WorldWideScience

Sample records for optical spectra recording

  1. Origin of the Red-Shifted Optical Spectra Recorded for Aza-BODIPY Dyes.

    Science.gov (United States)

    Karlsson, Joshua K G; Harriman, Anthony

    2016-04-28

    The optical properties are compared for two boron dipyrromethene (BODIPY) dyes that differ by virtue of the substituent at the meso-site, namely, aza-N versus C-methine atoms. Both compounds are equipped with aryl rings at the 3- and 5-positions of the dipyrrin backbone, which help to extend the degree of π-delocalization. The aza-BODIPY dye absorbs and fluoresces at much lower energy than does the conventional BODIPY dye, with red shifts of about 100 nm being observed in fluid solution, but with comparable fluorescence yield and lifetime. Hydrogen bonding donors, such as alcohols, attach to the aza-N atom and promote nonradiative decay without affecting the properties of the conventional dye. Triplet formation is ineffective in the absence of a spin-orbit coupler. Quantum chemical calculations indicate that the electronegative aza-N atom lowers the energy of the LUMO while having little effect on the corresponding HOMO energy. The resultant decrease in the HOMO-LUMO energy gap is primarily responsible for the red shift. The HOMO-LUMO energy gap is also affected by the dihedral angle subtended by the aryl rings, but this is insensitive to the geometry around the central 6-membered ring. The aza-N atom, by virtue of restricting spatial overlap between the HOMO and LUMO, decreases the energy gap between excited-singlet and -triplet states.

  2. Optical spectra analysis for breast cancer diagnostics

    Science.gov (United States)

    Belkov, S. A.; Kochemasov, G. G.; Lyubynskaya, T. E.; Maslov, N. V.; Nuzhny, A. S.; da Silva, L. B.; Rubenchik, A.

    2011-11-01

    Minimally invasive probe and optical biopsy system based on optical spectra recording and analysis seem to be a promising tool for early diagnostics of breast cancer. Light scattering and absorption spectra are generated continuously as far as the needle-like probe with one emitting and several collecting optical fibers penetrates through the tissues toward to the suspicious area. That allows analyzing not only the state of local site, but also the structure of tissues along the needle trace. The suggested method has the advantages of automated on-line diagnosing and minimal tissue destruction and in parallel with the conventional diagnostic procedures provides the ground for decision-making. 165 medical trials were completed in Nizhny Novgorod Regional Oncology Centre, Russia. Independent diagnoses were the results of fine biopsy and histology. Application of wavelet expansion and clasterization techniques for spectra analysis revealed several main spectral types for malignant and benign tumors. Automatic classification algorithm demonstrated specificity ˜90% and sensitivity ˜91%. Large amount of information, fuzziness in criteria and data noisiness make neural networks to be an attractive analytic tool. The model based on three-layer perceptron was tested over the sample of 29 `cancer' and 29 `non-cancer' cases and demonstrated total separation.

  3. Optical sedimentation recorder

    Science.gov (United States)

    Bishop, James K.B.

    2014-05-06

    A robotic optical sedimentation recorder is described for the recordation of carbon flux in the oceans wherein both POC and PIC particles are captured at the open end of a submersible sampling platform, the captured particles allowed to drift down onto a collection plate where they can be imaged over time. The particles are imaged using three separate light sources, activated in sequence, one source being a back light, a second source being a side light to provide dark field illumination, and a third source comprising a cross polarized light source to illuminate birefringent particles. The recorder in one embodiment is attached to a buoyancy unit which is capable upon command for bringing the sedimentation recorder to a programmed depth below the ocean surface during recordation mode, and on command returning the unit to the ocean surface for transmission of recorded data and receipt of new instructions. The combined unit is provided with its own power source and is designed to operate autonomously in the ocean for extended periods of time.

  4. Optical absorption spectra of Ag-11 isomers

    DEFF Research Database (Denmark)

    Martinez, Jose Ignacio; Fernandez, E. M.

    2009-01-01

    The optical absorption spectra of the three most; stable structural isomers of the Ag-11 cluster were calculated using the time-dependent, density functional theory within the Casida formalism. The slightly different, spectra, of the isomers may permit the identification of the ground-stale confi......The optical absorption spectra of the three most; stable structural isomers of the Ag-11 cluster were calculated using the time-dependent, density functional theory within the Casida formalism. The slightly different, spectra, of the isomers may permit the identification of the ground...

  5. OPTICAL SPECTRA OF LOW-DIMENSIONAL SEMICONDUCTORS

    Institute of Scientific and Technical Information of China (English)

    Fu Y Chiragwandi Z; G(o..)thberg P; Willander M

    2003-01-01

    We have studied the optical spectra of low-dimensional semiconductor systems by calculating all possible optical transitions between electronic states. Optical absorption and emission have been obtained under different carrier population conditions and in different photon wavelengths. The line-shapes of the peaks in the optical spectrum are determined by the density of electronic states of the system, and the symmetries and intensities of these peaks can be improved by reducing the dimensionality of the system. Optical gain requires in general a population inversion, whereas for a quantum-dot system, there exists a threshold value of the population inversion.

  6. FIT3D: Fitting optical spectra

    Science.gov (United States)

    Sánchez, S. F.; Pérez, E.; Sánchez-Blázquez, P.; González, J. J.; Rosales-Ortega, F. F.; Cano-Díaz, M.; López-Cobá, C.; Marino, R. A.; Gil de Paz, A.; Mollá, M.; López-Sánchez, A. R.; Ascasibar, Y.; Barrera-Ballesteros, J.

    2016-09-01

    FIT3D fits optical spectra to deblend the underlying stellar population and the ionized gas, and extract physical information from each component. FIT3D is focused on the analysis of Integral Field Spectroscopy data, but is not restricted to it, and is the basis of Pipe3D, a pipeline used in the analysis of datasets like CALIFA, MaNGA, and SAMI. It can run iteratively or in an automatic way to derive the parameters of a large set of spectra.

  7. Novel digital optical tape recorder

    Science.gov (United States)

    Oakley, William S.

    1996-01-01

    A novel very high performance digital optical tape recorder is described. Linear tape motion at 4.2 meters per second and simultaneous writing of about 80 parallel bit tracks with a data density of three bits per micron per track enables a data rate of 1,000 Megabits per second, sufficient for a data rate of 100 megabytes per second with error correction. One micron track to track spacing gives a data capacity of one Terabyte (1,000 GB) in a single '3480' style tape cartridge shell. A single beam from a frequency doubled, laser diode pumped, solid state (2X- LDP-SS) laser is split into a multiplicity of like beams, each of which is then independently modulated at 12.5 MHz for recording.

  8. Determination of Optical Constants of Polystyrene Films from IR Reflection-Absorption Spectra

    Directory of Open Access Journals (Sweden)

    Simion Jitian

    2010-09-01

    Full Text Available Determination of The transmittance values measured in IR reflectionabsorption (RA spectra were used to determine the optical constants of dielectric films laid on solid substrates. In order to obtain the optical constants of polystyrene films laid on steel we used dispersion analysis. In this case, the optical constants are obtained from IR spectrum recorded at a single incidence angle. The use of dispersion analysis offers the advantage of processing a large volume of data.

  9. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime

    OpenAIRE

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Lihong V. Wang

    2012-01-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method...

  10. VARIABILITY IN OPTICAL SPECTRA OF {epsilon} ORIONIS

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Gregory B. [Department of Physics, Adrian College, Adrian, MI 49221 (United States); Morrison, Nancy D., E-mail: gthompson@adrian.edu, E-mail: nmorris@utnet.utoledo.edu [Ritter Astrophysical Research Center, Department of Physics and Astronomy, University of Toledo, 2801 W. Bancroft, Toledo, OH 43606 (United States)

    2013-04-15

    We present the results of a time series analysis of 130 echelle spectra of {epsilon} Ori (B0 Ia), acquired over seven observing seasons between 1998 and 2006 at Ritter Observatory. The equivalent widths of H{alpha} (net) and He I {lambda}5876 were measured and radial velocities were obtained from the central absorption of He I {lambda}5876. Temporal variance spectra (TVS) revealed significant wind variability in both H{alpha} and He I {lambda}5876. The He I TVS have a double-peaked profile consistent with radial velocity oscillations. A periodicity search was carried out on the equivalent width and radial velocity data, as well as on wavelength-binned spectra. This analysis has revealed several periods in the variability with timescales of two to seven days. Many of these periods exhibit sinusoidal modulation in the associated phase diagrams. Several of these periods were present in both H{alpha} and He I, indicating a possible connection between the wind and the photosphere. Due to the harmonic nature of these periods, stellar pulsations may be the origin of some of the observed variability. Periods on the order of the rotational period were also detected in the He I line in the 1998-1999 season and in both lines during the 2004-2005 season. These periods may indicate rotational modulation due to structure in the wind.

  11. Resonance spectra of diabolo optical antenna arrays

    Science.gov (United States)

    Guo, Hong; Simpkins, Blake; Caldwell, Joshua D.; Guo, Junpeng

    2015-10-01

    A complete set of diabolo optical antenna arrays with different waist widths and periods was fabricated on a sapphire substrate by using a standard e-beam lithography and lift-off process. Fabricated diabolo optical antenna arrays were characterized by measuring the transmittance and reflectance with a microscope-coupled FTIR spectrometer. It was found experimentally that reducing the waist width significantly shifts the resonance to longer wavelength and narrowing the waist of the antennas is more effective than increasing the period of the array for tuning the resonance wavelength. Also it is found that the magnetic field enhancement near the antenna waist is correlated to the shift of the resonance wavelength.

  12. Resonance spectra of diabolo optical antenna arrays

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Hong; Guo, Junpeng, E-mail: guoj@uah.edu [Department of Electrical and Computer Engineering, University of Alabama in Huntsville, 301 Sparkman Drive, Huntsville, AL 35899 (United States); Simpkins, Blake; Caldwell, Joshua D. [Naval Research Laboratory, 4555 Overlook Ave., SW Washington, DC 20375 (United States)

    2015-10-15

    A complete set of diabolo optical antenna arrays with different waist widths and periods was fabricated on a sapphire substrate by using a standard e-beam lithography and lift-off process. Fabricated diabolo optical antenna arrays were characterized by measuring the transmittance and reflectance with a microscope-coupled FTIR spectrometer. It was found experimentally that reducing the waist width significantly shifts the resonance to longer wavelength and narrowing the waist of the antennas is more effective than increasing the period of the array for tuning the resonance wavelength. Also it is found that the magnetic field enhancement near the antenna waist is correlated to the shift of the resonance wavelength.

  13. Optical Spectra and Color of Silver Colloids

    Directory of Open Access Journals (Sweden)

    N.L. Dmitruk

    2013-10-01

    Full Text Available In present work, the color features of the aqueous silver suspensions were investigated. Color systems CIE XYZ and CIELAB are considered. In the case of low concentrations of nanoparticles chromaticity coordinates were determined from the transmission spectra of the colloids. For high concentrations of nanoparticles, when the multiple scattering effects play a key role and the medium turns to be turbid, the color of nanoparticles was found using the Kubelka-Munk relation. Experimental data is compared with that calculated from the Mie theory. Color features of a planar array of non-interacting silver nanoparticles are discussed for the first time.

  14. Resonance spectra of diabolo optical antenna arrays

    Directory of Open Access Journals (Sweden)

    Hong Guo

    2015-10-01

    Full Text Available A complete set of diabolo optical antenna arrays with different waist widths and periods was fabricated on a sapphire substrate by using a standard e-beam lithography and lift-off process. Fabricated diabolo optical antenna arrays were characterized by measuring the transmittance and reflectance with a microscope-coupled FTIR spectrometer. It was found experimentally that reducing the waist width significantly shifts the resonance to longer wavelength and narrowing the waist of the antennas is more effective than increasing the period of the array for tuning the resonance wavelength. Also it is found that the magnetic field enhancement near the antenna waist is correlated to the shift of the resonance wavelength.

  15. Optical Spectra and Light Curves of Supernovae

    CERN Document Server

    Filippenko, A V

    2003-01-01

    I review recent optical observations of supernovae (SNe) conducted by my group. The Lick Observatory Supernova Search with the 0.76-m Katzman Automatic Imaging Telescope is currently the world's most successful search for nearby SNe. We also use this telescope to obtain multicolor light curves of SNe. One of the more interesting SNe we discovered is SN 2000cx, which differs from all previously observed SNe Ia. Another very strange SN Ia that we studied is SN 2002cx, many of whose properties are opposite those of SN 2000cx. Extensive data on SNe II-P 1999em and 1999gi were used to derive distances with the expanding photosphere method. Results from spectropolarimetry suggest that the deeper we peer into the ejecta of core-collapse SNe, the greater the asphericity. We are using Hubble Space Telescope data to identify, or set limits on, the progenitors of core-collapse SNe.

  16. Mark formation model for optical rewritable recording

    NARCIS (Netherlands)

    Brusche, J.H.

    2007-01-01

    Optically rewritable discs contain one or more so-called recording stacks. These stacks consist of various grooved layers. At least one of these layers contains a so-called phase-change material. In the recording layer, amorphous regions are formed on a crystalline background by means of high power

  17. Interface phonon effect on optical spectra of quantum nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Maslov, Alexander Yu., E-mail: maslov.ton@mail.ioffe.r [Ioffe Physical Technical Institute, Polytechnicheskaya st., 26, 194021 Saint Petersburg (Russian Federation); Proshina, Olga V.; Rusina, Anastasia N. [Ioffe Physical Technical Institute, Polytechnicheskaya st., 26, 194021 Saint Petersburg (Russian Federation)

    2009-12-15

    This paper deals with theory of large radius polaron effect in quantum wells, wires and dots. The interaction of charge particles and excitons with both bulk and interface optical phonons is taken into consideration. The analytical expression for polaron binding energy is obtained for different types of nanostructures. It is shown that the contribution of interface phonons to the polaron binding energy may exceed the bulk phonon part. The manifestation of polaron effects in optical spectra of quantum nanostructures is discussed.

  18. Optical Absorption Spectra of Hydrous Wadsleyite to 32 GPa

    Science.gov (United States)

    Thomas, S.; Goncharov, A. F.; Jacobsen, S. D.; Bina, C. R.; Frost, D. J.

    2009-05-01

    Optical absorption spectra of high-pressure minerals can be used as indirect tools to calculate radiative conductivity of the Earth's interior [e.g., 1]. Recent high-pressure studies show that e.g. ringwoodite, γ-(Mg,Fe)2SiO4, does not become opaque in the near infrared and visible region, as previously assumed, but remains transparent to 21.5 GPa [2]. Therefore, it has been concluded that radiative heat transfer does not necessarily become blocked at high pressures of the mantle and ferromagnesian minerals actually could contribute to the heat flow in the Earth's interior [2]. In this study we use gem-quality single-crystals of hydrous Fe-bearing wadsleyite, β-(Mg,Fe)2SiO4, that were synthesized at 18 GPa and 1400 °C in a multianvil apparatus. Crystals were analyzed by Mössbauer and Raman spectroscopy, electron microprobe analysis and single-crystal X-ray diffraction. For absorption measurements a double-polished 50 μm sized single-crystal of wadsleyite was loaded in a diamond-anvil cell with neon as pressure medium. Optical absorption spectra were recorded at ambient conditions as well as up to 32 GPa from 400 to 50000 cm-1. At ambient pressure the absorption spectrum reveals two broad bands at - 10000 cm-1 and -15000 cm-1, and an absorption edge in the visible-ultraviolet range. With increasing pressure the absorption spectrum changes, both bands continuously shift to higher frequencies as has been observed for ringwoodite [2], but is contrary to earlier presumptions for wadsleyite [3]. Here, we will discuss band assignment along with the influence of iron, compare our results to previous absorption studies of mantle materials [2], and analyze possible implications for radiative conductivity of the transition zone. References: [1] Goncharov et al. (2008), McGraw Yearbook Sci. Tech., 242-245. [2] Keppler & Smyth (2005), Am. Mineral., 90 1209-1212. [3] Ross (1997), Phys. Chem. Earth, 22 113-118.

  19. Demonstrations of Optical Spectra with a Video Camera

    Science.gov (United States)

    Kraftmakher, Yaakov

    2012-01-01

    The use of a video camera may markedly improve demonstrations of optical spectra. First, the output electrical signal from the camera, which provides full information about a picture to be transmitted, can be used for observing the radiant power spectrum on the screen of a common oscilloscope. Second, increasing the magnification by the camera…

  20. Optical filters with fractal transmission spectra based on diffractive optics.

    Science.gov (United States)

    Mendoza-Yero, Omel; Mínguez-Vega, Gladys; Fernández-Alonso, Mercedes; Lancis, Jesús; Tajahuerce, Enrique; Climent, Vicent; Monsoriu, Juan A

    2009-03-01

    The duality between the axial irradiance distribution originated by any circularly symmetric diffracting aperture under monochromatic illumination and its diffracted spectral intensity at a fixed on-axis point under broadband illumination is highlighted and experimentally investigated. Two applications are derived from this basic result. On the one hand, we suggest the use of a broadband source and a spectrometer for a single-shot measurement of the axial response of pupil filters. Second, we implement a spectral filter having a transmission spectrum with a fractal structure of frequencies. Experimental results and potential applications in synthetic spectra designs are provided.

  1. Mark formation modeling in optical rewritable recording

    NARCIS (Netherlands)

    Brusche, J.H.; Segal, A.; Vuik, C.; Urbach, H.P.

    2006-01-01

    In optical rewritable recording media, such as the Blu-ray Disc, amorphous marks are formed on a crystalline background of a phase-change layer, by means of short, high power laser pulses. In order to improve this data storage concept, it is of great importance to understand the mark formation

  2. Mark formation modeling in optical rewritable recording

    NARCIS (Netherlands)

    Brusche, J.H.; Segal, A.; Vuik, C.; Urbach, H.P.

    2006-01-01

    In optical rewritable recording media, such as the Blu-ray Disc, amorphous marks are formed on a crystalline background of a phase-change layer, by means of short, high power laser pulses. In order to improve this data storage concept, it is of great importance to understand the mark formation proce

  3. Fluorescence spectra of atomic ensembles in a magneto-optical trap as an optical lattice

    CERN Document Server

    Yoon, Seokchan; Kang, Sungsam; Kim, Wook-Rae; Kim, Jung-Ryul; An, Kyungwon

    2015-01-01

    We present a study on characteristics of a magneto-optical trap (MOT) as an optical lattice. Fluorescence spectra of atoms trapped in a MOT with a passively phase-stabilized beam configuration have been measured by means of the photon-counting heterodyne spectroscopy. We observe a narrow Rayleigh peak and well-resolved Raman sidebands in the fluorescence spectra which clearly show that the MOT itself behaves as a three-dimensional optical lattice. Optical-lattice-like properties of the phase-stabilized MOT such as vibrational frequencies and lineshapes of Rayleigh peak and Raman sidebands are investigated systematically for various trap conditions.

  4. Optical transmission spectra in quasiperiodic multilayered photonic structure

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, F F de [Departamento de Fisica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Albuquerque, E L [Departamento de Fisica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Vasconcelos, M S [Departamento de Ciencias Exatas, Centro Federal de Educacao Tecnologica do Maranhao, 65025-001 Sao LuIs-MA (Brazil)

    2006-10-10

    Optical transmission spectra in quasiperiodic multilayered photonic structures, composed of both positive (SiO{sub 2}) and negative refractive index materials, are calculated by using a theoretical model based on the transfer matrix approach for normal incidence geometry. The quasiperiodic structures are substitutional sequences, characterized by the nature of their Fourier spectrum, which can be dense pure point (e.g. Fibonacci sequence) or singular continuous (e.g. Thue-Morse and double-period sequences). The transmission spectra for the case where both refractive indices can be approximated by a different constant show a unique mirror symmetrical profile, with no counterpart for the positive refractive index case, as well as a striking self-similar behaviour related to the Fibonacci sequence. For a more realistic frequency-dependent refractive index, the transmission spectra are characterized by a rich transmission profile of Bragg peaks with no more self-similarity or mirror symmetry.

  5. Optical transmission spectra in quasiperiodic multilayered photonic structure

    Science.gov (United States)

    de Medeiros, F. F.; Albuquerque, E. L.; Vasconcelos, M. S.

    2006-10-01

    Optical transmission spectra in quasiperiodic multilayered photonic structures, composed of both positive (SiO2) and negative refractive index materials, are calculated by using a theoretical model based on the transfer matrix approach for normal incidence geometry. The quasiperiodic structures are substitutional sequences, characterized by the nature of their Fourier spectrum, which can be dense pure point (e.g. Fibonacci sequence) or singular continuous (e.g. Thue-Morse and double-period sequences). The transmission spectra for the case where both refractive indices can be approximated by a different constant show a unique mirror symmetrical profile, with no counterpart for the positive refractive index case, as well as a striking self-similar behaviour related to the Fibonacci sequence. For a more realistic frequency-dependent refractive index, the transmission spectra are characterized by a rich transmission profile of Bragg peaks with no more self-similarity or mirror symmetry.

  6. Optical spectra of UX Ari with BOOTES-2

    Science.gov (United States)

    Caballero-Garcia, M. D.; Castro-Tirado, A.; Jelinek, M.

    2014-07-01

    Following the detection and subsequent monitoring of the new outburst from the RS CVn UX Ari by SWIFT and MAXI (ATEL#5907, #6315 , #6319 ), the 0.6m TELMA robotic telescope at the BOOTES-2 astronomical station Malaga (Spain), obtained optical 4000-9000 A spectra starting at 2014-07-19, 01:32:24.382 UT and ending at 04:25:55.652 UT.

  7. Optical Spectra of Hemoglobin Taken from Alcohol Dependent Humans

    OpenAIRE

    Dudok K.; Dudok T.; Vlokh I.; Vlokh R.

    2005-01-01

    Optical spectra of CNMetHb and CNMetHb-Coomassi G-250, taken from the blood of humans with alcohol dependence, are studied in the spectral range of 450–750nm. The shifts in the spectral absorption maxima of CNMetHb-Coomassi G-250 complexes are observed for the diseased persons with alcohol dependence. The obtained results show that the hemoglobin structure of alcohol dependent humans is changed.

  8. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

    Science.gov (United States)

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

    2012-06-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

  9. Multilevel read-only optical recording methods

    Institute of Scientific and Technical Information of China (English)

    Song Jie; Xu Duan-Yi; Qi Guo-Sheng; Hu Hua; Zhang Qi-Cheng; Xiong Jian-Ping

    2006-01-01

    The advantages of read-only storage is the predominance of optical recording relative to magnetic and other rewritable methods. Multilevel (ML) read-only technology has been a trend to improve the data capacity and transfer rate. Based on the principle and coding method of ML, this paper demonstrates some ML read-only recording methods, of which a new ML read-only recording is developed. This recording method integrates amplitude modulation achieved by the reaction mechanism of physics and chemistry of photoresist with the run-length-limited technology. The discs can be achieved using standard photoresist mastering and replication techniques with great compatibility to conventional binary read-only discs.

  10. HIGH RESOLUTION OPTICAL AND NIR SPECTRA OF HBC 722

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jeong-Eun; Park, Sunkyung [School of Space Research, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 446-701 (Korea, Republic of); Green, Joel D.; Cochran, William D. [Department of Astronomy, University of Texas at Austin, TX (United States); Kang, Wonseok; Lee, Sang-Gak [National Youth Space Center, 200 Deokheungyangjjok-gil, Dongil-myeon, Goheung-gun, Jeollanam-do 548-951 (Korea, Republic of); Sung, Hyun-Il, E-mail: jeongeun.lee@khu.ac.kr, E-mail: sunkyung@khu.ac.kr, E-mail: joel@astro.as.utexas.edu, E-mail: wdc@astro.as.utexas.edu, E-mail: wskang@kywa.or.kr, E-mail: sanggak@kywa.or.kr, E-mail: hisung@kasi.re.kr [Korea Astronomy and Space Science Institute, 776 Daedeok-daero, Yuseong-gu, Daejeon 305-348 (Korea, Republic of)

    2015-07-01

    We present the results of high resolution (R ≥ 30,000) optical and near-IR spectroscopic monitoring observations of HBC 722, a recent FU Orionis object that underwent an accretion burst in 2010. We observed HBC 722 in the optical/near-IR with the Bohyunsan Optical Echelle Spectrograph, Hobby–Eberly Telescope-HRS, and Immersion Grating Infrared Spectrograph, at various points in the outburst. We found atomic lines with strongly blueshifted absorption features or P Cygni profiles, both evidence of a wind driven by the accretion. Some lines show a broad double-peaked absorption feature, evidence of disk rotation. However, the wind-driven and disk-driven spectroscopic features are anti-correlated in time; the disk features became strong as the wind features disappeared. This anti-correlation might indicate that the rebuilding of the inner disk was interrupted by the wind pressure during the first 2 years. The half-width at half-depth of the double-peaked profiles decreases with wavelength, indicative of the Keplerian rotation; the optical spectra with the disk feature are fitted by a G5 template stellar spectrum convolved with a rotation velocity of 70 km s{sup −1} while the near-IR disk features are fitted by a K5 template stellar spectrum convolved with a rotation velocity of 50 km s{sup −1}. Therefore, the optical and near-IR spectra seem to trace the disk at 39 and 76 R{sub ⊙}, respectively. We fit a power-law temperature distribution in the disk, finding an index of 0.8, comparable to optically thick accretion disk models.

  11. Recording 2-D Nutation NQR Spectra by Random Sampling Method.

    Science.gov (United States)

    Glotova, Olga; Sinyavsky, Nikolaj; Jadzyn, Maciej; Ostafin, Michal; Nogaj, Boleslaw

    2010-10-01

    The method of random sampling was introduced for the first time in the nutation nuclear quadrupole resonance (NQR) spectroscopy where the nutation spectra show characteristic singularities in the form of shoulders. The analytic formulae for complex two-dimensional (2-D) nutation NQR spectra (I = 3/2) were obtained and the condition for resolving the spectral singularities for small values of an asymmetry parameter η was determined. Our results show that the method of random sampling of a nutation interferogram allows significant reduction of time required to perform a 2-D nutation experiment and does not worsen the spectral resolution.

  12. Infrared Spectra and Optical Constants of Elusive Amorphous Methane

    Science.gov (United States)

    Gerakines, Perry A.; Hudson, Reggie L.

    2015-01-01

    New and accurate laboratory results are reported for amorphous methane (CH4) ice near 10 K for the study of the interstellar medium (ISM) and the outer Solar System. Near- and mid-infrared (IR) data, including spectra, band strengths, absorption coefficients, and optical constants, are presented for the first time for this seldom-studied amorphous solid. The apparent IR band strength near 1300 cm(exp -1) (7.69 micrometer) for amorphous CH4 is found to be about 33% higher than the value long used by IR astronomers to convert spectral observations of interstellar CH4 into CH4 abundances. Although CH4 is most likely to be found in an amorphous phase in the ISM, a comparison of results from various laboratory groups shows that the earlier CH4 band strength at 1300 cm(exp -1) (7.69 micrometer) was derived from IR spectra of ices that were either partially or entirely crystalline CH4 Applications of the new amorphous-CH4 results are discussed, and all optical constants are made available in electronic form.

  13. Optical Recording of Neuronal Circuit Dynamics

    OpenAIRE

    Wolf, Alexander

    2007-01-01

    This work deals with the optical recording of cerebellar circuit dynamics from acute brain slices of the cerebellar surface. This preparation preserves the functional connectivity of the cerebellar cortex. It was used to investigate the function of Kv3 potassium channels in the cerebellar granule cell axon. Double knockout mice lacking both Kv3.1 and Kv3.3 potassium channels display severe motor deficits, while mice lacking only Kv3.1 or Kv3.3 do not. Since granule cells express both Kv3.1 an...

  14. Power spectra of extinction in the fossil record

    CERN Document Server

    Newman, M E J; Eble, Gunther J.

    1998-01-01

    Recent Fourier analyses of fossil extinction data have indicated that the power spectrum of extinction during the Phanerozoic may take the form of 1/f noise, a result which, it has been suggested, could be indicative of the presence of "critical dynamics" in the processes giving rise to extinction. In this paper we examine extinction power spectra in some detail, using family-level data from a variety of different sources. We find that although the average form of the power spectrum roughly obeys the 1/f law, the spectrum can be represented more accurately by dividing it into two regimes: a low-frequency one which is well fit by an exponential, and a high-frequency one in which it follows a power law with a 1/f^2 form. We give explanations for the occurrence of each of these behaviours and for the position of the cross-over between them.

  15. Image density property of optical information recording microcapsule material

    Science.gov (United States)

    Lai, Weidong; Li, Xiaowei; Li, Xinzheng; Fu, Guangsheng

    2009-05-01

    The microcapsules can act as novel optical functional material in which the optical recording substance such as color-forming substance, photoinitiator and prepolymer are encapsulated. In this paper, the microcapsules with average particle diameter of 300nm are prepared with interfacial polymerization method. The optical responding character of the microcapsule is analyzed based on IR spectra and image density technique. Results show that the microcapsule material encapsulated prepolymer TMPTA and photoinitiator Irgacure-ITX, TPO has thermal phase-change at 140°C, at which the penetrability of the microcapsule has the highest efficiency. With the increase of exposure time, the reduction in absorption intensities of the prepolymer TMPTA are observed at 1635cm-1 of C=C stretching and 898cm-1 of C-H stretching on the C=C molecular bond. Such a result can be ascribed to the double bond cleavage process of the prepolymer TMPTA is initiated by the optical-exposed photoinitiator, and superpolymer network is formed. The image density contrast between the unexposed and exposed microcapsule is enhanced with exposure time increased.

  16. High Resolution Optical and NIR Spectra of HBC 722

    CERN Document Server

    Lee, Jeong-Eun; Green, Joel D; Cochran, William D; Kang, Wonseok; Lee, Sang-Gak; Sung, Hyun-Il

    2015-01-01

    We present the results of high resolution (R$\\ge$30,000) optical and near-IR spectroscopic monitoring observations of HBC 722, a recent FU Orionis object that underwent an accretion burst in 2010. We observed HBC 722 in optical/near-IR with the BOES, HET-HRS, and IGRINS spectrographs, at various points in the outburst. We found atomic lines with strongly blueshifted absorption features or P Cygni profiles, both evidence of a wind driven by the accretion. Some lines show a broad double-peaked absorption feature, evidence of disk rotation. However, the wind-driven and disk-driven spectroscopic features are anti-correlated in time; the disk features became strong as the wind features disappeared. This anti-correlation might indicate that the rebuilding of the inner disk was interrupted by the wind pressure during the first two years. The Half-Width at Half-Depth (HWHD) of the double-peaked profiles decreases with wavelength, indicative of the Keplerian rotation; the optical spectra with the disk feature are fitt...

  17. Infrared Spectra, Index of Refraction, and Optical Constants of Nitrile Ices Relevant to Titan's Atmosphere

    Science.gov (United States)

    Moore, Marla; Ferrante, Robert; Moore, William; Hudson, Reggie

    2010-01-01

    Spectra and optical constants of nitrite ices known or suspected to be in Titan's atmosphere are presented from 2.5 to 200 microns (4000 to 50 per cm ). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan's winter pole. Ices studied include: HCN, hydrogen cyanide; C2N2, cyanogen; CH3CN, acetonitrile; C 2H5CN, propionitrile; and HC3N, cyanoacetylene. For each of these molecules we report new measurements of the index of refraction, n, determined in both the amorphous- and crystallinephase at 670 nm. Spectra were measured and optical constants were calculated for each nitrite at a variety of temperatures including 20, 35, 50, 75, 95, and 110 K, in the amorphous- and crystalline-phase. This laboratory effort uses a dedicated FTIR spectrometer to record transmission spectra of thin-film ice samples. Laser interference is used to measure film thickness during condensation onto a transparent cold window attached to the tail section of a closed-cycle helium cryostat. Optical constants, real (n) and imaginary (k) refractive indices, are determined using Kramers-Kronig (K-K) analysis. Our calculation reproduces the complete spectrum, including all interference effects. Index of refraction measurements are made in a separate dedicated FTIR spectrometer where interference deposit fringes are measured using two 670 nm lasers at different angles to the ice substrate. A survey of these new measurements will be presented along with a discussion of their validation, errors, and application to Titan data.

  18. FIBER AND INTEGRATED OPTICS, LASER APPLICATIONS, AND OTHER PROBLEMS IN QUANTUM ELECTRONICS: Raman scattering spectra recorded in the course of the water-ice phase transition and laser diagnostics of heterophase water systems

    Science.gov (United States)

    Glushkov, S. M.; Panchishin, I. M.; Fadeev, V. V.

    1989-04-01

    The method of laser Raman spectroscopy was used to study heterophase water systems. The apparatus included an argon laser, an optical multichannel analyzer, and a microcomputer. The temperature dependences of the profiles of the valence (stretching) band in the Raman spectrum of liquid water between + 50 °C and - 7 °C and of polycrystalline ice Ih (from 0 to - 62 °C) were determined, as well as the spectral polarization characteristics of the Raman valence band. A method was developed for the determination of the partial concentrations of the H2O molecules in liquid and solid phases present as a mixture. An analysis was made of the errors of the method and the sources of these errors. Applications of the method to multiparameter problems in more complex water systems (for example, solutions of potassium iodide in water) were considered. Other potential practical applications of the method were discussed.

  19. Optical spectra and lattice dynamics of molecular crystals

    CERN Document Server

    Zhizhin, GN

    1995-01-01

    The current volume is a single topic volume on the optical spectra and lattice dynamics of molecular crystals. The book is divided into two parts. Part I covers both the theoretical and experimental investigations of organic crystals. Part II deals with the investigation of the structure, phase transitions and reorientational motion of molecules in organic crystals. In addition appendices are given which provide the parameters for the calculation of the lattice dynamics of molecular crystals, procedures for the calculation of frequency eigenvectors of utilizing computers, and the frequencies and eigenvectors of lattice modes for several organic crystals. Quite a large amount of Russian literature is cited, some of which has previously not been available to scientists in the West.

  20. UV optical absorption spectra analysis of beryl crystals from Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Isotani, Sadao, E-mail: sisotani@if.usp.b [Instituto de Fisica da Universidade de Sao Paulo, Cidade Universitaria, Sao Paulo (Brazil); Regina Blak, Ana; Watanabe, Shigueo [Instituto de Fisica da Universidade de Sao Paulo, Cidade Universitaria, Sao Paulo (Brazil)

    2010-03-15

    The spectral decomposition analysis was applied to the optical absorption spectra of green and colorless beryl crystals from the Brazilian Eastern Pegmatitic province in the natural state, submitted to heat treatment and irradiated with UV light. The attributions of the lines were made taking into account highly accurate quantum mechanical calculations. The deconvolution of the green beryl spectra revealed four lines, two of them around 12,000 cm{sup -1} (1.5 eV) and two of them around 34,000 cm{sup -1} (4.2 eV) attributed to Fe{sup 2+} and Fe{sup 3+}, respectively. The deconvolution of the colorless beryl spectra without any treatment, after heating and for the same heat treatment followed by UV light irradiation revealed five lines. The analysis of ratio relations showed that the lines at 36,400 cm{sup -1} (4.5 eV) and 41,400 cm{sup -1} (5.1 eV) belongs to a single defect attributed to a silicon dangling bond defect (=Si:). Discussions and comparison with reported defects in quartz have supported the allocation of the lines at 61,000 cm{sup -1} (7.6 eV) and 43,800 cm{sup -1} (5.4 eV) to diamagnetic oxygen vacancy defect (ident toSi-Siident to) and unrelaxed (ident toSi...Siident to) defect, respectively. Finally, the line at 39,100 cm{sup -1} (4.8 eV), quite polarized along the c-axis, was attributed to a (Fe{sup 2+}OH{sup -}) defect in the structural channels.

  1. Mid-infrared spectra of optically selected type 2 quasars

    CERN Document Server

    Zakamska, Nadia L; Strauss, Michael A; Krolik, Julian H

    2008-01-01

    Type 2 quasars are luminous Active Galactic Nuclei whose central engines are seen through large amounts of gas and dust. We present Spitzer spectra of twelve type 2 quasars selected on the basis of their optical emission line properties. Within this sample, we find a surprising diversity of spectra, from those that are featureless to those showing strong PAH emission, deep silicate absorption at 10 micron, hydrocarbon absorption, high-ionization emission lines and H_2 rotational emission lines. About half of the objects in the sample are likely Compton-thick, including the two with the deepest Si absorption. The median star-formation luminosity of the objects in our sample measured from the strength of the PAH features is 5x10^11 L_sun, much higher than for field galaxies or for any other AGN sample, but similar to other samples of type 2 quasars. This suggests an evolutionary link between obscured quasars and peak star formation activity in the host galaxy. Despite the high level of star formation, the bolom...

  2. Optical forensics for tracing counterfeit recorded media

    Science.gov (United States)

    Smith, Patrick J.; O'Doherty, Phelim; Luna, Carlos; McCarthy, Sean

    2004-12-01

    We describe an optical forensic method for tracing a CD back to the pressing machine in which it was created, and present a system we have developed which maintains a library of the 'fingerprints' of such machines and can compare sample CDs against this library. In principle, any security feature that is deliberately created can be copied by a counterfeiter. In our forensic method we concentrate on features that arise spontaneously in the manufacturing process. Such features act as a signature or 'fingerprint'. In the case of CDs we show how the moulding process leaves an imprint of an unpolished part of the 'mirror plate' on the CD surface. Using machine vision and pattern-matching, we demonstrate the use of the system to acquire a positive match of a sample against a pre-recorded library entry created using a different CD from the same mould.

  3. Optical-optical double-resonant multiphoton ionization spectra of Rydberg states of nitrogen dioxide

    Institute of Scientific and Technical Information of China (English)

    Zhang Gui-Yin; Zhang Lian-Shui; Sun Bo; Han Xiao-Feng; Yu Wei

    2005-01-01

    The optical-optical double-resonant multiphoton ionization(OODR-MPI) technique has been applied to the study of the Rydberg states of nitrogen dioxide. The results show that ,althougy the OODR-MPI spectra of NO2 are composed of regular progression bands at different pump laser intensities, their ionization pathways are different.The NO2 mollecule is ionized through the (3+1+1)double-resonant process as the pump laser intensity is in a high value, or else it is through the (1+2+1)rpocess.The final resonant states in the two ionizing processes have been attributed to different Rydberg states.

  4. The optical spectra of X-shaped radio galaxies

    CERN Document Server

    Landt, Hermine; Healey, Stephen E

    2010-01-01

    X-shaped radio galaxies are defined by their peculiar large-scale radio morphology. In addition to the classical double-lobed structure they have a pair of low-luminosity wings that straddles the nucleus at almost right angles to the active lobes, thus giving the impression of an 'X'. In this paper we study for the first time the optical spectral properties of this object class using a large sample (~50 sources). We find that the X-shaped radio population is composed roughly equally of sources with weak and strong emission line spectra, which makes them, in combination with the well-known fact that they preferentially have radio powers intermediate between those of Fanaroff-Riley type I (FR I) and type II (FR II) radio galaxies, the archetypal transition population. We do not find evidence in support of the proposition that the X-shape is the result of a recent merger: X-shaped radio sources do not have unusually broad emission lines, their nuclear environments are in general not dusty, and their host galaxie...

  5. Optical Spectra and Color Nature of Lithium Amphiboles

    Directory of Open Access Journals (Sweden)

    S.I. Konovalenko

    2016-03-01

    Full Text Available Optical absorption spectra of two lithium amphiboles of the pedrisite group from rare-metal peg-matites of the Sangilen rare-metal province in the southeastern part of Tyva have been studied. One of them – a limit magnesian fluoro-sodium pedrisite of yellow-green color – was taken from the rocks hosting pegmatites, and another one – fluoro-sodium ferro-pedrisite of violet-blue color – was taken from pegmatites as such. It has been demonstrated that the color of the yellow-green mineral is associated with absorption bands of Cr3+ ions in the octahedral coordination. Absorption bands of Cr3+ ions in the spectrum of fluoro-sodium pedrisite are formed by a transmission window in the yellow-green region of the spectrum. Therefore, the color of this sample is yellow-green. The color of violet-blue pedrisite is de-fined by intensive absorption bands of charge transfer Fe2+ → Fe3+ 550, 680 nm. Very strong absorption bands of 550 and 680 nm are formed by a transmission window in the violet-blue region of the spectrum. Thus, the color of ferro-pedrisite is violet-blue.

  6. Optical spectra of lactoperoxidase as a function of solvent.

    Science.gov (United States)

    Zelent, B; Yano, T; Ohlsson, P-I; Smith, M L; Paul, J; Vanderkooi, J M

    2005-12-01

    The iron of lactoperoxidase is predominantly high-spin at ambient temperature. Optical spectra of lactoperoxidase indicate that the iron changes from high-spin to low-spin in the temperature range from room temperature to 20 K. The transformation is independent of whether the enzyme is in glycerol/water or solid sugar glass. Addition of the inhibitor benzohydroxamic acid increases the amount of the low-spin form, and again the transformation is independent of whether the protein is in an aqueous solution or a nearly anhydrous sugar. In contrast to lactoperoxidase, horseradish peroxidase remains high-spin over the temperature excursion in both solvents and with addition of benzohydroxamic acid. We conclude that details of the heme pocket of lactoperoxidase allow ligation changes with temperature that are dependent upon the apoprotein but independent of solvent fluctuations. At low pH, lactoperoxidase shows a solvent-dependent transition; the high-spin form is predominant in anhydrous sugar glass, but in the presence of water, the low-spin form is also present in abundance. The active site of lactoperoxidase is not as tightly constrained at low pH as at neutrality, though the enzyme is active over a wide pH range.

