Randomised, double-blinded, placebo-controlled, clinical trial of ozone therapy as treatment of sudden sensorineural hearing loss.

Science.gov (United States)

Ragab, A; Shreef, E; Behiry, E; Zalat, S; Noaman, M

2009-01-01

To investigate the safety and efficacy of ozone therapy in adult patients with sudden sensorineural hearing loss. Prospective, randomised, double-blinded, placebo-controlled, parallel group, clinical trial. Forty-five adult patients presented with sudden sensorineural hearing loss, and were randomly allocated to receive either placebo (15 patients) or ozone therapy (auto-haemotherapy; 30 patients). For the latter treatment, 100 ml of the patient's blood was treated immediately with a 1:1 volume, gaseous mixture of oxygen and ozone (from an ozone generator) and re-injected into the patient by intravenous infusion. Treatments were administered twice weekly for 10 sessions. The following data were recorded: pre- and post-treatment mean hearing gains; air and bone pure tone averages; speech reception thresholds; speech discrimination scores; and subjective recovery rates. Significant recovery was observed in 23 patients (77 per cent) receiving ozone treatment, compared with six (40 per cent) patients receiving placebo (p < 0.05). Mean hearing gains, pure tone averages, speech reception thresholds and subjective recovery rates were significantly better in ozone-treated patients compared with placebo-treated patients (p < 0.05). Ozone therapy is a significant modality for treatment of sudden sensorineural hearing loss; no complications were observed.

Assessment of crop yield losses in Punjab and Haryana using 2 years of continuous in situ ozone measurements

Science.gov (United States)

Sinha, B.; Singh Sangwan, K.; Maurya, Y.; Kumar, V.; Sarkar, C.; Chandra, B. P.; Sinha, V.

2015-08-01

In this study we use a high-quality data set of in situ ozone measurements at a suburban site called Mohali in the state of Punjab to estimate ozone-related crop yield losses for wheat, rice, cotton and maize for Punjab and the neighbouring state Haryana for the years 2011-2013. We intercompare crop yield loss estimates according to different exposure metrics, such as AOT40 (accumulated ozone exposure over a threshold of 40) and M7 (mean 7-hour ozone mixing ratio from 09:00 to 15:59), for the two major crop growing seasons of kharif (June-October) and rabi (November-April) and establish a new crop-yield-exposure relationship for southern Asian wheat, maize and rice cultivars. These are a factor of 2 more sensitive to ozone-induced crop yield losses compared to their European and American counterparts. Relative yield losses based on the AOT40 metrics ranged from 27 to 41 % for wheat, 21 to 26 % for rice, 3 to 5 % for maize and 47 to 58 % for cotton. Crop production losses for wheat amounted to 20.8 ± 10.4 million t in the fiscal year of 2012-2013 and 10.3 ± 4.7 million t in the fiscal year of 2013-2014 for Punjab and Haryana taken together. Crop production losses for rice totalled 5.4 ± 1.2 million t in the fiscal year of 2012-2013 and 3.2 ± 0.8 million t in the year 2013-2014 for Punjab and Haryana taken together. The Indian National Food Security Ordinance entitles ~ 820 million of India's poor to purchase about 60 kg of rice or wheat per person annually at subsidized rates. The scheme requires 27.6 Mt of wheat and 33.6 Mt of rice per year. The mitigation of ozone-related crop production losses in Punjab and Haryana alone could provide > 50 % of the wheat and ~ 10 % of the rice required for the scheme. The total economic cost losses in Punjab and Haryana amounted to USD 6.5 ± 2.2 billion in the fiscal year of 2012-2013 and USD 3.7 ± 1.2 billion in the fiscal year of 2013-2014. This economic loss estimate represents a very conservative lower limit based on

Modulations of stratospheric ozone by volcanic eruptions

Science.gov (United States)

Blanchette, Christian; Mcconnell, John C.

1994-01-01

We have used a time series of aerosol surface based on the measurements of Hofmann to investigate the modulation of total column ozone caused by the perturbation to gas phase chemistry by the reaction N2O5(gas) + H2O(aero) yields 2HNO3(gas) on the surface of stratospheric aerosols. We have tested a range of values for its reaction probability, gamma = 0.02, 0.13, and 0.26 which we compared to unperturbed homogeneous chemistry. Our analysis spans a period from Jan. 1974 to Oct. 1994. The results suggest that if lower values of gamma are the norm then we would expect larger ozone losses for highly enhanced aerosol content that for larger values of gamma. The ozone layer is more sensitive to the magnitude of the reaction probability under background conditions than during volcanically active periods. For most conditions, the conversion of NO2 to HNO3 is saturated for reaction probability in the range of laboratory measurements, but is only absolutely saturated following major volcanic eruptions when the heterogeneous loss dominates the losses of N2O5. The ozone loss due to this heterogeneous reaction increases with the increasing chlorine load. Total ozone losses calculated are comparable to ozone losses reported from TOMS and Dobson data.

Ozone induced leaf loss and decreased leaf production of European Holly (Ilex aquifolium L.) over multiple seasons

International Nuclear Information System (INIS)

Ranford, Jonathan; Reiling, Kevin

2007-01-01

European Holly (Ilex aquifolium L.) was used to study the impact of one short (28 day) ozone fumigation episode on leaf production, leaf loss and stomatal conductance (g s ), in order to explore potential longer term effects over 3 growing seasons. Young I. aquifolium plants received an episode of either charcoal-filtered air or charcoal-filtered air with 70 nl l -1 O 3 added for 7 h d -1 over a 28 day period from June 15th 1996, then placed into ambient environment, Stoke-on-Trent, U.K. Data were collected per leaf cohort over the next three growing seasons. Ozone exposure significantly increased leaf loss and stomatal conductance and reduced leaf production over all subsequent seasons. Impact of the initial ozone stress was still detected in leaves that had no direct experimental ozone exposure. This study has shown the potential of ozone to introduce long-term phenological perturbations into ecosystems by influencing productivity over a number of seasons. - Ozone significantly alters Ilex aquifolium leaf production and loss over multiple seasons

Ozone and Water Stress: Effects on the Behaviour of Two White Clover Biotypes

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Massimo Fagnano

Full Text Available ozone pollution, water stress, stomata conductance, ozone uptake, clover, OTC.Ozone is a strong oxidizing pollutant which derives by alteration of the photolytic NOx cycle and it accumulates in the troposphere spreading in rural areas and therefore determining injuries on natural vegetation and crops. Since its penetration occurs mainly through stomata, all factors which alter plant-atmosphere relations could be able to modify plant response to ozone. Interaction between ozone and water stress in Mediterranean environment was studied on ozone resistant and sensitive biotypes of white clover, which were grown in charcoal filtered and notfiltered Open Top Chambers in factorial combination with different levels of water supply. Measurements of biomass, leaf area and stomatal conductance were made during the growth period. Ozone injuries were estimated as not-filtered/filtered OTC yield ratio; the stomatal flux of ozone was estimated multiplying stomata conductance x diffusivity ratio between ozone and water vapour (0.613 x ozone hourly concentrations. The hourly values of ozone uptake were cumulated throughout the cropping periods of the two years. In the sensitive biotype, water stress reduced yield losses due to ozone from 38% to 22%, as well as yield losses due to water stress were reduced by the presence of ozone from 43% to 29%, while no interaction between ozone and water stress was observed in the resistant biotype. Biomass yield losses of the sensitive biotype were strictly correlated to cumulated ozone uptake (R2 = 0.99, while biomass yield losses of the resistant biotype were not affected by the ozone fluxes variations created by the treatments. Flux based models could better estimate yield losses due to ozone in Mediterranean environments in which other stresses could be contemporary present; therefore, the new European directives might replace the actual thresholds based

Projecting future summer mortality due to ambient ozone concentration and temperature changes

Science.gov (United States)

Lee, Jae Young; Lee, Soo Hyun; Hong, Sung-Chul; Kim, Ho

2017-05-01

Climate change is known to affect the human health both directly by increased heat stress and indirectly by altering environments, particularly by altering the rate of ambient ozone formation in the atmosphere. Thus, the risks of climate change may be underestimated if the effects of both future temperature and ambient ozone concentrations are not considered. This study presents a projection of future summer non-accidental mortality in seven major cities of South Korea during the 2020s (2016-2025) and 2050s (2046-2055) considering changes in temperature and ozone concentration, which were predicted by using the HadGEM3-RA model and Integrated Climate and Air Quality Modeling System, respectively. Four Representative Concentration Pathway (RCP) scenarios (RCP 2.6, 4.5, 6.0, and 8.5) were considered. The result shows that non-accidental summer mortality will increase by 0.5%, 0.0%, 0.4%, and 0.4% in the 2020s, 1.9%, 1.5%, 1.2%, and 4.4% in the 2050s due to temperature change compared to the baseline mortality during 2001-2010, under RCP 2.6, 4.5, 6.0, and 8.5, respectively, whereas the mortality will increase by 0.0%, 0.5%, 0.0%, and 0.5% in the 2020s, and 0.2%, 0.2%, 0.4%, and 0.6% in the 2050s due to ozone concentration change. The projection result shows that the future summer morality in South Korea is increased due to changes in both temperature and ozone, and the magnitude of ozone-related increase is much smaller than that of temperature-related increase, especially in the 2050s.

An Estimation of the Climatic Effects of Stratospheric Ozone Losses during the 1980s. Appendix K

Science.gov (United States)

MacKay, Robert M.; Ko, Malcolm K. W.; Shia, Run-Lie; Yang, Yajaing; Zhou, Shuntai; Molnar, Gyula

1997-01-01

In order to study the potential climatic effects of the ozone hole more directly and to assess the validity of previous lower resolution model results, the latest high spatial resolution version of the Atmospheric and Environmental Research, Inc., seasonal radiative dynamical climate model is used to simulate the climatic effects of ozone changes relative to the other greenhouse gases. The steady-state climatic effect of a sustained decrease in lower stratospheric ozone, similar in magnitude to the observed 1979-90 decrease, is estimated by comparing three steady-state climate simulations: 1) 1979 greenhouse gas concentrations and 1979 ozone, II) 1990 greenhouse gas concentrations with 1979 ozone, and III) 1990 greenhouse gas concentrations with 1990 ozone. The simulated increase in surface air temperature resulting from nonozone greenhouse gases is 0.272 K. When changes in lower stratospheric ozone are included, the greenhouse warming is 0.165 K, which is approximately 39% lower than when ozone is fixed at the 1979 concentrations. Ozone perturbations at high latitudes result in a cooling of the surface-troposphere system that is greater (by a factor of 2.8) than that estimated from the change in radiative forcing resulting from ozone depiction and the model's 2 x CO, climate sensitivity. The results suggest that changes in meridional heat transport from low to high latitudes combined with the decrease in the infrared opacity of the lower stratosphere are very important in determining the steady-state response to high latitude ozone losses. The 39% compensation in greenhouse warming resulting from lower stratospheric ozone losses is also larger than the 28% compensation simulated previously by the lower resolution model. The higher resolution model is able to resolve the high latitude features of the assumed ozone perturbation, which are important in determining the overall climate sensitivity to these perturbations.

The Effect of Elevated Ozone Concentrations with Varying Shading on Dry Matter Loss in a Winter Wheat-Producing Region in China.

Science.gov (United States)

Xu, Jingxin; Zheng, Youfei; He, Yuhong; Wu, Rongjun; Mai, Boru; Kang, Hanqing

2016-01-01

Surface-level ozone pollution causes crop production loss by directly reducing healthy green leaf area available for carbon fixation. Ozone and its precursors also affect crop photosynthesis indirectly by decreasing solar irradiance. Pollutants are reported to have become even more severe in Eastern China over the last ten years. In this study, we investigated the effect of a combination of elevated ozone concentrations and reduced solar irradiance on a popular winter wheat Yangmai13 (Triticum aestivum L.) at field and regional levels in China. Winter wheat was grown in artificial shading and open-top-chamber environments. Treatment 1 (T1, i.e., 60% shading with an enhanced ozone of 100±9 ppb), Treatment 2 (T2, i.e., 20% shading with an enhanced ozone of 100±9 ppb), and Control Check Treatment (CK, i.e., no shading with an enhanced ozone of 100±9 ppb), with two plots under each, were established to investigate the response of winter wheat under elevated ozone concentrations and varying solar irradiance. At the field level, linear temporal relationships between dry matter loss and cumulative stomatal ozone uptake were first established through a parameterized stomatal-flux model. At the regional level, ozone concentrations and meteorological variables, including solar irradiance, were simulated using the WRF-CMAQ model (i.e., a meteorology and air quality modeling system). These variables were then used to estimate cumulative stomatal ozone uptake for the four major winter wheat-growing provinces. The regional-level cumulative ozone uptake was then used as the independent variable in field data-based regression models to predict dry matter loss over space and time. Field-level results showed that over 85% (T1: R(2) = 0.85 & T2: R(2) = 0.89) of variation in dry matter loss was explained by cumulative ozone uptake. Dry matter was reduced by 3.8% in T1 and 2.2% in T2 for each mmol O3·m(-2) of cumulative ozone uptake. At the regional level, dry matter loss in winter

The Effect of Elevated Ozone Concentrations with Varying Shading on Dry Matter Loss in a Winter Wheat-Producing Region in China.

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Jingxin Xu

Full Text Available Surface-level ozone pollution causes crop production loss by directly reducing healthy green leaf area available for carbon fixation. Ozone and its precursors also affect crop photosynthesis indirectly by decreasing solar irradiance. Pollutants are reported to have become even more severe in Eastern China over the last ten years. In this study, we investigated the effect of a combination of elevated ozone concentrations and reduced solar irradiance on a popular winter wheat Yangmai13 (Triticum aestivum L. at field and regional levels in China. Winter wheat was grown in artificial shading and open-top-chamber environments. Treatment 1 (T1, i.e., 60% shading with an enhanced ozone of 100±9 ppb, Treatment 2 (T2, i.e., 20% shading with an enhanced ozone of 100±9 ppb, and Control Check Treatment (CK, i.e., no shading with an enhanced ozone of 100±9 ppb, with two plots under each, were established to investigate the response of winter wheat under elevated ozone concentrations and varying solar irradiance. At the field level, linear temporal relationships between dry matter loss and cumulative stomatal ozone uptake were first established through a parameterized stomatal-flux model. At the regional level, ozone concentrations and meteorological variables, including solar irradiance, were simulated using the WRF-CMAQ model (i.e., a meteorology and air quality modeling system. These variables were then used to estimate cumulative stomatal ozone uptake for the four major winter wheat-growing provinces. The regional-level cumulative ozone uptake was then used as the independent variable in field data-based regression models to predict dry matter loss over space and time. Field-level results showed that over 85% (T1: R(2 = 0.85 & T2: R(2 = 0.89 of variation in dry matter loss was explained by cumulative ozone uptake. Dry matter was reduced by 3.8% in T1 and 2.2% in T2 for each mmol O3·m(-2 of cumulative ozone uptake. At the regional level, dry matter

The major stratospheric final warming in 2016: dispersal of vortex air and termination of Arctic chemical ozone loss

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G. L. Manney

2016-12-01

Full Text Available The 2015/16 Northern Hemisphere winter stratosphere appeared to have the greatest potential yet seen for record Arctic ozone loss. Temperatures in the Arctic lower stratosphere were at record lows from December 2015 through early February 2016, with an unprecedented period of temperatures below ice polar stratospheric cloud thresholds. Trace gas measurements from the Aura Microwave Limb Sounder (MLS show that exceptional denitrification and dehydration, as well as extensive chlorine activation, occurred throughout the polar vortex. Ozone decreases in 2015/16 began earlier and proceeded more rapidly than those in 2010/11, a winter that saw unprecedented Arctic ozone loss. However, on 5–6 March 2016 a major final sudden stratospheric warming ("major final warming", MFW began. By mid-March, the mid-stratospheric vortex split after being displaced far off the pole. The resulting offspring vortices decayed rapidly preceding the full breakdown of the vortex by early April. In the lower stratosphere, the period of temperatures low enough for chlorine activation ended nearly a month earlier than that in 2011 because of the MFW. Ozone loss rates were thus kept in check because there was less sunlight during the cold period. Although the winter mean volume of air in which chemical ozone loss could occur was as large as that in 2010/11, observed ozone values did not drop to the persistently low values reached in 2011.We use MLS trace gas measurements, as well as mixing and polar vortex diagnostics based on meteorological fields, to show how the timing and intensity of the MFW and its impact on transport and mixing halted chemical ozone loss. Our detailed characterization of the polar vortex breakdown includes investigations of individual offspring vortices and the origins and fate of air within them. Comparisons of mixing diagnostics with lower-stratospheric N2O and middle-stratospheric CO from MLS (long-lived tracers show rapid vortex erosion and

The Sensitivity of Arctic Ozone Loss to Polar Stratospheric Cloud Volume and Chlorine and Bromine Loading in a Chemistry and Transport Model

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Douglass, A. R.; Stolarski, R. S.; Strahan, S. E.; Polansky, B. C.

2006-01-01

The sensitivity of Arctic ozone loss to polar stratospheric cloud volume (V(sub PSC)) and chlorine and bromine loading is explored using chemistry and transport models (CTMs). A simulation using multi-decadal output from a general circulation model (GCM) in the Goddard Space Flight Center (GSFC) CTM complements one recycling a single year s GCM output in the Global Modeling Initiative (GMI) CTM. Winter polar ozone loss in the GSFC CTM depends on equivalent effective stratospheric chlorine (EESC) and polar vortex characteristics (temperatures, descent, isolation, polar stratospheric cloud amount). Polar ozone loss in the GMI CTM depends only on changes in EESC as the dynamics repeat annually. The GSFC CTM simulation reproduces a linear relationship between ozone loss and Vpsc derived from observations for 1992 - 2003 which holds for EESC within approx.85% of its maximum (approx.1990 - 2020). The GMI simulation shows that ozone loss varies linearly with EESC for constant, high V(sub PSC).

Ozone depletion following future volcanic eruptions

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Eric Klobas, J.; Wilmouth, David M.; Weisenstein, Debra K.; Anderson, James G.; Salawitch, Ross J.

2017-07-01

While explosive volcanic eruptions cause ozone loss in the current atmosphere due to an enhancement in the availability of reactive chlorine following the stratospheric injection of sulfur, future eruptions are expected to increase total column ozone as halogen loading approaches preindustrial levels. The timing of this shift in the impact of major volcanic eruptions on the thickness of the ozone layer is poorly known. Modeling four possible climate futures, we show that scenarios with the smallest increase in greenhouse gas concentrations lead to the greatest risk to ozone from heterogeneous chemical processing following future eruptions. We also show that the presence in the stratosphere of bromine from natural, very short-lived biogenic compounds is critically important for determining whether future eruptions will lead to ozone depletion. If volcanic eruptions inject hydrogen halides into the stratosphere, an effect not considered in current ozone assessments, potentially profound reductions in column ozone would result.

SMM mesospheric ozone measurements

Science.gov (United States)

Aikin, A. C.

1990-01-01

The main objective was to understand the secular and seasonal behavior of ozone in the lower mesosphere, 50 to 70 km. This altitude region is important in understanding the factors which determine ozone behavior. A secondary objective is the study of stratospheric ozone in the polar regions. Use is made of results from the SBUV satellite borne instrument. In the Arctic the interaction between chlorine compounds and low molecular weight hydrocarbons is studied. More than 30,000 profiles were obtained using the UVSP instrument on the SMM spacecraft. Several orbits of ozone data per day were obtained allowing study of the current rise in solar activity from the minimum until the present. Analysis of Nimbus 7 SBUV data in Antarctic spring indicates that ozone is depleted within the polar vortex relative to ozone outside the vortex. This depletion confirms the picture of ozone loss at altitudes where polar stratospheric clouds exist. In addition, there is ozone loss above the cloud level indicating that there is another mechanism in addition to ozone loss initiated by heterogeneous chlorine reactions on cloud particles.

Chemical and Dynamical Impacts of Stratospheric Sudden Warmings on Arctic Ozone Variability

Science.gov (United States)

Strahan, S. E.; Douglass, A. R.; Steenrod, S. D.

2016-01-01

We use the Global Modeling Initiative (GMI) chemistry and transport model with Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields to quantify heterogeneous chemical ozone loss in Arctic winters 2005-2015. Comparisons to Aura Microwave Limb Sounder N2O and O3 observations show the GMI simulation credibly represents the transport processes and net heterogeneous chemical loss necessary to simulate Arctic ozone. We find that the maximum seasonal ozone depletion varies linearly with the number of cold days and with wave driving (eddy heat flux) calculated from MERRA fields. We use this relationship and MERRA temperatures to estimate seasonal ozone loss from 1993 to 2004 when inorganic chlorine levels were in the same range as during the Aura period. Using these loss estimates and the observed March mean 63-90N column O3, we quantify the sensitivity of the ozone dynamical resupply to wave driving, separating it from the sensitivity of ozone depletion to wave driving. The results show that about 2/3 of the deviation of the observed March Arctic O3 from an assumed climatological mean is due to variations in O3 resupply and 13 is due to depletion. Winters with a stratospheric sudden warming (SSW) before mid-February have about 1/3 the depletion of winters without one and export less depletion to the midlatitudes. However, a larger effect on the spring midlatitude ozone comes from dynamical differences between warm and cold Arctic winters, which can mask or add to the impact of exported depletion.

Trends in Pinus ponderosa foliar pigment concentration due to chronic exposure of ozone and acid rain

International Nuclear Information System (INIS)

Neuman, L.; Houpis, J.; Anderson, P.

1991-01-01

To determine the effects of ozone and acid rain on mature Ponderosa pine trees, Lawrence Livermore National Lab. has collaborated with University of California Berkeley, University of California Davis, California State University Chico, and the US Forest Service at the latter's Chico Tree Improvement Center. Foliar tissue from mature grafted scions of Pinus ponderosa were exposed to two times ambient ozone for ten months and to acid rain (3.0 pH) weekly for 10 weeks using branch exposure chambers. Pigment extracts were analyzed spectrophotometrically for concentrations of chlorophylls a and b, and carotenoid pigments, at 662 nm, 644 nm, and 470 nm, respectively. Pigment concentrations were expressed on a surface area basis. Preliminary results revealed that chlorophyll a showed a downward trend due to the ozone treatment. Acid rain caused no effects on these three pigments, however, chlorophyll b showed an upward trend due to the interaction of ozone and acid rain. The carotenoid pigments showed no changes due to the treatments either singly, or in combination

Temperature thresholds for chlorine activation and ozone loss in the polar stratosphere

Energy Technology Data Exchange (ETDEWEB)

Drdla, K. [NASA Ames Research Center, Moffett Field, CA (United States); Mueller, R. [Forschungszentrum Juelich (DE). Inst. of Energy and Climate Research (IEK-7)

2012-07-01

Low stratospheric temperatures are known to be responsible for heterogeneous chlorine activation that leads to polar ozone depletion. Here, we discuss the temperature threshold below which substantial chlorine activation occurs. We suggest that the onset of chlorine activation is dominated by reactions on cold binary aerosol particles, without the formation of polar stratospheric clouds (PSCs), i.e. without any significant uptake of HNO{sub 3} from the gas phase. Using reaction rates on cold binary aerosol in a model of stratospheric chemistry, a chlorine activation threshold temperature, T{sub ACL}, is derived. At typical stratospheric conditions, T{sub ACL} is similar in value to T{sub NAT} (within 1-2 K), the highest temperature at which nitric acid trihydrate (NAT) can exist. T{sub NAT} is still in use to parameterise the threshold temperature for the onset of chlorine activation. However, perturbations can cause T{sub ACL} to differ from T{sub NAT}: T{sub ACL} is dependent upon H{sub 2} O and potential temperature, but unlike T{sub NAT} is not dependent upon HNO3. Furthermore, in contrast to T{sub NAT}, T{sub ACL} is dependent upon the stratospheric sulfate aerosol loading and thus provides a means to estimate the impact on polar ozone of strong volcanic eruptions and some geo-engineering options, which are discussed. A parameterisation of T{sub ACL} is provided here, allowing it to be calculated for low solar elevation (or high solar zenith angle) over a comprehensive range of stratospheric conditions. Considering T{sub ACL} as a proxy for chlorine activation cannot replace a detailed model calculation, and polar ozone loss is influenced by other factors apart from the initial chlorine activation. However, T{sub ACL} provides a more accurate description of the temperature conditions necessary for chlorine activation and ozone loss in the polar stratosphere than T{sub NAT}. (orig.)

Fractal and variability analysis of simulations in ozone level due to oxides of nitrogen and sulphur

Science.gov (United States)

Bhardwaj, Rashmi; Pruthi, Dimple

2017-10-01

Air pollution refers to the release of pollutants into the air. These pollutants are detrimental to human the planet as a whole. Apart from causing respiratory infections and pulmonary disorders, rising levels of Nitrogen Dioxide is worsening ozone pollution. Formation of Ground-level ozone involves nitrogen oxides and volatile gases in the sunlight. Volatile gases are emitted from vehicles primarily. Ozone is harmful gas and its exposure can trigger serious health effects as it damages lung tissues. In order to decrease the level of ozone, level of oxides leading to ozone formation has to be dealt with. This paper deals with the simulations in ozone due to oxides of nitrogen and sulphur. The data from Central Pollution Control Board shows positive correlation for ozone with oxides of sulphur and nitrogen for RK Puram, Delhi in India where high concentration of ozone has been found. The correlation between ozone and sulphur, nitrogen oxides is moderate during summer while weak during winters. Ozone with nitrogen and sulphur dioxide follow persistent behavior as Hurst exponent is between 0.5 and 1. The fractal dimension for Sulphur dioxide is 1.4957 indicating the Brownian motion. The behavior of ozone is unpredictable as index of predictability is close to zero.

Chemical and climatic drivers of radiative forcing due to changes in stratospheric and tropospheric ozone over the 21st century

Science.gov (United States)

Banerjee, Antara; Maycock, Amanda C.; Pyle, John A.

2018-02-01

The ozone radiative forcings (RFs) resulting from projected changes in climate, ozone-depleting substances (ODSs), non-methane ozone precursor emissions and methane between the years 2000 and 2100 are calculated using simulations from the UM-UKCA chemistry-climate model (UK Met Office's Unified Model containing the United Kingdom Chemistry and Aerosols sub-model). Projected measures to improve air-quality through reductions in non-methane tropospheric ozone precursor emissions present a co-benefit for climate, with a net global mean ozone RF of -0.09 W m-2. This is opposed by a positive ozone RF of 0.05 W m-2 due to future decreases in ODSs, which is driven by an increase in tropospheric ozone through stratosphere-to-troposphere transport of air containing higher ozone amounts. An increase in methane abundance by more than a factor of 2 (as projected by the RCP8.5 scenario) is found to drive an ozone RF of 0.18 W m-2, which would greatly outweigh the climate benefits of non-methane tropospheric ozone precursor reductions. A small fraction (˜ 15 %) of the ozone RF due to the projected increase in methane results from increases in stratospheric ozone. The sign of the ozone RF due to future changes in climate (including the radiative effects of greenhouse gases, sea surface temperatures and sea ice changes) is shown to be dependent on the greenhouse gas emissions pathway, with a positive RF (0.05 W m-2) for RCP4.5 and a negative RF (-0.07 W m-2) for the RCP8.5 scenario. This dependence arises mainly from differences in the contribution to RF from stratospheric ozone changes. Considering the increases in tropopause height under climate change causes only small differences (≤ |0.02| W m-2) for the stratospheric, tropospheric and whole-atmosphere RFs.

Ozone Exposure-Response in Field Grown Soybean: Characterizing Intraspecific Variability of Physiology and Biochemistry

Science.gov (United States)

Crop losses due to rising tropospheric ozone concentrations ([ozone]) in 2000 were estimated to cost $1.8 to $3.9 billion in the U.S. and $3.0 to $5.5 billion in China, and are expected to grow with the predicted 25% increase in background [ozone] over the next 30 to 50 years. This challenge provide...

Multi-Decadal Global Cooling and Unprecedented Ozone Loss Following a Regional Nuclear Conflict

Science.gov (United States)

Mills, M. J.; Toon, O. B.; Lee-Taylor, J. M.; Robock, A.

2014-12-01

We present the first study of the global impacts of a regional nuclear war with an Earth system model including atmospheric chemistry, ocean dynamics, and interactive sea-ice and land models (Mills et al., 2014). A limited, regional nuclear war between India and Pakistan in which each side detonates 50 15-kt weapons could produce about 5 Tg of black carbon. This would self-loft to the stratosphere, where it would spread globally, producing a sudden drop in surface temperatures and intense heating of the stratosphere. Using the Community Earth System Model with the Whole Atmosphere Community Climate Model (CESM1(WACCM)), we calculate an e-folding time of 8.7 years for stratospheric black carbon, compared to 4-6.5 years for previous studies (figure panel a). Our calculations show that global ozone losses of 20-50% over populated areas, levels unprecedented in human history, would accompany the coldest average surface temperatures in the last 1000 years (figure panel c). We calculate summer enhancements in UV indices of 30-80% over Mid-Latitudes, suggesting widespread damage to human health, agriculture, and terrestrial and aquatic ecosystems. Killing frosts would reduce growing seasons by 10-40 days per year for 5 years. Surface temperatures would be reduced for more than 25 years, due to thermal inertia and albedo effects in the ocean and expanded sea ice. The combined cooling and enhanced UV would put significant pressures on global food supplies and could trigger a global nuclear famine. Knowledge of the impacts of 100 small nuclear weapons should motivate the elimination of the more than 17,000 nuclear weapons that exist today. Mills, M. J., O. B. Toon, J. Lee-Taylor, and A. Robock (2014), Multidecadal global cooling and unprecedented ozone loss following a regional nuclear conflict, Earth's Future, 2(4), 161-176, doi:10.1002/2013EF000205.

Chemical and climatic drivers of radiative forcing due to changes in stratospheric and tropospheric ozone over the 21st century

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A. Banerjee

2018-02-01

Full Text Available The ozone radiative forcings (RFs resulting from projected changes in climate, ozone-depleting substances (ODSs, non-methane ozone precursor emissions and methane between the years 2000 and 2100 are calculated using simulations from the UM-UKCA chemistry–climate model (UK Met Office's Unified Model containing the United Kingdom Chemistry and Aerosols sub-model. Projected measures to improve air-quality through reductions in non-methane tropospheric ozone precursor emissions present a co-benefit for climate, with a net global mean ozone RF of −0.09 W m−2. This is opposed by a positive ozone RF of 0.05 W m−2 due to future decreases in ODSs, which is driven by an increase in tropospheric ozone through stratosphere-to-troposphere transport of air containing higher ozone amounts. An increase in methane abundance by more than a factor of 2 (as projected by the RCP8.5 scenario is found to drive an ozone RF of 0.18 W m−2, which would greatly outweigh the climate benefits of non-methane tropospheric ozone precursor reductions. A small fraction (∼ 15 % of the ozone RF due to the projected increase in methane results from increases in stratospheric ozone. The sign of the ozone RF due to future changes in climate (including the radiative effects of greenhouse gases, sea surface temperatures and sea ice changes is shown to be dependent on the greenhouse gas emissions pathway, with a positive RF (0.05 W m−2 for RCP4.5 and a negative RF (−0.07 W m−2 for the RCP8.5 scenario. This dependence arises mainly from differences in the contribution to RF from stratospheric ozone changes. Considering the increases in tropopause height under climate change causes only small differences (≤ |0.02| W m−2 for the stratospheric, tropospheric and whole-atmosphere RFs.

Impacts of stratospheric sulfate geoengineering on tropospheric ozone

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L. Xia

2017-10-01

Full Text Available A range of solar radiation management (SRM techniques has been proposed to counter anthropogenic climate change. Here, we examine the potential effects of stratospheric sulfate aerosols and solar insolation reduction on tropospheric ozone and ozone at Earth's surface. Ozone is a key air pollutant, which can produce respiratory diseases and crop damage. Using a version of the Community Earth System Model from the National Center for Atmospheric Research that includes comprehensive tropospheric and stratospheric chemistry, we model both stratospheric sulfur injection and solar irradiance reduction schemes, with the aim of achieving equal levels of surface cooling relative to the Representative Concentration Pathway 6.0 scenario. This allows us to compare the impacts of sulfate aerosols and solar dimming on atmospheric ozone concentrations. Despite nearly identical global mean surface temperatures for the two SRM approaches, solar insolation reduction increases global average surface ozone concentrations, while sulfate injection decreases it. A fundamental difference between the two geoengineering schemes is the importance of heterogeneous reactions in the photochemical ozone balance with larger stratospheric sulfate abundance, resulting in increased ozone depletion in mid- and high latitudes. This reduces the net transport of stratospheric ozone into the troposphere and thus is a key driver of the overall decrease in surface ozone. At the same time, the change in stratospheric ozone alters the tropospheric photochemical environment due to enhanced ultraviolet radiation. A shared factor among both SRM scenarios is decreased chemical ozone loss due to reduced tropospheric humidity. Under insolation reduction, this is the dominant factor giving rise to the global surface ozone increase. Regionally, both surface ozone increases and decreases are found for both scenarios; that is, SRM would affect regions of the world differently in terms of air

Impacts of stratospheric sulfate geoengineering on tropospheric ozone

Science.gov (United States)

Xia, Lili; Nowack, Peer J.; Tilmes, Simone; Robock, Alan

2017-10-01

A range of solar radiation management (SRM) techniques has been proposed to counter anthropogenic climate change. Here, we examine the potential effects of stratospheric sulfate aerosols and solar insolation reduction on tropospheric ozone and ozone at Earth's surface. Ozone is a key air pollutant, which can produce respiratory diseases and crop damage. Using a version of the Community Earth System Model from the National Center for Atmospheric Research that includes comprehensive tropospheric and stratospheric chemistry, we model both stratospheric sulfur injection and solar irradiance reduction schemes, with the aim of achieving equal levels of surface cooling relative to the Representative Concentration Pathway 6.0 scenario. This allows us to compare the impacts of sulfate aerosols and solar dimming on atmospheric ozone concentrations. Despite nearly identical global mean surface temperatures for the two SRM approaches, solar insolation reduction increases global average surface ozone concentrations, while sulfate injection decreases it. A fundamental difference between the two geoengineering schemes is the importance of heterogeneous reactions in the photochemical ozone balance with larger stratospheric sulfate abundance, resulting in increased ozone depletion in mid- and high latitudes. This reduces the net transport of stratospheric ozone into the troposphere and thus is a key driver of the overall decrease in surface ozone. At the same time, the change in stratospheric ozone alters the tropospheric photochemical environment due to enhanced ultraviolet radiation. A shared factor among both SRM scenarios is decreased chemical ozone loss due to reduced tropospheric humidity. Under insolation reduction, this is the dominant factor giving rise to the global surface ozone increase. Regionally, both surface ozone increases and decreases are found for both scenarios; that is, SRM would affect regions of the world differently in terms of air pollution. In conclusion

Lagrangian Transport Calculations Using UARS Data. Part 2; Ozone

Science.gov (United States)

Manney, Gloria L.; Zurek, R. W.; Froidevaux, L.; Waters, J. W.; ONeill, A.; Swinbank, R.

1995-01-01

Trajectory calculations are used to examine ozone transport in the polar winter stratosphere during periods of the Upper Atmosphere Research Satellite (UARS) observations. The value of these calculations for determining mass transport was demonstrated previously using UARS observations of long-lived tracers, In the middle stratosphere, the overall ozone behavior observed by the Microwave Limb Sounder in the polar vortex is reproduced by this purely dynamical model. Calculations show the evolution of ozone in the lower stratosphere during early winter to be dominated by dynamics in December 1992 in the Arctic. Calculations for June 1992 in the Antarctic show evidence of chemical ozone destruction and indicate that approx. 50% of the chemical destruction may be masked by dynamical effects, mainly diabatic descent, which bring higher ozone into the lower-stratospheric vortex. Estimating differences between calculated and observed fields suggests that dynamical changes masked approx. 20% - 35% of chemical ozone loss during late February and early March 1993 in the Arctic. In the Antarctic late winter, in late August and early September 1992, below approx. 520 K, the evolution of vortex-averaged ozone is entirely dominated by chemical effects; above this level, however, chemical ozone depletion can be partially or completely masked by dynamical effects. Our calculations for 1992 showed that chemical loss was nearly completely compensated by increases due to diabatic descent at 655 K.

Effects of Volcanic Eruptions on Stratospheric Ozone Recovery

Science.gov (United States)

Rosenfield, Joan E.

2002-01-01

The effects of the stratospheric sulfate aerosol layer associated with the Mt. Pinatubo volcano and future volcanic eruptions on the recovery of the ozone layer is studied with an interactive two-dimensional photochemical model. The time varying chlorine loading and the stratospheric cooling due to increasing carbon dioxide have been taken into account. The computed ozone and temperature changes associated with the Mt. Pinatubo eruption in 1991 agree well with observations. Long model runs out to the year 2050 have been carried out, in which volcanoes having the characteristics of the Mount Pinatubo volcano were erupted in the model at 10-year intervals starting in the year 2010. Compared to a non-volcanic run using background aerosol loading, transient reductions of globally averaged column ozone of 2-3 percent were computed as a result of each of these eruptions, with the ozone recovering to that computed for the non-volcanic case in about 5 years after the eruption. Computed springtime Arctic column ozone losses of from 10 to 18 percent also recovered to the non-volcanic case within 5 years. These results suggest that the long-term recovery of ozone would not be strongly affected by infrequent volcanic eruptions with a sulfur loading approximating Mt. Pinatubo. Sensitivity studies in which the Arctic lower stratosphere was forced to be 4 K and 10 K colder resulted in transient ozone losses of which also recovered to the non-volcanic case in 5 years. A case in which a volcano five times Mt. Pinatubo was erupted in the year 2010 led to maximum springtime column ozone losses of 45 percent which took 10 years to recover to the background case. Finally, in order to simulate a situation in which frequent smaller volcanic eruptions result in increasing the background sulfate loading, a simulation was made in which the background aerosol was increased by 10 percent per year. This resulted in a delay of the recovery of column ozone to 1980 values of more than 10 years.

Ground-level ozone in China: Distribution and effects on crop yields

International Nuclear Information System (INIS)

Wang Xiaoke; Manning, William; Feng Zongwei; Zhu Yongguan

2007-01-01

Rapid economic development and an increasing demand for food in China have drawn attention to the role of ozone at pollution levels on crop yields. Some assessments of ozone effects on crop yields have been carried out in China. Determination of ozone distribution by geographical location and resulting crop loss estimations have been made by Chinese investigators and others from abroad. It is evident that surface level ozone levels in China exceed critical levels for occurrence of crop losses. Current levels of information from ozone dose/response studies are limited. Given the size of China, existing ozone monitoring sites are too few to provide enough data to scale ozone distribution to a national level. There are large uncertainties in the database for ozone effects on crop loss and for ozone distribution. Considerable research needs to be done to allow accurate estimation of crop losses caused by ozone in China. - More research is needed to reliably estimate ozone caused crop losses in China

Ozone's impact on public health: Contributions from indoor exposures to ozone and products of ozone-initiated chemistry

DEFF Research Database (Denmark)

Weschler, Charles J.

2006-01-01

OBJECTIVES: The associations between ozone concentrations measured outdoors and both morbidity and mortality may be partially due to indoor exposures to ozone and ozone-initiated oxidation products. In this article I examine the contributions of such indoor exposures to overall ozone-related heal...

Global tropospheric ozone modeling: Quantifying errors due to grid resolution

Science.gov (United States)

Wild, Oliver; Prather, Michael J.

2006-06-01

Ozone production in global chemical models is dependent on model resolution because ozone chemistry is inherently nonlinear, the timescales for chemical production are short, and precursors are artificially distributed over the spatial scale of the model grid. In this study we examine the sensitivity of ozone, its precursors, and its production to resolution by running a global chemical transport model at four different resolutions between T21 (5.6° × 5.6°) and T106 (1.1° × 1.1°) and by quantifying the errors in regional and global budgets. The sensitivity to vertical mixing through the parameterization of boundary layer turbulence is also examined. We find less ozone production in the boundary layer at higher resolution, consistent with slower chemical production in polluted emission regions and greater export of precursors. Agreement with ozonesonde and aircraft measurements made during the NASA TRACE-P campaign over the western Pacific in spring 2001 is consistently better at higher resolution. We demonstrate that the numerical errors in transport processes on a given resolution converge geometrically for a tracer at successively higher resolutions. The convergence in ozone production on progressing from T21 to T42, T63, and T106 resolution is likewise monotonic but indicates that there are still large errors at 120 km scales, suggesting that T106 resolution is too coarse to resolve regional ozone production. Diagnosing the ozone production and precursor transport that follow a short pulse of emissions over east Asia in springtime allows us to quantify the impacts of resolution on both regional and global ozone. Production close to continental emission regions is overestimated by 27% at T21 resolution, by 13% at T42 resolution, and by 5% at T106 resolution. However, subsequent ozone production in the free troposphere is not greatly affected. We find that the export of short-lived precursors such as NOx by convection is overestimated at coarse resolution.

Investigating Dry Deposition of Ozone to Vegetation

Science.gov (United States)

Silva, Sam J.; Heald, Colette L.

2018-01-01

Atmospheric ozone loss through dry deposition to vegetation is a critically important process for both air quality and ecosystem health. The majority of atmospheric chemistry models calculate dry deposition using a resistance-in-series parameterization by Wesely (1989), which is dependent on many environmental variables and lookup table values. The uncertainties contained within this parameterization have not been fully explored, ultimately challenging our ability to understand global scale biosphere-atmosphere interactions. In this work, we evaluate the GEOS-Chem model simulation of ozone dry deposition using a globally distributed suite of observations. We find that simulated daytime deposition velocities generally reproduce the magnitude of observations to within a factor of 1.4. When correctly accounting for differences in land class between the observations and model, these biases improve, most substantially over the grasses and shrubs land class. These biases do not impact the global ozone burden substantially; however, they do lead to local absolute changes of up to 4 ppbv and relative changes of 15% in summer surface concentrations. We use MERRA meteorology from 1979 to 2008 to assess that the interannual variability in simulated annual mean ozone dry deposition due to model input meteorology is small (generally less than 5% over vegetated surfaces). Sensitivity experiments indicate that the simulation is most sensitive to the stomatal and ground surface resistances, as well as leaf area index. To improve ozone dry deposition models, more measurements are necessary over rainforests and various crop types, alongside constraints on individual depositional pathways and other in-canopy ozone loss processes.

Ozone-UV-catalysis based advanced oxidation process for wastewater treatment.

Science.gov (United States)

Tichonovas, Martynas; Krugly, Edvinas; Jankunaite, Dalia; Racys, Viktoras; Martuzevicius, Dainius

2017-07-01

A bench-scale advanced oxidation (AO) reactor was investigated for the degradation of six pollutants (2-naphthol, phenol, oxalic acid, phthalate, methylene blue, and D-glucose) in a model wastewater at with the aim to test opportunities for the further upscale to industrial applications. Six experimental conditions were designed to completely examine the experimental reactor, including photolysis, photocatalysis, ozonation, photolytic ozonation, catalytic ozonation, and photocatalytic ozonation. The stationary catalyst construction was made from commercially available TiO 2 nanopowder by mounting it on a glass support and subsequently characterized for morphology (X-ray diffraction analysis and scanning electron microscopy) as well as durability. The ozone was generated in a dielectrical barrier discharge reactor using air as a source of oxygen. The degradation efficiency was estimated by the decrease in total organic carbon (TOC) concentration as well as toxicity using Daphnia magna, and degradation by-products by ultra-performance liquid chromatography-mass spectrometry. The photocatalytic ozonation was the most effective for the treatment of all model wastewater. The photocatalytic ozonation was most effective against ozonation and photolytic ozonation at tested pH values. A complete toxicity loss was obtained after the treatment using photocatalytic ozonation. The possible degradation pathway of the phthalate by oxidation was suggested based on aromatic ring opening reactions. The catalyst used at this experiment confirmed as a durable for continuous use with almost no loss of activity over time. The design of the reactor was found to be very effective for water treatment using photocatalytic ozonation. Such design has a high potential and can be further upscaled to industrial applications due to the simplicity and versatility of manufacturing and maintenance.

Multi-Model Simulations of Aerosol and Ozone Radiative Forcing Due to Anthropogenic Emission Changes During the Period 1990-2015

Science.gov (United States)

Myhre, Gunnar; Aas, Wenche; Ribu, Cherian; Collins, William; Faluvegi, Gregory S.; Flanner, Mark; Forster, Piers; Hodnebrog, Oivind; Klimont, Zbigniew; Lund, Marianne T.

2017-01-01

Over the past few decades, the geographical distribution of emissions of substances that alter the atmospheric energy balance has changed due to economic growth and air pollution regulations. Here, we show the resulting changes to aerosol and ozone abundances and their radiative forcing using recently updated emission data for the period 1990-2015, as simulated by seven global atmospheric composition models. The models broadly reproduce large-scale changes in surface aerosol and ozone based on observations (e.g. 1 to 3 percent per year in aerosols over the USA and Europe). The global mean radiative forcing due to ozone and aerosol changes over the 1990-2015 period increased by 0.17 plus or minus 0.08 watts per square meter, with approximately one-third due to ozone. This increase is more strongly positive than that reported in IPCC AR5 (Intergovernmental Panel on Climate Change Fifth Assessment Report). The main reasons for the increased positive radiative forcing of aerosols over this period are the substantial reduction of global mean SO2 emissions, which is stronger in the new emission inventory compared to that used in the IPCC analysis, and higher black carbon emissions.

Stomatal uptake and stomatal deposition of ozone in isoprene and monoterpene emitting plants.

Science.gov (United States)

Fares, S; Loreto, F; Kleist, E; Wildt, J

2008-01-01

Volatile isoprenoids were reported to protect plants against ozone. To understand whether this could be the result of a direct scavenging of ozone by these molecules, the stomatal and non-stomatal uptake of ozone was estimated in plants emitting isoprene or monoterpenes. Ozone uptake by holm oak (Quercus ilex, a monoterpene emitter) and black poplar (Populus nigra, an isoprene emitter) was studied in whole plant enclosures (continuously stirred tank reactors, CSTR). The ozone uptake by plants was estimated measuring ozone concentration at the inlet and outlet of the reactors, after correcting for the uptake of the enclosure materials. Destruction of ozone at the cuticle or at the plant stems was found to be negligible compared to the ozone uptake through the stomata. For both plant species, a relationship between stomatal conductance and ozone uptake was found. For the poplar, the measured ozone losses were explained by the uptake of ozone through the stomata only, and ozone destruction by gas phase reactions with isoprene was negligible. For the oak, gas phase reactions of ozone with the monoterpenes emitted by the plants contributed significantly to ozone destruction. This was confirmed by two different experiments showing a) that in cases of high stomatal conductance but under low CO(2) concentration, a reduction of monoterpene emission was still associated with reduced O(3) uptake; and b) that ozone losses due to the gas phase reactions only can be measured when using the exhaust from a plant chamber to determine the gas phase reactivity in an empty reaction chamber. Monoterpenes can therefore relevantly scavenge ozone at leaf level contributing to protection against ozone.

Global tropospheric ozone modeling: Quantifying errors due to grid resolution

OpenAIRE

Wild, Oliver; Prather, Michael J

2006-01-01

Ozone production in global chemical models is dependent on model resolution because ozone chemistry is inherently nonlinear, the timescales for chemical production are short, and precursors are artificially distributed over the spatial scale of the model grid. In this study we examine the sensitivity of ozone, its precursors, and its production to resolution by running a global chemical transport model at four different resolutions between T21 (5.6° × 5.6°) and T106 (1.1° × 1.1°) and by quant...

Ozone pollution and ozone biomonitoring in European cities Part II. Ozone-induced plant injury and its relationship with descriptors of ozone pollution

DEFF Research Database (Denmark)

Klumpp, A.; Ansel, W.; Klumpp, G.

2006-01-01

within local networks were relatively small, but seasonal and inter-annual differences were strong due to the variability of meteorological conditions and related ozone concentrations. The 2001 data revealed a significant relationship between foliar injury degree and various descriptors of ozone...... pollution such as mean value, AOT20 and AOT40. Examining individual sites of the local monitoring networks separately, however, yielded noticeable differences. Some sites showed no association between ozone pollution and ozone-induced effects, whereas others featured almost linear relationships...

Ozone fumigation under dark/light conditions of Norway Spruce (Picea Abies) and Scots Pine (Pinus Sylvestris)

Science.gov (United States)

Canaval, Eva; Jud, Werner; Hansel, Armin

2015-04-01

Norway Spruce (Picea abies) and Scots Pine (Pinus sylvestris) represent dominating tree species in the northern hemisphere. Thus, the understanding of their ozone sensitivity in the light of the expected increasing ozone levels in the future is of great importance. In our experiments we investigated the emissions of volatile organic compounds (VOCs) of 3-4 year old Norway Spruce and Scots Pine seedlings under ozone fumigation (50-150 ppbv) and dark/light conditions. For the experiments the plants were placed in a setup with inert materials including a glass cuvette equipped with a turbulent air inlet and sensors for monitoring a large range of meteorological parameters. Typical conditions were 20-25°C and a relative humidity of 70-90 % for both plant species. A fast gas exchange rate was used to minimize reactions of ozone in the gas phase. A Switchable-Reagent-Ion-Time-of-Flight-MS (SRI-ToF-MS) was used to analyze the VOCs at the cuvette outlet in real-time during changing ozone and light levels. The use of H3O+ and NO+ as reagent ions allows the separation of certain isomers (e.g. aldehydes and ketones) due to different reaction pathways depending on the functional groups of the molecules. Within the Picea abies experiments the ozone loss, defined as the difference of the ozone concentration between cuvette inlet and outlet, remained nearly constant at the transition from dark to light. This indicates that a major part of the supplied ozone is depleted non-stomatally. In contrast the ozone loss increased by 50 % at the transition from dark to light conditions within Pinus sylvestris experiments. In this case the stomata represent the dominant loss channel. Since maximally 0.1% of the ozone loss could be explained by gas phase reactions with monoterpenes and sesquiterpenes, we suggest that ozone reactions on the surface of Picea abies represent the major sink in this case and lead to an light-independent ozone loss. This is supported by the fact that we detected

Ozone Production in Global Tropospheric Models: Quantifying Errors due to Grid Resolution

Science.gov (United States)

Wild, O.; Prather, M. J.

2005-12-01

Ozone production in global chemical models is dependent on model resolution because ozone chemistry is inherently nonlinear, the timescales for chemical production are short, and precursors are artificially distributed over the spatial scale of the model grid. In this study we examine the sensitivity of ozone, its precursors, and its production to resolution by running a global chemical transport model at four different resolutions between T21 (5.6° × 5.6°) and T106 (1.1° × 1.1°) and by quantifying the errors in regional and global budgets. The sensitivity to vertical mixing through the parameterization of boundary layer turbulence is also examined. We find less ozone production in the boundary layer at higher resolution, consistent with slower chemical production in polluted emission regions and greater export of precursors. Agreement with ozonesonde and aircraft measurements made during the NASA TRACE-P campaign over the Western Pacific in spring 2001 is consistently better at higher resolution. We demonstrate that the numerical errors in transport processes at a given resolution converge geometrically for a tracer at successively higher resolutions. The convergence in ozone production on progressing from T21 to T42, T63 and T106 resolution is likewise monotonic but still indicates large errors at 120~km scales, suggesting that T106 resolution is still too coarse to resolve regional ozone production. Diagnosing the ozone production and precursor transport that follow a short pulse of emissions over East Asia in springtime allows us to quantify the impacts of resolution on both regional and global ozone. Production close to continental emission regions is overestimated by 27% at T21 resolution, by 13% at T42 resolution, and by 5% at T106 resolution, but subsequent ozone production in the free troposphere is less significantly affected.

Issues in Stratospheric Ozone Depletion.

Science.gov (United States)

Lloyd, Steven Andrew

Following the announcement of the discovery of the Antarctic ozone hole in 1985 there have arisen a multitude of questions pertaining to the nature and consequences of polar ozone depletion. This thesis addresses several of these specific questions, using both computer models of chemical kinetics and the Earth's radiation field as well as laboratory kinetic experiments. A coupled chemical kinetic-radiative numerical model was developed to assist in the analysis of in situ field measurements of several radical and neutral species in the polar and mid-latitude lower stratosphere. Modeling was used in the analysis of enhanced polar ClO, mid-latitude diurnal variation of ClO, and simultaneous measurements of OH, HO_2, H_2 O and O_3. Most importantly, such modeling was instrumental in establishing the link between the observed ClO and BrO concentrations in the Antarctic polar vortex and the observed rate of ozone depletion. The principal medical concern of stratospheric ozone depletion is that ozone loss will lead to the enhancement of ground-level UV-B radiation. Global ozone climatology (40^circS to 50^ circN latitude) was incorporated into a radiation field model to calculate the biologically accumulated dosage (BAD) of UV-B radiation, integrated over days, months, and years. The slope of the annual BAD as a function of latitude was found to correspond to epidemiological data for non-melanoma skin cancers for 30^circ -50^circN. Various ozone loss scenarios were investigated. It was found that a small ozone loss in the tropics can provide as much additional biologically effective UV-B as a much larger ozone loss at higher latitudes. Also, for ozone depletions of > 5%, the BAD of UV-B increases exponentially with decreasing ozone levels. An important key player in determining whether polar ozone depletion can propagate into the populated mid-latitudes is chlorine nitrate, ClONO_2 . As yet this molecule is only indirectly accounted for in computer models and field

Ozone and water vapour in the austral polar stratospheric vortex and sub-vortex

Directory of Open Access Journals (Sweden)

E. Peet

2004-12-01

Full Text Available In-situ measurements of ozone and water vapour, in the Antarctic lower stratosphere, were made as part of the APE-GAIA mission in September and October 1999. The measurements show a distinct difference above and below the 415K isentrope. Above 415K, the chemically perturbed region of low ozone and water vapour is clearly evident. Below 415K, but still above the tropopause, no sharp meridional gradients in ozone and water vapour were observed. The observations are consistent with analyses of potential vorticity from the European Centre for Medium Range Weather Forecasting, which show smaller radial gradients at 380K than at 450K potential temperature. Ozone loss in the chemically perturbed region above 415K averages 5ppbv per day for mid-September to mid-October. Apparent ozone loss rates in the sub-vortex region are greater, at 7ppbv per day. The data support, therefore, the existence of a sub-vortex region in which meridional transport is more efficient than in the vortex above. The low ozone mixing ratios in the sub-vortex region may be due to in-situ chemical destruction of ozone or transport of ozone-poor air out of the bottom of the vortex. The aircraft data we use cannot distinguish between these two processes. Key words. Meteorology and atmospheric dynamics polar meteorology – Atmospheric composition and structure (middle atmosphere–composition and chemistry

Interaction of ozone with plastic and metallic materials in a dynamic flow system

Energy Technology Data Exchange (ETDEWEB)

Altshuller, A P; Wartburg, A F

1961-01-01

The loss of ozone in the p.p.h.m. range after passing through or over various plastic and metallic substances has been investigated. The materials used include Teflon, glass, stainless steel, aluminium, polyethylene and polyvinyl tubing, Mylar film, and aluminium foil. Unused Teflon passes ozone without loss. Glass tubing, after a short exposure to ozone, passes ozone without loss. Stainless steel tubing, aluminum tubing or foil and Mylar film must be exposed to ozone in the p.p.h.m. range for several hours before 90% or more of the ozone initially present can be passed through or over these materials. More rapid conditioning to ozone can be achieved by several five to fifteen-minute exposures to about 10 p.p.m. of ozone. Polyethylene and Nalgon tubing even after many hours of exposure to ozone will pass only 75 to 80% of the ozone initially present in the gas stream. Some types of polyvinyl tubing are unsatisfactory for use with ozone irrespective of the amount of exposure to ozone. Flowrates below 1000 c/sup 3//min. will increase losses of ozone. Except for Teflon and glass, materials should not be used in ozone analysis under any circumstances at low flowrates until they are thoroughly conditioned. Results obtained with stainless steel, aluminium and polyethylene indicate that conditioning to ozone once obtained will persist for at least two weeks.

