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Sample records for oxide fuels irradiated

  1. Irradiation behavior of uranium oxide - Aluminum dispersion fuel

    International Nuclear Information System (INIS)

    Hofman, Gerard L.; Rest, Jeffrey; Snelgrove, James L.

    1996-01-01

    An oxide version of the DART code has been generated in order to assess the irradiation behavior of UO 2 -Al dispersion fuel. The aluminum-fuel interaction models were developed based on U 3 O 8 -Al irradiation data. Deformation of the fuel element occurs due to fuel particle swelling driven by both solid and gaseous fission products and as a consequence of the interaction between the fuel particles and the aluminum matrix. The calculations show that, with the assumption that the correlations derived from U 3 O 8 are valid for UO 2 , the LEU UO 2 -Al with a 42% fuel volume loading (4 g U/cm 3 ) irradiated at fuel temperatures greater than 413 K should undergo breakaway swelling at core burnups greater than about 1.12 x 10 27 fissions m -3 (∼63% 235 U burnup). (author)

  2. Irradiation behavior of uranium oxide-aluminum dispersion fuel

    International Nuclear Information System (INIS)

    Hofman, G.L.; Rest, J.; Snelgrove, J.L.

    1996-01-01

    An oxide version of the DART code has been generated in order to assess the irradiation behavior of UO 2 -Al dispersion fuel. The aluminum-fuel interaction models were developed based on U 3 O 8 -Al irradiation data. Deformation of the fuel element occurs due to fuel particle swelling driven by both solid and gaseous fission products, as well as a consequence of the interaction between the fuel particles and the aluminum matrix. The calculations show, that with the assumption that the correlations derived from U 3 O 8 are valid for UO 2 , the LEU UO 2 -Al with a 42% fuel volume loading (4 gm/cc) irradiated at fuel temperatures greater than 413 K should undergo breakaway swelling at core burnups greater than about 1.12 x 10 27 fissions m -3 (∼ 63% 235 U burnup)

  3. Light water reactor mixed-oxide fuel irradiation experiment

    International Nuclear Information System (INIS)

    Hodge, S.A.; Cowell, B.S.; Chang, G.S.; Ryskamp, J.M.

    1998-01-01

    The United States Department of Energy Office of Fissile Materials Disposition is sponsoring and Oak Ridge National Laboratory (ORNL) is leading an irradiation experiment to test mixed uranium-plutonium oxide (MOX) fuel made from weapons-grade (WG) plutonium. In this multiyear program, sealed capsules containing MOX fuel pellets fabricated at Los Alamos National Laboratory (LANL) are being irradiated in the Advanced Test Reactor (ATR) at the Idaho National Engineering and Environmental Laboratory (INEEL). The planned experiments will investigate the utilization of dry-processed plutonium, the effects of WG plutonium isotopics on MOX performance, and any material interactions of gallium with Zircaloy cladding

  4. Development of examination technique for oxide layer thickness measurement of irradiated fuel rods

    International Nuclear Information System (INIS)

    Koo, D. S.; Park, S. W.; Kim, J. H.; Seo, H. S.; Min, D. K.; Kim, E. K.; Chun, Y. B.; Bang, K. S.

    1999-06-01

    Technique for oxide layer thickness measurement of irradiated fuel rods was developed to measure oxide layer thickness and study characteristic of fuel rods. Oxide layer thickness of irradiated fuels were measured, analyzed. Outer oxide layer thickness of 3 cycle-irradiated fuel rods were 20 - 30 μm, inner oxide layer thickness 0 - 10 μm and inner oxide layer thickness on cracked cladding about 30 μm. Oxide layer thickness of 4 cycle-irradiated fuel rods were about 2 times as thick as those of 1 cycle-irradiated fuel rods. Oxide layer on lower region of irradiated fuel rods was thin and oxide layer from lower region to upper region indicated gradual increase in thickness. Oxide layer thickness from 2500 to 3000 mm showed maximum and oxide layer thickness from 3000 to top region of irradiated fuel rods showed decreasing trend. Inner oxide layer thicknesses of 4 cycle-irradiated fuel rod were about 8 μm at 750 - 3500 mm from the bottom end of fuel rod. Outer oxide layer thickness were about 8 μm at 750 - 1000 mm from the bottom end of fuel rod. These indicated gradual increase up to upper region from the bottom end of fuel rod. These indicated gradual increase up to upper region from the bottom end of fuel. Oxide layer thickness technique will apply safety evaluation and study of reactor fuels. (author). 6 refs., 14 figs

  5. In-pile irradiation of rock-like oxide fuels

    International Nuclear Information System (INIS)

    Nitani, N.; Kuramoto, K.; Yamashita, T.; Nakano, Y.; Akie, H.

    2001-01-01

    Five kinds of ROX fuels were prepared and irradiated using 20% enriched U instead of Pu. Non-destructive and destructive post-irradiation examinations were carried out. FP gas release rates of the particle-dispersed type fuels and homogeneously-blended type fuels were larger than that of the Yttria-stabilized zirconia containing UO 2 single phase fuel. From results of SEM and EPMA, decomposition of the spinel was observed. The decomposition of the spinel is probably avoided by lowering the irradiation temperature, less than 1700 K. The regions suffering the irradiation damage of the particle dispersed type fuels were less than those of the homogeneously-blended type fuels. (author)

  6. In-pile irradiation of rock-like oxide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nitani, N.; Kuramoto, K.; Yamashita, T.; Nakano, Y.; Akie, H. [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan)

    2001-07-01

    Five kinds of ROX fuels were prepared and irradiated using 20% enriched U instead of Pu. Non-destructive and destructive post-irradiation examinations were carried out. FP gas release rates of the particle-dispersed type fuels and homogeneously-blended type fuels were larger than that of the Yttria-stabilized zirconia containing UO{sub 2} single phase fuel. From results of SEM and EPMA, decomposition of the spinel was observed. The decomposition of the spinel is probably avoided by lowering the irradiation temperature, less than 1700 K. The regions suffering the irradiation damage of the particle dispersed type fuels were less than those of the homogeneously-blended type fuels. (author)

  7. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    International Nuclear Information System (INIS)

    Roake, W.E.; Adamson, M.G.; Hilbert, R.F.; Langer, S.

    1977-01-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to ∼60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  8. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    Energy Technology Data Exchange (ETDEWEB)

    Roake, W E [Westinghouse-Hanford Co., Richland, WA (United States); Adamson, M G [General Electric Company, Vallecitos Nuclear Center, Pleasanton, CA (United States); Hilbert, R F; Langer, S

    1977-04-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to {approx}60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  9. Cracking and bulk movement in irradiated uranium oxide fuel elements

    International Nuclear Information System (INIS)

    Bain, A.S.

    1963-09-01

    UO 2 pellets were fabricated with simulated circumferential or diametral cracks, and with voids formed by drilling axial or radial holes. Under irradiation the cracks healed in a region extending out slightly beyond the area of discernible grain growth. Cracks in the cooler outer annulus formed early and remained during the irradiation. Similarly voids in the outer annulus were unchanged, whereas those in the grain-growth region closed. Tungsten wire markers stayed in their original positions, demonstrating that the surrounding columnar grains in the UO 2 had not formed during the solidification of a melt. Decreases in diameter of 1 mm thick Zircaloy-2 sheathing assembled with large fuel/sheath diametral clearances were due to multi-axial stresses arising from axial elongation and the lack of diametral restraint. (author)

  10. Cracking and bulk movement in irradiated uranium oxide fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    Bain, A S

    1963-09-15

    UO{sub 2} pellets were fabricated with simulated circumferential or diametral cracks, and with voids formed by drilling axial or radial holes. Under irradiation the cracks healed in a region extending out slightly beyond the area of discernible grain growth. Cracks in the cooler outer annulus formed early and remained during the irradiation. Similarly voids in the outer annulus were unchanged, whereas those in the grain-growth region closed. Tungsten wire markers stayed in their original positions, demonstrating that the surrounding columnar grains in the UO{sub 2} had not formed during the solidification of a melt. Decreases in diameter of 1 mm thick Zircaloy-2 sheathing assembled with large fuel/sheath diametral clearances were due to multi-axial stresses arising from axial elongation and the lack of diametral restraint. (author)

  11. Pathfinder irradiation of advanced fuel (Th/U mixed oxide) in a power reactor

    International Nuclear Information System (INIS)

    Brant Pinheiro, R.

    1993-01-01

    Within the joint Brazilian-German cooperative R and D Program on Thorium Utilization in Pressurized Water Reactors carried out from 1979 to 1988 by Nuclebras/CDTN, KFA-Juelich, Siemens/KWU and NUKEM, a pathfinder irradiation of Th/U mixed oxide fuel in the Angra 1 nuclear power reactor was planned. The objectives of this irradiation testing, the irradiation strategy, the work performed and the status achieved at the end of the joint Program are presented. (author)

  12. Determination of melting point of mixed-oxide fuel irradiated in a fast breeder reactor

    International Nuclear Information System (INIS)

    Tachibana, Toshimichi

    1985-01-01

    The melting point of fuel is important to set its in-reactor maximum temperature in fuel design. The fuel melting point measuring methods are broadly the filament method and the capsule sealing method. The only instance of measuring the melting point of irradiated mixed oxide (U, Pu)O 2 fuel by the filament method is by GE in the United States. The capsule sealing method, while the excellent means, is difficult in weld sealing the irradiated fuel in a capsule within the cell. In the fast reactor development program, the remotely operated melting point measuring apparatus in capsule sealing the mixed (U, Pu)O 2 fuel irradiated in the experimental FBR Joyo was set in the cell and the melting point was measured, for the first time in the world. (Mori, K.)

  13. Experimental and thermodynamic evaluation of the melting behavior of irradiated oxide fuels

    International Nuclear Information System (INIS)

    Adamson, M.G.; Aitken, E.A.; Caputi, R.W.

    1985-01-01

    Onset of melting is an important performance limit for irradiated UO 2 and UO 2 -based nuclear reactor fuels. Melting (solidus) temperatures are reasonably well known for starting fuel materials such as UO 2 and (U,PU)O 2 , however the influence of burnup on oxide fuel melting behavior continues to represent an area of considerable uncertainty. In this paper we report the results of a variety of melting temperature measurements on pseudo-binary fuel-fissia mixtures such as UO 2 -PUO 2 , UO 2 -CeO 2 , UO 2 -BaO, UO 2 -SrO, UO 2 -BaZrO 3 and UO 2 -SrZrO 3 . These measurements were performed using the thermal arrest technique on tungsten-encapsulated specimens. Several low melting eutectics, the existence of which had previously been inferred from post-irradiation examinations of high burnup mixed oxide fuels, were characterized in the course of the investigation. Also, an assessment of melting temperature changes in irradiated oxide fuels due to the production and incorporation of soluble oxidic fission products was performed by application of solution theory to the available pseudo-binary phase diagram data. The results of this assessment suggest that depression of oxide fuel solidus temperatures by dissolved fission products is substantially less than that indicated by earlier experimental studies. (orig.)

  14. Modeling of thermo-mechanical and irradiation behavior of mixed oxide fuel for sodium fast reactors

    International Nuclear Information System (INIS)

    Karahan, Aydin; Buongiorno, Jacopo

    2010-01-01

    An engineering code to model the irradiation behavior of UO 2 -PuO 2 mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named fuel engineering and structural analysis tool (FEAST-OXIDE). FEAST-OXIDE has several modules working in coupled form with an explicit numerical algorithm. These modules describe: (1) fission gas release and swelling, (2) fuel chemistry and restructuring, (3) temperature distribution, (4) fuel-clad chemical interaction and (5) fuel-clad mechanical analysis. Given the fuel pin geometry, composition and irradiation history, FEAST-OXIDE can analyze fuel and cladding thermo-mechanical behavior at both steady-state and design-basis transient scenarios. The code was written in FORTRAN-90 program language. The mechanical analysis module implements the LIFE algorithm. Fission gas release and swelling behavior is described by the OGRES and NEFIG models. However, the original OGRES model has been extended to include the effects of joint oxide gain (JOG) formation on fission gas release and swelling. A detailed fuel chemistry model has been included to describe the cesium radial migration and JOG formation, oxygen and plutonium radial distribution and the axial migration of cesium. The fuel restructuring model includes the effects of as-fabricated porosity migration, irradiation-induced fuel densification, grain growth, hot pressing and fuel cracking and relocation. Finally, a kinetics model is included to predict the clad wastage formation. FEAST-OXIDE predictions have been compared to the available FFTF, EBR-II and JOYO databases, as well as the LIFE-4 code predictions. The agreement was found to be satisfactory for steady-state and slow-ramp over-power accidents.

  15. Modeling of thermo-mechanical and irradiation behavior of mixed oxide fuel for sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Karahan, Aydin, E-mail: karahan@mit.ed [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology, MA (United States); Buongiorno, Jacopo [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology, MA (United States)

    2010-01-31

    An engineering code to model the irradiation behavior of UO{sub 2}-PuO{sub 2} mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named fuel engineering and structural analysis tool (FEAST-OXIDE). FEAST-OXIDE has several modules working in coupled form with an explicit numerical algorithm. These modules describe: (1) fission gas release and swelling, (2) fuel chemistry and restructuring, (3) temperature distribution, (4) fuel-clad chemical interaction and (5) fuel-clad mechanical analysis. Given the fuel pin geometry, composition and irradiation history, FEAST-OXIDE can analyze fuel and cladding thermo-mechanical behavior at both steady-state and design-basis transient scenarios. The code was written in FORTRAN-90 program language. The mechanical analysis module implements the LIFE algorithm. Fission gas release and swelling behavior is described by the OGRES and NEFIG models. However, the original OGRES model has been extended to include the effects of joint oxide gain (JOG) formation on fission gas release and swelling. A detailed fuel chemistry model has been included to describe the cesium radial migration and JOG formation, oxygen and plutonium radial distribution and the axial migration of cesium. The fuel restructuring model includes the effects of as-fabricated porosity migration, irradiation-induced fuel densification, grain growth, hot pressing and fuel cracking and relocation. Finally, a kinetics model is included to predict the clad wastage formation. FEAST-OXIDE predictions have been compared to the available FFTF, EBR-II and JOYO databases, as well as the LIFE-4 code predictions. The agreement was found to be satisfactory for steady-state and slow-ramp over-power accidents.

  16. Chemical states of fission products in irradiated uranium-plutonium mixed oxide fuel

    International Nuclear Information System (INIS)

    Kurosaki, Ken; Uno, Masayoshi; Yamanaka, Shinsuke

    1999-01-01

    The chemical states of fission products (FPs) in irradiated uranium-plutonium mixed oxide (MOX) fuel for the light water reactor (LWR) were estimated by thermodynamic equilibrium calculations on system of fuel and FPs by using ChemSage program. A stoichiometric MOX containing 6.1 wt. percent PuO 2 was taken as a loading fuel. The variation of chemical states of FPs was calculated as a function of oxygen potential. Some pieces of information obtained by the calculation were compared with the results of the post-irradiation examination (PIE) of UO 2 fuel. It was confirmed that the multicomponent and multiphase thermodynamic equilibrium calculation between fuel and FPs system was an effective tool for understanding the behavior of FPs in fuel. (author)

  17. Dissolution behavior of irradiated mixed oxide fuel with short stroke shearing for fast reactor reprocessing

    International Nuclear Information System (INIS)

    Ikeuchi, Hirotomo; Sano, Yuichi; Shibata, Atsuhiro; Koizumi, Tsutomu; Washiya, Tadahiro

    2013-01-01

    An efficient dissolution process was established for future reprocessing in which mixed-oxide (MOX) fuels with high plutonium contents and dissolver solution with high heavy-metal (HM) concentrations (more than 500 g dm -3 ) will be treated. This dissolution process involves short stroke shearing of fuels (∼10 mm in length). The dissolution kinetics of irradiated MOX fuels and the effects of the Pu content, HM concentration, and fuel form on the dissolution rate were investigated. Irradiated fuel was found to dissolve as 10 2 -10 3 times fast as non-irradiated fuel, but the rate decreased with increasing Pu content. Kinetic analysis based on the fragmentation model, which considers the penetration and diffusion of nitric acid through fuel matrices prior to chemical reaction, indicated that the dissolution rate of irradiated fuel was affected not only by the volume ratio of liquid to solid (L/S ratio) but also by the exposed surface area per unit mole of nitric acid (A/m ratio). The penetration rate of nitric acid is expected to be decreased at high HM concentrations by a reduction in the L/S ratio, but enhanced by shearing the fuel pieces with short strokes and thus enlarging the A/m ratio. (author)

  18. Irradiation of inert matrix and mixed oxide fuel in the Halden test reactor

    International Nuclear Information System (INIS)

    Hellwig, Ch.; Kasemeyer, U.

    2001-01-01

    In a new type of fuel, called Inert Matrix Fuel (IMF), plutonium is embedded in a U-free matrix. This offers advantages for more efficient plutonium consumption, higher proliferation resistance, and for inert behaviour later in a waste repository. In the fuel type investigated at PSI, plutonium is dissolved in yttrium-stabilized zirconium oxide (YSZ), a highly radiation-resistant cubic phase, with addition of erbium as burnable poison for reactivity control. A first irradiation experiment of YSZ-based IMF is ongoing in the OECD Material Test Reactor in Halden (HBWR), together with MOX fuel (Rig IFA-651.1). The experiment is described herein and results are presented of the first 120 days of irradiation with an average assembly burnup of 47 kWd/cm 3 . The results are compared with neutronic calculations performed before the experiment, and are used to model the fuel behaviour with the PSI-modified TRANSURANUS code. The measured fuel temperatures are within the expected range. An unexpectedly strong densification of the IMF during the first irradiation cycle does not alter the fuel temperatures. An explanation for this behaviour is proposed. The irradiation at higher linear heat rates during forthcoming cycles will deliver information about the fission gas release behaviour of the IMF. (author)

  19. Irradiation of inert matrix and mixed oxide fuel in the Halden test reactor

    Energy Technology Data Exchange (ETDEWEB)

    Hellwig, Ch.; Kasemeyer, U

    2001-03-01

    In a new type of fuel, called Inert Matrix Fuel (IMF), plutonium is embedded in a U-free matrix. This offers advantages for more efficient plutonium consumption, higher proliferation resistance, and for inert behaviour later in a waste repository. In the fuel type investigated at PSI, plutonium is dissolved in yttrium-stabilized zirconium oxide (YSZ), a highly radiation-resistant cubic phase, with addition of erbium as burnable poison for reactivity control. A first irradiation experiment of YSZ-based IMF is ongoing in the OECD Material Test Reactor in Halden (HBWR), together with MOX fuel (Rig IFA-651.1). The experiment is described herein and results are presented of the first 120 days of irradiation with an average assembly burnup of 47 kWd/cm{sup 3}. The results are compared with neutronic calculations performed before the experiment, and are used to model the fuel behaviour with the PSI-modified TRANSURANUS code. The measured fuel temperatures are within the expected range. An unexpectedly strong densification of the IMF during the first irradiation cycle does not alter the fuel temperatures. An explanation for this behaviour is proposed. The irradiation at higher linear heat rates during forthcoming cycles will deliver information about the fission gas release behaviour of the IMF. (author)

  20. Calculation of oxygen distribution in uranium-plutonium oxide fuels during irradiation (programme CODIF)

    International Nuclear Information System (INIS)

    Moreno, A.; Sari, C.

    1978-01-01

    Radial gradients of oxygen to metal ratio, O/M, in uranium-plutonium oxide fuel pins, during irradiation and at the end of life, have been calculated on the basis of solid-state thermal diffusion using measured values of the heat of transport. A detailed computer model which includes the calculation of temperature profiles and the variation of the average O/M ratio as a function of burn-up is given. Calculations show that oxygen profiles are affected by the isotopic composition of the fuel, by the temperature profiles and by fuel-cladding interactions

  1. Irradiation of mixed UO2-PuO2 oxide samples for fast neutron reactor fuel elements

    International Nuclear Information System (INIS)

    Mikailoff, H.; Mustelier, J.; Bloch, J.; Conte, M.; Hayet, L.; Lauthier, J.C.; Leclere, J.

    1968-01-01

    Thermal flux irradiation testings of small mixed oxide pellets UPuO 2 fuel elements were performed in support of the fuel reference design for the Phenix fast reactor. The effects of different parameters (stoichiometry, pellet density, pellet clad gap). on the behaviour of the oxide (temperature distribution, microstructural changes, fission gas release) were investigated in various irradiation conditions. In particular, the effect of fuel density decrease and power rate increase on thermal performances were determined on short term irradiations of porous fuels. (authors) [fr

  2. Results of the irradiation of mixed UO2 - PuO2 oxide fuel elements

    International Nuclear Information System (INIS)

    Mikailoff, H.; Mustelier, J.P.; Bloch, J.; Ezran, L.; Hayet, L.

    1966-01-01

    In order to study the behaviour of fuel elements used for the first charge of the reactor Rapsodie, a first batch of eleven needles was irradiated in the reactor EL3 and then examined. These needles (having a shape very similar lo that of the actual needles to be used) were made up of a stack of sintered mixed-oxide pellets: UO 2 containing about 10 per cent of PuO 2 . The density was 85 to 97 per cent of the theoretical, value. The diametral gap between the oxide and the stainless steel can was between 0,06 and 0,27 mm. The specific powers varied from 1230 to 2700 W/cm 3 and the can temperature was between 450 and 630 C. The maximum burn-up attained was 22000 MW days/tonne. Examination of the needles (metrology, radiography and γ-spectrography) revealed certain macroscopic changes, and the evolution of the fuel was shown by micrographic studies. These observations were used, together with flux measurements results, to calculate the temperature distribution inside the fuel. The volume of the fission gas produced was measured in some of the samples; the results are interpreted taking into account the temperature distribution in the oxide and the burn-up attained. Finally a study was made both of the behaviour of a fuel element whose central part was molten during irradiation, and of the effect of sodium which had penetrated into some of the samples following can rupture. (author) [fr

  3. An improved characterization method for international accountancy measurements of fresh and irradiated mixed oxide (MOX) fuel: helping achieve continual monitoring and safeguards through the fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Louise G [Los Alamos National Laboratory; Croft, Stephen [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Tobin, S. J. [Los Alamos National Laboratory; Menlove, H. O. [Los Alamos National Laboratory; Schear, M. A. [Los Alamos National Laboratory; Worrall, Andrew [U.K. NNL

    2011-01-13

    Nuclear fuel accountancy measurements are conducted at several points through the nuclear fuel cycle to ensure continuity of knowledge (CofK) of special nuclear material (SNM). Non-destructive assay (NDA) measurements are performed on fresh fuel (prior to irradiation in a reactor) and spent nuclear fuel (SNF) post-irradiation. We have developed a fuel assembly characterization system, based on the novel concept of 'neutron fingerprinting' with multiplicity signatures to ensure detailed CofK of nuclear fuel through the entire fuel cycle. The neutron fingerprint in this case is determined by the measurement of the various correlated neutron signatures, specific to fuel isotopic composition, and therefore offers greater sensitivity to variations in fissile content among fuel assemblies than other techniques such as gross neutron counting. This neutron fingerprint could be measured at the point of fuel dispatch (e.g. from a fuel fabrication plant prior to irradiation, or from a reactor site post-irradiation), monitored during transportation of the fuel assembly, and measured at a subsequent receiving site (e.g. at the reactor site prior to irradiation, or reprocessing facility post-irradiation); this would confirm that no unexpected changes to the fuel composition or amount have taken place during transportation and/ or reactor operations. Changes may indicate an attempt to divert material for example. Here, we present the current state of the practice of fuel measurements for both fresh mixed oxide (MOX) fuel and SNF (both MOX and uranium dioxide). This is presented in the framework of international safeguards perspectives from the US and UK. We also postulate as to how the neutron fingerprinting concept could lead to improved fuel characterization (both fresh MOX and SNF) resulting in: (a) assured CofK of fuel across the nuclear fuel cycle, (b) improved detection of SNM diversion, and (c) greater confidence in safeguards of SNF transportation.

  4. Gamma scanning of mixed carbide and oxide fuel pins irradiated in FBTR

    International Nuclear Information System (INIS)

    Jayaraj, V.V.; Padalakshmi, M.; Ulaganathan, T.; Venkiteswaran, C.N.; Divakar, R.; Joseph, Jojo; Bhaduri, A.K.

    2016-01-01

    Fission in nuclear fuels results in a number of fission products that are gamma emitters in the energy range of 100 keV to 3 MeV. The gamma emitting fission products are therefore amenable for detection by gamma detectors. Assessment of the fission product distribution and their migration behavior through gamma scanning is important for characterizing the in reactor behavior of the fuel. Gamma scanning is an important non destructive technique used to evaluate the behavior of irradiated fuels. As a part of Post Irradiation Examinations (PIE), axial gamma scanning has been carried out on selected fuel pins of the FBTR Mark I mixed carbide fuel sub-assemblies and PFBR MOX test fuel sub-assembly irradiated in FBTR. This paper covers the results of gamma scanning and correlation of gamma scanning results with other PIE techniques

  5. Review of direct electrical heating experiments on irradiated mixed-oxide fuel

    International Nuclear Information System (INIS)

    Fenske, G.R.; Bandyopadhyay, G.

    1982-01-01

    Results of approximately 50 out-of-reactor experiments that simulated various stages of a loss-of-flow event with irradiated fuel are presented. The tests, which utilized the direct electrical heating technique to simulate nuclear heating, were performed either on fuel segments with their original cladding intact or on fuel segments that were extruded into quartz tubes. The test results demonstrated that the macro- and microscopic fuel behavior was dependent on a number of variables including fuel heating rate, thermal history prior to a transient, the number of heating cycles, type of cladding (quartz vs stainless steel), and fuel burnup

  6. Fundamental Studies of Irradiation-Induced Defect Formation and Fission Product Dynamics in Oxide Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Stubbins, James

    2012-12-19

    The objective of this research program is to address major nuclear fuels performance issues for the design and use of oxide-type fuels in the current and advanced nuclear reactor applications. Fuel performance is a major issue for extending fuel burn-up which has the added advantage of reducing the used fuel waste stream. It will also be a significant issue with respect to developing advanced fuel cycle processes where it may be possible to incorporate minor actinides in various fuel forms so that they can be 'burned' rather than join the used fuel waste stream. The potential to fission or transmute minor actinides and certain long-lived fission product isotopes would transform the high level waste storage strategy by removing the need to consider fuel storage on the millennium time scale.

  7. A review of irradiation induced re-solution in oxide fuels

    International Nuclear Information System (INIS)

    Turnbull, J.A.

    1980-01-01

    The paper reviews the existing experimental evidence for irradiation induced re-solution and also possible explanations for the mechanism. The importance of re-solution is considered with regard to intragranular bubbles and the accumulation of gas on grain boundaries. It is concluded that re-solution is most effective at low temperatures and could account for the present concern over gas release in high burn-up water reactor fuel assemblies. (author)

  8. Influence of fission gases on the mechanical state of irradiated oxide fuels

    International Nuclear Information System (INIS)

    Cagna, Celine

    2016-01-01

    The irradiation generates in the fuel, fission gases, mainly xenon and krypton, present in dissolved form and in the form of bubbles. This research objective is to contribute to the fission gas bubbles methodology of characterization and thus to bring elements of reference for the models validation. Two approaches are studied. Based on an existing method of bubbles average pressure evaluation by the coupling of three techniques: EPMA, SEM and SIMS, a new complementary method has been developed on an isolated bubble under the surface. The methodology consists in identifying a closed and filled bubble with xenon by microprobe mapping and SEM images and to measure the amount of present gas by SIMS. 3D observation by FIB abrasion provides an estimation of the bubble volume and thus allows to calculate the bubble pressure. At 300 K, an estimation of the pressure levels is obtained on intragranular micrometric bubbles from the fuel pellets center area. Meanwhile, a method of elastic field strain measurement, produced by the presence of pressurized bubbles, is developed by HR-EBSD. A finite element model evaluates the levels of strain around the fission gas bubbles and shows that only nano-metric bubbles generate measurable elastic strain by this technique. First, the method was calibrated from four points bending tests on monocrystalline silicon and ceramics implanted with xenon, allowing to take into account free strains. This step defines the parameters of acquisition and optimum treatment for its application on irradiated fuels. Measurement of elastic strain with HR-EBSD on irradiated fuel is a relative measure that will require further consideration in the choice of the reference. (author) [fr

  9. Superoxide radical and UV irradiation in ultrasound assisted oxidative desulfurization (UAOD): A potential alternative for greener fuels

    Science.gov (United States)

    Chan, Ngo Yeung

    This study is aimed at improving the current ultrasound assisted oxidative desulfurization (UAOD) process by utilizing superoxide radical as oxidant. Research was also conducted to investigate the feasibility of ultraviolet (UV) irradiation-assisted desulfurization. These modifications can enhance the process with the following achievements: (1) Meet the upcoming sulfur standards on various fuels including diesel fuel oils and residual oils; (2) More efficient oxidant with significantly lower consumption in accordance with stoichiometry; (3) Energy saving by 90%; (4) Greater selectivity in petroleum composition. Currently, the UAOD process and subsequent modifications developed in University of Southern California by Professor Yen's research group have demonstrated high desulfurization efficiencies towards various fuels with the application of 30% wt. hydrogen peroxide as oxidant. The UAOD process has demonstrated more than 50% desulfurization of refractory organic sulfur compounds with the use of Venturella type catalysts. Application of quaternary ammonium fluoride as phase transfer catalyst has significantly improved the desulfurization efficiency to 95%. Recent modifications incorporating ionic liquids have shown that the modified UAOD process can produce ultra-low sulfur, or near-zero sulfur diesels under mild conditions with 70°C and atmospheric pressure. Nevertheless, the UAOD process is considered not to be particularly efficient with respect to oxidant and energy consumption. Batch studies have demonstrated that the UAOD process requires 100 fold more oxidant than the stoichiometic requirement to achieve high desulfurization yield. The expected high costs of purchasing, shipping and storage of the oxidant would reduce the practicability of the process. The excess use of oxidant is not economically desirable, and it also causes environmental and safety issues. Post treatments would be necessary to stabilize the unspent oxidant residual to prevent the waste

  10. Fuel or irradiation subassembly

    International Nuclear Information System (INIS)

    Seim, O.S.; Hutter, E.

    1975-01-01

    A subassembly for use in a nuclear reactor is described which incorporates a loose bundle of fuel or irradiation pins enclosed within an inner tube which in turn is enclosed within an outer coolant tube and includes a locking comb consisting of a head extending through one side of the inner sleeve and a plurality of teeth which extend through the other side of the inner sleeve while engaging annular undercut portions in the bottom portion of the fuel or irradiation pins to prevent movement of the pins

  11. Irradiated fuel bundle counter

    International Nuclear Information System (INIS)

    Campbell, J.W.; Todd, J.L.

    1975-01-01

    The design of a prototype safeguards instrument for determining the number of irradiated fuel assemblies leaving an on-power refueled reactor is described. Design details include radiation detection techniques, data processing and display, unattended operation capabilities and data security methods. Development and operating history of the bundle counter is reported. (U.S.)

  12. Irradiated fuel bundle counter

    International Nuclear Information System (INIS)

    Campbell, J.W.; Todd, J.L.

    1975-01-01

    The design of a prototype safeguards instrument for determining the number of irradiated fuel assemblies leaving an on-power refueled reactor is described. Design details include radiation detection techniques, data processing and display, unattended operation capabilities and data security methods. Development and operating history of the bundle counter is reported

  13. Transient survivability of LMR oxide fuel pins

    International Nuclear Information System (INIS)

    Weber, E.T.; Pitner, A.L.; Bard, F.E.; Culley, G.E.; Hunter, C.W.

    1986-01-01

    Fuel pin integrity during transient events must be assessed for both the core design and safety analysis phases of a reactor project. A significant increase in the experience related to limits of integrity for oxide fuel pins in transient overpower events has been realized from testing of fuel pins irradiated in FFTF and PFR. Fourteen FFTF irradiated fuel pins were tested in TREAT, representing a range of burnups, overpower ramp rates and maximum overpower conditions. Results of these tests along with similar testing in the PFR/TREAT program, provide a demonstration of significant safety margins for oxide fuel pins. Useful information applied in analytical extrapolation of fuel pin test data have been developed from laboratory transient tests on irradiated fuel cladding (FCTT) and on unirradiated fuel pellet deformation. These refinements in oxide fuel transient performance are being applied in assessment of transient capabilities of long lifetime fuel designs using ferritic cladding

  14. Simulation of the chemical state of irradiated oxide fuel; influence of the internal corrosion on the mechanical properties of Zry-4 tubing

    International Nuclear Information System (INIS)

    Hofmann, P.

    1979-03-01

    Zircaloy is not compatible with oxide fuel nor with some fission product elements. Therefore, chemical interaction between the irradiated oxide fuel and the Zry cladding material take place, especially at temperatures that can be reached during reactor incidents (ATWS, LOCA). In order to find out which influence the chemical interaction between the fission products and the Zry cladding material have on the mechanical properties of Zry-4 tubing out-of-pile burst experiments and creep rupture tests have been performed at temperatures >=600 0 C with short tube specimens containing simulated fission products. First of all, assessments of the chemical state of irradiated oxide fuel were performed and a method is described for introducing simulated fission product species into fresh oxide fuel for irradiation tests. As the test results of the out-of-pile studies show, only iodine can lead to a low ductility failure of the Zry-tubing at temperatures >=600 0 C. However, the influence of iodine on the deformation behavior of Zry-tubing can be neglected above 850 0 C. (orig.) [de

  15. Fabrication, inspection, and test plan for the Advanced Test Reactor (ATR) Mixed-Oxide (MOX) fuel irradiation project

    International Nuclear Information System (INIS)

    Wachs, G.W.

    1997-11-01

    The Department of Energy (DOE) Fissile Materials Disposition Materials Disposition Program (FMDP) has announced that reactor irradiation of MOX fuel is one of the preferred alternatives for disposal of surplus weapons-usable plutonium (Pu). MOX fuel has been utilized domestically in test reactors and on an experimental basis in a number of Commercial Light Water Reactors (CLWRs). Most of this experience has been with Pu derived from spent low enriched uranium (LEU) fuel, known as reactor grade (RG) Pu. The MOX fuel test will be irradiated in the ATR to provide preliminary data to demonstrate that the unique properties of surplus weapons-derived or weapons-grade (WG) plutonium (Pu) do not compromise the applicability of this MOX experience base. In addition, the test will contribute experience with irradiation of gallium-containing fuel to the data base required for resolution of generic CLWR fuel design issues (ORNL/MD/LTR-76). This Fabrication, Inspection, and Test Plan (FITP) is a level 2 document as defined in the FMDP LWR MOX Fuel Irradiation Test Project Plan (ORNL/MD/LTR-78)

  16. Nondestructive analysis of irradiated fuels

    International Nuclear Information System (INIS)

    Dudey, N.D.; Frick, D.C.

    1977-01-01

    The principal nondestructive examination techniques presently used to assess the physical integrity of reactor fuels and cladding materials include gamma-scanning, profilometry, eddy current, visual inspection, rod-to-rod spacing, and neutron radiography. LWR fuels are generally examined during annual refueling outages, and are conducted underwater in the spent fuel pool. FBR fuels are primarily examined in hot cells after fuel discharge. Although the NDE techniques are identical, LWR fuel examinations emphasize tests to demonstrate adherence to technical specification and reliable fuel performance; whereas, FBR fuel examinations emphasize aspects more related to the relative performance of different types of fuel and cladding materials subjected to variable irradiation conditions

  17. Fission product phases in irradiated carbide fuels

    International Nuclear Information System (INIS)

    Ewart, F.T.; Sharpe, B.M.; Taylor, R.G.

    1975-09-01

    Oxide fuels have been widely adopted as 'first charge' fuels for demonstration fast reactors. However, because of the improved breeding characteristics, carbides are being investigated in a number of laboratories as possible advanced fuels. Irradiation experiments on uranium and mixed uranium-plutonium carbides have been widely reported but the instances where segregate phases have been found and subjected to electron probe analysis are relatively few. Several observations of such segregate phases have now been made over a period of time and these are collected together in this document. Some seven fuel pins have been examined. Two of the irradiations were in thermal materials testing reactors (MTR); the remainder were experimental assemblies of carbide gas bonded oxycarbide and sodium bonded oxycarbide in the Dounreay Fast Reactor (DFR). All fuel pins completed their irradiation without failure. (author)

  18. Safeguards approach for irradiated fuel

    International Nuclear Information System (INIS)

    Harms, N.L.; Roberts, F.P.

    1987-03-01

    IAEA verification of irradiated fuel has become more complicated because of the introduction of variations in what was once presumed to be a straightforward flow of fuel from reactors to reprocessing plants, with subsequent dissolution. These variations include fuel element disassembly and reassembly, rod consolidation, double-tiering of fuel assemblies in reactor pools, long term wet and dry storage, and use of fuel element containers. This paper reviews future patterns for the transfer and storage of irradiated LWR fuel and discusses appropriate safeguards approaches for at-reactor storage, reprocessing plant headend, independent wet storage, and independent dry storage facilities

  19. The transportation of PuO2 and MOX fuel and management of irradiated MOX fuel

    International Nuclear Information System (INIS)

    Dyck, H.P.; Rawl, R.; Durpel, L. van den

    2000-01-01

    Information is given on the transportation of PuO 2 and mixed-oxide (MOX) fuel, the regulatory requirements for transportation, the packages used and the security provisions for transports. The experience with and management of irradiated MOX fuel and the reprocessing of MOX fuel are described. Information on the amount of MOX fuel irradiated is provided. (author)

  20. CEA fuel pencil qualification under irradiation: from component conception to fuel assembly irradiation in a power reactor

    International Nuclear Information System (INIS)

    Marin, J.-F.; Pillet, Claude; Francois, Bernard; Morize, Pierre; Petitgrand, Sylvie; Atabek, R.-M.; Houdaille, Brigitte.

    1981-06-01

    Fabrication of fuel pins made of uranium oxide pellets and of a zircaloy 4 cladding is described. Irradiation experiment results are given. Thermomechanical behavior of the fuel pin in a power reactor is examined [fr

  1. Synchrotron X-ray diffraction investigations on strains in the oxide layer of an irradiated Zircaloy fuel cladding

    International Nuclear Information System (INIS)

    Chollet, Mélanie; Valance, Stéphane; Abolhassani, Sousan; Stein, Gene; Grolimund, Daniel; Martin, Matthias; Bertsch, Johannes

    2017-01-01

    For the first time the microstructure of the oxide layer of a Zircaloy-2 cladding after 9 cycles of irradiation in a boiling water reactor has been analyzed with synchrotron micro-X-ray diffraction. Crystallographic strains of the monoclinic and to some extent of the tetragonal ZrO 2 are depicted through the thick oxide layer. Thin layers of sub-oxide at the oxide-metal interface as found for autoclave-tested samples and described in the literature, have not been observed in this material maybe resulting from irradiation damage. Shifts of selected diffraction peaks of the monoclinic oxide show that the uniform strain produced during oxidation is orientated in the lattice and displays variations along the oxide layer. Diffraction peaks and their shifts from families of diffracting planes could be translated into a virtual tensor. This virtual tensor exhibits changes through the oxide layer passing by tensile or compressive components. - Highlights: •A Zircaloy-2 cladding irradiated 9 cycles was investigated thanks to synchrotron X-ray diffraction. •Microstructure and uniform strain through the oxide layer is revealed. •The m-ZrO 2 uniform strain is oriented presenting compression along the (−111) plane. •Virtual tensor is built based on reflecting planes of families of grains. •Tensor components vary from tensile to compressive along the oxide layer.

  2. Synchrotron X-ray diffraction investigations on strains in the oxide layer of an irradiated Zircaloy fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Chollet, Mélanie, E-mail: melanie.chollet@psi.ch [Paul Scherrer Institute, NES, 5232 Villigen (Switzerland); Valance, Stéphane; Abolhassani, Sousan; Stein, Gene [Paul Scherrer Institute, NES, 5232 Villigen (Switzerland); Grolimund, Daniel [Paul Scherrer Institute, SLS, 5232 Villigen (Switzerland); Martin, Matthias; Bertsch, Johannes [Paul Scherrer Institute, NES, 5232 Villigen (Switzerland)

    2017-05-15

    For the first time the microstructure of the oxide layer of a Zircaloy-2 cladding after 9 cycles of irradiation in a boiling water reactor has been analyzed with synchrotron micro-X-ray diffraction. Crystallographic strains of the monoclinic and to some extent of the tetragonal ZrO{sub 2} are depicted through the thick oxide layer. Thin layers of sub-oxide at the oxide-metal interface as found for autoclave-tested samples and described in the literature, have not been observed in this material maybe resulting from irradiation damage. Shifts of selected diffraction peaks of the monoclinic oxide show that the uniform strain produced during oxidation is orientated in the lattice and displays variations along the oxide layer. Diffraction peaks and their shifts from families of diffracting planes could be translated into a virtual tensor. This virtual tensor exhibits changes through the oxide layer passing by tensile or compressive components. - Highlights: •A Zircaloy-2 cladding irradiated 9 cycles was investigated thanks to synchrotron X-ray diffraction. •Microstructure and uniform strain through the oxide layer is revealed. •The m-ZrO{sub 2} uniform strain is oriented presenting compression along the (−111) plane. •Virtual tensor is built based on reflecting planes of families of grains. •Tensor components vary from tensile to compressive along the oxide layer.

  3. Container for irradiated fuel

    International Nuclear Information System (INIS)

    Guy, R.

    1978-01-01

    The transport container for irradiated or used nuclear fuel is provided with an identical heat shield against fires on the top and bottom sides. Each heat shield consists of two inner nickel plates, whose contact surfaces are polished to a mirror finish and an outer plate of stainless steel. The nickel plate on the box is spot welded to it while the second nickel plate is spot welded to the steel plate. Both together are in turn welded so as to be leaktight to the edges of the box. For extreme heat effects and based on the different (bimetal) coefficients of expansion, the steel plate with the nickel plate attached to it bulges away from the box. The second nickel plate remains at the box, so that a subpressure space is formed with the mirror nickel surfaces. The heat radiation and heat conduction to the box are greatly reduced by this. (DG) [de

  4. Interaction between uranium oxide alloyed with Al2O3·SiO2 and pyrocarbon coating during irradiation of micro fuel elements

    International Nuclear Information System (INIS)

    Chernikov, A.S.; Khromov, Y.F.; Svistunov, D.E.; Chuiko, E.E.

    1989-01-01

    The thermodynamics of the interaction between uranium oxide and carbon was previously studied in the presence of Al 2 O 3 ·SiO 2 , SiC, and UC 1.86 ; in this case, the quantity of the reacting substances does not have any effect on the attainment of the equilibrium state. Based on the obtained results, it is interesting to study the characteristic features of the interaction between the alloyed UO x cores (kernels) with the PyC-coating under the conditions involving irradiation of the micro fuel elements with thermal neutrons and the formation of solid fission products. The data concerning the characteristics of a micro fuel element (the weight of the core, its composition, etc.) are useful for carrying out a quantitative evaluation of the additives required for fixing the alkali-earth fission products by obtaining stable compounds of aluminosilicates with Ba, Sr, Rb, and Cs at different levels of depletion (burnup) of the oxide fuel. An analysis of the interaction processes in such a complex system as the irradiated alloyed uranium oxide fuel located in a micro fuel element is carried out by comparing the chemical potential of oxygen (RT ln P O 2 ) for the competing constituents of the system

  5. Development of a reconversion method for uranyl nitrate to oxide in the reconversion step of reprocessing of irradiated fuel

    International Nuclear Information System (INIS)

    Govindan, P.; Palamalai, A.; Vijayan, K.S.; Subbuthai, S.; Murugesan, S.; Mohan, S.V.; Subba Rao, R.V.

    2002-01-01

    Ammonium uranyl carbonate (AUC) precipitation is developed for the conversion of uranyl nitrate to oxide in the uranium reconversion step of reprocessing of irradiated fuel by the addition of ammonium carbonate salt. Different precipitation conditions of AUC are studied. The solubility of AUC as a function of uranium concentration in the feed at different temperatures using ammonium carbonate salt as precipitant is studied. This study indicates that 95-99.8% of uranium is recovered as AUC by precipitating 5-125 g/l of uranium with loss of uranium (250-10 ppm) in the filtrate by adding ammonium carbonate salt. It is also observed that the solubility of AUC increased as the concentration of uranium decreased. Thermal decomposition is carried out by thermogravimetry/differential thermal analysis (TG/DTA) and evolved gas analysis-mass spectrometry (EGA-MS) to find out AUC decomposition and gases evolved during decomposition. Studies are also carried out to characterize AUC by using X-ray diffraction (XRD). The data show that AUC obtained by the above conditions is very much consistent with published information. (author)

  6. Internal fuel pin oxidizer

    International Nuclear Information System (INIS)

    Andrews, M.G.

    1978-01-01

    A nuclear fuel pin has positioned within it material which will decompose to release an oxidizing agent which will react with the cladding of the pin and form a protective oxide film on the internal surface of the cladding

  7. Oxide particle size distribution from shearing irradiated and unirradiated LWR fuels in Zircaloy and stainless steel cladding: significance for risk assessment

    Energy Technology Data Exchange (ETDEWEB)

    Davis, W. Jr.; West, G.A.; Stacy, R.G.

    1979-03-22

    Sieve fractionation was performed with oxide particles dislodged during shearing of unirradiated or irradiated fuel bundles or single rods of UO/sub 2/ or 96 to 97% ThO/sub 2/--3 to 4% UO/sub 2/. Analyses of these data by nonlinear least-squares techniques demonstrated that the particle size distribution is lognormal. Variables involved in the numerical analyses include lognormal median size, lognormal standard deviation, and shear cut length. Sieve-fractionation data are presented for unirradiated bundles of stainless-steel-clad or Zircaloy-2-clad UO/sub 2/ or ThO/sub 2/--UO/sub 2/ sheared into lengths from 0.5 to 2.0 in. Data are also presented for irradiated single rods (sheared into lengths of 0.25 to 2.0 in.) of Zircaloy-2-clad UO/sub 2/ from BWRs and of Zircaloy-4-clad UO/sub 2/ from PWRs. Median particle sizes of UO/sub 2/ from shearing irradiated stainless-steel-clad fuel ranged from 103 to 182 ..mu..m; particle sizes of ThO/sub 2/--UO/sub 2/, under these same conditions, ranged from 137 to 202 ..mu..m. Similarly, median particle sizes of UO/sub 2/ from shearing unirradiated Zircaloy-2-clad fuel ranged from 230 to 957 ..mu..m. Irradiation levels of fuels from reactors ranged from 9,000 to 28,000 MWd/MTU. In general, particle sizes from shearing these irradiated fuels are larger than those from the unirradiated fuels; however, unirradiated fuel from vendors was not available for performing comparative shearing experiments. In addition, variations in particle size parameters pertaining to samples of a single vendor varied as much as those between different vendors. The fraction of fuel dislodged from the cladding is nearly proportional to the reciprocal of the shear cut length, until the cut length attains some minimum value below which all fuel is dislodged. Particles of fuel are generally elongated with a long-to-short axis ratio usually less than 3. Using parameters of the lognormal distribution estimates can be made of fractions of dislodged fuel having

  8. Fuel irradiation experience at Halden

    International Nuclear Information System (INIS)

    Vitanza, Carlo

    1996-01-01

    The OECD Halden Reactor Project is an international organisation devoted to improved safety and reliability of nuclear power station through an user-oriented experimental programme. A significant part of this programme consists of studies addressing fuel performance issues in a range of conditions realised in specialised irradiation. The key element of the irradiation carried out in the Halden reactor is the ability to monitor fuel performance parameters by means of in-pile instrumentation. The paper reviews some of the irradiation rigs and the related instrumentation and provides examples of experimental results on selected fuel performance items. In particular, current irradiation conducted on high/very high burn-up fuels are reviewed in some detail

  9. The behaviour under irradiation of molybdenum matrix for inert matrix fuel containing americium oxide (CerMet concept)

    Energy Technology Data Exchange (ETDEWEB)

    D' Agata, E., E-mail: elio.dagata@ec.europa.eu [European Commission, Joint Research Centre, Institute for Energy and Transport, P.O. Box 2, 1755 ZG Petten (Netherlands); Knol, S.; Fedorov, A.V. [Nuclear Research and Consultancy Group, P.O. Box 25, 1755 ZG Petten (Netherlands); Fernandez, A.; Somers, J. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany); Klaassen, F. [Nuclear Research and Consultancy Group, P.O. Box 25, 1755 ZG Petten (Netherlands)

    2015-10-15

    Americium is a strong contributor to the long term radiotoxicity of high activity nuclear waste. Transmutation by irradiation in nuclear reactors or Accelerator Driven System (ADS, subcritical reactors dedicated to transmutation) of long-lived nuclides like {sup 241}Am is therefore an option for the reduction of radiotoxicity of waste packages to be stored in a repository. In order to safely burn americium in a fast reactor or ADS, it must be incorporated in a matrix that could be metallic (CerMet target) or ceramic (CerCer target). One of the most promising matrix to incorporate Am is molybdenum. In order to address the issues (swelling, stability under irradiation, gas retention and release) of using Mo as matrix to transmute Am, two irradiation experiments have been conducted recently at the High Flux Reactor (HFR) in Petten (The Netherland) namely HELIOS and BODEX. The BODEX experiment is a separate effect test, where the molybdenum behaviour is studied without the presence of fission products using {sup 10}B to “produce” helium, the HELIOS experiment included a more representative fuel target with the presence of Am and fission product. This paper covers the results of Post Irradiation Examination (PIE) of the two irradiation experiments mentioned above where molybdenum behaviour has been deeply investigated as possible matrix to transmute americium (CerMet fuel target). The behaviour of molybdenum looks satisfying at operating temperature but at high temperature (above 1000 °C) more investigation should be performed.

  10. Results of the post-irradiation examination of a highly-rated mixed oxide fuel rod from the Mol 7B experiment

    International Nuclear Information System (INIS)

    Coquerelle, M.; Walker, C.T.; Whitlow, W.H.

    1980-01-01

    The experiment MOL 7B was carried out in a epithermal flux in the Belgian reactor BR2. The pin examined contained fuel of initial composition (Usub(0.7)Pusub(0.3))Osub(1.98). It had been irradiated to a maximum burn-up of 13.2 at% at a maximum linear power of 568Wcm -1 . The fuel was clad with coldworked stainless steel. Electron microprobe analysis indicated that a Cr 2 O 3 type oxide was the main constituent of the grey phases in the gap. A metallic phase on the fuel surface had apparently resulted from the mechanical compaction of fragments of cladding that had been depleted in chromium by oxidation. Thus the main components of the phase were iron and nickel. Chromium loss from the inner cladding surface was significant only in the upper regions of the pin. In pin sections that were metallographically examined sigma phase and carbides of the type M 23 C 6 were present at the grain boundaries of the cladding. Cladding corrosion was not an Arrhenius function of the cladding temperature: the amount of metal lost from the inner cladding surface decreased with rise in cladding temperature above 910 K. A contributor to metal loss was the mechanical detachment of fragments of cladding which reformed as a metallic layer on the surface of the fuel. Chromium depletion and sigma phase formation at grain boundaries lowered the cohesive forces between grains which were then mechanically detached. Chromium loss from grain boundaries is mainly the results of oxidation of the cladding by the mixed oxide fuel. Data are presented to support the view that the local average O/M of the fuel determined the rate of oxidation and consequently the extent of chromium depletion. Fuel-cladding mechanical interactions were weak in the upper regions of the pin where metal loss was small

  11. Oxide particle size distribution from shearing irradiated and unirradiated LWR fuels in Zircaloy and stainless steel cladding: significance for risk assessment

    International Nuclear Information System (INIS)

    Davis, W. Jr.; West, G.A.; Stacy, R.G.

    1979-01-01

    Sieve fractionation was performed with oxide particles dislodged during shearing of unirradiated or irradiated fuel bundles or single rods of UO 2 or 96 to 97% ThO 2 --3 to 4% UO 2 . Analyses of these data by nonlinear least-squares techniques demonstrated that the particle size distribution is lognormal. Variables involved in the numerical analyses include lognormal median size, lognormal standard deviation, and shear cut length. Sieve-fractionation data are presented for unirradiated bundles of stainless-steel-clad or Zircaloy-2-clad UO 2 or ThO 2 --UO 2 sheared into lengths from 0.5 to 2.0 in. Data are also presented for irradiated single rods (sheared into lengths of 0.25 to 2.0 in.) of Zircaloy-2-clad UO 2 from BWRs and of Zircaloy-4-clad UO 2 from PWRs. Median particle sizes of UO 2 from shearing irradiated stainless-steel-clad fuel ranged from 103 to 182 μm; particle sizes of ThO 2 --UO 2 , under these same conditions, ranged from 137 to 202 μm. Similarly, median particle sizes of UO 2 from shearing unirradiated Zircaloy-2-clad fuel ranged from 230 to 957 μm. Irradiation levels of fuels from reactors ranged from 9,000 to 28,000 MWd/MTU. In general, particle sizes from shearing these irradiated fuels are larger than those from the unirradiated fuels. In addition, variations in particle size parameters pertaining to samples of a single vendor varied as much as those between different vendors. The fraction of fuel dislodged from the cladding is nearly proportional to the reciprocal of the shear cut length, until the cut length attains some minimum value below which all fuel is dislodged. Particles of fuel are generally elongated with a long-to-short axis ratio usually less than 3. Using parameters of the lognormal distribution deduced from experimental data, realistic estimates can be made of fractions of dislodged fuel having dimensions less than specified values

  12. Production of mixed oxide fuel for fast reactor irradiation test by co-precipitation

    International Nuclear Information System (INIS)

    Todokoro, Akio; Masuda, Sumio; Naruki, Kaoru; Kaya, Akira; Koizumi, Masumichi

    1974-01-01

    Studies were made on the production of homogeneous mixed oxide by co-precipitation. Experiments were made on the effects of the addition rate of ammonia water, precipitation temperature, aging time of co-precipitate, and pH value. Plutonium refined by anion exchange was mixed with solution of uranium. The concentration of free acid in the mixed solution was adjusted to 1.5-2.0 M, and the total volume of the solution was made 3.01. The weight of Pu and U in the solution was 100g. The solution was kept at a definite temperature while being stirred. Concentrated ammonia solution was added to the solution at a definite rate. The precipitate thus formed was filtrated after aging, then dried for 24 hours at 100 +- 2 0 C. Dried co-precipitate was calcinated for 1 hr at 550 0 C. The reduction for 4 hours at 800 0 C gave the mixed powder of PuO 2 and UO 2 . After pressing, the powder was sintered for 2 hours at 1700 0 C. The shrinkage ratio decreased as the activity and tap density of the original powder increased. The activity determined by specific surface area increased as the rate of ammonia water addition increased, and as the precipitation temperature rose. Tap density was independent of the rate of addition of ammonia water. The activity of the powder increased and the tap density decreased as the aging time of precipitate increased. (Fukutomi, T.)

  13. Transportation of irradiated fuel elements

    International Nuclear Information System (INIS)

    1980-01-01

    A critique is presented of current methods of transporting spent nuclear fuel and the inadequacies of the associated contingency plans, with particular reference to the transportation of irradiated fuel through London. Anti-nuclear and pro-nuclear arguments are presented on a number of factors, including tests on flasks, levels of radiation exposure, routine transport arrangements and contingency arrangements. (U.K.)

  14. Annealing tests of in-pile irradiated oxide coated U-Mo/Al-Si dispersed nuclear fuel

    Science.gov (United States)

    Zweifel, T.; Valot, Ch.; Pontillon, Y.; Lamontagne, J.; Vermersch, A.; Barrallier, L.; Blay, T.; Petry, W.; Palancher, H.

    2014-09-01

    U-Mo/Al based nuclear fuels have been worldwide considered as a promising high density fuel for the conversion of high flux research reactors from highly enriched uranium to lower enrichment. In this paper, we present the annealing test up to 1800 °C of in-pile irradiated U-Mo/Al-Si fuel plate samples. More than 70% of the fission gases (FGs) are released during two major FG release peaks around 500 °C and 670 °C. Additional characterisations of the samples by XRD, EPMA and SEM suggest that up to 500 °C FGs are released from IDL/matrix interfaces. The second peak at 670 °C representing the main release of FGs originates from the interaction between U-Mo and matrix in the vicinity of the cladding.

  15. UK experience on fuel and cladding interaction in oxide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Batey, W [Dounreay Experimental Reactor Establishment, Thurso, Caithness (United Kingdom); Findlay, J R [AERE, Harwell, Didcot, Oxon (United Kingdom)

    1977-04-01

    The occurrence of fuel cladding interactions in fast reactor fuels has been observed in UK irradiations over a period of years. Chemical incompatibility between fuel and clad represents a potential source of failure and has, on this account, been studied using a variety of techniques. The principal fuel of interest to the UK for fast reactor application is mixed uranium plutonium oxide clad in stainless steel and it is in this field that the majority of work has been concentrated. Some consideration has been given to carbide fuels, because of their application as an advanced fuel. This experience is described in the accompanying paper. Several complementary initiatives have been followed to investigate the interactions in oxide fuel. The principal source of experimental information is from the experimental fuel irradiation programme in the Dounreay Fast Reactor (DFR). Supporting information has been obtained from irradiation programmes in Materials Testing Reactors (MTR). Conditions approaching those in a fast reactor are obtained and the effects of specific variables have been examined in specifically designed experiments. Out-of-reactor experiments have been used to determine the limits of fuel and cladding compatibility and also to give indications of corrosion The observations from all experiments have been examined in the light of thermo-dynamic predictions of fuel behaviour to assess the relative significance of various observations and operating conditions. An experimental programme to control and limit the interactions in oxide fuel is being followed.

  16. UK experience on fuel and cladding interaction in oxide fuels

    International Nuclear Information System (INIS)

    Batey, W.; Findlay, J.R.

    1977-01-01

    The occurrence of fuel cladding interactions in fast reactor fuels has been observed in UK irradiations over a period of years. Chemical incompatibility between fuel and clad represents a potential source of failure and has, on this account, been studied using a variety of techniques. The principal fuel of interest to the UK for fast reactor application is mixed uranium plutonium oxide clad in stainless steel and it is in this field that the majority of work has been concentrated. Some consideration has been given to carbide fuels, because of their application as an advanced fuel. This experience is described in the accompanying paper. Several complementary initiatives have been followed to investigate the interactions in oxide fuel. The principal source of experimental information is from the experimental fuel irradiation programme in the Dounreay Fast Reactor (DFR). Supporting information has been obtained from irradiation programmes in Materials Testing Reactors (MTR). Conditions approaching those in a fast reactor are obtained and the effects of specific variables have been examined in specifically designed experiments. Out-of-reactor experiments have been used to determine the limits of fuel and cladding compatibility and also to give indications of corrosion The observations from all experiments have been examined in the light of thermo-dynamic predictions of fuel behaviour to assess the relative significance of various observations and operating conditions. An experimental programme to control and limit the interactions in oxide fuel is being followed

  17. Effect of cladding defect size on the oxidation of irradiated spent LWR [light-water reactor] fuel below 3690C

    International Nuclear Information System (INIS)

    Einziger, R.E.; Strain, R.V.

    1984-01-01

    Tests on spent fuel fragments and rod segments were conducted between 250 and 360 0 C to relate temperature, defect size, and fuel oxidation rate with time-to-cladding-splitting. Defect sizes from 760 μm diameter down to 8 μm, the size of an SCC type breach, were used. Above 283 0 C, the time-to-cladding-splitting was longer for the smaller defects. The enhancement of the incubation time by smaller defects steadily decreased with temperature and was not detected at 250 0 C. 18 refs., 10 figs., 4 tabs

  18. The uranium and thorium separation in the chemical reprocessing of the irradiated fuel of thorium and uranium mixed oxides

    International Nuclear Information System (INIS)

    Oliveira, E.F. de.

    1984-09-01

    A bibliographic research has been carried out for reprocessing techniques of irradiated thorium fuel from nuclear reactors. The Thorex/Hoechst process has been specially considered to establish a method for reprocessing thorium-uranium fuel from PWR. After a series of cold tests performed in laboratory it was possible to set the behavior of several parameters affecting the Thorex/Hoechst process. Some comments and suggestions are presented for modifications in the process flosheet conditions. A discussion is carried out for operational conditions such as the aqueous to organic flow ratio the acidity of strip and scrub solutions in the process steps for thorium and uranium recovery. The operation diagrams have been constructed using equilibrium experimental data which correspond to conditions observed in laboratory. (Author) [pt

  19. Transport of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    1980-01-01

    In response to public interest in the transport by rail through London of containers of irradiated fuel elements on their way from nuclear power stations to Windscale, the Central Electricity Generating Board and British Rail held three information meetings in London in January 1980. One meeting was for representatives of London Borough Councils and Members of Parliament with a known interest in the subject, and the others were for press, radio and television journalists. This booklet contains the main points made by the principal speakers from the CEGB and BR. (The points covered include: brief description of the fuel cycle; effect of the fission process in producing plutonium and fission products in the fuel element; fuel transport; the fuel flasks; protection against accidents; experience of transporting fuel). (U.K.)

  20. Irradiation performance of metallic fuels

    International Nuclear Information System (INIS)

    Pahl, R.G.; Lahm, C.E.; Porter, D.L.; Batte, G.L.; Hofman, G.L.

    1989-01-01

    Argonne National Laboratory has been working for the past five years to develop and demonstrate the Integral Fast Reactor (IFR) concept. The concept involves a closed system for fast-reactor power generation and on-site fuel reprocessing, both designed specifically around the use of metallic fuel. The Experimental Breeder Reactor-II (EBR-II) has used metallic fuel for all of its 25-year life. In 1985, tests were begun to examine the irradiation performance of advanced-design metallic fuel systems based on U-Zr or U-Pu-Zr fuels. These tests have demonstrated the viable performance of these fuel systems to high burnup. The initial testing program will be described in this paper. 2 figs

  1. Post irradiation test report of irradiated DUPIC simulated fuel

    International Nuclear Information System (INIS)

    Yang, Myung Seung; Jung, I. H.; Moon, J. S. and others

    2001-12-01

    The post-irradiation examination of irradiated DUPIC (Direct Use of Spent PWR Fuel in CANDU Reactors) simulated fuel in HANARO was performed at IMEF (Irradiated Material Examination Facility) in KAERI during 6 months from October 1999 to March 2000. The objectives of this post-irradiation test are i) the integrity of the capsule to be used for DUPIC fuel, ii) ensuring the irradiation requirements of DUPIC fuel at HANARO, iii) performance verification in-core behavior at HANARO of DUPIC simulated fuel, iv) establishing and improvement the data base for DUPIC fuel performance verification codes, and v) establishing the irradiation procedure in HANARO for DUPIC fuel. The post-irradiation examination performed are γ-scanning, profilometry, density, hardness, observation the microstructure and fission product distribution by optical microscope and electron probe microanalyser (EPMA)

  2. Uranium plutonium oxide fuels

    International Nuclear Information System (INIS)

    Cox, C.M.; Leggett, R.D.; Weber, E.T.

    1981-01-01

    Uranium plutonium oxide is the principal fuel material for liquid metal fast breeder reactors (LMFBR's) throughout the world. Development of this material has been a reasonably straightforward evolution from the UO 2 used routinely in the light water reactor (LWR's); but, because of the lower neutron capture cross sections and much lower coolant pressures in the sodium cooled LMFBR's, the fuel is operated to much higher discharge exposures than that of a LWR. A typical LMFBR fuel assembly is shown. Depending on the required power output and the configuration of the reactor, some 70 to 400 such fuel assemblies are clustered to form the core. There is a wide variation in cross section and length of the assemblies where the increasing size reflects a chronological increase in plant size and power output as well as considerations of decreasing the net fuel cycle cost. Design and performance characteristics are described

  3. Management of irradiated CANDU fuel

    International Nuclear Information System (INIS)

    Lupien, Mario

    1985-01-01

    The nuclear industry, like any other industrial activity, generates waste and, since these radioactive products are known to be hazardous both to man and his natural environment, they are subject to stringent controls. The irradiated fuel is also highly radioactive and remains so for thousands of years. It is estimated that by the year 2000, nuclear reactors in Canada alone will have produced some 50 Gg of radioactive fuel which is stored at the nuclear plant site itself. The nuclear industry plays a leading role in the research and development effort to find suitable waste-management methods. Its R and D programs cover many scientific fields, including chemistry, and therefore demand a considerable amount of coordination. The knowledge acquired in this multidisciplinary context should form a basis for solving many of today's industrial-waste problems. This paper describes the various stages in the long management process. In the medium term, the irradiated fuel will be stored in surface installations but the long-term solution proposed is to emplace the used fuel or the fuel recycle waste deep underground in a stable geologic formation

  4. Transportation of irradiated fuel elements

    International Nuclear Information System (INIS)

    Preece, A.H.

