Stable π-Extended p -Quinodimethanes: Synthesis and Tunable Ground States

KAUST Repository

Zeng, Zebing

2014-12-18

© 2014 The Chemical Society of Japan and Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. p-Quinodimethane (p-QDM) is a highly reactive hydrocarbon showing large biradical character in the ground state. It has been demonstrated that incorporation of the p-QDM moiety into an aromatic hydrocarbon framework could lead to new π-conjugated systems with significant biradical character and unique optical, electronic and magnetic properties. On the other hand, the extension of p-QDM is expected to result in molecules with even larger biradical character and higher reactivity. Therefore, the synthesis of stable π-extended p-QDMs is very challenging. In this Personal Account we will briefly discuss different stabilizing strategies and synthetic methods towards stable π-extended p-QDMs with tunable ground states and physical properties, including two types of polycyclic hydrocarbons: (1) tetrabenzo-Tschitschibabin\\'s hydrocarbons, and (2) tetracyano-rylenequinodimethanes. We will discuss how the aromaticity, substituents and steric hindrance play important roles in determining their ground states and properties. Incorporation of the p-quinodimethane moiety into aromatic hydrocarbon frameworks can lead to new π-conjugated systems with significant biradical character and unique optical, electronic and magnetic properties. Furthermore, the extension of p-QDM is expected to result in molecules with even larger biradical character and higher reactivity. In this Personal Account, different stabilizing strategies and synthetic methods towards stable π-extended p-QDMs with tunable ground states and physical properties are briefly discussed, including the roles of aromaticity, substituents and steric hindrance.

Electrochromic Behaviors of Water-Soluble Polyaniline with Covalently Bonded Acetyl Ferrocene

Science.gov (United States)

Xiong, Shanxin; Wang, Ru; Li, Shuaishuai; Wu, Bohua; Chu, Jia; Wang, Xiaoqin; Zhang, Runlan; Gong, Ming

2018-04-01

A novel ferrocene-containing hybrid electrochromic material was synthesized via copolymerization of aniline with p-phenylenediamine functionalized acetyl ferrocene in the presence of poly (styrene sulfonate) dopant in an aqueous medium, and neat polyaniline (PANI) was prepared for comparison. The polymerization characteristics and the structure of the copolymer were systematically studied by Fourier-transform infrared, meanwhile, their electrochromic properties and electrochemical behaviors were tested by UV-vis spectra, cyclic voltammetry and electrochemical impedance spectroscopy (EIS). It was found that the strong covalent bond and large conjugated system between PANI and ferrocene enhance the electron transfer rate and electron delocalization in the ferrocene-polyaniline (Fc-PANI) hybrid. In particular, the electrochromic device with Fc-PANI as the active layer shows significant enhancement in optical contrast over the PANI-based device.

Preparation, spectroscopic and antibacterial studies on charge-transfer complexes of 2-hydroxypyridine with picric acid and 7,7‧,8,8‧-tetracyano-p-quinodimethane

Science.gov (United States)

Gaballa, Akmal S.; Amin, Alaa S.

2015-06-01

The reactions of electron acceptors such as picric acid (HPA) and 7,7‧,8,8‧-tetracyano-p-quinodimethane (TCNQ) with 2-hydroxypyridine (HPyO) have been investigated in EtOH at room temperature. Based on elemental analysis and IR spectra of the solid CT-complexes along with the photometric titration curves for the reactions, the data obtained indicate the formation of 1:1 charge transfer complexes [(H2PyO)(PA)] and [(PyO)(HTCNQ)], respectively. The infrared and 1H NMR spectroscopic data indicate a charge transfer interaction associated with a proton migration from the acceptor to the donor followed by intramolecular hydrogen bonding in [(H2PyO)(PA)] complex. Another charge transfer interaction was observed in [(PyO)(HTCNQ)] complex. The formation constants (KCT) for the CT-complexes are shown to be strongly dependent on the type and structure of the electron acceptors. Factors affecting the CT-processes and the kinetics of thermal decomposition of the complexes have been studied. The CT complexes were screened for their antibacterial activities against selected bacterial strains.

Para-quinodimethane-bridged perylene dimers and pericondensed quaterrylenes: The effect of the fusion mode on the ground states and physical properties

KAUST Repository

Das, Soumyajit; Lee, Sangsu; Son, Minjung; Zhu, Xiaojian; Zhang, Wenhua; Zheng, Bin; Hu, Pan; Zeng, Zebing; Sun, Zhe; Zeng, Wangdong; Li, Runwei; Huang, Kuo-Wei; Ding, Jun; Kim, Dongho; Wu, Jishan

2014-01-01

relationships. In this study, para-quinodimethane (p-QDM)-bridged quinoidal perylene dimers 4 and 5 with different fusion modes and their corresponding aromatic counterparts, the pericondensed quaterrylenes 6 and 7, were synthesized. Their ground

Facile route of biopolymer mediated ferrocene (FO) nanoparticles in aqueous dispersion

Energy Technology Data Exchange (ETDEWEB)

Kaus, Noor Haida Mohd., E-mail: noorhaida@usm.my [School of Chemical Sciences, Universiti Sains Malaysia, 11800, Penang, Malaysia and Centre for Organized Matter Chemistry, School of Chemistry, Cantock' s Close, BS8 1TS, Bristol (United Kingdom); Collins, A. M.; Mann, S. [Centre for Organized Matter Chemistry, School of Chemistry, Cantock' s Close, BS8 1TS, Bristol (United Kingdom)

2014-10-24

In this paper, we present a facile method for production stable aqueous dispersion of ferrocene (FO) nanoparticles. Ferrocene compounds were employed to achieve stable nanodispersions, stabilized with three different biopolymers namely, alginate, CM-dextran and chitosan. The nanoparticles produce are spherical, less than 10 nm in mean diameter and highly stable without any sedimentation. Fourier infrared transform (FTIR) and X-ray diffraction (XRD) studies confirmed the purity of ferrocene nanoparticles there is no modifications occur during the preparation route. FTIR spectra results were consistent with the presence of absorption band of cyclopentadienyl ring (C{sub 5}H{sub 5}{sup −} ion) which assigned to ν(C-C) vibrations (1409 cm-1), δ(C-H) stretching at 1001 cm{sup −1} and π(C-H) vibrations at 812 cm{sup −1}. Furthermore, all functional group for biopolymers such as CO from carboxyl group of CM-dextran and sodium alginate appears at 1712 cm{sup −1} and 1709 cm{sup −1} respectively, indicating there are steric repulsion interactions for particles stabilization. Powder X-ray diffraction patterns of sedimented samples of the biopolymers-stabilized ferrocene (FO) showed all reflections which were indexed respectively to the (−110), (001), (−201), (−111), (200), (−211), (210), (120) and (111) according to the monoclinic phase ferrocene. This confirmed that the products obtained were of high purity of Fe and EDAX analysis also suggests that the presence of the Fe element in the colloidal dispersion.

Hybrid Organometallic-Inorganic Nanomaterial: Acetyl Ferrocene Schiff base Immobilized on Silica Coated Magnetite Nanoparticles

Directory of Open Access Journals (Sweden)

M. Masteri-Farahani

2015-10-01

Full Text Available In  this  work,  a  new  hybrid  organometallic-inorganic  hybrid nanomaterial was prepared by immobilization of acetyl ferrocene on the  surface  of magnetite  nanoparticles. Covalent  grafting of silica coated magnetite nanoparticles (SCMNPs with 3-aminopropyl triethoxysilane gave aminopropyl-modified magnetite nanoparticles (AmpSCMNPs. Then, Schiff base condensation  of AmpSCMNPs with acetyl  ferrocene resulted in the preparation of acferro-SCMNPs hybrid nanomaterial. Characterization of the prepared nanomaterial was performed with different physicochemical methods such as Fourier transform infrared spectroscopy (FT-IR, X-ray diffraction (XRD, vibrating sample magnetometry (VSM, thermogravimetric analysis (TGA, scanning electron microscopy (SEM, and transmission electron microscopy (TEM. VSM analysis showed superparamagnetic properties of the prepared nanomaterial and TEM and SEM analyses indicated the relatively spherical nanoparticles with 15 nm average size.

Moessbauer study of tetramethylene bridged ferrocene derivatives Pt. 2

International Nuclear Information System (INIS)

Nagy, A.G.; Hillman, M.

1978-01-01

Suppositions for the molecular structure of trimethylene bridged ferrocene derivatives, i.e. for the tilt of cyclopentadienyl-rings and shortening of iron-ring distance, were supported by Moessbauer spectroscopic studies. The Moessbauer spectra of 1,1'-tetramethyleneferrocene and 1,1',3,3'-bis(tetramethylene)ferrocene were recorded by means of a constant acceleration type spectrometer using a 57 Co source in a chromium matrix. Simultaneous X-ray analysis of 1,1',3,3'-bis(trimethylene)ferrocene and 1,1',2,2',4,4'-tris(trimethylene)ferrocene confirmed the suppositions. (D.P.)

One-electron oxidations of ferrocenes: a pulse radiolysis study

International Nuclear Information System (INIS)

Faraggi, Moshe; Weinraub, Dany; Broitman, Federico; DeFelippis, M.R.; Klapper, M.H.

1988-01-01

Using the pulse radiolysis technique we have studied the oxidation by various inorganic radicals of four water soluble ferrocene derivatives, hydroxyethyl, dimethylaminomethyl, monocarboxylic acid and dicarboxylic acid. We report the second order rate constants for these reactions, the stabilities and spectral properties of the ferrocinium products, and the electrochemically determined ferrocinium/ferrocene redox potentials. We also present preliminary estimates of tyrosine and tryptophan radical redox potentials obtained with the dicarboxylic acid ferrocene derivative as reference, and we discuss the relationship between redox potential differences and the reactivities of the ferrocenes with the inorganic radicals. (author)

Convenient synthesis of magnetically recyclable Fe{sub 3}O{sub 4}@C@CdS photocatalysts by depositing CdS nanocrystals on carbonized ferrocene

Energy Technology Data Exchange (ETDEWEB)

Li, Dan [Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China); Xie, Jianjian [Department of Materials Physics, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China); Zhang, Yong; Qiao, Ru [Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China); Li, Sheng [Department of Materials Physics, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China); Li, Zhengquan, E-mail: zqli@zjnu.edu.cn [Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China); Department of Materials Physics, Zhejiang Normal University, Jinhua, Zhejiang 321004 (China)

2015-10-15

Development of magnetic visible-light-driven photocatalysts is desirable to the practical application of photocatalyts for collection and recycling use. Here we present a facile approach to synthesize Fe{sub 3}O{sub 4}@C@CdS magnetic photocatalysts which can avoid multi-step preparation process. Through one-step solvothermal carbonization of ferrocene, the produced carbon-coated Fe{sub 3}O{sub 4} clusters can serve as both magnetic cores and deposition substrates for in situ generating crystalline CdS nanocrystals on them by rapid microwave irradiation. The prepared Fe{sub 3}O{sub 4}@C@CdS nanoparticles exhibit a uniform core–shell structure and display good photocatalytic activity and recyclability in the degradation of organic dyes. These magnetic photocatalysts may find potential application in wastewater treatment for the future environment remedy. - Highlights: • A rapid strategy is presented to obtain multifunctional core–shell nanostructures. • Magnetic visible-light-driven Fe{sub 3}O{sub 4}@C@CdS nanophotocatalysts are synthesized. • Carbonized ferrocene can provide both magnetic cores and good deposition substrate. • Photocatalytic and recyclable properties of Fe{sub 3}O{sub 4}@C@CdS nanoparticles are explored.

Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets

International Nuclear Information System (INIS)

Lu, Yizhong; Jiang, Yuanyuan; Wu, Haibin; Chen, Wei

2015-01-01

Highlights: • Graphene oxide (GO) nanosheets functionalized with ferrocenyl moieties (GO-Fc) are fabricated. • GO-Fc shows efficient electronic communication between ferrocene centers. • GO-Fc exhibits two pairs of voltammetric peaks with a large potential spacing of 0.515 V. • GO-Fc shows a broad absorption peak in the near-infrared range (∼ 1428 nm) at mixed valence. - Abstract: Graphene oxide (GO) nanosheets functionalized with ferrocenyl moieties (GO-Fc) were fabricated through strong covalent C−C bonds. The resulting hybrid showed efficient electronic communication between ferrocene centers due to the strong electron delocalization facilitated by the large pi-pi conjugated structure of graphene sheets. The obtained hybrid exhibited two pairs of voltammetric peaks with a large potential spacing of 0.515 V and a broad absorption peak in the near-infrared range (∼ 1428 nm) at mixed valence. The electrochemical and near IR spectroscopic features suggested a Class II/III behavior of the intervalence charge transfer. This work indicates clearly that strong electronic coupling between ferrocene centers can be easily realized across graphene nanosheets with sp 2 -hybridized carbon

Potentiometric and amperometric titration of ferrocene by cerium(4)

International Nuclear Information System (INIS)

Solomatin, V.T.

1985-01-01

Redox-potentials (E) of ferrocene (ferricenium-cation), Ce(4)/Ce(3) pairs are investigated and a possibility of regulating E value of these systems depending on the composition of water-organic media is shown. E value of Ce(4)/Ce(3) system decreases as increasing H 2 SO 4 concentration and CH 3 COOH mol share in the water-organic phase. Kinetic investigations of Ce(4)-ferrocene reactions shown that E constant value is achieved in 12-16 s depending on donor-acceptor properties of the solvent. Optimum conditions are chosen for potentiometric and amperometric titration of ferrocene by ceruium (4) in technological products. The method is versatile and permits to determine from tenths to dozens per cent of ferrocene

Aptasensor for ATP based on analyte-induced dissociation of ferrocene-aptamer conjugates from manganese dioxide nanosheets on a screen-printed carbon electrode

International Nuclear Information System (INIS)

Tang, Dianping; Hou, Li

2016-01-01

The authors report on a new electrochemical aptasensing strategy for the determination of adenosine - 5’-triphosphate (ATP) at picomolar levels. First, manganese dioxide (MnO 2 ) nanosheets with an average size of ∼70 nm were synthesized via a hot-injection method on the basis of reaction between potassium permanganate and the cationic detergent cetyltrimethylammonium bromide. The resulting MnO 2 nanosheets were then immobilized onto a pretreated screen-printed carbon electrode which readily binds the ferrocene-labeled ATP aptamer through the van der Waals force between the nucleobases and the basal plane of the nanoflakes. The immobilized ferrocene-aptamer conjugates activates the electrical contact with the electrode and produces a strong signal in the potentials scanned (0.0 to 1.0 V vs. Ag/AgCl). Upon addition of ATP, it will react with the aptamer and cause the dissociation of the ferrocene-aptamer from the nanosheets, this resulting in a decrease in the electrical signal. Under optimal conditions, this platform exhibits a detection limit as low as 0.32 nM of ATP. The repeatability and intermediate precision is below 10.7 % at a 10 nM concentration level. The method was applied to analyze blank fetal calf serum spiked with ATP, and the recoveries (at 3 concentration levels) ranged between 91.3 and 118 %. This detection scheme is rapid, simple, cost-effective, and does not require extensive sample preparation or multiple washing steps. (author)

Covalent modification and exfoliation of graphene oxide using ferrocene

Science.gov (United States)

Avinash, M. B.; Subrahmanyam, K. S.; Sundarayya, Y.; Govindaraju, T.

2010-09-01

Large scale preparation of single-layer graphene and graphene oxide is of great importance due to their potential applications. We report a simple room temperature method for the exfoliation of graphene oxide using covalent modification of graphene oxide with ferrocene to obtain single-layer graphene oxide sheets. The samples were characterized by FESEM, HRTEM, AFM, EDAX, FT-IR, Raman and Mössbauer spectroscopic studies. HRTEM micrograph of the covalently modified graphene oxide showed increased interlayer spacing of ~2.4 nm due to ferrocene intercalation. The presence of single-layer graphene oxide sheets were confirmed by AFM studies. The covalently modified ferrocene-graphene oxide composite showed interesting magnetic behavior.Large scale preparation of single-layer graphene and graphene oxide is of great importance due to their potential applications. We report a simple room temperature method for the exfoliation of graphene oxide using covalent modification of graphene oxide with ferrocene to obtain single-layer graphene oxide sheets. The samples were characterized by FESEM, HRTEM, AFM, EDAX, FT-IR, Raman and Mössbauer spectroscopic studies. HRTEM micrograph of the covalently modified graphene oxide showed increased interlayer spacing of ~2.4 nm due to ferrocene intercalation. The presence of single-layer graphene oxide sheets were confirmed by AFM studies. The covalently modified ferrocene-graphene oxide composite showed interesting magnetic behavior. Electronic supplementary information (ESI) available: Magnetic data; AFM images; TEM micrographs; and Mössbauer spectroscopic data. See DOI: 10.1039/c0nr00024h

A ferrocene functionalized polymer: Poly [N-(ferrocenylmethyl)-o-phenylenediamine]. Electrochemical production and spectroelectroelectrochemical investigation in acetonitrile medium

International Nuclear Information System (INIS)

Gülce, Handan; Yetkin, Ahmet; Akgül, Eda; Gülce, Ahmet

2013-01-01

An electroactive and conductive polymer having pendant ferrocene units was prepared from the electrochemical polymerization of the synthesized monomer, N-(ferrocenylmethyl)-o-phenylenediamine in 0.1 M tetrabuthylammonium perchlorate/acetonitrile medium. The poly-N-(ferrocenylmethyl)-o-phenylenediamine (poly-FMOPD) was generated potentiodynamically or potentiostatically at both of indium tin oxide coated glass substrate and Pt electrodes. The poly-FMOPD film was characterized by cyclic voltammetry, chronoamperometry, electrochemical impedance spectroscopy, dry conductivity measurements, ultraviolet–visible absorption spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy. The electrical conductivity of polymer films was determined as 1.0 × 10 −1 and 4 × 10 −2 S cm −1 depending on the potential scanning range during electropolymerization. The electroactivity of the polymer film retained even after hundreds cycles between their reduced and oxidized states. The spectroelectrochemical analysis demonstrated that the polymer film reveals a reversible cycling with distinctive color changes between neutral and reduced/oxidized forms. For the polymer film, the maximum optical contrasts (ΔT%) were measured as 18% at and 37% at 480 nm by step the potential between (0.00 V)-(1.20 V) and (− 0.50 V)-(− 1.70 V), respectively. The optical energy band gaps as the onset energy for the π–π* transitions are calculated as 1.89 eV, 1.85 eV and 1.88 eV for the neutral, reduced and oxidized states of poly-FMOPD. - Highlights: • The ferrocene functionalized monomer and its polymer were synthesized electrochemically. • Spectroelectrochemical investigations were performed. • The polymer film showed reversible color changes between different redox forms. • It was found that the polymer film is conductive

Vapour pressures and enthalpies of vaporization of a series of the ferrocene derivatives

International Nuclear Information System (INIS)

Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Krol, Olesya V.; Varushchenko, Raisa M.; Chelovskaya, Nelly V.

2007-01-01

Vapour pressures of the ferrocene, ferrocene-methanol, benzyl-ferrocene, and benzoyl-ferrocene have been determined by the transpiration method. The molar enthalpies of sublimation Δ cr g H m and of vaporization Δ l g H m have been determined from the temperature dependence of the vapour pressure. The molar enthalpies of fusion of these compounds were measured by d.s.c. The measured data sets of vaporization, sublimation, and fusion enthalpies were checked for internal consistency

Smoke reduction from pool fires using ferrocene and derivatives

International Nuclear Information System (INIS)

Mitchell, J.B.A.; Moir, M.E.

1992-01-01

A series of acyl and alkyl substituted ferrocene derivatives were tested as smoke control agents in laboratory-scale burn tests. In the tests, the soot produced by a given volume was collected on a filter and its weight measured to determine the relative smoke reducing effectiveness of the various derivatives. As the molecular weight of the derivative increases, the effectiveness decreases when added at a fixed weight concentration. The heavier derivatives were much less effective on a per-weight basis than ferrocene, while the multiply substituted compounds appeared to be more effective. In field tests conducted to evaluate the effectiveness of ferrocene in reducing smoke during combustion of other hydrocarbon fuels, it was found that there was a very large soot yield from gasoline fuel, higher than for crude oil even when ferrocene was used. In meso-scale tests, a drastic reduction in smoke yield was obtained when using a new liquid smoke-control additive during combustion of dilbit (bitumen diluted by gas condensate) floating on water. 3 refs., 5 figs., 1 tab

Observation by flow 1H NMR and dimerization kinetics and products of reactive ortho-quinodimethanes and benzocyclobutadiene

International Nuclear Information System (INIS)

Fischer, D.

1990-01-01

The reactive o-quinodimethanes, 1,2-dimethylene-1,2-dihydronaphthalene (9) and o-xylylene (1) were observed by flow 1 H NMR spectroscopy at room temperature. The 1 H NMR spectrum of 9 was obtained in the absence of precursor and dimers. However, the 1 H NMR spectrum of the more reactive 1, generated in a similar manner from [o-((trimethylsilyl)methyl)benzyl]trimethylammonium iodide (5.) could be obtained only in the presence of its stable [4 + 2] and [4 + 4] dimers. The dimerization kinetics of 3-methyl- (5'), 3,6-dimethyl- (11), 3-isopropyl- (12), and 3,6-diisoproply-1,2-xylylene (13) in acetonitrile (CH 3 CN) were studied by stopped-flow UV-visible spectroscopy. Fluoride ion induced 1,2-elimination from 2-elimination from 2-trimethylsilylbenzocyclobutenyl-1 mesylate (26) was used to generate the reactive molecule benzocyclobutadiene (1') in CD 3 CN, which was observed by flow 1 H NMR spectroscopy at room temperature. The 1 H NMR spectrum (in CD 3 CN) of 1,2-dimethylene-1,2-dihydrothiophene (1 double-prime), obtained by fluoride ion induced 1,4-elimination from 3-(trimethylammoniummethyl)-2-(trimethylsilylmethyl)thiophene iodine was observed by flow 1 H NMR spectroscopy at room temperature. The dimerization rate of 1 double-prime in CH 3 CN, generated in the same manner, was measured by UV-visible spectroscopy. 166 refs., 7 figs., 7 tabs

Ionic interactions in electroactive self-assembled monolayers of ferrocene species

Science.gov (United States)

Delong, Hugh C.; Donohue, John J.; Buttry, Daniel A.

1991-04-01

The electrochemical and interfacial behavior of two types of electroactive self-assembled monolayer systems is investigated at gold electrodes. The first type is a ferrocene-based surfactant (a redox surfactant) derived from (dimethylamino)methylferrocene via quaternization of the amino group with various n-alkylbromides. These have a long alkyl chain with 16 or 18 carbons in the chain pendent from the cationic ammonium group. These are referred to as C16 and C18. The second type is a ferrocene-based dimeric species with a disulfide functional group capable of providing a permanent anchor to the Au electrode, thus endowing monolayers of this species with exceptional stability towards desorption. The electrochemical quartz crystal microbalance (EQM) is used to monitor the mass changes which occur at the electrode surface during the redox processes of these two species.

Enantiopure Ferrocene-Based Planar-Chiral Iridacycles: Stereospecific Control of Iridium-Centred Chirality.

Science.gov (United States)

Arthurs, Ross A; Ismail, Muhammad; Prior, Christopher C; Oganesyan, Vasily S; Horton, Peter N; Coles, Simon J; Richards, Christopher J

2016-02-24

Reaction of [IrCp*Cl2 ]2 with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6 H4 ) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration Sp *,RIr *. Extension to (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline gave highly diastereoselective control over the new elements of planar chirality and metal-based pseudo-tetrahedral chirality, to give both neutral and cationic half-sandwich iridacycles of absolute configuration Sc ,Sp ,RIr . Substitution reactions proceed with retention of configuration, with the planar chirality controlling the metal-centred chirality through an iron-iridium interaction in the coordinatively unsaturated cationic intermediate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Anomalous photoconductivity of ferrocene

Energy Technology Data Exchange (ETDEWEB)

Chakraborty, A K [Indian Association for the Cultivation of Science, Calcutta (India). Dept. of Spectroscopy; Mallik, B [Indian Association for the Cultivation of Science, Calcutta (India). Dept. of Spectroscopy

1995-08-15

Photoconductivity behaviour of ferrocene, a very useful metallo-organic sandwich compound, has been investigated at different constant temperatures using powdery material in a sandwich type of cell configuration and with the exposure of a polychromatic light source (mercury lamp of 125 W). Measurements with a constant d.c. bias voltage (27 V) across the sample cell and a fixed intensity of the exciting light source have shown a drastic change in the photocurrent versus time profile with the increase in temperature. Anomalous changes have been observed in the plot of the photocurrent versus reciprocal of temperature. Such changes are completely absent in the corresponding dark current behaviour. The photoinduced changes have been observed to be almost reversible in the entire temperature range. In a particular temperature range the reversibility of photocurrent is accompanied by fluctuations in equilibrium current obtained after switching off the light source. The observed anomalous changes in photocurrent have been explained by photoinduced phase transition in ferrocene. The possible origin and implications of this photoinduced phase transition are discussed. (orig.)

Organometallic and Bioorganometallic Chemistry - Ferrocene and Metal Carbonyls

Directory of Open Access Journals (Sweden)

Čakić Semenčić, M.

2011-02-01

Full Text Available Organometallic chemistry deals with compounds containing metal-carbon bonds. Basic organometallics derived from the s- and p-block metals (containing solely σ-bonds were understood earlier, while organometallic chemistry of the d- and f-block has developed much more recently. These compounds are characterized by three types of M-C bonds (σ, π and δand their structures are impossible to deduce by chemical means alone; fundamental advances had to await the development of X-ray diffraction, as well as IR- and NMR-spectroscopy. On the other hand, elucidation of the structure of e. g. vitamin B12 and ferrocene (discovered in 1951 contributed to progress in these instrumental analytical methods, influencing further phenomenal success of transition-metal organometallic chemistry in the second half of the twentieth century. The most thoroughly explored fields of application of organometallics were in the area of catalysis, asymmetric synthesis, olefin metathesis, as well as organic synthesis and access to new materials and polymers.The most usual ligands bound to d- and f-metals are carbon monoxide, phosphines, alkyls, carbenes and arenes, and in this review the bonding patterns in the metal carbonyls and ferrocene are elaborated. The common characteristics of these two classes are two-component bonds. The CO-M bonds include (i donation from ligand HOMO to vacant M d-orbitals (σ-bond, and (ii back-donation from the filled M d-orbitals in the ligand LUMO (π-bond. Similar (but much more complicated ferrocene contains delocalized bonds consisting of electron donation from Cp to Fe (σ-bonds- and π-bonding and δ-back-bonding from metal to Cp. In such a way ferrocene, i. e. (η5-Cp2Fe contains 18 bonding electrons giving to this compound "superaromatic" properties in the sense of stability and electrophilic substitution. In contrast to benzenoid aromatic compounds reactions in two Cp-rings can occur giving homo- and heteroannularly mono-, two-… per

Synthesis and Characterization of Ferrocene Derivatives and Preliminarily Electrocatalytic Oxidation of L-Cysteine at Nafion-Ferrocene Derivatives Modified Glassy Carbon Electrode

Directory of Open Access Journals (Sweden)

Jianping Yong

2014-01-01

Full Text Available Five new structural ferrocene derivatives (2a~2e were firstly synthesized and characterized by 1H NMR, 13C NMR, ESI-MS, and XRD. Subsequently, the preliminarily electrocatalytic oxidation of L-cysteine (L-Cys at nafion-ferrocene derivatives modified glassy carbon electrode (GCE has also been investigated by cyclic voltammetry. The results showed that 2e can dramatically electrocatalyze the oxidation of L-cysteine at its modified GCE in 0.1 mol L−1 NaNO3 aqueous solution with a quasireversible process with ΔEp≈55 mV.

1-(Ferrocen-1-ylmethyl-3-methylimidazol-3-ium iodide

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Vincent O. Nyamori

2012-12-01

Full Text Available The structure of the title compound, [Fe(C5H5(C10H12N2]I, consists of a 1-(ferrocen-1-ylmethyl-3-methylimidazolium cation which is counter-balanced by an iodide anion. The cyclopentadienyl (Cp rings of the ferrocene unit have a slightly staggered conformation skewed from an ideal eclipsed conformation by an angle of 3.5 (6°. The interplanar angle between the Cp and the imidazole ring is 67.94 (2°.

Highly efficient betanin dye based ZnO and ZnO/Au Schottky barrier solar cell

Energy Technology Data Exchange (ETDEWEB)

Thankappan, Aparna, E-mail: aparna.subhash@gmail.com [International School of Photonics (ISP), Cochin University of Science and Technology, Kochi (India); Inter University Centre for Nanomaterials and Devices (IUCND), Cochin University of Science and Technology, Kochi (India); Divya, S.; Augustine, Anju K.; Girijavallaban, C.P.; Radhakrishnan, P.; Thomas, Sheenu; Nampoori, V.P.N. [International School of Photonics (ISP), Cochin University of Science and Technology, Kochi (India)

2015-05-29

Performance of dye sensitized solar cells based on betanin natural dye from red beets with various nanostructured photoanodes on transparent conducting glass has been investigated. In four different electrolyte systems cell efficiency of 2.99% and overall photon to current conversion efficiency of 20% were achieved using ZnO nanosheet electrode with iodide based electrolyte in acetonitrile solution. To enhance solar harvesting in organic solar cells, uniform sized metal nanoparticles (gold (Au) of ~ 8 nm) synthesized via microwave irradiation method were incorporated into the device consisting of ZnO. Enhanced power conversion efficiency of 1.71% was achieved with ZnO/Au nanocomposite compared to the 0.868% efficiency of the bare ZnO nanosheet cell with ferrocene based electrolyte. - Highlights: • The influence of electrolytes has been studied. • Cell efficiency of 2.99% was achieved by ZnO. • Enhancement of efficiency with incorporation of Au nano.

Micro-sized organometallic compound of ferrocene as high-performance anode material for advanced lithium-ion batteries

Science.gov (United States)

Liu, Zhen; Feng, Li; Su, Xiaoru; Qin, Chenyang; Zhao, Kun; Hu, Fang; Zhou, Mingjiong; Xia, Yongyao

2018-01-01

An organometallic compound of ferrocene is first investigated as a promising anode for lithium-ion batteries. The electrochemical properties of ferrocene are conducted by galvanostatic charge and discharge. The ferrocene anode exhibits a high reversible capacity and great cycling stability, as well as superior rate capability. The electrochemical reaction of ferrocene is semi-reversible and some metallic Fe remains in the electrode even after delithiation. The metallic Fe formed in electrode and the stable solid electrolyte interphase should be responsible for its excellent electrochemical performance.

Chiral ferrocenes in asymmetric catalysis: synthesis and applications

National Research Council Canada - National Science Library

Dai, Li-Xin; Hou, Xue-Long

2010-01-01

.... It provides a thorough overview of the synthesis and characterization of different types of chiral ferrocene ligands, their application to various catalytic asymmetric reactions, and versatile chiral...

A Ferrocene-Based Catecholamide Ligand: the Consequences of Ligand Swivel for Directed Supramolecular Self-Assembly

Energy Technology Data Exchange (ETDEWEB)

Mugridge, Jeffrey; Fiedler, Dorothea; Raymond, Kenneth

2010-02-04

A ferrocene-based biscatecholamide ligand was prepared and investigated for the formation of metal-ligand supramolecular assemblies with different metals. Reaction with Ge(IV) resulted in the formation of a variety of Ge{sub n}L{sub m} coordination complexes, including [Ge{sub 2}L{sub 3}]{sup 4-} and [Ge{sub 2}L{sub 2}({mu}-OMe){sub 2}]{sup 2-}. The ligand's ability to swivel about the ferrocenyl linker and adopt different conformations accounts for formation of many different Ge{sub n}L{sub m} species. This study demonstrates why conformational ligand rigidity is essential in the rational design and directed self-assembly of supramolecular complexes.

Synthesis and application of aryl-ferrocenyl(pseudo-biarylic) complexes. Part 5. Design and synthesis of a new type of ferrocene-based planar chiral DMAP analogues. A new catalyst system for asymmetric nucleophilic catalysis

DEFF Research Database (Denmark)

Seitzberg, J.G; Dissing, C; Søtofte, Inger

2005-01-01

A new first-generation catalyst system for nucleophilic catalysis has been developed. It is based on a planar chiral ferrocene skeleton with either the potent nucleophile 4-(dimethylamino)pyridine (DMAP) or the related 4-nitropyridine N-oxide attached in either the 2- or the 3-position. The synth......A new first-generation catalyst system for nucleophilic catalysis has been developed. It is based on a planar chiral ferrocene skeleton with either the potent nucleophile 4-(dimethylamino)pyridine (DMAP) or the related 4-nitropyridine N-oxide attached in either the 2- or the 3-position...

Immobilization of ferrocene-modified SNAP-fusion proteins

NARCIS (Netherlands)

Wasserberg, D.; Uhlenheuer, D.; Neirynck, P.; Neirynck, Pauline; Cabanas Danés, Jordi; Schenkel, J.H.; Ravoo, B.J.; An, Q.; Huskens, Jurriaan; Milroy, L.G.; Brunsveld, Luc; Jonkheijm, Pascal

2013-01-01

The supramolecular assembly of proteins on surfaces has been investigated via the site-selective incorporation of a supramolecular moiety on proteins. To this end, fluorescent proteins have been site-selectively labeled with ferrocenes, as supramolecular guest moieties, via SNAP-tag technology. The

Synthesis of coumarin or ferrocene labeled nucleosides via Staudinger ligation

Directory of Open Access Journals (Sweden)

Kois Pavol

2006-11-01

Full Text Available Abstract Background Reaction of azides with triaryl phosphines under mild conditions gives iminophosphoranes which can react with almost any kind of electrophilic reagent, e.g. aldehydes/ketones to form imines or esters to form amides. This so-called Staudinger ligation has been employed in a wide range of applications as a general tool for bioconjugation including specific labeling of nucleic acids. Results A new approach for the preparation of labeled nucleosides via intermolecular Staudinger ligation is described. Reaction of azidonucleosides with triphenylphosphine lead to iminophosphorane intermediates, which react subsequently with derivatives of coumarin or ferrocene to form coumarin or ferrocene labeled nucleosides. Fluorescent properties of coumarin labeled nucleosides are determined. Conclusion New coumarin and ferrocene labeled nucleosides were prepared via intermolecular Staudinger ligation. This reaction joins the fluorescent coumarin and biospecific nucleoside to the new molecule with promising fluorescent and electrochemical properties. The isolated yields of products depend on the structure of azidonucleoside and carboxylic acids. A detailed study of the kinetics of the Staudinger ligation with nucleoside substrates is in progress.

O envolvimento parental após a separação/divórcio Parental involvement after separation/divorce

Directory of Open Access Journals (Sweden)

Luciana Suárez Grzybowski

2010-01-01

Full Text Available Apoiados no modelo ecológico-contextual e no conceito de envolvimento parental, este artigo se propõe a discutir as práticas parentais de pais e mães separados/divorciados com seus filhos. Para tanto, foram pesquisados 234 sujeitos (117 pais/117 mães com filhos em idade escolar, que responderam o Inventário de Práticas Parentais. Tal instrumento avaliou o envolvimento parental em 5 áreas: envolvimento afetivo, envolvimento didático, envolvimento social, envolvimento disciplinar e responsabilidade. Os resultados evidenciam maior envolvimento materno do que paterno com os filhos após o divórcio, tanto direto (cuidados, interação quanto indireto (monitoramento, preocupação. A coabitação com a mãe mostrou ser uma variável significativa associada ao maior envolvimento dela em atividades no espaço privado/doméstico, enquanto os pais tiveram maior envolvimento no espaço público/social. Características contextuais (coabitação, freqüência de visitas e características dos pais (ocupação, escolaridade, questões afetivo-conjugais mostraram-se fortemente associadas ao envolvimento parental após o divórcio.Based on the ecological-contextual model and on the concept of parental involvement, this article proposes to discuss the parental practices of separated/divorced fathers and mothers towards their children. In order to do so, 234 subjects (117 fathers/117 mothers with children at school were interviewed via the Parental Practices Inventory. Such instrument evaluated the parental involvement in 5 areas: affective involvement, didactic involvement, social involvement, disciplinary involvement and, responsibility. The results showed greater maternal involvement with children after the divorce: direct (care, interaction and indirect (monitoring, preoccupation. The cohabitation with the mother revealed itself as a significant variable associated to her greater involvement with activities in the private/domestic environment while

Electrochemical studies of ferrocene in a lithium ion conducting organic carbonate electrolyte

International Nuclear Information System (INIS)

Laoire, Cormac O.; Plichta, Edward; Hendrickson, Mary; Mukerjee, Sanjeev; Abraham, K.M.

2009-01-01

We carried out a detailed study of the kinetics of oxidation of ferrocene (Fc) to ferrocenium ion (Fc + ) in the non-aqueous lithium ion conducting electrolyte composed of a solution of 1 M LiPF 6 in 1:1 EC:EMC solvent mixture. This study using cyclic (CV) and rotating disk electrode (RDE) voltammetry showed that the Fc 0 /Fc + redox couple is reversible in this highly concentrated electrolyte. The ferrocene and ferrocenium ion diffusion coefficients (D) were calculated from these results. In addition, the electron transfer rate constant (k 0 ) and the exchange current density for the oxidation of ferrocene were determined. A comparison of the kinetic data obtained from the two electrochemical techniques appears to show that the data from the RDE experiments are more reliable because they are collected under strict mass transport control. A Tafel slope of c.a. 79 mV/decade and a transfer coefficient α of 0.3 obtained from analysis of the RDE data for ferrocene oxidation suggest that the structure of the activated complex is closer to that of the oxidized specie due to strong interactions with the carbonate solvents. The experiments reported here are relevant to the study of redox reagents for the chemical overcharge protection of Li-ion batteries.

A Ferrocene-Quinoxaline Derivative as a Highly Selective Probe for Colorimetric and Redox Sensing of Toxic Mercury(II Cations

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Antonio Caballero

2010-12-01

Full Text Available A new chemosensor molecule 3 based on a ferrocene-quinoxaline dyad recognizes mercury (II cations in acetonitrile solution. Upon recognition, an anodic shift of the ferrocene/ferrocenium oxidation peaks and a progressive red-shift (Δλ = 140 nm of the low-energy band, are observed in its absorption spectrum. This change in the absorption spectrum is accompanied by a colour change from orange to deep green, which can be used for a “naked-eye” detection of this metal cation.

Linkage of α-cyclodextrin-terminated poly(dimethylsiloxanes by inclusion of quasi bifunctional ferrocene

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Helmut Ritter

2013-07-01

Full Text Available We report the noncovalent linkage of terminally substituted oligo(dimethylsiloxanes bearing α-cyclodextrins (α-CD as host end groups for the cyclopentadienyl rings of ferrocene. This double complexation of unsubstituted ferrocene leads to a supramolecuar formation of the siloxane strands. Structural characterization was performed by the use of 1H NMR and IR spectroscopy and by mass spectrometry. Electron microscopy studies and dynamic light scattering measurements show a significant decrease of the derivative size after the complexation with ferrocene. In addition, further evidence for the successful complexation of the end groups was verified by the shifts of the protons in the 1H NMR spectra and in the correlation signals of the 2D ROESY NMR spectra.

Para-quinodimethane-bridged perylene dimers and pericondensed quaterrylenes: The effect of the fusion mode on the ground states and physical properties

KAUST Repository

Das, Soumyajit

2014-07-23

Polycyclic hydrocarbon compounds with a singlet biradical ground state show unique physical properties and promising material applications; therefore, it is important to understand the fundamental structure/biradical character/physical properties relationships. In this study, para-quinodimethane (p-QDM)-bridged quinoidal perylene dimers 4 and 5 with different fusion modes and their corresponding aromatic counterparts, the pericondensed quaterrylenes 6 and 7, were synthesized. Their ground-state electronic structures and physical properties were studied by using various experiments assisted with DFT calculations. The proaromatic p-QDM-bridged perylene monoimide dimer 4 has a singlet biradical ground state with a small singlet/triplet energy gap (-2.97 kcalmol-1), whereas the antiaromatic s-indacene-bridged N-annulated perylene dimer 5 exists as a closed-shell quinoid with an obvious intramolecular charge-transfer character. Both of these dimers showed shorter singlet excited-state lifetimes, larger two-photon-absorption cross sections, and smaller energy gaps than the corresponding aromatic quaterrylene derivatives 6 and 7, respectively. Our studies revealed how the fusion mode and aromaticity affect the ground state and, consequently, the photophysical properties and electronic properties of a series of extended polycyclic hydrocarbon compounds. A matter of fusion mode! Fusion of a para-quinodimethane (p-QDM) subunit at the peri and β positions of perylene dimers leads to systems with different ground states, that is, open and closed shell (see picture). These systems showed large two-photon absorption cross sections and ultrafast excited-state dynamics relative to their corresponding pericondensed aromatic quaterrylene counterparts. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spectroscopic Studies on the Effect of Some Ferrocene Derivatives in the Formation of Silver Nanoparticles.

Science.gov (United States)

Sanyal, Manik Kumar; Biswas, Bipul; Chowdhury, Avijit; Mallik, Biswanath

2016-06-01

Silver nanoparticles were prepared by microwave assisted method using silver nitrate as precursor in the presence of some ferrocene derivatives. The formation of the silver nanoparticles was monitored using UV-Vis spectroscopy. The UV-Vis spectroscopy revealed the formation of silver nanoparticles by exhibiting typical surface plasmon absorption band. The position of plasmon band (406-429 nm) was observed to depend on the nature of a particular ferrocene derivative used. TEM images indicated that the nanoparticles were spherical in shape and well-dispersed. Quantum dots (3.2 nm) were prepared by using ferrocenecarboxylic acid. The surface plasmon absorption band has shown red shift with increasing concentration of ferrocene derivative. For different duration of microwave heating time, intensity of absorption spectra in general was found to increase except in presence of ferrocene carbaldehyde where it decreased. Time-dependent spectra have indicated almost stable position of the surface plasmon band with increasing time of observation confirming that the as prepared silver nanoparticles did not aggregate with lapse of time.

Recommended vapor pressure and thermophysical data for ferrocene

Czech Academy of Sciences Publication Activity Database

Fulem, Michal; Růžička, K.; Červinka, C.; Rocha, M.A.A.; Santos, L.M.N.B.F.; Berg, R.F.

2013-01-01

Roč. 57, FEB (2013), 530-540 ISSN 0021-9614 Institutional support: RVO:68378271 Keywords : ferrocene * vapor pressure * heat capacity * ideal gas thermodynamic properties * sublimation enthalpy * recommended vapor pressure equation Subject RIV: BJ - Thermodynamics Impact factor: 2.423, year: 2013

A novel amperometric alcohol biosensor developed in a 3rd generation bioelectrode platform using peroxidase coupled ferrocene activated alcohol oxidase as biorecognition system.

Science.gov (United States)

Chinnadayyala, Somasekhar R; Kakoti, Ankana; Santhosh, Mallesh; Goswami, Pranab

2014-05-15

Alcohol oxidase (AOx) with a two-fold increase in efficiency (Kcat/Km) was achieved by physical entrapment of the activator ferrocene in the protein matrix through a simple microwave based partial unfolding technique and was used to develop a 3rd generation biosensor for improved detection of alcohol in liquid samples. The ferrocene molecules were stably entrapped in the AOx protein matrix in a molar ratio of ~3:1 through electrostatic interaction with the Trp residues involved in the functional activity of the enzyme as demonstrated by advanced analytical techniques. The sensor was fabricated by immobilizing ferrocene entrapped alcohol oxidase (FcAOx) and sol-gel chitosan film coated horseradish peroxidase (HRP) on a multi-walled carbon nanotube (MWCNT) modified glassy carbon electrode through layer-by-layer technique. The bioelectrode reactions involved the formation of H2O2 by FcAOx biocatalysis of substrate alcohol followed by HRP-catalyzed reduction of the liberated H2O2 through MWCNT supported direct electron transfer mechanism. The amperometric biosensor exhibited a linear response to alcohol in the range of 5.0 × 10(-6) to 30 × 10(-4)mol L(-1) with a detection limit of 2.3 × 10(-6) mol L(-1), and a sensitivity of 150 µA mM(-1) cm(-2). The biosensor response was steady for 28 successive measurements completed in a period of 5h and retained ~90% of the original response even after four weeks when stored at 4 °C. The biosensor was successfully applied for the determination of alcohol in commercial samples and its performance was validated by comparing with the data obtained by GC analyses of the samples. © 2013 Published by Elsevier B.V.

Liquid- and Gas-Phase Diffusion of Ferrocene in Thin Films of Metal-Organic Frameworks

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Wencai Zhou

2015-06-01

Full Text Available The mass transfer of the guest molecules in nanoporous host materials, in particular in metal-organic frameworks (MOFs, is among the crucial features of their applications. By using thin surface-mounted MOF films in combination with a quartz crystal microbalance (QCM, the diffusion of ferrocene vapor and of ethanolic and hexanic ferrocene solution in HKUST-1 was investigated. For the first time, liquid- and gas-phase diffusion in MOFs was compared directly in the identical sample. The diffusion coefficients are in the same order of magnitude (~10−16 m2·s−1, whereas the diffusion coefficient of ferrocene in the empty framework is roughly 3-times smaller than in the MOF which is filled with ethanol or n-hexane.

Liquid- and Gas-Phase Diffusion of Ferrocene in Thin Films of Metal-Organic Frameworks

Science.gov (United States)

Zhou, Wencai; Wöll, Christof; Heinke, Lars

2015-01-01

The mass transfer of the guest molecules in nanoporous host materials, in particular in metal-organic frameworks (MOFs), is among the crucial features of their applications. By using thin surface-mounted MOF films in combination with a quartz crystal microbalance (QCM), the diffusion of ferrocene vapor and of ethanolic and hexanic ferrocene solution in HKUST-1 was investigated. For the first time, liquid- and gas-phase diffusion in MOFs was compared directly in the identical sample. The diffusion coefficients are in the same order of magnitude (~10−16 m2·s−1), whereas the diffusion coefficient of ferrocene in the empty framework is roughly 3-times smaller than in the MOF which is filled with ethanol or n-hexane.

New ferrocenic pyrrolo[1,2-a]quinoxaline derivatives: synthesis, and in vitro antimalarial activity.

Science.gov (United States)

Guillon, Jean; Moreau, Stéphane; Mouray, Elisabeth; Sinou, Véronique; Forfar, Isabelle; Fabre, Solene Belisle; Desplat, Vanessa; Millet, Pascal; Parzy, Daniel; Jarry, Christian; Grellier, Philippe

2008-10-15

Following our search for antimalarial compounds, novel series of ferrocenic pyrrolo[1,2-a]quinoxaline derivatives 1-2 were synthesized from various substituted nitroanilines and tested for in vitro activity upon the erythrocytic development of Plasmodiumfalciparum strains with different chloroquine-resistance status. The pyrrolo[1,2-a]quinoxalines 1 were prepared in 6-8 steps through a regioselective palladium-catalyzed monoamination by coupling 4-chloropyrrolo[1,2-a]quinoxalines with 1,3-bis(aminopropyl)piperazine or -methylamine using Xantphos as the ligand. The ferrocenic bispyrrolo[1,2-a]quinoxalines 2 were prepared by reductive amination of previously described bispyrrolo[1,2-a]quinoxalines 9 with ferrocene-carboxaldehyde, by treatment with NaHB(OAc)(3). The best results were observed with ferrocenic pyrrolo[1,2-a]quinoxalines linked by a bis(3-aminopropyl)piperazine. Moreover, it was observed that a methoxy group on the pyrrolo[1,2-a]quinoxaline nucleus and no substitution on the terminal N-ferrocenylmethylamine function enhanced the pharmacological activity. Selected compounds 1b, 1f-h, 1l and 2a were tested for their ability to inhibit beta-haematin formation, the synthetic equivalent of hemozoin, by using the HPIA (heme polymerization inhibitory activity) assay. Of the tested compounds, only 2a showed a beta-haematin formation inhibition, but no inhibition of haem polymerization was observed with the other selected ferrocenic monopyrrolo[1,2-a]quinoxaline derivatives 1b, 1f-h and 1l, as the IC(50) values were superior to 10 equivalents.

Redox-Enabled, pH-Disabled Pyrazoline-Ferrocene INHIBIT Logic Gates.

Science.gov (United States)

Scerri, Glenn J; Cini, Miriam; Schembri, Jonathan S; da Costa, Paola F; Johnson, Alex D; Magri, David C

2017-07-05

Pyrazoline-ferrocene conjugates with an "electron-donor-spacer-fluorophore-receptor" format are demonstrated as redox-fluorescent two-input INHIBIT logic gates. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Solubilities of ferrocene and acetylferrocene in supercritical carbon dioxide

DEFF Research Database (Denmark)

Kazemi, Somayeh; Belandria, Veronica; Janssen, Nico

2012-01-01

In this work, the solubilities of ferrocene and acetylferrocene in supercritical carbon dioxide (scCO2) were measured using an analytical method in a quasi-flow apparatus. High-performance liquid chromatography was applied through an online sampling procedure to determine the concentration...

Charge-transfer spectra of ferrocene in halocarbon solvents under ...

Indian Academy of Sciences (India)

Unknown

Ferrocene (bis(cyclopentadienyl) iron: (C5H5)2Fe; abbreviated as FcH, the first ... For removing the dissolved oxygen from the solution, dry nitrogen gas was allowed to ... The error limit involved in the excitation wavelength is ~ 0⋅2 nm and the.

Construction of ferrocene modified conducting polymer based amperometric urea biosensor.

Science.gov (United States)

Dervisevic, Muamer; Dervisevic, Esma; Senel, Mehmet; Cevik, Emre; Yildiz, Huseyin Bekir; Camurlu, Pınar

2017-07-01

Herein, an electrochemical urea sensing bio-electrode is reported that has been constructed by firstly electropolymerizing 4-(2,5-Di(thiophen-2-yl)-1H-pyrrol-1-yl)aniline monomer (SNS-Aniline) on Pencil Graphite Electrode (PGE), then modifying the polymer coated electrode surface with di-amino-Ferrocene (DAFc) as the mediator, and lastly Urease enzyme through glutaraldehyde crosslinking. The effect of pH, temperature, polymer thickness, and applied potential on the electrode current response was investigated besides performing storage and operational stability experiments with the interference studies. The resulting urea biosensor's amperometric response was linear in the range of 0.1-8.5mM with the sensitivity of 0.54μA/mM, detection limit of 12μM, and short response time of 2s. The designed bio-electrode was tested with real human blood and urine samples where it showed excellent analytical performance with insignificant interference. Copyright © 2017 Elsevier Inc. All rights reserved.

[sup 57]Fe Moessbauer spectroscopic studies of the ferrocene molecular reorientation in AlPO[sub 4]-5 and AlPO[sub 4]-8 frameworks

Energy Technology Data Exchange (ETDEWEB)

Lund, A.; Nicholson, D.G. (Department of Chemistry, University of Trondheim, Dragvoll (Norway)); Parish, R.V.; Wright, J.P. (Department of Chemistry, UMIST, Manchester (United Kingdom))

1994-01-01

[sup 57]Fe Moessbauer spectroscopic studies were carried out on ferrocene guest molecules in some microporous aluminium phosphate host lattices in order to investigate their behaviour in the aluminium phosphate channels. The 300 K spectra show broad single lines with isomer shifts of 0.39 and 0.41 mm s[sup -1] relative to iron for AlPO[sub 4]-5:ferrocene and AlPO[sub 4]-8:ferrocene inclusion compounds, respectively. The absence of quadrupole splittings for these materials contrasts with the large quadrupole splitting observed for ferrocene itself at the same temperature. The low-temperature spectrum (20 K) for AlPO[sub 4]-5:ferrocene shows a doublet with quadrupole splitting of 2.37 mm s[sup -1] and an isomer shift of 0.55 mm s[sup -1]. The collapse of the quadrupole splitting at room temperature is consistent with the ferrocene molecules rotating within the channels. (au).

Solubility of solid ferrocene in pressurized hot water

Czech Academy of Sciences Publication Activity Database

Karásek, Pavel; Hohnová, Barbora; Planeta, Josef; Roth, Michal

2010-01-01

Roč. 55, č. 8 (2010), s. 2866-2869 ISSN 0021-9568 R&D Projects: GA ČR GA203/07/0886; GA ČR GA203/08/1465; GA ČR GA203/08/1536 Institutional research plan: CEZ:AV0Z40310501 Keywords : pressurized hot water * ferrocene * solubility Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 2.089, year: 2010

All-Plastic Electrochemical Transistor for Glucose Sensing Using a Ferrocene Mediator

Directory of Open Access Journals (Sweden)

George G. Malliaras

2009-12-01

Full Text Available We demonstrate a glucose sensor based on an organic electrochemical transistor (OECT in which the channel, source, drain, and gate electrodes are made from the conducting polymer poly(3,4-ethylenedioxythiophene doped with poly(styrene sulfonate (PEDOT:PSS. The OECT employs a ferrocene mediator to shuttle electrons between the enzyme glucose oxidase and a PEDOT:PSS gate electrode. The device can be fabricated using a one-layer patterning process and offers glucose detection down to the micromolar range, consistent with levels present in human saliva.

Polymersomes, smaller than you think: ferrocene as a TEM probe to determine core structure

International Nuclear Information System (INIS)

Johnston, A. H.; Dalton, P. D.; Newman, T. A.

2010-01-01

By incorporating ferrocene into the hydrophobic membrane of PEG-b-PCL polymersome nanoparticles it is possible to selectively visualize their core using Transmission Electron Microscopy (TEM). Two different sizes of ferrocene-loaded polymersomes with mean hydrodynamic diameters of approximately 40 and 90 nm were prepared. Image analysis of TEM pictures of these polymersomes found that the mean diameter of the core was 4-5 times smaller than the mean hydrodynamic diameter. The values obtained also allow the surface diameter and internal volume of the core to be calculated.

