning caused by flow-accelerated corrosion (FAC), liquid droplet impingement (LDI) erosion, and cavitation Erosion (C/E), is a very serious problem because it leads to serious damage and eventual destruction of the piping system [1]-[6]. In this study, pipe wall thinning caused by FAC in the downstream of an orifice nozzle (flow meter) was examined. Experimental Analyses were performed to clarify the characteristics of FAC, its generation mechanism, and the prediction of the thinning and reduction of the pipe wall. The corrosion pattern on the pipe wall was also examined through an experimental simulation. This simulation clarified that the occurrence of thinning mainly depend on the amount of pressure fluctuation p' on the pipe wall. It was also found that the wall thinning rate can be estimated using p' and that the suppression of p' can be realized by replacing the orifice nozzle with a tapered one having an angle to the upstream.

  8. Application of the results of pipe stress analyses into fracture mechanics defect analyses for welds of nuclear piping components; Uebernahme der Ergebnisse von Rohrsystemanalysen (Spannungsanalysen) fuer bruchmechanische Fehlerbewertungen fuer Schweissnaehte an Rohrleitungsbauteilen in kerntechnischen Anlagen

    Energy Technology Data Exchange (ETDEWEB)

    Dittmar, S.; Neubrech, G.E.; Wernicke, R. [TUeV Nord SysTec GmbH und Co.KG (Germany); Rieck, D. [IGN Ingenieurgesellschaft Nord mbH und Co.KG (Germany)

    2008-07-01

    For the fracture mechanical assessment of postulated or detected crack-like defects in welds of piping systems it is necessary to know the stresses in the un-cracked component normal to the crack plane. Results of piping stress analyses may be used if these are evaluated for the locations of the welds in the piping system. Using stress enhancing factors (stress indices, stress factors) the needed stress components are calculated from the component specific sectional loads (forces and moments). For this procedure the tabulated stress enhancing factors, given in the standards (ASME Code, German KTA regulations) for determination and limitation of the effective stresses, are not always and immediately adequate for the calculation of the stress component normal to the crack plane. The contribution shows fundamental possibilities and validity limits for adoption of the results of piping system analyses for the fracture mechanical evaluation of axial and circumferential defects in welded joints, with special emphasis on typical piping system components (straight pipe, elbow, pipe fitting, T-joint). The lecture is supposed to contribute to the standardization of a code compliant and task-related use of the piping system analysis results for fracture mechanical failure assessment. [German] Fuer die bruchmechanische Bewertung von postulierten oder bei der wiederkehrenden zerstoerungsfreien Pruefung detektierten rissartigen Fehlern in Schweissnaehten von Rohrsystemen werden die Spannungen in der ungerissenen Bauteilwand senkrecht zur Rissebene benoetigt. Hierfuer koennen die Ergebnisse von Rohrsystemanalysen (Spannungsanalysen) genutzt werden, wenn sie fuer die Orte der Schweissnaehte im Rohrsystem ausgewertet werden. Mit Hilfe von Spannungserhoehungsfaktoren (Spannungsindizes, Spannungsbeiwerten) werden aus den komponentenweise berechneten Schnittlasten (Kraefte und Momente) die benoetigten Spannungskomponenten berechnet. Dabei sind jedoch die in den Regelwerken (ASME

  9. Connections between morphological and mechanical evolution during galvanic corrosion of micromachined polycrystalline and monocrystalline silicon

    Science.gov (United States)

    Miller, David C.; Boyce, Brad L.; Kotula, Paul G.; Stoldt, Conrad R.

    2008-06-01

    Many microsystems fabrication technologies currently employ a metallic overlayer, such as gold, in electrical contact with silicon structural layers. During postprocessing in hydrofluoric-based acid solutions, a galvanic cell is created between the silicon and the metallic layer. Micromachined tensile specimens reveal that such etching in the presence of a galvanic cell can cause a catastrophic reduction in the tensile strength and apparent modulus of silicon. Detailed failure analysis was also used to compare fractured corroded Si to otherwise identical reference specimens via surface based (electron and scanning probe) microscopy as well as cross-section based structural- and composition-characterization techniques. For both polycrystalline and single-crystal silicon, galvanic corrosion can result in a thick corroded surface layer created via porous silicon formation, and/or generalized material removal depending on the etch chemistry and conditions. Under certain etching conditions, the porous silicon formation process results in cavity formation as well as preferential grain-boundary attack leading to intergranular fracture. The nature and severity of corrosion damage are shown to be influenced by the surface wetting characteristics of the etch chemistry, with poor wetting resulting in localized attack facilitated by the microstructure and good wetting resulting in generalized attack. The measured stiffness of the tensile specimens can be used to determine the effective modulus and porosity of the corroded surface layer. Extending beyond previous investigations, the present work examines the quantitative connection between the choice of chemical etchant, the corresponding damage morphology, and the resulting degradation in strength and apparent modulus. The present work also uniquely identifies important differences in polycrystalline and single-crystal Si based on their disparate damage evolution and related mechanical performance.

  10. Investigation of corrosion and wear mechanisms in hard material-reinforced duplex steel coatings; Untersuchungen zum Korrosions- und Verschleissverhalten von hartstoffverstaerkten `Duplex`-Schutzschichten. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Bouaifi, B. [Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany). Inst. fuer Schweisstechnik und Trennende Fertigungsverfahren; Goellner, J. [Technische Univ. Magdeburg (Germany). Inst. fuer Werkstofftechnik und Werkstoffpruefung

    1998-09-30

    The hard-material reinforced duplex steel coatings were deposited by plasma arc two-powder surfacing. By varying the angle of the hard materials feeding process, the deposition of the carbides was optimized so that they are deposited into the matrix in the trailing zone of the welding torch under conditions of very low thermal effects near the freezing point of the weld pool. Microstructural studies revealed that the deposition of the hard materials prevents devlopment of the typical, ferritic-austenitic microstructure of duplex steels. Due to a dissolution and diffusion process, the microstructure of the matrix takes up carbon and chromium or tungsten, depending on the carbide, thus enhancing the austenitic material in the microstructure. The wear behaviour of the surface deposits was found to be very good, wear being reduced by a factor of 6, irrespective of the type of carbide. The friction-affected surfaces showed no dissolving effects or cracking. The corrosion behaviour in sulfuric acid is also good. The welded deposits exhibited the typical behaviour of a passive material. Wear mechanisms slightly reduce the resistance. The behaviour of various specimens in artificial seawater could be distinctly assessed. Small grain fractions and pre-heating temperatures of 100 C have a beneficial effect on the corrosion resistance. The technique recommends itself for applications such as coatings for baffle plates used in flue gas desulfurisation, pipes, pump components, flanges or nozzles, or for recurrent coating of system components affected by abrasive corrosion. (orig./CB) [Deutsch] Zur Herstellung hartstoffverstaerkter Duplex-Beschichtungen wurde das Plasma-Zwei-Pulver-Auftragschweissverfahren verwendet. Hierbei wurde durch Variation des Zufuhrwinkels der Hartstoffe der Einbringungsort der Karbide optimiert, so dass diese im Nachlauf des Schweissbrenners mit sehr geringer thermischer Beeinflussung im erstarrungsnahen Schmelzbadbereich in die Matrix eingelagert

  11. Effect of long-period stacking ordered phase on microstructure, mechanical property and corrosion resistance of Mg alloys: A review

    Directory of Open Access Journals (Sweden)

    Daokui Xu

    2016-04-01

    Full Text Available Magnesium alloys containing long period stacking ordered (LPSO phase have been received a great deal of attention in the last decade owing to their excellent comprehensive properties of mechanical strength and corrosion resistance. In this paper, some fundamental aspects of LPSO containing Mg alloys have been reviewed, including: (1 microstructural characterization, formation conditions and the associated phase transformation of LPSO phases in Mg alloys; (2 deformation mechanism of LPSO phases and their influence on the deformation mechanism of the Mg matrix; (3 effect of LPSO structure on the mechanical performance such as tensile strength, creep resistance, fracture toughness and fatigue strength; (4 corrosion behavior of LPSO containing Mg alloys and their possible applications as the biomaterials. Moreover, some remaining unsolved issues of the LPSO containing Mg alloys and the future target about how to further improve their service properties have been also described.

  12. Unexpected corrosion of stainless steel in low chloride waters – microbial aspects

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel; Carpén, Leena; Møller, Per

    2009-01-01

    Abstract Stainless steels EN 1.4301 and 1.4401/1.4404 are normally considered corrosion resistant in low chloride natural waters like drinking water. However, a number of corrosion failures have been observed in e.g. fire extinguisher systems and drinking water installations, where stagnant...... in drinking water qualities, due to the formation of a biofilm. In itself, this is not enough to initiate pitting in these water qualities, but combined with a geometrically or metallurgically vulnerable area, corrosion may accelerate. The mechanism is linked to the naturally occurring microbial activity...... conditions or periods of low water consumption have occurred prior to the failure. Typically the corrosion attacks appear within 2-3 years in weld nuggets, heat affected zones or in crevices like e.g. press fitting pipe connections. The failure mode is pitting and crevice corrosion leading to leaks and rust...

  13. Heat transfer augmentation in double pipe heat exchanger using mechanical turbulators

    Science.gov (United States)

    Kamboj, Kushal; Singh, Gurjeet; Sharma, Rohit; Panchal, Dilbagh; Hira, Jaspreet

    2017-02-01

    The work presented here focuses on heat transfer augmentation by means of divergent-convergent spring turbulator (the enhancement device). Aim of the present work is to find such an optimum pitch at which the augmentation in heat transfer is maximum and the amount of power consumption is minimum, so that an economic design can be created with maximum thermal efficiency. So, the concept of pitch variation is introduced, which is defined as the horizontal distance between two consecutive turbulators. It describes that, the lesser is the pitch the more number of turbulators that can be inserted in inner pipe of double pipe heat exchanger, hence more will be the friction factor. This physics increases convective ability of the heat transfer process from the surface of inner pipe. There is a certain limit to which a pitch can be decreased, lesser the pitch the more the pressure drop and friction factor and hence the more will be the pumping power requirement to maintain a desired mass flow rate of hot water. Analysis of thermal factors such as Nusselts number, friction factor, with different pitches of divergent convergent spring turbulators of circular cross-section 15, 10, and 5 cm at Reynolds's number ranging between 9000 < Re < 40,000 is done graphically.

  14. Unravelling the mechanism behind Swirl-Switching in turbulent bent pipes

    Science.gov (United States)

    Schlatter, Philipp; Hufnagel, Lorenz; Canton, Jacopo; Örlü, Ramis; Marin, Oana; Merzari, Elia

    2016-11-01

    Turbulent flow through pipe bends has been extensively studied, but several phenomena still miss an exhaustive explanation. Due to centrifugal forces, the fluid flowing through a curved pipe forms two symmetric, counter-rotating Dean vortices. It has been observed, experimentally and numerically, that these vortices change their size, intensity and axis in a periodic, oscillatory fashion, a phenomenon known as swirl-switching. These oscillations are responsible for failure due to fatigue in pipes, and their origin has been attributed to a recirculation bubble, disturbances coming from the upstream straight section and others. The present study tackles the problem by direct numerical simulations (DNS) analysed, for the first time, with three-dimensional proper orthogonal decomposition (POD) as to distinguish between the spatial and temporal contributions. The simulations are performed at a friction Reynolds number of about 360 with a divergence-free synthetic turbulence inflow, as to avoid the interference of low-frequency oscillations generated by a standard recycling method. Results indicate that a single low-frequency, three-dimensional POD mode, representing a travelling wave, and previously mistaken by 2D POD for two different modes, is responsible for the swirl-switching.

  15. Improvement of mechanical properties and corrosion resistance of biodegradable Mg-Nd-Zn-Zr alloys by double extrusion

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiaobo, E-mail: xbxbzhang2003@163.com [School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing, 211167 (China); Wang, Zhangzhong [School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing, 211167 (China); Yuan, Guangyin [National Engineering Research Center of Light Alloy Net Forming, Shanghai Jiao Tong University, Shanghai, 200240 (China); Xue, Yajun [School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing, 211167 (China)

    2012-08-01

    Highlights: Black-Right-Pointing-Pointer Microstructure of Mg-Nd-Zn-Zr alloys was refined and homogenized by double extrusion process. Black-Right-Pointing-Pointer The mechanical properties of the alloys were significantly enhanced by double extrusion. Black-Right-Pointing-Pointer The biocorrosion resistance of the alloys was improved by double extrusion. - Abstract: Mg-Nd-Zn-Zr alloy is a novel and promising biodegradable magnesium alloy due to good biocompatibility, desired uniform corrosion mode and outstanding corrosion resistance in simulated body fluid (SBF). However, the corrosion resistance and mechanical properties should be improved to meet the requirement of the biodegradable implants, such as plates, screws and cardiovascular stents. In the present study, double extrusion process was adopted to refine microstructure and improve mechanical properties of Mg-2.25Nd-0.11Zn-0.43Zr and Mg-2.70Nd-0.20Zn-0.41Zr alloys. The corrosion resistance of the alloys after double extrusion was also studied. The results show that the microstructure of the alloys under double extrusion becomes much finer and more homogeneous than those under once extrusion. The yield strength, ultimate tensile strength and elongation of the alloys under double extrusion are over 270 MPa, 300 MPa and 32%, respectively, indicating that outstanding mechanical properties of Mg-Nd-Zn-Zr alloy can be obtained by double extrusion. The results of immersion experiment and electrochemical measurements in SBF show that the corrosion resistance of Alloy 1 and Alloy 2 under double extrusion was increased by 7% and 8% respectively compared with those under just once extrusion.

  16. Influence of temperature on AISI 316L corrosion in phosphoric acid solutions under hydrodynamic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Tovar, R.; Montanes, M.T.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain); Ben Bachir, A.; Abdelkebir, B.; Elmandoubi, N. [University Mohammed V-Agdal, Lab. Corrosion-Electrochimie, Faculty of Sciences, Rabat (Morocco)

    2009-07-01

    AISI 316L stainless steel, due to its good mechanical properties and corrosion resistance, is widely used in the phosphoric acid industry, including piping lines. However, phosphoric acid (H{sub 3}PO{sub 4}) is a medium-strong acid, and corrosion problems could occur, especially working with concentrated solutions and increasing temperature. Furthermore, fluid flow can increase corrosion rates. The objective of this work is to study the dynamic corrosion of AISI 316L stainless steel in a range of temperature from 25 C to 60 C by means of cyclic potentiodynamic curves. A hydrodynamic circuit was used in order to study dynamic corrosion. The experiments were carried out in an oxygen-free environment at different Reynolds numbers: 1,456, 3,166 and 5,066. The results show that uniform corrosion mechanisms can be expected for AISI 316L stainless steel in 5.5 M H{sub 3}PO{sub 4} solutions, since no hysteresis loop was observed. Moreover, temperature affects the corrosion parameters obtained from the polarization curves. Temperature shifts corrosion potential to nobler values, reduces the passivity region and enhances passivation current density. On the other hand, little influence of Reynolds number was observed on AISI 316L stainless steel corrosion. (authors)

  17. Management of Reinforcement Corrosion

    DEFF Research Database (Denmark)

    Küter, André; Geiker, Mette Rica; Møller, Per

    Reinforcement corrosion is the most important cause for deterioration of reinforced concrete structures, both with regard to costs and consequences. Thermodynamically consistent descriptions of corrosion mechanisms are expected to allow the development of innovative concepts for the management...... of reinforcement corrosion....

  18. Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired Mechanical and Corrosion Properties.

    Energy Technology Data Exchange (ETDEWEB)

    Dulikravich, George S.; Sikka, Vinod K.; Muralidharan, G.

    2006-06-01

    The goal of this project was to adapt and use an advanced semi-stochastic algorithm for constrained multiobjective optimization and combine it with experimental testing and verification to determine optimum concentrations of alloying elements in heat-resistant and corrosion-resistant H-series stainless steel alloys that will simultaneously maximize a number of alloy's mechanical and corrosion properties.

  19. Influence of Alloying Elements Corrosion Resistance of Cold on Mechanical Properties and Rolled C-Mn-Si TRIP Steels

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ling-yun; WU Di; LI Zhuang

    2012-01-01

    The rust layer plays an important role in the corrosion of steel in chlorinated environments. Salt spray, po- tentiodynamic polarization curve and tensile test were conducted in laboratory for the specimens after two-stage heat treatment. The influence of the alloying elements on mechanical properties and corrosion resistance of three kinds of steels was investigated by observing the microstructure and the morphologies of rust layer. The results show that the highest value (29%) of total elongation for steel A is obtained. The mechanical property of the specimen for steel C exhibits best strength ductility balance (21 384 MPa ·%) because of the presence of the multiphase microstructures after a two-stage heat treatment and the addition of the alloying elements. The corrosion products are known to be a complex mixture of Fe3O4 , Fe2O3 and α-FeOOH for steel C. The presence of the alloying elements results in the for mation of compact and dense rust layers in steel B and C. Passive film protects the substrate of TRIP (transformation induced plasticity) steel containing a complex mix of multiphase. Superior corrosion performance is exhibited for steel C with low alloying contents due to the enrichment of alloying elements within the rust layers.

  20. Effect of coating mild steel with CNTs on its mechanical properties and corrosion behaviour in acidic medium

    Science.gov (United States)

    Abdulmalik Abdulrahaman, Mahmud; Kamaldeeen Abubakre, Oladiran; Ambali Abdulkareem, Saka; Oladejo Tijani, Jimoh; Aliyu, Ahmed; Afolabi, Ayo Samuel

    2017-03-01

    The study investigated the mechanical properties and corrosion behaviour of mild steel coated with carbon nanotubes at different coating conditions. Multi-walled carbon nanotubes (MWCNTs) were synthesized via the conventional chemical vapour deposition reaction using bimetallic Fe–Ni catalyst supported on kaolin, with acetylene gas as a carbon source. The HRSEM/HRTEM analysis of the purified carbon materials revealed significant reduction in the diameters of the purified MWCNT bundles from 50 nm to 2 nm and was attributed to the ultrasonication assisted dispersion with surfactant (gum arabic) employed in purification process. The network of the dispersed MWCNTs was coated onto the surfaces of mild steel samples, and as the coating temperature and holding time increased, the coating thickness reduced. The mechanical properties (tensile strength, yield strength, hardness value) of the coated steel samples increased with increase in coating temperature and holding time. Comparing the different coating conditions, coated mild steels at the temperature of 950 °C for 90 min holding time exhibited high hardness, yield strength and tensile strength values compared to others. The corrosion current and corrosion rate of the coated mild steel samples decreased with increase in holding time and coating temperature. The lowest corrosion rate was observed on sample coated at 950 °C for 90 min.

  1. Influence of solid-solution treatment on microstructure, mechanical property and corrosion behavior of biodegradable Mg-Zn-Ca alloy

    Science.gov (United States)

    Ly, Xuan Nam; Yang, S.; Qin, Y.

    2017-03-01

    The influence of solid-solution treatment on microstructure, mechanical property and corrosion behavior of Mg-Zn-Ca alloy was studied in the present investigation by SEM, tensile test, electrochemical and immersion test. The results show that the microstructure of Mg alloys after solid solution treatment significantly changed, a large number of the second phase (Ca2Mg6Zn3, Mg2Ca) dissolved into the α-Mg matrix reaching a supersaturated state, and the grains size was bigger than before solid solution treatment; the mechanical properties were obviously improved. In particular the tensile strength of 0.5wt.% Ca of Mg alloy reached 220MPa and the ductility reached 16.6%. Compared with the as-cast Mg alloys, the corrosion potential after solid-solution treatment slightly shifted negative, but the corrosion current density significantly decreased. After solid solution treatment, the surface corrosion was not serious and the result of weight gain was lower compared with those of the as-cast Mg alloys.

