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Sample records for partially resolved hyperfine

  1. New Nuclear Magnetic Moment of 209Bi: Resolving the Bismuth Hyperfine Puzzle

    Science.gov (United States)

    Skripnikov, Leonid V.; Schmidt, Stefan; Ullmann, Johannes; Geppert, Christopher; Kraus, Florian; Kresse, Benjamin; Nörtershäuser, Wilfried; Privalov, Alexei F.; Scheibe, Benjamin; Shabaev, Vladimir M.; Vogel, Michael; Volotka, Andrey V.

    2018-03-01

    A recent measurement of the hyperfine splitting in the ground state of Li-like 80+208Bi has established a "hyperfine puzzle"—the experimental result exhibits a 7 σ deviation from the theoretical prediction [J. Ullmann et al., Nat. Commun. 8, 15484 (2017), 10.1038/ncomms15484; J. P. Karr, Nat. Phys. 13, 533 (2017), 10.1038/nphys4159]. We provide evidence that the discrepancy is caused by an inaccurate value of the tabulated nuclear magnetic moment (μI) of 209Bi. We perform relativistic density functional theory and relativistic coupled cluster calculations of the shielding constant that should be used to extract the value of μI(209ipts>) and combine it with nuclear magnetic resonance measurements of Bi (NO3 )3 in nitric acid solutions and of the hexafluoridobismuthate(V) BiF6- ion in acetonitrile. The result clearly reveals that μI(209Bi) is much smaller than the tabulated value used previously. Applying the new magnetic moment shifts the theoretical prediction into agreement with experiment and resolves the hyperfine puzzle.

  2. New Nuclear Magnetic Moment of ^{209}Bi: Resolving the Bismuth Hyperfine Puzzle.

    Science.gov (United States)

    Skripnikov, Leonid V; Schmidt, Stefan; Ullmann, Johannes; Geppert, Christopher; Kraus, Florian; Kresse, Benjamin; Nörtershäuser, Wilfried; Privalov, Alexei F; Scheibe, Benjamin; Shabaev, Vladimir M; Vogel, Michael; Volotka, Andrey V

    2018-03-02

    A recent measurement of the hyperfine splitting in the ground state of Li-like ^{208}Bi^{80+} has established a "hyperfine puzzle"-the experimental result exhibits a 7σ deviation from the theoretical prediction [J. Ullmann et al., Nat. Commun. 8, 15484 (2017)NCAOBW2041-172310.1038/ncomms15484; J. P. Karr, Nat. Phys. 13, 533 (2017)NPAHAX1745-247310.1038/nphys4159]. We provide evidence that the discrepancy is caused by an inaccurate value of the tabulated nuclear magnetic moment (μ_{I}) of ^{209}Bi. We perform relativistic density functional theory and relativistic coupled cluster calculations of the shielding constant that should be used to extract the value of μ_{I}(^{209}Bi) and combine it with nuclear magnetic resonance measurements of Bi(NO_{3})_{3} in nitric acid solutions and of the hexafluoridobismuthate(V) BiF_{6}^{-} ion in acetonitrile. The result clearly reveals that μ_{I}(^{209}Bi) is much smaller than the tabulated value used previously. Applying the new magnetic moment shifts the theoretical prediction into agreement with experiment and resolves the hyperfine puzzle.

  3. Spectrally resolved hyperfine interactions between polaron and nuclear spins in organic light emitting diodes: Magneto-electroluminescence studies

    Energy Technology Data Exchange (ETDEWEB)

    Crooker, S. A.; Kelley, M. R.; Martinez, N. J. D.; Nie, W.; Mohite, A.; Nayyar, I. H.; Tretiak, S.; Smith, D. L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Liu, F.; Ruden, P. P. [University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2014-10-13

    We use spectrally resolved magneto-electroluminescence (EL) measurements to study the energy dependence of hyperfine interactions between polaron and nuclear spins in organic light-emitting diodes. Using layered devices that generate bright exciplex emission, we show that the increase in EL emission intensity I due to small applied magnetic fields of order 100 mT is markedly larger at the high-energy blue end of the EL spectrum (ΔI/I ∼ 11%) than at the low-energy red end (∼4%). Concurrently, the widths of the magneto-EL curves increase monotonically from blue to red, revealing an increasing hyperfine coupling between polarons and nuclei and directly providing insight into the energy-dependent spatial extent and localization of polarons.

  4. Hyperfine-resolved transition frequency list of fundamental vibration bands of H35Cl and H37Cl

    Science.gov (United States)

    Iwakuni, Kana; Sera, Hideyuki; Abe, Masashi; Sasada, Hiroyuki

    2014-12-01

    Sub-Doppler resolution spectroscopy of the fundamental vibration bands of H35Cl and H37Cl has been carried out from 87.1 to 89.9 THz. We have determined the absolute transition frequencies of the hyperfine-resolved R(0) to R(4) transitions with a typical uncertainty of 10 kHz. We have also yielded six molecular constants for each isotopomer in the vibrational excited state, which reproduce the determined frequencies with a standard deviation of about 10 kHz.

  5. Nuclear hyperfine structure of muonium in CuCl resolved by means of avoided level crossing

    International Nuclear Information System (INIS)

    Schneider, J.W.; Celio, M.; Keller, H.; Kuendig, W.; Odermatt, W.; Puempin, B.; Savic, I.M.; Simmler, H.; Estle, T.L.; Schwab, C.; Kiefl, R.F.; Renker, D.

    1990-01-01

    We report detailed avoided-level-crossing spectra of a muonium center (Mu II ) in single-crystal CuCl in a magnetic field range of 4--5 T and at a temperature of 100 K. The hyperfine parameters of the muon and the closest two shells of nuclei indicate that this center consists of muonium at a tetrahedral interstice with four Cu nearest neighbors and six Cl next-nearest neighbors and that the spin density is appreciable on the muon and on the ten neighboring nuclei but negligible elsewhere

  6. Resolved nuclear hyperfine structure of muonium in CuCl by means of muon level-crossing resonance

    International Nuclear Information System (INIS)

    Schneider, J.W.; Keller, H.; Odermatt, W.; Puempin, B.; Savic, I.M.; Simmler, H.; Dodds, S.A.; Estle, T.L.; Duvarney, R.C.; Chow, K.; Kadono, R.; Kiefl, R.F.; Li, Q.; Riseman, T.M.; Zhou, H.; Lichti, R.L.; Schwab, C.

    1991-01-01

    Detailed muon level-crossing resonance measurements of Mu I and Mu II centres in single crystals of CuCl are presented. The hyperfine and nuclear hyperfine parameters of the closest two shells of nuclei are remarkably similar for the two centres, indicating that both are located at the same tetrahedral interstitial site with four Cu nearest neighbours and six Cl next-nearest neighbours. About 30% of the total unpaired-electron spin density is located on the muon, about 60% on the four nearest neighbours and the rest on the six next-nearest neighbours, with nothing observable for any other shell. (orig.)

  7. Spatially resolved Raman spectroscopy study of transformed zones in magnesia-partially-stabilized zirconia

    International Nuclear Information System (INIS)

    Davskardt, R.H.; Veirs, D.K.; Ritchie, R.O.

    1989-01-01

    Raman vibrational spectroscopy provides an effective phase characterization technique in materials systems containing particle dispersions of the tetragonal and monoclinic polymorphs of zirconia, each of which yields a unique Raman spectrum. An investigation is reported to assess a novel, spatially resolved Raman spectroscopy system in the study of transformed zones surrounding cracks in partially stabilized MgO-ZrO 2 (PSZ). The experimental arrangement uses an imaging (two-dimensional) photomultiplier tube to produce a one-dimensional Raman profile of phase compositions along a slitlike laser beam without translation of either the sample or the laser beam and without scanning the spectrometer. Results from phase characterization studies of the size, frontal morphology, and extent of transformation of transformation zones surrounding cracks produced under monotonic and cyclic loading conditions are presented

  8. Correlation functions for fully or partially state-resolved reactive scattering calculations

    International Nuclear Information System (INIS)

    Manthe, Uwe; Welsch, Ralph

    2014-01-01

    Flux correlation functions and the quantum transition state concept are important tools for the accurate description of polyatomic reaction processes. Combined with the multi-configurational time-dependent Hartree approach, they facilitate rigorous full-dimensional calculations of cumulative and initial-state selected reaction probabilities for six atom reactions. In recent work [R. Welsch, F. Huarte-Larrañaga, and U. Manthe, J. Chem. Phys. 136, 064117 (2012)], an approach which allows one to calculate also state-to-state reaction probabilities within the quantum transition state concept has been introduced. This article presents further developments. Alternative generalized flux correlation functions are introduced and discussed. Equations for the calculation of fully state-resolved differential cross section using arbitrary definitions of the body fixed frame are derived. An approach for the efficient calculation of partially state-resolved observables as a function of the collision energy is introduced. Finally, numerical test studying the D + H 2 reaction illustrate important aspects of the formalism

  9. Resolving intramolecular-distortion changes induced by the partial fluorination of pentacene adsorbed on Cu(111)

    Science.gov (United States)

    Franco-Cañellas, Antoni; Wang, Qi; Broch, Katharina; Shen, Bin; Gerlach, Alexander; Bettinger, Holger F.; Duhm, Steffen; Schreiber, Frank

    2018-04-01

    We experimentally quantify the molecular bending of a partially fluorinated pentacene (PEN) compound, namely 2,3,9,10-tetrafluoropentacene (F4PEN), adsorbed on Cu(111). By means of the x-ray standing wave (XSW) technique, we directly measure the adsorption distance of three inequivalent carbon sites, the fluorine atoms as well as the total and backbone carbon average adsorption distances. The precise positioning of different sites within the carbon core allows us to resolve two adsorption behaviors, namely a PEN-like strong coupling between the backbone and the substrate, and a repulsive interaction involving the fluorinated short molecular edges, which are 0.91 ±0.09 Å above the central benzene ring. This finding is further supported by additional electronic and in-plane-structure measurements, thus showing that the selective fluorination of a PEN molecule has only a local conformational effect and it is not sufficient to modify its interface properties. Yet, in the multilayer regime, the electronic and growth properties of the film differ completely from those of PEN and its perfluorinated derivative.

  10. Measurement of the ground-state hyperfine splitting of antihydrogen

    CERN Document Server

    Juhász, B; Federmann, S

    2011-01-01

    The ASACUSA collaboration at the Antiproton Decelerator of CERN is planning to measure the ground-state hyperfine splitting of antihydrogen using an atomic beam line, consisting of a cusp trap as a source of partially polarized antihydrogen atoms, a radiofrequency spin-flip cavity, a superconducting sextupole magnet as spin analyser, and an antihydrogen detector. This will be a measurement of the antiproton magnetic moment, and also a test of the CPT invariance. Monte Carlo simulations predict that the antihydrogen ground-state hyperfine splitting can be determined with a relative precision of ~10−7. The first preliminary measurements of the hyperfine transitions will start in 2011.

  11. Hyperfine excitation of OH+ by H

    Science.gov (United States)

    Lique, François; Bulut, Niyazi; Roncero, Octavio

    2016-10-01

    The OH+ ions are widespread in the interstellar medium and play an important role in the interstellar chemistry as they act as precursors to the H2O molecule. Accurate determination of their abundance rely on their collisional rate coefficients with atomic hydrogen and electrons. In this paper, we derive OH+-H fine and hyperfine-resolved rate coefficients by extrapolating recent quantum wave packet calculations for the OH+ + H collisions, including inelastic and exchange processes. The extrapolation method used is based on the infinite order sudden approach. State-to-state rate coefficients between the first 22 fine levels and 43 hyperfine levels of OH+ were obtained for temperatures ranging from 10 to 1000 K. Fine structure-resolved rate coefficients present a strong propensity rule in favour of Δj = ΔN transitions. The Δj = ΔF propensity rule is observed for the hyperfine transitions. The new rate coefficients will help significantly in the interpretation of OH+ spectra from photon-dominated region (PDR), and enable the OH+ molecule to become a powerful astrophysical tool for studying the oxygen chemistry.

  12. Spin-torsion effects in the hyperfine structure of methanol

    International Nuclear Information System (INIS)

    Coudert, L. H.; Gutlé, C.; Huet, T. R.; Grabow, J.-U.; Levshakov, S. A.

    2015-01-01

    The magnetic hyperfine structure of the non-rigid methanol molecule is investigated experimentally and theoretically. 12 hyperfine patterns are recorded using molecular beam microwave spectrometers. These patterns, along with previously recorded ones, are analyzed in an attempt to evidence the effects of the magnetic spin-torsion coupling due to the large amplitude internal rotation of the methyl group [J. E. M. Heuvel and A. Dymanus, J. Mol. Spectrosc. 47, 363 (1973)]. The theoretical approach setup to analyze the observed data accounts for this spin-torsion in addition to the familiar magnetic spin-rotation and spin-spin interactions. The theoretical approach relies on symmetry considerations to build a hyperfine coupling Hamiltonian and spin-rotation-torsion wavefunctions compatible with the Pauli exclusion principle. Although all experimental hyperfine patterns are not fully resolved, the line position analysis yields values for several parameters including one describing the spin-torsion coupling

  13. Fine- and hyperfine-structure effects in molecular photoionization. I. General theory and direct photoionization

    Energy Technology Data Exchange (ETDEWEB)

    Germann, Matthias; Willitsch, Stefan, E-mail: stefan.willitsch@unibas.ch [Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel (Switzerland)

    2016-07-28

    We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra, we derive highly symmetrized forms of the squared photoionization dipole matrix elements from which we derive the salient selection and propensity rules for fine- and hyperfine resolved photoionizing transitions. Our theoretical results are validated by the analysis of the fine-structure resolved photoelectron spectrum of O{sub 2} reported by Palm and Merkt [Phys. Rev. Lett. 81, 1385 (1998)] and are used for predicting hyperfine populations of molecular ions produced by photoionization.

  14. Fine- and hyperfine-structure effects in molecular photoionization. I. General theory and direct photoionization.

    Science.gov (United States)

    Germann, Matthias; Willitsch, Stefan

    2016-07-28

    We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra, we derive highly symmetrized forms of the squared photoionization dipole matrix elements from which we derive the salient selection and propensity rules for fine- and hyperfine resolved photoionizing transitions. Our theoretical results are validated by the analysis of the fine-structure resolved photoelectron spectrum of O2 reported by Palm and Merkt [Phys. Rev. Lett. 81, 1385 (1998)] and are used for predicting hyperfine populations of molecular ions produced by photoionization.

  15. Theoretical and experimental investigation of atomic radiative lifetimes and hyperfine structures

    International Nuclear Information System (INIS)

    Joensson, Per.

    1992-01-01

    Atomic radiative lifetimes and hyperfine structures as well as other properties, such as total energy and specific mass shift, have been studied theoretically and experimentally. Computer programs to calculate hyperfine structure constants from non-relativistic multiconfiguration Hartree-Fock (MCHF) and relativistic multi-configuration Dirac-Fock (MCDF) wavefunctions have been written. Using these programs large-scale calculations of hyperfine structures in lithium and sodium have been performed. It is shown, that the MCHF method is able to predict hyperfine structures to an accuracy of a few per mille in lithium, whereas for the more complex hyperfine structures to an accuracy of a few per mille in lithium, whereas for the more complex sodium atom an accuracy of a few per cent is obtainable. For lithium convergence of the total energy, ionization energy, specific mass shift and hyperfine parameters has been studied with the MCHF method. Radiative lifetimes and hyperfine structures of excited states in sodium and silver have been experimentally determined using time-resolved laser spectroscopy. By recording the fluorescence light decay curves following VUV excitation, the radiative lifetimes and hyperfine structures of the 7p 2 P states in silver were measured. The delayed-coincidence technique has been used to make very accurate measurements of the radiative lifetimes and hyperfine structures of the lowest P states in sodium and silver

  16. Fluctuating hyperfine interactions: computational implementation

    International Nuclear Information System (INIS)

    Zacate, M. O.; Evenson, W. E.

    2010-01-01

    A library of computational routines has been created to assist in the analysis of stochastic models of hyperfine interactions. We call this library the stochastic hyperfine interactions modeling library (SHIML). It provides routines written in the C programming language that (1) read a text description of a model for fluctuating hyperfine fields, (2) set up the Blume matrix, upon which the evolution operator of the system depends, and (3) find the eigenvalues and eigenvectors of the Blume matrix so that theoretical spectra of experimental hyperfine interaction measurements can be calculated. Example model calculations are included in the SHIML package to illustrate its use and to generate perturbed angular correlation spectra for the special case of polycrystalline samples when anisotropy terms of higher order than A 22 can be neglected.

  17. THE PANCHROMATIC HUBBLE ANDROMEDA TREASURY. III. MEASURING AGES AND MASSES OF PARTIALLY RESOLVED STELLAR CLUSTERS

    Energy Technology Data Exchange (ETDEWEB)

    Beerman, Lori C.; Johnson, L. Clifton; Fouesneau, Morgan; Dalcanton, Julianne J.; Weisz, Daniel R.; Williams, Ben F. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Seth, Anil C. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Bell, Eric F. [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Bianchi, Luciana C. [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Caldwell, Nelson [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Dolphin, Andrew E. [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Gouliermis, Dimitrios A. [Zentrum fuer Astronomie, Institut fuer Theoretische Astrophysik, Universitaet Heidelberg, Albert-Ueberle-Strasse 2, D-69120 Heidelberg (Germany); Kalirai, Jason S. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Larsen, Soren S. [Department of Astrophysics, IMAPP, Radboud University Nijmegen, P.O. Box 9010, NL-6500 GL Nijmegen (Netherlands); Melbourne, Jason L. [Caltech Optical Observatories, Division of Physics, Mathematics and Astronomy, Mail Stop 301-17, California Institute of Technology, Pasadena, CA 91125 (United States); Rix, Hans-Walter [Max-Planck-Institut fuer Astronomie, Koenigstuhl 17, D-69117 Heidelberg (Germany); Skillman, Evan D., E-mail: beermalc@astro.washington.edu [Department of Astronomy, University of Minnesota, 116 Church Street SE, Minneapolis, MN 55455 (United States)

    2012-12-01

    The apparent age and mass of a stellar cluster can be strongly affected by stochastic sampling of the stellar initial mass function (IMF), when inferred from the integrated color of low-mass clusters ({approx}<10{sup 4} M {sub Sun }). We use simulated star clusters to show that these effects are minimized when the brightest, rapidly evolving stars in a cluster can be resolved, and the light of the fainter, more numerous unresolved stars can be analyzed separately. When comparing the light from the less luminous cluster members to models of unresolved light, more accurate age estimates can be obtained than when analyzing the integrated light from the entire cluster under the assumption that the IMF is fully populated. We show the success of this technique first using simulated clusters, and then with a stellar cluster in M31. This method represents one way of accounting for the discrete, stochastic sampling of the stellar IMF in less massive clusters and can be leveraged in studies of clusters throughout the Local Group and other nearby galaxies.

  18. Stochastic hyperfine interactions modeling library

    Science.gov (United States)

    Zacate, Matthew O.; Evenson, William E.

    2011-04-01

    The stochastic hyperfine interactions modeling library (SHIML) provides a set of routines to assist in the development and application of stochastic models of hyperfine interactions. The library provides routines written in the C programming language that (1) read a text description of a model for fluctuating hyperfine fields, (2) set up the Blume matrix, upon which the evolution operator of the system depends, and (3) find the eigenvalues and eigenvectors of the Blume matrix so that theoretical spectra of experimental techniques that measure hyperfine interactions can be calculated. The optimized vector and matrix operations of the BLAS and LAPACK libraries are utilized; however, there was a need to develop supplementary code to find an orthonormal set of (left and right) eigenvectors of complex, non-Hermitian matrices. In addition, example code is provided to illustrate the use of SHIML to generate perturbed angular correlation spectra for the special case of polycrystalline samples when anisotropy terms of higher order than A can be neglected. Program summaryProgram title: SHIML Catalogue identifier: AEIF_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEIF_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: GNU GPL 3 No. of lines in distributed program, including test data, etc.: 8224 No. of bytes in distributed program, including test data, etc.: 312 348 Distribution format: tar.gz Programming language: C Computer: Any Operating system: LINUX, OS X RAM: Varies Classification: 7.4 External routines: TAPP [1], BLAS [2], a C-interface to BLAS [3], and LAPACK [4] Nature of problem: In condensed matter systems, hyperfine methods such as nuclear magnetic resonance (NMR), Mössbauer effect (ME), muon spin rotation (μSR), and perturbed angular correlation spectroscopy (PAC) measure electronic and magnetic structure within Angstroms of nuclear probes through the hyperfine interaction. When

  19. Non-contact measurement of partial gas pressure and distribution of elemental composition using energy-resolved neutron imaging

    Directory of Open Access Journals (Sweden)

    A. S. Tremsin

    2017-01-01

    Full Text Available Neutron resonance absorption imaging is a non-destructive technique that can characterize the elemental composition of a sample by measuring nuclear resonances in the spectrum of a transmitted beam. Recent developments in pixelated time-of-flight imaging detectors coupled with pulsed neutron sources pose new opportunities for energy-resolved imaging. In this paper we demonstrate non-contact measurements of the partial pressure of xenon and krypton gases encapsulated in a steel pipe while simultaneously passing the neutron beam through high-Z materials. The configuration was chosen as a proof of principle demonstration of the potential to make non-destructive measurement of gas composition in nuclear fuel rods. The pressure measured from neutron transmission spectra (∼739 ± 98 kPa and ∼751 ± 154 kPa for two Xe resonances is in relatively good agreement with the pressure value of ∼758 ± 21 kPa measured by a pressure gauge. This type of imaging has been performed previously for solids with a spatial resolution of ∼ 100 μm. In the present study it is demonstrated that the high penetration capability of epithermal neutrons enables quantitative mapping of gases encapsulate within high-Z materials such as steel, tungsten, urania and others. This technique may be beneficial for the non-destructive testing of bulk composition of objects (such as spent nuclear fuel assemblies and others containing various elements opaque to other more conventional imaging techniques. The ability to image the gaseous substances concealed within solid materials also allows non-destructive leak testing of various containers and ultimately measurement of gas partial pressures with sub-mm spatial resolution.

  20. Hyperfine interactions by Moessbauer effect

    International Nuclear Information System (INIS)

    Constantinescu, S.

    1980-01-01

    Moessbauer spectroscopy has been used to investigate hyperfine interactions in materials endowed with complex electromagnetic crystallographic structures. Such structures (Me 3 B 7 O 13 X boracite-type systems, for instance), equally interesting from both scientific and applications viewpoint, are drawing a special attention lately on account of their being examined by means of increasingly refined experimental techniques. In view of the wide prospects of using these materials in various practical fields, this thesis counts among the studies aiming to ameliorate the methods of processing and determining the Moessbauer spectra parameters, characterized by complex hyperfine interactions, as well as among the studies of electric, magnetic and crystallographic investigation of the Moessbauer nucleus neighbourhood, in boracite-type structures. (author)

  1. Calculation of magnetic hyperfine constants

    International Nuclear Information System (INIS)

    Bufaical, R.F.; Maffeo, B.; Brandi, H.S.

    1975-01-01

    The magnetic hyperfine constants of the V sub(K) center in CaF 2 , SrF 2 and BaF 2 have been calculated assuming a phenomenological model, based on the F 2 - 'central molucule', to describe the wavefunction of the defect. Calculations have shown that introduction of a small degree of covalence, between this central molecule and neighboring ions, is necessary to improve the electronic structure description of the defect. It was also shown that the results for the hyperfine constants are strongly dependent on the relaxations of the ions neighboring the central molecule; these relaxations have been determined by fitting the experimental data. The present results are compared with other previous calculations where similar and different theoretical methods have been used

  2. Hyperfine magnetic fields in substituted Finemet alloys

    Energy Technology Data Exchange (ETDEWEB)

    Brzózka, K., E-mail: k.brzozka@uthrad.pl [University of Technology and Humanities in Radom, Department of Physics (Poland); Sovák, P. [P.J. Šafárik University, Institute of Physics (Slovakia); Szumiata, T.; Gawroński, M.; Górka, B. [University of Technology and Humanities in Radom, Department of Physics (Poland)

    2016-12-15

    Transmission Mössbauer spectroscopy was used to determine the hyperfine fields of Finemet-type alloys in form of ribbons, substituted alternatively by Mn, Ni, Co, Al, Zn, V or Ge of various concentration. The comparative analysis of magnetic hyperfine fields was carried out which enabled to understand the role of added elements in as-quenched as well as annealed samples. Moreover, the influence of the substitution on the mean direction of the local hyperfine magnetic field was examined.

  3. The hyperfine structure - a message from the inner circle

    International Nuclear Information System (INIS)

    Sturesson, L.

    1992-06-01

    Experiment have been performed to determine the lifetimes and the hyperfine structures of excited states in atoms. Decay curves were recorded with the aid of time-resolved laser spectroscopy. From these curves, it was possible to evaluated the lifetimes with high accuracy. In certain cases, the hyperfine structures were also determined with high accuracy form quantum beat signals. The elements studied were lithium, sodium, copper, iron and silver. In favourable cases, the method of delayed coincidence gave uncertainties in lifetime measurements of about 0.5%. The detection of quantum beat signals with frequencies higher than 1 GHz was demonstrated. The effects of non-white excitation and delayed detection on level-crossing signals were also investigated. The method of delayed detection causes a narrowing of the detected signal, though most of the intensity of the signals is lost and it exhibits an oscillatory behaviour due to the gating procedure. The effect of high-intensity beams in combination with optically dense media applied to saturation absorption spectroscopy has been investigated both theoretically and experimentally. In this regime the signals exhibited sharp profiles, with widths narrower than the natural linewidth, duel to the non-linearity of the medium. Also, a strong rejection of the background was achieved. These features make this regime interesting for frequency stabilization purpose. Using wavefunctions calculated with the multi-configuration Hartree-Fock method, the hyperfine structure interaction constants of the 3s 2 S and the 3p 2 P states in 23 Na and the 3s3p 1.3 P and the 3s3d 1.3 D states in 25 Mg, the only stable isotope of magnesium with a hyperfine structure, were determined. (62 refs.) (au)

  4. Absolute configuration and enantiomeric composition of partially resolved mandelic, atrolactic and lactic acids by {sup 1}H NMR of their (S)-2-methylbutyl esters

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Francisco A. da C.; Mendes, Maricleide P. de L.; Fonseca, Neuracy C. da, E-mail: fandrade@ufba.br [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Instituto de Quimica. Departamento de Quimica Organica

    2013-06-15

    The mandelic, atrolactic and lactic acid esters of the (S)-2-methyl-1-butanol were examined as diastereomeric derivatives for the stereochemical analysis of the mentioned acids by {sup 1}H nuclear magnetic resonance (NMR) at 300 MHz. The diastereomeric esters showed distinctive signals in the methylenic absorption range (O-CH{sub 2}-CH) of the alcoholic moieties. By spectral analysis at this region, absolute configurations were attributed, chemical shifts of the correspondent pro-(R) and pro-(S) hydrogens from the methylene group of the alcohol moiety were assigned and enantiomeric compositions were determined for the original partially resolved acids. (author)

  5. Unexpected lines due to hyperfine interaction

    International Nuclear Information System (INIS)

    Andersson, Martin

    2009-01-01

    Hyperfine interaction is often viewed as a small perturbation that only broadens or in some cases splits a line into many closely spaced lines. In this work, we present some cases where this picture is obsolete and where the hyperfine interaction makes drastic changes to spectra. Off-diagonal hyperfine interaction introduces a mixing between states which can differ in the J quantum number. In most cases this mixing is very small, but even so it could have a dramatic influence on the spectra. Some metastable levels are sensitive to the hyperfine interaction and we show this by presenting the results for hyperfine-dependent lifetimes of the 3d 9 4s 3 D 3 level along parts of the higher end of the Ni-like iso-electronic sequence. In the absence of a nuclear spin, this level can only decay through a magnetic-octupole transition, but in the presence of a nuclear spin, the off-diagonal hyperfine interaction introduces a mixing with the 3d 9 4s 3 D 2 level and a new electric-quadrupole transition channel is opened. It is shown that this new transition channel in many cases is the dominant one and that the lifetime of the 3 D 3 level is sensitive to hyperfine interaction all along the sequence. An example of other types of states that are sensitive to hyperfine interaction are those belonging to configurations of the type nsn'l' where l≥3. In such systems the levels are close in energy and the open s-shell gives rise to a strong hyperfine interaction. This in turn introduces a large mixing between the hyperfine levels and shows up in the spectra as a large intensity redistribution among the hyperfine lines. We present detailed results for the 4s4d 3 D 2 -4s4f 3 F 2 transitions in Ga ii, and show that by including the hyperfine interaction in a proper way, we could reproduce experimental spectra that had not been possible earlier.

  6. Quark color-hyperfine interactions in baryons

    International Nuclear Information System (INIS)

    Anselmino, M.; Lichtenberg, D.B.

    1990-01-01

    We consider the contribution from the color-hyperfine interaction to the energies of groundstate hadrons, with an emphasis on baryons. We use experimental information about how the color-hyperfine term depends on flavor to make predictions about the masses of baryons containing a heavy quark. We then generalize some relations between color-hyperfine matrix elements in mesons and baryons to obtain a number of additional predictions about the masses of as-yet unobserved baryons. Most of our predictions are in the form of inequalities. (orig.)

  7. View-sharing in keyhole imaging: Partially compressed central k-space acquisition in time-resolved MRA at 3.0 T

    Energy Technology Data Exchange (ETDEWEB)

    Hadizadeh, Dariusch R., E-mail: Dariusch.Hadizadeh@ukb.uni-bonn.de [University of Bonn, Department of Radiology, Sigmund-Freud-Strasse 25, 53127 Bonn (Germany); Gieseke, Juergen [University of Bonn, Department of Radiology, Sigmund-Freud-Strasse 25, 53127 Bonn (Germany); Philips Healthcare, Best (Netherlands); Beck, Gabriele; Geerts, Liesbeth [Philips Healthcare, Best (Netherlands); Kukuk, Guido M. [University of Bonn, Department of Radiology, Sigmund-Freud-Strasse 25, 53127 Bonn (Germany); Bostroem, Azize [Department of Neurosurgery, Sigmund-Freud-Strasse 25, 53127 Bonn, Deutschland (Germany); Urbach, Horst; Schild, Hans H.; Willinek, Winfried A. [University of Bonn, Department of Radiology, Sigmund-Freud-Strasse 25, 53127 Bonn (Germany)

    2011-11-15

    Introduction: Time-resolved contrast-enhanced magnetic resonance (MR) angiography (CEMRA) of the intracranial vasculature has proved its clinical value for the evaluation of cerebral vascular disease in cases where both flow hemodynamics and morphology are important. The purpose of this study was to evaluate a combination of view-sharing with keyhole imaging to increase spatial and temporal resolution of time-resolved CEMRA at 3.0 T. Methods: Alternating view-sharing was combined with randomly segmented k-space ordering, keyhole imaging, partial Fourier and parallel imaging (4DkvsMRA). 4DkvsMRA was evaluated using varying compression factors (80-100) resulting in spatial resolutions ranging from (1.1 x 1.1 x 1.4) to (0.96 x 0.96 x 0.95) mm{sup 3} and temporal resolutions ranging from 586 ms/dynamic scan - 288 ms/dynamic scan in three protocols in 10 healthy volunteers and seven patients (17 subjects). DSA correlation was available in four patients with cerebral arteriovenous malformations (cAVMs) and one patient with cerebral teleangiectasia. Results: 4DkvsMRA was successfully performed in all subjects and showed clear depiction of arterial and venous phases with diagnostic image quality. At the maximum view-sharing compression factor (=100), a 'flickering' artefact was observed. Conclusion: View-sharing in keyhole imaging allows for increased spatial and temporal resolution in time-resolved MRA.

  8. View-sharing in keyhole imaging: Partially compressed central k-space acquisition in time-resolved MRA at 3.0 T

    International Nuclear Information System (INIS)

    Hadizadeh, Dariusch R.; Gieseke, Juergen; Beck, Gabriele; Geerts, Liesbeth; Kukuk, Guido M.; Bostroem, Azize; Urbach, Horst; Schild, Hans H.; Willinek, Winfried A.

    2011-01-01

    Introduction: Time-resolved contrast-enhanced magnetic resonance (MR) angiography (CEMRA) of the intracranial vasculature has proved its clinical value for the evaluation of cerebral vascular disease in cases where both flow hemodynamics and morphology are important. The purpose of this study was to evaluate a combination of view-sharing with keyhole imaging to increase spatial and temporal resolution of time-resolved CEMRA at 3.0 T. Methods: Alternating view-sharing was combined with randomly segmented k-space ordering, keyhole imaging, partial Fourier and parallel imaging (4DkvsMRA). 4DkvsMRA was evaluated using varying compression factors (80-100) resulting in spatial resolutions ranging from (1.1 x 1.1 x 1.4) to (0.96 x 0.96 x 0.95) mm 3 and temporal resolutions ranging from 586 ms/dynamic scan - 288 ms/dynamic scan in three protocols in 10 healthy volunteers and seven patients (17 subjects). DSA correlation was available in four patients with cerebral arteriovenous malformations (cAVMs) and one patient with cerebral teleangiectasia. Results: 4DkvsMRA was successfully performed in all subjects and showed clear depiction of arterial and venous phases with diagnostic image quality. At the maximum view-sharing compression factor (=100), a 'flickering' artefact was observed. Conclusion: View-sharing in keyhole imaging allows for increased spatial and temporal resolution in time-resolved MRA.

  9. Hyperfine structure of ScI by infrared Fourier transform spectroscopy

    International Nuclear Information System (INIS)

    Aboussaid, A.; Carleer, M.; Hurtmans, D.; Biemont, E.; Godefroid, M.R.

    1996-01-01

    The spectrum of scandium was recorded in the infrared region using a high resolution Fourier transform spectrometer and a hollow-cathode discharge. Hyperfine structures of the lines connecting the 3d 2 4s and 3d4s4p level systems of Sc 45 I were observed between 4000 and 5000 cm -1 . The structures were not completely resolved but the individual line contributions to the complex profiles were simulated using the 3d 2 4s 4 F J hyperfine structure constants previously measured with a high precision by laser techniques. We investigate the possibility of extracting the hyperfine constants of the 3d4s4p levels from a least-squares fit of the line profiles, assuming a Doppler lineshape and theoretical relative intensities. New results are presented for 12 levels. (orig.)

  10. Numerical Simulations of Hyperfine Transitions of Antihydrogen

    CERN Document Server

    Kolbinger, B.; Diermaier, M.; Lehner, S.; Malbrunot, C.; Massiczek, O.; Sauerzopf, C.; Simon, M.C.; Widmann, E.

    2015-02-04

    One of the ASACUSA (Atomic Spectroscopy And Collisions Using Slow Antiprotons) collaboration's goals is the measurement of the ground state hyperfine transition frequency in antihydrogen, the antimatter counterpart of one of the best known systems in physics. This high precision experiment yields a sensitive test of the fundamental symmetry of CPT. Numerical simulations of hyperfine transitions of antihydrogen atoms have been performed providing information on the required antihydrogen events and the achievable precision.

  11. Numerical simulations of hyperfine transitions of antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Kolbinger, B., E-mail: bernadette.kolbinger@oeaw.ac.at; Capon, A.; Diermaier, M.; Lehner, S. [Stefan Meyer Institute for Subatomic Physics, Austrian Academy of Sciences (Austria); Malbrunot, C. [CERN (Switzerland); Massiczek, O.; Sauerzopf, C.; Simon, M. C.; Widmann, E. [Stefan Meyer Institute for Subatomic Physics, Austrian Academy of Sciences (Austria)

    2015-08-15

    One of the ASACUSA (Atomic Spectroscopy And Collisions Using Slow Antiprotons) collaboration’s goals is the measurement of the ground state hyperfine transition frequency in antihydrogen, the antimatter counterpart of one of the best known systems in physics. This high precision experiment yields a sensitive test of the fundamental symmetry of CPT. Numerical simulations of hyperfine transitions of antihydrogen atoms have been performed providing information on the required antihydrogen events and the achievable precision.

  12. Towards the measurement of the ground-state hyperfine splitting of antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Juhasz, Bertalan, E-mail: bertalan.juhasz@oeaw.ac.at [Austrian Academy of Sciences, Stefan Meyer Institute for Subatomic Physics (Austria)

    2012-12-15

    The ASACUSA collaboration at the Antiproton Decelerator of CERN is planning to measure the ground-state hyperfine splitting of antihydrogen using an atomic beam line, which will consist of a superconducting cusp trap as a source of partially polarized antihydrogen atoms, a radiofrequency spin-flip cavity, a superconducting sextupole magnet as spin analyser, and an antihydrogen detector. This will be a measurement of the antiproton magnetic moment, and also a test of the CPT invariance. Monte Carlo simulations predict that the antihydrogen ground-state hyperfine splitting can be determined with a relative precision of better than {approx} 10{sup - 6}. The first preliminary measurements of the hyperfine transitions will start in 2011.

  13. Influence of hydrostatic pressure on dynamics and spatial distribution of protein partial molar volume: time-resolved surficial Kirkwood-Buff approach.

    Science.gov (United States)

    Yu, Isseki; Tasaki, Tomohiro; Nakada, Kyoko; Nagaoka, Masataka

    2010-09-30

    The influence of hydrostatic pressure on the partial molar volume (PMV) of the protein apomyoglobin (AMb) was investigated by all-atom molecular dynamics (MD) simulations. Using the time-resolved Kirkwood-Buff (KB) approach, the dynamic behavior of the PMV was identified. The simulated time average value of the PMV and its reduction by 3000 bar pressurization correlated with experimental data. In addition, with the aid of the surficial KB integral method, we obtained the spatial distributions of the components of PMV to elucidate the detailed mechanism of the PMV reduction. New R-dependent PMV profiles identified the regions that increase or decrease the PMV under the high pressure condition. The results indicate that besides the hydration in the vicinity of the protein surface, the outer space of the first hydration layer also significantly influences the total PMV change. These results provide a direct and detailed picture of pressure induced PMV reduction.

  14. Spin relaxation in nanowires by hyperfine coupling

    International Nuclear Information System (INIS)

    Echeverria-Arrondo, C.; Sherman, E.Ya.

    2012-01-01

    Hyperfine interactions establish limits on spin dynamics and relaxation rates in ensembles of semiconductor quantum dots. It is the confinement of electrons which determines nonzero hyperfine coupling and leads to the spin relaxation. As a result, in nanowires one would expect the vanishing of this effect due to extended electron states. However, even for relatively clean wires, disorder plays a crucial role and makes electron localization sufficient to cause spin relaxation on the time scale of the order of 10 ns. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. The hyperfine spectrum of hydrogen dimers

    International Nuclear Information System (INIS)

    Verberne, J.F.C.

    1979-01-01

    The authors' aim was to obtain the level scheme for the hydrogen dimers and to investigate the angle dependent interactions by analyzing the zero magnetic field hyperfine spectrum of the ortho-ortho and ortho-para species. The results were tested by several recent semi-empirical and ab initio potentials. (Auth.)

  16. Hyperfine splitting in ordinary and muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Tomalak, Oleksandr [Johannes Gutenberg Universitaet, Institut fuer Kernphysik and PRISMA Cluster of Excellence, Mainz (Germany)

    2018-01-15

    We provide an accurate evaluation of the two-photon exchange correction to the hyperfine splitting of S energy levels in muonic hydrogen exploiting the corresponding measurements in electronic hydrogen. The proton structure uncertainty in the calculation of α{sup 5} contribution is sizably reduced. (orig.)

  17. EFFECTIVE HYPERFINE-STRUCTURE FUNCTIONS OF AMMONIA

    Energy Technology Data Exchange (ETDEWEB)

    Augustovičová, L.; Soldán, P.; Špirko, V., E-mail: spirko@marge.uochb.cas.cz [Charles University in Prague, Faculty of Mathematics and Physics, Department of Chemical Physics and Optics, Ke Karlovu 3, CZ-12116 Prague 2 (Czech Republic)

    2016-06-20

    The hyperfine structure of the rotation-inversion ( v {sub 2} = 0{sup +}, 0{sup −}, 1{sup +}, 1{sup −}) states of the {sup 14}NH{sub 3} and {sup 15}NH{sub 3} ammonia isotopomers is rationalized in terms of effective (ro-inversional) hyperfine-structure (hfs) functions. These are determined by fitting to available experimental data using the Hougen’s effective hyperfine-structure Hamiltonian within the framework of the non-rigid inverter theory. Involving only a moderate number of mass independent fitting parameters, the fitted hfs functions provide a fairly close reproduction of a large majority of available experimental data, thus evidencing adequacy of these functions for reliable prediction. In future experiments, this may help us derive spectroscopic constants of observed inversion and rotation-inversion transitions deperturbed from hyperfine effects. The deperturbed band centers of ammonia come to the forefront of fundamental physics especially as the probes of a variable proton-to-electron mass ratio.

  18. Hyperfine interactions, the key to multiquark physics

    Energy Technology Data Exchange (ETDEWEB)

    Likpink, H.J.

    1988-08-08

    Clues in the search for a fundamental description of hadron physics based on QCD may be obtained from a phenomenological constituent quark model in which the color-electric force binds quarks into saturated color-singlet hadrons, and finer details of the spectrum and multiquark physics are dominated by the color-magnetic hyperfine interaction. 47 refs.

  19. Hyperfine interactions, the key to multiquark physics?

    International Nuclear Information System (INIS)

    Likpink, H.J.

    1988-01-01

    Clues in the search for a fundamental description of hadron physics based on QCD may be obtained from a phenomenological constituent quark model in which the color-electric force binds quarks into saturated color-singlet hadrons, and finer details of the spectrum and multiquark physics are dominated by the color-magnetic hyperfine interaction. 47 refs

  20. A Nonlinear Dynamic Subscale Model for Partially Resolved Numerical Simulation (PRNS)/Very Large Eddy Simulation (VLES) of Internal Non-Reacting Flows

    Science.gov (United States)

    Shih, Tsan-Hsing; Liu, nan-Suey

    2010-01-01

    A brief introduction of the temporal filter based partially resolved numerical simulation/very large eddy simulation approach (PRNS/VLES) and its distinct features are presented. A nonlinear dynamic subscale model and its advantages over the linear subscale eddy viscosity model are described. In addition, a guideline for conducting a PRNS/VLES simulation is provided. Results are presented for three turbulent internal flows. The first one is the turbulent pipe flow at low and high Reynolds numbers to illustrate the basic features of PRNS/VLES; the second one is the swirling turbulent flow in a LM6000 single injector to further demonstrate the differences in the calculated flow fields resulting from the nonlinear model versus the pure eddy viscosity model; the third one is a more complex turbulent flow generated in a single-element lean direct injection (LDI) combustor, the calculated result has demonstrated that the current PRNS/VLES approach is capable of capturing the dynamically important, unsteady turbulent structures while using a relatively coarse grid.

  1. Charge-density-wave partial gap opening in quasi-2D KMo 6O 17 purple bronze studied by angle resolved photoemission spectroscopy

    Science.gov (United States)

    Valbuena, M. A.; Avila, J.; Pantin, V.; Drouard, S.; Guyot, H.; Asensio, M. C.

    2006-05-01

    Low dimensional (LD) metallic oxides have been a subject of continuous interest in the last two decades, mainly due to the electronic instabilities that they present at low temperatures. In particular, charge density waves (CDW) instabilities associated with a strong electron-phonon interaction have been found in Molybdenum metallic oxides such as KMo 6O 17 purple bronze. We report an angle resolved photoemission (ARPES) study from room temperature (RT) to T ˜40 K well below the Peierls transition temperature for this material, with CDW transition temperature TCDW ˜120 K. We have focused on photoemission spectra along ΓM high symmetry direction as well as photoemission measurements were taken as a function of temperature at one representative kF point in the Brillouin zone in order to look for the characteristic gap opening after the phase transition. We found out a pseudogap opening and a decrease in the density of states near the Fermi energy, EF, consistent with the partial removal of the nested portions of the Fermi surface (FS) at temperature below the CDW transition. In order to elucidate possible Fermi liquid (FL) or non-Fermi liquid (NFL) behaviour we have compared the ARPES data with that one reported on quasi-1D K 0.3MoO 3 blue bronze.

  2. Charge-density-wave partial gap opening in quasi-2D KMo6O17 purple bronze studied by angle resolved photoemission spectroscopy

    International Nuclear Information System (INIS)

    Valbuena, M.A.; Avila, J.; Pantin, V.; Drouard, S.; Guyot, H.; Asensio, M.C.

    2006-01-01

    Low dimensional (LD) metallic oxides have been a subject of continuous interest in the last two decades, mainly due to the electronic instabilities that they present at low temperatures. In particular, charge density waves (CDW) instabilities associated with a strong electron-phonon interaction have been found in Molybdenum metallic oxides such as KMo 6 O 17 purple bronze. We report an angle resolved photoemission (ARPES) study from room temperature (RT) to T ∼40 K well below the Peierls transition temperature for this material, with CDW transition temperature T CDW ∼120 K. We have focused on photoemission spectra along ΓM high symmetry direction as well as photoemission measurements were taken as a function of temperature at one representative k F point in the Brillouin zone in order to look for the characteristic gap opening after the phase transition. We found out a pseudogap opening and a decrease in the density of states near the Fermi energy, E F , consistent with the partial removal of the nested portions of the Fermi surface (FS) at temperature below the CDW transition. In order to elucidate possible Fermi liquid (FL) or non-Fermi liquid (NFL) behaviour we have compared the ARPES data with that one reported on quasi-1D K 0.3 MoO 3 blue bronze

  3. Charge-density-wave partial gap opening in quasi-2D KMo{sub 6}O{sub 17} purple bronze studied by angle resolved photoemission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Valbuena, M.A. [LURE, Centre Universitaire Paris-Sud, Bat. 209D, B.P. 34, 91898 Orsay Cedex (France); Avila, J. [Instituto de Ciencia de Materiales de Madrid, ICMM - CSIC, 28049 Madrid (Spain); Synchrotron SOLEIL, L' Orme des Merisiers, Saint-Aubin - B.P. 48, 91192 GIF-SUR-YVETTE Cedex (France); Pantin, V. [LURE, Centre Universitaire Paris-Sud, Bat. 209D, B.P. 34, 91898 Orsay Cedex (France); Drouard, S. [LEPES-CENES, B.P. 166x, 38042 Grenoble, Cedex 9 (France); Guyot, H. [LEPES-CENES, B.P. 166x, 38042 Grenoble, Cedex 9 (France); Asensio, M.C. [Instituto de Ciencia de Materiales de Madrid, ICMM - CSIC, 28049 Madrid (Spain) and Synchrotron SOLEIL, L' Orme des Merisiers, Saint-Aubin - B.P. 48, 91192 GIF-SUR-YVETTE Cedex (France)]. E-mail: asensio@synchrotron-soleil.fr

    2006-05-30

    Low dimensional (LD) metallic oxides have been a subject of continuous interest in the last two decades, mainly due to the electronic instabilities that they present at low temperatures. In particular, charge density waves (CDW) instabilities associated with a strong electron-phonon interaction have been found in Molybdenum metallic oxides such as KMo{sub 6}O{sub 17} purple bronze. We report an angle resolved photoemission (ARPES) study from room temperature (RT) to T {approx}40 K well below the Peierls transition temperature for this material, with CDW transition temperature T {sub CDW} {approx}120 K. We have focused on photoemission spectra along {gamma}M high symmetry direction as well as photoemission measurements were taken as a function of temperature at one representative k {sub F} point in the Brillouin zone in order to look for the characteristic gap opening after the phase transition. We found out a pseudogap opening and a decrease in the density of states near the Fermi energy, E {sub F}, consistent with the partial removal of the nested portions of the Fermi surface (FS) at temperature below the CDW transition. In order to elucidate possible Fermi liquid (FL) or non-Fermi liquid (NFL) behaviour we have compared the ARPES data with that one reported on quasi-1D K{sub 0.3}MoO{sub 3} blue bronze.

  4. Evaluating Lightning-generated NOx (LNOx) Parameterization based on Cloud Top Height at Resolutions with Partially-resolved Convection for Upper Tropospheric Chemistry Studies

    Science.gov (United States)

    Wong, J.; Barth, M. C.; Noone, D. C.

    2012-12-01

    Lightning-generated nitrogen oxides (LNOx) is an important precursor to tropospheric ozone production. With a meteorological time-scale variability similar to that of the ozone chemical lifetime, it can nonlinearly perturb tropospheric ozone concentration. Coupled with upper-air circulation patterns, LNOx can accumulate in significant amount in the upper troposphere with other precursors, thus enhancing ozone production (see attached figure). While LNOx emission has been included and tuned extensively in global climate models, its inclusions in regional chemistry models are seldom tested. Here we present a study that evaluates the frequently used Price and Rind parameterization based on cloud-top height at resolutions that partially resolve deep convection using the Weather Research and Forecasting model with Chemistry (WRF-Chem) over the contiguous United States. With minor modifications, the parameterization is shown to generate integrated flash counts close to those observed. However, the modeled frequency distribution of cloud-to-ground flashes do not represent well for storms with high flash rates, bringing into question the applicability of the intra-cloud/ground partitioning (IC:CG) formulation of Price and Rind in some studies. Resolution dependency also requires attention when sub-grid cloud-tops are used instead of the originally intended grid-averaged cloud-top. LNOx passive tracers being gathered by monsoonal upper tropospheric anticyclone.

  5. Hyperfine interactions associated with iron substitute superconducting oxides

    International Nuclear Information System (INIS)

    Ellis, D.E.; Dunlap, B.D.; Saitovitch, E.B.; Azevedo, I.S.; Scorzelli, R.B.; Kimball, C.W.

    1988-01-01

    Theoretical and experimental Moessbauer spectroscopy studies have been made concerning charge and spin densities and magnetic hyperfine fields (H hf in iron-substituted superconducting oxides. Calculations were carried out in the self-consistent-field embedded cluster model using local density theory (SCF-Xα) with a variational atomic orbital basis. Spectral densities and changes in charge and spin density were monitored around neighboring Cu sites, as well as Fe impurity site, in La 2 Cu 1-x Fe x O 4 and YBa 2 Cu 3-x Fe x O 7-y compounds. Moessbauer isomer shifts (IS), quadrupole splittings (QS) and H hf are obtained by fitting multiline models to the observed spectra and are compared with SCF-Xα results for specific lattice sites. The influence of oxygen vacancies and partial oxygen disorder is modelled and compared with the experimental data on variable oxygen content and disorder. (author)

  6. Hyperfine structure of muonic lithium ions

    Directory of Open Access Journals (Sweden)

    Alexey P. Martynenko

    2015-06-01

    Full Text Available On the basis of perturbation theory in fine structure constant $\\alpha$ and the ratio of electron to muon masses we calculate recoil corrections of order $\\alpha^4 (M_e/M_\\mu$, $\\alpha^4 (M_e/M_\\mu^2\\ln(M_e/M_\\mu$, $\\alpha^4 (M_e/M_\\mu^2$, $\\alpha^5(m_e/m_\\mu\\ln(m_e/m_\\mu$ to hyperfine splitting of the ground state in muonic lithium ions $(\\mu e ^6_3\\mathrm{Li}^+$ and $(\\mu e ^7_3\\mathrm{Li}^+$. We obtain total results for the ground state small hyperfine splittings in $(\\mu e ^6_3\\mathrm{Li}^+$ $\\Delta\

  7. Hyperfine interactions measured by nuclear orientation technique

    International Nuclear Information System (INIS)

    Brenier, R.

    1982-01-01

    This report concerns the use of hyperfine interaction to magnetism measurements and to the determination of the nuclear structure of Terbium isotopes by the low temperature nuclear orientation technique. In the first part we show that the rhodium atom does not support any localized moment in the chromium matrix. The hyperfine magnetic field at the rhodium nuclear site follows the Overhauser distribution, and the external applied magnetic field supports a negative Knight shift of 16%. In the second part we consider the structure of neutron deficient Terbium isotopes. We introduce a coherent way of evaluation and elaborate a new nuclear thermometer. The magnetic moments allows to strike on the studied states configuration. The analysis of our results shows a decrease of the nuclear deformation for the lighter isotopes [fr

  8. The hyperfine Paschen–Back Faraday effect

    International Nuclear Information System (INIS)

    Zentile, Mark A; Andrews, Rebecca; Weller, Lee; Adams, Charles S; Hughes, Ifan G; Knappe, Svenja

    2014-01-01

    We investigate experimentally and theoretically the Faraday effect in an atomic medium in the hyperfine Paschen–Back regime, where the Zeeman interaction is larger than the hyperfine splitting. We use a small permanent magnet and a micro-fabricated vapour cell, giving magnetic fields of the order of a tesla. We show that for low absorption and small rotation angles, the refractive index is well approximated by the Faraday rotation signal, giving a simple way to measure the atomic refractive index. Fitting to the atomic spectra, we achieve magnetic field sensitivity at the 10 −4 level. Finally we note that the Faraday signal shows zero crossings which can be used as temperature insensitive error signals for laser frequency stabilization at large detuning. The theoretical sensitivity for 87 Rb is found to be ∼40 kHz °C −1 . (paper)

  9. A comparative transmission electron microscopy, energy dispersive x-ray spectroscopy and spatially resolved micropillar compression study of the yttria partially stabilised zirconia - porcelain interface in dental prosthesis

    Energy Technology Data Exchange (ETDEWEB)

    Lunt, Alexander J.G., E-mail: alexander.lunt@chch.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Mohanty, Gaurav, E-mail: gaurav.mohanty@empa.ch [EMPA Materials Science & Technology, Feuerwerkerstrasse 39, CH-3602 Thun (Switzerland); Ying, Siqi, E-mail: siqi.ying@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Dluhoš, Jiří, E-mail: jiri.dluhos@tescan.cz [TESCAN Brno, s.r.o., Libušina tř. 1, 623 00 Brno-Kohoutovice (Czech Republic); Sui, Tan, E-mail: tan.sui@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Neo, Tee K., E-mail: neophyte@singnet.com.sg [Specialist Dental Group, Mount Elizabeth Orchard, 3 Mount Elizabeth, #08-03/08-08/08-10, 228510 (Singapore); Michler, Johann, E-mail: johann.michler@empa.ch [EMPA Materials Science & Technology, Feuerwerkerstrasse 39, CH-3602 Thun (Switzerland); Korsunsky, Alexander M., E-mail: alexander.korsunsky@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom)

    2015-12-01

    μm. - Highlights: • Cross section of yttria partially stabilised zirconia (YPSZ)–porcelain prosthesis • Energy dispersive X-ray spectroscopy shows 2–6 μm elemental diffusion zone. • Transmission electron microscopy shows voids in near interface porcelain. • Complex near interface YPSZ microstructure shows grains embedded in porcelain. • Spatially resolved micropillar compression reveals modulus and strength variation.

  10. Muons as hyperfine interaction probes in chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Ghandi, Khashayar, E-mail: kghandi@triumf.ca; MacLean, Amy [Mount Allison University, Department of Chemistry & Biochemistry (Canada)

    2015-04-15

    Spin polarized positive muons injected in matter serve as magnetic probes for the investigation of physical and chemical properties of free radicals, mechanisms of free radical reactions and their formations, and radiation effects. All muon techniques rely on the evolution of spin polarization (of the muon) and in that respect are similar to conventional magnetic resonance techniques. The applications of the muon as a hyperfine probe in several fields in chemistry are described.

  11. Muons as hyperfine interaction probes in chemistry

    International Nuclear Information System (INIS)

    Ghandi, Khashayar; MacLean, Amy

    2015-01-01

    Spin polarized positive muons injected in matter serve as magnetic probes for the investigation of physical and chemical properties of free radicals, mechanisms of free radical reactions and their formations, and radiation effects. All muon techniques rely on the evolution of spin polarization (of the muon) and in that respect are similar to conventional magnetic resonance techniques. The applications of the muon as a hyperfine probe in several fields in chemistry are described

  12. Proceedings of 4 conference on hyperfine interaction spectroscopic investigations

    International Nuclear Information System (INIS)

    Shpinel', V.S.

    1992-01-01

    Results of theoretical and experimental investigations on nuclear-spectroscopy of hyperfine interactions are presented. Possibility of the data use for technological and materials sceince problems is demonstrated

  13. Observation of the hyperfine spectrum of antihydrogen

    Science.gov (United States)

    Ahmadi, M.; Alves, B. X. R.; Baker, C. J.; Bertsche, W.; Butler, E.; Capra, A.; Carruth, C.; Cesar, C. L.; Charlton, M.; Cohen, S.; Collister, R.; Eriksson, S.; Evans, A.; Evetts, N.; Fajans, J.; Friesen, T.; Fujiwara, M. C.; Gill, D. R.; Gutierrez, A.; Hangst, J. S.; Hardy, W. N.; Hayden, M. E.; Isaac, C. A.; Ishida, A.; Johnson, M. A.; Jones, S. A.; Jonsell, S.; Kurchaninov, L.; Madsen, N.; Mathers, M.; Maxwell, D.; McKenna, J. T. K.; Menary, S.; Michan, J. M.; Momose, T.; Munich, J. J.; Nolan, P.; Olchanski, K.; Olin, A.; Pusa, P.; Rasmussen, C. Ø.; Robicheaux, F.; Sacramento, R. L.; Sameed, M.; Sarid, E.; Silveira, D. M.; Stracka, S.; Stutter, G.; So, C.; Tharp, T. D.; Thompson, J. E.; Thompson, R. I.; van der Werf, D. P.; Wurtele, J. S.

    2017-08-01

    The observation of hyperfine structure in atomic hydrogen by Rabi and co-workers and the measurement of the zero-field ground-state splitting at the level of seven parts in 1013 are important achievements of mid-twentieth-century physics. The work that led to these achievements also provided the first evidence for the anomalous magnetic moment of the electron, inspired Schwinger’s relativistic theory of quantum electrodynamics and gave rise to the hydrogen maser, which is a critical component of modern navigation, geo-positioning and very-long-baseline interferometry systems. Research at the Antiproton Decelerator at CERN by the ALPHA collaboration extends these enquiries into the antimatter sector. Recently, tools have been developed that enable studies of the hyperfine structure of antihydrogen—the antimatter counterpart of hydrogen. The goal of such studies is to search for any differences that might exist between this archetypal pair of atoms, and thereby to test the fundamental principles on which quantum field theory is constructed. Magnetic trapping of antihydrogen atoms provides a means of studying them by combining electromagnetic interaction with detection techniques that are unique to antimatter. Here we report the results of a microwave spectroscopy experiment in which we probe the response of antihydrogen over a controlled range of frequencies. The data reveal clear and distinct signatures of two allowed transitions, from which we obtain a direct, magnetic-field-independent measurement of the hyperfine splitting. From a set of trials involving 194 detected atoms, we determine a splitting of 1,420.4 ± 0.5 megahertz, consistent with expectations for atomic hydrogen at the level of four parts in 104. This observation of the detailed behaviour of a quantum transition in an atom of antihydrogen exemplifies tests of fundamental symmetries such as charge-parity-time in antimatter, and the techniques developed here will enable more-precise such tests.

  14. Observation of the hyperfine spectrum of antihydrogen.

    Science.gov (United States)

    Ahmadi, M; Alves, B X R; Baker, C J; Bertsche, W; Butler, E; Capra, A; Carruth, C; Cesar, C L; Charlton, M; Cohen, S; Collister, R; Eriksson, S; Evans, A; Evetts, N; Fajans, J; Friesen, T; Fujiwara, M C; Gill, D R; Gutierrez, A; Hangst, J S; Hardy, W N; Hayden, M E; Isaac, C A; Ishida, A; Johnson, M A; Jones, S A; Jonsell, S; Kurchaninov, L; Madsen, N; Mathers, M; Maxwell, D; McKenna, J T K; Menary, S; Michan, J M; Momose, T; Munich, J J; Nolan, P; Olchanski, K; Olin, A; Pusa, P; Rasmussen, C Ø; Robicheaux, F; Sacramento, R L; Sameed, M; Sarid, E; Silveira, D M; Stracka, S; Stutter, G; So, C; Tharp, T D; Thompson, J E; Thompson, R I; van der Werf, D P; Wurtele, J S

    2017-08-02

    The observation of hyperfine structure in atomic hydrogen by Rabi and co-workers and the measurement of the zero-field ground-state splitting at the level of seven parts in 10 13 are important achievements of mid-twentieth-century physics. The work that led to these achievements also provided the first evidence for the anomalous magnetic moment of the electron, inspired Schwinger's relativistic theory of quantum electrodynamics and gave rise to the hydrogen maser, which is a critical component of modern navigation, geo-positioning and very-long-baseline interferometry systems. Research at the Antiproton Decelerator at CERN by the ALPHA collaboration extends these enquiries into the antimatter sector. Recently, tools have been developed that enable studies of the hyperfine structure of antihydrogen-the antimatter counterpart of hydrogen. The goal of such studies is to search for any differences that might exist between this archetypal pair of atoms, and thereby to test the fundamental principles on which quantum field theory is constructed. Magnetic trapping of antihydrogen atoms provides a means of studying them by combining electromagnetic interaction with detection techniques that are unique to antimatter. Here we report the results of a microwave spectroscopy experiment in which we probe the response of antihydrogen over a controlled range of frequencies. The data reveal clear and distinct signatures of two allowed transitions, from which we obtain a direct, magnetic-field-independent measurement of the hyperfine splitting. From a set of trials involving 194 detected atoms, we determine a splitting of 1,420.4 ± 0.5 megahertz, consistent with expectations for atomic hydrogen at the level of four parts in 10 4 . This observation of the detailed behaviour of a quantum transition in an atom of antihydrogen exemplifies tests of fundamental symmetries such as charge-parity-time in antimatter, and the techniques developed here will enable more-precise such tests.