  7. Rendering Optical Effects Based on Spectra Representation in Complex Scenes

    OpenAIRE

    Dong, Weiming

    2006-01-01

    http://www.springerlink.com/; Rendering the structural color of natural objects or modern industrial products in the 3D environment is not possible with RGB-based graphics platforms and software and very time consuming, even with the most efficient spectra representation based methods previously proposed. Our framework allows computing full spectra light object interactions only when it is needed, i.e. for the part of the scene that requires simulating special spectra sensitive phenomena. Ach...

  8. Vibrational spectra and non linear optical proprieties of L-histidine oxalate: DFT studies

    Science.gov (United States)

    Ahmed, A. Ben; Elleuch, N.; Feki, H.; Abid, Y.; Minot, C.

    2011-08-01

    This paper presents the results of our calculations on the geometric parameters, vibrational spectra and hyperpolarizability of a nonlinear optical material L-histidine oxalate. Due to the lack of sufficiently precise information on geometric structure in literature, theoretical calculations were preceded by re-determination of the crystal X-ray structure. Single crystal of L-histidine oxalate has been growing by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in the non-Centro symmetric space group P2 12 12 1 of orthorhombic system. The FT-IR and Raman spectra of L-histidine oxalate were recorded and analyzed. The vibrational wave numbers were examined theoretical with the aid of Gaussian98 package of programs using the DFT//B3LYP/6-31G(d) level of theory. The data obtained from vibrational wave number calculations are used to assign vibrational bands obtained in IR and Raman spectroscopy of the studied compound. The geometrical parameters of the title compound are in agreement with the values of similar structures. To investigate microscopic second order non-linear optical NLO behaviour of the examined complex, the electric dipole μtot, the polarizability αtot and the hyperpolarizability βtot were computed using DFT//B3LYP/6-31G(d) method. According to our calculation, the title compound exhibits non-zero βtot value revealing microscopic second order NLO behaviour.

  9. Krypton K-shell X-ray spectra recorded by the HENEX spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Seely, J.F. [Naval Research Laboratory, Space Science Division, Washington DC 20375 (United States)]. E-mail: john.seely@nrl.navy.mil; Back, C.A. [Lawrence Livermore National Laboratory, Livermore CA 94550 (United States); Constantin, C. [Lawrence Livermore National Laboratory, Livermore CA 94550 (United States); Lee, R.W. [Lawrence Livermore National Laboratory, Livermore CA 94550 (United States); Chung, H.-K. [Lawrence Livermore National Laboratory, Livermore CA 94550 (United States); Hudson, L.T. [National Institute of Standards and Technology, Gaithersburg MD 20899 (United States); Szabo, C.I. [National Institute of Standards and Technology, Gaithersburg MD 20899 (United States); Henins, A. [National Institute of Standards and Technology, Gaithersburg MD 20899 (United States); Holland, G.E. [SFA Inc., 9315 Largo Drive West Suite 200, Largo MD 20774 (United States); Atkin, R. [Tiger Innovations, L.L.C., 3610 Vacation Lane, Arlington VA 22207 (United States); Marlin, L. [Naval Research Laboratory, Space Science Division, Washington DC 20375 (United States)

    2006-05-15

    High-resolution X-ray spectra were recorded by the High-Energy Electronic X-ray (HENEX) spectrometer from a variety of targets irradiated by the Omega laser at the Laboratory for Laser Energetics. The HENEX spectrometer utilizes four reflection crystals covering the 1-20keV energy range and one quartz(10-11) transmission crystal (Laue geometry) covering the 11-40keV range. The time-integrated spectral images were recorded on five CMOS X-ray detectors. In the spectra recorded from krypton-filled gasbag and hohlraum targets, the helium-like K-shell transitions n=1-2, 1-3, and 1-4 appeared in the 13-17keV energy range. A number of additional spectral features were observed at energies lower than the helium-like n=1-3 and n=1-4 transitions. Based on computational simulations of the spectra using the FLYCHK/FLYSPEC codes, which included opacity effects, these additional features are identified to be inner-shell transitions from the Li-like through N-like krypton charge states. The comparisons of the calculated and observed spectra indicate that these transitions are characteristic of the plasma conditions immediately after the laser pulse when the krypton density is 2x10{sup 18}cm{sup -3} and the electron temperature is in the range 2.8-3.2keV. These spectral features represent a new diagnostic for the charge state distribution, the density and electron temperature, and the plasma opacity. Laboratory experiments indicate that it is feasible to record K-shell spectra from gold and higher Z targets in the >60keV energy range using a Ge(220) transmission crystal.

  10. Optical and Thermal Properties of Nickel-Azo Dyes for Digital Versatile Disc-Recordable

    Institute of Scientific and Technical Information of China (English)

    魏斌; 吴谊群; 顾冬红; 干福熹

    2003-01-01

    We investigate the absorption spectra, optical constants and thermal decomposition as well as red-light (650 nm)static recording properties of three novel nickel-azo dye filrns based on 4-methylthiazole, benzothiazole and 6-methylbenzothiazole. Particularly, we obtain the nickel-azo complex film based on 4-methylthiazole, peaking at 562nm and 613nm, with higher refractive index (n = 2.46) and lower extinction coefficient (k = 0.18) at the wavelength 650nm and a sharp threshold of thermal decomposition at 330℃. The results of the static optical recording test of this dye film indicate that high reflectivity contrast of 51% can be observed at a laser writing power of 5.9mW and pulse width of 350ns. These results imply that the nickel-azo complex based on 4-methylthiazole is a promising candidate for a recording medium of digital versatile disc-recordable.

  11. The Physics of Thin Film Optical Spectra An Introduction

    CERN Document Server

    Stenzel, Olaf

    2005-01-01

    The book is intended to bridge the gap between fundamental physics courses (such as optics, electrodynamics, quantum mechanics and solid state physics) and highly specialized literature on the spectroscopy, design, and application of optical thin film coatings. Basic knowledge from the above-mentioned courses is therefore presumed. Starting from fundamental physics, the book enables the reader derive the theory of optical coatings and to apply it to practically important spectroscopic problems. Both classical and semiclassical approaches are included. Examples describe the full range of classical optical coatings in various spectral regions as well as highly specialized new topics such as rugate filters and resonant grating waveguide structures.

  12. Review of Past Nuclear Accidents: Source Terms and Recorded Gamma-Ray Spectra

    OpenAIRE

    Sanderson, D.C.W.; Cresswell, A.; Allyson, J.D.; McConville, P.; Department of the Environment: Radioactive Substances Division

    1997-01-01

    Airborne gamma ray spectrometry using high volume scintillation detectors, optionally in conjunction with Ge detectors, has potential for making rapid environmental measurements in response to nuclear accidents. A literature search on past nuclear accidents has been conducted to define the source terms which have been experienced so far. Selected gamma ray spectra recorded after past accidents have also been collated to examine the complexity of observed behaviour.

  13. Displacement spectra and displacement modification factors, based on records from Greece

    OpenAIRE

    Athanassiadou, C. J.; Karakostas, C. Z.; Margaris, B. N.; Kappos, A. J.

    2011-01-01

    Elastic and inelastic displacement spectra (for periods up to 4.0 s) are derived, using a representative sample of acceleration records from Greece, carefully selected based on magnitude, distance and peak ground acceleration criteria, and grouped into three ground type categories according to the Eurocode 8 (EC8) provisions. The modification factor for the elastic design spectrum adopted in EC8 for accounting for damping is verified herein and is found to be satisfactory in the short to medi...

  14. Optical calculations and in-situ measurement of transmittance spectra of contaminant thin films

    Science.gov (United States)

    Shimazaki, Kazunori; Miyazaki, Eiji; Kimoto, Yugo

    2016-09-01

    Molecular contaminants outgassed from organic materials used for the spacecraft degrade the performance of optical surfaces of spacecraft. The influence of contaminants outgassed from epoxy resin on the spectral transmittance of the quartz substrate was investigated with an in-situ measurement system. The system can deposit the contaminants on temperature-controlled quartz substrates and the transmittance spectra were measured immediately after deposition in vacuum ambient. We tried to obtain the optical constants of the contaminant using transmittance spectrum and simple optical models for optical calculations. The optical constants were described with a harmonic oscillator model and the effective medium approximation model. This paper reports the in-situ measurement results of transmittance spectra of the epoxy-resin-induced contaminants. In addition, the result of optical calculations using the obtained optical constants were compared to the measurement results.

  15. Polarization holographic optical recording of a new photochromic diarylethene

    Science.gov (United States)

    Pu, Shouzhi; Miao, Wenjuan; Chen, Anyin; Cui, Shiqiang

    2008-12-01

    A new symmetrical photochromic diarylethene, 1,2-bis[2-methyl-5-(3-methoxylphenyl)-3-thienyl]perfluorocyclopentene (1a), was synthesized, and its photochromic properties were investigated. The compound exhibited good photochromism both in solution and in PMMA film with alternating irradiation by UV/VIS light, and the maxima absorption of its closed-ring isomer 1b are 582 and 599 nm, respectively. Using diarylethene 1b/PMMA film as recording medium and a He-Ne laser (633 nm) for recording and readout, four types of polarization and angular multiplexing holographic optical recording were performed perfectly. For different types of polarization recording including parallel linear polarization recording, parallel circular polarization recording, orthogonal linear polarization recording and orthogonal circular polarization recording,have been accomplished successfully. The results demonstrated that the orthogonal circular polarization recording is the best method for polarization holographic optical recording when this compound was used as recording material. With angular multiplexing recording technology, two high contrast holograms were recorded in the same place on the film with the dimension of 0.78 μm2.

  16. Optical Spectra of the High Voltage Erosive Water Discharge

    CERN Document Server

    Pirozerski, A L

    2008-01-01

    In the present paper kinetics of emission spectra of the high voltage erosive water discharge at near ultraviolet and visible spectral ranges has been investigated. Obtained results show a similarity of physical properties of this discharge (and of corresponding plasmoids) to that of some other types of erosional discharges which also result in the formation of dust-gas fireballs.

  17. Investigating the Fabrication Imperfections of Plasmonic Nanohole Arrays and Its Effect on the Optical Transmission Spectra

    Directory of Open Access Journals (Sweden)

    Amr M. Mahros

    2015-01-01

    Full Text Available We investigate the extraordinary optical transmission spectra of thin gold films perforated with imperfect nanohole arrays using the finite difference time domain (FDTD method. Exponential shapes for the nanohole sidewalls are used. To the best of our knowledge, such investigation of transmission spectra of imperfect nanohole arrays has not previously been demonstrated. It was found that the asymmetry between the two openings of the circular nanoholes or bending to their sidewalls strongly modifies both the intensity and resonance positions of the transmission spectra. Furthermore, the results of this study assist in explaining the technicality of extraordinary optical transmission phenomenon and why some experimental results on transmission differ from those expected.

  18. The physics of thin film optical spectra an introduction

    CERN Document Server

    Stenzel, Olaf

    2016-01-01

    The book bridges the gap between fundamental physics courses (such as optics, electrodynamics, quantum mechanics and solid state physics) and highly specialized literature on the spectroscopy, design, and application of optical thin film coatings. Basic knowledge from the above-mentioned courses is therefore presumed. Starting from fundamental physics, the book enables the reader derive the theory of optical coatings and to apply it to practically important spectroscopic problems. Both classical and semiclassical approaches are included. Examples describe the full range of classical optical coatings in various spectral regions as well as highly specialized new topics such as rugate filters and resonant grating waveguide structures.The second edition has been updated and extended with respect to probing matter in different spectral regions, homogenous and inhomogeneous line broadening mechanisms and the Fresnel formula for the effect of planar interfaces.

  19. The optical spectra of the brightest mid-IR-selected galaxies

    NARCIS (Netherlands)

    Caputi, K. I.

    2007-01-01

    We present here sore of the first results we have obtained oil the study of the optical spectra, of Spitzer/MIPS 24 mu m selected galaxies in the COSMOS field. This is part of a, series of studies we are conducting to analyse the optical spectral properties of mid-infrared (mid-IR) galaxies with dif

  20. STELLAR POPULATIONS IN MEDIUM REDSHIFT CLUSTERS .2. OPTICAL-INFRARED PHOTOMETRY AND SPECTRA

    NARCIS (Netherlands)

    PICKLES, AJ; VANDERKRUIT, PC

    1991-01-01

    We present optical and infrared photometry (BV RI, J H K) and spectra of galaxies in 6 medium redshift clusters covering the redshift range 0.19 less-than-or-equal-to z less-than-or-equal-to 0.4. The array photometry is used to note the radial distribution of the cluster galaxies with optical and in

  1. A study of aliphatic amino acids using simulated vibrational circular dichroism and Raman optical activity spectra

    CERN Document Server

    Ganesan, Aravindhan; Wang, Feng

    2013-01-01

    Vibrational optical activity (VOA) spectra, such as vibrational circular dichroism (VCD) and Raman optical activity (ROA) spectra, of aliphatic amino acids are simulated using density functional theory (DFT) methods in both gas phase (neutral form) and solution (zwitterionic form), together with their respective infrared (IR) and Raman spectra of the amino acids. The DFT models, which are validated by excellent agreements with the available experimental Raman and ROA spectra of alanine in solution, are employed to study other aliphatic amino acids. The inferred (IR) intensive region (below 2000 cm-1) reveals the signature of alkyl side chains, whereas the Raman intensive region (above 3000 cm-1) contains the information of the functional groups in the amino acids. Furthermore, the chiral carbons of the amino acids (except for glycine) dominate the VCD and ROA spectra in the gas phase, but the methyl group vibrations produce stronger VCD and ROA signals in solution. The C-H related asymmetric vibrations domina...

  2. System for recording bivariate intensity distribution of optical radiation

    Energy Technology Data Exchange (ETDEWEB)

    Vil' danov, R.R.; Deryugin, I.A.; Gladyshev, D.A.; Mirzaeu, A.T.

    1986-02-01

    This paper describes a system for recording the space-energy characteristics of optical radiation based on an MF-6 photodetector matrix and an AI-4096-3M multivariate pulse analyzer. The system can record optical images with from 2 to 64 quantization levels with visual monitoring of input data in the form of a space distribution in axonometric projection. The recording time for a complete image is from 11 to 700 msec. The system has been used to determine and monitor the crosssectional intensity distribution of laser beams as a function of radiation mode.

  3. Vibrational spectra and non linear optical proprieties of L-histidine oxalate: DFT studies.

    Science.gov (United States)

    Ben Ahmed, A; Elleuch, N; Feki, H; Abid, Y; Minot, C

    2011-08-01

    This paper presents the results of our calculations on the geometric parameters, vibrational spectra and hyperpolarizability of a nonlinear optical material L-histidine oxalate. Due to the lack of sufficiently precise information on geometric structure in literature, theoretical calculations were preceded by re-determination of the crystal X-ray structure. Single crystal of L-histidine oxalate has been growing by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in the non-Centro symmetric space group P2(1)2(1)2(1) of orthorhombic system. The FT-IR and Raman spectra of L-histidine oxalate were recorded and analyzed. The vibrational wave numbers were examined theoretical with the aid of Gaussian98 package of programs using the DFT//B3LYP/6-31G(d) level of theory. The data obtained from vibrational wave number calculations are used to assign vibrational bands obtained in IR and Raman spectroscopy of the studied compound. The geometrical parameters of the title compound are in agreement with the values of similar structures. To investigate microscopic second order non-linear optical NLO behaviour of the examined complex, the electric dipole μ(tot), the polarizability α(tot) and the hyperpolarizability β(tot) were computed using DFT//B3LYP/6-31G(d) method. According to our calculation, the title compound exhibits non-zero β(tot) value revealing microscopic second order NLO behaviour. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

  4. Crystal studies, vibrational spectra and non-linear optical properties of L-histidine chloride monohydrate.

    Science.gov (United States)

    Ben Ahmed, A; Feki, H; Abid, Y; Boughzala, H; Minot, C

    2010-01-01

    This paper presents the results of our calculations on the geometric parameters, vibrational spectra and hyperpolarizability of a non-linear optical material L-histidine chloride monohydrate. Due to the lack of sufficiently precise information on geometric parameters available in literature, theoretical calculations were preceded by re-determination of the crystal X-ray structure. Single crystal of L-histidine chloride monohydrate has been growing by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in the non-Centro-symmetric space group P2(1)2(1)2(1) of orthorhombic system. IR spectrum has been recorded in the range [400-4000 cm(-1)]. All the experimental vibrational bands have been discussed and assigned to normal mode or to combinations on the basis of our calculations. The optimized geometric bond lengths and bond angles obtained by using DFT//B3LYP/6-31G (d) method show a good agreement with the experimental data. The calculated vibrational spectra are in well agreement with the experimental one. To investigate microscopic second-order non-linear optical NLO behavior of the examined complex, the electric dipole mu, the polarizability alpha and the hyperpolarizability beta were computed using DFT//B3LYP/6-31G (d) method. The time-dependent density functional theory (TD-DFT) was employed to descript the molecular electron structure of the title compound using the B3LYP/6-31G (d) method. According to our calculations, L-histidine chloride monohydrate exhibits non-zero beta value revealing microscopic second-order NLO behavior. Copyright 2009 Elsevier B.V. All rights reserved.

  5. Crystal studies, vibrational spectra and non-linear optical properties of L-histidine chloride monohydrate

    Science.gov (United States)

    Ahmed, A. Ben; Feki, H.; Abid, Y.; Boughzala, H.; Minot, C.

    2010-01-01

    This paper presents the results of our calculations on the geometric parameters, vibrational spectra and hyperpolarizability of a non-linear optical material L-histidine chloride monohydrate. Due to the lack of sufficiently precise information on geometric parameters available in literature, theoretical calculations were preceded by re-determination of the crystal X-ray structure. Single crystal of L-histidine chloride monohydrate has been growing by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in the non-Centro-symmetric space group P2 12 12 1 of orthorhombic system. IR spectrum has been recorded in the range [400-4000 cm -1]. All the experimental vibrational bands have been discussed and assigned to normal mode or to combinations on the basis of our calculations. The optimized geometric bond lengths and bond angles obtained by using DFT//B3LYP/6-31G (d) method show a good agreement with the experimental data. The calculated vibrational spectra are in well agreement with the experimental one. To investigate microscopic second-order non-linear optical NLO behavior of the examined complex, the electric dipole μ, the polarizability α and the hyperpolarizability β were computed using DFT//B3LYP/6-31G (d) method. The time-dependent density functional theory (TD-DFT) was employed to descript the molecular electron structure of the title compound using the B3LYP/6-31G (d) method. According to our calculations, L-histidine chloride monohydrate exhibits non-zero β value revealing microscopic second-order NLO behavior.

  6. Comparison of optical and electron spectra in an infra-red free electron laser

    Energy Technology Data Exchange (ETDEWEB)

    MacLeod, A.M.; Gillespie, W.A.; Martin, P.F. [Univ. of Abertay, Dundee (United Kingdom)] [and others

    1995-12-31

    Time-resolved electron and optical spectra recently acquired at the FELIX facility are presented, showing the evolution of the respective macropulses. A comparison is made between the optical power output during the macropulse and the measured power extracted from the electron beam using a simple model of the cavity losses. Data are available for a wide range of operating conditions: the wavelength range is from 9 {mu}m to 28 {mu}m and detuning are between 1/4{lambda} and 2{lambda}. The effect of rapid electron beam energy changes on the optical and electron spectra will also be discussed.

  7. Supercontinuum Spectra generation in the single-mode optical fibre with Concave dispersion profile

    Institute of Scientific and Technical Information of China (English)

    Xu Wen-Cheng; Gao Jie-Li; Liang Zhan-Qiang; Chen Qiao-Hong; Liu Song-Hao

    2006-01-01

    In this paper,a new method is proposed to generate broad supercontinuum (SC) spectra in the single-mode optical fibre with concave dispersion profile.We numerically simulate pulse evolutions and discuss physics mechanism in detail for SC spectrum generation in the optical fibre with concave dispersion profile.Furthermore,general criteria are presented for specifying the shape of SC spectrum by introducing normalized parameters,which are related to the fibres and the initial pump pulses.The results show that the flat and broad SC spectra are indeed generated in our proposed optical fibre.

  8. Terahertz-Induced Changes of Optical Spectra in GaAs Quantum Wells

    Institute of Scientific and Technical Information of China (English)

    MI Xian-Wu; CAO Jun-Cheng

    2004-01-01

    @@ We have theoretically investigated optical absorption spectra in GaAs quantum well (QW) driven by both a strong terahertz (THz) field and a near-infrared field within the theory of density matrix. In presence of a strong THz field, the optical transitions in the QW subbands are altered by the THz field. The alteration has a direct impact on the optical absorption and results in the Autler-Townes splitting and the sidebands generation, which is in agreement with the experiments.

  9. Reconfigurable Optical Spectra from Perturbations on Elliptical Whispering Gallery Resonances

    Science.gov (United States)

    Mohageg, Makan; Maleki, Lute

    2008-01-01

    Elastic strain, electrical bias, and localized geometric deformations were applied to elliptical whispering-gallery-mode resonators fabricated with lithium niobate. The resultant perturbation of the mode spectrum is highly dependant on the modal indices, resulting in a discretely reconfigurable optical spectrum. Breaking of the spatial degeneracy of the whispering-gallery modes due to perturbation is also observed.

  10. Easy interpretation of optical two-dimensional correlation spectra

    NARCIS (Netherlands)

    Lazonder, K.; Pshenichnikov, M.S.; Wiersma, D.A.

    2006-01-01

    We demonstrate that the value of the underlying frequency-frequency correlation function can be retrieved from a two-dimensional optical correlation spectrum through a simple relationship. The proposed method yields both intuitive clues and a quantitative measure of the dynamics of the system. The t

  11. The Optical Spectra of X-Shaped Radio Galaxies

    Science.gov (United States)

    2010-01-01

    Sky Survey ( SDSS ; Abazajian et al. 2009) but has only narrow emission lines in its spectrum (see Fig. A1), and J0245+1047, whose X- shaped radio...spectroscopically observed by the SDSS (Data Release 5; see Fig. A1). For another seven sources, namely, J0113+0106, J0115−0000, J0245+1047, J1309−0012...of this task to deblend the indi- vidual features. However, this procedure was not necessary in the case of the SDSS spectra, whose spectral resolution

  12. Optical transmission spectra in symmetrical Fibonacci photonic multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Mauriz, P.W.; Vasconcelos, M.S. [Departamento de Ciencias Exatas, Centro Federal de Educacao Tecnologica do Maranhao, 65025-001 Sao Luis-MA (Brazil); Albuquerque, E.L. [Computational Physics for Engineering Materials, IfB, ETH-Zuerich, CH-8093 Zuerich (Switzerland)], E-mail: eudenilson@dfte.ufrn.br

    2009-01-19

    We study the transmission properties of light through the symmetric Fibonacci photonic multilayers, i.e, a binary one-dimensional quasiperiodic structure, made up of both positive (SiO{sub 2}) and negative refractive index materials with a mirror symmetry. These spectra are calculated by using a theoretical model based on the transfer matrix approach for normal incidence geometry, in which many perfect transmission peaks (the transmission coefficients are equal to the unity) are numerically obtained. Besides, the transmission coefficient exhibits a six-cycle self-similar behavior with respect to the generation number of the Fibonacci sequence.

  13. Optical and terahertz spectra analysis by the maximum entropy method.

    Science.gov (United States)

    Vartiainen, Erik M; Peiponen, Kai-Erik

    2013-06-01

    Phase retrieval is one of the classical problems in various fields of physics including x-ray crystallography, astronomy and spectroscopy. It arises when only an amplitude measurement on electric field can be made while both amplitude and phase of the field are needed for obtaining the desired material properties. In optical and terahertz spectroscopies, in particular, phase retrieval is a one-dimensional problem, which is considered as unsolvable in general. Nevertheless, an approach utilizing the maximum entropy principle has proven to be a feasible tool in various applications of optical, both linear and nonlinear, as well as in terahertz spectroscopies, where the one-dimensional phase retrieval problem arises. In this review, we focus on phase retrieval using the maximum entropy method in various spectroscopic applications. We review the theory behind the method and illustrate through examples why and how the method works, as well as discuss its limitations.

  14. Optical spectra of phthalocyanines and related compounds a guide for beginners

    CERN Document Server

    Isago, Hiroaki

    2015-01-01

    This book displays how optical (absorption, emission, and magnetic circular dichroism) spectra of phthalocyanines and related macrocyclic dyes can be varied from their prototypical ones depending on conditions. As these compounds can be involved in colorful chemistry (which might be driven by impurities in solvents), their spectra behave like the sea-god Proteus in their mutability. Therefore, those who have been engaged with phthalocyanines for the first time, including even educated professional researchers and engineers, may have been embarrassed by the deceptive behavior of their compounds and could have, in the worst cases, given up their projects. This book is aimed not merely at reviewing the optical spectra, but also at helping such people, particularly beginners, to figure them out by showing some examples of their prototypical spectra and their variations in several situations. For the purpose of better understanding, the book also provides an introduction to their theoretical backgrounds as graphic...

  15. Evolution of infrared spectra and optical emission spectra in hydrogenated silicon thin films prepared by VHF-PECVD

    Science.gov (United States)

    Hou, Guo-Fu; Geng, Xin-Hua; Zhang, Xiao-Dan; Sun, Jian; Zhang, Jian-Jun; Zhao, Ying

    2011-07-01

    A series of hydrogenated silicon thin films with varying silane concentrations have been deposited by using very high frequency plasma enhanced chemical vapor deposition (VHF-PECVD) method. The deposition process and the silicon thin films are studied by using optical emission spectroscopy (OES) and Fourier transfer infrared (FTIR) spectroscopy, respectively. The results show that when the silane concentration changes from 10% to 1%, the peak frequency of the Si-H stretching mode shifts from 2000 cm-1 to 2100 cm-1, while the peak frequency of the Si—H wagging—rocking mode shifts from 650 cm-1 to 620 cm-1. At the same time the SiH/Hα intensity ratio in the plasma decreases gradually. The evolution of the infrared spectra and the optical emission spectra demonstrates a morphological phase transition from amorphous silicon (a-Si:H) to microcrystalline silicon (μc-Si:H). The structural evolution and the μc-Si:H formation have been analyzed based on the variation of Hα and SiH intensities in the plasma. The role of oxygen impurity during the plasma process and in the silicon films is also discussed in this study.

  16. Quantum-dot based nanothermometry in optical plasmonic recording media

    Energy Technology Data Exchange (ETDEWEB)

    Maestro, Laura Martinez [Fluorescence Imaging Group, Departamento de Física de Materiales, Facultad de Ciencias Físicas, Universidad Autónoma de Madrid, Madrid 28049 (Spain); Centre for Micro-Photonics, Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia); Zhang, Qiming; Li, Xiangping; Gu, Min [Centre for Micro-Photonics, Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia); Jaque, Daniel [Fluorescence Imaging Group, Departamento de Física de Materiales, Facultad de Ciencias Físicas, Universidad Autónoma de Madrid, Madrid 28049 (Spain)

    2014-11-03

    We report on the direct experimental determination of the temperature increment caused by laser irradiation in a optical recording media constituted by a polymeric film in which gold nanorods have been incorporated. The incorporation of CdSe quantum dots in the recording media allowed for single beam thermal reading of the on-focus temperature from a simple analysis of the two-photon excited fluorescence of quantum dots. Experimental results have been compared with numerical simulations revealing an excellent agreement and opening a promising avenue for further understanding and optimization of optical writing processes and media.

  17. Optical, mass, and auger spectra from e-bombarded KBr

    Energy Technology Data Exchange (ETDEWEB)

    Arakawa, E.T.; Kamada, M.

    1988-01-01

    We have measured the mass spectrum and optical emission lines of neutral potassium atoms ejected from KBr at T = 300/degree/K and 443/degree/K bombarded by 2-keV electrons. The room-temperature data may be complicated by the nonstoichiometry of the alkali-enriched sample surface and seem difficult to interpret. The high-temperature sample, which maintains the proper stoichiometry, produces data in support of gas-phase excitation of alkali atoms desorbed from the surface. 15 refs., 4 figs.

  18. Exciton States and Linear Optical Spectra of Semiconducting Carbon Nanotubes under Uniaxial Strain

    Institute of Scientific and Technical Information of China (English)

    YU Gui-Li; JIA Yong-Lei

    2009-01-01

    Considering the exciton effect,the linear optical spectra of semiconducting single-walled carbon nanotubes (SWNTs) under uniaxial strain are theoretically studied by using the standard formulae of Orr and Ward [Mol.Phys.20(1971)513].It is found that due to the wrapping effect existing in the semiconducting zigzag tubes,the excitation energies of the linear optical spectra show two different kinds of variations with increasing uniaxial strain,among which one decreases such as tube (11,0),and the other increases firstly and then decreases such as tube (10,0).These variations of the linear optical spectra are consistent with the changes of the exciton binding energies or the (quasi)continuum edge of these SWNTs calculated in our previous work,which can be used as a supplemented tool to detect the deformation degree of an SWNT under uniaxiai strain.

  19. Absolute Determination of Optical Constants by a Direct Physical Modeling of Reflection Electron Energy Loss Spectra

    CERN Document Server

    Xu, H; Toth, J; Tokesi, K; Ding, Z J

    2016-01-01

    We present an absolute extraction method of optical constants of metal from the measured reflection electron energy loss (REELS) spectra by using the recently developed reverse Monte Carlo (RMC) technique. The method is based on a direct physical modeling of electron elastic and electron inelastic scattering near the surface region where the surface excitation becomes important to fully describe the spectrum loss feature intensity in relative to the elastic peak intensity. An optimization procedure of oscillator parameters appeared in the energy loss function (ELF) for describing electron inelastic scattering due to the bulk- and surface-excitations was performed with the simulated annealing method by a successive comparison between the measured and Monte Carlo simulated REELS spectra. The ELF and corresponding optical constants of Fe were obtained from the REELS spectra measured at incident energies of 1000, 2000 and 3000 eV. The validity of the present optical data has been verified with the f- and ps-sum r...

  20. Enumerative Encoding of TMTR Codes for Optical Recording Channel

    Directory of Open Access Journals (Sweden)

    Tsai Hui-Feng

    2010-01-01

    Full Text Available We propose a new time-varying maximum transition run (TMTR code for DVD recording systems, which has a rate higher than the EFMPlus code and a lower power spectral density (PSD at low frequencies. An enumeration method for constructing the new TMTR code is presented. Computer simulations indicate that the proposed TMTR code outperforms the EFMPlus code in error performance when applied to partial response optical recording channels.

  1. [Efficient method of analysis of optical spectra from kinetic studies].

    Science.gov (United States)

    Skvortsov, A N

    2009-01-01

    The application of principal components for the analysis of kinetic data obtained by optical spectroscopy is described. The use of singular value decomposition (SVD) for stable and reproducible generation of principal components, details of realization, advantages and drawbacks of the method are discussed. The described method with minor modifications may be used in a wide variety of UV-spectroscopy applications in molecular biology and biophysics. The developed method was applied to study the reaction of platinum anticancer drug, cisplatin, with DNA and methionine. Use of sensitive UV-spectroscopy allowed to study low platinum concentrations, typical for biological systems. It has been shown, that reactions of cisplatin with DNA and L-methionine generally follow the same pathway both at high and low concentrations.

  2. Hardware authentication using transmission spectra modified optical fiber.

    Energy Technology Data Exchange (ETDEWEB)

    Grubbs, Robert K.; Romero, Juan A.

    2010-09-01

    The ability to authenticate the source and integrity of data is critical to the monitoring and inspection of special nuclear materials, including hardware related to weapons production. Current methods rely on electronic encryption/authentication codes housed in monitoring devices. This always invites the question of implementation and protection of authentication information in an electronic component necessitating EMI shielding, possibly an on board power source to maintain the information in memory. By using atomic layer deposition techniques (ALD) on photonic band gap (PBG) optical fibers we will explore the potential to randomly manipulate the output spectrum and intensity of an input light source. This randomization could produce unique signatures authenticating devices with the potential to authenticate data. An external light source projected through the fiber with a spectrometer at the exit would 'read' the unique signature. No internal power or computational resources would be required.

  3. High Resolution Optical Spectra of HBC 722 after Outburst

    CERN Document Server

    Lee, Jeong-Eun; Lee, Sang-Gak; Sung, Hyun-Il; Lee, Byeong-Cheol; Sung, Hwankyung; Green, Joel D; Jeon, Young-Beom

    2011-01-01

    We report the results of our high resolution optical spectroscopic monitoring campaign ($\\lambda$ = 3800 -- 8800 A, R = 30000 -- 45000) of the new FU Orionis-type object HBC 722. We observed HBC 722 with the BOES 1.8-m telescope between 2010 November 26 and 2010 December 29 and FU Orionis itself on 2011 January 26. We detect a number of previously unreported high-resolution K I and Ca II lines beyond 7500 A. We resolve the H$\\alpha$ and Ca II line profiles into three velocity components, which we attribute to both disk and outflow. The increased accretion during outburst can heat the disk to produce the relatively narrow absorption feature and launch outflows appearing as high velocity blue and redshifted broad features.

  4. Optical and UV spectra of RS CVn stars

    Science.gov (United States)

    Ramsey, Lawrence W.

    1990-01-01

    The observed phenomenology in RS CVn and related binary systems is considered in terms of its modeling according to solar activity by examining UV and optical spectroscopy. Current data are examined to validate the existence of cool starspots, plage, prominences, and flares, as well as to determine the consistency of spatial correlations given by these data. RS CVn stars show spots at or near the poles, contrasting the low latitudes of solar spots; plage appears to be associated with cool spots on BY Draconis-like systems; plage and prominences, although identified as distinct phenomena, are theorized to be the same event in some cases. More spectroscopic and photometric observations are proposed to identify the detailed structure and locations of spots. UV and visible data are also required to distinguish plage regions from flare variations as well as determine the relation of extended structures to starspot and plage phenomena in RS CVn systems.

  5. Optical spectra of the heavy fermion uniaxial ferromagnet UGe2

    Science.gov (United States)

    Guritanu, V.; Armitage, N. P.; Tediosi, R.; Saxena, S. S.; Huxley, A.; van der Marel, D.

    2008-11-01

    We report a detailed study of UGe2 single crystals using infrared reflectivity and spectroscopic ellipsometry. The optical conductivity suggests the presence of a low-frequency interband transition and a narrow free-carrier response with strong frequency dependence of the scattering rate and effective mass. We observe sharp increase in the low-frequency mass and reduction in scattering rate below the upper ferromagnetic transition TC=53K indicating the emergence of a heavy fermion state triggered by the ferromagnetic order. The characteristic changes are exhibited most strongly at an energy scale below 12 meV. They recover their unrenormalized value above TC and for ω>40meV . In contrast no sign of an anomaly is seen at the lower transition temperature of unknown nature, Tx˜30K , observed in transport and thermodynamic experiments.

  6. Comparison between reflectance spectra obtained with an integrating sphere and a fiber optic collection system

    Science.gov (United States)

    Norvang Nilsen, Lill T.; Fiskerstrand, Elisanne J.; Koenig, Karsten; Bakken, B.; Grini, D.; Standahl, O.; Milner, Thomas E.; Berns, Michael W.; Nelson, J. Stuart; Svaasand, Lars O.

    1996-01-01

    Visible reflectance spectra of human skin might serve as a valuable tool for determining blood volume and pigmentation. They can therefore be used to evaluate the response to various skin treatments such as, e.g., port-wine stain therapy. A fiber-optic system is preferable for clinical evaluation of the therapeutic response due to its higher flexibility. Diffuse reflectance spectra obtained using a fiber system are compared with the corresponding spectra from an integrating sphere system. The results show that the most accurate reflectance spectra are obtained using the integrating sphere set-up. The aperture should then be much larger than the optical penetration depth of the skin. The system will then collect all the reflected light from superficial and deeper layers, and this enables a qualitative comparison between the wavelengths. However, the size and localization of many dermal lesions limit its use. In these cases the fiber-optic system is preferable. Light with an optical penetration depth shorter than the distance between the excitation and collecting fibers is, however, favorized. Normal dermis has typically a penetration depth of 600 micrometers and 2000 micrometers for, respectively, green/yellow and red light. Consequently, the collection efficiency of a typical fiber-optic system with a distance of 100 - 200 micrometers between the emitting and collecting fibers, will be higher in the green/yellow than in the red part of the spectrum. It is, however, important to remember that the relevant parameter is the change in reflectance at each particular wavelength, rather than comparison between the wavelengths. When such a comparison is required, the spectra collected by the fiber-optic system can be calibrated. The more accurate integrating sphere system is maybe preferable in a research laboratory environment, whereas the more flexible fiber-optic system is the most applicable for use in the clinic.

  7. Accelerated optical holographic recording using bis-DNO

    DEFF Research Database (Denmark)

    Rasmussen, Palle H.; Ramanujam, P.S.; Hvilsted, Søren

    1999-01-01

    The design, synthesis and optical holographic recording properties of bis-DNO are reported. Bis-DNO is composed of two identical azobenzene oligoornithine segments (DNO) connected via a dipeptide linker. The two segments were assembled in a parallel fashion at the two amino groups of the dipeptide...

  8. Calculation of Raman optical activity spectra for vibrational analysis.

    Science.gov (United States)

    Mutter, Shaun T; Zielinski, François; Popelier, Paul L A; Blanch, Ewan W

    2015-05-01

    By looking back on the history of Raman Optical Activity (ROA), the present article shows that the success of this analytical technique was for a long time hindered, paradoxically, by the deep level of detail and wealth of structural information it can provide. Basic principles of the underlying theory are discussed, to illustrate the technique's sensitivity due to its physical origins in the delicate response of molecular vibrations to electromagnetic properties. Following a short review of significant advances in the application of ROA by UK researchers, we dedicate two extensive sections to the technical and theoretical difficulties that were overcome to eventually provide predictive power to computational simulations in terms of ROA spectral calculation. In the last sections, we focus on a new modelling strategy that has been successful in coping with the dramatic impact of solvent effects on ROA analyses. This work emphasises the role of complementarity between experiment and theory for analysing the conformations and dynamics of biomolecules, so providing new perspectives for methodological improvements and molecular modelling development. For the latter, an example of a next-generation force-field for more accurate simulations and analysis of molecular behaviour is presented. By improving the accuracy of computational modelling, the analytical capabilities of ROA spectroscopy will be further developed so generating new insights into the complex behaviour of molecules.

  9. A first-principles investigation of the optical spectra of oxidized graphene

    KAUST Repository

    Singh, Nirpendra

    2013-01-14

    The electronic and optical properties of mono, di, tri, and tetravacancies in graphene are studied in comparison to each other, using density functional theory. In addition, oxidized monovacancies are considered for different oxygen concentrations. Pristine graphene is found to be more absorptive than any defect configuration at low energy. We demonstrate characteristic differences in the optical spectra of the various defects for energies up to 3 eV. This makes it possible to quantify by optical spectroscopy the ratios of the defect species present in a sample.

  10. Multilevel optical data recording methods on phase-change media

    Institute of Scientific and Technical Information of China (English)

    肖家曦; 齐国生; 佘鹏; 刘嵘; 徐端颐

    2003-01-01

    Multilevel data storage (ML) is a new method in the optical storage field, which is also a trend for improving the capability of future optical discs. This article introduces several ML methods based on phase-change media including pit depth modulation (PDM) and mark radial width modulation (MRWM). In addition, some disadvantages and advantages concerning the principle of these methods will be discussed. Finally, a new ML method will be advanced, through which the levels in one recording pit will be increased evidently.

  11. The Radio-optical Spectra of BL Lacs and Possible Relatives

    Science.gov (United States)

    Dennett-Thorpe, J.

    I consider the suggestion that, in a complete sample of flat-spectrum radio sources with available optical spectra (Marcha et al 1996), the strong emission line objects, or those with passive elliptical spectra are close relatives of the BL Lacs. New observations at four frequencies from 8 to 43GHz are presented, together with evidence for radio variability. Combined with other radio and optical data from the literature, we are able to construct the non-thermal SEDs and use these to address the questions: are the optically passive objects potentially `unrecognised' BL Lacs (either intrinsically weak and/or hidden by starlight)? What is the relationship between the surprising number of strong emission-line objects and the BL Lacs?

  12. The Gamma-ray Blazar Quest: new optical spectra, state of art and future perspectives

    CERN Document Server

    Massaro, F; D'Abrusco, R; Landoni, M; Masetti, N; Ricci, F; Milisavljevic, D; Paggi, A; Chavushyan, V; Jiménez-Bailón, E; Patiño-Álvarez, V; Strader, J; Chomiuk, L; La Franca, F; Smith, Howard A; Tosti, G

    2016-01-01

    We recently developed a procedure to recognize gamma-ray blazar candidates within the positional uncertainty regions of the unidentified/unassociated gamma-ray sources (UGSs). Such procedure was based on the discovery that Fermi blazars show peculiar infrared colors. However, to confirm the real nature of the selected candidates, optical spectroscopic data are necessary. Thus, we performed an extensive archival search for spectra available in the literature in parallel with an optical spectroscopic campaign aimed to reveal and confirm the nature of the selected gamma-ray blazar candidates. Here, we first search for optical spectra of a selected sample of gamma-ray blazar candidates that can be potential counterparts of UGSs using the Sloan Digital Sky Survey (SDSS DR12). This search enables us to update the archival search carried out to date. We also describe the state-of-art and the future perspectives of our campaign to discover previously unknown gamma-ray blazars.