Nicotiana tabacum as model for ozone - plant surface reactions

Science.gov (United States)

Jud, Werner; Fischer, Lukas; Wohlfahrt, Georg; Tissier, Alain; Canaval, Eva; Hansel, Armin

2015-04-01

Elevated tropospheric ozone concentrations are considered a toxic threat to plants, responsible for global crop losses with associated economic costs of several billion dollars per year. The ensuing injuries have been related to the uptake of ozone through the stomatal pores and oxidative effects damaging the internal leaf tissue. A striking question of current research is the environment and plant specific partitioning of ozone loss between gas phase, stomatal or plant surface sink terms. Here we show results from ozone fumigation experiments using various Nicotiana Tabacum varieties, whose surfaces are covered with different amounts of unsaturated diterpenoids exuded by their glandular trichomes. Exposure to elevated ozone levels (50 to 150 ppbv) for 5 to 15 hours in an exceptionally clean cuvette system did neither result in a reduction of photosynthesis nor caused any visible leaf damage. Both these ozone induced stress effects have been observed previously in ozone fumigation experiments with the ozone sensitive tobacco line Bel-W3. In our case ozone fumigation was accompanied by a continuous release of oxygenated volatile organic compounds, which could be clearly associated to their condensed phase precursors for the first time. Gas phase reactions of ozone were avoided by choosing a high enough gas exchange rate of the plant cuvette system. In the case of the Ambalema variety, that is known to exude only the diterpenoid cis-abienol, ozone fumigation experiments yield the volatiles formaldehyde and methyl vinyl ketone (MVK). The latter could be unequivocally separated from isomeric methacrolein (MACR) by the aid of a Selective Reagent Ion Time-of-Flight Mass Spectrometer (SRI-ToF-MS), which was switched every six minutes from H3O+ to NO+ primary ion mode and vice versa. Consistent with the picture of an ozone protection mechanism caused by reactive diterpenoids at the leaf surface are the results from dark-light experiments. The ozone loss obtained from the

Mortality tradeoff between air quality and skin cancer from changes in stratospheric ozone

Science.gov (United States)

Eastham, Sebastian D.; Keith, David W.; Barrett, Steven R. H.

2018-03-01

Skin cancer mortality resulting from stratospheric ozone depletion has been widely studied. Similarly, there is a deep body of literature on surface ozone and its health impacts, with modeling and observational studies demonstrating that surface ozone concentrations can be increased when stratospheric air mixes to the Earth’s surface. We offer the first quantitative estimate of the trade-off between these two effects, comparing surface air quality benefits and UV-related harms from stratospheric ozone depletion. Applying an idealized ozone loss term in the stratosphere of a chemistry-transport model for modern-day conditions, we find that each Dobson unit of stratospheric ozone depletion results in a net decrease in the global annual mortality rate of ~40 premature deaths per billion population (d/bn/DU). The impacts are spatially heterogeneous in sign and magnitude, composed of a reduction in premature mortality rate due to ozone exposure of ~80 d/bn/DU concentrated in Southeast Asia, and an increase in skin cancer mortality rate of ~40 d/bn/DU, mostly in Western Europe. This is the first study to quantify air quality benefits of stratospheric ozone depletion, and the first to find that marginal decreases in stratospheric ozone around modern-day values could result in a net reduction in global mortality due to competing health impact pathways. This result, which is subject to significant methodological uncertainty, highlights the need to understand the health and environmental trade-offs involved in policy decisions regarding anthropogenic influences on ozone chemistry over the 21st century.

Aromatic VOCs global influence in the ozone production

Science.gov (United States)

Cabrera-Perez, David; Pozzer, Andrea

2016-04-01

Aromatic hydrocarbons are a subgroup of Volatile Organic Compounds (VOCs) of special interest in the atmosphere of urban and semi-urban areas. Aromatics form a high fraction of VOCs, are highly reactive and upon oxidation they are an important source of ozone. These group of VOCs are released to the atmosphere by processes related to biomass burning and fossil fuel consumption, while they are removed from the atmosphere primarily by OH reaction and by dry deposition. In addition, a branch of aromatics (ortho-nitrophenols) produce HONO upon photolysis, which is responsible of certain amount of the OH recycling. Despite their importance in the atmosphere in anthropogenic polluted areas, the influence of aromatics in the ozone production remains largely unknown. This is of particular relevance, being ozone a pollutant with severe side effects on air quality, health and climate. In this work the atmospheric impacts at global scale of the most emitted aromatic VOCs in the gas phase (benzene, toluene, xylenes, ethylbenzene, styrene, phenol, benzaldehyde and trimethylbenzenes) are analysed and assessed. Specifically, the impact on ozone due to aromatic oxidation is estimated, as this is of great interest in large urban areas and can be helpful for developing air pollution control strategies. Further targets are the quantification of the NOx loss and the OH recycling due to aromatic oxidation. In order to investigate these processes, two simulations were performed with the numerical chemistry and climate simulation ECHAM/MESSy Atmospheric Chemistry (EMAC) model. The simulations compare two cases, one with ozone concentrations when aromatics are present or the second one when they are missing. Finally, model simulated ozone is compared against a global set of observations in order to better constrain the model accuracy.

Ozone decomposition kinetics on alumina: effects of ozone partial pressure, relative humidity and repeated oxidation cycles

Directory of Open Access Journals (Sweden)

R. C. Sullivan

2004-01-01

Full Text Available The room temperature kinetics of gas-phase ozone loss via heterogeneous interactions with thin alumina films has been studied in real-time using 254nm absorption spectroscopy to monitor ozone concentrations. The films were prepared from dispersions of fine alumina powder in methanol and their surface areas were determined by an in situ procedure using adsorption of krypton at 77K. The alumina was found to lose reactivity with increasing ozone exposure. However, some of the lost reactivity could be recovered over timescales of days in an environment free of water, ozone and carbon dioxide. From multiple exposures of ozone to the same film, it was found that the number of active sites is large, greater than 1.4x1014 active sites per cm2 of surface area or comparable to the total number of surface sites. The films maintain some reactivity at this point, which is consistent with there being some degree of active site regeneration during the experiment and with ozone loss being catalytic to some degree. The initial uptake coefficients on fresh films were found to be inversely dependent on the ozone concentration, varying from roughly 10-6 for ozone concentrations of 1014 molecules/cm3 to 10-5 at 1013 molecules/cm3. The initial uptake coefficients were not dependent on the relative humidity, up to 75%, within the precision of the experiment. The reaction mechanism is discussed, as well as the implications these results have for assessing the effect of mineral dust on atmospheric oxidant levels.

Evidence for a continuous decline in lower stratospheric ozone offsetting ozone layer recovery

Science.gov (United States)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stübi, Rene; Stenke, Andrea; Anderson, John; Bourassa, Adam; Davis, Sean M.; Degenstein, Doug; Frith, Stacey; Froidevaux, Lucien; Roth, Chris; Sofieva, Viktoria; Wang, Ray; Wild, Jeannette; Yu, Pengfei; Ziemke, Jerald R.; Rozanov, Eugene V.

2018-02-01

Ozone forms in the Earth's atmosphere from the photodissociation of molecular oxygen, primarily in the tropical stratosphere. It is then transported to the extratropics by the Brewer-Dobson circulation (BDC), forming a protective ozone layer around the globe. Human emissions of halogen-containing ozone-depleting substances (hODSs) led to a decline in stratospheric ozone until they were banned by the Montreal Protocol, and since 1998 ozone in the upper stratosphere is rising again, likely the recovery from halogen-induced losses. Total column measurements of ozone between the Earth's surface and the top of the atmosphere indicate that the ozone layer has stopped declining across the globe, but no clear increase has been observed at latitudes between 60° S and 60° N outside the polar regions (60-90°). Here we report evidence from multiple satellite measurements that ozone in the lower stratosphere between 60° S and 60° N has indeed continued to decline since 1998. We find that, even though upper stratospheric ozone is recovering, the continuing downward trend in the lower stratosphere prevails, resulting in a downward trend in stratospheric column ozone between 60° S and 60° N. We find that total column ozone between 60° S and 60° N appears not to have decreased only because of increases in tropospheric column ozone that compensate for the stratospheric decreases. The reasons for the continued reduction of lower stratospheric ozone are not clear; models do not reproduce these trends, and thus the causes now urgently need to be established.

Evidence for a Continuous Decline in Lower Stratospheric Ozone Offsetting Ozone Layer Recovery

Science.gov (United States)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stuebi, Rene; Stenke, Andrea; Anderson, John;

Spatio-temporal observations of the tertiary ozone maximum

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V. F. Sofieva

2009-07-01

Full Text Available We present spatio-temporal distributions of the tertiary ozone maximum (TOM, based on GOMOS (Global Ozone Monitoring by Occultation of Stars ozone measurements in 2002–2006. The tertiary ozone maximum is typically observed in the high-latitude winter mesosphere at an altitude of ~72 km. Although the explanation for this phenomenon has been found recently – low concentrations of odd-hydrogen cause the subsequent decrease in odd-oxygen losses – models have had significant deviations from existing observations until recently. Good coverage of polar night regions by GOMOS data has allowed for the first time to obtain spatial and temporal observational distributions of night-time ozone mixing ratio in the mesosphere.

The distributions obtained from GOMOS data have specific features, which are variable from year to year. In particular, due to a long lifetime of ozone in polar night conditions, the downward transport of polar air by the meridional circulation is clearly observed in the tertiary ozone maximum time series. Although the maximum tertiary ozone mixing ratio is achieved close to the polar night terminator (as predicted by the theory, TOM can be observed also at very high latitudes, not only in the beginning and at the end, but also in the middle of winter. We have compared the observational spatio-temporal distributions of the tertiary ozone maximum with that obtained using WACCM (Whole Atmosphere Community Climate Model and found that the specific features are reproduced satisfactorily by the model.

Since ozone in the mesosphere is very sensitive to HO_x concentrations, energetic particle precipitation can significantly modify the shape of the ozone profiles. In particular, GOMOS observations have shown that the tertiary ozone maximum was temporarily destroyed during the January 2005 and December 2006 solar proton events as a result of the HO_x enhancement from the increased ionization.

ER-2 #809 on the SAGE III Ozone Loss and Validation Experiment (SOLVE) with pilot Dee Porter prepari

Science.gov (United States)

2000-01-01

Lockheed Martin pilot Dee Porter climbs up the ladder wearing a heavy tan pressure suit, preparing to board NASA ER-2 #809 at Kiruna, Sweden, for the third flight in the SAGE III Ozone Loss and Validation Experiment. Assisting him is Jim Sokolik, a Lockheed Martin life support technician. Number 809, one of Dryden's two high-flying ER-2 Airborne Science aircraft, a civilian variant of Lockheed's U-2, and another NASA flying laboratory, Dryden's DC-8, were based north of the Arctic Circle in Kiruna, Sweden during the winter of 2000 to study ozone depletion as part of the SAGE III Ozone Loss and Validation Experiment (SOLVE). A large hangar built especially for research, 'Arena Arctica' housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. 'The collaborative campaign will provide an immense new body of information about the Arctic stratosphere,' said program scientist Dr. Michael Kurylo, NASA Headquarters. 'Our understanding of the Earth's ozone will be greatly enhanced by this research.' ER-2s bearing tail numbers 806 and 809 are used as airborne science platforms by NASA's Dryden Flight Research Center. The aircraft are platforms for a variety of high-altitude science missions flown over various parts of the world. They are also used for earth science and atmospheric sensor research and development, satellite calibration and data validation. The ER-2s are capable of carrying a maximum payload of 2,600 pounds of experiments in a nose bay, the main

Impacts of ozone on trees and crops

International Nuclear Information System (INIS)

Felzer, B.S.; Cronina, T.; Melillo, J.M.; Reilly, J.M.; Xiaodong, Wang

2007-01-01

In this review article, we explore how surface-level ozone affects trees and crops with special emphasis on consequences for productivity and carbon sequestration. Vegetation exposure to ozone reduces photosynthesis, growth, and other plant functions. Ozone formation in the atmosphere is a product of NO x , which are also a source of nitrogen deposition. Reduced carbon sequestration of temperate forests resulting from ozone is likely offset by increased carbon sequestration from nitrogen fertilization. However, since fertilized crop-lands are generally not nitrogen-limited, capping ozone-polluting substances in the USA, Europe, and China can reduce future crop yield loss substantially. (authors)

Ozone uptake, water loss and carbon exchange dynamics in annually drought-stressed Pinus ponderosa forests: measured trends and parameters for uptake modeling.

Science.gov (United States)

Panek, Jeanne A

2004-03-01

This paper describes 3 years of physiological measurements on ponderosa pine (Pinus ponderosa Dougl. ex Laws.) growing along an ozone concentration gradient in the Sierra Nevada, California, including variables necessary to parameterize, validate and modify photosynthesis and stomatal conductance algorithms used to estimate ozone uptake. At all sites, gas exchange was under tight stomatal control during the growing season. Stomatal conductance was strongly correlated with leaf water potential (R2=0.82), which decreased over the growing season with decreasing soil water content (R2=0.60). Ozone uptake, carbon uptake, and transpirational water loss closely followed the dynamics of stomatal conductance. Peak ozone and CO2 uptake occurred in early summer and declined progressively thereafter. As a result, periods of maximum ozone uptake did not correspond to periods of peak ozone concentration, underscoring the inappropriateness of using current metrics based on concentration (e.g., SUM0, W126 and AOT40) for assessing ozone exposure risk to plants in this climate region. Both Jmax (maximum CO2-saturated photosynthetic rate, limited by electron transport) and Vcmax (maximum rate of Rubisco-limited carboxylation) increased toward the middle of the growing season, then decreased in September. Intrinsic water-use efficiency rose with increasing drought stress, as expected. The ratio of Jmax to Vcmax was similar to literature values of 2.0. Nighttime respiration followed a Q10 of 2.0, but was significantly higher at the high-ozone site. Respiration rates decreased by the end of the summer as a result of decreased metabolic activity and carbon stores.

Plasmachemical and heterogeneous processes in ozonizers with oxygen activation by a dielectric barrier discharge

Energy Technology Data Exchange (ETDEWEB)

Mankelevich, Yu. A., E-mail: ymankelevich@mics.msu.su; Voronina, E. N.; Poroykov, A. Yu.; Rakhimov, T. V.; Voloshin, D. G.; Chukalovsky, A. A. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)

2016-10-15

Plasmachemical and heterogeneous processes of generation and loss of ozone in the atmosphericpressure dielectric barrier discharge in oxygen are studied theoretically. Plasmachemical and electronic kinetics in the stage of development and decay of a single plasma filament (microdischarge) are calculated numerically with and without allowance for the effects of ozone vibrational excitation and high initial ozone concentration. The developed analytical approach is applied to determine the output ozone concentration taking into account ozone heterogeneous losses on the Al{sub 2}O{sub 3} dielectric surface. Using the results of quantummechanical calculations by the method of density functional theory, a multistage catalytic mechanism of heterogeneous ozone loss based on the initial passivation of a pure Al{sub 2}O{sub 3} surface by ozone and the subsequent interaction of O{sub 3} molecules with the passivated surface is proposed. It is shown that the conversion reaction 2O{sub 3} → 3O{sub 2} of a gas-phase ozone molecule with a physically adsorbed ozone molecule can result in the saturation of the maximum achievable ozone concentration at high specific energy depositions, the nonstationarity of the output ozone concentration, and its dependence on the prehistory of ozonizer operation.

Unequivocal detection of ozone recovery in the Antarctic Ozone Hole through significant increases in atmospheric layers with minimum ozone

Science.gov (United States)

de Laat, Jos; van Weele, Michiel; van der A, Ronald

2015-04-01

An important new landmark in present day ozone research is presented through MLS satellite observations of significant ozone increases during the ozone hole season that are attributed unequivocally to declining ozone depleting substances. For many decades the Antarctic ozone hole has been the prime example of both the detrimental effects of human activities on our environment as well as how to construct effective and successful environmental policies. Nowadays atmospheric concentrations of ozone depleting substances are on the decline and first signs of recovery of stratospheric ozone and ozone in the Antarctic ozone hole have been observed. The claimed detection of significant recovery, however, is still subject of debate. In this talk we will discuss first current uncertainties in the assessment of ozone recovery in the Antarctic ozone hole by using multi-variate regression methods, and, secondly present an alternative approach to identify ozone hole recovery unequivocally. Even though multi-variate regression methods help to reduce uncertainties in estimates of ozone recovery, great care has to be taken in their application due to the existence of uncertainties and degrees of freedom in the choice of independent variables. We show that taking all uncertainties into account in the regressions the formal recovery of ozone in the Antarctic ozone hole cannot be established yet, though is likely before the end of the decade (before 2020). Rather than focusing on time and area averages of total ozone columns or ozone profiles, we argue that the time evolution of the probability distribution of vertically resolved ozone in the Antarctic ozone hole contains a better fingerprint for the detection of ozone recovery in the Antarctic ozone hole. The advantages of this method over more tradition methods of trend analyses based on spatio-temporal average ozone are discussed. The 10-year record of MLS satellite measurements of ozone in the Antarctic ozone hole shows a

1,2-Dichlorohexafluoro-Cyclobutane (1,2-c-C4F6Cl2, R-316c) a Potent Ozone Depleting Substance and Greenhouse Gas: Atmospheric Loss Processes, Lifetimes, and Ozone Depletion and Global Warming Potentials for the (E) and (Z) stereoisomers

Science.gov (United States)

Papadimitriou, Vassileios C.; McGillen, Max R.; Smith, Shona C.; Jubb, Aaron M.; Portmann, Robert W.; Hall, Bradley D.; Fleming, Eric L.; Jackman, Charles H.; Burkholder, James B.

2013-01-01

The atmospheric processing of (E)- and (Z)-1,2-dichlorohexafluorocyclobutane (1,2-c-C4F6Cl2, R-316c) was examined in this work as the ozone depleting (ODP) and global warming (GWP) potentials of this proposed replacement compound are presently unknown. The predominant atmospheric loss processes and infrared absorption spectra of the R-316c isomers were measured to provide a basis to evaluate their atmospheric lifetimes and, thus, ODPs and GWPs. UV absorption spectra were measured between 184.95 to 230 nm at temperatures between 214 and 296 K and a parametrization for use in atmospheric modeling is presented. The Cl atom quantum yield in the 193 nm photolysis of R- 316c was measured to be 1.90 +/- 0.27. Hexafluorocyclobutene (c-C4F6) was determined to be a photolysis co-product with molar yields of 0.7 and 1.0 (+/-10%) for (E)- and (Z)-R-316c, respectively. The 296 K total rate coefficient for the O(1D) + R-316c reaction, i.e., O(1D) loss, was measured to be (1.56 +/- 0.11) × 10(exp -10)cu cm/ molecule/s and the reactive rate coefficient, i.e., R-316c loss, was measured to be (1.36 +/- 0.20) × 10(exp -10)cu cm/molecule/s corresponding to a approx. 88% reactive yield. Rate coefficient upper-limits for the OH and O3 reaction with R-316c were determined to be model to be 74.6 +/- 3 and 114.1 +/-10 years, respectively, where the estimated uncertainties are due solely to the uncertainty in the UV absorption spectra. Stratospheric photolysis is the predominant atmospheric loss process for both isomers with the O(1D) reaction making a minor, approx. 2% for the (E) isomer and 7% for the (Z) isomer, contribution to the total atmospheric loss. Ozone depletion potentials for (E)- and (Z)-R-316c were calculated using the 2-D model to be 0.46 and 0.54, respectively. Infrared absorption spectra for (E)- and (Z)-R-316c were measured at 296 K and used to estimate their radiative efficiencies (REs) and GWPs; 100-year time-horizon GWPs of 4160 and 5400 were obtained for (E)- and (Z

An investigation into the causes of stratospheric ozone loss in the southern Australasian region

Science.gov (United States)

Lehmann, P.; Karoly, D. J.; Newmann, P. A.; Clarkson, T. S.; Matthews, W. A.

1992-07-01

Measurements of total ozone at Macquarie Island (55 deg S, 159 deg E) reveal statistically significant reductions of approximately twelve percent during July to September when comparing the mean levels for 1987-90 with those in the seventies. In order to investigate the possibility that these ozone changes may not be a result of dynamic variability of the stratosphere, a simple linear model of ozone was created from statistical analysis of tropopause height and isentropic transient eddy heat flux, which were assumed representative of the dominant dynamic influences. Comparison of measured and modeled ozone indicates that the recent downward trend in ozone at Macquarie Island is not related to stratospheric dynamic variability and therefore suggests another mechanism, possibly changes in photochemical destruction of ozone.

A cloud-ozone data product from Aura OMI and MLS satellite measurements

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J. R. Ziemke

2017-11-01

Full Text Available Ozone within deep convective clouds is controlled by several factors involving photochemical reactions and transport. Gas-phase photochemical reactions and heterogeneous surface chemical reactions involving ice, water particles, and aerosols inside the clouds all contribute to the distribution and net production and loss of ozone. Ozone in clouds is also dependent on convective transport that carries low-troposphere/boundary-layer ozone and ozone precursors upward into the clouds. Characterizing ozone in thick clouds is an important step for quantifying relationships of ozone with tropospheric H2O, OH production, and cloud microphysics/transport properties. Although measuring ozone in deep convective clouds from either aircraft or balloon ozonesondes is largely impossible due to extreme meteorological conditions associated with these clouds, it is possible to estimate ozone in thick clouds using backscattered solar UV radiation measured by satellite instruments. Our study combines Aura Ozone Monitoring Instrument (OMI and Microwave Limb Sounder (MLS satellite measurements to generate a new research product of monthly-mean ozone concentrations in deep convective clouds between 30° S and 30° N for October 2004–April 2016. These measurements represent mean ozone concentration primarily in the upper levels of thick clouds and reveal key features of cloud ozone including: persistent low ozone concentrations in the tropical Pacific of  ∼ 10 ppbv or less; concentrations of up to 60 pphv or greater over landmass regions of South America, southern Africa, Australia, and India/east Asia; connections with tropical ENSO events; and intraseasonal/Madden–Julian oscillation variability. Analysis of OMI aerosol measurements suggests a cause and effect relation between boundary-layer pollution and elevated ozone inside thick clouds over landmass regions including southern Africa and India/east Asia.

Economic losses due to important diseases of bovines in central India

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Dhananjay Singh

2014-08-01

Full Text Available Aim: To analyze the factors associated with morbidity and mortality rates as well as to evaluate economic losses due to important diseases of bovines, viz. mastitis, HS and surra in Purvanchal Region of Uttar Pradesh. Materials and Methods: A sample of 300 livestock owners were selected from each of five divisions of Purvanchal region of the state of Uttar Pradesh using multistage stratified sampling with simple random sampling without replacement at village level. The morbidity, mortality and case fatality rates due to different diseases were determined using standard statistical indices. Association between cattle morbidity and mortality rates and different factors was calculated by χ2 Test. The total economic loss due to diseases in bovines was worked out as sum of mortality loss, loss in milk yield and cost of treatment of affected animals. Results: The overall morbidity rates of mastitis, HS and surra in cattle and buffaloes were 15.5%, 7.1% and 5.3%, respectively. The mortality and case fatality due to HS was found higher in the young calves as compared to the adults in case of both buffaloes and cattle. Mortality and case fatality due to surra was greater in the adult animals as compared to the younger ones in case of both buffaloes and cattle. Total losses due to mastitis per lactation in ND cow, CB cow and buffalo were INR 868.34, INR 1, 314.10 and INR 1, 272.36, respectively. Total losses due to HS per animal in ND cows, CB cows and buffaloes were INR 2, 355.78, INR 3, 228.52 and INR 4, 262.57, respectively. Total losses due to surra per animal in ND cow, CB cow and buffalo were INR 3, 328.18, INR 6, 193 and INR 9, 872.33, respectively. Conclusion: The study thus revealed significant losses due to diseases in large ruminants on. There is thus ample scope for preventive measures to control the disease bovines.

Temperature effects on loss of prestress due to relaxation of steel

International Nuclear Information System (INIS)

Appa Rao, G.; Yamini Sreevalli, I.; Meher Prasad, A.; Reddy, G.R.; Prabhakar, G.

2007-01-01

Prestressed concrete is used in general civil engineering applications and in nuclear power plants for a number of structures such as containments, reactor pressure vessels, missile shield members, reactor cavity walls etc. Loss of prestress in containment structures is a serious concern for the longevity rather than serviceability. Loss of prestress higher than the initially designed values has been reported by various agencies at a number of nuclear power plants with prestressed concrete containment structures. At present the codes specify the prestress losses in Nuclear Power Plant Containment (NPPC) structures for 50 years. However there is a continuous effort to improve the life of NPPC particularly for a design life of 100 years. The long-term losses are mainly due to relaxation of prestressing cables, creep and shrinkage of concrete. The loss of prestress due to relaxation of prestressing cables is considered to be severe due to temperature effects. In this paper an effort has been made to understand the loss of prestress due to relaxation of steel at different temperatures namely 20 degC, 25 degC, 30 degC, 35 degC, 40 degC and 45 degC and the results up to 1000 hrs to estimate the losses over longer life of structures. The initial prestress was maintained at 0.70 times guaranteed ultimate tensile strength (GUTS) of cables. The prestressing loss due to relaxation of prestressing cables increases as the temperature increases. (author)

The global impact of ozone on agricultural crop yields under current and future air quality legislation

Science.gov (United States)

Van Dingenen, Rita; Dentener, Frank J.; Raes, Frank; Krol, Maarten C.; Emberson, Lisa; Cofala, Janusz

In this paper we evaluate the global impact of surface ozone on four types of agricultural crop. The study is based on modelled global hourly ozone fields for the year 2000 and 2030, using the global 1°×1° 2-way nested atmospheric chemical transport model (TM5). Projections for the year 2030 are based on the relatively optimistic "current legislation (CLE) scenario", i.e. assuming that currently approved air quality legislation will be fully implemented by the year 2030, without a further development of new abatement policies. For both runs, the relative yield loss due to ozone damage is evaluated based on two different indices (accumulated concentration above a 40 ppbV threshold and seasonal mean daytime ozone concentration respectively) on a global, regional and national scale. The cumulative metric appears to be far less robust than the seasonal mean, while the seasonal mean shows satisfactory agreement with measurements in Europe, the US, China and Southern India and South-East Asia. Present day global relative yield losses are estimated to range between 7% and 12% for wheat, between 6% and 16% for soybean, between 3% and 4% for rice, and between 3% and 5% for maize (range resulting from different metrics used). Taking into account possible biases in our assessment, introduced through the global application of "western" crop exposure-response functions, and through model performance in reproducing ozone-exposure metrics, our estimates may be considered as being conservative. Under the 2030 CLE scenario, the global situation is expected to deteriorate mainly for wheat (additional 2-6% loss globally) and rice (additional 1-2% loss globally). India, for which no mitigation measures have been assumed by 2030, accounts for 50% of these global increase in crop yield loss. On a regional-scale, significant reductions in crop losses by CLE-2030 are only predicted in Europe (soybean) and China (wheat). Translating these assumed yield losses into total global economic

Economic losses occurring due to brucellosis in Indian livestock populations.

Science.gov (United States)

Singh, B B; Dhand, N K; Gill, J P S

2015-05-01

Brucellosis is a serious public health issue in India. Estimation of economic losses occurring due to brucellosis is required to help formulate prevention and control strategies, but has not been done in India. We estimated economic losses due to brucellosis by sourcing prevalence data from epidemiological surveys conducted in India. Data for livestock populations were obtained from official records. Probability distributions were used for many of the input parameters to account for uncertainty and variability. The analysis revealed that brucellosis in livestock is responsible for a median loss of US $ 3.4 billion (5th-95th percentile 2.8-4.2 billion). The disease in cattle and buffalo accounted for 95.6% of the total losses occurring due to brucellosis in livestock populations. The disease is responsible for a loss of US $ 6.8 per cattle, US$18.2 per buffalo, US $ 0.7 per sheep, US $ 0.5 per goat and US $ 0.6 per pig. These losses are additional to the economic and social consequences of the disease in humans. The results suggest that the disease causes significant economic losses in the country and should be controlled on a priority basis. Copyright © 2015 Elsevier B.V. All rights reserved.

Atmospheric lifetimes and Ozone Depletion Potentials of trans-1-chloro-3,3,3-trifluoropropylene and trans-1,2-dichloroethylene in a three-dimensional model

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K. O. Patten

2010-11-01

Full Text Available The chloroalkenes trans-1-chloro-3,3,3-trifluoropropylene (tCFP and trans-1,2-dichloroethylene (tDCE have been proposed as candidate replacements for other compounds in current use that cause concerns regarding potential environmental effects including destruction of stratospheric ozone. Because tCFP and tDCE contain chlorine atoms, the effects of these short-lived compounds on stratospheric ozone must be established. In this study, we derive the atmospheric lifetimes and Ozone Depletion Potentials (ODPs for tCFP and for tDCE assuming emissions from land surfaces at latitudes 30° N to 60° N using the MOZART 3 three-dimensional model of atmospheric chemistry and physics. 53% of the ozone loss due to tCFP and 98% of the ozone loss due to tDCE take place in the troposphere, rather than in the stratosphere as generally expected from longer-lived chlorocarbons. The atmospheric lifetime of tCFP against chemical reaction is 40.4 days, and its ODP is quite small at 0.00034. The tDCE atmospheric lifetime is 12.7 days, and its ODP is 0.00024, which is the lowest ODP found for any chlorocarbon we have studied. Our study suggests that chlorine from tCFP and tDCE are unlikely to affect ozone at quantities likely to be emitted to the atmosphere.

Estimating changes in urban ozone concentrations due to life cycle emissions from hydrogen transportation systems

Science.gov (United States)

Wang, Guihua; Ogden, Joan M.; Chang, Daniel P. Y.

Hydrogen has been proposed as a low polluting alternative transportation fuel that could help improve urban air quality. This paper examines the potential impact of introducing a hydrogen-based transportation system on urban ambient ozone concentrations. This paper considers two scenarios, where significant numbers of new hydrogen vehicles are added to a constant number of gasoline vehicles. In our scenarios hydrogen fuel cell vehicles (HFCVs) are introduced in Sacramento, California at market penetrations of 9% and 20%. From a life cycle analysis (LCA) perspective, considering all the emissions involved in producing, transporting, and using hydrogen, this research compares three hypothetical natural gas to hydrogen pathways: (1) on-site hydrogen production; (2) central hydrogen production with pipeline delivery; and (3) central hydrogen production with liquid hydrogen truck delivery. Using a regression model, this research shows that the daily maximum temperature correlates well with atmospheric ozone formation. However, increases in initial VOC and NO x concentrations do not necessarily increase the peak ozone concentration, and may even cause it to decrease. It is found that ozone formation is generally limited by NO x in the summer and is mostly limited by VOC in the fall in Sacramento. Of the three hydrogen pathways, the truck delivery pathway contributes the most to ozone precursor emissions. Ozone precursor emissions from the truck pathway at 9% market penetration can cause additional 3-h average VOC (or NO x) concentrations up to approximately 0.05% (or 1%) of current pollution levels, and at 20% market penetration up to approximately 0.1% (or 2%) of current pollution levels. However, all of the hydrogen pathways would result in very small (either negative or positive) changes in ozone air quality. In some cases they will result in worse ozone air quality (mostly in July, August, and September), and in some cases they will result in better ozone air quality

Estimating changes in urban ozone concentrations due to life cycle emissions from hydrogen transportation systems

International Nuclear Information System (INIS)

Guihua Wang; Ogden, Joan M.; Chang, Daniel P.Y.

2007-01-01

Hydrogen has been proposed as a low polluting alternative transportation fuel that could help improve urban air quality. This paper examines the potential impact of introducing a hydrogen-based transportation system on urban ambient ozone concentrations. This paper considers two scenarios, where significant numbers of new hydrogen vehicles are added to a constant number of gasoline vehicles. In our scenarios hydrogen fuel cell vehicles (HFCVs) are introduced in Sacramento, California at market penetrations of 9% and 20%. From a life cycle analysis (LCA) perspective, considering all the emissions involved in producing, transporting, and using hydrogen, this research compares three hypothetical natural gas to hydrogen pathways: (1) on-site hydrogen production; (2) central hydrogen production with pipeline delivery; and (3) central hydrogen production with liquid hydrogen truck delivery. Using a regression model, this research shows that the daily maximum temperature correlates well with atmospheric ozone formation. However, increases in initial VOC and NO x concentrations do not necessarily increase the peak ozone concentration, and may even cause it to decrease. It is found that ozone formation is generally limited by NO x in the summer and is mostly limited by VOC in the fall in Sacramento. Of the three hydrogen pathways, the truck delivery pathway contributes the most to ozone precursor emissions. Ozone precursor emissions from the truck pathway at 9% market penetration can cause additional 3-h average VOC (or NO x ) concentrations up to approximately 0.05% (or 1%) of current pollution levels, and at 20% market penetration up to approximately 0.1% (or 2%) of current pollution levels. However, all of the hydrogen pathways would result in very small (either negative or positive) changes in ozone air quality. In some cases they will result in worse ozone air quality (mostly in July, August, and September), and in some cases they will result in better ozone air

Characteristics of tropospheric ozone depletion events in the Arctic spring: analysis of the ARCTAS, ARCPAC, and ARCIONS measurements and satellite BrO observations

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J.-H. Koo

2012-10-01

Full Text Available Arctic ozone depletion events (ODEs are caused by halogen catalyzed ozone loss. In situ chemistry, advection of ozone-poor air mass, and vertical mixing in the lower troposphere are important factors affecting ODEs. To better characterize the ODEs, we analyze the combined set of surface, ozonesonde, and aircraft in situ measurements of ozone and bromine compounds during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS, the Aerosol, Radiation, and Cloud Processes affecting Arctic Climate (ARCPAC, and the Arctic Intensive Ozonesonde Network Study (ARCIONS experiments (April 2008. Tropospheric BrO columns retrieved from satellite measurements and back trajectory calculations are also used to investigate the characteristics of observed ODEs. In situ observations from these field experiments are inadequate to validate tropospheric BrO columns derived from satellite measurements. In view of this difficulty, we construct an ensemble of tropospheric column BrO estimates from two satellite (OMI and GOME-2 measurements and with three independent methods of calculating stratospheric BrO columns. Furthermore, we select analysis methods that do not depend on the absolute magnitude of column BrO, such as time-lagged correlation analysis of ozone and tropospheric column BrO, to understand characteristics of ODEs. Time-lagged correlation analysis between in situ (surface and ozonesonde measurements of ozone and satellite derived tropospheric BrO columns indicates that the ODEs are due to either local halogen-driven ozone loss or short-range (∼1 day transport from nearby regions with ozone depletion. The effect of in situ ozone loss is also evident in the diurnal variation difference between low (10th and 25th percentiles and higher percentiles of surface ozone concentrations at Alert, Canada. Aircraft observations indicate low-ozone air mass transported from adjacent high-BrO regions. Correlation analyses of ozone

Brief communication "Stratospheric winds, transport barriers and the 2011 Arctic ozone hole"

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M. J. Olascoaga

2012-12-01

Full Text Available The Arctic stratosphere throughout the late winter and early spring of 2011 was characterized by an unusually severe ozone loss, resulting in what has been described as an ozone hole. The 2011 ozone loss was made possible by unusually cold temperatures throughout the Arctic stratosphere. Here we consider the issue of what constitutes suitable environmental conditions for the formation and maintenance of a polar ozone hole. Our discussion focuses on the importance of the stratospheric wind field and, in particular, the importance of a high latitude zonal jet, which serves as a meridional transport barrier both prior to ozone hole formation and during the ozone hole maintenance phase. It is argued that stratospheric conditions in the boreal winter/spring of 2011 were highly unusual inasmuch as in that year Antarctic-like Lagrangian dynamics led to the formation of a boreal ozone hole.

Ozone Transport Aloft Drives Surface Ozone Maxima Across the Mojave Desert

Science.gov (United States)

VanCuren, R. A.

2014-12-01

A persistent layer of polluted air in the lower free troposphere over the Mojave Desert (California and Nevada) drives spring and summer surface ozone maxima as deep afternoon mixing delivers ozone and ozone precursors to surface measurement sites 200 km or more downwind of the mountains that separate the deserts from the heavily populated coastal areas of California. Pollutants in this elevated layer derive from California source regions (the Los Angeles megacity region and the intensive agricultural region of the San Joaquin Valley), and from long-range transport from Asia. Recognition of this poorly studied persistent layer explains and expands the significance of previously published reports of ozone and other pollutants observed in and over the Mojave Desert, resolves an apparent paradox in the timing of ozone peaks due to transport from the upwind basins, and provides a new perspective on the long-range downwind impacts of megacity pollution plumes.

Multidecadal global cooling and unprecedented ozone loss following a regional nuclear conflict

Science.gov (United States)

Mills, Michael J.; Toon, Owen B.; Lee-Taylor, Julia; Robock, Alan

2014-04-01

We present the first study of the global impacts of a regional nuclear war with an Earth system model including atmospheric chemistry, ocean dynamics, and interactive sea ice and land components. A limited, regional nuclear war between India and Pakistan in which each side detonates 50 15 kt weapons could produce about 5 Tg of black carbon (BC). This would self-loft to the stratosphere, where it would spread globally, producing a sudden drop in surface temperatures and intense heating of the stratosphere. Using the Community Earth System Model with the Whole Atmosphere Community Climate Model, we calculate an e-folding time of 8.7 years for stratospheric BC compared to 4-6.5 years for previous studies. Our calculations show that global ozone losses of 20%-50% over populated areas, levels unprecedented in human history, would accompany the coldest average surface temperatures in the last 1000 years. We calculate summer enhancements in UV indices of 30%-80% over midlatitudes, suggesting widespread damage to human health, agriculture, and terrestrial and aquatic ecosystems. Killing frosts would reduce growing seasons by 10-40 days per year for 5 years. Surface temperatures would be reduced for more than 25 years due to thermal inertia and albedo effects in the ocean and expanded sea ice. The combined cooling and enhanced UV would put significant pressures on global food supplies and could trigger a global nuclear famine. Knowledge of the impacts of 100 small nuclear weapons should motivate the elimination of more than 17,000 nuclear weapons that exist today.

Trends of Ozone in Switzerland since 1992 (TROZOS)

Energy Technology Data Exchange (ETDEWEB)

Ordonez, C.; Mathis, H.; Furger, M.; Prevot, A.S.H

2004-07-01

This work reports on the trends of the daily afternoon (noon to midnight) maximum ozone concentrations at 15 of the 16 stations of the Swiss air quality monitoring network (NABEL) during the period 1992-2002. The use of numerous meteorological parameters and additional data allowed a detailed seasonal analysis of the influence of the weather on the ozone maxima at the different stations. An analysis of covariance (ANCOVA) was performed separately for each station and season in order to detect the parameters which best explain the variability of the daily ozone maximum concentrations. During the warm seasons (summer and spring) the most explanatory parameters are those related to the ozone production, in particular the afternoon temperature. In winter, the most explanatory variables are the ones influencing the vertical mixing and thus the ozone destruction by titration with NO and dry deposition, like the afternoon global radiation. The trends of both the measured and meteorologically corrected ozone maxima were calculated. The year-to-year variability in the ozone maxima was lowered by a factor of 3 by the meteorological correction. Significantly positive trends of corrected ozone maxima of 0.3 - 1.1 ppb/year were found at the low altitude stations in winter and autumn as well as at Lausanne - urban station - in all the seasons, mainly due to the lower loss of ozone by reaction with NO as a consequence of the decreased emissions of primary pollutants during the 90s. This could be partially confirmed by the lower trends of O{sub X} (sum O{sub 3} of and NO{sub 2}) maxima compared to the trends in ozone maxima. The absence of negative trends of the median or mean ozone maxima north of the Alps in summer suggests that the decrease in the emissions of ozone precursors did not have a strong impact on the afternoon maximum ozone concentrations during the last decade. In contrast to the project TOSS (Trends of Ozone in Southern Switzerland), no significantly negative

Trends of Ozone in Switzerland since 1992 (TROZOS)

International Nuclear Information System (INIS)

Ordonez, C.; Mathis, H.; Furger, M.; Prevot, A.S.H.

2004-07-01

This work reports on the trends of the daily afternoon (noon to midnight) maximum ozone concentrations at 15 of the 16 stations of the Swiss air quality monitoring network (NABEL) during the period 1992-2002. The use of numerous meteorological parameters and additional data allowed a detailed seasonal analysis of the influence of the weather on the ozone maxima at the different stations. An analysis of covariance (ANCOVA) was performed separately for each station and season in order to detect the parameters which best explain the variability of the daily ozone maximum concentrations. During the warm seasons (summer and spring) the most explanatory parameters are those related to the ozone production, in particular the afternoon temperature. In winter, the most explanatory variables are the ones influencing the vertical mixing and thus the ozone destruction by titration with NO and dry deposition, like the afternoon global radiation. The trends of both the measured and meteorologically corrected ozone maxima were calculated. The year-to-year variability in the ozone maxima was lowered by a factor of 3 by the meteorological correction. Significantly positive trends of corrected ozone maxima of 0.3 - 1.1 ppb/year were found at the low altitude stations in winter and autumn as well as at Lausanne - urban station - in all the seasons, mainly due to the lower loss of ozone by reaction with NO as a consequence of the decreased emissions of primary pollutants during the 90s. This could be partially confirmed by the lower trends of O X (sum O 3 of and NO 2 ) maxima compared to the trends in ozone maxima. The absence of negative trends of the median or mean ozone maxima north of the Alps in summer suggests that the decrease in the emissions of ozone precursors did not have a strong impact on the afternoon maximum ozone concentrations during the last decade. In contrast to the project TOSS (Trends of Ozone in Southern Switzerland), no significantly negative trends of ozone

Mass-dependent and non-mass-dependent isotope effects in ozone photolysis: Resolving theory and experiments

International Nuclear Information System (INIS)

Cole, Amanda S.; Boering, Kristie A.

2006-01-01

In addition to the anomalous 17 O and 18 O isotope effects in the three-body ozone formation reaction O+O 2 +M, isotope effects in the destruction of ozone by photolysis may also play a role in determining the isotopic composition of ozone and other trace gases in the atmosphere. While previous experiments on ozone photolysis at 254 nm were interpreted as evidence for preferential loss of light ozone that is anomalous (or 'non-mass-dependent'), recent semiempirical theoretical calculations predicted a preferential loss of heavy ozone at that wavelength that is mass dependent. Through photochemical modeling results presented here, we resolve this apparent contradiction between experiment and theory. Specifically, we show that the formation of ozone during the UV photolysis experiments is not negligible, as had been assumed, and that the well-known non-mass-dependent isotope effects in ozone formation can account for the non-mass-dependent enrichment of the heavy isotopologs of ozone observed in the experiment. Thus, no unusual non-mass-dependent fractionation in ozone photolysis must be invoked to explain the experimental results. Furthermore, we show that theoretical predictions of a mass-dependent preferential loss of the heavy isotopologs of ozone during UV photolysis are not inconsistent with the experimental data, particularly if mass-dependent isotope effects in the chemical loss reactions of ozone during the photolysis experiments or experimental artifacts enrich the remaining ozone in 17 O and 18 O. Before the calculated fractionation factors can be quantitatively evaluated, however, further investigation of possible mass-dependent isotope effects in the reactions of ozone with O( 1 D), O( 3 P), O 2 ( 1 Δ), and O 2 ( 1 Σ) is needed through experiments we suggest here

Evolution of stratospheric ozone during winter 2002/2003 as observed by a ground-based millimetre wave radiometer at Kiruna, Sweden

Directory of Open Access Journals (Sweden)

U. Raffalski

2005-01-01

Full Text Available We present ozone measurements from the millimetre wave radiometer installed at the Swedish Institute of Space Physics (Institutet för rymdfysik, IRF in Kiruna (67.8° N, 20.4° E, 420 m asl. Nearly continuous operation in the winter of 2002/2003 allows us to give an overview of ozone evolution in the stratosphere between 15 and 55 km. In this study we present a detailed analysis of the Arctic winter 2002/2003. By means of a methodology using equivalent latitudes we investigate the meteorological processes in the stratosphere during the entire winter/spring period. During the course of the winter strong mixing into the vortex took place in the middle and upper stratosphere as a result of three minor and one major warming event, but no evidence was found for significant mixing in the lower stratosphere. Ozone depletion in the lower stratosphere during this winter was estimated by measurements on those days when Kiruna was well inside the Arctic polar vortex. The days were carefully chosen using a definition of the vortex edge based on equivalent latitudes. At the 475 K isentropic level a cumulative ozone loss of about 0.5 ppmv was found starting in January and lasting until mid-March. The early ozone loss is probably a result of the very cold temperatures in the lower stratosphere in December and the geographical extension of the vortex to lower latitudes where solar irradiation started photochemical ozone loss in the pre-processed air. In order to correct for dynamic effects of the ozone variation due to diabatic subsidence of air masses inside the vortex, we used N2O measurements from the Odin satellite for the same time period. The derived ozone loss in the lower stratosphere between mid-December and mid-March varies between 1.1±0.1 ppmv on the 150 ppbv N2O isopleth and 1.7±0.1 ppmv on the 50 ppbv N2O isopleth.

Limitations on plasma acceleration due to synchrotron losses

International Nuclear Information System (INIS)

Barletta, W.A.; Lee, E.P.; Bonifacio, R.; De Salvo, L.

1999-01-01

In this letter we consider the effect of synchrotron radiation losses due to the betatron motion of the electron beam in its self-induced magnetic field in a plasma accelerator taking into account the charge neutralization factor. The most favorable case is where the plasma density is smaller than the beam density. The contrary regime is strongly disfavored by the synchrotron radiation loss for beams with characteristics for TeV energies. In both cases we find that upon increasing the plasma density the synchrotron losses kill the acceleration process, so that there are limitations on the maximum allowable plasma density

Stratospheric ozone profile and total ozone trends derived from the SAGE I and SAGE II data

Science.gov (United States)

Mccormick, M. P.; Veiga, Robert E.; Chu, William P.

1992-01-01

Global trends in both stratospheric column ozone and as a function of altitude are derived on the basis of SAGE I/II ozone data from the period 1979-1991. A statistical model containing quasi-biennial, seasonal, and semiannual oscillations, a linear component, and a first-order autoregressive noise process was fit to the time series of SAGE I/II monthly zonal mean data. The linear trend in column ozone above 17-km altitude, averaged between 65 deg S and 65 deg N, is -0.30 +/-0.19 percent/yr, or -3.6 percent over the time period February 1979 through April 1991. The data show that the column trend above 17 km is nearly zero in the tropics and increases towards the high latitudes with values of -0.6 percent/yr at 60 deg S and -0.35 percent/yr at 60 deg N. Both these results are in agreement with the recent TOMS results. The profile trend analyses show that the column ozone losses are occurring below 25 km, with most of the loss coming from the region between 17 and 20 km. Negative trend values on the order of -2 percent/yr are found at 17 km in midlatitudes.

Source attribution of tropospheric ozone

Science.gov (United States)

Butler, T. M.

2015-12-01

Tropospheric ozone is a harmful pollutant with adverse effects on human health and ecosystems. As well as these effects, tropospheric ozone is also a powerful greenhouse gas, with an anthropogenic radiative forcing one quarter of that of CO2. Along with methane and atmospheric aerosol, tropospheric ozone belongs to the so-called Short Lived Climate forcing Pollutants, or SLCP. Recent work has shown that efforts to reduce concentrations of SLCP in the atmosphere have the potential to slow the rate of near-term climate change, while simultaneously improving public health and reducing crop losses. Unlike many other SLCP, tropospehric ozone is not directly emitted, but is instead influenced by two distinct sources: transport of air from the ozone-rich stratosphere; and photochemical production in the troposphere from the emitted precursors NOx (oxides of nitrogen), CO (Carbon Monoxide), and VOC (volatile organic compounds, including methane). Better understanding of the relationship between ozone production and the emissions of its precursors is essential for the development of targeted emission reduction strategies. Several modeling methods have been employed to relate the production of tropospheric ozone to emissions of its precursors; emissions perturbation, tagging, and adjoint sensitivity methods all deliver complementary information about modelled ozone production. Most studies using tagging methods have focused on attribution of tropospheric ozone production to emissions of NOx, even though perturbation methods have suggested that tropospheric ozone is also sensitive to VOC, particularly methane. In this study we describe the implementation into a global chemistry-climate model of a scheme for tagging emissions of NOx and VOC with an arbitrary number of labels, which are followed through the chemical reactions of tropospheric ozone production in order to perform attribution of tropospehric ozone to its emitted precursors. Attribution is performed to both

Impact of enhanced ozone deposition and halogen chemistry on tropospheric ozone over the Northern Hemisphere

Science.gov (United States)

Fate of ozone in marine environments has been receiving increased attention due to the tightening of ambient air quality standards. The role of deposition and halogen chemistry is examined through incorporation of an enhanced ozone deposition algorithm and inclusion of halogen ch...

Effects of mineral nutrients on ozone susceptibility of Lemna minor

Energy Technology Data Exchange (ETDEWEB)

Craker, L E

1971-01-01

Susceptibility of Lemna minor L. to ozone injury was influenced by the mineral nutrients available to the Lemna plants. Additional nitrogen or additional iron in the nutrient media respectively enhanced or reduced chlorophyll loss of Lemna plants fumigated with ozone. Lemna plants growing on a nutrient medium lacking copper had significantly less injury from ozone fumigation than Lemna plants growing on a complete nutrient medium. There were apparent interactions among phosphorus and potassium nutrient levels in determing the Lemna plant's susceptibility to ozone.

Enhanced Ozone Production at Low Temperatures due to Ethanol (E85)

Science.gov (United States)

Ginnebaugh, D. L.; Livingstone, P. L.; Jacobson, M. Z.

2009-12-01

The increased use of ethanol in transportation fuels warrants an investigation of its consequences. An important component of such an investigation is the temperature-dependence of ethanol and gasoline exhaust chemistry. We use the near-explicit Master Chemical Mechanism (MCM, version 3.1, LEEDS University) with the SMVGEAR II chemical ordinary differential solver to provide the speed necessary to simulate explicit chemistry to examine such effects. The MCM has over 13,500 organic reactions and 4,600 species. SMVGEAR II is a sparse-matrix Gear solver that reduces the computation time significantly while maintaining any specified accuracy. Although for this study we use a box model, we determined that the speed of the MCM with the SMVGEAR solver will allow the MCM to be modeled in 3-dimensions. We also verified the accuracy of the model with comparisons to smog chamber data. We use species-resolved tailpipe emissions data for E85 (15% gasoline, 85% ethanol fuel blend) and gasoline vehicles to compare the impact of each on ozone and carcinogenic organic gases as a function of ambient temperature and background concentrations, using Los Angeles in 2020 as a base case. We use two different emissions sets - one is a compilation of data taken at near 24 C and the other from data taken at -7 C - to determine how atmospheric chemistry and emissions are affected by temperature. We include diurnal effects by examining 2 day and 5 day scenarios. We find that for both emission data sets, the average ozone concentrations through the range of temperatures tested are higher with E85 than with gasoline by 8 parts per billion volume (ppbv) at higher temperatures to 55 ppbv at low temperatures and low sunlight (winter conditions) for an area with a high nitrogen oxides (NOx) to non-methane organic gases (NMOG) ratio. The results suggest that E85's effect on health through ozone formation becomes increasingly more significant relative to gasoline as temperatures decreased due to the

Brief communication: Loss of life due to Hurricane Harvey

NARCIS (Netherlands)

Jonkman, Sebastiaan N.; Godfroij, Maartje; Sebastian, Antonia; Kolen, B.

2018-01-01

An analysis was made of the loss of life caused by Hurricane Harvey. Information was collected for 70 fatalities that occurred due to the event and were recovered within the first 2 weeks after landfall. Most fatalities occurred due to drowning (81 %), particularly in and around vehicles. Males

Effects of mineral nutrients on ozone susceptibility of Lemna minor

Energy Technology Data Exchange (ETDEWEB)

Craker, L.E.

1971-01-01

Susceptibility of Lemna minor L. to ozone injury was influenced by the mineral nutrients available to the Lemna plants. Additional nitrogen or additional iron in the nutrient media respectively enhanced or reduced chlorophyll loss of Lemna plants fumigated with ozone. Lemna plants growing on a nutrient medium lacking copper had significantly less injury from ozone fumigation than Lemna plants growing on a complete nutrient medium. There were apparent interactions among phosphorus and potassium nutrient levels in determing the Lemna plant's susceptibility to ozone.

Ozone and UV research at Finnish Meteorological Inst.: review of selected results

Energy Technology Data Exchange (ETDEWEB)

Taalas, P; Koskela, T; Damski, J; Supperi, A [Finnish Meteorological Inst., Helsinki (Finland). Section of Ozone and UV Research; Kyroe, E [Finnish Meteorologican Inst., Sodankylae (Finland). Sodankylae Observatory; Ginzburg, M [Servicio Meteorologico Nacional, Buenos Aires (Argentina); Dijkhuis, J L [Finnish Meteorological Inst., Helsinki (Finland). EUMETSAT

1996-12-31

Ozone and UV radiation research have become an important part of atmospheric research at Finnish Meteorological Institute after the discovery of chlorine based ozone loss in the Antarctic stratosphere

Ozone and UV research at Finnish Meteorological Inst.: review of selected results

Energy Technology Data Exchange (ETDEWEB)

Taalas, P.; Koskela, T.; Damski, J.; Supperi, A. [Finnish Meteorological Inst., Helsinki (Finland). Section of Ozone and UV Research; Kyroe, E. [Finnish Meteorologican Inst., Sodankylae (Finland). Sodankylae Observatory; Ginzburg, M. [Servicio Meteorologico Nacional, Buenos Aires (Argentina); Dijkhuis, J.L. [Finnish Meteorological Inst., Helsinki (Finland). EUMETSAT

1995-12-31

Ozone and UV radiation research have become an important part of atmospheric research at Finnish Meteorological Institute after the discovery of chlorine based ozone loss in the Antarctic stratosphere

Assessment of the economic impact of ozone on the agricultural sector in Ontario, Canada

International Nuclear Information System (INIS)

Jallala, A.M.