  15. Hyperfine characterization of the Ba Ti1-x Hfx O3 for x = 0.20

    International Nuclear Information System (INIS)

    Ayala, Alexandro; Lopez-Garcia, Alberto

    1996-01-01

    It is known that the cation substitution in perovskites produce changes in the macroscopic properties of these materials. A case to study is for example the influence of cation B partially substituted by cation B ' when ABO 3 is ferroelectric, and A B ' O 3 is paraelectric. In this work the system Ba Ti 1-x Hf x O 3 with x = 0.05, 0.10, 0.15 and 0.20 is studied by Perturbed Angular Correlations (Pac) in order to obtain microscopic information through the electric field gradient tensor (EFG) produced by electrons close to probes. Two hyperfine quadrupole interactions were detected. One interaction associated to probes with defects originated during the nuclear processes after neutron irradiation, and the other are located in B sites. At R T, the hyperfine parameters are analyzed in terms of Hf concentration. (author)

  16. Magnetic hyperfine field at caesium in iron

    International Nuclear Information System (INIS)

    Ashworth, C.J.; Back, P.; Stone, N.J.; White, J.P.; Ohya, S.

    1990-01-01

    We report temperature dependence of nuclear orientation (NO), and the first observation of NMR/ON on Cs in iron. 132,136 Cs were implanted at room temperature into polycrystalline and single crystal iron. NO values for the (average) magnetic hyperfine field B hf (CsFe) are close to 34 T, intermediate between the value of 40.7 T found in on-line samples made at mK temperatures and the NMR/ON value of 27.8(2) T. The latter studies. The site/field distribution is briefly discussed. (orig.)

  17. Hyperfine structure studies with the COMPLIS facility

    CERN Document Server

    Crawford, J E; Le Blanc, F; Lunney, M D; Obert, J; Oms, J; Putaux, J C; Roussière, B; Sauvage, J; Zemlyanoi, S G; Verney, D; Pinard, J; Cabaret, L A; Duong, H T; Huber, G; Krieg, M; Sebastian, V; Girod, M; Peru, S; Genevey, J; Ibrahim, F; Lettry, Jacques

    1998-01-01

    COMPLIS is an experimental facility designed to carry out spectroscopic studies on radioisotopes produced by disintegration of elements available at CERN's Booster-ISOLDE on-line isotope separator. During recent series of experimental runs, hyperfine structure measurements have yielded information on nuclear moments and deformations of platinum and iridium isotopes, For the first time, population by alpha -decay from Hg was exploited to investigate /sup 178/-/sup 181/Pt-the most neutron-deficient Pt isotopes yet studied. Successful measurements have recently been carried out on /sup 182-189/Ir. (10 refs).

  18. Directionally independent energy gap formation due to the hyperfine interaction

    NARCIS (Netherlands)

    Miyashita, Seiji; Raedt, Hans De; Michielsen, Kristel

    We study energy gap formation at the level-crossing point due to the hyperfine interaction. In contrast to the energy gap induced by the Dzyaloshinskii-Moriya interaction, the gap induced by the hyperfine interaction is independent of the direction of the magnetic field. We also study the dynamics

  19. Energy Levels, wavelengths and hyperfine structure measurements of Sc II

    Science.gov (United States)

    Hala, Fnu; Nave, Gillian

    2018-01-01

    Lines of singly ionized Scandium (Sc II) along with other Iron group elements have been observed [1] in the region surrounding the massive star Eta Carinae [2,3] called the strontium filament (SrF). The last extensive analysis of Sc II was the four-decade old work of Johansson & Litzen [4], using low-resolution grating spectroscopy. To update and extend the Sc II spectra, we have made observation of Sc/Ar, Sc/Ne and Sc/Ge/Ar hollow cathode emission spectrum on the NIST high resolution FT700 UV/Vis and 2 m UV/Vis/IR Fourier transform spectrometers (FTS). More than 850 Sc II lines have been measured in the wavelength range of 187 nm to 3.2 μm. connecting a total of 152 energy levels. The present work also focuses to resolve hyperfine structure (HFS) in Sc II lines. We aim to obtain accurate transition wavelengths, improved energy levels and HFS constants of Sc II. The latest results from work in progress will be presented.Reference[1] Hartman H, Gull T, Johansson S and Smith N 2004 Astron. Astrophys. 419 215[2] Smith N, Morse J A and Gull T R 2004 Astrophys. J. 605 405[3] Davidson K and Humphreys R M 1997 Annu. Rev. Astron. Astrophys. 35[4] Johansson S and Litzén U 1980 Phys. Scr. 22 49

  20. Nuclear Hyperfine Structure in the Donor – Acceptor Complexes (CH3)3N-BF3 and (CH)33N-B(CH3)3

    Science.gov (United States)

    The donor-acceptor complexes (CH3)3N-BF3 and (CH3)3N-B(CH3)3 have been reinvestigated at high resolution by rotational spectroscopy in a supersonic jet. Nuclear hyperfine structure resulting from both nitrogen and boron has been resolved and quadrupole coupling constants have bee...

  1. 1H NMR spectra of vertebrate [2Fe-2S] ferredoxins. Hyperfine resonances suggest different electron delocalization patterns from plant ferredoxins

    International Nuclear Information System (INIS)

    Skjeldal, L.; Markley, J.L.; Coghlan, V.M.; Vickery, L.E.

    1991-01-01

    The authors report the observation of paramagnetically shifted (hyperfine) proton resonances from vertebrate mitochondrial [2Fe-2S] ferredoxins. The hyperfine signals of human, bovine, and chick [2Fe-2S] ferredoxins are described and compared with those of Anabena 7120 vegetative ferredoxin, a plant-type [2Fe-2S] ferredoxin studied previously. The hyperfine resonances of the three vertebrate ferredoxins were very similar to one another both in the oxidized state and in the reduced state, and slow (on the NMR scale) electron self-exchange was observed in partially reduced samples. For the oxidized vertebrate ferredoxins, hyperfine signals were observed downfield of the diamagnetic envelope from +13 to +50 ppm, and the general pattern of peaks and their anti-Curie temperature dependence are similar to those observed for the oxidized plant-type ferredoxins. For the reduced vertebrate ferredoxins, hyperfine signals were observed for the oxidized plant-type ferredoxins. For the reduced vertebrate ferredoxins, hyperfine signals were observed both upfield (-2 to -18 ppm) and downfield (+15 to +45 ppm), and all were found to exhibit Curie-type temperature dependence. These results indicate that the contact-shifted resonances in the reduced vertebrate ferredoxins detect different spin magnetization from those in the reduced plant ferredoxins and suggest that plant and vertebrate ferredoxins have fundamentally different patterns of electron delocalization in the reduced [2Fe-2S] center

  2. Hyperfine interaction measurements on ceramics: PZT revisited

    International Nuclear Information System (INIS)

    Guarany, Cristiano A.; Araujo, Eudes B.; Silva, Paulo R.J.; Saitovitch, Henrique

    2007-01-01

    The solid solution of PbZr 1- x Ti x O 3 , known as lead-zirconate titanate (PZT), was probably one of the most studied ferroelectric materials, especially due to its excellent dielectric, ferroelectric and piezoelectric properties. The highest piezoelectric coefficients of the PZT are found near the morphotropic phase boundary (MPB) (0.46≤x≤0.49), between the tetragonal and rhombohedral regions of the composition-temperature phase diagram. Recently, a new monoclinic phase near the MPB was observed, which can be considered as a 'bridge' between PZT's tetragonal and rhombohedral phases. This work is concerned with the study of the structural properties of the ferroelectric PZT (Zr/Ti=52/48, 53/47) by hyperfine interaction (HI) measurements obtained from experiments performed by using the nuclear spectroscopy time differential perturbed angular correlation (TDPAC) in a wide temperature range

  3. Hyperfine interaction measurements on ceramics: PZT revisited

    Energy Technology Data Exchange (ETDEWEB)

    Guarany, Cristiano A. [Universidade Estadual Paulista (Unesp), Departmento de Fisica Quimica, Caixa Postal 31, 15.385-000 Ilha Solteira, SP (Brazil); Araujo, Eudes B. [Universidade Estadual Paulista (Unesp), Departmento de Fisica Quimica, Caixa Postal 31, 15.385-000 Ilha Solteira, SP (Brazil); Silva, Paulo R.J. [Centro Brasileiro de Pesquisas Fisicas-Rua Dr. Xavier Sigaud, 150, 22290-180 Rio de Janeiro, RJ (Brazil); Saitovitch, Henrique [Centro Brasileiro de Pesquisas Fisicas-Rua Dr. Xavier Sigaud, 150, 22290-180 Rio de Janeiro, RJ (Brazil)]. E-mail: henrique@cbpf.br

    2007-02-01

    The solid solution of PbZr{sub 1-} {sub x} Ti {sub x} O{sub 3}, known as lead-zirconate titanate (PZT), was probably one of the most studied ferroelectric materials, especially due to its excellent dielectric, ferroelectric and piezoelectric properties. The highest piezoelectric coefficients of the PZT are found near the morphotropic phase boundary (MPB) (0.46{<=}x{<=}0.49), between the tetragonal and rhombohedral regions of the composition-temperature phase diagram. Recently, a new monoclinic phase near the MPB was observed, which can be considered as a 'bridge' between PZT's tetragonal and rhombohedral phases. This work is concerned with the study of the structural properties of the ferroelectric PZT (Zr/Ti=52/48, 53/47) by hyperfine interaction (HI) measurements obtained from experiments performed by using the nuclear spectroscopy time differential perturbed angular correlation (TDPAC) in a wide temperature range.

  4. Hyperfine structure of S-states of muonic tritium

    Directory of Open Access Journals (Sweden)

    Martynenko F.A.

    2017-01-01

    Full Text Available On the basis of quasipotential method in quantum electrodynamics we carry out a precise calculation of hyperfine splitting of S-states in muonic tritium. The one-loop and two-loop vacuum polarization corrections, relativistic effects, nuclear structure corrections in first and second orders of perturbation theory are taken into account. The contributions to hyperfine structure are obtained in integral form and calculated analytically and numerically. Obtained results for hyperfine splitting can be used for a comparison with future experimental data of CREMA collaboration.

  5. Muonium hyperfine parameters in Si1-x Ge x alloys

    International Nuclear Information System (INIS)

    King, Philip; Lichti, Roger; Cottrell, Stephen; Yonenaga, Ichiro

    2006-01-01

    We present studies of muonium behaviour in bulk, Czochralski-grown Si 1- x Ge x alloy material, focusing in particular on the hyperfine parameter of the tetrahedral muonium species. In contrast to the bond-centred species, the hyperfine parameter of the tetrahedral-site muonium centre (Mu T ) appears to vary non-linearly with alloy composition. The temperature dependence of the Mu T hyperfine parameter observed in low-Ge alloy material is compared with that seen in pure Si, and previous models of the Mu T behaviour in Si are discussed in the light of results from Si 1- x Ge x alloys

  6. The hyperfine properties of a hydrogenated Fe/V superlattice

    Energy Technology Data Exchange (ETDEWEB)

    Elzain, M., E-mail: elzain@squ.edu.om; Al-Barwani, M.; Gismelseed, A.; Al-Rawas, A.; Yousif, A.; Widatallah, H.; Bouziane, K.; Al-Omari, I. [Sultan Qaboos University, Department of Physics, College of Science (Oman)

    2012-03-15

    We study the effect of hydrogen on the electronic, magnetic and hyperfine structures of an iron-vanadium superlattice consisting of three Fe monolayers and nine V monolayers. The contact charge density ({rho}), the contact hyperfine field (B{sub hf}) and the electronic field gradient (EFG) at the Fe sites for different H locations and H fillings are calculated using the first principle full-potential linear-augmented-plane-wave (FP-LAPW) method. It is found that sizeable changes in the hyperfine properties are obtained only when H is in the interface region.

  7. Structural properties and hyperfine characterization of Sn-substituted goethites

    Energy Technology Data Exchange (ETDEWEB)

    Larralde, A.L. [INQUIMAE, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires (Argentina); Ramos, C.P. [Departamento de Fisica de la Materia Condensada, GIyA - CAC - CNEA, Av. Gral. Paz 1499 (1650), San Martin, Bs. As. (Argentina); Arcondo, B. [Departamento de Fisica, Facultad de Ingenieria, Universidad de Buenos Aires, Av. Paseo Colon 850 (C1063ACV), Bs. As. (Argentina); Tufo, A.E. [INQUIMAE, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires (Argentina); Saragovi, C. [Departamento de Fisica de la Materia Condensada, GIyA - CAC - CNEA, Av. Gral. Paz 1499 (1650), San Martin, Bs. As. (Argentina); Sileo, E.E., E-mail: sileo@qi.fcen.uba.ar [INQUIMAE, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires (Argentina)

    2012-04-16

    Highlights: Black-Right-Pointing-Pointer Pure and tin-doped goethites were synthesized from Sn(II) solutions at ambient pressure and 70 Degree-Sign C. Black-Right-Pointing-Pointer The Rietveld refinement of PXRD data indicated that Sn partially substituted the Fe(III) ions. Black-Right-Pointing-Pointer The substitution provoked unit cell expansion, and a distortion of the coordination polyhedron. Black-Right-Pointing-Pointer {sup 119}Sn Moessbauer spectroscopy revealed that Sn(II) is incorporated as Sn(IV). Black-Right-Pointing-Pointer {sup 57}Fe Moessbauer spectroscopy showed a lower magnetic coupling as tin concentration increased. - Abstract: Tin-doped goethites obtained by a simple method at ambient pressure and 70 Degree-Sign C were characterized by inductively coupled plasma atomic emission spectrometry, scanning electron microscopy, Rietveld refinement of powder X-ray diffraction data, and {sup 57}Fe and {sup 119}Sn Moessbauer spectroscopy. The particles size and the length to width ratios decreased with tin-doping. Sn partially substituted the Fe(III) ions provoking unit cell expansion and increasing the crystallinity of the particles with enlarged domains that grow in the perpendicular and parallel directions to the anisotropic broadening (1 1 1) axis. Intermetallic E, E Prime and DC distances also change although the variations are not monotonous, indicating different variations in the coordination polyhedron. In general, the Sn-substituted samples present larger intermetallic distances than pure goethite, and the greatest change is shown in the E Prime distance which coincides with the c-parameter. {sup 119}Sn Moessbauer spectroscopy revealed that Sn(II) is incorporated as Sn(IV) in the samples. On the other hand, Fe(II) presence was not detected by {sup 57}Fe Moessbauer spectroscopy, suggesting the existence of vacancies in the Sn-doped samples. A lower magnetic coupling is also evidenced from the average magnetic hyperfine field values obtained as tin

  8. Variations of 57Fe hyperfine parameters in medicaments containing ferrous fumarate and ferrous sulfate

    International Nuclear Information System (INIS)

    Oshtrakh, M. I.; Novikov, E. G.; Dubiel, S. M.; Semionkin, V. A.

    2010-01-01

    Several commercially available medicaments containing ferrous fumarate (FeC 4 H 2 O 4 ) and ferrous sulfate (FeSO 4 ), as a source of ferrous iron, were studied using a high velocity resolution Mössbauer spectroscopy. A comparison of the 57 Fe hyperfine parameters revealed small variations for the main components in both medicaments indicating some differences in the ferrous fumarates and ferrous sulfates. It was also found that all spectra contained additional minor components probably related to ferrous and ferric impurities or to partially modified main components.

  9. Variations of {sup 57}Fe hyperfine parameters in medicaments containing ferrous fumarate and ferrous sulfate

    Energy Technology Data Exchange (ETDEWEB)

    Oshtrakh, M. I., E-mail: oshtrakh@mail.utnet.ru; Novikov, E. G. [Ural Federal University (The former Ural State Technical University-UPI), Faculty of Physical Techniques and Devices for Quality Control (Russian Federation); Dubiel, S. M. [AGH University of Science and Technology, Faculty of Physics and Computer Science (Poland); Semionkin, V. A. [Ural Federal University (The former Ural State Technical University-UPI), Faculty of Physical Techniques and Devices for Quality Control (Russian Federation)

    2010-04-15

    Several commercially available medicaments containing ferrous fumarate (FeC{sub 4}H{sub 2}O{sub 4}) and ferrous sulfate (FeSO{sub 4}), as a source of ferrous iron, were studied using a high velocity resolution Moessbauer spectroscopy. A comparison of the {sup 57}Fe hyperfine parameters revealed small variations for the main components in both medicaments indicating some differences in the ferrous fumarates and ferrous sulfates. It was also found that all spectra contained additional minor components probably related to ferrous and ferric impurities or to partially modified main components.

  10. Electrical detection of hyperfine interactions in silicon

    Energy Technology Data Exchange (ETDEWEB)

    Hoehne, Felix

    2012-12-15

    The main focus of this work was the measurement of hyperfine interactions of defects in silicon using EDMR. We combined the high sensitivity of EDMR when compared to conventional ESR with the two most commonly used methods for the measurement of hyperfine interactions: ESEEM and ENDOR. We first demonstrated the electrical detection of ESEEM by measuring the hyperfine interactions of {sup 31}P donors in Si:P with {sup 29}Si nuclear spins. We then apply EDESEEM to P{sub b0} defects at the Si/SiO{sub 2} interface. In isotopically engineered, we observe an ESEEM modulation with a characteristic beating caused by {sup 29}Si nuclei at 4th and 5th nearest neighbor lattice sites. Then we combine pulsed ENDOR with the high sensitivity of EDMR (EDENDOR). First we demonstrate the measurement of {sup 31}P nuclear spin hyperfine transitions and the coherent manipulation and readout of the {sup 31}P nuclear spins under continuous illumination with above bandgap light. We further show that the EDENDOR method can be greatly improved by switching off the illumination during the microwave and rf pulses. This improves the signal-to-noise ratio by two orders of magnitude and removes the non-resonant background induced by the strong rf pulse allowing to measure ENDOR with a sensitivity <3000 nuclear spins. We apply EDENDOR to the {sup 31}P-P{sub b0} spin system and the {sup 31}P-SL1 spin system allowing us to compare the hyperfine interactions of bulk and interface-near donors. The pulsed illumination also makes spectroscopy of the {sup 31}P{sup +} nuclear spin possible, which due to its long coherence time of 18 ms compared to 280 {mu}s for the {sup 31}P{sub 0} nuclear spin, might be a candidate for a nuclear spin memory. In the last part, we devise a scheme for the hyperpolarization of {sup 31}P nuclei by combining pulsed optical excitation and pulsed ENDOR and demonstrate a {sup 31}P nuclear spin polarization of more than 50%. Crucial for these experiments was the development of a

  11. Electrical detection of hyperfine interactions in silicon

    International Nuclear Information System (INIS)

    Hoehne, Felix

    2012-01-01

    The main focus of this work was the measurement of hyperfine interactions of defects in silicon using EDMR. We combined the high sensitivity of EDMR when compared to conventional ESR with the two most commonly used methods for the measurement of hyperfine interactions: ESEEM and ENDOR. We first demonstrated the electrical detection of ESEEM by measuring the hyperfine interactions of 31 P donors in Si:P with 29 Si nuclear spins. We then apply EDESEEM to P b0 defects at the Si/SiO 2 interface. In isotopically engineered, we observe an ESEEM modulation with a characteristic beating caused by 29 Si nuclei at 4th and 5th nearest neighbor lattice sites. Then we combine pulsed ENDOR with the high sensitivity of EDMR (EDENDOR). First we demonstrate the measurement of 31 P nuclear spin hyperfine transitions and the coherent manipulation and readout of the 31 P nuclear spins under continuous illumination with above bandgap light. We further show that the EDENDOR method can be greatly improved by switching off the illumination during the microwave and rf pulses. This improves the signal-to-noise ratio by two orders of magnitude and removes the non-resonant background induced by the strong rf pulse allowing to measure ENDOR with a sensitivity 31 P-P b0 spin system and the 31 P-SL1 spin system allowing us to compare the hyperfine interactions of bulk and interface-near donors. The pulsed illumination also makes spectroscopy of the 31 P + nuclear spin possible, which due to its long coherence time of 18 ms compared to 280 μs for the 31 P 0 nuclear spin, might be a candidate for a nuclear spin memory. In the last part, we devise a scheme for the hyperpolarization of 31 P nuclei by combining pulsed optical excitation and pulsed ENDOR and demonstrate a 31 P nuclear spin polarization of more than 50%. Crucial for these experiments was the development of a lock-in detection scheme for pEDMR, which improves the signal-to-noise ratio by one order of magnitude by removing low

  12. Measurement of the hyperfine magnetic field on rhodium in chromium

    International Nuclear Information System (INIS)

    Peretto, P.; Teisseron, G.; Berthier, J.

    1978-01-01

    Hyperfine magnetic field of rhodium in a chromium matrix is studied. Anisotropy of rhodium 100 is + 0.17. Time dependence of angular correlation is given with a sample containing 145 ppm of rhodium despite the short life [fr

  13. Measurement of the hyperfine structure of antihydrogen in a beam

    Energy Technology Data Exchange (ETDEWEB)

    Widmann, E., E-mail: ew@antihydrogen.at; Diermaier, M. [Austrian Academy of Sciences, Stefan Meyer Institute for Subatomic Physics (Austria); Juhasz, B. [Lufthansa Systems Hungaria Kft. (Hungary); Malbrunot, C.; Massiczek, O.; Sauerzopf, C.; Suzuki, K.; Wuenschek, B.; Zmeskal, J. [Austrian Academy of Sciences, Stefan Meyer Institute for Subatomic Physics (Austria); Federmann, S. [CERN (Switzerland); Kuroda, N. [University of Tokyo, Institute of Physics (Japan); Ulmer, S.; Yamazaki, Y. [RIKEN Advanced Science Institute (Japan)

    2013-03-15

    A measurement of the hyperfine structure of antihydrogen promises one of the best tests of CPT symmetry. We describe an experiment planned at the Antiproton Decelerator of CERN to measure this quantity in a beam of slow antihydrogen atoms.

  14. Hyperfine fields at 89Y nuclei in Y(Fesub(1-x)Tsub(x))2 (T=V, Mn, Co, Ni, Al) with low concentrations x

    International Nuclear Information System (INIS)

    Ichinose, Kazuyoshi; Yoshie, Hiroshi; Nagai, Hiroyuki; Tsujimura, Akira; Fujiwara, Katsuyuki.

    1983-01-01

    NMR of 89 Y nuclei in Y(Fesub(1-x)Tsub(x)) 2 (T=V, Mn, Co, Ni, Al) has been observed at 4.2K. Well-resolved satellite structures of Y resonance appear in these compounds. This shows that the Y hyperfine field is mainly due to the magnetic nearest neighbor atoms. The magnetic moment of T atoms is estimated by two methods: (i) the contribution of T atoms to the hyperfine field is proportional to the magnetic moments of Fe and T atoms and (ii) the well known empirical relation between the hyperfine field and the mean magnetic moment of alloys is used. These results are in good agreement with those in dilute T-Fe alloys except for T=Mn. The intensity ratio of satellite peaks is discussed based upon a statistical distribution of Fe and T atoms. (author)

  15. Experimental Constraints on Polarizability Corrections to Hydrogen Hyperfine Structure

    International Nuclear Information System (INIS)

    Nazaryan, Vahagn; Carlson, Carl E.; Griffioen, Keith A.

    2006-01-01

    We present a state-of-the-art evaluation of the polarizability corrections--the inelastic nucleon corrections--to the hydrogen ground-state hyperfine splitting using analytic fits to the most recent data. We find a value Δ pol =1.3±0.3 ppm. This is 1-2 ppm smaller than the value of Δ pol deduced using hyperfine splitting data and elastic nucleon corrections obtained from modern form factor fits

  16. Proceedings of the 2nd KUR symposium on hyperfine interactions

    International Nuclear Information System (INIS)

    Mekata, M.; Minamisono, T.; Kawase, Y.

    1991-10-01

    Hyperfine interactions between a nuclear spin and an electronic spin discovered from hyperfine splitting in atomic optical spectra have been utilized not only for the determination of nuclear parameters in nuclear physics but also for novel experimental techniques in many fields such as solid state physics, chemistry, biology, mineralogy and for diagnostic methods in medical science. Experimental techniques based on hyperfine interactions yield information about microscopic states of matter so that they are important in material science. Probes for material research using hyperfine interactions have been nuclei in the ground state and radioactive isotopes prepared with nuclear reactors or particle accelerators. But utilization of muons generated from accelerators is recently growing. Such wide spread application of hyperfine interaction techniques gives rise to some difficulty in collaboration among various research fields. In these circumstances, the present workshop was planned after four years since the last KUR symposium on the same subject. This report summarizes the contributions to the workshop in order to be available for the studies of hyperfine interactions. (J.P.N.)

  17. Hyperfine fields for B and N in nickel

    Energy Technology Data Exchange (ETDEWEB)

    Hamagaki, H; Nakai, K [Tokyo Univ. (Japan). Faculty of Science; Nojiri, Y; Tanihata, I; Sugimoto, K [Osaka Univ., Toyonaka (Japan). Faculty of Science

    1976-11-01

    Hyperfine fields for non-magnetic impurity atoms of /sup 12/B and /sup 12/N in nickel have been investigated using a nuclear resonance method involving ..beta.. decay. The temperature dependence of the hyperfine fields and nuclear spin lattice relaxation time were also studied for /sup 12/B in Ni. Resonances were observed for recoil nuclei produced in the reactions /sup 11/B(d,p)/sup 12/B or /sup 10/B(/sup 3/He,n)/sup 12/N, implanted in polycrystalline Ni foils. A small correction to the Lorentz field was made because of a Co impurity in the Ni foils used. The sign of the hyperfine field was negative for B in Ni and positive for N. This result is in qualitative agreement with hyperfine field systematics for such impurities. Spin lattice relaxation time was determined from the time spectra of the ..beta..-decay asymmetry. Hyperfine fields measured in the given temperature range deviated significantly from the magnetization curve of Ni. At low temperatures spin lattice was long in comparison with /sup 12/B half life (11 ms), but became shorter around Curie temperature Tsub(c) (631 K), increasing again above this temperature. This is due to slowing down of spin fluctuations at a critical point of the ferromagnetic-paramagnetic phase transition.

  18. Hyperfine structure of S-states of muonic deuterium

    Directory of Open Access Journals (Sweden)

    Alexey P. Martynenko

    2015-09-01

    Full Text Available On the basis of quasipotential method in quantum electrodynamics we calculate corrections of order $\\alpha^5$ and $\\alpha^6$ to hyperfine structure of $S$-wave energy levels of muonic deuterium. Relativistic corrections, effects of vacuum polarization in first, second and third orders of perturbation theory, nuclear structure and recoil corrections are taken into account. The obtained numerical values of hyperfine splitting $\\Delta E^{hfs}(1S=50.2814$ meV ($1S$ state and $\\Delta E^{hfs}(2S=6.2804$ meV ($2S$ state represent reliable estimate for a comparison with forthcoming experimental data of CREMA collaboration. The hyperfine structure interval $\\Delta_{12}=8\\Delta E^{hfs}(2S- \\Delta E^{hfs}(1S=-0.0379$ meV can be used for precision check of quantum electrodynamics prediction for muonic deuterium.

  19. Fe dimers: a theoretical study of the hyperfine interactions

    International Nuclear Information System (INIS)

    Guenzburger, D.J.R.; Saitovitch, E.M.B.

    1981-01-01

    The electronic structures of diatomic molecules Fe 2 and FeM, where M = Mn, Co, Ni and Cu, are investigated by molecular orbitals calculations using a discrete variational method and a local approximation for the exchange interaction. The one-electron wave functions obtained are used to calculate electric field gradients, electronic charge and spin densities at the Fe nucleus and spin-dipolar hyperfine fields, which are related to measured hyperfine parameters reported from experiments in solid inert-gas matrices. Molecular orbitals energy schemes and population analysis are presented. These and other aspects of the electronic structure of the FeM molecules are used in a qualitative interpretation of the hyperfine data; in some cases, are given suggestions for the ground-state configuration. (Author) [pt

  20. Hyperfine-mediated static polarizabilities of monovalent atoms and ions

    International Nuclear Information System (INIS)

    Dzuba, V. A.; Flambaum, V. V.; Beloy, K.; Derevianko, A.

    2010-01-01

    We apply relativistic many-body methods to compute static differential polarizabilities for transitions inside the ground-state hyperfine manifolds of monovalent atoms and ions. Knowledge of this transition polarizability is required in a number of high-precision experiments, such as microwave atomic clocks and searches for CP-violating permanent electric dipole moments. While the traditional polarizability arises in the second order of interaction with the externally applied electric field, the differential polarizability involves an additional contribution from the hyperfine interaction of atomic electrons with nuclear moments. We derive formulas for the scalar and tensor polarizabilities including contributions from magnetic dipole and electric quadrupole hyperfine interactions. Numerical results are presented for Al, Rb, Cs, Yb + , Hg + , and Fr.

  1. Determining hyperfine transitions with electromagnetically induced transparency and optical pumping

    International Nuclear Information System (INIS)

    Lee Yi-Chi; Tsai Chin-Chun; Huang Chen-Han; Chui Hsiang-Chen; Chang Yung-Yung

    2011-01-01

    A system is designed to observe the phenomena of electromagnetically induced transparency and optical pumping in cesium D 1 and D 2 lines at room temperature. When a pump laser is frequency-locked on the top of a hyperfine transition and the frequency of the probe laser scans over another hyperfine transition, a spectrum of V-type electromagnetically induced transparency or an optical pumping can be observed depending on whether the two lasers share a common ground state. Therefore, these results can be used to identify the unknown hyperfine transitions of the D 1 line transitions. For educational purposes, this system is helpful for understanding the electromagnetically induced transparency and the optical pumping

  2. Study of hyperfine anomaly in 9,11Be isotopes

    International Nuclear Information System (INIS)

    Parfenova, Y.; Leclercq-Willain

    2005-01-01

    The study of the hyperfine anomaly of neutron rich nuclei, in particular, neutron halo nuclei, can give a very specific and unique way to measure their neutron distribution and confirm a halo structure. The hyperfine structure anomaly in Be + ions is calculated with a realistic electronic wave function, obtained as a solution of the Dirac equation. In the calculations, the Coulomb potential modified by the charge distribution of the clustered nucleus and three electrons in the configuration 1s 2 2s is used. The nuclear wave function for the 11 Be nucleus is obtained in the core + nucleon model, and that for the 9 Be nucleus is calculated in the three-cluster (α+α + n) model. The aim of this study is to test whether the hyperfine structure anomaly reflects an extended spatial structure of '1 1 Be. The results of the calculations are listed. ε BW is the hyperfine anomaly in the Bohr-Weisskopf effect and δ is the charge structure correction, μ is the calculated magnetic moment, and μ exp is the experimental value of the magnetic moment, Q and Q exp are the calculated and measured values of the quadrupole moment. The results for 9 Be are obtained with two different three-body wave functions (WF1 and WF2) showing the sensitivity of the calculations to the input parameters. The value of ε BW is sensitive to the weights of the states in the nuclear ground state wave function. The total hyperfine anomaly value εε BW +δ in 11 Be differs from that in 9 Be by 25%. This gives a measure of the accuracy of the hyperfine anomaly measurements needed to study the neutron distribution in the Be isotopes. (authors)

  3. Coherent control of two individual electron spins and influence of hyperfine coupling in a double quantum dot

    International Nuclear Information System (INIS)

    Tarucha, S; Obata, T; Pioro-Ladriere, M; Brunner, R; Shin, Y-S; Kubo, T; Tokura, Y

    2011-01-01

    Electric dipole spin resonance of two individual electrons and the influence of hyperfine coupling on the spin resonance are studied for a double quantum dot equipped with a micro-magnet. The spin resonance occurs by oscillating the electron in each dot at microwave (MW) frequencies in the presence of a micro-magnet induced stray field. The observed continuous wave (CW) and time-resolved spin resonances are consistent with calculations in which the MW induced AC electric field and micro-magnet induced stray field are taken into account. The influence of hyperfine coupling causes an increase and broadening of the respective CW spin resonance peaks through dynamical nuclear polarization when sweeping up the magnetic field. This behaviour appears stronger for the larger of the two spin resonance peaks and in general becomes more pronounced as the MW power increases, both reflecting that the electron-nuclei interaction is more efficient for the stronger spin resonance. In addition the hyperfine coupling effect only becomes pronounced when the MW induced AC magnetic field exceeds the fluctuating nuclear field.

  4. Hyperfine interactions in iron substituted high-Tc superconducting oxides

    International Nuclear Information System (INIS)

    Ellis, D.E.; Saitovitch, E.B.; Lam, D.J.

    1991-01-01

    The hyperfine interactions in Fe substituted copper oxide ternary and quaternary compounds with perovskite-related structures are studied, using the Local Density theory in an embedded cluster approach. The self-consistent electronic structure is examined for Cu and Fe sites in a number of plausible local geometries representative of La 2 Cu O 4 , YBa 2 Cu 3 O 7-δ and related materials. Moessbauer isomer shifts, electric fields gradients, magnetic moments, and contact hyperfine fields are presented for comparison with experiment and discussed in light of lattice structure data. (author)

  5. Measurement of Nitrogen Hyperfine Structure on the 53 CM (562 MHz) Butyronitrile Line

    Science.gov (United States)

    Dewberry, Christopher T.; Grubbs, Garry S. Grubbs, II; Raphelt, Andrew; Cooke, Stephen A.

    2009-06-01

    Recent improvements to our cavity-based Fourier transform radiofrequency spectrometer will be presented. Amongst other improvements use of Miteq amp, model AMF-6F-00100400-10-10P (0.1 GHz to 4 GHz, 65 dB gain minimum, 1 dB noise figure maximum) together with shielding from an improved Faraday cage have significantly helped us in this regard. Electromagnetic fields within our near-spherical cavity have been modeled and results will be presented. We have been able to easily resolve the nitrogen hyperfine structure on the ^aQ_{0,-1} transition 1_{1,0} ← 1_{1,1} located at 562 MHz. This result will be discussed.

  6. Mössbauer studies of hyperfine fields in disordered Fe CrAl

    Indian Academy of Sciences (India)

    magnetic hyperfine field, the average hyperfine field follows the ´T Tcµ3 2 law. The paramagnetic part of the hyperfine field is explained in terms of the clustering of Cr ... These alloys offer excellent systems for studying magnetic interactions. Large volumes of studies have been devoted to Heusler alloys bearing the general ...

  7. Fine and hyperfine collisional excitation of C6H by He

    Science.gov (United States)

    Walker, Kyle M.; Lique, François; Dawes, Richard

    2018-01-01

    Hydrogenated carbon chains have been detected in interstellar and circumstellar media and accurate modelling of their abundances requires collisional excitation rate coefficients with the most abundant species. Among them, the C6H molecule is one of the most abundant towards many lines of sight. Hence, we determined fine and hyperfine-resolved rate coefficients for the excitation of C6H(X2Π) due to collisions with He. We present the first interaction potential energy surface for the C6H-He system, obtained from highly correlated ab initio calculations and characterized by a large anisotropy due to the length of the molecule. We performed dynamical calculations for transitions among the first fine structure levels (up to J = 30.5) of both spin-orbit manifolds of C6H using the close-coupling method, and rate coefficients are determined for temperatures ranging from 5 to 100 K. The largest rate coefficients for even ΔJ transitions conserve parity, while parity-breaking rate coefficients are favoured for odd ΔJ. Spin-orbit changing rate coefficients are several orders of magnitude lower than transitions within a single manifold. State-to-state hyperfine-resolved cross-sections for the first levels (up to J = 13.5) in the Ω = 3/2 spin-orbit manifold are deduced using recoupling techniques. Rate coefficients are obtained and the propensity rule ΔJ = ΔF is seen. These new data will help determine the abundance of C6H in astrophysical environments such as cold dense molecular clouds, star-forming regions and circumstellar envelopes, and will help in the interpretation of the puzzling C6H-/C6H abundance ratios deduced from observations.

  8. Isotope effects in interstellar molecules by chemical hyperfine interaction

    International Nuclear Information System (INIS)

    Haberkorn, R.; Michel-Beyerle, M.E.

    1977-01-01

    If free radicals recombine on grain surfaces, not only the different masses of isotopes but also their differing nuclear spin moments (e.g. 12 C/ 13 C, 14 N/ 15 N, 17 O/ 18 O) may imply variations in the recombination probability due to hyperfine interaction. This mechanism has not been accounted for so far. (orig.) [de

  9. Observation of Hyperfine Transitions in Trapped Ground-State Antihydrogen

    CERN Document Server

    Olin, Arthur

    2015-01-01

    This paper discusses the first observation of stimulated magnetic resonance transitions between the hyperfine levels of trapped ground state atomic antihydrogen, confirming its presence in the ALPHA apparatus. Our observations show that these transitions are consistent with the values in hydrogen to within 4~parts~in~$10^3$. Simulations of the trapped antiatoms in a microwave field are consistent with our measurements.

  10. Hyperfine field distribution of Fe83B17 glassy metal

    International Nuclear Information System (INIS)

    Miglierini, M.; Sitek, J.

    1990-01-01

    Convolutions of Gaussian and Lorentzian lines are proposed to fit the Moessbauer spectrum of Fe 83 B 17 metallic glass. The hyperfine field distribution is constructed from three Gaussian lines corresponding to the individual line pairs. (author). 1 fig., 7 refs

  11. Split and Compensated Hyperfine Fields in Magnetic Metal Clusters

    International Nuclear Information System (INIS)

    Nakamura, H.; Chudo, H.; Shiga, M.; Kohara, T.

    2004-01-01

    As prominent characteristics of magnetic metal cluster found in vanadium sulfides, we point out marked separation and compensation of the hyperfine field at the nuclear site; these are in somewhat discordance with the common sense for 3d transition-metal magnets, where the on-site isotropic field, scaling the ordered moment magnitude, is dominant.

  12. Kinetic models in spin chemistry. 1. The hyperfine interaction

    DEFF Research Database (Denmark)

    Mojaza, M.; Pedersen, J. B.

    2012-01-01

    Kinetic models for quantum systems are quite popular due to their simplicity, although they are difficult to justify. We show that the transformation from quantum to kinetic description can be done exactly for the hyperfine interaction of one nuclei with arbitrary spin; more spins are described w...... induced enhancement of the reaction yield. (C) 2012 Elsevier B.V. All rights reserved....

  13. Muon zero point motion and the hyperfine field in nickel

    International Nuclear Information System (INIS)

    Elzain, M.E.

    1984-09-01

    It is argued that the effect of zero point motion of muons in Ni is to induce local vibrations of the neighbouring Ni atoms. This local vibration reduces the Hubbard correlation and hence decreases the net spin per atom. This acts back to reduce the hyperfine field at the muon site. (author)

  14. Temperature dependence of the μ+ hyperfine field in ferromagnets

    International Nuclear Information System (INIS)

    Nagamine, K.; Nirhida, N.; Hayano, R.S.; Yamazaki, T.; Brewes, J.H.; Fleming, D.G.

    1977-01-01

    The temperature dependences of the μ + hyperfine fields in Ni and in Fe were found to deviate from that of the saturation magnetization in opposite senses. Difference in the screening mechanism of conduction electrons around the μ + is considered, among several possible explanations. (Auth.)

  15. Pure nuclear reflexes and combined hyperfine interactions in YIG

    Energy Technology Data Exchange (ETDEWEB)

    Winkler, H; Eisberg, R; Alp, E; Rueffer, R; Gerdau, E; Lauer, S; Trautwein, A X; Grodzicki, M; Vera, A

    1983-01-01

    Moessbauer spectra of oriented YIG single crystals were taken and the numerical analysis using the transmission integral yielded a consistent set of hyperfine interaction parameters. They are in good agreement with theoretical values obtained by MO-calculations which included clusters up to 62 ions. Finally pure nuclear reflexes are predicted for single crystals and two theoretical spectra are given.

  16. Observation of hyperfine transitions in trapped ground-state antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Collaboration: A. Olin for the ALPHA Collaboration

    2015-08-15

    This paper discusses the first observation of stimulated magnetic resonance transitions between the hyperfine levels of trapped ground state atomic antihydrogen, confirming its presence in the ALPHA apparatus. Our observations show that these transitions are consistent with the values in hydrogen to within 4 parts in 10{sup 3}. Simulations of the trapped antiatoms in a microwave field are consistent with our measurements.

  17. Laser and radiofrequency spectroscopy of the 4d55s5Dsub(0,1,2,3,4) and 4d45s5p5Psub(1,2,3) states in Mo I: Hyperfine structure and isotope shifts

    International Nuclear Information System (INIS)

    Olsson, T.; Fraenkel, L.; Lindgren, I.; Nyberg, A.; Robertsson, L.; Rosen, A.

    1986-01-01

    A series of experiments has been performed to determine the hyperfine structure in the metastable 4d 5 5s 5 Dsub(1,2,3,4) states of Mo I by means of the laser radiofrequency double-resonance technique. Furthermore, hyperfine structure splittings and isotope shifts in seven optical transitions connecting the 4d 5 5s 5 Dsub(0,1,2,3,4) and the 4d 4 5s5p 5 Psub(1,2,3) states were resolved with the high-resolution laser spectroscopy technique. Radial hyperfine structure parameters are deduced for the effective operator within the 5 D states using the configurations 4d 4 5s 2 , 4d 5 5s and 4d 6 as a model space. The isotope shifts are also discussed, utilizing an effective operator, with particular emphasis on the J dependence. (orig.)

  18. Hyperfine interaction studies with pulsed heavy-ion beams

    International Nuclear Information System (INIS)

    Raghavan, P.

    1985-01-01

    Heavy-ion reactions using pulsed beams have had a strong impact on the study of hyperfine interactions. Unique advantages offered by this technique have considerably extended the scope, detail and systematic range of its applications beyond that possible with radioactivity or light-ion reaction. This survey will cover a brief description of the methodological aspects of the field and recent applications to selected problems in nuclear and solid state physiscs illustrating its role. These include measurements of nuclear magnetic and electric quadrupole moments of high spin isomers, measurements of hyperfine magnetic fields at impurities in 3d and rare-earths ferromagnetic hosts, studies of paramagnetic systems, especially those exhibiting valence instabilities, and investigations of electric field gradients of impurities in noncubic metals. Future prospects of this technique will be briefly assessed. (orig.)

  19. Hyperfine spectroscopic study of Laves phase HfFe2

    International Nuclear Information System (INIS)

    Belosevic-Cavor, J.; Novakovic, N.; Cekic, B.; Ivanovic, N.; Manasijevic, M.

    2004-01-01

    Hyperfine fields in HfFe 2 were measured at 181 Ta probe using the time-differential perturbed angular correlation method (TDPAC) in the temperature range 78-1200 K. Analysis of the spectra revealed two interactions with hyperfine fields of 13.82(7) T and 8.0(2) T, at 293 K. First is ascribed to the interaction at the 8a position in the cubic C15 structure. The second can be assigned to a minor amount of hexagonal C14 phase, or to an irregular position of the probe in the C15 lattice. Results of calculations using LAPW-WIEN97 are in a good agreement with experiment

  20. Hyperfine relaxation of an optically pumped cesium vapor

    International Nuclear Information System (INIS)

    Tornos, J.; Amare, J.C.

    1986-01-01

    The relaxation of hyperfine orientation indirectly induced by optical pumping with a σ-polarized D 1 -light in a cesium vapor in the presence of Ar is experimentally studied. The detection technique ensures the absence of quadrupole relaxation contributions in the relaxation signals. The results from the dependences of the hyperfine relaxation rate on the temperature and argon pressure are: diffusion coefficient of Cs in Ar, D 0 = 0.101 +- 0.010 cm 2 s -1 at 0 0 C and 760 Torr; relaxation cross section by Cs-Ar collisions, σ/sub c/ = (104 +- 5) x 10 -23 cm 2 ; relaxation cross section by Cs-Cs (spin exchange) collisions, σ/sub e//sub x/ = (1.63 +- 0.13) x 10 -14 cm 2

  1. Calculation of hyperfine structure constants of small molecules using

    Indian Academy of Sciences (India)

    The Z-vector method in the relativistic coupled-cluster framework is employed to calculate the parallel and perpendicular components of the magnetic hyperfine structure constant of a few small alkaline earth hydrides (BeH, MgH, and CaH) and fluorides (MgF and CaF). We have compared our Z-vector results with the values ...

  2. Muonium hyperfine structure : An analytical solution to perturbative calculations

    International Nuclear Information System (INIS)

    Wotzasek, C.J.; Gregorio, M.A.; Reinecke, S.

    1982-01-01

    The purely coulombian contribution to the terms of order E sub(F) (α 2 m sub(e)/m sub(μ))ln α - 1 of the hyperfine splitting of muonium is computed. Results agree with those of other authors. The goal of the work was twofold: first, to confirm that contribution; second, and perhaps more important, to check the analytic solution of the relativistic coulombian problem of the Bethe-Salpeter equation with instantaneous kernel. (Author) [pt

  3. Dephasing and hyperfine interaction in carbon nanotubes double quantum dots

    DEFF Research Database (Denmark)

    Reynoso, Andres Alejandro; Flensberg, Karsten

    2012-01-01

    We study theoretically the return probability experiment, which is used to measure the dephasing time T-2*, in a double quantum dot (DQD) in semiconducting carbon nanotubes with spin-orbit coupling and disorder-induced valley mixing. Dephasing is due to hyperfine interaction with the spins of the C...... with these for DQDs in clean nanotubes, whereas the disorder effect is always relevant when the magnetic field is perpendicular to the nanotube axis....

  4. Hyperfine field at 111Cd nuclei in Heusler alloys

    International Nuclear Information System (INIS)

    Styczen, B.; Walus, W.; Szytula, A.

    1978-01-01

    The magnitudes and signs of the hyperfine fields in the ordered ferromagnetic Heusler Alloys X 2 MnZ and XMnZ (where X is Cu, Ni, Pd while Z is In, Sn and Sb) have been investigated at liquid nitrogen and room temperatures using TDPAC method. Their signs have been found to be negative. The results have been compared with the predictions of Caroll-Blandin and Cambell-Blandin models and RKKY theory. (Auth)

  5. Weak-interaction contributions to hyperfine splitting and Lamb shift

    International Nuclear Information System (INIS)

    Eides, M.I.

    1996-01-01

    Weak-interaction contributions to hyperfine splitting and the Lamb shift in hydrogen and muonium are discussed. The problem of sign of the weak-interaction contribution to HFS is clarified, and simple physical arguments that make this sign evident are presented. It is shown that weak-interaction contributions to HFS in hydrogen and muonium have opposite signs. A weak-interaction contribution to the Lamb shift is obtained. copyright 1996 The American Physical Society

  6. α-spectra hyperfine structure resolution by silicon planar detectors

    International Nuclear Information System (INIS)

    Eremin, V.K.; Verbitskaya, E.M.; Strokan, N.B.; Sukhanov, V.L.; Malyarenko, A.M.

    1986-01-01

    The lines with 13 keV step from the main one is α-spectra of nuclei with an odd number of nucleons take place. Silicon planar detectors n-Si with the operation surface of 10 mm 2 are developed for resolution of this hyperfine structure. The mechanism of losses in detectors for short-range-path particles is analyzed. The results of measurements from detectors with 10 keV resolution are presented

  7. cap alpha. -spectra hyperfine structure resolution by silicon planar detectors

    Energy Technology Data Exchange (ETDEWEB)

    Eremin, V K; Verbitskaya, E M; Strokan, N B; Sukhanov, V L; Malyarenko, A M

    1986-10-01

    The lines with 13 keV step from the main one is ..cap alpha..-spectra of nuclei with an odd number of nucleons take place. Silicon planar detectors n-Si with the operation surface of 10 mm/sup 2/ are developed for resolution of this hyperfine structure. The mechanism of losses in detectors for short-range-path particles is analyzed. The results of measurements from detectors with 10 keV resolution are presented.

  8. Muon contact hyperfine field in metals: A DFT calculation

    Science.gov (United States)

    Onuorah, Ifeanyi John; Bonfà, Pietro; De Renzi, Roberto

    2018-05-01

    In positive muon spin rotation and relaxation spectroscopy it is becoming customary to take advantage of density functional theory (DFT) based computational methods to aid the experimental data analysis. DFT-aided muon site determination is especially useful for measurements performed in magnetic materials, where large contact hyperfine interactions may arise. Here we present a systematic analysis of the accuracy of the ab initio estimation of muon's hyperfine contact field on elemental transition metals, performing state-of-the-art spin-polarized plane-wave DFT and using the projector-augmented pseudopotential approach, which allows one to include the core state effects due to the spin ordering. We further validate this method in not-so-simple, noncentrosymmetric metallic compounds, presently of topical interest for their spiral magnetic structure giving rise to skyrmion phases, such as MnSi and MnGe. The calculated hyperfine fields agree with experimental values in all cases, provided the spontaneous spin magnetization of the metal is well reproduced within the approach. To overcome the known limits of the conventional mean-field approximation of DFT on itinerant magnets, we adopt the so-called reduced Stoner theory [L. Ortenzi et al., Phys. Rev. B 86, 064437 (2012), 10.1103/PhysRevB.86.064437]. We establish the accuracy of the estimated muon contact field in metallic compounds with DFT and our results show improved agreement with experiments compared to those of earlier publications.

  9. The hyperfine properties of iron-gallium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Elzain, M., E-mail: elzain@squ.edu.om; Gismelseed, A.; Al-Rawas, A.; Yousif, A.; Widatallah, H.; Al-Azri, Maya [Sultan Qaboos University, Department of Physics (Oman); Al-Barwani, M. [NYU Abu Dhabi (United Arab Emirates)

    2016-12-15

    The hyperfine properties at Fe site in iron-gallium alloy are calculated using the full-potential linear-augmented-plane-waves method. We have calculated the Fermi contact field (B{sub hf}) and isomer shift (δ) at the Fe site versus the number of neighbouring Ga atoms. We found that B{sub hf} decrease whereas δ increases with increasing number of neighbouring G atom. In addition we have calculated the hyperfine properties of FeGa system with DO{sub 3} structure, where various distributions of 4 the Ga atoms in the conventional unit cell are considered (including the regular DO{sub 3} structure). We found that the DO{sub 3} structure has the lowest energy as compared to the other configurations. The two distinct A and D sites of the ordered DO{sub 3} conventional unit cell have two distinct values for B{sub hf} and δ. On changing the atomic arrangement of the Ga atoms within the conventional unit cell, the configuration of the A site is maintained whereas that of the D site becomes imperfect. The contact magnetic hyperfine fields of the D-like sites in the imperfect structures are lower than that of the DO{sub 3}D site.

  10. Hyperfine Structure Measurements of Antiprotonic $^3$He using Microwave Spectroscopy

    CERN Document Server

    Friedreich, Susanne

    The goal of this project was to measure the hyperfine structure of $\\overline{\\text{p}}^3$He$^+$ using the technique of laser-microwave-laser spectroscopy. Antiprotonic helium ($\\overline{\\text{p}}$He$^+$) is a neutral exotic atom, consisting of a helium nucleus, an electron and an antiproton. The interactions of the angular momenta of its constituents cause a hyperfine splitting ({HFS}) within the energy states of this new atom. The 3\\% of formed antiprotonic helium atoms which remain in a metastable, radiative decay-dominated state have a lifetime of about 1-3~$\\mu$s. This time window is used to do spectroscopic studies. The hyperfine structure of $\\overline{\\text{p}}^4$He$^+$ was already extensively investigated before. From these measurements the spin magnetic moment of the antiproton can be determined. A comparison of the result to the proton magnetic moment provides a test of {CPT} invariance. Due to its higher complexity the new exotic three-body system of $\\overline{\\text{p}}^3$He$^+$ is a cross-check...

  11. Vibration dependence of the tensor spin-spin and scalar spin-spin hyperfine interactions by precision measurement of hyperfine structures of 127I2 near 532 nm

    International Nuclear Information System (INIS)

    Hong Fenglei; Zhang Yun; Ishikawa, Jun; Onae, Atsushi; Matsumoto, Hirokazu

    2002-01-01

    Hyperfine structures of the R(87)33-0, R(145)37-0, and P(132)36-0 transitions of molecular iodine near 532 nm are measured by observing the heterodyne beat-note signal of two I 2 -stabilized lasers, whose frequencies are bridged by an optical frequency comb generator. The measured hyperfine splittings are fit to a four-term Hamiltonian, which includes the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions, with an accuracy of ∼720 Hz. High-accurate hyperfine constants are obtained from this fit. Vibration dependences of the tensor spin-spin and scalar spin-spin hyperfine constants are determined for molecular iodine, for the first time to our knowledge. The observed hyperfine transitions are good optical frequency references in the 532-nm region

  12. Hyperfine structure of nine levels in two configurations of 93Nb. Pt. 1

    International Nuclear Information System (INIS)

    Buettgenbach, S.; Dicke, R.; Gebauer, H.; Herschel, M.; Meisel, G.

    1975-01-01

    The hyperfine structure of the multiplets 4d 4 5s 6 D and 4d 3 5s 24 F of 93 Nb has been studied by the atomic-beam magnetic-resonance method. After applying corrections due to effects of off-diagonal hyperfine and Zeeman interactions the hyperfine interaction constants A and B and the electron g factors gsub(J) are determined for all nine levels of the two multiplets. (orig.) [de

  13. Manipulating ultracold polar molecules with microwave radiation: The influence of hyperfine structure

    International Nuclear Information System (INIS)

    Aldegunde, J.; Hutson, Jeremy M.; Ran Hong

    2009-01-01

    We calculate the microwave spectra of ultracold 40 K 87 Rb alkali-metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between different hyperfine states, but only because of the presence of nuclear quadrupole interactions. Hyperfine splittings may also complicate the use of ultracold molecules for quantum computing. The spectrum of molecules oriented in electric fields may be simplified dramatically by applying a simultaneous magnetic field.

  14. Nonrelativistic hyperfine splitting in muonic helium by adiabatic perturbation theory

    International Nuclear Information System (INIS)

    Drachman, R.J.

    1980-01-01

    Huang and Hughes have recently discussed the hyperfine splitting Δν of muonic helium (α ++ μ - e - ) using a variational approach. In this paper, the Born-Oppenheimer approximation is used to simplify the evaluation of Δν in the nonrelativistic limit. The first-order perturbed wave function of the electron is obtained in closed form by slightly modifying the method used by Dalgarno and Lynn. The result Δν=4450 MHz, is quite close to the published result of Huang and Hughes 4455.2 +- 1 MHz, which required a very large Hylleraas expansion as well as considerable extrapolation

  15. Nuclear hyperfine interactions and chemical bonding in high TC superconductors

    International Nuclear Information System (INIS)

    Danon, J.

    1987-01-01

    Nuclear quadrupole resonances of Cu 63 and Fe 57 Moessbauer spectroscopy of the high temperature superconductor YBa 2 Cu 3 O 7-γ e described together with synchrotron radiation studies of the copper oxidation states in this material. The Moessbauer spectra of 57 Fe in the two distinct crystallographic sites of the Cu atoms in YBa 2 Cu 3 O 7-γ are very similar from the quadrupole coupling point of view although exhibiting markedly different values for the isomer shift. The role of oxygen vacancies in the hyperfine interactions is discussed. (author) [pt

  16. Hyperfine magnetic fields at 111Cd in Heusler alloys

    International Nuclear Information System (INIS)

    Styczen, B.; Szytula, A.; Walus, W.

    1977-01-01

    The magnitudes and signs of the hyperfine magnetic field on 111 Cd nuclei at Z sites in the ordered ferromagnetic Heusler alloys X 2 MnZ and XMnZ (where X is Cu, Ni, Pd while Z is In, Sn and Sb) have been investigated at liquid nitrogen and room temperatures using TDPAC method. Their signs have been found to be negative. The results have been compared with the predictions of Caroli-Blandin and Campbell-Blandin models and RKKY theory. (author)

  17. Hyperfine interactions: the past, the present and the future

    Energy Technology Data Exchange (ETDEWEB)

    Langouche, Guido, E-mail: guido.langouche@kuleuven.be [Katholieke Universiteit Leuven, Physics Department, Institute of Nuclear and Radiation Physics (Belgium)

    2008-01-15

    Five major hyperfine interaction techniques, detected by nuclear radiation, originated in the short time span between 1950 and 1965. The coincidence with the demographic expansion, especially in Europe, of university education led to the creation of many new research laboratories applying these promising techniques in solid state physics, chemistry and biology. Since the turn of century many of the early pioneers are going into retirement, leading to a decline in activities in Europe, compensated in some degree by an increase in activities outside Europe. The organisation of the 2007 HI/NQI-conference was impeccable and took place in a superb setting. Thanks to all those involved in its organization.

  18. Hyperfine interactions in the cubic semiconductor CdO

    International Nuclear Information System (INIS)

    Desimoni, J.; Bibiloni, A.G.; Massolo, C.P.; Renteria, M.

    1990-01-01

    The time-differential perturbed angular correlation technique has been applied using 111 In probes, which decay through electron capture to 111 Cd, to study the hyperfine interaction in cubic cadmium oxide, in the temperature range RT--740 degree C (RT denotes room temperature). The main fraction of probes are located in perfect-lattice sites, with null electric field gradient in agreement with crystalline-structure considerations. Around 25% of the total intensity shows an electric-field-gradient distribution around V zz =0. This corresponds to probes located in sites perturbed by the vicinity of oxygen vacancies in the lattice. The temperature-independent behavior of the measured hyperfine parameters is discussed in terms of conductivity and band-structure properties of the semiconductor. No time-dependent interaction arising from nuclear electron-capture aftereffects are seen in this experiment. This is in agreement with a previously reported model of aftereffect processes which states that only holes trapped in impurity levels inside the band gap of the semiconductor can give rise to detectable fluctuating interactions

  19. Hyperfine interactions in the cubic semiconductor CdO

    Energy Technology Data Exchange (ETDEWEB)

    Desimoni, J.; Bibiloni, A.G.; Massolo, C.P.; Renteria, M. (Departamento de Fisica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Casilla de Correo No. 67, 1900 La Plata, Argentina (AR))

    1990-01-15

    The time-differential perturbed angular correlation technique has been applied using {sup 111}In probes, which decay through electron capture to {sup 111}Cd, to study the hyperfine interaction in cubic cadmium oxide, in the temperature range RT--740 {degree}C (RT denotes room temperature). The main fraction of probes are located in perfect-lattice sites, with null electric field gradient in agreement with crystalline-structure considerations. Around 25% of the total intensity shows an electric-field-gradient distribution around {ital V}{sub {ital zz}}=0. This corresponds to probes located in sites perturbed by the vicinity of oxygen vacancies in the lattice. The temperature-independent behavior of the measured hyperfine parameters is discussed in terms of conductivity and band-structure properties of the semiconductor. No time-dependent interaction arising from nuclear electron-capture aftereffects are seen in this experiment. This is in agreement with a previously reported model of aftereffect processes which states that only holes trapped in impurity levels inside the band gap of the semiconductor can give rise to detectable fluctuating interactions.

  20. Hyperfine interactions of /sup 12/B implanted in ferromagnetic nickel

    Energy Technology Data Exchange (ETDEWEB)

    Hamagaki, H; Nojiri, Y; Sugimoto, K [Osaka Univ., Toyonaka (Japan). Dept. of Physics; Nakai, K

    1979-12-01

    Temperature dependences of hyperfine interactions of /sup 12/B implanted in Ni were investigated in the temperature range of 6 K - 730 K by the NMR method with use of polarized /sup 12/B produced in a nuclear reaction and the asymmetric ..beta.. decay. Two kinds of hyperfine fields with different signs were observed (B sub(hf)sup(+) = +4.161 +- 0.022 kG and B sub(hf)sup(-) = -1.611 +- 0.021 kG at 6 K), which indicated that the implanted /sup 12/B were trapped in two different sites (S/sup +/ and S/sup -/, respectively). The spin-lattice relaxation times T/sub 1/ and the population rates at the two sites were studied. Near the Curie temperature, an effect of critical slowing-down of the spin-spin correlation was observed as steep variation of T/sub 1/. The behavior of local field around T sub(C) was also studied by varying the external field. Results of these experiments near T sub(C) indicate itinerant nature of the electron-spin structure in nickel.

  1. Complete analytic results for radiative-recoil corrections to ground-state muonium hyperfine splitting

    International Nuclear Information System (INIS)

    Karshenboim, S.G.; Shelyuto, V.A.; Eides, M.E.

    1988-01-01

    Analytic expressions are obtained for radiative corrections to the hyperfine splitting related to the muon line. The corresponding contribution amounts to (Z 2 a) (Za) (m/M) (9/2 ζ(3) - 3π 2 ln 2 + 39/8) in units of the Fermi hyperfine splitting energy. A complete analytic result for all radiative-recoil corrections is also presented

  2. Hyperfine spectra of the radioactive isotopes 81Kr and 85Kr

    International Nuclear Information System (INIS)

    Cannon, B.D.