Synthesis, characterization and catalytic utilization of a ferrocene diamidodiphosphane

Czech Academy of Sciences Publication Activity Database

Štěpnička, P.; Schulz, J.; Císařová, I.; Fejfarová, Karla

2007-01-01

Roč. 72, č. 4 (2007), s. 453-467 ISSN 0010-0765 Grant - others:GAMŠk(CZ) LC06070 Program:LC Institutional research plan: CEZ:AV0Z10100521 Keywords : ferrocene * phosphines * amides * Suzuki-Miyaura cross-coupling, crystal structure determination * igands * x-ray diffraction Subject RIV: CA - Inorganic Chemistry Impact factor: 0.879, year: 2007

Computational and Pharmacological Evaluation of Ferrocene-Based Acyl Ureas and Homoleptic Cadmium Carboxylate Derivatives for Anti-diabetic Potential

Directory of Open Access Journals (Sweden)

Shahar Bano

2018-01-01

Full Text Available We investigated possible anti-diabetic effect of ferrocene-based acyl ureas: 4-ferrocenyl aniline (PFA, 1-(4-chlorobenzoyl-3-(4-ferrocenylphenyl urea (DPC1, 1-(3-chlorobenzoyl-3-(4-ferrocenylphenyl urea (DMC1, 1-(2-chlorobenzoyl-3-(4-ferrocenylphenyl urea (DOC1 and homoleptic cadmium carboxylates: bis (diphenylacetato cadmium (II (DPAA, bis (4-chlorophenylacetato cadmium (II (CPAA, using in silico and in vivo techniques. PFA, DPC1, DMC1, DOC1, DPAA and CPAA exhibited high binding affinities (ACE ≥ −350 Kcal/mol against targets: aldose reductase, peroxisome proliferator-activated receptor γ, 11β-hydroxysteroid dehydrogenase-1, C-alpha glucosidase and glucokinase, while showed moderate affinities (ACE ≥ −250 Kcal/mol against N-alpha glucosidase, dipeptidyl peptidase-IV, phosphorylated-Akt, glycogen synthase kinase-3β, fructose-1,6-bisphosphatase and phosphoenolpyruvate carboxykinase, whereas revealed lower affinities (ACE < −250 Kcal/mol vs. alpha amylase, protein tyrosine phosphatases 1B, glycogen phosphorylase and phosphatidylinositol 3 kinase. In alloxan (300 mg/Kg-induced diabetic mice, DPAA and DPC1 (1–10 mg/Kg at day 1, 5, 10, 15, and 20th decreased blood glucose levels, compared to diabetic control group and improved the treated animals body weight. DPAA (10 mg/Kg and DPC1 (5 mg/Kg in time-dependent manner (30–120 min. enhanced tolerance of oral glucose overload in mice. DPAA and DPCI dose-dependently at 1, 5, and 10 mg/Kg decreased glycosylated hemoglobin levels in diabetic animals, as caused by metformin. These results indicate that aforementioned derivatives of ferrocene and cadmium possess anti-diabetic potential.

ALIENAÇÃO PARENTAL - MEIOS DE PREVENÇÃO ADOTADOS PELO ESTADO DEMOCRÁTICO DE DIREITO

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Priscila Fernandes Santana

2017-01-01

Full Text Available Diante da quebra da unidade familiar, uma das primeiras vítimas são as crianças e adolescentes. Nesta situação, é comum a ocorrência de Alienação Parental, com a tentativa de um cônjuge afastar a criança do outro. O Estado Democrático de Direito, ao atuar na defesa de garantias fundamentais, tem papel relevante na proteção do direito fundamental de convivência familiar e comunitária garantidos a criança e adolescente. Com base nas leis 12.318/2010 e 13.058/2014, bem como jurisprudência e doutrina pertinente, este artigo defende que a guarda compartilhada atua como um mecanismo com força preventiva enquanto a lei sobre alienação parental tem por foco atuar em situações em que já existem indícios de ocorrência de alienação parental – um papel, portanto, mais coativo que preventivo

A relação entre o estilo parental e o otimismo da criança The relationship between parenting style and child’s optimism

Directory of Open Access Journals (Sweden)

Lidia Natalia Dobrianskyj Weber

2003-06-01

Full Text Available Esta pesquisa investigou se o otimismo da criança está relacionado ao estilo parental. Os dados provêm de 280 alunos (entre 9 e 12 anos, de duas escola públicas de Curitiba. Os pais foram classificados em um dos quatro estilos parentais (autoritativo, autoritário, indulgente e negligente, de acordo com o escore que seus filhos lhes deram nas duas escalas de responsividade e exigência parental. O otimismo das crianças foi acessado pelo Questionário de Estilo de Atribuição para Crianças. Testes estatísticos (Anova e Correlação mostraram que pais autoritativos foram associados a maiores escores de otimismo e a menores escores de passividade, enquanto pais negligentes foram associados a menores escores de otimismo e a maiores escores de passividade. Esses resultados mostram que os pais possuem papel importante no processo de aprendizado do otimismo da criança, e sugere que crianças educadas por pais autoritativos estão melhor preparadas para enfrentar as adversidades de forma otimista.This study investigated whether child optimism is related to parenting style. The data came from 280 students, aged 9 to 12 years, from two public schools in Curitiba. Parents were classified in one of the four parenting styles (authoritative, authoritarian, indulgent and neglectful, according to the scores children gave them on the two scales of parental responsiveness and demandingness. Children optimism was assessed by the Children’s Attributional Style Questionnaire. Statistics tests (Anova and Correlation showed that authoritative parents were associated to higher optimism scores and to lower hopelessness score, while negligent parents were associated to lower optimism scores and higher hopelessness score. These results show that parents has an important role on the learning processes of children’s optimism, and suggest that children reared by authoritative parents are more prepared to face adversities in a optimist way.

Significação parental acerca do desvio fonológico Significación parental acerca del desvío fonológico Parental meaning about to speech disorder

Directory of Open Access Journals (Sweden)

Amanda Schreiner Pereira

2009-12-01

Full Text Available Este trabalho objetivou relacionar o desvio fonológico e o discurso parental. Para tanto, baseou-se em uma metodologia qualitativa, a partir da Análise de Conteúdo. Participaram da pesquisa 18 (dezoito familiar/responsável por crianças diagnosticadas como com Desvio Fonológico e encaminhados ao Centro de Estudo de Linguagem e Fala (CELF do Serviço de Atendimento Fonoaudiológico (SAF da Universidade Federal de Santa Maria (UFSM. O instrumento utilizado foi uma Entrevista do Discurso Parental. Os resultados iniciais, obtidos por meio da generalização dos dados das Entrevistas, compararam os participantes quanto à significação parental destinada tanto à criança quanto ao desvio. Observou-se que características comportamentais e temperamentais das crianças estavam ligadas aos discursos parentais, estes não apresentaram relação direta com o Desvio Fonológico.El objetivo del presente trabajo ha sido relacionar el desvío fonológico y el discurso parental. Por lo tanto, se ha basado en una metodología cualitativa, a partir del análisis de contenido. Participaron de la pesquisa 18 (dieciocho familiares / tutores por niños diagnosticados con Desvío Fonológico y encaminados al Centro de Estudios del Lenguaje y Habla del Servicio de Atención fonoaudiológica (SAF de la Universidad Federal de Santa Maria (UFSM. El instrumento utilizado fue una entrevista del discurso parental. Los resultados iniciales, obtenidos por medio de la generalización de los datos de las entrevistas, compararon los participantes cuánto a la significación parental destinada tanto al niño cuanto al desvío. Se ha observado que características de comportamiento y temperamento de los niños estaban conectadas al discurso parental, pero estos no presentaron relación directa con el desvío fonológico.The following paper aimed at relating speech disorders and parental speech. The basis was a qualitative methodology through Content Analysis. Eighteen

Addition of ferrocene controls polymorphism and enhances charge mobilities in poly(3-hexylthiophene) thin-film transistors

Science.gov (United States)

Smith, Brandon; Clark, Michael; Grieco, Christopher; Larsen, Alec; Asbury, John; Gomez, Enrique

2015-03-01

Crystalline organic molecules often exhibit the ability to form multiple crystal structures depending on the processing conditions. Exploiting this polymorphism to optimize molecular orbital overlap between adjacent molecules within the unit lattice of conjugated polymers is an approach to enhance charge transport within the material. We have demonstrated the formation of tighter π- π stacking poly(3-hexylthiophene-2,5-diyl) polymorphs in films spin coated from ferrocene-containing solutions using grazing incident X-ray diffraction. As a result, we found that the addition of ferrocene to casting solutions yields thin-film transistors which exhibit significantly higher source-drain current and charge mobilities than neat polymer devices. Insights gleaned from ferrocene/poly(3-hexylthiophene) mixtures can serve as a template for selection and optimization of next generation small molecule/polymer systems possessing greater baseline charge mobilities. Ultimately, the development of such techniques to enhance the characteristics of organic transistors without imparting high costs or loss of advantageous properties will be a critical factor determining the future of organic components within the electronics market.

LIENAÇÃO PARENTAL E O VÍNCULO DESTRUÍDO

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DA SILVA, T.C

2015-12-01

Full Text Available Quando alienação parental não é feita de forma harmônica e um (ou ambos dos genitores tenta de alguma maneira influenciar a criança negativamente a respeito do outro, colocando em prejuízo a imagem do outro genitor, dá-se a alienação parental. O termo cunhado por Richard Gardner em 1985 considera as consequências que são acarretadas por uma criança que sofre com uma separação litigiosa de seus pais fazendo com que os laços afetivos que a criança tinha com um deles vá se rompendo com o passar do tempo e a imagem que ela tinha de um dos genitores seja distorcida. Este estudo tem como objetivo avaliar a Repercussão Psicológica em Crianças que Sofrem Alienação Parental. Utilizou-se uma pesquisa bibliográfica acerca de pesquisas referentes aos termos empregados e às pesquisas recentes acerca dos prejuízos a médio e longo prazo. Notou-se que com a manipulação dos genitores a médio e longo prazo, contribuem para que alguns efeitos possam surgir, tais como: Depressão crônica, incapacidade de adaptação aos diversos ambientes, transtorno de imagem e identidade, isolamento, desespero, consumo de bebidas alcoólicas e drogas, comportamento hostil, transtornos psiquiátricos e até mesmo suicídios por não suportarem mais tantas intrigas. De acordo com as pesquisas realizadas, notou-se que a Alienação Parental é considerada uma síndrome, onde a criança passa a ter uma certa rejeição mediante ao outro genitor sem que algo concreto tenha sido realizado para a mesma ter essa rejeição. Baseia-se apenas a manipulação do outro genitor em dizer coisas que vão contra ao que realmente possa ter ocorrido e na maculação da imagem deste.

Observation of the Strong Electronic Coupling in Near-Infrared-Absorbing Tetraferrocene aza-Dipyrromethene and aza-BODIPY with Direct Ferrocene-α- and Ferrocene-β-Pyrrole Bonds: Toward Molecular Machinery with Four-Bit Information Storage Capacity.

Science.gov (United States)

Zatsikha, Yuriy V; Holstrom, Cole D; Chanawanno, Kullapa; Osinski, Allen J; Ziegler, Christopher J; Nemykin, Victor N

2017-01-17

The 1,3,7,9-tetraferrocenylazadipyrromethene (3) and the corresponding 1,3,5,7-tetraferrocene aza-BODIPY (4) were prepared via three and four synthetic steps, respectively, starting from ferrocenecarbaldehyde using the chalcone-type synthetic methodology. The novel tetra-iron compounds have ferrocene groups directly attached to both the α- and the β-pyrrolic positions, and the shortest Fe-Fe distance determined by X-ray crystallography for 3 was found to be ∼6.98 Å. These new compounds were characterized by UV-vis, nuclear magnetic resonance, and high-resolution electrospray ionization mass spectrometry methods, while metal-metal couplings in these systems were probed by electro- and spectroelectrochemistry, chemical oxidations, and Mössbauer spectroscopy. Electrochemical data are suggestive of the well-separated stepwise oxidations of all four ferrocene groups in 3 and 4, while spectroelectrochemical and chemical oxidation experiments allowed for characterization of the mixed-valence forms in the target compounds. Intervalence charge-transfer band analyses indicate that the mixed-valence [3] + and [4] + complexes belong to the weakly coupled class II systems in the Robin-Day classification. This interpretation was further supported by Mössbauer spectroscopy in which two individual doublets for Fe(II) and Fe(III) centers were observed in room-temperature experiments for the mixed-valence [3] n+ and [4] n+ species (n = 1-3). The electronic structure, redox properties, and UV-vis spectra of new systems were correlated with Density Functional Theory (DFT) and time-dependent DFT calculations (TDDFT), which are suggestive of a ferrocene-centered highest occupied molecular orbital and chromophore-centered lowest unoccupied molecular orbital in 3 and 4 as well as predominant spin localization at the ferrocene fragment attached to the α-pyrrolic positions in [3] + and [4] + .

The mechanism of mediated oxidation of carboxylates with ferrocene as redox catalyst in absence of grafting effects. An experimental and theoretical approach

International Nuclear Information System (INIS)

Hernández-Muñoz, Lindsay S.; Galano, Annia; Astudillo-Sánchez, Pablo D.; Abu-Omar, Mahdi M.; González, Felipe J.

2014-01-01

Graphical abstract: - Highlights: • The mechanism of mediated oxidation of carboxylates. • Thermodynamics of the mediated Kolbe and Non-Kolbe mechanisms. • The oxidation of acetate and diphenylacetate ions by using ferrocene as redox catalyst. • Simulation and DFT calculations of the mediated oxidation of carboxylates. • Radical and carbocationic pathways in the carboxylate oxidation in acetonitrile. - Abstract: The oxidation of tetrabutylammonium carboxylates by using ferrocene derivatives as redox mediators has been recently used to perform the covalent grafting of carbon surfaces with organic and organometallic groups. Due to the intervention of this surface process, a partial description of the reaction mechanism has only been stated. Therefore, this article concerns about two features of the oxidation of carboxylates mediated by ferrocene. In the first part, it is discussed that in the oxidation of acetate ions by using ferrocene as redox catalyst, the gap between both oxidation potentials is very high, which means that the homogeneous electron transfer between the acetate ion and the electrochemically generated ferrocenium ion is energetically unfavorable. However, by using density functional theory calculations, it has been shown that the whole set of coupled chemical reactions involved either in a Kolbe or Non-Kolbe pathway drive the overall mechanisms towards a thermodynamically favorable situation. In order to avoid the strong covalent grafting process that occurs during the mediated oxidation of acetate ions, the second part of this work deals with the oxidation of tetrabutylammonium diphenylacetate by using ferrocene as a redox mediator in acetonitrile on glassy carbon electrodes. With this carboxylate, no electrode inhibition process occurs and, therefore cyclic voltammetry simulation was done to propose the electrochemical and chemical steps that are present when a carboxylate oxidation is performed in the presence of ferrocene derivatives

Perceived Parental Legitimacy as a Moderator of Parent-Child Communication's Effects on Latina/o Adolescent Substance Use.

Science.gov (United States)

Kam, Jennifer A; Pérez Torres, Debora

2018-06-01

Utilizing primary socialization theory (PST) and longitudinal survey data from 381 Latina/o sixth- through eighth-grade students, we hypothesized that four types of parent anti-substance use messages (i.e., parents' own past substance use, religious beliefs, respect for family, and peer resistance) would discourage Latina/o students' substance use, particularly when the students perceived their parents' anti-substance use messages were legitimate. The results supported moderation. For Latina/o students who thought that their parents' anti-substance use messages were legitimate, many of the anti-substance use messages were negatively related to substance use, but the associations were positive or nonsignificant for Latina/o students who thought that their parents' anti-substance use messages were not legitimate. The findings extend past work on PST and anti-substance use parent-child communication, highlighting the importance of perceived legitimacy and message content.

Socialização parental: adaptação ao Brasil da escala ESPA29 Parental socialization: Brazilian adaptation of the ESPA29 Scale

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Isabel Martínez

2011-01-01

Full Text Available O objetivo deste estudo foi analisar as propriedades psicométricas da versão em português brasileiro da escala de socialização parental ESPA29 (Musitu & García, 2001. Esta escala permite medir os estilos de socialização parental - autoritativo, autoritário, indulgente e negligente - através de duas dimensões independentes da conduta parental, extraídas do uso que os pais fazem das distintas práticas de socialização. Utilizando uma amostra de 2105 adolescentes brasileiros, com idades entre os 10 e os 18 anos, replicou-se a estrutura de dois fatores - Aceitação/Implicação e Severidade/Imposição - que compõem a escala, mediante a análise fatorial exploratória. Para completar o estudo de replicabilidade, levou-se a cabo a análise da estrutura ortogonal de Procusto, comprovando-se que a estrutura era invariante para o pai e para a mãe.The objective of this study was to analyze the psychometric properties of the Brazilian version of the ESPA29 Parental Socialization Scale (Musitu & García, 2001. This scale allows measuring parental styles - authoritative, authoritarian, indulgent, and negligent - by means of two independent dimensions of parental conduct extracted from parents' use of different socialization practices. Using a sample of 2.105 Brazilian adolescents from 10 to 18 years old, the structure of two factors that define the scale - Acceptance/Implication and Strictness/Imposition - has been replicated using an exploratory factorial analysis. In order to complete a proper replication of the ESPA29 scale structure, the analysis of the orthogonal structure of Procrustes was carried out proving that the structure was invariant for the father as well as for the mother.

Water-soluble ferrocene complexes (WFCs) functionalized silica nanospheres for WFC delivery in HepG2 tumor therapy.

Science.gov (United States)

Yan, Saisai; Hu, Fan; Hong, Xia; Shuai, Qi

2018-09-01

Silica-encapsulated nanospheres of water-soluble ferrocene complexes WFCs@SiO 2 and WFCs@SiO 2 @glutaraldehyde (GA) were first synthesized by a facile inverse-microemulsion method. The surface functional groups, particle size, and morphologies of nanospheres were characterized by IR spectra, UV-vis absorption spectra, dynamic light scattering (DLS) and SEM images. Single-crystal X-ray diffraction was used to confirm the molecular structure of free ferrocenyl-pyrazol ligand (L) and three WFCs, namely, [Ni(C 22 H 14 F 6 FeN 4 O 4 )(H 2 O) 4 ] (5a), [Mg(C 22 H 14 F 6 FeN 4 O 4 )(H 2 O) 4 ]·3H 2 O (5b), and [Ba(C 22 H 14 F 6 FeN 4 O 4 )(H 2 O) 3 ] (5c). The electrochemical properties of 5a-5c were explored by cyclic voltammetry. The WFCs-loading capacities of 5a-5c in WFCs@SiO 2 were found to be 38.4, 38.2, and 38.1 μg/mg, respectively. Cell studies under two drug delivery modes (free diffusion and endocytosis) were carried out by MTT cell-survival assays and morphological observation of HepG2 cells. It's interesting that the cytotoxicity of WFCs against HepG2 was increased by applying silica nanocarriers. Compared to WFCs@SiO 2 , the modification of GA on the spherical surface provided not only the better water-dispersity but also additional functional groups for further modification of other pharmacophores. The novel nanocarrier system for WFC delivery present a novel concept-of-proof method to protect varieties of affordable metal-based anticancer agents in physiological conditions and provided experimental basis for future studies focusing on drug delivery of other WFCs. Copyright © 2018 Elsevier B.V. All rights reserved.

Correlation of Spectral and Electrochemical Properties of a Series of Ferrocene Derivatives

Science.gov (United States)

Hepp, Aloysius F.; Wrighton, Mark S.

2016-01-01

Charge-transfer-to-solvent (CTTS) bands are observed in the UV/VIS spectra of a series of ferrocene derivatives (ferrocene; 1,1'-dimethyl; 1,2,3,4,5-pentamethyl; 1,2,3,4,l',2',3',4'-octamethyl; and decamethyl) by the addition of increasing amounts of CCl4 to ethanol solutions. A linear correlation (slope = 8540 cm-1/V) was found between the redox potential and the energy of the CTTS band, consistent with electrochemical and photochemical oxidation by removal of an electron from the same molecular orbital. Inclusion of literature data for ruthenocene and [(?5-C5H5)Fe(CO)]4 results in a line with a slope of 8140 cm-1/V, within 1 percent of the wavenumber to electron volt conversion factor. Calculation of association constants (K) shows a slight decrease (1.2 to 0.7 mole fraction-1) as the bulkiness of the cyclopentadienyl ring increases, consistent with either a steric or a repulsive electronic effect. The extinction coefficient of the CTTS absorption was constant at approximately 1700/M/cm.

Loading of Two Related Metal-Organic Frameworks (MOFs, [Cu2(bdc2(dabco] and [Cu2(ndc2(dabco], with Ferrocene

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Wolfgang Wenzel

2011-09-01

Full Text Available We have studied the loading of two related, similar porous metal-organic frameworks (MOFs [Cu2(bdc2(dabco] (1, and [Cu2(ndc2(dabco] (2 with ferrocene by exposing bulk powder samples to the corresponding vapor. On the basis of powder X-ray diffraction data and molecular dynamics (MD calculations we propose that each pore can store one ferrocene molecule. Despite the rather pronounced similarity of the two MOFs a quite different behavior is observed, for 1 loading with ferrocene leads to an anisotropic 1% contraction, whereas for 2 no deformation is observed. Mössbauer spectroscopy studies reveal that the Fe oxidation level remains unchanged during the process. Time dependent studies reveal that the diffusion constant governing the loading from the gas-phase for 1 is approximately three times larger than the value for 2.

Study of ferrocene dicarboxylic acid on substrates of varying chemical activity

Czech Academy of Sciences Publication Activity Database

Berger, Jan; Kośmider, K.; Stetsovych, Oleksandr; Vondráček, Martin; Hapala, Prokop; Spadafora, Evan; Švec, Martin; Jelínek, Pavel

2016-01-01

Roč. 120, č. 38 (2016), 21955-21961 ISSN 1932-7447 R&D Projects: GA ČR(CZ) GA14-02079S; GA ČR GB14-37427G; GA MŠk(CZ) LG15050; GA MŠk LM2015088 Institutional support: RVO:68378271 Keywords : ferrocene * nc-AFM * DFT * STM * XPS * NEXAFS Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 4.536, year: 2016

Control of Helical Chirality of Ferrocene-Dipeptide Conjugates by the Secondary Structure of Dipeptide Chains.

Science.gov (United States)

Moriuchi, Toshiyuki; Nishiyama, Taiki; Nobu, Masaki; Hirao, Toshikazu

2017-09-18

Controlling helical chirality and creating protein secondary structures in cyclic/acyclic ferrocene-dipeptide bioorganometallic conjugates were achieved by adjusting the conformational flexibility of the dipeptide chains. In systems reported to date, the helical chirality of a conjugate was determined by the absolute configuration of the adjacent amino acid reside. In contrast, it was possible to induce both M- and P-helical chirality, even when the configuration of the adjacent amino acid was the same. It is particularly interesting to note that M-helical chirality was produced in a cyclic ferrocene-dipeptide conjugate composed of the l-Ala-d-Pro-cystamine-d-Pro-l-Ala dipeptide sequence (1), in which a type II β-turn-like secondary structure was established. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Heterogeneous electron transfer kinetics and electrocatalytic behaviour of mixed self-assembled ferrocenes and SWCNT layers

CSIR Research Space (South Africa)

Nkosi, D

2010-01-01

Full Text Available The electron transfer dynamics and electrocatalytic behaviour of ferrocene-terminated self-assembled monolayers (SAMs), co-adsorbed with single-walled carbon nanotubes (SWCNTs) on a gold electrode, have been interrogated for the first time...

Alienação parental e família

OpenAIRE

Brito, Clarissa Moraes

2015-01-01

O trabalho apresentado visa uma detalhada apreciação e análise da Alienação Parental, suas consequências, bem como sua recente tipificação legal no ordenamento jurídico brasileiro, de modo a prevenir conflitos, bem como solucioná-los, uma vez já ocorridos, tendo em vista a proteção da família e da convivência familiar de crianças e adolescentes e seus pais, tecendo ainda alguns comentários acerca da guarda, responsabilidades parentais e alienação parental no...

Alienação parental: uma revisão sistemática da literatura

OpenAIRE

Corrêa, Adalgiza Mara

2016-01-01

A presente revisão sistemática de literatura discorreu sobre a obra de Richard Gardner, o conceito de alienação parental, as intervenções realizadas e a legislação brasileira. Explanou sobre os artigos escritos por Gardner, a procedência ou não das críticas elaboradas quanto à sua teoria, o que já se encontra cientificamente comprovado das afirmações do autor e o que resta inexplorado. Aborda, ainda, os argumentos favoráveis e contrários à inserção da síndrome da alienação parental nos manuai...

C-C bond unsaturation degree in monosubstituted ferrocenes for molecular electronics investigated by a combined near-edge x-ray absorption fine structure, x-ray photoemission spectroscopy, and density functional theory approach

International Nuclear Information System (INIS)

Boccia, A.; Lanzilotto, V.; Marrani, A. G.; Zanoni, R.; Stranges, S.; Alagia, M.; Fronzoni, G.; Decleva, P.

2012-01-01

We present the results of an experimental and theoretical investigation of monosubstituted ethyl-, vinyl-, and ethynyl-ferrocene (EtFC, VFC, and EFC) free molecules, obtained by means of synchrotron-radiation based C 1s photoabsorption (NEXAFS) and photoemission (C 1s XPS) spectroscopies, and density functional theory (DFT) calculations. Such a combined study is aimed at elucidating the role played by the C-C bond unsaturation degree of the substituent on the electronic structure of the ferrocene derivatives. Such substituents are required for molecular chemical anchoring onto relevant surfaces when ferrocenes are used for molecular electronics hybrid devices. The high resolution C 1s NEXAFS spectra exhibit distinctive features that depend on the degree of unsaturation of the hydrocarbon substituent. The theoretical approach to consider the NEXAFS spectrum made of three parts allowed to disentangle the specific contribution of the substituent group to the experimental spectrum as a function of its unsaturation degree. C 1s IEs were derived from the experimental data analysis based on the DFT calculated IE values for the different carbon atoms of the substituent and cyclopentadienyl (Cp) rings. Distinctive trends of chemical shifts were observed for the substituent carbon atoms and the substituted atom of the Cp ring along the series of ferrocenes. The calculated IE pattern was rationalized in terms of initial and final state effects influencing the IE value, with special regard to the different mechanism of electron conjugation between the Cp ring and the substituent, namely the σ/π hyperconjugation in EtFC and the π-conjugation in VFC and EFC.

Improving cytotoxic properties of ferrocenes by incorporation of saturated N-heterocycles

Czech Academy of Sciences Publication Activity Database

Hodík, Tomáš; Lamač, Martin; Červenková Šťastná, Lucie; Cuřínová, Petra; Karban, Jindřich; Skoupilová, H.; Hrstka, R.; Císařová, I.; Gyepes, Robert; Pinkas, Jiří

2017-01-01

Roč. 846, OCT 2017 (2017), s. 141-151 ISSN 0022-328X R&D Projects: GA ČR(CZ) GAP207/12/2368; GA ČR(CZ) GA17-05838S Institutional support: RVO:61388955 ; RVO:67985858 Keywords : metallodrugs * ferrocene derrivatives * N-heterocycles Subject RIV: CF - Physical ; Theoretical Chemistry; CF - Physical ; Theoretical Chemistry (UCHP-M) OBOR OECD: Inorganic and nuclear chemistry; Physical chemistry (UCHP-M) Impact factor: 2.184, year: 2016

Peeling off effects in vertically aligned Fe3C filled carbon nanotubes films grown by pyrolysis of ferrocene

Science.gov (United States)

Boi, Filippo S.; Medranda, Daniel; Ivaturi, Sameera; Wang, Jiayu; Guo, Jian; Lan, Mu; Wen, Jiqiu; Wang, Shanling; He, Yi; Mountjoy, Gavin; Willis, Maureen A. C.; Xiang, Gang

2017-06-01

We report the observation of an unusual self-peeling effect which allows the synthesis of free standing vertically aligned carbon nanotube films filled with large quantities of Fe3C and small quantities of γ-Fe crystals. We demonstrate that this effect depends on the interplay of three main factors: (1) the physical interactions between the chosen substrate surface and grown carbon nanotubes (CNTs), which is fixed by the composition of the used substrate (111 SiO2/Si or quartz), (2) the CNT-CNT Van der Waals interactions, and (3) the differential thermal contraction between the grown CNT film and the used substrate, which is fixed by the cooling rate differences between the grown film and the used quartz or Si/SiO2 substrates. The width and stability of these films are then further increased to cm-scale by addition of small quantities of toluene to the ferrocene precursor.

O "lugar" do filho adotivo na dinâmica parental: revisão integrativa de literatura

OpenAIRE

Morelli, Ana Bárbara; Scorsolini-Comin, Fabio; Santeiro, Tales Vilela

2015-01-01

O estudo objetivou apresentar uma revisão integrativa de literatura acerca do lugar reservado às crianças na dinâmica dos pretendentes à adoção. O espaço destinado à criança no psiquismo parental fornece indícios de como será a interação entre os membros da nova família. Critérios de busca para definição da amostra (N=24): artigos disponíveis nas bases LILACS, SciELO e PePSIC; publicados entre 2002 e 2012; e cruzamento dos unitermos "pais", "casais", "adoção", "fantasia" e "psicanálise". Os r...

Identificação de estilos parentais: o ponto de vista dos pais e dos filhos Parenting style: perceptions of children and their parents

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Lidia Natalia Dobrianskyj Weber

2004-01-01

Full Text Available A fim de explorar os estilos parentais entre famílias brasileiras, 239 crianças (de 9 a 12 anos, de duas escolas municipais de Curitiba e seus respectivos pais responderam a duas escalas de responsividade e exigência parental. Estas escalas, que categorizam quatro estilos parentais, foram adaptadas de adolescentes para crianças e apresentaram índices de consistência interna adequados (alpha entre 0,58 e 0,76. Os pais foram classificados como: 45,4% negligentes, 32,8% autoritativos, 11,8% permissivos e 10,1% autoritários. Embora os pais tenham se percebido como mais responsivos e exigentes do que seus filhos perceberam, a correlação entre as respostas dadas pelas crianças e por seus pais foi significativa e positiva. Além disso, a percepção das crianças, de suas mães, foi correlacionada com a percepção delas de seus pais. As diferenças de percepção dos estilos parentais foram discutidas e as pesquisadoras chamam a atenção para o número muito alto de famílias negligentes observado.In order to explore parenting styles among Brazilian families, 239 children (9-12 yrs old, from two public schools in Curitiba, and their parents answered two scales of parental responsiveness and demandingness. These scales, which categorize four parenting styles, were adapted for use with children (they were originally developed to be anwered by adolescents and showed satisfactory reliability coefficients (alpha between 0,65 and 0,76. Parents were classified as: negligent (45,4%, authoritative (32,8%, indulgent (11,8% and authoritarian (10,1%. Although parents have perceived themselves as being more responsive and demanding when compared to the opinions of their children, the correlation between the answers of parents and children was significant and positive. Additionally, the childrens' perceptions of their mothers correlated with that of their fathers. These differences in perception of parenting styles are discussed and the researchers call

Ferrocene, ruthenocene or rhodocene analogues of Haloperidol. Synthesis and organ distribution after labelling with 103Ru or 103mRh

International Nuclear Information System (INIS)

Wenzel, M.; Wu, Y.

1988-01-01

Ferrocene-Haloperidol was synthesized by N-alkylation of 4-(4'-chlorophenyl)-4-hydroxypiperidine with 1-ferrocenyl-4-chlor-butan-1-on. By heating the ferrocene-haloperidol with 103 RuCl 3 the 103 Ru-labelled ruthenocene-haloperidol was obtained. This compound showed a high affinity for lung but not for brain in rats and mice. The decay of the 103 Ru labelled compound results in the formation of the 103m Rh labelled rhodocene-haloperidol, which is rapidly oxidized by air to the corresponding rhodocinium-haloperidol. This compound can be separated by extraction and TLC. (author)

Oxidation of ferrocene by thiocyanic acid in the presence of ammonium oxalate

Science.gov (United States)

Ruslin, Farah bt; Yamin, Bohari M.

2014-09-01

A flake-like crystalline salt was obtained from the reaction of ferrocene, oxalic acid and ammonium thiocyanate in ethanol The elemental analysis and spectroscopic data were in agreement with the preliminary X-ray molecular structure. The compound consists of four ferrocenium moieties and a counter anion consisting of two (tetraisothiocyanato)iron(III) linked by an oxalato bridging group in such a way that both iron central atoms adopt octahedral geometries.

Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5

Czech Academy of Sciences Publication Activity Database

Vitvarová, Dana; Voláková, Martina; Vlk, Josef; Vinu, A.; Štěpnička, P.; Čejka, Jiří

2010-01-01

Roč. 16, č. 26 (2010), s. 7773-7780 ISSN 0947-6539 R&D Projects: GA ČR GA104/07/0383; GA ČR GD203/08/H032 Institutional research plan: CEZ:AV0Z40400503 Keywords : acylation * aluminum * ferrocene Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 5.476, year: 2010

Effect of surface area of substrates aiming the optimization of carbon nanotube production from ferrocene

International Nuclear Information System (INIS)

Osorio, A.G.; Bergmann, C.P.

2013-01-01

Highlights: ► An optimized synthesis of CNTs by ferrocene is proposed. ► The surface area of substrates influences the nucleation of CNTs. ► The higher the surface area of substrates the lower the temperature of synthesis. ► Chemical composition of substrates has no influence on the growth of CNTs. - Abstract: Ferrocene is widely used for the synthesis of carbon nanotubes due to its ability to act as catalyst and precursor of the synthesis. This paper proposes an optimization of the synthesis of carbon nanotubes from ferrocene, using a substrate with high surface area for their nucleation. Four different surface areas of silica powder were tested: 0.5, 50, 200 and 300 m 2 /g. Raman spectroscopy and microscopy were used to characterize the product obtained and X-ray diffraction and thermal analysis were also performed to evaluate the phases of the material. It was observed that the silica powder with the highest surface area allowed the synthesis of carbon nanotubes to occur at a lower temperature (600 °C), whereas substrates with a surface area lower than 50 m 2 /g will only form carbon nanotubes at temperatures higher than 750 °C. In order to evaluate the influence of chemical composition of the substrate, three different ceramic powders were analyzed: alumina, silica and zirconia. carbon black and previously synthesized carbon nanotubes were also used as substrate for the synthesis and the results showed that the chemical composition of the substrate does not play a relevant role in the synthesis of carbon nanotubes, only the surface area showed an influence.

Zethrenes, Extended p -Quinodimethanes, and Periacenes with a Singlet Biradical Ground State

KAUST Repository

Sun, Zhe

2014-08-19

ConspectusResearchers have studied polycyclic aromatic hydrocarbons (PAHs) for more than 100 years, and most PAHs in the neutral state reported so far have a closed-shell electronic configuration in the ground state. However, recent studies have revealed that specific types of polycyclic hydrocarbons (PHs) could have a singlet biradical ground state and exhibit unique electronic, optical, and magnetic activities. With the appropriate stabilization, these new compounds could prove useful as molecular materials for organic electronics, nonlinear optics, organic spintronics, organic photovoltaics, and energy storage devices. However, before researchers can use these materials to design new devices, they need better methods to synthesize these molecules and a better understanding of the fundamental relationship between the structure and biradical character of these compounds and their physical properties. Their biradical character makes these compounds difficult to synthesize. These compounds are also challenging to physically characterize and require the use of various experimental techniques and theoretic methods to comprehensively describe their unique properties.In this Account, we will discuss the chemistry and physics of three types of PHs with a significant singlet biradical character, primarily developed in our group. These structures are zethrenes, Z-shaped quinoidal hydrocarbons; hydrocarbons that include a proaromatic extended p-quinodimethane unit; and periacenes, acenes fused in a peri-Arrangement. We used a variety of synthetic methods to prepare these compounds and stabilized them using both thermodynamic and kinetic approaches. We probed their ground-state structures by electronic absorption, NMR, ESR, SQUID, Raman spectroscopy, and X-ray crystallography and also performed density functional theory calculations. We investigated the physical properties of these PHs using various experimental methods such as one-photon absorption, two-photon absorption

Abuso físico infantil: analisando o estresse parental e o apoio social

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Lílian Paula D. Bérgamo

Full Text Available Verificou-se se o estresse parental e o apoio social relacionar-se-iam ao abuso físico infantil, comparando-se G1 - cuidadores notificados por abusos, e G2 - não-agressores. Utilizou-se um Questionário de caracterização socio-demográfica e econômica e um sobre Apoio Social e o Índice de Estresse Parental. Obteve-se diferença significativa no escore geral de estresse e na dimensão Criança Difícil, com G1 vivenciando mais estresse. Ademais, G1 apresentou menor nível de apoio, no geral e nas dimensões Afetiva e de Interação Social Positiva. G1 também relatou menos satisfação com o bairro de residência e, em média, era mais jovem quando do nascimento do primeiro filho. Essas variáveis devem receber investimentos em programas de prevenção e de tratamento dirigidos a tal problemática.

Síndrome de alienação parental: da teoria Norte-Americana à nova lei brasileira

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Analícia Martins de Sousa

Full Text Available A síndrome de alienação parental (SAP foi definida, na década de 1980, pelo psiquiatra norteamericano Richard Gardner, como um distúrbio infantil que acometeria crianças e adolescentes envolvidos em situações de disputa de guarda entre os pais. Na visão do autor, a síndrome se desenvolve a partir de programação ou lavagem cerebral realizada por um genitor - nomeado como alienador - para que a criança rejeite o outro responsável. No Brasil, após rápida tramitação no Legislativo, foi sancionada, em agosto de 2010, lei sobre a alienação parental, que prevê sanções ao genitor que causar impedimentos à convivência do(s filho(s com o outro responsável. A nova lei traz determinações quanto à atuação de psicólogos no exame de supostos casos de alienação parental, destacando também os aspectos emocionais observados em tais situações. No presente artigo, tem-se como proposta examinar - à luz dos conhecimentos da Psicologia - os argumentos, ligados a essa área, que fundamentaram a exposição de motivos do projeto de lei sobre a alienação parental, explanando-se também as decisões judiciais proferidas em diferentes países que tomaram por base esse conceito.

Evaluation of a Blog Based Parent Involvement Approach by Parents

Science.gov (United States)

Ozcinar, Zehra; Ekizoglu, Nihat

2013-01-01

Despite the well-known benefits of parent involvement in children's education, research clearly shows that it is difficult to effectively involve parents. This study aims to capture parents' views of a Blog Based Parent Involvement Approach (BPIA) designed to secure parent involvement in education by strengthening school-parent communication. Data…

Adaptação transcultural para o português brasileiro do Parental Bonding Instrument (PBI Cross-cultural adaptation of Parental Bonding Instrument (PBI to Brazilian Portuguese

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Simone Hauck

2006-08-01

Full Text Available OBJETIVO: O artigo apresenta a adaptação transcultural do Parental Bonding Instrument, um questionário auto-aplicável desenvolvido em 1979 e usado desde então para avaliar a percepção da qualidade do vínculo com os pais até os 16 anos. MÉTODO: Foram realizadas as etapas de equivalência conceitual, equivalência dos itens, equivalência semântica, equivalência operacional, equivalência funcional e aprovação da versão final pelo autor original do instrumento. RESULTADOS: Os critérios de equivalência foram satisfeitos, tendo a versão final sido aprovada pelo autor do instrumento original. CONCLUSÃO: A adaptação do Parental Bonding Instrument disponibiliza para uso um instrumento que já demonstrou ser extremamente útil em pesquisas de risco e resiliência nas últimas décadas, ao avaliar a percepção de características do comportamento dos pais tradicionalmente associadas ao desenvolvimento da personalidade.OBJETIVE: This article aims to present a cross-cultural adaptation of the Parental Bonding Instrument to Brazilian Portuguese. It is a self-administered questionnaire developed in 1979, which has been used since then to measure the subjective experience of being parented to the age of 16 years. METHOD: The following steps were performed: conceptual equivalence, item equivalence, semantic equivalence, operational equivalence, functional equivalence, and approval of the final version by the author of the original instrument. RESULTS: The study has reached the objectives of equivalence, and the final Brazilian Portuguese version has been approved by the original author. CONCLUSION: The study provides a Brazilian Portuguese version of an instrument that has been proven extremely useful in risk and resilience researches over the past decades, assessing the perception of parental characteristics traditionally related to personality development.

Twisting and Tilting 1,1 '-Bis(dialkylphosphino)ferrocene Bound to Low Valent Tricarbonylmaganese(I to -I)

Czech Academy of Sciences Publication Activity Database

Schäfer, K. M.; Reinders, L.; Fiedler, Jan; Ringenberg, M. R.

2017-01-01

Roč. 56, č. 23 (2017), s. 14688-14696 ISSN 0020-1669 Institutional support: RVO:61388955 Keywords : 1,1´-Bis(dialkylphosphino)ferrocene DPPF * metal-metal bonds * Fe interactions Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 4.857, year: 2016

SÍNDROME DA ALIENAÇÃO PARENTAL: O ABUSO PSICOLÓGICO RESULTANTE DA IMPLANTAÇÃO DE FALSAS MEMÓRIAS

OpenAIRE

Nascimento, Bianca Souto do; UFPB; Costa, Rafaelle Braga Vasconcelos; UFPB

2014-01-01

A Síndrome da Alienação Parental é um tema relativamente novo no âmbito do Direito, embora presente na sociedade há muito tempo. Envolvendo o psicológico dos pais e filhos, seu estudo apresenta-se como de extrema importância para o desenvolvimento familiar saudável e, consequentemente, para o futuro da sociedade. Mediante o exame do posicionamento de profissionais de diferentes áreas e a análise de alguns casos, pudemos entender a gravidade da situação de alienação parental: uma criança/adole...

Ferrocene-based diradicals of imino nitroxide, nitronyl nitroxide and verdazyl, and their cations are possible SMM: A quantum chemical study

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Pal, Arun K.; Datta, Sambhu N.

2017-05-01

Six diradicals designed from imino nitroxide, verdazyl and nitronyl nitroxide monoradicals coupled via the ferrocene moiety and six corresponding triradical cations are quantum chemically investigated. The transoid conformation is employed for considerations of general stability. All biradicals are found as very weakly and antiferromagnetically coupled. This agrees with experiment. The cations have strong antiferromagnetic spin-coupling. The charge and spin population distributions, spin alternation pattern, and the disjoint nature of SOMOs can be used to explain the nature and extent of magnetic interaction. Calculated EPR characteristics identify the neutral species as well as their cations as possible single molecule magnets.

Crystal structure of cyclic tris(ferrocene-1,1′-diyl

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Ruslan Shekurov

2014-09-01

Full Text Available The molecular structure of the trinuclear title compound, [Fe3(C10H83] {systematic name: tris[μ-(η5:η5-1,1′-bicyclopentadienyl]triiron(II}, consists of three ferrocene subunits (each with an eclipsed conformation that are condensed via C—C bonds of the fulvalene moieties into a cyclic trimer. The angles between the planes of the cyclopentadienyl (Cp rings within the three fulvalene moieties are 76.1 (3, 80.9 (3 and 81.7 (3°. In the crystal, C—H...π interactions between neighbouring molecules lead to the cohesion of the structure.

Tradução e adaptação brasileira do Parental-Caregiver Perceptions Questionnaire (P-CPQ Translation and brazilian adaptation of the Parental-Caregiver Perceptions Questionnaire (P-CPQ

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Taís de Souza Barbosa

2010-09-01

Full Text Available O objetivo deste estudo foi traduzir o instrumento Parental-Caregiver Perceptions Questionnaire (P-CPQ para a língua portuguesa do Brasil e realizar a adaptação cultural para aplicação na população de pais brasileiros. A tradução obedeceu às etapas de tradução, tradução reversa e revisão por um comitê de especialistas. No pré-teste, uma amostra de 20 pais respondeu ao questionário para avaliar os erros e desvios das traduções. Além disso, foi acrescentada a cada questão a alternativa "não entendi" para identificar questões que não fossem compreendidas pelos pais, isto é, consideradas culturalmente inadequadas. Os achados sugerem adequação do processo de adaptação cultural do instrumento para a língua portuguesa. No pré-teste, 20 indivíduos responderam ao questionário e apresentaram uma boa compreensão do instrumento, uma vez que nenhuma questão foi considerada incompreensível por 15% ou mais dos pais. A versão em português do P-CPQ mostrou ser de fácil compreensão pela população de pais brasileiros.The aim of this study was to translate the Parental-Caregiver Perceptions Questionnaire (P-CPQ into Brazilian Portuguese and to make the necessary cultural adaptations for use in the Brazilian parent population. The whole translation process consisted of translation, back-translation and committee review. In the pre-testing stage, a sample of 20 parents answered the questionnaire in order to check for errors and deviations in the translations. Furthermore, in each question the alternative "I didn't understand" was added to identify the questions that were not understood by the parents, i.e. questions considered culturally inappropriate. The findings suggested that the instrument is adequate to the Portuguese language and to the Brazilian cultural identity. In the pre-testing stage, 20 subjects answered the questionnaire and showed good understanding of the instrument, since no question was considered

Immobilization of Glucose Oxidase on a Carbon Nanotubes/Dendrimer-Ferrocene Modified Electrode for Reagentless Glucose Biosensing.

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Zhou, Juan; Li, Huan; Yang, Huasong; Cheng, Hui; Lai, Guosong

2017-01-01

Ferrocene-grafted dendrimer was covalently linked to the surface of a carbon nanotubes (CNTs)-chitosan (CS) nanocomposite modified electrode for immobilizing high-content glucose oxidase (GOx), which resulted in the successful development a novel reagentless glucose biosensor. Electrochemical impedance spectroscopy, cyclic voltammetry, and amperometry were used to characterize the preparation process and the enzymatically catalytic response of this biosensor. Due to the excellent electron transfer acceleration of the CNTs and the high-content loading of the GOx biomolecule and ferrocene mediator on the electrode matrix, this biosensor showed excellent analytical performance such as fast response time less than 10 s, wide linear range from 0.02 to 2.91 mM and low detection limit down to 7.5 μM as well as satisfactory stability and reproducibility toward the amperometric glucose determination. In addition, satisfactory result was obtained when it was used for the glucose measurements in human blood samples. Thus this biosensor provides great potentials for practical applications.

Crystal structure of bis[4-(1H-pyrrol-1-ylphenyl] ferrocene-1,1′-dicarboxylate: a potential chemotherapeutic drug

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Wanda I. Pérez

2015-05-01

Full Text Available The title iron(II complex, [Fe(C16H12NO22], crystallizes in the orthorhombic space group Pbca with the Fe2+ cation positioned on an inversion center. The cyclopentadienyl (Cp rings adopt an anti conformation in contrast with other substituted ferrocenes in which the Cp rings appear in a nearly eclipsed conformation. The Cp and the aromatic rings are positioned out of the plane, with a twist angle of 70.20 (12°, and the C(Cp—C(CO bond length is shorter than a typical C—C single bond, which suggests a partial double-bond character and delocalization with the Cp π system. The structure of the complex is compared to other functionalized ferrocenes synthesized in our laboratory.

A new approach to ferrocene derived alkenes via copper-catalyzed olefination.

Science.gov (United States)

Muzalevskiy, Vasily M; Shastin, Aleksei V; Demidovich, Alexandra D; Shikhaliev, Namiq G; Magerramov, Abel M; Khrustalev, Victor N; Rakhimov, Rustem D; Vatsadze, Sergey Z; Nenajdenko, Valentine G

2015-01-01

A new approach to ferrocenyl haloalkenes and bis-alkenes was elaborated. The key procedure involves copper catalyzed olefination of N-unsubstituted hydrazones, obtained from ferrocene-containing carbonyl compounds and hydrazine, with polyhaloalkanes. The procedure is simple, cheap and could be applied for the utilization of environmentally harmful polyhalocarbons. The cyclic voltammetry study of the representative examples of the synthesized ferrocenyl alkenes shows the strong dependence of the cathodic behavior on the amount of vinyl groups: while for the monoalkene containing molecules no reduction is seen, the divinyl products are reduced in several steps.

Web-Based Parenting Support: Development of the COPING Confident Parenting Programme

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Judith Hutchings

2018-04-01

Full Text Available Parents have the most significant impact on children’s development and the key parenting factors that promote child development and wellbeing are well known. Furthermore, many behavioural, social and emotional problems in children are associated with poor parenting practices. Parenting interventions that address parental skill deficits and teach positive parenting principles based on social learning theory are effective and are the recommended treatment for conduct disorder. Alongside the development of treatment programmes, universal parenting programmes have been developed; many present the same core parenting principles but their rationales vary from promoting children’s development to addressing common behavioural challenges and the evidence for these programmes is less well established. Most parents now have internet access and are making daily use of it, including seeking advice on parenting matters but that advice is often anecdotal and lacking evidence. In the meantime, a small number of web-based programmes, including parenting programmes have been developed and evaluated. This paper summarises the rationale for web-based universal programmes to support parents and briefly describes the history, content and a summary of the initial research on the COPING (confident parent internet guide programme developed by the authors. The paper concludes with suggestions for future research directions.

Ferrocene, ruthenocene or rhodocene analogues of Haloperidol. Synthesis and organ distribution after labelling with /sup 103/Ru or /sup 103m/Rh

Energy Technology Data Exchange (ETDEWEB)

Wenzel, M; Wu, Y

1988-01-01

Ferrocene-Haloperidol was synthesized by N-alkylation of 4-(4'-chlorophenyl)-4-hydroxypiperidine with 1-ferrocenyl-4-chlor-butan-1-on. By heating the ferrocene-haloperidol with /sup 103/RuCl/sub 3/ the /sup 103/Ru-labelled ruthenocene-haloperidol was obtained. This compound showed a high affinity for lung but not for brain in rats and mice. The decay of the /sup 103/Ru labelled compound results in the formation of the /sup 103m/Rh labelled rhodocene-haloperidol, which is rapidly oxidized by air to the corresponding rhodocinium-haloperidol. This compound can be separated by extraction and TLC.

O PAPEL DO MEDIADOR NA IDENTIFICAÇÃO E COMBATE À SÍNDROME DE ALIENAÇÃO PARENTAL

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Henata Mariana de Oliveira Mazzoni

2013-12-01

Full Text Available O presente estudo se propõe, através de uma apreciação crítica, baseada em pesquisa bibliográfica, a analisar como o mediador familiar pode identificar e atuar durante a mediação familiar no combate à Síndrome de Alienação Parental. O processo de divórcio é sempre muito difícil e, mesmo quando consensual acaba gerando sofrimento  principalmente nos filhos. Muitos genitores inconformados com o fim do relacionamento ou com a nova união do ex companheiro, acabam convencendo os filhos contra o outro genitor despertando na criança sentimentos de ódio e o afastamento do genitor. A mediação familiar dá a oportunidade de um casal em processo de divórcio refletir, dialogar e se responsabilizar pela situação dos filhos após o fim do relacionamento e o mediador, ao identificar os sinais da Síndrome de Alienação Parental durante a mediação, pode minimizar os danos

Effect of ferrocene-substituted porphyrin RL-91 on Candida albicans biofilm formation.

Science.gov (United States)

Lippert, Rainer; Vojnovic, Sandra; Mitrovic, Aleksandra; Jux, Norbert; Ivanović-Burmazović, Ivana; Vasiljevic, Branka; Stankovic, Nada

2014-08-01

Ferrocene-substituted porphyrin RL-91 exhibits antifungal activity against opportune human pathogen Candida albicans. RL-91 efficiently inhibits growth of both planktonic C. albicans cells and cells within biofilms without photoactivation. The minimal inhibitory concentration for plankton form (PMIC) was established to be 100 μg/mL and the same concentration killed 80% of sessile cells in the mature biofilm (SMIC80). Furthermore PMIC of RL-91 efficiently prevents C. albicans biofilm formation. RL-91 is cytotoxic for human fibroblasts in vitro in concentration of 10 μg/mL, however it does not cause hemolysis in concentrations of up to 50 μg/mL. These findings open possibility for application of RL-91 as an antifungal agent for external antibiofilm treatment of medical devices as well as a scaffold for further development of porphyrin based systemic antifungals. Copyright © 2014 Elsevier Ltd. All rights reserved.

Electrochemical Studies of Interactions Between Fe(II/Fe(III and Amino Acids Using Ferrocene-Modified Carbon Paste Electrode

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Vatrál Jaroslav

2014-12-01

Full Text Available The electrochemical behavior of an Fe(II/Fe(III redox couple in the presence of various selected amino acids has been studied using ferrocene-modified carbon paste electrode at pH = 7.4. Because of Fe(II/Fe(III solubility issues at physiological pH, ferrocene was used as a source of iron. Anodic oxidation of iron (pH = 7.2 occurred at 0.356 V and cathodic oxidation at 0.231 V, both vs Ag|AgCl. Treatment of the voltammetric data showed that it was a purely diffusion-controlled reaction with the involvement of one electron. After addition of amino acids, potential shifts and current changes can be observed on the voltammograms. Cyclic voltammetry experiments revealed the capability of amino acids to change the electrochemical behavior of the Fe(II/Fe(III redox couple.

Atitudes parentais em relação à educação inclusiva Parental attitudes toward inclusive education

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Altemir José Gonçalves Barbosa

2007-12-01

Full Text Available Com o objetivo de descrever as atitudes parentais em relação à inclusão escolar, 445 pais de alunos de primeira à quarta série do ensino fundamental de duas escolas municipais da cidade de São Paulo, responderam um questionário e uma escala de atitudes tipo Likert denominada Inventário Geral de Atitudes quanto à Educação Inclusiva (IGAEI. Participaram do estudo 169 (37,98% pais de alunos com necessidades educacionais especiais em processo de inclusão (G1 e 276 (62,02% progenitores de discentes que, de acordo com as instituições, não possuíam tal característica (G2. Os instrumentos foram aplicados coletivamente em reunião de pais e mestres com resposta individual. Os resultados obtidos revelam que ambos os grupos de pais tendiam a possuir atitudes favoráveis em relação à educação inclusiva. Porém, as atitudes dos pais de estudantes com necessidades educacionais especiais eram mais favoráveis à inclusão. São apresentados, ainda, resultados referentes a outras variáveis pesquisadas, como, por exemplo, tipos de necessidades educacionais em processo de inclusão. O estudo tende a corroborar resultados obtidos em pesquisas realizadas em outros países, ainda que algumas discrepâncias tenham sido percebidas. Conclui-se enfatizando a necessidade de mais pesquisas sobre o tema no contexto brasileiro e ressaltando a importância dos pais no desenvolvimento de sistemas educacionais inclusivos.In order to describe parental attitudes toward school inclusion, 445 parents of elementary school students from first to fourth grade of two municipal schools of the city of São Paulo answered a questionnaire and the Likert scale General Inventory of Attitudes toward Inclusive Education (IGAEI for assessing attitudes. The participants were 169 (37,98% parents of students with special educational needs included in regular schools (G1 and 276 (62,02% parents of students the school directors said did not have special needs (G2. The

Parental attachment style: examination of links with parent secure base provision and adolescent secure base use.