  2. CORRELATION BETWEEN MICROSTRUCTURE AND MECHANICAL AND CORROSION RESISTANCES OF A LEAD-FREE Sn-0,7%Cu SOLDER ALLOY

    Directory of Open Access Journals (Sweden)

    José Eduardo Spinelli

    2014-12-01

    Full Text Available Sn-Cu alloys are promising alternatives to the replacement of Pb-containing solder alloys. However, the effects of the cooling rate on the solidification microstructures of these alloys and the corresponding influence on the mechanical and corrosion resistances are not well known. In the present study, the transient directional solidification technique has been used to obtain a Sn-0,7wt.%Cu ingot. The experimental results include: solidification thermal parameters (cooling rate, Ṫ, growth rate, v, and metal/substrate heat transfer coefficient, hi , cellular spacing, λc , and primary dendritic arm spacing, λ1 , corrosion rate, corrosion potential and polarization resistance and mechanical strength and ductility. The results show a cellular/dendritic transition with eutectic cells prevailing for Ṫ< 0,9°C/s. Lower corrosion resistances have been associated with dendritic regions compared with regions characterized by eutectic cells. In the interdendritic regions extremely fine and fibrous Cu6 Sn5 intermetallic particles can be observed.

  3. Mechanical and corrosion resistant properties of martensitic stainless steel plasma nitrocarburized with rare earths addition

    Institute of Scientific and Technical Information of China (English)

    LIU Ruiliang; QIAO Yingjie; YAN Mufu; FU Yudong

    2012-01-01

    In order to improve surface hardness and corrosion resistant property of 17-4PH martensitic stainless steel,the steel was plasma nitrocarburized at 560 ℃ for 2-24 h in a gas mixture of nitrogen,hydrogen and ethanol with rare earths (RE) addition.The experimental results showed that the modified layer was characterized by a compound layer containing two distinct zones (i.e.out ‘dark zone’ and inner ‘white zone’).The inner ‘white zone’ was almost a precipitation free zone and had high hardness as well as good corrosion resistance.Anodic polarization test results showed that the specimens plasma nitrocarburized with RE addition had good corrosion resistance resulted mainly from their higher corrosion potentials,lower corrosion current densities and larger passive regions as compared with those of the untreated one.

  4. Structure, mechanical property and corrosion behaviors of (HA + β-TCP)/Mg–5Sn composite with interpenetrating networks

    Energy Technology Data Exchange (ETDEWEB)

    Wang, X., E-mail: wangxiang@hrbeu.edu.cn [Center for Biomedical Materials and Engineering, Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001 (China); Li, J.T.; Xie, M.Y. [Center for Biomedical Materials and Engineering, Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001 (China); Qu, L.J. [Key Lab of Biomedical Materials of University in Heilongjiang Province, Jiamusi University, Jiamusi 154007 (China); Zhang, P.; Li, X.L. [Center for Biomedical Materials and Engineering, Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001 (China)

    2015-11-01

    In this paper, a novel (Hydroxyapatite + β-tricalcium phosphate)/Mg–5Sn ((HA + β-TCP)/Mg–5Sn) composite with interpenetrating networks was fabricated by infiltrating Mg–5Sn alloy into porous HA + β-TCP using suction casting technique. The structure, mechanical property and corrosion behaviors of the composite have been evaluated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), mechanical testing, electrochemical and immersion test. It is shown that the molten Mg–5Sn alloy has infiltrated not only into the pores but also into the struts of the HA + β-TCP scaffold to forming a compact composite. The microstructure observation also shows that the Mg alloy contacts to the HA + β-TCP closely, and no reaction layer can be found between Mg–5Sn alloy and scaffold. The ultimate compressive strength of the composite is as high as 176 MPa, which is about four fifths of the strength of the Mg–5Sn bulk alloy. The electrochemical and immersion tests indicate that the corrosion resistance of the composite is better than that of the Mg–5Sn bulk alloy. The corrosion products on the composite surface are mainly Mg(OH){sub 2}, Ca{sub 3}(PO{sub 4}){sub 2} and HA. Appropriate mechanical and corrosion properties of the (HA + β-TCP)/Mg–5Sn composite indicate its possibility for new bone tissue implant materials. - Highlights: • The novel (HA + β-TCP)/Mg–5Sn composite with interpenetrating networks was fabricated using suction casting technique. • The ultimate compressive strength of the composite was near with the natural bone. • And the corrosion resistance of the composite was better than that of the Mg–5Sn bulk alloy.

  5. Enhanced Mechanical Properties and Corrosion Behavior of Biodegradable Mg-Zn/HA Composite

    Science.gov (United States)

    Salleh, Emee Marina; Zuhailawati, Hussain; Ramakrishnan, Sivakumar; Dhindaw, Brij Kumar

    2017-03-01

    Magnesium (Mg) and its alloys have shown potential for use in the biomedical industry due to their excellent biological performance and biodegradability in the bioenvironment. Thus, the aim of the present study was to develop a reliable biodegradable hard tissue substituent. Biodegradable and bioactive Mg-Zinc (Zn) reinforced by hydroxyapatite (HA) composite was prepared using mechanically alloyed Mg-6.5 wt pct Zn and pure HA powders as starting materials. Various HA contents (i.e., 5, 10, 15, and 20 wt pct) were introduced in forming the Mg-Zn/HA composite. The effect of bioactive HA incorporation in biodegradable Mg-6.5 wt pct Zn alloy matrix on mechanical and biodegradation properties as well as microstructural observation was investigated. As measured by the Williamson-Hall formula, the Mg crystallite size of the sintered composites containing 5, 10, 15, and 20 wt pct HA were 36.76, 29.08, 27.93, and 27.31 nm, respectively. According to X-ray diffraction (XRD) analysis, there was no new crystalline phase formed during milling, indicating that no mechanochemical reactions between Mg-Zn alloy and HA occurred. The -1.70 V shifted significantly toward the passive position of the plain Mg-6.5 wt pct Zn alloy and Mg-Zn/10 wt pct HA composite, which were -1.50 and -1.46 V, respectively, indicating that the Mg-Zn/10 wt pct HA composite was least susceptible to corrosion in the bioenvironment.

  6. Mechanical, physical, and corrosion characteristics of 2% vanadium alloyed ductile iron

    Science.gov (United States)

    Abdullah, Bulan; Jaffar, Ahmed; Alias, Siti Khadijah; Jaafar, Roseleena; Ramli, Abdullah; Faitullah, Ahmad

    2010-03-01

    This study was to investigate the effect of 2% vanadium alloyed austempered ductile iron on mechanical properties and microstructure and also to determine the desired austempering temperatures of vanadium alloyed ductile iron. In this study, specimens of 2%vanadium DI were produced by using the Y-block casting in the foundry lab. The specimen produced were machine according to the tensile and impact dimension followed the TSEN1002-1 and ASTM E23 standard. Then, austempering process was performed at the three different temperatures to the sample which are 500°, 600° and 700° in high temperature furnace. The specimens has been machine were undergoes the tensile, impact, density and hardness test. The microstructures were observed by using Olympus BX 41 M Microscopes image analysis system before and after etching by Nital 15%. Polarization test also were conduct between commercial DI and 2%V-DI. The results show that 2% vanadium alloyed ductile iron (2% V-DI) not only increases the nodule count and ferrite content in the microstructure, but also improves the mechanical properties such as tensile strength, impact toughness proportional to the austempered temperature as compared to unalloyed DI. The low corrosion rates also show for the 2% of vanadium alloyed compare to the commercial DI.

  7. Enhanced Mechanical Properties and Corrosion Behavior of Biodegradable Mg-Zn/HA Composite

    Science.gov (United States)

    Salleh, Emee Marina; Zuhailawati, Hussain; Ramakrishnan, Sivakumar; Dhindaw, Brij Kumar

    2017-05-01

    Magnesium (Mg) and its alloys have shown potential for use in the biomedical industry due to their excellent biological performance and biodegradability in the bioenvironment. Thus, the aim of the present study was to develop a reliable biodegradable hard tissue substituent. Biodegradable and bioactive Mg-Zinc (Zn) reinforced by hydroxyapatite (HA) composite was prepared using mechanically alloyed Mg-6.5 wt pct Zn and pure HA powders as starting materials. Various HA contents ( i.e., 5, 10, 15, and 20 wt pct) were introduced in forming the Mg-Zn/HA composite. The effect of bioactive HA incorporation in biodegradable Mg-6.5 wt pct Zn alloy matrix on mechanical and biodegradation properties as well as microstructural observation was investigated. As measured by the Williamson-Hall formula, the Mg crystallite size of the sintered composites containing 5, 10, 15, and 20 wt pct HA were 36.76, 29.08, 27.93, and 27.31 nm, respectively. According to X-ray diffraction (XRD) analysis, there was no new crystalline phase formed during milling, indicating that no mechanochemical reactions between Mg-Zn alloy and HA occurred. The -1.70 V shifted significantly toward the passive position of the plain Mg-6.5 wt pct Zn alloy and Mg-Zn/10 wt pct HA composite, which were -1.50 and -1.46 V, respectively, indicating that the Mg-Zn/10 wt pct HA composite was least susceptible to corrosion in the bioenvironment.

  8. Understanding the corrosion phenomena to organize the nondestructive evaluation programs in the nuclear power plants; Connaitre les phenomenes de corrosion pour organiser les programmes d'end dans les centrales nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Berge, J.Ph. [Federation Europeenne de Corrosion, 75 - Paris (France); Samman, J. [Electricite de France (EDF), Div. du Production Nucleaire, 75 - Paris (France)

    2001-07-01

    The french nuclear power plants used PWR which components revealed many corrosion defects of different shapes as stress corrosion cracks or pits. Understanding the corrosion processes will help the inspection of in service power plants. The following examples describe some corrosion cases and present the corresponding developed control methods: corrosion on condenser, secondary circuit pipes and corrosion-erosion, steam generator pipes, vessels head penetration. (A.L.B.)

  9. Evaluation and control of corrosion and encrustation in tube wells of the Indus Plains, West Pakistan

    Science.gov (United States)

    Clarke, Frank Eldridge; Barnes, Ivan

    1969-01-01

    Seepage from rivers and irrigation canals has contributed to waterlogging and soil salinization problems in much of the Indus Plains of West Pakistan. These problems are being overcome in part by tube-well dewatering and deep leaching of salinized soils. The ground waters described here are anaerobic and some are supersaturated with troublesome minerals such as calcium carbonate (calcite) and iron carbonate (siderite). These waters are moderately corrosive to steel. Some wells contain sulfate-reducing bacteria, which catalyze corrosion, and pH-electrode potential relationships favorable to the solution of iron also are rather common. Corrosion is concentrated in the relatively active (anodic) saw slots of water-well filter pipes (screens), where metal loss is least tolerable. Local changes in chemical properties of the water, because of corrosion, apparently cause deposition of calcium carbonate, iron carbonate, and other minerals which clog the filter pipes. In some places well capacities are seriously reduced in very short periods of time. There appears to be no practicable preventive treatment for corrosion and encrustation in these wells. Even chemical sterilization for bacterial control has yielded poor results. Periodic rehabilitation by down-hole blasting or by other effective mechanical or chemical cleaning methods will prolong well life. It may be possible to repair severely damaged well screens by inserting perforated sleeves of plastic or other inert material. The most promising approach to future, well-field development is to use filter pipes of epoxy-resin-bonded fiber glass, stainless steel, or other inert material which minimizes both corrosion and corrosion-catalyzed encrustation. Fiberglass plastic pipe appears to be the most economically practicable construction material at this time and already is being used with promising results.

  10. Corrosion studies in fuel element reprocessing environments containing nitric acid

    Energy Technology Data Exchange (ETDEWEB)

    Beavers, J A; White, R R; Berry, W E; Griess, J C

    1982-04-01

    Nitric acid is universally used in aqueous fuel element reprocessing plants; however, in the processing scheme being developed by the Consolidated Fuel Reprocessing Program, some of the equipment will be exposed to nitric acid under conditions not previously encountered in fuel element reprocessing plants. A previous report presented corrosion data obtained in hyperazeotropic nitric acid and in concentrated magnesium nitrate solutions used in its preparation. The results presented in this report are concerned with the following: (1) corrosion of titanium in nitric acid; (2) corrosion of nickel-base alloys in a nitric acid-hydrofluoric acid solution; (3) the formation of Cr(VI), which enhances corrosion, in nitric acid solutions; and (4) corrosion of mechanical pipe connectors in nitric acid. The results show that the corrosion rate of titanium increased with the refreshment rate of boiling nitric acid, but the effect diminished rapidly as the temperature decreased. The addition of iodic acid inhibited attack. Also, up to 200 ppM of fluoride in 70% HNO/sub 3/ had no major effect on the corrosion of either titanium or tantalum. In boiling 8 M HNO/sub 3/-0.05 M HF, Inconel 671 was more resistant than Inconel 690, but both alloys experienced end-grain attack. In the case of Inconel 671, heat treatment was very important; annealed and quenched material was much more resistant than furnace-cooled material.The rate of oxidation of Cr(III) to Cr(VI) increased significantly as the nitric acid concentration increased, and certain forms of ruthenium in the solution seemed to accelerate the rate of formation. Mechanical connectors of T-304L stainless steel experienced end-grain attack on the exposed pipe ends, and seal rings of both stainless steel and a titanium alloy (6% Al-4% V) underwent heavy attack in boiling 8 M HNO/sub 3/.

  11. Pipe inspection using the pipe crawler. Innovative technology summary report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    The US Department of Energy (DOE) continually seeks safer and more cost-effective remediation technologies for use in the decontamination and decommissioning (D and D) of nuclear facilities. In several of the buildings at the Fernald Site, there is piping that was used to transport process materials. As the demolition of these buildings occur, disposal of this piping has become a costly issue. Currently, all process piping is cut into ten-foot or less sections, the ends of the piping are wrapped and taped to prevent the release of any potential contaminants into the air, and the piping is placed in roll off boxes for eventual repackaging and shipment to the Nevada Test Site (NTS) for disposal. Alternatives that allow for the onsite disposal of process piping are greatly desired due to the potential for dramatic savings in current offsite disposal costs. No means is currently employed to allow for the adequate inspection of the interior of piping, and consequently, process piping has been assumed to be internally contaminated and thus routinely disposed of at NTS. The BTX-II system incorporates a high-resolution micro color camera with lightheads, cabling, a monitor, and a video recorder. The complete probe is capable of inspecting pipes with an internal diameter (ID) as small as 1.4 inches. By using readily interchangeable lightheads, the same system is capable of inspecting piping up to 24 inches in ID. The original development of the BTX system was for inspection of boiler tubes and small diameter pipes for build-up, pitting, and corrosion. However, the system is well suited for inspecting the interior of most types of piping and other small, confined areas. The report describes the technology, its performance, uses, cost, regulatory and policy issues, and lessons learned.

  12. Understanding of hydriding mechanisms of zircaloy-4 alloy during corrosion in PWR simulated conditions and influence of zirconium hydrides on zircaloy-4 corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Bisor-Melloul, C.; Tupin, M.; Bossis, P. [DEN/DANS/DMN/SEMI, CEA/Saclay, 91191 Gif-sur-Yvette (France); Chene, J. [DEN/DANS/DPC/SCCME, CEA/Saclay, 91191 Gif-sur-Yvette (France); Bechade, J.L. [DEN/DANS/DMN/SRMA, CEA/Saclay, 91191 Gif-sur-Yvette (France); Motta, A. [Mechanical and Nuclear Engineering Department, Penn State University, 227 Reber Building, University Park, PA 16802 (United States)

    2010-07-01

    Zirconium alloys are widely used as fuel claddings in Power Water Reactors. As they represent the first containment barrier to fission products, their mechanical integrity is essential for nuclear safety. During their corrosion in primary water, some of the hydrogen involved in the oxidation reaction with water ingresses into the alloy through the oxide layer. In the metallic matrix, once the solid solution limit is reached at the irradiation temperature, hydrogen precipitates as Zr hydrides mainly located just under the metal/oxide interface due to the thermal gradient across the cladding. As these hydrides may contribute to a larger oxide thickness and to a more fragile behaviour of the cladding, the minimization of hydrogen pick-up is required. Accordingly, since the Zircaloy-4 (Zr-1.3Sn-0.2Fe-0.1Cr) alloy is known to be sensitive to this phenomenon, the understanding of its hydriding mechanism and of the influence of zirconium hydrides on its corrosion behaviour is needed. Regarding the study of the hydriding mechanism, isotopic exchanges were carried out in D{sub 2}O environment at 360 deg. C and led to the localization, in the oxide scales, of the limiting step for the hydrogen diffusion. To estimate an apparent diffusion coefficient of hydrogen in the oxide formed on Zircaloy-4, we firstly based on SIMS profiles and penetration depth of deuterium in the dense part of the oxide film. Secondly, ERDA estimation of the hydrogen content in zirconia and fusion measurements of the hydrogen content in both metal and oxide were used to estimate a hydrogen flux absorbed by the alloy and hence to deduce an apparent diffusion coefficient. Finally, these two methods lead to quite similar values (between 2.10{sup -14} cm{sup 2}/s and 6.10{sup -14} cm{sup 2}/s) which are in accordance with bibliography. Concerning the impact of hydrides on the corrosion of Zircaloy-4, several pre-hydrided and reference samples were corroded simultaneously in primary water at 360 deg. C

  13. Effect of post weld heat treatment on the mechanical and corrosion behaviour of welded Al-Fe-Si alloy joints

    Directory of Open Access Journals (Sweden)

    Isiaka Oluwole OLADELE

    2017-06-01

    Full Text Available Al-Fe-Si alloy was joined by shielded metal arc welding (SMAW process and the effects of post weld heat treatment (PWHT on the mechanical (tensile and hardness properties, corrosion behaviour and microstructure of the welded joints were investigated. The welded samples were divided into as-weld (AW, PWHT, base metal (BM and heat treated base metal (HT BM samples. Artificial aging was carried out on part of the welded sample at 177 °C with holding time of 8 hours to obtain the PWHT samples. The various samples were subjected to tensile, hardness and corrosion tests while microstructures of the fractured surfaces were viewed under optical microscope. From the results, it was observed that corrosion susceptibility of the alloy in 3.5 wt% NaCl solution was highly reduced after PWHT. The hardness was reduced after PWHT while the yield strength and joint efficiency was improved compared to the AW sample. The improvement in corrosion resistance, yield strength and joint efficiency are 78, 8.4 and 8.7 %, respectively.

  14. Long-term in vivo corrosion behavior, biocompatibility and bioresorption mechanism of a bioresorbable nitrided iron scaffold.