1990-05-01

Ozone is the most damaging secondary pollutant to agricultural production, according to the literature. It is estimated that 90% of crop losses due to air pollution are caused by ozone. The economic impact of ozone on 20 agricultural commodities in Ontario is assessed in two steps. In the first, ozone contour maps are generated for the province. The results suggest an average ozone concentration of 40 ppB, higher than the natural background of 20 ppB. The second step measures the change in consumer and producer surplus that results from reductions in ozone levels in Ontario from 40 ppB to 20 ppB. Consumer plus producer surpluses correspond to the area below the demand curve and above the supply curve to the left of their intersection. A nonlinear programming model that maximizes consumer and producer surpluses, subject to a set of constraints, was run twice. The first run incorporates realized yields and production costs, and the second incorporates biological yield changes owing to ozone and the associated changes in production costs. The difference in value of the objective functions between the two runs shows the net benefits of reduced ozone levels. Results indicate an average net benefit of $64.3 million/y or 5.8% of the total value of all the crops considered. Average annual consumer benefits are $44.1 million and producer benefits $20.2 million. Not all producers benefit from ozone reductions; producers of fresh vegetables lose while producers of grain corn, soybeans, and winter wheat gain. 54 refs., 6 figs., 15 tabs

Seasonal Changes in Tropospheric Ozone Concentrations over South Korea and Its Link to Ozone Precursors

Science.gov (United States)

Jung, H. C.; Moon, B. K.; Wie, J.

2017-12-01

Concentration of tropospheric ozone over South Korea has steadily been on the rise in the last decades, mainly due to rapid industrializing and urbanizing in the Eastern Asia. To identify the characteristics of tropospheric ozone in South Korea, we fitted a sine function to the surface ozone concentration data from 2005 to 2014. Based on fitted sine curves, we analyzed the shifts in the dates on which ozone concentration reached its peak in the calendar year. Ozone monitoring sites can be classified into type types: where the highest annual ozone concentration kept occurring sooner (Esites) and those that kept occurring later (Lsites). The seasonal analysis shows that the surface ozone had increased more rapidly in Esites than in Lsites in the past decade during springtime and vice-versa during summertime. We tried to find the reason for the different seasonal trends with the relationship between ozone and ozone precursors. As a result, it was found that the changes in the ground-level ozone concentration in the spring and summer times are considerably influenced by changes in nitrogen dioxide concentration, and this is closely linked to the destruction (production) process of ozone by nitrogen dioxide in spring (summer). The link between tropospheric ozone and nitrogen dioxide discussed in this study will have to be thoroughly examined through climate-chemistry modeling in the future. Acknowledgements This research was supported by the Korea Ministry of Environment (MOE) as "Climate Change Correspondence Program."

Comparison of high-latitude line-of-sight ozone column density with derived ozone fields and the effects of horizontal inhomogeneity

Directory of Open Access Journals (Sweden)

W. H. Swartz

2006-01-01

Full Text Available Extensive ozone measurements were made during the second SAGE III Ozone Loss and Validation Experiment (SOLVE II. We compare high-latitude line-of-sight (LOS slant column ozone measurements from the NASA DC-8 to ozone simulated by forward integration of measurement-derived ozone fields constructed both with and without the assumption of horizontal homogeneity. The average bias and rms error of the simulations assuming homogeneity are relatively small (−6 and 10%, respectively in comparison to the LOS measurements. The comparison improves significantly (−2% bias; 8% rms error using forward integrations of three-dimensional proxy ozone fields reconstructed from potential vorticity-O3 correlations. The comparisons provide additional verification of the proxy fields and quantify the influence of large-scale ozone inhomogeneity. The spatial inhomogeneity of the atmosphere is a source of error in the retrieval of trace gas vertical profiles and column abundance from LOS measurements, as well as a complicating factor in intercomparisons that include LOS measurements at large solar zenith angles.

Estimation of economic losses due to Peste de Petits Ruminants in small ruminants in India

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B. Singh

2014-04-01

Full Text Available Aim: To develop a simple mathematical model to assess the losses due to peste des petits ruminants (PPR in small ruminants in India. Materials and Methods: The study was based on cases and deaths in goats and sheep due to PPR from the average combined data on ovine/caprine as published by Government of India for the last 5 years (2008-2012. All possible direct and indirect losses due to the disease, viz. mortality losses, losses due to direct reduction in milk/wool yield, losses due to reproduction failure, body weight losses, treatment costs and opportunity costs, were considered to provide estimate of annual economic losses due to PPR in sheep and goats in India. Based on cases and deaths as reported in sample survey studies, the annual economic loss was also estimated. Results: On the basis of data reported by Government of India, the study has shown average annual economic loss of Rs. 167.83 lacs, of which Rs. 125.67 lacs and Rs. 42.16 lacs respectively are due to the incidence of the disease in goats and sheep. Morbidity losses constituted the greater share of the total loss in both goats and sheep (56.99% and 61.34%, respectively. Among different components of morbidity loss, direct body weight loss was the most significant in both goats and sheep. Based on cases and deaths as reported in sample survey studies, the estimated annual economic loss due to PPR in goats and sheep is Rs. 8895.12 crores, of which Rs. 5477.48 and Rs. 3417.64 crores respectively are due to the disease in goats and sheep. Conclusion: The low economic losses as reported based on Government of India data points towards underreporting of cases and deaths due to the disease. The study thus revealed a significant loss due to PPR in small ruminants on a large scale.

OZONE CONCENTRATION ATTRIBUTABLE PREMATURE DEATH IN POLAND

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Krzysztof Skotak

2010-03-01

Full Text Available Ozone in the lower part of the atmosphere (troposphere, strong photochemical oxidant, is not directly emitted to the atmosphere but formed through a series of complex reactions. Ozone concentrations depends on ozone precursors air contamination (mainly nitrogen dioxide and non-methane volatile organic compounds and meteorological conditions (temperature and solar radiation. The main sectors emitted ozone precursors are road transport, power and heat generation plants, household (heating, industry, and petrol storage and distribution. Ozone and some of its precursors are also transported long distances in the atmosphere and are therefore considered a transboundary problem. As a result, the ozone concentrations are often low in busy urban areas and higher in suburban and rural areas. Nowadays, instead of particulate matter, ozone is one of the most widespread global air pollution problems. In and around urban areas, relatively large gradients of ozone can be observed. Because of its high reactivity in elevated concentrations ozone causes serious health problems and damage to ecosystems, agricultural crops and materials. Main ill-health endpoints as a results of ozone concentrations can be characterised as an effect of pulmonary and cardiovascular system, time morbidity and mortality series, development of atherosclerosis and asthma and finally reduction in life expectancy. The associations with increased daily mortality due to ozone concentrations are confirmed by many researches and epidemiological studies. Estimation of the level selected ill-health endpoints (mortality in total and due to cardiovascular and respiratory causes as a result of the short-term ozone exposure in Poland was the main aim of the project. Final results have been done based on estimation method elaborated by WHO, ozone measurements from National Air Quality Monitoring System and statistical information such as mortality rate and populations. All analysis have been done in

Effect of coupled anthropogenic perturbations on stratospheric ozone

International Nuclear Information System (INIS)

Wuebbles, D.J.; Luther, F.M.; Penner, J.E.

1992-01-01

Since 1976 the greatest concern about potential perturbations to stratospheric ozone has been in regard to the atmospheric release of chlorofluorocarbons. Consequently, atmospheric measurements of ozone have usually been compared with model calculations in which only chlorocarbon perturbations are considered. However, in order to compare theoretical calculations with recent measurements of ozone and to project expected changes to atmospheric ozone levels over the next few decades, one must consider the effect from other perturbations as well. In this paper, the authors consider the coupling between several possible anthropogenic atmospheric perturbations. Namely, they examine the effects of past and possible future increases of chlorocarbons, CO 2 , N 2 O, and NO x . The focus of these calculations is on the potential changes in ozone due to chlorocarbon emissions, how other anthropogenic perturbations may have influenced the actual change in ozone over the last decade, and how these perturbations may influence future changes in ozone. Although calculations including future chlorocarbon emissions alone result in significant reductions in ozone, there is very little change in total ozone over the coming decades when other anthropogenic sources are included. Increasing CO 2 concentrations have the largest offsetting effect on the change in total ozone due to chlorocarbons. Owing to the necessity of considering emissions from a number of trace gases simultaneously, determining expected global-scale chemical and climatic effects is more complex than was previously recognized

Breeding of ozone resistant rice: Relevance, approaches and challenges

International Nuclear Information System (INIS)

Frei, Michael

2015-01-01

Tropospheric ozone concentrations have been rising across Asia, and will continue to rise during the 21st century. Ozone affects rice yields through reductions in spikelet number, spikelet fertility, and grain size. Moreover, ozone leads to changes in rice grain and straw quality. Therefore the breeding of ozone tolerant rice varieties is warranted. The mapping of quantitative trait loci (QTL) using bi-parental populations identified several tolerance QTL mitigating symptom formation, grain yield losses, or the degradation of straw quality. A genome-wide association study (GWAS) demonstrated substantial natural genotypic variation in ozone tolerance in rice, and revealed that the genetic architecture of ozone tolerance in rice is dominated by multiple medium and small effect loci. Transgenic approaches targeting tolerance mechanisms such as antioxidant capacity are also discussed. It is concluded that the breeding of ozone tolerant rice can contribute substantially to the global food security, and is feasible using different breeding approaches. - Highlights: • Tropospheric ozone affects millions of hectares of rice land. • Ozone affects rice yield and quality. • Breeding approaches to adapt rice to high ozone are discussed. • Challenges in the breeding of ozone resistant rice are discussed. - This review summarizes the effects of tropospheric ozone on rice and outlines approaches and challenges in the breeding of adapted varieties

Impacts of increasing ozone on Indian plants

International Nuclear Information System (INIS)

Oksanen, E.; Pandey, V.; Pandey, A.K.; Keski-Saari, S.; Kontunen-Soppela, S.; Sharma, C.

2013-01-01

Increasing anthropogenic and biogenic emissions of precursor compounds have led to high tropospheric ozone concentrations in India particularly in Indo-Gangetic Plains, which is the most fertile and cultivated area of this rapidly developing country. Current ozone risk models, based on European and North American data, provide inaccurate estimations for crop losses in India. During the past decade, several ozone experiments have been conducted with the most important Indian crop species (e.g. wheat, rice, mustard, mung bean). Experimental work started in natural field conditions around Varanasi area in early 2000's, and the use of open top chambers and EDU (ethylene diurea) applications has now facilitated more advanced studies e.g. for intra-species sensitivity screening and mechanisms of tolerance. In this review, we identify and discuss the most important gaps of knowledge and future needs of action, e.g. more systematic nationwide monitoring for precursor and ozone formation over Indian region. -- Tropospheric ozone is an increasing threat to food production in India

A new approach to Ozone Depletion Potential (ODP) estimation

Science.gov (United States)

Portmann, R. W.; Daniel, J. S.; Yu, P.

2017-12-01

The Ozone Depletion Potential (ODP) is given by the time integrated global ozone loss of an ozone depleting substance (ODS) relative to a reference ODS (usually CFC-11). The ODP is used by the Montreal Protocol (and subsequent amendments) to inform policy decisions on the production of ODSs. Since the early 1990s, ODPs have usually been estimated using an approximate formulism that utilizes the lifetime and the fractional release factor of the ODS. This has the advantage that it can utilize measured concentrations of the ODSs to estimate their fractional release factors. However, there is a strong correlation between stratospheric lifetimes and fractional release factors of ODSs and that this can introduce uncertainties into ODP calculations when the terms are estimated independently. Instead, we show that the ODP is proportional to the average global ozone loss per equivalent chlorine molecule released in the stratosphere by the ODS loss process (which we call the Γ factor) and, importantly, this ratio varies only over a relatively small range ( 0.3-1.5) for ODPs with stratospheric lifetimes of 20 to more than 1,000 years. The Γ factor varies smoothly with stratospheric lifetime for ODSs with loss processes dominated by photolysis and is larger for long-lived species, while stratospheric OH loss processes produce relatively small Γs that are nearly independent of stratospheric lifetime. The fractional release approach does not accurately capture these relationships. We propose a new formulation that takes advantage of this smooth variation by parameterizing the Γ factor using ozone changes computed using the chemical climate model CESM-WACCM and the NOCAR two-dimensional model. We show that while the absolute Γ's vary between WACCM and NOCAR models, much of the difference is removed for the Γ/ΓCFC-11 ratio that is used in the ODP formula. This parameterized method simplifies the computation of ODPs while providing enhanced accuracy compared to the

Influence of isoprene chemical mechanism on modelled changes in tropospheric ozone due to climate and land use over the 21st century

Science.gov (United States)

Squire, O. J.; Archibald, A. T.; Griffiths, P. T.; Jenkin, M. E.; Smith, D.; Pyle, J. A.

2015-05-01

Isoprene is a~precursor to tropospheric ozone, a key pollutant and greenhouse gas. Anthropogenic activity over the coming century is likely to cause large changes in atmospheric CO2 levels, climate and land use, all of which will alter the global vegetation distribution leading to changes in isoprene emissions. Previous studies have used global chemistry-climate models to assess how possible changes in climate and land use could affect isoprene emissions and hence tropospheric ozone. The chemistry of isoprene oxidation, which can alter the concentration of ozone, is highly complex, therefore it must be parameterised in these models. In this work, we compare the effect of four different reduced isoprene chemical mechanisms, all currently used in Earth system models, on tropospheric ozone. Using a box model we compare ozone in these reduced schemes to that in a more explicit scheme (the Master Chemical Mechanism) over a range of NOx and isoprene emissions, through the use of O3 isopleths. We find that there is some variability, especially at high isoprene emissions, caused by differences in isoprene-derived NOx reservoir species. A global model is then used to examine how the different reduced schemes respond to potential future changes in climate, isoprene emissions, anthropogenic emissions and land use change. We find that, particularly in isoprene-rich regions, the response of the schemes varies considerably. The wide-ranging response is due to differences in the model descriptions of the peroxy radical chemistry, particularly their relative rates of reaction towards NO, leading to ozone formation, or HO2, leading to termination. Also important is the yield of isoprene nitrates and peroxyacyl nitrate precursors from isoprene oxidation. Those schemes that produce less of these NOx reservoir species, tend to produce more ozone locally and less away from the source region. We also note changes in other key oxidants such as NO3 and OH (due to the inclusion of

Impact of climate variability on tropospheric ozone

International Nuclear Information System (INIS)

Grewe, Volker

2007-01-01

A simulation with the climate-chemistry model (CCM) E39/C is presented, which covers both the troposphere and stratosphere dynamics and chemistry during the period 1960 to 1999. Although the CCM, by its nature, is not exactly representing observed day-by-day meteorology, there is an overall model's tendency to correctly reproduce the variability pattern due to an inclusion of realistic external forcings, like observed sea surface temperatures (e.g. El Nino), major volcanic eruption, solar cycle, concentrations of greenhouse gases, and Quasi-Biennial Oscillation. Additionally, climate-chemistry interactions are included, like the impact of ozone, methane, and other species on radiation and dynamics, and the impact of dynamics on emissions (lightning). However, a number of important feedbacks are not yet included (e.g. feedbacks related to biogenic emissions and emissions due to biomass burning). The results show a good representation of the evolution of the stratospheric ozone layer, including the ozone hole, which plays an important role for the simulation of natural variability of tropospheric ozone. Anthropogenic NO x emissions are included with a step-wise linear trend for each sector, but no interannual variability is included. The application of a number of diagnostics (e.g. marked ozone tracers) allows the separation of the impact of various processes/emissions on tropospheric ozone and shows that the simulated Northern Hemisphere tropospheric ozone budget is not only dominated by nitrogen oxide emissions and other ozone pre-cursors, but also by changes of the stratospheric ozone budget and its flux into the troposphere, which tends to reduce the simulated positive trend in tropospheric ozone due to emissions from industry and traffic during the late 80s and early 90s. For tropical regions the variability in ozone is dominated by variability in lightning (related to ENSO) and stratosphere-troposphere exchange (related to Northern Hemisphere Stratospheric

Economic evaluation of water loss saving due to the biological ...

African Journals Online (AJOL)

This paper focuses on water loss saving as the benefit derived from biological control of this plant between 1990 and 2013 at New Year's Dam, Alicedale, Eastern Cape, South Africa. Estimates of water loss due to evapotranspiration from water hyacinth vary significantly; therefore, the study used three different rates, high, ...

Influence of the ozone profile above Madrid (Spain) on Brewer estimation of ozone air mass factor

Energy Technology Data Exchange (ETDEWEB)

Anton, M. [Univ. de Extremadura, Badajoz (Spain). Dept. de Fisica; Evora Univ. (PT). Goephysics Centre of Evora (CGE); Lopez, M.; Banon, M. [Agenica Estatal de Meteorologia (AEMET), Madrid (Spain); Costa, M.J.; Silva, A.M. [Evora Univ. (PT). Goephysics Centre of Evora (CGE); Evora Univ. (Portugal). Dept. of Physics; Serrano, A. [Univ. de Extremadura, Badajoz (Spain). Dept. de Fisica; Bortoli, D. [Evora Univ. (PT). Goephysics Centre of Evora (CGE); Vilaplana, J.M. [Instituto Nacional de Tecnica Aeroespacial (INTA), Huelva (Spain). Estacion de Sondeos Atmosferico ' ' El Arenosillo' '

2009-07-01

The methodology used by Brewer spectroradiometers to estimate the ozone column is based on differential absorption spectroscopy. This methodology employs the ozone air mass factor (AMF) to derive the total ozone column from the slant path ozone amount. For the calculating the ozone AMF, the Brewer algorithm assumes that the ozone layer is located at a fixed height of 22 km. However, for a real specific site the ozone presents a certain profile, which varies spatially and temporally depending on the latitude, altitude and dynamical conditions of the atmosphere above the site of measurements. In this sense, this work address the reliability of the mentioned assumption and analyses the influence of the ozone profiles measured above Madrid (Spain) in the ozone AMF calculations. The approximated ozone AMF used by the Brewer algorithm is compared with simulations obtained using the libRadtran radiative transfer model code. The results show an excellent agreement between the simulated and the approximated AMF values for solar zenith angle lower than 75 . In addition, the relative differences remain lower than 2% at 85 . These good results are mainly due to the fact that the altitude of the ozone layer assumed constant by the Brewer algorithm for all latitudes notably can be considered representative of the real profile of ozone above Madrid (average value of 21.7{+-}1.8 km). The operational ozone AMF calculations for Brewer instruments are limited, in general, to SZA below 80 . Extending the usable SZA range is especially relevant for Brewer instruments located at high mid-latitudes. (orig.)

Ozone kinetics in low-pressure discharges

Science.gov (United States)

Guerra, Vasco; Marinov, Daniil; Guaitella, Olivier; Rousseau, Antoine

2012-10-01

Ozone kinetics is quite well established at atmospheric pressure, due to the importance of ozone in atmospheric chemistry and to the development of industrial ozone reactors. However, as the pressure is decreased and the dominant three-body reactions lose importance, the main mechanisms involved in the creation and destruction of ozone are still surrounded by important uncertainties. In this work we develop a self-consistent model for a pulsed discharge and its afterglow operating in a Pyrex reactor with inner radius 1 cm, at pressures in the range 1-5 Torr and discharge currents of 40-120 mA. The model couples the electron Boltzmann equation with a system of equations for the time evolution of the heavy particles. The calculations are compared with time-dependent measurements of ozone and atomic oxygen. Parametric studies are performed in order to clarify the role of vibrationally excited ozone in the overall kinetics and to establish the conditions where ozone production on the surface may become important. It is shown that vibrationally excited ozone does play a significant role, by increasing the time constants of ozone formation. Moreover, an upper limit for the ozone formation at the wall in these conditions is set at 10(-4).

Effect of ozone on photosynthesis and respiration of Scenedesmus obtusiusculus Chod. , with a general discussion of effects of air pollutants in plants

Energy Technology Data Exchange (ETDEWEB)

Verkroost, M

1974-01-01

In the present study the mode of action of the air pollutant ozone was investigated by studying its effects on photosynthesis, respiration and some biochemical and structural properties of the unicellular alga, Scenedesmus obtusiusculus CHOD. The extensive literature on the effects of the most important air pollutant gases SO/sub 2/, HF, NO/sub 2/, PAN and O/sub 3/ on the processes of photosynthesis and respiration is reviewed, while possible modes of action of each of these gases are discussed. The procedure for ozone exposure is extensively described. It is shown that photosynthesis and dark respiration are inhibited by previous exposure of the cell suspensions to ozone; the inhibition is increased with the duration of exposure and with temperature during exposure. The effect of an ozone treatment is increased by light during the exposure, and consequently, photosynthesis appears more inhibited in as much as the light-intensity during the preceding exposure to ozone was higher. It is shown that the chlorophyll content decreases by exposure to ozone; the decrease is more pronounced after exposure in the light than after exposure in the dark. It appeared in a preliminary study that there is a substantial loss of lipid in ozone-exposed algae, and there are indications that this in mainly due to oxidation of the unsaturated fatty acid, linoleic acid. A preliminary study showed that there is a very small loss of protein content in ozone-exposed algae, which may be ascribed mainly to oxidation of the acid component serine, and of an unidentified alkaline compound. In ozone exposed algae, ultrastructural changes are observed. 181 references, 21 figures, 11 tables.

"OZONE SOURCE APPORTIONMENT IN CMAQ' | Science ...

Science.gov (United States)

Ozone source attribution has been used to support various policy purposes including interstate transport (Cross State Air Pollution Rule) by U.S. EPA and ozone nonattainment area designations by State agencies. Common scientific applications include tracking intercontinental transport of ozone and ozone precursors and delineating anthropogenic and non-anthropogenic contribution to ozone in North America. As in the public release due in September 2013, CMAQ’s Integrated Source Apportionment Method (ISAM) attributes PM EC/OC, sulfate, nitrate, ammonium, ozone and its precursors NOx and VOC, to sectors/regions of users’ interest. Although the peroxide-to-nitric acid productions ratio has been the most common indicator to distinguish NOx-limited ozone production from VOC-limited one, other indicators are implemented in addition to allowing for an ensemble decision based on a total of 9 available indicator ratios. Moreover, an alternative approach of ozone attribution based on the idea of chemical sensitivity in a linearized system that has formed the basis of chemical treatment in forward DDM/backward adjoint tools has been implemented in CMAQ. This method does not require categorization into either ozone regime. In this study, ISAM will simulate the 2010 North America ozone using all of the above gas-phase attribution methods. The results are to be compared with zero-out difference out of those sectors in the host model runs. In addition, ozone contribution wil

When will the Antarctic Ozone Hole Recover?

Science.gov (United States)

Newman, Paul A.; Nash, Eric R.; Kawa, S. Randolph; Montzka, Steve

2006-01-01

The Antarctic ozone hole develops each year and culminates by early Spring. Antarctic ozone values have been monitored since 1979 using satellite observations from the .TOMS instrument. The severity of the hole has been assessed from TOMS using the minimum total ozone value from the October monthly mean (depth of the hole) and by calculating the average size during the September-October period. Ozone is mainly destroyed by halogen catalytic cycles, and these losses are modulated by temperature variations in the collar of the polar lower stratospheric vortex. In this presentation, we show the relationships of halogens and temperature to, both the size and depth of the hole. Because atmospheric halogen levels are responding to international agreements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Using projections of halogen levels combined with age-of-air estimates, we find that the ozone hole is recovering at an extremely slow rate and that large ozone holes will regularly recur over the next 2 decades. The ozone hole will begin to show first signs of recovery in about 2023, and the hole will fully recover to pre-1980 levels in approximately 2070. This 2070 recovery is 20 years later than recent projections.

7 CFR 610.12 - Equations for predicting soil loss due to water erosion.

Science.gov (United States)

2010-01-01

.... (a) The equation for predicting soil loss due to erosion for both the USLE and the RUSLE is A = R × K... 22161.) (b) The factors in the USLE equation are: (1) A is the estimation of average annual soil loss in... 7 Agriculture 6 2010-01-01 2010-01-01 false Equations for predicting soil loss due to water...

Ozone Depletion Caused by Rocket Engine Emissions: A Fundamental Limit on the Scale and Viability of Space-Based Geoengineering Schemes

Science.gov (United States)

Ross, M. N.; Toohey, D.

2008-12-01

Emissions from solid and liquid propellant rocket engines reduce global stratospheric ozone levels. Currently ~ one kiloton of payloads are launched into earth orbit annually by the global space industry. Stratospheric ozone depletion from present day launches is a small fraction of the ~ 4% globally averaged ozone loss caused by halogen gases. Thus rocket engine emissions are currently considered a minor, if poorly understood, contributor to ozone depletion. Proposed space-based geoengineering projects designed to mitigate climate change would require order of magnitude increases in the amount of material launched into earth orbit. The increased launches would result in comparable increases in the global ozone depletion caused by rocket emissions. We estimate global ozone loss caused by three space-based geoengineering proposals to mitigate climate change: (1) mirrors, (2) sunshade, and (3) space-based solar power (SSP). The SSP concept does not directly engineer climate, but is touted as a mitigation strategy in that SSP would reduce CO2 emissions. We show that launching the mirrors or sunshade would cause global ozone loss between 2% and 20%. Ozone loss associated with an economically viable SSP system would be at least 0.4% and possibly as large as 3%. It is not clear which, if any, of these levels of ozone loss would be acceptable under the Montreal Protocol. The large uncertainties are mainly caused by a lack of data or validated models regarding liquid propellant rocket engine emissions. Our results offer four main conclusions. (1) The viability of space-based geoengineering schemes could well be undermined by the relatively large ozone depletion that would be caused by the required rocket launches. (2) Analysis of space- based geoengineering schemes should include the difficult tradeoff between the gain of long-term (~ decades) climate control and the loss of short-term (~ years) deep ozone loss. (3) The trade can be properly evaluated only if our

Assessment of ozone impacts on vegetation in southern Africa and directions for future research

CSIR Research Space (South Africa)

Van Tienhoven, AM

2005-03-01

Full Text Available in the high ozone levels measured at the beginning of the southern African summer.17,23,24 The concentrations of ozone precursors, the complex production and removal pro- cesses, and the short lifespan of ozone, mean that ozone concentration in the atmosphere... jointoformextensiveareasofchlorosisas the leaf ages. Damage to foliage can be extensive enough to cause complete loss ofleafycropssuchaslettuceandchicory.39 Visible symptoms of ozone effects must be interpreted with caution, particularly in field studies where interactions...

Co-ordinated ozone and UV project COZUV

International Nuclear Information System (INIS)

Braathen, Geir

1999-01-01

The project encompasses all the major Norwegian research groups in the field of stratospheric ozone and UV research. the duration is from the 1st January 1999 to the 31st December 2000. The tasks carried out will include investigations of the ozone layer over the North Polar and middle latitudes, 3-D chemical modelling, diagnosis of chemical ozone loss, investigations of transport mechanisms between the polar vortex and middle latitudes, study of the coupling between ozone change and climate change in the stratosphere and upper troposphere, scenario calculations in order to investigate the consequences of temperature change in the stratosphere, development of methods to measure global, direct and radiance distribution of UV, to improve UV dose calculations, investigate the influence of clouds on the surface UV radiation and to use existing surface UV radiation measurements together with existing radiation models to investigate the connection between UV radiation and ozone, clouds and surface albedo. The results will be published in various publications, progress reports, by participation in international conferences, through information to the environmental authorities and through information on the Internet

Characterization of N-nitrosodimethylamine formation from the ozonation of ranitidine.

Science.gov (United States)

Lv, Juan; Wang, Lin; Li, Yongmei

2017-08-01

N-nitrosodimethylamine (NDMA) is an emerging disinfection by-product which is formed during water disinfection in the presence of amine-based precursors. Ranitidine, as one kind of amine-based pharmaceuticals, has been identified as NDMA precursor with high NDMA molar conversion during chloramination. This study focused on the characterization of NDMA formation during ozonation of ranitidine. Influences of operational variables (ozone dose, pH value) and water matrix on NDMA generation as well as ranitidine degradation were evaluated. The results indicate high reactivity of ranitidine with ozone. Dimethylamine (DMA) and NDMA were generated due to ranitidine oxidation. High pH value caused more NDMA accumulation. NDMA formation was inhibited under acid conditions (pH≤5) mainly due to the protonation of amines. Water matrix such as HCO 3 - and humic acid impacted NDMA generation due to OH scavenging. Compared with OH, ozone molecules dominated the productions of DMA and NDMA. However, OH was a critical factor in NDMA degradation. Transformation products of ranitidine during ozonation were identified using gas chromatography-mass spectrometry. Among these products, just DMA and N,N-dimethylformamide could contribute to NDMA formation due to the DMA group in the molecular structures. The NDMA formation pathway from ranitidine ozonation was also proposed. Copyright © 2017. Published by Elsevier B.V.

Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models

Directory of Open Access Journals (Sweden)

V. Eyring

2010-10-01

Full Text Available Projections of stratospheric ozone from a suite of chemistry-climate models (CCMs have been analyzed. In addition to a reference simulation where anthropogenic halogenated ozone depleting substances (ODSs and greenhouse gases (GHGs vary with time, sensitivity simulations with either ODS or GHG concentrations fixed at 1960 levels were performed to disaggregate the drivers of projected ozone changes. These simulations were also used to assess the two distinct milestones of ozone returning to historical values (ozone return dates and ozone no longer being influenced by ODSs (full ozone recovery. The date of ozone returning to historical values does not indicate complete recovery from ODSs in most cases, because GHG-induced changes accelerate or decelerate ozone changes in many regions. In the upper stratosphere where CO₂-induced stratospheric cooling increases ozone, full ozone recovery is projected to not likely have occurred by 2100 even though ozone returns to its 1980 or even 1960 levels well before (~2025 and 2040, respectively. In contrast, in the tropical lower stratosphere ozone decreases continuously from 1960 to 2100 due to projected increases in tropical upwelling, while by around 2040 it is already very likely that full recovery from the effects of ODSs has occurred, although ODS concentrations are still elevated by this date. In the midlatitude lower stratosphere the evolution differs from that in the tropics, and rather than a steady decrease in ozone, first a decrease in ozone is simulated from 1960 to 2000, which is then followed by a steady increase through the 21st century. Ozone in the midlatitude lower stratosphere returns to 1980 levels by ~2045 in the Northern Hemisphere (NH and by ~2055 in the Southern Hemisphere (SH, and full ozone recovery is likely reached by 2100 in both hemispheres. Overall, in all regions except the tropical lower stratosphere, full ozone recovery from ODSs occurs significantly later than the

Attribution of ozone changes to dynamical and chemical processes in CCMs and CTMs

Directory of Open Access Journals (Sweden)

H. Garny

2011-04-01

Full Text Available Chemistry-climate models (CCMs are commonly used to simulate the past and future development of Earth's ozone layer. The fully coupled chemistry schemes calculate the chemical production and destruction of ozone interactively and ozone is transported by the simulated atmospheric flow. Due to the complexity of the processes acting on ozone it is not straightforward to disentangle the influence of individual processes on the temporal development of ozone concentrations. A method is introduced here that quantifies the influence of chemistry and transport on ozone concentration changes and that is easily implemented in CCMs and chemistry-transport models (CTMs. In this method, ozone tendencies (i.e. the time rate of change of ozone are partitioned into a contribution from ozone production and destruction (chemistry and a contribution from transport of ozone (dynamics. The influence of transport on ozone in a specific region is further divided into export of ozone out of that region and import of ozone from elsewhere into that region. For this purpose, a diagnostic is used that disaggregates the ozone mixing ratio field into 9 separate fields according to in which of 9 predefined regions of the atmosphere the ozone originated. With this diagnostic the ozone mass fluxes between these regions are obtained. Furthermore, this method is used here to attribute long-term changes in ozone to chemistry and transport. The relative change in ozone from one period to another that is due to changes in production or destruction rates, or due to changes in import or export of ozone, are quantified. As such, the diagnostics introduced here can be used to attribute changes in ozone on monthly, interannual and long-term time-scales to the responsible mechanisms. Results from a CCM simulation are shown here as examples, with the main focus of the paper being on introducing the method.

Apparent losses due to domestic water meter under-registration in ...

African Journals Online (AJOL)

By combining these results with the average age of meters in South Africa, estimated from the National Water Demand Archive, it was possible to estimate the average meter under-registration due to meter aging. The study concluded that apparent losses due to water meter under-registration are around 5% of consumption ...

Chemistry, Dynamics, and Radiation of Ozone Loss: Airborne Measurements of OH, HO2, N02, Cl0, BrO, IO, ClON02, BrON02, CIOOCl, and H2O

Science.gov (United States)

Anderson, James G.

2005-01-01

This research addresses, through a combination of in situ and remote aircraft-borne Which mechanisms are responsible for the continuing erosion of ozone over midlatitudes of the Northern Hemisphere? Will the rapid loss of ozone over the Arctic in late winter continue to worsen over the next two decades? Are these large losses dynamically coupled to midlatitudes? Which mechanisms dictate the rate of exchange of material between the troposphere and stratosphere? How will these processes change in response to changes in climate? Will regional scale pollution episodes, that are emerging as predictable seasonal events, significantly affect the middle-to-upper troposphere chemical composition. If so, how will these changes alter the chemical composition of the middle world? What changes are predicted for the overworld? Why has the arctic stratosphere become colder in the late winter phase in recent years? Have increases in tropical upper troposphere temperatures increased the temperature gradient such as to change the trajectories of vertically propagating waves, thus reducing the effectiveness of the meridional circulation for transport of heat, momentum and ozone from the tropics to high latitudes?

Post-treatment of Fly Ash by Ozone in a Fixed Bed Reactor

DEFF Research Database (Denmark)

Pedersen, Kim Hougaard; Melia, M. C.; Jensen, Anker Degn

2009-01-01

to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O-3/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data....... prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found...

Ozone exposure affects leaf wettability and tree water balance

NARCIS (Netherlands)

Schreuder, M.D.J.; Hove, van L.W.A.; Brewer, C.A.

2001-01-01

Relatively little is known about the influences of growing-season background ozone (O3) concentrations on leaf cuticles and foliar water loss. Using fumigation chambers, leaf wettability and foliar water loss were studied in two poplar species, Populus nigra and P. euramericana, and a conifer,

Terrestrial ozone depletion due to a Milky Way gamma-ray burst

Science.gov (United States)

Thomas, Brian C.

Gamma-Ray Bursts (GRBs) are short, incredibly powerful astrophysical events which produce a flux of radiation detectable across the observable universe. A GRB within our own galaxy could cause major damage to the Earth's biosphere. Rate estimates suggest that at least one GRB has occurred within a dangerous range (about 2 kpc) in the last billion years. The gamma radiation from such a burst would quickly deplete much of the Earth's protective ozone layer, allowing an increase in solar UVB radiation reaching the surface. This radiation is harmful to life, causing sunburn and damaging DNA. In addition, NO 2 produced in the atmosphere would cause a decrease in visible sunlight reaching the surface and could cause global cooling. Nitric acid rain could stress portions of the biosphere, but the increased nitrate deposition could be helpful to land plants. We have used a two-dimensional atmospheric model to investigate the effects on the Earth's atmosphere of a GRB. We have simulated bursts delivering a range of fluences, at various latitudes, at the equinoxes and solstices, and at different times of day. We have computed DNA damage caused by increased solar UVB radiation, reduction in solar visible light due to NO 2 opacity; and deposition of nitrates through rainout of HNO 3 . For a "typical" burst in the last billion years, we find globally averaged ozone depletion up to 38%. Localized depletion reaches as much as 74%. Significant global depletion (at least 10%) persists up to about 7 years after the burst. Our results depend strongly on time of year and latitude over which the burst occurs. We find DNA damage of up to 16 times the normal annual global average, with greatest damage occurring at low to mid latitudes. We find reductions in visible sunlight of a few percent, primarily in the polar regions. Nitrate deposition similar to or slightly greater than that currently caused by lightning is also observed. We find support in our results for the hypothesis that the

Drift-corrected Odin-OSIRIS ozone product: algorithm and updated stratospheric ozone trends

Directory of Open Access Journals (Sweden)

A. E. Bourassa

2018-01-01

Full Text Available A small long-term drift in the Optical Spectrograph and Infrared Imager System (OSIRIS stratospheric ozone product, manifested mostly since 2012, is quantified and attributed to a changing bias in the limb pointing knowledge of the instrument. A correction to this pointing drift using a predictable shape in the measured limb radiance profile is implemented and applied within the OSIRIS retrieval algorithm. This new data product, version 5.10, displays substantially better both long- and short-term agreement with Microwave Limb Sounder (MLS ozone throughout the stratosphere due to the pointing correction. Previously reported stratospheric ozone trends over the time period 1984–2013, which were derived by merging the altitude–number density ozone profile measurements from the Stratospheric Aerosol and Gas Experiment (SAGE II satellite instrument (1984–2005 and from OSIRIS (2002–2013, are recalculated using the new OSIRIS version 5.10 product and extended to 2017. These results still show statistically significant positive trends throughout the upper stratosphere since 1997, but at weaker levels that are more closely in line with estimates from other data records.

Detecting the Recovery of the Antarctic Ozone Hole

Science.gov (United States)

Newman, Paul A.; Nash, Eric R.; Kawa, S. Randolph; Montzka, Steve

2004-01-01

The Antarctic ozone hole develops each year and culminates by early Spring. Antarctic ozone values have been monitored since 1979 using satellite observations from the TOMS instrument. The severity of the hole has been assessed from TOMS using the minimum total ozone value from the October monthly mean (depth of the hole) and by calculating the average size during the September-October period. Ozone is mainly destroyed by halogen catalytic cycles, and these losses are modulated by temperature variations in the collar of the polar lower stratospheric vortex. In this presentation, we show the relationships of halogens and temperature to both the size and depth of the hole. Because atmospheric halogen levels are responding to international agreements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Using projections of halogen levels combined with age-of-air estimates, we find that the ozone hole is recovering at an extremely slow rate and that large ozone holes will regularly recur over the next 2 decades. We will show estimates of both when the ozone hole will begin to show first signs of recovery, and when the hole will fully recover to pre-1980 levels.

Cooling tower water conditioning study. [using ozone

Science.gov (United States)

Humphrey, M. F.; French, K. R.

1979-01-01

Successful elimination of cooling tower treatment chemicals was demonstrated. Three towers functioned for long periods of time with ozone as the only treatment for the water. The water in the systems was reused as much as 30 times (cycles of concentration) without deleterious effects to the heat exchangers. Actual system blow-down was eliminated and the only makeup water added was that required to replace the evaporation and mist entrainment losses. Minimum water savings alone are approximately 75.1 1/kg/year. Cost estimates indicate that a savings of 55 percent was obtained on the systems using ozone. A major problem experienced in the use of ozone for cooling tower applications was the difficulty of accurate concentration measurements. The ability to control the operational characteristics relies on easily and accurately determined concentration levels. Present methods of detection are subject to inaccuracies because of interfering materials and the rapid destruction of the ozone.

Ecosystem-scale trade-offs between impacts of ozone and reactive nitrogen

Science.gov (United States)

Rowe, Ed; Hayes, Felicity; Sawicka, Kasia; Mills, Gina; Jones, Laurence; Moldan, Filip; Sereina, Bassin; van Dijk, Netty; Evans, Chris

2015-04-01

Nitrogen (N) deposition stimulates plant productivity in many terrestrial ecosystems. This is clearly beneficial for production agriculture and forestry, but increased litterfall and decreased ground-level light availability reduce the suitability of habitats for many biota (Jones et al., 2014). This mechanism (Hautier et al., 2009), together with the acidifying effects of N (Stevens et al., 2010), has caused considerable biodiversity loss at global scale. Ozone, by contrast, has the effect of reducing plant production, and a simple assessment would suggest that this might mitigate the effects of N pollution. We explored the interactions between ozone and nitrogen at mechanistic level using a version of the MADOC model (Rowe et al., 2014) modified to include effects of ozone. The model was tested against data from long-term monitoring and experimental sites with a focus on nitrogen and/or ozone effects. Effects on biodiversity were assessed by coupling the MADOC model to the MultiMOVE plant species model. We used this model-chain to explore trade-offs and synergies between the impacts of nitrogen and ozone on biodiversity and ecosystem biogeochemistry. In a review of the effects of ozone on ecosystem processes, two consistent effects were found: decreased net primary production due to damage to photosynthetic mechanisms; and an increase in litter nitrogen apparently caused by interference of ozone with the retranslocation process (Mills, in prep.). Insufficient evidence was found to justify inclusion of posited interactive mechanisms such as increased ozone susceptibility with greater nitrogen supply. However, the MADOC model illustrated emergent ozone-nitrogen interactions at ecosystem scale, for example an increase in N leaching due to decreased plant demand and greater litter N content. Empirical evidence for interactive effects of nitrogen and ozone at ecosystem scale is severely lacking, but simulated results were consistent with soil and soil solution

Global assessment of human losses due to earthquakes

Science.gov (United States)

Silva, Vitor; Jaiswal, Kishor; Weatherill, Graeme; Crowley, Helen

2014-01-01

Current studies have demonstrated a sharp increase in human losses due to earthquakes. These alarming levels of casualties suggest the need for large-scale investment in seismic risk mitigation, which, in turn, requires an adequate understanding of the extent of the losses, and location of the most affected regions. Recent developments in global and uniform datasets such as instrumental and historical earthquake catalogues, population spatial distribution and country-based vulnerability functions, have opened an unprecedented possibility for a reliable assessment of earthquake consequences at a global scale. In this study, a uniform probabilistic seismic hazard assessment (PSHA) model was employed to derive a set of global seismic hazard curves, using the open-source software OpenQuake for seismic hazard and risk analysis. These results were combined with a collection of empirical fatality vulnerability functions and a population dataset to calculate average annual human losses at the country level. The results from this study highlight the regions/countries in the world with a higher seismic risk, and thus where risk reduction measures should be prioritized.

Energy losses in magnetically insulated transmission lines due to microparticles

International Nuclear Information System (INIS)

Gray, E.W.; Stinnett, R.W.

1987-01-01

We discuss the effects of high-velocity and hypervelocity microparticles in the magnetically insulated transmission lines of multiterawatt accelerators used for particle beam fusion and radiation effects simulation. These microparticles may be a possible source for plasma production near the anode and cathode in early stages of the voltage pulse, and current carriers during and after the power pulse, resulting in power flow losses. Losses in the current pulse, due to microparticles, are estimated to be approximately 12 mA/cm 2 (0.3 kA) as a lower limit, and --0.3 A/cm 2 (7.2 kA) for microparticle initiated, anode plasma positive ion transport. We have calculated the velocities reached by these microparticles and the effects on them of Van der Waals forces. Field emission from the particles and their effects on cathode and anode plasma formation have been examined. Particle collision with the electrodes is also examined in terms of plasma production, as in the electron deposition in the particles in transit across the anode-cathode gap. Blistering of the electrode surface, thought to be due to H - bombardment was also observed and appears to be consistent with losses due to negative ions previously reported by J. P. VanDevender, R. W. Stinnett, and R. J. Anderson [App. Phys. Lett. 38, 229 (1981)

Vortex-averaged Arctic ozone depletion in the winter 2002/2003

Directory of Open Access Journals (Sweden)

T. Christensen

2005-01-01

Full Text Available A total ozone depletion of 68±7 Dobson units between 380 and 525K from 10 December 2002 to 10 March 2003 is derived from ozone sonde data by the vortex-average method, taking into account both diabatic descent of the air masses and transport of air into the vortex. When the vortex is divided into three equal-area regions, the results are 85±9DU for the collar region (closest to the edge, 52±5DU for the vortex centre and 68±7DU for the middle region in between centre and collar. Our results compare well with other studies: We find good agreement with ozone loss deduced from SAOZ data, with results inferred from POAM III observations and with results from tracer-tracer correlations using HF as the long-lived tracer. We find a higher ozone loss than that deduced by tracer-tracer correlations using CH4. We have made a careful comparison with Match results: The results were recalculated using a common time period, vortex edge definition and height interval. The two methods generally compare very well, except at the 475K level which exhibits an unexplained discrepancy.

Impact of climate change on tropospheric ozone and its global budgets

Directory of Open Access Journals (Sweden)

G. Zeng

2008-01-01

Full Text Available We present the chemistry-climate model UM_CAM in which a relatively detailed tropospheric chemical module has been incorporated into the UK Met Office's Unified Model version 4.5. We obtain good agreements between the modelled ozone/nitrogen species and a range of observations including surface ozone measurements, ozone sonde data, and some aircraft campaigns.

Four 2100 calculations assess model responses to projected changes of anthropogenic emissions (SRES A2, climate change (due to doubling CO₂, and idealised climate change-associated changes in biogenic emissions (i.e. 50% increase of isoprene emission and doubling emissions of soil-NO_x. The global tropospheric ozone burden increases significantly for all the 2100 A2 simulations, with the largest response caused by the increase of anthropogenic emissions. Climate change has diverse impacts on O₃ and its budgets through changes in circulation and meteorological variables. Increased water vapour causes a substantial ozone reduction especially in the tropical lower troposphere (>10 ppbv reduction over the tropical ocean. On the other hand, an enhanced stratosphere-troposphere exchange of ozone, which increases by 80% due to doubling CO₂, contributes to ozone increases in the extratropical free troposphere which subsequently propagate to the surface. Projected higher temperatures favour ozone chemical production and PAN decomposition which lead to high surface ozone levels in certain regions. Enhanced convection transports ozone precursors more rapidly out of the boundary layer resulting in an increase of ozone production in the free troposphere. Lightning-produced NO_x increases by about 22% in the doubled CO₂ climate and contributes to ozone production.

The response to the increase of isoprene emissions shows that the change of ozone is largely determined by background NO_x levels: high

Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data

Directory of Open Access Journals (Sweden)

B. Sauvage

2005-01-01

Full Text Available We analyze ozone observations recorded over Equatorial Africa between April 1997 and March 2003 by the MOZAIC programme, providing the first ozone climatology deriving from continental in-situ data over this region. Three-dimensional streamlines strongly suggests connections between the characteristics of the ozone monthly mean vertical profiles, the most persistent circulation patterns in the troposphere over Equatorial Africa (on a monthly basis such as the Harmattan, the African Easterly Jet, the Trades and the regions of ozone precursors emissions by biomass burning. During the biomass burning season in each hemisphere, the lower troposphere exhibits layers of enhanced ozone (i.e. 70 ppbv over the coast of Gulf of Guinea in December-February and 85 ppbv over Congo in June-August. The characteristics of the ozone monthly mean vertical profiles are clearly connected to the regional flow regime determined by seasonal dynamic forcing. The mean ozone profile over the coast of Gulf of Guinea in the burning season is characterized by systematically high ozone below 650hPa ; these are due to the transport by the Harmattan and the AEJ of the pollutants originating from upwind fires. The confinement of high ozone to the lower troposphere is due to the high stability of the Harmattan and the blocking Saharan anticyclone which prevents efficient vertical mixing. In contrast, ozone enhancements observed over Central Africa during the local dry season (June-August are not only found in the lower troposphere but throughout the troposphere. Moreover, this study highlights a connection between the regions of the coast of Gulf of Guinea and regions of Congo to the south that appears on a semi annual basis. Vertical profiles in wet-season regions exhibit ozone enhancements in the lower troposphere due to biomass burning products transport from fires situated in the opposite dry-season hemisphere.

Development of a climate record of tropospheric and stratospheric column ozone from satellite remote sensing: evidence of an early recovery of global stratospheric ozone

Directory of Open Access Journals (Sweden)

J. R. Ziemke

2012-07-01

Full Text Available Ozone data beginning October 2004 from the Aura Ozone Monitoring Instrument (OMI and Aura Microwave Limb Sounder (MLS are used to evaluate the accuracy of the Cloud Slicing technique in effort to develop long data records of tropospheric and stratospheric ozone and for studying their long-term changes. Using this technique, we have produced a 32-yr (1979–2010 long record of tropospheric and stratospheric column ozone from the combined Total Ozone Mapping Spectrometer (TOMS and OMI. Analyses of these time series suggest that the quasi-biennial oscillation (QBO is the dominant source of inter-annual variability of stratospheric ozone and is clearest in the Southern Hemisphere during the Aura time record with related inter-annual changes of 30–40 Dobson Units. Tropospheric ozone for the long record also indicates a QBO signal in the tropics with peak-to-peak changes varying from 2 to 7 DU. The most important result from our study is that global stratospheric ozone indicates signature of a recovery occurring with ozone abundance now approaching the levels of year 1980 and earlier. The negative trends in stratospheric ozone in both hemispheres during the first 15 yr of the record are now positive over the last 15 yr and with nearly equal magnitudes. This turnaround in stratospheric ozone loss is occurring about 20 yr earlier than predicted by many chemistry climate models. This suggests that the Montreal Protocol which was first signed in 1987 as an international agreement to reduce ozone destroying substances is working well and perhaps better than anticipated.

Application of computational fluid dynamics modelling to an ozone ...

African Journals Online (AJOL)

driniev

2004-01-01

Jan 1, 2004 ... Turbulent kinetic energy m2·s-2 km. Disinfection rate constant for .... modelling the kinetic reactions to achieve the most efficient use of the ozone dosed to the system. The USEPA techniques .... be globally categorised into off-gas losses, consumption, and loss by self-decomposition. (Bredtmann, 1982).

Quantifying the contributions to stratospheric ozone changes from ozone depleting substances and greenhouse gases

Directory of Open Access Journals (Sweden)

D. A. Plummer

2010-09-01

Full Text Available A state-of-the-art chemistry climate model coupled to a three-dimensional ocean model is used to produce three experiments, all seamlessly covering the period 1950–2100, forced by different combinations of long-lived Greenhouse Gases (GHGs and Ozone Depleting Substances (ODSs. The experiments are designed to quantify the separate effects of GHGs and ODSs on the evolution of ozone, as well as the extent to which these effects are independent of each other, by alternately holding one set of these two forcings constant in combination with a third experiment where both ODSs and GHGs vary. We estimate that up to the year 2000 the net decrease in the column amount of ozone above 20 hPa is approximately 75% of the decrease that can be attributed to ODSs due to the offsetting effects of cooling by increased CO₂. Over the 21st century, as ODSs decrease, continued cooling from CO₂ is projected to account for more than 50% of the projected increase in ozone above 20 hPa. Changes in ozone below 20 hPa show a redistribution of ozone from tropical to extra-tropical latitudes with an increase in the Brewer-Dobson circulation. In addition to a latitudinal redistribution of ozone, we find that the globally averaged column amount of ozone below 20 hPa decreases over the 21st century, which significantly mitigates the effect of upper stratospheric cooling on total column ozone. Analysis by linear regression shows that the recovery of ozone from the effects of ODSs generally follows the decline in reactive chlorine and bromine levels, with the exception of the lower polar stratosphere where recovery of ozone in the second half of the 21st century is slower than would be indicated by the decline in reactive chlorine and bromine concentrations. These results also reveal the degree to which GHG-related effects mute the chemical effects of N₂O on ozone in the standard future scenario used for the WMO Ozone Assessment. Increases in the

Development of a sensitive passive sampler using indigotrisulfonate for the determination of tropospheric ozone.

Science.gov (United States)

Garcia, Gabriel; Allen, Andrew George; Cardoso, Arnaldo Alves

2010-06-01

A new sampling and analytical design for measurement of ambient ozone is presented. The procedure is based on ozone absorption and decoloration (at 600 nm) of indigotrisulfonate dye, where ozone adds itself across the carbon-carbon double bond of the indigo. A mean relative standard deviation of 8.6% was obtained using samplers exposed in triplicate, and a correlation coefficient (r) of 0.957 was achieved in parallel measurements using the samplers and a commercial UV ozone instrument. The devices were evaluated in a measurement campaign, mapping spatial and temporal trends of ozone concentrations in a region of southeast Brazil strongly influenced by seasonal agricultural biomass burning, with associated emissions of ozone precursors. Ozone concentrations were highest in rural areas and lowest at an urban site, due to formation during downwind transport and short-term depletion due to titration with nitric oxide. Ozone concentrations showed strong seasonal trends, due to the influences of precursor emissions, relative humidity and solar radiation intensity. Advantages of the technique include ease and speed of use, the ready availability of components, and excellent sensitivity. Achievable temporal resolution of ozone concentrations is 8 hours at an ambient ozone concentration of 3.8 ppb, or 2 hours at a concentration of 15.2 ppb.

The Ecophysiology Of A Pinus Ponderosa Ecosystem Exposed To High Tropospheric Ozone: Implications For Stomatal And Non-Stomatal Ozone Fluxes

Science.gov (United States)

Fares, S.; McKay, M.; Goldstein, A.

2008-12-01

Ecosystems remove ozone from the troposphere through both stomatal and non-stomatal deposition. The portion of ozone taken up through stomata has an oxidative effect causing damage. We used a multi-year dataset to assess the physiological controls over ozone deposition. Environmental parameters, CO2 and ozone fluxes were measured continuously from January 2001 to December 2006 above a ponderosa pine plantation near Blodgett Forest, Georgetown, California. We studied the dynamic of NEE (Net Ecosystem Exchange, -838 g C m-2 yr-1) and water evapotranspiration on an annual and daily basis. These processes are tightly coupled to stomatal aperture which also controlled ozone fluxes. High levels of ozone concentrations (~ 100 ppb) were observed during the spring-summer period, with corresponding high levels of ozone fluxes (~ 30 μmol m-2 h-1). During the summer season, a large portion of the total ozone flux was due to non-stomatal processes, and we propose that a plant physiological control, releasing BVOC (Biogenic Volatile Organic Compounds), is mainly responsible. We analyzed the correlations of common ozone exposure metrics based on accumulation of concentrations (AOT40 and SUM0) with ozone fluxes (total, stomatal and non-stomatal). Stomatal flux showed poorer correlation with ozone concentrations than non-stomatal flux during summer and fall seasons, which largely corresponded to the growing period. We therefore suggest that AOT40 and SUM0 are poor predictors of ozone damage and that a physiologically based metric would be more effective.

