WorldWideScience

Sample records for oxide fuel characteristics

  1. Integrated Solid Oxide Fuel Cell Power System Characteristics Prediction

    Directory of Open Access Journals (Sweden)

    Marian GAICEANU

    2009-07-01

    Full Text Available The main objective of this paper is to deduce the specific characteristics of the CHP 100kWe Solid Oxide Fuel Cell (SOFC Power System from the steady state experimental data. From the experimental data, the authors have been developed and validated the steady state mathematical model. From the control room the steady state experimental data of the SOFC power conditioning are available and using the developed steady state mathematical model, the authors have been obtained the characteristic curves of the system performed by Siemens-Westinghouse Power Corporation. As a methodology the backward and forward power flow analysis has been employed. The backward power flow makes possible to obtain the SOFC power system operating point at different load levels, resulting as the load characteristic. By knowing the fuel cell output characteristic, the forward power flow analysis is used to predict the power system efficiency in different operating points, to choose the adequate control decision in order to obtain the high efficiency operation of the SOFC power system at different load levels. The CHP 100kWe power system is located at Gas Turbine Technologies Company (a Siemens Subsidiary, TurboCare brand in Turin, Italy. The work was carried out through the Energia da Ossidi Solidi (EOS Project. The SOFC stack delivers constant power permanently in order to supply the electric and thermal power both to the TurboCare Company and to the national grid.

  2. Sensitivity analysis of characteristics of spent mixed oxide fuel

    International Nuclear Information System (INIS)

    Hagura, Naoto; Yoshida, Tadashi

    2008-01-01

    Prediction error was evaluated for decay heat and nuclide generation in spent mixed oxide (MOX) fuels on the basis of error files in JENDL-3.3. This computational analysis was performed using SWAT code system, ORIGEN2 code, and ERRORJ code. The results of nuclide generation error evaluation were compared with some discrepancies in the calculated values to experimental values (C/E ratio) which were already published and were obtained by analysis of post irradiated experiments (PIE) data. Though the discrepancies of some C/E values, especially those of americium and curium isotopes, ranged from a half to twice, the present error evaluation based on the error file of nuclide generation became 10% or less. We conclude that the discrepancy between calculation and the PIE data is almost factor 5 larger than that evaluated from the covariance data in JENDL-3.3. Therefore the practical error value of total decay heat should be 20% or more on 1 σ basis. (authors)

  3. Sensitivity analysis of characteristics of spent mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Hagura, Naoto; Yoshida, Tadashi [Musashi Institute of Technology, 1-28-1 Tamazutsumi, Setagaya, Tokyo 158-8557 (Japan)

    2008-07-01

    Prediction error was evaluated for decay heat and nuclide generation in spent mixed oxide (MOX) fuels on the basis of error files in JENDL-3.3. This computational analysis was performed using SWAT code system, ORIGEN2 code, and ERRORJ code. The results of nuclide generation error evaluation were compared with some discrepancies in the calculated values to experimental values (C/E ratio) which were already published and were obtained by analysis of post irradiated experiments (PIE) data. Though the discrepancies of some C/E values, especially those of americium and curium isotopes, ranged from a half to twice, the present error evaluation based on the error file of nuclide generation became 10% or less. We conclude that the discrepancy between calculation and the PIE data is almost factor 5 larger than that evaluated from the covariance data in JENDL-3.3. Therefore the practical error value of total decay heat should be 20% or more on 1 sigma basis. (authors)

  4. Characteristics of SME biodiesel-fueled diesel particle emissions and the kinetics of oxidation.

    Science.gov (United States)

    Jung, Heejung; Kittelson, David B; Zachariah, Michael R

    2006-08-15

    Biodiesel is one of the most promising alternative diesel fuels. As diesel emission regulations have become more stringent, the diesel particulate filter (DPF) has become an essential part of the aftertreatment system. Knowledge of kinetics of exhaust particle oxidation for alternative diesel fuels is useful in estimating the change in regeneration behavior of a DPF with such fuels. This study examines the characteristics of diesel particulate emissions as well as kinetics of particle oxidation using a 1996 John Deere T04045TF250 off-highway engine and 100% soy methyl ester (SME) biodiesel (B100) as fuel. Compared to standard D2 fuel, this B100 reduced particle size, number, and volume in the accumulation mode where most of the particle mass is found. At 75% load, number decreased by 38%, DGN decreased from 80 to 62 nm, and volume decreased by 82%. Part of this decrease is likely associated with the fact that the particles were more easily oxidized. Arrhenius parameters for the biodiesel fuel showed a 2-3times greater frequency factor and approximately 6 times higher oxidation rate compared to regular diesel fuel in the range of 700-825 degrees C. The faster oxidation kinetics should facilitate regeneration when used with a DPF.

  5. Shippingport LWBR (Th/U Oxide) Fuel Characteristics for Disposal Criticality Analysis

    International Nuclear Information System (INIS)

    Taylor, L. L.; Loo, H. H.

    1999-01-01

    Department of Energy (DOE)-owned spent nuclear fuels encompass many fuel types. In an effort to facilitate criticality analysis for these various fuel types, they were categorized into eight characteristic fuel groups with emphasis on fuel matrix composition. Out of each fuel group, a representative fuel type was chosen for analysis as a bounding case within that fuel group. Generally, burnup data, fissile enrichments, and total fuel and fissile mass govern the selection of the representative or candidate fuel within that group. The Shippingport Light Water Breeder Reactor (LWBR) fuels incorporate more of the conventional materials (zirconium cladding/heavy metal oxides) and fabrication details (rods and spacers) that make them comparable to a typical commercial fuel assembly. The LWBR seed/blanket configuration tested a light-water breeder concept with Th-232/U-233 binary fuel matrix. Reactor design used several assembly configurations at different locations within the same core . The seed assemblies contain the greatest fissile mass per (displaced) unit volume, but the blanket assemblies actually contain more fissile mass in a larger volume; the atom-densities are comparable

  6. Plant Characteristics of an Integrated Solid Oxide Fuel Cell Cycle and a Steam Cycle

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2010-01-01

    Plant characteristics of a system containing a solid oxide fuel cell (SOFC) cycle on the top of a Rankine cycle were investigated. Natural gas (NG) was used as the fuel for the plant. A desulfurization reactor removes the sulfur content in the fuel, while a pre-reformer broke down the heavier...... recovery steam generator (HRSG). The remaining energy of the off-gases was recycled back to the topping cycle for further utilization. Several parameter studies were carried out to investigate the sensitivity of the suggested plant. It was shown that the operation temperature of the desulfurization unit...

  7. Plant characteristics of an integrated solid oxide fuel cell cycle and a steam cycle

    International Nuclear Information System (INIS)

    Rokni, Masoud

    2010-01-01

    Plant characteristics of a system containing a solid oxide fuel cell (SOFC) cycle on the top of a Rankine cycle were investigated. A desulfurization reactor removes the sulfur content in the fuel, while a pre-reformer broke down the heavier hydrocarbons in an adiabatic steam reformer (ASR). The pre-treated fuel then entered to the anode side of the SOFC. The remaining fuels after the SOFC stacks entered a catalytic burner for further combusting. The burned gases from the burner were then used to produce steam for the Rankine cycle in a heat recovery steam generator (HRSG). The remaining energy of the off-gases was recycled back to the topping cycle for further utilization. Several parameter studies were carried out to investigate the sensitivity of the suggested plant. It was shown that the operation temperature of the desulfurization and the pre-reformer had no effect on the plant efficiency, which was also true when decreasing the anode temperature. However, increasing the cathode temperature had a significant effect on the plant efficiency. In addition, decreasing the SOFC utilization factor from 0.8 to 0.7, increases the plant efficiency by about 6%. An optimal plant efficiency of about 71% was achieved by optimizing the plant.

  8. Plant characteristics of an integrated solid oxide fuel cell cycle and a steam cycle

    Energy Technology Data Exchange (ETDEWEB)

    Rokni, Masoud [Technical University of Denmark, Dept. of Mechanical Engineering, Thermal Energy System, Building 402, 2800 Kgs, Lyngby (Denmark)

    2010-12-15

    Plant characteristics of a system containing a solid oxide fuel cell (SOFC) cycle on the top of a Rankine cycle were investigated. A desulfurization reactor removes the sulfur content in the fuel, while a pre-reformer broke down the heavier hydrocarbons in an adiabatic steam reformer (ASR). The pre-treated fuel then entered to the anode side of the SOFC. The remaining fuels after the SOFC stacks entered a catalytic burner for further combusting. The burned gases from the burner were then used to produce steam for the Rankine cycle in a heat recovery steam generator (HRSG). The remaining energy of the off-gases was recycled back to the topping cycle for further utilization. Several parameter studies were carried out to investigate the sensitivity of the suggested plant. It was shown that the operation temperature of the desulfurization and the pre-reformer had no effect on the plant efficiency, which was also true when decreasing the anode temperature. However, increasing the cathode temperature had a significant effect on the plant efficiency. In addition, decreasing the SOFC utilization factor from 0.8 to 0.7, increases the plant efficiency by about 6%. An optimal plant efficiency of about 71% was achieved by optimizing the plant. (author)

  9. Uranium plutonium oxide fuels

    International Nuclear Information System (INIS)

    Cox, C.M.; Leggett, R.D.; Weber, E.T.

    1981-01-01

    Uranium plutonium oxide is the principal fuel material for liquid metal fast breeder reactors (LMFBR's) throughout the world. Development of this material has been a reasonably straightforward evolution from the UO 2 used routinely in the light water reactor (LWR's); but, because of the lower neutron capture cross sections and much lower coolant pressures in the sodium cooled LMFBR's, the fuel is operated to much higher discharge exposures than that of a LWR. A typical LMFBR fuel assembly is shown. Depending on the required power output and the configuration of the reactor, some 70 to 400 such fuel assemblies are clustered to form the core. There is a wide variation in cross section and length of the assemblies where the increasing size reflects a chronological increase in plant size and power output as well as considerations of decreasing the net fuel cycle cost. Design and performance characteristics are described

  10. Oxidation Characteristics and Electrical Properties of Doped Mn-Co Spinel Reaction Layer for Solid Oxide Fuel Cell Metal Interconnects

    Directory of Open Access Journals (Sweden)

    Pingyi Guo

    2018-01-01

    Full Text Available To prevent Cr poisoning of the cathode and to retain high conductivity during solid oxide fuel cell (SOFC operation, Cu or La doped Co-Mn coatings on a metallic interconnect is deposited and followed by oxidation at 750 °C. Microstructure and composition of coatings after preparation and oxidation is analyzed by X-ray diffraction (XRD and scanning electron microscopy (SEM. High energy micro arc alloying process, a low cost technique, is used to prepare Cu or La doped Co-Mn coatings with the metallurgical bond. When coatings oxidized at 750 °C in air for 20 h and 100 h, Co3O4 is the main oxide on the surface of Co-38Mn-2La and Co-40Mn coatings, and (Co,Mn3O4 spinel continues to grow with extended oxidation time. The outmost scales of Co-33Mn-17Cu are mainly composed of cubic MnCo2O4 spinel with Mn2O3 after oxidation for 20 h and 100 h. The average thickness of oxide coatings is about 60–70 μm after oxidation for 100 h, except that Co-40Mn oxide coatings are a little thicker. Area-specific resistance of Cu/La doped Co-Mn coatings are lower than that of Co-40Mn coating. (Mn,Co3O4/MnCo2O4 spinel layer is efficient at blocking the outward diffusion of chromium and iron.

  11. Analysis on Propagation Characteristics and Experimental Verification of A1 Circumferential Waves in Nuclear Fuel Rods Coated with Oxide Layers

    International Nuclear Information System (INIS)

    Joo, Young Sang; Jung, Hyun Kyu; Cheong, Yong Moo; Ih, Jeong Guon

    1999-01-01

    The resonance scattering of acoustic waves from the cylindrical shells of nuclear fuel rods coated with oxide layers has been theoretically modeled and numerically analyzed for the propagation characteristics of the circumferential waves. The normal mode solutions of the scattering pressure of the coated shells have been obtained. The pure resonance components have been isolated using the newly proposed inherent background coefficients. The propagation characteristics of resonant circumferential waves for the shells coated with oxide layers are affected by the presence and the thickness of an oxide layer. The characteristics have been experimentally confirmed through the method of isolation and identification of resonances. The change of the phase velocity of the A 1 circumferential wave mode for the coated shell is negligible at the specified partial waves in spite of the presence of the oxide layer and the increase in coating thickness. Utilizing the invariability characteristics of the phase velocity of the A 1 mode, the oxide layer thickness of the coated shells can be estimated. A new nondestructive technique for the relative measurement of the coating thickness of coated shells has been proposed

  12. Internal fuel pin oxidizer

    International Nuclear Information System (INIS)

    Andrews, M.G.

    1978-01-01

    A nuclear fuel pin has positioned within it material which will decompose to release an oxidizing agent which will react with the cladding of the pin and form a protective oxide film on the internal surface of the cladding

  13. Evaluation of the characteristics of uranium and plutonium Mixed Oxide (MOX) fuel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-15

    MOX fuel irradiation test up to high burnup has been performed for five years. Irradiation test of MOX fuel having high plutonium content has also been performed from JFY 2007 and it still continues. A lot of irradiation data have been obtained through these tests. The activities done in JFY 2012 are mainly focused on Post Irradiation Examination (PIE) data analysis concerning thermal property change and fission gas release. In the former work thermal conductivity degradation due to burnup is examined and in the latter work the dependence of fission gas release mechanism on fuel pellet microstructure is examined. This report mainly covers the result of analysis. It is found that thermal conductivity degradation of MOX fuel due to burnup is less than that of UO{sub 2} fuel and that fission gas release mechanism of high enriched fissile zone (so called Pu spot) is much different from that of low enriched fissile zone (so called Matrix). (author)

  14. Evaluation of the characteristics of high burnup and high plutonium content mixed oxide (MOX) fuel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    Two kinds of MOX fuel irradiation tests, i.e., MOX irradiation test up to high burnup and MOX having high plutonium content irradiation test, have been performed from JFY 2007 for five years in order to establish technical data concerning MOX fuel behavior during irradiation, which shall be needed in safety regulation of MOX fuel with high reliability. The high burnup MOX irradiation test consists of irradiation extension and post irradiation examination (PIE). The activities done in JFY 2011 are destructive post irradiation examination (D-PIE) such as EPMA and SIMS at CEA (Commissariat a l'Enegie Atomique) facility. Cadarache and PIE data analysis. In the frame of irradiation test of high plutonium content MOX fuel programme, MOX fuel rods with about 14wt % Pu content are being irradiated at BR-2 reactor and corresponding PIE is also being done at PIE facility (SCK/CEN: Studiecentrum voor Kernenergie/Centre d'Etude l'Energie Nucleaire) in Belgium. The activities done in JFY 2011 are non-destructive post irradiation examination (ND-PIE) and D-PIE and PIE data analysis. In this report the results of EPMA and SIMS with high burnup irradiation test and the result of gamma spectrometry measurement which can give FP gas release rate are reported. (author)

  15. Solid Oxide Fuel Cell

    DEFF Research Database (Denmark)

    2010-01-01

    The solid oxide fuel cell comprising a metallic support material, an active anode layer consisting of a good hydrocarbon cracking catalyst, an electrolyte layer, an active cathode layer, and a transition layer consisting of preferably a mixture of LSM and a ferrite to the cathode current collector...

  16. Internal reforming characteristics of cermet supported solid oxide fuel cell using yttria stabilized zirconia fed with partially reformed methane

    Energy Technology Data Exchange (ETDEWEB)

    Momma, Akihiko; Takano, Kiyonami; Tanaka, Yohei; Negishi, Akira; Kato, Ken; Nozaki, Ken; Kato, Tohru [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono Tsukuba Ibaraki, 305-8568 (Japan); Ichigi, Takenori; Matsuda, Kazuyuki; Ryu, Takashi [Application Development Project, Corporate R and D, NGK Insulators, Ltd., 2-56 Suda-cho Mizuho-ku Nagoya-shi Aichi, 467-8530 (Japan)

    2009-08-01

    In order to investigate the internal reforming characteristics in a cermet supported solid oxide fuel cell (SOFC) using YSZ as the electrolyte, the concentration profiles of the gaseous species along the gas flow direction in the anode were measured. Partially reformed methane using a pre-reformer kept at a constant temperature is supplied to the center of the cell which is operated with a seal-less structure at the gas outlet. The anode gas is sucked in via silica capillaries to the initially evacuated gas tanks. The process is simultaneously carried out using five sampling ports. The sampled gas is analyzed by a gas chromatograph. Most of the measurements are made at the cell temperature (T{sub cell}) of 750 C and at various temperatures of the pre-reformer (T{sub ref}) with various fuel utilizations (U{sub f}) of the cell. The composition of the fuel at the inlet of the anode was confirmed to be almost the same as that theoretically calculated assuming equilibrium at the temperature of the pre-reformer. The effect of internal reforming in the anode is clearly observed as a steady decrease in the methane concentration along the flow axis. The effect of the water-gas shift reaction is also observed as a decrease in the CO{sub 2} concentration and an increase of CO concentration around the gas inlet region, as the water-gas shift reaction inversely proceeds when T{sub cell} is higher than T{sub ref}. The diffusion of nitrogen from the seal-less outermost edge is observed, and the diffusion is confirmed to be more significant as U{sub f} decreases. The observations are compared with the results obtained by the SOFC supported by lanthanum gallate electrolyte. With respect to the internal reforming performance, the cell investigated here is found to be more effective when compared to the previously reported electrolyte supported cell. (author)

  17. Internal reforming characteristics of cermet supported solid oxide fuel cell using yttria stabilized zirconia fed with partially reformed methane

    Science.gov (United States)

    Momma, Akihiko; Takano, Kiyonami; Tanaka, Yohei; Negishi, Akira; Kato, Ken; Nozaki, Ken; Kato, Tohru; Ichigi, Takenori; Matsuda, Kazuyuki; Ryu, Takashi

    In order to investigate the internal reforming characteristics in a cermet supported solid oxide fuel cell (SOFC) using YSZ as the electrolyte, the concentration profiles of the gaseous species along the gas flow direction in the anode were measured. Partially reformed methane using a pre-reformer kept at a constant temperature is supplied to the center of the cell which is operated with a seal-less structure at the gas outlet. The anode gas is sucked in via silica capillaries to the initially evacuated gas tanks. The process is simultaneously carried out using five sampling ports. The sampled gas is analyzed by a gas chromatograph. Most of the measurements are made at the cell temperature (T cell) of 750 °C and at various temperatures of the pre-reformer (T ref) with various fuel utilizations (U f) of the cell. The composition of the fuel at the inlet of the anode was confirmed to be almost the same as that theoretically calculated assuming equilibrium at the temperature of the pre-reformer. The effect of internal reforming in the anode is clearly observed as a steady decrease in the methane concentration along the flow axis. The effect of the water-gas shift reaction is also observed as a decrease in the CO 2 concentration and an increase of CO concentration around the gas inlet region, as the water-gas shift reaction inversely proceeds when T cell is higher than T ref. The diffusion of nitrogen from the seal-less outermost edge is observed, and the diffusion is confirmed to be more significant as U f decreases. The observations are compared with the results obtained by the SOFC supported by lanthanum gallate electrolyte. With respect to the internal reforming performance, the cell investigated here is found to be more effective when compared to the previously reported electrolyte supported cell.

  18. Experience with oxide fuel for advanced reactors

    International Nuclear Information System (INIS)

    Leggett, R.D.

    1984-01-01

    This paper focuses on the use and potential of oxide fuel systems for the LMFBR. The flawless performance of mixed oxide (UO 2 -PuO 2 ) fuel in FFTF to 100,000 MWd/MTM is reviewed and means for achieving 200,000 MWd/MTM are presented. This includes using non-swelling alloys for cladding and ducts to overcome the limitations caused by swelling of the current alloys. Examples are provided of the inherently safe characteristics of oxide fuel including a large negative Doppler coefficient, its dispersive nature under hypothetical accident scenarios, and the low energy molten fuel-coolant interaction. Developments in fuel fabrication and reprocessing that stress safety and reduced personnel exposure are presented. Lastly, the flexibility to design for maximum fuel supply (high breeding gain) or minimum fuel cost (long lifetime) is shown

  19. Experience with oxide fuel for advanced reactors

    International Nuclear Information System (INIS)

    Leggett, R.D.

    1984-04-01

    This paper focuses on the use and potential of oxide fuel system for the LMFBR. The flawless performance of mixed oxide (UO 2 -PuO 2 ) fuel in FFTF to 100,000 MWd/MTM is reviewed and means for achieving 200,000 MWd/MTM are presented. This includes using non-swelling alloys for cladding and ducts to overcome the limitations caused by swelling of the current alloys. Exampled are provided of the inherently safe characteristics of oxide fuel including a large negative Doppler coefficient, its dispersive nature under hypothetical accident scenarios, and the low energy molten fuel-coolant interaction. Developments in fuel fabrication and reprocessing that stress safety and reduced personnel exposure are presented. Lastly, the flexibility to design for maximum fuel supply (high breeding gain) or minimum fuel cost (long lifetime) is shown

  20. Drying characteristics of thorium fuel corrosion products

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.-E. E-mail: rzl@inel.gov

    2004-07-01

    The open literature and accessible US Department of Energy-sponsored reports were reviewed for the dehydration and rehydration characteristics of potential corrosion products from thorium metal and thorium oxide nuclear fuels. Mixed oxides were not specifically examined unless data were given for performance of mixed thorium-uranium fuels. Thorium metal generally corrodes to thorium oxide. Physisorbed water is readily removed by heating to approximately 200 deg. C. Complete removal of chemisorbed water requires heating above 1000 deg. C. Thorium oxide adsorbs water well in excess of the amount needed to cover the oxide surface by chemisorption. The adsorption of water appears to be a surface phenomenon; it does not lead to bulk conversion of the solid oxide to the hydroxide. Adsorptive capacity depends on both the specific surface area and the porosity of the thorium oxide. Heat treatment by calcination or sintering reduces the adsorption capacity substantially from the thorium oxide produced by metal corrosion.

  1. A reduced chemical kinetic model for the analytical investigations on the oxidation kinetics and performance characteristics of diesel fuel

    International Nuclear Information System (INIS)

    Selvaraj, N.; Manoj Kumar, C.V.; Babu, M.S.

    2010-01-01

    A detailed study of the combustion of diesel fuel has been conducted analytically using a kinetic scheme with 767 elementary reactions and 158 species. A program has been developed in MATLAB for the analysis of ignition delay, performance, soot formation and emission characteristics of diesel fuel. Nitrogen is considered as the diluent and its percentage is assumed as 79%. The criteria used for the determination of ignition delay time are based on OH concentration to reach a value of 1x10 -9 . A brief review of diesel combustion and soot formation is given. (author)

  2. Microstructure characterizaton of advanced oxide fuel

    International Nuclear Information System (INIS)

    Rasmussen, D.E.; Gerber, E.W.; McCord, R.B.

    1977-01-01

    Preirradiation porosity, grain size, and microcomposition characteristics are presented for selected advanced oxide (PuO 2 -UO 2 ) LMFBR developmental fuels fabricated for irradiation testing in EBR-II. Quantitative microscopy, electron microprobe analysis, and a recently developed quantitative autoradiographic technique are utilized to relate microstructure characteristics to fabrication parameters

  3. Blending Biodiesel in Fishing Boat Fuels for Improved Fuel Characteristics

    International Nuclear Information System (INIS)

    Lin, Cherng-Yuan

    2014-01-01

    Biodiesel is a renewable, clean, alternative energy source with advantages, such as excellent lubricity, superior biodegradability, and high combustion efficiency. Biodiesel is considered for mixing with fishing boat fuels to adjust their fuel characteristics so that toxic pollutants and greenhouse-effect gas emissions from such shipping might be reduced. The effects of blending fishing boat fuels A and B with various weight proportions of biodiesel are experimentally investigated in this study. The results show that biodiesel blending can significantly improve the inferior fuel properties of both fishing boat fuels and particularly fuel B. The flash points of both of these fuels increases significantly with the addition of biodiesel and thus enhances the safety of transporting and storing these blended fuels. The flash point of fishing boat fuel B even increases by 16% if 25 wt.% biodiesel is blended. The blending of biodiesel with no sulfur content is found to be one of the most effective ways to reduce the high sulfur content of fishing boat fuel, resulting in a reduction in the emission of sulfur oxides. The addition of only 25 wt.% biodiesel decreased the sulfur content of the fishing boat fuel by 37%. The high kinematic viscosity of fishing boat fuel B was also observed to be reduced by 63% with the blending of just 25 wt.% biodiesel. However, biodiesel blending caused a slight decrease in heating value around 1–4.5%.

  4. Blending Biodiesel in Fishing Boat Fuels for Improved Fuel Characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Cherng-Yuan, E-mail: lin7108@ntou.edu.tw [Department of Marine Engineering, National Taiwan Ocean University, Keelung, Taiwan (China)

    2014-02-24

    Biodiesel is a renewable, clean, alternative energy source with advantages, such as excellent lubricity, superior biodegradability, and high combustion efficiency. Biodiesel is considered for mixing with fishing boat fuels to adjust their fuel characteristics so that toxic pollutants and greenhouse-effect gas emissions from such shipping might be reduced. The effects of blending fishing boat fuels A and B with various weight proportions of biodiesel are experimentally investigated in this study. The results show that biodiesel blending can significantly improve the inferior fuel properties of both fishing boat fuels and particularly fuel B. The flash points of both of these fuels increases significantly with the addition of biodiesel and thus enhances the safety of transporting and storing these blended fuels. The flash point of fishing boat fuel B even increases by 16% if 25 wt.% biodiesel is blended. The blending of biodiesel with no sulfur content is found to be one of the most effective ways to reduce the high sulfur content of fishing boat fuel, resulting in a reduction in the emission of sulfur oxides. The addition of only 25 wt.% biodiesel decreased the sulfur content of the fishing boat fuel by 37%. The high kinematic viscosity of fishing boat fuel B was also observed to be reduced by 63% with the blending of just 25 wt.% biodiesel. However, biodiesel blending caused a slight decrease in heating value around 1–4.5%.

  5. Solid oxide fuel cells fueled with reducible oxides

    Science.gov (United States)

    Chuang, Steven S.; Fan, Liang Shih

    2018-01-09

    A direct-electrochemical-oxidation fuel cell for generating electrical energy includes a cathode provided with an electrochemical-reduction catalyst that promotes formation of oxygen ions from an oxygen-containing source at the cathode, a solid-state reduced metal, a solid-state anode provided with an electrochemical-oxidation catalyst that promotes direct electrochemical oxidation of the solid-state reduced metal in the presence of the oxygen ions to produce electrical energy, and an electrolyte disposed to transmit the oxygen ions from the cathode to the solid-state anode. A method of operating a solid oxide fuel cell includes providing a direct-electrochemical-oxidation fuel cell comprising a solid-state reduced metal, oxidizing the solid-state reduced metal in the presence of oxygen ions through direct-electrochemical-oxidation to obtain a solid-state reducible metal oxide, and reducing the solid-state reducible metal oxide to obtain the solid-state reduced metal.

  6. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Chick, L.A. [Pacific Northwest Lab., Richland, WA (United States)

    1996-04-01

    Interconnection materials in a solid oxide fuel cell are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. The thermal expansion characteristics of substituted lanthanum and yttrium chromite interconnect materials were evaluated by dilatometry as a function of oxygen partial pressures from 1 atm to 10{sup -18} atm, controlled using a carbon dioxide/hydrogen buffer.

  7. Effect of antioxidant on the oxidation stability and combustion–performance–emission characteristics of a diesel engine fueled with diesel–biodiesel blend

    International Nuclear Information System (INIS)

    Rashedul, H.K.; Masjuki, H.H.; Kalam, M.A.; Teoh, Y.H.; How, H.G.; Rizwanul Fattah, I.M.

    2015-01-01

    Highlights: • Alexandrian laurel or Calophyllum inophyllum biodiesel blend fulfill the ASTM (D7467) specification. • Addition of antioxidant to biodiesel higher the oxidation stability. • Antioxidant treated blends showed lower NO X and BSFC compared to untreated blend. • Antioxidant treated blends showed higher CO, HC and smoke compared to untreated blend. - Abstract: Alexandrian laurel or Calophyllum inophyllum oil is recently considered one of the most anticipated nonconsumable or nonedible biodiesel sources. An attempt has been made in this study to increase the oxidation stability and investigate the engine performance, emission, and combustion characteristics of a diesel engine by adding 1% (by vol.) of two antioxidants, such as 2,6-Di-tert.-butyl-4-methylphenol and 2,2′-methylenebis (4-methyl-6-tert-butylphenol), in higher percentages of C. inophyllum biodiesel (CB30) with diesel fuel (B0). The experiment was performed on a single-cylinder, water-cooled, direct-injection diesel engine for this purpose. The addition of both antioxidants increased the oxidation stability without significantly changing other physicochemical properties. Results also show that the antioxidants enhanced the start of combustion of biodiesel, which resulted in a short ignition delay. The peak pressure and the peak heat release rate during premixed combustion phase of pure CB30 and its modified blend with antioxidant were higher than those of B0. Both antioxidant blends showed higher brake power, higher brake thermal efficiency, and lower brake specific fuel consumption than pure CB30. Both antioxidants significantly reduced NO X emission; however, CO, HC, and smoke opacity were slightly higher than those of CB30. Based on this study, Alexandrian laurel or C. inophyllum biodiesel blend (CB30) with antioxidant can be used as an alternative fuel in a diesel engine without modifications.

  8. A comparative study of the oxidation characteristics of two gasoline fuels and an n-heptane/iso-octane surrogate mixture

    KAUST Repository

    Javed, Tamour; Nasir, Ehson F.; Es-sebbar, Et-touhami; Farooq, Aamir

    2015-01-01

    Ignition delay times and CO, H2O, OH and CO2 time-histories were measured behind reflected shock waves for two FACE (Fuels for Advanced Combustion Engines) gasolines and one PRF (Primary Reference Fuel) blend. The FACE gasolines chosen for this work

  9. Heating subsurface formations by oxidizing fuel on a fuel carrier

    Science.gov (United States)

    Costello, Michael; Vinegar, Harold J.

    2012-10-02

    A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.

  10. Relationship Between Particle and Plasma Properties and Coating Characteristics of Samaria-Doped Ceria Prepared by Atmospheric Plasma Spraying for Use in Solid Oxide Fuel Cells

    Science.gov (United States)

    Cuglietta, Mark; Kesler, Olivera

    2012-06-01

    Samaria-doped ceria (SDC) has become a promising material for the fabrication of high-performance, intermediate-temperature solid oxide fuel cells (SOFCs). In this study, the in-flight characteristics, such as particle velocity and surface temperature, of spray-dried SDC agglomerates were measured and correlated to the resulting microstructures of SDC coatings fabricated using atmospheric plasma spraying, a manufacturing technique with the capability of producing full cells in minutes. Plasmas containing argon, nitrogen and hydrogen led to particle surface temperatures higher than those in plasmas containing only argon and nitrogen. A threshold temperature for the successful deposition of SDC on porous stainless steel substrates was calculated to be 2570 °C. Coating porosity was found to be linked to average particle temperature, suggesting that plasma conditions leading to lower particle temperatures may be most suitable for fabricating porous SOFC electrode layers.

  11. Solid Oxide Fuel Cell Experimental Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — NETL’s Solid Oxide Fuel Cell Experimental Laboratory in Morgantown, WV, gives researchers access to models and simulations that predict how solid oxide fuel cells...

  12. A comparative study of the oxidation characteristics of two gasoline fuels and an n-heptane/iso-octane surrogate mixture

    KAUST Repository

    Javed, Tamour

    2015-01-01

    Ignition delay times and CO, H2O, OH and CO2 time-histories were measured behind reflected shock waves for two FACE (Fuels for Advanced Combustion Engines) gasolines and one PRF (Primary Reference Fuel) blend. The FACE gasolines chosen for this work are primarily paraffinic and have the same octane rating (∼RON = 84) as the PRF blend, but contain varying amounts of iso- and n-paraffins. Species time-histories and ignition delay times were measured using laser absorption methods over a temperature range of 1350-1550 K and pressures near 2 atm. Measured species time-histories and ignition delay times of the PRF blend and the two FACE fuels agreed reasonably well. However, when compared to recent gasoline surrogate mechanisms, the simulations did not capture some of the kinetic trends found in the species profiles. To our knowledge, this work provides some of the first shock tube species time-history data for gasoline fuels and PRF surrogates and should enable further improvements in detailed kinetic mechanisms of gasoline fuels.

  13. A study on physical characteristics of supercritical light - water reactor loaded with (232U-238Th-238U) oxide fuel

    International Nuclear Information System (INIS)

    Kulikov, E. G.; Shmelev, A. N.; Apse, V. A.; Kulikov, G. G.

    2007-01-01

    The attractiveness of using (U-Th)-fuel in supercritical light water reactor is considered. The dilution of 2 33U in 2 38U is proposed with the purpose of increasing non-proliferation of this fissile isotope. Comparison of different fuel compositions is accomplished from the point of view of fissile isotope breeding and achieved burn-up; parasitic neutron absorption cross-sections are also compared. It is analyzed the impact for neutron balance of both cladding materials: zirconium alloy and stainless steel

  14. Fuel characteristics pertinent to the design of aircraft fuel systems

    Science.gov (United States)

    Barnett, Henry C; Hibbard, R R

    1953-01-01

    Because of the importance of fuel properties in design of aircraft fuel systems the present report has been prepared to provide information on the characteristics of current jet fuels. In addition to information on fuel properties, discussions are presented on fuel specifications, the variations among fuels supplied under a given specification, fuel composition, and the pertinence of fuel composition and physical properties to fuel system design. In some instances the influence of variables such as pressure and temperature on physical properties is indicated. References are cited to provide fuel system designers with sources of information containing more detail than is practicable in the present report.

  15. Characteristics of spent nuclear fuel

    International Nuclear Information System (INIS)

    Notz, K.J.

    1988-04-01

    The Office of Civilian Radioactive Waste Management (OCRWM) is responsible for the spent fuels and other wastes that will, or may, eventually be disposed of in a geological repository. The two major sources of these materials are commercial light-water reactor (LWR) spent fuel and immobilized high-level waste (HLW). Other wastes that may require long-term isolation include non-LWR spent fuels and miscellaneous sources such as activated metals. This report deals with spent fuels, but for completeness, the other sources are described briefly. Detailed characterizations are required for all of these potential repository wastes. These characteristics include physical, chemical, and radiological properties. The latter must take into account decay as a function of time. In addition, the present inventories and projected quantities of the various wastes are needed. This information has been assembled in a Characteristics Data Base which provides data in four formats: hard copy standard reports, menu-driven personal computer (PC) data bases, program-level PC data bases, and mainframe computer files. 5 refs., 3 figs., 4 tabs

  16. Characteristic of The RSG-Gas Oxide Fuel Element Temperature Under Forced Convection And Natural Convection Mode

    International Nuclear Information System (INIS)

    Sudarmono

    2000-01-01

    One of the methods used for fuel element plate temperature measurement in RSG-Gas is a direct measurement. Evaluation on the measurement results were done by using HEATHYDE and NATCON code, which was then compared to the safety margin criteria. Results of thermalhydraulic measurement on transitional core both under forced and natural convection were compared with the results of calculations using the two codes. Measurement result for maximum fuel element plate temperature at typical working core of 30 MW, was 121 o C. The deviation between calculation and measurement result was under 9.75 %. Under normal operation, safety margin on DNB and OFI are 3.56 and 2.60, respectively. Natcon calculation result showed that the typical working core under the natural circulation mode, an onset of nucleate boiling (ONB)occurred at a core power level of 826 kW (2.8% of the nominal power)

  17. Dissolving method for nuclear fuel oxide

    International Nuclear Information System (INIS)

    Tomiyasu, Hiroshi; Kataoka, Makoto; Asano, Yuichiro; Hasegawa, Shin-ichi; Takashima, Yoichi; Ikeda, Yasuhisa.

    1996-01-01

    In a method of dissolving oxides of nuclear fuels in an aqueous acid solution, the oxides of the nuclear fuels are dissolved in a state where an oxidizing agent other than the acid is present together in the aqueous acid solution. If chlorate ions (ClO 3 - ) are present together in the aqueous acid solution, the chlorate ions act as a strong oxidizing agent and dissolve nuclear fuels such as UO 2 by oxidation. In addition, a Ce compound which generates Ce(IV) by oxidation is added to the aqueous acid solution, and an ozone (O 3 ) gas is blown thereto to dissolve the oxides of nuclear fuels. Further, the oxides of nuclear fuels are oxidized in a state where ClO 2 is present together in the aqueous acid solution to dissolve the oxides of nuclear fuels. Since oxides of the nuclear fuels are dissolved in a state where the oxidizing agent is present together as described above, the oxides of nuclear fuels can be dissolved even at a room temperature, thereby enabling to use a material such as polytetrafluoroethylene and to dissolve the oxides of nuclear fuels at a reduced cost for dissolution. (T.M.)

  18. Spent fuel. Dissolution and oxidation

    International Nuclear Information System (INIS)

    Grambow, B.

    1989-03-01

    Data from studies of the low temperature air oxidation of spent fuel were retrieved in order to provide a basis for comparison between the mechanism of oxidation in air and corrosion in water. U 3 O 7 is formed by diffusion of oxygen into the UO 2 lattice. A diffusion coefficient of oxygen in the fuel matric was calculated for 25 degree C to be in the range of 10 -23 to 10 -25 m 2 /s. The initial rates of U release from spent fuel and from UO 2 appear to be similar. The lowest rates (at 25 degree c >10 -4 g/(m 2 d)) were observed under reducing conditions. Under oxidizing conditions the rates depend mainly of the nature and concentraion of the oxidant and/or on corbonate. In contact with air, typical initial rates at room temperature were in the range between 0.001 and 0.1 g/(m 2 d). A study of apparent U solubility under oxidizing conditions was performed and it was suggested that the controlling factor is the redox potential at the UO 2 surface rather than the E h of the bulk solution. Electrochemical arguments were used to predict that at saturation, the surface potential will eventually reach a value given by the boundaries at either the U 3 O 7 /U 3 O 8 or the U 3 O 7 /schoepite stability field, and a comparison with spent fuel leach data showed that the solution concentration of uranium is close to the calculated U solubility at the U 3 O 7 /U 3 O 8 boundary. The difference in the cumulative Sr and U release was calculated from data from Studsvik laboratory. The results reveal that the rate of Sr release decreases with the square root of time under U-saturated conditions. This time dependence may be rationalized either by grain boundary diffusion or by diffusion into the fuel matrix. Hence, there seems to be a possibility of an agreement between the Sr release data, structural information and data for oxygen diffusion in UO 2 . (G.B.)

  19. Fuel-cycle cost comparisons with oxide and silicide fuels

    International Nuclear Information System (INIS)

    Matos, J.E.; Freese, K.E.

    1982-01-01

    This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data are presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires that they are successfully demonstrated and licensed

  20. Transient survivability of LMR oxide fuel pins

    International Nuclear Information System (INIS)

    Weber, E.T.; Pitner, A.L.; Bard, F.E.; Culley, G.E.; Hunter, C.W.

    1986-01-01

    Fuel pin integrity during transient events must be assessed for both the core design and safety analysis phases of a reactor project. A significant increase in the experience related to limits of integrity for oxide fuel pins in transient overpower events has been realized from testing of fuel pins irradiated in FFTF and PFR. Fourteen FFTF irradiated fuel pins were tested in TREAT, representing a range of burnups, overpower ramp rates and maximum overpower conditions. Results of these tests along with similar testing in the PFR/TREAT program, provide a demonstration of significant safety margins for oxide fuel pins. Useful information applied in analytical extrapolation of fuel pin test data have been developed from laboratory transient tests on irradiated fuel cladding (FCTT) and on unirradiated fuel pellet deformation. These refinements in oxide fuel transient performance are being applied in assessment of transient capabilities of long lifetime fuel designs using ferritic cladding

  1. Gas transport in solid oxide fuel cells

    CERN Document Server

    He, Weidong; Dickerson, James

    2014-01-01

    This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.

  2. Fissile fuel doubling time characteristics for reactor lifetime fuel logistics

    International Nuclear Information System (INIS)

    Heindler, M.; Harms, A.A.

    1978-01-01

    The establishment of nuclear fuel requirements and their efficient utilization requires a detailed knowledge of some aspects of fuel dynamics and processing during the reactor lifetime. It is shown here that the use of the fuel stockpile inventory concept can serve effectively for this fuel management purpose. The temporal variation of the fissile fuel doubling time as well as nonequilibrium core conditions are among the characteristics which thus become more evident. These characteristics - rather than a single figure-of-merit - clearly provide an improved description of the expansion capacity and/or fuel requirements of a nuclear reactor energy system

  3. Quantifying physical characteristics of wildland fuels using the fuel characteristic classification system.

    Science.gov (United States)

    Cynthia L. Riccardi; Susan J. Prichard; David V. Sandberg; Roger D. Ottmar

    2007-01-01

    Wildland fuel characteristics are used in many applications of operational fire predictions and to understand fire effects and behaviour. Even so, there is a shortage of information on basic fuel properties and the physical characteristics of wildland fuels. The Fuel Characteristic Classification System (FCCS) builds and catalogues fuelbed descriptions based on...

  4. Development of examination technique for oxide layer thickness measurement of irradiated fuel rods

    International Nuclear Information System (INIS)

    Koo, D. S.; Park, S. W.; Kim, J. H.; Seo, H. S.; Min, D. K.; Kim, E. K.; Chun, Y. B.; Bang, K. S.

    1999-06-01

    Technique for oxide layer thickness measurement of irradiated fuel rods was developed to measure oxide layer thickness and study characteristic of fuel rods. Oxide layer thickness of irradiated fuels were measured, analyzed. Outer oxide layer thickness of 3 cycle-irradiated fuel rods were 20 - 30 μm, inner oxide layer thickness 0 - 10 μm and inner oxide layer thickness on cracked cladding about 30 μm. Oxide layer thickness of 4 cycle-irradiated fuel rods were about 2 times as thick as those of 1 cycle-irradiated fuel rods. Oxide layer on lower region of irradiated fuel rods was thin and oxide layer from lower region to upper region indicated gradual increase in thickness. Oxide layer thickness from 2500 to 3000 mm showed maximum and oxide layer thickness from 3000 to top region of irradiated fuel rods showed decreasing trend. Inner oxide layer thicknesses of 4 cycle-irradiated fuel rod were about 8 μm at 750 - 3500 mm from the bottom end of fuel rod. Outer oxide layer thickness were about 8 μm at 750 - 1000 mm from the bottom end of fuel rod. These indicated gradual increase up to upper region from the bottom end of fuel rod. These indicated gradual increase up to upper region from the bottom end of fuel. Oxide layer thickness technique will apply safety evaluation and study of reactor fuels. (author). 6 refs., 14 figs

  5. Electrolytes for solid oxide fuel cells

    Science.gov (United States)

    Fergus, Jeffrey W.

    The high operating temperature of solid oxide fuel cells (SOFCs), as compared to polymer electrolyte membrane fuel cells (PEMFCs), improves tolerance to impurities in the fuel, but also creates challenges in the development of suitable materials for the various fuel cell components. In response to these challenges, intermediate temperature solid oxide fuel cells (IT-SOFCs) are being developed to reduce high-temperature material requirements, which will extend useful lifetime, improve durability and reduce cost, while maintaining good fuel flexibility. A major challenge in reducing the operating temperature of SOFCs is the development of solid electrolyte materials with sufficient conductivity to maintain acceptably low ohmic losses during operation. In this paper, solid electrolytes being developed for solid oxide fuel cells, including zirconia-, ceria- and lanthanum gallate-based materials, are reviewed and compared. The focus is on the conductivity, but other issues, such as compatibility with electrode materials, are also discussed.

  6. Electrolytes for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Fergus, Jeffrey W. [Auburn University, Materials Research and Education Center, 275 Wilmore Laboratories, Auburn, AL 36849 (United States)

    2006-11-08

    The high operating temperature of solid oxide fuel cells (SOFCs), as compared to polymer electrolyte membrane fuel cells (PEMFCs), improves tolerance to impurities in the fuel, but also creates challenges in the development of suitable materials for the various fuel cell components. In response to these challenges, intermediate temperature solid oxide fuel cells (IT-SOFCs) are being developed to reduce high-temperature material requirements, which will extend useful lifetime, improve durability and reduce cost, while maintaining good fuel flexibility. A major challenge in reducing the operating temperature of SOFCs is the development of solid electrolyte materials with sufficient conductivity to maintain acceptably low ohmic losses during operation. In this paper, solid electrolytes being developed for solid oxide fuel cells, including zirconia-, ceria- and lanthanum gallate-based materials, are reviewed and compared. The focus is on the conductivity, but other issues, such as compatibility with electrode materials, are also discussed. (author)

  7. UK experience on fuel and cladding interaction in oxide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Batey, W [Dounreay Experimental Reactor Establishment, Thurso, Caithness (United Kingdom); Findlay, J R [AERE, Harwell, Didcot, Oxon (United Kingdom)

    1977-04-01

    The occurrence of fuel cladding interactions in fast reactor fuels has been observed in UK irradiations over a period of years. Chemical incompatibility between fuel and clad represents a potential source of failure and has, on this account, been studied using a variety of techniques. The principal fuel of interest to the UK for fast reactor application is mixed uranium plutonium oxide clad in stainless steel and it is in this field that the majority of work has been concentrated. Some consideration has been given to carbide fuels, because of their application as an advanced fuel. This experience is described in the accompanying paper. Several complementary initiatives have been followed to investigate the interactions in oxide fuel. The principal source of experimental information is from the experimental fuel irradiation programme in the Dounreay Fast Reactor (DFR). Supporting information has been obtained from irradiation programmes in Materials Testing Reactors (MTR). Conditions approaching those in a fast reactor are obtained and the effects of specific variables have been examined in specifically designed experiments. Out-of-reactor experiments have been used to determine the limits of fuel and cladding compatibility and also to give indications of corrosion The observations from all experiments have been examined in the light of thermo-dynamic predictions of fuel behaviour to assess the relative significance of various observations and operating conditions. An experimental programme to control and limit the interactions in oxide fuel is being followed.

  8. UK experience on fuel and cladding interaction in oxide fuels

    International Nuclear Information System (INIS)

    Batey, W.; Findlay, J.R.

    1977-01-01

    The occurrence of fuel cladding interactions in fast reactor fuels has been observed in UK irradiations over a period of years. Chemical incompatibility between fuel and clad represents a potential source of failure and has, on this account, been studied using a variety of techniques. The principal fuel of interest to the UK for fast reactor application is mixed uranium plutonium oxide clad in stainless steel and it is in this field that the majority of work has been concentrated. Some consideration has been given to carbide fuels, because of their application as an advanced fuel. This experience is described in the accompanying paper. Several complementary initiatives have been followed to investigate the interactions in oxide fuel. The principal source of experimental information is from the experimental fuel irradiation programme in the Dounreay Fast Reactor (DFR). Supporting information has been obtained from irradiation programmes in Materials Testing Reactors (MTR). Conditions approaching those in a fast reactor are obtained and the effects of specific variables have been examined in specifically designed experiments. Out-of-reactor experiments have been used to determine the limits of fuel and cladding compatibility and also to give indications of corrosion The observations from all experiments have been examined in the light of thermo-dynamic predictions of fuel behaviour to assess the relative significance of various observations and operating conditions. An experimental programme to control and limit the interactions in oxide fuel is being followed

  9. Direct Coal Oxidation in Modified Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Gil, Vanesa; Ippolito, Davide

    2015-01-01

    Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon-carbonate s......Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon......-carbonate slurry or anode layer. The nature of the coal affects both open circuit voltage and power output. Highest OCV and power densities were observed for bituminous coal and by adding manganese oxide or praseodymium-doped ceria to the carbon/carbonate mixture. Comparing the carbon black fueled performance...... bituminous coal (73 mW/cm2). © 2015 ECS - The Electrochemical Society...

  10. Direct Coal Oxidation in Modified Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Gil, Vanesa; Ippolito, Davide

    2017-01-01

    Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon-carbonate s......Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon......-carbonate slurry or anode layer. The nature of the coal affects both open circuit voltage and power output. Highest OCV and power densities were observed for bituminous coal and by adding manganese oxide or praseodymium-doped ceria to the carbon/carbonate mixture. Comparing the carbon black fueled performance...... bituminous coal (73 mW/cm2)....

  11. Jet Fuel Based High Pressure Solid Oxide Fuel Cell System

    Science.gov (United States)

    Gummalla, Mallika (Inventor); Yamanis, Jean (Inventor); Olsommer, Benoit (Inventor); Dardas, Zissis (Inventor); Bayt, Robert (Inventor); Srinivasan, Hari (Inventor); Dasgupta, Arindam (Inventor); Hardin, Larry (Inventor)

    2015-01-01

    A power system for an aircraft includes a solid oxide fuel cell system which generates electric power for the aircraft and an exhaust stream; and a heat exchanger for transferring heat from the exhaust stream of the solid oxide fuel cell to a heat requiring system or component of the aircraft. The heat can be transferred to fuel for the primary engine of the aircraft. Further, the same fuel can be used to power both the primary engine and the SOFC. A heat exchanger is positioned to cool reformate before feeding to the fuel cell. SOFC exhaust is treated and used as inerting gas. Finally, oxidant to the SOFC can be obtained from the aircraft cabin, or exterior, or both.

  12. Medium-temperature solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Maffei, N.; Kuriakose, A.K. [Natural Resources Canada, Ottawa, ON (Canada). Materials Technology Lab

    2000-07-01

    The Materials Technology Laboratory (MTL) of Natural Resources Canada has been conducting research on the development of a solid oxide fuel cell (SOFC) for the past decade. Fuel cells convert chemical energy directly into electric energy in an efficient and environmentally friendly manner. SOFCs are considered to be good stationary power sources for commercial and residential applications and will likely be commercialized in the near future. The research at MTL has focused on the development of new electrolytes for use in SOFCs. In the course of this research, monolithic planar single cell SOFCs based on doubly doped ceria and lanthanum gallate have been fabricated and tested at 700 degrees C. This paper compared the performance characteristics of both these systems. The data suggested the presence of a significant electronic conductivity in the SOFC incorporating doubly doped ceria, resulting in lower than expected voltage output. The stability of the SOFC, however, did not appear to be negatively affected. The lanthanum gallate based SOFC performed well. It was concluded that reducing the operating temperature of SOFCs would improve their reliability and enhance their operating life. First generation commercial SOFCs will use a zirconium oxide-based electrolytes while second generation units might possibly use ceria-based and/or lanthanum gallate electrolytes. 24 refs., 6 figs.

  13. A conceptual model for the fuel oxidation of defective fuel

    International Nuclear Information System (INIS)

    Higgs, J.D.; Lewis, B.J.; Thompson, W.T.; He, Z.

    2007-01-01

    A mechanistic conceptual model has been developed to predict the fuel oxidation behaviour in operating defective fuel elements for water-cooled nuclear reactors. This theoretical work accounts for gas-phase transport and sheath reactions in the fuel-to-sheath gap to determine the local oxygen potential. An improved thermodynamic analysis has also been incorporated into the model to describe the equilibrium state of the oxidized fuel. The fuel oxidation kinetics treatment accounts for multi-phase transport including normal diffusion and thermodiffusion for interstitial oxygen migration in the solid, as well as gas-phase transport in the fuel pellet cracks. The fuel oxidation treatment is further coupled to a heat conduction equation. A numerical solution of the coupled transport equations is obtained by a finite-element technique with the FEMLAB 3.1 software package. The model is able to provide radial-axial profiles of the oxygen-to-uranium ratio and the fuel temperatures as a function of time in the defective element for a wide range of element powers and defect sizes. The model results are assessed against coulometric titration measurements of the oxygen-to-metal profile for pellet samples taken from ten spent defective elements discharged from the National Research Universal Reactor at the Chalk River Laboratories and commercial reactors

  14. Electrometallurgical treatment of oxide spent fuels

    International Nuclear Information System (INIS)

    Karell, E. J.

    1999-01-01

    The Department of Energy (DOE) inventory of spent nuclear fuel contains a wide variety of oxide fuel types that may be unsuitable for direct repository disposal in their current form. The molten-salt electrometallurgical treatment technique developed by Argonne National Laboratory (ANL) has the potential to simplify preparing and qualifying these fuels for disposal by converting them into three uniform product streams: uranium metal, a metal waste form, and a ceramic waste form. This paper describes the major steps in the electrometallurgical treatment process for oxide fuels and provides the results of recent experiments performed to develop and scale up the process

  15. The neutronic and fuel cycle performance of interchangeable 3500 MWth metal and oxide fueled LMRs

    International Nuclear Information System (INIS)

    Fujita, E.K.; Wade, D.C.

    1990-01-01

    This study summarizes the neutronic and fuel cycle analysis performed at Argonne National Laboratory for an oxide and a metal fueled 3500 MWth LMR. These reactor designs formed the basis for a joint US/European study of LMR ATWS events. The oxide and metal core designs were developed to meet reactor performance specifications that are constrained by requirements for core loading interchangeability and for a small burnup reactivity swing. Differences in the computed performance parameters of the oxide and metal cores, arising from basic differences in their neutronic characteristics, are identified and discussed. It is shown that metal and oxide cores designed to the same ground rules exhibit many similar performance characteristics; however, they differ substantially in reactivity coefficients, control strategies, and fuel cycle options. 12 refs., 2 figs., 12 tabs

  16. Plutonium spot of mixed oxide fuel, 2

    International Nuclear Information System (INIS)

    Suzuki, Yukio; Maruishi, Yoshihiro; Satoh, Masaichi; Aoki, Toshimasa; Muto, Tadashi

    1974-01-01

    In a fast reactor, the specification for the homogeneity of plutonium in plutonium-uranium mixed-oxide fuel is mainly dependent on the nuclear characteristics, whereas in a thermal reactor, on thermal characteristics. This homogeneity is measured by autoradiography as the plutonium spot size of the specimens which are arbitrarily chosen fuel pellets from a lot. Although this is a kind of random sampling, it is difficult to apply this method to conventional digital standards including JIS standards. So a special sampling inspection method was studied. First, it is assumed that the shape of plutonium spots is spherical, the size distribution is logarithmic normal, and the standard deviation is constant. Then, if standard deviation and mean spot size are given, the logarithmic normal distribution is decided unitarily, and further if the total weight of plutonium spots for a lot of pellets is known, the number of the spots (No) which does not conform to the specification can be obtained. Then, the fraction defective is defined as No devided by the number of pellets per lot. As to the lot with such fraction defective, the acceptance coefficient of the lot was obtained through calculation, in which the number of sampling, acceptable diameter limit observed and acceptable conditions were used as parameters. (Tai, I.)

  17. The TMI regenerable solid oxide fuel cell

    Science.gov (United States)

    Cable, Thomas L.

    1995-04-01

    Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. These systems generally consist of photovoltaic solar arrays which operate during sunlight cycles to provide system power and regenerate fuel (hydrogen) via water electrolysis; during dark cycles, hydrogen is converted by the fuel cell into system. The currently preferred configuration uses two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Fuel cell/electrolyzer system simplicity, reliability, and power-to-weight and power-to-volume ratios could be greatly improved if both power production (fuel cell) and power storage (electrolysis) functions can be integrated into a single unit. The Technology Management, Inc. (TMI), solid oxide fuel cell-based system offers the opportunity to both integrate fuel cell and electrolyzer functions into one unit and potentially simplify system requirements. Based an the TMI solid oxide fuel cell (SOPC) technology, the TMI integrated fuel cell/electrolyzer utilizes innovative gas storage and operational concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H2O electrode (SOFC anode/electrolyzer cathode) materials for solid oxide, regenerative fuel cells. Improved H2/H2O electrode materials showed improved cell performance in both fuel cell and electrolysis modes in reversible cell tests. ln reversible fuel cell/electrolyzer mode, regenerative fuel cell efficiencies (ratio of power out (fuel cell mode) to power in (electrolyzer model)) improved from 50 percent (using conventional electrode materials) to over 80 percent. The new materials will allow the TMI SOFC system to operate as both the electrolyzer and fuel cell in a single unit. Preliminary system designs have also been developed which indicate the technical feasibility of using the TMI SOFC

  18. Fuel cycle cost comparisons with oxide and silicide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Matos, J E; Freese, K E [RERTR Program, Argonne National Laboratory (United States)

    1983-09-01

    This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. The status of the development and demonstration of the oxide and silicide fuels are presented in several papers in these proceedings. Routine utilization of these fuels with the uranium densities considered here requires that they are successfully demonstrated and licensed. Thermal-hydraulic safety margins, shutdown margins, mixed cores, and transient analyses are not addressed here, but analyses of these safety issues are in progress for a limited number of the most promising design options. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data is presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires that they are successfully demonstrated and licensed. All safety criteria for the reactor with these fuel element designs need to be satisfied as well. With LEU oxide fuel, 31 g U/cm{sup 3} 1 and 0.76 mm--thick fuel meat, elements with 18-22 plates 320-391 g {sup 235}U) result in the same or lower total costs than with the HEU element 23 plates, 280 g {sup 235}U). Higher LEU loadings (more plates per element) are needed for larger excess reactivity requirements. However, there is little cost advantage to using more than 20 of these plates per element. Increasing the fuel meat thickness from 0.76 mm to 1.0 mm with 3.1 g U/cm{sup 3} in the design with 20 plates per element could result in significant cost reductions if the

  19. Interconnection of bundled solid oxide fuel cells

    Science.gov (United States)

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  20. Characteristics of fuel cycle waste

    International Nuclear Information System (INIS)

    Aquilina, C.A.; Everette, S.E.

    1982-01-01

    The Low-Level Waste Management System started in 1979 to describe and model the existing commercial low-level waste management system. The system description produced is based on the identification of the different elements making up both the fuel and non-fuel cycle and their relationships to each other. A systems model based on the system description can accurately reflect the flow of low-level waste from generator to disposal site and is only limited by the reliability of the information it uses. For both the fuel cycle and non-fuel cycle large quantities of information is required in order to allow the system to operate at its full potential. Work is ongoing to collect this information. Significant progress is being made in the fuel cycle area primarily because the majority of fuel cycle low-level radioactive waste is produced by commercial power reactor plant operations. The Low-Level Waste Management system is only beginning to derive the benefits to be obtained from an accurate low-level waste management information system. As data is verified and analyzed, results on a national as well as individual organization level will be gained. Comparisons to previous studies will be made. Accurate projections of waste volumes and activities to be produced, projected impacts of waste streams of treatment or management changes are only examples of information to be produced. 1 figure, 1 table

  1. Durability of solid oxide fuel cells using sulfur containing fuels

    DEFF Research Database (Denmark)

    Hagen, Anke; Rasmussen, Jens Foldager Bregnballe; Thydén, Karl Tor Sune

    2011-01-01

    The usability of hydrogen and also carbon containing fuels is one of the important advantages of solid oxide fuel cells (SOFCs), which opens the possibility to use fuels derived from conventional sources such as natural gas and from renewable sources such as biogas. Impurities like sulfur compounds...... are critical in this respect. State-of-the-art Ni/YSZ SOFC anodes suffer from being rather sensitive towards sulfur impurities. In the current study, anode supported SOFCs with Ni/YSZ or Ni/ScYSZ anodes were exposed to H2S in the ppm range both for short periods of 24h and for a few hundred hours. In a fuel...

  2. Nonproliferation characteristics of advanced fuel cycle concepts

    International Nuclear Information System (INIS)

    Persiani, P.J.

    1998-01-01

    The purpose of this study is to comment on the proliferation characteristic profiles of some of the proposed fuel cycle alternatives to help ensure that nonproliferation concerns are introduced into the early stages of a fuel cycle concept development program, and to perhaps aid in the more effective implementation of the international nonproliferation regime initiatives and safeguards methods and systems. Alternative cycle concepts proposed by several countries involve the recycle of spent fuel without the separation of plutonium from uranium and fission products

  3. Lubricity characteristics of marine distillate fuels

    Energy Technology Data Exchange (ETDEWEB)

    Crutchley, Ian [Innospec Fuel Specialties, Ellesmere Port (United Kingdom); Green, Michael [Intertek Lintec ShipCare Services, Darlington (United Kingdom)

    2012-08-15

    This article from Innospec Fuel Specialties, Ellesmere Port, UK, and Intertek Lintec ShipCare Services, Darlington, UK, examines the lubricity characteristics of marine distillate fuels available today in relation to the requirements and limits imposed in ISO8217:2010. It will estimate expected failure rates and also asses the perceived relationship between lubricity, sulphur content and viscosity. (orig.)

  4. Solid Oxide Fuel Cells Operating on Alternative and Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaoxing; Quan, Wenying; Xiao, Jing; Peduzzi, Emanuela; Fujii, Mamoru; Sun, Funxia; Shalaby, Cigdem; Li, Yan; Xie, Chao; Ma, Xiaoliang; Johnson, David; Lee, Jeong; Fedkin, Mark; LaBarbera, Mark; Das, Debanjan; Thompson, David; Lvov, Serguei; Song, Chunshan

    2014-09-30

    This DOE project at the Pennsylvania State University (Penn State) initially involved Siemens Energy, Inc. to (1) develop new fuel processing approaches for using selected alternative and renewable fuels – anaerobic digester gas (ADG) and commercial diesel fuel (with 15 ppm sulfur) – in solid oxide fuel cell (SOFC) power generation systems; and (2) conduct integrated fuel processor – SOFC system tests to evaluate the performance of the fuel processors and overall systems. Siemens Energy Inc. was to provide SOFC system to Penn State for testing. The Siemens work was carried out at Siemens Energy Inc. in Pittsburgh, PA. The unexpected restructuring in Siemens organization, however, led to the elimination of the Siemens Stationary Fuel Cell Division within the company. Unfortunately, this led to the Siemens subcontract with Penn State ending on September 23rd, 2010. SOFC system was never delivered to Penn State. With the assistance of NETL project manager, the Penn State team has since developed a collaborative research with Delphi as the new subcontractor and this work involved the testing of a stack of planar solid oxide fuel cells from Delphi.

  5. Hydraulic characteristics of HANARO fuel bundles

    Energy Technology Data Exchange (ETDEWEB)

    Cho, S.; Chung, H. J.; Chun, S. Y.; Yang, S. K.; Chung, M. K. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1997-12-31

    This paper presents the hydraulic characteristics measured by using LDV (Laser Doppler Velocimetry) in subchannels of HANARO, KAERI research reactor, fuel bundle. The fuel bundle consists of 18 axially finned rods with 3 spacer grids, which are arranged in cylindrical configuration. The effects of the spacer grids on the turbulent flow were investigated by the experimental results. Pressure drops for each component of the fuel bundle were measured, and the friction factors of fuel bundle and loss coefficients for the spacer grids were estimated from the measured pressure drops. Implications regarding the turbulent thermal mixing were discussed. Vibration test results measured by using laser vibrometer were presented. 9 refs., 12 figs. (Author)

  6. Hydraulic characteristics of HANARO fuel bundles

    Energy Technology Data Exchange (ETDEWEB)

    Cho, S; Chung, H J; Chun, S Y; Yang, S K; Chung, M K [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1998-12-31

    This paper presents the hydraulic characteristics measured by using LDV (Laser Doppler Velocimetry) in subchannels of HANARO, KAERI research reactor, fuel bundle. The fuel bundle consists of 18 axially finned rods with 3 spacer grids, which are arranged in cylindrical configuration. The effects of the spacer grids on the turbulent flow were investigated by the experimental results. Pressure drops for each component of the fuel bundle were measured, and the friction factors of fuel bundle and loss coefficients for the spacer grids were estimated from the measured pressure drops. Implications regarding the turbulent thermal mixing were discussed. Vibration test results measured by using laser vibrometer were presented. 9 refs., 12 figs. (Author)

  7. Non-destructive delamination detection in solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Gazzarri, J.I.; Kesler, O. [Department of Mechanical Engineering, University of British Columbia, 2054-6250 Applied Science Lane, Vancouver, BC V6T 1Z4 (Canada)

    2007-05-15

    A finite element model has been developed to simulate the steady state and impedance behaviour of a single operating solid oxide fuel cell (SOFC). The model results suggest that electrode delamination can be detected minimally-invasively by using electrochemical impedance spectroscopy. The presence of cathode delamination causes changes in the cell impedance spectrum that are characteristic of this type of degradation mechanism. These changes include the simultaneous increase in both the series and polarization resistances, in proportion to the delaminated area. Parametric studies show the dependence of these changes on the extent of delamination, on the operating point, and on the kinetic characteristics of the fuel cell under study. (author)

  8. Comparison of Fuel-Nox Formation Characteristics in Conventional Air and Oxy fuel Combustion Conditions

    International Nuclear Information System (INIS)

    Woo, Mino; Park, Kweon Ha; Choi, Byung Chul

    2013-01-01

    Nitric oxide (NO x ) formation characteristics in non-premixed diffusion flames of methane fuels have been investigated experimentally and numerically by adding 10% ammonia to the fuel stream, according to the variation of the oxygen ratio in the oxidizer with oxygen/carbon dioxide and oxygen/nitrogen mixtures. In an experiment of co flow jet flames, in the case of an oxidizer with oxygen/carbon dioxide, the NO x emission increased slightly as the oxygen ratio increased. On the other hand, in case of an oxygen/nitrogen oxidizer, the NO x emission was the maximum at an oxygen ratio of 0.7, and it exhibited non-monotonic behavior according to the oxygen ratio. Consequently, the NO x emission in the condition of oxy fuel combustion was overestimated as compared to that in the condition of conventional air combustion. To elucidate the characteristics of NO x formation for various oxidizer compositions, 1a and 2a numerical simulations have been conducted by adopting one kinetic mechanism. The result of 2 simulation for an oxidizer with oxygen/nitrogen well predicted the trend of experimentally measured NO x emissions

  9. The TMI Regenerative Solid Oxide Fuel Cell

    Science.gov (United States)

    Cable, Thomas L.; Ruhl, Robert C.; Petrik, Michael

    1996-01-01

    Energy storage and production in space requires rugged, reliable hardware which minimizes weight, volume, and maintenance while maximizing power output and usable energy storage. Systems generally consist of photovoltaic solar arrays which operate (during sunlight cycles) to provide system power and regenerate fuel (hydrogen) via water electrolysis and (during dark cycles) fuel cells convert hydrogen into electricity. Common configurations use two separate systems (fuel cell and electrolyzer) in conjunction with photovoltaic cells. Reliability, power to weight and power to volume ratios could be greatly improved if both power production (fuel cells) and power storage (electrolysis) functions can be integrated into a single unit. The solid oxide fuel cell (SOFC) based design integrates fuel cell and electrolyzer functions and potentially simplifies system requirements. The integrated fuel cell/electrolyzer design also utilizes innovative gas storage concepts and operates like a rechargeable 'hydrogen-oxygen battery'. Preliminary research has been completed on improved H2/H20 electrode (SOFC anode/electrolyzer cathode) materials for regenerative fuel cells. Tests have shown improved cell performance in both fuel and electrolysis modes in reversible fuel cell tests. Regenerative fuel cell efficiencies, ratio of power out (fuel cell mode) to power in (electrolyzer mode), improved from 50 percent using conventional electrode materials to over 80 percent. The new materials will allow a single SOFC system to operate as both the electolyzer and fuel cell. Preliminary system designs have also been developed to show the technical feasibility of using the design for space applications requiring high energy storage efficiencies and high specific energy. Small space systems also have potential for dual-use, terrestrial applications.