    Science.gov (United States)

    Lin, Wenjiao; Qin, Li; Qi, Haiping; Zhang, Deyuan; Zhang, Gui; Gao, Runlin; Qiu, Hong; Xia, Ying; Cao, Ping; Wang, Xiang; Zheng, Wei

    2017-03-15

    Pure iron as a potential bioresorbable material for bioresorbable coronary scaffold has major disadvantages of slow corrosion and bioresorption. However, so far, there are neither quantitative data of long-term in vivo corrosion nor direct experimental evidence for bioresorption of pure iron and its alloys, which are fundamental and vital for developing novel Fe-based alloys overcoming the intrinsic drawbacks of pure iron. This work systemically investigated scaffold performance, long-term in vivo corrosion behavior and biocompatibility of a nitrided iron coronary scaffold and explored its bioresorption mechanism. It was found that the 70μm Fe-based scaffold was superior to a state of the art Co-Cr alloy stent (Xience Prime™) in terms of crossing profile, recoil and radial strength. Mass loss was 76.0±8.5wt% for the nitrided iron scaffold and 44.2±11.4wt% for the pure iron scaffold after 36months implantation in rabbit abdominal aorta (pscaffold showed good long-term biocompatibility in both rabbit and porcine model. Its insoluble corrosion products were demonstrated biosafe and could be cleared away by macrophages from in situ to adventitia to be indiscernible by Micro Computed Tomography and probably finally enter the lymphatics and travel to lymph nodes after 53months implantion in porcine coronary artery. The results indicate that the nitrided iron scaffold with further improvements shall be promising for coronary application.

  15. Effect of thermal treatment on the bio-corrosion and mechanical properties of ultrafine-grained ZK60 magnesium alloy.

    Science.gov (United States)

    Choi, H Y; Kim, W J

    2015-11-01

    The combination of solid solution heat treatments and severe plastic deformation by high-ratio differential speed rolling (HRDSR) resulted in the formation of an ultrafine-grained microstructure with high thermal stability in a Mg-5Zn-0.5Zr (ZK60) alloy. When the precipitate particle distribution was uniform in the matrix, the internal stresses and dislocation density could be effectively removed without significant grain growth during the annealing treatment (after HRDSR), leading to enhancement of corrosion resistance. When the particle distribution was non-uniform, rapid grain growth occurred in local areas where the particle density was low during annealing, leading to development of a bimodal grain size distribution. The bimodal grain size distribution accelerated corrosion by forming a galvanic corrosion couple between the fine-grained and coarse-grained regions. The HRDSR-processed ZK60 alloy with high thermal stability exhibited high corrosion resistance, high strength and high ductility, and excellent superplasticity, which allow the fabrication of biodegradable magnesium devices with complicated designs that have a high mechanical integrity throughout the service life in the human body.

  16. Characterization, mechanical properties and corrosion resistance of biocompatible Zn-HA/TiO2 nanocomposite coatings.

    Science.gov (United States)

    Mirak, Mohammad; Alizadeh, Morteza; Ghaffari, Mohammad; Ashtiani, Mohammad Najafi

    2016-09-01

    Biocompatible Zinc-hydroxyapatite-titania and Zinc-hydroxyapatite nanocomposite coatings have been prepared by electrodeposition on NiTi shape memory alloy. Structures of coatings were characterized using X-ray diffraction (XRD). It was found that addition of TiO2 particles cause to reduction of crystallite size of coating. Scanning Electronic Microscope (SEM) observation showed that the Zn-HA/TiO2 coating consists of plate-like regions which can express that this plate-like structure can facilitate bone growth. X-ray photoelectron microscope (XPS) was performed to investigation of chemical state of composite coating and showed that Zinc matrix was bonded to oxygen. high-resolution transmission electron microscope (HRTEM) result illustrated the crystalline structure of nanocomposite coating. Mechanical behavior of coating was evaluated using microhardness and ball on disk wear test. The TiO2 incorporated composite coatings exhibited the better hardness and anti-wear performance than the Zn-HA coatings. Polarization measurements have been used to evaluate the electrochemical coatings performance. The Zn-HA/TiO2 composite coatings showed the highest corrosion resistance compared with Zn-HA and bare NiTi. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Mechanism of intergranular stress corrosion cracking in HAZ for super-martensitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Miyata, Yukio; Kimura, Mitsuo [Tubular Products and Casting Research Dept., JFE Steel Corporation, 1-1, Kawasaki-cho, Handa (Japan); Nakamichi, Haruo; Sato, Kaoru [Analysis and Characterization Research Dept., JFE Steel Corporation, 1-1, Minamiwatarida-cho, Kawasaki-ku, Kawasaki (Japan); Itakura, Noritsugu [Products Service and Development Dept., Chita Works, JFE Steel Corporation. 1-1, Kawasaki-cho, Handa (Japan); Masamura, Katsumi [Tubular Products Business Planning Dept., JFE Steel Corporation, 2-2-3, Uchisaiwai-sho, Chiyoda-ku, Tokyo (Japan)

    2004-07-01

    Mechanism of intergranular stress corrosion cracking (IGSCC) for heat affected zone (HAZ) of super-martensitic stainless steel was studied using two types of the steel. One was a lean grade, which was Mo free and low Ni, and the other was a high grade, which was Mo added and high Ni. Specimens received heat treatments simulating welding thermal cycles were applied to SCC tests. Cracks were observed in some specimens after U-bend SCC test under low pH environments. Thermal cycle conditions with sensitization were verified from the results. No crack was observed in the specimen with the thermal cycle simulating post welding heat treatment (PWHT) after sensitizing conditions. Therefore, PWHT was clarified to be effective to prevent the cracking. Cr carbides were observed along prior austenite grain boundary intermittently, and Cr depleted zone was confirmed on the grain boundary adjacent to carbides that precipitated on the grain boundary. It is, therefore, concluded that the cracking results from Cr depletion on prior austenite grain boundary accompanied by precipitation of Cr carbides under specific welding conditions. (authors)

  18. The mechanism of cathodic electrodeposition of epoxy coatings and the corrosion behaviour of the electrodeposited

    Directory of Open Access Journals (Sweden)

    VESNA B. MISKOVIC-STANKOVIC

    2002-05-01

    Full Text Available The model of organic film growth on a cathode during electrodeposition process proposes the current density-time and film thickness-time relationships and enables the evaluation of the rate contants for the electrochemical reaction of OH– ion evolution and for the chemical reaction of organic film deposition. The dependences of film thickness and rate constants on the applied voltage, bath temperature and resin concentration in the electrodeposition bath have also been obtained. The deposition parameters have a great effect on the cathodic electrodeposition process and on the protective properties of the obtained electrodeposited coatings. From the time dependences of the pore resistance, coating capacitance and relative permittivity, obtained from impedance measurements, the effect of applied voltage, bath temperature and resin concentration on the protective properties of electrodeposited coatings has been shown. Using electrochemical impedance spectroscopy, thermogravimetric analysis, gravimetric liquid sorption experiments, differential scanning calorimetry and optical miscroscopy, the corrosion stability of epoxy coatings was investigated. A mechanism for the penetration of electrolyte through an organic coating has been suggested and the shape and dimensions of the conducting macropores have been determined. It was shown that conduction through a coating depends only on the conduction through the macropores, although the quantity of electrolyte in the micropores of the polymer net is about one order of magnitude greater than that inside the conducting macropores.

  19. Temperature effect on the corrosion mechanism of austenitic and martensitic steels in lead-bismuth

    Energy Technology Data Exchange (ETDEWEB)

    Benamati, G.; Fazio, C. E-mail: concetta@brasimone.enea.it; Piankova, H.; Rusanov, A

    2002-02-01

    Compatibility tests on the austenitic AISI 316L and the martensitic MANET II steels in stagnant PbBi were performed at 573, 673 and 823 K with exposures up to 5000 h. The change of the corrosion mechanism with increasing temperature has been evaluated. The results showed that at 573 and 673 K a thin oxide layer growth on the surface of both steels. By increasing the temperature to 823 K both types of steels were attacked by the liquid metal and dissolution of the steel alloying elements has been observed. The herein-reported experimental activities were performed in collaboration with the IPPE of Obninsk, where preliminary dynamic tests were performed in the experimental facility CU-2. The Russian ferritic-martensitic steel EP823 has been exposed to flowing PbBi at 623, 723 and 823 K for 700 h. After 700 h of testing, the surface of the EP823 samples showed for the three temperatures a compact oxide layer.

  20. Study of mechanical properties, microstructures and corrosion behavior of al 7075 t651 alloy with varying strain rate

    Science.gov (United States)

    Mukherjee, A.; Ghosh, M.; Mondal, K.; Venkitanarayanan, P.; Moon, A. P.; Varshney, A.

    2015-02-01

    Compression test of Al 7075 T651 was carried out at high strain rates (1138 - 2534 s-1) using Split Hopkinson Pressure Bar and at slow strain rate (10-4s-1) in 100KN Universal Testing machine to understand the improvement in mechanical properties and associated changes in microstructures. Cylindrical specimens of 6 mm height and 6 mm diameter were compressed dynamically. The influence of strain rates on mechanical properties, microstructure evolution and corrosion behavior after immersion test in 3.5% NaCl solution was also investigated. Strain rate, withdrawal stress and yield stress were observed to increase with impact velocity in high strain rate tests, while in slow strain rate tests, n value was observed to increase with increasing total strain. Microstructural observations revealed that after high strain rate test, grains of Al matrix were elongated. It was observed that corrosion resistance decreased with increase in impact velocity.

  1. INFLUENCE OF CONCRETE COVER ON CORROSION MECHANISM AND CORROSION RATE OF STEEL BARS%混凝土保护层对钢筋腐蚀机理及腐蚀速率的影响

    Institute of Scientific and Technical Information of China (English)

    余波; 毋铭; 杨绿峰

    2014-01-01

    混凝土保护层的厚度、电阻率和孔隙水饱和度对混凝土中钢筋的腐蚀机理及腐蚀速率具有重要影响。基于混凝土中钢筋宏电池腐蚀模型,定量分析了混凝土保护层的厚度、电阻率和孔隙水饱和度对钢筋腐蚀机理及腐蚀速率的影响。分析结果表明,混凝土保护层的电阻率和孔隙水饱和度对钢筋腐蚀的控制方式及腐蚀速率影响显著:当钢筋腐蚀受电阻控制时,钢筋腐蚀速率将随着混凝土保护层电阻率的增加而减小,随保护层厚度的增大而增大,但不受混凝土孔隙水饱和度的影响;当钢筋腐蚀受阴极控制时,钢筋腐蚀速率将随着混凝土保护层的孔隙水饱和度和厚度的增大而降低,但不受混凝土电阻率的影响。%The thickness , resistivity and degree of pore saturation of concrete cover have significant influences on the corrosion mechanism and corrosion rate of steel bar embedded in concrete .The influences of the thickness , resistivity and degree of pore saturation of concrete cover on the corrosion mechanism and corrosion rate of steel bar were investigated quantitatively , based on the macro-cell corrosion model of steel bar .The results show that the thickness and degree of pore saturation of concrete cover significantly affect the corrosion mechanism and corrosion rate of steel bar corrosion .If the corrosion of steel bar is under the control of resistivity , the corrosion rate diminishes with the increase of resistivity and accelerates with the increase of cover thickness , while the degree of pore saturation of concrete cover has negligible effect .When the cathodic reaction prevails , however , the corrosion rate decelerates with the increase of the degree of pore saturation and thickness of concrete cover while the effect of resistivity can be neglected .

  2. Fabrication of high nitrogen austenitic stainless steels with excellent mechanical and pitting corrosion properties

    Institute of Scientific and Technical Information of China (English)

    Hua-bing Li; Zhou-hua Jiang; Yang Cao; Zu-rui Zhang

    2009-01-01

    18Cr18Mn2Mo0.9N high nitrogen austenitic stainless steel exhibits high strength and good ductility at room temperature. The steel shows typical duc-tile-brittle transition behavior and excellent pitting corrosion resistance properties.

  3. The mechanism of stress-corrosion cracking in 7075 aluminum alloy

    Science.gov (United States)

    Jacobs, A. J.

    1970-01-01

    Various aspects of stress-corrosion cracking in 7075 aluminum alloy are discussed. A model is proposed in which the continuous anodic path along which the metal is preferentially attacked consists of two phases which alternate as anodes.

  4. Thermal and mechanical properties of e-beam irradiated butt-fusion joint in high-density polyethylene pipes

    Science.gov (United States)

    Vijayan, Vipin; Pokharel, Pashupati; Kang, Min Kwan; Choi, Sunwoong

    2016-05-01

    The effects of electron beam irradiation on the thermal and mechanical properties of a butt-fusion joint in high density polyethylene (HDPE) pipes were investigated. Differential scanning calorimetry, X-ray diffraction, and Fourier transform infra-red spectroscopy of welded samples revealed the changes of crystallinity due to the cross linking effect of electron beam irradiation. The suppression of the degree of crystallinity with increasing the irradiation dose from 0 kGy to 500 kGy indicated that the e-beam radiation induced cross-links among the polymer chains at the weld zone. The cross-link junction at the joint of HDPE pipe prevented chain folding and reorganization leading to the formation of imperfect crystallites with smaller size and also less in content. Tensile test of the welded samples with different dose of e-beam irradiation showed the increased values of the yield stress and Young's modulus as a function of irradiation dose. On the other hand, the elongation at break diminished clearly with increasing the irradiation doses.

  5. Coolant choice for the central beryllium pipe of the BESIII beam pipe

    Science.gov (United States)

    Zheng, Li-Fang; Wang, Li; Wu, Ping; Ji, Quan; Li, Xun-Feng; Liu, Jian-Ping

    2010-07-01

    In order to take away much more heat on the BESIII beam pipe to guarantee the normal particle detection, EDM-1 (oil No.1 for electric discharge machining), with good thermal and flow properties was selected as the candidate coolant for the central beryllium pipe of the BESIII beam pipe. Its cooling character was studied and dynamic corrosion experiment was undertaken to examine its corrosion on beryllium. The experiment results show that EDM-1 would corrode the beryllium 19.9 μm in the depth in 10 years, which is weak and can be neglected. Finite element simulation and experiment research were taken to check the cooling capacity of EDM-1. The results show that EDM-1 can meet the cooling requirement of the central beryllium pipe. Now EDM-1 is being used to cool the central beryllium pipe of the BESIII beam pipe.

  6. Study of alloy 600`S stress corrosion cracking mechanisms in high temperature water; Etude des mecanismes de corrosion sous contrainte de l`alliage 600 dans l`eau a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Rios, R.

    1994-06-01

    In order to better understand the mechanisms involved in Alloy 600`s stress corrosion cracking in PWR environment, laboratory tests were performed. The influence of parameters pertinent to the mechanisms was studies : hydrogen and oxygen overpressures, local chemical composition, microstructure. The results show that neither hydrogen nor dissolution/oxidation, despite their respective roles in the process, are sufficient to account for experimental facts. SEM observation of micro-cleavage facets on specimens` fracture surfaces leads to pay attention to a new mechanism of corrosion/plasticity interactions. (author). 113 refs., 73 figs., 15 tabs., 4 annexes.

  7. Fatigue Properties and Fracture Mechanism of Aluminum Alloy with Orifice Chamfer and Pre-corrosion Damage

    Directory of Open Access Journals (Sweden)

    ZHOU Song

    2016-06-01

    Full Text Available Fatigue fracture often occurs because of the corrosion damage to aerospace structural aluminum alloy with holes. Fatigue tests of 7075 aluminum alloy of both unchamfered and chamfered double-hole specimens under uncorrosion and 24h pre-corrosion were carried out. The influence of both pre-corrosion damage and orifice chamferer on fatigue properties and the differences of fatigue fracture characteristics were analyzed. The results show that the effect on fatigue life of pre-corrosion damage is significant. Median fatigue lives of both unchamfered and chamfered double-hole specimens under 24h pre-corrosion decrease about 31.74% and 26.92% compared with uncorrosion specimens. The orifice chamferer have a certain effect on fatigue life of both uncorrosion and 24h pre-corrosion specimens, with median fatigue lives decreased about 28.02% and 15.36% compared with unchamfered specimens, the main reason is due to the stress concentration after orifice chamfered, on the other hand, cutting marks lead to pre-damage during the orifice chamfering process which will result in an increase of the fatigue crack initiation sites and the fracture probability.

  8. Effect of boron addition on injection molded 316L stainless steel: mechanical, corrosion properties and in vitro bioactivity.

    Science.gov (United States)

    Bayraktaroglu, Esra; Gulsoy, H Ozkan; Gulsoy, Nagihan; Er, Ozay; Kilic, Hasan

    2012-01-01

    The research was investigated the effect of boron additions on sintering characteristics, mechanical, corrosion properties and biocompatibility of injection molded austenitic grade 316L stainless steel. Addition of boron is promoted to get high density of sintered 316L stainless steels. The amount of boron plays a role in determining the sintered microstructure and all properties. In this study, 316L stainless steel powders have been used with the elemental NiB powders. A feedstock containing 62.5 wt% powders loading was molded at different injection molded temperature. The binders were completely removed from molded components by solvent and thermal debinding at different temperature. The debinded samples were sintered at different temperature for 60 min. Mechanical property, microstructural characterization and electrochemical property of the sintered samples were performed using tensile testing, hardness, optical, scanning electron microscopy and electrochemical corrosion experiments. Sintered samples were immersed in a simulated body fluid (SBF) with elemental concentrations that were comparable to those of human blood plasma for a total period of 15 days. Both materials were implanted in fibroblast culture for biocompatibility evaluations were carried out. Results of study showed that sintered 316L and 316L with NiB addition samples exhibited high mechanical and corrosion properties in a physiological environment. Especially, 316L with NiB addition can be used in some bioapplications.

  9. Microstructure, texture evolution, mechanical properties and corrosion behavior of ECAP processed ZK60 magnesium alloy for biodegradable applications.

    Science.gov (United States)

    Mostaed, Ehsan; Hashempour, Mazdak; Fabrizi, Alberto; Dellasega, David; Bestetti, Massimiliano; Bonollo, Franco; Vedani, Maurizio

    2014-09-01

    Ultra-fine grained ZK60 Mg alloy was obtained by multi-pass equal-channel angular pressing at different temperatures of 250°C, 200°C and 150°C. Microstructural observations showed a significant grain refinement after ECAP, leading to an equiaxed and ultrafine grain (UFG) structure with average size of 600nm. The original extrusion fiber texture with planes oriented parallel to extrusion direction was gradually undermined during ECAP process and eventually it was substituted by a newly stronger texture component with considerably higher intensity, coinciding with ECAP shear plane. A combination of texture modification and grain refinement in UFG samples led to a marked reduction in mechanical asymmetric behavior compared to the as-received alloy, as well as adequate mechanical properties with about 100% improvement in elongation to failure while keeping relatively high tensile strength. Open circuit potential, potentiodynamic and weight loss measurements in a phosphate buffer solution electrolyte revealed an improved corrosion resistance of UFG alloy compared to the extruded one, stemming from a shift of corrosion regime from localized pitting in the as-received sample to a more uniform corrosion mode with reduced localized attack in ECAP processed alloy. Compression tests on immersed samples showed that the rate of loss of mechanical integrity in the UFG sample was lower than that in the as-received sample.

  10. PRELIMINARY ASSESSMENT OF NDE METHODS ON INSPECTION OF HDPE BUTT FUSION PIPING JOINTS FOR LACK OF FUSION WITH VALIDATION FROM MECHANICAL TESTING

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, Susan L.; Doctor, Steven R.; Cinson, Anthony D.; Watts, Michael W.; Moran, Traci L.; Anderson, Michael T.