    1980-01-01

    The report falls under the headings: introduction (explaining the special interest of the London Borough of Brent, as forming part of the route for transportation of irradiated fuel elements); nuclear power (with special reference to transport of spent fuel and radioactive wastes); the flask aspect (design, safety regulations, criticisms, tests, etc.); the accident aspect (working manual for rail staff, train formation, responsibility, postulated accident situations); the emergency arrangements aspect; the monitoring aspect (health and safety reports); legislation; contingency plans; radiation - relevant background information. (U.K.)

  5. Solid Oxide Fuel Cell

    DEFF Research Database (Denmark)

    2010-01-01

    The solid oxide fuel cell comprising a metallic support material, an active anode layer consisting of a good hydrocarbon cracking catalyst, an electrolyte layer, an active cathode layer, and a transition layer consisting of preferably a mixture of LSM and a ferrite to the cathode current collector...

  6. Pyroelectrochemical process for reprocessing irradiated nuclear fuels

    International Nuclear Information System (INIS)

    Brambilla, G.; Sartorelli, A.

    1982-01-01

    A pyroelectrochemical process for reprocessing irradiated fast reactor mixed oxide or carbide fuels is described. The fuel is dissolved in a bath of molten alkali metal sulfates. The Pu(SO 4 ) 2 formed in the bath is thermally decomposed, leaving crystalline PuO 2 on the bottom of the reaction vessel. Electrodes are then introduced into the bath, and UO 2 is deposited on the cathode. Alternatively, both UO 2 and PuO 2 may be electrodeposited. The molten salts, after decontamination by precipitating the fission products dissolved in the bath by introducing basic agents such as oxides, carbonates, or hydroxides, may be recycled. Since it is not possible to remove cesium from the molten salt bath, periodic disposal and partial renewal with fresh salts is necessary. The melted salts that contain the fission products are conditioned for disposal by embedding them in a metallic matrix

  7. Dry storage of irradiated nuclear fuels and vitrified wastes

    International Nuclear Information System (INIS)

    Deacon, D.

    1982-01-01

    A review is given of the work of GEC Energy Systems Ltd. over the years in the dry storage of irradiated fuel. The dry-storage module (designated as Cell 4) for irradiated magnox fuel recently constructed at Wylfa nuclear power station is described. Development work on the long-term dry storage of irradiated oxide fuels is reported. Four different methods of storage are compared. These are the pond, vault, cask and caisson stores. It is concluded that there are important advantages with the passive air-cooled ESL dry stove. (U.K.)

  8. Gamma scanning of the irradiated HANARO fuels

    International Nuclear Information System (INIS)

    Hong, Kwon Pyo; Lee, K. S.; Park, D. G.; Baik, S. Y.; Song, W. S.; Kim, T. Y.; Seo, C. K.

    1997-02-01

    To conform the burnup state of the fuels, we have transported the irradiated HANARO fuels from the reactor to IMEF (Irradiated Material Examination Facility), and executed gamma scanning for the fuels. By measuring the gamma-rays from the irradiated fuels we could see the features of the relative burnup distributions in the fuel bundles. All of 17 fuel bundles were taken in and out between HANARO and IMEF from March till August in 1996, and we carried out the related regulations. Longitudinal gamma scanning and angular gamma scanning are done for each fuel bundle without dismantlement of the bundles. (author). 5 tabs., 25 figs

  9. HANARO fuel irradiation test (II): revision

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, D. S.; Kim, H.; Chae, H. T.; Lee, C. S.; Kim, B. G.; Lee, C. B

    2001-04-01

    In order to fulfill the requirement to prove HANARO fuel integrity when irradiated at a power greater than 112.8 kW/m, which was imposed during HANARO licensing, and to verify the irradiation performance of HANARO fuel, the in-pile irradiation test of HANARO fuel has been performed. Two types of test fuel, the un-instrumented Type A fuel for higher burnup irradiation in shorter period than the driver fuel and the instrumented Type B fuel for higher linear heat rate and precise measurement of irradiation conditions, have been designed and fabricated. The test fuel assemblies were irradiated in HANARO. The two Type A fuel assemblies were intended to be irradiated to medium and high burnup and have been discharged after 69.9 at% and 85.5 at% peak burnup, respectively. Type B fuel assembly was intended to be irradiated at high power with different instrumentations and achieved a maximum power higher than 120 kW/m without losing its integrity and without showing any irregular behavior. The Type A fuel assemblies were cooled for about 6 months and transported to the IMEF(Irradiated Material Examination Facility) for consequent evaluation. Detailed non-destructive and destructive PIE (Post-Irradiation Examination), such as the measurement of burnup distribution, fuel swelling, clad corrosion, dimensional changes, fuel rod bending strength, micro-structure, etc., has been performed. The measured results have been analysed/compared with the predicted performance values and the design criteria. It has been verified that HANARO fuel maintains proper in-pile performance and integrity even at the high power of 120 kw/m up to the high burnup of 85 at%. This report is the revision of KAERI/TR-1816/2001 on the irradiation test for HANARO fuel.

  10. Microstructure characterizaton of advanced oxide fuel

    International Nuclear Information System (INIS)

    Rasmussen, D.E.; Gerber, E.W.; McCord, R.B.

    1977-01-01

    Preirradiation porosity, grain size, and microcomposition characteristics are presented for selected advanced oxide (PuO 2 -UO 2 ) LMFBR developmental fuels fabricated for irradiation testing in EBR-II. Quantitative microscopy, electron microprobe analysis, and a recently developed quantitative autoradiographic technique are utilized to relate microstructure characteristics to fabrication parameters

  11. Development of advanced neutron radiography for inspection on irradiated fuels and materials (2). Observation of hydride and oxide film on zircaloy cladding by using neutron radiography

    International Nuclear Information System (INIS)

    Yasuda, Ryou; Nakata, Masahito; Mastubayashi, Masahito; Harada, Katsuya

    2001-02-01

    Neutron radiography has been used as available diagnosis method of integrity on irradiated fuels, and has not been employed for estimating hydride and oxide film, which are influenced on integrity of Zircaloy cladding. Preliminary tests for PIE were carried out to assess possibility of neutron radiography as evaluation tool for hydrided and oxide film on the cladding. In these experiments, Zircaloy claddings with controlled amount of hydrogen absorption (200, 500, and 1000ppm) and thickness of oxide film were radiographed in center axis and in side directions of cladding tube by neutron imaging plate method. It is noted that thickness of oxide film was formed range from 7 μ m to 70 μ m at various temperatures (973, 1173, and 1323K) under steam atmosphere on the Zircaloy claddings. CT (Computed Tomography) restructure calculation was carried out to obtain cross section image of the claddings non-destructively. The Radiographs were qualitatively investigated about structure formation area and dependence of hydrogen absorption amount on PSL (Photo Simulated Luminescence) and CT values using by image analysis processor. At the results of imaging plate test, obvious difference was not found out between hydride formation (except for 1000ppm cladding) and standard claddings in side direction image. However, on the center axis direction image, outer circumference in the cladding cross-section that corresponded with hydride segregation area became blacker. In the case of oxide film formed cladding images, although oxide film could not find out on all speciments in the radiographs taken at the center axis and side directions, cross-section of claddings heat-processed at 973K showed appreciable blackness increasing with oxide film thickness on the radiographs. On the other hand, there is no effective difference between images of oxide film formed claddings processed at 1173K and 1323K and that of standard cladding. In CT image of 1000ppm hydrogen absorbed cladding, it is

  12. Gamma irradiation plants using reactor fuel elements

    International Nuclear Information System (INIS)

    Suckow, W.

    1976-11-01

    Recent irradiation plants utilizing fuel elements are described. Criteria for optimizing such plants, evaluation of the plants realized so far, and applications for the facilities are discussed. (author)

  13. Transport and reprocessing of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Lenail, B.

    1981-01-01

    This contribution deals with transport and packaging of oxide fuel from and to the Cogema reprocessing plant at La Hague (France). After a general discussion of nuclear fuel and the fuel cycle, the main aspects of transport and reprocessing of oxide fuel are analysed. (Auth.)

  14. KEY RESULTS FROM IRRADIATION AND POST-IRRADIATION EXAMINATION OF AGR-1 UCO TRISO FUEL

    Energy Technology Data Exchange (ETDEWEB)

    Demkowicz, Paul A.; Hunn, John D.; Petti, David A.; Morris, Robert N.

    2016-11-01

    The AGR-1 irradiation experiment was performed as the first test of tristructural isotropic (TRISO) fuel in the US Advanced Gas Reactor Fuel Development and Qualification Program. The experiment consisted of 72 right cylinder fuel compacts containing approximately 3×105 coated fuel particles with uranium oxide/uranium carbide (UCO) fuel kernels. The fuel was irradiated in the Advanced Test Reactor for a total of 620 effective full power days. Fuel burnup ranged from 11.3 to 19.6% fissions per initial metal atom and time average, volume average irradiation temperatures of the individual compacts ranged from 955 to 1136°C. This paper focuses on key results from the irradiation and post-irradiation examination, which revealed a robust fuel with excellent performance characteristics under the conditions tested and have significantly improved the understanding of UCO coated particle fuel irradiation behavior within the US program. The fuel exhibited a very low incidence of TRISO coating failure during irradiation and post-irradiation safety testing at temperatures up to 1800°C. Advanced PIE methods have allowed particles with SiC coating failure to be isolated and meticulously examined, which has elucidated the specific causes of SiC failure in these specimens. The level of fission product release from the fuel during irradiation and post-irradiation safety testing has been studied in detail. Results indicated very low release of krypton and cesium through intact SiC and modest release of europium and strontium, while also confirming the potential for significant silver release through the coatings depending on irradiation conditions. Focused study of fission products within the coating layers of irradiated particles down to nanometer length scales has provided new insights into fission product transport through the coating layers and the role various fission products may have on coating integrity. The broader implications of these results and the application of

  15. HANARO fuel irradiation test(II)

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, D. S.; Kim, H. R.; Chae, H. T.; Lee, B. C.; Lee, C. S.; Kim, B. G.; Lee, C. B.; Hwang, W

    2001-04-01

    In order to fulfill the requirement to prove HANARO fuel integrity when irradiated at a power greater than 112.8 kW/m, which was imposed during HANARO licensing, and to verify the irradiation performance of HANARO fuel, the in-pile irradiation test of HANARO fuel has been performed. Two types of test fuel, the un-instrumented Type A fuel for higher burnup irradiation in shorter period than the driver fuel and the instrumented Type B fuel for higher linear heat rate and precise measurement of irradiation conditions, have been designed and fabricated. The test fuel assemblies were irradiated in HANARO. The two Type A fuel assemblies were intended to be irradiated to medium and high burnup and have been discharged after 69.9 at% and 85.5 at% peak burnup, respectively. Type B fuel assembly was intended to be irradiatied at high power with different instrumentations and achieved a maximum power higher than 120 kW/m without losing its integrity and without showing any irregular behavior. The Type A fuel assemblies were cooled for about 6 months and transported to the IMEF(Irradiated Material Examination Facility) for consequent evaluation. Detailed non-destructive and destructive PIE (Post-Irradiation Examination), such as the measurement of burnup distribution, fuel swelling, clad corrosion, dimensional changes, fuel rod bending strength, micro-structure, etc., has been performed. The measured results have been analysed/compared with the predicted performance values and the design criteria. It has been verified that HANARO fuel maintains proper in-pile performance and integrity even at the high power of 120 kw/m up to the high burnup of 85 at%.

  16. Characterization and heading of irradiated fuels and their chemical analogs

    International Nuclear Information System (INIS)

    Serrano, J. A.

    2000-01-01

    This work presents results of leaching experiments under deionized water and under synthetic granite at room temperature in air using spent fuel (UO 2 and MOX LWR fuels) and the chemical analogues, natural UO 2 and SIMFUEL. The experimental conditions and procedure for irradiated and non-irradiated materials were kept similar as much as possible. Also dissolution behaviour studies of preoxidised LWR UO 2 and MOX spent fuel up to different on the oxidation degree. For both fuel types, UO 2 and MOX, the fission products considered showed a fractional release normalised to uranium higher than 1, due to either the larger inventory at preferential leaching zones, such as, grain boundaries or to the inherent higher solubility of some of these elements. In contrast to fission products, the fractional release of PU from the UO 2 fuel was not affected by the oxidation level. Finally a thermodynamic study of the experimental leaching results obtained in this work was performed. (Author)

  17. Irradiated test fuel shipment plan for the LWR MOX fuel irradiation test project

    International Nuclear Information System (INIS)

    Shappert, L.B.; Dickerson, L.S.; Ludwig, S.B.

    1998-01-01

    This document outlines the responsibilities of DOE, DOE contractors, the commercial carrier, and other organizations participating in a shipping campaign of irradiated test specimen capsules containing mixed-oxide (MOX) fuel from the Idaho National Engineering and Environmental Laboratory (INEEL) to the Oak Ridge National Laboratory (ORNL). The shipments described here will be conducted according to applicable regulations of the US Department of Transportation (DOT), US Nuclear Regulatory Commission (NRC), and all applicable DOE Orders. This Irradiated Test Fuel Shipment Plan for the LWR MOX Fuel Irradiation Test Project addresses the shipments of a small number of irradiated test specimen capsules and has been reviewed and agreed to by INEEL and ORNL (as participants in the shipment campaign). Minor refinements to data entries in this plan, such as actual shipment dates, exact quantities and characteristics of materials to be shipped, and final approved shipment routing, will be communicated between the shipper, receiver, and carrier, as needed, using faxes, e-mail, official shipping papers, or other backup documents (e.g., shipment safety evaluations). Any major changes in responsibilities or data beyond refinements of dates and quantities of material will be prepared as additional revisions to this document and will undergo a full review and approval cycle

  18. RECH-1 test fuel irradiation status report

    International Nuclear Information System (INIS)

    Marin, J.; Lisboa, J.; Olivares, L.; Chavez, J.

    2005-01-01

    Since May 2003, one RECH-1 fuel element has been submitted to irradiation at the HFR-Petten, Holland. By November 2004 the irradiation has achieved its pursued goal of 55% burn up. This irradiation qualification service will finish in the year 2005 with PIE tests, as established in a contractual agreement between the IAEA, NRG, and CCHEN. This report presents the objectives and the current results of this fuel qualification under irradiation. Besides, a brief description of CHI/4/021, IAEA's Technical Cooperation Project that has supported this irradiation test, is also presented here. (author)

  19. Irradiation behaviors of coated fuel particles, (3)

    International Nuclear Information System (INIS)

    Fukuda, Kousaku; Kashimura, Satoru; Iwamoto, Kazumi; Ikawa, Katsuichi

    1980-07-01

    This report is concerning to the irradiation experiments of the coated fuel particles, which were performed by 72F-6A and 72F-7A capsules in JMTR. The coated particles referred to the preliminary design of VHTR were prepared for the experiments in 1972 and 1973. 72F-6A capsule was irradiated at G-10 hole of JMTR fuel zone for 2 reactor cycles, and 72F-7A capsule had been planned to be irradiated at the same irradiation hole before 72F-6A. However, due to slight leak of the gaseous fission products into the vacuum system controlling irradiation temperature, irradiation of 72F-7A capsule was ceased after 85 hrs since the beginning. In the post irradiation examination, inspection to surface appearance, ceramography, X-ray microradiography and acid leaching for the irradiated particle samples were made, and crushing strength of the two particle samples was measured. (author)

  20. Results of the irradiation of mixed UO{sub 2} - PuO{sub 2} oxide fuel elements; Resultats d'irradiation d'elements combustibles en oxyde mixte UO{sub 2} - PuO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Mikailoff, H.; Mustelier, J.P.; Bloch, J.; Ezran, L.; Hayet, L. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    In order to study the behaviour of fuel elements used for the first charge of the reactor Rapsodie, a first batch of eleven needles was irradiated in the reactor EL3 and then examined. These needles (having a shape very similar lo that of the actual needles to be used) were made up of a stack of sintered mixed-oxide pellets: UO{sub 2} containing about 10 per cent of PuO{sub 2}. The density was 85 to 97 per cent of the theoretical, value. The diametral gap between the oxide and the stainless steel can was between 0,06 and 0,27 mm. The specific powers varied from 1230 to 2700 W/cm{sup 3} and the can temperature was between 450 and 630 C. The maximum burn-up attained was 22000 MW days/tonne. Examination of the needles (metrology, radiography and {gamma}-spectrography) revealed certain macroscopic changes, and the evolution of the fuel was shown by micrographic studies. These observations were used, together with flux measurements results, to calculate the temperature distribution inside the fuel. The volume of the fission gas produced was measured in some of the samples; the results are interpreted taking into account the temperature distribution in the oxide and the burn-up attained. Finally a study was made both of the behaviour of a fuel element whose central part was molten during irradiation, and of the effect of sodium which had penetrated into some of the samples following can rupture. (author) [French] Afin d'etudier le comportement des elements combustibles destines a la premiere charge du reacteur Rapsodie, une premiere serie de onze aiguilles a ete irradiee dans le reacteur EL3 et examinee apres irradiation. Ces aiguilles (aux caracteristiques geometriques tres proches de celles des aiguilles definitives) etaient constituees d'un empilement de pastilles frittees en oxyde mixte UO{sub 2} a 10 pour cent environ de PuO{sub 2}, dont la densite etait comprise entre 85 et 97 pour cent de la densite theorique. Le jeu diametral entre l'oxyde et la

  1. Results of the irradiation of mixed UO{sub 2} - PuO{sub 2} oxide fuel elements; Resultats d'irradiation d'elements combustibles en oxyde mixte UO{sub 2} - PuO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Mikailoff, H; Mustelier, J P; Bloch, J; Ezran, L; Hayet, L [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    In order to study the behaviour of fuel elements used for the first charge of the reactor Rapsodie, a first batch of eleven needles was irradiated in the reactor EL3 and then examined. These needles (having a shape very similar lo that of the actual needles to be used) were made up of a stack of sintered mixed-oxide pellets: UO{sub 2} containing about 10 per cent of PuO{sub 2}. The density was 85 to 97 per cent of the theoretical, value. The diametral gap between the oxide and the stainless steel can was between 0,06 and 0,27 mm. The specific powers varied from 1230 to 2700 W/cm{sup 3} and the can temperature was between 450 and 630 C. The maximum burn-up attained was 22000 MW days/tonne. Examination of the needles (metrology, radiography and {gamma}-spectrography) revealed certain macroscopic changes, and the evolution of the fuel was shown by micrographic studies. These observations were used, together with flux measurements results, to calculate the temperature distribution inside the fuel. The volume of the fission gas produced was measured in some of the samples; the results are interpreted taking into account the temperature distribution in the oxide and the burn-up attained. Finally a study was made both of the behaviour of a fuel element whose central part was molten during irradiation, and of the effect of sodium which had penetrated into some of the samples following can rupture. (author) [French] Afin d'etudier le comportement des elements combustibles destines a la premiere charge du reacteur Rapsodie, une premiere serie de onze aiguilles a ete irradiee dans le reacteur EL3 et examinee apres irradiation. Ces aiguilles (aux caracteristiques geometriques tres proches de celles des aiguilles definitives) etaient constituees d'un empilement de pastilles frittees en oxyde mixte UO{sub 2} a 10 pour cent environ de PuO{sub 2}, dont la densite etait comprise entre 85 et 97 pour cent de la densite theorique. Le jeu diametral entre l'oxyde et la gaine en acier

  2. Nonintrusive irradiated fuel inventory confirmation technique

    International Nuclear Information System (INIS)

    Dowdy, E.J.; Nicholson, N.; Caldwell, J.T.

    1980-01-01

    Successful tests showing correlation between the intensity of the Cerenkov glow surrounding irradiated fuel assemblies in water-filled spent fuel storage ponds and the exposure and cooling times of assemblies have been concluded. Fieldable instruments used in subsequent tests confirmed that such measurements can be made easily and rapidly, without fuel assembly movement or the introduction of apparatus into the storage ponds

  3. Irradiation effects on thermal properties of LWR hydride fuel

    Energy Technology Data Exchange (ETDEWEB)

    Terrani, Kurt, E-mail: terrani@berkeley.edu [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States); Balooch, Mehdi [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States); Carpenter, David; Kohse, Gordon [Massachusetts Institute of Technology, 138 Albany St., Cambridge, MA 02139 (United States); Keiser, Dennis; Meyer, Mitchell [Idaho National Laboratory, Idaho Falls, ID 83415 (United States); Olander, Donald [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States)

    2017-04-01

    Three hydride mini-fuel rods were fabricated and irradiated at the MIT nuclear reactor with a maximum burnup of 0.31% FIMA or ∼5 MWd/kgU equivalent oxide fuel burnup. Fuel rods consisted of uranium-zirconium hydride (U (30 wt%)ZrH{sub 1.6}) pellets clad inside a LWR Zircaloy-2 tubing. The gap between the fuel and the cladding was filled with lead-bismuth eutectic alloy to eliminate the gas gap and the large temperature drop across it. Each mini-fuel rod was instrumented with two thermocouples with tips that are axially located halfway through the fuel centerline and cladding surface. In-pile temperature measurements enabled calculation of thermal conductivity in this fuel as a function of temperature and burnup. In-pile thermal conductivity at the beginning of test agreed well with out-of-pile measurements on unirradiated fuel and decreased rapidly with burnup.

  4. Irradiated nuclear fuel transport from Japan to Europe

    International Nuclear Information System (INIS)

    Kavanagh, M.T.; Shimoyama, S.

    1976-01-01

    Irradiated nuclear fuel has been transported from Japan to Europe since 1969, although U.K. experience goes back almost two decades. Both magnox and oxide fuel have been transported, and the technical requirements associated with each type of fuel are outlined. The specialized ships used by British Nuclear Fuels Limited (BNFL) for this transport are described, as well as the ships being developed for future use in the Japan trade. The ship requirements are related to the regulatory position both in the United Kingdom and internationally, and the Japanese regulatory requirements are described. Finally, specific operational experience of a Japanese reactor operator is described

  5. Status of irradiation testing and PIE of MOX (Pu-containing) fuel

    International Nuclear Information System (INIS)

    Dimayuga, F.C.; Zhou, Y.N.; Ryz, M.A.

    1995-01-01

    This paper describes AECL's mixed oxide (MOX) fuel-irradiation and post-irradiation examination (PIE) program. Post-irradiation examination results of two major irradiation experiments involving several (U, Pu)O 2 fuel bundles are highlighted. One experiment involved bundles irradiated to burnups ranging fro 400 to 1200 MWh/kgHe in the Nuclear Power Demonstration (NPD) reactor. The other experiment consisted of several (U, Pu)O 2 bundles irradiated to burnups of up to 500 Mwh/kgHe in the National Research Universal (NRU) reactor. Results of these experiments demonstrate the excellent performance of CANDU MOX fuel. This paper also outlines the status of current MOX fuel irradiation tests, including the irradiation of various (U, Pu)O 2 bundles. The strategic importance of MOX fuel to CANDU fuel-cycle flexibility is discussed. (author)

  6. MOX fuel irradiation behavior in steady state (irradiation test in HBWR)

    Energy Technology Data Exchange (ETDEWEB)

    Kohno, S; Kamimura, K [Power Reactor and Nuclear Fuel Development Corp., Naka, Ibaraki (Japan)

    1997-08-01

    Two rigs of plutonium-uranium oxide (MOX) fuel rods have been irradiated in Halden boiling water reactor (HBWR) to investigate high burnup MOX fuel behavior for thermal reactor. The objective of irradiation tests is to investigate fuel behavior as influenced by pellet shape, pellet surface treatment, pellet-cladding gap size and MOX fuel powder preparations process. The two rigs have instrumentations for in-pile measurements of the fuel center-line temperature, plenum pressure, cladding elongation and fuel stack length change. The data, taken through in-operation instrumentation, have been analysed and compared with those from post-irradiation examination. The following observations are made: 1) PNC MOX fuels have achieved high burn-up as 59GWd/tMOX (67GWd/tM) at pellet peak without failure; 2) there was no significant difference in fission gas release fraction between PNC MOX fuels and UO{sub 2} fuels; 3) fission gas release from the co-converted fuel was lower than that from the mechanically blended fuel; 4) gap conductance was evaluated to decrease gradually with burn-up and to get stable in high burn-up region. 5) no evident difference of onset LHR for PCMI in experimental parameters (pellet shape and pellet-cladding gap size) was observed, but it decreased with burn-up. (author). 13 refs, 15 figs, 3 tabs.

  7. Status of fuel irradiation tests in HANARO

    International Nuclear Information System (INIS)

    Kim, Hark Rho; Lee, Choong Sung; Lee, Kye Hong; Jun, Byung Jin; Lee, Ji Bok

    1999-01-01

    Since 1996 after finishing the long-term operational test, HANARO (High-Flux Advanced Neutron Application Reactor) has been extensively used for material irradiation tests, beam application research, radioisotope production and neutron activation analysis. This paper presents the fuel irradiation test activities which are now conducted or have been finished in HANARO. KAERI developed LEU fuel using an atomization method for the research reactors. Using this LEU, we have set up and conducted three irradiation programs: (1) medium power irradiation test using a short-length mini-assembly made of 3.15 gU/cc U 3 Si, (2) high power irradiation tests using full-length test assemblies made of 3.15 gU/cc U 3 Si, and (3) irradiation test using a short-length mini-plate made of 4.8 gU/cc U 3 Si 2 . DUPIC (Direct Use of spent PWR fuels in CANDU Reactors) simulation fuel pellets, of which compositions are very similar to DUPIC pellets to keep the similarity in the thermo-mechanical property, were developed. Three mini-elements including 5 pellets each were installed in a capsule. This capsule has been irradiated for 2 months and unloaded from the HANARO core at the end of September 1999. Another very important test is the HANARO fuel qualification program at high power, which is required to resolve the licensing issue. This test is imposed on the HANARO operation license due to insufficient test data under high power environment. To resolve this licensing issue, we have been carrying out the required irradiation tests and PIE (Post-irradiation Examination) tests. Through this program, it is believed that the resolution of the licensing issue is achieved. In addition to these programs, several fuel test plans are under way. Through these vigorous activities of fuel irradiation test programs, HANARO is sure to significantly contribute to the national nuclear R and D programs. (author)

  8. Advanced disassembling technique of irradiated driver fuel assembly for continuous irradiation of fuel pins

    International Nuclear Information System (INIS)

    Ichikawa, Shoichi; Haga, Hiroyuki; Katsuyama, Kozo; Maeda, Koji; Nishinoiri, Kenji

    2012-01-01

    It was necessary to carry out continuous irradiation tests in order to obtain the irradiation data of high burn-up fuel and high neutron dose material for FaCT (Fast Reactor Cycle Technology Development) project. There, the disassembling technique of an irradiated fuel assembly was advanced in order to realize further continuous irradiation tests. Although the conventional disassembling technique had been cutting a lower end-plug of a fuel pin needed to fix fuel pins to an irradiation vehicle, the advanced disassembling technique did not need cutting a lower end-plug. As a result, it was possible to supply many irradiated fuel pins to various continuous irradiation tests for FaCT project. (author)

  9. Thermochemical aspects of fuel-cladding and fuel-coolant interactions in LMFBR oxide fuel pins

    International Nuclear Information System (INIS)

    Adamson, M.G.; Aitken, E.A.; Caputi, R.W.; Potter, P.E.; Mignanelli, M.A.

    1979-01-01

    This paper examines several thermochemical aspects of the fuel-cladding, fuel-coolant and fuel-fission product interactions that occur in LMFBR austenitic stainless steel-clad mixed (U,Pu)-oxide fuel pins during irradiation under normal operating conditions. Results are reported from a variety of high temperature EMF cell experiments in which continuous oxygen activity measurements on reacting and equilibrium mixtures of metal oxides and (excess) liquid alkali metal (Na, K, Cs) were performed. Oxygen potential and 0:M thresholds for Na-fuel reactions are re-evaluated in the light of new measurements and newly-assessed thermochemical data, and the influence on oxygen potential of possible U-Pu segregation between oxide and urano-plutonate (equilibrium) phases has been analyzed. (orig./RW) [de

  10. Interaction of Al2O3xSiO2 alloyed uranium oxide with pyrocarbon coating of fuel particles under irradiation

    International Nuclear Information System (INIS)

    Chernikov, A.S.; Khromov, Yu.F.; Svistunov, D.E.; Chujko, E.E.

    1989-01-01

    Method of comparative data analysis for P O2 and P CO was used to consider interaction in fuel particle between pyrocarbon coating and fuel sample, alloyed with alumosilicate addition. Equations of interaction reactions for the case of hermetic and depressurized fuel particle are presented. Calculations of required xAl 2 O 3 XySiO 2 content, depending on oxide fuel burnup, were conducted. It was suggested to use silicon carbide for limitation of the upper level of CO pressure in fuel particle. Estimation of thermal stability of alumosilicates under conditions of uranium oxide burnup equals 1100 and 1500 deg C for Al/Si ratio in addition 1/1 and 4/1 respectively

  11. Fission gas retention in irradiated metallic fuel

    International Nuclear Information System (INIS)

    Fenske, G.R.; Gruber, E.E.; Kramer, J.M.

    1987-01-01

    Theoretical calculations and experimental measurements of the quantity of retained fission gas in irradiated metallic fuel (U-5Fs) are presented. The calculations utilize the Booth method to model the steady-state release of gases from fuel grains and a simplified grain-boundary gas model to predict the gas release from intergranular regions. The quantity of gas retained in as-irradiated fuel was determined by collecting the gases released from short segments of EBR-II driver fuel that were melted in a gas-tight furnace. Comparison of the calculations to the measurements shows quantitative agreement with both the magnitude and the axial variation of the retained gas content

  12. Irradiation and performance evaluation of DUPIC fuel

    International Nuclear Information System (INIS)

    Bae, Ki Kwang; Yang, M. S.; Song, K. C.

    2000-05-01

    The objectives of the project is to establish the performance evaluation system for the experimental verification of DUPIC fuel. The scope and content for successful accomplishment of the phase 1 objectives is established as follows : irradiation test of DUPIC fuel at HANARO using a noninstrument capsule, study on the characteristics of DUPIC pellets, development of the analysis technology on the thermal behaviour of DUPIC fuel, basic design of a instrument capsule. The R and D results of the phase 1 are summarized as follows : - Performance analysis technology development of DUPIC fuel by model development for DUPIC fuel, review on the extendability of code(FEMAXI-IV, FRAPCON-3, ELESTRESS). - Study on physical properties of DUPIC fuel by design and fabrication of the equipment for measuring the thermal property. - HANARO irradiation test of simulated DUPIC fuel by the noninstrument capsule development. - PIE and result analysis

  13. Irradiation and performance evaluation of DUPIC fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Ki Kwang; Yang, M S; Song, K C [and others

    2000-05-01

    The objectives of the project is to establish the performance evaluation system for the experimental verification of DUPIC fuel. The scope and content for successful accomplishment of the phase 1 objectives is established as follows : irradiation test of DUPIC fuel at HANARO using a noninstrument capsule, study on the characteristics of DUPIC pellets, development of the analysis technology on the thermal behaviour of DUPIC fuel, basic design of a instrument capsule. The R and D results of the phase 1 are summarized as follows : - Performance analysis technology development of DUPIC fuel by model development for DUPIC fuel, review on the extendability of code(FEMAXI-IV, FRAPCON-3, ELESTRESS). - Study on physical properties of DUPIC fuel by design and fabrication of the equipment for measuring the thermal property. - HANARO irradiation test of simulated DUPIC fuel by the noninstrument capsule development. - PIE and result analysis.

  14. Irradiation performance of HTGR recycle fissile fuel

    International Nuclear Information System (INIS)

    Homan, F.J.; Long, E.L. Jr.

    1976-08-01

    The irradiation performance of candidate HTGR recycle fissile fuel under accelerated testing conditions is reviewed. Failure modes for coated-particle fuels are described, and the performance of candidate recycle fissile fuels is discussed in terms of these failure modes. The bases on which UO 2 and (Th,U)O 2 were rejected as candidate recycle fissile fuels are outlined, along with the bases on which the weak-acid resin (WAR)-derived fissile fuel was selected as the reference recycle kernel. Comparisons are made relative to the irradiation behavior of WAR-derived fuels of varying stoichiometry and conclusions are drawn about the optimum stoichiometry and the range of acceptable values. Plans for future testing in support of specification development, confirmation of the results of accelerated testing by real-time experiments, and improvement in fuel performance and reliability are described

  15. The physics of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Robin, M.

    1980-01-01

    The knowledge of the neutron irradiation effect is essential in dealing with all subjects related to the fuel. Neutron irradiation provokes fission reactions within the fuel and produces new nuclides. The formation chains are described and the importance of each isotope in the fuel cycle is explained with regards to its own characteristics. To solve the system of equations giving the evolution of different nuclides concentrations, the corresponding effective cross-sections and flux received are given by standard codes used for reactor calculations. A good test for calculation methods is the experimental study of irradiated fuel. Many techniques have been developed for this purpose. The last chapter compares fuel evolution in different reactors, in connection with some specific characteristics. (author)

  16. Irradiated fuel examination using the Cerenkov technique

    International Nuclear Information System (INIS)

    Nicholson, N.; Dowdy, E.J.

    1981-03-01

    A technique for monitoring irradiated nuclear fuel inventories located in water filled storage ponds has been developed and demonstrated. This technique provides sufficient qualitative information to be useful as a confirmatory technique to International Atomic Energy Agency inspectors. Measurements have been made on the Cerenkov glow light intensity from irradiated fuel that show the intensity of this light to be proportional to the cooling time. Fieldable instruments used in several tests confirm that such measurements can be made easily and rapidly, without fuel assembly movement or the introduction of apparatus into the storage ponds. The Cerenkov technique and instrumentation have been shown to be of potential use to operators of reactor spent fuel facilities and away from reactor storage facilities, and to the International Atomic Energy Agency inspectors who provide surveillance of the irradiated fuel stored in these facilities

  17. Loading procedures for shipment of irradiated fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bates, E F; Feltz, D E; Sandel, P S; Schoenbucher, B [Texas A and M University (United States)

    1974-07-01

    The Nuclear Science Center at Texas A and M does not have proper equipment and facilities for transferring irradiated fuel from the reactor pool to the transport vehicle. To accomplish the transfer of 23 MTR type fuel elements procedures were developed using a modified fork lift and flex-lift obtained locally. The transfer was accomplished without incident and with negligible personnel exposure. (author)

  18. Loading procedures for shipment of irradiated fuel

    International Nuclear Information System (INIS)

    Bates, E.F.; Feltz, D.E.; Sandel, P.S.; Schoenbucher, B.

    1974-01-01

    The Nuclear Science Center at Texas A and M does not have proper equipment and facilities for transferring irradiated fuel from the reactor pool to the transport vehicle. To accomplish the transfer of 23 MTR type fuel elements procedures were developed using a modified fork lift and flex-lift obtained locally. The transfer was accomplished without incident and with negligible personnel exposure. (author)

  19. Fuel fabrication and post-irradiation examination

    Energy Technology Data Exchange (ETDEWEB)

    Venter, P J; Aspeling, J C [Atomic Energy Corporation of South Africa Ltd., Pretoria (South Africa)

    1990-06-01

    This paper provides an overview of the A/c's Bevan and Eldopar facilities for the fabrication of nuclear fuel. It also describes the sophisticated Hot Cell Complex, which is capable of accommodating pressurised water reactor fuel and various other irradiated samples. Some interesting problems and their solutions are discussed. (author)

  20. Fuel fabrication and post-irradiation examination

    International Nuclear Information System (INIS)

    Venter, P.J.; Aspeling, J.C.

    1990-01-01

    This paper provides an overview of the A/c's Bevan and Eldopar facilities for the fabrication of nuclear fuel. It also describes the sophisticated Hot Cell Complex, which is capable of accommodating pressurised water reactor fuel and various other irradiated samples. Some interesting problems and their solutions are discussed. (author)

  1. Aluminum cladding oxidation of prefilmed in-pile fueled experiments

    Energy Technology Data Exchange (ETDEWEB)

    Marcum, W.R., E-mail: marcumw@engr.orst.edu [Oregon State University, School of Nuclear Science and Engineering, 116 Radiation Center, Corvallis, OR 97331 (United States); Wachs, D.M.; Robinson, A.B.; Lillo, M.A. [Idaho National Laboratory, Nuclear Fuels & Materials Department, 2525 Fremont Ave., Idaho Falls, ID 83415 (United States)

    2016-04-01

    A series of fueled irradiation experiments were recently completed within the Advanced Test Reactor Full size plate In center flux trap Position (AFIP) and Gas Test Loop (GTL) campaigns. The conduct of the AFIP experiments supports ongoing efforts within the global threat reduction initiative (GTRI) to qualify a new ultra-high loading density low enriched uranium-molybdenum fuel. This study details the characterization of oxide growth on the fueled AFIP experiments and cross-correlates the empirically measured oxide thickness values to existing oxide growth correlations and convective heat transfer correlations that have traditionally been utilized for such an application. This study adds new and valuable empirical data to the scientific community with respect to oxide growth measurements of highly irradiated experiments, of which there is presently very limited data. Additionally, the predicted oxide thickness values are reconstructed to produce an oxide thickness distribution across the length of each fueled experiment (a new application and presentation of information that has not previously been obtainable in open literature); the predicted distributions are compared against experimental data and in general agree well with the exception of select outliers. - Highlights: • New experimental data is presented on oxide layer thickness of irradiated aluminum fuel. • Five oxide growth correlations and four convective heat transfer correlations are used to compute the oxide layer thickness. • The oxide layer thickness distribution is predicted via correlation for each respective experiment. • The measured experiment and predicted distributions correlate well, with few outliers.

  2. Survey of post-irradiation examinations made of mixed carbide fuels

    International Nuclear Information System (INIS)

    Coquerelle, M.

    1997-01-01

    Post-irradiation examinations on mixed carbide, nitride and carbonitride fuels irradiated in fast flux reactors Rapsodie and DFR were carried out during the seventies and early eighties. In this report, emphasis was put on the fission gas release, cladding carburization and head-end gaseous oxidation process of these fuels, in particular, of mixed carbides. (author). 8 refs, 16 figs, 3 tabs

  3. Solid oxide fuel cells fueled with reducible oxides

    Science.gov (United States)

    Chuang, Steven S.; Fan, Liang Shih

    2018-01-09

    A direct-electrochemical-oxidation fuel cell for generating electrical energy includes a cathode provided with an electrochemical-reduction catalyst that promotes formation of oxygen ions from an oxygen-containing source at the cathode, a solid-state reduced metal, a solid-state anode provided with an electrochemical-oxidation catalyst that promotes direct electrochemical oxidation of the solid-state reduced metal in the presence of the oxygen ions to produce electrical energy, and an electrolyte disposed to transmit the oxygen ions from the cathode to the solid-state anode. A method of operating a solid oxide fuel cell includes providing a direct-electrochemical-oxidation fuel cell comprising a solid-state reduced metal, oxidizing the solid-state reduced metal in the presence of oxygen ions through direct-electrochemical-oxidation to obtain a solid-state reducible metal oxide, and reducing the solid-state reducible metal oxide to obtain the solid-state reduced metal.

  4. Horizontal modular dry irradiated fuel storage system

    Science.gov (United States)

    Fischer, Larry E.; McInnes, Ian D.; Massey, John V.

    1988-01-01

    A horizontal, modular, dry, irradiated fuel storage system (10) includes a thin-walled canister (12) for containing irradiated fuel assemblies (20), which canister (12) can be positioned in a transfer cask (14) and transported in a horizontal manner from a fuel storage pool (18), to an intermediate-term storage facility. The storage system (10) includes a plurality of dry storage modules (26) which accept the canister (12) from the transfer cask (14) and provide for appropriate shielding about the canister (12). Each module (26) also provides for air cooling of the canister (12) to remove the decay heat of the irradiated fuel assemblies (20). The modules (26) can be interlocked so that each module (26) gains additional shielding from the next adjacent module (26). Hydraulic rams (30) are provided for inserting and removing the canisters (12) from the modules (26).

  5. VVER fuel. Results of post irradiation examination

    International Nuclear Information System (INIS)

    Smirnov, V.P.; Markov, D.V.; Smirnov, A.V.; Polenok, V.S.; Perepelkin, S.O.; Ivashchenko, A.A.

    2005-01-01

    The present paper presents the main results of post-irradiation examination of more than 40 different fuel assemblies (FA) operated in the cores of VVER-1000 and VVER-440-type power reactors in a wide range of fuel burnup. The condition of fuel assembly components from the viewpoint of deformation, corrosion resistance and mechanical properties is described here. A serviceability of the FA design as a whole and interaction between individual FA components under vibration condition and mechanical load received primary emphasis. The reasons of FA damage fuel element failure in a wide range of fuel burnup are also analyzed. A possibility and ways of fuel burnup increase have been proved experimentally for the case of high-level serviceability maintenance of fuel elements to provide for advanced fuel cycles. (author)

  6. Irradiation behavior of metallic fast reactor fuels

    International Nuclear Information System (INIS)

    Pahl, R.G.; Porter, D.L.; Crawford, D.C.; Walters, L.C.

    1991-01-01

    Metallic fuels were the first fuels chosen for liquid metal cooled fast reactors (LMR's). In the late 1960's world-wide interest turned toward ceramic LMR fuels before the full potential of metallic fuel was realized. However, during the 1970's the performance limitations of metallic fuel were resolved in order to achieve a high plant factor at the Argonne National Laboratory's Experimental Breeder Reactor II. The 1980's spawned renewed interest in metallic fuel when the Integral Fast Reactor (IFR) concept emerged at Argonne National Laboratory. A fuel performance demonstration program was put into place to obtain the data needed for the eventual licensing of metallic fuel. This paper will summarize the results of the irradiation program carried out since 1985

  7. Consolidation equipment for irradiated nuclear fuel channels

    International Nuclear Information System (INIS)

    Taguchi, M.; Komatsu, Y.; Ose, T.

    1989-01-01

    The authors have developed and put into use a new type of mechanical consolidation equipment for irradiated nuclear fuel channels. This includes round-slice cutting of the top 100mm of the fuel channel with a guillotine cutter, and press cutting of the two corners of the remaining length of the fuel channel. Four guillotine blades work in combination with receiving blades arranged inside the fuel channel to cut the top 100mm, including the clips and spacers, of the fuel channel into a round slice. A press assembled in the consolidation equipment then presses the slice to achieve volume reduction. The press cutting operation uses two press cutting blades arranged inside the fuel channel and the receiving blades outside the fuel channel. The remaining length of fuel channel is cut off into L-shaped pieces by press cutting. This consolidation equipment is highly efficient because the round-slice cutting, pressing, and press cutting are all achieved by one unit

  8. Post-irradiation examination and R and D programs using irradiated fuels at KAERI

    International Nuclear Information System (INIS)

    Chun, Yong Bum; Min, Duck Kee; Kim, Eun Ka and others

    2000-12-01

    This report describes the Post-Irradiation Examination(PIE) and R and D programs using irradiated fuels at KAERI. The objectives of post-irradiation examination (PIE) for the PWR irradiated fuels, CANDU fuels, HANARO fuels and test fuel materials are to verify the irradiation performance and their integrity as well as to construct a fuel performance data base. The comprehensive utilization program of the KAERI's post-irradiation examination related nuclear facilities such as Post-Irradiation Examination Facility (PIEF), Irradiated Materials Examination Facility (IMEF) and HANARO is described

  9. Post-irradiation examination and R and D programs using irradiated fuels at KAERI

    International Nuclear Information System (INIS)

    Chun, Yong Bum; So, Dong Sup; Lee, Byung Doo; Lee, Song Ho; Min, Duck Kee

    2001-09-01

    This report describes the Post-Irradiation Examination(PIE) and R and D programs using irradiated fuels at KAERI. The objectives of post-irradiation examination (PIE) for the PWR irradiated fuels, CANDU fuels, HANARO fuels and test fuel materials are to verify the irradiation performance and their integrity as well as to construct a fuel performance data base. The comprehensive utilization program of the KAERI's post-irradiation examination related nuclear facilities such as Post-Irradiation Examination Facility (PIEF), Irradiated Materials Examination Facility (IMEF) and HANARO is described

  10. Direct electrical heating of irradiated metal fuel

    International Nuclear Information System (INIS)

    Fenske, G.R.; Emerson, J.E.; Savoie, F.E.; Johanson, E.W.

    1985-01-01

    The Integral Fast Reactor (IFR) concept proposed by Argonne National Laboratory utilizes a metal fuel core. Reactor safety analysis requires information on the potential for fuel axial expansion during severe thermal transients. In addition to a comparatively large thermal expansion coefficient, metallic fuel has a unique potential for enhanced pre-failure expansion driven by retained fission gas and ingested bond sodium. In this paper, the authors present preliminary results from three direct electrical heating (DEH) experiments performed on irradiated metal fuel to investigate axial expansion behavior. The test samples were from Experimental Breeder Reactor II (EBR-II) driver fuel ML-11 irradiated to 8 at.% burnup. Preliminary analysis of the results suggest that enhanced expansion driven by trapped fission gas can occur

  11. Fission gas retention in irradiated metallic fuel

    International Nuclear Information System (INIS)

    Fenske, G.R.; Gruber, E.; Kramer, J.M.

    1987-01-01

    Theoretical calculations and experimental measurements of the quantity of retained fission gas in irradiated metallic fuel (U-5 wt. % Fs) are presented. (The symbol 'Fs' designates fissium, a 'pseudo-element' which, in reality, is an alloy whose composition is representative of fission products that remain in reprocessed fuel). The calculations utilize the Booth method to model the steady-state release of gases from fuel grains and a simplified grain-boundary gas model to predict the gas release from intergranular regions. The quantity of gas retained in as-irradiated fuel was determined by collecting the gases released from short segments of EBR-II driver fuel that were melted in a gas-tight furnace. Comparison of the calculations with the measurements shows quantitative agreement in both the magnitude and the axial variation of the retained gas content. (orig.)

  12. Irradiated fuel performance evaluation technology development

    International Nuclear Information System (INIS)

    Koo, Yang Hyun; Bang, J. G.; Kim, D. H.

    2012-01-01

    Alpha version performance code for dual-cooled annular fuel under steady state operation, so called 'DUOS', has been developed applying performance models and proposed methodology. Furthermore, nonlinear finite element module which could be integrated into transient/accident fuel performance code was also developed and evaluated using commercial FE code. The first/second irradiation and PIE test of annular pellet for dual-cooled annular fuel in the world have been completed. In-pile irradiation test DB of annular pellet up to burnup of 10,000 MWd/MTU through the 1st test was established and cracking behavior of annular pellet and swelling rate at low temperature were studied. To do irradiation test of dual-cooled annular fuel under PWR's simulating steady-state conditions, irradiation test rig/rod design/manufacture of mock-up/performance test have been completed through international collaboration program with Halden reactor project. The irradiation test of large grain pellets has been continued from 2002 to 2011 and completed successfully. Burnup of 70,000 MWd/MTU which is the highest burnup among irradiation test pellets in domestic was achieved

  13. BR2 Reactor: Irradiation of fuels

    International Nuclear Information System (INIS)

    Verwimp, A.

    2005-01-01

    Safe, reliable and economical operation of reactor fuels, both UO 2 and MOX types, requires in-pile testing and qualification up to high target burn-up levels. In-pile testing of advanced fuels for improved performance is also mandatory. The objectives of research performed at SCK-CEN are to perform Neutron irradiation of LWR (Light Water Reactor) fuels in the BR2 reactor under relevant operating and monitoring conditions, as specified by the experimenter's requirements and to improve the on-line measurements on the fuel rods themselves

  14. Irradiation behaviors of coated fuel particles, (4)

    International Nuclear Information System (INIS)

    Fukuda, Kousaku; Kashimura, Satoru; Ogawa, Toru; Ikawa, Katsuichi; Iwamoto, Kazumi; Ishimoto, Kiyoshi

    1981-09-01

    Loose coated fuel particles prepared in confirmity to a preliminary design for the multi-purpose VHTR in fiscal 1972 - 1974 were irradiated by 73F - 12A capsule in JMTR. Main purpose for this irradiation experiment was to examine irradiation stability of the candidate TRISO coated fuel particles for the VHTR. Also the coated particles possessing low-density kernel (90%TD), highly anisotropic OLTI-PyC and ZrC coating layer were loaded with the candidate particles in this capsule. The coated particles were irradiated up to 1.5 x 10 21 n/cm 2 of fast neutron fluence (E > 0.18 MeV) and 3.2% FIMA of burnup. In the post irradiation examination it was observed that among three kinds of TRISO particles exposed to irradiation corresponding to the normal operating condition of the VHTR ones possessing poor characteristics of the coating layers did not show a good stability. The particles irradiated under abnormally high temperature condition (> 1800 0 C) revealed 6.7% of max. EOL failure fraction (95% confidence limit). Most of these particles were failed by the ameoba effect. Furthermore, among four kinds of the TRISO particles exposed to irradiation corresponding to the transient condition of the VHTR (--1500 0 C) the two showed a good stability, while the particles possessing highly anisotropic OLTI-PyC or poorly characteristic coating layers were not so good. (author)

  15. Studies of irradiated zircaloy fuel sheathing using XPS

    International Nuclear Information System (INIS)

    Chan, P.K.; Irving, K.G.; Hocking, W.H.; Duclos, A.M.; Gerwing, A.F.

    1995-01-01

    The preliminary results reported here support the hypothesis that CANLUB graphite coating reduces the rate at which oxygen can react with fuel sheathing. X-ray photoelectron spectroscopic (XPS) characterization of Zircaloy sheathing obtained from extended-burnup Bruce-type elements (BDL-406-XY (555 MW.h/kgU) and BDL-406-AAH (731 MW.h/kgU)) irradiated in NRU indicates that CANLUB may reduce fuel sheath oxidation, and hence that fission-liberated oxygen may remain in the fuel. Chemical shifts in the Zr 3d spectra suggest that a stoichiometric (ZrO 2 ) oxide film was formed only on Zircaloy in direct contact with fuel. Particulate fuel adhering to the sheath was also determined to be systematically more oxidized on surfaces with CANLUB than on those without it. The unique association of tin on sheathing specimens with the non-CANLUB-coated specimens might also suggest that the tin had segregated from the sheathing. It must be emphasized that further experiments are required to better define the effect of CANLUB on fuel oxidation. (author). 14 refs., 1 tab., 3 figs

  16. Studies of irradiated zircaloy fuel sheathing using XPS

    Energy Technology Data Exchange (ETDEWEB)

    Chan, P K; Irving, K G [Atomic Energy of Canada Ltd., Chalk River, ON (Canada); Hocking, W H; Duclos, A M; Gerwing, A F [Atomic Energy of Canada Ltd., Pinawa, MB (Canada). Whiteshell Labs.

    1996-12-31

    The preliminary results reported here support the hypothesis that CANLUB graphite coating reduces the rate at which oxygen can react with fuel sheathing. X-ray photoelectron spectroscopic (XPS) characterization of Zircaloy sheathing obtained from extended-burnup Bruce-type elements (BDL-406-XY (555 MW.h/kgU) and BDL-406-AAH (731 MW.h/kgU)) irradiated in NRU indicates that CANLUB may reduce fuel sheath oxidation, and hence that fission-liberated oxygen may remain in the fuel. Chemical shifts in the Zr 3d spectra suggest that a stoichiometric (ZrO{sub 2}) oxide film was formed only on Zircaloy in direct contact with fuel. Particulate fuel adhering to the sheath was also determined to be systematically more oxidized on surfaces with CANLUB than on those without it. The unique association of tin on sheathing specimens with the non-CANLUB-coated specimens might also suggest that the tin had segregated from the sheathing. It must be emphasized that further experiments are required to better define the effect of CANLUB on fuel oxidation. (author). 14 refs., 1 tab., 3 figs.

  17. EDF requirements for hot cells examinations on irradiated fuel

    International Nuclear Information System (INIS)

    Segura, J.C.; Ducros, G.

    2002-01-01

    The objectives of increasing French Nuclear Power Plants (NPP) availability while lengthening the fuel irradiation cycle and reaching higher burnups lead EDF to carry out on site and hot cell examinations. The data issued from such fuel behaviour monitoring programmes will be used to ascertain that the design criteria are met. Data are also needed for modelling, development and validation. The paper deals quickly with the logistics linked to the selection and transport of fuel rods from NPP to hot cell laboratory. Hot cell PIEs remain a valuable method to obtain data in such fields as PCI (Pellet-Cladding Interaction), internal pressure, FGR (Fission Gas Release), oxide thickness, metallurgical aspects. The paper introduces burnup determination methods, inner pressure evaluation, preparation of samples for further irradiation such as power ramps for PCI and RIA (Reactivity Initiated Accident) testing. The nuclear microprobe of Perre Suee laboratory is also presented. (author)

  18. Cerenkov methodology for monitoring irradiated reactor fuel

    International Nuclear Information System (INIS)

    Nicholson, N.; Dowdy, E.J.

    1984-01-01

    Attribute measurement methods for confirming declared irradiated fuel inventories at nuclear installations under safeguards surveillance are of significant interest to inspectors. High-gain measurements of the intensity of the Cerenkov glow from exposed assemblies in water-filled storage ponds are promising for this purpose because the measured intensities depend on cooling times and burnup. We have developed a Cerenkov Measuring Device, a hand-held instrument that examines irradiated fuel assemblies in water-filled storage ponds and measures the intensity of the associated Cerenkov glow. In addition, we have developed a method for making such high-gain measurements in the presence of intense ambient light

  19. Irradiation effects on fuels for space reactors

    International Nuclear Information System (INIS)

    Ranken, W.A.; Cronenberg, A.W.

    1984-01-01

    A review of irradiation-induced swelling and gas release experience is presented here for the three principal fuels UO 2 , UC, and UN. The primary advantage of UC and UN over UO 2 is higher thermal conductivity and attendant lower fuel temperature at equivalent pellet diameter and power density, while UO 2 offers the distinct benefit of well-known irradiation performance. Irradiation test results indicate that at equivalent burnup, temperature, and porosity conditions, UC experiences higher swelling than UO 2 or UN. Fission gas swelling becomes important at fuel temperatures above 1320 K for UC, and at somewhat higher temperatures for UO 2 and UN. Evidence exists that at equivalent fuel temperatures and burnups, high density UO 2 and UN experience comparable swelling behavior; however, differences in thermal conductivity influence overall irradiation performance. The low conductivity of UO 2 results in higher thermal gradients which contribute to fuel microcracking and gas release. As a result UO 2 exhibits higher fractional gas release than UN, at least or burnups up to about 3%

  20. Metal fuel manufacturing and irradiation performance

    International Nuclear Information System (INIS)

    Pedersen, D.R.; Walters, L.C.

    1992-01-01

    The advances in metal fuel by the Integral Fast Reactor Program at Argonne National Laboratory are the subject of this paper. The Integral Fast Reactor (IFR) is an advanced liquid-metal-cooled reactor concept being developed at Argonne National Laboratory. The advances stressed in the paper include fuel irradiation performance, and improved passive safety. The goals and the safety philosophy of the Integral Fast Reactor Program are stressed

  1. Advanced fuel cycle on the basis of pyroelectrochemical process for irradiated fuel reprocessing and vibropacking technology

    International Nuclear Information System (INIS)

    Mayorshin, A.A.; Skiba, O.V.; Tsykanov, V.A.; Golovanov, V.N.; Bychkov, A.V.; Kisly, V.A.; Bobrov, D.A.

    2000-01-01

    For advanced nuclear fuel cycle in SSC RIAR there is developed the pyroelectrochemical process to reprocess irradiated fuel and produce granulated oxide fuel UO 2 , PuO 2 or (U,Pu)O 2 from chloride melts. The basic technological stage is the extraction of oxides as a crystal product with the methods either of the electrolysis (UO 2 and UO 2 -PuO 2 ) or of the precipitating crystalIization (PuO 2 ). After treating the granulated fuel is ready for direct use to manufacture vibropacking fuel pins. Electrochemical model for (U,Pu)O 2 coprecipitation is described. There are new processes being developed: electroprecipitation of mixed oxides - (U,Np)O 2 , (U,Pu,Np)O 2 , (U,Am)O 2 and (U,Pu,Am)O 2 . Pyroelectrochemical production of mixed actinide oxides is used both for reprocessing spent fuel and for producing actinide fuel. Both the efficiency of pyroelectrochemical methods application for reprocessing nuclear fuel and of vibropac technology for plutonium recovery are estimated. (author)

  2. Nuclear fuel cycle: (5) reprocessing of irradiated fuel

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.A.

    1977-09-01

    The evolution of the reprocessing of irradiated fuel and the recovery of plutonium from it is traced out, starting by following the Manhatten project up to the present time. A brief description of the plant and processes used for reprocessing is given, while the Purex process, which is used in all plants today, is given special attention. Some of the important safety problems of reprocessing plants are considered, together with the solutions which have been adopted. Some examples of the more important safety aspects are the control of activity, criticality control, and the environmental impact. The related topic of irradiated fuel transport is briefly discussed.

  3. Nitride fuels irradiation performance data base

    International Nuclear Information System (INIS)

    Brozak, D.E.; Thomas, J.K.; Peddicord, K.L.

    1987-01-01

    An irradiation performance data base for nitride fuels has been developed from an extensive literature search and review that emphasized uranium nitride, but also included performance data for mixed nitrides [(U,Pu)N] and carbonitrides [(U,Pu)C,N] to increase the quantity and depth of pin data available. This work represents a very extensive effort to systematically collect and organize irradiation data for nitride-based fuels. The data base has many potential applications. First, it can facilitate parametric studies of nitride-based fuels to be performed using a wide range of pin designs and operating conditions. This should aid in the identification of important parameters and design requirements for multimegawatt and SP-100 fuel systems. Secondly, the data base can be used to evaluate fuel performance models. For detailed studies, it can serve as a guide to selecting a small group of pin specimens for extensive characterization. Finally, the data base will serve as an easily accessible and expandable source of irradiation performance information for nitride fuels

  4. Heating subsurface formations by oxidizing fuel on a fuel carrier

    Science.gov (United States)

    Costello, Michael; Vinegar, Harold J.

    2012-10-02

    A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.

  5. Calculation simulation of equivalent irradiation swelling for dispersion nuclear fuel

    International Nuclear Information System (INIS)

    Cai Wei; Zhao Yunmei; Gong Xin; Ding Shurong; Huo Yongzhong

    2015-01-01

    The dispersion nuclear fuel was regarded as a kind of special particle composites. Assuming that the fuel particles are periodically distributed in the dispersion nuclear fuel meat, the finite element model to calculate its equivalent irradiation swelling was developed with the method of computational micro-mechanics. Considering irradiation swelling in the fuel particles and the irradiation hardening effect in the metal matrix, the stress update algorithms were established respectively for the fuel particles and metal matrix. The corresponding user subroutines were programmed, and the finite element simulation of equivalent irradiation swelling for the fuel meat was performed in Abaqus. The effects of the particle size and volume fraction on the equivalent irradiation swelling were investigated, and the fitting formula of equivalent irradiation swelling was obtained. The results indicate that the main factors to influence equivalent irradiation swelling of the fuel meat are the irradiation swelling and volume fraction of fuel particles. (authors)

  6. Safe transport of irradiated fuel by sea

    International Nuclear Information System (INIS)

    Miller, M.L.

    1997-01-01

    The development is described of a transport system dedicated to the sea transport of irradiated nuclear fuel. The background is reviewed of why shipments were required and the establishment of a specialist shipping company, Pacific Nuclear Transport Limited. A description of the ships, flasks and other equipment utilised is provided, together with details of key procedures implemented to ensure safety and customer satisfaction. (Author)

  7. The sea transport of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Miller, M.L.

    1995-01-01

    The paper describes the development of a transport system dedicated to the sea transport of irradiated nuclear fuel. It reviews the background to why shipments were required and the establishment of a specialist shipping company, Pacific Nuclear Transport Limited. A description of the ships, flasks and other equipment utilized is provided, together with details of key procedures implemented to ensure safety and customer satisfaction

  8. Mechanisms of microstructural changes of fuel under irradiation

    International Nuclear Information System (INIS)

    Garcia, P.; Carlot, G.; Dorado, B.; Maillard, S.; Sabathier, C.; Martin, G.; Oh, J.Y.; Welland, M.J.

    2015-01-01

    Nuclear fuels are subjected to high levels of radiation damage mainly due to the slowing of fission fragments, which results in substantial modifications of the initial fuel microstructure. Microstructure changes alter practically all engineering fuel properties such as atomic transport or thermomechanical properties so understanding these changes is essential to predicting the performance of fuel elements. Also, with increasing burn-up, the fuel drifts away from its initial composition as the fission process produces new chemical elements. Because nuclear fuels operate at high temperature and usually under high-temperature gradients, damage annealing, foreign atom or defect clustering and migration occur on multiple time and length scales, which make long-term predictions difficult. The end result is a fuel microstructure which may show extensive differences on the scale of a single fuel pellet. The main challenge we are faced with is, therefore, to identify the phenomena occurring on the atom scale that are liable to have macroscopic effects that will determine the microstructure changes and ultimately the life-span of a fuel element. One step towards meeting this challenge is to develop and apply experimental or modelling methods capable of connecting events that occur over very short length and timescales to changes in the fuel microstructure over engineering length and timescales. In the first part of this chapter, we provide an overview of some of the more important microstructure modifications observed in nuclear fuels. The emphasis is placed on oxide fuels because of the extensive amount of data available in relation to these materials under neutron or ion irradiation. When possible and relevant, the specifics of other types of fuels such as metallic or carbide fuels are alluded to. Throughout this chapter but more specifically in the latter part, we attempt to give examples of how modelling and experimentation at various scales can provide us with

  9. Pyro-electrochemical reprocessing of irradiated MOX fast reactor fuel, testing of the reprocessing process with direct MOX fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Kormilitzyn, M.V.; Vavilov, S.K.; Bychkov, A.V.; Skiba, O.V.; Chistyakov, V.M.; Tselichshev, I.V

    2000-07-01

    One of the advanced technologies for fast reactor fuel recycle is pyro-electrochemical molten salt technology. In 1998 we began to study the next phase of the irradiated oxide fuel reprocessing new process MOX {yields} MOX. This process involves the following steps: - Dissolution of irradiated fuel in molten alkaline metal chlorides, - Purification of melt from fission products that are co-deposited with uranium and plutonium oxides, - Electrochemical co-deposition of uranium and plutonium oxides under the controlled cathode potential, - Production of granulated MOX (crushing,salt separation and sizing), and - Purification of melt from fission products by phosphate precipitation. In 1998 a series of experiments were prepared and carried out in order to validate this process. It was shown that the proposed reprocessing flowsheet of irradiated MOX fuel verified the feasibility of its decontamination from most of its fission products (rare earths, cesium) and minor-actinides (americium, curium)

  10. Pyro-electrochemical reprocessing of irradiated MOX fast reactor fuel, testing of the reprocessing process with direct MOX fuel production

    International Nuclear Information System (INIS)

    Kormilitzyn, M.V.; Vavilov, S.K.; Bychkov, A.V.; Skiba, O.V.; Chistyakov, V.M.; Tselichshev, I.V.