On the Climate Impacts of Upper Tropospheric and Lower Stratospheric Ozone

Science.gov (United States)

Xia, Yan; Huang, Yi; Hu, Yongyun

2018-01-01

The global warming simulations of the general circulation models (GCMs) are generally performed with different ozone prescriptions. We find that the differences in ozone distribution, especially in the upper tropospheric and lower stratospheric (UTLS) region, account for important model discrepancies shown in the ozone-only historical experiment of the Coupled Model Intercomparison Project Phase 5 (CMIP5). These discrepancies include global high cloud fraction, stratospheric temperature, and stratospheric water vapor. Through a set of experiments conducted by an atmospheric GCM with contrasting UTLS ozone prescriptions, we verify that UTLS ozone not only directly radiatively heats the UTLS region and cools the upper parts of the stratosphere but also strongly influences the high clouds due to its impact on relative humidity and static stability in the UTLS region and the stratospheric water vapor due to its impact on the tropical tropopause temperature. These consequences strongly affect the global mean effective radiative forcing of ozone, as noted in previous studies. Our findings suggest that special attention should be paid to the UTLS ozone when evaluating the climate effects of ozone depletion in the 20th century and recovery in the 21st century. UTLS ozone difference may also be important for understanding the intermodel discrepancy in the climate projections of the CMIP6 GCMs in which either prescribed or interactive ozone is used.

Elastic uplift in southeast Greenland due to rapid ice mass loss

DEFF Research Database (Denmark)

Khan, Shfaqat Abbas; Van dam, Tonie; Hamilton, Gordon S.

2007-01-01

The rapid unloading of ice from the southeastern sector of the Greenland ice sheet between 2001 and 2006 caused an elastic uplift of 35 mm at a GPS site in Kulusuk. Most of the uplift results from ice dynamic-induced volume losses on two nearby outlet glaciers. Volume loss from Helheim Glacier...... between 62N and 66N. Citation: Khan, S. A., J. Wahr, L. A. Stearns, G. S. Hamilton, T. van Dam, K. M. Larson, and O. Francis (2007), Elastic uplift in southeast Greenland due to rapid ice mass loss....

Treatability study of the effluent containing reactive blue 21 dye by ozonation and the mass transfer study of ozone

Science.gov (United States)

Velpula, Priyadarshini; Ghuge, Santosh; Saroha, Anil K.

2018-04-01

Ozonation is a chemical treatment process in which ozone reacts with the pollutants present in the effluent by infusion of ozone into the effluent. This study includes the effect of various parameters such as inlet ozone dose, pH of solution and initial concentration of dye on decolorization of dye in terms CRE. The maximum CRE of 98.62% with the reaction rate constant of 0.26 min-1 is achieved in 18 minutes of reaction time at inlet ozone dose of 11.5 g/m3, solution pH of 11 and 30 mg/L of initial concentration of dye. The presence of radical scavenger (Tertiary Butyl Alcohol) suppressed the CRE from 98.62% to 95.4% at high pH values indicates that the indirect mechanism dominates due to the presence of hydroxyl radicals which are formed by the decomposition of ozone. The diffusive and convective mass transfer coefficients of ozone are calculated as 1.78 × 10-5 cm2/sec and 0.075 min-1. It is observed that the fraction of resistance offered by liquid is very much high compared to gas phase indicates that the ozonation is a liquid phase mass transfer controlled operation.

Foreign and Domestic Contributions to Springtime Ozone Pollution over China

Science.gov (United States)

Ni, R.; Lin, J.; Yan, Y.; Lin, W.; Chen, H.

2017-12-01

Ozone is a critical air pollutant that damages human health and vegetation. Previous studies for the United States and Europe have shown large influences of foreign emissions on domestic ozone levels, whereas the relative contributions of foreign versus domestic emissions are much less clear for China. Here, we use a global-regional two-way coupled model system based on GEOS-Chem to quantify the contributions to springtime ozone over China from anthropogenic emissions in major source regions across the globe. Our results indicate considerable influences of foreign anthropogenic pollution on China's ozone pollution. Together, foreign anthropogenic emissions enhance springtime surface ozone over China by 3 12 ppb. Of all ozone over China produced by global anthropogenic emissions, foreign emissions contribute 40% near the surface, and the contribution increases with altitude until a value of 80% in the upper troposphere. Impact from Japan and Korea is 1 2 ppb over east coastal regions, and negligible in inland. Anthropogenic emissions of South and South-East Asia increase ozone over Tibet and the Yunnan-Guizhou Plateau by up to 5 ppb, and their contribution increases with height due to strong vertical transport. Pollution from North America and Europe mainly accompanies strong westerly winds and frequent cyclonic activities that are favorable to long-range transport. European anthropogenic pollution enhances surface ozone by 1 3 ppb over West and North China. Despite a much longer transport distance, the contribution from North America is greater than European contribution due to the nearly doubled amount of anthropogenic NMVOC emissions. The high percentage contribution of foreign anthropogenic emissions to China's ozone pollution can be partly explained by excessive domestic NOx emissions that suppress ozone production efficiency and even destroy ozone. Our study is relevant to Chinese ozone pollution control and global environmental protection collaboration.

Combination of ozone and packaging treatments maintained the quality and improved the shelf life of tomato fruit

Science.gov (United States)

Zainuri; Jayaputra; Sauqi, A.; Sjah, T.; Desiana, R. Y.

2018-01-01

Tomato is very important vegetable crop but has short shelf life. The objective of this research was to determine the effect of ozone and packaging combination treatment on the quality and the storage life of tomato fruit. There were six treatments including: control (without ozone and packaging); without ozone and packaged with polyethylene bag; without ozone and polyethylene terephtalate punnet; with ozone but without packaging; with ozone and packaged with polyethylene bag; and with ozone and polyethylene terephtalate punnet. Each treatment was made into 3 replications. Tomato samples were harvested at turning stage. Ozone treatment was applied for 60 seconds. Tomatoes were then treated with and without packaging. The fruit were then stored at room temperature for up to 12 days. The parameters for assessment were water content, color, texture, weight loss and the population of naturally contamination Escherichia coli. Each parameter was assessed on day 0, 6 and 12 of storage. The results indicated that combination of ozone and packaging treatments significantly affected the physical and biochemical changes (water content, color, texture and weight loss) of the fruit, suppressed the microbiological contamination on the fruit and maintained fruit freshness or quality after 12 days of storage. The combination of ozone and perforated polyethylene packaging treatment was the best treatment to maintain the quality and prolonged the shelf life of tomato fruit to be 12 days at room temperature.

Stratospheric ozone intrusion events and their impacts on tropospheric ozone in the Southern Hemisphere

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J. W. Greenslade

2017-09-01

Full Text Available Stratosphere-to-troposphere transport (STT provides an important natural source of ozone to the upper troposphere, but the characteristics of STT events in the Southern Hemisphere extratropics and their contribution to the regional tropospheric ozone budget remain poorly constrained. Here, we develop a quantitative method to identify STT events from ozonesonde profiles. Using this method we estimate the seasonality of STT events and quantify the ozone transported across the tropopause over Davis (69° S, 2006–2013, Macquarie Island (54° S, 2004–2013, and Melbourne (38° S, 2004–2013. STT seasonality is determined by two distinct methods: a Fourier bandpass filter of the vertical ozone profile and an analysis of the Brunt–Väisälä frequency. Using a bandpass filter on 7–9 years of ozone profiles from each site provides clear detection of STT events, with maximum occurrences during summer and minimum during winter for all three sites. The majority of tropospheric ozone enhancements owing to STT events occur within 2.5 and 3 km of the tropopause at Davis and Macquarie Island respectively. Events are more spread out at Melbourne, occurring frequently up to 6 km from the tropopause. The mean fraction of total tropospheric ozone attributed to STT during STT events is  ∼ 1. 0–3. 5 % at each site; however, during individual events, over 10 % of tropospheric ozone may be directly transported from the stratosphere. The cause of STTs is determined to be largely due to synoptic low-pressure frontal systems, determined using coincident ERA-Interim reanalysis meteorological data. Ozone enhancements can also be caused by biomass burning plumes transported from Africa and South America, which are apparent during austral winter and spring and are determined using satellite measurements of CO. To provide regional context for the ozonesonde observations, we use the GEOS-Chem chemical transport model, which is too coarsely

Quantifying Ozone Production throughout the Boundary Layer from High Frequency Tethered Profile Measurements during a High Ozone Episode in the Uinta Basin, Utah

Science.gov (United States)

Sterling, C. W.; Johnson, B.; Schnell, R. C.; Oltmans, S. J.; Cullis, P.; Hall, E. G.; Jordan, A. F.; Windell, J.; McClure-Begley, A.; Helmig, D.; Petron, G.

2015-12-01

During the Uinta Basin Winter Ozone Study (UBWOS) in Jan - Feb 2013, 735 tethered ozonesonde profiles were obtained at 3 sites including during high wintertime photochemical ozone production events that regularly exceeded 125 ppb. High resolution profiles of ozone and temperature with altitude, measured during daylight hours, showed the development of approximately week long high ozone episodes building from background levels of ~40 ppb to >150 ppb. The topography of the basin combined with a strong temperature inversion trapped oil and gas production effluents in the basin and the snow covered surface amplified the sun's radiation driving the photochemical ozone production at rates up to 13 ppb/hour in a cold layer capped at 1600-1700 meters above sea level. Beginning in mid-morning, ozone mixing ratios throughout the cold layer increased until late afternoon. Ozone mixing ratios were generally constant with height indicating that ozone production was nearly uniform throughout the depth of the cold pool. Although there was strong diurnal variation, ozone mixing ratios increased during the day more than decreased during the night, resulting in elevated levels the next morning; an indication that nighttime loss processes did not compensate for daytime production. Even though the 3 tethersonde sites were at elevations differing by as much as 140 m, the top of the high ozone layer was nearly uniform in altitude at the 3 locations. Mobile van surface ozone measurements across the basin confirmed this capped structure of the ozone layer; the vehicle drove out of high ozone mixing ratios at an elevation of ~1900 meters above sea level, above which free tropospheric ozone mixing ratios of ~50 ppb were measured. Exhaust plumes from a coal-fired power plant in the eastern portion of the basin were intercepted by the tethersondes. The structure of the profiles clearly showed that effluents in the plumes were not mixed downward and thus did not contribute precursor nitrogen

Two-phase ozonation of chlorinated organics

International Nuclear Information System (INIS)

Bhattacharyya, D.; Freshour, A.; West, D.

1995-01-01

In the last few years the amount of research being conducted in the field of single-phase ozonation has grown extensively. However, traditional aqueous-phase ozonation systems are limited by a lack of selective oxidation potential, low ozone solubility in water, and slow intermediate decomposition rates. Furthermore, ozone may decompose before it can be utilized for pollutant destruction since ozone can be highly unstable in aqueous solutions. Naturally occurring compounds such as NaHCO 3 also affect ozone reactions by inhibiting the formation of OH-free radicals. To compensate for these factors, excess ozone is typically supplied to a reactor. Since ozone generation requires considerable electric power consumption (16 - 24 kWh/kg of O 3 ), attempts to enhance the ozone utilization rate and stability should lead to more efficient application of this process to hazardous waste treatment. To improve the process, ozonation may be more efficiently carried out in a two-phase system consisting of an inert solvent (saturated with O 3 ) contacted with an aqueous phase containing pollutants. The non-aqueous phase must meet the following criteria: (1) non-toxic, (2) very low vapor pressure, (3) high density (for ease of separation), (4) complete insolubility in water, (5) reusability, (6) selective pollutant extractability, (7) high oxidant solubility, and (8) extended O 3 stability. Previously published studies (1) have indicated that a number of fluorinated hydrocarbon compounds fit these criteria. For this project, FC40 (a product of 3M Co.) was chosen due to its low vapor pressure (3 mm Hg) and high specific gravity (1.9). The primary advantages of the FC40 solvent are that it is non-toxic, reusable, has an ozone solubility 10 times that of water, and that 85 % of the ozone remains in the solvent even after 2 hours. This novel two-phase process has been utilized to study the rapid destruction of organic chlorine compounds and organic mixtures

Chemistry, Dynamics, and Radiation of Ozone Loss: Airborne Measurements of OH, HO2, NO2, ClO, BrO, IO, ClONO2, BrONO2, ClOOCl, and H2O

Science.gov (United States)

Anderson, James G.

2005-01-01

This grant continued the research initially funded under NAG1-01095. This research addresses, through a combination of in situ and remote aircraft-borne instruments, the following scientific questions: Which mechanisms are responsible for the continuing erosion of ozone over midlatitudes of the Northern Hemisphere? Will the rapid loss of ozone over the Arctic in late winter continue to worsen over the next two decades? Are these large losses dynamically coupled to midlatitudes? Which mechanisms dictate the rate of exchange of material between the troposphere and stratosphere? How will these processes change in response to changes in climate? Will regional scale pollution episodes, that are emerging as predictable seasonal events, significantly affect the middle-to-upper troposphere chemical composition. If so, how will these changes alter the chemical composition of the middle world? What changes are predicted for the overworld? Why has the arctic stratosphere become colder in the late winter phase in recent years? Have increases in tropical upper troposphere temperatures increased the temperature gradient such as to change the trajectories of vertically propagating waves, thus reducing the effectiveness of the meridional circulation for transport of heat, momentum and ozone from the tropics to high latitudes?

Interactive ozone and methane chemistry in GISS-E2 historical and future climate simulations

Directory of Open Access Journals (Sweden)

D. T. Shindell

2013-03-01

Full Text Available The new generation GISS climate model includes fully interactive chemistry related to ozone in historical and future simulations, and interactive methane in future simulations. Evaluation of ozone, its tropospheric precursors, and methane shows that the model captures much of the large-scale spatial structure seen in recent observations. While the model is much improved compared with the previous chemistry-climate model, especially for ozone seasonality in the stratosphere, there is still slightly too rapid stratospheric circulation, too little stratosphere-to-troposphere ozone flux in the Southern Hemisphere and an Antarctic ozone hole that is too large and persists too long. Quantitative metrics of spatial and temporal correlations with satellite datasets as well as spatial autocorrelation to examine transport and mixing are presented to document improvements in model skill and provide a benchmark for future evaluations. The difference in radiative forcing (RF calculated using modeled tropospheric ozone versus tropospheric ozone observed by TES is only 0.016 W m−2. Historical 20th Century simulations show a steady increase in whole atmosphere ozone RF through 1970 after which there is a decrease through 2000 due to stratospheric ozone depletion. Ozone forcing increases throughout the 21st century under RCP8.5 owing to a projected recovery of stratospheric ozone depletion and increases in methane, but decreases under RCP4.5 and 2.6 due to reductions in emissions of other ozone precursors. RF from methane is 0.05 to 0.18 W m−2 higher in our model calculations than in the RCP RF estimates. The surface temperature response to ozone through 1970 follows the increase in forcing due to tropospheric ozone. After that time, surface temperatures decrease as ozone RF declines due to stratospheric depletion. The stratospheric ozone depletion also induces substantial changes in surface winds and the Southern Ocean circulation, which may play a role in

Loss of urinary voiding sensation due to herpes zoster.

Science.gov (United States)

Hiraga, Akiyuki; Nagumo, Kiyomi; Sakakibara, Ryuji; Kojima, Shigeyuki; Fujinawa, Naoto; Hashimoto, Tasuku

2003-01-01

A case of sacral herpes zoster infection in a 56-year-old man with the complication of loss of urinary voiding sensation is presented. He had typical herpes zoster eruption on the left S2 dermatome, hypalgesia of the S1-S4 dermatomes, and absence of urinary voiding sensation. There was no other urinary symptom at the first medical examination. Urinary complications associated with herpes zoster are uncommon, but two types, acute cystitis and acute retention, have been recognized. No cases of loss of urinary voiding sensation due to herpes zoster have been reported. In this case, hypalgesia of the sacral dermatomes was mild compared to the marked loss of urethral sensation. This inconsistency is explained by the hypothesis that the number of urethral fibers is very small as compared to that of cutaneous fibers, therefore, urethral sensation would be more severely disturbed than cutaneous sensation. Copyright 2003 Wiley-Liss, Inc.

Ozone trends at northern mid- and high latitudes – a European perspective

Directory of Open Access Journals (Sweden)

N. R. P. Harris

2008-05-01

Full Text Available The EU CANDIDOZ project investigated the chemical and dynamical influences on decadal ozone trends focusing on the Northern Hemisphere. High quality long-term ozone data sets, satellite-based as well as ground-based, and the long-term meteorological reanalyses from ECMWF and NCEP are used together with advanced multiple regression models and atmospheric models to assess the relative roles of chemistry and transport in stratospheric ozone changes. This overall synthesis of the individual analyses in CANDIDOZ shows clearly one common feature in the NH mid latitudes and in the Arctic: an almost monotonic negative trend from the late 1970s to the mid 1990s followed by an increase. In most trend studies, the Equivalent Effective Stratospheric Chlorine (EESC which peaked in 1997 as a consequence of the Montreal Protocol was observed to describe ozone loss better than a simple linear trend. Furthermore, all individual analyses point to changes in dynamical drivers, such as the residual circulation (responsible for the meridional transport of ozone into middle and high latitudes playing a key role in the observed turnaround. The changes in ozone transport are associated with variations in polar chemical ozone loss via heterogeneous ozone chemistry on PSCs (polar stratospheric clouds. Synoptic scale processes as represented by the new equivalent latitude proxy, by conventional tropopause altitude or by 250 hPa geopotential height have also been successfully linked to the recent ozone increases in the lowermost stratosphere. These show significant regional variation with a large impact over Europe and seem to be linked to changes in tropospheric climate patterns such as the North Atlantic Oscillation. Some influence in recent ozone increases was also attributed to the rise in solar cycle number 23. Changes from the late 1970s to the mid 1990s were found in a number of characteristics of the Arctic vortex. However, only one trend was found when more recent

Ozonation for source treatment of pharmaceuticals in hospital wastewater - ozone lifetime and required ozone dose

DEFF Research Database (Denmark)

Hansen, Kamilla Marie Speht; Spiliotopoulou, Aikaterini; Chhetri, Ravi Kumar

2016-01-01

Ozonation aimed at removing pharmaceuticals was studied in an effluent from an experimental pilot system using staged moving bed biofilm reactor (MBBR) tanks for the optimal biological treatment of wastewater from a medical care unit of Aarhus University Hospital. Dissolved organic carbon (DOC......) and pH in samples varied considerably, and the effect of these two parameters on ozone lifetime and the efficiency of ozone in removing pharmaceuticals were determined. The pH in the effluent varied from 5.0 to 9.0 resulting in approximately a doubling of the required ozone dose at the highest p......H for each pharmaceutical. DOC varied from 6 to 20 mg-DOC/L. The ozone required for removing each pharmaceutical, varied linearly with DOC and thus, ozone doses normalized to DOC (specific ozone dose) agreed between water samples (typically within 15%). At neutral pH the specific ozone dose required...

Brief communication: Loss of life due to Hurricane Harvey

Science.gov (United States)

Jonkman, Sebastiaan N.; Godfroy, Maartje; Sebastian, Antonia; Kolen, Bas

2018-04-01

An analysis was made of the loss of life caused by Hurricane Harvey. Information was collected for 70 fatalities that occurred due to the event and were recovered within the first 2 weeks after landfall. Most fatalities occurred due to drowning (81 %), particularly in and around vehicles. Males (70 %) and people over 50 years old (56 %) were overrepresented in the dataset. More than half of the fatalities occurred in the greater Houston area (n = 37), where heavy rainfall and dam releases caused unprecedented urban flooding. The majority of fatalities were recovered outside the designated 100- and 500-year flood hazard areas.

Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

International Nuclear Information System (INIS)

Souza, Lara; Neufeld, Howard S.; Chappelka, Arthur H.; Burkey, Kent O.; Davison, Alan W.

2006-01-01

The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts and individual tall milkweeds (Asclepias exaltata L.) in Great Smoky Mountains National Park. Plants were classified as either ozone-sensitive or insensitive based on the amount of foliar injury. Sensitive plants developed injury earlier in the season and to a greater extent than insensitive plants. Older leaf cohorts were more likely to belong to high injury classes by the end of each of the two growing seasons. In addition, leaf loss was more likely for older cohorts (2000) and lower leaf positions (2001) than younger cohorts and upper leaves, respectively. Most leaves abscised without prior ozone-like stippling or chlorosis. Failure to take this into account can result in underestimation of the effects of ozone on these plants. - Leaf loss was not necessarily accompanied by symptoms of foliar ozone injury

Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

Energy Technology Data Exchange (ETDEWEB)

Souza, Lara [Department of Biology, 572 Rivers Street, Appalachian State University, Boone, NC 28608 (United States)]. E-mail: lsouza@utk.edu; Neufeld, Howard S. [Department of Biology, 572 Rivers Street, Appalachian State University, Boone, NC 28608 (United States); Chappelka, Arthur H. [School of Forestry and Wildlife Sciences, 108 M White-Smith Hall, Auburn University, Auburn, AL 36849 (United States); Burkey, Kent O. [US Department of Agriculture, Agricultural Research Service, Plant Science Research Unit and Department of Crop Science, North Carolina State University, 3908 Inwood Road, Raleigh, NC 26703 (United States); Davison, Alan W. [School of Biology, Ridley Building, University of Newcastle, Newcastle Upon Tyne, NE1 7RU (United Kingdom)

2006-05-15

The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts and individual tall milkweeds (Asclepias exaltata L.) in Great Smoky Mountains National Park. Plants were classified as either ozone-sensitive or insensitive based on the amount of foliar injury. Sensitive plants developed injury earlier in the season and to a greater extent than insensitive plants. Older leaf cohorts were more likely to belong to high injury classes by the end of each of the two growing seasons. In addition, leaf loss was more likely for older cohorts (2000) and lower leaf positions (2001) than younger cohorts and upper leaves, respectively. Most leaves abscised without prior ozone-like stippling or chlorosis. Failure to take this into account can result in underestimation of the effects of ozone on these plants. - Leaf loss was not necessarily accompanied by symptoms of foliar ozone injury.

Energy loss mechanism for suspended micro- and nanoresonators due to the Casimir force

OpenAIRE

Gusso, André

2011-01-01

A so far not considered energy loss mechanism in suspended micro- and nanoresonators due to noncontact acoustical energy loss is investigated theoretically. The mechanism consists on the conversion of the mechanical energy from the vibratory motion of the resonator into acoustic waves on large nearby structures, such as the substrate, due to the coupling between the resonator and those structures resulting from the Casimir force acting over the separation gaps. Analytical expressions for the ...

Uncertainties in models of tropospheric ozone based on Monte Carlo analysis: Tropospheric ozone burdens, atmospheric lifetimes and surface distributions

Science.gov (United States)

Derwent, Richard G.; Parrish, David D.; Galbally, Ian E.; Stevenson, David S.; Doherty, Ruth M.; Naik, Vaishali; Young, Paul J.

2018-05-01

Recognising that global tropospheric ozone models have many uncertain input parameters, an attempt has been made to employ Monte Carlo sampling to quantify the uncertainties in model output that arise from global tropospheric ozone precursor emissions and from ozone production and destruction in a global Lagrangian chemistry-transport model. Ninety eight quasi-randomly Monte Carlo sampled model runs were completed and the uncertainties were quantified in tropospheric burdens and lifetimes of ozone, carbon monoxide and methane, together with the surface distribution and seasonal cycle in ozone. The results have shown a satisfactory degree of convergence and provide a first estimate of the likely uncertainties in tropospheric ozone model outputs. There are likely to be diminishing returns in carrying out many more Monte Carlo runs in order to refine further these outputs. Uncertainties due to model formulation were separately addressed using the results from 14 Atmospheric Chemistry Coupled Climate Model Intercomparison Project (ACCMIP) chemistry-climate models. The 95% confidence ranges surrounding the ACCMIP model burdens and lifetimes for ozone, carbon monoxide and methane were somewhat smaller than for the Monte Carlo estimates. This reflected the situation where the ACCMIP models used harmonised emissions data and differed only in their meteorological data and model formulations whereas a conscious effort was made to describe the uncertainties in the ozone precursor emissions and in the kinetic and photochemical data in the Monte Carlo runs. Attention was focussed on the model predictions of the ozone seasonal cycles at three marine boundary layer stations: Mace Head, Ireland, Trinidad Head, California and Cape Grim, Tasmania. Despite comprehensively addressing the uncertainties due to global emissions and ozone sources and sinks, none of the Monte Carlo runs were able to generate seasonal cycles that matched the observations at all three MBL stations. Although

Influence of inter-annual variations of stratospheric dynamics in model simulations of ozone losses by aircraft emissions

Energy Technology Data Exchange (ETDEWEB)

Jadin, E.A. [Central Aerological Observatory, Dolgoprudny (Russian Federation)

1997-12-31

The questions of model predictions of aircraft emission impacts on the ozone variations are considered. Using the NMC data it is shown that the stratospheric circulation underwent the abrupt transition to a new regime in summer 1980. The strong correlations are found between the monthly mean total ozone and stratospheric angular momentum anomalies during 1979-1991. The natural long-term changes of transport processes are necessary to take into account in model simulations of anthropogenic impacts on the ozone layer. (author) 12 refs.

Influence of inter-annual variations of stratospheric dynamics in model simulations of ozone losses by aircraft emissions

Energy Technology Data Exchange (ETDEWEB)

Jadin, E A [Central Aerological Observatory, Dolgoprudny (Russian Federation)

1998-12-31

The questions of model predictions of aircraft emission impacts on the ozone variations are considered. Using the NMC data it is shown that the stratospheric circulation underwent the abrupt transition to a new regime in summer 1980. The strong correlations are found between the monthly mean total ozone and stratospheric angular momentum anomalies during 1979-1991. The natural long-term changes of transport processes are necessary to take into account in model simulations of anthropogenic impacts on the ozone layer. (author) 12 refs.

Some current problems in atmospheric ozone chemistry; role of chemical kinetics

Energy Technology Data Exchange (ETDEWEB)

Cox, R.A.

1987-03-01

A review is given on selected aspects of the reaction mechanisms of current interest in the chemistry of atmospheric ozone. Atmospheric ozone is produced and removed by a complex series of elementary gas-phase photochemical reactions involving O/sub x/, HO/sub x/, NO/sub x/, CIO/sub x/ and hydrocarbon species. At the present time there is a good knowledge of the basic processes involved in ozone chemistry in the stratosphere and the troposphere and the kinetics of most of the key reactions are well defined. There are a number of difficulties in the theoretical descriptions of observed ozone behaviour which may be due to uncertainties in the chemistry. Examples are the failure to predict present day ozone in the photochemically controlled region above 35 Km altitude and the large reductions in the ozone column in the Antartic Spring which has been observed in recent years. In the troposphere there is growing evidence that ozone and other trace gases have changed appreciably from pre-industrial concentrations, due to chemical reactions involving man-made pollutants. Quantitative investigation of the mechanisms by which these changes may occur requires a sound laboratory kinetics data base.

Quantitative Analysis Method of Output Loss due to Restriction for Grid-connected PV Systems

Science.gov (United States)

Ueda, Yuzuru; Oozeki, Takashi; Kurokawa, Kosuke; Itou, Takamitsu; Kitamura, Kiyoyuki; Miyamoto, Yusuke; Yokota, Masaharu; Sugihara, Hiroyuki

Voltage of power distribution line will be increased due to reverse power flow from grid-connected PV systems. In the case of high density grid connection, amount of voltage increasing will be higher than the stand-alone grid connection system. To prevent the over voltage of power distribution line, PV system's output will be restricted if the voltage of power distribution line is close to the upper limit of the control range. Because of this interaction, amount of output loss will be larger in high density case. This research developed a quantitative analysis method for PV systems output and losses to clarify the behavior of grid connected PV systems. All the measured data are classified into the loss factors using 1 minute average of 1 second data instead of typical 1 hour average. Operation point on the I-V curve is estimated to quantify the loss due to the output restriction using module temperature, array output voltage, array output current and solar irradiance. As a result, loss due to output restriction is successfully quantified and behavior of output restriction is clarified.

On the link between martian total ozone and potential vorticity

Science.gov (United States)

Holmes, James A.; Lewis, Stephen R.; Patel, Manish R.

2017-01-01

We demonstrate for the first time that total ozone in the martian atmosphere is highly correlated with the dynamical tracer, potential vorticity, under certain conditions. The degree of correlation is investigated using a Mars global circulation model including a photochemical model. Potential vorticity is the quantity of choice to explore the dynamical nature of polar vortices because it contains information on winds and temperature in a single scalar variable. The correlation is found to display a distinct seasonal variation, with a strong positive correlation in both northern and southern winter at poleward latitudes in the northern and southern hemisphere respectively. The identified strong correlation implies variations in polar total ozone during winter are predominantly controlled by dynamical processes in these spatio-temporal regions. The weak correlation in northern and southern summer is due to the dominance of photochemical reactions resulting from extended exposure to sunlight. The total ozone/potential vorticity correlation is slightly weaker in southern winter due to topographical variations and the preference for ozone to accumulate in Hellas basin. In northern winter, total ozone can be used to track the polar vortex edge. The ozone/potential vorticity ratio is calculated for both northern and southern winter on Mars for the first time. Using the strong correlation in total ozone and potential vorticity in northern winter inside the polar vortex, it is shown that potential vorticity can be used as a proxy to deduce the distribution of total ozone where satellites cannot observe for the majority of northern winter. Where total ozone observations are available on the fringes of northern winter at poleward latitudes, the strong relationship of total ozone and potential vorticity implies that total ozone anomalies in the surf zone of the northern polar vortex can potentially be used to determine the origin of potential vorticity filaments.

Meteorologically-adjusted trend analysis of surface observed ozone at three monitoring sites in Delhi, India: 2007-2011

Science.gov (United States)

Biswas, J.; Farooqui, Z.; Guttikunda, S. K.

2012-12-01

It is well known that meteorological parameters have significant impact on surface ozone concentrations. Therefore it is important to remove the effects of meteorology on ozone concentrations to correctly estimate long-term trends in ozone levels due to the alterations in precursor emissions. This is important for the development of effectual control strategies. In this study surface observed ozone trends in New Delhi are analyzed using Komogorov-Zurbenko (KZ) filter, US EPA ozone adjustment due to weather approach and the classification and regression tree method. The statistical models are applied to the ozone data at three observational sites in New Delhi metropolitan areas, 1) Income Tax Office (ITO) 2) Sirifort and 3) Delhi College of Engineering (DCE). The ITO site is located adjacent to a traffic crossing, Sirifort is an urban site and the DCE site is located in a residential area. The ITO site is also influenced by local industrial emissions. DCE has higher ozone levels than the other two sites. It was found that ITO has lowest ozone concentrations amongst the three sites due to ozone titrating due to industrial and on-road mobile NOx emissions. The statistical methods employed can assess ozone trends at these sites with a high degree of confidence and the results can be used to gauge the effectiveness of control strategies on surface ozone levels in New Delhi.

Global economic effects of changes in crops, pasture, and forests due to changing climate, carbon dioxide, and ozone

International Nuclear Information System (INIS)

Reilly, J.; Paltsev, S.; Felzer, B.; Wang, X.; Kicklighter, D.; Melillo, J.; Prinn, R.; Sarofim, M.; Sokolov, A.; Wang, C.

2007-01-01

Multiple environmental changes will have consequences for global vegetation. To the extent that crop yields and pasture and forest productivity are affected, there can be important economic consequences. We examine the combined effects of changes in climate, increases in carbon dioxide (CO 2 ), and changes in tropospheric ozone on crop, pasture, and forest lands and the consequences for the global and regional economies. We examine scenarios where there is limited or little effort to control these substances, and policy scenarios that limit emissions of CO 2 and ozone precursors. We find the effects of climate and CO 2 to be generally positive, and the effects of ozone to be very detrimental. Unless ozone is strongly controlled, damage could offset CO 2 and climate benefits. We find that resource allocation among sectors in the economy, and trade among countries, can strongly affect the estimate of economic effect in a country

Comparison of SAGE 2 ozone measurements and ozone soundings at Uccle (Belgium) during the period February 1985 to January 1986

Science.gov (United States)

Debacker, Hugo; Demuer, Dirk; Veiga, R. E.; Zawodny, J. M.

1994-01-01

The ozone profiles obtained from 24 balloon soundings, at 50 deg 48 min N, 4 deg 21 min E, carried out with the electro-chemical ozonesondes are discussed. The data were used as correlative data to the ozone profiles acquired by the Stratospheric Aerosol and Gas Experiment (SAGE 2). Good agreement was obtained between the two data sets. The difference of percentage between the ozone column density of the mean balloon and SAGE profile is 4.4% in the altitude region between 10 to 26 km. From the statistical analysis it seems that there is a difference between the mean profiles at the level of the ozone maximum and around the 30 km level. Similar results are obtained with an error analysis of both data. The differences between the mean profiles in the lower stratosphere are probably real, and are due to the presence of ozone.

Breaks induced in the deoxyribonucleic acid of aerosolized Escherichia coli by ozonized cyclohexene.

Science.gov (United States)

De Mik, G; De Groot, I

1978-01-01

The inactivation of aerosolized Escherichia coli by ozone, cyclohexene, and ozonized cyclohexene was studied. The parameters for damage were loss of reproduction and introduction of breaks in the deoxyribonucleic acid (DNA). Aerosolization of E. coli in clean air at 80 percent relative humidity or in air containing either ozone or cyclohexene hardly affected survival; however, some breaks per DNA molecule were induced, as shown by sucrose gradient sedimentation of the DNA. Aerosolization of E. coli in air containing ozonized cyclohexene at 80 percent relative humidity decreased the survival by a factor of 10(3) or more after 1 h of exposure and induced many breaks in the DNA. PMID:341811

What would have happened to the ozone layer if chlorofluorocarbons (CFCs) had not been regulated?

OpenAIRE

P. A. Newman; L. D. Oman; A. R. Douglass; E. L. Fleming; S. M. Frith; M. M. Hurwitz; S. R. Kawa; C. H. Jackman; N. A. Krotkov; E. R. Nash; J. E. Nielsen; S. Pawson; R. S. Stolarski; G. J. M. Velders

2009-01-01

Ozone depletion by chlorofluorocarbons (CFCs) was first proposed by Molina and Rowland in their 1974 Nature paper. Since that time, the scientific connection between ozone losses and CFCs and other ozone depleting substances (ODSs) has been firmly established with laboratory measurements, atmospheric observations, and modeling research. This science research led to the implementation of international agreements that largely stopped the production of ODSs. In this study we use a fully-c...

N-nitrosodimethylamine (NDMA) formation from the ozonation of model compounds.

Science.gov (United States)

Marti, Erica J; Pisarenko, Aleksey N; Peller, Julie R; Dickenson, Eric R V

2015-04-01

Nitrosamines are a class of toxic disinfection byproducts commonly associated with chloramination, of which several were included on the most recent U.S. EPA Contaminant Candidate List. Nitrosamine formation may be a significant barrier to ozonation in water reuse applications, particularly for direct or indirect potable reuse, since recent studies show direct formation during ozonation of natural water and treated wastewaters. Only a few studies have identified precursors which react with ozone to form N-nitrosodimethylamine (NDMA). In this study, several precursor compound solutions, prepared in ultrapure water and treated wastewater, were subjected to a 10 M excess of ozone. In parallel experiments, the precursor solutions in ultrapure water were exposed to gamma radiation to determine NDMA formation as a byproduct of reactions of precursor compounds with hydroxyl radicals. The results show six new NDMA precursor compounds that have not been previously reported in the literature, including compounds with hydrazone and carbamate moieties. Molar yields in deionized water were 61-78% for 3 precursors, 12-23% for 5 precursors and NDMA formation for the other precursors. NDMA formation due to chloramination was minimal compared to formation due to ozonation, suggesting distinct groups of precursor compounds for these two oxidants. Hydroxyl radical reactions with the precursors will produce NDMA, but formation is much greater in the presence of molecular ozone. Also, hydroxyl radical scavenging during ozonation leads to increased NDMA formation. Molar conversion yields were higher for several precursors in wastewater as compared to deionized water, which could be due to catalyzed reactions with constituents found in wastewater or hydroxyl radical scavenging. Copyright © 2014 Elsevier Ltd. All rights reserved.

What-ifs for a Northern ozone hole

Energy Technology Data Exchange (ETDEWEB)

Newman, A.

1993-08-01

Based on papers presented at a recent American Geophysical Union meeting in Baltimore, this article discusses various processes that could lead to further significant stratospheric ozone losses over northern latitudes. In southern high latitudes, ClO, formed when Cl atoms react with O[sub 3], persists into the spring and enters a photocatalytic cycle that regenerates ozone-destroying Cl atoms. Type II polar stratospheric clouds (PSCs) are believed to act as catalysts in this cycle. Although type II PSCs rarely form in the warmer Arctic stratosphere, it is possible that type I PSCs and sulfuric acid droplets may act as catalytic surfaces in this region. The arctic however, currently lacks a pronounced ozone hole, unlike Antartica. This is because in the Northern Hemisphere, large-scale tropospheric weather disturbances leak a portion of their energy to the less dense stratosphere. This indirectly leads to the descent of air over the Arctic region which produces compression heating of the polar cap and keeps the Arctic winter stratosphere warm enough to evade the cold temperatures that would produce widespread PSCs, and the associated significant ozone destruction. However, the greenhouse effect could lead to a cooler stratosphere containing more water and weaker tropospheric large-scale disturbances meaning colder Arctic winters. All these factors would contribute to greater PSC formation and the associated ozone destruction.

What-ifs for a Northern ozone hole

International Nuclear Information System (INIS)

Newman, A.

1993-01-01

Based on papers presented at a recent American Geophysical Union meeting in Baltimore, this article discusses various processes that could lead to further significant stratospheric ozone losses over northern latitudes. In southern high latitudes, ClO, formed when Cl atoms react with O 3 , persists into the spring and enters a photocatalytic cycle that regenerates ozone-destroying Cl atoms. Type II polar stratospheric clouds (PSCs) are believed to act as catalysts in this cycle. Although type II PSCs rarely form in the warmer Arctic stratosphere, it is possible that type I PSCs and sulfuric acid droplets may act as catalytic surfaces in this region. The arctic however, currently lacks a pronounced ozone hole, unlike Antartica. This is because in the Northern Hemisphere, large-scale tropospheric weather disturbances leak a portion of their energy to the less dense stratosphere. This indirectly leads to the descent of air over the Arctic region which produces compression heating of the polar cap and keeps the Arctic winter stratosphere warm enough to evade the cold temperatures that would produce widespread PSCs, and the associated significant ozone destruction. However, the greenhouse effect could lead to a cooler stratosphere containing more water and weaker tropospheric large-scale disturbances meaning colder Arctic winters. All these factors would contribute to greater PSC formation and the associated ozone destruction

Perspectives regarding 50 years of research on effects of tropospheric ozone air pollution on US forests

Energy Technology Data Exchange (ETDEWEB)

Karnosky, David F. [School of Forest Resources and Environmental Science, Michigan Tech University, 1400 Townsend Drive, Houghton, MI 49931 (United States)]. E-mail: karnosky@mtu.edu; Skelly, John M. [5316 Wyndemere Circle, Mineral, VA 23117 (United States); Percy, Kevin E. [Natural Resources Canada, Canadian Forest Service-Atlantic Forestry Centre, PO 1350 Regent Street, Fredericton, New Brunswick, E3B 5P7 (Canada); Chappelka, Art H. [School of Forestry and Wildlife Sciences, Auburn University, 206 M. White-Smith Hall, Auburn, AL 36849-5418 (United States)

2007-06-15

Tropospheric ozone (O{sub 3}) was first determined to be phytotoxic to grapes in southern California in the 1950s. Investigations followed that showed O{sub 3} to be the cause of foliar symptoms on tobacco and eastern white pine. In the 1960s, 'X' disease of ponderosa pines within the San Bernardino Mountains was likewise determined to be due to O{sub 3}. Nearly 50 years of research have followed. Foliar O{sub 3} symptoms have been verified under controlled chamber conditions. Studies have demonstrated negative growth effects on forest tree seedlings due to season-long O{sub 3} exposures, but due to complex interactions within forest stands, evidence of similar losses within mature tree canopies remains elusive. Investigations on tree growth, O{sub 3} flux, and stand productivity are being conducted along natural O{sub 3} gradients and in open-air exposure systems to better understand O{sub 3} effects on forest ecosystems. Given projected trends in demographics, economic output and climate, O{sub 3} impacts on US forests will continue and are likely to increase. - Elevated tropospheric ozone remains an important phytotoxic air pollutant over large areas of US forests.

Perspectives regarding 50 years of research on effects of tropospheric ozone air pollution on US forests

International Nuclear Information System (INIS)

Karnosky, David F.; Skelly, John M.; Percy, Kevin E.; Chappelka, Art H.

2007-01-01

Tropospheric ozone (O 3 ) was first determined to be phytotoxic to grapes in southern California in the 1950s. Investigations followed that showed O 3 to be the cause of foliar symptoms on tobacco and eastern white pine. In the 1960s, 'X' disease of ponderosa pines within the San Bernardino Mountains was likewise determined to be due to O 3 . Nearly 50 years of research have followed. Foliar O 3 symptoms have been verified under controlled chamber conditions. Studies have demonstrated negative growth effects on forest tree seedlings due to season-long O 3 exposures, but due to complex interactions within forest stands, evidence of similar losses within mature tree canopies remains elusive. Investigations on tree growth, O 3 flux, and stand productivity are being conducted along natural O 3 gradients and in open-air exposure systems to better understand O 3 effects on forest ecosystems. Given projected trends in demographics, economic output and climate, O 3 impacts on US forests will continue and are likely to increase. - Elevated tropospheric ozone remains an important phytotoxic air pollutant over large areas of US forests

Ozone Layer Protection

Science.gov (United States)

... and Research Centers Contact Us Share Ozone Layer Protection The stratospheric ozone layer is Earth’s “sunscreen” – protecting ... GreenChill Partnership Responsible Appliance Disposal (RAD) Program Ozone Protection vs. Ozone Pollution This website addresses stratospheric ozone ...

Improvements in Total Column Ozone in GEOSCCM and Comparisons with a New Ozone-Depleting Substances Scenario

Science.gov (United States)

Oman, Luke D.; Douglass, Anne R.

2014-01-01

The evolution of ozone is examined in the latest version of the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM) using old and new ozone-depleting substances (ODS) scenarios. This version of GEOSCCM includes a representation of the quasi-biennial oscillation, a more realistic implementation of ozone chemistry at high solar zenith angles, an improved air/sea roughness parameterization, and an extra 5 parts per trillion of CH3Br to account for brominated very short-lived substances. Together these additions improve the representation of ozone compared to observations. This improved version of GEOSCCM was used to simulate the ozone evolution for the A1 2010 and the newStratosphere-troposphere Processes and their Role in Climate (SPARC) 2013 ODS scenario derived using the SPARC Lifetimes Report 2013. This new ODS scenario results in a maximum Cltot increase of 65 parts per trillion by volume (pptv), decreasing slightly to 60 pptv by 2100. Approximately 72% of the increase is due to the longer lifetime of CFC-11. The quasi-global (60degS-60degN) total column ozone difference is relatively small and less than 1Dobson unit on average and consistent with the 3-4% larger 2050-2080 average Cly in the new SPARC 2013 scenario. Over high latitudes, this small change in Cly compared to the relatively large natural variabilitymakes it not possible to discern a significant impact on ozone in the second half of the 21st century in a single set of simulations.

Responses of Surface Ozone Air Quality to Anthropogenic Nitrogen Deposition

Science.gov (United States)

Zhang, L.; Zhao, Y.; Tai, A. P. K.; Chen, Y.; Pan, Y.

2017-12-01

Human activities have substantially increased atmospheric deposition of reactive nitrogen to the Earth's surface, inducing unintentional effects on ecosystems with complex environmental and climate consequences. One consequence remaining unexplored is how surface air quality might respond to the enhanced nitrogen deposition through surface-atmosphere exchange. We combine a chemical transport model (GEOS-Chem) and a global land model (Community Land Model) to address this issue with a focus on ozone pollution in the Northern Hemisphere. We consider three processes that are important for surface ozone and can be perturbed by addition of atmospheric deposited nitrogen: emissions of biogenic volatile organic compounds (VOCs), ozone dry deposition, and soil nitrogen oxide (NOx) emissions. We find that present-day anthropogenic nitrogen deposition (65 Tg N a-1 to the land), through enhancing plant growth (represented as increases in vegetation leaf area index (LAI) in the model), could increase surface ozone from increased biogenic VOC emissions, but could also decrease ozone due to higher ozone dry deposition velocities. Meanwhile, deposited anthropogenic nitrogen to soil enhances soil NOx emissions. The overall effect on summer mean surface ozone concentrations show general increases over the globe (up to 1.5-2.3 ppbv over the western US and South Asia), except for some regions with high anthropogenic NOx emissions (0.5-1.0 ppbv decreases over the eastern US, Western Europe, and North China). We compare the surface ozone changes with those driven by the past 20-year climate and historical land use changes. We find that the impacts from anthropogenic nitrogen deposition can be comparable to the climate and land use driven surface ozone changes at regional scales, and partly offset the surface ozone reductions due to land use changes reported in previous studies. Our study emphasizes the complexity of biosphere-atmosphere interactions, which can have important

Are we approaching an Arctic ozone hole

International Nuclear Information System (INIS)

Braathen, Geir

1999-01-01

Observations during the last decade in the Arctic areas mainly made by satellite, on the ground and by probes and sensors in the stratosphere are presented. Future perspectives are deducted from the results. Factors that may influence the ozone layer negatively are: Emission rate of ozone destroying compounds, the rapidly increasing use of some substitutes, increased concentrations of steam from aeroplanes and increased amount of methane, decreasing temperature in the stratosphere due to increasing amounts of climatic gases, large volcanic eruptions and altered timing for the polar whirl dissolution. It is concluded that the ozone reduction will be larger than observed at present in the next 10 to 20 years

Optical losses due to tracking error estimation for a low concentrating solar collector

International Nuclear Information System (INIS)

Sallaberry, Fabienne; García de Jalón, Alberto; Torres, José-Luis; Pujol-Nadal, Ramón

2015-01-01

Highlights: • A solar thermal collector with low concentration and one-axis tracking was tested. • A quasi-dynamic testing procedure for IAM was defined for tracking collector. • The adequation between the concentrator optics and the tracking was checked. • The maximum and long-term optical losses due to tracking error were calculated. - Abstract: The determination of the accuracy of a solar tracker used in domestic hot water solar collectors is not yet standardized. However, while using optical concentration devices, it is important to use a solar tracker with adequate precision with regard to the specific optical concentration factor. Otherwise, the concentrator would sustain high optical losses due to the inadequate focusing of the solar radiation onto its receiver, despite having a good quality. This study is focused on the estimation of long-term optical losses due to the tracking error of a low-temperature collector using low-concentration optics. For this purpose, a testing procedure for the incidence angle modifier on the tracking plane is proposed to determinate the acceptance angle of its concentrator even with different longitudinal incidence angles along the focal line plane. Then, the impact of maximum tracking error angle upon the optical efficiency has been determined. Finally, the calculation of the long-term optical error due to the tracking errors, using the design angular tracking error declared by the manufacturer, is carried out. The maximum tracking error calculated for this collector imply an optical loss of about 8.5%, which is high, but the average long-term optical loss calculated for one year was about 1%, which is reasonable for such collectors used for domestic hot water

Drag and power-loss in rowing due to velocity fluctuations

NARCIS (Netherlands)

Greidanus, A.J.; Delfos, R.; Westerweel, J.; Jansen, A.J.

2016-01-01

The flow motions in the turbulent boundary layer between water and a rowing boat initiate a turbulent skin friction. Reducing this skin friction results in better rowing performances. A Taylor-Couette (TC) facility was used to verify the power losses due to velocity fluctuations P_V′ in

Global budget of tropospheric ozone: Evaluating recent model advances with satellite (OMI), aircraft (IAGOS), and ozonesonde observations

Science.gov (United States)

Hu, Lu; Jacob, Daniel J.; Liu, Xiong; Zhang, Yi; Zhang, Lin; Kim, Patrick S.; Sulprizio, Melissa P.; Yantosca, Robert M.

2017-10-01

The global budget of tropospheric ozone is governed by a complicated ensemble of coupled chemical and dynamical processes. Simulation of tropospheric ozone has been a major focus of the GEOS-Chem chemical transport model (CTM) over the past 20 years, and many developments over the years have affected the model representation of the ozone budget. Here we conduct a comprehensive evaluation of the standard version of GEOS-Chem (v10-01) with ozone observations from ozonesondes, the OMI satellite instrument, and MOZAIC-IAGOS commercial aircraft for 2012-2013. Global validation of the OMI 700-400 hPa data with ozonesondes shows that OMI maintained persistent high quality and no significant drift over the 2006-2013 period. GEOS-Chem shows no significant seasonal or latitudinal bias relative to OMI and strong correlations in all seasons on the 2° × 2.5° horizontal scale (r = 0.88-0.95), improving on previous model versions. The most pronounced model bias revealed by ozonesondes and MOZAIC-IAGOS is at high northern latitudes in winter-spring where the model is 10-20 ppbv too low. This appears to be due to insufficient stratosphere-troposphere exchange (STE). Model updates to lightning NOx, Asian anthropogenic emissions, bromine chemistry, isoprene chemistry, and meteorological fields over the past decade have overall led to gradual increase in the simulated global tropospheric ozone burden and more active ozone production and loss. From simulations with different versions of GEOS meteorological fields we find that tropospheric ozone in GEOS-Chem v10-01 has a global production rate of 4960-5530 Tg a-1, lifetime of 20.9-24.2 days, burden of 345-357 Tg, and STE of 325-492 Tg a-1. Change in the intensity of tropical deep convection between these different meteorological fields is a major factor driving differences in the ozone budget.

Video-documentation: 'The Pannonic ozon project'

International Nuclear Information System (INIS)

Loibl, W.; Cabela, E.; Mayer, H. F.; Schmidt, M.

1998-07-01

Goal of the project was the production of a video film as documentation of the Pannonian Ozone Project- POP. The main part of the video describes the POP-model consisting of the modules meteorology, emissions and chemistry, developed during the POP-project. The model considers the European emission patterns of ozone precursors and the actual wind fields. It calculates ozone build up and depletion within air parcels due to emission and weather situation along trajectory routes. Actual ozone concentrations are calculated during model runs simulating the photochemical processes within air parcels moving along 4 day trajectories before reaching the Vienna region. The model computations were validated during extensive ground and aircraft-based measurements of ozone precursors and ozone concentration within the POP study area. Scenario computations were used to determine how much ozone can be reduced in north-eastern Austria by emissions control measures. The video lasts 12:20 minutes and consists of computer animations and life video scenes, presenting the ozone problem in general, the POP model and the model results. The video was produced in co-operation by the Austrian Research Center Seibersdorf - Department of Environmental Planning (ARCS) and Joanneum Research - Institute of Informationsystems (JR). ARCS was responsible for idea, concept, storyboard and text while JR was responsible for computer animation and general video production. The speaker text was written with scientific advice by the POP - project partners: Institute of Meteorology and Physics, University of Agricultural Sciences- Vienna, Environment Agency Austria - Air Quality Department, Austrian Research Center Seibersdorf- Environmental Planning Department/System Research Division. The film was produced as German and English version. (author)

Self-amplified Amazon forest loss due to vegetation-atmosphere feedbacks

Science.gov (United States)

Zemp, Delphine Clara; Schleussner, Carl-Friedrich; Barbosa, Henrique M. J.; Hirota, Marina; Montade, Vincent; Sampaio, Gilvan; Staal, Arie; Wang-Erlandsson, Lan; Rammig, Anja

2017-03-01

Reduced rainfall increases the risk of forest dieback, while in return forest loss might intensify regional droughts. The consequences of this vegetation-atmosphere feedback for the stability of the Amazon forest are still unclear. Here we show that the risk of self-amplified Amazon forest loss increases nonlinearly with dry-season intensification. We apply a novel complex-network approach, in which Amazon forest patches are linked by observation-based atmospheric water fluxes. Our results suggest that the risk of self-amplified forest loss is reduced with increasing heterogeneity in the response of forest patches to reduced rainfall. Under dry-season Amazonian rainfall reductions, comparable to Last Glacial Maximum conditions, additional forest loss due to self-amplified effects occurs in 10-13% of the Amazon basin. Although our findings do not indicate that the projected rainfall changes for the end of the twenty-first century will lead to complete Amazon dieback, they suggest that frequent extreme drought events have the potential to destabilize large parts of the Amazon forest.

Hydrogen emissions and their effects on the arctic ozone losses. Risk analysis of a global hydrogen economy; Wasserstoff-Emissionen und ihre Auswirkungen auf den arktischen Ozonverlust. Risikoanalyse einer globalen Wasserstoffwirtschaft

Energy Technology Data Exchange (ETDEWEB)

Feck, Thomas

2009-07-01

Hydrogen (H{sub 2}) could be used as one of the major components in our future energy supply in an effort to avoid greenhouse gas emissions. ''Green'' hydrogen in particular, which is produced from renewable energy sources, should significantly reduce emissions that damage the climate. Despite this basically environmentally-friendly property, however, the complex chain of interactions of hydrogen with other compounds means that the implications for the atmosphere must be analysed in detail. For example, H{sub 2} emissions, which could increase the tropospheric H{sub 2} inventory, can be released throughout the complete hydrogen process chain. H{sub 2} enters the stratosphere via the tropical tropopause and is oxidised there to form water vapour (H{sub 2}O). This extra water vapour causes increased radiation in the infrared region of the electromagnetic spectrum and thus causes the stratosphere to cool down. Both the increase in H{sub 2}O and the resulting cooling down of the stratosphere encourage the formation of polar stratospheric clouds (PSC) and liquid sulphate aerosols, which facilitate the production of reactive chlorine, which in turn currently leads to dramatic ozone depletion in the polar stratosphere. In the future, H{sub 2} emissions from a global hydrogen economy could therefore encourage stratospheric ozone depletion in the polar regions and thus inhibit the ozone layer in recovering from the damage caused by chlorofluorocarbons (CFCs). In addition to estimating possible influences on the trace gas composition of the stratosphere, one of the main aims of this thesis is to evaluate the risk associated with increased polar ozone depletion caused by additional H{sub 2} emissions. Studies reported on here have shown that even if around 90% of today's fossil primary energy input was to be replaced by hydrogen and if around 9.5% of the gas was to escape in a ''worst-case'' scenario, the additional ozone loss for unchanged CFC loading in the stratosphere

Comparative study of ozonized olive oil and ozonized sunflower oil

Directory of Open Access Journals (Sweden)

Díaz Maritza F.