    2010-07-22

    Studies at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, are being conducted to evaluate nondestructive examinations (NDE) coupled with mechanical testing of butt fusion joints in high density polyethylene (HDPE) pipe for assessing lack of fusion. The work provides information to the United States Nuclear Regulatory Commission (NRC) on the effectiveness of volumetric inspection techniques of HDPE butt fusion joints in Section III, Division 1, Class 3, buried piping systems in nuclear power plants. This paper describes results from preliminary assessments using ultrasonic and microwave nondestructive techniques and mechanical testing with the high speed tensile impact test and the bend test for determining joint integrity. A series of butt joints were fabricated in 3408, 12 inch (30.5 cm) IPS DR-11 HDPE material by varying the fusion parameters to create good joints and joints containing a range of lack of fusion conditions. Six of these butt joints were volumetrically examined with time of flight diffraction (TOFD), phased array (PA) ultrasound, and the Evisive microwave system. The outer diameter (OD) weld beads were removed for microwave evaluation and the pipes ultrasonically re-evaluated. In two of the six pipes both the outer and inner diameter (ID) weld beads were removed and the pipe joints re-evaluated. Several of the pipes were sectioned and the joints destructively evaluated with the following techniques: high speed tensile test, bend test, and focused immersion ultrasound on a joint section removed from the pipe coupled with slicing through the joint and examining the revealed surfaces. The fusion parameters, nondestructive, and destructive evaluation results will be correlated to validate the effectiveness of what each NDE technology detects and what each does not detect. This is an initial limited study which will aid in identifying key future work.

  11. Variable amplitude corrosion fatigue and fracture mechanics of weldable high strength jack-up steels

    Science.gov (United States)

    Etube, Linus Sone

    The tubular welded joints used in the construction of Offshore structures can experience millions of variable amplitude wave induced stress cycles during their operational life. Fatigue has been identified as the main cause of degradation of structural integrity in these structures. As a result, fatigue is an important consideration in their design. Jack-up legs are made from a range of high strength steels with yield strengths up to TOOMPa. These steels are thought to exhibit fatigue resistance properties which are different when compared with conventional fixed platform steels such as BS 4360 50D and BS 7191 355D. The difference in their behaviour was heightened by the discovery, in the late 80s and early 90s, of extensive cracking around the spud can regions of several Jack-ups operating in the North Sea. It was thought that these steels may be more susceptible to hydrogen cracking and embrittlement. There was the additional requirement to study their behaviour under realistic loading conditions typical of the North Sea environment. This thesis contains results of an investigation undertaken to assess the performance of a typical high strength weldable Jack-up steel under realistic loading and environmental conditions. Details of the methodology employed to develop a typical Jack-up Offshore Standard load History (JOSH) are presented. The factors which influence fatigue resistance of structural steels used in the construction of Jack-up structures are highlighted. The methods used to model the relevant factors for inclusion in JOSH are presented with particular emphasis on loading and structural response interaction. Results and details of experimental variable amplitude corrosion fatigue (VACF) tests conducted using JOSH are reported and discussed with respect to crack growth mechanisms in high strength weldable Jack-up steels. Different fracture mechanics models for VACF crack growth prediction are compared and an improved generalised methodology for fast

  12. Comparison Between Corrosion Behavior of Copper and Stainless Steel 90° Elbow and Failure Investigation of 90° Copper Elbow

    Science.gov (United States)

    Fouad, Mohamed Ahmed; Zewail, Taghreed Mohamed; Amine, Nieven Abbas; El-Tawail, Yehia Ahmed

    2016-06-01

    Frequently found in elbow, erosion failures may lead to the leakage of pipes and even damage the whole system. Erosion is a form of material degradation that involves electrochemical corrosion and mechanical wear processes encountered on the surface of metal pipes. Research on the erosion-corrosion mechanism indicates that the erosion mainly results from the interactions between the elbow surface and the fluid traveling along the surface. Corrosion behavior of 90° copper and stainless steel elbow was studied. Scanning electron microscopy was processed on the 90° copper elbow to show the surface morphology of the failed copper elbow. Failure investigation was carried out on 90° copper elbow to determine failure location and failure causes.

  13. Approximate mechanism for measuring stability of Internet link in aggregated Internet pipe

    CERN Document Server

    M, Vipin

    2009-01-01

    In this article we propose a method for measuring internet connection stability which is fast and has negligible overhead for the process of its complexity. This method finds a relative value for representing the stability of internet connections and can also be extended for aggregated internet connections. The method is documented with help of a real time implementation and results are shared. This proposed measurement scheme uses HTTP GET method for each connections. The normalized responses to identified sites like gateways of ISPs, google.com etc are used for calculating current link stability. The novelty of the approach is that historic values are used to calculate overall link stability. In this discussion, we also document a method to use the calculated values as a dynamic threshold metric. This is used in routing decisions and for load-balancing each of the connections in an aggregated bandwidth pipe. This scheme is a very popular practice in aggregated internet connections.

  14. Mechanical Properties and Corrosion Behavior of CeO2 and SiC Incorporated Al5083 Alloy Surface Composites

    Science.gov (United States)

    Amra, M.; Ranjbar, Khalil; Dehmolaei, R.

    2015-08-01

    In this investigation, nano-sized cerium oxide (CeO2) and silicon carbide (SiC) particles were stirred and mixed into the surface of an Al5083 alloy rolled plate using friction stir processing (FSP) to form a surface nano-composite layer. For this purpose, various volume ratios of the reinforcements either separately or in the combined form were packed into a pre-machined groove on the surface of the plate. Microstructural features, mechanical properties, and corrosion behavior of the resultant surface composites were determined. Microstructural analysis, optical microscopy and scanning electron microscopy, showed that reinforcement particles were fairly dispersed inside the stir zone and grain refinement was gained. Compared with the base alloy, all of the FSP composites showed higher hardness and tensile strength values with the maximum being obtained for the composite containing 100% SiC particles, i.e., Al5083/SiC. The corrosion behavior of the samples was studied by conducting potentiodynamic polarization tests and assessed in terms of corrosion potential, pitting potential, and passivation range. The result shows a significant increase in corrosion resistance of the base alloy; i.e., the longest passivation range when CeO2 alone was incorporated into the surface by acting as cathodic inhibitors. Composites reinforced with SiC particles exhibited lower pitting resistance due to the formation of microgalvanic couples between cathodic SiC particles and anodic aluminum matrix. The study was aimed to fabricate metal matrix surface composites with improved hardness, tensile strength, and corrosion resistance by the incorporation of CeO2 and SiC reinforcement particles into the surface of Al5083 base alloy. Optimum mechanical properties and corrosion resistance were obtained for the FSP composite Al5083/(75%CeO2 + 25%SiC). In this particular FSP composite, hardness and tensile strength were increased by 30, and 14%, respectively, and passivation range was increased

  15. Relationship between H2 sorption properties and aqueous corrosion mechanisms in A2Ni7 hydride forming alloys (A = Y, Gd or Sm)

    Science.gov (United States)

    Charbonnier, Véronique; Monnier, Judith; Zhang, Junxian; Paul-Boncour, Valérie; Joiret, Suzanne; Puga, Beatriz; Goubault, Lionel; Bernard, Patrick; Latroche, Michel

    2016-09-01

    Intermetallic compounds A2B7 (A = rare earth, B = transition metal) are of interest for Ni-MH batteries. Indeed they are able to absorb hydrogen reversibly and exhibit good specific capacity in electrochemical route. To understand the effect of rare earth on properties of interest such as thermodynamic, cycling stability and corrosion, we synthesized and studied three compounds: Y2Ni7, Gd2Ni7 and Sm2Ni7. Using Sieverts' method, we plot P-c-isotherms up to 10 MPa and study hydride stability upon solid-gas cycling. Electrochemical cycling was also performed, as well as calendar and cycling corrosion study. Corrosion products were characterized by means of X-ray diffraction, electron diffraction, Raman micro-spectroscopy and scanning and transmission electron microscopies. Magnetic measurements were also performed to calculate corrosion rates. A corrosion mechanism, based on the nature of corrosion products, is proposed. By combining results from solid-gas cycling, electrochemical cycling and corrosion study, we attribute the loss in capacity either to corrosion or loss of crystallinity.

  16. Microstructure, Mechanical and Corrosion Properties of Friction Stir Welding High Nitrogen Martensitic Stainless Steel 30Cr15Mo1N

    Directory of Open Access Journals (Sweden)

    Xin Geng

    2016-11-01

    Full Text Available High nitrogen martensitic stainless steel 30Cr15Mo1N plates were successfully welded by friction stir welding (FSW at a tool rotation speed of 300 rpm with a welding speed of 100 mm/min, using W-Re tool. The sound joint with no significant nitrogen loss was successfully produced. Microstructure, mechanical and corrosion properties of an FSW joint were investigated. The results suggest that the grain size of the stir zone (SZ is larger than the base metal (BM and is much larger the case in SZ-top. Some carbides and nitrides rich in chromium were found in BM while not observed in SZ. The martensitic phase in SZ could transform to austenite phase during the FSW process and the higher peak temperature, the greater degree of transformation. The hardness of SZ is significantly lower than that of the BM. An abrupt change of hardness defined as hard zone (HZ was found in the thermo-mechanically affected zone (TMAZ on the advancing side (AS, and the HZ is attributed to a combination result of temperature, deformation, and material flow behavior. The corrosion resistance of SZ is superior to that of BM, which can be attributed to less precipitation and lower angle boundaries (LABs. The corrosion resistance of SZ-bottom is slight higher than that of SZ-top because of the finer grained structure.

  17. Study of the mechanism action of sodium gluconate used for the protection of scale and corrosion in cooling water system

    Directory of Open Access Journals (Sweden)

    Rachid Touir

    2014-12-01

    Full Text Available This work based on the mechanism action study of sodium gluconate (SG for ordinary mild steel used for cooling water system treatment. In the first time, we evaluated the temperature effect on the scale inhibition of SG using statistic scale inhibition method. Result showed that the inhibition efficiency became more important with increasing temperature, at great concentration (10−2 and 10−3 M. This can be explained by forming of stable complex SG–Ca2+. In the second time, the present work focuses on the study of operational parameters and corrosion products effect on SG performance using potentiodynamic polarization and electrochemical impedance spectroscopic method. The obtained results show that SG is a very good inhibitor for corrosion and scale and remains effective in the presence of corrosion products. For this study we were proposed a mechanism action for SG on metallic surface. In addition, the SG keeps its effectiveness in a more aggressive medium such as 3% NaCl. Finally, to complete the formulation, we added a not oxidizing biocide (CTAB to SG. The results obtained show that SG remains its effective.

  18. New Insights in the Long-Term Atmospheric Corrosion Mechanisms of Low Alloy Steel Reinforcements of Cultural Heritage Buildings.

    Science.gov (United States)

    Bouchar, Marie; Dillmann, Philippe; Neff, Delphine

    2017-06-19

    Reinforcing clamps made of low alloy steel from the Metz cathedral and corroded outdoors during 500 years were studied by OM, FESEM/EDS, and micro-Raman spectroscopy. The corrosion product layer is constituted of a dual structure. The outer layer is mainly constituted of goethite and lepidocrocite embedding exogenous elements such as Ca and P. The inner layer is mainly constituted of ferrihydrite. The behaviour of the inner layer under conditions simulating the wetting stage of the RH wet/dry atmospheric corrosion cycle was observed by in situ micro-Raman spectroscopy. The disappearance of ferrihydrite near the metal/oxide interface strongly suggests a mechanism of reductive dissolution caused by the oxidation of the metallic substrate and was observed for the first time in situ on an archaeological system.

  19. 陕津高压燃气管网腐蚀与测绘的联合应用%The Combined Application of Corrosion and Surveying in High Pressure Gas Pipe Network

    Institute of Scientific and Technical Information of China (English)

    王庆国; 孙光军

    2016-01-01

    Shanjin pipeline network due to the lack of historical reasons based on information brings many difficulties and risks to network management, maintenance and operation In order to solve the problems faced by the current pipe network, through the implementation of a pipeline detection, while the pipeline mapping and corrosion of two work completed, the pipeline detection has a certain reference.%陕津管线由于历史等原因管网基础资料不足,给管网的管理、维护和运行带来诸多困难和隐患。为了解决当前管网所面临的问题,通过实施一次管道检测,同时将管道的测绘和腐蚀两项工作完成,对管道的检测具有一定的借鉴作用。

  20. On-line Testing Method for Underwater Pipeline Corrosion on Both Side of Pipe Wall%海底管道内外腐蚀的在线检测技术

    Institute of Scientific and Technical Information of China (English)

    毛宁林; 李新军; 魏中格

    2001-01-01

    目前,主要是把智能检测器放到管内,在输送介质 的推动下,完成海底管道内、外腐蚀的在线检测,智能检测器的原理主要基于漏磁技术、超 声波技术和涡流技术。本文介绍了以上三种检测技术的原理、检测器的结构、适应的介质以 及优缺点。%At present,on-line testing method for underwater pipeline corrosion on both side of pipe wall is that a intelligent testing pig was put into the pipeline and pushed by fluid medium. The intelligent testing pig mainly based on the principle of magnetic leakage, ultrasonic & eddy. The paper introduced the principle, structure, advantages & defects for the 3 types testing technology.

  1. Effect of natural aging on the microstructural regions, mechanical properties, corrosion resistance and fracture in welded joints on API5L X52 steel pipeline

    Directory of Open Access Journals (Sweden)

    Vargas-Arista, Benjamín

    2014-09-01

    Full Text Available A characterization study was done to analyze how microstructural regions affect the mechanical properties, corrosion and fractography of the Heat Affected Zone (HAZ, weld bead and base metal for pipe naturally aged for 21 years at 30 °C. Results showed that microstructures exhibited damage and consequently decrease in properties, resulting in over-aged due to service. SEM analysis showed that base metal presented coarse ferrite grain. Tensile test indicated that microstructures showed discontinuous yield. Higher tensile strength was obtained for weld bead, which exhibited a lower impact energy in comparison to that of HAZ and base metal associated with brittle fracture by trans-granular cleavage. The degradation of properties was associated with the coarsening of nano-carbides observed through TEM images analysis, which was confirmed by SEM fractography of tensile and impact fracture surfaces. The weld bead reached the largest void density and highest susceptibility to corrosion in H2S media when compared to those of the HAZ and base metal.Se realizó un estudio de caracterización para analizar cómo la microestructura afecta a las propiedades mecánicas, corrosión y fractura de la zona afectada por calor (ZAC, soldadura y metal base para tubería envejecida naturalmente durante 21 años a 30 °C. Los resultados indicaron que las microestructuras presentaron daño y consecuentemente reducción en propiedades mecánicas, como consecuencia del envejecimiento por servicio. El estudio mediante MEB mostró que el metal base presenta grano ferrítico grueso. La prueba de tensión indicó que las microestructuras mostraron fluencia discontinua. La mayor resistencia a la tracción se presentó en la soldadura, la cual alcanzó menor energía de impacto en comparación con la ZAC y metal base asociado con fractura frágil por clivaje transgranular. La degradación de las propriedades está en relación con el engrosamiento de nanocarburos observados a

  2. Concrete filled steel pipe inspection using electro magnetic acoustic transducer (EMAT)

    Science.gov (United States)

    Na, Won-Bae; Kundu, Tribikram; Ryu, Yeon-Sun; Kim, Jeong-Tae

    2005-05-01

    Concrete-filled steel pipes are usually exposed in hostile environments such as seawater and deicing materials. The outside corrosion of the steel pipe can reduce the wall thickness and the corrosion-induced delamination of internal concrete can increase internal volume or pressure. In addition, the void that can possibly exist in the pipe reduces the bending resistance. To avoid structural failure due to this type of deterioration, appropriate inspection and repair techniques are to be developed. Guided wave techniques have strong potentials for this kind of inspection because of long-distance inspection capability. Among different transducer-coupling mechanism, electro-magnetic acoustic transducers (EMATs) give relatively consistent results in comparison to piezoelectric transducers since they do not need any couplant. In this study EMATs are used for transmitting and receiving cylindrical guided waves through concrete-filled steel pipes. Through time history curves and wavelet transform, it is shown that EMAT-generated cylindrical guided wave techniques have good potential for the interface inspection of concrete-filled steel pipes.

  3. Structure, mechanical properties, corrosion behavior and cytotoxicity of biodegradable Mg–X (X = Sn, Ga, In) alloys

    Energy Technology Data Exchange (ETDEWEB)

    Kubásek, J., E-mail: Jiri.Kubasek@vscht.cz [Department of Metals and Corrosion Engineering, Institute of Chemical Technology, Prague, Technická 5, 166 28 Prague 6 (Czech Republic); Vojtěch, D. [Department of Metals and Corrosion Engineering, Institute of Chemical Technology, Prague, Technická 5, 166 28 Prague 6 (Czech Republic); Lipov, J.; Ruml, T. [Department of Biochemistry and Microbiology, Institute of Chemical Technology, Prague, Technická 5, 166 28 Prague 6 (Czech Republic)

    2013-05-01

    As-cast Mg–Sn, Mg–Ga and Mg–In alloys containing 1–7 wt.% of alloying elements were studied in this work. Structural and chemical analysis of the alloys was performed by using light and scanning electron microscopy, energy dispersive spectrometry, x-ray diffraction, x-ray photoelectron spectroscopy and glow discharge spectrometry. Mechanical properties were determined by Vickers hardness measurements and tensile testing. Corrosion behavior in a simulated physiological solution (9 g/l NaCl) was studied by immersion tests and potentiodynamic measurements. The cytotoxicity effect of the alloys on human osteosarcoma cells (U-2 OS) was determined by an indirect contact assay. Structural investigation revealed the dendritic morphology of the as-cast alloys with the presence of secondary eutectic phases in the Mg–Sn and Mg–Ga alloys. All the alloying elements showed hardening and strengthening effects on magnesium. This effect was the most pronounced in the case of Ga. All the alloying elements at low concentrations of approximately 1 wt.% were also shown to positively affect the corrosion resistance of Mg. But at higher concentrations of Ga and Sn the corrosion resistance worsened due to galvanic effects of secondary phases. Cytotoxicity tests indicated that Ga had the lowest toxicity, followed by Sn. The most severe toxicity was observed in the case of In. - Highlights: ► Gallium addition (up to 7 wt.%) improves the strength and toughness of as-cast Mg. ► The effect of indium addition (up to 7 wt.%) on mechanical properties is small. ► Gallium, Tin and Indium addition improves the corrosion resistance of as-cast Mg. ► Gallium shows no toxic effect on osteosarcoma cells. ► Tin and indium show serious toxic effect on osteosarcoma cells.