Science.gov (United States)

Jones, Jason D; Cassidy, Jude

2014-01-01

The secure base construct represents one of attachment theory's most important contributions to our understanding of parent-child relationships and child development. The present study represents the first examination of how parents' self-reported attachment styles relate to parental secure base provision and adolescent (mean age = 16.6 years, SE = .59) secure base use during an observed parent-adolescent interaction. Further, the present study is the first to examine how fathers', as well as mothers', attachment styles relate to observed behavior in a parent-child interaction. At the bivariate level, maternal avoidance, but not anxiety, was negatively associated with observed adolescent secure base use. In addition, path analysis revealed that maternal avoidance was indirectly related to less adolescent secure base use through mothers' self-reported hostile behavior toward their adolescents and through adolescents' less positive perceptions of their mothers. Further, paternal anxiety, but not avoidance, was indirectly related to less adolescent secure base use through fathers' self-reported hostile behavior toward their adolescents. No significant findings emerged in relation to parental secure base provision. We discuss these results in the context of attachment theory and suggest directions for future research.

ALIENAÇÃO PARENTAL E SUAS CONSEQUÊNCIAS JURÍDICAS

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Suellen Fernanda Portela

2017-02-01

Full Text Available O objetivo deste trabalho é analisar as consequências jurídicas advindas com a prática da Alienação Parental. A lei 12.318/2010 foi criada com o fim de garantir à criança e ao adolescente um desenvolvimento saudável em uma família devidamente estruturada, prevendo “punições” àquele que abusar do seu poder familiar ou influência sobre a criança, implantando falsas memórias sobre qualquer dos genitores, vindo a praticar com isso, o cada dia mais conhecido ato de Alienação Parental. O texto conduz a uma análise das consequências trazidas nos incisos do artigo 6º dessa lei como forma de conscientização da gravidade desse ato e como a lei se incumbe de apresentar meios inibidores para o mesmo.

Alienação parental e relações escolares: a atuação do psicólogo

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Jéssica Alves de Jesus

Full Text Available Resumo O presente artigo aborda os efeitos da Alienação Parental nas relações que se manifestam no contexto escolar entre pais e filhos e identifica quais são as contribuições do Psicólogo Escolar para lidar com esse cenário. Para tanto, faz-se necessária uma exposição acerca de três principais eixos que se articulam sobre a questão, abordados por meio de uma revisão bibliográfica: as definições acerca de alienação parental, as atribuições da escola e família e as possibilidades de atuação do psicólogo escolar. Nesse contexto, conclui-se que as três instâncias têm importante papel na minimização dos efeitos da Síndrome de Alienação Parental vivenciada por algumas crianças. Entretanto, evidencia-se escassa literatura relacionada às possíveis correlações entre a alienação parental e seus efeitos concretos no ambiente escolar, caracterizando-se como um desafio para os profissionais que se deparam com contexto semelhante ao abordado neste artigo.

A new approach to ferrocene derived alkenes via copper-catalyzed olefination

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Vasily M. Muzalevskiy

2015-11-01

Full Text Available A new approach to ferrocenyl haloalkenes and bis-alkenes was elaborated. The key procedure involves copper catalyzed olefination of N-unsubstituted hydrazones, obtained from ferrocene-containing carbonyl compounds and hydrazine, with polyhaloalkanes. The procedure is simple, cheap and could be applied for the utilization of environmentally harmful polyhalocarbons. The cyclic voltammetry study of the representative examples of the synthesized ferrocenyl alkenes shows the strong dependence of the cathodic behavior on the amount of vinyl groups: while for the monoalkene containing molecules no reduction is seen, the divinyl products are reduced in several steps.

Ferrocene and cobaltocene derivatives for non-aqueous redox flow batteries.

Science.gov (United States)

Hwang, Byunghyun; Park, Min-Sik; Kim, Ketack

2015-01-01

Ferrocene and cobaltocene and their derivatives are studied as new redox materials for redox flow cells. Their high reaction rates and moderate solubility are attractive properties for their use as active materials. The cyclability experiments are carried out in a static cell; the results showed that these materials exhibit stable capacity retention and predictable discharge potentials, which agree with the potential values from the cyclic voltammograms. The diffusion coefficients of these materials are 2 to 7 times higher than those of other non-aqueous materials such as vanadium acetylacetonate, iron tris(2,2'-bipyridine) complexes, and an organic benzene derivative. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Study of TiO{sub 2} nanomembranes obtained by an induction heated MOCVD reactor

Energy Technology Data Exchange (ETDEWEB)

Crisbasan, A., E-mail: andreea.crisbasan@yahoo.com [NANOFORM Group, ICB, Université de Bourgogne, BP 47 870, 21078 Dijon (France); Chaumont, D. [NANOFORM Group, ICB, Université de Bourgogne, BP 47 870, 21078 Dijon (France); Sacilotti, M. [NANOFORM Group, ICB, Université de Bourgogne, BP 47 870, 21078 Dijon (France); Departamento de Fisica – Universidade Federal de Pernambuco, Recife (Brazil); Crisan, A.; Lazar, A.M.; Ciobanu, I. [Science and Materials Engineering Faculty, University of Transilvania, Brasov (Romania); Lacroute, Y.; Chassagnon, R. [Université de Bourgogne, BP 47 870, 21078 Dijon (France)

2015-12-15

Highlights: • The TiO{sub 2} structures have been obtained by the MOCVD technique using ferrocene, cobalt layer (annealed at 350 °C) and Ti(OC{sub 3}H{sub 7}){sub 4}. • The TiO{sub 2} growth at 550 °C, during 20 min on the cobalt layer (obtained by electron beam evaporation method) on soda-lime glass has as result TiO{sub 2} nanomembranes. • The TiO{sub 2} nanomembranes grow on the cobalt nuclei. • The TiO{sub 2} nanomembranes are polycrystalline, built from TiO{sub 2} anatase and rutile crystals. - Abstract: Nanostructures of TiO{sub 2} were grown using the metal oxide chemical vapor deposition (MOCVD) technique. The procedure used induction heating on a graphite susceptor. This specific feature and the use of cobalt and ferrocene catalysts resulted in nanomembranes never obtained by common MOCVD reactors. The present study discusses the preparation of TiO{sub 2} nanomembranes and the dependence of nanomembrane structure and morphology on growth parameters.

Feasibility of Internet-based Parent Training for Low-income Parents of Young Children.

Science.gov (United States)

McGoron, Lucy; Hvizdos, Erica; Bocknek, Erika L; Montgomery, Erica; Ondersma, Steven J

2018-01-01

Parent training programs promote positive parenting and benefit low-income children, but are rarely used. Internet-based delivery may help expand the reach of parent training programs, although feasibility among low-income populations is still unclear. We examined the feasibility of internet-based parent training, in terms of internet access/use and engagement, through two studies. In Study 1, 160 parents recruited from Women, Infants, and Children (WIC) centers completed a brief paper survey regarding internet access and use (all parents received government aid). We found high levels of access, openness, and comfort with the internet and internet-enabled devices. In Study 2, a pilot study, we assessed use of an online parenting program in a project with a sample of 89 predominately low-income parents (75% received government aid). Parents learned about a new, online parenting program (the "5-a-Day Parenting Program") and provided ratings of level of interest and program use 2-weeks and 4-weeks later. Local website traffic was also monitored. At baseline, parents were very interested in using the web-based program, and the majority of parents (69.6%) reported visiting the website at least once. However, in-depth use was rare (only 9% of parents reported frequent use of the online program). Results support the feasibility of internet-based parent training for low-income parents, as most parent were able to use the program and were interested in doing so. However, results also suggest the need to develop strategies to promote in-depth program use.

Covalent functionalization of few-wall carbon nanotubes by ferrocene derivatives for bioelectrochemical devices

Energy Technology Data Exchange (ETDEWEB)

Allali, Naoual [Laboratoire de Chimie Physique et Microbiologie pour l' Environnement, UMR 7564 CNRS-Universite de Lorraine, 54602 Villers-les-Nancy (France); Laboratoire de Structure et Reactivite des Systemes Moleculaires Complexes, UMR 7565 CNRS-Universite de Lorraine, 54506 Vandoeuvre-les-Nancy (France); Department of Engineering Sciences and Mathematics, Luleaa University of Technology, 97187 Luleaa (Sweden); Urbanova, Veronika; Waldbock, Jeremy; Etienne, Mathieu; Mallet, Martine; Walcarius, Alain; Dossot, Manuel [Laboratoire de Chimie Physique et Microbiologie pour l' Environnement, UMR 7564 CNRS-Universite de Lorraine, 54602 Villers-les-Nancy (France); Mamane, Victor; Fort, Yves [Laboratoire de Structure et Reactivite des Systemes Moleculaires Complexes, UMR 7565 CNRS-Universite de Lorraine, 54506 Vandoeuvre-les-Nancy (France); Devaux, Xavier [Insitut Jean Lamour, Department P2M, UMR 7198 CNRS-Universite de Lorraine, Ecole des Mines, 54042 Nancy (France); Vigolo, Brigitte; McRae, Edward [Insitut Jean Lamour, Department CP2S, UMR 7198 CNRS-Universite de Lorraine, 54506 Vandoeuvre-les-Nancy (France); Noel, Maxime [Department of Engineering Sciences and Mathematics, Luleaa University of Technology, 97187 Luleaa (Sweden); Soldatov, Alexander V. [Department of Engineering Sciences and Mathematics, Luleaa University of Technology, 97187 Luleaa (Sweden); Department of Physics, Harvard University, Cambridge, MA 02138 (United States)

2012-12-15

The present work reports the covalent functionalization of few-wall CNTs (FWCNTs) by ferrocene derivatives to (i) improve their dispersion efficiency in water and (ii) graft electroactive chemical groups on their side-walls in order to promote electron transfer to biomolecules. The functionalized CNTs (f-CNTs) are used to modify a glassy carbon electrode and this modified electrode is used for oxidizing the cofactor NADH (dihydronicotinamide adenine dinucleotide). (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

ENVOLVIMENTO PARENTAL NA PARTICIPAÇÃO DESPORTIVA DAS CRIANÇAS

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João Serrano

2015-04-01

Full Text Available Diferentes autores têm mostrado algum consenso sobre a participação de pais e mães no desporto dos filhos, referindo que se podem apresentar como uma fonte de apoio, mas também de pressão. Os fatores referidos variam de acordo com os diferentes tipos de participação dos pais.Aroni, (2011 refere que o envolvimento parental no desporto é determinante no processo de formação desportiva dos jovens desportistas, exercendo os pais uma grande influência nas atividades dos filhos. O seu apoio para o alcance de objetivos propostos e de resultados na carreira desportiva são essenciais, mas muitas vezes estão relacionados às crenças e perceções de sucesso que eles (pais tiveram no passado, quando praticaram o mesmo desporto ou foram ex-atletas. Carr, Weigand e Jones (2000, referem que os pais influenciam os filhos quando expõem as razões que levam ao sucesso e como devem agir para alcançar tais objetivos.Objetivo: Conhecer a opinião das crianças sobre o envolvimento parental na sua prática de Futebol.

Ferrocene-based guanidine derivatives: in vitro antimicrobial, DNA binding and docking supported urease inhibition studies.

Science.gov (United States)

Gul, Rukhsana; Rauf, Muhammad Khawar; Badshah, Amin; Azam, Syed Sikander; Tahir, Muhammad Nawaz; Khan, Azim

2014-10-06

Some novel ferrocenyl guanidines 1-8 were synthesized and characterized by different spectroscopic methods, elemental analysis and single crystal X-rays diffraction techniques. The crystallographic studies revealed that the existence of the strong non-bonding interactions facilitate these molecules to interact with biological macro-molecules like DNA that described to inherit good biological activities. The DNA interaction studies carried out by cyclic voltammetry (CV) and UV-visible spectroscopy are in close agreement with the binding constants (K) (0.79-5.4) × 10(5) (CV) and (0.72-5.1) × 10(5) (UV-vis). The shift in peak potential, current and absorption maxima of the studied ferrocenyl guanidines in the presence of DNA revealed that CV coupled with UV-vis spectroscopy could provide an opportune to characterize metal-based compounds-DNA interaction mechanism, a prerequisite for the design of new anticancer agents and understanding the molecular basis of their action. The compounds 1-8 have been screened for their antibacterial, antifungal and urease inhibition potency. A concurrent in silico study has also been applied on ferrocene moiety impregnated guanidines 1-8 to identify most active compounds having for inhibiting the activity of urease (pdb id 3LA4). Most of the compounds were found as potent inhibitors of urease and the compound 1 was found to be the most active with an IC50 of 16.83 ± 0.03 μM. The docking scores are in close agreement with the in vitro obtained IC50 values of inhibitors 1-8. Copyright © 2014 Elsevier Masson SAS. All rights reserved.

Direct observation of electronic and nuclear ground state splitting in external magnetic field by inelastic neutron scattering on oxidized ferrocene and ferrocene containing polymers

Science.gov (United States)

Appel, Markus; Frick, Bernhard; Elbert, Johannes; Gallei, Markus; Stühn, Bernd

2015-01-01

The quantum mechanical splitting of states by interaction of a magnetic moment with an external magnetic field is well known, e.g., as Zeeman effect in optical transitions, and is also often seen in magnetic neutron scattering. We report excitations observed in inelastic neutron spectroscopy on the redox-responsive polymer poly(vinylferrocene). They are interpreted as splitting of the electronic ground state in the organometallic ferrocene units attached to the polymer chain where a magnetic moment is created by oxidation. In a second experiment using high resolution neutron backscattering spectroscopy we observe the hyperfine splitting, i.e., interaction of nuclear magnetic moments with external magnetic fields leading to sub-μeV excitations observable in incoherent neutron spin-flip scattering on hydrogen and vanadium nuclei.

SÍNDROME DE ALIENAÇÃO PARENTAL, FALSO ABUSO SEXUAL E GUARDA COMPARTILHADA: A NECESSIDADE DE UMA OBSERVAÇÃO JURÍDICA TRANSDISCIPLINAR

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Ana Maria Oliveira de Souza, CEULM/ULBRA, Brasil

2012-03-01

Full Text Available Resumo: O presente texto tem por objetivo relacionar a síndrome da alienação parental, o falso abuso sexual e a guarda compartilhada partindo, para tanto, de uma perspectiva transdisciplinar. Visa-se, assim, desvelar noções que são comuns tanto ao Direito como a Psicologia a partir de uma perspectiva diferenciada. Especificamente, busca-se observar tanto aspectos jus-normativos, como a postura psicossocial que cristaliza a alienação parental, observando seus efeitos, sobretudo, em relação ao falso abuso sexual e a guarda compartilhada. Com efeito, as consequências da alienação parental tornam-se mais radicalizadas e universalizadas em um contexto de modernidade tardia, trazendo a necessidade de uma análise que parta de um prisma complexo, que não obstrua as relações de solidariedade existentes entre o Direito e a Psicologia. Palavras-chave: Direito. Transdisciplinaridade. Alienação Parental. Falso Abuso Sexual. Guarda Compartilhada.

Click-generated triazole based ferrocene-carbohydrate bioconjugates

Indian Academy of Sciences (India)

carbohydrate bioconjugates, 2,. C46H56O20N6Fe and 3, C28H33O10N3Fe were designed and synthesized in good yields. Both the compounds,. 2 and 3, behave as very selective and sensitive chromogenic and electrochemical chemosensor for Cu2+ ...

A Biosensor Based on Immobilization of Horseradish Peroxidase in Chitosan Matrix Cross-linked with Glyoxal for Amperometric Determination of Hydrogen Peroxide

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Gui-Xiang Wang

2005-05-01

Full Text Available An amperometric biosensor for hydrogen peroxide (H2O2 was developed viaan easy and effective enzyme immobilization method with the “sandwich” configuration:ferrocene-chitosan: HRP: chitosan-glyoxal using a glassy carbon electrode as the basicelectrode. In order to prevent the loss of immobilized HRP under optimized conditions,the biosensor surface was cross-linked with glyoxal. Ferrocene was selected andimmobilized on the glassy carbon electrode surface as a mediator. The fabricationprocedure was systematically optimized to improve the biosensor performance. Thebiosensor had a fast response of less than 10 s to H2O2, with a linear range of 3.5×10-5 to1.1×10-3 M, and a detection limit of 8.0×10-6 M based on S/N = 3.

Chemical and morphological changes during production of conducting carbons from ferrocene-poly (furfuryl alcohol)

International Nuclear Information System (INIS)

Ozaki, J.; Cashion, J.D.; Brown, L.J.

1996-01-01

Carbons are obtained by heating organic substances up to 1000 deg C under inert atmosphere. The electronic properties of carbons change dramatically during this carbonisation process. By controlled preparation, it is possible to obtain electronically functional materials. The addition of iron to the organic starting material has a strong modifying effect and, in particular, carbonising a ferrocene-poly(furfuryl alcohol) (PFA) mixture at 700 deg C produces a carbon with a comparable electron transfer rate to platinum. 57 Moessbauer spectra showed that the first transformation of the ferrocene is to magnetite, at 200-300 deg C. At 600 deg C, the magnetite is converted to wustite, while at 650 deg C α-iron starts to appear. The final products at 800 deg C were α-iron, γ-iron and cementite, Fe 3 C. Morphological changes were studied by SEM. The tentative explanation for these results is that the iron promotes the elimination of oxygen from the initial PFA structure to produce magnetite. At 600-650 deg C , the magnetite is carbothermically reduced to wustite and α-iron, forming glassy carbon. Above 700 deg C, the iron dissolves carbon atoms to make a solid solution. On cooling, some of this fractionates into graphitic carbon, cementite and γ-iron stabilised by the carbon atoms. We believe that the furry surface is produced in this cooling process

Chemical and morphological changes during production of conducting carbons from ferrocene-poly (furfuryl alcohol)

Energy Technology Data Exchange (ETDEWEB)

Ozaki, J [Tohoku University, Sendai, Japan (Japan). Institute of Chemical Reaction Science; Cashion, J D; Brown, L J [Monash Univ., Clayton, VIC (Australia). Dept. of Physics

1997-12-31

Carbons are obtained by heating organic substances up to 1000 deg C under inert atmosphere. The electronic properties of carbons change dramatically during this carbonisation process. By controlled preparation, it is possible to obtain electronically functional materials. The addition of iron to the organic starting material has a strong modifying effect and, in particular, carbonising a ferrocene-poly(furfuryl alcohol) (PFA) mixture at 700 deg C produces a carbon with a comparable electron transfer rate to platinum. {sup 57} Moessbauer spectra showed that the first transformation of the ferrocene is to magnetite, at 200-300 deg C. At 600 deg C, the magnetite is converted to wustite, while at 650 deg C {alpha}-iron starts to appear. The final products at 800 deg C were {alpha}-iron, {gamma}-iron and cementite, Fe{sub 3}C. Morphological changes were studied by SEM. The tentative explanation for these results is that the iron promotes the elimination of oxygen from the initial PFA structure to produce magnetite. At 600-650 deg C , the magnetite is carbothermically reduced to wustite and {alpha}-iron, forming glassy carbon. Above 700 deg C, the iron dissolves carbon atoms to make a solid solution. On cooling, some of this fractionates into graphitic carbon, cementite and {gamma}-iron stabilised by the carbon atoms. We believe that the furry surface is produced in this cooling process

Study of superconducting properties of ferrocene-added MgB{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Sudesh; Varma, G.D. [Department of Physics, Indian Institute of Technology Roorkee (India); Das, S.; Bernhard, C. [Department of Physics, Fribourg Centre for Nanomaterials-FriMat, University of Fribourg (Switzerland); Shripathi, T. [UGC-DAE CSR, University Campus, Indore (India)

2014-07-15

In the present study, we have shown the effects of ferrocene (FeC{sub 10}H{sub 10}) addition on the superconducting properties of polycrystalline MgB{sub 2} superconductor using transport and magnetic measurements. The addition of FeC{sub 10}H{sub 10} up to 2 wt% in the MgB{sub 2} sample has shown enhanced critical current density, J{sub C} in the entire magnetic field region without affecting much the transition temperature. At 10 K, with respect to a pristine MgB{sub 2} sample, J{sub C} has improved by a factor of 6.55 at 6 T applied field for 1 wt% FeC{sub 10}H{sub 10}. An improvement in the upper critical field, H{sub C{sub 2}} and irreversibility field, H{sub irr} has also been observed up to 2 wt% addition of FeC{sub 10}H{sub 10}. The value of H{sub C{sub 2}} (0) as obtained using the Ginzburg-Landau (GL)-theory fit of the experimental data increases by almost 2 T for 2 wt% FeC{sub 10}H{sub 10}-added MgB{sub 2} as compared to the pristine samples. From X-ray photoemission spectroscopy (XPS), we observed that the Fe is present in sample in the form of ferromagnetic oxides, Fe{sub 3}O{sub 4} and γ-Fe{sub 2}O{sub 3}. These ferromagnetic inclusions provide efficient pinning centers to improve J{sub C}(H) behavior. The flux pinning mechanisms present in the FeC{sub 10}H{sub 10}-added samples are described and discussed in this paper. (copyright 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Effectiveness of a Technology-Based Supportive Educational Parenting Program on Parental Outcomes in Singapore: Protocol for a Randomized Controlled Trial.

Science.gov (United States)

Shorey, Shefaly; Ng, Yvonne Peng Mei; Siew, An Ling; Yoong, Joanne; Mörelius, Evalotte

2018-01-10

Supportive educational programs during the perinatal period are scarce in Singapore. There is no continuity of care available in terms of support from community care nurses in Singapore. Parents are left on their own most of the time, which results in a stressful transition to parenthood. There is a need for easily accessible technology-based educational programs that can support parents during this crucial perinatal period. The aim of this study was to describe the study protocol of a randomized controlled trial on a technology-based supportive educational parenting program. A randomized controlled two-group pretest and repeated posttest experimental design will be used. The study will recruit 118 parents (59 couples) from the antenatal clinics of a tertiary public hospital in Singapore. Eligible parents will be randomly allocated to receive either the supportive educational parenting program or routine perinatal care from the hospital. Outcome measures include parenting self-efficacy, parental bonding, postnatal depression, social support, parenting satisfaction, and cost evaluation. Data will be collected at the antenatal period, immediate postnatal period, and at 1 month and 3 months post childbirth. Recruitment of the study participants commenced in December 2016 and is still ongoing. Data collection is projected to finish within 12 months, by December 2017. This study will identify a potentially clinically useful, effective, and cost-effective supportive educational parenting program to improve parental self-efficacy and bonding in newborn care, which will then improve parents' social support-seeking behaviors, emotional well-being, and satisfaction with parenting. It is hoped that better supported and satisfied parents will consider having more children, which may in turn influence Singapore's ailing birth rate. International Standard Randomized Controlled Trial Number (ISRCTN): 48536064; https://www.isrctn.com/ISRCTN48536064 (Archived by WebCite at http

A comparative study on the thermoelectric effect of parent oxypnictides LaTAsO (T = Fe, Ni)

International Nuclear Information System (INIS)

Tao Qian; Zhu Zengwei; Lin Xiao; Cao Guanghan; Xu Zhuan; Chen Genfu; Luo Jianlin; Wang Nanlin

2010-01-01

The thermopower and Nernst effect were investigated for undoped parent compounds LaFeAsO and LaNiAsO. Both the thermopower and Nernst signal in iron-based LaFeAsO are significantly larger than those in nickel-based LaNiAsO. Furthermore, abrupt changes in both the thermopower and Nernst effect are observed below the structural phase transition temperature and spin-density wave (SDW) type antiferromagnetic (AFM) order temperature in Fe-based LaFeAsO. On the other hand, the Nernst effect is very small in the Ni-based LaNiAsO and it is weakly temperature-dependent, reminiscent of the case in normal metals. We suggest that the effect of SDW order on the spin scattering rate should play an important role in the anomalous temperature dependence of the Hall effect and Nernst effect in LaFeAsO. The contrasting behaviour between the LaFeAsO and LaNiAsO systems implies that the LaFeAsO system is fundamentally different from the LaNiAsO system and this may provide clues to the mechanism of high T c superconductivity in Fe-based systems. (fast track communication)

Ferro-based derivatizing agents for LC/MS an LC/EC/MS

NARCIS (Netherlands)

Seiwert, Bettina

2007-01-01

Within this thesis, the development and application of ferrocene-based derivatizing agents for LC/MS and LC/EC/MS is presented. The advantages of derivatization by ferrocenes are the similtaneous introduction of a mass tag and an electroactive group, which make them ideally suited for LC/MS and

Positron annihilation studies on reactor irradiated and thermal annealed ferrocene

International Nuclear Information System (INIS)

Marques Netto, A.; Carvalho, R.S.; Magalhaes, W.F.; Sinisterra, R.D.

1996-01-01

Retention and thermal annealing following (n, γ) reaction in solid ferrocene, Fe(C 5 H 5 ) 2 , were studied by positron annihilation lifetime spectroscopy (PAL). Positronium (Ps) formation was observed in the non-irradiated compound with a probability or intensity (I 3 ) of 30%. Upon irradiation of the compound with thermal neutrons in a nuclear reactor, I 3 decreases with increasing irradiation time. Thermal treatment again increases I 3 values from 16% to 25%, revealing an important proportion of molecular reformation without variation of the ortho-positronium lifetime (τ 3 ). These results point out the major influence of the electronic structure as determining the Ps yields in the pure complex. In the irradiated and non irradiated complexes the results are satisfactorily explained on the basis of the spur model. (orig.)

Ferrocene-quinoxaline Y-shaped chromophores as fascinating second-order NLO building blocks for long lasting highly active SHG polymeric films.

Science.gov (United States)

Senthilkumar, Kabali; Thirumoorthy, Krishnan; Dragonetti, Claudia; Marinotto, Daniele; Righetto, Stefania; Colombo, Alessia; Haukka, Matti; Palanisami, Nallasamy

2016-07-26

The first example of a Y-shaped ferrocene quinoxaline derivative with a surprisingly high and stable second harmonic generation (SHG) response in composite polymeric films is reported. The interesting quadratic hyperpolarizability values of different substituted Y-shaped chromophores are also investigated in solution by the EFISH technique.

Synthesis and application of a triazene-ferrocene modifier for immobilization and characterization of oligonucleotides at electrodes.

Science.gov (United States)

Hansen, Majken N; Farjami, Elaheh; Kristiansen, Martin; Clima, Lilia; Pedersen, Steen Uttrup; Daasbjerg, Kim; Ferapontova, Elena E; Gothelf, Kurt V

2010-04-16

A new DNA modifier containing triazene, ferrocene, and activated ester functionalities was synthesized and applied for electrochemical grafting and characterization of DNA at glassy carbon (GC) and gold electrodes. The modifier was synthesized from ferrocenecarboxylic acid by attaching a phenyltriazene derivative to one of the ferrocene Cp rings, while the other Cp ring containing the carboxylic acid was converted to an activated ester. The modifier was conjugated to an amine-modified DNA sequence. For immobilization of the conjugate at Au or GC electrodes, the triazene was activated by dimethyl sulfate for release of the diazonium salt. The salt was reductively converted to the aryl radical which was readily immobilized at the surface. DNA grafted onto electrodes exhibited remarkable hybridization properties, as detected through a reversible shift in the redox potential of the Fc redox label upon repeated hybridization/denaturation procedures with a complementary target DNA sequence. By using a methylene blue (MB) labeled target DNA sequence the hybridization could also be followed through the MB redox potential. Electrochemical studies demonstrated that grafting through the triazene modifier can successfully compete with existing protocols for DNA immobilization through the commonly used alkanethiol linkers and diazonium salts. Furthermore, the triazene modifier provides a practical one-step immobilization procedure.

Solvent Effects in the Electroreduction of Ferrocene at Pt in the Temperature Range 200-300 K

Science.gov (United States)

1991-03-20

been obtained at iow temperatures downto 92 K ata P ulramcroeectode(dimete, 2 pm inthree alcohol solvents, namely, methanol, ethanol , and n-propanol. In...In this aree.-doutee-eace&4 Kinetic parameters for the electrooxidation of ferrocene have been obtained at low temperatures down to 193 ’K at a Pt...with solvent nature. tnsvetsiky of~aitm Davis, CA 95616 Kinetic data obtained in mteehanol, ethanol . and I1- propanol as a function of temperature

Os filhos de Medeia e a Síndrome da Alienação Parental

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Yvanna Aires Gadelha Sarmet

Full Text Available Resumo A Síndrome da Alienação Parental (SAP refere-se a um conjunto de sintomas manifestos pela criança durante e após o processo de separação dos seus pais. A SAP demonstra o sofrimento da família e os golpes psíquicos sofridos pela criança quando enredada nos sentimentos de vingança, ódio e rejeição. A criança é desrespeitada e usada como instrumento para punir e provocar dor no genitor alienado. Como no mito de Medeia, no qual a mãe mata seus filhos, na alienação parental, o alienador os sufoca e aniquila neles a capacidade de perceber, sentir e julgar livremente. A criança torna-se uma extensão do alienador, impedida de pensar, discriminar e escolher por si mesma. Ao adotar a tragédia de Medeia e o referencial teórico junguiano, este trabalho analisa as referências feitas às crianças no mito, relaciona-o à SAP e apresenta as consequências da alienação parental para o desenvolvimento psíquico da criança.

Involving Latina/o parents in patient-centered outcomes research: Contributions to research study design, implementation and outcomes.

Science.gov (United States)

Pérez Jolles, Mónica; Martinez, Maria; Garcia, San Juanita; Stein, Gabriela L; Thomas, Kathleen C

2017-10-01

Comparative effectiveness research (CER) is supported by policymakers as a way to provide service providers and patients with evidence-based information to make better health-care decisions and ultimately improve services for patients. However, Latina/o patients are rarely involved as study advisors, and there is a lack of documentation on how their voices contribute to the research process when they are included as collaborators. The purpose of this article was to contribute to the literature by presenting concrete contributions of Latina/o parent involvement to study design, implementation and outcomes in the context of a CER study called Padres Efectivos (Parent Activation). Researchers facilitated a collaborative relationship with parents by establishing a mentor parent group. The contributions of parent involvement in the following stages of the research process are described: (i) proposal development, (ii) implementation of protocols, (iii) analysis plan and (iv) dissemination of results. Mentor parents' contributions helped tailor the content of the intervention to their needs during proposal, increased recruitment, validated the main outcome measure and added two important outcome measures, emphasized the importance of controlling for novice treatment status and developed innovative dissemination strategies. Mentor parents' guidance to the researchers has contributed to reaching recruitment goals, strengthened the study protocol, expanded findings, supported broad ownership of study implications and enriched the overall study data collection efforts. These findings can inform future research efforts seeking an active Latino parent collaboration and the timely incorporation of parent voices in each phase of the research process. © 2017 The Authors Health Expectations Published by John Wiley & Sons Ltd.

Parental involvement after separation/divorce / O envolvimento parental após a separação/divórcio

Directory of Open Access Journals (Sweden)

Luciana Suárez Grzybowski

2010-01-01

Full Text Available Based on the ecological-contextual model and on the concept of parental involvement, this article proposes to discuss the parental practices of separated/divorced fathers and mothers towards their children. In order to do so, 234 subjects (117 fathers/117 mothers with children at school were interviewed via the Parental Practices Inventory. Such instrument evaluated the parental involvement in 5 areas: affective involvement, didactic involvement, social involvement, disciplinary involvement and, responsibility. The results showed greater maternal involvement with children after the divorce: direct (care, interaction and indirect (monitoring, preoccupation. The cohabitation with the mother revealed itself as a significant variable associated to her greater involvement with activities in the private/domestic environment while fathers had greater involvement in the public/social space. Contextual characteristics (cohabitation, frequency of visits and characteristics of the parents (occupation, education, affective and conjugal issues showed to be strongly associated with the parental involvement after divorce.

Literacy Benefits for Latina/o Parents Engaged in a Spanish Literacy Project

Science.gov (United States)

Larrotta, Clarena; Ramirez, Ysabel

2009-01-01

This qualitative study reports on a Latina/o parent literacy project teaching literacy lessons in Spanish to Latina mothers and their children enrolled at a public elementary school. The participating mothers study and practice reading strategies to later put them into practice with their children. Data sources include: Parents' reflective…

GUARDA COMPARTILHADA: um caminho para inibir a alienação parental?

Directory of Open Access Journals (Sweden)

Edwirges Elaine Rodrigues

2014-12-01

Full Text Available Esta pesquisa resume-se ao instituto jurídico da Guarda Compartilhada, uma das modalidades de guarda presente no ordenamento jurídico brasileiro, introduzida pela Lei nº 11.698/2008. Contudo, muito há de se discutir a respeito deste instituto, uma vez que a guarda compartilhada exige alguns requisitos que muitas vezes impede sua aplicação, pois, só trará vantagens caso haja perfeita harmonia na relação entre os genitores. A lei que trata da alienação parental, nº 12.318/2010, também é abordada por este artigo, esta legislação prevê a mudança de guarda para guarda compartilhada como uma das principais sanções para inibir a prática de alienação parental. Entretanto, cada caso deve ser analisado de forma particular, tendo em vista que o principal sujeito de toda esta disputa é o filho, que deve ser protegido pelo princípio do melhor interesse da criança e do adolescente.

Co-construir o tempo : avaliação de um curso de formação parental e parentalidade masculina positiva em contexto de risco

OpenAIRE

Ferreira, Luana Cunha

2008-01-01

Tese de mestrado integrado em Psicologia (Psicologia Clínica da Saúde - Núcleo de Psicologia Clínica Sistémica), apresentada à Universidade de Lisboa através da Faculdade de Psicologia e de Ciências da Educação, 2008 A formação parental surge como uma resposta às necessidades das famílias, particularmente às famílias multidesafiadas e/ou em contextos de risco. Através de uma abordagem eco-sistémica, esta investigação propõe-se avaliar um curso de formação parental do Centro de Apoio Famili...

Modification of Au surfaces using new ferrocene derivatives

International Nuclear Information System (INIS)

Diaz-Ortiz, Tanya L.; Malave-Leon, Maria; Rivera-Claudio, Mirna; Castillo-Ramirez, Jorge; Cabrera-Martinez, Carlos R.; Brito-Gomez, Rosa; Tremont, Rolando J.

2008-01-01

Gold surfaces have been modified by self-assembled techniques. Here the adsorption time of diasteroisomers (1R, 3S)-1-ferrocenyl-3-methyl-4,4-diphenyl-2,5-dioxacyclopentane and (1S, 3S)-1-ferrocenyl-3-methyl-4,4-diphenyl-2,5-dioxacyclopentane (, 3a and 3b) at a Au surface in ethanol solution was controlled. This study was followed by electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS) analysis. The method used for the surface modification was the control of exposure time of a Au surface in the modifier/ethanol solution. It was demonstrated by EIS and XPS that the Au surface was modified with mixture of compounds 3a + 3b, avoiding the electron transference in the interface. It was also observed that the organometallic molecule indeed had been adsorbed on the Au surface. In addition, evidence seems to conclude that the molecule-Au interaction is through the electrons of cyclopentadienyl moiety, where the oxygen atoms are near the air-molecule interface and the iron atom is near the Au surface. This type of interaction of the ferrocene derivatives with gold surfaces has not been reported by any other author

Evaluation of a Community-Based Parenting Program with the Parents of Young Children.

Science.gov (United States)

Brenner, Viktor; Nicholson, Bonnie C.; Fox, Robert A.

1999-01-01

Evaluated effectiveness of a cognitive-behavioral parenting program for parents of children ages 1 to 5 years offered through community-based family resource centers. Found that participants showed significant decreases in use of verbal and corporal punishment, and increases in nurturing behaviors as measured by the Parent Behavior Checklist.…

A Population-Based Comparison of Female and Male Same-Sex Parent and Different-Sex Parent Households.

Science.gov (United States)

Bos, Henny M W; Kuyper, Lisette; Gartrell, Nanette K

2018-03-01

This investigation compared Dutch same-sex parent and different-sex parent households on children's psychological well-being, parenting stress, and support in child rearing. It was also assessed whether associations among children's well-being, parenting stress, and support in child rearing were different in the two household types. Data were based on a nationally representative survey (N = 25,250). Matching was used to enhance similarity in background characteristics between both types of families. Parental and child characteristics were matched for 43 female same-sex parent, 52 male same-sex parent, and 95 different-sex parent households with offspring between 5 and 18 years old. No significant differences were found on children's well-being, problems in the parent-child relationship, being worried about the child, or the use of formal and informal support between mothers in same-sex and different-sex parent households or for fathers in same-sex and different-sex parent households. Regarding perceived confidence in child rearing, fathers in same-sex parent households and mothers in different-sex parent households felt less competent than their counterparts. Neither the associations between children's well-being and the predictors (parenting stress variables) nor those between support and the predictors (parenting stress and children's well-being) differed along household type. In this population-based study, the similarity in child outcomes regardless of household type confirms the results of prior investigations based on convenience samples. These findings are pertinent to family therapists, practitioners, court officials, and policymakers who seek information on parenting experiences and child outcomes in female and male same-sex parent families. © 2017 Family Process Institute.

O impacto do envolvimento parental no desempenho acadêmico de crianças escolares El impacto del envolvimiento parental en el desempeño académico de niños escolares The impact of parental involvement on children's academic performance

Directory of Open Access Journals (Sweden)

Fabiana Cia

2008-06-01

Full Text Available O objetivo deste trabalho foi estudar a relação entre o envolvimento dos pais na educação dos filhos e o desempenho acadêmico destes. Participaram deste estudo 110 crianças da 4ªsérie do Ensino Fundamental. As crianças preencheram o questionário " Qualidade da interação familiar na visão dos filhos" e foram avaliadas usando-se o Teste de Desempenho Escolar - TDE. Observou-se que quanto maior a freqüência de comunicações entre ambos os pais e seus filhos e a participação de ambos os pais nas atividades escolares, culturais e de lazer dos filhos, melhor o desempenho acadêmico das crianças. Tais resultados sugerem a importância do envolvimento parental no desempenho acadêmico dos filhos e, em caso de déficits nessa área, a necessidade de programas, visando melhorar a qualidade das interações entre pais e filhos.El objetivo de este trabajo fue estudiar la relación entre el envolvimiento de los padres en la educación de los hijos y el desempeño académico de estos. Participaron de este estudio 110 niños de la 4ªserie de la Enseñanza Fundamental. Los niños rellenaron el cuestionario " Cualidad de la interacción familiar en la visión de los hijos" y fueron evaluados usándose el Teste de Desempeño Escolar - TDE. Se observó que cuanto mayor la frecuencia de comunicaciones entre ambos los padres y sus hijos y la participación de ambos los padres en las actividades escolares, culturales y de lazer de los hijos, mejor el desempeño académico de los niños. Tales resultados sugieren la importancia del envolvimiento parental en el desempeño académico de los hijos y, en caso de déficits en esa área, la necesidad de programas, visando mejorar la cualidad de las interacciones entre padres e hijos.The relationship between parental involvement in children’s education and children’s academic performance is provided. A total of 110 (fourth grade children participated in this study. The children completed the

Intervenção com pais de crianças deficientes auditivas: elaboração e avaliação de um programa de orientação não presencial Intervention with parents of hearing impaired children: elaboration and evaluation of an orientation program not requiring attendance

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Telma Flores Genaro Motti

2010-12-01

Full Text Available As orientações aos pais favorecem a aceitação da deficiência auditiva e esclarecem possibilidades e condutas que viabilizam o desenvolvimento da criança. Devem ser cuidadosas, a fim de evitar insegurança, ansiedade, expectativas irreais ou reações inadequadas dos pais. Essas orientações são oferecidas no diagnóstico e no acompanhamento, mas as restrições de tempo e financeiras são dificuldades dos pais para o comparecimento freqüente a programas que forneçam um suporte contínuo. A proposta deste trabalho foi elaborar e avaliar um programa de orientação não presencial para pais de crianças com deficiência auditiva severa e profunda, de dois a seis anos de idade. O programa, estruturado em quatro unidades, foi aplicado a 30 pais atendidos no Hospital de Reabilitação de Anomalias Craniofaciais da USP, em Bauru/SP. As unidades foram formuladas com base nas orientações que os especialistas de diferentes áreas transmitem durante o diagnóstico da deficiência auditiva e nas dificuldades e interesses dos pais, identificando-se o conhecimento sobre as avaliações e acompanhamentos, opiniões sobre desempenho e necessidades da criança, deles próprios e das famílias. Para avaliação do programa foram analisadas as respostas dos pais aos questionários das unidades e às entrevistas finais. As análises revelaram que o programa forneceu aos pais, como eles desejavam, informações claras e sugestões de atividades que pudessem ser adequadas ao contexto familiar e colaborassem para o desenvolvimento da criança. Alguns pais encontraram dificuldade em se expressar por escrito e realizar algumas atividades, mas nas entrevistas, foi verificado que tal fato não inviabilizou o entendimento e a participação no programa.Orientation of parents enables them to accept their child's deafness and it also helps them understand treatment options that will enable their child to develop favorably. Orientation should be carefully

Community-based childhood obesity prevention intervention for parents improves health behaviors and food parenting practices among Hispanic, low-income parents.

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Otterbach, Laura; Mena, Noereem Z; Greene, Geoffrey; Redding, Colleen A; De Groot, Annie; Tovar, Alison

2018-01-01

Given the current prevalence of childhood obesity among Hispanic populations, and the importance of parental feeding behaviors, we aimed to assess the impact of the evidence-based Healthy Children, Healthy Families (HCHF) intervention on responsive food parenting practices (FPPs) in a low-income Hispanic population. This community-based pilot study used a non-experimental pre/post within-subjects design. Parents ( n  = 94) of children aged 3-11 years old were recruited to participate in an 8-week, weekly group-based intervention. The intervention was delivered to nine groups of parents by trained paraprofessional educators over a two-year period. Children participated in a separate curriculum that covered topics similar to those covered in the parent intervention. Parents completed self-administered pre/post surveys, which included demographic questions, seven subscales from the Comprehensive Feeding Practices Questionnaire, and the 16-item HCHF Behavior Checklist. Descriptive statistics and paired samples t-tests were used to analyze data from parents that completed the intervention. Fifty-two, primarily Hispanic (93%) parents completed the intervention (39% attrition rate). For parents who completed the intervention, there was a significant increase in one of the feeding practice subscales: encouragement of balance and variety ( p  = 0.01). There were significant improvements in several parent and child diet and activity outcomes ( p  ≤ 0.01). Although attrition rates were high, parents completing the study reported enjoying and being satisfied with the intervention. For parents who completed the intervention, reported 'encouragement of balance and variety', in addition to several health behaviors significantly improved. Larger studies utilizing an experimental design, should further explore the impact of the HCHF curriculum on improving certain FPPs and health behaviors that contribute to obesity.

Forging Fluorine-Containing Quaternary Stereocenters by a Light-Driven Organocatalytic Aldol Desymmetrization Process.

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Cuadros, Sara; Dell'Amico, Luca; Melchiorre, Paolo

2017-09-18

Reported herein is a light-triggered organocatalytic strategy for the desymmetrization of achiral 2-fluoro-substituted cyclopentane-1,3-diketones. The chemistry is based on an intermolecular aldol reaction of photochemically generated hydroxy-o-quinodimethanes and simultaneously forges two adjacent fully substituted carbon stereocenters, with one bearing a stereogenic carbon-fluorine unit. The method uses readily available substrates, a simple chiral organocatalyst, and mild reaction conditions to afford an array of highly functionalized chiral 2-fluoro-3-hydroxycyclopentanones. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Comportamentos violentos de adolescentes e coabitação parento-filial Comportamientos violentos de adolescentes y co-habitabilidad parental-filial Violent behavior in adolescents and parent-child cohabitation

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Rogério Lessa Horta

2010-12-01

Full Text Available OBJETIVO: Analisar a associação entre comportamentos violentos de adolescentes e a coabitação parento-filial. MÉTODOS: Estudo transversal de base populacional realizado na área urbana de Pelotas, RS, em 2002, com amostragem em múltiplos estágios. Foram entrevistados 960 adolescentes com utilização de questionário auto-aplicado. As variáveis dependentes (uso de armas e envolvimento em brigas no último ano foram referidos pelos adolescentes e a variável independente coabitação parento-filial foram submetidas a análise pelo teste de qui-quadrado e razão de prevalências, ajustada para idade, sexo, nível socioeconômico e relato de uso na vida e recente de álcool, tabaco ou drogas ilícitas. RESULTADOS: O envolvimento em brigas no último ano foi referido por 23% dos sujeitos e o uso de armas por 9,6%. A razão de prevalência de ocorrência desses comportamentos foi de 1,38 (IC95%: 0,71; 2,68, p = 0,34 para envolvimento em brigas e de 1,68 (IC95%: 1,06; 2,67, p = 0,03 para uso de armas, tendo como referência sujeitos que coabitavam com pai, com mãe ou com ambos. CONCLUSÕES: A coabitação parento-filial deve ser considerada em políticas de prevenção ao uso de armas por crianças e adolescentes, mas recomenda-se o cuidado de não estigmatizar crianças e adolescentes que não coabitam com pais e mães.OBJETIVO: Analizar la asociación entre comportamientos violentos de adolescentes y la co-habitabilidad parental-filial. MÉTODOS: Estudio transversal de base poblacional realizado en el área urbana de Pelotas, Sur de Brasil, en 2002, con muestreo en múltiples fases. Fueron entrevistados 960 adolescentes con utilización de cuestionario auto-aplicado. Las variables dependientes (uso de armas y envolvimiento en peleas en el último año fueron referidos por los adolescentes y la variable independiente co-habitabilidad parental-filial fueron sometidas a análisis por la prueba e chi-cuadrado y la tasa de prevalencias, ajustada

Synthesis and in vacuo deposition of iron oxide nanoparticles by microplasma-assisted decomposition of ferrocene

International Nuclear Information System (INIS)

Schaefer, Michael; Kumar, Ajay; Mohan Sankaran, R.; Schlaf, Rudy

2014-01-01

Microplasma-assisted gas-phase nucleation has emerged as an important new approach to produce high-purity, nanometer-sized, and narrowly dispersed particles. This study aims to integrate this technique with vacuum conditions to enable synthesis and deposition in an ultrahigh vacuum compatible environment. The ultimate goal is to combine nanoparticle synthesis with photoemission spectroscopy-based electronic structure analysis. Such measurements require in vacuo deposition to prevent surface contamination from sample transfer, which can be deleterious for nanoscale materials. A homebuilt microplasma reactor was integrated into an existing atomic layer deposition system attached to a surface science multi-chamber system equipped with photoemission spectroscopy. As proof-of-concept, we studied the decomposition of ferrocene vapor in the microplasma to synthesize iron oxide nanoparticles. The injection parameters were optimized to achieve complete precursor decomposition under vacuum conditions, and nanoparticles were successfully deposited. The stoichiometry of the deposited samples was characterized in situ using X-ray photoelectron spectroscopy indicating that iron oxide was formed. Additional transmission electron spectroscopy characterization allowed the determination of the size, shape, and crystal lattice of the particles, confirming their structural properties.

Synthesis, antioxidant and antibacterial activities of 3-nitrophenyl ferrocene

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Benabdesselam, S.; Izza, H.; Lanez, T.; Guechi, E. K.

2018-03-01

The current work aims in its first part to synthesize 3-nitrophenylferrocene after diazotizing nitroaniline in the meta position by the sodium nitrite and the formation of the corresponding diazonium salt: 3-nitrobenzendiazonium sulfate, then the salt in solution was added to the ferrocene for the purpose of introducing the nitrophenyl moiety thereon (arylation) and the formation of 3-nitrophenylferrocene. The second part is devoted to the study of the antioxidant activity of 3-NPF by applying the trapping test of superoxide radical using cyclic voltammetry, the free radical DPPH trapping test by spectrophotometry. The results showed that 3-nitrophenylferrocene has a scavenging effect of DPPH radical with IC50 = 1.44mg/ml, superoxide radical with IC50=5.38mg/ml. The third part is devoted to the study of antibacterial activity of the synthesized compound tested on four strains of bacteria: Escherichia coli, Pseudomonas aeruginosa, Enterococcus faecalis and Klebsiella pneumoniae. The obtained results clearly showed that 3-nitrophenylferrocene has low activities on the four bacterial strains with diameters of inhibition zones do not exceeding 17 mm at concentrations of 25mg/ml.

Electrochemical detection of carbidopa using a ferrocene-modified carbon nanotube paste electrode

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FATEMEH KARIMI

2009-12-01

Full Text Available A chemically modified carbon paste electrode (MCPE containing ferrocene (FC and carbon nanotubes (CNT was constructed. The electrochemical behavior and stability of the MCPE were investigated by cyclic voltammetry. The electrocatalytic activity of the MCPE was investigated and it showed good characteristics for the oxidation of carbidopa (CD in phosphate buffer solution (PBS. A linear concentration range of 5 to 600 μM CD, with a detection limit of 3.6±0.17 μM CD, was obtained. The diffusion coefficient of CD and the transfer coefficient ( were also determined. The MCPE showed good reproducibility, remarkable long-term stability and especially good surface renewability by simple mechanical polishing. The results showed that this electrode could be used as an electrochemical sensor for the determination of CD in real samples, such as urine samples.

A relação escola-pais: um modelo de trocas e colaboração The school-parent relationship: a collaboration and exchange model

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Eliana Bhering

1999-03-01

Full Text Available Este estudo usa dados qualitativos coletados em entrevistas com um grupo de 21 "pais" de crianças de 4º série do 1º grau, em oito escolas estaduais de Belo Horizonte, Minas Gerais. O objetivo foi o de pesquisar sua opinião sobre seu envolvimento com a escola primária e com aspectos educacionais. Os dados foram coletados utilizando a tipologia criada por Epstein (in Brandt, 1989, na qual foram resumidas em cinco categorias as várias maneiras de envolver os pais com a escola. Esta tipologia tem sido usada em várias pesquisas, em diferentes países e sua validade já se encontra testada cientificamente. É também usada a teoria das esferas sobrepostas (Epstein, 1987. Os resultados mostram o surgimento de um modelo diferente do de Epstein, que pode ser resumido em três categorias: ajuda, comunicação e envolvimento. A nossa definição de "pais" inclui mães, pais, e todos os outros responsáveis pela guarda legal da criança, mas isso não implica a participação de pais neste estudo, pois nele prevaleceram mães que costumam ser mais presentes na escola, tanto no Brasil como em outros países.This study uses data from 21 fourth grade parents in 8 Brazilian state pre- and primary schools in Belo Horizonte - MG, Brazil, to examine their views about parental involvement and others issues related to their children's school education. The data has been collected through using Epstein's typology (in Brandt, 1989. This typology has already been validated in the past and it was created to summarise many of the kinds of parental involvement practices that any level of school education - from nursery years to secondary level - may develop. A different pattern of the parents and the schools relationship emerged from the parents' data analysis if put in contrast with Epstein's parental involvement typology (1987. The pattern can be unfolded in three variations described as help, involvement and communication. A semi-structured questionnaire was

Ferrocene-Functionalized 4-(2,5-Di(thiophen-2-yl-1H-pyrrol-1-ylaniline: A Novel Design in Conducting Polymer-Based Electrochemical Biosensors

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Rukiye Ayranci

2015-01-01

Full Text Available Herein, we report a novel ferrocenyldithiophosphonate functional conducting polymer and its use as an immobilization matrix in amperometric biosensor applications. Initially, 4-(2,5-di(thiophen-2-yl-1H-pyrrol-1-ylamidoferrocenyldithiophosphonate was synthesized and copolymerized with 4-(2,5-di(thiophen-2-yl-1H-pyrrol-1-ylbenzenamine at graphite electrodes. The amino groups on the polymer were utilized for covalent attachment of the enzyme glucose oxidase. Besides, ferrocene on the backbone was used as a redox mediator during the electrochemical measurements. Prior to the analytical characterization, optimization studies were carried out. The changes in current signals at +0.45 V were proportional to glucose concentration from 0.5 to 5.0 mM. Finally, the resulting biosensor was applied for glucose analysis in real samples and the data were compared with the spectrophotometric Trinder method.

The development of a parenting program for incarcerated mothers in Australia: a review of prison-based parenting programs.

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Newman, Claire; Fowler, Cathrine; Cashin, Andrew

2011-08-01

The increasing population of children with an incarcerated parent is a significant public health issue. A literature search highlighted that children of incarcerated parents experience psychological stressors that may potentially impact on health and behavioural outcomes. Parenting programs for prisoners may be of benefit as early parenting experiences during childhood have a significant impact on a child's future experiences as an adolescent and adult. A review of identified evaluation-based studies of parenting programs for prisoners (N = 11), although varied in program delivery approaches and evaluation methods, suggest that such programs have the potential to improve the parenting skills, knowledge and confidence of incarcerated parents. Finally, this paper provides an outline of the development of an Australian based parenting program for incarcerated mothers and their young children.

Synthesis and Anchoring of Antineoplastic Ferrocene and Phthalocyanine Derivatives on Water-Soluble Polymeric Drug Carriers Derived from Lysine and Aspartic Acid

OpenAIRE

Maree, M. David; Neuse, Eberhard W.; Erasmus, Elizabeth; Swarts, Jannie C.

2007-01-01

The general synthetic strategy towards water-soluble biodegradable drug carriers and the properties that they must have are discussed. The syntheses of water-soluble biodegradable copolymers of lysine and aspartic acid as potential drug-delivering devices, having amine-functionalised side chains are then described. Covalent anchoring of carboxylic acid derivatives of the antineoplastic ferrocene and photodynamically active phthalocyanine moieties to the amine-containing drug carrier copolymer...

Supporting parents and parenting: An overview of data-based papers recently published in Contemporary Nurse.

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Jackson, Debra; Power, Tamara; Dean, Sue; Potgieter, Ingrid; Cleary, Michelle

2013-10-02

Abstract Nurses have a crucial role in play in supporting parents and in delivering and referring parents to family-support services. In this editorial, we reflect on papers recently published in Contemporary Nurse. We sought to consider data-based papers on parenting published between 2008 and 2012 and elucidate the role/s and potential roles of nurses in enhancing and supporting parenting. Parenting is recognised as a crucial variable for achieving positive outcomes for children (Dawson et al 2012). Poor, inconsistent or abusive parenting is linked to poor outcomes (Griffin et al. 2000, Holt et al.2008, Patterson et al.1989), while consistent and effective parenting is associated with enhanced child outcomes (Lamb 2012, Landry et al.2001). In addition to being important to outcomes for children, perceived parenting quality is also important to parents themselves. Disrupted relationships between parents and their children have been identified as distressing and potentially damaging to both parties (Jackson 2000; East 2006, 2007; Power 2012).