  13. Optical voice recorder by off-axis digital holography.

    Science.gov (United States)

    Matoba, Osamu; Inokuchi, Hiroki; Nitta, Kouichi; Awatsuji, Yasuhiro

    2014-11-15

    An optical voice recorder capable of recording and reproducing propagating sound waves by using off-axis digital holography, as well as quantitative visualization, is presented. Propagating sound waves temporally modulate the phase distribution of an impinging light wave via refractive index changes. This temporally modulated phase distribution is recorded in the form of digital holograms by a high-speed image sensor. After inverse propagation using Fresnel diffraction of a series of the recorded holograms, the temporal phase profile of the reconstructed object wave at each three-dimensional position can be used to reproduce the original sound wave. Experimental results using a tuning fork vibrating at 440 Hz and a human voice are presented to show the feasibility of the proposed method.

  14. Parallel optical evaluation of double-exposure records in optical metrology.

    Science.gov (United States)

    Arnold, W; Hinsch, K D

    1989-02-15

    The evaluation of double-exposure records in optical metrology (speckle photography or particle image velocimetry) is simplified by using two-step optical processing that is performed on many interrogation areas simultaneously by a 2-D array of narrow focused light beams. A first application of this procedure to the original record, if dimensioned properly, produces an array of small nonoverlapping Young's fringe systems. The photographic record of these patterns is subjected to the same operation once more, each beam illuminating precisely one pattern. The resulting output is an array of autocorrelation functions that are a direct representation of the displacement field since the spacing of respective side peaks gives the displacement. A single whole-field interrogation of the array of fringe systems produces an optical representation of accumulated displacement values thus rendering the statistics of the displacement field. The required matrix of light beams is generated by holographic optical elements.

  15. Gonio photometric imaging for recording of reflectance spectra of 3D objects

    Science.gov (United States)

    Miyake, Yoichi; Tsumura, Norimichi; Haneishi, Hideaki; Hayashi, Junichiro

    2002-06-01

    In recent years, it is required to develop a system for 3D capture of archives in museums and galleries. In visualizing of 3D object, it is important to reproduce both color and glossiness accurately. Our final goal is to construct digital archival systems in museum and Internet or virtual museum via World Wide Web. To archive our goal, we have developed the multi-spectral imaging systems to record and estimate reflectance spectra of the art paints based on principal component analysis and Wiener estimation method. In this paper, Gonio photometric imaging method is introduced for recording of 3D object. Five-band images of the object are taken under seven different illuminants angles. The set of five-band images are then analyzed on the basis of both dichromatic reflection model and Phong model to extract Gonio photometric information of the object. Prediction of reproduced images of the object under several illuminants and illumination angles is demonstrated and images that are synthesized with 3D wire frame image taken by 3D digitizer are also presented.

  16. Velocity anisotropy effect in pump-probe spectra of cesium in a micrometric thickness optical cell

    Science.gov (United States)

    Ghosh, P. N.; Mitra, S.; Ray, B.; Krasteva, A.; Slavov, D.; Todorov, P.; Cartaleva, S.

    2015-01-01

    The pump-probe spectra in a cell of micrometric thickness containing cesium vapor are reported. The line shape and nonlinear features observed in the case of fluorescence in the direction parallel to the cell windows and the transmission spectra observed along the propagation direction of the probe beam show considerable differences in the spectral profiles. We observed Electromagnetically Induced Transparency (EIT) and enhanced Velocity Selective Optical Pumping (VSOP) signals. Atoms moving nearly parallel to the windows and perpendicular to the collinear pump and probe beams will see much lower Doppler shift of incident frequencies and hence will lead to considerable narrowing of the Doppler background in the fluorescence spectra. The coherence decay rate is also low for such atoms as they do not meet with the cell walls. A theoretical model based on five level optical Bloch equations is used to simulate the spectra. The Doppler convolution includes all possible orientation of atomic velocities with respect to the laser beam direction. The simulated curves reproduce the observed sharp EIT peaks and enhanced broad VSOP signals for the closed probe transition in the fluorescence and absorption spectra. The observed effect of the light intensity and temperature change on the non-linear features is reproduced by the simulation.

  17. Effects of chirp of pump pulses on broadband terahertz pulse spectra generated by optical rectification

    Science.gov (United States)

    Hamazaki, Junichi; Furusawa, Kentaro; Sekine, Norihiko; Kasamatsu, Akifumi; Hosako, Iwao

    2016-11-01

    The effects of the chirp of the pump pulse in broadband terahertz (THz) pulse generation by optical rectification (OR) in GaP were systematically investigated. It was found that the pre-compensation for the dispersion of GaP is important for obtaining smooth and single-peaked THz spectra as well as high power-conversion efficiency. It was also found that an excessive amount of chirp leads to distortions in THz spectra, which can be quantitatively analyzed by using a simple model. Our results highlight the importance of accurate control over the chirp of the pump pulse for generating broadband THz pulses by OR.

  18. Comment on "Orientation dependence of the optical spectra in graphene at high frequencies"

    Science.gov (United States)

    Nguyen, Huy-Viet; Nguyen, V. Hung

    2016-09-01

    Zhang et al. [Phys. Rev. B 77, 241402(R) (2008), 10.1103/PhysRevB.77.241402] reported a theoretical study of the optical spectra of monolayer graphene employing the Kubo formula within a tight-binding model. Their calculations predicted that at high frequencies the optical conductivity of graphene becomes strongly anisotropic. In particular, at frequencies comparable to the energy separation of the upper and lower bands at the Γ point, the optical conductivity is strongly suppressed if the field polarization is along the zigzag direction whereas it is significantly high for the armchair one. We find that, unfortunately, this result is just a consequence of the incorrect determination of the current operator in k space. Here, we present a standard scheme to obtain this operator correctly. As a result, we show that the optical conductivity of monolayer graphene is indeed isotropic, which is consistent with the results of other (both theoretical and experimental) studies in the literature.

  19. Optical detection of NMR J-spectra at zero magnetic field.

    Science.gov (United States)

    Ledbetter, M P; Crawford, C W; Pines, A; Wemmer, D E; Knappe, S; Kitching, J; Budker, D

    2009-07-01

    Scalar couplings of the form JI(1) x I(2) between nuclei impart valuable information about molecular structure to nuclear magnetic-resonance spectra. Here we demonstrate direct detection of J-spectra due to both heteronuclear and homonuclear J-coupling in a zero-field environment where the Zeeman interaction is completely absent. We show that characteristic functional groups exhibit distinct spectra with straightforward interpretation for chemical identification. Detection is performed with a microfabricated optical atomic magnetometer, providing high sensitivity to samples of microliter volumes. We obtain 0.1 Hz linewidths and measure scalar-coupling parameters with 4-mHz statistical uncertainty. We anticipate that the technique described here will provide a new modality for high-precision "J spectroscopy" using small samples on microchip devices for multiplexed screening, assaying, and sample identification in chemistry and biomedicine.

  20. Optical detection of NMR J-spectra at zero magnetic field

    CERN Document Server

    Ledbetter, M P; Pines, A; Wemmer, D E; Knappe, S; Kitching, J; Budker, D

    2009-01-01

    Scalar couplings of the form J I_1 \\cdot I_2 between nuclei impart valuable information about molecular structure to nuclear magnetic-resonance spectra. Here we demonstrate direct detection of J-spectra due to both heteronuclear and homonuclear J-coupling in a zero-field environment where the Zeeman interaction is completely absent. We show that characteristic functional groups exhibit distinct spectra with straightforward interpretation for chemical identification. Detection is performed with a microfabricated optical atomic magnetometer, providing high sensitivity to samples of microliter volumes. We obtain 0.1 Hz linewidths and measure scalar-coupling parameters with 4-mHz statistical uncertainty. We anticipate that the technique described here will provide a new modality for high-precision "J spectroscopy" using small samples on microchip devices for multiplexed screening, assaying, and sample identification in chemistry and biomedicine.

  1. Electronic absorption spectra and nonlinear optical properties of CO2 molecular aggregates: A quantum chemical study

    Indian Academy of Sciences (India)

    Tarun K Mandal; Sudipta Dutta; Swapan K Pati

    2009-09-01

    We have investigated the structural aspects of several carbon dioxide molecular aggregates and their spectroscopic and nonlinear optical properties within the quantum chemical theory framework. We find that, although the single carbon dioxide molecule prefers to be in a linear geometry, the puckering of angles occur in oligomers because of the intermolecular interactions. The resulting dipole moments reflect in the electronic excitation spectra of the molecular assemblies. The observation of significant nonlinear optical properties suggests the potential application of the dense carbon dioxide phases in opto-electronic devices.

  2. Detection of Fast Radio Variability of Radio Objects with Continuous Optical Spectra

    Science.gov (United States)

    Pustilnik, S. A.

    The results of the search for rapid variability (T > 1 day) in centimeter range using RATAN-600 in 14 radio objects with contiuous optical spectra are given. In 9 of them, namely 0109+224, 0139-097, 0300+471, 0306+102, 0754+100, 0818-128, 0823-223, 1034-293 and 1538+149 the rapid variability is detected at the wavelengths either 3.9 or 8.2 cm with the confidence probability > 0.98. The conclusion is reached on the close correlation of the presence of the rapid radiovariability and the relative power of non-thermal optical continuum.

  3. Intramolecular charge delocalization and nonlinear optical properties of push-pull chromophore 1-(4-N,N-dimethylaminopyridinium) acetic acid bromide monohydrate from vibrational spectra.

    Science.gov (United States)

    John, C Jesintha; Amalanathan, M; Sajan, D; Lakshmi, K Udaya; Joe, I Hubert

    2011-01-01

    FT-Raman and FT-IR spectra of the nonlinear optical crystal 1-(4-N,N-dimethylaminopyridinium) acetic acid bromide monohydrate have been recorded and analyzed. The equilibrium geometry, vibrational wavenumbers and the first order hyperpolarizability of the crystal have been calculated with the help of density functional theory computations. The assignments of the vibrational spectra have been carried out with the help of Scaled Quantum Mechanic force field theory. Optimized geometry gives the charge transfer interaction of the pyridine ring and the amino group in the electron-donor side of the nonlinear optic chromophore. Electron-phonon coupling and O-H⋯O interactions in making the molecule nonlinear optical active have been analyzed based on the vibrational spectral features. The Natural Bond Orbital analysis confirms the occurrence of strong intermolecular O-H⋯O hydrogen bonding. Copyright © 2010 Elsevier B.V. All rights reserved.

  4. A comparative study of the spectra recorded at RRCAT synchrotron BL-8 dispersive EXAFS beamline with other beamlines

    Indian Academy of Sciences (India)

    Abhijeet Gaur; B D Shrivastava; S N Jha; D Bhattacharyya; A Poswal

    2013-01-01

    The aim of the present work is to make a comparative study of the EXAFS spectra recorded at the BL-8 dispersive EXAFS beamline at 2 GeV Indus-2 synchrotron source at RRCAT, Indore (India) with those recorded at other synchrotron EXAFS beamlines, viz., X-19A at NSLS, BNL (USA), EXAFS wiggler beamline 4-1 at the SSRL (USA) and beamline 11.1 at ELETTRA (Italy). For this purpose, EXAFS spectra at Cu K-edge in copper metal have been recorded at these four beamlines. Further, EXAFS spectra at Cu K-edge in a copper complex have also been recorded at BL-8 beamline and beamline 11.1 at ELETTRA (Italy). The obtained experimental () data have been background-subtracted and then normalized. The normalized data have been then converted to () data, which have been Fourier-transformed and then fitted with the theoretical model, thereby yielding different structural parameters. It has been shown that the results obtained from the EXAFS spectra recorded at the BL-8 beamline are comparable with those obtained from other synchrotron EXAFS beamlines and also with the crystallographic results reported by earlier workers. The reliability, usefulness and data quality of the BL-8 beamline have been discussed.

  5. Optical vibronic spectra of aggregates in Eu sup 2 sup + -doped KCl and KBr crystals

    CERN Document Server

    Pérez, S R; Aceves, R; Rodríguez, R; Barboza, M

    2003-01-01

    The vibronic structure on the optical absorption, emission, and excitation spectra of aggregates in Eu sup 2 sup + -doped KCl and KBr crystals has been obtained. The crystals were annealed at 435 K. During the aggregation process, four groups of narrow bands were found in KCl: Eu sup 2 sup + and two in KBr: Eu sup 2 sup + ,which were considered as the signature of different Eu sup 2 sup + -ion aggregated phases. The vibration frequency for each group is very similar. (Author)

  6. Multiplexed neural recording along a single optical fiber via optical reflectometry

    Science.gov (United States)

    Rodriques, Samuel G.; Marblestone, Adam H.; Scholvin, Jorg; Dapello, Joel; Sarkar, Deblina; Mankin, Max; Gao, Ruixuan; Wood, Lowell; Boyden, Edward S.

    2016-05-01

    We introduce the design and theoretical analysis of a fiber-optic architecture for neural recording without contrast agents, which transduces neural electrical signals into a multiplexed optical readout. Our sensor design is inspired by electro-optic modulators, which modulate the refractive index of a waveguide by applying a voltage across an electro-optic core material. We estimate that this design would allow recording of the activities of individual neurons located at points along a 10-cm length of optical fiber with 40-μm axial resolution and sensitivity down to 100 μV using commercially available optical reflectometers as readout devices. Neural recording sites detect a potential difference against a reference and apply this potential to a capacitor. The waveguide serves as one of the plates of the capacitor, so charge accumulation across the capacitor results in an optical effect. A key concept of the design is that the sensitivity can be improved by increasing the capacitance. To maximize the capacitance, we utilize a microscopic layer of material with high relative permittivity. If suitable materials can be found-possessing high capacitance per unit area as well as favorable properties with respect to toxicity, optical attenuation, ohmic junctions, and surface capacitance-then such sensing fibers could, in principle, be scaled down to few-micron cross-sections for minimally invasive neural interfacing. We study these material requirements and propose potential material choices. Custom-designed multimaterial optical fibers, probed using a reflectometric readout, may, therefore, provide a powerful platform for neural sensing.

  7. Raman Optical Activity Spectra for Large Molecules through Molecules-in-Molecules Fragment-Based Approach.

    Science.gov (United States)

    Jovan Jose, K V; Raghavachari, Krishnan

    2016-02-09

    We present an efficient method for the calculation of the Raman optical activity (ROA) spectra for large molecules through the molecules-in-molecules (MIM) fragment-based method. The relevant higher energy derivatives from smaller fragments are used to build the property tensors of the parent molecule to enable the extension of the MIM method for evaluating ROA spectra (MIM-ROA). Two factors were found to be particularly important in yielding accurate results. First, the link-atom tensor components are projected back onto the corresponding host and supporting atoms through the Jacobian projection method, yielding a mathematically rigorous method. Second, the long-range interactions between fragments are taken into account by using a less computationally expensive lower level of theory. The performance of the MIM-ROA model is calibrated on the enantiomeric pairs of 10 carbohydrate benchmark molecules, with strong intramolecular interactions. The vibrational frequencies and ROA intensities are accurately reproduced relative to the full, unfragmented, results for these systems. In addition, the MIM-ROA method is employed to predict the ROA spectra of d-maltose, α-D-cyclodextrin, and cryptophane-A, yielding spectra in excellent agreement with experiment. The accuracy and performance of the benchmark systems validate the MIM-ROA model for exploring ROA spectra of large molecules.

  8. Optical and UV Spectra of the Remnant of SN 1885 (S And) in M31

    CERN Document Server

    Fesen, Robert A; Hoeflich, Peter A; Hamilton, Andrew J

    2016-01-01

    We present optical and ultraviolet spectra of SN 1885 (S And), visible in absorption against the bulge of the Andromeda galaxy (M31), using the Hubble Space Telescope's STIS spectrograph to probe the three dimensional arrangement of the supernova debris. Spectra covering 2900-5700 A taken using six 0.2"slit positions in two orientations show broad Ca II absorption with blue and red radial velocities out to at least 11,500 km/s, consistent with HST Ca II images of S And. Enhanced Ca II absorption is seen between 2000-5000 km/s suggestive of a Ca II-rich shell. The spectra also show strong, asymmetric Ca I 4227 A absorption extending out to +12,400 km/s, along with weak Fe I 3720 A absorption in a shell with velocities between 2000 and 9000 km/s. Ultraviolet spectra obtained revealed weak broad absorption shortward of 3000 A consistent with model predictions. The STIS spectra, together with previous HST images, show a layered structure with a well defined Ca-rich outer edge indicative of a delayed detonation ph...

  9. Exciton scattering approach for optical spectra calculations in branched conjugated macromolecules

    Science.gov (United States)

    Li, Hao; Wu, Chao; Malinin, Sergey V.; Tretiak, Sergei; Chernyak, Vladimir Y.

    2016-12-01

    The exciton scattering (ES) technique is a multiscale approach based on the concept of a particle in a box and developed for efficient calculations of excited-state electronic structure and optical spectra in low-dimensional conjugated macromolecules. Within the ES method, electronic excitations in molecular structure are attributed to standing waves representing quantum quasi-particles (excitons), which reside on the graph whose edges and nodes stand for the molecular linear segments and vertices, respectively. Exciton propagation on the linear segments is characterized by the exciton dispersion, whereas exciton scattering at the branching centers is determined by the energy-dependent scattering matrices. Using these ES energetic parameters, the excitation energies are then found by solving a set of generalized "particle in a box" problems on the graph that represents the molecule. Similarly, unique energy-dependent ES dipolar parameters permit calculations of the corresponding oscillator strengths, thus, completing optical spectra modeling. Both the energetic and dipolar parameters can be extracted from quantum-chemical computations in small molecular fragments and tabulated in the ES library for further applications. Subsequently, spectroscopic modeling for any macrostructure within a considered molecular family could be performed with negligible numerical effort. We demonstrate the ES method application to molecular families of branched conjugated phenylacetylenes and ladder poly-para-phenylenes, as well as structures with electron donor and acceptor chemical substituents. Time-dependent density functional theory (TD-DFT) is used as a reference model for electronic structure. The ES calculations accurately reproduce the optical spectra compared to the reference quantum chemistry results, and make possible to predict spectra of complex macromolecules, where conventional electronic structure calculations are unfeasible.

  10. Accretion Rates for T Tauri Stars Using Nearly Simultaneous Ultraviolet and Optical Spectra

    CERN Document Server

    Ingleby, Laura; Herczeg, Gregory; Blaty, Alex; Walter, Frederick; Ardila, David; Alexander, Richard; Edwards, Suzan; Espaillat, Catherine; Gregory, Scott G; Hillenbrand, Lynne; Brown, Alexander

    2013-01-01

    We analyze the accretion properties of 21 low mass T Tauri stars using a dataset of contemporaneous near ultraviolet (NUV) through optical observations obtained with the Hubble Space Telescope Imaging Spectrograph (STIS) and the ground based Small and Medium Aperture Research Telescope System (SMARTS), a unique dataset because of the nearly simultaneous broad wavelength coverage. Our dataset includes accreting T Tauri stars (CTTS) in Taurus, Chamaeleon I, $\\eta$ Chamaeleon and the TW Hydra Association. For each source we calculate the accretion rate by fitting the NUV and optical excesses above the photosphere, produced in the accretion shock, introducing multiple accretion components characterized by a range in energy flux (or density) for the first time. This treatment is motivated by models of the magnetospheric geometry and accretion footprints, which predict that high density, low filling factor accretion spots co-exist with low density, high filling factor spots. By fitting the UV and optical spectra wi...

  11. Accretion Rates for T Tauri Stars Using Nearly Simultaneous Ultraviolet and Optical Spectra

    Science.gov (United States)

    Ingleby, Laura; Calvet, Nuria; Herczeg, Gregory; Blaty, Alex; Walter, Frederick; Ardila, David; Alexander, Richard; Edwards, Suzan; Espaillat, Catherine; Gregory, Scott G.; Hillenbrand, Lynne; Brown, Alexander

    2013-04-01

    We analyze the accretion properties of 21 low-mass T Tauri stars using a data set of contemporaneous near-UV (NUV) through optical observations obtained with the Hubble Space Telescope Imaging Spectrograph and the ground-based Small and Medium Aperture Research Telescope System, a unique data set because of the nearly simultaneous broad wavelength coverage. Our data set includes accreting T Tauri stars in Taurus, Chamaeleon I, η Chamaeleon, and the TW Hydra Association. For each source we calculate the accretion rate (\\dot{M}) by fitting the NUV and optical excesses above the photosphere, produced in the accretion shock, introducing multiple accretion components characterized by a range in energy flux (or density) for the first time. This treatment is motivated by models of the magnetospheric geometry and accretion footprints, which predict that high-density, low filling factor accretion spots coexist with low-density, high filling factor spots. By fitting the UV and optical spectra with multiple accretion components, we can explain excesses which have been observed in the near-IR. Comparing our estimates of \\dot{M} to previous estimates, we find some discrepancies; however, they may be accounted for when considering assumptions for the amount of extinction and variability in optical spectra. Therefore, we confirm many previous estimates of the accretion rate. Finally, we measure emission line luminosities from the same spectra used for the \\dot{M} estimates, to produce correlations between accretion indicators (Hβ, Ca II K, C II], and Mg II) and accretion properties obtained simultaneously.

  12. Principal component analysis for the forensic discrimination of black inkjet inks based on the Vis-NIR fibre optics reflection spectra.

    Science.gov (United States)

    Gál, Lukáš; Oravec, Michal; Gemeiner, Pavol; Čeppan, Michal

    2015-12-01

    Nineteen black inkjet inks of six different brands were examined by fibre optics reflection spectroscopy in Visible and Near Infrared Region (Vis-NIR FORS) directly on paper with a view to achieving good resolution between them. These different inks were tested on nineteen different inkjet printers from three brands. Samples were obtained from prints by reflection probe. Processed reflection spectra in the range 500-1000 nm were used as samples in principal component analysis. Variability between spectra of the same ink obtained from different prints, as well as between spectra of square areas and lines was examined. For both spectra obtained from square areas and lines reference, Principal Component Analysis (PCA) models were created. According to these models, the inkjet inks were divided into clusters. PCA method is able to separate inks containing carbon black as main colorant from the other inks using other colorants. Some spectra were recorded from another piece of printer and used as validation samples. Spectra of validation samples were projected onto reference PCA models. According to position of validation samples in score plots it can be concluded that PCA based on Vis-NIR FORS can reliably differentiate inkjet inks which are included in the reference database. The presented method appears to be a suitable tool for forensic examination of questioned documents containing inkjet inks. Inkjet inks spectra were obtained without extraction or cutting sample with possibility to measure out of the laboratory.

  13. Optical and UV Spectra of the Remnant of SN 1885 (S And) in M31

    Science.gov (United States)

    Fesen, Robert; Hoeflich, Peter; Hamilton, Andrew

    2016-06-01

    The remnant of Supernova 1885 (S And), a probable Type Ia supernova, can be seen in absorption against the bulge of the Andromeda galaxy, M31. Here we present Hubble Space Telescope optical and ultraviolet STIS spectra of S And taken in order to investigate the remnant's three dimensional structure. Optical spectra covering 2900 - 5700 ˚A, taken using six 0.2” wide slit positions in two orientations, show broad Ca II H&K absorption extending out to at least 11,500 km s-1 consistent with previous HST narrow passband Ca II images of S And. We find enhancement of Ca II absorption between expansion velocities of 2,000 and 5,000 km s-1 suggestive of a lumpy Ca-rich shell. These spectra, together with previous HST images, indicate a remnant with less than a 10 percent departure from purely spherical expansion, a layered abundance structure indicative of a detonation phase, and a clumpy and plume-like Fe distribution suggestive of Rayleigh-Taylor instabilities although significantly less than expected from hydrodynamic simulations.

  14. Monte Carlo Simulation ofin situ Gamma-Spectra Recorded by NaI (Tl) Detector in the Marine Environment

    Institute of Scientific and Technical Information of China (English)

    WANG Yiming; ZHANG Yingying; WU Ning; WU Bingwei; LIU Yan; CAO Xuan; WANG Qian

    2015-01-01

    To develop a NaI (Tl) detector for in situ radioactivity monitoring in the marine environment and enhance the confidence of the probability of the gamma-spectrum analysis, Monte Carlo simulations using the Monte Carlo N-Particle ( MNCP ) code were performed to provide the response spectra of some interested radionuclides and the background spectra originating from the natural radionuclides in seawater recorded by a NaI (Tl) detector. A newly developed 75mm×75mm NaI (Tl) detector was calibrated using four reference radioactive sources137Cs,60Co,40K and54Mn in the laboratory before the field measurements in seawater. A simulation model was established for the detector immersed in seawater. The simulated spectra were all broadened with Gaussian pulses to reflect the statistical fluctuations and electrical noise in the real measurement. The simulated spectra show that the single-energy photons into the detector are mostly scattering low-energy photons and the high background in the low energy region mainly originates from the Compton effect of the high energyγ-rays of natural radionuclides in seawater. The simulated background spectrum was compared with the experimental one recorded in field measurement and they seem to be in good agreement. The simulation method and spectra can be used for the accurate analysis of the filed measurement results of low concentration radioactivity in seawater.

  15. Optical properties of organic semiconductor thin films. Static spectra and real-time growth studies

    Energy Technology Data Exchange (ETDEWEB)

    Heinemeyer, Ute

    2009-07-20

    The aim of this work was to establish the anisotropic dielectric function of organic thin films on silicon covered with native oxide and to study their optical properties during film growth. While the work focuses mainly on the optical properties of Diindenoperylene (DIP) films, also the optical response of Pentacene (PEN) films during growth is studied for comparison. Spectroscopic ellipsometry and differential reflectance spectroscopy are used to determine the dielectric function of the films ex-situ and in-situ, i.e. in air and in ultrahigh vacuum. Additionally, Raman- and fluorescence spectroscopy is utilized to characterize the DIP films serving also as a basis for spatially resolved optical measurements beyond the diffraction limit. Furthermore, X-ray reflectometry and atomic force microscopy are used to determine important structural and morphological film properties. The absorption spectrum of DIP in solution serves as a monomer reference. The observed vibronic progression of the HOMO-LUMO transition allows the determination of the Huang-Rhys parameter experimentally, which is a measure of the electronic vibrational coupling. The corresponding breathing modes are measured by Raman spectroscopy. The optical properties of DIP films on native oxide show significant differences compared to the monomer spectrum due to intermolecular interactions. First of all, the thin film spectra are highly anisotropic due to the structural order of the films. Furthermore the Frenkel exciton transfer is studied and the energy difference between Frenkel and charge transfer excitons is determined. Real-time measurements reveal optical differences between interfacial or surface molecules and bulk molecules that play an important role for device applications. They are not only performed for DIP films but also for PEN films. While for DIP films on glass the appearance of a new mode is visible, the spectra of PEN show a pronounced energy red-shift during growth. It is shown how the

  16. General Method for Calculating the Response and Noise Spectra of Active Fabry-Perot Semiconductor Waveguides With External Optical Injection

    DEFF Research Database (Denmark)

    Blaaberg, Søren; Mørk, Jesper

    2009-01-01

    of the input field can be calculated. Both responses and noise spectra are given through semianalytical expressions taking into account the longitudinal extent and finite end-facet reflectivities of the active device. Different examples of responses and spectra are presented for semiconductor optical...

  17. Optimization of eigenstates and spectra for quasi-linear nonlinear optical systems

    CERN Document Server

    Lytel, Rick; Kuzyk, Mark G

    2015-01-01

    Quasi-one-dimensional quantum structures with spectra scaling faster than the square of the eigenmode number (superscaling) can generate intrinsic, off-resonant optical nonlinearities near the fundamental physical limits, independent of the details of the potential energy along the structure. The scaling of spectra is determined by the topology of the structure, while the magnitudes of the transition moments are set by the geometry of the structure. This paper presents a comprehensive study of the geometrical optimization of superscaling quasi-one-dimensional structures and provides heuristics for designing molecules to maximize intrinsic response. A main result is that designers of conjugated structures should attach short side groups at least a third of the way along the bridge, not near its end as is conventionally done. A second result is that once a side group is properly placed, additional side groups do not further enhance the response.

  18. All-real spectra in optical systems with arbitrary gain and loss distributions

    CERN Document Server

    Nixon, Sean

    2015-01-01

    A method for constructing optical potentials with an arbitrary distribution of gain and loss and completely real spectrum is presented. For each arbitrary distribution of gain and loss, several classes of refractive-index profiles with freely tunable parameters are obtained such that the resulting complex potentials, although being non-parity-time-symmetric in general, still feature all-real spectra for a wide range of tuning parameters. When these refractive indices are tuned below certain thresholds, phase transition can occur, where complex-conjugate pairs of eigenvalues appear in the spectrum. These non-parity-time-symmetric complex potentials generalize the concept of parity-time-symmetric potentials to allow for more flexible gain and loss distributions while still maintaining all-real spectra and the phenomenon of phase transition.

  19. Optical Stark effect in the four-wave mixing and stimulated Raman spectra of N2

    Science.gov (United States)

    Moosmuller, H.; She, C. Y.; Huo, Winifred M.

    1989-01-01

    The influence of the optical Stark effect on spectral line shapes in four-wave-mixing Raman spectroscopy (FWMRS) and stimulated Raman spectroscopy (SRS) is investigated experimentally and theoretically. Using an experimental setup capable of rapid alternation between the simultaneous measurement of coherent Stokes Raman spectroscopy and inverse Raman spectroscopy at low and high intensities, together with a sophisticated frequency reference scheme, it was possible to perform a rather direct comparison between Stark-broadened and non-Stark-broadened spectra of both classes of Raman spectroscopies. The results demonstrate that SRS spectra show more Stark shift and broadening than their FWMRS counterparts. A discrepancy with theoretical results is pointed out, and an attempt is made to explain it.

  20. Observation of Amorphous Recording Marks Using Reflection-Mode Near-Field Scanning Optical Microscope Supported by Optical Interference Method

    Science.gov (United States)

    Sakai, Masaru; Mononobe, Shuji; Yusu, Keiichiro; Tadokoro, Toshiyasu; Saiki, Toshiharu

    2005-09-01

    A signal enhancing technique for a reflection-mode near-field scanning optical microscope (NSOM) is proposed. Optical interference between the signal light, from an aperture at the tip of a tapered optical fiber, and the reflected light, from a metallic coating around the aperture, enhances the signal intensity. We used a rewritable high-definition digital versatile disc (HD DVD) with dual recording layers as a sample medium, and demonstrated observation of amorphous recording marks on the semitransparent (the first) recording layer. In spite of low optical contrast between the crystal region and the amorphous region on this layer, we successfully observed recording marks with good contrast.

  1. Holographic optical elements recorded in silver halide sensitized gelatin emulsions. Part I. Transmission holographic optical elements.

    Science.gov (United States)

    Kim, J M; Choi, B S; Kim, S I; Kim, J M; Bjelkhagen, H I; Phillips, N J

    2001-02-10

    Silver halide sensitized gelatin (SHSG) holograms are similar to holograms recorded in dichromated gelatin (DCG), the main recording material for holographic optical elements (HOE's). The drawback of DCG is its low sensitivity and limited spectral response. Silver halide materials can be processed in such a way that the final hologram will have properties like a DCG hologram. Recently this technique has become more interesting since the introduction of new ultra-high-resolution silver halide emulsions. An optimized processing technique for transmission HOE's recorded in these materials is introduced. Diffraction efficiencies over 90% can be obtained for transmissive diffraction gratings. Understanding the importance of the selective hardening process has made it possible to obtain results similar to conventional DCG processing. The main advantage of the SHSG process is that high-sensitivity recording can be performed with laser wavelengths anywhere within the visible spectrum. This simplifies the manufacturing of high-quality, large-format HOE's.

  2. Optical spectra and spin-Hamiltonian parameters of trivalent ytterbium in lead tungstate

    Indian Academy of Sciences (India)

    W-L Feng; X-M Li

    2011-01-01

    By using crystal-field theory, the optical spectra and spin-Hamiltonian parameters (abbr. SH parameters, i.e. the anisotropic factors $g_{\\|} g_{⊥}$, and hyperfine structure constants $A_{\\|}, A_{⊥}$) of 171Yb3+ and 173Yb3+ isotopes in the tetragonal PbWO4 are calculated. The theoretical results agree well with the experimental values. The crystal-field parameters and the signs of the hyperfine structure constants for both 171Yb3+ and 173Yb3+ isotopes are determined. The validities of the theoretical results are discussed.

  3. A Bloch equation approach to intensity dependent optical spectra of light harvesting complex II: excitation dependence of light harvesting complex II pump-probe spectra.

    Science.gov (United States)

    Richter, Marten; Renger, Thomas; Knorr, Andreas

    2008-01-01

    On the basis of the recent progress in the resolution of the structure of the antenna light harvesting complex II (LHC II) of the photosystem II, we propose a microscopically motivated theory to predict excitation intensity-dependent spectra. We show that optical Bloch equations provide the means to include all 2( N ) excited states of an oligomer complex of N coupled two-level systems and analyze the effects of Pauli Blocking and exciton-exciton annihilation on pump-probe spectra. We use LHC Bloch equations for 14 Coulomb coupled two-level systems, which describe the S (0) and S (1) level of every chlorophyll molecule. All parameter introduced into the Hamiltonian are based on microscopic structure and a quantum chemical model. The derived Bloch equations describe not only linear absorption but also the intensity dependence of optical spectra in a regime where the interplay of Pauli Blocking effects as well as exciton-exciton annihilation effects are important. As an example, pump-probe spectra are discussed. The observed saturation of the spectra for high intensities can be viewed as a relaxation channel blockade on short time scales due to Pauli blocking. The theoretical investigation is useful for the interpretation of the experimental data, if the experimental conditions exceed the low intensity pump limit and effects like strong Pauli Blocking and exciton-exciton annihilation need to be considered. These effects become important when multiple excitations are generated by the pump pulse in the complex.

  4. Decision-Directed Correction for Bloom in Optical Recording Channels

    Science.gov (United States)

    Gopalaswamy, Srinivasan; Kee, Ng See; Farhang-Boroujeny, B.

    2000-02-01

    A threshold adaptation scheme is proposed in a non-Viterbi simple detector for d=2 minimum run-length-constraint coded optical recording schemes, to increase robustness to bloom. The detector has a simple structure comprising of a threshold detector, post processing error correction, and decision directed threshold adaptation. The equalization target is a free symmetric 7-tap target and the detection exploits the d=2 constraint in the input sequence. The detector is evaluated for digital versatile disk (DVD) specifications and compared with other threshold-based detectors as well as Viterbi detectors following targets of length up to 5. Performance improvement of over 1.5 dB is observed with the proposed feature for bloom larger than 15% of the channel bit period.

  5. Optical function spectra and bandgap energy of Cu{sub 2}SnSe{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Choi, S. G., E-mail: sukgeun.choi@nrel.gov; Kang, J.; Beall, C.; Wei, S.-H.; Christensen, S. T.; Repins, I. L. [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States); Li, J.; Haneef, H.; Podraza, N. J. [Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, Ohio 43606 (United States)

    2015-01-26

    We present the optical function spectra of Cu{sub 2}SnSe{sub 3} determined from 0.30 to 6.45 eV by spectroscopic ellipsometry (SE) at room temperature. We analyze the SE data using the Tauc-Lorentz model and obtain the direct-bandgap energy of 0.49 ± 0.02 eV, which is much smaller than the previously known value of 0.84 eV for the monoclinic-phase Cu{sub 2}SnSe{sub 3}. We also perform density-functional theory calculations to obtain the complex dielectric function data, and the results show good agreement with the experimental spectrum. Finally, we discuss the electronic origin of the main optical structures.

  6. Geometrical structure, multifractal spectra and localized optical modes of aperiodic Vogel spirals.

    Science.gov (United States)

    Trevino, Jacob; Liew, Seng Fatt; Noh, Heeso; Cao, Hui; Dal Negro, Luca

    2012-01-30

    We present a numerical study of the structural properties, photonic density of states and bandedge modes of Vogel spiral arrays of dielectric cylinders in air. Specifically, we systematically investigate different types of Vogel spirals obtained by the modulation of the divergence angle parameter above and below the golden angle value (≈137.507°). We found that these arrays exhibit large fluctuations in the distribution of neighboring particles characterized by multifractal singularity spectra and pair correlation functions that can be tuned between amorphous and random structures. We also show that the rich structural complexity of Vogel spirals results in a multifractal photonic mode density and isotropic bandedge modes with distinctive spatial localization character. Vogel spiral structures offer the opportunity to create novel photonic devices that leverage radially localized and isotropic bandedge modes to enhance light-matter coupling, such as optical sensors, light sources, concentrators, and broadband optical couplers.

  7. Optical Absorption Spectra and Intraband Dynamics in Terahertz-Driven Semiconductor Superlattice

    Institute of Scientific and Technical Information of China (English)

    MI Xian-Wu

    2004-01-01

    @@ We have theoretically investigated the optical absorption spectrum and intraband dynamics by subjecting a superlattice to both a terahertz (THz)-frequency driving field and an optical pulse by using an excitonic basis.In the presence of a THz dc field, the satellite structures in the absorption spectra are presented. The satellite structure is a result from the THz nonlinear dynamics of Wannier-Stark ladder excitons. On the other hand, the coherent intraband polarization is investigated. We find that the excitonic Bloch oscillation is driven by the THz field and yields an intraband polarization that continues to oscillate at times much longer than the intraband dephasing time. The temporal evolution of the slowly varying components of the intraband polarization is dependent on the THz frequency.

  8. Localization and fractal spectra of optical phonon modes in quasiperiodic structures

    Science.gov (United States)

    Anselmo, D. H. A. L.; Dantas, A. L.; Medeiros, S. K.; Albuquerque, E. L.; Freire, V. N.

    2005-04-01

    The dispersion relation and localization profile of confined optical phonon modes in quasiperiodic structures, made up of nitride semiconductor materials, are analyzed through a transfer-matrix approach. The quasiperiodic structures are characterized by the nature of their Fourier spectrum, which can be dense pure point (Fibonacci sequences) or singular continuous (Thue-Morse and Double-period sequences). These substitutional sequences are described in terms of a series of generations that obey peculiar recursion relations and/or inflation rules. We present a quantitative analysis of the localization and magnitude of the allowed band widths in the optical phonons spectra of these quasiperiodic structures, as well as how they scale as a function of the number of generations of the sequences.

  9. Infrared Spectra and Optical Constants of Astronomical Ices: II. Ethane and Ethylene

    CERN Document Server

    Hudson, R L; Moore, M H

    2015-01-01

    Infrared spectroscopic observations have established the presence of hydrocarbon ices on Pluto and other TNOs, but the abundances of such molecules cannot be deduced without accurate optical constants (n, k) and reference spectra. In this paper we present our recent measurements of near- and mid-infrared optical constants for ethane (C$_2$H$_6$) and ethylene (C$_2$H$_4$) in multiple ice phases and at multiple temperatures. As in our recent work on acetylene (C$_2$H$_2$), we also report new measurements of the index of refraction of each ice at 670 nm. Comparisons are made to earlier work where possible, and electronic versions of our new results are made available.

  10. Infrared Spectra and Optical Constants of Astronomical Ices: II. Ethane and Ethylene

    Science.gov (United States)

    Hudson, Reggie L.; Gerakines, Perry A.; Moore, M. H.

    2014-01-01

    Infrared spectroscopic observations have established the presence of hydrocarbon ices on Pluto and other TNOs, but the abundances of such molecules cannot be deduced without accurate optical constants (n, k) and reference spectra. In this paper we present our recent measurements of near- and mid-infrared optical constants for ethane (C2H6) and ethylene (C2H4) in multiple ice phases and at multiple temperatures. As in our recent work on acetylene (C2H2), we also report new measurements of the index of refraction of each ice at 670 nm. Comparisons are made to earlier work where possible, and electronic versions of our new results are made available.

  11. Large-scale segmentation errors in optical gratings and their unique effect onto optical scattering spectra

    Science.gov (United States)

    Heusinger, Martin; Flügel-Paul, Thomas; Zeitner, Uwe-Detlef

    2016-08-01

    In this paper, we analyze the influence of large-scale segmentation errors in the morphology of high-performance optical gratings. It is thus assumed that the optical grating under consideration (typical lateral extends S are 10-1000 mm) can be spatially decomposed into a great many but unique sub-segments (≪ S; typical extends are 10-100 μm). Any violation of the perfect periodicity will result in the generation of stray light, especially Rowland ghosts, which radiate into a small angular region around the grating's diffraction orders. In this paper, we focus on three different kinds of segmentation errors. On the one hand, there are statistic as well as deterministic alignment errors between otherwise perfect sub-segments. On the other hand, we analyze the effect of chirping of geometrical parameters, i.e., the groove width, within every sub-segment. Most importantly, we find that the particular type of imperfection results in a unique characteristic of the according stray light spectrum which thus acts as a fingerprint. We come to this conclusion on three different ways. First, we rely on a simple theoretical model that is based on scalar diffraction theory. Second, we have performed rigorous numerical simulations for a high aspect ratio purely dielectric spectrometer grating (period = {667} nm). Third, the very same grating was then fabricated by e-beam lithography and its stray light spectrum was measured with a purposely designed optical setup. Eventually, all different routes to analyze the problem turn out to be in very good agreement, and we are confident that stray light measurements can be used as an important tool in the detection of fabrication imperfections.