  4. Effect of erbium modification on the microstructure, mechanical and corrosion characteristics of binary Mg–Al alloys

    Energy Technology Data Exchange (ETDEWEB)

    Seetharaman, Sankaranarayanan, E-mail: seetharaman.s@nus.edu.sg [Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, 117576 (Singapore); Blawert, Carsten [Helmholtz-Zentrum Geesthacht, Magnesium Innovation Centre, Max-Planck-Straße 1, D-21502, Geesthacht (Germany); Ng, Baoshu Milton [Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, 117576 (Singapore); Wong, Wai Leong Eugene [School of Mechanical and Systems Engineering, New Castle University International Singapore, 180 Ang Mo Kio Avenue 8, 569830 (Singapore); Goh, Chwee Sim [ITE Technology Development Centre, ITE College Central, 2 Ang Mo Kio Drive, 567720 (Singapore); Hort, Norbert [Helmholtz-Zentrum Geesthacht, Magnesium Innovation Centre, Max-Planck-Straße 1, D-21502, Geesthacht (Germany); Gupta, Manoj, E-mail: mpegm@nus.edu.sg [Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, 117576 (Singapore)

    2015-11-05

    In this study, new erbium modified Mg–Al alloys were developed by integrating trace erbium (in the form of Al{sub 94.67}Er{sub 5.33} master alloy) into pure Mg using disintegrated melt deposition technique. The developed Er- modified Mg–Al alloys were investigated for their microstructural, mechanical and corrosion characteristics in comparison with their unmodified counterparts. Microstructural investigation revealed (i) improved purity, (ii) (marginal) grain refinement, (iii) more uniform second phase distribution and (iv) Al{sub 3}Er phase formation due to Er modification. Mechanical property measurements revealed an overall enhancement under indentation, tension and compression loads. A remarkable improvement in tensile ductility (without adverse effects on strength) by +19%, +29%, and +58% was obtained in Mg–3Al–0.1Er, Mg–6Al–0.3Er and Mg–9Al–0.5Er when compared to Mg–3Al, Mg–6Al and Mg–9Al respectively. While the Mg–6Al–0.3Er alloy exhibited best ductility, the Mg–9Al–0.5Er has the best strength under both tension and compression loads. Corrosion characteristics evaluated by hydrogen evolution, salt spray and electrochemical impedance experiments revealed improved corrosion resistance of Er modified Mg–Al alloys by the enhanced purity levels and the formation of Al–Er phases. - Highlights: • New erbium modified Mg–Al alloys successfully synthesized using DMD method. • Erbium modification promoted Al{sub 3}Er formation and improved the purity. • Remarkable improvement in tensile ductility obtained after erbium modification. • The developed erbium modified Mg–Al alloys exhibit improved corrosion resistance.

  5. Microstructure, mechanical and bio-corrosion properties of Mn-doped Mg–Zn–Ca bulk metallic glass composites

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jingfeng, E-mail: jfwang@cqu.edu.cn [National Engineering Research Center for Magnesium Alloys, College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China); Huang, Song; Li, Yang; Wei, Yiyun [National Engineering Research Center for Magnesium Alloys, College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China); Xi, Xingfeng; Cai, Kaiyong [College of Bioengineering, Chongqing University, Chongqing 400044 (China)

    2013-10-15

    The effects of Mn substitution for Mg on the microstructure, mechanical properties, and corrosion behavior of Mg{sub 69−x}Zn{sub 27}Ca{sub 4}Mn{sub x} (x = 0, 0.5 and 1 at.%) alloys were investigated using X-ray diffraction, compressive tests, electrochemical treatments, and immersion tests, respectively. Microstructural observations showed that the Mg{sub 69}Zn{sub 27}Ca{sub 4} alloy was mainly amorphous. The addition of Mn decreases the glass-forming ability, which results in a decreased strength from 545 MPa to 364 MPa. However, this strength is still suitable for implant application. Polarization and immersion tests in the simulated body fluid at 37 °C revealed that the Mn-doped Mg–Zn–Ca alloys have significantly higher corrosion resistance than traditional ZK60 and pure Mg alloys. Cytotoxicity test showed that cell viabilities of osteoblasts cultured with Mn-doped Mg–Zn–Ca alloys extracts were higher than that of pure Mg. Mg{sub 68.5}Zn{sub 27}Ca{sub 4}Mn{sub 0.5} exhibits the highest bio-corrosion resistance, biocompatibility and has desirable mechanical properties, which could suggest to be used as biomedical materials in the future. - Highlights: • Novel Mn-doped Mg–Zn–Ca bulk metallic glass composites were made by copper mold cast. • The strength of the Mn-doped Mg–Zn–Ca is suitable for implant application. • The Mn-doped Mg–Zn–Ca alloys have significantly high bio-corrosion resistance. • The Mn-doped Mg–Zn–Ca alloys show better cell viabilities than that of pure Mg.

  6. Microstructure, mechanical properties, bio-corrosion properties and cytotoxicity of as-extruded Mg-Sr alloys.

    Science.gov (United States)

    Zhao, Chaoyong; Pan, Fusheng; Zhang, Lei; Pan, Hucheng; Song, Kai; Tang, Aitao

    2017-01-01

    In this study, as-extruded Mg-Sr alloys were studied for orthopedic application, and the microstructure, mechanical properties, bio-corrosion properties and cytotoxicity of as-extruded Mg-Sr alloys were investigated by optical microscopy, scanning electron microscopy with an energy dispersive X-ray spectroscopy, X-ray diffraction, tensile and compressive tests, immersion test, electrochemical test and cytotoxicity test. The results showed that as-extruded Mg-Sr alloys were composed of α-Mg and Mg17Sr2 phases, and the content of Mg17Sr2 phases increased with increasing Sr content. As-extruded Mg-Sr alloy with 0.5wt.% Sr was equiaxed grains, while the one with a higher Sr content was long elongated grains and the grain size of the long elongated grains decreased with increasing Sr content. Tensile and compressive tests showed an increase of both tensile and compressive strength and a decrease of elongation with increasing Sr content. Immersion and electrochemical tests showed that as-extruded Mg-0.5Sr alloy exhibited the best anti-corrosion property, and the anti-corrosion property of as-extruded Mg-Sr alloys deteriorated with increasing Sr content, which was greatly associated with galvanic couple effect. The cytotoxicity test revealed that as-extruded Mg-0.5Sr alloy did not induce toxicity to cells. These results indicated that as-extruded Mg-0.5Sr alloy with suitable mechanical properties, corrosion resistance and good cytocompatibility was potential as a biodegradable implant for orthopedic application. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Pipe drafting and design

    CERN Document Server

    Parisher, Roy A

    2011-01-01

    Pipe Drafting and Design, Third Edition provides step-by-step instructions to walk pipe designers, drafters, and students through the creation of piping arrangement and isometric drawings. It includes instructions for the proper drawing of symbols for fittings, flanges, valves, and mechanical equipment. More than 350 illustrations and photographs provide examples and visual instructions. A unique feature is the systematic arrangement of drawings that begins with the layout of the structural foundations of a facility and continues through to the development of a 3-D model. Advanced chapters

  8. Study on Corrosion Mechanism Between MgO-CaO Refractories and Slag

    Institute of Scientific and Technical Information of China (English)

    YU Yanwen; WANG Ning

    2006-01-01

    Magnesia-Calcia materials containing 22- 53wt% CaO have been investigated for refinery slag corrosion and penetration resistance by Scanning Electron Microscopy (SEM) and XRD. The corrosion and penetration resistance of MgO-CaO materials is enhanced with the increase of CaO content in specimens. It can be explained that, with increase of CaO content, the specimens reacted with slag form higher melting point minerals of C3S and C2S, creating a dense surface layer.which stopped others from penetrating further. Thus. the corrosion and penetration resistance was improved. No matter what kinds of slag were chosen, the depth of penetration decreased with increase of CaO content.

  9. Simulation on function mechanism of Tl(Al2CuLi) precipitate in localized corrosion of Al-Cu-Li alloys

    Institute of Scientific and Technical Information of China (English)

    LI Jin-feng; ZHENG Zi-qiao; REN Wen-da; CHEN Wen-jing; ZHAO Xu-shan; LI Shi-chen

    2006-01-01

    To clarify the corrosion mechanism associated with the precipitate of T1(Al2CuLi) in Al-Li alloys, the simulated bulk precipitate of T1 was fabricated through melting and casting. Its electrochemical behavior and coupling behavior with a(Al) in 3.5%NaCl solution were investigated. Meanwhile, the simulated Al alloy containing T1 particle was prepared and its corrosion morphology was observed. The results show that there exists a dynamic conversion corrosion mechanism associated with the precipitate of T1. At the beginning, the precipitate of T1 is anodic to the alloy base and corrosion occurs on its surface. However,during its corrosion process, its potential moves to a positive direction with immersion time increasing, due to the preferential dissolution of Li and the enrichment of Cu. As a result, the corroded T1 becomes cathodic to the alloy base at a later stage, leading to the anodic dissolution and corrosion of the alloy base at its adjacent periphery. It is suggested that the localized corrosion associated with the precipitate of T1 in Al-Li alloys is caused by the alternate anodic dissolution of the T1 precipitate and the alloy base at its adjacent periphery.

  10. Influence of Cu content on the mechanical properties and corrosion resistance of Mg-Zn-Ca bulk metallic glasses

    Science.gov (United States)

    Zhao, Yan-feng; Zhu, Jian; Chang, Li; Song, Jing-guo; Chen, Xiao-hua; Hui, Xi-dong

    2014-05-01

    (Mg66.2Zn28.8Ca5)100- x Cu x (at%, x = 0, 1, 3, and 5) bulk metallic glasses (BMGs) of 2 mm in diameter were prepared by the conventional copper mold injection casting method. Besides, the influence of Cu content on the microstructure, thermal stability, mechanical properties, and corrosion behavior of Mg-Zn-Ca BMGs was investigated. It is found that the addition of Cu decreases the glass-forming ability of Mg-Zn-Ca BMGs. Crystalline phases are precipitated at a higher Cu content, larger than 3at%. The compressive fracture strength of Mg-Zn-Ca BMGs is enhanced by the addition of Cu. With the formation of in-situ composites, the compressive strength of the Mg-Zn-Ca alloy with 3at% Cu reaches 979 MPa, which is the highest strength among the Mg-Zn-Ca alloys. Furthermore, the addition of Cu also results in the increase of corrosion potential and the decrease of corrosion current density in Mg-Zn-Ca BMGs, thereby delaying their biodegradability.

  11. Effect of Annealing Temperature on the Mechanical and Corrosion Behavior of a Newly Developed Novel Lean Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Yanjun Guo

    2014-09-01

    Full Text Available The effect of annealing temperature (1000–1150 °C on the microstructure evolution, mechanical properties, and pitting corrosion behavior of a newly developed novel lean duplex stainless steel with 20.53Cr-3.45Mn-2.08Ni-0.17N-0.31Mo was studied by means of optical metallographic microscopy (OMM, scanning electron microscopy (SEM, magnetic force microscopy (MFM, scanning Kelvin probe force microscopy (SKPFM, energy dispersive X-ray spectroscopy (EDS, uniaxial tensile tests (UTT, and potentiostatic critical pitting temperature (CPT. The results showed that tensile and yield strength, as well as the pitting corrosion resistance, could be degraded with annealing temperature increasing from 1000 up to 1150 °C. Meanwhile, the elongation at break reached the maximum of 52.7% after annealing at 1050 °C due to the effect of martensite transformation induced plasticity (TRIP. The localized pitting attack preferentially occurred at ferrite phase, indicating that the ferrite phase had inferior pitting corrosion resistance as compared to the austenite phase. With increasing annealing temperature, the pitting resistance equivalent number (PREN of ferrite phase dropped, while that of the austenite phase rose. Additionally, it was found that ferrite possessed a lower Volta potential than austenite phase. Moreover, the Volta potential difference between ferrite and austenite increased with the annealing temperature, which was well consistent with the difference of PREN.

  12. Effect of Annealing Temperature on the Mechanical and Corrosion Behavior of a Newly Developed Novel Lean Duplex Stainless Steel.

    Science.gov (United States)

    Guo, Yanjun; Hu, Jincheng; Li, Jin; Jiang, Laizhu; Liu, Tianwei; Wu, Yanping

    2014-09-12

    The effect of annealing temperature (1000-1150 °C) on the microstructure evolution, mechanical properties, and pitting corrosion behavior of a newly developed novel lean duplex stainless steel with 20.53Cr-3.45Mn-2.08Ni-0.17N-0.31Mo was studied by means of optical metallographic microscopy (OMM), scanning electron microscopy (SEM), magnetic force microscopy (MFM), scanning Kelvin probe force microscopy (SKPFM), energy dispersive X-ray spectroscopy (EDS), uniaxial tensile tests (UTT), and potentiostatic critical pitting temperature (CPT). The results showed that tensile and yield strength, as well as the pitting corrosion resistance, could be degraded with annealing temperature increasing from 1000 up to 1150 °C. Meanwhile, the elongation at break reached the maximum of 52.7% after annealing at 1050 °C due to the effect of martensite transformation induced plasticity (TRIP). The localized pitting attack preferentially occurred at ferrite phase, indicating that the ferrite phase had inferior pitting corrosion resistance as compared to the austenite phase. With increasing annealing temperature, the pitting resistance equivalent number (PREN) of ferrite phase dropped, while that of the austenite phase rose. Additionally, it was found that ferrite possessed a lower Volta potential than austenite phase. Moreover, the Volta potential difference between ferrite and austenite increased with the annealing temperature, which was well consistent with the difference of PREN.

  13. Understanding of Hydriding Mechanisms of Zircaloy-4 Alloy during Corrosion in PWR Simulated Conditions and Influence of Zirconium Hydrides on Zircaloy-4 Corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Bisor-Melloul, C.; Tupin, M.; Bossis, P.; Chene, J.; Bechade, J.L. [CEA Saclay, 91 - Gif sur Yvette (France); Motta, A. [Pennsylvania State Univ. (United States)

    2011-03-15

    Zirconium alloys represent the first containment barrier to fission products, their mechanical integrity is essential for nuclear safety in PWR. During their corrosion in primary water, some of the hydrogen involved in the oxidation reaction with water ingresses into the alloy through the oxide layer. In the metallic matrix, once the solid solution limit is reached at the irradiation temperature, hydrogen precipitates as Zr hydrides mainly located just under the metal/oxide interface due to the thermal gradient across the cladding. As these hydrides may contribute to a larger oxide thickness and to a more fragile behaviour of the cladding, the minimization of hydrogen pick-up is required. Accordingly, since the Zircaloy-4 (Zr-1.3Sn-0.2Fe-0.1Cr) alloy is known to be sensitive to this phenomenon, the understanding of its hydriding mechanism, isotopic exchanges were carried out in D{sub 2}O environment at 360 C and led to the localization, in the oxide scales, of the limiting step for the hydrogen diffusion. To estimate an apparent diffusion coefficient of hydrogen in the oxide formed on Zircaloy-4, we based on SIMS profiles and penetration depth of deuterium in the dense part of the oxide film. Then ERDA estimation of the hydrogen content in zirconia and fusion measurement of the hydrogen content in both metal and oxide were used to estimate a hydrogen flux absorbed by the alloy and hence to deduce an apparent diffusion coefficient. Finally, these 2 methods lead to quite similar values (between 1.10{sup -14} cm{sup 2}/s and 6.10{sup -14} cm{sup 2}/s) which are in accordance with bibliography. Concerning the impact of hydrides on the corrosion of Zircaloy-4, several pre-hydrided and reference samples were corroded simultaneously at 360 C. The characterization of the pre-hydrided samples revealed some changes, as the presence of the Zr{sub 3}O sub-oxide at the inner metal/oxide interface, a lower fraction of -ZrO{sub 2} in the oxide and a faster diffusion of oxygen

  14. On the mechanisms of the corrosion of weathering steel by SO{sub 2} in laboratory studies: influence of the environmental parameters

    Energy Technology Data Exchange (ETDEWEB)

    Marco, J. F., E-mail: jfmarco@iqfr.csic.es [Instituto de Química Física “Rocasolano”, CSIC (Spain)

    2017-11-15

    We report here on the mechanisms underlying the corrosion of weathering steel in accelerated laboratory tests using artificially polluted SO{sub 2}-atmospheres. The role of corrosion parameters such as the SO{sub 2} concentration, the exposure time, the relative humidity and temperature of the environment are discussed in detail. Through the extensive use of Mössbauer spectroscopy in both its transmission and electron detection modes, as well as with the help of other analysis techniques, the characterization of the different corrosion products at the various stages of the corrosion process has been carried out. The results complement the data obtained in field studies and help to understand the mechanisms involved in this complex phenomenon.

  15. An Investigation of the Mechanism of IGA/SCC of Alloy 600 in Corrosion Accelerating Heated Crevice Environments. Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Lumsden, Jesse

    1999-01-01

    OAK-B135 An Investigation of the Mechanism of IGA/SCC of Alloy 600 in Corrosion Accelerating Heated Crevice Environments. Technical Progress Report. This program focuses on understanding the mechanisms causing corrosion damage to steam generator tubes in a pressurized water reactor (PWR) and the effects of the proposed remedial measures. The crevice formed by the tube/tube support plate (T/TSP) intersection in a PWR steam generator is a concentration site for nonvolatile impurities (referred to as hideout) in the steam generator water. The restricted mass transport in the small crevice volume prevents the species, which concentrate during the generation of steam, from quickly dispersing into the bulk water. The concentrated solutions in crevices have been a contributing cause of several forms of corrosion of steam generator tubes including intergranular attack/stress corrosion cracking (IGA/SCC), pitting, and wastage.

  16. Evaluation of Iron Nickel Oxide Nanopowder as Corrosion Inhibitor: Effect of Metallic Cations on Carbon Steel in Aqueous NaCl

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhry, A. U.; Mishra, Brajendra [Colorado School of Mines, Denver (United States); Mittal, Vikas [The Petroleum Institute, Abu Dhabi (United Arab Emirates)

    2016-01-15

    The aim of this study was to evaluate the use of iron-nickel oxide (Fe{sub 2}O{sub 3}.NiO) nanopowder (FeNi) as an anti-corrosion pigment for a different application. The corrosion protection ability and the mechanism involved was determined using aqueous solution of FeNi prepared in a corrosive solution containing 3.5 wt.% NaCl. Anti-corrosion abilities of aqueous solution were determined using electrochemical impedance spectroscopy (EIS) on line pipe steel (API 5L X-80). The protection mechanism involved the adsorption of metallic cations on the steel surface forming a protective film. Analysis of EIS spectra revealed that corrosion inhibition occurred at low concentration, whereas higher concentration of aqueous solution produced induction behavior.

  17. An Evaluation of the Corrosion and Mechanical Performance of Interstitially Surface Hardened Stainless Steel

    Science.gov (United States)

    2013-05-10

    metallography and microhardness profiling. The corrosion performance of the hardened surface is assessed using electrochemical potentiodynamic testing to...cracking resistance, and galling performance. Metallurgical Evaluation: Microhardness testing was conducted for Processes B1 and B2, which represent...incorporated experimental testing conducted on 316L stainless steel that has been surface hardened using available commercial techniques, using both

  18. Revealing Nanoscale Passivation and Corrosion Mechanisms of Reactive Battery Materials in Gas Environments.

    Science.gov (United States)

    Li, Yuzhang; Li, Yanbin; Sun, Yongming; Butz, Benjamin; Yan, Kai; Koh, Ai Leen; Zhao, Jie; Pei, Allen; Cui, Yi

    2017-08-09

    Lithium (Li) metal is a high-capacity anode material (3860 mAh g(-1)) that can enable high-energy batteries for electric vehicles and grid-storage applications. However, Li metal is highly reactive and repeatedly consumed when exposed to liquid electrolyte (during battery operation) or the ambient environment (throughout battery manufacturing). Studying these corrosion reactions on the nanoscale is especially difficult due to the high chemical reactivity of both Li metal and its surface corrosion films. Here, we directly generate pure Li metal inside an environmental transmission electron microscope (TEM), revealing the nanoscale passivation and corrosion process of Li metal in oxygen (O2), nitrogen (N2), and water vapor (H2O). We find that while dry O2 and N2 (99.9999 vol %) form uniform passivation layers on Li, trace water vapor (∼1 mol %) disrupts this passivation and forms a porous film on Li metal that allows gas to penetrate and continuously react with Li. To exploit the self-passivating behavior of Li in dry conditions, we introduce a simple dry-N2 pretreatment of Li metal to form a protective layer of Li nitride prior to battery assembly. The fast ionic conductivity and stable interface of Li nitride results in improved battery performance with dendrite-free cycling and low voltage hysteresis. Our work reveals the detailed process of Li metal passivation/corrosion and demonstrates how this mechanistic insight can guide engineering solutions for Li metal batteries.

