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Sample records for paramagnitnykh bis-izodibutilditiofosfinatnykh kompleksov

  1. On kinetics of paramagnetic radiation defects accumulation in beryllium ceramics; O kinetike nakopleniya paramagnitnykh radiatsionnykh defektov v berillievykh keramikakh

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    Polyakov, A I; Ryabikin, Yu A; Zashkvara, O V; Bitenbaev, M I; Petykhov, Yu V [Fiziko-Tekhnicheskij Inst., Almaty (Kazakhstan); Inst. Atomnoj Ehnergii, Kurchatov (Kazakhstan)

    1999-07-01

    Results of paramagnetic radiation defects concentration dependence study in beryllium ceramics from gamma-irradiation dose ({sup 60}Co) within interval 0-100 Mrem are cited. Obtained dose dependence has form of accumulation curve with saturation typical of for majority of solids (crystals, different polymers, organic substances and others) , in which under irradiation occur not only formation of paramagnetic radiation defects, but its destruction due to recombination and interaction with radiation fields. Analysis of accumulation curve by the method of distant asymptotics allows to determine that observed in gamma-irradiated beryllium ceramics double line of electron spin resonance is forming of two types of paramagnetic radiation defects. It was defined, that sum paramagnetic characteristics of beryllium ceramics within 1-100 Mrad gamma- irradiation dose field change insignificantly and define from first type of paramagnetic radiation defects.

  2. About kinetics of paramagnetic radiation malformations in beryllium ceramics; O kinetike nakopleniya paramagnitnykh radiatsionnykh defectov v berillievykh keramikakh

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    Polyakov, A I; Ryabinkin, Yu A; Zashkvara, O V; Bitenbaev, M I [Fiziko-tekhniucheskij Inst. Ministerstva Nauki i Vysshego Obrazovaniya Respubliki Kazakhstan, Almaty (Kazakhstan); Petukhov, Yu V [Inst. Atomnoj Ehnergii Natsional' nogo Yadernogo Tsentra Respubliki Kazakhstan, Almaty (Kazakhstan)

    1999-07-01

    This paper [1] specifies that {gamma}-radiation of the beryllium-oxide-based ceramics results in development of paramagnetic radiation malformations emerging the ESR spectrum in form of doublet with the splitting rate of oestrasid {delta}{approx}1.6 and g-factor of 2.008. This report presents evaluation outcomes of dependence of paramagnetic radiation malformations concentration in beryllium ceramics on gamma-radiation dose ({sup 60}Co) within the range of 0-100 Mrad. Total paramagnetic parameters of beryllium ceramics in the range 0-100 Mrad of gamma-radiation dose varied slightly, and were specified by the first type of paramagnetic radiation malformations.

  3. Thermal decomposition of rhenium (5) complexes with 1,2,4-triazole. Termicheskoe razlozhenie kompleksov reniya (5) s 1,2,4-triazolom

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    Amindzhanov, A A; Gagieva, S Ch; Kotegov, K V [Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)

    1991-01-01

    Processes of thermal decomposition of rhenium (5) complexes with 1,2,4-triazole were studied. Thermolysis products were identified on the basis of data of the element analysis, IR spectra, conductometry and other methods. It is ascertained that at the first stage of thermolysis of hydroxyl-containing monomer complexes removal of water molecules occurs, and at the second one - dimerization process with formation of Re-O-Re group. It is shown that the nature of halide ion practically does not affect the temperature of the start of intensive thermal decomposition of the complexes.

  4. Cs-137 behaviour in landscape-geochemical structures of barrier complexes; Povedenie Cs-137 v landshaftno-geokhimicheskikh strukturakh bar`ernykh kompleksov

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    Strakh, L I; Ivashkevich, I I; Adamovich, A A [Akadehmiya Navuk Belarusi, Minsk (Belarus). Inst. Radyyabiyalogii; Zarubin, O L [AN Ukrainskoj SSR, Kiev (Ukraine). Inst. Yadernykh Issledovanij

    1999-12-31

    The Cs-137 distribution and cumulation accrues more actively in a marsh ecological systems of barrier complexes. The physical chemical and biogeochemical barriers influence on different way on these processes.