    2000-01-01

    One of the advanced technologies for fast reactor fuel recycle is pyro-electrochemical molten salt technology. In 1998 we began to study the next phase of the irradiated oxide fuel reprocessing new process MOX → MOX. This process involves the following steps: - Dissolution of irradiated fuel in molten alkaline metal chlorides, - Purification of melt from fission products that are co-deposited with uranium and plutonium oxides, - Electrochemical co-deposition of uranium and plutonium oxides under the controlled cathode potential, - Production of granulated MOX (crushing,salt separation and sizing), and - Purification of melt from fission products by phosphate precipitation. In 1998 a series of experiments were prepared and carried out in order to validate this process. It was shown that the proposed reprocessing flowsheet of irradiated MOX fuel verified the feasibility of its decontamination from most of its fission products (rare earths, cesium) and minor-actinides (americium, curium)

  11. Behaviour of irradiated uranium silicide fuel revisited

    International Nuclear Information System (INIS)

    Finlay, M. Ross; Hofman, Gerard L.; Rest, Jeffrey; Snelgrove, James L.

    2002-01-01

    Irradiated U 3 Si 2 dispersion fuels demonstrate very low levels of swelling, even at extremely high burn-up. This behaviour is attributed to the stability of fission gas bubbles that develop during irradiation. The bubbles remain uniformly distributed throughout the fuel and show no obvious signs of coalescence. Close examination of high burn-up samples during the U 3 Si 2 qualification program revealed a bimodal distribution of fission gas bubbles. Those observations suggested that an underlying microstructure was responsible for the behaviour. An irradiation induced recrystallisation model was developed that relied on the presence of sufficient grain boundary surface to trap and pin fission gas bubbles and prevent coalescence. However, more recent work has revealed that the U 3 Si 2 becomes amorphous almost instantaneously upon irradiation. Consequently, the recrystallisation model does not adequately explain the nucleation and growth of fission gas bubbles in U 3 Si 2 . Whilst it appears to work well within the range of measured data, it cannot be relied on to extrapolate beyond that range since it is not mechanistically valid. A review of the mini-plates irradiated in the Oak Ridge Research Reactor from the U 3 Si 2 qualification program has been performed. This has yielded a new understanding of U 3 Si 2 behaviour under irradiation. (author)

  12. Advanced Reactor Fuels Irradiation Experiment Design Objectives

    International Nuclear Information System (INIS)

    Chichester, Heather Jean MacLean; Hayes, Steven Lowe; Dempsey, Douglas; Harp, Jason Michael

    2016-01-01

    This report summarizes the objectives of the current irradiation testing activities being undertaken by the Advanced Fuels Campaign relative to supporting the development and demonstration of innovative design features for metallic fuels in order to realize reliable performance to ultra-high burnups. The AFC-3 and AFC-4 test series are nearing completion; the experiments in this test series that have been completed or are in progress are reviewed and the objectives and test matrices for the final experiments in these two series are defined. The objectives, testing strategy, and test parameters associated with a future AFC test series, AFC-5, are documented. Finally, the future intersections and/or synergies of the AFC irradiation testing program with those of the TREAT transient testing program, emerging needs of proposed Versatile Test Reactor concepts, and the Joint Fuel Cycle Study program’s Integrated Recycle Test are discussed.

  13. Advanced Reactor Fuels Irradiation Experiment Design Objectives

    Energy Technology Data Exchange (ETDEWEB)

    Chichester, Heather Jean MacLean [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hayes, Steven Lowe [Idaho National Lab. (INL), Idaho Falls, ID (United States); Dempsey, Douglas [Idaho National Lab. (INL), Idaho Falls, ID (United States); Harp, Jason Michael [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-09-01

    This report summarizes the objectives of the current irradiation testing activities being undertaken by the Advanced Fuels Campaign relative to supporting the development and demonstration of innovative design features for metallic fuels in order to realize reliable performance to ultra-high burnups. The AFC-3 and AFC-4 test series are nearing completion; the experiments in this test series that have been completed or are in progress are reviewed and the objectives and test matrices for the final experiments in these two series are defined. The objectives, testing strategy, and test parameters associated with a future AFC test series, AFC-5, are documented. Finally, the future intersections and/or synergies of the AFC irradiation testing program with those of the TREAT transient testing program, emerging needs of proposed Versatile Test Reactor concepts, and the Joint Fuel Cycle Study program’s Integrated Recycle Test are discussed.

  14. Solid Oxide Fuel Cell Experimental Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — NETL’s Solid Oxide Fuel Cell Experimental Laboratory in Morgantown, WV, gives researchers access to models and simulations that predict how solid oxide fuel cells...

  15. Post irradiation examination on test fuel pins for PWR

    International Nuclear Information System (INIS)

    Fogaca Filho, N.; Ambrozio Filho, F.

    1981-01-01

    Certain aspects of irradiation technology on test fuel pins for PWR, are studied. The results of post irradiation tests, performed on test fuel pins in hot cells, are presented. The results of the tests permit an evaluation of the effects of irradiation on the fuel and cladding of the pin. (Author) [pt

  16. Irradiation performance of full-length metallic IFR fuels

    International Nuclear Information System (INIS)

    Tsai, H.; Neimark, L.A.

    1992-07-01

    An assembly irradiation of 169 full-length U-Pu-Zr metallic fuel pins was successfully completed in FFTF to a goal burnup of 10 at.%. All test fuel pins maintained their cladding integrity during the irradiation. Postirradiation examination showed minimal fuel/cladding mechanical interaction and excellent stability of the fuel column. Fission-gas release was normal and consistent with the existing data base from irradiation testing of shorter metallic fuel pins in EBR-II

  17. System of leak inspection of irradiated fuel

    International Nuclear Information System (INIS)

    Delfin L, A.; Castaneda J, G.; Mazon R, R.; Aguilar H, F.

    2007-01-01

    The International Atomic Energy Agency (IAEA) through the project RLA/04/18 Irradiated Fuel Management in Research reactors, recommended among other that the participant countries (Brazil, Argentina, Chile, Peru and Mexico), develop the sipping tool to generate registrations of the state that keep the irradiated fuels in the facilities of each country. The TRIGA Mark lll Reactor (RTMIII) Department, generated a project that it is based on the dimensions of the used fuel by the RTMIII, for design and to build an inspection system of irradiated fuel well known as SIPPING. This technique, provides a high grade of accuracy in the detection of gassy fission products or liquids that escape from the enveloping of fuels that have flaws or flights. The operation process of the SIPPING is carried out generating the migration of fission products through the creation of a pressure differential gas or vacuum to identify fuel assemblies failed by means of the detection of the xenon and/or krypton presence. The SIPPING system, is a device in revolver form with 4 tangential nozzles, which will discharge the fluid between the external surface of the enveloping of the fuel and the interior surface of the encircling one; the device was designed with independent pieces, with threaded joining and with stamps to impede flights of the fluid toward the exterior of the system. The System homogenizes and it distributes the fluid pressure so that the 4 nozzles work to equality of conditions, for what the device was designed in 3 pieces, an internal that is denominated revolver, one external that calls cover, and a joining called mamelon that will unite with the main encircling of the system. The detection of fission products in failed fuels, its require that inside the encircling one where the irradiated fuel element is introduced, be generated a pressure differential of gas or vacuum, and that it allows the samples extraction of water. For what generated a top for the encircling with the

  18. Results of Microstructural Examinations of Irradiated LEU U-Mo Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, D.D. Jr.; Jue, J.F.; Robinson, A.B. [Idaho National Laboratory, P.O. Box 2528, Idaho Falls, ID 83415-6188 (United States); Finlay, M.R. [Australian Nuclear Science and Technology Organization (Australia)

    2009-06-15

    Introduction: The RERTR program is responsible for converting research reactors that use high-enriched uranium fuels to ones that use low-enriched uranium fuels [1]. As part of the development of LEU fuels, a variety of irradiation experiments are being conducted using the Advanced Test Reactor. Based on the results of initial fuel plate testing, adjustments have been made to the characteristics of fuel plates to improve the stability of the fuel microstructure. One improvement has been to add Si to the matrix of a dispersion fuel. This material is also being added at the fuel/cladding interface of a monolithic fuel. This paper will discuss the irradiation performance of these fuels, in terms of the stability of their microstructures during irradiation. Results and discussion: The post-irradiation examinations of fuel plates are performed at the Idaho National Laboratory. These examinations consist of visual examinations of fuel plates, gamma scanning, thickness measurements, oxide thickness measurements, and optical metallographic examinations of the fuel plate microstructures. Microstructural analysis is also performed using scanning electron microscopy. Overall, U-7Mo and U-10Mo alloy fuels have displayed the best irradiation performance, particularly, when a Si-containing Al alloy is used as the dispersion fuel matrix. The benefit of using this type of matrix is that the commonly observed fuel/cladding interaction that occurs during irradiation is reduced and the interaction layer that forms exhibit stable behavior during irradiation. Monolithic-type fuels, which consist of a U-Mo foil encased in Al alloy cladding, are also being developed. These types of fuels are also showing promise and will continue to be developed. One challenge with this type of fuel is in trying to maximize the bond strength at the foil/cladding interface. Fuel/cladding interactions can affect the quality of the boding at this interface. Si is being added to improve the characteristics

  19. Irradiation Experiments on Plutonium Fuels for Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Frost, B. R.T.; Wait, E. [Atomic Energy Research Establishment Harwell, Berks. (United Kingdom)

    1967-09-15

    An assessment carried out some years ago indicated that cermet fuels might provide the high burn-up and integrity required for fast reactors. An irradiation programme was started at Harwell on (U, Pu)O{sub 2} -SS cermet plates and rods, mainly In thermal neutron fluxes, to gain experience of dimensional stability at temperatures typical of modern sodium-cooled fast reactor designs (600-650 Degree-Sign C). A subsequent assessment showed that cermets carried a large penalty as far as breeding was concerned and (U, Pu)C was chosen by Harwell for long-term study as an alternative, economic, fast reactor fuel. However, the results from the cermet experiments were of sufficient promise to proceed with parallel irradiation programmes on cermets and carbide. The studies of cermets showed that dimensional instability (swelling and cladding rupture) were caused by the pressures exerted on the steel matrix by the fuel particles, and that the initial density of the fuel particles was important in determining the burn-up at which failure occurred. Further, it was shown that cermets provided a useful vehicle for studying the changes occurring in oxide fuel particles with increasing burn-up. The disappearance of initial porosity and its replacement by fission gas bubbles and segregated solid fission products was studied in some detaiL No significant differences were observed between UO{sub 2} and(U,Pu)O{sub 2} particles. The initial studies of (U, Pu)C were concerned with the effect of varying composition and structure on swelling and fission gas release. A tantalum-lined nickel alloy cladding material was used to contain both pellet and powder specimens In an irradiation experiment in the core of the Dounreay fast reactor. This showed that the presence of a metal phase in the fuel led to a high swelling rate, that fission gas release was low up to {approx} 3% bum-up, and that a low density powder accommodated the swelling without excessive straining of the can. A subsequent

  20. Development of cutting device for irradiated fuel rod

    International Nuclear Information System (INIS)

    Lee, E. P.; Jun, Y. B.; Hong, K. P.; Min, D. K.; Lee, H. K.; Su, H. S.; Kim, K. S.; Kwon, H. M.; Joo, Y. S.; Yoo, K. S.; Joo, J. S.; Kim, E. K.

    2004-01-01

    Post Irradiation Examination(PIE) on irradiated fuel rods is essential for the evaluation of integrity and irradiation performance of fuel rods of commercial reactor fuel. For PIE, fuel rods should be cut very precisely. The cutting positions selected from NDT data are very important for further destructive examination and analysis. A fuel rod cutting device was developed witch can cut fuel rods longitudinal very precisely and can also cut the fuels into the same length rod cuts repeatedly. It is also easy to remove the fuel cutting powder after cutting works and it can extend the life time of cutting device and lower the contamination level of hot cell

  1. Analysis of fuel cladding chemical interaction in mixed oxide fuel pins

    International Nuclear Information System (INIS)

    Weber, J.W.; Dutt, D.S.

    1976-01-01

    An analysis is presented of the observed interaction between mixed oxide 75 wt percent UO 2 --25 wt percent PuO 2 fuel and 316--20 percent CW stainless steel cladding in LMFBR type fuel pins irradiated in EBR-II. A description is given of the test pins and their operating conditions together with, metallographic observations and measurements of the fuel/cladding reaction, and a correlation equation is developed relating depth of cladding attack to temperature and burnup. Some recent data on cladding reaction in fuel pins with low initial O/M in the fuel are given and compared with the correlation equation curves

  2. Thermal performance of fresh mixed-oxide fuel in a fast flux LMR [liquid metal reactor

    International Nuclear Information System (INIS)

    Ethridge, J.L.; Baker, R.B.

    1985-01-01

    A test was designed and irradiated to provide power-to-melt (heat generation rate necessary to initiate centerline fuel melting) data for fresh mixed-oxide UO 2 -PuO 2 fuel irradiated in a fast neutron flux under prototypic liquid metal reactor (LMR) conditions. The fuel pin parameters were selected to envelope allowable fabrication ranges and address mass production of LMR fuel using sintered-to-size techniques. The test included fuel pins with variations in fabrication technique, pellet density, fuel-to-cladding gap, Pu concentration, and fuel oxygen-to-metal ratios. The resulting data base has reestablished the expected power-to-melt in mixed-oxide fuels during initial reactor startup when the fuel temperatures are expected to be the highest. Calibration of heat transfer models of fuel pin performance codes with these data are providing more accurate capability for predicting steady-state thermal behavior of current and future mixed-oxide LMR fuels

  3. Breaking up of pure and simulated 'burnt' mixed oxide fuel by chemical interaction with oxidized sodium

    International Nuclear Information System (INIS)

    Besnard, R.; Chaudat, J.P.

    1983-01-01

    A large experimental program have permitted to investigate the behaviour of mixed oxide fuel coming in contact with hot oxidized sodium. The kinetic of the reaction, the size and the chemical nature of the particules after interaction have been studied. The main part of experiments have been performed using mixed oxide fuel non irradiated at first and with simulated fission products afterwards. Complementary informations have been obtained with UO 2 fuel pellets. After description of the experimental devices, the results are discussed and the importance of the main parameters, like temperature and fission products effect, are pointed out. (orig.)

  4. Oxide thickness measurement for monitoring fuel performance at high burnup

    International Nuclear Information System (INIS)

    Jaeger, M.A.; Van Swam, L.F.P.; Brueck-Neufeld, K.

    1991-01-01

    For on-site monitoring of the fuel performance at high burnup, Advanced Nuclear Fuels uses the linear scan eddy current method to determine the oxide thickness of irradiated Zircaloy fuel cans. Direct digital data acquisition methods are employed to collect the data on magnetic storage media. This field-proven methodology allows oxide thickness measurements and rapid interpretation of the data during the reactor outages and makes it possible to immediately reinsert the assemblies for the next operating cycle. The accuracy of the poolside measurements and data acquisition/interpretation techniques have been verified through hot cell metallographic measurements of rods previously measured in the fuel pool. The accumulated data provide a valuable database against which oxide growth models have been benchmarked and allow for effective monitoring of fuel performance. (orig.) [de

  5. Caramel, uranium oxide fuel plates for water cooled reactors

    International Nuclear Information System (INIS)

    Bussy, Pierre; Delafosse, Jacques; Lestiboudois, Guy; Cerles, J.-M.; Schwartz, J.-P.

    1979-01-01

    The fuel is composed of thin plates assembled parallel to each other to form bundles or assemblies. Each plate is composed of a pavement of uranium oxide pellets, insulated from each other by a zircaloy cladding. The 235 U enrichment does not exceed 8%. The range of uses for this fuel extends from electric power generating reactors to irradiation reactors for research work. A parametric study in test loops has made it possible to determine the operating limits of this thick fuel, without bursting. The resulting diagram gives the permissible power densities, with and without cycling for specific burn-ups beyond 50,000 MWd/t. The thinnest plates were also irradiated in total in the form of advance assemblies irradiated in the core of the OSIRIS pile prior to its transformation. This transformation and the operation of this reactor with a core of 'Caramel' elements is the main trial experiment of this fuel [fr

  6. Dissolving method for nuclear fuel oxide

    International Nuclear Information System (INIS)

    Tomiyasu, Hiroshi; Kataoka, Makoto; Asano, Yuichiro; Hasegawa, Shin-ichi; Takashima, Yoichi; Ikeda, Yasuhisa.

    1996-01-01

    In a method of dissolving oxides of nuclear fuels in an aqueous acid solution, the oxides of the nuclear fuels are dissolved in a state where an oxidizing agent other than the acid is present together in the aqueous acid solution. If chlorate ions (ClO 3 - ) are present together in the aqueous acid solution, the chlorate ions act as a strong oxidizing agent and dissolve nuclear fuels such as UO 2 by oxidation. In addition, a Ce compound which generates Ce(IV) by oxidation is added to the aqueous acid solution, and an ozone (O 3 ) gas is blown thereto to dissolve the oxides of nuclear fuels. Further, the oxides of nuclear fuels are oxidized in a state where ClO 2 is present together in the aqueous acid solution to dissolve the oxides of nuclear fuels. Since oxides of the nuclear fuels are dissolved in a state where the oxidizing agent is present together as described above, the oxides of nuclear fuels can be dissolved even at a room temperature, thereby enabling to use a material such as polytetrafluoroethylene and to dissolve the oxides of nuclear fuels at a reduced cost for dissolution. (T.M.)

  7. Small-scale irradiated fuel electrorefining

    International Nuclear Information System (INIS)

    Benedict, R.W.; Krsul, J.R.; Mariani, R.D.; Park, K.; Teske, G.M.

    1993-01-01

    In support of the metallic fuel cycle development for the Integral Fast Reactor (IFR), a small scale electrorefiner was built and operated in the Hot Fuel Examination Facility (HFEF) at Argonne National Laboratory-West. The initial purpose of this apparatus was to test the single segment dissolution of irradiated metallic fuel via either direct dissolution in cadmium or anodic dissolution. These tests showed that 99.95% of the uranium and 99.99% of the plutonium was dissolved and separated from the fuel cladding material. The fate of various fission products was also measured. After the dissolution experiments, the apparatus was upgraded to stady fission product behavior during uranium electrotransport. Preliminary decontamination factors were estimated for different fission products under different processing conditions. Later modifications have added the following capabilities: Dissolution of multiple fuel segments simultaneously, electrotransport to a solid cathode or liquid cathode and actinide recovery with a chemical reduction crucible. These capabilities have been tested with unirradiated uranium-zirconium fuel and will support the Fuel Cycle Demonstration program

  8. Composite fuel behaviour under and after irradiation

    International Nuclear Information System (INIS)

    Dehaudt, P.; Mocellin, A.; Eminet, G.; Caillot, L.; Delette, G.; Bauer, M.; Viallard, I.

    1997-01-01

    Two kinds of composite fuels have been irradiated in the SILOE reactor. They are made of UO 2 particles dispersed in a molybdenum metallic (CERMET) or a MgAl 2 O 4 ceramic (CERCER) matrix. The irradiation conditions have allowed to reach a 50000 MWd/t U burn-up in these composite fuels after a hundred equivalent full power days long irradiation. The irradiation is controlled by a continuous measure of the pellet centre line temperature. It allows to have information about the TANOX rods thermal behaviour and the fuels thermal conductivities in comparing the centre line temperature versus linear power curves among themselves. Our results show that the CERMET centre line temperature is much lower than the CERCER and UO 2 ones: 520 deg. C against 980 deg. C at a 300W/cm linear power. After pin puncturing tests the rods are dismantled to recover each fuel pellet. In the CERCER case, the cladding peeling off has revealed that the fuel came into contact with the cladding and that some of the pellets were linked together. Optical microscopy observations show a changing of the MgAl 2 O 4 matrix state around the UO 2 particles at the pellets periphery. This transformation may have caused a swelling and would be at the origin of the pellet-cladding and the pellet-pellet interactions. No specific damage is seen after irradiation. The CERMET pellets are not cracked and remain as they were before irradiation. The CERCER crack network is slightly different from that observed in UO 2 . Kr retention was evaluated by annealing tests under vacuum at 1580 deg. C or 1700 deg. C for 30 minutes. The CERMET fission gas release is lower than the CERCER one. Inter- and intragranular fission gas bubbles are observed in the UO 2 particles after heat treatments. The CERCER pellet periphery has also cracked and the matrix has transformed again around UO 2 particles to present a granular and porous aspect. (author). 4 refs, 6 figs, 2 tabs

  9. Whole-Pin Furnace system: An experimental facility for studying irradiated fuel pin behavior under potential reactor accident conditions

    International Nuclear Information System (INIS)

    Liu, Y.Y.; Tsai, H.C.; Donahue, D.A.; Pushis, D.O.; Savoie, F.E.; Holland, J.W.; Wright, A.E.; August, C.; Bailey, J.L.; Patterson, D.R.

    1990-05-01

    The whole-pin furnace system is a new in-cell experimental facility constructed to investigate how irradiated fuel pins may fail under potential reactor accident conditions. Extensive checkouts have demonstrated excellent performance in remote operation, temperature control, pin breach detection, and fission gas handling. The system is currently being used in testing of EBIR-II-irradiated Integral Fast Reactor (IFR) metal fuel pins; future testing will include EBR-II-irradiated mixed-oxide fuel pins. 7 refs., 4 figs

  10. Leaching of irradiated CANDU UO2 fuel

    International Nuclear Information System (INIS)

    Vandergraaf, T.T.; Johnson, L.H.; Lau, D.W.P.

    1980-01-01

    Irradiated fuel, leached at room temperature with distilled water and with slightly chlorinated river water, releases approx. 4% of its cesium inventory over a comparatively sort period of a few days but releases its actinides and rare earths more slowly. The matrix itself dissolves at a rate conservatively calculated to be less than approx. 2 x 10 -6 g UO 2 /cm 2 day and, with time, the leach rates of the various nuclides approach this value

  11. Fabrication of Fast Reactor Fuel Pins for Test Irradiations

    Energy Technology Data Exchange (ETDEWEB)

    Karsten, G. [Institute for Applied Reactor Physics, Kernforschungszentrum Karlsruhe, Karlsruhe, Federal Republic of Germany (Germany); Dippel, T. [Institute for Radiochemistry, Kernforschungszentrum Karlsruhe, Karlsruhe, Federal Republic of Germany (Germany); Laue, H. J. [Institute for Applied Reactor Physics, Kernforschungszentrum Karlsruhe, Karlsruhe, Federal Republic of Germany (Germany)

    1967-09-15

    An extended irradiation programme is being carried out for the fuel element development of the Karlsruhe fast breeder project. A very important task within the programme is the testing of plutonium-containing fuel pins in a fast-reactor environment. This paper deals with fabrication of such pins by our laboratories at Karlsruhe. For the fast reactor test positions at present envisaged a fuel with 15% plutonium and the uranium fully enriched is appropriate. Hie mixed oxide is both pelletized and vibro-compacted with smeared densities between 80 and 88% theoretical. The pin design is, for example, such that there are two gas plena at the top and bottom, and one blanket above the fuel with the fuel zone fitting to the test reactor core length. The specifications both for fuel and cladding have been adapted to the special purpose of a fast-breeder reactor - the outer dimensions, the choice of cladding and fuel types, the data used and the kind of tests outline the targets of the development. The fuel fabrication is described in detail, and also the powder line used for vibro-compaction. The source materials for the fuel are oxalate PuO{sub 2} and UO{sub 2} from the UF{sub 6} process. The special problems of mechanical mixing and of plutonium homogeneity have been studied. The development of the sintering technique and grain characteristics for vibratory compactive fuel had to overcome serious problems in order to reach 82-83% theoretical. The performance of the pin fabrication needed a major effort in welding, manufacturing of fits and decontamination of the pin surfaces. This was a stimulation for the development of some very subtle control techniques, for example taking clear X-ray photographs and the tube testing. In general the selection of tests was a special task of the production routine. In conclusion the fabrication of the pins resulted in valuable experiences for the further development of fast reactor fuel elements. (author)

  12. Irradiation test and performance evaluation of DUPIC fuel

    International Nuclear Information System (INIS)

    Yang, Myung Seung; Song, K. C.; Moon, J. S.

    2002-05-01

    The objective of the project is to establish the performance evaluation system of DUPIC fuel during the Phase II R and D. In order to fulfil this objectives, irradiation test of DUPIC fuel was carried out in HANARO using the non-instrumented and SPND-instrumented rig. Also, the analysis on the in-reactor behavior analysis of DUPIC fuel, out-pile test using simulated DUPIC fuel as well as performance and integrity assessment in a commercial reactor were performed during this Phase. The R and D results of the Phase II are summarized as follows : - Performance evaluation of DUPIC fuel via irradiation test in HANARO - Post irradiation examination of irradiated fuel and performance analysis - Development of DUPIC fuel performance code (modified ELESTRES) considering material properties of DUPIC fuel - Irradiation behavior and integrity assessment under the design power envelope of DUPIC fuel - Foundamental technology development of thermal/mechanical performance evaluation using ANSYS (FEM package)

  13. Spent fuel. Dissolution and oxidation

    International Nuclear Information System (INIS)

    Grambow, B.

    1989-03-01

    Data from studies of the low temperature air oxidation of spent fuel were retrieved in order to provide a basis for comparison between the mechanism of oxidation in air and corrosion in water. U 3 O 7 is formed by diffusion of oxygen into the UO 2 lattice. A diffusion coefficient of oxygen in the fuel matric was calculated for 25 degree C to be in the range of 10 -23 to 10 -25 m 2 /s. The initial rates of U release from spent fuel and from UO 2 appear to be similar. The lowest rates (at 25 degree c >10 -4 g/(m 2 d)) were observed under reducing conditions. Under oxidizing conditions the rates depend mainly of the nature and concentraion of the oxidant and/or on corbonate. In contact with air, typical initial rates at room temperature were in the range between 0.001 and 0.1 g/(m 2 d). A study of apparent U solubility under oxidizing conditions was performed and it was suggested that the controlling factor is the redox potential at the UO 2 surface rather than the E h of the bulk solution. Electrochemical arguments were used to predict that at saturation, the surface potential will eventually reach a value given by the boundaries at either the U 3 O 7 /U 3 O 8 or the U 3 O 7 /schoepite stability field, and a comparison with spent fuel leach data showed that the solution concentration of uranium is close to the calculated U solubility at the U 3 O 7 /U 3 O 8 boundary. The difference in the cumulative Sr and U release was calculated from data from Studsvik laboratory. The results reveal that the rate of Sr release decreases with the square root of time under U-saturated conditions. This time dependence may be rationalized either by grain boundary diffusion or by diffusion into the fuel matrix. Hence, there seems to be a possibility of an agreement between the Sr release data, structural information and data for oxygen diffusion in UO 2 . (G.B.)

  14. Fabrication, irradiation and post-irradiation examinations of MO2 and UO2 sphere-pac and UO2 pellet fuel pins irradiated in a PWR loop

    International Nuclear Information System (INIS)

    Linde, A. van der; Lucas Luijckx, H.J.B.; Verheugen, J.H.N.

    1982-01-01

    The document reports in detail the fuel pin fabrication data and describes the irradiation conditions and history. All the relevant results of the non-destructive and destructive post-irradiation examinations are reported. They include: visual inspection and chemical analysis of crud; length and diameter measurements; neutron radiography and gamma scanning; juncture tests and fission gas analysis (including residual gas in fuel samples); microscopy and alpha + beta/gamma autoradiography; microprobe investigations; burn-up and isotopic analysis; and hydrogen analysis in clad. The data and observations obtained are discussed in detail and conclusions are given. The irradiation and post-irradiation examinations of the R-109 pins have shown the safe, pre-calculable performance of LWR fuel pins containing mixed-oxide sphere-pac fuel with the fissile material mainly present in the large spheres

  15. Gamma spectrometrical examination of irradiated fuel

    International Nuclear Information System (INIS)

    Kristof, Edvard; Pregl, Gvido

    1988-01-01

    Gamma scanning is the only non-destructive technique for quantitative measuring of fission or activation products in spent fuel. The negligence of local variation of the linear attenuation coefficient of gamma rays in the irradiated fuel remains the main source of systematic error. To eliminate it we combine the (single) emission gamma ray scanning technique with a transmission measurement. Mathematical procedure joined with the experiment is particularly convenient for fuel elements of circular cross-section. In such a manner good results are obtainable even for relatively small number of measuring data. Accomplished routines enable to esteem the finite width of the collimation slit. The experiment has been partially automated. Trial measurements were carried out, and the measured data were successfully processed

  16. Nondestructive assay methods for irradiated nuclear fuels

    International Nuclear Information System (INIS)

    Hsue, S.T.; Crane, T.W.; Talbert, W.L. Jr.; Lee, J.C.

    1978-01-01

    This report is a review of the status of nondestructive assay (NDA) methods used to determine burnup and fissile content of irradiated nuclear fuels. The gamma-spectroscopy method measures gamma activities of certain fission products that are proportional to the burnup. Problems associated with this method are migration of the fission products and gamma-ray attenuation through the relatively dense fuel material. The attenuation correction is complicated by generally unknown activity distributions within the assemblies. The neutron methods, which usually involve active interrogation and prompt or delayed signal counting, are designed to assay the fissile content of the spent-fuel elements. Systems to assay highly enriched spent-fuel assemblies have been tested extensively. Feasibility studies have been reported of systems to assay light-water reactor spent-fuel assemblies. The slowing-down spectrometer and neutron resonance absorption methods can distinguish between the uranium and plutonium fissile contents, but they are limited to the assay of individual rods. We have summarized the status of NDA techniques for spent-fuel assay and present some subjects in need of further investigation. Accuracy of the burnup calculations for power reactors is also reviewed

  17. Irradiation performance of AGR-1 high temperature reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel–including the extent of fission product release and the evolution of kernel and coating microstructures–was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 1×10 4 to 5×10 4 for 154Eu and 8×10 7 to 3×10 5 for 90Sr. The average 134Cs release from compacts was <3×10 6 when all particles maintained intact SiC. An estimated four particles out of 2.98×105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization

  18. Irradiation creep of the mixed oxide UPuO2

    International Nuclear Information System (INIS)

    Combette, Patrick; Milet, Claude

    1976-01-01

    The irradiation creep under compression of the mixed oxide UO 2 -PuO 2 was studied up to fission yields of 6x10 13 fcm -3 s -1 , under stresses -2 , in the temperature range 700-900 deg C. The creep rate is proportional to the applied stress and fission yield, athermal in the studied temperature range and non-dependent of burnup (up to 30000MWjt -1 ). In a sample under compression, swelling is observed due to the formation of fission products during the irradiation and the swelling rate is of the same order that in a cladded fuel element [fr

  19. Review of oxidation rates of DOE spent nuclear fuel : Part 1 : nuclear fuel

    International Nuclear Information System (INIS)

    Hilton, B.A.

    2000-01-01

    The long-term performance of Department of Energy (DOE) spent nuclear fuel (SNF) in a mined geologic disposal system depends highly on fuel oxidation and subsequent radionuclide release. The oxidation rates of nuclear fuels are reviewed in this two-volume report to provide a baseline for comparison with release rate data and technical rationale for predicting general corrosion behavior of DOE SNF. The oxidation rates of nuclear fuels in the DOE SNF inventory were organized according to metallic, Part 1, and non-metallic, Part 2, spent nuclear fuels. This Part 1 of the report reviews the oxidation behavior of three fuel types prototypic of metallic fuel in the DOE SNF inventory: uranium metal, uranium alloys and aluminum-based dispersion fuels. The oxidation rates of these fuels were evaluated in oxygen, water vapor, and water. The water data were limited to pure water corrosion as this represents baseline corrosion kinetics. Since the oxidation processes and kinetics discussed in this report are limited to pure water, they are not directly applicable to corrosion rates of SNF in water chemistry that is significantly different (such as may occur in the repository). Linear kinetics adequately described the oxidation rates of metallic fuels in long-term corrosion. Temperature dependent oxidation rates were determined by linear regression analysis of the literature data. As expected the reaction rates of metallic fuels dramatically increase with temperature. The uranium metal and metal alloys have stronger temperature dependence than the aluminum dispersion fuels. The uranium metal/water reaction exhibited the highest oxidation rate of the metallic fuel types and environments that were reviewed. Consequently, the corrosion properties of all DOE SNF may be conservatively modeled as uranium metal, which is representative of spent N-Reactor fuel. The reaction rate in anoxic, saturated water vapor was essentially the same as the water reaction rate. The long-term intrinsic

  20. Fuel-cycle cost comparisons with oxide and silicide fuels

    International Nuclear Information System (INIS)

    Matos, J.E.; Freese, K.E.

    1982-01-01

    This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data are presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires that they are successfully demonstrated and licensed

  1. Irradiation tests of THTR fuel elements in the DRAGON reactor (irradiation experiment DR-K3)

    International Nuclear Information System (INIS)

    Burck, W.; Duwe, R.; Groos, E.; Mueller, H.

    1977-03-01

    Within the scope of the program 'Development of Spherical Fuel Elements for HTR', similar fuel elements (f.e.) have been irradiated in the DRAGON reactor. The f.e. were fabricated by NUKEM and were to be tested under HTR conditions to scrutinize their employability in the THTR. The fuel was in the form of coated particles moulded into A3 matrix. The kernels of the particles were made of mixed oxide of uranium and thorium with an U 235 enrichment of 90%. One aim of the post irradiation examination was the investigation of irradiation induced changes of mechanical properties (dimensional stability and elastic behaviour) and of the corrosion behaviour which were compared with the properties determined with unirradiated f.e. The measurement of the fission gas release in annealing tests and ceramografic examinations exhibited no damage of the coated particles. The measured concentration distribution of fission metals led to conclusions about their release. All results showed, that neither the coated particles nor the integral fuel spheres experienced any significant changes that could impair their utilization in the THTR. (orig./UA) [de

  2. Results of Am isotopic ratio analysis in irradiated MOX fuels

    Energy Technology Data Exchange (ETDEWEB)

    Koyama, Shin-ichi; Osaka, Masahiko; Mitsugashira, Toshiaki; Konno, Koichi [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center; Kajitani, Mikio

    1997-04-01

    For analysis of a small quantity of americium, it is necessary to separate from curium which has similar chemical property. As a chemical separation method for americium and curium, the oxidation of americium with pentavalent bismuth and subsequent co-precipitation of trivalent curium with BIP O{sub 4} were applied to analyze americium in irradiated MOX fuels which contained about 30wt% plutonium and 0.9wt% {sup 241}Am before irradiation and were irradiated up to 26.2GWd/t in the experimental fast reactor Joyo. The purpose of this study is to measure isotopic ratio of americium and to evaluate the change of isotopic ratio with irradiation. Following results are obtained in this study. (1) The isotopic ratio of americium ({sup 241}Am, {sup 242m}Am and {sup 243}Am) can be analyzed in the MOX fuels by isolating americium. The isotopic ratio of {sup 242m}Am and {sup 243}Am increases up to 0.62at% and 0.82at% at maximum burnup, respectively, (2) The results of isotopic analysis indicates that the contents of {sup 241}Am decreases, whereas {sup 242m}Am, {sup 243}Am increase linearly with increasing burnup. (author)

  3. Interim results from UO2 fuel oxidation tests in air

    International Nuclear Information System (INIS)

    Campbell, T.K.; Gilbert, E.R.; Thornhill, C.K.; White, G.D.; Piepel, G.F.; Griffin, C.W.j.

    1987-08-01

    An experimental program is being conducted at Pacific Northwest Laboratory (PNL) to extend the characterization of spent fuel oxidation in air. To characterize oxidation behavior of irradiated UO 2 , fuel oxidation tests were performed on declad light-water reactor spent fuel and nonirradited UO 2 pellets in the temperature range of 135 to 250 0 C. These tests were designed to determine the important independent variables that might affect spent fuel oxidation behavior. The data from this program, when combined with the test results from other programs, will be used to develop recommended spent fuel dry-storage temperature limits in air. This report describes interim test results. The initial PNL investigations of nonirradiated and spent fuels identified the important testing variables as temperature, fuel burnup, radiolysis of the air, fuel microstructure, and moisture in the air. Based on these initial results, a more extensive statistically designed test matrix was developed to study the effects of temperature, burnup, and moisture on the oxidation behavior of spent fuel. Oxidation tests were initiated using both boiling-water reactor and pressurized-water reactor fuels from several different reactors with burnups from 8 to 34 GWd/MTU. A 10 5 R/h gamma field was applied to the test ovens to simulate dry storage cask conditions. Nonirradiated fuel was included as a control. This report describes experimental results from the initial tests on both the spent and nonirradiated fuels and results to date on the tests in a 10 5 R/h gamma field. 33 refs., 51 figs., 6 tabs

  4. The 3rd irradiation test plan of DUPIC fuel

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Myung Seung; Song, K. C.; Park, J. H. and others

    2001-05-01

    The objective of the 3rd irradiation test of DUPIC fuel at the HANARO is to estimate the in-core behaviour of a DUPIC pellet that is irradiated up to more than average burnup of CANDU fuel. The irradiation of DUPIC fuel is planned to start at May 21, 2001, and will be continued at least for 8 months. The burnup of DUPIC fuel through this irradiation test is thought to be more than 7,000 MWd/tHE. The DUPIC irradiation rig instrumented with three SPN detectors will be used to accumulate the experience for the instrumented irradiation and to estimate the burnup of irradiated DUPIC fuel more accurately. Under normal operating condition, the maximum linear power of DUPIC fuel was estimated as 55.06 kW/m, and the centerline temperature of a pellet was calculated as 2510 deg C. In order to assess the integrity of DUPIC fuel under the accident condition postulated at the HANARO, safety analyses on the locked rotor and reactivity insertion accidents were carried out. The maximum centerline temperature of DUPIC fuel was estimated 2590 deg C and 2094 deg C for each accident, respectively. From the results of the safety analysis, the integrity of DUPIC fuel during the HANARO irradiation test will be secured. The irradiated DUPIC fuel will be transported to the IMEF. The post-irradiation examinations are planned to be performed at the PIEF and IMEF.

  5. HRB-22 capsule irradiation test for HTGR fuel. JAERI/USDOE collaborative irradiation test

    Energy Technology Data Exchange (ETDEWEB)

    Minato, Kazuo; Sawa, Kazuhiro; Fukuda, Kousaku [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; and others

    1998-03-01

    As a JAERI/USDOE collaborative irradiation test for high-temperature gas-cooled reactor fuel, JAERI fuel compacts were irradiated in the HRB-22 irradiation capsule in the High Flux Isotope Reactor at the Oak Ridge National Laboratory (ORNL). Postirradiation examinations also were performed at ORNL. This report describes 1) the preirradiation characterization of the irradiation samples of annular-shaped fuel compacts containing the Triso-coated fuel particles, 2) the irradiation conditions and fission gas releases during the irradiation to measure the performance of the coated particle fuel, 3) the postirradiation examinations of the disassembled capsule involving visual inspection, metrology, ceramography and gamma-ray spectrometry of the samples, and 4) the accident condition tests on the irradiated fuels at 1600 to 1800degC to obtain information about fuel performance and fission product release behavior under accident conditions. (author)

  6. PIE Report on the KOMO-3 Irradiation Test Fuels

    International Nuclear Information System (INIS)

    Park, Jong Man; Ryu, H. J.; Yang, J. H.

    2009-04-01

    In the KOMO-3, in-reactor irradiation test had been performed for 12 kinds of dispersed U-Mo fuel rods, a multi wire fuel rod and a tube fuel rod. In this report we described the PIE results on the KOMO-3 irradiation test fuels. The interaction layer thickness between fuel particle and matrix could be reduced by using a large size U-Mo fuel particle or introducing Al-Si matrix or adding the third element in the U-Mo particle. Monolithic fuel rod of multi-wire or tube fuel was also effective in reducing the interaction layer thickness

  7. Irradiation of novel MTR fuel plates in BR2

    International Nuclear Information System (INIS)

    Verboomen, B.; Aoust, Th.; Beeckmans De Westmeerbeeck, A.; De Raedt, Ch.

    2000-01-01

    Since the end of 1999, novel MTR fuel plates with very high-density meat are being irradiated in BR2. The purpose of the irradiation is to investigate the behaviour of these fuel plates under very severe reactor operation conditions. The novel fuel plates are inserted in two standard six-tube BR2 fuel elements in the locations normally occupied by the standard outer fuel plates. The irradiation in BR2 was prepared by carrying out detailed neutron Monte Carlo calculations of the whole BR2 core containing the two experimental fuel elements for various positions in the reactor and for various azimuthal orientations of the fuel elements. Comparing the thus determined fission density levels and azimuthal profiles in the new MTR fuel plates irradiated in the various channels allowed the experimenters to choose the most appropriate BR2 channel and the most appropriate fuel element orientation. (author)

  8. Microwave irradiated Ni–MnO{sub x}/C as an electrocatalyst for methanol oxidation in KOH solution for fuel cell application

    Energy Technology Data Exchange (ETDEWEB)

    Hameed, R.M. Abdel, E-mail: randa311eg@yahoo.com

    2015-12-01

    Graphical abstract: - Highlights: • Ni–MnO{sub x}/C had nickel nanoparticles with an average diameter of 4.5 nm. • Oxidation current density increased by 1.43 times at Ni–MnO{sub x}/C. • Ni–MnO{sub x}/C showed k{sub s} value of 3.26 × 103 cm{sup 3} mol{sup −1} s{sup −1}. • Adding MnO{sub x} to Ni/C lowered its phase angle and impedance values. - Abstract: Ni–MnO{sub x}/C electrocatalyst was synthesized by the reduction of nickel precursor salt on MnO{sub x}/C powder using NaBH{sub 4} and the deposition process was motivated with the aid of microwave irradiation. Finer nickel nanoparticles were detected in Ni–MnO{sub x}/C using transmission electron microscopy with a lower particle size of 4.5 nm compared to 6 nm in Ni/C. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy (EIS) were applied to study the electrocatalytic activity of Ni–MnO{sub x}/C for methanol oxidation in 0.5 M KOH solution. The presence of 7.5 wt.% MnO{sub x} in Ni–MnO{sub x}/C enhanced the oxidation current density by 1.43 times. The catalytic rate constant of methanol oxidation at Ni–MnO{sub x}/C was calculated as 3.26 × 10{sup 3} cm{sup 3} mol{sup −1} s{sup −1}. An appreciable shift in the maximum frequency at the transition from the resistive to capacitive regions to a higher value in Bode plots of Ni–MnO{sub x}/C was shown when compared to Ni/C. It was accompanied by lowered phase angle values. The lowered Warburg impedance value (W) of Ni–MnO{sub x}/C at 400 mV confirmed the faster methanol diffusion rate at its surface.

  9. Gas transport in solid oxide fuel cells

    CERN Document Server

    He, Weidong; Dickerson, James

    2014-01-01

    This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.

  10. Discrimination of irradiated MOX fuel from UOX fuel by multivariate statistical analysis of simulated activities of gamma-emitting isotopes

    Science.gov (United States)

    Åberg Lindell, M.; Andersson, P.; Grape, S.; Hellesen, C.; Håkansson, A.; Thulin, M.

    2018-03-01

    This paper investigates how concentrations of certain fission products and their related gamma-ray emissions can be used to discriminate between uranium oxide (UOX) and mixed oxide (MOX) type fuel. Discrimination of irradiated MOX fuel from irradiated UOX fuel is important in nuclear facilities and for transport of nuclear fuel, for purposes of both criticality safety and nuclear safeguards. Although facility operators keep records on the identity and properties of each fuel, tools for nuclear safeguards inspectors that enable independent verification of the fuel are critical in the recovery of continuity of knowledge, should it be lost. A discrimination methodology for classification of UOX and MOX fuel, based on passive gamma-ray spectroscopy data and multivariate analysis methods, is presented. Nuclear fuels and their gamma-ray emissions were simulated in the Monte Carlo code Serpent, and the resulting data was used as input to train seven different multivariate classification techniques. The trained classifiers were subsequently implemented and evaluated with respect to their capabilities to correctly predict the classes of unknown fuel items. The best results concerning successful discrimination of UOX and MOX-fuel were acquired when using non-linear classification techniques, such as the k nearest neighbors method and the Gaussian kernel support vector machine. For fuel with cooling times up to 20 years, when it is considered that gamma-rays from the isotope 134Cs can still be efficiently measured, success rates of 100% were obtained. A sensitivity analysis indicated that these methods were also robust.

  11. Study of inhibition on lipid oxidation of irradiated pork

    International Nuclear Information System (INIS)

    Ha Yiming

    2006-03-01

    It was studied that the effect factors of irradiation dose, preservation temperature, oxygen content and antioxidant on lipid oxidation of irradiated pork. A mechanism was explained on lipid oxidation of irradiated pork. The results showed that irradiation might aggravate lipid oxidation of pork and that decreased preservation temperature and oxygen content of the packaging, added antioxidant also could effectively inhibit lipid oxidation of irradiated pork. (authors)

  12. Dry storage of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Tolmie, R.D.

    1983-01-01

    In transferring radioactive material between the preparation and clean chambers of a dry storage complex, irradiated nuclear fuel is posted from the preparation chamber to a sealable canister supported in a closable bucket in the clean chamber, or a contaminated sealed canister is posted from a closed bucket in the clean chamber into the preparation chamber by using a facility comprising two coaxial tubes constituting a closable orifice between the two chambers, the tubes providing sealing means for the bucket, and masking means for the bucket and canister closures together with means for withdrawing the closures into the preparation chamber. (author)

  13. UK irradiation experience relevant to advanced carbide fuel concepts for LMFBR's

    International Nuclear Information System (INIS)

    Bagley, K.Q.; Batey, W.; Paris, R.; Sloss, W.M.; Snape, G.P.

    1977-01-01

    Despite discouraging prognoses of fabrication and reprocessing problems, it is recognized that the quest for a carbide fuel pin design which fully exploits the favourable density and thermal conductivity of (U,Pu) monocarbide must be maintained. Studies in aid of carbide fuel development have, therefore, continued in the UK in parallel with those on oxide, albeit at a substantially lower level of effort, and a sufficient body of irradiation experience has been accumulated to allow discrimination of realistic fuel pin designs

  14. Shielding considerations for advanced fuel irradiation experiments

    International Nuclear Information System (INIS)

    Kang, Young-Hwan; Kim, Hee-Moon; Kim, Bong-Goo; Kim, Hark-Rho; Lee, Dong-Soo

    2008-01-01

    An in-pile test program for the development of a high burn-up fuel is planned for the HANARO reactor. The source term originates from a leakage of fission products from the anticipated failed fuels into the gas flow tubes and around the instrumentation and control system. In order to quantify the fuel composition in the event of a fuel failure, the isotope generation and depletion code ORIGEN 2.0 was used. The computer program Microshield 6.2 was used to calculate the doses from specific locations, where a high radioactivity is expected during an irradiation. The results indicate that the equivalent dose in the investigated working areas is less than the permitted dose rate of 6.25 μSv/hr. However, access to the area of a decay vessel may need to be limited, and the installation of a Pb wall with a 20.5 cm thickness is recommended. From the analysis of a radioactive decay with time, most of the concerned gaseous nuclides with short half-lives after 3 months, were decayed, with one exception which was Kr-85, thus it should be released in accordance with applicable government laws after measuring its activity in individual holding vessels. (author)

  15. General considerations on the oxide fuel-cladding chemical interaction

    International Nuclear Information System (INIS)

    Pascard, R.

    1977-01-01

    Since the very first experimental irradiations in thermal reactors, performed in view of the future Rapsodie fuel general study, corrosion cladding anomalies were observed. After 10 years of Rapsodie and more than two years of Phenix, performance brought definite confirmation of the chemical reactions between the irradiated fuel and cladding. That is the reason for which the fuel designers express an urgent need for determining the corrosion rates. Semi-empirical laws and mechanisms describing corrosion processes are proposed. Erratic conditions for appearance of the oxide-cladding corrosion are stressed upon. Obviously such a problem can be fully appreciated only by a statistical approach based on a large number of observations on the true LMFBR fuel pins

  16. Some results on development, irradiation and post-irradiation examinations of fuels for fast reactor-actinide burner (MOX and inert matrix fuel)

    International Nuclear Information System (INIS)

    Poplavsky, V.; Zabudko, L.; Moseev, L.; Rogozkin, B.; Kurina, I.

    1996-01-01

    Studies performed have shown principal feasibility of the BN-600 and BN-800 cores to achieve high efficiency of Pu burning when MOX fuel with Pu content up to 45% is used. Valuable experience on irradiation behaviour of oxide fuel with high Pu content (100%) was gained as a result of operation of two BR-10 core loadings where the maximum burnup 14 at.% was reached. Post-irradiation examination (PIE) allowed to reveal some specific features of the fuel with high plutonium content. Principal irradiation and PIE results are presented in the paper. Use of new fuel without U-238 provides the maximum burning capability as in this case the conversion ratio is reduced to zero. Technological investigations of inert matrix fuels have been continued now. Zirconium carbide, zirconium nitride, magnesium oxide and other matrix materials are under consideration. Inert matrices selection criteria are discussed in the paper. Results of technological study, of irradiation in the BOR-60 reactor and PIE results of some inert matrix fuels are summarized in this report. (author). 2 refs, 1 fig., 3 tabs

  17. Device for taking gaseous samples from irradiated fuel elements

    International Nuclear Information System (INIS)

    Lengacker, B.

    1983-01-01

    The described device allows to take gaseous samples from irradiated fuel elements. It is connected with a gas analyzer and a pressure gage, so that in opening the fuel can the internal pressure can be determined

  18. SP-100 Fuel Pin Performance: Results from Irradiation Testing

    Science.gov (United States)

    Makenas, Bruce J.; Paxton, Dean M.; Vaidyanathan, Swaminathan; Marietta, Martin; Hoth, Carl W.

    1994-07-01

    A total of 86 experimental fuel pins with various fuel, liner, and cladding candidate materials have been irradiated in the Experimental Breeder Reactor-II (EBR-II) and the Fast Flux Test Facility (FFTF) reactor as part of the SP-100 fuel pin irradiation testing program. Postirradiation examination results from these fuel pins are key in establishing performance correlations and demonstrating the lifetime and safety of the reactor fuel system. This paper provides a brief description of the in-reactor fuel pin tests and presents the most recent irradiation data on the performance of wrought rhenium (Re) liner material and high density UN fuel at goal burnup of 6 atom percent (at. %). It also provides an overview of the significant variety of other fuel/liner/cladding combinations which were irradiated as part of this program and which may be of interest to more advanced efforts.

  19. Coordinated irradiation plan for the Fuel Refabrication and Development Program

    International Nuclear Information System (INIS)

    Barner, J.O.

    1979-04-01

    The Department of Energy's Fuel Refabrication and Development (FRAD) Program is developing a number of proliferation-resistant fuel systems and forms for alternative use in nuclear reactors. A major portion of the program is the development of irradiation behavioral information for the fuel system/forms with the ultimate objective of qualifying the design for licensing and commercial utilization. The nuclear fuel systems under development include denatured thoria--urania fuels and spiked urania--plutonia or thoria--plutonia fuels. The fuel forms being considered include pellet fuel produced from mechanically mixed or coprecipitated feed materials, pellet fuel fabricated from partially calcined gel-derived or freeze-dried spheres (hybrid fuel) and packed-particle fuel produced from sintered gel-derived spheres (sphere-pac). This document describes the coordinated development program that will be used to test and demonstrate the irradiation performance of alternative fuels

  20. Fuel temperature prediction during high burnup HTGR fuel irradiation test. US-JAERI irradiation test for HTGR fuel

    International Nuclear Information System (INIS)

    Sawa, Kazuhiro; Fukuda, Kousaku; Acharya, R.

    1995-01-01

    This report describes the preirradiation thermal analysis of the HRB-22 capsule designed for an irradiation test in a removable beryllium position of the High Flux Isotope Reactor(HFIR) at Oak Ridge National Laboratory. This test is being carried out under Annex 2 of the Arrangement between the U.S. Department of Energy and the Japan Atomic Energy Research Institute on Cooperation in Research and Development regarding High-Temperature Gas-cooled Reactors. The fuel used in the test is an advanced type. The advanced fuel was designed aiming at burnup of about 10%FIMA(% fissions per initial metallic atom) which was higher than that of the first charge fuel for the High Temperature Engineering Test Reactor(HTTR) and was produced in Japan. CACA-2, a heavy isotope and fission product concentration calculational code for experimental irradiation capsules, was used to determine time-dependent fission power for the fuel compacts. The Heat Engineering and Transfer in Nine Geometries(HEATING) code was used to solve the steady-state heat conduction problem. The diameters of the graphite fuel body, which contains the fuel compacts, and of the primary pressure vessel were determined such that the requirements of running the fuel compacts at an average temperature less than 1250degC and of not exceeding a maximum fuel temperature of 1350degC were met throughout the four cycles of irradiation. The detail design of the capsule was carried out based on this analysis. (author)

  1. Behavior of solid fission products in irradiated fuel

    International Nuclear Information System (INIS)

    Song, Ung Sup; Jung, Yang Hong; Kim, Hee Moon; Yoo, Byun Gok; Kim, Do Sik; Choo, Yong Sun; Hong, Kwon Pyo

    2004-01-01

    Many fission products are generated by fission events in UO 2 fuel under irradiation in nuclear reactor. Concentration of each fission product is changed by conditions of neutron energy spectrum, fissile material, critical thermal power, irradiation period and cooling time. Volatile materials such as Cs and I, the fission products, degrade nuclear fuel rod by the decrease of thermal conductivity in pellet and the stress corrosion cracking in cladding. Metal fission products (white inclusion) make pellet be swelled and decrease volume of pellet by densification. It seems that metal fission products are filled in the pore in pellet and placed between UO 2 lattices as interstitial. In addition, metal oxide state may change structural lattice volume. Considering behavior of fission products mentioned above, concentration of them is important. Fission products could be classified as bellows; solid solution in matrix : Sr, Zr, Nb, Y, La, Ce, Pr, Nd, Pm, Sm - metal precipitates : Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sb, Te - oxide precipitates : Ba, Zr, Nb, Mo, (Rb, Cs, Te) - volatile and gases : Kr, Xe, Br, I, (Rb, Cs, Te)

  2. Modeling of coated fuel particles irradiation behavior

    International Nuclear Information System (INIS)

    Liang Tongxiang; Phelip, M.

    2006-01-01

    In this report, PANAMA code was used to estimate the CP performance under normal and accident condition. Under the normal irradiation test (1000 degree C 625 efpd, 10% FIMA), for intact CP fuel, failure fraction is in the level of 10 -7 . As-fabricated SiC failed particles results in the through coatings failed particles much earlier than the intact particles does, OPyC layer does not fail immediately after irradiation starts. The significant failures start at beyond the burnup of about 7% FIMA. Under the accident condition, the calculated results showed that when the heating temperature is much higher than 1850 degree C, the failure fraction of coated particle can reach the level of 1 percent. The CP fuel fails significantly if it has a buffer layer thinner than 65 urn, SiC layer thinner than 30 μm. High burnup CP need to develop small size kernel, thick buffer layer and thick SiC layer. (authors)

  3. Irradiation performance of AGR-1 high temperature reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Demkowicz, Paul A., E-mail: paul.demkowicz@inl.gov [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Hunn, John D. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Ploger, Scott A. [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Morris, Robert N.; Baldwin, Charles A. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Harp, Jason M.; Winston, Philip L. [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Gerczak, Tyler J. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Rooyen, Isabella J. van [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Montgomery, Fred C.; Silva, Chinthaka M. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States)

    2016-09-15

    Highlights: • Post-irradiation examination was performed on AGR-1 coated particle fuel. • Cesium release from the particles was very low in the absence of failed SiC layers. • Silver release was often substantial, and varied considerably with temperature. • Buffer and IPyC layers were found to play a key role in TRISO coating behavior. • Fission products palladium and silver were found in the SiC layer of particles. - Abstract: The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.6% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel including the extent of fission product release and the evolution of kernel and coating microstructures was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of {sup 110m}Ag from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocarbon and compact matrix. The capsule-average fractional release from the compacts was 1 × 10{sup −4} to 5 × 10{sup −4} for {sup 154}Eu and 8 × 10{sup −7} to 3 × 10{sup −5} for {sup 90}Sr. The average {sup 134}Cs fractional release from compacts was <3 × 10{sup −6} when all particles maintained intact SiC. An estimated four particles out of 2.98 × 10{sup 5} in the experiment experienced partial cesium release due to SiC failure during the irradiation, driving {sup 134}Cs fractional release in two capsules to approximately 10{sup −5}. Identification and characterization of these particles has provided unprecedented insight into

  4. The Analysis Of Spent Fuel Utilization For A Gamma Irradiator

    International Nuclear Information System (INIS)

    MS, Pudjijanto; Setiyanto

    2002-01-01

    The gamma irradiator using RSG-GAS spent fuels was analyzed. The cylindrical geometry of the irradiator was designed by locating the spent fuels the cylindrical periphery. The analysis was focused to evaluate the feasibilities of the irradiator as a fruits and vegetables irradiator. The spent fuels activities were calculated using Origen2 code, while the dose rate at the irradiation positions was determined by linear attenuation model with transport coefficient. The evaluated results showed that the cylindrical geometry of irradiators with diameter around 1-1.5 m gave the effective dose rate for fruits and vegetables preservation. It can be concluded that one can use the RSG-GAS spent fuels effectively as a gamma irradiator for certain applications

  5. Oxidative dissolution of ADOPT compared to standard UO2 fuel

    International Nuclear Information System (INIS)

    Nilsson, Kristina; Roth, Olivia; Jonsson, Mats

    2017-01-01

    In this work we have studied oxidative dissolution of pure UO 2 and ADOPT (UO 2 doped with Al and Cr) pellets using H 2 O 2 and gammaradiolysis to induce the process. There is a small but significant difference in the oxidative dissolution rate of UO 2 and ADOPT pellets, respectively. However, the difference in oxidative dissolution yield is insignificant. Leaching experiments were also performed on in-reactor irradiated ADOPT and UO 2 pellets under oxidizing conditions. The results indicate that the U(VI) release is slightly slower from the ADOPT pellet compared to the UO 2. This could be attributed to differences in exposed surface area. However, fission products with low UO 2 solubility display a higher relative release from ADOPT fuel compared to standard UO 2 -fuel. This is attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel. The release of Cs is higher from UO 2 which is attributed to the larger grain size of ADOPT. - Highlights: •Oxidative dissolution of ADOPT fuel is compared to standard UO 2 fuel. •Only marginal differences are observed. •The main difference observed is in the relative release rate of fission products. •Differences are claimed to be attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel.

  6. Melting temperature of uranium - plutonium mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Tetsuya; Hirosawa, Takashi [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center

    1997-08-01

    Fuel melting temperature is one of the major thermodynamical properties that is used for determining the design criteria on fuel temperature during irradiation in FBR. In general, it is necessary to evaluate the correlation of fuel melting temperature to confirm that the fuel temperature must be kept below the fuel melting temperature during irradiation at any conditions. The correlations of the melting temperature of uranium-plutonium mixed oxide (MOX) fuel, typical FBR fuel, used to be estimated and formulized based on the measured values reported in 1960`s and has been applied to the design. At present, some experiments have been accumulated with improved experimental techniques. And it reveals that the recent measured melting temperatures does not agree well to the data reported in 1960`s and that some of the 1960`s data should be modified by taking into account of the recent measurements. In this study, the experience of melting temperature up to now are summarized and evaluated in order to make the fuel pin design more reliable. The effect of plutonium content, oxygen to metal ratio and burnup on MOX fuel melting was examined based on the recent data under the UO{sub 2} - PuO{sub 2} - PuO{sub 1.61} ideal solution model, and then formulized. (J.P.N.)

  7. Melting temperature of uranium - plutonium mixed oxide fuel

    International Nuclear Information System (INIS)

    Ishii, Tetsuya; Hirosawa, Takashi

    1997-08-01

    Fuel melting temperature is one of the major thermodynamical properties that is used for determining the design criteria on fuel temperature during irradiation in FBR. In general, it is necessary to evaluate the correlation of fuel melting temperature to confirm that the fuel temperature must be kept below the fuel melting temperature during irradiation at any conditions. The correlations of the melting temperature of uranium-plutonium mixed oxide (MOX) fuel, typical FBR fuel, used to be estimated and formulized based on the measured values reported in 1960's and has been applied to the design. At present, some experiments have been accumulated with improved experimental techniques. And it reveals that the recent measured melting temperatures does not agree well to the data reported in 1960's and that some of the 1960's data should be modified by taking into account of the recent measurements. In this study, the experience of melting temperature up to now are summarized and evaluated in order to make the fuel pin design more reliable. The effect of plutonium content, oxygen to metal ratio and burnup on MOX fuel melting was examined based on the recent data under the UO 2 - PuO 2 - PuO 1.61 ideal solution model, and then formulized. (J.P.N.)

  8. Report of Post Irradiation Examination for Dry Process Fuel

    International Nuclear Information System (INIS)

    Par, Jang Jin; Jung, I. H.; Kang, K. H.; Moon, J. S.; Lee, C. R.; Ryu, H. J.; Song, K. C.; Yang, M. S.; Yoo, B. O.; Jung, Y. H.; Choo, Y. S.

    2006-08-01

    The spent PWR fuel typically contains 0.9 wt.% of fissile uranium and 0.6 wt.% of fissile plutonium, which exceeds the natural uranium fissile content of 0.711 wt.%. The neutron economy of a CANDU reactor is sufficient to utilize the DUPIC fuel, even though the neutron-absorbing fission products contained in the spent PWR fuel were remained in the DUPIC fuel. The DUPIC fuel cycle offers advantages to the countries operating both the PWR and CANDU reactors, such as saving the natural uranium, reducing the spent fuel in both PWR and CANDU, and acquiring the extra energy by reuse of the PWR spent fuel. This report contains the results of post-irradiation examination of the DUPIC fuel irradiated four times at HANARO from May 2000 to August 2006 present except the first irradiation test of simulated DUPIC fuel at HANARO on August 1999

  9. Reprocessing fuel from the Southwest Experimental Fast Oxide Reactor at the Savannah River Plant

    International Nuclear Information System (INIS)

    Gray, L.W.; Campbell, T.G.

    1985-11-01

    The irradiated fuel, reject fuel tubes, and fuel fabrication scrap from the Southwest Experimental Fast Oxide Reactor (SEFOR) were transferred to the Savannah River Plant (SRP) for uranium and plutonium recovery. The unirradiated material was declad and dissolved at SRP; dissolution was accomplished in concentrated nitric acid without the addition of fluoride. The irradiated fuel was declad at Atomics International and repacked in aluminum. The fuel and aluminum cans were dissolved at SRP using nitric acid catalyzed by mercuric nitrate. As this fuel was dissolved in nongeometrically favorable tanks, boron was used as a soluble neutron poison

  10. Irradiation performance updates on Korean advanced fuels for PWRs

    International Nuclear Information System (INIS)

    Jang, Y.K.; Jeon, K.L.; Kim, Y.H.; Yoo, J.S.; Kim, J.I.; Shin, J.C.; Chung, J.G.; Park, J.R.; Chung, S.K.; Kim, T.W.; Yoon, Y.B.; Park, K.M.; Yoo, M.J.; Kim, M.S.; Lee, T.H.

    2010-01-01

    The developments of advanced nuclear fuels for PWRs were started in 1999 and in 2001, respectively: PLUS7 TM for eight operating optimized power reactors of 1000 MWe class (OPR1000) and four advanced power reactors of 1400 MWe class (APR1400) under construction, and 16ACE7 TM and 17ACE7 TM for an operating 16x16 Westinghouse type plant and six operating 17x17 Westinghouse type plants. The design targets were as follows: batch average burnup up to 55 GWD/MTU, over 10% thermal margin increase, improvement of the mechanical integrity of higher seismic capability, higher debris or grid fretting wear performance, higher control rod insertion capability, increase of neutron economy, improvement of manufacturability, solving incomplete rod insertion (IRI) issue and top nozzle screw failure issue, etc. in comparison of the existing nuclear fuels. The irradiation tests using each four LTAs (Lead Test Assemblies) during 3 cycles were completed in three Korean nuclear reactors until 2009. The eight irradiation performance items which are assembly growth, rod growth, grid width growth, assembly bow, rod bow, assembly twist, rod diameter and cladding oxidation were examined in pool-side after each cycle and evaluated. The irradiation tests could be continued by expecting the good performances for next cycle from the previous cycle. After 2 cycle irradiations, the region implementation could be started in 15 nuclear power plants. Even though the verifications using the LTAs were completed, each surveillance program was launched and the irradiation performance data were being updated during region implementation. In addition to pool-side examinations (PSEs) by assembly-wise during irradiation tests, six rod-wise performance items were also examined in pool-side using each LTA after discharge. All performance items met their design criteria as a result of the evaluation. Even though the interesting ones among the irradiation performance parameters were assembly and grid growths

  11. Reirradiation of mixed-oxide fuel pins at increased temperatures

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Weber, E.T.