  19. Effect of Process Parameters on Microstructural Evolution, Mechanical Properties and Corrosion Behavior of Friction Stir Processed Al 7075 Alloy

    Science.gov (United States)

    Kumar, Atul; Sharma, Sandan Kumar; Pal, Kaushik; Mula, Suhrit

    2017-03-01

    Aim of the present study is to investigate the effect of process parameters on microstructural evolution, mechanical properties and corrosion behavior of an age-hardenable Al 7075 alloy. The alloy plates (6 mm thickness) were friction stir processed (FSPed) at various traverse speed, namely 25, 45, 65, 85, 100 and 150 mm/min at 2 different rpm of 508 and 720. The optimized result in terms of defect-free processed zone with refined microstructure was obtained only at a rotational speed of 720 rpm for a traverse speed of 25, 45, 65 and 85 mm/min. The microstructural evolution was investigated using optical, scanning and transmission electron microscopy. The grain size of the nugget zone was found to decrease with increase in the traverse speed from 25 to 85 mm/min at a constant rpm of 720. The mechanical properties were evaluated by Vickers hardness measurements, tensile and wear testing. Yield strength was found to be the maximum ( 366 MPa) for the FSPed sample processed at 85 mm/min. The hardness values also followed the similar increasing trend with increase in the traverse speed. The wear volume loss decreased by 38% for the sample processed at a traverse speed of 85 mm/min as compared to that of the sample processed at 25 mm/min. The friction coefficient was found to substantiate well with the wear track morphology. The improvement in mechanical properties is ascertained to the refinement of grain size at higher traverse speed (due to less heat input). The FSPed samples showed inferior corrosion resistance in contrast to that of the base metal. This is possibly due to the coarsening of precipitates and depletion of solutes in the matrix. The morphology of the corroded samples corroborated well with the corrosion behavior of the corresponding specimen.

  20. Effect of Process Parameters on Microstructural Evolution, Mechanical Properties and Corrosion Behavior of Friction Stir Processed Al 7075 Alloy

    Science.gov (United States)

    Kumar, Atul; Sharma, Sandan Kumar; Pal, Kaushik; Mula, Suhrit

    2017-02-01

    Aim of the present study is to investigate the effect of process parameters on microstructural evolution, mechanical properties and corrosion behavior of an age-hardenable Al 7075 alloy. The alloy plates (6 mm thickness) were friction stir processed (FSPed) at various traverse speed, namely 25, 45, 65, 85, 100 and 150 mm/min at 2 different rpm of 508 and 720. The optimized result in terms of defect-free processed zone with refined microstructure was obtained only at a rotational speed of 720 rpm for a traverse speed of 25, 45, 65 and 85 mm/min. The microstructural evolution was investigated using optical, scanning and transmission electron microscopy. The grain size of the nugget zone was found to decrease with increase in the traverse speed from 25 to 85 mm/min at a constant rpm of 720. The mechanical properties were evaluated by Vickers hardness measurements, tensile and wear testing. Yield strength was found to be the maximum ( 366 MPa) for the FSPed sample processed at 85 mm/min. The hardness values also followed the similar increasing trend with increase in the traverse speed. The wear volume loss decreased by 38% for the sample processed at a traverse speed of 85 mm/min as compared to that of the sample processed at 25 mm/min. The friction coefficient was found to substantiate well with the wear track morphology. The improvement in mechanical properties is ascertained to the refinement of grain size at higher traverse speed (due to less heat input). The FSPed samples showed inferior corrosion resistance in contrast to that of the base metal. This is possibly due to the coarsening of precipitates and depletion of solutes in the matrix. The morphology of the corroded samples corroborated well with the corrosion behavior of the corresponding specimen.

  1. 苯并咪唑类缓蚀剂缓蚀机理以及研究趋势%Corrosion-inhibiting mechanism and research tendency of the benzimidazole corrosion inhibitor

    Institute of Scientific and Technical Information of China (English)

    王娴

    2012-01-01

    Benzimidazole corrosion inhibitor was a kind of hydrochloride pickling inhibitor. It was possessed various inhibition efficiency because of the distinction of substitutional group. It was occupied the characteristics of high performance,low mammalian toxicity and biodegradation. It also was a kind of adsorption corrosion inhibitor, it also was involved many aspects of resistance chemical corrosion, molecular interface adsorption, the groups covering effects as well as hydrogen-bonding association effects. It was analysised and introduced the preparation method, corrosion-inhibiting mechanism and research tendency of the benzimidazole corrosion inhibitor in this article.%苯并咪唑类缓蚀剂是一类盐酸酸洗缓蚀剂,当取代基不同,其分子呈现不同的缓蚀效率。苯并咪唑类缓蚀剂具有高效、低毒和生物易降解等特点。苯并咪唑缓蚀剂是吸附型缓蚀剂,它涉及到阻化效应、分子界面吸附、基团覆盖效应和氢键缔合效应等多方面。文中介绍了苯并咪唑类缓蚀剂的制备方式、缓释机理以及发展状况。

  2. Influence of silver additions to type 316 stainless steels on bacterial inhibition, mechanical properties, and corrosion resistance

    DEFF Research Database (Denmark)

    Chiang, Wen-Chi; Tseng, I-Sheng; Møller, Per;

    2010-01-01

    techniques. The microstructure of these 316 stainless steels was examined, and the influences of silver additions to 316 stainless steels on bacterial inhibition, mechanical properties, and corrosion resistance were investigated. This study suggested that silver-bearing 316 stainless steels could be used......Bacterial contamination is a major concern in many areas. In this study, silver was added to type 316 stainless steels in order to obtain an expected bacteria inhibiting property to reduce the occurrence of bacterial contamination. Silver-bearing 316 stainless steels were prepared by vacuum melting...

  3. MECHANICAL PROPERTIES AND CORROSION PROTECTION OF CARBON STEEL COATED WITH AN EPOXY BASED POWDER COATING CONTAINING MONTMORILONITE FUNCTIONALIZED WITH SILANE

    Directory of Open Access Journals (Sweden)

    Paula Tibola Bertuoli

    2014-06-01

    Full Text Available In the present work the MMT-Na+ clay was functionalized with 3-aminopropyltriethoxysilane (γ-APS and incorporated in a commercial formulation epoxy-based powder coating in a proportion of 8 wt% and applied on 1008 carbon steel panels by electrostatic spray. Adhesion, flexibility, impact and corrosion performance in salt spray chamber tests were performed to evaluate the coatings. The presence of clay did not affect the mechanical properties of the film, however greater subcutaneous migration was assessed after the completion of salt spray testing, which can compromise the use of paints obtained as primers.

  4. Effect of micrometer-scale metallic fillers on the mechanical and corrosion resistance properties of alternative materials for conservative dentistry.

    Science.gov (United States)

    Luponio, C; Causa, F; Angelini, E; Pinasco, M R; Ambrosio, L

    2006-01-01

    In conservative dentistry, glass-ionomer cements (GICs) have been proposed as substitutes for composite resins. This is because the latter, although widely used over the last 10 yrs, exhibit inadequate physico-chemical properties. Although the performance of a typical commercial GIC is not yet optimal for restorative dentistry, the addition of metallic filler could improve this. In this study, a series of commercially available GICs were incorporated in trial dental amalgams, whose mechanical and calorimetric properties and morphologies, were examined. The metallic component of these amalgams comprised one of three metallic fillers, each including micrometer-scale metal particles of a different shape. The corrosion resistance of the amalgams, in fluids simulating the oral cavity environment, was also studied. The addition of metallic filler to GIC produced a general improvement in mechanical properties. Of particular note were increases in the elastic modulus, up to around sixfold, with the addition of Valiant metallic filler to the GIC Fuji II, and of the stress at break, up to around fourfold, for the New Gen metallic filler/GIC Fuji II amalgam. In these cases, the mechanical properties of dentine were studied. Micrographic observations showed a highly compact structure of the added GICs, thus reflecting a reduction in shrinkage. Calorimetric and dilatometric analyses further confirmed the suitability for applications in preservative dentistry. Finally, with respect to corrosion resistance, the effect of the introduction of the metallic filler was beneficial in samples with low porosity.

  5. Novel electrochemical approach to study corrosion mechanism of Al-Au wire-bond pad interconnections

    DEFF Research Database (Denmark)

    Elisseeva, O. V.; Bruhn, A.; Cerezo, J.;

    2013-01-01

    A gold-aluminium material combination is typically employed as an interconnection for microelectronic devices. One of the reliability risks of such devices is that of corrosion of aluminium bond pads resulting from the galvanic coupling between an aluminium bond pad and a gold wire. The research...... presented in this manuscript focuses on studying bond pad corrosion by selecting an appropriate model system and a dedicated set of electrochemical and analytical experimental tools. Taking into account the complex three-dimensional structure and the small dimensions of Au-Al interconnections (around 50...... gold films were applied on Ti-Al covered silicon surfaces, and their morphology and electrochemical behaviour were analysed using the localised electrochemical cell, scanning vibrating electrode technique, scanning electron microscopy-energy dispersive X-ray spectroscopy, scanning electron microscopy...

  6. Mechanism of Pitting Corrosion Prevention by Nitrite in Carbon Steel Exposed to Dilute Salt Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Philip E. Zapp; John W. Van Zee

    2002-02-01

    The research has developed a broad fundamental understanding of the inhibition action of nitrite ions in preventing nitrate pitting corrosion of carbon steel tanks containing high-level radioactive waste. This fundamental understanding can be applied to specific situations during waste removal for permanent disposition and waste tank closure to ensure that the tanks are maintained safely. The results of the research provide the insight necessary to develop solutions that prevent further degradation.

  7. Recent Developments in the Identification of Mechanisms for Microbiologically Influenced Corrosion

    Science.gov (United States)

    2010-09-23

    31 (1997) pp.813-818. 36 Weiner, J.M., Lovley D.R.; "Rapid Benzene Degradation in Methanogenic Sediments from a Petroleum-Contaminated Aquifer ...wide variety of electron donors and acceptors. In the absence of an electron acceptor, SRB can enter into syntrophic relationships with methanogens or...Microorganisms," Corrosion, 64(2008) pp.854-859. 22 Dolfing, J., Tiedje J.M.; "Acetate Inhibition of Methanogenic Syntrophic Benzoate Degradation

  8. Corrosion of steel structures in sea-bed sediment

    Indian Academy of Sciences (India)

    Xiutong Wang; Jizhou Duan; Yan Li; Jie Zhang; Shide Ma; Baorong Hou

    2005-04-01

    Seabed sediment (SBS) is a special soil that is covered by seawater. With the developments in marine oil exploitation and engineering, more and more steel structures have been buried in SBS. SBS corrosion has now become a serious problem in marine environment and an important issue in corrosion science. In this paper, approach in the field of SBS corrosion is reviewed. Electrochemical and microbial corrosion factors, corrosion mechanism, measurement of metal corrosion rate, corrosion evaluation and prediction of corrosion are also discussed here.

  9. Corrosion inhibitors; Los inhibidores de corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Godinez, L. A.; Meas, Y.; Ortega-Borges, R.; Corona, A.

    2003-07-01

    In this paper, we briefly describe the characteristics, cost and electrochemical nature of the corrosion phenomena as well as some of the technologies that are currently employed to minimize its effect. The main subject of the paper however, deals with the description, classification and mechanism of protection of the so-called corrosion inhibitors. Examples of the use of these substances in different aggressive environments are also presented as means to show that these compounds, or their combination, can in fact be used as excellent and relatively cheap technologies to control the corrosion of some metals. In the last part of the paper, the most commonly used techniques to evaluate the efficiency and performance of corrosion inhibitors are presented as well as some criteria to make a careful and proper selection of a corrosion inhibitor technology in a given situation. (Author) 151 refs.

  10. Improved mechanical and corrosion properties of nickel composite coatings by incorporation of layered silicates

    Energy Technology Data Exchange (ETDEWEB)

    Tientong, J. [University of North Texas, Department of Chemistry, 1155 Union Circle #305070, Denton, TX 76203 (United States); Ahmad, Y.H. [Center for Advanced Materials, P.O. Box 2713, Qatar University, Doha (Qatar); Nar, M.; D' Souza, N. [University of North Texas, Department of Mechanical and Energy Engineering, Denton, TX 76207 (United States); Mohamed, A.M.A. [Center for Advanced Materials, P.O. Box 2713, Qatar University, Doha (Qatar); Golden, T.D., E-mail: tgolden@unt.edu [University of North Texas, Department of Chemistry, 1155 Union Circle #305070, Denton, TX 76203 (United States)

    2014-05-01

    Layered silicates as exfoliated montmorillonite are incorporated into nickel films by electrodeposition, enhancing both corrosion resistance and hardness. Films were deposited onto stainless steel from a plating solution adjusted to pH 9 containing nickel sulfate, sodium citrate, and various concentrations of exfoliated montmorillonite. The presence of the incorporated layered silicate was confirmed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. The composite films were also compact and smooth like the pure nickel films deposited under the same conditions as shown by scanning electron microscopy. X-ray diffraction results showed that incorporation of layered silicates into the film do not affect the nickel crystalline fcc structure. The nanocomposite films exhibited improved stability and adhesion. Pure nickel films cracked and peeled from the substrate when immersed in 3.5% NaCl solution within 5 days, while the nanocomposite films remained attached even after 25 days. The corrosion resistance of the nickel nanocomposites was also improved compared to nickel films. Nickel-layered silicate composites showed a 25% increase in Young's modulus and a 20% increase in hardness over pure nickel films. - Highlights: • 0.05–2% of layered silicates are incorporated into crystalline nickel films. • Resulting composite films had improved stability and adhesion. • Corrosion resistance improved for the composite films. • Hardness improved 20% and young's modulus improved 25% for the composite films.

  11. Corrosion resistance, chemistry, and mechanical aspects of Nitinol surfaces formed in hydrogen peroxide solutions

    Energy Technology Data Exchange (ETDEWEB)

    Shabalovskay, Svetlana A.; Anderegg, James W.; Undisz, Andreas; Rettenmayr, Markus; Rondelli, Gianni C.

    2012-06-12

    Ti oxides formed naturally on Nitinol surfaces are only a few nanometers thick. To increase their thickness, heat treatments are explored. The resulting surfaces exhibit poor resistance to pitting corrosion. As an alternative approach to accelerate surface oxidation and grow thicker oxides, the exposure of Nitinol to strong oxidizing H2O2 aqueous solutions (3 and 30%) for various periods of time was used. Using X-Ray Photoelectron Spectroscopy (XPS) and Auger spectroscopy, it was found that the surface layers with variable Ti (6–15 at %) and Ni (5–13 at %) contents and the thickness up to 100 nm without Ni-enriched interfaces could be formed. The response of the surface oxides to stress in superelastic regime of deformations depended on oxide thickness. In the corrosion studies performed in both strained and strain-free states using potentiodynamic and potentiostatic polarizations, the surfaces treated in H2O2 showed no pitting in corrosive solution that was assigned to higher chemical homogeneity of the surfaces free of secondary phases and inclusions that assist better biocompatibility of Nitinol medical devices. © 2012 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 100B: 1490–1499, 2012

  12. Embrittlement and anodic process in stress corrosion cracking: study of the influent micro-mechanical parameters; Fragilisation et processus anodiques en corrosion sous contrainte: etude des parametres micro-mecaniques influents

    Energy Technology Data Exchange (ETDEWEB)

    Tinnes, J.Ph

    2006-11-15

    We study the influence of local mechanical parameters on crack propagation in Stress Corrosion Cracking, at the scale of the microstructure. Two systems are compared: the CuAl{sub 9}Ni{sub 3}Fe{sub 2} copper-aluminium alloy in synthetic sea water under cathodic polarization, where the crack propagation mechanism is related to strain-assisted anodic dissolution, and the 316L austenitic stainless steel in MgCl{sub 2} solution, where embrittlement mechanisms related to hydrogen effects prevail. We use micro-notched tensile specimen that allow to study isolated short cracks. These experiments are modelled by means of finite elements calculations, and further characterized by Electron Back scattered Diffraction (EBSD) in the case of the 316L alloy. In terms of the local mechanical parameters that control propagation, fundamental differences are outlined between the two systems. They are discussed from the viewpoint of the available models of Stress Corrosion Cracking. (author)

  13. Corrosion electrochemical mechanism of chemical mechanical polishing of copper in K3Fe(CN)6 solution

    Institute of Scientific and Technical Information of China (English)

    何捍卫; 胡岳华; 黄可龙

    2002-01-01

    Polarization curves of copper were measured in NH3*H2O media containing K3Fe(CN)6. Components of passive film were analyzed by XPS. Relation of polishing rate with corrosion current density was investigated during CMP. Copper can be passivated in the slurry and main component of passive film is Cu4Fe(CN)6. Relation of polishing rate with corrosion current density is linear direct ratio and expressed as R=KJcorr during CMP. Coefficient K varies with different slurry systems but is constant under experimental conditions, which does not vary with NH3*H2O, K3Fe(CN)6, γ-Al2O3 concentrations, polishing pressures and rotative rate in a slurry system during CMP.

  14. Assessment of NDE Methods on Inspection of HDPE Butt Fusion Piping Joints for Lack of Fusion with Validation from Mechanical Testing

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Michael T.; Cinson, Anthony D.; Crawford, Susan L.; Doctor, Steven R.; Moran, Traci L.; Watts, Michael W.

    2010-12-01

    Studies at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, are being conducted to evaluate nondestructive examinations (NDE) coupled with mechanical testing of butt fusion joints in high-density polyethylene (HDPE) pipe for assessing lack of fusion. The work provides information to the U.S. Nuclear Regulatory Commission (NRC) on the effectiveness of volumetric inspection techniques of HDPE butt fusion joints in Section III, Division 1, Class 3, buried piping systems in nuclear power plants. This paper describes results from preliminary assessments using ultrasonic and microwave nondestructive techniques and mechanical testing with the high-speed tensile impact test and the side-bend test for determining joint integrity. A series of butt joints were fabricated in 3408, 12-in. IPS DR-11 HDPE material by varying the fusion parameters to create good joints and joints containing a range of lack-of-fusion conditions. Six of these butt joints were volumetrically examined with time-of-flight diffraction (TOFD), phased-array (PA) ultrasound, and the Evisive microwave system. The outer-diameter weld beads were removed for the microwave inspection. In two of the four pipes, both the outer and inner weld beads were removed and the pipe joints re-evaluated. The pipes were sectioned and the joints destructively evaluated with the side-bend test by cutting portions of the fusion joint into slices that were planed and bent. The last step in this limited study will be to correlate the fusion parameters, nondestructive, and destructive evaluation results to validate the effectiveness of what each NDE technology detects and what each does not detect. The results of the correlation will be used in identifying any future work that is needed.