    1993-01-01

    Isotope shifts and hyperfine constants are reported for the radioactive isotopes 81 Kr and 85 Kr and the stable isotope 83 Kr. The previously unreported nuclear moments of 81 Kr were determined to be μ I =-0.909(4) nuclear magneton and Q=+0.630(13) b from the hyperfine constants. This work increases the number of transitions for which 85 Kr hyperfine constants and isotope shifts have been measured from 1 to 4. The hyperfine anomaly for krypton reported in the previous measurement of 85 Kr hyperfine constants [H. Gerhardt et al., Hyperfine Interact. 9, 175 (1981)] is not supported by this work. The isotope shifts and hyperfine constants of 83 Kr measured in this work are in excellent agreement with previous work. Saturation spectroscopy was used to study transitions from krypton's metastable 1s 5 state to the 2p 9 , 2p 7 , and 2p 6 states. In saturation spectra, different line shapes were observed for the even- and odd-mass krypton isotopes. This even- versus odd-line-mass shape difference can be explained using the large cross section that has been reported for collisional transfer of the 1s 5 state excitation between krypton atoms. Two-color two-photon laser-induced fluorescence was used to measure the hyperfine spectra of the 1s 5- 4d 4 ' transition using the 2p 9 state as the intermediate state. This technique proved to be more sensitive than saturation spectroscopy

  3. Comment on contact contributions to the magnetic hyperfine interaction of rare-earth impurities in iron

    International Nuclear Information System (INIS)

    Bernas, H.

    1977-01-01

    The influence of the strong d character of the Fe conduction band on the hyperfine interaction of dilute rare earth impurities is emphasized, and the contact contributions are estimated. Apparent inconsistencies between hyperfine field measurements for Eu and Gd in Fe are noted

  4. Coulomb artifacts and bottomonium hyperfine splitting in lattice NRQCD

    Energy Technology Data Exchange (ETDEWEB)

    Liu, T. [Department of Physics, University of Alberta,11455 Saskatchewan Drive, Edmonton, Alberta T6G 2J1 (Canada); Penin, A.A. [Department of Physics, University of Alberta,11455 Saskatchewan Drive, Edmonton, Alberta T6G 2J1 (Canada); Institut für Theoretische Teilchenphysik, Karlsruhe Institute of Technology,Wolfgang-Gaede-Strasse 1, 76128 Karlsruhe (Germany); Rayyan, A. [Department of Physics, University of Alberta,11455 Saskatchewan Drive, Edmonton, Alberta T6G 2J1 (Canada)

    2017-02-16

    We study the role of the lattice artifacts associated with the Coulomb binding effects in the analysis of the heavy quarkonium within lattice NRQCD. We find that a “naïve” perturbative matching generates spurious linear Coulomb artifacts, which result in a large systematic error in the lattice predictions for the heavy quarkonium spectrum. This effect is responsible, in particular, for the discrepancy between the recent determinations of the bottomonium hyperfine splitting in the radiatively improved lattice NRQCD (DOI: 10.1103/PhysRevD.92.054502; Arxiv:1309.5797). We show that the correct matching procedure which provides full control over discretization errors is based on the asymptotic expansion of the lattice theory about the continuum limit, which gives M{sub Υ(1S)}−M{sub η{sub b(1S)}}=52.9±5.5 MeV (DOI: 10.1103/PhysRevD.92.054502).

  5. Measurement and modeling of hyperfine parameters in ferroic materials

    CERN Document Server

    Gonçalves, João Nuno; Correia, J G

    This thesis presents the results of perturbed angular correlation (PAC) experiments , an experimental technique which measures the hyperfine interaction at probes (radioactive ions implanted in the materials to study), from which one infers local information on an atomic scale. Furthermore, abinitio calculations using density functional theory electronic obtain results that directly complement the experiments, and are also used for theoretical research. These methods were applied in two families of materials. The manganites, with the possible existence of magnetic, charge, orbital and ferroelectric orders, are of fundamental and technological interest. The experimental results are obtained in the alkaline-earth manganites (Ca, Ba, Sr), with special interest due to the structural variety of possible polymorphs. With probes of Cd and In the stability of the probe and its location in a wide temperature range is established and a comparison with calculations allows the physical interpretation of the results. Cal...

  6. Hyperfine Structure and Isotope Shifts in Dy II

    Directory of Open Access Journals (Sweden)

    Dylan F. Del Papa

    2017-01-01

    Full Text Available Using fast-ion-beam laser-fluorescence spectroscopy (FIBLAS, we have measured the hyperfine structure (hfs of 14 levels and an additional four transitions in Dy II and the isotope shifts (IS of 12 transitions in the wavelength range of 422–460 nm. These are the first precision measurements of this kind in Dy II. Along with hfs and IS, new undocumented transitions were discovered within 3 GHz of the targeted transitions. These atomic data are essential for astrophysical studies of chemical abundances, allowing correction for saturation and the effects of blended lines. Lanthanide abundances are important in diffusion modeling of stellar interiors, and in the mechanisms and history of nucleosynthesis in the universe. Hfs and IS also play an important role in the classification of energy levels, and provide a benchmark for theoretical atomic structure calculations.

  7. Improved Study of the Antiprotonic Helium Hyperfine Structure

    CERN Document Server

    Pask, T.; Dax, A.; Hayano, R.S.; Hori, M.; Horvath, D.; Juhasz, B.; Malbrunot, C.; Marton, J.; Ono, N.; Suzuki, K.; Zmeskal, J.; Widmann, E.

    2008-01-01

    We report the initial results from a systematic study of the hyperfine (HF) structure of antiprotonic helium (n,l) = (37,~35) carried out at the Antiproton Decelerator (AD) at CERN. We performed a laser-microwave-laser resonance spectroscopy using a continuous wave (cw) pulse-amplified laser system and microwave cavity to measure the HF transition frequencies. Improvements in the spectral linewidth and stability of our laser system have increased the precision of these measurements by a factor of five and reduced the line width by a factor of three compared to our previous results. A comparison of the experimentally measured transition frequencies with three body QED calculations can be used to determine the antiproton spin magnetic moment, leading towards a test of CPT invariance.

  8. Hyperfine splitting of low-lying heavy baryons

    Energy Technology Data Exchange (ETDEWEB)

    Harada, M.; Qamar, A.; Schechter, J. [Syracuse Univ., NY (United States). Dept. of Physics; Sannino, F. [Syracuse Univ., NY (United States). Dept. of Physics]|[Dipartimento di Scienze Fisiche and Istituto Nazionale di Fisica Nucleare, Mostra D`Oltremare Pad. 19, 80125, Napoli (Italy); Weigel, H. [Institute for Theoretical Physics, Tuebingen University, Auf der Morgenstelle 14, D-72076, Tuebingen (Germany)

    1997-11-10

    We calculate the next-to-leading order contribution to the masses of the heavy baryons in the bound-state approach for baryons containing a heavy quark. These 1/N{sub C} corrections arise when states of good spin and isospin are generated from the background soliton of the light meson fields. Our study is motivated by the previously established result that light vector meson fields are required for this soliton in order to reasonably describe the spectrum of both the light and the heavy baryons. We note that the inclusion of light vector mesons significantly improves the agreement of the predicted hyperfine splitting with experiment. A number of aspects of this somewhat complicated calculation are discussed in detail. (orig.). 33 refs.

  9. Control of inhomogeneous atomic ensembles of hyperfine qudits

    DEFF Research Database (Denmark)

    Mischuck, Brian Edward; Merkel, Seth T.; Deutsch, Ivan H.

    2012-01-01

    We study the ability to control d-dimensional quantum systems (qudits) encoded in the hyperfine spin of alkali-metal atoms through the application of radio- and microwave-frequency magnetic fields in the presence of inhomogeneities in amplitude and detuning. Such a capability is essential...... to the design of robust pulses that mitigate the effects of experimental uncertainty and also for application to tomographic addressing of particular members of an extended ensemble. We study the problem of preparing an arbitrary state in the Hilbert space from an initial fiducial state. We prove...... that inhomogeneous control of qudit ensembles is possible based on a semianalytic protocol that synthesizes the target through a sequence of alternating rf and microwave-driven SU(2) rotations in overlapping irreducible subspaces. Several examples of robust control are studied, and the semianalytic protocol...

  10. A source of antihydrogen for in-flight hyperfine spectroscopy

    CERN Document Server

    Kuroda, N; Murtagh, D J; Van Gorp, S; Nagata, Y; Diermaier, M; Federmann, S; Leali, M; Malbrunot, C; Mascagna, V; Massiczek, O; Michishio, K; Mizutani, T; Mohri, A; Nagahama, H; Ohtsuka, M; Radics, B; Sakurai, S; Sauerzopf, C; Suzuki, K; Tajima, M; Torii, H A; Venturelli, L; Wünschek, B; Zmeskal, J; Zurlo, N; Higaki, H; Kanai, Y; Lodi Rizzini, E; Nagashima, Y; Matsuda, Y; Widmann, E; Yamazaki, Y

    2014-01-01

    Antihydrogen, a positron bound to an antiproton, is the simplest antiatom. Its counterpart—hydrogen—is one of the most precisely investigated and best understood systems in physics research. High-resolution comparisons of both systems provide sensitive tests of CPT symmetry, which is the most fundamental symmetry in the Standard Model of elementary particle physics. Any measured difference would point to CPT violation and thus to new physics. Here we report the development of an antihydrogen source using a cusp trap for in-flight spectroscopy. A total of 80 antihydrogen atoms are unambiguously detected 2.7 m downstream of the production region, where perturbing residual magnetic fields are small. This is a major step towards precision spectroscopy of the ground-state hyperfine splitting of antihydrogen using Rabi-like beam spectroscopy.

  11. Analysis of Hydrogen Cyanide Hyperfine Spectral Components towards Star Forming Cores

    Directory of Open Access Journals (Sweden)

    Loughnane R. M.

    2011-12-01

    Full Text Available Although hydrogen cyanide has become quite a common molecular tracing species for a variety of astrophysical sources, it, however, exhibits dramatic non-LTE behaviour in its hyperfine line structure. Individual hyperfine components can be strongly boosted or suppressed. If these so-called hyperfine line anomalies are present in the HCN rotational spectra towards low or high mass cores, this will affect the interpretation of various physical properties such as the line opacity and excitation temperature in the case of low mass objects and infall velocities in the case of their higher mass counterparts. Anomalous line ratios are present either through the relative strengths of neighboring hyperfine lines or through the varying widths of hyperfine lines belonging to a particular rotational line. This work involves the first observational investigation of these anomalies in two HCN rotational transitions, J=1→0 and J=3→2, towards both low mass starless cores and high mass protostellar objects. The degree of anomaly in these two rotational transitions is considered by computing the ratios of neighboring hyperfine lines in individual spectra. Results indicate some degree of anomaly is present in all cores considered in our survey, the most likely cause being line overlap effects among hyperfine components in higher rotational transitions.

  12. Wavelengths, energy levels and hyperfine structure of Mn II and Sc II.

    Science.gov (United States)

    Nave, Gillian; Pickering, Juliet C.; Townley-Smith, Keeley I. M.; Hala, .

    2015-08-01

    For many decades, the Atomic Spectroscopy Groups at the National Institute of Standards and Technology (NIST) and Imperial College London (ICL) have measured atomic data of astronomical interest. Our spectrometers include Fourier transform (FT) spectrometers at NIST and ICL covering the region 1350 Å to 5.5 μm and a 10.7-m grating spectrometer at NIST covering wavelengths from 300 - 5000 Å. Sources for these spectra include high-current continuous and pulsed hollow cathode (HCL) lamps, Penning discharges, and sliding spark discharges. Recent work has focused on the measurement and analysis of wavelengths, energy levels, and hyperfine structure (HFS) constants for iron-group elements. The analysis of FT spectra of Cr I, Mn I, and Mn II is being led by ICL and is described in a companion poster [1]. Current work being led by NIST includes the analysis of HFS in Mn II, analysis of Mn II in the vacuum ultraviolet, and a comprehensive analysis of Sc II.Comprehensive HFS constants for Mn II are needed for the interpretation of stellar spectra and incorrect abundances may be obtained when HFS is omitted. Holt et al. [2] have measured HFS constants for 59 levels of Mn II using laser spectroscopy. We used FT spectra of Mn/Ni and Mn/Cu HCLs covering wavelength ranges from 1350 Å to 5.4 μm to confirm 26 of the A constants of Holt et al. and obtain values for roughly 40 additional levels. We aim to obtain HFS constants for the majority of lines showing significant HFS that are observed in chemically-peculiar stars.Spectra of Sc HCLs have been recorded from 1800 - 6700 Å using a vacuum ultraviolet FT spectrometer at NIST. Additional measurements to cover wavelengths above 6700 Å and below 1800 Å are in progress. The spectra are being analyzed by NIST and Alighar Muslim University, India in order to derive improved wavelengths, energy levels, and hyperfine structure parameters.This work was partially supported by NASA, the STFC and PPARC (UK), the Royal Society of the UK

  13. Hyperfine structure of 2Σ molecules containing alkaline-earth-metal atoms

    Science.gov (United States)

    Aldegunde, Jesus; Hutson, Jeremy M.

    2018-04-01

    Ultracold molecules with both electron spin and an electric dipole moment offer new possibilities in quantum science. We use density-functional theory to calculate hyperfine coupling constants for a selection of molecules important in this area, including RbSr, LiYb, RbYb, CaF, and SrF. We find substantial hyperfine coupling constants for the fermionic isotopes of the alkaline-earth-metal and Yb atoms. We discuss the hyperfine level patterns and Zeeman splittings expected for these molecules. The results will be important both to experiments aimed at forming ultracold open-shell molecules and to their applications.

  14. Contact hyperfine field of the 4p and 4f series elements (rare-earths)

    International Nuclear Information System (INIS)

    Doi, I.

    1973-01-01

    The Coulomb correlation effect in the description of the contact hyperfine magnetic structure was analysed. The hyperfine magnetic structure was calculated from the spin polarized Hartree-Fock formalism, using the free electron gas approximation to the exchange-correlation energy of the 4p series atoms and some atoms and ions of the 4f series. No one of the analysed approximations to the exchange-correlation energy describes satisfactorily the contact hyperfine magnetic structure of the 4p and 4f series elements, which were studied [pt

  15. Fine- and hyperfine-structure effects in molecular photoionization. II. Resonance-enhanced multiphoton ionization and hyperfine-selective generation of molecular cations

    Energy Technology Data Exchange (ETDEWEB)

    Germann, Matthias; Willitsch, Stefan, E-mail: stefan.willitsch@unibas.ch [Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel (Switzerland)

    2016-07-28

    Resonance-enhanced multiphoton ionization (REMPI) is a widely used technique for studying molecular photoionization and producing molecular cations for spectroscopy and dynamics studies. Here, we present a model for describing hyperfine-structure effects in the REMPI process and for predicting hyperfine populations in molecular ions produced by this method. This model is a generalization of our model for fine- and hyperfine-structure effects in one-photon ionization of molecules presented in Paper I [M. Germann and S. Willitsch, J. Chem. Phys. 145, 044314 (2016)]. This generalization is achieved by covering two main aspects: (1) treatment of the neutral bound-bound transition including the hyperfine structure that makes up the first step of the REMPI process and (2) modification of our ionization model to account for anisotropic populations resulting from this first excitation step. Our findings may be used for analyzing results from experiments with molecular ions produced by REMPI and may serve as a theoretical background for hyperfine-selective ionization experiments.

  16. Hyperfine interaction mediated electric-dipole spin resonance: the role of frequency modulation

    International Nuclear Information System (INIS)

    Li, Rui

    2016-01-01

    The electron spin in a semiconductor quantum dot can be coherently controlled by an external electric field, an effect called electric-dipole spin resonance (EDSR). Several mechanisms can give rise to the EDSR effect, among which there is a hyperfine mechanism, where the spin-electric coupling is mediated by the electron–nucleus hyperfine interaction. Here, we investigate the influence of frequency modulation (FM) on the spin-flip efficiency. Our results reveal that FM plays an important role in the hyperfine mechanism. Without FM, the electric field almost cannot flip the electron spin; the spin-flip probability is only about 20%. While under FM, the spin-flip probability can be improved to approximately 70%. In particular, we find that the modulation amplitude has a lower bound, which is related to the width of the fluctuated hyperfine field. (paper)

  17. Anomalies in resonant absorption line profiles of atoms with large hyperfine splitting

    International Nuclear Information System (INIS)

    Parkhomenko, A.I.; Pod'yachev, S.P.; Privalov, T.I.; Shalagin, A.M.

    1997-01-01

    We examine a monochromatic absorption line in the velocity-nonselective excitation of atoms when the components of the hyperfine stricture of the electronic ground states are optically pumped. We show that the absorption lines possess unusual substructures for some values of the hyperfine splitting of the ground state (which exceed the Doppler absorption linewidth severalfold). These substructures in the absorption spectrum are most apparent if the hyperfine structure of the excited electronic state is taken into account. We calculate the absorption spectra of monochromatic light near the D 1 and D 2 lines of atomic rubidium 85,87 Rb. With real hyperfine splitting taken into account, the D 1 and D 2 lines are modeled by 4- and 6-level diagrams, respectively. Finally, we show that atomic rubidium vapor can be successfully used to observe the spectral features experimentally

  18. Hyperfine interactions and structures of ferrous hydroxide and green rust II in sulfated aqueous media

    International Nuclear Information System (INIS)

    Olowe, A.A.; Genin, J.M.R.; Bauer, P.

    1988-01-01

    A sulfated ferrous hydroxide is obtained by mixing NaOH with melanterite depending on the R = [SO 4 -- ]/[OH - ] ratio and leading by oxidation to the green rust II transient compound. Hyperfine parameters are presented. (orig.)

  19. THE HYPERFINE STRUCTURE OF THE ROTATIONAL SPECTRUM OF HDO AND ITS EXTENSION TO THE THz REGION: ACCURATE REST FREQUENCIES AND SPECTROSCOPIC PARAMETERS FOR ASTROPHYSICAL OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Cazzoli, Gabriele; Lattanzi, Valerio; Puzzarini, Cristina [Dipartimento di Chimica “Giacomo Ciamician”, Università di Bologna, Via Selmi 2, I-40126 Bologna (Italy); Alonso, José Luis [Grupo de Espectroscopía Molecular (GEM), Unidad Asociada CSIC, Edificio Quifima, Laboratorios de Espectroscopia y Bioespectroscopia, Parque Científico UVa, Universidad de Valladolid, E-47005 Valladolid (Spain); Gauss, Jürgen, E-mail: cristina.puzzarini@unibo.it [Institut für Physikalische Chemie, Universität Mainz, D-55099 Mainz (Germany)

    2015-06-10

    The rotational spectrum of the mono-deuterated isotopologue of water, HD{sup 16}O, has been investigated in the millimeter- and submillimeter-wave frequency regions, up to 1.6 THz. The Lamb-dip technique has been exploited to obtain sub-Doppler resolution and to resolve the hyperfine (hf) structure due to the deuterium and hydrogen nuclei, thus enabling the accurate determination of the corresponding hf parameters. Their experimental determination has been supported by high-level quantum-chemical calculations. The Lamb-dip measurements have been supplemented by Doppler-limited measurements (weak high-J and high-frequency transitions) in order to extend the predictive capability of the available spectroscopic constants. The possibility of resolving hf splittings in astronomical spectra has been discussed.

  20. Two-photon exchange correction to the hyperfine splitting in muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Tomalak, Oleksandr [Johannes Gutenberg Universitaet, Institut fuer Kernphysik and PRISMA Cluster of Excellence, Mainz (Germany)

    2017-12-15

    We reevaluate the Zemach, recoil and polarizability corrections to the hyperfine splitting in muonic hydrogen expressing them through the low-energy proton structure constants and obtain the precise values of the Zemach radius and two-photon exchange (TPE) contribution. The uncertainty of TPE correction to S energy levels in muonic hydrogen of 105 ppm exceeds the ppm accuracy level of the forthcoming 1S hyperfine splitting measurements at PSI, J-PARC and RIKEN-RAL. (orig.)

  1. Calculations of hyperfine interactions in transition metal compounds in the local density approximation

    International Nuclear Information System (INIS)

    Guenzburger, D.J.R.

    1982-01-01

    A survey is made of some theoretical calculations of electrostatic and magnetic hyperfine interactions in transition metal compounds and complex irons. The molecular orbital methods considered are the Multiple Scattering and Discrete Variational, in which the local Xα approximation for the exchange interaction is employed. Emphasis is given to the qualitative informations, derived from the calculations, relating the hyperfine parameters to characteristics of the chemical bonds. (Author) [pt

  2. Theoretical study of Moessbauer hyperfine parameters of Fe bound to ammonia

    International Nuclear Information System (INIS)

    Terra, J.; Guenzburger, D.

    1995-01-01

    The first-principles Discrete Variational method was employed to study the species formed by the interaction of an Fe atom and ammonia. Total energy calculations were performed for several configurations. The hyperfine parameters isomer shift, quadrupole splitting and magnetic hyperfine were calculated for the ground state found, and compared to reported experimental values obtained by Moessbauer spectroscopy in frozen ammonia. (author). 14 refs, 1 tab

  3. Hyperfine structure of the S- and P-wave states of muonic deuterium

    International Nuclear Information System (INIS)

    Martynenko, A. P.; Martynenko, G. A.; Sorokin, V. V.; Faustov, R. N.

    2016-01-01

    Corrections of order α"5 and α"6 to the hyperfine structure of the S- and P-wave states of muonic deuteriumwere calculated on the basis of the quasipotential approach in quantum electrodynamics. Relativistic corrections, vacuum-polarization and deuteron-structure effects, and recoil corrections were taken into account in this calculation. The resulting hyperfine-splitting values can be used in a comparison with experimental data obtained by the CREMA Collaboration.

  4. Hyperfine magnetic fields of disorder systems by 57Fe Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Miglierini, M.; Sitek, J.; Lipka, J.

    1994-01-01

    The feasibility of 57 Fe transmission Moessbauer spectroscopy in the study of hyperfine magnetic fields is described with emphasis on amorphous, nanocrystalline and quasicrystalline alloys. Distributions of hyperfine magnetic fields obtained are presented via three-dimensional projects where effects of sample composition, temperature and annealing time on magnetic structure are followed by changes in probability of the field values. This allows magnetic transitions as well as mixed electric-quadrupole and magnetic-dipole interactions to be observed

  5. Hyperfine field distributions in disordered Mn2CoSn and Mn2NiSn ...

    Indian Academy of Sciences (India)

    Unknown

    Jha S, Seyoum H M, Demarco M, Julian G M, Stubbs D A,. Blue J W, Silva M T X and Vasquez A 1983 Hyperfine Inter- act. 15/16 685. Ritcey S P and Dunlap R A 1984 J. Appl. Phys. 55 2051. Surikov V V, Zhordochkin V N and Astakhova T Yu 1990. Hyperfine Interact. 59 469. Webster P J and Ziebeck K R A 1973 J. Phys.

  6. Paramagnetic hyperfine interactions of iron in solid ammonia from Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Litterst, F.J.; Saitovitch, E.M.B.; Terra, J.

    1988-01-01

    Moessbauer studies on highly dilute 57 Fe in solid ammonia are reported. The hyperfine parameters of the paramagnetic reaction product FeNH 3 point to a nearly atomic configuration of iron [Ar]3d 7 4s. The electronic spin relaxation slows down rapidly under application of an external magnetic field. The field dependence of the magnetic hyperfine patterns indicates a strong axial magnetic anisotropy. (author) [pt

  7. Hyperfine Fields on Actinide Impurities in Ferromagnetic Fe and Ni Hosts

    International Nuclear Information System (INIS)

    Oliveira, A.L. de; Oliveira, N.A. de; Troper, A.

    2003-01-01

    We discuss the local magnetic moments and magnetic hyperfine fields on actinide impurities diluted in Fe and Ni hosts. One adopts a Anderson- Moriya model in which a localized 5f level is hybridized with a spin polarized and charge perturbed d-conduction band. Our self-consistent numerical calculations for the hyperfine fields on the impurity sites are in good agreement with the available experimental data. (author)

  8. Hyperfine anomalies of HCN in cold dark clouds

    International Nuclear Information System (INIS)

    Walmsley, C.M.; Churchwell, E.; Nash, A.; Fitzpatrick, E.; and Physics Department, University of Illinois at Urbana-Champaign)

    1982-01-01

    We report observations of the J = 1→0 line of HCN measured toward six positions in nearby low-temperature dark clouds. The measured relative intensities of the hyperfine components of the J = 1→0 line are anomalous in that the F = 0→1 transition is stronger than would be expected if all three components (F = 2→1, F = 1→1, F = 0→1) had equal excitation temperatures. Differences of approximately 20% in the populations per sublevel of J = 1 could account for the observations. The results are in contrast to the situation observed in warmer molecular clouds associated with H II regions where the F = 1→1 line is anomalously weak. The apparent overpopulation of J = 1, F = 0 in dark clouds may be related to the phenomenon observed in the J = 1→0 transitions of HCO + and HNC in the same objects where 13 C substituted version of these species is found to be stronger than the 12 C species

  9. Hyperfine structure and isotope shift analysis of singly ionized titanium

    Science.gov (United States)

    Bouazza, Safa

    2013-04-01

    The even-parity low configuration system of Ti II has been considered on the basis of the experimental data found in the literature, and its fine structure has been reanalyzed by simultaneous parameterization of one- and two-body interactions for the model space (3d + 4s)3. Furthermore, the main one-electron hyperfine structure parameters for these configurations have been evaluated. For instance, for 3d24s1, a_{3{\\rm{d}}}^{01} = - {\\rm{63}}.{\\rm{2}}\\left( {{\\rm{3}}.{\\rm{1}}} \\right)\\,{\\rm{MHz}} and a_{4{\\rm{s}}}^{10} = - {\\rm{984}}.{\\rm{1}}\\left( {{\\rm{7}}.{\\rm{1}}} \\right)\\,{\\rm{MHz}} . Field shifts (FS) and specific mass shifts (SMS) of the main Ti II configurations are deduced by means of ab initio estimates combined with a small quantity of experimental isotope shift data available in the literature: FS(3d3) = -63.3 MHz, FS(3d24p1) = -49.7 MHz, FS(3d14s2) = 98.2 MHz, FS(4s24P1) = 163.4 MHz and SMS(3d3) = 1453.3 MHz, SMS(3d14s2) = -2179.7 MHz, …, referred to 3d24s1 for the pair Ti46-Ti48.

  10. Hyperfine interaction measurements in biological compounds: the case of hydroxyapatite

    International Nuclear Information System (INIS)

    Leite Neto, Osmar Flavio da Silveira

    2014-01-01

    The use o nanoparticles in current medicine are under intense investigation. The possible advantages proposed by these systems are very impressive and the results may be quite schemer. In this scenario, the association of nanoparticles with radioactive materials (radionuclide) may be the most important step since the discovery of radioactive for nuclear medicine and radiopharmacy, especially for cancer targeting and therapy. The hyperfine interaction of the nuclear probe 111 Cd in the Hydroxyapatite compounds has been investigated by perturbed angular correlation (PAC) spectroscopy in room temperature for the hydroxyapatite made in the temperatures of 90°C, 35°C and with Ho doped, both thermalized and not. The thermalized samples were heated to T= 1273 K for 6 h. The 111 Cd was broadcast in the structure of the material by diffusion, closing in quartz tubes were heated – together with the radioactive PAC probe 111 In/ 111 Cd to T = 1073 K for 12 h. In not thermalized samples the PAC spectra indicate a distribution of frequency, but in the thermalized samples, the PAC spectra shows the presence of β-tri calcium phosphate in the structure of this kind of Hydroxyapatite. (author)

  11. Ab initio calculation of hyperfine splitting constants of molecules

    Science.gov (United States)

    Ohta, K.; Nakatsuji, H.; Hirao, K.; Yonezawa, T.

    1980-08-01

    Hyperfine splitting (hfs) constants of molecules, methyl, ethyl, vinyl, allyl, cyclopropyl, formyl, O3-, NH2, NO2, and NF2 radicals have been calculated by the pseudo-orbital (PO) theory, the unrestricted HF (UHF), projected UHF (PUHF) and single excitation (SE) CI theories. The pseudo-orbital (PO) theory is based on the symmetry-adapted-cluster (SAC) expansion proposed previously. Several contractions of the Gaussian basis sets of double-zeta accuracy have been examined. The UHF results were consistently too large to compare with experiments and the PUHF results were too small. For molecules studied here, the PO theory and SECI theory gave relatively close results. They were in fair agreement with experiments. The first-order spin-polarization self-consistency effect, which was shown to be important for atoms, is relatively small for the molecules. The present result also shows an importance of eliminating orbital-transformation dependence from conventional first-order perturbation calculations. The present calculations have explained well several important variations in the experimental hfs constants.

  12. Some recoil corrections to the hydrogen hyperfine splitting

    International Nuclear Information System (INIS)

    Bodwin, G.T.; Yennie, D.R.

    1988-01-01

    We compute all of the recoil corrections to the ground-state hyperfine splitting in hydrogen, with the exception of the proton polarizability, that are required to achieve an accuracy of 1 ppm. Our approach includes a unified treatment of the corrections that would arise from a pointlike Dirac proton and the corrections that are due to the proton's non-QED structure. Our principal new results are a calculation of the relative order-α 2 (m/sub e//m/sub p/) contributions that arise from the proton's anomalous magnetic moment and a systematic treatment of the relative order-α(m/sub e//m/sub p/) contributions that arise from form-factor corrections. In the former calculation we introduce some new technical improvements and are able to evaluate all of the expressions analytically. In the latter calculation, which has been the subject of previous investigations by other authors, we express the form-factor corrections in terms of two-dimensional integrals that are convenient for numerical evaluation and present numerical results for the commonly used dipole parametrization of the form factors. Because we use a parametrization of the form factors that differs slightly from the ones used in previous work, our numerical results are shifted from older ones by a small amount

  13. Progress towards antihydrogen hyperfine spectroscopy in a beam

    Energy Technology Data Exchange (ETDEWEB)

    Widmann, Eberhard [Stefan Meyer Institute for Subatomic Physics, Vienna (Austria); Collaboration: ASACUSA CUSP collaboration

    2014-07-01

    The spectroscopy of antihydrogen promises one of the most precise tests of CPT symmetry. The ASACUSA CUSP collaboration at the Antiproton Decelerator of CERN is preparing an experiment to measure the ground-state hyperfine structure GS-HFS of antihydrogen, since this quantity is one of the most precisely determined transitions in ordinary hydrogen (relative accuracy ∝10{sup -12}). The experiment uses a Rabi-type atomic beam apparatus consisting of a source of spin-polarized antihydrogen (a so-called cusp trap), a microwave cavity to induce a spin flip, a superconducting sextuple magnet for spin analysis, and an antihydrogen detector. In this configuration, a relative accuracy of better than 10{sup -6} can be obtained. This precision will already allow to be sensitive to finite size effects of the antiproton, provided its magnetic moment will measured to higher precision, which is in progress by two collaborations at the AD. The recent progress in producing a beam of antihydrogen atoms and in the development of the apparatus as well as ways to further improve the accuracy by using the Ramsey method of separated oscillatory fields are presented.

  14. Recoil effects in the hyperfine structure of QED bound states

    International Nuclear Information System (INIS)

    Bodwin, G.T.; Yennie, D.R.; Gregorio, M.A.

    1985-01-01

    The authors give a general discussion of the derivation from field theory of a formalism for the perturbative solution of the relativistic two-body problem. The lowest-order expression for the four-point function is given in terms of a two-particle three-dimensional propagator in a static potential. It is obtained by fixing the loop energy in the four-dimensional formalism at a point which is independent of the loop momentum and is symmetric in the two particle variables. This method avoids awkward positive- and negative-energy projectors, with their attendant energy square roots, and allows one to recover the Dirac equation straightforwardly in the nonrecoil limit. The perturbations appear as a variety of four-dimensional kernels which are rearranged and regrouped into convenient sets. In particular, they are transformed from the Coulomb to the Feynman gauge, which greatly simplifies the expressions that must be evaluated. Although the approach is particularly convenient for the precision analysis of QED bound states, it is not limited to such applications. The authors use it to give the first unified treatment of all presently known recoil corrections to the muonium hyperfine structure and also to verify the corresponding contributions through order α 2 lnαE/sub F/ in positronium. The required integrals are evaluated analytically

  15. Hyperfine 3D neutronic calculations in CANDU supercells

    International Nuclear Information System (INIS)

    Balaceanu, V.; Aioanei, L.; Pavelescu, M.

    2010-01-01

    For an accurate evaluation of the fuel performances, it is very important to have capability to calculate the three dimensional spatial flux distributions in the fuel bundle. According this issue, in our Institute, a multigroup calculation methodology named WIMS-PIJXYZ was especially developed for estimating the local neutronic parameters in CANDU cell/supercells. The objective of this paper is to present this calculation methodology and to use it in performing some hyperfine neutronic calculations in CANDU type supercells. More exactly, after a short description for the WIMS-PIJXYZ methodology, the end effect for some CANDU fuel bundles is estimated. The WIMS-PIJXYZ methodology is based on WIMS and PIJXYZ transport codes. WIMS is a standard lattice-cell code and it is used for generating the multigroup macroscopic cross sections for the materials in the fuel cells. For obtaining the flux and power distributions in CANDU fuel bundles the PIJXYZ code is used. This code is consistent with WIMS lattice-cell calculations and allows a good geometrical representation of the CANDU bundle in three dimensions. The end effect consists in the increasing of the thermal neutron flux in the end region and the increasing of power in the end of the fuel rod. The region separating the CANDU fuel in two adjoining bundles in a channel is called the 'end region' and the end of the last pellet in the fuel stack adjacent to the end region is called the 'fuel end'. The end effect appears because the end region of the bundle is made up of coolant and Zircaloy-4, a very low neutron absorption material. To estimate the end effect, the flux peaking factors and the power peaking factors are calculated. It was taken in consideration CANDU Standard (Natural Uranium, with 37 elements) fuel bundles. In the end of the paper, the results obtained by WIMS-PIJXYZ methodology with the similar LEGENTR results are compared. The comparative analysis shows a good agreement. (authors)

  16. Hyperfine Interaction Studies on Y, Zr, Nb, Mo, Rh, In and Xe in Co

    International Nuclear Information System (INIS)

    Seewald, G.; Zech, E.; Ratai, H.; Schmid, R.; Stadler, R.; Schramm, O.; Koenig, C.; Hinfurtner, B.; Hagn, E.; Deicher, M.; Eder, R.; Forkel-Wirth, D.

    2004-01-01

    Nuclear magnetic resonance on oriented nuclei and modulated adiabatic fast passage on oriented nuclei measurements were performed on several 4d and 5sp impurities in polycrystalline Co(fcc) foils and Co(hcp) single crystals. The hyperfine fields of Y and Zr in Co(fcc), the hyperfine fields of Y, Zr, Nb, Mo, Rh, In and Xe in Co(hcp), the electric field gradients of Zr, Nb and In in Co(hcp), and the nuclear spin-lattice relaxations of Zr, Nb, Rh and In in Co(hcp) were determined. The dependence of the hyperfine fields and electric field gradients in Co(hcp) on the angle between the magnetization and the c axis was investigated in most cases. The magnetic-field dependence of the spin-lattice relaxation was studied for Nb, Rh and In in Co(hcp), applying the magnetic field perpendicular to the c axis. The known hyperfine interaction parameters of the4d and 5sp impurities in Co(fcc) and Co(hcp) are summarized. The new results provide a more detailed picture of the hyperfine interaction in Co.

  17. Transient nutation electron spin resonance spectroscopy on spin-correlated radical pairs: A theoretical analysis on hyperfine-induced nuclear modulations

    Science.gov (United States)

    Weber, Stefan; Kothe, Gerd; Norris, James R.

    1997-04-01

    The influence of anisotropic hyperfine interaction on transient nutation electron paramagnetic resonance (EPR) of light-induced spin-correlated radical pairs is studied theoretically using the density operator formalism. Analytical expressions for the time evolution of the transient EPR signal during selective microwave excitation of single transitions are derived for a model system comprised of a weakly coupled radical pair and one hyperfine-coupled nucleus with I=1/2. Zero-quantum electron coherence and single-quantum nuclear coherence are created as a result of the sudden light-induced generation of the radical pair state from a singlet-state precursor. Depending on the relative sizes of the nuclear Zeeman frequency and the secular and pseudo-secular parts of the hyperfine coupling, transitions between levels with different nuclear spin orientations are predicted to modulate the time-dependent EPR signal. These modulations are in addition to the well-known transient nutations and electron zero-quantum precessions. Our calculations provide insight into the mechanism of recent experimental observations of coherent nuclear modulations in the time-resolved EPR signals of doublets and radical pairs. Two distinct mechanisms of the modulations are presented for various microwave magnetic field strengths. The first modulation scheme arises from electron and nuclear coherences initiated by the laser excitation pulse and is "read out" by the weak microwave magnetic field. While the relative modulation depth of these oscillations with respect to the signal intensity is independent of the Rabi frequency, ω1, the frequencies of this coherence phenomenon are modulated by the effective microwave amplitude and determined by the nuclear Zeeman interaction and hyperfine coupling constants as well as the electron-electron spin exchange and dipolar interactions between the two radical pair halves. In a second mechanism the modulations are both created and detected by the microwave

  18. Hyperfine structure in 5s4d 3D-5snf transitions of 87Sr

    International Nuclear Information System (INIS)

    Bushaw, B.A.; Kluge, H.J.; Lantzsch, J.; Schwalbach, R.; Stenner, J.; Stevens, H.; Wendt, K.; Zimmer, K.

    1993-01-01

    The hyperfine spectra of the 5s4d 3 D 1 -5s20f, 5s4d 3 D 2 -5s23f, and 5s4d 3 D 3 -5s32f transitions of 87 Sr (I=9/2) have been measured by collinear fast beam laser spectroscopy. The structure in the upper configurations is highly perturbed by fine structure splitting that is of comparable size to the hyperfine interaction energy. These perturbations can be adequately treated with conventional matrix diagonalization methods, using the 5s-electron magnetic dipole interaction term a 5s and the unperturbed fine structure splittings as input parameters. Additionally, hyperfine constants for the lower 5s4d 3 D configurations, including the A- and B-factors and a separation of the individual s- and d-electron contributions to these factors, are derived. (orig.)

  19. Hyperfine electric parameters calculation in Si samples implanted with {sup 57}Mn→{sup 57}Fe

    Energy Technology Data Exchange (ETDEWEB)

    Abreu, Y., E-mail: yabreu@ceaden.edu.cu [Centro de Aplicaciones Tecnológicas y Desarrollo Nuclear (CEADEN), Calle 30 No. 502 e/5ta y 7ma Ave., 11300 Miramar, Playa, La Habana (Cuba); Cruz, C.M.; Piñera, I.; Leyva, A.; Cabal, A.E. [Centro de Aplicaciones Tecnológicas y Desarrollo Nuclear (CEADEN), Calle 30 No. 502 e/5ta y 7ma Ave., 11300 Miramar, Playa, La Habana (Cuba); Van Espen, P. [Departement Chemie, Universiteit Antwerpen, Middelheimcampus, G.V.130, Groenenborgerlaan 171, 2020 Antwerpen (Belgium); Van Remortel, N. [Departement Fysica, Universiteit Antwerpen, Middelheimcampus, G.U.236, Groenenborgerlaan 171, 2020 Antwerpen (Belgium)

    2014-07-15

    Nowadays the electronic structure calculations allow the study of complex systems determining the hyperfine parameters measured at a probe atom, including the presence of crystalline defects. The hyperfine electric parameters have been measured by Mössbauer spectroscopy in silicon materials implanted with {sup 57}Mn→{sup 57}Fe ions, observing four main contributions to the spectra. Nevertheless, some ambiguities still remain in the {sup 57}Fe Mössbauer spectra interpretation in this case, regarding the damage configurations and its evolution with annealing. In the present work several implantation environments are evaluated and the {sup 57}Fe hyperfine parameters are calculated. The observed correlation among the studied local environments and the experimental observations is presented, and a tentative microscopic description of the behavior and thermal evolution of the characteristic defects local environments of the probe atoms concerning the location of vacancies and interstitial Si in the neighborhood of {sup 57}Fe ions in substitutional and interstitial sites is proposed.

  20. Hyperfine structure of the S levels of the muonic helium ion

    International Nuclear Information System (INIS)

    Martynenko, A. P.

    2008-01-01

    Corrections of the α 5 and α 6 orders to the energy spectrum of the hyperfine splitting of the 1S and 2S levels of the muonic helium ion are calculated with the inclusion of the electron vacuum polarization effects, nuclear-structure corrections, and recoil effects. The values ΔE hfs (1S) = -1334.56 meV and ΔE hfs (2S) = -166.62 meV obtained for hyperfine splitting values can be considered as reliable estimates for comparison with experimental data. The hyperfine structure interval Δ 12 = 8ΔE hfs (2S) - ΔE hfs (1S) = 1.64 meV can be used to verify QED predictions

  1. Hyperfine interactions of a muoniated ethyl radical in supercritical CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Cormier, Philip; Taylor, Becky [Department of Chemistry, Mount Allison University, Sackville, New Brunswick, E4L 1G8 (Canada); Ghandi, Khashayar, E-mail: kghandi@mta.c [Department of Chemistry, Mount Allison University, Sackville, New Brunswick, E4L 1G8 (Canada)

    2009-04-15

    A muoniated ethyl radical was studied in supercritical carbon dioxide. The muon and the proton hyperfine coupling constants were measured over temperatures ranging from 305 to 475 K, and a density range from 0.2 to 0.7 (g cm{sup -3}). A decrease was found in the muon hyperfine coupling constants as a function of the density, which can be attributed to the interaction between the CO{sub 2} molecule and the p-orbital of the ethyl radical. The changes to the alpha-proton and beta-proton hyperfine coupling constants with density are attributed to changes in the overall geometry in the formed radical. This system was modeled using quantum calculations.

  2. Hyperfine interactions of a muoniated ethyl radical in supercritical CO2

    International Nuclear Information System (INIS)

    Cormier, Philip; Taylor, Becky; Ghandi, Khashayar

    2009-01-01

    A muoniated ethyl radical was studied in supercritical carbon dioxide. The muon and the proton hyperfine coupling constants were measured over temperatures ranging from 305 to 475 K, and a density range from 0.2 to 0.7 (g cm -3 ). A decrease was found in the muon hyperfine coupling constants as a function of the density, which can be attributed to the interaction between the CO 2 molecule and the p-orbital of the ethyl radical. The changes to the α-proton and β-proton hyperfine coupling constants with density are attributed to changes in the overall geometry in the formed radical. This system was modeled using quantum calculations.

  3. Ab initio calculations of torsionally mediated hyperfine splittings in E states of acetaldehyde

    Science.gov (United States)

    Xu, Li-Hong; Reid, E. M.; Guislain, B.; Hougen, J. T.; Alekseev, E. A.; Krapivin, I.

    2017-12-01

    Quantum chemistry packages can be used to predict with reasonable accuracy spin-rotation hyperfine interaction constants for methanol, which contains one methyl-top internal rotor. In this work we use one of these packages to calculate components of the spin-rotation interaction tensor for acetaldehyde. We then use torsion-rotation wavefunctions obtained from a fit to the acetaldehyde torsion-rotation spectrum to calculate the expected magnitude of hyperfine splittings analogous to those observed at relatively high J values in the E symmetry states of methanol. We find that theory does indeed predict doublet splittings at moderate J values in the acetaldehyde torsion-rotation spectrum, which closely resemble those seen in methanol, but that the factor of three decrease in hyperfine spin-rotation constants compared to methanol puts the largest of the acetaldehyde splittings a factor of two below presently available Lamb-dip resolution.

  4. Effect of vanadium neighbors on the hyperfine properties of iron-vanadium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Elzain, M., E-mail: elzain@squ.edu.om; Yousif, A.; Gismelseed, A.; Al Rawas, A.; Widatallah, H.; Bouziane, K.; Al-Omari, I. [College of Science, Sultan Qaboos University, Physics Department (Oman)

    2008-06-15

    The electronic and magnetic structures of Fe-V alloys are calculated using the discrete-variational and full-potential linearized-augmented-plane wave methods. The derived hyperfine properties at Fe sites are studied against the number of Fe atoms in the neighbouring shells. As expected the magnetic hyperfine field depends strongly on the number of Fe atoms in the first and second shells of neighbours while its dependence on the variation of atoms in the third shell is weak. The calculated distribution of the magnetic hyperfine fields at the Fe sites, are compared to the experimental data of Krause et al. (Phys Rev B 61:6196-6204, 2000). The contact charge densities and the magnetic moments are also calculated. It was found that the contact charge density increases with increasing V contents and this leads to negative isomer shift on addition of V.

  5. Ground-state hyperfine splitting for Rb, Cs, Fr, Ba+, and Ra+

    Science.gov (United States)

    Ginges, J. S. M.; Volotka, A. V.; Fritzsche, S.

    2017-12-01

    We have systematically investigated the ground-state hyperfine structure for alkali-metal atoms 87Rb,133Cs, and 211Fr and alkali-metal-like ions +135Ba and +225Ra, which are of particular interest for parity violation studies. The quantum electrodynamic one-loop radiative corrections have been rigorously evaluated within an extended Furry picture employing core-Hartree and Kohn-Sham atomic potentials. Moreover, the effect of the nuclear magnetization distribution on the hyperfine structure intervals has been studied in detail and its uncertainty has been estimated. Finally, the theoretical description of the hyperfine structure has been completed with full many-body calculations performed in the all-orders correlation potential method.

  6. Moessbauer effect study of hyperfine interaction of /sup 161/Dy and /sup 151/Eu in tungsten bronzes Dysub(0. 18) WO/sub 3/ and Eusub(0. 18) WO/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Kisynska, K

    1979-01-01

    The Moessbauer technique was used to investigate the hyperfine interaction of /sup 161/Dy and /sup 151/Eu in cubic rare earth tungsten bronzes: Dysub(0.18)WO/sub 3/ and Eusub(0.18)WO/sub 3/. Well resolved hfs spectrum was obtained at 4.2 K for Dysub(0.18)WO/sub 3/. The effective hf field approximation sufficed to interpret the spectrum. The obtained hyperfine interaction parameters were: -g/sub 0/..beta..sub(N)Hsub(eff)=(805+-19) Mc/s and e/sup 2/qQ/sub 0//4 = (506+-56) Mc/s. These results imply that ground doublet of Dy/sup +3/ ion in bronze is a Kramers doublet Vertical Bar+-15/2> with asymmetrical hyperfine tensor Asub(z) non equal to 0, Asub(x) = Asub(y) = 0 and that local crystalline field at RE metal in tungsten bronze at 4.2 K cannot be cubic. From ME absorption spectra of Eusub(0.18)WO/sub 3/ taken at 4.2 K, 78 K and 300 K the values of quadrupole interaction constants for bronze lattice and its temperature dependence were obtained. These data indicate that a phase transition from the high temperature ideal perovskite structure to a distorted one occurs in RE bronzes and that the distortion concerns the nearest tungsten-oxygen environment of RE ion.

  7. Hyperfine splitting of the optical lines in the odd isotopes of uranium

    International Nuclear Information System (INIS)

    Gangrskij, Yu.P.; Zemlyanoj, S.G.; Markov, B.N.; Kul'dzhanov, B.K.

    1996-01-01

    The hyperfine structure was studied for two optical transitions in U between the ground state term 5 L 6 and the excited ones 7 M 7 and 7 L 6 . The method of laser resonance fluorescence in the atomic beam was used. The values of constants of hyperfine splitting-magnetic dipole and octupole, electric quadrupole were obtained for odd isotopes 223 U and 235 U. The connection of these constants and atomic and nuclear parameters is discussed. (author). 20 refs., 2 figs., 4 tabs

  8. Hyperfine structure investigations for the odd-parity configuration system in atomic holmium

    Science.gov (United States)

    Stefanska, D.; Furmann, B.

    2018-02-01

    In this work new experimental results of the hyperfine structure (hfs) in the holmium atom are reported, concerning the odd-parity level system. Investigations were performed by the method of laser induced fluorescence in a hollow cathode discharge lamp on 97 spectral lines in the visible part of the spectrum. Hyperfine structure constants: magnetic dipole - A and electric quadrupole - B for 40 levels were determined for the first time; for another 21 levels the hfs constants available in the literature were remeasured. Results for the A constants can be viewed as fully reliable; for B constants further possibilities of improving the accuracy are considered.

  9. International summer school on hyperfine interactions and physics with oriented nuclei - 1985. Pt.1,2

    International Nuclear Information System (INIS)

    Rotter, M.

    1985-01-01

    Part I and part II are presented of the contributions submitted to the International study meeting on physics with oriented nuclei and of papers from the International summer school on hyperfine interactions. The contributions and papers are devoted to the present status and further development of low temperature nuclear orientation of short-lived nuclei with emphasis on online techniques. The following topics are covered: nuclear orientation, NMR/ON, level mixing and level crossing resonances, laser spectroscopy, Moessbauer spectroscopy, polarization phenomena in low, medium and high energy physics, applications of hyperfine interaction techniques in nuclear physics, atomic physics, solid state physics, biology and materials research. (Z.J.)

  10. Theory of Electric-Field Effects on Electron-Spin-Resonance Hyperfine Couplings

    International Nuclear Information System (INIS)

    Karna, S.P.

    1997-01-01

    A quantum mechanical theory of the effects of a uniform electric field on electron-spin-resonance hyperfine couplings is presented. The electric-field effects are described in terms of perturbation coefficients which can be used to probe the local symmetry as well as the strength of the electric field at paramagnetic sites in a solid. Results are presented for the first-order perturbation coefficients describing the Bloembergen effect (linear electric-field effect on hyperfine coupling tensor) for the O atom and the OH radical. copyright 1997 The American Physical Society

  11. Study of coupled-cluster correlations on electromagnetic transitions and hyperfine structure constants of W VI

    International Nuclear Information System (INIS)

    Bhowmik, Anal; Majumder, Sonjoy; Roy, Sourav; Dutta, Narendra Nath

    2017-01-01

    This work presents precise calculations of important electromagnetic transition amplitudes along with details of their many-body correlations using the relativistic coupled-cluster method. Studies of hyperfine interaction constants, useful for plasma diagnostics, with this correlation exhaustive many-body approach, are another important area of this work. The calculated oscillator strengths of allowed transitions, amplitudes of forbidden transitions and lifetimes are compared with the other theoretical results wherever available and they show a good agreement. Hyperfine constants of different isotopes of W VI, presented in this paper, will be helpful in gaining an accurate picture of the abundances of this element in different astronomical bodies. (paper)

  12. Moessbauer investigation of magnetic hyperfine fields near bivalent Eu compounds under high pressure

    International Nuclear Information System (INIS)

    Abd Elmeguid, M.

    1979-01-01

    The paper deals with the pressure or volume dependence of hyperfine interactions of magnetically ordered, bivalent europium compounds. Emphasis is laid on the investigation of the pressure or volume dependence of magnetic hyperfine fields as they are found at the nuclear site of 151 Eu or of diamagnetic 119 Sn or 197 Au probe atoms. The measurements were carried out with the aid of the gamma resonance of 151 Eu (21.6 keV) 119 Sn (23.8 keV) and 167 Au (77.4 keV) at low temperatures and external pressures up to 65 kbar. (orig./WBU) [de

  13. The hyperfine fields at 181Ta in HfFe2

    International Nuclear Information System (INIS)

    Cekic, B.; Ivanovic, N.; Manasijevic, M.; Koicki, S.; Koteski, V.; Cavor, J.; Radisavljevic, I.; Milosevic, Z.; Novakovic, N.

    2001-01-01

    The hyperfine fields (HFF) in the polycrystalline HfFe 2 binary compound consisting the two various phases MgCu 2 and MgZn 2 , were measured at 181 Ta probe ion sites by gamma-gamma time differential perturbed angular correlations (TDPAC) technique in a wide temperature range. The origin of the hyperfine magnetic field is discussed taking in account the coordination of the 181 Ta probe ion, its core polarization and the polarization of conduction electrons around the 181 Ta site in both phases. (author)

  14. Investigation of transferred hyperfine interactions from 129I and 119Sn by Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Sanchez, J.-P.

    1976-01-01

    The hyperfine parameters at 129 I have been measured in the series of compounds CrI 3 , CsCrI 3 , MI 2 (M=V, Cr, Mn, Fe, Co, Ni, Cd) and NR 4 FeI 4 (R=ethyl, butyl). They have been interpreted in terms of the charge and spin densities in the ligand valence orbitals. Information about the spin polarization mechanisms as well as about the local magnetic and crystallographic structural arrangements have been furthermore deduced. The 119 Sn hyperfine data in the series of RESn 3 intermetallics have provided information about the magnetic structure and the spin polarization mechanisms [fr

  15. Improving the calculation of electron paramagnetic resonance hyperfine coupling tensors for d-block metals

    DEFF Research Database (Denmark)

    Hedegård, Erik Donovan; Kongsted, Jacob; Sauer, Stephan P. A.

    2012-01-01

    Calculation of hyperfine coupling constants (HFCs) of Electron Paramagnetic Resonance from first principles can be a beneficial compliment to experimental data in cases where the molecular structure is unknown. We have recently investigated basis set convergence of HFCs in d-block complexes...... and obtained a set of basis functions for the elements Sc–Zn, which were saturated with respect to both the Fermi contact and spin-dipolar components of the hyperfine coupling tensor [Hedeg°ard et al., J. Chem. Theory Comput., 2011, 7, pp. 4077-4087]. Furthermore, a contraction scheme was proposed leading...

  16. Quantum versus classical hyperfine-induced dynamics in a quantum dota)

    Science.gov (United States)

    Coish, W. A.; Loss, Daniel; Yuzbashyan, E. A.; Altshuler, B. L.

    2007-04-01

    In this article we analyze spin dynamics for electrons confined to semiconductor quantum dots due to the contact hyperfine interaction. We compare mean-field (classical) evolution of an electron spin in the presence of a nuclear field with the exact quantum evolution for the special case of uniform hyperfine coupling constants. We find that (in this special case) the zero-magnetic-field dynamics due to the mean-field approximation and quantum evolution are similar. However, in a finite magnetic field, the quantum and classical solutions agree only up to a certain time scale t <τc, after which they differ markedly.

  17. Hyperfine structure of six low-lying fine structure levels of 191Ir and 193Ir and the 191Δs193 hyperfine anomaly

    International Nuclear Information System (INIS)

    Buettgenbach, S.; Dicke, R.; Gebauer, H.; Kuhnen, R.; Traeber, F.

    1978-01-01

    The hyperfine interaction constants A and B of six low-lying metastable fine structure states of the two iridium isotopes 191 Ir and 193 Ir and the electronic g-factors of these levels have been measured using the atomic-beam magnetic-resonance method. From the values of the magnetic-dipole interaction constants A, corrected for off-diagonal perturbations, we extracted the hyperfine anomaly of a pure 6s-electron state: 191 Δs 193 = 0.64(7)%. Using nonrelativistic approximations for the effective radial parameters the nuclear electric-quadrupole moments were obtained: Q( 191 Ir) = 0.81(21)b, Q( 193 Ir) = 0.73(19)b (corrected for Sternheimer shielding effects). (orig.) [de

  18. Hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements; Etude du couplage hyperfin dans les alliages gadolinium-praseodyme par mesures de chaleur specifique

    Energy Technology Data Exchange (ETDEWEB)

    Michel, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-12-01

    We have studied the hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements down to 0.3 K. In the first part we describe the apparatus used to perform our measurements. The second part is devoted to some theoretical considerations. We have studied in detail the case of praseodymium which is an exception in the rare earth series. The third part shows the results we have obtained. (author) [French] Nous avons etudie le couplage hyperfin d'alliages de gadolinium-praseodyme par des mesures de chaleur specifique jusqu'a 0.3 K. Dans la premiere partie de cette etude nous decrivons le dispositif experimental. La deuxieme partie est consacree a des considerations theoriques. Nous avons etudie en detail le cas du praseodyme qui est une exception dans la serie des terres rares. La troisieme partie est consacree aux resultats experimentaux. (auteur)

  19. l-Tryptophan Radical Cation Electron Spin Resonance Studies: Connecting Solution-derived Hyperfine Coupling Constants with Protein Spectral Interpretations

    Science.gov (United States)

    Connor, Henry D.; Sturgeon, Bradley E.; Mottley, Carolyn; Sipe, Herbert J.; Mason, Ronald P.

    2009-01-01

    Fast-flow electron spin resonance (ESR) spectroscopy has been used to detect a free radical formed from the reaction of l-tryptophan with Ce4+ in an acidic aqueous environment. Computer simulations of the ESR spectra from l-tryptophan and several isotopically modified forms strongly support the conclusion that the l-tryptophan radical cation has been detected by ESR for the first time. The hyperfine coupling constants (HFCs) determined from the well-resolved isotropic ESR spectra support experimental and computational efforts to understand l-tryptophan's role in protein catalysis of oxidation-reduction processes. l-tryptophan HFCs facilitated the simulation of fast-flow ESR spectra of free radicals from two related compounds, tryptamine and 3-methylindole. Analysis of these three compounds' β-methylene hydrogen HFC data along with equivalent l-tyrosine data has led to a new computational method that can distinguish between these two amino acid free radicals in proteins without dependence on isotope labeling, electron nuclear double resonance or high-field ESR. This approach also produces geometric parameters (dihedral angles for the β-methylene hydrogens) which should facilitate protein site assignment of observed l-tryptophan radicals as has been done for l-tyrosine radicals. PMID:18433127

  20. Implication for using heme methyl hyperfine shifts as indicators of heme seating as related to stereoselectivity in the catabolism of heme by heme oxygenase: in-plane heme versus axial his rotation.

    Science.gov (United States)

    Ogura, Hiroshi; Evans, John P; de Montellano, Paul R Ortiz; La Mar, Gerd N

    2008-01-08

    The triple mutant of the solubilized, 265-residue construct of human heme oxygenase, K18E/E29K/R183E-hHO, has been shown to redirect the exclusive alpha-regioselectivity of wild-type hHO to primarily beta,delta-selectivity in the cleavage of heme (Wang, J., Evans, J. P., Ogura, H., La Mar, G. N., and Ortiz de Montellano, P. R. (2006) Biochemistry 45, 61-73). The 1H NMR hyperfine shift pattern for the substrate and axial His CbetaH's and the substrate-protein contacts of the cyanide-inhibited protohemin and 2,4-dimethyldeuterohemin complexes of the triple mutant have been analyzed in detail and compared to data for the WT complex. It is shown that protein contacts for the major solution isomers for both substrates in the mutant dictate approximately 90 degrees in-plane clockwise rotation relative to that in the WT. The conventional interpretation of the pattern of substrate methyl hyperfine shifts, however, indicates substrate rotations of only approximately 50 degrees . This paradox is resolved by demonstrating that the axial His25 imidazole ring also rotates counterclockwise with respect to the protein matrix in the mutant relative to that in the WT. The axial His25 CbetaH hyperfine shifts are shown to serve as independent probes of the imidazole plane orientation relative to the protein matrix. The analysis indicates that the pattern of heme methyl hyperfine shifts cannot be used alone to determine the in-plane orientation of the substrate as it relates to the stereospecificity of heme cleavage, without explicit consideration of the orientation of the axial His imidazole plane relative to the protein matrix.

  1. Hyperfine field and electronic structure of magnetite below the Verwey transition

    Czech Academy of Sciences Publication Activity Database

    Řezníček, R.; Chlan, V.; Štěpánková, H.; Novák, Pavel

    2015-01-01

    Roč. 91, č. 12 (2015), "125134-1"-"125134-10" ISSN 1098-0121 Institutional support: RVO:68378271 Keywords : hyperfine interactions and isotope effects * density functional theory * local density approximation * gradient and other corrections * nuclear magnetic resonance Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.736, year: 2014

  2. First-principles calculations of Moessbauer hyperfine parameters for solids and large molecules

    Energy Technology Data Exchange (ETDEWEB)

    Guenzburger, Diana [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil); Ellis, D.E. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Zeng, Z. [Academia Sinica, Hefei, AH (China). Inst. of Solid-State Physics

    1997-10-01

    Electronic structure calculations based on Density Functional theory were performed for solids and large molecules. The solids were represented by clusters of 60-100 atoms embedded in the potential of the external crystal. Magnetic moments and Moessbauer hyperfine parameters were derived. (author) 22 refs., 8 figs., 1 tab.

  3. First-principles calculations of Moessbauer hyperfine parameters for solids and large molecules

    International Nuclear Information System (INIS)

    Guenzburger, Diana; Ellis, D.E.; Zeng, Z.

    1997-10-01

    Electronic structure calculations based on Density Functional theory were performed for solids and large molecules. The solids were represented by clusters of 60-100 atoms embedded in the potential of the external crystal. Magnetic moments and Moessbauer hyperfine parameters were derived. (author)

  4. Hyperfine splitting in positronium to O(α7me). One-photon annihilation contribution

    International Nuclear Information System (INIS)

    Baker, M.; Penin, A.A.; Karlsruher Institut fuer Technologie; Piclum, J.; RWTH Aachen; Steinhauser, M.

    2014-02-01

    We present the complete result for the O(α 7 m e ) one-photon annihilation contribution to the hyperfine splitting of the ground state energy levels in positronium. Numerically it increases the prediction of quantum electrodynamics by 217±1 kHz.

  5. Man-made materials : An exciting area for hyperfine-interaction investigation

    International Nuclear Information System (INIS)

    Freeman, A.; Wu, R.