    1976-05-01

    Mixed-oxide fuel pins from EBR-II irradiations were reirradiated in the General Electric Test Reactor (GETR) at higher temperatures than experienced in EBR-II to study effects of the increased operating temperatures on thermal/mechanical and chemical behavior. The response of a mixed-oxide fuel pin to a power increase after having operated at a lower power for a significant portion of its life-time is an area of performance evaluation where little information currently exists. Results show that the cladding diameter changes resulting from the reirradiation are strongly dependent upon both prior burnup level and the magnitude of the temperature increase. Results provide the initial rough outlines of boundaries within which mixed-oxide fuel pins can or cannot tolerate power increases after substantial prior burnup at lower powers

  12. Irradiation experiments of recycled PuO2-UO2 fuels by SAXTON reactor, (1)

    International Nuclear Information System (INIS)

    Yumoto, Ryozo; Akutsu, Hideo

    1975-01-01

    Seventy two mixed oxide fuel rods made by PNC were irradiated in Saxton Core 3. This paper generally describes the fuel specifications, the power history of the fuel and the post-irradiation examination of the PNC fuel. The specifications of the 4.0 w/o and 5.0 w/o enriched PuO 2 fuel rods with zircaloy-4 cladding are presented in a table and a figure. The positions of PNC fuel rods in the Saxton reactor are shown in a figure. Sixty eight 5.0 w/o PuO 2 -UO 2 fuel rods were assembled in a 9 x 9 rod array together with zircaloy-4 bars, a flux thimble, and a Sb-Be source. The power history of the Saxton Core 3 and the irradiation history of the PNC fuel rods are summarized in tables. The peak power and burnup of each fuel rod and the axial power profile are also presented. The maximum linear power rate and burnup attained were 512W/cm and 8700 MWD/T, respectively. As for the post irradiation examination, the items of nondestructive test, destructive test, and cladding test are presented together with the working flow diagram of the examination. It is concluded that the performance of all fuel rods was safe and satisfactory throughout the power history. (Aoki, K.)

  13. Behavior of molybdenum in mixed-oxide fuel

    International Nuclear Information System (INIS)

    Giacchetti, G.; Sari, C.

    1976-01-01

    Metallic molybdenum, Mo--Ru--Rh--Pd alloys, barium, zirconium, and tungsten were added to uranium and uranium--plutonium oxides by coprecipitation and mechanical mixture techniques. This material was treated in a thermal gradient similar to that existing in fuel during irradiation to study the behavior of molybdenum in an oxide matrix as a function of the O/(U + Pu) ratio and some added elements. Result of ceramographic and microprobe analysis shows that when the overall O/(U + Pu) ratio is less than 2, molybdenum and Mo--Ru--Rh--Pd alloy inclusions are present in the uranium--plutonium oxide matrix. If the O/(U + Pu) ratio is greater than 2, molybdenum oxidizes to MoO 2 , which is gaseous at a temperature approximately 1000 0 C. Molybdenum oxide vapor reacts with barium oxide and forms a compound that exists as a liquid phase in the columnar grain region. Molybdenum oxide also reacts with tungsten oxide (tungsten is often present as an impurity in the fuel) and forms a compound that contains approximately 40 wt percent of actinide metals. The apparent solubility of molybdenum in uranium and uranium--plutonium oxides, determined by electron microprobe, was found to be less than 250 ppM both for hypo- and hyperstoichiometric fuels

  14. WWER fuel: Results of post irradiation examination

    International Nuclear Information System (INIS)

    Markov, D.V.; Smirnov, V.P.; Smirnov, A.V.; Polenok, V.S.; Perepelkin, S.O.; Ivashchenko, A.A.

    2006-01-01

    Experience in the field of fabrication, operation, testing and post-irradiation examinations (PIE) made it possible to settle the following requirements for a new generation of WWER nuclear fuel: - For WWER-1000 FA, the service life is no less than 5 years, 3 alternative fuel cycles (FC): 12 months x 4 FCs, 12 months x 5 FCs and 18 months x 3 FCs; - For WWER-440 FA, fuel cycle is 12 months x 5 FCs and a part of operating assembly is left for the 6. year; - High fuel burnup - up to 70 MWd/kgU; - Dimensional stability of FA and its components; - FA repairability; - Adaptability of fuel cycles; - Maintenance of maneuvering operating conditions at the NPP; - Reliability of control rod operation; - High serviceability level - FE leakage is no worse than 10-5 l/year. In order to provide the fulfillment of the above-given requirements, designers and production engineers have worked out cumulative measures and engineering solutions, which are introduced in development of a new generation fuel. Currently old design FA-M assemblies provided with steel skeleton are being operated in WWER-1000 reactors at Ukrainian and Bulgarian NPPs. As for Russian NPPs, new-type FAs are operated. These are advanced FAs (AFA), FA-A and FA-2 provided with zirconium alloy skeletons. A design of the second generation of WWER-440 operating assemblies was developed with respect to changes in some geometrical parameters, fastening of FEs in the lower grid (splinting was substituted for collet), usage of reinforcing rib under the lower grid, anti-debris filter and hafnium elements of junction unit as well as hafnium content decrease from 0.05 % mass down to 0.01% mass in zirconium materials. They are basic designs of FAs in order to be introduced in a five-year fuel cycle of WWER-440 NPPs in Czech Republic and Slovakia since 2005 and have got prospects for development. The operating experience of dismountable operating assemblies at the Loviisa NPP, vibration-proof operating assemblies at the

  15. Evaluation of fuel rods behavior - under irradiation test

    International Nuclear Information System (INIS)

    Lameiras, F.S.; Terra, J.L.; Pinto, L.C.M.; Dias, M.S.; Pinheiro, R.B.

    1981-04-01

    By the accompanying of the irradiation of instrumented test fuel rods simulating the operational conditions in reactors, plus the results of post - irradiation exams, tests, evaluation and calibration of analitic modelling of such fuel rods is done. (E.G.) [pt

  16. Experience with oxide fuel for advanced reactors

    International Nuclear Information System (INIS)

    Leggett, R.D.

    1984-01-01

    This paper focuses on the use and potential of oxide fuel systems for the LMFBR. The flawless performance of mixed oxide (UO 2 -PuO 2 ) fuel in FFTF to 100,000 MWd/MTM is reviewed and means for achieving 200,000 MWd/MTM are presented. This includes using non-swelling alloys for cladding and ducts to overcome the limitations caused by swelling of the current alloys. Examples are provided of the inherently safe characteristics of oxide fuel including a large negative Doppler coefficient, its dispersive nature under hypothetical accident scenarios, and the low energy molten fuel-coolant interaction. Developments in fuel fabrication and reprocessing that stress safety and reduced personnel exposure are presented. Lastly, the flexibility to design for maximum fuel supply (high breeding gain) or minimum fuel cost (long lifetime) is shown

  17. Electrolytes for solid oxide fuel cells

    Science.gov (United States)

    Fergus, Jeffrey W.

    The high operating temperature of solid oxide fuel cells (SOFCs), as compared to polymer electrolyte membrane fuel cells (PEMFCs), improves tolerance to impurities in the fuel, but also creates challenges in the development of suitable materials for the various fuel cell components. In response to these challenges, intermediate temperature solid oxide fuel cells (IT-SOFCs) are being developed to reduce high-temperature material requirements, which will extend useful lifetime, improve durability and reduce cost, while maintaining good fuel flexibility. A major challenge in reducing the operating temperature of SOFCs is the development of solid electrolyte materials with sufficient conductivity to maintain acceptably low ohmic losses during operation. In this paper, solid electrolytes being developed for solid oxide fuel cells, including zirconia-, ceria- and lanthanum gallate-based materials, are reviewed and compared. The focus is on the conductivity, but other issues, such as compatibility with electrode materials, are also discussed.

  18. Electrolytes for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Fergus, Jeffrey W. [Auburn University, Materials Research and Education Center, 275 Wilmore Laboratories, Auburn, AL 36849 (United States)

    2006-11-08

    The high operating temperature of solid oxide fuel cells (SOFCs), as compared to polymer electrolyte membrane fuel cells (PEMFCs), improves tolerance to impurities in the fuel, but also creates challenges in the development of suitable materials for the various fuel cell components. In response to these challenges, intermediate temperature solid oxide fuel cells (IT-SOFCs) are being developed to reduce high-temperature material requirements, which will extend useful lifetime, improve durability and reduce cost, while maintaining good fuel flexibility. A major challenge in reducing the operating temperature of SOFCs is the development of solid electrolyte materials with sufficient conductivity to maintain acceptably low ohmic losses during operation. In this paper, solid electrolytes being developed for solid oxide fuel cells, including zirconia-, ceria- and lanthanum gallate-based materials, are reviewed and compared. The focus is on the conductivity, but other issues, such as compatibility with electrode materials, are also discussed. (author)

  19. Experience with oxide fuel for advanced reactors

    International Nuclear Information System (INIS)

    Leggett, R.D.

    1984-04-01

    This paper focuses on the use and potential of oxide fuel system for the LMFBR. The flawless performance of mixed oxide (UO 2 -PuO 2 ) fuel in FFTF to 100,000 MWd/MTM is reviewed and means for achieving 200,000 MWd/MTM are presented. This includes using non-swelling alloys for cladding and ducts to overcome the limitations caused by swelling of the current alloys. Exampled are provided of the inherently safe characteristics of oxide fuel including a large negative Doppler coefficient, its dispersive nature under hypothetical accident scenarios, and the low energy molten fuel-coolant interaction. Developments in fuel fabrication and reprocessing that stress safety and reduced personnel exposure are presented. Lastly, the flexibility to design for maximum fuel supply (high breeding gain) or minimum fuel cost (long lifetime) is shown

  20. Irradiation test of fuel containing minor actinides in the experimental fast reactor Joyo

    International Nuclear Information System (INIS)

    Soga, Tomonori; Sekine, Takashi; Wootan, David; Tanaka, Kosuke; Kitamura, Ryoichi; Aoyama, Takafumi

    2007-01-01

    The mixed oxide containing minor actinides (MA-MOX) fuel irradiation program is being conducted using the experimental fast reactor Joyo of the Japan Atomic Energy Agency to research early thermal behavior of MA-MOX fuel. Two irradiation experiments were conducted in the Joyo MK-III 3rd operational cycle. Six prepared fuel pins included MOX fuel containing 3% or 5% americium (Am-MOX), MOX fuel containing 2% americium and 2% neptunium (Np/Am-MOX), and reference MOX fuel. The first test was conducted with high linear heat rates of approximately 430 W/cm maintained during only 10 minutes in order to confirm whether or not fuel melting occurred. After 10 minutes irradiation in May 2006, the test subassembly was transferred to the hot cell facility and an Am-MOX pin and a Np/Am-MOX pin were replaced with dummy pins including neutron dosimeters. The test subassembly loaded with the remaining four fuel pins was re-irradiated in Joyo for 24-hours in August 2006 at nearly the same linear power to obtain re-distribution data on MA-MOX fuel. Linear heat rates for each pin were calculated using MCNP, accounting for both prompt and delayed heating components, and then adjusted using E/C for 10 B (n, α) reaction rates measured in the MK-III core neutron field characterization test. Post irradiation examination of these pins to confirm the fuel melting and the local concentration under irradiation of NpO 2-x or AmO 2-x in the (U, Pu)O 2-x fuel are underway. The test results are expected to reduce uncertainties on the design margin in the thermal design for MA-MOX fuel. (author)

  1. Transient redistribution of intragranular fission gas in irradiated mixed oxide

    International Nuclear Information System (INIS)

    Hinman, C.A.; Randklev, E.H.

    1981-01-01

    Safety analyses for an LMFBR require a knowledge of the fuel and fission gas behavior under transient conditions. Analyses of microstructural data derived from transiently heated, irradiated, mixed oxide fuel specimens have allowed the calculation of the degree of nonequilibrium of intragranular bubbles formed during the transient. It is hypothesized that the observed over-pressurization of the intragranular bubbles mechanically loads the fuel within the grain, leading to a stress gradient derived force upon near-grain-surface bubbles, driving them preferentially to the grain boundaries. Using existing models for forced diffusion it can be estimated that the stress derived forces on bubbles are within the same magnitude, and possibly greater, than the forces derived from the thermal gradient

  2. Ceramography of Irradiated tristructural isotropic (TRISO) Fuel from the AGR-2 Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Rice, Francine Joyce [Idaho National Lab. (INL), Idaho Falls, ID (United States); Stempien, John Dennis [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-09-01

    Ceramography was performed on cross sections from four tristructural isotropic (TRISO) coated particle fuel compacts taken from the AGR-2 experiment, which was irradiated between June 2010 and October 2013 in the Advanced Test Reactor (ATR). The fuel compacts examined in this study contained TRISO-coated particles with either uranium oxide (UO2) kernels or uranium oxide/uranium carbide (UCO) kernels that were irradiated to final burnup values between 9.0 and 11.1% FIMA. These examinations are intended to explore kernel and coating morphology evolution during irradiation. This includes kernel porosity, swelling, and migration, and irradiation-induced coating fracture and separation. Variations in behavior within a specific cross section, which could be related to temperature or burnup gradients within the fuel compact, are also explored. The criteria for categorizing post-irradiation particle morphologies developed for AGR-1 ceramographic exams, was applied to the particles in the AGR-2 compacts particles examined. Results are compared with similar investigations performed as part of the earlier AGR-1 irradiation experiment. This paper presents the results of the AGR-2 examinations and discusses the key implications for fuel irradiation performance.

  3. An equipment for the dimensional characterization of irradiated fuel channels

    International Nuclear Information System (INIS)

    Cederquist, H.

    1985-01-01

    The reuse of irradiated fuel channels in BWRs is highly beneficial. However, one prerequisite for reuse of a fuel channel is the detailed knowledge of its dimensions, which are affected by irradiation and pressure drop during operation. Therefore an equipment for fast and accurate dimensional measurement of irradiated fuel channels has been developed. The measurements are carried out when the fuel assembly is supported in the same manner as in the reactor core. The equipment utilizes stationary ultrasonic transducers that measure the fuel channel at a number of predetermined axial levels. Measurement data are fed into a computer which calculates the requested dimensional characteristics such as transversal flatness, bow, twist, side perpendicularity etc. Data are automatically printed for subsequent evaluation. Measurements can be performed both when the fuel channel is placed on a fuel bundle and on an empty fuel channel

  4. Performance of advanced oxide fuel pins in EBR-II

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Jensen, S.M.; Hales, J.W.; Karnesky, R.A.; Makenas, B.J.

    1986-05-01

    The effects of design and operating parameters on mixed-oxide fuel pin irradiation performance were established for the Hanford Engineering Development Laboratory (HEDL) advanced oxide EBR-II test series. Fourteen fuel pins breached in-reactor with reference 316 SS cladding. Seven of the breaches are attributed to FCMI. Of the remaining seven breached pins, three are attributed to local cladding over-temperatures similar to the breach mechanism for the reference oxide pins irradiated in EBR-II. FCCI was found to be a contributing factor in two high burnup, i.e., 11.7 at. % breaches. The remaining two breaches were attributed to mechanical interaction of UO 2 fuel and fission products accumulated in the lower cladding insulator gap, and a loss of cladding ductility possibly due to liquid metal embrittlement. Fuel smear density appears to have the most significant impact on lifetime. Quantitative evaluations of cladding diameter increases attributed to FCMI, established fuel smear density, burnup, and cladding thickness-to-diameter ratio as the major parameters influencing the extent of cladding strain

  5. Direct Coal Oxidation in Modified Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Gil, Vanesa; Ippolito, Davide

    2015-01-01

    Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon-carbonate s......Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon......-carbonate slurry or anode layer. The nature of the coal affects both open circuit voltage and power output. Highest OCV and power densities were observed for bituminous coal and by adding manganese oxide or praseodymium-doped ceria to the carbon/carbonate mixture. Comparing the carbon black fueled performance...... bituminous coal (73 mW/cm2). © 2015 ECS - The Electrochemical Society...

  6. Direct Coal Oxidation in Modified Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Gil, Vanesa; Ippolito, Davide

    2017-01-01

    Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon-carbonate s......Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon......-carbonate slurry or anode layer. The nature of the coal affects both open circuit voltage and power output. Highest OCV and power densities were observed for bituminous coal and by adding manganese oxide or praseodymium-doped ceria to the carbon/carbonate mixture. Comparing the carbon black fueled performance...... bituminous coal (73 mW/cm2)....

  7. Oxidation kinetic changes of UO2 by additive addition and irradiation

    International Nuclear Information System (INIS)

    You, Gil-Sung; Kim, Keon-Sik; Min, Duck-Kee; Ro, Seung-Gy

    2000-01-01

    The kinetic changes of air-oxidation of UO 2 by additive addition and irradiation were investigated. Several kinds of specimens, such as unirradiated-UO 2 , simulated-UO 2 for spent PWR fuel (SIMFUEL), unirradiated-Gd-doped UO 2 , irradiated-UO 2 and -Gd-doped UO 2 , were used for these experiments. The oxidation results represented that the kinetic patterns among those samples are remarkably different. It was also revealed that the oxidation kinetics of irradiated-UO 2 seems to be more similar to that of unirradiated-Gd-doped UO 2 than that of SIMFUEL

  8. Study of bixin oxidation by ionizing irradiation

    International Nuclear Information System (INIS)

    Fonseca, Thais N.; Teixeira, Paula S.; Moura, Eduardo de; Geraldo, Áurea Beatriz C.

    2017-01-01

    Brazil is the world's largest producer of anatto, followed by Kenya and Peru. The fruit of the annatto tree is constituted by a capsule containing external spines and internal seeds with reddish coloration, providing a natural pigment which is environmentally efficient, being able to replace synthetic pigments and dyes. The active substance of the pigment is Bixin, which is a type of carotenoid which constitutes a greater percentage of pigment in these seeds and has a lipo soluble character. Bixin reacts with NaOH in a saponification reaction giving norbixin, which is water soluble. It is known that the destination of the dye extracted from the fruit is intended for industry, especially the food industry. The culture of annatto tree brings prospects of development in agricultural programs for medium and small producers, which are able to use decadent areas of other crops. In addition to the food sector, new applications for the pigment helps the development of family farming. The pigment extracted from annatto undergoes a natural oxidation; this work aims to evaluate this phenomenon and also the oxidation of the pigment after the irradiation process. This work also evaluates of the how the oxidation process is affected by irradiation and the modifications introduced to irradiated pigments. Irradiated and nonirradiated samples were characterized by thermogravimetry, UV-vis spectrophotometry and infrared spectroscopy (FTIR). The results are then discussed. (author)

  9. Jet Fuel Based High Pressure Solid Oxide Fuel Cell System

    Science.gov (United States)

    Gummalla, Mallika (Inventor); Yamanis, Jean (Inventor); Olsommer, Benoit (Inventor); Dardas, Zissis (Inventor); Bayt, Robert (Inventor); Srinivasan, Hari (Inventor); Dasgupta, Arindam (Inventor); Hardin, Larry (Inventor)

    2015-01-01

    A power system for an aircraft includes a solid oxide fuel cell system which generates electric power for the aircraft and an exhaust stream; and a heat exchanger for transferring heat from the exhaust stream of the solid oxide fuel cell to a heat requiring system or component of the aircraft. The heat can be transferred to fuel for the primary engine of the aircraft. Further, the same fuel can be used to power both the primary engine and the SOFC. A heat exchanger is positioned to cool reformate before feeding to the fuel cell. SOFC exhaust is treated and used as inerting gas. Finally, oxidant to the SOFC can be obtained from the aircraft cabin, or exterior, or both.

  10. Irradiation performance of HTGR fuel in HFIR capsule HT-31

    International Nuclear Information System (INIS)

    Tiegs, T.N.; Robbins, J.M.; Hamner, R.L.; Montgomery, B.H.; Kania, M.J.; Lindemer, T.B.; Morgan, C.S.

    1979-05-01

    The capsule was irradiated in the High Flux Isotope Reactor at ORNL to peak particle temperatures up to 1600 0 C, fast neutron fluences (0.18 MeV) up to 9 x 10 25 n/m 2 , and burnups up to 8.9% FIMA for ThO 2 particles. The oxygen release from plutonium fissions was less than calculated, possibly because of the solid solution of SrO and rare earth oxides in UO 2 . Tentative results show that pyrocarbon permeability decreases with increasing fast neutron fluence. Fission products in sol-gel UO 2 particles containing natural uranium mostly behaved similarly to those in particles containing highly enriched uranium (HEU). Thus, much of the data base collected on HEU fuel can be applied to low-enriched fuel. Fission product palladium penetrated into the SiC on Triso-coated particles. Also the SiC coating provided some retention of /sup 110m/Ag. Irradiation above about 1200 0 C without an outer pyrocarbon coating degraded the SiC coating on Triso-coated particles

  11. Fuel pins irradiation: experimental devices and analytical behaviour

    International Nuclear Information System (INIS)

    Lemaignan, C.

    1996-01-01

    In this text we present the general characteristics of adapted irradiation loops in research reactors and the main results that we can expected with these loops in the behaviour field of PWR and LMFBR fuels( fuel densification, fuel cladding interactions, fission products release, reactor accidents)

  12. HFR irradiation testing of light water reactor (LWR) fuel

    International Nuclear Information System (INIS)

    Markgraf, J.F.W.

    1985-01-01

    For the materials testing reactor HFR some characteristic information with emphasis on LWR fuel rod testing capabilities and hot cell investigation is presented. Additionally a summary of LWR fuel irradiation programmes performed and forthcoming programmes are described. Project management information and a list of publications pertaining to LWR fuel rod test programmes is given

  13. A general evaluation of the irradiation behaviour of dispersion fuels

    International Nuclear Information System (INIS)

    Hofman, G.L.

    1995-01-01

    The irradiation behaviour of aluminum-based dispersion fuels is evaluated with emphasis on metallurgical processes that control the dispersion behaviour. Phase transformations and microstructural changes resulting from fuel-matrix interactions and the effect of fissioning in fuel are discussed. (author)

  14. A conceptual model for the fuel oxidation of defective fuel

    International Nuclear Information System (INIS)

    Higgs, J.D.; Lewis, B.J.; Thompson, W.T.; He, Z.

    2007-01-01

    A mechanistic conceptual model has been developed to predict the fuel oxidation behaviour in operating defective fuel elements for water-cooled nuclear reactors. This theoretical work accounts for gas-phase transport and sheath reactions in the fuel-to-sheath gap to determine the local oxygen potential. An improved thermodynamic analysis has also been incorporated into the model to describe the equilibrium state of the oxidized fuel. The fuel oxidation kinetics treatment accounts for multi-phase transport including normal diffusion and thermodiffusion for interstitial oxygen migration in the solid, as well as gas-phase transport in the fuel pellet cracks. The fuel oxidation treatment is further coupled to a heat conduction equation. A numerical solution of the coupled transport equations is obtained by a finite-element technique with the FEMLAB 3.1 software package. The model is able to provide radial-axial profiles of the oxygen-to-uranium ratio and the fuel temperatures as a function of time in the defective element for a wide range of element powers and defect sizes. The model results are assessed against coulometric titration measurements of the oxygen-to-metal profile for pellet samples taken from ten spent defective elements discharged from the National Research Universal Reactor at the Chalk River Laboratories and commercial reactors

  15. Post-irradiation examination of CANDU fuel bundles fuelled with (Th, Pu)O2

    International Nuclear Information System (INIS)

    Karam, M.; Dimayuga, F.C.; Montin, J.

    2010-01-01

    AECL has extensive experience with thoria-based fuel irradiations as part of an ongoing R&D program on thorium within the Advanced Fuel Cycles Program. The BDL-422 experiment was one component of the thorium program that involved the fabrication and irradiation testing of six Bruce-type bundles fuelled with (Th, Pu)O 2 pellets. The fuel was manufactured in the Recycle Fuel Fabrication Laboratories (RFFL) at Chalk River allowing AECL to gain valuable experience in fabrication and handling of thoria fuel. The fuel pellets contained 86.05 wt.% Th and 1.53 wt.% Pu in (Th, Pu)O 2 . The objectives of the BDL-422 experiment were to demonstrate the ability of 37-element geometry (Th, Pu)O 2 fuel bundles to operate to high burnups up to 1000 MWh/kgHE (42 MWd/kgHE), and to examine the (Th, Pu)O 2 fuel performance. This paper describes the post-irradiation examination (PIE) results of BDL-422 fuel bundles irradiated to burnups up to 856 MWh/kgHE (36 MWd/kgHE), with power ratings ranging from 52 to 67 kW/m. PIE results for the high burnup bundles (>1000 MWh/kgHE) are being analyzed and will be reported at a later date. The (Th, Pu)O 2 fuel performance characteristics were superior to UO 2 fuel irradiated under similar conditions. Minimal grain growth was observed and was accompanied by benign fission gas release and sheath strain. Other fuel performance parameters, such as sheath oxidation and hydrogen distribution, are also discussed. (author)

  16. Irradiation performance of U-Mo monolithic fuel

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, M. K.; Gan, J.; Jue, J. F.; Keiser, D. D.; Perez, E.; Robinson, A.; Wachs, D. M.; Woolstenhulme, N. [Idaho National Laboratory, Idaho (Korea, Republic of); Kim, Y.S.; Hofman, G. L. [Argonne National Laboratory, Lemont (United States)

    2014-04-15

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. U-Mo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  17. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    Directory of Open Access Journals (Sweden)

    M.K. MEYER

    2014-04-01

    Full Text Available High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  18. Electrometallurgical treatment of oxide spent fuels

    International Nuclear Information System (INIS)

    Karell, E. J.

    1999-01-01

    The Department of Energy (DOE) inventory of spent nuclear fuel contains a wide variety of oxide fuel types that may be unsuitable for direct repository disposal in their current form. The molten-salt electrometallurgical treatment technique developed by Argonne National Laboratory (ANL) has the potential to simplify preparing and qualifying these fuels for disposal by converting them into three uniform product streams: uranium metal, a metal waste form, and a ceramic waste form. This paper describes the major steps in the electrometallurgical treatment process for oxide fuels and provides the results of recent experiments performed to develop and scale up the process

  19. Irradiation behavior of modified high-performance nuclear fuels

    Energy Technology Data Exchange (ETDEWEB)

    Jungwirth, Rainer

    2011-11-03

    To overcome the problem of UMo/Al fuel swelling, four different possibilities have been identified: (i) the modification of the Al matrix by adding diffusion limiting elements (ii) the insertion of a diffusion barrier at the interface UMo-Al (iii) further alloying the UMo with a third element to stabilize the γ-UMo phase (iv) a combination of means (i)-(iii). In consequence, 20 different UMoX/AlY (X=Si, Ti, Mg, Bi, with and without oxidation layer; Y=Nb, Ti, Pt) samples have been examined before and after irradiation with Iodine at 80MeV. First it has been shown, that a protective oxidation layer on the UMo grains does not prevent the formation of a interdiffusion layer. In contrast, additions to the Al matrix can be reduced to the self-acting formation of a protective layer at the UMo/Al interface. Additions to the UMo to stabilize the γ-UMo upon heating are of minor importance since irradiation reverses the phase decomposition of UMo.

  20. Electron microscope study of irradiated beryllium oxide

    International Nuclear Information System (INIS)

    Bisson, A.A.

    1965-06-01

    The beryllium oxide is studied first by fractography, before and after irradiation, using sintered samples. The fractures are examined under different aspects. The higher density sintered samples, with transgranular fractures are the most interesting for a microscopic study. It is possible to mark the difference between the 'pores' left by the sintering process and the 'bubbles' of gases that can be produced by former thermal treatments. After irradiation, the grain boundaries are very much weakened. By annealing, it is possible to observe the evolution of the gases produced by the reaction (n, 2n) and (n. α) and gathered on the grain boundaries. The irradiated beryllium oxide is afterwards studied by transmission. For that, a simple method has been used: little chips of the crushed material are examined. Clusters of point defects produced by neutrons are thus detected in crystals irradiated at the three following doses: 6 x 10 19 , 9 x 10 19 and 2 x 10 20 n f cm -2 at a temperature below 100 deg. C. For the irradiation at 6 x 10 19 n f cm -2 , the defects are merely visible, but at 2 x l0 20 n f cm -2 the crystals an crowded with clusters and the Kikuchi lines have disappeared from the micro-diffraction diagrams. The evolution of the clusters into dislocation loops is studied by a series of annealings. The activation energy (0,37 eV) calculated from the annealing curves suggests that it must be interstitials that condense into dislocation loops. Samples irradiated at high temperatures (650, 900 and 1100 deg. C) are also studied. In those specimens the size of the loops is not the same as the equilibrium size obtained after out of pile annealing at the same temperature. Those former loops are more specifically studied and their Burgers vector is determined by micro-diffraction. (author) [fr

  1. Some UK experience and practice in the packaging and transport of irradiated fuel

    International Nuclear Information System (INIS)

    Edney, C.J.; Rutter, R.L.

    1977-01-01

    The origin and growth of irradiated fuel transport within and to the U.K. is described and the role of the organisations presently carrying out transport operations is explained. An explanation of the relevant U.K. regulations and laws affecting irradiated fuel transport and the role of the controlling body, the Department of the Environment is given. An explanation is given of the technical requirements for the transport of irradiated Magnox fuel and of the type of flask used, and the transport arrangements, both within the U.K. and to the U.K., from overseas is discussed. The technical requirements for the transport of C.A.G.R. fuel are outlined and the flask and transport arrangements are discussed. The transport requirements of oxide fuel from water reactors is outlined and the flask and shipping arrangements under which this fuel is brought to the U.K. from overseas is explained. The shipping arrangements are explained with particular reference to current international and national requirements. The requirements of the transport of M.T.R. fuel are discussed and the flask type explained. The expected future expansion of the transport of irradiated fuel within and to the U.K. is outlined and the proposed operating methods are briefly discussed. A summary is given of the U.K. experience and the lessons to be drawn from that experience

  2. EDF energy generation UK transport of irradiated fuel

    Energy Technology Data Exchange (ETDEWEB)

    James, R. [EDF Energy, London, (United Kingdom)

    2015-07-01

    This paper give an overview of irradiated fuel transport in the UK. It describes the design of irradiated fuel flask used by EDF Energy; operational experience and good practices learnt from over 50 years of irradiated fuel transport. The AGRs can store approximately 9 months generation of spent fuel, hence the ability to transport irradiated fuel is vital. Movements are by road to the nearest railhead, typically less than 2 miles and then by rail to Sellafield, up to 400 miles, for reprocessing or long term storage. Road and rail vehicles are covered. To date in the UK: over 30,000 Magnox flask journeys and over 15,000 AGR A2 flask journeys have been carried out.

  3. Evaluation of burnup characteristics and energy deposition during NSRR pulse irradiation tests on irradiated BWR fuels

    International Nuclear Information System (INIS)

    Nakamura, Takehiko; Yoshinaga, Makio

    2000-11-01

    Pulse irradiation tests of irradiated fuel are performed in the Nuclear Safety Research Reactor (NSRR) to investigate the fuel behavior under Reactivity Initiated Accident Conditions (RIA). The severity of the RIA is represented by energy deposition or peak fuel enthalpy during the power excursion. In case of the irradiated fuel tests, the energy deposition varies depending both on the amounts and distribution of residual fissile and neutron absorbing fission products generated during the base irradiation. Thus, proper fuel burnup characterization, especially for low enriched commercial fuels, is important, because plutonium (Pu) takes a large part of fissile and its generation depends on the neutron spectrum during the base irradiation. Fuel burnup calculations were conducted with ORIGEN2, RODBURN and SWAT codes for the BWR fuels tested in the NSRR. The calculation results were compared with the measured isotope concentrations and used for the NSRR neutron calculations to evaluate energy depositions of the test fuel. The comparison of the code calculations and the measurements revealed that the neutron spectrum change due to difference in void fraction altered Pu generation and energy deposition in the NSRR tests considerably. With the properly evaluated neutron spectrum, the combined burnup and NSRR neutron calculation gave reasonably good evaluation of the energy deposition. The calculations provided radial distributions of the fission product accumulation during the base irradiation and power distribution during the NSRR pulse irradiation, which were important for the evaluation of both burnup characteristics and fission gas release behavior. (author)

  4. Apparatus for inspecting a irradiated nuclear fuel rod

    International Nuclear Information System (INIS)

    Saura, Hideaki; Yonemura, Eizo.

    1975-01-01

    Object: To increase safety and inspection efficiency by operating irradiated fuel rods, which are accommodated in a water-filled pool after being taken out from the reactor. Structure: When making inspection of irradiated fuel rods, particularly the cladding tube thereof, a fuel box which stores irradiated fuel rods in a water pool is secured to a securement mechanism with slime removal apparatus and inspection apparatus on either side capable of being vertically moved, and it is then stopped at a water depth of about 2 meters. When the lid of the box is opened, irradiated fuel rods are taken out with gripping means and then secured together with the gripping means to an operation base provided on the outside of the pool. Thereafter, the box is lowered by operating pedals on the operation base to completely pull out the irradiated fuel rods from the box, and the irradiated fuel rods are then horizontally moved and then held in a suspended state. Next a slime removal apparatus in raised by operating pedals and an inspection element assembly are progressively raised for inspection of the state of the cladding tube of each fuel rod after removal of slime therefrom. (Nakamura, S.)

  5. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Boltax, A [Westinghouse Electric Corporation, Advanced Reactor Division, Madison, PA (United States); Biancheria, A

    1977-04-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  6. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    International Nuclear Information System (INIS)

    Boltax, A.; Biancheria, A.

    1977-01-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  7. The TMI regenerable solid oxide fuel cell

    Science.gov (United States)

    Cable, Thomas L.

    1995-04-01

    Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. These systems generally consist of photovoltaic solar arrays which operate during sunlight cycles to provide system power and regenerate fuel (hydrogen) via water electrolysis; during dark cycles, hydrogen is converted by the fuel cell into system. The currently preferred configuration uses two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Fuel cell/electrolyzer system simplicity, reliability, and power-to-weight and power-to-volume ratios could be greatly improved if both power production (fuel cell) and power storage (electrolysis) functions can be integrated into a single unit. The Technology Management, Inc. (TMI), solid oxide fuel cell-based system offers the opportunity to both integrate fuel cell and electrolyzer functions into one unit and potentially simplify system requirements. Based an the TMI solid oxide fuel cell (SOPC) technology, the TMI integrated fuel cell/electrolyzer utilizes innovative gas storage and operational concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H2O electrode (SOFC anode/electrolyzer cathode) materials for solid oxide, regenerative fuel cells. Improved H2/H2O electrode materials showed improved cell performance in both fuel cell and electrolysis modes in reversible cell tests. ln reversible fuel cell/electrolyzer mode, regenerative fuel cell efficiencies (ratio of power out (fuel cell mode) to power in (electrolyzer model)) improved from 50 percent (using conventional electrode materials) to over 80 percent. The new materials will allow the TMI SOFC system to operate as both the electrolyzer and fuel cell in a single unit. Preliminary system designs have also been developed which indicate the technical feasibility of using the TMI SOFC

  8. A disposal centre for irradiated nuclear fuel: conceptual design study

    International Nuclear Information System (INIS)

    1980-09-01

    This report describes a conceptual design of a disposal centre for irradiated nuclear fuel. The surface facilities consist of plants for the preparation of steel cylinders containing irradiated nuclear fuel immobilized in lead, shaft headframe buildings, and all necessary support facilities. The undergound disposal vault is located on one level at a depth of 1000 metres. The cylinders containing the irradiated fuel are emplaced on a one-metre thick layer of backfill material and then completely covered with backfill. All surface and subsurface facilities are described, operations and schedules are summarized, and cost estimates and manpower requirements are given. (auth)

  9. Gamma-ray spectroscopy on irradiated fuel rods

    International Nuclear Information System (INIS)

    Terremoto, Luis Antonio Albiac

    2009-01-01

    The recording of gamma-ray spectra along an irradiated fuel rod allows the fission products to be qualitatively and quantitatively examined. Among all nondestructive examinations performed on irradiated fuel rods by gamma-ray spectroscopy, the most comprehensive one is the average burnup measurement, which is quantitative. Moreover, burnup measurements by means of gamma-ray spectroscopy are less time-consuming and waste-generating than burnup measurements by radiochemical, destructive methods. This work presents the theoretical foundations and experimental techniques necessary to measure, using nondestructive gamma-ray spectroscopy, the average burnup of irradiated fuel rods in a laboratory equipped with hot cells. (author)

  10. The achivements of Japanese fuel irradiation experiments in HBWR

    International Nuclear Information System (INIS)

    Ichikawa, Michio; Yanagisawa, Kazuaki; Domoto, Kazunari

    1984-02-01

    OECD Halden Reactor Project celebrated the 25th anniversary in 1983. The JAERI has been participating in the Project since 1967 on behalf of Japanese Government. Since the participation, thirty-six Japanese instrumented fuel assemblies have been irradiated in HBWR. The irradiation experiments were either sponsored by JAERI or by domestic organizations under the joint research agreements with JAERI, beeing steered by the Committee for the Joint Research Programme. The cooperative efforts have attained significant contributions to the development of water reactor fuel technology in Japan. This report review the irradiation experiments of Japanese fuel assemblies. (author)

  11. Fuel cycle cost comparisons with oxide and silicide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Matos, J E; Freese, K E [RERTR Program, Argonne National Laboratory (United States)

    1983-09-01

    This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. The status of the development and demonstration of the oxide and silicide fuels are presented in several papers in these proceedings. Routine utilization of these fuels with the uranium densities considered here requires that they are successfully demonstrated and licensed. Thermal-hydraulic safety margins, shutdown margins, mixed cores, and transient analyses are not addressed here, but analyses of these safety issues are in progress for a limited number of the most promising design options. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data is presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires that they are successfully demonstrated and licensed. All safety criteria for the reactor with these fuel element designs need to be satisfied as well. With LEU oxide fuel, 31 g U/cm{sup 3} 1 and 0.76 mm--thick fuel meat, elements with 18-22 plates 320-391 g {sup 235}U) result in the same or lower total costs than with the HEU element 23 plates, 280 g {sup 235}U). Higher LEU loadings (more plates per element) are needed for larger excess reactivity requirements. However, there is little cost advantage to using more than 20 of these plates per element. Increasing the fuel meat thickness from 0.76 mm to 1.0 mm with 3.1 g U/cm{sup 3} in the design with 20 plates per element could result in significant cost reductions if the

  12. Interconnection of bundled solid oxide fuel cells

    Science.gov (United States)

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  13. Study of the lattice parameter evolution of PWR irradiated MOX fuel by X-Ray diffraction

    International Nuclear Information System (INIS)

    Clavier, B.

    1995-01-01

    Fuel irradiation leads to a swelling resulting from the formation of gaseous (Kr, Xe) or solid fission products which are found either in solution or as solid inclusions in the matrix. This phenomena has to be evaluated to be taken into account in fuel cladding Interaction. Fuel swelling was studied as a function of burn up by measuring the corresponding cell constant evolution by X-Ray diffraction. This study was realized on Mixed Oxide Fuels (MOX) irradiated in a Pressurized Water Reactor (PWR) at different burn-up for 3 initial Pu contents. Lattice parameter evolutions were followed as a function of burn-up for the irradiated fuel with and without an annealing thermal treatment. These experimental evolutions are compared to the theoretical evolutions calculated from the hard sphere model, using the fission product concentrations determined by the APPOLO computer code. Contribution of varying parameters influencing the unit cell value is discussed. Thermal treatment effects were checked by metallography, X-Ray diffraction and microprobe analysis. After thermal treatment, no structural change was observed but a decrease of the lattice parameter was measured. This modification results essentially from self-irradiation defect annealing and not from stoichiometry variations. Microprobe analysis showed that about 15% of the formed Molybdenum is in solid solution In the oxide matrix. Micrographs showed the existence of Pu packs in the oxide matrix which induces a broadening of diffraction lines. The RIETVELD method used to analyze the X-Ray patterns did not allow to characterize independently the Pu packs and the oxide matrix lattice parameters. Nevertheless, with this method, the presence of micro-strains in the irradiated nuclear fuel could be confirmed. (author)

  14. Durability of solid oxide fuel cells using sulfur containing fuels

    DEFF Research Database (Denmark)

    Hagen, Anke; Rasmussen, Jens Foldager Bregnballe; Thydén, Karl Tor Sune

    2011-01-01

    The usability of hydrogen and also carbon containing fuels is one of the important advantages of solid oxide fuel cells (SOFCs), which opens the possibility to use fuels derived from conventional sources such as natural gas and from renewable sources such as biogas. Impurities like sulfur compounds...... are critical in this respect. State-of-the-art Ni/YSZ SOFC anodes suffer from being rather sensitive towards sulfur impurities. In the current study, anode supported SOFCs with Ni/YSZ or Ni/ScYSZ anodes were exposed to H2S in the ppm range both for short periods of 24h and for a few hundred hours. In a fuel...

  15. Irradiation Testing of TRISO-Coated Particle Fuel in Korea

    International Nuclear Information System (INIS)

    Kim, Bong Goo; Yeo, Sunghwan; Jeong, Kyung-Chai; Eom, Sung-Ho; Kim, Yeon-Ku; Kim, Woong Ki; Lee, Young Woo; Cho, Moon Sung; Kim, Yong Wan

    2014-01-01

    In Korea, coated particle fuel is being developed to support development of a VHTR. At the end of March 2014, the first irradiation test in HANARO at KAERI to demonstrate and qualify TRISO-coated particle fuel for use in a VHTR was terminated. This experiment was conducted in an inert gas atmosphere without on-line temperature monitoring and control, or on-line fission product monitoring of the sweep gas. The irradiation device contained two test rods, one has nine fuel compacts and the other five compacts and eight graphite specimens. Each compact contains about 260 TRISO-coated particles. The duration of irradiation testing at HANARO was about 135 full power days from last August 2013. The maximum average power per particle was about 165 mW/particle. The calculated peak burnup of the TRISO-coated fuel was a little less than 4 atom percent. Post-irradiation examination is being carried out at KAERI’s Irradiated Material Examination Facility beginning in September of 2014. This paper describes characteristics of coated particle fuel, the design of the test rod and irradiation device for this coated particle fuel, and discusses the technical results of irradiation testing at HANARO. (author)

  16. Design of a transportation cask for irradiated CANDU fuel

    International Nuclear Information System (INIS)

    Nash, K.E.; Gavin, M.E.

    1983-01-01

    A major step in the development of a large-scale transportation system for irradiated CANDU fuel is being made by Ontario Hydro in the design and construction of a demonstration cask by 1988/89. The system being designed is based on dry transportation with the eventual fully developed system providing for dry fuel loading and unloading. Research carried out to date has demonstrated that it is possible to transport irradiated CANDU fuel in a operationally efficient and simple manner without any damage which would prejudice subsequent automated fuel handling

  17. Power-to-melt evaluation of fresh mixed-oxide fast reactor fuel. Technical improvements of the post-irradiation-experiment and the evaluation of the results for the power-to-melt test PTM-2 in 'JOYO'

    International Nuclear Information System (INIS)

    Yamamoto, Kazuya; Kushida, Naoya; Koizumi, Atsuhiro

    1999-11-01

    The second Power-To-Melt (PTM) test, PTM-2, was performed in the experimental fast reactor 'JOYO'. All of the twenty-four fuel pins of the irradiation vehicle, B5D-2, for the PTM-2 test, were provided for post-irradiation-experiment (PIE) to evaluate the PTM values. In this study, the PIE technique for PTM test was established and the PTM results were evaluated. The findings are as follows: The maximum fuel-melting ratio on the transverse section was 10.7%, and was within the limit of fuel-melting in this PTM test enough. Unexpected fuel-melting amount to a ratio of 11.8% was found at ∼24 mm below the peak power elevation in a test fuel pin. It is possible that this arose from secondary fuel-melting. Combination of metallographical observation with X-ray microanalysis of plutonium distribution was very effective for the identification of once-molten fuel zone. The PTM evaluation suggested that dependence of the PTM on the fuel pellet density was stronger than that of previous foreign PTM tests, while the dependence on the pellet-cladding gap and the oxygen-to-metal ratio was indistinctly. The dependence on the cladding temperature and the fill gas composition was not shown as well. (author)

  18. Examination of irradiated fuel elements using gamma scanning technique

    International Nuclear Information System (INIS)

    Ichim, O.; Mincu, M.; Man, I.; Stanica, M.

    2016-01-01

    The purpose of this paper is to validate the gamma scanning technique used to calculate the activity of gamma fission products from CANDU/TRIGA irradiated fuel elements. After a short presentation of the equipments used and their characteristics, the paper describes the calibration technique for the devices and how computed tomography reconstruction is done. Following the previously mentioned steps is possible to obtain the axial and radial profiles and the computed tomography reconstruction for calibration sources and for the irradiated fuel elements. The results are used to validate the gamma scanning techniques as a non-destructive examination method. The gamma scanning techniques will be used to: identify the fission products in the irradiated CANDU/TRIGA fuel elements, construct the axial and radial distributions of fission products, get the distribution in cross section through computed tomography reconstruction, and determine the nuclei number and the fission products activity of the irradiated CANDU/TRIGA fuel elements. (authors)

  19. Calculation and experimental estimation of the equation of state of irradiated fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bober, M; Breitung, W; Karow, H U; Schumacher, G [Gesellschaft fuer Kernforschung mbH, INR Kernforschungszentrum, Karlsruhe (Germany)

    1977-07-01

    The gas pressure development in an irradiated mixed oxide fuel is mainly influenced by fission gases and volatile fission products in the temperature range below the melting point and by the fuel material itself and the less volatile fission products in the temperature region above 4000 K. Besides the temperature the important factors for the vapor pressure are the oxygen potential of the fuel and the concentration of fission products in the fuel. As demonstrated previously the oxygen potential influences strongly the pressure of vapor species above (U Pu)O{sub 2}. The pressure of the species U, UO, UO{sub 2}, Pu, PuO, PuO{sub 2} varies over a range of more than five orders of magnitude by variation of the oxygen potential at 2000 K. Similar effects were observed with oxides of the fission products. Fission products dissolved in mixed oxide fuel on the other hand can influence significantly the oxygen potential of the irradiated mixed oxide. In the first paragraph of the paper an attempt is made to calculate oxygen potentials of mixed oxides containing dissolved fission products. The model used is based on the equilibrium of oxygen defects in the mixed oxide. The chemical state and distribution of fission products is a further behavior that should be considered in calculation of the local and overall pressures and behavior of the fuel. Fission products were transported during the irradiation time and collect at different positions within the fuel pin. This process can produce high local concentrations of fission products, thus enabling elements with low overall concentrations to reach their saturation pressure. The distribution of fission products and their behavior in irradiated mixed oxide fuel is described in the second paragraph. The third paragraph deals with the calculation of vapor pressures that has been conducted using a model described for uranium-plutonium mixed oxides. This model is based on the law of mass action and provides vapor pressures as a

  20. Development status of irradiation devices and instrumentation for material and nuclear fuel irradiation tests in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bong Goo; Sohn, Jae Min; Choo, Kee Nam [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2010-04-15

    The High flux Advanced Neutron Application ReactOr (HANARO), an open-tank-in-pool type reactor, is one of the multi-purpose research reactors in the world. Since the commencement of HANARO's operations in 1995, a significant number of experimental facilities have been developed and installed at HANARO, and continued efforts to develop more facilities are in progress. Owing to the stable operation of the reactor and its frequent utilization, more experimental facilities are being continuously added to satisfy various fields of study and diverse applications. The irradiation testing equipment for nuclear fuels and materials at HANARO can be classified into capsules and the Fuel Test Loop (FTL). Capsules for irradiation tests of nuclear fuels in HANARO have been developed for use under the dry conditions of the coolant and materials at HANARO and are now successfully utilized to perform irradiation tests. The FTL can be used to conduct irradiation testing of a nuclear fuel under the operating conditions of commercial nuclear power plants. During irradiation tests conducted using these capsules in HANARO, instruments such as the thermocouple, Linear Variable Differential Transformer (LVDT), small heater, Fluence Monitor (F/M) and Self-Powered Neutron Detector (SPND) are used to measure various characteristics of the nuclear fuel and irradiated material. This paper describes not only the status of HANARO and the status and perspective of irradiation devices and instrumentation for carrying out nuclear fuel and material tests in HANARO but also some results from instrumentation during irradiation tests

  1. Thermal conductivity of fresh and irradiated U-Mo fuels

    Science.gov (United States)

    Huber, Tanja K.; Breitkreutz, Harald; Burkes, Douglas E.; Casella, Amanda J.; Casella, Andrew M.; Elgeti, Stefan; Reiter, Christian; Robinson, Adam. B.; Smith, Frances. N.; Wachs, Daniel. M.; Petry, Winfried

    2018-05-01

    The thermal conductivity of fresh and irradiated U-Mo dispersion and monolithic fuel has been investigated experimentally and compared to theoretical models. During in-pile irradiation, thermal conductivity of fresh dispersion fuel at a temperature of 150 °C decreased from 59 W/m·K to 18 W/m·K at a burn-up of 4.9·1021 f/cc and further to 9 W/m·K at a burn-up of 6.1·1021 f/cc. Fresh monolithic fuel has a considerably lower thermal conductivity of 15 W/m·K at a temperature of 150 °C and consequently its decrease during in-pile irradiation is less steep than for dispersion fuel. For a burn-up of 3.5·1021 f/cc of monolithic fuel, a thermal conductivity of 11 W/m·K at a temperature of 150 °C has been measured by Burkes et al. (2015). The difference of decrease for both fuels originates from effects in the matrix that occur during irradiation, like for dispersion fuel the gradual disappearance of the Al matrix with increased burn-up and the subsequent growth of an interaction layer (IDL) between the U-Mo fuel particle and Al matrix and subsequent matrix hardening. The growth of fission gas bubbles and the decomposition of the U-Mo crystal lattice also affect both dispersion and monolithic fuel.

  2. Metallographic analysis of irradiated RERTR-3 fuel test specimens

    International Nuclear Information System (INIS)

    Meyer, M. K.; Hofman, G. L.; Strain, R. V.; Clark, C. R.; Stuart, J. R.

    2000-01-01

    The RERTR-3 irradiation test was designed to investigate the irradiation behavior of aluminum matrix U-MO alloy dispersion fuels under high-temperature, high-fission-rate conditions. Initial postirradiation examination of RERTR-3 fuel specimens has concentrated on binary U-MO atomized fuels. The rate of matrix aluminum depletion was found to be higher than predictions based on low temperature irradiation data. Wavelength Dispersive X-ray Spectroscopy (WDS) indicates that aluminum is present in the interior of the fuel particles. WDS data is supported by a mass and volume balance calculation performed on the basis of image analysis results. The depletion of matrix aluminum seems to have no detrimental effects on fuel performance under the conditions tested to date

  3. Irradiation behavior of miniature experimental uranium silicide fuel plates

    International Nuclear Information System (INIS)

    Hofman, G.L.; Neimark, L.A.; Mattas, R.F.

    1983-01-01

    Uranium silicides, because of their relatively high uranium density, were selected as candidate dispersion fuels for the higher fuel densities required in the Reduced Enrichment Research and Test Reactor (RERTR) Program. Irradiation experience with this type of fuel, however, was limited to relatively modest fission densities in the bulk from, on the order of 7 x 10 20 cm -3 , far short of the approximately 20 x 10 20 cm -3 goal established for the RERTR program. The purpose of the irradiation experiments on silicide fuels on the ORR, therefore, was to investigate the intrinsic irradiation behavior of uranium silicide as a dispersion fuel. Of particular interest was the interaction between the silicide particles and the aluminum matrix, the swelling behavior of the silicide particles, and the maximum volume fraction of silicide particles that could be contained in the aluminum matrix

  4. Irradiation testing of high-density uranium alloy dispersion fuels

    International Nuclear Information System (INIS)

    Hayes, S.L.; Trybus, C.L.; Meyer, M.K.

    1997-01-01

    Two irradiation test vehicles have been designed, fabricated, and inserted into the Advanced Test Reactor in Idaho. Irradiation of these experiments began in August 1997. These irradiation tests were designed to obtain irradiation performance information on a variety of potential new, high-density dispersion fuels. Each of the two irradiation vehicles contains 32 'microplates'. Each microplate is aluminum clad, having an aluminum matrix phase and containing one of the following compositions as the fuel phase: U-10Mo, U-8Mo, U-6Mo, U-4Mo, U-9Nb-3Zr, U-6Nb-4Zr, U-5Nb-3Zr, U-6Mo-1Pt, U-6Mo-0.6Ru, U10Mo-0.05Sn, U2Mo, or U 3 Si 2 . These experiments will be discharged at peak fuel burnups of approximately 40 and 80 at.% U 235 . Of particular interest are the extent of reaction of the fuel and matrix phases and the fission gas retention/swelling characteristics of these new fuel alloys. This paper presents the design of the irradiation vehicles and the irradiation conditions. (author)

  5. Solid Oxide Fuel Cells Operating on Alternative and Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaoxing; Quan, Wenying; Xiao, Jing; Peduzzi, Emanuela; Fujii, Mamoru; Sun, Funxia; Shalaby, Cigdem; Li, Yan; Xie, Chao; Ma, Xiaoliang; Johnson, David; Lee, Jeong; Fedkin, Mark; LaBarbera, Mark; Das, Debanjan; Thompson, David; Lvov, Serguei; Song, Chunshan

    2014-09-30

    This DOE project at the Pennsylvania State University (Penn State) initially involved Siemens Energy, Inc. to (1) develop new fuel processing approaches for using selected alternative and renewable fuels – anaerobic digester gas (ADG) and commercial diesel fuel (with 15 ppm sulfur) – in solid oxide fuel cell (SOFC) power generation systems; and (2) conduct integrated fuel processor – SOFC system tests to evaluate the performance of the fuel processors and overall systems. Siemens Energy Inc. was to provide SOFC system to Penn State for testing. The Siemens work was carried out at Siemens Energy Inc. in Pittsburgh, PA. The unexpected restructuring in Siemens organization, however, led to the elimination of the Siemens Stationary Fuel Cell Division within the company. Unfortunately, this led to the Siemens subcontract with Penn State ending on September 23rd, 2010. SOFC system was never delivered to Penn State. With the assistance of NETL project manager, the Penn State team has since developed a collaborative research with Delphi as the new subcontractor and this work involved the testing of a stack of planar solid oxide fuel cells from Delphi.

  6. Behaviour in air at 175-400 degrees C of irradiated UO2 fuel

    International Nuclear Information System (INIS)

    Hastings, I.J.; McCracken, D.

    1984-09-01

    The authors extended their study of irradiated, defected UO 2 fuel elements to 200 and 400 degrees C. At 200 degrees C there was no diametral change, but at 400 degrees C we observed swelling and severe sheath splitting. Neither short-lived fission products, nor Cs-134, Cs-137 or Ru-106 above background, were detected. Maximum Kr-85 release was 4 Bq ( -6 Ci). Discharge time was 2.5 years. UO 2 fragment studies were extended to 400 degrees C. The oxidation process for unirradiated and irradiated fuel up to 300 degrees C was characterized by activation energies of 140 +- 10 and 120 +- 10 kJ/mol, respectively; enhancement of oxidation rate was confirmed in the irradiated samples. There is an apparent reduction of activation energy above about 300 degrees C. Fuel elements with artificial and natural defects showed similar oxidation and dimensional response at 250 degrees C. Behaviour of fuel fragments from the defect area of a naturally-defected element is consistent with that for fragments from intact elements when prior oxidation during the defect period is considered

  7. Study of candu fuel elements irradiated in a nuclear power plant

    International Nuclear Information System (INIS)

    Ionescu, S.; Uta, O.; Mincu, M.; Anghel, D.; Prisecaru, I.

    2015-01-01

    The object of this work is the behaviour of CANDU fuel elements after service in nuclear power plant. The results are analysed and compared with previous result obtained on unirradiated samples and with the results obtained on samples irradiated in the TRIGA reactor of INR Pitesti. Zircaloy-4 is the material used for CANDU fuel sheath. The importance of studying its behaviour results from the fact that the mechanical properties of the CANDU fuel sheath suffer modifications during normal and abnormal operation. In the nuclear reactor, the fuel elements endure dimensional and structural changes as well as cladding oxidation, hydriding and corrosion. These changes can lead to defects and even to the loss of integrity of the cladding. This paper presents the results of examinations performed in the Post Irradiation Examination Laboratory (PIEL) of INR Pitesti on samples from fuel elements after they were removed out of the nuclear power plant: - dimensional and macrostructural characterization; - microstructural characterization by metallographic analyses; - determination of mechanical properties; - fracture surface analysis by scanning electron microscopy (SEM). A full set of non-destructive and destructive examinations concerning the integrity, dimensional changes, oxidation, hydriding and mechanical properties of the cladding was performed. The obtained results are typical for CANDU 6-type fuel. The obtained data could be used to evaluate the security, reliability and nuclear fuel performance, and for the improvement of the CANDU fuel. (authors)

  8. Ion irradiation studies of oxide ceramics

    International Nuclear Information System (INIS)

    Zinkle, S.J.

    1988-01-01

    This paper presents the initial results of an investigation of the depth-dependent microstructures of three oxide ceramics following ion implantation to moderate doses. The implantations were performed using ion species that occur as cations in the target material; for example, Mg + ions were used for MgO and MgAl 2 O 4 (spinel) irradiations. This minimized chemical effects associated with the implantation and allowed a more direct evaluation to be made of the effects of implanted ions on the microstructure. 11 refs., 14 figs

  9. Dissolution of mixed oxide fuel as a function of fabrication variables

    International Nuclear Information System (INIS)

    Lerch, R.E.

    1979-08-01

    Dissolution properties of mechanically blended mixed oxide fuel were very dependent on the six fuel fabrication variables studied. Fuel sintering temperature, source of PuO 2 and PuO 2 content of the fuel had major effects: (1) as the sintering temperature was increased from 1400 to 1700 0 C, pellet dissolution was more complete; (2) pellets made from burned metal derived PuO 2 were more completely dissolved than pellets made from calcined nitrate derived PuO 2 which in turn were more completely dissolved than pellets made from calcined nitrate derived PuO 2 ; (3) as the PuO 2 content decreased from 25 to 15 wt % PuO 2 , pellet dissolution was more complete. Preferential dissolution of uranium occurred in all the mechanically blended mixed oxide. Unirradiated mixed oxide fuel pellets made by the Sol Gel process were generally quite soluble in nitric acid. Unirradiated mixed oxide fuel pellets made by the coprecipitation process dissolved completely and rapidly in nitric acid. Fuel made by the coprecipitation process was more completely dissolved than fuel made by the Sol Gel process which, in turn, was more completely dissolved than fuel made by mechanically blending UO 2 and PuO 2 as shown below. Addition of uncomplexed fluoride to nitric acid during fuel dissolution generally rendered all fuel samples completely dissolvable. In boiling 12M nitric acid, 95 to 99% of the plutonium which was going to dissolve did so in the first hour. Irradiated mechanically blended mixed oxide fuel with known fuel fabrication conditions was also subjected to fuel dissolution tests. While irradiation was shown to increase completeness of plutonium dissolution, poor dissolubility due to adverse fabrication conditions (e.g., low sintering temperature) remained after irradiation

  10. Post-irradiation examination of Al-61 wt% U3Si fuel rods from the NRU reactor

    International Nuclear Information System (INIS)

    Sears, D.F.; Wang, N.

    1997-01-01

    This paper describes the post-irradiation examination of 4 intact low enrichment uranium (LEU) fuel rods from the national research universal (NRU) reactor at the Chalk River Laboratories of AECL. The rods were irradiated during the period 1993 through 1995, under typical driver fuel operating conditions in NRU, i.e., nominal D 2 O coolant inlet temperature 37E C, inlet pressure 654 kPa and mass flow 12.4 L/s. Irradiation exposures ranged from 147 to 251 full-power days, corresponding to 40 to 84 atom % 235 U burnup. The maximum rod power was ∼2 MW, with element linear power ratings up to 68 kW/m. Post-irradiation examinations, conducted in 1997, focused on optical metallography to measure cladding oxide thickness and fuel core and cladding microstructural examinations. The cladding oxide was approximately 24 : m thick at the mid-plane of fuel rods irradiated to 251 full-power days, with small areas up to 34 : m thick on the fins. The cladding retained significant ductility after irradiation, and its microstructure appeared unchanged. Fuel core diametral increases were small (up to 4%) and within the range previously observed on Al-61 wt% U 3 Si fuel irradiated in the NRU reactor. (author)

  11. Post-irradiation examination of A1-61 wt % U3Si fuel rods from the NRU reactor

    International Nuclear Information System (INIS)

    Sears, D.F.; Wang, N.

    1997-09-01

    This paper describes the post-irradiation examination of 4 intact low-enrichment uranium (LEU) fuel rods from the national research universal (NRU) reactor at the Chalk River Laboratories of AECL. The rods were irradiated during the period 1993 through 1995, under typical driver fuel operating conditions in NRU, i.e., nominal D 2 0 coolant inlet temperature 37 degrees C, inlet pressure 654 kPa and mass flow 12.4 L/s. Irradiation exposures ranged from 147 to 251 full-power days, corresponding to 40 to 84 atom % 235 U burnup. The maximum rod power was ∼2 MW, with element linear power ratings up to 68 kW/m. Post-irradiation examinations, conducted in 1997, focused on optical metallography to measure cladding oxide thickness and fuel core and cladding microstructural examinations. The cladding oxide was approximately 24 μm thick at the mid-plane of fuel rods irradiated to 251 full-power days, with small areas up to 34 μm thick on the fins. The cladding retained significant ductility after irradiation, and its microstructure appeared unchanged. Fuel core diametral increases were small (up to 4%) and within the range previously observed on A1-61 wt % U 3 Si fuel irradiated in the NRU reactor. (author)

  12. New JMTR irradiation test plan on fuels and materials

    International Nuclear Information System (INIS)

    Nakamura, Takehiko; Nishiyama, Yutaka; Chimi, Yasuhiro; Sasajima, Hideo; Ogiyanagi, Jin; Nakamura, Jinichi; Suzuki, Masahide; Kawamura, Hiroshi

    2009-01-01

    In order to maintain and enhance safety of light water reactors (LWRs) in long-term and up-graded operations, proper understanding of irradiation behavior of fuels and materials is essentially important. Japanese government and the Japan Atomic Energy Agency (JAEA) have decided to refurbish the Japan Materials Testing Reactor (JMTR) and to install new tests rigs, in order to play an active role for solving irradiation related issues on plant aging and high-duty uses of the current LWRs and on development of next-generation reactors. New tests on fuel integrity under simulated abnormal transients and high-duty irradiation conditions are planned in the JMTR. Power ramp tests of newdesign fuel rods will also be performed in the first stage of the program, which is expected to start in year 2011 after refurbishment of the JMTR. Combination of the JMTR tests with simulated reactivity initiated accident tests in the Nuclear Safety Research Reactor (NSRR) and loss of coolant accident tests in hot laboratories would serve as the integrated fuel safety research on the high performance fuels at extended burnups, covering from the normal to the accident conditions, including abnormal transients. For the materials irradiation, fracture toughness of reactor vessel steels and stress corrosion cracking behavior of stainless steels are being studied in addition to basic irradiation behavior of nuclear materials such as hafnium. The irradiation studies would contribute not only to solve the current problems but also to identify possible seeds of troubles and to make proactive responses. (author)

  13. Irradiation testing of high density uranium alloy dispersion fuels

    International Nuclear Information System (INIS)

    Hayes, S.L.; Trybus, C.L.; Meyer, M.K.