  15. Effect of steel reinforcement with different degree of corrosion on degeneration of mechanical performance of reinforced concrete frame joints

    Directory of Open Access Journals (Sweden)

    Wu Xu

    2016-02-01

    Full Text Available Beam-column joints which shoulders high-level and vertical shearing effect that maintains balance of beam and column end is the major component influencing the performance of the whole framework. Post earthquake investigation suggests that collapse of frame structure is induced by failure of joints in most cases. Thus, beam-column joints must have strong bearing capacity and good ductility, and reinforced concrete structure just meets the above requirement. But corrosion caused by long time use of reinforced concrete framework will lead to degeneration of mechanical performance of joints. To find out the rule of effect of steel reinforcement with different corrosion rate on degeneration of bearing capacity of reinforced concrete framework joints, this study made a nonlinear numerical analysis on fifteen models without stirrup in the core area of reinforced concrete frame joints using displacement method considering axial load ratio of column end and constraint condition. This work aims to find out the key factor that influences mechanical performance of joints, thus to provide a basis for repair and reinforcement of degenerated framework joints.

  16. Effect of copper addition on mechanical properties, corrosion resistance and antibacterial property of 316L stainless steel.

    Science.gov (United States)

    Xi, Tong; Shahzad, M Babar; Xu, Dake; Sun, Ziqing; Zhao, Jinlong; Yang, Chunguang; Qi, Min; Yang, Ke

    2017-02-01

    The effects of addition of different Cu content (0, 2.5 and 3.5wt%) on mechanical properties, corrosion resistance and antibacterial performance of 316L austenitic stainless steel (SS) after solution and aging treatment were investigated by mechanical test, transmission electron microscope (TEM), X-ray diffraction (XRD), electrochemical corrosion, X-ray photoelectron spectroscopy (XPS) and antibacterial test. The results showed that the Cu addition and heat treatment had no obvious influence on the microstructure with complete austenite features. The yield strength (YS) after solution treatment was almost similar, whereas the aging treatment obviously increased the YS due to formation of tiny Cu-rich precipitates. The pitting and protective potential of the solution treated Cu-bearing 316L SS in 0.9wt% NaCl solution increased with increasing Cu content, while gradually declined after aging, owing to the high density Cu-rich precipitation. The antibacterial test proved that higher Cu content and aging were two compulsory processes to exert good antibacterial performance. The XPS results further indicated that aging enhanced the Cu enrichment in passive film, which could effectively stimulate the Cu ions release from the surface of passive film.

  17. Fault Diagnosis for Nonlinear Hydraulic-Mechanical Drilling Pipe Handling System

    DEFF Research Database (Denmark)

    Choux, Martin; Blanke, Mogens

    2011-01-01

    Leakage and increased friction are common faults in hydraulic cylinders that can have serious consequences if they are not detected at early stage. In this paper, the design of a fault detector for a nonlinear hydraulic mechanical system is presented. By considering the system in steady state, tw...

  18. Review on Stress Corrosion and Corrosion Fatigue Failure of Centrifugal Compressor Impeller

    Institute of Scientific and Technical Information of China (English)

    SUN Jiao; CHEN Songying; QU Yanpeng; LI Jianfeng

    2015-01-01

    Corrosion failure, especially stress corrosion cracking and corrosion fatigue, is the main cause of centrifugal compressor impeller failure. And it is concealed and destructive. This paper summarizes the main theories of stress corrosion cracking and corrosion fatigue and its latest developments, and it also points out that existing stress corrosion cracking theories can be reduced to the anodic dissolution (AD), the hydrogen-induced cracking (HIC), and the combined AD and HIC mechanisms. The corrosion behavior and the mechanism of corrosion fatigue in the crack propagation stage are similar to stress corrosion cracking. The effects of stress ratio, loading frequency, and corrosive medium on the corrosion fatigue crack propagation rate are analyzed and summarized. The corrosion behavior and the mechanism of stress corrosion cracking and corrosion fatigue in corrosive environments, which contain sulfide, chlorides, and carbonate, are analyzed. The working environments of the centrifugal compressor impeller show the behavior and the mechanism of stress corrosion cracking and corrosion fatigue in different corrosive environments. The current research methods for centrifugal compressor impeller corrosion failure are analyzed. Physical analysis, numerical simulation, and the fluid-structure interaction method play an increasingly important role in the research on impeller deformation and stress distribution caused by the joint action of aerodynamic load and centrifugal load.

  19. Piping Flexibility

    Science.gov (United States)

    1978-01-01

    A NASA computer program aids Hudson Engineering Corporation, Houston, Texas, in the design and construction of huge petrochemical processing plants like the one shown, which is located at Ju'aymah, Saudi Arabia. The pipes handling the flow of chemicals are subject to a variety of stresses, such as weight and variations in pressure and temperature. Hudson Engineering uses a COSMIC piping flexibility analysis computer program to analyze stresses and unsure the necessary strength and flexibility of the pipes. This program helps the company realize substantial savings in reduced engineering time.

  20. Piping Analysis

    Science.gov (United States)

    1980-01-01

    Burns & McDonnell provide architectural and engineering services in planning, design and construction of a wide range of projects all over the world. In design analysis, company regularly uses COSMIC computer programs. In computer testing piping design of a power plant, company uses Pipe Flexibility Analysis Program (MEL-21) to analyze stresses due to weight, temperature, and pressure found in proposed piping systems. Individual flow rates are put into the computer, then computer calculates the pressure drop existing across each component; if needed, design corrections or adjustments can be made and rechecked.

  1. Heat pipes

    CERN Document Server

    Dunn, Peter D

    1994-01-01

    It is approximately 10 years since the Third Edition of Heat Pipes was published and the text is now established as the standard work on the subject. This new edition has been extensively updated, with revisions to most chapters. The introduction of new working fluids and extended life test data have been taken into account in chapter 3. A number of new types of heat pipes have become popular, and others have proved less effective. This is reflected in the contents of chapter 5. Heat pipes are employed in a wide range of applications, including electronics cooling, diecasting and injection mo

  2. Tantalum Nitride-Decorated Titanium with Enhanced Resistance to Microbiologically Induced Corrosion and Mechanical Property for Dental Application.

    Directory of Open Access Journals (Sweden)

    Yifei Zhang

    Full Text Available Microbiologically induced corrosion (MIC of metallic devices/implants in the oral region is one major cause of implant failure and metal allergy in patients. Therefore, it is crucial to develop practical approaches which can effectively prevent MIC for broad clinical applications of these materials. In the present work, tantalum nitride (TaN-decorated titanium with promoted bio-corrosion and mechanical property was firstly developed via depositing TaN layer onto pure Ti using magnetron sputtering. The microstructure and chemical constituent of TaN coatings were characterized, and were found to consist of a hard fcc-TaN outer layer. Besides, the addition of TaN coatings greatly increased the hardness and modulus of pristine Ti from 2.54 ± 0.20 to 29.88 ± 2.59 GPa, and from 107.19 ± 6.98 to 295.46 ± 19.36 GPa, respectively. Potentiodynamic polarization and electrochemical impedance spectroscopy studies indicated that TaN coating exhibited higher MIC resistance in comparison to bare Ti and TiN-coated coating in two bacteria-containing artificial saliva solutions. Moreover, the biofilm experiment showed that the TaN-decorated Ti sample possessed good antibacterial performance. The SEM and XPS results after biofilm removal demonstrated that TaN film remained its integrity and stability, while TiN layer detached from Ti surface in the bio-corrosion tests, demonstrating the anti-MIC behavior and the strong binding property of TaN coating to Ti substrate. Considering all these results, TaN-decorated Ti material exhibits the optimal comprehensive performance and holds great potential as implant material for dental applications.

  3. A study on the mechanism of stress corrosion cracking of duplex stainless steels in hot alkaline-sulfide solution

    Science.gov (United States)

    Chasse, Kevin Robert

    Duplex stainless steels (DSS) generally have superior strength and corrosion resistance as compared to most standard austenitic and ferritic stainless grades owing to a balanced microstructure of austenite and ferrite. As a result of having favorable properties, DSS have been selected for the construction of equipment in pulp and paper, chemical processing, nuclear, oil and gas as well as other industries. The use of DSS has been restricted in some cases because of stress corrosion cracking (SCC), which can initiate and grow in either the ferrite or austenite phase depending on the environment. Thorough understanding of SCC mechanisms of DSS in chloride- and hydrogen sulfide-containing solutions has been useful for material selection in many environments. However, understanding of SCC mechanisms of DSS in sulfide-containing caustic solutions is limited, which has restricted the capacity to optimize process and equipment design in pulp and paper environments. Process environments may contain different concentrations of hydroxide, sulfide, and chloride, altering corrosion and SCC susceptibility of each phase. Crack initiation and growth behavior will also change depending on the relative phase distribution and properties of austenite and ferrite. The role of microstructure and environment on the SCC of standard grade UNS S32205 and lean grade UNS S32101 in hot alkaline-sulfide solution were evaluated in this work using electrochemical, film characterization, mechanical testing, X-ray diffraction, and microscopy techniques. Microstructural aspects, which included residual stress state, phase distribution, phase ratio, and microhardness, were related to the propensity for SCC crack initiation in different simulated alkaline pulping liquors at 170 °C. Other grades of DSS and reference austenitic and superferritic grades of stainless steel were studied using exposure coupons for comparison to understand compositional effects and individual phase susceptibility

  4. The Dislocation Mechanism of Stress Corrosion Embrittlement in Ti-6Al-2Sn-4Zr-6Mo

    Science.gov (United States)

    Chapman, Tamara P.; Vorontsov, Vassili A.; Sankaran, Ananthi; Rugg, David; Lindley, Trevor C.; Dye, David

    2016-01-01

    An observation of the dislocation mechanisms operating below a naturally initiated hot-salt stress corrosion crack is presented, suggesting how hydrogen may contribute to embrittlement. The observations are consistent with the hydrogen-enhanced localized plasticity mechanism. Dislocation activity has been investigated through post-mortem examination of thin foils prepared by focused ion beam milling, lifted directly from the fracture surface. The results are in agreement with the existing studies, suggesting that hydrogen enhances dislocation motion. It is found that the presence of hydrogen in (solid) solution results in dislocation motion on slip systems that would not normally be expected to be active. A rationale is presented regarding the interplay of dislocation density and the hydrogen diffusion length.

  5. Characterisation of Al corrosion and its impact on the mechanical performance of composite cement wasteforms by the acoustic emission technique

    Science.gov (United States)

    Spasova, L. M.; Ojovan, M. I.

    2008-04-01

    In this study acoustic emission (AE) non-destructive method was used to evaluate the mechanical performance of cementitious wasteforms with encapsulated Al waste. AE waves generated as a result of Al corrosion in small-size blast furnace slag/ordinary Portland cement wasteforms were recorded and analysed. The basic principles of the conventional parameter-based AE approach and signal-based analysis were combined to establish a relationship between recorded AE signals and different interactions between the Al and the encapsulating cement matrix. The AE technique was shown as a potential and valuable tool for a new area of application related to monitoring and inspection of the mechanical stability of cementitious wasteforms with encapsulated metallic wastes such as Al.

  6. Effect of different processings on mechanical property and corrosion behavior in simulated body fluid of Mg-Zn-Y-Nd alloy for cardiovascular stent application

    Science.gov (United States)

    Zhu, Shi-Jie; Liu, Qian; Qian, Ya-Feng; Sun, Bin; Wang, Li-Guo; Wu, Jing-Min; Guan, Shao-Kang

    2014-09-01

    The biomagnesium alloys have been considered to be one of the most potential biodegradable metal materials due to its good mechanical compatibility, biological compatibility, biological security and biodegradable characteristics. However, the two major problems of high degradation rates in physiological environment and low mechanical properties prevent the development of biomagnesium alloys. In the present work, the samples of Mg-Zn-Y-Nd alloy were prepared by cyclic extrusion compression (CEC) and equal channel angular pressing (ECAP). The microstructures, mechanical properties of alloy and its corrosion behavior in simulated body fluid (SBF) were evaluated. The results reveal that Mg-Zn-Y-Nd alloy consists of equiaxial fine grain structure with the homogeneous distribution of micrometer size and nano-sized second phase, which was caused by the dynamic recrystallization during the ECAP and CEC. The corrosion resistance of alloy was improved. The tensile and corrosion resistance were improved, especially the processed alloy exhibit uniform corrosion performances and decreased corrosion rate. This will provide theoretical ground for Mg-Zn-Y-Nd alloy as vascular stent application.

  7. Improved Corrosion Resistance and Mechanical Properties of CrN Hard Coatings with an Atomic Layer Deposited Al2O3 Interlayer.

    Science.gov (United States)

    Wan, Zhixin; Zhang, Teng Fei; Lee, Han-Bo-Ram; Yang, Ji Hoon; Choi, Woo Chang; Han, Byungchan; Kim, Kwang Ho; Kwon, Se-Hun

    2015-12-01

    A new approach was adopted to improve the corrosion resistance of CrN hard coatings by inserting a Al2O3 layer through atomic layer deposition. The influence of the addition of a Al2O3 interlayer, its thickness, and the position of its insertion on the microstructure, surface roughness, corrosion behavior, and mechanical properties of the coatings was investigated. The results indicated that addition of a dense atomic layer deposited Al2O3 interlayer led to a significant decrease in the average grain size and surface roughness and to greatly improved corrosion resistance and corrosion durability of CrN coatings while maintaining their mechanical properties. Increasing the thickness of the Al2O3 interlayer and altering its insertion position so that it was near the surface of the coating also resulted in superior performance of the coating. The mechanism of this effect can be explained by the dense Al2O3 interlayer acting as a good sealing layer that inhibits charge transfer, diffusion of corrosive substances, and dislocation motion.

  8. 49 CFR 192.275 - Cast iron pipe.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Cast iron pipe. 192.275 Section 192.275... Cast iron pipe. (a) Each caulked bell and spigot joint in cast iron pipe must be sealed with mechanical leak clamps. (b) Each mechanical joint in cast iron pipe must have a gasket made of a...

  9. Mechanical Structure Design of PGZX-1 Pipe Climbing Robot%PGZX-1型炉管爬行机器人机械结构设计

    Institute of Scientific and Technical Information of China (English)

    张灵聪; 李浩; 仲于海

    2012-01-01

    PGZX-1 pipe is specific reference the straight pipe which pipe diameter is from 50 mm to 90 mm, and its tube spacing is 30 mm. At present, most factory boiler pipes and heating pipes of thermal power plant belong to it It is easily to have serious cementation phenomenon that heated the furnace tube for a long time, and the cementation will make the pipe wall material carbon amount to advance, thus cause the pipe wall hardening changes crisp, extremely easy to create the furnace tube break. The frequent examination to the tube column can know the furnace tube interior cementation situation, will guarantee the work more stable and more safe. One kind robot is proposed that can climb the tube column, and it can climb the tube does not on the limit of column material and the caliber. It will reduce the size and weight of the new robot This design aimed at the problem which is that the tube spacing is narrow and small, the caliber change and the body distortion we faced while we do the work of tube crawling. The robot's principle plan, and elaborated the design of the new crawl robot primary mechanical structure principle are introduced.%PGZX-1型炉管特指管径在50 mm-90 mm,管间距在30 mm左右的直管.目前很多化工厂锅炉管道和热电厂加热管均属于PGZX-1型炉管.因长期受热,炉管极易产生严重的渗碳现象,需对管柱渗碳层厚度进行检测,以随对了解炉管内部渗碳情况,确保工作的稳定性及安全性.提出了一种能够攀爬管柱的机器人,这种机器人不受攀爬管柱材料和管径限制,在尺寸及重量上实现最小化.对炉管爬行工作时面临的管间距狭小,管径变动及管体变形进行了针对性设计,介绍了新型爬管机器人的原理方案,阐述了新型爬管机器人主要机械结构的设计原理.

  10. Case study of a fast propagating bacteriogenically induced concrete corrosion in an Austrian sewer system

    Science.gov (United States)

    Grengg, Cyrill; Mittermayr, Florian; Baldermann, Andre; Böttcher, Michael; Leis, Albrecht; Koraimann, Günther; Dietzel, Martin

    2015-04-01

    Reaction mechanisms leading to microbially induced concrete corrosion (MICC) are highly complex and often not fully understood. The aim of the present case study is to contribute to a deeper understanding of reaction paths, environmental controls, and corrosion rates related to MICC in a modern Austrian sewer system by introducing an advanced multi proxy approach that comprises gaseous, hydro-geochemical, bacteriological, and mineralogical analyses. Various crucial parameters for detecting alteration features were determined in the field and laboratory, including (i) temperature, pH, alkalinity, chemical compositions of the solutions, (ii) chemical and mineralogical composition of solids, (iii) bacterial analysis, and (iv) concentrations of gaseous H2S, CH4 and CO2 within the sewer pipe atmosphere. An overview of the field site and analytical results, focusing on reaction mechanisms causing the corrosion, as well as possible remediation strategies will be presented.

  11. Controlled Thermal-Mechanical Processing of Tubes and Pipes for Enhanced Manufacturing and Performance

    Energy Technology Data Exchange (ETDEWEB)

    Kolarik, Robert V.

    2005-11-11

    The Alloy Steel Business of The Timken Company won an award for the controlled thermo-mechanical processing (CTMP) project and assembled a strong international public/private partnership to execute the project. The premise of the CTMP work was to combine Timken's product understanding with its process expertise and knowledge of metallurgical and deformation fundamentals developed during the project to build a predictive process design capability. The CTMP effort succeeded in delivering a pc-based capability in the tube optimization model, with a virtual pilot plant (VPP) feature to represent the desired tube making process to predict the resultant microstructure tailored for the desired application. Additional tasks included a system for direct, online measurement of grain size and demonstration of application of CTMP via robotically enhanced manufacturing.

  12. The corrosive nature of manganese in drinking water

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez-Bastida, C. [Centro Interamericano de Recursos del Agua, Facultad de Ingeniería, Universidad Autónoma del Estado de México, Carretera Toluca-Ixtlahuaca, Km. 14.5, C.P. 50200, Toluca, Estado de México (Mexico); Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón y Tollocan s/n, C.P. 50000, Toluca, Estado de México (Mexico); Martínez-Miranda, V.; Vázquez-Mejía, G. [Centro Interamericano de Recursos del Agua, Facultad de Ingeniería, Universidad Autónoma del Estado de México, Carretera Toluca-Ixtlahuaca, Km. 14.5, C.P. 50200, Toluca, Estado de México (Mexico); Solache-Ríos, M., E-mail: marcos.solache@inin.gob.mx [Departamento de Química, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C.P. 11801 México, D.F. (Mexico); Fonseca-Montes de Oca, G. [Centro Interamericano de Recursos del Agua, Facultad de Ingeniería, Universidad Autónoma del Estado de México, Carretera Toluca-Ixtlahuaca, Km. 14.5, C.P. 50200, Toluca, Estado de México (Mexico); Trujillo-Flores, E. [Facultad de Ingeniería, Universidad Autónoma del Estado de México, Cerro de Coatepec s/n, Ciudad Universitaria, C.P. 50130, Toluca, Estado de México (Mexico)

    2013-03-01

    Corrosion problems having to do with drinking water distribution systems are related to many processes and factors and two of them are ionic acidity and carbon dioxide, which were considered in this work. The corrosion character of water is determined by the corrosion indexes of Langelier, Ryznar, Larson, and Mojmir. The results show that pipes made of different materials, such as plastics or metals, are affected by corrosion, causing manganese to be deposited on materials and dissolved in water. The deterioration of the materials, the degree of corrosion, and the deposited corrosion products were determined by X-ray diffraction and Scanning Electron Microscopy. High levels of manganese and nitrate ions in water may cause serious damage to the health of consumers of water. Three wells were examined, one of them presented a high content of manganese; the others had high levels of nitrate ions, which increased the acidity of the water and, therefore, the amount of corrosion of the materials in the distribution systems. - Highlights: ► Corrosion of distribution systems affects the quality of drinking water. ► Corrosion in water distribution systems is related to acidity and carbon dioxide. ► Pipes are corroded and manganese is deposited on pipes and dissolved in water. ► The deterioration of the pipes and the corrosion products were determined. ► Nitrate ions increase the acidity of water in the wells.