  10. Vibration characteristics analysis for HANARO fuel assembly

    International Nuclear Information System (INIS)

    Ryu, Jeong Soo; Yoon, Doo Byung

    2001-06-01

    For investigating the vibration characteristics of HANARO fuel assembly, the finite element models of the in-air fuel assemblies and flow tubes were developed. By calculating the hydrodynamic mass and distributing it on the in-air models, the in-water models of the flow tubes and the fuel assemblies were developed. Then, modal analysis of the developed models was carried out. The analysis results show that the fundamental vibration modes of the in-air 18-element and 36-element fuel assemblies are lateral bending modes and its corresponding natural frequencies are 26.4Hz and 27.7Hz, respectively. The fundamental natural frequency of the in-water 18-element and 36-element fuel assemblies were obtained as 16.1Hz and 16.5Hz. For the verification of the developed finite element models, modal analysis results were compared with those obtained from the modal test. These results demonstrate that the natural frequencies of lower order modes obtained from finite element analysis agree well with those of the modal test and the estimation of the hydrodynamic mass is appropriate. It is expected that the analysis results will be applied as a basic data for the operation and management of the HANARO. In addition, when it is necessary to improve the design of the fuel assembly, the developed finite element models will be utilized as a base model for the vibration characteristic analysis of the modified fuel assembly

  11. Mathematical modeling of solid oxide fuel cells

    Science.gov (United States)

    Lu, Cheng-Yi; Maloney, Thomas M.

    1988-01-01

    Development of predictive techniques, with regard to cell behavior, under various operating conditions is needed to improve cell performance, increase energy density, reduce manufacturing cost, and to broaden utilization of various fuels. Such technology would be especially beneficial for the solid oxide fuel cells (SOFC) at it early demonstration stage. The development of computer models to calculate the temperature, CD, reactant distributions in the tubular and monolithic SOFCs. Results indicate that problems of nonuniform heat generation and fuel gas depletion in the tubular cell module, and of size limitions in the monolithic (MOD 0) design may be encountered during FC operation.

  12. Critical experiments with mixed oxide fuel

    International Nuclear Information System (INIS)

    Harris, D.R.

    1997-01-01

    This paper very briefly outlines technical considerations in performing critical experiments on weapons-grade plutonium mixed oxide fuel assemblies. The experiments proposed would use weapons-grade plutonium and Er 2 O 3 at various dissolved boron levels, and for specific fuel assemblies such as the ABBCE fuel assembly with five large water holes. Technical considerations described include the core, the measurements, safety, security, radiological matters, and licensing. It is concluded that the experiments are feasible at the Rensselaer Polytechnic Institute Reactor Critical Facility. 9 refs

  13. Statistical model for grain boundary and grain volume oxidation kinetics in UO2 spent fuel

    International Nuclear Information System (INIS)

    Stout, R.B.; Shaw, H.F.; Einziger, R.E.

    1989-09-01

    This paper addresses statistical characteristics for the simplest case of grain boundary/grain volume oxidation kinetics of UO 2 to U 3 O 7 for a fragment of a spent fuel pellet. It also presents a limited discussion of future extensions to this simple case to represent the more complex cases of oxidation kinetics in spent fuels. 17 refs., 1 fig

  14. Physics characteristics of CANDU cores with advanced fuel cycles

    International Nuclear Information System (INIS)

    Garvey, P.M.

    1985-01-01

    The current generation of CANDU reactors, of which some 20 GWE are either in operations or under construction worldwide, have been designed specifically for the natural uranium fuel cycle. The CANDU concept, due to its D 2 O coolant and moderator, on-power refuelling and low absorption structural materials, makes the most effective utilization of mined uranium of all currently commercialized reactors. An economic fuel cycle cost is also achieved through the use of natural uranium and a simple fuel bundle design. Total unit energy costs are achieved that allow this reactor concept to effectively compete with other reactor types and other forms of energy production. There are, however, other fuel cycles that could be introduced into this reactor type. These include the slightly enriched uranium fuel cycle, fuel cycles in which plutonium is recycled with uranium, and the thorium cycle in which U-233 is recycled. There is also a special range of fuel cycles that could utilize the spent fuel from LWR's. Two specific variants are a fuel cycle that only utilizes the spent uranium, and a fuel cycle in which both the uranium and plutonium are recycled into a CANDU. For the main part these fuel cycles are characterized by a higher initial enrichment, and hence discharge burnup, than the natural uranium cycle. For these fuel cycles the main design features of both the reactor and fuel bundle would be retained. Recently a detailed study of the use in a CANDU of mixed plutonium and uranium oxide fuel from an LWR has been undertaken by AECL. This study illustrates many of the generic technical issues associated with the use of Advanced Fuel Cycles. This paper will report the main findings of this evaluation, including the power distribution in the reactor and fuel bundle, the choice of fuel management scheme, and the impact on the control and safety characteristics of the reactor. These studies have not identified any aspects that significantly impact upon the introduction of

  15. Acceptance of spent fuel of varying characteristics

    International Nuclear Information System (INIS)

    Short, S.M.

    1990-03-01

    This paper is a preliminary overview of a study with the primary objective of establishing a set of acceptance selection criteria and corresponding spent fuel characteristics to be incorporated as a component of requirements for the Federal Waste Management System (FWMS). A number of alternative acceptance allocations and selection rules were analyzed to determine the operational sensitivity of each element of the FWMS to the resultant spent fuel characteristics. Preliminary recommendations of the study include three different sets of selection rules to be included in the FWMS design basis. 2 refs., 4 figs., 4 tabs

  16. Improving the characteristics of liquid fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sakan, T

    1983-02-04

    In order to improve the operational characteristics of a light boiler fuel (LKT) (based on analogous characteristics for a fuel for an internal combustion engine (DVS)) it is proposed to add ether and alcohol to it. The additive of ether improves the viscosity of the fuel, but reduces the heat creating capability. The addition of ether and alcohol (a 3 to 1 ratio by volume) increases the stability of the mixture. With mixing of 75 total percent of the light boiler fuel (a heat creativity of 9,500 kilocalories per liter and a viscosity of 10 centistokes per 30 degrees) with 25 total percent ether produced a fuel with a heat producing capability of 8,690 kilocalories per liter and a viscosity of 2.3 centistokes. With mixing of 70 total percent light boiler oil and 18 total percent ether and 7 total percent alcohol a fuel with a heat creativity of 8,640 kilocalories per liter and a viscosity of 2.7 centistokes was produced.

  17. Comparison of burning characteristics of live and dead chaparral fuels

    Science.gov (United States)

    L. Sun; X. Zhou; S. Mahalingam; D.R. Weise

    2006-01-01

    Wildfire spread in living vegetation, such as chaparral in southern California, often causes significant damage to infrastructure and ecosystems. The effects of physical characteristics of fuels and fuel beds on live fuel burning and whether live fuels differ fundamentally from dead woody fuels in their burning characteristics are not well understood. Toward this end,...

  18. Fuel composition effects on HYPER core characteristics

    International Nuclear Information System (INIS)

    Han, Chi Young; Kim, Yong Nam; Kim, Jong Kyung

    2001-01-01

    At KAERI(Korea Atomic Energy Research Institute), a subcritical transmutation reactor is under development, named HYPER(Hybrid Power Extraction Reactor). For the HYPER system, a pyrochemical process is being considered for fuel reprocessing. Separated from the separation process, the fuel contains not only TRU but also the considerable percentages of impurity such as uranium nuclides and lanthanides. The amount of these impurities depends on strongly the refining efficiency of the reprocessing and may change the core characteristics. This paper has analyzed fuel composition effects on th HYPER core characteristics. Assuming various recovery factors of uranium and lanthanides, some dynamic parameters have been evaluated which are the neutron spectrum, the neutron reaction balance, the reactivity coefficients, the effective delayed neutron fraction, and the effective neutron lifetime

  19. Trends for Methane Oxidation at Solid Oxide Fuel Cell Conditions

    DEFF Research Database (Denmark)

    Kleis, Jesper; Jones, Glenn; Abild-Pedersen, Frank

    2009-01-01

    First-principles calculations are used to predict a plausible reaction pathway for the methane oxidation reaction. In turn, this pathway is used to obtain trends in methane oxidation activity at solid oxide fuel cell (SOFC) anode materials. Reaction energetics and barriers for the elementary...... the Ni surfaces to other metals of interest. This allows the reactivity over the different metals to be understood in terms of two reactivity descriptors, namely, the carbon and oxygen adsorption energies. By combining a simple free-energy analysis with microkinetic modeling, activity landscapes of anode...

  20. Development of advanced spent fuel management process. The fabrication and oxidation behavior of simulated metallized spent fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ro, Seung Gy; Shin, Y.J.; You, G.S.; Joo, J.S.; Min, D.K.; Chun, Y.B.; Lee, E.P.; Seo, H.S.; Ahn, S.B

    1999-03-01

    The simulated metallized spent fuel ingots were fabricated and evaluated the oxidation rates and the activation energies under several temperature conditions to develop an advanced spent fuel management process. It was also checked the alloying characteristics of the some elements with metal uranium. (Author). 3 refs., 1 tab., 36 figs.

  1. Thermal radiation modelling in a tubular solid oxide fuel cell

    International Nuclear Information System (INIS)

    Austin, M.E.; Pharoah, J.G.; Vandersteen, J.D.J.

    2004-01-01

    Solid Oxide Fuel Cells (SOFCs) are becoming the fuel cell of choice among companies and research groups interested in small power generation units. Questions still exist, however, about the operating characteristics of these devices; in particular the temperature distribution in the fuel cell. Using computational fluid dynamics (CFD) a model is proposed that incorporates conduction, convection and radiation. Both surface-to-surface and participating media are considered. It is hoped that a more accurate account of the temperature field in the various flow channels and cell components will be made to assist work on design of fuel cell components and reaction mechanisms. The model, when incorporating radiative heat transfer with participating media, predicts substantially lower operating temperatures and smaller temperature gradients than it does without these equations. It also shows the importance of the cathode air channel in cell cooling. (author)

  2. Modern new nuclear fuel characteristics and radiation protection aspects.

    Science.gov (United States)

    Terry, Ian R

    2005-01-01

    The glut of fissile material from reprocessing plants and from the conclusion of the cold war has provided the opportunity to design new fuel types to beneficially dispose of such stocks by generating useful power. Thus, in addition to the normal reactor core complement of enriched uranium fuel assemblies, two other types are available on the world market. These are the ERU (enriched recycled uranium) and the MOX (mixed oxide) fuel assemblies. Framatome ANP produces ERU fuel assemblies by taking feed material from reprocessing facilities and blending this with highly enriched uranium from other sources. MOX fuel assemblies contain plutonium isotopes, thus exploiting the higher neutron yield of the plutonium fission process. This paper describes and evaluates the gamma, spontaneous and alpha reaction neutron source terms of these non-irradiated fuel assembly types by defining their nuclear characteristics. The dose rates which arise from these terms are provided along with an overview of radiation protection aspects for consideration in transporting and delivering such fuel assemblies to power generating utilities.

  3. Comparison of Core Performance with Various Oxide fuels on Sodium Cooled Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jin Ha; Kim, Myung Hyun [Kyung Hee University, Yongin (Korea, Republic of)

    2016-05-15

    The system is called Prototype GenIV Sodium-cooled Fast Reactor (PGSFR). Ultimate goal of PGSFR is test for capability of TRU transmutation. Purpose of this study is test for evaluation of in-core performance and TRU transmutation performance by applying various oxide fuel loaded TRU. Fuel type of reference core is changed to uranium-based oxide fuel. Oxide fuel has a lot of experience through fuel fabrication and reactor operation. This study performed by compared and analyzed a core performance of various oxide fuels. (U,Pu)O{sub 2} and (U,TRU)O{sub 2} which various oxide fuel types are selected as extreme case for comparison with core performance and transmutation capability of TRU isotopes. Thorium-based fuel is known that it has good performance for burner reactor due to low proliferation characteristic. To check the performance of TRU incineration for comparison with uranium-based fuel on prototype SFR, Thorium-based fuel, (Th,U)O{sub 2}, (Th,Pu)O{sub 2} and (Th,TRU)O{sub 2}, is selected. Calculations of core performance for various oxide fuel are performed using the fast calculation tool, TRANSX / DANTSTS / REBUS-3. In this study, comparison of core performance and transmutation performance is conducted with various fuel types in a sodium-cooled fast reactor. Mixed oxide fuel with TRU can produce the energy with small amount of fissile material. However, the TRU fuel is confirmed to bring a potential decline of the safety parameters. In case of (Th,U)O2 fuel, the flux level in thermal neutron region becomes lower because of higher capture cross-section of Th-232 than U-238. However, Th-232 has difficulty in converting to TRU isotopes. Therefore, the TRU consumption mass is relatively high in mixed oxide fuel with thorium and TRU.

  4. Comparison of Core Performance with Various Oxide fuels on Sodium Cooled Fast Reactor

    International Nuclear Information System (INIS)

    Choi, Jin Ha; Kim, Myung Hyun

    2016-01-01

    The system is called Prototype GenIV Sodium-cooled Fast Reactor (PGSFR). Ultimate goal of PGSFR is test for capability of TRU transmutation. Purpose of this study is test for evaluation of in-core performance and TRU transmutation performance by applying various oxide fuel loaded TRU. Fuel type of reference core is changed to uranium-based oxide fuel. Oxide fuel has a lot of experience through fuel fabrication and reactor operation. This study performed by compared and analyzed a core performance of various oxide fuels. (U,Pu)O_2 and (U,TRU)O_2 which various oxide fuel types are selected as extreme case for comparison with core performance and transmutation capability of TRU isotopes. Thorium-based fuel is known that it has good performance for burner reactor due to low proliferation characteristic. To check the performance of TRU incineration for comparison with uranium-based fuel on prototype SFR, Thorium-based fuel, (Th,U)O_2, (Th,Pu)O_2 and (Th,TRU)O_2, is selected. Calculations of core performance for various oxide fuel are performed using the fast calculation tool, TRANSX / DANTSTS / REBUS-3. In this study, comparison of core performance and transmutation performance is conducted with various fuel types in a sodium-cooled fast reactor. Mixed oxide fuel with TRU can produce the energy with small amount of fissile material. However, the TRU fuel is confirmed to bring a potential decline of the safety parameters. In case of (Th,U)O2 fuel, the flux level in thermal neutron region becomes lower because of higher capture cross-section of Th-232 than U-238. However, Th-232 has difficulty in converting to TRU isotopes. Therefore, the TRU consumption mass is relatively high in mixed oxide fuel with thorium and TRU.

  5. Thermochemical aspects of fuel-cladding and fuel-coolant interactions in LMFBR oxide fuel pins

    International Nuclear Information System (INIS)

    Adamson, M.G.; Aitken, E.A.; Caputi, R.W.; Potter, P.E.; Mignanelli, M.A.

    1979-01-01

    This paper examines several thermochemical aspects of the fuel-cladding, fuel-coolant and fuel-fission product interactions that occur in LMFBR austenitic stainless steel-clad mixed (U,Pu)-oxide fuel pins during irradiation under normal operating conditions. Results are reported from a variety of high temperature EMF cell experiments in which continuous oxygen activity measurements on reacting and equilibrium mixtures of metal oxides and (excess) liquid alkali metal (Na, K, Cs) were performed. Oxygen potential and 0:M thresholds for Na-fuel reactions are re-evaluated in the light of new measurements and newly-assessed thermochemical data, and the influence on oxygen potential of possible U-Pu segregation between oxide and urano-plutonate (equilibrium) phases has been analyzed. (orig./RW) [de

  6. A review of the breeding potentials of carbide, nitride and oxide fueled LMFBRs and GCFRs

    International Nuclear Information System (INIS)

    Handa, Muneo

    1977-11-01

    The effects of design parameters in large variation on compound system doubling time of large advanced-fueled LMFBR are described on the base of recent U.S. results. The fuel element design by Combustion Engineering Inc. in step-by-step substitution of the initial oxide fuel subassemblies with carbide ones is explained. Breeding characteristics of the oxide-fueled LMFBR and its potential design modifications are expounded. The gas cooled fast breeder program in West Germany and in the United States are briefed. Definitions of the breeding ratio and doubling time in overall fuel cycle are given. (auth.)

  7. MARMOT update for oxide fuel modeling

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Schwen, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States); Chakraborty, Pritam [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jiang, Chao [Idaho National Lab. (INL), Idaho Falls, ID (United States); Aagesen, Larry [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ahmed, Karim [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jiang, Wen [Idaho National Lab. (INL), Idaho Falls, ID (United States); Biner, Bulent [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bai, Xianming [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Tonks, Michael [Pennsylvania State Univ., University Park, PA (United States); Millett, Paul [Univ. of Arkansas, Fayetteville, AR (United States)

    2016-09-01

    This report summarizes the lower-length-scale research and development progresses in FY16 at Idaho National Laboratory in developing mechanistic materials models for oxide fuels, in parallel to the development of the MARMOT code which will be summarized in a separate report. This effort is a critical component of the microstructure based fuel performance modeling approach, supported by the Fuels Product Line in the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program. The progresses can be classified into three categories: 1) development of materials models to be used in engineering scale fuel performance modeling regarding the effect of lattice defects on thermal conductivity, 2) development of modeling capabilities for mesoscale fuel behaviors including stage-3 gas release, grain growth, high burn-up structure, fracture and creep, and 3) improved understanding in material science by calculating the anisotropic grain boundary energies in UO$_2$ and obtaining thermodynamic data for solid fission products. Many of these topics are still under active development. They are updated in the report with proper amount of details. For some topics, separate reports are generated in parallel and so stated in the text. The accomplishments have led to better understanding of fuel behaviors and enhance capability of the MOOSE-BISON-MARMOT toolkit.

  8. Behaviour of defective CANDU fuel: fuel oxidation kinetic and thermodynamic modelling

    International Nuclear Information System (INIS)

    Higgs, J.

    2005-01-01

    The thermal performance of operating CANDU fuel under defect conditions is affected by the ingress of heavy water into the fuel element. A mechanistic model has been developed to predict the extent of fuel oxidation in defective fuel and its affect on fuel thermal performance. A thermodynamic treatment of such oxidized fuel has been performed as a basis for the boundary conditions in the kinetic model. Both the kinetic and thermodynamic models have been benchmarked against recent experimental work. (author)

  9. Solid oxide fuel cells and hydrogen production

    International Nuclear Information System (INIS)

    Dogan, F.

    2009-01-01

    'Full text': A single-chamber solid oxide fuel cell (SC-SOFC), operating in a mixture of fuel and oxidant gases, provides several advantages over the conventional SOFC such as simplified cell structure (no sealing required). SC-SOFC allows using a variety of fuels without carbon deposition by selecting appropriate electrode materials and cell operating conditions. The operating conditions of single chamber SOFC was studied using hydrocarbon-air gas mixtures for a cell composed of NiO-YSZ / YSZ / LSCF-Ag. The cell performance and catalytic activity of the anode was measured at various gas flow rates. The results showed that the open-circuit voltage and the power density increased as the gas flow rate increased. Relatively high power densities up to 660 mW/cm 2 were obtained in a SC-SOFC using porous YSZ electrolytes instead of dense electrolytes required for operation of a double chamber SOFC. In addition to propane- or methane-air mixtures as a fuel source, the cells were also tested in a double chamber configuration using hydrogen-air mixtures by controlling the hydrogen/air ratio at the cathode and the anode. Simulation of single chamber conditions in double chamber configurations allows distinguishing and better understanding of the electrode reactions in the presence of mixed gases. Recent research efforts; the effect of hydrogen-air mixtures as a fuel source on the performance of anode and cathode materials in single-chamber and double-chamber SOFC configurations,will be presented. The presentation will address a review on hydrogen production by utilizing of reversible SOFC systems. (author)

  10. Investigation of combustion characteristics of methane-hydrogen fuels

    Science.gov (United States)

    Vetkin, A. V.; Suris, A. L.; Litvinova, O. A.

    2015-01-01

    Numerical investigations of combustion characteristics of methane-hydrogen fuel used at present in tube furnaces of some petroleum refineries are carried out and possible problems related to change-over of existing furnaces from natural gas to methane-hydrogen fuel are analyzed. The effect of the composition of the blended fuel, associated temperature and emissivity of combustion products, temperature of combustion chamber walls, mean beam length, and heat release on variation in the radiation heat flux is investigated. The methane concentration varied from 0 to 100%. The investigations were carried out both at arbitrary given gas temperatures and at effective temperatures determined based on solving a set of equations at various heat-release rates of the combustion chamber and depended on the adiabatic combustion temperature and the temperature at the chamber output. The approximation dependence for estimation of the radiation heat exchange rate in the radiant chamber of the furnace at change-over to fuel with a greater hydrogen content is obtained. Hottel data were applied in the present work in connection with the impossibility to use approximated formulas recommended by the normative method for heat calculation of boilers to determine the gas emissivity, which are limited by the relationship of partial pressures of water steam and carbon dioxide in combustion products . The effect of the methane-hydrogen fuel on the equilibrium concentration of nitrogen oxides is also investigated.

  11. Turbulent Flame Propagation Characteristics of High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Seitzman, Jerry [Georgia Inst. of Technology, Atlanta, GA (United States); Lieuwen, Timothy [Georgia Inst. of Technology, Atlanta, GA (United States)

    2014-09-30

    This final report describes the results of an effort to better understand turbulent flame propagation, especially at conditions relevant to gas turbines employing fuels with syngas or hydrogen mixtures. Turbulent flame speeds were measured for a variety of hydrogen/carbon monoxide (H2/CO) and hydrogen/methane (H2/CH4) fuel mixtures with air as the oxidizer. The measurements include global consumption speeds (ST,GC) acquired in a turbulent jet flame at pressures of 1-10 atm and local displacement speeds (ST,LD) acquired in a low-swirl burner at atmospheric pressure. The results verify the importance of fuel composition in determining turbulent flame speeds. For example, different fuel-air mixtures having the same unstretched laminar flame speed (SL,0) but different fuel compositions resulted in significantly different ST,GC for the same turbulence levels (u'). This demonstrates the weakness of turbulent flame speed correlations based simply on u'/SL,0. The results were analyzed using a steady-steady leading points concept to explain the sensitivity of turbulent burning rates to fuel (and oxidizer) composition. Leading point theories suggest that the premixed turbulent flame speed is controlled by the flame front characteristics at the flame brush leading edge, or, in other words, by the flamelets that advance farthest into the unburned mixture (the so-called leading points). For negative Markstein length mixtures, this is assumed to be close to the maximum stretched laminar flame speed (SL,max) for the given fuel-oxidizer mixture. For the ST,GC measurements, the data at a given pressure were well-correlated with an SL,max scaling. However the variation with pressure was not captured, which may be due to non-quasi-steady effects that are not included in the current model. For the ST,LD data, the leading points model again faithfully captured the variation of turbulent flame speed over a wide range of fuel-compositions and turbulence intensities. These

  12. Durable and Robust Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Hjalmarsson, Per; Knibbe, Ruth; Hauch, Anne

    project had as one of its’ overarching goals to improve durability and robustness of the Danish solid oxide fuel cells. The project focus was on cells and cell components suitable for SOFC operation in the temperature range 600 – 750 °C. The cells developed and/or studied in this project are intended......The solid oxide fuel cell (SOFC) is an attractive technology for the generation of electricity with high efficiency and low emissions. Risø DTU (now DTU Energy Conversion) works closely together with Topsoe Fuel Cell A/S in their effort to bring competitive SOFC systems to the market. This 2-year...... for use within the CHP (Combined Heat and Power) market segment with stationary power plants in the range 1 – 250 kWe in mind. Lowered operation temperature is considered a good way to improve the stack durability since corrosion of the interconnect plates in a stack is lifetime limiting at T > 750 °C...

  13. Performance analysis of hybrid solid oxide fuel cell and gas turbine cycle: Application of alternative fuels

    International Nuclear Information System (INIS)

    Zabihian, Farshid; Fung, Alan S.

    2013-01-01

    Highlights: • Variation of the stream properties in the syngas-fueled hybrid SOFC–GT cycle. • Detailed analysis of the operation of the methane-fueled SOFC–GT cycle. • Investigate effects of inlet fuel type and composition on performance of cycle. • Comparison of system operation when operated with and without anode recirculation. - Abstract: In this paper, the hybrid solid oxide fuel cell (SOFC) and gas turbine (GT) model was applied to investigate the effects of the inlet fuel type and composition on the performance of the cycle. This type of analysis is vital for the real world utilization of manufactured fuels in the hybrid SOFC–GT system due to the fact that these fuel compositions depends on the type of material that is processed, the fuel production process, and process control parameters. In the first part of this paper, it is shown that the results of a limited number of studies on the utilization of non-conventional fuels have been published in the open literature. However, further studies are required in this area to investigate all aspects of the issue for different configurations and assumptions. Then, the results of the simulation of the syngas-fueled hybrid SOFC–GT cycle are employed to explain the variation of the stream properties throughout the cycle. This analysis can be very helpful in understanding cycle internal working and can provide some interesting insights to the system operation. Then, the detailed information of the operation of the methane-fueled SOFC–GT cycle is presented. For both syngas- and methane-fueled cycles, the operating conditions of the equipment are presented and compared. Moreover, the comparison of the characteristics of the system when it is operated with two different schemes to provide the required steam for the cycle, with anode recirculation and with an external source of water, provides some interesting insights to the system operation. For instance, it was shown that although the physical

  14. Solid Oxide Fuel Cell Systems PVL Line

    International Nuclear Information System (INIS)

    Shearer, Susan; Rush, Gregory

    2012-01-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability to

  15. Predicting spent fuel oxidation states in a tuff repository

    International Nuclear Information System (INIS)

    Einziger, R.E.; Woodley, R.E.

    1987-01-01

    Nevada Nuclear Waste Storage Investigations Project (NNWSI) is studying the suitability of the tuffaceous rocks at Yucca Mountain as a waste repository for spent fuel disposal. The oxidation state of the LWR spent fuel in the moist air environment of a tuff repository could be a significant factor in determining its leaching and dissolution characteristics. Predictions as to which oxidation states would be present are important in analyzing such a repository and thus the present study was undertaken. A set of TGA (thermogravimetric analysis) tests were conducted on well-controlled samples of irradiated PWR fuel with time and temperature as the only variables. The tests were conducted between 140 and 225 0 C for a duration up to 2200 hours. The weight gain curves were analyzed in terms of diffusion through a layer of U 3 O 7 , diffusion into the grains to form a solid solution, a simplified empirical representation of a combination of grain boundary diffusion and bulk grain oxidation. Reaction rate constants were determined in each case, but analysis of these data could not establish a definitive mechanism. 21 refs., 10 figs., 3 tabs

  16. Tubular solid oxide fuel cell development program

    Energy Technology Data Exchange (ETDEWEB)

    Ray, E.R.; Cracraft, C.

    1995-12-31

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  17. Solid oxide fuel cell field trial evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Wilcox, C.P.; Winstanley, R.; Nietsch, T.; Smith, C.; Knight, R.; Seymore, C.

    2000-07-01

    This report focuses on issues relating to a field trial of a solid oxide fuel cell (SOFC). Aspects examined include markets for SOFC systems, the choice of systems for demonstration in year 2002, the assessment of industrial interest, and evaluation and ranking of candidate systems. The identification and evaluation of interest in field trials, the estimation of the capital and running costs of a field trial, and identification of the benefits to the UK and barriers to implementation of SOFC systems are discussed. (UK)

  18. Spent oxide fuel regeneration by crystallization in molybdate melts

    International Nuclear Information System (INIS)

    Ustinov, O.A.; Sukhanov, L.P.; Yakunin, S.A.

    2006-01-01

    Paper describes a procedure to regenerate spent oxide fuel by its crystallization in molybdate melts. Paper presents the process procedures to regenerate spent fuel of both fast and thermal neutron reactors. One analyzes the advantages of the elaborated procedure [ru

  19. Fuel temperature characteristics of the 37-element and CANFLEX fuel bundle

    International Nuclear Information System (INIS)

    Bae, Jun Ho; Rho, Gyu Hong; Park, Joo Hwan

    2009-10-01

    This report describes the fuel temperature characteristics of CANFLEX fuel bundles and 37-element fuel bundles for a different burnup of fuel. The program was consisted for seeking the fuel temperature of fuel bundles of CANFLEX fuel bundles and 37-element fuel bundles by using the method in NUCIRC. Fuel temperature has an increasing pattern with the burnup of fuel for CANFLEX fuel bundles and 37-element fuel bundles. For all the case of burnup, the fuel temperature of CANFLEX fuel bundles has a lower value than that of 37-element fuel bundles. Especially, for the high power channel, the CANFLEX fuel bundles show a lower fuel temperature as much as about 75 degree, and the core averaged fuel temperature has a lower fuel temperature of about 50 degree than that of 37-element fuel bundles. The lower fuel temperature of CANFLEX fuel bundles is expected to enhance the safety by reducing the fuel temperature coefficient. Finally, for each burnup of CANFLEX fuel bundles and 37-element fuel bundles, the equation was present for predicting the fuel temperature of a bundle in terms of a coolant temperature and bundle power

  20. Comparison of fuel cycles characteristics for nuclear energy systems based on WWER-TOI and BN-1200 reactors

    International Nuclear Information System (INIS)

    Kagramanyan, V.S.; Kalashnikov, A.G.; Kapranova, Eh.N.; Puzakov, A.Yu.

    2014-01-01

    Authors determine the characteristics of the fuel cycle (FC) based on stationary nuclear power system based on WWER-TOI and BN-1200 reactors with fuel of different composition. Characteristics of reactor systems with partial or complete spent nuclear fuel reprocessing and recycling of plutonium are compared to those of the reference system consisting only of WWER-TOI with uranium oxide fuel, operating in an open FC [ru

  1. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Coffey, G.W.; Pederson, L.R. [Pacific Northwest National Lab., Richland, WA (United States)] [and others

    1996-08-01

    Chromite interconnection materials in an SOFC are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. Because such conditions could lead to component failure, the authors have evaluated thermal, electrical, chemical, and structural stabilities of these materials as a function of temperature and oxygen partial pressure. The crystal lattice of the chromites was shown to expand for oxygen partial pressures smaller than 10{sup {minus}10} atm, which could lead to cracking and debonding in an SOFC. Highly substituted lanthanum chromite compositions were the most susceptible to lattice expansion; yttrium chromites showed better dimensional stability by more than a factor of two. New chromite compositions were developed that showed little tendency for lattice expansion under strongly reducing conditions, yet provided a good thermal expansion match to other fuel cell components. Use of these new chromite interconnect compositions should improve long-term SOFC performance, particularly for planar cell configurations. Thermodynamic properties of substituted lanthanum manganite cathode compositions have been determined through measurement of electromotive force as a function of temperature. Critical oxygen decomposition pressures for Sr and Ca-substituted lanthanum manganites were established using cells based on a zirconia electrolyte. Strontium oxide and calcium oxide activities in a lanthanum manganite matrix were determined using cells based on strontium fluoride and calcium fluoride electrolytes, respectively. The compositional range of single-phase behavior of these ABO{sub 3}-type perovskites was established as a function of A/B cation ratios and the extent of acceptor doping. Before this work, very little thermodynamic information was in existence for substituted manganite compositions. Such information is needed to predict the long-term stability of solid oxide fuel cell assemblies.

  2. Development of solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Dae Kab; Kim, Sun Jae; Jung, Choong Hwan; Kim, Kyung Hoh; Park, Ji Yun; Oh, Suk Jin [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-01-01

    Solid Oxide Fuel Cell (SOFC) technologies that use zirconium oxide as the electrolyte material were studied in this present report. SOFC exhibits a very high power generation efficiency of over 50 %, and does not discharge pollution materials such as dusts, sulfur dioxide, and nitrogen oxide. Zirconia, Ni/YSZ (yttria stabilized zirconia), and La-Sr-Mn-Oxide materials were developed for the electrolyte material, for the anode, and for the cathode, respectively. After making thin zirconia plate using tape casting process, anode and cathode powders were screen printed on the zirconia plate for fabricating unit cells. A test system composed of a vertical tube furnace, digital multimeter, DC current supplier, and measuring circuit was constructed for testing the unit cell performance. This system was controlled by a home-made computer program. Founded on this unit cell technology and system, a multi-stack SOFC system was studied. This system was composed of 10 unit cells each of them had an electrode area of 40 x 40 mm. Based on this system design, large and thin zirconia plates of 70 x 70 mm in area was fabricated for the electrolyte. Different from in the unit cell system, interconnectors are needed in the multi-stack system for connecting unit cells electrically. For this interconnectors, Inconel 750 alloy was selected, sliced into wafers, machined, surface finished, and then Pt-plated. 55 figs, 8 tabs, 51 refs. (Author).

  3. Development of solid oxide fuel cell technology

    International Nuclear Information System (INIS)

    Kang, Dae Kab; Kim, Sun Jae; Jung, Choong Hwan; Kim, Kyung Hoh; Park, Ji Yun; Oh, Suk Jin

    1995-01-01

    Solid Oxide Fuel Cell (SOFC) technologies that use zirconium oxide as the electrolyte material were studied in this present report. SOFC exhibits a very high power generation efficiency of over 50 %, and does not discharge pollution materials such as dusts, sulfur dioxide, and nitrogen oxide. Zirconia, Ni/YSZ (yttria stabilized zirconia), and La-Sr-Mn-Oxide materials were developed for the electrolyte material, for the anode, and for the cathode, respectively. After making thin zirconia plate using tape casting process, anode and cathode powders were screen printed on the zirconia plate for fabricating unit cells. A test system composed of a vertical tube furnace, digital multimeter, DC current supplier, and measuring circuit was constructed for testing the unit cell performance. This system was controlled by a home-made computer program. Founded on this unit cell technology and system, a multi-stack SOFC system was studied. This system was composed of 10 unit cells each of them had an electrode area of 40 x 40 mm. Based on this system design, large and thin zirconia plates of 70 x 70 mm in area was fabricated for the electrolyte. Different from in the unit cell system, interconnectors are needed in the multi-stack system for connecting unit cells electrically. For this interconnectors, Inconel 750 alloy was selected, sliced into wafers, machined, surface finished, and then Pt-plated. 55 figs, 8 tabs, 51 refs. (Author)

  4. Study on Thermal Degradation Characteristics and Regression Rate Measurement of Paraffin-Based Fuel

    Directory of Open Access Journals (Sweden)

    Songqi Hu

    2015-09-01

    Full Text Available Paraffin fuel has been found to have a regression rate that is higher than conventional HTPB (hydroxyl-terminated polybutadiene fuel and, thus, presents itself as an ideal energy source for a hybrid rocket engine. The energy characteristics of paraffin-based fuel and HTPB fuel have been calculated by the method of minimum free energy. The thermal degradation characteristics were measured for paraffin, pretreated paraffin, HTPB and paraffin-based fuel in different working conditions by the using differential scanning calorimetry (DSC and a thermogravimetric analyzer (TGA. The regression rates of paraffin-based fuel and HTPB fuel were tested by a rectangular solid-gas hybrid engine. The research findings showed that: the specific impulse of paraffin-based fuel is almost the same as that of HTPB fuel; the decomposition temperature of pretreated paraffin is higher than that of the unprocessed paraffin, but lower than that of HTPB; with the increase of paraffin, the initial reaction exothermic peak of paraffin-based fuel is reached in advance, and the initial reaction heat release also increases; the regression rate of paraffin-based fuel is higher than the common HTPB fuel under the same conditions; with the increase of oxidizer mass flow rate, the regression rate of solid fuel increases accordingly for the same fuel formulation.

  5. Experimental investigation of spray characteristics of alternative aviation fuels

    International Nuclear Information System (INIS)

    Kannaiyan, Kumaran; Sadr, Reza

    2014-01-01

    Highlights: • Physical properties of GTL fuel are different from those of conventional jet fuels. • Spray characteristics of GTL and Jet A-1 fuels are experimentally investigated using phase Doppler anemometry. • Regions near the nozzle are influenced by differences in fuel physical properties. • Spray characteristics of GTL can be predicted by empirical relations developed for conventional jet fuels. - Abstract: Synthetic fuels derived from non-oil feedstock are gaining importance due to their cleaner combustion characteristics. This work investigates spray characteristics of two Gas-to-Liquid (GTL) synthetic jet fuels from a pilot-scale pressure swirl nozzle and compares them with those of the conventional Jet A-1 fuel. The microscopic spray parameters are measured at 0.3 and 0.9 MPa injection pressures at several points in the spray using phase Doppler anemometry. The results show that the effect of fuel physical properties on the spray characteristics is predominantly evident in the regions close to the nozzle exit at the higher injection pressure. The lower viscosity and surface tension of GTL fuel seems to lead to faster disintegration and dispersion of the droplets when compared to those of Jet A-1 fuel under atmospheric conditions. Although the global characteristics of the fuels are similar, the effects of fuel properties are evident on the local spray characteristics at the higher injection pressure

  6. Addressing fuel recycling in solid oxide fuel cell systems fed by alternative fuels

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2017-01-01

    An innovative study on anode recirculation in solid oxide fuel cell systems with alternative fuels is carried out and investigated. Alternative fuels under study are ammonia, pure hydrogen, methanol, ethanol, DME and biogas from biomass gasification. It is shown that the amount of anode off......%. Furthermore, it is founded that for the case with methanol, ethanol and DME then at high utilization factors, low anode recirculation is recommended while at low utilization factors, high anode recirculation is recommended. If the plant is fed by biogas from biomass gasification then for each utilization...

  7. Integrated analysis of oxide nuclear fuel sintering

    International Nuclear Information System (INIS)

    Baranov, V.; Kuzmin, R.; Tenishev, A.; Timoshin, I.; Khlunov, A.; Ivanov, A.; Petrov, I.

    2011-01-01

    Dilatometric and thermal-gravimetric investigations have been carried out for the sintering process of oxide nuclear fuel in gaseous Ar - 8% H 2 atmosphere at temperatures up to 1600 0 C. The pressed compacts were fabricated under real production conditions of the OAO MSZ with application of two different technologies, so called 'dry' and 'wet' technologies. Effects of the grain size growth after the heating to different temperatures were observed. In order to investigate the effects produced by rate of heating on properties of sintered fuel pellets, the heating rates were varied from 1 to 8 0 C per minute. Time of isothermal overexposure at maximal temperature (1600 0 C) was about 8 hours. Real production conditions were imitated. The results showed that the sintering process of the fuel pellets produced by two technologies differs. The samples sintered under different heating rates were studied with application of scanning electronic microscopy analysis for determination of mean grain size. A simulation of heating profile for industrial furnaces was performed to reduce the beam cycles and estimate the effects of variation of the isothermal overexposure temperatures. Based on this data, an optimization of the sintering conditions was performed in operations terms of OAO MSZ. (authors)

  8. Burnup simulations and spent fuel characteristics of ZrO{sub 2} based inert matrix fuels

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, E.A. [Department of Mechanical Engineering, University of Texas, Austin, TX (United States); Deinert, M.R. [Department of Theoretical and Applied Mechanics, Cornell University, Ithaca, NY (United States)]. E-mail: mrd6@cornell.edu; Herring, S.T. [Idaho National Laboratory, Idaho Falls, ID (United States); Cady, K.B. [Department of Theoretical and Applied Mechanics, Cornell University, Ithaca, NY (United States)

    2007-03-31

    Reducing the inventory of long lived isotopes that are contained in spent nuclear fuel is essential for maximizing repository capacity and extending the lifetime of related storage. Because of their non-fertile matrices, inert matrix fuels (IMF's) could be an ideal vehicle for using light-water reactors to help decrease the inventory of plutonium and other transuranics (neptunium, americium, curium) that are contained within spent uranium oxide fuel (UOX). Quantifying the characteristics of spent IMF is therefore of fundamental importance to determining its effect on repository design and capacity. We consider six ZrO{sub 2} based IMF formulations with different transuranic loadings in a 1-8 IMF to UOX pin-cell arrangement. Burnup calculations are performed using a collision probability model where transport of neutrons through space is modeled using fuel to moderator transport and escape probabilities. The lethargy dependent neutron flux is treated with a high resolution multigroup thermalization method. The results of the reactor physics model are compared to a benchmark case performed with Montebruns and indicate that the approach yields reliable results applicable to high-level analyses of spent fuel isotopics. The data generated show that a fourfold reduction in the radiological and integrated thermal output is achievable in single recycle using IMF, as compared to direct disposal of an energy equivalent spent UOX.

  9. Characteristics of used CANDU fuel relevant to the Canadian nuclear fuel waste management program

    Energy Technology Data Exchange (ETDEWEB)

    Wasywich, K M

    1993-05-01

    Literature data on the characteristics of used CANDU power reactor fuel that are relevant to its performance as a waste form have been compiled in a convenient handbook. Information about the quantities of used fuel generated, burnup, radionuclide inventories, fission gas release, void volume and surface area, fuel microstructure, fuel cladding properties, changes in fuel bundle properties due to immobilization processes, radiation fields, decay heat and future trends is presented for various CANDU fuel designs. (author). 199 refs., 39 tabs., 100 figs.

  10. Characteristics of used CANDU fuel relevant to the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    Wasywich, K.M.

    1993-05-01

    Literature data on the characteristics of used CANDU power reactor fuel that are relevant to its performance as a waste form have been compiled in a convenient handbook. Information about the quantities of used fuel generated, burnup, radionuclide inventories, fission gas release, void volume and surface area, fuel microstructure, fuel cladding properties, changes in fuel bundle properties due to immobilization processes, radiation fields, decay heat and future trends is presented for various CANDU fuel designs. (author). 199 refs., 39 tabs., 100 figs

  11. Technical test description of activities to determine the potential for spent fuel oxidation in a tuff repository

    International Nuclear Information System (INIS)

    Einziger, R.E.

    1985-06-01

    The potential change in the oxidation state of spent fuel during its residence in a repository must be known to evaluate its radionuclide retention capabilities. Once the container breaches, the spent fuel in a repository sited above the water table will be exposed to a moist air atmosphere at low temperatures. Thermodynamically, there is no reason why the fuel should not oxidize to a higher oxidation state under these conditions, given enough time. Depending on the rate of oxidation, higher oxides with potentially higher leach rates may eventually form or the cladding may even split open. If either of these oxidation effects occurs, the ability of spent fuel to retard radionuclide migration will be reduced. A technical test description is presented to study spent fuel oxidation at low temperatures characteristic of the post-container breach period and at high temperatures in a moist inert atmosphere characteristic of a sealed container with waterlogged fuel, early in the repository life. The approach taken will be to perform tests and evaluations to gain understanding of the operative oxidation mechanisms, to obtain oxidation rate data, and to make projections of potential long-term fuel oxidation states. Time and temperature dependence of existing models will be evaluated, and the dependence of the model projections on fuel variables will be determined. 27 refs., 7 figs., 4 tabs

  12. Fuel cracking in relation to fuel oxidation in support of an out-reactor instrumented defected fuel experiment

    Energy Technology Data Exchange (ETDEWEB)

    Quastel, A.; Thiriet, C. [Atomic Energy of Canada Limited, Chalk River, ON (Canada); Lewis, B., E-mail: brent.lewis@uoit.ca [Univ. of Ontario Inst. of Tech., Oshawa, ON (Canada); Corcoran, E., E-mail: emily.corcoran@rmc.ca [Royal Military College of Canada, Kingston, ON (Canada)

    2014-07-01

    An experimental program funded by the CANDU Owners Group (COG) is studying an out-reactor instrumented defected fuel experiment in Stern Laboratories (Hamilton, Ontario) with guidance from Atomic Energy of Canada Limited (AECL). The objective of this test is to provide experimental data for validation of a mechanistic fuel oxidation model. In this experiment a defected fuel element with UO{sub 2} pellets will be internally heated with an electrical heater element, causing the fuel to crack. By defecting the sheath in-situ the fuel will be exposed to light water coolant near normal reactor operating conditions (pressure 10 MPa and temperature 265-310{sup o}C) causing fuel oxidation, especially near the hotter regions of the fuel in the cracks. The fuel thermal conductivity will change, resulting in a change in the temperature distribution of the fuel element. This paper provides 2D r-θ plane strain solid mechanics models to simulate fuel thermal expansion, where conditions for fuel crack propagation are investigated with the thermal J integral to predict fuel crack stress intensity factors. Finally since fuel crack geometry can affect fuel oxidation this paper shows that the solid mechanics model with pre-set radial cracks can be coupled to a 2D r-θ fuel oxidation model. (author)

  13. Performance Evaluation of Solid Oxide Fuel Cell by Computer ...

    African Journals Online (AJOL)

    The search for sustainable energy source that can compete with the existing one led to the discovery and acceptance of fuel cell technologies as a perfect replacement for fossil fuel. The ability of Solid Oxide Fuel Cells (SOFC) to capture the heat generation during the process of energy generation from electrochemical ...

  14. Reviews on Solid Oxide Fuel Cell Technology

    Directory of Open Access Journals (Sweden)

    Apinan Soottitantawat

    2009-02-01

    Full Text Available Solid Oxide Fuel Cell (SOFC is one type of high temperature fuel cell that appears to be one of the most promising technology to provide the efficient and clean energy production for wide range of applications (from small units to large scale power plants. This paper reviews the current status and related researches on SOFC technologies. In details, the research trend for the development of SOFC components(i.e. anode, electrolyte, cathode, and interconnect are presented. Later, the current important designs of SOFC (i.e. Seal-less Tubular Design, Segmented Cell in Series Design, Monolithic Design and Flat Plate Design are exampled. In addition, the possible operations of SOFC (i.e. external reforming, indirect internal reforming, and direct internal reforming are discussed. Lastly, the research studies on applications of SOFCs with co-generation (i.e. SOFC with Combined Heat and Power (SOFC-CHP, SOFC with Gas Turbine (SOFC-GT and SOFC with chemical production are given.

  15. Learning curves for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Rivera-Tinoco, R.; Schoots, K. [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Zwaan, B.C.C. van der [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Columbia Univ., New York City, NY (United States). Lenfest Center for Sustainable Energy

    2010-07-01

    We present learning curves for solid oxide fuel cells (SOFCs) and combined heat and power (CHP) SOFC systems with an electric capacity between 1 and 250 kW. On the basis of the cost breakdown of production cost data from fuel cell manufacturers, we developed a bottom-up model that allows for determining overall manufacturing costs from their respective cost components, among which material, energy, labor, and capital charges. The results obtained from our model prove to deviate by at most 13% from total cost figures quoted in the literature. For the early pilot stage of development, we find for SOFC manufacturing a learning rate between 14% and 17%, and for total SOFC system fabrication between 16% and 19%. We argue that the corresponding cost reductions result largely from learning-by-searching effects (R and D) rather than learning-by-doing. When considering a longer time frame that includes the early commercial production stage, we find learning rates between 14% and 39%, which represent a mix of phenomena such as learning-by-doing, learning-by-searching, economies-of-scale and automation. (orig.)

  16. Nanostructured Solid Oxide Fuel Cell Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Sholklapper, Tal Zvi [Univ. of California, Berkeley, CA (United States)

    2007-01-01

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  17. Solid Oxide Fuel Cells Canada (SOFCC)

    International Nuclear Information System (INIS)

    Birss, V.; Borglum, B.

    2006-01-01

    Vision: To enhance co-ordination and to ensure sustainable funding of research, development, and commercialization of solid oxide fuel cells and related technologies in Canada in order to create products that serve the world. Current Research Areas of Investigation: Mission: To provide cleaner air, reduce CO 2 emissions, better utilize fuel resources, increase economic prosperity, and enhance the quality of life in Canada and the world by enabling and accelerating development of the Canadian SOFC industry. To achieve this, we will: 1. Establish national priorities for the research, development, design, demonstration, and the innovation process; commercialization of SOFC and related technologies; 2. Develop a strategy to produce commercial products within 5 years; 3. Co-ordinate activities as one integrated Canada-wide initiative; 4. Facilitate effective access to funding by providing a venue for funders to directly participate in; 5. Provide an integrating and interdisciplinary function to maximize the collective knowledge, expertise, and capacity of the alliance partners; 6. Maintain strategic relevance within an ever changing global context by providing high-quality intelligence. (author)

  18. Advanced methods of solid oxide fuel cell modeling

    CERN Document Server

    Milewski, Jaroslaw; Santarelli, Massimo; Leone, Pierluigi

    2011-01-01

    Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. ""Advanced Methods of Solid Oxide Fuel Cell Modeling"" proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. ""Advanced Methods

  19. Learning curves for solid oxide fuel cells

    International Nuclear Information System (INIS)

    Rivera-Tinoco, Rodrigo; Schoots, Koen; Zwaan, Bob van der

    2012-01-01

    Highlights: ► We present learning curves for fuel cells based on empirical data. ► We disentangle different cost reduction mechanisms for SOFCs. ► We distinguish between learning-by-doing, R and D, economies-of-scale and automation. - Abstract: In this article we present learning curves for solid oxide fuel cells (SOFCs). With data from fuel cell manufacturers we derive a detailed breakdown of their production costs. We develop a bottom-up model that allows for determining overall SOFC manufacturing costs with their respective cost components, among which material, energy, labor and capital charges. The results obtained from our model prove to deviate by at most 13% from total cost figures quoted in the literature. For the R and D stage of development and diffusion, we find local learning rates between 13% and 17% and we demonstrate that the corresponding cost reductions result essentially from learning-by-searching effects. When considering periods in time that focus on the pilot and early commercial production stages, we find regional learning rates of 27% and 1%, respectively, which we assume derive mainly from genuine learning phenomena. These figures turnout significantly higher, approximately 44% and 12% respectively, if also effects of economies-of-scale and automation are included. When combining all production stages we obtain lr = 35%, which represents a mix of cost reduction phenomena. This high learning rate value and the potential to scale up production suggest that continued efforts in the development of SOFC manufacturing processes, as well as deployment and use of SOFCs, may lead to substantial further cost reductions.

  20. The burnup dependence of light water reactor spent fuel oxidation

    International Nuclear Information System (INIS)

    Hanson, B.D.

    1998-07-01

    Over the temperature range of interest for dry storage or for placement of spent fuel in a permanent repository under the conditions now being considered, UO 2 is thermodynamically unstable with respect to oxidation to higher oxides. The multiple valence states of uranium allow for the accommodation of interstitial oxygen atoms in the fuel matrix. A variety of stoichiometric and nonstoichiometric phases is therefore possible as the fuel oxidizers from UO 2 to higher oxides. The oxidation of UO 2 has been studied extensively for over 40 years. It has been shown that spent fuel and unirradiated UO 2 oxidize via different mechanisms and at different rates. The oxidation of LWR spent fuel from UO 2 to UO 2.4 was studied previously and is reasonably well understood. The study presented here was initiated to determine the mechanism and rate of oxidation from UO 2.4 to higher oxides. During the early stages of this work, a large variability in the oxidation behavior of samples oxidized under nearly identical conditions was found. Based on previous work on the effect of dopants on UO 2 oxidation and this initial variability, it was hypothesized that the substitution of fission product and actinide impurities for uranium atoms in the spent fuel matrix was the cause of the variable oxidation behavior. Since the impurity concentration is roughly proportional to the burnup of a specimen, the oxidation behavior of spent fuel was expected to be a function of both temperature and burnup. This report (1) summarizes the previous oxidation work for both unirradiated UO 2 and spent fuel (Section 2.2) and presents the theoretical basis for the burnup (i.e., impurity concentration) dependence of the rate of oxidation (Sections 2.3, 2.4, and 2.5), (2) describes the experimental approach (Section 3) and results (Section 4) for the current oxidation tests on spent fuel, and (3) establishes a simple model to determine the activation energies associated with spent fuel oxidation (Section 5)

  1. Vibrational characteristics and wear of fuel rods

    International Nuclear Information System (INIS)

    Schmugar, K.L.

    1977-01-01

    Fuel rod wear, due to vibration, is a continuing concern in the design of liquid-cooled reactors. In my report, the methodology and models that are used to predict fuel rod vibrational response and vibratory wear, in a light water reactor environment, are discussed. This methodology is being followed at present in the design of Westinghouse Nuclear Fuel. Fuel rod vibrations are expressed as the normal bending modes, and sources of rod vibration are examined with special emphasis on flow-induced mechanisms in the stable flow region. In a typical Westinghouse PWR fuel assembly design, each fuel rod is supported at multiple locations along the rod axis by a square-shaped 'grid cell'. For a fuel rod /grid support system, the development of small oscillatory motions, due to fluid flow at the rod/grid interface, results in material wear. A theoretical wear mode is developed using the Archard Theory of Adhesive Wear as the basis. Without question certainty, fretting wear becomes a serious problem if it progresses to the stage where the fuel cladding is penetrated and fuel is exposed to the coolant. Westinghouse fuel is designed to minimize fretting wear by limiting the relative motion between the fuel rod and its supports. The wear producing motion between the fuel rod and its supports occurs when the vibration amplitude exceeds the slippage threshold amplitude

  2. Post operation: The changing characteristics of nuclear fuel cycle costs

    International Nuclear Information System (INIS)

    Frank, F.J.

    1986-01-01

    Fundamental changes have occurred in the nuclear fuel cycle. These changes forged by market forces, legislative action, and regulatory climate appear to be a long term characteristic of the nuclear fuel cycle. The nature of these changes and the resulting emerging importance of post-operation and its impact on fuel cycle costs are examined

  3. Characteristics of Butanol Isomers Oxidation in a Micro Flow Reactor

    KAUST Repository

    Bin Hamzah, Muhamad Firdaus

    2017-05-01

    Ignition and combustion characteristics of n-butanol/air, 2-butanol.air and isobutanol/air mixtures at stoichiometric (ϕ = 1) and lean (ϕ = 0.5) conditions were investigated in a micro flow reactor with a controlled temperature profile from 323 K to 1313 K, under atmospheric pressure. Sole distinctive weak flame was observed for each mixture, with inlet fuel/air mixture velocity set low at 2 cm/s. One-dimensional computation with comprehensive chemistry and transport was conducted. At low mixture velocities, one-stage oxidation was confirmed from heat release rate profiles, which was broadly in agreement with the experimental results. The weak flame positions were congruent with literature describing reactivity of the butanol isomers. These weak flame responses were also found to mirror the trend in Anti-Knock Indexes of the butanol isomers. Flux and sensitivity analyses were performed to investigate the fuel oxidation pathways at low and high temperatures. Further computational investigations on oxidation of butanol isomers at higher pressure of 5 atm indicated two-stage oxidation through the heat release rate profiles. Low temperature chemistry is accentuated in the region near the first weak cool flame for oxidation under higher pressure, and its impact on key species – such as hydroxyl radical, hydrogen peroxide and carbon monoxide – were considered. Both experimental and computational findings demonstrate the advantage of employing the micro flow reactor in investigating oxidation processes in the temperature region of interest along the reactor channel. By varying physical conditions such as pressure, the micro flow reactor system is proven to be highly beneficial in elucidating oxidation behavior of butanol isomers in conditions in engines such as those that mirror HCCI operations.

  4. Aluminum cladding oxidation of prefilmed in-pile fueled experiments

    Energy Technology Data Exchange (ETDEWEB)

    Marcum, W.R., E-mail: marcumw@engr.orst.edu [Oregon State University, School of Nuclear Science and Engineering, 116 Radiation Center, Corvallis, OR 97331 (United States); Wachs, D.M.; Robinson, A.B.; Lillo, M.A. [Idaho National Laboratory, Nuclear Fuels & Materials Department, 2525 Fremont Ave., Idaho Falls, ID 83415 (United States)

    2016-04-01

    A series of fueled irradiation experiments were recently completed within the Advanced Test Reactor Full size plate In center flux trap Position (AFIP) and Gas Test Loop (GTL) campaigns. The conduct of the AFIP experiments supports ongoing efforts within the global threat reduction initiative (GTRI) to qualify a new ultra-high loading density low enriched uranium-molybdenum fuel. This study details the characterization of oxide growth on the fueled AFIP experiments and cross-correlates the empirically measured oxide thickness values to existing oxide growth correlations and convective heat transfer correlations that have traditionally been utilized for such an application. This study adds new and valuable empirical data to the scientific community with respect to oxide growth measurements of highly irradiated experiments, of which there is presently very limited data. Additionally, the predicted oxide thickness values are reconstructed to produce an oxide thickness distribution across the length of each fueled experiment (a new application and presentation of information that has not previously been obtainable in open literature); the predicted distributions are compared against experimental data and in general agree well with the exception of select outliers. - Highlights: • New experimental data is presented on oxide layer thickness of irradiated aluminum fuel. • Five oxide growth correlations and four convective heat transfer correlations are used to compute the oxide layer thickness. • The oxide layer thickness distribution is predicted via correlation for each respective experiment. • The measured experiment and predicted distributions correlate well, with few outliers.

  5. Unified approach to the study of solid fuel combustion characteristics at high airflow speeds

    Science.gov (United States)

    Vnuchkov, D. A.; Lukashevich, S. V.; Nalivaychenko, D. G.; Zvegintsev, V. I.

    2017-10-01

    The main objective of the research is the development of guidelines for a unified approach to testing the combustion of different solid fuels in gaseous oxidant high-speed flow, so that research outcomes could be presented in a standardized and cohesive form. All the experiments were performed on a special experimental installation designed for quantification of the burning characteristics of different fuels in a wide range of the airflow parameters at the same geometry of the combustion chamber.

  6. Interim results from UO2 fuel oxidation tests in air

    International Nuclear Information System (INIS)

    Campbell, T.K.; Gilbert, E.R.; Thornhill, C.K.; White, G.D.; Piepel, G.F.; Griffin, C.W.j.

    1987-08-01

    An experimental program is being conducted at Pacific Northwest Laboratory (PNL) to extend the characterization of spent fuel oxidation in air. To characterize oxidation behavior of irradiated UO 2 , fuel oxidation tests were performed on declad light-water reactor spent fuel and nonirradited UO 2 pellets in the temperature range of 135 to 250 0 C. These tests were designed to determine the important independent variables that might affect spent fuel oxidation behavior. The data from this program, when combined with the test results from other programs, will be used to develop recommended spent fuel dry-storage temperature limits in air. This report describes interim test results. The initial PNL investigations of nonirradiated and spent fuels identified the important testing variables as temperature, fuel burnup, radiolysis of the air, fuel microstructure, and moisture in the air. Based on these initial results, a more extensive statistically designed test matrix was developed to study the effects of temperature, burnup, and moisture on the oxidation behavior of spent fuel. Oxidation tests were initiated using both boiling-water reactor and pressurized-water reactor fuels from several different reactors with burnups from 8 to 34 GWd/MTU. A 10 5 R/h gamma field was applied to the test ovens to simulate dry storage cask conditions. Nonirradiated fuel was included as a control. This report describes experimental results from the initial tests on both the spent and nonirradiated fuels and results to date on the tests in a 10 5 R/h gamma field. 33 refs., 51 figs., 6 tabs

  7. Development of advanced mixed oxide fuels for plutonium management

    International Nuclear Information System (INIS)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-06-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium

  8. Development of advanced mixed oxide fuels for plutonium management

    International Nuclear Information System (INIS)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-01-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium. (author)

  9. Physicochemical analysis of interaction of oxide fuel with pyrocarbon coatings of fuel particles

    International Nuclear Information System (INIS)

    Lyutikov, R.A.; Khromov, Yu.F.; Chernikov, A.S.

    1990-01-01

    Equilibrium pressure of (CO+Kr,Xe) gases inside fuel particle with oxide kern depending on design features of fuel particle, on temperature. on (O/U) initial composition and fuel burnup is calculated using the suggested model. Analysis of possibility for gas pressure reduction by means of uranium carbide alloying of kern and degree increase of solid fission product retention (Cs for example) during alumosilicate alloying of uranium oxide is conducted

  10. Sealing materials for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, P.H.

    1999-02-01

    A major obstacle in the achievement of high electrical efficiency for planar solid oxide fuel cell stacks (SOFC) is the need for long term stable seals at the operational temperature between 850 and 1000 deg. C. In the present work the formation and properties of sealing materials for SOFC stacks that fulfil the necessary requirements were investigated. The work comprises analysis of sealing material properties independently, in simple systems as well as tests in real SOFC stacks. The analysed sealing materials were based on pure glasses or glass-ceramic composites having B{sub 2}O{sub 3}, P{sub 2}O{sub 5} or siO{sub 2} as glass formers, and the following four glass systems were investigated: MgO/caO/Cr{sub 2}O{sub 3}-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}-P{sub 2}O{sub 5}, MgO-Al{sub 2}O{sub 3}-P{sub 2}O{sub 5}, MgO-Al{sub 2}O{sub 3}-P{sub 2}O{sub 5}-SiO{sub 2} and BaO/Na{sub 2}O-Al{sub 2}O{sub 3}-SiO{sub 2}. (au) 32 tabs., 106 ills., 107 refs.

  11. Simulation study of a PEM fuel cell system fed by hydrogen produced by partial oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Ozdogan, S [Marmara University, Faculty of Engineering, Istanbul (Turkey); Ersoz, A; Olgun, H [TUBITAK Marmara Research Center, Energy Systems and Environmental Research Institute, Kocaeli (Turkey)

    2003-09-01

    Within the frame of sustainable development, efficient and clean, if possible zero emission energy production technologies are of utmost importance in various sectors such as utilities, industry, households and transportation. Low-temperature fuel cell systems are suitable for powering transportation systems such as automobiles and trucks in an efficient and low-emitting manner. Proton exchange membrane (PEM) fuel cell systems constitute the most promising low temperature fuel cell option being developed globally. PEM fuel cells generate electric power from air and hydrogen or from a hydrogen rich gas via electrochemical reactions. Water and waste heat are the only by-products of PEM fuel cells. There is great interest in converting current hydrocarbon based common transportation fuels such as gasoline and diesel into hydrogen rich gases acceptable by PEM fuel cells. Hydrogen rich gases can be produced from conventional transportation fuels via various reforming technologies. Steam reforming, partial oxidation and auto-thermal reforming are the three major reforming technologies. In this paper, we discuss the results of a simulation study for a PEM fuel cell with partial oxidation. The Aspen HYSYS 3.1 code has been used for simulation purposes. Two liquid hydrocarbon fuels have been selected to investigate the effect of average molecular weights of hydrocarbons, on the fuel processing efficiency. The overall system efficiency depends on the fuel preparation and fuel cell efficiencies as well as on the heat integration within the system. It is desired to investigate the overall system efficiencies for net electrical power production at 100 kW considering bigger scale transport applications. Results indicate that fuel properties, fuel preparation system operating parameters and PEM fuel cell polarization curve characteristics all affect the overall system efficiency. (authors)

  12. Structural analysis of nickel doped cerium oxide catalysts for fuel reforming in solid oxide fuel cells

    Science.gov (United States)

    Cavendish, Rio

    As world energy demands increase, research into more efficient energy production methods has become imperative. Heterogeneous catalysis and nanoscience are used to promote chemical transformations important for energy production. These concepts are important in solid oxide fuel cells (SOFCs) which have attracted attention because of their potential to provide an efficient and environmentally favorable power generation system. The SOFC is also fuel-flexible with the ability to run directly on many fuels other than hydrogen. Internal fuel reforming directly in the anode of the SOFC would greatly reduce the cost and complexity of the device. Methane is the simplest hydrocarbon and a main component in natural gas, making it useful when testing catalysts on the laboratory scale. Nickel (Ni) and gadolinium (Gd) doped ceria (CeO 2) catalysts for potential use in the SOFC anode were synthesized with a spray drying method and tested for catalytic performance using partial oxidation of methane and steam reforming. The relationships between catalytic performance and structure were then investigated using X-ray diffraction, transmission electron microscopy, and environmental transmission electron microscopy. The possibility of solid solutions, segregated phases, and surface layers of Ni were explored. Results for a 10 at.% Ni in CeO2 catalyst reveal a poor catalytic behavior while a 20 at.% Ni in CeO2 catalyst is shown to have superior activity. The inclusion of both 10 at.% Gd and 10 at.% Ni in CeO2 enhances the catalytic performance. Analysis of the presence of Ni in all 3 samples reveals Ni heterogeneity and little evidence for extensive solid solution doping. Ni is found in small domains throughout CeO2 particles. In the 20 at.% Ni sample a segregated, catalytically active NiO phase is observed. Overall, it is found that significant interaction between Ni and CeO2 occurs that could affect the synthesis and functionality of the SOFC anode.