    1997-10-01

    Two irradiation test vehicles have been designed, fabricated, and inserted into the Advanced Test Reactor in Idaho. Irradiation of these experiments began in August 1997. These irradiation tests were designed to obtain irradiation performance information on a variety of potential new, high-density dispersion fuels. Each of the two irradiation vehicles contains 32 microplates. Each microplate is aluminum clad, having an aluminum matrix phase and containing one of the following compositions as the fuel phase: U-10Mo, U-8Mo, U-6Mo, U-4Mo, U-9Nb-3Zr, U-6Nb-4Zr, U-5Nb-3Zr, U-6Mo-1Pt, U-6Mo-0.6Ru, U-10Mo-0.05Sn, U 2 Mo, or U 3 Si 2 . These experiments will be discharged at peak fuel burnups of 40% and 80%. Of particular interest is the fission gas retention/swelling characteristics of these new fuel alloys. This paper presents the design of the irradiation vehicles and the irradiation conditions

  14. Characterization of irradiated fuel rods using pulsed eddy current techniques

    International Nuclear Information System (INIS)

    Martin, M.R.; Francis, W.C.

    1975-11-01

    A number of irradiated fuel rods and unfueled zircaloy cladding tubes (''water tubes'') were obtained from the Saxton reactor through arrangements with the Westinghouse Electric Corporation for use in subsequent irradiation effects and fuel behavior programs. A comprehensive nondestructive and corroborative destructive characterization program was undertaken on these fuel rods and tubes by ANC to provide baseline data on their characteristics prior to further testing and for comparison against post-post data. This report deals primarily with one portion of the NDT program performed remotely in the hot cells. The portion of interest in this paper is the pulsed eddy current inspection used in the nondestructive phase of the work. 6 references

  15. Heat and radiation analysis of NPP Krsko irradiated fuel

    International Nuclear Information System (INIS)

    Lalovic, M.

    1986-01-01

    Radioactive and heat potential for irradiated fuel in the region 2 with burnup of 13400 MWd/tHM, and in the region 4A with burnup of 9360 MWd/tHM for NPP KRSKO, was calculated. Computer code KORIGEN (Karlsruhe Oak Ridge Isotope Generation and Depletion Code) was used. The aspects of radiation (mainly gamma and neutrons) and of heat production was considered with respect to their impact on fuel handing and waste management. Isotopic concentrations for irradiated fuel was calculated and compared with Westinghouse data. (author)

  16. Analysis of irradiation temperature in fuel rods of OGL-1 fuel assembly

    International Nuclear Information System (INIS)

    Fukuda, Kousaku; Kobayashi, Fumiaki; Minato, Kazuo; Ikawa, Katsuichi; Iwamoto, Kazumi

    1984-10-01

    Irradiation temperature in the fuel rods of 5th OGL-1 fuel assembly was analysed by the system composed by STPDSP2 and TRUMP codes. As the measured input-data, following parameters were allowed for; circumferential heating distribution around the fuel rod, which was measured in the JMTR critical assembly, axial heating distribution through the fuel rod, ratio of peak heatings of three fuel rods, and pre- and post-irradiation outer radii of the fuel compacts and inner radii of the graphite sleeves, which had been measured in PIE of the 5th OGL-1 fuel assembly. In computation the axial distributions of helium coolant temperature through the fuel rod and the heating value of each fuel rod were, firstly, calculated as input data for TRUMP. The TRUMP calculation yielded the temperatures which were fitted in those measured by all of the thermo-couples installed in the fuel rods, by adjusting only the value of the surface heat transfer coefficient, and consequently, the temperatures in all portions of the fuel rod were obtained. The apparent heat transfer coefficient changed to 60% of the initial values in the middle period of irradiation. For this reduction it was deduced that shoot had covered the surface of the fuel rod during irradiation, which was confirmed in PIE. Beside it, several things were found in this analysis. (author)

  17. Evaluation of microstructure of irradiated fuel channel components of PHWR

    International Nuclear Information System (INIS)

    Ramadasan, E.

    2005-01-01

    Performance evaluation and failure analysis of irradiated reactor structural components such as those in-core and PHT circuit components necessitate metallographic evaluation using special metallographic specimen preparation techniques due to the radiation dose and contamination levels involved in handling the specimens. The metallographic specimen preparation techniques that are resorted to involve use of fully automatic and semi automatic machines, shielded metallographic microscope and specialised equipment developed for lead-cell metallography. The techniques used and the results obtained in the metallographic studies on irradiated fuel channel components such as pressure tubes and garter springs of various Indian PHWRs at RAPS, NAPS and MAPS are presented as case studies in the paper. The evaluation of oxidation and hydriding behaviour of zircaloy-2 pressure tubes and garter springs are presented. The paper also gives in detail the microstructural evaluation of hydride blistering seen at the PT-CT contact location of the pressure tubes of RAPS-2. The evaluation revealed that the hydride blisters was small compared to their length, unlike the hydride blisters seen in the CANDU pressure tube G-16 of Pickering-2. This could be attributed to be due to the difference in the annulus conditions between the two types of reactors. The hydride blisters in J-07 pressure tube of RAPS-2 had ductile material adjacent to them. The paper also gives the hydride blistering observation on irradiated Zr-2.5% Nb-0.5% Cu garter springs of RAPS-2. It was seen that there was only negligible hydriding of the garter springs during service through they showed presence of benign hydride blisters in them. The general hydriding observations made on the pressure tubes of Indian PHWRs under different conditions are also presented. (author)

  18. Irradiation testing of coated particle fuel at Hanaro

    International Nuclear Information System (INIS)

    Goo Kim, Bong; Sung Cho, Moo; Kim, Yong Wan

    2014-01-01

    TRISO-coated particle fuel is developing to support development of VHTR in Korea. From August 2013, the first irradiation testing of coated particle fuel was begun to demonstrate and qualify TRISO fuel for use in VHTR in the HANARO at KAERI. This experiment is currently undergoing under the atmosphere of a mixed inert gas without on-line temperature monitoring and control combined with on-line fission product monitoring of the sweep gas. The irradiation device contains two test rods, one contains nine fuel compacts and the other five compacts and eight graphite specimens. Each compact has 263 coated particles. After a peak burn-up of about 4 at% and a peak fast neutron fluence of about 1.7 x 10 21 n/cm 2 , PIE will be carried out at KAERI's Irradiated Material Examination Facility. This paper is described characteristics of coated particle fuel, the design of test rod and irradiation device for coated particle fuel, discusses the technical results for irradiation testing at HANARO. (authors)

  19. Out-pile Test of Double Cladding Fuel Rod Mockups for a Nuclear Fuel Irradiation Test

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, Jaemin; Park, Sungjae; Kang, Younghwan; Kim, Harkrho; Kim, Bonggoo; Kim, Youngki [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2008-05-15

    An instrumented capsule for a nuclear fuel irradiation test has been developed to measure fuel characteristics, such as a fuel temperature, internal pressure of a fuel rod, a fuel pellet elongation and a neutron flux during an irradiation test at HANARO. In the future, nuclear fuel irradiation tests under a high temperature condition are expected from users. To prepare for this request, we have continued developing the technology for a high temperature nuclear fuel irradiation test at HANARO. The purpose of this paper is to verify the possibility that the temperature of a nuclear fuel can be controlled at a high temperature during an irradiation test. Therefore we designed and fabricated double cladding fuel rod mockups. And we performed out-pile tests using these mockups. The purposes of a out-pile test is to analyze an effect of a gap size, which is between an outer cladding and an inner cladding, on the temperature and the effect of a mixture ratio of helium gas and neon gas on the temperature. This paper presents the design and fabrication of double cladding fuel rod mockups and the results of the out-pile test.

  20. Application of FE-SEM with elemental analyzer for irradiated fuel materials

    International Nuclear Information System (INIS)

    Sasaki, Shinji; Maeda, Koji; Yamada, A.

    2012-01-01

    It is important to study the irradiation behavior of the uranium-plutonium mixed oxide fuels (MOX fuels) for development of fast reactor fuels. During irradiation in a fast reactor, the changes of microstructures and the changes of element distributions along radial direction occur in the MOX fuels because of a radial temperature gradient. In order to make detailed observations of microstructure and elemental analyses of fuel samples, a field emission scanning electron microscope (FE-SEM) equipped with a wavelength-dispersive X-ray spectrometer (WDX) and an energy-dispersive X-ray spectrometer (EDX) were installed in a hot laboratory. Because fuel samples have high radioactivities and emit α-particles, the instrument was modified correspondingly. The notable modified points were as follows. 1) To prevent leakage of radioactive materials, the instrument was attached to a remote control air-tight sample transfer unit between a shielded hot cell and the FE-SEM. 2) To protect operators and the instruments from radiation, the FE-SEM was installed in a lead shield box and the control unit was separately located outside the box. After the installation, the microscopy and elemental analyses were made on low burnup fuel samples. High resolution images were obtained on the fuel sample surface. The characteristic X-rays (U, Pu) emitted from the fuel sample surface measured along radial direction successfully. Thereby, it was able to grasp the change of U, Pu radial distribution after irradiation. The technique has the great advantage of being able to evaluate the changes of microstructures and the changes of element distributions of MOX fuels due to irradiation. In future work, samples of even higher radioactivity will be observed and analyzed. (author)

  1. Physical properties of beryllium oxide - Irradiation effects

    International Nuclear Information System (INIS)

    Elston, J.; Caillat, R.

    1958-01-01

    This work has been carried out in view of determining several physical properties of hot-pressed beryllium oxide under various conditions and the change of these properties after irradiation. Special attention has been paid on to the measurement of the thermal conductivity coefficient and thermal diffusivity coefficient. Several designs for the measurement of the thermal conductivity coefficient have been achieved. They permit its determination between 50 and 300 deg. C, between 400 and 800 deg. C. Some measurements have been made above 1000 deg. C. In order to measure the thermal diffusivity coefficient, we heat a perfectly flat surface of a sample in such a way that the heat flux is modulated (amplitude and frequency being adjustable). The thermal diffusivity coefficient is deduced from the variations of temperature observed on several spots. Tensile strength; compressive strength; expansion coefficient; sound velocity and crystal parameters have been also measured. Some of the measurements have been carried out after neutron irradiation. Some data have been obtained on the change of the properties of beryllium oxide depending on the integrated neutron flux. (author) [fr

  2. Irradiation testing of miniature fuel plates for the RERTR program

    Energy Technology Data Exchange (ETDEWEB)

    Senn, R L; Martin, M M [Oak Ridge National Laboratory, Oak Ridge, TN 37830 (United States)

    1983-08-01

    An irradiation test facility, which provides a test bed for irradiating a variety of miniature fuel plates miniplates) for the Reduced Enrichment Research and Test Reactors (RERTR) program, has been placed into operation. The objective of these tests is to screen various candidate fuel materials as to their suitability for replacing the highly enriched uranium fuel materials currently used by the world's test and research reactors with a lower enrichment fuel material, without significantly degrading reactor operating characteristics and power levels. The use of low uranium enrichment of about 20% {sup 235}U in place of highly enriched fuel for these reactors would reduce the potential for {sup 235}U diversion. Fuel materials currently being evaluated in this first phase of these screening tests include aluminum-base dispersion-type fuel plates with fuel cores of 1) high uranium content U{sup 3}){sup 8}-Al being developed by ORNL, 2) high uranium content UAI{sub x}-Al being developed by EG and G Idaho, Inc., and 3) very high uranium content U{sub 3}Si-Al- being developed by ANL. The miniplates are 115-mm long by 50-mm wide with overall plate thicknesses of 1.27 or 1.52 mm. The fuel core dimensions vary according to overall plate thicknesses with a minimal clad thickness requirement of 0.20 mm. Sixty such miniplates (thirty of each thickness) can be irradiated in one test facility. The irradiation test facility, designated as HFED-1 is operating in core position E-7 in the Oak Ridge Research Reactor (ORR), a 30-MW water-moderated reactor. The peak neutron flux measured for this experiment is 1.96 x 10{sup 18} neutrons m{sub -2} s{sub -1}. The various types of miniplates will achieve burnups of up to approximately 2.2x10{sup 27} fissions/m{sup 3} of fuel, which will require approximately eight full power months of irradiation. During reactor shutdown periods, the experiment is removed from the reactor, moved to a special poolside station, disassembled, and inspected

  3. New trends in nuclear fuel experimental irradiation. Modern control and acquisition of the irradiation data

    International Nuclear Information System (INIS)

    Preda, M.; Ciocanescu, M.; Ana, E.M.

    2010-01-01

    With the irradiation devices used in the irradiation tests, the following experiments have been performed in TRIGA-SCN reactor: a) In capsule-type irradiation devices: - fission gases composition determination; - dimensional measurements; - fission gases pressure measurement; - power pre-ramp and ramp; - power cycling; - structural materials testing. b) In loop-type irradiation device: - power ramp; - multiple power ramps; - overpower. Aiming to develop irradiation tests for advanced nuclear fuel elements, it is mandatory to increase the maximum neutron flux in the core with about 20%. This will lead to reactor power increase up to 21 MW. This objective can be reached through: - increasing the number of fuel clusters in the reactor core; - using the 6x6 fuel cluster to replace the present 5x5 clusters; - relocation of the control rods. In this context, the new control system and the data acquisition system operates online and allows real-time data evaluation. (author)

  4. Cost of transporting irradiated fuels and maintenance costs of a chemical treatment plant for irradiated fuels

    International Nuclear Information System (INIS)

    Sousselier, Y.

    1964-01-01

    Numerous studies have been made of the cost of a fuel cycle, but many of them are based on a priori studies and are therefore to be treated with reserve. Thus, in the part dealing with the treatment of irradiated fuels, some important factors in the cost have only rarely been given on the basis of practical experience: the cost of transporting the fuels themselves and the plant maintenance costs. Investigations relating to transport costs are generally based on calculations made from somewhat arbitrary data. The studies carried out in France on the transport of irradiated uranium between the EDF reactors at Chinon and the retreatment plant at La Hague of the irradiated uranium from research reactors to foreign retreatment plants, are reported; they show that by a suitable choice of transport containers and details of expedition it has been possible to reduce the costs very considerably. This has been achieved either by combining rail and road transport or by increasing the writ capacities of the transport containers: an example is given of a container for swimming-pool pile elements which can transport a complete pile core at one time, thus substantially reducing the cost. Studies concerning the maintenance costs of retreatment plants are rarer still, although in direct maintenance plants these figures represent an appreciable fraction of the total treatment cost. An attempt has been made, on the basis of operational experience of a plant, to obtain some idea of these costs. Only maintenance proper has been considered, excluding subsidiary operations such as the final decontamination of apparatus, the burial of contaminated material and radioprotection operations Maintenance has been divided into three sections: mechanical maintenance, maintenance of electrical equipment and maintenance of control and adjustment apparatus. In each of these sections the distinction has been made between manpower and the material side. In order to allow comparisons to be made with

  5. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Neimark, L.A.; Poeppel, R.B.; Hofman, G.L.

    1985-01-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release. 29 refs., 12 figs

  6. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Hofman, G.L.; Neimark, L.A.; Poeppel, R.B.

    1983-11-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release

  7. The TMI Regenerative Solid Oxide Fuel Cell

    Science.gov (United States)

    Cable, Thomas L.; Ruhl, Robert C.; Petrik, Michael

    1996-01-01

    Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. Systems generally consist of photovoltaic solar arrays which operate (during sunlight cycles) to provide system power and regenerate fuel (hydrogen) via water electrolysis and (during dark cycles) fuel cells convert hydrogen into electricity. Common configurations use two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Reliability, power to weight and power to volume ratios could be greatly improved if both power production (fuel cells) and power storage (electrolysis) functions can be integrated into a single unit. The solid oxide fuel cell (SOFC) based design integrates fuel cell and electrolyzer functions and potentially simplifies system requirements. The integrated fuel cell/electrolyzer design also utilizes innovative gas storage concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H20 electrode (SOFC anode/electrolyzer cathode) materials for regenerative fuel cells. Tests have shown improved cell performance in both fuel and electrolysis modes in reversible fuel cell tests. Regenerative fuel cell efficiencies, ratio of power out (fuel cell mode) to power in (electrolyzer mode), improved from 50 percent using conventional electrode materials to over 80 percent. The new materials will allow a single SOFC system to operate as both the electolyzer and fuel cell. Preliminary system designs have also been developed to show the technical feasibility of using the design for space applications requiring high energy storage efficiencies and high specific energy. Small space systems also have potential for dual-use, terrestrial applications.

  8. Behaviour of rock-like oxide fuels under reactivity-initiated accident conditions

    International Nuclear Information System (INIS)

    Kazuyuki, Kusagaya; Takehiko, Nakamura; Makio, Yoshinaga; Hiroshi, Akie; Toshiyuki, Yamashita; Hiroshi, Uetsuka

    2002-01-01

    Pulse irradiation tests of three types of un-irradiated rock-like oxide (ROX) fuel - yttria-stabilised zirconia (YSZ) single phase, YSZ and spinel (MgAl 2 O 4 ) homogeneous mixture and particle-dispersed YSZ/spinel - were conducted in the Nuclear Safety Research Reactor to investigate the fuel behaviour under reactivity-initiated accident conditions. The ROX fuels failed at fuel volumetric enthalpies above 10 GJ/m 3 , which was comparable to that of un-irradiated UO 2 fuel. The failure mode of the ROX fuels, however, was quite different from that of the UO 2 fuel. The ROX fuels failed with fuel pellet melting and a part of the molten fuel was released out to the surrounding coolant water. In spite of the release, no significant mechanical energy generation due to fuel/coolant thermal interaction was observed in the tested enthalpy range below∼12 GJ/m 3 . The YSZ type and homogenous YSZ/spinel type ROX fuels failed by cladding burst when their temperatures peaked, while the particle-dispersed YSZ/spinel type ROX fuel seemed to have failed by cladding local melting. (author)

  9. Irradiation-induced dimensional changes of fuel compacts and graphite sleeves of OGL-1 fuel assemblies

    International Nuclear Information System (INIS)

    Hayashi, Kimio; Minato, Kazuo; Kobayashi, Fumiaki; Tobita, Tsutomu; Kikuchi, Teruo; Kurobane, Shiro; Adachi, Mamoru; Fukuda, Kousaku

    1988-06-01

    Experimental data are summarized on irradiation-induced dimensional changes of fuel compacts and graphite sleeves of the first to ninth OGL-1 fuel assemblies. The range of fast-neutron fluence is up to 4 x 10 24 n/m 2 (E > 0.18 MeV); and that of irradiation temperature is 900 - 1400 deg C for fuel compacts and 800 - 1050 deg C for graphite sleeves. The dimensional change of the fuel compacts was shrinkage under these test conditions, and the shrinkage fraction increased almost linearly with fast-neutron fluence. The shrinkage fraction of the fuel compacts was larger by 20 % in the axial direction than in the radial direction. Influence of the irradiation temperature on the dimensional-change behavior of the fuel compacts was not observed clearly; presumably the influence was hidden by scatter of the data because of low level of the fast-neutron fluence and the resultant small dimensional changes. (author)

  10. Irradiation behavior of experimental miniature uranium silicide fuel plates

    International Nuclear Information System (INIS)

    Hofman, Gerard L.; Neimark, L.A.; Mattas, R.F.

    1983-01-01

    Uranium silicides, because of their relatively high uranium density, were selected as candidate dispersion fuels for the higher fuel densities required in the Reduced Enrichment Research and Test Reactor (RERTR) Program. Irradiation experience with this type of fuel, however, was limited to relatively modest fission densities in the bulk form, on the order of 7 x 10 20 cm -3 , far short of he approximately 20 x 10 20 cm -3 goal established for the RERTR Program. The purpose of the irradiation experiments on silicide fuels in the ORR, therefore, was to investigate the intrinsic irradiation behavior of uranium silicide as a dispersion fuel. Of particular interest was the interaction between the silicide particles and the aluminum matrix, the swelling behavior of the silicide particles, and the maximum volume fraction of silicide particles that could be contained in the aluminum matrix. The first group of experimental 'mini' fuel plates have recently reached the program's goal burnup and are in various stages of examination. Although the results to date indicate some limitations, it appears that within the range of parameters examined thus far the uranium silicide dispersion holds promise for satisfying most of the needs of the RERTR Program. The twelve experimental silicide dispersion fuel plates that were irradiated to approximately their goal exposure show the 30-vol % U 3 Si-Al plates to be in a stage of relatively rapid fission-gas-driven swelling at a fission density of 2 x 10 20 cm -3 . This fuel swelling will likely result in unacceptably large plate-thickness increases. The U 3 Si plates appear to be superior in this respect; however, they, too, are starting to move into the rapid fuel-swelling stage. Analysis of the currently available post irradiation data indicates that a 40-vol % dispersed fuel may offer an acceptable margin to the onset of unstable thickness changes at exposures of 2 x 10 21 fission/cm 3 . The interdiffusion between fuel and matrix

  11. Mathematical modeling of solid oxide fuel cells

    Science.gov (United States)

    Lu, Cheng-Yi; Maloney, Thomas M.

    1988-01-01

    Development of predictive techniques, with regard to cell behavior, under various operating conditions is needed to improve cell performance, increase energy density, reduce manufacturing cost, and to broaden utilization of various fuels. Such technology would be especially beneficial for the solid oxide fuel cells (SOFC) at it early demonstration stage. The development of computer models to calculate the temperature, CD, reactant distributions in the tubular and monolithic SOFCs. Results indicate that problems of nonuniform heat generation and fuel gas depletion in the tubular cell module, and of size limitions in the monolithic (MOD 0) design may be encountered during FC operation.

  12. Critical experiments with mixed oxide fuel

    International Nuclear Information System (INIS)

    Harris, D.R.

    1997-01-01

    This paper very briefly outlines technical considerations in performing critical experiments on weapons-grade plutonium mixed oxide fuel assemblies. The experiments proposed would use weapons-grade plutonium and Er 2 O 3 at various dissolved boron levels, and for specific fuel assemblies such as the ABBCE fuel assembly with five large water holes. Technical considerations described include the core, the measurements, safety, security, radiological matters, and licensing. It is concluded that the experiments are feasible at the Rensselaer Polytechnic Institute Reactor Critical Facility. 9 refs

  13. Reduction of Graphene Oxide to Graphene by Using Gamma Irradiation

    International Nuclear Information System (INIS)

    Shamellia Sharin; Irman Abdul Rahman; Ainee Fatimah Ahmad

    2015-01-01

    This research aims to gauge the ability of gamma radiation to induce the reduction of graphene oxide to graphene. Graphene oxide powders were dispersed into a mixture of alcohol and deionized water, and the mixture was then irradiated with a "6"0Co source using a GammaCell 220 Excel irradiator at absorbed doses of 0, 5, 15, 20 and 35 kGy. According to characterization using Fourier Transformed Infrared Spectroscopy (FTIR), it can be seen that almost every oxygen-containing functional group has been removed after irradiation of the graphene oxide mixture. Reduction of graphene oxide was also proven from the characterization using UV-Vis Spectroscopy, in which the wavelength of graphene oxide at 237 nm was red-shifted to 277 nm after being irradiated and the peak at 292 nm, (indicating the carboxyl group) disappears in the UV-Vis spectrum of reduced graphene oxide. Morphology of graphene oxide also changed from a smooth and flat surface to crumpled. The ratio of carbon/ oxygen in the graphene oxide was lower than the carbon/ oxygen of reduced graphene oxide. At the end of the experiment, it can be deduced that graphene oxide underwent reduction, characterized before and after irradiation using Emission Scanned Electron Microscopy and Energy Dispersive X-ray, Fourier Transformed Infrared Spectroscopy and UV-Vis Spectroscopy. Therefore, we postulate that the irradiation technique that induces reduction, can be used to obtain reduced graphene oxide from graphene oxide. (author)

  14. Examination of the creep behaviour of ceramic fuel elements under neutron irradiation

    International Nuclear Information System (INIS)

    Brucklacher, D.

    1978-01-01

    This paper examines the creeping of UO 2 , UO 2 -PuO 2 and UN under neutron irradiation. It starts with the experimental results about the relation between the thermal creep rate and the load, the temperature, as well as characteristic material values, stoichiometry, grain size and porosity. These correlation are first qualitatively discussed and then compared with the statements of actual quantitative equations. From the models and theories on which these equations are based a modified Nabarro-Heering-equation results for the correlation between the creep rate of ceramic fuels, stress, temperature and the fission rate. In the experimental part of the examination, length-changes of creep samples of UO 2 , (U,Pu)O 2 and UN were measured in specially developed irradiation creep casings in different reactors. The measuring data were corrected and evaluated considering the thermal expansion effects, irregular temperature distribution and swelling effects in such a way that the dependences of the creep rate of UO 2 , UO 2 -PuO 2 and UN under irradiation on stress, temperature, fission rate, burn-up and porosity is obtained. It shows that creeping of fuels under irradiation at high temperatures is equivalent to thermally activated creeping, while at low temperature the creep rate induced by irradiation is much higher than the condition without irradiation. The increment of oxidic nuclear fuels is greater than in UN, the stress dependence on low burn-up is proportional in both cases, and the influence of temperature is quite small. (orig.) [de

  15. Design, Manufacturing and Irradiation Behaviour of Fast Reactor Fuel. Proceedings of a Technical Meeting

    International Nuclear Information System (INIS)

    2013-04-01

    Fast reactors are vital for ensuring the sustainability of nuclear energy in the long term. They offer vastly more efficient use of uranium resources and the ability to burn actinides, which are otherwise the long-lived component of high level nuclear waste. These reactors require development, qualification, testing and deployment of improved and innovative nuclear fuel and structural materials having very high radiation resistance, corrosion/erosion and other key operational properties. Several IAEA Member States have made efforts to advance the design and manufacture of technologies of fast reactor fuels, as well as to investigate their irradiation behaviour. Due to the acute shortage of fast neutron testing and post-irradiation examination facilities and the insufficient understanding of high dose radiation effects, there is a need for international exchange of knowledge and experience, generation of currently missing basic data, identification of relevant mechanisms of materials degradation and development of appropriate models. Considering the important role of nuclear fuels in fast reactor operation, the IAEA Technical Working Group on Fuel Performance and Technology (TWGFPT) proposed a Technical Meeting (TM) on 'Design, Manufacturing and Irradiation Behaviour of Fast Reactors Fuels', which was hosted by the Institute of Physics and Power Engineering (IPPE) in Obninsk, Russian Federation, from 30 May to 3 June 2011. The TM included a technical visit to the fuel production plant MSZ in Elektrostal. The purpose of the meeting was to provide a forum to share knowledge, practical experience and information on the improvement and innovation of fuels for fast reactors through scientific presentations and brainstorming discussions. The meeting brought together 34 specialists from national nuclear agencies, R and D and design institutes, fuel vendors and utilities from 10 countries. The presentations were structured into four sections: R and D Programmes on FR Fuel

  16. MOX fuel irradiation behaviour: Results from X-ray microbeam analysis

    International Nuclear Information System (INIS)

    Walker, C.T.; Goll, W.; Matsumura, T.

    1997-01-01

    The behaviour of plutonium, xenon and caesium were investigated in two sections of irradiated MOX fuel produced by the OCOM process. In one fuel (OCOM30), the MOX agglomerates contained 18 wt% fissile plutonium, and had a low volume fraction of 0.17; in the other (OCOM15) the agglomerates contained 9 wt% fissile plutonium, and had a high volume fraction of 0.34. Both fuels had been irradiated under normal power reactor conditions to a burn-up of approximately 44 GWd/t. The main aim of the work was to establish whether the above differences in composition affected the percentage fission gas released by the fuels. Since U/Pu interdiffusion did not occurred during the irradiation, both fuels remained inhomogeneous on the microscopic scale. However, the concentration of plutonium in the MOX agglomerates decreases by about 50% as a result of fission, whereas the plutonium content of the UO 2 matrix increased by about a factor of four to approximately 2 wt% due to neutron capture by 238 U. The agglomerates in the OCOM15 fuel generally exhibited a finer structure due to the lower burn-up. More than 80% of the fission gas had been released from the oxide lattice of the MOX agglomerates in both fuels. However, a very high fraction of this gas precipitated and remained in the pore structure of the agglomerates. Consequently, puncturing revealed that for both fuels the percentage of gas released to the rod free volume increased from less than 0.5% at 10 GWd/t to a maximum of 3.5% at 45 GWd/t. The conclusion is that the percentage of gas released by MOX fuel is largely unaffected of the level of inhomogeneity of the fuel. In both fuels caesium showed near complete retention in both the MOX agglomerates and the UO 2 matrix. (author). 8 refs, 11 figs, 3 tabs

  17. Study of Irradiation Effect onto Uranium silicide Fuel

    International Nuclear Information System (INIS)

    Suparjo

    1998-01-01

    The irradiation effect onto the U 3 Si-Al and U 3 Si 2 -Al dispersion type of fuel element has been studied. The fuel material performs swelling during irradiation due to boehmite (Al 2 O 3 (H 2 O)) formation in which might occurs inside the meat and on the cladding surface, the interaction between the fuel and aluminium matrix that produce U(Al,Si) 3 phase, and the formation of fission gas bubble inside the fuel. At a constant fission density, the U 3 Si-Al fuel swelling is higher than that of U 3 Si 2 -Al fuel. The swellings of both fuels increase with the increasing of fission density. The difference of swelling behavior was caused by formation of large bubble gases generated from fission product of U 3 Si fuel and distributed non-uniformly over all of fuel zone. On the other hand, the U 3 Si 2 fission produced small bubble gases, and those were uniformly distributed. The growth rate of fission gas bubble in the U 3 Si fuel has shown high diffusivity, transformation into amorph material and thus decrease its mechanical strength

  18. The investigation of fast reactor fuel pin start up behaviour in the irradiation experiment DUELL II

    International Nuclear Information System (INIS)

    Freund, D.; Geithoff, D.

    1988-04-01

    The irradiation experiments DUELL-II within the SNR-300 operational Transient Experimental Program deal with the investigation of fresh mixed oxide fuel behaviour at start-up. The irradiation has been carried out in the HFR Petten in four so-called DUELL capsules with two fuel pin samples each. The fuel pins with a total length of 453 mm contained a fuel column of 150 mm length, consisting of high dense (U,Pu)O 2-x fuel with an initial porosity of 4%, a Pu-content of 20.9%, and an O/Me ratio of 1.96. The fuel pellet diameter was 6.37 mm, the outer diameter of the SS cladding, material No. 1.4970, was 7.6 mm. The irradiation included four phases, consisting of preconditioning at 85% nominal power (corresponds to 550 W/cm), a following increase to full power, and two following full power periods of 1 and 10 days, respectively. Post irradiation examination showed incomplete fuel restructuring in the first capsules with central void diameters of 800 μm in the hot plane, complete restructuring in the last capsule, leading to central voids of approximately 1 mm diameter. The residual gaps between fuel and clad varied between 25 and 44 μm. The clad inner surface did not show any corrosion attack. The analysis of fuel restructuring has been carried out with the computer code SATURN-S showing good agreement with the PIE results. The analysis led to a series of model improvements, especially for crack volume and relocation modelling. (orig./GL) [de

  19. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Chick, L.A. [Pacific Northwest Lab., Richland, WA (United States)

    1996-04-01

    Interconnection materials in a solid oxide fuel cell are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. The thermal expansion characteristics of substituted lanthanum and yttrium chromite interconnect materials were evaluated by dilatometry as a function of oxygen partial pressures from 1 atm to 10{sup -18} atm, controlled using a carbon dioxide/hydrogen buffer.

  20. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1993-03-01

    This circular has been prepared to provide information on the shipment of irradiated reactor fuel (spent fuel) subject to regulation by the Nuclear Regulatory Commission (NRC), and to meet the requirements of Public Law 96--295. The report provides a brief description of NRC authority for certain aspects of transporting spent fuel. It provides descriptive statistics on spent fuel shipments regulated by the NRC from 1979 to 1992. It also lists detailed highway and railway segments used within each state from October 1, 1987 through December 31, 1992

  1. Segmented fuel irradiation program: investigation on advanced materials

    International Nuclear Information System (INIS)

    Uchida, H.; Goto, K.; Sabate, R.; Abeta, S.; Baba, T.; Matias, E. de; Alonso, J.

    1999-01-01

    The Segmented Fuel Irradiation Program, started in 1991, is a collaboration between the Japanese organisations Nuclear Power Engineering Corporation (NUPEC), the Kansai Electric Power Co., Inc. (KEPCO) representing other Japanese utilities, and Mitsubishi Heavy Industries, Ltd. (MHI); and the Spanish Organisations Empresa Nacional de Electricidad, S.A. (ENDESA) representing A.N. Vandellos 2, and Empresa Nacional Uranio, S.A. (ENUSA); with the collaboration of Westinghouse. The objective of the Program is to make substantial contribution to the development of advanced cladding and fuel materials for better performance at high burn-up and under operational power transients. For this Program, segmented fuel rods were selected as the most appropriate vehicle to accomplish the aforementioned objective. Thus, a large number of fuel and cladding combinations are provided while minimising the total amount of new material, at the same time, facilitating an eventual irradiation extension in a test reactor. The Program consists of three major phases: phase I: design, licensing, fabrication and characterisation of the assemblies carrying the segmented rods (1991 - 1994); phase II: base irradiation of the assemblies at Vandellos 2 NPP, and on-site examination at the end of four cycles (1994-1999). Phase III: ramp testing at the Studsvik facilities and hot cell PIE (1996-2001). The main fuel design features whose effects on fuel behaviour are being analysed are: alloy composition (MDA and ZIRLO vs. Zircaloy-4); tubing texture; pellet grain size. The Program is progressing satisfactorily as planned. The base irradiation is completed in the first quarter of 1999, and so far, tests and inspections already carried out are providing useful information on the behaviour of the new materials. Also, the Program is delivering a well characterized fuel material, irradiated in a commercial reactor, which can be further used in other fuel behaviour experiments. The paper presents the main

  2. HT oxidation activity of soil irradiated with gamma radiation

    International Nuclear Information System (INIS)

    Momoshima, Noriyuki; Tjahaja, P.I.; Takashima, Yoshimasa

    1992-01-01

    The HT oxidation activity was examined for soils irradiated with 60 Co γ-rays at various doses. The HT oxidation rate decreased with increase of initial H 2 concentration, indicating a similar oxidation mechanism between HT and H 2 . Irradiated soils showed decrease of oxidation activity with dose suggests that HT and H 2 oxidation activities were affected by sterilization with γ-rays. The decline of the oxidation activity with dose was analyzed by a composite of two components with different radiosensitivity and they were considered to be activities of soil microorganisms and abiotic soil enzymes. The oxidation activity due to soil microorganisms would be important at low dose range and more radioresistant abiotic soil enzymes would be responsible for the oxidation activity observed at more than several kGy. In non-irradiated soil about half of the oxidation activity was considered resulting from abiotic soil enzymes. (author)

  3. Evaluation model for PWR irradiated fuel

    International Nuclear Information System (INIS)

    Gomes, I.C.

    1983-01-01

    The individual economic value of the plutonium isotopes for the recycle of the PWR reactor is investigated, assuming the existence of an market for this element. Two distinct market situations for the stages of the fuel cycle are analysed: one for the 1972 costs and the other for costs of 1982. Comparisons are made for each of the two market situations concerning enrichment of the U-235 in the uranium fuel that gives the minimum cost in the fuel cycle. The method adopted to establish the individual value of the plutonium isotopes consists on the economical analyses of the plutonium fuel cycle for four different isotopes mixtures refering to the uranium fuel cycle. (Author) [pt

  4. A technique of melting temperature measurement and its application for irradiated high-burnup MOX fuels

    International Nuclear Information System (INIS)

    Namekawa, Takashi; Hirosawa, Takashi

    1999-01-01

    A melting temperature measurement technique for irradiated oxide fuels is described. In this technique, the melting temperature was determined from a thermal arrest on a heating curve of the specimen which was enclosed in a tungsten capsule to maintain constant chemical composition of the specimen during measurement. The measurement apparatus was installed in an alpha-tight steel box within a gamma-shielding cell and operated by remote handling. The temperature of the specimen was measured with a two-color pyrometer sighted on a black-body well at the bottom of the tungsten capsule. The diameter of the black-body well was optimized so that the uncertainties of measurement were reduced. To calibrate the measured temperature, two reference melting temperature materials, tantalum and molybdenum, were encapsulated and run before and after every oxide fuel test. The melting temperature data on fast reactor mixed oxide fuels irradiated up to 124 GWd/t were obtained. In addition, simulated high-burnup mixed oxide fuel up to 250 GWd/t by adding non-radioactive soluble fission products was examined. These data shows that the melting temperature decrease with increasing burnup and saturated at high burnup region. (author)

  5. Stability under irradiation of a fine dispersion of oxides in a ferritic matrix

    International Nuclear Information System (INIS)

    Monnet, I.

    1999-01-01

    Oxide dispersion strengthened (ODS) ferritic-martensitic steels are being considered for high temperature, high fluence nuclear applications, like fuel pin cladding in Fast Breeder Reactors. ODS alloys offer improved out of pile strength characteristics at temperature above 550 deg.C and ferritic-martensitic matrix is highly swelling resistant. A clad in an ODS ferritic steel, call DY (Fe-13Cr-1,5Mo+TiO 2 +Y 2 O 3 ) has been irradiated in the experimental reactor Phenix. Under irradiation oxide dissolution occurs. Microstructural observations indicated that oxide evolution is correlated with the dose and consist in four phenomena: the interfaces of oxide particles with the matrix become irregular, the uniform distribution of the finest oxide ( 2 O 3 , Y 2 O 3 , MgO or MgAl 2 O 4 . These materials were irradiated with charged particles in order to gain a better understanding of the mechanisms of dissolution. Irradiation with 1 MeV Helium does not induce any modification, neither in the chemical modification of the particles nor in their spatial and size distribution. Since most of the energy of helium ions is lost by inelastic interaction, this result proves that this kind of interaction does not induce oxide dissolution. Irradiation with 1 MeV or 1.2 MeV electrons leads to a significant dissolution with a radius decrease proportional to the dose. These experiments prove that oxide dissolution can be induced by Frenkel pairs alone, provided that metallic atoms are displaced. The comparison between irradiation with ions (displacements cascades) and electrons (Frenkel pairs only) shows the importance of free point defects in the dissolution phenomena. For all the irradiations (ions or electrons) the spinel MgAl 2 O 4 seems more resistant than Y 2 O 3 to dissolution, and MgO and Al 2 O 3 are even less resistant. This is the order of stability under irradiation of bulk oxides. (author)

  6. Gas-Cooled Reactor Programs annual progress report for period ending December 31, 1973. [HTGR fuel reprocessing, fuel fabrication, fuel irradiation, core materials, and fission product distribution; GCFR fuel irradiation and steam generator modeling

    Energy Technology Data Exchange (ETDEWEB)

    Kasten, P.R.; Coobs, J.H.; Lotts, A.L.

    1976-04-01

    Progress is summarized in studies relating to HTGR fuel reprocessing, refabrication, and recycle; HTGR fuel materials development and performance testing; HTGR PCRV development; HTGR materials investigations; HTGR fuel chemistry; HTGR safety studies; and GCFR irradiation experiments and steam generator modeling.

  7. Pilot-scale equipment development for pyrochemical treatment of spent oxide fuel

    International Nuclear Information System (INIS)

    Herrmann, S. D.

    1999-01-01

    Fundamental objectives regarding spent nuclear fuel treatment technologies include, first, the effective distribution of spent fuel constituents among product and stable waste forms and, second, the minimization and standardization of waste form types and volumes. Argonne National Laboratory (ANL) has developed and is presently demonstrating the electrometallurgical treatment of sodium-bonded metal fuel from Experimental Breeder Reactor II, resulting in an uranium product and two stable waste forms, i.e. ceramic and metallic. Engineering efforts are underway at ANL to develop pilot-scale equipment which would precondition irradiated oxide fuel via pyrochemical processing and subsequently allow for electrometallurgical treatment of such non-metallic fuels into standard product and waste forms. This paper highlights the integration of proposed spent oxide fuel treatment with existing electrometallurgical processes. System designs and technical bases for development of pilot-scale oxide reduction equipment are also described

  8. Updated FY12 Ceramic Fuels Irradiation Test Plan

    International Nuclear Information System (INIS)

    Nelson, Andrew T.

    2012-01-01

    The Fuel Cycle Research and Development program is currently devoting resources to study of numerous fuel types with the aim of furthering understanding applicable to a range of reactors and fuel cycles. In FY11, effort within the ceramic fuels campaign focused on planning and preparation for a series of rabbit irradiations to be conducted at the High Flux Isotope Reactor located at Oak Ridge National Laboratory. The emphasis of these planned tests was to study the evolution of thermal conductivity in uranium dioxide and derivative compositions as a function of damage induced by neutron damage. Current fiscal realities have resulted in a scenario where completion of the planned rabbit irradiations is unlikely. Possibilities for execution of irradiation testing within the ceramic fuels campaign in the next several years will thus likely be restricted to avenues where strong synergies exist both within and outside the Fuel Cycle Research and Development program. Opportunities to augment the interests and needs of modeling, advanced characterization, and other campaigns present the most likely avenues for further work. These possibilities will be pursued with the hope of securing future funding. Utilization of synthetic microstructures prepared to better understand the most relevant actors encountered during irradiation of ceramic fuels thus represents the ceramic fuel campaign's most efficient means to enhance understanding of fuel response to burnup. This approach offers many of the favorable attributes embraced by the Separate Effects Testing paradigm, namely production of samples suitable to study specific, isolated phenomena. The recent success of xenon-imbedded thick films is representative of this approach. In the coming years, this strategy will be expanded to address a wider range of problems in conjunction with use of national user facilities novel characterization techniques to best utilize programmatic resources to support a science-based research program.

  9. Evolution of zirconium-based precipitates during oxidation and irradiation of Zr alloys (impact on the oxidation kinetics of Zr alloys)

    International Nuclear Information System (INIS)

    Pecheur, Dominique

    1993-01-01

    As the oxidation of the zircaloy sheath is one of the factors which limit the lifetime of nuclear fuel rods, this research thesis aims at a better knowledge of the involved oxidation mechanisms and to improve the oxidation resistance in order to increase rod lifetime. Oxidation test performed in autoclave to study zirconium alloy oxidation without irradiation showed that oxidation kinetics is significantly higher under irradiation. This difference is attributed to a different evolution of the sheath material under irradiation. Thus, this research focused on the role of precipitates in the oxidation process of zirconium alloys, and on the impact of their amorphization on this oxidation. After a detailed description of the context and of the various implemented experimental means, the author presents the results obtained on a reference material on the one hand, and on a material irradiated by ions or neutrons on the other hand. More particularly, the author studied in these both cases the introduction of precipitates in the oxide layer by transmission electronic microscopy, and oxidation kinetics obtained in autoclave on these two types of material. He reports the analysis of the introduction of precipitates in the oxide layer formed on the reference material. He proposes interpretations for the evolutions of structure and of chemical compositions of precipitates in the oxide layer. These observations are then correlated with oxidation kinetics in these alloys. Finally, the author discusses results of oxidation tests obtained on materials irradiated by ions and by neutrons [fr

  10. SLIGHTLY IRRADIATED FUEL (SIF) INTERIM DISPOSITION PROJECT

    International Nuclear Information System (INIS)

    Norton, S.H.

    2010-01-01

    CH2M HILL Plateau Remediation Company (CH2M HILL PRC) is proud to submit the Slightly Irradiated Fuel (SIF) Interim Disposition Project for consideration by the Project Management Institute as Project of the Year for 2010. The SIF Project was a set of six interrelated sub-projects that delivered unique stand-alone outcomes, which, when integrated, provided a comprehensive and compliant system for storing high risk special nuclear materials. The scope of the six sub-projects included the design, construction, testing, and turnover of the facilities and equipment, which would provide safe, secure, and compliant Special Nuclear Material (SNM) storage capabilities for the SIF material. The project encompassed a broad range of activities, including the following: Five buildings/structures removed, relocated, or built; Two buildings renovated; Structural barriers, fencing, and heavy gates installed; New roadways and parking lots built; Multiple detection and assessment systems installed; New and expanded communication systems developed; Multimedia recording devices added; and A new control room to monitor all materials and systems built. Project challenges were numerous and included the following: An aggressive 17-month schedule to support the high-profile Plutonium Finishing Plant (PFP) decommissioning; Company/contractor changeovers that affected each and every project team member; Project requirements that continually evolved during design and construction due to the performance- and outcome-based nature ofthe security objectives; and Restrictions imposed on all communications due to the sensitive nature of the projects In spite of the significant challenges, the project was delivered on schedule and $2 million under budget, which became a special source of pride that bonded the team. For years, the SIF had been stored at the central Hanford PFP. Because of the weapons-grade piutonium produced and stored there, the PFP had some of the tightest security on the Hanford

  11. SLIGHTLY IRRADIATED FUEL (SIF) INTERIM DISPOSITION PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    NORTON SH

    2010-02-23

    CH2M HILL Plateau Remediation Company (CH2M HILL PRC) is proud to submit the Slightly Irradiated Fuel (SIF) Interim Disposition Project for consideration by the Project Management Institute as Project of the Year for 2010. The SIF Project was a set of six interrelated sub-projects that delivered unique stand-alone outcomes, which, when integrated, provided a comprehensive and compliant system for storing high risk special nuclear materials. The scope of the six sub-projects included the design, construction, testing, and turnover of the facilities and equipment, which would provide safe, secure, and compliant Special Nuclear Material (SNM) storage capabilities for the SIF material. The project encompassed a broad range of activities, including the following: Five buildings/structures removed, relocated, or built; Two buildings renovated; Structural barriers, fencing, and heavy gates installed; New roadways and parking lots built; Multiple detection and assessment systems installed; New and expanded communication systems developed; Multimedia recording devices added; and A new control room to monitor all materials and systems built. Project challenges were numerous and included the following: An aggressive 17-month schedule to support the high-profile Plutonium Finishing Plant (PFP) decommissioning; Company/contractor changeovers that affected each and every project team member; Project requirements that continually evolved during design and construction due to the performance- and outcome-based nature ofthe security objectives; and Restrictions imposed on all communications due to the sensitive nature of the projects In spite of the significant challenges, the project was delivered on schedule and $2 million under budget, which became a special source of pride that bonded the team. For years, the SIF had been stored at the central Hanford PFP. Because of the weapons-grade piutonium produced and stored there, the PFP had some of the tightest security on the Hanford

  12. Fuel-cladding chemical interaction in mixed-oxide fuels

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Weber, J.W.; Devary, J.L.

    1978-10-01

    The character and extent of fuel-cladding chemical interaction (FCCI) was established for UO 2 -25 wt% PuO 2 clad with 20% cold worked Type 316 stainless steel irradiated at high cladding temperatures to peak burnups greater than 8 atom %. The data base consists of 153 data sets from fuel pins irradiated in EBR-II with peak burnups to 9.5 atom %, local cladding inner surface temperatures to 725 0 C, and exposure times to 415 equivalent full power days. As-fabricated oxygen-to-metal ratios (O/M) ranged from 1.938 to 1.984 with the bulk of the data in the range 1.96 to 1.98. HEDL P-15 pins provided data at low heat rates, approx. 200 W/cm, and P-23 series pins provided data at higher heat rates, approx. 400 W/cm. A design practice for breeder reactors is to consider an initial reduction of 50 microns in cladding thickness to compensate for possible FCCI. This approach was considered to be a conservative approximation in the absence of a comprehensive design correlation for extent of interaction. This work provides to the designer a statistically based correlation for depth of FCCI which reflects the influences of the major fuel and operating parameters on FCCI

  13. Reprocessing of irradiated fuel: pros and cons

    International Nuclear Information System (INIS)

    Lebedev, O.G.; Novikov, V.M.

    1991-01-01

    The acceptable-safety nuclear reactors (APWR, LMFBR, MSBR, MSCR) can be provided by the enrichment industry and by plutonium reserves. But steady accumulation of spent fuel will inevitably make to return to the problems of fuel recycle. PUREX-processing increases a danger of radionuclides spreading due to the presence of large buffer tanks. Using of compact fluoride - volatility process will sharply reduce a nuclide leakage likewise permit to reprocess a fuel with a burnup as high as possible. Success of a powerful robots development give an opportunity to design a fluoride-volatility plant twice cheaper than PUREX. (author)

  14. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1982-06-01

    This publication is the third in a proposed series of annual publications issued by the Nuclear Regulatory Commission in response to public information requests regarding the Commission's regulation of shipments of irradiated reactor fuel. Subsequent issues in this series will update the information contained herein. This publication contains basically three kinds of information: (1) routes approved by the Commission for the shipment of irradiated reactor fuel, (2) information regarding any safeguards-significant incidents which have been reported to occur during shipments along such routes, and (3) cumulative amounts of material shipped

  15. Predicting spent fuel oxidation states in a tuff repository

    International Nuclear Information System (INIS)

    Einziger, R.E.; Woodley, R.E.

    1987-01-01

    Nevada Nuclear Waste Storage Investigations Project (NNWSI) is studying the suitability of the tuffaceous rocks at Yucca Mountain as a waste repository for spent fuel disposal. The oxidation state of the LWR spent fuel in the moist air environment of a tuff repository could be a significant factor in determining its leaching and dissolution characteristics. Predictions as to which oxidation states would be present are important in analyzing such a repository and thus the present study was undertaken. A set of TGA (thermogravimetric analysis) tests were conducted on well-controlled samples of irradiated PWR fuel with time and temperature as the only variables. The tests were conducted between 140 and 225 0 C for a duration up to 2200 hours. The weight gain curves were analyzed in terms of diffusion through a layer of U 3 O 7 , diffusion into the grains to form a solid solution, a simplified empirical representation of a combination of grain boundary diffusion and bulk grain oxidation. Reaction rate constants were determined in each case, but analysis of these data could not establish a definitive mechanism. 21 refs., 10 figs., 3 tabs

  16. Monitoring for fuel sheath defects in three shipments of irradiated CANDU nuclear fuel

    International Nuclear Information System (INIS)

    Johnson, H.M.

    1978-01-01

    Analyses of radioactive gases within the Pegase shipping flask were performed at the outset and at the completion of three shipments of irradiated nuclear fuel from the Douglas Point Generating Station to Whiteshell Nuclear Research Establishment. No increases in the concentration of active gases, volatiles or particulates were observed. The activity of the WR-1 bay water rose only marginally due to the storage of the fuel. Other tests indicated that minimal surface contamination was present. These data established that defects in fuel element sheaths did not arise during the transport or the handling of this irradiated fuel. The observation has significance for the prospect of irradiated nuclear fuel transfer and handling in preparation for storage or disposal. (author)

  17. SIEX3: A correlated computer code for prediction of fast reactor mixed oxide fuel and blanket pin performance

    International Nuclear Information System (INIS)

    Baker, R.B.; Wilson, D.R.

    1986-04-01

    The SIEX3 computer program was developed to calculate the fuel and cladding performance of oxide fuel and oxide blanket pins irradiated in the fast neutron environment of a liquid metal cooled reactor. The code is uniquely designed to be accurate yet quick running and use a minimum of computer core storage. This was accomplished through the correlation of physically based models to very large data bases of irradiation test results. Data from over 200 fuel pins and over 800 transverse fuel microscopy samples were used in the calibrations

  18. Trends for Methane Oxidation at Solid Oxide Fuel Cell Conditions

    DEFF Research Database (Denmark)

    Kleis, Jesper; Jones, Glenn; Abild-Pedersen, Frank

    2009-01-01

    First-principles calculations are used to predict a plausible reaction pathway for the methane oxidation reaction. In turn, this pathway is used to obtain trends in methane oxidation activity at solid oxide fuel cell (SOFC) anode materials. Reaction energetics and barriers for the elementary...... the Ni surfaces to other metals of interest. This allows the reactivity over the different metals to be understood in terms of two reactivity descriptors, namely, the carbon and oxygen adsorption energies. By combining a simple free-energy analysis with microkinetic modeling, activity landscapes of anode...

  19. Irradiation performance of uranium-molybdenum alloy dispersion fuels

    International Nuclear Information System (INIS)

    Almeida, Cirila Tacconi de

    2005-01-01

    The U-Mo-Al dispersion fuels of Material Test Reactors (MTR) are analyzed in terms of their irradiation performance. The irradiation performance aspects are associated to the neutronic and thermal hydraulics aspects to propose a new core configuration to the IEA-R1 reactor of IPEN-CNEN/SP using U-Mo-Al fuels. Core configurations using U-10Mo-Al fuels with uranium densities variable from 3 to 8 gU/cm 3 were analyzed with the computational programs Citation and MTRCR-IEA R1. Core configurations for fuels with uranium densities variable from 3 to 5 gU/cm 3 showed to be adequate to use in IEA-R1 reactor e should present a stable in reactor performance even at high burn-up. (author)

  20. Basic properties of fuel determining its behavior under irradiation

    International Nuclear Information System (INIS)

    Konovalov, I.I.

    2000-01-01

    The theoretical model describing a swelling of nuclear fuel at low irradiation temperatures is considered. The critical physical parameters of substances determining behavior of point defects, gas fission atoms, dislocation density, nucleation and growth of gas-contained pores are determined. The correlation between meanings of critical parameters and physical properties of substance is offered. The accounts of swelling of various dense fuels with reference to work in conditions of research reactors are given. (author)

  1. What destiny could be given to the nuclear irradiated fuel

    International Nuclear Information System (INIS)

    Mundim, S.G.

    1985-01-01

    The uranium used in nuclear plants in the production of electric energy is not totally consumed. Part of the fuel that is left over is composed of radioactive material, that represents great danger to earth life. The destines that could be given to the irradiated fuel - reprocessing, provisional or definite storage - depend on the policy adopted by each country that enters the nuclear era, being involved in this increasing problem. (Author) [pt

  2. Oxidative stability examination of irradiated swine for samples

    International Nuclear Information System (INIS)

    Formanek, Z.

    1995-01-01

    DSC (Differential Scanning Calorimetry), OBM (Oxygen Bomb Method) methods and POV (Peroxide Value) determination was applied to determine the oxidative stability of lard samples irradiated by a Co 60 gamma source at the dose of 0; 0.75; 2.5kGy. Both of the methods seem to be suitable to determine oxidative stability of fats, because in every case lowering oxidative stability was received with increasing irradiation dose. (R.P.). 8 refs., 7 figs., 1 tab

  3. Dearomatization of jet fuel on irradiated platinum-supported catalyst

    International Nuclear Information System (INIS)

    Mucka, V.; Ostrihonova, A.; Kopernicky, I.; Mikula, O.

    1983-01-01

    The effect of ionizing radiation ( 60 Co #betta#-rays) on Pt-supported catalyst used for the dearomatization of jet fuel with distillation in the range 395 to 534 K has been studied. Pre-irradiation of the catalyst with doses in the range 10 2 to 5 x 10 4 Gy leads to the partial catalyst activation. Irradiation of the catalyst enhances its resistance to catalyst poisons, particularly to sulphur-compounds, and this is probably the reason for its catalytic activity being approx. 60 to 100% greater than that of un-irradiated catalyst. Optimum conditions for dearomatization on the irradiated catalyst were found and, by means of a rotary three-factorial experiment, it was shown that these lie at lower temperatures and lower pressures than those for un-irradiated catalyst. (author)

  4. Clarification of dissolved irradiated light-water-reactor fuel

    International Nuclear Information System (INIS)

    Rodrigues, G.C.

    1983-02-01

    Bench-scale studies with actual dissolved irradiated light water reactor (LWR) fuels showed that continuous centrifugation is a practical clarification method for reprocessing. Dissolved irradiated LWR fuel was satisfactorily clarified in a bench-scale, continuous-flow bowl centrifuge. The solids separated were successfully reslurried in water. When the reslurried solids were mixed with clarified centrate, the resulting suspension behaved similar to the original dissolver solution during centrifugation. Settling rates for solids in actual irradiated fuel solutions were measured in a bottle centrifuge. The results indicate that dissolver solutions may be clarified under conditions achievable by available plant-scale centrifuge technology. The effective particle diameter of residual solids was calculated to be 0.064 microns for Oconee-1 fuel and 0.138 microns for Dresden-1 fuel. Filtration was shown unsuitable for clarification of LWR fuel solutions. Conventional filtration with filter aid would unacceptably complicate remote canyon operation and maintenance, might introduce dissolved silica from filter aids, and might irreversibly plug the filter with dissolver solids. Inertial filtration exhibited irreversible pluggage with nonradioactive stand-in suspensions under all conditions tested

  5. DISSOLUTION OF IRRADIATED MURR FUEL ASSEMBLIES

    Energy Technology Data Exchange (ETDEWEB)

    Kyser, E.

    2010-06-17

    A literature survey on the dissolution of spent nuclear fuel from the University of Missouri Research Reactor (MURR) has been performed. This survey encompassed both internal and external literature sources for the dissolution of aluminum-clad uranium alloy fuels. The most limiting aspect of dissolution in the current facility configuration involves issues related to the control of the flammability of the off-gas from this process. The primary conclusion of this work is that based on past dissolution of this fuel in H-Canyon, four bundles of this fuel (initial charge) may be safely dissolved in a nitric acid flowsheet catalyzed with 0.002 M mercuric nitrate using a 40 scfm purge to control off-gas flammability. The initial charge may be followed by a second charge of up to five bundles to the same dissolver batch depending on volume and concentration constraints. The safety of this flowsheet relies on composite lower flammability limits (LFL) estimated from prior literature, pilot-scale work on the dissolution of site fuels, and the proposed processing flowsheet. Equipment modifications or improved LFL data offer the potential for improved processing rates. The fuel charging sequence, as well as the acid and catalyst concentrations, will control the dissolution rate during the initial portion of the cycle. These parameters directly impact the hydrogen and off-gas generation and, along with the purge flowrate determine the number of bundles that may be charged. The calculation approach within provides Engineering a means to determine optimal charging patterns. Downstream processing of this material should be similar to that of recent processing of site fuels requiring only minor adjustments of the existing flowsheet parameters.

  6. The KNK II/1 fuel assembly NY-205: Compilation of the irradiation history and the fuel and fuel pin fabrication data of the INTERATOM data bank system BESEX

    International Nuclear Information System (INIS)

    Patzer, G.; Geier, F.

    1988-01-01

    The fuel assembly NY-205 has been irradiated during the first and the second core of KNK II with a total residence time of 832 equivalent full-power days. A maximum burnup of 175.000 MWd/tHM or 18.6 % was reached with a maximum steel damage of 66 dpa-NRT. For the cladding the materials 1.4970 and 1.4981 have been used in different metallurgical conditions, and for the Uranium/Plutonium mixed- oxide fuel the most important variants of the major fabrication parameters had been realized. The assembly will be brought to the Hot Cells of the KfK Karlsruhe for post-irradiation examination in February 1988, so that the knowledge of the fabrication data is of interest for the selection of fuel pins and for the evaluation of the examination results. Therefore this report compiles the fuel and fuel pin fabrication data from the INTERATOM data bank system BESEX and additionally, an overview of the irradiation history of the assembly is given [de

  7. Study on the irradiation swelling of U3Si2-Al dispersion fuel

    International Nuclear Information System (INIS)

    Xing Zhonghu; Ying Shihao

    2001-01-01

    The dominant modeling mechanisms on irradiation swelling of U 3 Si 2 -Al dispersion fuel are introduced. The core of dispersion fuel is looked to as micro-fuel elements of continuous matrix. The formation processes of gas bubbles in the fuel phase are described through the behavior mechanisms of fission gases. The swelling in the fuel phase causes the interaction between fuel particles and metal matrix, and the metal matrix can restrain the irradiation swelling of fuel particles. The developed code can predict irradiation-swelling values according to the parameters of fuel elements and irradiation conditions, and the predicted values are in agreement with the measured results

  8. Bilateral cooperation between Germany and Brazil on fuel irradiation

    International Nuclear Information System (INIS)

    Dias, J.W.

    1977-01-01

    Within the framework of the Government Agreement on Scientific and Technical Cooperation between the Federal Republic of Germany and Brazil, the Brazilian National Atomic Commission and the Juelich Nuclear Research Center (KFA) signed on 23rd April, 1971 an Agreement on Cooperation in the field of Nuclear Research and Reactor Technology. Projects have been elaborated in fields of mutual interest to share activities between the partner institutes in both countries. A typical project is the fuel irradiation programme jointly prepared by NUCLEBRAS and KFA-Juelich. Brazil is planning to use elements of its own production in nuclear power plants to be erected within the German-Brazilian Industrial Agreement. As no material test reactor is available in Brazil it is expedient to irradiate samples of Brazilian production in Germany. Brazilian collaborators will participate in the preparation, execution and post-irradiation examination. In this way an optimum transfer of all information and results is assured. In the first phase, sample rods manufactured in Brazil are irradiated in the FRJ-2 test reactor in Juelich. These rods are assembled under clean conditions in the NUCLEBRAS research centres. The first Brazilian test rods showed excellent in-pile behaviour even under very high fuel rod capacity. In the second phase, fuel rods of original length manufactured and assembled in Brazil will be irradiated in German power plants, and, at the same time, additional irradiations of small samples will be carried out in test reactors. In the third phase, rod clusters and complete fuel elements will be manufactured in Brazil and irradiated in German power plants until target burn-up. All the necessary prerequisites have been fulfilled to meet the above requirements, i.e. mutual interest, good infrastructure maintained by both partners, qualified personnel and last but not least unbureaucratic and effective help by the coordinating offices of NUCLEBRAS and KFA

  9. Irradiation test plan of oxidation-resistant graphite in WWR-K Research Reactor

    International Nuclear Information System (INIS)

    Sumita, Junya; Shibata, Taiju; Sakaba, Nariaki; Osaki, Hirotaka; Kato, Hideki; Fujitsuka, Kunihiro; Muto, Takenori; Gizatulin, Shamil; Shaimerdenov, Asset; Dyussambayev, Daulet; Chakrov, Petr

    2014-01-01

    Graphite materials are used for the in-core components of High Temperature Gas-cooled Reactor (HTGR) which is a graphite-moderated and helium gas-cooled reactor. In the case of air ingress accident in HTGR, SiO_2 protective layer is formed on the surface of SiC layer in TRISO CFP and oxidation of SiC does not proceed and fission products are retained inside the fuel particle. A new safety concept for the HTGR, called Naturally Safe HTGR, has been recently proposed. To enhance the safety of Naturally Safe HTGR ultimately, it is expected that oxidation-resistant graphite is used for graphite components to prevent the TRISO CFPs and fuel compacts from failure. SiC coating is one of candidate methods for oxidation-resistant graphite. JAEA and four graphite companies launched R&Ds to develop the oxidation-resistant graphite and the International Science and Technology Center (ISTC) partner project with JAEA and INP was launched to investigate the irradiation effects on the oxidation-resistant graphite. To determine grades of the oxidation-resistant graphite which will be adopted as irradiation test, a preliminary oxidation test was carried out. This paper described the results of the preliminary oxidation test, the plan of out-of-pile test, irradiation test and post-irradiation test (PIE) of the oxidation-resistant graphite. The results of the preliminary oxidation test showed that the integrity of the oxidation resistant graphite was confirmed and that all of grades used in the preliminary test can be adopted as the irradiation test. Target irradiation temperature was determined to be 1473 (K) and neutron fluence was determined to be from 0.54 × 10"2"5through 1.4 × 10"2"5 (/m"2, E>0.18MeV). Weight change, oxidation rate, activation energy, surface condition, etc. will be evaluated in out-of-pile test and weight change, irradiation effect on oxidation rate and activation energy, surface condition, etc. will be evaluated in PIE. (author)

  10. Fuel Accident Condition Simulator (FACS) Furnace for Post-Irradiation Heating Tests of VHTR Fuel Compacts

    Energy Technology Data Exchange (ETDEWEB)

    Paul A Demkowicz; Paul Demkowicz; David V Laug

    2010-10-01

    Abstract –Fuel irradiation testing and post-irradiation examination are currently in progress as part of the Next Generation Nuclear Plant Fuels Development and Qualification Program. The PIE campaign will include extensive accident testing of irradiated very high temperature reactor fuel compacts to verify fission product retention characteristics at high temperatures. This work will be carried out at both the Idaho National Laboratory (INL) and the Oak Ridge National Laboratory, beginning with accident tests on irradiated fuel from the AGR-1 experiment in 2010. A new furnace system has been designed, built, and tested at INL to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000°C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, Eu, and I) and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator (FACS) furnace system, as well as preliminary system calibration results.