2006-01-01

Full Text Available In this study the ozonized olive and sunflower oils are chemical and microbiologically compared. These oils were introduced into a reactor with bubbling ozone gas in a water bath at room temperature until they were solidified. The peroxide, acidity and iodine values along with antimicrobial activity were determined. Ozonization effects on the fatty acid composition of these oils were analyzed using Gas-Liquid Chromatographic Technique. An increase in peroxidation and acidity values was observed in both oils but they were higher in ozonized sunflower oil. Iodine value was zero in ozonized olive oil whereas in ozonized sunflower was 8.8 g Iodine per 100 g. The antimicrobial activity was similar for both ozonized oils except for Minimum Bactericidal Concentrations of Pseudomona aeruginosa. Composition of fatty acids in both ozonized oils showed gradual decrease in unsaturated fatty acids (C18:1, C18:2 with gradual increase in ozone doses.

Ozone damage to tobacco in Canada

Energy Technology Data Exchange (ETDEWEB)

Macdowall, F D.H.; Vickery, L S; Runeckles, V C; Patrick, Z A

1963-12-01

Tobacco weather fleck has caused significant losses of flue-cured tobacco in southern Ontario since 1955. Fleck damage was greatest near the coast of Lake Erie and decreased progressively inland. Ozone has been shown to be one of the most important incitants of the fleck response in tobacco whereas parasitic fungi, bacteria and viruses were proven not to be implicated as causes of the disorder. The inherently susceptible variety White Gold, used in all tests, was rendered more susceptible by irrigation and nitrogen deficiency. It was also more susceptible during flowering and when producing lateral shoots. The degree and duration of stomatal opening were important factors in determining the amount of injury. Concentration of ozone in the air was shown experimentally to affect the speed of fleck response as well as the severity of symptoms. Statistically significant correlations between ozone concentrations and fleck damage were obtained from field data when the response of highly susceptible tissues only was considered. The merits of several visual rating methods are compared and discussed. 22 references, 5 figures, 11 tables.

Foliar injury responses of eleven plant species to ozone/sulfur dioxide mixtures

Energy Technology Data Exchange (ETDEWEB)

Tingey, D T; Reinert, R A; Dunning, J A; Heck, W W

1973-01-01

Eleven plant species were exposed to ozone and/or sulfur dioxide to determine if a mixture of the two gases enhanced foliar injury. Tobacco, radish, and alfalfa developed more injury that the additive injury of the single gases. In other species, such as cabbage, broccoli, and tomato, the foliar injury from mixed-gas exposures was additive or less than additive. Leaf injury from the ozone/sulfur dioxide mixture appeared as upper surface flecking, stipple, bifacial necrosis, and lower surface glazing and, in general, appeared similar to injury from oxidant or ozone. The concentrations of ozone and sulfur dioxide that caused plant injury were similar to those found in urban areas. These concentrations may result in yield losses to plants grown under field conditions.

Tropospheric Ozone Change from 1980 to 2010 Dominated by Equatorward Redistribution of Emissions

Science.gov (United States)

Zhang, Yuqiang; Cooper, Owen R.; Gaudel, Audrey; Thompson, Anne M.; Nedelec, Philippe; Ogino, Shin-Ya; West, J. Jason

2016-01-01

Ozone is an important air pollutant at the surface, and the third most important anthropogenic greenhouse gas in the troposphere. Since 1980, anthropogenic emissions of ozone precursors methane, non-methane volatile organic compounds, carbon monoxide and nitrogen oxides (NOx) have shifted from developed to developing regions. Emissions have thereby been redistributed equatorwards, where they are expected to have a stronger effect on the tropospheric ozone burden due to greater convection, reaction rates and NOx sensitivity. Here we use a global chemical transport model to simulate changes in tropospheric ozone concentrations from 1980 to 2010, and to separate the influences of changes in the spatial distribution of global anthropogenic emissions of short-lived pollutants, the magnitude of these emissions, and the global atmospheric methane concentration. We estimate that the increase in ozone burden due to the spatial distribution change slightly exceeds the combined influences of the increased emission magnitude and global methane. Emission increases in Southeast, East and South Asia may be most important for the ozone change, supported by an analysis of statistically significant increases in observed ozone above these regions. The spatial distribution of emissions dominates global tropospheric ozone, suggesting that the future ozone burden will be determined mainly by emissions from low latitudes.

Brief communication: Loss of life due to Hurricane Harvey

Directory of Open Access Journals (Sweden)

S. N. Jonkman

2018-04-01

Full Text Available An analysis was made of the loss of life caused by Hurricane Harvey. Information was collected for 70 fatalities that occurred due to the event and were recovered within the first 2 weeks after landfall. Most fatalities occurred due to drowning (81 %, particularly in and around vehicles. Males (70 % and people over 50 years old (56 % were overrepresented in the dataset. More than half of the fatalities occurred in the greater Houston area (n  =  37, where heavy rainfall and dam releases caused unprecedented urban flooding. The majority of fatalities were recovered outside the designated 100- and 500-year flood hazard areas.

Ozone modeling within plasmas for ozone sensor applications

OpenAIRE

Arshak, Khalil; Forde, Edward; Guiney, Ivor

2007-01-01

peer-reviewed Ozone (03) is potentially hazardous to human health and accurate prediction and measurement of this gas is essential in addressing its associated health risks. This paper presents theory to predict the levels of ozone concentration emittedfrom a dielectric barrier discharge (DBD) plasma for ozone sensing applications. This is done by postulating the kinetic model for ozone generation, with a DBD plasma at atmospheric pressure in air, in the form of a set of rate equations....

Impact of parameterization choices on the restitution of ozone deposition over vegetation

Science.gov (United States)

Le Morvan-Quéméner, Aurélie; Coll, Isabelle; Kammer, Julien; Lamaud, Eric; Loubet, Benjamin; Personne, Erwan; Stella, Patrick

2018-04-01

Ozone is a potentially phyto-toxic air pollutant, which can cause leaf damage and drastically alter crop yields, causing serious economic losses around the world. The VULNOZ (VULNerability to OZone in Anthropised Ecosystems) project is a biology and modeling project that aims to understand how plants respond to the stress of high ozone concentrations, then use a set of models to (i) predict the impact of ozone on plant growth, (ii) represent ozone deposition fluxes to vegetation, and finally (iii) estimate the economic consequences of an increasing ozone background the future. In this work, as part of the VULNOZ project, an innovative representation of ozone deposition to vegetation was developed and implemented in the CHIMERE regional chemistry-transport model. This type of model calculates the average amount of ozone deposited on a parcel each hour, as well as the integrated amount of ozone deposited to the surface at the regional or country level. Our new approach was based on a refinement of the representation of crop types in the model and the use of empirical parameters specific to each crop category. The results obtained were compared with a conventional ozone deposition modeling approach, and evaluated against observations from several agricultural areas in France. They showed that a better representation of the distribution between stomatal and non-stomatal ozone fluxes was obtained in the empirical approach, and they allowed us to produce a new estimate of the total amount of ozone deposited on the subtypes of vegetation at the national level.

Iron doped fibrous-structured silica nanospheres as efficient catalyst for catalytic ozonation of sulfamethazine.

Science.gov (United States)

Bai, Zhiyong; Wang, Jianlong; Yang, Qi

2018-04-01

Sulfonamide antibiotics are ubiquitous pollutants in aquatic environments due to their large production and extensive application. In this paper, the iron doped fibrous-structured silica (KCC-1) nanospheres (Fe-KCC-1) was prepared, characterized, and applied as a catalyst for catalytic ozonation of sulfamethazine (SMT). The effects of ozone dosage, catalyst dosage, and initial concentration of SMT were examined. The experimental results showed that Fe-KCC-1 had large surface area (464.56 m2 g -1 ) and iron particles were well dispersed on the catalyst. The catalyst had high catalytic performance especially for the mineralization of SMT, with mineralization ratio of about 40% in a wide pH range. With addition of Fe-KCC-1, the ozone utilization increased nearly two times than single ozonation. The enhancement of SMT degradation was mainly due to the surface reaction, and the increased mineralization of SMT was due to radical mechanism. Fe-KCC-1 was an efficient catalyst for SMT degradation in catalytic ozonation system.

Limonene and its ozone-initiated reaction products attenuate allergic lung inflammation in mice.

Science.gov (United States)

Hansen, Jitka S; Nørgaard, Asger W; Koponen, Ismo K; Sørli, Jorid B; Paidi, Maya D; Hansen, Søren W K; Clausen, Per Axel; Nielsen, Gunnar D; Wolkoff, Peder; Larsen, Søren Thor

2016-11-01

Inhalation of indoor air pollutants may cause airway irritation and inflammation and is suspected to worsen allergic reactions. Inflammation may be due to mucosal damage, upper (sensory) and lower (pulmonary) airway irritation due to activation of the trigeminal and vagal nerves, respectively, and to neurogenic inflammation. The terpene, d-limonene, is used as a fragrance in numerous consumer products. When limonene reacts with the pulmonary irritant ozone, a complex mixture of gas and particle phase products is formed, which causes sensory irritation. This study investigated whether limonene, ozone or the reaction mixture can exacerbate allergic lung inflammation and whether airway irritation is enhanced in allergic BALB/cJ mice. Naïve and allergic (ovalbumin sensitized) mice were exposed via inhalation for three consecutive days to clean air, ozone, limonene or an ozone-limonene reaction mixture. Sensory and pulmonary irritation was investigated in addition to ovalbumin-specific antibodies, inflammatory cells, total protein and surfactant protein D in bronchoalveolar lavage fluid and hemeoxygenase-1 and cytokines in lung tissue. Overall, airway allergy was not exacerbated by any of the exposures. In contrast, it was found that limonene and the ozone-limonene reaction mixture reduced allergic inflammation possibly due to antioxidant properties. Ozone induced sensory irritation in both naïve and allergic mice. However, allergic but not naïve mice were protected from pulmonary irritation induced by ozone. This study showed that irritation responses might be modulated by airway allergy. However, aggravation of allergic symptoms was observed by neither exposure to ozone nor exposure to ozone-initiated limonene reaction products. In contrast, anti-inflammatory properties of the tested limonene-containing pollutants might attenuate airway allergy.

Landfill leachate treatment with ozone and ozone/hydrogen peroxide systems

International Nuclear Information System (INIS)

Tizaoui, Chedly; Bouselmi, Latifa; Mansouri, Loubna; Ghrabi, Ahmed

2007-01-01

In the search for an efficient and economical method to treat a leachate generated from a controlled municipal solid waste landfill site (Jebel Chakir) in the region of greater Tunis in Tunisia, ozone alone and ozone combined with hydrogen peroxide were studied. The leachate was characterised by high COD, low biodegradability and intense dark colour. A purpose-built reactor, to avoid foaming, was used for the study. It was found that ozone efficacy was almost doubled when combined with hydrogen peroxide at 2 g/L but higher H 2 O 2 concentrations gave lower performances. Enhancement in the leachate biodegradability from about 0.1 to about 0.7 was achieved by the O 3 /H 2 O 2 system. Insignificant changes in pH that may due to buffering effect of bicarbonate was found. A small decrease in sulphate concentrations were also observed. In contrast, chloride concentration declined at the beginning of the experiment then increased to reach its initial value. Estimates of the operating costs were made for comparison purposes and it was found that the O 3 /H 2 O 2 system at 2 g/L H 2 O 2 gave the lowest cost of about 3.1 TND (∼2.3 USD)/kg COD removed

Update of the Polar SWIFT model for polar stratospheric ozone loss (Polar SWIFT version 2)

Science.gov (United States)

Wohltmann, Ingo; Lehmann, Ralph; Rex, Markus

2017-07-01

The Polar SWIFT model is a fast scheme for calculating the chemistry of stratospheric ozone depletion in polar winter. It is intended for use in global climate models (GCMs) and Earth system models (ESMs) to enable the simulation of mutual interactions between the ozone layer and climate. To date, climate models often use prescribed ozone fields, since a full stratospheric chemistry scheme is computationally very expensive. Polar SWIFT is based on a set of coupled differential equations, which simulate the polar vortex-averaged mixing ratios of the key species involved in polar ozone depletion on a given vertical level. These species are O3, chemically active chlorine (ClOx), HCl, ClONO2 and HNO3. The only external input parameters that drive the model are the fraction of the polar vortex in sunlight and the fraction of the polar vortex below the temperatures necessary for the formation of polar stratospheric clouds. Here, we present an update of the Polar SWIFT model introducing several improvements over the original model formulation. In particular, the model is now trained on vortex-averaged reaction rates of the ATLAS Chemistry and Transport Model, which enables a detailed look at individual processes and an independent validation of the different parameterizations contained in the differential equations. The training of the original Polar SWIFT model was based on fitting complete model runs to satellite observations and did not allow for this. A revised formulation of the system of differential equations is developed, which closely fits vortex-averaged reaction rates from ATLAS that represent the main chemical processes influencing ozone. In addition, a parameterization for the HNO3 change by denitrification is included. The rates of change of the concentrations of the chemical species of the Polar SWIFT model are purely chemical rates of change in the new version, whereas in the original Polar SWIFT model, they included a transport effect caused by the

Quasi-biennial oscillation in atmospheric ozone, and its possible consequences for damaging UV-B radiation and for determination of long-term ozone trends

Energy Technology Data Exchange (ETDEWEB)

Gruzdev, A N [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Atmospheric Physics

1996-12-31

The quasi-biennial oscillation (QBO) in ozone is supposed to be related to the QBO of zonal wind in the tropical stratosphere, with an approximate period of 29 months. Generally speaking, mechanisms of QBO-related effects in the extratropical atmosphere should depend on season and region, resulting in other periodicities (e.g., a 20-month periodicity) due to nonlinear interaction between the `pure` QBO and an annual cycle. Seasonal and regional dependences of QBO-related effects in ozone not only influence the regime of ozone variability itself, but can have important consequences, for example, for interannual changes in biologically active UV-B radiation and for determination of long-term ozone trends. This work is concerned with these problems

Quasi-biennial oscillation in atmospheric ozone, and its possible consequences for damaging UV-B radiation and for determination of long-term ozone trends

Energy Technology Data Exchange (ETDEWEB)

Gruzdev, A.N. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Atmospheric Physics

1995-12-31

The quasi-biennial oscillation (QBO) in ozone is supposed to be related to the QBO of zonal wind in the tropical stratosphere, with an approximate period of 29 months. Generally speaking, mechanisms of QBO-related effects in the extratropical atmosphere should depend on season and region, resulting in other periodicities (e.g., a 20-month periodicity) due to nonlinear interaction between the `pure` QBO and an annual cycle. Seasonal and regional dependences of QBO-related effects in ozone not only influence the regime of ozone variability itself, but can have important consequences, for example, for interannual changes in biologically active UV-B radiation and for determination of long-term ozone trends. This work is concerned with these problems

Expected Performance of Ozone Climate Data Records from Ozone Mapping and Profiler Suite Limb Profiler

Science.gov (United States)

Xu, P. Q.; Rault, D. F.; Pawson, S.; Wargan, K.; Bhartia, P. K.

2012-01-01

The Ozone Mapping and Profiler Suite Limb Profiler (OMPS/LP) was launched on board of the Soumi NPP space platform in late October 2011. It provides ozone-profiling capability with high-vertical resolution from 60 Ian to cloud top. In this study, an end-to-end Observing System Simulation Experiment (OSSE) of OMPS/LP ozone is discussed. The OSSE was developed at NASA's Global Modeling and Assimilation Office (GMAO) using the Goddard Earth Observing System (GEOS-5) data assimilation system. The "truth" for this OSSE is built by assimilating MLS profiles and OMI ozone columns, which is known to produce realistic three-dimensional ozone fields in the stratosphere and upper troposphere. OMPS/LP radiances were computed at tangent points computed by an appropriate orbital model. The OMPS/LP forward RT model, Instrument Models (IMs) and EDR retrieval model were introduced and pseudo-observations derived. The resultant synthetic OMPS/LP observations were evaluated against the "truth" and subsequently these observations were assimilated into GEOS-5. Comparison of this assimilated dataset with the "truth" enables comparisons of the likely uncertainties in 3-D analyses of OMPS/LP data. This study demonstrated the assimilation capabilities of OMPS/LP ozone in GEOS-5, with the monthly, zonal mean (O-A) smaller than 0.02ppmv at all levels, the nns(O-A) close to O.lppmv from 100hPa to 0.2hPa; and the mean(O-B) around the 0.02ppmv for all levels. The monthly zonal mean analysis generally agrees to within 2% of the truth, with larger differences of 2-4% (0.1-0.2ppmv) around 10hPa close to North Pole and in the tropical tropopause region, where the difference is above 20% due to the very low ozone concentrations. These OSSEs demonstrated that, within a single data assimilation system and the assumption that assimilated MLS observations provide a true rendition of the stratosphere, the OMPS/LP ozone data are likely to produce accurate analyses through much of the stratosphere

Ozone decomposition

Directory of Open Access Journals (Sweden)

Batakliev Todor

2014-06-01

Full Text Available Catalytic ozone decomposition is of great significance because ozone is a toxic substance commonly found or generated in human environments (aircraft cabins, offices with photocopiers, laser printers, sterilizers. Considerable work has been done on ozone decomposition reported in the literature. This review provides a comprehensive summary of the literature, concentrating on analysis of the physico-chemical properties, synthesis and catalytic decomposition of ozone. This is supplemented by a review on kinetics and catalyst characterization which ties together the previously reported results. Noble metals and oxides of transition metals have been found to be the most active substances for ozone decomposition. The high price of precious metals stimulated the use of metal oxide catalysts and particularly the catalysts based on manganese oxide. It has been determined that the kinetics of ozone decomposition is of first order importance. A mechanism of the reaction of catalytic ozone decomposition is discussed, based on detailed spectroscopic investigations of the catalytic surface, showing the existence of peroxide and superoxide surface intermediates

Global earthquake casualties due to secondary effects: A quantitative analysis for improving rapid loss analyses

Science.gov (United States)

Marano, K.D.; Wald, D.J.; Allen, T.I.

2010-01-01

This study presents a quantitative and geospatial description of global losses due to earthquake-induced secondary effects, including landslide, liquefaction, tsunami, and fire for events during the past 40 years. These processes are of great importance to the US Geological Survey's (USGS) Prompt Assessment of Global Earthquakes for Response (PAGER) system, which is currently being developed to deliver rapid earthquake impact and loss assessments following large/significant global earthquakes. An important question is how dominant are losses due to secondary effects (and under what conditions, and in which regions)? Thus, which of these effects should receive higher priority research efforts in order to enhance PAGER's overall assessment of earthquakes losses and alerting for the likelihood of secondary impacts? We find that while 21.5% of fatal earthquakes have deaths due to secondary (non-shaking) causes, only rarely are secondary effects the main cause of fatalities. The recent 2004 Great Sumatra-Andaman Islands earthquake is a notable exception, with extraordinary losses due to tsunami. The potential for secondary hazards varies greatly, and systematically, due to regional geologic and geomorphic conditions. Based on our findings, we have built country-specific disclaimers for PAGER that address potential for each hazard (Earle et al., Proceedings of the 14th World Conference of the Earthquake Engineering, Beijing, China, 2008). We will now focus on ways to model casualties from secondary effects based on their relative importance as well as their general predictability. ?? Springer Science+Business Media B.V. 2009.

Aviation-attributable ozone as a driver for changes in mortality related to air quality and skin cancer

Science.gov (United States)

Eastham, Sebastian D.; Barrett, Steven R. H.

2016-11-01

Aviation is a significant source of tropospheric ozone, which is a critical UV blocking agent, an indirect precursor to the formation of particulate matter, and a respiratory health hazard. To date, investigations of human health impacts related to aviation emissions have focused on particulate matter, and no global estimate yet exists of the combined health impact of aviation due to ozone, particulate matter and UV exposure changes. We use a coupled tropospheric-stratospheric chemical-transport model with a global aviation emissions inventory to estimate the total impact of aviation on all three risk factors. We find that surface ozone due to aviation emissions is maximized during hemispheric winter due to the greater wintertime chemical lifetime of ozone, but that a smaller enhancement of 0.5 ppbv occurs during summertime. This summertime increase results in an estimated 6,800 premature mortalities per year due to ozone exposure, over three times greater than previous estimates. During the winter maximum, interaction with high background NOx concentrations results in enhanced production of nitrate aerosol and increased annual average exposure to particulate matter. This ozone perturbation is shown to be the driving mechanism behind an additional 9,200 premature mortalities due to exposure to particulate matter. However, the increase in tropospheric ozone is also found to result in 400 fewer mortalities due to melanoma skin cancer in 2006. This is the first estimate of global melanoma mortality due to aviation, and the first estimate of skin cancer mortality impacts due to aviation using a global chemical transport model.

Ozone air pollution effects on tree-ring growth,{delta}{sup 13}C, visible foliar injury and leaf gas exchange in three ozone-sensitive woody plant species

Energy Technology Data Exchange (ETDEWEB)

Novak, K. [Swiss Federal Inst. for Forest, Snow and Landscape Research, Birmensdorf (Switzerland); Agroscope FAL Reckenholz, Swiss Federal Research Station for Agroecology and Agriculture, Zurich (Switzerland); Saurer, M. [Paul Scherrer Inst. Villigen (Switzerland); Fuhrer, J. [Agroscope FAL Reckenholz, Swiss Federal Research Station for Agroecology and Agriculture, Zurich (Switzerland); Skelly, J.M. [Pennsylvania State Univ., University Park, PA (United States). Dept. of Plant Pathology; Krauchi, N.; Schaub, M. [Swiss Federal Inst. for Forest, Snow and Landscape Research, Birmensdorf (Switzerland)

2007-07-15

Species specific plant responses to tropospheric ozone pollution depend on a range of morphological, biochemical and physiological characteristics as well as environmental factors. The effects of ambient tropospheric ozone on annual tree-ring growth, {delta}{sup 13} C in the rings, leaf gas exchange and ozone-induced visible foliar injury in three ozone-sensitive woody plant species in southern Switzerland were assessed during the 2001 and 2002 growing seasons. Seedlings of Populus nigra L., Viburnum lantana L. and Fraxinus excelsior L. were exposed to charcoal-filtered air and non-filtered air in open-top chambers, and to ambient air (AA) in open plots. The objective was to determine if a relationship exists between measurable ozone-induced effects at the leaf level and subsequent changes in annual tree-ring growth and {delta} {sup 13} C signatures. The visible foliar injury, early leaf senescence and premature leaf loss in all species was attributed to the ambient ozone exposures in the region. Ozone had pronounced negative effects on net photosynthesis and stomatal conductance in all species in 2002 and in V. lantana and F. excelsior in 2001. Water-use efficiency decreased and intercellular carbon dioxide concentrations increased in all species in response to ozone in 2002 only. The width and {delta}{sup 13} C of the 2001 and 2002 growth rings were measured for all species at the end of the 2002 growing season. Significant ozone-induced effects at the leaf level did not correspond to reduced tree-ring growth or increased {delta}{sup 13} C in all species, suggesting that the timing of ozone exposure and extent of leaf-level responses may be relevant in determining the sensitivity of tree productivity to ozone exposure. 48 refs., 4 tabs., 2 figs.

Solar Backscatter UV (SBUV total ozone and profile algorithm

Directory of Open Access Journals (Sweden)

P. K. Bhartia

2013-10-01

Full Text Available We describe the algorithm that has been applied to develop a 42 yr record of total ozone and ozone profiles from eight Solar Backscatter UV (SBUV instruments launched on NASA and NOAA satellites since April 1970. The Version 8 (V8 algorithm was released more than a decade ago and has been in use since then at NOAA to produce their operational ozone products. The current algorithm (V8.6 is basically the same as V8, except for updates to instrument calibration, incorporation of new ozone absorption cross-sections, and new ozone and cloud height climatologies. Since the V8 algorithm has been optimized for deriving monthly zonal mean (MZM anomalies for ozone assessment and model comparisons, our emphasis in this paper is primarily on characterizing the sources of errors that are relevant for such studies. When data are analyzed this way the effect of some errors, such as vertical smoothing of short-term variability, and noise due to clouds and aerosols diminish in importance, while the importance of others, such as errors due to vertical smoothing of the quasi-biennial oscillation (QBO and other periodic and aperiodic variations, become more important. With V8.6 zonal mean data we now provide smoothing kernels that can be used to compare anomalies in SBUV profile and partial ozone columns with models. In this paper we show how to use these kernels to compare SBUV data with Microwave Limb Sounder (MLS ozone profiles. These kernels are particularly useful for comparisons in the lower stratosphere where SBUV profiles have poor vertical resolution but partial column ozone values have high accuracy. We also provide our best estimate of the smoothing errors associated with SBUV MZM profiles. Since smoothing errors are the largest source of uncertainty in these profiles, they can be treated as error bars in deriving interannual variability and trends using SBUV data and for comparing with other measurements. In the V8 and V8.6 algorithms we derive total

Ozone decay in chemical reactor for ozone-dynamical disintegration of used tyres

International Nuclear Information System (INIS)

Golota, V.I.; Manuilenko, O.V.; Taran, G.V.; Dotsenko, Yu.V.; Pismenetskii, A.S.; Zamuriev, A.A.; Benitskaja, V.A.

2011-01-01

The ozone decay kinetics in the chemical reactor intended for used tyres disintegration is investigated experimentally and theoretically. Ozone was synthesized in barrierless ozonizers based on the streamer discharge. The chemical reactor for tyres disintegration in the ozone-air environment represents the cylindrical chamber, which feeds from the ozonizer by ozone-air mixture with the specified rate of volume flow, and with known ozone concentration. The output of the used mixture, which rate of volume flow is also known, is carried out through the ozone destructor. As a result of ozone decay in the volume and on the reactor walls, and output of the used mixture from the reactor, the ozone concentration in the reactor depends from time. In the paper, the analytical expression for dependence of ozone concentration in the reactor from time and from the parameters of a problem such as the volumetric feed rate, ozone concentration on the input in the reactor, volume flow rate of the used mixture, the volume of the reactor and the area of its internal surface is obtained. It is shown that experimental results coincide with good accuracy with analytical ones.

Impact of enhanced ozone deposition and halogen chemistry on model performance

Science.gov (United States)

In this study, an enhanced ozone deposition scheme due to the interaction of iodide in sea-water and atmospheric ozone and the detailed chemical reactions of organic and inorganic halogen species are incorporated into the hemispheric Community Multiscale Air Quality model. Prelim...

A new diagnostic for tropospheric ozone production

Science.gov (United States)

Edwards, Peter M.; Evans, Mathew J.

2017-11-01

Tropospheric ozone is important for the Earth's climate and air quality. It is produced during the oxidation of organics in the presence of nitrogen oxides. Due to the range of organic species emitted and the chain-like nature of their oxidation, this chemistry is complex and understanding the role of different processes (emission, deposition, chemistry) is difficult. We demonstrate a new methodology for diagnosing ozone production based on the processing of bonds contained within emitted molecules, the fate of which is determined by the conservation of spin of the bonding electrons. Using this methodology to diagnose ozone production in the GEOS-Chem chemical transport model, we demonstrate its advantages over the standard diagnostic. We show that the number of bonds emitted, their chemistry and lifetime, and feedbacks on OH are all important in determining the ozone production within the model and its sensitivity to changes. This insight may allow future model-model comparisons to better identify the root causes of model differences.

A new diagnostic for tropospheric ozone production

Directory of Open Access Journals (Sweden)

P. M. Edwards

2017-11-01

Full Text Available Tropospheric ozone is important for the Earth's climate and air quality. It is produced during the oxidation of organics in the presence of nitrogen oxides. Due to the range of organic species emitted and the chain-like nature of their oxidation, this chemistry is complex and understanding the role of different processes (emission, deposition, chemistry is difficult. We demonstrate a new methodology for diagnosing ozone production based on the processing of bonds contained within emitted molecules, the fate of which is determined by the conservation of spin of the bonding electrons. Using this methodology to diagnose ozone production in the GEOS-Chem chemical transport model, we demonstrate its advantages over the standard diagnostic. We show that the number of bonds emitted, their chemistry and lifetime, and feedbacks on OH are all important in determining the ozone production within the model and its sensitivity to changes. This insight may allow future model–model comparisons to better identify the root causes of model differences.

Shelf Life Determination of Fresh Blueberries (Vaccinium corymbosum Stored under Controlled Atmosphere and Ozone

Directory of Open Access Journals (Sweden)

Anibal Concha-Meyer

2015-01-01

Full Text Available Fresh blueberries are commonly stored and transported by refrigeration in controlled atmospheres to protect shelf life for long periods of storage. Ozone is an antimicrobial gas that can extend shelf life and protect fruit from microbial contamination. Shelf life of fresh highbush blueberries was determined over 10-day storage in isolated cabinets at 4°C or 12°C under different atmosphere conditions, including air (control; 5% O2 : 15% CO2 : 80% N2 (controlled atmosphere storage (CAS; and ozone gas (O3 4 ppm at 4°C or 2.5 ppm at 12°C, at high relative humidity (90–95%. Samples were evaluated for yeast and molds growth, weight loss, and firmness. CAS and O3 did not delay or inhibit yeast and molds growth in blueberries after 10 days at both temperatures. Fruit stored at 4°C showed lower weight loss values compared with 12°C. Blueberries stored under O3 atmosphere showed reduced weight loss at 12°C by day 10 and loss of firmness when compared to the other treatments. Low concentrations of ozone gas together with proper refrigeration temperature can help protect fresh blueberries quality during storage.

Shelf Life Determination of Fresh Blueberries (Vaccinium corymbosum) Stored under Controlled Atmosphere and Ozone.

Science.gov (United States)

Concha-Meyer, Anibal; Eifert, Joseph D; Williams, Robert C; Marcy, Joseph E; Welbaum, Gregory E

2015-01-01

Fresh blueberries are commonly stored and transported by refrigeration in controlled atmospheres to protect shelf life for long periods of storage. Ozone is an antimicrobial gas that can extend shelf life and protect fruit from microbial contamination. Shelf life of fresh highbush blueberries was determined over 10-day storage in isolated cabinets at 4°C or 12°C under different atmosphere conditions, including air (control); 5% O2 : 15% CO2 : 80% N2 (controlled atmosphere storage (CAS)); and ozone gas (O3) 4 ppm at 4°C or 2.5 ppm at 12°C, at high relative humidity (90-95%). Samples were evaluated for yeast and molds growth, weight loss, and firmness. CAS and O3 did not delay or inhibit yeast and molds growth in blueberries after 10 days at both temperatures. Fruit stored at 4°C showed lower weight loss values compared with 12°C. Blueberries stored under O3 atmosphere showed reduced weight loss at 12°C by day 10 and loss of firmness when compared to the other treatments. Low concentrations of ozone gas together with proper refrigeration temperature can help protect fresh blueberries quality during storage.

Apparent losses due to domestic water meter under-registration in South Africa

OpenAIRE

Couvelis, FA; van Zyl, JE

2015-01-01

This study investigated the extent of apparent losses due to water meter under-registration in South Africa. This was done by first estimating the under-registration of new meters due to on-site leakage, and then the additional under-registration due to meter aging. The extent and flow distributions of on-site leakage were determined through field studies in Cape Town, Mangaung and Johannesburg, by measuring the flow through new water meters when no legitimate consumption occurred on the prop...

Occurrence of ozone anomalies over cloudy areas in TOMS version-7 level-2 data

Directory of Open Access Journals (Sweden)

X. Liu

2003-01-01

Full Text Available This study investigates anomalous ozone distributions over cloudy areas in Nimbus-7 (N7 and Earth-Probe (EP TOMS version-7 data and analyzes the causes for ozone anomaly formation. A 5°-longitude by 5°-latitude region is defined to contain a Positive Ozone Anomaly (POA or Negative Ozone Anomaly (NOA if the correlation coefficient between total ozone and reflectivity is > 0.5 or -0.5. The average fractions of ozone anomalies among all cloud fields are 31.8 ± 7.7% and 35.8 ± 7.7% in the N7 and EP TOMS data, respectively. Some ozone anomalies are caused by ozone retrieval errors, and others are caused by actual geophysical phenomena. Large cloud-height errors are found in the TOMS version-7 algorithm in comparison to the Temperature Humidity Infrared Radiometer (THIR cloud data. On average, cloud-top pressures are overestimated by ~200 hPa (THIR cloud-top pressure 200 hPa for high-altitude clouds and underestimated by ~150 hPa for low-altitude clouds (THIR cloud-top pressure > 750 hPa. Most tropical NOAs result from negative errors induced by large cloud-height errors, and most tropical POAs are caused by positive errors due to intra-cloud ozone absorption enhancement. However, positive and negative errors offset each other, reducing the ozone anomaly occurrence in TOMS data. Large ozone/reflectivity slopes for mid-latitude POAs show seasonal variation consistent with total ozone fluctuation, indicating that they result mainly from synoptic and planetary wave disturbances. POAs with an occurrence fraction of 30--60% occur in regions of marine stratocumulus off the west coast of South Africa and off the west coast of South America. Both fractions and ozone/reflectivity slopes of these POAs show seasonal variations consistent with that in the tropospheric ozone. About half the ozone/reflectivity slope can be explained by ozone retrieval errors over clear and cloudy areas. The remaining slope may result from there being more ozone production

Chloroplastic responses of ponderosa pine (Pinus ponderosa) seedlings to ozone exposure.

Science.gov (United States)

Anderson, Paul D; Palmer, Brent; Houpis, James L J; Smith, Mary K; Pushnik, James C

2003-06-01

Integrity of chloroplast membranes is essential to photosynthesis. Loss of thylakoid membrane integrity has been proposed as a consequence of ozone (O(3)) exposure and therefore may be a mechanistic basis for decreased photosynthetic rates commonly associated with ozone exposure. To investigate this hypothesis, Pinus ponderosa seedlings were exposed to ambient air or ozone concentrations maintained at 0.15 or 0.30 microliter l(-1) for 10 h day(-1) for 51 days during their second growing season. Over the course of the study, foliage samples were periodically collected for thylakoid membrane, chlorophyll and protein analyses. Additionally, gas-exchange measurements were made in conjunction with foliage sampling to verify that observed chloroplastic responses were associated with ozone-induced changes in photosynthesis. Needles exposed to elevated ozone exhibited decreases in chlorophyll a and b content. The decreases were dependent on the duration and intensity of ozone exposure. When based on equal amounts of chlorophyll, ozone-exposed sample tissue exhibited an increase in total protein. When based on equal amounts of protein, ozone-exposed samples exhibited an increase in 37 kDa proteins, possibly consisting of breakdown products, and a possible decrease in 68 kDa proteins, Rubisco small subunit. There was also a change in the ratio of Photosystem I protein complexes CPI and CPII that may have contributed to decreased photosynthesis. Net photosynthetic rates were decreased in the high ozone treatment suggesting that observed structural and biochemical changes in the chloroplast were associated with alterations of the photosynthetic process.

Rates and regimes of photochemical ozone production over Central East China in June 2006: a box model analysis using comprehensive measurements of ozone precursors

Directory of Open Access Journals (Sweden)

Y. Kanaya

2009-10-01

Full Text Available An observation-based box model approach was undertaken to estimate concentrations of OH, HO₂, and RO₂ radicals and the net photochemical production rate of ozone at the top of Mount Tai, located in the middle of Central East China, in June 2006. The model calculation was constrained by the measurements of O₃, H₂O, CO, NO, NO₂, hydrocarbon, HCHO, and CH₃CHO concentrations, and temperature and J values. The net production rate of ozone was estimated to be 6.4 ppb h⁻¹ as a 6-h average (09:00–15:00 CST, suggesting 58±37 ppb of ozone is produced in one day. Thus the daytime buildup of ozone recorded at the mountain top as ~23 ppb on average is likely affected by in situ photochemistry as well as by the upward transport of polluted air mass in the daytime. On days with high ozone concentrations (hourly values exceeding 100 ppb at least once, in situ photochemistry was more active than it was on low ozone days, suggesting that in situ photochemistry is an important factor controlling ozone concentrations. Sensitivity model runs for which different NO_x and hydrocarbon concentrations were assumed suggested that the ozone production occurred normally under NO_x-limited conditions, with some exceptional periods (under volatile-organic-compound-limited conditions in which there was fresh pollution. We also examined the possible influence of the heterogeneous loss of gaseous HO₂ radicals in contact with aerosol particle surfaces on the rate and regimes of ozone production.

Hydrogen emissions and their effects on the arctic ozone losses. Risk analysis of a global hydrogen economy; Wasserstoff-Emissionen und ihre Auswirkungen auf den arktischen Ozonverlust. Risikoanalyse einer globalen Wasserstoffwirtschaft

Energy Technology Data Exchange (ETDEWEB)

Feck, Thomas

2009-07-01

Hydrogen (H{sub 2}) could be used as one of the major components in our future energy supply in an effort to avoid greenhouse gas emissions. ''Green'' hydrogen in particular, which is produced from renewable energy sources, should significantly reduce emissions that damage the climate. Despite this basically environmentally-friendly property, however, the complex chain of interactions of hydrogen with other compounds means that the implications for the atmosphere must be analysed in detail. For example, H{sub 2} emissions, which could increase the tropospheric H{sub 2} inventory, can be released throughout the complete hydrogen process chain. H{sub 2} enters the stratosphere via the tropical tropopause and is oxidised there to form water vapour (H{sub 2}O). This extra water vapour causes increased radiation in the infrared region of the electromagnetic spectrum and thus causes the stratosphere to cool down. Both the increase in H{sub 2}O and the resulting cooling down of the stratosphere encourage the formation of polar stratospheric clouds (PSC) and liquid sulphate aerosols, which facilitate the production of reactive chlorine, which in turn currently leads to dramatic ozone depletion in the polar stratosphere. In the future, H{sub 2} emissions from a global hydrogen economy could therefore encourage stratospheric ozone depletion in the polar regions and thus inhibit the ozone layer in recovering from the damage caused by chlorofluorocarbons (CFCs). In addition to estimating possible influences on the trace gas composition of the stratosphere, one of the main aims of this thesis is to evaluate the risk associated with increased polar ozone depletion caused by additional H{sub 2} emissions. Studies reported on here have shown that even if around 90% of today's fossil primary energy input was to be replaced by hydrogen and if around 9.5% of the gas was to escape in a ''worst-case'' scenario, the additional ozone loss for

Removal of blue-green algae using the hybrid method of hydrodynamic cavitation and ozonation.

Science.gov (United States)

Wu, Zhilin; Shen, Haifeng; Ondruschka, Bernd; Zhang, Yongchun; Wang, Weimin; Bremner, David H

2012-10-15

A suspension of Microcystis aeruginosa (30 μg L(-1)chlorophyll a) was circulated in a hydrodynamic cavitation device and ozone was introduced at the suction side of the pump. The removal of algae over 10 min using hydrodynamic cavitation alone and ozone alone is less than 15% and 35%, respectively. The destruction of algae rises significantly from 24% in the absence of the orifice to 91% with the optimized orifice on 5 min of processing using hydrodynamic cavitation along with ozone (HC/O(3)) and the utilization of ozone increases from 32% to 61%. Interestingly, the suction process is more effective than the extrusion method (positive pressure) and the optimal bulk temperature for algal elimination was found to be 20 °C. Increasing the input concentration of ozone is favorable for the removal of algae but leads to a greater loss of ozone and a decrease in the utilization of ozone. Under the optimal conditions, the algal cells and chlorophyll a are completely destroyed in 10 min by use of the hybrid method. Copyright © 2012 Elsevier B.V. All rights reserved.

CONTRIBUTION TO INDOOR OZONE LEVELS OF AN OZONE GENERATOR

Science.gov (United States)

This report gives results of a study of a commonly used commercially available ozone generator, undertaken to determine its impact on indoor ozone levels. xperiment were conducted in a typical mechanically ventilated office and in a test house. he generated ozone and the in-room ...

Development of Compact Ozonizer with High Ozone Output by Pulsed Power

Science.gov (United States)

Tanaka, Fumiaki; Ueda, Satoru; Kouno, Kanako; Sakugawa, Takashi; Akiyama, Hidenori; Kinoshita, Youhei

Conventional ozonizer with a high ozone output using silent or surface discharges needs a cooling system and a dielectric barrier, and therefore becomes a large machine. A compact ozonizer without the cooling system and the dielectric barrier has been developed by using a pulsed power generated discharge. The wire to plane electrodes made of metal have been used. However, the ozone output was low. Here, a compact and high repetition rate pulsed power generator is used as an electric source of a compact ozonizer. The ozone output of 6.1 g/h and the ozone yield of 86 g/kWh are achieved at 500 pulses per second, input average power of 280 W and an air flow rate of 20 L/min.

Application of ozonation for pharmaceuticals and personal care products removal from water.

Science.gov (United States)

Gomes, João; Costa, Raquel; Quinta-Ferreira, Rosa M; Martins, Rui C

2017-05-15

Due to the shortening on natural water resources, reclaimed wastewater will be an important water supply source. However, suitable technologies must be available to guaranty its proper detoxification with special concern for the emerging pharmaceutical and personal care products that are continuously reaching municipal wastewater treatment plants. While conventional biological systems are not suitable to remove these compounds, ozone, due to its interesting features involving molecular ozone oxidation and the possibility of generating unselective hydroxyl radicals, has a wider range of action on micropollutants removal and water disinfection. This paper aims to review the studies dealing with ozone based processes for water reuse by considering municipal wastewater reclamation as well as natural and drinking water treatment. A comparison with alternative technologies is given. The main drawback of ozonation is related with the low mineralization achieved that may lead to the production of reaction intermediates with toxic features. The use of hydrogen peroxide and light aided systems enhance ozone action over pollutants. Moreover, scientific community is focused on the development of solid catalysts able to improve the mineralization level achieved by ozone. Special interest is now being given to solar light catalytic ozonation systems with interesting results both for chemical and biological contaminants abatement. Nowadays the integration between ozonation and sand biofiltration seems to be the most interesting cost effective methodology for water treatment. However, further studies must be performed to optimize this system by understanding the biofiltration mechanisms. Copyright © 2017 Elsevier B.V. All rights reserved.

Impact of future nitrous oxide and carbon dioxide emissions on the stratospheric ozone layer

International Nuclear Information System (INIS)

Stolarski, Richard S; Waugh, Darryn W; Douglass, Anne R; Oman, Luke D

2015-01-01

The atmospheric levels of human-produced chlorocarbons and bromocarbons are projected to make only small contributions to ozone depletion by 2100. Increases in carbon dioxide (CO 2 ) and nitrous oxide (N 2 O) will become increasingly important in determining the future of the ozone layer. N 2 O increases lead to increased production of nitrogen oxides (NO x ), contributing to ozone depletion. CO 2 increases cool the stratosphere and affect ozone levels in several ways. Cooling decreases the rate of many photochemical reactions, thus slowing ozone loss rates. Cooling also increases the chemical destruction of nitrogen oxides, thereby moderating the effect of increased N 2 O on ozone depletion. The stratospheric ozone level projected for the end of this century therefore depends on future emissions of both CO 2 and N 2 O. We use a two-dimensional chemical transport model to explore a wide range of values for the boundary conditions for CO 2 and N 2 O, and find that all of the current scenarios for growth of greenhouse gases project the global average ozone to be larger in 2100 than in 1960. (letter)

Ozone-induced gene expression occurs via ethylene-dependent and -independent signalling.

Science.gov (United States)

Grimmig, Bernhard; Gonzalez-Perez, Maria N; Leubner-Metzger, Gerhard; Vögeli-Lange, Regina; Meins, Fred; Hain, Rüdiger; Penuelas, Josep; Heidenreich, Bernd; Langebartels, Christian; Ernst, Dieter; Sandermann, Heinrich

2003-03-01

Recent studies suggest that ethylene is involved in signalling ozone-induced gene expression. We show here that application of ozone increased glucuronidase (GUS) expression of chimeric reporter genes regulated by the promoters of the tobacco class I beta-1,3-glucanases (GLB and Gln2) and the grapevine resveratrol synthase (Vst1) genes in transgenic tobacco leaves. 5'-deletion analysis of the class I beta-1,3-glucanase promoter revealed that ozone-induced gene regulation is mainly mediated by the distal enhancer region containing the positively acting ethylene-responsive element (ERE). In addition, application of 1-methylcyclopropene (1-MCP), an inhibitor of ethylene action, blocked ozone-induced class I beta-1,3-glucanase promoter activity. Enhancer activity and ethylene-responsiveness depended on the integrity of the GCC boxes, cis-acting elements present in the ERE of the class I beta-1,3-glucanase and the basic-type pathogenesis-related PR-1 protein (PRB-1b) gene promoters. The minimal PRB-1b promoter containing only the ERE with intact GCC boxes, was sufficient to confer 10-fold ozone inducibility to a GUS-reporter gene, while a substitution mutation in the GCC box abolished ozone responsiveness. The ERE region of the class I beta-1,3-glucanase promoter containing two intact GCC boxes confered strong ozone inducibility to a minimal cauliflower mosaic virus (CaMV) 35S RNA promoter, whereas two single-base substitution in the GCC boxes resulted in a complete loss of ozone inducibility. Taken together, these datastrongly suggest that ethylene is signalling ozone-induced expression of class I beta-l,3-glucanase and PRB-1b genes. Promoter analysis of the stilbene synthase Vst1 gene unravelled different regions for ozone and ethylene-responsiveness. Application of 1-MCP blocked ethylene-induced Vst1 induction, but ozone induction was not affected. This shows that ozone-induced gene expression occurs via at least two different signalling mechanisms and suggests an

Application of ozone in the treatment of periodontal disease

Science.gov (United States)

Srikanth, Adusumilli; Sathish, Manthena; Sri Harsha, Anumolu Venkatanaga

2013-01-01

Gingivitis and periodontitis are most common inflammatory diseases of supporting tissues of teeth. Role of microbial etiology and host response in progression of gingival and periodontal diseases has been well established. Because of the beneficial biological effects of ozone, due to its antimicrobial and immunostimulating effect, it is well indicated in the treatment of gingival and periodontal diseases. The objective of this article is to provide a general review about clinical applications of ozone in treatment of periodontal diseases and to summarize the available in vitro and in vivo studies in Periodontics in which ozone has been used. PMID:23946585

Secondary maxima in ozone profiles

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R. Lemoine

2004-01-01

Full Text Available Ozone profiles from balloon soundings as well as SAGEII ozone profiles were used to detect anomalous large ozone concentrations of ozone in the lower stratosphere. These secondary ozone maxima are found to be the result of differential advection of ozone-poor and ozone-rich air associated with Rossby wave breaking events. The frequency and intensity of secondary ozone maxima and their geographical distribution is presented. The occurrence and amplitude of ozone secondary maxima is connected to ozone variability and trend at Uccle and account for a large part of the total ozone and lower stratospheric ozone variability.

Near-ground ozone source attributions and outflow in central eastern China during MTX2006

Science.gov (United States)

Li, J.; Wang, Z.; Akimoto, H.; Yamaji, K.; Takigawa, M.; Pochanart, P.; Liu, Y.; Tanimoto, H.; Kanaya, Y.

2008-12-01

A 3-D regional chemical transport model, the Nested Air Quality Prediction Model System (NAQPMS), with an on-line tracer tagging module was used to study the source of the near-ground (pollutants, and it captured highly polluted and clean cases well. The simulated near-ground ozone level over CEC was 60-85 ppbv (parts per billion by volume), which was higher than values in Japan and over the North Pacific (20-50 ppbv). The simulated tagged tracer data indicated that the regional-scale transport of chemically produced ozone over other areas in CEC contributed to the greatest fraction (49%) of the near-ground mean ozone at Mt. Tai in June; in situ photochemistry contributed only 12%. Due to high anthropogenic and biomass burning emissions that occurred in the southern part of the CEC, the contribution to ground ozone levels from this area played the most important role (32.4 ppbv, 37.9% of total ozone) in the monthly mean ozone concentration at Mt. Tai; values reached 59 ppbv (62%) on 6-7 June 2006. The monthly mean horizontal distribution of chemically produced ozone from various ozone production regions indicated that photochemical reactions controlled the spatial distribution of O3 over CEC. The regional-scale transport of pollutants also played an important role in the spatial and temporal distribution of ozone over CEC. Chemically produced ozone from the southern part of the study region can be transported northeastwardly to the northern rim of CEC; the mean contribution was 5-10 ppbv, and it reached 25 ppbv during high ozone events. Studies of the outflow of CEC ozone and its precursors, as well as their influences and contributions to the ozone level over adjacent regions/countries, revealed that the contribution of CEC ozone to mean ozone mixing ratios over the Korean Peninsula and Japan was 5-15 ppbv, of which about half was due to the direct transport of ozone from CEC and half was produced locally by ozone precursors transported from CEC.

Diclofenac removal from water with ozone and activated carbon.

Science.gov (United States)

Beltrán, Fernando J; Pocostales, Pablo; Alvarez, Pedro; Oropesa, Ana

2009-04-30

Diclofenac (DCF) has been treated in water with ozone in the presence of various activated carbons. Activated carbon-free ozonation or single ozonation leads to a complete degradation of DCF in less than 15 min while in the presence of activated carbons higher degradation rates of TOC and DCF are noticeably achieved. Among the activated carbons used, P110 Hydraffin was found the most suitable for the catalytic ozonation of DCF. The influence of pH was also investigated. In the case of the single ozonation the increasing pH slightly increases the TOC removal rate. This effect, however, was not so clear in the presence of activated carbons where the influence of the adsorption process must be considered. Ecotoxicity experiments were performed, pointing out that single ozonation reduces the toxicity of the contaminated water but catalytic ozonation improved those results. As far as kinetics is concerned, DCF is removed with ozone in a fast kinetic regime and activated carbon merely acts as a simple adsorbent. However, for TOC removal the ozonation kinetic regime becomes slow. In the absence of the adsorbent, the apparent rate constant of the mineralization process was determined at different pH values. On the other hand, determination of the rate constant of the catalytic reaction over the activated carbon was not possible due to the effect of mass transfer resistances that controlled the process rate at the conditions investigated.

Fusion plasma losses due to the charge exchange of injected neutrals

International Nuclear Information System (INIS)

Bender, D.J.; Carlson, G.A.

1975-01-01

The interaction of a neutral beam, consisting of full, half and third energy components, with a mirror plasma is analyzed. The beam-plasma interaction is assumed to occur via ionization and charge exchange collisions. The plasma was approximated as being spherical in shape, having a uniform density, isotropic velocity distribution, and a mirror plasma energy distribution. It was found that to a first approximation, for plasma energies less than 100 keV, the charge exchange power loss (per injected atom) of the half energy component is at least twice that of the full energy component. For the third energy component, the loss is at least three times that of the full energy component. For some plasma conditions, the neutral beam can act as an energy sink for the plasma due to these charge exchange losses. (U.S.)

Tropospheric Ozone Assessment Report: Present-day distribution and trends of tropospheric ozone relevant to climate and global atmospheric chemistry model evaluation

Directory of Open Access Journals (Sweden)

A. Gaudel

2018-05-01

Full Text Available 'The Tropospheric Ozone Assessment Report' (TOAR is an activity of the International Global Atmospheric Chemistry Project. This paper is a component of the report, focusing on the present-day distribution and trends of tropospheric ozone relevant to climate and global atmospheric chemistry model evaluation. Utilizing the TOAR surface ozone database, several figures present the global distribution and trends of daytime average ozone at 2702 non-urban monitoring sites, highlighting the regions and seasons of the world with the greatest ozone levels. Similarly, ozonesonde and commercial aircraft observations reveal ozone’s distribution throughout the depth of the free troposphere. Long-term surface observations are limited in their global spatial coverage, but data from remote locations indicate that ozone in the 21st century is greater than during the 1970s and 1980s. While some remote sites and many sites in the heavily polluted regions of East Asia show ozone increases since 2000, many others show decreases and there is no clear global pattern for surface ozone changes since 2000. Two new satellite products provide detailed views of ozone in the lower troposphere across East Asia and Europe, revealing the full spatial extent of the spring and summer ozone enhancements across eastern China that cannot be assessed from limited surface observations. Sufficient data are now available (ozonesondes, satellite, aircraft across the tropics from South America eastwards to the western Pacific Ocean, to indicate a likely tropospheric column ozone increase since the 1990s. The 2014–2016 mean tropospheric ozone burden (TOB between 60°N–60°S from five satellite products is 300 Tg ± 4%. While this agreement is excellent, the products differ in their quantification of TOB trends and further work is required to reconcile the differences. Satellites can now estimate ozone’s global long-wave radiative effect, but evaluation is difficult due to limited

Epidemiological features and financial loss due to clinically diagnosed Haemorrhagic Septicemia in bovines in Karnataka, India.

Science.gov (United States)

Govindaraj, G; Krishnamoorthy, P; Nethrayini, K R; Shalini, R; Rahman, H

2017-09-01

The epidemiological features and financial losses due to Haemorrhagic Septicemia (HS) in bovines were studied in Karnataka state using the primary data collected from 133 clinically diagnosed HS affected farms. The various losses due to HS and the Benefit- Cost of the vaccination programme in cattle and water buffaloes were studied using mathematical models. The number of HS outbreaks were higher during the year 2002 and peaked during 2005 and thereafter declined due to targeted vaccination against HS. The morbidity and mortality risks were lower in large farms than medium and small farms, and lower in indigenous cattle compared to high yielding crossbred cattle and water buffaloes. The disease occurrence was more in in-milk animals causing serious economic loss to the farmers. Most outbreaks were observed during monsoon season, though the disease was prevalent throughout the year. The mean milk loss per animal was $2, $11 and $50 in indigenous cattle, water buffaloes and crossbred cattle, respectively. In the case of draught animals, the average effective draught power was unavailable for 1.2days/outbreak resulting in a loss of $5 per affected oxen. The treatment and extra labor expenses incurred per animal were $24 and $7, respectively. The average loss per animal due to mortality loss was $275, $284 and $415 in case of indigenous cattle, water buffaloes and crossbred cattle, respectively. The projected loss for the state of Karnataka were $23.89, $17.92 and $11.95 million under high, medium and low HS incidence scenarios, respectively. The Benefit Cost Analysis (BCA) of the vaccination against HS has been estimated at 5.97:1, 4.48:1 and 2.98:1 under high, medium and low incidence scenarios, respectively. The results highlight the important epidemiological features and financial losses to the affected households and the state of Karnataka. Copyright © 2017 Elsevier B.V. All rights reserved.

Ozone impacts of natural gas development in the Haynesville Shale.

Science.gov (United States)

Kemball-Cook, Susan; Bar-Ilan, Amnon; Grant, John; Parker, Lynsey; Jung, Jaegun; Santamaria, Wilson; Mathews, Jim; Yarwood, Greg

2010-12-15

The Haynesville Shale is a subsurface rock formation located beneath the Northeast Texas/Northwest Louisiana border near Shreveport. This formation is estimated to contain very large recoverable reserves of natural gas, and during the two years since the drilling of the first highly productive wells in 2008, has been the focus of intensive leasing and exploration activity. The development of natural gas resources within the Haynesville Shale is likely to be economically important but may also generate significant emissions of ozone precursors. Using well production data from state regulatory agencies and a review of the available literature, projections of future year Haynesville Shale natural gas production were derived for 2009-2020 for three scenarios corresponding to limited, moderate, and aggressive development. These production estimates were then used to develop an emission inventory for each of the three scenarios. Photochemical modeling of the year 2012 showed increases in 2012 8-h ozone design values of up to 5 ppb within Northeast Texas and Northwest Louisiana resulting from development in the Haynesville Shale. Ozone increases due to Haynesville Shale emissions can affect regions outside Northeast Texas and Northwest Louisiana due to ozone transport. This study evaluates only near-term ozone impacts, but the emission inventory projections indicate that Haynesville emissions may be expected to increase through 2020.