  13. Desulfurization of Diesel Fuel by Oxidation and Solvent Extraction

    Directory of Open Access Journals (Sweden)

    Wadood Taher Mohammed

    2015-02-01

    Full Text Available This research presents a study in ultra-desulfurization of diesel fuel produced from conventional hydro desulfurization process, using oxidation and solvent extraction techniques. Dibenzothiophene (DBT was the organosulfur compound that had been detected in sulfur removal. The oxidation process used hydrogen peroxide as an oxidant and acetic acid as homogeneous catalyst . The solvent extraction process used acetonitrile (ACN and N-methyl – 2 - pyrrolidone (NMP as extractants . Also the effect of five parameters (stirring speed :150 , 250 , 350 , and 450 rpm, temperature (30 , 40 , 45 , and 50 oC, oxidant/simulated diesel fuel ratio (0.5 , 0.75 , 1 , and 1.5 , catalyst/oxidant ratio(0.125,0.25,0.5,and0.75 , and solvent/simulated diesel fuel ratio(0.5,0.6,0.75,and1 were examined as well as solvent type. The results exhibit that the highest removal of sulfur is 98.5% using NMP solvent while it is 95.8% for ACN solvent. The set of conditions that show the highest sulfur removal is: stirring speed of 350 rpm , temperature 50oC , oxidant/simulated diesel fuel ratio 1 , catalyst/oxidant ratio 0.5 , solvent/simulated diesel fuel ratio 1. These best conditions were applied upon real diesel fuel (produced from Al-Dora refinerywith 1000 ppm sulfur content . It was found that sulfur removal was 64.4% using ACN solvent and 75% using NMP solvent.

  14. MODELING OF FUEL SPRAY CHARACTERISTICS AND DIESEL COMBUSTION CHAMBER PARAMETERS

    Directory of Open Access Journals (Sweden)

    G. M. Kukharonak

    2011-01-01

    Full Text Available The computer model for coordination of fuel spray characteristics with diesel combustion chamber parameters has been created in the paper.  The model allows to observe fuel sprays  develоpment in diesel cylinder at any moment of injection, to calculate characteristics of fuel sprays with due account of a shape and dimensions of a combustion chamber, timely to change fuel injection characteristics and supercharging parameters, shape and dimensions of a combustion chamber. Moreover the computer model permits to determine parameters of holes in an injector nozzle that provides the required fuel sprays characteristics at the stage of designing a diesel engine. Combustion chamber parameters for 4ЧН11/12.5 diesel engine have been determined in the paper.

  15. Oxide thickness measurement for monitoring fuel performance at high burnup

    International Nuclear Information System (INIS)

    Jaeger, M.A.; Van Swam, L.F.P.; Brueck-Neufeld, K.

    1991-01-01

    For on-site monitoring of the fuel performance at high burnup, Advanced Nuclear Fuels uses the linear scan eddy current method to determine the oxide thickness of irradiated Zircaloy fuel cans. Direct digital data acquisition methods are employed to collect the data on magnetic storage media. This field-proven methodology allows oxide thickness measurements and rapid interpretation of the data during the reactor outages and makes it possible to immediately reinsert the assemblies for the next operating cycle. The accuracy of the poolside measurements and data acquisition/interpretation techniques have been verified through hot cell metallographic measurements of rods previously measured in the fuel pool. The accumulated data provide a valuable database against which oxide growth models have been benchmarked and allow for effective monitoring of fuel performance. (orig.) [de

  16. performance calculations of gadolinium oxide and boron nitride coated fuel

    International Nuclear Information System (INIS)

    Tanker, E.; Uslu, I.; Disbudak, H.; Guenduez, G.

    1997-01-01

    A comparative study was performed on the behaviour of natural uranium dioxide-gadolinium oxide mixture fuel and boron nitride coated low enriched fuel in a pressurized water reactor. A fuel element containing one burnable poison fuel pins was modeled with the computer code WIMS, and burn-up dependent critically, fissile isotope inventory and two dimensional power distribution were obtained. Calculations were performed for burnable poison fuels containing 5% and 10% gadolinium oxide and for those coated with 1μ,5μ and 10μ of boron nitride. Boron nitride coating was found superior to gadolinium oxide on account of its smoother criticality curve, lower power peaks and insignificant change in fissile isotope content

  17. Combustion and emission characteristics of diesel engine fueled with diesel-like fuel from waste lubrication oil

    International Nuclear Information System (INIS)

    Wang, Xiangli; Ni, Peiyong

    2017-01-01

    Highlights: • 100% diesel-like fuel from waste lubricating oil was conducted in a diesel engine. • Good combustion and fuel economy are achieved without engine modifications. • Combustion duration of DLF is shorter than diesel. • NOx and smoke emissions with the DLF are slightly higher than pure diesel. - Abstract: Waste lubricant oil (WLO) is one of the most important types of the energy sources. WLO cannot be burned directly in diesel engines, but can be processed to be used as diesel-like fuel (DLF) to minimize its harmful effect and maximize its useful values. Moreover, there are some differences in physicochemical properties between WLO and diesel fuel. In order to identify the differences in combustion and emission performance of diesel engine fueled with the two fuels, a bench test of a single-cylinder direct injection diesel engine without any engine modification was investigated at four engine speeds and five engine loads. The effects of the fuels on fuel economic performance, combustion characteristics, and emissions of hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx) and smoke were discussed. The DLF exhibits longer ignition delay period and shorter combustion duration than diesel fuel. The test results indicate that the higher distillation temperatures of the DLF attribute to the increase of combustion pressure, temperature and heat release rate. The brake specific fuel consumption (BSFC) of the DLF compared to diesel is reduced by about 3% at 3000 rpm under light and medium loads. The DLF produces slightly higher NOx emissions at middle and heavy loads, somewhat more smoke emissions at middle loads, and notably higher HC and CO emissions at most measured points than diesel fuel. It is concluded that the DLF can be used as potential available fuel in high-speed diesel engines without any problems.

  18. Redox Stable Anodes for Solid Oxide Fuel Cells

    Directory of Open Access Journals (Sweden)

    Guoliang eXiao

    2014-06-01

    Full Text Available Solid oxide fuel cells (SOFCs can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as the fuel. This review aims to highlight recent progresses on improving redox stability of the conventional Ni-based anode through microstructure optimization and exploration of alternative ceramic-based anode materials.

  19. Review of oxidation rates of DOE spent nuclear fuel : Part 1 : nuclear fuel

    International Nuclear Information System (INIS)

    Hilton, B.A.

    2000-01-01

    The long-term performance of Department of Energy (DOE) spent nuclear fuel (SNF) in a mined geologic disposal system depends highly on fuel oxidation and subsequent radionuclide release. The oxidation rates of nuclear fuels are reviewed in this two-volume report to provide a baseline for comparison with release rate data and technical rationale for predicting general corrosion behavior of DOE SNF. The oxidation rates of nuclear fuels in the DOE SNF inventory were organized according to metallic, Part 1, and non-metallic, Part 2, spent nuclear fuels. This Part 1 of the report reviews the oxidation behavior of three fuel types prototypic of metallic fuel in the DOE SNF inventory: uranium metal, uranium alloys and aluminum-based dispersion fuels. The oxidation rates of these fuels were evaluated in oxygen, water vapor, and water. The water data were limited to pure water corrosion as this represents baseline corrosion kinetics. Since the oxidation processes and kinetics discussed in this report are limited to pure water, they are not directly applicable to corrosion rates of SNF in water chemistry that is significantly different (such as may occur in the repository). Linear kinetics adequately described the oxidation rates of metallic fuels in long-term corrosion. Temperature dependent oxidation rates were determined by linear regression analysis of the literature data. As expected the reaction rates of metallic fuels dramatically increase with temperature. The uranium metal and metal alloys have stronger temperature dependence than the aluminum dispersion fuels. The uranium metal/water reaction exhibited the highest oxidation rate of the metallic fuel types and environments that were reviewed. Consequently, the corrosion properties of all DOE SNF may be conservatively modeled as uranium metal, which is representative of spent N-Reactor fuel. The reaction rate in anoxic, saturated water vapor was essentially the same as the water reaction rate. The long-term intrinsic

  20. Influence of fuel properties on fundamental spray characteristics and soot emissions using different tailor-made fuels from biomass

    International Nuclear Information System (INIS)

    García, Antonio; Monsalve-Serrano, Javier; Heuser, Benedikt; Jakob, Markus; Kremer, Florian; Pischinger, Stefan

    2016-01-01

    Highlights: • TMFB show clear potential to reduce soot emissions under mixing-controlled combustion. • The larger lift-off-length of 2-MTHF and 1-octanol promotes soot emissions reduction. • Oxidation process governs the improved soot emissions of DNBE. - Abstract: This work evaluates the potential of some new biomass-derived fuels as candidates for compression ignition operation. Thus, fundamental spray characteristics related to fuel vaporization and fuel/air mixing process for 2-Methyltetrahydrofuran, Di-n-butyl ether and 1-octanol has been studied and compared with conventional EN590 Diesel fuel. For this purpose, OH"∗ chemiluminescence and shadowgraphy measurements in a high pressure chamber as well as 1D simulations with a spray model have been carried out at different operating conditions representative of the NEDC driving cycle. Finally, measured soot emissions in the single-cylinder engine were presented and discussed. Results from the high pressure chamber presented very good agreement in terms of liquid length and vapor penetration with simulation results. Thus, some analytical expressions related to macroscopic spray characteristics have been proposed and validated experimentally for all four fuels. Finally, the single-cylinder engine results confirmed the relevant role of soot formation on final emissions for 1-octanol and 2-MTHF. In addition, DNBE showed greater soot oxidation potential than diesel and other TMFB candidates.

  1. Nozzle flow and atomization characteristics of ethanol blended biodiesel fuel

    Energy Technology Data Exchange (ETDEWEB)

    Park, Su Han; Suh, Hyun Kyu; Lee, Chang Sik [Department of Mechanical Engineering, Graduate School of Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul, 133-791 (Korea)

    2010-01-15

    This study was conducted to investigate the injection and atomization characteristics of biodiesel-ethanol blended fuel. The injection performance of biodiesel-ethanol blended fuel was analyzed from the injection rate characteristics using the injection rate measuring system, and the effective injection velocity and effective spray diameter using the nozzle flow model. Moreover, the atomization characteristics, such as local and overall SMD distributions, overall axial velocity and droplet arrival time were analyzed and compared with these from diesel and biodiesel fuels to obtain the atomization characteristics of biodiesel-ethanol blended fuel. It was revealed that ethanol fuel affects the decrease of the peak injection rate and the shortening of the injection delay due to the decrease of fuel properties, such as fuel density and dynamic viscosity. In addition, the ethanol addition improved the atomization performance of biodiesel fuel, because the ethanol blended fuel has a low kinematic viscosity and surface tension, then that has more active interaction with the ambient gas, compared to BD100. (author)

  2. Fission product release by fuel oxidation after water ingress

    International Nuclear Information System (INIS)

    Schreiber.

    1990-01-01

    On the basis of data obtained by a literature search, a computer code has been established for the calculation of the degree of oxidation of the fuel in the damaged fuel particles, and hence of the fission product release as a function of the time period of steam ingress. (orig.) [de

  3. Spent fuel characteristics provided by the CDB: An update

    International Nuclear Information System (INIS)

    Notz, K.J.; Salmon, R.; Welch, T.D.; Reich, W.J.; Moore, R.S.

    1992-01-01

    The Characteristics Data Base (CDB) task provides OCRWM with the detailed technical characteristics of potential repository wastes, which consist primarily of commercial spent nuclear fuel, but also includes other spent fuel (and also high-level and miscellaneous wastes). A major revision of the original CDB report and PC data bases has just been completed under formal QA peer review guidelines and Revision 1 is ready to be issued. This paper describes the classification scheme developed for LWR fuel assemblies and the five PC data bases for LWR spent fuel, which provide data on quantities, assemblies, radiological properties, non-fuel assembly hardware, and serial numbers. The future role of other (i.e., non-LWR) spent fuel is also cited

  4. Assessment of the Dry Processed Oxide Fuel in Liquid Metal Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Roh, Gyu Hong; Choi, Hang Bok

    2005-09-15

    The neutronic feasibility of the dry process oxide fuel was assessed for the sodium-cooled and lead-cooled fast reactors (SFR and LFR, respectively), which were recommended as Generation-IV (Gen-IV) reactor systems by the Gen-IV international forum. The reactor analysis was performed for the equilibrium fuel cycle of two core configurations: Hybrid BN-600 benchmark core with an enlarged lattice pitch and a modified BN-600 core. The dry process technology assumed in this study is the molten-salt process, which was developed by Russian scientists for recycling oxide fuels. The core calculation was performed by the REBUS-3 code and the reactor characteristics such as the transuranic (TRU) enrichment, breeding ratio, peak linear power, burnup reactivity swing, etc. were calculated for the equilibrium core under a fixed fuel management scheme. The results showed that a fissile self-sustainable breakeven core was achievable without blanket fuels when the fuel volume fraction was {approx}50% and most of the fission products were removed. If the design criteria used in this study is proved to be acceptable through a detailed physics design and thermal hydraulic analysis in the future, it is practically possible to construct an equilibrium fuel cycle of the SFR and LFR systems based on the oxide fuel by utilizing the dry process technology.

  5. Assessment of the Dry Processed Oxide Fuel in Liquid Metal Fast Reactors

    International Nuclear Information System (INIS)

    Roh, Gyu Hong; Choi, Hang Bok

    2005-09-01

    The neutronic feasibility of the dry process oxide fuel was assessed for the sodium-cooled and lead-cooled fast reactors (SFR and LFR, respectively), which were recommended as Generation-IV (Gen-IV) reactor systems by the Gen-IV international forum. The reactor analysis was performed for the equilibrium fuel cycle of two core configurations: Hybrid BN-600 benchmark core with an enlarged lattice pitch and a modified BN-600 core. The dry process technology assumed in this study is the molten-salt process, which was developed by Russian scientists for recycling oxide fuels. The core calculation was performed by the REBUS-3 code and the reactor characteristics such as the transuranic (TRU) enrichment, breeding ratio, peak linear power, burnup reactivity swing, etc. were calculated for the equilibrium core under a fixed fuel management scheme. The results showed that a fissile self-sustainable breakeven core was achievable without blanket fuels when the fuel volume fraction was ∼50% and most of the fission products were removed. If the design criteria used in this study is proved to be acceptable through a detailed physics design and thermal hydraulic analysis in the future, it is practically possible to construct an equilibrium fuel cycle of the SFR and LFR systems based on the oxide fuel by utilizing the dry process technology

  6. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    International Nuclear Information System (INIS)

    Roake, W.E.; Adamson, M.G.; Hilbert, R.F.; Langer, S.

    1977-01-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to ∼60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  7. Investigations of fuel cladding chemical interaction in irradiated LMFBR type oxide fuel pins

    Energy Technology Data Exchange (ETDEWEB)

    Roake, W E [Westinghouse-Hanford Co., Richland, WA (United States); Adamson, M G [General Electric Company, Vallecitos Nuclear Center, Pleasanton, CA (United States); Hilbert, R F; Langer, S

    1977-04-01

    Understanding and controlling the chemical attack of fuel pin cladding by fuel and fission products are major objectives of the U.S. LMFBR Mixed Oxide Irradiation Testing Program. Fuel-cladding chemical interaction (FCCI) has been recognized as an important factor in the ability to achieve goal peak burnups of 8% (80.MWd/kg) in FFTF and in excess of 10% (100.MWd/kg) in the LMFBR demonstration reactors while maintaining coolant bulk outlet temperatures up to {approx}60 deg. C (1100 deg. F). In this paper we review pertinent parts of the irradiation program and describe recent observation of FCCI in the fuel pins of this program. One goal of the FCCI investigations is to obtain a sufficiently quantitative understanding of FCCI such that correlations can be developed relating loss of effective cladding thickness to irradiation and fuel pin fabrication parameters. Wastage correlations being developed using different approaches are discussed. Much of the early data on FCCI obtained in the U.S. Mixed Oxide Fuel Program came from capsule tests irradiated in both fast and thermal flux facilities. The fast flux irradiated encapsulated fuel pins continue to provide valuable data and insight into FCCI. Currently, however, bare pins with prototypic fuels and cladding irradiated in the fast flux Experimental Breeder Reactor-II (EBR-II) as multiple pin assemblies under prototypic powers, temperatures and thermal gradients are providing growing quantities of data on FCCI characteristics and cladding thickness losses from FCCI. A few special encapsulated fuel pin tests are being conducted in the General Electric Test Reactor (GETR) and EBR-II, but these are aimed at providing specific information under irradiation conditions not achievable in the fast flux bare pin assemblies or because EBR-II Operation or Safety requirements dictate that the pins be encapsulated. The discussion in this paper is limited to fast flux irradiation test results from encapsulated pins and multiple pin

  8. Characteristics of radioactive waste streams generated in HTGR fuel reprocessing

    International Nuclear Information System (INIS)

    Lin, K.H.

    1976-01-01

    Results are presented of a study concerned with identification and characterization of radioactive waste streams from an HTGR fuel reprocessing plant. Approximate quantities of individual waste streams as well as pertinent characteristics of selected streams have been estimated. Most of the waste streams are unique to HTGR fuel reprocessing. However, waste streams from the solvent extraction system and from the plant facilities do not differ greatly from the corresponding LWR fuel reprocessing wastes

  9. Introduction of mixed oxide fuel elements in the belgian cores

    International Nuclear Information System (INIS)

    Charlier, A.F.; Hollasky, N.A.

    1994-01-01

    The important amount of plutonium recovered from the reprocessing of spent fuel on the one hand, the national and international experience of the use of mixed oxide UO 2 -PuO 2 fuel in power reactors on the other hand, have led Belgian utilities to decide the introduction of Mixed-Oxide fuel in Doel unit 3 and Tihange unit 2 cores. The 'MOX' project has shown that it was possible without reducing safety or requiring modifications of the plant equipment. It has been approved by the Belgian 'Nuclear Safety Commission'. (authors). 1 tab., 2 figs

  10. Conversion of hydrocarbons in solid oxide fuel cells

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Kammer Hansen, K.

    2003-01-01

    Recently, a number of papers about direct oxidation of methane and hydrocarbon in solid oxide fuel cells (SOFC) at relatively low temperatures (about 700degreesC) have been published. Even though the conversion of almost dry CH4 at 1000degreesC on ceramic anodes was demonstrated more than 10 years...

  11. Design and main characteristics of HTGR fuel elements

    International Nuclear Information System (INIS)

    Chernikov, A.S.; Kolesov, V.S.; Permyakov, L.N.; Koshelev, Yu.V.; Mikhajlichenko, L.I.

    1983-01-01

    Two types of spherical fuel elements and coated particles were investigated under the operating conditions of the high temperature reactors in the Soviet Union (VGR-50 and VG-400). This paper gives the main characteristics of spherical fuel elements (thermal conductivity, static and dynamic strength, wear resistance, release of gaseous fission products, etc.) as determined in test facilities. (author)

  12. Irradiation behavior of uranium oxide - Aluminum dispersion fuel

    International Nuclear Information System (INIS)

    Hofman, Gerard L.; Rest, Jeffrey; Snelgrove, James L.

    1996-01-01

    An oxide version of the DART code has been generated in order to assess the irradiation behavior of UO 2 -Al dispersion fuel. The aluminum-fuel interaction models were developed based on U 3 O 8 -Al irradiation data. Deformation of the fuel element occurs due to fuel particle swelling driven by both solid and gaseous fission products and as a consequence of the interaction between the fuel particles and the aluminum matrix. The calculations show that, with the assumption that the correlations derived from U 3 O 8 are valid for UO 2 , the LEU UO 2 -Al with a 42% fuel volume loading (4 g U/cm 3 ) irradiated at fuel temperatures greater than 413 K should undergo breakaway swelling at core burnups greater than about 1.12 x 10 27 fissions m -3 (∼63% 235 U burnup). (author)

  13. Irradiation behavior of uranium oxide-aluminum dispersion fuel

    International Nuclear Information System (INIS)

    Hofman, G.L.; Rest, J.; Snelgrove, J.L.

    1996-01-01

    An oxide version of the DART code has been generated in order to assess the irradiation behavior of UO 2 -Al dispersion fuel. The aluminum-fuel interaction models were developed based on U 3 O 8 -Al irradiation data. Deformation of the fuel element occurs due to fuel particle swelling driven by both solid and gaseous fission products, as well as a consequence of the interaction between the fuel particles and the aluminum matrix. The calculations show, that with the assumption that the correlations derived from U 3 O 8 are valid for UO 2 , the LEU UO 2 -Al with a 42% fuel volume loading (4 gm/cc) irradiated at fuel temperatures greater than 413 K should undergo breakaway swelling at core burnups greater than about 1.12 x 10 27 fissions m -3 (∼ 63% 235 U burnup)

  14. Transmutation of minor actinide using BWR fueled mixed oxide

    International Nuclear Information System (INIS)

    Susilo, Jati

    2000-01-01

    Nuclear spent fuel recycle has a strategic importance in the aspect of nuclear fuel economy and prevention of its spread-out. One among other application of recycle is to produce mixed oxide fuel (Mo) namely mixed Plutonium and uranium oxide. As for decreasing the burden of nuclear high level waste (HLW) treatment, transmutation of minor actinide (MA) that has very long half life will be carried out by conversion technique in nuclear reactor. The purpose of this study was to know influence of transition fuel cell regarding the percent weight of transmutation MA in the BWR fueled MOX. Calculation of cell BWR was used SRAC computer code, with assume that the reactor in equilibrium. The percent weight of transmutation MA to be optimum by increasing the discharge burn-up of nuclear fuel, raising ratio of moderator to fuel volume (Vm/Vf), and loading MA with percent weight about 3%-6% and also reducing amount of percent weight Pu in MOX fuel. For mixed fuel standard reactor, reactivity value were obtained between about -50pcm ∼ -230pcm for void coefficient and -1.8pcm ∼ -2.6pcm for fuel temperature coefficient

  15. Assessment of bio-fuel options for solid oxide fuel cell applications

    Science.gov (United States)

    Lin, Jiefeng

    Rising concerns of inadequate petroleum supply, volatile crude oil price, and adverse environmental impacts from using fossil fuels have spurred the United States to promote bio-fuel domestic production and develop advanced energy systems such as fuel cells. The present dissertation analyzed the bio-fuel applications in a solid oxide fuel cell-based auxiliary power unit from environmental, economic, and technological perspectives. Life cycle assessment integrated with thermodynamics was applied to evaluate the environmental impacts (e.g., greenhouse gas emission, fossil energy consumption) of producing bio-fuels from waste biomass. Landfill gas from municipal solid wastes and biodiesel from waste cooking oil are both suggested as the promising bio-fuel options. A nonlinear optimization model was developed with a multi-objective optimization technique to analyze the economic aspect of biodiesel-ethanol-diesel ternary blends used in transportation sectors and capture the dynamic variables affecting bio-fuel productions and applications (e.g., market disturbances, bio-fuel tax credit, policy changes, fuel specification, and technological innovation). A single-tube catalytic reformer with rhodium/ceria-zirconia catalyst was used for autothermal reformation of various heavy hydrocarbon fuels (e.g., diesel, biodiesel, biodiesel-diesel, and biodiesel-ethanol-diesel) to produce a hydrogen-rich stream reformates suitable for use in solid oxide fuel cell systems. A customized mixing chamber was designed and integrated with the reformer to overcome the technical challenges of heavy hydrocarbon reformation. A thermodynamic analysis, based on total Gibbs free energy minimization, was implemented to optimize the operating environment for the reformations of various fuels. This was complimented by experimental investigations of fuel autothermal reformation. 25% biodiesel blended with 10% ethanol and 65% diesel was determined to be viable fuel for use on a truck travelling with

  16. Oxidative dissolution of ADOPT compared to standard UO2 fuel

    International Nuclear Information System (INIS)

    Nilsson, Kristina; Roth, Olivia; Jonsson, Mats

    2017-01-01

    In this work we have studied oxidative dissolution of pure UO 2 and ADOPT (UO 2 doped with Al and Cr) pellets using H 2 O 2 and gammaradiolysis to induce the process. There is a small but significant difference in the oxidative dissolution rate of UO 2 and ADOPT pellets, respectively. However, the difference in oxidative dissolution yield is insignificant. Leaching experiments were also performed on in-reactor irradiated ADOPT and UO 2 pellets under oxidizing conditions. The results indicate that the U(VI) release is slightly slower from the ADOPT pellet compared to the UO 2. This could be attributed to differences in exposed surface area. However, fission products with low UO 2 solubility display a higher relative release from ADOPT fuel compared to standard UO 2 -fuel. This is attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel. The release of Cs is higher from UO 2 which is attributed to the larger grain size of ADOPT. - Highlights: •Oxidative dissolution of ADOPT fuel is compared to standard UO 2 fuel. •Only marginal differences are observed. •The main difference observed is in the relative release rate of fission products. •Differences are claimed to be attributed to a lower matrix solubility imposed by the dopants in ADOPT fuel.

  17. Desulfurization of Diesel Fuel by Oxidation and Solvent Extraction

    OpenAIRE

    Wadood Taher Mohammed; Raghad Fareed Kassim Almilly; Sheam Bahjat Abdulkareem Al-Ali

    2015-01-01

    This research presents a study in ultra-desulfurization of diesel fuel produced from conventional hydro desulfurization process, using oxidation and solvent extraction techniques. Dibenzothiophene (DBT) was the organosulfur compound that had been detected in sulfur removal. The oxidation process used hydrogen peroxide as an oxidant and acetic acid as homogeneous catalyst . The solvent extraction process used acetonitrile (ACN) and N-methyl – 2 - pyrrolidone (NMP) as extractants . Also the ef...

  18. Analysis of fuel cladding chemical interaction in mixed oxide fuel pins

    International Nuclear Information System (INIS)

    Weber, J.W.; Dutt, D.S.

    1976-01-01

    An analysis is presented of the observed interaction between mixed oxide 75 wt percent UO 2 --25 wt percent PuO 2 fuel and 316--20 percent CW stainless steel cladding in LMFBR type fuel pins irradiated in EBR-II. A description is given of the test pins and their operating conditions together with, metallographic observations and measurements of the fuel/cladding reaction, and a correlation equation is developed relating depth of cladding attack to temperature and burnup. Some recent data on cladding reaction in fuel pins with low initial O/M in the fuel are given and compared with the correlation equation curves

  19. Universal electrode interface for electrocatalytic oxidation of liquid fuels.

    Science.gov (United States)

    Liao, Hualing; Qiu, Zhipeng; Wan, Qijin; Wang, Zhijie; Liu, Yi; Yang, Nianjun

    2014-10-22

    Electrocatalytic oxidations of liquid fuels from alcohols, carboxylic acids, and aldehydes were realized on a universal electrode interface. Such an interface was fabricated using carbon nanotubes (CNTs) as the catalyst support and palladium nanoparticles (Pd NPs) as the electrocatalysts. The Pd NPs/CNTs nanocomposite was synthesized using the ethylene glycol reduction method. It was characterized using transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, voltammetry, and impedance. On the Pd NPs/CNTs nanocomposite coated electrode, the oxidations of those liquid fuels occur similarly in two steps: the oxidations of freshly chemisorbed species in the forward (positive-potential) scan and then, in the reverse scan (negative-potential), the oxidations of the incompletely oxidized carbonaceous species formed during the forward scan. The oxidation charges were adopted to study their oxidation mechanisms and oxidation efficiencies. The oxidation efficiency follows the order of aldehyde (formaldehyde) > carboxylic acid (formic acid) > alcohols (ethanol > methanol > glycol > propanol). Such a Pd NPs/CNTs nanocomposite coated electrode is thus promising to be applied as the anode for the facilitation of direct fuel cells.

  20. Behavior of molybdenum in mixed-oxide fuel

    International Nuclear Information System (INIS)

    Giacchetti, G.; Sari, C.

    1976-01-01

    Metallic molybdenum, Mo--Ru--Rh--Pd alloys, barium, zirconium, and tungsten were added to uranium and uranium--plutonium oxides by coprecipitation and mechanical mixture techniques. This material was treated in a thermal gradient similar to that existing in fuel during irradiation to study the behavior of molybdenum in an oxide matrix as a function of the O/(U + Pu) ratio and some added elements. Result of ceramographic and microprobe analysis shows that when the overall O/(U + Pu) ratio is less than 2, molybdenum and Mo--Ru--Rh--Pd alloy inclusions are present in the uranium--plutonium oxide matrix. If the O/(U + Pu) ratio is greater than 2, molybdenum oxidizes to MoO 2 , which is gaseous at a temperature approximately 1000 0 C. Molybdenum oxide vapor reacts with barium oxide and forms a compound that exists as a liquid phase in the columnar grain region. Molybdenum oxide also reacts with tungsten oxide (tungsten is often present as an impurity in the fuel) and forms a compound that contains approximately 40 wt percent of actinide metals. The apparent solubility of molybdenum in uranium and uranium--plutonium oxides, determined by electron microprobe, was found to be less than 250 ppM both for hypo- and hyperstoichiometric fuels

  1. Emission of nitrous oxide during combustion of organic fuels

    Energy Technology Data Exchange (ETDEWEB)

    Kotler, V.R.; Gol' dberg, A.S.

    1990-11-01

    Analyzes formation of nitrogen oxides during combustion of coal, natural gas and mazout: chemical reactions that lead to formation of nitrous oxide during coal combustion, reaction kinetics and reaction yields, factors that influence emission of nitrogen oxides from a furnace, factors that influence formation of nitrous oxide (temperature effects, air excess ratio, coal burnout degree, etc.), effects of fuel type and its chemical composition, effects of flue gas desulfurization and denitrification methods on nitrous oxide yield. Analyses show that yield of nitrous oxide is low and does not exceed 5 cm{sup 3}/m{sup 3} flue gas (0.0005%). However chemical reactions of nitrogen oxides, sulfur dioxide and water vapor in the atmosphere are said to form additional quantities of nitrous oxide which negatively influence the ozone layer. 4 refs.

  2. Characteristics of several equilibrium fuel cycles of PWR

    International Nuclear Information System (INIS)

    Waris, Abdul; Sekimoto, Hiroshi

    2001-01-01

    This paper evaluated the influence of neutron spectrum on characteristics of several equilibrium fuel cycles of pressurized water reactor (PWR). In this study, five kinds of fuel cycles were investigated. Required uranium enrichment, required natural uranium amount, and toxicity of heavy metals (HMs) in spent fuel were presented for comparison. The results showed that the enrichment and the required amount of natural uranium decrease significantly with increasing number of confined heavy nuclides when uranium is discharged from the reactor. On the other hand, when uranium is totally confined, the enrichment becomes extremely high. The confinement of plutonium and minor actinides (MA) seems effective in reducing radio-toxicity of discharged wastes. By confining all heavy nuclides except uranium those three characteristics could be reduced considerably. For this fuel cycle the toxicity of HMs in spent fuel become nearly equal to or less than that of loaded uranium. (author)

  3. Oxidation behavior of fuel cladding tube in spent fuel pool accident condition

    International Nuclear Information System (INIS)

    Nemoto, Yoshiyuki; Kaji, Yoshiyuki; Ogawa, Chihiro; Nakashima, Kazuo; Tojo, Masayuki

    2017-01-01

    In spent fuel pool (SFP) under loss-of-cooling or loss-of-coolant severe accident condition, the spent fuels will be exposed to air and heated by their own residual decay heat. Integrity of fuel cladding is crucial for SFP safety therefore study on cladding oxidation in air at high temperature is important. Zircaloy-2 (Zry2) and zircaloy-4 (Zry4) were applied for thermogravimetric analyses (TGA) in different temperatures in air at different flow rates to evaluate oxidation behavior. Oxidation rate increased with testing temperature. In a range of flow rate of air which is predictable in spent fuel lack during a hypothetical SFP accident, influence of flow rate was not clearly observed below 950degC for the Zry2, or below 1050degC for Zry4. In higher temperature, oxidation rate was higher in high rate condition, and this trend was seen clearer when temperature increased. Oxide layers were carefully examined after the TGA analyses and compared with mass gain data to investigate detail of oxidation process in air. It was revealed that the mass gain data in pre-breakaway regime reflects growth of dense oxide film on specimen surface, meanwhile in post-breakaway regime, it reflects growth of porous oxide layer beneath fracture of the dense oxide film. (author)

  4. Advances in direct oxidation methanol fuel cells

    Science.gov (United States)

    Surampudi, S.; Narayanan, S. R.; Vamos, E.; Frank, H.; Halpert, G.; Laconti, Anthony B.; Kosek, J.; Prakash, G. K. Surya; Olah, G. A.

    1993-01-01

    Fuel cells that can operate directly on fuels such as methanol are attractive for low to medium power applications in view of their low weight and volume relative to other power sources. A liquid feed direct methanol fuel cell has been developed based on a proton exchange membrane electrolyte and Pt/Ru and Pt catalyzed fuel and air/O2 electrodes, respectively. The cell has been shown to deliver significant power outputs at temperatures of 60 to 90 C. The cell voltage is near 0.5 V at 300 mA/cm(exp 2) current density and an operating temperature of 90 C. A deterrent to performance appears to be methanol crossover through the membrane to the oxygen electrode. Further improvements in performance appear possible by minimizing the methanol crossover rate.

  5. Breaking up of pure and simulated 'burnt' mixed oxide fuel by chemical interaction with oxidized sodium

    International Nuclear Information System (INIS)

    Besnard, R.; Chaudat, J.P.

    1983-01-01

    A large experimental program have permitted to investigate the behaviour of mixed oxide fuel coming in contact with hot oxidized sodium. The kinetic of the reaction, the size and the chemical nature of the particules after interaction have been studied. The main part of experiments have been performed using mixed oxide fuel non irradiated at first and with simulated fission products afterwards. Complementary informations have been obtained with UO 2 fuel pellets. After description of the experimental devices, the results are discussed and the importance of the main parameters, like temperature and fission products effect, are pointed out. (orig.)

  6. Characteristics of fast reactor core designs and closed fuel cycle

    International Nuclear Information System (INIS)

    Poplavsky, V.M.; Eliseev, V.A.; Matveev, V.I.; Khomyakov, Y.S.; Tsyboulya, A.M.; Tsykunov, A.G.; Chebeskov, A.N.

    2007-01-01

    On the basis of the results of recent studies, preliminary basic requirements related to characteristics of fast reactor core and nuclear fuel cycle were elaborated. Decreasing reactivity margin due to approaching breeding ratio to 1, requirements to support non-proliferation of nuclear weapons, and requirements to decrease amount of radioactive waste are under consideration. Several designs of the BN-800 reactor core have been studied. In the case of MOX fuel it is possible to reach a breeding ratio about 1 due to the use of larger size of fuel elements with higher fuel density. Keeping low axial fertile blanket that would be reprocessed altogether with the core, it is possible to set up closed fuel cycle with the use of own produced plutonium only. Conceptual core designs of advanced commercial reactor BN-1800 with MOX and nitride fuel are also under consideration. It has been shown that it is expedient to use single enrichment fuel core design in this reactor in order to reach sufficient flattening and stability of power rating in the core. The main feature of fast reactor fuel cycle is a possibility to utilize plutonium and minor actinides which are the main contributors to the long-living radiotoxicity in irradiated nuclear fuel. The results of comparative analytical studies on the risk of plutonium proliferation in case of open and closed fuel cycle of nuclear power are also presented in the paper. (authors)

  7. Alternative anode materials for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Goodenough, John B.; Huang, Yun-Hui [Texas Materials Institute, ETC 9.102, 1 University Station, C2200, The University of Texas at Austin, Austin, TX 78712 (United States)

    2007-11-08

    The electrolyte of a solid oxide fuel cell (SOFC) is an O{sup 2-}-ion conductor. The anode must oxidize the fuel with O{sup 2-} ions received from the electrolyte and it must deliver electrons of the fuel chemisorption reaction to a current collector. Cells operating on H{sub 2} and CO generally use a porous Ni/electrolyte cermet that supports a thin, dense electrolyte. Ni acts as both the electronic conductor and the catalyst for splitting the H{sub 2} bond; the oxidation of H{sub 2} to H{sub 2}O occurs at the Ni/electrolyte/H{sub 2} triple-phase boundary (TPB). The CO is oxidized at the oxide component of the cermet, which may be the electrolyte, yttria-stabilized zirconia, or a mixed oxide-ion/electron conductor (MIEC). The MIEC is commonly a Gd-doped ceria. The design and fabrication of these anodes are evaluated. Use of natural gas as the fuel requires another strategy, and MIECs are being explored for this application. The several constraints on these MIECs are outlined, and preliminary results of this on-going investigation are reviewed. (author)

  8. Fuel-cladding chemical interaction in mixed-oxide fuels

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Weber, J.W.; Devary, J.L.

    1978-10-01

    The character and extent of fuel-cladding chemical interaction (FCCI) was established for UO 2 -25 wt% PuO 2 clad with 20% cold worked Type 316 stainless steel irradiated at high cladding temperatures to peak burnups greater than 8 atom %. The data base consists of 153 data sets from fuel pins irradiated in EBR-II with peak burnups to 9.5 atom %, local cladding inner surface temperatures to 725 0 C, and exposure times to 415 equivalent full power days. As-fabricated oxygen-to-metal ratios (O/M) ranged from 1.938 to 1.984 with the bulk of the data in the range 1.96 to 1.98. HEDL P-15 pins provided data at low heat rates, approx. 200 W/cm, and P-23 series pins provided data at higher heat rates, approx. 400 W/cm. A design practice for breeder reactors is to consider an initial reduction of 50 microns in cladding thickness to compensate for possible FCCI. This approach was considered to be a conservative approximation in the absence of a comprehensive design correlation for extent of interaction. This work provides to the designer a statistically based correlation for depth of FCCI which reflects the influences of the major fuel and operating parameters on FCCI

  9. High temperature transient deformation of mixed oxide fuels

    International Nuclear Information System (INIS)

    Slagle, O.D.

    1986-01-01

    The purpose of this paper is to present recent experimental results on fuel creep under transient conditions at high temperatures. The effect of temperature, stress, heating rate, density and grain size were considered. An empirical formulation is derived for the relationship between strain, stress, temperature and heating rate. This relationship provides a means for incorporating stress relief into the analysis of fuel-cladding interaction during an overpower transient. The effect of sample density and initial grain size is considered by varying the sample parameters. Previously derived steady-state creep relationships for the high temperature creep of mixed oxide fuel were combined with the time dependency of creep found for UO 2 to calculate a transient creep relationship for mixed oxide fuel. These calculated results were found to be in good agreement with the measured high temperature transient creep results

  10. Reirradiation of mixed-oxide fuel pins at increased temperatures

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Weber, E.T.

    1976-05-01

    Mixed-oxide fuel pins from EBR-II irradiations were reirradiated in the General Electric Test Reactor (GETR) at higher temperatures than experienced in EBR-II to study effects of the increased operating temperatures on thermal/mechanical and chemical behavior. The response of a mixed-oxide fuel pin to a power increase after having operated at a lower power for a significant portion of its life-time is an area of performance evaluation where little information currently exists. Results show that the cladding diameter changes resulting from the reirradiation are strongly dependent upon both prior burnup level and the magnitude of the temperature increase. Results provide the initial rough outlines of boundaries within which mixed-oxide fuel pins can or cannot tolerate power increases after substantial prior burnup at lower powers

  11. A novel direct carbon fuel cell by approach of tubular solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Renzhu; Zhao, Chunhua; Li, Junliang; Zeng, Fanrong; Wang, Shaorong; Wen, Tinglian; Wen, Zhaoyin [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Inorganic Energy Materials and Power Source Engineering Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China)

    2010-01-15

    A direct carbon fuel cell based on a conventional anode-supported tubular solid oxide fuel cell, which consisted of a NiO-YSZ anode support tube, a NiO-ScSZ anode functional layer, a ScSZ electrolyte film, and a LSM-ScSZ cathode, has been successfully achieved. It used the carbon black as fuel and oxygen as the oxidant, and a preliminary examination of the DCFC has been carried out. The cell generated an acceptable performance with the maximum power densities of 104, 75, and 47 mW cm{sup -2} at 850, 800, and 750 C, respectively. These results demonstrate the feasibility for carbon directly converting to electricity in tubular solid oxide fuel cells. (author)

  12. Model alloy oxidation in oxyfuel characteristic environment

    International Nuclear Information System (INIS)

    Coelho, D.; Rizzo, F.; Kranzmann, A.; Monteiro, M.; Caminha, I.

    2014-01-01

    In the oxyfuel process, pure oxygen is burned in boilers with recycled gas producing a gas rich in CO_2, making it easer to capture the CO_2 in the end of the process. The present work investigates the high temperature corrosion characteristics of a model Fe-Cr-Co alloy in typical oxyfuel process environment. Samples were oxidized at 600°C during 1000 hours in single atmosphere condition, where the samples is exposed to the same gas in all faces, and in a dual atmosphere condition, where the sample is exposed to water vapor in one side and to oxyfuel gas in the other. Samples where characterized by SEM and EDX. Results showed that corrosion is higher in a dual atmosphere condition than in single condition. (author)

  13. Model-supported interpretation of the electrochemical characteristics of solid oxide fuel cells with Ni/YSZ cermet anodes; Modellgestuetzte Interpretation der elektrochemischen Charakteristik von Festoxid-Brennstoffzellen mit Ni/YSZ-Cermetanoden

    Energy Technology Data Exchange (ETDEWEB)

    Gewies, Stefan

    2009-01-29

    This work presents the development, validation and application of a multiscale model for the detailed description of a solid oxide fuel cell (SOFC) with a Ni/YSZ (nickel/yttria-stabilized zirconia) cermet anode. The aim of the study is the identification of the physico-chemical loss processes, as seen in impedance spectra and polarization curves. The model consists of an elementary kinetic description of the electrochemistry including the development of an electrical double layer at the electrode/electrolyte interface of the cermet anode, a homogenized description of charge and gas-phase transport in the electrodes as well as a macroscopic description of convective and diffusive mass transport in the gas phase above the electrodes. For the rst time this study allows for a complete description of the impedance spectra of a diffusively fuel-supplied cermet anode. By comparing simulations with experiments on symmetrical cells (University of Karlsruhe) three dominant loss processes could be identified. The model was extended to account for the description of segmented SOFCs. In correspondence with experimental data (German Aerospace Center) the simulations show strong gradients in current densities and gas concentrations. (orig.)

  14. Improving the performance of solid oxide fuel cell systems

    OpenAIRE

    Halinen, Matias

    2015-01-01

    Solid oxide fuel cell (SOFC) systems can provide power production at a high electrical efficiency and with very low emissions. Furthermore, they retain their high electrical efficiency over a wide range of output power and offer good fuel flexibility, which makes them well suited for a range of applications. Currently SOFC systems are under investigation by researchers as well as being developed by industrial manufacturers. The first commercial SOFC systems have been on the market for some...

  15. Effect of increased fuel exploitation on the main characteristics of spent WWER 440 fuel

    International Nuclear Information System (INIS)

    Zib, A.

    2001-01-01

    The article deals with the effect of a higher fuel exploitation on the main characteristics (particularly radioactivity and decay heat power) of spent WWER 440 fuel. The main characteristics were calculated by using the Origen code. The study was implemented as a three-stage process. In the first stage, the radioactivity and residual thermal power time evolution values were calculated for the 'typical fuel', i. e. fuel assembly with initial enrichment of 3.6% U-235, 3 years in reactor, and burnup of 30 MWd/kg U. In the second stage, ceteris paribus radioactivity and thermal power analyses of sensitivity to changes in the fuel burnup, initial fuel enrichment, and time in reactor were carried out for the typical fuel assembly. In the third stage, the effect of changes in all three variables was investigated for fuel assemblies possessing parameters that approach those applied at the Dukovany NPP. The effect of a higher fuel exploitation on the interim fuel storage is also mentioned. (author)

  16. Description of a reference mixed oxide fuel fabrication plant (MOFFP)

    International Nuclear Information System (INIS)

    1978-01-01

    In order to evaluate the environment impact, due to the Mixed Oxide Fuel Fabrication Plants, work has been initiated to describe the general design and operating conditions of a reference Mixed Oxide Fuel Fabrication Plant (MOFFP) for the 1990 time frame. The various reference data and basic assumptions for the reference MOFFP plant have been defined after discussion with experts. The data reported in this document are only made available to allow an evaluation of the environmental impact due to a reference MOFFP plant. These data have therefore not to be used as recommandation, standards, regulatory guides or requirements

  17. Process for producing nuclear reactor fuel oxides

    International Nuclear Information System (INIS)

    Goenrich, H.; Druckenbrodt, W.G.

    1981-01-01

    The waste gases of the calcination process furnace in the AVC or AV/PuC process (manufacture of nuclear reactor fuel dioxides) are returned to the furnace in a closed circuit. The NH 3 produced replaces the hydrogen which would otherwise be required for reduction in this process. (orig.) [de

  18. Effects of dimethyl ether on the performance characteristics of a direct methanol fuel cell

    International Nuclear Information System (INIS)

    Seo, Sang Hern; Lee, Chang Sik

    2013-01-01

    Highlights: • Activation loss is significantly reduced in fuel cell with DME-methanol. • DME crossover through the membrane reduces. • The open circuit voltage of DME-methanol the fuel cell increases. • The overall efficiency of the mixed fuel cell is higher than that of DMFC. - Abstract: The objective of this study was to determine the effects of dimethyl ether (DME) on the performance characteristics of a direct methanol fuel cell. Impedance and crossover experiments were performed in order to investigate the performance losses such as ohmic loss, activation loss and crossover loss accurately. The DME was pressurized to 5 bar to supply with liquid phase was and blended with an aqueous methanol solution. In this experiment, the membrane electrode assembly (MEA) was composed of Nafion 115, anode catalyst loaded Pt–Ru and cathode catalyst loaded Pt-Black. Experimental results showed that fuel cells with DME-methanol enhanced performance when compared to fuel cells with methanol only. Such performance enhancement was due to a decrease in activation losses by DME oxidation reactions. As the DME crossover through the membrane was reduced, the open circuit voltage (OCV) of the fuel cell increased. Other output characteristics are also discussed

  19. Fabrication of oxide dispersion strengthened ferritic clad fuel pins

    International Nuclear Information System (INIS)

    Zirker, L.R.; Bottcher, J.H.; Shikakura, S.; Tsai, C.L.

    1991-01-01

    A resistance butt welding procedure was developed and qualified for joining ferritic fuel pin cladding to end caps. The cladding are INCO MA957 and PNC ODS lots 63DSA and 1DK1, ferritic stainless steels strengthened by oxide dispersion, while the end caps are HT9 a martensitic stainless steel. With adequate parameter control the weld is formed without a residual melt phase and its strength approaches that of the cladding. This welding process required a new design for fuel pin end cap and weld joint. Summaries of the development, characterization, and fabrication processes are given for these fuel pins. 13 refs., 6 figs., 1 tab

  20. Steam and partial oxidation reforming options for hydrogen production from fossil fuels for PEM fuel cells

    Directory of Open Access Journals (Sweden)

    Yousri M.A. Welaya

    2012-06-01

    Full Text Available Proton exchange membrane fuel cell (PEM generates electrical power from air and from hydrogen or hydrogen rich gas mixtures. Therefore, there is an increasing interest in converting current hydrocarbon based marine fuels such as natural gas, gasoline, and diesel into hydrogen rich gases acceptable to the PEM fuel cells on board ships. Using chemical flow sheeting software, the total system efficiency has been calculated. Natural gas appears to be the best fuel for hydrogen rich gas production due to its favorable composition of lower molecular weight compounds. This paper presents a study for a 250 kW net electrical power PEM fuel cell system utilizing a partial oxidation in one case study and steam reformers in the second. This study has shown that steam-reforming process is the most competitive fuel processing option in terms of fuel processing efficiency. Partial oxidation process has proved to posses the lowest fuel processing efficiency. Among the options studied, the highest fuel processing efficiency is achieved with natural gas steam reforming system.

  1. Melting temperature of uranium - plutonium mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Tetsuya; Hirosawa, Takashi [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center

    1997-08-01

    Fuel melting temperature is one of the major thermodynamical properties that is used for determining the design criteria on fuel temperature during irradiation in FBR. In general, it is necessary to evaluate the correlation of fuel melting temperature to confirm that the fuel temperature must be kept below the fuel melting temperature during irradiation at any conditions. The correlations of the melting temperature of uranium-plutonium mixed oxide (MOX) fuel, typical FBR fuel, used to be estimated and formulized based on the measured values reported in 1960`s and has been applied to the design. At present, some experiments have been accumulated with improved experimental techniques. And it reveals that the recent measured melting temperatures does not agree well to the data reported in 1960`s and that some of the 1960`s data should be modified by taking into account of the recent measurements. In this study, the experience of melting temperature up to now are summarized and evaluated in order to make the fuel pin design more reliable. The effect of plutonium content, oxygen to metal ratio and burnup on MOX fuel melting was examined based on the recent data under the UO{sub 2} - PuO{sub 2} - PuO{sub 1.61} ideal solution model, and then formulized. (J.P.N.)

  2. Melting temperature of uranium - plutonium mixed oxide fuel

    International Nuclear Information System (INIS)

    Ishii, Tetsuya; Hirosawa, Takashi

    1997-08-01

    Fuel melting temperature is one of the major thermodynamical properties that is used for determining the design criteria on fuel temperature during irradiation in FBR. In general, it is necessary to evaluate the correlation of fuel melting temperature to confirm that the fuel temperature must be kept below the fuel melting temperature during irradiation at any conditions. The correlations of the melting temperature of uranium-plutonium mixed oxide (MOX) fuel, typical FBR fuel, used to be estimated and formulized based on the measured values reported in 1960's and has been applied to the design. At present, some experiments have been accumulated with improved experimental techniques. And it reveals that the recent measured melting temperatures does not agree well to the data reported in 1960's and that some of the 1960's data should be modified by taking into account of the recent measurements. In this study, the experience of melting temperature up to now are summarized and evaluated in order to make the fuel pin design more reliable. The effect of plutonium content, oxygen to metal ratio and burnup on MOX fuel melting was examined based on the recent data under the UO 2 - PuO 2 - PuO 1.61 ideal solution model, and then formulized. (J.P.N.)

  3. Ignition delay and soot oxidative reactivity of MTBE blended diesel fuel

    KAUST Repository

    Yang, Seung Yeon; Naser, Nimal; Chung, Suk-Ho; Al-Qurashi, Khalid

    2014-01-01

    Methyl tert-butyl ether (MTBE) was added to diesel fuel to investigate the effect on ignition delay and soot oxidative reactivity. An ignition quality tester (IQT) was used to study the ignition propensity of MTBE blended diesel fuels in a reactive spray environment. The IQT data showed that ignition delay increases linearly as the MTBE fraction increases in the fuel. A four-stroke single cylinder diesel engine was used to generate soot samples for a soot oxidation study. Soot samples were pre-treated using a tube furnace in a nitrogen environment to remove any soluble organic fractions and moisture content. Non-isothermal oxidation of soot samples was conducted using a thermogravimetric analyzer (TGA). It was observed that oxidation of 'MTBE soot' started began at a lower temperature and had higher reaction rate than 'diesel soot' across a range of temperatures. Several kinetic analyses including an isoconversional method and a combined model fitting method were carried out to evaluate kinetic parameters. The results showed that Diesel and MTBE soot samples had similar activation energy but the pre-exponential factor of MTBE soot was much higher than that of the Diesel soot. This may explain why MTBE soot was more reactive than Diesel soot. It is suggested that adding MTBE to diesel fuel is better for DPF regeneration since an MTBE blend can significantly influence the ignition characteristics and, consequently, the oxidative reactivity of soot. Copyright © 2014 SAE International.

  4. Ignition delay and soot oxidative reactivity of MTBE blended diesel fuel

    KAUST Repository

    Yang, Seung Yeon

    2014-04-01

    Methyl tert-butyl ether (MTBE) was added to diesel fuel to investigate the effect on ignition delay and soot oxidative reactivity. An ignition quality tester (IQT) was used to study the ignition propensity of MTBE blended diesel fuels in a reactive spray environment. The IQT data showed that ignition delay increases linearly as the MTBE fraction increases in the fuel. A four-stroke single cylinder diesel engine was used to generate soot samples for a soot oxidation study. Soot samples were pre-treated using a tube furnace in a nitrogen environment to remove any soluble organic fractions and moisture content. Non-isothermal oxidation of soot samples was conducted using a thermogravimetric analyzer (TGA). It was observed that oxidation of \\'MTBE soot\\' started began at a lower temperature and had higher reaction rate than \\'diesel soot\\' across a range of temperatures. Several kinetic analyses including an isoconversional method and a combined model fitting method were carried out to evaluate kinetic parameters. The results showed that Diesel and MTBE soot samples had similar activation energy but the pre-exponential factor of MTBE soot was much higher than that of the Diesel soot. This may explain why MTBE soot was more reactive than Diesel soot. It is suggested that adding MTBE to diesel fuel is better for DPF regeneration since an MTBE blend can significantly influence the ignition characteristics and, consequently, the oxidative reactivity of soot. Copyright © 2014 SAE International.

  5. LG Solid Oxide Fuel Cell (SOFC) Model Development

    Energy Technology Data Exchange (ETDEWEB)

    Haberman, Ben [LG Fuel Cell Systems Inc., North Canton, OH (United States); Martinez-Baca, Carlos [LG Fuel Cell Systems Inc., North Canton, OH (United States); Rush, Greg [LG Fuel Cell Systems Inc., North Canton, OH (United States)

    2013-05-31

    This report presents a summary of the work performed by LG Fuel Cell Systems Inc. during the project LG Solid Oxide Fuel Cell (SOFC) Model Development (DOE Award Number: DE-FE0000773) which commenced on October 1, 2009 and was completed on March 31, 2013. The aim of this project is for LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) to develop a multi-physics solid oxide fuel cell (SOFC) computer code (MPC) for performance calculations of the LGFCS fuel cell structure to support fuel cell product design and development. A summary of the initial stages of the project is provided which describes the MPC requirements that were developed and the selection of a candidate code, STAR-CCM+ (CD-adapco). This is followed by a detailed description of the subsequent work program including code enhancement and model verification and validation activities. Details of the code enhancements that were implemented to facilitate MPC SOFC simulations are provided along with a description of the models that were built using the MPC and validated against experimental data. The modeling work described in this report represents a level of calculation detail that has not been previously available within LGFCS.

  6. Strength of Anode‐Supported Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Faes, A.; Frandsen, Henrik Lund; Kaiser, Andreas

    2011-01-01

    Nickel oxide and yttria doped zirconia composite strength is crucial for anode‐supported solid oxide fuel cells, especially during transient operation, but also for the initial stacking process, where cell curvature after sintering can cause problems. This work first compares tensile and ball....... Even though the electrolyte is to the tensile side, it is found that the anode support fails due to the thermo‐mechanical residual stresses....

  7. Platinum redispersion on metal oxides in low temperature fuel cells

    DEFF Research Database (Denmark)

    Tripkovic, Vladimir; Cerri, Isotta; Nagami, Tetsuo

    2013-01-01

    We have analyzed the aptitude of several metal oxide supports (TiO2, SnO2, NbO2, ZrO2, SiO2, Ta2O5 and Nb2O5) to redisperse platinum under electrochemical conditions pertinent to the Proton Exchange Membrane Fuel Cell (PEMFC) cathode. The redispersion on oxide supports in air has been studied in ...

  8. Fuel cells: spectroscopic studies in the electrocatalysis of alcohol oxidation

    OpenAIRE

    Iwasita Teresa

    2002-01-01

    Modern spectroscopic methods are useful for elucidating complex electrochemical mechanisms as those occurring during the oxidation of small organic molecules (CH3OH, HCOH, HCOOH). In the present paper it is shown the use of spectroscopic methods to study the oxidation of alcohols on platinum or Pt-based binary electrodes. These reactions are of importance in conexion with the development of anode systems for use in fuel cells. Mass spectrometry and FT infrared spectroscopy allow to establishi...

  9. Characteristic test technology for PWR fuel and its components

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dae Ho; Lee, Chan Bock; Bang, Je Gun; Jung, Yeon Ho; Jeong, Yong Hwan; Park, Sang Yoon; Kim, Kyeng Ho; Nam, Cheol; Baek, Jong Hyuk; Lee, Myung Ho; Choi, Byoung Kwon; Song, Kun Woo; Kang, Ki Won; Kim, Keon Sik; Kim, Jong Hun; Kim, Young Min; Yang, Jae Ho; Song, Kee Nam; Kim, Hyung Kyu; Kang, Heung Seok; Yoon, Kyung Ho; Chun, Tae Hyun; In, Wang Kee; Oh, Dong Seok [Korea Atomic Energy Research Institute, Taejeon (Korea)

    2000-01-01

    Characteristic tests of fuel assembly and its components being developed in the Advanced LWR Fuel Development Project supported by the mid-long term nuclear R and D program are described in this report. Performance verification of fuel and its components by the characteristic tests are essential to their development. Fuel components being developed in the Advanced LWR Fuel Development Project are zirconium alloy cladding, UO{sub 2} and burnable absorber pellets, spacer grid and top and bottom end pieces. Detailed test plans for those fuel components are described in this report, and test procedures of cladding and pellet are also described in the Appendix. Examples of the described tests are in- and out-of- pile corrosion and mechanical tests such as creep and burst tests for the cladding, in-pile capsule and ramp tests for the pellet, mechanical tests such as strength and vibration, and thermal-hydraulic tests such as pressure drop and critical heat flux for the spacer grid and top and bottom end pieces. It is expected that this report could be used as the standard reference for the performance verification tests in the development of LWR fuel and its components. 11 refs., 9 figs., 2 tabs. (Author)

  10. Low temperature spent fuel oxidation under tuff repository conditions

    International Nuclear Information System (INIS)

    Einziger, R.E.; Woodley, R.E.

    1985-01-01

    The Nevada Nuclear Waste Storage Investigations Project is studying the suitability of tuffaceous rocks at Yucca Mountain, Nye County, Nevada, for high level waste disposal. The oxidation state of LWR spent fuel in a tuff repository may be a significant factor in determining its ability to inhibit radionuclide migration. Long term exposure at low temperatures to the moist air expected in a tuff repository is expected to increase the oxidation state of the fuel. A program is underway to determine the spent fuel oxidation mechanisms which might be active in a tuff repository. Initial work involves a series of TGA experiments to determine the effectiveness of the technique and to obtain preliminary oxidation data. Tests were run at 200 0 C and 225 0 C for as long as 720 hours. Grain boundary diffusion appears to open up a greater surface area for oxidation prior to onset of bulk diffusion. Temperature strongly influences the oxidation rates. The effect of moisture is small but readily measurable. 25 refs., 7 figs., 4 tabs

  11. Monitoring the oxidation of nuclear fuel cladding using Raman spectroscopy

    International Nuclear Information System (INIS)

    Mi, Hongyi; Mikael, Solomon; Allen, Todd; Sridharan, Kumar; Butt, Darryl; Blanchard, James P.; Ma, Zhenqiang

    2014-01-01

    In order to observe Zircaloy-4 (Zr-4) cladding oxidation within a spent fuel canister, cladding oxidized in air at 500 °C was investigated by micro-Raman spectroscopy to measure the oxide layer thickness. Systematic Raman scans were performed to study the relationship between typical Raman spectra and various oxide layer thicknesses. The thicknesses of the oxide layers developed for various exposure times were measured by cross-sectional Scanning Electron Microscopy (SEM). The results of this work reveal that each oxide layer thickness has a corresponding typical Raman spectrum. Detailed analysis suggests that the Raman scattering peaks around wave numbers of 180 cm −1 and 630 cm −1 are the best choices for accurately determining the oxide layer thickness. After Gaussian–Lorentzian deconvolution, these two peaks can be quantitatively represented by four peaks. The intensities of the deconvoluted peaks increase consistently as the oxide layer becomes thicker and sufficiently strong signals are produced, allowing one to distinguish the bare and oxidized cladding samples, as well as samples with different oxide layer thicknesses. Hence, a process that converts sample oxide layer thickness to optical signals can be achieved

  12. Engine performance and emissions characteristics of a diesel engine fueled with diesel-biodiesel-bioethanol emulsions

    International Nuclear Information System (INIS)

    Tan, Yie Hua; Abdullah, Mohammad Omar; Nolasco-Hipolito, Cirilo; Zauzi, Nur Syuhada Ahmad; Abdullah, Georgie Wong

    2017-01-01

    Highlights: • Different composition of diesel fuel, biodiesel and bioethanol emulsions were examined. • The fuels were tested in a direct injection diesel engine and parameters were evaluated. • Engine power, torque, exhaust gas temperature & fuel consumptions were compared. • Emulsions fuels emitted lower CO and CO_2 than fossil diesel. • Lower NOx emission was observed at medium engine speeds and loads for emulsion fuels. - Abstract: In this research work, the experimental investigation of the effect of diesel-biodiesel-bioethanol emulsion fuels on combustion, performance and emission of a direct injection (DI) diesel engine are reported. Four kind of emulsion fuels were employed: B (diesel-80%, biodiesel-20% by volume), C (diesel-80%, biodiesel-15%, bioethanol-5%), D (diesel-80%, biodiesel-10%, bioethanol-10%) and E (diesel-80%, biodiesel-5%, bioethanol-15%) to compare its’ performance with the conventional diesel, A. These emulsion fuels were prepared by mechanical homogenizer machine with the help of Tween 80 (1% v/v) and Span 80 (0.5% v/v) as surfactants. The emulsion characteristics were determined by optical electron microscope, emulsification stability test, FTIR, and the physiochemical properties of the emulsion fuels which were all done by following ASTM test methods. The prepared emulsion fuels were then tested in diesel engine test bed to obtain engine performance and exhaust emissions. All the engine experiments were conducted with engine speeds varying from 1600 to 2400 rpm. The results showed the heating value and density of the emulsion fuels decrease as the bioethanol content in the blend increases. The total heating value of the diesel-biodiesel-bioethanol fuels were averagely 21% higher than the total heating value of the pure biodiesel and slightly lower (2%) than diesel fuel. The engine power, torque and exhaust gas temperature were reduced when using emulsion fuels. The brake specific fuel consumption (BSFC) for the emulsion fuels

  13. Fuel-sodium reaction product formation in breached mixed-oxide fuel

    International Nuclear Information System (INIS)

    Bottcher, J.H.; Lambert, J.D.B.; Strain, R.V.; Ukai, S.; Shibahara, S.

    1988-01-01

    The run-beyond-cladding-breach (RBCB) operation of mixed-oxide LMR fuel pins has been studied for six years in the Experimental Breeder Reactor-II (EBR-II) as part of a joint program between the US Department of Energy and the Power Reactor and Nuclear Fuel Development Corporation of Japan. The formation of fuel-sodium reaction product (FSRP), Na 3 MO 4 , where M = U/sub 1-y/Pu/sub y/, in the outer fuel regions is the major phenomenon governing RBCB behavior. It increases fuel volume, decreases fuel stoichiometry, modifies fission-product distributions, and alters thermal performance of a pin. This paper describes the morphology of Na 3 MO 4 observed in 5.84-mm diameter pins covering a variety of conditions and RBCB times up to 150 EFPD's. 8 refs., 1 fig

  14. Solid Oxide Fuel Cell Stack Diagnostics

    DEFF Research Database (Denmark)

    Mosbæk, Rasmus Rode; Barfod, Rasmus Gottrup

    As SOFC technology is moving closer to a commercial break through, methods to measure the “state-of-health” of operating stacks are becoming of increasing interest. This requires application of advanced methods for detailed electrical and electrochemical characterization during operation....... An operating stack is subject to compositional gradients in the gaseous reactant streams, and temperature gradients across each cell and across the stack, which complicates detailed analysis. Several experimental stacks from Topsoe Fuel Cell A/S were characterized using Electrochemical Impedance Spectroscopy...... in the hydrogen fuel gas supplied to the stack. EIS was used to examine the long-term behavior and monitor the evolution of the impedance of each of the repeating units and the whole stack. The observed impedance was analyzed in detail for one of the repeating units and the whole stack and the losses reported...

  15. Oxide fuels and targets for transmutation

    International Nuclear Information System (INIS)

    Sudreau, F.; Bonnerot, J.M.; Warin, D.; Gaillard-Groleas, G.; Ferroud-Plattet, M.P.