  11. Irradiation test plan of the simulated DUPIC fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Ki Kwang; Yang, M. S.; Kim, B. K. [Korea Atomic Energy Research Institute, Taejon (Korea)

    1999-11-01

    Simulated DUPIC fuel had been irradiated from Aug. 4, 1999 to Oct. 4 1999, in order to produce the data of its in-core behavior, to verify the design of DUPIC non-instrumented capsule developed, and to ensure the irradiation requirements of DUPIC fuel at HANARO. The welding process was certified for manufacturing the mini-element, and simulated DUPIC fuel rods were manufactured with simulated DUPIC pellets through examination and test. The non-instrumented capsule for a irradiation test of DUPIC fuel has been designed and manufactured referring to the design specification of the HANARO fuel. This is to be the design basis of the instrumented capsule under consideration. The verification experiment, whether the capsule loaded in the OR4 hole meet the HANARO requirements under the normal operation condition, as well as the structural analysis was carried out. The items for this experiment were the pressure drop test, vibration test, integrity test, et. al. It was noted that each experimental result meet the HANARO operational requirements. For the safety analysis of the DUPIC non-instrumented capsule loaded in the HANARO core, the nuclear/mechanical compatibility, thermodynamic compatibility, integrity analysis of the irradiation samples according to the reactor condition as well as the safety analysis of the HANARO were performed. Besides, the core reactivity effects were discussed during the irradiation test of the DUPIC capsule. The average power of each fuel rod in the DUPIC capsule was calculated, and maximal linear power reflecting the axial peaking power factor from the MCNP results was evaluated. From these calculation results, the HANARO core safety was evaluated. At the end of this report, similar overseas cases were introduced. 9 refs., 16 figs., 10 tabs. (Author)

  12. Some alternatives to the mixed oxide fuel cycle

    International Nuclear Information System (INIS)

    Deonigi, D.E.; Eschbach, E.A.; Goldsmith, S.; Pankaskie, P.J.; Rohrmann, C.A.; Widrig, R.D.

    1977-02-01

    While on initial examination each of the six fuel cycle concepts (tandem cycle, extended burnup, fuel rejuvenation, coprocessing, partial reprocessing, and thorium) described in the report may have some potential for improving safeguards, none of the six appears to have any other major or compelling advantages over the mixed oxide (MOX) fuel cycle. Compared to the MOX cycle, all but coprocessing appear to have major disadvantages, including severe cost penalties. Three of the concepts-tandem, extended burnup, and rejuvenation--share the basic problems of the throwaway cycle (GESMO Alternative 6): without reprocessing, high-level waste volumes and costs are substantially increased, and overall uranium utilization decreases for three reasons. First, the parasitic fission products left in the fuel absorb neutrons in later irradiation steps reducing the overall neutronic efficiencies of these cycles. Second, discarded fuel still has sufficient fissile values to warrant recycle. Third, perhaps most important, the plutonium needed for breeder start-up will not be available; without the breeder, uranium utilization would drop by about a factor of sixty. Two of the concepts--coprocessing and partial reprocessing--involve variations of the basic MOX fuel cycle's chemical reprocessing step to make plutonium diversion potentially more difficult. These concepts could be used with the MOX fuel cycle or in conjunction with the tandem, extended burnup and rejuvenation concepts to eliminate some of the problems with those cycles. But in so doing, the basic impetus for those cycles--elimination of reprocessing for safeguards purposes--no longer exists. Of all the concepts considered, only coprocessing--and particularly the ''master blend'' version--appears to have sufficient promise to warrant a more detailed study. The master blend concept could possibly make plutonium diversion more difficult with minimal impact on the reprocessing and MOX fuel fabrication operations

  13. Status Report on the Fabrication of Fuel Cladding Chemical Interaction Test Articles for ATR Irradiations

    Energy Technology Data Exchange (ETDEWEB)

    Field, Kevin G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Howard, Richard H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-09-28

    FeCrAl alloys are a promising new class of alloys for light water reactor (LWR) applications due to their superior oxidation and corrosion resistance in high temperature environments. The current R&D efforts have focused on the alloy composition and processing routes to generate nuclear grade FeCrAl alloys with optimized properties for enhanced accident tolerance while maintaining properties needed for normal operation conditions. Therefore, the composition and processing routes must be optimized to maintain the high temperature steam oxidation (typically achieved by increasing the Cr and Al content) while still exhibiting properties conducive to normal operation in a LWR (such as radiation tolerance where reducing Cr content is favorable). Within this balancing act is the addition of understanding the influence on composition and processing routes on the FeCrAl alloys for fuel-cladding chemical interactions (FCCI). Currently, limited knowledge exists on FCCI for the FeCrAl-UO2 clad-fuel system. To overcome the knowledge gaps on the FCCI for the FeCrAl-UO2 clad-fuel system a series of fueled irradiation tests have been developed for irradiation in the Advanced Test Reactor (ATR) housed at the Idaho National Laboratory (INL). The first series of tests has already been reported. These tests used miniaturized 17x17 PWR fuel geometry rodlets of second-generation FeCrAl alloys fueled with industrial Westinghouse UO2 fuel. These rodlets were encapsulated within a stainless steel housing.To provide high fidelity experiments and more robust testing, a new series of rodlets have been developed deemed the Accident Tolerant Fuel Experiment #1 Oak Ridge National Laboratory FCCI test (ATF-1 ORNL FCCI). The main driving factor, which is discussed in detail, was to provide a radiation environment where prototypical fuel-clad interface temperatures are met while still maintaining constant contact between industrial fuel and the candidate cladding alloys

  14. Effects of irradiation on color and lipid oxidation of prosciutto

    International Nuclear Information System (INIS)

    Kong Qiulian; Qi Wenyuan; Yue Ling; Chen Zhijun; Bao Yingzi; Dai Xudong; Xu Yun

    2011-01-01

    This study dealt with the effect of irradiation on the color, ordor and lipid oxidation of prosciutto crudo. The hams were irradiated by γ-ray and electronic beam (EB). Changes of color, ordor, TBA value (TBARS), peroxide value (POV), carbonyl value and conjugated diene value were analyzed and compared with nonirradiated hams. Results showed that color index (a * ) of control, γ-ray irradiated and EB irradiated were 14.39, 9.45 and 11.71 respectively. γ-ray irradiation had been shown to have apparently detrimental effect on the color and ordor of hams, while EB irradiation had little detrimental effect. Irradiation increased POV and conjugated diene value, but the amounts of lipid oxidation products (TBARS, carbonyl value) were less than nonirradiated hams. (authors)

  15. Final safety analysis report for the irradiated fuels storage facility

    International Nuclear Information System (INIS)

    Bingham, G.E.; Evans, T.K.

    1976-01-01

    A fuel storage facility has been constructed at the Idaho Chemical Processing Plant to provide safe storage for spent fuel from two commercial HTGR's, Fort St. Vrain and Peach Bottom, and from the Rover nuclear rocket program. The new facility was built as an addition to the existing fuel storage basin building to make maximum use of existing facilities and equipment. The completed facility provides dry storage for one core of Peach Bottom fuel (804 elements), 1 1 / 2 cores of Fort St. Vrain fuel (2200 elements), and the irradiated fuel from the 20 reactors in the Rover program. The facility is designed to permit future expansion at a minimum cost should additional storage space for graphite-type fuels be required. A thorough study of the potential hazards associated with the Irradiated Fuels Storage Facility has been completed, indicating that the facility is capable of withstanding all credible combinations of internal accidents and pertinent natural forces, including design basis natural phenomena of a 10,000 year flood, a 175-mph tornado, or an earthquake having a bedrock acceleration of 0.33 g and an amplification factor of 1.3, without a loss of integrity or a significant release of radioactive materials. The design basis accident (DBA) postulated for the facility is a complete loss of cooling air, even though the occurrence of this situation is extremely remote, considering the availability of backup and spare fans and emergency power. The occurrence of the DBA presents neither a radiation nor an activity release hazard. A loss of coolant has no effect upon the fuel or the facility other than resulting in a gradual and constant temperature increase of the stored fuel. The temperature increase is gradual enough that ample time (28 hours minimum) is available for corrective action before an arbitrarily imposed maximum fuel centerline temperature of 1100 0 F is reached

  16. Precise measurement of fuel content of irradiated and nonirradiated materials

    International Nuclear Information System (INIS)

    Harker, Y.D.; Napper, P.R.; Proctor, A.E.

    1984-01-01

    This paper discusses the application of precise reactivity measurements in the Advanced Reactivity Measurement Facility at Idaho National Engineering Laboratory (INEL) to determine th fuel content in irradiated and nonirradiated materials. Different methods of reactivity measurements and examples of how they have been are presented, which provides an insight in capabilities available to analyze samples with different geometrical sizes from small volumes approx. 100 cc to 12 ft long fuel pins and also samples with different fuel content ranges from approx. 2 mg to approx. 600 g. The overall accuracy of these measurements is approx. 0.5% (1sigma)

  17. Advanced post-irradiation examination techniques for water reactor fuel. Proceedings of a technical committee meeting

    International Nuclear Information System (INIS)

    2002-03-01

    The purpose of the meeting was to provide and overview of the status of post-irradiation examination (PIE) techniques for water cooled reactor fuel assemblies and their components with emphasis given to advanced PIE techniques applied to high burnup fuel. Papers presented at the meeting described progress obtained in non-destructive (e.g. dimensional measurements, oxide layer thickness measurements, gamma scanning and tomography, neutron and X-ray radiography, etc.) and destructive PIE techniques (e.g. microstructural studies, elemental and isotopic analysis, measurement of physical and mechanical properties, etc.) used for investigation of water reactor fuel. Recent practice in high burnup fuel investigation revealed the importance of advanced PIE techniques, such as 3-D tomography, secondary ion mass spectrometry, laser flash, high resolution transmission and scanning electron microscopy, image analysis in microstructural studies, for understanding mechanisms of fuel behaviour under irradiation. Importance and needs for in-pile irradiation of samples and rodlets in instrumented rigs were also discussed. This TECDOC contains 20 individual papers presented at the meeting; each of the papers has been indexed separately

  18. Fission gas retention and axial expansion of irradiated metallic fuel

    International Nuclear Information System (INIS)

    Fenske, G.R.; Emerson, J.E.; Savoie, F.E.; Johanson, E.W.

    1986-05-01

    Out-of-reactor experiments utilizing direct electrical heating and infrared heating techniques were performed on irradiated metallic fuel. The results indicate accelerated expansion can occur during thermal transients and that the accelerated expansion is driven by retained fission gases. The results also demonstrate gas retention and, hence, expansion behavior is a function of axial position within the pin

  19. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1983-07-01

    This publication contains basically three kinds of information: routes approved by the Commission for the shipment of irradiated reactor fuel, information regarding any safeguards-significant incidents which have been reported to occur during shipments along such routes, and cumulative amounts of material shipped

  20. Isotope correlation and mass spectrometry techniques for irradiated fuel assay

    International Nuclear Information System (INIS)

    Deron, S.

    1985-01-01

    This paper outlines the methods used to account for fissionable materials in irradiated nuclear fuel elements entering reprocessing plants. Verification is accomplished at three mass balance stations in the plant. Techniques employed fall into two categories: isotopic and isotope dilution analyses by mass spectometry and isotope correlation techniques. These methods are discussed in some detail

  1. Irradiation of TZM: Uranium dioxide fuel pin at 1700 K

    Science.gov (United States)

    Mcdonald, G. E.

    1973-01-01

    A fuel pin clad with TZM and containing solid pellets of uranium dioxide was fission heated in a static helium-cooled capsule at a maximum surface temperature of 1700 K for approximately 1000 hr and to a total burnup of 2.0 percent of the uranium-235. The results of the postirradiation examination indicated: (1) A transverse, intergranular failure of the fuel pin occurred when the fuel pin reached 2.0-percent burnup. This corresponds to 1330 kW-hr/cu cm, where the volume is the sum of the fuel, clad, and void volumes in the fuel region. (2) The maximum swelling of the fuel pin was less than 1.5 percent on the fuel-pin diameter. (3) There was no visible interaction between the TZM clad and the UO2. (4) Irradiation at 1700 K produced a course-grained structure, with an average grain diameter of 0.02 centimeter and with some of the grains extending one-half of the thickness of the clad. (5) Below approximately 1500 K, the irradiation of the clad produced a moderately fine-grained structure, with an average grain diameter of 0.004 centimeter.

  2. DUPIC fuel irradiation test and performance evaluation; the performance analysis of pellet-cladding contact fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ho, K. I.; Kim, H. M.; Yang, K. B.; Choi, S. J. [Suwon University, Whasung (Korea)

    2002-04-01

    Thermal and mechanical models were reviewed, and selected for the analysis of nuclear fuel performance in reactor. 2 dimensional FEM software was developed. Thermal models-gap conductances, thermal conductivity of pellets, fission gas release, temperature distribution-were set and packaged into a software. Both thermal and mechanical models were interrelated to each other, and the final results, fuel performance during irradiation is obtained by iteration calculation. Also, the contact phenomena between pellet and cladding was analysed by mechanical computer software which was developed during this work. dimensional FEM program was developed which estimate the mechanical behavior and the thermal behaviors of nuclear fuel during irradiation. Since there is a importance during the mechanical deformation analysis in describing pellet-cladding contact phenomena, simplified 2 dimensional calculation method is used after the contact. The estimation of thermal fuel behavior during irradiation was compared with the results of other. 8 refs., 17 figs. (Author)

  3. ORR irradiation experiment OF-1: accelerated testing of HTGR fuel

    International Nuclear Information System (INIS)

    Tiegs, T.N.; Long, E.L. Jr.; Kania, M.J.; Thoms, K.R.; Allen, E.J.

    1977-08-01

    The OF-1 capsule, the first in a series of High-Temperature Gas-Cooled Reactor fuel irradiations in the Oak Ridge Research Reactor, was irradiated for more than 9300 hr at full reactor power (30 MW). Peak fluences of 1.08 x 10 22 neutrons/cm 2 (> 0.18 MeV) were achieved. General Atomic Company's magazine P13Q occupied the upper two-thirds of the test space and the ORNL magazine OF-1 the lower one-third. The ORNL portion tested various HTGR recycle particles and fuel bonding matrices at accelerated flux levels under reference HTGR irradiation conditions of temperature, temperature gradient, and fast fluence exposure

  4. Element bow profiles from new and irradiated CANDU fuel bundles

    International Nuclear Information System (INIS)

    Dennier, D.; Manzer, A.M.; Ryz, M.A.

    1996-01-01

    Improved methods of measuring element profiles on new CANDU fuel bundles were developed at the Sheridan Park Engineering Laboratory, and have now been applied in the hot cells at Whiteshell Laboratories. For the first time, the outer element profiles have been compared between new, out-reactor tested, and irradiated fuel elements. The comparison shows that irradiated element deformation is similar to that observed on elements in out-reactor tested bundles. In addition to the restraints applied to the element via appendages, the element profile appears to be strongly influenced by gravity and the end loads applied by local deformation of the endplate. Irradiation creep in the direction of gravity also tends to be a dominant factor. (author)

  5. Effects of irradiation on color and lipid oxidation of prosciutto

    International Nuclear Information System (INIS)

    Kong Qiulian; Qi Wenyuan; Yue Ling; Chen Zhijun; Bao Yingzi; Dai Xudong; Xu Yun

    2012-01-01

    This study dealt with the effect of irradiation on the color, irradiation odor and lipid oxidation of prosciutto crudo. The hams were irradiated by γ-ray and electronic beam (EB). Changes of color, irradiation odor, TBA value (TBARS), peroxide value (POV), carbonyl value and conjugated diene value were analyzed and compared with non-irradiated hams. Results showed that color index (a * ) of control, γ-ray irradiated and EB irradiated were 14.39, 9.45 and 11.71 respectively. The ratios of a * /b * were different with the type of rays. The ratio of a * /b * of EB irradiation was same with control, while that of γ-ray irradiation was decreased apparently. γ-ray irradiation had been shown to have apparently detrimental effect on the color and odor of hams, while EB irradiation had little detrimental effect. Irradiation increased POV and conjugated diene value, but the amounts of lipid oxidation products (TBARS, carbonyl value) were less than nonirradiated hams. (authors)

  6. Pilot-scale equipment development for lithium-based reduction of spent oxide fuel

    International Nuclear Information System (INIS)

    Herrmann, S. D.

    1998-01-01

    An integral function of the electrometallurgical conditioning of DOE spent nuclear fuel is the standardization of waste forms. Argonne National Laboratory (ANL) has developed and is presently demonstrating the electrometallurgical conditioning of sodium-bonded metal fuel from Experimental Breeder Reactor II, resulting in uranium, ceramic waste, and metal waste forms. Engineering studies are underway at ANL in support of pilot-scale equipment development, which would precondition irradiated oxide fuel and likewise demonstrate the application of electrometallurgical conditioning to such non-metallic fuels. This paper highlights the integration of proposed spent oxide fuel conditioning with existing electrometallurgical processes. Additionally, technical bases for engineering activities to support a scale up of an oxide reduction process are described

  7. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1991-01-01

    This circular has been prepared to provide information on the shipment of irradiated reactor fuel (spent fuel) subject to regulation by the US Nuclear Regulatory Commission (NRC). It provides a brief description of spent fuel shipment safety and safeguards requirements of general interest, a summary of data for 1979--1989 highway and railway shipments, and a listing, by State, of recent highway and railway shipment routes. The enclosed route information reflects specific NRC approvals that have been granted in response to requests for shipments of spent fuel. This publication does not constitute authority for carriers or other persons to use the routes described to ship spent fuel, other categories of nuclear waste, or other materials. 11 figs., 3 tabs

  8. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1992-06-01

    The circular has been prepared to provide information on the shipment of irradiated reactor fuel (spent fuel) subject to regulation by the US Nuclear Regulatory Commission (NRC). It provides a brief description of spent fuel shipment safety and safeguards requirements of general interest, a summary of data for 1979--1991 highway and railway shipments, and a listing, by State, of recent highway and railway shipment routes. The enclosed route information reflects specific NRC approvals that have been granted in response to requests for shipments of spent fuel. This publication does not constitute authority for carriers or other persons to use the routes described to ship spent fuel, other categories of nuclear waste, or other materials

  9. Examples of remote handling of irradiated fuel assemblies in Germany

    International Nuclear Information System (INIS)

    Peehs, M.; Knecht, K.

    1999-01-01

    Examples for the remote handling of irradiated fuel in Germany are presented in the following areas: - fuel assembling pool service activities; - early encapsulation of spent fuel in the pool of a nuclear power plant (NPP) at the end of the wet storage period. All development in remote fuel assembly handling envisages minimization of the radioactive dose applied to the operating staff. In the service area a further key objective for applying advanced methods is to perform the work faster and at a higher quality standard. The early encapsulation is a new technology to provide the final packaging of spent fuel already in the pool of a NPP to ensure reliable handling for all further back end processes. (author)

  10. Examination in hot laboratories of irradiated fuels from fast reactors

    International Nuclear Information System (INIS)

    Clottes, G.; Peray, R.; Ratier, J.L.

    1980-05-01

    Low irradiation rate examinations were carried out soon after the Rapsodie, Rapsodie Fortissimo and Phenix reactors were started up for the first time in order to check the level of maximum temperatures reached and the radial migration of oxygen and plutonium and to assess the movements of fuels inside the cladding. The other examinations were effected at a high specific burnup in order to defines the limit specific burnup securing the integrity of the fuel pin claddings (distortion, ruptures and possible consequences). The examinations carried out so far on fuel elements coming from Phenix or Rapsodie have allowed good fuel surveillance to be undertaken and the acquisition of a large number of data, thanks to which the fuel characteristics of future reactors of the system have been developed [fr

  11. MARMOT update for oxide fuel modeling

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Schwen, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States); Chakraborty, Pritam [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jiang, Chao [Idaho National Lab. (INL), Idaho Falls, ID (United States); Aagesen, Larry [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ahmed, Karim [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jiang, Wen [Idaho National Lab. (INL), Idaho Falls, ID (United States); Biner, Bulent [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bai, Xianming [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Tonks, Michael [Pennsylvania State Univ., University Park, PA (United States); Millett, Paul [Univ. of Arkansas, Fayetteville, AR (United States)

    2016-09-01

    This report summarizes the lower-length-scale research and development progresses in FY16 at Idaho National Laboratory in developing mechanistic materials models for oxide fuels, in parallel to the development of the MARMOT code which will be summarized in a separate report. This effort is a critical component of the microstructure based fuel performance modeling approach, supported by the Fuels Product Line in the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program. The progresses can be classified into three categories: 1) development of materials models to be used in engineering scale fuel performance modeling regarding the effect of lattice defects on thermal conductivity, 2) development of modeling capabilities for mesoscale fuel behaviors including stage-3 gas release, grain growth, high burn-up structure, fracture and creep, and 3) improved understanding in material science by calculating the anisotropic grain boundary energies in UO$_2$ and obtaining thermodynamic data for solid fission products. Many of these topics are still under active development. They are updated in the report with proper amount of details. For some topics, separate reports are generated in parallel and so stated in the text. The accomplishments have led to better understanding of fuel behaviors and enhance capability of the MOOSE-BISON-MARMOT toolkit.

  12. Irradiation experience with HTGR fuels in the Peach Bottom Reactor

    International Nuclear Information System (INIS)

    Scheffel, W.J.; Scott, C.B.

    1974-01-01

    Fuel performance in the Peach Bottom High-Temperature Gas-Cooled Reactor (HTGR) is reviewed, including (1) the driver elements in the second core and (2) the test elements designed to test fuel for larger HTGR plants. Core 2 of this reactor, which is operated by the Philadelphia Electric Company, performed reliably with an average nuclear steam supply availability of 85 percent since its startup in July 1970. Core 2 had accumulated a total of 897.5 equivalent full power days (EFPD), almost exactly its design life-time of 900 EFPD, when the plant was shut down permanently on October 31, 1974. Gaseous fission product release and the activity of the main circulating loop remained significantly below the limits allowed by the technical specifications and the levels observed during operation of Core 1. The low circulating activity and postirradiation examination of driver fuel elements have demonstrated the improved irradiation stability of the coated fuel particles in Core 2. Irradiation data obtained from these tests substantiate the performance predictions based on accelerated tests and complement the fuel design effort by providing irradiation data in the low neutron fluence region

  13. Irradiation test plan of instrumented capsule(05F-01K) for nuclear fuel irradiation in Hanaro (Revision 1)

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, Jae Min; Kim, B. G.; Choi, M. H. (and others)

    2006-09-15

    An instrumented capsule was developed to be able to measure fuel characteristics, such as fuel temperature, internal pressure of fuel rod, fuel pellet elongation, and neutron flux, etc., during the irradiation test of nuclear fuel in HANARO. The instrumented capsule for measuring and monitoring fuel centerline temperature and neutron flux was designed and manufactured. And then, to verify the design of the instrumented capsule in the test hole, it was successfully irradiated in the test hole of HANARO from March 14, 2003 to June 1, 2003 (53.84 full power days at 24 MW). In the year of 2004, 3 test fuel rods and the 03F-05K instrumented fuel capsule were designed and fabricated to measure fuel centerline temperature, internal pressure of fuel rod, and fuel axial deformation during irradiation test. Now, this capsule was successfully irradiated in the test hole OR5 of HANARO reactor from April 27, 2004 to October 1, 2004 (59.5 full power days at 24-30 MW). The capsule and fuel rods have been be dismantled and fuel rods have been examined at the hot cell of IMEF. The instrumented fuel capsule (05F-01K) was designed and manufactured for a design verification test of the dual instrumented fuel rods. The irradiation test of the 05F-01K instrumented fuel capsule will be carried out at the OR5 vertical experimental hole of HANARO.

  14. 78 FR 50313 - Physical Protection of Irradiated Reactor Fuel in Transit

    Science.gov (United States)

    2013-08-19

    ... Irradiated Reactor Fuel in Transit AGENCY: Nuclear Regulatory Commission. ACTION: Orders; rescission. SUMMARY... the NRC published a final rule, ``Physical Protection of Irradiated Fuel in Transit,'' on May 20, 2013... of Irradiated Reactor Fuel in Transit'' (RIN 3150-AI64; NRC-2009-0163). The final rule incorporates...

  15. Enhanced low-temperature oxidation of zirconium alloys under irradiation

    International Nuclear Information System (INIS)

    Cox, B.; Fidleris, V.

    1989-01-01

    The linear growth of relatively thick (>300 nm) interference-colored oxide films on zirconium alloy specimens exposed in the Advanced Test Reactor (ATR) coolant at ≤55 o C was unexpected. Initial ideas were that this was a photoconduction effect. Experiments to study photoconduction in thin anodic zirconium oxide (ZrO 2 ) films in the laboratory were initiated to provide background data. It was found that, in the laboratory, provided a high electric field was maintained across the oxide during ultraviolet (UV) irradiation, enhanced growth of oxide occurred in the irradiated area. Similarly enhanced growth could be obtained on thin thermally formed oxide films that were immersed in an electrolyte with a high electric field superimposed. This enhanced growth was found to be caused by the development of porosity in the barrier oxide layer by an enhanced local dissolution and reprecipitation process during UV irradiation. Similar porosity was observed in the oxide films on the ATR specimens. Since it is not thought that a high electric field could have been present in this instance, localized dissolution of fast-neutron primary recoil tracks may be the operative mechanism. In all instances, the specimens attempt to maintain the normal barrier-layer oxide thickness, which causes the additional oxide growth. Similar mechanisms may have operated during the formation of thick loosely adherent, porous oxides in homogeneous reactor solutions under irradiation, and may be the cause of enhanced oxidation of zirconium alloys in high-temperature water-cooled reactors in some water chemistries. (author)

  16. Oxide fuels and targets for transmutation

    International Nuclear Information System (INIS)

    Sudreau, F.; Bonnerot, J.M.; Warin, D.; Gaillard-Groleas, G.; Ferroud-Plattet, M.P.

    2007-01-01

    Full text of publication follows. Direction 1 of the French Act dated 30 December 1991 on the management of high-level, long-lived radioactive waste involves exploring solutions designed to separate long-lived radionuclides from the spent fuel and to transmute them under neutron flux into shorter half-lives or stable elements. In the French research programme conducted by CEA, these radionuclides are mainly minor actinides (americium, neptunium and curium) and fission products (particularly caesium, iodine and technetium). Within this context, this paper aims at illustrating the vast programme that CEA has performed in order to demonstrate the scientific and technical feasibility of minor actinide transmutation. An important part of the research was carried out in collaboration with French research (CNRS) and industrial (EDF, AREVA) organisations, and also in the framework of international co-operation programmes with the European Institute for Transuranium Elements in Karlsruhe (ITU), the US Department of Energy (DOE), the Japanese Atomic Energy Research Institute (now JAEA) and Central Research Institute of Electric Power Industry (CRIEPI) and the Russian Ministry for Atomic Energy (ROSATOM). Such research made it possible to evaluate the capacity of MOX fuels to be used as a support for minor actinide transmutation (homogeneous method). Simulations of pressurised water reactor (PWR) fuels have revealed the limits of this transmutation method, which are mainly related to the pressurization of the fuel rods and the formation of high active californium. On the contrary, for sodium-cooled fast reactor fuels possibly designed with large expansion plenums a first experimental demonstration of the transmutation of americium and neptunium has been successful in the Phenix reactor. Various studies designed to demonstrate the theoretical and experimental feasibility of transmutation using an inert support (heterogeneous method) have been carried out in HFR (EFTTRA

  17. Irradiation of UO2+x fuels in the TANOX device

    International Nuclear Information System (INIS)

    Dehaudt, P.; Caillot, L.; Delette, G.; Eminet, G.; Mocellin, A.

    1998-01-01

    The TANOX analytical irradiation device is presented and the first results concerning stoichiometric and hyper stoichiometric uranium dioxide fuels with two different grain sizes are given. The TANOX device is designed to obtain rapidly significant burnups in fuels at relatively low temperatures. It is placed at the periphery of the SILOE reactor and translated to adjust the irradiation power. The continuous measure of the centre-line temperature allows to control the experiment and to evaluate the thermal behaviour of the rods. A TANOX fuel rod has a length of 100 mm with 20 fuel pellets in a stainless steel cladding and is inserted in a thick aluminium alloy overcladding which is cooled by the primary water circuit reactor. These conditions of small size pellets and improved thermal exchanges have been designed to dissipate the heat power due to fission densities three to five times higher than in a PWR. The first analytical irradiation was devoted to the study of UO 2.00 , UO 2.01 and UO 2.02 fuels with standard and large grain sizes obtained by annealing. A burnup of about 9000 MWd.t -1 U was reached in these fuels. The thermal analysis shows a degraded conductivity for the UO 2.02 fuel rod due to the hyper stoichiometry. The released fractions of 85 Kr during irradiation are negligible as expected (lower than 0,1%). Some of the pellets were heat treated at 1700 deg. C for 5 hours. The gas release was analysed after 30 minutes and at the end of the treatment. The main results are as follows: the fission gas release (FGR) of the standard UO 2 varies from one sample to another; the FGR of the hyper stoichiometric fuels is of the same order of magnitude than that of the stoichiometric UO 2 fuel of normal grain sizes; the grain size increase has no effect on FGR for UO 2.00 but considerably decreases the FGR for UO 2.01 and UO 2.02 fuels. These heat treated samples are also observed to characterize the inter- and intragranular fission gas bubbles. (author)

  18. Information for irradiation and post-irradiation of the silicide fuel element prototype P-07

    International Nuclear Information System (INIS)

    Abbate, Maximo J.; Sbaffoni, Maria M.

    2003-01-01

    Included in the 'Silicides' Project, developed by the Nuclear Fuels Department of the National Atomic Energy Commission (CNEA), it is foreseen the qualification of this type of fuel for research reactors in order to be used in the Argentine RA-3 reactor and to confirm the CNEA as an international supplier. The paper presents basic information on several parameters corresponding to the new silicide prototype, called P-07, to be taken into account for its irradiation, postirradiation and qualification. (author)

  19. Behaviour of defective CANDU fuel: fuel oxidation kinetic and thermodynamic modelling

    International Nuclear Information System (INIS)

    Higgs, J.

    2005-01-01

    The thermal performance of operating CANDU fuel under defect conditions is affected by the ingress of heavy water into the fuel element. A mechanistic model has been developed to predict the extent of fuel oxidation in defective fuel and its affect on fuel thermal performance. A thermodynamic treatment of such oxidized fuel has been performed as a basis for the boundary conditions in the kinetic model. Both the kinetic and thermodynamic models have been benchmarked against recent experimental work. (author)

  20. Dissolution of mixed oxide spent fuel from FBR

    International Nuclear Information System (INIS)

    Sanyoshi, H.; Nishina, H.; Toyota, O.; Yamamoto, R.; Nemoto, S.; Okamoto, F.; Togashi, A.; Kawata, T.; Hayashi, S.

    1991-01-01

    At the Tokai Works of the Power Reactor and Nuclear Fuel Development Corporation (PNC), the Chemical Processing Facility (CPF) has been continuing operation since 1982 for laboratory scale hot experiments on reprocessing of FBR mixed oxide fuel. As a part of these experiments, dissolution experiments have been performed to define the key parameters affecting dissolution rates such as concentration of nitric acid, temperature and burnup and also to confirm the amount of insoluble residue. The dissolution rate of the irradiated fuel was determined to be in proportion to the 1.7 power of the nitric acid concentration. The activation energy determined from the experiments varied from 6 to 11 kcal/mol depending on the method of dissolution. The dissolution rate decreased as the fuel burnup increased in low nitric acid media below 5 mol/l. However, it was found that the effect of the burnup became negligible in a high concentration of nitric acid media. The amount of insoluble residue and its constituents were evaluated by changing the dissolution condition. (author)

  1. Industrial experience of irradiated nuclear fuel reprocessing

    International Nuclear Information System (INIS)

    Delange, M.

    1981-01-01

    At the moment and during the next following years, France and La Hague plant particularly, own the greatest amount of industrial experience in the field of reprocessing, since this experience is referred to three types of reactors, either broadly spread all through the world (GCR and LWR) or ready to be greatly developed in the next future (FBR). Then, the description of processes and technologies used now in France, and the examination of the results obtained, on the production or on the security points of view, are a good approach of the actual industrial experience in the field of spent fuel reprocessing. (author)

  2. Design considerations and operating experience with wet storage of Ontario Hydro's irradiated fuel

    International Nuclear Information System (INIS)

    Frost, C.R.; Naqvi, S.J.; McEachran, R.A.

    1987-01-01

    The characteristics of Ontario Hydro's fuel and at-reactor irradiated fuel storage water pools (or irradiated fuel bays) are described. There are two types of bay known respectively as primary bays and auxiliary bays, used for at-reactor irradiated fuel storage. Irradiated fuel is discharged remotely from Ontario Hydro's reactors to the primary bays for initial storage and cooling. The auxiliary bays are used to receive and store fuel after its initial cooling in the primary bay, and provide additional storage capacity as needed. The major considerations in irradiated fuel bay design, including site-specific requirements, reliability and quality assurance, are discussed. The monitoring of critical fuel bay components, such as bay liners, the development of high storage density fuel containers, and the use of several irradiated fuel bays at each reactor site have all contributed to the safe handling of the large quantities of irradiated fuel over a period of about 25 years. Routine operation of the irradiated fuel bays and some unusual bay operational events are described. For safety considerations, the irradiated fuel in storage must retain its integrity. Also, as fuel storage is an interim process, likely for 50 years or more, the irradiated fuel should be retrievable for downstream fuel management phases such as reprocessing or disposal. A long-term experimental program is being used to monitor the integrity of irradiated fuel in long-term wet storage. The well characterized fuel, some of which has been in wet storage since 1962 is periodically examined for possible deterioration. The evidence from this program indicates that there will be no significant change in irradiated fuel integrity (and retrievability) over a 50 year wet storage period

  3. Irradiation behavior of uranium-molybdenum dispersion fuel: Fuel performance data from RERTR-1 and RERTR-2

    International Nuclear Information System (INIS)

    Meyer, M.K.; Clark, C.R.; Hayes, S.L.; Strain, R.V.; Hofman, G.L.; Snelgrove, J.L.; Park, J.M.; Kim, K.H.

    1999-01-01

    This paper presents quantitative data on the irradiation behavior of uranium-molybdenum fuels from the low temperature RERTR-1 and -2 experiments. Fuel swelling measurements of U-Mo fuels at ∼40% and ∼70% burnup are presented. The rate of fuel-matrix interaction layer growth is estimated. Microstructures of fuel in the pre- and postirradiation condition were compared. Based on these data, a qualitative picture of the evolution of the U-Mo fuel microstructure during irradiation has been developed. Estimates of uranium-molybdenum fuel swelling and fuel-matrix interaction under high-power research reactor operating conditions are presented. (author)

  4. Status on the construction of the fuel irradiation test facility

    International Nuclear Information System (INIS)

    Park, Kook Nam; Sim, Bong Shick; Lee, Chung Young; Yoo, Seong Yeon

    2005-01-01

    As a facility to examine general performance of nuclear fuel under irradiation condition in HANARO, Fuel Test Loop(FTL) has been developed which can accommodate 3 fuel pins at the core irradiation hole(IR1 hole) taking consideration user's test requirement. 3-Pin FTL consists of In-Pile Test Section (IPS) and Out-of- Pile System (OPS). Test condition in IPS such as pressure, temperature and the water quality, can be controlled by OPS. 3-Pin FTL Conceptual design was set up in 2001 and had completed detail design including a design requirement and basic Piping and Instrument Diagram (P and ID) in 2004. The safety analysis report was prepared and submitted in early 2005 to the regulatory body(KINS) for review and approval of FTL. In 2005, the development team is going to purchase and manufacture hardware and make a contract for construction work. In 2006, the development team is going to install an FTL system performance test shall be done as a part of commissioning. After a 3-Pin FTL development which is expected to be finished by the 2007, FTL will be used for the irradiation test of the new PWR-type fuel and the usage of HANARO will be enhanced

  5. On Cherenkov light production by irradiated nuclear fuel rods

    International Nuclear Information System (INIS)

    Branger, E.; Grape, S.; Svärd, S. Jacobsson; Jansson, P.; Sundén, E. Andersson

    2017-01-01

    Safeguards verification of irradiated nuclear fuel assemblies in wet storage is frequently done by measuring the Cherenkov light in the surrounding water produced due to radioactive decays of fission products in the fuel. This paper accounts for the physical processes behind the Cherenkov light production caused by a single fuel rod in wet storage, and simulations are presented that investigate to what extent various properties of the rod affect the Cherenkov light production. The results show that the fuel properties have a noticeable effect on the Cherenkov light production, and thus that the prediction models for Cherenkov light production which are used in the safeguards verifications could potentially be improved by considering these properties. It is concluded that the dominating source of the Cherenkov light is gamma-ray interactions with electrons in the surrounding water. Electrons created from beta decay may also exit the fuel and produce Cherenkov light, and e.g. Y-90 was identified as a possible contributor to significant levels of the measurable Cherenkov light in long-cooled fuel. The results also show that the cylindrical, elongated fuel rod geometry results in a non-isotropic Cherenkov light production, and the light component parallel to the rod's axis exhibits a dependence on gamma-ray energy that differs from the total intensity, which is of importance since the typical safeguards measurement situation observes the vertical light component. It is also concluded that the radial distributions of the radiation sources in a fuel rod will affect the Cherenkov light production.

  6. Post-irradiation examinations of THERMHET composite fuels for transmutation

    Science.gov (United States)

    Noirot, J.; Desgranges, L.; Chauvin, N.; Georgenthum, V.

    2003-07-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl 2O 4 spinel inert matrix and around 40% weight of UO 2 to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour.

  7. Post-irradiation examinations of THERMHET composite fuels for transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Noirot, J. E-mail: jnoirot@cea.fr; Desgranges, L.; Chauvin, N.; Georgenthum, V

    2003-07-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl{sub 2}O{sub 4} spinel inert matrix and around 40% weight of UO{sub 2} to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour.

  8. Post-irradiation examinations of THERMHET composite fuels for transmutation

    International Nuclear Information System (INIS)

    Noirot, J.; Desgranges, L.; Chauvin, N.; Georgenthum, V.

    2003-01-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl 2 O 4 spinel inert matrix and around 40% weight of UO 2 to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour

  9. Solid oxide fuel cells and hydrogen production

    International Nuclear Information System (INIS)

    Dogan, F.

    2009-01-01

    'Full text': A single-chamber solid oxide fuel cell (SC-SOFC), operating in a mixture of fuel and oxidant gases, provides several advantages over the conventional SOFC such as simplified cell structure (no sealing required). SC-SOFC allows using a variety of fuels without carbon deposition by selecting appropriate electrode materials and cell operating conditions. The operating conditions of single chamber SOFC was studied using hydrocarbon-air gas mixtures for a cell composed of NiO-YSZ / YSZ / LSCF-Ag. The cell performance and catalytic activity of the anode was measured at various gas flow rates. The results showed that the open-circuit voltage and the power density increased as the gas flow rate increased. Relatively high power densities up to 660 mW/cm 2 were obtained in a SC-SOFC using porous YSZ electrolytes instead of dense electrolytes required for operation of a double chamber SOFC. In addition to propane- or methane-air mixtures as a fuel source, the cells were also tested in a double chamber configuration using hydrogen-air mixtures by controlling the hydrogen/air ratio at the cathode and the anode. Simulation of single chamber conditions in double chamber configurations allows distinguishing and better understanding of the electrode reactions in the presence of mixed gases. Recent research efforts; the effect of hydrogen-air mixtures as a fuel source on the performance of anode and cathode materials in single-chamber and double-chamber SOFC configurations,will be presented. The presentation will address a review on hydrogen production by utilizing of reversible SOFC systems. (author)

  10. Pickering irradiated fuel transfer conveyor isolation

    Energy Technology Data Exchange (ETDEWEB)

    Koivisto, D J; Eijsermans, L J [Atomic Energy of Canada Ltd., Mississauga, ON (Canada)

    1997-12-31

    Pickering A NGS has been in operation for 25 years and is one of the longest in service CANDU stations. Some underwater fuel handling equipment, notably the conveyor stops, have been without maintenance throughout that time. This paper describes the concept of a conveyor isolation system that permits draining of a single or multiple elevator columns and also the early stages of a development program for the elastomeric sealing element. The prototype seal element has been proven in lab tests to be capable of limiting leakage to 0.5 IGPM (imperial gallons per minute) at the design pressure of 6.5 psi. The design of a sealing element is particularly interesting because the conveyor tube is a square cross-section which contains an additional obstruction , a conveyor drive cable. A seal delivery, actuating and positioning system has been conceptually laid out and the design is proceeding, with projected implementation in 1998. (author). 8 figs.

  11. Pickering irradiated fuel transfer conveyor isolation

    International Nuclear Information System (INIS)

    Koivisto, D.J.; Eijsermans, L.J.

    1996-01-01

    Pickering A NGS has been in operation for 25 years and is one of the longest in service CANDU stations. Some underwater fuel handling equipment, notably the conveyor stops, have been without maintenance throughout that time. This paper describes the concept of a conveyor isolation system that permits draining of a single or multiple elevator columns and also the early stages of a development program for the elastomeric sealing element. The prototype seal element has been proven in lab tests to be capable of limiting leakage to 0.5 IGPM (imperial gallons per minute) at the design pressure of 6.5 psi. The design of a sealing element is particularly interesting because the conveyor tube is a square cross-section which contains an additional obstruction , a conveyor drive cable. A seal delivery, actuating and positioning system has been conceptually laid out and the design is proceeding, with projected implementation in 1998. (author). 8 figs

  12. Thoria-fuel irradiation. Program to irradiate 80% ThO2/20% UO2 ceramic pellets at the Savannah River Plant

    International Nuclear Information System (INIS)

    Pickett, J.B.

    1982-02-01

    This report describes the fabrication of proliferation-resistant thorium oxide/uranium oxide ceramic fuel pellets and preparations at the Savannah River Laboratory (SRL) to irradiate those materials. The materials were fabricated in order to study head end process steps (decladding, tritium removal, and dissolution) which would be required for an irradiated proliferation-resistant thorium based fuel. The thorium based materials were also to be studied to determine their ability to withstand average commercial light water reactor (LWR) irradiation conditions. This program was a portion of the Thorium Fuel Cycle Technology (TFCT) Program, and was coordinated by the Oak Ridge National Laboratory (ORNL) under the Consolidated Fuel Reprocessing Program (CFRP). The fuel materials were to be irradiated in a Savannah River Plant (SRP) reactor at conditions simulating the heat ratings and burnup of a commercial LWR. The program was terminated due to a de-emphasis of the TFCT Program, following completion of the fabrication of the fuel and the modified assemblies which were to be used in the SRP reactor. The reactor grade ceramic pellets were fabricated for SRL by Battelle, Pacific Northwest Laboratories. Five fuel types were prepared: 100% UO 2 pellets (control); 80% ThO 2 /20% UO 2 pellets; approximately 80% ThO 2 /20% UO 2 + 0.25 CaO (dissolution aid) pellets; 100% UO 2 hybrid pellets (prepared from sol-gel microspheres); and 100% ThO 2 pellets (control). All of the fuel materials were transferred to SRL from PNL and were stored pending a subsequent reactivation of the TFCT Programs

  13. Diametral strain of fast reactor MOX fuel pins with austenitic stainless steel cladding irradiated to high burnup

    Energy Technology Data Exchange (ETDEWEB)

    Uwaba, Tomoyuki, E-mail: uwaba.tomoyuki@jaea.go.jp [Japan Atomic Energy Agency, 4002, Narita-cho, Oarai-machi, Ibaraki 311-1393 (Japan); Ito, Masahiro; Maeda, Koji [Japan Atomic Energy Agency, 4002, Narita-cho, Oarai-machi, Ibaraki 311-1393 (Japan)

    2011-09-30

    Highlights: > We evaluated diametral strain of fast reactor MOX fuel pins irradiated to 130 GWd/t. > The strain was due to cladding void swelling and irradiation creep. > The irradiation creep was caused by internal gas pressure and PCMI. > The PCMI was associated with pellet swelling by rim structure or by cesium uranate. > The latter effect tended to increase the cumulative damage fraction of the cladding. - Abstract: The C3M irradiation test, which was conducted in the experimental fast reactor, 'Joyo', demonstrated that mixed oxide (MOX) fuel pins with austenitic steel cladding could attain a peak pellet burnup of about 130 GWd/t safely. The test fuel assembly consisted of 61 fuel pins, whose design specifications were similar to those of driver fuel pins of a prototype fast breeder reactor, 'Monju'. The irradiated fuel pins exhibited diametral strain due to cladding void swelling and irradiation creep. The cladding irradiation creep strain were due to the pellet-cladding mechanical interaction (PCMI) as well as the internal gas pressure. From the fuel pin ceramographs and {sup 137}Cs gamma scanning, it was found that the PCMI was associated with the pellet swelling which was enhanced by the rim structure formation or by cesium uranate formation. The PCMI due to cesium uranate, which occurred near the top of the MOX fuel column, significantly affected cladding hoop stress and thermal creep, and the latter effect tended to increase the cumulative damage fraction (CDF) of the cladding though the CDF indicated that the cladding still had some margin to failure due to the creep damage.

  14. Fuel utilization potential in light water reactors with once-through fuel irradiation (AWBA Development Program)

    International Nuclear Information System (INIS)

    Rampolla, D.S.; Conley, G.H.; Candelore, N.R.; Cowell, G.K.; Estes, G.P.; Flanery, B.K.; Duncombe, E.; Dunyak, J.; Satterwhite, D.G.

    1979-07-01

    Current commercial light water reactor cores operate without recylce of fuel, on a once-through fuel cycle. To help conserve the limited nuclear fuel resources, there is interest in increasing the energy yield and, hence, fuel utilization from once-through fuel irradiation. This report evaluates the potential increase in fuel utilization of light water reactor cores operating on a once-through cycle assuming 0.2% enrichment plant tails assay. This evaluation is based on a large number of survey calculations using techniques which were verified by more detailed calculations of several core concepts. It is concluded that the maximum fuel utilization which could be achieved by practical once-through pressurized light water reactor cores with either uranium or thorium is about 17 MWYth/ST U 3 O 8 (Megawatt Years Thermal per Short Ton of U 3 O 8 ). This is about 50% higher than that of current commercial light water reactor cores. Achievement of this increased fuel utilization would require average fuel burnup beyond 50,000 MWD/MT and incorporation of the following design features to reduce parasitic losses of neutrons: reflector blankets to utilize neutrons that would otherwise leak out of the core; fuel management practices in which a smaller fraction of the core is replaced at each refueling; and neutron economic reactivity control, such as movable fuel control rather than soluble boron control. For a hypothetical situation in which all neutron leakage and parasitic losses are eliminated and fuel depletion is not limited by design considerations, a maximum fuel utilization of about 20 MWYth/ST U 3 O 8 is calculated for either uranium or thorium. It is concluded that fuel utilization for comparable reactor designs is better with uranium fuel than with thorium fuel for average fuel depletions of 30,000 to 35,000 MWD/MT which are characteristic of present light water reactor cores

  15. Evolution of fuel rod support under irradiation impact on the mechanical behaviour of fuel assemblies

    International Nuclear Information System (INIS)

    Billerey, Antoine; Waeckel, Nicolas

    2005-01-01

    New fuel management targets imply to increase fuel assembly discharge burnup. Therefore, the prediction of the mechanical behaviour of the irradiated fuel assembly is essential such as excessive fuel assembly distortion induce incomplete Rod Cluster Control Assembly insertion problems (safety issue) or fuel rod vibration induced wear leading to leaking rods (plant operation problems). Within this framework, one of the most important parameter is the knowledge of the fuel rod support in the grid cell because it directly governs the mechanical behaviour of the fuel assembly and consequently allows to predict the behaviour of irradiated structures in terms of (1) axial and lateral deformation (global behaviour of the assembly) and (2) rod vibration induced wear (local behaviour of the rod). Generally, fuel rod support is provided by a spring-dimple system fixed to the grid. During irradiation, the spring force decreases and a gap between the rod and the spring may occur. This phenomenon is due to (1) stress relieving in the spring and in the dimples, (2) grid growth and (3) reduction of the rod diameter. Two models have been developed to predict the behaviour of the rod in the cell. The first model is dedicated to the evaluation of the spring force relaxation during irradiation. The second one can assess the rotation characteristic of the fuel rod in the cell, function of the spring force. The main input parameters are (1) the creep laws of the grid materials, (2) the growth law of the grid, (3) the evolution of rod diameter and (4) the design of the fuel rod support. The aim of this paper is to: (1) evaluate the consequences of grid support design modifications on the rod vibration sensitivity in terms of predicted rod to grid maximum gap during irradiation and time in operation with an open rod to grid gap, (2) evaluate, using a linear or non-linear Finite Element assembly model, the impact of the evolution of grid support under irradiation on the overall mechanical

  16. Method for monitoring irradiated nuclear fuel using cerenkov radiation

    International Nuclear Information System (INIS)

    Caldwell, J.T.; Dowdy, E.J.; Nicholson, N.

    1983-01-01

    A method is provided for monitoring irradiated nuclear fuel inventories located in a water-filled storage pond wherein the intensity of the cerenkov radiation emitted from the water in the vicinity of the nuclear fuel is measured. This intensity is then compared with the expected intensity for nuclear fuel having a corresponding degree of irradiation exposure and time period after removal from a reactor core. Where the nuclear fuel inventory is located in an assembly having fuel pins or rods with intervening voids, the cerenkov light intensity measurement is taken at selected bright spots corresponding to the water-filled interstices of the assembly in the water storage, the waterfilled interstices acting as cerenkov light channels so as to reduce cross-talk. On-line digital analysis of an analog video signal is possible, or video tapes may be used for later measurement using a video editor and an electrometer. Direct measurement of the cerenkov radiation intensity also is possible using spot photometers pointed at the assembly

  17. Microbial biofilm growth on irradiated, spent nuclear fuel cladding

    International Nuclear Information System (INIS)

    Bruhn, D.F.; Frank, S.M.; Roberto, F.F.; Pinhero, P.J.; Johnson, S.G.

    2009-01-01

    A fundamental criticism regarding the potential for microbial influenced corrosion in spent nuclear fuel cladding or storage containers concerns whether the required microorganisms can, in fact, survive radiation fields inherent in these materials. This study was performed to unequivocally answer this critique by addressing the potential for biofilm formation, the precursor to microbial-influenced corrosion, in radiation fields representative of spent nuclear fuel storage environments. This study involved the formation of a microbial biofilm on irradiated spent nuclear fuel cladding within a hot cell environment. This was accomplished by introducing 22 species of bacteria, in nutrient-rich media, to test vessels containing irradiated cladding sections and that was then surrounded by radioactive source material. The overall dose rate exceeded 2 Gy/h gamma/beta radiation with the total dose received by some of the bacteria reaching 5 x 10 3 Gy. This study provides evidence for the formation of biofilms on spent-fuel materials, and the implication of microbial influenced corrosion in the storage and permanent deposition of spent nuclear fuel in repository environments

  18. Durable and Robust Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Hjalmarsson, Per; Knibbe, Ruth; Hauch, Anne

    project had as one of its’ overarching goals to improve durability and robustness of the Danish solid oxide fuel cells. The project focus was on cells and cell components suitable for SOFC operation in the temperature range 600 – 750 °C. The cells developed and/or studied in this project are intended......The solid oxide fuel cell (SOFC) is an attractive technology for the generation of electricity with high efficiency and low emissions. Risø DTU (now DTU Energy Conversion) works closely together with Topsoe Fuel Cell A/S in their effort to bring competitive SOFC systems to the market. This 2-year...... for use within the CHP (Combined Heat and Power) market segment with stationary power plants in the range 1 – 250 kWe in mind. Lowered operation temperature is considered a good way to improve the stack durability since corrosion of the interconnect plates in a stack is lifetime limiting at T > 750 °C...

  19. Prototypic fabrication of TRIGA irradiated fuel shipping casks

    International Nuclear Information System (INIS)

    Kim, B.K.; Lee, Y.W.; Whang, C.K.; Lee, J.B.

    1980-01-01

    This is the safety analysis report on the prototypic fabrication of ''TRIGA Irradiated Fuel Shipping Cask'' conducted by KAERI in 1980. The results of the evaluation show that the shipping cask is in compliance with the applicable regulation for the normal conditions of transport as well as hypothetical accident conditions. The prototypic fabrication of the shipping cask (type B) was carried out for the first time in Korea after getting technical experience from fabrication of the ''TRIGA Spent Fuel Shipping Cask'' and ''the KO-RI Unit 1 surveillance capsule shipping cask'' in 1979. This report contains structural evaluation, thermal evaluation, shielding, criticality, quality assurance, and handling procedures of the shipping cask

  20. Irradiation Experiment Conceptual Design Parameters for NBSR Fuel Conversion

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N. R. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Brown, N. R. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Baek, J. S [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Hanson, A. L. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Cuadra, A. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Cheng, L. Y. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.; Diamond, D. J. [Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.

    2014-04-30

    It has been proposed to convert the National Institute of Standards and Technology (NIST) research reactor, known as the NBSR, from high-enriched uranium (HEU) fuel to low-Enriched uranium (LEU) fuel. The motivation to convert the NBSR to LEU fuel is to reduce the risk of proliferation of special nuclear material. This report is a compilation of relevant information from recent studies related to the proposed conversion using a metal alloy of LEU with 10 w/o molybdenum. The objective is to inform the design of the mini-plate and full-size-Plate irradiation experiments that are being planned. This report provides relevant dimensions of the fuel elements, and the following parameters at steady state: average and maximum fission rate density and fission density, fuel temperature distribution for the plate with maximum local temperature, and two-dimensional heat flux profiles of fuel plates with high power densities. The latter profiles are given for plates in both the inner and outer core zones and for cores with both fresh and depleted shim arms (reactivity control devices). A summary of the methodology to obtain these results is presented. Fuel element tolerance assumptions and hot channel factors used in the safety analysis are also given.

  1. Achievements of Japanese fuel irradiation experiments in HBWR

    International Nuclear Information System (INIS)

    1992-10-01

    OECD NEA Halden Reactor Project started in 1958, and JAERI has been participated in the Project since 1967 on behalf of Japanese Government. During the participation period, not only JAERI but also many Japanese companies and PNC, which cooperated with JAERI, have carried out many irradiation tests of fuel at HBWR. The Committee of the Halden Joint Research Programme was organized by agencies and companies, which joined the cooperative researches, and the committee has worked to promote the cooperative researches. This report summarizes the achievements of the Halden Joint Research Programme on fuel irradiation tests between Jan. 1988 and Dec. 1990., as the Halden Project renews the agreement every three years. Some researches, which have not yet been completed in the period, are also included in this report. (author)

  2. Experimental fuel channel for samples irradiation at the RB reactor

    International Nuclear Information System (INIS)

    Pesic, M.; Markovic, H.; Sokcic-Kostic, M.; Miric, I.; Prokic, M.; Strugar, P.

    1984-12-01

    An 80% enriched UO 2 fuel channel at the RB nuclear reactor in the 'Boris Kidric' Institute of Nuclear Sciences is modified for samples irradiation by fast neutrons. Maximum sample diameter is 25 mm and length up to 1000 mm. Characteristics of neutron and gamma radiation fields of this new experimental channel are investigated. In the centre of the channel, the main contribution to the total neutron absorbed dose, i.e. 0.29 Gy/Wh of reactor operation, is due to the fast neutron spectrum component. Only 0.05 Gy and 0.07 Gy in the total neutron absorbed dose are due to intermediate and thermal neutrons, respectively. At the same time the gamma absorbed dose is 0.35 Gy. The developed experimental fuel channel, EFC, has wide possibilities for utilization, from fast neutron spectrum studies, electronic component irradiations, dosemeters testing, up to cross-section measurements. (author)

  3. Solid Oxide Fuel Cell Systems PVL Line

    International Nuclear Information System (INIS)

    Shearer, Susan; Rush, Gregory

    2012-01-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability to

  4. Oxide glass structure evolution under swift heavy ion irradiation

    International Nuclear Information System (INIS)

    Mendoza, C.; Peuget, S.; Charpentier, T.; Moskura, M.; Caraballo, R.; Bouty, O.; Mir, A.H.; Monnet, I.; Grygiel, C.; Jegou, C.

    2014-01-01

    Highlights: • Structure of SHI irradiated glass is similar to the one of a hyper quenched glass. • D2 Raman band associated to 3 members ring is only observed in irradiated glass. • Irradiated state seems slightly different to an equilibrated liquid quenched rapidly. - Abstract: The effects of ion tracks on the structure of oxide glasses were examined by irradiating a silica glass and two borosilicate glass specimens containing 3 and 6 oxides with krypton ions (74 MeV) and xenon ions (92 MeV). Structural changes in the glass were observed by Raman and nuclear magnetic resonance spectroscopy using a multinuclear approach ( 11 B, 23 Na, 27 Al and 29 Si). The structure of irradiated silica glass resembles a structure quenched at very high temperature. Both borosilicate glass specimens exhibited depolymerization of the borosilicate network, a lower boron coordination number, and a change in the role of a fraction of the sodium atoms after irradiation, suggesting that the final borosilicate glass structures were quenched from a high temperature state. In addition, a sharp increase in the concentration of three membered silica rings and the presence of large amounts of penta- and hexacoordinate aluminum in the irradiated 6-oxide glass suggest that the irradiated glass is different from a liquid quenched at equilibrium, but it is rather obtained from a nonequilibrium liquid that is partially relaxed by very rapid quenching within the ion tracks

  5. Irradiation behavior of uranium-silicide dispersion fuels

    International Nuclear Information System (INIS)

    Hofman, G.L.; Neimark, L.A.

    1984-01-01

    This paper describes and analyzes the irradiation behavior of experimental fuel plates containing U 3 Si, U 3 Si-1.5 w/o Al, and U 3 Si 2 particulate fuel dispersed and clad in aluminum. The fuel is nominally 19.9%-enriched 235 U and the fuel volume fraction in the central ''meat'' section of the plates is approximately 33%. Sets of fuel plates were removed from the Oak Ridge Research reactor at burnup levels of 35, 83, and 94% 235 U depletion and examined at the Alpha-Gamma Hot-Cell Facility at Argonne National Laboratory. The results of the examination may be summarized as follows. The dimensional stability of the U 3 Si 2 and pure U 3 Si fuel was excellent throughout the entire burnup range, with uniform plate thickness increases up to a maximum of 4 mils at the highest burnup level (94% 235 U depletion). This corresponds to a meat volume increase of 11%. The swelling was partially due to solid fission products but to a larger extent to fission gas bubbles. The fission gas bubbles in U 3 Si 2 were small (submicrometer size) and very uniformly distributed, indicating great stability. To a large extent this was also the case for U 3 Si; however, larger bubbles ( 3 Si-1.5 w/o Al fuel became unstable at the higher burnup levels. Fission gas bubbles were larger than in the other two fuels and were present throughout the fuel particles. At 94% 235 U depletion, the formation of fission gas bubbles with diameters up to 20 mils caused the plates to pillow. It is proposed that aluminum in U 3 Si destabilizes fission gas bubble formation to the point of severe breakaway swelling in the prealloyed silicide fuel. (author)

  6. Efficient Biomass Fuel Cell Powered by Sugar with Photo- and Thermal-Catalysis by Solar Irradiation.

    Science.gov (United States)

    Liu, Wei; Gong, Yutao; Wu, Weibing; Yang, Weisheng; Liu, Congmin; Deng, Yulin; Chao, Zi-Sheng

    2018-06-19

    The utilization of biomass sugars has received great interesting recently. Herein, we present a highly efficient hybrid solar biomass fuel cell that utilizes thermal- and photocatalysis of solar irradiation and converts biomass sugars into electricity with high power output. The fuel cell uses polyoxometalates (POMs) as photocatalyst to decompose sugars and capture their electrons. The reduced POMs have strong visible and near-infrared light adsorption, which can significantly increase the temperature of the reaction system and largely promotes the thermal oxidation of sugars by the POM. In addition, the reduced POM functions as charge carrier that can release electrons at the anode in the fuel cell to generate electricity. The electron-transfer rates from glucose to POM under thermal and light-irradiation conditions were investigated in detail. The power outputs of this solar biomass fuel cell are investigated by using different types of sugars as fuels, with the highest power density reaching 45 mW cm -2 . © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Irradiation performance of PFBR MOX fuel after 112 GWd/t burn-up

    Energy Technology Data Exchange (ETDEWEB)

    Venkiteswaran, C.N., E-mail: cnv@igcar.gov.in; Jayaraj, V.V.; Ojha, B.K.; Anandaraj, V.; Padalakshmi, M.; Vinodkumar, S.; Karthik, V.; Vijaykumar, Ran; Vijayaraghavan, A.; Divakar, R.; Johny, T.; Joseph, Jojo; Thirunavakkarasu, S.; Saravanan, T.; Philip, John; Rao, B.P.C.; Kasiviswanathan, K.V.; Jayakumar, T.

    2014-06-01

    The 500 MWe Prototype Fast Breeder Reactor (PFBR) which is in advanced stage of construction at Kalpakkam, India, will use mixed oxide (MOX) fuel with a target burnup of 100 GWd/t. The fuel pellet is of annular design to enable operation at a peak linear power of 450 W/cm with the requirement of minimum duration of pre-conditioning. The performance of the MOX fuel and the D9 clad and wrapper material was assessed through Post Irradiation Examinations (PIE) after test irradiation of 37 fuel pin subassembly in Fast Breeder Test Reactor (FBTR) to a burn-up of 112 GWd/t. Fission product distribution, swelling and fuel–clad gap evolution, central hole diameter variation, restructuring, fission gas release and clad wastage due to fuel–clad chemical interaction were evaluated through non-destructive and destructive examinations. The examinations have indicated that the MOX fuel can safely attain the desired target burn-up in PFBR.

  8. Equipment for detach the fuel elements of the irradiated candu fuel bundle

    International Nuclear Information System (INIS)

    Cojocaru, V.; Dinuta, G.

    2013-01-01

    Monitoring the behaviour of the fuel bundles during their combustion provides useful information for the operation of the nuclear power plant as well as for the fuel manufacturer. Before placing it inside the reactor, the fuel bundle is inspected visually, dimensionally and, during combustion in the reactor, its radioactive behaviour is monitored. The purpose of the presented equipment is to allow the visual external inspection of the damaged fuel bundle in order to identify visible defects and to detach the fuel element by breaking the welded connection between the cap and grid. These devices are operated using the handler devices already existing in the hot cells Post-Irradiation Examination Laboratory (LEPI). This equipment has been used successfully in the LEPI laboratory at SCN Pitesti to inspect the damaged fuel from Cernavoda NPP, in March 2013. (authors)

  9. American proposals for long range storage of irradiated fuel

    International Nuclear Information System (INIS)

    Sugier, Annie

    1978-01-01

    The American politics of irradiated fuel management is reviewed, the short-range storage of huge amounts of wastes being the fundamental problem. Two steps are considered: the ''At the Reactor'' storage, ensured by the electricity companies, and the ''Away From Reactor'' storage on the DOE's responsibility. A technical and economical study has been carried out in order to estimate the cost of the AFR provisory storage and a project of taxation has been established on this basis [fr

  10. The permission of transport of irradiated nuclear fuel elements

    International Nuclear Information System (INIS)

    Klomberg, T.J.M.

    2000-01-01

    In July and October 2000 the Dutch government granted permits for the transportation of irradiated nuclear fuel elements. The environmental organization Greenpeace objected against the permit, but that was rejected by the Dutch Council of State. A brief overview is given of the judgements and the state-of-the-art with respect to the transportation of the elements from Dutch reactors and storage facilities in Petten, Dodewaard and Borssele to Cogema in La Hague, France and BNFL in Sellafield, England

  11. American proposals for long range storage of irradiated fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sugier, A [CEA, 75 - Paris (France). Dept. des Programmes

    1978-12-01

    The American politics of irradiated fuel management is reviewed, the short-range storage of huge amounts of wastes being the fundamental problem. Two steps are considered: the ''At the Reactor'' storage, ensured by the electricity companies, and the ''Away From Reactor'' storage on the DOE's responsibility. A technical and economical study has been carried out in order to estimate the cost of the AFR provisory storage and a project of taxation has been established on this basis.