Parents and Young Children with Disabilities: The Effects of a Home-Based Music Therapy Program on Parent-Child Interactions.

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Yang, Yen-Hsuan

2016-01-01

Responsive parenting style and synchronous parent-child interactions have a positive impact on children in terms of language, cognitive, and social-emotional development. Despite widely documented benefits of music therapy on parent-child interactions, empirical evidence for the effects of music therapy on parent-child synchrony is lacking. To examine effects of parent-child dyads' participation in a six-week home-based music therapy program on parent response, child initiation, and parent-child synchrony, as well as parents' daily use of musical activities with their child. Twenty-six parent-child dyads participated in this pretest-posttest within-subject single-group design study. Participating dyads included parents and their child with disabilities or developmental delays (ages 1-3 years inclusive). Parent-child dyads participated in a home-based music therapy program that included six weekly 40-minute sessions, and incorporated five responsive teaching strategies (i.e., affect, match, reciprocity, shared control, and contingency). Observational data were recorded for parent-child interactions and parent-child synchrony. Parents' positive physical and verbal responses, as well as children's positive verbal initiations, increased significantly pre- to post-intervention; however, children's positive physical initiations did not increase significantly. Parent-child synchrony also improved significantly pre- to post-intervention. Findings support the use of home-based music therapy programs to facilitate parent-child interactions in the areas of parental responsiveness and child-initiated communication, as well as parent-child synchrony. © the American Music Therapy Association 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Examining the impact of differential cultural adaptation with Latina/o immigrants exposed to adapted parent training interventions.

Science.gov (United States)

Parra-Cardona, J Rubén; Bybee, Deborah; Sullivan, Cris M; Rodríguez, Melanie M Domenech; Dates, Brian; Tams, Lisa; Bernal, Guillermo

2017-01-01

There is a dearth of empirical studies aimed at examining the impact of differential cultural adaptation of evidence-based clinical and prevention interventions. This prevention study consisted of a randomized controlled trial aimed at comparing the impact of 2 differentially culturally adapted versions of the evidence-based parenting intervention known as Parent Management Training, the Oregon Model (PMTOR). The sample consisted of 103 Latina/o immigrant families (190 individual parents). Each family was allocated to 1 of 3 conditions: (a) a culturally adapted PMTO (CA), (b) culturally adapted and enhanced PMTO (CE), and (c) a wait-list control. Measurements were implemented at baseline (T1), treatment completion (T2) and 6-month follow up (T3). Multilevel growth modeling analyses indicated statistically significant improvements on parenting skills for fathers and mothers (main effect) at 6-month follow-up in both adapted interventions, when compared with the control condition. With regard to parent-reported child behaviors, child internalizing behaviors were significantly lower for both parents in the CE intervention (main effect), compared with control at 6-month follow-up. No main effect was found for child externalizing behaviors. However, a Parent × Condition effect was found indicating a significant reduction of child externalizing behaviors for CE fathers compared with CA and control fathers at posttest and 6-month follow-up. Present findings indicate the value of differential cultural adaptation research designs and the importance of examining effects for both mothers and fathers, particularly when culturally focused and gender variables are considered for intervention design and implementation. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

Register-based estimates of parents' coresidence in Sweden, 1969-2007

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Elizabeth Thomson

2013-12-01

Full Text Available Background: Many of the dramatic changes in family formation and dissolution observed in wealthy countries over the past 60 years are tracked through vital statistics or censuses. The signature change in family behavior -- non-marital cohabitation -- is not, however, registered in most settings. Objective: We evaluate the quality of new register-based estimates of parents' union status at birth and of separation during the childrearing years. Methods: Parents of a common child are identified through the Multi-Generation Register that links each child to each parent and therefore each parent to each other. The Total Population Register identifies the property at which each parent is registered at the end of each year. We use the five-year censuses 1960-1990 as one standard of comparison because the censuses identify the dwelling unit for each parent on the census date. Results: Property-based estimates of parents' coresidence compare very well to census reports. Register-based estimates are virtually identical with those produced from the 1992 Swedish Fertility and Family Survey; differences between register estimates and those produced from the 1991 and 2000 Level of Living Survey can be explained by differences in measurement of marriage and cohabitation. Conclusions: Estimates of parents' cohabitation based on annual, property-level registration are of sufficient quality for their use in substantive analyses of union status at birth and parents' separation in Sweden. Comments: Although register-based estimates of parents' coresidence at a child's birth or afterwards can be generated only for a select group of countries, their use can be fruitful for understanding more general processes of family change. Centralized administrative registers exist in many countries but have not been made fully available for research therefore losing much of the potential value.

Estudo bioético dos transplantes renais com doadores vivos não-parentes no Brasil: a ineficácia da legislação no impedimento do comércio de órgãos

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Passarinho Lúcia Eugênia Velloso

2003-01-01

Full Text Available OBJETIVO: Conhecer a opinião de cinco diferentes segmentos sociais (promotores públicos, magistrados, população geral, pacientes da lista de espera para transplante renal e profissionais da equipe de transplantes renais do Hospital de Base de Brasília, a respeito da lei que rege a doação de órgãos para transplantes, particularizando a doação de rim por doador vivo não parente, com a nova redação dada pela lei nº 10.211 de 23/03/2001, especificamente em seu artigo 9º, que amplia os critérios da doação de órgãos entre vivos não parentes. MÉTODOS: Foi aplicado um questionário composto por seis perguntas objetivas, com a finalidade de se conhecer a opinião de cinco grupos de pessoas do Distrito Federal, sobre a atual lei de transplantes de órgãos no Brasil. RESULTADOS: Para 80% dos entrevistados, a lei brasileira, ao permitir a doação de órgãos entre vivos não-parentes, possibilita a existência de doação remunerada e 81% consideram que a exigência de autorização judicial não é instrumento hábil para impedir a comercialização de órgãos. CONCLUSÕES: A presente pesquisa mostra que a legislação brasileira é falha no que se refere à utilização de rins para transplantes a partir de doadores vivos não parentes, abrindo possibilidades para o comércio de órgãos no país. Partindo da premissa que as pessoas pobres são as mais vulneráveis neste contexto, os autores sugerem mudanças na legislação vigente, objetivando sua proteção e, portanto, mais justiça.

Ferrocene-functionalized 4-(2,5-Di(thiophen-2-yl)-1H-pyrrol-1-yl)aniline: a novel design in conducting polymer-based electrochemical biosensors.

Science.gov (United States)

Ayranci, Rukiye; Demirkol, Dilek Odaci; Ak, Metin; Timur, Suna

2015-01-13

Herein, we report a novel ferrocenyldithiophosphonate functional conducting polymer and its use as an immobilization matrix in amperometric biosensor applications. Initially, 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)amidoferrocenyldithiophosphonate was synthesized and copolymerized with 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine at graphite electrodes. The amino groups on the polymer were utilized for covalent attachment of the enzyme glucose oxidase. Besides, ferrocene on the backbone was used as a redox mediator during the electrochemical measurements. Prior to the analytical characterization, optimization studies were carried out. The changes in current signals at +0.45 V were proportional to glucose concentration from 0.5 to 5.0 mM. Finally, the resulting biosensor was applied for glucose analysis in real samples and the data were compared with the spectrophotometric Trinder method.

Does self-directed and web-based support for parents enhance the effects of viewing a reality television series based on the Triple P-Positive Parenting Programme?

Science.gov (United States)

Sanders, Matthew; Calam, Rachel; Durand, Marianne; Liversidge, Tom; Carmont, Sue Ann

2008-09-01

This study investigated whether providing self-directed and web-based support for parents enhanced the effects of viewing a reality television series based on the Triple P - Positive Parenting Programme. Parents with a child aged 2 to 9 (N = 454) were randomly assigned to either a standard or enhanced intervention condition. In the standard television alone viewing condition, parents watched the six-episode weekly television series, 'Driving Mum and Dad Mad'. Parents in the enhanced television viewing condition received a self-help workbook, extra web support involving downloadable parenting tip sheets, audio and video streaming of positive parenting messages and email support, in addition to viewing the television series. Parents in both conditions reported significant improvements in their child's disruptive behaviour and improvements in dysfunctional parenting practices. Effects were greater for the enhanced condition as seen on the ECBI, two of the three parenting indicators and overall programme satisfaction. However, no significant differences were seen on other measures, including parent affect indicators. The level of improvement was related to number of episodes watched, with greatest changes occurring in families who watched each episode. Improvements achieved at post-intervention by parents in both groups were maintained at six-month follow-up. Online tip sheets were frequently accessed; uptake of web-based resources was highest early in the series. The value of combining self-help approaches, technology and media as part of a comprehensive public health approach to providing parenting support is discussed.

A relação entre o sentimento de competência educativa parental, o apoio social, a autoestima e o rendimento escolar em alunos do ensino básico

OpenAIRE

Afonso, Andreia de Fátima Lino

2011-01-01

Dissertação de Mestrado em Psicologia: especialização em Psicologia da Educação O sentimento de competência parental é definido como a perceção que os pais ou cuidadores possuem quanto à sua competência enquanto pais; e pode estar associado com o apoio social e a autoestima dos pais. Além disso, de acordo com diversos autores, as atitudes e o clima familiar influenciam o rendimento escolar dos filhos. Embora não esteja tão estudada, a relação entre o sentimento de auto-eficácia e satisfaçã...

Allowing Imprisoned Fathers to Parent: Maximising the Potential Benefits of Prison Based Parenting Programmes

Science.gov (United States)

Hayes, David; Butler, Michelle; Devaney, John; Percy, Andrew

2018-01-01

During imprisonment, fathers are separated from their families and contact is limited. When delivering a prison based parenting programme, providing an opportunity to rehearse newly acquired parenting skills can be key for mastering the performance of these skills and using these skills to improve father-child relationships. This paper takes an…

Parenting and Politics: Exploring Early Moral Bases of Political Orientation

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Ronnie Janoff-Bulman

2014-03-01

Full Text Available Based on Lakoff’s (2002 Strict Father and Nurturant Parent metaphors for political conservatism and liberalism respectively, two studies explored parenting styles, political ideology, and the moral orientations that might link the two. Restrictive parenting (by both mother and father predicted political conservatism, and this path was mediated by a strong Social Order orientation (Study 1 reflecting, more broadly, an inhibition-based proscriptive morality (Study 2. Political liberalism was associated with a Social Justice orientation, but was not predicted by nurturant parenting in either study. Study 1 included mothers’ reports of their own parenting, and these were correlated with the students’ responses. Findings support a restrictive moral underpinning for conservatism, but raise questions about the assumed unique association between parental nurturance and political liberalism, which is addressed in the discussion.

Oxidative stress and damage in liver, but not in brain, of Fischer 344 rats subjected to dietary iron supplementation with lipid-soluble[(3,5,5-Trimethylhexanoyl)ferrocene

DEFF Research Database (Denmark)

Lykkesfeldt, Jens; Morgan, Evan; Christen, Stephan

2007-01-01

Accumulation of iron probably predisposes the aging brain to progressive neuronal loss. We examined various markers of oxidative stress and damage in the brain and liver of 3- and 24-month old rats following supplementationwith the lipophilic iron derivative [(3,5,5-trimethylhexanoyl)ferrocene] (......, they also demonstrated that the brain is well protected against dietary iron overload by using iron in a lipid-soluble formulation.......Accumulation of iron probably predisposes the aging brain to progressive neuronal loss. We examined various markers of oxidative stress and damage in the brain and liver of 3- and 24-month old rats following supplementationwith the lipophilic iron derivative [(3,5,5-trimethylhexanoyl......)ferrocene] (TMHF), which is capable of crossing the blood-brain barrier. At both ages, iron concentration increased markedly in the liver but failed to increase in the brain. In the liver of TMHF-treated young rats, levels of a- and ¿-tocopherols and glutathione (GSH) were also higher. In contrast, the brain...

Parenting and Politics: Exploring Early Moral Bases of Political Orientation

OpenAIRE

Janoff-Bulman, Ronnie; Carnes, Nate C.; Sheikh, Sana

2014-01-01

Based on Lakoff’s (2002) Strict Father and Nurturant Parent metaphors for political conservatism and liberalism respectively, two studies explored parenting styles, political ideology, and the moral orientations that might link the two. Restrictive parenting (by both mother and father) predicted political conservatism, and this path was mediated by a strong Social Order orientation (Study 1) reflecting, more broadly, an inhibition-based proscriptive morality (Study 2). Political liberalism wa...

A quadruplet electrochemical platform for ultrasensitive and simultaneous detection of ascorbic acid, dopamine, uric acid and acetaminophen based on a ferrocene derivative functional Au NPs/carbon dots nanocomposite and graphene

Energy Technology Data Exchange (ETDEWEB)

Yang, Liuqing; Huang, Na; Lu, Qiujun; Liu, Meiling, E-mail: liumeilingww@126.com; Li, Haitao; Zhang, Youyu; Yao, Shouzhuo

2016-01-15

In this work, a new nanomaterial of thiol functional ferrocene derivative (Fc-SH) stabilized Au NPs/carbon dots nanocomposite (Au/C NC) coupling with graphene modified glassy carbon electrode (Fc-S-Au/C NC/graphene/GCE) was fabricated to serve as a quadruplet detection platform for ultrasensitive and simultaneous determination of ascorbic acid (AA), dopamine (DA), uric acid (UA) and acetaminophen (AC). The Au/C NC was synthesized by adding HAuCl{sub 4} into carbon nanodots solution without using any additional reductant and stabilizing agent. Then the Fc-SH was utilized as the protective and capping agent to modify the Au/C NC. Transmission electron microscopy (TEM), UV–Vis, Fourier-transform infrared (FT-IR), scanning electron microscopy (SEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) were adopted to characterize the morphology and electrochemical properties of the materials and the electrodes. The Fc-S-Au/C NC/graphene/GCE exhibits a synergistic catalytic and amplification effects towards oxidation of AA, DA, UA and AC owing to the existence of the nanomaterial and electron mediator. When simultaneous detection of AA, DA, UA and AC, the oxidation peak potentials of the four compounds on the electrode can be well separated and the peak currents were linearly dependent on their concentrations. The quadruplet detection platform shows excellent linear range and ultrasensitive response to the four components, the detection limits were estimated to be as low as 1.00, 0.05, 0.12 and 0.10 μM (S/N = 3), and the modified electrode exhibits excellent stability and reproducibility. The proposed electrode has been successfully applied to detect of these four analytes in real samples with satisfactory results. - Highlights: • A quadruplet detection platform for ultrasensitive and simultaneous determination of AA, DA, UA and AC was constructed. • The platform was based on the composite containing Au/C NC, graphene and a ferrocene

Social media and gamification: Engaging vulnerable parents in an online evidence-based parenting program.

Science.gov (United States)

Love, Susan M; Sanders, Matthew R; Turner, Karen M T; Maurange, Marianne; Knott, Theresa; Prinz, Ronald; Metzler, Carol; Ainsworth, Andrew T

2016-03-01

The aim of this study was to examine the feasibility (accessibility, engagement and impact) of adding social media and gaming features (e.g., social sharing with anonymity, badges to incentivize skills practice, an accredited facilitator for support) and access via smartphones to an evidenced-based parenting program, Triple P Online. The highly vulnerable population included 155 disadvantaged, high-risk parents (e.g., 76% had a family annual income of less than $15,000; 41% had been incarcerated; 38% were in drug/alcohol treatment; and 24% had had a child removed due to maltreatment). The ethnic groups most commonly identified were African American (24%) and Hispanic (66%). Respondents were primarily mothers (86%) from five community programs in Los Angeles. The study used a single group repeated measures design (pre, post, 6-month follow-up). Data collected included standardized self-report measures, post-intervention focus groups and interviews, website usage reports, and Google Analytics. Significant multivariate ANOVA time effects were found, demonstrating reductions in child behavioral problems, reduced lax/permissive and over-reactive parenting, and decreased parental stress. No effects were found for parental confidence, attributions, or depression and anxiety (which were in the normal range at baseline). Positive effects were maintained or improved at 6-month follow-up. The participants engaged in the online community and valued its flexibility, anonymity, and shared learning. This foundational implementation trial provides support for future rigorous evaluation of social media and gaming features as a medium for increasing parental engagement in evidence-based parenting programs online--a public health approach to protect and improve the development of vulnerable children. Copyright © 2016 Elsevier Ltd. All rights reserved.

Latina/o Parent Organizing for Educational Justice: An Ethnographic Account of Community Building and Radical Healing

Science.gov (United States)

Nygreen, Kysa

2017-01-01

This article describes a parent organizing effort with Latina/o immigrant parents in a large, high-poverty, racially and linguistically diverse urban school district. Drawing from ethnographic research and the theoretical framework of "mujerismo," it examines the relational processes of community building and radical healing that…

Design, synthesis and structure of new potential electrochemically active boronic acid-based glucose sensors

DEFF Research Database (Denmark)

Norrild, Jens Chr.; Søtofte, Inger

2002-01-01

In the course of our investigations on new boronic acid based carbohydrate sensors three new boronic acids 3, 7 and 11 containing a ferrocene moiety were synthesised. Their design includes an intramolecular B-N bonding motif in order to facilitate binding at physiological pH. We report the synthe......In the course of our investigations on new boronic acid based carbohydrate sensors three new boronic acids 3, 7 and 11 containing a ferrocene moiety were synthesised. Their design includes an intramolecular B-N bonding motif in order to facilitate binding at physiological pH. We report...

Addressing Parent-Child Conflict: Attachment-Based Interventions with Parents

Science.gov (United States)

Kindsvatter, Aaron; Desmond, Kimberly J.

2013-01-01

This article describes the use of attachment theory to address parent-child conflict. The authors propose that parent-child conflict is attributable to the unmet attachment needs of both children and parents and that attachment insecurity results in problematic patterns of attachment in parent-child relationships. Three conversational frames are…

Emission spectroscopy of argon ferrocene mixture jet in a low pressure plasma reactor

International Nuclear Information System (INIS)

Tiwari, N.; Tak, A.K.; Chakravarthy, Y.; Shukla, A.; Meher, K.C.; Ghorui, S.; Thiyagarajan, T.K.

2015-01-01

Emission spectroscopy is employed to measure the plasma temperature and species identification in a reactor used for studying homogenous nucleation and growth of iron nano particle. Reactor employs segmented non transferred plasma torch mounted on water cooled cylindrical chamber. The plasma jet passes through graphite nozzle and expands in low pressure reactor. Ferrocene is fed into the nozzle where it mixes with Argon plasma jet. A high resolution spectrograph (SHAMROCK 303i, resolution 0.06 nm) has been used to record the spectra over a wide range. Identification of different emission lines has been done using NIST database. Lines from (700 to 860nm) were considered for calculation of temperature. Spectra were recorded for different axial location, pressure and power. Temperature was calculated using Maxwell Boltzman plot method. Variation in temperature with pressure and location is presented and possible reasons for different behaviour are explored. (author)

Cost of talking parents, healthy teens: a worksite-based intervention to promote parent-adolescent sexual health communication.

Science.gov (United States)

Ladapo, Joseph A; Elliott, Marc N; Bogart, Laura M; Kanouse, David E; Vestal, Katherine D; Klein, David J; Ratner, Jessica A; Schuster, Mark A

2013-11-01

To examine the cost and cost-effectiveness of implementing Talking Parents, Healthy Teens, a worksite-based parenting program designed to help parents address sexual health with their adolescent children. We enrolled 535 parents with adolescent children at 13 worksites in southern California in a randomized trial. We used time and wage data from employees involved in implementing the program to estimate fixed and variable costs. We determined cost-effectiveness with nonparametric bootstrap analysis. For the intervention, parents participated in eight weekly 1-hour teaching sessions at lunchtime. The program included games, discussions, role plays, and videotaped role plays to help parents learn to communicate with their children about sex-related topics, teach their children assertiveness and decision-making skills, and supervise and interact with their children more effectively. Implementing the program cost $543.03 (standard deviation, $289.98) per worksite in fixed costs, and $28.05 per parent (standard deviation, $4.08) in variable costs. At 9 months, this $28.05 investment per parent yielded improvements in number of sexual health topics discussed, condom teaching, and communication quality and openness. The cost-effectiveness was $7.42 per new topic discussed using parental responses and $9.18 using adolescent responses. Other efficacy outcomes also yielded favorable cost-effectiveness ratios. Talking Parents, Healthy Teens demonstrated the feasibility and cost-effectiveness of a worksite-based parenting program to promote parent-adolescent communication about sexual health. Its cost is reasonable and is unlikely to be a significant barrier to adoption and diffusion for most worksites considering its implementation. Copyright © 2013 Society for Adolescent Health and Medicine. Published by Elsevier Inc. All rights reserved.

Effectiveness of a Group-Based Program for Parents of Children with Dyslexia

Science.gov (United States)

Multhauf, Bettina; Buschmann, Anke; Soellner, Renate

2016-01-01

Parents of children with dyslexia experience more parenting stress and depressive symptoms than other parents. The purpose of this study was to evaluate the effects of a cognitive-behavioral group-based program for parents of dyslexic children on parenting stress levels, parent-child homework interactions and parental competencies. 39 children…

What do parents think about parental participation in school-based interventions on energy balance-related behaviours? a qualitative study in 4 countries

Science.gov (United States)

2011-01-01

Background Overweight and obesity in youth has increased dramatically. Therefore, overweight prevention initiatives should start early in life and target modifiable energy balance-related behaviours. Parental participation is often advocated as important for school-based interventions, however, getting parents involved in school-based interventions appears to be challenging based on earlier intervention experiences. The purpose of this study was to get insight into the determinants of and perspectives on parental participation in school-interventions on energy balance-related behaviours (physical activity, healthy eating, sedentary behaviours) in parents of ten- to twelve-year olds in order to develop an effective parental module for school-based interventions concerning energy balance-related behaviours. Methods Four countries (Belgium, Hungary, Norway and Spain) conducted the focus group research based on a standardised protocol and a semi-structured questioning route. A variation in parental socio-economic status (SES) and parental school involvement was taken into account when recruiting the parents. The audio taped interviews were transcribed, and a qualitative content analysis of the transcripts was conducted in each country. Results Seventeen focus group interviews were conducted with a total of 92 parents (12 men, 80 women). Physical activity was considered to be a joint responsibility of school and parents, nutrition as parent's responsibility but supported by the school, and prevention of sedentary behaviours as parent's sole responsibility. Parents proposed interactive and practical activities together with their child as the best way to involve them such as cooking, food tasting, nutrition workshops, walking or cycling tours, sport initiations together with their child. Activities should be cheap, on a convenient moment, focused on their children and not on themselves, not tutoring, not theoretical, and school-or home-based. Conclusions Parents want to

Use of one- and two-mediator systems for developing a BOD biosensor based on the yeast Debaryomyces hansenii.

Science.gov (United States)

Zaitseva, A S; Arlyapov, V A; Yudina, N Yu; Alferov, S V; Reshetilov, A N

2017-03-01

We investigated the use of one- and two-mediator systems in amperometric BOD biosensors (BOD, biochemical oxygen demand) based on the yeast Debaryomyces hansenii. Screening of nine mediators potentially capable of electron transfer - ferrocene, 1,1'-dimethylferrocene, ferrocenecarboxaldehyde, ferroceneacetonitrile, neutral red, 2,6-dichlorophenolindophenol, thionine, methylene blue and potassium ferricyanide - showed only ferrocene and neutral red to be efficient electron carriers for the eukaryotes studied. Two-mediator systems based on combinations of the investigated compounds were used to increase the efficiency of electron transfer. The developed two-mediator biosensors exceeded their one-mediator analogs by their characteristics. The most preferable two-mediator system for developing a BOD biosensor was a ferrocene-methylene blue combination that ensured a satisfactory long-time stability (43 days), selectivity, sensitivity (the lower limit of the determined BOD 5 concentrations, 2.5mg О 2 /dm 3 ) and speed (assay time for one sample, not greater than 10min) of BOD determination. Analysis of water samples showed that the use of a ferrocene-methylene blue two-mediator system and the yeast D. hansenii enabled registration of data that highly correlated with the results of the standard method (R=0.9913). Copyright © 2017 Elsevier Inc. All rights reserved.

Ferrocene-catalyzed heterogeneous Fenton-like degradation mechanisms and pathways of antibiotics under simulated sunlight: A case study of sulfamethoxazole.

Science.gov (United States)

Li, Yingjie; Zhang, Biaojun; Liu, Xiangliang; Zhao, Qun; Zhang, Heming; Zhang, Yuechao; Ning, Ping; Tian, Senlin

2018-07-05

Readily-available and efficient catalyst is essential for activating oxidants to produce reactive species for deeply remediating water bodies contaminated by antibiotics. In this study, Ferrocene (Fc) was introduced to establish a heterogeneous photo-Fenton system for the degradation of sulfonamide antibiotics, taking sulfamethoxazole as a representative. Results showed that the removal of sulfamethoxazole was effective in Fc-catalyzed photo-Fenton system. Electron spin resonance and radical scavenging experiments verified that there was a photoindued electron transfer process from Fc to H 2 O 2 and dissolved oxygen resulting in the formation of OH that was primarily responsible for the degradation of sulfamethoxazole. The reactions of OH with substructure model compounds of sulfamethoxazole unveiled that aniline moiety was the preferable reaction site of sulfamethoxazole, which was verified by the formation of hydroxylated product and the dimer of sulfamethoxazole in Fc-catalyzed photo-Fenton system. This heterogeneous photo-Fenton system displayed an effective degradation efficiency even in a complex water matrices, and Fc represented a long-term stability by using the catalyst for multiple cycles. These results demonstrate that Fc-catalyzed photo-Fenton oxidation may be an efficient approach for remediation of wastewater containing antibiotics. Copyright © 2018. Published by Elsevier B.V.

Influência dos pais no processo de escolha profissional dos filhos: uma revisão da literatura Parental influence on their children's career choice: a literature review

Directory of Open Access Journals (Sweden)

Fabiana Hilário de Almeida

2011-04-01

Full Text Available Considerando a reconhecida importância da família, sobretudo dos pais, no desenvolvimento vocacional do adolescente, como aponta a literatura, este estudo objetiva contribuir com uma sistematização da produção do conhecimento sobre a influência dos pais no processo de escolha da carreira de filhos adolescentes. Trata-se de um estudo ilustrativo e não representativo. O corpus de análise foi constituído por artigos, livros, teses e dissertações, encontrados em bases eletrônicas de dados e em acervos de universidades. As publicações foram sistematizadas segundo os referenciais teóricos predominantes nos textos analisados. Os resultados mostraram que, independentemente dos referenciais, a influência dos pais ocorre continuamente nos processos de interação dentro dos grupos familiares. Apesar dessa constatação, identificou-se lacuna de estudos sobre intervenções realizadas diretamente com os pais de jovens em processo de escolha da carreira no contexto brasileiro.Having in view the importance of family, chiefly parents, in adolescents' vocational development, as seen in the literature, this study aimed at contributing with a systematization of production of knowledge about the influence of parents on their adolescent children's career choice. This is an illustrative, not representative study. The corpus for analysis constituted of papers, books, theses and dissertations found in electronic data bases and university libraries. The publications were systematized according to the prevailing theoretical approaches in the analyzed texts. The results showed that, whatever the approaches are, parental influence occurs continuously in the interaction processes within family groups. Despite this observation, a lack of studies about interventions carried out directly with parents of adolescents in career-choice processes was verified to exist in the Brazilian context.

A novel continuous process for synthesis of carbon nanotubes using iron floating catalyst and MgO particles for CVD of methane in a fluidized bed reactor

Energy Technology Data Exchange (ETDEWEB)

Maghsoodi, Sarah; Khodadadi, Abasali [Catalysis and Nanostructured Materials Research Laboratory, School of Chemical Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Mortazavi, Yadollah, E-mail: mortazav@ut.ac.ir [Nanoelectronics Centre of Excellence, University of Tehran, POB 11365-4563, Tehran (Iran, Islamic Republic of)

2010-02-15

A novel continuous process is used for production of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CVD) of methane on iron floating catalyst in situ deposited on MgO in a fluidized bed reactor. In the hot zone of the reactor, sublimed ferrocene vapors were contacted with MgO powder fluidized by methane feed to produce Fe/MgO catalyst in situ. An annular tube was used to enhance the ferrocene and MgO contacting efficiency. Multi-wall as well as single-wall CNTs was grown on the Fe/MgO catalyst while falling down the reactor. The CNTs were continuously collected at the bottom of the reactor, only when MgO powder was used. The annular tube enhanced the contacting efficiency and improved both the quality and quantity of CNTs. The SEM and TEM micrographs of the products reveal that the CNTs are mostly entangled bundles with diameters of about 10-20 nm. Raman spectra show that the CNTs have low amount of amorphous/defected carbon with I{sub G}/I{sub D} ratios as high as 10.2 for synthesis at 900 deg. C. The RBM Raman peaks indicate formation of single-walled carbon nanotubes (SWNTs) of 1.0-1.2 nm diameter.

Integrating Faith-based and Community-based Participatory Research Approaches to Adapt the Korean Parent Training Program.

Science.gov (United States)

Kim, Eunjung; Boutain, Doris; Kim, Sangho; Chun, Jin-Joo; Im, Hyesang

Faith and community based inquiry approaches are rarely used to develop research interventions. The purpose of this article is to present how a research team worked with six Korean American Christian churches to revise the prototype Korean Parent Training Program (KPTP), based upon the Bright Futures Parenting Program. The collaboration was sought to better integrate and align the KPTP with Korean culture and faith. The KPTP was developed to promote positive parenting practices and decrease mental health disparities of Korean American children. Sixteen church participants completed a Delphi survey, a workshop series, Community Theaters, and focus groups. The participants suggested adding Korean traditional parenting virtues, Christian parenting principles, and revising the standardized parent training and program philosophy. Revisions made KPTP sensitive to Korean culture and faith, and promoted program acceptability. The process demonstrated the importance of working with church volunteers to develop faith-based and community-based health promotion interventions targeting Korean American faith communities. This research presents significant and meaningful implications for working with other faith communities from minority backgrounds. Copyright © 2017 Elsevier Inc. All rights reserved.

Engaging parents in evidence-based treatments in schools: Community perspectives from implementing CBITS.

Science.gov (United States)

Santiago, Catherine Decarlo; Pears, Gillian; Baweja, Shilpa; Vona, Pamela; Tang, Jennifer; Kataoka, Sheryl H

2013-12-01

This study explored parent engagement in an evidence-based treatment, the Cognitive Behavioral Intervention for Trauma in Schools (CBITS), which was delivered in a school setting. To examine the successes and challenges in engaging parents in this school-based program, we conducted qualitative interviews by phone to obtain data from clinicians, parents, and other school personnel across eleven schools from 3 different regions of the United States. Almost all of these schools served low-income and ethnically diverse communities. We describe general impressions of parent engagement, parent reactions and preferences with regard to CBITS, barriers to parent engagement, and how to overcome barriers from multiple perspectives. Parent engagement across schools varied, with extensive outreach and relatively good parent engagement in CBITS described in some schools, while in other schools, efforts to engage parents were not as consistent. Implications for future efforts to engage parents in school-based treatments are discussed.

Pathways to Achievement: Career and Educational Aspirations and Expectations of Latina/o Immigrant Parents and Early Adolescents

Science.gov (United States)

Chavira, Gabriela; Cooper, Catherine R.; Vasquez-Salgado, Yolanda

2016-01-01

Drawing on sociocultural and related theories, 4 questions examined career and educational aspirations and expectations among 24 immigrant Latina/o early adolescents and their parents as predictors of students' grades. First, adolescents' career aspirations and expectations were correlated, and both parents and adolescents held educational…

Centros de Apoio Familiar e Aconselhamento Parental: proposta de um modelo global de organização The Centers for Family Support and Parental Counseling: proposal of a global organization model

Directory of Open Access Journals (Sweden)

Ana Teixeira de Melo

2009-04-01

Full Text Available Os Centros de Apoio Familiar e Aconselhamento Parental constituem, no panorama dos serviços sociais portugueses, uma tipologia relativamente recente de serviços de apoio familiar dirigidos a crianças e jovens em situação de risco e suas famílias. No entanto, tendem a operar de formas muito distintas, carecendo ainda de enquadramento técnico e legal adequado. No presente artigo, revêem-se os objetivos dos CAFAP e apresenta-se uma proposta de um Modelo Global de Organização destes serviços, para que se apresentem como recursos eficazes de apoio ao trabalho solicitado pelos Tribunais e pelas Comissões de Protecção de Crianças e Jovens, bem como de suporte à própria comunidade, na protecção e promoção do bem-estar das famílias, crianças e jovens. O modelo apresentado pretende oferecer um enquadramento de base que permita uniformizar práticas e metodologias e facilitar o desenvolvimento de esforços futuros de investigação e avaliação da eficácia dos serviços prestados.The Centros de Apoio Familiar e Aconselhamento Parental (CAFAP, Center for Family Support and Parental Counseling correspond, in the Portuguese reality of Portuguese services, to a category of services designed to support families with at-risk children and youth. However, these services tend to operate in many different ways, still without legal and technical framing. In the present article, one aims to review the CAFAP's objectives and present a Global Organization Model for these services, so they can operate as effective support resources for the activities of the courts, the child protection services and the community in the protection and promotion of families', children's and youth's well-being. With the purpose of creating common practices and methodologies, the proposed model offers a basic framework for the development of future research and evaluation efforts in regard to the efficacy of the services provided.

What do parents think about parental participation in school-based interventions on energy balance-related behaviours? a qualitative study in 4 countries

Directory of Open Access Journals (Sweden)

Van Lippevelde Wendy

2011-11-01

Full Text Available Abstract Background Overweight and obesity in youth has increased dramatically. Therefore, overweight prevention initiatives should start early in life and target modifiable energy balance-related behaviours. Parental participation is often advocated as important for school-based interventions, however, getting parents involved in school-based interventions appears to be challenging based on earlier intervention experiences. The purpose of this study was to get insight into the determinants of and perspectives on parental participation in school-interventions on energy balance-related behaviours (physical activity, healthy eating, sedentary behaviours in parents of ten- to twelve-year olds in order to develop an effective parental module for school-based interventions concerning energy balance-related behaviours. Methods Four countries (Belgium, Hungary, Norway and Spain conducted the focus group research based on a standardised protocol and a semi-structured questioning route. A variation in parental socio-economic status (SES and parental school involvement was taken into account when recruiting the parents. The audio taped interviews were transcribed, and a qualitative content analysis of the transcripts was conducted in each country. Results Seventeen focus group interviews were conducted with a total of 92 parents (12 men, 80 women. Physical activity was considered to be a joint responsibility of school and parents, nutrition as parent's responsibility but supported by the school, and prevention of sedentary behaviours as parent's sole responsibility. Parents proposed interactive and practical activities together with their child as the best way to involve them such as cooking, food tasting, nutrition workshops, walking or cycling tours, sport initiations together with their child. Activities should be cheap, on a convenient moment, focused on their children and not on themselves, not tutoring, not theoretical, and school-or home-based

Group-based antenatal birth and parent preparation for improving birth outcomes and parenting resources: Study protocol for a randomised trial

DEFF Research Database (Denmark)

Koushede, Vibeke; Brixval, Carina Sjöberg; Axelsen, Solveig Forberg

2013-01-01

To examine the efficacy and cost-effectiveness of group based antenatal education for improving childbirth and parenting resources compared to auditorium based education.......To examine the efficacy and cost-effectiveness of group based antenatal education for improving childbirth and parenting resources compared to auditorium based education....

Effectiveness of Mindfulness-Based Parenting Educational Program on the Anxiety, Parent-Child Conflict and Parent Self-Agency in Mothers with Oppositional Defiant Disorder Children

Directory of Open Access Journals (Sweden)

F. Ghazanfari

2017-09-01

Full Text Available Aims: Oppositional defiant disorder that occurs in pre-school or early school-age children and in pre-adolescent stage has a widespread impact on the child, family, teachers and society. The aim of the study was to determine the effect of mindful parenting education program on reducing the anxiety and parent-child conflict and increasing the self-agency of parenting in mothers who have oppositional defiant disorder daughters. Materials & Methods: This semi-experimental study with a pretest-posttest control group was performed during 2015-2016 academic year in 34 mothers of primary school girl students of Noorabad City, Iran, who were suffering from oppositional defiant disorder. The samples were selected by purposeful clustering method and were randomly divided into 2 test and control groups (each had 17 members. The research tools were Child Behavioral Logbook and Teacher Report Form, Beck Anxiety Inventory, Conflict Strategy and Parent Self-efficacy Questionnaires. Mindfulness-based parenting educational program was conducted for the experimental group one 2-hour session a week for 2 months. Data were analyzed by SPSS 23 software using MANCOVA test. Findings: The average of total anxiety, parent-child conflict and parental self-efficacy scores were higher in the experimental group in posttest. After controlling the effect of pre-test scores, there were significant differences between the test and control groups in terms of all variables (p<0.001. Conclusion: Mindfulness-based parenting educational program reduces the anxiety and parent-child conflict and increases the parental self-efficacy in mothers with oppositional defiant disorder.

IMPLEMENTING AN ATTACHMENT-BASED PARENTING INTERVENTION WITHIN HOME-BASED EARLY HEAD START: HOME-VISITORS' PERCEPTIONS AND EXPERIENCES.

Science.gov (United States)

West, Allison L; Aparicio, Elizabeth M; Berlin, Lisa J; Jones Harden, Brenda

2017-07-01

Implementation of evidence-based interventions in "real-world" settings is enhanced when front-line staff view the intervention as acceptable, appropriate, and feasible. This qualitative study addresses Early Head Start (EHS) home visitors' perceptions and experiences of an evidence-based parenting intervention, the Attachment and Biobehavioral Catch-up program (M. Dozier, O. Lindhiem, & J. Ackerman, 2005), when added to EHS services as usual within the context of a research-practice partnership. Thematic analysis of in-depth, qualitative interviews indicates that home visitors experienced the intervention as positive and helpful for EHS families. Some challenges included scheduling and uncertainty regarding the goals of the intervention. Concerns over participation in the research centered on information exchange, confidentiality, and time limitations. © 2017 Michigan Association for Infant Mental Health.

The Maudsley Model of Family-Based Treatment for Anorexia Nervosa: A Qualitative Evaluation of Parent-to-Parent Consultation

Science.gov (United States)

Rhodes, Paul; Brown, Jac; Madden, Sloane

2009-01-01

This article describes the qualitative analysis of a randomized control trial that explores the use of parent-to-parent consultations as an augmentation to the Maudsley model of family-based treatment for anorexia. Twenty families were randomized into two groups, 10 receiving standard treatment and 10 receiving an additional parent-to-parent…

Estresse parental em famílias de crianças com paralisia cerebral: revisão integrativa Parental stress in families of children with cerebral palsy: an integrative review

Directory of Open Access Journals (Sweden)

Celmo Celeno Porto

2013-06-01

Full Text Available O objetivo deste artigo é selecionar, avaliar e interpretar criticamente as publicações que tiveram como foco principal o estresse vivenciado pelos pais/cuidadores de crianças com paralisia cerebral. Revisão integrativa da literatura. A busca foi conduzida na Biblioteca Virtual em Saúde (BVS, no United States National Library of Medicine (PubMED e busca manual de referências nos estudos selecionados. Optou-se por selecionar aqueles publicados no período de 1998 a 2011. Integraram a amostra 13 artigos. Pais de crianças com paralisia cerebral apresentam níveis de estresse maiores do que os de sem deficiência. Os problemas de comportamento, os distúrbios psicológicos e emocionais das crianças foram os fatores mais comumente associados aos maiores níveis de estresse. A satisfação com apoio social, satisfação com o papel de pai/mãe, o bom funcionamento familiar, o vínculo afetivo pai/mãe-filho, o apoio do cônjuge e o sentimento de participar ativamente da vida social contribuem para reduzir os níveis de estresse. A saúde dos pais de crianças com paralisia cerebral está comprometida pelos maiores níveis de estresse. Desta forma, profissionais da saúde devem oferecer uma atenção especial a eles.This article aims to select, evaluate and interpret critically the bibliographic production focused on the stress experienced by parents/caregivers of children with cerebral palsy. An integrative literature review was conducted. Sources for this search were the Virtual Health Library (VHL, the United States National Library of Medicine (PubMed and manual search of references from the selected studies. It was decided to select studies published between 1998 and 2011. The sample included 13 articles. Parents of children with cerebral palsy have higher stress levels than parents of children without disabilities. Behavioral problems, psychological disorders and emotional needs of children were factors commonly associated with high

A smartphone-based ecological momentary assessment of parental behavioral consistency: Associations with parental stress and child ADHD symptoms.

Science.gov (United States)

Li, James J; Lansford, Jennifer E

2018-04-02

Inconsistent parental discipline is a robust correlate of child attention-deficit/hyperactivity disorder (ADHD) symptoms, but few studies have considered the role of inconsistent positive parenting on ADHD, as well as the effects of stress on negative and positive parental consistency. This study advanced a novel ecological momentary assessment (EMA) using participant smartphones to measure parental consistency, and examined its associations with family, social, and parenting-related dimensions of stress and child ADHD symptoms. Participants were 184 kindergartners with and without ADHD and their parents. Harsh and warm dimensions of parental behavior were assessed using questionnaires, observations, and an EMA administered through parents' smartphones, which measured parent-child behaviors every day for a period of 1 week. Family, social, and parenting-related stress were assessed from questionnaires, and child ADHD symptoms were assessed from a fully structured diagnostic interview with the parent. Child ADHD symptoms were associated with variability in warm parenting behaviors, and higher levels of parenting-related stress were related to greater variability in harsh parenting behaviors. No significant interactions were detected between parental stress and child ADHD on parental variability. These findings suggest that different factors influence the consistency in parenting behavior, depending on whether positive parenting or negative parenting is assessed. Parent-based treatment programs for children with ADHD should include a stronger focus on reducing stress from parenting (e.g., teaching coping skills for parents), as this may lead to greater consistency in parental behavior more generally, and presumably better child outcomes. (PsycINFO Database Record (c) 2018 APA, all rights reserved).

Ferrocene: Disposition following nose-only inhalation by the rat

International Nuclear Information System (INIS)

Slauter, R.W.; Tippin, T.K.; Jeffcoat, A.R.; Matthews, H.B.

1990-01-01

Ferrocene (FCN) is a volatile solid organometallic proposed for use as an anti-knock additive in gasoline. Such use would provide significant potential for human exposure via inhalation. Nose-only exposure of male F344 rats over 6 h to constant concentrations of 5 and 25 ng of [ 14 C]FCN/mL air was conducted by blending correct proportions of an air stream concentrated with [ 14 C]FCN vapor with one that was FCN free. Fractional pulmonary absorption of FCN was estimated to be ca. 66 and 55% with concentrations of 14 C in blood increasing steadily throughout the exposure period to 80 and 370 ng-eq of FCN/mL, respectively. Disappearance of 14 C from the blood was multiphasic (terminal t 1/2 =∼2 d) following inhalation exposure, resulting in blood concentrations of 10 and 50 ng-eq of FCN/mL 72 h after end of exposure. More than 80% of the recovered 14 C was in the 0-72 h urine, approximately half of which was a single metabolite (radio-HPLC). Unchanged FCN was excreted in only minor amounts ( 14 C were also excreted in feces (ca. 10% of total) and breath (ca. 4% of total). Neither lung nor nasopharynx had tissue to blood ratios of 14 C>3 72 h after exposure. Similar disposition was shown after an iv bolus of 1.0 mg of [ 14 C]FCN/kg body weight

Parental Perceptions of Child Care Quality in Centre-Based and Home-Based Settings: Associations with External Quality Ratings

Science.gov (United States)

Lehrer, Joanne S.; Lemay, Lise; Bigras, Nathalie

2015-01-01

The current study examined how parental perceptions of child care quality were related to external quality ratings and considered how parental perceptions of quality varied according to child care context (home-based or centre-based settings). Parents of 179 4-year-old children who attended child care centres (n = 141) and home-based settings…

Structural (UV) and carotenoid-based plumage coloration - signals for parental investment?

Science.gov (United States)

Lucass, Carsten; Iserbyt, Arne; Eens, Marcel; Müller, Wendt

2016-05-01

Parental care increases parental fitness through improved offspring condition and survival but comes at a cost for the caretaker(s). To increase life-time fitness, caring parents are, therefore, expected to adjust their reproductive investment to current environmental conditions and parental capacities. The latter is thought to be signaled via ornamental traits of the bearer. We here investigated whether pre- and/or posthatching investment of blue tit (Cyanistes caeruleus) parents was related to ornamental plumage traits (UV crown coloration and carotenoid-based plumage coloration) expressed by either the individual itself (i.e. "good parent hypothesis") or its partner (i.e. "differential allocation hypothesis"). Our results show that neither prehatching (that is clutch size and offspring begging intensity) nor posthatching parental investment (provisioning rate, offspring body condition at fledging) was related to an individual's UV crown coloration or to that of its partner. Similar observations were made for carotenoid-based plumage coloration, except for a consistent positive relationship between offspring begging intensity and maternal carotenoid-based plumage coloration. This sex-specific pattern likely reflects a maternal effect mediated via maternally derived egg substances, given that the relationship persisted when offspring were cross-fostered. This suggests that females adjust their offspring's phenotype toward own phenotype, which may facilitate in particular mother-offspring co-adaptation. Overall, our results contribute to the current state of evidence that structural or pigment-based plumage coloration of blue tits are inconsistently correlated with central life-history traits.

Abriendo Caminos Para La Educacion: A Case Study of a Parent Outreach Initiative Building on the Knowledge, Skills, and Resources of the Latina/o Community

Science.gov (United States)

Fernandez, Graciela

2010-01-01

Informed by research studies that demonstrate a positive relationship between parent engagement and student academic attainment, state and national parent outreach initiatives have aimed to bridge the gap between Latina/o parents and schools. Such was the case with the Latina/o Family, School and Community "Avanzando" Project, which…

Adaptação ao divórcio e relações coparentais: contributos da teoria da vinculação Adjustment to divorce and co-parental relations: contributions from the theory of attachment

Directory of Open Access Journals (Sweden)

Diogo Lamela

2010-01-01

Full Text Available Neste artigo propõe-se uma contribuição da teoria da vinculação na compreensão dos processos de adaptação dos adultos ao seu divórcio e como a desvinculação ao ex-cônjuge interfere na coparentalidade pós-divórcio. Este artigo formula duas hipóteses teóricas. A primeira hipótese afirma que o divórcio, enquanto processo relacional, deve ser lido como um momento de perda que germina reacções psicológicas similares às experienciadas pelos viúvos, tal como descreve Bowlby no modelo de perda da figura de vinculação, estando dependente dos estilos de vinculação dos adultos. A segunda hipótese sustenta que a coparentalidade pós-divórcio é predita pelos estilos de vinculação e pela qualidade da reorganização da vinculação dos pais. Finalmente, uma integração teórica é apresentada, operacionalizada numa proposta de investigação futura neste domínio.In this article, it is proposed the contribution of the attachment theory for understanding adults' adjustment processes to their divorce and how detachment to ex-spouse can infer in co-parenting relationships after marital dissolution. This article makes two theoretical assumptions that focus on two dimensions. The first hypothesis states that the divorce, while a relational process, should be read as a moment of loss that germinates similar psychological reactions to those experienced by widows. Bowlby describes it in his model of loss of the attachment figure as dependent on attachment styles of divorced adults. The second hypothesis argues that the post-divorce co-parenting relationships are predicted by the attachment styles and by the quality of parents' attachment reorganization. At the end, a theoretical integration is built, based on a proposal for future research in this area.

Adaptação cultural e validação para a língua portuguesa da Parental Stress Scale: Neonatal Intensive Care Unit (PSS:NICU Adaptación cultural y validación al idioma português del Parental Stress Scale: Neonatal Intensive Care Unit (PSS:NICU Cultural adaptation and validation for the portuguese language of the Parental Stress Scale: Neonatal Intensive Care Unit (PSS:NICU

Directory of Open Access Journals (Sweden)

Sandra Regina de Souza

2012-01-01

Full Text Available OBJETIVO: Traduzir, realizar a adaptação cultural e validar a escala Parental Stress Scale:Neonatal Intensive Care Unit (PSS:NICU para a língua portuguesa. MÉTODOS: Utilizou-se o método descritivo de validação de instrumentos de medida, baseado nas etapas propostas por Guillemin et al. A análise da confiabilidade foi realizada por meio dos testes e retestes e da consistência interna. Na validação clínica, participaram 163 pais de recém-nascidos internados em Unidade de Terapia Intensiva Neonatal (UTIN. RESULTADOS: Os coeficientes de correlação intraclasse ficaram em torno de 0,70 mostrando boa estabilidade entre as duas avaliações. A análise fatorial pelo método de componentes principais utilizou os mesmos critérios da escala original, com rotação Varimax, com grau de variância adequado de 57,9%. Os maiores níveis de estresse dos pais foram obtidos na subescala "alteração do papel de pais". CONCLUSÃO: A PSS:NICU na versão em português é uma ferramenta válida e confiável para avaliação do estresse de pais com filho internado na UTIN.OBJETIVO: Traducir, realizar la adaptación cultural y validar la escala Parental Stress Scale:Neonatal Intensive Care Unit (PSS:NICU al idioma portugués. MÉTODOS: Se utilizó el método descriptivo de validación de instrumentos de medida, basado en las etapas propuestas por Guillemin et al. El análisis de la confiabilidad fue realizado por medio de los tests y retests y de la consistencia interna. En la validación clínica, participaron 163 padres de recién nacidos internados en una Unidad de Cuidados Intensivos Neonatal (UCIN. RESULTADOS: Los coeficientes de correlación intraclase quedaron alrededor de 0,70 mostrando buena estabilidad entre las dos evaluaciones El análisis factorial por el método de componentes principales utilizó los mismos criterios de la escala original, con rotación Varimax, con grado de varianza adecuado de 57,9%. Los mayores niveles de estrés de

Parents Plus Systemic, Solution-Focused Parent Training Programs: Description, Review of the Evidence Base, and Meta-Analysis.

Science.gov (United States)

Carr, Alan; Hartnett, Dan; Brosnan, Eileen; Sharry, John

2017-09-01

Parents Plus (PP) programs are systemic, solution-focused, group-based interventions. They are designed for delivery in clinical and community settings as treatment programs for families with child-focused problems, such as behavioral difficulties, disruptive behavior disorders, and emotional disorders in young people with and without developmental disabilities. PP programs have been developed for families of preschoolers, preadolescent children, and teenagers, as well as for separated or divorced families. Seventeen evaluation studies involving over 1,000 families have shown that PP programs have a significant impact on child behavior problems, goal attainment, and parental satisfaction and stress. The effect size of 0.57 (p < .001) from a meta-analysis of 10 controlled studies for child behavior problems compares favorably with those of meta-analyses of other well-established parent training programs with large evidence bases. In controlled studies, PP programs yielded significant (p < .001) effect sizes for goal attainment (d = 1.51), parental satisfaction (d = 0.78), and parental stress reduction (d = 0.54). PP programs may be facilitated by trained front-line mental health and educational professionals. © 2016 Family Process Institute.

Estudo bioético dos transplantes renais com doadores vivos não-parentes no Brasil: a ineficácia da legislação no impedimento do comércio de órgãos

OpenAIRE

Passarinho,Lúcia Eugênia Velloso; Gonçalves,Maura Pedroso; Garrafa,Volnei

2003-01-01

OBJETIVO: Conhecer a opinião de cinco diferentes segmentos sociais (promotores públicos, magistrados, população geral, pacientes da lista de espera para transplante renal e profissionais da equipe de transplantes renais do Hospital de Base de Brasília), a respeito da lei que rege a doação de órgãos para transplantes, particularizando a doação de rim por doador vivo não parente, com a nova redação dada pela lei nº 10.211 de 23/03/2001, especificamente em seu artigo 9º, que amplia os critérios ...

A Review of Parent-Based Barriers to Parent-Adolescent Communication about Sex and Sexuality: Implications for Sex and Family Educators

Science.gov (United States)

Malacane, Mona; Beckmeyer, Jonathon J.

2016-01-01

Although adolescents' sexual health is generally better when parents and adolescents communicate about sex and sexuality, researchers have found parents can be reluctant to engage adolescents in conversations about those topics. To better understand why, we reviewed prior literature and identified four types of parent-based barriers to…

Prevalência de abuso físico na infância e exposição à violência parental em uma amostra brasileira Prevalence of physical abuse in childhood and exposure to parental violence in a Brazilian sample

Directory of Open Access Journals (Sweden)

Daniela Viganó Zanoti-Jeronymo

2009-11-01

Full Text Available O estudo objetivou avaliar a prevalência de abuso físico e exposição à violência parental na infância, segundo características sócio-demográficas. Um procedimento de amostragem de múltiplos estágios foi usado para selecionar 3.007 indivíduos de 14 anos de idade ou mais, entre 2005/2006, incluindo sujeitos de todas as regiões do país, assim, os resultados são nacionalmente representativos. Foram acessadas experiências de abuso físico (bater, bater com alguma coisa, queimar/escaldar, ameaçar/usar faca ou arma e exposição à violência parental (testemunhou ameaça e/ou agressão física parental na infância. Realizaram-se as análises através do teste qui-quadrado de Pearson. A prevalência de história de abuso físico na infância foi de 44,1%, sendo que 33,8% relataram história de abuso físico moderado e 10,3% abuso físico severo. A prevalência de exposição à violência parental foi de 26,1%, sendo que 7,5% testemunharam violência parental moderada e 18,6% testemunharam violência parental severa na infância. Análises combinadas entre estes dois tipos de violência demonstraram significativas associações entre elas. Estes resultados podem ajudar na implementação de estratégias de intervenção alertando profissionais de saúde para alta prevalência deste tipo de violência na população.The aim of this study was to investigate the prevalence of physical abuse and exposure to parental violence during childhood, in relation to socio-demographic characteristics. Multi-stage sampling was used to select 3,007 individuals 14 years or older in 2005-2006, from all regions of the country. The study detected cases of physical abuse (beating, striking with objects, burning or scalding, threatening and/or using knives or firearms and exposure to parental violence (witnessing parental threats and/or actual physical aggression during childhood. Analyses were performed with the Pearson chi-square test. Prevalence of

Study of fluorescence quenching due to 2, 3, 5, 6-tetrafluoro-7, 7', 8, 8'-tetracyano quinodimethane and its solid state diffusion analysis using photoluminescence spectroscopy.