    2007-01-01

    Full text of publication follows. Direction 1 of the French Act dated 30 December 1991 on the management of high-level, long-lived radioactive waste involves exploring solutions designed to separate long-lived radionuclides from the spent fuel and to transmute them under neutron flux into shorter half-lives or stable elements. In the French research programme conducted by CEA, these radionuclides are mainly minor actinides (americium, neptunium and curium) and fission products (particularly caesium, iodine and technetium). Within this context, this paper aims at illustrating the vast programme that CEA has performed in order to demonstrate the scientific and technical feasibility of minor actinide transmutation. An important part of the research was carried out in collaboration with French research (CNRS) and industrial (EDF, AREVA) organisations, and also in the framework of international co-operation programmes with the European Institute for Transuranium Elements in Karlsruhe (ITU), the US Department of Energy (DOE), the Japanese Atomic Energy Research Institute (now JAEA) and Central Research Institute of Electric Power Industry (CRIEPI) and the Russian Ministry for Atomic Energy (ROSATOM). Such research made it possible to evaluate the capacity of MOX fuels to be used as a support for minor actinide transmutation (homogeneous method). Simulations of pressurised water reactor (PWR) fuels have revealed the limits of this transmutation method, which are mainly related to the pressurization of the fuel rods and the formation of high active californium. On the contrary, for sodium-cooled fast reactor fuels possibly designed with large expansion plenums a first experimental demonstration of the transmutation of americium and neptunium has been successful in the Phenix reactor. Various studies designed to demonstrate the theoretical and experimental feasibility of transmutation using an inert support (heterogeneous method) have been carried out in HFR (EFTTRA

  16. NITROUS OXIDE EMISSIONS FROM FOSSIL FUEL COMBUSTION

    Science.gov (United States)

    The role of coal combustion as a significant global source of nitrous oxide (N2O) emissions was reexamined through on-line emission measurements from six pulverized-coal-fired utility boilers and from laboratory and pilot-scale combustors. The full-scale utility boilers yielded d...

  17. Radiation characteristics of GD-2 fuel

    International Nuclear Information System (INIS)

    Chrapciak, V.

    2008-01-01

    The assembly WWER-440 type Gd-2 has radial profile of enrichment and has 6 pins with Gd 2 O 3 . The maximal enrichment is 4.4%. Some analyses are done for assembly with flat enrichment (4.4%) and without Gd 2 O 3 . In this article are compared some characteristics (decay heat, some nuclide concentration, photon and gamma sources) for real Gd-2 assembly and for flat 4.4% assembly. The TRITON module (in SCALE 5.1) was used. (Author)

  18. Micro-Solid Oxide Fuel Cell: A multi-fuel approach for portable applications

    International Nuclear Information System (INIS)

    Patil, Tarkeshwar C.; Duttagupta, Siddhartha P.

    2016-01-01

    Highlights: • We report the oxygen ion transport properties at the electrode–electrolyte interface (EEI) of the SOFC for the first time. • This ion transport plays a key role in the overall performance of SOFCs with different fuels. • The GIIB mechanism is also studied for the first time. • GIIB is assumed to be the prime reason for low power density and ion conductivity at the EEI when using hydrocarbon fuels. • Due to its scalability, a fuel cell can serve as a power source for on-chip applications and all portable equipment. - Abstract: The impact of oxygen ion transport at the electrolyte–electrode interface of a micro-solid oxide fuel cell using different fuels is investigated. Model validation is performed to verify the results versus the reported values. Furthermore, as the hydrogen-to-carbon ratio decreases, the diffusivity of the oxygen ion increases. This increase in diffusivity is observed because the number of hydrogen atoms available as the reacting species increases in fuels with lower hydrogen-to-carbon ratios. The oxygen ion conductivity and output power density decrease as the hydrogen-to-carbon ratio of the fuels decreases. The reason behind this impact is the formation of a gas-induced ion barrier at the electrode–electrolyte interface by the CO_2 molecules formed during the reaction at the interface, thus blocking the flow of oxygen ions. As the oxygen ions become blocked, the output current contribution from the reaction also decreases and thereby affects the overall performance of the micro-solid oxide fuel cell. The experimental verification confirms this because of a significant decrease in the output power density. Furthermore, as per the application in portable devices, the appropriate choice of fuel can be chosen so that the micro-solid oxide fuel cell operates at the maximum power density.

  19. Performance of advanced oxide fuel pins in EBR-II

    International Nuclear Information System (INIS)

    Lawrence, L.A.; Jensen, S.M.; Hales, J.W.; Karnesky, R.A.; Makenas, B.J.

    1986-05-01

    The effects of design and operating parameters on mixed-oxide fuel pin irradiation performance were established for the Hanford Engineering Development Laboratory (HEDL) advanced oxide EBR-II test series. Fourteen fuel pins breached in-reactor with reference 316 SS cladding. Seven of the breaches are attributed to FCMI. Of the remaining seven breached pins, three are attributed to local cladding over-temperatures similar to the breach mechanism for the reference oxide pins irradiated in EBR-II. FCCI was found to be a contributing factor in two high burnup, i.e., 11.7 at. % breaches. The remaining two breaches were attributed to mechanical interaction of UO 2 fuel and fission products accumulated in the lower cladding insulator gap, and a loss of cladding ductility possibly due to liquid metal embrittlement. Fuel smear density appears to have the most significant impact on lifetime. Quantitative evaluations of cladding diameter increases attributed to FCMI, established fuel smear density, burnup, and cladding thickness-to-diameter ratio as the major parameters influencing the extent of cladding strain

  20. Technoeconomy of different solid oxide fuel cell based hybrid cycle

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2014-01-01

    Gas turbine, steam turbine and heat engine (Stirling engine) is used as bottoming cycle for a solid oxide fuel cell plant to compare different plants efficiencies, CO2 emissionsand plants cost in terms of $/kW. Each plant is then integrated with biomass gasification and finally six plants...

  1. Kinetic and geometric aspects of solid oxide fuel cell electrodes

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Skaarup, Steen

    1996-01-01

    The paper gives an overview of the main factors controlling the performance of the solid oxide fuel cell (SOFC) electrodes, emphasizing the most widely chosen anodes and cathodes, Ni-YSZ and LSM-YSZ. They are often applied as composites (mixtures) of the electron conducting electrode material...

  2. Safety criteria related to microheterogeneities in LWR mixed oxide fuels

    International Nuclear Information System (INIS)

    Renard, A.; Mostin, N.

    1978-01-01

    The main safety aspets of PuO 2 microheterogeneities in the pellets of LWR mixed oxide fuels are reviewed. Points of interest are studied, especially the transient behaviour in accidental conditions and criteria are deduced for use in the specification and quality control of the fabricated product. (author)

  3. POST CRITICAL HEAT TRANSFER AND FUEL CLADDING OXIDATION

    Directory of Open Access Journals (Sweden)

    Vojtěch Caha

    2016-12-01

    Full Text Available The knowledge of heat transfer coefficient in the post critical heat flux region in nuclear reactor safety is very important. Although the nuclear reactors normally operate at conditions where critical heat flux (CHF is not reached, accidents where dryout occur are possible. Most serious postulated accidents are a loss of coolant accident or reactivity initiated accident which can lead to CHF or post CHF conditions and possible disruption of core integrity. Moreover, this is also influenced by an oxide layer on the cladding surface. The paper deals with the study of mathematical models and correlations used for heat transfer calculation, especially in post dryout region, and fuel cladding oxidation kinetics of currently operated nuclear reactors. The study is focused on increasing of accuracy and reliability of safety limit calculations (e.g. DNBR or fuel cladding temperature. The paper presents coupled code which was developed for the solution of forced convection flow in heated channel and oxidation of fuel cladding. The code is capable of calculating temperature distribution in the coolant, cladding and fuel and also the thickness of an oxide layer.

  4. Simulation with GOTHIC of experiments Oxidation of fuel in Air

    International Nuclear Information System (INIS)

    Martinez-Murillo Mendez, J. C.

    2012-01-01

    In the present work has been addressed for the first time la simulation with the GOTHIC code, experiments oxidation and ignition of SFP in phase 1. This work represents a solid starting point for analysis of specific degradation of fuel in the pools of our facilities.

  5. Safety problems related to microheterogeneities in physically mixed oxide fuels

    International Nuclear Information System (INIS)

    Renard, A.; Evrard, G.; Vanhellemont, G.

    1976-01-01

    The safety aspects of microheterogeneities in LMFBR mixed oxide fuel are reviewed from the point of view of the pin behaviour dynamic study, the fabrication and the quality control. The paper emphasizes some significant parameters in transient conditions, the prevention means in the fabrication process and the analysis methods for the control

  6. Characteristics and behaviour of the PHENIX fuel element

    International Nuclear Information System (INIS)

    Delpeyroux, P.; Balloffet, Y.; Blanchard, P.; Courcon, P.; Jallade, M.; Millet, P.; Rousseau, J.; Carteret, Y.; Coulon, P.

    1977-01-01

    The Phenix reactor has been in regular industrial operation for two years and has functioned very satisfactorily thanks in particular to the very good behaviour of the fuel element. A brief description is given of the fuel element and the operating conditions which were set for the fuel at the time of start-up (50000 MWd/t). The surveillance scheme is then described with the examinations in the hot laboratory on the basis of which it was possible to achieve the nominal specific burn-up and then to clear the Phenix fuel for a specific burn-up of 60000 MWd/t or 7 at.%. The behaviour of the mixed oxide (U, Pu)O 2 is quite normal and conforms to predictions as regards the heat conditions, swelling and fission gas release. The corrosion reaction between the oxide and the clad is progressing slowly and affects only small thicknesses of cladding. The mechanical integrity of the clad under thermal stresses and the stresses produced by swelling and fission gas pressure do not pose any special problem. The present limitation of the irradiation level is essentially based on the permissible deformations due to swelling and irradiation creep in the fuel pin cladding and in the hexagonal tube. This corresponds to damage to the steel of the order of 80 dpa. The mechanical behaviour of the bundle of pins, its interaction with the hexagonal tube and the thermohydraulic consequences of the deformations are all satisfactory to date. The absence of fuel failures is also worth noting; the only burst can detected to date did not affect either the operation of the fuel assembly or the performance of the reactor [fr

  7. Thermodynamic and kinetic modelling of fuel oxidation behaviour in operating defective fuel

    International Nuclear Information System (INIS)

    Lewis, B.J.; Thompson, W.T.; Akbari, F.; Thompson, D.M.; Thurgood, C.; Higgs, J.

    2004-01-01

    A theoretical treatment has been developed to predict the fuel oxidation behaviour in operating defective nuclear fuel elements. The equilibrium stoichiometry deviation in the hyper-stoichiometric fuel has been derived from thermodynamic considerations using a self-consistent set of thermodynamic properties for the U-O system, which emphasizes replication of solubilities and three-phase invariant conditions displayed in the U-O binary phase diagram. The kinetics model accounts for multi-phase transport including interstitial oxygen diffusion in the solid and gas-phase transport of hydrogen and steam in the fuel cracks. The fuel oxidation model is further coupled to a heat conduction model to account for the feedback effect of a reduced thermal conductivity in the hyper-stoichiometric fuel. A numerical solution has been developed using a finite-element technique with the FEMLAB software package. The model has been compared to available data from several in-reactor X-2 loop experiments with defective fuel conducted at the Chalk River Laboratories. The model has also been benchmarked against an O/U profile measurement for a spent defective fuel element discharged from a commercial reactor

  8. Corrosion mechanisms of spent fuel under oxidizing conditions

    International Nuclear Information System (INIS)

    Finn, P.A.; Finch, R.; Buck, E.; Bates, J.

    1997-01-01

    The release of 99 Tc can be used as a reliable marker for the extent of spent oxide fuel reaction under unsaturated high-drip-rate conditions at 90 degrees C. Evidence from leachate data and from scanning and transmission electron microscopy (SEM and TEM) examination of reacted fuel samples is presented for radionuclide release, potential reaction pathways, and the formation of alteration products. In the ATM-103 fuel, 0.03 of the total inventory of 99 Tc is released in 3.7 years under unsaturated and oxidizing conditions. Two reaction pathways that have been identified from SEM are (1) through-grain dissolution with subsequent formation of uranyl alteration products, and (2) grain-boundary dissolution. The major alteration product identified by x-ray diffraction (XRD) and SEM, is Na-boltwoodite, Na[(UO 2 )(SiO 3 OH)]lg-bullet H 2 O, which is formed from sodium and silicon in the water leachant

  9. Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Faress Rahman; Nguyen Minh

    2004-01-04

    This report summarizes the work performed by Hybrid Power Generation Systems, LLC (HPGS) during the July 2003 to December 2003 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a micro-turbine. In addition, an activity included in this program focuses on the development of an integrated coal gasification fuel cell system concept based on planar SOFC technology. Also, another activity included in this program focuses on the development of SOFC scale up strategies.

  10. Development of a solid oxide fuel cell (SOFC) automotive auxiliary power unit (APU) fueled by gasoline

    International Nuclear Information System (INIS)

    DeMinco, C.; Mukerjee, S.; Grieve, J.; Faville, M.; Noetzel, J.; Perry, M.; Horvath, A.; Prediger, D.; Pastula, M.; Boersma, R.; Ghosh, D.

    2000-01-01

    This paper describes the design and the development progress of a 3 to 5 auxiliary power unit (APU) based on a gasoline fueled solid oxide fuel cell (SOFC). This fuel cell was supplied reformate gas (reactant) by a partial oxidation (POx) catalytic reformer utilizing liquid gasoline and designed by Delphi Automotive Systems. This reformate gas consists mainly of hydrogen, carbon monoxide and nitrogen and was fed directly in to the SOFC stack without any additional fuel reformer processing. The SOFC stack was developed by Global Thermoelectric and operates around 700 o C. This automotive APU produces power to support future 42 volt vehicle electrical architectures and loads. The balance of the APU, designed by Delphi Automotive Systems, employs a packaging and insulation design to facilitate installation and operation on-board automobiles. (author)

  11. Combustion and emission characteristics of a natural gas-fueled diesel engine with EGR

    International Nuclear Information System (INIS)

    Abdelaal, M.M.; Hegab, A.H.

    2012-01-01

    Highlights: ► An existed DI diesel engine has been modified to suit dual fuel operation with EGR. ► Comparative study has been conducted between different operating modes. ► Dual fuel mode exhibits better performance at high loads than diesel. ► Dual fuel mode exhibits lower NOx and higher HC emissions than diesel. ► EGR improves performance at part loads and emissions of dual fuel mode. - Abstract: The use of natural gas as a partial supplement for liquid diesel fuel is a very promising solution for reducing pollutant emissions, particularly nitrogen oxides (NOx) and particulate matters (PM), from conventional diesel engines. In most applications of this technique, natural gas is inducted or injected in the intake manifold to mix uniformly with air, and the homogenous natural gas–air mixture is then introduced to the cylinder as a result of the engine suction. This type of engines, referred to as dual-fuel engines, suffers from lower thermal efficiency and higher carbon monoxide (CO) and unburned hydrocarbon (HC) emissions; particularly at part load. The use of exhaust gas recirculation (EGR) is expected to partially resolve these problems and to provide further reduction in NOx emission as well. In the present experimental study, a single-cylinder direct injection (DI) diesel engine has been properly modified to run on dual-fuel mode with natural gas as a main fuel and diesel fuel as a pilot, with the ability to employ variable amounts of EGR. Comparative results are given for various operating modes; conventional diesel mode, dual-fuel mode without EGR, and dual-fuel mode with variable amounts of EGR, at different operating conditions; revealing the effect of utilization of EGR on combustion process and exhaust emission characteristics of a pilot ignited natural gas diesel engine.

  12. Analysis of some fuel characteristics deviations and their influence over WWER-440 fuel cycle design

    International Nuclear Information System (INIS)

    Stoyanova, I.; Kamenov, K.

    2001-01-01

    The aim of this study is to estimate the influence of some deviations in WWER-440 fuel assemblies (FA) characteristics upon fuel core design. A large number of different fresh fuel assemblies with enrichment of 3.5 t % are examined related to the enrichment, mass of initial metal Uranium and assembly shroud thickness. Infinite multiplication factor (Kinf) in fuel assembly has been calculated by HELIOS spectral code for basic assembly and for different FA with deviation of a single parameter. The effects from single parameter deviation (enrichment) and from two parameter deviations (enrichment and wall thickness) on the neutron-physics characteristics of the core are estimated for different fuel assemblies. Relatively week burnup dependence on Kinf is observed as result of deviation in the enrichment of the fuel and in the wall thickness of the assembly. An assessment of a FA single and two parameter deviations effects on design fuel cycle duration and relative power peaking factor is also considers in the paper. As a final conclusion can be settled that the maximum relative shortness of fuel cycle can be observed in the case of two FA parameters deviations

  13. Confinement of ruthenium oxides volatilized during nuclear fuels reprocessing

    International Nuclear Information System (INIS)

    Maas, E.T. Jr.; Longo, J.M.

    1980-01-01

    While many materials have been suggested and employed as trapping agents for gaseous oxides of fission product ruthenium volatilized during nuclear fuels reprocessing, none that is known to form thermodynamically stable compounds with rutheniunm has been utilized. We have employed alkaline earth metal compounds for this purpose because of their ability to form stable mixed metal oxide phases with ruthenium. Results of experiments in which RuO 4 was volatilized from either a solid source (RuO 2 .xH 2 O) or from solution [Ru(NO)(NO 3 ) 3 ] in HNO 3 and passed through beds of alkaline earth metal carbonates and calcium oxide held at 600 to 750 0 C have demonstrated that compounds of formulation MRuO 3 (M = calcium, strontium, barium) are formed. Under oxidizing conditions, these materials exist as stable ceramic phases, whereas under reducing conditions, they are transformed into intimate mixtures of the alkaline earth metal oxide and nonvolatile ruthenium metal

  14. Contribution to characteristics of uranium oxides

    International Nuclear Information System (INIS)

    Fritsche, R.; Dahlkamp, F.J.

    2001-01-01

    Uranium oxides from pegmatitic, metamorphic and metasomatic uranium occurrences were investigated with the objective to check for differences in their physico-chemical properties and, whether such properties are sufficiently distinct to be applied as an exploration tool. Research methods included microscopy, electron microprobe and X-ray diffractometry amended by determinations of reflectance, Vickers hardness, unit-cell dimension and oxidation grade. Tentative research results are as follows: (a) U-oxides (uraninites) of pegmatites always contain significant amounts of Th (1,5-10 wt.% ThO2). (b) U-oxides from metasomatic environments have high, but variable contents of Fe, Ca, Ti, Si and Th (around 10 wt.%), Th being low. (c) U-oxides crystallised during metamorphism contain minor impurities of the above listed elements (total of oxides < 2 wt.%). (d) Redistributed U-oxides have elevated amounts of these elements. (e) Unit-cell dimensions of U-oxides tend to reflect a complex function of formation temperature, oxidation grade and the influence of incorporated elements caused by their radius and electro-negativity. (f) A global negative correlation of unit-cell dimension and oxidation grade of uranium oxides is indicated but based on widely varying ratios of the two parameters. (g) Colloform U-oxide (pitchblende) is characterised by elevated Ca-contents (1-5 wt.% CaO) and an almost complete lack of Th (< 1 wt.% ThO2). (h) Idiomorphic U-oxide (uraninite) is commonly low in Ca (< 1.5 wt.% CaO) but contains relatively high Th values. (i) The reflectance of U-oxides generally correlates positively with Vickers hardness and unit-cell dimension, but the incorporation of other elements in the lattice of U-oxides may cause strong interference. (author)

  15. A development of solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Hee Chun; Lee, Chang Woo [Korea Electric Power Corp. (KEPCO), Taejon (Korea, Republic of). Research Center; Kim, Kwy Youl; Yoon, Moon Soo; Kim, Ho Ki; Kim, Young Sik; Mun, Sung In; Eom, Sung Wuk [Korea Electrotechnology Research Inst., Changwon (Korea, Republic of)

    1995-12-31

    Solid oxide fuel cell which was consisted of ceramics has high power density and is very simple in shape. The project named A development of SOFC(Solid Oxide Fuel Cell) technology is to develop the unit cell fabrication processing and to evaluate the unit cell of solid oxide full cell. In this project, a manufacturing process of cathode by citrate method and polymeric precursor methods were established. By using tape casting method, high density thin electrolyte was manufactured and has high performance. Unit cell composed with La{sub 17}Sr{sub 13}Mn{sub 3} as cathode, 8YSZ electrolyte and 50% NiYSZ anode had a performance of O.85 W/cm{sup 2} and recorded 510 hours operation time. On the basis of these results. 100 cm{sup 2} class unit cell will be fabricated and tests in next program (author). 59 refs., 120 figs.

  16. A development of solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Hee Chun; Lee, Chang Woo [Korea Electric Power Corp. (KEPCO), Taejon (Korea, Republic of). Research Center; Kim, Kwy Youl; Yoon, Moon Soo; Kim, Ho Ki; Kim, Young Sik; Mun, Sung In; Eom, Sung Wuk [Korea Electrotechnology Research Inst., Changwon (Korea, Republic of)

    1996-12-31

    Solid oxide fuel cell which was consisted of ceramics has high power density and is very simple in shape. The project named A development of SOFC(Solid Oxide Fuel Cell) technology is to develop the unit cell fabrication processing and to evaluate the unit cell of solid oxide full cell. In this project, a manufacturing process of cathode by citrate method and polymeric precursor methods were established. By using tape casting method, high density thin electrolyte was manufactured and has high performance. Unit cell composed with La{sub 17}Sr{sub 13}Mn{sub 3} as cathode, 8YSZ electrolyte and 50% NiYSZ anode had a performance of O.85 W/cm{sup 2} and recorded 510 hours operation time. On the basis of these results. 100 cm{sup 2} class unit cell will be fabricated and tests in next program (author). 59 refs., 120 figs.

  17. The underwater coincidence counter for plutonium measurements in mixed-oxide fuel assemblies manual

    International Nuclear Information System (INIS)

    Eccleston, G.W.; Menlove, H.O.; Abhold, M.; Baker, M.; Pecos, J.

    1999-01-01

    This manual describes the Underwater Coincidence Counter (UWCC) that has been designed for the measurement of plutonium in mixed-oxide (MOX) fuel assemblies prior to irradiation. The UWCC uses high-efficiency 3 He neutron detectors to measure the spontaneous-fission and induced-fission rates in the fuel assembly. Measurements can be made on MOX fuel assemblies in air or underwater. The neutron counting rate is analyzed for singles, doubles, and triples time correlations to determine the 240 Pu effective mass per unit length of the fuel assembly. The system can verify the plutonium loading per unit length to a precision of less than 1% in a measurement time of 2 to 3 minutes. System design, components, performance tests, and operational characteristics are described in this manual

  18. Spent fuel and radioactive waste inventories, projections, and characteristics

    International Nuclear Information System (INIS)

    1984-09-01

    Current inventories and characteristics of commercial spent fuels and both commercial and US Department of Energy (DOE) radioactive wastes were compiled through December 31, 1983, based on the most reliable information available from government sources and the open literature, technical reports, and direct contacts. Future waste and spent fuel to be generated over the next 37 years and characteristics of these materials are also presented, consistent with the latest DOE/Energy Information Administration (EIA) or projection of US commercial nuclear power growth and expected defense-related and private industrial and institutional activities. Materials considered, on a chapter-by-chapter basis, are: spent fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, airborne waste, remedial action waste, and decommissioning waste. For each category, current and projected inventories are given through the year 2020, and the radioactivity and thermal power are calculated, based on reported or calculated isotopic compositions. 48 figures, 107 tables

  19. Caramel, uranium oxide fuel plates for water cooled reactors

    International Nuclear Information System (INIS)

    Bussy, Pierre; Delafosse, Jacques; Lestiboudois, Guy; Cerles, J.-M.; Schwartz, J.-P.

    1979-01-01

    The fuel is composed of thin plates assembled parallel to each other to form bundles or assemblies. Each plate is composed of a pavement of uranium oxide pellets, insulated from each other by a zircaloy cladding. The 235 U enrichment does not exceed 8%. The range of uses for this fuel extends from electric power generating reactors to irradiation reactors for research work. A parametric study in test loops has made it possible to determine the operating limits of this thick fuel, without bursting. The resulting diagram gives the permissible power densities, with and without cycling for specific burn-ups beyond 50,000 MWd/t. The thinnest plates were also irradiated in total in the form of advance assemblies irradiated in the core of the OSIRIS pile prior to its transformation. This transformation and the operation of this reactor with a core of 'Caramel' elements is the main trial experiment of this fuel [fr

  20. General considerations on the oxide fuel-cladding chemical interaction

    International Nuclear Information System (INIS)

    Pascard, R.

    1977-01-01

    Since the very first experimental irradiations in thermal reactors, performed in view of the future Rapsodie fuel general study, corrosion cladding anomalies were observed. After 10 years of Rapsodie and more than two years of Phenix, performance brought definite confirmation of the chemical reactions between the irradiated fuel and cladding. That is the reason for which the fuel designers express an urgent need for determining the corrosion rates. Semi-empirical laws and mechanisms describing corrosion processes are proposed. Erratic conditions for appearance of the oxide-cladding corrosion are stressed upon. Obviously such a problem can be fully appreciated only by a statistical approach based on a large number of observations on the true LMFBR fuel pins

  1. Emission computer tomography on a Dodewaard mixed oxide fuel pin

    International Nuclear Information System (INIS)

    Buurveld, H.A.; Dassel, G.

    1993-12-01

    A nondestructive technique as well as a destructive PIE technique have been used to verify the results obtained with a newly 8-e computer tomography (GECT) system. Multi isotope Scanning (MIS), electron probe micro analysis (EPMA) and GECT were used on a mixed oxide (MOX) fuel rod from the Dodewaard reactor with an average burnup of 24 MWd/kg fuel. GECT shows migration of Cs to the periphery of fuel pellets and to radial cracks and pores in the fuel, whereas MIS shows Cs migration to pellet interfaces. The EPMA technique appeared not to be useful to show migration of Cs but, it shows the distribution of fission products from Pu. EPMA clearly shows the distribution of fission products from Pu, but did not reveal the Cs-migration. (orig./HP)

  2. Thermodynamic Investigation of an Integrated Gasification Plant with Solid Oxide Fuel Cell and Steam Cycles

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2012-01-01

    A gasification plant is integrated on the top of a solid oxide fuel cell (SOFC) cycle, while a steam turbine (ST) cycle is used as a bottoming cycle for the SOFC plant. The gasification plant was fueled by woodchips to produce biogas and the SOFC stacks were fired with biogas. The produced gas...... generator (HRSG). The steam cycle was modeled with a simple single pressure level. In addition, a hybrid recuperator was used to recover more energy from the HRSG and send it back to the SOFC cycle. Thus two different configurations were investigated to study the plants characteristic. Such system...

  3. U.S. Commercial Spent Nuclear Fuel Assembly Characteristics - 1968-2013

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Jianwei [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Peterson, Joshua L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Gauld, Ian C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bowman, Stephen M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-09-01

    Activities related to management of spent nuclear fuel (SNF) are increasing in the US and many other countries. Over 240,000 SNF assemblies have been discharged from US commercial reactors since the late 1960s. The enrichment and burnup of SNF have changed significantly over the past 40 years, and fuel assembly designs have also evolved. Understanding the general characteristics of SNF helps regulators and other stakeholders form overall strategies towards the final disposal of US SNF. This report documents a survey of all US commercial SNF assemblies in the GC-859 database and provides reference SNF source terms (e.g., nuclide inventories, decay heat, and neutron/photon emission) at various cooling times up to 200 years after fuel discharge. This study reviews the distribution and evolution of fuel parameters of all SNF assemblies discharged over the past 40 years. Assemblies were categorized into three groups based on discharge year, and the median burnups and enrichments of each group were used to establish representative cases. An extended burnup case was created for boiling water reactor (BWR) fuels, and another was created for the pressurized water reactor (PWR) fuels. Two additional cases were developed to represent the eight mixed oxide (MOX) fuel assemblies in the database. Burnup calculations were performed for each representative case. Realistic parameters for fuel design and operations were used to model the SNF and to provide reference fuel characteristics representative of the current inventory. Burnup calculations were performed using the ORIGEN code, which is part of the SCALE nuclear modeling and simulation code system. Results include total activity, decay heat, photon emission, neutron flux, gamma heat, and plutonium content, as well as concentrations for 115 significant nuclides. These quantities are important in the design, regulation, and operations of SNF storage, transportation, and disposal systems.

  4. Design and performance of tubular flat-plate solid oxide fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, T.; Ikeda, D.; Kanagawa, H. [NTT Integrated Information & Energy Systems Labs., Tokyo (Japan)] [and others

    1996-12-31

    With the growing interest in conserving the environmental conditions, much attention is being paid to Solid Oxide Fuel Cell (SOFC), which has high energy-conversion efficiency. Many organizations have conducted studies on tubular and flat type SOFCs. Nippon Telegraph and Telephone Corporation (NTT) has studied a combined tubular flat-plate SOFC, and already presented the I-V characteristics of a single cell. Here, we report the construction of a stack of this SOFC cell and successful generation tests results.

  5. Nuclear characteristics of Pu fueled LWR and cross section sensitivities

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, Toshikazu [Osaka Univ., Suita (Japan). Faculty of Engineering

    1998-03-01

    The present status of Pu utilization to thermal reactors in Japan, nuclear characteristics and topics and cross section sensitivities for analysis of Pu fueled thermal reactors are described. As topics we will discuss the spatial self-shielding effect on the Doppler reactivity effect and the cross section sensitivities with the JENDL-3.1 and 3.2 libraries. (author)

  6. Correlations among FBR core characteristics for various fuel compositions

    International Nuclear Information System (INIS)

    Maruyama, Shuhei; Ohki, Shigeo; Okubo, Tsutomu; Kawashima, Katsuyuki; Mizuno, Tomoyasu

    2012-01-01

    In the design of a fast breeder reactor (FBR) core for the light water reactor (LWR) to FBR transition stage, it is indispensable to grasp the effect of a wide range of fuel composition variations on the core characteristics. This study finds good correlations between burnup reactivity and safety parameters, such as the sodium void reactivity and Doppler coefficient, for various fuel compositions and determines the mechanisms behind these correlations with the aid of sensitivity analyses. It is clarified that the Doppler coefficient is actually correlated with the other core characteristics by considering the constraint imposed by the requirement of sustaining criticality on the fuel composition variations. These correlations make it easy to specify the various properties ranges for core reactivity control and core safety, which are important for core design in determining the core specifications and performance. They provide significant information for FBR core design for the transition stage. Moreover, as an application of the above-mentioned correlations, a simplified burnup reactivity index is developed for rapid and rational estimation of the core characteristic variations. With the use of this index and these correlations, the core characteristic variations can be estimated for various fuel compositions without repeating the core calculations. (author)

  7. Synthesis and Characterization of Oxide Feedstock Powders for the Fuel Cycle R and D Program

    International Nuclear Information System (INIS)

    Voit, Stewart L.; Vedder, Raymond James; Johnson, Jared A.

    2010-01-01

    Nuclear fuel feedstock properties, such as physical, chemical, and isotopic characteristics, have a significant impact on the fuel fabrication process and, by extension, the in-reactor fuel performance. This has been demonstrated through studies with UO 2 spanning greater than 50 years. The Fuel Cycle R and D Program with The Department of Energy Office of Nuclear Energy has initiated an effort to develop a better understanding of the relationships between oxide feedstock, fresh fuel properties, and in-reactor fuel performance for advanced mixed oxide compositions. Powder conditioning studies to enable the use of less than ideal powders for ceramic fuel pellet processing are ongoing at Los Alamos National Laboratory (LANL) and an understanding of methods to increase the green density and homogeneity of pressed pellets has been gained for certain powders. Furthermore, Oak Ridge National Laboratory (ORNL) is developing methods for the co-conversion of mixed oxides along with techniques to analyze the degree of mixing. Experience with the fabrication of fuel pellets using co-synthesized multi-constituent materials is limited. In instances where atomically mixed solid solutions of two or more species are needed, traditional ceramic processing methods have been employed. Solution-based processes may be considered viable synthesis options, including co-precipitation (AUPuC), direct precipitation, direct-conversion (Modified Direct Denitration or MDD) and internal/external gelation (sol-gel). Each of these techniques has various advantages and disadvantages. The Fiscal Year 2010 feedstock development work at ORNL focused on the synthesis and characterization of one batch of UO x and one batch of U 80 Ce 20 O x . Oxide material synthesized at ORNL is being shipped to LANL for fuel fabrication process development studies. The feedstock preparation was performed using the MDD process which utilizes a rotary kiln to continuously thermally denitrate double salts of ammonium

  8. Oxidation behaviour and electrical properties of cobalt/cerium oxide composite coatings for solid oxide fuel cell interconnects

    DEFF Research Database (Denmark)

    Harthøj, Anders; Holt, Tobias; Møller, Per

    2015-01-01

    This work evaluates the performance of cobalt/cerium oxide (Co/CeO2) composite coatings and pure Co coatings to be used for solid oxide fuel cell (SOFC) interconnects. The coatings are electroplated on the ferritic stainless steels Crofer 22 APU and Crofer 22H. Coated and uncoated samples...

  9. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Boltax, A [Westinghouse Electric Corporation, Advanced Reactor Division, Madison, PA (United States); Biancheria, A

    1977-04-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  10. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    International Nuclear Information System (INIS)

    Boltax, A.; Biancheria, A.

    1977-01-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  11. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    Energy Technology Data Exchange (ETDEWEB)

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  12. Thermodynamic analysis of SOFC (solid oxide fuel cell)–Stirling hybrid plants using alternative fuels

    International Nuclear Information System (INIS)

    Rokni, Masoud

    2013-01-01

    A novel hybrid power system (∼10 kW) for an average family home is proposed. The system investigated contains a solid oxide fuel cell (SOFC) on top of a Stirling engine. The off-gases produced in the SOFC cycle are fed to a bottoming Stirling engine, at which additional power is generated. Simulations of the proposed system were conducted using different fuels, which should facilitate the use of a variety of fuels depending on availability. Here, the results for natural gas (NG), ammonia, di-methyl ether (DME), methanol and ethanol are presented and analyzed. The system behavior is further investigated by comparing the effects of key factors, such as the utilization factor and the operating conditions under which these fuels are used. Moreover, the effect of using a methanator on the plant efficiency is also studied. The combined system improves the overall electrical efficiency relative to that of a stand-alone Stirling engine or SOFC plant. For the combined SOFC and Stirling configuration, the overall power production was increased by approximately 10% compared to that of a stand-alone SOFC plant. System efficiencies of approximately 60% are achieved, which is remarkable for such small plant sizes. Additionally, heat is also produced to heat the family home when necessary. - Highlights: • Integrating a solid oxide fuel with a Stirling engine • Design of multi-fuel hybrid plants • Plants running on alternative fuels; natural gas, methanol, ethanol, DME and ammonia • Thermodynamic analysis of hybrid SOFC–Stirling engine plants

  13. Solid Oxide Fuel Cells coupled with a biomass gasification unit

    Directory of Open Access Journals (Sweden)

    Skrzypkiewicz Marek

    2016-01-01

    Full Text Available A possibility of fuelling a solid oxide fuel cell stack (SOFC with biomass fuels can be realized by coupling a SOFC system with a self-standing gasification unit. Such a solution enables multi-fuel operation, elasticity of the system as well as the increase of the efficiency of small-scale biomass-to-electricity conversion units. A system of this type, consisting of biomass gasification unit, gas purification unit, SOFC stack, anode off-gas afterburner and peripherals was constructed and operated successfully. During the process, biomass fuel (wood chips was gasified with air as gasification agent. The gasifier was capable of converting up to 30 kW of fuel to syngas with efficiencies up to 75%. Syngas leaving the gasification unit is delivered to a medium temperature adsorber for sulphur compounds removal. Steam is added to the purified fuel to maintain steam to carbon ratio higher than 2. The syngas then is passed to a SOFC stack through a fuel preheater. In such a configuration it was possible to operate a commercial 1.3 kW stack within its working regime. Conducted tests confirmed successful operation of a SOFC stack fuelled by biomass-sourced syngas.

  14. Characteristics of fuel CRUD from Ringhals Unit 4. A comparison of CRUD samples from ultrasonic fuel cleaning and fuel scrape

    International Nuclear Information System (INIS)

    Chen, Jiaxin; Eskhult, Jonas; Marks, Chuck; Dingee, John; Bengtsson, Bernt; Wells, Daniel

    2014-01-01

    The characteristics and behaviour of PWR fuel CRUD are closely related to plant radiation field build-up and the risks of CRUD-Induced Power Shifts (CIPS, previously AOA) and CRUD-Induced Localized Corrosion (CILC). At Ringhals NPP fuel scrape technology has frequently been used to collect fuel CRUD samples as a part of plant water chemistry monitoring programs. In 2012, high efficiency ultrasonic fuel cleaning (HE-UFC) technology was first used at Ringhals Unit 4 to reduce the risk of CIPS, which was expected to increase due to steam generator replacement and a subsequent power uprate. In the HE-UFC system a “first-of-a-kind” CRUD sampling system was installed for collecting fuel CRUD. It is of interest to compare the fuel CRUD samples collected by the two different CRUD sampling methods and to understand if HE-UFC crud sampling could be used to replace or supplement the fuel scrape method. This paper presents some preliminary results on isotopic compositions, elemental compositions, and phase compositions of fuel CRUD samples collected from similar fuel rods and assemblies by both methods during the 2012 refueling outage, one cycle after steam generator replacement at Ringhals Unit 4. The results show that the characteristics of fuel CRUD sampled by HE-UFC and fuel scrape, although not always identical, were similar or correlated to some extent in terms of weight ratios of Ni to Fe and Cr to Fe as well as specific activities of Co-58, Co-60 and Cr-51. However, due to the limited experience with the HE-UFC sampling method, more consideration is required if the statistical significance of the obtained data and indications are to be verified. (author)

  15. Catalytic oxidative desulfurization of liquid hydrocarbon fuels using air

    Science.gov (United States)

    Sundararaman, Ramanathan

    Conventional approaches to oxidative desulfurization of liquid hydrocarbons involve use of high-purity, expensive water soluble peroxide for oxidation of sulfur compounds followed by post-treatment for removal of oxidized sulfones by extraction. Both are associated with higher cost due to handling, storage of oxidants and yield loss with extraction and water separation, making the whole process more expensive. This thesis explores an oxidative desulfurization process using air as an oxidant followed by catalytic decomposition of sulfones thereby eliminating the aforementioned issues. Oxidation of sulfur compounds was realized by a two step process in which peroxides were first generated in-situ by catalytic air oxidation, followed by catalytic oxidation of S compounds using the peroxides generated in-situ completing the two step approach. By this technique it was feasible to oxidize over 90% of sulfur compounds present in real jet (520 ppmw S) and diesel (41 ppmw S) fuels. Screening of bulk and supported CuO based catalysts for peroxide generation using model aromatic compound representing diesel fuel showed that bulk CuO catalyst was more effective in producing peroxides with high yield and selectivity. Testing of three real diesel fuels obtained from different sources for air oxidation over bulk CuO catalyst showed different level of effectiveness for generating peroxides in-situ which was consistent with air oxidation of representative model aromatic compounds. Peroxides generated in-situ was then used as an oxidant to oxidize sulfur compounds present in the fuel over MoO3/SiO2 catalyst. 81% selectivity of peroxides for oxidation of sulfur compounds was observed on MoO3/SiO2 catalyst at 40 °C and under similar conditions MoO3/Al2O3 gave only 41% selectivity. This difference in selectivity might be related to the difference in the nature of active sites of MoO3 on SiO2 and Al2O 3 supports as suggested by H2-TPR and XRD analyses. Testing of supported and bulk Mg

  16. Combustion characteristics of a turbocharged DI compression ignition engine fueled wth petroleum diesel fuels and biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Canakci, M. [Kocaeli University, Izmit (Turkey). Department of Mechanical Education

    2007-04-15

    In this study, the combustion characteristics and emissions of two different petroleum diesel fuels (No. 1 and No. 2) and biodiesel from soybean oil were compared. The tests were performed at steady state conditions in a four-cylinder turbocharged DI diesel engine at full load at 1400-rpm engine speed. The experimental results compared with No. 2 diesel fuel showed that biodiesel provided significant reductions in PM, CO, and unburned HC, the NO{sub x} increased by 11.2%. Biodiesel had a 13.8% increase in brake-specific fuel consumption due to its lower heating value. However, using No. 1 diesel fuel gave better emission results, NO{sub x} and brake-specific fuel consumption reduced by 16.1% and 1.2%, respectively. The values of the principal combustion characteristics of the biodiesel were obtained between two petroleum diesel fuels. The results indicated that biodiesel may be blended with No. 1 diesel fuel to be used without any modification on the engine. (author)

  17. Iron oxide redox chemistry and nuclear fuel disposal

    International Nuclear Information System (INIS)

    Jobe, D.J.; Lemire, R.J.; Taylor, P.

    1997-04-01

    Solubility and stability data for iron (III) oxides and aqueous Fe(II) and Fe(III) species are reviewed, and selected values are used to calculate potential-pH diagrams for the iron system at temperatures of 25 and 100 deg C, chloride activities {C1 - } = 10 -2 and 1 mol/kg, total carbonate activity {C T } = 10 -3 mol/kg, and iron(III) oxide/oxyhydroxide solubility products (25 deg C values) K sp = {Fe 3+ }{OH - } 3 = 10 -38.5 , 10 -40 and 10 -42 . The temperatures and anion concentrations bracket the range of conditions expected in a Canadian nuclear fuel waste disposal vault. The three solubility products represent a conservative upper limit, a most probable value, and a minimum credible value, respectively, for the iron oxides likely to be important in controlling redox conditions in a disposal vault for CANDU nuclear reactor fuel. Only in the first of these three cases do the calculated redox potentials significantly exceed values under which oxidative dissolution of the fuel may occur. (author)

  18. Quality Assurance of Solid Oxide Fuel Cell (SOFC) and Electrolyser (SOEC) Stacks

    DEFF Research Database (Denmark)

    Lang, Michael; Auer, Corinna; Couturier, Karine

    2017-01-01

    In the EU-funded project “Solid oxide cell and stack testing and quality assurance” (SOCTESQA) standardized and industry wide test modules and programs for high temperature solid oxide cells and stacks are being developed. These test procedures can be applied for the fuel cell (SOFC......), the electrolysis (SOEC) and in the combined SOFC/SOEC mode. In order to optimize the test modules the project partners have tested identical SOC stacks with the same test programs in several testing campaigns. Altogether 10 pre-normative test modules were developed: Start-up, current-voltage characteristics...

  19. Light water reactor mixed-oxide fuel irradiation experiment

    International Nuclear Information System (INIS)

    Hodge, S.A.; Cowell, B.S.; Chang, G.S.; Ryskamp, J.M.

    1998-01-01

    The United States Department of Energy Office of Fissile Materials Disposition is sponsoring and Oak Ridge National Laboratory (ORNL) is leading an irradiation experiment to test mixed uranium-plutonium oxide (MOX) fuel made from weapons-grade (WG) plutonium. In this multiyear program, sealed capsules containing MOX fuel pellets fabricated at Los Alamos National Laboratory (LANL) are being irradiated in the Advanced Test Reactor (ATR) at the Idaho National Engineering and Environmental Laboratory (INEEL). The planned experiments will investigate the utilization of dry-processed plutonium, the effects of WG plutonium isotopics on MOX performance, and any material interactions of gallium with Zircaloy cladding

  20. DGMK 729. Application characteristics of fuels with biogenic components

    Energy Technology Data Exchange (ETDEWEB)

    Neulen, Martin; Hoffmann, Hajo [OWI - Oel-Waerme-Institut GmbH, Herzogenrath (Germany)

    2013-06-01

    Using the test rig developed within a project funded by the DGMK (project 729), fuel can be aged semi-realistically in a short time. The test rig was designed to age a fuel within less than 1,000 hours of operation. Another aspect was to investigate the influence of the different aging mechanisms on the fuel, such as light, ambient air, high temperatures and mechanical stress. By defining these parameters and intensifying them, the goal of 1,000 hours of operation has already been achieved in the first test run. A high repeatability and the possibility to vary the parameters of the test runs for all four nearly identical apparatuses are the main characteristics of this test rig. With this test rig it can be tried out how additives react when the fuel ages and how a fuel behaves during its storage. The test runs are supervised by pressure transducer and thermocouples, so that the test rig can be operated unattendedly when started. During the test run every 300 hours of operation fuel samples are taken. These samples are analyzed according to an analysis matrix. Furthermore, the deposits sedimented in the filters or other components can be analyzed. By this, the aging can be understood and monitored. (orig.)

  1. Operation of real landfill gas fueled solid oxide fuel cell (SOFC) using internal dry reforming

    DEFF Research Database (Denmark)

    Langnickel, Hendrik; Hagen, Anke

    2017-01-01

    Biomass is one renewable energy source, which is independent from solar radiation and wind effect. Solid oxide fuel cells (SOFC’s) are able to convert landfill gas derived from landfill directly into electricity and heat with a high efficiency. In the present work a planar 16cm2 SOFC cell...... was necessary to prevent poisoning and thereby to decrease the degradation rate....

  2. Catalyst development and systems analysis of methanol partial oxidation for the fuel processor - fuel cell integration

    Energy Technology Data Exchange (ETDEWEB)

    Newson, E; Mizsey, P; Hottinger, P; Truong, T B; Roth, F von; Schucan, Th H [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Methanol partial oxidation (pox) to produce hydrogen for mobile fuel cell applications has proved initially more successful than hydrocarbon pox. Recent results of catalyst screening and kinetic studies with methanol show that hydrogen production rates have reached 7000 litres/hour/(litre reactor volume) for the dry pox route and 12,000 litres/hour/(litre reactor volume) for wet pox. These rates are equivalent to 21 and 35 kW{sub th}/(litre reactor volume) respectively. The reaction engineering problems remain to be solved for dry pox due to the significant exotherm of the reaction (hot spots of 100-200{sup o}C), but wet pox is essentially isothermal in operation. Analyses of the integrated fuel processor - fuel cell systems show that two routes are available to satisfy the sensitivity of the fuel cell catalysts to carbon monoxide, i.e. a preferential oxidation reactor or a membrane separator. Targets for individual system components are evaluated for the base and best case systems for both routes to reach the combined 40% efficiency required for the integrated fuel processor - fuel cell system. (author) 2 figs., 1 tab., 3 refs.

  3. Safety aspects of LWR fuel reprocessing and mixed oxide fuel fabrication plants

    International Nuclear Information System (INIS)

    Fischer, M.; Leichsenring, C.H.; Herrmann, G.W.; Schueller, W.; Hagenberg, W.; Stoll, W.

    1977-01-01

    The paper is focused on the safety and the control of the consequences of credible accidents in LWR fuel reprocessing plants and in mixed oxide fuel fabrication plants. Each of these plants serve for many power reactor (about 50.000 Mwel) thus the contribution to the overall risk of nuclear energy is correspondingly low. Because of basic functional differences between reprocessing plants, fuel fabrication plants and nuclear power reactors, the structure and safety systems of these plants are different in many respects. The most important differences that influence safety systems are: (1) Both fuel reprocessing and fabrication plants do not have the high system pressure that is associated with power reactors. (2) A considerable amount of the radioactivity of the fuel, which is in the form of short-lived radionuclides has decayed. Therefore, fuel reprocessing plants and mixed oxide fuel fabrication plants are designed with multiple confinement barriers for control of radioactive materials, but do not require the high-pressure containment systems that are used in LWR plants. The consequences of accidents which may lead to the dispersion of radioactive materials such as chemical explosions, nuclear excursions, fires and failure of cooling systems are considered. A reasonable high reliability of the multiple confinement approach can be assured by design. In fuel reprocessing plants, forced cooling is necessary only in systems where fission products are accumulated. However, the control of radioactive materials can be maintained during normal operation and during the above mentioned accidents, if the dissolver off-gas and vessel off-gas treatment systems provide for effective removal of radioactive iodine, radioactive particulates, nitrogen oxides, tritium and krypton 85. In addition, the following incidents in the dissolver off-gas system itself must be controlled: failures of iodine filters, hydrogen explosion in O 2 - and NOsub(x)-reduction component, decomposition of

  4. Lanthanum Manganate Based Cathodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Jørgensen, Mette Juhl

    Composite cathodes for solid oxide fuel cells were investigated using electrochemical impedance spectroscopy and scanning electron microscopy. The aim was to study the oxygen reduction process in the electrode in order to minimise the voltage drop in the cathode. The electrodes contained...... five processes were found to affect the impedance of LSM/YSZ composite electrodes. Two high frequency processes were ascribed to transport of oxide ions/oxygen intermediates across LSM/YSZ interfaces and through YSZ in the composite. Several competitive elementary reaction steps, which appear as one...

  5. Process for the fabrication of nuclear fuel oxide pellets

    International Nuclear Information System (INIS)

    Francois, Bernard; Paradis, Yves.

    1977-01-01

    Process for the fabrication of nuclear fuel oxide pellets of the type for which particles charged with an organic binder -selected from the group that includes polyvinyl alcohol, carboxymethyl cellulose, polyvinyl compounds and methyl cellulose- are prepared from a powder of such an oxide, for instance uranium dioxide. These particles are then compressed into pellets which are then sintered. Under this process the binder charged particles are prepared by stirring the powder with a gas, spraying on to the stirred powder a solution or a suspension in a liquid of this organic binder in order to obtain these particles and then drying the particles so obtained with this gas [fr

  6. Some characteristics of uranium oxides in China

    International Nuclear Information System (INIS)

    Xu, Guoqing; Wang, Aizhen; Gu, Qifang; Zhang, Jingyi; Zhang, Zhaoming; Huang, Yuzhu

    1981-01-01

    According to the analytical data of seventy-seven samples from several tens of uranium ore deposits and occurrences in China, chemical properties, cell dimensions and reflectance of uranium oxides are studied. Chemical properties of uranium oxides from different types of uranium ore deposits and the influence of various mineralization ages and hosts on the compositions of uranium oxides are presented. The influence of these factor such as mineralization temperatures, the compositions of hosts and geochemical background on the compositions of uranium oxides are evident. Lead in proterozoic uranium oxides is relatively enriched by the decay of radio-active elements. Cell dimensions have positive correlation with mineralization ages, formation temperatures and concentration of rare earths and Pb, and negative correlation with the oxidation coefficient. The cell size is an exponential function of the content in CaO. It is suggested that among the factors of influence the most important is the mineralization temperature. The size of ionic radius of elements substituted U 4 + and autooxidation of U 4 + during the process of the decay of radioactive elements are of secondary importance. The reflectance is independent of the content of CaO and SiO 2 . The reflectance is positively correlative with the cell size and negatively correlative with oxidation coefficient. The relation between the reflectance and the content of PbO is logarithmic

  7. Materials for high temperature solid oxide fuel cells

    International Nuclear Information System (INIS)

    Singhal, S.C.

    1987-01-01

    High temperature solid oxide fuel cells show great promise for economical production of electricity. These cells are based upon the ability of stabilized zirconia to operate as an oxygen ion conductor at elevated temperatures. The design of the tubular solid oxide fuel cell being pursued at Westinghouse is illustrated. The cell uses a calcia-stabilized zironcia porous support tube, which acts both as a structural member onto which the other cell components are fabricated in the form of thin layers, and as a functional member to allow the passage, via its porosity, of air (or oxygen) to the air electrode. This paper summarizes the materials and fabrication processes for the various cell components

  8. Passive measurements of mixed-oxide fuel for nuclear nonproliferation

    International Nuclear Information System (INIS)

    Dolan, Jennifer L.; Flaska, Marek; Pozzi, Sara A.; Chichester, David L.

    2013-01-01

    We present new results on passive measurements and simulations of mixed-oxide fuel-pin assemblies. Potential tools for mixed-oxide fuel pin characterization are discussed for future nuclear-nonproliferation applications. Four EJ-309 liquid scintillation detectors coupled with an accurate pulse timing and digital, offline and optimized pulse-shape discrimination method were used. Measurement analysis included pulse-height distributions to distinguish between purely fission neutron sources and alpha-n plus fission neutrons sources. Time-dependent cross-correlation functions were analyzed to measure the fission neutron contribution to the measured sample's neutron source. The use of Monte Carlo particle transport code MCNPX-PoliMi is discussed in conjunction with the measurements

  9. Characteristics of Sr0.92Y0.08Ti1-yNiyO3-δ anode and Ni-infiltrated Sr0.92Y0.08TiO3-δ anode using CH4 fuel in solid oxide fuel cells

    Science.gov (United States)

    Park, Eun Kyoung; Lee, Soonil; Yun, Jeong Woo

    2018-01-01

    Strontium titanium oxide co-doped with yttrium and nickel (SrxY1-xTiyNi1-yO3-δ; hereafter, SYTN), was investigated as an alternative anode material for solid oxide fuel cells. To improve the ionic conductivity of the Sr0.92Y0.08TiO3-δ (SYT) anode, Ni2+ was substituted into the B-site (initially occupied by Ti4+), thereby forming oxygen vacancies. To analyze the effects of Ni-doping in the SYT anode, the electrochemical properties of the SYTN anode were compared with those of the Ni-infiltrated SYT(Ni@SYT) using H2 and CH4 as fuels. The electrochemical reactions at the SYTN anode in the presence of both H2 and CH4 were limited by relatively slow reactions, such as non-charged processes including oxygen surface exchange and solid surface diffusion. The high electrical conductivity and excellent catalytic activity of the Ni nanoparticles in the Ni@SYT anode led to improved cell performance. CH4 decomposition at the Ni@SYT anode occurred via thermal pyrolysis of CH4 rather than by steam methane reforming, resulting in carbon deposition. In comparison, the poor inherent catalytic activity for CH4 oxidation exhibited by the SYTN anode minimized carbon deposition on the anode surface.

  10. Characteristics of sustainable bio-solid fuel produced from sewage sludge as a conventional fuel substitute

    International Nuclear Information System (INIS)

    Jung, Bongjin; Nam, Wonjun; Lee, Na-Yeon; Kim, Kyung-Hoon

    2010-01-01

    Safely final disposal of sewage sludge which is being increased every year has already become serious problems. As one of the promising technologies to solve this problem, thermal drying method has been attracting wide attention due to energy recovery from sewage sludge. This paper describes several characteristics of sustainable bio-solid fuel, as a conventional fuel substitute, produced from sewage sludge drying and granulation plant having the treatment capacity of 10 ton/ day. This plant has been successfully operated many times and is now designing for scale-up. Average moisture content of twelve kinds of bio-solid fuels produced from the plant normally less than 10 wt% and average shape of them is mainly composed of granular type having a diameter of 2-8 mm for easy handling and transportation to the final market destinations. Average higher heating value, which is one of the important properties to estimate the possibility of available energy, of bio-solid fuels is about 3800 kcal/ kg as dry basis. So they can be utilized to supply energy in the coal power plant and cement kiln etc. as a conventional fuel substitute for a beneficial reuse. Characteristics including proximate analysis, ultimate analysis, contents of heavy metals, wettability etc. of bio-solid fuels have been also analyzed for the environmentally safe re utilization. (author)

  11. Characteristics of fuel crud and its impact on storage, handling, and shipment of spent fuel

    International Nuclear Information System (INIS)

    Hazelton, R.F.

    1987-09-01

    Corrosion products, called ''crud,'' form on out-of-reactor surfaces of nuclear reactor systems and are transported by reactor coolant to the core, where they deposit on external fuel-rod cladding surfaces and are activated by nuclear reactions. After discharge of spent fuel from a reactor, spallation of radioactive crud from the fuel rods could impact wet or dry storage operations, handling (including rod consolidation), and shipping. It is the purpose of this report to review earlier (1970s) and more recent (1980s) literature relating to crud, its characteristics, and any impact it has had on actual operations. Crud characteristics vary from reactor type to reactor type, reactor to reactor, fuel assembly to fuel assembly in a reactor, circumferentially and axially in an assembly, and from cycle to cycle for a specific facility. To characterize crud of pressurized-water (PWRs) and boiling-water reactors (BWRs), published information was reviewed on appearance, chemical composition, areal density and thickness, structure, adhesive strength, particle size, and radioactivity. Information was also collected on experience with crud during spent fuel wet storage, rod consolidation, transportation, and dry storage. From experience with wet storage, rod consolidation, transportation, and dry storage, it appears crud spallation can be managed effectively, posing no significant radiological problems. 44 refs., 11 figs

  12. Method to fabricate high performance tubular solid oxide fuel cells

    Science.gov (United States)

    Chen, Fanglin; Yang, Chenghao; Jin, Chao

    2013-06-18

    In accordance with the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes forming an asymmetric porous ceramic tube by using a phase inversion process. The method further includes forming an asymmetric porous ceramic layer on a surface of the asymmetric porous ceramic tube by using a phase inversion process. The tube is co-sintered to form a structure having a first porous layer, a second porous layer, and a dense layer positioned therebetween.

  13. Current status of Westinghouse tubular solid oxide fuel cell program

    Energy Technology Data Exchange (ETDEWEB)

    Parker, W.G. [Westinghouse Science and Technology Center, Pittsburgh, PA (United States)

    1996-04-01

    In the last ten years the solid oxide fuel cell (SOFC) development program at Westinghouse has evolved from a focus on basic material science to the engineering of fully integrated electric power systems. Our endurance for this cell is 5 to 10 years. To date we have successfully operated at power for over six years. For power plants it is our goal to have operated before the end of this decade a MW class power plant. Progress toward these goals is described.

  14. Structural design considerations for micromachined solid-oxide fuel cells

    Science.gov (United States)

    Srikar, V. T.; Turner, Kevin T.; Andrew Ie, Tze Yung; Spearing, S. Mark

    Micromachined solid-oxide fuel cells (μSOFCs) are among a class of devices being investigated for portable power generation. Optimization of the performance and reliability of such devices requires robust, scale-dependent, design methodologies. In this first analysis, we consider the structural design of planar, electrolyte-supported, μSOFCs from the viewpoints of electrochemical performance, mechanical stability and reliability, and thermal behavior. The effect of electrolyte thickness on fuel cell performance is evaluated using a simple analytical model. Design diagrams that account explicitly for thermal and intrinsic residual stresses are presented to identify geometries that are resistant to fracture and buckling. Analysis of energy loss due to in-plane heat conduction highlights the importance of efficient thermal isolation in microscale fuel cell design.

  15. Some alternatives to the mixed oxide fuel cycle

    International Nuclear Information System (INIS)

    Deonigi, D.E.; Eschbach, E.A.; Goldsmith, S.; Pankaskie, P.J.; Rohrmann, C.A.; Widrig, R.D.

    1977-02-01

    While on initial examination each of the six fuel cycle concepts (tandem cycle, extended burnup, fuel rejuvenation, coprocessing, partial reprocessing, and thorium) described in the report may have some potential for improving safeguards, none of the six appears to have any other major or compelling advantages over the mixed oxide (MOX) fuel cycle. Compared to the MOX cycle, all but coprocessing appear to have major disadvantages, including severe cost penalties. Three of the concepts-tandem, extended burnup, and rejuvenation--share the basic problems of the throwaway cycle (GESMO Alternative 6): without reprocessing, high-level waste volumes and costs are substantially increased, and overall uranium utilization decreases for three reasons. First, the parasitic fission products left in the fuel absorb neutrons in later irradiation steps reducing the overall neutronic efficiencies of these cycles. Second, discarded fuel still has sufficient fissile values to warrant recycle. Third, perhaps most important, the plutonium needed for breeder start-up will not be available; without the breeder, uranium utilization would drop by about a factor of sixty. Two of the concepts--coprocessing and partial reprocessing--involve variations of the basic MOX fuel cycle's chemical reprocessing step to make plutonium diversion potentially more difficult. These concepts could be used with the MOX fuel cycle or in conjunction with the tandem, extended burnup and rejuvenation concepts to eliminate some of the problems with those cycles. But in so doing, the basic impetus for those cycles--elimination of reprocessing for safeguards purposes--no longer exists. Of all the concepts considered, only coprocessing--and particularly the ''master blend'' version--appears to have sufficient promise to warrant a more detailed study. The master blend concept could possibly make plutonium diversion more difficult with minimal impact on the reprocessing and MOX fuel fabrication operations

  16. SOLID OXIDE FUEL CELL HYBRID SYSTEM FOR DISTRIBUTED POWER GENERATION

    Energy Technology Data Exchange (ETDEWEB)

    Faress Rahman; Nguyen Minh

    2003-07-01

    This report summarizes the work performed by Hybrid Power Generation Systems, LLC during the January 2003 to June 2003 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a micro-turbine. In addition, an activity included in this program focuses on the development of an integrated coal gasification fuel cell system concept based on planar SOFC technology. This report summarizes the results obtained to date on: System performance analysis and model optimization; Reliability and cost model development; System control including dynamic model development; Heat exchanger material tests and life analysis; Pressurized SOFC evaluation; and Pre-baseline system definition for coal gasification fuel cell system concept.

  17. Influence of the fuel in the nanostructure catalyzer oxides synthesis

    International Nuclear Information System (INIS)

    Zampiva, R.Y.S.; Panta, P.C.; Carlos, R.B.; Alves, A.K.; Bergmann, C.P.

    2012-01-01

    Among the techniques used in catalysts production, the solution combustion synthesis (SCS) has been increasingly applied due the possibility of producing, at low cost, highly pure and homogeneous nanostructured powders. The smaller the particle diameter, the greater the activity of the catalyst. In SCS, the size of the particles produced depends on the process variables. In order to formulate the optimal methodology for the preparation of nanostructured oxides for catalysis, it was studied the fuel-oxidant concentration ratio, and the use of glycine and polyethylene glycol with molecular weight 200 (PEG 200) as fuel in the SCS of Iron, Magnesium and Molybdenum based catalysts. The phase identification of the products was performed by x-ray diffraction (XRD). Particle size and surface area analysis were done to characterize the particles size and the samples morphology was obtained by scanning electron microscopy. Results indicated the formation of high purity nanomaterials obtained for low concentrations of fuel, and a wide variation in the nanostructure sizes depending on the concentration and type of fuel used. (author)

  18. Solid oxide fuel cell having a monolithic core

    International Nuclear Information System (INIS)

    Ackerman, J.P.; Young, J.E.

    1984-01-01

    A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick

  19. Strategies for Lowering Solid Oxide Fuel Cells Operating Temperature

    Directory of Open Access Journals (Sweden)

    Albert Tarancón

    2009-11-01

    Full Text Available Lowering the operating temperature of solid oxide fuel cells (SOFCs to the intermediate range (500–700 ºC has become one of the main SOFC research goals. High operating temperatures put numerous requirements on materials selection and on secondary units, limiting the commercial development of SOFCs. The present review first focuses on the main effects of reducing the operating temperature in terms of materials stability, thermo-mechanical mismatch, thermal management and efficiency. After a brief survey of the state-of-the-art materials for SOFCs, attention is focused on emerging oxide-ionic conductors with high conductivity in the intermediate range of temperatures with an introductory section on materials technology for reducing the electrolyte thickness. Finally, recent advances in cathode materials based on layered mixed ionic-electronic conductors are highlighted because the decreasing temperature converts the cathode into the major source of electrical losses for the whole SOFC system. It is concluded that the introduction of alternative materials that would enable solid oxide fuel cells to operate in the intermediate range of temperatures would have a major impact on the commercialization of fuel cell technology.

  20. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    Energy Technology Data Exchange (ETDEWEB)

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; John Noetzel; Larry Chick

    2003-12-08

    The objective of Phase I under this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from January 1, 2003 to June 30, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; and Task 9 Stack Testing with Coal-Based Reformate.

  1. Burnup performance of rock-like oxide (ROX) fuel in small pebble bed reactor with accumulative fuel loading scheme

    International Nuclear Information System (INIS)

    Simanullang, Irwan Liapto; Obara, Toru

    2017-01-01

    Highlights: • Burnup performance using ROX fuel in PBR with accumulative fuel loading scheme was analyzed. • Initial excess reactivity was suppressed by reducing 235 U enrichment in the startup condition. • Negative temperature coefficient was achieved in all condition of PBR with accumulative fuel loading scheme using ROX fuel. • Core lifetime of PBR with accumulative fuel loading scheme using ROX fuel was shorter than with UO 2 fuel. • In PBR with accumulative fuel loading scheme using ROX fuel, achieved discharged burnup can be as high as that for UO 2 fuel. - Abstract: The Japan Atomic Energy Agency (JAEA) has proposed rock-like oxide (ROX) fuel as a new, once-through type fuel concept. Here, burnup performance using ROX fuel was simulated in a pebble bed reactor with an accumulative fuel loading scheme. The MVP-BURN code was used to simulate the burnup calculation. Fuel of 5 g-HM/pebble with 20% 235 U enrichment was selected as the optimum composition. Discharged burnup could reach up to 218 GWd/t, with a core lifetime of about 8.4 years. However, high excess reactivity occurred in the initial condition. Initial fuel enrichment was therefore reduced from 20% to 4.65% to counter the initial excess reactivity. The operation period was reduced by the decrease of initial fuel enrichment, but the maximum discharged burnup was 198 GWd/t. Burnup performance of ROX fuel in this reactor concept was compared with that of UO 2 fuel obtained previously. Discharged burnup for ROX fuel in the PBR with an accumulative fuel loading scheme was as high as UO 2 fuel. Maximum power density could be lowered by introducing ROX fuel compared to UO 2 fuel. However, PBR core lifetime was shorter with ROX fuel than with UO 2 fuel. A negative temperature coefficient was achieved for both UO 2 and ROX fuels throughout the operation period.