  5. Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze

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    Ashurova, N Kh; Yakubov, K G [Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)

    1992-11-01

    Methods for synthesis and separation in solid state of the rhenium(5) and molybdenum(5) onium complexes with diaza-18-crown-6(L), the content of which according to the data of elementary analysis, IRS in the close and remote areas, thermogravimetry, conductometry and potentiometry corresponds to the (H[sub 2]L)[EOX[sub 5

  6. Revitalizacija območja Kolinska v Ljubljani

    OpenAIRE

    Bajec, Eva

    2017-01-01

    Magistrsko delo obravnava problematiko območja nekdanje tovarne kavnih primesi Kolinska v Ljubljani. Območje se nahaja ob mestni vpadnici, Šmartinski cesti. Vsebuje objekte industrijske dediščine in skladiščne objekte, ki so ob selitvi proizvodnje v tujino popolnoma odslužili svojemu namenu. V teoretičnem delu je opisano zgodovinsko ozadje nastanka tovarniških kompleksov in industrijske arhitekture v Sloveniji. V nadaljevanju je predstavljena zgodovina nekdanje tovarne Kolinske in njenih...

  7. Preparative Radiation Chemistry of Transition Metal Complexes; Radiosynthese de complexes de metaux de transition; Radiatsionno-khimicheskij sintez kompleksnykh soedinenij perekhodnykh metallov; Radiosintesis de complejos de los metales de transicion

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    Gustorf, E. Koerner Von; Jun, M. -J.; Koller, H.; Schenck, G. O. [Max-Planck-Institut fuer Kohlenforschung, Abteilung Strahlenchemie, Muelheim-Ruhr, Federal Republic of Germany (Germany)

    1963-11-15

    aktivnosti. Provedeny sleduyushchie issledovaniya: 1) Radiatsionno-khimicheskij sintez {pi}-kompleksov metallov peremennoj valentnosti. Primerom mozhet sluzhit' poluchenie kompleksov angidrid maleinovoj kisloty + tetrakarbonil zheleza, diametilovyj ehfir fumarovoj kisloty + tetrakarbonil zheleza, metilovyj ehfir metakrilovoj kisloty + tetrakarbonil zheleza, vinilatsetat + tetrakarbonil zheleza i t.d. pri gamma-obluchenii ot kobal'tovogo istochnika Fe(CO){sub 5} s sootvetstvuyushchimi nenasyshchennymi soedineniyami. 2) Khimicheskie reaktsii v sluchae {pi}-kompleksov, poluchennykh pri radiatsionno-khimicheskom sinteze. Primerom mozhet sluzhit' polimerizatsiya vinilovykh soedinenij pri komnatnoj temperature pod dejstviem organicheskikh galogenovykh soedinenij na takie kompleksy, kak metilovyj ehfir metakrilovoj kisloty - tetrakarbonil zheleza, vinilatsetat - tetrakarbonil zheleza i t.d. 3) Sintez {pi}-kompleksov i karbonil'nykh soedinenij metallov peremennoj valentnosti pri obluchenii. Primerom mozhet sluzhit' gamma-obluchenie ot istochnika Co{sup 60} v srede galogenovykh uglevodorodov sleduyushchikh {pi}-kompleksov: [(C{sub 5}H{sub 5}) Fe], [(C{sub 5}H{sub 5}){sub 2}Ni], CH{sub 3}C{sub 5}H{sub 4}Mn(CO){sub 3}, (C{sub 5}H{sub 5})TiCl{sub 2}, Fe(CO){sub 5}, Ni(CO){sub 4}.