    1996-01-01

    Man-made low-dimensional magnetic systems including surfaces, interfaces and multilayers, have attracted a great amount of attention in the past decade because, as expected, the lowered symmetry and coordination number offer a variety of opportunities for inducing new and exotic phenomena and so hold out the promise of new device applications. Local spin density functional (LSDF) ab initio electronic-structure calculations employing the full-potential -linearized augmented-plane-wave (FLAPW) method have played a key role in the development of this exciting field by not only providing a clearer understanding of the experimental observations but also predicting new systems with desired properties. One of the striking successes of theory in the last decade has been the calculation of hyperfine fields at surfaces and interfaces. Concurrently, several groups have followed the pioneering work of Korecki and Gradmann and have measured hyperfine fields at surfaces and interfaces. In this paper, it is reviewed new features of hyperfine-interaction investigations in man-made materials which are essential because the hyperfine field is not proportional to the magnetization and so interpretations of experiment are totally dependent on theory

  6. 61Ni Moessbauer study of the surface hyperfine magnetic field in nickel

    International Nuclear Information System (INIS)

    Stadnik, Z.M.; Stroink, G.; Griesbach, P.; Guetlich, P.; Kohara, T.

    1988-01-01

    61 Ni Moessbauer measurements have been performed at 4.2 K on spherical Ni particles with an average diameter of 100 and 30 A, covered with a protective layer of SiO. Their spectra contain a surface component with a significantly reduced hyperfine magnetic field as compared with the field in the bulk. This result confirms recent theoretical predictions. (orig.)

  7. Towards measuring the ground state hyperfine splitting of antihydrogen – a progress report

    Energy Technology Data Exchange (ETDEWEB)

    Sauerzopf, C., E-mail: clemens.sauerzopf@oeaw.ac.at; Capon, A. A.; Diermaier, M. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Dupré, P. [Atomic Physics Laboratory, RIKEN (Japan); Higashi, Y. [University of Tokyo, Institute of Physics, Graduate School of Arts and Sciences (Japan); Kaga, C. [Hiroshima University, Graduate School of Advanced Sciences of Matter (Japan); Kolbinger, B. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Leali, M. [Università di Brescia, Dipartimento di Ingegneria dell’ Informazione (Italy); Lehner, S. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Rizzini, E. Lodi [Università di Brescia, Dipartimento di Ingegneria dell’ Informazione (Italy); Malbrunot, C. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Mascagna, V. [Università di Brescia, Dipartimento di Ingegneria dell’ Informazione (Italy); Massiczek, O. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Murtagh, D. J.; Nagata, Y.; Radics, B. [Atomic Physics Laboratory, RIKEN (Japan); Simon, M. C.; Suzuki, K. [Stefan Meyer Institute for subatomic physics, Austrian Academy of Sciences (Austria); Tajima, M. [University of Tokyo, Institute of Physics, Graduate School of Arts and Sciences (Japan); Ulmer, S. [Ulmer Initiative Research Unit, RIKEN (Japan); and others

    2016-12-15

    We report the successful commissioning and testing of a dedicated field-ioniser chamber for measuring principal quantum number distributions in antihydrogen as part of the ASACUSA hyperfine spectroscopy apparatus. The new chamber is combined with a beam normalisation detector that consists of plastic scintillators and a retractable passivated implanted planar silicon (PIPS) detector.

  8. Measurement of the magnetic hyperfine field at the 181 Ta site in nickel matrix

    International Nuclear Information System (INIS)

    Saxena, R.N.; Carbonari, A.W.; Pendl Junior, W.; Attili, R.N.; Kenchian, G.; Soares, J.C.A.C.R.; Moreno, M.S.

    1990-01-01

    The hyperfine magnetic field on the Ta 181 nucleus were determined using the gamma-gamma perturbed angular correlation method, on a nickel matrix, with a 133-482 KeV cascade from the Hf- 181 beta minus decay. (L.C.J.A.)

  9. Relativistic DFT calculations of hyperfine coupling constants in the 5d hexafluorido complexes

    DEFF Research Database (Denmark)

    Haase, Pi Ariane Bresling; Repisky, Michal; Komorovsky, Stanislav

    2018-01-01

    We have investigated the performance of the most popular relativistic density functional theory methods, zeroth order regular approximation (ZORA) and 4-component Dirac-Kohn-Sham (DKS), in the calculation of the recently measured hyperfine coupling constants of ReIV and IrIV in their hexafluorido...

  10. Magnetic hyperfine field at a Cd impurity diluted in RCo{sub 2} at finite temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, A.L. de, E-mail: alexandre.oliveira@ifrj.edu.br [Instituto Federal de Educação, Ciência e Tecnologia do Rio de Janeiro, Campus Nilópolis – RJ (Brazil); Chaves, C.M., E-mail: cmch@cbpf.br [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro (Brazil); Oliveira, N.A. de [Instituto de Física Armando Dias Tavares, Universidade do Estado do Rio de Janeiro, Rio de Janeiro (Brazil); Troper, A. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro (Brazil)

    2015-06-15

    The local magnetic moments and the magnetic hyperfine fields at an s–p Cd impurity diluted in inter-metallic Laves phase compounds RCo{sub 2} (R=Gd, Tb) at finite temperatures are calculated. For other rare earth elements (light or heavy) the pure compounds display a magnetic first order transition and are not describable by our formalism. The host has two coupled lattices (R and Co) both having itinerant d electrons but only the rare earth lattice has localized f electrons. They all contribute to the magnetization of the host and also to the local moment and to the magnetic hyperfine field at the impurity. The investigation of magnetic hyperfine field in these materials then provides valuable information on the d-itinerant electrons and also on the localized (4f) magnetic moments. For the d–d electronic interaction we use the Hubbard–Stratonovich identity thus allowing the employment of functional integral in the static saddle point approximation. Our model reproduces quite well the experimental data. - Highlights: • A functional integral method in the static limit, producing site disorder, is used. • The site disorder is treated with the coherent potential approximation (CPA) • A Friedel sum rule gives a self-consistency condition for the impurity energy. • The experimental curve of hyperfine fields×temperature is very well reproduced.

  11. Spectroscopy Apparatus for the Measurement of The Hyperfine Structure of Antihydrogen

    CERN Document Server

    Malbrunot, C.; Diermaier, M.; Dilaver, N.; Friedreich, S.; Kolbinger, B.; Lehner, S.; Lundmark, R.; Massiczek, O.; Radics, B.; Sauerzopf, C.; Simon, M.; Widmann, E.; Wolf, M.; Wünschek, B.; Zmeskal, J.

    2014-02-04

    The ASACUSA CUSP collaboration at the Antiproton Decelerator (AD) of CERN is planning to measure the ground-state hyperfine splitting of antihydrogen using an atomic spectroscopy beamline. We describe here the latest developments on the spectroscopy apparatus developed to be coupled to the antihydrogen production setup (CUSP).

  12. Towards Measuring the Ground State Hyperfine Splitting of Antihydrogen -- A Progress Report

    CERN Document Server

    Sauerzopf, C.

    2016-06-20

    We report the successful commissioning and testing of a dedicated field-ioniser chamber for measuring principal quantum number distributions in antihydrogen as part of the ASACUSA hyperfine spectroscopy apparatus. The new chamber is combined with a beam normalisation detector that consists of plastic scintillators and a retractable passivated implanted planar silicon (PIPS) detector.

  13. Investigation of the hyperfine structure of Praseodymium-transitions using laser spectroscopy

    International Nuclear Information System (INIS)

    Shamim Khan

    2011-01-01

    A comprehensive knowledge of the electron levels in an atom is one of the prerequisite for understanding the electron-electron and electron-nucleus interactions inside an atom and for the classification of the atomic spectrum of an element. The spin-orbit interaction is the largest relativistic effect and is responsible for the fine structure splitting in an atom. The hyperfine structure splitting of the fine structure atomic energy levels arise as a result of the interaction between spinning and orbiting electrons and electromagnetic multipole nuclear moments. The electronic ground state configuration of praseodymium 59 Pr 141 is [Xe] 4f 3 6s 2 , with ground state level 4 I 9/2 . Because of its 5 outer electrons Praseodymium has a high density of energy levels which give rise to an extremely line rich emission spectrum. Due to this fact praseodymium serves as an efficient testing ground for hyperfine structure studies. The thesis is mainly devoted to the finding of previously unknown energy levels by the investigation of spectral lines and their hyperfine structures. In a hollow cathode discharge lamp praseodymium atoms and ions in ground and excited states are excited to high lying states by laser light. The excitation source is a tunable ring-dye laser system, operated with Stilbene 3, Rhodamine 6G, Kiton Red, DCM and LD 700. A high resolution Fourier Transform spectrum is used for extracting excitation wavelengths. Then the laser wavelength is tuned to a strong hyperfine component of the spectral line to be investigated, and a search for fluorescence from excited levels is performed. From the observed hyperfine structure pattern, J-values and hyperfine interaction constants A of the combining levels are determined. This information, together with excitation and fluorescence wavelengths, allows us to find the energies of the involved levels. During the course of this dissertation 313 new energy levels of Pr I and 4 new energy levels of Pr II were discovered

  14. Theoretical hyperfine structures of 19F i and 17O i

    Science.gov (United States)

    Aourir, Nouria; Nemouchi, Messaoud; Godefroid, Michel; Jönsson, Per

    2018-03-01

    Multiconfiguration Hartree-Fock (MCHF) and multiconfiguration Dirac-Hartree-Fock (MCDHF) calculations are performed for the 2 p5P2o , 2 p4(3P ) 3 s 4P , 2 p4(3P ) 3 s 2P , and 2 p4(3P ) 3 p 4So states of 19F i to determine their hyperfine constants. Several computing strategies are considered to investigate electron correlation and relativistic effects. High-order correlation contributions are included in MCHF calculations based on single and double multireference expansions. The largest components of the single reference MCHF wave functions are selected to define the multireference (MR) sets. In this scheme, relativistic corrections are evaluated in the Breit-Pauli approximation. A similar strategy is used for the calculation of MCDHF relativistic wave functions and hyperfine parameters. While correlation and relativistic corrections are found to be rather small for the ground state, we highlight large relativistic effects on the hyperfine constant A3 /2 of 2 p4(3P ) 3 p 4So and, to a lesser extent, on A1 /2 of 2 p4(3P ) 3 s 4P . As expected for such a light system, electron correlation effects dominate over relativity in the calculation of the hyperfine interaction of all other levels considered. We also revisit the hyperfine constants of 2 p3(4S ) 3 s S5o and 2 p3(4S ) 3 p 5P in 17O using similar strategies. The results are found to be in excellent agreement with experiment.

  15. Partial Cancellation

    Indian Academy of Sciences (India)

    First page Back Continue Last page Overview Graphics. Partial Cancellation. Full Cancellation is desirable. But complexity requirements are enormous. 4000 tones, 100 Users billions of flops !!! Main Idea: Challenge: To determine which cross-talker to cancel on what “tone” for a given victim. Constraint: Total complexity is ...

  16. Vickers Microhardness and Hyperfine Magnetic Field Variations of Heat Treated Amorphous Fe{sub 78}Si{sub 9}B{sub 13} Alloy Ribbons

    Energy Technology Data Exchange (ETDEWEB)

    Cabral-Prieto, A., E-mail: acpr@nuclear.inin.mx [Instituto Nacional de Investigaciones Nucleares, Department of Chemistry (Mexico); Garcia-Santibanez, F.; Lopez, A.; Lopez-Castanares, R.; Olea Cardoso, O. [Universidad Autonoma del Estado de Mexico, El Cerrillo Piedras Blancas, Facultad de Ciencias (Mexico)

    2005-02-15

    Amorphous Fe{sub 78}Si{sub 9}B{sub 13} alloy ribbons were heat treated between 296 and 763 K, using heating rates between 1 and 4.5 K/min. Whereas one ribbon partially crystallized at T{sub x} = 722 K, the other one partially crystallized at T{sub x} = 763 K. The partially crystallized ribbon at 722 K, heat treated using a triangular form for the heating and cooling rates, was substantially less fragile than the partially crystallized at 763 K where a tooth saw form for the heating and cooling rates was used. Vickers microhardness and hyperfine magnetic field values behaved almost concomitantly between 296 and 673 K. The Moessbauer spectral line widths of the heat-treated ribbons decreased continuously from 296 to 500 K, suggesting stress relief in this temperature range where the Vickers microhardness did not increase. At 523 K the line width decreased further but the microhardness increased substantially. After 523 K the line width behave in an oscillating form as well as the microhardness, indicating other structural changes in addition to the stress relief. Finally, positron lifetime data showed that both inner part and surface of Fe{sub 78}Si{sub 9}B{sub 13} alloy ribbons were affected distinctly. Variations on the surface may be the cause of some of the high Vickers microhardness values measured in the amorphous state.

  17. Partial processing

    International Nuclear Information System (INIS)

    1978-11-01

    This discussion paper considers the possibility of applying to the recycle of plutonium in thermal reactors a particular method of partial processing based on the PUREX process but named CIVEX to emphasise the differences. The CIVEX process is based primarily on the retention of short-lived fission products. The paper suggests: (1) the recycle of fission products with uranium and plutonium in thermal reactor fuel would be technically feasible; (2) it would, however, take ten years or more to develop the CIVEX process to the point where it could be launched on a commercial scale; (3) since the majority of spent fuel to be reprocessed this century will have been in storage for ten years or more, the recycling of short-lived fission products with the U-Pu would not provide an effective means of making refabrication fuel ''inaccessible'' because the radioactivity associated with the fission products would have decayed. There would therefore be no advantage in partial processing

  18. Partial gigantism

    Directory of Open Access Journals (Sweden)

    М.М. Karimova

    2017-05-01

    Full Text Available A girl with partial gigantism (the increased I and II fingers of the left foot is being examined. This condition is a rare and unresolved problem, as the definite reason of its development is not determined. Wait-and-see strategy is recommended, as well as correcting operations after closing of growth zones, and forming of data pool for generalization and development of schemes of drug and radial therapeutic methods.

  19. Torsionally mediated spin-rotation hyperfine splittings at moderate to high J values in methanol

    Energy Technology Data Exchange (ETDEWEB)

    Belov, S. P.; Golubiatnikov, G. Yu.; Lapinov, A. V. [Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov Street, 603950 Nizhny Novgorod (Russian Federation); Ilyushin, V. V.; Mescheryakov, A. A. [Institute of Radio Astronomy of National Academy of Sciences of Ukraine, Chervonopraporna 4, 61002 Kharkov (Ukraine); Alekseev, E. A. [Institute of Radio Astronomy of National Academy of Sciences of Ukraine, Chervonopraporna 4, 61002 Kharkov (Ukraine); Quantum Radiophysics Department of V. N. Karazin Kharkiv National University, Svobody Square 4, 61022 Kharkov (Ukraine); Hougen, J. T., E-mail: jon.hougen@nist.gov [Sensor Science Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8441 (United States); Xu, Li-Hong [Department of Physics and Centre for Laser, Atomic, and Molecular Sciences, University of New Brunswick, Saint John, New Brunswick E2L 4L5 (Canada)

    2016-07-14

    This paper presents an explanation based on torsionally mediated proton-spin–overall-rotation interaction for the observation of doublet hyperfine splittings in some Lamb-dip sub-millimeter-wave transitions between ground-state torsion-rotation states of E symmetry in methanol. These unexpected doublet splittings, some as large as 70 kHz, were observed for rotational quantum numbers in the range of J = 13 to 34, and K = − 2 to +3. Because they increase nearly linearly with J for a given branch, we confined our search for an explanation to hyperfine operators containing one nuclear-spin angular momentum factor I and one overall-rotation angular momentum factor J (i.e., to spin-rotation operators) and ignored both spin-spin and spin-torsion operators, since they contain no rotational angular momentum operator. Furthermore, since traditional spin-rotation operators did not seem capable of explaining the observed splittings, we constructed totally symmetric “torsionally mediated spin-rotation operators” by multiplying the E-species spin-rotation operator by an E-species torsional-coordinate factor of the form e{sup ±niα}. The resulting operator is capable of connecting the two components of a degenerate torsion-rotation E state. This has the effect of turning the hyperfine splitting pattern upside down for some nuclear-spin states, which leads to bottom-to-top and top-to-bottom hyperfine selection rules for some transitions, and thus to an explanation for the unexpectedly large observed hyperfine splittings. The constructed operator cannot contribute to hyperfine splittings in the A-species manifold because its matrix elements within the set of torsion-rotation A{sub 1} and A{sub 2} states are all zero. The theory developed here fits the observed large doublet splittings to a root-mean-square residual of less than 1 kHz and predicts unresolvable splittings for a number of transitions in which no doublet splitting was detected.

  20. Torsionally mediated spin-rotation hyperfine splittings at moderate to high J values in methanol

    Science.gov (United States)

    Belov, S. P.; Golubiatnikov, G. Yu.; Lapinov, A. V.; Ilyushin, V. V.; Alekseev, E. A.; Mescheryakov, A. A.; Hougen, J. T.; Xu, Li-Hong

    2016-07-01

    This paper presents an explanation based on torsionally mediated proton-spin-overall-rotation interaction for the observation of doublet hyperfine splittings in some Lamb-dip sub-millimeter-wave transitions between ground-state torsion-rotation states of E symmetry in methanol. These unexpected doublet splittings, some as large as 70 kHz, were observed for rotational quantum numbers in the range of J = 13 to 34, and K = - 2 to +3. Because they increase nearly linearly with J for a given branch, we confined our search for an explanation to hyperfine operators containing one nuclear-spin angular momentum factor I and one overall-rotation angular momentum factor J (i.e., to spin-rotation operators) and ignored both spin-spin and spin-torsion operators, since they contain no rotational angular momentum operator. Furthermore, since traditional spin-rotation operators did not seem capable of explaining the observed splittings, we constructed totally symmetric "torsionally mediated spin-rotation operators" by multiplying the E-species spin-rotation operator by an E-species torsional-coordinate factor of the form e±niα. The resulting operator is capable of connecting the two components of a degenerate torsion-rotation E state. This has the effect of turning the hyperfine splitting pattern upside down for some nuclear-spin states, which leads to bottom-to-top and top-to-bottom hyperfine selection rules for some transitions, and thus to an explanation for the unexpectedly large observed hyperfine splittings. The constructed operator cannot contribute to hyperfine splittings in the A-species manifold because its matrix elements within the set of torsion-rotation A1 and A2 states are all zero. The theory developed here fits the observed large doublet splittings to a root-mean-square residual of less than 1 kHz and predicts unresolvable splittings for a number of transitions in which no doublet splitting was detected.

  1. Influence of radiation damage evolution on hyperfine interactions of implanted impurities: 169Tm and 175Lu in Fe

    International Nuclear Information System (INIS)

    Thome, L.; Bernas, H.; Meunier, R.

    1978-01-01

    The hyperfine interaction of 169 Tm and 175 Lu implanted in Fe and annealed, or implanted at high temperatures, was studied by time-integral and time-differential perturbed angular correlation experiments. The heat treatment was performed in order to modify the impurity-radiation damage interaction in the sample. Comparison of our results with other hyperfine interaction results on rare earths implanted in iron shows that after room-temperature implantation, all the implanted nuclei experience the same hyperfine interaction. The annealing-and implantation-temperature dependences of the fraction of nuclei experiencing this hyperfine interaction are significantly different. The results are interpreted in terms of precipitation of an increasing proportion of implanted impurities. A discussion of their relation to the implanted impurity lattice location is presented in a companion paper

  2. Determination of hyperfine-induced transition rates from observations of a planetary nebula.

    Science.gov (United States)

    Brage, Tomas; Judge, Philip G; Proffitt, Charles R

    2002-12-31

    Observations of the planetary nebula NGC3918 made with the STIS instrument on the Hubble Space Telescope reveal the first unambiguous detection of a hyperfine-induced transition 2s2p 3P(o)(0)-->2s2 1S0 in the berylliumlike emission line spectrum of N IV at 1487.89 A. A nebular model allows us to confirm a transition rate of 4x10(-4) sec(-1)+/-33% for this line. The measurement represents the first independent confirmation of the transition rate of hyperfine-induced lines in low ionization stages, and it provides support for the techniques used to compute these transitions for the determination of very low densities and isotope ratios.

  3. Fine- and hyperfine structure investigations of the even-parity configuration system of the atomic holmium

    Science.gov (United States)

    Stefanska, D.; Ruczkowski, J.; Elantkowska, M.; Furmann, B.

    2018-04-01

    In this work new experimental results concerning the hyperfine structure (hfs) for the even-parity level system of the holmium atom (Ho I) were obtained; additionally, hfs data obtained recently as a by-product in investigations of the odd-parity level system were summarized. In the present work the values of the magnetic dipole and the electric quadrupole hfs constants A and B were determined for 24 even-parity levels, for 14 of them for the first time. On the basis of these results, as well as on available literature data, a parametric study of the fine structure and the hyperfine structure for the even-parity configurations of atomic holmium was performed. A multi-configuration fit of 7 configurations was carried out, taking into account second-order of the perturbation theory. For unknown electronic levels predicted values of the level energies and hfs constants are given, which can facilitate further experimental investigations.

  4. Studies of hyperfine magnetic fields in transition metals by radioactive ion implantation

    International Nuclear Information System (INIS)

    Kawase, Yoichi; Uehara, Shin-ichi; Nasu, Saburo; Ni Xinbo.

    1994-01-01

    In order to investigate hyperfine magnetic fields in transition metals by a time-differential perturbed angular correlation (TDPAC) technique, radioactive probes of 140 Cs obtained by KUR-ISOL have been implanted on transition metals of Fe, Ni and Co. Lamor precessions of 140 Ce used as a probe nucleus have been observed clearly and the hyperfine fields have been determined precisely corresponding to implanted sites in host metal. The irradiation effects caused by implantation have been examined by annealing the irradiated specimen at about 723 K. Some of the Lamor precessions have disappeared by the annealing. Discussions have been made on the occupied sites after implantation and the recovery process of induced damages by annealing. (author)

  5. Towards isotope shift and hyperfine structure measurements of the element nobelium

    Energy Technology Data Exchange (ETDEWEB)

    Chhetri, Premaditya; Lautenschlaeger, Felix; Walther, Thomas [Institut fuer Angewandte Physik, TU Darmstadt, D-64289 Darmstadt (Germany); Laatiaoui, Mustapha [Helmholtz Institut Mainz, D-55099 Mainz (Germany); Block, Michael; Hessberger, Fritz-Peter [Helmholtz Institut Mainz, D-55099 Mainz (Germany); GSI, D-64291 Darmstadt (Germany); Lauth, Werner; Backe, Hartmut [Institut fuer Kernphysik, JGU Mainz, D-55122 Mainz (Germany); Kunz, Peter [TRIUMF, D-V6T2A3 Vancouver (Canada)

    2014-07-01

    Laser spectroscopy on the heaviest elements is of great interest as it allows the study of the evolution of relativistic effects on their atomic structure. In our experiment we exploit the Radiation Detected Resonance Ionization Spectroscopy technique and use excimer-laser pumped dye lasers to search for the first time the {sup 1}P{sub 1} level in {sup 254}No. Etalons will be used in the forthcoming experiments at GSI, Darmstadt, to narrow down the bandwidth of the dye lasers to 0.04 cm{sup -1}, for the determination of the isotope shift and hyperfine splitting of {sup 253,} {sup 255}No. In this talk results from preparatory hyperfine structure studies in nat. ytterbium and the perspectives for future experiments of the heaviest elements are discussed.

  6. Hyperfine structure in the Gd II spectrum and the nuclear electric quadrupole moment of 157Gd

    International Nuclear Information System (INIS)

    Clieves, H.P.; Steudel, A.

    1979-01-01

    The hyperfine structure of 157 Gd was investigated in 20 Gd II lines by means of a photoelectric recording Fabry-Perot interferometer with digital data processing. The hyperfine splitting factors, A and B, were obtained by computer fits to the observed line structures. Using a multiconfigurational set of wave functions in intermediate coupling derived by Wyart, mono-electronic parameters were deduced by a parametric treatment. The nuclear electric quadrupole moment of 157 Gd was evaluated from the quadrupole interaction of the 5d electron in 4f 7 5d6s, the 5d electron in 4f 7 5d6p, and the 6p electron in 4f 7 5d6p. The three values obtained for the quadrupole moment agree very well. The final result, corrected for Sternheimer shielding, is Q( 157 Gd) = 1.34(7) x 10 -24 cm 2 . (orig.) [de

  7. Development of atomic spectroscopy technologies - Hyperfine structure of 2 period atoms using optogalvanic effects

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Nam Ic [Hankuk University of foreign studies, Seoul (Korea)

    2000-03-01

    The source of anomalous broad linewidth of 3{sup 3}P{sub 1},{sub 2},{sub 3}-3{sup 3}D{sub 2},{sub 3},4(3s') transition was explained. The broad optogalvanic spectrum was consisted of two gaussian peaks of different linewidths, and they are separated by 250 MHz. The Narrow peak, which has linewidth of room temperature, is from oxygen atoms already separated, and the shifted broad peak, which has linewidth corresponding to a temperature of 9000 K, is from weakly bound molecular ions. Obtained hyperfine spectrum of fluorine atom at the expected frequency, was too weak to analyze hyperfine structure constants. Microwave discharge might be necessary for higher density of excited state. 16 refs., 11 figs. (Author)

  8. Derivation of the electric dipole--dipole interaction as an electric hyperfine interaction

    International Nuclear Information System (INIS)

    Parker, G.W.

    1986-01-01

    The electric dipole--dipole interaction is derived by assuming that the electron and proton in hydrogen have intrinsic electric dipole moments that interact to give an electric hyperfine interaction. The electric field at the proton due to the electron's presumed dipole moment then gives rise to a contact type term for l = 0 and the normal dipole--dipole term for lnot =0. When combined with our previous derivation of the magnetic hyperfine interaction [Am. J. Phys. 52, 36 (1984)], which used a similar approach, these derivations provide a unified treatment of the interaction of electric and magnetic dipoles. As an application of these results, the product of the electron's and proton's dipole moments is estimated to be less than 10 -29 e 2 cm 2

  9. Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

    Energy Technology Data Exchange (ETDEWEB)

    Adam, Ahmad Y.; Jensen, Per, E-mail: jensen@uni-wuppertal.de [Fakultät Mathematik und Naturwissenschaften, Physikalische und Theoretische Chemie, Bergische Universität Wuppertal, D-42097 Wuppertal (Germany); Yachmenev, Andrey; Yurchenko, Sergei N. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2015-12-28

    We present the first variational calculation of the isotropic hyperfine coupling constant of the carbon-13 atom in the CH{sub 3} radical for temperatures T = 0, 96, and 300 K. It is based on a newly calculated high level ab initio potential energy surface and hyperfine coupling constant surface of CH{sub 3} in the ground electronic state. The ro-vibrational energy levels, expectation values for the coupling constant, and its temperature dependence were calculated variationally by using the methods implemented in the computer program TROVE. Vibrational energies and vibrational and temperature effects for coupling constant are found to be in very good agreement with the available experimental data. We found, in agreement with previous studies, that the vibrational effects constitute about 44% of the constant’s equilibrium value, originating mainly from the large amplitude out-of-plane bending motion and that the temperature effects play a minor role.

  10. Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

    Science.gov (United States)

    Adam, Ahmad Y.; Yachmenev, Andrey; Yurchenko, Sergei N.; Jensen, Per

    2015-12-01

    We present the first variational calculation of the isotropic hyperfine coupling constant of the carbon-13 atom in the CH3 radical for temperatures T = 0, 96, and 300 K. It is based on a newly calculated high level ab initio potential energy surface and hyperfine coupling constant surface of CH3 in the ground electronic state. The ro-vibrational energy levels, expectation values for the coupling constant, and its temperature dependence were calculated variationally by using the methods implemented in the computer program TROVE. Vibrational energies and vibrational and temperature effects for coupling constant are found to be in very good agreement with the available experimental data. We found, in agreement with previous studies, that the vibrational effects constitute about 44% of the constant's equilibrium value, originating mainly from the large amplitude out-of-plane bending motion and that the temperature effects play a minor role.

  11. Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

    International Nuclear Information System (INIS)

    Adam, Ahmad Y.; Jensen, Per; Yachmenev, Andrey; Yurchenko, Sergei N.

    2015-01-01

    We present the first variational calculation of the isotropic hyperfine coupling constant of the carbon-13 atom in the CH 3 radical for temperatures T = 0, 96, and 300 K. It is based on a newly calculated high level ab initio potential energy surface and hyperfine coupling constant surface of CH 3 in the ground electronic state. The ro-vibrational energy levels, expectation values for the coupling constant, and its temperature dependence were calculated variationally by using the methods implemented in the computer program TROVE. Vibrational energies and vibrational and temperature effects for coupling constant are found to be in very good agreement with the available experimental data. We found, in agreement with previous studies, that the vibrational effects constitute about 44% of the constant’s equilibrium value, originating mainly from the large amplitude out-of-plane bending motion and that the temperature effects play a minor role

  12. The hyperfine structure constants for the 4s24p and 4s25s states of Ga

    International Nuclear Information System (INIS)

    Wang Qingmin; Dong Chenzhong

    2012-01-01

    The hyperfine structure (hfs) constants for the states 4s 2 4p 2 P 1/2,3/2 and 4s 2 5s 2 S 1/2 of 71 Ga were calculated using the GRASP2K package based on the multiconfiguration Dirac-Fock (MCDF) method. The results indicated that the core polarization effect was important for the hyperfine structure constants. (authors)

  13. Hyperfine transition in 209Bi80+—one step forward

    International Nuclear Information System (INIS)

    Sánchez, R; Andelkovic, Z; Geithner, W; König, K; Litvinov, Yu A; Maaß, B; Ullmann, J; Geppert, Ch; Gorges, Ch; Lochmann, M; Nörtershäuser, W; Schmidt, S; Vollbrecht, J; Hannen, V; Dax, A; Hammen, M; Kaufmann, S; Meisner, J; Schmidt, M; Murböck, T

    2015-01-01

    The hyperfine transitions in lithium-like and hydrogen-like bismuth were remeasured by direct laser spectroscopy at the experimental storage ring. For this we have now employed a voltage divider which enabled us to monitor the electron cooler voltage in situ. This will improve the experimental accuracy by about one order of magnitude with respect to our previous measurement using the same technique. (paper)

  14. Fine-hyperfine splittings of quarkonium levels in an effective power-law potential

    Energy Technology Data Exchange (ETDEWEB)

    Barik, N; Jena, S N [Utkal Univ., Bhubaneswar (India). Dept. of Physics

    1980-12-01

    We have shown that an effective non-coulombic power-law potential generating spin dependence through scalar and vector exchanges in almost equal proportions along with a very small or zero quark anomalous moment can describe very satisfactorily the up-to-date data on the fine-hyperfine levels and the leptonic width ratios of the vector mesons in the cc and bb families in a flavour independent manner.

  15. Fine-hyperfine splittings of quarkonium levels in an effective power-law potential

    International Nuclear Information System (INIS)

    Barik, N.; Jena, S.N.

    1980-01-01

    We have shown that an effective non-coulombic power-law potential generating spin dependence through scalar and vector exchanges in almost equal proportions along with a very small or zero quark anomalous moment can describe very satisfactorily the up-to-date data on the fine-hyperfine levels and the leptonic width ratios of the vector mesons in the cc and bb families in a flavour independent manner. (orig.)

  16. Nuclear spin of 185Au and hyperfine structure of 188Au

    International Nuclear Information System (INIS)

    Ekstroem, C.; Ingelman, S.; Wannberg, G.

    1977-03-01

    The nuclear spin of 185 Au, I = 5/2, and the hyperfine separation of 188 Au, Δγ = +- 2992(30) MHz, have been measured with the atomic-beam magnetic resonance method. The spin of 185 Au indicates a deformed nuclear shape in the ground state. The small magnetic moment of 188 Au is close in value to those of the heavier I = 1 gold isotopes 190 192 194 Au, being located in a typical transition region. (Auth.)

  17. Hyperfine interactions of {beta}-emitter {sup 12}N in TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, Yukiko [Osaka Univ., Toyonaka (Japan). Faculty of Science; Izumikawa, Takuji; Tanigaki, Minoru [and others

    1997-03-01

    Hyperfine interactions of {beta}-emitter {sup 12}N (I{sup {pi}} = 1{sup -}, T{sub 1/2} 11ms) in TiO{sub 2} has been studied. A {beta}-NMR spectrum on the polarized {sup 12}N implanted in TiO{sub 2} shows that {sup 12}N are located at two different sites and maintain about 100% of initial polarization. These are the first phenomena observed in ionic crystals. (author)

  18. The contribution of pseudoscalar mesons to hyperfine structure of muonic hydrogen

    International Nuclear Information System (INIS)

    Dorokhov, A.E.; Kochelev, N.I.; Martynenko, A.P.; Martynenko, F.A.; Faustov, R.N.

    2017-01-01

    In the framework of the quasipotential method in quantum electrodynamics we calculate the contribution of pseudoscalar mesons to the interaction operator of a muon and a proton in muonic hydrogen atom. The parametrization of the transition form factor of two photons into π, η mesons, based on the experimental data on the transition form factors and QCD asymptotics is used. Numerical estimates of the contributions to the hyperfine structure of the spectrum of the S and P levels are presented.

  19. The contribution of pseudoscalar mesons to hyperfine structure of muonic hydrogen

    OpenAIRE

    Dorokhov, A. E.; Kochelev, N. I.; Martynenko, A. P.; Martynenko, F. A.; Faustov, R. N.

    2017-01-01

    In the framework of the quasipotential method in quantum electrodynamics we calculate the contribution of pseudoscalar mesons to the interaction operator of a muon and a proton in muonic hydrogen atom. The parametrization of the transition form factor of two photons into $\\pi$, $\\eta$ mesons, based on the experimental data on the transition form factors and QCD asymptotics is used. Numerical estimates of the contributions to the hyperfine structure of the spectrum of the S and P levels are pr...

  20. The contribution of axial-vector mesons to hyperfine structure of muonic hydrogen

    OpenAIRE

    Dorokhov, A. E.; Kochelev, N. I.; Martynenko, A. P.; Martynenko, F. A.; Radzhabov, A. E.

    2017-01-01

    The contribution from the axial-vector meson exchange to the potential of the muon–proton interaction in muonic hydrogen induced by anomalous axial-vector meson coupling to two photon state is calculated. It is shown that such contribution to the hyperfine splitting in muonic hydrogen is large and important for a comparison with precise experimental data. In the light of our result, the proton radius “puzzle” is discussed.

  1. Theoretical study of hyperfine fields due to S-P and transition impurities in gadolinium matrix

    International Nuclear Information System (INIS)

    Santos Leal, C.E. dos.

    1985-01-01

    This work presents a systematic theoretical study for the hyperfine field due to diluted s-p-and transition impurities in metallic gadolinium matrices. The peculiarities de a gadolinium matrix are shown, they are characterized by a semi-completed 4f-shell, which is far from (below) the energetic levels such as the type s-p and d-conduction bands. (author)

  2. Hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements

    International Nuclear Information System (INIS)

    Michel, J.

    1969-01-01

    We have studied the hyperfine coupling in gadolinium-praseodymium alloys by specific heat measurements down to 0.3 K. In the first part we describe the apparatus used to perform our measurements. The second part is devoted to some theoretical considerations. We have studied in detail the case of praseodymium which is an exception in the rare earth series. The third part shows the results we have obtained. (author) [fr

  3. Computation of the hyperfine structure in the (α-μ- e-)0 atom

    International Nuclear Information System (INIS)

    Amusia, M.Ya.; Kuchiev, M.Ju.; Yakhontov, V.L.

    1983-01-01

    Computation of the ground-state hyperfine splitting of neutral muonic helium (α-μ - e - ) 0 has been carried out. Account of two terms in the expansion of this quantity in power series of a small parameter #betta# of the order of msub(e)/msub(μ) of the order of 1/200 results in the energy splitting value δ#betta# = 4462.9 MHz in good agreement with previously obtained experimental and theoretical values. (author)

  4. Contribution to the theoretical study of metallic systems containing rare earths: hyperfine interactions and exchange coupling

    International Nuclear Information System (INIS)

    Troper, A.

    1978-01-01

    A theoretical study involving rare earth impurities, which were embedded in transition metals (s-p or noble), from the point of view of the hyperfine interactions is presented. A model was created to describe a d-resonance (Anderson-Moriya) acting on a s-p conduction band which was strongly perturbed by a slater-koster potential, used to describe the rare earths which were diluted in matrices of transition elements. (author)

  5. New precise measurement of muonium hyperfine structure interval at J-PARC

    Energy Technology Data Exchange (ETDEWEB)

    Ueno, Y., E-mail: yueno@radphys4.c.u-tokyo.ac.jp [University of Tokyo, Graduate School of Arts and Sciences (Japan); Aoki, M. [Osaka University, Graduate School of Science (Japan); Fukao, Y. [KEK (Japan); Higashi, Y.; Higuchi, T. [University of Tokyo, Graduate School of Arts and Sciences (Japan); Iinuma, H.; Ikedo, Y. [KEK (Japan); Ishida, K. [RIKEN (Japan); Ito, T. U. [Japan Atomic Energy Agency (Japan); Iwasaki, M. [RIKEN (Japan); Kadono, R. [KEK (Japan); Kamigaito, O. [RIKEN (Japan); Kanda, S. [University of Tokyo, Department of Physics (Japan); Kawall, D. [University of Massachusetts, Amherst, Department of Physics (United States); Kawamura, N.; Koda, A.; Kojima, K. M. [KEK (Japan); Kubo, M. K. [International Christian University, Graduate School of Arts and Science (Japan); Matsuda, Y. [University of Tokyo, Graduate School of Arts and Sciences (Japan); Mibe, T. [KEK (Japan); and others

    2017-11-15

    MuSEUM is an international collaboration aiming at a new precise measurement of the muonium hyperfine structure at J-PARC (Japan Proton Accelerator Research Complex). Utilizing its intense pulsed muon beam, we expect a ten-fold improvement for both measurements at high magnetic field and zero magnetic field. We have developed a sophisticated monitoring system, including a beam profile monitor to measure the 3D distribution of muonium atoms to suppress the systematic uncertainty.

  6. Higher order Stark effect and transition probabilities on hyperfine structure components of hydrogen like atoms

    Energy Technology Data Exchange (ETDEWEB)

    Pal' chikov, V.G. [National Research Institute for Physical-Technical and Radiotechnical Measurements - VNIIFTRI (Russian Federation)], E-mail: vitpal@mail.ru

    2000-08-15

    A quantum-electrodynamical (QED) perturbation theory is developed for hydrogen and hydrogen-like atomic systems with interaction between bound electrons and radiative field being treated as the perturbation. The dependence of the perturbed energy of levels on hyperfine structure (hfs) effects and on the higher-order Stark effect is investigated. Numerical results have been obtained for the transition probability between the hfs components of hydrogen-like bismuth.

  7. Investigation of hyperfine interactions in DNA nitrogenous bases using perturbed angular correlation spectroscopy

    International Nuclear Information System (INIS)

    Silva, Andreia dos Santos; Carbonari, Artur Wilson; Lapolli, Andre Luis; Saxena, Rajendra Narain; Saitovitch, Henrique

    2013-01-01

    Perturbed γγ angular correlations (PAC) spectroscopy has been used to study the DNA nitrogenous bases (adenine, cytosine, guanine, thymine), using 111 In→ 111 Cd and 111m Cd→ 111 Cd probe nuclei. One of the advantages of applying PAC technique to biological molecules is that the experiments can be carried out on molecules in aqueous solution [1], approaching the function of molecules under conditions that are close to in vivo conditions. The measurements were carried out for DNA nitrogenous bases molecules at 295 K and 77 K in order to investigate dynamic and static hyperfine interactions, respectively. The interpretation of the results was based on the measurements of dynamic interaction characterized by the decay constant from which valuable information on the macroscopic behavior of the molecules was obtained [2; 3]. On the other hand, PAC measurements at low temperature showed interaction frequency (ν Q ), asymmetry parameter (η) and the distribution of the quadrupole frequency (δ). These parameters provide a local microscopic description of the chemical environment in the neighborhood of the probe nuclei. Results showed differences in the hyperfine interactions of probe nuclei bound to the studied biomolecules. Such differences were observed by variations in the hyperfine parameters, which depended on the type of biomolecule and the results also showed that the probe nuclei bounded at the molecules in some cases and at others did not. (author)

  8. Hyperfine structure analysis in magnetic resonance spectroscopy: from astrophysical measurements towards endogenous biosensors in human tissue

    International Nuclear Information System (INIS)

    Schroeder, L.; California Univ., Berkeley, CA; Lawrence Berkeley National Lab., Berkeley, CA

    2007-01-01

    The hyperfine interaction of two spins is a well studied effect in atomic systems. Magnetic resonance experiments demonstrate that the detectable dipole transitions are determined by the magnetic moments of the constituents and the external magnetic field. Transferring the corresponding quantum mechanics to molecular bound nuclear spins allows for precise prediction of NMR spectra obtained from metabolites in human tissue. This molecular hyperfine structure has been neglected so far in in vivo NMR spectroscopy but contains useful information, especially when studying molecular dynamics. This contribution represents a review of the concept of applying the Breit-Rabi formalism to coupled nuclear spins and discusses the immobilization of different metabolites in anisotropic tissue revealed by 1H NMR spectra of carnosine, phosphocreatine and taurine. Comparison of atomic and molecular spin systems allows for statements on the biological constraints for direct spin-spin interactions. Moreover, the relevance of hyperfine effects on the line shapes of multiplets of indirectly-coupled spin systems with more than two constituents can be predicted by analyzing quantum mechanical parameters. As an example, the superposition of eigenstates of the AMX system of adenosine 5'-triphosphate and its application for better quantification of 31P-NMR spectra will be discussed. (orig.)

  9. [Hyperfine structure analysis in magnetic resonance spectroscopy: from astrophysical measurements towards endogenous biosensors in human tissue].

    Science.gov (United States)

    Schröder, Leif

    2007-01-01

    The hyperfine interaction of two spins is a well studied effect in atomic systems. Magnetic resonance experiments demonstrate that the detectable dipole transitions are determined by the magnetic moments of the constituents and the external magnetic field. Transferring the corresponding quantum mechanics to molecular bound nuclear spins allows for precise prediction of NMR spectra obtained from metabolites in human tissue. This molecular hyperfine structure has been neglected so far in in vivo NMR spectroscopy but contains useful information, especially when studying molecular dynamics. This contribution represents a review of the concept of applying the Breit-Rabi formalism to coupled nuclear spins and discusses the immobilization of different metabolites in anisotropic tissue revealed by 1H NMR spectra of carnosine, phosphocreatine and taurine. Comparison of atomic and molecular spin systems allows for statements on the biological constraints for direct spin-spin interactions. Moreover, the relevance of hyperfine effects on the line shapes of multiplets of indirectly-coupled spin systems with more than two constituents can be predicted by analyzing quantum mechanical parameters. As an example, the superposition of eigenstates of the A MX system of adenosine 5'-triphosphate and its application for better quantification of 31P-NMR spectra will be discussed.

  10. Calculation of the hyperfine interaction using an effective-operator form of many-body theory

    International Nuclear Information System (INIS)

    Garpman, S.; Lindgren, I.; Lindgren, J.; Morrison, J.

    1975-01-01

    The effective-operator form of many-body theory is reviewed and applied to the calculation of the hyperfine structure. Numerical results are given for the 2p, 3p, and 4p excited states of Li and the 3p state of Na. This is the first complete calculation of the hyperfine structure using an effective-operator form of perturbation theory. As in the Brueckner-Goldstone form of many-body theory, the various terms in the perturbation expansion are represented by Feynman diagrams which correspond to basic physical processes. The angular part of the perturbation diagrams are evaluated by taking advantage of the formal analogy between the Feynman diagrams and the angular-momentum diagrams, introduced by Jucys et al. The radial part of the diagrams is calculated by solving one- and two-particle equations for the particular linear combination of excited states that contribute to the Feynman diagrams. In this way all second- and third-order effects are accurately evaluated without explicitly constructing the excited orbitals. For the 2p state of Li our results are in agreement with the calculations of Nesbet and of Hameed and Foley. However, our quadrupole calculation disagrees with the work of Das and co-workers. The many-body results for Li and Na are compared with semiempirical methods for evaluating the quadrupole moment from the hyperfine interaction, and a new quadrupole moment of 23 Na is given

  11. Investigation of ferromagnetic spinel semiconductors by hyperfine interactions of implanted nuclear probes

    CERN Document Server

    Samokhvalov, V; Dietrich, M; Schneider, F; Tiginyanu, I M; Tsurkan, V; Unterricker, S

    2003-01-01

    The semiconducting ferromagnetic spinel compounds CdCr//2Se //4, CdCr //2S//4, HgCr//2Se//4 and CuCr//2Se//4 (metallic) were investigated by the perturbed angular correlations (PAC) method with the radioactive probes **1**1**1In, **1**1**1**mCd, **1**1**1Ag, **1**1**7Cd, **1**9**9**mHg and **7**7Br. The probes were implanted at the ISOLDE on-line separator (CERN-Geneva) into single crystals. From the time dependence of the PAC spectra and the measured hyperfine interaction parameters: electric field gradient and magnetic hyperfine field, the probe positions and the thermal behavior of the probes could be determined. Cd, Ag and Hg are substituted at the A-site, In at the A- and B-site in the semiconducting compounds and Br at the anion position. Electric and magnetic hyperfine fields were used as test quantities for theoretical charge and spin density distributions of LAPW calculations (WIEN97).

  12. Vibrational Averaging of the Isotropic Hyperfine Coupling Constants for the Methyl Radical

    Science.gov (United States)

    Adam, Ahmad; Jensen, Per; Yachmenev, Andrey; Yurchenko, Sergei N.

    2014-06-01

    Electronic contributions to molecular properties are often considered as the major factor and usually reported in the literature without ro-vibrational corrections. However, there are many cases where the nuclear motion contributions are significant and even larger than the electronic contribution. In order to obtain accurate theoretical predictions, nuclear motion effects on molecular properties need to be taken into account. The computed isotropic hyperfine coupling constants for the nonvibrating methyl radical CH_3 are far from the experimental values. For CH_3, we have calculated the vibrational-state-dependence of the isotropic hyperfine coupling constant in the electronic ground state. The vibrational wavefunctions used in the averaging procedure were obtained variationally with the TROVE program. Analytical representations for the potential energy surfaces and the hyperfine coupling constant surfaces are obtained in least-squares fitting procedures. Thermal averaging has been carried out for molecules in thermal equilibrium, i.e., with Boltzmann-distributed populations. The calculation methods and the results will be discussed in detail.

  13. Comprehensive Wavelengths, Energy Levels, and Hyperfine Structure Parameters of Singly-Ionized Iron-Group Elements

    Science.gov (United States)

    Nave, Gillian

    We propose to measure wavelengths, energy levels, and hyperfine structure parameters of Ni II, Mn II, Sc II and other singly-ionized iron-group elements, covering the wavelength range 80 nm to 5500 nm. We shall use archival data from spectrometers at NIST and Kitt Peak National Observatory for spectra above 140 nm. Additional experimental observations will be taken if needed using Fourier transform spectrometers at NIST. Spectra will be taken using our normal incidence grating spectrograph to provide better sensitivity than the FT spectra and to extend the wavelength range down to 80 nm. We aim to produce a comprehensive description of the spectra of all singly-ionized iron- group elements. The wavelength uncertainty of the strong lines will be better than 1 part in 10^7. For most singly-ionized iron-group elements available laboratory data have uncertainties an order of magnitude larger than astronomical observations over wide spectra ranges. Some of these laboratory measurements date back to the 1960's. Since then, Fourier transform spectroscopy has made significant progress in improving the accuracy and quantity of data in the UV-vis-IR region, but high quality Fourier transform spectra are still needed for Mn II, Ni II and Sc II. Fourier transform spectroscopy has low sensitivity in the VUV region and is limited to wavelengths above 140 nm. Spectra measured with high-resolution grating spectrographs are needed in this region in order to obtain laboratory data of comparable quality to the STIS and COS spectrographs on the Hubble Space Telescope. Currently, such data exist only for Fe II and Cr II. Lines of Sc II, V II, and Mn II show hyperfine structure, but hyperfine structure parameters have been measured for relatively few lines of these elements. Significant errors can occur if hyperfine structure is neglected when abundances are determined from stellar spectra. Measurements of hyperfine structure parameters will be made using Fourier transform spectroscopy

  14. Hyperfine structure investigation of the first excited state 4Isub(13/2) (5,418-1) in Holmium-165 by the atomic beam resonance method

    International Nuclear Information System (INIS)

    Aldenhoven, R.

    1976-01-01

    By the method of atomic beam resonance the hyperfine structure of the first excited state 4 Isub(13/2) (5418 cm -1 ) of 165 Holmium was studied for the first time. Using a suitable ΔF = 0 transition, the gsub(J)-factor was measured. After a determination of estimates for the hyperfine constants A and B from two suitably chosen ΔF = 0 transitions, the hyperfine splittings have been measured. (orig./WL) [de

  15. Hyperfine structure in 229gTh3+ as a probe of the 229gTh→ 229mTh nuclear excitation energy.

    Science.gov (United States)

    Beloy, K

    2014-02-14

    We identify a potential means to extract the 229gTh→ 229mTh nuclear excitation energy from precision microwave spectroscopy of the 5F(5/2,7/2) hyperfine manifolds in the ion 229gTh3+. The hyperfine interaction mixes this ground fine structure doublet with states of the nuclear isomer, introducing small but observable shifts to the hyperfine sublevels. We demonstrate how accurate atomic structure calculations may be combined with the measurement of the hyperfine intervals to quantify the effects of this mixing. Further knowledge of the magnetic dipole decay rate of the isomer, as recently reported, allows an indirect determination of the nuclear excitation energy.

  16. Operation: Inherent Resolve

    DEFF Research Database (Denmark)

    Cramer-Larsen, Lars

    2015-01-01

    Kapitlet giver læseren indsigt i den internationale koalitions engagement mod IS igennem Operaton Inherent Resolve; herunder koalitionens strategi i forhold til IS strategi, ligesom det belyser kampagnens legalitet og folkeretlige grundlag, ligesom det giver et bud på overvejelser om kampagnens...

  17. Hyperfine interaction in the Autler-Townes effect: The formation of bright, dark, and chameleon states

    Science.gov (United States)

    Kirova, T.; Cinins, A.; Efimov, D. K.; Bruvelis, M.; Miculis, K.; Bezuglov, N. N.; Auzinsh, M.; Ryabtsev, I. I.; Ekers, A.

    2017-10-01

    This paper is devoted to clarifying the implications of hyperfine (HF) interaction in the formation of adiabatic (i.e., "laser-dressed") states and their expression in the Autler-Townes (AT) spectra. We first use the Morris-Shore model [J. R. Morris and B. W. Shore, Phys. Rev. A 27, 906 (1983), 10.1103/PhysRevA.27.906] to illustrate how bright and dark states are formed in a simple reference system where closely spaced energy levels are coupled to a single state with a strong laser field with the respective Rabi frequency ΩS. We then expand the simulations to realistic hyperfine level systems in Na atoms for a more general case when non-negligible HF interaction can be treated as a perturbation in the total system Hamiltonian. A numerical analysis of the adiabatic states that are formed by coupling of the 3 p3 /2 and 4 d5 /2 states by the strong laser field and probed by a weak laser field on the 3 s1 /2-3 p3 /2 transition yielded two important conclusions. Firstly, the perturbation introduced by the HF interaction leads to the observation of what we term "chameleon" states—states that change their appearance in the AT spectrum, behaving as bright states at small to moderate ΩS, and fading from the spectrum similarly to dark states when ΩS is much larger than the HF splitting of the 3 p3 /2 state. Secondly, excitation by the probe field from two different HF levels of the ground state allows one to address orthogonal sets of adiabatic states; this enables, with appropriate choice of ΩS and the involved quantum states, a selective excitation of otherwise unresolved hyperfine levels in excited electronic states.

  18. Study of hyperfine parameters in Co-doped tin dioxide using PAC spectroscopy

    International Nuclear Information System (INIS)

    Ramos, Juliana M.; Carbonari, Artur W.; Martucci, Thiago; Costa, Messias S.; Saxena, Rajendra N.; Vianden, R.; Kessler, P.; Geruschke, T.; Steffens, M.

    2011-01-01

    PAC technique has been used to measure the hyperfine interactions in nano-structured powder samples of semiconducting SnO 2 doped with Co. The aim of this work is to compare the results of PAC measurements using two different techniques of introducing the radioactive 111 In probe nuclei in the sample of SnO 2 doped with Co. The perturbed gamma-gamma angular correlation (PAC) spectroscopy is used for the measurements of the magnetic hyperfine field (MHF) and the electric field gradient (EFG) at 111 Cd sites in SnO 2 doped with 1% and 2% Co. The measurement of EFG is used to study the defects introduced in the semiconductor material and also for the identification of different phases formed within the compound. The techniques utilized for introducing the radioactive 111 In in the sample are the ion-implantation using radioactive ion beam of 111 In and the chemical process in which 111 InCl 3 solution is added during the preparation of SnO 2 doped with Co using sol gel method. The ion-implantation of 111 In in SnO 2 doped with Co was carried out using the University of Bonn ion-implanter with beam energy of 160 keV. The PAC measurements were carried out with four BaF 2 detector gamma spectrometer in the temperature range of 10-295 K. The results show no significant difference in the values of hyperfine parameters. Both techniques show practically the same electric quadrupole interaction for the substitutional site. The results were compared with previous PAC and Moessbauer measurements of SnO 2 powder samples using 111 In- 111 Cd probe. (author)

  19. Study of hyperfine parameters in Co-doped tin dioxide using PAC spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ramos, Juliana M.; Carbonari, Artur W.; Martucci, Thiago; Costa, Messias S.; Saxena, Rajendra N. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Vianden, R.; Kessler, P.; Geruschke, T.; Steffens, M., E-mail: vianden@hiskp.uni-bonn.d [Rheinische Friedrich-Wilhelms-Universitaet Bonn (HISKP- Bonn) (Germany). Helmholtz - Institut fuer Strahlen- und Kernphysik

    2011-07-01

    PAC technique has been used to measure the hyperfine interactions in nano-structured powder samples of semiconducting SnO{sub 2} doped with Co. The aim of this work is to compare the results of PAC measurements using two different techniques of introducing the radioactive {sup 111}In probe nuclei in the sample of SnO{sub 2} doped with Co. The perturbed gamma-gamma angular correlation (PAC) spectroscopy is used for the measurements of the magnetic hyperfine field (MHF) and the electric field gradient (EFG) at {sup 111}Cd sites in SnO{sub 2} doped with 1% and 2% Co. The measurement of EFG is used to study the defects introduced in the semiconductor material and also for the identification of different phases formed within the compound. The techniques utilized for introducing the radioactive {sup 111}In in the sample are the ion-implantation using radioactive ion beam of {sup 111}In and the chemical process in which {sup 111}InCl{sub 3} solution is added during the preparation of SnO{sub 2} doped with Co using sol gel method. The ion-implantation of {sup 111}In in SnO{sub 2} doped with Co was carried out using the University of Bonn ion-implanter with beam energy of 160 keV. The PAC measurements were carried out with four BaF{sub 2} detector gamma spectrometer in the temperature range of 10-295 K. The results show no significant difference in the values of hyperfine parameters. Both techniques show practically the same electric quadrupole interaction for the substitutional site. The results were compared with previous PAC and Moessbauer measurements of SnO{sub 2} powder samples using {sup 111}In-{sup 111}Cd probe. (author)

  20. Optical dephasing, hyperfine structure, and hyperfine relaxation associated with the 580.8-nm 7F0-5D0 transition of europium in Eu/sup 3+/:Y2O3

    International Nuclear Information System (INIS)

    Babbitt, W.R.; Lezama, A.; Mossberg, T.W.

    1989-01-01

    We have employed spectral-hole-burning, coherent-transient, and optical-rf double-resonance techniques to measure various parameters associated with the 580.8-nm 7 F 0 - 5 D 0 transition of Eu/sup 3+/ doped into Y 2 O 3 . In particular, we have measured the hyperfine splittings of the terminal levels (for both /sup 151/Eu and /sup 153/Eu), an effective thermalization rate of the ground-state ( 7 F 0 ) hyperfine manifold over the temperature range of ≅4--15 K, and the homogeneous linewidth of the optical transition over the range of ≅14--35 K. Large ratios of inhomogeneous to homogeneous linewidth at elevated temperatures (10 3 at 25 K) and long ground-state hyperfine thermalization times (>30 h at 4 K) make this an interesting crystal in the context of spectrally addressable optical memories

  1. Design of a spin-flip cavity for the measurement of the antihydrogen hyperfine structure

    CERN Document Server

    Kroyer, T

    2008-01-01

    In the framework of the ASACUSA collaboration at the CERN Antiproton Decelerator an experiment for precisely testing the CPT invariance of the hydrogen hyperfine structure is currently being designed. An integral part of the set-up is the 1.42 GHz spin-flipping cavity, which should have a good field homogeneity over the large aperture of the antihydrogen beam. After the evaluation of various approaches a structure based on a resonant stripline is proposed as a concrete cavity design. For this structure the field homogeneity, undesired modes, coupling and power issues are discussed in detail.

  2. Chemically induced dynamic nuclear polarization in systems containing large hyperfine coupling constants

    International Nuclear Information System (INIS)

    Roth, H.D.; Hutton, R.S.; Hwang, Kuochu; Turro, N.J.; Welsh, K.M.

    1989-01-01

    Nuclear spin polarization effects induced in radical pairs with one or more strong ( 13 C) hyperfine coupling constants have been evaluated. The pairs were generated by photoinduced α-cleavage or hydrogen abstraction reactions of carbonyl compounds. Several examples illustrate how changes in the magnetic field strength (H 0 ) and the g-factor difference (Δg) affect the general appearance of the resulting CIDNP multiplets. The results bear out an earlier caveat concerning the qualitative interpretation of CIDNP effects observed for multiplets

  3. Ab Initio Calculation of Hyperfine Interaction Parameters: Recent Evolutions, Recent Examples

    International Nuclear Information System (INIS)

    Cottenier, Stefaan; Vanhoof, Veerle; Torumba, Doru; Bellini, Valerio; Cakmak, Mehmet; Rots, Michel

    2004-01-01

    For some years already, ab initio calculations based on Density Functional Theory (DFT) belong to the toolbox of the field of hyperfine interaction studies. In this paper, the standard ab initio approach is schematically sketched. New features, methods and possibilities that broke through during the past few years are listed, and their relation to the standard approach is explained. All this is illustrated by some highlights of recent ab initio work done by the Nuclear Condensed Matter Group at the K.U.Leuven.

  4. Cryogenic tunable microwave cavity at 13GHz for hyperfine spectroscopy of antiprotonic helium

    International Nuclear Information System (INIS)

    Sakaguchi, J.; Gilg, H.; Hayano, R.S.; Ishikawa, T.; Suzuki, K.; Widmann, E.; Yamaguchi, H.; Caspers, F.; Eades, J.; Hori, M.; Barna, D.; Horvath, D.; Juhasz, B.; Torii, H.A.; Yamazaki, T.

    2004-01-01

    For the precise measurement of the hyperfine structure of antiprotonic helium, microwave radiation of 12.9GHz frequency is needed, tunable over +/-100MHz. A cylindrical microwave cavity is used whose front and rear faces are meshed to allow the antiprotons and laser beams to enter. The cavity is embedded in a cryogenic helium gas target. Frequency tuning of ∼300MHz with Q values of 2700-3000 was achieved using over-coupling and an external triple stub tuner. We also present Monte-Carlo simulations of the stopping distribution of antiprotons in the low-density helium gas using the GEANT4 package with modified energy loss routines

  5. Hyperfine electric parameters calculation in Si samples irradiated with 57Mn

    International Nuclear Information System (INIS)

    Abreu, Y.; Cruz, C. M.; Pinnera, I.; Leyva, A.; Van Espen, P.; Perez, C.

    2011-01-01

    The radiation damage created in silicon crystalline material by 57 Mn→ 57 Fe ion implantation was characterized by Moessbauer spectroscopy showing three main lines, assigned to: substitutional, interstitial and a damage configuration sites of the implanted ions. The hyperfine electric parameters, Quadrupole Splitting and Isomer Shift, were calculated for various implantation environments. In the calculations the full potential linearized-augmented plane-wave plus local orbitals (L/APW+lo) method as embodied in the WIEN2k code was used. Good agreement was found between the experimental and the calculated values for some implantation configurations; suggesting that the implantation environments could be similar to the ones proposed by the authors. (Author)

  6. Negative muon spin precession measurement of the hyperfine states of muonic sodium

    International Nuclear Information System (INIS)

    Brewer, J.H.; Ghandi, K.; Froese, A.M.; Fryer, B.A.

    2005-01-01

    Both hyperfine states of muonic 23 Na and the rate R of conversion between them have been observed directly in a high field negative muon spin precession experiment using a backward muon beam with transverse spin polarization. The result in metallic sodium, R=13.7±2.2 μs -1 , is consistent with Winston's prediction in 1963 based on Auger emission of core electrons, and with the measurements of Gorringe et al. in Na metal, but not with their smaller result in NaF. In NaOH we find R=23.5±8 μs -1 , leaving medium-dependent effects ambiguous

  7. Forward two-photon exchange in elastic lepton-proton scattering and hyperfine-splitting correction

    Energy Technology Data Exchange (ETDEWEB)

    Tomalak, Oleksandr [Johannes Gutenberg Universitaet, Institut fuer Kernphysik and PRISMA Cluster of Excellence, Mainz (Germany)

    2017-08-15

    We relate the forward two-photon exchange (TPE) amplitudes to integrals of the inclusive lepton-proton scattering cross sections. These relations yield an alternative way for the evaluation of the TPE correction to hyperfine-splitting (HFS) in the hydrogen-like atoms with an equivalent to the standard approach (Iddings, Drell and Sullivan) result implying the Burkhardt-Cottingham sum rule. For evaluation of the individual effects (e.g., elastic contribution) our approach yields a distinct result. We compare both methods numerically on examples of the elastic contribution and the full TPE correction to HFS in electronic and muonic hydrogen. (orig.)