Science.gov (United States)

Tyagi, Priyanka; Tuli, Suneet; Srivastava, Ritu

2015-02-07

In this work, we have studied the fluorescence quenching and solid state diffusion of 2, 3, 5, 6-tetrafluoro-7,  7',  8,  8'-tetracyano quinodimethane (F4-TCNQ) using photoluminescence (PL) spectroscopy. Quenching studies were performed with tris (8-hydroxyquinolinato) aluminum (Alq3) in solid state samples. Thickness of F4-TCNQ was varied in order to realize different concentrations and study the effect of concentration. PL intensity has reduced with the increase in F4-TCNQ thicknesses. Stern-Volmer and bimolecular quenching constants were evaluated to be 13.8 M(-1) and 8.7 × 10(8) M(-1) s(-1), respectively. The quenching mechanism was found to be of static type, which was inferred by the independent nature of excited state life time from the F4-TCNQ thickness. Further, solid state diffusion of F4-TCNQ was studied by placing a spacing layer of α-NPD between F4-TCNQ and Alq3, and its thickness was varied to probe the diffusion length. PL intensity was found to increase with the increase in this thickness. Quenching efficiency was evaluated as a function of distance between F4-TCNQ and Alq3. These studies were performed for the samples having 1, 2.5, and 5.5 nm thicknesses of F4-TCNQ to study the thickness dependence of diffusion length. Diffusion lengths were evaluated to be 12.5, 15, and 20 nm for 1, 2.5, and 5.5 nm thicknesses of F4-TCNQ. These diffusion lengths were found to be very close to that of determined by secondary ion mass spectroscopy technique.

Development of an Internet-Based Parent Training Intervention for Children with ASD

Science.gov (United States)

2014-10-01

eHealth . Invited talk at the DOCTRID Conference, Dublin, Ireland. Ingersoll, B. (2014, May) Efficacy of an eHealth -based parent-mediated intervention...PM 40    Appendix C Efficacy of an eHealth -based parent-mediated intervention for young children with ASD: Comparison of two delivery approaches...parent-mediated intervention services is often limited in rural and under-resourced areas. eHealth , the delivery of health information over the

Target-responsive aptamer release from manganese dioxide nanosheets for electrochemical sensing of cocaine with target recycling amplification.

Science.gov (United States)

Chen, Zongbao; Lu, Minghua

2016-11-01

A novel electrochemical sensing platform based on manganese dioxide (MnO2) nanosheets was developed for sensitive screening of target cocaine with the signal amplification. Ferrocene-labeled cocaine aptamers were initially immobilized onto MnO2 nanosheets-modified screen-printed carbon electrode because of π-stacking interaction between nucleobases and nanosheets. The immobilized ferrocene-aptamer activated the electrical contact with the electrode, thereby resulting in the sensor circuit to switch on. Upon target cocaine introduction, the analyte reacted with the aptamer and caused the dissociation of ferrocene-aptamer from the electrode, thus giving rise to the detection circuit to switch off. The released aptamer was cleaved by DNase I with target recycling. Under optimal conditions, the decreasing percentage of the electronic signal relative to background current increased with the increasing cocaine concentration in the dynamic range of 0.1-20nM, and the detection limit was 32pM. The reproducibility, selectivity and method accuracy were acceptable. Importantly, this concept offers promise for rapid, simple, and cost-effective analysis of cocaine biological samples without the needs of sample separation and multiple washing steps. Copyright © 2016 Elsevier B.V. All rights reserved.

School-based influenza vaccination: parents' perspectives.

Directory of Open Access Journals (Sweden)

Candace Lind

Full Text Available School-age children are important drivers of annual influenza epidemics yet influenza vaccination coverage of this population is low despite universal publicly funded influenza vaccination in Alberta, Canada. Immunizing children at school may potentially increase vaccine uptake. As parents are a key stakeholder group for such a program, it is important to consider their concerns.We explored parents' perspectives on the acceptability of adding an annual influenza immunization to the immunization program that is currently delivered in Alberta schools, and obtained suggestions for structuring such a program.Forty-eight parents of children aged 5-18 years participated in 9 focus groups. Participants lived in urban areas of the Alberta Health Services Calgary Zone.Three major themes emerged: Advantages of school-based influenza vaccination (SBIV, Disadvantages of SBIV, and Implications for program design & delivery. Advantages were perceived to occur for different populations: children (e.g. emotional support, families (e.g. convenience, the community (e.g. benefits for school and multicultural communities, the health sector (e.g. reductions in costs due to burden of illness and to society at large (e.g. indirect conduit of information about health services, building structure for pandemic preparedness, building healthy lifestyles. Disadvantages, however, might also occur for children (e.g. older children less likely to be immunized, families (e.g. communication challenges, perceived loss of parental control over information, choices and decisions and the education sector (loss of instructional time. Nine second-level themes emerged within the major theme of Implications for program design & delivery: program goals/objectives, consent process, stakeholder consultation, age-appropriate program, education, communication, logistics, immunizing agent, and clinic process.Parents perceived advantages and disadvantages to delivering annual seasonal

Implementation Evaluation of "Steering Teens Safe": Engaging Parents to Deliver a New Parent-Based Teen Driving Intervention to Their Teens

Science.gov (United States)

Ramirez, Marizen; Yang, Jingzhen; Young, Tracy; Roth, Lisa; Garinger, Anne; Snetselaar, Linda; Peek-Asa, Corinne

2013-01-01

Parents play a fundamental role in teaching their children safe driving skills to reduce risk of motor vehicle crashes, the leading cause of death for teens. "Steering Teens Safe" is a new parent-based intervention that equips parents with communication skills to talk about, demonstrate, and practice safe driving behaviors and skills…

Parents Working Together: development and feasibility trial of a workplace-based program for parents that incorporates general parenting and health behaviour messages.

Science.gov (United States)

Wilson, L; Lero, Donna; Smofsky, Allan; Gross, Deborah; Haines, Jess

2016-11-10

desired direction post-intervention; however, confidence intervals substantially overlapped zero. Contrary to expectations, parents also reported an increase in restrictive feeding practices. Our results indicate that a workplace-based program that addresses general parenting skills and weight-related behaviours may be a feasible way to engage and educate parents, including fathers. A full-scale trial is needed to examine the effectiveness of this approach.

Observational attachment theory-based parenting measures predict children's attachment narratives independently from social learning theory-based measures.

Science.gov (United States)

Matias, Carla; O'Connor, Thomas G; Futh, Annabel; Scott, Stephen

2014-01-01

Conceptually and methodologically distinct models exist for assessing quality of parent-child relationships, but few studies contrast competing models or assess their overlap in predicting developmental outcomes. Using observational methodology, the current study examined the distinctiveness of attachment theory-based and social learning theory-based measures of parenting in predicting two key measures of child adjustment: security of attachment narratives and social acceptance in peer nominations. A total of 113 5-6-year-old children from ethnically diverse families participated. Parent-child relationships were rated using standard paradigms. Measures derived from attachment theory included sensitive responding and mutuality; measures derived from social learning theory included positive attending, directives, and criticism. Child outcomes were independently-rated attachment narrative representations and peer nominations. Results indicated that Attachment theory-based and Social Learning theory-based measures were modestly correlated; nonetheless, parent-child mutuality predicted secure child attachment narratives independently of social learning theory-based measures; in contrast, criticism predicted peer-nominated fighting independently of attachment theory-based measures. In young children, there is some evidence that attachment theory-based measures may be particularly predictive of attachment narratives; however, no single model of measuring parent-child relationships is likely to best predict multiple developmental outcomes. Assessment in research and applied settings may benefit from integration of different theoretical and methodological paradigms.

Ser família : construção, implementação e avaliação de um programa de educação parental

OpenAIRE

Ribeiro, Maria José dos Santos

2003-01-01

A Educação Parental, conceptualizada como uma intervenção que engloba serviços disponibilizados ao nível dos sectores público e privado, a mães e pais de diversos níveis sócio-culturais e económicos, de natureza educativa e preventiva, ou como resposta a situações de crise, tem sido alvo de um interesse crescente, quer a nível internacional, quer designadamente no nosso país. As recentes mudanças ocorridas na estrutura social e familiar, têm vindo a constituir-se como factores que incentiv...

Detecting child abuse based on parental characteristics: does the Hague Protocol cause parents to avoid the emergency department?

Science.gov (United States)

Diderich, Hester M; Fekkes, Minne; Dechesne, Mark; Buitendijk, Simone E; Oudesluys-Murphy, Anne Marie

2015-04-01

The Hague Protocol is used by professionals at the adult Emergency Departments (ED) in The Netherlands to detect child abuse based on three parental characteristics: (1) domestic violence, (2) substance abuse or (3) suicide attempt or self-harm. After detection, a referral is made to the Reporting Center for Child Abuse and Neglect (RCCAN). This study investigates whether implementing this Protocol will lead parents to avoid medical care. We compared the number of patients (for whom the Protocol applied) who attended the ED prior to implementation with those attending after implementation. We conducted telephone interviews (n = 14) with parents whose children were referred to the RCCAN to investigate their experience with the procedure. We found no decline in the number of patients, included in the Protocol, visiting the ED during the 4 year implementation period (2008-2011). Most parents (n = 10 of the 14 interviewed) were positive and stated that they would, if necessary, re-attend the ED with the same complaints in the future. ED nurses and doctors referring children based on parental characteristics do not have to fear losing these families as patients. Copyright © 2014 Elsevier Ltd. All rights reserved.

An Emotional Awareness Based Parenting Group for Parents with Mental Illness: A Mixed Methods Feasibility Study of Community Mental Health Nurse Facilitation.

Science.gov (United States)

Isobel, Sophie; Meehan, Felicity; Pretty, Danielle

2016-02-01

There has been limited examination of the use of relationship based structured parenting programs that focus on emotional interactions in the parent-child dyad in families where a parent has a mental illness. There is also a lack of awareness of the practicalities of providing such interventions within adult mental health services. This study explores the process and outcomes of a nurse led emotional awareness based parenting program for adult clients of a mental health service. Participants demonstrated a significant reduction in difficult parenting moments and associated stress and distress as well as promising improvements in overall distress and emotional awareness. Crown Copyright © 2015. Published by Elsevier Inc. All rights reserved.

Development and preliminary evaluation of culturally specific web-based intervention for parents of adolescents.

Science.gov (United States)

Choi, H; Kim, S; Ko, H; Kim, Y; Park, C G

2016-10-01

WHAT IS KNOWN ON THE SUBJECT?: Problematic parent-child relationships have been identified as one of the main predictors of adolescents' mental health problems, but there are few existing interventions that address this issue. The format and delivery method of existing interventions for parents are relatively inaccessible for parents with full-time jobs and families living in rural areas. WHAT DOES THIS PAPER ADD TO EXISTING KNOWLEDGE?: The newly developed 'Stepping Stone' culturally specific web-based intervention, which is intended to help Korean parents of adolescents to acquire both knowledge and communication and conflict management skills, was found to be feasible and well-accepted by parents. This study enabled us to identify areas for improvement in the content and format of the intervention and strategies. This will potentially increase effect sizes for the outcome variables of parents' perception and behaviours. WHAT ARE THE IMPLICATIONS FOR PRACTICE?: This web-based intervention could be delivered across diverse settings, such as schools and community mental health centers, to increase parents' knowledge of adolescent's mental health and allow for early detection of mental health problems. Mental health nurses working in schools may spend a significant amount of time addressing students' mental health issues; thus, this web-based intervention could be a useful resource to share with parents and children. In this way, the mental health nurses could facilitate parental engagement in the intervention and then help them to continue to apply and practice the knowledge and skills obtained through the program. Introduction There is a need for accessible, culturally specific web-based interventions to address parent-child relationships and adolescents' mental health. Aims This study developed and conducted a preliminary evaluation of a 4-week web-based intervention for parents of adolescents aged 11 to 16 years in Korea. Methods We used a two-group, repeated

Exploring the Impact of Parental Psychopathology and Emotion Regulation on Evidence-Based Parenting Interventions: A Transdiagnostic Approach to Improving Treatment Effectiveness

Science.gov (United States)

Maliken, Ashley C.; Katz, Lynn Fainsilber

2013-01-01

Parenting interventions, particularly those categorized as parent management training (PMT), have a large evidence base supporting their effectiveness with most families who present for treatment of childhood behavior problems. However, data suggest that PMTs are not effective at treating all families who seek services. Parental psychopathology…

Analyses of residual iron in carbon nanotubes produced by camphor/ferrocene pyrolysis and purified by high temperature annealing

Energy Technology Data Exchange (ETDEWEB)

Antunes, E.F., E-mail: ericafa@las.inpe.br [Instituto Tecnologico de Aeronautica (ITA), Praca Marechal Eduardo Gomes, 50, CEP 12.228-900, Sao Jose dos Campos, SP (Brazil); Instituto Nacional de Pesquisas Espaciais (INPE), Av. dos Astronautas, 1758, CEP 12.227-010, Sao Jose dos Campos, SP (Brazil); Resende, V.G. de; Mengui, U.A. [Instituto Nacional de Pesquisas Espaciais (INPE), Av. dos Astronautas, 1758, CEP 12.227-010, Sao Jose dos Campos, SP (Brazil); Cunha, J.B.M. [Universidade Federal do Rio Grande do Sul (UFRGS), Av. Bento Goncalves, 9500, CEP 91.501-970, Porto Alegre, RS (Brazil); Corat, E.J.; Massi, M. [Instituto Nacional de Pesquisas Espaciais (INPE), Av. dos Astronautas, 1758, CEP 12.227-010, Sao Jose dos Campos, SP (Brazil)

2011-07-01

A detailed analysis of iron-containing phases in multiwall carbon nanotube (MWCNT) powder was carried out. The MWCNTs were produced by camphor/ferrocene and purified by high temperature annealing in an oxygen-free atmosphere (N{sub 2} or VC). Thermogravimetric analysis, Moessbauer spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy enabled the evaluation of the residual iron in MWCNTs after purification. The VC treatments provided MWCNTs with a purity degree higher than 99%. Moreover, Raman spectroscopy revealed a significant improvement in graphitic ordering after thermal annealing. A brief description of the mechanism of iron removal was included. We highlight the mobility of iron atoms through graphitic sheets and the large contact angle of iron clusters formed on MWCNT surfaces at high temperatures.

A Parent-to-Parent Program in Taiwan

Science.gov (United States)

Liu, Kae

2018-01-01

Parent-to-parent programs provide emotional and informational support to parents of children with special needs by matching trained and experienced parents with parents needing support. This study examined the implementation and effects of a Parent-to-Parent Program in Taiwan that supported 3 families of youngsters with special needs. Based on the…

School-Based Health Promotion Intervention: Parent and School Staff Perspectives

Science.gov (United States)

Patino-Fernandez, Anna M.; Hernandez, Jennifer; Villa, Manuela; Delamater, Alan

2013-01-01

Background: The prevalence of childhood obesity is high, particularly among minority youth. The objective of this article was to evaluate parent and school staff perspectives of childhood health and weight qualitatively to guide the development of a school-based obesity prevention program for minority youth. Methods: Hispanic parents (N?=?9) of…

Parent Perspectives on Home-Based Intervention for Young Children with Developmental Disabilities: The Parent-Implemented Communication Strategies (PiCS) Project in Illinois, USA

Science.gov (United States)

Meadan, Hedda; Stoner, Julia B.; Angell, Maureen E.

2015-01-01

Parents' perspectives on a home-based, parent-implemented social-pragmatic communication intervention for young children aged 37 to 60 months with limited expressive language are presented in this report. The researchers analyzed the perspectives of seven parent participants in the Institute of Education Sciences-funded Parent-Implemented…

Molecular design of novel fullerene-based acceptors for enhancing the open circuit voltage in polymer solar cells

Science.gov (United States)

Tajbakhsh, Mahmood; Kariminasab, Mohaddeseh; Ganji, Masoud Darvish; Alinezhad, Heshmatollah

2017-12-01

Organic solar cells, especially bulk hetero-junction polymer solar cells (PSCs), are the most successful structures for applications in renewable energy. The dramatic improvement in the performance of PSCs has increased demand for new conjugated polymer donors and fullerene derivative acceptors. In the present study, quantum chemical calculations were performed for several representative fullerene derivatives in order to determine their frontier orbital energy levels and electronic structures, thereby helping to enhance their performance in PSC devices. We found correlations between the theoretical lowest unoccupied molecular orbital levels and electrophilicity index of various fullerenes with the experimental open circuit voltage of photovoltaic devices according to the poly(3-hexylthiophene) (P3HT):fullerene blend. The correlations between the structure and descriptors may facilitate screening of the best fullerene acceptor for the P3HT donor. Thus, we considered fullerenes with new functional groups and we predicted the output factors for the corresponding P3HT:fullerene blend devices. The results showed that fullerene derivatives based on thieno-o-quinodimethane-C60 with a methoxy group will have enhanced photovoltaic properties. Our results may facilitate the design of new fullerenes and the development of favorable acceptors for use in photovoltaic applications.

Parents Working Together: development and feasibility trial of a workplace-based program for parents that incorporates general parenting and health behaviour messages

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L. Wilson

2016-11-01

parents’ reports of family interfering with work were in the desired direction post-intervention; however, confidence intervals substantially overlapped zero. Contrary to expectations, parents also reported an increase in restrictive feeding practices. Conclusion Our results indicate that a workplace-based program that addresses general parenting skills and weight-related behaviours may be a feasible way to engage and educate parents, including fathers. A full-scale trial is needed to examine the effectiveness of this approach.

Competing Paradigms of Educational Justice: Parent Organizing for Educational Equity in a Neoliberal Reform Context

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Nygreen, Kysa

2016-01-01

This article examines a grassroots parent organizing effort in a large, high-poverty, urban school district. Drawing from ethnographic field research at a community-based popular education organization, the study describes how parent organizers worked to educate and mobilize Latina/o immigrant parents on issues of educational justice and equity.…

Facial emotion recognition deficits in relatives of children with autism are not associated with 5HTTLPR Prejuízos no reconhecimento de emoções faciais em parentes de primeiro grau de portadores de autismo não são associados com o polimorfismo 5HTTLPR

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Maila de Castro Lourenço das Neves

2011-09-01

Full Text Available OBJECTIVE: A large body of evidence suggests that several aspects of face processing are impaired in autism and that this impairment might be hereditary. This study was aimed at assessing facial emotion recognition in parents of children with autism and its associations with a functional polymorphism of the serotonin transporter (5HTTLPR. METHOD: We evaluated 40 parents of children with autism and 41 healthy controls. All participants were administered the Penn Emotion Recognition Test (ER40 and were genotyped for 5HTTLPR. RESULTS: Our study showed that parents of children with autism performed worse in the facial emotion recognition test than controls. Analyses of error patterns showed that parents of children with autism over-attributed neutral to emotional faces. We found evidence that 5HTTLPR polymorphism did not influence the performance in the Penn Emotion Recognition Test, but that it may determine different error patterns. CONCLUSION: Facial emotion recognition deficits are more common in first-degree relatives of autistic patients than in the general population, suggesting that facial emotion recognition is a candidate endophenotype for autism.OBJETIVO: Diversos estudos sugerem que o processamento de emoções faciais está prejudicado em portadores de autismo e que tal prejuízo possa ser hereditário. Nós estudamos o reconhecimento de emoções faciais em parentes de primeiro grau de portadores de autismo e suas associações com o polimorfismo funcional de transportador de serotonina (5HTTLPR. MÉTODO: Foram avaliados 40 parentes de primeiro grau de portadores de autismo e 41 controles saudáveis. Todos os participantes foram submetidos ao Teste de Reconhecimento de Emoções (ER40 da Bateria Neuropsicológica Computadorizada da Universidade da Pensilvânia (PENNCNP e genotipados para o 5HTTLPR. RESULTADOS: Os parentes de primeiro grau de portadores de autismo apresentaram pior reconhecimento de emoções faciais comparados aos

Parent Interest in a School-Based, School Nurse-Led Weight Management Program

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Kubik, Martha Y.; Lee, Jiwoo

2014-01-01

Because one in three children is already overweight or obese, school-based interventions targeting secondary obesity prevention merit consideration. This study assessed parent interest in participating in a school-based, school nurse-led weight management program for young school-aged children. A random sample of parents ("n" = 122) of…

The Investigation of Research-Based Home Parental Involvement Practices, Parental Style, and Student Achievement

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Colson, Myron Jamal

2010-01-01

The purpose of the study was to investigate the relationship of home parental involvement practices, parental style and student achievement. Dimensions of parental involvement practices are parental instruction, parental reinforcement, parental modeling, and parental encouragement. Dimensions of parental style are authoritarian, permissive, and…

Using Consumer Preference Information to Increase the Reach and Impact of Media-Based Parenting Interventions in a Public Health Approach to Parenting Support

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Metzler, Carol W.; Sanders, Matthew R.; Rusby, Julie C.; Crowley, Ryann N.

2012-01-01

Within a public health approach to improving parenting, the mass media offer a potentially more efficient and affordable format for directly reaching a large number of parents with evidence-based parenting information than do traditional approaches to parenting interventions that require delivery by a practitioner. Little is known, however, about…

Graphene by one-step chemical vapor deposition from ferrocene vapors: Properties and electrochemical evaluation

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Pilatos, George; Perdikaki, Anna V.; Sapalidis, Andreas; Pappas, George S.; Giannakopoulou, Tatiana; Tsoutsou, Dimitra; Xenogiannopoulou, Evangelia; Boukos, Nikos; Dimoulas, Athanasios; Trapalis, Christos; Kanellopoulos, Nick K.; Karanikolos, Georgios N.

2016-02-01

Growth of few-layer graphene using ferrocene as precursor by chemical vapor deposition is reported. The growth did not involve any additional carbon or catalyst source or external hydrocarbon gases. Parametric investigation was performed using different conditions, namely, varying growth temperature from 600 to1000 °C, and growth duration from 5 min to 3 h, as well as using fast quenching or gradual cooling after the thermal treatment, in order to examine the effect on the quality of the produced graphene. The growth took place on silicon wafers and resulted, under optimal conditions, in formation of graphene with 2-3 layers and high graphitic quality, as evidenced by Raman spectroscopy, with characteristic full width at half maximum of the 2D band of 49.46 cm-1, and I2D/IG and ID/IG intensity ratios of 1.15 and 0.26, respectively. Atomic force microscopy and X-ray photoelectron spectroscopy were employed to further evaluate graphene characteristics and enlighten growth mechanism. Electrochemical evaluation of the developed material was performed using cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge-discharge measurements.

MATERNAL PERCEPTIONS OF PARENTING FOLLOWING AN EVIDENCE-BASED PARENTING PROGRAM: A QUALITATIVE STUDY OF LEGACY FOR CHILDRENTM.

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Hartwig, Sophie A; Robinson, Lara R; Comeau, Dawn L; Claussen, Angelika H; Perou, Ruth

2017-07-01

This article presents the findings of a qualitative study of maternal perceptions of parenting following participation in Legacy for Children TM (Legacy), an evidence-based parenting program for low-income mothers of young children and infants. To further examine previous findings and better understand participant experiences, we analyzed semistructured focus-group discussions with predominantly Hispanic and Black, non-Hispanic Legacy mothers at two sites (n = 166) using thematic analysis and grounded theory techniques. The qualitative study presented here investigated how mothers view their parenting following participation in Legacy, allowing participants to describe their experience with the program in their own words, thus capturing an "insider" perspective. Mothers at both sites communicated knowledge and use of positive parenting practices targeted by the goals of Legacy; some site-specific differences emerged related to these parenting practices. These findings align with the interpretation of quantitative results from the randomized controlled trials and further demonstrate the significance of the Legacy program in promoting positive parenting for mothers living in poverty. This study emphasizes the importance of understanding real-world context regarding program efficacy and the benefit of using qualitative research to understand participant experiences. © 2017 Michigan Association for Infant Mental Health.

Are single-parent families different from two-parent families in the treatment of adolescent bulimia nervosa using family-based treatment?

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Doyle, Angela Celio; McLean, Carmen; Washington, Blaine N; Hoste, Renee Rienecke; le Grange, Daniel

2009-03-01

To examine whether family-based treatment (FBT) for adolescent bulimia nervosa (BN), which emphasizes family involvement in helping to reduce binge eating and purging behaviors, is differentially efficacious in single-parent families versus two-parent families. Forty-one adolescents (97.6% female; 16.0 +/- 1.7 years old) with either BN (n = 18) or subthreshold BN (n = 23) were randomized to FBT as part of a larger randomized controlled trial studying treatments for adolescent BN. Two-parent (n = 27; 65.9%) and single-parent (n = 14; 34.2%) families were compared on demographic variables, presence of comorbid psychiatric illnesses, and symptoms of BN at baseline, post, and 6-month follow-up. ANOVA and chi-square analyses revealed no statistically significant differences between two-parent and single-parent families on any variables with the exception of ethnicity, for which a greater proportion of Caucasians and Hispanic families had two- parent families compared with African-American families (chi(2) = 8.68, p = .01). These findings suggest that FBT may be an appropriate and efficacious treatment for single-parent families as well as two-parent families, despite the reliance on parental intervention to reduce bulimic symptoms and normalize eating patterns.

Self-concept, academic performance and behavioral evaluation of the children of alcoholic parents Autoconceito, desempenho escolar e avaliação comportamental de crianças filhas de alcoolistas

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Daniela Viganó Zanoti-Jeronymo

2005-09-01

Full Text Available OBJECTIVE: It has been shown that being the child of an alcoholic is a risk factor for the development of alcoholism in adulthood. Due to the suffering caused by living with alcoholic parents, other vulnerabilities appear in such children. Among these are low self-esteem, poor academic performance and behavioral problems. This work aims to comparatively evaluate children of alcoholic parents and children of nonalcoholic parents. METHODS: The study design was quasi-experimental, involving two comparison groups. Two groups of 20 children were selected. The groups consisted of 10- to 12-year-old male and female children. One group comprised children of alcoholic parents, whereas the other comprised children of nonalcoholic parents. The self-concepts of these children were evaluated using the Piers-Harris Children's Self-Concept Scale as well as the Academic Performance Test. Their mothers participated in the study by answering questions related to the behavior of their children on the Rutter A2 scale of Child Behavior. RESULTS: The results showed that the children of alcoholic parents tended to have more negative self-concepts and presented lower academic performance in reading and arithmetic than did children of nonalcoholic parents. Based on the responses given by the mothers, the children of alcoholic parents presented more behavioral problems than did those of nonalcoholic parents. CONCLUSIONS: The results of this study confirm those of other studies and call attention to the need to be aware of the potential vulnerabilities of children of alcoholic parents and, especially, to try to minimize such vulnerabilities, thereby altering the course of psychological suffering that can mark their lives.OBJETIVO: A literatura vem mostrando que ser filho de alcoolista é um fator de risco para o desenvolvimento de alcoolismo na idade adulta. Além do sofrimento ocasionado pela convivência com pais alcoolistas, essa condição implica em outras

Screen-Printed Photochromic Textiles through New Inks Based on SiO2@naphthopyran Nanoparticles.

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Pinto, Tânia V; Costa, Paula; Sousa, Céu M; Sousa, Carlos A D; Pereira, Clara; Silva, Carla J S M; Pereira, Manuel Fernando R; Coelho, Paulo J; Freire, Cristina

2016-10-26

Photochromic silica nanoparticles (SiO 2 @NPT), fabricated through the covalent immobilization of silylated naphthopyrans (NPTs) based on 2H-naphtho[1,2-b]pyran (S1, S2) and 3H-naphtho[2,1-b]pyran (S3, S4) or through the direct adsorption of the parent naphthopyrans (1, 3) onto silica nanoparticles (SiO 2 NPs), were successfully incorporated onto cotton fabrics by a screen-printing process. Two aqueous acrylic- (AC-) and polyurethane- (PU-) based inks were used as dispersing media. All textiles exhibited reversible photochromism under UV and solar irradiation, developing fast responses and intense coloration. The fabrics coated with SiO 2 @S1 and SiO 2 @S2 showed rapid color changes and high contrasts (ΔE* ab = 39-52), despite presenting slower bleaching kinetics (2-3 h to fade to the original color), whereas the textiles coated with SiO 2 @S3 and SiO 2 @S4 exhibited excellent engagement between coloration and decoloration rates (coloration and fading times of 1 and 2 min, respectively; ΔE* ab = 27-53). The PU-based fabrics showed excellent results during the washing fastness tests, whereas the AC-based textiles evidenced good results only when a protective transfer film was applied over the printed design.

Family-Based Obesity Prevention: Perceptions of Canadian Parents of Preschool-Age Children.

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O'Kane, Carley; Wallace, Angela; Wilson, Laura; Annis, Angela; Ma, David W L; Haines, Jess

2018-03-01

Our objectives were to explore the perspectives of a community-based sample of Canadian parents with 2-5-year-old children on: (i) strategies to support the development of healthful weight-related behaviours and (ii) assessment approaches to measure weight-related behaviours and outcomes among children and families. We conducted 4 focus groups with 28 parents (89% mothers and 68% identified as White). Transcripts were analyzed using conventional content analysis. Regarding parent's perceptions of strategies to support healthful behaviours, we found that parents largely valued: home-based interventions, expert opinion, practical health behaviour strategies delivered in a nonjudgmental manner, and opportunities for social support. Regarding perceptions of assessment procedures, parents had mixed views on children providing blood samples, but looked upon it more favourably if it would contribute to research on child health. Our results suggest that to increase parental engagement interventions focused on improving weight-related behaviours among families with young children should be delivered within the home and include easy-to-implement behaviour change strategies communicated by experts, such as dietitians working in the clinical or public health setting. Using social media to share information and provide a platform for social support may also be an effective way to engage parents of young children.

Novel organometallic aromatic polyester based on ferrocene

Institute of Scientific and Technical Information of China (English)

Wei

2010-01-01

A novel polyester containing ferrocenyl was prepared by low-temperature interface polycondensation of 1,1'-ferrocenedi-carboxylic acid chloride with 4-(4-hydroxyphenyl)-2,3-phthalazin-l-one(DHPZ), which is a twisted non-coplanar heterocyclic bisphenol-like monomer. The newly generated polymer was evaluated based on characterization of its solubility, viscosity measurements, elemental analysis, FTIR spectroscopy, differential scanning calorimetric and thermogravimetric studies.

PAIS BIÓGRAFOS. ESCRITURAS PARENTAIS E DIÁRIOS DE NASCIMENTO (Tradução. PARENT BIOGRAPHERS. FAMILY SCRIPTURES AND BIRTH DIARIES (Translation

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Francis, Véronique

2011-11-01

Full Text Available Este artigo analisa as escrituras parentais acerca do nascimento e da primeira infância. Fragmentos biográficos ou enunciados desenvolvidos acompanhados ou não de fotografia, estas escrituras podem se inserir nas seções de um diário de nascimento no setor de edição, ser arquivadas em um caderno em nome da criança ou fixadas na Internet por meio do formato eletrônico do blog. Vários estudos qualitativos (FRANCIS, 2006, 2007, 2010 permitiram cruzar diferentes tipos de dados: a estrutura e a organização do diário de nascimento, os textos realizados pelos futuros pais e parentes, assim como, as entrevistas realizadas com as famílias – pais e filhos – tendo por objetivo abordar as práticas familiares em torno destes objetos. Os resultados mostram que as escrituras parentais demonstram as representações sobre a família, a infância e sobre o papel dos pais. Na fronteira entre as “escritas de si” e as “escritas para os outros” (SIMONET-TENANT, 2001; LEJEUNE ET BOGAERT, 2006, os diários de nascimento podem ser definidos como objetos de conotação memorial. Eles são uma oportunidade para as atividades de linguagem que buscam, em primeiro lugar, fixar pela escrita e pela imagem a história familiar e, em segundo lugar, para evocar e transmitir a memória familiar. Se o estudo das práticas familiares em torno dos blogs e dos diários de nascimento destacam as figuras dos pais biógrafos (FRANCIS, 2006 e o papel da criança, o estudo situa igualmente a atividade biográfica dos pais em sua extensão socializadora. This paper examines the parental writings about birth and infancy. Biographic fragments or texts, with or without photographies, can fit into the sections of a baby record book. They can also be archived in babies’ diaries or on the Internet, in the family’s blog. Several qualitative researches (FRANCIS, 2006, 2007, 2010 cross various types of data: the structure and the organization of babies’ books, texts

Indecisão profissional, ansiedade e depressão na adolescência: a influência dos estilos parentais Vocational indecision, anxiety and depression in adolescence: The influence of parenting styles

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Claudio Simon Hutz

2006-06-01

Full Text Available Este estudo investigou a influência dos estilos parentais percebidos sobre os níveis de indecisão profissional, ansiedade e depressão de adolescentes. Participaram do estudo 467 adolescentes, de 15 a 20 anos, estudantes do último ano do ensino médio em Porto Alegre. Os instrumentos utilizados foram um Questionário Sóciodemográfico, uma Escala de Indecisão Profissional, uma Escala de Estilos Parentais e os Inventários Beck de Ansiedade e Depressão. Houve correlação positiva entre indecisão, ansiedade e depressão. Filhos de pais autoritários e negligentes apresentaram maior depressão e ansiedade do que os outros. Os estilos parentais não influenciaram diretamente a indecisão profissional, mas sim o bem-estar psicológico dos adolescentes, indicando que o padrão de interação familiar é fundamental para o entendimento de como a indecisão está sendo vivenciada. Assim, enfatiza-se a importância do trabalho relativo à saúde emocional e à interação familiar nos processos de Orientação Profissional.This study investigated perceived parenting styles and its influence on adolescents' vocational indecision, anxiety, and depression. Participants were 467 male and female high school students, aged 15 to 20 years old in Porto Alegre. Instruments were a demographic questionnaire, Beck Depression and Anxiety Inventories and scales to measure vocational indecision and perceived parenting styles. Positive correlation was found between indecision, anxiety, and depression. Adolescents from authoritarian and neglectful families scored significantly higher than others in depression and anxiety. Parenting styles had no direct influence on vocational indecision, but on adolescents' well being, suggesting that family interaction patterns are important to understand how indecision is been experienced. This study concludes that professional guidance processes must include family interaction aspects and must focus on adolescents' mental

Criteria Based Case Review: The Parent Child Psychological Support Program

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Pilar Bujia-Couso

2010-01-01

Full Text Available The Parent Child Psychological Support Program (PCPS was established in an area of South West Dublin in 2001. Since then until May 2008 it has offered its services to over 700 children and their parents. This preventative, parenting support service is available to all parents of children aged 3 to 18 months within its catchment area. During periodical visits, the infant’s development and growth are measured and parents receive specific information about their child’s progress. Parents are empowered in their parenting practices, thus promoting consistency and synchrony in parent-child interaction. Between 2001 and 2006, 538 parents and their infants participated in the Program. Out of these cases, 130 (24.16% were considered to require additional support and were included in the Monthly Meeting Case Review (MM based on initial concerns The aims of this study were: 1. to review the first five years of MM cases and to explore the socio-demographic profile of the MM cases in comparison to those not in need of additional support (non-MM and 2. To illustrate an approach to refining the case review process which will inform practice and provides the service providers with better understanding of the early detection of parent-child relation difficulties. In pursuing this goal the cases screened over five years of practice were analyzed to explore the structure of the different factors by using statistical techniques of data reduction, i.e. factor analysis. The results showed that the MM group differed on several socio-demographic dimensions from the non-MM group and there was a four factor structure underlying the case review decision process. Implications of this research are discussed.

Multimedia based health information to parents in a pediatric acute ward: a randomized controlled trial.

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Botngård, Anja; Skranes, Lars P; Skranes, Jon; Døllner, Henrik

2013-12-01

To determine whether multimedia based health information presented to parents of children with breathing difficulties in a pediatric acute ward, is more effective than verbal information, to reduce parental anxiety and increase satisfaction. This randomized controlled trial was conducted in a pediatric acute ward in Norway, from January to March 2011. Parents were randomly assigned to a multimedia intervention (n=53), or verbal health information (n=48). Primary outcome measure was parental anxiety, and secondary outcome measures were parental satisfaction with nursing care and health information. Parental anxiety decreased from arrival to discharge within both groups. At discharge the anxiety levels in the intervention group were no lower than in the control group. There was no difference in satisfaction with nursing care between the groups, but parents in the intervention group reported higher satisfaction with the health information given in the acute ward (p=.005). Multimedia based health information did not reduce anxiety more than verbal information, among parents to children with breathing difficulties. However, after discharge the parents were more satisfied with the multimedia approach. More research is needed to recommend the use of multimedia based information as a routine to parents in pediatric emergency care. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

CuO reduction induced formation of CuO/Cu2O hybrid oxides

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Yuan, Lu; Yin, Qiyue; Wang, Yiqian; Zhou, Guangwen

2013-12-01

Reduction of CuO nanowires results in the formation of a unique hierarchical hybrid nanostructure, in which the parent oxide phase (CuO) works as the skeleton while the lower oxide (Cu2O) resulting from the reduction reaction forms as partially embedded nanoparticles that decorate the skeleton of the parent oxide. Using in situ transmission electron microscopy observations of the reduction process of CuO nanowires, we demonstrate that the formation of such a hierarchical hybrid oxide structure is induced by topotactic nucleation and growth of Cu2O islands on the parent CuO nanowires.

Parenting Styles and Dimensions Questionnaire - versão portuguesa de autorrelato

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Marta Figueiredo Pedro

2015-06-01

Full Text Available Os estilos parentais educativos constituem um conceito central na área de estudos da parentalidade e do desenvolvimento infantil. Neste sentido, décadas de investigação demonstram o impacto dos estilos parentais em vários aspectos do ajustamento socioemocional da criança e do adolescente. Este estudo teve como objetivo avaliar as propriedades psicométricas e a validade fatorial da versão portuguesa de autorrelato do Parenting Styles and Dimensions Questionnaire. A amostra foi constituída por 2081 indivíduos portugueses (1085 mães; 996 pais com filhos dos 3 aos 15 anos. Os resultados da análise fatorial confirmatória replicaram a estrutura original de três fatores: autoritativo, autoritário e permissivo. Os índices de ajustamento revelaram uma boa adequação do modelo aos dados. Os níveis de consistência interna dos fatores autoritativo e autoritário revelaram-se adequados, mas o fator permissivo apresentou valores ligeiramente abaixo dos aceitáveis. Os valores de validade convergente e discriminante também se revelaram adequados. Apesar dos níveis menos aceitáveis de consistência interna do factor permissivo, o QDEP revelou, em geral, qualidades psicométricas adequadas para fins de investigação e clínicos, permitindo não só a avaliação de estilos parentais como também de diferentes dimensões e comportamentos parentais com impacto relevante no ajustamento socioemocional da criança e do adolescente.

Educação parental na transição e adaptação das crianças portuguesas da pré-escola ao 1º Ciclo do Ensino Básico

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Martins, Ernesto; Martins, Susana

2017-01-01

A educação parental é um recurso psicoeducativo, relacional e comunicacional na adaptação escolar. A entrada das crianças no ensino básico, provenientes da pré-escola (transição), é um momento de mudanças para elas e para os pais. A literatura, em geral, refere como fatores essenciais para o sucesso dessa adaptação escolar: o contexto; a família; a escola; a etnia, a cultura e linguagem; as características pessoais da criança. O estudo realizou-se em 2014, numa turma (N= 24 alunos) de uma esc...

Parenting Styles and Dimensions Questionnaire — Adaptação da Versão Portuguesa de Heterorrelato

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Filipa Nunes

2018-01-01

Full Text Available O presente estudo procura analisar as propriedades psicométricas do Parenting Styles and Dimension Questionnaire (PSDQ e adaptar para a população portuguesa a sua versão de heterorrelato. A amostra foi constituída por 604 ado-lescentes com idades entre os 15 e os 18 anos (M=15.99, DP=.97. A confiabilidade foi avaliada através do alfa de Cronbach, que revelou índices de .86/.81 para a totalidade do instrumento na versão do pai e da mãe respetivamente, e índices que variaram entre .48/.85 para as respetivas subescalas. A análise fatorial confirmatória evidenciou que os índices de ajustamento apresentaram valores desajustados. Confirmou-se a estrutura original do instrumento organizada em três fatores mediante as análises de componentes principais que revelaram a presença de um item do estilo permissivo a saturar noutro fator. Através da análise semântica deste item e da sua respetiva reorganização, verificaram-se índices de ajustamento adequados. Propõe-se a nova estrutura fatorial do PSDQpor se considerar que é mais ajustada à cultura portuguesa.

The effect of telephone-based cognitive-behavioural therapy on parenting stress: A randomised controlled trial.

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Ngai, Fei Wan; Wong, Paul Wai-Ching; Chung, Ka Fai; Leung, Kwok Yin

2016-07-01

Objective Stress related to parenting has detrimental effects on the well-being of children, parents and the family system as a whole. There are limited studies about the efficacy of cognitive-behavioural therapy delivered by telephone in reducing parenting stress. The present study investigates the effect of telephone-based cognitive-behavioural therapy on parenting stress at six weeks and six months postpartum. This is a multi-site randomised controlled trial. A total of 397 Chinese mothers at risk of postnatal depression were randomly assigned to receive either telephone-based cognitive-behavioural therapy or routine postpartum care. Parental stress was assessed by the Parenting Stress Index Short Form at six weeks and six months postpartum. The findings revealed that mothers who had received telephone-based cognitive-behavioural therapy showed significantly lower levels of parenting stress than women only receiving routine postpartum care at six weeks (mean difference=9.42, 95% confidence interval 5.85-12.99, pparenting and reducing stress during the transition period. Integration of telephone-based cognitive-behavioural therapy into routine postpartum care might facilitate positive adaptation in particular for mothers at risk of postnatal depression. Copyright © 2016. Published by Elsevier Inc.

DEGRADAÇÃO DO VÍNCULO PARENTAL E VIOLÊNCIA CONTRA A CRIANÇA: O USO DO GENOGRAMA FAMILIAR NA PRÁTICA CLÍNICA PEDIÁTRICA

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Égle Thomaz Leoncio

Full Text Available RESUMO Objetivo: Demonstrar a importância da utilização do genograma familiar na consulta pediátrica como ferramenta de análise da presença de degradação do vínculo parental e da violência contra a criança. Métodos: Estudo qualitativo, conduzido em 2011. A população compreendeu 63 crianças, com idades entre 2 e 6 anos, matriculadas em creche. Para a construção do genograma, a coleta dos dados se deu em quatro momentos: avaliação pediátrica na creche; entrevista dos cuidadores; entrevista dos professores; e entrevista da coordenadora da creche. Foram utilizados os dados sobre as famílias para a construção dos genogramas, com auxilio do programa GenoPro®-2016. Na avaliação da qualidade de vínculo, foram incluídos na representação do genograma: violência contra a criança, dependência química, negligência, transtorno mental, tipo de relação entre os membros da família. Resultados: As crianças e respectivas famílias avaliadas deram origem a 55 genogramas. Em 38 deles, observaram-se arranjos familiares funcionais e com vínculos afetivos próximos ou muito próximos. Em 17 dos casos, evidenciaram-se situações que envolviam violência física, emocional ou sexual contra as crianças. Dentre esses, quatro representavam casos mais extremos, com esgarçamento do vinculo parental e arranjos familiares disfuncionais. Nessas famílias predominava a dependência química de múltiplos membros, transtorno mental grave, agressões física e verbal persistentes e abuso sexual. Conclusões: A utilização do genograma auxilia na identificação precoce da degradação do vínculo parental e da violência praticada contra a criança e, quando incorporada à prática pediátrica rotineira, pode contribuir para a promoção de uma assistência integral à saúde da criança, independentemente da presença de vulnerabilidades social.

Trabalho de casa, tarefas escolares, auto-regulação e envolvimento parental Homework, self-regulated learning and parent involvement

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Pedro Rosário

2005-12-01

Full Text Available Urge entender o Trabalho de Casa (TPC como processo complexo para o qual conflui um vasto leque de factores impactantes. Neste relato analisam-se as relações entre os perfis de atitudes e comportamentos diante do TPC de Inglês e o nível instrutivo dos pais, a auto-eficácia percebida nessa disciplina bem como a correlação entre tais perfis de TPC e os perfis auto-regulatórios, em face do estudo. A amostra tomada é composta de 3929 alunos. O nível instrutivo dos pais associa-se positiva e significativamente aos perfis de atitudes e comportamentos de TPC. As atitudes e comportamentos de TPC correlacionam-se, positiva e significativamente, com os perfis auto-regulatórios, diante do estudo. Alunos que se percepcionam como mais auto-eficazes registam melhores perfis de atitudes e comportamentos de TPC. Os resultados sugerem a necessidade de os diferentes parceiros do sistema educativo analisarem e promoverem activamente os processos auto-regulatórios envolvidos no ensino-aprendizagem em geral e no TPC em particular.There is a need to view homework (HW as a process for which a vast number of obstructive factors converges. In this report the interrelations between students of English as a Foreign Language, homework attitudes and behaviors, and their parents' education and students' perceived self-efficacy in EFL are analyzed. The correlation between students' EFL homework attitudes and behaviors and students' self-regulated learning profiles are also discussed. The study involved 3929 students, from 5th to 9th grades compulsory education. The collected data evidenced the positive and significant associations between EFL students' attitudes and behaviors towards homework and the parents' education and students' perceived self-efficacy in EFL. The correlation between EFL students' attitudes and behaviors towards homework and students' self-regulated learning profiles proves to be positive and significant. Calling the attention of teachers and

The International Adoption Project: population-based surveillance of Minnesota parents who adopted children internationally.

Science.gov (United States)

Hellerstedt, Wendy L; Madsen, Nikki J; Gunnar, Megan R; Grotevant, Harold D; Lee, Richard M; Johnson, Dana E

2008-03-01

To conduct the first population-based surveillance in the United States of parents who adopted children from countries outside of the United States. A 556-item survey was mailed to 2,977 parents who finalized an international adoption in Minnesota between January 1990 and December 1998; 1,834 (62%) parents returned a survey. Eighty-eight percent of the parents reported transracial adoptions (97% of the parents were white); 57% of the adopted children were Asian; 60% were female; and on average, the children were 18 months-old at the time of placement. Only 15% of the parents reported household annual incomes less than $50,000 and 71% reported they had college educations. Sixty-one percent traveled to their child's country of birth prior to the adoption. Almost three-quarters involved their children in experiences related to their birth countries and 98% would recommend international adoption. Three-quarters of the parents believe that parental leave was an issue for them as they adopted. This is the first population-based survey of U.S. parents who have adopted internationally. The adoptive parents were socioeconomically different than birth parents in Minnesota and their families are most likely to be transracial. Because international adoption has become more prevalent, it is important to understand the strengths and needs of families that are created through this unique form of migration.

The Online Parent Information and Support project, meeting parents' information and support needs for home-based management of childhood chronic kidney disease: research protocol.

Science.gov (United States)

Swallow, Veronica; Knafl, Kathleen; Sanatacroce, Sheila; Hall, Andrew; Smith, Trish; Campbell, Malcolm; Webb, Nicholas J A

2012-09-01

This article is a report of a protocol for studying the development and evaluation of an online parent information and support package for home-based care of children with chronic kidney disease stages 3-5. The study is funded by a National Institute of Health Research, Research for Patient Benefit Grant awarded (December 2010). Approval to undetake the study was obtained from the Department of Health National Research Ethics Service (June 2011). Children with chronic kidney disease require skilled, home-based care by parents, supported by professionals. Parents have identified a need for continuously available online resources to supplement professional support, and structured resources tailored to parents' needs are highlighted by policy makers as key to optimizing care; yet, online resource provision is patchy with little evidence base. Using mixed methods, we will (i) conduct parent/child/young person/professional/patient and parent volunteer focus groups to explore views on existing resources, (ii) collaboratively define gaps in provision, identify desirable components, develop/test resources and conduct a feasibility randomized controlled trial, and (iii) of usual professional support versus usual support supplemented by the package. Eighty parents of children with chronic kidney disease will be randomized. Primary outcomes will assess parents' self-efficacy and views of resources, using standardized measures at entry and 24 weeks, and semi-structured interviews at 24 weeks. We will finalize trial components for a later definitive trial. By working collaboratively, we will derive a detailed insight into parents' information and support needs and experiences of using the package, and should see improved parental self-efficacy. © 2012 Blackwell Publishing Ltd.

Ultrasensitive electrochemical sensing platform based on graphene wrapping SnO2 nanocorals and autonomous cascade DNA duplication strategy.

Science.gov (United States)

Chen, Ying-Xu; Huang, Ke-Jing; Lin, Feng; Fang, Lin-Xia

2017-12-01

In this work, a sensitive, universal and reusable electrochemical biosensor based on stannic oxide nanocorals-graphene hybrids (SnO 2 NCs-Gr) is developed for target DNA detection by using two kinds of DNA enzymes for signal amplification through an autonomous cascade DNA duplication strategy. A hairpin probe is designed composing of a projecting part at the 3'-end as identification sequence for target, a recognition site for nicking endonuclease, and an 18-carbon shim to stop polymerization process. The designed DNA duplication-incision-replacement process is handled by KF polymerase and endonuclease, then combining with gold nanoparticles as signal carrier for further signal amplification. In the detection system, the electrochemical-chemical-chemical procedure, which uses ferrocene methanol, tris(2-carboxyethyl)phosphine and l-ascorbic acid 2-phosphate as oxidoreduction neurogen, deoxidizer and zymolyte, separately, is applied to amplify detection signal. Benefiting from the multiple signal amplification mechanism, the proposed sensor reveals a good linear connection between the peak current and logarithm of analyte concentration in range of 0.0001-1 × 10 -11 molL -1 with a detection limit of 1.25 × 10 -17 molL -1 (S/N=3). This assay also opens one promising strategy for ultrasensitive determination of other biological molecules for bioanalysis and biomedicine diagnostics. Copyright © 2017 Elsevier B.V. All rights reserved.

Parental competence programs to promote positive parenting and healthy lifestyles in children: a systematic review

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Cayetana Ruiz‐Zaldibar

2018-05-01

Full Text Available Objective: To analyze the available evidence regarding the efficacy of interventions on parents whose children were aged 2–5 years to promote parental competence and skills for children's healthy lifestyles. Source: Articles published in English and Spanish, available at PubMed, Psycinfo, CINAHL, Web of Science, Eric, and Cochrane Library were reviewed. Summary of the findings: The literature search yielded 2282 articles. Forty‐one full texts were retrieved and assessed for inclusion using the PRISMA flow diagram. Twenty‐six articles were excluded, as they did not meet the inclusion criteria. In the end, 15 studies were included. The studies were conducted between 2003 and 2016, nine in North America, four in Europe, and two in Asia. Extracted data were synthesized in a tabular format. CASPe guide was used to assess the quality of studies that was moderate overall. Parental self‐efficacy was the main construct assessed in most studies. Four studies reported an increase in parental self‐efficacy, although most of them were studies without control groups. Conclusions: Outcomes of interventions to improve parental competence in order to promote children's lifestyles are promising, but inconsistent. Additional studies with higher methodological and conceptual quality are needed. Resumo: Objetivo: Analisar as evidências disponíveis com relação à eficácia de intervenções em pais de filhos entre dois e cinco anos para promover a competência e as habilidades dos pais a respeito de estilos de vida saudáveis para as crianças. Fonte: Foram analisados artigos publicados em PubMed, Psycinfo, CINAHL, Web of Science, Eric e Biblioteca Cochrane. Inglês e espanhol. Resumo dos achados: A pesquisa da literatura encontrou 2.282 artigos; 41 textos completos foram selecionados e avaliados para inclusão com o fluxograma Prisma; 26 artigos foram excluídos, pois não atendiam aos critérios de inclusão. Por fim, 15 estudos foram incluídos. Os

Parent Perspectives of Applying Mindfulness-Based Stress Reduction Strategies to Special Education.

Science.gov (United States)

Burke, Meghan M; Chan, Neilson; Neece, Cameron L

2017-06-01

Parents of children with (versus without) intellectual and developmental disabilities report greater stress; such stress may be exacerbated by dissatisfaction with school services, poor parent-school partnerships, and the need for parent advocacy. Increasingly, mindfulness interventions have been used to reduce parent stress. However, it is unclear whether parents apply mindfulness strategies during the special education process to reduce school-related stress. To investigate whether mindfulness may reduce school-related stress, interviews were conducted with 26 parents of children with intellectual and developmental disabilities who completed a mindfulness-based stress reduction intervention. Participants were asked about their stress during meetings with the school, use of mindfulness strategies in communicating with the school, and the impact of such strategies. The majority of parent participants reported: special education meetings were stressful; they used mindfulness strategies during IEP meetings; and such strategies affected parents' perceptions of improvements in personal well-being, advocacy, family-school relationships, and access to services for their children. Implications for future research, policy, and practice are discussed.

O projeto de parentalidade e suas consequências na existência do ser humano. Uma reflexão a partir da perspectiva religiosa (The parenting project and its consequences in human being’s existence. A consideration from the religious view

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Waldir Souza

2013-09-01

Full Text Available O projeto de parentalidade e suas consequências na existência do ser humano. Uma reflexão a partir da perspectiva religiosa (The parenting project and its consequences in human being’s existence. A consideration from the religious view - DOI: 10.5752/P.2175-5841.2013v11n31p1059Gerar um filho é gerar uma vida. No processo geracional estão embutidas várias implicações e consequências tanto para quem gera, quanto para quem é gerado. Para o casal, o nascimento de um filho é o fruto inquestionável de sua união. Entretanto, também deve ser fruto da vontade, do cuidado e do amor desse casal. Um ser humano que se sente amado e querido por seus pais será o reflexo de uma existência radicada no amor e por isso, uma presença amorosa. Deste modo, o estudo a respeito do projeto de parentalidade tem como proposta colaborar na reflexão a respeito da totalidade do ser humano a partir de uma existência ainda como intenção, que se desenvolve no encontro de um pai e uma mãe que desejam como fruto de seu amor, gerar aquele ou aquela que já é por eles amado, amada. Trata-se de um ato de amor que constrói de maneira consciente a existência de uma humanidade plenamente consciente de si em virtude da consciência e da vontade de quem quis gerá-la. A religião tem um forte apelo na maneira com que o ser humano se relaciona com o projeto de parentalidade. Palavras chave: Teologia. Bioética. Parentalidade. Família. Religião. Abstract To generate a child is to generate a life. In the generation process are embedded several implications and consequences both for those who generate and for those who are generated. For the couple the birth of a child is unquestionably the fruit of their union. However, it should also be the result of the will, the care and the love of this couple. A human being who feels loved and cherished by its parents will be the reflection of a life based in love and therefore, a loving presence. Thus, the study about the

Mindfulness-based stress reduction for parents of young children with developmental delays: implications for parental mental health and child behavior problems.