  12. The Relationship Between Flying Height Variation of the Flying Optical Head and Statistical Recording Density in Near—field Optical Recording

    Institute of Scientific and Technical Information of China (English)

    PEIXiandeng,; ZHANGXiaoga; HUANGHao

    2003-01-01

    This paper models the head-disk cou-pling in waveguide probe near-field recording, and derives the relationship curve between full width at half maxi-mum (FWHM) of static light distribution as well as static recording density and near-field coupling distance by com-puter simulation. Then after defining the FWHM of sta-tistical light distribution and statistical recording density,we discuss the relationship between flying height variation of the flying optical head and statistical recording density in near-field optical recording.

  13. Reference-free, high-resolution measurement method of timing jitter spectra of optical frequency combs

    Science.gov (United States)

    Kwon, Dohyeon; Jeon, Chan-Gi; Shin, Junho; Heo, Myoung-Sun; Park, Sang Eon; Song, Youjian; Kim, Jungwon

    2017-01-01

    Timing jitter is one of the most important properties of femtosecond mode-locked lasers and optical frequency combs. Accurate measurement of timing jitter power spectral density (PSD) is a critical prerequisite for optimizing overall noise performance and further advancing comb applications both in the time and frequency domains. Commonly used jitter measurement methods require a reference mode-locked laser with timing jitter similar to or lower than that of the laser-under-test, which is a demanding requirement for many laser laboratories, and/or have limited measurement resolution. Here we show a high-resolution and reference-source-free measurement method of timing jitter spectra of optical frequency combs using an optical fibre delay line and optical carrier interference. The demonstrated method works well for both mode-locked oscillators and supercontinua, with 2 × 10−9 fs2/Hz (equivalent to −174 dBc/Hz at 10-GHz carrier frequency) measurement noise floor. The demonstrated method can serve as a simple and powerful characterization tool for timing jitter PSDs of various comb sources including mode-locked oscillators, supercontinua and recently emerging Kerr-frequency combs; the jitter measurement results enabled by our method will provide new insights for understanding and optimizing timing noise in such comb sources. PMID:28102352

  14. Real-time Fourier transformation of lightwave spectra and application in optical reflectometry.

    Science.gov (United States)

    Malacarne, Antonio; Park, Yongwoo; Li, Ming; LaRochelle, Sophie; Azaña, José

    2015-12-14

    We propose and experimentally demonstrate a fiber-optics scheme for real-time analog Fourier transform (FT) of a lightwave energy spectrum, such that the output signal maps the FT of the spectrum of interest along the time axis. This scheme avoids the need for analog-to-digital conversion and subsequent digital signal post-processing of the photo-detected spectrum, thus being capable of providing the desired FT processing directly in the optical domain at megahertz update rates. The proposed concept is particularly attractive for applications requiring FT analysis of optical spectra, such as in many optical Fourier-domain reflectrometry (OFDR), interferometry, spectroscopy and sensing systems. Examples are reported to illustrate the use of the method for real-time OFDR, where the target axial-line profile is directly observed in a single-shot oscilloscope trace, similarly to a time-of-flight measurement, but with a resolution and depth of range dictated by the underlying interferometry scheme.

  15. iSpectra: An Open Source Toolbox For The Analysis of Spectral Images Recorded on Scanning Electron Microscopes.

    Science.gov (United States)

    Liebske, Christian

    2015-08-01

    iSpectra is an open source and system-independent toolbox for the analysis of spectral images (SIs) recorded on energy-dispersive spectroscopy (EDS) systems attached to scanning electron microscopes (SEMs). The aim of iSpectra is to assign pixels with similar spectral content to phases, accompanied by cumulative phase spectra with superior counting statistics for quantification. Pixel-to-phase assignment starts with a threshold-based pre-sorting of spectra to create groups of pixels with identical elemental budgets, similar to a method described by van Hoek (2014). Subsequent merging of groups and re-assignments of pixels using elemental or principle component histogram plots enables the user to generate chemically and texturally plausible phase maps. A variety of standard image processing algorithms can be applied to groups of pixels to optimize pixel-to-phase assignments, such as morphology operations to account for overlapping excitation volumes over pixels located at phase boundaries. iSpectra supports batch processing and allows pixel-to-phase assignments to be applied to an unlimited amount of SIs, thus enabling phase mapping of large area samples like petrographic thin sections.

  16. Effective method to compute Franck-Condon integrals for optical spectra of large molecules in solution.

    Science.gov (United States)

    Santoro, Fabrizio; Improta, Roberto; Lami, Alessandro; Bloino, Julien; Barone, Vincenzo

    2007-02-28

    The authors present a new method for the computation of vibrationally resolved optical spectra of large molecules, including the Duschinsky [Acta Physicochim. URSS 7, 551 (1937)] rotation of the normal modes. The method automatically selects the relevant vibronic contributions to the spectrum, independent of their frequency, and it is able to provide fully converged spectra with a quite modest computational time, both in vacuo and in condensed phase. Starting from the rigorous time-dependent expression they discuss indeed in which limits the spectrum of a molecule embedded in a solvent, described as a polarizable continuum, can be computed in a time-independent formalism, defining both nonequilibrium and equilibrium limits. In these cases the polarizable continuum model provides a suitable description of the solvent field. By computing the absorption spectra of anthracene in gas phase and of coumarin C153 in gas phase and cyclohexane, and the phosphorescence spectrum of the unsubstituted coumarin in ethanol they show that the method is fast and efficient.

  17. Infrared Spectra and Optical Constants of Nitrile Ices Relevant to Titan's Atmosphere

    Science.gov (United States)

    Anderson, Carrie; Ferrante, Robert F.; Moore, W. James; Hudson, Reggie; Moore, Marla H.

    2011-01-01

    Spectra and optical constants of nitrile ices known or suspected to be in Titan?s atmosphere have been determined from 2.0 to 333.3 microns (approx.5000 to 30/cm). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan?s winter pole. Ices studied were: HCN, hydrogen cyanide; C2N2, cyanogen; CH3CN, acetonitrile; C2H5CN, propionitrile; and HC3N, cyanoacetylene. Optical constants were calculated, using Kramers-Kronig analysis, for each nitrile ice?s spectrum measured at a variety of temperatures, in both the amorphous- and crystalline phases. Spectra were also measured for many of the nitriles after quenching at the annealing temperature and compared with those of annealed ices. For each of these molecules we also measured the real component, n, of the refractive index for amorphous and crystalline phases at 670 nm. Several examples of the information contained in these new data sets and their usefulness in modeling Titan?s observed features will be presented (e.g., the broad emission feature at 160/cm; Anderson and Samuelson, 2011).

  18. Importance of backbone angles versus amino acid configurations in peptide vibrational Raman optical activity spectra

    Science.gov (United States)

    Herrmann, Carmen; Ruud, Kenneth; Reiher, Markus

    2008-01-01

    In this work, we investigate whether the differential scattering of right- and left-circularly polarized light in peptide Raman optical activity spectra are uniquely dominated by the backbone conformation, or whether the configurations of the individual amino acid also play a significant role. This is achieved by calculating Raman optical activity spectra using density functional theory for four structurally related peptides with a common backbone conformation, but with different sequences of amino acid configurations. Furthermore, the ROA signals of the amide normal modes are decomposed into contributions from groups of individual atoms. It is found that the amino acid configuration has a considerable influence on the ROA peaks in the amide I, II, and III regions, although the local decomposition reveals that the side-chain atoms only contribute to those peaks directly in the case of the amide II vibrations. Furthermore, small changes in the amide normal modes may lead to large and irregular modifications in the ROA intensity differences, making it difficult to establish transferable ROA intensity differences even for structurally similar vibrations.

  19. VizieR Online Data Catalog: 4 AGN optical spectra (Simmonds+, 2016)

    Science.gov (United States)

    Simmonds, C.; Bauer, F. E.; Thuan, T. X.; Izotov, Y. I.; Stern, D.; Harrison, F. A.

    2016-11-01

    We targeted with dedicated Chandra observations the four most extreme ELGs reported by Izotov and Thuan (2008ApJ...687..133I) (J1025+1402, J1047+0739, J0045+1339, and J1222+3602). For completeness, we also report the results of archival Chandra observations for three weaker objects (J1536+3122, J0840+4707, and J1404+5423) in the parent Izotov et al. (2007ApJ...671.1297I) sample which also have broad Hα emission lines. New optical spectra for galaxies J0045+1339, J1025+1402, J1047+0739, and J1222+3602 were obtained using the Apache Point Observatory (APO) 3.5m telescope using the Dual Imaging Spectrograph (DIS) in both the blue and red wavelength ranges. The sources were observed on several occasions between 2007-2015. New optical spectra for galaxies J0045+1339 and J1222+3602 were obtained using the MODS instrument on the Large Binocular Telescope (LBT) on UT 2013 October 27 and UT 2015 May 18, respectively. (2 data files).

  20. Interaction between guest AgI and host zeolite FAU studied by optical spectra and EXAFS

    Science.gov (United States)

    Kodaira, T.; Kubota, T.; Okamoto, Y.; Koshizaki, N.

    2005-07-01

    AgI molecules were dilutely adsorbed into nano-cages of Na{}^+, K{}+ and Cs{}+ type FAU zeolites in order to understand the interaction between host zeolite and guest AgI. This interaction was investigated using optical absorption spectroscopy and extended X-ray absorption fine structure (EXAFS). The optical spectra strongly depend on the type of the alkali cations. Compared with the lowest absorption band of AgI molecules in gas phase, the spectra of AgI molecules adsorbed in the zeolite cages shifts to higher energy in the order of Cs{}^+, K{}^+, and Na{}^+. On the contrary, Ag-I bond lengths of adsorbed AgI molecules obtained from EXAFS were independent of the type of the alkali-cations. The bond length was very close to gas phase AgI molecules. Therefore, the interaction between AgI molecules and the zeolite, whose magnitude is Na{}+ > K{}+ > Cs{}^+, is important in the photo-excited electronic state.

  1. Calibration-free absolute quantification of optical absorption coefficients using acoustic spectra in 3D photoacoustic microscopy of biological tissue.

    Science.gov (United States)

    Guo, Zijian; Hu, Song; Wang, Lihong V

    2010-06-15

    Optical absorption is closely associated with many physiological important parameters, such as the concentration and oxygen saturation of hemoglobin, and it can be used to quantify the concentrations of nonfluorescent molecules. We propose a method to use acoustic spectra of photoacoustic signals to quantify the absolute optical absorption. This method is self-calibrating and thus insensitive to variations in the optical fluence. Factors such as system bandwidth and acoustic attenuation can affect the quantification but can be canceled by dividing the acoustic spectra measured at two optical wavelengths. Using optical-resolution photoacoustic microscopy, we quantified the absolute optical absorption of black ink samples with various concentrations. We also quantified both the concentration and oxygen saturation of hemoglobin in a live mouse in absolute units.

  2. Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: organic carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2014-11-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, the organic carbon concentration is measured using thermal methods such as Thermal-Optical Reflectance (TOR) from quartz fiber filters. Here, methods are presented whereby Fourier Transform Infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters are used to accurately predict TOR OC. Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filters. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites sampled during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to artifact-corrected TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date which leads to precise and accurate OC predictions by FT-IR as indicated by high coefficient of determination (R2; 0.96), low bias (0.02 μg m-3, all μg m-3 values based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision and accuracy to collocated TOR measurements. FT-IR spectra are also divided into calibration and test sets by OC mass and by OM / OC which reflects the organic composition of the particulate matter and is obtained from organic functional group composition; this division also leads to precise and accurate OC predictions. Low OC concentrations have higher bias and normalized error due to TOR analytical errors and artifact correction errors, not due to the range of OC mass of the samples in the calibration set. However, samples with low OC mass can be used to predict samples with high OC mass indicating that the

  3. OPTICAL SPECTRA OF CANDIDATE INTERNATIONAL CELESTIAL REFERENCE FRAME (ICRF) FLAT-SPECTRUM RADIO SOURCES

    Energy Technology Data Exchange (ETDEWEB)

    Titov, O.; Stanford, Laura M. [Geoscience Australia, P.O. Box 378, Canberra, ACT 2601 (Australia); Johnston, Helen M.; Hunstead, Richard W. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Pursimo, T. [Nordic Optical Telescope, Nordic Optical Telescope Apartado 474E-38700 Santa Cruz de La Palma, Santa Cruz de Tenerife (Spain); Jauncey, David L. [CSIRO Astronomy and Space Science, ATNF and Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Maslennikov, K. [Central Astronomical Observatory at Pulkovo, Pulkovskoye Shosse, 65/1, 196140, St. Petersburg (Russian Federation); Boldycheva, A., E-mail: oleg.titov@ga.gov.au [Ioffe Physical Technical Institute, 26 Polytekhnicheskaya, St. Petersburg, 194021 (Russian Federation)

    2013-07-01

    Continuing our program of spectroscopic observations of International Celestial Reference Frame (ICRF) sources, we present redshifts for 120 quasars and radio galaxies. Data were obtained with five telescopes: the 3.58 m European Southern Observatory New Technology Telescope, the two 8.2 m Gemini telescopes, the 2.5 m Nordic Optical Telescope (NOT), and the 6.0 m Big Azimuthal Telescope of the Special Astrophysical Observatory in Russia. The targets were selected from the International VLBI Service for Geodesy and Astrometry candidate International Celestial Reference Catalog which forms part of an observational very long baseline interferometry (VLBI) program to strengthen the celestial reference frame. We obtained spectra of the potential optical counterparts of more than 150 compact flat-spectrum radio sources, and measured redshifts of 120 emission-line objects, together with 19 BL Lac objects. These identifications add significantly to the precise radio-optical frame tie to be undertaken by Gaia, due to be launched in 2013, and to the existing data available for analyzing source proper motions over the celestial sphere. We show that the distribution of redshifts for ICRF sources is consistent with the much larger sample drawn from Faint Images of the Radio Sky at Twenty cm (FIRST) and Sloan Digital Sky Survey, implying that the ultra-compact VLBI sources are not distinguished from the overall radio-loud quasar population. In addition, we obtained NOT spectra for five radio sources from the FIRST and NRAO VLA Sky Survey catalogs, selected on the basis of their red colors, which yielded three quasars with z > 4.

  4. Dielectric function spectra and inter-band optical transitions in TlGaS{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Kawabata, Toshiyuki [Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University, Gakuen-cho 1-1, Nakaku, Sakai, Osaka 599-8531 (Japan); Shim, YongGu, E-mail: shim@pe.osakafu-u.ac.jp [Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University, Gakuen-cho 1-1, Nakaku, Sakai, Osaka 599-8531 (Japan); Wakita, Kazuki [Department of Electrical, Electronics and Computer Engineering, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino 275-0016 (Japan); Mamedov, Nazim [Department of Ellipsometry, Institute of Physics, Azerbaijan National Academy of Sciences, H. Javid Ave. 33, Baku AZ-1143 (Azerbaijan)

    2014-11-28

    TlGaS{sub 2} with a quasi-two-dimensional structure has been accessed by spectroscopic ellipsometry over the 1.5–6.0 eV spectral range. A uniaxial approach applicable to monoclinic TlGaS{sub 2} at room temperature has been employed for ellipsometric data treatment. Principal components of the dielectric function tensor have then been retrieved. Inter-band optical transitions associated with the obtained dielectric function have been determined by using standard critical point analysis. The transitions have been assigned within the electronic band structure obtained for TlGaS{sub 2} from calculations based on density functional theory. - Highlights: • We investigate the dielectric function spectra of TlGaS{sub 2}. • Inter-band optical transition energies are extracted by critical point analysis. • The electronic band structure and the dielectric functions of TlGaS{sub 2} are calculated. • The electronic band states related to the optical transitions are assigned.

  5. RECOVERING FOSSIL RECORDS FROM GALAXY SPECTRA USING A 2D DYNAMICAL BASE

    Directory of Open Access Journals (Sweden)

    J. Mateu

    2009-01-01

    chemical composition. Nevertheless, the components of this linear combination, that is the spectra of the stellar population represented as a vector in a N-dimensional space (elements of the basis, are almost parallel in spite of being linearly independent and this, combined with the uncertainties of the observed spectra causes that di erent star formation histories reproduce the same observed spectrum. The amount of information that can be extracted will essentially depend on the signal to noise ratio and wavelength interval of the observed spectrum. Until now the algorithms to recover the star formation history from observed spectra use a static basis with a number of elements between 8 and 125. When increasing the number of basis elements it certainly improves the tting of the observed spectrum but also it increases the degeneration of the solution signi cantly, making very difficult the interpretation of the results. In this work we developed a new algorithm with a dynamical (not static basis of only 2 elements which is used to recover both the coefficients of the linear combination and the age of the basis vectors. We made some simulations designed to test the algorithm obtaining excellent, high quality ttings with easy to interpret results and very well de ned uncertainties.

  6. Optical and Near-infrared Spectra of σ Orionis Isolated Planetary-mass Objects

    Science.gov (United States)

    Zapatero Osorio, M. R.; Béjar, V. J. S.; Peña Ramírez, K.

    2017-06-01

    We have obtained low-resolution optical (0.7-0.98 μm) and near-infrared (1.11-1.34 μm and 0.8-2.5 μm) spectra of 12 isolated planetary-mass candidates (J = 18.2-19.9 mag) of the 3 Myr σ Orionis star cluster with the aim of determining the spectroscopic properties of very young, substellar dwarfs and assembling a complete cluster mass function. We have classified our targets by visual comparison with high- and low-gravity standards and by measuring newly defined spectroscopic indices. We derived L0-L4.5 and M9-L2.5 using high- and low-gravity standards, respectively. Our targets reveal clear signposts of youth, thus corroborating their cluster membership and planetary masses (6-13 M Jup). These observations complete the σ Orionis mass function by spectroscopically confirming the planetary-mass domain to a confidence level of ˜75%. The comparison of our spectra with BT-Settl solar metallicity model atmospheres yields a temperature scale of 2350-1800 K and a low surface gravity of log g ≈ 4.0 [cm s-2], as would be expected for young planetary-mass objects. We discuss the properties of the cluster’s least-massive population as a function of spectral type. We have also obtained the first optical spectrum of S Ori 70, a T dwarf in the direction of σ Orionis. Our data provide reference optical and near-infrared spectra of very young L dwarfs and a mass function that may be used as templates for future studies of low-mass substellar objects and exoplanets. The extrapolation of the σ Orionis mass function to the solar neighborhood may indicate that isolated planetary-mass objects with temperatures of ˜200-300 K and masses in the interval 6-13 M Jup may be as numerous as very low-mass stars.

  7. Spectral scalability and optical spectra of fractal multilayer structures: FDTD analysis

    Science.gov (United States)

    Simsek, Sevket; Palaz, Selami; Mamedov, Amirullah M.; Ozbay, Ekmel

    2017-01-01

    An investigation of the optical properties and band structures for the conventional and Fibonacci photonic crystals (PCs) based on SrTiO3 and Sb2Te3 is made in the present research. Here, we use one-dimensional SrTiO3- and Sb2Te3-based layers. We have theoretically calculated the photonic band structure and transmission spectra of SrTiO3- and Sb2Te3-based PC superlattices. The position of minima in the transmission spectrum correlates with the gaps obtained in the calculation. The intensity of the transmission depths is more intense in the case of higher refractive index contrast between the layers.

  8. Quick analysis of optical spectra to quantify epidermal melanin and papillary dermal blood content of skin.

    Science.gov (United States)

    Jacques, Steven L

    2015-04-01

    This paper presents a practical approach for assessing the melanin and blood content of the skin from total diffuse reflectance spectra, R(λ), where λ is wavelength. A quick spectral analysis using just three wavelengths (585 nm, 700 nm and 800 nm) is presented, based on the 1985 work of Kollias and Baquer who documented epidermal melanin of skin using the slope of optical density (OD) between 620 nm and 720 nm. The paper describes the non-rectilinear character of such a quick analysis, and shows that almost any choice of two wavelengths in the 600-900 range can achieve the characterization of melanin. The extrapolation of the melanin slope to 585 nm serves as a baseline for subtraction from the OD (585 nm) to yield a blood perfusion score. Monte Carlo simulations created spectral data for a skin model with epidermis, papillary dermis and reticular dermis to illustrate the analysis.

  9. Squeezing spectra from s-ordered quasiprobability distributions. Application to dispersive optical bistability

    CERN Document Server

    Garcia-Ferrer, F V; De Valcarcel, G J; Roldan, E; Garcia-Ferrer, Ferran V.; Perez-Arjona, Isabel; Valcarcel, German J. de; Roldan, Eugenio

    2005-01-01

    It is well known that the squeezing spectrum of the field exiting a nonlinear cavity can be directly obtained from the fluctuation spectrum of normally ordered products of creation and annihilation operators of the cavity mode. In this article we show that the output field squeezing spectrum can be derived also by combining the fluctuation spectra of any pair of s-ordered products of creation and annihilation operators. The interesting result is that the spectrum obtained in this way from the linearized Langevin equations is exact, and this occurs in spite of the fact that no s-ordered quasiprobability distribution verifies a true Fokker-Planck equation, i.e., the Langevin equations used for deriving the squeezing spectrum are not exact. The (linearized) intracavity squeezing obtained from any s-ordered distribution is also exact. These results are exemplified in the problem of dispersive optical bistability.

  10. Infrared Spectra and Optical Constants of Astronomical Ices: I. Amorphous and Crystalline Acetylene

    Science.gov (United States)

    Hudson, R. L.; Ferrante, R. F.; Moore, M. H.

    2013-01-01

    Here we report recent measurements on acetylene (C2H2) ices at temperatures applicable to the outer Solar System and the interstellar medium. New near- and mid-infrared data, including optical constants (n, k), absorption coefficients (alpha), and absolute band strengths (A), are presented for both amorphous and crystalline phases of C2H2 that exist below 70 K. Comparisons are made to earlier work. Electronic versions of the data are made available, as is a computer routine to use our reported n and k values to simulate the observed IR spectra. Suggestions are given for the use of the data and a comparison to a spectrum of Makemake is made.

  11. 2 μm mid-infrared optical spectra of Tm~(3+)-doped germanium gallate glasses

    Institute of Scientific and Technical Information of China (English)

    XIA Haiping; LIN Qiongfei; ZHANG Jianli; ZHANG Qinyuan

    2009-01-01

    Glasses with the composition of 65GeO_2-12Ga_2O_3-10BaO-8Li_2O-5La_2O_3(molar ratio) doped with 1.526 wt.%, 3.006 wt.%, 5.836 wt.%, 11.028 wt.%, and 15.678 wt.% Tm2O3, respectively, were fabricated by conventional melting method. According to the absorption spectra and the Judd-Ofelt theory, the J-O strength parameters (Ω_2,Ω_4,Ω_6) were calculated, with which the radiative transition probabilities,branching ratios and radiative lifetimes were obtained. The infrared emission spectra (with 808 nm LD excitation) at~1.47 and~1.8 μm of various concentrations of Tm3+-doped glasses were studied. The emission intensity at~1.8 μm reached to the maximum when the Tm2O3-doping concentration was near to be~3.006 wt.% (1.0 mol.%), and then decreased as doping concentration increased further. The mechanism of the fluorescence intensity change was explained with the cross-relaxation effect and the concentration quenching effect of Tm~(3+). Meanwhile, according to McCumber theory, the absorption and emission cross-sections corresponding to the ~3F_4→~3H_6 transitions of Tm~(3+) at 1.8 μm was obtained. For Tm3+-doped germanate glasses, the maximum emission cross-section reached a value higher than that re-ported for fluorozircoaluminate glasses. It is expected to be a favorable candidate host for~2.0 μm mid-inflated laser because the glass shows favorable optical spectra.

  12. 2 μm mid-infrared optical spectra of Tm3+-doped germanium gallate glasses

    Institute of Scientific and Technical Information of China (English)

    XIA; Haiping

    2009-01-01

    Glasses with the composition of 65GeO212Ga2O3-10BaO-8Li2O-5La2O3(molar ratio) doped with 1.526 wt.%, 3.006 wt.%, 5.836 wt.%, 11.028 wt.%, and 15.678 wt.% Tm2O3, respectively, were fabricated by conventional melting method. According to the absorption spectra and the Judd-Ofelt theory, the J-O strength parameters (Ω2,Ω4, Ω6) were calculated, with which the radiative transition probabilities,branching ratios and radiative lifetimes were obtained. The infrared emission spectra (with 808 nm LD excitation) at~1.47 and~1.8 μm of various concentrations of Tm3+-doped glasses were studied. The emission intensity at~1.8 μm reached to the maximum when the Tm2O3-doping concentration was near to be~3.006 wt.% (1.0 mol.%), and then decreased as doping concentration increased further. The mechanism of the fluorescence intensity change was explained with the cross-relaxation effect and the concentration quenching effect of Tm3+. Meanwhile, according to McCumber theory, the absorption and emission cross-sections corresponding to the 3F4→3H6 transitions of Tm3+ at 1.8 μm was obtained. For Tm3+-doped germanate glasses, the maximum emission cross-section reached a value higher than that re-ported for fluorozircoaluminate glasses. It is expected to be a favorable candidate host for~2.0 μm mid-inflated laser because the glass shows favorable optical spectra.

  13. Optical spectra of radio planetary nebulae in the large Magellanic Cloud

    Directory of Open Access Journals (Sweden)

    Payne J.L.

    2008-01-01

    Full Text Available We present 11 spectra from 12 candidate radio sources co-identified with known planetary nebulae (PNe in the Large Magellanic Cloud (LMC. Originally found in Australia Telescope Compact Array (ATCA LMC surveys at 1.4, 4.8 and 8.64 GHz and confirmed by new high resolution ATCA images at 6 and 3 cm (4' /2' , these complement data recently presented for candidate radio PNe in the Small Magellanic Cloud (SMC. Their spectra were obtained using the Radcliff 1.9-meter telescope in Sutherland (South Africa. All of the optical PNe and radio candidates are within 2' and may represent a population of selected radio bright sample only. Nebular ionized masses of these objects are estimated to be as high as 1.8 Mfi, supporting the idea that massive PNe progenitor central stars lose much of their mass in the asymptotic giant branch (AGB phase or prior. We also identify a sub-population (33% of radio PNe candidates with prominent ionized iron emission lines.

  14. Optical Spectra of Radio Planetary Nebulae in the Large Magellanic Cloud

    Directory of Open Access Journals (Sweden)

    Payne, J. L.

    2008-12-01

    Full Text Available We present 11 spectra from 12 candidate radio sources co-identified with known planetary nebulae (PNe in the Large Magellanic Cloud (LMC. Originally found in Australia Telescope Compact Array (ATCA LMC surveys at 1.4, 4.8 and 8.64~GHz and confirmed by new high resolution ATCA images at 6 and 3~cm (4arcsec/2arcsec, these complement data recently presented for candidate radio PNe in the Small Magellanic Cloud (SMC. Their spectra were obtained using the Radcliffe 1.9-meter telescope in Sutherland (South Africa. All of the optical PNe and radio candidates are within 2arcsec and may represent a population of selected radio bright sample only. Nebular ionized masses of these objects are estimated to be as high as 1.8~$M_odot$, supporting the idea that massive PNe progenitor central stars lose much of their mass in the asymptotic giant branch (AGB phase or prior. We also identify a sub-population (33\\% of radio PNe candidates with prominent ionized iron emission lines.

  15. Holographic optical elements recorded in silver halide sensitized gelatin emulsions. Part 2. Reflection holographic optical elements.

    Science.gov (United States)

    Kim, Jong Man; Choi, Byung So; Choi, Yoon Sun; Kim, Jong Min; Bjelkhagen, Hans I; Phillips, Nicholas J

    2002-03-10

    Silver halide sensitized gelatin (SHSG) holograms are similar to holograms recorded in dichromated gelatin (DCG), the main recording material for holographic optical elements (HOEs). The drawback of DCG is its low energetic sensitivity and limited spectral response. Silver halide materials can be processed in such away that the final hologram will have properties like a DCG hologram. Recently this technique has become more interesting since the introduction of new ultra-fine-grain silver halide (AgHal) emulsions. In particular, high spatial-frequency fringes associated with HOEs of the reflection type are difficult to construct when SHSG processing methods are employed. Therefore an optimized processing technique for reflection HOEs recorded in the new AgHal materials is introduced. Diffraction efficiencies over 90% can be obtained repeatably for reflection diffraction gratings. Understanding the importance of a selective hardening process has made it possible to obtain results similar to conventional DCG processing. The main advantage of the SHSG process is that high-sensitivity recording can be performed with laser wavelengths anywhere within the visible spectrum. This simplifies the manufacturing of high-quality, large-format HOEs, also including high-quality display holograms of the reflection type in both monochrome and full color.

  16. The manifestation of optical centers in UV-Vis absorption and luminescence spectra of white blood human cells

    Science.gov (United States)

    Terent'yeva, Yu G.; Yashchuk, V. M.; Zaika, L. A.; Snitserova, O. M.; Losytsky, M. Yu

    2016-12-01

    A white blood human cells spectral investigation is presented. The aim of this series of experiments was to obtain and analyze the absorption and luminescence (fluorescence and phosphorescence) spectra at room temperature and at 78 K of newly isolated white blood human cells and their organelles. As a result the optical centers and possible biochemical components that form the studied spectra where identified. Also the differences between the spectra of abnormal cells (B-cell chronic lymphocytic leukemia BCLL) and normal ones were studied for the whole cells and individual organelles.

  17. IR Spectra of Nano- and Macro-Crystals: the Overriding Importance of Optical Path

    Science.gov (United States)

    Hofmeister, A. M.; Rosen, L. J.; Speck, A. K.

    2000-03-01

    To clarify the effect of optical path, infrared (IR) absorption spectra were collected from nanocrystals of SiC and structurally related AlN and TiB2, and from commercial bulk samples using thin film, powder dispersion and single crystal methods. Crystals of 5-10 nm that were individually encapsulated in salt and subsequently pressed into thin films give identical features to those from thin films of the bulk sample (grain size >1 μm), which removes all possibility of a matrix effect, and negates the importance of grain size below a micron. Shifts in peak position for SiC samples are shown to relate to optical path, and are such that the β- and α- polymorphs can be distinguished. The shifts arise because peaks have finite widths and hence small frequency increments can have widely different absorption coefficient for the intense Si-C stretch. The high absorption coefficient serves as a filter for particulate dimensions perpendicular to the propagation of light.

  18. Optical phonon spectra of CdS crosslinked sulfonate polystyrene nanocomposites

    Science.gov (United States)

    Govani, Jayesh; Manciu, Felicia; Ortiz-Ón, S., , Col; Espe, Matthew; Ziolo, Ronald

    2007-03-01

    We have used IR transmission and FT-Raman spectroscopy to study optically active phonon modes of CdS nanoparticles synthesized in sulfonated polystyrene resin and obtained information about the morphology, crystallinity, and surface interactions. The dominant feature in the far-infrared region of CdS/polystyrene nanocomposites spectra is a sharp peak centered at 255 cm-1, which could be assigned to the transversal optical mode at the L edge of the Brillouin zone of CdS nanoparticles. Also, this vibrational line, based on theoretical core-shell model calculation, could be attributed to the presence of a very thin CdS shell layer. HRTEM images of the CdS nanocomposites show CdS nanoparticles of about 2.5 nm aligned in rows or strings on the polymer surface. Amorphous CdS is also present and may be seen surrounding the nanocrystalline regions. Complementary solid state ^113Cd NMR analysis will be presented as well.

  19. Detection of rapid radivariability of Radio Objects with Continuous Optical Spectra

    Science.gov (United States)

    Pustilnik, S. A.

    The results of the search for rapid variability (characteristic time of > 1 day) in centimeter range using RATAN-600 in 14 radio objects with continuous optical spectra are given. In 9 of them, namely 0109+224, 0139-097, 0300+471, 0306+102, 0754+100, 0818-128, 0823-223, 1034-293 and 1538+149, the rapid variability is detected at wavelengths either 3.9 or 8.2 cm with the confidence probability alpha > 0.98. The conclusion is reached on the close correlation of the presence of rapid radiovariability and the relative power of the non-thermal optical continuum. It is noted the the search for interstellar scintillations in centimeter range in the studied objects during the periods of their rapid variability could test the hypothesis about belonging these objects to the extragalactic class of BL Lac type objects. The proposals are expressed on the necessety of more carefull and complex investigation of the phenomenon of rapid variability.

  20. Visual Evoked Potential Recording in a Rat Model of Experimental Optic Nerve Demyelination.

    Science.gov (United States)

    You, Yuyi; Gupta, Vivek K; Chitranshi, Nitin; Reedman, Brittany; Klistorner, Alexander; Graham, Stuart L

    2015-07-29

    The visual evoked potential (VEP) recording is widely used in clinical practice to assess the severity of optic neuritis in its acute phase, and to monitor the disease course in the follow-up period. Changes in the VEP parameters closely correlate with pathological damage in the optic nerve. This protocol provides a detailed description about the rodent model of optic nerve microinjection, in which a partial demyelination lesion is produced in the optic nerve. VEP recording techniques are also discussed. Using skull implanted electrodes, we are able to acquire reproducible intra-session and between-session VEP traces. VEPs can be recorded on individual animals over a period of time to assess the functional changes in the optic nerve longitudinally. The optic nerve demyelination model, in conjunction with the VEP recording protocol, provides a tool to investigate the disease processes associated with demyelination and remyelination, and can potentially be employed to evaluate the effects of new remyelinating drugs or neuroprotective therapies.

  1. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: organic carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-03-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, organic carbon is measured from a quartz fiber filter that has been exposed to a volume of ambient air and analyzed using thermal methods such as thermal-optical reflectance (TOR). Here, methods are presented that show the feasibility of using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters to accurately predict TOR OC. This work marks an initial step in proposing a method that can reduce the operating costs of large air quality monitoring networks with an inexpensive, non-destructive analysis technique using routinely collected PTFE filter samples which, in addition to OC concentrations, can concurrently provide information regarding the composition of organic aerosol. This feasibility study suggests that the minimum detection limit and errors (or uncertainty) of FT-IR predictions are on par with TOR OC such that evaluation of long-term trends and epidemiological studies would not be significantly impacted. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least-squares regression is used to calibrate sample FT-IR absorbance spectra to TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date. The calibration produces precise and accurate TOR OC predictions of the test set samples by FT-IR as indicated by high coefficient of variation (R2; 0.96), low bias (0.02 μg m-3, the nominal IMPROVE sample volume is 32.8 m3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision to collocated TOR measurements. FT-IR spectra are also

  2. Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: elemental carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-06-01

    Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as Thermal-Optical Reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier Transform Infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure tested and developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FTIR spectra are divided into calibration and test sets. Two calibrations are developed, one which is developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a~uniform distribution of low EC mass samples (EC TOR EC samples in the same mass range and an estimate of the minimum detection limit (MDL) that is on par with TOR EC MDL. For all samples, this hybrid approach leads to precise and accurate TOR EC predictions by FT-IR as indicated by high coefficient of variation (R2; 0.96), no bias (0.00 μg m-3, concentration value based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.03 μg m-3) and reasonable normalized error (21 %). These performance metrics can be achieved with various degrees of spectral pretreatment

  3. Calculation of optical and K pre-edge absorption spectra for ferrous iron of distorted sites in oxide crystals

    Science.gov (United States)

    Vercamer, Vincent; Hunault, Myrtille O. J. Y.; Lelong, Gérald; Haverkort, Maurits W.; Calas, Georges; Arai, Yusuke; Hijiya, Hiroyuki; Paulatto, Lorenzo; Brouder, Christian; Arrio, Marie-Anne; Juhin, Amélie

    2016-12-01

    Advanced semiempirical calculations have been performed to compute simultaneously optical absorption and K pre-edge x-ray absorption spectra of Fe2 + in four distinct site symmetries found in minerals. The four symmetries, i.e., a distorted octahedron, a distorted tetrahedron, a square planar site, and a trigonal bipyramidal site, are representative of the Fe2 + sites found in crystals and glasses. A particular attention has been paid to the definition of the p -d hybridization Hamiltonian which occurs for noncentrosymmetric symmetries in order to account for electric dipole transitions. For the different sites under study, an excellent agreement between calculations and experiments was found for both optical and x-ray absorption spectra, in particular in terms of relative intensities and energy positions of electronic transitions. To our knowledge, these are the first calculations of optical absorption spectra on Fe2 + placed in such diverse site symmetries, including centrosymmetric sites. The proposed theoretical model should help to interpret the features of both the optical absorption and the K pre-edge absorption spectra of 3 d transition metal ions and to go beyond the usual fingerprint interpretation.

  4. Vibronic effects and destruction of exciton coherence in optical spectra of J-aggregates: A variational polaron transformation approach

    Science.gov (United States)

    Bloemsma, E. A.; Silvis, M. H.; Stradomska, A.; Knoester, J.

    2016-12-01

    Using a symmetry adapted polaron transformation of the Holstein Hamiltonian, we study the interplay of electronic excitation-vibration couplings, resonance excitation transfer interactions, and temperature in the linear absorption spectra of molecular J-aggregates. Semi-analytical expressions for the spectra are derived and compared with results obtained from direct numerical diagonalization of the Hamiltonian in the two-particle basis set representation. At zero temperature, we show that our polaron transformation reproduces both the collective (exciton) and single-molecule (vibrational) optical response associated with the appropriate standard perturbation limits. Specifically, for the molecular dimer excellent agreement with the spectra from the two-particle approach for the entire range of model parameters is obtained. This is in marked contrast to commonly used polaron transformations. Upon increasing the temperature, the spectra show a transition from the collective to the individual molecular features, which results from the thermal destruction of the exciton coherence.

  5. Application of normalized biomass size spectra to laser optical plankton counter net intercomparisons of zooplankton distributions

    Science.gov (United States)

    Herman, A. W.; Harvey, M.

    2006-05-01

    The optical plankton counter (OPC) and recently the laser OPC (LOPC) have been used primarily in two measurement applications: (1) identification of specific zooplankton species and (2) changes in zooplankton community structure using size-based spectral measurements. The normalized biomass size spectra (NBSS) are one representation of the size-based approach. The present study is based on utilizing the NBSS to describe the conditions or characteristics of the zooplankton community that allow a reasonable intercomparison of net samples and LOPC measurements made simultaneously for data collected during two oceanographic cruises carried out in the Lower Estuary and the Gulf of St. Lawrence in spring 2001 and 2002, respectively. NBSS linear slopes plankton material such as diatom aggregates and gelatinous material (present during or immediately following blooms) that are less present in nets and are not intercomparable with LOPC measurements. Conversely, slopes >-0.7, or more "blue water" conditions, indicate the potential for reasonable intercomparison of the two methods. This observation applies to smaller-sized zooplankton such as copepodites of Calanus spp. with equivalent spherical diameter gelatinous material and reasonable intercomparisons between LOPC and net were obtained for both sampling years. The LOPC signals produced by Calanus spp. (IV-VI) were larger and more easily separated.

  6. Circumstellar C2, CN, and CH+ in the optical spectra of post-AGB stars

    CERN Document Server

    Bakker, E J; Waters, L B F M; Schoenmaker, T; Bakker, Eric J.; Dishoeck, Ewine F. van; Schoenmaker, Ton

    1996-01-01

    We present optical high-resolution spectra of a sample of sixteen post-AGB stars and IRC +10216. Of the post-AGB stars, ten show C2 Phillips and Swan and CN Red System absorption, one CH+ emission, one CH+ absorption, and four without any molecules. We find typically Trot=43-399, 155-202, and 18-50 K, log N = 14.90-15.57, 14.35, and 15.03-16.47 cm-2 for C2, CH+, and CN respectively, and 0.620. The presence of C2 and CN absorption is correlated with cold dust (Tdust300K). All objects with the unidentified 21mum emission feature exhibit C2 and CN absorption, but not all objects with C2 and CN detections exhibit a 21mum feature. The derived expansion velocity, ranging from 5 to 44 km/s, is the same as that derived from CO millimeter line emission. This unambiguously proves that these lines are of circumstellar origin and are formed in the AGB ejecta (circumstellar shell expelled during the preceding AGB phase). Furthermore there seems to be a relation between the C2 molecular column density and the expansion vel...

  7. Comparative Analysis of SN 2012dn Optical Spectra: Days -14 to +114

    CERN Document Server

    Parrent, J T; Fesen, R A; Parker, S; Bianco, F B; Dilday, B; Sand, D; Valenti, S; Vinkó, J; Berlind, P; Challis, P; Milisavljevic, D; Sanders, N; Marion, G H; Wheeler, J C; Brown, P; Calkins, M L; Friesen, B; Kirshner, R; Pritchard, T; Quimby, R; Roming, P

    2016-01-01

    SN 2012dn is a super-Chandrasekhar mass candidate in a purportedly normal spiral (SAcd) galaxy, and poses a challenge for theories of type Ia supernova diversity. Here we utilize the fast and highly parameterized spectrum synthesis tool, SYNAPPS, to estimate relative expansion velocities of species inferred from optical spectra obtained with six facilities. As with previous studies of normal SN Ia, we find that both unburned carbon and intermediate mass elements are spatially coincident within the ejecta near and below 14,000 km/s. Although the upper limit on SN 2012dn's peak luminosity is comparable to some of the most luminous normal SN Ia, we find a progenitor mass exceeding ~1.6 Msun is not strongly favored by leading merger models since these models do not accurately predict spectroscopic observations of SN 2012dn and more normal events. In addition, a comparison of light curves and host-galaxy masses for a sample of literature and Palomar Transient Factory SN Ia reveals a diverse distribution of SN Ia s...