  8. Calculation of hyperfine constants for the H center in LiF

    International Nuclear Information System (INIS)

    Alencar, P.T.S.

    1975-01-01

    The EPR and the ENDOR hyperfine parameters for the H center in LiF are calculated assuming that the F - 2 central molecule is a simplified model for the electronic structure of this deffect. The best theoretical fitting was obtained by relaxing the ions neighboring the central molecule. We have obtained relaxations which are in agreement with the physical nature of this deffect, but for some ions the results have shown that a better wave functions for the unpaired electrons must be used. The results and the limitations of the suggested model, are discussed proposing a more realistic description for the deffect, than the F - 2 central molecule model

  9. Isotope shifts and hyperfine splittings in 144-154Sm I

    International Nuclear Information System (INIS)

    England, J.G.; Grant, I.S.; Newton, G.W.A.; Walker, P.M.

    1990-01-01

    The isotope shifts and hyperfine splittings have been measured in 144-154 Sm I using the crossed-beam laser fluorescence method. Transitions at 598.98 nm and 570.68 nm were investigated for all isotopes except 146 Sm and 153 Sm, in which measurements were only obtained at 570.68 nm. Laser-induced fluorescence has not previously been reported for 145 Sm. The magnetic dipole and electric quadrupole moments of the odd isotopes and the changes in mean square radii of the even ones are shown to be consistent with the information obtained from nuclear spectroscopy. (author)

  10. Hyperfine splitting in positronium measured through quantum beats in the 3γ decay

    International Nuclear Information System (INIS)

    Fan, S.; Beling, C.D.; Fung, S.

    1996-01-01

    Quantum beat oscillations in the 3γ decay of the positronium atom arising from interference between the different spin states have been observed using a simple β-start and γ-stop detection system. Measurements of the beat frequency at different magnetic fields have yielded a value of the 1 1 S 0 -1 3 S 1 hyperfine interaction of 202.5±3.5 GHz, in good agreement with previous measurements. This novel approach does not require high magnetic fields and the use of microwave radiation to quench the triplet substate of the positronium atom. (orig.)

  11. Host material induced hyperfine structure of F{sup +} centres EPR spectra in CaS

    Energy Technology Data Exchange (ETDEWEB)

    Seeman, Viktor, E-mail: viktor.seeman@ut.ee; Dolgov, Sergei; Maaroos, Aarne

    2017-05-15

    The hyperfine structure (HFS) of F{sup +} centres in CaS single crystals due to the interaction with {sup 33}S and {sup 43}Ca nuclei was observed in EPR spectra for the first time. Angular variations of the HFS were measured for rotation of magnetic field in {100} and {110} crystallographic planes. Using measured orientation-dependent EPR spectra and the EPR NMR program, the parameters of the spin Hamiltonian were determined. In case of {sup 33}S nucleus there is a strong dependence of the F{sup +} centre EPR spectrum on the quadrupole term whereas for {sup 43}Ca nucleus this dependence is insignificant.

  12. Solvent polarity effects on hyperfine couplings of cyclohexadienyl-type radicals

    International Nuclear Information System (INIS)

    Vujosevic', D.; Scheuermann, R.; Dilger, H.; Tucker, I.M.; Martyniak, A.; McKenzie, I.; Roduner, E.

    2006-01-01

    In this study muon-spin rotation (μSR) serves as a tool for sensitive monitoring of the environment of muoniated radicals in isotropic liquids. A systematic investigation of the behaviour of the hyperfine coupling constants of cyclohexadienyl-type radicals is performed, and it is found that they are in linear dependence on solvent polarity, with certain deviations. These deviations are discussed in detail. It is found that with increasing length of the hydroxyalkyl substituent group the perturbation of the phenyl ring becomes smaller

  13. Solvent polarity effects on hyperfine couplings of cyclohexadienyl-type radicals

    Energy Technology Data Exchange (ETDEWEB)

    Vujosevic' , D. [Institut fuer Physikalische Chemie, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart (Germany); Scheuermann, R. [Laboratory for Muon Spin Spectroscopy, Paul Scherrer Institute, CH-5232 Villigen (Switzerland); Dilger, H. [Institut fuer Physikalische Chemie, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart (Germany); Tucker, I.M. [Unilever Research and Development, Port Sunlight, Wirral CH63 3JW (United Kingdom); Martyniak, A. [Institut fuer Physikalische Chemie, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart (Germany); McKenzie, I. [Institut fuer Physikalische Chemie, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart (Germany); Roduner, E. [Institut fuer Physikalische Chemie, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart (Germany)]. E-mail: e.rodunder@ipc.uni-stuttgart.de

    2006-03-31

    In this study muon-spin rotation ({mu}SR) serves as a tool for sensitive monitoring of the environment of muoniated radicals in isotropic liquids. A systematic investigation of the behaviour of the hyperfine coupling constants of cyclohexadienyl-type radicals is performed, and it is found that they are in linear dependence on solvent polarity, with certain deviations. These deviations are discussed in detail. It is found that with increasing length of the hydroxyalkyl substituent group the perturbation of the phenyl ring becomes smaller.

  14. A classic case of Jahn–Teller effect theory revisited: Ab initio simulation of hyperfine coupling and pseudorotational tunneling in the 1"2E′ state of Na_3

    International Nuclear Information System (INIS)

    Hauser, Andreas W.; Pototschnig, Johann V.; Ernst, Wolfgang E.

    2015-01-01

    Highlights: • Multireference and Coupled Cluster methods are applied to Na_3. • The PES is characterized by an analytical function fitted to ab initio data. • An effective rovibrational Hamiltonian is set up, with all parameters derived ab initio. • The coupling of pseudorotational tunneling and hyperfine interactions is investigated. • The theoretical predictions are compared to microwave spectra. - Abstract: The predictive capabilities of current ab initio approaches are tested in a benchmark study on the well known case of the Na_3 ground state. This molecule is small enough to be treated with computationally demanding methods, but also shows an interesting interplay between Jahn–Teller-, spin-orbit-, rovibrational- and hyperfine-interactions. The necessary parameters for the effective Hamiltonian are derived from the potential energy surface of the 1"2E′ ground state and from spin density evaluations at selected geometries, without any fitting adjustments to experimental data. We compare our results to highly resolved microwave spectra, with the aim to improve previous assignment attempts, where some parameters had to be estimated from fits to measured spectra.

  15. Characterization of the hyperfine interaction of the excited D50 state of Eu3 +:Y2SiO5

    Science.gov (United States)

    Cruzeiro, Emmanuel Zambrini; Etesse, Jean; Tiranov, Alexey; Bourdel, Pierre-Antoine; Fröwis, Florian; Goldner, Philippe; Gisin, Nicolas; Afzelius, Mikael

    2018-03-01

    We characterize the europium (Eu3 +) hyperfine interaction of the excited state (D50) and determine its effective spin Hamiltonian parameters for the Zeeman and quadrupole tensors. An optical free induction decay method is used to measure all hyperfine splittings under a weak external magnetic field (up to 10 mT) for various field orientations. On the basis of the determined Hamiltonian, we discuss the possibility to predict optical transition probabilities between hyperfine levels for the F70⟷D50 transition. The obtained results provide necessary information to realize an optical quantum memory scheme which utilizes long spin coherence properties of 3 + 151Eu :Y2SiO5 material under external magnetic fields.

  16. Measurement of a heavy-hole hyperfine interaction in InGaAs quantum dots using resonance fluorescence.

    Science.gov (United States)

    Fallahi, P; Yilmaz, S T; Imamoğlu, A

    2010-12-17

    We measure the strength and the sign of hyperfine interaction of a heavy hole with nuclear spins in single self-assembled quantum dots. Our experiments utilize the locking of a quantum dot resonance to an incident laser frequency to generate nuclear spin polarization. By monitoring the resulting Overhauser shift of optical transitions that are split either by electron or exciton Zeeman energy with respect to the locked transition using resonance fluorescence, we find that the ratio of the heavy-hole and electron hyperfine interactions is -0.09 ± 0.02 in three quantum dots. Since hyperfine interactions constitute the principal decoherence source for spin qubits, we expect our results to be important for efforts aimed at using heavy-hole spins in quantum information processing.

  17. Mixing of the lowest-lying qqq configurations with JP =1/2- in different hyperfine interaction models

    Science.gov (United States)

    Chen, Jia; An, Chunsheng; Chen, Hong

    2018-02-01

    We investigate mixing of the lowest-lying qqq configurations with JP = 1/2- caused by the hyperfine interactions between quarks mediated by Goldstone Boson Exchange, One Gluon Exchange, and both Goldstone Boson and One Gluon exchange, respectively. The first orbitally excited nucleon, Σ, Λ and Ξ states are considered. Contributions of both the contact term and tensor term are taken into account. Our numerical results show that mixing of the studied configurations in the two employed hyperfine interaction models are very different. Therefore, the present results, which should affect the strong and electromagnetic decays of baryon resonances, may be used to examine the present employed hyperfine interaction models. Supported by National Natural Science Foundation of China (11675131,11645002), Chongqing Natural Science Foundation (cstc2015jcyjA00032) and Fundamental Research Funds for the Central Universities (SWU115020)

  18. Design and development of high-resolution atomic beam fluorescence spectroscopy facility for isotope shift and hyperfine structure measurements

    International Nuclear Information System (INIS)

    Acharyulu, G.V.S.G.; Sankari, M.; Kiran Kumar, P.V.; Suryanarayana, M.V.

    2012-01-01

    A high-resolution atomic beam fluorescence spectroscopy facility for the determination of isotope shifts and hyperfine structure in atomic species has been designed and developed. A resistively heated graphite tube atomic beam source was designed, tested and integrated into a compact interaction chamber for atomic beam fluorescence experiments. The design of the laser-atom interaction chamber and the source has been modified in a phased manner so as to achieve sub-Doppler resolution. The system has been used to record the hyperfine spectrum of the D2 transitions of Rb and K isotopes. The spectral resolution achieved is ∼ 26 MHz and is adequate to carry out high resolution measurement of isotope shifts and hyperfine structure of various atomic species. The other major advantage of the source is that it requires very small amounts of sample for achieving very good signal to noise ratio. (author)

  19. Hyperfine interactions and some thermomagnetic properties of amorphous FeZr(CrNbBCu alloys

    Directory of Open Access Journals (Sweden)

    Łukiewska Agnieszka

    2017-06-01

    Full Text Available In this research, we studied the magnetic phase transition by Mössbauer spectroscopy and using vibrating sample magnetometer for amorphous Fe86-xZr7CrxNb2Cu1B4 (x = 0 or 6 alloys in the as-quenched state and after accumulative annealing in the temperature range 600-750 K. The Mössbauer investigations were carried out at room and nitrogen temperatures. The Mössbauer spectra of the investigated alloys at room temperature are characteristic of amorphous paramagnets and have a form of asymmetric doublets. However, at nitrogen temperature, the alloys behave like ferromagnetic amorphous materials. The two components are distinguished in the spectrum recorded at both room and nitrogen temperatures. The low field component in the distribution of hyperfine field induction shifts towards higher field with the annealing temperature. It is assumed that during annealing at higher temperature, due to diffusion processes, the grains of α-Fe are created in the area corresponding to this component. Both investigated alloys show the invar effect and the decrease of hyperfine field induction after annealing at 600 K for 10 min is observed. It is accompanied by the lowering of Curie temperature.

  20. High precision measurements of hyperfine structure in Tm II, N2+ and Sc II

    International Nuclear Information System (INIS)

    Mansour, N.B.; Dinneen, T.P.; Young, L.

    1988-01-01

    We have applied the technique of collinear fast-ion-beam laser spectroscopy to measure the hyperfine structure (hfs) in Sc II, Tm II and N 2 + . Laser induced fluorescence was observed from a 50 keV ion beam which was superimposed with the output of an actively stabilized ring dye laser (rms bandwidth 2 and the excited 3d4p configuration of Sc II and in the 4f 13 6s and 4f 13 5d configurations of the Tm II. The fine and hyperfine structure of N 2 + has been observed in the (0,1) and (1,2) band of B 2 Σ/sub u/ + /minus/X 2 Σ/sub g/ + system. Higher resolution measurements of the metastable 3d 2 configuration in Sc II were also made by laser-rf double resonance. The experimental results will be compared with those obtained by multiconfiguration Hartree-Fock ab-initio calculations. 15 refs., 4 figs., 5 tabs

  1. Electron plasmas as a diagnostic tool for hyperfine spectroscopy of antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Friesen, T.; Thompson, R. I. [Department of Physics and Astronomy, University of Calgary, Calgary AB, T2N 1N4 (Canada); Amole, C.; Capra, A.; Menary, S. [Department of Physics and Astronomy, York University, Toronto ON, M3J 1P3 (Canada); Ashkezari, M. D.; Hayden, M. E. [Department of Physics, Simon Fraser University, Burnaby BC, V5A 1S6 (Canada); Baquero-Ruiz, M.; Fajans, J.; Little, A.; So, C.; Wurtele, J. S. [Department of Physics, University of California, Berkeley, CA 94720-7300 (United States); Bertsche, W. [School of Physics and Astronomy, University of Manchester, M13 9PL Manchester, UK and The Cockcroft Institute, WA4 4AD Warrington (United Kingdom); Bowe, P. D.; Hangst, J. S.; Rasmussen, C. O. [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Butler, E. [Physics Department, CERN, CH-1211 Geneva 23 (Switzerland); Cesar, C. L.; Silveira, D. M. [Instituto de Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21941-972 (Brazil); Charlton, M. [Department of Physics, College of Science, Swansea University, Swansea SA2 8PP (United Kingdom); and others

    2013-03-19

    Long term magnetic confinement of antihydrogen atoms has recently been demonstrated by the ALPHA collaboration at CERN, opening the door to a range of experimental possibilities. Of particular interest is a measurement of the antihydrogen spectrum. A precise comparison of the spectrum of antihydrogen with that of hydrogen would be an excellent test of CPT symmetry. One prime candidate for precision CPT tests is the ground-state hyperfine transition; measured in hydrogen to a precision of nearly one part in 10{sup 12}. Effective execution of such an experiment with trapped antihydrogen requires precise knowledge of the magnetic environment. Here we present a solution that uses an electron plasma confined in the antihydrogen trapping region. The cyclotron resonance of the electron plasma is probed with microwaves at the cyclotron frequency and the subsequent heating of the electron plasma is measured through the plasma quadrupole mode frequency. Using this method, the minimum magnetic field of the neutral trap can be determined to within 4 parts in 10{sup 4}. This technique was used extensively in the recent demonstration of resonant interaction with the hyperfine levels of trapped antihydrogen atoms.

  2. Theory of long-range interactions for Rydberg states attached to hyperfine-split cores

    Science.gov (United States)

    Robicheaux, F.; Booth, D. W.; Saffman, M.

    2018-02-01

    The theory is developed for one- and two-atom interactions when the atom has a Rydberg electron attached to a hyperfine-split core state. This situation is relevant for some of the rare-earth and alkaline-earth atoms that have been proposed for experiments on Rydberg-Rydberg interactions. For the rare-earth atoms, the core electrons can have a very substantial total angular momentum J and a nonzero nuclear spin I . In the alkaline-earth atoms there is a single (s ) core electron whose spin can couple to a nonzero nuclear spin for odd isotopes. The resulting hyperfine splitting of the core state can lead to substantial mixing between the Rydberg series attached to different thresholds. Compared to the unperturbed Rydberg series of the alkali-metal atoms, the series perturbations and near degeneracies from the different parity states could lead to qualitatively different behavior for single-atom Rydberg properties (polarizability, Zeeman mixing and splitting, etc.) as well as Rydberg-Rydberg interactions (C5 and C6 matrices).

  3. Study of hyperfine interactions in V2O3 by angular correlation

    International Nuclear Information System (INIS)

    Jesus Silva, P.R. de.

    1985-01-01

    The hyperfine interaction in v 2 O 3 in function of temperature by measurements of time differential perturbed angular correlation is studied. The samples presented quadrupole interaction in the probe center, Cd 111 immediatelly after sintering, when reduced in H 2 flux at 800 0 C. A pure electric quadrupole interaction at the metallic phase and a combined interaction of magnetic dipole and electric quadrupole at the insulating antiferromagnetic phase, were observed. The electric field gradient undergoes abrupt variation at the metal-insulating transition at T=160 0 K from 8.2x10 17 v/cm 2 at the insulating phase to 6.3x10 17 v/cm 2 in the metallic phase, however varies smoothly with the temperature at T=450 0 K when variations in resistivity also occur. At metallic phase the electric field increases with the temperature enhacement. The hyperfine magnetic field of Cd 111 at antiferromagnetic phase of V 2 O 3 has a saturation value of 15(1) KOe and performes an angle of β=68(2) 0 with the main component direction of electric field gradient. (M.C.K.) [pt

  4. Hyperfine interactions in ferromagnetic materials and magnetic properties of 1fsub(7/2) nuclei

    International Nuclear Information System (INIS)

    Bozek, E.

    1976-01-01

    Hyperfine interactions of light nuclei recoil-implanted into iron, nickel and cobalt were studied using the perturbed integral angular distribution IMPAD. Isomeric states of lifetimes within the nanosecond range were excited in the following reactions: 28 Si 14 N, xn, yp 37 Ar, 39 K, 40 K; 27 Al 16 O, xn, yp 41 K, 41 Ca. In all cases except implantation of potassium isotopes into nickel observed shifts of angular distribution were found much smaller than the ones calculated using the known values of g factors, livetimes and strengths of the hyperfine fields. This effect can be explained under the assumption that only a fraction of nuclei feel the full magnetic field. Different fractions obtained for 40 K and 41 K suggest a migration process on a ns time scale. The magnetic moments of isomeric nuclear states excited in reaction 27 Al 14 N, p 36 Cl, 24 Mg 19 F, 2pn 40 K and 48 Ca, 2n 50 Ti were measured using the perturbed integral angular distribution technique - IPAD in an external magnetic field. The g factors for the investigated states were interpreted on the base of the shell model, assuming the effective magnetic moments associated with shell model orbitals dsub(3/2) and fsub(7/2). (author)

  5. Hyperfine interaction mechanism of magnetic field effects in sequential fluorophore and exciplex fluorescence.

    Science.gov (United States)

    Dodin, Dmitry V; Ivanov, Anatoly I; Burshtein, Anatoly I

    2013-03-28

    The magnetic field effect on the fluorescence of the photoexcited electron acceptor, (1)A∗, and the exciplex, (1)[D(+δ)A(-δ)] formed at contact of (1)A∗ with an electron donor (1)D, is theoretically explored in the framework of Integral Encounter Theory. It is assumed that the excited fluorophore is equilibrated with the exciplex that reversibly dissociates into the radical-ion pair. The magnetic field sensitive stage is the spin conversion in the resulting geminate radical-ion pair, (1, 3)[D(+)...A(-)] that proceeds due to hyperfine interaction. We confirm our earlier conclusion (obtained with a rate description of spin conversion) that in the model with a single nucleus spin 1/2 the magnitude of the Magnetic Field Effect (MFE) also vanishes in the opposite limits of low and high dielectric permittivity of the solvent. Moreover, it is shown that MFE being positive at small hyperfine interaction A, first increases with A but approaching the maximum starts to decrease and even changes the sign.

  6. Electronic structure of radiation damage centre in zinc silicate from ESR hyperfine data

    International Nuclear Information System (INIS)

    Prasad, C.; Chakravarty, Sulata

    1979-01-01

    The occurrence of an ESR spectrum with six hyperfine components in X-irradiated zinc silicate, Zn 2 SiO was reported earlier. It is known that by the use of the experimental ESR data it is possible to work out the electronic structure of the paramagnetic damage center. The values of the hyperfine parameters A and B have been utilized to calculate the values of f'sub(s) and fsub(sigma), the fractional occupation of the 3s and 3psub(sigma) orbitals of the metal atom by the unpaired electron. The metal atom is 27 Al (I = 5/2, n.a. = 100%) which is present as an impurity in the lattice and occupies silicon sites. The bonding between the metal atom and each of the surrounding oxygen atom is assumed to be of the sigma-type. The values obtained for the fractional occupation are : f'sub(s) = 0.71 x 10sup(-2), fsub(sigma) = 14.65 x10sup(-2). The unpaired electron appears to belong to the ligand atom and is moderately delocalised on the Al atom where it occupies mainly the 3psup(sigma) orbital and not the 3s orbital. (auth.)

  7. Orbital hyperfine interaction and qubit dephasing in carbon nanotube quantum dots

    Science.gov (United States)

    Palyi, Andras; Csiszar, Gabor

    2015-03-01

    Hyperfine interaction (HF) is of key importance for the functionality of solid-state quantum information processing, as it affects qubit coherence and enables nuclear-spin quantum memories. In this work, we complete the theory of the basic hyperfine interaction mechanisms (Fermi contact, dipolar, orbital) in carbon nanotube quantum dots by providing a theoretical description of the orbital HF. We find that orbital HF induces an interaction between the nuclear spins of the nanotube lattice and the valley degree of freedom of the electrons confined in the quantum dot. We show that the resulting nuclear-spin-electron-valley interaction (i) is approximately of Ising type, (ii) is essentially local, in the sense that an effective atomic interaction strength can be defined, and (iii) has a strength that is comparable to the combined strength of Fermi contact and dipolar interactions. We argue that orbital HF provides a new decoherence mechanism for single-electron valley qubits and spin-valley qubits in a range of multi-valley materials. We explicitly evaluate the corresponding inhomogeneous dephasing time T2* for a nanotube-based valley qubit. We acknowledge funding from the EU Marie Curie CIG-293834, OTKA Grant PD 100373, and EU ERC Starting Grant CooPairEnt 258789. AP is supported by the Janos Bolyai Scholarship of the Hungarian Academy of Sciences.

  8. Very low temperature studies of hyperfine effects in metals. [Progress report

    International Nuclear Information System (INIS)

    Weyhmann, W.

    1985-01-01

    We are using nuclei through the hyperfine coupling as a probe of magnetic interactions in metallic systems, emphasizing the role conduction electrons play. Three types of systems are of interest to us: nuclear singlet ground state intermetallic compounds, very dilute magnetic impurities in non-magnetic metals, and itinerant ferromagnets. The nuclear ordering in singlet ground state alloys of praseodymium appears to be analogous to electronic ordering in rare earth metals, with the RKKY interaction moderating the indirect exchange in both cases. We are measuring the static and dynamic properties of these materials both to study rare earth ordering, since only first order effects should play a role in the nuclear case, and to develop the sub-millikelvin refrigeration capabilities of these materials. Using this cooling power, we propose studying the local moment of Mn based Kondo systems at millikelvin and sub-millikelvin temperatures. Kondo systems with a Kondo temperature below 0.1 K have the advantage that magnetic saturation can be achieved with available magnets. We propose studying both the local magnetization as measured with nuclear orientation and the macroscopic magnetization measured with SQUID magnetometry. We also propose searching for electron polarization effects in itinerant ferromagnets using nuclear orientation. Induced hyperfine fields of less than 1 k0e can be detected at 1 mK

  9. Stark effect of the hyperfine structure of ICl in its rovibronic ground state: Towards further molecular cooling

    Science.gov (United States)

    Qing-Hui, Wang; Xu-Ping, Shao; Xiao-Hua, Yang

    2016-01-01

    Hyperfine structures of ICl in its vibronic ground state due to the nuclear spin and electric quadruple interactions are determined by diagonalizing the effective Hamiltonian matrix. Furthermore, the Stark sub-levels are precisely determined as well. The results are helpful for electro-static manipulation (trapping or further cooling) of cold ICl molecules. For example, an electric field of 1000 V/cm can trap ICl molecules less than 637 μK in the lowest hyperfine level. Project supported by the National Natural Science Foundation of China (Grant No. 11034002), the National Basic Research Program of China (Grant No. 2011CB921602), and Qing Lan Project, China.

  10. Mixed hyperfine interaction in amorphous Fe-Zr sputtered films in external magnetic field - a 57Fe Moessbauer study

    International Nuclear Information System (INIS)

    Fries, S.M.; Crummenauer, J.; Wagner, H.-G.; Gonser, U.; Chien, C.L.

    1986-01-01

    Conventional 57 Fe-Moessbauer spectroscopy provides only information about the magnitude of the splitting QS in the case of electric quadrupole hyperfine interaction, but not on the sign of the main component of the electric field gradient (EFG) or the asymmetry parameter which are sensitive to the local environment of the 57 Fe nuclei. This kind of information is obtained by measurements in external magnetic fields. In the case of amorphous Fe-Zr sputtered films mixed hyperfine interaction leads to a clear change in the behaviour of the Zr-rich and the Fe-rich alloys, indicating the existence of magnetic clusters in the Fe-rich samples. (Auth.)

  11. Construction of the energy matrix for complex atoms. Part VIII: Hyperfine structure HPC calculations for terbium atom

    Science.gov (United States)

    Elantkowska, Magdalena; Ruczkowski, Jarosław; Sikorski, Andrzej; Dembczyński, Jerzy

    2017-11-01

    A parametric analysis of the hyperfine structure (hfs) for the even parity configurations of atomic terbium (Tb I) is presented in this work. We introduce the complete set of 4fN-core states in our high-performance computing (HPC) calculations. For calculations of the huge hyperfine structure matrix, requiring approximately 5000 hours when run on a single CPU, we propose the methods utilizing a personal computer cluster or, alternatively a cluster of Microsoft Azure virtual machines (VM). These methods give a factor 12 performance boost, enabling the calculations to complete in an acceptable time.

  12. Systematic study of hyperfine fields in Rh2 Y Z type Heusler alloys with 119 Sn impurity using Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Ramos, S.M.M.

    1985-01-01

    The magnetic hyperfine fields in the Heusler alloys Rh 2 Mn .98 Ge Sn 02 , Rh 2 Mn Ge .98 Sn .02 , Rh 2 Mn Pb .98 Sn .02 and Rh 2 Mn Sn has been studied by 119 Sn Moessbauer spectroscopy at 293 K, 77 K, 4.2 K and 293 K with applied external magnetic field. The results show that when one compare the magnetic hyperfine fields systematic with the Heusler alloys X 2 Mn Z (X = Co, Ni, Cu, Pd, and Z = s p metal), this systematic is similar to the Co alloys, although can not explained by the currents models for the Heusler alloys. (author)

  13. Optogalvanic spectroscopy of the hyperfine structure of weak La I lines: discovery of new even parity fine structure levels

    International Nuclear Information System (INIS)

    Siddiqui, Imran; Khan, Shamim; Gamper, B; Windholz, L; Dembczyński, J

    2013-01-01

    The hyperfine structure of weak La I lines was experimentally investigated using laser optogalvanic spectroscopy in a hollow cathode discharge lamp. More than 100 La I lines were investigated and 40 new energy levels were discovered, most of them having even parity. The magnetic hyperfine interaction constants A and in some cases the electric quadrupole interaction constants B for these levels were determined. All the newly discovered levels were confirmed either by additional laser excitations (from other known levels) or by lines in a Fourier transform spectrum which could now be classified. (paper)

  14. Searching for an oscillating massive scalar field as a dark matter candidate using atomic hyperfine frequency comparisons

    OpenAIRE

    Hees, A.; Guéna, J.; Abgrall, M.; Bize, S.; Wolf, P.

    2016-01-01

    We use six years of accurate hyperfine frequency comparison data of the dual rubidium and caesium cold atom fountain FO2 at LNE-SYRTE to search for a massive scalar dark matter candidate. Such a scalar field can induce harmonic variations of the fine structure constant, of the mass of fermions and of the quantum chromodynamic mass scale, which will directly impact the rubidium/caesium hyperfine transition frequency ratio. We find no signal consistent with a scalar dark matter candidate but pr...

  15. High-precision hyperfine structure measurement in slow atomic ion beams by collinear laser-rf double resonance

    International Nuclear Information System (INIS)

    Amarjit Sen; Childs, W.J.; Goodman, L.S.

    1987-01-01

    A new collinear laser-ion beam apparatus for slow ions (1 to 1.5 keV) has been built for measuring the hyperfine structure of metastable levels of ions with laser-rf double resonance technique. Narrow linewidths of ∼60 kHz (FWHM) have been observed for the first time in such systems. As a first application the hyperfine structure of the 4f 7 ( 8 S 0 )5d 9 D/sub J/ 0 metastable levels of /sup 151,153/Eu + has been measured with high precision. 10 refs., 8 figs

  16. Hyperfine structure of 147,149Sm measured using saturated absorption spectroscopy in combination with resonance-ionization mass spectroscopy

    International Nuclear Information System (INIS)

    Park, Hyunmin; Lee, Miran; Rhee, Yongjoo

    2003-01-01

    The hyperfine structures of four levels of the Sm isotopes have been measured by means of diode-laser-based Doppler-free saturated absorption spectroscopy in combination with a diode-laser-initiated resonance-ionization mass spectroscopy. It was demonstrated that combining the two spectroscopic methods was very effective for the identification and accurate measurement of the spectral lines of atoms with several isotopes, such as the rare-earth elements. From the obtained spectra, the hyperfine constants A and B for the odd-mass isotopes 147 Sm and 149 Sm were determined for four upper levels of the studied transitions.

  17. Hyperfine interaction studies of radon in some metals and metal oxides with the alpha-gamma angular correlation method

    International Nuclear Information System (INIS)

    Orre, B.; Norlin, L.O.; Johansson, K.; Falk, F.; Thun, J.E.

    1975-11-01

    The α-γ angular correlation method has been applied to 226 Ra and 224 Ra decay with emphasis on source and backing preparations. A simple method to prepare sources suitable for hyperfine interaction studies has been developed, namely to implant the 224 Ra activity into the backing by recoil implantation in vacuum from a 228 Th source. A high voltage should be applied, which considerably improved the profile of the implantation. The hyperfine interactions in Fe,Co,Gd,Ni were measured and analysed according to a random static quadrupole interaction combined with an aligned magnetic interaction. (Auth.)

  18. Hyperfine fields of Fe in Nd2Fe14BandSm2Fe17N3

    Science.gov (United States)

    Akai, Hisazumi; Ogura, Masako

    2015-03-01

    High saturation magnetization of rare-earth magnets originates from Fe and the strong magnetic anisotropy stems from f-states of rare-earth elements such as Nd and Sm. Therefore the hyperfine fields of both Fe and rare-earth provide us with important pieces of information: Fe NMR enable us to detect site dependence of the local magnetic moment and magnetic anisotropy (Fe sites also contribute to the magnetic anisotropy) while rare-earth NQR directly give the information of electric field gradients (EFG) that are related to the shape of the f-electron cloud as well as the EFG produced by ligands. In this study we focus on the hyperfine fields of materials used as permanent magnets, Nd2Fe14BandSm2Fe17N3 from theoretical points of view. The detailed electronic structure together with the hyperfine interactions are discussed on the basis of the first-principles calculation. In particular, the relations between the observed hyperfine fields and the magnetic properties are studies in detail. The effects of doping of those materials by other elements such as Dy and the effects of N adding in Sm2Fe17N3 will be discussed. This work was supported by Elements Strategy Initiative Center for Magnetic Materials Project, the Ministry of Education, Culture, Sports, Science and Technology, Japan.

  19. Model-independent determination of the two-photon exchange contribution to hyperfine splitting in muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Peset, Clara; Pineda, Antonio [Grup de Física Teòrica, Dept. Física and IFAE-BIST, Universitat Autònoma de Barcelona,E-08193 Bellaterra (Barcelona) (Spain)

    2017-04-11

    We obtain a model-independent prediction for the two-photon exchange contribution to the hyperfine splitting in muonic hydrogen. We use the relation of the Wilson coefficients of the spin-dependent dimension-six four-fermion operator of NRQED applied to the electron-proton and to the muon-proton sectors. Their difference can be reliably computed using chiral perturbation theory, whereas the Wilson coefficient of the electron-proton sector can be determined from the hyperfine splitting in hydrogen. This allows us to give a precise model-independent determination of the Wilson coefficient for the muon-proton sector, and consequently of the two-photon exchange contribution to the hyperfine splitting in muonic hydrogen, which reads δĒ{sub pμ,HF}{sup TPE}(nS)=−(1/(n{sup 3}))1.161(20) meV. Together with the associated QED analysis, we obtain a prediction for the hyperfine splitting in muonic hydrogen that reads E{sub pμ,HF}{sup th}(1S)=182.623(27) meV and E{sub pμ,HF}{sup th}(2S)=22.8123(33) meV. The error is dominated by the two-photon exchange contribution.

  20. Hyperfine coupling of the iodine {\\boldsymbol{D}}{0}_{{\\boldsymbol{u}}}^{+} and β1 g ion-pair states

    Science.gov (United States)

    Baturo, V. V.; Cherepanov, I. N.; Lukashov, S. S.; Petrov, A. N.; Poretsky, S. A.; Pravilov, A. M.

    2018-05-01

    Detailed studies of I2(β1 g , v β = 13, J β ∼ D{0}u+, v D = 12, J D and D, 48, J D ∼ β, 47, J β ) rovibronic state coupling have been carried out using two-step two-color, hν 1 + hν 2 and hν 1 + 2hν 2, optical–optical double resonance excitation schemes, respectively. The hyperfine interaction satisfying the | {{Δ }}J| = 0, 1 selection rules (magnetic-dipole interaction) has been observed. No electric-quadrupole hyperfine coupling (| {{Δ }}J| = 2) has been found. The dependences of ratios of luminescence intensities from the rovibronic states populated due to the hyperfine coupling to those from optically populated ones on energy gaps between these states have been experimentally determined. The matrix elements as well as the hyperfine structure constant have been obtained using these dependences. It is shown that they increase slightly with the vibrational quantum number of the states.

  1. High-Fidelity Quantum Logic Gates Using Trapped-Ion Hyperfine Qubits.

    Science.gov (United States)

    Ballance, C J; Harty, T P; Linke, N M; Sepiol, M A; Lucas, D M

    2016-08-05

    We demonstrate laser-driven two-qubit and single-qubit logic gates with respective fidelities 99.9(1)% and 99.9934(3)%, significantly above the ≈99% minimum threshold level required for fault-tolerant quantum computation, using qubits stored in hyperfine ground states of calcium-43 ions held in a room-temperature trap. We study the speed-fidelity trade-off for the two-qubit gate, for gate times between 3.8  μs and 520  μs, and develop a theoretical error model which is consistent with the data and which allows us to identify the principal technical sources of infidelity.

  2. Theory of solvent effects on the hyperfine splitting constants in ESR spectra of free radicals

    International Nuclear Information System (INIS)

    Abe, T.; Tero-Kubota, S.; Ikegami, Y.

    1982-01-01

    An expression for the effects of solvation and hydrogen bonding on the hyperfine splitting constants of a free radical has been derived by obtaining π-electron spin densities of the radical in solution by perturbation theory. When no hydrogen bonding occurs between the radical and a solvent molecule, the splitting constant is approximately proportional to the Block and Walker parameter of theta(epsilon/sub r/) identical with 3 epsilon/sub r/ (ln epsilon/sub r/)/(epsilon/sub r/ ln epsilon/sub r/ - epsilon/sub r/ + 1) - 6/(ln epsilon/sub r/) - 2, where epsilon/sub r/ is the relative permittivity of the solvent. The expression is successfully applied to the di-tert-butyl nitroxide radical, the 1-methyl-4-(methoxycarbonyl)pyridinyl radical, and other free radicals. The effects of hydrogen bonding are discussed

  3. Hyperfine splitting of B mesons and Bs production at the Υ(5S)

    International Nuclear Information System (INIS)

    Lee-Franzini, J.; Heintz, U.; Lovelock, D.M.J.; Narain, M.; Schamberger, R.D.; Willins, J.; Yanagisawa, C.; Franzini, P.; Tuts, P.M.

    1990-01-01

    Using the Columbia University--Stony Brook (CUSB-II) detector we have studied the inclusive photon spectrum from 2.9x10 4 Υ(5S) decays. We observe a strong signal due to B * →Bγ decays. From this we obtain (i) the average B * -B mass difference, 46.7±0.4 MeV, (ii) the photon yield per Υ(5S) decay, left-angle γ/Υ(5S)right-angle=1.09±0.06, and (iii) the average velocity of the B * 's, left-angle β right-angle=0.156±0.010, for a mix of nonstrange (B) and strange (B s ) B * mesons from Υ(5S) decays. From the shape of the photon line, we find that both B and B s mesons are produced with nearly equal values for the hyperfine splitting of the B and B s meson systems

  4. High precision hyperfine measurements in Bismuth challenge bound-state strong-field QED.

    Science.gov (United States)

    Ullmann, Johannes; Andelkovic, Zoran; Brandau, Carsten; Dax, Andreas; Geithner, Wolfgang; Geppert, Christopher; Gorges, Christian; Hammen, Michael; Hannen, Volker; Kaufmann, Simon; König, Kristian; Litvinov, Yuri A; Lochmann, Matthias; Maaß, Bernhard; Meisner, Johann; Murböck, Tobias; Sánchez, Rodolfo; Schmidt, Matthias; Schmidt, Stefan; Steck, Markus; Stöhlker, Thomas; Thompson, Richard C; Trageser, Christian; Vollbrecht, Jonas; Weinheimer, Christian; Nörtershäuser, Wilfried

    2017-05-16

    Electrons bound in highly charged heavy ions such as hydrogen-like bismuth 209 Bi 82+ experience electromagnetic fields that are a million times stronger than in light atoms. Measuring the wavelength of light emitted and absorbed by these ions is therefore a sensitive testing ground for quantum electrodynamical (QED) effects and especially the electron-nucleus interaction under such extreme conditions. However, insufficient knowledge of the nuclear structure has prevented a rigorous test of strong-field QED. Here we present a measurement of the so-called specific difference between the hyperfine splittings in hydrogen-like and lithium-like bismuth 209 Bi 82+,80+ with a precision that is improved by more than an order of magnitude. Even though this quantity is believed to be largely insensitive to nuclear structure and therefore the most decisive test of QED in the strong magnetic field regime, we find a 7-σ discrepancy compared with the theoretical prediction.

  5. Investigation of Pr I lines by a simulation of their hyperfine patterns: discovery of new levels

    International Nuclear Information System (INIS)

    Uddin, Zaheer; Siddiqui, Imran; Shamim, Khan; Windholz, L; Zafar, Roohi; Sikander, Rubeka

    2012-01-01

    Hyperfine structure (hf) patterns of unclassified spectral lines of the praseodymium atom, as appear in a high-resolution Fourier transform spectrum, have been simulated. In this way, the J-values and hf constants of the levels involved in the transitions were determined. Assuming that so far only one unknown level is participating in the transition, these constants were used to identify the known level. The second unknown level was found by performing subtraction or addition of the wave number of the transition to the wave number of the known level. The existence of the new level was then checked by explaining other unclassified lines with respect to the wave number and the hf pattern. In this way, 19 new levels of the praseodymium atom were discovered and are presented in this paper. In some cases, the accuracy of the hf constants was improved by laser-induced fluorescence spectroscopy.

  6. Toward the measurement of the hyperfine splitting in the ground state of muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Bakalov, Dimitar, E-mail: dbakalov@inrne.bas.bg [Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy (Bulgaria); Adamczak, Andrzej [Polish Academy of Sciences, Institute of Nuclear Physics (Poland); Stoilov, Mihail [Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy (Bulgaria); Vacchi, Andrea [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste (Italy)

    2015-08-15

    The recent Lamb shift experiment at PSI and the controversy about proton size revived the interest in measuring the hyperfine splitting in muonic hydrogen and extracting the proton Zemach radius. The efficiency of the experimental method depends on the energy dependence of the muon transfer rate to higher-Z gases in the near epithermal energy range. As long as the available experimental data only give the average transfer rate in the whole epithermal range, and the detailed theoretical calculations have not yet been verified, an experiment has been started for the measurement of the transfer rate in thermalized gas target at different temperatures and extracting from the data an estimate of the transfer rate for arbitrary energies. We outline the underlying mathematical method and estimate its accuracy.

  7. Hyperfine structure, nuclear spins and magnetic moments of some cesium isotopes

    International Nuclear Information System (INIS)

    Ekstroem, C.; Ingelman, S.; Wannberg, G.

    1977-03-01

    Using an atomic-beam magnetic resonance apparatus connected on-line with the ISOLDE isotope separator, CERN, hyperfine structure measurements have been performed in the 2 Ssub(1/2) electronic ground state of some cesium isotopes. An on-line oven system which efficiently converts a mass separated ion-beam of alkali isotopes to an atomic beam is described in some detail. Experimentally determined nuclear spins of sup(120, 121, 121m, 122, 122m, 123, 124, 126, 128, 130m, 135m)Cs and magnetic moments of sup(122, 123, 124, 126, 128, 130)Cs are reported and discussed in terms of different nuclear models. The experimental data indicate deformed nuclear shapes of the lightest cesium isotopes. (Auth.)

  8. Self-energy correction to the hyperfine splitting for excited states

    International Nuclear Information System (INIS)

    Wundt, B. J.; Jentschura, U. D.

    2011-01-01

    The self-energy corrections to the hyperfine splitting is evaluated for higher excited states in hydrogenlike ions using an expansion in the binding parameter Zα, where Z is the nuclear-charge number and α is the fine-structure constant. We present analytic results for D, F, and G states, and for a number of highly excited Rydberg states, with principal quantum numbers in the range 13≤n≤16, and orbital angular momenta l=n-2 and l=n-1. A closed-form analytic expression is derived for the contribution of high-energy photons, valid for any state with l≥2 and arbitrary n, l, and total angular momentum j. The low-energy contributions are written in the form of generalized Bethe logarithms and evaluated for selected states.

  9. Decoupling of the hyperfine interactions in /sup 12/B ions by the external magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Sugimoto, K; Tanihata, I; Kogo, S; Tanaka, M [Osaka Univ., Toyonaka (Japan). Faculty of Science

    1976-11-01

    It is known that product nuclei /sup 12/B (Isup(..pi..) = 1/sup +/, Tsub(1/2) = 20 ms) by the /sup 11/B(d,p)/sup 12/B reaction are sizably oriented if one selects recoil nuclei at the incident deuteron energy and the recoil angle thetasub(R). The hyperfine interactions in recoil ions in flight in free space affect the nuclear orientation. In this experiment, the nuclear orientation in the recoil ions implanted into a stopper were measured as a function of strength of a static magnetic field applied in normal to the reaction plane. A thin single crystal of magnesium was used as the recoil stopper, of which the hexagonal c-axis was set in parallel to the external field.

  10. Hyperfine structure of the odd parity level system in the terbium atom

    International Nuclear Information System (INIS)

    Stefanska, D; Furmann, B

    2017-01-01

    Within this work new experimental results concerning the hyperfine structure ( hfs ) in the terbium atom are presented, concerning the odd parity levels system, hitherto only scarcely investigated (apart from the ground term). hfs constants A and B for 113 levels were determined for the first time, and for another 16 levels, which already occurred in our earlier works, supplementary results were obtained; additionally, our earlier results for 93 levels were compiled. The hfs of the odd parity levels was investigated using the method of laser induced fluorescence in a hollow cathode discharge. The hfs of 165 spectral lines, where the levels in question were involved as the upper levels, was recorded. Literature values of hfs constants of the even-parity lower levels (including our own earlier results) greatly facilitated the present data evaluation. (paper)

  11. Analysis of structure of hyperfine poly(3-hydroxybutyrate) fibers (PHB) for controlled drug delivery

    Science.gov (United States)

    Olkhov, A. A.; Kosenko, R. Yu; Markin, V. S.; Zykova, A. K.; Pantyukhov, P. V.; Karpova, S. G.; Iordanskii, A. L.

    2017-12-01

    Hyperfine fibers based on biodegradable poly (3-hydroxybutyrate) with encapsulated drug substance (dipyridamol) were obtained by using electrospinning method. Addition of dipyridamol has a significant effect on geometrical shape and structure of microfibers as well as total porosity of fibrous material. Observation of fibers using scanning electron microscopy (SEM) method showed that without or at lower dipyridamol content (<3%) fibers consisted of interleaved ellipsoid and cylindrical fragments. At higher dipyridamol content (3-5%) anomalous ellipsoid structures did not practically form, and fiber’s shape became cylindrical. The totality of morphological and structural characteristics determined the rate of dipyridamol diffusive transports. The simplified model of drug desorption from fibrous matrix was presented. In current work it was showed that the rate-limiting stage of transport was the diffusion of dipyridamol in the bulk of cylindrical fibers.

  12. Hyperfine spectrum measurement of an optically pumped far-infrared laser with a Michelson interferometer

    International Nuclear Information System (INIS)

    Zuo, Z G; Ling, F R; Wang, P; Liu, J S; Yao, J Q; Weng, C X

    2013-01-01

    In this letter, we present a Michelson interferometer for the hyperfine spectrum measurement of an optically pumped far-infrared laser with a highest frequency resolution of 3–5 GHz. CH 3 OH gas with a purity of 99.9%, is pumped by the CO 2 9P36 and 9R10 laser lines to generate terahertz lasers with frequencies of 2.52 and 3.11 THz, respectively. Moreover, except for the center frequency, which is in good agreement with theoretical work, some additional frequencies on both sides of the center frequency are obtained at a frequency interval of 0.15 THz. Meanwhile, the mechanism behind the observed experimental results is also investigated. (letter)

  13. Hyperfine field calculations: search for muon stopping sites in Fe3O4

    International Nuclear Information System (INIS)

    Boekema, C.; Denison, A.B.; Cooke, D.W.; Heffner, R.H.; Hutson, R.L.; Leon, M.; Schillaci, M.E.

    1983-01-01

    Muon Spin Rotation (μSR) results for magnetite (Fe 3 O 4 ) are analyzed and discussed. At room temperature, a μSR signal is observed due to the presence of an internal magnetic field (Bsub(int)) at the muon site. External transverse field measurements show that Bsub(int) is parallel to the magnetic spin direction, the direction in zero applied field. Calculations of the hyperfine field to pinpoint muon stopping sites in magnetite show that the local field contains supertransfer (covalent) and dipolar field contributions. The implanted muons appear to stop at sites structurally similar to those reported for hematite (α-Fe 2 O 3 ), where muon-oxygen bond formation was strongly indicated. (Auth.)

  14. Velocity dependence of enhanced dynamic hyperfine field for Pd ions swiftly recoiling in magnetized Fe

    International Nuclear Information System (INIS)

    Stuchbery, A.E.; Ryan, G.C.; Bolotin, H.H.; Sie, S.H.

    1980-01-01

    The velocity-dependence of the magnitude of the enchanced dynamic hyperfine magnetic field (EDF) manifest at nuclei of 108 Pd ions swiftly recoiling through thin magnetized Fe has been investigated at ion velocities higher than have heretofore been examined for the heavier nuclides (i.e., at initial recoil velocities (v/Zv 0 )=0.090 and 0.160, v 0 =c/137). These results for 108 Pd, when taken in conjunction with those of prior similar measurements for 106 Pd at lower velocities, and fitted to a velocity dependence for the EDF, give for the Pd isotopes over the extended velocity range 1.74 0 )<=7.02, p=0.41+-0.15; a result incompatible with previous attributions of a linear velocity dependence for the field

  15. Highly resolving computerized tomography

    International Nuclear Information System (INIS)

    Kurtz, B.; Petersen, D.; Walter, E.

    1984-01-01

    With the development of highly-resolving devices for computerized tomography, CT diagnosis of the lumbar vertebral column has gained increasing importance. As an ambulatory, non-invasive method it has proved in comparative studies to be at least equivalent to myelography in the detection of dislocations of inter-vertebral disks (4,6,7,15). Because with modern devices not alone the bones, but especially the spinal soft part structures are clearly and precisely presented with a resolution of distinctly below 1 mm, a further improvement of the results is expected as experience will increase. The authors report on the diagnosis of the lumbar vertebral column with the aid of a modern device for computerized tomography and wish to draw particular attention to the possibility of doing this investigation as a routine, and to the diagnostic value of secondary reconstructions. (BWU) [de

  16. Highly resolving computerized tomography

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, B.; Petersen, D.; Walter, E.

    1984-01-01

    With the development of highly-resolving devices for computerized tomography, CT diagnosis of the lumbar vertebral column has gained increasing importance. As an ambulatory, non-invasive method it has proved in comparative studies to be at least equivalent to myelography in the detection of dislocations of inter-vertebral disks (4,6,7,15). Because with modern devices not alone the bones, but especially the spinal soft part structures are clearly and precisely presented with a resolution of distinctly below 1 mm, a further improvement of the results is expected as experience will increase. The authors report on the diagnosis of the lumbar vertebral column with the aid of a modern device for computerized tomography and wish to draw particular attention to the possibility of doing this investigation as a routine, and to the diagnostic value of secondary reconstructions.

  17. Hyperfine interactions and structural features of Fe–44Co–6Mo (wt.%) nanostructured powders

    International Nuclear Information System (INIS)

    Moumeni, Hayet; Nemamcha, Abderrafik; Alleg, Safia; Grenèche, Jean Marc

    2013-01-01

    Nanocrystalline Fe–44Co–6Mo (wt.%) powders have been prepared by high-energy ball milling from elemental Fe, Co and Mo pure powders in a P7 planetary ball mill. The obtained powders were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Mössbauer spectrometry techniques. The influence of milling process and Mo substitution for Co in equiatomic FeCo have been examined in order to study structural evolution and formation mechanism of nanostructured Fe(CoMo) solid solution. XRD results show the formation of a BCC Fe(CoMo) solid solution (a = 0.2874 nm) where unmixed nanocrystalline Mo with a BCC structure is embedded. Disordered Fe(CoMo) solid solution is characterized by a broad hyperfine magnetic field distribution with two regions centered at B 1 = 35.0 T and B 2 = 30.7 T, respectively, attributed to disordered Fe(Co) solid solution and CoMo enriched environments. Prolonged milling and Mo addition cause the decrease of average hyperfine magnetic field while the average isomer shift remains nearly constant. - Highlights: ► BCC nanostructured Fe(CoMo) solid solution is prepared by milling of Fe, Co and Mo. ► Formation mechanism: Co diffusion into Fe lattice and Mo dissolution in Fe(Co). ► Crystallite size of Fe(CoMo) solid solution reaches 11 nm after 24 h of milling. ► Mössbauer analysis reveals 3 components: high field, enriched Co and low field

  18. Hyperfine interactions and structural features of Fe–44Co–6Mo (wt.%) nanostructured powders

    Energy Technology Data Exchange (ETDEWEB)

    Moumeni, Hayet, E-mail: hmoumeni@yahoo.fr [Laboratoire de Chimie Computationnelle et Nanostructures, Département des Sciences de la Matière, Faculté des Mathématiques et de l' Informatique et des Sciences de la Matière, Université 08 Mai 1945 - Guelma, B.P. 401, Guelma 24000 (Algeria); Nemamcha, Abderrafik [Laboratoire d' Analyses Industrielles et Génie des Matériaux, Faculté des Sciences et de la Technologie, Université 08 Mai 1945 - Guelma, B.P. 401, Guelma 24000 (Algeria); Alleg, Safia [Laboratoire de Magnétisme et de Spectroscopie des Solides, Département de Physique, Faculté des Sciences, Université de Annaba, B.P. 12, Annaba 23000 (Algeria); Grenèche, Jean Marc [Laboratoire de Physique de l' Etat Condensé, UMR CNRS 6087, Institut de Recherche en Ingénierie Moléculaire et Matériaux Fonctionnels IRIM2F, FR CNRS 2575, Université du Maine, 72085 Le Mans Cedex 9 (France)

    2013-02-15

    Nanocrystalline Fe–44Co–6Mo (wt.%) powders have been prepared by high-energy ball milling from elemental Fe, Co and Mo pure powders in a P7 planetary ball mill. The obtained powders were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Mössbauer spectrometry techniques. The influence of milling process and Mo substitution for Co in equiatomic FeCo have been examined in order to study structural evolution and formation mechanism of nanostructured Fe(CoMo) solid solution. XRD results show the formation of a BCC Fe(CoMo) solid solution (a = 0.2874 nm) where unmixed nanocrystalline Mo with a BCC structure is embedded. Disordered Fe(CoMo) solid solution is characterized by a broad hyperfine magnetic field distribution with two regions centered at B{sub 1} = 35.0 T and B{sub 2} = 30.7 T, respectively, attributed to disordered Fe(Co) solid solution and CoMo enriched environments. Prolonged milling and Mo addition cause the decrease of average hyperfine magnetic field while the average isomer shift remains nearly constant. - Highlights: ► BCC nanostructured Fe(CoMo) solid solution is prepared by milling of Fe, Co and Mo. ► Formation mechanism: Co diffusion into Fe lattice and Mo dissolution in Fe(Co). ► Crystallite size of Fe(CoMo) solid solution reaches 11 nm after 24 h of milling. ► Mössbauer analysis reveals 3 components: high field, enriched Co and low field.

  19. Hyperfine structure measurements and discovery of new energy levels in neutral praseodymium

    Energy Technology Data Exchange (ETDEWEB)

    Imran, Siddiqui; Khan, Shamim; Syed, Tanweer Iqbal; Gamper, Bettina; Windholz, Laurentius [Inst. f. Experimentalphysik, Techn. Univ. Graz, Petersgasse 16, A-8010 Graz (Austria)

    2011-07-01

    We present here 14 even and 17 odd parity new energy levels of the neutral praseodymium atom. Free praseodymium atoms in ground and excited states are produced in a hollow cathode discharge lamp by cathode sputtering. The hyperfine structure (hfs) of the spectral lines is investigated by the method of laser induced fluorescence (LIF) spectroscopy. As an example of the method used we discuss briefly the finding of the new level at 27304.431 cm{sup -1}, even parity, J=9/2 and A=690(1) MHz. Laser excitation of the line at 6004.23 Aa is performed and a LIF signal is detected at fluorescence lines 5246.709, 5412.95, 5925.10, 6107.88, 6287.02, 6419.16, and 6620.63 A. The hfs is then recorded digitally and fitted to find reliable values of angular momentum J, magnetic and electric quadrupole hyperfine constants A and B for the combining fine structure levels. Assuming an unknown upper level, a lower level is searched in the data base of known levels, having the J and A values determined from the fit procedure. A level with 10654.11 cm{sup -1}, odd parity, J=7/2 and A=169(2) MHz is found. The energy of the upper level is calculated by adding the center of gravity wave number of the excited line to the energy of the lower level. The existence of the new level is checked by at least one additional laser excitation from another known lower level.

  20. On a comprehensive evaluation of Moessbauer hyperfine spectra measured on different types of magnetic nanoparticles

    International Nuclear Information System (INIS)

    Kraken, Mathias

    2014-01-01

    Magnetic nanoparticles (MNPs) nowadays have a wide variety of applications that are mostly based on the fact that MNPs below a critical size consist of only a single magnetic domain. The big magnetic moments of these MNPs may fluctuate, driven by thermal excitations and controlled by magnetic anisotropies and interparticle interactions. Successful applications go along with a good control of the properties of the MNPs, which requires detailed knowledge about the preparation process and a proper characterization. These are the main topics this thesis deals with. First, the characterization of the MNPs using Moessbauer spectroscopy is discussed. Despite it is a standard method in research on iron-based MNPs, most publications only present a qualitative discussion of measurements, since available analysis models for dynamic hyperfine spectra are not capable of a satisfying description. Here, a modified version of an established model is presented, which proved to be applicable to the majority of hyperfine spectra and allows deriving detailed microscopic information about magnetic fluctuations on nanoscale. This model is succesfully used, to study the preparation of MNPs with the so-called non-aqueous sol-gel method (a cooperation with the Institut fuer Partikeltechnik, Technische Universitaet Braunschweig). In the last part of the thesis, a model is developed that describes the Moessbauer spectra of magnetically fluctuating iron clusters in different non-magnetic metallic matrices (silver and ytterbium). This part is based on a cooperation with the Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro, Brasil. The results of this thesis present possibilities for a detailed quantitative analysis of the magnetic dynamics derived from Moessbauer spectra measured on iron-based MNPs and nanoscale clusters.

  1. Effect of nanocrystallization on the electrical conductivity enhancement and Moessbauer hyperfine parameters of iron based glasses

    Energy Technology Data Exchange (ETDEWEB)

    El-Desoky, M.M., E-mail: mmdesoky@gmail.com [Department of Physics, Faculty of Education, Suez Canal University, Al-Arish 45511, North Sinaa (Egypt); Ibrahim, F.A. [Department of Physics, Faculty of Education, Suez Canal University, Al-Arish 45511, North Sinaa (Egypt); Mostafa, A.G.; Hassaan, M.Y. [Department of Physics, Faculty of Science, Al-Azhar University, Nasr City 11884, Cairo (Egypt)

    2010-09-15

    Selected glasses of Fe{sub 2}O{sub 3}-PbO{sub 2}-Bi{sub 2}O{sub 3} system have been transformed into nanomaterials by annealing at temperature close to crystallization temperature (T{sub c}) for 1 h. The effects of the annealing of the present samples on its structural and electrical properties were studied by Moessbauer spectroscopy, transmission electron micrograph (TEM), differential scanning calorimeter (DSC) and dc conductivity ({sigma}). Moessbauer spectroscopy was used in order to determine the states of iron and its hyperfine structure. The effect of nanocrystalization on the Moessbauer hyperfine parameters did not exhibit significant modifications in present glasses. However, in case of glass ceramic nanocrystals show a distinct decrease in the quadrupole splitting ({Delta}) is observed, reflecting an evident decrease in the distortion of structural units like FeO{sub 4} units. In general, the Moessbauer parameters of the nano-crystalline phase exhibit tendency to increase with PbO{sub 2} content. TEM of as-quenched glasses confirm the homogeneous and essentially featureless morphology. TEM of the corresponding glass ceramic nanocrystals indicates nanocrystals embedded in the glassy matrix with average particle size of about 32 nm. The crystallization temperature (T{sub c}) was observed to decrease with PbO{sub 2} content. The glass ceramic nanocrystals obtained by annealing at T{sub c} exhibit improvement of electrical conductivity up to four orders of magnitude than the starting glasses. This considerable improvement of electrical conductivity after nanocrystallization is attributed to formation of defective, well-conducting phases 'easy conduction paths' along the glass-crystallites interfaces.

  2. Energy- and angled-resolved photoelectron spectroscopy of negative ions

    International Nuclear Information System (INIS)

    Pegg, D.J.; Thompson, J.S.; Compton, R.N.; Alton, G.D.

    1988-01-01

    Energy- and angle-resolved photoelectron detachment spectroscopy is currently being used to investigate the structure of negative ions and their interaction with radiation. Measurements of the electron affinity of the Ca atom and the partial cross sections for photodetachment of the metastable negative ion, He - (1s2s2p 4 P), are reported. 5 refs., 5 figs

  3. Resolving inventory differences

    International Nuclear Information System (INIS)

    Weber, J.H.; Clark, J.P.

    1991-01-01

    Determining the cause of an inventory difference (ID) that exceeds warning or alarm limits should not only involve investigation into measurement methods and reexamination of the model assumptions used in the calculation of the limits, but also result in corrective actions that improve the quality of the accountability measurements. An example illustrating methods used by Savannah River Site (SRS) personnel to resolve an ID is presented that may be useful to other facilities faced with a similar problem. After first determining that no theft or diversion of material occurred and correcting any accountability calculation errors, investigation into the IDs focused on volume and analytical measurements, limit of error of inventory difference (LEID) modeling assumptions, and changes in the measurement procedures and methods prior to the alarm. There had been a gradual gain trend in IDs prior to the alarm which was reversed by the alarm inventory. The majority of the NM in the facility was stored in four large tanks which helped identify causes for the alarm. The investigation, while indicating no diversion or theft, resulted in changes in the analytical method and in improvements in the measurement and accountability that produced a 67% improvement in the LEID

  4. Time-resolved studies

    International Nuclear Information System (INIS)

    Mills, D.M.

    1992-01-01

    When new or more powerful probes become available that offer both shorter data-collection times and the opportunity to apply innovative approaches to established techniques, it is natural that investigators consider the feasibility of exploring the kinetics of time-evolving systems. This stimulating area of research not only can lead to insights into the metastable or excited states that a system may populate on its way to a ground state, but can also lead to a better understanding of that final state. Synchrotron radiation, with its unique properties, offers just such a tool to extend X-ray measurements from the static to the time-resolved regime. The most straight-forward application of synchrotron radiation to the study of transient phenomena is directly through the possibility of decreased data-collection times via the enormous increase in flux over that of a laboratory X-ray system. Even further increases in intensity can be obtained through the use of novel X-ray optical devices. Widebandpass monochromators, e.g., that utilize the continuous spectral distribution of synchrotron radiation, can increase flux on the sample several orders of magnitude over conventional X-ray optical systems thereby allowing a further shortening of the data-collection time. Another approach that uses the continuous spectral nature of synchrotron radiation to decrease data-collection times is the open-quote parallel data collectionclose quotes method. Using this technique, intensities as a function of X-ray energy are recorded simultaneously for all energies rather than sequentially recording data at each energy, allowing for a dramatic decrease in the data-collection time

  5. Magnetism and Hyperfine Parameters in Iron Rich Gd_2Fe_{17-x}Si_x Intermetallics

    Science.gov (United States)

    Nouri, K.; Bartoli, T.; Chrobak, A.; Moscovici, J.; Bessais, L.