Science.gov (United States)

Neece, Cameron L

2014-03-01

Parents of children with developmental delays (DD) typically report elevated levels of parental stress compared with parents of typically developing children. Children with DD are also at high risk for exhibiting significant behaviour problems. Parental stress has been shown to impact the development of these behaviour problems; however, it is rarely addressed in interventions aimed at reducing child behaviour problems. The current study examined the efficacy of mindfulness-based stress reduction (MBSR) for parents of children with DD by investigating whether this intervention is effective in reducing parenting stress and whether decreases in parenting stress lead to reductions in behaviour problems among children with DD. Forty six parents of children with DD were randomly assigned to an immediate treatment or wait list-control group. Participants completed questionnaires assessing parental stress and child behaviour problems at intake and at a second assessment, which took place after only the immediate treatment group had received the MBSR. Parents who participated in MBSR reported significantly less stress and depression as well as greater life satisfaction compared with wait list-control parents. Regarding child outcomes, children whose parents participated in MBSR were reported to have fewer behaviour problems following the intervention, specifically in the areas of attention problems and ADHD symptomatology. Results indicated that MBSR may be an effective intervention for ameliorating parental stress and mental health problems among parents of children with DD. Additionally, these benefits may 'spill over' and improve behaviour challenges among these children. © 2013 John Wiley & Sons Ltd.

Elementos para a satisfação e eficácia percebida da formação parental: um estudo das percepções de pais e filhos

OpenAIRE

Tavares, Sara Cristina Machado Santos

2009-01-01

Dissertação de mestrado em Estudos da Criança (área de especialização em Intervenção Psicossocial com Crianças, Jovens e Famílias) O presente trabalho de investigação consiste num estudo de caso que tem como objectivo apresentar os resultados da avaliação da satisfação e eficácia percebida junto de famílias que participaram no programa de formação parental “Strengthening Families Program”, que adopta a designação de Programa de Fortalecimento de Famílias na língua portuguesa. Esta nossa o...

Gaze-based assistive technology used in daily life by children with severe physical impairments - parents' experiences.

Science.gov (United States)

Borgestig, Maria; Rytterström, Patrik; Hemmingsson, Helena

2017-07-01

To describe and explore parents' experiences when their children with severe physical impairments receive gaze-based assistive technology (gaze-based assistive technology (AT)) for use in daily life. Semi-structured interviews were conducted twice, with one year in between, with parents of eight children with cerebral palsy that used gaze-based AT in their daily activities. To understand the parents' experiences, hermeneutical interpretations were used during data analysis. The findings demonstrate that for parents, children's gaze-based AT usage meant that children demonstrated agency, provided them with opportunities to show personality and competencies, and gave children possibilities to develop. Overall, children's gaze-based AT provides hope for a better future for their children with severe physical impairments; a future in which the children can develop and gain influence in life. Gaze-based AT provides children with new opportunities to perform activities and take initiatives to communicate, giving parents hope about the children's future.

Genealogical and molecular analysis of a family-based cohort of congenital heart disease patients from the São Miguel Island (Azores, Portugal).

Science.gov (United States)

Cabral, Rita; Pires, Renato; Anjos, Rui; Branco, Claudia C; Maciel, Paula; Mota-Vieira, Luisa

2016-11-01

Congenital heart disease (CHD) is one common birth malformation, accounting for ∼30% of total congenital abnormalities. Considering the unknown role of consanguinity in causing CHD, this study hypothesised that consanguineous unions and/or familial aggregation may be frequent in the Azorean Island of São Miguel (Portugal). To that end, a retrospective observational study was performed based on genealogical and molecular analyses. The study enrolled 112 CHD patients from São Miguel Island, which allowed the assessment of type of family (simplex or multiplex), parental consanguinity and grandparental endogamy. Based on 15 STR markers, inbreeding coefficients (F IS ) in the CHD cohort and healthy control group (n = 114) were estimated. Multiplex families were 37.6% (n = 41/109), a rate considerably higher than previously described in the literature (genealogical and genetic features related with CHD, revealing the presence of parental consanguinity and extensive familial aggregation in the CHD patients from São Miguel Island.

Implementation evaluation of steering teens safe: engaging parents to deliver a new parent-based teen driving intervention to their teens.

Science.gov (United States)

Ramirez, Marizen; Yang, Jingzhen; Young, Tracy; Roth, Lisa; Garinger, Anne; Snetselaar, Linda; Peek-Asa, Corinne

2013-08-01

Parents play a fundamental role in teaching their children safe driving skills to reduce risk of motor vehicle crashes, the leading cause of death for teens. Steering Teens Safe is a new parent-based intervention that equips parents with communication skills to talk about, demonstrate, and practice safe driving behaviors and skills with their teens. This implementation evaluation focuses on a sample of 83 parents who delivered Steering Teens Safe to their teens. One-, 2- and 3-month follow-up assessments were conducted with intervention parents to evaluate the self-reported quantity and quality of talking about, demonstrating, and practicing safe driving goals with teens; perceived success and benefit of the program; and barriers to implementation. Over 3 months of follow-up, parents discussed driving goals with their teens for a median of 101.5 minutes. The most frequently addressed topics were general safety principles, including distracted driving, driving in bad weather, wearing a seat belt, and being a safe passenger. Parents spent a median of 30 minutes practicing safe driving skills such as changing lanes. Sixty-seven percent of parents talked to their children about rural road safety, but just 36% demonstrated and half practiced these skills with their teens. Barriers to implementation include time and opportunity barriers and resistant attitudes of their teens. However, barriers neither affected frequency of engagement nor parents' perceived benefit and comfort in delivering the program. Parents with time/opportunity barriers also had higher practice and demonstration times than parents without these barriers. Findings indicate high acceptability among parent implementers and promise for real-world delivery. Future studies are needed to assess intervention impact.

Envolvimento em atos infracionais e com drogas como possibilidades para lidar com o papel de filho parental

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Maria Aparecida Penso

2004-01-01

Full Text Available Este estudo busca compreender a contribuição da dinâmica familiar no processo de construção identitária de adolescentes que cometeram atos infracionais e são usuários de drogas, vivendo em situação de pobreza e exclusão social. Seu referencial teórico é a Teoria Sistêmica. Utiliza-se da metodologia qualitativa de pesquisa-intervenção com dez adolescentes em medida sócio-educativa de semiliberdade e suas famílias. Os resultados apontam para a função do uso de drogas e do cometimento de atos infracionais na adolescência, como uma das saídas encontradas pelo adolescente para lidar com o papel de filho parental, permitindo a resolução da crise identitária.

O desempenho escolar dos filhos na percepção de pais de alunos com sucesso e insucesso escolar The children's school performance in the perception of parents of students with school success and school failure

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Valéria Aparecida Chechia

2005-12-01

Full Text Available Neste artigo investigam-se as percepções de pais sobre o desempenho escolar dos seus filhos, analisando o conteúdo de entrevistas semi-estruturadas com 32 pais, sendo dezesseis pais de alunos com desempenho classificado como sucesso e demais pais de alunos com insucesso escolar. Quanto ao desempenho escolar, tanto os pais de alunos com sucesso, como os de insucesso atribuem razões relacionadas à responsabilidade do filho, do professor e também às da própria família. Os resultados permitem evidenciar que tanto uns quanto outros revelam que a família deve promover a valorização da escola e de auxílio às tarefas, bem como a escola precisa rever os seus valores e procedimentos em relação ao aluno e à família. Assim, destacamos a necessidade de os pais serem mais bem orientados pela escola para poderem assessorar seus filhos. Estratégias sugeridas pela escola, ou outros pais, podem auxiliar pais que, por trabalharem, não possam estar presentes na escola.This article examines parents' perceptions of children's school performance, by analyzing the contents of semi-structured interviews with 32 parents, grouped in sixteen parents of students with performance classified as successful and, in the other half, parents of students with school failure. As for school performance, both groups attribute responsibilities to the child, to the teacher and also to the family itself. The results for both groups reveal that the family should promote valorization of school and of homework assistance, and also that school needs to revise its values and procedures concerning students and their families. So, we emphasize the need of parents being better oriented by school so that they can help their children. Strategies suggested by school, or by other parents, may help parents who, because of their work, can not be present at school.

Examining the Process of Change in an Evidence-Based Parent Training Intervention: A Qualitative Study Grounded in the Experiences of Parents

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Holtrop, Kendal N.

2011-01-01

The evidence-based parent training intervention known as Parent Management Training-the Oregon Model (PMTO) is one particularly well-supported treatment approach for addressing child behavioral problems. Yet, there remains a need to further examine how this intervention promotes change. The purpose of this study was to develop a grounded theory…

Parenting style: perceptions of children and their parents / Identificação de estilos parentais: o ponto de vista dos pais e dos filhos

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Lidia Natalia Dobrianskyj Weber

2004-01-01

Full Text Available In order to explore parenting styles among Brazilian families, 239 children (9-12 yrs old, from two public schools in Curitiba, and their parents answered two scales of parental responsiveness and demandingness. These scales, which categorize four parenting styles, were adapted for use with children (they were originally developed to be anwered by adolescents and showed satisfactory reliability coefficients (alpha between 0,65 and 0,76. Parents were classified as: negligent (45,4%, authoritative (32,8%, indulgent (11,8% and authoritarian (10,1%. Although parents have perceived themselves as being more responsive and demanding when compared to the opinions of their children, the correlation between the answers of parents and children was significant and positive. Additionally, the childrens' perceptions of their mothers correlated with that of their fathers. These differences in perception of parenting styles are discussed and the researchers call attention to the high number of negligent families observed.

Gaze-based assistive technology used in daily life by children with severe physical impairments - parents' experiences

OpenAIRE

Borgestig, Maria; Rytterstrom, Patrik; Hemmingsson, Helena

2017-01-01

Objective: To describe and explore parents' experiences when their children with severe physical impairments receive gaze-based assistive technology (gaze-based assistive technology (AT)) for use in daily life. Methods: Semi-structured interviews were conducted twice, with one year in between, with parents of eight children with cerebral palsy that used gaze-based AT in their daily activities. To understand the parents' experiences, hermeneutical interpretations were used during data analysis...

Predicting the Resiliency in Parents with Exceptional Children Based on Their Mindfulness

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Jabbari, Sosan; Firoozabadi, Somayeh Sadati; Rostami, Sedighe

2016-01-01

The purpose of the present study was to predict the resiliency in parents with exceptional children based on their mindfulness. This descriptive correlational study was performed on 260 parents of student (105 male and 159 female) that were selected by cluster sampling method. Family resiliency questionnaire (Sickby, 2005) and five aspect…

Parental Mediation Regarding Children's Smartphone Use: Role of Protection Motivation and Parenting Style.

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Hwang, Yoori; Choi, Inho; Yum, Jung-Yoon; Jeong, Se-Hoon

2017-06-01

Parental mediation is a type of behavior that could protect children against the negative uses and effects of smartphones. Based on protection motivation theory, this research (a) predicted parental mediation based on parents' threat and efficacy perceptions and (b) predicted threat and efficacy perceptions based on parenting styles and parents' addiction to smartphone use. An online survey of 448 parents of fourth to sixth graders was conducted. Results showed that both restrictive and active parental mediation were predicted by perceived severity, response efficacy, and self-efficacy. With regard to parenting styles, (a) authoritative parenting was positively related to perceived severity as well as response- and self-efficacy, whereas (b) permissive parenting was negatively related to self-efficacy. In addition, parents' addiction was a negative predictor of perceived severity, but a positive predictor of perceived susceptibility.

Synthesis of Stable Interfaces on SnO2 Surfaces for Charge-Transfer Applications

Science.gov (United States)

Benson, Michelle C.

The commercial market for solar harvesting devices as an alternative energy source requires them to be both low-cost and efficient to replace or reduce the dependence on fossil fuel burning. Over the last few decades there has been promising efforts towards improving solar devices by using abundant and non-toxic metal oxide nanomaterials. One particular metal oxide of interest has been SnO2 due to its high electron mobility, wide-band gap, and aqueous stability. However SnO2 based solar cells have yet to reach efficiency values of other metal oxides, like TiO2. The advancement of SnO2 based devices is dependent on many factors, including improved methods of surface functionalization that can yield stable interfaces. This work explores the use of a versatile functionalization method through the use of the Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction. The CuAAC reaction is capable of producing electrochemically, photochemically, and electrocatalytically active surfaces on a variety of SnO2 materials. The resulting charge-transfer characteristics were investigated as well as an emphasis on understanding the stability of the resulting molecular linkage. We determined the CuAAC reaction is able to proceed through both azide-modified and alkyne-modified surfaces. The resulting charge-transfer properties showed that the molecular tether was capable of supporting charge separation at the interface. We also investigated the enhancement of electron injection upon the introduction of an ultra-thin ZrO2 coating on SnO2. Several complexes were used to fully understand the charge-transfer capabilities, including model systems of ferrocene and a ruthenium coordination complex, a ruthenium mononuclear water oxidation catalyst, and a commercial ruthenium based dye.

Emotional reasoning and parent-based reasoning in non-clinical children and their prospective relationships with anxiety symptoms

NARCIS (Netherlands)

Morren, M.; Muris, P.; Kindt, M.; Schouten, E.; van den Hout, M.

2008-01-01

Emotional and parent-based reasoning refer to the tendency to rely on personal or parental anxiety response information rather than on objective danger information when estimating the dangerousness of a situation. This study investigated the prospective relationships of emotional and parent-based

Study of Adolescents Perceived Parenting Styles Based on their Gender and Age

OpenAIRE

صادق تقی لو

2017-01-01

Parenting styles play a major role in determining the life styles of adolescents and that is why they share a special significance. The present study was done with the aim to investigate adolescents’ perceived parenting styles based on their gender and age. The study was conducted by a post-event method and with a sample size of 623 subjects (311 female and 312 male), who were selected by the multistage sampling method. Data were analyzed, after being collected by the Baumrind Parenting Style...

Latino Parent Home-Based Practices that Bolster Student Academic Persistence

Science.gov (United States)

Mena, Jasmine A.

2011-01-01

Home-based parental involvement practices (i.e., educational encouragement, monitoring, and support) and their impact on students' academic persistence were investigated with a sample of 137, ninth-grade Latino students in a northeast high school. Structural Equation Modeling results indicate that the relationship between home-based parental…

A Model-Based Cluster Analysis of Maternal Emotion Regulation and Relations to Parenting Behavior.

Science.gov (United States)

Shaffer, Anne; Whitehead, Monica; Davis, Molly; Morelen, Diana; Suveg, Cynthia

2017-10-15

In a diverse community sample of mothers (N = 108) and their preschool-aged children (M age  = 3.50 years), this study conducted person-oriented analyses of maternal emotion regulation (ER) based on a multimethod assessment incorporating physiological, observational, and self-report indicators. A model-based cluster analysis was applied to five indicators of maternal ER: maternal self-report, observed negative affect in a parent-child interaction, baseline respiratory sinus arrhythmia (RSA), and RSA suppression across two laboratory tasks. Model-based cluster analyses revealed four maternal ER profiles, including a group of mothers with average ER functioning, characterized by socioeconomic advantage and more positive parenting behavior. A dysregulated cluster demonstrated the greatest challenges with parenting and dyadic interactions. Two clusters of intermediate dysregulation were also identified. Implications for assessment and applications to parenting interventions are discussed. © 2017 Family Process Institute.

How parents can affect excessive spending of time on screen-based activities.

Science.gov (United States)

Brindova, Daniela; Pavelka, Jan; Ševčikova, Anna; Žežula, Ivan; van Dijk, Jitse P; Reijneveld, Sijmen A; Geckova, Andrea Madarasova

2014-12-12

The aim of this study is to explore the association between family-related factors and excessive time spent on screen-based activities among school-aged children. A cross-sectional survey using the methodology of the Health Behaviour in School-aged Children study was performed in 2013, with data collected from Slovak (n = 258) and Czech (n = 406) 11- and 15-year-old children. The effects of age, gender, availability of a TV or computer in the bedroom, parental rules on time spent watching TV or working on a computer, parental rules on the content of TV programmes and computer work and watching TV together with parents on excessive time spent with screen-based activities were explored using logistic regression models. Two-thirds of respondents watch TV or play computer games at least two hours a day. Older children have a 1.80-times higher chance of excessive TV watching (CI: 1.30-2.51) and a 3.91-times higher chance of excessive computer use (CI: 2.82-5.43) in comparison with younger children. More than half of children have a TV (53%) and a computer (73%) available in their bedroom, which increases the chance of excessive TV watching by 1.59 times (CI: 1.17-2.16) and of computer use by 2.25 times (CI: 1.59-3.20). More than half of parents rarely or never apply rules on the length of TV watching (64%) or time spent on computer work (56%), and their children have a 1.76-times higher chance of excessive TV watching (CI: 1.26-2.46) and a 1.50-times greater chance of excessive computer use (CI: 1.07-2.08). A quarter of children reported that they are used to watching TV together with their parents every day, and these have a 1.84-times higher chance of excessive TV watching (1.25-2.70). Reducing time spent watching TV by applying parental rules or a parental role model might help prevent excessive time spent on screen-based activities.

Comparação das formas de aplicação papel e caneta e eletrônica do índice de estresse parental versão reduzida (PSI-SF

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Camila Piccini Aiello

2014-04-01

Full Text Available Objetivo avaliar se a aplicação eletrônica do Índice de Estresse Parental – versão reduzida (PSI-SF é comparável à aplicação em formato papel e caneta. Verificar o estresse em pais de crianças com desenvolvimento normal. Métodos quarenta adultos, pais de crianças entre seis meses e 10 anos, foram divididos em quatro grupos, sendo pareados por idade, sexo, escolaridade e idade da criança. Cada participante completou o questionário em duas ocasiões, com intervalo de sete a dez dias, nas versões: papel-caneta/papel-caneta (PP, papel-caneta/eletrônico (PE, eletrônico/eletrônico (EE, eletrônico/papel-caneta (EP. O PSI-SF apresenta 36 afirmações, divididas em três subescalas: Sofrimento Parental (SP; Interações Disfuncionais entre Pai e Criança (IDPC e Criança Difícil (CD. Para análise dos dados foram realizadas as correlações (Pearson e comparação da pontuação do PSI-SF intra e inter-grupos. Resultados foram obtidas correlações positivas fortes e médias e significantes entre a pontuação total e das subescalas do PSI-SF na primeira e segunda aplicação, para todos os grupos. Diferenças significantes foram observadas entre as médias das pontuações para o grupo PP (subescala “Criança Difícil”; e grupo EE (subescala “Criança Difícil”; e pontuação total. No entanto, tais diferenças de pontuação não alteraram a interpretação do resultado do questionário. Não houve diferença significante entre os grupos para as quatro subescalas analisadas, confirmando equivalência da variância entre os grupos. O estresse dos participantes, em todas as subescalas, recaiu dentro da normalidade. Conclusão a aplicação no formato eletrônico do questionário PSI-SF apresenta resultados semelhantes à aplicação papel e caneta. Os níveis de estresse observados foram considerados normais.

A “four-ferrocene” modified stem-loop structure as a probe for sensitive detection and single-base mismatch discrimination of DNA

International Nuclear Information System (INIS)

Chatelain, Grégory; Ripert, Micaël; Farre, Carole; Ansanay-Alex, Salomé; Chaix, Carole

2012-01-01

We report the use of a four-ferrocene modified oligonucleotide as a probe for DNA detection with a gold electrode microsystem. This oligonucleotide is synthesized by automated solid-phase synthesis with four successive ferrocene moieties at the 5′-end and a C6-thiol modifier group at the 3′-end. The grafting of this 4Fc-DNA probe on a gold electrode microsystem results in the appearance of the ferrocene redox couple in cyclic voltammetry. The probe sequence is a stem-loop structure that folds efficiently on the electrode, thus optimizing electron transfer. Such architecture serves as sensor for DNA detection which is based on hybridization. The resulting disposable voltammetric sensor allowed direct, reagentless DNA detection in a small volume (20 μL). Electrochemical response upon hybridization with complementary short sequence (30-base length) and long sequence (50-base length) strands was observed by differential pulse voltammetry. Current variations were compared. The longer the sequence, the greater the decrease in current. The system's detection limit was estimated at 3.5 pM (0.07 fmol in 20 μL) with the 50-base length target and provided a dynamic detection range between 3.5 pM and 5 nM. Single mismatch detection showed a good level of sensitivity. The system was regenerated twice with no significant loss of Fc signal. Finally, 1 pM sensitivity was reached with a long chain analog of DNA PCR products of Influenza virus.

The pragmatic language, communication skills, parent-child relationships, and symptoms of children with ADHD and their playmates 18-months after a parent-delivered play-based intervention.

Science.gov (United States)

Wilkes-Gillan, Sarah; Cantrill, Alycia; Parsons, Lauren; Smith, Cally; Cordier, Reinie

2017-07-01

This study examined the communication skills, pragmatic language, parent-child relationships, and attention deficit hyperactivity disorder (ADHD) symptoms of children with ADHD and their playmates 18-months after a pilot parent-delivered intervention for improving social play skills and pragmatic language. Participants were five children with ADHD, their parents, and five typically-developing playmates. Outcomes were measured immediately post and 18-months following the intervention. Parent-rated norm-based assessments and an observational measure were used. Differences within and between the ADHD and playmate groups were examined. Children maintained all skills gained 18-months following the intervention. Compared to a normative sample, children with ADHD remained below the average range on aspects of communication skills, parent-child relationships, and ADHD symptom levels 18-months following intervention. After intervention, children with ADHD still experienced pragmatic language skills below those of their peers on norm-based assessments that measure their skills across contexts. School-based interventions are needed to facilitate ongoing skill development and generalization.

School- And Home-Based Drug Prevention: Environmental, Parent, and Child Risk Reduction

Science.gov (United States)

Hahn, Ellen J.; Hall, Lynne A.; Rayens, Mary Kay; Myers, April V.; Bonnel, Galadriel

2007-01-01

The study purpose was to test the effect of a school- and home-based alcohol, tobacco, and other drug (ATOD) prevention program on reducing environmental, parent, and child risk factors for ATOD use. The design was a three-group pretest-posttest with interviews at baseline and 1 and 6 months post-intervention. The sample was 126 parents and their…

Single step hydrothermal based synthesis of M(II)Sb2O6 (M = Cd ...

Indian Academy of Sciences (India)

characterized by powder X-ray diffraction, scanning electron microscopy, energy dispersive .... SEM images and EDAX analysis of (a) and (b) CdSb2O6 and (c) and (d) ZnSb2O6. ... The parent compound, ilmenite (NaSbO3) could degrade MB.

Emotional Reasoning and Parent-Based Reasoning in Non-Clinical Children, and Their Prospective Relationships with Anxiety Symptoms

Science.gov (United States)

Morren, Mattijn; Muris, Peter; Kindt, Merel; Schouten, Erik; van den Hout, Marcel

2008-01-01

Emotional and parent-based reasoning refer to the tendency to rely on personal or parental anxiety response information rather than on objective danger information when estimating the dangerousness of a situation. This study investigated the prospective relationships of emotional and parent-based reasoning with anxiety symptoms in a sample of…

Mindful Parenting Training in Child Psychiatric Settings : Heightened Parental Mindfulness Reduces Parents' and Children's Psychopathology

NARCIS (Netherlands)

Meppelink, Renee; de Bruin, Esther I.; Wanders-Mulder, Femy H.; Vennik, Corinne J.; Bogels, Susan M.

Mindful parenting training is an application of mindfulness-based interventions that allows parents to perceive their children with unbiased and open attention without prejudgment and become more attentive and less reactive in their parenting. This study examined the effectiveness of mindful

The application of defaults to optimize parents' health-based choices for children.

Science.gov (United States)

Loeb, Katharine L; Radnitz, Cynthia; Keller, Kathleen; Schwartz, Marlene B; Marcus, Sue; Pierson, Richard N; Shannon, Michael; DeLaurentis, Danielle

2017-06-01

Optimal defaults is a compelling model from behavioral economics and the psychology of human decision-making, designed to shape or "nudge" choices in a positive direction without fundamentally restricting options. The current study aimed to test the effectiveness of optimal (less obesogenic) defaults and parent empowerment priming on health-based decisions with parent-child (ages 3-8) dyads in a community-based setting. Two proof-of-concept experiments (one on breakfast food selections and one on activity choice) were conducted comparing the main and interactive effects of optimal versus suboptimal defaults, and parent empowerment priming versus neutral priming, on parents' health-related choices for their children. We hypothesized that in each experiment, making the default option more optimal will lead to more frequent health-oriented choices, and that priming parents to be the ultimate decision-makers on behalf of their child's health will potentiate this effect. Results show that in both studies, default condition, but not priming condition or the interaction between default and priming, significantly predicted choice (healthier vs. less healthy option). There was also a significant main effect for default condition (and no effect for priming condition or the interaction term) on the quantity of healthier food children consumed in the breakfast experiment. These pilot studies demonstrate that optimal defaults can be practicably implemented to improve parents' food and activity choices for young children. Results can inform policies and practices pertaining to obesogenic environmental factors in school, restaurant, and home environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

Children's Quality of Life Based on the KIDSCREEN-27: Child Self-Report, Parent Ratings and Child-Parent Agreement in a Swedish Random Population Sample.

Directory of Open Access Journals (Sweden)

Anne H Berman

Full Text Available The KIDSCREEN-27 is a measure of child and adolescent quality of life (QoL, with excellent psychometric properties, available in child-report and parent-rating versions in 38 languages. This study provides child-reported and parent-rated norms for the KIDSCREEN-27 among Swedish 11-16 year-olds, as well as child-parent agreement. Sociodemographic correlates of self-reported wellbeing and parent-rated wellbeing were also measured.A random population sample consisting of 600 children aged 11-16, 100 per age group and one of their parents (N = 1200, were approached for response to self-reported and parent-rated versions of the KIDSCREEN-27. Parents were also asked about their education, employment status and their own QoL based on the 26-item WHOQOL-Bref. Based on the final sampling pool of 1158 persons, a 34.8% response rate of 403 individuals was obtained, including 175 child-parent pairs, 27 child singleton responders and 26 parent singletons. Gender and age differences for parent ratings and child-reported data were analyzed using t-tests and the Mann-Whitney U-test. Post-hoc Dunn tests were conducted for pairwise comparisons when the p-value for specific subscales was 0.05 or lower. Child-parent agreement was tested item-by-item, using the Prevalence- and Bias-Adjusted Kappa (PABAK coefficient for ordinal data (PABAK-OS; dimensional and total score agreement was evaluated based on dichotomous cut-offs for lower well-being, using the PABAK and total, continuous scores were evaluated using Bland-Altman plots.Compared to European norms, Swedish children in this sample scored lower on Physical wellbeing (48.8 SE/49.94 EU but higher on the other KIDSCREEN-27 dimensions: Psychological wellbeing (53.4/49.77, Parent relations and autonomy (55.1/49.99, Social Support and peers (54.1/49.94 and School (55.8/50.01. Older children self-reported lower wellbeing than younger children. No significant self-reported gender differences occurred and parent ratings

Vietnamese American Immigrant Parents: A Pilot Parenting Intervention

Science.gov (United States)

Wong, Y. Joel; Tran, Kimberly K.; Schwing, Alison E.; Cao, Lien H.; Ho, Phoenix Phung-Hoang; Nguyen, Quynh-Tram

2011-01-01

The main goal of this mixed-methods study was to examine the perceived effectiveness of a brief, community-based parenting intervention for Vietnamese American immigrant parents. A key component of the intervention involved participants listening to Vietnamese American adolescents' discussions about their relationships with their parents utilizing…

Kinetics of electron transfer through ferrocene-terminated alkanethiol monolayers on gold

Energy Technology Data Exchange (ETDEWEB)

Smalley, J.F.; Feldberg, S.W.; Newton, M.D.; Liu, Y.P. [Brookhaven National Lab., Upton, NY (United States); Chidsey, C.E.D.; Linford, M.R. [Stanford Univ., CA (United States)

1995-08-31

The kinetics of electron transfer between a substrate gold electrode and a self-assembled monolayer formed from CH{sub 3}(CH{sub 2}){sub n-1}SH and ({eta}{sup 5} C{sub 5}H{sub 5})Fe ({eta}{sup 5}-C{sub 5}H{sub 4})CO{sub 2}(CH{sub 2}){sub n}SH were studied as a function of n, the number of methylenes in the alkyl chain tethering the ferrocene moiety to the electrode, using the indirect laser-induced temperature jump method (ILIT). For 5 {<=} n {<=} 9 the standard electron-transfer rate constants vary according to {kappa}{sub {tau}a,n=0} exp[-{beta}{sub n}n] where {kappa}{sub {tau}a,n=0} is the (extrapolated) rate constant for the electron transfer at n = 0. At {Tau} = 25{degree}C, {kappa}{sub {tau}a,n} 0 {approx_equal} 6 x 10{sup 8} s{sup -1} and {beta}{sub n} = 1.21 x 0.05. The ILIT method allows rates to be measured that are too fast to be measured by conventional chronoamperometry at a macroelectrode, which is limited to rate constants of {<=} 10{sup 4} s{sup -1}. Using a Marcus formalism, the reorganization energy, {lambda}, for the electron-transfer process at a given n was determined from the slope of an Arrhenius plot over the temperature range 15-55{degree}C. Values of {lambda} determined from Arrhenius slopes for n = 8 and 9 using ILIT are in reasonable agreement with the value of {lambda} previously deduced from the potential dependence of the rate constant for n = 16. 39 refs., 13 figs., 3 tabs.

Design of the FRESH study: A randomized controlled trial of a parent-only and parent-child family-based treatment for childhood obesity.

Science.gov (United States)

Boutelle, Kerri N; Braden, Abby; Douglas, Jennifer M; Rhee, Kyung E; Strong, David; Rock, Cheryl L; Wilfley, Denise E; Epstein, Leonard; Crow, Scott

2015-11-01

Approximately 1 out of 3 children in the United States is overweight or obese. Family-based treatment (FBT) is considered the gold-standard treatment for childhood obesity, but FBT is both staff and cost intensive. Therefore, we developed the FRESH (Family, Responsibility, Education, Support, & Health) study to evaluate the effectiveness of intervening with parents, without child involvement, to facilitate and improve the child's weight status. Targeting parents directly in the treatment of childhood obesity could be a promising approach that is developmentally appropriate for grade-school age children, highly scalable, and may be more cost effective to administer. The current paper describes the FRESH study which was designed to compare the effectiveness of parent-based therapy for pediatric obesity (PBT) to a parent and child (FBT) program for childhood obesity. We assessed weight, diet, physical activity, and parenting, as well as cost-effectiveness, at baseline, post-treatment, and at 6- and 18-month follow-ups. Currently, all participants have been recruited and completed assessment visits, and the initial stages of data analysis are underway. Ultimately, by evaluating a PBT model, we hope to optimize available child obesity treatments and improve their translation into clinical settings. Copyright © 2015 Elsevier Inc. All rights reserved.

Parenting style and practices in stepfamilies

Directory of Open Access Journals (Sweden)

Cassoni C

2012-09-01

Full Text Available Cynthia Cassoni,1 Regina HL Caldana21Graduate School in Psychology, 2Department of Psychology and Education, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP BrazilAbstract: There are several studies on the best way to raise a child, ie, what would be the consequences of our actions for our children. We tend to think of how to educate children in a traditional family, but society has undergone many changes and, hence, family structures have undergone changes too. Today, we find a large number of stepfamilies facing the same issues concerning how to educate a child. Stepfamily configuration often entails more than just the addition of a new parent figure. The objective of this study was to shed some light on how these stepfamilies deal with issues of parenting style and practices. We reviewed the Brazilian and international literature concerning parenting styles and practices in stepfamilies. The papers identified were organized and submitted to analysis. We identified very few papers addressing parenting styles and practices, pointing to an important but unaddressed social change as reflected in new family structures. There is a need for longitudinal studies aimed at understanding not only a particular moment in time, but also moments within a context, ie, an analysis with a holistic approach without preconceived ideas.Keywords: parenting styles, parenting practices, stepfamilies

Web-Based Prevention of Parenting Difficulties in Young, Urban Mothers Enrolled in Post-Secondary Education.

Science.gov (United States)

Ehrensaft, Miriam K; Knous-Westfall, Heather M; Alonso, Thailyn Lopez

2016-12-01

Research consistently indicates that young mothers are at elevated risk for adverse social and economic risks. Recent attention has been paid to the value of maternal educational attainment for their children's economic and social outcomes. Pursuit of post-secondary education requires mothers to balance multiple roles, potentially stressing the parent-child relationship. Yet, almost no studies have addressed parenting and associated stress in young mothers enrolled in post-secondary education, and no preventive intervention trials have been conducted. We screened young mothers (parenting stress, and participated in a randomized controlled trial to assess the efficacy of a web-based parenting intervention (Triple P Online) in reducing parenting stress and dysfunctional discipline (N = 52). Mothers were randomly assigned to the web-based parenting program condition or to a waitlist control condition. Mothers who completed at least the first four core modules of the online program had lower scores on the Parenting Scale's subscales (Overreactivity, Verbosity, and Laxness), compared to those who did not complete four or more modules. No intervention effects were obtained for parenting stress. The current study provides preliminary evidence of the efficacy of this online parenting program for reducing risk for dysfunctional discipline in student mothers. Future research is warranted to replicate these findings, and to test whether provision of supplemental support for implementation, or briefer program formats may promote both program compliance and outcomes related to reducing parenting stress.

Parents' experiences and perceptions of group-based antenatal care in four clinics in Sweden.

Science.gov (United States)

Andersson, Ewa; Christensson, Kyllike; Hildingsson, Ingegerd

2012-08-01

group-based antenatal care consists of six to nine two-hour sessions in which information is shared and discussed during the first hour and individual examinations are conducted during the second hour. Groups generally consist of six to eight pregnant women. Parent education is built into the programme, which originated in the United States and was introduced in Sweden at the beginning of the year of 2000. to investigate parents' experiences of group antenatal care in four different clinics in Sweden. a qualitative study was conducted using content analysis five group interviews and eleven individual interviews with parents who experienced group-based antenatal care. An interview guide was used. the study was set in four antenatal clinics that had offered group-based antenatal care for at least one year. The clinics were located in three different areas of Sweden. the participants were women and their partners who had experienced group-based antenatal care during pregnancy. Other criteria for participation were mastery of the Swedish language and having followed the care programme. three themes emerged, 'The care-combining individual physical needs with preparation for parenthood, refers to the context, organisation, and content of care'. Group antenatal care with inbuilt parent education was appreciated, but respondents reported that they felt unprepared for the first few weeks after birth. Their medical needs (for physical assessment and screening) were, however, fulfilled. The theme, 'The group-a composed recipient of care', showed the participants role and experience. The role could be passive or active in groups or described as sharers. Groups helped parents normalise their symptoms. The theme, 'The midwife-a controlling professional', showed midwives are ignorant of gender issues but, for their medical knowledge, viewed as respectable professionals. in the four clinics studied, group-based antenatal care appeared to meet parents' needs for physical assessment

Study of Adolescents Perceived Parenting Styles Based on their Gender and Age

Directory of Open Access Journals (Sweden)

صادق تقی لو

2017-12-01

Full Text Available Parenting styles play a major role in determining the life styles of adolescents and that is why they share a special significance. The present study was done with the aim to investigate adolescents’ perceived parenting styles based on their gender and age. The study was conducted by a post-event method and with a sample size of 623 subjects (311 female and 312 male, who were selected by the multistage sampling method. Data were analyzed, after being collected by the Baumrind Parenting Styles Questionnaire, using multivariate analysis of variance. The results indicated that the main effects of gender and age are significant at 0.01 level. Parents’ interaction with boys is more authoritarian and with girls more authoritative; also compared with adolescents less than 17 years, they interact with adolescents 17 years old more permissively. The interaction effects of gender and age were significant at 0.05 level only in the permissive parenting style. This means that unlike the girls, parents use more and more the permissive parenting style along with increasing age of adolescent teenage boys. It was concluded that the interaction patterns of parents with children are not fixed and these patterns vary according to gender and age of the children.

Improving anti-bullying laws and policies to protect youth from weight-based victimization: parental support for action.

Science.gov (United States)

Puhl, R M; Suh, Y; Li, X

2017-04-01

Weight-based bullying is a prevalent problem among youth with overweight and obesity, but remains neglected in existing policy-level strategies to address youth bullying. Parental support is an influential catalyst motivating political will for policy decisions affecting youth, but has received limited research attention. To assess levels of, and predictors of, parental support for school-based policies and state/federal legal measures to address weight-based bullying in 2014 and 2015. Identical online questionnaires were completed by two independent national samples of parents in 2014 and 2015 (N = 1804). Parental support for all policy actions was high (at least 81%) and significantly increased from 2014 to 2015 for legal measures that would a) require state anti-bullying laws to add protections against weight-based bullying, and b) enact a federal anti-bullying law that includes weight-based bullying. These findings can inform policy discourse about remedies for youth bullying, and suggest that parental support for improved legal protections against weight-based bullying is present, consistent, and strong. © 2016 World Obesity Federation.

Effectiveness of an email-based intervention helping parents to enhance alcohol-related parenting skills and reduce their children's alcohol consumption: A randomised controlled trial

NARCIS (Netherlands)

Wurdak, M.; Kuntsche, E.N.; Wolstein, J.

2017-01-01

Aims: Developing and evaluating an email-based intervention (EBI) to enhance alcohol-related parenting skills and reduce alcohol consumption among adolescents. Methods: Over four weeks, participating parents received a weekly email containing scientific findings, practical advice and exercises in

Web-based tailored intervention for preparation of parents and children for outpatient surgery (WebTIPS): development.

Science.gov (United States)

Kain, Zeev N; Fortier, Michelle A; Chorney, Jill MacLaren; Mayes, Linda

2015-04-01

As a result of cost-containment efforts, preparation programs for outpatient surgery are currently not available to the majority of children and parents. The recent dramatic growth in the Internet presents a unique opportunity to transform how children and their parents are prepared for surgery. In this article, we describe the development of a Web-based Tailored Intervention for Preparation of parents and children undergoing Surgery (WebTIPS). A multidisciplinary taskforce agreed that a Web-based tailored intervention consisting of intake, matrix, and output modules was the preferred approach. Next, the content of the various intake variables, the matrix logic, and the output content was developed. The output product has a parent component and a child component and is described in http://surgerywebtips.com/about.php. The child component makes use of preparation strategies such as information provision, modeling, play, and coping skills training. The parent component of WebTIPS includes strategies such as information provision, coping skills training, and relaxation and distraction techniques. A reputable animation and Web design company developed a secured Web-based product based on the above description. In this article, we describe the development of a Web-based tailored preoperative preparation program that can be accessed by children and parents multiple times before and after surgery. A follow-up article in this issue of Anesthesia & Analgesia describes formative evaluation and preliminary efficacy testing of this Web-based tailored preoperative preparation program.

Parent-based adolescent sexual health interventions and effect on communication outcomes: a systematic review and meta-analyses.

Science.gov (United States)

Santa Maria, Diane; Markham, Christine; Bluethmann, Shirley; Mullen, Patricia Dolan

2015-03-01

Parent-based adolescent sexual health interventions aim to reduce sexual risk behaviors by bolstering parental protective behaviors. Few studies of theory use, methods, applications, delivery and outcomes of parent-based interventions have been conducted. A systematic search of databases for the period 1998-2013 identified 28 published trials of U.S. parent-based interventions to examine theory use, setting, reach, delivery mode, dose and effects on parent-child communication. Established coding schemes were used to assess use of theory and describe methods employed to achieve behavioral change; intervention effects were explored in meta-analyses. Most interventions were conducted with minority parents in group sessions or via self-paced activities; interventions averaged seven hours, and most used theory extensively. Meta-analyses found improvements in sexual health communication: Analysis of 11 controlled trials indicated a medium effect on increasing communication (Cohen's d, 0.5), and analysis of nine trials found a large effect on increasing parental comfort with communication (0.7); effects were positive regardless of delivery mode or intervention dose. Intervention participants were 68% more likely than controls to report increased communication and 75% more likely to report increased comfort. These findings point to gaps in the range of programs examined in published trials-for example, interventions for parents of sexual minority youth, programs for custodial grandparents and faith-based services. Yet they provide support for the effectiveness of parent-based interventions in improving communication. Innovative delivery approaches could extend programs' reach, and further research on sexual health outcomes would facilitate the meta-analysis of intervention effectiveness in improving adolescent sexual health behaviors. Copyright © 2015 by the Guttmacher Institute.

Investimento parental e desenvolvimento da criança Parental investment and child development

Directory of Open Access Journals (Sweden)

Eulina Rocha Lordelo

2006-12-01

Full Text Available Segundo a teoria do investimento parental, seria esperada uma relação entre condições de criação da mãe e sua carreira reprodutiva e, por conseqüência, seus padrões de cuidado aos filhos, com repercussões no desenvolvimento das crianças. Esta pesquisa buscou verificar essas relações, em amostra de 37 mães e seus filhos entre um e quatro anos, de um bairro pobre de Salvador, Bahia. Foi investigada a história familiar e reprodutiva das mães, associada a resultados desenvolvimentais das crianças, medidos através das escalas Bayley e WIPPSI-R, em quatro avaliações realizadas ao longo de três anos. Foram encontradas correlações entre condições de criação da mãe e sua carreira reprodutiva subseqüente. Por sua vez, esses padrões mostraram-se modestamente relacionados ao desenvolvimento cognitivo de seus filhos, favorecendo as crianças cujas mães iniciaram sua vida reprodutiva mais tarde. Os resultados são, em geral, compatíveis com a teoria do investimento parental. Limitações do estudo e perspectivas futuras são discutidas.According to the parental investment theory, it would be expected an association between maternal family environment and her reproductive behavior and, as a consequence, her patterns of parental investment on her children, with effects on their development. This study aimed to verify that association, in a sample of 37 mothers and their children (one to four years old, in a poor neighborhood of Salvador, in the state of Bahia, Brazil. We studied the family and reproductive history of the mothers and assessed the cognitive development of children, through Bayley and WIPPSI-R scales, in four assessments during three years. We found correlation between the raising environment of the mother and her subsequent reproductive patterns. These patterns were related to cognitive development of children, favoring children whose mothers started their reproductive life later. The results are, in general

Parental Catastrophizing Partially Mediates the Association between Parent-Reported Child Pain Behavior and Parental Protective Responses

OpenAIRE

Langer, Shelby L.; Romano, Joan M.; Mancl, Lloyd; Levy, Rona L.

2014-01-01

This study sought to model and test the role of parental catastrophizing in relationship to parent-reported child pain behavior and parental protective (solicitous) responses to child pain in a sample of children with Inflammatory Bowel Disease and their parents (n = 184 dyads). Parents completed measures designed to assess cognitions about and responses to their child's abdominal pain. They also rated their child's pain behavior. Mediation analyses were performed using regression-based techn...

Parent-based interventions for preventing or reducing adolescent substance use: A systematic literature review

NARCIS (Netherlands)

Kuntsche, S.; Kuntsche, E.N.

2016-01-01

Despite the increasing relevance of peers, parents remain important socializing agents for their adolescent children and are therefore promising agents for inclusion in prevention or intervention programs. This systematic review provides an overview of the effectiveness of parent-based programs in

A ira dos anjos: uma análise psicológica e jurídica da alienação parental

Directory of Open Access Journals (Sweden)

Cláudia Roberta Leite Vieira Figueiredo

2017-12-01

Full Text Available A síndrome de alienação parental (SAP consiste num termo cunhado pelo psiquiatra norte-americano Richard Gardner, que a descreveu como um distúrbio infantil que acometia crianças e adolescentes envolvidos em situações de disputa de guarda judicial entre os pais. A SAP insere-se no contexto do Poder Judiciário em muitos casos de separação ou divórcio, quando marcas nocivas são deixadas em um dos cônjuges, o qual alimenta sentimentos de rancor, levando-o a criar falsas situações a partir de pensamentos irracionais, manipulando os filhos para que também desenvolvam sentimentos negativos em relação ao outro genitor, com objetivo de afastá-los totalmente de sua convivência com este. As discussões jurídicas em torno da SAP envolvem diversas ciências, especialmente a psicologia e a psiquiatria. No Brasil desde agosto de 2010, a Lei 12.318/2010 conceitua e reconhece a alienação parental (AP e a SAP, alocando-as definitivamente no direito brasileiro. A Lei prevê sanções ao genitor que causar impedimentos à convivência do(s filho(s com o outro responsável. O presente trabalho tem como objetivo descortinar a SAP sob uma ótica multidisciplinar, abordando seus mais relevantes aspectos psicológicos e suas repercussões no âmbito jurídico.

Estresse pós-traumático da criança sobrevivente de câncer e sua percepção acerca da experiência parental Post-Traumatic stress disorder of the child survivor of cancer and their perception about parental experience

Directory of Open Access Journals (Sweden)

Camila Tokarski Boaventura

2012-08-01

Full Text Available Nas últimas décadas, paralelamente ao aumento progressivo das taxas de cura em Oncologia Pediátrica, evidencia-se um interesse crescente pela sobrevivência ao câncer na infância. Esta investigação teve como objetivo analisar essa experiência de sobrevivência ao câncer na infância, enfatizando a percepção da criança acerca da experiência parental e avaliando o Transtorno de Estresse Pós-traumático infantil nesse contexto. Realizaram-se entrevistas semiestruturadas com a criança, complementadas pela aplicação do UCLA Posttraumatic Stress Disorder Reaction Index for DSM-IV - Child Version. Evidenciaram-se taxas moderadas de diagnóstico total e parcial de Transtorno de Estresse Pós-Traumático. Especificamente no que se refere aos sintomas de estresse pós-traumático, os escores encontrados foram baixos. Os resultados também sugeriram uma relação entre o modo como a experiência parental é percebida pela criança e o escore total de gravidade de Transtorno de Estresse Pós-traumático Infantil. Recomendam-se estudos com amostras mais extensas, visando disponibilizar instrumentos de avaliação para a área da saúde.This investigation aimed to describe, analyze and comprehend the experience of survival after childhood cancer, emphasizing the child's perception of the parent's experience and the evaluation of the child Post-Traumatic Stress Disorder. So, semi-structured interviews were conducted with the participants, who also answered the UCLA Posttraumatic Stress Disorder Reaction Index for DSM-IV - Child Version. The child's perception of the parental experience confirmed evidences pointed out by specialized literature. The total and partial diagnosis rates of Post-Traumatic Stress Disorder were moderate. Finally, it was possible to suggest a likely connection between the way the parental experience is perceived and the total severity score of the Post-Traumatic Stress Disorder in children. Further investigation, with

Paralisia cerebral e síndrome de Down: nível de conhecimento e informação dos pais Cerebral palsy and Down syndrome: level of parental knowledge and information

Directory of Open Access Journals (Sweden)

Maysa Ferreira Martins Ribeiro

2011-04-01

Full Text Available O estudo objetivou identificar e analisar pesquisas relacionadas ao conhecimento e às informações recebidas pelos pais de crianças com paralisia cerebral ou síndrome de Down. Tratase de revisão bibliográfica com limitação temporal de 1993 a 2008. Utilizaram-se as bases de dados informatizadas para a coleta das informações, tendo como palavras-chave os termos paralisia cerebral, síndrome de Down, conhecimento e família. Foram encontrados 57 estudos e selecionados 16; dentre estes, sete relacionados à paralisia cerebral, quatro referentes à síndrome de Down e cinco sobre deficiências diversas. Os pais recebem poucas informações dos profissionais e apresentam muitas dúvidas em relação à paralisia cerebral e à síndrome de Down, o que dificulta a adesão deles ao tratamento dos filhos, interfere nas práticas educacionais e nas tomadas de decisão. Existe carência de ações educacionais no sentido de mudar essa realidade. Somente uma pesquisa teve como proposta implementar estratégias de educação que buscassem ampliar o conhecimento da família a respeito de aspectos relacionados à síndrome de Down. Concluiu-se que há urgência em pesquisar e elaborar ações que contribuam para que os pais sejam mais bem informados e se tornem seguros no cuidado dos filhos.The study sought to identify and analyze research related to knowledge and information received by parents of children with cerebral palsy or Down syndrome about these disabilities. It involves a bibliographical revision limited to the period from 1996 through 2008. Computerized data bases were used to collect information, using the following terms as key words: cerebral palsy, Down syndrome, knowledge and family. Fifty-seven studies were located from which 16 were selected; of these, seven were related to cerebral palsy, four to Down syndrome and five were related to sundry deficiencies. The parents receive little information from the healthcare staff and clearly

Perícias Psicológicas em Processos Judiciais Envolvendo Suspeita de Alienação Parental

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Ilana Luiz Fermann

Full Text Available Resumo A alienação parental (AP é uma forma de abuso emocional que pode estar presente em processos judiciais envolvendo disputas de guarda. Nesse contexto, psicólogos(as comumente são convocados para perícias e elaboração de laudos psicológicos. Os laudos compõem as provas processuais e podem auxiliar os juízes em sua tomada de decisão. Os objetivos deste estudo foram: (1 verificar os critérios e indicadores de AP considerados pelos psicólogos(as em perícias incluídas em processos envolvendo guarda de crianças e suspeita de AP; (2 investigar quais os procedimentos de avaliação adotados; (3 avaliar a adequação dos laudos psicológicos emitidos pelos profissionais nomeados pelos juízes tendo como base orientações do Conselho Federal de Psicologia (CFP; (4 verificar se houve concordância entre conclusão do laudo psicológico e da sentença judicial sobre presença/ausência de AP. Foi realizada uma análise documental descritiva, a partir de oito laudos psicológicos, envolvendo dez crianças, que compunham os processos sentenciados ou em andamento que contivessem a suspeita de AP. Os resultados indicaram que: (1 ainda não há consenso entre critérios e indicadores de AP entre os profissionais; (2 entrevistas e testes projetivos foram procedimentos predominantes; (3 nenhum dos oito laudos analisados estava de acordo com as exigências do CFP sobre a elaboração de documentos e (4 juízes e psicólogos posicionaram-se da mesma forma em quatro casos, dois considerando a existência de AP e dois a ausência. Conclui-se que não há um padrão para avaliação de AP adotado pelos psicólogos(as em perícias e os problemas quanto a adequação de documentos sugerem a necessidade de maior capacitação profissional para atuação na área.

Warm/cool-tone switchable thermochromic material for smart windows by orthogonally integrating properties of pillar[6]arene and ferrocene.

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Wang, Sai; Xu, Zuqiang; Wang, Tingting; Xiao, Tangxin; Hu, Xiao-Yu; Shen, Ying-Zhong; Wang, Leyong

2018-04-30

Functional materials play a vital role in the fabrication of smart windows, which can provide a more comfortable indoor environment for humans to enjoy a better lifestyle. Traditional materials for smart windows tend to possess only a single functionality with the purpose of regulating the input of solar energy. However, different color tones also have great influences on human emotions. Herein, a strategy for orthogonal integration of different properties is proposed, namely the thermo-responsiveness of ethylene glycol-modified pillar[6]arene (EGP6) and the redox-induced reversible color switching of ferrocene/ferrocenium groups are orthogonally integrated into one system. This gives rise to a material with cooperative and non-interfering dual functions, featuring both thermochromism and warm/cool tone-switchability. Consequently, the obtained bifunctional material for fabricating smart windows can not only regulate the input of solar energy but also can provide a more comfortable color tone to improve the feelings and emotions of people in indoor environments.

Positive parenting by parents of children up to three years of age: development and validation of measurement scales Ejercicio parental positivo por los padres de niños hasta tres años: construcción y validación de escalas de medición Exercício da parentalidade positiva pelos pais de crianças até três anos: construção e validação de escalas de medida

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Maria da Saudade de Oliveira Custódio Lopes

2012-08-01

Full Text Available This study aimed to describe the development and validation of three multidimensional scales in which the same 30 items, distributed among five dimensions, measure parents' self-perceived confidence, difficulties and knowledge needs in the exercise of positive parenting during the first three years of the child's life. The content of the scales resulted from the literature and exploratory studies and was validated by experts. The analysis of its reliability and validity, using Pearson's correlations and Cronbach's alpha, was based on data from a questionnaire administered to a non-probabilistic sample of 1011 parents. In the dimensions and items, α-values ranged between 0.769 and 0.890 and r-coefficients were >0.37;p Este estudio tuvo el objetivo de describir la construcción y validación de tres escalas multidimensionales en que los mismos 30 ítems, distribuidos en 5 dimensiones, miden la auto-percepción de la confianza, de las dificultades y de la necesidad de conocimientos de los padres en el ejercicio parental positivo en los primeros tres años del niño. El contenido de las escalas resultó de la literatura y de estudios de explotación y fue validado por expertos. El análisis de su fidelidad y validez partió de los resultados de un cuestionario aplicado la una muestra no probabilística de 1011 padres. En las dimensiones e ítems, los valores de Coeficiente Alfa de Cronbach se situaron entre 0,769 y 0,890 y los de fueron >0,37; pOs objetivos deste estudo foram descrever a construção e obtenção de algumas evidências de validade de três escalas multidimensionais em que os mesmos 30 itens, distribuídos por cinco dimensões, medem a autoperceção da confiança, das dificuldades e da necessidade de conhecimentos dos pais no exercício da parentalidade positiva, nos primeiros três anos da criança. O conteúdo das escalas resultou da literatura e de estudos exploratórios e foi validado por peritos. A análise da sua

Weight-based Teasing and Bullying in Children: How Parents Can Help

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... Weight-based Teasing and Bullying in Children: How Parents Can Help Page Content Children with obesity have to deal with many challenges beyond pressures to lose weight. They may also be teased ...

Secure base scripts are associated with maternal parenting behavior across contexts and reflective functioning among trauma-exposed mothers.