  2. Spent fuel and radioactive waste inventories, projections, and characteristics

    International Nuclear Information System (INIS)

    1983-09-01

    Current inventories and characteristics of commercial spent fuels and both commercial and US Department of Energy radioactive wastes were compiled through December 31, 1982, based on the most reliable information available from government sources and the open literature, technical reports, and direct contacts. Future waste and spent fuel to be generated over the next 40 years and characteristics of these materials are also presented, based on the latest DOE/EIA projection of US commercial nuclear power growth and expected defense-related and industrial and institutional activities. Materials considered, on a chapter-by-chapter bases, are: spent fuel, high-level waste, transuranic waste, low-level waste, active uranium mill tailings, airborne waste, remedial action waste, and decommissioning waste. For each category, current and projected inventories are given through the year 2020, and the radioactivity and thermal power are calculated, based on reported or calculated isotopic compositions. One chapter gives broad, summary data on the costs of spent fuel and radioactive waste management and disposal to provide an economic perspective. This chapter is not intended as a definitive guide, but it is a source of reasonable, order-of-magnitude costs and also provides references to more-detailed and scenario-specific studies. An appendix on generic flowsheets and source terms used for the projections is also included

  3. Spent fuel and radioactive-waste inventories, projections, and characteristics

    International Nuclear Information System (INIS)

    1982-10-01

    Current inventories and characteristics of commercial spent fuels and both commercial and US Department of Energy radioactive wastes were compiled, based on the most reliable information available from government sources and the open literature, technical reports, and direct contacts. Future waste and spent fuel to be generated over the next 40 years, and characteristics of these materials are also presented, based on a present DOE/EIA projection of US commercial nuclear power growth and expected defense-related and industrial and institutional activities. Materials considered, on a chapter-by-chapter basis, are: spent fuel, high-level waste, transuranic waste, low-level waste, remedial action waste, active uranium mill tailings, airborne waste, and decommissioning. For each category, current and projected inventories are given through the year 2020. The land usage requirements are given for storage/disposal of low-level and transuranic wastes, and for the present inventories of inactive uranium mill tailings. For each waste category the radioactivity and thermal power are calculated. Isotopic compositions and cost data are given for each waste type and for spent fuel

  4. Effect of unequal fuel and oxidizer Lewis numbers on flame dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Shamim, Tariq [Department of Mechanical Engineering, The University of Michigan-Dearborn, Dearborn, MI 48128-1491 (United States)

    2006-12-15

    The interaction of non-unity Lewis number (due to preferential diffusion and/or unequal rates of heat and mass transfer) with the coupled effect of radiation, chemistry and unsteadiness alters several characteristics of a flame. The present study numerically investigates this interaction with a particular emphasis on the effect of unequal and non-unity fuel and oxidizer Lewis numbers in a transient diffusion flame. The unsteadiness is simulated by considering the flame subjected to modulations in reactant concentration. Flames with different Lewis numbers (ranging from 0.5 to 2) and subjected to different modulating frequencies are considered. The results show that the coupled effect of Lewis number and unsteadiness strongly influences the flame dynamics. The impact is stronger at high modulating frequencies and strain rates, particularly for large values of Lewis numbers. Compared to the oxidizer side Lewis number, the fuel side Lewis number has greater influence on flame dynamics. (author)

  5. Elementary kinetic modelling applied to solid oxide fuel cell pattern anodes and a direct flame fuel cell system

    Energy Technology Data Exchange (ETDEWEB)

    Vogler, Marcel

    2009-05-27

    In the course of this thesis a model for the prediction of polarisation characteristics of solid oxide fuel cells (SOFC) was developed. The model is based on an elementary kinetic description of electrochemical reactions and the fundamental conservation principles of mass and energy. The model allows to predict the current-voltage relation of an SOFC and offers ideal possibilities for model validation. The aim of this thesis is the identification of rate-limiting processes and the determination of the elementary pathway during charge transfer. The numerical simulation of experiments with model anodes allowed to identify a hydrogen transfer to be the most probable charge-transfer reaction and revealed the influence of diffusive transport. Applying the hydrogen oxidation kinetics to the direct flame fuel cell system (DFFC) showed that electrochemical oxidation of CO is possible based on the same mechanism. Based on the quantification of loss processes in the DFFC system, improvements on cell design, predicting 80% increase of efficiency, were proposed. (orig.)

  6. Electrode Design for Low Temperature Direct-Hydrocarbon Solid Oxide Fuel Cells

    Science.gov (United States)

    Chen, Fanglin (Inventor); Zhao, Fei (Inventor); Liu, Qiang (Inventor)

    2015-01-01

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  7. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    Science.gov (United States)

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  8. Thermal performance of fresh mixed-oxide fuel in a fast flux LMR [liquid metal reactor

    International Nuclear Information System (INIS)

    Ethridge, J.L.; Baker, R.B.

    1985-01-01

    A test was designed and irradiated to provide power-to-melt (heat generation rate necessary to initiate centerline fuel melting) data for fresh mixed-oxide UO 2 -PuO 2 fuel irradiated in a fast neutron flux under prototypic liquid metal reactor (LMR) conditions. The fuel pin parameters were selected to envelope allowable fabrication ranges and address mass production of LMR fuel using sintered-to-size techniques. The test included fuel pins with variations in fabrication technique, pellet density, fuel-to-cladding gap, Pu concentration, and fuel oxygen-to-metal ratios. The resulting data base has reestablished the expected power-to-melt in mixed-oxide fuels during initial reactor startup when the fuel temperatures are expected to be the highest. Calibration of heat transfer models of fuel pin performance codes with these data are providing more accurate capability for predicting steady-state thermal behavior of current and future mixed-oxide LMR fuels

  9. Numerical simulation of mass and energy transport phenomena in solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Arpino, F. [Dipartimento di Meccanica, Strutture, Ambiente e Territorio (DiMSAT), University of Cassino, via Di Biasio 43, Cassino (Italy); Massarotti, N. [Dipertimento per le Tecnologie (DiT), University of Naples ' ' Parthenope' ' , Centro Direzionale, isola C4, 80143 Napoli (Italy)

    2009-12-15

    Solid Oxide Fuel Cells (SOFCs) represent a very promising technology for near future energy conversion thanks to a number of advantages, including the possibility of using different fuels. In this paper, a detailed numerical model, based on a general mathematical description and on a finite element Characteristic based Split (CBS) algorithm code is employed to simulate mass and energy transport phenomena in SOFCs. The model predicts the thermodynamic quantity of interest in the fuel cell. Full details of the numerical solution obtained are presented both in terms of heat and mass transfer in the cell and in terms of electro-chemical reactions that occur in the system considered. The results obtained with the present algorithm is compared with the experimental data available in the literature for validation, showing an excellent agreement. (author)

  10. New methodology of preparation support for solid oxide fuel cells using different pore forming agent

    Energy Technology Data Exchange (ETDEWEB)

    Fiuza, Raigenis da P.; Guedes, Bruna C.F.; Silva, Marcos A. da; Carvalho, Luiz F.V. de; Boaventura, Jaime S. [Universidade Federal da Bahia (IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica; Pontes, Luiz A.M. [Universidade Federal da Bahia (EP/UFBA), Salvador, BA (Brazil). Escola Politecnica. Programa de Pos-Graduacao em Engenharia Quimica

    2008-07-01

    The development of environment-friendly energy sources has been of the most important scientific and technological area. Solid oxide fuel cells (SOFC) are very promising alternative for their ability to handle renewable fuels with low emissions and high efficiency. However, this device requires massive improvement before commercial application. This work studies the pore formation in the cell anode and cathode with NaHCO{sub 3} or citric acid, comparing to graphite. The three agents make pore with similar features, but the use of NaHCO{sub 3} and citric acid considerably improves the adhesion of the electrode-electrolyte interface, critical characteristic for good cell efficiency. The prepared anode-electrolyte-cathode structure was studied by SEM technique. The SOFC prepared using citric acid was tested with gaseous ethanol, natural gas and hydrogen. For all these three fuels the SOFC shows virtually no overpotential, indicating the good ionic conductance of the electrodes-electrolyte interface.. (author)

  11. Fuel cells: spectroscopic studies in the electrocatalysis of alcohol oxidation

    Directory of Open Access Journals (Sweden)

    Iwasita Teresa

    2002-01-01

    Full Text Available Modern spectroscopic methods are useful for elucidating complex electrochemical mechanisms as those occurring during the oxidation of small organic molecules (CH3OH, HCOH, HCOOH. In the present paper it is shown the use of spectroscopic methods to study the oxidation of alcohols on platinum or Pt-based binary electrodes. These reactions are of importance in conexion with the development of anode systems for use in fuel cells. Mass spectrometry and FT infrared spectroscopy allow to establishing the reaction intermediates and products and the dependence of the amount of species on the applied potential. FTIR and scanning tunneling microscopy contribute to understand the effects of the surface structure on the rate of reaction. Examples are presented for methanol and ethanol oxidation at pure and modified Pt catalysts.

  12. Solid oxide fuel cell having a glass composite seal

    Science.gov (United States)

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  13. New Catalysts for Direct Methanol Oxidation Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Adzic, Radoslav

    1998-08-01

    A new class of efficient electrocatalytic materials based on platinum - metal oxide systems has been synthetized and characterized by several techniques. Best activity was found with NiWO{sub 4}-, CoWO{sub 4}-, and RuO{sub 2}- sr¡pported platinum catalysts. A very similar activity at room temperature was observed with the electrodes prepared with the catalyst obtained from International Fuel Cells Inc. for the same Pt loading. Surprisingly, the two tungstates per se show a small activity for methanol oxidation without any Pt loading. Synthesis of NiWO{sub 4} and CoWO{sub 4} were carried out by solid-state reactions. FTIR spectroscopy shows that the tungstates contain a certain amount of physically adsorbed water even after heating samples at 200{degrees}C. A direct relationship between the activity for methanol oxidation and the amount of adsorbed water on those oxides has been found. The Ru(0001) single crystal shows a very small activity for CO adsorption and oxidation, in contrast to the behavior of polycrystalline Ru. In situ extended x-ray absorption fine structure spectroscopy (EXAFS) and x-ray absorption near edge spectroscopy (XANES) showed that the OH adsorption on Ru in the Pt-Ru alloy appears to be the limiting step in methanol oxidation. This does not occur for Pt-RuO{SUB 2} electrocatalyst, which explains its advantages over the Pt-Ru alloys. The IFCC electrocatalyst has the properties of the Pt-Ru alloy.

  14. Thermal imaging of solid oxide fuel cell anode processes

    Energy Technology Data Exchange (ETDEWEB)

    Pomfret, Michael B.; Kidwell, David A.; Owrutsky, Jeffrey C. [Chemistry Division, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Steinhurst, Daniel A. [Nova Research Inc., Alexandria, VA 22308 (United States)

    2010-01-01

    A Si-charge-coupled device (CCD), camera-based, near-infrared imaging system is demonstrated on Ni/yttria-stabilized zirconia (YSZ) fragments and the anodes of working solid oxide fuel cells (SOFCs). NiO reduction to Ni by H{sub 2} and carbon deposition lead to the fragment cooling by 5 {+-} 2 C and 16 {+-} 1 C, respectively. When air is flowed over the fragments, the temperature rises 24 {+-} 1 C as carbon and Ni are oxidized. In an operational SOFC, the decrease in temperature with carbon deposition is only 4.0 {+-} 0.1 C as the process is moderated by the presence of oxides and water. Electrochemical oxidation of carbon deposits results in a {delta}T of +2.2 {+-} 0.2 C, demonstrating that electrochemical oxidation is less vigorous than atmospheric oxidation. While the high temperatures of SOFCs are challenging in many respects, they facilitate thermal imaging because their emission overlaps the spectral response of inexpensive Si-CCD cameras. Using Si-CCD cameras has advantages in terms of cost, resolution, and convenience compared to mid-infrared thermal cameras. High spatial ({proportional_to}0.1 mm) and temperature ({proportional_to}0.1 C) resolutions are achieved in this system. This approach provides a convenient and effective analytical technique for investigating the effects of anode chemistry in operating SOFCs. (author)

  15. Thermal imaging of solid oxide fuel cell anode processes

    Science.gov (United States)

    Pomfret, Michael B.; Steinhurst, Daniel A.; Kidwell, David A.; Owrutsky, Jeffrey C.

    A Si-charge-coupled device (CCD), camera-based, near-infrared imaging system is demonstrated on Ni/yttria-stabilized zirconia (YSZ) fragments and the anodes of working solid oxide fuel cells (SOFCs). NiO reduction to Ni by H 2 and carbon deposition lead to the fragment cooling by 5 ± 2 °C and 16 ± 1 °C, respectively. When air is flowed over the fragments, the temperature rises 24 ± 1 °C as carbon and Ni are oxidized. In an operational SOFC, the decrease in temperature with carbon deposition is only 4.0 ± 0.1 °C as the process is moderated by the presence of oxides and water. Electrochemical oxidation of carbon deposits results in a Δ T of +2.2 ± 0.2 °C, demonstrating that electrochemical oxidation is less vigorous than atmospheric oxidation. While the high temperatures of SOFCs are challenging in many respects, they facilitate thermal imaging because their emission overlaps the spectral response of inexpensive Si-CCD cameras. Using Si-CCD cameras has advantages in terms of cost, resolution, and convenience compared to mid-infrared thermal cameras. High spatial (∼0.1 mm) and temperature (∼0.1 °C) resolutions are achieved in this system. This approach provides a convenient and effective analytical technique for investigating the effects of anode chemistry in operating SOFCs.

  16. Combustion characteristics of the LO2/GCH4 fuel-rich preburners for staged combustion cycle rocket engines

    Science.gov (United States)

    Ono, Fumiei; Tamura, Hiroshi; Sakamoto, Hiroshi; Sasaki, Masaki

    1991-09-01

    The combustion characteristics of Liquid Oxygen (LO2)/Gaseous Methane (GCH4) fuel rich preburners were experimentally studied using subscale hardware. Three types of preburners with coaxial type propellant injection elements were designed and fabricated, and were used for hot fire testing. LO2 was used as oxidizer, and GCH4 at room temperature was used as fuel. The tests were conducted at chamber pressures ranging from 6.7 to 11.9 M Pa, and oxidizer to fuel ratios ranged from 0.16 to 0.42. The test results, which include combustion gas temperature T(sub c), characteristic velocity C(sup *) and soot adhesion data, are presented. The T(sub c) efficiency and the C(sup *) efficiency were found to be a function of oxidizer to fuel ratio and chamber pressure. These efficiencies are correlated by an empirical correlation parameter which accounts for the effects of oxidizer to fuel ratio and chamber pressure. The exhaust plumes were colorless and transparent under all tests conditions. There was some soot adhesion to the chamber wall, but no soot adhesion was observed on the main injector simulator orifices. Higher temperature igniter gas was required to ignite the main propellants of the preburner compared with that of the LO2/Gaseous Hydrogen (GH2) propellants combination.

  17. Thermal gradient effects on the oxidation of Zircaloy fuel cladding

    International Nuclear Information System (INIS)

    Klein, A.C.; Reyes, J.N. Jr.; Maguire, M.A.

    1990-01-01

    A Thermal Gradient Test Facility (TGTF) has been designed and constructed to measure the thermal gradient effect on pressurized water reactor (PWR) fuel rod cladding. The TGTF includes a heat flux simulator assembly capable of producing a wide range of PWR operating conditions including water flow velocities and temperatures, water chemistry conditions, cladding temperatures, and heat fluxes ranging to 160 W/cm 2 . It is fully instrumented including a large number of thermocouples both inside the water flow channel and inside the cladding. Two test programs are in progress. First, cladding specimens are pre-oxidized in air at 500 deg. C and in 400 deg. C steam for various lengths of time to develop a range of uniform oxide thicknesses from 1 to 60 micrometers. The pre-oxidized specimens are placed in the TGTF to characterize the oxide thermal conductivity under a variety of water flow and heat flux conditions. Second, to overcome the long exposure times required under typical PWR conditions a series of tests with the addition of high concentrations of lithium hydroxide to the water are being considered. Static autoclave tests have been conducted with lithium hydroxide concentrations ranging from 0 to 2 moles per liter at 300, 330, and 360 deg. C for up to 36 hours. Results for zircaloy-4 show a considerable increase in the weight gain for the exposed samples with oxidation rate enhancement factors as high as 70 times that of pure water. Operation of the TGTF with elevated lithium hydroxide levels will yield real-time information concerning the effects of a heat flux on the oxidation kinetics of zircaloy fuel rod cladding. (author). 5 refs, 5 figs, 2 tabs

  18. Gas phase deposition of oxide and metal-oxide coatings on fuel particles

    International Nuclear Information System (INIS)

    Patokin, A.P.; Khrebtov, V.L.; Shirokov, B.M.

    2008-01-01

    Production processes and properties of oxide (Al 2 O 3 , ZrO 2 ) and metal-oxide (Mo-Al 2 O 3 , Mo-ZrO 2 , W-Al 2 O 3 , W-ZrO 2 ) coatings on molybdenum substrates and uranium dioxide fuel particles were investigated. It is shown that the main factors that have an effect on the deposition rate, density, microstructure and other properties of coatings are the deposition temperature, the ratio of H 2 and CO 2 flow rates, the total reactor pressure and the ratio of partial pressures of corresponding metal chlorides during formation of metal-oxide coatings

  19. The SLOWPOKE-2 reactor with low enrichment uranium oxide fuel

    International Nuclear Information System (INIS)

    Townes, B.M.; Hilborn, J.W.

    1985-06-01

    A SLOWPOKE-2 reactor core contains less than 1 kg of highly enriched uranium (HEU) and the proliferation risk is very low. However, to overcome proliferation concerns a new low enrichment uranium (LEU) fuelled reactor core has been designed. This core contains approximately 180 fuel elements based on the Zircaloy-4 clad UOsub(2) CANDU fuel element, but with a smaller outside diameter. The physics characteristics of this new reactor core ensure the inherent safety of the reactor under all conceivable conditions and thus the basic SLOWPOKE safety philosophy which permits unattended operation is not affected

  20. The distinguishing characteristics of interlayer oxidation zone and burial ancient ground oxidation zone

    International Nuclear Information System (INIS)

    Zhang Zhanshi; Zhou Wenbin

    1998-01-01

    The author discusses the main characteristics of interlayer oxidation zones and the burial ancient ground oxidation zones of Uranium deposit No. 512 in Xinjiang Uigur municipality. The epigenetic genesis, depending on some aquifer, the tongue-like in section, having the zonation along dip direction and having certain mineral assemblage are the typical features for interlayer oxidation zones

  1. Reversible solid oxide fuel cells (R-SOFCs) with chemically stable proton-conducting oxides

    KAUST Repository

    Bi, Lei

    2015-07-01

    Proton-conducting oxides offer a promising way of lowering the working temperature of solid oxide cells to the intermediate temperate range (500 to 700. °C) due to their better ionic conductivity. In addition, the application of proton-conducting oxides in both solid oxide fuel cells (SOFCs) and sold oxide electrolysis cells (SOECs) provides unique advantages compared with the use of conventional oxygen-ion conducting conductors, including the formation of water at the air electrode site. Since the discovery of proton conduction in some oxides about 30. years ago, the development of proton-conducting oxides in SOFCs and SOECs (the reverse mode of SOFCs) has gained increased attention. This paper briefly summarizes the development in the recent years of R-SOFCs with proton-conducting electrolytes, focusing on discussing the importance of adopting chemically stable materials in both fuel cell and electrolysis modes. The development of electrode materials for proton-conducting R-SOFCs is also discussed. © 2015 Elsevier B.V.

  2. Experimental studies on the combustion characteristics and performance of a direct injection engine fueled with biodiesel/diesel blends

    International Nuclear Information System (INIS)

    Qi, D.H.; Chen, H.; Geng, L.M.; Bian, Y. ZH.

    2010-01-01

    Biodiesel is an alternative diesel fuel that can be produced from different kinds of vegetable oils. It is an oxygenated, non-toxic, sulphur-free, biodegradable, and renewable fuel and can be used in diesel engines without significant modification. However, the performance, emissions and combustion characteristics will be different for the same biodiesel used in different types of engine. In this study, the biodiesel produced from soybean crude oil was prepared by a method of alkaline-catalyzed transesterification. The effects of biodiesel addition to diesel fuel on the performance, emissions and combustion characteristics of a naturally aspirated DI compression ignition engine were examined. Biodiesel has different properties from diesel fuel. A minor increase in brake specific fuel consumption (BSFC) and decrease in brake thermal efficiency (BTE) for biodiesel and its blends were observed compared with diesel fuel. The significant improvement in reduction of carbon monoxide (CO) and smoke were found for biodiesel and its blends at high engine loads. Hydrocarbon (HC) had no evident variation for all tested fuels. Nitrogen oxides (NOx) were slightly higher for biodiesel and its blends. Biodiesel and its blends exhibited similar combustion stages to diesel fuel. The use of transesterified soybean crude oil can be partially substituted for the diesel fuel at most operating conditions in terms of the performance parameters and emissions without any engine modification.

  3. Equipment to weld fuel rods of mixed oxides

    International Nuclear Information System (INIS)

    Aparicio, G.; Orlando, O.S.; Olano, V.R.; Toubes, B.; Munoz, C.A.

    1987-01-01

    Two welding outfits system T1G were designed and constructed to weld fuel rods with mixed oxides pellets (uranium and plutonium). One of them is connected to a glove box where the loading of sheaths takes place. The sheaths are driven to the welder through a removable plug pusher in the welding chamber. This equipment was designed to perform welding tests changing the parameters (gas composition and pressure, welding current, electrode position, etc.). The components of the welder, such as plug holder, chamber closure and peripheral accessories, were designed and constructed taking into account the working pressures in the machine, which is placed in a controlled area and connected to a glove box, where special safety conditions are necessary. The equipment to weld fuel bars is complemented by another machine, located in cold area, of the type presently used in the fuel elements factory. This equipment has been designed to perform some welding operations in sheaths and mixed oxide rods of the type Atucha I and II. Both machines have a programmed power supply of wide range and a vacuum, and pressurizing system that allows the change of parameters. Both systems have special features of handling and operation. (Author)

  4. Oxide fuel pin transient performance analysis and design with the TEMECH code

    International Nuclear Information System (INIS)

    Bard, F.E.; Dutt, S.P.; Hinman, C.A.; Hunter, C.W.; Pitner, A.L.

    1986-01-01

    The TEMECH code is a fast-running, thermal-mechanical-hydraulic, analytical program used to evaluate the transient performance of LMR oxide fuel pins. The code calculates pin deformation and failure probability due to fuel-cladding differential thermal expansion, expansion of fuel upon melting, and fission gas pressurization. The mechanistic fuel model in the code accounts for fuel cracking, crack closure, porosity decrease, and the temperature dependence of fuel creep through the course of the transient. Modeling emphasis has been placed on results obtained from Fuel Cladding Transient Test (FCTT) testing, Transient Fuel Deformation (TFD) tests and TREAT integral fuel pin experiments

  5. Platinum redispersion on metal oxides in low temperature fuel cells.

    Science.gov (United States)

    Tripković, Vladimir; Cerri, Isotta; Nagami, Tetsuo; Bligaard, Thomas; Rossmeisl, Jan

    2013-03-07

    We have analyzed the aptitude of several metal oxide supports (TiO(2), SnO(2), NbO(2), ZrO(2), SiO(2), Ta(2)O(5) and Nb(2)O(5)) to redisperse platinum under electrochemical conditions pertinent to the Proton Exchange Membrane Fuel Cell (PEMFC) cathode. The redispersion on oxide supports in air has been studied in detail; however, due to different operating conditions it is not straightforward to link the chemical and the electrochemical environment. The largest differences reflect in (1) the oxidation state of the surface (the oxygen species coverage), (2) temperature and (3) the possibility of platinum dissolution at high potentials and the interference of redispersion with normal working potential of the PEMFC cathode. We have calculated the PtO(x) (x = 0, 1, 2) adsorption energies on different metal oxides' surface terminations as well as inside the metal oxides' bulk, and we have concluded that NbO(2) might be a good support for platinum redispersion at PEMFC cathodes.

  6. Alternation of Sediment Characteristics during Sediment Microbial Fuel Cells Amended Biochar

    Science.gov (United States)

    Yang, Xunan; Chen, Shanshan

    2018-01-01

    Sediment microbial fuel cells (SMFCs) are considered as a new technology in sediment remediation, while biochars can promote interspecies electron transfer in bioelectrochemical systems. We conducted the SMFCs amended with biochars to investigate their effects on of sediment characteristics. Results showed that the anode of SMFCs could oxidize the chemical oxidizable matter in sediments (by 4%-16%) correlating with the maximum power density (r=0.982, palternations under SMFC operation, which gave information on the element pool related to pollutants and the risk of the application of SMFCs.

  7. Mixed oxide fuel pellet and manufacturing method thereof

    International Nuclear Information System (INIS)

    Yuda, Ryoichi; Ito, Ken-ichi; Masuda, Hiroshi.

    1993-01-01

    In a method of manufacturing nuclear fuel pellets which comprises compression molding a mixed oxide powder containing UO 2 and PuO 2 followed by sintering, a sintering agent having a composition comprising about 40 to 80 wt% of SiO 2 and the balance of Al 2 O 3 is mixed to a mixed oxide at a ratio of about 40ppm to about 0.5 wt% based on the total amount of the mixed oxide and the sintering agent, to prepare a mixture. The mixture is molded into a compression product and then sintered at a weakly acidic atmosphere at a temperature of about 1500degC to 1800degC. With such procedures, the sintering agent forms an eutectic product of a single liquid phase, PuO 2 is dispersed over the entire region of the pellet by way of the liquid phase, formation of a solid solution phase is promoted to annihilate a free PuO 2 phase. Further, growth of crystal grains is promoted. Accordingly, since the MOX fuel pellets prepared according to the present invention have a uniform solid solution state, and no free PuO 2 phase remains, increase of FP gas emission due to local nuclear fission of Pu can be avoided. (T.M.)

  8. Chemical Characterization and Reactivity of Fuel-Oxidizer Reaction Product

    Science.gov (United States)

    David, Dennis D.; Dee, Louis A.; Beeson, Harold D.

    1997-01-01

    Fuel-oxidizer reaction product (FORP), the product of incomplete reaction of monomethylhydrazine and nitrogen tetroxide propellants prepared under laboratory conditions and from firings of Shuttle Reaction Control System thrusters, has been characterized by chemical and thermal analysis. The composition of FORP is variable but falls within a limited range of compositions that depend on three factors: the fuel-oxidizer ratio at the time of formation; whether the composition of the post-formation atmosphere is reducing or oxidizing; and the reaction or post-reaction temperature. A typical composition contains methylhydrazinium nitrate, ammonium nitrate, methylammonium nitrate, and trace amounts of hydrazinium nitrate and 1,1-dimethylhydrazinium nitrate. Thermal decomposition reactions of the FORP compositions used in this study were unremarkable. Neither the various compositions of FORP, the pure major components of FORP, nor mixtures of FORP with propellant system corrosion products showed any unusual thermal activity when decomposed under laboratory conditions. Off-limit thruster operations were simulated by rapid mixing of liquid monomethylhydrazine and liquid nitrogen tetroxide in a confined space. These tests demonstrated that monomethylhydrazine, methylhydrazinium nitrate, ammonium nitrate, or Inconel corrosion products can induce a mixture of monomethylhydrazine and nitrogen tetroxide to produce component-damaging energies. Damaging events required FORP or metal salts to be present at the initial mixing of monomethylhydrazine and nitrogen tetroxide.

  9. Thermal stress analysis of sulfur deactivated solid oxide fuel cells

    Science.gov (United States)

    Zeng, Shumao; Parbey, Joseph; Yu, Guangsen; Xu, Min; Li, Tingshuai; Andersson, Martin

    2018-03-01

    Hydrogen sulfide in fuels can deactivate catalyst for solid oxide fuel cells, which has become one of the most critical challenges to stability. The reactions between sulfur and catalyst will cause phase changes, leading to increase in cell polarization and mechanical mismatch. A three-dimensional computational fluid dynamics (CFD) approach based on the finite element method (FEM) is thus used to investigate the polarization, temperature and thermal stress in a sulfur deactivated SOFC by coupling equations for gas-phase species, heat, momentum, ion and electron transport. The results indicate that sulfur in fuels can strongly affect the cell polarization and thermal stresses, which shows a sharp decrease in the vicinity of electrolyte when 10% nickel in the functional layer is poisoned, but they remain almost unchanged even when the poisoned Ni content was increased to 90%. This investigation is helpful to deeply understand the sulfur poisoning effects and also benefit the material design and optimization of electrode structure to enhance cell performance and lifetimes in various hydrocarbon fuels containing impurities.

  10. Dissolution of mixed oxide spent fuel from FBR

    International Nuclear Information System (INIS)

    Sanyoshi, H.; Nishina, H.; Toyota, O.; Yamamoto, R.; Nemoto, S.; Okamoto, F.; Togashi, A.; Kawata, T.; Hayashi, S.

    1991-01-01

    At the Tokai Works of the Power Reactor and Nuclear Fuel Development Corporation (PNC), the Chemical Processing Facility (CPF) has been continuing operation since 1982 for laboratory scale hot experiments on reprocessing of FBR mixed oxide fuel. As a part of these experiments, dissolution experiments have been performed to define the key parameters affecting dissolution rates such as concentration of nitric acid, temperature and burnup and also to confirm the amount of insoluble residue. The dissolution rate of the irradiated fuel was determined to be in proportion to the 1.7 power of the nitric acid concentration. The activation energy determined from the experiments varied from 6 to 11 kcal/mol depending on the method of dissolution. The dissolution rate decreased as the fuel burnup increased in low nitric acid media below 5 mol/l. However, it was found that the effect of the burnup became negligible in a high concentration of nitric acid media. The amount of insoluble residue and its constituents were evaluated by changing the dissolution condition. (author)

  11. Effects of tunnel oxide process on SONOS flash memory characteristics

    International Nuclear Information System (INIS)

    Li, Dong Hua; Park, Il Han; Yun, Jang-Gn; Park, Byung-Gook

    2010-01-01

    In this paper, various process conditions of tunnel oxides are applied in SONOS flash memory to investigate their effects on charge transport during the program/erase operations. We focus the key point of analysis on Fermi-level (E F ) variation at the interface of silicon substrate and tunnel oxide. The Si-O chemical bonding information which describes the interface oxidation states at the Si/SiO 2 is obtained by the core-level X-ray photoelectron spectroscopy (XPS). Moreover, relative E F position is determined by measuring the Si 2p energy shift from XPS spectrums. Experimental results from memory characteristic measurement show that MTO tunnel oxide structure exhibits faster erase speed, and larger memory window during P/E cycle compared to FTO and RTO tunnel oxide structures. Finally, we examine long-term charge retention characteristic and find that the memory windows of all the capacitors remain wider than 2 V after 10 5 s.

  12. AlliedSignal solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Minh, N.; Barr, K.; Kelly, P.; Montgomery, K. [AlliedSignal Aerospace Equipment Systems, Torrance, CA (United States)

    1996-12-31

    AlliedSignal has been developing high-performance, lightweight solid oxide fuel cell (SOFC) technology for a broad spectrum of electric power generation applications. This technology is well suited for use in a variety of power systems, ranging from commercial cogeneration to military mobile power sources. The AlliedSignal SOFC is based on stacking high-performance thin-electrolyte cells with lightweight metallic interconnect assemblies to form a compact structure. The fuel cell can be operated at reduced temperatures (600{degrees} to 800{degrees}C). SOFC stacks based on this design has the potential of producing 1 kW/kg and 1 ML. This paper summarizes the technical status of the design, manufacture, and operation of AlliedSignal SOFCs.

  13. Planar solid oxide fuel cells: the Australian experience and outlook

    Science.gov (United States)

    Godfrey, Bruce; Föger, Karl; Gillespie, Rohan; Bolden, Roger; Badwal, S. P. S.

    Since 1992, Ceramic Fuel Cells (CFCL) has grown to what is now the largest focussed program globally for development of planar ceramic (solid oxide) fuel cell, SOFC, technology. A significant intellectual property position in know-how and patents has been developed, with over 80 people involved in the venture. Over $A60 million in funding for the activities of the company has been raised from private companies, government-owned corporations and government business-support programs, including from energy — particularly electricity — industry shareholders that can facilitate access to local markets for our products. CFCL has established state-of-the-art facilities for planar SOFC R&D, with their expansion and scaling-up to pilot manufacturing capability underway. We expect to achieve commercial introduction of our market-entry products in 2002, with prototype systems expected to be available from early 2001.

  14. Development of solid oxide fuel cells; Desenvolvimento de celulas a combustivel do tipo oxido solido (SOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Boaventura, Jaime S.; Alencar, Marcelo Goncalves F. de; Amaral, Alexandre Alves do; Benedicto, Joao Paulo Santos; Silva, Marcos A. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica. Dept. de Fisico-Quimica

    2006-07-01

    Fuel cells allow the energy production without the thermodynamic restriction of the conversion of heat into work. Among their various types, the solid oxide fuel cells (SOFC), operating at high temperatures, allow the methane conversion into electricity directly on the anode. The main element of the SOFC is the structure A/E/C: anode/electrolyte/cathode, all sintered at high temperature as resistant ceramic materials. Dense electrolyte (YSZ: zirconia stabilized for Yttria) separates the anode (Ni+Co/YSZ: cobalt promoted nickel, supported on YSZ) and cathode (LSM: strontium-doped lanthanum manganite), both with porosity obtained by graphite addition. To obtain suitable A/E/C pellets, the layer sintering with appropriate mechanical and textural characteristics is essential, requiring excellent electric junctions between them. The cell performance has been evaluated between 850 and 950 degree C, using hydrogen or methane fuel; the tension and current for different resistance values in the electrical circuit have been measured. The cobalt addition to the cell anode significantly increased its activity for the reform reaction. The beneficial effect was probably due to the easier nickel reduction in cobalt presence. This work had the objectives of developing and evaluating electro-catalysts, as well as the solid oxide fuel cells using these catalysts as anode. Five SOFC models (SOFC 1 to SOFC 5) are described; all of them were developed aiming at improving the preparation of the anode/electrolyte/cathode structure (A/E/C). (author)

  15. The PEMFC-integrated CO oxidation — a novel method of simplifying the fuel cell plant

    Science.gov (United States)

    Rohland, Bernd; Plzak, Vojtech

    Natural gas and methanol are the most economical fuels for residential fuel cell power generators as well as for mobile PEM-fuel cells. However, they have to be reformed with steam into hydrogen, which is to be cleaned from CO by shift-reaction and by partial oxidation to a level of no more than 30 ppm CO. This level is set by the Pt/Ru-C-anode of the PEMFC. A higher partial oxidation reaction rate for CO than those of Pt/Ru-C can be achieved in an oxidic Au-catalyst system. In the Fe 2O 3-Au system, a reaction rate of 2·10 -3 mol CO/s g Au at 1000 ppm CO and 5% "air bleed" at 80°C is achieved. This high rate allows to construct a catalyst-sheet for each cell within a PEMFC-stack. Practical and theoretical current/voltage characteristics of PEMFCs with catalyst-sheet are presented at 1000 ppm CO in hydrogen with 5% "air bleed". This gives the possibility of simplifying the gas processor of the plant.

  16. SOLID STATE ENERGY CONVERSION ALLIANCE DELPHI SOLID OXIDE FUEL CELL

    Energy Technology Data Exchange (ETDEWEB)

    Steven Shaffer; Sean Kelly; Subhasish Mukerjee; David Schumann; Gail Geiger; Kevin Keegan; Larry Chick

    2004-05-07

    The objective of this project is to develop a 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. During Phase I, the following will be accomplished: Develop and demonstrate technology transfer efforts on a 5 kW stationary distributed power generation system that incorporates steam reforming of natural gas with the option of piped-in water (Demonstration System A). Initiate development of a 5 kW system for later mass-market automotive auxiliary power unit application, which will incorporate Catalytic Partial Oxidation (CPO) reforming of gasoline, with anode exhaust gas injected into an ultra-lean burn internal combustion engine. This technical progress report covers work performed by Delphi from July 1, 2003 to December 31, 2003, under Department of Energy Cooperative Agreement DE-FC-02NT41246. This report highlights technical results of the work performed under the following tasks: Task 1 System Design and Integration; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant (BOP) Components; Task 5 Manufacturing Development (Privately Funded); Task 6 System Fabrication; Task 7 System Testing; Task 8 Program Management; Task 9 Stack Testing with Coal-Based Reformate; and Task 10 Technology Transfer from SECA CORE Technology Program. In this reporting period, unless otherwise noted Task 6--System Fabrication and Task 7--System Testing will be reported within Task 1 System Design and Integration. Task 8--Program Management, Task 9--Stack Testing with Coal Based Reformate, and Task 10--Technology Transfer from SECA CORE Technology Program will be reported on in the Executive Summary section of this report.

  17. Identification of a Methane Oxidation Intermediate on Solid Oxide Fuel Cell Anode Surfaces with Fourier Transform Infrared Emission.

    Science.gov (United States)

    Pomfret, Michael B; Steinhurst, Daniel A; Owrutsky, Jeffrey C

    2013-04-18

    Fuel interactions on solid oxide fuel cell (SOFC) anodes are studied with in situ Fourier transform infrared emission spectroscopy (FTIRES). SOFCs are operated at 800 °C with CH4 as a representative hydrocarbon fuel. IR signatures of gas-phase oxidation products, CO2(g) and CO(g), are observed while cells are under load. A broad feature at 2295 cm(-1) is assigned to CO2 adsorbed on Ni as a CH4 oxidation intermediate during cell operation and while carbon deposits are electrochemically oxidized after CH4 operation. Electrochemical control provides confirmation of the assignment of adsorbed CO2. FTIRES has been demonstrated as a viable technique for the identification of fuel oxidation intermediates and products in working SOFCs, allowing for the elucidation of the mechanisms of fuel chemistry.

  18. Impedance Modeling of Solid Oxide Fuel Cell Cathodes

    DEFF Research Database (Denmark)

    Mortensen, Jakob Egeberg; Søgaard, Martin; Jacobsen, Torben

    2010-01-01

    A 1-dimensional impedance model for a solid oxide fuel cell cathode is formulated and applied to a cathode consisting of 50/50 wt% strontium doped lanthanum cobaltite and gadolinia doped ceria. A total of 42 impedance spectra were recorded in the temperature range: 555-852°C and in the oxygen...... partial pressure range 0.028-1.00 atm. The recorded impedance spectra were successfully analyzed using the developed impedance model in the investigated temperature and oxygen partial pressure range. It is also demonstrated that the model can be used to predict how impedance spectra evolve with different...

  19. Fabrication of mixed oxide fuel using plutonium from dismantled weapons

    International Nuclear Information System (INIS)

    Blair, H.T.; Chidester, K.; Ramsey, K.B.

    1996-01-01

    A very brief summary is presented of experimental studies performed to support the use of plutonium from dismantled weapons in fabricating mixed oxide (MOX) fuel for commercial power reactors. Thermal treatment tests were performed on plutonium dioxide powder to determine if an effective dry gallium removal process could be devised. Fabrication tests were performed to determine the effects of various processing parameters on pellet quality. Thermal tests results showed that the final gallium content is highly dependent on the treatment temperature. Fabrication tests showed that the milling process, sintering parameters, and uranium feed did effect pellet properties. 1 ref., 1 tab

  20. Validation of KENO, ANISN and Hansen-Roach cross-section set on plutonium oxide and metal fuel system

    International Nuclear Information System (INIS)

    Matsumoto, Tadakuni; Yumoto, Ryozo; Nakano, Koh.

    1980-01-01

    In the previous report, the authors discussed the validity of KENO, ANISN and Hansen-Roach 16 group cross-section set on the critical plutonium nitrate solution systems with various geometries, absorbers and neutron interactions. The purpose of the present report is to examine the validity of the same calculation systems on the homogeneous plutonium oxide and plutonium-uranium mixed oxide fuels with various density values. Eleven experiments adopted for validation are summarized. First six experiments were performed at Pacific Northwest Laboratory of Battelle Memorial Institute, and the remaining five at Los Alamos Scientific Laboratory. The characteristics of core fuel are given, and the isotopic composition of plutonium, the relation between H/(Pu + U) atomic ratio and fuel density as compared with the atomic ratios of PuO 2 and mixed oxides in powder storage and pellet fabrication processes, and critical core dimensions and reflector conditions are shown. The effective multiplication factors were calculated with the KENO code. In case of the metal fuels with simple sphere geometry, additional calculations with the ANISN code were performed. The criticality calculation system composed of KENO, ANISN and Hansen-Roach cross-section set was found to be valid for calculating the criticality on plutonium oxide, plutonium-uranium mixed oxide, plutonium metal and uranium metal fuel systems as well as on plutonium solution systems with various geometries, absorbers and neutron interactions. There seems to remain some problems in the method for evaluating experimental correction. Some discussions foloow. (Wakatsuki, Y.)

  1. Hydrogen peroxide oxidant fuel cell systems for ultra-portable applications

    Science.gov (United States)

    Valdez, T. I.; Narayanan, S. R.

    2001-01-01

    This paper will address the issues of using hydrogen peroxide as an oxidant fuel in a miniature DMFC system. Cell performance for DMFC based fuel cells operating on hydrogen peroxide will be presented and discussed.

  2. Mixed fuel strategy for carbon deposition mitigation in solid oxide fuel cells at intermediate temperatures.

    Science.gov (United States)

    Su, Chao; Chen, Yubo; Wang, Wei; Ran, Ran; Shao, Zongping; Diniz da Costa, João C; Liu, Shaomin

    2014-06-17

    In this study, we propose and experimentally verified that methane and formic acid mixed fuel can be employed to sustain solid oxide fuel cells (SOFCs) to deliver high power outputs at intermediate temperatures and simultaneously reduce the coke formation over the anode catalyst. In this SOFC system, methane itself was one part of the fuel, but it also played as the carrier gas to deliver the formic acid to reach the anode chamber. On the other hand, the products from the thermal decomposition of formic acid helped to reduce the carbon deposition from methane cracking. In order to clarify the reaction pathways for carbon formation and elimination occurring in the anode chamber during the SOFC operation, O2-TPO and SEM analysis were carried out together with the theoretical calculation. Electrochemical tests demonstrated that stable and high power output at an intermediate temperature range was well-maintained with a peak power density of 1061 mW cm(-2) at 750 °C. With the synergic functions provided by the mixed fuel, the SOFC was running for 3 days without any sign of cell performance decay. In sharp contrast, fuelled by pure methane and tested at similar conditions, the SOFC immediately failed after running for only 30 min due to significant carbon deposition. This work opens a new way for SOFC to conquer the annoying problem of carbon deposition just by properly selecting the fuel components to realize their synergic effects.

  3. Multi-metallic anodes for solid oxide fuel cell applications

    International Nuclear Information System (INIS)

    Restivo, T.A. Guisard; Mello-Castanho, S.R.H.; Leite, D. Will

    2009-01-01

    A new method for direct preparation of materials for solid oxide fuel cell anode - Ni- YSZ cermets - based on mechanical alloying (MA) of the original powders is developed, allowing to admix homogeneously any component. Additive metals are selected from thermodynamic criteria, leading to compacts consolidation through sintering by activated surface (SAS). The combined process MA-SSA can reduce the sintering temperature by 300 deg C, yielding porous anodes. Densification mechanisms are discussed from quasi-isothermal sintering kinetics results. Doping with Ag, W, Cu, Mo, Nb, Ta, in descending order, promotes the densification of pellets through liquid phase sintering and evaporation of metals and oxides, which allow reducing the sintering temperature. Powders and pellets characterization by electronic microscopy and X-ray diffraction completes the result analyses. (author)

  4. Failure mechanisms for compacted uranium oxide fuel cores

    International Nuclear Information System (INIS)

    Berghaus, D.G.; Peacock, H.B.

    1980-01-01

    Tension, compression, and shear tests were performed on test specimens of aluminum-clad, compacted powder fuel cores to determine failure mechanisms of the core material. The core, which consists of 70% uranium oxide in an aluminum matrix, frequently fails during post-extrusion drawing. Tests were conducted to various strain levels up to failure of the core. Sections were made of tested specimens to microscopically study initiation of failure. Two failure modes wee observed. Tensile failure mode is initiated by prior tensile failure of uranium oxide particles with the separation path strongly influenced by the arrangement of particles. Delamination mode consists of the separation of laminae formed during extrusion of tubes. Separation proceeds from fine cracks formed parallel to the laminae. Tensile failure mode was experienced in tension and shear tests. Delamination mode was produced in compression tests

  5. Anodes for Solid Oxide Fuel Cells Operating at Low Temperatures

    DEFF Research Database (Denmark)

    Abdul Jabbar, Mohammed Hussain

    An important issue that has limited the potential of Solid Oxide Fuel Cells (SOFCs) for portable applications is its high operating temperatures (800-1000 ºC). Lowering the operating temperature of SOFCs to 400-600 ºC enable a wider material selection, reduced degradation and increased lifetime....... On the other hand, low-temperature operation poses serious challenges to the electrode performance. Effective catalysts, redox stable electrodes with improved microstructures are the prime requisite for the development of efficient SOFC anodes. The performance of Nb-doped SrT iO3 (STN) ceramic anodes...... at 400ºC. The potential of using WO3 ceramic as an alternative anode materials has been explored. The relatively high electrode polarization resistance obtained, 11 Ohm cm2 at 600 ºC, proved the inadequate catalytic activity of this system for hydrogen oxidation. At the end of this thesis...

  6. Fuel rod quenching with oxidation and precursory cooling

    International Nuclear Information System (INIS)

    Davidi, A.; Elias, E.; Olek, S.

    1999-01-01

    During a loss-of-coolant-accident in LWR fuel rods may be temporarily exposed thus reaching high temperature levels. The injection of cold water into the core, while providing the necessary cooling to prevent melting may also generate steam inducing exothermal oxidation of the cladding. A number of high temperature quenching experiments [I] have demonstrated that during the early phase of the quenching process, the rate of hydrogen generation increased markedly and the surface temperatures rose rapidly. These effects are believed to result from thermal stresses breaking up the oxide layer on the zircalloy cladding, thus exposing the inner surface to oxidizing atmosphere. Steam reacts exothermally with the metallic components of the newly formed surface causing temporarily local temperature escalation. The main objective of this study is to develop and assess a one-dimensional time-dependent rewetting model to address the problem of quenching of hot surfaces undergoing exothermic oxidation reactions. Addressing a time-dependent problem is an important aspect of the work since it is believed that the progression of a quench-front along a hot oxidizing surface is an unsteady process. Several studies dealing with time-dependent rewetting problems have been published, e.g. [2]-[5], but none considers oxidation reactions downstream of the quench-front. The main difficulty in solving time-dependent rewetting problems stems from the fact that either the quench-front velocity or the quench-front positions constitute a time-dependent eigenvalue of the problem. The model is applied to describe the interrelated processes of cooling and exothermic steam-metal reactions at the vapor zirconium-cladding interface during quenching of degraded fuel rods. A constant heat transfer coefficient is assumed upstream of the quenching front whereas the combined effect of oxidation and post dry-out cooling is described by prescribing a heat flux distribution of general form downstream. The

  7. Nondestructive characterization of mixed oxide pellets in welded nuclear fuel pins by neutron radiography and gamma-autoradiography

    International Nuclear Information System (INIS)

    Panakkal, J.P.; Ghosh, J.K.; Roy, P.R.

    1989-01-01

    Nondestructive evaluation of nuclear fuel pellets after the welding of fuel pins plays a vital role in assuring a safe and reliable operation of reactors. Some of the important characteristics to be monitored in low plutonium enriched mixed oxide fuel pellets are plutonium enrichment, size of plutonium dioxide agglomerates, incorrect loading and geometric shape. Experiments were carried out at Bhabha Atomic Research Centre, Bombay on experimental fuel pins containing mixed oxide pellets of different geometry (solid and annular), of different plutonium enrichment (0-6 w% of plutonium dioxide) and containing PuO 2 agglomerates of size 125-2000 microns to evaluate these characteristics nondestructively. Neutron radiography of these fuel pins was carried out using a swimming pool type reactor 'APSARA'. Results of quantitative evaluation of the neutron radiographs and a simple model correlating neutron interaction probability and the optical density are presented. Gamma autoradiography of these fuel pins showed that these parameters could be evaluated with a few limitations. This paper presents the experimental details, quantitative analysis of the radiographs by microdensitometry and merits and demerits of neutron radiography and gamma autoradiography for nondestructive charcterisation of nuclear fuel pellets. (orig.)

  8. On the intrinsic transient capability and limitations of solid oxide fuel cell systems

    OpenAIRE

    Mueller, F; Jabbari, F; Brouwer, J

    2009-01-01

    The intrinsic transient performance capability and limitation of integrated solid oxide fuel cell (SOFC) systems is evaluated based on the system balance-of-plant response and fuel cell operating requirements (i.e., allowable deviation from nominal operation). Specifically, non-dimensional relations are derived from conservation principles that quantify the maximum instantaneous current increase that a solid oxide fuel cell system can safely manage based on (1) the desired fuel cell operating...

  9. Bench-scale and full-scale studies of nitric oxides reduction by gaseous fuel reburning

    International Nuclear Information System (INIS)

    Su, S.; Xiang, J.; Sun, L.S.; Hu, S.; Zhu, J.M.

    2008-01-01

    Nitrogen oxides (NOx) emissions from coal-fired boilers are significant contributors to atmospheric pollution. China has specified more rigorous legal limits for NOx emissions from power plants. As a result of the need to reduce NOx emissions, cost-effective NOx reduction strategies must be explored. This paper presented detailed experimental studies on a gaseous fuel reburning process that was performed in a 36 kilowatt bench-scale down-fired furnace to define the optimal reburning operating conditions when different Chinese coals were fired in the furnace. In addition, the combustion system of a 350 megawatt full-scale boiler was retrofitted according to the experimental results. Finally, the gaseous fuel reburning was applied to the retrofitted full-scale boiler. The purpose of the study was to obtain a better understanding of the influence of the key parameters on nitric oxide (NO) reduction efficiency of the reburning process and demonstrate the gaseous fuel reburning on a 350 MWe coal-fired boiler in China. The paper described the experimental procedure with particular reference to the experimental facility and measurement; a schematic diagram of the experimental system; experimental fuels; and characteristics of coals for the reburning experiments. Results that were presented included influence of reburn zone residence time; influence of gaseous reburn fuel per cent; influence of excess air coefficient; and unburned carbon in fly ash. It was concluded that both an above 50 per cent NO reduction efficiency and low carbon loss can be obtained by the gaseous fuel reburning process under the optimal operating conditions. 20 refs., 5 tabs., 10 figs

  10. Physical and decay characteristics of commercial LWR spent fuel

    International Nuclear Information System (INIS)

    Roddy, J.W.; Claiborne, H.C.; Ashline, R.C.; Johnson, P.J.; Rhyne, B.T.

    1986-01-01

    Information was collected from the literature and from major manufacturers that will be useful in the design and construction of a mined geologic repository for the disposal of light-water-reactor spent fuel. Pertinent data are included on mechanical design characteristics and materials of construction for fuel assemblies and fuel rods and computed values for heat generation rates, radioactivity, and photon and neutron emission rates as a function of time for four reference cases. Calculations were made with the ORIGEN2 computer code for burnups of 27,500 and 40,000 MWd for a typical boiling-water reactor and 33,000 and 60,000 MWd for a typical pressurized-water reactor. The results are presented in figures depicting the individual contributions per metric ton of initial heavy metal for the activation products, fission products, and actinides and their daughters to the radioactivity and thermal power as a function of time. Tables are also presented that list the contribution of each major nuclide to the radioactivity, thermal power, and photons and neutrons emitted for disposal emitted for disposal periods from 1 to 100,000 years

  11. Modeling of thermal expansion coefficient of perovskite oxide for solid oxide fuel cell cathode

    Science.gov (United States)

    Heydari, F.; Maghsoudipour, A.; Alizadeh, M.; Khakpour, Z.; Javaheri, M.

    2015-09-01

    Artificial intelligence models have the capacity to eliminate the need for expensive experimental investigation in various areas of manufacturing processes, including the material science. This study investigates the applicability of adaptive neuro-fuzzy inference system (ANFIS) approach for modeling the performance parameters of thermal expansion coefficient (TEC) of perovskite oxide for solid oxide fuel cell cathode. Oxides (Ln = La, Nd, Sm and M = Fe, Ni, Mn) have been prepared and characterized to study the influence of the different cations on TEC. Experimental results have shown TEC decreases favorably with substitution of Nd3+ and Mn3+ ions in the lattice. Structural parameters of compounds have been determined by X-ray diffraction, and field emission scanning electron microscopy has been used for the morphological study. Comparison results indicated that the ANFIS technique could be employed successfully in modeling thermal expansion coefficient of perovskite oxide for solid oxide fuel cell cathode, and considerable savings in terms of cost and time could be obtained by using ANFIS technique.

  12. Fuel characteristics pertinent to the design of aircraft fuel systems, Supplement I : additional information on MIL-F-7914(AER) grade JP-5 fuel and several fuel oils

    Science.gov (United States)

    Barnett, Henry C; Hibbard, Robert R

    1953-01-01

    Since the release of the first NACA publication on fuel characteristics pertinent to the design of aircraft fuel systems (NACA-RM-E53A21), additional information has become available on MIL-F7914(AER) grade JP-5 fuel and several of the current grades of fuel oils. In order to make this information available to fuel-system designers as quickly as possible, the present report has been prepared as a supplement to NACA-RM-E53A21. Although JP-5 fuel is of greater interest in current fuel-system problems than the fuel oils, the available data are not as extensive. It is believed, however, that the limited data on JP-5 are sufficient to indicate the variations in stocks that the designer must consider under a given fuel specification. The methods used in the preparation and extrapolation of data presented in the tables and figures of this supplement are the same as those used in NACA-RM-E53A21.

  13. Performance of planar single cell lanthanum gallate based solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Maffei, N.; Kuriakose, A.K. [Materials Technology Labs., CANMET, Natural Resources Canada, Ottawa, ON (Canada)

    1998-09-01

    A novel synthesis of high purity, single phase strontium-magnesium doped lanthanum gallate through a nitrate route is described. The prepared powder is formed into planar monolithic elements by uniaxial pressing followed by isostatic pressing and sintering. XRD analysis of the sintered elements reveal no detectable secondary phases. The performance of the electrolyte in solid oxide fuel cells (SOFC) with three different anode/cathode combinations tested at 700 C with respect to the J-V and power density is reported. The data show that the characteristics of this SOFC are strongly dependent on the particular anode/cathode system chosen. (orig.)

  14. Performance of planar single cell lanthanum gallate based solid oxide fuel cells

    Science.gov (United States)

    Maffei, N.; Kuriakose, A. K.

    A novel synthesis of high purity, single phase strontium-magnesium doped lanthanum gallate through a nitrate route is described. The prepared powder is formed into planar monolithic elements by uniaxial pressing followed by isostatic pressing and sintering. XRD analysis of the sintered elements reveal no detectable secondary phases. The performance of the electrolyte in solid oxide fuel cells (SOFC) with three different anode/cathode combinations tested at 700°C with respect to the J- V and power density is reported. The data show that the characteristics of this SOFC are strongly dependent on the particular anode/cathode system chosen.

  15. A Neutronic Feasibility Study on the Recycling of an Oxide Fuel in Sodium-Cooled Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Roh, Gyu Hong; Choi, Hang Bok

    2006-06-15

    Neutronic feasibility was implemented for the recycling of a mixed oxide fuel in sodium-cooled fast reactors (SFR) through a thermal/mechanical dry process, which is recognized as one of the most proliferation- resistant recycling processes. In order to assess the applicability of a simple dry process which is not capable of completely removing all the fission products from a spent fuel, sensitivity calculations were performed for the reactor physics parameters with a dependency on the fission product removal rate of the recycled spent fuel. The equilibrium core calculations were performed by the REBUS-3 code for a BN-600 core without blanket fuels and a modified core with an increased fuel volume fraction. The reactor performance parameters such as the transuranic content, breeding ratio, peak linear power, burnup reactivity swing and reactivity coefficients were calculated for an equilibrium core under a fixed fuel management scheme. The results showed that a recycling of the oxide fuel in the SFR is feasible if the fission products are removed by more than 70% through the dry process as far as the material balance is concerned. However the physics analysis also showed that some of the physics design parameters are slightly deteriorated. The results of this study indicate that the recycling characteristics can be improved if the dry process can remove more fission products, and the reactor configuration is further optimized or the spent fuel composition is adjusted.

  16. A Neutronic Feasibility Study on the Recycling of an Oxide Fuel in Sodium-Cooled Fast Reactors

    International Nuclear Information System (INIS)

    Roh, Gyu Hong; Choi, Hang Bok

    2006-06-01

    Neutronic feasibility was implemented for the recycling of a mixed oxide fuel in sodium-cooled fast reactors (SFR) through a thermal/mechanical dry process, which is recognized as one of the most proliferation- resistant recycling processes. In order to assess the applicability of a simple dry process which is not capable of completely removing all the fission products from a spent fuel, sensitivity calculations were performed for the reactor physics parameters with a dependency on the fission product removal rate of the recycled spent fuel. The equilibrium core calculations were performed by the REBUS-3 code for a BN-600 core without blanket fuels and a modified core with an increased fuel volume fraction. The reactor performance parameters such as the transuranic content, breeding ratio, peak linear power, burnup reactivity swing and reactivity coefficients were calculated for an equilibrium core under a fixed fuel management scheme. The results showed that a recycling of the oxide fuel in the SFR is feasible if the fission products are removed by more than 70% through the dry process as far as the material balance is concerned. However the physics analysis also showed that some of the physics design parameters are slightly deteriorated. The results of this study indicate that the recycling characteristics can be improved if the dry process can remove more fission products, and the reactor configuration is further optimized or the spent fuel composition is adjusted

  17. Composite cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells

    International Nuclear Information System (INIS)

    Xia Changrong; Zhang Yuelan; Liu Meilin

    2003-01-01

    Composites consisting of silver and yttria stabilized bismuth oxide (YSB) have been investigated as cathodes for low-temperature honeycomb solid oxide fuel cells with stabilized zirconia as electrolytes. At 600 deg. C, the interfacial polarization resistances of a porous YSB-Ag cathode is about 0.3 Ω cm 2 , more than one order of magnitude smaller than those of other reported cathodes on stabilized zirconia. For example, the interfacial resistances of a traditional YSZ-lanthanum maganites composite cathode is about 11.4 Ω cm 2 at 600 deg. C. Impedance analysis indicated that the performance of an YSB-Ag composite cathode fired at 850 deg. C for 2 h is severely limited by gas transport due to insufficient porosity. The high performance of the YSB-Ag cathodes is very encouraging for developing honeycomb fuel cells to be operated at temperatures below 600 deg. C

  18. A solid oxide fuel cell system for buildings

    International Nuclear Information System (INIS)

    Zink, Florian; Lu, Yixin; Schaefer, Laura

    2007-01-01

    This paper examines an integrated solid oxide fuel cell (SOFC) absorption heating and cooling system used for buildings. The integrated system can provide heating/cooling and/or hot water for buildings while consuming natural gas. The aim of this study is to give an overall description of the system. The possibility of such an integrated system is discussed and the configuration of the system is described. A system model is presented, and a specific case study of the system, which consists of a pre-commercial SOFC system and a commercial LiBr absorption system, is performed. In the case study, the detailed configuration of an integrated system is given, and the heat and mass balance and system performance are obtained through numerical calculation. Based on the case study, some considerations with respect to system component selection, system configuration and design are discussed. Additionally, the economic and environmental issues of this specific system are evaluated briefly. The results show that the combined system demonstrates great advantages in both technical and environmental aspects. With the present development trends in solid oxide fuel cells and the commercial status of absorption heating and cooling systems, it is very likely that such a combined system will become increasingly feasible within the following decade

  19. Thermal characteristics during hydrogen fueling process of type IV cylinder

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Chan [Department of Fire and Disaster Prevention, Kyungil University, 33, Buhori, Hayang, Kyungsan 712-701 (Korea); Lee, Seung Hoon; Yoon, Kee Bong [Department of Mechanical Engineering, Chung Ang University, 221, Huksuk, Dongjak, Seoul 156-756 (Korea)

    2010-07-15

    Temperature increase during hydrogen fueling process is a significant safety concern of a high pressure hydrogen vessel. Hence, thermal characteristics of a Type IV cylinder during hydrogen filling process need to be understood. In this study, a series of experiments were conducted to quantify the temperature change of the cylinder during hydrogen filling to 35 MPa. Computational fluid dynamics (CFD) analysis was also conducted to simulate the conditions of the experiments. The results predicted by the CFD analysis show reasonable agreement with the experiments and the discrepancy between the CFD results and experimental results decrease with higher initial gas pressures. The upper and the lower parts of the vessel showed a temperature difference in the vertical direction. The upper gas temperature was higher than that of the lower part due to the buoyancy effect in the vessel. The maximum gas temperature was higher than the maximum temperature allowed in the ISO safety code (85 C) for the case in which the vessel was pressurized from 0 MPa to 35 MPa. This work contributes to the understanding of the thermal flow characteristics of the hydrogen filling process and notes that additional efforts should be made to guarantee the safety of a type IV cylinder during the hydrogen fueling process. (author)

  20. Basic evaluation on nuclear characteristics of BWR high burnup MOX fuel and core

    International Nuclear Information System (INIS)

    Nagano, M.; Sakurai, S.; Yamaguchi, H.

    1997-01-01

    MOX fuel will be used in existing commercial BWR cores as a part of reload fuels with equivalent operability, safety and economy to UO 2 fuel in Japan. The design concept should be compatible with UO 2 fuel design. High burnup UO 2 fuels are being developed and commercialized step by step. The MOX fuel planned to be introduced in around year 2000 will use the same hardware as UO 2 8 x 8 array fuel developed for a second step of UO 2 high burnup fuel. The target discharge exposure of this MOX fuel is about 33 GWd/t. And the loading fraction of MOX fuel is approximately one-third in an equilibrium core. On the other hand, it becomes necessary to minimize a number of MOX fuels and plants utilizing MOX fuel, mainly due to the fuel economy, handling cost and inspection cost in site. For the above reasons, it needed to developed a high burnup MOX fuel containing much Pu and a core with a large amount of MOX fuels. The purpose of this study is to evaluate basic nuclear fuel and core characteristics of BWR high burnup MOX fuel with batch average exposure of about 39.5 GWd/t using 9 x 9 array fuel. The loading fraction of MOX fuel in the core is within a range of about 50% to 100%. Also the influence of Pu isotopic composition fluctuations and Pu-241 decay upon nuclear characteristics are studied. (author). 3 refs, 5 figs, 3 tabs

  1. On-road emission characteristics of CNG-fueled bi-fuel taxis

    Science.gov (United States)

    Yao, Zhiliang; Cao, Xinyue; Shen, Xianbao; Zhang, Yingzhi; Wang, Xintong; He, Kebin

    2014-09-01

    To alleviate air pollution and lessen the petroleum demand from the motor vehicle sector in China, natural gas vehicles (NGVs) have been rapidly developed over the last several years. However, the understanding of the real-world emissions of NGVs is very limited. In this study, the emissions from 20 compressed-natural-gas-fueled bi-fuel taxis were measured using a portable emission measurement system (PEMS) under actual driving conditions in Yichang, China. The emission characteristics of the tested vehicles were analyzed, revealing that the average CO2, CO, HC and NOx emissions from the tested compressed-natural-gas (CNG) taxis under urban driving conditions were 1.6, 4.0, 2.0 and 0.98 times those under highway road conditions, respectively. The CO, HC and NOx emissions from Euro 3 CNG vehicles were approximately 40%, 55% and 44% lower than those from Euro 2 vehicles, respectively. Compared with the values for light-duty gasoline vehicles reported in the literature, the CO2 and CO emissions from the tested CNG taxis were clearly lower; however, significant increases in the HC and NOx emissions were observed. Finally, we normalized the emissions under the actual driving cycles of the entire test route to the New European Driving Cycle (NEDC)-based emissions using a VSP modes method developed by North Carolina State University. The simulated NEDC-based CO emissions from the tested CNG taxis were better than the corresponding emissions standards, whereas the simulated NEDC-based HC and NOx emissions greatly exceeded the standards. Thus, more attention should be paid to the emissions from CNG vehicles. As for the CNG-fueled bi-fuel taxis currently in use, the department of environmental protection should strengthen their inspection and supervision to reduce the emissions from these vehicles. The results of this study will be helpful in understanding and controlling emissions from CNG-fueled bi-fuel vehicles in China.

  2. Fuel characteristics and trace gases produced through biomass burning

    Directory of Open Access Journals (Sweden)

    BAMBANG HERO SAHARJO

    2010-01-01

    Full Text Available Saharjo BH, Sudo S, Yonemura S, Tsuruta H (2010 Fuel characteristics and trace gases produced through biomass burning. Biodiversitas 11: 40-45. Indonesian 1997/1998 forest fires resulted in forest destruction totally 10 million ha with cost damaged about US$ 10 billion, where more than 1 Gt CO2 has been released during the fire episode and elevating Indonesia to one of the largest polluters of carbon in the world where 22% of world’s carbon dioxide produced. It has been found that 80-90% of the fire comes from estate crops and industrial forest plantation area belongs to the companies which using fire illegally for the land preparation. Because using fire is cheap, easy and quick and also support the companies purpose in achieving yearly planted area target. Forest management and land use practices in Sumatra and Kalimantan have evolved very rapidly over the past three decades. Poor logging practices resulted in large amounts of waste will left in the forest, greatly elevating fire hazard. Failure by the government and concessionaires to protect logged forests and close old logging roads led to and invasion of the forest by agricultural settlers whose land clearances practices increased the risk of fire. Several field experiments had been done in order to know the quality and the quantity of trace produced during biomass burning in peat grass, peat soil and alang-alang grassland located in South Sumatra, Indonesia. Result of research show that different characteristics of fuel burned will have the different level also in trace gasses produced. Peat grass with higher fuel load burned produce more trace gasses compared to alang-alang grassland and peat soil.