    2018-04-01

    Gd_2Fe_{17-x}Si_x (x = 0.25 , 0.5 and 1) samples were synthesized by arc melting and annealed at 1073 K for 1 week. X-ray diffraction analysis by the Rietveld method has shown that these materials crystallize in the rhombohedral Th_2Zn_{17} -type structure (space group R\\bar{3}m ). The Curie temperature increases with Si content x, whereas the unit-cell parameters decrease slightly. The temperature dependence of magnetization data revealed that Gd_2Fe_{17-x}Si_x exhibits a second-order ferromagnetic to paramagnetic phase transition in the vicinity of the Curie temperature. Exchange coupling parameters of R-R, M-M and R-M (R—rare earth, M—transition metal) have been determined from M(T) magnetization curves based on the mean field theory calculation. The magnetic entropy change Δ S_M and the relative cooling power were estimated from isothermal magnetization curves for all samples. In the proximity of {T}_C and in an applied field of 1.56 T, Δ S_M reached a maximum values of 1.38, 1.67 and 3.07 J/kg K for x = 0.25, 0.5 and 1, respectively. We have calculated the magnetic moment per Fe atom from magnetization measurements at 293 K up to 17 kOe, and it decreases with Si content. These results are verified by the Mössbauer spectrometry measurements obtained at the same temperature. The Mössbauer spectra analysis is based on the correlation between the Wigner-Seitz volume and the isomer-shift evolution of each specific site 6c, 9d, 18f, and 18h of the R\\bar{3} m structure. For all Si concentrations, the magnitude of the hyperfine fields are {H_HF}{6c} > {H_HF}{9d} > {H_HF}{18f} > {H_HF}{18h} . The mean hyperfine field decreases with the Si content.

  6. Comparing Zeeman qubits to hyperfine qubits in the context of the surface code: +174Yb and +171Yb

    Science.gov (United States)

    Brown, Natalie C.; Brown, Kenneth R.

    2018-05-01

    Many systems used for quantum computing possess additional states beyond those defining the qubit. Leakage out of the qubit subspace must be considered when designing quantum error correction codes. Here we consider trapped ion qubits manipulated by Raman transitions. Zeeman qubits do not suffer from leakage errors but are sensitive to magnetic fields to first order. Hyperfine qubits can be encoded in clock states that are insensitive to magnetic fields to first order, but spontaneous scattering during the Raman transition can lead to leakage. Here we compare a Zeeman qubit (+174Yb) to a hyperfine qubit (+171Yb) in the context of the surface code. We find that the number of physical qubits required to reach a specific logical qubit error can be reduced by using +174Yb if the magnetic field can be stabilized with fluctuations smaller than 10 μ G .

  7. Hyperfine-Interaction-Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single-Ion Magnet.

    Science.gov (United States)

    Chen, Yan-Cong; Liu, Jun-Liang; Wernsdorfer, Wolfgang; Liu, Dan; Chibotaru, Liviu F; Chen, Xiao-Ming; Tong, Ming-Liang

    2017-04-24

    An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm -1 . The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field-induced QTMs can be observed even from the field-dependent alternating-current magnetic susceptibility in addition to single-crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal-field environment and the hyperfine interactions arising from 165 Ho (I=7/2) with a natural abundance of 100 %. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Hyperfine-interaction-driven suppression of quantum tunneling at zero field in a holmium(III) single-ion magnet

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yan-Cong; Liu, Jun-Liang; Chen, Xiao-Ming; Tong, Ming-Liang [Key Lab. of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen Univ., Guangzhou (China); Wernsdorfer, Wolfgang [Institut Neel, CNRS and Universite Joseph Fournier, Grenoble (France); Institute of Nanotechnology, Karlsruhe Institute of Technology (Germany); Physikalisches Institut, Karlsruhe Institute of Technology (Germany); Liu, Dan; Chibotaru, Liviu F. [Theory of Nanomaterials Group and INPAC-Institute of Nanoscale Physics and Chemistry, Katholieke Universiteit Leuven (Belgium)

    2017-04-24

    An extremely rare non-Kramers holmium(III) single-ion magnet (SIM) is reported to be stabilized in the pentagonal-bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm{sup -1}. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field-induced QTMs can be observed even from the field-dependent alternating-current magnetic susceptibility in addition to single-crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal-field environment and the hyperfine interactions arising from {sup 165}Ho (I=7/2) with a natural abundance of 100 %. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. Hyperfine structure of electronic levels and the first measurement of the nuclear magnetic moment of {sup 63}Ni

    Energy Technology Data Exchange (ETDEWEB)

    D' yachkov, A.B.; Firsov, V.A.; Gorkunov, A.A.; Labozin, A.V.; Mironov, S.M.; Saperstein, E.E.; Tolokonnikov, S.V.; Tsvetkov, G.O.; Panchenko, V.Y. [National Research Center ' ' Kurchatov Institute' ' , Moscow (Russian Federation)

    2017-01-15

    Laser resonant photoionization spectroscopy was used to study the hyperfine structure of the optical 3d{sup 8}4s{sup 2} {sup 3}F{sub 4} → 3d{sup 8}4s4p {sup 3}G{sup o}{sub 3} and 3d{sup 9}4s {sup 3}D{sub 3} → 3d{sup 8}4s4p {sup 3}G{sup o}{sub 3} transitions of {sup 63}Ni and {sup 61}Ni isotopes. Experimental spectra allowed us to derive hyperfine interaction constants and determine the magnetic dipole moment of the nuclear ground state of {sup 63}Ni for the first time: μ = +0.496(5)μ{sub N}. The value obtained agrees well with the prediction of the self-consistent theory of finite Fermi systems. (orig.)

  10. Searching for an Oscillating Massive Scalar Field as a Dark Matter Candidate Using Atomic Hyperfine Frequency Comparisons.

    Science.gov (United States)

    Hees, A; Guéna, J; Abgrall, M; Bize, S; Wolf, P

    2016-08-05

    We use 6 yrs of accurate hyperfine frequency comparison data of the dual rubidium and caesium cold atom fountain FO2 at LNE-SYRTE to search for a massive scalar dark matter candidate. Such a scalar field can induce harmonic variations of the fine structure constant, of the mass of fermions, and of the quantum chromodynamic mass scale, which will directly impact the rubidium/caesium hyperfine transition frequency ratio. We find no signal consistent with a scalar dark matter candidate but provide improved constraints on the coupling of the putative scalar field to standard matter. Our limits are complementary to previous results that were only sensitive to the fine structure constant and improve them by more than an order of magnitude when only a coupling to electromagnetism is assumed.

  11. Hyperfine electron-nuclear interactions in the frame of the Density Functional and of the Density Matrix Methods

    International Nuclear Information System (INIS)

    Pavlov, R.L.; Pavlov, L.I.; Raychev, P.P.; Garistov, V.P.; Dimitrova-Ivanovich, M.

    2002-01-01

    The matrix elements and expectation values of the hyperfine interaction operators are presented in a form suitable for numerical implementation in density matrix methods. The electron-nuclear spin-spin (dipolar and contact) interactions are considered, as well as the interaction between nuclear spin and electron-orbital motions. These interactions from the effective Breit-Pauli Hamiltonian determine the hyperfine structure in ESR spectra and contribute to chemical shifts in NMR. Applying the Wigner-Eckart theorem in the irreducible tensor-operator technique and the spin-space separation scheme, the matrix elements and expectation values of these relativistic corrections are expressed in analytical form. The final results are presented as products, or sums of products, of factors determined by the spin and (or) angular momentum symmetry and a spatial part determined by the action of the symmetrized tensor-operators on the normalized matrix or function of the spin or charge distribution.

  12. Magnetism, chemical bonding and hyperfine properties in the nanoscale antiferromagnet [Fe(O Me)2(O2 C C H2 Cl)]10

    International Nuclear Information System (INIS)

    Zeng, Z.; Duan, Y.; Guenzburger, Diana

    1996-09-01

    The electronic and magnetic properties of the nanometer-size antiferromagnet (the ferric wheel molecule) are investigated with the first-principles spin-polarized Discrete Variational Method, in the framework of Density Functional theory. Magnetic moments, densities of the states and charge and spin-density maps are obtained. The Moessbauer hyperfine parameters Isomer shift, Quadrupole Splitting and Hyperfine Field are obtained from the calculations and compared to reported experimental values when available. (author). 33 refs., 8 figs., 4 tabs

  13. Elucidation of electronic structure by the analysis of hyperfine interactions: The MnH A 7Π-X 7Sigma + (0,0) band

    Science.gov (United States)

    Varberg, Thomas D.; Field, Robert W.; Merer, Anthony J.

    1991-08-01

    We present a complete analysis of the hyperfine structure of the MnH A 7Π-X 7Σ+ (0,0) band near 5680 Å, studied with sub-Doppler resolution by intermodulated fluorescence spectroscopy. Magnetic hyperfine interactions involving both the 55Mn (I=5/2) and 1H (I=1/2) nuclear spins are observed as well as 55Mn electric quadrupole effects. The manganese Fermi contact interaction in the X 7Σ+ state is the dominant contributor to the observed hyperfine splittings; the ΔF=0, ΔN=0, ΔJ=±1 matrix elements of this interaction mix the electron spin components of the ground state quite strongly at low N, destroying the ``goodness'' of J as a quantum number and inducing rotationally forbidden, ΔJ=±2 and ±3 transitions. The hyperfine splittings of over 50 rotational transitions covering all 7 spin components of both states were analyzed and fitted by least squares, allowing the accurate determination of 14 different hyperfine parameters. Using single electronic configurations to describe the A 7Π and X 7Σ+ states and Herman-Skillman atomic radial wave functions to represent the molecular orbitals, we calculated a priori values for the 55Mn and 1H hyperfine parameters which agree closely with experiment. We show that the five high-spin coupled Mn 3d electrons do not contribute to the manganese hyperfine structure but are responsible for the observed proton magnetic dipolar couplings. Furthermore, the results suggest that the Mn 3d electrons are not significantly involved in bonding and demonstrate that the molecular hyperfine interactions may be quantitatively understood using simple physical interpretations.

  14. Fried-Yennie gauge recalculation of the electron line induced radiative-recoil corrections to muonium hyperfine splitting

    International Nuclear Information System (INIS)

    Brook, V.Yu.; Eides, M.I.; Karshenboim, S.G.; Shelyuto, V.A.

    1989-01-01

    A new analytic calculation of radiative-recoil corrections to muonium ground-state hyperfine splitting induced by electron line insertions is performed. The starting point of this calculation is presented by the Fried-Yennie gauge expression for the electron line factor. The final result confirms the one obtained previously from the apparently different expression in the Feynman gauge and removes the slight discrepancy which existed in the literature between the calculations in different gauges. (orig.)

  15. ENDOR investigations of the Ce.sup.3+./sup. ions in YAG: Transferred hyperfine interaction with nearest aluminum ions

    Czech Academy of Sciences Publication Activity Database

    Azamat, Dmitry; Badalyan, A. G.; Feng, D.H.; Lančok, Ján; Jastrabík, Lubomír; Dejneka, Alexandr; Baranov, P. G.; Yakovlev, D.R.; Bayer, M.

    2017-01-01

    Roč. 122, č. 24 (2017), s. 1-3, č. článku 243903. ISSN 0021-8979 R&D Projects: GA MŠk LO1409; GA ČR GA16-22092S Institutional support: RVO:68378271 Keywords : ENDOR * Ce 3+ ions in YAG * transferred hyperfine interactions Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 2.068, year: 2016

  16. Transferred hyperfine interaction between the rare-earth ions and the fluorine nuclei in rare-earth trifluorides

    DEFF Research Database (Denmark)

    Hansen, P. E.; Nevald, Rolf; Guggenheim, H. G.

    1978-01-01

    The isotropic and anisotropic transferred hyperfine interactions between F ions in the two chemically inequivalent sites and the rare-earth ions (R) have been derived from 19F NMR measurements in the temperature region 100-300 K on single crystals of TbF3 and DyF3. The isotropic interactions are ...... to vary only slightly with temperature. They are further assigned to definite R's in the unit cell, which cannot be done from macroscopic magnetic measurements....

  17. Anomalous behavior of the magnetic hyperfine field at 140Ce impurities at La sites in LaMnSi2

    Science.gov (United States)

    Domienikan, C.; Bosch-Santos, B.; Cabrera-Pasca, G. A.; Saxena, R. N.; Carbonari, A. W.

    2018-05-01

    Magnetic hyperfine field has been measured in the orthorhombic intermetallic compound LaMnSi2 with perturbed angular correlation (PAC) spectroscopy using radioactive 140La(140Ce) nuclear probes. Magnetization measurements were also carried out in this compound with MPSM-SQUID magnetometer. Samples of LaMnSi2 compound were prepared by arc melting the component metals with high purity under argon atmosphere followed by annealing at 1000°C for 60 h under helium atmosphere and quenching in water. X-ray analysis confirmed the samples to be in a single phase with correct crystal structure expected for LaMnSi2 compound. The radioactive 140La (T1/2 = 40 h) nuclei were produced by direct irradiation of the sample with neutrons in the IEA-R1 nuclear research reactor at IPEN with a flux of ˜ 1013 n cm-2s-1 for about 3 - 4 min. The PAC measurements were carried out with a six BaF2 detector spectrometer at several temperatures between 10 K and 400 K. Temperature dependence of the hyperfine field, Bhf was found to be anomalous. A modified two-state model explained this anomalous behavior where the effective magnetic hyperfine field at 140Ce is believed to have two contributions, one from the unstable localized spins at Ce impurities and another from the magnetic Mn atoms of the host. The competition of these two contributions explains the anomalous behavior observed for the temperature dependence of the magnetic hyperfine field at 140Ce. The ferromagnetic transition temperature (TC) of LaMnSi2 was determined to be 400(1) K confirming the magnetic measurements.

  18. Partial tooth gear bearings

    Science.gov (United States)

    Vranish, John M. (Inventor)

    2010-01-01

    A partial gear bearing including an upper half, comprising peak partial teeth, and a lower, or bottom, half, comprising valley partial teeth. The upper half also has an integrated roller section between each of the peak partial teeth with a radius equal to the gear pitch radius of the radially outwardly extending peak partial teeth. Conversely, the lower half has an integrated roller section between each of the valley half teeth with a radius also equal to the gear pitch radius of the peak partial teeth. The valley partial teeth extend radially inwardly from its roller section. The peak and valley partial teeth are exactly out of phase with each other, as are the roller sections of the upper and lower halves. Essentially, the end roller bearing of the typical gear bearing has been integrated into the normal gear tooth pattern.

  19. Moessbauer study of supertransferred hyperfine field of /sup 119/Sn (Sn/sup 4 +/) in Casub(1-x)Srsub(x)MnO/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Takano, M [Konan Univ., Kobe (Japan). Faculty of Science; Takeda, Y; Shimada, M; Matsuzawa, T; Shinjo, T

    1975-09-01

    Casub(1-x)Srsub(x)Mnsub(0.99)Snsub(0.01)O/sub 3/(0<=x<=1) with (nearly) cubic perovskite structures were prepared and the magnetic hyperfine fields of /sup 119/Sn (Sn/sup 4 +/) were measured by the Moessbauer effect. The hyperfine fields arise from unpaired s electron spin densities transferred from Mn/sup 4 +/ ions (supertransferred hyperfine interaction). The hyperfine field for a tin ion was found to depend linearly upon the numbers of Ca/sup 2 +/ and Sr/sup 2 +/ ions in the neighboring divalent cation sites, with proportional coefficients having opposite signs. To explain experimental results two kinds of spin transfer processes contributing to the hyperfine field oppositely to each other have been considered, and spin transfer via a divalent cation is emphasized particularly. The hyperfine field at 0 K for Sn/sup 4 +/ in CaMnO/sub 3/ is -75 kOe, while +20 kOe for Sn/sup 4 +/ in SrMnO/sub 3/.

  20. Time-resolved and doppler-reduced laser spectroscopy on atoms

    International Nuclear Information System (INIS)

    Bergstroem, H.

    1991-10-01

    Radiative lifetimes have been studied in neutral boron, carbon, silicon and strontium, in singly ionized gadolinium and tantalum and in molecular carbon monoxide and C 2 . The time-resolved techniques were based either on pulsed lasers or pulse-modulated CW lasers. Several techniques have been utilized for the production of free atoms and ions such as evaporation into an atomic beam, sputtering in hollow cathodes and laser-produced plasmas. Hyperfine interactions in boron, copper and strontium have been examined using quantum beat spectroscopy, saturation spectroscopy and collimated atomic beam spectroscopy. Measurement techniques based on effusive hollow cathodes as well as laser produced plasmas in atomic physics have been developed. Investigations on laser produced plasmas using two colour beam deflection tomography for determination of electron densities have been performed. Finally, new possibilities for view-time-expansion in light-in-flight holography using mode-locked CW lasers have been demonstrated. (au)

  1. Hyperfine structure in 5s4d [sup 3]D-5snf transitions of [sup 87]Sr

    Energy Technology Data Exchange (ETDEWEB)

    Bushaw, B.A. (Pacific Northwest Lab., Richland, WA (United States)); Kluge, H.J. (Mainz Univ. (Germany). Inst. fuer Physik); Lantzsch, J. (Mainz Univ. (Germany). Inst. fuer Physik); Schwalbach, R. (Mainz Univ. (Germany). Inst. fuer Physik); Stenner, J. (Mainz Univ. (Germany). Inst. fuer Physik); Stevens, H. (Mainz Univ. (Germany). Inst. fuer Physik); Wendt, K. (Mainz Univ. (Germany). Inst. fuer Physik); Zimmer, K. (Mainz Univ. (Germany). Inst. fuer Physik)

    1993-12-01

    The hyperfine spectra of the 5s4d[sup 3]D[sub 1]-5s20f, 5s4d[sup 3]D[sub 2]-5s23f, and 5s4d[sup 3]D[sub 3]-5s32f transitions of [sup 87]Sr (I=9/2) have been measured by collinear fast beam laser spectroscopy. The structure in the upper configurations is highly perturbed by fine structure splitting that is of comparable size to the hyperfine interaction energy. These perturbations can be adequately treated with conventional matrix diagonalization methods, using the 5s-electron magnetic dipole interaction term a[sub 5s] and the unperturbed fine structure splittings as input parameters. Additionally, hyperfine constants for the lower 5s4d[sup 3]D configurations, including the A- and B-factors and a separation of the individual s- and d-electron contributions to these factors, are derived. (orig.)

  2. Hyperfine fields and spin relaxation of Ce in GdAl2 and DyAl2

    International Nuclear Information System (INIS)

    Waeckelgaard, E.; Karlsson, E.; Lindgren, B.; Mayer, A.

    1987-04-01

    We have investigated the ferromagnetic state of the cubic intermetallic compounds GdAl 2 and DyAl 2 with the 140 Ce nuclei using DPAC. The local fields of Ce are for the lowest measured temperatures B eff (30 K) = 54(2) T for GdAl 2 and B eff (12.5 K) = 27(1) T for DyAl 2 which are considerably lower than the hyperfine field measured for a free Ce ion (183 T). By introducing a crystal field, of cubic symmetry, a lower hyperfine field is obtained which is in quantitative agreement with the local field of Ce in GdAl 2 . For DyAl 2 an additional effect, represented by a non-magnetic level below the lowest magnetic level, may explain a further reduction of the hyperfine field. Two models relating to a Kondo non-magnetic state of Ce are discussed. Spin relaxation in the paramagnetic state are also studied and compared with observations of the same systems measured with μSR. (authors)

  3. Essays on partial retirement

    NARCIS (Netherlands)

    Kantarci, T.

    2012-01-01

    The five essays in this dissertation address a range of topics in the micro-economic literature on partial retirement. The focus is on the labor market behavior of older age groups. The essays examine the economic and non-economic determinants of partial retirement behavior, the effect of partial

  4. Determination of hyperfine fields and atomic ordering in NiMnFeGe exhibiting martensitic transformation

    Directory of Open Access Journals (Sweden)

    Satuła Dariusz

    2015-03-01

    Full Text Available The hyperfine fields and atomic ordering in Ni1−xFexMnGe (x = 0.1, 0.2, 0.3 alloys were investigated using X-ray diffraction and Mössbauer spectroscopy at room temperature. The X-ray diffraction measurements show that the samples with x = 0.2, 0.3 crystallized in the hexagonal Ni2In-type of structure, whereas in the sample with x = 0.1, the coexistence of two phases, Ni2In- and orthorhombic TiNiSi-type of structures, were found. The Mössbauer spectra measured with x = 0.2, 0.3 show three doublets with different values of isomer shift (IS and quadrupole splitting (QS related to three different local surroundings of Fe atoms in the hexagonal Ni2In-type structure. It was shown that Fe atoms in the hexagonal Ni2In-type structure of as-cast Ni1−xFexMnGe alloys are preferentially located in Ni sites and small amount of Fe is located in Mn and probably in Ge sites. The spectrum for x = 0.1 shows the doublets in the central part of spectrum and a broad sextet. The doublets originate from the Fe atoms in the paramagnetic state of hexagonal Ni2In-type structure, whereas the sextet results from the Fe atoms in orthorhombic TiNiSi-type structure.

  5. Hyperfine structure measurements of neutral iodine atom (127I) using Fourier Transform Spectrometry

    Science.gov (United States)

    Ashok, Chilukoti; Vishwakarma, S. R.; Bhatt, Himal; Ankush, B. K.; Deo, M. N.

    2018-01-01

    We report the hyperfine Structure (hfs) splitting observations of neutral iodine atom (II) in the 6000 - 10,000 cm-1 near infrared spectral region. The measurements were carried out using a high-resolution Fourier Transform Spectrometer (FTS), where an electrodeless discharge lamp (EDL), excited using microwaves, was employed as the light source and InGaAs as the light detector. A specially designed setup was used to lower the plasma temperature of the medium so as to reduce the Doppler width and consequently to increase the spectral resolution of hfs components. A total of 183 lines with hfs splitting have been observed, out of which hfs in 53 spectral lines are reported for the first time. On the basis of hfs analysis, we derived the magnetic dipole and electric quadrupole coupling constants, A and B respectively for 30 even and 30 odd energy levels and are compared with the values available in the literature. New hfs values for 5 even and 4 odd levels are also reported here for the first time.

  6. Analytic calculation of radiative-recoil corrections to muonium hyperfine splitting: Electron-line contribution

    International Nuclear Information System (INIS)

    Eides, M.I.; Karshenboim, S.G.; Shelyuto, V.A.

    1991-01-01

    The detailed account of analytic calculation of radiative-recoil correction to muonium hyperfine splitting, induced by electron-line radiative insertions, is presented. The consideration is performed in the framework of the effective two-particle formalism. A good deal of attention is paid to the problem of the divergence cancellation and the selection of graphs, relevant to radiative-recoil corrections. The analysis is greatly facilitated by use of the Fried-Yennie gauge for radiative photons. The obtained set of graphs turns out to be gauge-invariant and actual calculations are performed in the Feynman gauge. The main technical tricks, with the help of which we have effectively utilized the existence in the problem of the small parameter-mass ratio and managed to perform all calculations in the analytic form are described. The main intermediate results, as well as the final answer, δE rr = (α(Ζα)/π 2 )(m/M)E F (6ζ(3) + 3π 2 In 2 + π 2 /2 + 17/8), are also presented

  7. Systematic model calculations of the hyperfine structure in light and heavy ions

    CERN Document Server

    Tomaselli, M; Nörtershäuser, W; Ewald, G; Sánchez, R; Fritzsche, S; Karshenboim, S G

    2003-01-01

    Systematic model calculations are performed for the magnetization distributions and the hyperfine structure (HFS) of light and heavy ions with a mass close to A ~ 6 208 235 to test the interplay of nuclear and atomic structure. A high-precision measurement of lithium-isotope shifts (IS) for suitable transition, combined with an accurate theoretical evaluation of the mass-shift contribution in the respective transition, can be used to determine the root-mean-square (rms) nuclear-charge radius of Li isotopes, particularly of the halo nucleus /sup 11/Li. An experiment of this type is currently underway at GSI in Darmstadt and ISOLDE at CERN. However, the field-shift contributions between the different isotopes can be evaluated using the results obtained for the charge radii, thus casting, with knowledge of the ratio of the HFS constants to the magnetic moments, new light on the IS theory. For heavy charged ions the calculated n- body magnetization distributions reproduce the HFS of hydrogen-like ions well if QED...

  8. Combined ion beam and hyperfine interaction studies of LiNbO3 single crystals

    International Nuclear Information System (INIS)

    Marques, J.G.; Kling, A.; Soares, J.C.; Rebouta, L.

    1999-01-01

    A review of recent studies of LiNbO 3 crystals doped with Hf and Mg,Hf combining high precision RBS/channelling, PIXE/channelling and hyperfine interaction techniques is presented. The lattice location of Hf was found to depend strongly on the dopant concentration, crystal stoichiometry and Mg co-doping level. At low concentrations Hf occupies Li sites in congruent crystals, while it occupies both Li and Nb sites for higher doping levels or in near-stoichiometric crystals. Co-doping with Mg also forces a split location of Hf in Li and Nb sites and when the MgO amount exceeds 4.5 mol% Hf occupies only Nb sites. Neutron irradiation of these crystals displaces Hf from its initial lattice site and leads to a strong decrease of the Nb site fraction. The results are discussed in the framework of the Li and Nb vacancy models currently proposed in the literature for the defect structure of LiNbO 3 . (author)

  9. Singlet-to-triplet interconversion using hyperfine as well as ferromagnetic fringe fields.

    Science.gov (United States)

    Wohlgenannt, M; Flatté, M E; Harmon, N J; Wang, F; Kent, A D; Macià, F

    2015-06-28

    Until recently the important role that spin-physics ('spintronics') plays in organic light-emitting devices and photovoltaic cells was not sufficiently recognized. This attitude has begun to change. We review our recent work that shows that spatially rapidly varying local magnetic fields that may be present in the organic layer dramatically affect electronic transport properties and electroluminescence efficiency. Competition between spin-dynamics due to these spatially varying fields and an applied, spatially homogeneous magnetic field leads to large magnetoresistance, even at room temperature where the thermodynamic influences of the resulting nuclear and electronic Zeeman splittings are negligible. Spatially rapidly varying local magnetic fields are naturally present in many organic materials in the form of nuclear hyperfine fields, but we will also review a second method of controlling the electrical conductivity/electroluminescence, using the spatially varying magnetic fringe fields of a magnetically unsaturated ferromagnet. Fringe-field magnetoresistance has a magnitude of several per cent and is hysteretic and anisotropic. This new method of control is sensitive to even remanent magnetic states, leading to different conductivity/electroluminescence values in the absence of an applied field. We briefly review a model based on fringe-field-induced polaron-pair spin-dynamics that successfully describes several key features of the experimental fringe-field magnetoresistance and magnetoelectroluminescence. © 2015 The Author(s) Published by the Royal Society. All rights reserved.

  10. Helium Pressure Shift of the Hyperfine Clock Transition in Hg-201(+)

    Science.gov (United States)

    Larigani, S. Taghavi; Burt, E. A.; Tjoelker, R. L.

    2010-01-01

    There are two stable odd isotopes of mercury with singly ionized hyperfine structure suitable for a microwave atomic clock: Hg-199(+) and Hg-201(+). We are investigating the viability of a trapped ion clock based on Hg-201(+) in a configuration that uses a buffer gas to increase ion loading efficiency and counter ion heating from rf trapping fields. Traditionally, either helium or neon is used as the buffer gas at approx. 10(exp -5) torr to confine mercury ions near room temperature. In addition to the buffer gas, other residual background gasses such as H2O, N2, O2, CO, CO2, and CH2 may be present in trace quantities. Collisions between trapped ions and buffer gas or background gas atoms/molecules produce a momentary shift of the ion clock transition frequency and constitute one of the largest systematic effects in this type of clock. Here we report an initial measurement of the He pressure shift in Hg-201(+) and compare this to Hg-199(+).

  11. Leggett-Garg inequalities violation via the Fermi contact hyperfine interaction

    Energy Technology Data Exchange (ETDEWEB)

    Lobejko, Marcin; Dajka, Jerzy [Institute of Physics, University of Silesia, Katowice (Poland); Silesian Center for Education and Interdisciplinary Research, University of Silesia, Chorzow (Poland)

    2017-06-15

    In this paper we examine theoretically how the spin-spin interaction between a nuclei and an electron in the atom affects violation of the Leggett-Garg inequalities. We consider the simplest case of atoms in the {sup 2}S{sub 1/2} state that in the valence shell have just a single electron and the evolution in time of the spin is dictated only by the Fermi contact hyperfine interaction. We found that for special initial conditions and a particular measured observable the high spin nucleus couple to the valence electron such that violation of Leggett-Garg inequalities increases with total spin of states. Consequently, our results show that for the Hydrogen, the smallest atom in Nature, the violation of the Leggett-Garg inequalities is the smallest whereas for the largest atom, the Cesium, the violation is the largest. Moreover, this violation does not depend on a principal quantum number, thus our model can be used for Rydberg atoms in order to test macrorealism for 'almost macroscopic' objects. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Velocity dependence of transient hyperfine field at Pt ions rapidly recoiling through magnetized Fe

    International Nuclear Information System (INIS)

    Stuchbery, A.E.; Ryan, C.G.; Bolotin, H.H.

    1981-01-01

    The velocity-dependence of the transient hyperfine magnetic field acting at nuclei of 196 Pt ions rapidly recoiling through thin magnetized Fe was investigated at a number of recoil velocities. The state of interest (2 1 + ) was populated by Coulomb excitation using beams of 80- and 120-MeV 32 S and 150- and 220-MeV 58 Ni ions. The 2 1 + →0 1 + γ-ray angular distribution precession measurements were carried out in coincidence with backscattered projectiles. From these results, the strength of the transient field acting on Pt ions recoiling through magnetized Fe with average velocities in the extended range 2.14<=v/vsub(o)<=4.82 (vsub(o) = c/137) was found to be consistent with a linear velocity dependence and to be incompatible with the specific vsup(0.45+-0.18) dependence which has been previously reported to account well for all ions in the mass range from oxygen through samarium. This seemingly singular behaviour for Pt and other ions in the Pt mass vicinity is discussed

  13. Maraging-350 steel: Following the aging through diffractometric, magnetic and hyperfine analysis

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, G.C.S. [Universidade Estadual de Maringá, Departamento de Física, Av. Colombo, 5790, PR, 87.020-900 Brazil (Brazil); Sarvezuk, P.W.C. [Universidade Tecnológica Federal do Paraná, Campo Mourão, PR (Brazil); Alves, T.J.B.; Biondo, V.; Ivashita, F.F. [Universidade Estadual de Maringá, Departamento de Física, Av. Colombo, 5790, PR, 87.020-900 Brazil (Brazil); Paesano, A., E-mail: paesano@wnet.com.br [Universidade Estadual de Maringá, Departamento de Física, Av. Colombo, 5790, PR, 87.020-900 Brazil (Brazil)

    2017-01-01

    Plates of solution annealed Maraging-350 steel were submitted to aging under an inert atmosphere, varying the time and temperature. The aged samples were characterized by X-ray diffraction and Mössbauer spectroscopy. The results revealed that the aging treatments induced the reversion of austenite, in amounts that vary with the time and the temperature of the heat treatment. The lattice parameters of the martensite and austenite phases, as well as their hyperfine parameters, were obtained at all aging conditions. No intermetallic compounds were identified in any of the aged samples, but a poorly crystallized phase fraction, the consequence of an incomplete martensite ⇒ austenite reversion transformation, was observed for some samples. The tetragonal distortion from cubic symmetry presented by the martensite in the solution annealed steel was not eliminated after aging. - Highlights: • We report a fine characterization of aged Maraging-350 steel. • Martensite shows a crystallographic distortion from the cubic symmetry. • Reverted austenite is present in amounts that depend on the aging conditions. • Properties measured are key information for a proper control of the steel aging.

  14. Unravelling the local structure of topological crystalline insulators using hyperfine interactions

    CERN Multimedia

    Phenomena emerging from relativistic electrons in solids have become one the main topical subjects in condensed matter physics. Among a wealth of intriguing new phenomena, several classes of materials have emerged including graphene, topological insulators and Dirac semi-metals. This project is devoted to one such class of materials, in which a subtle distortion of the crystalline lattice drives a material through different topological phases: Z$_{2}$ topological insulator (Z$_{2}$-TI), topological crystalline insulator (TCI), or ferroelectric Rashba semiconductor (FERS). We propose to investigate the local structure of Pb$_{1-x}$Sn$_{x}$Te and Ge$_{1-x}$Sn$_{x}$Te (with $\\textit{x}$ from 0 to 1) using a combination of experimental techniques based on hyperfine interactions: emission Mössbauer spectroscopy (eMS) and perturbed angular correlation spectroscopy (PAC). In particular, we propose to study the effect of composition ($\\textit{x}$ in Pb$_{1-x}$Sn$_{x}$Te and Ge$_{1-x}$Sn$_{x}$Te) on: \\\\ \\\\(1) the mag...

  15. Experimental and theoretical study of the hyperfine structure in the lower configurations in 45Sc II

    International Nuclear Information System (INIS)

    Villemoes, P.; van Leeuwen, R.; Arnesen, A.; Heijkenskjoeld, F.; Kastberg, A.; Larsson, M.O.; Kotochigova, S.A.

    1992-01-01

    We have measured the hyperfine structure (hfs) of 12 levels in the configurations 3d4s, 3d 2 , and 3d4p in singly ionized scandium by collinear fast-ion-beam--laser spectroscopy. The hfs of the four levels in the configuration 3d4s has to our knowledge not been measured before. From these levels the ions were excited to levels in the 3d4p configuration by the frequency-doubled output of a ring dye laser with an intracavity mounted LiIO 3 crystal. Levels in the 3d 2 configuration were excited to levels in the 3d4p configuration with visible laser light. The resulting magnetic dipole (A) and electric quadrupole (B) hfs constants are analyzed in Sandars-Beck effective-operator formalism. The multiconfiguration Dirac-Fock method has been used to calculate the hfs constants for levels in the configurations 3d4s, 3d5s, 3d6s, 3d 2 , and 3d4p. Within the framework of the configuration-interaction method, an approach is presented for the calculation of the core polarization, which uses a virtual basis set localized inside the core. For all levels, this approach gives better results compared to previously published calculations

  16. Structural, hyperfine and Raman properties of RE2FeSbO7 compounds

    International Nuclear Information System (INIS)

    Berndt, G.; Silva, K.L.; Ivashita, F.F.; Paesano, A.; Blanco, M.C.; Miner, E.V.P.; Carbonio, R.E.; Dantas, S.M.; Ayala, A.P.; Isnard, O.

    2015-01-01

    Highlights: • We prepared monophasic RE 2 FeSbO 7 pyrochlores. • RE 2 FeSbO 7 compounds were characterized regarding crystallographic, vibrational and hyperfine properties. • We find out that a site disorder takes place for the RE’s of larger ionic radii. • Lattice parameters, Raman bands and quadrupole splittings were shown to depend correlatedly on the RE ionic radius. - Abstract: Pyrochlores of the RE 2 FeSbO 7 type were synthesized by ball-milling followed by annealing in free atmosphere at high temperatures. The samples prepared were characterized by X-ray diffraction, Raman spectroscopy and 57 Fe Mössbauer spectroscopy, at room temperature. The results showed that RE 2 FeSbO 7 compounds have a cubic structure, i.e., Fd-3m (#227) space group, and that a site disorder takes place for the RE’s of larger ionic radii. Lattice parameters, Raman bands and quadrupole splittings were shown to depend correlatedly on the RE ionic radius. This behavior is discussed in terms of the pyrochlore crystallographic structure

  17. In-beam measurement of the hydrogen hyperfine splitting and prospects for antihydrogen spectroscopy.

    Science.gov (United States)

    Diermaier, M; Jepsen, C B; Kolbinger, B; Malbrunot, C; Massiczek, O; Sauerzopf, C; Simon, M C; Zmeskal, J; Widmann, E

    2017-06-12

    Antihydrogen, the lightest atom consisting purely of antimatter, is an ideal laboratory to study the CPT symmetry by comparison with hydrogen. With respect to absolute precision, transitions within the ground-state hyperfine structure (GS-HFS) are most appealing by virtue of their small energy separation. ASACUSA proposed employing a beam of cold antihydrogen atoms in a Rabi-type experiment, to determine the GS-HFS in a field-free region. Here we present a measurement of the zero-field hydrogen GS-HFS using the spectroscopy apparatus of ASACUSA's antihydrogen experiment. The measured value of ν HF =1,420,405,748.4(3.4) (1.6) Hz with a relative precision of 2.7 × 10 -9 constitutes the most precise determination of this quantity in a beam and verifies the developed spectroscopy methods for the antihydrogen HFS experiment to the p.p.b. level. Together with the recently presented observation of antihydrogen atoms 2.7 m downstream of the production region, the prerequisites for a measurement with antihydrogen are now available within the ASACUSA collaboration.

  18. Temperature-induced variation in the intrinsic hyperfine separation of a tightly bound nitroxide spin label

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, M.E.

    1979-01-01

    Recently there has been increasing interest in studying the rotational motion of biological molecules by monitoring the electron paramagnetic resonance (EPR) spectra of spin labels which are tightly bound to the molecule of interest. Theoretical studies have shown that in the slow motion region the correlation time may be determined by comparing the apparent hyperfine separation (HFS) in the presence of rotational motion with the rigid limit HFS in the absence of rotational motion. The majority of work to date has assumed the tightly bound nitroxide label to act simply as a reporter group for molecular motion, exhibiting little or no intrinsic environmental or temperature sensitivity. However, we have demonstrated that the rigid limit EPR spectra exhibit a substantial intrinsic temperature dependence, with the rigid limit HFS of MAL-6-labelled carboxyhemoglobin (HbCO) decreasing by nearly 10G over the temperature range -196/sup 0/C to +45/sup 0/C. The steepest temperature dependence was also found to occur over the 0 to 40/sup 0/C temperature range where most biological measurements are made. This strong temperature dependence in the intrinsic HFS was shown to produce substantial errors in correlation time calculations if it was not explicitly recognized and appropriate corrections made. This detailed behavior of this intrinsic temperature dependence suggests that it is most probably produced by equilibrium hydrogen bonding between the nitroxide NO/sup ./ group and an unidentified proton donor within the spin label binding site. (RJC)

  19. Resolved nuclear hyperfine structure of muonium centres in CuCl and GaAs by means of the avoided-level-crossing technique

    International Nuclear Information System (INIS)

    Schneider, J.W.; Keller, H.; Schmid, B.; Boesiger, K.; Kuendig, W.; Odermatt, W.; Patterson, B.D.; Puempin, B.; Simmler, H.; Savic, I.M.; Heming, M.; Reid, I.D.; Roduner, E.; Louwrier, P.W.F.

    1988-01-01

    Avoided-level-crossing resonances from isotropic muonium centres interacting with neighbouring nuclear spins in powdered CuCl are reported. The prominent resonances have a complex multiline structure and are strongly temperature-dependent. In addition, previously unobserved resonances in single-crystal GaAs from anomalous muonium interacting with a 71 Ga neighbour are presented. (orig.)

  20. First principles density functional calculation of magnetic moment and hyperfine fields of dilute transition metal impurities in Gd host

    International Nuclear Information System (INIS)

    Mohanta, S.K.; Mishra, S.N.; Srivastava, S.K.

    2014-01-01

    We present first principles calculations of electronic structure and magnetic properties of dilute transition metal (3d, 4d and 5d) impurities in a Gd host. The calculations have been performed within the density functional theory using the full potential linearized augmented plane wave technique and the GGA+U method. The spin and orbital contributions to the magnetic moment and the hyperfine fields have been computed. We find large magnetic moments for 3d (Ti–Co), 4d (Nb–Ru) and 5d (Ta–Os) impurities with magnitudes significantly different from the values estimated from earlier mean field calculation [J. Magn. Magn. Mater. 320 (2008) e446–e449]. The exchange interaction between the impurity and host Gd moments is found to be positive for early 3d elements (Sc–V) while in all other cases an anti-ferromagnetic coupling is observed. The trends for the magnetic moment and hyperfine field of d-impurities in Gd show qualitative difference with respect to their behavior in Fe, Co and Ni. The calculated total hyperfine field, in most cases, shows excellent agreement with the experimental results. A detailed analysis of the Fermi contact hyperfine field has been made, revealing striking differences for impurities having less or more than half filled d-shell. The impurity induced perturbations in host moments and the change in the global magnetization of the unit cell have also been computed. The variation within each of the d-series is found to correlate with the d–d hybridization strength between the impurity and host atoms. - Highlights: • Detailed study of transition metal impurities in ferromagnetic Gd has been carried out. • The trends in impurity magnetic moment are qualitatively different from Fe, Co and Ni. • The variation within each of the d-series is found to correlate with the d–d hybridization strength between the impurity and host atoms. • Experimental trend in a hyperfine field has been reproduced successfully

  1. Recurrent Partial Words

    Directory of Open Access Journals (Sweden)

    Francine Blanchet-Sadri

    2011-08-01

    Full Text Available Partial words are sequences over a finite alphabet that may contain wildcard symbols, called holes, which match or are compatible with all letters; partial words without holes are said to be full words (or simply words. Given an infinite partial word w, the number of distinct full words over the alphabet that are compatible with factors of w of length n, called subwords of w, refers to a measure of complexity of infinite partial words so-called subword complexity. This measure is of particular interest because we can construct partial words with subword complexities not achievable by full words. In this paper, we consider the notion of recurrence over infinite partial words, that is, we study whether all of the finite subwords of a given infinite partial word appear infinitely often, and we establish connections between subword complexity and recurrence in this more general framework.

  2. Healthcare Teams Neurodynamically Reorganize When Resolving Uncertainty

    Directory of Open Access Journals (Sweden)

    Ronald Stevens

    2016-11-01

    Full Text Available Research on the microscale neural dynamics of social interactions has yet to be translated into improvements in the assembly, training and evaluation of teams. This is partially due to the scale of neural involvements in team activities, spanning the millisecond oscillations in individual brains to the minutes/hours performance behaviors of the team. We have used intermediate neurodynamic representations to show that healthcare teams enter persistent (50–100 s neurodynamic states when they encounter and resolve uncertainty while managing simulated patients. Each of the second symbols was developed situating the electroencephalogram (EEG power of each team member in the contexts of those of other team members and the task. These representations were acquired from EEG headsets with 19 recording electrodes for each of the 1–40 Hz frequencies. Estimates of the information in each symbol stream were calculated from a 60 s moving window of Shannon entropy that was updated each second, providing a quantitative neurodynamic history of the team’s performance. Neurodynamic organizations fluctuated with the task demands with increased organization (i.e., lower entropy occurring when the team needed to resolve uncertainty. These results show that intermediate neurodynamic representations can provide a quantitative bridge between the micro and macro scales of teamwork.

  3. Precision Measurements of Atomic Lifetimes and Hyperfine Energies in Alkali Like Systems

    International Nuclear Information System (INIS)

    Tanner, Carol E.

    2005-01-01

    Financial support of this research project has lead to advances in the study of atomic structure through precision measurements of atomic lifetimes, energy splittings, and transitions energies. The interpretation of data from many areas of physics and chemistry requires an accurate understanding of atomic structure. For example, scientists in the fields of astrophysics, geophysics, and plasma fusion depend on transition strengths to determine the relative abundances of elements. Assessing the operation of discharges and atomic resonance line filters also depends on accurate knowledge of transition strengths. Often relative transition strengths are measured precisely, but accurate atomic lifetimes are needed to obtain absolute values. Precision measurements of atomic lifetimes and energy splittings also provide fundamentally important atomic structure information. Lifetimes of allowed transitions depend most strongly on the electronic wave function far from the nucleus. Alternatively, hyperfine splittings give important information about the electronic wave function in the vicinity of the nucleus as well as the structure of the nucleus. Our main focus throughout this project has been the structure of atomic cesium because of its connection to the study of atomic parity nonconservation (PNC). The interpretation of atomic PNC experiments in terms of weak interaction coupling constants requires accurate knowledge of the electronic wave function near the nucleus as well as far from the nucleus. It is possible to address some of these needs theoretically with sophisticated many-electron atomic structure calculations. However, this program has been able to address these needs experimentally with a precision that surpasses current theoretical accuracy. Our measurements also play the important role of providing a means for testing the accuracy of many-electron calculations and guiding further theoretical development, Atomic systems such as cesium, with a single electron

  4. Precision Measurements of Atomic Lifetimes and Hyperfine Energies in Alkali Like Systems

    Energy Technology Data Exchange (ETDEWEB)

    Tanner, Carol E.

    2005-03-04

    Financial support of this research project has lead to advances in the study of atomic structure through precision measurements of atomic lifetimes, energy splittings, and transitions energies. The interpretation of data from many areas of physics and chemistry requires an accurate understanding of atomic structure. For example, scientists in the fields of astrophysics, geophysics, and plasma fusion depend on transition strengths to determine the relative abundances of elements. Assessing the operation of discharges and atomic resonance line filters also depends on accurate knowledge of transition strengths. Often relative transition strengths are measured precisely, but accurate atomic lifetimes are needed to obtain absolute values. Precision measurements of atomic lifetimes and energy splittings also provide fundamentally important atomic structure information. Lifetimes of allowed transitions depend most strongly on the electronic wave function far from the nucleus. Alternatively, hyperfine splittings give important information about the electronic wave function in the vicinity of the nucleus as well as the structure of the nucleus. Our main focus throughout this project has been the structure of atomic cesium because of its connection to the study of atomic parity nonconservation (PNC). The interpretation of atomic PNC experiments in terms of weak interaction coupling constants requires accurate knowledge of the electronic wave function near the nucleus as well as far from the nucleus. It is possible to address some of these needs theoretically with sophisticated many-electron atomic structure calculations. However, this program has been able to address these needs experimentally with a precision that surpasses current theoretical accuracy. Our measurements also play the important role of providing a means for testing the accuracy of many-electron calculations and guiding further theoretical development, Atomic systems such as cesium, with a single electron

  5. Hyperfine Induced Transitions as Diagnostics of Isotopic Composition and Densities of Low-Density Plasmas

    Science.gov (United States)

    Brage, Tomas; Judge, Philip G.; Aboussaïd, Abdellatif; Godefroid, Michel R.; Jönsson, Per; Ynnerman, Anders; Froese Fischer, Charlotte; Leckrone, David S.

    1998-06-01

    The J = 0 --> J' = 0 radiative transitions, usually viewed as allowed through two-photon decay, may also be induced by the hyperfine (HPF) interaction in atoms or ions having a nonzero nuclear spin. We compute new and review existing decay rates for the nsnp 3PoJ --> ns2 1SJ'=0 transitions in ions of the Be (n = 2) and Mg (n = 3) isoelectronic sequences. The HPF induced decay rates for the J = 0 --> J' = 0 transitions are many orders of magnitude larger than those for the competing two-photon processes, and when present are typically 1 or 2 orders of magnitude smaller than the decay rates of the magnetic quadrupole (J = 2 --> J' = 0) transitions for these ions. Several HPF induced transitions are potentially of astrophysical interest in ions of C, N, Na, Mg, Al, Si, K, Cr, Fe, and Ni. We highlight those cases that may be of particular diagnostic value for determining isotopic abundance ratios and/or electron densities from UV or EUV emission-line data. We present our atomic data in the form of scaling laws so that, given the isotopic nuclear spin and magnetic moment, a simple expression yields estimates for HPF induced decay rates. We examine some UV and EUV solar and nebular data in light of these new results and suggest possible applications for future study. We could not find evidence for the existence of HPF induced lines in the spectra we examined, but we demonstrate that existing data have come close to providing interesting upper limits. For the planetary nebula SMC N2, we derive an upper limit of 0.1 for 13C/12C from Goddard High-Resolution Spectrograph data obtained by Clegg. It is likely that more stringent limits could be obtained using newer data with higher sensitivities in a variety of objects.

  6. Time resolved techniques: An overview

    International Nuclear Information System (INIS)

    Larson, B.C.; Tischler, J.Z.

    1990-06-01

    Synchrotron sources provide exceptional opportunities for carrying out time-resolved x-ray diffraction investigations. The high intensity, high angular resolution, and continuously tunable energy spectrum of synchrotron x-ray beams lend themselves directly to carrying out sophisticated time-resolved x-ray scattering measurements on a wide range of materials and phenomena. When these attributes are coupled with the pulsed time-structure of synchrotron sources, entirely new time-resolved scattering possibilities are opened. Synchrotron beams typically consist of sub-nanosecond pulses of x-rays separated in time by a few tens of nanoseconds to a few hundred nanoseconds so that these beams appear as continuous x-ray sources for investigations of phenomena on time scales ranging from hours down to microseconds. Studies requiring time-resolution ranging from microseconds to fractions of a nanosecond can be carried out in a triggering mode by stimulating the phenomena under investigation in coincidence with the x-ray pulses. Time resolution on the picosecond scale can, in principle, be achieved through the use of streak camera techniques in which the time structure of the individual x-ray pulses are viewed as quasi-continuous sources with ∼100--200 picoseconds duration. Techniques for carrying out time-resolved scattering measurements on time scales varying from picoseconds to kiloseconds at present and proposed synchrotron sources are discussed and examples of time-resolved studies are cited. 17 refs., 8 figs

  7. Hyperfine magnetic fields at 57Fe and 119Sn nuclei in the Fe48Rh52 alloy under pressure

    International Nuclear Information System (INIS)

    Nikolaev, I.N.; Potapov, V.N.; Bezotosnyj, I.Yu.; Mar'in, V.P.

    1978-01-01

    The pressure dependences of the hyperfine magnetic fields, H, and isomer shifts epsilon at the 57 Fe and 119 Sn nuclei in the Fe 48 Rh 52 alloy with an admixture of approximately 1 at. % Sn are measured by the Moessbauer effect technique. Under pressure epsilon decreases this signifying an increase (for 57 Fe) or decrease (for 119 Sn) of the s-electron density at the nuclei. In the ferromagnetic (FM) state at 398 K, ΔH/HΔp=(-2.8+-0.2)x10 -3 kbar -1 for 57 Fe and ΔH/HΔp=(-4.8+-0.8)x10 -3 kbar -1 for 119 Sn. In the antiferromagnetic (AFM) state at 78 K, ΔH/HΔp approximately 0 for 57 Fe and ΔH/HΔp=(-6.2+-1.0)x10 -3 kbar -1 for 119 Sn. The results for 57 Fe in the FM state can be ascribed to the strong dependence of the alloy matrix magnetization on the pressure and in the AFM state to the absence of local polarization of s-similar collectivized electrons and to the independence of the magnetic moments of the Fe ions of pressure. The causes of the different effect of pressure on the magnetic moments of Fe ions in the FM and AFM states are discussed. The results for 119 Sn in the FM and AFM states of the alloy are in agreement with the model of hyperfine fields at impurity Sn atoms in the magnetic matrices proposed earlier. The radial dependence of the hyperfine field at the 119 Sn nuclei in the AFM state is estimated and it is found that H(r) is stronger than r -9

  8. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1990-05-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1990) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. Also included are a number of enforcement actions that had been previously resolved but not published in this NUREG. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  9. Time-resolved ESR spectroscopy

    International Nuclear Information System (INIS)

    Beckert, D.

    1986-06-01

    The time-resolved ESR spectroscopy is one of the modern methods in radiospectroscopy and plays an important role in solving various problems in chemistry and biology. Proceeding from the basic ideas of time-resolved ESR spectroscopy the experimental equipment is described generally including the equipment developed at the Central Institute of Isotope and Radiation Research. The experimental methods applied to the investigation of effects of chemically induced magnetic polarization of electrons and to kinetic studies of free radicals in polymer systems are presented. The theory of radical pair mechanism is discussed and theoretical expressions are summarized in a computer code to compute the theoretical polarization for each pair of the radicals

  10. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1989-06-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1989) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. Also included are a number of enforcement actions that had been previously resolved but not published in this NUREG. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  11. Structure and Hyperfine Interactions in Aurivillius Bi9Ti3Fe5O27 Conventionally Sintered Compound

    International Nuclear Information System (INIS)

    Mazurek, M.; Lisinska-Czekaj, A.; Surowiec, Z.; Jartych, E.; Czekaj, D.

    2011-01-01

    The structure and hyperfine interactions in the Bi 9 Ti 3 Fe 5 O 27 Aurivillius compound were studied using X-ray diffraction and Moessbauer spectroscopy. Samples were prepared by the conventional solid-state sintering method at various temperatures. An X-ray diffraction analysis proved that the sintered compounds formed single phases at temperature above 993 K. Moessbauer measurements have been carried out at room and liquid nitrogen temperatures. Room-temperature Moessbauer spectrum of the Bi 9 Ti 3 Fe 5 O 27 compound confirmed its paramagnetic properties. However, low temperature measurements revealed the additional paramagnetic phase besides the antiferromagnetic one. (authors)

  12. The method of extraction of subspectra with appreciably different values of hyperfine interaction parameters from Moessbauer spectra

    International Nuclear Information System (INIS)

    Nemtsova, O.M.

    2006-01-01

    The task of Moessbauer spectra processing of complex locally inhomogeneous or multi-phase systems is to reveal subspectral contributions with appreciably different values of hyperfine interaction parameters (HFI) in them. A universal method of processing such spectra is suggested which allows to extract the probability density distribution (PDD) of HFI parameters corresponding to the subspectra with essentially different parameters values. The basis of the method is Tikhonov's regularization method with selection for each subspectrum its own value of the regularization parameter. The universal application of the method is demonstrated in the examples of processing real spectra with different sets of subspectral contributions

  13. Hyperfine Interactions in the Electron Paramagnetic Resonance Spectra of Point Defects in Wide-Band-Gap Semiconductors

    Science.gov (United States)

    2014-09-18

    between the 5s electron and the silver nucleus. Breit and Rabi [5] described this hyperfine interaction in the context of the Stern-Gerlach...experiment, and Rabi et al. [6] were the first to directly measure nuclear magnetic moments with this beam technique [7]. 1 quantum angular momentum or spin...interaction matrix can be separated into isotropic and anisotropic parts, A( 14N) → A  1 0 0 0 1 0 0 0 1 + P  -2 5 0 0 0 -2 5 0 0 0 4 5

  14. Hyperfine structure and isotope shift of the neutron-rich barium isotopes 139-146Ba and 148Ba

    International Nuclear Information System (INIS)

    Wendt, K.; Ahmad, S.A.; Klempt, W.; Neugart, R.; Otten, E.W.

    1988-01-01

    The hyperfine structure and isotope shift in the 6s 2 S 1/2 -6p 2 P 3/2 line of Ba II (455.4 nm) have been measured by collinear fast-beam laser spectroscopy for the neutron-rich isotopes 139-146 Ba and 148 Ba. Nuclear moments and mean square charge radii of these isotopes have been recalculated. The isotope shift of the isotope 148 Ba (T 1/2 = 0.64 s) could be studied for the first time, yielding δ 2 > 138,148 = 1.245(3) fm 2 . (orig.)

  15. Hyperfine Induced Transitions as Diagnostics of Low Density Plasmas and Isotopic Abundance ratios.

    Science.gov (United States)

    Brage, T.; Judge, P. G.; Aboussaid, A.; Godefroid, M. R.; Jonsson, P.; Leckrone, D. S.

    1996-05-01

    We propose a new diagnostics of isotope abundance ratios and electron densities for low density plasmas, in the form of J = 0 -> J(') = 0 radiative transitions. These are usually viewed as being allowed only through two-photon decay, but they may also be induced by the hyperfine (HPF) interaction in atomic ions. This predicts a companion line to the E1] and M2 lines in the UV0.01 multiplet of ions isoelectronic to beryllium (e.g. C III, N IV, O V and Fe XXII) or magnesium (e.g. Si II, Ca IX, Fe XV and Ni XVII). As an example the companion line to the well known lambda lambda 1906.7,1908.7 lines in C III will be at 1909.597 Angstroms, but only present in the (13) C isotope (which has nuclear spin different from zero). We present new and accurate decay rates for the nsnp (3P^oJ) -> ns(2) (1S_{J('}=0)) transitions in ions of the Be (n=2) and Mg (n=3) isoelectronic sequences. We show that the HPF induced decay rates for the J = 0 -> J(') = 0 transitions are many orders of magnitude larger than those for the competing two-photon processes and, when present, are typically one or two orders of magnitude smaller than the decay rates of the magnetic quadrupole ( J = 2-> J(') = 0) transitions for these ions. We show that several of these HPF-induced transitions are of potential astrophysical interest, in ions of C, N, Na, Mg, Al, Si, K, Cr, Fe and Ni. We highlight those cases that may be of particular diagnostic value for determining isotopic abundance ratios and/or electron densities from UV or EUV emission line data. We present our atomic data in the form of scaling laws so that, given the isotopic nuclear spin and magnetic moment, a simple expression yields estimates for HPF induced decay rates. We examine some UV solar and nebular data in the light of these new results and suggest possible cases for future study. We could not find evidence for the existence of HPF induced lines in the spectra we examined, but we demonstrate that existing data have come close to providing

  16. Experimental and ab initio study of the hyperfine parameters of ZnFe {sub 2}O{sub 4} with defects

    Energy Technology Data Exchange (ETDEWEB)

    Quintero, J. Melo; Salcedo Rodríguez, K. L.; Pasquevich, G. A.; Zélis, P. Mendoza; Stewart, S. J., E-mail: stewart@fisica.unlp.edu.ar; Rodríguez Torres, C. E.; Errico, L. A. [Universidad Nacional de La Plata, IFLP-CCT- La Plata-CONICET and Departamento de Física, Facultad de Ciencias Exactas, C. C. 67 (Argentina)

    2016-12-15

    We present a combined Mössbauer and ab initio study on the influence of oxygen-vacancies on the hyperfine and magnetic properties of the ZnFe {sub 2}O{sub 4} spinel ferrite. Samples with different degree of oxygen-vacancies were obtained from zinc ferrite powder that was thermally treated at different temperatures up to 650 {sup ∘}C under vacuum.Theoretical calculations of the hyperfine parameters, magnetic moments and magnetic alignment have been carried out considering different defects such as oxygen vacancies and cation inversion. We show how theoretical and experimental approaches are complementary to characterize the local structure around Fe atoms and interpret the observed changes in the hyperfine parameters as the level of defects increases.

  17. Time-resolved quantitative phosphoproteomics

    DEFF Research Database (Denmark)

    Verano-Braga, Thiago; Schwämmle, Veit; Sylvester, Marc

    2012-01-01

    proteins involved in the Ang-(1-7) signaling, we performed a mass spectrometry-based time-resolved quantitative phosphoproteome study of human aortic endothelial cells (HAEC) treated with Ang-(1-7). We identified 1288 unique phosphosites on 699 different proteins with 99% certainty of correct peptide...

  18. Time-resolved vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Tokmakoff, Andrei [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Champion, Paul [Northeastern Univ., Boston, MA (United States); Heilweil, Edwin J. [National Inst. of Standards and Technology (NIST), Boulder, CO (United States); Nelson, Keith A. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Ziegler, Larry [Boston Univ., MA (United States)

    2009-05-14

    This document contains the Proceedings from the 14th International Conference on Time-Resolved Vibrational Spectroscopy, which was held in Meredith, NH from May 9-14, 2009. The study of molecular dynamics in chemical reaction and biological processes using time-resolved spectroscopy plays an important role in our understanding of energy conversion, storage, and utilization problems. Fundamental studies of chemical reactivity, molecular rearrangements, and charge transport are broadly supported by the DOE's Office of Science because of their role in the development of alternative energy sources, the understanding of biological energy conversion processes, the efficient utilization of existing energy resources, and the mitigation of reactive intermediates in radiation chemistry. In addition, time-resolved spectroscopy is central to all fiveof DOE's grand challenges for fundamental energy science. The Time-Resolved Vibrational Spectroscopy conference is organized biennially to bring the leaders in this field from around the globe together with young scientists to discuss the most recent scientific and technological advances. The latest technology in ultrafast infrared, Raman, and terahertz spectroscopy and the scientific advances that these methods enable were covered. Particular emphasis was placed on new experimental methods used to probe molecular dynamics in liquids, solids, interfaces, nanostructured materials, and biomolecules.

  19. Resolving Ethical Issues at School

    Science.gov (United States)

    Benninga, Jacques S.