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Huth-Bocks, Alissa C; Muzik, Maria; Beeghly, Marjorie; Earls, Lauren; Stacks, Ann M

2014-01-01

There is growing evidence that "secure-base scripts" are an important part of the cognitive underpinnings of internal working models of attachment. Recent research in middle class samples has shown that secure-base scripts are linked to maternal attachment-oriented behavior and child outcomes. However, little is known about the correlates of secure base scripts in higher-risk samples. Participants in the current study included 115 mothers who were oversampled for childhood maltreatment and their infants. Results revealed that a higher level of secure base scriptedness was significantly related to more positive and less negative maternal parenting in both unstructured free play and structured teaching contexts, and to higher reflective functioning scores on the Parent Development Interview-Revised Short Form. Associations with parent-child secure base scripts, specifically, indicate some level of relationship-specificity in attachment scripts. Many, but not all, significant associations remained after controlling for family income and maternal age. Findings suggest that assessing secure base scripts among mothers known to be at risk for parenting difficulties may be important for interventions aimed at altering problematic parental representations and caregiving behavior.

Diels-Alder cyclo-addition as an efficient tool for linking π-donors onto fullerene C60

International Nuclear Information System (INIS)

Hudhomme, P.

2006-01-01

Diels-Alder reaction of endo-cyclic, acyclic 1,3-dienes or (hetero) o-quinodimethanes with the dienophilic fullerene C 60 is presented as an efficient tool for linking electro-active units giving rise to systems where both the donor and C 60 partners take up well defined volumes and orientations with respect to one another. While porphyrin is the most frequently used electron donor in artificial photosynthetic models, C 60 -based tetrathiafulvalene (TTF) or p-conjugated oligomer adducts remain interesting candidates for the preparation of photovoltaic devices. In this account, we focus on the use of the Diels-Alder cyclo-addition and its use in the synthesis of TTF-C 60 dyads, (TTF) n -C 60 polyads and C 60 -TTF-C 60 dumbbells as part of ongoing research into materials which display efficient photo-induced electron transfer. (author)

Avaliação da pressão arterial em bombeiros militares filhos de hipertensos através da monitorização ambulatorial da pressão arterial Using ambulatory blood pressure monitoring to assess blood pressure of firefighters with parental history of hypertension

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Carlos Eduardo de Mattos

2006-12-01

Full Text Available OBJETIVO: Avaliar a influência do antecedente familiar de hipertensão arterial sistêmica (HASF sobre o efeito do estresse do trabalho em bombeiros militares comunicantes (BMC, através da monitorização ambulatorial da pressão arterial (MAPA. MÉTODOS: Estudo prospectivo caso-controle. Foi realizada a MAPA em 66 BMC saudáveis, durante 12 horas de trabalho na central de comunicações (CC, sendo 34 filhos de hipertensos (grupo 1 e 32 filhos de normotensos (grupo 2. RESULTADOS: O grupo 1 diferiu do grupo 2, pois apresentou, no trabalho, maiores médias sistólicas (134,1 ± 9,9 mmHg X 120,8 ± 9,9 mmHg p OBJECTIVE: To evaluate the influence of family history of systemic arterial hypertension (FSAH on the effect of stress from work in Uniformed Firefighters (BMCs through Ambulatory Blood Pressure Monitoring (ABPM. METHODS: A prospective case-control study. Sixty-six healthy BMC underwent ABPM during 12 hours of work at the Communication Center (CC. Thirty-four had hypertensive parents (group 1 and thirty-two had normotensive parents (group 2. RESULTS: Group I differed from group 2 in that it showed higher mean systolic (134.1 ± 9.9 mmHg X 120.8 ± 9.9 mmHg p < 0.0001 and diastolic (83.8 ± 8.3 mmHg X 72.9 ± 8.6 mmHg p < 0.001 blood pressure, in addition to greater systolic (31.4 ± 25.6 % X 9.4 ± 9.4 % p = 0.0001 and diastolic (28.3 ± 26.6 % X 6.1 ± 8.9 % p = 0.0001 loads. The prevalence of systemic arterial hypertension (SAH in group 1 at the workplace was 32.3%. Monitored away from the job, these subjects showed normal blood pressure (functionally hypertensive. Group 2 revealed normal blood pressure (BP at work. CONCLUSION: Higher blood pressure in BMC with hypertensive parents is explained independently by the SAH. Subjects who developed SAH during their work at the CC may be considered functionally hypertensive, whereas those with normotensive parents and who underwent psychological stress are free of blood pressure changes.

Home-based bimanual training based on motor learning principles in children with unilateral cerebral palsy and their parents (the COAD-study): rationale and protocols.

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Schnackers, Marlous; Beckers, Laura; Janssen-Potten, Yvonne; Aarts, Pauline; Rameckers, Eugène; van der Burg, Jan; de Groot, Imelda; Smeets, Rob; Geurts, Sander; Steenbergen, Bert

2018-04-18

Home-based training is considered an important intervention in rehabilitation of children with unilateral cerebral palsy. Despite consensus on the value of home-based upper limb training, no evidence-based best practice exists. Promoting compliance of children to adhere to an intensive program while keeping parental stress levels low is an important challenge when designing home-based training programs. Incorporating implicit motor learning principles emerges to be a promising method to resolve this challenge. Here we describe two protocols for home-based bimanual training programs, one based on implicit motor learning principles and one based on explicit motor learning principles, for children with unilateral spastic cerebral palsy aged 2 through 7 years. Children receive goal-oriented, task-specific bimanual training in their home environment from their parents for 3.5 h/week for 12 weeks according to an individualized program. Parents will be intensively coached by a multidisciplinary team, consisting of a pediatric therapist and remedial educationalist. Both programs consist of a preparation phase (goal setting, introductory meetings with coaching professionals, design of individualized program, instruction of parents, home visit) and home-based training phase (training, video-recordings, registrations, and telecoaching and home visits by the coaching team). The programs contrast with respect to the teaching strategy, i.e. how the parents support their child during training. In both programs parents provide their child with instructions and feedback that focus on the activity (i.e. task-oriented) or the result of the activity (i.e. result-oriented). However, in the explicit program parents are in addition instructed to give exact instructions and feedback on the motor performance of the bimanual activities, whereas in the implicit program the use of both hands and the appropriate motor performance of the activity are elicited via manipulation of the

An overview on the research of Sr2IrO4-based system probed by X-ray absorption spectroscopy

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Cheng, Jie; Zhu, Chaomin; Ma, Jingyuan; Wang, Yu; Liu, Shengli

2018-03-01

Investigations of materials with 5d transition metal ions have opened up new paradigms in condensed-matter physics because of their large spin-orbit coupling (SOC) interactions. The typical compound is Sr2IrO4, which attracted much attention due to its similarities to the parent compound of high-Tc cuprate superconductor La2CuO4. Theoretical calculations predicted that the unconventional superconductivity can occur in carrier doped-Sr2IrO4 system. Until now, hundreds of experimental methods were devoted to investigate the carrier doping effect on Sr2IrO4. Synchrotron radiation-based X-ray absorption spectroscopy (XAS) made great contributions to the local lattice and electronic structure, and also the intimate relationship between the local structure and physical properties induced by carrier doping. The aim of this review is a short introduction to the progress of research on Sr2IrO4-based system probed by the unique technique — XAS, including the strength of the SOC, valence changes upon doping and even local lattice structure with atomic level for this Sr2IrO4-based family.

In Search of the Sources of Psychologically Controlling Parenting: The Role of Parental Separation Anxiety and Parental Maladaptive Perfectionism

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Soenens, Bart; Vansteenkiste, Maarten; Duriez, Bart; Goossens, Luc

2006-01-01

This study investigated the role of two dimensions of parental separation anxiety--Anxiety about Adolescent Distancing (AAD) and Comfort with Secure Base Role (CSBR)--and parental maladaptive perfectionism in the prediction of psychologically controlling parenting. In a sample of middle adolescents and their parents (N=677), it was found that…

[Behavioral intervention for preschool children with autism – outcome of parent-based Intervention].

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Molnár, Claire; Eldevik, Sigmund

2017-01-01

Early intensive behavioral intervention (EIBI) has proved to be an effective intervention for children with autism spectrum disorder (ASD). In this exploratory study, we evaluated the effects of a community-based service model with parents as active therapists. 13 children with ASD between 2 and 5 years of age at intake participated in the study. A waiting-list control design was employed. The children received 1 year of home-based EIBI for approximately 20 hours a week, their parents functioning as primary therapists. The waiting-list control group consisted of seven children who were tested 6 months before the intervention commenced. The intervention was based on the University of California at Los Angeles Young Autism Project model (UCLA YAP; Lovaas, 1981, 1987, 2003). The Psychoeducational Profile (3rd ed., PEP-3), the Parenting Stress Index (PSI), and the Childhood Autism Rating Scale (2nd ed., CARS 2) were used to measure outcome. In addition, a mental developmental index (MDI) was calculated on the basis of the Cognitive Verbal/Preverbal subscale of the PEP-3. After 1 year of EIBI, we found a significant increase in the PEP-3 scores and MDI scores as well as a significant reduction in the CARS 2 scores. No significant changes were seen when participants were on the waiting list. The stress level of the parents did not change significantly and in fact showed overall a slight decrease. This model of providing EIBI appears to hold some promise. Comprehensive parental involvement did not affect their stress level. The study need to be replicated with a larger sample and an improved design.

Youths' and Parents' Views on the Acceptability and Design of a Video-Based Tobacco Prevention Intervention

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Mahabee-Gittens, E. Melinda; Vaughn, Lisa; Gordon, Judith S.

2010-01-01

The purpose of this study was to evaluate the acceptability of a brief, video-based parental intervention that modeled parent-child communication about tobacco, delivered within an emergency department (ED) setting. While waiting to be seen by a physician in the ED, 20 parent-youth dyads watched the video together and then private, semi-structured…

An easy compartment-less biofuel cell construction based on the physical co-inclusion of enzyme and mediator redox within pressed graphite discs

Energy Technology Data Exchange (ETDEWEB)

Cosnier, Serge [Department de Chimie Moleculaire UMR-5250, ICMG FR-2607, CNRS Universite Joseph Fourier, BP-53, 38041 Grenoble (France); Shan, Dan [Department de Chimie Moleculaire UMR-5250, ICMG FR-2607, CNRS Universite Joseph Fourier, BP-53, 38041 Grenoble (France); School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 (China); Ding, Shou-Nian [Department de Chimie Moleculaire UMR-5250, ICMG FR-2607, CNRS Universite Joseph Fourier, BP-53, 38041 Grenoble (France); School of Chemistry and Chemical Engineering, Shouthest University, Nanjing 211189 (China)

2010-02-15

We report on the easy and fast immobilization of glucose oxidase (GOD) and laccase by mechanical compression with graphite particles to form disc electrodes. The electrical wiring of GOD and laccase was efficiently carried out by their co-inclusion with ferrocene (Fc) and 2,2'-azinobis (3-ethylbenzothiazoline-6-sulfonate) diammonium salt (ABTS) respectively. A glucose/air compartment-less biofuel cell was constructed based on the association of GOD-ferrocene-graphite disc and laccase-ABTS - graphite disc electrodes as bioanode and biocathode respectively. Such biofuel cell yielded a power density of 23 {mu}W cm{sup -2} at 0.33 V as well as an open-circuit voltage and a short-circuit current of 0.63 V and 166 {mu}A, respectively. (author)

Detecting child abuse based on parental characteristics: Does The Hague Protocol cause parents to avoid the Emergency Department?

NARCIS (Netherlands)

Diderich, H.M.; Fekkes, M.; Dechesne, M.; Buitendijk, S.E.; Oudesluys-Murphy, A.M.

2015-01-01

Objectives: The Hague Protocol is used by professionals at the adult Emergency Departments (ED) in The Netherlands to detect child abuse based on three parental characteristics: (1) domestic violence, (2) substance abuse or (3) suicide attempt or self-harm. After detection, a referral is made to the

A Self-Administered Parent Training Program Based upon the Principles of Applied Behavior Analysis

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Maguire, Heather M.

2012-01-01

Parents often respond to challenging behavior exhibited by their children in such a way that unintentionally strengthens it. Applied behavior analysis (ABA) is a research-based science that has been proven effective in remediating challenging behavior in children. Although many parents could benefit from using strategies from the field of ABA with…

Electrochemical impedance spectroscopy for analytical determination of paraquat in meconium samples using an immunosensor modified with fullerene, ferrocene and ionic liquid

Energy Technology Data Exchange (ETDEWEB)

Sun Xiulan [State Key Laboratory of Food Science and Technology, Wuxi 214122 (China); Li Zaijun, E-mail: zaijunli@263.ne [School of Chemical and Materials Engineering, Jiangnan University, Lihu Road 1800, Wuxi 214122 (China); Cai, Yan; Wei, Zhilei [School of Chemical and Materials Engineering, Jiangnan University, Lihu Road 1800, Wuxi 214122 (China); Fang Yinjun; Ren Guoxiao; Huang Yaru [Zhejiang Zanyu Technology Limited Corporation, Hangzhou 311215 (China)

2011-01-01

The paper reports a highly sensitive electrochemical immunosensor for the detection of paraquat. The immunosensor bases on glassy carbon electrode modified with a composite made from fullerene, ferrocene and the ionic liquid. The components were immobilized on the electrode surface by chitosan. The antibody of paraquat was covalently conjugated to the surface which was then blocked with bovine serum albumin. Analytical characteristics of the immunosensor were investigated by electrochemical impedance spectroscopy. It offers good repeatability (RSD = 1.5%), a stability of more than 150 days, an impedimetric response to paraquat in the range from 3.89 x 10{sup -11} to 4.0 x 10{sup -8} mol L{sup -1}, and a detection limit (S/N = 3) of 9.0 x 10{sup -12} mol L{sup -1}. The effects of omitting fullerene and the ionic liquid were well tested. The results indicated that sensitivity of the immunosensor is 3.7-fold better if fullerene and ionic liquid are used. This demonstrates that fullerene facilitates electron transfer on surface of the electrode due to unique electrochemical properties, while the ionic liquid provides biocompatible microenvironment for the antibody, which results in the enhanced sensitivity and stability. Moreover, surface morphology feature and electrochemical properties of the electrode were also examined. The method was satisfactorily applied to the determination of paraquat in meconium.

Group-based parent training programmes for improving emotional and behavioural adjustment in young children.

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Barlow, Jane; Bergman, Hanna; Kornør, Hege; Wei, Yinghui; Bennett, Cathy

2016-08-01

Emotional and behavioural problems in children are common. Research suggests that parenting has an important role to play in helping children to become well-adjusted, and that the first few months and years are especially important. Parenting programmes may have a role to play in improving the emotional and behavioural adjustment of infants and toddlers, and this review examined their effectiveness with parents and carers of young children. 1. To establish whether group-based parenting programmes are effective in improving the emotional and behavioural adjustment of young children (maximum mean age of three years and 11 months); and2. To assess whether parenting programmes are effective in the primary prevention of emotional and behavioural problems. In July 2015 we searched CENTRAL (the Cochrane Library), Ovid MEDLINE, Embase (Ovid), and 10 other databases. We also searched two trial registers and handsearched reference lists of included studies and relevant systematic reviews. Two reviewers independently assessed the records retrieved by the search. We included randomised controlled trials (RCTs) and quasi-RCTs of group-based parenting programmes that had used at least one standardised instrument to measure emotional and behavioural adjustment in children. One reviewer extracted data and a second reviewer checked the extracted data. We presented the results for each outcome in each study as standardised mean differences (SMDs) with 95% confidence intervals (CIs). Where appropriate, we combined the results in a meta-analysis using a random-effects model. We used the GRADE (Grades of Recommendations, Assessment, Development, and Evaluation) approach to assess the overall quality of the body of evidence for each outcome. We identified 22 RCTs and two quasi-RCTs evaluating the effectiveness of group-based parenting programmes in improving the emotional and behavioural adjustment of children aged up to three years and 11 months (maximum mean age three years 11 months

Measurement of Family-centered care perception and parental stress in a neonatal unit.

Science.gov (United States)

Balbino, Flávia Simphronio; Balieiro, Maria Magda Ferreira Gomes; Mandetta, Myriam Aparecida

2016-08-08

to evaluate the effects of the implementation of the Patient and Family-Centered Care Model on parents and healthcare perceptions and parental stress. a quasi-experimental study developed in a neonatal unit of a university hospital in the municipality of São Paulo, Brazil, with the implementation of this model of care. Data collection were performed by two sample groups, one using non-equivalent groups of parents, and another using equivalent groups of healthcare professionals. The instruments Perceptions of Family-Centered Care-Parent Brazilian Version, Perceptions of Family-Centered Care-Staff Brazilian Version and Parental Stress Scale: Neonatal Intensive Care Unit, were applied to 132 parents of newborns hospitalized and to 57 professionals. there was a statistically significant improvement in the perceptions of the parents in most items assessed (p ≤0,05) and for the staff in relation to the family welcome in the neonatal unit (p = 0.041) and to the comprehension of the family's experience with the infant´s hospitalization (p = 0,050). There was a reduction in the average scores of parental stress, with a greater decrease in the Alteration in Parental Role from 4,2 to 3,8 (p = 0,048). the interventions improved the perceptions of parents and healthcare team related to patient and family-centered care and contributed to reducing parental stress. avaliar os efeitos da implementação do Modelo do Cuidado Centrado no Paciente e Família na percepção de pais e profissionais de saúde e no estresse parental. Estudo quase experimental com grupos não equivalentes para avaliação dos efeitos da intervenção na percepção de pais; e com grupos equivalentes para a avaliação na percepção de profissionais de saúde, desenvolvido na unidade neonatal de um hospital universitário do município de São Paulo. Os instrumentos, Percepção do Cuidado Centrado na Família- Pais versão brasileira, Percepção do Cuidado Centrado na Família- Equipe versão

Rare variant association analysis in case-parents studies by allowing for missing parental genotypes.

Science.gov (United States)

Li, Yumei; Xiang, Yang; Xu, Chao; Shen, Hui; Deng, Hongwen

2018-01-15

The development of next-generation sequencing technologies has facilitated the identification of rare variants. Family-based design is commonly used to effectively control for population admixture and substructure, which is more prominent for rare variants. Case-parents studies, as typical strategies in family-based design, are widely used in rare variant-disease association analysis. Current methods in case-parents studies are based on complete case-parents data; however, parental genotypes may be missing in case-parents trios, and removing these data may lead to a loss in statistical power. The present study focuses on testing for rare variant-disease association in case-parents study by allowing for missing parental genotypes. In this report, we extended the collapsing method for rare variant association analysis in case-parents studies to allow for missing parental genotypes, and investigated the performance of two methods by using the difference of genotypes between affected offspring and their corresponding "complements" in case-parent trios and TDT framework. Using simulations, we showed that, compared with the methods just only using complete case-parents data, the proposed strategy allowing for missing parental genotypes, or even adding unrelated affected individuals, can greatly improve the statistical power and meanwhile is not affected by population stratification. We conclude that adding case-parents data with missing parental genotypes to complete case-parents data set can greatly improve the power of our strategy for rare variant-disease association.

Locations of Joint Physical Activity in Parent-Child Pairs Based on Accelerometer and GPS Monitoring

Science.gov (United States)

Dunton, Genevieve Fridlund; Liao, Yue; Almanza, Estela; Jerrett, Micheal; Spruijt-Metz, Donna; Pentz, Mary Ann

2012-01-01

Background Parental factors may play an important role in influencing children’s physical activity levels. Purpose This cross-sectional study sought to describe the locations of joint physical activity among parents and children. Methods Parent-child pairs (N = 291) wore an Actigraph GT2M accelerometer and GlobalSat BT-335 Global Positioning Systems (GPS) device over the same 7-day period. Children were ages 8–14 years. Joint behavior was defined by a linear separation distance of less than 50m between parent and child. Land use classifications were assigned to GPS data points. Results Joint physical activity was spread across residential locations (35%), and commercial venues (24%), and open spaces/parks (20%). Obese children and parents performed less joint physical activity in open spaces/parks than under/normal weight children and parents (p’s parent-child physical activity naturally occurs may inform location-based interventions to promote these behaviors. PMID:23011914

Mothers' and fathers' attendance in a community-based universally offered parenting program in Sweden.

Science.gov (United States)

Wells, Michael B; Sarkadi, Anna; Salari, Raziye

2016-05-01

Using a public health perspective, this study examined the characteristics of mothers and fathers who attended, compared to those who did not attend, a community-based practitioner-led universally offered parenting program. Mothers (141) and fathers (96) of 4- to 5-year-olds completed a set of questionnaires, including their demographic characteristics, their child's behavioral and emotional problems, and their own parenting behavior. They were all then given the opportunity to attend level 2 of the Triple P--Positive Parenting Program. During the first six months of the study, 33 mothers and 11 fathers opted to attend the program. The relation between program attendance and parental characteristics was similar for mothers and fathers. In general, fathers, non-native and lower educated parents were less likely to attend the program. Mothers, but not fathers, were more likely to attend if they reported more child behavior problems, while fathers, but not mothers, were observed at a trend level to attend if they perceived their child as having more emotional problems. In addition, parents in general were more likely to attend if they used more harsh parenting strategies. Although the universal offer did not reach parents universally, generally those parents who needed it were more likely to attend. Furthermore, this study shows that different factors may impact mothers' and fathers' attendance; therefore, parental data should be analyzed separately and different recruitment strategies should be used for mothers and fathers. © 2015 the Nordic Societies of Public Health.

Active Parenting Now: Program Kit.

Science.gov (United States)

Popkin, Michael H.

Based largely on the theories of Alfred Adler and Rudolf Dreikurs, this parent education curriculum is a video-based interactive learning experience that teaches a comprehensive model of parenting to parents of children ages 5 to 12 years. The kit provides parents with the skills needed to help their children develop courage, responsibility, and…

Comparing parents' and overweight adolescents' reports on parent mealtime actions.

Science.gov (United States)

Volpe, Carolina Bertagnoli; Petty, Maria Luiza Blanques; de Souza, Altay Alves Lino; Escrivão, Maria Arlete Meil Schimith

2018-01-01

This study aimed to compare answers given by parents and their adolescent children to the Portuguese version of the Parent Mealtime Action Scale (PMAS) and to assess associations among the reported behaviors. To compare these answers, a cross-sectional study was conducted in a sample of 72 patients of the Obesity Clinic of the Division of Nutrology of the Pediatrics Department at the Federal University of São Paulo (Unifesp), Brazil. These patients were aged from 10 years to 19 years and 11 months, and their parents or legal guardians also participated. First, parents were interviewed and instructed to answer how often they perform each behavior measured by the PMAS (never, sometimes or always). Next, the same questions were answered by the adolescents. The general linear model (GLM) showed the effects of the interviewees and of the interaction between interviewees and sex. We also observed a triple interaction effect (sex x interviewees x categorized age). The internal reliability of the PMAS was higher for parental answers than for those given by the children. This finding is probably observed because the scale has been developed and validated to evaluate the pattern of parental responses concerning their eating practices during their children's meals. In addition, although parents believe they are engaging in certain behaviors, the effectiveness of these strategies may not be recognized by their children. Very low intraclass correlation coefficients were observed between parents' and children's answers to the original domains of the PMAS (ICC: 0.130-0.578), suggesting that the factorial structure of the PMAS may only be used to assess parental behavior, as it is not sufficiently accurate to assess the children's understanding of parent mealtime actions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Parental intimate partner homicide and its consequences for children : protocol for a population-based study

NARCIS (Netherlands)

Alisic, Eva; Groot, Arend; Snetselaar, Hanneke; Stroeken, Tielke; van de Putte, Elise

2015-01-01

Background: The loss of a parent due to intimate partner homicide has a major impact on children. Professionals involved have to make far-reaching decisions regarding placement, guardianship, mental health care and contact with the perpetrating parent, without an evidence base to guide these

The Likelihood of Parent-Adult Child Coresidence: Effects of Family Structure and Parental Characteristics.

Science.gov (United States)

Aquilino, William S.

1990-01-01

Estimated influence of child, parent, and family structural characteristics on likelihood of parents having coresident adult child, based on national sample of 4,893 parents. Results indicated most parents maintained own households and most parents and adult children who coresided lived in parents' home. Family structure was found to exert strong…

Ferrocene-based Lewis acids and Lewis pairs: Synthesis and ...

Indian Academy of Sciences (India)

The design and synthesis of molecules containing non-interacting Lewis base and Lewis acid groups. [Frustrated Lewis pairs (FLP's)] have received intense attention due to their potential applications in the area of molecular catalysis.1–3. For example,. Stephen's and co-workers have demonstrated that the unquenched ...

¿Necesidad Económica o Preferencias Culturales? La Justificación Parental del Trabajo Infantil en Chile Economic Constraints or Cultural Preferences? The Parent Justification of Child Labor in Chile

Directory of Open Access Journals (Sweden)

María Francisca del Río

2008-11-01

Full Text Available Con base en los datos de la Primera Encuesta Nacional sobre Trabajo Infantil realizada el año 2003 en Chile, se analizó la justificación parental para el trabajo de sus hijos. Se hipotetizó que se observaría una mayor probabilidad de justificación económica del trabajo infantil para los casos de mayor vulnerabilidad, es decir, niños y niñas de bajo nivel socioeconómico (NSE, menores de 12 años y el grupo de las niñas y adolescentes mujeres. El análisis de los datos, mediante una prueba de regresión logística, reveló que, si bien la necesidad económica efectivamente continúa siendo el principal motor del trabajo infantil en algunos grupos más vulnerables, las preferencias culturales y la participación de los adolescentes en esta decisión tienen un peso cada vez más importante.Using data from the First National Survey on Children Labor conducted in 2003, we analyzed parental justification for children labor. We hypothesized that a higher probability of economic justification would be observed in parents of children from vulnerable groups: lower socioeconomic status (SES, children younger than 12 years, and girls. Logistic regression revealed that economic constraints are the most common justification among the more vulnerable groups, but that others reasons, such as cultural preferences and adolescence participation in the decision making process, are increasingly important.

Engaging military parents in a home-based reintegration program: a consideration of strategies.

Science.gov (United States)

Ross, Abigail M; DeVoe, Ellen R

2014-02-01

For more than a decade, the long wars in Afghanistan and Iraq have placed tremendous and cumulative strain on U.S. military personnel and their families. The high operational tempo, length, and number of deployments-and greater in-theater exposure to threat-have resulted in well-documented psychological health concerns among service members and veterans. In addition, there is increasing and compelling evidence describing the significant deleterious impact of the deployment cycle on family members, including children, in military-connected families. However, rates of engagement and service utilization in prevention and intervention services continue to lag far below apparent need among service members and their families, because of both practical and psychological barriers. The authors describe the dynamic and ultimately successful process of engaging military families with young children in a home-based reintegration program designed to support parenting and strengthen parent-child relationships as service member parents move back into family life. In addition to the integration of existing evidence-based engagement strategies, the authors applied a strengths-based approach to working with military families and worked from a community-based participatory foundation to enhance family engagement and program completion. Implications for engagement of military personnel and their loved ones are discussed.

Steering teens safe: a randomized trial of a parent-based intervention to improve safe teen driving.

Science.gov (United States)

Peek-Asa, Corinne; Cavanaugh, Joseph E; Yang, Jingzhen; Chande, Vidya; Young, Tracy; Ramirez, Marizen

2014-07-31

Crashes are the leading cause of death for teens, and parent-based interventions are a promising approach. We assess the effectiveness of Steering Teens Safe, a parent-focused program to increase safe teen driving. Steering Teens Safe aimed to improve parental communication with teens about safe driving using motivational interviewing techniques in conjunction with 19 safe driving lessons. A randomized controlled trial involved 145 parent-teen dyads (70 intervention and 75 control). Intervention parents received a 45-minute session to learn the program with four follow-up phone sessions, a DVD, and a workbook. Control parents received a standard brochure about safe driving. Scores were developed to measure teen-reported quantity and quality of parental communication about safe driving. The main outcome measure was a previously validated Risky Driving Score reported by teens. Because the Score was highly skewed, a generalized linear model based on a gamma distribution was used for analysis. Intervention teens ranked their parent's success in talking about driving safety higher than control teens (p = 0.035) and reported that their parents talked about more topics (non-significant difference). The Risky Driving Score was 21% lower in intervention compared to control teens (85% CI = 0.60, 1.00). Interaction between communication quantity and the intervention was examined. Intervention teens who reported more successful communication had a 42% lower Risky Driving Score (95% CI = 0.37, 0.94) than control parents with less successful communication. This program had a positive although not strong effect, and it may hold the most promise in partnership with other programs, such as Driver's Education or Graduated Driver's License policies. ClinicalTrials.gov NCT01014923. Registered Nov. 16, 2009.

A phenomenologic investigation of pediatric residents' experiences being parented and giving parenting advice.

Science.gov (United States)

Bax, A C; Shawler, P M; Blackmon, D L; DeGrace, E W; Wolraich, M L

2016-09-01

Factors surrounding pediatricians' parenting advice and training on parenting during residency have not been well studied. The primary purpose of this study was to examine pediatric residents' self-reported experiences giving parenting advice and explore the relationship between parenting advice given and types of parenting residents received as children. Thirteen OUHSC pediatric residents were individually interviewed to examine experiences being parented and giving parenting advice. Phenomenological methods were used to explicate themes and secondary analyses explored relationships of findings based upon Baumrind's parenting styles (authoritative, authoritarian, permissive). While childhood experiences were not specifically correlated to the parenting advice style of pediatric residents interviewed, virtually all reported relying upon childhood experiences to generate their advice. Those describing authoritative parents reported giving more authoritative advice while others reported more variable advice. Core interview themes related to residents' parenting advice included anxiety about not being a parent, varying advice based on families' needs, and emphasis of positive interactions and consistency. Themes related to how residents were parented included discipline being a learning process for their parents and recalling that their parents always had expectations, yet always loved them. Pediatric residents interviewed reported giving family centered parenting advice with elements of positive interactions and consistency, but interviews highlighted many areas of apprehension residents have around giving parenting advice. Our study suggests that pediatric residents may benefit from more general educational opportunities to develop the content of their parenting advice, including reflecting on any impact from their own upbringing.

Beyond the discourse of reproductive choice: narratives of pregnancy resolution among Latina/o teenage parents.

Science.gov (United States)

Mann, Emily S; Cardona, Vanessa; Gómez, Cynthia A

2015-01-01

Despite the fact that the US teenage birth rate has declined dramatically in recent years, teen births among Latinas are higher than any other racial/ethnic group. Most studies focus on the causes and consequences of early motherhood among Latina teenagers, neglecting other important dimensions of the issue. This study examines how Latina/o teenage parents living in California narrate their experiences with unintended pregnancy resolution. Qualitative analysis reveals three central themes. First, participants expressed shock upon learning they or their partner was pregnant, followed by acceptance about their impending parenthood. Second, participants' views of abortion and adoption largely foreclosed these options as pathways by which to resolve their unintended pregnancies. Third, participants recounted numerous stories of the messages they received from parents, other family members and male partners that were frequently directive regarding how to resolve their pregnancies. These findings have implications for young people's reproductive health and rights, and for reproductive justice more broadly.

A SÍNDROME DA ALIENAÇÃO PARENTAL DIANTE DO DIVÓRCIO DOS PAIS: UMA PERSPECTIVA À LUZ DA LEI 12.318/10

OpenAIRE

Fernandes, Nathália Nayara Soares; URCA

2013-01-01

A temática do presente artigo tem por escopo mostrar um fenômeno que não é novo, mas que é desconhecido de muitas pessoas e que de certa forma, vem sendo tratado de forma retraída pelo universo jurídico. Trata-se da Síndrome da Alienação Parental (SAP), expressão esta, usada primeiramente por Richard Gardner, para caracterizar a influência que um dos genitores exerce sobre o filho para afastar o outro genitor. À luz de tal anseio, o presente trabalho tem por finalidade apresentar a Síndrome d...

Electrochemical Sensor for Determination of Ascorbic Acid Using a 2-Chlorobenzoyl Ferrocene/Carbon Nanotube Paste Electrode

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Sayed Zia Mohammadi

2016-12-01

Full Text Available A chemically modified carbon paste electrode with 2-chlorobenzoyl ferrocene (2CBF and carbon nanotube (2CBFCNPE was employed to study the electrocatalytic oxidation of ascorbic acid in aqueous solution using cyclic voltammetry, square wave voltammetry and chronoamperometry. The diffusion coefficient (D = 1.42 × 10-6 cm2 s-1, and the kinetic parameter such as the catalytic rate constant (k = 3.7 × 10 3 M-1 s-1 of ascorbic acid oxidation at the surface of 2CBFCNPE were determined using electrochemical approaches. It has been found that under an optimum condition (pH 4.0, the oxidation of ascorbic acid at the surface of such an electrode occurs at a potential about 85 mV less positive than that of an unmodified carbon paste electrode. Applying square wave voltammetry, in phosphate buffer solution (PBS of pH 4.0, the oxidation current increases linearly with two concentration intervals of ascorbic acid, one is 1.0 × 10-7-2.5 × 10-6 M and the other is 2.5 × 10-6-7.0 × 10-5 M. Detection limit (3δ was obtained 64.0 nM. This method was also examined for determination of ascorbic acid in some real samples.

Mediation of glycosylated and partially-deglycosylated glucose oxidase of Aspergillus niger by a ferrocene-derivatised detergent.

Science.gov (United States)

Fraser, D M; Zakeeruddin, S M; Grätzel, M

1992-01-30

A ferrocene-derivatised detergent, (11-ferrocenylundecyl) trimethylammonium bromide (FTMAB), when oxidised to the corresponding ferricinium ion, was found by electrochemical studies to be an effective electron acceptor for reduced glucose oxidase of Aspergillus niger (EC 1.13.4) and thus acts as a electron-transfer mediator between glucose oxidase and a working electrode held at a potential sufficiently positive to reoxidise reduced FTMAB. An increase in mediating activity was produced when FTMAB was present in concentrations above its critical micelle concentration. An 'enzyme electrode' was formed by adsorption of glucose oxidase and FTMAB surfactant on a graphite rod. The electrode functioned as an amperometric biosensor for glucose in phosphate-buffered saline solution. A mixed micelle of glucose oxidase and FTMAB, probably adsorbed on the electrode surface, appears to be advantageous for the amperometric determination of glucose. Additionally, glucose oxidase was treated with alpha-mannosidase. When this partially-deglycosylated glucose oxidase was incorporated in an enzyme electrode, a 100-fold increase in the second-order rate constant (k) for electron transfer between the enzyme and FTMAB was observed, together with increased current densities, with respect to the equivalent values for FTMAB and commercial glucose oxidase. The use of deglycosylated enzymes in biosensors is suggested.

Effect of iron on the production of high electrocatalytic activity carbons from ferrocene - PFA mixtures

International Nuclear Information System (INIS)

Cashion, J.D.; Brown, L.J.; Ozaki, J.; Yamada, K.; Nozawa, K.; Matsui, K.; Oya, A.

1999-01-01

Full text: We have previously studied the carbonisation of mixtures of ferrocene and poly(furfury 1 alcohol) (PFA) which, after heating at 700 deg C, produces electrodes with an electrocatalytic activity comparable to that of platinum. The carbons have a distinctive furry structure under the SEM and an XRD profile characteristic of turbostratic carbon. The iron had been converted to a mixture of α- and γiron and cementite, Fe 3 C and we conjectured that the furry carbon could be formed by the exsolution of carbon from the γ iron on cooling. The present experiments have shown that changing the cooling rate has only a small effect so exsolution is not the cause. However, the increased conductivity correlates well with the proportion of turbostratic carbon which, in turn, correlates with the percentage of cementite. The turbostratic carbon forms cages surrounding an iron phase, presumably the cementite. The conductivity data can be fitted well to either a power law or logarithmic behaviour above the percolation theory critical concentration. The normal percolation theory model for conductivity assumes a growing volume of good conductor in an insulating matrix. However, our system has a good conductor in a matrix of moderate conductor, the conductivity of which is not constant but is increasing under heat treatment at the same time as the good conductor volume is increasing. Some possible analyses will be given

The Parenting Questionnaire: An Inventory for Assessing Outcomes of Adlerian Parent Groups.

Science.gov (United States)

Tiffany, Jeanne; Tollefson, Nona

This study field tests and evaluates the Parenting Questionnaire, an instrument designed to assess parental attitudes and behavior, based on the child-raising theories of Dreikurs and Dinkmeyer and the Adlerian model for parent study groups. Dreikurs and Adler stress the purposive nature of children's behavior or misbehavior, and teach parents to…

Estilos parentais e consumo de drogas entre adolescentes: revisão sistemática Estilos parentales y el consumo de drogas entre adolescentes Parental styles and consumption of drugs among adolescents

Directory of Open Access Journals (Sweden)

Fernando Santana de Paiva

2009-03-01

Full Text Available Na tentativa de compreender o consumo abusivo de álcool e outras drogas durante a adolescência, inúmeras pesquisas têm apontado a família como um importante fator de risco ou proteção. Diante disso, o presente artigo teve por objetivo realizar uma revisão sistemática a respeito de trabalhos científicos sobre a associação entre os estilos e práticas parentais de socialização e o consumo de substâncias psicoativas entre adolescentes. Os artigos foram pesquisados em três bancos de dados - Medline, Adolec e Pubmed, sendo utilizados dois descritores de busca bibliográfica: parental styles e parental monitoring juntamente com substance use. A amostra final se constituiu de 30 artigos, provenientes de diferentes países. Através dos resultados deste trabalho, foi possível constatar uma significativa associação entre o consumo abusivo de álcool e outras drogas na adolescência e os estilos e práticas parentais. Estes achados apontam a importância de se conhecer essa relação no contexto brasileiro.En el intento de comprenderse el consumo abusivo de alcohol y otras drogas durante la adolescencia, innúmeras investigaciones apuntan la familia como un importante factor de riesgo o protección. Así, el presente artículo tuvo como objetivo realizar una revisión sistemática sobre trabajos científicos relativos a la asociación entre los estilos y prácticas parentales de socialización y el consumo de sustancias psicoactivas entre adolescentes. Los artículos fueran investigados en tres bancos de datos - Medline, Adolec y Pubmed, siendo utilizados dos descriptores en la búsqueda bibliográfica: parental styles y parental monitoring juntamente con substance use. La muestra final fue constituida por 30 artículos provenientes de diferentes países. A través de los resultados de este trabajo, fue posible constatar una significativa asociación entre el consumo abusivo de alcohol y otras drogas en la adolescencia y los estilos y

Consumer engagement and the development, evaluation and dissemination of evidence-based parenting programs

Science.gov (United States)

Sanders, Matthew R.; Kirby, James N.

2013-01-01

A consumer perspective can contribute much to enhancing the “ecological fit” of population level parenting interventions so they meet the needs of parents. This approach involves building relationships with consumer groups and soliciting consumer input into the relevance and acceptability of interventions, clarifying the enablers and barriers to engagement and involvement of parents, and clarifying variables that influence a parent’s program completion. The adoption of a more collaborative approach to working with consumers is important if meaningful population level change in the prevalence of serious social, emotional and behavioral problems in children and young people is to be achieved. Parents seeking assistance for their children’s behavior come from a diverse range of socioeconomic backgrounds, educational levels, cultures and languages. This paper examines consumer engagement strategies that can be employed throughout the process of program development, evaluation, training and dissemination and in “scaling up” the intervention. We argue that a multi-level public health approach to parenting intervention requires a strong consumer perspective to enable interventions to be more responsive to the preferences and needs of families and to ensure improved population reach of interventions. Examples from large scale dissemination trials are used to illustrate how consumer input can result in an increasingly differentiated suite of evidence-based parenting programs. PMID:22440062

Parental perceptions of school-based influenza immunisation in Ontario, Canada: a qualitative study

Science.gov (United States)

MacDougall, Donna; Crowe, Lois; Pereira, Jennifer A; Kwong, Jeffrey C; Quach, Susan; Wormsbecker, Anne E; Ramsay, Hilary; Salvadori, Marina I; Russell, Margaret L

2014-01-01

Objective To understand the perspectives of Ontario parents regarding the advantages and disadvantages of adding influenza immunisation to the currently existing Ontario school-based immunisation programmes. Design Descriptive qualitative study. Participants Parents of school-age children in Ontario, Canada, who were recruited using a variety of electronic strategies (social media, emails and media releases), and identified as eligible (Ontario resident, parent of one or more school-age children, able to read/write English) on the basis of a screening questionnaire. We used stratified purposeful sampling to obtain maximum variation in two groups: parents who had ever immunised at least one child against influenza or who had never done so. We conducted focus groups (teleconference or internet forum) and individual interviews to collect data. Thematic analysis was used to analyse the data. Setting Ontario, Canada. Results Of the 55 participants, 16 took part in four teleconference focus groups, 35 in 6 internet forum focus groups and four in individual interviews conducted between October 2012 and February 2013. Participants who stated that a school-based influenza immunisation programme would be worthwhile for their child valued its convenience and its potential to reduce influenza transmission without interfering with the family routine. However, most thought that for a programme to be acceptable, it would need to be well designed and voluntary, with adequate parental control and transparent communication between the key stakeholder groups of public health, schools and parents. Conclusions These results will benefit decision-makers in the public health and education sectors as they consider the advantages and disadvantages of immunising children in schools as part of a system-wide influenza prevention approach. Further research is needed to assess the perceptions of school board and public health stakeholders. PMID:24902736

Impact of parental weight status on a school-based weight management programme designed for Mexican-American children.

Science.gov (United States)

Moreno, J P; Johnston, C A; Hernandez, D C; LeNoble, J; Papaioannou, M A; Foreyt, J P

2016-10-01

While overweight and obese children are more likely to have overweight or obese parents, less is known about the effect of parental weight status on children's success in weight management programmes. This study was a secondary data analysis of a randomized controlled trial and investigated the impact of having zero, one or two obese parents on children's success in a school-based weight management programme. Sixty-one Mexican-American children participated in a 24-week school-based weight management intervention which took place in 2005-2006. Children's heights and weights were measured at baseline, 3, 6 and 12 months. Parental weight status was assessed at baseline. Repeated measures anova and ancova were conducted to compare changes in children's weight within and between groups, respectively. Within-group comparisons revealed that the intervention led to significant decreases in standardized body mass index (zBMI) for children with zero (F = 23.16, P weight management programme appears to be most efficacious for children with one or no obese parents compared to children with two obese parents. These results demonstrate the need to consider parental weight status when engaging in childhood weight management efforts. © 2015 World Obesity.

Child Temperament and Home-Based Parent Involvement at Kindergarten Entry: Evidence from a Low-Income, Urban Sample

Science.gov (United States)

Han, Jinjoo; O'Connor, Erin E.; McCormick, Meghan P.; McClowry, Sandee G.

2017-01-01

Research Findings: Home-based involvement--defined as the actions parents take to promote children's learning outside of school--is often the most efficient way for low-income parents to be involved with their children's education. However, there is limited research examining the factors predicting home-based involvement at kindergarten entry for…

School-Based BMI and Body Composition Screening and Parent Notification in California: Methods and Messages

Science.gov (United States)

Madsen, Kristine A.; Linchey, Jennifer

2012-01-01

Background: School-based body mass index (BMI) or body composition screening is increasing, but little is known about the process of parent notification. Since 2001, California has required annual screening of body composition via the FITNESSGRAM, with optional notification. This study sought to identify the prevalence of parental notification…

Feasibility and principal acceptability of school-based mobile communication applications to disseminate healthy lunchbox messages to parents.

Science.gov (United States)

Reynolds, Renee; Sutherland, Rachel; Nathan, Nicole; Janssen, Lisa; Lecathelinais, Christophe; Reilly, Kathryn; Walton, Alison; Wolfenden, Luke

2018-03-12

This study aimed to assess the feasibility and acceptability of using an existing school-based mobile communication application to deliver messages to parents on how to pack a healthy lunchbox. A telephone survey was conducted with 196 primary school principals within the Hunter New England region of New South Wales, Australia, in 2016. Almost two thirds of primary schools (59%) currently use a school-based mobile communication application to communicate with parents. Most principals (91%) agreed school lunchboxes need improving, of which 80% agree it is a school's role to provide information and guidelines to parents. However, only 50% of principals reported currently providing such information. The provision of lunchbox messages to parents by a third party appeared an acceptable model of delivery by principals. Larger schools and schools in urban and lower socio-economic localities were more likely to have used a school-based mobile communication application. The majority of principals recognise student lunchboxes need improving. The use of school-based mobile communication applications appears to be feasible and acceptable by principals as a method of communicating lunchbox messages to parents. SO WHAT?: Use of school-based mobile communication applications may be an effective method for delivering health information at a population level. Future research should assess the potential efficacy of disseminating health interventions via this modality. © 2018 Australian Health Promotion Association.

Parental neglect during childhood and increased risk of obesity in young adulthood

DEFF Research Database (Denmark)

Lissau, I; Sørensen, T I

1994-01-01

The association of various features of family life with obesity in childhood is well established, but less is known about the effect of these influences on the risk of later obesity. In this prospective, population-based study, we examined the influence of parental care in childhood on the risk o...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Voltammetric sensor for D-penicillamine determination based on its electrocatalytic oxidation at the surface of ferrocenes modified carbon paste electrodes · Jahan-Bakhsh Raoof Reza Ojani Fereshteh Chekin · More Details Abstract Fulltext PDF. Electrocatalytic oxidation of D-penicillamine (D-PA) at the surface of ferrocene ...

Effectiveness of web-based tailored advice on parents' child safety behaviors: randomized controlled trial.

Science.gov (United States)

van Beelen, Mirjam Elisabeth Johanna; Beirens, Tinneke Monique Jozef; den Hertog, Paul; van Beeck, Eduard Ferdinand; Raat, Hein

2014-01-24

Injuries at home are a major cause of death, disability, and loss of quality of life among young children. Despite current safety education, required safety behavior of parents is often lacking. To prevent various childhood disorders, the application of Web-based tools has increased the effectiveness of health promotion efforts. Therefore, an intervention with Web-based, tailored, safety advice combined with personal counseling (E-Health4Uth home safety) was developed and applied. To evaluate the effect of E-Health4Uth home safety on parents' safety behaviors with regard to the prevention of falls, poisoning, drowning, and burns. A randomized controlled trial was conducted (2009-2011) among parents visiting well-baby clinics in the Netherlands. Parents were randomly assigned to the intervention group (E-Health4Uth home safety intervention) or to the control condition consisting of usual care. Parents in the intervention condition completed a Web-based safety behavior assessment questionnaire; the resulting tailored safety advice was discussed with their child health care professional at a well-baby visit (age approximately 11 months). Parents in the control condition received counseling using generic safety information leaflets at this well-baby visit. Parents' child safety behaviors were derived from self-report questionnaires at baseline (age 7 months) and at follow-up (age 17 months). Each specific safety behavior was classified as safe/unsafe and a total risk score was calculated. Logistic and linear regression analyses were used to reveal differences in safety behavior between the intervention and the control condition at follow-up. A total of 1292 parents (response rate 44.79%) were analyzed. At follow-up, parents in the intervention condition (n=643) showed significantly less unsafe behavior compared to parents in the control condition (n=649): top of staircase (23.91% vs. 32.19%; OR 0.65, 95% CI 0.50-0.85); bottom of staircase (63.53% vs. 71.94%; OR 0

Bidirectional associations between activity-related parenting practices, and child physical activity, sedentary screen-based behavior and body mass index: a longitudinal analysis.

Science.gov (United States)

Sleddens, Ester F C; Gubbels, Jessica S; Kremers, Stef P J; van der Plas, Eline; Thijs, Carel

2017-07-06

It has been generally assumed that activity-related parenting practices influence children's activity behavior and weight status. However, vice versa parents may also change their parenting behaviors in response to their perceptions of their child's activity behavior and weight status. This study examined the bidirectional relationships between activity-related parenting practices, and physical activity, sedentary screen-based behavior, and body mass index (BMI) between children's age of 5 and 7 years. Three scales of the Activity-related Parenting Questionnaire (i.e. 'restriction of sedentary behavior', 'stimulation of physical activity', and 'monitoring of physical activity') were completed by 1694 parents of the Dutch KOALA Birth Cohort Study at the child's age of around 5 and again around age 7. Physical activity, sedentary screen-based behavior and BMI were measured at both ages as well. Linear regression models were used to estimate the bidirectional associations between each parenting practice and the child's physical activity levels, sedentary screen-based behavior and BMI z-scores. Several parenting practices at age 5 predicted child physical activity, sedentary screen-based behavior, and BMI z-scores at age 7. Restriction of sedentary behavior positively predicted child BMI and sedentary screen-based behavior, whereas this practice negatively predicted child physical activity. In addition, stimulation of physical activity at age 5 was significantly associated with higher levels of child physical activity at age 7. The following child factors at age 5 predicted parenting practices at age 7: Child physical activity positively predicted parental stimulation of physical activity and monitoring activities. Sedentary screen-based behavior was associated with lower parental stimulation to be active. Findings generally revealed that parents and children mutually influence each other's behavior. A reinforcing feedback loop was present between parental stimulation

Healthy Parent Carers programme: development and feasibility of a novel group-based health-promotion intervention

Directory of Open Access Journals (Sweden)

Aleksandra J. Borek

2018-02-01

Full Text Available Abstract Background Parent carers of disabled children report poor physical health and mental wellbeing. They experience high levels of stress and barriers to engagement in health-related behaviours and with ‘standard’ preventive programmes (e.g. weight loss programmes. Interventions promoting strategies to improve health and wellbeing of parent carers are needed, tailored to their specific needs and circumstances. Methods We developed a group-based health promotion intervention for parent carers by following six steps of the established Intervention Mapping approach. Parent carers co-created the intervention programme and were involved in all stages of the development and testing. We conducted a study of the intervention with a group of parent carers to examine the feasibility and acceptability. Standardised questionnaires were used to assess health and wellbeing pre and post-intervention and at 2 month follow up. Participants provided feedback after each session and took part in a focus group after the end of the programme. Results The group-based Healthy Parent Carers programme was developed to improve health and wellbeing through engagement with eight achievable behaviours (CLANGERS – Connect, Learn, be Active, take Notice, Give, Eat well, Relax, Sleep, and by promoting empowerment and resilience. The manualised intervention was delivered by two peer facilitators to a group of seven parent carers. Feedback from participants and facilitators was strongly positive. The study was not powered or designed to test effectiveness but changes in measures of participants’ wellbeing and depression were in a positive direction both at the end of the intervention and 2 months later which suggest that there may be a potential to achieve benefit. Conclusions The Healthy Parent Carers programme appears feasible and acceptable. It was valued by, and was perceived to have benefited participants. The results will underpin future refinement of the

Parents' decision-making regarding vaccinating their children against influenza: A web-based survey.

Science.gov (United States)

Flood, Emuella M; Rousculp, Matthew D; Ryan, Kellie J; Beusterien, Kathleen M; Divino, Victoria M; Toback, Seth L; Sasané, Medha; Block, Stan L; Hall, Matthew C; Mahadevia, Parthiv J

2010-08-01

Despite the recommendation from the Centers for Disease Control and Prevention that children between the ages of 6 months and 18 years be vaccinated against influenza annually, vaccination rates remain suboptimal. This study was conducted to explore factors that influence parents' decisions regarding influenza vaccination for children aged 2 to 12 years, to quantify the relative importance of these factors, to identify an appropriate theoretical model for illustrating the relationships among these factors, and to characterize parents by their likelihood of vaccinating their children against influenza. A quantitative Web-based survey was administered to a sample of parents from an online panel representative of the US population. Parents were stratified based on self-reported rates of their personal influenza vaccination (every year, sometimes, or never) and the age of their child (2-4 years or 5-12 years). The results were examined by parents' likelihood of vaccinating their child in the next year (high, medium, or low). Participants were asked to rank their agreement with statements representing various beliefs and perceptions about influenza and influenza vaccine on a scale from 1 = strongly agree to 5 = strongly disagree. Parents who indicated that they vaccinate their child every year were asked to select the drivers of their decision to vaccinate; parents who indicated that they never vaccinate their child were asked to select the barriers affecting their decision not to vaccinate; and parents who responded that they sometimes vaccinate their child were asked to select both the drivers and barriers affecting their decision. Participants were then asked to rank the importance of each driver or barrier on a scale from 1 = a little important to 5 = extremely important. Mean agreement ratings were calculated for parents' beliefs and perceptions about influenza and influenza vaccine and were compared across likelihood subgroups. Mean importance ratings of the

Parental Expectation from Children with Cochlear Implants in Indian Context: a Questionnaire Based Study.

Science.gov (United States)

Kumar, Prawin; Sanju, Himanshu Kumar; Mishra, Rajkishor; Singh, Varun; Mohan, Priyanka

2017-04-01

Introduction  Parental support is important in the habilitation/rehabilitation of children using cochlear implant devices. Hence, it is important for families to know the realistic expectations regarding outcomes from CIs. Objective  The objective of the present study is to know the parents' expectation from children using CIs. Methods  For this study, we recruited 23 parents of children using CIs. We administered 15 questions translated in to Hindi related to communication abilities, social skills, academic achievement, change in future life, rehabilitation demand, and stress due to hearing impairment. Results  The response of the questions (5-point rating scale) related to communication abilities showed that parents were expecting children using CIs to use the telephone (95%), to be able to detect soft sounds (99%), to listen in crowds (86%), to be able to easily understand others (76%), and to show improvement in communication skills (78%). Similarly, for questions related to social skills showed 90% of the parents expecting that their children with CIs should be able to easily make friends with normal hearing peers, and 80% of the parents were expecting the children to achieve high standards in their reading and writing skills. Questions related to change in future life showed 86% of the parents expecting their children with CIs to act like normal hearing children. Further, 78% parents showed positive response regarding importance of intensive training. However, 70% of the parents reported stress in the family due to the existence of the hearing impaired child. Conclusion  Overall, the existing questionnaire-based study showed that parents have high expectations from their children with cochlear implant.

Social Learning Theory Parenting Intervention Promotes Attachment-Based Caregiving in Young Children: Randomized Clinical Trial

Science.gov (United States)

O'Connor, Thomas G.; Matias, Carla; Futh, Annabel; Tantam, Grace; Scott, Stephen

2013-01-01

Parenting programs for school-aged children are typically based on behavioral principles as applied in social learning theory. It is not yet clear if the benefits of these interventions extend beyond aspects of the parent-child relationship quality conceptualized by social learning theory. The current study examined the extent to which a social…

Envolvimento parental na terapia cognitivo comportamental em crianças com perturbações de ansiedade : caracterização e seus determinantes

OpenAIRE

Santos, Inês Cabugueira Custódio dos

2013-01-01

Tese de mestrado, Psicologia (Secção de Psicologia Clínica e da Saúde - Núcleo de Psicologia da Saúde e da Doença), Universidade de Lisboa, Faculdade de Psicologia, 2013 Enquadramento: A Terapia Cognitivo Comportamental tem sido apontada como a mais eficaz na intervenção com crianças ansiosas. A forma como os pais são envolvidos no processo tem sido alvo de diversos estudos que procuram verificar as diferenças eficácia terapêutica, face aos diferentes tipos de envolvimento parental. O pres...