  13. DEVELOPMENT OF A REPRODUCIBLE SCREENING METHOD TO DETERMINE THE MECHANISM AND EFFECT OF ORGANIC ACIDS AND OTHER CONTAMINANTS ON THE CORROSION OF ALUMINUM-FINNED COPPER-TUBE HEAT EXCHANGE COILS

    Energy Technology Data Exchange (ETDEWEB)

    Richard A. Corbett; Dave Severance

    2005-02-01

    Formicary corrosion is an insidious form of localized pitting corrosion. Notoya (1997b) wrote, ?In Japan, this type of corrosion is found in approximately 10% of cases of premature failure of copper tubes.? Attack characteristically features very small surface pits which are not visible to the un-aided eye, and random directional changes in the underlying copper metal. Attack is rapid. Failures have occurred before installation, shortly thereafter, or within several years later. Objectives of this Research Project Conduct an in depth literature search on the subject of formicary corrosion. Define the corrosion mechanism. Develop a test method that will reproduce formicary corrosion. Develop a test method for screening candidate materials that could cause formicary corrosion.

  14. Influence of Simulated Acid Rain Corrosion on the Uniaxial Tensile Mechanical Properties of Concrete

    Directory of Open Access Journals (Sweden)

    Ying-zi Zhang

    2012-01-01

    Full Text Available An experimental study on the uniaxial tensile property of concrete exposed to the acid rain environment was carried out. Acid rain with pH level of 1.0 was deposed by the mixture of sulfate and nitric acid solution in the laboratory. Dumbbell-shaped concrete specimens were immersed in the simulated acid rain completely. After being exposed to the deposed mixture for a certain period, uniaxial tensile test was performed on the concrete specimens. The results indicate that elastic modulus, tensile strength, and peak strain have a slight increase at the initial corrosion stage, and with the extension of corrosion process, elastic modulus and tensile strength decrease gradually, while the peak strain still increases. It is found that the compressive strength is more sensitive than the tensile strength in aggressive environment. Based on the experimental results, an equation was proposed to describe the ascending branch of the stress-strain curve of the concrete corroded by acid rain.

  15. Auger electron spectroscopic study of mechanism of sulfide-accelerated corrosion of copper-nickel alloy in seawater

    Science.gov (United States)

    Schrader, Malcolm E.

    The mechanism of sulfide-induced accelerated corrosion of 90-10 copper-nickel(iron) alloy is investigated. Samples of the alloy are exposed to flowing (2.4 m/s) seawater, with and without 0 01 mg/l sulfide, for various periods of time. The resulting surfaces are examined by means of Auger electron spectroscopy coupled with inert-ion-homoardment. A detailed depth profile is thereby obtained of concentrations in the surface region of a total of nine elements. The results are consistent with the hypothesis that iron hydroxide segregates at the surface to form a protective gelatinous layer against the normal chloride-induced corrosion process. Trace sulfide interferes with formation of a good protective layer and leaves the iron hydroxide vulnerable to ultimate partial or complete debonding. When the alloy is first exposed to "pure" seawater for a prolonged period of time, however, subsequent exposure to sulfide is no longer deleterious. This is apparently due to a layer of copper-nickel salt that slowly forms over the iron hydroxide.

  16. Environmentally Assisted Cracking of Drill Pipes in Deep Drilling Oil and Natural Gas Wells

    Science.gov (United States)

    Ziomek-Moroz, M.

    2012-06-01

    Corrosion fatigue (CF), hydrogen induced cracking (HIC) and sulfide stress cracking (SSC), or environmentally assisted cracking (EAC) have been identified as the most challenging causes of catastrophic brittle fracture of drill pipes during drilling operations of deep oil and natural gas wells. Although corrosion rates can be low and tensile stresses during service can be below the material yield stress, a simultaneous action between the stress and corrosive environment can cause a sudden brittle failure of a drill component. Overall, EAC failure consists of two stages: incubation and propagation. Defects, such as pits, second-phase inclusions, etc., serve as preferential sites for the EAC failure during the incubation stage. Deep oil and gas well environments are rich in chlorides and dissolved hydrogen sulfide, which are extremely detrimental to steels used in drilling operations. This article discusses catastrophic brittle fracture mechanisms due to EAC of drill pipe materials, and the corrosion challenges that need to be overcome for drilling ultra-deep oil and natural gas wells.

  17. Mechanical properties and corrosion behavior of the nitriding surface layer of Ti−6Al−7Nb using large pulsed electron beam (LPEB)

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jisoo; Lee, Woo Jin; Park, Hyung Wook, E-mail: hwpark@unist.ac.kr

    2016-09-15

    Large pulsed electron beam (LPEB) irradiation was used as a single surface finishing process for Ti−Al−7Nb. Nitrogen plasma gas and cathodic apparatus have been adopted to induce nitriding effect of Ti−6Al−7Nb during the electron beam irradiation. The atomic concentration of nitrogen atoms at the re-solidified layer could be t5achieved up to ∼18% by LPEB nitriding. Nano-hardness in the re-solidified layer was improved by ∼75% following the irradiation process, as a result of a phase transformation and the formation of TiN. The re-solidified layer induced by the LPEB nitriding, consisted of TiN, TiO{sub 2}, and TiO{sub x}N{sub y}, indicated significantly modified corrosion resistance showing a nobler corrosion potential, decreased corrosion current density, and improved charge transfer resistance. The increasing fraction of TiN at the re-solidified layer, induced by LPEB nitriding, was suggested as being responsible for remarkable improvement of mechanical properties and corrosion resistance, embedding uniformly noble and stable characteristics at the top surface. The corrosion-resistant surface layer with superior mechanical properties on Ti−6Al−7Nb has been successfully demonstrated by LPEB nitriding technique. - Highlights: • The nitrogen plasma source facilitated the formation of TiN at the re-solidified layer induced by LPEB. • The negative DC bias increased TiN fraction at the re-solidified layer. • The passivation of re-solidified layer enhanced corrosion resistance of Ti−6Al−7Nb. • The formation of uniformly stable oxy-nitride layer increased corrosion resistance. • Large pulsed electron beam irradiation with N{sub 2} plasma source generated surface hardening.

  18. Caracterização e avaliação da resistência à corrosão na soldagem de tubulação de aço inoxidável duplex UNS S31803 pelo processo a arco submerso Characterization and evaluation of corrosion resistance of welded joint of duplex stainless steel pipe UNS S31803 by submerged arc process

    Directory of Open Access Journals (Sweden)

    Juan Manuel Pardal

    2011-12-01

    Full Text Available O presente trabalho apresenta os resultados da caracterização e avaliação da resistência à corrosão de uma junta soldada correspondente a uma tubulação de aço inoxidável duplex (AID UNS S31803 de 35 mm de espessura de parede soldada pelos processos de soldagem TIG (GTAW na raiz e arco submerso (SAW no enchimento e acabamento. Foram empregados como consumíveis de soldagem metais de adição de liga 25Cr-9Ni-4Mo (% em peso. Os resultados da caracterização das propriedades mecânicas, composição química e resistência à corrosão em diversas regiões da junta soldada foram comparados com os obtidos para o metal de base da tubulação, assim como com os valores mínimos exigidos pelas normas de projeto. Os resultados obtidos demonstram claramente a possibilidade da implementação do processo SAW na pré fabricação de tubulações de paredes espessas de AID, tendo em vista os resultados das propriedades analisadas e a grande demanda na construção e montagem de tubulações desta família de aço inoxidáveis na indústria offshore.This work presents the mechanical properties, microstructural and corrosion resistance evaluation of a welded joint of duplex stainless steel (DSS pipe with 35 mm wall thickness. The joint was welded by gas tungsten arc welding (GTAW process in the root passes and submerged arc welding (SAW in the filling and cap passes using filler metals with composition 25Cr-9Ni-4Mo (%wt.. The results of mechanical properties, chemical composition and corrosion resistance characterization in different regions of the welded joint were compared to the base metal and to the specifications required by the standards applied in the project. The main focus of this work was to show the successful utilization of SAW process in the welding of thick wall pipes of DSS. The application of high productivity process such as SAW has a crescent demand in offshore industry.

  19. Inhibition of Corrosion of Carbon Steel in 3.5% NaCl Solution by Myrmecodia Pendans Extract

    Directory of Open Access Journals (Sweden)

    Atria Pradityana

    2016-01-01

    Full Text Available Inhibitor is a substance that is added to the corrosive media to inhibit corrosion rate. Organic inhibitors are preferred to inorganic ones since they are environmentally friendly. One of the organic compounds which is rarely reported as a corrosion inhibitor is Myrmecodia Pendans. The organic compounds can be adsorbed on the metal surface and block the active surface to reduce the rate of corrosion. In this study, the used pipe was carbon steel API 5L Grade B with 3.5% NaCl solution as the corrosion medium. The objective of this research was to analyze the inhibition mechanism Myrmecodia Pendans towards carbon steel in a corrosion medium. Concentration variations of extract Myrmecodia Pendans were 0–500 ppm. Fourier Transform Infrared (FTIR was used for chemical characterization of Myrmecodia Pendans. Polarization and Electrochemical Impedance Spectroscopy (EIS were used to measure the corrosion rate and behaviour. From the electrochemical measurements, it was found that the addition of 400 mg/L inhibitor gave the highest inhibition efficiency. Myrmecodia Pendans acted as a corrosion inhibitor by forming a thin layer on the metal surface.

  20. Corrosion and Corrosion Control in Light Water Reactors

    Science.gov (United States)

    Gordon, Barry M.

    2013-08-01

    Serious corrosion problems have plagued the light water reactor (LWR) industry for decades. The complex corrosion mechanisms involved and the development of practical engineering solutions for their mitigation will be discussed in this article. After a brief overview of the basic designs of the boiling water reactor (BWR) and pressurized water reactor (PWR), emphasis will be placed on the general corrosion of LWR containments, flow-accelerated corrosion of carbon steel components, intergranular stress corrosion cracking (IGSCC) in BWRs, primary water stress corrosion cracking (PWSCC) in PWRs, and irradiation-assisted stress corrosion cracking (IASCC) in both systems. Finally, the corrosion future of both plants will be discussed as plants extend their period of operation for an additional 20 to 40 years.

  1. Custom titanium sleeve for surgical treatment of mechanically assisted crevice corrosion in the well-fixed, noncontemporary stem in total hip arthroplasty

    Directory of Open Access Journals (Sweden)

    Thomas Leibiger

    2015-12-01

    Full Text Available Adverse local tissue reaction associated with total hip replacement may occur when mechanically assisted crevice corrosion occurs at metal-metal modular junctions in which at least one of the components is fabricated from cobalt-chromium alloy. Complete removal of components may be associated with significant morbidity; when components are well fixed and in acceptable position, it may be appropriate to consider modular rather than complete revision. We have diagnosed mechanically assisted crevice corrosion in total hip arthroplasty patients with noncontemporary but well-fixed femoral components and found that modular conversion to a ceramic femoral head to remove a source of CoCr corrosion and fretting products was only possible by having a custom titanium sleeve manufactured. Surgical implantation with a revision style Biolox ceramic head (CeramTec, Plochingen, Germany was then achieved.

  2. Effect of WO3 nanoparticle loading on the microstructural, mechanical and corrosion resistance of Zn matrix/TiO2-WO3 nanocomposite coatings for marine application

    Science.gov (United States)

    Popoola, A. P. I.; Daniyan, A. A.; Umoru, L. E.; Fayomi, O. S. I.

    2017-03-01

    In this study, for marine application purposes, we evaluated the effect of process parameter and particle loading on the microstructure, mechanical reinforcement and corrosion resistance properties of a Zn-TiO2-WO3 nanocomposite produced via electrodeposition. We characterized the morphological properties of the composite coatings with a Scanning Electron Microscope (SEM) equipped with an Energy Dispersive Spectrometer (EDS). We carried out mechanical examination using a Dura Scan hardness tester and a CERT UMT-2 multi-functional tribological tester. We evaluated the corrosion properties by linear polarization in 3.5% NaCl. The results show that the coatings exhibited good stability and the quantitative particle loading greatly enhanced the structural and morphological properties, hardness behavior and corrosion resistance of the coatings. We observed the precipitation of this alloy on steel is greatly influenced by the composite characteristics.

  3. Degradation of titanium drillpipe from corrosion and wear

    Energy Technology Data Exchange (ETDEWEB)

    Ferg, T.E.; Aldrich, C.S. (Colorado School of Mines, Golden, CO (United States)); Craig, B.D. (Metallurgical Consultants Inc., Montebello (United States))

    1993-06-01

    Drilling deeper than 35,000 ft is limited by the extreme hook loads of steel drillpipe and temperature constraints of aluminum drillpipe. Titanium Alloys Ti-6Al-4V and Beta C have been proposed for use in drillpipe for wells deeper than 35,000 ft because of their high strength/weight ratios, superior high-temperature corrosion resistance, and thermal stability. Their suitability in drilling environments, however, has not been evaluated. To determine the corrosion and wear characteristics of two types of titanium-alloy drillpipe under dogleg conditions, a test cell was constructed to test titanium drillpipe joints in contact with API Spec. 5CT Grade P-110 casing in different drilling muds. Titanium-alloy pipe and Grade P-110 casing wear rates were measured, and tests showed that both titanium-alloy pipes exhibited much greater wear than did steel drillpipe in water-based mud under the same conditions. Test data showed that the total wear rate of Alloys Ti-6Al-4V and Beta C in a drilling environment is a combination of mechanical wear and corrosion.

  4. Corrosion resistance of Fe-based amorphous alloys

    Energy Technology Data Exchange (ETDEWEB)

    Botta, W.J., E-mail: wjbotta@ufscar.br [LEPMI, UMR5279 CNRS, Grenoble INP, Université de Savoie, Université Joseph Fourier, 1130, Rue de la piscine, BP 75, 38402 Saint Martin d’Hères (France); Departamento de Engenharia de Materiais, Universidade Federal de São Carlos, Rod. Washington Luiz, Km 235, 13565-905 São Carlos, SP (Brazil); Berger, J.E.; Kiminami, C.S. [Departamento de Engenharia de Materiais, Universidade Federal de São Carlos, Rod. Washington Luiz, Km 235, 13565-905 São Carlos, SP (Brazil); Roche, V.; Nogueira, R.P. [LEPMI, UMR5279 CNRS, Grenoble INP, Université de Savoie, Université Joseph Fourier, 1130, Rue de la piscine, BP 75, 38402 Saint Martin d’Hères (France); Bolfarini, C. [Departamento de Engenharia de Materiais, Universidade Federal de São Carlos, Rod. Washington Luiz, Km 235, 13565-905 São Carlos, SP (Brazil)

    2014-02-15

    Highlights: ► We report corrosion properties of Fe-based amorphous alloys in different media. ► The Cr-containing alloys had corrosion resistance close to that of Pt in all media. ► The wide range of electrochemical stability is relevant in many industrial domains. -- Abstract: Fe-based amorphous alloys can be designed to present an attractive combination of properties with high corrosion resistance and high mechanical strength. Such properties are clearly adequate for their technological use as coatings, for example, in steel pipes. In this work, we studied the corrosion properties of amorphous ribbons of the following Fe-based compositions: Fe{sub 66}B{sub 30}Nb{sub 4}, [(Fe{sub 0.6}Co{sub 0.4}){sub 0.75}B{sub 0.2}Si{sub 0.05}]{sub 96}Nb{sub 4}, [(Fe{sub 0.7}Co{sub 0.3}){sub 0.75}B{sub 0.2}Si{sub 0.05}]{sub 96}Nb{sub 4}, Fe{sub 56}Cr{sub 23}Ni{sub 5.7}B{sub 16}, Fe{sub 53}Cr{sub 22}Ni{sub 5.6}B{sub 19} and Fe{sub 50}Cr{sub 22}Ni{sub 5.4}B{sub 23}. The ribbons were obtained by rapid solidification using the melt-spinning process, and were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and optical (OM) and scanning electron microscopy (SEM). The corrosion properties were evaluated by corrosion potential survey and potentiodynamic polarization. The Cr containing alloys, that is the FeCrNiB type of alloys, showed the best corrosion resistance properties with the formation of a stable passive film that ensured a very large passivation plateau.

  5. Assessment of the integrity of welded pipes

    OpenAIRE

    Šarkoćević, Živče; Arsić, Miodrag; Sedmak, Aleksandar; MEĐO, Bojan; Mišić, Milan; id_orcid 0000-0003-0550-1851

    2014-01-01

    The subject of the paper is analysis of the integrity of welded pipes made of API J55 steel by high frequency contact welding (HF). Experimental research on the mechanical properties of the base material was conducted on pipes withdrawn from exploatation after 70 000 hours at service. Defect influence of the surface crack on the integrity of pipes was tested using hydrostatic pressure of pipes with axial surface crack in the base material. Fracture behaviour was tested using modified compact ...

  6. Some peculiarities of corrosion of wheel steel

    Directory of Open Access Journals (Sweden)

    Alexander SHRAMKO

    2009-01-01

    Full Text Available Corrosion mechanism and rate of different chemical composition and structural condition of wheel steel were investigated. It was shown that “white layers”, variation in grain size and banding of wheel steel structure results in corrosion rate. Microstructure of steel from different elements of railway wheels after operation with corrosion was investigated. Wheel steel with addition of vanadium corroded more quickly than steel without vanadium. Non-metallic inclusions are the centre of corrosion nucleation and their influence on corrosion depends on type of inclusion. Mechanism of corrosion of wheel steel corrosion was discussed.

  7. Design of core-pulling mechanism of injection mould for flaring pipe fitting%扩口类管件注射模抽芯机构设计

    Institute of Scientific and Technical Information of China (English)

    苏伟

    2014-01-01

    分析了扩口类管件结构及成型工艺,以ϕ75 mm扩口管件为例详细介绍了扩口管件注射模的结构,阐述了扩口管件模具抽芯机构、锁模机构以及定位机构等的设计,叙述了模具工作过程,可为扩口类模具设计提供思路。%The structure and forming process of a flaring pipe fitting was analyzed; and the structure and working process of an injection mould for a ϕ75 mm flaring pipe fitting were presented, in particular the flaring, core-pulling, mould clamping and positioning mech-anism.

  8. Corrosion behavior of corrosion resistant alloys in stimulation acids

    Energy Technology Data Exchange (ETDEWEB)

    Cheldi, Tiziana [ENI E and P Division, 20097 San Donato Milanese Milano (Italy); Piccolo, Eugenio Lo; Scoppio, Lucrezia [Centro Sviluppo Materiali, via Castel Romano 100, 00128 Rome (Italy)

    2004-07-01

    In the oil and gas industry, selection of CRAs for downhole tubulars is generally based on resistance to corrosive species in the production environment containing CO{sub 2}, H{sub 2}S, chloride and in some case elemental sulphur. However, there are non-production environments to which these materials must also be resistant for either short term or prolonged duration; these environments include stimulation acids, brine and completion fluids. This paper reports the main results of a laboratory study performed to evaluate the corrosion and stress <