  8. Extremely Red Quasars from SDSS, BOSS and WISE: Classification of Optical Spectra

    CERN Document Server

    Ross, Nicholas P; Zakamska, Nadia L; Richards, Gordon T; Villforth, Carolin; Strauss, Michael A; Greene, Jenny E; Alexandroff, Rachael; Brandt, W Niel; Liu, Guilin; Myers, Adam D; Paris, Isabelle; Schneider, Donald P

    2014-01-01

    Quasars with extremely red colours are an interesting population that can test ideas about quasar evolution as well as orientation and geometric effects in the so-called AGN unified model. To identify such a population we search the quasar catalogs of the Sloan Digital Sky Survey (SDSS), the Baryon Oscillation Spectroscopic Survey (BOSS) and the Wide-Field Infrared Survey Explorer (WISE) for quasars with extremely high infrared-to-optical ratios. We identify 65 objects with r(AB)-W4(Vega)>14 mag (i.e., F_nu(22um)/F_nu(r) > ~1000). This sample spans a redshift range of 0.282.6 objects that are detected in the W4-band but not W1 or W2 (i.e., "W1W2-dropouts"). The SDSS/BOSS spectra show that the majority of the objects are reddened Type 1 quasars, Type 2 quasars (both at low and high redshift) or objects with deep low-ionization broad absorption lines (BALs) that suppress the observed r-band flux. In addition, we identify a class of Type 1 permitted broad-emission line objects at z~2-3 which are characterized by...

  9. Development of goniophotometric imaging system for recording reflectance spectra of 3D objects

    Science.gov (United States)

    Tonsho, Kazutaka; Akao, Y.; Tsumura, Norimichi; Miyake, Yoichi

    2001-12-01

    In recent years, it is required to develop a system for 3D capture of archives in museums and galleries. In visualizing of 3D object, it is important to reproduce both color and glossiness accurately. Our final goal is to construct digital archival systems in museum and internet or virtual museum via World Wide Web. To achieve our goal, we have developed gonio-photometric imaging system by using high accurate multi-spectral camera and 3D digitizer. In this paper, gonio-photometric imaging method is introduced for recording 3D object. 5-bands images of the object are taken under 7 different illuminants angles. The 5-band image sequences are then analyzed on the basis of both dichromatic reflection model and Phong model to extract gonio-photometric property of the object. The images of the 3D object under illuminants with arbitrary spectral radiant distribution, illuminating angles, and visual points are rendered by using OpenGL with the 3D shape and gonio-photometric property.

  10. An optical study of amorphous (Se80Te20)100-xGex thin films using their transmission spectra

    Science.gov (United States)

    Mainika; Sharma, Pankaj; Katyal, S. C.; Thakur, Nagesh

    2008-12-01

    Optical constants (refractive index and extinction coefficient) have been studied for a-(Se80Te20)100-xGex (x = 0, 2, 4, 6) thin films using transmission spectra in the wavelength range 500 2500 nm. It is observed from optical transmission measurements that the optical energy gap (Eg) increases while the refractive index (n) and the extinction coefficient (k) decrease with the incorporation of Ge in the Se Te system. The increase in the optical energy gap is interpreted by correlating the optical energy gap with the decrease in electronegativity and increase in the heat of atomization (Hs). The dispersion of the refractive index is discussed in terms of the single-oscillator Wemple DiDomenico model.

  11. Design of pitch conversion component for formation of multibeam optical recording head.

    Science.gov (United States)

    Sasaki, Kentaro; Kawamura, Norikazu; Tokumaru, Haruki

    2008-04-10

    We describe a design of a planar lightwave circuit for parallel information processing using visible light. The circuit serves as a pitch conversion component (PCC) that can align multiple beams close together and easily composes a compact optical system that can project optical spots at a narrow pitch on a certain small plane. From the viewpoint of its application to optical recording, a PCC is designed to have over 50 waveguides according to the fabrication of waveguides for a blue-violet beam. It is analytically confirmed that a PCC contributes to the formation of a multibeam optical recording head with numerous beams.

  12. Modeling of electromagnetic wave propagation and spectra of optical excitations in complex media using 4x4 matrix formalism

    CERN Document Server

    Rogers, P D; Sirenko, A A

    2011-01-01

    Using 4x4 matrix formalism we analyzed electromagnetic wave propagation and Jones matrix components for reflectivity and transmittivity in bi-anisotropic materials. Analytic formulas for complex reflection and transmission coefficients for bi-anisotropic materials in both semi-infinite and thin-film configurations have been derived. The obtained results are applicable for analysis of the optical spectra of multiferroic crystals and metamaterials. The Adjusted Oscillator Strength Matching Condition (AOSM) for hybrid magnetic- and electric-dipole excitations in anisotropic multiferroics is derived for oblique angles of incidence. Mueller Matrices are used to simulate spectra of magneto-electric and chiral excitations and methods to distinguish them are discussed.

  13. Optical fibre Bragg grating recorded in TOPAS cyclic olefin copolymer

    DEFF Research Database (Denmark)

    Johnson, I.P.; Yuan, Scott Wu; Stefani, Alessio

    2011-01-01

    A report is presented on the inscription of a fibre Bragg grating into a microstructured polymer optical fibre fabricated from TOPAS cyclic olefin copolymer. This material offers two important advantages over poly (methyl methacrylate), which up to now has formed the basis for polymer fibre Bragg...

  14. Magneto-optical recording media - CoNi/Pt and Co/Pt multilayers

    NARCIS (Netherlands)

    Meng, Q.; Meng, Q.

    1996-01-01

    Concluding Remarks 5.1. General Statement As described in Chapter 1, magneto-optical recording disks have been used in the audio (MiniDisc) and PC as removable disks with high data capacity. Recently, MO disks have been in the competition with the phase-change type of optical disks. Up to now, the

  15. Magneto-optical recording media - CoNi/Pt and Co/Pt multilayers

    NARCIS (Netherlands)

    Meng, Q.

    1996-01-01

    Concluding Remarks 5.1. General Statement As described in Chapter 1, magneto-optical recording disks have been used in the audio (MiniDisc) and PC as removable disks with high data capacity. Recently, MO disks have been in the competition with the phase-change type of optical disks. Up to now,

  16. A novel measuring method for arbitrary optical vortex by three spiral spectra

    Energy Technology Data Exchange (ETDEWEB)

    Ni, Bo [School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006 (China); Guo, Lana [School of Electronics and Information, Guangdong Polytechnic Normal University, Guangzhou 510665 (China); Yue, Chengfeng [School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006 (China); Tang, Zhilie, E-mail: tangzhl@scnu.edu.cn [School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006 (China)

    2017-02-26

    In this letter, the topological charge of non-integer vortices determined by three arbitrary spiral spectra is theoretically demonstrated for the first time. Based on the conclusion, a novel method to measure non-integer vortices is presented. This method is applicable not only to arbitrary non-integer vortex but also to arbitrary integer vortex. - Highlights: • Different non-integer vortices cannot have three spiral spectra is demonstrated. • Relationship between the non-integer topological charge and the spiral spectra is presented. • Topological charge of non-integer vortices can be determined by three arbitrary spiral spectra.

  17. The Type Ic SN 2007gr: a census of the ejecta from late-time optical-infrared spectra

    CERN Document Server

    Mazzali, P A; Valenti, S; Kotak, R; Hunter, D

    2010-01-01

    Nebular spectra of Supernovae (SNe) offer an unimpeded view of the inner region of the ejecta, where most nucleosynthesis takes place. Optical spectra cover most, but not all of the emitting elements, and therefore offer only a partial view of the products of the explosion. Simultaneous optical-infrared spectra, on the other hand, contain emission lines of all important elements, from C and O through to the Intermediate Mass Elements (IME) Mg, Si, S, Ca, and to Fe and Ni. In particular, Si and S are best seen in the IR. The availability of IR data makes it possible to explore in greater detail the results of the explosion. SN\\,2007gr is the first Type Ic SN for which such data are available. Modelling the spectra with a NLTE code reveals that the inner ejecta contain $\\sim 1 \\Msun$ of material within a velocity of $\\approx 4500$\\,\\kms. %The spectrum is powered by \\Nifs, in an amount ($0.076 \\Msun$) consistent with that %derived from the early-time data. The same mass of \\Nifs\\ derived from the light curve pea...

  18. The peculiar optical-UV X-ray spectra of the X-ray weak quasar PG 0043+039

    CERN Document Server

    Kollatschny, W; Zetzl, M; Santos-Lleó, M; Rodríguez-Pascual, P M; Ballo, L; Talavera, A

    2016-01-01

    The object PG 0043+039 has been identified as a broad absorption line (BAL) quasar based on its UV spectra. However, this optical luminous quasar has not been detected before in deep X-ray observations, making it the most extreme X-ray weak quasar known today. This study aims to detect PG 0043+039 in a deep X-ray exposure. The question is what causes the extreme X-ray weakness of PG 0043+039? Does PG 0043+039 show other spectral or continuum peculiarities? We took simultaneous deep X-ray spectra with XMM-Newton, far-ultraviolet (FUV) spectra with the Hubble Space Telescope (HST) and optical spectra of PG 0043+039 with the Hobby-Eberly Telescope (HET) and Southern African Large Telescope (SALT) in July, 2013. We have detected PG 0043+039 in our X-ray exposure taken in 2013. We presented our first results in a separate paper (Kollatschny et al. 2015). PG 0043+039 shows an extreme {\\alpha}_ox gradient ({\\alpha}_ox =-2.37). Furthermore, we were able to verify an X-ray flux of this source in a reanalysis of the X-...

  19. Nonlinear optical spectra having characteristics of Fano interferences in coherently coupled lowest exciton biexciton states in semiconductor quantum dots

    Directory of Open Access Journals (Sweden)

    Hideki Gotoh

    2014-10-01

    Full Text Available Optical nonlinear effects are examined using a two-color micro-photoluminescence (micro-PL method in a coherently coupled exciton-biexciton system in a single quantum dot (QD. PL and photoluminescence excitation spectroscopy (PLE are employed to measure the absorption spectra of the exciton and biexciton states. PLE for Stokes and anti-Stokes PL enables us to clarify the nonlinear optical absorption properties in the lowest exciton and biexciton states. The nonlinear absorption spectra for excitons exhibit asymmetric shapes with peak and dip structures, and provide a distinct contrast to the symmetric dip structures of conventional nonlinear spectra. Theoretical analyses with a density matrix method indicate that the nonlinear spectra are caused not by a simple coherent interaction between the exciton and biexciton states but by coupling effects among exciton, biexciton and continuum states. These results indicate that Fano quantum interference effects appear in exciton-biexciton systems at QDs and offer important insights into their physics.

  20. Ultrafast chirped optical waveform recorder using a time microscope

    Science.gov (United States)

    Bennett, Corey Vincent

    2015-04-21

    A new technique for capturing both the amplitude and phase of an optical waveform is presented. This technique can capture signals with many THz of bandwidths in a single shot (e.g., temporal resolution of about 44 fs), or be operated repetitively at a high rate. That is, each temporal window (or frame) is captured single shot, in real time, but the process may be run repeatedly or single-shot. By also including a variety of possible demultiplexing techniques, this process is scalable to recoding continuous signals.

  1. Optical Absorption Spectra and Excitons of Dye-Substrate Interfaces: Catechol on TiO2(110).

    Science.gov (United States)

    Mowbray, Duncan John; Migani, Annapaola

    2016-06-14

    Optimizing the photovoltaic efficiency of dye-sensitized solar cells (DSSC) based on staggered gap heterojunctions requires a detailed understanding of sub-band gap transitions in the visible from the dye directly to the substrate's conduction band (CB) (type-II DSSCs). Here, we calculate the optical absorption spectra and spatial distribution of bright excitons in the visible region for a prototypical DSSC, catechol on rutile TiO2(110), as a function of coverage and deprotonation of the OH anchoring groups. This is accomplished by solving the Bethe-Salpeter equation (BSE) based on hybrid range-separated exchange and correlation functional (HSE06) density functional theory (DFT) calculations. Such a treatment is necessary to accurately describe the interfacial level alignment and the weakly bound charge transfer transitions that are the dominant absorption mechanism in type-II DSSCs. Our HSE06 BSE spectra agree semiquantitatively with spectra measured for catechol on anatase TiO2 nanoparticles. Our results suggest deprotonation of catechol's OH anchoring groups, while being nearly isoenergetic at high coverages, shifts the onset of the absorption spectra to lower energies, with a concomitant increase in photovoltaic efficiency. Further, the most relevant bright excitons in the visible region are rather intense charge transfer transitions with the electron and hole spatially separated in both the [110] and [001] directions. Such detailed information on the absorption spectra and excitons is only accessible via periodic models of the combined dye-substrate interface.

  2. Detecting single DNA molecule interactions with optical microcavities (Presentation Recording)

    Science.gov (United States)

    Vollmer, Frank

    2015-09-01

    Detecting molecules and their interactions lies at the heart of all biosensor devices, which have important applications in health, environmental monitoring and biomedicine. Achieving biosensing capability at the single molecule level is, moreover, a particularly important goal since single molecule biosensors would not only operate at the ultimate detection limit by resolving individual molecular interactions, but they could also monitor biomolecular properties which are otherwise obscured in ensemble measurements. For example, a single molecule biosensor could resolve the fleeting interaction kinetics between a molecule and its receptor, with immediate applications in clinical diagnostics. We have now developed a label-free biosensing platform that is capable of monitoring single DNA molecules and their interaction kinetics[1], hence achieving an unprecedented sensitivity in the optical domain, Figure 1. We resolve the specific contacts between complementary oligonucleotides, thereby detecting DNA strands with less than 2.4 kDa molecular weight. Furthermore we can discern strands with single nucleotide mismatches by monitoring their interaction kinetics. Our device utilizes small glass microspheres as optical transducers[1,2, 3], which are capable of increasing the number of interactions between a light beam and analyte molecules. A prism is used to couple the light beam into the microsphere. Ourr biosensing approach resolves the specific interaction kinetics between single DNA fragments. The optical transducer is assembled in a simple three-step protocol, and consists of a gold nanorod attached to a glass microsphere, where the surface of the nanorod is further modified with oligonucleotide receptors. The interaction kinetics of an oligonucleotide receptor with DNA fragments in the surrounding aqueous solution is monitored at the single molecule level[1]. The light remains confined inside the sphere where it is guided by total internal reflections along a

  3. Optical Spectra of Candidate International Celestial Reference Frame (ICRF) Flat-spectrum Radio Sources. III.

    Science.gov (United States)

    Titov, O.; Pursimo, T.; Johnston, Helen M.; Stanford, Laura M.; Hunstead, Richard W.; Jauncey, David L.; Zenere, Katrina A.

    2017-04-01

    In extending our spectroscopic program, which targets sources drawn from the International Celestial Reference Frame (ICRF) Catalog, we have obtained spectra for ˜160 compact, flat-spectrum radio sources and determined redshifts for 112 quasars and radio galaxies. A further 14 sources with featureless spectra have been classified as BL Lac objects. Spectra were obtained at three telescopes: the 3.58 m European Southern Observatory New Technology Telescope, and the two 8.2 m Gemini telescopes in Hawaii and Chile. While most of the sources are powerful quasars, a significant fraction of radio galaxies is also included from the list of non-defining ICRF radio sources.

  4. Laser-induced fluorescence and optical reflection spectra of Japanese natural dyes on silk

    OpenAIRE

    Miyoshi, Tadaki; Matsuda, Yasunori

    1987-01-01

    Fluorescence spectra under nitrogen-laser excitation were measured for silk cloth dyed with Japanese natural dyes. An identification of the dyes on silk was carried out using a laser-induced fluorescence (LIF) technique since dyed cloth has a characteristic fluorescence spectra. Moreover, it is possible to identify dyes on faded cloth and on cloth prepared by a combination dyeing using two kinds of dyes. The LIF technique can identify dyes on cloth which is difficult to identify using the ref...

  5. Pulsed Cathodoluminescence Spectra of Solid Oxides with Low Concentrations of Optically-Active Impurities

    CERN Document Server

    Kozlov, V A; Pestovskii, N V; Petrov, A A; Savinov, S Yu; Zavartsev, Yu D; Zavertyaev, M V; Zagumenniy, A I

    2016-01-01

    Pulsed cathodoluminescence (PCL) spectra of ultra-pure SiO2, GeO2, SnO2, TiO2, La2O3, Y2O3, Sc2O3, CaCO3 powders and {\\alpha}-quartz, Ca:YVO4, LiNbO3 and Sc:LiNbO3 crystals were studied under the same experimental conditions. It was found that PCL spectra of SiO2, SnO2, GeO2, TiO2, La2O3 and CaCO3 powders contain a common band with maximum intensity at 500 nm, PCL spectra of samples Y2O3, Sc2O3, PbWO4 and Ca:YVO4 contain a common band at 490 nm and PCL spectra of LiNbO3 and Sc:LiNbO3 crystals contain a common band at 507 nm. It was found that the average intensity of the PCL spectra and position of the maximum intensity of these common bands depend on the type of a band gap transition of the material. We suppose that these common bands have the same origin in PCL spectra of all the materials studied and are related to recombination of O2--O-oxygen complexes. These complexes appear in the vicinities of anionic and cationic vacancies, where the geometry and orientation of coordination polyhedrons are violated d...

  6. Plasma-etched nanostructures for optical applications (Presentation Recording)

    Science.gov (United States)

    Schulz, Ulrike; Rickelt, Friedrich; Munzert, Peter; Kaiser, Norbert

    2015-08-01

    A basic requirement for many optical applications is the reduction of Fresnel-reflections. Besides of interference coatings, nanostructures with sub-wavelength size as known from the eye of the night-flying moth can provide antireflective (AR) properties. The basic principle is to mix a material with air on a sub-wavelength scale to decrease the effective refractive index. To realize AR nanostructures on polymers, the self-organized formation of stochastically arranged antireflective structures using a low-pressure plasma etching process was studied. An advanced procedure involves the use of additional deposition of a thin oxide layer prior etching. A broad range of different structure morphologies exhibiting antireflective properties can be generated on almost all types of polymeric materials. For applications on glass, organic films are used as a transfer medium. Organic layers as thin film materials were evaluated to identify compounds suitable for forming nanostructures by plasma etching. The vapor deposition and etching of organic layers on glass offers a new possibility to achieve antireflective properties in a broad spectral range and for a wide range of light incidence.

  7. Optical archival spectra of blazar candidates of uncertain type in the 3$^{rd}$ Fermi Large Area Telescope Catalog

    CERN Document Server

    Crespo, N Álvarez; D'Abrusco, R; Landoni, M; Masetti, N; Chavushyan, V; Jiménez-Bailón, E; La Franca, F; Milisavljevic, D; Paggi, A; Patiño-Álvarez, V; Ricci, F; Smith, Howard A

    2016-01-01

    Despite the fact that blazars constitute the rarest class among active galactic nuclei (AGNs) they are the largest known population of associated $\\gamma$-ray sources. Many of the $\\gamma$-ray objects listed in the Fermi-Large Area Telescope Third Source catalog (3FGL) are classified as blazar candidates of uncertain type (BCUs), either because they show multifrequency behaviour similar to blazars but lacking optical spectra in the literature, or because the quality of such spectra is too low to confirm their nature. Here we select, out of 585 BCUs in the 3FGL, 42 BCUs which we identify as probable blazars by their WISE infrared colors and which also have optical spectra that are available in the Sloan Digital Sky Survey (SDSS) and/or Six-Degree Field Galaxy Survey Database (6dFGS). We confirm the blazar nature of all of the sources. We furthermore conclude that 28 of them are BL Lacs, 8 are radio-loud quasars with flat radio spectrum and 6 are BL Lac whose emission is dominated by their host galaxy.

  8. Optical archival spectra of blazar candidates of uncertain type in the 3rd Fermi Large Area Telescope Catalog

    Science.gov (United States)

    Álvarez Crespo, N.; Massaro, F.; D'Abrusco, R.; Landoni, M.; Masetti, N.; Chavushyan, V.; Jiménez-Bailón, E.; La Franca, F.; Milisavljevic, D.; Paggi, A.; Patiño-Álvarez, V.; Ricci, F.; Smith, Howard A.

    2016-09-01

    Despite the fact that blazars constitute the rarest class among active galactic nuclei (AGNs) they are the largest known population of associated γ-ray sources. Many of the γ-ray objects listed in the Fermi-Large Area Telescope Third Source catalog (3FGL) are classified as blazar candidates of uncertain type (BCUs), either because they show multifrequency behavior similar to blazars but lacking optical spectra in the literature, or because the quality of such spectra is too low to confirm their nature. Here we select, out of 585 BCUs in the 3FGL, 42 BCUs which we identify as probable blazars by their WISE infrared colors and which also have optical spectra that are available in the Sloan Digital Sky Survey (SDSS) and/or Six-Degree Field Galaxy Survey Database (6dFGS). We confirm the blazar nature of all of the sources. We furthermore conclude that 28 of them are BL Lacs, 8 are radio-loud quasars with flat radio spectrum and 6 are BL Lac whose emission is dominated by their host galaxy.

  9. In−Vitro and In−Vivo Noise Analysis for Optical Neural Recording

    Science.gov (United States)

    Foust, Amanda J.; Schei, Jennifer L.; Rojas, Manuel J.; Rector, David M.

    2008-01-01

    Laser diodes (LD) are commonly used for optical neural recordings in chronically recorded animals and humans, primarily due to their brightness and small size. However, noise introduced by LDs may counteract the benefits of brightness when compared to low−noise light emitting diodes (LEDs). To understand noise sources in optical recordings, we systematically compared instrument and physiological noise profiles in two recording paradigms. A better understanding of noise sources will help improve optical recordings and make them more practical with fewer averages. We stimulated lobster nerves and rat cortex, then compared the root mean square (RMS) noise and signal−to−noise ratios (SNRs) of data obtained with LED, superluminescent diode (SLD) and LD illumination for different numbers of averages. The LED data exhibited significantly higher SNRs in fewer averages than LD data in all recordings. In the absence of tissue, LED noise increased linearly with intensity, while LD noise increased sharply in the transition to lasing and settled to noise levels significantly higher than the LED’s, suggesting that speckle noise contributed to the LD’s higher noise and lower SNRs. Our data recommend low coherence and portable light sources for in−vivo chronic neural recording applications. PMID:19021365

  10. In vitro and in vivo noise analysis for optical neural recording.

    Science.gov (United States)

    Foust, Amanda J; Schei, Jennifer L; Rojas, Manuel J; Rector, David M

    2008-01-01

    Laser diodes (LD) are commonly used for optical neural recordings in chronically recorded animals and humans, primarily due to their brightness and small size. However, noise introduced by LDs may counteract the benefits of brightness when compared to low-noise light-emitting diodes (LEDs). To understand noise sources in optical recordings, we systematically compared instrument and physiological noise profiles in two recording paradigms. A better understanding of noise sources can help improve optical recordings and make them more practical with fewer averages. We stimulated lobster nerves and a rat cortex, then compared the root mean square (RMS) noise and signal-to-noise ratios (SNRs) of data obtained with LED, superluminescent diode (SLD), and LD illumination for different numbers of averages. The LED data exhibited significantly higher SNRs in fewer averages than LD data in all recordings. In the absence of tissue, LED noise increased linearly with intensity, while LD noise increased sharply in the transition to lasing and settled to noise levels significantly higher than the LED's, suggesting that speckle noise contributed to the LD's higher noise and lower SNRs. Our data recommend low coherence and portable light sources for in vivo chronic neural recording applications.

  11. A generalized method for discriminating thermodynamic phase and retrieving cloud optical thickness and effective radius using transmitted shortwave radiance spectra

    Directory of Open Access Journals (Sweden)

    S. E. LeBlanc

    2014-06-01

    Full Text Available A new retrieval scheme for cloud optical thickness, effective radius, and thermodynamic phase was developed for ground-based measurements of cloud shortwave spectral transmittance. 15 parameters were derived to quantify spectral variations in shortwave transmittance due to absorption and scattering of liquid water and ice clouds, manifested by shifts in spectral slopes, curvatures, maxima, and minima. To retrieve cloud optical thickness and effective particle radius a weighted least square fit that matched the modeled parameters was applied. The measurements for this analysis were made with a ground-based Solar Spectral Flux Radiometer (SSFR in Boulder, Colorado, between May 2012 and January 2013. We compared the cloud optical thickness and effective radius from the new retrieval to two other retrieval methods. By using multiple spectral features, we find a closer fit (with a root mean square difference over the entire spectra of 3.1% for a liquid water cloud and 5.9% for an ice cloud between measured and modeled spectra compared to two other retrieval methods, which diverge by a root-mean-square of up to 6.4% for a liquid water cloud and 22.5% for an ice cloud. The new retrieval introduced here has an average uncertainty in effective radius (±1.2 μm smaller by factor of at least 2.5 than two other methods when applied to an ice cloud.

  12. Optical vibronic emission spectra for irradiation induced F aggregate centers in single crystal α-Al2O3

    Science.gov (United States)

    Mohammad Saliqur, Rahman Abu Zayed; Awata, T.; Yamashita, N.; Xu, Qiu; Atobe, K.

    The optical vibronic emission spectra of the single crystal α-Al2O3 caused by neutron bombardment have been studied. New sharp line features near the 470 nm emission band were found. The phonon side band of the previously found zero-phonon line near the 380 nm emission band is also observed in the present study. Vibronic structures associated with the 470 nm emission band are predominantly featured. The Huang-Rhys factor and the Debye temperature are estimated by a curve fitting method to be 3.2 and 710 K, respectively. It can be seen that the origin of the 470 nm vibronic emission spectra is derived from the Fimg style="vertical-align: text-bottom;" class="inlinematheqn" src="/ampp/image?path=/713648881/915810374/grad_a_398864_o_ilm0001.gif" alt="./GRAD_A_398864_O_XML_IMAGES/GRAD_A_398864_O_ILM0001.gif" border="0" /> type center.

  13. Orientation and Optical Polarized Spectra (380–900 nm of Methylene Blue Crystals on a Glass Surface

    Directory of Open Access Journals (Sweden)

    Maja D. Milošević

    2013-01-01

    Full Text Available The crystallographic directions of the crystal toward the vector of polarized light can accurately be positioned, so the information that we gain from polarized spectra can be consistently interpreted according to known crystal structure. The orientation and optical properties of the methylene blue (MB crystals were analyzed by XRD, XRPD, and polarized VIS-NIR spectroscopy. Cationic dye, MB, was polymerized into crystals on a glass slate. The blue color crystals showed pronounced dichroism, twin lamellar structure and bladed to fibrous habit. According to XRD data, [010] direction lies perpendicular to the crystal surface, so we recognized it as (0k0 face, while [100] and [001] directions coincide with crystal elongation and crystal thickness respectively. In this paper, the polarized spectra of MB crystal are presented, measured with the aim of acquisition of referent values, which could be helpful for the identification of MB molecular aggregation.

  14. Lines of Circumstellar C2, CN, and CH$^+$ in the Optical Spectra of Post-Agb Stars

    CERN Document Server

    Bakker, E J; Van Dishoeck, E F; Bakker, Eric J.; Lambert, David L.; Dishoeck, Ewine F. van

    1996-01-01

    Recent optical spectra of post-AGB stars show the presence of C2, CN, and CH+ originating in the circumstellar shell. We present here new, higher resolution spectra which provide constraints on the physical parameters and information on the line profiles. An empirical curve of growth for the C2 Phillips and CN Red system lines in the spectrum of HD 56126 yields b = 0.50 (+0.59, -0.23) km/s. CH+ (0,0) emission lines in the spectrum of the Red Rectangle have been resolved with a FWHM approx 8.5 pm 0.8 km/s. The circumstellar CN lines of IRAS 08005--2356 are resolved into two separate components with a velocity separation of Delta v = 5.7 pm 2.0 km/s. The line profiles of CN of HD 235858 have not been resolved.

  15. Theoretical investigations of the optical and EPR spectra for trivalent cerium and ytterbium ions in orthorhombic YF3 crystal

    Science.gov (United States)

    Liu, Hong-Gang; Zheng, Wen-Chen

    2016-09-01

    The optical spectra and electron paramagnetic resonance (EPR) parameters (g factors and hyperfine structure constants A) for trivalent cerium and ytterbium ions in YF3 crystal with orthorhombic structure are investigated together by the complete diagonalization (of energy matrix) method (CDM). The obtained results are in reasonable agreement with the experimental ones. More importantly, two magnetically nonequivalent centers in YF3 crystal observed in EPR experiments are confirmed and ascribed to their specific positions in a unit cell by our calculations based on superposition model (SPM) analysis. Such identification of local sites with different magnetic properties would help us to understand not only the EPR spectra and magnetic susceptibility of other lanthanide ions doped in crystals with the same structure as YF3 but also the energy transfer scheme between two lanthanide ions occupying such two sites. All results are discussed carefully.

  16. Optical Spectra of Ultracool Dwarfs with the Southern African Large Telescope

    CERN Document Server

    Koen, C; Väisänen, P; Koen, T

    2016-01-01

    New spectra of 81 ultracool dwarfs (spectral types M7 and later) are discussed. Spectral classifications of 49 objects are available in the literature, while 32 objects are newly classified. The known spectral types were used to test an automated classification scheme, which relies primarily on template fitting, supplemented by matching of spectral indices calibrated against the template spectra. An attempt was made to quantify the uncertainty in the spectral types, which is generally better than two subclasses. Objects for which spectral types differ by more than one subclass from the literature classifications are discussed individually. Discrepancies between automated classifications based on respectively template fitting and spectral index matching, may be useful for flagging objects with unusual spectra. Aside from the 32 first-time classifications, alternative classifications are presented for 32 previously classified dwarfs. Very large (equivalent width greater than 130 \\AA) H$\\alpha$ flares are report...

  17. A new method for detecting velocity shifts and distortions between optical spectra

    CERN Document Server

    Evans, Tyler M

    2013-01-01

    Recent quasar spectroscopy from the VLT and Keck telescopes suggests that fundamental constants may not actually be constant. To better confirm or refute this result, systematic errors between telescopes must be minimized. We present a new method to directly compare spectra of the same object and measure any velocity shifts between them. This method allows for the discovery of wavelength-dependent velocity shifts between spectra, i.e. velocity distortions, that could produce spurious detections of cosmological variations in fundamental constants. This "direct comparison" method has several advantages over alternative techniques: it is model-independent (cf. line-fitting approaches), blind, in that spectral features do not need to be identified beforehand, and it produces meaningful uncertainty estimates for the velocity shift measurements. In particular, we demonstrate that, when comparing echelle-resolution spectra with unresolved absorption features, the uncertainty estimates are reliable for signal-to-nois...

  18. Structure Prediction of Self-Assembled Dye Aggregates from Cryogenic Transmission Electron Microscopy, Molecular Mechanics, and Theory of Optical Spectra.

    Science.gov (United States)

    Friedl, Christian; Renger, Thomas; Berlepsch, Hans V; Ludwig, Kai; Schmidt Am Busch, Marcel; Megow, Jörg

    2016-09-01

    Cryogenic transmission electron microscopy (cryo-TEM) studies suggest that TTBC molecules self-assemble in aqueous solution to form single-walled tubes with a diameter of about 35 Å. In order to reveal the arrangement and mutual orientations of the individual molecules in the tube, we combine information from crystal structure data of this dye with a calculation of linear absorbance and linear dichroism spectra and molecular dynamics simulations. We start with wrapping crystal planes in different directions to obtain tubes of suitable diameter. This set of tube models is evaluated by comparing the resulting optical spectra with experimental data. The tubes that can explain the spectra are investigated further by molecular dynamics simulations, including explicit solvent molecules. From the trajectories of the most stable tube models, the short-range ordering of the dye molecules is extracted and the optimization of the structure is iteratively completed. The final structural model is a tube of rings with 6-fold rotational symmetry, where neighboring rings are rotated by 30° and the transition dipole moments of the chromophores form an angle of 74° with respect to the symmetry axis of the tube. This model is in agreement with cryo-TEM images and can explain the optical spectra, consisting of a sharp red-shifted J-band that is polarized parallel to to the symmetry axis of the tube and a broad blue-shifted H-band polarized perpendicular to this axis. The general structure of the homogeneous spectrum of this hybrid HJ-aggregate is described by an analytical model that explains the difference in redistribution of oscillator strength inside the vibrational manifolds of the J- and H-bands and the relative intensities and excitation energies of those bands. In addition to the particular system investigated here, the present methodology can be expected to aid the structure prediction for a wide range of self-assembled dye aggregates.

  19. Far-field head-media optical interaction in heat-assisted magnetic recording

    CERN Document Server

    Yang, Ruoxi; Klemmer, Timothy; Olson, Heidi; Zhang, Deming; Perry, Tyler; Yin, Huaqing; Hipwell, Roger; Thiele, Jan-Ulrich; Tang, Huan; Seigler, Mike

    2015-01-01

    We have used a plane-wave expansion method to theoretically study the far-field head-media optical interaction in HAMR. For the ASTC media stack specifically, we notice the outstanding sensitivity related to interlayer's optical thickness for media reflection and magnetic layer's light absorption. With 10-nm interlayer thickness change, the recording layer absorption can be changed by more than 25%. The 2-D results are found to correlate well with full 3-D model and magnetic recording tests on flyable disc with different interlayer thickness.

  20. Vibrational relaxation beyond the linear damping limit in two-dimensional optical spectra of molecular aggregates

    Science.gov (United States)

    Perlík, Václav; Šanda, František

    2017-08-01

    We present a computational model for the spectra of molecular aggregates with signatures of vibronic progression. Vibronic dynamics is implemented by coupling the dynamics of Frenkel excitons with underdamped vibrations. Vibrational dynamics includes linear damping resulting in the exponential decay and quadratic damping inducing subexponential or power law relaxation and increasing vibrational decoherence as demonstrated on lineshapes of the absorption spectrum. Simulations of the third-order coherent response account for bath reorganization during excitonic transport, which allows us to study the line-shape evolution of cross peaks of 2D spectra.

  1. Optical absorption spectra as a useful tool to find parameters of deep impurity centers in semiconductors.

    Science.gov (United States)

    Makhniy, Viktor P; Horley, Paul P; Kinzerskaya, Oksana V; Stets, Elena V

    2014-04-01

    We analyze physical models accounting for deep-level conduction band transitions to describe impurity absorption spectra in tetrahedral-structured semiconductors. The investigations were carried out for ZnSe crystals doped with transition metals (Ti, V, Cr, Mn, Fe, Co, Ni) from a vapor phase. It was shown that the impurities provide acceptor centers with ground state energy offset by 0.3-0.6 eV from the edge of the conduction band, forming long-wave bands in the absorption spectra of the materials studied.

  2. Could bright γ-ray burst optical transients have been recorded historically?

    Institute of Scientific and Technical Information of China (English)

    Richard G. Strom; Fu-Yuan Zhao; Cheng-Min Zhang

    2012-01-01

    The brightest optical flash from a γ-ray burst (GRB) was,briefly,a nakedeye object.Several other GRBs have produced optical transients only slightly fainter.We argue that,based upon the recently accumulated data from hundreds of GRB transients,many such optical events should have been visible to the unaided eye in the course of human history.The most likely repositories of such observations are historical records from the Orient,and we have located and discuss a number of candidates.We also consider the value of such observations,should any very likely ones be uncovered,to modern astrophysics.

  3. Structural characterization of astaxanthin aggregates as revealed by analysis and simulation of optical spectra

    Science.gov (United States)

    Lu, Liping; Hu, Taoping; Xu, Zhigang

    2017-10-01

    Carotenoids can self-assemble in hydrated polar solvents to form J- or H-type aggregates, inducing dramatic changes in photophysical properties. Here, we measured absorption and emission spectra of astaxanthin in ethanol-water solution using ultraviolet-visible and fluorescence spectrometers. Two types of aggregates were distinguished in mixed solution at different water contents by absorption spectra. After addition of water, all probed samples immediately formed H-aggregates with maximum blue shift of 31 nm. In addition, J-aggregate was formed in 1:3 ethanol-water solution measured after an hour. Based on Frenkel exciton model, we calculated linear absorption and emission spectra of these aggregates to describe aggregate structures in solution. For astaxanthin, experimental results agreed well with the fitted spectra of H-aggregate models, which consisted of tightly packed stacks of individual molecules, including hexamers, trimers, and dimers. Transition moment of single astaxanthin in ethanol was obtained by Gaussian 09 program package to estimate the distance between molecules in aggregates. Intermolecular distance of astaxanthin aggregates ranges from 0.45 nm to 0.9 nm. Fluorescence analysis showed that between subbands, strong exciton coupling induced rapid relaxation of H-aggregates. This coupling generated larger Stokes shift than monomers and J-aggregates.

  4. A novel measuring method for arbitrary optical vortex by three spiral spectra

    Science.gov (United States)

    Ni, Bo; Guo, Lana; Yue, Chengfeng; Tang, Zhilie

    2017-02-01

    In this letter, the topological charge of non-integer vortices determined by three arbitrary spiral spectra is theoretically demonstrated for the first time. Based on the conclusion, a novel method to measure non-integer vortices is presented. This method is applicable not only to arbitrary non-integer vortex but also to arbitrary integer vortex.

  5. Optical absorption and magnetic circular dichroism spectra of thiouracils: a quantum mechanical study in solution

    DEFF Research Database (Denmark)

    Martínez-Fernández, L.; Fahleson, Tobias; Norman, Patrick

    2017-01-01

    The excited electronic states of 2-thiouracil, 4-thiouracil and 2,4-dithiouracil, the analogues of uracil where the carbonyl oxygens are substituted by sulphur atoms, have been investigated by computing the magnetic circular dichroism (MCD) and one-photon absorption (OPA) spectra at the time...

  6. Long-Term Optical Spectra Variability of BL Lacertae Object S5 0716+714

    Indian Academy of Sciences (India)

    Zhang Hao Jing; Zhao Gang; Zhang Xiong; Bai Jing Ming; Tang Ling; Xu Yun Bing

    2011-03-01

    Based on the long-term data from observations, we present an evidence for its spectral index variability behaviour in optical bands for BL Lacertae object S5 0716+714.We find that the spectral index variability period is in agreement with the flux variability period of about 1180 days in optical bands.We also find that the spectral index variability has periods of about 71 and 60 days which cannot be compared with the amplitude of long-term variability.

  7. Microstructures and Recording Mechanism of Mo/Si Bilayer Applied for Write-Once Blue Laser Optical Recording

    Directory of Open Access Journals (Sweden)

    Sin-Liang Ou

    2014-01-01

    Full Text Available Mo/Si bilayer thin films were grown by magnetron sputtering and applied to write-once blu-ray disc (BD-R. The microstructures and optical storage properties of Mo/Si bilayer were investigated. From the temperature dependence of reflectivity measurement, it was revealed that a phase change occurred in the range of 255–425°C. Transmission electron microscopy analysis showed that the as-deposited film possessed Mo polycrystalline phase. The hexagonal MoSi2 and cubic Mo3Si phases appeared after annealing at 300 and 450°C, respectively. By measuring the optical reflectivity at a wavelength of 405 nm, the optical contrast of Mo/Si bilayer between as-deposited and 450°C-annealed states was evaluated to 25.8%. The optimum jitter value of 6.8% was obtained at 10.65 mW for 4× recording speed. The dynamic tests show that the Mo/Si bilayer has high potential in BD-R applications.

  8. Realization of non-PT -symmetric optical potentials with all-real spectra in a coherent atomic system

    Science.gov (United States)

    Hang, Chao; Gabadadze, Gregory; Huang, Guoxiang

    2017-02-01

    We present a physical setup for realizing all-real-spectrum optical potentials with arbitrary gain-and-loss distributions in a coherent medium consisting of a cold three-level atomic gas driven by control and probe laser fields. We show that by the interference of Raman resonances and the Stark shift induced by a far-detuned laser field, tunable, non-parity-time (non-PT )-symmetric optical potentials with all-real spectra proposed recently by Nixon and Yang [Phys. Rev. A 93, 031802(R) (2016), 10.1103/PhysRevA.93.031802] can be actualized physically. We also show that when the real parts of the non-PT -symmetric optical potentials are tuned cross certain thresholds, phase transitions—where the eigenspectrum of the system changes from all real to complex—may occur and hence the stability of the probe-field propagation is altered. Our scheme can also be extended to high dimensions and to a nonlinear propagation regime, where stable optical solitons with power of the order of nano-Watts may be generated in the system.

  9. Synthesis and application for optical recording of a new diarylethene having a benzene unit

    Energy Technology Data Exchange (ETDEWEB)

    Yan Peijian; Pu Shouzhi; Liu Weijun; Liu Gang, E-mail: pushouzhi@tsinghua.org.cn [Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013 (China)

    2011-02-01

    A novel photochromic diarylethene was synthesized and its photochromism, fluorescence properties have been investigated. This compound exhibited good photochromism and functioned as a fluorescence switch upon alternating irradiation with UV and visible light both in solution and in PMMA film. When diarylethene was used as recording medium, the results demonstrated that the diarylethene compound had attractive properties for high density optical storage.

  10. Modeling Optical Spectra of Large Organic Systems Using Real-Time Propagation of Semiempirical Effective Hamiltonians.