  8. Thermal And Gamma-Radiation Annealing Of The Iridium-192 Recoil Species In Crystalline Na{sub 2}IrCl{sub 6} {center_dot} 6H{sub 2}O; Recuit Thermique et par Rayonnement Gamma de l'espece {sup 192}Ir de Recul dans des Cristaux de Na{sub 2}IrCl{sub 6} * 6H{sub 2}O; 0422 0415 041f 041b 041e 0412 041e 0419 0418 0413 0410 041c 041c 0410 - 041e 0422 0416 0418 0413 041f 0420 041e 0414 0423 041a 0422 041e 0412 041e 0422 0414 0410 0427 0418 0418 0420 0418 0414 0418 042f -192 0412 041a 0420 0418 0421 0422 0410 041b 041b 0418 0427 0415 0421 041a 041e 041c Na{sub 2}IrCl{sub 6} {center_dot} 6H{sub 2}O; Regeneracion Termica y por Irradiacion Gamma de las Especies de Retroceso del Iridio-192 en Na{sub 2}IrCl{sub 6} {center_dot} 6H{sub 2}O Cristalino

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    Bell, Rita; Herr, W. [Kernforschungsanlage Juelich, Institut fuer Kernchemie der Universitaet Koeln, Cologne, Federal Republic of Germany (Germany)

    1965-04-15

    bol'shinstvo iz nih imeet anionnyj harakter, dva vystupajut v kachestve kationov, mechennyh Ir{sup 192}. Izuchalos' povedenie jetih svobodnyh ot nositelja soedinenij po otnosheniju k vosstanoviteljam i okisliteljam i ih starenie v rastvore. Nezavisimo ot jetogo byl issledovan gidroliz geksahloridn'hh kompleksov treh- i chetyrehvalentnogo iridija, mechennyh Cl{sup 36} i Ir{sup 192} . Sravnenie jetih dvuh serij rezul'tatov, podkreplennoe posledujushhimi rezul'tatami, poluchennymi pri nejtronnom aktivacionnom analize, daet vozmozhnost' obnaruzhit', chto bol'shaja chast' produktov otdachi sushhestvuet v vide oktajedricheskih kompleksov Ir-III, soderzhashhih razlichnye kolichestva Cl{sup -}, H{sub 2}O i OH{sup -} v kachestve ligandov. Po vsej vidimosti, kristallizacionnaja voda igraet vazhnuju rol' v formirovanii soedinenija otdachi. Teplovoj otzhig jetih produktov pri temperature 120 Degree-Sign C privodit k bystromu umen'sheniju vyhoda akvohlor-, gidrohlor- i akvogidroksohlorkompleksov po sravneniju s obrazovaniem ishodnogo soedinenija. Iskljucheniem javljaetsja pentahlorkompleks, vyhod kotorogo umen'shaetsja tol'ko posle pervonachal'nogo uvelichenija, chto ukazyvaet na to, chto on javljaetsja promezhutochnym sredi drugih produktov, obrazujushhihsja vo vremja otzhiga. Gamma-radiacionnyj otzhig pokazyvaet mnogie prostye stadii processa, obshhej tendenciej kotoryh javljaetsja perehod ot kompleksov s men'shim kolichestvom Cl k kompleksam, soderzhashhim gorazdo bol'shee kolichestvo Cl, chto v konechnom schete privodit k obrazovaniju geksahlor kompleksa. Jeto pokazyvaet, chto v processe otzhiga v ligandnuju sferu vhodjat dopolnitel'nye atomy (ili iony) hlora, zameshhaja H{sub 2}O, a takzhe ON (ON-). (author)

  9. Possible Utilization of Nitronitrosylruthenium Complexes as Tracers in Hydrology; Note sur l'utilisation eventuelle des complexes de nitronitrosylruthenium comme traceurs en hydrologie; O vozmozhnom ispol'zovanii kompleksa nitronitrozilruteniya v kachestve indikatorov v gidrologii; Nota sobre el posible empleo de los complejos de nitronitrosilrutenio como indicadores en hidrologia

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    Gailledreau, C. [Commissariat a l' Energie Atomique (France)