Effects of a Family-Based Childhood Obesity Treatment Program on Parental Weight Status.

Science.gov (United States)

Trier, Cæcilie; Dahl, Maria; Stjernholm, Theresa; Nielsen, Tenna R H; Bøjsøe, Christine; Fonvig, Cilius E; Pedersen, Oluf; Hansen, Torben; Holm, Jens-Christian

2016-01-01

The aim of this study was to investigate the prevalence of overweight/obesity among parents of children entering childhood obesity treatment and to evaluate changes in the parents' weight statuses during their child's treatment. The study included parents of 1,125 children and adolescents aged 3-22 years, who were enrolled in a multidisciplinary childhood obesity treatment program. At baseline, weight and height of the parents were obtained by self-reported information and parental body mass index (BMI) was calculated. Weight and height of the children were measured in the clinic and BMI standard deviation scores were calculated. Furthermore, anthropometric data from parents of 664 children were obtained by telephone interview after a mean of 2.5 years of treatment (ranging 16 days to 7 years), and changes in parental BMI were analyzed. Data on changes in BMI were available in 606 mothers and 479 fathers. At baseline, the median BMI of the mothers was 28.1 kg/m2 (range: 16.9-66.6), and the median BMI of the fathers was 28.9 kg/m2 (range: 17.2-48.1). Seventy percent of the mothers and 80% of the fathers were overweight or obese at the time of their child's treatment initiation. Both the mothers and fathers lost weight during their child's treatment with a mean decrease in BMI in the mothers of 0.5 (95% CI: 0.2-0.8, p = 0.0006) and in the fathers of 0.4 (95% CI: 0.2-0.6, p = 0.0007). Of the overweight/obese parents, 60% of the mothers and 58% of the fathers lost weight during their child's treatment. There is a high prevalence of overweight/obesity among parents of children entering childhood obesity treatment. Family-based childhood obesity treatment with a focus on the child has a positive effect on parental BMI with both mothers and fathers losing weight. ClinicalTrials.gov NCT00928473.

An analysis of the phenomenon of increased parental participation during the child's dental experience.

Science.gov (United States)

Pinkham, J R

1991-01-01

The role of the parent during their child's dental experience, in contemporary society, has changed during the past decade and should be addressed by pediatric dentists. Included in this matter are issues regarding risk management and practice management. Behavioral pediatric dentistry is in flux, much like the world that it serves; there appear to be schisms within the profession regarding one aspect of this: the presence of parents in the dental operatory. Presented here is an analysis of the paradigm-shifts in society since World War II, when a postfigurative parenting strategy was in vogue. An explication of noted anthropologist Margaret Mead's descriptions of this and two subsequent parenting styles, including configurative (or transitional) and prefigurative (contemporary) are presented. They are analyzed in terms of parental attitudes concerning trusting their child to authority figures, including the dental clinician. This emerging protective instinct is termed "social hypertrophy", based on social biologist Edward O. Wilson's work. Dentists are encouraged to understand parental attitudes and avoid unnecessary conflict.

New generation of electrochemical immunoassay based on polymeric nanoparticles for early detection of breast cancer

Directory of Open Access Journals (Sweden)

Mouffouk F

2017-04-01

Full Text Available Fouzi Mouffouk,1 Sihem Aouabdi,2 Entesar Al-Hetlani,1 Hacene Serrai,3 Tareq Alrefae,4 Liaohai Leo Chen5 1Department of Chemistry, Kuwait University, Safat, Kuwait; 2King Abdullah International Medical Research Center (KAIMRC, Jeddah, Kingdom of Saudi Arabia; 3Department of Radiology and Nuclear Medicine, University Hospital of Gent (UZG, Gent, Belgium; 4Department of Physics, Kuwait University, Safat, Kuwait; 5Surgical Precision Research Lab. Department of Surgery, University of Illinois at Chicago, IL, USA Abstract: Screening and early diagnosis are the key factors for the reduction of mortality rate and treatment cost of cancer. Therefore, sensitive and selective methods that can reveal the low abundance of cancer biomarkers in a biological sample are always desired. Here, we report the development of a novel electrochemical biosensor for early detection of breast cancer by using bioconjugated self-assembled pH-responsive polymeric micelles. The micelles were loaded with ferrocene molecules as “tracers” to specifically target cell surface-associated epithelial mucin (MUC1, a biomarker for breast and other solid carcinoma. The synthesis of target-specific, ferrocene-loaded polymeric micelles was confirmed, and the resulting sensor was capable of detecting the presence of MUC1 in a sample containing about 10 cells/mL. Such a high sensitivity was achieved by maximizing the loading capacity of ferrocene inside the polymeric micelles. Every single event of binding between the antibody and antigen was represented by the signal of hundreds of thousands of ferrocene molecules that were released from the polymeric micelles. This resulted in a significant increase in the intensity of the ferrocene signal detected by cyclic voltammetry. Keywords: electrochemical immunoassay, polymeric nanoparticles, breast cancer biomarkers, biosensors 

[Parent-child interaction therapy (PCIT)].

Science.gov (United States)

Briegel, Wolfgang

2016-11-01

Parent-child interaction therapy (PCIT), a manualized evidence-based intervention, was originally developed to treat disruptive behavior problems in children aged 2–6 years. It is also considered to be an evidence-based intervention for physical abuse among children. Moreover, PCIT has proved to be effective for attention deficit hyperactivity disorder, autism spectrum disorder, separation anxiety disorder, and depression. Thus, it could become the first evidence-based, transdiagnostic intervention method for 2–6-year-old children. PCIT is based on attachment theory as well as learning theory, combining aspects of play therapy and behavior therapy. It consists of two treatment phases: child-directed interaction (CDI) and parent-directed interaction (PDI). In both phases parents are taught special skills. When interacting with their child parents practice these skills and are live coached by the therapist. CDI aims at improving the parent-child relationship and is the basis for PDI. In CDI, parents learn to follow their child’s lead as long as the child shows appropriate behavior. In PDI, parents practice effectively taking the lead wherever necessary. On average, it takes about 15–20 sessions to complete PCIT, which can be terminated as soon as the parents demonstrate a mastery of the skills, when child disruptive behavior has been reduced to clearly normal levels, and when the parents have become confident in managing child behavior on their own.

Functional Assessment Based Parent Intervention in Reducing Children’s Challenging Behaviors: Exploratory Study of Group Training

OpenAIRE

Angel Fettig; Michaelene M. Ostrosky

2014-01-01

This study examined the effects of group parent training on children’s challenging behaviors in home settings. Eight parents of young children with challenging behaviors were trained in a large group setting on using functional assessment to design interventions that fit the strengths and needs of individual families. The training included information sharing and collaborating with parents on designing functional-assessment based interventions. An Interrupted Time Series Design was used to ex...

Relação da doença respiratória declarada pelos pais e fatores socioeconômicos e culturais Relationship between respiratory tract diseases declared by parents and socioeconomic and cultural factors

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Maria Aparecida F Aranha

2011-09-01

Full Text Available OBJETIVO: Verificar a relação entre a doença respiratória das crianças declarada pelos pais e os seguintes aspectos: instituição de ensino da criança, grau de instrução dos pais, renda per capita, classe de consumo e grupo étnico da família. MÉTODOS: Estudo descritivo com enfoque retrospectivo, por meio da análise de dados coletados de pais de uma amostra de 959 escolares entre cinco e nove anos, que residiam no distrito estudado, em São Paulo, em 2004. O levantamento das informações foi realizado por meio de instrumento de coleta de dados. As doenças respiratórias pesquisadas no conjunto foram: rinite, rinossinusite, otite, laringite, faringoamigdalite, pneumonia e asma. A associação entre doença respiratória declarada e aspectos socioeconômicos foi avaliada pelo teste do qui-quadrado. RESULTADOS: Os pais de crianças que frequentavam escolas privadas declararam significativamente mais doenças respiratórias em seus filhos, em comparação aos pais de crianças que estudavam em escolas públicas. Os pais com grau de instrução superior ou ensino médio completo declararam significativamente mais doença respiratória em seus filhos. Não houve associação entre a doença respiratória com renda per capita, classe de consumo e etnia. CONCLUSÕES: A percepção mais apurada sobre a saúde dos filhos geralmente associa-se à maior escolaridade dos pais, o que também determina melhores condições de vida. Provavelmente, por isso, os pais cujos filhos frequentavam escolas privadas e com melhor nível de escolaridade referiram mais doenças respiratórias nas crianças. Infere-se, portanto, que conquistas na percepção de saúde e, consequentemente, nas condições de saúde associam-se à melhora do nível educacional.OBJECTIVE: To determine the association between children's respiratory diseases reported by parents and the following criteria: attendance at private or public school, parents' educational level; family

Facebook advertisements recruit parents of children with cancer for an online survey of web-based research preferences.

Science.gov (United States)

Akard, Terrah Foster; Wray, Sarah; Gilmer, Mary Jo

2015-01-01

Studies involving samples of children with life-threatening illnesses and their families face significant challenges, including inadequate sample sizes and limited diversity. Social media recruitment and Web-based research methods may help address such challenges yet have not been explored in pediatric cancer populations. This study examined the feasibility of using Facebook advertisements to recruit parent caregivers of children and teenagers with cancer. We also explored the feasibility of Web-based video recording in pediatric palliative care populations by surveying parents of children with cancer regarding (a) their preferences for research methods and (b) technological capabilities of their computers and phones. Facebook's paid advertising program was used to recruit parent caregivers of children currently living with cancer to complete an electronic survey about research preferences and technological capabilities. The advertising campaign generated 3 897 981 impressions, which resulted in 1050 clicks at a total cost of $1129.88. Of 284 screened individuals, 106 were eligible. Forty-five caregivers of children with cancer completed the entire electronic survey. Parents preferred and had technological capabilities for Web-based and electronic research methods. Participant survey responses are reported. Facebook was a useful, cost-effective method to recruit a diverse sample of parent caregivers of children with cancer. Web-based video recording and data collection may be feasible and desirable in samples of children with cancer and their families. Web-based methods (eg, Facebook, Skype) may enhance communication and access between nurses and pediatric oncology patients and their families.

Emotional reasoning and parent-based reasoning in normal children.

OpenAIRE

Morren, M.; Muris, P.; Kindt, M.

2004-01-01

A previous study by Muris, Merckelbach, and Van Spauwen demonstrated that children display emotional reasoning irrepective of their anxiety levels. That is when estimating whether a situation is dangerous, childen not only rely on objective danger information but also on their own anciety-response. The present study further examined emotional reasoning in childeren aged 7-13 years (N=508). In addition, it was investigated whether children also show parent-based reasoning, which can be defined...

Parent-to-parent support for parents with children who are deaf or hard of hearing: a conceptual framework.

Science.gov (United States)

Henderson, Rebecca J; Johnson, Andrew; Moodie, Sheila

2014-12-01

Parent-to-parent support for parents with children who are deaf or hard of hearing (D/HH) is identified as an important component of Early Hearing Detection and Intervention (EHDI) programs for children with hearing loss. The specific aim of this review was to identify the constructs and components of parent-to-parent support for parents of children who are D/HH. An extensive scoping literature review identified 39 peer-reviewed articles published from 2000 to 2014. Studies were selected and reviewed based on standardized procedures. Data were identified, extracted, and organized into libraries of thematic and descriptive content. A conceptual framework of parent-to-parent support for parents of children who are D/HH was developed and presented in a comprehensive, bidirectional informational graphic. The constructs and components of the conceptual framework are (a) well-being: parent, family, and child; (b) knowledge: advocacy, system navigation, and education; and (c) empowerment: confidence and competence. The findings from this scoping review led to the development of a structured conceptual framework of parent-to-parent support for parents of children who are D/HH. The conceptual framework provides an important opportunity to explore and clearly define the vital contribution of parents in EHDI programs.

Democratic parenting: paradoxical messages in democratic parent education theories

Science.gov (United States)

Oryan, Shlomit; Gastil, John

2013-06-01

Some prominent parent education theories in the United States and other Western countries base their educational viewpoint explicitly on democratic values, such as mutual respect, equality and personal freedom. These democratic parenting theories advocate sharing power with children and including them in family decision making. This study presents a textual analysis of two such theories, the Adlerian model of parent education and the Parent Effectiveness Training (PET) model, as they are embodied in two original bestselling textbooks. Through content and argumentation analysis of these influential texts, this study examines the paradoxes inherent in these two theories when they articulate how to implement fully democratic principles within the parent-child relationship. We discover that in spite of their democratic rationale, both books offer communication practices that guide the child to modify misbehaviour, enforce parental power, and manipulate the child to make decisions that follow parental judgment, and thus do not endorse the use of a truly democratic parenting style. We suggest, as an alternative to the democratic parenting style, that parents be introduced to a guardianship management style, in which they do not share authority with children, but seek opportunities for enabling children to make more autonomous decisions and participate in more family decision making.

Defect formation and carrier doping in epitaxial films of the ''parent'' compound SrCuO2: Synthesis of two superconductors descendants

International Nuclear Information System (INIS)

Feenstra, R.; Norton, D.P.; Budai, J.D.; Jones, E.C.; Christen, D.K.; Kawai, T.

1995-04-01

The infinite layer or parent compounds ACuO 2 (A: Ca-Sr-Ba) constitute the simplest copper oxygen perovskites that contain the CuO 2 sheets essential for superconductivity. The stabilization of these basic ''building blocks'' as epitaxial films, therefore, provides alluring opportunities towards the search for new superconducting compounds and elucidation of the underlying mechanisms. In this work, general trends of the defect formation and carrier doping for epitaxial films of the intermediate endmember SrCuO 2 are reviewed. First results are presented from successful attempts to induce hole-doped superconductivity via the processing-controlled incorporation of charge reservoir layers

The Incredible Years Parent-Toddler Programme and parental language: a randomised controlled trial.

Science.gov (United States)

Gridley, N; Hutchings, J; Baker-Henningham, H

2015-01-01

Parental language is associated with children's later language development. Parenting programmes, based on social learning theory, enhance a range of parenting behaviours, yet there is limited evidence for their effect on parental language. To assess the benefits of a behavioural-based parenting programme, which features components of language and communication, to enhance parental language. Parents of toddlers, aged 12 to 36 months, were recruited from eight Flying Start early intervention centres across Wales. Participants were randomised 2:1 either to a parenting programme (n = 60) or to a wait-list control group (n = 29). Researchers were blind to participant allocation throughout the trial. Fifteen-minute video-recorded observations of parents and children interacting during free-play, both at a pre-intervention and at 6-month follow-up, provided the data for the study. Five observed measures of parental language were assessed; quantity and variety, encouraging, critical, child-led and parent led interactions. The Incredible Years Parent-Toddler Programme (IYPTP) is a 12-week group-based behavioural intervention that teaches effective relationship and behavioural management skills including social, emotional and persistence coaching to enable parents to better support their children's development. Of 89 dyads that completed pre-intervention assessments 81 (54 intervention and 27 control) met the criteria for the current study. Intention to treat analysis indicated that child-led language interactions significantly benefited from the intervention [regression coefficient (B) = -1.44, 95% confidence intervals (CI) = -2.59 to -0.29, P = 0.015, effect size (ES) = 0.47] and a positive trend for encouraging language in favour of the intervention sample was evident. Per-protocol sample analysis replicated these findings with encouraging language reaching statistical significance (B = 1.07, 95% CI = 0.11 to 2.03, P = 0.03, ES = 0.52). No further benefits were evident

Pediatric Primary Care-Based Obesity Prevention for Parents of Preschool Children: A Pilot Study.

Science.gov (United States)

Sherwood, Nancy E; JaKa, Meghan M; Crain, A Lauren; Martinson, Brian C; Hayes, Marcia G; Anderson, Julie D

2015-12-01

The Healthy Homes/Healthy Kids Preschool (HHHK-Preschool) pilot program is an obesity prevention intervention integrating pediatric care provider counseling and a phone-based program to prevent unhealthy weight gain among 2- to 4-year-old children at risk for obesity (BMI percentile between the 50th and 85th percentile and at least one overweight parent) or currently overweight (85th percentile ≤ BMI pediatric primary care clinics were randomized to: (1) the Busy Bodies/Better Bites Obesity Prevention Arm or the (2) Healthy Tots/Safe Spots safety/injury prevention Contact Control Arm. Baseline and 6-month data were collected, including measured height and weight, accelerometry, previous day dietary recalls, and parent surveys. Intervention process data (e.g., call completion) were also collected. High intervention completion and satisfaction rates were observed. Although a statistically significant time by treatment interaction was not observed for BMI percentile or BMI z-score, post-hoc examination of baseline weight status as a moderator of treatment outcome showed that the Busy Bodies/Better Bites obesity prevention intervention appeared to be effective among children who were in the overweight category at baseline relative to those who were categorized as at risk for obesity (p = 0.04). HHHK-Preschool pilot study results support the feasibility, acceptability, and potential efficacy in already overweight children of a pediatric primary care-based obesity prevention intervention integrating brief provider counseling and parent-targeted phone coaching. What's New: Implementing pediatric primary care-based obesity interventions is challenging. Previous interventions have primarily involved in-person sessions, a barrier to sustained parent involvement. HHHK-preschool pilot study results suggest that integrating brief provider counseling and parent-targeted phone coaching is a promising approach.

Evaluation of a U.S. Evidence-Based Parenting Intervention in Rural Western Kenya: From Parents Matter! to Families Matter!

Science.gov (United States)

Vandenhoudt, Hilde; Miller, Kim S.; Ochura, Juliet; Wyckoff, Sarah C.; Obong'o, Christopher O.; Otwoma, Nelson J.; Poulsen, Melissa N.; Menten, Joris; Marum, Elizabeth; Buve, Anne

2010-01-01

We evaluated Families Matter! Program (FMP), an intervention designed to improve parent-child communication about sexual risk reduction and parenting skills. Parents of 10- to 12-year-olds were recruited in western Kenya. We aimed to assess community acceptability and FMP's effect on parenting practices and effective parent-child communication.…

Impact of parental smoking on childhood asthma

Directory of Open Access Journals (Sweden)

Francisco-Javier Gonzalez-Barcala

2013-05-01

Full Text Available Objetive: To evaluate the exposure to environmental tobacco smoke (ETS of the childhood population in this community and its relationship with asthma symptoms. Methods: A cross-sectional study was conducted using the International Study of Asthma and Allergies in Childhood (ISAAC questionnaire on children and adolescents in this community. The symptoms “wheezing ever”, “current asthma”, “severe asthma”, and “exercise-induced asthma” were defined by this questionnaire. Parental smoking was classified into four mutually exclusive categories: 1 no parent smokes; 2 only the mother smokes; 3 only the father smokes; and 4 both parents smoke. The odds ratio of the prevalence of asthma symptoms according to ETS exposure was calculated using logistic regression. Results: A total of 10,314 children and 10,453 adolescents were included. Over 51% of the children and adolescents were exposed to ETS at home. ETS is associated with a higher prevalence of asthma symptoms, particularly if the mother or both parents smoke. Conclusion: The prevalence of ETS is still high in this community, although there has been a decreasing tendency in the last 15 years. ETS is associated with higher prevalence of asthma. Resumo: Objetivo: Avaliar a exposição da população infantil à FCA em nossa comunidade e sua relação com os sintomas de asma. Métodos: Foi realizado um estudo transversal usando o questionário de estudo ISAAC em crianças e adolescentes da nossa comunidade. Pelo questionário, fez-se a definição por “já ocorreu sibilância”, “asma atual”, “asma grave” e “asma induzida pelo exercício”. O tabagismo parental foi classificado em quatro categorias mutuamente excludentes: 1 nenhum dos pais fuma; 2 somente a mãe fuma; 3 somente o pai fuma; e 4 ambos os pais fumam. Calculou-se a odds ratio da prevalência de sintomas de asma, de acordo com a exposição à FCA, usando regressão logística. Resultados: Foram incluídas, no

Design, synthesis and structure of new potential electrochemically active boronic acid-based glucose sensors

DEFF Research Database (Denmark)

Norrild, Jens Chr.; Søtofte, Inger

2002-01-01

In the course of our investigations on new boronic acid based carbohydrate sensors three new boronic acids 3, 7 and 11 containing a ferrocene moiety were synthesised. Their design includes an intramolecular B-N bonding motif in order to facilitate binding at physiological pH. We report the synthe......In the course of our investigations on new boronic acid based carbohydrate sensors three new boronic acids 3, 7 and 11 containing a ferrocene moiety were synthesised. Their design includes an intramolecular B-N bonding motif in order to facilitate binding at physiological pH. We report...... the synthesis of the compounds and our investigations on glucose complexation as studied by C-13 NMR spectroscopy. The crystal structure of 2,4,6-tris[2-(N-ferrocenylmethyl-N-methylaminomethyl) phenyl] boroxin (13) (boroxin of boronic acid 3) (boroxin = cyclotriboroxane) was obtained and compared...... with structures obtained of 2,4,6-tris[2-(N,N-dimethylaminomethyl)phenyl]boroxin (14) and 2,2-dimethyl-1,3-diyl[2-(N,N-dimethylaminomethyl)phenyl]boronate (15). The structure of 13 shows the existence of intramolecular B-N bonds in the solid phase....

Does childhood cancer affect parental divorce rates? A population-based study.

Science.gov (United States)

Syse, Astri; Loge, Jon H; Lyngstad, Torkild H

2010-02-10

PURPOSE Cancer in children may profoundly affect parents' personal relationships in terms of psychological stress and an increased care burden. This could hypothetically elevate divorce rates. Few studies on divorce occurrence exist, so the effect of childhood cancers on parental divorce rates was explored. PATIENTS AND METHODS Data on the entire Norwegian married population, age 17 to 69 years, with children age 0 to 20 years in 1974 to 2001 (N = 977,928 couples) were retrieved from the Cancer Registry, the Central Population Register, the Directorate of Taxes, and population censuses. Divorce rates for 4,590 couples who were parenting a child with cancer were compared with those of otherwise similar couples by discrete-time hazard regression models. Results Cancer in a child was not associated with an increased risk of parental divorce overall. An increased divorce rate was observed with Wilms tumor (odds ratio [OR], 1.52) but not with any of the other common childhood cancers. The child's age at diagnosis, time elapsed from diagnosis, and death from cancer did not influence divorce rates significantly. Increased divorce rates were observed for couples in whom the mothers had an education greater than high school level (OR, 1.16); the risk was particularly high shortly after diagnosis, for CNS cancers and Wilms tumors, for couples with children 0 to 9 years of age at diagnosis, and after a child's death. CONCLUSION This large, registry-based study shows that cancer in children is not associated with an increased parental divorce rate, except with Wilms tumors. Couples in whom the wife is highly educated appear to face increased divorce rates after a child's cancer, and this may warrant additional study.

Momentary Parental Stress and Food-Related Parenting Practices.

Science.gov (United States)

Berge, Jerica M; Tate, Allan; Trofholz, Amanda; Fertig, Angela R; Miner, Michael; Crow, Scott; Neumark-Sztainer, Dianne

2017-12-01

Research suggests that stress and depressed mood are associated with food-related parenting practices (ie, parent feeding practices, types of food served at meals). However, current measures of parental stress, depressed mood, and food-related parenting practices are typically survey-based and assessed as static/unchanging characteristics, failing to account for fluctuations across time and context. Identifying momentary factors that influence parent food-related parenting practices will facilitate the development of effective interventions aimed at promoting healthy food-related parenting practices. In this study, we used ecological momentary assessment to examine the association between momentary factors (eg, stress, depressed mood) occurring early in the day and food-related parenting practices at the evening meal. Children aged 5 to 7 years and their families ( N = 150) from 6 racial and/or ethnic groups ( n = 25 each African American, Hispanic/Latino, Hmong, American Indian, Somali, and white families) were recruited for this mixed-methods study through primary care clinics. Higher stress and depressed mood earlier in the day predicted pressure-to-eat feeding practices and fewer homemade foods served at meals the same night. Effect modification was found for certain racial and/or ethnic groups with regard to engaging in pressure-to-eat feeding practices (ie, America Indian, Somali) or serving fewer homemade meals (ie, African American, Hispanic/Latino) in the face of high stress or depressed mood. Clinicians may want to consider discussing with parents the influence stress and depressed mood can have on everyday food-related parenting practices. Additionally, future researchers should consider using real-time interventions to reduce parental stress and depressed mood to promote healthy parent food-related parenting practices. Copyright © 2017 by the American Academy of Pediatrics.

Parents' asthma information needs and preferences for school-based asthma support.

Science.gov (United States)

Al Aloola, Noha Abdullah; Nissen, Lisa; Alewairdhi, Huda Abdullaziz; Al Faryan, Nawaf; Saini, Bandana

2017-11-01

This study sought to investigate parents' needs and preferences for school-based asthma support in Saudi Arabian primary schools. Semi-structured qualitative interviews were conducted in the period between November 2015 and February 2016, with a convenience sample that comprised Saudi parents and carers of children with asthma. Recruitment of participants was primarily driven through Saudi primary schools; passive snowballing and social networks were used to boost participation rates further. Interviews were audio-recorded, transcribed verbatim, translated and data were thematically organised using a latent content analysis approach. Twenty interviews were conducted. Six themes emerged from the interviews and were grouped into three major categories: (1) general asthma management issues; (2) school-based asthma management issues; and (3) communication dissatisfaction. Participants expressed concern at schools' social and physical environments and a lack of confidence in the ability of schools to manage their child's asthma, especially when their child was ill. Most of the participants advocated for staff training and school community engagement to improve the management of asthma in Saudi primary schools. This research clearly describes a need for school-based asthma support, including asthma-related policies, procedures and education on asthma and first aid in Saudi primary schools.

Examining within- and across-day relationships between transient and chronic stress and parent food-related parenting practices in a racially/ethnically diverse and immigrant population

OpenAIRE

Berge, Jerica M.; Tate, Allan; Trofholz, Amanda; Fertig, Angela; Crow, Scott; Neumark-Sztainer, Dianne; Miner, Michael

2018-01-01

Background Although prior research suggests that stress may play a role in parent’s use of food-related parenting practices, it is unclear whether certain types of stress (e.g., transient, chronic) result in different food-related parenting practices. Identifying whether and how transient (i.e., momentary; parent/child conflict) and chronic (i.e., long-term; unemployment >6 months) sources of stress are related to parent food-related parenting practices is important with regard to childhood o...

Nonohmic behavior of SnO2.MnO2-based ceramics

Directory of Open Access Journals (Sweden)

Marcelo O. Orlandi

2003-06-01

Full Text Available The present paper describes the nonohmic behavior of the SnO2.MnO-based system and analyzes the influence of the sintering time and the Nb2O5 concentration on this system's electrical properties. A nonlinear coefficient of ~7 was obtained for a 0.2 mol%-doped Nb2O5 composition, which is comparable to other values reported in the literature for the ternary SnO2-based systems. A recent barrier formation model proposed in the literature to explain the nonlinear electrical behavior of SnO2-based systems is used to clarify the role of the MnO constituent in the formation of the barrier, taking into account the influence of segregated atoms, precipitated phase and oxygen species in the grain boundary region.

Parental history of psychiatric diagnoses and unipolar depression: a Danish National Register-based cohort study.

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Musliner, K L; Trabjerg, B B; Waltoft, B L; Laursen, T M; Mortensen, P B; Zandi, P P; Munk-Olsen, T

2015-10-01

Depression is known to run in families, but the effects of parental history of other psychiatric diagnoses on depression rates are less well studied. Few studies have examined the impact of parental psychopathology on depression rates in older age groups. We established a population-based cohort including all individuals born in Denmark after 1954 and alive on their 10th birthday (N = 29 76 264). Exposure variables were maternal and paternal history of schizophrenia, bipolar disorder, depression, anxiety or 'other' psychiatric diagnoses. Incidence rate ratios (IRRs) were estimated using Poisson regressions. Parental history of any psychiatric diagnosis increased incidence rates of outpatient (maternal: IRR 1.88, p history. IRRs for parental history of non-affective disorders remained relatively stable across age groups, while IRRs for parental affective disorders (unipolar or bipolar) decreased with age from 2.29-3.96 in the youngest age group to 1.53-1.90 in the oldest group. IRR estimates for all parental diagnoses were similar among individuals aged ⩾41 years (IRR range 1.51-1.90). Parental history of any psychiatric diagnosis is associated with increased incidence rates of unipolar depression. In younger age groups, parental history of affective diagnoses is more strongly associated with rates of unipolar depression than non-affective diagnoses; however, this distinction disappears after age 40, suggesting that parental psychopathology in general, rather than any one disorder, confers risk for depression in middle life.

Parent-based interventions for preventing or reducing adolescent substance use - A systematic literature review.

Science.gov (United States)

Kuntsche, Sandra; Kuntsche, Emmanuel

2016-04-01

Despite the increasing relevance of peers, parents remain important socializing agents for their adolescent children and are therefore promising agents for inclusion in prevention or intervention programs. This systematic review provides an overview of the effectiveness of parent-based programs in preventing, curbing or reducing substance use (i.e. alcohol, tobacco and cannabis) among 10 to 18-year-olds. The databases PubMed, PsychInfo, Eric and Google Scholar were used to identify randomized trials published within the past 12years evaluating effects on adolescent substance use. Of the 653 identified in the first screening, 39 publications dealing with 13 programs were included. Results reveal desirable effects of parenting measures such as rule-setting, monitoring and parent-child communication. There was also some evidence in terms of preventing, curbing or reducing adolescent substance use. However, this appears to depend particularly on the age group of the adolescents in question, the kind of parents included and the intensity of the program. To conclude, the results of this systematic review underline the importance of including parents in programs aiming to impede initiation of substance use or curb or reduce already existing substance use in adolescence. Copyright © 2016 Elsevier Ltd. All rights reserved.

Comparison of pediatric self reports and parent proxy reports utilizing PROMIS: Results from a chiropractic practice-based research network.

Science.gov (United States)

Alcantara, Joel; Ohm, Jeanne; Alcantara, Junjoe

2017-11-01

To measure the cross-informant variant of pediatric quality of life (QoL) based on self-reports and parent proxy measures. A secondary analysis of baseline data obtained from two independent studies measuring the QoL based on the pediatric PROMIS-25 self-report and the PROMIS parent-proxy items banks. A scoring manual associated raw scores to a T score metric (mean = 50; SD = 10). Reliability of QoL ratings utilized the ICC while comparison of mean T Scores utilized the unpaired t-test. A total of 289 parent-child dyads comprised our study responders. Average age for parents and children was 41.27 years and 12.52 years, respectively. The mean T score (child self-report: parent proxy) for each QoL domains were: mobility (50.82:52.58), anxiety (46.73:44.21), depression (45.18:43.60), fatigue (45.59:43.92), peer-relationships (52.15:52.88) and pain interference (47.47:44.80). Parents tend to over-estimate their child's QoL based on measures of anxiety, depression, fatigue, peer-relationships and pain interference. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Influence of Self-Esteem, Parenting Style and Parental Monitoring ...

African Journals Online (AJOL)

Based on this, this study was set out to investigate the influence of self esteem, parental monitoring and parenting styles on adolescents' risky sexual behavior in Ibadan. Cross-sectional research design was used. A total number of 194 adolescents selected from three secondary schools participated in the study.

Facebook Ads Recruit Parents of Children with Cancer for an Online Survey of Web-Based Research Preferences

Science.gov (United States)

Akard, Terrah Foster; Wray, Sarah; Gilmer, Mary

2014-01-01

Background Studies involving samples of children with life-threatening illnesses and their families face significant challenges, including inadequate sample sizes and limited diversity. Social media recruitment and web-based research methods may help address such challenges yet have not been explored in pediatric cancer populations. Objective This study examined the feasibility of using Facebook ads to recruit parent caregivers of children and teens with cancer. We also explored the feasibility of web-based video recording in pediatric palliative care populations by surveying parents of children with cancer regarding (a) their preferences for research methods and (b) technological capabilities of their computers and phones. Methods Facebook's paid advertising program was used to recruit parent caregivers of children currently living with cancer to complete an electronic survey about research preferences and technological capabilities. Results The advertising campaign generated 3,897,981 impressions which resulted in 1050 clicks at a total cost of $1129.88. Of 284 screened individuals, 106 were eligible. Forty-five caregivers of children with cancer completed the entire electronic survey. Parents preferred and had technological capabilities for web-based and electronic research methods. Participant survey responses are reported. Conclusion Facebook was a useful, cost-effective method to recruit a diverse sample of parent caregivers of children with cancer. Web-based video recording and data collection may be feasible and desirable in samples of children with cancer and their families. Implications for Practice Web-based methods (e.g., Facebook, Skype) may enhance communication and access between nurses and pediatric oncology patients and their families. PMID:24945264

Avaliação e intervenção da disortografia baseada na semiologia dos erros: revisão da literatura Evaluation and intervention of dysortographia based on error semiology: literature review

Directory of Open Access Journals (Sweden)

Amparo Ygual Fernández

2010-06-01

Full Text Available TEMA: avaliação e intervenção na disortografia. OBJETIVO: descrever e discutir os achados encontrados na literatura sobre a disortografia segundo a sua definição, etiologia, classificação da semiologia dos erros, quadro clínico, avaliação e intervenção. CONCLUSÃO: a avaliação e a intervenção fonoaudiológica com a disortografia devem estar baseadas na classificação semiológica dos erros, pois desta forma, pode-se compreender cada tipo de erro e os fatores cognitivos ou linguísticos implicados. Isso se associa às orientações aos pais e professores de como enfocar o trabalho com a ortografia, seja em casa ou na escola sem gerar angústia e ansiedade na criança.BACKGROUND: evaluation and intervention in dysortographia. PURPOSE: to describe and discuss findings from researches concerning dysortographia according to its definition, etiology, errors semiology classification, clinical findings, evaluation, and intervention. CONCLUSION: speech language evaluation and intervention should be based on error semiology classification because in this way it is possible to understand each type of error and the linguistic and cognitive factors related to them. This is associated with the orientations to parents and teachers on how to work with orthography at home or at the classroom without causing distress and anxiety to the children.

The Examination of Views of Parents about the Web-Based Performance Evaluation Program in the Science Teaching Process

OpenAIRE

Bakırcı, Hasan; KARA, YILMAZ; ÇEPNİ, Salih

2018-01-01

The research was aimed to reveal the views of parents on web-based performance evaluation program. The case study method adopted for this study. The research was conducted in the central district of Trabzon province during the fall semester of 2012-2013 academic years. A questionnaire was administered to three hundred parents and face-to-face interviews were conducted with 10 of those parents. The obtained data was analyzed through descriptive and content analysis. Majority of the parents wer...

Sleep of Parents Living With a Child Receiving Hospital-Based Home Care: A Phenomenographical Study.

Science.gov (United States)

Angelhoff, Charlotte; Edéll-Gustafsson, Ulla; Mörelius, Evalotte

2015-01-01

Caring for an ill child at home gives the family the chance to be together in a familiar environment. However, this involves several nocturnal sleep disturbances, such as frequent awakenings and bad sleep quality, which may affect parents' ability to take care of the child and themselves. The aim of this study was to describe parents' perceptions of circumstances influencing their own sleep when living with a child enrolled in hospital-based home care (HBHC) services. This is a phenomenographical study with an inductive, exploratory design. Fifteen parents (11 mothers and 4 fathers) with children enrolled in HBHC services were interviewed. Data were analyzed to discover content-related categories describing differences in ways parents experienced sleep when caring for their children receiving HBHC. Four descriptive categories were detected: sleep influences mood and mood influences sleep; support influences safeness and safeness influences sleep; the child's needs influence routines and routines influence sleep; and "me time" influences sleep. Sleep does not affect only the parents' well-being but also the child's care. Symptoms of stress may limit the parents' capacity to meet the child's needs. Support, me time, and physical activity were perceived as essential sources for recovery and sleep. It is important for nurses to acknowledge parental sleep in the child's nursing care plan and help the parents perform self-care to promote sleep and maintain life, health, and well-being.

Individual and group based parenting programmes for improving psychosocial outcomes for teenage parents and their children

Science.gov (United States)

Barlow, Jane; Smailagic, Nadja; Bennett, Cathy; Huband, Nick; Jones, Hannah; Coren, Esther

2014-01-01

Background Parenting programmes are a potentially important means of supporting teenage parents and improving outcomes for their children, and parenting support is a priority across most Western countries. This review updates the previous version published in 2001. Objectives To examine the effectiveness of parenting programmes in improving psychosocial outcomes for teenage parents and developmental outcomes in their children. Search methods We searched to find new studies for this updated review in January 2008 and May 2010 in CENTRAL, MEDLINE, EMBASE, ASSIA, CINAHL, DARE, ERIC, PsycINFO, Sociological Abstracts and Social Science Citation Index. The National Research Register (NRR) was last searched in May 2005 and UK Clinical Research Network Portfolio Database in May 2010. Selection criteria Randomised controlled trials assessing short-term parenting interventions aimed specifically at teenage parents and a control group (no-treatment, waiting list or treatment-as-usual). Data collection and analysis We assessed the risk of bias in each study. We standardised the treatment effect for each outcome in each study by dividing the mean difference in post-intervention scores between the intervention and control groups by the pooled standard deviation. Main results We included eight studies with 513 participants, providing a total of 47 comparisons of outcome between intervention and control conditions. Nineteen comparisons were statistically significant, all favouring the intervention group. We conducted nine meta-analyses using data from four studies in total (each meta-analysis included data from two studies). Four meta-analyses showed statistically significant findings favouring the intervention group for the following outcomes: parent responsiveness to the child post-intervention (SMD −0.91, 95% CI −1.52 to −0.30, P = 0.04); infant responsiveness to mother at follow-up (SMD −0.65, 95% CI −1.25 to −0.06, P = 0.03); and an overall measure of parent

Parent Characteristics, Economic Stress and Neighborhood Context as Predictors of Parent Involvement in Preschool Children's Education

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Waanders, Christine; Mendez, Julia L.; Downer, Jason T.

2007-01-01

This study examines factors related to three dimensions of parent involvement in preschool: school-based involvement, home-based involvement, and the parent-teacher relationship. Participants were 154 predominantly African American parents recruited from two Head Start programs. Results of bivariate and canonical correlation analyses support the…

Reducing Children's Susceptibility to Alcohol Use: Effects of a Home-Based Parenting Program.

Science.gov (United States)

Jackson, Christine; Ennett, Susan T; Reyes, H Luz McNaughton; Hayes, Kim A; Dickinson, Denise M; Choi, Seulki; Bowling, J Michael

2016-07-01

This 4-year efficacy trial tested whether a home-based, self-administered parenting program could have a long-term effect on children's cognitive susceptibility to alcohol use, and it tested hypothesized moderators and mediators of any such program effect. Using a two-group randomized controlled design, 1076 children (540 treatment; 536 control; mean age of 9.2 years at baseline) completed telephone interviews prior to randomization and follow-up interviews 12, 24, 36, and 48 months post-baseline. Mothers of children randomized to treatment received a 5-month-long parenting program during year 1, followed by two 1-month-long boosters in years 2 and 3. Exposure to the program was significantly inversely associated with susceptibility to alcohol use 48 months post-baseline (b = -0.03, p = .04), with no variation in program effects by parental alcohol use or mother's race/ethnicity or education, suggesting broad public health relevance of the parenting program. Path analyses of simple indirect effects through each hypothesized mediator showed that program exposure positively influenced parental communication to counter pro-drinking influences in the family and media domains and parental rule setting 36 months post-baseline; these variables, in turn, predicted reduced susceptibility to alcohol use 48 months post-baseline. Parallel (multiple) mediation analysis showed that the program had a significant indirect effect on susceptibility through parental rule setting. Together, the findings indicate that internalization of protective alcohol-related expectancies and intentions is possible among children whose mothers provide early exposure to alcohol-specific socialization. Additional research is needed to link alcohol-specific socialization during childhood with adolescent drinking outcomes.

Stability of memories of parental rearing among psychiatric inpatients: a replication based on EMBU subscales.

Science.gov (United States)

Richter, J; Eisemann, M

2001-01-01

With regard to information about parental rearing, retrospective data are exclusively available among adults. These data are vulnerable due to various biases. This study was performed in order to replicate the findings of overall stability of three perceived parental rearing factors of the EMBU (Swedish acronym for 'own memories of childhood upbringing') based on 14 rather detailed subscales. A consecutive sample of 220 depressive inpatients were investigated on admission and at discharge by means of the EMBU, the Beck Depression Inventory and the Dysfunctional Attitude Scale. Perceived parental rearing scores showed high stability despite clinically significant changes in the severity of depression, except for 'tolerance', 'guilt engendering', 'performance orientation' and 'shaming' parenting with probable gender-specific effects which were found to covary with dysfunctional attitudes. Recall of parenting should be taken as a subjective truth when it is assessed by standardised behaviour-oriented questionnaires like the EMBU. Copyright 2002 S. Karger AG, Basel

A web-based communication system for integrated care in cerebral palsy: experienced contribution to parent-professional communication

NARCIS (Netherlands)

Gulmans, Jitske; Vollenbroek-Hutten, Miriam Marie Rosé; van Gemert-Pijnen, Julia E.W.C.; van Harten, Wim H.; van Harten, Willem H.

2012-01-01

Introduction: to improve communication in the integrated care setting of children with cerebral palsy, we developed a web-based system for parent-professional and inter-professional communication. The present study aimed to evaluate parents' experiences regarding the system's contribution to their

Effects of Coaching on the Implementation of Functional Assessment-Based Parent Intervention in Reducing Challenging Behaviors

Science.gov (United States)

Fettig, Angel; Schultz, Tia R.; Sreckovic, Melissa A.

2015-01-01

This study examined the effects of coaching on the implementation of functional assessment--based parent intervention in reducing children's challenging behaviors. A multiple baseline across participants design was used with three parent-child dyads with children between the ages of 2 and 5 years. The intervention consisted of training and delayed…

Reducing youth internalizing symptoms: Effects of a family-based preventive intervention on parental guilt induction and youth cognitive style

Science.gov (United States)

McKEE, LAURA G.; PARENT, JUSTIN; FOREHAND, REX; RAKOW, AARON; WATSON, KELLY H.; DUNBAR, JENNIFER P.; REISING, MICHELLE M.; HARDCASTLE, EMILY; COMPAS, BRUCE E.

2014-01-01

This study utilized structural equation modeling to examine the associations among parental guilt induction (a form of psychological control), youth cognitive style, and youth internalizing symptoms, with parents and youth participating in a randomized controlled trial of a family-based group cognitive–behavioral preventive intervention targeting families with a history of caregiver depression. The authors present separate models utilizing parent report and youth report of internalizing symptoms. Findings suggest that families in the active condition (family-based group cognitive–behavioral group) relative to the comparison condition showed a significant decline in parent use of guilt induction at the conclusion of the intervention (6 months postbaseline). Furthermore, reductions in parental guilt induction at 6 months were associated with significantly lower levels of youth negative cognitive style at 12 months. Finally, reductions in parental use of guilt induction were associated with lower youth internalizing symptoms 1 year following the conclusion of the intervention (18 months postbaseline). PMID:24438999

A randomized, controlled trial to test the efficacy of an online, parent-based intervention for reducing the risks associated with college-student alcohol use

Science.gov (United States)

Donovan, Elizabeth; Wood, Mollie; Frayjo, Kezia; Black, Ryan A.; Surette, Daniel A.

2011-01-01

Alcohol consumption among college students remains a major public health concern. Universal, Web-based interventions to reduce risks associated with student alcohol consumption have been found to be effective in changing their alcohol-related behavior. Recent studies also indicate that parent-based interventions, delivered in booklet form, are effective. A parent-based intervention that is also Web-based may be well suited to a dispersed parent population; however, no such tool is currently available. The purpose of this study was to test the efficacy of an online parent-based intervention designed to (1) increase communication between parents and students about alcohol and (2) reduce risks associated with alcohol use to students. A total of 558 participants, comprising 279 parent-teen dyads, were enrolled in the study. The findings suggested that parents who participated in the online intervention were more likely to discuss protective behavioral strategies, particularly those related to manner of drinking and stopping/limiting drinking, with their teens, as compared with parents in an e-newsletter control group. Moreover, students whose parents received the intervention were more likely to use a range of protective behavioral strategies, particularly those related to manner of drinking and stopping/limiting drinking, as compared with students whose parents did not receive the intervention. A universal, online, parent-based intervention to reduce risks associated with student alcohol consumption may be an efficient and effective component of a college’s overall prevention strategy. PMID:21963316

The role of parental personality traits in differential parenting.

Science.gov (United States)

Browne, Dillon T; Meunier, Jean Christophe; O'Connor, Thomas G; Jenkins, Jennifer M

2012-08-01

Significant relationships have been demonstrated between parental personality and parenting toward individual children, but there is little research exploring the relationship between parental personality and differential parenting (DP). The present study examined the relationship between the Big Five personality dimensions and differential positivity and negativity in parenting (observed and self-report measures). The analyses are based on a sample of 867 children nested within 381 families. Using multilevel modeling and controlling for child age, gender, birth order, behavior, and family socioeconomic status analyses revealed that maternal and paternal agreeableness were inversely related to reports of differential positivity. Agreeableness predicted observed differential negativity, and the relationship was curvilinear (at both high and low levels of agreeableness, differential negativity was higher). Finally, mothers with the most openness to experience exhibited the highest levels of reported differential negativity. The findings suggest that parental personality is a modest yet important influence to consider when conceptualizing the sources of DP. PsycINFO Database Record (c) 2012 APA, all rights reserved.

New structural and electrical data on Bi-Mo mixed oxides with a structure based on [Bi12O14]∞ columns

International Nuclear Information System (INIS)

Vannier, R.N.; Abraham, F.; Nowogrocki, G.; Mairesse, G.

1999-01-01

The authors recently described a new family of oxide anion conductors with a structure based on [Bi 12 O 14 ] ∞ columns (Journal of Solid State Chemistry 122, 394 (1996)). The parent compound of this series can be formulated as Bi 26 Mo 10 O 69 and formation of a solid solution, in the Bi 2 O 3 -MoO 3 binary system, in the range 2.57 ≤ Bi/Mo ≤ 2.77 was established. The stoichiometry of this series was questioned by R. Enjalbert et al. (Journal of Solid State Chemistry 131, 236 (1997)), but confirmed by D.J. Buttrey et al. (Materials Research Bulletin 32, 947 (1997)). The first part of this paper is devoted to a refutation of criticisms by R. Enjalbert et al. In the second part, a comparison with other Bi 2 O 3 -based oxide anion conductors enables the authors to propose an iono-covalent description of this novel structure type, taking into account all the structural and electrical features, especially new neutron powder diffraction refinement and conductivity measurements under variable oxygen partial pressures

A study of the Fe-based superconductor SmFeAsO{sub 1-x}F{sub x} by x-ray photoelectron spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Zhang, Y; Chen, Y L; Cui, Y J; Cheng, C H; Zhao, Y [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhang, H [Department of Physics, Peking University, Beijing 100871 (China)], E-mail: yzhao@swjtu.edu.cn

2009-01-15

The electronic structure of the Fe-based superconductor SmFeAsO{sub 1-x}F{sub x} (x = 0 and 0.2) is studied with x-ray photoemission spectroscopy (XPS) through comparing the band structures of the nonsuperconducting parent material SmFeAsO and the superconducting SmFeAsO{sub 0.8}F{sub 0.2} (T{sub c} = 52.5 K). A small peak centered at 0.2 eV below the Fermi level, E{sub F}, in the valence band is observed in the parent material SmFeAsO, which is due to the low-spin state of the Fe 3d electrons. With fluorine doping, the peak at 0.2 eV disappears and a broad plateau forms near the Fermi level; in the meantime, the density of states at E{sub F} is slightly suppressed. The O 1s and Sm 3d core levels shift towards high energy by {approx}0.55 eV with fluorine doping, but in a sharp comparison, the Fe 2p and As 3d core levels do not shift significantly (the binding energy shift is less than 0.01 eV). It is deduced from the core-level shifts that the Fermi level of the system moves up by 0.55 eV by fluorine doping.

Population-based geographic access to parent and satellite National Cancer Institute Cancer Center Facilities.

Science.gov (United States)

Onega, Tracy; Alford-Teaster, Jennifer; Wang, Fahui

2017-09-01

Satellite facilities of National Cancer Institute (NCI) cancer centers have expanded their regional footprints. This study characterized geographic access to parent and satellite NCI cancer center facilities nationally overall and by sociodemographics. Parent and satellite NCI cancer center facilities, which were geocoded in ArcGIS, were ascertained. Travel times from every census tract in the continental United States and Hawaii to the nearest parent and satellite facilities were calculated. Census-based population attributes were used to characterize measures of geographic access for sociodemographic groups. From the 62 NCI cancer centers providing clinical care in 2014, 76 unique parent locations and 211 satellite locations were mapped. The overall proportion of the population within 60 minutes of a facility was 22% for parent facilities and 32.7% for satellite facilities. When satellites were included for potential access, the proportion of some racial groups for which a satellite was the closest NCI cancer center facility increased notably (Native Americans, 22.6% with parent facilities and 39.7% with satellite facilities; whites, 34.8% with parent facilities and 50.3% with satellite facilities; and Asians, 40.0% with parent facilities and 54.0% with satellite facilities), with less marked increases for Hispanic and black populations. Rural populations of all categories had dramatically low proportions living within 60 minutes of an NCI cancer center facility of any type (1.0%-6.6%). Approximately 14% of the population (n = 43,033,310) lived more than 180 minutes from a parent or satellite facility, and most of these individuals were Native Americans and/or rural residents (37% of Native Americans and 41.7% of isolated rural residents). Racial/ethnic and rural populations showed markedly improved geographic access to NCI cancer center care when satellite facilities were included. Cancer 2017;123:3305-11. © 2017 American Cancer Society. © 2017 American

Individual and group-based parenting programmes for the treatment of physical child abuse and neglect.

Science.gov (United States)

Barlow, J; Johnston, I; Kendrick, D; Polnay, L; Stewart-Brown, S

2006-07-19

Child physical abuse and neglect are important public health problems and recent estimates of their prevalence suggest that they are considerably more common than had hitherto been realised. Many of the risk factors for child abuse and neglect are not amenable to change in the short term. Intervening to change parenting practices may, however, be important in its treatment. Parenting programmes are focused, short-term interventions aimed at improving parenting practices in addition to other outcomes (many of which are risk factors for child abuse e.g. parental psychopathology, and parenting attitudes and practices), and may therefore be useful in the treatment of physically abusive or neglectful parents. To assess the efficacy of group-based or one-to-one parenting programmes in addressing child physical abuse or neglect. A range of biomedical and social science databases were searched including MEDLINE, EMBASE, CINAHL, PsychINFO, Sociofile, Social Science Citation Index, ASSIA, the Cochrane Library, Campbell Library (including SPECTR and CENTRAL), National Research Register (NRR) and ERIC, from inception to May 2005. Only randomised controlled trials or randomised studies that compared two treatments were included. Studies had to include at least one standardised instrument measuring some aspect of abusive or neglectful parenting. In the absence of studies using objective assessments of child abuse, studies reporting proxy measures of abusive parenting were included. Only studies evaluating the effectiveness of standardised group-based or one-to-one parenting programmes aimed at the treatment of physical child abuse or neglect were included. Studies were also only eligible for inclusion if they had targeted parents of children aged 0-19 years who had been investigated for physical abuse or neglect. The treatment effect for each outcome in each study was standardised by dividing the mean difference in post-intervention scores for the intervention and treatment

Crystal Structure of the Sodium Cobaltate Deuterate Superconductor NaxCoO2o4xD2O (x=1/3)

OpenAIRE

Jorgensen, J. D.; Avdeev, M.; Hinks, D. G.; Burley, J. C.; Short, S.

2003-01-01

Neutron and x-ray powder diffraction have been used to investigate the crystal structures of a sample of the newly-discovered superconducting sodium cobaltate deuterate compound with composition Na0.31(3)CoO2o1.25(2)D2O and its anhydrous parent compound Na0.61(1)CoO2. The deuterate superconducting compound is formed by coordinating four D2O molecules (two above and two below) to each Na ion in a way that gives Na-O distances nearly equal to those in the parent compound. One deuteron of the D2...

Parent Perceptions of School-Based Occupational Therapy Services

Science.gov (United States)

Benson, Jeryl D.; Elkin, Kathleen; Wechsler, Julie; Byrd, Lindsey

2015-01-01

This study aims to explore the perceptions of parents of children receiving occupational therapy in educational settings, understand the importance of the parent/occupational therapist relationship and its impact on the outcomes of therapy. In addition, this study aims to reveal best practices when providing services within the school system in…

Parentalidade Positiva e Enfermagem: Revisão Sistemática da literatura Parentalidad Positiva y Enfermería: Revisión Sistemática de la literatura Positive Parenting and Nursing: Systematic literature Review

Directory of Open Access Journals (Sweden)

M. Saudade O. Custódio Lopes

2010-07-01

paternidad positiva de niños sanos de los cero a los tres años de edad. Las variables en estudio y el contenido de los programas tradujeron centros de interés en los siguientes temas: capacidad de los padres; comportamiento, desarrollo y estimulación del niño; interacción positiva entre padres y niño; seguridad y salud del niño; disciplina positiva; y construcción de capital social. En las estrategias de intervención, el trabajo individual con los padres / familia y el trabajo en grupo mostraron ganancias y pérdidas en la capacidad de los padres y en la construcción de capital social. La necesidad de una respuesta a estos centros de interés y las ganancias resultantes de las intervenciones demostraron ser oportuno que las enfermeras mejoren la atención al niño y a la familia.Support for positive parenting is critical in the first three years of life and requires a positive approach based on the potential of involving parents and family, implying demands and challenges for nurses. This literature review aims to identify the issues and strategies for nursing intervention to support positive parenting for children under three years old. Literature from 2000 to 2010 in EBSCOhost and ISI Web of Knowledge databases was searched to locate studies that included aspects of positive parenting and nursing interventions with healthy children under the age of three years. Nine papers met the inclusion criteria. The variables and programmes focused on the following themes: parents’ empowerment, children’s behavior, development and stimulation, positive parent-child interaction, children’s health and safety, positive discipline, and building social capital. Intervention strategies in individual work with parents and discussion groups showed improvements in empowering parents and building social capital. The need to respond to these issues and the gains resulting from interventions highlight the opportunity for nurses to improve care for the child and family.

Examining a conceptual model of parental nurturance, parenting practices and physical activity among 5-6 year olds.