    Science.gov (United States)

    Ghosh, Soumen; Andersen, Amity; Gagliardi, Laura; Cramer, Christopher J; Govind, Niranjan

    2017-09-12

    We present an implementation of a time-dependent semiempirical method (INDO/S) in NWChem using real-time (RT) propagation to address, in principle, the entire spectrum of valence electronic excitations. Adopting this model, we study the UV/vis spectra of medium-sized systems such as P3B2 and f-coronene, and in addition much larger systems such as ubiquitin in the gas phase and the betanin chromophore in the presence of two explicit solvents (water and methanol). RT-INDO/S provides qualitatively and often quantitatively accurate results when compared with RT- TDDFT or experimental spectra. Even though we only consider the INDO/S Hamiltonian in this work, our implementation provides a framework for performing electron dynamics in large systems using semiempirical Hartree-Fock Hamiltonians in general.

  11. Modeling Optical Spectra of Large Organic Systems using Real-Time Propagation of Semiempirical Effective Hamiltonians

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Soumen; Andersen, Amity; Gagliardi, Laura; Cramer, Christopher J.; Govind, Niranjan

    2017-09-01

    We present an implementation of a time-dependent semiempirical method (INDO/S) in NWChem using real-time (RT) propagation to address, in principle, the entire spectrum of valence electronic excitations. Adopting this model, we study the UV-visible spectra of medium-sized systems like P3B2, f-coronene, and in addition much larger systems like ubiquitin in the gas phase and the betanin chromophore in the presence of two explicit solvents (water and methanol). RT-INDO/S provides qualitatively and indeed often quantitatively accurate results when compared with RT- TDDFT or experimental spectra. While demonstrated here for INDO/S in particular, our implementation provides a framework for performing electron dynamics in large systems using semiempirical Hartree-Fock (HF) Hamiltonians in general.

  12. Optical-NIR spectra of quasars close to reionization (z~ 6)

    CERN Document Server

    D’Odorico, V; Cristiani, S; Maiolino, R; Molaro, P; Nonino, M; Cimatti, A; Alighieri, S di Serego; Fiore, F; Fontana, A; Gallerani, S; Giallongo, E; Mannucci, F; Marconi, A; Pentericci, L; Viel, M; Vladilo, G

    2011-01-01

    X-shooter, with its characteristics of resolution, spectral coverage and efficiency, provides a unique opportunity to obtain spectra of the highest-redshift quasars (z ~ 6) that will allow us to carry out successful investigations on key cosmological issues, from the details of the re-ionization process, to the evolution of the first galaxies and AGNs. In this paper, we present the spectra of three z ~ 6 quasars: one obtained during the commissioning of X-shooter and two in the context of our ongoing GTO programme. Combining this sample with data in the literature, we update the value of the C IV cosmic mass density in the range 4.5 \\leq z \\leq 5, confirming the constant trend with redshift between 2.5 and 5.

  13. An efficient tool to calculate two-dimensional optical spectra for photoactive molecular complexes

    CERN Document Server

    Duan, Hong-Guang; Nalbach, Peter; Thorwart, Michael

    2015-01-01

    We combine the coherent modified Redfield theory (CMRT) with the equation of motion-phase matching approach (PMA) to calculate two-dimensional photon echo spectra for photoactive molecular complexes with an intermediate strength of the coupling to their environment. Both techniques are highly efficient, yet they involve approximations at different levels. By explicitly comparing with the numerically exact quasi-adiabatic path integral approach, we show for the Fenna-Matthews-Olson complex that the CMRT describes the decay rates in the population dynamics well, but final stationary populations and the oscillation frequencies differ slightly. In addition, we use the combined CMRT+PMA to calculate two-dimensional photon-echo spectra for a simple dimer model. We find excellent agreement with the exact path integral calculations at short waiting times where the dynamics is still coherent. For long waiting times, differences occur due to different final stationary states, specifically for strong system-bath couplin...

  14. Growth and Optical Spectra of Zn:Er:LiNbO3 Crystals Using Bridgman Method

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The growth of LiNbO3 single crystal with Er3 + and Zn2 + co-doped using Bridgman method and its characteristicabsorption spectra and fluorescence spectra were reported. Large-size crystals initially containing Zn2+ (3%) and Er3+diffraction and differential thermal analysis (DTA) were used to characterize the crystals. The results indicate that the con-centration of Er3 + ions in crystals, their absorption intensity, and their fluorescence intensity decrease from the bottom to thetop in the crystals. However, for the upper part of the crystal, the up-conversion fluorescence intensity is higher than that ofthe lower part excited by an 800 or 970 nm pump. The effects of the crystal lattice, their structural defect and their effectivesegregation of Er3 + ions were discussed with respect to the variations of the up-conversion fluorescence intensity.

  15. Nanofabrication at 1nm resolution by quantum optical lithography (Presentation Recording)

    Science.gov (United States)

    Pavel, Eugen

    2015-08-01

    A major problem in the optical lithography was the diffraction limit. Here, we report and demonstrate a lithography method, Quantum Optical Lithography [1,2], able to attain 1 nm resolution by optical means using new materials (fluorescent photosensitive glass-ceramics and QMC-5 resist). The performance is several times better than that described for any optical or Electron Beam Lithography (EBL) methods. In Fig. 1 we present TEM images of 1 nm lines recorded at 9.6 m/s. a) b) Fig. 1 TEM images of: a) multiple 1 nm lines written in a fluorescent photosensitive glass-ceramics sample; b) single 1 nm line written in QMC-5 resist. References [1] E. Pavel, S. Jinga, B.S. Vasile, A. Dinescu, V. Marinescu, R. Trusca and N. Tosa, "Quantum Optical Lithography from 1 nm resolution to pattern transfer on silicon wafer", Optics and Laser Technology, 60 (2014) 80-84. [2] E. Pavel, S. Jinga, E. Andronescu, B.S. Vasile, G. Kada, A. Sasahara, N. Tosa, A. Matei, M. Dinescu, A. Dinescu and O.R. Vasile, "2 nm Quantum Optical Lithography", Optics Communications,291 (2013) 259-263

  16. Performance of DFT Methods in the Calculation of Optical Spectra of TCF-Chromophores.

    Science.gov (United States)

    Andzelm, Jan; Rinderspacher, Berend C; Rawlett, Adam; Dougherty, Joseph; Baer, Roi; Govind, Niranjan

    2009-10-13

    We present electronic structure calculations of the ultraviolet/visible (UV-vis) spectra of highly active push-pull chromophores containing the tricyanofuran (TCF) acceptor group. In particular, we have applied the recently developed long-range corrected Baer-Neuhauser-Livshits (BNL) exchange-correlation functional. The performance of this functional compares favorably with other density functional theory (DFT) approaches, including the CAM-B3LYP functional. The accuracy of UV-vis results for these molecules is best at low values of attenuation parameters (γ) for both BNL and CAM-B3LYP functionals. The optimal value of γ is different for the charge-transfer (CT) and π-π* excitations. The BNL and PBE0 exchange correlation functionals capture the CT states particularly well, while the π-π* excitations are less accurate and system dependent. Chromophore conformations, which considerably affect the molecular hyperpolarizability, do not significantly influence the UV-vis spectra on average. As expected, the color of chromophores is a sensitive function of modifications to its conjugated framework and is not significantly affected by increasing aliphatic chain length linking a chromophore to a polymer. For selected push-pull aryl-chromophores, we find a significant dependence of absorption spectra on the strength of diphenylaminophenyl donors.

  17. Optical spectra of ultracool dwarfs with the Southern African Large Telescope

    Science.gov (United States)

    Koen, C.; Miszalski, B.; Väisänen, P.; Koen, T.

    2017-03-01

    New spectra of 81 ultracool dwarfs (spectral types M7 and later) are discussed. Spectral classifications of 49 objects are available in the literature, while 32 objects are newly classified. The known spectral types were used to test an automated classification scheme, which relies primarily on template fitting, supplemented by matching of spectral indices calibrated against the template spectra. An attempt was made to quantify the uncertainty in the spectral types, which is generally better than two subclasses. Objects for which spectral types differ by more than one subclass from the literature classifications are discussed individually. Discrepancies between automated classifications based on, respectively, template fitting and spectral index matching, may be useful for flagging objects with unusual spectra. Aside from the 32 first-time classifications, alternative classifications are presented for 32 previously classified dwarfs. Very large (equivalent width greater than 130 Å) Hα flares are reported for the known ultracool dwarf binary 2MASS J15200224-4422419; curiously, the object does not appear to have quiescent emission lines. Non-zero equivalent-width measurements are listed for a further 29 objects.

  18. Mirror symmetry and vibrational structure in optical spectra of chlorophyll a.

    Science.gov (United States)

    Rätsep, Margus; Linnanto, Juha; Freiberg, Arvi

    2009-05-21

    The absorption and fluorescence emission spectra of chlorophyll a in different organic solvents where the central Mg atom is either penta- or hexacoordinated have been studied using conventional and selective spectroscopy methods at ambient and cryogenic temperatures. A breakdown of the basic model mirror-symmetry rule in relation to the lowest-energy Q(y) transitions was observed due to Franck-Condon and Hertzberg-Teller interactions. Detailed vibrational structure in the ground electronic state, virtually independent of the Mg coordination state, was revealed by hole-burning fluorescence line-narrowing technique. The total Huang-Rhys factor associated with the linear vibronic coupling strength of the solvent collective vibrations and the local chlorophyll a intramolecular vibrations is equal to 0.53+/-0.07 in fluorescence and to 0.39+/-0.05 in absorption. The electron-phonon coupling part was also found to depend on the excitation wavelength within the inhomogeneously broadened absorption origin band, its average value being S(ph) approximately = 0.38. All these numbers qualify for the weak vibronic coupling. A comparison of the conjugate Q(y) absorption and fluorescence emission spectra as well as the temperature dependence of the absorption spectra allowed unambiguous locating of the still controversial Q(x) absorption band position for penta- and hexacoordinated chlorophyll a species. The basic experimental findings have been qualitatively supported by semiempirical quantum chemical calculations.

  19. Determination of Structural and Morphological Parameters of Human Bulbar Conjunctiva from Optical Diffuse Reflectance Spectra

    Science.gov (United States)

    Lisenko, S. A.; Firago, V. A.; Kugeiko, M. M.; Kubarko, A. I.

    2016-09-01

    We have developed a method for on-the-fl y retrieval of the volume concentration of blood vessels, the average diameter of the blood vessels, the blood oxygenation level, and the molar concentrations of chromophores in the bulbar conjunctiva from its diffuse reflectance spectra, measured when the radiation delivery and detection channels are spatially separated. The relationship between the diffuse reflectance spectrum of the conjunctiva and its unknown parameters is described in terms of an analytical model, constructed on the basis of a highly accurate approximation analog of the Monte Carlo method. We have studied the effect of localization of hemoglobin in erythrocytes and localization of erythrocytes in the blood vessels on the power of the retrieval of structural and morphological parameters for the conjunctiva. We developed a device for obtaining video images of the conjunctiva and contactless measurements of its diffuse reflectance spectrum. By comparing simulated diffuse reflectance spectra of the conjunctiva with the experimental measurements, we established a set of chromophores which must be taken into account in the model for reproducing the experimental data within the measurement error. We observed absorption bands for neuroglobin in the experimental spectra, and provided a theoretical basis for the possibility of determining its absolute concentrations in the conjunctiva. We have shown that our method can detect low bilirubin concentrations in blood.

  20. Theoretical Investigation of the Optical Spectra of Organic Compounds in Natural Surrounding

    Science.gov (United States)

    Pomogaev, V. A.; Artyukhov, V. Ya.

    2016-08-01

    The hybrid multiscale approximation based on molecular dynamics, quantum mechanics, and statistical theory is used to generate profiles of electronic vibrational absorption and fluorescence bands of some organic compounds and biological objects whose photophysical properties specifically depend on external conditions. A temperature dependence of the spectrum width and intensity of transition to the long-wavelength band of benzene surrounded by cyclohexane molecules is demonstrated. Statistical broadband absorption spectra for estradiol in ethanol, hexane, and dimethyl sulfoxide have been obtained and analyzed at room temperature together with a wide spectrum of transitions to numerous excited states of Trp-cage miniprotein. The absorption and emission spectra of 9-cyan anthracene have been generated under various thermodynamic conditions. This allows changes in the spectral profile with increasing temperatures and pressure to be detected. A dependence of the tryptophan spectra on the protein microsurrounding is investigated. The possibility of charge transfer from tryptophan residue to the eupatorin molecule trapped by human serum albumin is analyzed. Spectral properties and charge transfer from the excited donor to acceptor states are calculated using the polarizable embedding approach for modeling of surrounding protein structure.

  1. Library of medium-resolution fiber optic echelle spectra of F, G, K and M field dwarfs to giant stars

    CERN Document Server

    Montes, D; Welty, A D; Montes, David; Ramsey, Lawrence W.; Welty, Alan D.

    1999-01-01

    We present a library of Penn State Fiber Optic Echelle (FOE) observations of a sample of field stars with spectral types F to M and luminosity classes V to I. The spectral coverage is from 3800 AA to 10000 AA with nominal a resolving power 12000. These spectra include many of the spectral lines most widely used as optical and near-infrared indicators of chromospheric activity such as the Balmer lines (H_alpha, H_beta), Ca II H & K, Mg I b triplet, Na I D_{1} and D_{2}, He I D_{3}, and Ca II IRT lines. There are also a large number of photospheric lines, which can also be affected by chromospheric activity, and temperature sensitive photospheric features such as TiO bands. The spectra have been compiled with the goal of providing a set of standards observed at medium resolution. We have extensively used such data for the study of active chromosphere stars by applying a spectral subtraction technique. However, the data set presented here can also be utilized in a wide variety of ways ranging from radial vel...

  2. The influence of oxygen and nitrogen doping on GeSbTe phase-change optical recording media properties

    Energy Technology Data Exchange (ETDEWEB)

    Dimitrov, D.; Shieh, H.-P.D

    2004-03-15

    Nitrogen and oxygen doped and co-doped GeSbTe (GST) films for phase-change optical recording are investigated. It is found that the crystallization temperature increased as well as the crystalline microstructure refined by doping. The carrier-to-noise ratio (CNR) and erasability of phase-change optical disks are improved being up to 52 and 35 dB, respectively, by using an appropriate nitrogen doping or co-doping concentration in the recording layer. Optical disks with co-doped recording layer are found to be superior in the recording characteristics then the single doped recording layer disks.

  3. Low-resolution optical spectra of ultracool dwarfs with OSIRIS/GTC

    CERN Document Server

    Metodieva, Yanina; Golev, Valeri; Dimitrov, Dinko; García-Álvarez, David; Doyle, John Gerard

    2014-01-01

    We present the results of low-resolution optical spectroscopy with OSIRIS/GTC (Optical System for Imaging and Low Resolution Integrated Spectroscopy / Gran Telescopio Canarias) for a sample of ultracool dwarfs. For a subsample of seven objects, based on 2MASS NIR photometric colours, a 'photometric' spectral type is determined and compared to the results of the optical spectroscopy. For the stars, showing H$\\alpha$ line in emission, equivalent widths were measured, and the ratio of H$\\alpha$ to bolometric luminosity were calculated. We find that two dwarfs show the presence of magnetic activity over long periods, LP 326-21 -- quasi-constant-like, and 2MASS J17071830+6439331 -- variable.

  4. Optical phonon spectra of GaP nanoparticles prepared by nanochemistry

    Science.gov (United States)

    Manciu, F. S.; Sahoo, Y.; MacRae, D. J.; Furis, M.; McCombe, B. D.; Prasad, P. N.

    2003-06-01

    Gallium phosphide (GaP) nanoparticles have been synthesized by colloidal nanochemistry with two different surfactants: trioctylphosphine oxide and dodecylamine. Transverse optical (bulk) and surface optical phonons associated with the GaP nanoparticles were observed and studied experimentally by infrared transmission spectroscopy of a solid dispersion of these nanoparticles in cesium iodide pellets. These vibrational properties of the nanoparticles were used to obtain information about the crystallinity and surface interactions. The crystallinity and the stoichiometry of the samples were also examined and characterized by transmission electron microscopy, electron diffraction, and energy dispersive x-ray spectroscopy.

  5. Comments on the optical lineshape function: Application to transient hole-burned spectra of bacterial reaction centers

    Energy Technology Data Exchange (ETDEWEB)

    Reppert, Mike; Kell, Adam; Pruitt, Thomas [Department of Chemistry, Kansas State University, Manhattan, Kansas 66506 (United States); Jankowiak, Ryszard, E-mail: ryszard@ksu.edu [Department of Chemistry, Kansas State University, Manhattan, Kansas 66506 (United States); Department of Physics, Kansas State University, Manhattan, Kansas 66506 (United States)

    2015-03-07

    The vibrational spectral density is an important physical parameter needed to describe both linear and non-linear spectra of multi-chromophore systems such as photosynthetic complexes. Low-temperature techniques such as hole burning (HB) and fluorescence line narrowing are commonly used to extract the spectral density for a given electronic transition from experimental data. We report here that the lineshape function formula reported by Hayes et al. [J. Phys. Chem. 98, 7337 (1994)] in the mean-phonon approximation and frequently applied to analyzing HB data contains inconsistencies in notation, leading to essentially incorrect expressions in cases of moderate and strong electron-phonon (el-ph) coupling strengths. A corrected lineshape function L(ω) is given that retains the computational and intuitive advantages of the expression of Hayes et al. [J. Phys. Chem. 98, 7337 (1994)]. Although the corrected lineshape function could be used in modeling studies of various optical spectra, we suggest that it is better to calculate the lineshape function numerically, without introducing the mean-phonon approximation. New theoretical fits of the P870 and P960 absorption bands and frequency-dependent resonant HB spectra of Rb. sphaeroides and Rps. viridis reaction centers are provided as examples to demonstrate the importance of correct lineshape expressions. Comparison with the previously determined el-ph coupling parameters [Johnson et al., J. Phys. Chem. 94, 5849 (1990); Lyle et al., ibid. 97, 6924 (1993); Reddy et al., ibid. 97, 6934 (1993)] is also provided. The new fits lead to modified el-ph coupling strengths and different frequencies of the special pair marker mode, ω{sub sp}, for Rb. sphaeroides that could be used in the future for more advanced calculations of absorption and HB spectra obtained for various bacterial reaction centers.

  6. Acousto-Optic Tunable Filter Hyperspectral Microscope Imaging Method for Characterizing Spectra from Foodborne Pathogens.

    Science.gov (United States)

    Hyperspectral microscope imaging (HMI) method, which provides both spatial and spectral characteristics of samples, can be effective for foodborne pathogen detection. The acousto-optic tunable filter (AOTF)-based HMI method can be used to characterize spectral properties of biofilms formed by Salmon...

  7. The structural parameters of self-assembled quantum dots determined from the optical spectra

    Science.gov (United States)

    Hong, Boon Hon; Tinkler, Lloyd; Beaumont, Matthew; Rybchenko, Sergey I.; Itskevich, Igor E.; Haywood, Stephanie K.; Hugues, Maxime

    2013-12-01

    Structural parameters of InGaAs/GaAs self-assembled quantum dots (SAQDs), which were grown using In-flush technique, were deduced using optical spectroscopy combined with computer modeling. The results are in excellent agreement with the experimental data obtained from transmission electron microscopy. The developed approach suggests a promising alternative to structural characterization methods for SAQDs.

  8. The structural parameters of self-assembled quantum dots determined from the optical spectra

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Boon Hon; Beaumont, Matthew; Rybchenko, Sergey I.; Itskevich, Igor E.; Haywood, Stephanie K. [Department of Engineering, University of Hull, Cottingham Road, Hull, HU6 7RX (United Kingdom); Tinkler, Lloyd [Department of Engineering, University of Hull, Cottingham Road, Hull, HU6 7RX, UK and Department of Physics and Astronomy, University of Sheffield, Hounsfield Road, Sheffield, S3 7RH (United Kingdom); Hugues, Maxime [CRHEA-CNRS, Rue Bernard Grégory, 06560 Valbonne (France)

    2013-12-04

    Structural parameters of InGaAs/GaAs self-assembled quantum dots (SAQDs), which were grown using In-flush technique, were deduced using optical spectroscopy combined with computer modeling. The results are in excellent agreement with the experimental data obtained from transmission electron microscopy. The developed approach suggests a promising alternative to structural characterization methods for SAQDs.

  9. Effect of Molar Concentration on Optical Absorption Spectra of ZnS:Mn Nanoparticles

    Directory of Open Access Journals (Sweden)

    Ravi Sharma

    2010-01-01

    Full Text Available The present paper reports the synthesis and characterization of luminescent nanocrystals of manganese doped zinc sulphide. Nanocrystals of zinc sulphide were prepared by chemical precipitation method using the solution of zinc chloride, sodium sulphide, manganese chloride and mercaptoethanol was used as the capping agent. It was found that change in the molar concentration changes the particle size. The particle size of such nanocrystals was measured using XRD pattern and it is found to be in between 3 nm – 5 nm. The blue-shift in absorption spectra was found with reducing size of the nanoparticles

  10. Optical constants of silicon carbide for astrophysical applications. II. Extending optical functions from IR to UV using single-crystal absorption spectra

    CERN Document Server

    Hofmeister, A M; Goncharov, A F; Speck, A K

    2009-01-01

    Laboratory measurements of unpolarized and polarized absorption spectra of various samples and crystal stuctures of silicon carbide (SiC) are presented from 1200--35,000 cm$^{-1}$ ($\\lambda \\sim$ 8--0.28 $\\mu$m) and used to improve the accuracy of optical functions ($n$ and $k$) from the infrared (IR) to the ultraviolet (UV). Comparison with previous $\\lambda \\sim$ 6--20 $\\mu$m thin-film spectra constrains the thickness of the films and verifies that recent IR reflectivity data provide correct values for $k$ in the IR region. We extract $n$ and $k$ needed for radiative transfer models using a new ``difference method'', which utilizes transmission spectra measured from two SiC single-crystals with different thicknesses. This method is ideal for near-IR to visible regions where absorbance and reflectance are low and can be applied to any material. Comparing our results with previous UV measurements of SiC, we distinguish between chemical and structural effects at high frequency. We find that for all spectral re...

  11. Deriving depth-dependent light escape efficiency and optical Swank factor from measured pulse height spectra of scintillators.

    Science.gov (United States)

    Howansky, Adrian; Peng, Boyu; Lubinsky, Anthony R; Zhao, Wei

    2017-03-01

    Pulse height spectroscopy has been used by investigators to deduce the imaging properties of scintillators. Pulse height spectra (PHS) are used to compute the Swank factor, which describes the variation in scintillator light output per x-ray interaction. The spread in PHS measured below the K-edge is related to the optical component of the Swank factor, i.e., variations in light escape efficiency from different depths of x-ray interaction in the scintillator, denoted ε¯(z). Optimizing scintillators for medical imaging applications requires understanding of these optical properties, as they determine tradeoffs between parameters such as x-ray absorption, light yield, and spatial resolution. This work develops a model for PHS acquisition such that the effect of measurement uncertainty can be removed. This method allows ε¯(z) to be quantified on an absolute scale and permits more accurate estimation of the optical Swank factor of scintillators. The pulse height spectroscopy acquisition chain was modeled as a linear system of stochastic gain stages. Analytical expressions were derived for signal and noise propagation through the PHS chain, accounting for deterministic and stochastic aspects of x-ray absorption, scintillation, and light detection with a photomultiplier tube. The derived expressions were used to calculate PHS of thallium-doped cesium iodide (CsI) scintillators using parameters that were measured, calculated, or known from literature. PHS were measured at 25 and 32 keV of CsI samples designed with an optically reflective or absorptive backing, with or without a fiber-optic faceplate (FOP), and with thicknesses ranging from 150-1000 μm. Measured PHS were compared with calculated PHS, then light escape model parameters were varied until measured and modeled results reached agreement. Resulting estimates of ε¯(z) were used to calculate each scintillator's optical Swank factor. For scintillators of the same optical design, only minor differences in

  12. Optical spectra of Nd{sup 3+} in niobates of the tetragonal tungsten bronze family

    Energy Technology Data Exchange (ETDEWEB)

    Cavalli, Enrico [INFM and Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Universita di Parma, Viale delle Scienze 17/a, 43100 Parma (Italy); Calestani, Gianluca [INFM and Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Universita di Parma, Viale delle Scienze 17/a, 43100 Parma (Italy); Bovero, Enrico [INFM and Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Universita di Parma, Viale delle Scienze 17/a, 43100 Parma (Italy); Belletti, Alessandro [INFM and Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Universita di Parma, Viale delle Scienze 17/a, 43100 Parma (Italy); Migliori, Andrea [CNR-IMM, Sezione di Bologna, Via P Godetti 101, 40129 Bologna (Italy)

    2004-02-18

    Nd:Ba{sub 2}NaNb{sub 5}O{sub 15} (Nd:BNN), Nd:Ba{sub 2}KNb{sub 5}O{sub 15} (Nd:BKN) and Ba{sub 1.90}Nd{sub 0.26} Li{sub 0.42}Nb{sub 5}O{sub 15} (BNdLN) single crystals with the tetragonal tungsten-bronze (TTB) structure have been grown by means of the 'flux growth' method. The 10 and 298 K absorption and emission spectra and the room temperature decay curves have been measured and discussed in the light of the crystallographic information. The room temperature absorption spectra of Nd:BKN and BNdLN have been analysed in the framework of Judd-Ofelt theory and the {omega}{sub {lambda}} ({lambda} = 2, 4, 6) intensity parameters have been evaluated. The structural and emission properties of a new TB phase, Nd:Ba{sub 2}LiNb{sub 5}O{sub 15} (Nd:BLN), have also been reported because they are useful in the discussion concerning the site occupancy of the active ions in these materials.

  13. Evaluation of a fiber-optic technique for recording intramuscular pressure in the human leg.

    Science.gov (United States)

    Nilsson, Andreas; Zhang, Qiuxia; Styf, Jorma

    2016-10-01

    To evaluate a forward-sensing fiber-optic pressure technique for recording of intramuscular pressure (IMP) in the human leg and investigate factors that may influence IMP measurements used in diagnosing compartment syndromes. IMP in the tibialis anterior muscle was recorded simultaneously by a fiber-optic technique and needle-injection technique in 12 legs of 7 healthy subjects. Both measurement catheters were placed in parallel with the muscle fibers to the same depth, as verified by sonography. IMP recordings were performed at rest before, during and after applying a model of abnormally elevated IMP (simulated compartment syndrome). IMP was elevated by venous obstruction induced by a thigh tourniquet of a casted leg. IMP was also measured during injections of 0.1 ml of saline into the muscle through the catheters. IMP at baseline was 5.1 (SD = 2.6) mmHg measured with the fiber-optic technique and 7.1 (SD = 2.5) mmHg with the needle-injection technique (p syndrome. IMP increased significantly following injection of 0.1 ml of saline, measured by both techniques. It remained increased 1 min after injection. The fiber-optic technique was able to record pulse-synchronous IMP oscillations. The fiber-optic technique may be used for IMP measurements in a muscle with both normal and abnormally elevated IMP. It has good dynamic properties allowing for measurement of IMP oscillations. Saline injection used with needle-injection systems to ensure catheter patency compromises IMP readings at least one minute after injection.

  14. Effects of crossed electric and magnetic fields on the interband optical absorption spectra of variably spaced semiconductor superlattices

    Science.gov (United States)

    Zuleta, J. N.; Reyes-Gómez, E.

    2016-05-01

    The interband optical absorption spectra of a GaAs-Ga1-xAlxAs variably spaced semiconductor superlattice under crossed in-plane magnetic and growth-direction applied electric fields are theoretically investigated. The electronic structure, transition strengths and interband absorption coefficients are analyzed within the weak and strong magnetic-field regimes. A dramatic quenching of the absorption coefficient is observed, in the weak magnetic-field regime, as the applied electric field is increased, in good agreement with previous experimental measurements performed in a similar system under growth-direction applied electric fields. A decrease of the resonant tunneling in the superlattice is also theoretically obtained in the strong magnetic-field regime. Moreover, in this case, we found an interband absorption coefficient weakly dependent on the applied electric field. Present theoretical results suggest that an in-plane magnetic field may be used to tune the optical properties of variably spaced semiconductor superlattices, with possible future applications in solar cells and magneto-optical devices.

  15. Temperature-induced tuning of emission spectra of liquid-crystal optical microcavities

    Science.gov (United States)

    Zemánek, Pavel; Pilát, Zdeněk.; Ježek, Jan; Bernatová, Silvie; Aas, Mehdi; Kiraz, Alper; Jonáš, Alexandr

    2016-12-01

    Emulsion droplets of liquid crystals (LC) suspended in water and labeled with a suitable fluorescent dye can serve as active optofluidic microcavities, since the contrast of refractive index between the LC droplets and the surrounding aqueous medium allows excitation of whispering gallery modes (WGMs) in the droplets. In addition, such emulsion droplets can be also stably trapped in three-dimensions using optical tweezers which stabilizes the droplets while investigating their spectral characteristics. We explore various combinations of fluorescently dyed LC droplets and host liquid - surfactant systems and show that the WGM emission spectrum of an optically trapped LC droplet-based cavity can be largely and (almost) reversibly tuned by controlled changes of the ambient temperature that induce phase transitions in the LC droplets. Our results indicate feasibility of this approach for creating miniature tunable sources of coherent light.

  16. The effect of temperature and pressure on optical absorption spectra of transition zone minerals - Implications for the radiative conductivity of the Earth's interior

    Science.gov (United States)

    Thomas, S.; Jacobsen, S. D.; Bina, C. R.; Goncharov, A. F.; Frost, D. J.; McCammon, C. A.

    2010-12-01

    Optical absorption spectra of high-pressure minerals can be used as indirect tools to calculate radiative conductivities of the Earth’s interior [e.g., 1]. Recent high-pressure studies imply that e.g. ringwoodite, γ-(Mg,Fe)2SiO4, does not become opaque in the near infrared and visible region, as previously assumed, but remains transparent to 21.5 GPa [2]. Therefore, it has been concluded that radiative heat transfer does not necessarily become blocked at high pressures of the mantle and ferromagnesian minerals actually might contribute to the heat flow in the Earth’s interior [2]. However, experimental results on temperature effects on radiative heat transfer are not available. We studied the effect of both, pressure and temperature, on the optical absorption of hydrous Fe-bearing ringwoodite, γ-(Mg,Fe)2SiO4, and hydrous Fe-bearing wadsleyite, β-(Mg,Fe)2SiO4, which are the main components of the Earth’s transition zone. Gem-quality single-crystals were synthesized at 18 GPa and 1400 °C in a 5000t multianvil apparatus. Crystals were analyzed by Mössbauer and Raman spectroscopy, electron microprobe analysis and single-crystal X-ray diffraction. For optical absorption measurements in the IR - VIS - UV spectral range (400 - 50000 cm-1) 50 µm sized single-crystals of ringwoodite and wadsleyite were double polished to thicknesses of 13 µm and 18 µm, respectively, and loaded in resistively heated diamond-anvil cells with argon as pressure medium. After taking measurements at high pressure and room temperature, ringwoodite was studied at 26 GPa up to 650 °C and wadsleyite spectra were recorded at 16 GPa up to 450 °C. At ambient pressure the absorption spectrum of ringwoodite reveals a crystal field band (Fe2+) at 12075 cm-1, an intervalence charge transfer band (Fe2+ to Fe3+) at 16491 cm-1, and an absorption edge due to ligand-metal charge transfer close to 30000 cm-1. The wadsleyite spectrum is characterized by a similar absorption edge in the VIS-UV range

  17. Use of nondegenerate resonant leaky modes to fashion diverse optical spectra.

    Science.gov (United States)

    Ding, Y; Magnusson, Robert

    2004-05-03

    In this paper, we show that bandstop and bandpass filters with versatile spectral attributes can be implemented with modulated films possessing asymmetric grating profiles. The profile asymmetry breaks the resonant leaky mode degeneracy at normal incidence thereby permitting precise spectral spacing of interacting leaky modes with interesting implications in optical filter design. Several example filters, containing only a single grating layer, are designed with this methodology to demonstrate the concept.

  18. Design and performance of magnetic heads for magneto-optic recording with magnetic field modulation

    Science.gov (United States)

    Ruigrok, J. J. M.; Greidanus, F. J. A. M.; Godlieb, W. F.; Spruit, J. H. M.

    1988-04-01

    In magneto-optic recording, the most direct way to overwrite stored information is to switch the magnetization in a laser-heated region of the magneto-optic layer by means of an alternating magnetic field generated by a magnetic head. The heat dissipation in the head and the necessary voltage and current amplitude associated with fast switching, the desired high field, and a large head-to-medium distance make high demands upon the head design and the current source, respectively. Design criteria and numerical and experimental results for some circularly symmetric head configurations are presented.

  19. Further Indications of Jet Rotation in New Ultraviolet and Optical HST/STIS Spectra

    CERN Document Server

    Coffey, D; Ray, T P; Eislöffel, J; Woitas, J; Coffey, Deirdre; Bacciotti, Francesca; Ray, Thomas P.; Eisl\\"offel, Jochen; Woitas, Jens

    2007-01-01

    We present survey results which suggest rotation signatures at the base of T-Tauri jets. Observations were conducted with the Hubble Space Telescope Imaging Spectrograph at optical and near ultraviolet wavelengths (NUV). Results are presented for the approaching jet from DG Tau, CW Tau, HH 30 and the bipolar jet from TH 28. Systematic asymmetries in Doppler shift were detected across the jet, within 100 AU from the star. At optical wavelengths, radial velocity differences were typically 10 to 25 (+/-5) km/s, while differences in the NUV range were consistently lower at typically 10 (+/-5) km/s. Results are interpreted as possible rotation signatures. Importantly, there is agreement between the optical and NUV results for DG Tau. Under the assumption of steady magnetocentrifugal acceleration, the survey results lead to estimates for the distance of the jet footpoint from the star, and give values consistent with earlier studies. In the case of DG Tau, for example, we see that the higher velocity component appe...

  20. Early optical spectra of nova V1369 Cen show presence of Lithium

    CERN Document Server

    Izzo, L; Mason, E; Matteucci, F; Romano, D; Pasquini, L; Vanzi, L; Jordan, A; Fernandez, J M; Bluhm, P; Brahm, R; Espinoza, N; Williams, R

    2015-01-01

    We present early high resolution spectroscopic observations of the nova V1369 Cen. We have detected an absorption feature at 6695.6 \\AA\\, that we have identified as blue--shifted $^7$Li I $\\lambda$6708 \\AA. The absorption line, moving at -550 km/s, was observed in five high-resolution spectra of the nova obtained at different epochs. On the basis of the intensity of this absorption line we infer that a single nova outburst can inject in the Galaxy $M_{Li} =$ 0.3 - 4.8 $\\times 10^{-10}$ M$_{\\odot}$. Given the current estimates of Galactic nova rate, this amount is sufficient to explain the puzzling origin of the overabundance of Lithium observed in young star populations.

  1. Host galaxies of luminous quasars: population synthesis of optical off-axis spectra

    CERN Document Server

    Wold, I; Wolf, M J; Hooper, E J

    2010-01-01

    There is increasing evidence of a connection between AGN activity and galaxy evolution. To obtain further insight into this potentially important evolutionary phase, we analyse the properties of quasar host galaxies. In this paper, we present a population synthesis modeling technique for off-axis spectra, the results of which constrain host colour and the stellar ages of luminous quasars (M_V(nuc) 10^40 erg s^-1) quasars to be located in redder host galaxies in comparison to th eir less luminous radio counterparts. While the host colour and age of our radio luminous sample is in close proximity to the green valley, our radio faint sample is consistent with quiescent star-forming galaxies. However, further observations are needed to confirm these results. Finally, we discuss future applications for our technique on a larger sample of objects being obtained via SALT and WIYN telescope observing campaigns.

  2. Nonnegative matrix factorization: a blind spectra separation method for in vivo fluorescent optical imaging.

    Science.gov (United States)

    Montcuquet, Anne-Sophie; Hervé, Lionel; Navarro, Fabrice; Dinten, Jean-Marc; Mars, Jérôme I

    2010-01-01

    Fluorescence imaging in diffusive media is an emerging imaging modality for medical applications that uses injected fluorescent markers that bind to specific targets, e.g., carcinoma. The region of interest is illuminated with near-IR light and the emitted back fluorescence is analyzed to localize the fluorescence sources. To investigate a thick medium, as the fluorescence signal decreases with the light travel distance, any disturbing signal, such as biological tissues intrinsic fluorescence (called autofluorescence) is a limiting factor. Several specific markers may also be simultaneously injected to bind to different molecules, and one may want to isolate each specific fluorescent signal from the others. To remove the unwanted fluorescence contributions or separate different specific markers, a spectroscopic approach is explored. The nonnegative matrix factorization (NMF) is the blind positive source separation method we chose. We run an original regularized NMF algorithm we developed on experimental data, and successfully obtain separated in vivo fluorescence spectra.

  3. Excitations, optical absorption spectra, and optical excitonic gaps of heterofullerenes: I. C60, C59N+ and C48N12

    Energy Technology Data Exchange (ETDEWEB)

    Xie, R; Bryant, G W; Sun, G; C.Nicklaus, M; Heringer, D; Frauenheim, T; Manaa, M R; Smith, Jr., V H; Araki, Y; Ito, O

    2003-10-02

    Low-energy excitations and optical absorption spectrum of C{sub 60} are computed by using time-dependent (TD) Hartree-Fock (HF), TD-density functional theory (TD-DFT), TD-DFT-based tight-binding (TD-DFT-TB) and a semiempirical ZINDO method. A detailed comparison of experiment and theory for the excitation energies, optical gap and absorption spectrum of C{sub 60} is presented. It is found that electron correlations and collective effects of exciton pairs play important roles in assigning accurately the spectral features of C{sub 60} and the TD-DFT method with non-hybrid functionals or a local spin density approximation leads to more accurate excitation energies than with hybrid functionals. The level of agreement between theory and experiment for C{sub 60} justifies similar calculations of the excitations and optical absorption spectrum of a monomeric azafullerene cation C{sub 59}N{sup +} exhibits distinguishing spectral features different from C{sub 60}: (1) the first singlet is dipole-allowed and the optical gap is redshifted by 1.44 eV; (2) several weaker absorption maxima occur in the visible region; (3) the transient triplet-triplet absorption at 1.60 eV (775 nm) is much broader and the decay of the triplet state is much faster. The calculated spectra of C{sub 59}N{sup +} characterize and explain well our measured ultraviolet-visible (UV-vis) and transient absorption spectra of the carborane anion salt [C{sub 59}N][Ag(CB{sub 11}H{sub 6}Cl{sub 6}){sub 2}]. For the most stable isomer of C{sub 48}N{sub 12}, we predict that the first singlet is dipole-allowed, the optical gap is redshifted by 1.22 eV relative to that of C{sub 60}, and optical absorption maxima occur at 585, 528, 443, 363, 340, 314 and 303 nm. We point out that the characterization of the UV-vis and transient absorption spectra of C{sub 48}N{sub 12} isomers is helpful in distinguishing the isomer structures required for applications in molecular electronics. For C{sub 59}N{sup +} and C{sub 48}N

  4. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    CUI JinHua; XU ZhenFeng; ZHANG JiaLiang; NIE QiuYue; XU GenHui; REN LongLiang

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy.In this study,CH4+H2 dis-charge plasma was on-line diagnosed by optical emission spectra so as to char-acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas.The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure.The diagnostic method is easy,efficient and fairly precise.A serious er-ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  5. Optimized geometry, vibration (IR and Raman spectra and nonlinear optical activity of p-nitroanilinium perchlorate molecule: A theoretical study

    Directory of Open Access Journals (Sweden)

    Tamer Ömer

    2016-03-01

    Full Text Available The molecular modeling of p-nitroanilinium perchlorate molecule was carried out by using B3LYP and HSEH1PBE levels of density functional theory (DFT. The IR and Raman spectra were simulated and the assignments of vibrational modes were performed on the basis of relative contribution of various internal co-ordinates. NBO analysis was performed to demonstrate charge transfer, conjugative interactions and the formation of intramolecular hydrogen bonding interactions within PNAPC. Obtained large dipole moment values showed that PNAPC is a highly polarizable complex, and the charge transfer occurs within PNAPC. Hydrogen bonding and charge transfer interactions were also displayed by small HOMO-LUMO gap and molecular electrostatic potential (MEP surface. The strong evidences that the material can be used as an efficient nonlinear optical (NLO material of PNAPC were demonstrated by considerable polarizability and hyperpolarizability values obtained at DFT levels.

  6. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy. In this study, CH4+H2 dis- charge plasma was on-line diagnosed by optical emission spectra so as to char- acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas. The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure. The diagnostic method is easy, efficient and fairly precise. A serious er- ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  7. Optical diagnosis of cervical cancer by higher order spectra and boosting

    Science.gov (United States)

    Pratiher, Sawon; Mukhopadhyay, Sabyasachi; Barman, Ritwik; Pratiher, Souvik; Pradhan, Asima; Ghosh, Nirmalya; Panigrahi, Prasanta K.

    2017-03-01

    In this contribution, we report the application of higher order statistical moments using decision tree and ensemble based learning methodology for the development of diagnostic algorithms for optical diagnosis of cancer. The classification results were compared to those obtained with an independent feature extractors like linear discriminant analysis (LDA). The performance and efficacy of these methodology using higher order statistics as a classifier using boosting has higher specificity and sensitivity while being much faster as compared to other time-frequency domain based methods.