  3. Possible effects of UO2 oxidation on light water reactor spent fuel performance in long-term geologic disposal

    International Nuclear Information System (INIS)

    Almassy, M.Y.; Woodley, R.E.

    1982-08-01

    Disposal of spent nuclear fuel in a conventionally mined geologic formation is the nearest-term option for permanently isolating radionuclides from the biosphere. Because irradiated uranium dioxide (UO 2 ) fuel pellets retain 95 to 99% of the radionuclides generated during normal light water reactor operation, they may represent a significant barrier to radionuclide release. This document presents a technical assessment of published literature representing the current level of understanding of spent fuel characteristics and conditions that may degrade pellet integrity during a geologic disposal sequence. A significant deterioration mechanism is spent UO 2 oxidation with possible consequences identified as fission gas release, rod diameter increases, cladding breach extension, and release of solid fuel particles containing radionuclides. Areas requiring further study to support development of a comprehensive spent fuel performance prediction model are highlighted. A program and preliminary schedule to obtain the information needed to develop model correlations are also presented

  4. Influence of injection timing on DI diesel engine characteristics fueled with waste transformer oil

    Directory of Open Access Journals (Sweden)

    S. Prasanna Raj Yadav

    2015-12-01

    Full Text Available This research work targets on the effective utilization of WTO (waste transformer oil in a diesel engine, which would rather reduce environmental problems caused by disposing of it in the open land. The waste transformer oil was compared with the conventional diesel fuel and found that it can also be used as fuel in compression ignition engines since the WTO is also a derivative of crude oil. In this present work, the WTO has been subjected to traditional base-catalyzed trans-esterification process in order to reduce the high viscosity of the WTO which helps to effectively utilize WTO as a fuel in DI diesel engine. The objective of the work is to study the influence of injection timing on the performance, emission and combustion characteristics of a single cylinder, four stroke, direct injection diesel engine using TWTO (trans-esterified waste transformer oil as a fuel. Experiments were performed at four injection timings (23°, 22°, 21°, and 20° bTDC. The results indicate that the retarded injection timing of 20° bTDC resulted in decreased oxides of nitrogen, carbon monoxide and unburned hydrocarbon by 11.57%, 17.24%, and 10% respectively while the brake thermal efficiency and smoke increased under all the load conditions when compared to that of standard injection timing.

  5. Copper based anodes for bio-ethanol fueled low-temperature solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Kondakindi, R.R.; Karan, K. [Queen' s Univ., Kingston, ON (Canada)

    2003-07-01

    Laboratory studies have been conducted to develop a low-temperature solid oxide fuel cell (SOFC) fueled by bio-ethanol. SOFCs are considered to be a potential source for clean and efficient electricity. The use of bio-ethanol to power the SOFC contributes even further to reducing CO{sub 2} emissions. The main barrier towards the development of the proposed SOFC is the identification of a suitable anode catalyst that prevents coking during electro-oxidation of ethanol while yielding good electrical performance. Copper was selected as the catalyst for this study. Composite anodes consisting of copper catalysts and gadolinium-doped ceria (GDC) electrolytes were prepared using screen printing of GDC and copper oxide on dense GDC electrolytes and by wet impregnation of copper nitrate in porous GDC electrolytes followed by calcination and sintering. The electrical conductivity of the prepared anodes was characterized to determine the percolation threshold. Temperature-programmed reduction and the Brunner Emmett Teller (BET) methods were used to quantify the catalyst dispersion and surface area. Electrochemical performance of the single-cell SOFC with a hydrogen-air system was used to assess the catalytic activities. Electrochemical Impedance Spectroscopy was used to probe the electrode kinetics.

  6. The Assessment Of High Temperature Reactor Fuel (Characteristics Of HTTR Fuel)

    International Nuclear Information System (INIS)

    Dewita, Erlan; Tuka, Veronica; Gunandjar

    1996-01-01

    HTTR is one of the reactor type with Helium coolant and outlet coolant temperature of 950 o C. One possibility of HTTR application is the coo generation of steam in high temperature and electric power for supply energy to industry in the future. Considering to the high operating temperature of HTTR, therefore it is needed the reactor fuel which have good mechanical, chemical and physical stability to the high temperature, and stable to the influence of fission fragment and neutron during irradiation. This assessment of the HTTR fuel characteristic based on the experiment data to find information of HTTR operation feasibility. Result of the assessment indicated that fission gas release at burn-up of 3.6 % FIMA which was the same as the maximum burn up in the HTTR design was fairly lower than the maximum release estimated in the design (5 x 10 - 4), which is R/B from the fuel fabricated by the prismatic block fuel method would be low (between 10 - 9 dan 10 - 8)

  7. A review on the engine performance and exhaust emission characteristics of diesel engines fueled with biodiesel blends.

    Science.gov (United States)

    Damanik, Natalina; Ong, Hwai Chyuan; Tong, Chong Wen; Mahlia, Teuku Meurah Indra; Silitonga, Arridina Susan

    2018-06-01

    Biodiesels have gained much popularity because they are cleaner alternative fuels and they can be used directly in diesel engines without modifications. In this paper, a brief review of the key studies pertaining to the engine performance and exhaust emission characteristics of diesel engines fueled with biodiesel blends, exhaust aftertreatment systems, and low-temperature combustion technology is presented. In general, most biodiesel blends result in a significant decrease in carbon monoxide and total unburned hydrocarbon emissions. There is also a decrease in carbon monoxide, nitrogen oxide, and total unburned hydrocarbon emissions while the engine performance increases for diesel engines fueled with biodiesels blended with nano-additives. The development of automotive technologies, such as exhaust gas recirculation systems and low-temperature combustion technology, also improves the thermal efficiency of diesel engines and reduces nitrogen oxide and particulate matter emissions.

  8. Hydrocarbon fuel processing of micro solid oxide fuel cell systems[Dissertation 17455

    Energy Technology Data Exchange (ETDEWEB)

    Stutz, M. J.

    2007-07-01

    The scope of this thesis is the numerical and experimental investigation of the fuel processing of a micro solid oxide fuel cell (SOFC) running on hydrocarbon fuel. The goal is to enhance the overall system efficiency by optimization of the reforming process in the steady state and the improvement of the start-up process. Micro SOFC are a potential alternative to the currently used batteries in portable devices. Liquid butane in a cartridge could be the energy source. This dissertation is focused on the fuel processing of the system, namely the reforming and post-combusting processes. The reformer converts the hydrocarbon fuel to a hydrogen rich gas that can be utilized by the SOFC. The post-combustor depletes the toxic and/or explosive gases before leaving the exhaust. Chapter One presents a short introduction to the field of hydrocarbon fuel processing in micro solid oxide fuel cell systems, the next three chapters deal with computational modeling of the transport phenomena inside a micro-reformer, which leads to a better understanding of the chemistry and the physics therein, hence progress in the design and operation parameters. The experimental part (i.e. Chapter Five) of this thesis focuses on the feasibility of a novel hybrid start-up method of a fuel cell system that employs existing components as an additional heat source. In Chapter Two the effect of wall heat conduction on the syngas (hydrogen and carbon monoxide) production of a micro-reformer, representing micro-fabricated channels or monoliths, is investigated. Methane is used as a model hydrocarbon fuel since its heterogeneous reaction path on rhodium is known and validated. The simulations demonstrate that the axial wall conduction strongly influences the performance of the micro-reformer and should not be neglected without a careful a priori investigation of its impact. Methane conversion and hydrogen yield are strongly dependent of the wall inner surface temperature, which is influenced by the

  9. Evaluation of apatite silicates as solid oxide fuel cell electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Marrero-Lopez, D. [Dpto. de Fisica Aplicada I, Laboratorio de Materiales y Superficies (Unidad Asociada al C.S.I.C.), Universidad de Malaga, 29071 Malaga (Spain); Dpto. de Quimica Inorganica, Universidad de La Laguna, 38200 La Laguna, Tenerife (Spain); Martin-Sedeno, M.C.; Aranda, M.A.G. [Dpto. de Quimica Inorganica, Universidad Malaga, 29071 Malaga (Spain); Pena-Martinez, J. [Dpto. de Quimica Inorganica, Universidad de La Laguna, 38200 La Laguna, Tenerife (Spain); Instituto de Energias Renovables, Parque Tecnologico, Universidad de Castilla La Mancha, 02006 Albacete (Spain); Ruiz-Morales, J.C.; Nunez, P. [Dpto. de Quimica Inorganica, Universidad de La Laguna, 38200 La Laguna, Tenerife (Spain); Ramos-Barrado, J.R. [Dpto. de Fisica Aplicada I, Laboratorio de Materiales y Superficies (Unidad Asociada al C.S.I.C.), Universidad de Malaga, 29071 Malaga (Spain)

    2010-05-01

    Apatite-type silicates have been considered as promising electrolytes for Solid Oxide Fuel Cells (SOFC); however studies on the potential use of these materials in SOFC devices have received relatively little attention. The lanthanum silicate with composition La{sub 10}Si{sub 5.5}Al{sub 0.5}O{sub 26.75} has been evaluated as electrolyte with the electrode materials commonly used in SOFC, i.e. manganite, ferrite and cobaltite as cathode materials and NiO-CGO composite, chromium-manganite and Sr{sub 2}MgMoO{sub 6} as anode materials. Chemical compatibility, area-specific resistance and fuel cell studies have been performed. X-ray powder diffraction (XRPD) analysis did not reveal any trace of reaction products between the apatite electrolyte and most of the aforementioned electrode materials. However, the area-specific polarisation resistance (ASR) of these electrodes in contact with apatite electrolyte increased significantly with the sintering temperature, indicating reactivity at the electrolyte/electrode interface. On the other hand, the ASR values are significantly improved using a ceria buffer layer between the electrolyte and electrode materials to prevent reactivity. Maximum power densities of 195 and 65 mWcm{sup -2} were obtained at 850 and 700 C, respectively in H{sub 2} fuel, using an 1 mm-thick electrolyte, a NiO-Ce{sub 0.8}Gd{sub 0.2}O{sub 1.9} composite as anode and La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} as cathode materials. This fuel cell was tested for 100 h in 5%H{sub 2}-Ar atmosphere showing stable performance. (author)

  10. Conversion of highly enriched uranium in thorium-232 based oxide fuel for light water reactors: MOX-T fuel

    Energy Technology Data Exchange (ETDEWEB)

    Vapirev, E; Jordanov, T; Khristoskov, I [Sofia Univ. (Bulgaria). Fizicheski Fakultet

    1996-12-31

    The possibility of using highly enriched uranium available from military inventories for production of mixed oxide fuel (MOX) has been proposed. The fuel is based on U-235 dioxide as fissile isotope and Th-232 dioxide as a non-fissile isotope. It is shown that although the fuel conversion coefficient to U-233 is expected to be less than 1, the proposed fuel has several important advantages resulting in cost reduction of the nuclear fuel cycle. The expected properties of MOX fuel (cross-sections, generated chains, delayed neutrons) are estimated. Due to fuel generation the initial enrichment is expected to be 1% less for production of the same energy. In contrast to traditional fuel no long living actinides are generated which reduces the disposal and reprocessing cost. 7 refs.

  11. Control loop design and control performance study on direct internal reforming solid oxide fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, H.; Weng, S.; Su, M. [Key Laboratory of Power Machinery and Engineering of the Education Ministry, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2009-10-15

    A solid oxide fuel cell (SOFC) stack is a complicated nonlinear power system. Its system model includes a set of partial differential equations that describe species, mass, momentum and energy conservation, as well as the electrochemical reaction models. The validation and verification of the control system by experiment is very expensive and difficult. Based on the distributed and lumped model of a one-dimensional SOFC, the dynamic performance with different control loops for SOFC is investigated. The simulation result proves that the control system is appropriate and feasible, and can effectively satisfy the requirement of variable load power demand. This simulation model not only can prevent some latent dangers of the fuel cell system but also predict the distributed parameters' characteristics inside the SOFC system. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  12. Concept for a small, colocated fuel cycle facility for oxide breeder fuels

    International Nuclear Information System (INIS)

    Burch, W.D.; Stradley, J.G.; Lerch, R.E.

    1987-01-01

    As part of a United States Department of Energy (USDOE) program to examine innovative liquid-metal reactor (LMR) system designs over the past three years, the Oak Ridge National Laboratory (ORNL) and the Westinghouse Hanford Company (WHC) collaborated on studies of mixed oxide fuel cycle options. A principal effort was an advanced concept for a small integrated fuel cycle colocated with a 1300-MW(e) reactor station. The study provided a scoping design and a basis on which to proceed with implementation of such a facility if future plans so dictate. The facility integrated reprocessing, waste management, and refabrication functions in a single facility of nominal 35-t/year capacity utilizing the latest technology developed in fabrication programs at WHC and in reprocessing at ORNL. The concept was based on many years of work at both sites and extensive design studies of prior years

  13. Concept for a small, colocated fuel cycle facility for oxide breeder fuels

    International Nuclear Information System (INIS)

    Burch, W.D.; Lerch, R.E.; Stradley, J.G.

    1987-01-01

    As part of a United States Department of Energy (USDOE) program to examine innovative liquid-metal reactor (LMR) system designs over the past three years, the Oak Ridge National Laboratory (ORNL) and the Westinghouse Hanford Company (WHC) collaborated on studies of mixed oxide fuel cycle options. A principal effort was an advanced concept for a small integrated fuel cycle colocated with a 1300-MW(e) reactor station. The study provided a scoping design, capital and operating cost estimates, and a basis on which to proceed with implementation of such a facility if future plans so dictate. The facility integrated reprocessing, waste management, and refabrication functions in a single facility of nominal 35-t/year capacity utilizing the latest technology developed in fabrication programs at WHC and in reprocessing at ORNL. The concept was based on many years of work at both sites and extensive design studies of prior years

  14. Characteristics of MOX dissolution with silver mediated electrolytic oxidation method

    Energy Technology Data Exchange (ETDEWEB)

    Umeda, Miki; Nakazaki, Masato; Kida, Takashi; Sato, Kenji; Kato, Tadahito; Kihara, Takehiro; Sugikawa, Susumu [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2003-03-01

    MOX dissolution with silver mediated electrolytic oxidation method is to be applied to the preparation of plutonium nitrate solution to be used for criticality safety experiments at Nuclear Fuel Cycle Safety Engineering Research Facility (NUCEF). Silver mediated electrolytic oxidation method uses the strong oxidisation ability of Ag(II) ion. This method is though to be effective for the dissolution of MOX, which is difficult to be dissolved with nitric acid. In this paper, the results of experiments on dissolution with 100 g of MOX are described. It was confirmed from the results that the MOX powder to be used at NUCEF was completely dissolved by silver mediated electrolytic oxidation method and that Pu(VI) ion in the obtained solution was reduced to tetravalent by means of NO{sub 2} purging. (author)

  15. Characteristics of Subfreezing Operation of Polymer Electrolyte Membrane Fuel Cells

    Science.gov (United States)

    Mishler, Jeffrey Harris

    validated against experimental data. The ice coverage coefficient was shown to be a key variable in matching with experimental data. From model analysis, it appears that the coulombs of charge passed before operation failure is an important parameter characterizing PEM fuel cell cold start. To investigate the coulombs of charge and its determining factors, PEM fuel cells were constructed to measure the effects of membrane configuration (thickness and initial state), catalyst layer configuration (thickness and ionomer-carbon ratio), current density, and temperature on the quantity. It was found that subfreezing temperature, ionomer-catalyst ratio, and catalyst-layer thickness significantly affect the amount of charge transferred before operational failure, whereas the membrane thickness and initial hydration level have limited effect for the considered cases. In addition, degradation of the catalyst layer was observed and quantified. These results improve the fundamental understanding of characteristics of subfreezing operation and thus are valuable for automobile applications of PEM fuel cells. The model directly relates the material properties to voltage loss, and predicts voltage evolution, thus providing a way for material optimization and diagnostics. Additionally, insights into component design and operating conditions can be used to better optimize the fuel cell for cold start-up of the vehicle.

  16. Effect of the structural characteristics of binary Pt-Ru and ternary Pt-Ru-M fuel cell catalysts on the activity of ethanol electrooxidation in acid medium.

    Science.gov (United States)

    Antolini, Ermete

    2013-06-01

    In view of their possible use as anode materials in acid direct ethanol fuel cells, the electrocatalytic activity of Pt-Ru and Pt-Ru-M catalysts for ethanol oxidation has been investigated. This minireview examines the effects of the structural characteristics of Pt-Ru, such as the degree of alloying and Ru oxidation state, on the electrocatalytic activity for ethanol oxidation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Thermodynamic analysis of SOFC (solid oxide fuel cell) - Stirling hybrid plants using alternative fuels

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2013-01-01

    A novel hybrid power system (∼10 kW) for an average family home is proposed. The system investigated contains a solid oxide fuel cell (SOFC) on top of a Stirling engine. The off-gases produced in the SOFC cycle are fed to a bottoming Stirling engine, at which additional power is generated...... to that of a stand-alone Stirling engine or SOFC plant. For the combined SOFC and Stirling configuration, the overall power production was increased by approximately 10% compared to that of a stand-alone SOFC plant. System efficiencies of approximately 60% are achieved, which is remarkable for such small plant sizes...

  18. Effect of coating density on oxidation resistance and Cr vaporization from solid oxide fuel cell interconnects

    Science.gov (United States)

    Talic, Belma; Falk-Windisch, Hannes; Venkatachalam, Vinothini; Hendriksen, Peter Vang; Wiik, Kjell; Lein, Hilde Lea

    2017-06-01

    Manganese cobalt spinel oxides are promising materials for protective coatings for solid oxide fuel cell (SOFC) interconnects. To achieve high density such coatings are often sintered in a two-step procedure, involving heat treatment first in reducing and then in oxidizing atmospheres. Sintering the coating inside the SOFC stack during heating would reduce production costs, but may result in a lower coating density. The importance of coating density is here assessed by characterization of the oxidation kinetics and Cr evaporation of Crofer 22 APU with MnCo1.7Fe0.3O4 spinel coatings of different density. The coating density is shown to have minor influence on the long-term oxidation behavior in air at 800 °C, evaluated over 5000 h. Sintering the spinel coating in air at 900 °C, equivalent to an in-situ heat treatment, leads to an 88% reduction of the Cr evaporation rate of Crofer 22 APU in air-3% H2O at 800 °C. The air sintered spinel coating is initially highly porous, however, densifies with time in interaction with the alloy. A two-step reduction and re-oxidation heat treatment results in a denser coating, which reduces Cr evaporation by 97%.

  19. Designing and optimization of a micro CHP system based on Solid Oxide Fuel Cell with different fuel processing technologies

    DEFF Research Database (Denmark)

    Liso, Vincenzo; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2009-01-01

    are the possibility to partially reform hydrocarbon in the fuel cell anode compartment and the possibility to use high quality heat for cogeneration. In this work, different configurations of solid oxide fuel cell system for decentralized electricity production are examined. The Balance of Plant (BoP) components...

  20. Development of planar solid oxide fuel cells for power generation applications

    Energy Technology Data Exchange (ETDEWEB)

    Minh, N.Q. [AlliedSignal Aerospce Equipment Systems, Torrance, CA (United States)

    1996-04-01

    Planar solid oxide fuel cells (SOFCs) are presently being developed for a variety of electric power generation application. The planar design offers simple cell geometry, high power density, and multiple fabrication and gas manifolding options. Planar SOFC technology has received much attention recently, and significant progress has been made in this area. Recent effort at AlliedSignal has focused on the development of high-performance, lightweight planar SOFCs, having thin-electrolyte films, that can be operated efficiently at reduced temperatures (< 1000{degrees}C). The advantages of reduced-temperature operation include wider material choice (including use of metallic interconnects), expected longer cell life, reduced thermal stress, improved reliability, and reduced fuel cell cost. The key aspect in the development of thin-film SIFCs is to incorporate the thin electrolyte layer into the desired structure of cells in a manner that yields the required characteristics. AlliedSignal has developed a simple and cost-effective method based on tape calendering for the fabrication of thin-electrolyte SOFCs. Thin-electrolyte cells made by tape calendering have shown extraordinary performance, e.g., producing more than 500mW/cm{sup 2} at 700{degrees}C and 800mW/cm{sup 2} at 800{degrees}C with hydrogen as fuel and air is oxidant. thin-electrolyte single cells have been incorporated into a compliant metallic stack structure and operated at reduced and operated at reduced-temperature conditions.

  1. Magnetoviscoelastic characteristics of superparamagnetic oxides (Fe, Ni) based ferrofluids

    Science.gov (United States)

    Katiyar, Ajay; Dhar, Purbarun; Nandi, Tandra; Das, Sarit K.

    2017-08-01

    Ferrofluids have been popular among the academic and scientific communities owing to their intelligent physical characteristics under external stimuli and are in fact among the first nanotechnology products to be employed in real world applications. However, studies on the magnetoviscoelastic behavior of concentrated ferrofluids, especially of superparamagnetic oxides of iron and nickel are rare. The present article comprises the formulation of magneto-colloids utilizing the three various metal oxides nanoparticles viz. Iron (II, III) oxide (Fe3O4), Iron (III) oxide (Fe2O3) and Nickel oxide (NiO) in oil. Iron (II, III) oxide based colloids demonstrate high magnetoviscous characteristics over the other oxides based colloids under external magnetic fields. The maximum magnitude of yield stress and viscosity is found to be 3.0 kPa and 2.9 kPa.s, respectively for iron (II, III) oxide based colloids at 2.6 vol% particle concentration and 1.2 T magnetic field. Experimental investigations reveal that the formulated magneto-nanocolloids are stable, even in high magnetic fields and almost reversible when exposed to rising and drop of magnetic fields of the same magnitude. Observations also reveal that the elastic behavior dominates over the viscous behavior with enhanced relaxation and creep characteristics under the magnetic field. The effect of temperature on viscosity and yield stress of magneto-nanocolloids under magnetic fields has also been discussed. Thus, the present findings have potential applications in various fields such as electromagnetic clutch and brakes of automotive, damping, sealing, optics, nanofinishing etc.

  2. Hydrogen sulfide-powered solid oxide fuel cells

    Science.gov (United States)

    Liu, Man

    2004-12-01

    The potential utilization of hydrogen sulfide as fuel in solid oxide fuel cells has been investigated using an oxide-ion conducting YSZ electrolyte and different kinds of anode catalysts at operating temperatures in the range of 700--900°C and at atmospheric pressure. This technology offers an economically attractive alternative to present methods for removing toxic and corrosive H2S gas from sour gas streams and a promising approach for cogenerating electrical energy and useful chemicals. The primary objective of the present research was to find active and stable anode materials. Fuel cell experimental results showed that platinum was a good electrocatalyst for the conversion of H2S, but the Pt/YSZ interface was physically unstable due to the reversible formation and decomposition of PtS in H 2S streams at elevated temperatures. Moreover, instability of the Pt/YSZ interface was accelerated significantly by electrochemical reactions, and ultimately led to the detachment of the Pt anode from the electrolyte. It has been shown that an interlayer of TiO2 stabilized the Pt anode on YSZ electrolyte, thereby prolonging cell lifetime. However, the current output for a fuel cell using Pt/TiO2 as anode was not improved compared to using Pt alone. It was therefore necessary to investigate novel anode systems for H 2S-air SOFCs. New anode catalysts comprising composite metal sulfides were developed. These catalysts exhibited good electrical conductivity and better catalytic activity than Pt. In contrast to MoS2 alone, composite catalysts (M-Mo-S, M = Fe, Co, Ni) were not volatile and had superior stability. However, when used for extended periods of time, detachment of Pt current collecting film from anodes comprising metal sulfides alone resulted in a large increase in contact resistance and reduction in cell performance. Consequently, a systematic investigation was conducted to identify alternative electronic conductors for use with M-Mo-S catalysts. Anode catalysts

  3. High temperature steam oxidation of Al3Ti-based alloys for the oxidation-resistant surface layer on Zr fuel claddings

    International Nuclear Information System (INIS)

    Park, Jeong-Yong; Kim, Il-Hyun; Jung, Yang-Il; Kim, Hyun-Gil; Park, Dong-Jun; Choi, Byung-Kwon

    2013-01-01

    We investigated the feasibility to apply Al 3 Ti-based alloys as the surface layer for improving the oxidation resistance of Zr fuel claddings under accident conditions. Two types of Al 3 Ti-based alloys with the compositions of Al–25Ti–10Cr and Al–21Ti–23Cr in atomic percent were prepared by arc-melting followed by homogenization annealing at 1423 K for 48 h. Al–25Ti–10Cr alloy showed an L1 2 quasi-single phase microstructure with a lot of needle-shaped minor phase and pores. Al–21Ti–23Cr alloy consisted of an L1 2 matrix and Cr 2 Al as the second phase. Al 3 Ti-based alloys showed an extremely low oxidation rate in a 1473 K steam for up to 7200 s when compared to Zircaloy-4. Both alloys exhibited almost the same oxidation rate in the early stage of oxidation, but Al–25Ti–10Cr showed a little lower oxidation rate after 4000 s than Al–21Ti–23Cr. The difference in the oxidation rate between two types of Al 3 Ti-based alloys was too marginal to distinguish the oxidation behavior of each alloy. The resultant oxide exhibited almost the same characteristics in both alloys even though the microstructure was explicitly distinguished from each other. The crystal structure of the oxide formed up to 2000 s was identified as Al 2 O 3 in both alloys. The oxide morphology consisted of columnar grains whose length was almost identical to the average oxide thickness. On the basis of the results obtained, it is considered that Al 3 Ti-based alloy is one of the promising candidates for the oxidation-resistant surface layer on Zr fuel claddings

  4. PWR and WWER fuel performance. A comparison of major characteristics

    International Nuclear Information System (INIS)

    Weidinger, H.

    2006-01-01

    PWR and WWER fuel technologies have the same basic performance targets: most effective use of the energy stored in the fuel and highest possible reliability. Both fuel technologies use basically the same strategies to reach these targets: 1) Optimized reload strategies; 2) Maximal use of structural material with low neutron cross sections; 3) Decrease the fuel failure frequency towards a 'zero failure' performance by understanding and eliminating the root causes of those defects. The key driving force of the technology of both, PWR and WWER fuel is high burn-up. Presently a range of 45 - 50 MWD/kgU have been reached commercially for PWR and WWER fuel. The main technical limitations to reach high burn-up are typically different for PWR and WWER fuel: for PWR fuel it is the corrosion and hydrogen uptake of the Zr-based materials; for WWER fuel it is the mechanical and dimensional stability of the FA (and the whole core). Corrosion and hydrogen uptake of Zr-materials is a 'non-problem' for WWER fuel. Other performance criteria that are important for high burn-up are the creep and growth behaviour of the Zr materials and the fission gas release in the fuel rod. There exists a good and broad data base to model and design both fuel types. FA and fuel rod vibration appears to be a generic problem for both fuel types but with more evidence for PWR fuel performance reliability. Grid-to-rod fretting is still a major issue in the fuel failure statistics of PWR fuel. Fuel rod cladding defects by debris fretting is no longer a key problem for PWR fuel, while it still appears to be a significant root cause for WWER fuel failures. 'Zero defect' fuel performance is achievable with a high probability, as statistics for US PWR and WWER-1000 fuel has shown

  5. Technical Review of the Characteristics of Spent Nuclear Fuel Scrap

    International Nuclear Information System (INIS)

    Kuhn, William L.; Abrefah, John; Pitner, Allen L.; Damschen, Dennis W.

    2000-01-01

    Spent Nuclear Fuel scrap generated while washing the SNF in Hanford's K-Basins to prepare it for cold vacuum drying differed significantly from that envisioned during project design. Therefore, a technical review panel evaluated the new information about the physical characteristics of scrap generated during processing by characterizing it based on measured weights and digital photographic images. They examined images of the scrap and from them estimated the volume and hence the masses of inert material and of large fragments of spent fuel. The panel estimated the area of these particles directly from images and by fitting a lognormal distribution to the relative number particles in four size ranges and then obtaining the area-to-volume ratio from the distribution. The estimated area is 0.3 m2 for the mass of scrap that could be loaded into a container for drying, which compares to a value of 4.5 m2 assumed for safe operation of the baseline process. The small quantity of scrap genera ted is encouraging. However, the size and mass of the scrap depend both on processes degrading the fuel while in the basin and on processes catching the scrap during washing, the latter including essentially unintentional filtration as debris accumulates. Therefore, the panel concluded that the estimated surface area meets the criterion for loading scrap into an MCO for drying, but because it did not attempt to evaluate the criterion itself, it is not in a position to actually recommend loading the scrap. Further, this is not a sufficiently strong technical position from which to extrapolate the results from the examined scrap to all future scrap generated by the existing process

  6. Storage of LWR spent fuel in air: Volume 1: Design and operation of a spent fuel oxidation test facility

    International Nuclear Information System (INIS)

    Thornhill, C.K.; Campbell, T.K.; Thornhill, R.E.

    1988-12-01

    This report describes the design and operation and technical accomplishments of a spent-fuel oxidation test facility at the Pacific Northwest Laboratory. The objective of the experiments conducted in this facility was to develop a data base for determining spent-fuel dry storage temperature limits by characterizing the oxidation behavior of light-water reactor (LWR) spent fuels in air. These data are needed to support licensing of dry storage in air as an alternative to spent-fuel storage in water pools. They are to be used to develop and validate predictive models of spent-fuel behavior during dry air storage in an Independent Spent Fuel Storage Installation (ISFSI). The present licensed alternative to pool storage of spent fuel is dry storage in an inert gas environment, which is called inerted dry storage (IDS). Licensed air storage, however, would not require monitoring for maintenance of an inert-gas environment (which IDS requires) but does require the development of allowable temperature limits below which UO 2 oxidation in breached fuel rods would not become a problem. Scoping tests at PNL with nonirradiated UO 2 pellets and spent-fuel fragment specimens identified the need for a statistically designed test matrix with test temperatures bounding anticipated maximum acceptable air-storage temperatures. This facility was designed and operated to satisfy that need. 7 refs

  7. Experimental assessment of non-edible candlenut biodiesel and its blend characteristics as diesel engine fuel.

    Science.gov (United States)

    Imdadul, H K; Zulkifli, N W M; Masjuki, H H; Kalam, M A; Kamruzzaman, M; Rashed, M M; Rashedul, H K; Alwi, Azham

    2017-01-01

    Exploring new renewable energy sources as a substitute of petroleum reserves is necessary due to fulfilling the oncoming energy needs for industry and transportation systems. In this quest, a lot of research is going on to expose different kinds of new biodiesel sources. The non-edible oil from candlenut possesses the potential as a feedstock for biodiesel production. The present study aims to produce biodiesel from crude candlenut oil by using two-step transesterification process, and 10%, 20%, and 30% of biodiesel were mixed with diesel fuel as test blends for engine testing. Fourier transform infrared (FTIR) and gas chromatography (GC) were performed and analyzed to characterize the biodiesel. Also, the fuel properties of biodiesel and its blends were measured and compared with the specified standards. The thermal stability of the fuel blends was measured by thermogravimetric analysis (TGA) and differential scan calorimetry (DSC) analysis. Engine characteristics were measured in a Yanmar TF120M single cylinder direct injection (DI) diesel engine. Biodiesel produced from candlenut oil contained 15% free fatty acid (FFA), and two-step esterification and transesterification were used. FTIR and GC remarked the biodiesels' existing functional groups and fatty acid methyl ester (FAME) composition. The thermal analysis of the biodiesel blends certified about the blends' stability regarding thermal degradation, melting and crystallization temperature, oxidative temperature, and storage stability. The brake power (BP), brake specific fuel consumption (BSFC), and brake thermal efficiency (BTE) of the biodiesel blends decreased slightly with an increasing pattern of nitric oxide (NO) emission. However, the hydrocarbon (HC) and carbon monoxides (CO) of biodiesel blends were found decreased.

  8. Optimization of Additive-Powder Characteristics for Metallic Micro-Cell UO{sub 2} Fuel Pellet Fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong-Joo; Kim, Keon Sik; Rhee, Young Woo; Kim, Jong Hun; Oh, Jang Soo; Yang, Jae Ho; Koo, Yang-Hyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    The improvement in the thermal conductivity of the UO{sub 2} fuel pellet can enhance the fuel performance in various aspects. The mobility of the fission gases is reduced by the lower temperature gradient in the UO{sub 2} fuel pellet. That is to say, the capability of the fission gas retention of the fuel pellet can increase. In addition, the lower centerline temperature of the fuel pellet affects the accident tolerance for nuclear fuel as well as the enhancement of fuel safety and fuel pellet integrity under normal operation conditions. The nuclear reactor power can be uprated owing to the higher safety margin. Thus, many researches on enhancing the thermal conductivity of a nuclear fuel pellet for LWRs have been performed. Typically, an enhancement of the thermal conductivity of the UO{sub 2} fuel pellet can be obtained by the addition of a higher thermal conductive material in the fuel pellet. To maximize the effect of the thermal conductivity enhancement, a continuous and uniform channel of the thermal conductive material in the UO{sub 2} matrix must be formed. To enhance the thermal conductivity of a UO{sub 2} fuel pellet, the development of fabrication process of a Cr metallic micro-cell UO{sub 2} pellet with a continuous and uniform channel of the Cr metallic phase was carried out. The formation of the Cr-oxide phases was prevented and the uniformity of the Cr-metal phase distribution was enhanced simultaneously, through the optimization of the additive-powder characteristics. In the results, the Cr metallic micro-cell pellet with continuous and uniform Cr metallic channel could be obtained.

  9. Physical characteristics of non-fuel assembly reactor components

    International Nuclear Information System (INIS)

    Hawkes, E.C.

    1994-09-01

    The primary objective of this report is to enhance the utility of the Characteristics Data Base (CDB). This has been accomplished by providing a pictorial representation of the principal non-fuel assembly (NFA) components along with a tabular summary of key information about each type of component. This report is intended for use as an adjunct to the CDB. Toward this end, the report may be used either as a complement to the detailed descriptions in the CDB, or as a stand-alone document that acts as an illustrated abstract of the CDB. Line drawings of major NFA components are included. Data not provided in the CDB are also included. Summary descriptions of each component are given in tabular format

  10. Oxidation behavior of austenitic stainless steels as fuel cladding candidate materials for SCWR in superheated steam

    International Nuclear Information System (INIS)

    Abe, Hiroshi; Hong, Seung Mo; Watanabe, Yutaka

    2014-01-01

    Highlights: • Effect of cold work on oxidation kinetics was clearly observed for 15Cr–20Ni SS. • The tube-shaped 15Cr–20Ni SS showed very good oxidation resistance. • The machined layer by cold drawing has a significant role to mitigate oxidation. - Abstract: Oxidation behavior of austenitic stainless steels as fuel cladding candidate materials for supercritical-water-cooled reactor (SCWR), including three types of 15Cr–20Ni stainless steels (1520 SSs), in the temperature range of 700–780 °C superheated steam have been investigated. Effect of temperature, dissolved oxygen (DO), degree of cold work (CW), and machined layer by cold drawing process on the oxidation kinetics assuming power-law kinetics are discussed. Characteristics of oxide layers and its relation to oxidation behaviors are also discussed. The effect of DO on the weight gain behavior in superheated steam at 700 °C was minor for all specimens at least up to 200 ppb DO. The tube-shaped specimens of 1520 SSs showed very good oxidation resistance at 700–780 °C. There was no clear difference in the oxidation kinetics among the three investigated types of 1520 SSs. The machined layer formed at the tube surface has a significant role to mitigate oxidation in superheated steam. A fine-grained microstructure near the surface due to recrystallization by cold drawing process is effective to form the protective Cr 2 O 3 layer. It has been suggested that since Cr diffusion in the outside surface of tubes is accelerated as a result of an increased dislocation density and/or grain refinement by cold drawing, tube specimens show very slow oxidation kinetics. Breakdown of the protective Cr 2 O 3 layer and nodule oxide formation were partly observed on the tube-shaped specimens of 15Cr–20Ni SSs. The reliability of Cr 2 O 3 layer has to be carefully examined to predict the oxidation kinetics after long-term exposure

  11. Oxidation behavior of austenitic stainless steels as fuel cladding candidate materials for SCWR in superheated steam

    Energy Technology Data Exchange (ETDEWEB)

    Abe, Hiroshi, E-mail: hiroshi.abe@qse.tohoku.ac.jp; Hong, Seung Mo; Watanabe, Yutaka

    2014-12-15

    Highlights: • Effect of cold work on oxidation kinetics was clearly observed for 15Cr–20Ni SS. • The tube-shaped 15Cr–20Ni SS showed very good oxidation resistance. • The machined layer by cold drawing has a significant role to mitigate oxidation. - Abstract: Oxidation behavior of austenitic stainless steels as fuel cladding candidate materials for supercritical-water-cooled reactor (SCWR), including three types of 15Cr–20Ni stainless steels (1520 SSs), in the temperature range of 700–780 °C superheated steam have been investigated. Effect of temperature, dissolved oxygen (DO), degree of cold work (CW), and machined layer by cold drawing process on the oxidation kinetics assuming power-law kinetics are discussed. Characteristics of oxide layers and its relation to oxidation behaviors are also discussed. The effect of DO on the weight gain behavior in superheated steam at 700 °C was minor for all specimens at least up to 200 ppb DO. The tube-shaped specimens of 1520 SSs showed very good oxidation resistance at 700–780 °C. There was no clear difference in the oxidation kinetics among the three investigated types of 1520 SSs. The machined layer formed at the tube surface has a significant role to mitigate oxidation in superheated steam. A fine-grained microstructure near the surface due to recrystallization by cold drawing process is effective to form the protective Cr{sub 2}O{sub 3} layer. It has been suggested that since Cr diffusion in the outside surface of tubes is accelerated as a result of an increased dislocation density and/or grain refinement by cold drawing, tube specimens show very slow oxidation kinetics. Breakdown of the protective Cr{sub 2}O{sub 3} layer and nodule oxide formation were partly observed on the tube-shaped specimens of 15Cr–20Ni SSs. The reliability of Cr{sub 2}O{sub 3} layer has to be carefully examined to predict the oxidation kinetics after long-term exposure.

  12. Synthesis and characterization of magnesium doped cerium oxide for the fuel cell application

    International Nuclear Information System (INIS)

    Kumar, Amit; Kumari, Monika; Kumar, Mintu; Kumar, Sacheen; Kumar, Dinesh

    2016-01-01

    Cerium oxide has attained much attentions in global nanotechnology market due to valuable application for catalytic, fuel additive, and widely as electrolyte in solid oxide fuel cell. Doped cerium oxide has large oxygen vacancies that allow for greater reactivity and faster ion transport. These properties make cerium oxide suitable material for SOFCs application. Cerium oxide electrolyte requires lower operation temperature which shows improvement in processing and the fabrication technique. In our work, we synthesized magnesium doped cerium oxide by the co-precipitation method. With the magnesium doping catalytic reactivity of CeO_2 was increased. Synthesized nanoparticle were characterized by the XRD and UV absorption techniques.

  13. Neutronic study using oxide and nitride fuels for the Super Phenix 2 reactor

    International Nuclear Information System (INIS)

    Batista, J.L.; Renke, C.A.C.

    1991-11-01

    This report presents a neutronic analysis and a description of the Super Phenix 2 reactor, taken as reference. We present the methodology and results for cell and global reactor calculations for oxide (U O 2 - Pu O 2 ) and nitride (U N - Pu N) fuels. To conclude we compare the performance of oxide and nitride fuels for the reference reactor. (author)

  14. Modern methods of material accounting for mixed oxide fuel fabrication facility

    International Nuclear Information System (INIS)

    Eggers, R.F.; Pindak, J.L.; Brouns, R.J.; Williams, R.C.; Brite, D.W.; Kinnison, R.R.; Fager, J.E.

    1981-01-01

    The generic requirements loss detection, and response to alarms of a contemporary material control and accounting (MCandA) philosophy have been applied to a mixed oxide fuel fabrication plant to produce a detailed preliminary MCandA system design that is generally applicable to facilities of this type. This paper summarizes and discusses detailed results of the mixed oxide fuel fabrication plant study

  15. Hydrogen Oxidation Reaction at the Ni/YSZ Anode of Solid Oxide Fuel Cells from First Principles

    Science.gov (United States)

    Cucinotta, Clotilde S.; Bernasconi, Marco; Parrinello, Michele

    2011-11-01

    By means of ab initio simulations we here provide a comprehensive scenario for hydrogen oxidation reactions at the Ni/zirconia anode of solid oxide fuel cells. The simulations have also revealed that in the presence of water chemisorbed at the oxide surface, the active region for H oxidation actually extends beyond the metal/zirconia interface unraveling the role of water partial pressure in the decrease of the polarization resistance observed experimentally.

  16. Cathodes for Solid Oxide Fuel Cells Operating at Low Temperatures

    DEFF Research Database (Denmark)

    Samson, Alfred Junio

    . High performance cathodes were obtained from strontium-doped lanthanum cobaltite (LSC) infiltrated - Ce0.9Gd0.1O1.95 (CGO) ionic conducting backbone. Systematic tuning of the CGO and LSC firing temperatures and LSC loading resulted in a cathode with low polarization resistance, Rp = 0.044 cm2 at 600......This dissertation focuses on the development of nanostructured cathodes for solid oxide fuel cells (SOFCs) and their performance at low operating temperatures. Cathodes were mainly fabricated by the infiltration method, whereby electrocatalysts are introduced onto porous, ionic conducting backbones...... with increasing LSC firing temperature, highlighting the importance of materials compability over higher ionic conductivity. The potential of Ca3Co4O9+delta as an electrocatalyst for SOFCs has also been explored and encouraging results were found i.e., Rp = 0.64 cm2 for a Ca3Co4O9+delta/CGO 50 vol % composite...

  17. Decommissioning of a mixed oxide fuel fabrication facility

    International Nuclear Information System (INIS)

    Buck, S.; Colquhoun, A.

    1990-01-01

    Decommissioning of the coprecipitation plant, which made plutonium/uranium oxide fuel, is a lead project in the BNFL Sellafield decommissioning programme. The overall programme has the objectives of gaining data and experience in a wide range of decommissioning operations and hence in this specific project to pilot the decommissioning of plant heavily contaminated with plutonium and other actinides. Consequently the operations have been used to test improvements in temporary containment, contamination control and decontamination methods and also to develop in situ plutonium assay, plutonium recovery and size-reduction methods. Finally the project is also yielding data on manpower requirements, personnel radiation uptake and waste arisings to help in the planning of future decommissioning projects

  18. Role of thermal analysis in uranium oxide fuel fabrication process

    International Nuclear Information System (INIS)

    Balaji Rao, Y.; Yadav, R.B.

    2006-01-01

    The present paper discusses the application of thermal analysis, particularly, differential thermal analysis (Dta) at various stages of fuel fabrication process. The useful role of Dta in knowing the decomposition pattern and calcination temperature of Adu along with de-nitration temperature is explained. The decomposition pattern depends upon the type of drying process adopted for wet ADU cake (ADU C). Also, the paper highlights the utility of DTA in determining the APS and SSA of UO 2+x and U 3 O 8 powders as an alternate technique. Further, the temperature difference (ΔT max ) between the two exothermic peaks obtained in UO 2+x powder oxidation is related to sintered density of UO 2 pellets. (author)

  19. Measurement and analysis of transient vaporization in oxide fuel materials

    International Nuclear Information System (INIS)

    Benson, D.A.; Bergeron, E.G.

    1979-01-01

    This paper describes a series of experiments in which samples are heated to produce high vapor pressure states in times of 10 -6 to 10 -3 seconds. Experimental measurements of vapor pressures over fresh UO 2 from the pulsed electron beam and pulsed reactor heating tests are presented and compared with other high temperature data. The interpretation of the vapor pressure measured in the tests is discussed in detail. Effects of original sample stoichiometry, chemical interactions with the container and non-equilibrium evaporation due to induced temperature gradients are discussed. Special attention is given to dynamic behavior in rapid heating and vaporization of the oxide due to chemical non-equilibrium. Finally, similar projected reactor experiments on irradiated fuel are described and vapor pressure predictions made using available equilibrium models. A discussion of information accessible from such future tests and its importance is presented. (orig.) [de

  20. Failure analysis of electrolyte-supported solid oxide fuel cells

    Science.gov (United States)

    Fleischhauer, Felix; Tiefenauer, Andreas; Graule, Thomas; Danzer, Robert; Mai, Andreas; Kuebler, Jakob

    2014-07-01

    For solid oxide fuel cells (SOFCs) one key aspect is the structural integrity of the cell and hence its thermo mechanical long term behaviour. The present study investigates the failure mechanisms and the actual causes for fracture of electrolyte supported SOFCs which were run using the current μ-CHP system of Hexis AG, Winterthur - Switzerland under lab conditions or at customer sites for up to 40,000 h. In a first step several operated stacks were demounted for post-mortem inspection, followed by a fractographic evaluation of the failed cells. The respective findings are then set into a larger picture including an analysis of the present stresses acting on the cell like thermal and residual stresses and the measurements regarding the temperature dependent electrolyte strength. For all investigated stacks, the mechanical failure of individual cells can be attributed to locally acting bending loads, which rise due to an inhomogeneous and uneven contact between the metallic interconnect and the cell.

  1. Measurement and analysis of transient vaporization in oxide fuel materials

    International Nuclear Information System (INIS)

    Gorham-Bergeron, E.; Benson, D.A.

    1978-01-01

    A series of experiments is described in which samples are heated to produce high vapor pressure states in times of 10 -6 to 10 -3 seconds. Experimental measurements of vapor pressures over fresh UO 2 from the pulsed electron beam and pulsed reactor heating tests are presented and compared with other high temperature data. The interpretation of the vapor pressures measured in the tests is discussed in detail. Effects of original sample stoichiometry, chemical interactions with the container and non-equilibrium evaporation due to induced temperature gradients are discussed. Special attention is given to dynamic behavior in rapid heating and vaporization of the oxide due to chemical nonequilibrium. Finally, similar projected reactor experiments on irradiated fuel are described and vapor pressure predictions made using available equilibrium models. A discussion of information accessible from such future tests and its importance is presented

  2. Project proposals on the creation of Russian-American joint enterprise for investigation, development and manufacture of power plants on the basis of solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Smotrov, N.V.; Kleschev, Yu.N.

    1996-04-01

    This paper describes a proposal for a joint Russian-American enterprise for performing scientific investigations, development, and manufacture of fuel cell power plants on the basis of the solid oxide fuel cell. RASOFCo. Russian-American Solid Oxide Fuel Cells Company. RASOFCo will provide the series output of the electrochemical generator (ECG) of 1kW power, then of 5kW and 10kW as well as the development and the output of 10kW power plant with the subsequent output of a power plant of greater power. An ECG based on solid oxide fuel cells uses methane as a fuel. Predicted technical characteristics, market analysis, assessment of potential demands for power plants of low power for Tyumentransgas, participants of the joint enterprise and their founding contributions, strategy for manufacture and financing, and management of RASOFCo are discussed.

  3. Performance of IN-706 and PE-16 cladding in mixed-oxide fuel pins

    International Nuclear Information System (INIS)

    Makenas, B.J.; Lawrence, L.A.; Jensen, B.W.

    1982-05-01

    Iron-nickel base, precipitation-strengthened alloys, IN-706 and PE-16, advanced alloy cladding considered for breeder reactor applications, were irradiated in mixed-oxide fuel pins in the HEDL-P-60 subassembly in EBR-II. Initial selection of candidate advanced alloys was done using only nonfueled materials test results. However, to establish the performance characteristics of the candidate cladding alloys, i.e., dimensional stability and structural integrity under conditions of high neutron flux, elevated temperature, and applied stress, it was necessary to irradiate fuel pins under typical operating conditions. Fuel pins were clad with solution treated IN-706 and PE-16 and irradiated to peak fluences of 6.1 x 10 22 n/cm 2 (E > .1 MeV) and 8.8 x 10 22 n/cm 2 (E > .1 MeV) respectively. Fabrication and operating parameters for the fuel pins with the advanced cladding alloy candidates are summarized. Irradiation of HEDL-P-60 was interrupted with the breach of a pin with IN-706 cladding at 5.1 at % and the test was terminated with cladding breach in a pin with PE-16 cladding at 7.6 at %

  4. Thermodynamic investigation of an integrated gasification plant with solid oxide fuel cell and steam cycles

    Energy Technology Data Exchange (ETDEWEB)

    Rokni, Masoud [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Mechanical Engineering, Thermal Energy System

    2012-07-01

    A gasification plant is integrated on the top of a solid oxide fuel cell (SOFC) cycle, while a steam turbine (ST) cycle is used as a bottoming cycle for the SOFC plant. The gasification plant was fueled by woodchips to produce biogas and the SOFC stacks were fired with biogas. The produced gas was rather clean for feeding to the SOFC stacks after a simple cleaning step. Because all the fuel cannot be burned in the SOFC stacks, a burner was used to combust the remaining fuel. The off-gases from the burner were then used to produce steam for the bottoming steam cycle in a heat recovery steam generator (HRSG). The steam cycle was modeled with a simple single pressure level. In addition, a hybrid recuperator was used to recover more energy from the HRSG and send it back to the SOFC cycle. Thus two different configurations were investigated to study the plants characteristic. Such system integration configurations are completely novel and have not been studied elsewhere. Plant efficiencies of 56% were achieved under normal operation which was considerably higher than the IGCC (Integrated Gasification Combined Cycle) in which a gasification plant is integrated with a gas turbine and a steam turbine. Furthermore, it is shown that under certain operating conditions, plant efficiency of about 62 is also possible to achieve. (orig.)

  5. Fuel component of electricity generation cost for the BN-800 reactor with MOX fuel and uranium oxide fuel with increasing of fuel burnup and removing of radial breeding blanket

    International Nuclear Information System (INIS)

    Raskach, A.

    2001-01-01

    BN-800 at the Beloyarsk site were started in 1984. For now readiness of thermal equipment and industrial base is from 40 to 80%. By evaluations of various experts, a volume of construction and installation works performed for the first unit of the South Ural Nuclear Power Plant is from 10 to 13%. In connection with economical difficulties in Russia, the construction of all these objects have been discontinued and an issue to fund this project is as yet uncertain. Furthermore, the interrelation of the reactors and Complex-300 makes invoking of investments to complete construction of at least one BN-800 reactor much more difficult. Thus, along with MOX fuel loading of BN-800, it might be reasonable to consider a possibility to use uranium fuel until Complex-300 is put into operation and picks up sufficient output. And making a decision to load BN-800 with uranium oxide fuel in the initial stage of its operating should be based on analyses of fuel components in parallel with other decisive parameters. General technical characteristics on some versions of the BN-800 core with MOX and uranium fuel are shown in Table. (author)

  6. Combustion and exhaust emission characteristics of a dual fuel compression ignition engine operated with pilot Diesel fuel and natural gas

    International Nuclear Information System (INIS)

    Papagiannakis, R.G.; Hountalas, D.T.

    2004-01-01

    Towards the effort of reducing pollutant emissions, especially soot and nitrogen oxides, from direct injection Diesel engines, engineers have proposed various solutions, one of which is the use of a gaseous fuel as a partial supplement for liquid Diesel fuel. These engines are known as dual fuel combustion engines, i.e. they use conventional Diesel fuel and a gaseous fuel as well. This technology is currently reintroduced, associated with efforts to overcome various difficulties of HCCI engines, using various fuels. The use of natural gas as an alternative fuel is a promising solution. The potential benefits of using natural gas in Diesel engines are both economical and environmental. The high autoignition temperature of natural gas is a serious advantage since the compression ratio of conventional Diesel engines can be maintained. The present contribution describes an experimental investigation conducted on a single cylinder DI Diesel engine, which has been properly modified to operate under dual fuel conditions. The primary amount of fuel is the gaseous one, which is ignited by a pilot Diesel liquid injection. Comparative results are given for various engine speeds and loads for conventional Diesel and dual fuel operation, revealing the effect of dual fuel combustion on engine performance and exhaust emissions

  7. Study of catalysis for solid oxide fuel cells and direct methanol fuel cells

    Science.gov (United States)

    Jiang, Xirong

    Fuel cells offer the enticing promise of cleaner electricity with lower environmental impact than traditional energy conversion technologies. Driven by the interest in power sources for portable electronics, and distributed generation and automotive propulsion markets, active development efforts in the technologies of both solid oxide fuel cell (SOFC) and direct methanol fuel cell (DMFC) devices have achieved significant progress. However, current catalysts for fuel cells are either of low catalytic activity or extremely expensive, presenting a key barrier toward the widespread commercialization of fuel cell devices. In this thesis work, atomic layer deposition (ALD), a novel thin film deposition technique, was employed to apply catalytic Pt to SOFC, and investigate both Pt skin catalysts and Pt-Ru catalysts for methanol oxidation, a very important reaction for DMFC, to increase the activity and utilization levels of the catalysts while simultaneously reducing the catalyst loading. For SOFCs, we explored the use of ALD for the fabrication of electrode components, including an ultra-thin Pt film for use as the electrocatalyst, and a Pt mesh structure for a current collector for SOFCs, aiming for precise control over the catalyst loading and catalyst geometry, and enhancement in the current collect efficiency. We choose Pt since it has high chemical stability and excellent catalytic activity for the O2 reduction reaction and the H2 oxidation reaction even at low operating temperatures. Working SOFC fuel cells were fabricated with ALD-deposited Pt thin films as an electrode/catalyst layer. The measured fuel cell performance reveals that comparable peak power densities were achieved for ALD-deposited Pt anodes with only one-fifth of the Pt loading relative to a DC-sputtered counterpart. In addition to the continuous electrocatalyst layer, a micro-patterned Pt structure was developed via the technique of area selective ALD. By coating yttria-stabilized zirconia, a

  8. Electrode Reaction Pathway in Oxide Anode for Solid Oxide Fuel Cells

    Science.gov (United States)

    Li, Wenyuan

    Oxide anodes for solid oxide fuel cells (SOFC) with the advantage of fuel flexibility, resistance to coarsening, small chemical expansion and etc. have been attracting increasing interest. Good performance has been reported with a few of perovskite structure anodes, such as (LaSr)(CrMn)O3. However, more improvements need to be made before meeting the application requirement. Understanding the oxidation mechanism is crucial for a directed optimization, but it is still on the early stage of investigation. In this study, reaction mechanism of oxide anodes is investigated on doped YCrO 3 with H2 fuel, in terms of the origin of electrochemical activity, rate-determining steps (RDS), extension of reactive zone, and the impact from overpotential under service condition to those properties. H2 oxidation on the YCs anodes is found to be limited by charge transfer and H surface diffusion. A model is presented to describe the elementary steps in H2 oxidation. From the reaction order results, it is suggested that any models without taking H into the charge transfer step are invalid. The nature of B site element determines the H2 oxidation kinetics primarily. Ni displays better adsorption ability than Co. However, H adsorption ability of such oxide anode is inferior to that of Ni metal anode. In addition, the charge transfer step is directly associated with the activity of electrons in the anode; therefore it can be significantly promoted by enhancement of the electron activity. It is found that A site Ca doping improves the polarization resistance about 10 times, by increasing the activity of electrons to promote the charge transfer process. For the active area in the oxide anode, besides the traditional three-phase boundary (3PB), the internal anode surface as two-phase boundary (2PB) is proven to be capable of catalytically oxidizing the H2 fuel also when the bulk lattice is activated depending on the B site elements. The contribution from each part is estimated by switching

  9. Impact of physical properties of mixture of diesel and biodiesel fuels on hydrodynamic characteristics of fuel injection system

    Directory of Open Access Journals (Sweden)

    Filipović Ivan M.

    2014-01-01

    Full Text Available One of the alternative fuels, originating from renewable sources, is biodiesel fuel, which is introduced in diesel engines without major construction modifications on the engine. Biodiesel fuel, by its physical and chemical properties, is different from diesel fuel. Therefore, it is expected that by the application of a biodiesel fuel, the characteristic parameters of the injection system will change. These parameters have a direct impact on the process of fuel dispersion into the engine cylinder, and mixing with the air, which results in an impact on the quality of the combustion process. Method of preparation of the air-fuel mixture and the quality of the combustion process directly affect the efficiency of the engine and the level of pollutant emissions in the exhaust gas, which today is the most important criterion for assessing the quality of the engine. The paper presents a detailed analysis of the influence of physical properties of a mixture of diesel and biodiesel fuels on the output characteristics of the fuel injection system. The following parameters are shown: injection pressure, injection rate, the beginning and duration of injection, transformation of potential into kinetic energy of fuel and increase of energy losses in fuel injection system of various mixtures of diesel and biodiesel fuels. For the analysis of the results a self-developed computer program was used to simulate the injection process in the system. Computational results are verified using the experiment, for a few mixtures of diesel and biodiesel fuels. This paper presents the verification results for diesel fuel and biodiesel fuel in particular.

  10. Fission gas behavior in mixed-oxide fuel during transient overpower

    International Nuclear Information System (INIS)

    Randklev, E.H.; Treibs, H.A.; Mastel, B.; Baldwin, D.L.

    1979-01-01

    Fission gas behavior can be important in determining fuel pin and core performance during a reactor transient. The results are presented of examinations characterizing the changes in microstructural distribution and retention of fission gas in fuel for a series of transient overpower (50 cents/s) tested mixed-oxide fuel pins and their steady state siblings

  11. Evaluation of the oxide and silicide fuels reactivity in the RSG-GAS core

    International Nuclear Information System (INIS)

    S, Tukiran; M S, Tagor; S, Lily; Pinem, S.

    2000-01-01

    Fuel exchange of The RSG-GAS reactor core from uranium oxide to uranium silicide in the same loading, density, and enrichment, that is, 250 gr, 2.98 gr/cm 3 , and 19.75 % respectively, will be performed in-step wise. In every cycle of exchange with 5/l mode, it is needed to evaluate the parameter of reactor core operation. One of the important operation parameters is fuel reactivity that gives effect to the core reactivity. The experiment was performed at core no. 36, BOC, low power which exist 2 silicide fuels. The evaluation was done based on the RSG-GAS control rod calibration consisting of 40 fuels and 8 control rod.s. From 40 fuels in the core, there are 2 silicide fuels, RI-225/A-9 and RI-224/C-3. For inserting 2 silicide fuels, the reactivity effect to the core must be know. To know this effect , it was performed fuels reactivity experiment, which based on control rod calibration. But in this case the RSG-GAS has no other fresh oxide fuel so that configuration of the RSG-GAS core was rearranged by taking out the both silicide fuels and this configuration is used as reference core. Then silicide fuel RI-224 was inserted to position F-3 replacing the fresh oxide fuel RI-260 so the different reactivity of the fuels is obtained. The experiment result showed that the fuel reactivity change is in amount of 12.85 cent (0.098 % ) The experiment result was compared to the calculation result, using IAFUEL code which amount to 13.49 cent (0.103 %) The result showed that the reactivity change of oxide to silicide fuel is small so that the fuel exchange from uranium oxide to uranium silicide in the first step can be done without any significant change of the operation parameter

  12. SIMS and TEM study on oxide characteristics of Zircaloy

    International Nuclear Information System (INIS)

    Jung, Y. H.; Baek, J. H.; Kim, S. J.; Kim, K. H.; Choi, B. K.; Jung, Y. H.

    1998-01-01

    Long-term corrosion test, SIMS analysis, and TEM study were carried out to investigate the corrosion characteristics and corrosion mechanism of Zircaloy-4 in LiOH solution. The corrosion tests were performed in alkali solutions at 350 deg C for 500days. SIMS analysis was performed for the specimens prepared to have an equal oxide thickness to measure the cation content. TEM studies on the samples formed in various alkali solutions were also conducted. Based on the corrosion test, SIMS analysis, and TEM study, the cation is considered to control the corrosion in LiOH solution and its effect is dependent on the concentration of alkali and the oxide thickness. The slight acceleration of corrosion rate at a low concentration is thought to be caused by the cation incorporation into oxide while the significant acceleration at a high concentration is due to the transformation of oxide microstructure that would be induced by the cation incorporation

  13. Performance Analysis and Development Strategies for Solid Oxide Fuel Cells

    International Nuclear Information System (INIS)

    Ivers-Tiffee, E; Leonide, A; Weber, A

    2011-01-01

    Solid oxide fuel cells (SOFC) are of great interest for a diverse range of applications. Within the past 10 years, an increase in power density by one order of magnitude, a lowering of the operating temperature by 200 K, and degradation rates lowered by a factor of 10 have been achieved on the cell and stack level. However, there is still room for further enhancement of the overall performance by suitably tailoring the cell components on a micro- and nanostructural level. The efficiency of the electrochemically active single cell is characterized by the linear ohmic losses within the electrolyte and by nonlinear polarization losses at the electrode-electrolyte interfaces. Both depend on material composition and operation conditions (temperature and time, fuel utilisation and gas composition). The area-specific resistance (ASR) is considered as the figure of merit for overall performance. ASR values of anode supported cells (ASC) were determined by means of impedance spectroscopy and subsequently separated into ohmic losses (mainly electrolyte) and nonlinear polarisation losses resulting from gas diffusion and activation polarization in the cathode and anode. The efficiencies of ASCs will be discussed for various material combinations in the temperature range of technological interest (between 550 deg. C and 850 deg. C).

  14. Investigation of aluminosilicate refractory for solid oxide fuel cell applications

    Science.gov (United States)

    Gentile, Paul Steven

    Stationary solid oxide fuel cells (SOFCs) have been demonstrated to provide clean and reliable electricity through electro-chemical conversion of various fuel sources (CH4 and other light hydrocarbons). To become a competitive conversion technology the costs of SOFCs must be reduced to less than $400/kW. Aluminosilicate represents a potential low cost alternative to high purity alumina for SOFC refractory applications. The objectives of this investigation are to: (1) study changes of aluminosilicate chemistry and morphology under SOFC conditions, (2) identify volatile silicon species released by aluminosilicates, (3) identify the mechanisms of aluminosilicate vapor deposition on SOFC materials, and (4) determine the effects of aluminosilicate vapors on SOFC electrochemical performance. It is shown thermodynamically and empirically that low cost aluminosilicate refractory remains chemically and thermally unstable under SOFC operating conditions between 800°C and 1000°C. Energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) of the aluminosilicate bulk and surface identified increased concentrations of silicon at the surface after exposure to SOFC gases at 1000°C for 100 hours. The presence of water vapor accelerated surface diffusion of silicon, creating a more uniform distribution. Thermodynamic equilibrium modeling showed aluminosilicate remains stable in dry air, but the introduction of water vapor indicative of actual SOFC gas streams creates low temperature (active anode interface.

  15. Glass/Ceramic Composites for Sealing Solid Oxide Fuel Cells

    Science.gov (United States)

    Bansal, Narottam P.; Choi, Sung R.

    2007-01-01

    A family of glass/ceramic composite materials has been investigated for use as sealants in planar solid oxide fuel cells. These materials are modified versions of a barium calcium aluminosilicate glass developed previously for the same purpose. The composition of the glass in mole percentages is 35BaO + 15CaO + 5Al2O3 + 10B2O3 + 35SiO2. The glass seal was found to be susceptible to cracking during thermal cycling of the fuel cells. The goal in formulating the glass/ ceramic composite materials was to (1) retain the physical and chemical advantages that led to the prior selection of the barium calcium aluminosilicate glass as the sealant while (2) increasing strength and fracture toughness so as to reduce the tendency toward cracking. Each of the composite formulations consists of the glass plus either of two ceramic reinforcements in a proportion between 0 and 30 mole percent. One of the ceramic reinforcements consists of alumina platelets; the other one consists of particles of yttria-stabilized zirconia wherein the yttria content is 3 mole percent (3YSZ). In preparation for experiments, panels of the glass/ceramic composites were hot-pressed and machined into test bars.

  16. Solid oxide fuel cell performance under severe operating conditions

    DEFF Research Database (Denmark)

    Koch, Søren; Hendriksen, P.V.; Mogensen, Mogens Bjerg

    2006-01-01

    The performance and degradation of Solid Oxide Fuel Cells (SOFC) were studied under severe operating conditions. The cells studied were manufactured in a small series by ECN, in the framework of the EU funded CORE-SOFC project. The cells were of the anode-supported type with a double layer LSM...... cathode. They were operated at 750 °C or 850 °C in hydrogen with 5% or 50% water at current densities ranging from 0.25 A cm–2 to 1 A cm–2 for periods of 300 hours or more. The area specific cell resistance, corrected for fuel utilisation, ranged between 0.20 Ω cm2 and 0.34 Ω cm2 at 850 °C and 520 m......V, and between 0.51 Ω cm2 and 0.92 Ω cm2 at 750 °C and 520 mV. The degradation of cell performance was found to be low (ranging from 0 to 8%/1,000 hours) at regular operating conditions. Voltage degradation rates of 20 to 40%/1,000 hours were observed under severe operating conditions, depending on the test...