The stratospheric ozone and the ozone layer

International Nuclear Information System (INIS)

Zea Mazo, Jorge Anibal; Leon Aristizabal Gloria Esperanza; Eslava Ramirez Jesus Antonio

2000-01-01

An overview is presented of the principal characteristics of the stratospheric ozone in the Earth's atmosphere, with particular emphasis on the tropics and the ozone hole over the poles. Some effects produced in the atmosphere as a consequence of the different human activities will be described, and some data on stratospheric ozone will be shown. We point out the existence of a nucleus of least ozone in the tropics, stretching from South America to central Africa, with annual mean values less than 240 DU, a value lower than in the middle latitudes and close to the mean values at the South Pole. The existence of such a minimum is confirmed by mean values from measurements made on satellites or with earthbound instruments, for different sectors in Colombia, like Medellin, Bogota and Leticia

Evaluation of Loss Due to Storm Surge Disasters in China Based on Econometric Model Groups.

Science.gov (United States)

Jin, Xue; Shi, Xiaoxia; Gao, Jintian; Xu, Tongbin; Yin, Kedong

2018-03-27

Storm surge has become an important factor restricting the economic and social development of China's coastal regions. In order to improve the scientific judgment of future storm surge damage, a method of model groups is proposed to refine the evaluation of the loss due to storm surges. Due to the relative dispersion and poor regularity of the natural property data (login center air pressure, maximum wind speed, maximum storm water, super warning water level, etc.), storm surge disaster is divided based on eight kinds of storm surge disaster grade division methods combined with storm surge water, hypervigilance tide level, and disaster loss. The storm surge disaster loss measurement model groups consist of eight equations, and six major modules are constructed: storm surge disaster in agricultural loss, fishery loss, human resource loss, engineering facility loss, living facility loss, and direct economic loss. Finally, the support vector machine (SVM) model is used to evaluate the loss and the intra-sample prediction. It is indicated that the equations of the model groups can reflect in detail the relationship between the damage of storm surges and other related variables. Based on a comparison of the original value and the predicted value error, the model groups pass the test, providing scientific support and a decision basis for the early layout of disaster prevention and mitigation.

Evaluation of Loss Due to Storm Surge Disasters in China Based on Econometric Model Groups

Science.gov (United States)

Shi, Xiaoxia; Xu, Tongbin; Yin, Kedong

2018-01-01

Storm surge has become an important factor restricting the economic and social development of China’s coastal regions. In order to improve the scientific judgment of future storm surge damage, a method of model groups is proposed to refine the evaluation of the loss due to storm surges. Due to the relative dispersion and poor regularity of the natural property data (login center air pressure, maximum wind speed, maximum storm water, super warning water level, etc.), storm surge disaster is divided based on eight kinds of storm surge disaster grade division methods combined with storm surge water, hypervigilance tide level, and disaster loss. The storm surge disaster loss measurement model groups consist of eight equations, and six major modules are constructed: storm surge disaster in agricultural loss, fishery loss, human resource loss, engineering facility loss, living facility loss, and direct economic loss. Finally, the support vector machine (SVM) model is used to evaluate the loss and the intra-sample prediction. It is indicated that the equations of the model groups can reflect in detail the relationship between the damage of storm surges and other related variables. Based on a comparison of the original value and the predicted value error, the model groups pass the test, providing scientific support and a decision basis for the early layout of disaster prevention and mitigation. PMID:29584628

Evaluation of Loss Due to Storm Surge Disasters in China Based on Econometric Model Groups

Directory of Open Access Journals (Sweden)

Xue Jin

2018-03-01

Full Text Available Storm surge has become an important factor restricting the economic and social development of China’s coastal regions. In order to improve the scientific judgment of future storm surge damage, a method of model groups is proposed to refine the evaluation of the loss due to storm surges. Due to the relative dispersion and poor regularity of the natural property data (login center air pressure, maximum wind speed, maximum storm water, super warning water level, etc., storm surge disaster is divided based on eight kinds of storm surge disaster grade division methods combined with storm surge water, hypervigilance tide level, and disaster loss. The storm surge disaster loss measurement model groups consist of eight equations, and six major modules are constructed: storm surge disaster in agricultural loss, fishery loss, human resource loss, engineering facility loss, living facility loss, and direct economic loss. Finally, the support vector machine (SVM model is used to evaluate the loss and the intra-sample prediction. It is indicated that the equations of the model groups can reflect in detail the relationship between the damage of storm surges and other related variables. Based on a comparison of the original value and the predicted value error, the model groups pass the test, providing scientific support and a decision basis for the early layout of disaster prevention and mitigation.

Valuing productivity loss due to absenteeism: firm-level evidence from a Canadian linked employer-employee survey.

Science.gov (United States)

Zhang, Wei; Sun, Huiying; Woodcock, Simon; Anis, Aslam H

2017-12-01

In health economic evaluation studies, to value productivity loss due to absenteeism, existing methods use wages as a proxy value for marginal productivity. This study is the first to test the equality between wage and marginal productivity losses due to absenteeism separately for team workers and non-team workers. Our estimates are based on linked employer-employee data from Canada. Results indicate that team workers are more productive and earn higher wages than non-team workers. However, the productivity gap between these two groups is considerably larger than the wage gap. In small firms, employee absenteeism results in lower productivity and wages, and the marginal productivity loss due to team worker absenteeism is significantly higher than the wage loss. No similar wage-productivity gap exists for large firms. Our findings suggest that productivity loss or gain is most likely to be underestimated when valued according to wages for team workers. The findings help to value the burden of illness-related absenteeism. This is important for economic evaluations that seek to measure the productivity gain or loss of a health care technology or intervention, which in turn can impact policy makers' funding decisions.

Lower tropospheric ozone over India and its linkage to the South Asian monsoon

Science.gov (United States)

Lu, Xiao; Zhang, Lin; Liu, Xiong; Gao, Meng; Zhao, Yuanhong; Shao, Jingyuan

2018-03-01

Lower tropospheric (surface to 600 hPa) ozone over India poses serious risks to both human health and crops, and potentially affects global ozone distribution through frequent deep convection in tropical regions. Our current understanding of the processes controlling seasonal and long-term variations in lower tropospheric ozone over this region is rather limited due to spatially and temporally sparse observations. Here we present an integrated process analysis of the seasonal cycle, interannual variability, and long-term trends of lower tropospheric ozone over India and its linkage to the South Asian monsoon using the Ozone Monitoring Instrument (OMI) satellite observations for years 2006-2014 interpreted with a global chemical transport model (GEOS-Chem) simulation for 1990-2010. OMI observed lower tropospheric ozone over India averaged for 2006-2010, showing the highest concentrations (54.1 ppbv) in the pre-summer monsoon season (May) and the lowest concentrations (40.5 ppbv) in the summer monsoon season (August). Process analyses in GEOS-Chem show that hot and dry meteorological conditions and active biomass burning together contribute to 5.8 Tg more ozone being produced in the lower troposphere in India in May than January. The onset of the summer monsoon brings ozone-unfavorable meteorological conditions and strong upward transport, which all lead to large decreases in the lower tropospheric ozone burden. Interannually, we find that both OMI and GEOS-Chem indicate strong positive correlations (r = 0.55-0.58) between ozone and surface temperature in pre-summer monsoon seasons, with larger correlations found in high NOx emission regions reflecting NOx-limited production conditions. Summer monsoon seasonal mean ozone levels are strongly controlled by monsoon strengths. Lower ozone concentrations are found in stronger monsoon seasons mainly due to less ozone net chemical production. Furthermore, model simulations over 1990-2010 estimate a mean annual trend of 0

Effects and mechanism on Kapton film under ozone exposure in a ground near space simulator

Science.gov (United States)

Wei, Qiang; Yang, Guimin; Liu, Gang; Jiang, Haifu; Zhang, Tingting

2018-05-01

The effect on aircraft materials in the near space environment is a key part of air-and-space integration research. Ozone and aerodynamic fluids are important organizational factors in the near space environment and both have significant influences on the performance of aircraft materials. In the present paper a simulated ozone environment was used to test polyimide material that was rotated at the approximate velocity of 150-250 m/s to form an aerodynamic fluid field. The goal was to evaluate the performance evolution of materials under a comprehensive environment of ozone molecular corrosion and aerodynamic fluids. The research results show that corrosion and sputtering by ozone molecules results in Kapton films exhibiting a rugged "carpet-like" morphology exhibits an increase in surface roughness. The morphology after ozone exposure led to higher surface roughness and an increase in surface optical diffuse reflection, which is expressed by the lower optical transmittance and the gradual transition from light orange to brown. The mass loss test, XPS, and FTIR analysis show that the molecular chains on the surface of the Kapton film are destroyed resulting in Csbnd C bond breaking to form small volatile molecules such as CO2 or CO, which are responsible for a linear increase in mass loss per unit area. The Csbnd N and Csbnd O structures exhibit weakening tendency under ozone exposure. The present paper explores the evaluation method for Kapton's adaptability under the ozone exposure test in the near space environment, and elucidates the corrosion mechanism and damage mode of the polyimide material under the combined action of ozone corrosion and the aerodynamic fluid. This work provides a methodology for studying materials in the near-space environment.

Crop production and economic loss due to wind erosion in hot arid ecosystem of India

Science.gov (United States)

Santra, Priyabrata; Moharana, P. C.; Kumar, Mahesh; Soni, M. L.; Pandey, C. B.; Chaudhari, S. K.; Sikka, A. K.

2017-10-01

Wind erosion is a severe land degradation process in hot arid western India and affects the agricultural production system. It affects crop yield directly by damaging the crops through abrasion, burial, dust deposition etc. and indirectly by reducing soil fertility. In this study, an attempt was made to quantify the indirect impact of wind erosion process on crop production loss and associated economic loss in hot arid ecosystem of India. It has been observed that soil loss due to wind erosion varies from minimum 1.3 t ha-1 to maximum 83.3 t ha-1 as per the severity. Yield loss due to wind erosion was found maximum for groundnut (Arachis hypogea) (5-331 kg ha-1 yr-1), whereas minimum for moth bean (Vigna aconitifolia) (1-93 kg ha-1 yr-1). For pearl millet (Pennisetum glaucum), which covers a major portion of arable lands in western Rajasthan, the yield loss was found 3-195 kg ha-1 yr-1. Economic loss was found higher for groundnut and clusterbean (Cyamopsis tetragonoloba) than rest crops, which are about

Losses due to weather phenomena in the bituminous concrete construction industry in Wisconsin

Science.gov (United States)

Kuhn, H. A. J.

1973-01-01

The losses (costs) due to weather phenomena as they affect the bituminous concrete industry in Wisconsin were studied. The bituminous concrete industry's response to precipitation, in the form of rain, is identified through the use of a model, albeit crude, which identifies a typical industry decision-response mechanism. Using this mechanism, historical weather data and 1969 construction activity, dollar losses resulting from rain occurrences were developed.

Earth's ozone layer

International Nuclear Information System (INIS)

Lasa, J.

1991-01-01

The paper contain the actual results of investigations of the influence of the human activity on the Earth's ozone layer. History of the ozone measurements and of the changes in its concentrations within the last few years are given. The influence of the trace gases on both local and global ozone concentrations are discussed. The probable changes of the ozone concentrations are presented on the basis of the modelling investigations. The effect of a decrease in global ozone concentration on human health and on biosphere are also presented. (author). 33 refs, 36 figs, 5 tabs

Urban Summertime Ozone of China: Peak Ozone Hour and Nighttime Mixing

Science.gov (United States)

Qu, H.; Wang, Y.; Zhang, R.

2017-12-01

We investigate the observed diurnal cycle of summertime ozone in the cities of China using a regional chemical transport model. The simulated daytime ozone is in general agreement with the observations. Model simulations suggest that the ozone peak time and peak concentration are a function of NOx (NO + NO2) and volatile organic compound (VOC) emissions. The differences between simulated and observed ozone peak time and peak concentration in some regions can be applied to understand biases in the emission inventories. For example, the VOCs emissions are underestimated over the Pearl River Delta (PRD) region, and either NOx emissions are underestimated or VOC emissions are overestimated over the Yangtze River Delta (YRD) regions. In contrast to the general good daytime ozone simulations, the simulated nighttime ozone has a large low bias of up to 40 ppbv. Nighttime ozone in urban areas is sensitive to the nocturnal boundary-layer mixing, and enhanced nighttime mixing (from the surface to 200-500 m) is necessary for the model to reproduce the observed level of ozone.

Comparison of SAGE II ozone measurements and ozone soundings at Uccle (Belgium) during the period February 1985 to January 1986

Science.gov (United States)

De Muer, D.; De Backer, H.; Zawodny, J. M.; Veiga, R. E.

1990-01-01

The ozone profiles obtained from 24 balloon soundings at Uccle (50 deg 48 min N, 4 deg 21 min E) made with electrochemical ozonesondes were used as correlative data for SAGE II ozone profiles retrieved within a distance of at most 600 km from Uccle. The agreement between the two data sets is in general quite good, especially for profiles nearly coincident in time and space, and during periods of little dynamic activity over the area considered. The percent difference between the ozone column density of the mean balloon and SAGE profile is 4.4 percent (-3.3) percent in the altitude region between 10 and 26 km. From a statistical analysis it appears that there is a small but meaningful difference between the mean profiles at the level of the ozone maximum and around the 30-km level. An error analysis of both data sets give similar results, leading to the conclusion that these differences are instrumentally induced. However, differences between the mean profiles in the lower stratosphere are probably real and due to the high ozone variability in time and space in that altitude region.

Total ozone changes in the 1987 Antarctic ozone hole

Science.gov (United States)

Krueger, Arlin J.; Schoeberl, Mark R.; Doiron, Scott D.; Sechrist, Frank; Galimore, Reginald

1988-01-01

The development of the Antarctic ozone minimum was observed in 1987 with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) instrument. In the first half of August the near-polar (60 and 70 deg S) ozone levels were similar to those of recent years. By September, however, the ozone at 70 and 80 deg S was clearly lower than any previous year including 1985, the prior record low year. The levels continued to decrease throughout September until October 5 when a new record low of 109 DU was established at a point near the South Pole. This value is 29 DU less than the lowest observed in 1985 and 48 DU less than the 1986 low. The zonal mean total ozone at 60 deg S remained constant throughout the time of ozone hole formation. The ozone decline was punctuated by local minima formed away from the polar night boundary at about 75 deg S. The first of these, on August 15 to 17, formed just east of the Palmer Peninsula and appears to be a mountain wave. The second major minimum formed on September 5 to 7 again downwind of the Palmer Peninsula. This event was larger in scale than the August minimum and initiated the decline of ozone across the polar region. The 1987 ozone hole was nearly circular and pole centered for its entire life. In previous years the hole was perturbed by intrusions of the circumpolar maximum into the polar regions, thus causing the hole to be elliptical. The 1987 hole also remained in place until the end of November, a few days longer than in 1985, and this persistence resulted in the latest time for recovery to normal values yet observed.

Measuring production loss due to health and work environment problems: construct validity and implications.

Science.gov (United States)

Karlsson, Malin Lohela; Bergström, Gunnar; Björklund, Christina; Hagberg, Jan; Jensen, Irene

2013-12-01

The aim was to validate two measures of production loss, health-related and work environment-related production loss, concerning their associations with health status and work environment factors. Validity was assessed by evaluating the construct validity. Health problems related and work environment-related problems (or factors) were included in separate analyses and evaluated regarding the significant difference in proportion of explained variation (R) of production loss. health problems production loss was not found to fulfill the criteria for convergent validity in this study; however, the measure of work environment-related production loss did fulfill the criteria that were set up. The measure of work environment-related production loss can be used to screen for production loss due to work environment problems as well as an outcome measure when evaluating the effect of organizational interventions.

Ozonation control and effects of ozone on water quality in recirculating aquaculture systems

DEFF Research Database (Denmark)

Spiliotopoulou, Aikaterini; Rojas-Tirado, Paula Andrea; Chetri, Ravi K.

2018-01-01

To address the undesired effect of chemotherapeutants in aquaculture, ozone has been suggested as an alternative to improve water quality. To ensure safe and robust treatment, it is vital to define the ozone demand and ozone kinetics of the specific water matrix to avoid ozone overdose. Different...... ozone dosages were applied to water in freshwater recirculating aquaculture systems (RAS). Experiments were performed to investigate ozone kinetics and demand, and to evaluate the effects on the water quality, particularly in relation to fluorescent organic matter. This study aimed at predicting...... a suitable ozone dosage for water treatment based on daily ozone demand via laboratory studies. These ozone dosages will be eventually applied and maintained at these levels in pilot-scale RAS to verify predictions. Selected water quality parameters were measured, including natural fluorescence and organic...

Update of the Polar SWIFT model for polar stratospheric ozone loss (Polar SWIFT version 2

Directory of Open Access Journals (Sweden)

I. Wohltmann

2017-07-01

Full Text Available The Polar SWIFT model is a fast scheme for calculating the chemistry of stratospheric ozone depletion in polar winter. It is intended for use in global climate models (GCMs and Earth system models (ESMs to enable the simulation of mutual interactions between the ozone layer and climate. To date, climate models often use prescribed ozone fields, since a full stratospheric chemistry scheme is computationally very expensive. Polar SWIFT is based on a set of coupled differential equations, which simulate the polar vortex-averaged mixing ratios of the key species involved in polar ozone depletion on a given vertical level. These species are O3, chemically active chlorine (ClOx, HCl, ClONO2 and HNO3. The only external input parameters that drive the model are the fraction of the polar vortex in sunlight and the fraction of the polar vortex below the temperatures necessary for the formation of polar stratospheric clouds. Here, we present an update of the Polar SWIFT model introducing several improvements over the original model formulation. In particular, the model is now trained on vortex-averaged reaction rates of the ATLAS Chemistry and Transport Model, which enables a detailed look at individual processes and an independent validation of the different parameterizations contained in the differential equations. The training of the original Polar SWIFT model was based on fitting complete model runs to satellite observations and did not allow for this. A revised formulation of the system of differential equations is developed, which closely fits vortex-averaged reaction rates from ATLAS that represent the main chemical processes influencing ozone. In addition, a parameterization for the HNO3 change by denitrification is included. The rates of change of the concentrations of the chemical species of the Polar SWIFT model are purely chemical rates of change in the new version, whereas in the original Polar SWIFT model, they included a transport effect

Ozone modeling

International Nuclear Information System (INIS)

McIllvaine, C.M.

1994-01-01

Exhaust gases from power plants that burn fossil fuels contain concentrations of sulfur dioxide (SO 2 ), nitric oxide (NO), particulate matter, hydrocarbon compounds and trace metals. Estimated emissions from the operation of a hypothetical 500 MW coal-fired power plant are given. Ozone is considered a secondary pollutant, since it is not emitted directly into the atmosphere but is formed from other air pollutants, specifically, nitrogen oxides (NO), and non-methane organic compounds (NMOQ) in the presence of sunlight. (NMOC are sometimes referred to as hydrocarbons, HC, or volatile organic compounds, VOC, and they may or may not include methane). Additionally, ozone formation Alternative is a function of the ratio of NMOC concentrations to NO x concentrations. A typical ozone isopleth is shown, generated with the Empirical Kinetic Modeling Approach (EKMA) option of the Environmental Protection Agency's (EPA) Ozone Isopleth Plotting Mechanism (OZIPM-4) model. Ozone isopleth diagrams, originally generated with smog chamber data, are more commonly generated with photochemical reaction mechanisms and tested against smog chamber data. The shape of the isopleth curves is a function of the region (i.e. background conditions) where ozone concentrations are simulated. The location of an ozone concentration on the isopleth diagram is defined by the ratio of NMOC and NO x coordinates of the point, known as the NMOC/NO x ratio. Results obtained by the described model are presented

Reduction of N-nitrosodimethylamine formation from ranitidine by ozonation preceding chloramination: influencing factors and mechanisms.

Science.gov (United States)

Zou, Rusen; Liao, Xiaobin; Zhao, Lei; Yuan, Baoling

2018-05-01

Formation of toxic N-nitrosodimethylamine (NDMA) by chloramination of ranitidine, a drug to block histamine, was still an ongoing issue and posed a risk to human health. In this study, the effect of ozonation prior to chloramination on NDMA formation and the transformation pathway were determined. Influencing factors, including ozone dosages, pH, hydroxyl radical scavenger, bromide, and NOM, were studied. The results demonstrated that small ozone dosage (0.5 mg/L) could effectively control NDMA formation from subsequent chloramination (from 40 to 0.8%). The NDMA molar conversion was not only influenced by pH but also by ozone dosages at various pre-ozonation pH (reached the highest value of 5% at pH 8 with 0.5 mg/L O 3 but decreased with the increasing pH with 1 mg/L O 3 ). The NDMA molar yield by chloramination of ranitidine without pre-ozonation was reduced by the presence of bromide ion due to the decomposition of disinfectant. However, due to the formation of brominated intermediate substances (i.e., dimethylamine (DMA), dimethyl-aminomethyl furfuryl alcohol (DFUR)) with higher NDMA molar yield than their parent substances, more NDMA was formed than that without bromide ion upon ozonation. Natural organic matter (NOM) and hydroxyl radical scavenger (tert-butyl alcohol, tBA) enhanced NDMA generation because of the competition of ozone and more ranitidine left. The NDMA reduction mechanism by pre-ozonation during chloramination of ranitidine may be due to the production of oxidation products with less NDMA yield (such as DMA) than parent compound. Based on the result of Q-TOF and GC-MS/MS analysis, three possible transformation pathways were proposed. Different influences of oxidation conditions and water quality parameters suggest that strategies to reduce NDMA formation should vary with drinking water sources and choose optimal ozone dosage.

Estimation of loss due to post harvest diseases of potato in markets ...

African Journals Online (AJOL)

Administrator

2011-09-26

Sep 26, 2011 ... percentage loss of potatoes due to important diseases occurring in the ... Survey of diseased potato and Collection of disease sample ... alcohol swab. A piece of ..... temperature of 17 to 25°C over 70% relative humidity and.

Particulate matter air pollution may offset ozone damage to global crop production

Science.gov (United States)

Schiferl, Luke D.; Heald, Colette L.

2018-04-01

Ensuring global food security requires a comprehensive understanding of environmental pressures on food production, including the impacts of air quality. Surface ozone damages plants and decreases crop production; this effect has been extensively studied. In contrast, the presence of particulate matter (PM) in the atmosphere can be beneficial to crops given that enhanced light scattering leads to a more even and efficient distribution of photons which can outweigh total incoming radiation loss. This study quantifies the impacts of ozone and PM on the global production of maize, rice, and wheat in 2010 and 2050. We show that accounting for the growing season of these crops is an important factor in determining their air pollution exposure. We find that the effect of PM can offset much, if not all, of the reduction in yield associated with ozone damage. Assuming maximum sensitivity to PM, the current (2010) global net impact of air quality on crop production varies by crop (+5.6, -3.7, and +4.5 % for maize, wheat, and rice, respectively). Future emissions scenarios indicate that attempts to improve air quality can result in a net negative effect on crop production in areas dominated by the PM effect. However, we caution that the uncertainty in this assessment is large, due to the uncertainty associated with crop response to changes in diffuse radiation; this highlights that a more detailed physiological study of this response for common cultivars is crucial.

Particulate matter air pollution may offset ozone damage to global crop production

Directory of Open Access Journals (Sweden)

L. D. Schiferl

2018-04-01

Full Text Available Ensuring global food security requires a comprehensive understanding of environmental pressures on food production, including the impacts of air quality. Surface ozone damages plants and decreases crop production; this effect has been extensively studied. In contrast, the presence of particulate matter (PM in the atmosphere can be beneficial to crops given that enhanced light scattering leads to a more even and efficient distribution of photons which can outweigh total incoming radiation loss. This study quantifies the impacts of ozone and PM on the global production of maize, rice, and wheat in 2010 and 2050. We show that accounting for the growing season of these crops is an important factor in determining their air pollution exposure. We find that the effect of PM can offset much, if not all, of the reduction in yield associated with ozone damage. Assuming maximum sensitivity to PM, the current (2010 global net impact of air quality on crop production varies by crop (+5.6, −3.7, and +4.5 % for maize, wheat, and rice, respectively. Future emissions scenarios indicate that attempts to improve air quality can result in a net negative effect on crop production in areas dominated by the PM effect. However, we caution that the uncertainty in this assessment is large, due to the uncertainty associated with crop response to changes in diffuse radiation; this highlights that a more detailed physiological study of this response for common cultivars is crucial.

Beginning of the ozone recovery over Europe? − Analysis of the total ozone data from the ground-based observations, 1964−2004

Directory of Open Access Journals (Sweden)

J. W. Krzyścin

2005-07-01

Full Text Available The total ozone variations over Europe (~50° N in the period 1964–2004 are analyzed for detection of signals of ozone recovery. The ozone deviations from the long-term monthly means (1964–1980 for selected European stations, where the ozone observations (by the Dobson spectrophotometers have been carried out continuously for at least 3–4 decades, are averaged and examined by a regression model. A new method is proposed to disclose both the ozone trend variations and date of the trend turnaround. The regression model contains a piecewise linear trend component and the terms describing the ozone response to forcing by "natural" changes in the atmosphere. Standard proxies for the dynamically driven ozone variations are used. The Multivariate Adaptive Regression Splines (MARS methodology and principal component analysis are used to find an optimal set of the explanatory variables and the trend pattern. The turnaround of the ozone trend in 1994 is suggested from the pattern of the piecewise linear trend component. Thus, the changes in the ozone mean level are calculated over the periods 1970–1994 and 1994–2003, for both the original time series and the time series having "natural" variations removed. Statistical significance of the changes are derived by bootstrapping. A first stage of recovery (according to the definition of the International Ozone Commission, i.e. lessening of a negative trend, is found over Europe. It seems possible that the increase in the ozone mean level since 1994 of about 1–2% is due to superposition of the "natural" processes. Comparison of the total ozone ground-based network (the Dobson and Brewer spectrophotometers and the satellite (TOMS, version 8 data over Europe shows the small bias in the mean values for the period 1996–2004, but the differences between the daily ozone values from these instruments are not trendless, and this may hamper an identification of the next stage of the ozone recovery over

Hydrological controls on the tropospheric ozone greenhouse gas effect

Directory of Open Access Journals (Sweden)

Le Kuai

2017-03-01

Full Text Available The influence of the hydrological cycle in the greenhouse gas (GHG effect of tropospheric ozone (O3 is quantified in terms of the O3longwave radiative effect (LWRE, which is defined as the net reduction of top-of-atmosphere flux due to total tropospheric O3absorption. The O3LWRE derived from the infrared spectral measurements by Aura’s Tropospheric Emission Spectrometer (TES show that the spatiotemporal variation of LWRE is relevant to relative humidity, surface temperature, and tropospheric O3column. The zonally averaged subtropical LWRE is ~0.2 W m-2higher than the zonally averaged tropical LWRE, generally due to lower water vapor concentrations and less cloud coverage at the downward branch of the Hadley cell in the subtropics. The largest values of O3LWRE over the Middle East (>1 W/m2 are further due to large thermal contrasts and tropospheric ozone enhancements from atmospheric circulation and pollution. Conversely, the low O3LWRE over the Inter-Tropical Convergence Zone (on average 0.4 W m-2 is due to strong water vapor absorption and cloudiness, both of which reduce the tropospheric O3absorption in the longwave radiation. These results show that changes in the hydrological cycle due to climate change could affect the magnitude and distribution of ozone radiative forcing.

Bromate formation in a hybrid ozonation-ceramic membrane filtration system.

Science.gov (United States)

Moslemi, Mohammadreza; Davies, Simon H; Masten, Susan J

2011-11-01

The effect of pH, ozone mass injection rate, initial bromide concentration, and membrane molecular weight cut off (MWCO) on bromate formation in a hybrid membrane filtration-ozonation reactor was studied. Decreasing the pH, significantly reduced bromate formation. Bromate formation increased with increasing gaseous ozone mass injection rate, due to increase in dissolved ozone concentrations. Greater initial bromide concentrations resulted in higher bromate concentrations. An increase in the bromate concentration was observed by reducing MWCO, which resulted in a concomitant increase in the retention time in the system. A model to estimate the rate of bromate formation was developed. Good correlation between the model simulation and the experimental data was achieved. Copyright © 2011 Elsevier Ltd. All rights reserved.

Achieving accurate simulations of urban impacts on ozone at high resolution

International Nuclear Information System (INIS)

Li, J; Georgescu, M; Mahalov, A; Moustaoui, M; Hyde, P

2014-01-01

The effects of urbanization on ozone levels have been widely investigated over cities primarily located in temperate and/or humid regions. In this study, nested WRF-Chem simulations with a finest grid resolution of 1 km are conducted to investigate ozone concentrations [O 3 ] due to urbanization within cities in arid/semi-arid environments. First, a method based on a shape preserving Monotonic Cubic Interpolation (MCI) is developed and used to downscale anthropogenic emissions from the 4 km resolution 2005 National Emissions Inventory (NEI05) to the finest model resolution of 1 km. Using the rapidly expanding Phoenix metropolitan region as the area of focus, we demonstrate the proposed MCI method achieves ozone simulation results with appreciably improved correspondence to observations relative to the default interpolation method of the WRF-Chem system. Next, two additional sets of experiments are conducted, with the recommended MCI approach, to examine impacts of urbanization on ozone production: (1) the urban land cover is included (i.e., urbanization experiments) and, (2) the urban land cover is replaced with the region’s native shrubland. Impacts due to the presence of the built environment on [O 3 ] are highly heterogeneous across the metropolitan area. Increased near surface [O 3 ] due to urbanization of 10–20 ppb is predominantly a nighttime phenomenon while simulated impacts during daytime are negligible. Urbanization narrows the daily [O 3 ] range (by virtue of increasing nighttime minima), an impact largely due to the region’s urban heat island. Our results demonstrate the importance of the MCI method for accurate representation of the diurnal profile of ozone, and highlight its utility for high-resolution air quality simulations for urban areas. (letter)

Modelling and analysis of ozone concentration by artificial intelligent techniques for estimating air quality

Science.gov (United States)

Taylan, Osman

2017-02-01

High ozone concentration is an important cause of air pollution mainly due to its role in the greenhouse gas emission. Ozone is produced by photochemical processes which contain nitrogen oxides and volatile organic compounds in the lower atmospheric level. Therefore, monitoring and controlling the quality of air in the urban environment is very important due to the public health care. However, air quality prediction is a highly complex and non-linear process; usually several attributes have to be considered. Artificial intelligent (AI) techniques can be employed to monitor and evaluate the ozone concentration level. The aim of this study is to develop an Adaptive Neuro-Fuzzy inference approach (ANFIS) to determine the influence of peripheral factors on air quality and pollution which is an arising problem due to ozone level in Jeddah city. The concentration of ozone level was considered as a factor to predict the Air Quality (AQ) under the atmospheric conditions. Using Air Quality Standards of Saudi Arabia, ozone concentration level was modelled by employing certain factors such as; nitrogen oxide (NOx), atmospheric pressure, temperature, and relative humidity. Hence, an ANFIS model was developed to observe the ozone concentration level and the model performance was assessed by testing data obtained from the monitoring stations established by the General Authority of Meteorology and Environment Protection of Kingdom of Saudi Arabia. The outcomes of ANFIS model were re-assessed by fuzzy quality charts using quality specification and control limits based on US-EPA air quality standards. The results of present study show that the ANFIS model is a comprehensive approach for the estimation and assessment of ozone level and is a reliable approach to produce more genuine outcomes.

Lusaka, Zambia during SAFARI-2000: A Collection Point for Ozone Pollution

Science.gov (United States)

Thompson, Anne M.; Witte, Jacquelyn C.; Freiman, M. Tal; Phahlane, N. Agnes; Coetzee, G. J. R.; Bhartia, P. K. (Technical Monitor)

2002-01-01

In August and September, throughout south central Africa, seasonal clearing of dry vegetation and other fire-related activities lead to intense smoke haze and ozone formation. The first ozone soundings in the heart of the southern African burning region were taken at Lusaka, Zambia (155 deg S, 28 deg E) in early September 2000. Over 90 ppbv ozone was recorded at the surface (1.3 km elevation) and column tropospheric ozone was greater than 50 DU during a stagnant period. These values are much higher than concurrent measurements over Nairobi (1 deg S, 38 deg E) and Irene (25 deg S, 28 deg E, near Pretoria). The heaviest ozone pollution layer (800-500 hPa) over Lusaka is due to recirculated trans-boundary ozone. Starting out over Zambia, Angola, and Namibia, ozone heads east to the Indian Ocean, before turning back over Mozambique and Zimbabwe, heading toward Lusaka. Thus, Lusaka is a collection point for pollution, consistent with a picture of absolutely stable layers recirculating in a gyre over southern Africa.

Southern Hemisphere Additional Ozonesondes (SHADOZ) Ozone Climatology (2005-2009): Tropospheric and Tropical Tropopause Layer (TTL) Profiles with Comparisons to Omi-based Ozone Products

Science.gov (United States)

Thompson, Anne M.; Miller, Sonya K.; Tilmes, Simone; Kollonige, Debra W.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Johnson, Brian J.; Fujiwara, Masatomo; Schmidlin, F. J.; Coetzee, G. J. R.;

The chemical and biological characteristics of coke-oven wastewater by ozonation

International Nuclear Information System (INIS)

Chang, E.-E.; Hsing, H.-J.; Chiang, P.-C.; Chen, M.-Y.; Shyng, J.-Y.

2008-01-01

A bench-scale bubble column reactor was used to investigate the biological and chemical characteristics of coke-oven wastewater after ozonation treatment through the examination of selected parameters. Color and thiocyanate could be removed almost entirely; however, organic matter and cyanide could not, due to the inadequate oxidation ability of ozone to remove ozonated byproducts under given experimental conditions. The removal of cyanide and total organic carbon were pH-dependent and were found to be efficient under neutral to alkaline conditions. The removal rate for thiocyanate was about five times that of cyanide. The ozone consumption ratio approached to about 1 at the early stage of ozonation (time TOC ) increased to 30%, indicating that easily degraded pollutants were degraded almost entirely. The effect of ozonation on the subsequent biological treatment unit (i.e., activated sludge process) was determined by observing the ratio of 5-day biological oxygen demand to chemical oxygen demand (BOD 5 /COD) and the specific oxygen utilization rate (SOUR). The results indicated that the contribution of ozonation to inhibition reduction was very significant but limited to the enhancement of biodegradation. The operation for ozonation of coke-oven wastewater was feasible under neutral condition and short ozone contact time in order to achieve better performance and cost savings

Electrical discharges of plasma ozonizer and its application

Directory of Open Access Journals (Sweden)

Tirawanichakul, S.

2007-05-01

most effective method for dye wastewater treatment was the combination of ozonation and adsorption by activated carbon.For chemical compound analysis, the Fourier Transform Infrared (FTIR spectrograph illustrated that the treated dye solutions using ozonization were slightly different compared to the reference sample.This is due to some complicated functional groups (methylene, carboxylate etc. being broken down during ozonation.

Hearing Loss due to Carbon Monoxide Poisoning

DEFF Research Database (Denmark)

Mehrparvar, Amir Houshang; Davari, Mohammad Hossein; Mollasadeghi, Abolfazl

2013-01-01

Carbon monoxide poisoning is one of the rare causes of hearing loss which may cause reversible or irreversible, unilateral or bilateral hearing loss after acute or chronic exposure. In this report, we present a case of bilateral sensorineural hearing loss in a secondary smelting workshop worker...... after an acute exposure to carbon monoxide. This complication was diagnosed by pure-tone audiometry and confirmed by transient evoked otoacoustic emissions. Hearing loss has not improved after 3 months of followup....

Stratospheric ozone measurements at Arosa (Switzerland): history and scientific relevance

Science.gov (United States)

Staehelin, Johannes; Viatte, Pierre; Stübi, Rene; Tummon, Fiona; Peter, Thomas

2018-05-01

Climatic Observatory (LKO) in Arosa (Switzerland), marking the beginning of the world's longest series of total (or column) ozone measurements. They were driven by the recognition that atmospheric ozone is important for human health, as well as by scientific curiosity about what was, at the time, an ill characterised atmospheric trace gas. From around the mid-1950s to the beginning of the 1970s studies of high atmosphere circulation patterns that could improve weather forecasting was justification for studying stratospheric ozone. In the mid-1970s, a paradigm shift occurred when it became clear that the damaging effects of anthropogenic ozone-depleting substances (ODSs), such as long-lived chlorofluorocarbons, needed to be documented. This justified continuing the ground-based measurements of stratospheric ozone. Levels of ODSs peaked around the mid-1990s as a result of a global environmental policy to protect the ozone layer, implemented through the 1987 Montreal Protocol and its subsequent amendments and adjustments. Consequently, chemical destruction of stratospheric ozone started to slow around the mid-1990s. To some extent, this raises the question as to whether continued ozone observation is indeed necessary. In the last decade there has been a tendency to reduce the costs associated with making ozone measurements globally including at Arosa. However, the large natural variability in ozone on diurnal, seasonal, and interannual scales complicates the capacity for demonstrating the success of the Montreal Protocol. Chemistry-climate models also predict a super-recovery of the ozone layer at mid-latitudes in the second half of this century, i.e. an increase of ozone concentrations beyond pre-1970 levels, as a consequence of ongoing climate change. These factors, and identifying potentially unexpected stratospheric responses to climate change, support the continued need to document stratospheric ozone changes. This is particularly valuable at the Arosa site, due

Impact of climate change on ozone-related mortality and morbidity in Europe.

Science.gov (United States)

Orru, Hans; Andersson, Camilla; Ebi, Kristie L; Langner, Joakim; Aström, Christofer; Forsberg, Bertil

2013-02-01

Ozone is a highly oxidative pollutant formed from precursors in the presence of sunlight, associated with respiratory morbidity and mortality. All else being equal, concentrations of ground-level ozone are expected to increase due to climate change. Ozone-related health impacts under a changing climate are projected using emission scenarios, models and epidemiological data. European ozone concentrations are modelled with the model of atmospheric transport and chemistry (MATCH)-RCA3 (50×50 km). Projections from two climate models, ECHAM4 and HadCM3, are applied under greenhouse gas emission scenarios A2 and A1B, respectively. We applied a European-wide exposure-response function to gridded population data and country-specific baseline mortality and morbidity. Comparing the current situation (1990-2009) with the baseline period (1961-1990), the largest increase in ozone-associated mortality and morbidity due to climate change (4-5%) have occurred in Belgium, Ireland, the Netherlands and the UK. Comparing the baseline period and the future periods (2021-2050 and 2041-2060), much larger increases in ozone-related mortality and morbidity are projected for Belgium, France, Spain and Portugal, with the impact being stronger using the climate projection from ECHAM4 (A2). However, in Nordic and Baltic countries the same magnitude of decrease is projected. The current study suggests that projected effects of climate change on ozone concentrations could differentially influence mortality and morbidity across Europe.

Monitoring of the ozone layer. Annual report 1997

International Nuclear Information System (INIS)

Braathen, Geir O.; Svenoee, Trond; Hansen, Georg H.; Dahlback, Arne

1998-10-01

The three stations in Oslo, Tromsoe and at Ny-Aalesund at Svalbard measure the total ozone levels and these show low monthly averages in 1997 compared to the long-term monthly averages. In Oslo the averages for January to April were 3-13 % below those from 1979 to 1989. Detailed measurements are presented. Analyses based on model calculations and measurements both in Norway and at other places are presented and show the low spring ozone values largely to be a result of chemical oxone decomposition. Particularly in 1997 the polar whirl lasted longer than usual. This lead to reduced ozone transport from the equator to the poles which normally is strongest in spring. At the same time the ozone was decomposed through natural processes where NO x is involved. The report concludes that the extremely low values registered are caused by a combination of chemical decomposition due to chlorofluorocarbons and halon and the particularly dynamic meteorological situation. A trend analysis for the period of 1979 to 1997 was carried out. The trend has been declining unevenly. In Oslo, Tromsoe and Ny-Aalesund the UV radiation from the sun is continually measured using GUV instrumentation. The measurements confirm that the main factors influencing the UV level are the height of the sun, the amount of clouds, the thickness of the ozone layer and the reflection properties at the earth surface. Monthly radiation doses are presented as well. Both at the Oslo and Tromsoe universities two ozone layer measuring instruments of the Dobson and Brewer types, are used. Instrumental comparisons are made. From the Bjoernoeya and the Gardermoen there are regularly lifted balloons which may reach a 35 km altitude carrying ozone probes. The ozone altitude distribution is registered. Similar measurements in the Antarctic show that the yearly ozone decomposition from September to November occurs at the heights of 14 to 24 km. Studies show there is extensive ozone decomposition in the Arctic as well

The exhibition to ozone diminishes the adherence and increases the membrane permeability of macrophages alveolar of rate

International Nuclear Information System (INIS)

Garcia, J.

2000-01-01

Ozone gas is generated photochemically in areas with high levels of automotive or industrial emissions, and causes irritation and inflammation of the airways if inhaled. Rat alveolar macrophages were obtained by lung lavage from male Sprague Dawley rats and used as a model to assess ozone induced cell damage (0,594 ppm for up to 60 minutes). Ozone exposure caused loss of cell adherence to a polystyrene substrate and increased membrane permeability, as noted by increases in specific 51 Cr release and citoplasmic calcium levels. The results indicate that the cell membrane is a target for ozone damage. Elevations of cytoplasmic calcium could mediate other macrophage responses to ozone , including eicosanoid and nitric oxide production, with concomitant decreases in phagocytic ability and superoxide production. (Author) [es

Ozone modeling

Energy Technology Data Exchange (ETDEWEB)

McIllvaine, C M

1994-07-01

Exhaust gases from power plants that burn fossil fuels contain concentrations of sulfur dioxide (SO{sub 2}), nitric oxide (NO), particulate matter, hydrocarbon compounds and trace metals. Estimated emissions from the operation of a hypothetical 500 MW coal-fired power plant are given. Ozone is considered a secondary pollutant, since it is not emitted directly into the atmosphere but is formed from other air pollutants, specifically, nitrogen oxides (NO), and non-methane organic compounds (NMOQ) in the presence of sunlight. (NMOC are sometimes referred to as hydrocarbons, HC, or volatile organic compounds, VOC, and they may or may not include methane). Additionally, ozone formation Alternative is a function of the ratio of NMOC concentrations to NO{sub x} concentrations. A typical ozone isopleth is shown, generated with the Empirical Kinetic Modeling Approach (EKMA) option of the Environmental Protection Agency's (EPA) Ozone Isopleth Plotting Mechanism (OZIPM-4) model. Ozone isopleth diagrams, originally generated with smog chamber data, are more commonly generated with photochemical reaction mechanisms and tested against smog chamber data. The shape of the isopleth curves is a function of the region (i.e. background conditions) where ozone concentrations are simulated. The location of an ozone concentration on the isopleth diagram is defined by the ratio of NMOC and NO{sub x} coordinates of the point, known as the NMOC/NO{sub x} ratio. Results obtained by the described model are presented.

Direct observation of ozone formation on SiO2 surfaces in O2 discharges

Science.gov (United States)

Marinov, D.; Guaitella, O.; Booth, J. P.; Rousseau, A.

2013-01-01

Ozone production is studied in a pulsed O2 discharge at pressures in the range 1.3-6.7 mbar. Time-resolved absolute concentrations of O3 and O are measured in the post-discharge using UV absorption spectroscopy and two-photon absorption laser-induced fluorescence. In a bare silica discharge tube ozone is formed mainly by three-body gas-phase recombination. When the tube surface is covered by a high specific surface silica catalyst heterogeneous formation becomes the main source of ozone. The efficiency of this surface process increases with O2 pressure and is favoured by the presence of OH groups and adsorbed H2O on the surface. At p = 6.7 mbar ozone production accounts for up to 25% of the atomic oxygen losses on the surface.

Direct observation of ozone formation on SiO2 surfaces in O2 discharges

International Nuclear Information System (INIS)

Marinov, D; Guaitella, O; Booth, J P; Rousseau, A

2013-01-01

Ozone production is studied in a pulsed O 2 discharge at pressures in the range 1.3-6.7 mbar. Time-resolved absolute concentrations of O 3 and O are measured in the post-discharge using UV absorption spectroscopy and two-photon absorption laser-induced fluorescence. In a bare silica discharge tube ozone is formed mainly by three-body gas-phase recombination. When the tube surface is covered by a high specific surface silica catalyst heterogeneous formation becomes the main source of ozone. The efficiency of this surface process increases with O 2 pressure and is favoured by the presence of OH groups and adsorbed H 2 O on the surface. At p = 6.7 mbar ozone production accounts for up to 25% of the atomic oxygen losses on the surface.

Hearing Loss due to Carbon Monoxide Poisoning

DEFF Research Database (Denmark)

Mehrparvar, Amir Houshang; Davari, Mohammad Hossein; Mollasadeghi, Abolfazl

2013-01-01

Carbon monoxide poisoning is one of the rare causes of hearing loss which may cause reversible or irreversible, unilateral or bilateral hearing loss after acute or chronic exposure. In this report, we present a case of bilateral sensorineural hearing loss in a secondary smelting workshop worker a...

The Antarctic ozone hole

International Nuclear Information System (INIS)

Jones, Anna E

2008-01-01

Since the mid 1970s, the ozone layer over Antarctica has experienced massive destruction during every spring. In this article, we will consider the atmosphere, and what ozone and the ozone layer actually are. We explore the chemistry responsible for the ozone destruction, and learn about why conditions favour ozone destruction over Antarctica. For the historical perspective, the events leading up to the discovery of the 'hole' are presented, as well as the response from the international community and the measures taken to protect the ozone layer now and into the future

Buoyancy driven flow in a hot water tank due to standby heat loss

DEFF Research Database (Denmark)

Fan, Jianhua; Furbo, Simon

2012-01-01

Results of experimental and numerical investigations of thermal behavior in a vertical cylindrical hot water tank due to standby heat loss of the tank are presented. The effect of standby heat loss on temperature distribution in the tank is investigated experimentally on a slim 150l tank...... show that the CFD model predicts satisfactorily water temperatures at different levels of the tank during cooling by standby heat loss. It is elucidated how the downward buoyancy driven flow along the tank wall is established by the heat loss from the tank sides and how the natural convection flow...... with a height to diameter ratio of 5. A tank with uniform temperatures and with thermal stratification is studied. A detailed computational fluid dynamics (CFD) model of the tank is developed to calculate the natural convection flow in the tank. The distribution of the heat loss coefficient for the different...

Ozonated Olive Oils and Troubles

Directory of Open Access Journals (Sweden)

Bulent Uysal

2014-04-01

Full Text Available One of the commonly used methods for ozone therapy is ozonated oils. Most prominent type of used oils is extra virgin olive oil. But still, each type of unsaturated oils may be used for ozonation. There are a lot of wrong knowledge on the internet about ozonated oils and its use as well. Just like other ozone therapy studies, also the studies about ozone oils are inadequate to avoid incorrect knowledge. Current data about ozone oil and its benefits are produced by supplier who oversees financial interests and make misinformation. Despite the rapidly increasing ozone oil sales through the internet, its quality and efficacy is still controversial. Dozens of companies and web sites may be easily found to buy ozonated oil. But, very few of these products are reliable, and contain sufficiently ozonated oil. This article aimed to introduce the troubles about ozonated oils and so to inform ozonated oil users. [J Intercult Ethnopharmacol 2014; 3(2.000: 49-50

Effect of ozonation on minocycline degradation and N-Nitrosodimethylamine formation.

Science.gov (United States)

Lv, Juan; Li, Yong M

2018-06-07

The objective of this study was to assess reactivity of Minocycline (MNC) towards ozone and determine the effects of ozone dose, pH value, and water matrix on MNC degradation as well as to characterize N-Nitrosodimethylamine (NDMA) formation from MNC ozonation. The MNC initial concentration of the solution was set in the range of 2-20 mg/L to investigate NDMA formation during MNC ozonation. Four ozone doses (22.5, 37.2, 58.0, and 74.4 mg/min) were tested to study the effect of ozone dose. For the evaluation of effects of pH value, pH was adjusted from 5 to 9 in the presence of phosphate buffer. MNC ozonation experiments were also conducted in natural water to assess the influence of water matirx. The influence of the typical component of natural water was also investigated with the addition of HA and NaHCO 3 solution. Results indicated that ozone was effective in MNC removal. Consequently, NDMA and dimethylamine (DMA) were generated from MNC oxidation. Increasing pH value enhanced MNC removal but led to greater NDMA generation. Water matrices, such as HCO 3 - and humic acid, affected MNC degradation. Conversely, more NDMA accumulated due to the inhibition of NDMA oxidation by oxidant consumption. Though ⋅OH can enhance MNC degradation, ozone molecules were heavily involved in NDMA production. Seven transformation products were identified. However, only DMA and the unidentified tertiary amine containing DMA group contributed to NDMA formation.

Ozone depletion, related UVB changes and increased skin cancer incidence

Science.gov (United States)

Kane, R. P.

1998-03-01

Stratospheric ozone at middle latitudes shows a seasonal variation of about +/-20%, a quasi-biennial oscillation of 1-10% range and a long-term variation in which the level was almost steady up to about 1979 and declined thereafter to the present day by about 10%. These variations are expected to be reflected in solar UVB observed at the ground, but in an opposite direction. Thus UVB should have had a long-term increase of about 10-20%, which should cause an increase in skin cancer incidence of about 20-40%. Skin cancer incidence has increased all over the world, e.g. about 90% in USA during 1974-1990. It is popularly believed that this increase in skin cancer incidence is related to the recent ozone depletion. This seems to be incorrect, for two reasons. Firstly, the observed skin cancer increase is too large (90%) compared with the expected value (40%) from ozone depletion. Secondly, cancer does not develop immediately after exposure to solar UVB. The sunburns may occur within hours; but cancer development and detection may take years, even decades. Hence the observed skin cancer increase since 1974 (no data available for earlier periods) must have occurred due to exposure to solar UVB in the 1950s and 1960s, when there was no ozone depletion. Thus, the skin cancer increase must be attributed to harmful solar UVB levels existing even in the 1960s, accentuated later not by ozone depletion (which started only much later, by 1979) but by other causes, such as a longer human life span, better screening, increasing tendencies of sunbathing at beaches, etc., in affluent societies. On the other hand, the recent ozone depletion and the associated UVB increases will certainly take their toll; only that the effects will not be noticed now but years or decades from now. The concern for the future expressed in the Montreal Protocol for reducing ozone depletion by controlling CFC production is certainly justified, especially because increased UVB is harmful to animal and

The prevalence of vision loss due to ocular trauma in the Australian National Eye Health Survey.

Science.gov (United States)

Keel, Stuart; Xie, Jing; Foreman, Joshua; Taylor, Hugh R; Dirani, Mohamed

2017-11-01

To determine the prevalence of vision loss due to ocular trauma in Australia. The National Eye Health Survey (NEHS) is a population-based cross-sectional study that examined 3098 non-Indigenous Australians (aged 50-98 years) and 1738 Indigenous Australians (aged 40-92 years) living in 30 randomly selected sites, stratified by remoteness. An eye was considered to have vision loss due to trauma if the best-corrected visual acuity was worse than 6/12 and the main cause was attributed to ocular trauma. This determination was made by two independent ophthalmologists and any disagreements were adjudicated by a third senior ophthalmologist. The sampling weight adjusted prevalence of vision loss due to ocular trauma in non-Indigenous Australians aged 50 years and older and Indigenous Australians aged 40 years and over was 0.24% (95%CI: 0.10, 0.52) and 0.79% (95%CI: 0.56, 1.13), respectively. Trauma was attributed as an underlying cause of bilateral vision loss in one Indigenous participant, with all other cases being monocular. Males displayed a higher prevalence of vision loss from ocular trauma than females in both the non-Indigenous (0.47% vs. 1.25%, p=0.03) and Indigenous populations (0.12% vs. 0.38%, p=0.02). After multivariate adjustments, residing in Very Remote geographical areas was associated with higher odds of vision loss from ocular trauma. We estimate that 2.4 per 1000 non-Indigenous and 7.9 per 1000 Indigenous Australian adults have monocular vision loss due to a previous severe ocular trauma. Our findings indicate that males, Indigenous Australians and those residing in Very Remote communities may benefit from targeted health promotion to improve awareness of trauma prevention strategies. Copyright © 2017 Elsevier Ltd. All rights reserved.

Neutrino energy loss rates due to key iron isotopes for core-collapse physics

International Nuclear Information System (INIS)

Nabi, J.-U.

2008-07-01

Accurate estimates of neutrino energy loss rates are needed for the study of the late stages of the stellar evolution, in particular for the cooling of neutron stars and white dwarfs. The energy spectra of neutrinos and antineutrinos arriving at the Earth can also provide useful information on the primary neutrino fluxes as well as neutrino mixing scenario. Proton-neutron quasi-particle random phase approximation (pn-QRPA) theory has recently being used for a microscopic calculation of stellar weak interaction rates of fp-shell nuclide, particularly iron isotopes, with success. Here I present the calculation of neutrino and antineutrino energy loss rates due to key iron isotopes in stellar matter using the pn-QRPA theory. The rates are calculated on a fine grid of temperature-density scale suitable for core-collapse simulators. The calculated rates are compared against earlier calculations. The neutrino cooling rates due to even-even isotopes of iron, 54,56 Fe, are in good agreement with the rates calculated using the large-scale shell model. The pn-QRPA calculated neutrino energy loss rates due to 55 Fe are enhanced roughly around an order of magnitude compared to the large-scale shell model calculation during the oxygen and silicon shell burning stages of massive stars and favor a lower entropy for the cores of massive stars. (author)

A global analysis of the ozone deficit in the upper stratosphere and lower mesosphere

Science.gov (United States)

Eluszkiewicz, Janusz; Allen, Mark

1993-01-01

The global measurements of temperature, ozone, water vapor, and nitrogen dioxide acquired by the Limb Infrared Monitor of the Stratosphere (LIMS), supplemented by a precomputed distribution of chlorine monoxide, are used to test the balance between odd oxygen production and loss in the upper stratosphere and lower mesosphere. An efficient photochemical equilibrium model, whose validity is ascertained by comparison with the results from a fully time-dependent one-dimensional model at selected latitudes, is used in the calculations. The computed ozone abundances are systematically lower than observations for May 1-7, 1979, which suggests, contrary to the conclusions of other recent studies, a real problem in model simulations of stratospheric ozone.