  8. All-optical tailoring of single-photon spectra in a quantum-dot microcavity system

    CERN Document Server

    Breddermann, Dominik; Binder, Rolf; Zrenner, Artur; Schumacher, Stefan

    2016-01-01

    Semiconductor quantum-dot cavity systems are promising sources for solid-state based on-demand generation of single photons for quantum communication. Commonly, the spectral characteristics of the emitted single photon are fixed by system properties such as electronic transition energies and spectral properties of the cavity. In the present work we study single-photon generation from the quantum-dot biexciton through a partly stimulated non-degenerate two-photon emission. We show that frequency and linewidth of the single photon can be fully controlled by the stimulating laser pulse, ultimately allowing for efficient all-optical spectral shaping of the single photon.

  9. Optical spectra of CdMnSe of nano-ferro- and antiferro-magnets.

    Science.gov (United States)

    Proshchenko, Vitaly; Dahnovsky, Yuri

    2015-10-28

    We study optical transitions in CdSe quantum dots doped by Mn atoms. At low concentrations the transitions are spin-forbidden. Nevertheless, strong light absorption was experimentally found. To explain this effect we propose a new mechanism that includes two or more Mn atoms closely placed to each other containing the electrons with opposite spin projections. In this case the spin-flip is unnecessary. In addition we study absorption from quantum dots containing two Mn atoms with different multiplicities. We find that the strongest absorption from the gap is for an antiferromagnetic arrangement. The obtained results confirm the experimental concentration dependencies.

  10. Using the Kramers-Kronig method to determine optical constants and evaluating its suitability as a linear transform for near-normal front-surface reflectance spectra.

    Science.gov (United States)

    Kocak, A; Berets, S L; Milosevic, V; Milosevic, M

    2006-09-01

    In this paper, the suitability of using the Kramers-Kronig transform to routinely extract optical constants from near-normal incidence reflectance spectra of solids and liquids is demonstrated. In addition, the possibility of utilizing the Kramers-Kronig transform as a linearizing transform for near-normal incidence reflectance spectra is investigated. Also, several commercial Kramers-Kronig software packages were utilized in determining the optical constants from the near-normal incidence reflectance of Plexiglas. Unexpectedly, the results produced by the various packages differed significantly. The near-normal reflectance of water was measured, the Kramers-Kronig transform was applied to extract the optical constants of water, and the result was compared to values found in the literature. Furthermore, the Kramers-Kronig transforms of near-normal incidence reflectance spectra of various concentrations of sugar in water were calculated to evaluate its use as a linearizing transform for quantitative applications.

  11. Multichannel decision feedback equalizer for high track density in optical recording

    Science.gov (United States)

    Gopalaswamy, Srinivasan; Kumar, B. V. K.

    1996-08-01

    A possible approach to high track density in optical recording is to reduce the track widths and eliminate the spacing between consecutive tracks. Parallel readback of several tracks and combined equalization of the multitrack readback signals is a viable approach toward reducing the deteriorating effects of interference in such a high-track- density system. Multichannel readback using laser diode arrays has been reported in optical recording. An additional advantage of multitrack readback is a high data rate. A novel multichannel decision feedback equalizer to reduce interference both within and across the tracks using 2D feedback is presented. Simulation results shows good improvement in error-rate performance by using multichannel decision feedback equalization. By this readback method, tracks can be brought closer, thus increasing the areal density.

  12. Stability Comparison of Recordable Optical Discs—A Study of Error Rates in Harsh Conditions

    Science.gov (United States)

    Slattery, Oliver; Lu, Richang; Zheng, Jian; Byers, Fred; Tang, Xiao

    2004-01-01

    The reliability and longevity of any storage medium is a key issue for archivists and preservationists as well as for the creators of important information. This is particularly true in the case of digital media such as DVD and CD where a sufficient number of errors may render the disc unreadable. This paper describes an initial stability study of commercially available recordable DVD and CD media using accelerated aging tests under conditions of increased temperature and humidity. The effect of prolonged exposure to direct light is also investigated and shown to have an effect on the error rates of the media. Initial results show that high quality optical media have very stable characteristics and may be suitable for long-term storage applications. However, results also indicate that significant differences exist in the stability of recordable optical media from different manufacturers. PMID:27366630

  13. The spectral temperature of optically thick outflows with application to light echo spectra from η Carinae's giant eruption

    Science.gov (United States)

    Owocki, Stanley P.; Shaviv, Nir J.

    2016-10-01

    The detection by Rest et al. of light echoes from η Carinae has provided important new observational constraints on the nature of its 1840s era giant eruption. Spectra of the echoes suggest a relatively cool spectral temperature of about 5500 K, lower than the lower limit of about 7000 K suggested in the optically thick wind-outflow analysis of Davidson. This has led to a debate about the viability of this steady wind model relative to alternative, explosive scenarios. Here we present an updated analysis of the wind-outflow model using newer low-temperature opacity tabulations and accounting for the stronger mass-loss implied by the >10 M⊙ mass now inferred for the Homunculus. A major conclusion is that, because of the sharp drop in opacity due to recombination loss of free electrons for T < 6500 K, a low temperature of about 5000 K is compatible with, and indeed expected from, a wind with the extreme mass-loss inferred for the eruption. Within a spherical grey model in radiative equilibrium, we derive spectral energy distributions for various assumptions for the opacity variation of the wind, providing a basis for comparisons with observed light echo spectra. The scaling results here are also potentially relevant for other highly optically thick outflows, including those from classical novae, giant eruptions of luminous blue variables and supernovae Type IIn precursors. A broader issue therefore remains whether the complex, variable features observed from such eruptions are better understood in terms of a steady or explosive paradigm, or perhaps a balance of these idealizations.

  14. Facile determination of the spectra of unstable electrode products using simultaneous fiber-optic chronoabsorptometry and chronoamperometry.

    Science.gov (United States)

    Shaw, Michael J; Cranford, Daniel L; Rodgers, Kenneth W; Eilers, James E; Noble, Bradley; Warhausen, Adam J; Richter-Addo, George B

    2010-10-18

    A widely applicable fiber-optic UV-vis method to determine the spectra of in situ generated redox products and intermediates at or near an electrode surface is described mathematically and implemented experimentally. The quantitative spectral information obtained gives extinction coefficients (absorptivities) as a function of wavelength, requires no arbitrary subtraction of the spectrum of the starting material, and is relatively insensitive to path length and concentration during the spectroelectrochemical measurements. We demonstrate proof-of-concept of this methodology by reproducing the expected spectrum of the ferrocenium ion from electrooxidation of ferrocene in MeCN, and by reproducing the spectrum that reveals π-radical cation formation from the electrooxidation of (T(p-OMe)PP)Co(NO) ((T(p-OMe)PP = 5,10,15,20-tetra(p-methoxyphenyl)porphyrinato dianion). Importantly, we demonstrate its use for the facile detection of unstable redox products not previously detected by current spectroelectrochemical methods. We obtain, for the first time, the experimental UV-vis spectrum of the short-lived fac-[(dppe)Mn(CO)(3)Br](+) cation, a hitherto uncharacterized intermediate that forms during the archetypal redox-induced fac-to-mer isomerization of (dppe)Mn(CO)(3)Br (dppe = diphenylphosphinoethane). Spectral features of the Mn-containing species have been verified by comparison to theoretical spectra calculated by time-dependent density functional theory methods.

  15. A Practical Deconvolution Computation Algorithm to Extract 1D Spectra from 2D Images of Optical Fiber Spectroscopy

    CERN Document Server

    Li, Guangwei; Bai, Zhongrui

    2015-01-01

    Bolton and Schlegel presented a promising deconvolution method to extract 1D spectra from a 2D optical fiber spectral CCD image. The method could eliminate the PSF difference between fibers, extract spectra to the photo noise level, as well as improve the resolution. But the method is limited by its huge computation requirement and thus cannot be implemented in actual data reduction. In this article, we develop a practical computation method to solve the computation problem. The new computation method can deconvolve a 2D fiber spectral image of any size with actual PSFs, which may vary with positions. Our method does not require large amounts of memory and can extract a 4k multi 4k noise-free CCD image with 250 fibers in 2 hr. To make our method more practical, we further consider the influence of noise, which is thought to be an intrinsic illposed problem in deconvolution algorithms. We modify our method with a Tikhonov regularization item to depress the method induced noise. Compared with the results of tra...

  16. Theoretical Studies on Electronic Spectra and Second-order Nonlinear Optical Properties of Barbituric Acid Derivatives Substituted with Schiff Base

    Institute of Scientific and Technical Information of China (English)

    SUN,Gang(孙刚); QIU,Yong-Qing(仇永清); SUN,Hai-Zhu(孙海珠); SU,Zhong-Min(苏忠民); FENG,Jing-Dong(冯静东); ZHU,Yu-Lan(朱玉兰)

    2004-01-01

    The structures of barbituric acid derivatives substituted with Schiff base were optimized using ab initio HF method at 6-31G basis set.Based on the optimized structures,the electronic spectra were obtained by INDO/CI method.The second-order nonlinear optical (NLO) coefficients βu were calculated according to the sum-over-states (SOS) formula.In addition,the effect of conjugation on electronic spectra and second-order NLO coefficients was investigated.The influence of exchange between C and N atoms as well as the substituted effect on the barbituric acid was discussed.It was indicated that the exchange between C and N atoms on Schiff base is important for enhancing the NLO coefficient of the whole molecule with donor and acceptor (D-A).Meanwhile significant changes in electron donation and acception were observed as substituents changes positions.Among the designed models,molecule 1b has maximal βμ value of 124.65 × 10-30 esu.About molecule 1b,barbituric acid is considered as an accepted electronic group and the position of N atom on Schiff base is close to it.

  17. Integrating seasonal optical and thermal infrared spectra to characterize urban impervious surfaces with extreme spectral complexity: a Shanghai case study

    Science.gov (United States)

    Wang, Wei; Yao, Xinfeng; Ji, Minhe

    2016-01-01

    Despite recent rapid advancement in remote sensing technology, accurate mapping of the urban landscape in China still faces a great challenge due to unusually high spectral complexity in many big cities. Much of this complication comes from severe spectral confusion of impervious surfaces with polluted water bodies and bright bare soils. This paper proposes a two-step land cover decomposition method, which combines optical and thermal spectra from different seasons to cope with the issue of urban spectral complexity. First, a linear spectral mixture analysis was employed to generate fraction images for three preliminary endmembers (high albedo, low albedo, and vegetation). Seasonal change analysis on land surface temperature induced from thermal infrared spectra and coarse component fractions obtained from the first step was then used to reduce the confusion between impervious surfaces and nonimpervious materials. This method was tested with two-date Landsat multispectral data in Shanghai, one of China's megacities. The results showed that the method was capable of consistently estimating impervious surfaces in highly complex urban environments with an accuracy of R2 greater than 0.70 and both root mean square error and mean average error less than 0.20 for all test sites. This strategy seemed very promising for landscape mapping of complex urban areas.

  18. Solvent-free optical recording of structural colours on pre-imprinted photocrosslinkable nanostructures

    Science.gov (United States)

    Jiang, Hao; Rezaei, Mohamad; Abdolahi, Mahssa; Kaminska, Bozena

    2017-09-01

    Optical digital information storage media, despite their ever-increasing storage capacity and data transfer rate, are vulnerable to the potential risk of turning inaccessible. For this reason, long-term eye-readable full-colour optical archival storage is in high demand for preserving valuable information from cultural, intellectual, and scholarly resources. However, the concurrent requirements in recording colours inexpensively and precisely, and preserving colours for the very long term (for at least 100 years), have not yet been met by existing storage techniques. Structural colours hold the promise to overcome such challenges. However, there is still the lack of an inexpensive, rapid, reliable, and solvent-free optical patterning technique for recording structural colours. In this paper, we introduce an enabling technique based on optical and thermal patterning of nanoimprinted SU-8 nanocone arrays. Using photocrosslinking and thermoplastic flow of SU-8, diffractive structural colours of nanocone arrays are recorded using ultra-violet (UV) exposure followed by the thermal development and reshaping of nanocones. Different thermal treatment procedures in reshaping nanocones are investigated and compared, and two-step progressive baking is found to allow the controllable reshaping of nanocones. The height of the nanocones and brightness of diffractive colours are modulated by varying the UV exposure dose to enable grey-scale patterning. An example of recorded full-colour image through half-tone patterning is also demonstrated. The presented technique requires only low-power continuous-wave UV light and is very promising to be adopted for professional and consumer archival storage applications.

  19. Laser Setup for Volume Diffractive Optical Elements Recording in Photo-Thermo-Refractive Glass

    Science.gov (United States)

    2016-04-14

    ADDRESS (ES) U.S. Army Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 UV laser , third harmonic generation, hologram recording...of uniformity of VBGs across the aperture that is a key for large aperture pulse compressors used in high power ultrashort pulse lasers . ? A new...the College of Optics and Photonics, University of Central Florida. 4304 Scorpius Str. Orlando, FL 32816 6. Key words: UV laser , third harmonic

  20. Temperature transformations of optical spectra in semiconductor flat heterostructures with quantum wells.

    Science.gov (United States)

    Kondryuk, D V; Derevyanchuk, A V; Kramar, V M

    2016-04-20

    The results of theoretical study of the temperature dependence of a long-wave range fundamental absorption edge in flat nanoheterostructures with a single quantum well (nanofilms) are adduced. The quantum well is assumed to be rectangular, of finite depth, and with unstrained heterojunctions as the nanofilm surface. Energies of electrons, holes, and excitons have been calculated within the framework of the effective mass model using the Green functions techniques, with account of their interaction with polar optical phonons confined within a quantum well. Numerical calculations are performed for nanofilms β-CdS/β-HgS/β-CdS and Al0.3Ga0.7As/GaAs/Al0.3Ga0.7As. It is shown that interaction with optical phonons causes a long-wave shift of the threshold frequency of the fundamental absorption band and a shift of exciton peaks by hundreds of Å for the first mentioned nanofilm and by dozens of Å for the second one, which is characterized by lower magnitudes of the constants of the electron-phonon coupling. The shift magnitude, as well as the height and half-width of the exciton absorption band, changes when the temperature exceeds 80 and 100 K, respectively.

  1. Chemically deposited Sb{sub 2}S{sub 3} thin films for optical recording

    Energy Technology Data Exchange (ETDEWEB)

    Shaji, S; Arato, A; Castillo, G Alan; Palma, M I Mendivil; Roy, T K Das; Krishnan, B [Facultad de IngenierIa Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon, C.P- 66450 (Mexico); O' Brien, J J; Liu, J, E-mail: bkrishnan@fime.uanl.m [Center for Nanoscience and Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One Univ. Blvd., St. Louis, MO - 63121 (United States)

    2010-02-24

    Laser induced changes in the properties of Sb{sub 2}S{sub 3} thin films prepared by chemical bath deposition are described in this paper. Sb{sub 2}S{sub 3} thin films of thickness 550 nm were deposited from a solution containing SbCl{sub 3} and Na{sub 2}S{sub 2}O{sub 3} at 27 {sup 0}C for 5 h. These thin films were irradiated by a 532 nm continuous wave laser beam under different conditions at ambient atmosphere. X-ray diffraction analysis showed amorphous to polycrystalline transformation due to laser exposure of these thin films. Morphology and composition of these films were described. Optical properties of these films before and after laser irradiation were analysed. The optical band gap of the material was decreased due to laser induced crystallization. The results obtained confirm that there is further scope for developing this material as an optical recording media.

  2. Single-intensity-recording optical encryption technique based on phase retrieval algorithm and QR code

    Science.gov (United States)

    Wang, Zhi-peng; Zhang, Shuai; Liu, Hong-zhao; Qin, Yi

    2014-12-01

    Based on phase retrieval algorithm and QR code, a new optical encryption technology that only needs to record one intensity distribution is proposed. In this encryption process, firstly, the QR code is generated from the information to be encrypted; and then the generated QR code is placed in the input plane of 4-f system to have a double random phase encryption. For only one intensity distribution in the output plane is recorded as the ciphertext, the encryption process is greatly simplified. In the decryption process, the corresponding QR code is retrieved using phase retrieval algorithm. A priori information about QR code is used as support constraint in the input plane, which helps solve the stagnation problem. The original information can be recovered without distortion by scanning the QR code. The encryption process can be implemented either optically or digitally, and the decryption process uses digital method. In addition, the security of the proposed optical encryption technology is analyzed. Theoretical analysis and computer simulations show that this optical encryption system is invulnerable to various attacks, and suitable for harsh transmission conditions.

  3. Analysis of the Early-Time Optical Spectra of SN 2011fe in M101

    CERN Document Server

    Parrent, J T; Friesen, B; Thomas, R C; Fesen, R A; Milisavljevic, D; Bianco, F B; Dilday, B; Nugent, P; Baron, E; Arcavi, I; Ben-Ami, S; Bersier, D; Bildsten, L; Bloom, J; Cao, Y; Cenko, S B; Filippenko, A V; Gal-Yam, A; Kasliwal, M M; Konidaris, N; Kulkarni, S R; Law, N M; Levitan, D; Maguire, K; Mazzali, P A; Ofek, E O; Pan, Y; Polishook, D; Poznanski, D; Quimby, R M; Silverman, J M; Sternberg, A; Sullivan, M; Walker, E S; Buton, C; Pereira, R

    2012-01-01

    The nearby Type Ia supernova SN 2011fe in M101 (cz=241 km s^-1) provides a unique opportunity to study the early evolution of a "normal" Type Ia supernova, its compositional structure, and its elusive progenitor system. We present 18 high signal-to-noise spectra of SN 2011fe during its first month beginning 1.2 days post-explosion and with an average cadence of 1.8 days. This gives a clear picture of how various line-forming species are distributed within the outer layers of the ejecta, including that of unburned material (C+O). We follow the evolution of C II absorption features until they diminish near maximum light, showing overlapping regions of burned and unburned material between ejection velocities of 10,000 and 16,000 km s^-1. This supports the notion that incomplete burning, in addition to progenitor scenarios, is a relevant source of spectroscopic diversity among SNe Ia. The observed evolution of the highly Doppler-shifted O I 7774 absorption features detected within five days post-explosion indicat...

  4. Quantitative Studies of the Optical and UV Spectra of Galactic Early B Supergiants

    Science.gov (United States)

    Searle, S. C.; Prinja, R. K.; Massa, D.; Ryans, R.

    2008-01-01

    We undertake an optical and ultraviolet spectroscopic analysis of a sample of 20 Galactic B0-B5 supergiants of luminosity classes Ia, Ib, Iab, and II. Fundamental stellar parameters are obtained from optical diagnostics and a critical comparison of the model predictions to observed UV spectral features is made. Methods. Fundamental parameters (e.g., T(sub eff), log L(sub *), mass-loss rates and CNO abundances) are derived for individual stars using CMFGEN, a nLTE, line-blanketed model atmosphere code. The impact of these newly derived parameters on the Galactic B supergiant Ten scale, mass discrepancy, and wind-momentum luminosity relation is examined. Results. The B supergiant temperature scale derived here shows a reduction of about 1000-3000 K compared to previous results using unblanketed codes. Mass-loss rate estimates are in good agreement with predicted theoretical values, and all of the 20 BO-B5 supergiants analysed show evidence of CNO processing. A mass discrepancy still exists between spectroscopic and evolutionary masses, with the largest discrepancy occuring at log (L/(solar)L approx. 5.4. The observed WLR values calculated for B0-B0.7 supergiants are higher than predicted values, whereas the reverse is true for B1-B5 supergiants. This means that the discrepancy between observed and theoretical values cannot be resolved by adopting clumped (i.e., lower) mass-loss rates as for O stars. The most surprising result is that, although CMFGEN succeeds in reproducing the optical stellar spectrum accurately, it fails to precisely reproduce key UV diagnostics, such as the N v and C IV P Cygni profiles. This problem arises because the models are not ionised enough and fail to reproduce the full extent of the observed absorption trough of the P Cygni profiles. Conclusions. Newly-derived fundamental parameters for early B supergiants are in good agreement with similar work in the field. The most significant discovery, however, is the failure of CMFGEN to predict

  5. Quantitative Studies of the Optical and UV Spectra of Galactic Early B Supergiants

    Science.gov (United States)

    Searle, S. C.; Prinja, R. K.; Massa, D.; Ryans, R.

    2008-01-01

    We undertake an optical and ultraviolet spectroscopic analysis of a sample of 20 Galactic B0-B5 supergiants of luminosity classes Ia, Ib, Iab, and II. Fundamental stellar parameters are obtained from optical diagnostics and a critical comparison of the model predictions to observed UV spectral features is made. Methods. Fundamental parameters (e.g., T(sub eff), log L(sub *), mass-loss rates and CNO abundances) are derived for individual stars using CMFGEN, a nLTE, line-blanketed model atmosphere code. The impact of these newly derived parameters on the Galactic B supergiant Ten scale, mass discrepancy, and wind-momentum luminosity relation is examined. Results. The B supergiant temperature scale derived here shows a reduction of about 1000-3000 K compared to previous results using unblanketed codes. Mass-loss rate estimates are in good agreement with predicted theoretical values, and all of the 20 BO-B5 supergiants analysed show evidence of CNO processing. A mass discrepancy still exists between spectroscopic and evolutionary masses, with the largest discrepancy occuring at log (L/(solar)L approx. 5.4. The observed WLR values calculated for B0-B0.7 supergiants are higher than predicted values, whereas the reverse is true for B1-B5 supergiants. This means that the discrepancy between observed and theoretical values cannot be resolved by adopting clumped (i.e., lower) mass-loss rates as for O stars. The most surprising result is that, although CMFGEN succeeds in reproducing the optical stellar spectrum accurately, it fails to precisely reproduce key UV diagnostics, such as the N v and C IV P Cygni profiles. This problem arises because the models are not ionised enough and fail to reproduce the full extent of the observed absorption trough of the P Cygni profiles. Conclusions. Newly-derived fundamental parameters for early B supergiants are in good agreement with similar work in the field. The most significant discovery, however, is the failure of CMFGEN to predict

  6. Optical to ultraviolet spectra of sandwiches of benzene and transition metal atoms: Time dependent density functional theory and many-body calculations

    DEFF Research Database (Denmark)

    Martinez, Jose Ignacio; García Lastra, Juan Maria; Lopez, M. J.

    2010-01-01

    The optical spectra of sandwich clusters formed by transition metal atoms (titanium, vanadium, and chromium) intercalated between parallel benzene molecules have been studied by time-dependent density functional theory (TDDFT) and many-body perturbation theory. Sandwiches with different number...... the optical properties according to specific functionality targets. The differences in the spectra could be used to identify relative abundances of isomers with different spins in experimental studies. As a salient feature, this theoretical spectroscopic analysis predicts the metallization of the infinite (Ti...

  7. Optical spectra of radio planetary nebulae in the small Magellanic cloud

    Directory of Open Access Journals (Sweden)

    Payne J.L.

    2008-01-01

    Full Text Available We present preliminary results from spectral observations of four (4 candidate radio sources co-identified with known planetary nebulae (PNe in the Small Magellanic Cloud (SMC. These were made using the Radcliffe 1.9-meter telescope in Sutherland, South Africa. These radio PNe were originally found in Australia Telescope Compact Array (ATCA surveys of the SMC at 1.42 and 2.37 GHz, and were further confirmed by new high resolution ATCA images at 6 and 3 cm (400 /200 . Optical PNe and radio candidates are within 200 and may represent a sub- population of selected radio bright objects. Nebular ionized masses of these objects may be 2.6 Mo or greater, supporting the existence of PNe progenitor central stars with masses up to 8 Mo.

  8. An analytical derivative procedure for the calculation of vibrational Raman optical activity spectra

    Science.gov (United States)

    Liégeois, Vincent; Ruud, Kenneth; Champagne, Benoît

    2007-11-01

    We present an analytical time-dependent Hartree-Fock algorithm for the calculation of the derivatives of the electric dipole-magnetic dipole polarizability with respect to atomic Cartesian coordinates. Combined with analogous procedures to determine the derivatives of the electric dipole-electric dipole and electric dipole-electric quadrupole polarizabilities, it enables a fully analytical evaluation of the three frequency-dependent vibrational Raman optical activity (VROA) invariants within the harmonic approximation. The procedure employs traditional non-London atomic orbitals, and the gauge-origin dependence of the VROA intensities has, therefore, been assessed for the commonly used aug-cc-pVDZ and rDPS:3-21G basis sets.

  9. Estimation of Purcell factor from mode-splitting spectra in an optical microcavity

    CERN Document Server

    Ozdemir, Sahin Kaya; He, Lina; Yang, Lan

    2011-01-01

    We investigate scattering process in an ultra-high-Q optical microcavity coupled to subwavelength scatterers by introducing "splitting quality" Qsp, a dimensionless parameter defined as the ratio of the scatterer-induced mode splitting to the total loss of the coupled system. A simple relation is introduced to directly estimate the Purcell factor from single-shot measurement of transmission spectrum of scatterer-coupled cavity. Experiments with polystyrene (PS) and gold (Au) nanoparticles, Erbium ions and Influenza A virions show that Purcell-factor-enhanced preferential funneling of scattering into the cavity mode takes place regardless of the scatterer type. Experimentally determined highest Qsp for single PS and Au nanoparticles are 9.4 and 16.19 corresponding to Purcell factors with lower bounds of 353 and 1049, respectively. The highest observed Qsp was 31.2 for an ensemble of Au particles. These values are the highest Qsp and Purcell factors reported up to date.

  10. Optical Spectra of Radio Planetary Nebulae in the Small Magellanic Cloud

    CERN Document Server

    Payne, J L; Crawford, E J; De Horta, A Y; White, G L; Stootman, F H

    2008-01-01

    We present preliminary results from spectral observations of four candidate radio sources co-identified with known planetary nebulae (PNe) in the Small Magellanic Cloud (SMC). These were made using the Radcliffe 1.9-meter telescope in Sutherland, South Africa. These radio PNe were originally found in Australia Telescope Compact Array (ATCA) surveys of the SMC at 1.42 and 2.37 GHz, and were further confirmed by new high resolution ATCA images at 6 and 3 cm (4"/2"). Optical PNe and radio candidates are within 2" and may represent a subpopulation of selected radio bright objects. Nebular ionized masses of these objects may be 2.6 MSol or greater, supporting the existence of PNe progenitor central stars with masses up to 8 MSol.

  11. Measurement of optical constants of Si and SiO2 from reflection electron energy loss spectra using factor analysis method

    Science.gov (United States)

    Jin, H.; Shinotsuka, H.; Yoshikawa, H.; Iwai, H.; Tanuma, S.; Tougaard, S.

    2010-04-01

    The energy loss functions (ELFs) and optical constants of Si and SiO2 were obtained from quantitative analysis of reflection electron energy loss spectroscopy (REELS) by a new approach. In order to obtain the ELF, which is directly related to the optical constants, we measured series of angular and energy dependent REELS spectra for Si and SiO2. The λ(E )K(ΔE) spectra, which are the product of the inelastic mean free path (IMFP) and the differential inverse IMFP, were obtained from the measured REELS spectra. We used the factor analysis (FA) method to analyze series of λ(E )K(ΔE) spectra for various emission angles at fixed primary beam energy to separate the surface-loss and bulk-loss components. The extracted bulk-loss components enable to obtain the ELFs of Si and SiO2, which are checked by oscillator strength-sum and perfect-screening-sum rules. The real part of the reciprocal of the complex dielectric function was determined by Kramers-Kronig analysis of the ELFs. Subsequently, the optical constants of Si and SiO2 were calculated. The resulting optical constants in terms of the refractive index and the extinction coefficient for Si and SiO2 are in good agreement with Palik's reference data. The results demonstrate the general applicability of FA as an efficient method to obtain the bulk ELF and to determine the optical properties from REELS measurements.

  12. Tracing Quasar Narrow-Line Regions Across Redshift: A Library of High S/N Optical Spectra

    CERN Document Server

    Tammour, A; Richards, G T

    2015-01-01

    In a single optical spectrum, the quasar narrow-line region (NLR) reveals low density, photoionized gas in the host galaxy interstellar medium, while the immediate vicinity of the central engine generates the accretion disk continuum and broad emission lines. To isolate these two components, we construct a library of high S/N optical composite spectra created from the Sloan Digital Sky Survey (SDSS-DR7). We divide the sample into bins of continuum luminosity and Hbeta FWHM that are used to construct median composites at different redshift steps up to 0.75. We measure the luminosities of the narrow-emission lines [NeV]3427, [NeIII]3870, [OIII]5007, and [OII]3728 with ionization potentials (IPs) of 97, 40, 35, and 13.6 eV respectively. The high IP lines' luminosities show no evidence of increase with redshift consistent with no evolution in the AGN SED or the host galaxy ISM illuminated by the continuum. In contrast, we find that the [OII] line becomes stronger at higher redshifts, and we interpret this as a co...

  13. On the complex structure of the optical spectra of a tetragonal calomel single crystal in a wide energy range

    Energy Technology Data Exchange (ETDEWEB)

    Sobolev, V. V., E-mail: sobolev@uni.udm.ru [Udmurt State University (Russian Federation); Sobolev, V. Val. [Izhevsk State Technical University (Russian Federation); Anisimov, D. V. [Udmurt State University (Russian Federation)

    2016-01-15

    The spectral complex of optical functions of the calomel Hg{sub 2}Cl{sub 2} single crystal is determined in the range 0–20 eV at 300 K in unpolarized light. The spectra of the imaginary part of the permittivity ε{sub 2}(E), the bulk–Imε{sup –1} and the surface–Im(1 + ε){sup –1} electron energy losses are decomposed into elementary bands. Their main parameters, including energies and oscillator strengths of the transition bands are determined. Calculations are performed on the basis of the experimental reflectance spectrum of the crystal cleavage. Computer programs based on Kramers–Kronig relations, analytical formulas, and the advanced parameterfree method of combined Argand diagrams are used. The main features of the spectral set of optical functions and the parameters of expansion band components ε{sub 2}(E),–Imε{sup –1}, and–Im(1 + ε){sup –1} are determined.

  14. Kramers-Kronig analysis of molecular evanescent-wave absorption spectra obtained by multimode step-index optical fibers.

    Science.gov (United States)

    Potyrailo, R A; Ruddy, V P; Hieftje, G M

    1996-07-20

    Spectral distortions that arise in evanescent-wave absorption spectra obtained with multimode step-index optical fibers are analyzed both theoretically and experimentally. Theoretical analysis is performed by the application of Kramers-Kronig relations to the real and the imaginary parts of the complex refractive index of an absorbing external medium. It is demonstrated that even when the extinction coefficient of the external medium is small, anomalous dispersion of that medium in the vicinity of an absorption band must be considered. Deviations from Beer's law, band distortions, and shifts in peak position are quantified theoretically as a function of the refractive index and the extinction coefficient of the external medium; the effect of bandwidth for both Lorentzian and Gaussian bands is also evaluated. Numerical simulations are performed for two types of sensing sections in commonly used plastic-clad silica optical fibers. These sensors include an unclad fiber in contact with a lower-index absorbing liquid and a fiber with the original cladding modified with an absorbing species. The numerical results compare favorably with those found experimentally with these types of sensing sections.

  15. Optical pathology using oral tissue fluorescence spectra: classification by principal component analysis and k-means nearest neighbor analysis.

    Science.gov (United States)

    Kamath, Sudha D; Mahato, K K

    2007-01-01

    The spectral analysis and classification for discrimination of pulsed laser-induced autofluorescence spectra of pathologically certified normal, premalignant, and malignant oral tissues recorded at a 325-nm excitation are carried out using MATLAB@R6-based principal component analysis (PCA) and k-means nearest neighbor (k-NN) analysis separately on the same set of spectral data. Six features such as mean, median, maximum intensity, energy, spectral residuals, and standard deviation are extracted from each spectrum of the 60 training samples (spectra) belonging to the normal, premalignant, and malignant groups and they are used to perform PCA on the reference database. Standard calibration models of normal, premalignant, and malignant samples are made using cluster analysis. We show that a feature vector of length 6 could be reduced to three components using the PCA technique. After performing PCA on the feature space, the first three principal component (PC) scores, which contain all the diagnostic information, are retained and the remaining scores containing only noise are discarded. The new feature space is thus constructed using three PC scores only and is used as input database for the k-NN classification. Using this transformed feature space, the centroids for normal, premalignant, and malignant samples are computed and the efficient classification for different classes of oral samples is achieved. A performance evaluation of k-NN classification results is made by calculating the statistical parameters specificity, sensitivity, and accuracy and they are found to be 100, 94.5, and 96.17%, respectively.

  16. Characterization of volume holographic optical elements recorded in Bayfol HX photopolymer for solar photovoltaic applications.

    Science.gov (United States)

    Marín-Sáez, Julia; Atencia, Jesús; Chemisana, Daniel; Collados, María-Victoria

    2016-03-21

    Volume Holographic Optical Elements (HOEs) present interesting characteristics for photovoltaic applications as they can select spectrum for concentrating the target bandwidth and avoiding non-desired wavelengths, which can cause the decrease of the performance on the cell, for instance by overheating it. Volume HOEs have been recorded on Bayfol HX photopolymer to test the suitability of this material for solar concentrating photovoltaic systems. The HOEs were recorded at 532 nm and provided a dynamic range, reaching close to 100% efficiency at 800 nm. The diffracted spectrum had a FWHM of 230 nm when illuminating at Bragg angle. These characteristics prove HOEs recorded on Bayfol HX photopolymer are suitable for concentrating solar light onto photovoltaic cells sensitive to that wavelength range.

  17. Magnetism, optical absorbance, and 19F NMR spectra of nafion films with self-assembling paramagnetic networks

    Energy Technology Data Exchange (ETDEWEB)

    Levin, E. M.; Chen, Q.; Bud' ko, S. L.

    2012-01-15

    Magnetization, optical absorbance, and {sup 19}F NMR spectra of Nafion transparent films as received and doped with Mn{sup 2+}, Co{sup 2+}, Fe{sup 2+}, and Fe{sup 3+} ions with and without treatment in 1H-1,2,4-triazole (trz) have been studied. Doping of Nafion with Fe{sup 2+} and Co{sup 2+} and their bridging to nitrogen of triazole yields a hybrid self-assembling paramagnetic system that exhibits interesting magnetic and optical properties. These include spin crossover phenomena between high-spin (HS) and low-spin (LS) states in Nafion-Fe{sup 2+}-trz and Nafion-Co{sup 2+}-trz accompanied by thermochromic effects in the visible range induced by temperature. A large shift of the magnetization curve induced by a magnetic field in the vicinity of the HS {leftrightarrow} LS, {approx}220 K, observed for Nafion-Fe{sup 2+}-trz has a rate of {approx}6 K/kOe, which is about three orders of magnitude larger than that in bulk spin crossover Fe{sup 2+} materials. Selective response of {sup 19}F NMR signals on doping with paramagnetic ions demonstrates that NMR can be used as spatially resolved method to study Nafion film with paramagnetic network. Both chemical shift and width of {sup 19}F NMR signals show that SO groups of Nafion, Fe or Co ions, and nitrogen of triazole are bonded whereas they form a spin crossover system. Based on a model of nanosize cylinders proposed for Nafion [K. Schmidt-Rohr and Q. Chen, Nat Mater (2008), 75], we suggest that paramagnetic ions are located inside these cylinders, forming self-assembling magnetically and optically active nanoscale networks.

  18. The optical jet of RW Aurigae: excitation temperature and ionization state from long-slit spectra.

    Science.gov (United States)

    Bacciotti, F.; Hirth, G. A.; Natta, A.

    1996-06-01

    The physical properties of the optical jet associated with the T Tauri star RW Aurigae are discussed. The excitation temperature, the hydrogen ionization fraction, the electron and gas densities are estimated in various positions along the flow axis using a diagnostic technique originally developed for the study of the physical conditions in highly collimated Herbig-Haro jets (Bacciotti, Chiuderi & Oliva 1995). The receding portion of the jet (red lobe) has an ionization fraction which is slowly decreasing from about 25% near the star to about 2% at a distance of 6-7" (~1000AU); the hydrogen density is roughly constant with a value of about 10^4^cm^-3^; the temperature shows a slight decline, with typical values of about 4500K. These results are consistent with the idea that the gas is initially ionized in the jet acceleration zone and that the physical conditions in the visible part of the jet are determined by time-dependent hydrogen recombination. It has not been possible to obtain any result for the blue lobe, due to the weakness of the [SII] 6716,6731A lines. The mass-loss and momentum rate in the flow (red lobe) are ˙(M)~5x10^-8^Msun_/yr and ˙(P)~6.5x10^-6^Msun_/yr.km/s.

  19. [Spectra modulated surface plasmon resonance sensor based on side polished multi-mode optical fiber].

    Science.gov (United States)

    Luo, Yun-Han; Chen, Xiao-Long; Xu, Meng-Yun; Ge, Jia; Zhang, Yi-Long; He, Yong-Hong; Tang, Jie-Yuan; Yu, Jian-Hui; Zhang, Jun; Chen, Zhe; Chen, Xing-Dan

    2014-03-01

    Surface plasmon resonance, which utilizes the resonance of optical evanescent wave with the metal surface plasmon wave, has been developed into a high sensitivity, rapid, label-less measurement method for chemical and biological analysis. In order to improve the spectral sensitivity in refractive index for a side polished fiber surface plasmon resonance sensor, the whole cladding layer and part of core of a multimode fiber was polished off. Additionally, an extra chrome layer with relatively high refractive index was coated on the polished zone before a gold film. The results showed that the sensor can measure the refractive index range from 1.333 to 1. 431 RIU, with the average spectral sensitivity of 4.11 x 10(3) nm RIU(-1), which is better than the reported results. Especially, in the refractive index range of 1. 417 1. 431 RIU, the sensitivity reaches to 1.09 x 10(4) nm RIU(-1). The minimum resolution of approximately 3.6 x 10(-5) RIU was estimated by a combination analysis with the sensor sensitivity and stability. The superiorities possessed by the proposed sensor in high sensitivity, wide detection range, small size and good stability and reproducibility, etc., make it a good candidate for food testing, environmental monitoring, biomedical testing and other related fields.

  20. Synthesis, crystal structure, vibrational spectra, optical properties and theoretical investigation of a two-dimensional self-assembled organic-inorganic hybrid material

    Science.gov (United States)

    Dammak, Hajer; Elleuch, Slim; Feki, Habib; Abid, Younes

    2016-11-01

    Organic-inorganic hybrid material of formula (C4H3SC2H4NH3)2[PbI4] was synthesized and studied by X-ray diffraction, Infrared absorption, Raman scattering, UV-Visible absorption and photoluminescence measurements. The molecule crystallizes as an organic-inorganic two-dimensional (2D) structure built up from infinite PbI6 octahedra surrounded by organic cations. Such a structure may be regarded as quantum wells system in which the inorganic layers act as semiconductor wells and the organic cations act as insulator barriers. Room temperature IR and Raman spectra were recorded in the 520-3500 and 10-3500 cm-1 frequency range, respectively. Optical absorption measurements performed on thin films of (C4H3SC2H4NH3)2[PbI4] revealed three distinct bands at 2.4, 2.66 and 3.25 eV. We also report DFT calculations of the electric dipole moments (μ), polarizability (α), the static first hyperpolarizability (β) and HOMO-LUMO analysis of the title compound investigated by GAUSSIAN 09 package. The calculated static first Hyperpolarizability is equal to 11.46 × 10-31 esu.

  1. First observation of natural circular dichroism spectra in the extreme ultraviolet region using a polarizing undulator-based optical system and its polarization characteristics.

    Science.gov (United States)

    Tanaka, Masahito; Yagi-Watanabe, Kazutoshi; Kaneko, Fusae; Nakagawa, Kazumichi

    2009-07-01

    Natural circular dichroism (CD) spectra in the extreme ultraviolet (EUV) region down to a wavelength of 80 nm have been observed for the first time, using an alanine thin film deposited on sodium salicylate coated glass as a sample. Calibrated EUV-CD spectra of L-alanine exhibited a large negative peak at around 120 nm and a positive CD signal below 90 nm, which were roughly predicted by theoretical calculations. A CD measurement system with an Onuki-type polarizing undulator was used to obtain the EUV-CD spectra. This CD system, the development of which took five years, can be used to observe even weak natural CD spectra. The polarization characteristics of this system were also evaluated in order to calibrate the recorded CD spectra.

  2. Development of an optical character recognition pipeline for handwritten form fields from an electronic health record.

    Science.gov (United States)

    Rasmussen, Luke V; Peissig, Peggy L; McCarty, Catherine A; Starren, Justin

    2012-06-01

    Although the penetration of electronic health records is increasing rapidly, much of the historical medical record is only available in handwritten notes and forms, which require labor-intensive, human chart abstraction for some clinical research. The few previous studies on automated extraction of data from these handwritten notes have focused on monolithic, custom-developed recognition systems or third-party systems that require proprietary forms. We present an optical character recognition processing pipeline, which leverages the capabilities of existing third-party optical character recognition engines, and provides the flexibility offered by a modular custom-developed system. The system was configured and run on a selected set of form fields extracted from a corpus of handwritten ophthalmology forms. The processing pipeline allowed multiple configurations to be run, with the optimal configuration consisting of the Nuance and LEADTOOLS engines running in parallel with a positive predictive value of 94.6% and a sensitivity of 13.5%. While limitations exist, preliminary experience from this project yielded insights on the generalizability and applicability of integrating multiple, inexpensive general-purpose third-party optical character recognition engines in a modular pipeline.