    1963-08-15

    Ru{sup 106} might be a useful tracer in hydrology. Its half-life of about one year is in a range in which there are few radioisotopes which can be used as tracers. There are a great variety of complexes of Ru{sup 106}, the nitro-complexes of nitrosylruthenium being amongst the most stable. Percolation tests have been made with nitronitrosylruthenium diluted in water from the mains, on columns of aquilerous sand and a very argillaceous soil. (author) [French] Le {sup 106}Ru pourrait etre un traceur interessant en hydrologie. Sa vie moyenne, environ un an, se situe dans une gamme ou il existe peu d'autres radioisotopes susceptibles d'etre utilises comme traceurs. Il existe une grande variete de complexes du les complexes nitro de nitrosylruthenium etant parmi les plus stables. Des essais de percolation ont ete effectues avec du nitronitrosylruthenium dilue dans de l'eau de ville, sur des colonnes de sable aquifere et d'un sol tres argileux. (author) [Spanish] El ''1''0''6Ru podria emplearse en calidad de indicador en hidrologia. Tiene un periodo del orden de un ano que le situa en una gama en la que existen muy pocos radioisotopos utilisable: como indicadores. El {sup 106}Ru puede formar una gran variedad de complejos, siendo los mas estables los nitrocomplejos de nitrosilrutenio. El autor ha realizado ensayos de percolacion con nitronitrosilrutenio diluido en agua de grifo, en columnas de arena acuifera y de suelo muy arcilloso. (author) [Russian] Ru{sup 106} mozhet byt' ispol'zovan v kachestve indikatora, predstavlyayushchego opredelennyj interes dlya gidrologii. Ego period poluraspada (priblizitel'n o 1'god) raspolagaetsj v gamme, gde sushchestvuet malo drugikh radioizotopov, kotorye mogut byt' ispol'zovany v kachestve indikatorov. Sushchestvuet bol'shoe mnogoobrazie kompleksov Ru{sup 106}, prichem kompleksy nitronitrozilruteniya otnosyatsya k naibolee stabil'nym. Provodilis ' opyty po perkolyatsii s nitronitrozilruteniem, rastvorennym v vodoprovodnoj vode, na

  10. Isotopic Ligand Exchange of Some Hexa-Coordinated Inorganic Complexes with Halide Ions in Solution and in Crystals; Echanges Isotopiques de Coordinats de Complexes Inorganiques Hexacoordonnes Avec des Ions Halogenures en Solution et dans les Cristaux; Izotopnyj obmen ligand v nekotorykh geksakoordinirovannykh ne- organicheskikh kompleksakh s ionami galoidov v rastvore i kristallakh; Intercambio Isotopico de Ligandos de Complejos Inorganicos Hexacoordinados y Iones Haluro en Solucion y en Cristales

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    Schmidt, G. B. [Institut fuer Kernchemie der Universitaet Koeln, Cologne, Federal Republic of Germany (Germany)

    1965-10-15

    -intercambio para los dos complejos isomericos de Co en estado solido es de mas del orden de 26 h. Se calculo que las energias de activacion son de 30 a 35 kcal/mol. La exposicion a los rayos X acelera el intercambio en forma proporcional a la dosis. Asimismo, se observa un aumento de la velocidad de intercambio termico de los cristales irradiados. Contrariamente a lo que sucede con los complejos de etilendiamina, los bromuros o cloruros de pentamminobromo, rodio y de pentamminobromoiridio en estado solido sufren un intercambio muy lento incluso elevando la temperatura a 210 Degree-Sign C. Pero si estos complejos solidos reciben energia de excitacion procedente de un proceso nuclear como la transicion isomerica {sup 80m}Br -> {sup 80}Br se producen reacciones de intercambio 'activadas'. Este fenomeno se ha investigado con cierto detalle. (author) [Russian] Kinetika reakcij izotopicheskogo obmena daet informaciju otnositel'no neustojchivosti kompleksov v rastvore i otnositel'no mehanizmov zameshhenija-. V kislotnyh rastvorah izuchali obmen mechennyh Vg{sup 82} kompleksov [Rh (NH{sub 3}){sub 5}Vg]{sup 2+} i [ier(NH{sub 3}){sub 5}Br]{sup 2+} s ionami Vg{sup -}, trans - [ Rh (en){sub 2}Cl{sub 2}]+ i trans - [ So(ep){sub 2}Sl{sub 2} ]+ s ionami Sl i trans [ So(ep){sub 2}Vg{sub 2} ] + s Vg{sup -} i [OsCl{sub 6}]{sup 2-} i [OsI{sub 6}]{sup 2-} s ionami SG{sup -} i 1{sup -} sootvetstvenno. Obmen v komplekse pentaminebromoiridium proishodit priblizitel'no v 60 raz medlennee, chem v sootvetstvujushhem komplekse pentamine- bromorodij. Bylo ustanovleno, chto postojannye skorosti dlja Rh-kompleksa sostavljajut pri 100 Degree-Sign S k = (1,03{+-}0,02) * 10{sup -2} min{sup -1} . Dlja Ir - kompleksa k{sub 100 Degree-Sign C} = 1,7 * 10{sup -4} min{sup -1}. Dlja oboih kompleksov skorost' obmena RnpH koncentracii kompleksa predstavljaet soboj velichinu pervogo porjadka. V kislotnyh rastvorah R pochti ne zavisit ot koncentracii bromida i vodoroda, a takzhe ot ionnoj nasyshhennosti. Jeto ukazyvaet na