What would have happened to the ozone layer if chlorofluorocarbons (CFCs had not been regulated?

Directory of Open Access Journals (Sweden)

P. A. Newman

2009-03-01

Full Text Available Ozone depletion by chlorofluorocarbons (CFCs was first proposed by Molina and Rowland in their 1974 Nature paper. Since that time, the scientific connection between ozone losses and CFCs and other ozone depleting substances (ODSs has been firmly established with laboratory measurements, atmospheric observations, and modeling studies. This science research led to the implementation of international agreements that largely stopped the production of ODSs. In this study we use a fully-coupled radiation-chemical-dynamical model to simulate a future world where ODSs were never regulated and ODS production grew at an annual rate of 3%. In this "world avoided" simulation, 17% of the globally-averaged column ozone is destroyed by 2020, and 67% is destroyed by 2065 in comparison to 1980. Large ozone depletions in the polar region become year-round rather than just seasonal as is currently observed in the Antarctic ozone hole. Very large temperature decreases are observed in response to circulation changes and decreased shortwave radiation absorption by ozone. Ozone levels in the tropical lower stratosphere remain constant until about 2053 and then collapse to near zero by 2058 as a result of heterogeneous chemical processes (as currently observed in the Antarctic ozone hole. The tropical cooling that triggers the ozone collapse is caused by an increase of the tropical upwelling. In response to ozone changes, ultraviolet radiation increases, more than doubling the erythemal radiation in the northern summer midlatitudes by 2060.

Ozone formation in pulsed SDBD in a wide pressure range

Science.gov (United States)

Starikovskiy, Andrey; Nudnova, Maryia; mipt Team

2011-10-01

Ozone concentration in surface anode-directed DBD for wide pressure range (150 - 1300 torr) was experimentally measured. Voltage and pressure effect were investigated. Reduced electric field was measured for anode-directed and cathode-directed SDBD. E/n values in cathode-directed SDBD is higher than in cathode-directed on 50 percent at atmospheric pressure. E/n value increase leads to decrease the rate of oxygen dissociation and Ozone formation at lower pressures. Radiating region thickness of sliding discharge was measured. Typical thickness of radiating zone is 0.4-1.0 mm within pressure range 220-740 torr. It was shown that high-voltage pulsed nanosecond discharge due to high E/n value produces less Ozone with compare to other discharges. Kinetic model was proposed to describe Ozone formation in the pulsed nanosecond SDBD.

Morphological and Metabolic Parameters of Red Blood Cells after Their Treatment with Ozone

Directory of Open Access Journals (Sweden)

Anna V. Deryugina

2018-01-01

Full Text Available The purpose of the study was to assess the morphology of red blood cells (RBC and the association of morphological parameters with lipid peroxidation processes and the content of organic phosphates in RBC when treating packed red blood cells with the ozonized saline solution (with an ozone concentration of 2 mg/l after different storage periods.Materials and methods. The morphology of human RBC, the concentration of malonic dialdehyde (MDA in RBC, the catalase activity, the concentration of ATP and 2,3-diphosphoglycerate (2,3-DPG were studied before and after treatment of RBC with the ozonized saline (with the ozone concentration of 2 mg/l after 7, 14, 21 and 30 days of storage.Results. The effect of ozone (2 ng/l in vitro on the packed red blood cells after 7–21 days of storage contributed to the recovery of RBC shape, increased the concentration of ATP and 2,3-DPG, and optimized the lipid peroxidation. Ozone did not demonstrate a pronounced positive effect on these parameters when the packed RBCs were stored for 30 days.Conclusion. The treatment of the packed RBCs with the ozonized saline solution (with the ozone concentration of 2 mg/l contributed to the recovery of the discocyte count due to optimization of lipid peroxidation processes in cell membranes and enhanced the synthesis of organic phosphates in cells due to the activation of glycolysis and the pentose phosphate pathway. This can be used to improve the morphological and metabolic status of the packed RBCs before their transfusion. 

Effects on stratospheric moistening by rates of change of aerosol optical depth and ozone due to solar activity in extra-tropics

Science.gov (United States)

Saha, U.; Maitra, A.

2014-11-01

The solar-induced changes in ozone and aerosol optical depth have relative effects on stratospheric moistening at upper troposphere/lower stratosphere region. Wavelet-based multi-scale principal component analysis technique has been applied to de-noise component of quasi-biennial oscillation and El Niño-Southern Oscillation from ozone and aerosol optical depth variations. Rate of change of aerosol optical depth sharply increases indicating a positive gradient whereas rate of change of ozone sharply decreases indicating a negative gradient with solar activity during the years 2004-2010. It is also observed that with increase of rate of change of aerosol optical depth, there is a sharp increase of stratospheric moistening caused by enhanced deep convection. On the contrary, with the increase of stratospheric moistening, there is a sharp decrease of rate of change of ozone resulting in a cross-over between the two parameters. An increase in aerosol optical depth may cause a significant increase in the gradient of vertical temperature profile, as well as formation of cloud condensation nuclei, clouds and hence rainfall. This may lead to formation of strong convective system in the atmosphere that is essential for vertical transfer of water vapour in the tropics percolating tropical tropopause layer and depleting stratospheric ozone in the extra-tropics.

Ozone Antimicrobial Efficacy

Science.gov (United States)

Ozone is a potent germicide that has been used extensively for water purification. In Europe, 90 percent of the municipal water systems are treated with ozone, and in France, ozone has been used to treat drinking water since 1903. However, there is limited information on the bioc...

Power fluctuation and power loss of wind turbines due to wind shear and tower shadow

Institute of Scientific and Technical Information of China (English)

Binrong WEN; Sha WEI; Kexiang WEI; Wenxian YANG; Zhike PENG; Fulei CHU

2017-01-01

The magnitude and stability of power output are two key indices of wind turbines.This study investigates the effects of wind shear and tower shadow on power output in terms of power fluctuation and power loss to estimate the capacity and quality of the power generated by a wind turbine.First,wind speed models,particularly the wind shear model and the tower shadow model,are described in detail.The widely accepted tower shadow model is modified in view of the cone-shaped towers of modem large-scale wind turbines.Power fluctuation and power loss due to wind shear and tower shadow are analyzed by performing theoretical calculations and case analysis within the framework of a modified version of blade element momentum theory.Results indicate that power fluctuation is mainly caused by tower shadow,whereas power loss is primarily induced by wind shear.Under steady wind conditions,power loss can be divided into wind farm loss and rotor loss.Wind farm loss is constant at 3α(3α-1)R2/(8H2).By contrast,rotor loss is strongly influenced by the wind turbine control strategies and wind speed.That is,when the wind speed is measured in a region where a variable-speed controller works,the rotor loss stabilizes around zero,but when the wind speed is measured in a region where the blade pitch controller works,the rotor loss increases as the wind speed intensifies.The results of this study can serve as a reference for accurate power estimation and strategy development to mitigate the fluctuations in aerodynamic loads and power output due to wind shear and tower shadow.

Strategic Ozone Sounding Networks: Review of Design and Accomplishments

Science.gov (United States)

Thompson, Anne M.; Oltmans, Samuel J.; Tarasick, David W.; von der Gathen, Peter; Smit, Herman G. J.; Witte, Jacquelyn C.

2011-01-01

Ozone soundings are used to integrate models, satellite, aircraft and ground-based measurements for better interpretation of ozone variability, including atmospheric losses (predominantly in the stratosphere) and pollution (troposphere). A well-designed network of ozonesonde stations gives information with high vertical and horizontal resolution on a number of dynamical and chemical processes, allowing us to answer questions not possible with aircraft campaigns or current satellite technology. Strategic ozonesonde networks are discussed for high, mid- and low latitude studies. The Match sounding network was designed specifically to follow ozone depletion within the polar vortex; the standard sites are at middle to high northern hemisphere latitudes and typically operate from December through mid-March. Three mid-latitude strategic networks (the IONS series) operated over North America in July-August 2004, March-May and August 2006, and April and June-July-2008. These were designed to address questions about tropospheric ozone budgets and sources, including stratosphere-troposphere transport, and to validate satellite instruments and models. A global network focusing on processes in the equatorial zone, SHADOZ (Southern Hemisphere Additional Ozonesondes), has operated since 1998 in partnership with NOAA, NASA and the Meteorological Services of host countries. Examples of important findings from these networks are described,

Ozone effects on radish (Raphanus sativus L. cv. Cherry Belle): gradient of ultrastructural changes

Energy Technology Data Exchange (ETDEWEB)

Athanassious, R.

1980-01-01

Ultrastructural changes produced by low ( less than or equal to 0.5 ppm) levels of ozone may be attributed to water deficit resulting from injury to the sensitive paravenial cells. The drastic alterations, resulting from high ( greater than or equal to 0.5 ppm) ozone concentrations, were apparently due to more direct effects. Although differential fixation images of membranes in control and ozone treated leaves were not obtained the significance of ozone attacking the olefinic groups of fatty acids in the membrane bilayer should not be completely ignored. 19 references, 12 figures.

Mexico City ozone concentrations as a function of readily-available meteorological parameters

International Nuclear Information System (INIS)

Brown, M.J.

1994-01-01

Daily maximum ozone concentrations measured at four sites within the Mexico City basin during the winter months are plotted as functions of different meteorological parameters that are routinely measured at surface stations. We found that ozone concentrations are most strongly correlated to the increase in daytime temperature and the maximum daytime wind speed. We also discovered that high ozone values at the sites in the southern end of the basin occur when winds come out of the northeast. In contrast, wind direction was found to be uncorrelated with high ozone values at the northern sites. From straightforward combinations of the meteorological variables, we derived some simple rules for estimating lower and upper bounds on the ozone concentration. Scatter in the data was too long to give significance to best-fit equations and statistics. Additionally, a small rawinsonde data set was used to investigate ozone's dependence on boundary-layer height and near-surface temperature gradient. Results were inconclusive, however, due to the small size of the data set

Merged SAGE II, Ozone_cci and OMPS ozone profile dataset and evaluation of ozone trends in the stratosphere

Directory of Open Access Journals (Sweden)

V. F. Sofieva

2017-10-01

Full Text Available In this paper, we present a merged dataset of ozone profiles from several satellite instruments: SAGE II on ERBS, GOMOS, SCIAMACHY and MIPAS on Envisat, OSIRIS on Odin, ACE-FTS on SCISAT, and OMPS on Suomi-NPP. The merged dataset is created in the framework of the European Space Agency Climate Change Initiative (Ozone_cci with the aim of analyzing stratospheric ozone trends. For the merged dataset, we used the latest versions of the original ozone datasets. The datasets from the individual instruments have been extensively validated and intercompared; only those datasets which are in good agreement, and do not exhibit significant drifts with respect to collocated ground-based observations and with respect to each other, are used for merging. The long-term SAGE–CCI–OMPS dataset is created by computation and merging of deseasonalized anomalies from individual instruments. The merged SAGE–CCI–OMPS dataset consists of deseasonalized anomalies of ozone in 10° latitude bands from 90° S to 90° N and from 10 to 50 km in steps of 1 km covering the period from October 1984 to July 2016. This newly created dataset is used for evaluating ozone trends in the stratosphere through multiple linear regression. Negative ozone trends in the upper stratosphere are observed before 1997 and positive trends are found after 1997. The upper stratospheric trends are statistically significant at midlatitudes and indicate ozone recovery, as expected from the decrease of stratospheric halogens that started in the middle of the 1990s and stratospheric cooling.

Tropospheric Ozone from the TOMS TDOT (TOMS-Direct-Ozone-in-Troposphere) Technique During SAFARI-2000

Science.gov (United States)

Stone, J. B.; Thompson, A. M.; Frolov, A. D.; Hudson, R. D.; Bhartia, P. K. (Technical Monitor)

2002-01-01

There are a number of published residual-type methods for deriving tropospheric ozone from TOMS (Total Ozone Mapping Spectrometer). The basic concept of these methods is that within a zone of constant stratospheric ozone, the tropospheric ozone column can be computed by subtracting stratospheric ozone from the TOMS Level 2 total ozone column, We used the modified-residual method for retrieving tropospheric ozone during SAFARI-2000 and found disagreements with in-situ ozone data over Africa in September 2000. Using the newly developed TDOT (TOMS-Direct-Ozone-in-Troposphere) method that uses TOMS radiances and a modified lookup table based on actual profiles during high ozone pollution periods, new maps were prepared and found to compare better to soundings over Lusaka, Zambia (15.5 S, 28 E), Nairobi and several African cities where MOZAIC aircraft operated in September 2000. The TDOT technique and comparisons are described in detail.

Valuing productivity loss due to absenteeism: firm-level evidence from a Canadian linked employer-employee survey

OpenAIRE

Zhang, Wei; Sun, Huiying; Woodcock, Simon; Anis, Aslam H.

2017-01-01

In health economic evaluation studies, to value productivity loss due to absenteeism, existing methods use wages as a proxy value for marginal productivity. This study is the first to test the equality between wage and marginal productivity losses due to absenteeism separately for team workers and non-team workers. Our estimates are based on linked employer-employee data from Canada. Results indicate that team workers are more productive and earn higher wages than non-team workers. However, t...

What Would Have Happened to the Ozone Layer if Chlorofluorocarbons (CFCs) had not been Regulated?

Science.gov (United States)

Newman, Paul A.; Oman, L. D.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M. M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.;

A Review of Atmospheric Ozone and Current Thinking on the Antarctic Ozone Hole.

Science.gov (United States)

1987-01-01

UNIVERSITY OF CALIFORNIA 0 A Review of Atmospheric ozone and Current Thinking on the Antartic Ozone Hole A thesis submitted in partial satisfaction of the...4. TI TLE (Pit 5,1tlfie) S. TYPE OF REPORT & PFRIOO COVERED A Review of Atmospheric Ozone and Current THESIS/DA/;J.At1AAU00 Thinking on the Antartic ...THESIS A Review of Atmospheric Ozone and Current Thinking on the Antartic Ozone Hole by Randolph Antoine Fix Master of Science in Atmospheric Science

Influence of local meteorology and NO2 conditions on ground-level ozone concentrations in the eastern part of Texas, USA.

Science.gov (United States)

Gorai, A K; Tuluri, F; Tchounwou, P B; Ambinakudige, S

2015-02-01

The influence of local climatic factors on ground-level ozone concentrations is an area of increasing interest to air quality management in regards to future climate change. This study presents an analysis on the role of temperature, wind speed, wind direction, and NO 2 level on ground-level ozone concentrations over the region of Eastern Texas, USA. Ozone concentrations at the ground level depend on the formation and dispersion processes. Formation process mainly depends on the precursor sources, whereas, the dispersion of ozone depends on meteorological factors. Study results showed that the spatial mean of ground-level ozone concentrations was highly dependent on the spatial mean of NO 2 concentrations. However, spatial distributions of NO 2 and ozone concentrations were not uniformed throughout the study period due to uneven wind speeds and wind directions. Wind speed and wind direction also played a significant role in the dispersion of ozone. Temperature profile in the area rarely had any effects on the ozone concentrations due to low spatial variations.

Effects of anthropogenic emissions on tropospheric ozone and its radiative forcing

Energy Technology Data Exchange (ETDEWEB)

Berntsen, T.; Isaksen, I.S.A.; Fuglestvedt, J.S.; Myhre, G.; Larsen, T. Alsvik; Stordal, F.; Freckleton, R.S.; Shine, K.P.

1997-12-31

As described in this report, changes in tropospheric ozone since pre-industrial times due to changes in emissions have been calculated by the University of Oslo global three-dimensional photochemical model. The radiative forcing caused by the increase in ozone has been calculated by means of two independent radiative transfer models: the University of Reading model (Reading), and the University of Oslo/Norwegian Institute for Air Research model (OsloRad). Significant increases in upper tropospheric ozone concentrations are found at northern mid-latitudes at about 10 km altitude. In the tropical regions the largest increase is found at about 15 km altitude. The increase is found to be caused mainly by enhanced in situ production due to transport of precursors from the boundary layer, with a smaller contribution from increased transport of ozone produced in the boundary layer. The lifetime of ozone in the troposphere decreased by about 35% as a result of enhanced concentrations of HO{sub 2}. The calculated increase in surface ozone in Europe is in good agreement with observations. The calculations of radiative forcing include the effect of clouds and allow for thermal adjustment in the stratosphere. The global and annual averaged radiative forcing at the tropopause from both models are in the lower part of the Intergovernmental Panel on Climate Change estimated range. The calculated radiative forcing is similar in magnitude to the negative radiative forcing by sulfate aerosols, but displaced southward in source regions at northern mid-latitudes. The increase in tropospheric ozone is calculated to have cooled the lower stratosphere by up to 0.9 K, with possibly half of this cooling occurring in the past 2 to 3 decades. 76 refs., 16 figs., 9 tabs.

Global health and economic impacts of future ozone pollution

International Nuclear Information System (INIS)

Selin, N E; Nam, K M; Reilly, J M; Paltsev, S; Prinn, R G; Webster, M D; Wu, S

2009-01-01

We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis - Health Effects (EPPA-HE) model, in combination with results from the GEOS-Chem global tropospheric chemistry model of climate and chemistry effects of projected future emissions. We use EPPA-HE to assess the human health damages (including mortality and morbidity) caused by ozone pollution, and quantify their economic impacts in sixteen world regions. We compare the costs of ozone pollution under scenarios with 2000 and 2050 ozone precursor and greenhouse gas emissions (using the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emissions Scenarios (SRES) A1B scenario). We estimate that health costs due to global ozone pollution above pre-industrial levels by 2050 will be $580 billion (year 2000$) and that mortalities from acute exposure will exceed 2 million. We find that previous methodologies underestimate costs of air pollution by more than a third because they do not take into account the long-term, compounding effects of health costs. The economic effects of emissions changes far exceed the influence of climate alone.

Ozone depletion calculations

International Nuclear Information System (INIS)

Luther, F.M.; Chang, J.S.; Wuebbles, D.J.; Penner, J.E.

1992-01-01

Models of stratospheric chemistry have been primarily directed toward an understanding of the behavior of stratospheric ozone. Initially this interest reflected the diagnostic role of ozone in the understanding of atmospheric transport processes. More recently, interest in stratospheric ozone has arisen from concern that human activities might affect the amount of stratospheric ozone, thereby affecting the ultraviolet radiation reaching the earth's surface and perhaps also affecting the climate with various potentially severe consequences for human welfare. This concern has inspired a substantial effort to develop both diagnostic and prognostic models of stratospheric ozone. During the past decade, several chemical agents have been determined to have potentially significant impacts on stratospheric ozone if they are released to the atmosphere in large quantities. These include oxides of nitrogen, oxides of hydrogen, chlorofluorocarbons, bromine compounds, fluorine compounds and carbon dioxide. In order to assess the potential impact of the perturbations caused by these chemicals, mathematical models have been developed to handle the complex coupling between chemical, radiative, and dynamical processes. Basic concepts in stratospheric modeling are reviewed

Quantifying the Impact of Tropospheric Ozone on Crops Productivity at regional scale using JULES-crop

Science.gov (United States)

Leung, F.

2016-12-01

Tropospheric ozone (O3) is the third most important anthropogenic greenhouse gas. It is causing significant crop production losses. Currently, O3 concentrations are projected to increase globally, which could have a significant impact on food security. The Joint UK Land Environment Simulator modified to include crops (JULES-crop) is used here to quantify the impacts of tropospheric O3 on crop production at the regional scale until 2100. We evaluate JULES-crop against the Soybean Free-Air-Concentration-Enrichment (SoyFACE) experiment in Illinois, USA. Experimental data from SoyFACE and various literature sources is used to calibrate the parameters for soybean and ozone damage parameters in soybean in JULES-crop. The calibrated model is then applied for a transient factorial set of JULES-crop simulations over 1960-2005. Simulated yield changes are attributed to individual environmental drivers, CO2, O3 and climate change, across regions and for different crops. A mixed scenario of RCP 2.6 and RCP 8.5 climatology and ozone are simulated to explore the implication of policy. The overall findings are that regions with high ozone concentration such as China and India suffer the most from ozone damage, soybean is more sensitive to O3 than other crops. JULES-crop predicts CO2 fertilisation would increase the productivity of vegetation. This effect, however, is masked by the negative impacts of tropospheric O3. Using data from FAO and JULES-crop estimated that ozone damage cost around 55.4 Billion USD per year on soybean. Irrigation improves the simulation of rice only, and it increases the relative ozone damage because drought can reduce the ozone from entering the plant stomata. RCP 8.5 scenario results in a high yield for all crops mainly due to the CO2 fertilisation effect. Mixed climate scenarios simulations suggest that RCP 8.5 CO2 concentration and RCP 2.6 O3 concentration result in the highest yield. Further works such as more crop FACE-O3 experiments and more Crop

Artificially ionized region as a source of ozone in the stratosphere

International Nuclear Information System (INIS)

Gurevich, Aleksandr V; Litvak, Aleksandr G; Vikharev, A L; Ivanov, O A; Borisov, Nikolai D; Sergeichev, Konstantin F

2000-01-01

A set of physical and chemical processes occurring in a microwave stratospheric discharge of nanosecond duration is discussed in connection with the effect they may have locally on the ozone layer in the artificially ionized region (AIR) in the stratosphere. The AIR, to be created at altitudes of 18 - 20 km by the microwave breakdown of air with ground-produced powerful electromagnetic wave beams, is planned for use in the natural physical experiment aimed at active monitoring of the ozone layer (its internal state and a set of plasma-chemical and photochemical processes) by controllably generating a considerable amount of ozone in the stratosphere. Results of relevant theoretical studies are presented, as are those of a large series of laboratory experiments performed under conditions similar to those prevailing in the stratosphere. Discharge regimes securing the efficient growth of ozone concentration are identified and studied in detail. It is demonstrated that such a stratospheric ozonizer is about as efficient as the best ground-based ozonizers used at present. For typical stratospheric conditions (low pressures and temperatures T ∼ 200 - 220 K), it is shown that the intense generation of ozone in a microwave breakdown effected by groups of short nanosecond pulses does not virtually increase the density of nitrogen oxides - gases that play a vital role in catalytic ozone-decomposing reactions. The possibility of effectively producing ozone in prebreakdown electric fields is established experimentally. It is demonstrated that due to its long lifetime, ozone produced locally at altitudes of 18 - 20 km may spread widely under the action of winds and turbulent diffusion, thus leading to an additional - artificial - ozonization of the stratosphere. (reviews of topical problems)

Effects of model chemistry and data biases on stratospheric ozone assimilation

Directory of Open Access Journals (Sweden)

L. Coy

2007-06-01

Full Text Available The innovations or observation minus forecast (O–F residuals produced by a data assimilation system provide a convenient metric of evaluating global analyses. In this study, O–F statistics from the Global Ozone Assimilation Testing System (GOATS are used to examine how ozone assimilation products and their associated O–F statistics depend on input data biases and ozone photochemistry parameterizations (OPP. All the GOATS results shown are based on a 6-h forecast and analysis cycle using observations from SBUV/2 (Solar Backscatter UltraViolet instrument-2 during September–October 2002. Results show that zonal mean ozone analyses are more independent of observation biases and drifts when using an OPP, while the mean ozone O–Fs are more sensitive to observation drifts when using an OPP. In addition, SD O–Fs (standard deviations are reduced in the upper stratosphere when using an OPP due to a reduction of forecast model noise and to increased covariance between the forecast model and the observations. Experiments that changed the OPP reference state to match the observations by using an "adaptive" OPP scheme reduced the mean ozone O–Fs at the expense of zonal mean ozone analyses being more susceptible to data biases and drifts. Additional experiments showed that the upper boundary of the ozone DAS can affect the quality of the ozone analysis and therefore should be placed well above (at least a scale height the region of interest.

Ozone phytotoxicity evaluation and prediction of crops production in tropical regions

Science.gov (United States)

Mohammed, Nurul Izma; Ramli, Nor Azam; Yahya, Ahmad Shukri

2013-04-01

Increasing ozone concentration in the atmosphere can threaten food security due to its effects on crop production. Since the 1980s, ozone has been believed to be the most damaging air pollutant to crops. In Malaysia, there is no index to indicate the reduction of crops due to the exposure of ozone. Therefore, this study aimed to identify the accumulated exposure over a threshold of X ppb (AOTX) indexes in assessing crop reduction in Malaysia. In European countries, crop response to ozone exposure is mostly expressed as AOT40. This study was designed to evaluate and predict crop reduction in tropical regions and in particular, the Malaysian climate, by adopting the AOT40 index method and modifying it based on Malaysian air quality and crop data. Nine AOTX indexes (AOT0, AOT5, AOT10, AOT15, AOT20, AOT25, AOT30, AOT40, and AOT50) were analyzed, crop responses tested and reduction in crops predicted. The results showed that the AOT50 resulted in the highest reduction in crops and the highest R2 value between the AOT50 and the crops reduction from the linear regression analysis. Hence, this study suggests that the AOT50 index is the most suitable index to estimate the potential ozone impact on crops in tropical regions. The result showed that the critical level for AOT50 index if the estimated crop reduction is 5% was 1336 ppb h. Additionally, the results indicated that the AOT40 index in Malaysia gave a minimum percentage of 6% crop reduction; as contrasted with the European guideline of 5% (due to differences in the climate e.g., average amount of sunshine).

Effect of excess ozone on UV-stimulated tritium oxidation

International Nuclear Information System (INIS)

Hasegawa, Kiyoshi; Horii, Kazuhiro; Matsuyama, Masao; Watanabe, Kuniaki.

1995-01-01

The authors have reported that the oxidation of tritium is considerably accelerated by irradiating a mixture gas of HT(H 2 )-O 2 with UV-photons, and this UV-stimulated HT oxidation is mainly due to the formation of intermediates such as ozone and activated oxygen species. This suggests that the oxidation will be much more enhanced in the presence of excess ozone in the reaction system. To examine this possibility, effects of the excess ozone on the UV-stimulated HT oxidation was experimentally studied on the one hand, and reaction mechanisms were investigated by developing a computer simulation program applicable to the three-component system of HT(H 2 )-O 2 -O 3 . The formation rate of HTO was measured for gas mixtures consisting of O 2 (75.5 Torr), O 3 (0.5-2% of O 2 ), H 2 (0.1-3% of O 2 ) and HT(H 2 /HT=12000). The experiments showed considerable enhancement of the HTO production rate in the presence of excess ozone by UV-photons from a low pressure mercury lamp(5W). The time course of the reaction was reproduced quite well by computer simulation, indicating that the assumed reaction mechanism is valid. This is also supported by observations that computer simulation reproduced the experimentally observed dependence of ozone decomposition rate on ozone and hydrogen pressures under the UV-irradiation. Those results showed that UV-stimulated HT oxidation was accelerated by about 14000 times in the presence of excess ozone. It strongly suggests that the UV-stimulated oxidation in the presence of excess ozone will be applicable to tritium handling systems as a non-catalytic tritium removal method. (author)

Ceramic membrane ozonator for soluble organics removal from produced water

Science.gov (United States)

Siagian, U. W. R.; Dwipramana, A. S.; Perwira, S. B.; Khoiruddin; Wenten, I. G.

2018-01-01

In this work, the performance of ozonation for degradation of soluble organic compounds in produced water was investigated. Tubular ceramic membrane diffuser (with and without a static mixer in the lumen side) was used to facilitate contact between ozone and produced water. The ozonation was conducted at ozone flow rate of 8 L.min-1, ozone concentration of 0.4 ppm, original pH of the solution, and pressure of 1.2 bar, while the flow rates of the produced water were varied (192, 378 and 830 mL.min-1). It was found that the reduction of benzene, toluene, ethylbenzene, and xylene were 85%, 99%, 85%, and 95%, respectively. A lower liquid flow rate in a laminar state showed a better component reduction due to the longer contacting time between the liquid and the gas phase. The introduction of the static mixer in the lumen side of the membrane as a turbulence promoter provided a positive effect on the performance of the membrane diffuser. The twisted static mixer exhibited the better removal rate than the spiral static mixer.

[Labor productivity losses attributable to premature deaths due to traffic injuries between 2002 and 2012].

Science.gov (United States)

Cubí-Mollá, Patricia; Peña-Longobardo, Luz María; Casal, Bruno; Rivera, Berta; Oliva-Moreno, Juan

2015-09-01

To estimate the years of potential life lost, years of potential productive life lost and the labor productivity losses attributable to premature deaths due to traffic injuries between 2002 and 2012 in Spain. Several statistical sources were combined (Spanish Registry of Deaths, Labor Force Survey and Wage Structure Survey) to develop a simulation model based on the human capital approach. This model allowed us to estimate the loss of labor productivity caused by premature deaths following traffic injuries from 2002 to 2012. In addition, mortality tables with life expectancy estimates were used to compute years of potential life lost and years of potential productive life lost. The estimated loss of labour productivity caused by fatal traffic injuries between 2002 and 2012 in Spain amounted to 9,521 million euros (baseline year 2012). The aggregate number of years of potential life lost in the period amounted to 1,433,103, whereas the years of potential productive life lost amounted to 875,729. Throughout the period analyzed, labor productivity losses and years of life lost diminished substantially. Labor productivity losses due to fatal traffic injuries decreased throughout the period analyzed. Nevertheless, the cumulative loss was alarmingly high. Estimation of the economic impact of health problems can complement conventional indicators of distinct dimensions and be used to support public policy making. Copyright © 2014 SESPAS. Published by Elsevier Espana. All rights reserved.

[Ozone concentration distribution of urban].

Science.gov (United States)

Yin, Yong-quan; Li, Chang-mei; Ma, Gui-xia; Cui, Zhao-jie

2004-11-01

The increase of ozone concentration in urban is one of the most important research topics on environmental science. With the increase of nitrogen oxides and hydrogen-carbon compounds which are exhausted from cars, the ozone concentration in urban is obviously increased on sunlight, and threat of photochemistry smog will be possible. Therefore, it is very important to monitor and study the ozone concentration distribution in urban. The frequency-distribution, diurnal variation and monthly variation of ozone concentration were studied on the campus of Shandong University during six months monitoring. The influence of solar radiation and weather conditions on ozone concentration were discussed. The frequency of ozone concentration less than 200 microg/m3 is 96.88%. The ozone concentration has an obvious diurnal variation. The ozone concentration in the afternoon is higher than in the morning and in the evening. The maximum appears in June, when it is the strong solar radiation and high air-temperature. The weather conditions also influence the ozone concentration. The ozone concentration in clear day is higher than in rainy and cloudy day.

Ozonation and/or Coagulation - Ceramic Membrane Hybrid for Filtration of Impaired-Quality Source Waters

KAUST Repository

Ha, Changwon

2013-09-01

When microfiltration (MF) and ultrafiltration (UF) membranes are applied for drinking water treatment/wastewater reuse, membrane fouling is an evitable problem, causing the loss of productivity over time. Polymeric membranes have been often reported to experience rapid and/or problematical fouling, restraining sustainable operation. Ceramic membranes can be effectively employed to treat impaired-quality source waters due to their inherent robustness in terms of physical and chemical stability. This research aimed to identify the effects of coagulation and/or ozonation on ceramic membrane filtration for seawater and wastewater (WW) effluent. Two different types of MF and UF ceramic membranes obtained by sintering (i.e., TAMI made of TiO2+ZrO2) and anodic oxidation process (i.e., AAO made of Al2O3) were employed for bench-scale tests. Precoagulation was shown to play an important role in both enhancing membrane filterability and natural organic matter (NOM) removal efficacy for treating a highorganic surface water. The most critical factors were found to be pH and coagulant dosage with the highest efficiency resulting under low pH and high coagulant dose. Due to the ozone-resistance nature of the ceramic membranes, preozonation allowed the ceramic membranes to be operated at higher flux, especially leading to significant flux improvement when treating seawater in the presence of calcium and magnesium. 4 Dissolved ozone in contact with the TAMI ceramic membrane surface accelerated the formation of hydroxyl (˙OH) radicals in WW effluent treatment. Flux restoration of both ceramic membranes, fouled with seawater and WW effluent, was efficiently achieved by high backwash (BW) pressure and ozone in chemically enhanced backwashing (CEB). Ceramic membranes exhibited a pH-dependent permeate flux while filtering WW effluent, showing reduced fouling with increased pH. On the other hand, for filtering seawater, differences in permeate flux between the two membranes was

Galactic cosmic rays and tropical ozone asymmetries

International Nuclear Information System (INIS)

Kilifarska, Natalya; Bakhmutov, Volodymyr; Melnyk, Galyna

2017-01-01

Lower stratospheric ozone O_3 is of special interest to climatic studies due to its direct influence on the tropopause temperature, and correspondingly on Earth’s radiation balance. By reason of the suppressed dissociation of molecular oxygen by solar UV radiation and the long life span of the lower stratospheric O_3 , its temporal variability is usually attributed to atmospheric circulation. Here we report about latitudinal-longitudinal differences in a centennial evolution of the tropical O_3 at 70 hPa. These asymmetries are hardly explicable within the concept of the ozone’s dynamical control alone. Analysis of ozone, energetic particles and the geomagnetic records from the last 111 years has revealed that they all evolve synchronously with time. This coherence motivates us to propose a mechanism explaining the geomagnetic and galactic cosmic ray influence on the near tropopause O_3 , allowing for an understanding of its spatial-temporal variability during the past century. Key words: galactic cosmic rays, asymmetries of tropical ozone distribution, geomagnetic filed

Ozone kinetics in low-pressure discharges: vibrationally excited ozone and molecule formation on surfaces

Science.gov (United States)

Marinov, Daniil; Guerra, Vasco; Guaitella, Olivier; Booth, Jean-Paul; Rousseau, Antoine

2013-10-01

A combined experimental and modeling investigation of the ozone kinetics in the afterglow of pulsed direct current discharges in oxygen is carried out. The discharge is generated in a cylindrical silica tube of radius 1 cm, with short pulse durations between 0.5 and 2 ms, pressures in the range 1-5 Torr and discharge currents ˜40-120 mA. Time-resolved absolute concentrations of ground-state atoms and ozone molecules were measured simultaneously in situ, by two-photon absorption laser-induced fluorescence and ultraviolet absorption, respectively. The experiments were complemented by a self-consistent model developed to interpret the results and, in particular, to evaluate the roles of vibrationally excited ozone and of ozone formation on surfaces. It is found that vibrationally excited ozone, O_3^{*} , plays an important role in the ozone kinetics, leading to a decrease in the ozone concentration and an increase in its formation time. In turn, the kinetics of O_3^{*} is strongly coupled with those of atomic oxygen and O2(a 1Δg) metastables. Ozone formation at the wall does not contribute significantly to the total ozone production under the present conditions. Upper limits for the effective heterogeneous recombination probability of O atoms into ozone are established.

Ozone kinetics in low-pressure discharges: vibrationally excited ozone and molecule formation on surfaces

International Nuclear Information System (INIS)

Marinov, Daniil; Guaitella, Olivier; Booth, Jean-Paul; Rousseau, Antoine; Guerra, Vasco

2013-01-01

A combined experimental and modeling investigation of the ozone kinetics in the afterglow of pulsed direct current discharges in oxygen is carried out. The discharge is generated in a cylindrical silica tube of radius 1 cm, with short pulse durations between 0.5 and 2 ms, pressures in the range 1–5 Torr and discharge currents ∼40–120 mA. Time-resolved absolute concentrations of ground-state atoms and ozone molecules were measured simultaneously in situ, by two-photon absorption laser-induced fluorescence and ultraviolet absorption, respectively. The experiments were complemented by a self-consistent model developed to interpret the results and, in particular, to evaluate the roles of vibrationally excited ozone and of ozone formation on surfaces. It is found that vibrationally excited ozone, O 3 * , plays an important role in the ozone kinetics, leading to a decrease in the ozone concentration and an increase in its formation time. In turn, the kinetics of O 3 * is strongly coupled with those of atomic oxygen and O 2 (a 1 Δ g ) metastables. Ozone formation at the wall does not contribute significantly to the total ozone production under the present conditions. Upper limits for the effective heterogeneous recombination probability of O atoms into ozone are established. (paper)

Improvement of ozone yield by a multi-discharge type ozonizer using superposition of silent discharge plasma

International Nuclear Information System (INIS)

Song, Hyun-Jig; Chun, Byung-Joon; Lee, Kwang-Sik

2004-01-01

In order to improve ozone generation, we experimentally investigated the silent discharge plasma and ozone generation characteristics of a multi-discharge type ozonizer. Ozone in a multi-discharge type ozonizer is generated by superposition of a silent discharge plasma, which is simultaneously generated in separated discharge spaces. A multi-discharge type ozonizer is composed of three different kinds of superposed silent discharge type ozonizers, depending on the method of applying power to each electrode. We observed that the discharge period of the current pulse for a multi discharge type ozonizer can be longer than that of silent discharge type ozonizer with two electrodes and one gap. Hence, ozone generation is improved up to 17185 ppm and 783 g/kwh in the case of the superposed silent discharge type ozonizer for which an AC high voltages with a 180 .deg. phase difference were applied to the internal electrode and the external electrode, respectively, with the central electrode being grounded.

Ozone concentrations at a selected high-elevation forest site downwind Mexico City

Science.gov (United States)

Torres-JArdon, R.

2013-05-01

July to September. Episodes of high concentrations occurred mainly during the dry warm months. Most of the year, nocturnal ozone levels were higher than those registered in the urban area due to the PMH altitude. As a great part of the mountain terrain regularly is above the nocturnal mixing layer formed each day on the valley floor, the ozone remanent levels above this layer in the mountains are kept isolated from urban NOx emissions generated at night. An evaluation of the AOT40 indicator shows that the forest zone is under a strong risk due to ozone pollution. A preliminary analysis of several ozone events in the PNMH shows the suppression of the diel peak, suggesting that a stratospheric intrusion of ozone occurs frequently in high-elevation sites surrounding MCMA.

Climate Change Impacts on Human Health Due to Changes in Ambient Ozone Concentrations (External Review Draft)

Science.gov (United States)

This report uses results from a previous report titled Assessment of the Impacts of Global Change on Regional U.S. Air Quality: A Synthesis of Climate Change Impacts on Ground-Level Ozone, a number of high-resolution, spatially explicit population projections developed ...

A Mathematical Model Of Ageing In Man Due To Gene Loss | Mbah ...

African Journals Online (AJOL)

Aging is as a result of dysfunction of the body mechanisms due to failure of one organelle, tissue, component or the other. In man there is a pointer towards gene loss as a primary cause of ageing. In this paper we develop a mathematical model describing changes in gene efficiency or gene failure. This model is used to ...

Cardiopulmonary Mortalities and Chronic Obstructive Pulmonary Disease Attributed to Ozone Air Pollution

Directory of Open Access Journals (Sweden)

Gholamreza Goudarzi

2013-07-01

Full Text Available Background & Aims of the Study: Ozone is a summer pollutant which can cause respiratory complications, eye burning sensation and failure of immune defense against infectious diseases. Ahvaz city (southwestern Iran is one of the seven polluted Iranian metropolises. In this study we examined the health impacts of ozone pollution in Ahvaz city during years 2010 and 2011. Materials & Methods: The health effects of ozone pollution in Ahvaz estimated by determining mortality and morbidity, and incidence of diseases attributed to the ozone, i.e., cardiopulmonary mortalities and chronic obstructive pulmonary disease (COPD using Air Quality Model. Ozone data were taken from Ahvaz Department of Environment (ADoE. Conversion between volumetric and gravimetric units (correction of temperature and pressure, coding, processing (averaging and filtering were implemented. Results: Sum of accumulative cases of mortalities attributed to ozone was 358 cases in 2010 and 276 cases in 2011. Cardiovascular and respiratory mortality attributed to ozone were 118 and 31 persons, respectively; which revealed a considerable reduction compared to those values in 2010. Number of cases for hospital admissions due to COPD was 35 in 2011, while it was 45 cases in 2010. The concentration of ozone in 2011 was lower than that of 2010 and this is why both mortalities and morbidities of 2011 attributed to ozone pollutant had decreased when compared to those values of 2010. Conclusions: Mortality and morbidity attributed to ozone concentrations in 2011 were lower than those of 2010. The most important reason was less concentration in ground level ozone of 2011 than that of 2010 in Ahvaz city air.

Towards the retrieval of tropospheric ozone with the ozone monitoring instrument (OMI)

NARCIS (Netherlands)

Mielonen, T.; De Haan, J.F.; Van Peet, J.C.A.; Eremenko, M.; Veefkind, J.P.

2015-01-01

We have assessed the sensitivity of the operational Ozone Monitoring Instrument (OMI) ozone profile retrieval algorithm to a number of a priori and radiative transfer assumptions. We studied the effect of stray light correction, surface albedo assumptions and a priori ozone profiles on the retrieved

The impact of anthropogenic and biogenic emissions on surface ozone concentrations in Istanbul.

Science.gov (United States)

Im, Ulas; Poupkou, Anastasia; Incecik, Selahattin; Markakis, Konstantinos; Kindap, Tayfun; Unal, Alper; Melas, Dimitros; Yenigun, Orhan; Topcu, Sema; Odman, M Talat; Tayanc, Mete; Guler, Meltem

2011-03-01

Surface ozone concentrations at Istanbul during a summer episode in June 2008 were simulated using a high resolution and urban scale modeling system coupling MM5 and CMAQ models with a recently developed anthropogenic emission inventory for the region. Two sets of base runs were performed in order to investigate for the first time the impact of biogenic emissions on ozone concentrations in the Greater Istanbul Area (GIA). The first simulation was performed using only the anthropogenic emissions whereas the second simulation was performed using both anthropogenic and biogenic emissions. Biogenic NMVOC emissions were comparable with anthropogenic NMVOC emissions in terms of magnitude. The inclusion of biogenic emissions significantly improved the performance of the model, particularly in reproducing the low night time values as well as the temporal variation of ozone concentrations. Terpene emissions contributed significantly to the destruction of the ozone during nighttime. Biogenic NMVOCs emissions enhanced ozone concentrations in the downwind regions of GIA up to 25ppb. The VOC/NO(x) ratio almost doubled due to the addition of biogenic NMVOCs. Anthropogenic NO(x) and NMVOCs were perturbed by ±30% in another set of simulations to quantify the sensitivity of ozone concentrations to the precursor emissions in the region. The sensitivity runs, as along with the model-calculated ozone-to-reactive nitrogen ratios, pointed NO(x)-sensitive chemistry, particularly in the downwind areas. On the other hand, urban parts of the city responded more to changes in NO(x) due to very high anthropogenic emissions. Copyright © 2010 Elsevier B.V. All rights reserved.

Comparative study of ozonized olive oil and ozonized sunflower oil

OpenAIRE

Díaz,Maritza F.; Hernández,Rebeca; Martínez,Goitybell; Vidal,Genny; Gómez,Magali; Fernández,Harold; Garcés,Rafael

2006-01-01

In this study the ozonized olive and sunflower oils are chemical and microbiologically compared. These oils were introduced into a reactor with bubbling ozone gas in a water bath at room temperature until they were solidified. The peroxide, acidity and iodine values along with antimicrobial activity were determined. Ozonization effects on the fatty acid composition of these oils were analyzed using Gas-Liquid Chromatographic Technique. An increase in peroxidation and acidity values was observ...

Effects of ozone-vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks

Science.gov (United States)

Sadiq, Mehliyar; Tai, Amos P. K.; Lombardozzi, Danica; Martin, Maria Val

2017-02-01

Tropospheric ozone is one of the most hazardous air pollutants as it harms both human health and plant productivity. Foliage uptake of ozone via dry deposition damages photosynthesis and causes stomatal closure. These foliage changes could lead to a cascade of biogeochemical and biogeophysical effects that not only modulate the carbon cycle, regional hydrometeorology and climate, but also cause feedbacks onto surface ozone concentration itself. In this study, we implement a semi-empirical parameterization of ozone damage on vegetation in the Community Earth System Model to enable online ozone-vegetation coupling, so that for the first time ecosystem structure and ozone concentration can coevolve in fully coupled land-atmosphere simulations. With ozone-vegetation coupling, present-day surface ozone is simulated to be higher by up to 4-6 ppbv over Europe, North America and China. Reduced dry deposition velocity following ozone damage contributes to ˜ 40-100 % of those increases, constituting a significant positive biogeochemical feedback on ozone air quality. Enhanced biogenic isoprene emission is found to contribute to most of the remaining increases, and is driven mainly by higher vegetation temperature that results from lower transpiration rate. This isoprene-driven pathway represents an indirect, positive meteorological feedback. The reduction in both dry deposition and transpiration is mostly associated with reduced stomatal conductance following ozone damage, whereas the modification of photosynthesis and further changes in ecosystem productivity are found to play a smaller role in contributing to the ozone-vegetation feedbacks. Our results highlight the need to consider two-way ozone-vegetation coupling in Earth system models to derive a more complete understanding and yield more reliable future predictions of ozone air quality.

Vertical distribution of ozone at the terminator on Mars

Science.gov (United States)

Maattanen, Anni; Lefevre, Franck; Guilbon, Sabrina; Listowski, Constantino; Montmessin, Franck

2016-10-01

The SPICAM/Mars Express UV solar occultation dataset gives access to the ozone vertical distribution via the ozone absorption in the Hartley band (220-280 nm). We present the retrieved ozone profiles and compare them to the LMD Mars Global Climate Model (LMD-MGCM) results.Due to the photochemical reactivity of ozone, a classical comparison of local density profiles is not appropriate for solar occultations that are acquired at the terminator, and we present here a method often used in the Earth community. The principal comparison is made via the slant profiles (integrated ozone concentration on the line-of-sight), since the spherical symmetry hypothesis made in the onion-peeling vertical inversion method is not valid for photochemically active species (e.g., ozone) around terminator. For each occultation, we model the ozone vertical and horizontal distribution with high solar zenith angle (or local time) resolution around the terminator and then integrate the model results following the lines-of-sight of the occultation to construct the modeled slant profile. We will also discuss the difference of results between the above comparison method and a comparison using the local density profiles, i.e., the observed ones inverted by using the spherical symmetry hypothesis and the modeled ones extracted from the LMD-MGCM exactly at the terminator. The method and the results will be presented together with the full dataset.SPICAM is funded by the French Space Agency CNES and this work has received funding from the European Union's Horizon 2020 Programme (H2020-Compet-08-2014) under grant agreement UPWARDS-633127.

Brief communication: Post-event analysis of loss of life due to hurricane Harvey

OpenAIRE

Jonkman, Sebastiaan N.; Godfroy, Maartje; Sebastian, Antonia; Kolen, Bas

2018-01-01

An analysis was made of the loss of life directly caused by hurricane Harvey. Information was collected for 70 fatalities that occurred directly due to the event. Most of the fatalities occurred in the greater Houston area, which was most severely affected by extreme rainfall and heavy flooding. The majority of fatalities in this area were recovered outside the designated 100 and 500 year flood zones. Most fatalities occurred due to drowning (81 %), particularly in and around vehicles...

Tooth loss due to periodontal abscess: a retrospective study.

Science.gov (United States)

McLeod, D E; Lainson, P A; Spivey, J D

1997-10-01

This retrospective study focused on the frequency of tooth loss due to periodontal abscess among 42 patients who were treated by a single clinician over a 5- to 29-year period. A total of 114 patients were selected from the active periodontal recall schedule of a single periodontist at The University of Iowa College of Dentistry. The criteria for inclusion in the study included having a history of moderate to advanced periodontitis, being on 3 to 6 month recall periodontal maintenance care, and completion of active periodontal therapy prior to October 1987. Other parameters evaluated were age; gender; number of teeth present and missing at the initial, reevaluation, and last periodontal recall visit; initial periodontal prognosis; furcation involvement; non-surgical and surgical periodontal therapy; and reasons for tooth loss. Patients were grouped according to the number of teeth lost following active periodontal treatment into well-maintained (0 to 3), downhill (4 to 9), and extreme downhill (10 to 23) groups. Forty-two of the 114 patients were identified as having one or more periodontal abscesses. A total of 109 teeth were affected by periodontal abscess of which 49 (45%) teeth were lost and 60 (55%) were successfully maintained over an average of 12.5 years (5 to 29 years). More furcated teeth were lost than nonfurcated teeth and teeth given a hopeless prognosis were lost more consistently than those given a questionable prognosis in all groups. The frequency of periodontal abscess and tooth loss per patient was greater in the downhill and extreme downhill response groups than the well-maintained group. This suggests that teeth with a history of periodontal abscess can be treated and maintained for several years.

Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

Energy Technology Data Exchange (ETDEWEB)

Morrison, Glenn Charles [Univ. of California, Berkeley, CA (United States)

1999-12-01

In this dissertation, results are presented of laboratory investigations and mathematical modeling efforts designed to better understand the interactions of ozone with surfaces. In the laboratory, carpet and duct materials were exposed to ozone and measured ozone uptake kinetics and the ozone induced emissions of volatile organic compounds. To understand the results of the experiments, mathematical methods were developed to describe dynamic indoor aldehyde concentrations, mass transport of reactive species to smooth surfaces, the equivalent reaction probability of whole carpet due to the surface reactivity of fibers and carpet backing, and ozone aging of surfaces. Carpets, separated carpet fibers, and separated carpet backing all tended to release aldehydes when exposed to ozone. Secondary emissions were mostly n-nonanal and several other smaller aldehydes. The pattern of emissions suggested that vegetable oils may be precursors for these oxidized emissions. Several possible precursors and experiments in which linseed and tung oils were tested for their secondary emission potential were discussed. Dynamic emission rates of 2-nonenal from a residential carpet may indicate that intermediate species in the oxidation of conjugated olefins can significantly delay aldehyde emissions and act as reservoir for these compounds. The ozone induced emission rate of 2-nonenal, a very odorous compound, can result in odorous indoor concentrations for several years. Surface ozone reactivity is a key parameter in determining the flux of ozone to a surface, is parameterized by the reaction probability, which is simply the probability that an ozone molecule will be irreversibly consumed when it strikes a surface. In laboratory studies of two residential and two commercial carpets, the ozone reaction probability for carpet fibers, carpet backing and the equivalent reaction probability for whole carpet were determined. Typically reaction probability values for these materials were 10

Evaluation of The Surface Ozone Concentrations In Greater Cairo Area With Emphasis On Helwan, Egypt

International Nuclear Information System (INIS)

Ramadan, A.; Kandil, A.T.; Abd Elmaged, S.M.; Mubarak, I.

2011-01-01

Various biogenic and anthropogenic sources emit huge quantities of surface ozone. The main purpose of this study is to evaluate the surface ozone levels present at Helwan area in order to improve the knowledge and understanding troposphere processes. Surface Ozone has been measured at 2 sites at Helwan; these sites cover the most populated area in Helwan. Ozone concentration is continuously monitored by UV absorption photometry using the equipment O 3 41 M UV Photometric Ozone Analyzer. The daily maximum values of the ozone concentration in the greater Cairo area have approached but did not exceeded the critical levels during the year 2008. Higher ozone concentrations at Helwan are mainly due to the transport of ozone from regions further to the north of greater Cairo and to a lesser extent of ozone locally generated by photochemical smog process. The summer season has the largest diurnal variation, with the tendency of the daily ozone maxima occur in the late afternoon. The night time concentration of ozone was significantly higher at Helwan because there are no fast acting sinks, destroying ozone since the average night time concentration of ozone is maintained at 40 ppb at the site. No correlation between the diurnal total suspended particulate (TSP) matter and the diurnal cumulative ozone concentration was observed during the Khamasin period

Production loss due to new subclinical mastitis in Dutch dairy cows estimated iwth a test-day model

NARCIS (Netherlands)

Halasa, T.; Nielen, M.; Roos, de S.; Hoorne, van R.; Jong, de G.; Lam, T.J.G.M.; Werven, van T.; Hogeveen, H.

2009-01-01

Milk, fat, and protein loss due to a new subclinical mastitis case may be economically important, and the objective of this study was to estimate this loss. The loss was estimated based on test-day (TD) cow records collected over a 1-yr period from 400 randomly selected Dutch dairy herds. After

Cyanide Containing Wastewater Treatment by Ozone Enhanced Catalytic Oxidation over Diatomite Catalysts

Directory of Open Access Journals (Sweden)

Lin Mingguo

2018-01-01

Full Text Available Cyanide containing wastewater that discharged from gold mining process creates environmental problems due to the toxicity of cyanide. As one of the promising advanced oxidation process, catalytic oxidation with ozone is considered to be effective on the purification of cyanide. Diatomite, a natural mineral, was used as catalyst in this study. The effect of O3 dosage, salinity, initial cyanide concentration and initial pH condition were investigated. It was observed that the removal rate of cyanide was much higher in the catalytic oxidation with ozone process than the one in zone alone process. Alkaline condition was especially favorable for cyanide in catalytic oxidation with ozone. The ozone and catalytic oxidation with ozone were simulated by pseudo-first-order kinetics model. The apparent first-order rate constant contribution of the diatomite catalyst was 0.0757 min-1, and the contribution percentage was 65.77%.

Experimental and theoretical studies of nuclear generation of ozone from oxygen and oxygen--sulfur hexafluoride mixtures

International Nuclear Information System (INIS)

Elsayed-Ali, H.E.; Miley, G.H.

1986-01-01

A series of experimental measurements of the yield of O 3 in nuclear-induced O 2 and O 2 -SF 6 discharges are reported. The discharges were created by bombardment with energetic particles from the 10 B(n,α) 7 Li reaction. Continuous irradiation at dose rates of 10 15 --10 17 eV cm -3 s -1 and pulsed irradiation (--10 ms FWHM) at a peak dose rate of --10 20 eV cm -3 s -1 were conducted. At the lower dose rates, the addition of SF 6 generally increased the ozone yield due to the slowing of ozone destruction by negative oxygen and ozone ions. In contrast, at the high dose rates, the ozone concentration decreased due to SF 6 suppression of atomic oxygen formation by ion--ion recombination. A numerical model was developed and tested against experimental conditions. This model indicates that the steady-state ozone concentration was limited by the reaction O - 3 +O 3 →2O 2 +O - 2 with a rate coefficient of --1 x 10 -12 cm 3 s -1 . In addition to dose rate effects, pressure and temperature effects on ozone production are discussed and methods for increasing the ozone yield are suggested

Experimental and theoretical studies of nuclear generation of ozone from oxygen and oxygen-sulfur hexafluoride mixtures

Science.gov (United States)

Elsayed-Ali, H. E.; Miley, G. H.

1986-08-01

A series of experimental measurements of the yield of O3 in nuclear-induced O2 and O2-SF6 discharges are reported. The discharges were created by bombardment with energetic particles from the 10B(n,α)7Li reaction. Continuous irradiation at dose rates of 1015-1017 eV cm-3 s-1 and pulsed irradiation (˜10 ms FWHM) at a peak dose rate of ˜1020 eV cm-3 s-1 were conducted. At the lower dose rates, the addition of SF6 generally increased the ozone yield due to the slowing of ozone destruction by negative oxygen and ozone ions. In contrast, at the high dose rates, the ozone concentration decreased due to SF6 suppression of atomic oxygen formation by ion-ion recombination. A numerical model was developed and tested against experimental conditions. This model indicates that the steady-state ozone concentration was limited by the reaction O-3+O3→2O2+O-2 with a rate coefficient of ˜1×10-12 cm3 s-1. In addition to dose rate effects, pressure and temperature effects on ozone production are discussed and methods for increasing the ozone yield are suggested.