  12. Post irradiation examinations of uranium-plutonium mixed carbide fuels irradiated at low linear power rate

    International Nuclear Information System (INIS)

    Maeda, Atsushi; Sasayama, Tatsuo; Iwai, Takashi; Aizawa, Sakuei; Ohwada, Isao; Aizawa, Masao; Ohmichi, Toshihiko; Handa, Muneo

    1988-11-01

    Two pins containing uranium-plutonium carbide fuels which are different in stoichiometry, i.e. (U,Pu)C 1.0 and (U,Pu)C 1.1 , were constructed into a capsule, ICF-37H, and were irradiated in JRR-2 up to 1.0 at % burnup at the linear heat rate of 420 W/cm. After being cooled for about one year, the irradiated capsule was transferred to the Reactor Fuel Examination Facility where the non-destructive examinations of the fuel pins in the β-γ cells and the destructive ones in two α-γ inert gas atmosphere cells were carried out. The release rates of fission gas were low enough, 0.44 % from (U,Pu)C 1.0 fuel pin and 0.09% from (U,Pu)C 1.1 fuel pin, which is reasonable because of the low central temperature of fuel pellets, about 1000 deg C and is estimated that the release is mainly governed by recoil and knock-out mechanisms. Volume swelling of the fuels was observed to be in the range of 1.3 ∼ 1.6 % for carbide fuels below 1000 deg C. Respective open porosities of (U,Pu)C 1.0 and (U,Pu)C 1.1 fuel were 1.3 % and 0.45 %, being in accordance with the release behavior of fission gas. Metallographic observation of the radial sections of pellets showed the increase of pore size and crystal grain size in the center and middle region of (U,Pu)C 1.0 pellets. The chemical interaction between fuel pellets and claddings in the carbide fuels is the penetration of carbon in the fuels to stainless steel tubes. The depth of corrosion layer in inner sides of cladding tubes ranged 10 ∼ 15 μm in the (U,Pu)C 1.0 fuel and 15 #approx #25 μm in the (U,Pu)C 1.1 fuel, which is correlative with the carbon potential of fuels posibly affecting the amount of carbon penetration. (author)

  13. Irradiation performance of HTGR fuel in HFIR experiment HRB-13

    International Nuclear Information System (INIS)

    Tiegs, T.N.

    1982-03-01

    Irradiation capsule HRB-13 tested High-Temperature Gas-Cooled Reactor (HTGR) fuel under accelerated conditions in the High Flux Isotope Reactor (HFIR) at ORNL. The ORNL part of the capsule was designed to provide definitive results on how variously misshapen kernels affect the irradiation performance of weak-acid-resin (WAR)-derived fissile fuel particles. Two batches of WAR fissile fuel particles were Triso-coated and shape-separated into four different fractions according to their deviation from spericity, which ranged from 9.6 to 29.7%. The fissile particles were irradiated for 7721 h. Heavy-metal burnups ranged from 80 to 82.5% FIMA (fraction of initial heavy-metal atoms). Fast neutron fluences (>0.18 MeV) ranged from 4.9 x 10 25 neutrons/m 2 to 8.5 x 10 25 neutrons/m 2 . Postirradiation examination showed that the two batches of fissile particles contained chlorine, presumably introduced during deposition of the SiC coating

  14. Technique of manufacturing specimen of irradiated fuel rods

    International Nuclear Information System (INIS)

    Min, Duck Seok; Seo, Hang Seok; Min, Duck Kee; Koo, Dae Seo; Lee, Eun Pyo; Yang, Song Yeol

    1999-04-01

    Technique of manufacturing specimen of irradiated fuel rods to perform efficient PIE is developed by analyzing the relation between requiring time of manufacturing specimen and manufacturing method in irradiated fuel rods. It takes within an hour to grind 1 mm of specimen thickness under 150 rpm in speed of grinding, 600 g gravity in force using no.120, no.240, no.320 of grinding paper. In case of no.400 of grinding paper, it takes more an hour to grind the same thickness as above. It takes up to a quarter to grind 80-130 μm in specimen thickness using no.400 of grinding paper. When grinding time goes beyond 15 minutes, the grinding thickness of specimen does not exist. The polishing of specimen with 150 Rpms in speed of grinding machine, 600 g gravity in force, 10 minutes in polishing time using diamond paste 15 μm on polishing cloths amounts to 50 μm in specimen thickness. In case of diamond paste 9 μm on polishing cloth, the polishing of specimen amounts to 20 μm. The polishing thickness of specimen with 15 minutes in polishing time using 6 μm, 3 μm, 1 μm, 1/4 μm does not exist. Technique of manufacturing specimen of irradiated fuel rods will have application to the destructive examination of PIE. (author). 6 refs., 1 tab., 10 figs

  15. Tubular solid oxide fuel cell development program

    Energy Technology Data Exchange (ETDEWEB)

    Ray, E.R.; Cracraft, C.

    1995-12-31

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  16. Solid oxide fuel cell field trial evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Wilcox, C.P.; Winstanley, R.; Nietsch, T.; Smith, C.; Knight, R.; Seymore, C.

    2000-07-01

    This report focuses on issues relating to a field trial of a solid oxide fuel cell (SOFC). Aspects examined include markets for SOFC systems, the choice of systems for demonstration in year 2002, the assessment of industrial interest, and evaluation and ranking of candidate systems. The identification and evaluation of interest in field trials, the estimation of the capital and running costs of a field trial, and identification of the benefits to the UK and barriers to implementation of SOFC systems are discussed. (UK)

  17. Advances in the manufacturing and irradiation of reduced enrichment fuels for canadian research reactors

    International Nuclear Information System (INIS)

    Wood, J.C.; Foo, M.T.; Berthiaume, L.C.; Herbert, L.N.; Schaefer, J.D.

    1984-01-01

    The procedures for manufacturing fuel rods of uranium silicide dispersed in aluminum and clad in aluminum have been optimized to maximize production rates while minimizing scrap losses. Melting and casting, chip machining and core extrusion have all been re-evaluated to improve their efficiency and significant gains have been made, whilst maintaining high quality standards. The results of our irradiation program on mini-elements up to a burnup of 80 atomic percent continue to be encouraging. The upper bound curve of fuel core swelling versus burnup in the range 0-80 atomic percent represents 1% swelling per 10 atomic percent burnup. Fuel core swelling has now been measured directly on six mini-elements from which the clad surface oxide had been removed showing that previous calculated values of core swelling were marginally conservative. (author)

  18. Spent oxide fuel regeneration by crystallization in molybdate melts

    International Nuclear Information System (INIS)

    Ustinov, O.A.; Sukhanov, L.P.; Yakunin, S.A.

    2006-01-01

    Paper describes a procedure to regenerate spent oxide fuel by its crystallization in molybdate melts. Paper presents the process procedures to regenerate spent fuel of both fast and thermal neutron reactors. One analyzes the advantages of the elaborated procedure [ru

  19. Evolution of fuel rod support under irradiation consequences on the mechanical behavior of fuel assembly

    International Nuclear Information System (INIS)

    Billerey, A.; Bouffioux, P.

    2002-01-01

    The complete paper follows. According to the fuel management policy in French PWR with respect to high burn-up, the prediction of the mechanical behavior of the irradiated fuel assembly is required as far as excessive deformations of fuel assembly might lead to incomplete Rod Cluster Control Assembly insertion (safety problems) and fretting wear lead to leaking rods (plant operation problems). One of the most important parameter is the evolution of the fuel rod support in the grid cell as it directly governs the mechanical behavior of the fuel assembly and consequently allows to predict the behavior of irradiated structure in terms of (i) axial and lateral deformation (global behavior of the assembly) and (ii) fretting wear (local behavior of the rod). Fuel rod support is provided by a spring-dimple system fixed on the grid. During irradiation, the spring force decreases and a gap between the rod and the spring might open. This phenomenon is due to (i) irradiation-induced stress relaxation for the spring and for the dimples, (ii) grid growth and (iii) reduction of rod diameter. Two models have been developed to predict the behavior of the rod in the grid cell. The first model is able to evaluate the spring force relaxation during irradiation. The second one is able to evaluate the rotation characteristic of the fuel rod in the cell, function of the spring force. The main input parameters are (i) the creep laws of the grid materials, (ii) the growth law of the grid, (iii) the evolution of rod diameter and (iv) the design of the fuel rod support. The objectives of this paper are to: (i) evaluate the consequences of grid support design modifications on the fretting sensitivity in terms of predicted maximum gap during irradiation and operational time to gap appearance; (ii) evaluate, using a non-linear Finite Element assembly model, the impact of the evolution of grid support under irradiation on the mechanical behavior of the full assembly in terms of axial and

  20. Measurement and analysis of transient vaporization in oxide fuel materials

    International Nuclear Information System (INIS)

    Benson, D.A.; Bergeron, E.G.

    1979-01-01

    This paper describes a series of experiments in which samples are heated to produce high vapor pressure states in times of 10 -6 to 10 -3 seconds. Experimental measurements of vapor pressures over fresh UO 2 from the pulsed electron beam and pulsed reactor heating tests are presented and compared with other high temperature data. The interpretation of the vapor pressure measured in the tests is discussed in detail. Effects of original sample stoichiometry, chemical interactions with the container and non-equilibrium evaporation due to induced temperature gradients are discussed. Special attention is given to dynamic behavior in rapid heating and vaporization of the oxide due to chemical non-equilibrium. Finally, similar projected reactor experiments on irradiated fuel are described and vapor pressure predictions made using available equilibrium models. A discussion of information accessible from such future tests and its importance is presented. (orig.) [de

  1. Measurement and analysis of transient vaporization in oxide fuel materials

    International Nuclear Information System (INIS)

    Gorham-Bergeron, E.; Benson, D.A.

    1978-01-01

    A series of experiments is described in which samples are heated to produce high vapor pressure states in times of 10 -6 to 10 -3 seconds. Experimental measurements of vapor pressures over fresh UO 2 from the pulsed electron beam and pulsed reactor heating tests are presented and compared with other high temperature data. The interpretation of the vapor pressures measured in the tests is discussed in detail. Effects of original sample stoichiometry, chemical interactions with the container and non-equilibrium evaporation due to induced temperature gradients are discussed. Special attention is given to dynamic behavior in rapid heating and vaporization of the oxide due to chemical nonequilibrium. Finally, similar projected reactor experiments on irradiated fuel are described and vapor pressure predictions made using available equilibrium models. A discussion of information accessible from such future tests and its importance is presented

  2. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Coffey, G.W.; Pederson, L.R. [Pacific Northwest National Lab., Richland, WA (United States)] [and others

    1996-08-01

    Chromite interconnection materials in an SOFC are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. Because such conditions could lead to component failure, the authors have evaluated thermal, electrical, chemical, and structural stabilities of these materials as a function of temperature and oxygen partial pressure. The crystal lattice of the chromites was shown to expand for oxygen partial pressures smaller than 10{sup {minus}10} atm, which could lead to cracking and debonding in an SOFC. Highly substituted lanthanum chromite compositions were the most susceptible to lattice expansion; yttrium chromites showed better dimensional stability by more than a factor of two. New chromite compositions were developed that showed little tendency for lattice expansion under strongly reducing conditions, yet provided a good thermal expansion match to other fuel cell components. Use of these new chromite interconnect compositions should improve long-term SOFC performance, particularly for planar cell configurations. Thermodynamic properties of substituted lanthanum manganite cathode compositions have been determined through measurement of electromotive force as a function of temperature. Critical oxygen decomposition pressures for Sr and Ca-substituted lanthanum manganites were established using cells based on a zirconia electrolyte. Strontium oxide and calcium oxide activities in a lanthanum manganite matrix were determined using cells based on strontium fluoride and calcium fluoride electrolytes, respectively. The compositional range of single-phase behavior of these ABO{sub 3}-type perovskites was established as a function of A/B cation ratios and the extent of acceptor doping. Before this work, very little thermodynamic information was in existence for substituted manganite compositions. Such information is needed to predict the long-term stability of solid oxide fuel cell assemblies.

  3. Development of solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Dae Kab; Kim, Sun Jae; Jung, Choong Hwan; Kim, Kyung Hoh; Park, Ji Yun; Oh, Suk Jin [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-01-01

    Solid Oxide Fuel Cell (SOFC) technologies that use zirconium oxide as the electrolyte material were studied in this present report. SOFC exhibits a very high power generation efficiency of over 50 %, and does not discharge pollution materials such as dusts, sulfur dioxide, and nitrogen oxide. Zirconia, Ni/YSZ (yttria stabilized zirconia), and La-Sr-Mn-Oxide materials were developed for the electrolyte material, for the anode, and for the cathode, respectively. After making thin zirconia plate using tape casting process, anode and cathode powders were screen printed on the zirconia plate for fabricating unit cells. A test system composed of a vertical tube furnace, digital multimeter, DC current supplier, and measuring circuit was constructed for testing the unit cell performance. This system was controlled by a home-made computer program. Founded on this unit cell technology and system, a multi-stack SOFC system was studied. This system was composed of 10 unit cells each of them had an electrode area of 40 x 40 mm. Based on this system design, large and thin zirconia plates of 70 x 70 mm in area was fabricated for the electrolyte. Different from in the unit cell system, interconnectors are needed in the multi-stack system for connecting unit cells electrically. For this interconnectors, Inconel 750 alloy was selected, sliced into wafers, machined, surface finished, and then Pt-plated. 55 figs, 8 tabs, 51 refs. (Author).

  4. Development of solid oxide fuel cell technology

    International Nuclear Information System (INIS)

    Kang, Dae Kab; Kim, Sun Jae; Jung, Choong Hwan; Kim, Kyung Hoh; Park, Ji Yun; Oh, Suk Jin

    1995-01-01

    Solid Oxide Fuel Cell (SOFC) technologies that use zirconium oxide as the electrolyte material were studied in this present report. SOFC exhibits a very high power generation efficiency of over 50 %, and does not discharge pollution materials such as dusts, sulfur dioxide, and nitrogen oxide. Zirconia, Ni/YSZ (yttria stabilized zirconia), and La-Sr-Mn-Oxide materials were developed for the electrolyte material, for the anode, and for the cathode, respectively. After making thin zirconia plate using tape casting process, anode and cathode powders were screen printed on the zirconia plate for fabricating unit cells. A test system composed of a vertical tube furnace, digital multimeter, DC current supplier, and measuring circuit was constructed for testing the unit cell performance. This system was controlled by a home-made computer program. Founded on this unit cell technology and system, a multi-stack SOFC system was studied. This system was composed of 10 unit cells each of them had an electrode area of 40 x 40 mm. Based on this system design, large and thin zirconia plates of 70 x 70 mm in area was fabricated for the electrolyte. Different from in the unit cell system, interconnectors are needed in the multi-stack system for connecting unit cells electrically. For this interconnectors, Inconel 750 alloy was selected, sliced into wafers, machined, surface finished, and then Pt-plated. 55 figs, 8 tabs, 51 refs. (Author)

  5. The reprocessing of irradiated fuels by halides and their compounds

    International Nuclear Information System (INIS)

    Bourgeois, M.; Faugeras, P.

    1964-01-01

    A brief description is given of the experiments leading to the choice of the process volatilization of fluorides by gas phase attack. The chemical process is described for certain current types of clad Fuels: the aluminium or the zirconium cladding is first volatilized as chloride by attack with gaseous hydrogen chloride. The uranium is then transformed into volatile hexafluoride by attack with fluorine. These reactions are carried out consecutively in the same reactor in the presence of a fluidized bed of alumina which facilitates heat exchange. The experiments have been carried out in quantities from 100 gms to several kilograms of fuel, first without activity, and then with tracers. A description is given of the laboratory research which was carried out simultaneously on the separation of uranium and plutonium fluorides. Finally, an apparatus is described which is intended to test the process on irradiated fuel at an activity level of several thousands of curies of fission products. (authors) [fr

  6. Test requirement for PIE of HANARO irradiated fuel rod

    International Nuclear Information System (INIS)

    Lim, I. C.; Cho, Y. G.

    2000-06-01

    Since the first criticality of HANARO reached in Feb. of 1995, the rod type U 3 Si-A1 fuel imported from AECL has been used. From the under-water fuel inspection which has been conducted since 1997, a ballooning-rupture type abnormality was observed in several fuel rods. In order to find the root cause of this abnormality and to find the resolution, the post irradiation examination(PIE) was proposed as the best way. In this document, the information from the under-water inspection as well as the PIE requirements are described. Based on the information in this document, a detail test plan will be developed by the project team who shall conduct the PIE

  7. Electron trapping during irradiation in reoxidized nitrided oxide

    International Nuclear Information System (INIS)

    Mallik, A.; Vasi, J.; Chandorkar, A.N.

    1993-01-01

    Isochronal detrapping experiments have been performed following irradiation under different gate biases in reoxidized nitrided oxide (RNO) MOS capacitors. These show electron trapping by the nitridation-induced electron traps at low oxide fields during irradiation. A difference in the detrapping behavior of trapped holes and electrons is observed, with trapped holes being detrapped at relatively lower temperatures compared to trapped electrons. Electron trapping shows a strong dependence on tile magnitude of the applied gate bias during irradiation but is independent of its polarity. Conventional oxide devices, as expected, do not show any electron trapping during irradiation by the native electron traps. Finally, a comparison of the isochronal detrapping behavior following irradiation and following avalanche injection of electrons has been made to estimate the extent of electron trapping. The results show that electron trapping by the nitridation-induced electron traps does not play the dominant role in improving radiation performance of RNO, though its contribution cannot be completely neglected for low oxide field irradiations

  8. Experimental irradiation of UMo fuel: Pie results and modeling of fuel behaviour

    International Nuclear Information System (INIS)

    Languille, A.; Plancq, D.; Huet, F.; Guigon, B.; Lemoine, P.; Sacristan, P.; Hofman, G.; Snelgrove, J.; Rest, J.; Hayes, S.; Meyer, M.; Vacelet, H.; Leborgne, E.; Dassel, G.

    2002-01-01

    Seven full-sized U Mo plates containing ca. 8 g/cm 3 of uranium in the fuel meat have been irradiated since the beginning of the French U Mo development program. The first three of them with 20% 235 U enrichment were irradiated at maximum surfacic power under 150 W/cm 2 in the OSIRIS reactor up to 50% burn-up and are under examination. Their global behaviour is satisfactory: no failure and a low swelling. The other four plates were irradiated in the HFR Petten at maximum surfacic power between 150 and 250 W/cm 2 with two enrichments 20 and 35%. The experiment was stopped after two cycles due to a fuel failure. The post- irradiation examinations were completed in 2001 in Petten. Examinations showed a correct behaviour of 20% enriched plates and an abnormal behaviour of the two other plates (35%-enriched) with a clad failure on the plate 4. The fuel failure appears to result from a combination of factors that led to high corrosion cladding and high fuel meat temperatures. (author)

  9. Method for the chemical reprocessing of irradiated nuclear fuels, in particular nuclear fuels containing uranium

    International Nuclear Information System (INIS)

    Koch, G.

    1976-01-01

    In the chemical processing of irradiated uranium-containing nuclear fuels which are hydrolyzed with aqueous nitric acid, a suggestion is made to use as quaternary ammonium nitrate trialkyl-methyl ammonium nitrates as extracting agent, in which the sum of C atoms is greater than 16. In the illustrated examples, tricaprylmethylammonium nitrate, trilaurylmethylammonium nitrate and tridecylmethylammonium nitrate are named. (HPH/LH) [de

  10. Medium-temperature solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Maffei, N.; Kuriakose, A.K. [Natural Resources Canada, Ottawa, ON (Canada). Materials Technology Lab

    2000-07-01

    The Materials Technology Laboratory (MTL) of Natural Resources Canada has been conducting research on the development of a solid oxide fuel cell (SOFC) for the past decade. Fuel cells convert chemical energy directly into electric energy in an efficient and environmentally friendly manner. SOFCs are considered to be good stationary power sources for commercial and residential applications and will likely be commercialized in the near future. The research at MTL has focused on the development of new electrolytes for use in SOFCs. In the course of this research, monolithic planar single cell SOFCs based on doubly doped ceria and lanthanum gallate have been fabricated and tested at 700 degrees C. This paper compared the performance characteristics of both these systems. The data suggested the presence of a significant electronic conductivity in the SOFC incorporating doubly doped ceria, resulting in lower than expected voltage output. The stability of the SOFC, however, did not appear to be negatively affected. The lanthanum gallate based SOFC performed well. It was concluded that reducing the operating temperature of SOFCs would improve their reliability and enhance their operating life. First generation commercial SOFCs will use a zirconium oxide-based electrolytes while second generation units might possibly use ceria-based and/or lanthanum gallate electrolytes. 24 refs., 6 figs.

  11. Design and manufacturing of 05F-01K instrumented capsule for nuclear fuel irradiation in Hanaro

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, J. M.; Shin, Y. T.; Park, S. J. (and others)

    2007-07-15

    An instrumented capsule was developed to be able to measure fuel characteristics, such as fuel temperature, internal pressure of fuel rod, fuel pellet elongation, and neutron flux, etc., during the irradiation test of nuclear fuel in Hanaro. The instrumented capsule(02F-11K) for measuring and monitoring and monitoring fuel centerline temperature and neutron flux was designed and manufactured. It was successfully irradiated in the test hole OR5 of Hanaro from March 14, 2003 to June 1, 2003 (53.84 full power days at 24 MW). In the year of 2004, 3 test fuel rods and the instrumented capsule(03F-05K) were designed and manufactured to measure fuel centerline temperature, internal pressure of fuel rod, and fuel axial deformation during irradiation test. This capsule was irradiated in the test hole OR5 of Hanaro reactor from April 26, 2004 to October 1, 2004 (59.5 EFPD at 24 {approx} 30 MW). The six typed dual instrumented fuel rods, which allow for two characteristics to be measured simultaneously in one fuel rod, have been designed and manufactured to enhance the efficiency of the irradiation test using the instrumented fuel capsule. The 05F-01K instrumented fuel capsule was designed and manufactured for a design verification test of the three dual instrumented fuel rods. The irradiation test of the 05F-01K instrumented fuel capsule will be carried out at the OR5 vertical experimental hole of Hanaro.

  12. Addressing fuel recycling in solid oxide fuel cell systems fed by alternative fuels

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2017-01-01

    An innovative study on anode recirculation in solid oxide fuel cell systems with alternative fuels is carried out and investigated. Alternative fuels under study are ammonia, pure hydrogen, methanol, ethanol, DME and biogas from biomass gasification. It is shown that the amount of anode off......%. Furthermore, it is founded that for the case with methanol, ethanol and DME then at high utilization factors, low anode recirculation is recommended while at low utilization factors, high anode recirculation is recommended. If the plant is fed by biogas from biomass gasification then for each utilization...

  13. Integrated analysis of oxide nuclear fuel sintering

    International Nuclear Information System (INIS)

    Baranov, V.; Kuzmin, R.; Tenishev, A.; Timoshin, I.; Khlunov, A.; Ivanov, A.; Petrov, I.

    2011-01-01

    Dilatometric and thermal-gravimetric investigations have been carried out for the sintering process of oxide nuclear fuel in gaseous Ar - 8% H 2 atmosphere at temperatures up to 1600 0 C. The pressed compacts were fabricated under real production conditions of the OAO MSZ with application of two different technologies, so called 'dry' and 'wet' technologies. Effects of the grain size growth after the heating to different temperatures were observed. In order to investigate the effects produced by rate of heating on properties of sintered fuel pellets, the heating rates were varied from 1 to 8 0 C per minute. Time of isothermal overexposure at maximal temperature (1600 0 C) was about 8 hours. Real production conditions were imitated. The results showed that the sintering process of the fuel pellets produced by two technologies differs. The samples sintered under different heating rates were studied with application of scanning electronic microscopy analysis for determination of mean grain size. A simulation of heating profile for industrial furnaces was performed to reduce the beam cycles and estimate the effects of variation of the isothermal overexposure temperatures. Based on this data, an optimization of the sintering conditions was performed in operations terms of OAO MSZ. (authors)

  14. Spent fuels conditioning and irradiated nuclear fuel elements examination: the STAR facility and its abilities

    Energy Technology Data Exchange (ETDEWEB)

    Boussard, F.; Huillery, R. [CEA Centre d`Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. d`Etudes des Combustibles; Averseng, J.L.; Serpantie, J.P. [Novatome Industries, 92 - Le Plessis-Robinson (France)

    1994-12-31

    This paper is a presentation of the STAR facility, a high activity laboratory located in Cadarache Nuclear Research Center (France). The purpose of the STAR facility and of the associated processes, is the treatment, cleaning and conditioning of spent fuels from Gas Cooled Reactors (GCR) and in particular of about 2300 spent GCR fuel cartridges irradiated more than 20 years ago in Electricite de France (EDF) or CEA Uranium Graphite GCR. The processes are: to separate the nuclear fuel from the clad remains, to chemically stabilize the nuclear material and to condition it in sealed canisters. An additional objective of STAR consists in non-destructive or destructive examinations and tests on PWR rods or FBR pins in the frame of fuel development programs. The paper describes the STAR facility conceptual design (safety design rules, hot cells..) and the different options corresponding to the GCR reconditioning process and to further research and development works on various fuel types. (J.S.). 3 figs.

  15. Spent fuels conditioning and irradiated nuclear fuel elements examination: the STAR facility and its abilities

    International Nuclear Information System (INIS)

    Boussard, F.; Huillery, R.

    1994-01-01

    This paper is a presentation of the STAR facility, a high activity laboratory located in Cadarache Nuclear Research Center (France). The purpose of the STAR facility and of the associated processes, is the treatment, cleaning and conditioning of spent fuels from Gas Cooled Reactors (GCR) and in particular of about 2300 spent GCR fuel cartridges irradiated more than 20 years ago in Electricite de France (EDF) or CEA Uranium Graphite GCR. The processes are: to separate the nuclear fuel from the clad remains, to chemically stabilize the nuclear material and to condition it in sealed canisters. An additional objective of STAR consists in non-destructive or destructive examinations and tests on PWR rods or FBR pins in the frame of fuel development programs. The paper describes the STAR facility conceptual design (safety design rules, hot cells..) and the different options corresponding to the GCR reconditioning process and to further research and development works on various fuel types. (J.S.). 3 figs

  16. Microscopic analysis of irradiated AGR-1 coated particle fuel compacts

    Energy Technology Data Exchange (ETDEWEB)

    Ploger, Scott A., E-mail: scott.ploger@inl.gov [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3855 (United States); Demkowicz, Paul A. [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3855 (United States); Hunn, John D.; Kehn, Jay S. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831-6093 (United States)

    2014-05-01

    The AGR-1 experiment involved irradiation of 72 TRISO-coated particle fuel compacts to a peak compact-average burnup of 19.5% FIMA with no in-pile failures observed out of 3 × 10{sup 5} total particles. Irradiated AGR-1 fuel compacts have been cross-sectioned and analyzed with optical microscopy to characterize kernel, buffer, and coating behavior. Six compacts have been examined, spanning a range of irradiation conditions (burnup, fast fluence, and irradiation temperature) and including all four TRISO coating variations irradiated in the AGR-1 experiment. The cylindrical specimens were sectioned both transversely and longitudinally, then polished to expose from 36 to 79 individual particles near midplane on each mount. The analysis focused primarily on kernel swelling and porosity, buffer densification and fracturing, buffer–IPyC debonding, and fractures in the IPyC and SiC layers. Characteristic morphologies have been identified, 981 particles have been classified, and spatial distributions of particle types have been mapped. No significant spatial patterns were discovered in these cross sections. However, some trends were found between morphological types and certain behavioral aspects. Buffer fractures were found in 23% of the particles, and these fractures often resulted in unconstrained kernel protrusion into the open cavities. Fractured buffers and buffers that stayed bonded to IPyC layers appear related to larger pore size in kernels. Buffer–IPyC interface integrity evidently factored into initiation of rare IPyC fractures. Fractures through part of the SiC layer were found in only four classified particles, all in conjunction with IPyC–SiC debonding. Compiled results suggest that the deliberate coating fabrication variations influenced the frequencies of IPyC fractures and IPyC–SiC debonds.

  17. The irradiation performance of austenitic stainless steel clade PWR fuel rods

    International Nuclear Information System (INIS)

    Teixeira e Silva, A.; Esteves, A.M.

    1988-01-01

    The steady state irradiation performance of austenitic stainless steel clad pressurized water reactor fuel rods is modeled with fuel performance codes of the FRAP series. These codes, originally developed to model the thermal-mechanical behavior of zircaloy clad fuel rods, are modified to model stainless steel clad fuel rods. The irradiation thermal-mechanical behavior of type 348 stainless steel and zircaloy fuel rods is compared. (author) [pt

  18. Technical specification: Mixed-oxide pellets for the light-water reactor irradiation demonstration test

    International Nuclear Information System (INIS)

    Cowell, B.S.

    1997-06-01

    This technical specification is a Level 2 Document as defined in the Fissile Materials Disposition Program Light-Water Reactor Mixed-oxide Fuel Irradiation Test Project Plan. It is patterned after the pellet specification that was prepared by Atomic Energy of Canada, Limited, for use by Los Alamos National Laboratory in fabrication of the test fuel for the Parallex Project, adjusted as necessary to reflect the differences between the Canadian uranium-deuterium reactor and light-water reactor fuels. This specification and the associated engineering drawing are to be utilized only for preparation of test fuel as outlined in the accompanying Request for Quotation and for additional testing as directed by Oak Ridge National Laboratory or the Department of Energy

  19. Power ramp tests of MOX fuel rods. HBWR irradiation with the instrument rig, IFA-591

    International Nuclear Information System (INIS)

    Ozawa, Takayuki; Abe, Tomoyuki

    2006-03-01

    Plutonium-uranium mixed oxide (MOX) fuel rods of instrumental rig IFA-591 were ramped in HBWR to study the Advanced Thermal Reactor (ATR) MOX fuel behavior during transient operation and to determine a failure threshold of the MOX fuel rods. Eleven segments were base-irradiated in ATR 'FUGEN' up to 18.4 GWd/t. Zirconium liner claddings were adopted for four segments of them. As the results of non-destructive post irradiation examinations (PIEs) after the base-irradiation and before the ramp tests, no remarkable behavior affecting the integrity of fuel assembly and fuel rod was confirmed. All segments to be used for the ramp tests, which consisted of the multi-step ramp tests and the single-step ramp tests, had instrumentations for in-pile measurements of cladding elongation or plenum pressure, and heated up to the maximum linear power of 58.3-68.4 kW/m without failure. The major results of ramp tests are as follows: There is no difference in PCMI behaviors between two type rods of Zry-2 and Zirconium liner claddings from the in-pile measurements of cladding elongation and plenum pressure. The computations of cladding elongation and inner pressure gave slightly lower elongation and pressure than the in-pile measurements during the ramp-test. However, the cladding relaxation during the power hold was in good agreement, and the fission gas release behavior during cooling down could be evaluated by taking into account the relaxation of contact pressure between pellet and cladding. Although the final power during IFA-591 ramp tests reached the higher linear power than the failure threshold power of UO 2 fuel rods, no indication of fuel failure was observed during the ramp tests. The cladding relaxation due to the creep deformation of the MOX pellets at high temperature could be confirmed at the power steps during the multi-ramp test. The fission gas release due to the emancipation from PCMI stress was observed during the power decreasing. The burn-up dependence could be

  20. Stability under irradiation of a fine dispersion of oxides in a ferritic matrix; Stabilite sous irradiation de particules d'oxydes finement dispersees dans des alliages ferritiques

    Energy Technology Data Exchange (ETDEWEB)

    Monnet, I

    1999-07-01

    Oxide dispersion strengthened (ODS) ferritic-martensitic steels are being considered for high temperature, high fluence nuclear applications, like fuel pin cladding in Fast Breeder Reactors. ODS alloys offer improved out of pile strength characteristics at temperature above 550 deg.C and ferritic-martensitic matrix is highly swelling resistant. A clad in an ODS ferritic steel, call DY (Fe-13Cr-1,5Mo+TiO{sub 2}+Y{sub 2}O{sub 3}) has been irradiated in the experimental reactor Phenix. Under irradiation oxide dissolution occurs. Microstructural observations indicated that oxide evolution is correlated with the dose and consist in four phenomena: the interfaces of oxide particles with the matrix become irregular, the uniform distribution of the finest oxide (< 20 nm) disappear, the modification of oxide composition, and a halo of fine oxides appear around the larger oxides. The use of such a material requires a study of oxide stability under irradiation, since the oxide particles provide the desired mechanical properties. The study is based on two types of alloys, the DY and four ferritic steels Fe-9Cr-1Mo reinforced by Al{sub 2}O{sub 3}, Y{sub 2}O{sub 3}, MgO or MgAl{sub 2}O{sub 4}. These materials were irradiated with charged particles in order to gain a better understanding of the mechanisms of dissolution. Irradiation with 1 MeV Helium does not induce any modification, neither in the chemical modification of the particles nor in their spatial and size distribution. Since most of the energy of helium ions is lost by inelastic interaction, this result proves that this kind of interaction does not induce oxide dissolution. Irradiation with 1 MeV or 1.2 MeV electrons leads to a significant dissolution with a radius decrease proportional to the dose. These experiments prove that oxide dissolution can be induced by Frenkel pairs alone, provided that metallic atoms are displaced. The comparison between irradiation with ions (displacements cascades) and electrons (Frenkel

  1. Tritium distribution between the fuel can and the oxide of fuel elements of light-water reactors

    International Nuclear Information System (INIS)

    Masson, M.

    1986-12-01

    The study on the measurement of tritium and other radionuclide contained in zircaloy fuel cans of the water cooled reactor fuel elements had two aims: the first was to estimate with accuracy the distribution of tritium in a fuel element (can + oxide). The measurement of tritium in the zircaloy fuel cans of the BORSSELE fuel elements associated with the measurement of tritium in the oxide allowed the establishment of a complete tritium balance on an industrial spent fuel element. This result has been compared to the values calculated by the code CEA/SEN and will allow to validate or adjust this calculation. The second aim delt with the characterization of the other radionuclides gaseous (Kr85) or not (Cs 134 and 137) contained in the solid zircaloy wastes (hulls) coming from the industrial reprocessing of ''water cooled'' fuel elements. These activity measurements in the hulls allowed to estimate the residual content of tritium, Kr 85 and other radionuclides which may be found in these solid wastes (high-level βγ radioactive wastes). Original experimental methods have been developed to reach these aims (dissolution in ammonium bifluoride medium and quantitative recovery of gases produced, radiochromatography, and liquid scintillation after double distillation). One tries to explain the presence of Kr 85 in the irradiated can [fr

  2. Behavior of pre-irradiated fuel under a simulated RIA condition

    International Nuclear Information System (INIS)

    Fuketa, Toyoshi; Sasajima, Hideo; Mori, Yukihide

    1994-07-01

    This report presents results from the power burst experiment with pre-irradiated fuel rod, Test JM-3, conducted in the Nuclear Safety Research Reactor (NSSR). The data concerning test method, pre-irradiation, pre-pulse fuel examination, pulse irradiation, transient records and post-pulse fuel examination are described, and analyses, interpretations, and discussions of the results are presented. Preceding to the pulse irradiation in the NSRR, test fuel rod was irradiated in the Japan Materials Testing Reactor (JMTR) up to a fuel burnup of 19.6MWd/kgU with average linear heat rate of 25.3 kW/m. The fuel rod was subjected to the pulse irradiation resulting in a deposited energy of 174±6 cal/g·fuel and a peak fuel enthalpy of 130±5 cal/g·fuel under stagnant water cooling condition at atmospheric pressure and ambient temperature. Test fuel rod behavior was assessed from pre- and post-pulse fuel examinations and transient records during the pulse. The cladding surface temperature increased to only 150degC, and the test resulted in slight fuel deformation and no fuel failure. An estimated rod-average fission gas release during the transient was about 2.2%. Through the detailed fuel examinations, the information concerning microstructural change in the fuel pellets were also obtained. (author)

  3. Development, irradiation testing and PIE of UMo fuel at AECL

    International Nuclear Information System (INIS)

    Sears, D.F.

    2005-01-01

    This paper reviews recent U-Mo dispersion fuel development, irradiation testing and postirradiation examination (PIE) activities at AECL. Low-enriched uranium fuel alloys and powders have been fabricated at Chalk River Labs, with compositions ranging from U-7Mo to U-10Mo. The bulk alloys and powders were characterized using optical and scanning electron microscopy, chemical analysis, X-ray diffraction and neutron diffraction analysis. The analyses confirmed that the powders were of high quality, and in the desired gamma phase. Subsequently, kilogram quantities of DU-Mo and LEU-Mo powder have been manufactured for commercial customers. Mini-elements have been fabricated with LEU-7Mo and LEU-10Mo dispersed in aluminum, with a nominal loading of 4.5 gU/cm 3 . These have been irradiated in the NRU reactor at linear powers up to 100 kW/m. The mini-elements achieved 60 atom% 235 U burnup in 2004 March, and the irradiation is continuing to a planned discharge burnup of 80 atom% 235 U. Interim PIE has been conducted on mini-elements that were removed after 20 atom% 235 U burnup. The PIE results are presented in this paper. (author)

  4. Microstructure and elemental distribution of americium containing MOX fuel under the short term irradiation tests

    International Nuclear Information System (INIS)

    Tanaka, Kosuke; Hirosawa, Takashi; Obayashi, Hiroshi; Koyama, Shin Ichi; Yoshimochi, Hiroshi; Tanaka, Kenya

    2008-01-01

    In order to investigate the effect of americium addition to MOX fuels on the irradiation behavior, the 'Am-1' program is being conducted in JAEA. The Am-1 program consists of two short term irradiation tests of 10-minute and 24 hour irradiations and a steady-state irradiation test. The short-term irradiation tests were successfully completed and the post irradiation examinations (PIEs) are in progress. The PIEs for Am-containing MOX fuels focused on the microstructural evolution and redistribution behavior of Am at the initial stage of irradiation and the results to date are reported

  5. EBSD and TEM Characterization of High Burn-up Mixed Oxide Fuel

    International Nuclear Information System (INIS)

    Teague, Melissa C; Gorman, Brian P.; Miller, Brandon D; King, Jeffrey

    2014-01-01

    Understanding and studying the irradiation behavior of high burn-up oxide fuel is critical to licensing of future fast breeder reactors. Advancements in experimental techniques and equipment are allowing for new insights into previously irradiated samples. In this work dual column focused ion beam (FIB)/scanning electron microscope (SEM) was utilized to prepared transmission electron microscope samples from mixed oxide fuel with a burn-up of 6.7% FIMA. Utilizing the FIB/SEM for preparation resulted in samples with a dose rate of <0.5 mRem/h compared to approximately 1.1 R/h for a traditionally prepared TEM sample. The TEM analysis showed that the sample taken from the cooler rim region of the fuel pellet had approximately 2.5x higher dislocation density than that of the sample taken from the mid-radius due to the lower irradiation temperature of the rim. The dual column FIB/SEM was additionally used to prepared and serially slice approximately 25 um cubes. High quality electron back scatter diffraction (EBSD) were collected from the face at each step, showing, for the first time, the ability to obtain EBSD data from high activity irradiated fuel

  6. Public information circular for shipments of irradiated reactor fuel

    International Nuclear Information System (INIS)

    1988-04-01

    This circular has been prepared in response to numerous requests for information regarding routes for the shipment of irradiated reactor (spent) fuel subject to regulation by the Nuclear Regulatory Commission (NRC). The NRC staff approves such routes prior to their use, in accordance with the regulatory provisions of 10 CFR Part 73.37. The objective of the safeguards regulations contained in 10 CFR Part 73.37 is to provide protection against radioactive dispersal caused by malevolent acts by persons. The design and construction of the casks used to ship the spent fuel provide adequate radiological protection of the public health and safety against accidents. Therfore, transporting appropriately packaged spent fuel over existing rail systems and via any highway system is radiologically safe without specific NRC approval of the route. However, to assure adequate planning for protection against actual or attempted acts of radiological sabotage, the NRC requires advance route approval. This approval is given on a shipment-by-shipment or series basis, it is not general approval of the route for subsequent spent fuel shipments. Spent fuel shipment routes, primarily for road transportation, but also including three rail routes, are indicated on reproductions of road maps. Also included are the amounts of material shipped during the approximate 8-year period that safeguards regulations have been effective. This information is current as of September 30, 1987

  7. Oxidizing dissolution of spent MOX47 fuel subjected to water radiolysis: Solution chemistry and surface characterization by Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Jegou, C., E-mail: christophe.jegou@cea.f [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Caraballo, R.; De Bonfils, J.; Broudic, V.; Peuget, S. [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Vercouter, T. [Commissariat a l' Energie Atomique (CEA), Saclay Reasearch Center, B.P. 11, F-91191 Gif-sur-Yvette Cedex (France); Roudil, D. [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France)

    2010-04-01

    The mechanisms of oxidizing dissolution of spent MOX fuel (MIMAS TU2 (registered) ) subjected to water radiolysis were investigated experimentally by leaching spent MOX47 fuel samples in pure water at 25 deg. C under different oxidizing conditions (with and without external gamma irradiation); the leached surfaces were characterized by Raman spectroscopy. The highly oxidizing conditions resulting from external gamma irradiation significantly increased the concentration of plutonium (Pu(V)) and uranium (U(VI)) compared with a benchmark experiment (without external irradiation). The oxidation behavior of the plutonium-enriched aggregates differed significantly from that of the UO{sub 2} matrix after several months of leaching in water under gamma irradiation. The plutonium in the aggregates appears to limit fuel oxidation. The only secondary phases formed and identified to date by Raman spectroscopy are uranium peroxides that generally precipitate on the surface of the UO{sub 2} grains. Concerning the behavior of plutonium, solution analysis results appear to be compatible with a conventional explanation based on an equilibrium with a Pu(OH){sub 4(am)} phase. The fission product release - considered as a general indicator of matrix alteration - from MOX47 fuel also increases under external gamma irradiation and a change in the leaching mode is observed. Diffusive leaching was clearly identified, coinciding with the rapid onset of steady-state actinide concentrations in the bulk solution.

  8. Oxidative dissolution of ADOPT compared to standard UO{sub 2} fuel

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Kristina [School of Chemical Science and Engineering, Applied Physical Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Roth, Olivia [Studsvik Nuclear AB, SE-611 82 Nyköping (Sweden); Jonsson, Mats, E-mail: matsj@kth.se [School of Chemical Science and Engineering, Applied Physical Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm (Sweden)

    2017-05-15

    In this work we have studied oxidative dissolution of pure UO{sub 2} and ADOPT (UO{sub 2} doped with Al and Cr) pellets using H{sub 2}O{sub 2} and gammaradiolysis to induce the process. There is a small but significant difference in the oxidative dissolution rate of UO{sub 2} and ADOPT pellets, respectively. However, the difference in oxidative dissolution yield is insignificant. Leaching experiments were also performed on in-reactor irradiated ADOPT and UO{sub 2} pellets under oxidizing conditions. The results indicate that the U(VI) release is slightly slower from the ADOPT pellet compared to the UO{sub 2.} This could be attributed to differences in exposed surface area. However, fission products with low UO{sub 2} solubility display a higher relative release from ADOPT fuel compared to standard UO{sub 2}-fuel. This is attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel. The release of Cs is higher from UO{sub 2} which is attributed to the larger grain size of ADOPT. - Highlights: •Oxidative dissolution of ADOPT fuel is compared to standard UO{sub 2} fuel. •Only marginal differences are observed. •The main difference observed is in the relative release rate of fission products. •Differences are claimed to be attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel.

  9. Survey of Worldwide Light Water Reactor Experience with Mixed Uranium-Plutonium Oxide Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Cowell, B.S.; Fisher, S.E.

    1999-02-01

    The US and the Former Soviet Union (FSU) have recently declared quantities of weapons materials, including weapons-grade (WG) plutonium, excess to strategic requirements. One of the leading candidates for the disposition of excess WG plutonium is irradiation in light water reactors (LWRs) as mixed uranium-plutonium oxide (MOX) fuel. A description of the MOX fuel fabrication techniques in worldwide use is presented. A comprehensive examination of the domestic MOX experience in US reactors obtained during the 1960s, 1970s, and early 1980s is also presented. This experience is described by manufacturer and is also categorized by the reactor facility that irradiated the MOX fuel. A limited summary of the international experience with MOX fuels is also presented. A review of MOX fuel and its performance is conducted in view of the special considerations associated with the disposition of WG plutonium. Based on the available information, it appears that adoption of foreign commercial MOX technology from one of the successful MOX fuel vendors will minimize the technical risks to the overall mission. The conclusion is made that the existing MOX fuel experience base suggests that disposition of excess weapons plutonium through irradiation in LWRs is a technically attractive option.

  10. Survey of Worldwide Light Water Reactor Experience with Mixed Uranium-Plutonium Oxide Fuel

    International Nuclear Information System (INIS)

    Cowell, B.S.; Fisher, S.E.

    1999-01-01

    The US and the Former Soviet Union (FSU) have recently declared quantities of weapons materials, including weapons-grade (WG) plutonium, excess to strategic requirements. One of the leading candidates for the disposition of excess WG plutonium is irradiation in light water reactors (LWRs) as mixed uranium-plutonium oxide (MOX) fuel. A description of the MOX fuel fabrication techniques in worldwide use is presented. A comprehensive examination of the domestic MOX experience in US reactors obtained during the 1960s, 1970s, and early 1980s is also presented. This experience is described by manufacturer and is also categorized by the reactor facility that irradiated the MOX fuel. A limited summary of the international experience with MOX fuels is also presented. A review of MOX fuel and its performance is conducted in view of the special considerations associated with the disposition of WG plutonium. Based on the available information, it appears that adoption of foreign commercial MOX technology from one of the successful MOX fuel vendors will minimize the technical risks to the overall mission. The conclusion is made that the existing MOX fuel experience base suggests that disposition of excess weapons plutonium through irradiation in LWRs is a technically attractive option

  11. Irradiated fuel by-product separation research in Canada

    International Nuclear Information System (INIS)

    Burston, M.

    1984-01-01

    Although no decision has been made to reprocess irradiated CANDU fuel, by-product separation research has recently been initiated in Canada because of its potential importance to Canadian research programs in advanced fuel cycles (especially U/Pu cycle development in the near term) and nuclear waste management. In addition, separated by-products could have a significant commercial potential. Demonstrated applications include: heat sources, gamma radiation sources, light sources, new materials for productions of other useful isotopes, etc. For illustrative purposes the calculated market value of by-products currently stored in irradiated CANDU fuel is approximately $210/kgU. Ontario Hydro has initiated a program to study the application of new separation technolgies, such as laser-based techniques and the plasma ion cyclotron resonance separation technique, to either augment and/or supplant the chemical extraction methods. The main goal is to develop new, more economical extraction methods in order to increase the magnitude of the advantages resulting from this approach to reprocessing. (author)

  12. Monitoring of releases from an irradiated fuel reprocessing plant

    International Nuclear Information System (INIS)

    Fitoussi, L.

    1978-01-01

    At its UP 2 plant, the La Hague facility reprocesses irradiated fuel by the PUREX process. The fuel stems from graphite/gas, natural-uranium reactors and pressurized or boiling water enriched-uranium reactors. The gaseous effluents are collected and purified by high-efficiency washing and filtration. After purification the gas stream is discharged into the atmosphere by a single stack, 100m high and 6m in diameter, located at a high point on the site (184m). The radionuclides released into the air are: krypton-85, iodine-129 and -131, and tritium. The liquid effluents are collected by drainage systems, which transfer them to the effluent treatment station in the case of active or suspect solutions. Active solutions undergo treatment by chemical and physical processes. After purification the waste water is released into the sea by an underwater drainage system 5km long, which brings the outlet point into the middle of a tidal current 2km offshore. The radionuclides contained in the purified waste water are fission products originating from irradiated fuels in only slightly variable proportions, in which ruthenium-rhodium-106 predominates. Traces of the transuranium elements are also found in these solutions

  13. A new code for predicting the thermo-mechanical and irradiation behavior of metallic fuels in sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Karahan, Aydin, E-mail: karahan@mit.ed [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology (United States); Buongiorno, Jacopo [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology (United States)

    2010-01-31

    An engineering code to predict the irradiation behavior of U-Zr and U-Pu-Zr metallic alloy fuel pins and UO{sub 2}-PuO{sub 2} mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named Fuel Engineering and Structural analysis Tool (FEAST). FEAST has several modules working in coupled form with an explicit numerical algorithm. These modules describe fission gas release and fuel swelling, fuel chemistry and restructuring, temperature distribution, fuel-clad chemical interaction, and fuel and clad mechanical analysis including transient creep-fracture for the clad. Given the fuel pin geometry, composition and irradiation history, FEAST can analyze fuel and clad thermo-mechanical behavior at both steady-state and design-basis (non-disruptive) transient scenarios. FEAST was written in FORTRAN-90 and has a simple input file similar to that of the LWR fuel code FRAPCON. The metal-fuel version is called FEAST-METAL, and is described in this paper. The oxide-fuel version, FEAST-OXIDE is described in a companion paper. With respect to the old Argonne National Laboratory code LIFE-METAL and other same-generation codes, FEAST-METAL emphasizes more mechanistic, less empirical models, whenever available. Specifically, fission gas release and swelling are modeled with the GRSIS algorithm, which is based on detailed tracking of fission gas bubbles within the metal fuel. Migration of the fuel constituents is modeled by means of thermo-transport theory. Fuel-clad chemical interaction models based on precipitation kinetics were developed for steady-state operation and transients. Finally, a transient intergranular creep-fracture model for the clad, which tracks the nucleation and growth of the cavities at the grain boundaries, was developed for and implemented in the code. Reducing the empiricism in the constitutive models should make it more acceptable to extrapolate FEAST-METAL to new fuel compositions and higher burnup, as envisioned in advanced sodium

  14. A new code for predicting the thermo-mechanical and irradiation behavior of metallic fuels in sodium fast reactors

    International Nuclear Information System (INIS)

    Karahan, Aydin; Buongiorno, Jacopo

    2010-01-01

    An engineering code to predict the irradiation behavior of U-Zr and U-Pu-Zr metallic alloy fuel pins and UO 2 -PuO 2 mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named Fuel Engineering and Structural analysis Tool (FEAST). FEAST has several modules working in coupled form with an explicit numerical algorithm. These modules describe fission gas release and fuel swelling, fuel chemistry and restructuring, temperature distribution, fuel-clad chemical interaction, and fuel and clad mechanical analysis including transient creep-fracture for the clad. Given the fuel pin geometry, composition and irradiation history, FEAST can analyze fuel and clad thermo-mechanical behavior at both steady-state and design-basis (non-disruptive) transient scenarios. FEAST was written in FORTRAN-90 and has a simple input file similar to that of the LWR fuel code FRAPCON. The metal-fuel version is called FEAST-METAL, and is described in this paper. The oxide-fuel version, FEAST-OXIDE is described in a companion paper. With respect to the old Argonne National Laboratory code LIFE-METAL and other same-generation codes, FEAST-METAL emphasizes more mechanistic, less empirical models, whenever available. Specifically, fission gas release and swelling are modeled with the GRSIS algorithm, which is based on detailed tracking of fission gas bubbles within the metal fuel. Migration of the fuel constituents is modeled by means of thermo-transport theory. Fuel-clad chemical interaction models based on precipitation kinetics were developed for steady-state operation and transients. Finally, a transient intergranular creep-fracture model for the clad, which tracks the nucleation and growth of the cavities at the grain boundaries, was developed for and implemented in the code. Reducing the empiricism in the constitutive models should make it more acceptable to extrapolate FEAST-METAL to new fuel compositions and higher burnup, as envisioned in advanced sodium reactors

  15. Pyrolytic electrochemical process for the reprocessing of irradiated nuclear fuels

    International Nuclear Information System (INIS)

    Brambilla, G.; Sartorelli, A.

    1980-01-01

    The reprocessing is aimed at synthetic UO 2 -PuO 2 mixed oxides, UC-PuC mixed carbides and at oxides and carbides of U, Pu and Th from fast nuclear reactors. The nuclear fuel is dissolved in a salt melting bath. The conversion of the Pu(SO 4 ) 2 is done thermally and that of UO 2 is done electrolytically. The molten salts are returned to the input of the process and the fission products and the molten salts are conditioned. (DG) [de

  16. Thermophysical properties of the irradiated uranium-zirconium fuel

    International Nuclear Information System (INIS)

    Gajduchenko, A.B.

    2008-01-01

    The dependence of the thermophysical properties of metallic nuclear fuel, i.e. Zr alloy 40U, in a wide temperature range as a function of accumulated fission products amount is presented. Both non-irradiated and irradiated test pieces with different degrees of accumulation of fission products, i.e. 0.4, 0.6, and 0.9 g/cm 3 , are investigated. The specific heat is measured in the range of 50-1000 deg C, the thermal diffusivity is measured in the range 300-1000 deg C, and the variation of the dimensions and density of the samples on heating is also investigated. The thermal conductivity in the range of 50-1000 deg C is calculated on the basis of the experimental data [ru

  17. Ceramographic Examinations of Irradiated AGR-1 Fuel Compacts

    Energy Technology Data Exchange (ETDEWEB)

    Paul Demkowicz; Scott Ploger; John Hunn

    2012-05-01

    The AGR 1 experiment involved irradiating 72 cylindrical fuel compacts containing tri-structural isotropic (TRISO)-coated particles to a peak burnup of 19.5% fissions per initial metal atom with no in-pile failures observed out of almost 300,000 particles. Five irradiated AGR 1 fuel compacts were selected for microscopy that span a range of irradiation conditions (temperature, burnup, and fast fluence). These five compacts also included all four TRISO coating variations irradiated in the AGR experiment. The five compacts were cross-sectioned both transversely and longitudinally, mounted, ground, and polished after development of careful techniques for preserving particle structures against preparation damage. Approximately 40 to 80 particles within each cross section were exposed near enough to mid-plane for optical microscopy of kernel, buffer, and coating behavior. The microstructural analysis focused on kernel swelling and porosity, buffer densification and fracture, debonding between the buffer and inner pyrolytic carbon (IPyC) layers, and fractures in the IPyC and SiC layers. Three basic particle morphologies were established according to the extent of bonding between the buffer and IPyC layers: complete debonding along the interface (Type A), no debonding along the interface (Type B), and partial debonding (Type AB). These basic morphologies were subdivided according to whether the buffer stayed intact or fractured. The resulting six characteristic morphologies were used to classify particles within each cross section, but no spatial patterns were clearly observed in any of the cross-sectional morphology maps. Although positions of particle types appeared random within compacts, examining a total of 830 classified particles allowed other relationships among morphological types to be established.

  18. Ceramographic Examinations of Irradiated AGR-1 Fuel Compacts

    International Nuclear Information System (INIS)

    Demkowicz, Paul; Ploger, Scott; Hunn, John

    2012-01-01

    The AGR 1 experiment involved irradiating 72 cylindrical fuel compacts containing tri-structural isotropic (TRISO)-coated particles to a peak burnup of 19.5% fissions per initial metal atom with no in-pile failures observed out of almost 300,000 particles. Five irradiated AGR 1 fuel compacts were selected for microscopy that span a range of irradiation conditions (temperature, burnup, and fast fluence). These five compacts also included all four TRISO coating variations irradiated in the AGR experiment. The five compacts were cross-sectioned both transversely and longitudinally, mounted, ground, and polished after development of careful techniques for preserving particle structures against preparation damage. Approximately 40 to 80 particles within each cross section were exposed near enough to mid-plane for optical microscopy of kernel, buffer, and coating behavior. The microstructural analysis focused on kernel swelling and porosity, buffer densification and fracture, debonding between the buffer and inner pyrolytic carbon (IPyC) layers, and fractures in the IPyC and SiC layers. Three basic particle morphologies were established according to the extent of bonding between the buffer and IPyC layers: complete debonding along the interface (Type A), no debonding along the interface (Type B), and partial debonding (Type AB). These basic morphologies were subdivided according to whether the buffer stayed intact or fractured. The resulting six characteristic morphologies were used to classify particles within each cross section, but no spatial patterns were clearly observed in any of the cross-sectional morphology maps. Although positions of particle types appeared random within compacts, examining a total of 830 classified particles allowed other relationships among morphological types to be established.

  19. Fission gas induced deformation model for FRAP-T6 and NSRR irradiated fuel test simulations

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Takehiko; Sasajima, Hideo; Fuketa, Toyoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Hosoyamada, Ryuji; Mori, Yukihide

    1996-11-01

    Pulse irradiation tests of irradiated fuels under simulated reactivity initiated accidents (RIAs) have been carried out at the Nuclear Safety Research Reactor (NSRR). Larger cladding diameter increase was observed in the irradiated fuel tests than in the previous fresh fuel tests. A fission gas induced cladding deformation model was developed and installed in a fuel behavior analysis code, FRAP-T6. The irradiated fuel tests were analyzed with the model in combination with modified material properties and fuel cracking models. In Test JM-4, where the cladding temperature rose to higher temperatures and grain boundary separation by the pulse irradiation was significant, the fission gas model described the cladding deformation reasonably well. The fuel had relatively flat radial power distribution and the grain boundary gas from the whole radius was calculated to contribute to the deformation. On the other hand, the power density in the irradiated LWR fuel rods in the pulse irradiation tests was remarkably higher at the fuel periphery than the center. A fuel thermal expansion model, GAPCON, which took account of the effect of fuel cracking by the temperature profile, was found to reproduce well the LWR fuel behavior with the fission gas deformation model. This report present details of the models and their NSRR test simulations. (author)

  20. Determination of fuel irradiation parameters. Required accuracies and available methods

    International Nuclear Information System (INIS)

    Mas, P.

    1977-01-01

    This paper reports on the present point of some main methods to determine the nuclear parameters of fuel irradiation in testing reactors (nuclear power, burn up, ...) The different methods (theoretical or experimental) are reviewed: neutron measurements and calculations, gamma scanning, heat balance, ... . The required accuracies are reviewed: they are of 3-5 % on flux, fluences, nuclear power, burn-up, conversion factor. These required accuracies are compared with the real accuracies available which are the present time of order of 5-20 % on these parameters

  1. Evaluation of the problems associated with ENEL's irradiated fuel management

    International Nuclear Information System (INIS)

    Sani, L.; Belelli, U.

    1978-01-01

    The present difficulties in the reprocessing field, wich will continue for a period of time not easily definable, impose on the nuclear utilities the research of adequate solutions to solve the problem associated with storage of the fuels discharged by the nuclear power stations in operation. In this context, the paper examines the technical aspects of the various possible alternatives and on the basis of the Italian nuclear program, possible storage strategies are discussed in the assumption of the development of an adequate oxide-fuel reprocessing capacity. The problems related to storage in pools at the station or away from reactor are described in the light of the recent experience made in Italy with the adaptation of an old pool reactor out of service, that is, the Avogadro reactor in Saluggia, to store the fuels of the stations now in operation. Finally some economic aspects are considered in order to ascertain their impact on the cost of energy produced. (author)

  2. Fission product Pd-SiC interaction in irradiated coated particle fuels

    International Nuclear Information System (INIS)

    Tiegs, T.N.

    1980-04-01

    Silicon carbide is the main barrier to fission product release from coated particle fuels. Consequently, degradation of the SiC must be minimized. Electron microprobe analysis has identified that palladium causes corrosion of the SiC in irradiated coated particles. Further ceramographic and electron microprobe examinations on irradiated particles with kernels ranging in composition from UO 2 to UC 2 , including PuO/sub 2 -x/ and mixed (Th, Pu) oxides, and in enrichment from 0.7 to 93.0% 235 U revealed that temperature is the major factor affecting the penetration rate of SiC by Pd. The effects of kernel composition, Pd concentration, other fission products, and SiC properties are secondary

  3. Fuel cracking in relation to fuel oxidation in support of an out-reactor instrumented defected fuel experiment

    Energy Technology Data Exchange (ETDEWEB)

    Quastel, A.; Thiriet, C. [Atomic Energy of Canada Limited, Chalk River, ON (Canada); Lewis, B., E-mail: brent.lewis@uoit.ca [Univ. of Ontario Inst. of Tech., Oshawa, ON (Canada); Corcoran, E., E-mail: emily.corcoran@rmc.ca [Royal Military College of Canada, Kingston, ON (Canada)

    2014-07-01

    An experimental program funded by the CANDU Owners Group (COG) is studying an out-reactor instrumented defected fuel experiment in Stern Laboratories (Hamilton, Ontario) with guidance from Atomic Energy of Canada Limited (AECL). The objective of this test is to provide experimental data for validation of a mechanistic fuel oxidation model. In this experiment a defected fuel element with UO{sub 2} pellets will be internally heated with an electrical heater element, causing the fuel to crack. By defecting the sheath in-situ the fuel will be exposed to light water coolant near normal reactor operating conditions (pressure 10 MPa and temperature 265-310{sup o}C) causing fuel oxidation, especially near the hotter regions of the fuel in the cracks. The fuel thermal conductivity will change, resulting in a change in the temperature distribution of the fuel element. This paper provides 2D r-θ plane strain solid mechanics models to simulate fuel thermal expansion, where conditions for fuel crack propagation are investigated with the thermal J integral to predict fuel crack stress intensity factors. Finally since fuel crack geometry can affect fuel oxidation this paper shows that the solid mechanics model with pre-set radial cracks can be coupled to a 2D r-θ fuel oxidation model. (author)

  4. Irradiation behavior of U 6Mn-Al dispersion fuel elements

    Science.gov (United States)

    Meyer, M. K.; Wiencek, T. C.; Hayes, S. L.; Hofman, G. L.

    2000-02-01

    Irradiation testing of U 6Mn-Al dispersion fuel miniplates was conducted in the Oak Ridge Research Reactor (ORR). Post-irradiation examination showed that U 6Mn in an unrestrained plate configuration performs similarly to U 6Fe under irradiation, forming extensive and interlinked fission gas bubbles at a fission density of approximately 3×10 27 m-3. Fuel plate failure occurs by fission gas pressure driven `pillowing' on continued irradiation.

  5. Assessment of uranium dioxide fuel performance with the addition of beryllium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Muniz, Rafael O.R.; Abe, Alfredo; Gomes, Daniel S.; Silva, Antonio T., E-mail: romuniz@usp.br, E-mail: ayabe@ipen.br, E-mail: danieldesouza@gmail.com, E-mail: teixeira@ipen.br [Instituto de Pesquisas Energética s e Nucleares (IPEN/CNEN-SP), São Paulo, SP (Brazil); Giovedi, Claudia, E-mail: claudia.giovedi@labrisco.usp.br [Universidade de Sao Paulo (LabRisco/USP), Sao Paulo, SP (Brazil). Lab. de Análise, Avaliação e Gerenciamento de Risco; Aguiar, Amanda A., E-mail: amanda.abati.aguiar@gmail.com [Centro Tecnológico da Marinha em São Paulo (CTMSP), São Paulo, SP (Brazil)

    2017-07-01

    The Fukushima Daiichi accident in 2011 pointed the problem related to the hydrogen generation under accident scenarios due to the oxidation of zirconium-based alloys widely used as fuel rod cladding in water-cooled reactors. This problem promoted research programs aiming the development of accident tolerant fuels (ATF) which are fuels that under accident conditions could keep longer its integrity enabling the mitigation of the accident effects. In the framework of the ATF program, different materials have been studied to be applied as cladding to replace zirconium-based alloy; also efforts have been made to improve the uranium dioxide thermal conductivity doping the fuel pellet. This paper evaluates the addition of beryllium oxide (BeO) to the uranium dioxide in order to enhance the thermal conductivity of the fuel pellet. Investigations performed in this area considering the addition of 10% in volume of BeO, resulting in the UO{sub 2}-BeO fuel, have shown good results with the improvement of the fuel thermal conductivity and the consequent reduction of the fuel temperatures under irradiation. In this paper, two models obtained from open literature for the thermal conductivity of UO{sub 2}- BeO fuel were implemented in the FRAPCON 3.5 code and the results obtained using the modified code versions were compared. The simulations were carried out using a case available in the code documentation related to a typical pressurized water reactor (PWR) fuel rod irradiated under steady state condition. The results show that the fuel centerline temperatures decrease with the addition of BeO, when compared to the conventional UO{sub 2} pellet, independent of the model applied. (author)

  6. Modified fuel channel for sample irradiation at the RB reactor

    International Nuclear Information System (INIS)

    Pesic, M.; Markovic, H.; Sokcic, M.; Miric, I.; Prokic, M.; Strugar, P.