  11. The Role of Free-Radicals in the Radiation Vulcanizing of Elastomers; Role des radicaux libres dans la vulcanisation radiochimique des elastomeres; O roli svobodnykh radikalov v protsesse radiatsionnoj vulkanizatsii ehlastomerov; Papel de los radicales libres en la radiovulcanizacion de los elastomeros

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    Kuz' minskij, A. S.; Fedoseeva, T. E.; Chertkova, V. F.

    1963-11-15

    izlucheniya v poslednee vremya ispol'zuetsya dlya sozdaniya promyshlennykh protsessov vulkanizatsii rezinovykh izdelij. Issledovateli udelyayut dostatochno bol'shoe vnimanie voprosam mekhanizma obrazovaniya trekhmernoj setki pod dejstviem izlucheniya; odnako do sikh por nedostatochno izucheny nachal'nye i promezhutochnye stadii radiatsionno-khimicheskikh reaktsij, vedushchikh k zashivaniyu molekulyarnykh tsepej, kotorye svyazany s obrazovaniem i gibel'yu svobodnykh radikalov, ion-radikalov i vozbuzhdennykh molekul. Izuchenie struktury i svojstv ehtikh chastits stalo vozmozhnym tol'ko s razrabotkoj i shirokim ispol'zovaniem metoda ehlektronnogo paramagnitnogo rezonansa (EHPR), pozvolyayushchego poluchit' neposredstvennuyu informatsiyu o strukture i svojstvakh paramagnitnykh chastits. Issledovanie protsessov rekombinatsii svobodnykh radikalov v linejnykh polimerakh daet vozmozhnost' podojti neposredstvenno k mekhanizmu radiatsionnoj vulkanizatsii. V poslednee vremya poyavilas' tendentsiya ispol'zovat' ioniziruyushchee izluchenie dlya vulkanizatsii sernykh vulkanizatov, tak kak sochetanie sernykh i uglerodnykh poperechnykh svyazej daet maksimal'noe uluchshenie fiziko-mekhanicheskikh svojstv izdelij. V svyaz'i s ehtoj novoj problemoj predstavlyalo interes izuchenie kineticheskikh svojstv svobodnykh radikalov v polimerakh s razvitoj prostranstvennoj strukturoj. Podrobno isledovalis' protsessy rekombinatsii svobodnykh radikalov, poluchennykh u-oblucheniem, v svyazi so strukturnymi osobennostyami linejnykh i sshitykh polimerov, a imenno - orientatsiej i vnutrennej podvizhnost'yu molekulyarnykh tsepej. V vysokoehlasticheskikh polimerakh tipa kauchukov, kharakterizukhshchikhsya bol'shoj vnutrennej podvizhnost'yu tsepej i maloj ehnergiej mezhmolekulyarnykh svyazej, pri temperaturakh vyshe T akty rekombinatsii svobodnykh radikalov osushchestvlyayutsya s ochen' bol'shimi skorostyami. Kontsentratsiya radikalov v obraztsakh kauchukov, obluchennykh v zhidkom azote, umen'shaetsya pri