    2013-01-01

    Although ethical dilemmas are a constant in teachers' lives, the profession has offered little in the way of training to help teachers address such issues. This paper presents a framework, based on developmental theory, for resolving professional ethical dilemmas. The Four-Component Model of Moral Maturity, when used in conjunction with a…

  20. Hyperbolic partial differential equations

    CERN Document Server

    Witten, Matthew

    1986-01-01

    Hyperbolic Partial Differential Equations III is a refereed journal issue that explores the applications, theory, and/or applied methods related to hyperbolic partial differential equations, or problems arising out of hyperbolic partial differential equations, in any area of research. This journal issue is interested in all types of articles in terms of review, mini-monograph, standard study, or short communication. Some studies presented in this journal include discretization of ideal fluid dynamics in the Eulerian representation; a Riemann problem in gas dynamics with bifurcation; periodic M

  1. Successful removable partial dentures.

    Science.gov (United States)

    Lynch, Christopher D

    2012-03-01

    Removable partial dentures (RPDs) remain a mainstay of prosthodontic care for partially dentate patients. Appropriately designed, they can restore masticatory efficiency, improve aesthetics and speech, and help secure overall oral health. However, challenges remain in providing such treatments, including maintaining adequate plaque control, achieving adequate retention, and facilitating patient tolerance. The aim of this paper is to review the successful provision of RPDs. Removable partial dentures are a successful form of treatment for replacing missing teeth, and can be successfully provided with appropriate design and fabrication concepts in mind.

  2. Beginning partial differential equations

    CERN Document Server

    O'Neil, Peter V

    2011-01-01

    A rigorous, yet accessible, introduction to partial differential equations-updated in a valuable new edition Beginning Partial Differential Equations, Second Edition provides a comprehensive introduction to partial differential equations (PDEs) with a special focus on the significance of characteristics, solutions by Fourier series, integrals and transforms, properties and physical interpretations of solutions, and a transition to the modern function space approach to PDEs. With its breadth of coverage, this new edition continues to present a broad introduction to the field, while also addres

  3. Investigation of hyperfine interactions in pure silicon and NTD silicon by means of perturbed angular γ-γ correlation spectroscopy

    International Nuclear Information System (INIS)

    Cordeiro, Moacir Ribeiro

    2007-01-01

    III the present work, a microscopic investigation of hyperfine interactions in single crystal silicon samples was carried out by means of Perturbed Angular γ -γ correlation technique (PAC), which is based in hyperfine interactions. In order to achieve these measurements, it was used 111 In → 111 Cd radioactive probe nuclei, which decay through the well known γ cascade 171-245 keV with an intermediate level of 245 keV ( I 5 + /2, Q = 0.83b, T 1/2 = 84.5 ns). The samples were prepared using different probe nuclei insertion methods, making possible to increase our understanding on the impact generated by each of these techniques in PAC measurements. Ion implantation, diffusion and evaporation were carefully investigated giving emphasis on its characteristics and particularities. Then, it was made a study about the concentration of intrinsic defects as function of severe annealing processes. Finally, a comparative analysis was made for all these probe nuclei insertion methods. This work also accomplished PAC measurements in single crystal silicon doped with phosphorus by means of Neutron Transmutation Doping (NTD) method, carried out in a research nuclear reactor. The extremely high doping uniformity allied to the nonexistence of previous measurements in these materials emphasize the importance of the results obtained. These results are then compared with literature results for samples doped by conventional methods presenting the respective conclusions. (author)

  4. Hyperfine interactions in dilute Se doped Fe{sub x}Sb{sub 1−x} bulk alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sarkar, Mitesh, E-mail: miteshsarkar-msu@yahoo.com; Agrawal, Naveen [The M. S. University of Baroda, Department of Physics (India); Chawda, Mukesh [Polytechnic, The M. S. University of Baroda, Department of Applied Physics (India)

    2016-12-15

    Hyperfine Interaction technique like Moessbauer spectroscopy is a very sensitive tool to study the local probe interactions in Iron doped alloys and compounds. We report here the Moessbauer study of the effect of Fe concentration variations in dilute magnetic semiconducting Se{sub 0.004}Fe{sub x}Sb{sub 1−x} alloys for x = 0.002, 0.004 and 0.008. The materials were characterized using X-ray diffraction technique (XRD), Fourier Transform Infra-red spectroscopy (FTIR), Neutron depolarization and Moessbauer spectroscopy. The FTIR result shows the semiconducting behavior of the alloys with band gap of 0.18 eV. From Moessbauer spectroscopy two magnetic sites (A and B) were observed. The value of hyperfine magnetic fields (HMF) of ∼ 308 kOe (site A) and 270 kOe (site B) was constant with increase in Fe concentration. A nonmagnetic interaction was also observed with quadrupole splitting (QS) of 1.26 mm/sec (site C) for x = 0.004 and x = 0.008. The Neutron depolarization studies indicate that the clusters of Fe or Fe based compounds having net magnetic moments with a size greater than 100 Å is absent.

  5. Interaction potential of the H-He system and the hyperfine frequency shift of H in He buffer gas

    International Nuclear Information System (INIS)

    Tang, K.T.; Yang, X.D.

    1990-01-01

    The van der Waals potential of the H-He interaction and the hyperfine frequency shift of H in He are predicted using the Tang-Toennies model. This model damps the long-range ab initio dispersion terms individually using a universal damping function and adds to this a simple Born-Mayer repulsive term. The Born-Mayer parameters are derived from self-consistent-field calculations. The resulting potential is found to be in good agreement with two molecular-beam experiments and its well parameters, in excellent agreement with the complete configuration-interaction calculation. In order to compare with experiment, the hyperfine frequency shift is thermally averaged over the potential both quantum mechanically and classically. The thermally averaged results are in excellent agreement with experiment in the high-temperature range but there are some discrepancies with the measurements at 0.5 and at 1.15 K. These discrepancies may be due to the fact that the long-range coefficient K 10 used is too small. The quantum and classical results are practically identical for temperature above 40 K. The classical statistics fails completely only for temperature below 5 K. Also in the quantum calculation, the isotope effect between 3 He and 4 He is found to show up only for temperature below 10 K. The theoretical isotope effect is in qualitative agreement with experiment

  6. Temperature dependence of the magnetic hyperfine field at an s–p impurity diluted in RNi_2

    International Nuclear Information System (INIS)

    Oliveira, A.L. de; Chaves, C.M.; Oliveira, N.A. de; Troper, A.

    2016-01-01

    We study the formation of local magnetic moments and magnetic hyperfine fields at an s–p impurity diluted in intermetallic Laves phase compounds RNi_2 (R=Nd, Sm, Gd, Tb, Dy) at finite temperatures. We start with a clean host and later the impurity is introduced. The host has two-coupled (R and Ni) sublattice Hubbard Hamiltonians but the Ni sublattice can be disregarded because its d band, being full, is magnetically ineffective. Also, the effect of the 4f electrons of R is represented by the polarization they produce on the d band. This leaves us with a lattice of effective rare earth R-ions with polarized electrons. For the dd electronic interaction we use the Hubbard–Stratonovich identity in a functional integral approach in the static saddle point approximation. - Highlights: • Functional integral method in the static limit, producing site disorder, is used. • The site disorder is treated with the Coherent Potential Approximation (CPA). • Non magnetic Ni generates an effective lattice with only a polarized R d band. • The effective R lattice differ from the pure R metal: Results and Discussions. • The experimental curve of hyperfine fields × temperature are very well reproduced.

  7. Hyperfine magnetic fields for 5d impurities in iron: pre-equilibrium effects, texture and the Aharoni effect

    International Nuclear Information System (INIS)

    Stuchbery, A.E.; Bezakova, E.

    1998-01-01

    Static magnetic hyperfine fields acting on impurities recoil-implanted into ferromagnetic hosts following heavy-ion induced reactions have been studied using the implantation perturbed angular correlation (IMPAC) technique to determine the magnetic moments of subnanosecond excited states in neutron-deficient nuclei. Problems, which in time-integral measurements cannot always be treated independently were studied and include: (i) corrections for the transient field effect, (ii) whether the hyperfine field is parallel to the applied field, (iii) whether the implanted nuclei all experience the same magnetic interaction, (iv) the time the static field takes to reach equilibrium after implantation. The focus here is on pre-equilibrium phenomena associated with the implantation process and the direction of the internal magnetic field at implanted impurities after equilibrium is reached. It was found that the internal field does become increasingly misaligned with respect to external field direction at fields below 0.08 T. This is due to the incomplete saturation of the foil and not to the microscopic effect as proposed by Aharoni

  8. Temperature dependence of the magnetic hyperfine field at an s–p impurity diluted in RNi{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, A.L. de, E-mail: alexandre.oliveira@ifrj.edu.br [Instituto Federal de Educação, Ciência e Tecnologia do Rio de Janeiro, Campus Nilópolis, RJ (Brazil); Chaves, C.M., E-mail: cmch@cbpf.br [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ (Brazil); Oliveira, N.A. de [Instituto de Física Armando Dias Tavares, Universidade do Estado do Rio de Janeiro, Rio de Janeiro (Brazil); Troper, A. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ (Brazil)

    2016-03-01

    We study the formation of local magnetic moments and magnetic hyperfine fields at an s–p impurity diluted in intermetallic Laves phase compounds RNi{sub 2} (R=Nd, Sm, Gd, Tb, Dy) at finite temperatures. We start with a clean host and later the impurity is introduced. The host has two-coupled (R and Ni) sublattice Hubbard Hamiltonians but the Ni sublattice can be disregarded because its d band, being full, is magnetically ineffective. Also, the effect of the 4f electrons of R is represented by the polarization they produce on the d band. This leaves us with a lattice of effective rare earth R-ions with polarized electrons. For the dd electronic interaction we use the Hubbard–Stratonovich identity in a functional integral approach in the static saddle point approximation. - Highlights: • Functional integral method in the static limit, producing site disorder, is used. • The site disorder is treated with the Coherent Potential Approximation (CPA). • Non magnetic Ni generates an effective lattice with only a polarized R d band. • The effective R lattice differ from the pure R metal: Results and Discussions. • The experimental curve of hyperfine fields × temperature are very well reproduced.

  9. High precision measurement of the hyperfine fields of substitutional and defect associated Cd in single crystalline hcp cobalt

    CERN Document Server

    Correia, J G; Melo, A A; Soares, J C

    1996-01-01

    The hyperfine fields of Cd in single crystalline hcp Co were measured after simultaneous implantation of 111mCd and 111In. High statistics measurements could be done separately for each parent isotope combining the e--g and g-g PAC techniques. The hyperfine coupling constants wL(CdCo)=422.8(1) Mrad/s and w0(CdCo)=6.14(11) Mrad/s are determined for Cd probes in undisturbed substitutional sites. Several defect associated sites in the hcp Co lattice are clearly seen in the data. Most of the radiation damage created by the ion implantation anneals out at temperatures below 503 K, with only one dominating component surviving at this temperature. This defect is assigned as a probe atom in an interstitial site, surrounded by a vacancy tetrahedron. The corresponding magnetic field and electric field gradient are collinear with the c-axis of the Co lattice, and the respective coupling constants are wL(defect)= 216.7(2) Mrad/s and w0(defect)= 45.3(6) Mrad/s.

  10. On the origin of discontinuity of the hyperfine fields at {sup 57}Fe nuclei in bulk iron and aerosol Fe nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Petrov, Yu.I. [Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygin str. 4, 119991, GSP-1, Moscow (Russian Federation); Shafranovsky, E.A., E-mail: shafr@chph.ras.r [Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygin str. 4, 119991, GSP-1, Moscow (Russian Federation); Casas, Ll. [Departament de Geologia, Universitat Autonoma de Barcelona, Edifici C, Campus de la UAB, 08193 Bellaterra (Spain); Molins, E. [Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra (Spain)

    2011-03-14

    Advancing the early work in which a discontinuity of hyperfine fields at {sup 57}Fe nuclei in bulk iron and in aerosol Fe nanoparticles has been revealed by analyzing their Moessbauer spectra the present Letter evidences that the existence of several peaks in the hyperfine distribution (HFD) for bulk Fe is caused with the internal magnetic fields owing to its multidomain structure whereas aerosol Fe nanoparticles are single-domain and show only a unique peak in HFD. This argument has been corroborated by transformation of the HFD pattern for Fe foil after applying the external magnetic field of 0.03 T.

  11. Partial knee replacement - slideshow

    Science.gov (United States)

    ... page: //medlineplus.gov/ency/presentations/100225.htm Partial knee replacement - series—Normal anatomy To use the sharing ... A.M. Editorial team. Related MedlinePlus Health Topics Knee Replacement A.D.A.M., Inc. is accredited ...

  12. Matrix elements of hyperfine structure operators in the SL and jj representations for the s, pN, and dN configurations and the SL-jj transformation

    International Nuclear Information System (INIS)

    Childs, W.J.

    1997-01-01

    Matrix elements of the hyperfine operators corresponding to the magnetic-dipole (A) and electric-quadrupole (B) hyperfine structures constants are given as linear combinations of the appropriate radial integrals for all states of the s, p N , and d N configurations in both the SL and pure jj representations. The associated SL-jj transformations are also given. 13 refs., 10 tabs

  13. Beginning partial differential equations

    CERN Document Server

    O'Neil, Peter V

    2014-01-01

    A broad introduction to PDEs with an emphasis on specialized topics and applications occurring in a variety of fields Featuring a thoroughly revised presentation of topics, Beginning Partial Differential Equations, Third Edition provides a challenging, yet accessible,combination of techniques, applications, and introductory theory on the subjectof partial differential equations. The new edition offers nonstandard coverageon material including Burger's equation, the telegraph equation, damped wavemotion, and the use of characteristics to solve nonhomogeneous problems. The Third Edition is or

  14. High-precision QED calculations of the hyperfine structure in hydrogen and transition rates in multicharged ions

    International Nuclear Information System (INIS)

    Volotka, A.V.

    2006-01-01

    Studies of the hyperfine splitting in hydrogen are strongly motivated by the level of accuracy achieved in recent atomic physics experiments, which yield finally model-independent informations about nuclear structure parameters with utmost precision. Considering the current status of the determination of corrections to the hyperfine splitting of the ground state in hydrogen, this thesis provides further improved calculations by taking into account the most recent value for the proton charge radius. Comparing theoretical and experimental data of the hyperfine splitting in hydrogen the proton-size contribution is extracted and a relativistic formula for this contribution is derived in terms of moments of the nuclear charge and magnetization distributions. An iterative scheme for the determination of the Zemach and magnetic radii of the proton is proposed. As a result, the Zemach and magnetic radii are determined and the values are compared with the corresponding ones deduced from data obtained in electron-proton scattering experiments. The extraction of the Zemach radius from a rescaled difference between the hyperfine splitting in hydrogen and in muonium is considered as well. Investigations of forbidden radiative transitions in few-electron ions within ab initio QED provide a most sensitive tool for probing the influence of relativistic electron-correlation and QED corrections to the transition rates. Accordingly, a major part of this thesis is devoted to detailed studies of radiative and interelectronic-interaction effects to the transition probabilities. The renormalized expressions for the corresponding corrections in one- and twoelectron ions as well as for ions with one electron over closed shells are derived employing the two-time Green's function method. Numerical results for the correlation corrections to magnetic transition rates in He-like ions are presented. For the first time also the frequency-dependent contribution is calculated, which has to be

  15. High-precision QED calculations of the hyperfine structure in hydrogen and transition rates in multicharged ions

    Energy Technology Data Exchange (ETDEWEB)

    Volotka, A.V.

    2006-07-01

    Studies of the hyperfine splitting in hydrogen are strongly motivated by the level of accuracy achieved in recent atomic physics experiments, which yield finally model-independent informations about nuclear structure parameters with utmost precision. Considering the current status of the determination of corrections to the hyperfine splitting of the ground state in hydrogen, this thesis provides further improved calculations by taking into account the most recent value for the proton charge radius. Comparing theoretical and experimental data of the hyperfine splitting in hydrogen the proton-size contribution is extracted and a relativistic formula for this contribution is derived in terms of moments of the nuclear charge and magnetization distributions. An iterative scheme for the determination of the Zemach and magnetic radii of the proton is proposed. As a result, the Zemach and magnetic radii are determined and the values are compared with the corresponding ones deduced from data obtained in electron-proton scattering experiments. The extraction of the Zemach radius from a rescaled difference between the hyperfine splitting in hydrogen and in muonium is considered as well. Investigations of forbidden radiative transitions in few-electron ions within ab initio QED provide a most sensitive tool for probing the influence of relativistic electron-correlation and QED corrections to the transition rates. Accordingly, a major part of this thesis is devoted to detailed studies of radiative and interelectronic-interaction effects to the transition probabilities. The renormalized expressions for the corresponding corrections in one- and twoelectron ions as well as for ions with one electron over closed shells are derived employing the two-time Green's function method. Numerical results for the correlation corrections to magnetic transition rates in He-like ions are presented. For the first time also the frequency-dependent contribution is calculated, which has to be

  16. Minimum resolvable power contrast model

    Science.gov (United States)

    Qian, Shuai; Wang, Xia; Zhou, Jingjing

    2018-01-01

    Signal-to-noise ratio and MTF are important indexs to evaluate the performance of optical systems. However,whether they are used alone or joint assessment cannot intuitively describe the overall performance of the system. Therefore, an index is proposed to reflect the comprehensive system performance-Minimum Resolvable Radiation Performance Contrast (MRP) model. MRP is an evaluation model without human eyes. It starts from the radiance of the target and the background, transforms the target and background into the equivalent strips,and considers attenuation of the atmosphere, the optical imaging system, and the detector. Combining with the signal-to-noise ratio and the MTF, the Minimum Resolvable Radiation Performance Contrast is obtained. Finally the detection probability model of MRP is given.

  17. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1994-03-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October - December 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  18. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1992-11-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (July - September 1992) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  19. Hyperfine characterization of the Ba Ti{sub 1-x} Hf{sub x} O{sub 3} for x = 0.20; Caracterizacion hiperfina de Ba Ti{sub 1-x} Hf{sub x} O{sub 3} para x 0.20

    Energy Technology Data Exchange (ETDEWEB)

    Ayala, Alexandro; Lopez-Garcia, Alberto [La Plata Univ. Nacional (Argentina). Dept. de Fisica

    1997-12-31

    It is known that the cation substitution in perovskites produce changes in the macroscopic properties of these materials. A case to study is for example the influence of cation B partially substituted by cation B{sup `} when ABO{sub 3} is ferroelectric, and A B{sup `}O{sub 3} is paraelectric. In this work the system Ba Ti{sub 1-x} Hf{sub x} O{sub 3} with x = 0.05, 0.10, 0.15 and 0.20 is studied by Perturbed Angular Correlations (Pac) in order to obtain microscopic information through the electric field gradient tensor (EFG) produced by electrons close to probes. Two hyperfine quadrupole interactions were detected. One interaction associated to probes with defects originated during the nuclear processes after neutron irradiation, and the other are located in B sites. At R T, the hyperfine parameters are analyzed in terms of Hf concentration. (author). 5 refs., 2 figs., 2 tabs.

  20. Hyperfine interactions studies in perovskite oxides of the type LaMO3 (M = Fe, Cr, Mn and Co)

    International Nuclear Information System (INIS)

    Junqueira, Astrogildo de Carvalho

    2004-01-01

    ABO 3 -type perovskite oxides have ideal cubic structure and usually show distortions to the orthorhombic or rombohedric symmetry. The A and B siteshave 12-fold and 6-fold oxygen coordination, respectively. Distortions of thecubic structure give rise to new electric, structural and magnetic propertieswhich have great technological and scientific interests. Magnetic dipole and electric quadrupole hyperfine interaction measurements were obtained using 111 In -> 111 Cd , 181 Hf -> 181 Ta e 140 La -> 140 Ceradioactive nuclei substituting for the A or B sites via Perturbed Angulargamma-gamma Correlation technique (1-4) . LaMO 3 (M = Fe, Cr, Mn and Co)samples were prepared through the chemical route known as Sol-Gel techniqueand analyzed with x-ray diffraction. Both 111 In and 181 Hf nuclei wereintroduced in to the sample during the chemical procedure and the 140 Lawas obtained by irradiating with neutrons in the IPEN reactor the natural Lapresent in the samples. One of the aims of this work was the analysis of theElectric Field Gradient (EFG) in the A and B sites as function oftemperature, crystal structure or the electronic characteristic of thetransition metal in the B site. The temperature range of the measurements wasabout from 4 K to 1400 K. The experimental EFG showed to be dependent of thesite occupation and the nuclear probe used in the measurements. Spintransition phenomena were also observed in LaCoO 3 samples, which confirmed amodel used to interpret the spin properties in such compound.Crystallographic phase transition effects on the hyperfine parameters inperovskites where M = Fe, Cr and K4n were also analyzed. An additional aim ofthis work was to carry out measurements in the antiferromagnetic region ofthe systems with M = Fe, Cr and Mn using the three radioactive nuclei. Theresults for the magnetic interaction measurements showed a strong influenceof the substitutional sites in the supertransferred magnetic hyperfine fieldfor all the three probe nuclei

  1. Partial differential equations

    CERN Document Server

    Evans, Lawrence C

    2010-01-01

    This text gives a comprehensive survey of modern techniques in the theoretical study of partial differential equations (PDEs) with particular emphasis on nonlinear equations. The exposition is divided into three parts: representation formulas for solutions; theory for linear partial differential equations; and theory for nonlinear partial differential equations. Included are complete treatments of the method of characteristics; energy methods within Sobolev spaces; regularity for second-order elliptic, parabolic, and hyperbolic equations; maximum principles; the multidimensional calculus of variations; viscosity solutions of Hamilton-Jacobi equations; shock waves and entropy criteria for conservation laws; and, much more.The author summarizes the relevant mathematics required to understand current research in PDEs, especially nonlinear PDEs. While he has reworked and simplified much of the classical theory (particularly the method of characteristics), he primarily emphasizes the modern interplay between funct...

  2. Transferred hyperfine interaction at 295 K between the rare-earth ions and the fluorine and lithium nuclei in lithium rare-earth fluorides

    DEFF Research Database (Denmark)

    Hansen, P. E.; Nevald, Rolf

    1977-01-01

    The nuclear-magnetic-resonance rotation spectra for the fluorine and lithium nuclei in LiTbF4, LiDyF4, LiHoF4, and LiErF4 have been obtained at 295 K. They are separated in contributions from the dipole and the transferred hyperfine interactions. In general, the latter consists of an isotropic part...

  3. Proceedings of the International Workshop on Nanomaterials, Magnetic Ions and Magnetic Semiconductors Studied Mostly by Hyperfine Interactions (IWNMS 2004) held in Baroda, India, 10–14 February 2004

    CERN Document Server

    Somayajulu, D. R. S; IWNMS 2004

    2005-01-01

    Proceedings of the Baroda Workshop IWNMS 2004, held in Baroda, India, 10-14 February, 2004 Researchers and graduate students interested in the Mössbauer Effect and its applications will find this volume indispensable. The volume presents the most recent developments in the methodology of Mössbauer spectroscopy. Reprinted from Hyperfine Interactions (HYPE) Volume 160, 1-4

  4. Study of the hyperfine magnetic field at Ta181 site in the Heusler Co2 Sc Sn, Co2 Sc Ga and Co2 Hf Sn alloys

    International Nuclear Information System (INIS)

    Attili, R.N.

    1992-01-01

    The hyperfine magnetic fields acting on 181 Ta nuclei at the Sc and Hf sites have been measured in Heusler alloys Co 2 Sc Sn and Co 2 Sc Ga and Co 2 Hf Sn using the Time Differential Perturbed γ-γ Angular Correlation (TDPAC) technique. The measurements were carried out using an automatic spectrometer consisting of two Ba F 2 detectors and the conventional electronics. The magnitude of hyperfine magnetic field at 181 Ta was measured for all the alloys. The signs of the were determined in the cases of Co 2 Sc Sn and Co 2 Hf Sn alloys by performing the Perturbed Angular Correlation measurements with an external polarizing magnetic field of ≅ 5 k Gauss. The hyperfine magnetic fields obtained are -187,6± 3,3 and 90,0 ± 2,1 kOe measured at 77 K for Co 2 Sc Sn and Co 2 Sc Ga alloys respectively, and -342,4 ± 10,1 kOe measured at the room temperature for Co 2 Hf Sn alloy. These results are discussed and compared with the hyperfine magnetic field systematics in Co-based Heusler alloy. (author)

  5. Electronic structure optical spectra and contact hyperfine parameters of CoF64- complex in LiF and KMgF3

    International Nuclear Information System (INIS)

    Albuquerque, E.L. de.

    1975-12-01

    The electronic structure, the optical absorption bands and the magnetic hyperfine contact terms have been calculated for CoF 6 4- cluster in LiF and KMgF 3 using the Self-Consistent-Field Multiple-Scattering Xα Method. The results obtained are compared with experiment and indicate that this scheme is convenient to treat such complex problems. (Author) [pt

  6. Hyperfine structure and isotope shift of transitions in YbI using UV and deep-UV cw laser light and the angular distribution of fluorescence radiation

    NARCIS (Netherlands)

    Zinkstok, R.T.; van Duijn, E.J.; Witte, S.; Hogervorst, W.

    2002-01-01

    Using the third harmonic of a cw titanium:sapphire laser, the hyperfine structure (HFS) and isotope shift (IS) of three deep-UV transitions of neutral Yb have been measured for the first time. By exploiting the angular distribution of fluorescence radiation, accurate and complete results are

  7. Optimization of partial search

    International Nuclear Information System (INIS)

    Korepin, Vladimir E

    2005-01-01

    A quantum Grover search algorithm can find a target item in a database faster than any classical algorithm. One can trade accuracy for speed and find a part of the database (a block) containing the target item even faster; this is partial search. A partial search algorithm was recently suggested by Grover and Radhakrishnan. Here we optimize it. Efficiency of the search algorithm is measured by the number of queries to the oracle. The author suggests a new version of the Grover-Radhakrishnan algorithm which uses a minimal number of such queries. The algorithm can run on the same hardware that is used for the usual Grover algorithm. (letter to the editor)

  8. Hyperfine Structure of Spectral Lines of 143Nd+, 145Nd+, 139La+, 141Pr+ and 137Ba+ Investigated by Collinear Laser Ion Beam Spectroscopy

    International Nuclear Information System (INIS)

    Anjum, N.

    2012-01-01

    In this research work the hyperfine structures of spectral lines of barium (Ba) and three lanthanides elements; praseodymium (Pr), lanthanum (La) and neodymium (Nd) have been investigated. The hyperfine splitting factors A and B of the involved levels have been determined with high accuracy and the data are compared with other published results. This research work is divided in four parts. In the 1st part, the hyperfine structures of the spectral lines of the singly ionized praseodymium (Pr II) are investigated by three different laser spectroscopic techniques; laser induced fluorescence (LIF) spectroscopy, inter-modulated saturation spectroscopy and collinear laser ion beam spectroscopy (CLIBS). The 2nd part is concerned with the a control-check of the Marburg mass separator (MARS-II), as it was shifted from the University of Marburg, Germany, to Graz University of Technology in 2002. The check is performed using a well known spectral line 5853.67 Å of the odd isotope of singly ionized barium (137Ba II). In the 3rd part of this work the hyperfine structure of spectral lines of lanthanum-139 ions (139La II) is investigated. The 4th part is devoted to the investigation of the hyperfine structure of spectral lines of two odd isotopes of singly ionized neodymium (143Nd II and 145Nd II) and the determination of the coupling constants A and B of the involved levels. To determine the hyperfine anomaly the ratios of the magnetic dipole constants, i.e A143/A145, and the electric quadrupole constants B143/B145 of the corresponding levels are also calculated. The last three parts of this research project are executed using the high resolution, Doppler reduced method of CLIBS. In CLIBS technique the ions are accelerated by applying a high potential difference (∼ 20 kV). Due to the accelerating cooling (kinematic compression) the spread in velocities in the direction of the flight is reduced several times, hence the Doppler width is reduced. The accelerated ion beam is mass

  9. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1993-09-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  10. Mediation for resolving family disputes

    Directory of Open Access Journals (Sweden)

    Kamenecka-Usova M.

    2016-01-01

    Full Text Available Nowadays the understanding of the institute of marriage and its importance in the society has changed. Marriage is no longer assumed to be a commitment for a lifetime. As the principle of equality has replaced hierarchy as the guiding principle of family law it gave more grounds for family disputes and it became socially acceptable to leave marriages that are intolerable or merely unfulfilling. The aim of this article is to suggest an alternative dispute resolution method-mediation as a worthy option for resolving family conflicts.

  11. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1991-05-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1991) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  12. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1991-02-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October--December 1990) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  13. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1990-03-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October--December 1989) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  14. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1990-11-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (July--September 1990) and includes copies of letters, notices, and orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  15. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1992-08-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1992) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  16. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1990-09-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1990) and includes copies of letters, notices, and orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  17. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1993-06-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  18. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1992-05-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1992) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  19. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1993-12-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (July--September 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  20. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1993-03-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October--December 1992) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  1. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1991-07-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April-June 1991) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  2. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1991-11-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (July--September 1991) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  3. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1992-03-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October--December 1991) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  4. Enforcement actions: Significant actions resolved

    International Nuclear Information System (INIS)

    1989-12-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (July--September 1989) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication

  5. Magnetic field dependent 13C and 1H CIDNP from biradicals. The role of the hyperfine coupling constant

    International Nuclear Information System (INIS)

    Kanter, F.J.J. de; Sagdeev, R.Z.

    1978-01-01

    Magnetic field dependent biradical CIDNP has been observed in the natural abundance 13 C and 1 H NMR spectra taken immediately after irradiation of cyclic ketones in an auxillary magnet. The 13 C field dependence curves differ from the corresponding 1 H curves: The maxima of the curves for the C 11 and C 12 biradicals appear at a higher magnetic field strength, and the 13 C curves are broader than the 1 H curves. These differences are due to the different magnitudes of the hyperfine coupling constants for 13 C and 1 H and can be accounted for by a model based on a stochastic Liouville method which incorporates the dynamics of the biradicals. (Auth.)

  6. Quarkonium fine-hyperfine splittings and the Lorentz structure of the confining potential with vacuum-polarization corrections

    International Nuclear Information System (INIS)

    Barik, N.; Jena, S.N.

    1980-01-01

    Within the framework of the Poggio-Schnitzer flavor-independent static-potential model with long-distance vacuum-polarization correction, we analyze the Lorentz-Dirac structure of the confinement potential with reference to the charmonium hyperfine splittings. In view of the questionable existence and/or doubtful identity of the X(2830) and chi(3455) states, we give preference to the Lorentz-Dirac character of the confinement potential in the form of an approximately equal admixture of scalar and vector components with no anomalous moment. This in turn predicts the 1 S 0 partners of psi and psi' to be near the 3.0- and 3.6-GeV mass regions, respectively. This also suggests the 1 P 1 state of charmonium is to be found above the 3 P 0 state near the mass region of 3.48 GeV

  7. Measurement of the hyperfine structure of the 31D2, 41D2, 51D2 levels of helium 3

    International Nuclear Information System (INIS)

    Lemery, H.; Hamel, J.; Barrat, J.-P.

    1981-01-01

    It is well known that, in a discharge in 3 He, the nuclear spins in the ground state can be oriented through metastability exchange, by optical pumping of the metastable 2 3 S 1 atoms. The orientation is transmitted to the other levels excited in the discharge. If the nuclear spins in the ground state are submitted to magnetic resonance, the light emitted from these excited states is modulated at the R.F. field frequency. The degree of modulation is important only near a level crossing, in zero field or in non-zero field. This method has been used to determine the hyperfine structure of the 3 1 D 2 , 4 1 D 2 , 5 1 D 2 levels. The results are in good agreement with those of previous measurements and with theoretical predictions [fr

  8. Calculation of the electronic structure optical transitions and contact hyperfine parameters of interstitial hydrogen in alkaline halogen crystals

    International Nuclear Information System (INIS)

    Maciel, A.K.A.

    1977-03-01

    The electronic structure of the interstitial hydrogen atom in KF, NaCl, KCl, and RbCl cristals has been studied using the self-consistent-field multiple-scattering Xα method. In the present calculation a cluster constituted by the hydrogen atom surrounded by its first anion and cation neighbors in a cubic shell has been used. The optical transition energies and hyperfine contact parameters with the interstitial proton and the first shell nuclei have been evaluated. The agreement obtained with the experimental data and the relative independence of the method under variations of its intrinsic parameters, indicate that this method can be adequate to the study of defects in ionic cristals. (author) [pt

  9. Measured static hyperfine magnetic fields following implantation of Pt into Fe interpreted as evidence for pre-equilibrium effects

    International Nuclear Information System (INIS)

    Anderssen, S.S.; Stuchberry, A.E.

    1994-06-01

    The static hyperfine magnetic field present at Pt nuclei implanted in ferromagnetic Fe has been measured using the ion-implantation perturbed angular correlation (IMPAC) technique following Coulomb excitation. The present measured precessions agree with earlier data, but more recent information on the transient field correction leads to an inferred static field strength that is ∼ 25% smaller than obtained previously. Comparisons are made between the static fields measured by various techniques for Pt and neighbouring ions in iron. From these comparisons, it is show that the IMPAC data are consistent with a scenario in which (i) the static field takes about 10 ps to reach its equilibrium value, following recovery from dynamic structural damage caused by the ion-implantation process, and (ii) following equilibration, a large fraction (∼ 90%) of the implanted ions have final positions on lattice sites of the Fe host. 50 refs., 5 tabs., 7 figs

  10. Measured static hyperfine magnetic fields following implantation of Pt into Fe interpreted as evidence for pre-equilibrium effects

    Energy Technology Data Exchange (ETDEWEB)

    Anderssen, S S; Stuchberry, A E

    1994-06-01

    The static hyperfine magnetic field present at Pt nuclei implanted in ferromagnetic Fe has been measured using the ion-implantation perturbed angular correlation (IMPAC) technique following Coulomb excitation. The present measured precessions agree with earlier data, but more recent information on the transient field correction leads to an inferred static field strength that is {approx} 25% smaller than obtained previously. Comparisons are made between the static fields measured by various techniques for Pt and neighbouring ions in iron. From these comparisons, it is show that the IMPAC data are consistent with a scenario in which (i) the static field takes about 10 ps to reach its equilibrium value, following recovery from dynamic structural damage caused by the ion-implantation process, and (ii) following equilibration, a large fraction ({approx} 90%) of the implanted ions have final positions on lattice sites of the Fe host. 50 refs., 5 tabs., 7 figs.

  11. Hyperfine field calculations: search for muon stopping sites in Fe/sub 3/O/sub 4/

    Energy Technology Data Exchange (ETDEWEB)

    Boekema, C. (Texas Tech Univ., Lubbock (USA)); Denison, A.B. (Wyoming Univ., Laramie (USA)); Cooke, D.W.; Heffner, R.H.; Hutson, R.L.; Leon, M.; Schillaci, M.E. (Los Alamos National Lab., NM (USA))

    1983-12-01

    Muon Spin Rotation (..mu..SR) results for magnetite (Fe/sub 3/O/sub 4/) are analyzed and discussed. At room temperature, a ..mu..SR signal is observed due to the presence of an internal magnetic field (Bsub(int)) at the muon site. External transverse field measurements show that Bsub(int) is parallel to the magnetic spin direction, the <111> direction in zero applied field. Calculations of the hyperfine field to pinpoint muon stopping sites in magnetite show that the local field contains supertransfer (covalent) and dipolar field contributions. The implanted muons appear to stop at sites structurally similar to those reported for hematite (..cap alpha..-Fe/sub 2/O/sub 3/), where muon-oxygen bond formation was strongly indicated.

  12. Investigation of the hyperfine properties of deoxy hemoglobin based on its electronic structure obtained by Hartree-Fock-Roothan procedure

    Energy Technology Data Exchange (ETDEWEB)

    Lata, K. Ramani [State University of New York at Albany, Department of Physics (United States); Sahoo, N. [University of Texas M.D. Anderson Cancer Center, Department of Radiation Physics (United States); Dubey, Archana [University of Central Florida, Department of Physics (United States); Scheicher, R. H. [Uppsala University, Condensed Matter Theory Group, Department of Physics and Materials Science (Sweden); Badu, S. R.; Pink, R. H.; Mahato, Dip N. [State University of New York at Albany, Department of Physics (United States); Schulte, A. F.; Saha, H. P. [University of Central Florida, Department of Physics (United States); Maharjan, N. B. [State University of New York at Albany, Department of Physics (United States); Chow, Lee [University of Central Florida, Department of Physics (United States); Das, T. P., E-mail: tpd56@albany.edu [State University of New York at Albany, Department of Physics (United States)

    2008-01-15

    The electronic structure of the heme unit of deoxyhemoglobin including the proximal imidazole has been studied using the first-principles Hartree-Fock procedure. Our results for the {sup 57m}Fe isomer shift and asymmetry parameter are in very good agreement with the values obtained from Moessbauer spectroscopy measurements. The {sup 57m}Fe nuclear quadrupole coupling constant is smaller than the experimental result and possible ways to improve the agreement in the future are discussed. Improved analysis of the Moessbauer data, removing some approximations made for deriving the magnetic hyperfine tensor for the {sup 57m}Fe nucleus, is suggested to allow quantitative comparison with our results in the future.

  13. Investigation of hyperfine interactions in DNA and antibody of different lineages of mice infected by T. cruzi by perturbed gamma-gamma angular correlation spectroscopy

    International Nuclear Information System (INIS)

    Silva, Andreia dos Santos

    2012-01-01

    In the present work perturbed angular correlation (PAC) spectroscopy was used to measured electric quadrupole interactions in DNA biomolecules of different mice lineages (A/J, C57BL/6, B6AF1, BXA1 e BXA2), samples of different isotypes of immunoglobulin G (IgG1, IgG2a e IgG2b) and active portions of complete and fragmented immunoglobulin responsible by the immune response. Electric quadrupole interactions were also measured in DNA nitrogenous bases (adenine, cytosine, guanine, thymine). PAC measurements were performed using 111 In → 111C d; 111mC d → 111 Cd; 111 Ag → 111 Cd; e 181 Hf → 181 Ta as probe nuclei, and carried out at room temperature and liquid nitrogen temperature, in order to investigate dynamic and static hyperfine interactions, respectively. The biomolecule samples were directly marked with the radioactive parent nuclei, whose atom link to a certain site in the biomolecules. The biological materials as well as the probe nuclei were chosen to investigate the possibility to use PAC spectroscopy to measure hyperfine parameters at nuclei from metallic elements bound to biomolecules (including the use of different probe nuclei produced in the decay of parent nuclei of four different metals) and also to study the behavior of different biomolecules by means of the measured hyperfine parameters. Results show differences in the hyperfine interactions of probe nuclei bound to the studied biomolecules. Such differences were observed by variations in the hyperfine parameters, which depend on the type of biomolecule and the results also show that the probe nuclei atom bound to the molecule in some cases and in others do not. (author)

  14. Auxiliary partial liver transplantation

    NARCIS (Netherlands)

    C.B. Reuvers (Cornelis Bastiaan)

    1986-01-01

    textabstractIn this thesis studies on auxiliary partial liver transplantation in the dog and the pig are reported. The motive to perform this study was the fact that patients with acute hepatic failure or end-stage chronic liver disease are often considered to form too great a risk for successful

  15. Partial Remission Definition

    DEFF Research Database (Denmark)

    Andersen, Marie Louise Max; Hougaard, Philip; Pörksen, Sven

    2014-01-01

    OBJECTIVE: To validate the partial remission (PR) definition based on insulin dose-adjusted HbA1c (IDAA1c). SUBJECTS AND METHODS: The IDAA1c was developed using data in 251 children from the European Hvidoere cohort. For validation, 129 children from a Danish cohort were followed from the onset...

  16. Fundamental partial compositeness

    DEFF Research Database (Denmark)

    Sannino, Francesco; Strumia, Alessandro; Tesi, Andrea

    2016-01-01

    We construct renormalizable Standard Model extensions, valid up to the Planck scale, that give a composite Higgs from a new fundamental strong force acting on fermions and scalars. Yukawa interactions of these particles with Standard Model fermions realize the partial compositeness scenario. Unde...

  17. Partially ordered models

    NARCIS (Netherlands)

    Fernandez, R.; Deveaux, V.

    2010-01-01

    We provide a formal definition and study the basic properties of partially ordered chains (POC). These systems were proposed to model textures in image processing and to represent independence relations between random variables in statistics (in the later case they are known as Bayesian networks).

  18. Partially Hidden Markov Models

    DEFF Research Database (Denmark)

    Forchhammer, Søren Otto; Rissanen, Jorma

    1996-01-01

    Partially Hidden Markov Models (PHMM) are introduced. They differ from the ordinary HMM's in that both the transition probabilities of the hidden states and the output probabilities are conditioned on past observations. As an illustration they are applied to black and white image compression where...

  19. Honesty in partial logic

    NARCIS (Netherlands)

    W. van der Hoek (Wiebe); J.O.M. Jaspars; E. Thijsse

    1995-01-01

    textabstractWe propose an epistemic logic in which knowledge is fully introspective and implies truth, although truth need not imply epistemic possibility. The logic is presented in sequential format and is interpreted in a natural class of partial models, called balloon models. We examine the

  20. Excited-level lifetimes and hyperfine-structure measurements on ions using collinear laser--ion-beam spectroscopy

    International Nuclear Information System (INIS)

    Jin, J.; Church, D.A.

    1994-01-01

    The mean lifetimes τ of the Ca II 4p 2 P 1/2 and 4p 2 P 3/2 levels, and the 35 Cl II 4p' 1 F 3 level, have been measured by a variant of the collinear laser--ion-beam lifetime technique applied previously to the Ar II 4p' 2 F 7/2 o level [Jian Jin and D. A. Church, Phys. Rev. A 47, 132 (1993)]. The present results are τ(Ca II, 4p 2 P 1/2 )=7.098(0.020) ns, τ(Ca II, 4p 2 P 3/2 )=6.924(0.019) ns, and τ(Cl II, 4p' 1 F 3 ) =11.17(0.06) ns. The experimental lifetimes of these, plus the Ar II 4p' 2 F 7/2 level, are compared with available recent many-electron calculations. Typically 1%--3% differences between measurement and ab initio theory are found, while certain semiempirical calculations are in better agreement with experiment. Data for other precise lifetime measurements on alkali-metal systems are compared with recent ab initio and semiempirical calculations to provide perspective on the Ca II results. The hyperfine structure of the 35 Cl II 3d' 1 G 4 --4p' 1 F 3 transition was also measured and analyzed in the course of the measurements, with the resulting hyperfine-structure constants: A( 1 F 3 )=301.9(0.5) MHz, B( 1 F 3 )=-6.7(0.8) MHz, A( 1 G 4 )=205.1(0.5) MHz, and B( 1 G 4 )=-3.9(2.4) MHz

  1. Construction of a two-photon-laser spectrometer and determination of the hyperfine splitting and isotopic shift of barium

    International Nuclear Information System (INIS)

    Jitschin, W.

    1977-01-01

    A sensitive two-photon-laser spectrometer was constructed, that allowed to measure atomic states with an energy from 31 000 up to 37500 cm -1 with about 2 MHz resolution. The large energy range and the high resolution were reached by using a wide-wavelength tunable, narrow-band dye-laser. With this spectrometer transitions could be detected at barium from the electron ground-state 6s 2 1 S 0 to 10 upper states in the 5 most common isotopes 138 Ba, 137 Ba, 136 Ba, 135 Ba and 134 Ba. The transitions could be measured precisely. It was possible to derive lower limits of the life-time of these states from the widths of the recorded resonance lines (typically several nsec), that should in fact not be smaller than the actual lifetimes. From the measured hyper-fine splitting of the 6 transitions with angular momentum J = 2 at the oddnumbered isotopes 137 Ba and 135 Ba the parameters of the hyper-fine splitting could be determined. Hereby an accuracy of about IMH 2 could be reached at the A-factor and about 5MHz at the B-factor. At the measured transitions the isotopic shifts of the particular isotope could be determined with an accuracy of a few MHz. There was only a simple theory of the isotopic shift with only few parameters worked out for the theoretical interpretation of the measured data, that describes the data even at the experimentally reached high accuracy. Two parameters of this theory depending only from atomic nucleus properties, could be determined with a 0.5 % error. (orig./WB) [de

  2. Algebraic partial Boolean algebras

    International Nuclear Information System (INIS)

    Smith, Derek

    2003-01-01

    Partial Boolean algebras, first studied by Kochen and Specker in the 1960s, provide the structure for Bell-Kochen-Specker theorems which deny the existence of non-contextual hidden variable theories. In this paper, we study partial Boolean algebras which are 'algebraic' in the sense that their elements have coordinates in an algebraic number field. Several of these algebras have been discussed recently in a debate on the validity of Bell-Kochen-Specker theorems in the context of finite precision measurements. The main result of this paper is that every algebraic finitely-generated partial Boolean algebra B(T) is finite when the underlying space H is three-dimensional, answering a question of Kochen and showing that Conway and Kochen's infinite algebraic partial Boolean algebra has minimum dimension. This result contrasts the existence of an infinite (non-algebraic) B(T) generated by eight elements in an abstract orthomodular lattice of height 3. We then initiate a study of higher-dimensional algebraic partial Boolean algebras. First, we describe a restriction on the determinants of the elements of B(T) that are generated by a given set T. We then show that when the generating set T consists of the rays spanning the minimal vectors in a real irreducible root lattice, B(T) is infinite just if that root lattice has an A 5 sublattice. Finally, we characterize the rays of B(T) when T consists of the rays spanning the minimal vectors of the root lattice E 8

  3. Partially composite Higgs models

    DEFF Research Database (Denmark)

    Alanne, Tommi; Buarque Franzosi, Diogo; Frandsen, Mads T.

    2018-01-01

    We study the phenomenology of partially composite-Higgs models where electroweak symmetry breaking is dynamically induced, and the Higgs is a mixture of a composite and an elementary state. The models considered have explicit realizations in terms of gauge-Yukawa theories with new strongly...... interacting fermions coupled to elementary scalars and allow for a very SM-like Higgs state. We study constraints on their parameter spaces from vacuum stability and perturbativity as well as from LHC results and find that requiring vacuum stability up to the compositeness scale already imposes relevant...... constraints. A small part of parameter space around the classically conformal limit is stable up to the Planck scale. This is however already strongly disfavored by LHC results. in different limits, the models realize both (partially) composite-Higgs and (bosonic) technicolor models and a dynamical extension...

  4. Photogenic partial seizures.

    Science.gov (United States)

    Hennessy, M J; Binnie, C D

    2000-01-01

    To establish the incidence and symptoms of partial seizures in a cohort of patients investigated on account of known sensitivity to intermittent photic stimulation and/or precipitation of seizures by environmental visual stimuli such as television (TV) screens or computer monitors. We report 43 consecutive patients with epilepsy, who had exhibited a significant EEG photoparoxysmal response or who had seizures precipitated by environmental visual stimuli and underwent detailed assessment of their photosensitivity in the EEG laboratory, during which all were questioned concerning their ictal symptoms. All patients were considered on clinical grounds to have an idiopathic epilepsy syndrome. Twenty-eight (65%) patients reported visually precipitated attacks occurring initially with maintained consciousness, in some instances evolving to a period of confusion or to a secondarily generalized seizure. Visual symptoms were most commonly reported and included positive symptoms such as coloured circles or spots, but also blindness and subjective symptoms such as "eyes going funny." Other symptoms described included nonspecific cephalic sensations, deja-vu, auditory hallucinations, nausea, and vomiting. No patient reported any clear spontaneous partial seizures, and there were no grounds for supposing that any had partial epilepsy excepting the ictal phenomenology of some or all of the visually induced attacks. These findings provide clinical support for the physiological studies that indicate that the trigger mechanism for human photosensitivity involves binocularly innervated cells located in the visual cortex. Thus the visual cortex is the seat of the primary epileptogenic process, and the photically triggered discharges and seizures may be regarded as partial with secondary generalization.

  5. Arthroscopic partial medial meniscectomy

    Directory of Open Access Journals (Sweden)

    Dašić Žarko

    2011-01-01

    Full Text Available Background/Aim. Meniscal injuries are common in professional or recreational sports as well as in daily activities. If meniscal lesions lead to physical impairment they usually require surgical treatment. Arthroscopic treatment of meniscal injuries is one of the most often performed orthopedic operative procedures. Methods. The study analyzed the results of arthroscopic partial medial meniscectomy in 213 patients in a 24-month period, from 2006, to 2008. Results. In our series of arthroscopically treated medial meniscus tears we noted 78 (36.62% vertical complete bucket handle lesions, 19 (8.92% vertical incomplete lesions, 18 (8.45% longitudinal tears, 35 (16.43% oblique tears, 18 (8.45% complex degenerative lesions, 17 (7.98% radial lesions and 28 (13.14% horisontal lesions. Mean preoperative International Knee Documentation Committee (IKDC score was 49.81%, 1 month after the arthroscopic partial medial meniscectomy the mean IKDC score was 84.08%, and 6 months after mean IKDC score was 90.36%. Six months after the procedure 197 (92.49% of patients had good or excellent subjective postoperative clinical outcomes, while 14 (6.57% patients subjectively did not notice a significant improvement after the intervention, and 2 (0.93% patients had no subjective improvement after the partial medial meniscectomy at all. Conclusion. Arthroscopic partial medial meniscetomy is minimally invasive diagnostic and therapeutic procedure and in well selected cases is a method of choice for treatment of medial meniscus injuries when repair techniques are not a viable option. It has small rate of complications, low morbidity and fast rehabilitation.

  6. Hierarchical partial order ranking

    International Nuclear Information System (INIS)

    Carlsen, Lars

    2008-01-01

    Assessing the potential impact on environmental and human health from the production and use of chemicals or from polluted sites involves a multi-criteria evaluation scheme. A priori several parameters are to address, e.g., production tonnage, specific release scenarios, geographical and site-specific factors in addition to various substance dependent parameters. Further socio-economic factors may be taken into consideration. The number of parameters to be included may well appear to be prohibitive for developing a sensible model. The study introduces hierarchical partial order ranking (HPOR) that remedies this problem. By HPOR the original parameters are initially grouped based on their mutual connection and a set of meta-descriptors is derived representing the ranking corresponding to the single groups of descriptors, respectively. A second partial order ranking is carried out based on the meta-descriptors, the final ranking being disclosed though average ranks. An illustrative example on the prioritisation of polluted sites is given. - Hierarchical partial order ranking of polluted sites has been developed for prioritization based on a large number of parameters

  7. Time-resolved fluorescence spectroscopy

    International Nuclear Information System (INIS)

    Gustavsson, Thomas; Mialocq, Jean-Claude

    2007-01-01

    This article addresses the evolution in time of light emitted by a molecular system after a brief photo-excitation. The authors first describe fluorescence from a photo-physical point of view and discuss the characterization of the excited state. Then, they explain some basic notions related to fluorescence characterization (lifetime and decays, quantum efficiency, so on). They present the different experimental methods and techniques currently used to study time-resolved fluorescence. They discuss basic notions of time resolution and spectral reconstruction. They briefly present some conventional methods: intensified Ccd cameras, photo-multipliers and photodiodes associated with a fast oscilloscope, and phase modulation. Other methods and techniques are more precisely presented: time-correlated single photon counting (principle, examples, and fluorescence lifetime imagery), streak camera (principle, examples), and optical methods like the Kerr optical effect (principle and examples) and fluorescence up-conversion (principle and theoretical considerations, examples of application)

  8. Quadrupole splitting and Eu partial lattice dynamics in europium orthophosphate EuPO {sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Klobes, B., E-mail: b.klobes@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Arinicheva, Y., E-mail: y.arinicheva@fz-juelich.de; Neumeier, S., E-mail: s.neumeier@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Simon, R. E., E-mail: r.simon@fz-juelich.de; Jafari, A., E-mail: a.jafari@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Bosbach, D., E-mail: d.bosbach@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Hermann, R. P., E-mail: hermannrp@ornl.gov [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany)

    2016-12-15

    Hyperfine interactions in europium orthophosphate EuPO{sub 4} were investigated using {sup 151}Eu Mössbauer spectroscopy from 6 to 300 K. The value of the quadrupole splitting and the asymmetry parameter were refined and further substantiated by nuclear forward scattering data obtained at room temperature. The temperature dependence of the relative absorption was modeled with an Eu specific Debye temperature of 221(1) K. Eu partial lattice dynamics were probed by means of nuclear inelastic scattering and the mean force constant, the Lamb-Mössbauer factor, the internal energy, the vibrational entropy, the average phonon group velocity were calculated using the extracted density of phonon states. In general, Eu specific vibrations are characterized by rather small phonon energies and contribute strongly to the total entropy of the system. Although there is no classical Debye like behavior at low vibrational energies, the average phonon group velocity can be reasonably approximated using a linear fit.

  9. Local atomic structure of Fe/Cr multilayers: Depth-resolved method

    Science.gov (United States)

    Babanov, Yu. A.; Ponomarev, D. A.; Devyaterikov, D. I.; Salamatov, Yu. A.; Romashev, L. N.; Ustinov, V. V.; Vasin, V. V.; Ageev, A. L.

    2017-10-01

    A depth-resolved method for the investigation of the local atomic structure by combining data of X-ray reflectivity and angle-resolved EXAFS is proposed. The solution of the problem can be divided into three stages: 1) determination of the element concentration profile with the depth z from X-ray reflectivity data, 2) determination of the X-ray fluorescence emission spectrum of the element i absorption coefficient μia (z,E) as a function of depth and photon energy E using the angle-resolved EXAFS data Iif (E , ϑl) , 3) determination of partial correlation functions gij (z , r) as a function of depth from μi (z , E) . All stages of the proposed method are demonstrated on a model example of a multilayer nanoheterostructure Cr/Fe/Cr/Al2O3. Three partial pair correlation functions are obtained. A modified Levenberg-Marquardt algorithm and a regularization method are applied.

  10. Interface-Resolving Simulation of Collision Efficiency of Cloud Droplets

    Science.gov (United States)

    Wang, Lian-Ping; Peng, Cheng; Rosa, Bodgan; Onishi, Ryo

    2017-11-01

    Small-scale air turbulence could enhance the geometric collision rate of cloud droplets while large-scale air turbulence could augment the diffusional growth of cloud droplets. Air turbulence could also enhance the collision efficiency of cloud droplets. Accurate simulation of collision efficiency, however, requires capture of the multi-scale droplet-turbulence and droplet-droplet interactions, which has only been partially achieved in the recent past using the hybrid direct numerical simulation (HDNS) approach. % where Stokes disturbance flow is assumed. The HDNS approach has two major drawbacks: (1) the short-range droplet-droplet interaction is not treated rigorously; (2) the finite-Reynolds number correction to the collision efficiency is not included. In this talk, using two independent numerical methods, we will develop an interface-resolved simulation approach in which the disturbance flows are directly resolved numerically, combined with a rigorous lubrication correction model for near-field droplet-droplet interaction. This multi-scale approach is first used to study the effect of finite flow Reynolds numbers on the droplet collision efficiency in still air. Our simulation results show a significant finite-Re effect on collision efficiency when the droplets are of similar sizes. Preliminary results on integrating this approach in a turbulent flow laden with droplets will also be presented. This work is partially supported by the National Science Foundation.

  11. Partially ordered algebraic systems

    CERN Document Server

    Fuchs, Laszlo

    2011-01-01

    Originally published in an important series of books on pure and applied mathematics, this monograph by a distinguished mathematician explores a high-level area in algebra. It constitutes the first systematic summary of research concerning partially ordered groups, semigroups, rings, and fields. The self-contained treatment features numerous problems, complete proofs, a detailed bibliography, and indexes. It presumes some knowledge of abstract algebra, providing necessary background and references where appropriate. This inexpensive edition of a hard-to-find systematic survey will fill a gap i

  12. Infinite partial summations

    International Nuclear Information System (INIS)

    Sprung, D.W.L.

    1975-01-01

    This paper is a brief review of those aspects of the effective interaction problem that can be grouped under the heading of infinite partial summations of the perturbation series. After a brief mention of the classic examples of infinite summations, the author turns to the effective interaction problem for two extra core particles. Their direct interaction is summed to produce the G matrix, while their indirect interaction through the core is summed in a variety of ways under the heading of core polarization. (orig./WL) [de

  13. On universal partial words

    OpenAIRE

    Chen, Herman Z. Q.; Kitaev, Sergey; Mütze, Torsten; Sun, Brian Y.

    2016-01-01

    A universal word for a finite alphabet $A$ and some integer $n\\geq 1$ is a word over $A$ such that every word in $A^n$ appears exactly once as a subword (cyclically or linearly). It is well-known and easy to prove that universal words exist for any $A$ and $n$. In this work we initiate the systematic study of universal partial words. These are words that in addition to the letters from $A$ may contain an arbitrary number of occurrences of a special `joker' symbol $\\Diamond\

  14. Partial differential equations

    CERN Document Server

    Agranovich, M S

    2002-01-01

    Mark Vishik's Partial Differential Equations seminar held at Moscow State University was one of the world's leading seminars in PDEs for over 40 years. This book celebrates Vishik's eightieth birthday. It comprises new results and survey papers written by many renowned specialists who actively participated over the years in Vishik's seminars. Contributions include original developments and methods in PDEs and related fields, such as mathematical physics, tomography, and symplectic geometry. Papers discuss linear and nonlinear equations, particularly linear elliptic problems in angles and gener

  15. Partial differential equations

    CERN Document Server

    Levine, Harold

    1997-01-01

    The subject matter, partial differential equations (PDEs), has a long history (dating from the 18th century) and an active contemporary phase. An early phase (with a separate focus on taut string vibrations and heat flow through solid bodies) stimulated developments of great importance for mathematical analysis, such as a wider concept of functions and integration and the existence of trigonometric or Fourier series representations. The direct relevance of PDEs to all manner of mathematical, physical and technical problems continues. This book presents a reasonably broad introductory account of the subject, with due regard for analytical detail, applications and historical matters.

  16. Partial differential equations

    CERN Document Server

    Sloan, D; Süli, E

    2001-01-01

    /homepage/sac/cam/na2000/index.html7-Volume Set now available at special set price ! Over the second half of the 20th century the subject area loosely referred to as numerical analysis of partial differential equations (PDEs) has undergone unprecedented development. At its practical end, the vigorous growth and steady diversification of the field were stimulated by the demand for accurate and reliable tools for computational modelling in physical sciences and engineering, and by the rapid development of computer hardware and architecture. At the more theoretical end, the analytical insight in

  17. Elliptic partial differential equations

    CERN Document Server

    Han, Qing

    2011-01-01

    Elliptic Partial Differential Equations by Qing Han and FangHua Lin is one of the best textbooks I know. It is the perfect introduction to PDE. In 150 pages or so it covers an amazing amount of wonderful and extraordinary useful material. I have used it as a textbook at both graduate and undergraduate levels which is possible since it only requires very little background material yet it covers an enormous amount of material. In my opinion it is a must read for all interested in analysis and geometry, and for all of my own PhD students it is indeed just that. I cannot say enough good things abo

  18. Generalized Partial Volume

    DEFF Research Database (Denmark)

    Darkner, Sune; Sporring, Jon

    2011-01-01

    Mutual Information (MI) and normalized mutual information (NMI) are popular choices as similarity measure for multimodal image registration. Presently, one of two approaches is often used for estimating these measures: The Parzen Window (PW) and the Generalized Partial Volume (GPV). Their theoret...... of view as well as w.r.t. computational complexity. Finally, we present algorithms for both approaches for NMI which is comparable in speed to Sum of Squared Differences (SSD), and we illustrate the differences between PW and GPV on a number of registration examples....

  19. Calculation of the hyperfine constants of Vk center in CaF2, SrF2 and BaF2

    International Nuclear Information System (INIS)

    Bufaical, R.F.

    1975-03-01

    The magnetic hyperfine constants of the V sub(K) center in CaF 2 , SrF 2 and BaF 2 have been calculated, assuming a phenomenological model, based on the F 2 central molecule, to describe the wave function of the defect. The introduction of covalence, with the ions neighboring the central molecule, have shown that this is a better description for the defect than a simple central molecule model. It was also shown that the results for the hyperfine constants are strongly dependent on the relaxations of these neighboring ions, which have been determined by fitting the experimental data. The present results are compared with other previous calculations where similar and different methods have been used. A better description for the wave function of the defect is suggested

  20. Temperature dependence of the hyperfine parameters of the iron bearing phases in the Moessbauer spectra collected by the Mars Exploration Rover Spirit

    International Nuclear Information System (INIS)

    Van Cromphaut, Caroline; Resende, Valdirene G. de; De Grave, Eddy; Vandenberghe, Robert E.

    2009-01-01

    This contribution focuses on the Moessbauer spectra acquired by the Mars Exploration Rover Spirit which carried a MIMOS II Moessbauer spectrometer. Only those spectra which present a reasonable statistical quality were selected to for this study. Twenty five Moessbauer spectra have been considered. Common phases identified from the temperature dependent hyperfine parameters are olivine, pyroxene, hematite and magnetite. It is believed that the applied analysis method has provided accurate values for the various hyperfine data averaged over single 10 K temperature intervals in the range 210-260 K. The obtained results, to some extent forced to evolve consistently over the various ΔT intervals considered for a given soil/rock target, are in many cases different from previously published data. Possible reasons for these differences will be discussed.

  1. Calculation of the hyperfine constants of the V sub (K) center in CaF2, SrF2 e BaF2

    International Nuclear Information System (INIS)

    Bufaical, R.F.