  17. Challenge for lowering concentration polarization in solid oxide fuel cells

    Science.gov (United States)

    Shimada, Hiroyuki; Suzuki, Toshio; Yamaguchi, Toshiaki; Sumi, Hirofumi; Hamamoto, Koichi; Fujishiro, Yoshinobu

    2016-01-01

    In the scope of electrochemical phenomena, concentration polarization at electrodes is theoretically inevitable, and lowering the concentration overpotential to improve the performance of electrochemical cells has been a continuing challenge. Electrodes with highly controlled microstructure, i.e., high porosity and uniform large pores are therefore essential to achieve high performance electrochemical cells. In this study, state-of-the-art technology for controlling the microstructure of electrodes has been developed for realizing high performance support electrodes of solid oxide fuel cells (SOFCs). The key is controlling the porosity and pore size distribution to improve gas diffusion, while maintaining the integrity of the electrolyte and the structural strength of actual sized electrode supports needed for the target application. Planar anode-supported SOFCs developed in this study realize 5 μm thick dense electrolyte (yttria-stabilized zirconia: YSZ) and the anode substrate (Ni-YSZ) of 53.6 vol.% porosity with a large median pore diameter of 0.911 μm. Electrochemical measurements reveal that the performance of the anode-supported SOFCs improves with increasing anode porosity. This Ni-YSZ anode minimizes the concentration polarization, resulting in a maximum power density of 3.09 W cm-2 at 800 °C using humidified hydrogen fuel without any electrode functional layers.

  18. Solid oxide fuel cells towards real life applications. Final report

    Energy Technology Data Exchange (ETDEWEB)

    2010-07-01

    Solid Oxide Fuel Cells offer a clean and efficient way of producing electricity and heat from a wide selection of fuels. The project addressed three major challenges to be overcome by the technology to make commercialisation possible. (1) At the cell level, increased efficiency combined with production cost reduction has been achieved through an optimization of the manufacturing processes, b) by using alternative raw materials with a lower purchase price and c) by introducing a new generation of fuel cells with reduced loss and higher efficiency. (2) At the stack level, production cost reduction is reduced and manufacturing capacity is increased through an optimization of the stack production. (3) At the system level, development of integrated hotbox concepts for the market segments distributed generation (DG), micro combined heat and power (mCHP), and auxiliary power units (APU) have been developed. In the mCHP segment, two concepts have been developed and validated with regards to market requirements and scalability. In the APU-segment, different types of reformers have been tested and it has been proven that diesel can be reformed through appropriate reformers. Finally, operation experience and feedback has been gained by deployment of stacks in the test facility at the H.C. OErsted Power Plant (HCV). This demonstration has been carried out in collaboration between TOFC and DONG Energy Power A/S (DONG), who has participated as a subcontractor to TOFC. The demonstration has given valuable knowledge and experience with design, start-up and operation of small power units connected to the grid and future development within especially the mCHP segment will benefit from this. In this report, the project results are described for each of the work packages in the project. (Author)

  19. Method of manufacturing gadolinium oxide-incorporated nuclear fuel sintering products

    International Nuclear Information System (INIS)

    Komono, Akira; Seki, Makoto; Omori, Sadayuki.

    1987-01-01

    Purpose: To manufacture nuclear fuel sintering products excellent in burning property and mechanical property. Constitution: In the manufacturing step for nuclear fuel sintering products, specific metal oxides are added for promoting the growth of crystal grains in the sintering. Those metal oxides melted at a temperature lower than the sintering temperature of a mixture of nuclear fuel oxide powder and oxide power, or those metal oxides causing eutectic reaction are used as the metal oxide. Particularly, those compounds having oxygen atom - metal atom ratio (O/M) of not less than 2 are preferably used. As such metal oxides usable herein transition metal oxides, e.g., Nb 2 O 5 , TiO 2 , MoO 3 and WO 3 are preferred, with Nb 2 O 3 and TiO 2 being preferred particularly. (Seki, T.)

  20. Electrochemical processing of spent nuclear fuels: An overview of oxide reduction in pyroprocessing technology

    Directory of Open Access Journals (Sweden)

    Eun-Young Choi

    2015-12-01

    Full Text Available The electrochemical reduction process has been used to reduce spent oxide fuel to a metallic form using pyroprocessing technology for a closed fuel cycle in combination with a metal-fuel fast reactor. In the electrochemical reduction process, oxides fuels are loaded at the cathode basket in molten Li2O–LiCl salt and electrochemically reduced to the metal form. Various approaches based on thermodynamic calculations and experimental studies have been used to understand the electrode reaction and efficiently treat spent fuels. The factors that affect the speed of the electrochemical reduction have been determined to optimize the process and scale-up the electrolysis cell. In addition, demonstrations of the integrated series of processes (electrorefining and salt distillation with the electrochemical reduction have been conducted to realize the oxide fuel cycle. This overview provides insight into the current status of and issues related to the electrochemical processing of spent nuclear fuels.

  1. Advanced manufacturing of intermediate temperature, direct methane oxidation membrane electrode assemblies for durable solid oxide fuel cell, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — ITN proposes to create an innovative anode supported membrane electrode assembly (MEA) for solid oxide fuel cells (SOFCs) that is capable of long-term operation at...

  2. The spectrographic analysis of plutonium oxide or mixed plutonium oxide/uranium oxide fuel pellets by the dried residue technique

    International Nuclear Information System (INIS)

    Jarbo, G.J.; Faught, P.; Hildebrandt, B.

    1980-05-01

    An emission spectrographic method for the quantitative determination of metallic impurities in plutonium oxide and mixed plutonium oxide/uranium oxide is described. The fuel is dissolved in nitric acid and the plutonium and/or uranium extracted with tributyl phosphate. A small aliquot of the aqueous residue is dried on a 'mini' pyrolitic graphite plate and excited by high voltage AC spark in an oxygen atmosphere. Spectra are recorded in a region which has been specially selected to record simultaneously lines of boron and cadmium in the 2nd order and all the other elements of interest in the 1st order. Indium is used as an internal standard. The excitation of very small quantities of the uraniumm/plutonium free residue by high voltage spark, together with three separate levels of containment reduce the hazards to personnel and the environment to a minimum with limited effect on sensitivity and accuracy of the results. (auth)

  3. Perovskites synthesis for solid oxide fuel cells; Sintese de perovsquitas para celulas a combustivel de oxido solido

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Sibelle F.C.X.; Melo, Dulce M.A.; Pimentel, Patricia M.; Melo, Marcus A. Freitas; Martinelli, Daniele M.H. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Quimica]. E-mail: sibelle.cunha@gmail

    2008-07-01

    This work aims to study on the obtaining powders of lanthanum manganite oxides with partial substitution of La with strontium at 20% for the application as a cathode for solid oxide fuel cell, through a route of synthesis that are similar to the Pechini method, in which gelatin replaces the ethylene glycol as polymerization agent. The method highlights itself due to its simplicity, low cost and capability to obtain crystalline powders with the high purity and good stoichiometric control. The perovskite obtained were characterized by thermogravimetric analysis, X ray diffraction, electronic scanning microscopy and the superficial area by BET method. The deposition of the perovskite on electrolyte/anode system was done through the spin coating technique. The methodology used for the perovskite synthesis was very efficient, considering a monophasic material was obtained and with characteristics that were proper to the application as electrode to solid oxide fuel cells. (author)

  4. Carbon and Redox Tolerant Infiltrated Oxide Fuel-Electrodes for Solid Oxide Cells

    DEFF Research Database (Denmark)

    Skafte, Theis Løye; Sudireddy, Bhaskar Reddy; Blennow, P.

    2016-01-01

    To solve issues of coking and redox instability related to the presence of nickel in typical fuel electrodes in solid oxide cells,Gd-doped CeO2 (CGO) electrodes were studied using symmetriccells. These electrodes showed high electro-catalytic activity, butlow electronic conductivity. When...... infiltrated with Sr0.99Fe0.75Mo0.25O3-δ (SFM), the electronic conductivity wasenhanced. However, polarization resistance of the cells increased,suggesting that the infiltrated material is less electro-catalyticallyactive and was partly blocking the CGO surface reaction sites. Theactivity could be regained...... by infiltrating nano-sized CGO orNiCGO on top of SFM, while still sustaining the high electronicconductivity. Ohmic resistance of the electrodes was thuspractically eliminated and performance comparable to, or betterthan, state-of-the-art fuel electrodes was achieved. The Nicontaining cells were damaged by carbon...

  5. Biobutanol as Fuel for Direct Alcohol Fuel Cells-Investigation of Sn-Modified Pt Catalyst for Butanol Electro-oxidation.

    Science.gov (United States)

    Puthiyapura, Vinod Kumar; Brett, Dan J L; Russell, Andrea E; Lin, Wen-Feng; Hardacre, Christopher

    2016-05-25

    Direct alcohol fuel cells (DAFCs) mostly use low molecular weight alcohols such as methanol and ethanol as fuels. However, short-chain alcohol molecules have a relative high membrane crossover rate in DAFCs and a low energy density. Long chain alcohols such as butanol have a higher energy density, as well as a lower membrane crossover rate compared to methanol and ethanol. Although a significant number of studies have been dedicated to low molecular weight alcohols in DAFCs, very few studies are available for longer chain alcohols such as butanol. A significant development in the production of biobutanol and its proposed application as an alternative fuel to gasoline in the past decade makes butanol an interesting candidate fuel for fuel cells. Different butanol isomers were compared in this study on various Pt and PtSn bimetallic catalysts for their electro-oxidation activities in acidic media. Clear distinctive behaviors were observed for each of the different butanol isomers using cyclic voltammetry (CV), indicating a difference in activity and the mechanism of oxidation. The voltammograms of both n-butanol and iso-butanol showed similar characteristic features, indicating a similar reaction mechanism, whereas 2-butanol showed completely different features; for example, it did not show any indication of poisoning. Ter-butanol was found to be inactive for oxidation on Pt. In situ FTIR and CV analysis showed that OHads was essential for the oxidation of primary butanol isomers which only forms at high potentials on Pt. In order to enhance the water oxidation and produce OHads at lower potentials, Pt was modified by the oxophilic metal Sn and the bimetallic PtSn was studied for the oxidation of butanol isomers. A significant enhancement in the oxidation of the 1° butanol isomers was observed on addition of Sn to the Pt, resulting in an oxidation peak at a potential ∼520 mV lower than that found on pure Pt. The higher activity of PtSn was attributed to the

  6. How well does ORIGEN predict spent LWR fuel characteristics

    International Nuclear Information System (INIS)

    Mailen, J.C.; Roddy, J.W.

    1987-01-01

    The ORIGEN computer code is widely used to estimate the radionuclide content (actinides, activation and fission products) of irradiated reactor fuel and the resultant heat generation and radiation levels associated with such fuel. These estimates are used as source terms in safety evaluations of operating reactors, for evaluation of fuel behavior and regulation of the at-reactor storage, for transportation studies, and for evaluation of the ultimate geologic storage of the fuel. This survey summarizes the fuel data available in the open literature and, where given, the calculated values by ORIGEN. Plans for additional analyses of well-characterized reactor fuel samples to improve the validation of ORIGEN2 are discussed

  7. Soot formation characteristics of gasoline surrogate fuels in counterflow diffusion flames

    KAUST Repository

    Choi, Byungchul

    2011-01-01

    The characteristics of polycyclic aromatic hydrocarbon (PAH) and soot for gasoline surrogate fuels have been investigated in counterflow diffusion flames by adopting laser-induced fluorescence (LIF) and laser-induced incandescence (LII) techniques for both soot formation and soot formation/oxidation flames. Tested fuels were three binary mixtures from the primary reference fuels of n-heptane, iso-octane, and toluene. The result showed that PAH and soot maintained near zero level for all mixtures of n-heptane/iso-octane case under present experimental conditions. For n-heptane/toluene and iso-octane/toluene mixtures, PAH initially increased and then decreased with the toluene ratio, exhibiting a synergistic effect. The soot formation increased monotonically with the toluene ratio, however the effect of toluene on soot formation was minimal for relatively small toluene ratios. These results implied that even though toluene had a dominant role in soot and PAH formations, small amount of toluene had a minimal effect on soot formation. Numerical simulations have also been conducted by adopting recently proposed two kinetic mechanisms. The synergistic behavior of aromatic rings was predicted similar to the experimental PAH measurement, however, the degree of the synergistic effect was over-predicted for the soot formation flame, indicating the need for refinements in the kinetic mechanisms. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  8. Study of core characteristics on fuel and coolant type. Results of F/S phase-I

    International Nuclear Information System (INIS)

    Ikegami, Tetsuo; Hayashi, Hideyuki; Sasaki, Makoto; Mizuno, Tomoyasu; Yamadate, Megumi; Takaki, Naoyuki; Kurosawa, Norifumi; Sakashita, Yoshiaki; Naganuma, Masayuki

    2001-03-01

    The phase-I of the Feasibility Study of Commercialized Fast Reactor Cycle Systems (F/S) were started from July, 1999 and terminated at the end of FY2000 in order to executed examination about technology alternatives of various commercialized fast reactor (FR) recycle concepts, in response to the JNC middle long term enterprise plan. In the phase-I of this F/S, a number of conceptual candidates have been selected from the following 5 viewpoints: a) ensuring safety, b) economic competitiveness to future LWRs, c) efficient utilization of resources, d) reduction of environmental burden, e) enhancement of nuclear non-proliferation. As for this study from the above viewpoints, core characteristics of many kinds of reactors have been investigated, analyzed and examined a core / a fuel characteristic in the combinations of fuel and coolant types and power output scales. Based on these results, R and D plans of the phase-II to be performed have been proposed, and a database to select candidate reactor concepts has been prepared. The conclusions have been obtained in the phase-I are as follows: (1) Evaluation of a fuel form in every each coolant was compared. A promising fuel form was extracted as follows: an oxide and a metal fuel for sodium coolant cores, a metal and a nitride fuel for heavy metal coolant cores, an oxide and a nitride fuel for carbon dioxide coolant cores and a nitride fuel for He gas coolant cores. (2) As the general idea that performance of a core nucleus can be compatible with re-criticality evasion in sodium coolant large-sized oxide fuel cores, a axial blanket particle elimination radial heterogeneous core is one influential candidate. (3) In case of Pb-Bi coolant nature circulation medium size core with an oxide fuel, it is difficult to simultaneously achieve higher discharged burn-up and higher breeding ratio according to the viewpoints of the phase-I. (4) Core characteristics of a carbon dioxide coolant core shows to be almost equivalent to that of

  9. The thermomechanical stability of micro-solid oxide fuel cells fabricated on anodized aluminum oxide membranes

    Science.gov (United States)

    Kwon, Chang-Woo; Lee, Jae-Il; Kim, Ki-Bum; Lee, Hae-Weon; Lee, Jong-Ho; Son, Ji-Won

    2012-07-01

    The thermomechanical stability of micro-solid oxide fuel cells (micro-SOFCs) fabricated on an anodized aluminum oxide (AAO) membrane template is investigated. The full structure consists of the following layers: AAO membrane (600 nm)/Pt anode/YSZ electrolyte (900 nm)/porous Pt cathode. The utilization of a 600-nm-thick AAO membrane significantly improves the thermomechanical stability due to its well-known honeycomb-shaped nanopore structure. Moreover, the Pt anode layer deposited in between the AAO membrane and the YSZ electrolyte preserves its integrity in terms of maintaining the triple-phase boundary (TPB) and electrical conductivity during high-temperature operation. Both of these results guarantee thermomechanical stability of the micro-SOFC and extend the cell lifetime, which is one of the most critical issues in the fabrication of freestanding membrane-type micro-SOFCs.

  10. Magnetoviscoelastic characteristics of superparamagnetic oxides (Fe, Ni) based ferrofluids

    Energy Technology Data Exchange (ETDEWEB)

    Katiyar, Ajay, E-mail: ajay_k@ric.drdo.in [Research and Innovation Centre (DRDO), IIT Madras Research Park, Chennai 600113 (India); Department of Mechanical Engineering, Indian Institute of Technology Madras, Chennai 600036 (India); Dhar, Purbarun [Department of Mechanical Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India); Nandi, Tandra [Defence Materials and Stores Research and Development Establishment (DRDO), G.T. Road, Kanpur 208013 (India); Das, Sarit K. [Department of Mechanical Engineering, Indian Institute of Technology Madras, Chennai 600036 (India); Department of Mechanical Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India)

    2017-08-15

    Highlights: • The magnetoviscous effect in ferrofluids in the presence of magnetic field is investigated. • Oxides of Fe and Ni are dispersed in oil to formulate the ferrofluids. • Drastic enhancement in the yield stress and viscosity under the magnetic field is observed for Fe{sub 3}O{sub 4}-based ferrofluids. • Viscoelastic properties of the formulated ferrofluids demonstrate the strong function of magnetic field. • The increase in temperature reduces the magneto-viscous effect in ferrofluids under the magnetic field. - Abstract: Ferrofluids have been popular among the academic and scientific communities owing to their intelligent physical characteristics under external stimuli and are in fact among the first nanotechnology products to be employed in real world applications. However, studies on the magnetoviscoelastic behavior of concentrated ferrofluids, especially of superparamagnetic oxides of iron and nickel are rare. The present article comprises the formulation of magneto-colloids utilizing the three various metal oxides nanoparticles viz. Iron (II, III) oxide (Fe{sub 3}O{sub 4}), Iron (III) oxide (Fe{sub 2}O{sub 3}) and Nickel oxide (NiO) in oil. Iron (II, III) oxide based colloids demonstrate high magnetoviscous characteristics over the other oxides based colloids under external magnetic fields. The maximum magnitude of yield stress and viscosity is found to be 3.0 kPa and 2.9 kPa.s, respectively for iron (II, III) oxide based colloids at 2.6 vol% particle concentration and 1.2 T magnetic field. Experimental investigations reveal that the formulated magneto-nanocolloids are stable, even in high magnetic fields and almost reversible when exposed to rising and drop of magnetic fields of the same magnitude. Observations also reveal that the elastic behavior dominates over the viscous behavior with enhanced relaxation and creep characteristics under the magnetic field. The effect of temperature on viscosity and yield stress of magneto

  11. Behavior of mixed-oxide fuel elements during the TOPI-1E transient overpower test

    International Nuclear Information System (INIS)

    Tsai, H.; Neimark, L.A.; Yamamoto, K.; Hirai, K.; Shikakura, S.

    1993-12-01

    A slow-ramp, extended overpower transient test was conducted on a group of nineteen preirradiated mixed-oxide fuel elements in EBR-II. During the transient two of the test elements with high-density fuel and tempered martensitic cladding (PNC-FMS) breached at an overpower of ∼75%. Fuel elements with austenitic claddings (D9, PNC316, and PNC150), many with aggressive design features and high burnups, survived the overpower transient and incurred little or no cladding strain. Fuel elements with annual fuel or heterogeneous fuel columns also behaved well

  12. Reprocessing fuel from the Southwest Experimental Fast Oxide Reactor at the Savannah River Plant

    International Nuclear Information System (INIS)

    Gray, L.W.; Campbell, T.G.

    1985-11-01

    The irradiated fuel, reject fuel tubes, and fuel fabrication scrap from the Southwest Experimental Fast Oxide Reactor (SEFOR) were transferred to the Savannah River Plant (SRP) for uranium and plutonium recovery. The unirradiated material was declad and dissolved at SRP; dissolution was accomplished in concentrated nitric acid without the addition of fluoride. The irradiated fuel was declad at Atomics International and repacked in aluminum. The fuel and aluminum cans were dissolved at SRP using nitric acid catalyzed by mercuric nitrate. As this fuel was dissolved in nongeometrically favorable tanks, boron was used as a soluble neutron poison

  13. Comparison of atomization characteristics of drop-in and conventional jet fuels

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza; Micro Scale Thermo-Fluids Lab Team

    2016-11-01

    Surge in energy demand and stringent emission norms have been driving the interest on alternative drop-in fuels in aviation industry. The gas-to-liquid (GTL), synthetic paraffinic kerosene fuel derived from natural gas, has drawn significant attention as drop-in fuel due to its cleaner combustion characteristics when compared to other alternative fuels derived from various feedstocks. The fuel specifications such as chemical and physical properties of drop-in fuels are different from those of the conventional jet fuels, which can affect their atomization characteristics and in turn the combustion performance. The near nozzle liquid sheet dynamics of the drop-in fuel, GTL, is studied at different nozzle operating conditions and compared with that of the conventional Jet A-1 fuel. The statistical analysis of the near nozzle sheet dynamics shows that the drop-in fuel atomization characteristics are comparable to those of the conventional fuel. Furthermore, the microscopic spray characteristics measured using phase Doppler anemometry at downstream locations are slightly different between the fuels. Authors acknowledge the support by National Priorities Research Program (NPRP) of Qatar National Research Fund through the Grant NPRP-7-1449-2-523.

  14. Assessment of core characteristics during transition from 37-element fuel to CANFLEX-NU fuel in CANDU 6

    International Nuclear Information System (INIS)

    Jeong, Chang Joon; Suk, Ho Chun

    2002-01-01

    A transition from 37-element natural uranium fuel to CANFLEX-NU fuel has been modeled in a 1200-day time-dependent fuel management simulation for a CANDU 6 reactor. The simulation was divided into three parts. The pre-transition period extended from 0 to 300 FPD, in which the reactor was fuelled only with standard 37-element fuel bundles. In the transition period, refueling took place only with the CANFLEX-NU fuel bundle. The transition stage lasted from 300 to 920 FPD, at which point all of the 37-element fuel in the core had been replaced by CANFLEX-NU fuel bundle. In the post-transition phase, refueling continued with CANFLEX-NU fuel until 1200 FPD, to arrive at estimate of the equilibrium core characteristics with CANFLEX-NU fuel. Simulation results show that the CANFLEX-NU fuel bundle has a operational compatibility with the CANDU 6 reactor during the transition core, and also show that the transition core from 37-element natural uranium fuel to CANFLEX-NU can be operated without violating any license limit of the CANDU 6 reactor

  15. Large-scale calculations of solid oxide fuel cell cermet anode by tight-binding quantum chemistry method

    International Nuclear Information System (INIS)

    Koyama, Michihisa; Kubo, Momoji; Miyamoto, Akira

    2005-01-01

    Improvement of anode characteristics of solid oxide fuel cells is important for the better cell performance and especially the direct use of hydrocarbons. A mixture of ceramics and metal is generally used as anode, and different combinations of ceramics and metals lead to different electrode characteristics. We performed large-scale calculations to investigate the characteristics of Ni/CeO 2 and Cu/CeO 2 anodes at the electronic level using our tight-binding quantum chemical molecular dynamics program. Charge distribution analysis clarified the electron transfer from metal to oxide in both anodes. The calculations of density of states clarified different contributions of Ni and Cu orbitals to the energy levels at around Fermi level in each cermet. Based on the obtained results, we made considerations to explain different characteristics of both cermet anodes. The effectiveness of our approach for the investigation of complex cermet system was proved

  16. Dissolution of mixed oxide fuel as a function of fabrication variables

    International Nuclear Information System (INIS)

    Lerch, R.E.

    1979-08-01

    Dissolution properties of mechanically blended mixed oxide fuel were very dependent on the six fuel fabrication variables studied. Fuel sintering temperature, source of PuO 2 and PuO 2 content of the fuel had major effects: (1) as the sintering temperature was increased from 1400 to 1700 0 C, pellet dissolution was more complete; (2) pellets made from burned metal derived PuO 2 were more completely dissolved than pellets made from calcined nitrate derived PuO 2 which in turn were more completely dissolved than pellets made from calcined nitrate derived PuO 2 ; (3) as the PuO 2 content decreased from 25 to 15 wt % PuO 2 , pellet dissolution was more complete. Preferential dissolution of uranium occurred in all the mechanically blended mixed oxide. Unirradiated mixed oxide fuel pellets made by the Sol Gel process were generally quite soluble in nitric acid. Unirradiated mixed oxide fuel pellets made by the coprecipitation process dissolved completely and rapidly in nitric acid. Fuel made by the coprecipitation process was more completely dissolved than fuel made by the Sol Gel process which, in turn, was more completely dissolved than fuel made by mechanically blending UO 2 and PuO 2 as shown below. Addition of uncomplexed fluoride to nitric acid during fuel dissolution generally rendered all fuel samples completely dissolvable. In boiling 12M nitric acid, 95 to 99% of the plutonium which was going to dissolve did so in the first hour. Irradiated mechanically blended mixed oxide fuel with known fuel fabrication conditions was also subjected to fuel dissolution tests. While irradiation was shown to increase completeness of plutonium dissolution, poor dissolubility due to adverse fabrication conditions (e.g., low sintering temperature) remained after irradiation

  17. Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel production

    KAUST Repository

    Garcia Esparza, Angel T.; Limkrailassiri, Kevin; Leroy, Fré dé ric; Rasul, Shahid; Yu, Weili; Lin, Liwei; Takanabe, Kazuhiro

    2014-01-01

    We report the use of a facile and highly scalable synthesis process to control growth products of earth-abundant Cu-based oxides and their application in relevant photoelectrochemical and electrochemical solar fuel generation systems. Characterization of the synthesized Cu(I)/Cu(II) oxides indicates that their surface morphology and chemical composition can be simply tuned by varying two synthesis parameters (time and temperature). UV-Vis spectroscopy and impedance spectroscopy studies are performed to estimate the band structures and electronic properties of these p-type semiconductor materials. Photoelectrodes made of Cu oxides possess favorable energy band structures for production of hydrogen from water; the position of their conduction band is ≈1 V more negative than the water-reduction potential. High acceptor concentrations on the order of 1018-1019 cm-3 are obtained, producing large electric fields at the semiconductor-electrolyte interface and thereby enhancing charge separation. The highly crystalline pristine samples used as photocathodes in photoelectrochemical cells exhibit high photocurrents under AM 1.5G simulated illumination. When the samples are electrochemically reduced under galvanostatic conditions, the co-existence of the oxide with metallic Cu on the surface seems to function as an effective catalyst for the selective electrochemical reduction of CO2. © the Partner Organisations 2014.

  18. A combined SEM and CV Study of Solid Oxide Fuel Cell Interconnect Steels

    DEFF Research Database (Denmark)

    Kammer Hansen, Kent; Ofoegbu, Stanley; Mikkelsen, Lars

    2012-01-01

    Scanning electron microscopy and cyclic voltammetry were used to investigate the high temperature oxidation behavior of two solid oxide fuel cell interconnect steels. One alloy had a low content of manganese; the other alloy had a high content of manganese. Four reduction and four oxidation peaks...

  19. Simulating Dynamic Fracture in Oxide Fuel Pellets Using Cohesive Zone Models

    Energy Technology Data Exchange (ETDEWEB)

    R. L. Williamson

    2009-08-01

    It is well known that oxide fuels crack during the first rise to power, with continued fracture occurring during steady operation and especially during power ramps or accidental transients. Fractures have a very strong influence on the stress state in the fuel which, in turn, drives critical phenomena such as fission gas release, fuel creep, and eventual fuel/clad mechanical interaction. Recently, interest has been expressed in discrete fracture methods, such as the cohesive zone approach. Such models are attractive from a mechanistic and physical standpoint, since they reflect the localized nature of cracking. The precise locations where fractures initiate, as well as the crack evolution characteristics, are determined as part of the solution. This paper explores the use of finite element cohesive zone concepts to predict dynamic crack behavior in oxide fuel pellets during power-up, steady operation, and power ramping. The aim of this work is first to provide an assessment of cohesive zone models for application to fuel cracking and explore important numerical issues associated with this fracture approach. A further objective is to provide basic insight into where and when cracks form, how they interact, and how cracking effects the stress field in a fuel pellet. The ABAQUS commercial finite element code, which includes powerful cohesive zone capabilities, was used for this study. Fully-coupled thermo-mechanical behavior is employed, including the effects of thermal expansion, swelling due to solid and gaseous fission products, and thermal creep. Crack initiation is determined by a temperature-dependent maximum stress criterion, based on measured fracture strengths for UO2. Damage evolution is governed by a traction-separation relation, calibrated to data from temperature and burn-up dependent fracture toughness measurements. Numerical models are first developed in 2D based on both axisymmetric (to explore axial cracking) and plane strain (to explore radial

  20. In situ Reduction and Oxidation of Nickel from Solid Oxide Fuel Cells in a Transmission Electron Microscope

    DEFF Research Database (Denmark)

    Faes, Antonin; Jeangros, Quentin; Wagner, Jakob Birkedal

    2009-01-01

    Environmental transmission electron microscopy was used to characterize in situ the reduction and oxidation of nickel from a Ni/YSZ solid oxide fuel cell anode support between 300-500{degree sign}C. The reduction is done under low hydrogen pressure. The reduction initiates at the NiO/YSZ interface...

  1. A study of the stabilities, microstructures and fuel characteristics of tri-fuel (diesel-biodiesel-ethanol) using various fuel preparation methods

    Science.gov (United States)

    Lee, K. H.; Mukhtar, N. A. M.; Yohaness Hagos, Ftwi; Noor, M. M.

    2017-10-01

    In this study, the work was carried out to investigate the effects of ethanol proportions on the stabilities and physicochemical characteristics of tri-fuel (Diesel-Biodiesel-Ethanol). For the first time, tri-fuel emulsions and blended were compared side by side. The experiment was done with composition having 5%, 10%, 15%, 20% and 25 % of ethanol with fixed 10% of biodiesel from palm oil origin on a volume basis into diesel. The results indicated that the phase stabilities of the emulsified fuels were higher compared to the blended fuels. In addition, tri-fuel composition with higher proportion of ethanol were found unstable with high tendency to form layer separation. It was found that tri-fuel emulsion with 5% ethanol content (D85B10E5) was of the best in stability with little separation. Furthermore, tri-fuel with lowest ethanol proportion indicated convincing physicochemical characteristics compared to others. Physicochemical characteristics of tri-fuel blending yield almost similar results to tri-fuel emulsion but degrading as more proportion ethanol content added. Emulsion category had cloudy look but on temporarily basis. Under the microscope, tri-fuel emulsion and blending droplet were similar for its active moving about micro-bubble but distinct in term of detection of collision, average disperse micro-bubble size, the spread and organization of the microstructure.

  2. Pilot-scale equipment development for pyrochemical treatment of spent oxide fuel

    International Nuclear Information System (INIS)

    Herrmann, S. D.

    1999-01-01

    Fundamental objectives regarding spent nuclear fuel treatment technologies include, first, the effective distribution of spent fuel constituents among product and stable waste forms and, second, the minimization and standardization of waste form types and volumes. Argonne National Laboratory (ANL) has developed and is presently demonstrating the electrometallurgical treatment of sodium-bonded metal fuel from Experimental Breeder Reactor II, resulting in an uranium product and two stable waste forms, i.e. ceramic and metallic. Engineering efforts are underway at ANL to develop pilot-scale equipment which would precondition irradiated oxide fuel via pyrochemical processing and subsequently allow for electrometallurgical treatment of such non-metallic fuels into standard product and waste forms. This paper highlights the integration of proposed spent oxide fuel treatment with existing electrometallurgical processes. System designs and technical bases for development of pilot-scale oxide reduction equipment are also described

  3. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    Science.gov (United States)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative

  4. Effects of Biodiesel Blend on Marine Fuel Characteristics for Marine Vessels

    Directory of Open Access Journals (Sweden)

    Cherng-Yuan Lin

    2013-09-01

    Full Text Available Biodiesel produced from vegetable oils, animal fats and algae oil is a renewable, environmentally friendly and clean alternative fuel that reduces pollutants and greenhouse gas emissions in marine applications. This study investigates the influence of biodiesel blend on the characteristics of residual and distillate marine fuels. Adequate correlation equations are applied to calculate the fuel properties of the blended marine fuels with biodiesel. Residual marine fuel RMA has inferior fuel characteristics compared with distillate marine fuel DMA and biodiesel. The flash point of marine fuel RMA could be increased by 20% if blended with 20 vol% biodiesel. The sulfur content of residual marine fuel could meet the requirement of the 2008 MARPOL Annex VI Amendment by blending it with 23.0 vol% biodiesel. In addition, the kinematic viscosity of residual marine fuel could be reduced by 12.9% and the carbon residue by 23.6% if 20 vol% and 25 vol% biodiesel are used, respectively. Residual marine fuel blended with 20 vol% biodiesel decreases its lower heating value by 1.9%. Moreover, the fuel properties of residual marine fuel are found to improve more significantly with biodiesel blending than those of distillate marine fuel.

  5. Palladium-based electrocatalysts for ethanol oxidation reaction in alkaline direct ethanol fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Leticia Poras Reis de; Amico, Sandro Campos; Malfatti, Celia de Fraga, E-mail: leticiamoraes@usp.br [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre (Brazil); Matos, Bruno R.; Santiago, Elisabete Inacio; Fonseca, Fabio Coral [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2016-07-01

    Full text: Direct ethanol fuel cells require adequate electrocatalysts to promote the carbon carbon cleavage of ethanol molecule. Typical electrocatalysts are based on platinum, which have shown improved activity in acidic media. However, Pt-based catalysts have high cost and are easily deactivated by CO poisoning. Therefore, novel catalysts have been developed, and among then, palladium-based materials have shown promising results for the oxidation of ethanol in alkaline media. The present study reports on the performance of alkaline direct ethanol fuel cell (ADEFC) by using carbon-supported Pd, PdSn, PdNi, and PdNiSn produced by impregnation-reduction of the metallic precursors. The effect of chemical functionalization by acid treatment of the carbon support (Vulcan) was investigated. The electrocatalysts were studied by thermogravimetric analysis (TGA), X-rays diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry (CV), and ADEFC tests. TGA measurements of functionalized Vulcan evidenced the characteristic weight losses attributed to the presence of surface functional groups due to the acid treatment. A high degree of alloying between Pd and Sn was inferred from XRD data, whereas in both PdNi and PdNiSn, Ni occurs mostly segregated in the oxide form. TEM analyses indicated agglomeration of Pd and PdSn particles, whereas a more uniform particle distribution was observed for PdNi and PdNiSn samples. CV curves showed that the peak potential for the oxidation of ethanol shifts towards negative values for all samples supported on functionalized Vulcan indicating that ethanol oxidation is facilitated. Microstructural and electrochemical features were confirmed by ADEFC tests, which revealed that the highest open circuit voltage and maximum power density were achieved for PdNiSn electrocatalysts supported on functionalized Vulcan with uniform particle distribution and improved triple phase boundaries. (author)

  6. Palladium-based electrocatalysts for ethanol oxidation reaction in alkaline direct ethanol fuel cell

    International Nuclear Information System (INIS)

    Moraes, Leticia Poras Reis de; Amico, Sandro Campos; Malfatti, Celia de Fraga; Matos, Bruno R.; Santiago, Elisabete Inacio; Fonseca, Fabio Coral

    2016-01-01

    Full text: Direct ethanol fuel cells require adequate electrocatalysts to promote the carbon carbon cleavage of ethanol molecule. Typical electrocatalysts are based on platinum, which have shown improved activity in acidic media. However, Pt-based catalysts have high cost and are easily deactivated by CO poisoning. Therefore, novel catalysts have been developed, and among then, palladium-based materials have shown promising results for the oxidation of ethanol in alkaline media. The present study reports on the performance of alkaline direct ethanol fuel cell (ADEFC) by using carbon-supported Pd, PdSn, PdNi, and PdNiSn produced by impregnation-reduction of the metallic precursors. The effect of chemical functionalization by acid treatment of the carbon support (Vulcan) was investigated. The electrocatalysts were studied by thermogravimetric analysis (TGA), X-rays diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry (CV), and ADEFC tests. TGA measurements of functionalized Vulcan evidenced the characteristic weight losses attributed to the presence of surface functional groups due to the acid treatment. A high degree of alloying between Pd and Sn was inferred from XRD data, whereas in both PdNi and PdNiSn, Ni occurs mostly segregated in the oxide form. TEM analyses indicated agglomeration of Pd and PdSn particles, whereas a more uniform particle distribution was observed for PdNi and PdNiSn samples. CV curves showed that the peak potential for the oxidation of ethanol shifts towards negative values for all samples supported on functionalized Vulcan indicating that ethanol oxidation is facilitated. Microstructural and electrochemical features were confirmed by ADEFC tests, which revealed that the highest open circuit voltage and maximum power density were achieved for PdNiSn electrocatalysts supported on functionalized Vulcan with uniform particle distribution and improved triple phase boundaries. (author)

  7. High-performance micro-solid oxide fuel cells fabricated on nanoporous anodic aluminum oxide templates

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Chang-Woo; Kim, Hyun-Mi; Kim, Ki-Bum [WCUHybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul, 151-742 (Korea, Republic of); Son, Ji-Won; Lee, Jong-Ho; Lee, Hae-Weon [High Temperature Energy Materials Center, Korea Institute of Science and Technology, 39-1, Hawolgok-dong, Seongbuk-gu, Seoul, 136-791 (Korea, Republic of)

    2011-03-22

    Micro-solid oxide fuel cells ({mu}-SOFCs) are fabricated on nanoporous anodic aluminum oxide (AAO) templates with a cell structure composed of a 600-nm-thick AAO free-standing membrane embedded on a Si substrate, sputter-deposited Pt electrodes (cathode and anode) and an yttria-stabilized zirconia (YSZ) electrolyte deposited by pulsed laser deposition (PLD). Initially, the open circuit voltages (OCVs) of the AAO-supported {mu}-SOFCs are in the range of 0.05 V to 0.78 V, which is much lower than the ideal value, depending on the average pore size of the AAO template and the thickness of the YSZ electrolyte. Transmission electron microscopy (TEM) analysis reveals the formation of pinholes in the electrolyte layer that originate from the porous nature of the underlying AAO membrane. In order to clog these pinholes, a 20-nm thick Al{sub 2}O{sub 3} layer is deposited by atomic layer deposition (ALD) on top of the 300-nm thick YSZ layer and another 600-nm thick YSZ layer is deposited after removing the top intermittent Al{sub 2}O{sub 3} layer. Fuel cell devices fabricated in this way manifest OCVs of 1.02 V, and a maximum power density of 350 mW cm{sup -2} at 500 C. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. A Study on the Influence of Fuel Pipe on Fuel Injection Characteristics of Each Nozzle Hole in Diesel Injector

    Directory of Open Access Journals (Sweden)

    Luo Fuqiang

    2016-01-01

    Full Text Available The inner diameter of high pressure fuel pipe has a significant effect on the fuel injection process and the performance of a diesel engine. The spray impact force of each nozzle hole of a conventional injection system of pump-line-nozzle for diesel engine (based on the spray momentum flux and the injection pressure (on a fuel injection pump test rig were measured. With varying fuel injection quantities and pump speed, the effects of the inner diameter of the high pressure fuel pipe on fuel injection process and the fuel injection characteristics of each nozzle hole were analyzed. It was noted from experimental results that the fuel injection pressure changes with variations in the inner diameter of the high pressure fuel pipe and also the injection duration gradually increases with increase in the inner diameter. At low injection pump speed, even with the same geometric fuel deliver rate, the injection duration also increases gradually. Due to throttling effect and reduction in injection pressure, the fuel injection quantities of the injection nozzle were relatively minimal when the inner diameters of the high pressure fuel pipe were respectively small and large. The optimum injection pipe inner diameter for the right quantity for fuel injection falls between the two cases (between small and large. In addition, the injection rate of each nozzle hole increases with the decrease in angle between the needle axis and each of the nozzle hole axis. The fuel injection quantity of each nozzle hole increases while their relative difference decreases with increasing pump speed.

  9. Fundamental Studies of Irradiation-Induced Defect Formation and Fission Product Dynamics in Oxide Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Stubbins, James

    2012-12-19

    The objective of this research program is to address major nuclear fuels performance issues for the design and use of oxide-type fuels in the current and advanced nuclear reactor applications. Fuel performance is a major issue for extending fuel burn-up which has the added advantage of reducing the used fuel waste stream. It will also be a significant issue with respect to developing advanced fuel cycle processes where it may be possible to incorporate minor actinides in various fuel forms so that they can be 'burned' rather than join the used fuel waste stream. The potential to fission or transmute minor actinides and certain long-lived fission product isotopes would transform the high level waste storage strategy by removing the need to consider fuel storage on the millennium time scale.

  10. Simulation of Thermal, Neutronic and Radiation Characteristics in Spent Nuclear Fuel and Radwaste Facilities

    International Nuclear Information System (INIS)

    Poskas, P.; Bartkus, G.

    1999-01-01

    The overview of the activities in the Division of Thermo hydro-mechanics related with the assessment of thermal, neutronic and radiation characteristics in spent nuclear fuel and radwaste facilities are performed. Also some new data about radiation characteristics of the RBMK-1500 spent nuclear fuel are presented. (author)

  11. Lanthanum manganate based cathodes for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Juhl Joergensen, M.

    2001-07-01

    Composite cathodes for solid oxide fuel cells were investigated using electrochemical impedance spectroscopy and scanning electron microscopy. The aim was to study the oxygen reduction process in the electrode in order to minimise the voltage drop in the cathode. The electrodes contained a composite layer made from lanthanum strontium manganate (LSM) and yttria stabilised zirconia (YSZ) and a layer of pure LSM aimed for current collection. The performance of the composite electrodes was sensitive to microstructure and thickness. Further, the interface between the composite and the current collecting layer proved to affect the performance. In a durability study severe deg-radation of the composite electrodes was found when passing current through the electrode for 2000 hours at 1000 deg. C. This was ascribed to pore formation along the composite interfaces and densification of the composite and current collector microstructure. An evaluation of the measurement approach indicated that impedance spectroscopy is a very sensitive method. This affects the reproducibility, as small undesirable variations in for instance the microstructure from electrode to electrode may change the impedance. At least five processes were found to affect the impedance of LSM/YSZ composite electrodes. Two high frequency processes were ascribed to transport of oxide ions/oxygen intermediates across LSM/YSZ interfaces and through YSZ in the composite. Several competitive elementary reaction steps, which appear as one medium frequency process in the impedance spectra, were observed. A low frequency arc related to gas diffusion limitation in a stagnant gas layer above the composite structure was detected. Finally, an inductive process, assumed to be connected to an activation process involving segregates at the triple phase boundary between electrode, electrolyte and gas phase, was found. (au)

  12. Carbon deposition thresholds on nickel-based solid oxide fuel cell anodes I. Fuel utilization

    Science.gov (United States)

    Kuhn, J.; Kesler, O.

    2015-03-01

    In the first of a two part publication, the effect of fuel utilization (Uf) on carbon deposition rates in solid oxide fuel cell nickel-based anodes was studied. Representative 5-component CH4 reformate compositions (CH4, H2, CO, H2O, & CO2) were selected graphically by plotting the solutions to a system of mass-balance constraint equations. The centroid of the solution space was chosen to represent a typical anode gas mixture for each nominal Uf value. Selected 5-component and 3-component gas mixtures were then delivered to anode-supported cells for 10 h, followed by determination of the resulting deposited carbon mass. The empirical carbon deposition thresholds were affected by atomic carbon (C), hydrogen (H), and oxygen (O) fractions of the delivered gas mixtures and temperature. It was also found that CH4-rich gas mixtures caused irreversible damage, whereas atomically equivalent CO-rich compositions did not. The coking threshold predicted by thermodynamic equilibrium calculations employing graphite for the solid carbon phase agreed well with empirical thresholds at 700 °C (Uf ≈ 32%); however, at 600 °C, poor agreement was observed with the empirical threshold of ∼36%. Finally, cell operating temperatures correlated well with the difference in enthalpy between the supplied anode gas mixtures and their resulting thermodynamic equilibrium gas mixtures.

  13. Internal shorting and fuel loss of a low temperature solid oxide fuel cell with SDC electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xinge; Robertson, Mark; Deces-Petit, Cyrille; Qu, Wei; Kesler, Olivera; Maric, Radenka; Ghosh, Dave [Institute for Fuel Cell Innovation, National Research Council Canada, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5 (Canada)

    2007-02-10

    A solid oxide fuel cell with Sm{sub 0.2}Ce{sub 0.8}O{sub 1.9} (SDC) electrolyte of 10 {mu}m in thickness and Ni-SDC anode of 15 {mu}m in thickness on a 0.8 mm thick Ni-YSZ cermet substrate was fabricated by tape casting, screen printing and co-firing. A composite cathode, 75 wt.% Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3} (SSCo) + 25 wt.% SDC, approximately 50 {mu}m in thickness, was printed on the co-fired half-cell, and sintered at 950 C. The cell showed a high electrochemical performance at temperatures ranging from 500 to 650 C. Peak power density of 545 mW cm{sup -2} at 600 C was obtained. However, the cell exhibited severe internal shorting due to the mixed conductivity of the SDC electrolyte. Both the amount of water collected from the anode outlet and the open circuit voltage (OCV) indicated that the internal shorting current could reach 0.85 A cm{sup -2} or more at 600 C. Zr content inclusions were found at the surface and in the cross-section of the SDC electrolyte, which could be one of the reasons for reduced OCV and oxygen ionic conductivity. Fuel loss due to internal shorting of the thin SDC electrolyte cell becomes a significant concern when it is used in applications requiring high fuel utilization and electrical efficiency. (author)

  14. Physical characteristics of GE [General Electric] BWR [boiling-water reactor] fuel assemblies

    International Nuclear Information System (INIS)

    Moore, R.S.; Notz, K.J.

    1989-06-01

    The physical characteristics of fuel assemblies manufactured by the General Electric Company for boiling-water reactors are classified and described. The classification into assembly types is based on the GE reactor product line, the Characteristics Data Base (CDB) assembly class, and the GE fuel design. Thirty production assembly types are identified. Detailed physical data are presented for each assembly type in an appendix. Descriptions of special (nonstandard) fuels are also reported. 52 refs., 1 fig., 6 tabs

  15. Thermodynamic Analysis of an Integrated Solid Oxide Fuel Cell Cycle with a Rankine Cycle

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2010-01-01

    Hybrid systems consisting of Solid Oxide Fuel Cells (SOFC) on the top of a Steam Turbine (ST) are investigated. The plants are fired by natural gas (NG). A desulfurization reactor removes the sulfur content in the fuel while a pre-reformer breaks down the heavier hydrocarbons. The pre-treated fuel......% are achieved which is considerably higher than the conventional Combined Cycles (CC). Both ASR (Adiabatic Steam Reformer) and CPO (Catalytic Partial Oxidation) fuel pre-reformer reactors are considered in this investigation....

  16. Experimental study on oxidation and combustion characteristics of sodium droplets

    International Nuclear Information System (INIS)

    Zhang Zhigang; Sun Shubin; Liu Chongchong; Tang Yexin

    2015-01-01

    In the operation of the sodium-cooled fast reactor, the accident caused by the leakage and combustion of liquid sodium is common and frequent. In this paper, the oxidation and combustion characteristics of sodium droplets were studied by carrying out the experiments of the oxidation and combustion under different conditions of initial temperatures (140-370℃) of the sodium droplets and oxygen concentrations (4%-21%). The oxidation and combustion behaviors were visualized by a set of combustion apparatus of sodium droplet and a high speed camera. The experiment results show that the columnar oxides grow longer as the initial temperature of sodium droplet and oxygen concentration become lower. Under the same oxygen concentration condition, the sodium droplet with the higher initial temperature is easier to ignite and burn. When the initial temperature of sodium droplet is below 200℃, it is very difficult to ignite. If there is a turbulence damaging the oxide layer on the surface, the sodium droplet will also burn gradually. When the initial temperature ranges from 140℃ to 370℃ and the oxygen fraction is equal to or higher than 12%, the sodium droplet could burn completely and the maximum combustion temperature could roughly reach 600-800℃. When the oxygen concentration is below 12%, the sodium droplet could not burn completely and the highest combustion temperature is below 600℃. The results are helpful to the research on the columnar flow and spray sodium fire. (authors)

  17. Effects of diesel/ethanol dual fuel on emission characteristics in a heavy-duty diesel engine

    Science.gov (United States)

    Liu, Junheng; Sun, Ping; Zhang, Buyun

    2017-09-01

    In order to reduce emissions and diesel consumption, the gas emissions characteris-tics of diesel/aqueous ethanol dual fuel combustion (DFC) were carried out on a heavy-duty turbocharged and intercooled automotive diesel engine. The aqueous ethanol is prepared by a blend of anhydrous ethanol and water in certain volume proportion. In DFC mode, aqueous ethanol is injected into intake port to form homogeneous charge, and then ignited by the diesel fuel. Results show that DFC can reduce NOx emissions but increase HC and CO emissions, and this trend becomes more prominent with the increase of water blending ratio. Increased emissions of HC and CO could be efficiently cleaned by diesel oxidation catalytic converter (DOC), even better than those of diesel fuel. It is also found that DFC mode reduces smoke remarkably, while increases some unconventional emissions such as formaldehyde and acetal-dehyde. However, unconventional emissions could be reduced approximately to the level of baseline engine with a DOC.

  18. Numerical analysis of spray characteristics of dimethyl ether and diethyl ether fuel

    International Nuclear Information System (INIS)

    Mohan, Balaji; Yang, Wenming; Yu, Wenbin; Tay, Kun Lin

    2017-01-01

    Highlights: • Thermo-physical properties of liquid DME and DEE are reported. • Ether fuels tend to cavitate higher compared to that of diesel fuel. • Spray tip penetration and SMD are found to be lesser for ether fuels. • Ether fuels shows excellent atomization behavior. - Abstract: In this work, the spray characteristics of ether fuels such as dimethyl ether (DME) and diethyl ether (DEE) have been numerically investigated using KIVA-4 CFD code. A new hybrid spray model developed by coupling the standard KHRT model to cavitation sub model was used. The detailed thermo-physical properties of ether fuels have been predicted and validated with experimental results available from literature. The cavitation inception inside the injector nozzle hole has been studied for ether fuels in comparison with diesel fuel. It was found that ether fuels cavitates higher compared to that of conventional diesel fuel because of its low viscosity. The spray tip penetration of diesel fuel was longer than that of ether fuels due to high viscosity and density of diesel fuel. Ether fuels characterized by low Ohnesorge number and high Reynolds number showed better atomization behavior compared to that of the diesel fuel.

  19. Solid oxide fuel cells with bi-layered electrolyte structure

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xinge; Robertson, Mark; Deces-Petit, Cyrille; Xie, Yongsong; Hui, Rob; Qu, Wei; Kesler, Olivera; Maric, Radenka; Ghosh, Dave [Institute for Fuel Cell Innovation, National Research Council Canada, 4250 Wesbrook Mall, Vancouver, B.C. V6T 1W5 (Canada)

    2008-01-10

    In this work, we have developed solid oxide fuel cells with a bi-layered electrolyte of 2 {mu}m SSZ and 4 {mu}m SDC using tape casting, screen printing, and co-firing processes. The cell reached power densities of 0.54 W cm{sup -2} at 650 C and 0.85 W cm{sup -2} at 700 C, with open circuit voltage (OCV) values larger than 1.02 V. The electrical leaking between anode and cathode through an SDC electrolyte has been blocked in the bi-layered electrolyte structure. However, both the electrolyte resistance (R{sub el}) and electrode polarization resistance (R{sub p,a+c}) increased in comparison to cells with single-layered SDC electrolytes. The formation of a solid solution of (Ce, Zr)O{sub 2-x} during sintering process and the flaws in the bi-layered electrolyte structure seem to be the main causes for the increase in the R{sub el} value (0.32 {omega} cm{sup 2}) at 650 C, which is almost one order of magnitude higher than the calculated value. (author)

  20. Innovative Seals for Solid Oxide Fuel Cells (SOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Raj

    2008-06-30

    A functioning SOFC requires different type of seals such as metal-metal, metal-ceramic, and ceramic-ceramic. These seals must function at high temperatures between 600--900{sup o}C and in oxidizing and reducing environments of the fuels and air. Among the different type of seals, the metal-metal seals can be readily fabricated using metal joining, soldering, and brazing techniques. However, the metal-ceramic and ceramic-ceramic seals require significant research and development because the brittle nature of ceramics/glasses can lead to fracture and loss of seal integrity and functionality. Consequently, any seals involving ceramics/glasses require a significant attention and technology development for reliable SOFC operation. This final report is prepared to describe the progress made in the program on the needs, approaches, and performance of high temperature seals for SOFC. In particular, a new concept of self-healing glass seals is pursued for making seals between metal-ceramic material combinations, including some with a significant expansion mismatch.

  1. Internal reforming of methane in solid oxide fuel cell systems

    Science.gov (United States)

    Peters, R.; Dahl, R.; Klüttgen, U.; Palm, C.; Stolten, D.

    Internal reforming is an attractive option offering a significant cost reduction, higher efficiencies and faster load response of a solid oxide fuel cell (SOFC) power plant. However, complete internal reforming may lead to several problems which can be avoided with partial pre-reforming of natural gas. In order to achieve high total plant efficiency associated with low energy consumption and low investment costs, a process concept has been developed based on all the components of the SOFC system. In the case of anode gas recycling an internal steam circuit exists. This has the advantage that there is no need for an external steam generator and the steam concentration in the anode gas is reduced. However, anode gas recycling has to be proven by experiments in a pre-reformer and for internal reforming. The addition of carbon dioxide clearly shows a decrease in catalyst activity, while for temperatures higher than 1000 K hydrogen leads to an increase of the measured methane conversion rates.

  2. Constrained Sintering in Fabrication of Solid Oxide Fuel Cells.

    Science.gov (United States)

    Lee, Hae-Weon; Park, Mansoo; Hong, Jongsup; Kim, Hyoungchul; Yoon, Kyung Joong; Son, Ji-Won; Lee, Jong-Ho; Kim, Byung-Kook

    2016-08-09

    Solid oxide fuel cells (SOFCs) are inevitably affected by the tensile stress field imposed by the rigid substrate during constrained sintering, which strongly affects microstructural evolution and flaw generation in the fabrication process and subsequent operation. In the case of sintering a composite cathode, one component acts as a continuous matrix phase while the other acts as a dispersed phase depending upon the initial composition and packing structure. The clustering of dispersed particles in the matrix has significant effects on the final microstructure, and strong rigidity of the clusters covering the entire cathode volume is desirable to obtain stable pore structure. The local constraints developed around the dispersed particles and their clusters effectively suppress generation of major process flaws, and microstructural features such as triple phase boundary and porosity could be readily controlled by adjusting the content and size of the dispersed particles. However, in the fabrication of the dense electrolyte layer via the chemical solution deposition route using slow-sintering nanoparticles dispersed in a sol matrix, the rigidity of the cluster should be minimized for the fine matrix to continuously densify, and special care should be taken in selecting the size of the dispersed particles to optimize the thermodynamic stability criteria of the grain size and film thickness. The principles of constrained sintering presented in this paper could be used as basic guidelines for realizing the ideal microstructure of SOFCs.

  3. Constrained Sintering in Fabrication of Solid Oxide Fuel Cells

    Science.gov (United States)

    Lee, Hae-Weon; Park, Mansoo; Hong, Jongsup; Kim, Hyoungchul; Yoon, Kyung Joong; Son, Ji-Won; Lee, Jong-Ho; Kim, Byung-Kook

    2016-01-01

    Solid oxide fuel cells (SOFCs) are inevitably affected by the tensile stress field imposed by the rigid substrate during constrained sintering, which strongly affects microstructural evolution and flaw generation in the fabrication process and subsequent operation. In the case of sintering a composite cathode, one component acts as a continuous matrix phase while the other acts as a dispersed phase depending upon the initial composition and packing structure. The clustering of dispersed particles in the matrix has significant effects on the final microstructure, and strong rigidity of the clusters covering the entire cathode volume is desirable to obtain stable pore structure. The local constraints developed around the dispersed particles and their clusters effectively suppress generation of major process flaws, and microstructural features such as triple phase boundary and porosity could be readily controlled by adjusting the content and size of the dispersed particles. However, in the fabrication of the dense electrolyte layer via the chemical solution deposition route using slow-sintering nanoparticles dispersed in a sol matrix, the rigidity of the cluster should be minimized for the fine matrix to continuously densify, and special care should be taken in selecting the size of the dispersed particles to optimize the thermodynamic stability criteria of the grain size and film thickness. The principles of constrained sintering presented in this paper could be used as basic guidelines for realizing the ideal microstructure of SOFCs. PMID:28773795

  4. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    Energy Technology Data Exchange (ETDEWEB)

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  5. Mixing Characteristics during Fuel Coolant Interaction under Reactor Submerged Conditions

    International Nuclear Information System (INIS)

    Hong, S. W.; Na, Y. S.; Hong, S. H.; Song, J. H.

    2014-01-01

    A molten material is injected into an interaction chamber by free gravitation fall. This type of fuel coolant interaction could happen to operating plants. However, the flooding of a reactor cavity is considered as SAM measures for new PWRs such as APR-1400 and AP1000 to assure the IVR of a core melt. In this case, a molten corium in a reactor is directly injected into water surrounding the reactor vessel without a free fall. KAERI has carried out fuel coolant interaction tests without a free fall using ZrO 2 and corium to simulate the reactor submerged conditions. There are four phases in a steam explosion. The first phase is a premixing phase. The premixing is described in the literature as follows: during penetration of melt into water, hydrodynamic instabilities, generated by the velocities and density differences as well as vapor production, induce fragmentation of the melt into particles; the particles fragment in turn into smaller particles until they reach a critical size such that the cohesive forces (surface tension) balance exactly the disruptive forces (inertial); and the molten core material temperature (>2500 K) is such that the mixing always occurs in the film boiling regime of the water: It is very important to qualify and quantify this phase because it gives the initial conditions for a steam explosion This paper mainly focuses on the observation of the premixing phase between a case with 1 m free fall and a case without a free fall to simulate submerged reactor condition. The premixing behavior between a 1m free fall case and reactor case submerged without a free fall is observed experimentally. The average velocity of the melt front passing through 1m water pool; - Case without a free fall: The average velocity of corium, 2.7m/s, is faster than ZrO 2 , 2.3m/s, in water. - Cases of with a 1 m free fall and without a free fall : The case without a free fall is about two times faster than a case with a 1 m free fall. Bubble characteristics; - Case

  6. Mathematical modeling of synthesis gas fueled electrochemistry and transport including H2/CO co-oxidation and surface diffusion in solid oxide fuel cell

    Science.gov (United States)

    Bao, Cheng; Jiang, Zeyi; Zhang, Xinxin

    2015-10-01

    Fuel flexibility is a significant advantage of solid oxide fuel cell (SOFC). A comprehensive macroscopic framework is proposed for synthesis gas (syngas) fueled electrochemistry and transport in SOFC anode with two main novelties, i.e. analytical H2/CO electrochemical co-oxidation, and correction of gas species concentration at triple phase boundary considering competitive absorption and surface diffusion. Staring from analytical approximation of the decoupled charge and mass transfer, we present analytical solutions of two defined variables, i.e. hydrogen current fraction and enhancement factor. Giving explicit answer (rather than case-by-case numerical calculation) on how many percent of the current output contributed by H2 or CO and on how great the water gas shift reaction plays role on, this approach establishes at the first time an adaptive superposition mechanism of H2-fuel and CO-fuel electrochemistry for syngas fuel. Based on the diffusion equivalent circuit model, assuming series-connected resistances of surface diffusion and bulk diffusion, the model predicts well at high fuel utilization by keeping fixed porosity/tortuosity ratio. The model has been validated by experimental polarization behaviors in a wide range of operation on a button cell for H2-H2O-CO-CO2-N2 fuel systems. The framework could be helpful to narrow the gap between macro-scale and meso-scale SOFC modeling.

  7. Effects of an oxidizing atmosphere in a spent fuel packaging facility

    International Nuclear Information System (INIS)

    Einziger, R.E.

    1991-09-01

    Sufficient oxidation of spent fuel can cause a cladding breach to propagate, resulting in dispersion of fuel particulates and gaseous radionuclides. The literature for spent fuel oxidation in storage and disposal programs was reviewed to evaluate the effect of an oxidizing atmosphere in a preclosure packaging facility on (1) physical condition of the fuel and (2) operations in the facility. Effects such as cladding breach propagation, cladding oxidation, rod dilation, fuel dispersal, 14 C and 85 Kr release, and crud release were evaluated. The impact of these effects, due to oxidation, upon a spent fuel handling facility is generally predicted to be less than the impact of similar effects due to fuel rod breached during handling in an inert-atmosphere facility. Preliminary temperature limits of 240 degree C and 227 degree C for a 2-week or 4-week handling period and 175 degree C for 2-year lag storage would prevent breach propagation and fuel dispersal. Additional data that are needed to support the assumptions in this analysis or complete the database were identified

  8. Effect of increased fuel temperature on emissions of oxides of nitrogen from a gas turbine combustor burning ASTM jet-A fuel

    Science.gov (United States)

    Marchionna, N. R.

    1974-01-01

    An annular gas turbine combustor was tested with heated ASTM Jet-A fuel to determine the effect of increased fuel temperature on the formation of oxides of nitrogen. Fuel temperature ranged from ambient to 700 K. The NOx emission index increased at a rate of 6 percent per 100 K increase in fuel temperature.

  9. Modeling of thermo-mechanical and irradiation behavior of mixed oxide fuel for sodium fast reactors

    International Nuclear Information System (INIS)

    Karahan, Aydin; Buongiorno, Jacopo

    2010-01-01

    An engineering code to model the irradiation behavior of UO 2 -PuO 2 mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named fuel engineering and structural analysis tool (FEAST-OXIDE). FEAST-OXIDE has several modules working in coupled form with an explicit numerical algorithm. These modules describe: (1) fission gas release and swelling, (2) fuel chemistry and restructuring, (3) temperature distribution, (4) fuel-clad chemical interaction and (5) fuel-clad mechanical analysis. Given the fuel pin geometry, composition and irradiation history, FEAST-OXIDE can analyze fuel and cladding thermo-mechanical behavior at both steady-state and design-basis transient scenarios. The code was written in FORTRAN-90 program language. The mechanical analysis module implements the LIFE algorithm. Fission gas release and swelling behavior is described by the OGRES and NEFIG models. However, the original OGRES model has been extended to include the effects of joint oxide gain (JOG) formation on fission gas release and swelling. A detailed fuel chemistry model has been included to describe the cesium radial migration and JOG formation, oxygen and plutonium radial distribution and the axial migration of cesium. The fuel restructuring model includes the effects of as-fabricated porosity migration, irradiation-induced fuel densification, grain growth, hot pressing and fuel cracking and relocation. Finally, a kinetics model is included to predict the clad wastage formation. FEAST-OXIDE predictions have been compared to the available FFTF, EBR-II and JOYO databases, as well as the LIFE-4 code predictions. The agreement was found to be satisfactory for steady-state and slow-ramp over-power accidents.

  10. Modeling of thermo-mechanical and irradiation behavior of mixed oxide fuel for sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Karahan, Aydin, E-mail: karahan@mit.ed [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology, MA (United States); Buongiorno, Jacopo [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology, MA (United States)

    2010-01-31

    An engineering code to model the irradiation behavior of UO{sub 2}-PuO{sub 2} mixed oxide fuel pins in sodium-cooled fast reactors was developed. The code was named fuel engineering and structural analysis tool (FEAST-OXIDE). FEAST-OXIDE has several modules working in coupled form with an explicit numerical algorithm. These modules describe: (1) fission gas release and swelling, (2) fuel chemistry and restructuring, (3) temperature distribution, (4) fuel-clad chemical interaction and (5) fuel-clad mechanical analysis. Given the fuel pin geometry, composition and irradiation history, FEAST-OXIDE can analyze fuel and cladding thermo-mechanical behavior at both steady-state and design-basis transient scenarios. The code was written in FORTRAN-90 program language. The mechanical analysis module implements the LIFE algorithm. Fission gas release and swelling behavior is described by the OGRES and NEFIG models. However, the original OGRES model has been extended to include the effects of joint oxide gain (JOG) formation on fission gas release and swelling. A detailed fuel chemistry model has been included to describe the cesium radial migration and JOG formation, oxygen and plutonium radial distribution and the axial migration of cesium. The fuel restructuring model includes the effects of as-fabricated porosity migration, irradiation-induced fuel densification, grain growth, hot pressing and fuel cracking and relocation. Finally, a kinetics model is included to predict the clad wastage formation. FEAST-OXIDE predictions have been compared to the available FFTF, EBR-II and JOYO databases, as well as the LIFE-4 code predictions. The agreement was found to be satisfactory for steady-state and slow-ramp over-power accidents.

  11. Fuel Cell Power Plant Initiative. Volume 1; Solid Oxide Fuel Cell/Logistics Fuel Processor 27 kWe Power System Demonstration for ARPA

    Science.gov (United States)

    Veyo, S.E.

    1997-01-01

    This report describes the successful testing of a 27 kWe Solid Oxide Fuel Cell (SOFC) generator fueled by natural gas and/or a fuel gas produced by a brassboard logistics fuel preprocessor (LFP). The test period began on May 24, 1995 and ended on February 26, 1996 with the successful completion of all program requirements and objectives. During this time period, this power system produced 118.2 MWh of electric power. No degradation of the generator's performance was measured after 5582 accumulated hours of operation on these fuels: local natural gas - 3261 hours, jet fuel reformate gas - 766 hours, and diesel fuel reformate gas - 1555 hours. This SOFC generator was thermally cycled from full operating temperature to room temperature and back to operating temperature six times, because of failures of support system components and the occasional loss of test site power, without measurable cell degradation. Numerous outages of the LFP did not interrupt the generator's operation because the fuel control system quickly switched to local natural gas when an alarm indicated that the LFP reformate fuel supply had been interrupted. The report presents the measured electrical performance of the generator on all three fuel types and notes the small differences due to fuel type. Operational difficulties due to component failures are well documented even though they did not affect the overall excellent performance of this SOFC power generator. The final two appendices describe in detail the LFP design and the operating history of the tested brassboard LFP.