    1983-01-01

    Fuel channel of 80% enriched UO 2 at RB reactor in Boris Kidric Institute of nuclear sciences is modified for sample irradiation in the fast neutron field. Maximum sample diameter is 25 mm and length up to 100 mm. Characteristics of neutron as well as gamma radiation fields of this new experimental channel are investigated. In the center of channel, the main contribution to the total neutron absorbed dose i.e. 0.29 Gy per 1 Wh of reactor operation, is due to the fast neutron spectrum component. Only 0.05 Gy and 0.07 Gy in the total neutron absorbed dose are due to epithermal and thermal neutrons respectively. At the same time gamma absorption dose is 0.35 Gy. The development of experimental fuel channel GRK has wide possibility for utilization, from electronic components fast neutron studies, dosimeters testing, to cross section measurements for fast neutron energies. (author)

  7. Performance Evaluation of Solid Oxide Fuel Cell by Computer ...

    African Journals Online (AJOL)

    The search for sustainable energy source that can compete with the existing one led to the discovery and acceptance of fuel cell technologies as a perfect replacement for fossil fuel. The ability of Solid Oxide Fuel Cells (SOFC) to capture the heat generation during the process of energy generation from electrochemical ...

  8. Reviews on Solid Oxide Fuel Cell Technology

    Directory of Open Access Journals (Sweden)

    Apinan Soottitantawat

    2009-02-01

    Full Text Available Solid Oxide Fuel Cell (SOFC is one type of high temperature fuel cell that appears to be one of the most promising technology to provide the efficient and clean energy production for wide range of applications (from small units to large scale power plants. This paper reviews the current status and related researches on SOFC technologies. In details, the research trend for the development of SOFC components(i.e. anode, electrolyte, cathode, and interconnect are presented. Later, the current important designs of SOFC (i.e. Seal-less Tubular Design, Segmented Cell in Series Design, Monolithic Design and Flat Plate Design are exampled. In addition, the possible operations of SOFC (i.e. external reforming, indirect internal reforming, and direct internal reforming are discussed. Lastly, the research studies on applications of SOFCs with co-generation (i.e. SOFC with Combined Heat and Power (SOFC-CHP, SOFC with Gas Turbine (SOFC-GT and SOFC with chemical production are given.

  9. Plutonium spot of mixed oxide fuel, 2

    International Nuclear Information System (INIS)

    Suzuki, Yukio; Maruishi, Yoshihiro; Satoh, Masaichi; Aoki, Toshimasa; Muto, Tadashi

    1974-01-01

    In a fast reactor, the specification for the homogeneity of plutonium in plutonium-uranium mixed-oxide fuel is mainly dependent on the nuclear characteristics, whereas in a thermal reactor, on thermal characteristics. This homogeneity is measured by autoradiography as the plutonium spot size of the specimens which are arbitrarily chosen fuel pellets from a lot. Although this is a kind of random sampling, it is difficult to apply this method to conventional digital standards including JIS standards. So a special sampling inspection method was studied. First, it is assumed that the shape of plutonium spots is spherical, the size distribution is logarithmic normal, and the standard deviation is constant. Then, if standard deviation and mean spot size are given, the logarithmic normal distribution is decided unitarily, and further if the total weight of plutonium spots for a lot of pellets is known, the number of the spots (No) which does not conform to the specification can be obtained. Then, the fraction defective is defined as No devided by the number of pellets per lot. As to the lot with such fraction defective, the acceptance coefficient of the lot was obtained through calculation, in which the number of sampling, acceptable diameter limit observed and acceptable conditions were used as parameters. (Tai, I.)

  10. Learning curves for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Rivera-Tinoco, R.; Schoots, K. [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Zwaan, B.C.C. van der [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Columbia Univ., New York City, NY (United States). Lenfest Center for Sustainable Energy

    2010-07-01

    We present learning curves for solid oxide fuel cells (SOFCs) and combined heat and power (CHP) SOFC systems with an electric capacity between 1 and 250 kW. On the basis of the cost breakdown of production cost data from fuel cell manufacturers, we developed a bottom-up model that allows for determining overall manufacturing costs from their respective cost components, among which material, energy, labor, and capital charges. The results obtained from our model prove to deviate by at most 13% from total cost figures quoted in the literature. For the early pilot stage of development, we find for SOFC manufacturing a learning rate between 14% and 17%, and for total SOFC system fabrication between 16% and 19%. We argue that the corresponding cost reductions result largely from learning-by-searching effects (R and D) rather than learning-by-doing. When considering a longer time frame that includes the early commercial production stage, we find learning rates between 14% and 39%, which represent a mix of phenomena such as learning-by-doing, learning-by-searching, economies-of-scale and automation. (orig.)

  11. Nanostructured Solid Oxide Fuel Cell Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Sholklapper, Tal Zvi [Univ. of California, Berkeley, CA (United States)

    2007-01-01

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  12. Solid Oxide Fuel Cells Canada (SOFCC)

    International Nuclear Information System (INIS)

    Birss, V.; Borglum, B.

    2006-01-01

    Vision: To enhance co-ordination and to ensure sustainable funding of research, development, and commercialization of solid oxide fuel cells and related technologies in Canada in order to create products that serve the world. Current Research Areas of Investigation: Mission: To provide cleaner air, reduce CO 2 emissions, better utilize fuel resources, increase economic prosperity, and enhance the quality of life in Canada and the world by enabling and accelerating development of the Canadian SOFC industry. To achieve this, we will: 1. Establish national priorities for the research, development, design, demonstration, and the innovation process; commercialization of SOFC and related technologies; 2. Develop a strategy to produce commercial products within 5 years; 3. Co-ordinate activities as one integrated Canada-wide initiative; 4. Facilitate effective access to funding by providing a venue for funders to directly participate in; 5. Provide an integrating and interdisciplinary function to maximize the collective knowledge, expertise, and capacity of the alliance partners; 6. Maintain strategic relevance within an ever changing global context by providing high-quality intelligence. (author)

  13. Advanced methods of solid oxide fuel cell modeling

    CERN Document Server

    Milewski, Jaroslaw; Santarelli, Massimo; Leone, Pierluigi

    2011-01-01

    Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. ""Advanced Methods of Solid Oxide Fuel Cell Modeling"" proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. ""Advanced Methods

  14. Learning curves for solid oxide fuel cells

    International Nuclear Information System (INIS)

    Rivera-Tinoco, Rodrigo; Schoots, Koen; Zwaan, Bob van der

    2012-01-01

    Highlights: ► We present learning curves for fuel cells based on empirical data. ► We disentangle different cost reduction mechanisms for SOFCs. ► We distinguish between learning-by-doing, R and D, economies-of-scale and automation. - Abstract: In this article we present learning curves for solid oxide fuel cells (SOFCs). With data from fuel cell manufacturers we derive a detailed breakdown of their production costs. We develop a bottom-up model that allows for determining overall SOFC manufacturing costs with their respective cost components, among which material, energy, labor and capital charges. The results obtained from our model prove to deviate by at most 13% from total cost figures quoted in the literature. For the R and D stage of development and diffusion, we find local learning rates between 13% and 17% and we demonstrate that the corresponding cost reductions result essentially from learning-by-searching effects. When considering periods in time that focus on the pilot and early commercial production stages, we find regional learning rates of 27% and 1%, respectively, which we assume derive mainly from genuine learning phenomena. These figures turnout significantly higher, approximately 44% and 12% respectively, if also effects of economies-of-scale and automation are included. When combining all production stages we obtain lr = 35%, which represents a mix of cost reduction phenomena. This high learning rate value and the potential to scale up production suggest that continued efforts in the development of SOFC manufacturing processes, as well as deployment and use of SOFCs, may lead to substantial further cost reductions.

  15. Irradiation behavior evaluation of oxide dispersion strengthened ferritic steel cladding tubes irradiated in JOYO

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, Shinichiro, E-mail: yamashita.shinichiro@jaea.go.jp; Yano, Yasuhide; Ohtsuka, Satoshi; Yoshitake, Tsunemitsu; Kaito, Takeji; Koyama, Shin-ichi; Tanaka, Kenya

    2013-11-15

    Irradiation behavior of ODS steel cladding tubes was evaluated for the further progress in understanding of the neutron-irradiation effects on ODS steel. Two types of ODS (9Cr–ODS{sub F}/M, 12Cr–ODS{sub F}) steel cladding tubes with differences in basic compositions and matrix phases were irradiated in JOYO. Post-irradiation examination data concerning hardness, ring tensile property, and microstructure were obtained. Hardness measurement after irradiation showed that there was an apparent irradiation temperature dependence on hardness for 9Cr–ODS{sub F}/M steel whereas no distinct temperature dependence for 12Cr–ODS{sub F} steel. Also, there was no significant change in tensile strengths after irradiation below 923 K, but those above 1023 K up to 6.6 × 10{sup 26} n/m{sup 2} (E > 0.1 MeV) were decreased by about 20%. TEM observations showed that the radiation-induced defect cluster formation during irradiation was suppressed because of high density sink site for defect such as initially-existed dislocation, and precipitate interfaces. In addition, oxide particles were stable up to the maximum doses of this irradiation test.

  16. Safety aspects of advanced fuels irradiations in EBR-II

    International Nuclear Information System (INIS)

    Lehto, W.K.

    1975-09-01

    Basic safety questions such as MFCI, loss-of-Na bond, pin behavior during design basis transients, and failure propagation were evaluated as they pertain to advanced fuels in EBR-II. With the exception of pin response to the unlikely loss-of-flow transient, the study indicates that irradiation of significant numbers of advanced fueled subassemblies in EBR-II should pose no safety problems. The analysis predicts, however, that Na boiling may occur during the postulated design basis unlikely loss-of-flow transient in subassemblies containing He-bonded fuel pins with the larger fuel-clad gaps. The calculations indicate that coolant temperatures at top of core in the limiting S/A's, containing the He bonded pins, would reach approximately 1480 0 F during the transient without application of uncertainty factors. Inclusion of uncertainties could result in temperature predictions which approach coolant boiling temperatures (1640 0 F). Further analysis of He-bonded pins is being done in this potential problem area, e.g., to apply best estimates of uncertainty factors and to determine the sensitivity of the preliminary results to gap conductance

  17. Irradiation performance of coated fuel particles with fission product retaining kernel additives

    International Nuclear Information System (INIS)

    Foerthmann, R.

    1979-10-01

    The four irradiation experiments FRJ2-P17, FRJ2-P18, FRJ2-P19, and FRJ2-P20 for testing the efficiency of fission product-retaining kernel additives in coated fuel particles are described. The evaluation of the obtained experimental data led to the following results: - zirconia and alumina kernel additives are not suitable for an effective fission product retention in oxide fuel kernels, - alumina-silica kernel additives reduce the in-pile release of Sr 90 and Ba 140 from BISO-coated particles at temperatures of about 1200 0 C by two orders of magnitude, and the Cs release from kernels by one order of magnitude, - effective transport coefficients including all parameters which contribute to kernel release are given for (Th,U)O 2 mixed oxide kernels and low enriched UO 2 kernels containing 5 wt.% alumina-silica additives: 10g sub(K)/cm 2 s -1 = - 36 028/T + 6,261 (Sr 90), 10g Dsub(K)/cm 2 c -2 = - 29 646/T + 5,826 (Cs 134/137), alumina-silica kernel additives are ineffective for retaining Ag 110 m in coated particles. However, also an intact SiC-interlayer was found not to be effective at temperatures above 1200 0 C, - the penetration of the buffer layer by fission product containing eutectic additive melt during irradiation can be avoided by using additives which consist of alumina and mullite without an excess of silica, - annealing of LASER-failed irradiated particles and the irradiation test FRJ12-P20 indicate that the efficiency of alumina-silica kernel additives is not altered if the coating becomes defect. (orig.) [de

  18. The burnup dependence of light water reactor spent fuel oxidation

    International Nuclear Information System (INIS)

    Hanson, B.D.

    1998-07-01

    Over the temperature range of interest for dry storage or for placement of spent fuel in a permanent repository under the conditions now being considered, UO 2 is thermodynamically unstable with respect to oxidation to higher oxides. The multiple valence states of uranium allow for the accommodation of interstitial oxygen atoms in the fuel matrix. A variety of stoichiometric and nonstoichiometric phases is therefore possible as the fuel oxidizers from UO 2 to higher oxides. The oxidation of UO 2 has been studied extensively for over 40 years. It has been shown that spent fuel and unirradiated UO 2 oxidize via different mechanisms and at different rates. The oxidation of LWR spent fuel from UO 2 to UO 2.4 was studied previously and is reasonably well understood. The study presented here was initiated to determine the mechanism and rate of oxidation from UO 2.4 to higher oxides. During the early stages of this work, a large variability in the oxidation behavior of samples oxidized under nearly identical conditions was found. Based on previous work on the effect of dopants on UO 2 oxidation and this initial variability, it was hypothesized that the substitution of fission product and actinide impurities for uranium atoms in the spent fuel matrix was the cause of the variable oxidation behavior. Since the impurity concentration is roughly proportional to the burnup of a specimen, the oxidation behavior of spent fuel was expected to be a function of both temperature and burnup. This report (1) summarizes the previous oxidation work for both unirradiated UO 2 and spent fuel (Section 2.2) and presents the theoretical basis for the burnup (i.e., impurity concentration) dependence of the rate of oxidation (Sections 2.3, 2.4, and 2.5), (2) describes the experimental approach (Section 3) and results (Section 4) for the current oxidation tests on spent fuel, and (3) establishes a simple model to determine the activation energies associated with spent fuel oxidation (Section 5)

  19. The reprocessing of irradiated fuels improvement and extension of the solvent extraction process

    International Nuclear Information System (INIS)

    Faugeras, P.; Chesne, A.

    1964-01-01

    Improvements made in the conventional tri-butylphosphate process are described, in particular. the concentration and the purification of plutonium by one extraction cycle using tri-butyl-phosphate with reflux; and the use of an apparatus working continuously for precipitating plutonium oxalate, for calcining the oxalate, and for fluorinating the oxide. The modifications proposed for the treatment of irradiated uranium - molybdenum alloys are described, in particular, the dissolution of the fuel, and the concentration of the fission product solutions. The solvent extraction treatment is used also for the plutonium fuels utilized for the fast breeder reactor (Rapsodie) An outline of the process is presented and discussed, as well as the first experimental results and the plans for a pilot plant having a capacity of 1 kg/day. The possible use of tn-lauryl-amine in the plutonium purification cycle is now under consideration for the processing plant at La Hague. The flowsheet for this process and its performance are presented. The possibility of vitrification is considered for the final treatment of the concentrated radioactive wastes from the Marcoule (irradiated uranium) and La Hague (irradiated uranium-molybdenum) Centers. Three possible processes are described and discussed, as well as the results obtained from the operation of the corresponding experimental units using tracers. (authors) [fr

  20. On the fission gas release from oxide fuels during normal grain growth

    International Nuclear Information System (INIS)

    Paraschiv, M.C.; Paraschiv, A.; Glodeanu, F.

    1997-01-01

    A mathematical formalism for calculating the fission gas release from oxide fuels considering an arbitrary distribution of fuel grain size with only zero boundary condition for gas diffusion at the grain boundary is proposed. It has also been proved that it becomes unnecessary to consider the grain volume distribution function for fission products diffusion when the grain boundary gas resolution is considered, if thermodynamic forces on grain boundaries are only time dependent. In order to highlight the effect of the normal grain growth on fission gas release from oxide fuels Hillert's and Lifshitz and Slyozov's theories have been selected. The last one was used to give an adequate treatment of normal grain growth for the diffusion-controlled grain boundary movement in oxide fuels. It has been shown that during the fuel irradiation, the asymptotic form of the grain volume distribution functions given by Hillert and Lifshitz and Slyozov models can be maintained but the grain growth rate constant becomes time dependent itself. Experimental results have been used to correlate the two theoretical models of normal grain growth to the fission gas release from oxide fuels. (orig.)

  1. An overview on dry reprocessing of irradiated nuclear fuels

    International Nuclear Information System (INIS)

    Ouyang Yinggen

    2002-01-01

    Although spent nuclear fuels have been reprocessed successfully for many years by the well-know Purex process based on solvent extraction, other reprocessing method which do not depend upon the use of organic solvents and aqueous media appear to have important potential advantage. There are two main non-aqueous methods for the reprocessing of spent fuel: fluoride-volatility process and pyro-electrochemical process. The presence of a poser in the process is that PuF 6 is obviously thermodynamically stable only in the presence of a large excess of fluorine. Pyro-electrochemical process is suited to processing metallic, oxide and carbide fuels. First, the fuel is dissolved in fresh salts, then, electrodes are introduced into the bath, U and Pu are deposited on the cathode, third, separation and refinement U and Pu are deposited on the cathode. There is a couple of contradictions in the process that are not in harmonious proportion in the fields on the nuclear fuel is dissolved the ability in the molten salt and corrosiveness of the molten salt for equipment used in the process

  2. POST-IRRADIATION ANALYSES OF U-MO DISPERSION FUEL RODS OF KOMO TESTS AT HANARO

    Directory of Open Access Journals (Sweden)

    H.J. RYU

    2013-12-01

    Full Text Available Since 2001, a series of five irradiation test campaigns for atomized U-Mo dispersion fuel rods, KOMO-1, -2, -3, -4, and -5, has been conducted at HANARO (Korea in order to develop high performance low enriched uranium dispersion fuel for research reactors. The KOMO irradiation tests provided valuable information on the irradiation behavior of U-Mo fuel that results from the distinct fuel design and irradiation conditions of the rod fuel for HANARO. Full size U-Mo dispersion fuel rods of 4–5 g-U/cm3 were irradiated at a maximum linear power of approximately 105 kW/m up to 85% of the initial U-235 depletion burnup without breakaway swelling or fuel cladding failure. Electron probe microanalyses of the irradiated samples showed localized distribution of the silicon that was added in the matrix during fuel fabrication and confirmed its beneficial effect on interaction layer growth during irradiation. The modifications of U-Mo fuel particles by the addition of a ternary alloying element (Ti or Zr, additional protective coatings (silicide or nitride, and the use of larger fuel particles resulted in significantly reduced interaction layers between fuel particles and Al.

  3. MICRO/NANO-STRUCTURAL EXAMINATION AND FISSION PRODUCT IDENTIFICATION IN NEUTRON IRRADIATED AGR-1 TRISO FUEL

    Energy Technology Data Exchange (ETDEWEB)

    van Rooyen, I. J.; Lillo, T. M.; Wen, H. M.; Hill, C. M.; Holesinger, T. G.; Wu, Y. Q.; Aguiara, J. A.

    2016-11-01

    Advanced microscopic and microanalysis techniques were developed and applied to study irradiation effects and fission product behavior in selected low-enriched uranium oxide/uranium carbide TRISO-coated particles from fuel compacts in six capsules irradiated to burnups of 11.2 to 19.6% FIMA. Although no TRISO coating failures were detected during the irradiation, the fraction of Ag-110m retained in individual particles often varied considerably within a single compact and at the capsule level. At the capsule level Ag-110m release fractions ranged from 1.2 to 38% and within a single compact, silver release from individual particles often spanned a range that extended from 100% retention to nearly 100% release. In this paper, selected irradiated particles from Baseline, Variant 1 and Variant 3 type fueled TRISO coated particles were examined using Scanning Electron Microscopy, Atom Probe Tomography; Electron Energy Loss Spectroscopy; Precession Electron Diffraction, Transmission Electron Microscopy, Scanning Transmission Electron Microscopy (STEM), High Resolution Electron Microscopy (HRTEM) examinations and Electron Probe Micro-Analyzer. Particle selection in this study allowed for comparison of the fission product distribution with Ag retention, fuel type and irradiation level. Nano sized Ag-containing features were predominantly identified in SiC grain boundaries and/or triple points in contrast with only two sitings of Ag inside a SiC grain in two different compacts (Baseline and Variant 3 fueled compacts). STEM and HRTEM analysis showed evidence of Ag and Pd co-existence in some cases and it was found that fission product precipitates can consist of multiple or single phases. STEM analysis also showed differences in precipitate compositions between Baseline and Variant 3 fuels. A higher density of fission product precipitate clusters were identified in the SiC layer in particles from the Variant 3 compact compared with the Variant 1 compact. Trend analysis shows

  4. Computer-controlled gamma-ray scanner for irradiated reactor fuel

    International Nuclear Information System (INIS)

    Mandler, J.W.; Coates, R.A.; Killian, E.W.

    1979-01-01

    Gamma-ray scanning of irradiated fuel is an important nondestructive technique used in the thermal fuels behavior program currently under way at the Idaho National Engineering Laboratory. This paper is concerned with the computer-controlled isotopic gamma-ray-scanning system developed for postirradiation examination of fuel and includes a brief discussion of some scan results obtained from fuel rods irradiated in the Power-Burst Facility to illustrate gamma-ray spectrometry for this application. Both burnup profiles and information concerning fission-product migration in irradiated fuel are routinely obtained with the computer-controlled system

  5. Post-irradiation examination of overheated fuel bundles

    International Nuclear Information System (INIS)

    Sears, D.F.; Primeau, M.F.; Leach, D.A.

    1995-01-01

    Post-irradiation examinations (PIE) were conducted on prototype 43-element CANDU fuel bundles that overheated during test irradiations in the NRU reactor. PIE revealed that the bundles remained physically intact, but on several elements the Zr-4 sheath collapsed into axial gaps between the pellet stack and end caps, between adjacent pellets within the stacks, and into missing pellet chips and cracks. Helium pressurization tests showed that none of the collapsed elements leaked. Hydride blisters were discovered on a few elements, but the source of the hydrogen was not linked to a breach of the cladding or end caps. These defects were attributed to primary hydriding. Microstructural changes in the fuel and cladding indicate that the cladding-was briefly exposed to temperatures in the range 600-800 o C and pressures above 11.2 MPa. The results show that Zr-4 cladding behaves in a highly ductile manner during such transient, high-temperature and high-pressure excursions. (author)

  6. Post-irradiation examination of overheated fuel bundles

    International Nuclear Information System (INIS)

    Sears, D.F.; Primeau, M.F.; Leach, D.A.

    1997-08-01

    Post-irradiation examinations (PIE) were conducted on prototype 43-element CANDU fuel bundles that overheated during test irradiations in the NRU reactor. PIE revealed that the bundles remained physically intact, but on several elements the Zr-4 sheath collapsed into axial gaps between the pellet stack and end caps, between adjacent pellets within the stacks, and into missing pellet chips and cracks. Helium pressurization tests showed that none of the collapsed elements leaked. Hydride blisters were discovered on a few elements, but the source of the hydrogen was.not linked to a breach of the cladding or end caps. These defects were attributed to primary hydriding. Microstructural changes in the fuel and cladding indicate that the cladding was briefly exposed to temperatures in the range 600-800 o C and pressures above 11.2MPa. The results show that Zr-4 cladding behaves in a highly ductile manner during such transient, high-temperature and high-pressure excursions. (author)

  7. Design verification test of instrumented capsule (02F-11K) for nuclear fuel irradiation in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bong Goo; Sohn, J. M.; Oh, J. M. [and others

    2004-01-01

    An instrumented capsule is being developed to be able to measure fuel characteristics, such as fuel temperature, internal pressure of fuel rod, fuel elongation, and neutron flux, etc., during the irradiation test of nuclear fuel in HANARO. The instrumented capsule for measuring and monitoring fuel centerline temperature and neutron flux was designed and manufactured. The instrumented capsule includes three test fuel rods installed thermocouple to measure fuel centerline temperature and three SPNDs (Self-Powered Neutron Detector) to monitor the neutron flux. Its stability was verified by out-of-pile performance test, and its safety evaluation was also shown that the safety requirements were satisfied. And then, to verify the design of the instrumented capsule in the test hole, it was successfully irradiated in the test hole of HANARO from March 14, 2003 to June 1, 2003 (53.8 full power days at 24 MWth). During irradiation, the centerline temperature of PWR UO{sub 2} fuel pellets fabricated by KEPCO Nuclear Fuel Company and the neutron flux were continuously measured and monitored. The test fuel rods were irradiated at less than 350 W/cm to 5.13 GWD/MTU with fuel centerline peak temperature below 1,375 .deg. C. The structural stability of the capsule was satisfied by the naked eye in service pool of HANARO. The capsule and test fuel rods were dismantled and test fuel rods were examined at the hot cell of IMEF (Irradiated Material Examination Facility)

  8. Design and manufacturing of instrumented capsule(03F-05K) for nuclear fuel irradiation in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bong Goo; Sohn, J. M.; Shin, Y. T. [and others

    2004-06-01

    An instrumented capsule is being developed to be able to measure fuel characteristics, such as fuel temperature, internal pressure of fuel rod, fuel elongation, and neutron flux, etc., during the irradiation test of nuclear fuel in HANARO. The instrumented capsule(02F-11K) for measuring and monitoring fuel centerline temperature and neutron flux was designed and manufactured. The instrumented capsule includes three test fuel rods installed thermocouple to measure fuel centerline temperature and three SPNDs (self-powered neutron detector) to monitor the neutron flux. Its stability was verified by out-of-pile performance test, and its safety evaluation was also shown that the safety requirements were satisfied. And then, to verify the design of the instrumented capsule in the test hole, it was successfully irradiated in the test hole of HANARO from March 14, 2003 to June 1, 2003 (53.8 full power days at 24 MWth). During irradiation, the centerline temperature of PWR UO{sub 2} fuel pellets fabricated by KEPCO Nuclear Fuel Company and the neutron flux were continuously measured and monitored. In the year of 2004, 3 test fuel rods and the instrumented capsule(03F-05K) were designed and fabricated to measure fuel centerline temperature, internal pressure of fuel rod, and fuel axial deformation during irradiation test. This capsule is being irradiated in the test hole OR5 of HANARO reactor from April 26, 2004.

  9. Prediction of failure enthalpy and reliability of irradiated fuel rod under reactivity-initiated accidents by means of statistical approach

    International Nuclear Information System (INIS)

    Nam, Cheol; Choi, Byeong Kwon; Jeong, Yong Hwan; Jung, Youn Ho

    2001-01-01

    During the last decade, the failure behavior of high-burnup fuel rods under RIA has been an extensive concern since observations of fuel rod failures at low enthalpy. Of great importance is placed on failure prediction of fuel rod in the point of licensing criteria and safety in extending burnup achievement. To address the issue, a statistics-based methodology is introduced to predict failure probability of irradiated fuel rods. Based on RIA simulation results in literature, a failure enthalpy correlation for irradiated fuel rod is constructed as a function of oxide thickness, fuel burnup, and pulse width. From the failure enthalpy correlation, a single damage parameter, equivalent enthalpy, is defined to reflect the effects of the three primary factors as well as peak fuel enthalpy. Moreover, the failure distribution function with equivalent enthalpy is derived, applying a two-parameter Weibull statistical model. Using these equations, the sensitivity analysis is carried out to estimate the effects of burnup, corrosion, peak fuel enthalpy, pulse width and cladding materials used

  10. The Analysis of RSG-GAS Spent Fuel Elements Utilization as a Gamma Irradiator

    International Nuclear Information System (INIS)

    Pudjijanto MS; Setiyanto

    2004-01-01

    A gamma irradiator using RSG-GAS spent fuels was analyzed. The cylindrical geometry of the irradiator was designed using spent fuels placed in the cylindrical periphery. The analysis especially was focused to evaluate the feasibilities of the irradiator for foods and non-foods which need not too high dose rates. While the spent fuels activities were calculated by ORIGEN2 code, the dose rates at the irradiation positions were determined by linear attenuation model with transport coefficient. The evaluated results showed that the cylindrical geometry of the irradiator with diameter around 1-1.5 m gave the effective dose rate for irradiation needs the dose rate about 2 kGy/hr. Regarding this work, it can be concluded that one can use the unutilized spent fuels effectively as a gamma irradiator for certain applications. (author)

  11. Irradiated fuel behavior under accident heating conditions and correlation with fission gas release and swelling model (Chicago)

    International Nuclear Information System (INIS)

    Kryger, B.; Ducamp, F.; Combette, P.

    1981-08-01

    We analyse the mixed oxide fast fuel response to off normal conditions obtained by means of an out-of-pile transient simulation apparatus designed to provide direct observations (temperature, pressure, fuel motion) of fuel fission gas phenomena that might occur during the transients. The results are concerning fast transient tests (0,1 to 1 second) obtained with high gas concentration irradiated fuel (4 to 7 at % burn up, 0,4 cm 3 Xe + Kr /g.UPuO 2 ). The kinetics of fission gas release during the transients have been directly measured and then compared with the calculated results issued of the Chicago model. This model agrees, quite well, with other experiments done in the silene prompt reactor. Other gases than xenon and krypton (such as hydrogen and carbon monoxide) do not play any role in fuel behavior, since they have been completely ruled out

  12. The development of the neutron flux measurement technology using SPNDs during nuclear fuel irradiation test

    Energy Technology Data Exchange (ETDEWEB)

    Kim, B. G.; Kang, Y. H.; Cho, M. S.; Joo, K. N.; Choi, M. H.; Park, S. J.; Shin, Y. T.; Oh, J. M.; Kim, Y. J

    2004-03-01

    As a part of the development of instrumentation technologies for a nuclear fuel irradiation test in HANARO(High-flux Advanced Nuclear Application Reactor), a study is performed to measure and evaluate the neutron flux at the same position as the nuclear fuel during irradiation test using the SPND(Self Powered Neutron Detector). To perform this study, rhodium type SPNDs and amplifier are selected suitable to irradiation test, and the selected SPNDs are installed in instrumented fuel capsule(02F-11K). The irradiation test using a instrumented fuel capsule are performed in the OR5 vertical hole of HANARO for about 54 days, and SPND output signals are acquired successfully during irradiation test. Acquired SPND signals are analyzed and evaluated as a reliable data by COSMOS Code. This will be utilized for the fuel related research together with fuel center temperature and reactor operation data.

  13. Post-irradiation examinations of inert matrix nitride fuel irradiated in JMTR (01F-51A capsule)

    International Nuclear Information System (INIS)

    Iwai, Takashi; Nakajima, Kunihisa; Kikuchi, Hironobu; Honda, Junichi; Hatakeyama, Yuichi; Ono, Katsuto; Matsui, Hiroki; Arai, Yasuo

    2007-03-01

    A plutonium nitride fuel pin containing inert matrix such as ZrN and TiN was encapsulated in 01F-51A and irradiated in JMTR. Minor actinides are surrogated by plutonium. Average linear powers and burnups were 408W/cm, 30000MWd/t(Zr+Pu) [132000MWd/t-Pu] for (Zr,Pu)N and 355W/cm, 38000MWd/t(Ti+Pu) [153000MWd/t-Pu] for (TiN,PuN). The irradiated capsule was transported to Reactor Fuel Examination Facility and subjected to non-destructive and destructive post irradiation examinations. Any failure was not observed in the irradiated fuel pin. Very low fission gas release rate of about 1.6% was measured. The inner surface of cladding tube did not show any signs of chemical interaction with fuel pellet. (author)

  14. Separation of Plutonium from Irradiated Fuels and Targets

    Energy Technology Data Exchange (ETDEWEB)

    Gray, Leonard W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Holliday, Kiel S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Murray, Alice [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Thompson, Major [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Thorp, Donald T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Yarbro, Stephen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Venetz, Theodore J. [Hanford Site, Benton County, WA (United States)

    2015-09-30

    Spent nuclear fuel from power production reactors contains moderate amounts of transuranium (TRU) actinides and fission products in addition to the still slightly enriched uranium. Originally, nuclear technology was developed to chemically separate and recover fissionable plutonium from irradiated nuclear fuel for military purposes. Military plutonium separations had essentially ceased by the mid-1990s. Reprocessing, however, can serve multiple purposes, and the relative importance has changed over time. In the 1960’s the vision of the introduction of plutonium-fueled fast-neutron breeder reactors drove the civilian separation of plutonium. More recently, reprocessing has been regarded as a means to facilitate the disposal of high-level nuclear waste, and thus requires development of radically different technical approaches. In the last decade or so, the principal reason for reprocessing has shifted to spent power reactor fuel being reprocessed (1) so that unused uranium and plutonium being recycled reduce the volume, gaining some 25% to 30% more energy from the original uranium in the process and thus contributing to energy security and (2) to reduce the volume and radioactivity of the waste by recovering all long-lived actinides and fission products followed by recycling them in fast reactors where they are transmuted to short-lived fission products; this reduces the volume to about 20%, reduces the long-term radioactivity level in the high-level waste, and complicates the possibility of the plutonium being diverted from civil use – thereby increasing the proliferation resistance of the fuel cycle. In general, reprocessing schemes can be divided into two large categories: aqueous/hydrometallurgical systems, and pyrochemical/pyrometallurgical systems. Worldwide processing schemes are dominated by the aqueous (hydrometallurgical) systems. This document provides a historical review of both categories of reprocessing.

  15. Irradiation of a CANDU UOsub(2) fuel element with twenty-three machined slits cut through the zircaloy sheath

    International Nuclear Information System (INIS)

    DaSilva, R.L.

    1984-09-01

    A CANDU fuel element was purposely defected, exposing a minimum UOsub(2) fuel stack area of 272 mmsup(2), by machining 23 longitudinal slits through the Zircaloy-4 sheathing. The element was then irradiated in the X-2 loop of the NRX reactor for a period of 14.64 effective full power days at a linear heat rating of 48 kW/m to investigate the relationship between fission product release and UOsub(2) oxidation behaviour in an element with minimal fuel-to-gap fission gas trapping. The fission product releases, as measured by on-line gamma-ray spectroscopy, revealed that the noble gases and radioiodines are both released from the UOsub(2) fuel matrix directly to the coolant via simple diffusion kinetics, and that their diffusivities in hyperstoichiometric UOsub(2) are approximately equal. The oxidation of UOsub(2) to the higher states UOsub(2+x), Usub(4)Osub(9) and Usub(3)Osub(8), was accompanied by substantial fuel swelling and sheath deformation preferentially located in the lower powered end of the element. The spalling and erosion behaviour of the fuel pellets was correlated to the rate of fuel oxidation

  16. LOCA scenario tests of irradiated fuel rod specimens

    International Nuclear Information System (INIS)

    Scott, Harold

    2004-01-01

    Full text: The NRC's cladding performance program at Argonne National Laboratory (ANL) is testing fueled high-burnup segments subjected to LOCA integral phenomena. The data are provided to NRC and the nuclear industry for their independent assessment of the adequacy of licensing criteria for LOCA events. The tests are being conducted with high-burnup 30 cm segments from Limerick (9x9 Zry-2) and H.B. Robinson (15x15 Zry-4) reactors. Prior to testing, sibling samples are characterized with respect to fuel morphology, fuel-cladding bond, cladding oxide layer thickness, hydrogen content and high-temperature steam oxidation kinetics. Specimens that survive quench are subjected to four-point bend tests, followed by local diametral compression tests. The retention of post-quench ductility is a more limiting requirement than surviving thermal stresses during quench. Companion tests are conducted with unirradiated cladding to generate baseline data for comparison with the high-burnup fuel results. LOCA integral tests have the following sequential steps: stabilization of temperature, internal pressure and steam flow at 300 C, ramping of temperature (∼5C/s) through ballooning and burst to 1204 C, hold at 1204 C for 1-5 minutes, slow-cooling (∼3C/s) to 800 C, and water quenching at ∼800C. Two high-burnup tests were completed in 2002 with Limerick BWR rod segments: ramp to burst in argon followed by slow cooling; and the LOCA test with 5-minute hold time at 1204 C, followed by slow cooling. With the exception of burst-opening shape, results for burst temperature, burst pressure, burst length, and ballooning strain profile are more similar to, than different from, results for unirradiated Zry-2 cladding exposed to the same time-temperature history. The 3rd Limerick test with quench was performed in December 2003, and a 4th Limerick test was performed in March 2004. Tests on high-burnup Robinson PWR fuel segments are scheduled to begin in June 2004. The presentation points

  17. Microstructure of irradiated Inconel 706 fuel pin cladding

    International Nuclear Information System (INIS)

    Yang, W.J.S.; Makenas, B.J.

    1983-08-01

    A fuel pin from the HEDL-P-60 experiment with a cladding of solution-annealed Inconel 706 breached in an apparently brittle manner at a position 12.7 cm above the bottom of the fuel column with a crack of 5.72 cm in length after 5.0 atomic percent burnup in EBR-II. Temperatures (time-averaged midwall) and fast fluences for the fractured area range from 447 0 C and 5.5 x 10 22 n/cm 2 to 526 0 C and 6.1 x 10 22 n/cm 2 (E > 0.1 MeV). Specimens of the fractured fuel pin section were successfully prepared and examined in both a scanning electron microscope and a transmission electron microscope. The fracture surfaces of the breached section showed brittle intergranular fracture characteristics for both the axial and circumferential cracks. Formation of γ' in the matrix near the breach confirmed that the irradiation temperature at the breached area was below 500 0 C, in agreement with other estimates of the temperature for the area, 447 to 526 0 C. A hexagonal eta-phase, Ni 3 (Ti,Nb), precipitated at boundaries near the breach. A more extensive eta-phase coating at grain boundaries was found in a section irradiated at 650 0 C. The eta-phase plates at grain boundaries are expected to have a detrimental effect on alloy ductility. A plane of weakness in this region along the (111) slip planes will develop in Inconel 706 because the eta-plates have a (111) habit relationship with the matrix

  18. Influence of oxygen-metal ratio on mixed-oxide fuel performance

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Leggett, R.D.

    1979-04-01

    The fuel oxygen-to-metal ratio (O/M) is recognized as an important consideration for performance of uranium--plutonium oxide fuels. An overview of the effects of differing O/M's on the irradiation performance of reference design mixed-oxide fuel in the areas of chemical and mechanical behavior, thermal performance, and fission gas behavior is presented. The pellet fuel has a nominal composition of 75 wt% UO 2 + 25 wt% PuO 2 at a pellet density of approx. 90% TD. for nominal conditions this results in a smeared density of approx. 85%. The cladding in all cases is 20% CW type 316 stainless steel with an outer diameter of 5.84 to 6.35 mm. O/M has been found to significantly influence fuel pin chemistry, mainly FCCI and fission product and fuel migration. It has little effect on thermal performance and overall mechanical behavior or fission gas release. The effects of O/M (ranging from 1.938 to 1.984) in the areas of fuel pin chemistry, to date, have not resulted in any reduction in fuel pin performance capability to goal burnups of approx. 8 atom% or more

  19. Laser induced densification of cerium gadolinium oxide: Application to single-chamber solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Mariño, Mariana [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Rieu, Mathilde, E-mail: rieu@emse.fr [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Viricelle, Jean-Paul [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Garrelie, Florence [Université Jean Monnet, Laboratoire Hubert Curien, CNRS: UMR 5516, 42000 Saint-Etienne (France)

    2016-06-30

    Graphical abstract: - Highlights: • CGO surface densifications were induced by UV and IR laser irradiations. • Grain growth or densified cracked surfaces were observed by SEM. • UV laser treatments allow a decrease of gas permeation through electrolyte layer. • Electrical conductivity of the electrolyte was modified by laser treatments. • Grain growth of electrolyte induced by UV laser improved cell performances. - Abstract: In single-chamber solid oxide fuel cells (SC-SOFC), anode and cathode are placed in a gas chamber where they are exposed to a fuel/air mixture. Similarly to conventional dual-chamber SOFC, the anode and the cathode are separated by an electrolyte. However, as in the SC-SOFC configuration the electrolyte does not play tightness role between compartments, this one can be a porous layer. Nevertheless, it is necessary to have a diffusion barrier to prevent the transportation of hydrogen produced locally at the anode to the cathode that reduces fuel cell performances. This study aims to obtain directly a diffusion barrier through the surface densification of the electrolyte Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} (CGO) by a laser treatment. KrF excimer laser and Yb fiber laser irradiations were used at different fluences and number of pulses to modify the density of the electrolyte coating. Microstructural characterizations confirmed the modifications on the surface of the electrolyte for appropriate experimental conditions showing either grain growth or densified but cracked surfaces. Gas permeation and electrical conductivities of the modified electrolyte were evaluated. Finally SC-SOFC performances were improved for the cells presenting grain growth at the electrolyte surface.

  20. Fabrication of Non-instrumented capsule for DUPIC simulated fuel irradiation test in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Kim, B.G.; Kang, Y.H.; Park, S.J.; Shin, Y.T. [Korea Atomic Energy Research Institute, Taejon (Korea)

    1999-10-01

    In order to develope DUPIC nuclear fuel, the irradiation test for simulated DUPIC fuel was planed using a non-instrumented capsule in HANARO. Because DUPIC fuel is highly radioactive material the non-instrumented capsule for an irradiation test of simulated DUPIC fuel in HANARO was designed to remotely assemble and disassemble in hot cell. And then, according to the design requirements the non-instrumented DUPIC capsule was successfully manufactured. Also, the manufacturing technologies of the non-instrumented capsule for irradiating the nuclear fuel in HANARO were established, and the basic technology for the development of the instrumented capsule technology was accumulated. This report describes the manufacturing of the non-instrumented capsule for simulated DUPIC fuel. And, this report will be based to develope the instrumented capsule, which will be utilized to irradiate the nuclear fuel in HANARO. 26 refs., 4 figs. (Author)

  1. Post-irradiation examinations of uranium-plutonium mixed nitride fuel irradiated in JMTR (89F-3A capsule)

    International Nuclear Information System (INIS)

    Iwai, Takashi; Nakajima, Kunihisa; Kikuchi, Hironobu; Arai, Yasuo; Kimura, Yasuhiko; Nagashima, Hisao; Sekita, Noriaki

    2000-03-01

    Two helium-bonded fuel pins filled with uranium-plutonium mixed nitride pellets were encapsulated in 89F-3A and irradiated in JMTR up to 5.5% FIMA at a maximum linear power of 73 kW/m. The capsule cooled for ∼5 months was transported to Reactor Fuel Examination Facility and subjected to non-destructive and destructive post irradiation examinations. Any failure was not observed in the irradiated fuel pins. Very low fission gas release rate of about 2 ∼ 3% was observed, while the diametric increase of fuel pin was limited to ∼0.4% at the position of maximum reading. The inner surface of cladding tube did not show any signs of chemical interaction with fuel pellet. (author)

  2. The post-irradiated examination of CANDU type fuel irradiated in the Institute for Nuclear Research TRIGA reactor

    International Nuclear Information System (INIS)

    Tuturici, I.L.; Parvan, M.; Dobrin, R.; Popov, M.; Radulescu, R.; Toma, V.

    1995-01-01

    This post-irradiation examination work has been done under the Research Contract No. 7756/RB, concluded between the International Atomic Energy Agency and the Institute for Nuclear Research. The paper contains a general description of the INR post-irradiation facility and methods and the relevant post-irradiation examination results obtained from an irradiated experimental CANDU type fuel element designed, manufactured and tested by INR in a power ramp test in the 100 kW Pressurised Water Irradiation Loop of the TRIGA 14 MW(th) Reactor. The irradiation experiment consisted in testing an assembly of six fuel elements, designed to reach a bumup of ∼ 200 MWh/kgU, with typical CANDU linear power and ramp rate. (author)

  3. Fabrication and characterization of oxide type fluorite with controlled porosity to study the mechanical behaviour of the fuel irradiated in storage conditions; Fabricacion y caracterizacion de oxidos tipo fluorita con porosidad controlada para estudiar el comportamiento mecanico del combustible irradiado en condiciones de almacenamiento

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, S.; Borjas, S.; Gutierrez, L.; Bonales, L. J.; Rodriguez, N.; Cobo, J. M.; Torres, Y.; Cobos, J.

    2014-07-01

    The objective of this research is to get pills with distribution of porosity to simulate mechanical properties in the irradiated fuel resulting from own burnt of the material to produce the release of fission gases. (Author)

  4. Irradiation temperature dependence of production efficiency of lattice defects in some neutron-irradiated oxides

    International Nuclear Information System (INIS)

    Okada, Moritami; Atobe, Kozo; Nakagawa, Masuo

    2004-01-01

    Temperature dependence of production efficiency of irradiation-induced defects in neutron-irradiated oxides has been investigated. Some oxide single crystals, MgO, α-Al 2 O 3 (sapphire) and TiO 2 (rutile), were irradiated at several controlled temperatures, 10, 20, 50, 100, 150 and 200 K, using the low-temperature irradiation facility of Kyoto University Reactor (KUR-LTL), and at ambient temperature (∼370 K) in the same facility. Irradiation temperature dependence of production efficiency of a 1 μm band in TiO 2 differs greatly from that of anion vacancy (F-type centers) in MgO and α-Al 2 O 3 . Results for MgO and α-Al 2 O 3 show steep negative gradients from 10 to 370 K, whereas that for TiO 2 includes a valley between 40 and 60 K and a hump at about 130 K, and then disappear at about 200 K. In MgO and α-Al 2 O 3 , this behavior can be explained by the recombination of Frenkel pairs, which is activated at higher temperature. In TiO 2 , in addition to the recombination mechanism, a covalent bonding property is thought to be exerted strong influence, and it is suggested that a disappearance of the 1 μm band at above 200 K is due to the recombination process of Frenkel pairs which is caused by the irradiation-induced crystallization

  5. A recommendation for the thermal conductivity of oxide fuels

    International Nuclear Information System (INIS)

    Kang, K. H.; Ryu, H. J.; Song, K. C.; Yang, M. S.; Na, S. H.; Lee, Y. W.; Moon, H. S.; Kim, H. S.

    2004-01-01

    The thermal conductivity of nuclear fuel is one of the most important properties because it affects the fuel operating temperature. Therefore, it influences almost all the important processes occurred in nuclear fuel during irradiation, such as gas release, swelling and grain growth. The model of the thermal conductivity of nuclear fuel should be used in the codes to evaluate the performance of it analytically and be required in the nuclear fuel research and development. The thermal conductivity, k, of UO 2 depends on the deviation from stoichiometry, x, the burnup, b, and the fractional porosity, p, as well as the temperature, T: k = k(x, b, p, T), (1) Changes in thermal conductivity occur during irradiation because of fission-gas bubble formation, pores, cracks, fission product build-up and possible changes in the oxygen to uranium ratio (O/U). The dependence on temperature and porosity has been well studied and incorporated in computer codes used for the in-pile fuel behavior analysis. There are several studies on the effect of impurity on the thermal conductivity of UO 2 . In this paper, the variables affected on the thermal conductivity were studied. The available data of the thermal conductivity of UO 2 , UO 2+x , (U, Pu)O 2 , (U, Pu)O 2 and simulated fuel for irradiation fuel were reviewed and analyzed. The best models were recommended

  6. Performance of IN-706 and PE-16 cladding in mixed-oxide fuel pins

    International Nuclear Information System (INIS)

    Makenas, B.J.; Lawrence, L.A.; Jensen, B.W.

    1982-05-01

    Iron-nickel base, precipitation-strengthened alloys, IN-706 and PE-16, advanced alloy cladding considered for breeder reactor applications, were irradiated in mixed-oxide fuel pins in the HEDL-P-60 subassembly in EBR-II. Initial selection of candidate advanced alloys was done using only nonfueled materials test results. However, to establish the performance characteristics of the candidate cladding alloys, i.e., dimensional stability and structural integrity under conditions of high neutron flux, elevated temperature, and applied stress, it was necessary to irradiate fuel pins under typical operating conditions. Fuel pins were clad with solution treated IN-706 and PE-16 and irradiated to peak fluences of 6.1 x 10 22 n/cm 2 (E > .1 MeV) and 8.8 x 10 22 n/cm 2 (E > .1 MeV) respectively. Fabrication and operating parameters for the fuel pins with the advanced cladding alloy candidates are summarized. Irradiation of HEDL-P-60 was interrupted with the breach of a pin with IN-706 cladding at 5.1 at % and the test was terminated with cladding breach in a pin with PE-16 cladding at 7.6 at %

  7. Development of advanced mixed oxide fuels for plutonium management

    International Nuclear Information System (INIS)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-06-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium

  8. Development of advanced mixed oxide fuels for plutonium management

    International Nuclear Information System (INIS)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-01-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium. (author)

  9. Physicochemical analysis of interaction of oxide fuel with pyrocarbon coatings of fuel particles

    International Nuclear Information System (INIS)

    Lyutikov, R.A.; Khromov, Yu.F.; Chernikov, A.S.

    1990-01-01

    Equilibrium pressure of (CO+Kr,Xe) gases inside fuel particle with oxide kern depending on design features of fuel particle, on temperature. on (O/U) initial composition and fuel burnup is calculated using the suggested model. Analysis of possibility for gas pressure reduction by means of uranium carbide alloying of kern and degree increase of solid fission product retention (Cs for example) during alumosilicate alloying of uranium oxide is conducted

  10. Reliability of fast reactor mixed-oxide fuel during operational transients

    International Nuclear Information System (INIS)

    Boltax, A.; Neimark, L.A.; Tsai, Hanchung; Katsuragawa, M.; Shikakura, S.

    1991-07-01

    Results are presented from the cooperative DOE and PNC Phase 1 and 2 operational transient testing programs conducted in the EBR-2 reactor. The program includes second (D9 and PNC 316 cladding) and third (FSM, AST and ODS cladding) generation mixed-oxide fuel pins. The irradiation tests include duty cycle operation and extended overpower tests. the results demonstrate the capability of second generation fuel pins to survive a wide range of duty cycle and extended overpower events. 15 refs., 9 figs., 4 tabs

  11. Characterization of an irradiated RERTR-7 fuel plate using transmission electron microscopy

    International Nuclear Information System (INIS)

    Gan, J.; Keiser, D.D. Jr.; Miller, B.D.; Robinson, A.B.; Medvedev, P.

    2010-01-01

    Transmission electron microscopy (TEM) has been used to characterize an irradiated fuel plate with Al-2Si matrix from the Reduced Enrichment Research and Test Reactor RERTR-7 experiment that was irradiated under moderate reactor conditions. The results of this work showed the presence of a bubble superlattice within the U-7Mo grains that accommodated fission gases (e.g., Xe). The presence of this structure helps the U-7Mo exhibit a stable swelling behaviour during irradiation. Furthermore, TEM analysis showed that the Si-rich interaction layers that develop around the fuel particles at the U-7Mo/matrix interface during fuel plate fabrication and irradiation become amorphous during irradiation. An important question that remains to be answered about the irradiation behaviour of U-Mo dispersion fuels is how do more aggressive irradiation conditions affect the behaviour of fission gases within the U-7Mo fuel particles and in the amorphous interaction layers on the microstructural scale that can be characterized using TEM? This paper will discuss the results of TEM analysis that was performed on a sample taken from an irradiated RERTR-7 fuel plate with Al-2Si matrix. This plate was exposed to more aggressive irradiation conditions than the RERTR-6 plate. The microstructural features present within the U-7Mo and the amorphous interaction layers will be discussed. The results of this analysis will be compared to what was observed in the earlier RERTR-6 fuel plate characterization. (author)

  12. EDRP public local inquiry, UKAEA/BNFL precognition on: the transport of irradiated fuel by rail

    International Nuclear Information System (INIS)

    Singleton, Leslie

    1986-02-01

    The experience in handling of irradiated fuel flasks by the British Railways Board is outlined. The steps taken to ensure the effective and safe transport of irradiated fuel and nuclear waste by rail are identified. It is concluded that the proposed rail transport link to the EDRP at Dounreay should prove practicable. (UK)

  13. Preliminary test results for post irradiation examination on the HTTR fuel

    International Nuclear Information System (INIS)

    Ueta, Shohei; Umeda, Masayuki; Sawa, Kazuhiro; Sozawa, Shizuo; Shimizu, Michio; Ishigaki, Yoshinobu; Obata, Hiroyuki

    2007-01-01

    The future post-irradiation program for the first-loading fuel of the HTTR is scheduled using the HTTR fuel handling facilities and the Hot Laboratory in the Japan Materials Testing Reactor (JMTR) to confirm its irradiation resistance and to obtain data on its irradiation characteristics in the core. This report describes the preliminary test results and the future plan for a post-irradiation examination for the HTTR fuel. In the preliminary test, fuel compacts made with the same SiC-coated fuel particle as the first loading fuel were used. In the preliminary test, dimension, weight, fuel failure fraction, and burnup were measured, and X-ray radiograph, SEM, and EPMA observations were carried out. Finally, it was confirmed that the first-loading fuel of the HTTR showed good quality under an irradiation condition. The future plan for the post-irradiation tests was described to confirm its irradiation performance and to obtain data on its irradiation characteristics in the HTTR core. (author)

  14. Sealing materials for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, P.H.

    1999-02-01

    A major obstacle in the achievement of high electrical efficiency for planar solid oxide fuel cell stacks (SOFC) is the need for long term stable seals at the operational temperature between 850 and 1000 deg. C. In the present work the formation and properties of sealing materials for SOFC stacks that fulfil the necessary requirements were investigated. The work comprises analysis of sealing material properties independently, in simple systems as well as tests in real SOFC stacks. The analysed sealing materials were based on pure glasses or glass-ceramic composites having B{sub 2}O{sub 3}, P{sub 2}O{sub 5} or siO{sub 2} as glass formers, and the following four glass systems were investigated: MgO/caO/Cr{sub 2}O{sub 3}-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}-P{sub 2}O{sub 5}, MgO-Al{sub 2}O{sub 3}-P{sub 2}O{sub 5}, MgO-Al{sub 2}O{sub 3}-P{sub 2}O{sub 5}-SiO{sub 2} and BaO/Na{sub 2}O-Al{sub 2}O{sub 3}-SiO{sub 2}. (au) 32 tabs., 106 ills., 107 refs.

  15. VHTR-fuel irradiation capsules for VT-1 hole of JRR-2

    International Nuclear Information System (INIS)

    Kikuchi, Teruo; Kikuchi, Akira; Tobita, Tsutomu; Kashimura, Satoru; Miyasaka, Yasuhiko

    1977-02-01

    Irradiations of VHTR fuels were made in the VT-1 irradiation hole of JRR-2. Three capsules, VP-1, VP-2 and VP-4, which contained fuel compacts, were irradiated for 300 hr at temperatures of 950 0 , 1370 0 and 1500 0 C up to the estimated burn-ups of 0.74, 0.87 and 0.80%FIMA, respectively. And, to study the amoeba effect of fuel particles, two capsules, VP-3 and VP-5, were irradiated for 300 hr at temperatures of 1650 0 and 1670 0 C up to the estimated burn-ups of 0.38 and 0.33%FIMA, respectively. (auth.)

  16. Dry Storage at long term of nuclear fuels: Influence of the fuel design and commercial irradiation conditions

    International Nuclear Information System (INIS)

    Marino, Armando C

    2009-01-01

    The BaCo code was applied to simulate the behaviour for a PHWR fuel under storage conditions showing a strong dependence on the original design of the fuel and the irradiation history. In particular, the results of the statistical analysis of BaCo indicate that the integrity of the fuel is influenced by the manufacture tolerances and the solicitations during the NPP irradiation. The main conclusion of the present study is that the fuel temperature of the device should be carefully controlled in order to ensure safe storage conditions. [es

  17. Structural analysis of nickel doped cerium oxide catalysts for fuel reforming in solid oxide fuel cells

    Science.gov (United States)

    Cavendish, Rio

    As world energy demands increase, research into more efficient energy production methods has become imperative. Heterogeneous catalysis and nanoscience are used to promote chemical transformations important for energy production. These concepts are important in solid oxide fuel cells (SOFCs) which have attracted attention because of their potential to provide an efficient and environmentally favorable power generation system. The SOFC is also fuel-flexible with the ability to run directly on many fuels other than hydrogen. Internal fuel reforming directly in the anode of the SOFC would greatly reduce the cost and complexity of the device. Methane is the simplest hydrocarbon and a main component in natural gas, making it useful when testing catalysts on the laboratory scale. Nickel (Ni) and gadolinium (Gd) doped ceria (CeO 2) catalysts for potential use in the SOFC anode were synthesized with a spray drying method and tested for catalytic performance using partial oxidation of methane and steam reforming. The relationships between catalytic performance and structure were then investigated using X-ray diffraction, transmission electron microscopy, and environmental transmission electron microscopy. The possibility of solid solutions, segregated phases, and surface layers of Ni were explored. Results for a 10 at.% Ni in CeO2 catalyst reveal a poor catalytic behavior while a 20 at.% Ni in CeO2 catalyst is shown to have superior activity. The inclusion of both 10 at.% Gd and 10 at.% Ni in CeO2 enhances the catalytic performance. Analysis of the presence of Ni in all 3 samples reveals Ni heterogeneity and little evidence for extensive solid solution doping. Ni is found in small domains throughout CeO2 particles. In the 20 at.% Ni sample a segregated, catalytically active NiO phase is observed. Overall, it is found that significant interaction between Ni and CeO2 occurs that could affect the synthesis and functionality of the SOFC anode.

  18. Recycling of nuclear fuel swarf at the fabrication of UO sub(2)-pellets and its influence on the irradiation behavior

    International Nuclear Information System (INIS)

    Dias, M.S.; Lameiras, F.S.; Santos, A.M.M. dos

    1991-01-01

    From the fabrication of UO sub(2) pellets for light water reactor fuel rods, nuclear fuel scraps results in form of UO sub(2) grinding swarf and UO sub(2) sinter scraps oxidized to U sub(3)O sub(8) powder. Detailed investigations on five types of UO sub(2) pellets fabricated with different portions of this scrap kinds added to the UO sub(2) press powder showed that there is only a small influence of such scrap additions on the irradiation behavior, especially for the fission gas release. This allows to recycle the fabrication scrap in a simple and economic way. (author)

  19. Oxidation of nuclear fuel below 400 deg. Consequence on long-term dry storage

    International Nuclear Information System (INIS)

    Dehaudt, Ph.

    2000-01-01

    This document reviews the status of the knowledge on the oxidation of fuels below 400 deg C, in all its forms, including fuel rods, by examining the consequences of this reaction on the strength or ruin of the fuel rods during dry storage in air for a hundred years. The data available in the scientific literature, and the data acquired by CEA, are abundant on irradiated powders and pellets, but sparser for irradiated fuel fragments and for rods or sections of fuel rods. A bibliographic review is made to identify the morphological and structural changes, as well as the kinetic laws. An analysis and a summary is made with a concern to evaluate the risks of rod ruin by oxidation. The final section, in a few pages, addresses the essential lessons from this study. It presents: first, a summary of the main results of this review and its analysis, recommendations and remedies for storage; proposed research guidelines as well as precise topics, in order to fill out our knowledge and, even better, to identify the acceptable limits for storage. (author)

  20. Desulfurization of Diesel Fuel by Oxidation and Solvent Extraction

    Directory of Open Access Journals (Sweden)

    Wadood Taher Mohammed

    2015-02-01

    Full Text Available This research presents a study in ultra-desulfurization of diesel fuel produced from conventional hydro desulfurization process, using oxidation and solvent extraction techniques. Dibenzothiophene (DBT was the organosulfur compound that had been detected in sulfur removal. The oxidation process used hydrogen peroxide as an oxidant and acetic acid as homogeneous catalyst . The solvent extraction process used acetonitrile (ACN and N-methyl – 2 - pyrrolidone (NMP as extractants . Also the effect of five parameters (stirring speed :150 , 250 , 350 , and 450 rpm, temperature (30 , 40 , 45 , and 50 oC, oxidant/simulated diesel fuel ratio (0.5 , 0.75 , 1 , and 1.5 , catalyst/oxidant ratio(0.125,0.25,0.5,and0.75 , and solvent/simulated diesel fuel ratio(0.5,0.6,0.75,and1 were examined as well as solvent type. The results exhibit that the highest removal of sulfur is 98.5% using NMP solvent while it is 95.8% for ACN solvent. The set of conditions that show the highest sulfur removal is: stirring speed of 350 rpm , temperature 50oC , oxidant/simulated diesel fuel ratio 1 , catalyst/oxidant ratio 0.5 , solvent/simulated diesel fuel ratio 1. These best conditions were applied upon real diesel fuel (produced from Al-Dora refinerywith 1000 ppm sulfur content . It was found that sulfur removal was 64.4% using ACN solvent and 75% using NMP solvent.

  1. Formation of actinides in irradiated HTGR fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    dos Santos, A. M.

    1976-03-15

    Actinide nuclide concentrations of 11 spent AVR fuel elements were determined experimentally. The burnup of the spheres varied in the range between 10% and 100% fifa, the Th : U ratio was 5 : 1. The separation procedures for an actinide isolation were tested with highly irradiated ThO/sub 2/. Separation and decontamination factors are presented. Build-up of /sup 232/U was discussed. The AVR breeding rate was ascertained to be 0.5. The hazard potential of high activity waste was calculated. Actinide recovery factors were proposed in order to reduce the hazard potential of the waste by an actinide removal under consideration of the reprocessing technology which is available presently.

  2. Gas Generation from K East Basin Sludges and Irradiated Metallic Uranium Fuel Particles Series III Testing

    International Nuclear Information System (INIS)

    Schmidt, Andrew J.; Delegard, Calvin H.; Bryan, Samuel A.; Elmore, Monte R.; Sell, Rachel L.; Silvers, Kurt L.; Gano, Susan R.; Thornton, Brenda M.

    2003-01-01

    The path forward for managing of Hanford K Basin sludge calls for it to be packaged, shipped, and stored at T Plant until final processing at a future date. An important consideration for the design and cost of retrieval, transportation, and storage systems is the potential for heat and gas generation through oxidation reactions between uranium metal and water. This report, the third in a series (Series III), describes work performed at the Pacific Northwest National Laboratory (PNNL) to assess corrosion and gas generation from irradiated metallic uranium particles (fuel particles) with and without K Basin sludge addition. The testing described in this report consisted of 12 tests. In 10 of the tests, 4.3 to 26.4 g of fuel particles of selected size distribution were placed into 60- or 800-ml reaction vessels with 0 to 100 g settled sludge. In another test, a single 3.72-g fuel fragment (i.e., 7150-mm particle) was placed in a 60 ml reaction vessel with no added sludge. The twelfth test contained only sludge. The fuel particles were prepared by crushing archived coupons (samples) from an irradiated metallic uranium fuel element. After loading the sludge materials (whether fuel particles, mixtures of fuel particles and sludge, or sludge-only) into reaction vessels, the solids were covered with an excess of K Basin water, the vessels closed and connected to a gas measurement manifold, and the vessels back-flushed with inert neon cover gas. The vessels were then heated to a constant temperature. The gas pressures and temperatures were monitored continuously from the times the vessels were purged. Gas samples were collected at various times during the tests, and the samples analyzed by mass spectrometry. Data on the reaction rates of uranium metal fuel particles with water as a function of temperature and particle size were generated. The data were compared with published studies on metallic uranium corrosion kinetics. The effects of an intimate overlying sludge layer

  3. performance calculations of gadolinium oxide and boron nitride coated fuel

    International Nuclear Information System (INIS)

    Tanker, E.; Uslu, I.; Disbudak, H.; Guenduez, G.

    1997-01-01

    A comparative study was performed on the behaviour of natural uranium dioxide-gadolinium oxide mixture fuel and boron nitride coated low enriched fuel in a pressurized water reactor. A fuel element containing one burnable poison fuel pins was modeled with the computer code WIMS, and burn-up dependent critically, fissile isotope inventory and two dimensional power distribution were obtained. Calculations were performed for burnable poison fuels containing 5% and 10% gadolinium oxide and for those coated with 1μ,5μ and 10μ of boron nitride. Boron nitride coating was found superior to gadolinium oxide on account of its smoother criticality curve, lower power peaks and insignificant change in fissile isotope content