    1975-03-01

    The magnetic hyperfine constants of the V sub(K) center in CaF 2 , SrF 2 and BaF 2 have been calculated, assuming a phenomenological model, based on the F - 2 'central molecule', to describe the wave function of the defect. The introduction of covalence with the ions neighboring the 'central molecule', has shown that this is a better description for the defect than a simple 'central molecule' model. It was also shown that the results for the hyperfine constants are strongly dependent on the relaxations of these neighboring ions, which have been determined by fitting the experimental data. The present results are compared with other previous calculations where similar and different methods have been used. A better description for the wave function of the defect is suggested. (author) [pt

  2. Proton, muon and ¹³C hyperfine coupling constants of C₆₀X and C₇₀X (X = H, Mu).

    Science.gov (United States)

    Brodovitch, Jean-Claude; Addison-Jones, Brenda; Ghandi, Khashayar; McKenzie, Iain; Percival, Paul W

    2015-01-21

    The reaction of H atoms with fullerene C70 has been investigated by identifying the radical products formed by addition of the atom muonium (Mu) to the fullerene in solution. Four of the five possible radical isomers of C70Mu were detected by avoided level-crossing resonance (μLCR) spectroscopy, using a dilute solution of enriched (13)C70 in decalin. DFT calculations were used to predict muon and (13)C isotropic hyperfine constants as an aid to assigning the observed μLCR signals. Computational methods were benchmarked against previously published experimental data for (13)C60Mu in solution. Analysis of the μLCR spectrum resulted in the first experimental determination of (13)C hyperfine constants in either C70Mu or C70H. The large number of values confirms predictions that the four radical isomers have extended distributions of unpaired electron spin.

  3. Unilateral removable partial dentures.

    Science.gov (United States)

    Goodall, W A; Greer, A C; Martin, N

    2017-01-27

    Removable partial dentures (RPDs) are widely used to replace missing teeth in order to restore both function and aesthetics for the partially dentate patient. Conventional RPD design is frequently bilateral and consists of a major connector that bridges both sides of the arch. Some patients cannot and will not tolerate such an extensive appliance. For these patients, bridgework may not be a predictable option and it is not always possible to provide implant-retained restorations. This article presents unilateral RPDs as a potential treatment modality for such patients and explores indications and contraindications for their use, including factors relating to patient history, clinical presentation and patient wishes. Through case examples, design, material and fabrication considerations will be discussed. While their use is not widespread, there are a number of patients who benefit from the provision of unilateral RPDs. They are a useful treatment to have in the clinician's armamentarium, but a highly-skilled dental team and a specific patient presentation is required in order for them to be a reasonable and predictable prosthetic option.

  4. Magnetism, chemical bonding and hyperfine properties in the nanoscale antiferromagnet [Fe(O Me){sub 2}(O{sub 2} C C H{sub 2} Cl)]{sub 10}

    Energy Technology Data Exchange (ETDEWEB)

    Zeng, Z.; Duan, Y.; Guenzburger, Diana [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil)

    1996-09-01

    The electronic and magnetic properties of the nanometer-size antiferromagnet (the ferric wheel molecule) are investigated with the first-principles spin-polarized Discrete Variational Method, in the framework of Density Functional theory. Magnetic moments, densities of the states and charge and spin-density maps are obtained. The Moessbauer hyperfine parameters Isomer shift, Quadrupole Splitting and Hyperfine Field are obtained from the calculations and compared to reported experimental values when available. (author). 33 refs., 8 figs., 4 tabs.

  5. Hyperfine structure of the metastable p-barHe+ atom revealed by a laser-induced (n,l) = (37,35) → (38,34) transition

    International Nuclear Information System (INIS)

    Widmann, E.; Eades, J.; Yamazaki, T.

    1996-11-01

    A precise scan of the previously discovered laser-induced transition (n,l) = (37,35) → (38,34) in p-barHe + revealed a doublet structure with a separation of Δν HF = 1.70 ± 0.05 GHz. This new type of 'hyperfine' splitting is ascribed to the interaction of the antiproton orbital angular momentum and the electron spin. (author)

  6. Mixed hyperfine interaction - a tool to investigate the short range order and the strange magnetic behaviour of amorphous Fe-based binary alloys

    International Nuclear Information System (INIS)

    Fries, S.M.; Crummenauer, J.; Gonser, U.; Schaaf, P.; Chien, C.L.

    1989-01-01

    The Moessbauer study of the mixed magnetic dipole and electric quadrupole interaction in the paramagnetic state of amorphous Fe-Zr and Fe-Hf alloys is presented. Strong evidence for chemical short range order of the iron-pure alloys is found. The hyperfine parameters of the iron-rich alloys are marked by a complex applied field and temperature dependence, suggesting a not negligible spin-correlation well above Tc. (orig.)

  7. Hyperfine fields at some 4d, 5d and 4f impurities in ferromagnetic GdZn and GdCd

    International Nuclear Information System (INIS)

    Kasamatsu, Y.; Kojima, K.; Hihara, T.

    1995-01-01

    Hyperfine (hf) fields at 4d (Y, Nb, Rh, Pd), 5d (Lu, Ta, Ir) and 4f (La, Nd, Sm, Eu) impurities in ferromagnetic GdZn and GdCd have been measured by NMR at 4.2 K. The local moment contributions to the hf field suggest that the impurity moments at the beginning and end of the d series are parallel and antiparallel to Gd moments, respectively. The hf results for 4f impurities are also discussed. ((orig.))

  8. Tutorial on Online Partial Evaluation

    Directory of Open Access Journals (Sweden)

    William R. Cook

    2011-09-01

    Full Text Available This paper is a short tutorial introduction to online partial evaluation. We show how to write a simple online partial evaluator for a simple, pure, first-order, functional programming language. In particular, we show that the partial evaluator can be derived as a variation on a compositionally defined interpreter. We demonstrate the use of the resulting partial evaluator for program optimization in the context of model-driven development.

  9. A Partially Observed Markov Decision Process for Dynamic Pricing

    OpenAIRE

    Yossi Aviv; Amit Pazgal

    2005-01-01

    In this paper, we develop a stylized partially observed Markov decision process (POMDP) framework to study a dynamic pricing problem faced by sellers of fashion-like goods. We consider a retailer that plans to sell a given stock of items during a finite sales season. The objective of the retailer is to dynamically price the product in a way that maximizes expected revenues. Our model brings together various types of uncertainties about the demand, some of which are resolvable through sales ob...

  10. Comparison of blind imaging performance of Fizeau and Michelson type arrays for a partially resolved object

    NARCIS (Netherlands)

    Van der Avoort, C.; Den Herder, J.W.; Braat, J.

    2005-01-01

    This paper compares two well-known types of interferometer arrays for optical aperture synthesis. An analytical model for both types describes the expected output, in terms of photon counts. The goal is to characterize the performance of both types of array for blind imaging of a wide-field or

  11. Type-Directed Partial Evaluation

    DEFF Research Database (Denmark)

    Danvy, Olivier

    1998-01-01

    Type-directed partial evaluation uses a normalization function to achieve partial evaluation. These lecture notes review its background, foundations, practice, and applications. Of specific interest is the modular technique of offline and online type-directed partial evaluation in Standard ML...

  12. Type-Directed Partial Evaluation

    DEFF Research Database (Denmark)

    Danvy, Olivier

    1998-01-01

    Type-directed partial evaluation uses a normalization function to achieve partial evaluation. These lecture notes review its background, foundations, practice, and applications. Of specific interest is the modular technique of offline and online type-directed partial evaluation in Standard ML of ...

  13. Theoretical study of hyperfine interactions and optically detected magnetic resonance spectra by simulation of the C291[NV]-H172 diamond cluster hosting nitrogen-vacancy center

    International Nuclear Information System (INIS)

    Nizovtsev, A P; Ya Kilin, S; Pushkarchuk, A L; Pushkarchuk, V A; Jelezko, F

    2014-01-01

    Single nitrogen-vacancy (NV) centers in diamond coupled to neighboring nuclear spins are promising candidates for room-temperature applications in quantum information processing, quantum sensing and metrology. Here we report on a systematic density functional theory simulation of hyperfine coupling of the electronic spin of the NV center to individual 13 C nuclear spins arbitrarily disposed in the H-terminated C 291 [NV] - H 172 cluster hosting the NV center. For the ‘families’ of equivalent positions of the 13 C atom in diamond lattices around the NV center we calculated hyperfine characteristics. For the first time the data are given for a system where the 13 C atom is located on the NV center symmetry axis. Electron paramagnetic resonance transitions in the coupled electron–nuclear spin system 14 NV- 13 C are analyzed as a function of the external magnetic field. Previously reported experimental data from Dréau et al (2012 Phys. Rev. B 85 134107) are described using simulated hyperfine coupling parameters. (paper)

  14. The magnetic hyperfine field in the 181Ta site in the Co2HfAl and Co2HfGa Heusler alloys

    International Nuclear Information System (INIS)

    Silva, R. da.

    1979-01-01

    The hyperfine magnetic fields at 181 Ta nuclei in Heusler alloys Co 2 HfZ (Z=Al, Ga) have been measured using the time differential perturbed gamma-gamma angular correlation (TDPAC) method. The hyperfine fields obtained from these measurements at the liquid nitrogen temperature are -189 and +- 150 kOersted for Co 2 HfAl and Co 2 HfGa, respectively. The concept that the hyperfine field at the Y site is similar to the solute fields in Fe, Co, Ni and Gd matrices is corroborated. We have verified that ratios H sub(hf) sub(Ta)/T sub(c) and H sub(hf) sub(Ta)μ sub(Co) in Co 2 HfZ compounds (Z=Al, Ga, Sn) do not depend on the nature of Z element. However a dependence in the value of observed field with the s-p element in Z site was noticed. We feel that the samples are not completely ordered cubic as observed by the quadrupole interaction measurements. The results are interpreted in terms of the Campbell-Blandin formalism, and it is shown that the spin polarization of conduction electrons at Hf and Ta have opposite signs. (Author) [pt

  15. Magnetic hyperfine fields on 181Ta at the Nb and V sites in Heusler alloys CO2YAL (Y=NB,V)

    International Nuclear Information System (INIS)

    Pendl Junior, W.

    1990-01-01

    Magnetic hyperfine fields (MHF) acting on sup(181)Ta at the Nb and V sites have been determined in the Heusler alloys Co sub(2) NbA1 and Co sub(2) VA1 by the time differential perturbed angular correlation (TDPAC) technique utilizing the well known 133-482 Kev gamma cascade in sup(181)Ta. The measurement were carried out using an automatic spectrometer consisting of three NaI(T1) detectors and a fast-slow coincidence system. The measurements were performed at 77 K with and without an externally applied magnetic field ( ∼ 4.5 KGauss) to determine the sign as well as the magnitude of the hyperfine fields in both alloys. For the alloy Co sub(2) NbA1 a unique field of -138(4) KOe was observed whereas in the case of Co sub(2)VA1 two distinct magnetic sites were observed. The present result show that approximately 24% of the sup(181)Ta atoms in this alloy probe a field of -116(4) KOe while the other ∼ 76% of the atoms feel -83(3) KOe. Present data along with the existing results on similar alloys Co sub(2)T1,Hf,Zr (Al,Ga,Sn) are discussed and compared with the magnetic hyperfine field systematics in Heusler alloys. (author)

  16. Spin-Rotation Hyperfine Splittings at Moderate to High J Values in Methanol

    Science.gov (United States)

    Xu, Li-Hong; Hougen, Jon T.; Belov, Sergey; Golubiatnikov, G. Yu; Lapinov, Alexander; Ilyushin, V.; Alekseev, E. A.; Mescheryakov, A. A.

    2015-06-01

    In this talk we present a possible explanation, based on torsionally mediated proton-spin-overall-rotation interaction operators, for the surprising observation in Nizhny Novgorod several years ago of doublets in some Lamb-dip sub-millimeter-wave transitions between torsion-rotation states of E symmetry in methanol. These observed doublet splittings, some as large as 70 kHz, were later confirmed by independent Lamb-dip measurements in Kharkov. In this talk we first show the observed J-dependence of the doublet splittings for two b-type Q branches (one from each laboratory), and then focus on our theoretical explanation. The latter involves three topics: (i) group theoretically allowed terms in the spin-rotation Hamiltonian, (ii) matrix elements of these terms between the degenerate components of torsion-rotation E states, calculated using wavefunctions from an earlier global fit of torsion-rotation transitions of methanol in the vt = 0, 1, and 2 states, and (iii) least-squares fits of coefficients of these terms to about 35 experimentally resolved doublet splittings in the quantum number ranges of K = -2 to +2, J = 13 to 34, and vt = 0. Rather pleasing residuals are obtained for these doublet splittings, and a number of narrow transitions, in which no doublet splitting could be detected, are also in agreement with predictions from the theory. Some remaining disagreements between experiment and the present theoretical explanation will be mentioned. G. Yu. Golubiatnikov, S. P. Belov, A. V. Lapinov, "CH_3OH Sub-Doppler Spectroscopy," (Paper MF04) and S.P. Belov, A.V. Burenin, G.Yu. Golubiatnikov, A.V. Lapinov, "What is the Nature of the Doublets in the E-Methanol Lamb-dip Spectra?" (Paper FB07), 68th International Symposium on Molecular Spectroscopy, Columbus, Ohio, June 2013. Li-Hong Xu, J. Fisher, R.M. Lees, H.Y. Shi, J.T. Hougen, J.C. Pearson, B.J. Drouin, G.A. Blake, R. Braakman, "Torsion-Rotation Global Analysis of the First Three Torsional States (vt = 0, 1, 2

  17. Resolvability of regional density structure

    Science.gov (United States)

    Plonka, A.; Fichtner, A.

    2016-12-01

    Lateral density variations are the source of mass transport in the Earth at all scales, acting as drivers of convectivemotion. However, the density structure of the Earth remains largely unknown since classic seismic observables and gravityprovide only weak constraints with strong trade-offs. Current density models are therefore often based on velocity scaling,making strong assumptions on the origin of structural heterogeneities, which may not necessarily be correct. Our goal is to assessif 3D density structure may be resolvable with emerging full-waveform inversion techniques. We have previously quantified the impact of regional-scale crustal density structure on seismic waveforms with the conclusion that reasonably sized density variations within thecrust can leave a strong imprint on both travel times and amplitudes, and, while this can produce significant biases in velocity and Q estimates, the seismic waveform inversion for density may become feasible. In this study we performprincipal component analyses of sensitivity kernels for P velocity, S velocity, and density. This is intended to establish theextent to which these kernels are linearly independent, i.e. the extent to which the different parameters may be constrainedindependently. Since the density imprint we observe is not exclusively linked to travel times and amplitudes of specific phases,we consider waveform differences between complete seismograms. We test the method using a known smooth model of the crust and seismograms with clear Love and Rayleigh waves, showing that - as expected - the first principal kernel maximizes sensitivity to SH and SV velocity structure, respectively, and that the leakage between S velocity, P velocity and density parameter spaces is minimal in the chosen setup. Next, we apply the method to data from 81 events around the Iberian Penninsula, registered in total by 492 stations. The objective is to find a principal kernel which would maximize the sensitivity to density

  18. Applied partial differential equations

    CERN Document Server

    Logan, J David

    2004-01-01

    This primer on elementary partial differential equations presents the standard material usually covered in a one-semester, undergraduate course on boundary value problems and PDEs. What makes this book unique is that it is a brief treatment, yet it covers all the major ideas: the wave equation, the diffusion equation, the Laplace equation, and the advection equation on bounded and unbounded domains. Methods include eigenfunction expansions, integral transforms, and characteristics. Mathematical ideas are motivated from physical problems, and the exposition is presented in a concise style accessible to science and engineering students; emphasis is on motivation, concepts, methods, and interpretation, rather than formal theory. This second edition contains new and additional exercises, and it includes a new chapter on the applications of PDEs to biology: age structured models, pattern formation; epidemic wave fronts, and advection-diffusion processes. The student who reads through this book and solves many of t...

  19. Inductance loop and partial

    CERN Document Server

    Paul, Clayton R

    2010-01-01

    "Inductance is an unprecedented text, thoroughly discussing "loop" inductance as well as the increasingly important "partial" inductance. These concepts and their proper calculation are crucial in designing modern high-speed digital systems. World-renowned leader in electromagnetics Clayton Paul provides the knowledge and tools necessary to understand and calculate inductance." "With the present and increasing emphasis on high-speed digital systems and high-frequency analog systems, it is imperative that system designers develop an intimate understanding of the concepts and methods in this book. Inductance is a much-needed textbook designed for senior and graduate-level engineering students, as well as a hands-on guide for working engineers and professionals engaged in the design of high-speed digital and high-frequency analog systems."--Jacket.

  20. Fundamental partial compositeness

    CERN Document Server

    Sannino, Francesco

    2016-11-07

    We construct renormalizable Standard Model extensions, valid up to the Planck scale, that give a composite Higgs from a new fundamental strong force acting on fermions and scalars. Yukawa interactions of these particles with Standard Model fermions realize the partial compositeness scenario. Successful models exist because gauge quantum numbers of Standard Model fermions admit a minimal enough 'square root'. Furthermore, right-handed SM fermions have an SU(2)$_R$-like structure, yielding a custodially-protected composite Higgs. Baryon and lepton numbers arise accidentally. Standard Model fermions acquire mass at tree level, while the Higgs potential and flavor violations are generated by quantum corrections. We further discuss accidental symmetries and other dynamical features stemming from the new strongly interacting scalars. If the same phenomenology can be obtained from models without our elementary scalars, they would reappear as composite states.

  1. Fundamental partial compositeness

    International Nuclear Information System (INIS)

    Sannino, Francesco; Strumia, Alessandro; Tesi, Andrea; Vigiani, Elena

    2016-01-01

    We construct renormalizable Standard Model extensions, valid up to the Planck scale, that give a composite Higgs from a new fundamental strong force acting on fermions and scalars. Yukawa interactions of these particles with Standard Model fermions realize the partial compositeness scenario. Under certain assumptions on the dynamics of the scalars, successful models exist because gauge quantum numbers of Standard Model fermions admit a minimal enough ‘square root’. Furthermore, right-handed SM fermions have an SU(2)_R-like structure, yielding a custodially-protected composite Higgs. Baryon and lepton numbers arise accidentally. Standard Model fermions acquire mass at tree level, while the Higgs potential and flavor violations are generated by quantum corrections. We further discuss accidental symmetries and other dynamical features stemming from the new strongly interacting scalars. If the same phenomenology can be obtained from models without our elementary scalars, they would reappear as composite states.

  2. Relation between hyperfine field and lattice location measurements for heavy impurities in iron: influence of radiation damage

    International Nuclear Information System (INIS)

    Thome, L.; Bernas, H.; Cohen, C.

    1978-01-01

    The relation between the hyperfine interaction (HFI) and the lattice location of heavy impurities in iron is discussed in the light of results (see companion papers) on 169 Yb, 175 Yb and Au in Fe. A compilation of all known results in Fe and Cu reveals a simple correlation between the difference in atomic radii of implanted and host atoms and the corrected extinction ratio in lattice location experiments. A simple model is developed to account simultaneously for the annealing -and implantation- temperature dependence of the impurity HFI and lattice location in Fe between room temperature and 800K. It is based on existing information concerning the nature and evolution of radiation damage in Fe: impurity evolution is described in terms of a two-stage process involving (i) vacancy migration towards the impurity and (ii) migration of the impurity-vacancy complex, with the latter stage being much faster than the former. Quantitative agreement is found with our experimental results, as well as with results obtained on other impurities in Fe. It is suggested that the model is applicable in all cases where vacancy motion determines impurity evolution

  3. Hyperfine properties of La(V{sub 1−x}Fe{sub x})O{sub 3} compounds

    Energy Technology Data Exchange (ETDEWEB)

    Tupan, L. F. S.; Ivashita, F. F.; Barco, R. [Universidade Estadual de Maringá (Brazil); Hallouche, B. [Universidade de Santa Cruz do Sul (Brazil); Paesano, A., E-mail: paesano@wnet.com.br [Universidade Estadual de Maringá (Brazil)

    2017-11-15

    LaV{sub 1−x}Fe{sub x}O{sub 3} perovskites were synthesized in the vanadium-rich concentration range (i.e., x < 0.5) and characterized structurally and for the hyperfine properties of the iron nuclear probe. The aim of this investigation was to better understand the physical transformations that take place in the undoped compound (LaVO{sub 3}) at low temperatures. For that, X-ray diffraction analysis and, more extensively, {sup 57}Fe Mössbauer spectroscopy were applied. The results revealed that the LaV{sub 1}-xFexO{sub 3} vanadium-rich perovskites are orthorhombic at RT, and their lattice parameters decrease with increasing vanadium concentration. Lowering the temperature, the system becomes magnetic, with the iron moment freezing progressively. The presence of two magnetic subspectral components obtained at the lowest measurement temperatures suggests that the vanadium-rich samples, including LaVO{sub 3}, undergo a phase transition from an orthorhombic to a monoclinic structure at low temperatures.

  4. The muon spin response to intermittent hyperfine interaction: modelling the high-temperature electrical activity of hydrogen in silicon

    International Nuclear Information System (INIS)

    Lord, J S; Cox, S F J; Charlton, M; Werf, D P Van der; Lichti, R L; Amato, A

    2004-01-01

    At temperatures above 600 K in silicon, unlike at lower temperatures, the partitioning of muonium between its neutral paramagnetic states and its charged or electronically diamagnetic states corresponds closely to thermodynamic equilibrium. The individual charge states are short lived, with many cycles of carrier capture and release occurring within the muon lifetime. The resultant intermittent hyperfine interaction depolarizes the muons strongly, with longitudinal and transverse relaxation rates remaining distinct up to about 700 K but becoming equal at still higher temperatures. Data up to 900 K are presented and interpreted. The muon spin rotation spectrum in transverse magnetic fields, although collapsed to a single broad line in this charge exchange regime, is shifted substantially from the muon Larmor frequency, the shift being non-linear in field and only in small part due to electron polarization. A new density matrix treatment shows how all three observables can be accounted for with a consistent set of transition rates. These in turn may be interpreted in terms of effective donor and acceptor energy levels appropriate to this high-temperature regime, confirming negative-U behaviour and providing the first estimate, for muonium, of this elusive parameter. At temperatures where passivation complexes are dissociated, these findings provide a guide to, and microscopic models for, the electrical activity of hydrogen

  5. On-line hyperfine structure and isotope shift measurements with diffuse light collection and photon burst detection

    International Nuclear Information System (INIS)

    Lassen, J.; Benck, E.C.; Schuessler, H.A.

    1997-01-01

    An experiment is presently being set up which combines collinear-fast-beam laser spectroscopy with photon burst spectroscopy. Selectivity is provided by the large kinetic isotope shifts together with the practically Doppler free linewidth of the fluorescence from the fast atom beam. The photon burst detection, based on photon correlations in the resonance fluorescence, increases the sensitivity, so that on-line optical isotope shift and hyperfine structure measurements on low intensity radioactive beams become feasible. In order to improve photon burst detection the solid angle of detection and the observation time have to be optimized. To this end a diffuse reflecting cavity has been designed and built, which collects fluorescence over a 45 cm length of the beam and covers the full solid angle. The light collection efficiency of the cavity is calculated to be about 45%. The cavity is being tested with a 11 keV beam of krypton atoms, probing the near infrared transitions in our apparatus at Texas A ampersand M University. copyright 1997 American Institute of Physics

  6. Characterization of magnetic phase transitions in PrMn2Ge2 compound investigated by magnetization and hyperfine field measurements

    Directory of Open Access Journals (Sweden)

    B. Bosch-Santos

    2017-05-01

    Full Text Available The magnetic properties of PrMn2Ge2 compound have been investigated by perturbed γ−γ angular correlation (PAC spectroscopy using 111In(111Cd as probe nuclei as well as by magnetization measurements. This ternary intermetallic compound exhibits different magnetic structures depending on the temperature. The magnetic ordering is mainly associated with the magnetic moment of 3d-Mn sublattice but at low temperatures a magnetic contribution due to ordering of the magnetic moment from 4f-Pr sublattice appears. PAC results with 111Cd probe nuclei at Mn sites show that the temperature dependence of hyperfine field Bhf(T follows the expected behavior for the host magnetization, which could be fitted by two Brillouin functions, one for antiferromagnetic phase and the other for ferromagnetic phase, associated with the magnetic ordering of Mn ions. Magnetization measurements showed the magnetic behavior due to Mn ions highlighting the antiferromagnetic to ferromagnetic transition around 326 K and an increase in the magnetization around 36 K, which is ascribed to Pr ions ordering.

  7. Relativistic coupled-cluster-theory analysis of energies, hyperfine-structure constants, and dipole polarizabilities of Cd+

    Science.gov (United States)

    Li, Cheng-Bin; Yu, Yan-Mei; Sahoo, B. K.

    2018-02-01

    Roles of electron correlation effects in the determination of attachment energies, magnetic-dipole hyperfine-structure constants, and electric-dipole (E 1 ) matrix elements of the low-lying states in the singly charged cadmium ion (Cd+) have been analyzed. We employ the singles and doubles approximated relativistic coupled-cluster (RCC) method to calculate these properties. Intermediate results from the Dirac-Hartree-Fock approximation,the second-order many-body perturbation theory, and considering only the linear terms of the RCC method are given to demonstrate propagation of electron correlation effects in this ion. Contributions from important RCC terms are also given to highlight the importance of various correlation effects in the evaluation of these properties. At the end, we also determine E 1 polarizabilities (αE 1) of the ground and 5 p 2P1 /2 ;3 /2 states of Cd+ in the ab initio approach. We estimate them again by replacing some of the E 1 matrix elements and energies from the measurements to reduce their uncertainties so that they can be used in the high-precision experiments of this ion.

  8. Annihilation detector for an in-beam spectroscopy apparatus to measure the ground state hyperfine splitting of antihydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Sauerzopf, Clemens, E-mail: clemens.sauerzopf@oeaw.ac.at [Stefan Meyer Institute for subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Wien (Austria); Capon, Aaron A.; Diermaier, Martin; Fleck, Markus; Kolbinger, Bernadette [Stefan Meyer Institute for subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Wien (Austria); Malbrunot, Chloé [Stefan Meyer Institute for subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Wien (Austria); Organisation Européenne pour la Recherche Nucléaire (CERN), 1211 Geneva 23 (Switzerland); Massiczek, Oswald; Simon, Martin C.; Vamosi, Stefan; Zmeskal, Johann; Widmann, Eberhard [Stefan Meyer Institute for subatomic Physics, Austrian Academy of Sciences, Boltzmanngasse 3, 1090 Wien (Austria)

    2017-02-11

    The matter-antimatter asymmetry observed in the universe today still lacks a quantitative explanation. One possible mechanism that could contribute to the observed imbalance is a violation of the combined Charge-, Parity- and Time symmetries (CPT). A test of CPT symmetry using anti-atoms is being carried out by the ASACUSA-CUSP collaboration at the CERN Antiproton Decelerator using a low temperature beam of antihydrogen—the most simple atomic system built only of antiparticles. While hydrogen is the most abundant element in the universe, antihydrogen is produced in very small quantities in a laboratory framework. A detector for in-beam measurements of the ground state hyperfine structure of antihydrogen has to be able to detect very low signal rates within high background. To fulfil this challenging task, a two layer barrel hodoscope detector was developed. It is built of plastic scintillators with double sided readout via Silicon Photomultipliers (SiPMs). The SiPM readout is done using novel, compact and cost efficient electronics that incorporate power supply, amplifier and discriminator on a single board. This contribution will evaluate the performance of the new hodoscope detector. - Highlights: • A novel detector for Antihydrogen was successfully commissioned. • A time of flight resolution of better than 1 ns was achieved. • Rudimentary 3D tracking is possible without bar segmentation.

  9. Partial oxidation process

    International Nuclear Information System (INIS)

    Najjar, M.S.

    1987-01-01

    A process is described for the production of gaseous mixtures comprising H/sub 2/+CO by the partial oxidation of a fuel feedstock comprising a heavy liquid hydrocarbonaceous fuel having a nickel, iron, and vanadium-containing ash or petroleum coke having a nickel, iron, and vanadium-containing ash, or mixtures thereof. The feedstock includes a minimum of 0.5 wt. % of sulfur and the ash includes a minimum of 5.0 wt. % vanadium, a minimum of 0.5 ppm nickel, and a minimum of 0.5 ppm iron. The process comprises: (1) mixing together a copper-containing additive with the fuel feedstock; wherein the weight ratio of copper-containing additive to ash in the fuel feedstock is in the range of about 1.0-10.0, and there is at least 10 parts by weight of copper for each part by weight of vanadium; (2) reacting the mixture from (1) at a temperature in the range of 2200 0 F to 2900 0 F and a pressure in the range of about 5 to 250 atmospheres in a free-flow refactory lined partial oxidation reaction zone with a free-oxygen containing gas in the presence of a temperature moderator and in a reducing atmosphere to produce a hot raw effluent gas stream comprising H/sub 2/+CO and entrained molten slag; and where in the reaction zone and the copper-containing additive combines with at least a portion of the nickel and iron constituents and sulfur found in the feedstock to produce a liquid phase washing agent that collects and transports at least a portion of the vanadium-containing oxide laths and spinels and other ash components and refractory out of the reaction zone; and (3) separating nongaseous materials from the hot raw effluent gas stream

  10. Imposing resolved turbulence in CFD simulations

    DEFF Research Database (Denmark)

    Gilling, L.; Sørensen, Niels N.

    2011-01-01

    In large‐eddy simulations, the inflow velocity field should contain resolved turbulence. This paper describes and analyzes two methods for imposing resolved turbulence in the interior of the domain in Computational Fluid Dynamics simulations. The intended application of the methods is to impose...

  11. Resolving Gas-Phase Metallicity In Galaxies

    Science.gov (United States)

    Carton, David

    2017-06-01

    with sizes approximately equal to the half width at half maximum of the point-spread function. However, we also find that the presence of star forming clumps can significantly complicate the interpretation of metallicity gradients in moderately resolved high-redshift galaxies. Therefore we emphasize that care should be taken when comparing nearby well-resolved observations to high-redshift observations of partially resolved galaxies. Chapter 4 We present gas-phase metallicity gradients for 94 star-forming galaxies between (0.08 , i.e. on average we find the centres of these galaxies to be more metal-rich than their outskirts. However, there is significant scatter underlying this and we find that 10% (9) galaxies have significantly positive metallicity gradients, 39% (37) have significantly negative gradients, 28% (26) have gradients consistent with being flat, the remainder 23% (22) are considered to have unreliable gradient estimates. We find a slight trend for a more negative metallicity gradient with both increasing stellar mass and increasing star formation rate (SFR). However, given the potential redshift and size selection effects, we do not consider these trends to be significant. Indeed when we normalize the SFR of our galaxies relative to the main sequence, we do not observe any trend between the metallicity gradient and the normalized SFR. This finding is contrary to other recent studies of galaxies at similar and higher redshifts. We do, however, identify a novel trend between the metallicity gradient of a galaxy and its size. Small galaxies ((r_d 3 kpc) with positive metallicity gradients, and overall there is less scatter in the metallicity gradient amongst the large galaxies. We suggest that these large (well-evolved) galaxies may be analogues of galaxies in the present-day Universe, which also present a common negative metallicity gradient. Chapter 5 The relationship between a galaxy's stellar mass and its gas-phase metallicity results from the complex

  12. ppcor: An R Package for a Fast Calculation to Semi-partial Correlation Coefficients.

    Science.gov (United States)

    Kim, Seongho

    2015-11-01

    Lack of a general matrix formula hampers implementation of the semi-partial correlation, also known as part correlation, to the higher-order coefficient. This is because the higher-order semi-partial correlation calculation using a recursive formula requires an enormous number of recursive calculations to obtain the correlation coefficients. To resolve this difficulty, we derive a general matrix formula of the semi-partial correlation for fast computation. The semi-partial correlations are then implemented on an R package ppcor along with the partial correlation. Owing to the general matrix formulas, users can readily calculate the coefficients of both partial and semi-partial correlations without computational burden. The package ppcor further provides users with the level of the statistical significance with its test statistic.

  13. Experts' understanding of partial derivatives using the Partial Derivative Machine

    OpenAIRE

    Roundy, David; Dorko, Allison; Dray, Tevian; Manogue, Corinne A.; Weber, Eric

    2014-01-01

    Partial derivatives are used in a variety of different ways within physics. Most notably, thermodynamics uses partial derivatives in ways that students often find confusing. As part of a collaboration with mathematics faculty, we are at the beginning of a study of the teaching of partial derivatives, a goal of better aligning the teaching of multivariable calculus with the needs of students in STEM disciplines. As a part of this project, we have performed a pilot study of expert understanding...

  14. Partial Measurements and the Realization of Quantum-Mechanical Counterfactuals

    Science.gov (United States)

    Paraoanu, G. S.

    2011-07-01

    We propose partial measurements as a conceptual tool to understand how to operate with counterfactual claims in quantum physics. Indeed, unlike standard von Neumann measurements, partial measurements can be reversed probabilistically. We first analyze the consequences of this rather unusual feature for the principle of superposition, for the complementarity principle, and for the issue of hidden variables. Then we move on to exploring non-local contexts, by reformulating the EPR paradox, the quantum teleportation experiment, and the entanglement-swapping protocol for the situation in which one uses partial measurements followed by their stochastic reversal. This leads to a number of counter-intuitive results, which are shown to be resolved if we give up the idea of attributing reality to the wavefunction of a single quantum system.

  15. Spatial capture–recapture with partial identity: An application to camera traps

    Science.gov (United States)

    Augustine, Ben C.; Royle, J. Andrew; Kelly, Marcella J.; Satter, Christopher B.; Alonso, Robert S.; Boydston, Erin E.; Crooks, Kevin R.

    2018-01-01

    Camera trapping surveys frequently capture individuals whose identity is only known from a single flank. The most widely used methods for incorporating these partial identity individuals into density analyses discard some of the partial identity capture histories, reducing precision, and, while not previously recognized, introducing bias. Here, we present the spatial partial identity model (SPIM), which uses the spatial location where partial identity samples are captured to probabilistically resolve their complete identities, allowing all partial identity samples to be used in the analysis. We show that the SPIM outperforms other analytical alternatives. We then apply the SPIM to an ocelot data set collected on a trapping array with double-camera stations and a bobcat data set collected on a trapping array with single-camera stations. The SPIM improves inference in both cases and, in the ocelot example, individual sex is determined from photographs used to further resolve partial identities—one of which is resolved to near certainty. The SPIM opens the door for the investigation of trapping designs that deviate from the standard two camera design, the combination of other data types between which identities cannot be deterministically linked, and can be extended to the problem of partial genotypes.

  16. Partial Actions and Power Sets

    Directory of Open Access Journals (Sweden)

    Jesús Ávila

    2013-01-01

    Full Text Available We consider a partial action (X,α with enveloping action (T,β. In this work we extend α to a partial action on the ring (P(X,Δ,∩ and find its enveloping action (E,β. Finally, we introduce the concept of partial action of finite type to investigate the relationship between (E,β and (P(T,β.

  17. Algorithms over partially ordered sets

    DEFF Research Database (Denmark)

    Baer, Robert M.; Østerby, Ole

    1969-01-01

    in partially ordered sets, answer the combinatorial question of how many maximal chains might exist in a partially ordered set withn elements, and we give an algorithm for enumerating all maximal chains. We give (in § 3) algorithms which decide whether a partially ordered set is a (lower or upper) semi......-lattice, and whether a lattice has distributive, modular, and Boolean properties. Finally (in § 4) we give Algol realizations of the various algorithms....

  18. Doping effects on the structural, magnetic, and hyperfine properties of Gd-doped SnO{sub 2} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Coelho-Júnior, H.; Aquino, J. C. R.; Aragón, F. H. [Universidade de Brasília, Núcleo de Física Aplicada, Instituto de Física (Brazil); Hidalgo, P. [Universidade de Brasília, Faculdade Gama-FGA, Setor Central Gama (Brazil); Cohen, R.; Nagamine, L. C. C. M. [Universidade de São Paulo, Instituto de Física (Brazil); Coaquira, J. A. H., E-mail: coaquira@unb.br; Silva, S. W. da [Universidade de Brasília, Núcleo de Física Aplicada, Instituto de Física (Brazil); Brito, H. F. [Universidade de São Paulo, Instituto de Química (Brazil)

    2014-12-15

    In this work we present the study of the structural, magnetic, and hyperfine properties of Gd-doped SnO{sub 2} nanoparticles synthesized by a polymer precursor method. The X-ray diffraction data analysis shows the formation of the rutile-type structure in all samples with Gd content from 1.0 to 10.0 mol%. The mean crystallite size is ∼11 nm for the 1.0 mol% Gd-doped samples and it shows a decreasing tendency as the Gd content is increased. The analysis of magnetic measurements indicates the coexistence of ferromagnetic and paramagnetic phases for the 1.0 mol% Gd-doped sample; however, above that content, only a paramagnetic phase is observed. The ferromagnetic phase observed in the 1.0 mol% Gd-doped sample has been assigned to the presence of bound magnetic polarons which overlap to create a spin-split impurity band. Room-temperature {sup 119}Sn Mössbauer measurements reveal the occurrence of strong electric quadrupole interactions. It has been determined that the absence of magnetic interactions even for 1.0 mol% Gd-doped sample has been related to the weak magnetic field associated to the exchange interaction between magnetic ions and the donor impurity band. The broad distribution of electric quadrupole interactions are attributed to the several non-equivalent surroundings of Sn{sup 4+} ions provoked by the entrance of Gd{sup 3+} ions and to the likely presence of Sn{sup 2+} ions. The isomer shift seems to be nearly independent of the Gd content for samples with Gd content below 7.5 mol%.

  19. MAGNETIC AND HYPERFINE CHARACTERIZATION OF THE THERMAL TRANSFORMATION CuO - Fe2O3 TO Fe3O4

    Directory of Open Access Journals (Sweden)

    Juan D. Betancur

    2018-01-01

    Full Text Available A magnetic study about the thermal transformation of hematite doped with CuO (Fe2O3 + CuO is presented. The heat treatment was carried out at a temperature of 375 ± 1 ºC, in a controlled atmosphere composed by 20% hydrogen and 80% nitrogen. Samples were characterized by Mössbauer spectroscopy at room temperature, magnetization as a function of temperature and hysteresis loops at 10K. Our results suggest that both the hyperfine fields and linewidths of the A and B sites remain essentially constant with increasing the CuO concentration, while at the same time a paramagnetic component arises, which is indicative of the appearance of a precipitate or a new phase of Fe-Cu, i.e. there is not an effective incorporation of the copper into the structure of the magnetite. The saturation magnetization falls from approximately 87 emu/g to 78 emu/g, consistent with such a paramagnetic phase. Also, an increase in the coercivity from ~576 Oe up to ~621 Oe by increasing the percentage of CuO from 2% up to 20% is observed. Such increase is also attributed to the paramagnetic phase acting as pinning center for domain walls, besides also de pinning effect due to vacancies induced by the thermal treatment. Finally, an inversion of the magnetization in the Verwey temperature is observed. The data suggest that by means of the synthesis method employed, it is possible to obtain Fe3O4 magnetite particles coexisting with precipitates of Fe-Cu, giving rise to a modification in the magnetic properties and generatingan interesting effect in the magnetization at the Verwey temperature.

  20. Hyperfine interaction studies of the perovskite oxides of the type RCrO3 (R = Gd, Tb e Dy)

    International Nuclear Information System (INIS)

    Silva, Renilson Adriano da

    2009-01-01

    ABO 3 perovskite oxides have ideal cubic structure, however, some distortions in this type of structure may induce changes from cubic to orthorhombic or rhombroedric symmetry. The larger atoms A are located at the center of a cube, the B atoms are on 8 vertices and oxygen atoms occupy 12 positions in the middle of each side of the cube. Distortions in this structure may lead to new magnetic and electrical properties, with great scientific and technological interest. In this work RCrO 3 (R = Gd, Tb, Dγ) compounds (also known as orthocromites) were studied. The samples were produced by means of sol-gel chemical procedure and analyzed by X-Ray Diffraction. The results showed a single phase with Pbnm space group. The perturbed gamma-gamma angular correlation (PAC) measurements were carried out using 181 Hf( 181 Ta) and 111 In( 111 Cd) nuclear probes, which substitute 'A' and 'B' positions respectively. The probe nuclei were introduced in the samples during the chemical procedures for preparation. One of the objectives of this work's was to study the hyperfine magnetic field and its variation as a function of temperature, crystallographic structure as well as the antiferromagnetic transition temperature (T N ). The PAC Measurements were carried out in the temperature range of 20 to 300 K for R = Gd, Tb and 20 to 800 K in the case of R = Dγ from. Electric field gradient was also measured as a function of temperature. It was possible to observe the expected transition as well as the alignment of Cr spins, as found in literature. The Neel temperatures (TN) for investigated samples are ∼170 K, ∼164 K and ∼148 K for GdCrO 3 , TbCrO 3 and DyCrO 3 respectively. (author)

  1. A path integral molecular dynamics study of the hyperfine coupling constants of the muoniated and hydrogenated acetone radicals

    Energy Technology Data Exchange (ETDEWEB)

    Oba, Yuki; Kawatsu, Tsutomu; Tachikawa, Masanori, E-mail: tachi@yokohama-cu.ac.jp [Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan)

    2016-08-14

    The on-the-fly ab initio density functional path integral molecular dynamics (PIMD) simulations, which can account for both the nuclear quantum effect and thermal effect, were carried out to evaluate the structures and “reduced” isotropic hyperfine coupling constants (HFCCs) for muoniated and hydrogenated acetone radicals (2-muoxy-2-propyl and 2-hydoxy-2-propyl) in vacuo. The reduced HFCC value from a simple geometry optimization calculation without both the nuclear quantum effect and thermal effect is −8.18 MHz, and that by standard ab initio molecular dynamics simulation with only the thermal effect and without the nuclear quantum effect is 0.33 MHz at 300 K, where these two methods cannot distinguish the difference between muoniated and hydrogenated acetone radicals. In contrast, the reduced HFCC value of the muoniated acetone radical by our PIMD simulation is 32.1 MHz, which is about 8 times larger than that for the hydrogenated radical of 3.97 MHz with the same level of calculation. We have found that the HFCC values are highly correlated with the local molecular structures; especially, the Mu—O bond length in the muoniated acetone radical is elongated due to the large nuclear quantum effect of the muon, which makes the expectation value of the HFCC larger. Although our PIMD result calculated in vacuo is about 4 times larger than the measured experimental value in aqueous solvent, the ratio of these HFCC values between muoniated and hydrogenated acetone radicals in vacuo is in reasonable agreement with the ratio of the experimental values in aqueous solvent (8.56 MHz and 0.9 MHz); the explicit presence of solvent molecules has a major effect on decreasing the reduced muon HFCC of in vacuo calculations for the quantitative reproduction.

  2. A path integral molecular dynamics study of the hyperfine coupling constants of the muoniated and hydrogenated acetone radicals

    International Nuclear Information System (INIS)

    Oba, Yuki; Kawatsu, Tsutomu; Tachikawa, Masanori

    2016-01-01

    The on-the-fly ab initio density functional path integral molecular dynamics (PIMD) simulations, which can account for both the nuclear quantum effect and thermal effect, were carried out to evaluate the structures and “reduced” isotropic hyperfine coupling constants (HFCCs) for muoniated and hydrogenated acetone radicals (2-muoxy-2-propyl and 2-hydoxy-2-propyl) in vacuo. The reduced HFCC value from a simple geometry optimization calculation without both the nuclear quantum effect and thermal effect is −8.18 MHz, and that by standard ab initio molecular dynamics simulation with only the thermal effect and without the nuclear quantum effect is 0.33 MHz at 300 K, where these two methods cannot distinguish the difference between muoniated and hydrogenated acetone radicals. In contrast, the reduced HFCC value of the muoniated acetone radical by our PIMD simulation is 32.1 MHz, which is about 8 times larger than that for the hydrogenated radical of 3.97 MHz with the same level of calculation. We have found that the HFCC values are highly correlated with the local molecular structures; especially, the Mu—O bond length in the muoniated acetone radical is elongated due to the large nuclear quantum effect of the muon, which makes the expectation value of the HFCC larger. Although our PIMD result calculated in vacuo is about 4 times larger than the measured experimental value in aqueous solvent, the ratio of these HFCC values between muoniated and hydrogenated acetone radicals in vacuo is in reasonable agreement with the ratio of the experimental values in aqueous solvent (8.56 MHz and 0.9 MHz); the explicit presence of solvent molecules has a major effect on decreasing the reduced muon HFCC of in vacuo calculations for the quantitative reproduction.

  3. Second rank direction cosine spherical tensor operators and the nuclear electric quadrupole hyperfine structure Hamiltonian of rotating molecules

    Science.gov (United States)

    di Lauro, C.

    2018-03-01

    Transformations of vector or tensor properties from a space-fixed to a molecule-fixed axis system are often required in the study of rotating molecules. Spherical components λμ,ν of a first rank irreducible tensor can be obtained from the direction cosines between the two axis systems, and a second rank tensor with spherical components λμ,ν(2) can be built from the direct product λ × λ. It is shown that the treatment of the interaction between molecular rotation and the electric quadrupole of a nucleus is greatly simplified, if the coefficients in the axis-system transformation of the gradient of the electric field of the outer charges at the coupled nucleus are arranged as spherical components λμ,ν(2). Then the reduced matrix elements of the field gradient operators in a symmetric top eigenfunction basis, including their dependence on the molecule-fixed z-angular momentum component k, can be determined from the knowledge of those of λ(2) . The hyperfine structure Hamiltonian Hq is expressed as the sum of terms characterized each by a value of the molecule-fixed index ν, whose matrix elements obey the rule Δk = ν. Some of these terms may vanish because of molecular symmetry, and the specific cases of linear and symmetric top molecules, orthorhombic molecules, and molecules with symmetry lower than orthorhombic are considered. Each ν-term consists of a contraction of the rotational tensor λ(2) and the nuclear quadrupole tensor in the space-fixed frame, and its matrix elements in the rotation-nuclear spin coupled representation can be determined by the standard spherical tensor methods.

  4. Anatomic partial nephrectomy: technique evolution.

    Science.gov (United States)

    Azhar, Raed A; Metcalfe, Charles; Gill, Inderbir S

    2015-03-01

    Partial nephrectomy provides equivalent long-term oncologic and superior functional outcomes as radical nephrectomy for T1a renal masses. Herein, we review the various vascular clamping techniques employed during minimally invasive partial nephrectomy, describe the evolution of our partial nephrectomy technique and provide an update on contemporary thinking about the impact of ischemia on renal function. Recently, partial nephrectomy surgical technique has shifted away from main artery clamping and towards minimizing/eliminating global renal ischemia during partial nephrectomy. Supported by high-fidelity three-dimensional imaging, novel anatomic-based partial nephrectomy techniques have recently been developed, wherein partial nephrectomy can now be performed with segmental, minimal or zero global ischemia to the renal remnant. Sequential innovations have included early unclamping, segmental clamping, super-selective clamping and now culminating in anatomic zero-ischemia surgery. By eliminating 'under-the-gun' time pressure of ischemia for the surgeon, these techniques allow an unhurried, tightly contoured tumour excision with point-specific sutured haemostasis. Recent data indicate that zero-ischemia partial nephrectomy may provide better functional outcomes by minimizing/eliminating global ischemia and preserving greater vascularized kidney volume. Contemporary partial nephrectomy includes a spectrum of surgical techniques ranging from conventional-clamped to novel zero-ischemia approaches. Technique selection should be tailored to each individual case on the basis of tumour characteristics, surgical feasibility, surgeon experience, patient demographics and baseline renal function.

  5. Partial order infinitary term rewriting

    DEFF Research Database (Denmark)

    Bahr, Patrick

    2014-01-01

    We study an alternative model of infinitary term rewriting. Instead of a metric on terms, a partial order on partial terms is employed to formalise convergence of reductions. We consider both a weak and a strong notion of convergence and show that the metric model of convergence coincides with th...... to the metric setting -- orthogonal systems are both infinitarily confluent and infinitarily normalising in the partial order setting. The unique infinitary normal forms that the partial order model admits are Böhm trees....

  6. Time-resolved absorption measurements on OMEGA

    International Nuclear Information System (INIS)

    Jaanimagi, P.A.; DaSilva, L.; Delettrez, J.; Gregory, G.G.; Richardson, M.C.

    1986-01-01

    Time-resolved measurements of the incident laser light that is scattered and/or refracted from targets irradiated by the 24 uv-beam OMEGA laser at LLE, have provided some interesting features related to time-resolved absorption. The decrease in laser absorption characteristic of irradiating a target that implodes during the laser pulse has been observed. The increase in absorption expected as the critical density surface moves from a low to a high Z material in the target has also been noted. The detailed interpretation of these results is made through comparisons with simulation using the code LILAC, as well as with streak data from time-resolved x-ray imaging and spectroscopy. In addition, time and space-resolved imaging of the scattered light yields information on laser irradiation uniformity conditions on the target. The report consists of viewgraphs

  7. Knowledge Extraction from Atomically Resolved Images.

    Science.gov (United States)

    Vlcek, Lukas; Maksov, Artem; Pan, Minghu; Vasudevan, Rama K; Kalinin, Sergei V

    2017-10-24

    Tremendous strides in experimental capabilities of scanning transmission electron microscopy and scanning tunneling microscopy (STM) over the past 30 years made atomically resolved imaging routine. However, consistent integration and use of atomically resolved data with generative models is unavailable, so information on local thermodynamics and other microscopic driving forces encoded in the observed atomic configurations remains hidden. Here, we present a framework based on statistical distance minimization to consistently utilize the information available from atomic configurations obtained from an atomically resolved image and extract meaningful physical interaction parameters. We illustrate the applicability of the framework on an STM image of a FeSe x Te 1-x superconductor, with the segregation of the chalcogen atoms investigated using a nonideal interacting solid solution model. This universal method makes full use of the microscopic degrees of freedom sampled in an atomically resolved image and can be extended via Bayesian inference toward unbiased model selection with uncertainty quantification.

  8. Transient analysis for resolving safety issues

    International Nuclear Information System (INIS)

    Chao, J.; Layman, W.

    1987-01-01

    The Nuclear Safety Analysis Center (NSAC) has a Generic Safety Analysis Program to help resolve high priority generic safety issues. This paper describes several high priority safety issues considered at NSAC and how they were resolved by transient analysis using thermal hydraulics and neutronics codes. These issues are pressurized thermal shock (PTS), anticipated transients without scram (ATWS), steam generator tube rupture (SGTR), and reactivity transients in light of the Chernobyl accident

  9. Time-resolved spectroscopy in synchrotron radiation

    International Nuclear Information System (INIS)

    Rehn, V.; Stanford Univ., CA

    1980-01-01

    Synchrotron radiation (SR) from large-diameter storage rings has intrinsic time structure which facilitates time-resolved measurements form milliseconds to picoseconds and possibly below. The scientific importance of time-resolved measurements is steadily increasing as more and better techniques are discovered and applied to a wider variety of scientific problems. This paper presents a discussion of the importance of various parameters of the SR facility in providing for time-resolved spectroscopy experiments, including the role of beam-line optical design parameters. Special emphasis is placed on the requirements of extremely fast time-resolved experiments with which the effects of atomic vibrational or relaxation motion may be studied. Before discussing the state-of-the-art timing experiments, we review several types of time-resolved measurements which have now become routine: nanosecond-range fluorescence decay times, time-resolved emission and excitation spectroscopies, and various time-of-flight applications. These techniques all depend on a short SR pulse length and a long interpulse period, such as is provided by a large-diameter ring operating in a single-bunch mode. In most cases, the pulse shape and even the stability of the pulse shape is relatively unimportant as long as the pulse length is smaller than the risetime of the detection apparatus, typically 1 to 2 ns. For time resolution smaller than 1 ns, the requirements on the pulse shape become more stringent. (orig./FKS)

  10. On Degenerate Partial Differential Equations

    OpenAIRE

    Chen, Gui-Qiang G.

    2010-01-01

    Some of recent developments, including recent results, ideas, techniques, and approaches, in the study of degenerate partial differential equations are surveyed and analyzed. Several examples of nonlinear degenerate, even mixed, partial differential equations, are presented, which arise naturally in some longstanding, fundamental problems in fluid mechanics and differential geometry. The solution to these fundamental problems greatly requires a deep understanding of nonlinear degenerate parti...

  11. [Acrylic resin removable partial dentures

    NARCIS (Netherlands)

    Baat, C. de; Witter, D.J.; Creugers, N.H.J.

    2011-01-01

    An acrylic resin removable partial denture is distinguished from other types of removable partial dentures by an all-acrylic resin base which is, in principle, solely supported by the edentulous regions of the tooth arch and in the maxilla also by the hard palate. When compared to the other types of

  12. Partial Epilepsy with Auditory Features

    Directory of Open Access Journals (Sweden)

    J Gordon Millichap

    2004-07-01

    Full Text Available The clinical characteristics of 53 sporadic (S cases of idiopathic partial epilepsy with auditory features (IPEAF were analyzed and compared to previously reported familial (F cases of autosomal dominant partial epilepsy with auditory features (ADPEAF in a study at the University of Bologna, Italy.

  13. Manipulation resolves non-trivial structure of corrole monolayer on Ag(111)

    International Nuclear Information System (INIS)

    Tebi, Stefano; Serrano, Giulia; Koch, Reinhold; Müllegger, Stefan; Aldahhak, Hazem; Rauls, Eva; Schmidt, Wolf Gero; Schöfberger, Wolfgang

    2016-01-01

    Non-trivial arrangement of molecules within a molecular network complicates structure determination due to interdigitation, partial overlap, or stacking. We demonstrate that combined imaging and lateral manipulation with a scanning tunneling microscope resolves the intricate structure of a molecular network in two-dimensions in a straightforward manner. The network, formed by a monolayer of 5,10,15-tris(pentafluorophenyl)-corrole molecules on Ag(111), is manipulated for the first time with single-molecule precision. Our results reveal a shingle-like packing of partially overlapping corrole molecules. Density functional theory calculations support our findings. (paper)

  14. Partial twisting for scalar mesons

    International Nuclear Information System (INIS)

    Agadjanov, Dimitri; Meißner, Ulf-G.; Rusetsky, Akaki

    2014-01-01

    The possibility of imposing partially twisted boundary conditions is investigated for the scalar sector of lattice QCD. According to the commonly shared belief, the presence of quark-antiquark annihilation diagrams in the intermediate state generally hinders the use of the partial twisting. Using effective field theory techniques in a finite volume, and studying the scalar sector of QCD with total isospin I=1, we however demonstrate that partial twisting can still be performed, despite the fact that annihilation diagrams are present. The reason for this are delicate cancellations, which emerge due to the graded symmetry in partially quenched QCD with valence, sea and ghost quarks. The modified Lüscher equation in case of partial twisting is given

  15. Reanalysis and extension of the MnH A7Π- X7Σ + (0, 0) band: Fine structure and hyperfine-induced rotational branches

    Science.gov (United States)

    Varberg, Thomas D.; Gray, Jeffrey A.; Field, Robert W.; Merer, Anthony J.

    1992-12-01

    The A7Π- X7Σ + (0, 0) band of MnH at 568 nm has been recorded by laser fluorescence excitation spectroscopy. The original rotational analysis of Nevin [ Proc. R. Irish Acad.48A, 1-45 (1942); 50A, 123-137 (1945)] has been extended with some corrections at low J. Systematic internal hyperfine perturbations in the X7Σ + state, caused by the Δ N = 0, Δ J = ±1 matrix elements of the 55Mn hyperfine term in the Hamiltonian, have been observed in all seven electron spin components over the entire range of N″ studied. These perturbations destroy the "goodness" of J″ as a quantum number, giving rise to hyperfine-induced Δ J = ±2 rotational branches and to observable energy shifts of the most severely affected levels. The A7Π state, with A = 40.5 cm -1 and B = 6.35 cm -1, evolves rapidly from Hund's case ( a) to case ( b) coupling, which produces anomalous branch patterns at low J. A total of 156 rotational branches have been identified and fitted by least squares to an effective Hamiltonian, providing precise values for the rotational and fine structure constants. Values of the principal constants determined in the fit are (1σ errors in units of the last digit are listed in parentheses): The fine structures of the A7Π and X7Σ + states confirm the assignment of the A ← X transition as Mn 4 pπ ← 4 sσ in the presence of a spectator, nonbonding Mn 3 d5 ( 6S) open core.

  16. Dynamic hyperfine interactions in {sup 111}In({sup 111}Cd)-doped ZnO semiconductor: PAC results supported by ab initio calculations

    Energy Technology Data Exchange (ETDEWEB)

    Munoz, Emiliano L., E-mail: munoz@fisica.unlp.edu.ar [Departamento de Fisica and Instituto de Fisica La Plata (IFLP, CONICET La Plata), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900 La Plata (Argentina); Mercurio, Marcio E.; Cordeiro, Moacir R.; Pereira, Luciano F.D.; Carbonari, Artur W. [Instituto de Pesquisas Energeticas y Nucleares-IPEN-CNEN/SP, Sao Paulo (Brazil); Renteria, Mario [Departamento de Fisica and Instituto de Fisica La Plata (IFLP, CONICET La Plata), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 67, 1900 La Plata (Argentina)

    2012-08-15

    In this work, we present results of Time-Differential {gamma}-{gamma} Perturbed-Angular-Correlations (PAC) experiments performed in {sup 111}Cd-doped ZnO semiconductor. The PAC technique has been applied in order to characterize the electric-field-gradient (EFG) tensor at ({sup 111}In (EC){yields}) {sup 111}Cd nuclei located, as was later demonstrated, at defect-free cation sites of the ZnO host structure. The PAC experiments were performed in the temperature range of 77-1075 K. At first glance, the unexpected presence of low-intensity dynamic hyperfine interactions was observed, which were analyzed with a perturbation factor based on the Baeverstam and Othaz model. The experimental EFG results were compared with ab initio calculations performed with the Full-Potential Augmented Plane Wave plus local orbital (FP-APW+lo) method, in the framework of the Density Functional Theory (DFT), using the Wien2K code. The presence of the dynamic hyperfine interactions has been analyzed enlightened by the FP-APW+lo calculations of the EFG performed as a function of the charge state of the cell. We could correlate the large strength of the dynamic hyperfine interaction with the strong variation of the EFG due to changes in the electronic charge distribution in the Cd vicinity during the time-window of the PAC measurement. It was also revealed that the Cd impurity decays to a final stable neutral charge state (Cd{sup 2+}) fast enough (in few ns) to produce the nearly undamped observed PAC spectra.

  17. Hyperfine structure of 87,89Sr 5s4d3D-5snf transitions in collinear fast beam RIMS

    International Nuclear Information System (INIS)

    Bushaw, B. A.; Kluge, H.-J.; Lantzsch, J.; Schwalbach, R.; Schwarz, M.; Stenner, J.; Stevens, H.; Wendt, K.; Zimmer, K.

    1995-01-01

    The title transition, with n=20, 23, and 32 were measured for stable 87 Sr and the observed hfs was interpreted and strong hyperfine mixing of all four terms 1 F3 and 3 F2,3,4 in the upper configuration. The results of the analysis were used to predict the hfs for the radioactive isotope 89 Sr. Measurement were then performed on samples containing 10 9 atoms 89 Sr. The positions and intensities of the hfs components selected for study were found to agree well with the predicted values

  18. Radiative Improvement of the Lattice Nonrelativistic QCD Action Using the Background Field Method and Application to the Hyperfine Splitting of Quarkonium States

    International Nuclear Information System (INIS)

    Hammant, T. C.; Horgan, R. R.; Monahan, C. J.; Hart, A. G.; Hippel, G. M. von

    2011-01-01

    We present the first application of the background field method to nonrelativistic QCD (NRQCD) on the lattice in order to determine the one-loop radiative corrections to the coefficients of the NRQCD action in a manifestly gauge-covariant manner. The coefficients of the σ·B term in the NRQCD action and the four-fermion spin-spin interaction are computed at the one-loop level; the resulting shift of the hyperfine splitting of bottomonium is found to bring the lattice predictions in line with experiment.

  19. Radiative nonrecoil nuclear finite size corrections of order α(Zα){sup 5} to the hyperfine splitting of S-states in muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Faustov, R.N. [Dorodnicyn Computing Centre, Russian Academy of Science, Vavilov Str. 40, 119991 Moscow (Russian Federation); Martynenko, A.P. [Samara State University, Pavlov Str. 1, 443011 Samara (Russian Federation); Samara State Aerospace University named after S.P. Korolyov, Moskovskoye Shosse 34, 443086 Samara (Russian Federation); Martynenko, G.A.; Sorokin, V.V. [Samara State University, Pavlov Str. 1, 443011 Samara (Russian Federation)

    2014-06-02

    On the basis of quasipotential method in quantum electrodynamics we calculate nuclear finite size radiative corrections of order α(Zα){sup 5} to the hyperfine structure of S-wave energy levels in muonic hydrogen and muonic deuterium. For the construction of the particle interaction operator we employ the projection operators on the particle bound states with definite spins. The calculation is performed in the infrared safe Fried–Yennie gauge. Modern experimental data on the electromagnetic form factors of the proton and deuteron are used.

  20. Radiative nonrecoil nuclear finite size corrections of order α(Zα)5 to the hyperfine splitting of S-states in muonic hydrogen

    International Nuclear Information System (INIS)

    Faustov, R.N.; Martynenko, A.P.; Martynenko, G.A.; Sorokin, V.V.

    2014-01-01

    On the basis of quasipotential method in quantum electrodynamics we calculate nuclear finite size radiative corrections of order α(Zα) 5 to the hyperfine structure of S-wave energy levels in muonic hydrogen and muonic deuterium. For the construction of the particle interaction operator we employ the projection operators on the particle bound states with definite spins. The calculation is performed in the infrared safe Fried–Yennie gauge. Modern experimental data on the electromagnetic form factors of the proton and deuteron are used.