  12. Dry air oxidation kinetics of K-Basin spent nuclear fuel

    International Nuclear Information System (INIS)

    Abrefah, J.; Buchanan, H.C.; Gerry, W.M.; Gray, W.J.; Marschman, S.C.

    1998-06-01

    The safety and process analyses of the proposed Integrated Process Strategy (IPS) to move the N-Reactor spent nuclear fuel (SNF) stored at K-Basin to an interim storage facility require information about the oxidation behavior of the metallic uranium. Limited experiments have been performed on the oxidation reaction of SNF samples taken from an N-Reactor outer fuel element in various atmospheres. This report discusses studies on the oxidation behavior of SNF using two independent experimental systems: (1) a tube furnace with a flowing gas mixture of 2% oxygen/98% argon; and (2) a thermogravimetric system for dry air oxidation

  13. PERFORMANCE, EMISSION, AND COMBUSTION CHARACTERISTICS OF A CI ENGINE USING LIQUID PETROLEUM GAS AND NEEM OIL IN DUAL FUEL MODE

    Directory of Open Access Journals (Sweden)

    Palanimuthu Vijayabalan

    2010-01-01

    Full Text Available Increased environmental awareness and depletion of resources are driving the industries to develop viable alternative fuels like vegetable oils, compresed natural gas, liquid petroleum gas, producer gas, and biogas in order to provide suitable substitute to diesel for compression ignition engine. In this investigation, a single cylinder, vertical, air-cooled diesel engine was modified to use liquid petroleum gas in dual fuel mode. The liquefied petroleum gas, was mixed with air and supplied through intake manifold. The liquid fuel neem oil or diesel was injected into the combustion chamber. The performance, emission, and combustion characteristics were studied and compared for neat fuel and dual fuel mode. The experimental results on dual fuel engine show a reduction in oxides of nitrogen up to 70% of the rated power and smoke in the entire power range. However the brake thermal efficiency was found decreased in low power range due to lower calorific value of liquid petroleum gas, and increase in higher power range due to the complete burning of liquid petroleum gas. Hydrocarbon and carbon monoxide emissions were increased significantly at lower power range and marginal variation in higher power range.

  14. Tritium distribution between the fuel can and the oxide of fuel elements of light-water reactors

    International Nuclear Information System (INIS)

    Masson, M.

    1986-12-01

    The study on the measurement of tritium and other radionuclide contained in zircaloy fuel cans of the water cooled reactor fuel elements had two aims: the first was to estimate with accuracy the distribution of tritium in a fuel element (can + oxide). The measurement of tritium in the zircaloy fuel cans of the BORSSELE fuel elements associated with the measurement of tritium in the oxide allowed the establishment of a complete tritium balance on an industrial spent fuel element. This result has been compared to the values calculated by the code CEA/SEN and will allow to validate or adjust this calculation. The second aim delt with the characterization of the other radionuclides gaseous (Kr85) or not (Cs 134 and 137) contained in the solid zircaloy wastes (hulls) coming from the industrial reprocessing of ''water cooled'' fuel elements. These activity measurements in the hulls allowed to estimate the residual content of tritium, Kr 85 and other radionuclides which may be found in these solid wastes (high-level βγ radioactive wastes). Original experimental methods have been developed to reach these aims (dissolution in ammonium bifluoride medium and quantitative recovery of gases produced, radiochromatography, and liquid scintillation after double distillation). One tries to explain the presence of Kr 85 in the irradiated can [fr

  15. Solid oxide fuel cells for transportation: A clean, efficient alternative for propulsion

    International Nuclear Information System (INIS)

    Kumar, R.; Krumpelt, M.; Myles, K.M.

    1993-01-01

    Fuel cells show great promise for providing clean and efficient transportation power. Of the fuel cell propulsion systems under investigation, the solid oxide fuel cell (SOFC) is particularly attractive for heavy duty transportation applications that have a relatively long duty cycle, such as locomotives, trucks, and barges. Advantages of the SOFC include a simple, compact system configuration; inherent fuel flexibility for hydrocarbon and alternative fuels; and minimal water management. The specific advantages of the SOFC for powering a railroad locomotive are examined. Feasibility, practicality, and safety concerns regarding SOFCs in transportation applications are discussed, as am the major R ampersand D issues

  16. Neutronic feasibility of PWR core with mixed oxide fuels in the Republic of Korea

    International Nuclear Information System (INIS)

    Kim, Y.J.; Joo, H.K.; Jung, H.G.; Sohn, D.S.

    1997-01-01

    Neutronic feasibility of a PWR core with mixed oxide (MOX) fuels has been investigated as part of the feasibility study for recycling spent fuels in Korea. A typical 3-loop PWR with 900 MWe capacity is selected as reference plant to develop equilibrium core designs with low-leakage fuel management scheme, while incorporating various MOX loading. The fuel management analyses and limited safety analyses show that, safely stated, MOX recycling with 1/3 reload fraction can be accommodated for both annual and 18 month fuel cycle schemes in Korean PWRs, without major design modifications on the reactor systems. (author). 12 refs, 4 figs, 3 tabs

  17. Fuzzy Logic Based Controller for a Grid-Connected Solid Oxide Fuel Cell Power Plant.

    Science.gov (United States)

    Chatterjee, Kalyan; Shankar, Ravi; Kumar, Amit

    2014-10-01

    This paper describes a mathematical model of a solid oxide fuel cell (SOFC) power plant integrated in a multimachine power system. The utilization factor of a fuel stack maintains steady state by tuning the fuel valve in the fuel processor at a rate proportional to a current drawn from the fuel stack. A suitable fuzzy logic control is used for the overall system, its objective being controlling the current drawn by the power conditioning unit and meet a desirable output power demand. The proposed control scheme is verified through computer simulations.

  18. Influences of Fuel Additive, Crude Palm and Waste Cooking Oil on Emission Characteristics of Small Diesel Engine

    Science.gov (United States)

    Khalid, Amir; Jaat, Norrizam; Manshoor, Bukhari; Zaman, Izzuddin; Sapit, Azwan; Razali, Azahari; Basharie, Mariam

    2017-08-01

    Major research has been conducted on the use of input products, such as rapeseed, canola, soybean, sunflower oil, waste cooking oil (WCO), crude palm oil (CPO) and crude jatropha oil as alternative fuels. Biodiesel is renewable, biodegradable and oxygenated, where it can be easily adopted by current existing conventional diesel engine without any major modification of the engine. To meet the future performance and emission regulations, is urged to improve the performance and exhaust emissions from biodiesel fuels. Hence, further investigation have been carried out on the emission characteristics of small diesel engine that fuelled by variant blending ratio of WCO and CPO with booster additive. For each of the biodiesel blends ratio from 5 to 15 percent volume which are WCO5, WCO10 and WCO15 for WCO biodiesel and CPO5, CPO10 and CPO15 for CPO biodiesel. The exhaust emissions were measured at engine speeds varied at 2000 rpm and 2500 rpm with different booster additive volume DRA (biodiesel without additive), DRB (0.2 ml) and DRC (0.4 ml). Emissions characteristics that had been measured were Hydrocarbon (HC), Carbon Monoxide (CO), Carbon Dioxide (CO2), Nitrogen Oxide (NOx), and smoke opacity. The results showed that increased of blending ratio with booster additive volume significantly decreased the CO emission, while increased in NOx and CO2 due to changes of fuel characteristics in biodiesel fuel blends.

  19. Pilot-scale equipment development for lithium-based reduction of spent oxide fuel

    International Nuclear Information System (INIS)

    Herrmann, S. D.

    1998-01-01

    An integral function of the electrometallurgical conditioning of DOE spent nuclear fuel is the standardization of waste forms. Argonne National Laboratory (ANL) has developed and is presently demonstrating the electrometallurgical conditioning of sodium-bonded metal fuel from Experimental Breeder Reactor II, resulting in uranium, ceramic waste, and metal waste forms. Engineering studies are underway at ANL in support of pilot-scale equipment development, which would precondition irradiated oxide fuel and likewise demonstrate the application of electrometallurgical conditioning to such non-metallic fuels. This paper highlights the integration of proposed spent oxide fuel conditioning with existing electrometallurgical processes. Additionally, technical bases for engineering activities to support a scale up of an oxide reduction process are described

  20. Application of the monolithic solid oxide fuel cell to space power systems

    International Nuclear Information System (INIS)

    Myles, K.M.; Bhattacharyya, S.K.

    1991-01-01

    The monolithic solid-oxide fuel cell (MSOFC) is a promising electrochemical power generation device that is currently under development at Argonne National Laboratory. The extremely high power density of the MSOFC leads to MSOFC systems that have sufficiently high energy densities that they are excellent candidates for a number of space missions. The fuel cell can also be operated in reverse, if it can be coupled to an external power source, to regenerate the fuel and oxidant from the water product. This feature further enhances the potential mission applications of the MSOFC. In this paper, the current status of the fuel cell development is presented---the focus being on fabrication and currently achievable performance. In addition, a specific example of a space power system, featuring a liquid metal cooled fast spectrum nuclear reactor and a monolithic solid oxide fuel cell, is presented to demonstrate the features of an integrated system

  1. Thermodynamic analysis of Direct Urea Solid Oxide Fuel Cell in combined heat and power applications

    Science.gov (United States)

    Abraham, F.; Dincer, I.

    2015-12-01

    This paper presents a comprehensive steady state modelling and thermodynamic analysis of Direct Urea Solid Oxide Fuel Cell integrated with Gas Turbine power cycle (DU-SOFC/GT). The use of urea as direct fuel mitigates public health and safety risks associated with the use of hydrogen and ammonia. The integration scheme in this study covers both oxygen ion-conducting solid oxide fuel cells (SOFC-O) and hydrogen proton-conducting solid oxide fuel cells (SOFC-H). Parametric case studies are carried out to investigate the effects of design and operating parameters on the overall performance of the system. The results reveal that the fuel cell exhibited the highest level of exergy destruction among other system components. Furthermore, the SOFC-O based system offers better overall performance than that with the SOFC-H option mainly due to the detrimental reverse water-gas shift reaction at the SOFC anode as well as the unique configuration of the system.

  2. Application of the monolithic solid oxide fuel cell to space power systems

    Science.gov (United States)

    Myles, Kevin M.; Bhattacharyya, Samit K.

    1991-01-01

    The monolithic solid-oxide fuel cell (MSOFC) is a promising electrochemical power generation device that is currently under development at Argonne National Laboratory. The extremely high power density of the MSOFC leads to MSOFC systems that have sufficiently high energy densities that they are excellent candidates for a number of space missions. The fuel cell can also be operated in reverse, if it can be coupled to an external power source, to regenerate the fuel and oxidant from the water product. This feature further enhances the potential mission applications of the MSOFC. In this paper, the current status of the fuel cell development is presented—the focus being on fabrication and currently achievable performance. In addition, a specific example of a space power system, featuring a liquid metal cooled fast spectrum nuclear reactor and a monolithic solid oxide fuel cell, is presented to demonstrate the features of an integrated system.

  3. Improving the neutronic characteristics of a boiling water reactor by using uranium zirconium hydride fuel instead of uranium dioxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Galahom, Ahmed Abdelghafar [Higher Technological Institute, Ramadan (Egypt)

    2016-06-15

    The present work discusses two different models of boiling water reactor (BWR) bundle to compare the neutronic characteristics of uranium dioxide (UO{sub 2}) and uranium zirconium hydride (UZrH{sub 1.6}) fuel. Each bundle consists of four assemblies. The BWR assembly fueled with UO{sub 2} contains 8 × 8 fuel rods while that fueled with UZrH{sub 1.6} contains 9 × 9 fuel rods. The Monte Carlo N-Particle Transport code, based on the Mont Carlo method, is used to design three dimensional models for BWR fuel bundles at typical operating temperatures and pressure conditions. These models are used to determine the multiplication factor, pin-by-pin power distribution, axial power distribution, thermal neutron flux distribution, and axial thermal neutron flux. The moderator and coolant (water) are permitted to boil within the BWR core forming steam bubbles, so it is important to calculate the reactivity effect of voiding at different values. It is found that the hydride fuel bundle design can be simplified by eliminating water rods and replacing the control blade with control rods. UZrH{sub 1.6} fuel improves the performance of the BWR in different ways such as increasing the energy extracted per fuel assembly, reducing the uranium ore, and reducing the plutonium accumulated in the BWR through burnup.

  4. Experimental study on spray characteristics of alternate jet fuels using Phase Doppler Anemometry

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza

    2013-11-01

    Gas-to-Liquid (GTL) fuels have gained global attention due to their cleaner combustion characteristics. The chemical and physical properties of GTL jet fuels are different from conventional jet fuels owing to the difference in their production methodology. It is important to study the spray characteristics of GTL jet fuels as the change of physical properties can affect atomization, mixing, evaporation and combustion process, ultimately affecting emission process. In this work, spray characteristics of two GTL synthetic jet fuels are studied using a pressure-swirl nozzle at different injection pressures and atmospheric ambient condition. Phase Doppler Anemometry (PDA) measurements of droplet size and velocity are compared with those of regular Jet A-1 fuel at several axial and radial locations downstream of the nozzle exit. Experimental results show that although the GTL fuels have different physical properties such as viscosity, density, and surface tension, among each other the resultant change in the spray characteristics is insignificant. Furthermore, the presented results show that GTL fuel spray characteristics exhibit close similarity to those of Jet A-1 fuel. Funded by Qatar Science and Technology Park.

  5. Effect of Biodiesel Fuel Injection Timing and Venture for Gaseous Fuel Induction on the Performance, Emissions and Combustion Characteristics of Dual Fuel Engine

    Directory of Open Access Journals (Sweden)

    Mallikarjun Bhovi

    2018-02-01

    Full Text Available Advancing or retarding pilot fuel injection timing in a diesel engine provided with either conventional mechanical fuel injection (CMFIS or high pressure injection as in common rail fuel injection (CRDI systems can significantly affect its performance and tail pipe emissions. Performance of diesel engine when fueled with various biofuels as well as gaseous fuels tends to vary with subsequent changes in pilot fuel injection timings. Biodiesel derived from rubber seed oil called Rubber Seed Oil Methyl Ester (RuOME and hydrogen (H2 and hydrogen enriched compressed natural gas called (HCNG both being renewable fuels when used in diesel engines modified to operate in dual fuel mode can provide complete replacement for fossil diesel. In the present study, effect of injection timings and venture design for gas mixing on the performance, combustion and emission characteristics of dual fuel engine fitted with both CMFIS and CRDI injection systems and operated on RuOME and HCNG/hydrogen has been investigated. Results showed that high pressure CRDI assisted injection of RuOME with optimized mixing chamber (carburetor for hydrogen induction in dual fuel engine performed improved compared to that with CMFIS. In addition, for the same fuel combinations, CRDI resulted in lower biodiesel consumption, lower carbon monoxide (BSCO and hydrocarbon (BSHC emissions and increased NOx emissions than CMFIS operation.

  6. Efficient and Scalable Fabrication of Solid Oxide Fuel Cells via 3D-Printing

    Data.gov (United States)

    National Aeronautics and Space Administration — Although solid oxide fuel cells (SOFCs) are a source of both efficient and clean electricity, the brittle ceramic materials which comprise them are difficult to form...

  7. Novel quasi-symmetric solid oxide fuel cells with enhanced electrochemical performance

    KAUST Repository

    Chen, Yonghong; Cheng, Zhuanxia; Yang, Yang; Gu, Qingwen; Tian, Dong; Lu, Xiaoyong; Yu, Weili; Lin, Bin

    2016-01-01

    Symmetrical solid oxide fuel cell (SSOFC) using same materials as both anode and cathode simultaneously has gained extensively attentions, which can simplify fabrication process, minimize inter-diffusion between components, enhance sulfur and coking

  8. Solid Oxide Fuel Cell Based Upon Colloidal Deposition of Thin Films for Lower Temperature Operation (Preprint)

    National Research Council Canada - National Science Library

    Reitz, T. L; Xiao, H

    2006-01-01

    In order to reduce the operating temperature of solid oxide fuel cells (SOFCs), anode-supported cells incorporating thin film electrolytes in conjunction with anode/electrolyte and cathode/electrolyte interlayers were studied...

  9. Microstructural evolution of nanograin nickel-zirconia cermet anode materials for solid oxide fuel cell applications

    International Nuclear Information System (INIS)

    Nayak, Bibhuti Bhusan

    2012-01-01

    The aim of the study is to study the structure, microstructure, porosity, thermal expansion, electrical conductivity and electrochemical behavior of the anode material thus synthesized in order to find its suitability for solid oxide fuel cell (SOFC) anode application

  10. Development of an engineered safeguards system concept for a mixed-oxide fuel fabrication facility

    International Nuclear Information System (INIS)

    Chapman, L.D.; de Montmollin, J.M.; Deveney, J.E.; Fienning, W.C.; Hickman, J.W.; Watkins, L.D.; Winblad, A.E.

    1976-08-01

    An initial concept of an Engineered Safeguards System for a representative commercial mixed-oxide fuel fabrication facility is presented. Computer simulation techniques for evaluation and further development of the concept are described. An outline of future activity is included

  11. Electroplating of Protective Coatings on Interconnects Used for Solid Oxide Fuel Cell Stacks

    DEFF Research Database (Denmark)

    Harthøj, Anders

    Solid oxide fuel Cell (SOFC) technology can with a high efficiency produce environmentally clean electricity by converting the chemical energy in a fuel to electrical energy. SOFC systems have a high operation temperature, approx. 600-850 °C. Advantages compared to other types of fuel cells......, are they can utilize a wide range of fuels, e.g. hydrogen, natural gas and methanol, do not contain noble metals and have a high efficiency. A major obstacle to the commercialization of SOFC technology is the high degradation rates and costs of the systems. A significant source of degradation is high...... on the side facing its anode. Two high temperature corrosion issues, which both affect the air side of the interconnect, are especially significant, both of: Formation of thick oxide scales on its surface and evaporation of chromium species from the oxide. The oxide scales increases the electrical resistance...

  12. Uranium dioxide and beryllium oxide enhanced thermal conductivity nuclear fuel development

    International Nuclear Information System (INIS)

    Andrade, Antonio Santos; Ferreira, Ricardo Alberto Neto

    2007-01-01

    The uranium dioxide is the most used substance as nuclear reactor fuel for presenting many advantages such as: high stability even when it is in contact with water in high temperatures, high fusion point, and high capacity to retain fission products. The conventional fuel is made with ceramic sintered pellets of uranium dioxide stacked inside fuel rods, and presents disadvantages because its low thermal conductivity causes large and dangerous temperature gradients. Besides, the thermal conductivity decreases further as the fuel burns, what limits a pellet operational lifetime. This research developed a new kind of fuel pellets fabricated with uranium dioxide kernels and beryllium oxide filling the empty spaces between them. This fuel has a great advantage because of its higher thermal conductivity in relation to the conventional fuel. Pellets of this kind were produced, and had their thermophysical properties measured by the flash laser method, to compare with the thermal conductivity of the conventional uranium dioxide nuclear fuel. (author) (author)

  13. Development of Head-end Pyrochemical Reduction Process for Advanced Oxide Fuels

    International Nuclear Information System (INIS)

    Park, B. H.; Seo, C. S.; Hur, J. M.; Jeong, S. M.; Hong, S. S.; Choi, I. K.; Choung, W. M.; Kwon, K. C.; Lee, I. W.

    2008-12-01

    The development of an electrolytic reduction technology for spent fuels in the form of oxide is of essence to introduce LWR SFs to a pyroprocessing. In this research, the technology was investigated to scale a reactor up, the electrochemical behaviors of FPs were studied to understand the process and a reaction rate data by using U 3 O 8 was obtained with a bench scale reactor. In a scale of 20 kgHM/batch reactor, U 3 O 8 and Simfuel were successfully reduced into metals. Electrochemical characteristics of LiBr, LiI and Li 2 Se were measured in a bench scale reactor and an electrolytic reduction cell was modeled by a computational tool

  14. Individual monitoring of internal exposure to uranium oxides in two fuel fabrication plants

    International Nuclear Information System (INIS)

    Bourdeix, F.; Achiary, J.; Berard, P.

    1989-01-01

    Individual monitoring of personal exposure to inhalation of uranium oxides throughout the manufacture of fuel for pressurized water reactor (PWR) includes lung gamma-spectrometry, fecal analysis and urine analysis. Examination of the results shows the following: internal exposure is the consequence of repeated intake incidents as revealed by early peaks of urinary and particularly fecal elimination; a shift is often observed with the results of aerosol concentration measured through air collectors; the measured variations of uranium lung incorporations are relatively fast (apparent mean period 165 d). Correct evaluation of the effective dose equivalent from inhalation requires further information concerning the aerosol size distribution at work stations, the physico-chemical characteristics of the product leading to an estimate of its actual biological solubility, and the measurement of the fraction of aerosol liable to intake with an individual portable collector [fr

  15. Development of Head-end Pyrochemical Reduction Process for Advanced Oxide Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Park, B. H.; Seo, C. S.; Hur, J. M.; Jeong, S. M.; Hong, S. S.; Choi, I. K.; Choung, W. M.; Kwon, K. C.; Lee, I. W. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2008-12-15

    The development of an electrolytic reduction technology for spent fuels in the form of oxide is of essence to introduce LWR SFs to a pyroprocessing. In this research, the technology was investigated to scale a reactor up, the electrochemical behaviors of FPs were studied to understand the process and a reaction rate data by using U{sub 3}O{sub 8} was obtained with a bench scale reactor. In a scale of 20 kgHM/batch reactor, U{sub 3}O{sub 8} and Simfuel were successfully reduced into metals. Electrochemical characteristics of LiBr, LiI and Li{sub 2}Se were measured in a bench scale reactor and an electrolytic reduction cell was modeled by a computational tool.

  16. An oxidation-resistant indium tin oxide catalyst support for proton exchange membrane fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Chhina, H.; Campbell, S. [Ballard Power Systems Inc., 9000 Glenlyon Parkway, Burnaby, BC V5J 5J8 (Canada); Kesler, O. [Department of Mechanical Engineering, University of British Columbia, Vancouver, BC, V6T 1Z4 (Canada)

    2006-10-27

    The oxidation of carbon catalyst supports causes degradation in catalyst performance in proton exchange membrane fuel cells (PEMFCs). Indium tin oxide (ITO) is considered as a candidate for an alternative catalyst support. The electrochemical stability of ITO was studied by use of a rotating disk electrode (RDE). Oxidation cycles between +0.6 and +1.8V were applied to ITO supporting a Pt catalyst. Cyclic voltammograms (CVs) both before and after the oxidation cycles were obtained for Pt on ITO, Hispec 4000 (a commercially available catalyst), and 40wt.% Pt dispersed in-house on Vulcan XC-72R. Pt on ITO showed significantly better electrochemical stability, as determined by the relative change in electrochemically active surface area after cycling. Hydrogen desorption peaks in the CVs existed even after 100 cycles from 0.6 to 1.8V for Pt on ITO. On the other hand, most of the active surface area was lost after 100 cycles of the Hispec 4000 catalyst. The 40wt.% Pt on Vulcan made in-house also lost most of its active area after only 50 cycles. Pt on ITO was significantly more electrochemically stable than both Hispec 4000 and Pt on Vulcan XC-72R. In this study, it was found that the Pt on ITO had average crystallite sizes of 13nm for Pt and 38nm for ITO. Pt on ITO showed extremely high thermal stability, with only {approx}1wt.% loss of material for ITO versus {approx}57wt.% for Hispec 4000 on heating to 1000{sup o}C. The TEM data show Pt clusters dispersed on small crystalline ITO particles. The SEM data show octahedral shaped ITO particles supporting Pt. (author)

  17. Study of fuel element characteristic of SM and SMP (SM-PRIMA) fuel assemblies

    International Nuclear Information System (INIS)

    Klinov, A.V.; Kuprienko, V.A.; Lebedev, V.A.; Makhin, V.M.; Tuchnin, L.M.; Tsykanov, V.A.

    1999-01-01

    The paper discusses the techniques and results of reactor tests and post-reactor investigations of the SM reactor fuel elements and fuel elements developed in the process of designing the specialized PRIMA test reactor with the SM reactor fuel elements used as a prototype and which are referred to as the SMP fuel elements. The behavior of fuel elements under normal operating conditions and under deviation from normal operating conditions was studied to verify the calculation techniques, to check the calculation results during preparation of the SM reactor safety substantiation report and to estimate the possibility of using such fuel elements in other projects. During tests of fuel rods under deviation from normal operating conditions their advantages were shown over fuel elements, the components of which were produced using the Al-based alloys. (author)

  18. Preparation, characterisation, engine performance and emission characteristics of coconut oil based hybrid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Pranil J.; Singh, Anirudh [Division of Physics, School of Engineering and Physics, Faculty of Science, Technology and Environment, University of the South Pacific, 325 Fletcher Road, Suva (Fiji); Khurma, Jagjit [Division of Chemistry, School of Biological, Chemical and Environmental Sciences, Faculty of Science, Technology and Environment, University of the South Pacific, Suva (Fiji)

    2010-09-15

    In this study, hybrid fuels consisting of coconut oil, aqueous ethanol and a surfactant (butan-1-ol) were prepared and tested as a fuel in a direct injection diesel engine. After determining fuel properties such as the density, viscosity and gross calorific values of these fuels, they were used to run a diesel engine. The engine performance and exhaust emissions were investigated and compared with that of diesel. The experimental results show that the efficiency of the hybrid fuels is comparable to that of diesel. As the viscosity of the hybrid fuels decreased and approached that of diesel, the efficiency increased progressively towards that of diesel. The exhaust emissions were lower than those for diesel, except carbon monoxide emissions, which increased. Hence, it is concluded that these hybrid fuels can be used successfully as an alternative fuel in diesel engines without any modifications. Their completely renewable nature ensures that they are environmentally friendly with regard to their emissions characteristics. (author)

  19. Design characteristics of pantograph type in vessel fuel handling system in SFR

    International Nuclear Information System (INIS)

    Kim, S. H.; Koo, G. H.

    2012-01-01

    The pantograph type in vessel fuel handling system in a sodium cooled fast reactor (SFR), which requires installation space for the slot in the upper internal structure attached under the rotating plug, is composed of an in vessel transfer machine (IVTM), a single rotating plug, in vessel storage, and a fuel transfer port (FTP). The pantograph type IVTM can exchange fuel assemblies through a slot, the design requirement of which should be essentially considered in the design of the in vessel fuel handling system. In addition, the spent fuel assemblies temporarily stored in the in vessel storage of the reactor vessel are removed to the outside of the reactor vessel through the FTP. The fuel transfer basket is then provided in the FTP, and a fuel transfer is performed by using it. In this study, the design characteristics for a pantograph type in vessel fuel handling system are reviewed, and the preconceptual designs are studied

  20. Design characteristics of pantograph type in vessel fuel handling system in SFR

    Energy Technology Data Exchange (ETDEWEB)

    Kim, S. H.; Koo, G. H. [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    The pantograph type in vessel fuel handling system in a sodium cooled fast reactor (SFR), which requires installation space for the slot in the upper internal structure attached under the rotating plug, is composed of an in vessel transfer machine (IVTM), a single rotating plug, in vessel storage, and a fuel transfer port (FTP). The pantograph type IVTM can exchange fuel assemblies through a slot, the design requirement of which should be essentially considered in the design of the in vessel fuel handling system. In addition, the spent fuel assemblies temporarily stored in the in vessel storage of the reactor vessel are removed to the outside of the reactor vessel through the FTP. The fuel transfer basket is then provided in the FTP, and a fuel transfer is performed by using it. In this study, the design characteristics for a pantograph type in vessel fuel handling system are reviewed, and the preconceptual designs are studied.

  1. An afterburner-powered methane/steam reformer for a solid oxide fuel cells application

    Science.gov (United States)

    Mozdzierz, Marcin; Chalusiak, Maciej; Kimijima, Shinji; Szmyd, Janusz S.; Brus, Grzegorz

    2018-04-01

    Solid oxide fuel cell (SOFC) systems can be fueled by natural gas when the reforming reaction is conducted in a stack. Due to its maturity and safety, indirect internal reforming is usually used. A strong endothermic methane/steam reforming process needs a large amount of heat, and it is convenient to provide thermal energy by burning the remainders of fuel from a cell. In this work, the mathematical model of afterburner-powered methane/steam reformer is proposed. To analyze the effect of a fuel composition on SOFC performance, the zero-dimensional model of a fuel cell connected with a reformer is formulated. It is shown that the highest efficiency of a solid oxide fuel cell is achieved when the steam-to-methane ratio at the reforming reactor inlet is high.

  2. System modeling of an air-independent solid oxide fuel cell system for unmanned undersea vehicles

    Science.gov (United States)

    Burke, A. Alan; Carreiro, Louis G.

    To examine the feasibility of a solid oxide fuel cell (SOFC)-powered unmanned undersea vehicle (UUV), a system level analysis is presented that projects a possible integration of the SOFC stack, fuel steam reformer, fuel/oxidant storage and balance of plant components into a 21-in. diameter UUV platform. Heavy hydrocarbon fuel (dodecane) and liquid oxygen (LOX) are chosen as the preferred reactants. A maximum efficiency of 45% based on the lower heating value of dodecane was calculated for a system that provides 2.5 kW for 40 h. Heat sources and sinks have been coupled to show viable means of thermal management. The critical design issues involve proper recycling of exhaust steam from the fuel cell back into the reformer and effective use of the SOFC stack radiant heat for steam reformation of the hydrocarbon fuel.

  3. Fuel component of electricity generation cost for the BN-800 reactor with 800 MOX fuel and uranium oxide fuel, increased fuel burnup, and removal of radial breeding blanket

    International Nuclear Information System (INIS)

    Raskach, A.

    2000-01-01

    There are two completed design concepts of NPP with BN-800 type reactors developed with due regard for enhanced safety requirements. They have been created for the 3 rd unit of Beloyarsk NPP and for three units of South Ural NPP. Both concepts are proposed to use mixed oxide fuel (MOX) based on civil plutonium. At this moment economical estimations carried out for these projects need to be revised in connection with the changes of economical situation in Russia and the world nuclear market structure. It is also essential to take into account the existing problem of the excess ex-weapons plutonium utilization and the possibility of using this plutonium to fabricate MOX fuel for the BN-800 reactors. (authors)

  4. Radioactive characteristics of spent fuels and reprocessing products in thorium fueled alternative cycles

    International Nuclear Information System (INIS)

    Maeda, Mitsuru

    1978-09-01

    In order to provide one fundamental material for the evaluation of Th cycle, compositions of the spent fuels were calculated with the ORIGEN code on following fuel cycles: (1) PWR fueled with Th- enriched U, (2) PWR fueled with Th-denatured U, (3) CANDU fueled with Th-enriched U and (4) HTGR fueled with Th-enriched U. Using these data, product specifications on radioactivity for their reprocessing were calculated, based on a criterion that radioactivities due to foreign elements do not exceed those inherent in nuclear fuel elements, due to 232 U in bred U or 228 Th in recovered Th, respectively. Conclusions are as the following: (1) Because of very high contents of 232 U and 228 Th in the Th cycle fuels from water moderated reactors, especially from PWR, required decontamination factors for their reprocessing will be smaller by a factor of 10 3 to 10 4 , compared with those from U-Pu fueled LWR cycle. (2) These less stringent product specifications on the radioactivity of bred U and recovered Th will justify introduction of some low decontaminating process, with additional advantage of increased proliferation resistance. (3) Decontamination factors required for HTGR fuel will be 10 to 30 times higher than for the other fuels, because of less 232 U and 228 Th generation, and higher burn-up in the fuel. (author)

  5. A study on the thermal expansion characteristics of simulated spent fuel and simulated DUPIC fuel

    International Nuclear Information System (INIS)

    Kang, Kweon Ho; Ryu, H. J.; Kim, H. S.; Song, K. C.; Yang, M. S.

    2001-10-01

    Thermal expansions of simulated spent PWR fuel and simulated DUPIC fuel were studied using a dilatometer in the temperature range from 298 to 1900 K. The densities of simulated spent PWR fuel and simulated DUPIC fuel used in the measurement were 10.28 g/cm3 (95.35 % of TD) and 10.26 g/cm3 (95.14 % of TD), respectively. Their linear thermal expansions of simulated fuels are higher than that of UO2, and the difference between these fuels and UO2 increases progressively as temperature increases. However, the difference between simulated spent PWR fuel and simulated DUPIC fuel can hardly be observed. For the temperature range from 298 to 1900 K, the values of the average linear thermal expansion coefficients for simulated spent PWR fuel and simulated DUPIC fuel are 1.391 10-5 and 1.393 10-5 K-1, respectively. As temperature increases to 1900 K, the relative densities of simulated spent PWR fuel and simulated DUPIC fuel decrease to 93.81 and 93.76 % of initial densities at 298 K, respectively

  6. Initiation of depleted uranium oxide and spent fuel testing for the spent fuel sabotage aerosol ratio program

    Energy Technology Data Exchange (ETDEWEB)

    Molecke, M.A.; Gregson, M.W.; Sorenson, K.B. [Sandia National Labs. (United States); Billone, M.C.; Tsai, H. [Argonne National Lab. (United States); Koch, W.; Nolte, O. [Fraunhofer Inst. fuer Toxikologie und Experimentelle Medizin (Germany); Pretzsch, G.; Lange, F. [Gesellschaft fuer Anlagen- und Reaktorsicherheit (Germany); Autrusson, B.; Loiseau, O. [Inst. de Radioprotection et de Surete Nucleaire (France); Thompson, N.S.; Hibbs, R.S. [U.S. Dept. of Energy (United States); Young, F.I.; Mo, T. [U.S. Nuclear Regulatory Commission (United States)

    2004-07-01

    We provide a detailed overview of an ongoing, multinational test program that is developing aerosol data for some spent fuel sabotage scenarios on spent fuel transport and storage casks. Experiments are being performed to quantify the aerosolized materials plus volatilized fission products generated from actual spent fuel and surrogate material test rods, due to impact by a high energy density device, HEDD. The program participants in the U.S. plus Germany, France, and the U.K., part of the international Working Group for Sabotage Concerns of Transport and Storage Casks, WGSTSC have strongly supported and coordinated this research program. Sandia National Laboratories, SNL, has the lead role for conducting this research program; test program support is provided by both the U.S. Department of Energy and Nuclear Regulatory Commission. WGSTSC partners need this research to better understand potential radiological impacts from sabotage of nuclear material shipments and storage casks, and to support subsequent risk assessments, modeling, and preventative measures. We provide a summary of the overall, multi-phase test design and a description of all explosive containment and aerosol collection test components used. We focus on the recently initiated tests on ''surrogate'' spent fuel, unirradiated depleted uranium oxide, and forthcoming actual spent fuel tests. The depleted uranium oxide test rodlets were prepared by the Institut de Radioprotection et de Surete Nucleaire, in France. These surrogate test rodlets closely match the diameter of the test rodlets of actual spent fuel from the H.B. Robinson reactor (high burnup PWR fuel) and the Surry reactor (lower, medium burnup PWR fuel), generated from U.S. reactors. The characterization of the spent fuels and fabrication into short, pressurized rodlets has been performed by Argonne National Laboratory, for testing at SNL. The ratio of the aerosol and respirable particles released from HEDD-impacted spent

  7. Neutron radiation characteristics of the IVth generation reactor spent fuel

    Science.gov (United States)

    Bedenko, Sergey; Shamanin, Igor; Grachev, Victor; Knyshev, Vladimir; Ukrainets, Olesya; Zorkin, Andrey

    2018-03-01

    Exploitation of nuclear power plants as well as construction of new generation reactors lead to great accumulation of spent fuel in interim storage facilities at nuclear power plants, and in spent fuel «wet» and «dry» long-term storages. Consequently, handling the fuel needs more attention. The paper is focused on the creation of an efficient computational model used for developing the procedures and regulations of spent nuclear fuel handling in nuclear fuel cycle of the new generation reactor. A Thorium High-temperature Gas-Cooled Reactor Unit (HGTRU, Russia) was used as an object for numerical research. Fuel isotopic composition of HGTRU was calculated using the verified code of the MCU-5 program. The analysis of alpha emitters and neutron radiation sources was made. The neutron yield resulting from (α,n)-reactions and at spontaneous fission was calculated. In this work it has been shown that contribution of (α,n)-neutrons is insignificant in case of such (Th,Pu)-fuel composition and HGTRU operation mode, and integral neutron yield can be approximated by the Watt spectral function. Spectral and standardized neutron distributions were achieved by approximation of the list of high-precision nuclear data. The distribution functions were prepared in group and continuous form for further use in calculations according to MNCP, MCU, and SCALE.

  8. Characteristics of uranium oxide cathode for neutron streak camera

    International Nuclear Information System (INIS)

    Niki, H.; Itoga, K.; Yamanaka, M.; Yamanaka, T.; Yamanaka, C.

    1986-01-01

    In laser fusion research, time-resolved neutron measurements require 20ps resolution in order to obtain the time history of the D-T burn. Uranium oxide was expected to be a sensitive material as a cathode of a neutron streak camera because of its large fission cross section. The authors report their measurements of some characteristics of the uranium oxide cathode connected to a conventional streak tube. 14 MeV neutron signal were observed as the bright spots on a TV monitor using a focus mode opration. Detection efficiency was ∼ 1 x 10 -6 for 1 μm thick cathode. Each signal consisted of more than several tens of components, which were corresponding to the secondary electrons dragged out from the cathode by a fission fragment. Time resolution is thought to be limited mainly by the transit time spread of the secondary electrons. 14ps resolution was obtained by a streak mode operation for a single fission event

  9. Experimental and thermodynamic evaluation of the melting behavior of irradiated oxide fuels

    International Nuclear Information System (INIS)

    Adamson, M.G.; Aitken, E.A.; Caputi, R.W.

    1985-01-01

    Onset of melting is an important performance limit for irradiated UO 2 and UO 2 -based nuclear reactor fuels. Melting (solidus) temperatures are reasonably well known for starting fuel materials such as UO 2 and (U,PU)O 2 , however the influence of burnup on oxide fuel melting behavior continues to represent an area of considerable uncertainty. In this paper we report the results of a variety of melting temperature measurements on pseudo-binary fuel-fissia mixtures such as UO 2 -PUO 2 , UO 2 -CeO 2 , UO 2 -BaO, UO 2 -SrO, UO 2 -BaZrO 3 and UO 2 -SrZrO 3 . These measurements were performed using the thermal arrest technique on tungsten-encapsulated specimens. Several low melting eutectics, the existence of which had previously been inferred from post-irradiation examinations of high burnup mixed oxide fuels, were characterized in the course of the investigation. Also, an assessment of melting temperature changes in irradiated oxide fuels due to the production and incorporation of soluble oxidic fission products was performed by application of solution theory to the available pseudo-binary phase diagram data. The results of this assessment suggest that depression of oxide fuel solidus temperatures by dissolved fission products is substantially less than that indicated by earlier experimental studies. (orig.)

  10. Fuel elements based on mixed oxides UO{sub 2} - PuO{sub 2}; Gorivni elementi na bazi mesanih oksida UO{sub 2} - PuO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Katanic-Popovic, J; Stevanovic, M [Boris Kidric Institute of nuclear sciences, Vinca, Belgrade (Yugoslavia)

    1978-07-01

    Questions concerning utilization of plutonium as a fissionable material in fuel elements for nuclear power plants have been discussed. Characteristics and application of fuel elements with mixed UO{sub 2} - PuO{sub 2} fuel for thermal and fast breeder reactors have also been dealt with. In the presentation of technological processes for production of fuel elements based on mixed oxides specific characteristics are given with respect to the work with plutonium and relatively high production costs as compared to classical fuel elements based on sintered UO{sub 2}. (author)

  11. Simulation of the steady-state behaviour of a new design of a single planar Solid Oxide Fuel Cell

    Directory of Open Access Journals (Sweden)

    Pianko-Oprych Paulina

    2016-03-01

    Full Text Available The aim of the work was to develop a mathematical model for computing the steady-state voltage – current characteristics of a planar Solid Oxide Fuel Cell and to determine the performance of a new SOFC design. The design involves cross-flow bipolar plates. Each of the bipolar plates has an air channel system on one side and a fuel channel system on the other side. The proposed model was developed using the ANSYS-Fluent commercial Computational Fluid Dynamics (CFD software supported by additional Fuel Cell module. The results confirm that the model can well simulate the diagonal current path. The effects of temperature and gas flow through the channels and a Membrane Electrode Assembly (MEA structure were taken into account. It was shown that a significant increase of the MEA temperature at high current density can lead to hot spots formation and hence electrode damage.

  12. Strontium Titanate-based Composite Anodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Blennow Tullmar, Peter; Kammer Hansen, Kent; Wallenberg, L.R.

    2008-01-01

    Surfactant-assisted infiltration of Gd-doped ceria (CGO) in Nb-doped SrTiO3 (STN) was investigated as a potential fuel electrode for solid oxide fuel cells (SOFC). An electronically conductive backbone structure of STN was first fabricated at high temperatures and then combined with the mixed con...

  13. EVALUATION OF TIRE-DERIVED FUEL FOR USE IN NITROGEN OXIDE REDUCTION BY REBURNING

    Science.gov (United States)

    Tire-derived fuel (TDF) was tested in a small-scale (44 kW or 150,000 Btu/hr) combustor to determine its feasibility as a fuel for use in reburning for control of nitrogen oxide (NO). TDF was gravity-fed into upward flowing combustion gases from a primary natural gas flame doped ...

  14. Biomass-powered Solid Oxide Fuel Cells : Experimental and Modeling Studies for System Integrations

    NARCIS (Netherlands)

    Liu, M.

    2013-01-01

    Biomass is a sustainable energy source which, through thermo-chemical processes of biomass gasification, is able to be converted from a solid biomass fuel into a gas mixture, known as syngas or biosyngas. A solid oxide fuel cell (SOFC) is a power generation device that directly converts the chemical

  15. Characteristics of axial splits in failed BWR fuel rods

    International Nuclear Information System (INIS)

    Lysell, G.; Grigoriev, V.

    2000-01-01

    Secondary cladding defects in BWR fuel sometimes have the shape of long axial cracks or ''splits''. Due to the large open UO 2 surfaces exposed to the water, fission product and UO 2 release to the coolant can reach excessive levels leading to forced shut downs to remove the failed fuel rods. A number of such fuel rods have been examined in Studsvik over the last 10 years. The paper describes observations from the PIE of long cracks and discusses the driving force of the cracks. Details such as starting cracks, macroscopic and microscopic fracture surface appearance, cross sections of cracks, hydride precipitates, location and degree of plastic deformation are given. (author)

  16. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Neimark, L.A.; Poeppel, R.B.; Hofman, G.L.

    1985-01-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release. 29 refs., 12 figs

  17. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Hofman, G.L.; Neimark, L.A.; Poeppel, R.B.

    1983-11-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release

  18. Mathematical modeling of oxygen transport in solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Svensson, Ann Mari

    1997-12-31

    This thesis develops mathematical models to describe the electrochemical performance of a solid oxide fuel cell cathode based on electrochemical kinetics and mass transfer. The individual effects of various coupled processes are investigated. A one-dimensional model is developed based on porous electrode theory. Two different mechanisms are investigated for the charge transfer reaction. One of these assumes that intermediately adsorbed oxygen atoms are reduced at the electrode/electrolyte interface, similar to the models proposed for metal electrodes. Simulated polarization curves exhibit limited currents due to depletion of oxygen adsorbates at high cathodic overvoltages. An empirical correlation is confirmed to exist between the limiting current an the oxygen partial pressure, however, a similar correlation often assumed to exist between the measured polarization resistance and the oxygen partial pressure could not be justified. For the other model, oxygen vacancies are assumed to be exchanged directly at the electrode/electrolyte interface. The electrochemical behaviour is improved by reducing the oxygen partial pressure, due to increased vacancy concentration of the electrode material. Simulated polarization curves exhibit Tafel-like slopes in the cathodic direction, which are due to polarization concentration, and not activation polarization in the conventional sense. Anodic limiting currents are predicted due to lack of available free sites for vacancy exchange at the cathode side. The thesis also presents a theoretical treatment of current and potential distributions in simple two-dimensional cell geometries, and a two-dimensional model for a porous electrode-electrolyte system for investigation of the effect of interfacial diffusion of adsorbates along the electrode/electrolyte interface. 172 refs., 60 figs., 11 tabs.

  19. Laser induced densification of cerium gadolinium oxide: Application to single-chamber solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Mariño, Mariana [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Rieu, Mathilde, E-mail: rieu@emse.fr [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Viricelle, Jean-Paul [École Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF, F-42023 Saint-Étienne (France); Garrelie, Florence [Université Jean Monnet, Laboratoire Hubert Curien, CNRS: UMR 5516, 42000 Saint-Etienne (France)

    2016-06-30

    Graphical abstract: - Highlights: • CGO surface densifications were induced by UV and IR laser irradiations. • Grain growth or densified cracked surfaces were observed by SEM. • UV laser treatments allow a decrease of gas permeation through electrolyte layer. • Electrical conductivity of the electrolyte was modified by laser treatments. • Grain growth of electrolyte induced by UV laser improved cell performances. - Abstract: In single-chamber solid oxide fuel cells (SC-SOFC), anode and cathode are placed in a gas chamber where they are exposed to a fuel/air mixture. Similarly to conventional dual-chamber SOFC, the anode and the cathode are separated by an electrolyte. However, as in the SC-SOFC configuration the electrolyte does not play tightness role between compartments, this one can be a porous layer. Nevertheless, it is necessary to have a diffusion barrier to prevent the transportation of hydrogen produced locally at the anode to the cathode that reduces fuel cell performances. This study aims to obtain directly a diffusion barrier through the surface densification of the electrolyte Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} (CGO) by a laser treatment. KrF excimer laser and Yb fiber laser irradiations were used at different fluences and number of pulses to modify the density of the electrolyte coating. Microstructural characterizations confirmed the modifications on the surface of the electrolyte for appropriate experimental conditions showing either grain growth or densified but cracked surfaces. Gas permeation and electrical conductivities of the modified electrolyte were evaluated. Finally SC-SOFC performances were improved for the cells presenting grain growth at the electrolyte surface.

  20. Thermal-hydraulic and neutron-physical characteristics of a new SCWR fuel assembly

    International Nuclear Information System (INIS)

    Liu, X.J.; Cheng, X.

    2009-01-01

    A new fuel assembly design for a thermal supercritical water cooled reactor (SCWR) core is proposed. Compared to the existing fuel assemblies, the present fuel assembly has two-rows of fuel rods between the moderator channels, to achieve a more uniform moderation for all fuel rod cells, and subsequently, a more uniform radial power distribution. In addition, a neutron-kinetics/thermal-hydraulics coupling method is developed, to analyze the neutron-physical and thermal-hydraulic behavior of the fuel assembly designs. This coupling method is based on the sub-channel analysis code COBRA-IV for thermal-hydraulics and the neutron-kinetics code SKETCH-N for neutron-physics. Both the COBRA-IV code and the SKETCH-N code are accordingly modified. An interface is established for the data transfer between these two codes. This coupling method is applied to both the one-row fuel assemblies (previous design) and the two-row fuel assemblies (present design). The performance of the two types of fuel assemblies is compared. The results show clearly that the two-row fuel assembly has more favorable neutron-physical and thermal-hydraulic characteristics than the one-row fuel assembly. The effect of various parameters on the fuel assembly performance is discussed. The coupling method is proven to be well suitable for further applications to SCWR fuel assembly design analysis

  1. Effect of fuel characteristics on synthesis of calcium hydroxyapatite ...

    Indian Academy of Sciences (India)

    Administrator

    measurements. The particle size of phase pure HA powder was found to be <20 nm in this investigation. ..... selective samples obtained from mixed fuel excess condi- tions. Various .... <50 nm. Figure 6(d) shows the qualitative EDX analysis.

  2. COD removal characteristics in air-cathode microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan; He, Weihua; Ren, Lijiao; Stager, Jennifer; Evans, Patrick J.; Logan, Bruce E.

    2015-01-01

    © 2014 Elsevier Ltd. Exoelectrogenic microorganisms in microbial fuel cells (MFCs) compete with other microorganisms for substrate. In order to understand how this affects removal rates, current generation, and coulombic efficiencies (CEs

  3. Behaviour of rock-like oxide fuels under reactivity-initiated accident conditions

    International Nuclear Information System (INIS)

    Kazuyuki, Kusagaya; Takehiko, Nakamura; Makio, Yoshinaga; Hiroshi, Akie; Toshiyuki, Yamashita; Hiroshi, Uetsuka

    2002-01-01

    Pulse irradiation tests of three types of un-irradiated rock-like oxide (ROX) fuel - yttria-stabilised zirconia (YSZ) single phase, YSZ and spinel (MgAl 2 O 4 ) homogeneous mixture and particle-dispersed YSZ/spinel - were conducted in the Nuclear Safety Research Reactor to investigate the fuel behaviour under reactivity-initiated accident conditions. The ROX fuels failed at fuel volumetric enthalpies above 10 GJ/m 3 , which was comparable to that of un-irradiated UO 2 fuel. The failure mode of the ROX fuels, however, was quite different from that of the UO 2 fuel. The ROX fuels failed with fuel pellet melting and a part of the molten fuel was released out to the surrounding coolant water. In spite of the release, no significant mechanical energy generation due to fuel/coolant thermal interaction was observed in the tested enthalpy range below∼12 GJ/m 3 . The YSZ type and homogenous YSZ/spinel type ROX fuels failed by cladding burst when their temperatures peaked, while the particle-dispersed YSZ/spinel type ROX fuel seemed to have failed by cladding local melting. (author)

  4. Improvement of the environmental and operational characteristics of vehicles through decreasing the motor fuel density.

    Science.gov (United States)

    Magaril, Elena

    2016-04-01

    The environmental and operational characteristics of motor transport, one of the main consumers of motor fuel and source of toxic emissions, soot, and greenhouse gases, are determined to a large extent by the fuel quality which is characterized by many parameters. Fuel density is one of these parameters and it can serve as an indicator of fuel quality. It has been theoretically substantiated that an increased density of motor fuel has a negative impact both on the environmental and operational characteristics of motor transport. The use of fuels with a high density leads to an increase in carbonization within the engine, adversely affecting the vehicle performance and increasing environmental pollution. A program of technological measures targeted at reducing the density of the fuel used was offered. It includes a solution to the problem posed by changes in the refining capacities ratio and the temperature range of gasoline and diesel fuel boiling, by introducing fuel additives and adding butanes to the gasoline. An environmental tax has been developed which allows oil refineries to have a direct impact on the production of fuels with improved environmental performance, taking into account the need to minimize the density of the fuel within a given category of quality.

  5. New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Allan J. Jacobson

    2006-09-30

    Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study were perovskite oxides based on substituted LaFeO{sub 3} (P1 compositions), where significant data in single cell tests exist at PNNL for example, for La{sub 0.8}Sr{sub 0.2}FeO{sub 3} cathodes on both YSZ and CSO/YSZ. The materials selection was then extended to La{sub 2}NiO{sub 4} compositions (K1 compositions), and then in a longer range task we evaluated the possibility of completely unexplored group of materials that are also perovskite related, the ABM{sub 2}O{sub 5+{delta}}. A key component of the research strategy was to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. In the initial phase, we did this in parallel with

  6. Properties of Copper Doped Neodymium Nickelate Oxide as Cathode Material for Solid Oxide Fuel Cells

    Directory of Open Access Journals (Sweden)

    Lee Kyoung-Jin

    2016-06-01

    Full Text Available Mixed ionic and electronic conducting K2NiF4-type oxide, Nd2Ni1-xCuxO4+δ (x=0~1 powders were synthesized by solid state reaction technique and solid oxide fuel cells consisting of a Nd2Ni1-xCuxO4+δ cathode, a Ni-YSZ anode and ScSZ as an electrolyte were fabricated. The effect of copper substitution for nickel on the electrical and electrochemical properties was examined. Small amount of copper doping (x=0.2 resulted in the increased electrical conductivity and decreased polarization resistance. It appears that this phenomenon was associated with the high mean valence of nickel and copper and the resulting excess oxygen (δ. It was found that power densities of the cell with the Nd2Ni1-xCuxO4+δ (x=0.1 and 0.2 cathode were higher than that of the cell with the Nd2NiO4+δ cathode.

  7. In-pile irradiation of rock-like oxide fuels

    International Nuclear Information System (INIS)

    Nitani, N.; Kuramoto, K.; Yamashita, T.; Nakano, Y.; Akie, H.

    2001-01-01

    Five kinds of ROX fuels were prepared and irradiated using 20% enriched U instead of Pu. Non-destructive and destructive post-irradiation examinations were carried out. FP gas release rates of the particle-dispersed type fuels and homogeneously-blended type fuels were larger than that of the Yttria-stabilized zirconia containing UO 2 single phase fuel. From results of SEM and EPMA, decomposition of the spinel was observed. The decomposition of the spinel is probably avoided by lowering the irradiation temperature, less than 1700 K. The regions suffering the irradiation damage of the particle dispersed type fuels were less than those of the homogeneously-blended type fuels. (author)

  8. In-pile irradiation of rock-like oxide fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nitani, N.; Kuramoto, K.; Yamashita, T.; Nakano, Y.; Akie, H. [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan)

    2001-07-01

    Five kinds of ROX fuels were prepared and irradiated using 20% enriched U instead of Pu. Non-destructive and destructive post-irradiation examinations were carried out. FP gas release rates of the particle-dispersed type fuels and homogeneously-blended type fuels were larger than that of the Yttria-stabilized zirconia containing UO{sub 2} single phase fuel. From results of SEM and EPMA, decomposition of the spinel was observed. The decomposition of the spinel is probably avoided by lowering the irradiation temperature, less than 1700 K. The regions suffering the irradiation damage of the particle dispersed type fuels were less than those of the homogeneously-blended type fuels. (author)

  9. Models for the Configuration and Integrity of Partially Oxidized Fuel Rod Cladding at High Temperatures

    International Nuclear Information System (INIS)

    Siefken, L.J.

    1999-01-01

    Models were designed to resolve deficiencies in the SCDAP/RELAP5/MOD3.2 calculations of the configuration and integrity of hot, partially oxidized cladding. These models are expected to improve the calculations of several important aspects of fuel rod behavior. First, an improved mapping was established from a compilation of PIE results from severe fuel damage tests of the configuration of melted metallic cladding that is retained by an oxide layer. The improved mapping accounts for the relocation of melted cladding in the circumferential direction. Then, rules based on PIE results were established for calculating the effect of cladding that has relocated from above on the oxidation and integrity of the lower intact cladding upon which it solidifies. Next, three different methods were identified for calculating the extent of dissolution of the oxidic part of the cladding due to its contact with the metallic part. The extent of dissolution effects the stress and thus the integrity of the oxidic part of the cladding. Then, an empirical equation was presented for calculating the stress in the oxidic part of the cladding and evaluating its integrity based on this calculated stress. This empirical equation replaces the current criterion for loss of integrity which is based on temperature and extent of oxidation. Finally, a new rule based on theoretical and experimental results was established for identifying the regions of a fuel rod with oxidation of both the inside and outside surfaces of the cladding. The implementation of these models is expected to eliminate the tendency of the SCDAP/RELAP5 code to overpredict the extent of oxidation of the upper part of fuel rods and to underpredict the extent of oxidation of the lower part of fuel rods and the part with a high concentration of relocated material. This report is a revision and reissue of the report entitled, Improvements in Modeling of Cladding Oxidation and Meltdown

  10. Design characteristics of metallic fuel rod on its in-LMR performance

    International Nuclear Information System (INIS)

    Hwang, Woan; Kang Hee Young; Nam, Cheol; Kim, Jong Oh

    1997-01-01

    Fuel design is a key feature to assure LMR safety goals. To date, a large effort had been devoted to develop metallic fuels at ANL's experimental breeder reactor (EBR-II). The major design and performance parameters investigated include; thermal conductivity and temperature profile; smear density; axial plenum; FCMI and cladding deformation including creep, and fission gas release. In order to evaluate the sensitivity of each parameter, in-LMR performances of metallic fuels are not only reviewed by the experiment results in literatures, but also key design characteristics according to the variation of metallic fuel rod design parameters are analyzed by using the MACSIS code which simulates in-reactor behaviors of metal fuel rod. In this study, key design characteristics and the criteria which must be considered to design fuel rod in LMR, are proposed and discussed. (author). 14 refs., 4 figs

  11. Pressurized solid oxide fuel cell integral air accumular containment

    Science.gov (United States)

    Gillett, James E.; Zafred, Paolo R.; Basel, Richard A.

    2004-02-10

    A fuel cell generator apparatus contains at least one fuel cell subassembly module in a module housing, where the housing is surrounded by a pressure vessel such that there is an air accumulator space, where the apparatus is associated with an air compressor of a turbine/generator/air compressor system, where pressurized air from the compressor passes into the space and occupies the space and then flows to the fuel cells in the subassembly module, where the air accumulation space provides an accumulator to control any unreacted fuel gas that might flow from the module.

  12. Safety aspects related to burnup increase and mixed oxide fuel

    International Nuclear Information System (INIS)

    Thomas, W.

    1992-01-01

    The dominant factor presently limiting the fuel burnup is the response of the cladding hulls. To maintain the excellent record of very low fuel failure rates for increased burnups further technical development is underway and necessary. In the nuclear fuel cycle increased burnups lead to a remarkable reduction of spent fuel arisings and corresponding economic savings. Thermal recycling of plutonium presently provides an opportunity to reduce the rising accumulation of plutunium in a situation where there is no demand for this fissile material in Fast Breeder Reactors. (orig.) [de

  13. The effect of the fuel rod friction force to the fuel assembly lateral mechanical characteristics

    International Nuclear Information System (INIS)

    Ha, Dong Geun; Jeon, Sang Youn; Suh, Jung Min

    2012-01-01

    The Fuel Assembly (FA) for light water reactor consists of hundreds of fuel rods, guide tubes, spacer grids, top/bottom nozzles. The guide tubes transmit vertical loads between the top and bottom nozzles, position the fuel rod support grids vertically, react the loads from the fuel rods that are applied to the grids, and provide some of the lateral load capability for the overall fuel assembly. The guide tubes are the structural members of the skeleton assembly. And the spacer grids maintain the fuel rod array by providing positive lateral restraint to the fuel rod but only frictional restraint in the axial direction. Figure 1 shows the outline of skeleton, FA and the location of guide tubes in the view of cross section. 17x17 FA has 24 guide tubes and one instrumentation tube. When the FA is in reactor, the lateral stiffness is one of very important factors from the view point of in reactor integrity of fuel assembly such as guarantee of the cool able geometry, the control rod insertion etc. The lateral stiffness of FA is mainly determined by skeleton lateral stiffness. And the fuel rods loaded in the spacer grids reinforce the FA lateral stiffness. Generally, fuel rods and spacer grids create the nonlinear friction force between fuel rod tube and grid spring/dimple against external lateral force of FA. Thus, it is necessary to study the contribution of the fuel rods friction force to the FA lateral stiffness. So, this paper is to show how much amount of the fuel rod grid interaction contributes to the FA lateral stiffness based on the test results

  14. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    Science.gov (United States)

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  15. Use of a Burkholderia cenocepacia ABTS Oxidizer in a Microbial Fuel Cell

    Science.gov (United States)

    Microbial fuel cells (MFCs) often use biological processes to generate electrons from organic material contained in the anode chamber and abiotic processes employing atmospheric oxygen as the oxidant in the cathode chamber. This study investigated the accumulation of an oxidant in bacterial cultures...

  16. Plutonium rock-like fuel LWR nuclear characteristics and transient behavior in accidents

    Energy Technology Data Exchange (ETDEWEB)

    Akie, Hiroshi; Anoda, Yoshinari; Takano, Hideki [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Yamaguchi, Chouichi; Sugo, Yukihiro

    1998-03-01

    For the disposition of excess plutonium, rock-like oxide (ROX) fuel systems based on zirconia (ZrO{sub 2}) or thoria (ThO{sub 2}) have been studied. Safety analysis of ROX fueled PWR showed it is necessary to increase Doppler reactivity coefficient and to reduce power peaking factor of zirconia type ROX (Zr-ROX) fueled core. For these improvements, Zr-ROX fuel composition was modified by considering additives of ThO{sub 2}, UO{sub 2} or Er{sub 2}O{sub 3}, and reducing Gd{sub 2}O{sub 3} content. As a result of the modification, comparable, transient behavior to UO{sub 2} fuel PWR was obtained with UO{sub 2}-Er{sub 2}O{sub 3} added Zr-ROX fuel, while the plutonium transmutation capability is slightly reduced. (author)

  17. Uranium oxide fuel cycle analysis in VVER-1000 with VISTA simulation code

    Science.gov (United States)

    Mirekhtiary, Seyedeh Fatemeh; Abbasi, Akbar

    2018-02-01

    The VVER-1000 Nuclear power plant generates about 20-25 tons of spent fuel per year. In this research, the fuel transmutation of Uranium Oxide (UOX) fuel was calculated by using of nuclear fuel cycle simulation system (VISTA) code. In this simulation, we evaluated the back end components fuel cycle. The back end component calculations are Spent Fuel (SF), Actinide Inventory (AI) and Fission Product (FP) radioisotopes. The SF, AI and FP values were obtained 23.792178 ton/y, 22.811139 ton/y, 0.981039 ton/y, respectively. The obtained value of spent fuel, major actinide, and minor actinide and fission products were 23.8 ton/year, 22.795 ton/year, 0.024 ton/year and 0.981 ton/year, respectively.

  18. Potential electrode materials for symmetrical Solid Oxide Fuel Cells

    Directory of Open Access Journals (Sweden)

    Ruiz Morales, J. C.

    2008-08-01

    Full Text Available Chromites, titanates and Pt-YSZ-CeO2 cermets have been investigated as potential electrode materials for an alternative concept of Solid Oxide Fuel Cell (SOFC, the symmetrical SOFCs (SFC. In this configuration, the same electrode material is used simultaneously as anode and cathode. Interconnector materials, such as chromites, could be considered as potential SFC electrodes, at least under pure hydrogen-fed at relatively high temperatures, as they do not exhibit significant catalytic activity towards hydrocarbon oxidation. This may be overcome by partially substituting Cr in the perovskite B-sites by other transition metal cations such as Mn. La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM is a good candidate for such SFCs, rendering fuel cell performances in excess of 500 and 300mW/cm2 using pure H2 and CH4 as fuel, at 950 oC. Similarly, typical n-type electronic conductors traditionally regarded as anode materials, such as strontium titanates, may also operate under oxidising conditions as cathodes by substituting some Ti content for Fe to introduce p-type conductivity. Preliminary electrochemical experiments on La4Sr8Ti12-xFexO38-δ-based SFCs show that they perform reasonably well under humidified H2, at high temperatures. A third group of materials is the support material of any typical cermet anode, i.e. YSZ, CeO2 plus a current collector. It has been found that this combination could be optimised to operate as SFC electrodes, rendering performances of 400mW/cm2 under humidified pure H2 at 950oC.

    Cromitas, titanatos y cermets de Pt-YSZ-CeO2 han sido investigados como potenciales materiales de electrodo para un concepto alternativo de Pilas de Combustible de Óxidos Sólidos (SOFC, las pilas SOFC simétricas (SFC. En

  19. Effects of Fuel and Nozzle Characteristics on Micro Gas Turbine System: A Review

    Science.gov (United States)

    Akasha Hashim, Muhammad; Khalid, Amir; Salleh, Hamidon; Sunar, Norshuhaila Mohamed

    2017-08-01

    For many decades, gas turbines have been used widely in the internal combustion engine industry. Due to the deficiency of fossil fuel and the concern of global warming, the used of bio-gas have been recognized as one of most clean fuels in the application of engine to improve performance of lean combustion and minimize the production of NOX and PM. This review paper is to understand the combustion performance using dual-fuel nozzle for a micro gas turbine that was basically designed as a natural gas fuelled engine, the nozzle characteristics of the micro gas turbine has been modelled and the effect of multi-fuel used were investigated. The used of biogas (hydrogen) as substitute for liquid fuel (methane) at constant fuel injection velocity, the flame temperature is increased, but the fuel low rate reduced. Applying the blended fuel at constant fuel rate will increased the flame temperature as the hydrogen percentages increased. Micro gas turbines which shows the uniformity of the flow distribution that can be improved without the increase of the pressure drop by applying the variable nozzle diameters into the fuel supply nozzle design. It also identifies the combustion efficiency, better fuel mixing in combustion chamber using duel fuel nozzle with the largest potential for the future. This paper can also be used as a reference source that summarizes the research and development activities on micro gas turbines.

  20. Oxidative dissolution of ADOPT compared to standard UO{sub 2} fuel

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Kristina [School of Chemical Science and Engineering, Applied Physical Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Roth, Olivia [Studsvik Nuclear AB, SE-611 82 Nyköping (Sweden); Jonsson, Mats, E-mail: matsj@kth.se [School of Chemical Science and Engineering, Applied Physical Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm (Sweden)

    2017-05-15

    In this work we have studied oxidative dissolution of pure UO{sub 2} and ADOPT (UO{sub 2} doped with