Estonian total ozone climatology

Directory of Open Access Journals (Sweden)

K. Eerme

Full Text Available The climatological characteristics of total ozone over Estonia based on the Total Ozone Mapping Spectrometer (TOMS data are discussed. The mean annual cycle during 1979–2000 for the site at 58.3° N and 26.5° E is compiled. The available ground-level data interpolated before TOMS, have been used for trend detection. During the last two decades, the quasi-biennial oscillation (QBO corrected systematic decrease of total ozone from February–April was 3 ± 2.6% per decade. Before 1980, a spring decrease was not detectable. No decreasing trend was found in either the late autumn ozone minimum or in the summer total ozone. The QBO related signal in the spring total ozone has an amplitude of ± 20 DU and phase lag of 20 months. Between 1987–1992, the lagged covariance between the Singapore wind and the studied total ozone was weak. The spring (April–May and summer (June–August total ozone have the best correlation (coefficient 0.7 in the yearly cycle. The correlation between the May and August total ozone is higher than the one between the other summer months. Seasonal power spectra of the total ozone variance show preferred periods with an over 95% significance level. Since 1986, during the winter/spring, the contribution period of 32 days prevails instead of the earlier dominating 26 days. The spectral densities of the periods from 4 days to 2 weeks exhibit high interannual variability.

Key words. Atmospheric composition and structure (middle atmosphere – composition and chemistry; volcanic effects – Meteorology and atmospheric dynamics (climatology

Transient cortical blindness after intradiscal oxygen–ozone therapy

Directory of Open Access Journals (Sweden)

Agostino Salvatore Vaiano

2016-01-01

Full Text Available A 54-year-old caucasian male developed bilateral blindness during an oxygen–ozone injection for disc herniation. The visual loss (VL was immediately followed by severe frontal headache, vomiting, and nausea. The patient underestimated the VL showing Anton's syndrome, with a complete visual recovery after 2-month follow-up. Magnetic resonance data were consistent with recent ischemic lesions in bilateral vascular territories of posterior cerebral arteries.

Dobson spectrophotometer ozone measurements during international ozone rocketsonde intercomparison

Science.gov (United States)

Parsons, C. L.

1980-01-01

Measurements of the total ozone content of the atmosphere, made with seven ground based instruments at a site near Wallops Island, Virginia, are discussed in terms for serving as control values with which the rocketborne sensor data products can be compared. These products are profiles of O3 concentration with altitude. By integrating over the range of altitudes from the surface to the rocket apogee and by appropriately estimating the residual ozone amount from apogee to the top of the atmosphere, a total ozone amount can be computed from the profiles that can be directly compared with the ground based instrumentation results. Dobson spectrophotometers were used for two of the ground-based instruments. Preliminary data collected during the IORI from Dobson spectrophotometers 72 and 38 are presented. The agreement between the two and the variability of total ozone overburden through the experiment period are discussed.

Physiological responses of Pinus sylvestris to changing carbon dioxide and ozone concentrations

Energy Technology Data Exchange (ETDEWEB)

Holopainen, T [Kuopio Univ. (Finland). Dept. of Ecology and Environmental Science; Palomaeki, V [Joensuu Univ. (Finland). Faculty of Forestry; Helmisaari, H S [Finnish Forest Research Inst., Helsinki (Finland); and others

1997-12-31

The objective of this research is to study the effects of elevated ozone, carbon dioxide and their combination on ultrastructural, physiological and biochemical responses of Scots pine needles and how these effects are reflected to photosynthesis, carbohydrate and nutrient allocation and finally to shoot and root growth of trees. In addition the interactions of the studied trees and mycorrhizal fungi as well as insect herbivores are studied. The exposures have been running only for two growing periods and it seems necessary to continue the experiment over the third growing season in 1996. Since the analyses are partially incomplete, only preliminary conclusions are possible at the moment. The slightly increased shoot growth and needle width and increased amount of starch in chloroplasts point to the slight stimulating effect of elevated CO{sub 2} among the chamber treatments. Altogether the growth of the seedlings was best in the chamberless treatment indicating a negative chamber effect. The elevated ozone significantly increased the chlorotic mottling and overall yellowing of second year needles as well as caused increased density of chloroplast stroma and declined photosynthesis, all these responses being often related to ozone exposures. The ozone related responses appeared at both CO{sub 2} levels indicating no clear protection due to elevated CO{sub 2}. The ozone or carbon dioxide treatments were not able to significantly change nutrient concentrations, insect herbivory or carbon allocation among the secondary compounds of needles. A tendency of increased carbon allocation to fine roots due to ozone but not so clearly to CO{sub 2} was observed

Physiological responses of Pinus sylvestris to changing carbon dioxide and ozone concentrations

Energy Technology Data Exchange (ETDEWEB)

Holopainen, T. [Kuopio Univ. (Finland). Dept. of Ecology and Environmental Science; Palomaeki, V. [Joensuu Univ. (Finland). Faculty of Forestry; Helmisaari, H.S. [Finnish Forest Research Inst., Helsinki (Finland)] [and others

1996-12-31

The objective of this research is to study the effects of elevated ozone, carbon dioxide and their combination on ultrastructural, physiological and biochemical responses of Scots pine needles and how these effects are reflected to photosynthesis, carbohydrate and nutrient allocation and finally to shoot and root growth of trees. In addition the interactions of the studied trees and mycorrhizal fungi as well as insect herbivores are studied. The exposures have been running only for two growing periods and it seems necessary to continue the experiment over the third growing season in 1996. Since the analyses are partially incomplete, only preliminary conclusions are possible at the moment. The slightly increased shoot growth and needle width and increased amount of starch in chloroplasts point to the slight stimulating effect of elevated CO{sub 2} among the chamber treatments. Altogether the growth of the seedlings was best in the chamberless treatment indicating a negative chamber effect. The elevated ozone significantly increased the chlorotic mottling and overall yellowing of second year needles as well as caused increased density of chloroplast stroma and declined photosynthesis, all these responses being often related to ozone exposures. The ozone related responses appeared at both CO{sub 2} levels indicating no clear protection due to elevated CO{sub 2}. The ozone or carbon dioxide treatments were not able to significantly change nutrient concentrations, insect herbivory or carbon allocation among the secondary compounds of needles. A tendency of increased carbon allocation to fine roots due to ozone but not so clearly to CO{sub 2} was observed

Representativeness of single lidar stations for zonally averaged ozone profiles, their trends and attribution to proxies

Directory of Open Access Journals (Sweden)

C. Zerefos

2018-05-01

Full Text Available This paper is focusing on the representativeness of single lidar stations for zonally averaged ozone profile variations over the middle and upper stratosphere. From the lower to the upper stratosphere, ozone profiles from single or grouped lidar stations correlate well with zonal means calculated from the Solar Backscatter Ultraviolet Radiometer (SBUV satellite overpasses. The best representativeness with significant correlation coefficients is found within ±15° of latitude circles north or south of any lidar station. This paper also includes a multivariate linear regression (MLR analysis on the relative importance of proxy time series for explaining variations in the vertical ozone profiles. Studied proxies represent variability due to influences outside of the earth system (solar cycle and within the earth system, i.e. dynamic processes (the Quasi Biennial Oscillation, QBO; the Arctic Oscillation, AO; the Antarctic Oscillation, AAO; the El Niño Southern Oscillation, ENSO, those due to volcanic aerosol (aerosol optical depth, AOD, tropopause height changes (including global warming and those influences due to anthropogenic contributions to atmospheric chemistry (equivalent effective stratospheric chlorine, EESC. Ozone trends are estimated, with and without removal of proxies, from the total available 1980 to 2015 SBUV record. Except for the chemistry related proxy (EESC and its orthogonal function, the removal of the other proxies does not alter the significance of the estimated long-term trends. At heights above 15 hPa an inflection point between 1997 and 1999 marks the end of significant negative ozone trends, followed by a recent period between 1998 and 2015 with positive ozone trends. At heights between 15 and 40 hPa the pre-1998 negative ozone trends tend to become less significant as we move towards 2015, below which the lower stratosphere ozone decline continues in agreement with findings of recent literature.

Representativeness of single lidar stations for zonally averaged ozone profiles, their trends and attribution to proxies

Science.gov (United States)

Zerefos, Christos; Kapsomenakis, John; Eleftheratos, Kostas; Tourpali, Kleareti; Petropavlovskikh, Irina; Hubert, Daan; Godin-Beekmann, Sophie; Steinbrecht, Wolfgang; Frith, Stacey; Sofieva, Viktoria; Hassler, Birgit

2018-05-01

This paper is focusing on the representativeness of single lidar stations for zonally averaged ozone profile variations over the middle and upper stratosphere. From the lower to the upper stratosphere, ozone profiles from single or grouped lidar stations correlate well with zonal means calculated from the Solar Backscatter Ultraviolet Radiometer (SBUV) satellite overpasses. The best representativeness with significant correlation coefficients is found within ±15° of latitude circles north or south of any lidar station. This paper also includes a multivariate linear regression (MLR) analysis on the relative importance of proxy time series for explaining variations in the vertical ozone profiles. Studied proxies represent variability due to influences outside of the earth system (solar cycle) and within the earth system, i.e. dynamic processes (the Quasi Biennial Oscillation, QBO; the Arctic Oscillation, AO; the Antarctic Oscillation, AAO; the El Niño Southern Oscillation, ENSO), those due to volcanic aerosol (aerosol optical depth, AOD), tropopause height changes (including global warming) and those influences due to anthropogenic contributions to atmospheric chemistry (equivalent effective stratospheric chlorine, EESC). Ozone trends are estimated, with and without removal of proxies, from the total available 1980 to 2015 SBUV record. Except for the chemistry related proxy (EESC) and its orthogonal function, the removal of the other proxies does not alter the significance of the estimated long-term trends. At heights above 15 hPa an inflection point between 1997 and 1999 marks the end of significant negative ozone trends, followed by a recent period between 1998 and 2015 with positive ozone trends. At heights between 15 and 40 hPa the pre-1998 negative ozone trends tend to become less significant as we move towards 2015, below which the lower stratosphere ozone decline continues in agreement with findings of recent literature.

SYNTHESIS OF AUTOMOBILE IGNITION SYSTEM USING OZONIZED FUEL

Directory of Open Access Journals (Sweden)

O. M. Pilipenko

2015-01-01

Full Text Available The paper presents a mathematical model for electronic control system of the angular ignition timing (AIT in the (ICE, which is running on ozonized fuel. An algorithm for  ignition system control of internal combustion engine using ozonized fuel has been developed in the paper. A structure of the dynamic ignition system while using a control unit for supplying  ozone into fuel with a purpose to improve automobile ecological and economical indices adapted to operational conditions. Application of the given system allows to ensure minimum reduction of operational petrol consumption and concentration of incomplete combustion products due to optimum ozone dosage into the fuel.  The paper proposes a controlled automobile ignition system as a sequential scheme which has a great number of discrete inputs and outputs and many discrete internal  states. The scheme establishes a functional dependence between input and output states. The paper provides an assessment of ecological indices according to massive emissions of carbon monoxide СО, hydrocarbon СпНт and nitric oxide NOx .  The analysis of  investigations results has been carried out in the paper.

Nitrogen mediates above-ground effects of ozone but not below-ground effects in a rhizomatous sedge

International Nuclear Information System (INIS)

Jones, M.L.M.; Hodges, G.; Mills, G.

2010-01-01

Ozone and atmospheric nitrogen are co-occurring pollutants with adverse effects on natural grassland vegetation. Plants of the rhizomatous sedge Carex arenaria were exposed to four ozone regimes representing increasing background concentrations (background-peak): 10-30, 35-55, 60-80 and 85-105 ppb ozone at two nitrogen levels: 12 and 100 kg N ha -1 yr -1 . Ozone increased the number and proportion of senesced leaves, but not overall leaf number. There was a clear nitrogen x ozone interaction with high nitrogen reducing proportional senescence in each treatment and increasing the ozone dose (AOT40) at which enhanced senescence occurred. Ozone reduced total biomass due to significant effects on root biomass. There were no interactive effects on shoot:root ratio. Rhizome tissue N content was increased by both nitrogen and ozone. Results suggest that nitrogen mediates above-ground impacts of ozone but not impacts on below-ground resource translocation. This may lead to complex interactive effects between the two pollutants on natural vegetation. - Nitrogen alters threshold of ozone-induced senescence, but not below-ground resource allocation.

Assimilation of stratospheric ozone in the chemical transport model STRATAQ

Directory of Open Access Journals (Sweden)

B. Grassi

2004-09-01

Full Text Available We describe a sequential assimilation approach useful for assimilating tracer measurements into a three-dimensional chemical transport model (CTM of the stratosphere. The numerical code, developed largely according to Kha00, uses parameterizations and simplifications allowing assimilation of sparse observations and the simultaneous evaluation of analysis errors, with reasonable computational requirements. Assimilation parameters are set by using χ2 and OmF (Observation minus Forecast statistics. The CTM used here is a high resolution three-dimensional model. It includes a detailed chemical package and is driven by UKMO (United Kingdom Meteorological Office analyses. We illustrate the method using assimilation of Upper Atmosphere Research Satellite/Microwave Limb Sounder (UARS/MLS ozone observations for three weeks during the 1996 antarctic spring. The comparison of results from the simulations with TOMS (Total Ozone Mapping Spectrometer measurements shows improved total ozone fields due to assimilation of MLS observations. Moreover, the assimilation gives indications on a possible model weakness in reproducing polar ozone values during springtime.

Assimilation of stratospheric ozone in the chemical transport model STRATAQ

Directory of Open Access Journals (Sweden)

B. Grassi

2004-09-01

Full Text Available We describe a sequential assimilation approach useful for assimilating tracer measurements into a three-dimensional chemical transport model (CTM of the stratosphere. The numerical code, developed largely according to Kha00, uses parameterizations and simplifications allowing assimilation of sparse observations and the simultaneous evaluation of analysis errors, with reasonable computational requirements. Assimilation parameters are set by using χ² and OmF (Observation minus Forecast statistics. The CTM used here is a high resolution three-dimensional model. It includes a detailed chemical package and is driven by UKMO (United Kingdom Meteorological Office analyses. We illustrate the method using assimilation of Upper Atmosphere Research Satellite/Microwave Limb Sounder (UARS/MLS ozone observations for three weeks during the 1996 antarctic spring. The comparison of results from the simulations with TOMS (Total Ozone Mapping Spectrometer measurements shows improved total ozone fields due to assimilation of MLS observations. Moreover, the assimilation gives indications on a possible model weakness in reproducing polar ozone values during springtime.

Effect of ozone exposure on maximal airway narrowing in non-asthmatic and asthmatic subjects

NARCIS (Netherlands)

Hiltermann, T J; Stolk, J; Hiemstra, P S; Fokkens, P H; Rombout, P J; Sont, J K; Sterk, P J; Dijkman, J H

1995-01-01

1. Ozone is a major constituent of air pollution in the summer. Epidemiological studies have demonstrated that there is an increase in hospital admissions for respiratory diseases 1 day after peak levels of ambient ozone. This may be due to an increase in the responsiveness of the airways to

Measurement of Ozone Production Sensor

Directory of Open Access Journals (Sweden)

M. Cazorla

2010-05-01

Full Text Available A new ambient air monitor, the Measurement of Ozone Production Sensor (MOPS, measures directly the rate of ozone production in the atmosphere. The sensor consists of two 11.3 L environmental chambers made of UV-transmitting Teflon film, a unit to convert NO₂ to O₃, and a modified ozone monitor. In the sample chamber, flowing ambient air is exposed to the sunlight so that ozone is produced just as it is in the atmosphere. In the second chamber, called the reference chamber, a UV-blocking film over the Teflon film prevents ozone formation but allows other processes to occur as they do in the sample chamber. The air flows that exit the two chambers are sampled by an ozone monitor operating in differential mode so that the difference between the two ozone signals, divided by the exposure time in the chambers, gives the ozone production rate. High-efficiency conversion of NO₂ to O₃ prior to detection in the ozone monitor accounts for differences in the NO_x photostationary state that can occur in the two chambers. The MOPS measures the ozone production rate, but with the addition of NO to the sampled air flow, the MOPS can be used to study the sensitivity of ozone production to NO. Preliminary studies with the MOPS on the campus of the Pennsylvania State University show the potential of this new technique.

The ozone backlash

International Nuclear Information System (INIS)

Taubes, G.

1993-01-01

While evidence for the role of chlorofluorocarbons in ozone depletion grows stronger, researchers have recently been subjected to vocal public criticism of their theories-and their motives. Their understanding of the mechanisms of ozone destruction-especially the annual ozone hole that appears in the Antarctic-has grown stronger, yet everywhere they go these days, they seem to be confronted by critics attacking their theories as baseless. For instance, Rush Limbaugh, the conservative political talk-show host and now-best-selling author of The Way Things Ought to Be, regularly insists that the theory of ozone depletion by CFCs is a hoax: bladerdash and poppycock. Zoologist Dixy Lee Ray, former governor of the state of Washington and former head of the Atomic Energy Commission, makes the same argument in her book, Trashing the Planet. The Wall Street Journal and National Review have run commentaries by S. Fred Singer, a former chief scientists for the Department of Transportation, purporting to shoot holes in the theory of ozone depletion. Even the June issue of Omni, a magazine with a circulation of more than 1 million that publishes a mixture of science and science fiction, printed a feature article claiming to expose ozone research as a politically motivated scam

A Global Ozone Climatology from Ozone Soundings via Trajectory Mapping: A Stratospheric Perspective

Science.gov (United States)

Liu, J. J.; Tarasick, D. W.; Fioletov, V. E.; McLinden, C.; Zhao, T.; Gong, S.; Sioris, G.; Jin, J. J.; Liu, G.; Moeini, O.

2013-01-01

This study explores a domain-filling trajectory approach to generate a global ozone climatology from sparse ozonesonde data. Global ozone soundings of 51,898 profiles at 116 stations over 44 years (1965-2008) are used, from which forward and backward trajectories are performed for 4 days, driven by a set of meteorological reanalysis data. Ozone mixing ratios of each sounding from the surface to 26 km altitude are assigned to the entire path along the trajectory. The resulting global ozone climatology is archived monthly for five decades from the 1960s to the 2000s with grids of 5 degree 5 degree 1 km (latitude, longitude, and altitude). It is also archived yearly from 1965 to 2008. This climatology is validated at 20 ozonesonde stations by comparing the actual ozone sounding profile with that found through the trajectories, using the ozone soundings at all the stations except one being tested. The two sets of profiles are in good agreement, both individually with correlation coefficients between 0.975 and 0.998 and root mean square (RMS) differences of 87 to 482 ppbv, and overall with a correlation coefficient of 0.991 and an RMS of 224 ppbv. The ozone climatology is also compared with two sets of satellite data, from the Satellite Aerosol and Gas Experiment (SAGE) and the Optical Spectrography and InfraRed Imager System (OSIRIS). Overall, the ozone climatology compares well with SAGE and OSIRIS data by both seasonal and zonal means. The mean difference is generally under 20 above 15 km. The comparison is better in the northern hemisphere, where there are more ozonesonde stations, than in the southern hemisphere; it is also better in the middle and high latitudes than in the tropics, where assimilated winds are imperfect in some regions. This ozone climatology can capture known features in the stratosphere, as well as seasonal and decadal variations of these features. Furthermore, it provides a wealth of detail about longitudinal variations in the stratosphere such

A Compact Mobile Ozone Lidar for Atmospheric Ozone and Aerosol Profiling

Science.gov (United States)

De Young, Russell; Carrion, William; Pliutau, Denis

2014-01-01

A compact mobile differential absorption lidar (DIAL) system has been developed at NASA Langley Research Center to provide ozone, aerosol and cloud atmospheric measurements in a mobile trailer for ground-based atmospheric ozone air quality campaigns. This lidar is integrated into the Tropospheric Ozone Lidar Network (TOLNet) currently made up of four other ozone lidars across the country. The lidar system consists of a UV and green laser transmitter, a telescope and an optical signal receiver with associated Licel photon counting and analog channels. The laser transmitter consist of a Q-switched Nd:YLF inter-cavity doubled laser pumping a Ce:LiCAF tunable UV laser with all the associated power and lidar control support units on a single system rack. The system has been configured to enable mobile operation from a trailer and was deployed to Denver, CO July 15-August 15, 2014 supporting the DISCOVER-AQ campaign. Ozone curtain plots and the resulting science are presented.

Catalytic ozonation of fenofibric acid over alumina-supported manganese oxide

Energy Technology Data Exchange (ETDEWEB)

Rosal, Roberto, E-mail: roberto.rosal@uah.es [Departamento de Quimica Analitica e Ingenieria Quimica, Universidad de Alcala, E-28771 Alcala de Henares (Spain); Gonzalo, Maria S.; Rodriguez, Antonio; Garcia-Calvo, Eloy [Departamento de Quimica Analitica e Ingenieria Quimica, Universidad de Alcala, E-28771 Alcala de Henares (Spain)

2010-11-15

The catalytic ozonation of fenofibric acid was studied using activated alumina and alumina-supported manganese oxide in a semicontinuous reactor. The rate constants at 20 deg. C for the non-catalytic reaction of fenofibric acid with ozone and hydroxyl radicals were 3.43 {+-} 0.20 M{sup -1} s{sup -1} and (6.55 {+-} 0.33) x 10{sup 9} M{sup -1} s{sup -1}, respectively. The kinetic constant for the catalytic reaction between fenofibric acid and hydroxyl radicals did not differ significantly from that of homogeneous ozonation, either using Al{sub 2}O{sub 3} or MnO{sub x}/Al{sub 2}O{sub 3}. The results showed a considerable increase in the generation of hydroxyl radicals due to the use of catalysts even in the case of catalytic runs performed using a real wastewater matrix. Both catalysts promoted the decomposition of ozone in homogeneous phase, but the higher production of hydroxyl radicals corresponded to the catalyst with more activity in terms of ozone decomposition. We did not find evidence of the catalysts having any effect on rate constants, which suggests that the reaction may not involve the adsorption of organics on catalyst surface.

Atmospheric Ozone and Methane in a Changing Climate

Directory of Open Access Journals (Sweden)

Ivar S. A. Isaksen

2014-07-01

Full Text Available Ozone and methane are chemically active climate-forcing agents affected by climate–chemistry interactions in the atmosphere. Key chemical reactions and processes affecting ozone and methane are presented. It is shown that climate-chemistry interactions have a significant impact on the two compounds. Ozone, which is a secondary compound in the atmosphere, produced and broken down mainly in the troposphere and stratosphre through chemical reactions involving atomic oxygen (O, NOx compounds (NO, NO2, CO, hydrogen radicals (OH, HO2, volatile organic compounds (VOC and chlorine (Cl, ClO and bromine (Br, BrO. Ozone is broken down through changes in the atmospheric distribution of the afore mentioned compounds. Methane is a primary compound emitted from different sources (wetlands, rice production, livestock, mining, oil and gas production and landfills.Methane is broken down by the hydroxyl radical (OH. OH is significantly affected by methane emissions, defined by the feedback factor, currently estimated to be in the range 1.3 to 1.5, and increasing with increasing methane emission. Ozone and methane changes are affected by NOx emissions. While ozone in general increase with increases in NOx emission, methane is reduced, due to increases in OH. Several processes where current and future changes have implications for climate-chemistry interactions are identified. It is also shown that climatic changes through dynamic processes could have significant impact on the atmospheric chemical distribution of ozone and methane, as we can see through the impact of Quasi Biennial Oscillation (QBO. Modeling studies indicate that increases in ozone could be more pronounced toward the end of this century. Thawing permafrost could lead to important positive feedbacks in the climate system. Large amounts of organic material are stored in the upper layers of the permafrost in the yedoma deposits in Siberia, where 2 to 5% of the deposits could be organic material

A Two-Timescale Response to Ozone Depletion: Importance of the Background State

Science.gov (United States)

Seviour, W.; Waugh, D.; Gnanadesikan, A.

2015-12-01

It has been recently suggested that the response of Southern Ocean sea-ice extent to stratospheric ozone depletion is time-dependent; that the ocean surface initially cools due to enhanced northward Ekman drift caused by a poleward shift in the eddy-driven jet, and then warms after some time due to upwelling of warm waters from below the mixed layer. It is therefore possible that ozone depletion could act to favor a short-term increase in sea-ice extent. However, many uncertainties remain in understanding this mechanism, with different models showing widely differing time-scales and magnitudes of the response. Here, we analyze an ensemble of coupled model simulations with a step-function ozone perturbation. The two-timescale response is present with an approximately 30 year initial cooling period. The response is further shown to be highly dependent upon the background ocean temperature and salinity stratification, which is influenced by both natural internal variability and the isopycnal eddy mixing parameterization. It is suggested that the majority of inter-model differences in the Southern Ocean response to ozone depletion is caused by differences in stratification.

Generation of ozone and safety aspects in an accelerator facility of BARC

International Nuclear Information System (INIS)

Dubey, Praveen; Sawatkar, Aparna R.; Sathe, Arun P.; Soundararajan, S.; Sarma, K.S.S.

2009-01-01

Industrial electron beam accelerators up to 10 MeV are commonly employed for different applications. During normal operation of an accelerator, the principal hazard is the high radiation level produced. Experiments and applications in which the electron beam is used to irradiate materials outside the accelerator vacuum system are associated with problems such as radiation damage and production of considerable quantities of ozone. The possible generation of ozone during the operation of an electron beam accelerator is of special interest due to reactivity, corrosivity and the toxic characteristics of ozone. Industrial hygiene surveys were conducted to estimate the airborne concentration of ozone during operations of the electron beam accelerator (Type: ILU-6; 2 MeV; 20 KW) at varied operating parameters. The ozone concentration in the accelerator room was measured at different powers of the accelerator and the ozone decay pattern was also observed after beam shut down. Ozone in the accelerator room was measured by different methods such as colorimetry using neutral buffered potassium iodide, chemiluminescence method using ethylene and by using electrochemical sensor. An air velocity meter was used to measure the linear air velocity across the exhaust grills and the number of air changes available in the accelerator room was calculated. Necessary control measures were suggested to keep the occupational exposure of the personnel to ozone concentrations well within the Threshold Limit Values. (author)

Evaluation of Global Ozone Monitoring Experiment (GOME) ozone profiles from nine different algorithms

NARCIS (Netherlands)

Meijer, Y.J.; Swart, D.P.J.; Baier, F.; Bhartia, P.K.; Bodeker, G.E.; Casadio, S.; Chance, K.; Frate, Del F.; Erbertseder, T.; Felder, M.D.; Flynn, L.E.; Godin-Beekmann, S.; Hansen, G.; Hasekamp, O.P.; Kaifel, A.; Kelder, H.M.; Kerridge, B.J.; Lambert, J.-C.; Landgraf, J.; Latter, B.G.; Liu, X.; McDermid, I.S.; Pachepsky, Y.; Rozanov, V.; Siddans, R.; Tellmann, S.; A, van der R.J.; Oss, van R.F.; Weber, M.; Zehner, C.

2006-01-01

An evaluation is made of ozone profiles retrieved from measurements of the nadir-viewing Global Ozone Monitoring Experiment (GOME) instrument. Currently, four different approaches are used to retrieve ozone profile information from GOME measurements, which differ in the use of external information

Evaluating A Priori Ozone Profile Information Used in TEMPO Tropospheric Ozone Retrievals

Science.gov (United States)

Johnson, Matthew S.; Sullivan, John T.; Liu, Xiong; Newchurch, Mike; Kuang, Shi; McGee, Thomas J.; Langford, Andrew O'Neil; Senff, Christoph J.; Leblanc, Thierry; Berkoff, Timothy;

Evaluating A Priori Ozone Profile Information Used in TEMPO Tropospheric Ozone Retrievals

Science.gov (United States)

Johnson, M. S.; Sullivan, J. T.; Liu, X.; Newchurch, M.; Kuang, S.; McGee, T. J.; Langford, A. O.; Senff, C. J.; Leblanc, T.; Berkoff, T.; Gronoff, G.; Chen, G.; Strawbridge, K. B.

2016-12-01

Ozone (O3) is a greenhouse gas and toxic pollutant which plays a major role in air quality. Typically, monitoring of surface air quality and O3 mixing ratios is primarily conducted using in situ measurement networks. This is partially due to high-quality information related to air quality being limited from space-borne platforms due to coarse spatial resolution, limited temporal frequency, and minimal sensitivity to lower tropospheric and surface-level O3. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite is designed to address these limitations of current space-based platforms and to improve our ability to monitor North American air quality. TEMPO will provide hourly data of total column and vertical profiles of O3 with high spatial resolution to be used as a near-real-time air quality product. TEMPO O3 retrievals will apply the Smithsonian Astrophysical Observatory profile algorithm developed based on work from GOME, GOME-2, and OMI. This algorithm uses a priori O3 profile information from a climatological data-base developed from long-term ozone-sonde measurements (tropopause-based (TB) O3 climatology). It has been shown that satellite O3 retrievals are sensitive to a priori O3 profiles and covariance matrices. During this work we investigate the climatological data to be used in TEMPO algorithms (TB O3) and simulated data from the NASA GMAO Goddard Earth Observing System (GEOS-5) Forward Processing (FP) near-real-time (NRT) model products. These two data products will be evaluated with ground-based lidar data from the Tropospheric Ozone Lidar Network (TOLNet) at various locations of the US. This study evaluates the TB climatology, GEOS-5 climatology, and 3-hourly GEOS-5 data compared to lower tropospheric observations to demonstrate the accuracy of a priori information to potentially be used in TEMPO O3 algorithms. Here we present our initial analysis and the theoretical impact on TEMPO retrievals in the lower troposphere.

Ozone: The secret greenhouse gas

International Nuclear Information System (INIS)

Berntsen, Terje; Tjernshaugen, Andreas

2001-01-01

The atmospheric ozone not only protects against harmful ultraviolet radiation; it also contributes to the greenhouse effect. Ozone is one of the jokers to make it difficult to calculate the climatic effect of anthropogenic emissions. The greenhouse effect and the ozone layer should not be confused. The greenhouse effect creates problems when it becomes enhanced, so that the earth becomes warmer. The problem with the ozone layer, on the contrary, is that it becomes thinner and so more of the harmful ultraviolet radiation gets through to the earth. However, ozone is also a greenhouse gas and so the greenhouse effect and the ozone layer are connected

New dynamic NNORSY ozone profile climatology

Science.gov (United States)

Kaifel, A. K.; Felder, M.; Declercq, C.; Lambert, J.-C.

2012-01-01

Climatological ozone profile data are widely used as a-priori information for total ozone using DOAS type retrievals as well as for ozone profile retrieval using optimal estimation, for data assimilation or evaluation of 3-D chemistry-transport models and a lot of other applications in atmospheric sciences and remote sensing. For most applications it is important that the climatology represents not only long term mean values but also the links between ozone and dynamic input parameters. These dynamic input parameters should be easily accessible from auxiliary datasets or easily measureable, and obviously should have a high correlation with ozone. For ozone profile these parameters are mainly total ozone column and temperature profile data. This was the outcome of a user consultation carried out in the framework of developing a new, dynamic ozone profile climatology. The new ozone profile climatology is based on the Neural Network Ozone Retrieval System (NNORSY) widely used for ozone profile retrieval from UV and IR satellite sounder data. NNORSY allows implicit modelling of any non-linear correspondence between input parameters (predictors) and ozone profile target vector. This paper presents the approach, setup and validation of a new family of ozone profile climatologies with static as well as dynamic input parameters (total ozone and temperature profile). The neural network training relies on ozone profile measurement data of well known quality provided by ground based (ozonesondes) and satellite based (SAGE II, HALOE, and POAM-III) measurements over the years 1995-2007. In total, four different combinations (modes) for input parameters (date, geolocation, total ozone column and temperature profile) are available. The geophysical validation spans from pole to pole using independent ozonesonde, lidar and satellite data (ACE-FTS, AURA-MLS) for individual and time series comparisons as well as for analysing the vertical and meridian structure of different modes of

Ozone therapy in periodontics.

Science.gov (United States)

Gupta, G; Mansi, B

2012-02-22

Gingival and Periodontal diseases represent a major concern both in dentistry and medicine. The majority of the contributing factors and causes in the etiology of these diseases are reduced or treated with ozone in all its application forms (gas, water, oil). The beneficial biological effects of ozone, its anti-microbial activity, oxidation of bio-molecules precursors and microbial toxins implicated in periodontal diseases and its healing and tissue regeneration properties, make the use of ozone well indicated in all stages of gingival and periodontal diseases. The primary objective of this article is to provide a general review about the clinical applications of ozone in periodontics. The secondary objective is to summarize the available in vitro and in vivo studies in Periodontics in which ozone has been used. This objective would be of importance to future researchers in terms of what has been tried and what the potentials are for the clinical application of ozone in Periodontics.

OZONE ABSORPTION IN RAW WATERS

Directory of Open Access Journals (Sweden)

LJILJANA TAKIĆ

2008-03-01

Full Text Available The ozone absorption in raw water entering the main ozonization step at the Belgrade drinking water supply plant was investigated in a continuous stirred tank reactor (CSTR. A slow chemical reaction rate of dissolved ozone and pollutants present in raw water have been experimentally determined. The modified Hatta number was defined and calculated as a criterion which determines whether and to which extent the reactions of ozone and pollutants influence the rate of the pure physical ozone absorption.

Role of anti-thrombotic therapy for recurrent pregnancy loss due to anti-phospholipid syndrome

International Nuclear Information System (INIS)

Fawad, S.

2010-01-01

Background: Recurrent pregnancy loss is a major health problem effecting 1 to 2% of women of reproductive age. Its causes range from chromosomal abnormalities to endocrinological factors and thrombophilia related factors. Treating thrombophilia s especially anti phospholipid syndrome with low dose aspirin and low molecular weight heparin improves foetal outcome. This study will add local data to already existing knowledge. Method: Sixty selected patients from gynaecology OPD of Aero Hospital with clinical and/or serological findings of anti phospholipid syndrome from February 2009 to January 2011 were given aspirin 75 mg once daily and enoxaparine 40 mg subcutaneously once daily from 6 - 8 weeks to 35 and 37 weeks respectively. Results : Ninety-three percent of patients achieved live birth. Out of these 75% patients delivered at term and 18% had preterm delivered. Four (7%) had early pregnancy loss and only one had early neonatal death due to extreme prematurity. None of patients experienced any major hemorrhagic complications . Conclusion: Use of low dose aspirin and low molecular weight heparin is safe in pregnancy and improve foetal outcome in patients with recurrent pregnancy loss due to anti phospholipids syndrome. (author)

Influence of pitch, twist, and taper on a blade`s performance loss due to roughness

Energy Technology Data Exchange (ETDEWEB)

Tangler, J.L. [National Renewable Energy Lab., Golden, CO (United States)

1996-12-31

The purpose of this study was to determine the influence of blade geometric parameters such as pitch, twist, and taper on a blade`s sensitivity to leading edge roughness. The approach began with an evaluation of available test data of performance degradation due to roughness effects for several rotors. In addition to airfoil geometry, this evaluation suggested that a rotor`s sensitivity to roughness was also influenced by the blade geometric parameters. Parametric studies were conducted using the PROP computer code with wind-tunnel airfoil characteristics for smooth and rough surface conditions to quantify the performance loss due to roughness for tapered and twisted blades relative to a constant-chord, non-twisted blade at several blade pitch angles. The results indicate that a constant-chord, non-twisted blade pitched toward stall will have the greatest losses due to roughness. The use of twist, taper, and positive blade pitch angles all help reduce the angle-of-attack distribution along the blade for a given wind speed and the associated performance degradation due to roughness. 8 refs., 6 figs.

Influence of pitch, twist, and taper on a blade`s performance loss due to roughness

Energy Technology Data Exchange (ETDEWEB)

Tangler, J.L. [National Renewable Energy Laboratory, Golden, Colorado (United States)

1997-08-01

The purpose of this study was to determine the influence of blade geometric parameters such as pitch, twist, and taper on a blade`s sensitivity to leading edge roughness. The approach began with an evaluation of available test data of performance degradation due to roughness effects for several rotors. In addition to airfoil geometry, this evaluation suggested that a rotor`s sensitivity to roughness was also influenced by the blade geometric parameters. Parametric studies were conducted using the PROP computer code with wind-tunnel airfoil characteristics for smooth and rough surface conditions to quantify the performance loss due to roughness for tapered and twisted blades relative to a constant-chord, non-twisted blade at several blade pitch angles. The results indicate that a constant-chord, non-twisted blade pitched toward stall will have the greatest losses due to roughness. The use of twist, taper, and positive blade pitch angles all help reduce the angle-of-attack distribution along the blade for a given wind speed and the associated performance degradation due to roughness. (au)

Scenarios for future biodiversity loss due to multiple drivers reveal conflict between mitigating climate change and preserving biodiversity

International Nuclear Information System (INIS)

Powell, Thomas W R; Lenton, Timothy M

2013-01-01

We assess the potential for future biodiversity loss due to three interacting factors: energy withdrawal from ecosystems due to biomass harvest, habitat loss due to land-use change, and climate change. We develop four scenarios to 2050 with different combinations of high or low agricultural efficiency and high or low meat diets, and use species–energy and species–area relationships to estimate their effects on biodiversity. In our scenarios, natural ecosystems are protected except when additional land is necessary to fulfil the increasing dietary demands of the global population. Biomass energy with carbon capture and storage (BECCS) is used as a means of carbon dioxide removal (CDR) from the atmosphere (and offsetting fossil fuel emissions). BECCS is based on waste biomass, with the addition of bio-energy crops only when already managed land is no longer needed for food production. Forecast biodiversity loss from natural biomes increases by more than a factor of five in going from high to low agricultural efficiency scenarios, due to destruction of productive habitats by the expansion of pasture. Biodiversity loss from energy withdrawal on managed land varies by a factor of two across the scenarios. Biodiversity loss due to climate change varies only modestly across the scenarios. Climate change is lowest in the ‘low meat high efficiency’ scenario, in which by 2050 around 660 million hectares of pasture are converted to biomass plantation that is used for BECCS. However, the resulting withdrawal of energy from managed ecosystems has a large negative impact on biodiversity. Although the effects of energy withdrawal and climate change on biodiversity cannot be directly compared, this suggests that using bio-energy to tackle climate change in order to limit biodiversity loss could instead have the opposite effect. (letter)

Effect of pulsed corona discharge voltage and feed gas flow rate on dissolved ozone concentration

International Nuclear Information System (INIS)

Prasetyaningrum, A.; Ratnawati,; Jos, B.

2015-01-01

Ozonization is one of the methods extensively used for water purification and degradation of organic materials. Ozone (O 3 ) is recognized as a powerful oxidizing agent. Due to its strong oxidability and better environmental friendless, ozone increasing being used in domestic and industrial applications. Current technology in ozone production utilizes several techniques (corona discharge, ultra violet radiation and electrolysis). This experiment aimed to evaluating effect of voltage and gas flow rate on ozone production with corona discharge. The system consists of two net-type stainless steel electrode placed in a dielectric barrier. Three pulsed voltage (20, 30, 40 KV) and flow rate (5, 10, 15 L/min) were prepare for operation variable at high frequency (3.7 kHz) with AC pulsed power supply. The dissolved ozone concentration depends on the applied high-voltage level, gas flow rate and the discharge exposure duration. The ozone concentration increases with decreasing gas flow rate. Dissolved ozone concentrations greater than 200 ppm can be obtained with a minimum voltage 40 kV

Effect of pulsed corona discharge voltage and feed gas flow rate on dissolved ozone concentration

Science.gov (United States)

Prasetyaningrum, A.; Ratnawati, Jos, B.

2015-12-01

Ozonization is one of the methods extensively used for water purification and degradation of organic materials. Ozone (O3) is recognized as a powerful oxidizing agent. Due to its strong oxidability and better environmental friendless, ozone increasing being used in domestic and industrial applications. Current technology in ozone production utilizes several techniques (corona discharge, ultra violet radiation and electrolysis). This experiment aimed to evaluating effect of voltage and gas flow rate on ozone production with corona discharge. The system consists of two net-type stainless steel electrode placed in a dielectric barrier. Three pulsed voltage (20, 30, 40 KV) and flow rate (5, 10, 15 L/min) were prepare for operation variable at high frequency (3.7 kHz) with AC pulsed power supply. The dissolved ozone concentration depends on the applied high-voltage level, gas flow rate and the discharge exposure duration. The ozone concentration increases with decreasing gas flow rate. Dissolved ozone concentrations greater than 200 ppm can be obtained with a minimum voltage 40 kV.

Effect of pulsed corona discharge voltage and feed gas flow rate on dissolved ozone concentration

Energy Technology Data Exchange (ETDEWEB)

Prasetyaningrum, A., E-mail: ajiprasetyaningrum@gmail.com; Ratnawati,; Jos, B. [Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Jl. Prof. H. Soedarto Tembalang, Semarang, Central Java, Indonesia, 50276 (Indonesia)

2015-12-29

Ozonization is one of the methods extensively used for water purification and degradation of organic materials. Ozone (O{sub 3}) is recognized as a powerful oxidizing agent. Due to its strong oxidability and better environmental friendless, ozone increasing being used in domestic and industrial applications. Current technology in ozone production utilizes several techniques (corona discharge, ultra violet radiation and electrolysis). This experiment aimed to evaluating effect of voltage and gas flow rate on ozone production with corona discharge. The system consists of two net-type stainless steel electrode placed in a dielectric barrier. Three pulsed voltage (20, 30, 40 KV) and flow rate (5, 10, 15 L/min) were prepare for operation variable at high frequency (3.7 kHz) with AC pulsed power supply. The dissolved ozone concentration depends on the applied high-voltage level, gas flow rate and the discharge exposure duration. The ozone concentration increases with decreasing gas flow rate. Dissolved ozone concentrations greater than 200 ppm can be obtained with a minimum voltage 40 kV.

Percutaneous intradiscal ozone (O3)-injection: an experimental study in canines

International Nuclear Information System (INIS)

Yu Zhijian; He Xiaofeng; Chen Yong; Zeng Qingle; Liu Chihong; Zhao Zhongqing; Lu Yong; Li Yanhao

2002-01-01

Objective: To evaluate the influence of ozone on normal nucleus pulpous and the safety of intradiscal ozone-injection for the treatment of herniated lumbar disc. Methods: Ozone was injected into selected lumbar discs (3 ml) and the para-spinal space (7 ml) with 20 G Chiba needle under fluoroscopy in five canines. The ozone concentration was 30 μg/ml and 50 μg/ml respectively. Two discs were selected for each concentration. Total 20 discs were injected. Three of the canines were given one-time ozone-injection and were sacrificed for pathology one week, one month and two months respectively after the procedure, and the other two canines were given two-time ozone-injection and were sacrificed one month and two months respectively after the procedure. The specimens including nucleus pulpous, end-plate, spinal cord, nerve root, and greater psoas muscle were observed macroscopically and microscopically. Results: No serious behavior abnormalities were observed in all animals. The atrophy of nucleus pulpous could be observed one month after ozone-injection due to significant reduction of water and extensive proliferation of collagenous fiber. The influence on the atrophy of nucleus pulpous demonstrated no apparent difference between the selected two concentrations of ozone, but was more apparent with two-time injection than that with one-time injection. The end-plates increased slightly or moderately in thickness in 16 simples and a few of fibers in greater psoas muscle suffered slight atrophy in 5 samples. Conclusion: It is suggested that percutaneous intradiscal ozone-injection is a safe method, and can cause gradual atrophy of nucleus pulpous. This study provides the evidence of the feasibility and value of this procedure's application in clinics

Characterising the three-dimensional ozone distribution of a tidally locked Earth-like planet

Science.gov (United States)

Proedrou, Elisavet; Hocke, Klemens

2016-06-01

We simulate the 3D ozone distribution of a tidally locked Earth-like exoplanet using the high-resolution, 3D chemistry-climate model CESM1(WACCM) and study how the ozone layer of a tidally locked Earth (TLE) (Ω _{TLE}= 1/365 days) differs from that of our present-day Earth (PDE) (Ω _{PDE}= 1/1 day). The middle atmosphere reaches a steady state asymptotically within the first 80 days of the simulation. An upwelling, centred on the subsolar point, is present on the day side while a downwelling, centred on the antisolar point, is present on the night side. In the mesosphere, we find similar global ozone distributions for the TLE and the PDE, with decreased ozone on the day side and enhanced ozone on the night side. In the lower mesosphere, a jet stream transitions into a large-scale vortex around a low-pressure system, located at low latitudes of the TLE night side. In the middle stratosphere, the concentration of odd oxygen is approximately equal to that of the ozone [({O}x) ≈ ({O}3)]. At these altitudes, the lifetime of odd oxygen is ˜16 h and the transport processes significantly contribute to the global distribution of stratospheric ozone. Compared to the PDE, where the strong Coriolis force acts as a mixing barrier between low and high latitudes, the transport processes of the TLE are governed by jet streams variable in the zonal and meridional directions. In the middle stratosphere of the TLE, we find high ozone values on the day side, due to the increased production of atomic oxygen on the day side, where it immediately recombines with molecular oxygen to form ozone. In contrast, the ozone is depleted on the night side, due to changes in the solar radiation distribution and the presence of a downwelling. As a result of the reduced Coriolis force, the tropical and extratropical air masses are well mixed and the global temperature distribution of the TLE stratosphere has smaller horizontal gradients than the PDE. Compared to the PDE, the total ozone column

Infrared radiation models for atmospheric ozone

Science.gov (United States)

Kratz, David P.; Ces, Robert D.

1988-01-01

A hierarchy of line-by-line, narrow-band, and broadband infrared radiation models are discussed for ozone, a radiatively important atmospheric trace gas. It is shown that the narrow-band (Malkmus) model is in near-precise agreement with the line-by-line model, thus providing a means of testing narrow-band Curtis-Godson scaling, and it is found that this scaling procedure leads to errors in atmospheric fluxes of up to 10 percent. Moreover, this is a direct consequence of the altitude dependence of the ozone mixing ratio. Somewhat greater flux errors arise with use of the broadband model, due to both a lesser accuracy of the broadband scaling procedure and to inherent errors within the broadband model, despite the fact that this model has been tuned to the line-by-line model.

Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park.

Science.gov (United States)

Souza, Lara; Neufeld, Howard S; Chappelka, Arthur H; Burkey, Kent O; Davison, Alan W

2006-05-01

The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts and individual tall milkweeds (Asclepias exaltata L.) in Great Smoky Mountains National Park. Plants were classified as either ozone-sensitive or insensitive based on the amount of foliar injury. Sensitive plants developed injury earlier in the season and to a greater extent than insensitive plants. Older leaf cohorts were more likely to belong to high injury classes by the end of each of the two growing seasons. In addition, leaf loss was more likely for older cohorts (2000) and lower leaf positions (2001) than younger cohorts and upper leaves, respectively. Most leaves abscised without prior ozone-like stippling or chlorosis. Failure to take this into account can result in underestimation of the effects of ozone on these plants.

Proposed standardized definitions for vertical resolution and uncertainty in the NDACC lidar ozone and temperature algorithms - Part 2: Ozone DIAL uncertainty budget

Science.gov (United States)

Leblanc, Thierry; Sica, Robert J.; van Gijsel, Joanna A. E.; Godin-Beekmann, Sophie; Haefele, Alexander; Trickl, Thomas; Payen, Guillaume; Liberti, Gianluigi

2016-08-01

A standardized approach for the definition, propagation, and reporting of uncertainty in the ozone differential absorption lidar data products contributing to the Network for the Detection for Atmospheric Composition Change (NDACC) database is proposed. One essential aspect of the proposed approach is the propagation in parallel of all independent uncertainty components through the data processing chain before they are combined together to form the ozone combined standard uncertainty. The independent uncertainty components contributing to the overall budget include random noise associated with signal detection, uncertainty due to saturation correction, background noise extraction, the absorption cross sections of O3, NO2, SO2, and O2, the molecular extinction cross sections, and the number densities of the air, NO2, and SO2. The expression of the individual uncertainty components and their step-by-step propagation through the ozone differential absorption lidar (DIAL) processing chain are thoroughly estimated. All sources of uncertainty except detection noise imply correlated terms in the vertical dimension, which requires knowledge of the covariance matrix when the lidar signal is vertically filtered. In addition, the covariance terms must be taken into account if the same detection hardware is shared by the lidar receiver channels at the absorbed and non-absorbed wavelengths. The ozone uncertainty budget is presented as much as possible in a generic form (i.e., as a function of instrument performance and wavelength) so that all NDACC ozone DIAL investigators across the network can estimate, for their own instrument and in a straightforward manner, the expected impact of each reviewed uncertainty component. In addition, two actual examples of full uncertainty budget are provided, using nighttime measurements from the tropospheric ozone DIAL located at the Jet Propulsion Laboratory (JPL) Table Mountain Facility, California, and nighttime measurements from the JPL

Ozone and radon at Cape Grim: A study of their interdependence

International Nuclear Information System (INIS)

Zahorowski, W.; Galbally, I.E.; Meyer, C.P.

1996-01-01

A discussion of the ozone and radon variations at Cape Grim, Tasmania, and their interdependence is presented. The use of radon concentration as a criterion for baseline conditions ( - 3) results in a baseline data set that has a smaller range of concentrations within each month than that obtained using wind speed and direction as baseline criteria. The passage of cold fronts at Cape Grim is associated with a change in air flow from the continent to the Southern Ocean. Comparison of radon, wind direction and ozone during these events indicates that continental air continues arriving at Cape Grim for several hours after passage of the front and the establishment of the air flow from the baseline sector. This confirms that use of the speed and direction is not necessarily a good method of defining baseline conditions for ozone. When air comes to Cape Grim form over the Tasmanian land surface during those times of the year when (due to solar radiation and temperature) the probability of ozone production is low, the ozone and radon concentrations observed are negatively correlated. A simple model of ozone destruction at the Earth's surface and radon emission from the surface quantitatively describes these observations. (author). 1 tab., 5 figs., 6 refs

Now you see it, now you don't: The ozone hole

International Nuclear Information System (INIS)

Wilkniss, P.E.

1990-01-01

Fragile, rainbow-colored clouds high in the antarctic sky are a beautiful but onerous reminder that all is not well in the universe. To the trained scientist, the clouds foretell the destruction of Antarctic ozone - a gas that protects the Earth from the sun's destructive ultraviolet rays. The author describes the scene while telling of the Dr. Jekyll/Mr. Hyde role that ozone plays in the environment. In the lower atmosphere, ozone is a nasty pollutant. In the upper atmosphere, it shields the Earth's surface from unwanted ultraviolet radiation. A bombshell was dropped in 1985 by the discovery of a large hole in the ozone layer in the upper atmosphere over the entire expanse of Antarctica. The hole later confirmed in other studies, has been appearing each spring and disappearing each summer since 1975. The mass of scientific evidence leaves no doubt that chlorine from chlorofluorocarbons (CFCs) is responsible for destroying the ozone. He predicts the hole will remain for 50 to 100 years, even if the world were to stop releasing CFCs now, although the size of the hole will wax and wane. Increased ultraviolet radiation resulting from the ozone depletion will cause an increase in skin cancer, cataracts, and infection due to weakened immune systems

Observation of stratospheric ozone with NIES lidar system in Tsukuba, Japan

International Nuclear Information System (INIS)

Nakane, H.; Hayashida, S.; Sasano, Y.; Sugimoto, N.; Matsui, I.; Minato, A.

1992-01-01

Lidars are expected to play important roles in an international monitoring network of the stratosphere such as the Network for the Detection of Stratospheric Change (NDSC). The National Institute for Environmental Studies (NIES) in Tsukuba constructed an ozone lidar system in March 1988 and started observation in August 1988. The lidar system has a 2-m telescope and injection locked XeCl and XeF excimer lasers which can measure ozone profiles (15-45 km) and temperature profiles (30-80 km). From December 1991, lidar observations have been carried out in which the second Stokes line of the stimulated Raman scattering of a KrF laser has been used. Ozone profiles obtained with the NIES lidar system are compared with the data provided by the SAGE II satellite sensor. Results showed good agreement for the individual and the zonal mean profiles. Variations of ozone with various time scales at each altitude can be studied using the data obtained with the NIES ozone lidar system. Seasonal variations are easily found at 20 km, 30 km, and 35 km, which are qualitatively understood as a result of dynamical and photochemical effects. Systematic errors of ozone profiles due to the Pinatubo stratospheric aerosols have been detected using multi-wavelength observation

Evaluation of ozone profile and tropospheric ozone retrievals from GEMS and OMI spectra

Directory of Open Access Journals (Sweden)

J. Bak

2013-02-01

Full Text Available South Korea is planning to launch the GEMS (Geostationary Environment Monitoring Spectrometer instrument into the GeoKOMPSAT (Geostationary Korea Multi-Purpose SATellite platform in 2018 to monitor tropospheric air pollutants on an hourly basis over East Asia. GEMS will measure backscattered UV radiances covering the 300–500 nm wavelength range with a spectral resolution of 0.6 nm. The main objective of this study is to evaluate ozone profiles and stratospheric column ozone amounts retrieved from simulated GEMS measurements. Ozone Monitoring Instrument (OMI Level 1B radiances, which have the spectral range 270–500 nm at spectral resolution of 0.42–0.63 nm, are used to simulate the GEMS radiances. An optimal estimation-based ozone profile algorithm is used to retrieve ozone profiles from simulated GEMS radiances. Firstly, we compare the retrieval characteristics (including averaging kernels, degrees of freedom for signal, and retrieval error derived from the 270–330 nm (OMI and 300–330 nm (GEMS wavelength ranges. This comparison shows that the effect of not using measurements below 300 nm on retrieval characteristics in the troposphere is insignificant. However, the stratospheric ozone information in terms of DFS decreases greatly from OMI to GEMS, by a factor of ∼2. The number of the independent pieces of information available from GEMS measurements is estimated to 3 on average in the stratosphere, with associated retrieval errors of ~1% in stratospheric column ozone. The difference between OMI and GEMS retrieval characteristics is apparent for retrieving ozone layers above ~20 km, with a reduction in the sensitivity and an increase in the retrieval errors for GEMS. We further investigate whether GEMS can resolve the stratospheric ozone variation observed from high vertical resolution Earth Observing System (EOS Microwave Limb Sounder (MLS. The differences in stratospheric ozone profiles between GEMS and MLS are comparable to those

Managing for No Net Loss of Ecological Services: An Approach for Quantifying Loss of Coastal Wetlands due to Sea Level Rise.