  3. Analysis of the near-resonant fluorescence spectra of a single rubidium atom localized in a three-dimensional optical lattice

    CERN Document Server

    Kim, Wookrae; Kim, Jung-Ryul; Lee, Yea-Lee; Ihm, Jisoon; An, Kyungwon

    2010-01-01

    Supplementary information is presented on the recent work by W. Kim et al. on the matter-wave-tunneling-induced broadening in the near-resonant spectra of a single rubidium atom localized in a three-dimensional optical lattice in a strong Lamb-Dicke regime.

  4. Optical recording of calcium currents during impulse conduction in cardiac tissue.

    Science.gov (United States)

    Jousset, Florian; Rohr, Stephan

    2015-04-01

    We explore the feasibility of obtaining a spatially resolved picture of [Formula: see text] inward currents ([Formula: see text]) in multicellular cardiac tissue by differentiating optically recorded [Formula: see text] transients that accompany propagating action potentials. Patterned growth strands of neonatal rat ventricular cardiomyocytes were stained with the [Formula: see text] indicators Fluo-4 or Fluo-4FF. Preparations were stimulated at 1 Hz, and [Formula: see text] transients were recorded with high spatiotemporal resolution ([Formula: see text], 2 kHz analog bandwidth) with a photodiode array. Signals were differentiated after appropriate digital filtering. Differentiation of [Formula: see text] transients resulted in optically recorded calcium currents (ORCCs) that carried the temporal and pharmacological signatures of L-type [Formula: see text] inward currents: the time to peak amounted to [Formula: see text] (Fluo-4FF) and [Formula: see text] (Fluo-4), full-width at half-maximum was [Formula: see text], and ORCCs were completely suppressed by [Formula: see text][Formula: see text]. Also, and as reported before from patch-clamp studies, caffeine reversibly depressed the amplitude of ORCCs. The results demonstrate that the differentiation of [Formula: see text] transients can be used to obtain a spatially resolved picture of the initial phase of [Formula: see text] in cardiac tissue and to assess relative changes of activation/fast inactivation of [Formula: see text] following pharmacological interventions.

  5. Electronic structure and magneto-optical Kerr effect spectra of ferromagnetic shape-memory Ni-Mn-Ga alloys: Experiment and density functional theory calculations

    Science.gov (United States)

    Uba, S.; Bonda, A.; Uba, L.; Bekenov, L. V.; Antonov, V. N.; Ernst, A.

    2016-08-01

    In this joint experimental and ab initio study, we focused on the influence of the chemical composition and martensite phase transition on the electronic, magnetic, optical, and magneto-optical properties of the ferromagnetic shape-memory Ni-Mn-Ga alloys. The polar magneto-optical Kerr effect (MOKE) spectra for the polycrystalline sample of the Ni-Mn-Ga alloy of Ni60Mn13Ga27 composition were measured by means of the polarization modulation method over the photon energy range 0.8 ≤h ν ≤5.8 eV in magnetic field up to 1.5 T. The optical properties (refractive index n and extinction coefficient k ) were measured directly by spectroscopic ellipsometry using the rotating analyzer method. To complement experiments, extensive first-principles calculations were made with two different first-principles approaches combining the advantages of a multiple scattering Green function method and a spin-polarized fully relativistic linear-muffin-tin-orbital method. The electronic, magnetic, and MO properties of Ni-Mn-Ga Heusler alloys were investigated for the cubic austenitic and modulated 7M-like incommensurate martensitic phases in the stoichiometric and off-stoichiometric compositions. The optical and MOKE properties of Ni-Mn-Ga systems are very sensitive to the deviation from the stoichiometry. It was shown that the ab initio calculations reproduce well experimental spectra and allow us to explain the microscopic origin of the Ni2MnGa optical and magneto-optical response in terms of interband transitions. The band-by-band decomposition of the Ni2MnGa MOKE spectra is presented and the interband transitions responsible for the prominent structures in the spectra are identified.

  6. Modeling of optical spectra of the light-harvesting CP29 antenna complex of photosystem II--part II.

    Science.gov (United States)

    Feng, Ximao; Kell, Adam; Pieper, Jörg; Jankowiak, Ryszard

    2013-06-01

    Until recently, it was believed that the CP29 protein from higher plant photosystem II (PSII) contains 8 chlorophylls (Chl's) per complex (Ahn et al. Science 2008, 320, 794-797; Bassi et al. Proc. Natl. Acad. Sci. U.S.A. 1999, 96, 10056-10061) in contrast to the 13 Chl's revealed by the recent X-ray structure (Pan et al. Nat. Struct. Mol. Biol. 2011, 18, 309-315). This disagreement presents a constraint on the interpretation of the underlying electronic structure of this complex. To shed more light on the interpretation of various experimental optical spectra discussed in the accompanying paper (part I, DOI 10.1021/jp4004328 ), we report here calculated low-temperature (5 K) absorption, fluorescence, hole-burned (HB), and 300 K circular dichroism (CD) spectra for CP29 complexes with a different number of pigments. We focus on excitonic structure and the nature of the low-energy state using modeling based on the X-ray structure of CP29 and Redfield theory. We show that the lowest energy state is mostly contributed to by a612, a611, and a615 Chl's. We suggest that in the previously studied CP29 complexes from spinach (Pieper et al. Photochem. Photobiol.2000, 71, 574-589) two Chl's could have been lost during the preparation/purification procedure, but it is unlikely that the spinach CP29 protein contains only eight Chl's, as suggested by the sequence homology-based study (Bassi et al. Proc. Natl. Acad. Sci. U.S.A.1999, 96, 10056-10061). The likely Chl's missing in wild-type (WT) CP29 complexes studied previously (Pieper et al. Photochem. Photobiol. 2000, 71, 574-589) include a615 and b607. This is why the nonresonant HB spectra shown in that reference were ~1 nm blue-shifted with the low-energy state mostly localized on about one Chl a (i.e., a612) molecule. Pigment composition of CP29 is discussed in the context of light-harvesting and excitation energy transfer.

  7. Simulations and analysis of the Raman scattering and differential Raman scattering/Raman optical activity (ROA) spectra of amino acids, peptides and proteins in aqueous solution

    DEFF Research Database (Denmark)

    Jalkanen, Karl J.; Nieminen, R. M.; Bohr, Jakob

    2000-01-01

    The Raman and Raman optical activity (ROA) spectra of amino acids and small peptides in aqueous solution have been simulated by density functional theory and restricted Hartree/Fock methods. The treatment of the aqueous environment in treated in two ways. The water molecules in the first hydration...... shell which strongly interact with the molecule are treated explicitly while the waters in the bulk are treated by a continuum model. The structures are optimized and the harmonic force elds are calculated. The derivatives needed to simulate the Raman and ROA intensities are calculated from first...... principles. The simulated Raman and ROA spectra have been compared to recently meassured spectra on amino acids and peptides. The simulations and understanding from them are used to interpret the Raman and ROA spectra of proteins. A comparison to vibrational absorption (VA) and vibrational circular dichroism...

  8. Quasi-ordering of composition fluctuations and their interaction with lattice imperfections in an optical spectra of dilute nitride alloys

    Science.gov (United States)

    Mintairov, A. M.; He, Y.; Merz, J. L.; Jin, Y.; Goldman, R. S.; Kudrawiec, R.; Misiewicz, J.; Akimov, I. A.; Yakovlev, D. R.; Bayer, M.

    2016-09-01

    Using optical spectroscopy experiments, including conventional low-temperature photo-reflectance and photoluminescence (PL) together with time-resolved PL and near-field magneto PL, we distinguish between statistical composition fluctuations (CFs) and nitrogen clusters (Ncl) in i- and n-type GaAs1-x N x alloys (x = 0.01-0.03). We measured the size (l = 3-24 nm), activation energy (E a = 15-30 meV) and density (n l ˜ 1011 cm-2) of CFs in i-type material. In n-type material we resolved the emission of nitrogen clusters (Ncl) having activation energy ˜70 meV and density n cl ˜ 1012 cm-2. Analysis of l and E a values in i-GaAs1-x N x revealed a strong interaction between substitutional (Ns) and interstitial (Ni) nitrogen, which results in band gap splitting accompanied by activation of the heavy-hole exciton and Ncl emission. In the optical spectra of i-GaAs1-x N x , we suggest the identification of different Ni species and Ni-Ns arrangements, and in n-GaAs1-x N x we observed activation/suppression of Ncl/CF emission and interference between CFs and ionized donors. Using numerical analysis of amplitude, size and density of CFs we revealed unexpected quasi-ordering which results in modulation of CFs having period 2l. This is consistent with the high n l values observed. We show that this quasi-ordering, arising from statistical non-uniformity of the CFs, creates a set of latent states, which allows us to probe exciton properties, defect density and the structural homogeneity in GaAs1-x N x .

  9. Feature extraction for magnetic domain images of magneto-optical recording films using gradient feature segmentation

    Science.gov (United States)

    Quanqing, Zhu; Xinsai, Wang; Xuecheng, Zou; Haihua, Li; Xiaofei, Yang

    2002-07-01

    In this paper, we present a method to realize feature extraction on low contrast magnetic domain images of magneto-optical recording films. The method is based on the following three steps: first, Lee-filtering method is adopted to realize pre-filtering and noise reduction; this is followed by gradient feature segmentation, which separates the object area from the background area; finally the common linking method is adopted and the characteristic parameters of magnetic domain are calculated. We describe these steps with particular emphasis on the gradient feature segmentation. The results show that this method has advantages over other traditional ones for feature extraction of low contrast images.

  10. Decision feedback equalization with multichannel readback in high-density optical recording

    Science.gov (United States)

    Gopalaswamy, Srinivasan; Vijaya Kumar, Bhagavatula

    1995-12-01

    Multi-channel readback using array heads has been reported in optical recording. A method to reduce both interference along and across the tracks using multi-channel readback is presented. In this method, the non-linear multi-channel decision feedback equalization is used to remove both forms of interference. Simulation results show good improvement (in performance) by using the multi-channel equalization. By this readback method, tracks can be brought closer, thus increasing the areal density. Another advantage of this method is the high data rate possible.

  11. Optical gain spectra of unstrained graded GaAs/Al{sub x}Ga{sub 1−x}As quantum well laser

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, E.L. [Departamento de Biofísica e Farmacologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Fulco, U.L., E-mail: umbertofulco@gmail.com [Departamento de Biofísica e Farmacologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Vasconcelos, M.S. [Escola de Ciências e Tecnologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Mauriz, P.W. [Departamento de Física, Instituto Federal de Educação, Ciência e Tecnologia do Maranhão, 65020-300 São Luís, MA (Brazil)

    2013-02-15

    We have calculated the optical gain spectra in unstrained graded GaAs/Al{sub x}Ga{sub 1−x}As single quantum well lasers as a function of the energy of the radiation, the quantum well width and the interface thickness. The optical gain spectra were calculated using the density matrix approach (Luttinger–Kohn method), considering the parabolic band model (conduction band), all subband mixing between the heavy and light holes (valence band), and the transversal electrical light polarization. Our results show that the optical peak gain is sensitive to the width and the graded profile of the interfaces, and is blue-shifted as a function of the interface width.

  12. Land/groove optical recording with GeTe/Sb2Te3 superlattice-like structure

    Institute of Scientific and Technical Information of China (English)

    Wei Qiang(墙威); Luping Shi; Towchong Chong; Yang Cao(曹阳)

    2004-01-01

    A superlattice-like (SLL) structure was applied to phase-change optical recording. The recording layer consisting of alternating thin layers of two different phase-change materials, GeTe and Sb2Tes, were grown by magnetron sputtering on polycarbonate substrates. Land/groove optical recording was adopted to suppress crosstalk and obtain a large track density. Dynamic properties of the SLL disc were investigated with the shortest 1T pulse duration of 8 ns. Clear eye pattern was observed after 10000 direct overwrite cycles. Erasability above 20 dB was achieved at a constant linear velocity of 19 m/s. Carrier-noise ratio (CNR) kept above 46 dB when the recording frequency reaches 21 MHz. The SLL phase change optical disc demonstrates a better recording performance than the Ge1Sb2Te4 and Ge1Sb4Te7 discs in terms of CNR, erasability, and overwrite jitter.

  13. The Spectral Temperature of Optically Thick Outflows with Application to Light Echo Spectra from $\\eta$~Carinae's Giant Eruption

    CERN Document Server

    Owocki, Stanley P

    2016-01-01

    The detection by Rest et al. (2012) of light echoes from $\\eta$ Carinae has provided important new observational constraints on the nature of its 1840's era giant eruption. Spectra of the echoes suggest a relatively cool spectral temperature of about 5500K, lower than the lower limit of about 7000K suggested in the optically thick wind outflow analysis of Davidson (1987). This has lead to a debate about the viability of this steady wind model relative to alternative, explosive scenarios. Here we present an updated analysis of the wind outflow model using newer low-temperature opacity tabulations and accounting for the stronger mass loss implied by the $>$10 Msun mass now inferred for the Homunculus. A major conclusion is that, because of the sharp drop in opacity due to free electron recombination for $T<$6500K, a low temperature of about 5000K is compatible with, and indeed expected from, a wind with the extreme mass loss inferred for the eruption. Within a spherical gray model in radiative equilibrium, w...

  14. An optical study of amorphous (Se{sub 80}Te{sub 20}){sub 100-x}Ge{sub x} thin films using their transmission spectra

    Energy Technology Data Exchange (ETDEWEB)

    Mainika; Thakur, Nagesh [Department of Physics, H P University, Summer Hill Shimla, HP-171005 (India); Sharma, Pankaj; Katyal, S C [Department of Physics, Jaypee University of Information Technology, Waknaghat-173215 (India)], E-mail: mainika_phy@rediffmail.com, E-mail: pankaj.sharma@juit.ac.in

    2008-12-07

    Optical constants (refractive index and extinction coefficient) have been studied for a-(Se{sub 80}Te{sub 20}){sub 100-x}Ge{sub x} (x = 0, 2, 4, 6) thin films using transmission spectra in the wavelength range 500-2500 nm. It is observed from optical transmission measurements that the optical energy gap (E{sub g}) increases while the refractive index (n) and the extinction coefficient (k) decrease with the incorporation of Ge in the Se-Te system. The increase in the optical energy gap is interpreted by correlating the optical energy gap with the decrease in electronegativity and increase in the heat of atomization (H{sub s}). The dispersion of the refractive index is discussed in terms of the single-oscillator Wemple-DiDomenico model.

  15. Experiments on the data recording of optical waveguide multilayer storage devices

    Science.gov (United States)

    Liang, Zhongcheng; Ding, Dongyan; Xie, Haiyan; Gu, Minfen; Chen, Jiabi; Zhuang, Songlin

    2005-12-01

    The basic principles of optical waveguide multilayer storage (WMS) device include recording data in the form of waveguide defects, reading data by collecting the scatter light from the waveguide defects, and restraining the cross talk between layers by taking the benefit of the waveguide structure. In this paper, we give some experimental results obtained by three different approaches of data recording. They are laser direct writing, photolithography and hot embossing. In the first method, a laser beam is focused on the top of a polymer film. The thermal effect alters the medium property locally at the focus point, which acts as the defect in the waveguide structure. The second method resorts to the processes of photolithography to record pits on the photoresist layer. The process of hot embossing is similar to the fabrication of CD-ROM, however, the data pits deeper than the wavelength are embossed on the polymer surface to increase the scattering efficiency. WMS devices based on different data writing methods are presented and the data scattering patterns are observed. The comparison between the different data writing approaches is made and discussed as well.

  16. Signatures of the non-Maxwellian $\\kappa$-distributions in optically thin line spectra \\subtitle{I. Theory and synthetic Fe IX--XIII spectra}

    CERN Document Server

    Dudík, J; Mason, H E; Dzifčáková, E

    2014-01-01

    We investigate the possibility of diagnosing the degree of departure from the Maxwellian distribution using single-ion spectra originating in astrophysical plasmas in collisional ionization equilibrium. New atomic data for excitation of Fe IX-XIII are integrated under the assumption of a kappa-distribution of electron energies. Diagnostic methods using lines of a single ion formed at any wavelength are explored. Such methods minimize uncertainties from the ionization and recombination rates, as well as the possible presence of non-equilibrium ionization. Approximations to the collision strengths are also investigated. The calculated intensities of most of the Fe IX-XIII EUV lines show consistent behaviour with kappa at constant temperature. Intensities of these lines decrease with kappa, with the vast majority of ratios of strong lines showing little or no sensitivity to kappa. Several of the line ratios, especially involving temperature-sensitive lines, show a sensitivity to kappa that is of the order of sev...

  17. Extraction of compositional and hydration information of sulfates from laser-induced plasma spectra recorded under Mars atmospheric conditions - Implications for ChemCam investigations on Curiosity rover

    Energy Technology Data Exchange (ETDEWEB)

    Sobron, Pablo, E-mail: pablo.sobron@asc-csa.gc.ca [Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, St. Louis, MO 63130 (United States); Wang, Alian [Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, St. Louis, MO 63130 (United States); Sobron, Francisco [Unidad Asociada UVa-CSIC a traves del Centro de Astrobiologia, Parque Tecnologico de Boecillo, Parcela 203, Boecillo (Valladolid), 47151 (Spain)

    2012-02-15

    Given the volume of spectral data required for providing accurate compositional information and thereby insight in mineralogy and petrology from laser-induced breakdown spectroscopy (LIBS) measurements, fast data processing tools are a must. This is particularly true during the tactical operations of rover-based planetary exploration missions such as the Mars Science Laboratory rover, Curiosity, which will carry a remote LIBS spectrometer in its science payload. We have developed: an automated fast pre-processing sequence of algorithms for converting a series of LIBS spectra (typically 125) recorded from a single target into a reliable SNR-enhanced spectrum; a dedicated routine to quantify its spectral features; and a set of calibration curves using standard hydrous and multi-cation sulfates. These calibration curves allow deriving the elemental compositions and the degrees of hydration of various hydrous sulfates, one of the two major types of secondary minerals found on Mars. Our quantitative tools are built upon calibration-curve modeling, through the correlation of the elemental concentrations and the peak areas of the atomic emission lines observed in the LIBS spectra of standard samples. At present, we can derive the elemental concentrations of K, Na, Ca, Mg, Fe, Al, S, O, and H in sulfates, as well as the hydration degrees of Ca- and Mg-sulfates, from LIBS spectra obtained in both Earth atmosphere and Mars atmospheric conditions in a Planetary Environment and Analysis Chamber (PEACh). In addition, structural information can be potentially obtained for various Fe-sulfates. - Highlights: Black-Right-Pointing-Pointer Routines for LIBS spectral data fast automated processing. Black-Right-Pointing-Pointer Identification of elements and determination of the elemental composition. Black-Right-Pointing-Pointer Calibration curves for sulfate samples in Earth and Mars atmospheric conditions. Black-Right-Pointing-Pointer Fe curves probably related to the crystalline

  18. Vibrational analysis of various irotopes of L-alanyl-L-alanine in aqueous solution: Vibrational Absorption (VA), Vibrational Circular Dichroism (VCD), Raman and Raman Optical Activity (ROA) Spectra

    DEFF Research Database (Denmark)

    Jalkanen, Karl J.; Nieminen, R.M.; Knapp-Mohammady, M.

    2003-01-01

    In a recent work (Knapp-Mohammady, M.; Jalkanen, K. J.; Nardi, F.; Wade, R. C.; Suhai, S. Chem Phys 1999, 240, 63-77) the structures of the zwitterionic species Of L-alanyI-L-alanine (LALA) in aqueous solution using a combination of molecular mechanics (MM) and density functional theory (DFT) have...... been reported. Subsequently, the vibrational absorption (VA) and vibrational circular dichroism (VCD) and the Raman and Raman Optical Activity (ROA) spectra have been reported. In this work an analysis of the aqueous solution VA, VCD, Raman, and ROA spectra for various isotopomers of LALA are reported...... pattern could be reproduced with the DIFT atomic axial tensors calculated for the LALA plus explicit water molecules. The continuum treatment of the solvent for the calculation of these tensors appeirs to be a secondary effect. The ROA spectra are not well reproduced due to the failure to take...

  19. Reconstruction of long-term aerosol optical depth series with sunshine duration records

    Science.gov (United States)

    Sanchez-Romero, A.; Sanchez-Lorenzo, A.; González, J. A.; Calbó, J.

    2016-02-01

    We report the suitability of sunshine duration (SD) records as a proxy for the reconstruction of atmospheric aerosol content, for which little information exists, especially prior to the 1980s. Specifically, we have treated cloudless summer days in 16 stations throughout Spain. For almost all sites we find statistically significant relationships between aerosol optical depth (AOD) and daily SD. The correlation coefficient presents a mean value of -0.72, and slope values of the linear regressions are within the range [-0.11, -0.36]. The relationships are used to generate AOD series back to the 1960s (to the 1920s for Madrid). These reconstructed series show an increase in AOD from the mid-1960s to the 1980s, followed by a decrease until the present, in agreement with changes in anthropogenic aerosol emissions and with opposite trends of solar irradiance. The method can be used to reconstruct AOD from the late nineteenth century at many stations worldwide.

  20. Optical recording-guided pacing to create functional line of block during ventricular fibrillation

    Science.gov (United States)

    Ravi, Krishna; Nihei, Motoki; Willmer, Anjuli; Hayashi, Hideki; Lin, Shien-Fong

    2006-03-01

    Low-energy defibrillation is very desirable in cardiac rhythm management. We previously reported that ventricular fibrillation (VF) can be synchronized with a novel synchronized pacing technique (SyncP) using low-energy pacing pulses. This study sought to create a line of block during VF using SyncP. SyncP was performed in six isolated rabbit hearts during VF using optical recording to control the delivery of pacing pulses in real time. Four pacing electrodes with interelectrode distances of 5 mm were configured in a line along and across the myocardial fiber direction. The electrodes were controlled independently (independent mode) or fired together (simultaneous mode). Significant wavefront synchronization was observed along the electrode line as indicated by a decrease in variance. With the independent SyncP protocol, the decrease in the variance was 19.3 and 13.7% (Pventricular defibrillation.

  1. Thermal Analysis of Heat-Assisted Magnetic Recording Optical Head with Laser Diode on Slider

    Science.gov (United States)

    Xu, Baoxi; Chia, Cheow Wee; Zhang, Qide; Teck Toh, Yeow; An, Chengwu; Vienne, Guillaume

    2011-09-01

    For the optical head used in heat-assisted magnetic recording (HAMR), mounting a laser diode chip on the slider offers a more integrated, compact, and stable design. However, the heat generated by the laser diode will cause the head temperature to increase, which may decrease the laser output power and change the slider flying status. In this paper, the thermal analysis of the HAMR head including the laser diode and a transducer is conducted. The effects of the laser diode power, the power absorbed by the transducer, boundary thermal resistance between the laser diode chip and the slider substrate, and slider fly speed and fly height on the laser temperature increase, the transducer temperature increase, and the air-bearing surface temperature distribution are studied. The deformation of the air-bearing surface caused by its temperature change is also analyzed.

  2. Optical spectra and local structure of Eu3+ ions doped in Nb2O5-La2O3-B2O3-BaO glasses

    Institute of Scientific and Technical Information of China (English)

    Haiping Xia; Jianli Zhang; Jinhao Wang; Yuepin Zhang

    2006-01-01

    @@ The xNb2O5-(15-x)La2O3-40B2O3-45BaO (x = 5, 7.5, 12.5 mol%) glasses doped with Eu3+ ions in 1mol% are fabricated by the melting method. The Fourier transform infrared (FTIR) spectra, phonon sideband spectra, emission and excitation spectra of the glasses are measured. The crystal field parameter and coordination number of Eu3+ ions in the glasses are obtained according to the splitting of their 5D0 - 7F1levels. The intensity parameters Ω2 and Ω4 of Eu3+ ions for optical transition are calculated from their emission spectra in terms of reduced matrix U(t) (λ= 2,4,6) character for optical transitions. The results indicate that the intensity parameters Ω2 and Ω4 increase with the increase of Nb2O5 content, suggesting that the symmetry becomes lower, the band of Eu and O atoms becomes stronger and the covalence increases with the increase of Nb2O5 content.

  3. Quantitative analysis of reflection electron energy loss spectra to determine electronic and optical properties of Fe–Ni alloy thin films

    Energy Technology Data Exchange (ETDEWEB)

    Tahir, Dahlang, E-mail: dtahir@fmipa.unhas.ac.id [Department of Physics, Hasanuddin University, Makassar 90245 (Indonesia); Oh, Sukh Kun [Department of Physics, Chungbuk National University, Cheongju 362-763 (Korea, Republic of); Kang, Hee Jae, E-mail: hjkang@cbu.ac.kr [Department of Physics, Chungbuk National University, Cheongju 362-763 (Korea, Republic of); Tougaard, Sven, E-mail: svt@sdu.dk [Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Odense M, Odense DK-5230 (Denmark)

    2016-01-15

    Highlights: • Electronic and optical properties of Fe-Ni alloy thin films grown on Si (1 0 0) were studied via quantitative analyses of reflection electron energy loss spectra (REELS). • The energy loss functions (ELF) are dominated by a plasmon peak at 23.6 eV for Fe and moves gradually to lower energies in Fe-Ni alloys towards the bulk plasmon energy of Ni at 20.5 eV. • Fe has a strong effect on the dielectric and optical properties of Fe-Ni alloy thin films even for an alloy with 72% Ni. Electronic and optical properties of Fe-Ni alloy thin films grown on Si (1 0 0) were studied via quantitative analyses of reflection electron energy loss spectra (REELS). - Abstract: Electronic and optical properties of Fe–Ni alloy thin films grown on Si (1 0 0) by ion beam sputter deposition were studied via quantitative analyses of reflection electron energy loss spectra (REELS). The analysis was carried out by using the QUASES-XS-REELS and QUEELS-ε(k,ω)-REELS softwares to determine the energy loss function (ELF) and the dielectric functions and optical properties by analyzing the experimental spectra. For Ni, the ELF shows peaks around 3.6, 7.5, 11.7, 20.5, 27.5, 67 and 78 eV. The peak positions of the ELF for Fe{sub 28}Ni{sub 72} are similar to those of Fe{sub 51}Ni{sub 49}, even though there is a small peak shift from 18.5 eV for Fe{sub 51}Ni{sub 49} to 18.7 eV for Fe{sub 28}Ni{sub 72}. A plot of n, k, ε{sub 1}, and ε{sub 2} shows that the QUEELS-ε(k,ω)-REELS software for analysis of REELS spectra is useful for the study of optical properties of transition metal alloys. For Fe–Ni alloy with high Ni concentration (Fe{sub 28}Ni{sub 72}), ε{sub 1}, and ε{sub 2} have strong similarities with those of Fe. This indicates that the presence of Fe in the Fe–Ni alloy thin films has a strong effect.

  4. Refractometry of melanocyte cell nuclei using optical scatter images recorded by digital Fourier microscopy.

    Science.gov (United States)

    Seet, Katrina Y T; Nieminen, Timo A; Zvyagin, Andrei V

    2009-01-01

    The cell nucleus is the dominant optical scatterer in the cell. Neoplastic cells are characterized by cell nucleus polymorphism and polychromism-i.e., the nuclei exhibits an increase in the distribution of both size and refractive index. The relative size parameter, and its distribution, is proportional to the product of the nucleus size and its relative refractive index and is a useful discriminant between normal and abnormal (cancerous) cells. We demonstrate a recently introduced holographic technique, digital Fourier microscopy (DFM), to provide a sensitive measure of this relative size parameter. Fourier holograms were recorded and optical scatter of individual scatterers were extracted and modeled with Mie theory to determine the relative size parameter. The relative size parameter of individual melanocyte cell nuclei were found to be 16.5+/-0.2, which gives a cell nucleus refractive index of 1.38+/-0.01 and is in good agreement with previously reported data. The relative size parameters of individual malignant melanocyte cell nuclei are expected to be greater than 16.5.

  5. Assessment of 10 Year Record of Aerosol Optical Depth from OMI UV Observations

    Science.gov (United States)

    Ahn, Changwoo; Torres, Omar; Jethva, Hiren

    2014-01-01

    The Ozone Monitoring Instrument (OMI) onboard the EOS-Aura satellite provides information on aerosol optical properties by making use of the large sensitivity to aerosol absorption in the near-ultraviolet (UV) spectral region. Another important advantage of using near UV observations for aerosol characterization is the low surface albedo of all terrestrial surfaces in this spectral region that reduces retrieval errors associated with land surface reflectance characterization. In spite of the 13 × 24 square kilometers coarse sensor footprint, the OMI near UV aerosol algorithm (OMAERUV) retrieves aerosol optical depth (AOD) and single-scattering albedo under cloud-free conditions from radiance measurements at 354 and 388 nanometers. We present validation results of OMI AOD against space and time collocated Aerosol Robotic Network measured AOD values over multiple stations representing major aerosol episodes and regimes. OMAERUV's performance is also evaluated with respect to those of the Aqua-MODIS Deep Blue and Terra-MISR AOD algorithms over arid and semi-arid regions in Northern Africa. The outcome of the evaluation analysis indicates that in spite of the "row anomaly" problem, affecting the sensor since mid-2007, the long-term aerosol record shows remarkable sensor stability.

  6. Synthesis, photochromism and holographic optical recording of a novel diarylethene bearing a pyrrole unit

    Science.gov (United States)

    Liu, Gang; Liu, Ming; Pu, Shouzhi; Fan, Congbin

    2011-02-01

    A unsymmetrical photochromic diarylethene, 1-[2-methyl-5-(3-fluorophenyl)-3-thienyl]-2 -(2-cyano-1,5-dimethyl-4-pyrryl)hexafluorocyclopentene (1o), was synthesized. The photoconversion ratios from open-ring to closed-ring isomers at photostationary state under UV irradiation in hexane solution was measured by HPLC, and the properties, including photochromism and fluorescence properties were also investigated systematically. The results showed that this compound had good thermal stability and exhibited reversible photochromism, changing from colorless to blue after irradiation with UV light both in solution and in PMMA amorphous film. The open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 427 nm in hexane solution (5×10-5 mol/L) when excited at 340 nm. The fluorescence intensity decreased along with the photochromism upon irradiation with 297 nm light and its closed-ring isomer showed almost no fluorescence. Using diarylethene 1 as recording medium, polarization holographic optical recording was carried out successfully.

  7. Synthesis, photochromism and holographic optical recording of a novel diarylethene bearing a pyrrole unit

    Energy Technology Data Exchange (ETDEWEB)

    Liu Gang; Liu Ming; Pu Shouzhi; Fan Congbin, E-mail: pushouzhi@tsinghua.org.cn [Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013 (China)

    2011-02-01

    A unsymmetrical photochromic diarylethene, 1-[2-methyl-5-(3-fluorophenyl)-3-thienyl]-2 -(2-cyano-1,5-dimethyl-4-pyrryl)hexafluorocyclopentene (1o), was synthesized. The photoconversion ratios from open-ring to closed-ring isomers at photostationary state under UV irradiation in hexane solution was measured by HPLC, and the properties, including photochromism and fluorescence properties were also investigated systematically. The results showed that this compound had good thermal stability and exhibited reversible photochromism, changing from colorless to blue after irradiation with UV light both in solution and in PMMA amorphous film. The open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 427 nm in hexane solution (5x10{sup -5} mol/L) when excited at 340 nm. The fluorescence intensity decreased along with the photochromism upon irradiation with 297 nm light and its closed-ring isomer showed almost no fluorescence. Using diarylethene 1 as recording medium, polarization holographic optical recording was carried out successfully.

  8. Negative hemodynamic response without neuronal inhibition investigated by combining optical imaging and electrophysiological recording.

    Science.gov (United States)

    Ma, Zengguang; Cao, Pengjia; Sun, Pengcheng; Lu, Zhuofan; Li, Liming; Chen, Yao; Chai, Xinyu

    2017-01-10

    Understanding the mechanisms underlying negative hemodynamic responses is critical for the interpretation of functional brain imaging signals. Negative imaging signals have been found in the visual, somatosensory and motor cortices in functional magnetic resonance imaging (fMRI) and intrinsic signal optical imaging (ISOI) studies. However, the origin of negative imaging signals is still controversial. The present study investigated the visual cortical responses to peripheral grating stimuli using multi-wavelength ISOI and electrophysiological recording. We found an increased cerebral blood volume (CBV) in the stimulus-induced regions and a decreased CBV in the adjacent regions in the visual cortex. Nevertheless, there was no significant change in blood oxygenation in the negative CBV regions. Furthermore, by combining the planar and laminar electrophysiological recordings, we did not observe significantly decreased neuronal activity in the negative CBV regions. Our results suggest that the negative hemodynamic response does not necessarily originate in decreased neuronal activity. Therefore, caution should be taken when interpreting a negative hemodynamic response as neuronal inhibition.

  9. Improving Recording Density of All-Optical Magnetic Storage by Using High-Pass Angular Spectrum Filters

    Institute of Scientific and Technical Information of China (English)

    ZHUANG You-Yi; ZHANG Yao-Ju

    2009-01-01

    A new design is presented to improve the magnetic recording density in all-optical magnetic storage.By using the high numerical lens with a high-pass angular spectrum filter, circularly polarized laser pulses are focused into the magneto-optic film with the perpendicular anisotropy.Magnetization of the film is induced by the inverse Faraday effect.As the obstructed angle of the filter increases the magnetic recording density increases evidently.The magnetization intensity and the sidelobe effect are also discussed.

  10. Decoding of digital magnetic recording with longitudinal magnetization of a tape from a magneto-optical image of stray fields

    Science.gov (United States)

    Lisovskii, F. V.; Mansvetova, E. G.

    2017-05-01

    For digital magnetic recording of encoded information with longitudinal magnetization of the tape, the connection between the domain structure of a storage medium and magneto-optical image of its stray fields obtained using a magnetic film with a perpendicular anisotropy and a large Faraday rotation has been studied. For two-frequency binary code without returning to zero, an algorithm is developed, that allows uniquely decoding of the information recorded on the tape based on analysis of an image of stray fields.

  11. Abundances of disk and bulge giants from hi-res optical spectra: I. O, Mg, Ca, and Ti in the Solar neighborhood and Kepler field samples

    CERN Document Server

    Jönsson, H; Nordlander, T; Pehlivan, A; Hartman, H; Jönsson, P; Eriksson, K

    2016-01-01

    The galactic bulge is a significant part of our galaxy, but it is hard to observe, being both distant and covered by dust in the disk. Therefore there do not exist many hi-res optical spectra of bulge stars with large wavelength coverage, whose determined abundances can be compared with nearby, similarly analyzed stellar samples. We aim to determine the, for chemical evolution models, so important alpha elements of a sample of bulge giants using hi-res optical spectra with large wavelength coverage. The abundances found will be compared to similarly derived abundances from similar spectra of similar stars in the local thin and thick disks. In this first paper we focus on the Solar neighborhood reference sample. We use spectral synthesis to derive the stellar parameters as well as the elemental abundances of both the local as well as the bulge samples of giants. Special care is taken to benchmark our method of determining stellar parameters against independent measurements of effective temperatures from angula...

  12. Reconstruction of mechanically recorded sound from an edison cylinder using three dimensional non-contact optical surface metrology

    Energy Technology Data Exchange (ETDEWEB)

    Fadeyev, V.; Haber, C.; Maul, C.; McBride, J.W.; Golden, M.

    2004-04-20

    Audio information stored in the undulations of grooves in a medium such as a phonograph disc record or cylinder may be reconstructed, without contact, by measuring the groove shape using precision optical metrology methods and digital image processing. The viability of this approach was recently demonstrated on a 78 rpm shellac disc using two dimensional image acquisition and analysis methods. The present work reports the first three dimensional reconstruction of mechanically recorded sound. The source material, a celluloid cylinder, was scanned using color coded confocal microscopy techniques and resulted in a faithful playback of the recorded information.

  13. Optical memory system based on incoherent recorder and coherent reader of multiplexed computer generated one-dimensional Fourier transform holograms

    Science.gov (United States)

    Odinokov, Sergey; Zlokazov, Evgenii; Donchenko, Sergey; Verenikina, Nina

    2017-09-01

    The present article highlights the development results of archive memory holographic system based on application of computer generated Fourier holograms. The proposed idea allows realization of holographic principles of digital data record using simple and compact optical devices. Special interest is paid to synthesis and multiplexed record of one-dimensional Fourier transform holograms. The principal schemes of constructed prototypes of incoherent data recorder and coherent data reader are described in the present paper. The results of experimental implementation of the constructed devices are presented.

  14. On the Nature of Type Ia-CSM Supernovae: Optical and Near-Infrared Spectra of SN 2012ca and SN 2013dn

    CERN Document Server

    Fox, Ori D; Filippenko, Alexei V; Mauerhan, Jon; Becker, Juliette; Borish, H Jacob; Cenko, S Bradley; Clubb, Kelsey I; Graham, Melissa; Hsiao, Eric; Kelly, Patrick L; Lee, William H; Marion, G H; Milisavljevic, Dan; Parrent, Jerod; Shivvers, Isaac; Skrutskie, Michael; Smith, Nathan; Wilson, John; Zheng, Weikang

    2014-01-01

    A growing subset of Type Ia supernovae (SNe Ia) show evidence for unexpected interaction with a dense circumstellar medium (SNe Ia-CSM). The precise nature of the progenitor, however, remains debated owing to spectral ambiguities arising from a strong contribution from the CSM interaction. Late-time spectra offer potential insight if the post-shock cold, dense shell becomes sufficiently thin and/or the ejecta begin to cross the reverse shock. To date, few high-quality spectra of this kind exist. Here we report on the late-time optical and infrared spectra of the SNe~Ia-CSM 2012ca and 2013dn. These SNe Ia-CSM spectra exhibit low [Fe III]/[Fe II] ratios and strong [Ca II] at late epochs. Such characteristics are reminiscent of the super-Chandrasekhar-mass (SC) candidate SN 2009dc, for which these features suggested a low-ionisation state due to high densities, although the broad Fe features admittedly show similarities to the blue "quasi-continuum" observed in some core-collapse SNe Ibn and IIn. Neither SN 2012...

  15. NOAA Climate Data Record (CDR) of AVHRR Daily and Monthly Aerosol Optical Thickness over Global Oceans, Version 2.0

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This NOAA Climate Data Record (CDR) of Aerosol Optical Thickness (AOT) is derived from data taken over global oceans from the PATMOS-x AVHRR level-2b channel 1 (0.63...

  16. Algorithms for classification of astronomical object spectra

    Science.gov (United States)

    Wasiewicz, P.; Szuppe, J.; Hryniewicz, K.

    2015-09-01

    Obtaining interesting celestial objects from tens of thousands or even millions of recorded optical-ultraviolet spectra depends not only on the data quality but also on the accuracy of spectra decomposition. Additionally rapidly growing data volumes demands higher computing power and/or more efficient algorithms implementations. In this paper we speed up the process of substracting iron transitions and fitting Gaussian functions to emission peaks utilising C++ and OpenCL methods together with the NOSQL database. In this paper we implemented typical astronomical methods of detecting peaks in comparison to our previous hybrid methods implemented with CUDA.

  17. KAPPA: A Package for Synthesis of optically thin spectra for the non-Maxwellian kappa-distributions based on the CHIANTI database

    CERN Document Server

    Dzifčáková, Elena; Kotrč, Pavel; Fárník, František; Zemanová, Alena

    2015-01-01

    The non-Maxwellian $\\kappa$-distributions have been detected in the solar transition region and flares. These distributions are characterized by a high-energy tail and a near-Maxwellian core and are known to have significant impact on the resulting optically thin spectra arising from collisionally dominated astrophysical plasmas. We developed the KAPPA package (http://kappa.asu.cas.cz) for synthesis of such line and continuum spectra. The package is based on the freely available CHIANTI database and software, and can be used in a similar manner. Ionization and recombination rates together with the ionization equilibria are provided for a range of $\\kappa$ values. Distribution-averaged collision strengths for excitation are obtained by an approximate method for all transitions in all ions available within CHIANTI. The validity of this approximate method is tested by comparison with direct calculations. Typical precisions of better than 5% are found, with all cases being within 10%. Tools for calculation of syn...

  18. Theoretical investigations of the optical and EPR spectra for trivalent cerium and ytterbium ions in orthorhombic YF{sub 3} crystal

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hong-Gang, E-mail: kezhouliu@163.com; Zheng, Wen-Chen

    2016-09-01

    The optical spectra and electron paramagnetic resonance (EPR) parameters (g factors and hyperfine structure constants A) for trivalent cerium and ytterbium ions in YF{sub 3} crystal with orthorhombic structure are investigated together by the complete diagonalization (of energy matrix) method (CDM). The obtained results are in reasonable agreement with the experimental ones. More importantly, two magnetically nonequivalent centers in YF{sub 3} crystal observed in EPR experiments are confirmed and ascribed to their specific positions in a unit cell by our calculations based on superposition model (SPM) analysis. Such identification of local sites with different magnetic properties would help us to understand not only the EPR spectra and magnetic susceptibility of other lanthanide ions doped in crystals with the same structure as YF{sub 3} but also the energy transfer scheme between two lanthanide ions occupying such two sites. All results are discussed carefully.

  19. Incorporation of AgI clusters into the cages of zeolites LTA and FAU observed by optical spectra and X-ray diffraction patterns

    Science.gov (United States)

    Kodaira, Tetsuya; Ikeda, Takuji; Takeo, Harutoshi

    1999-02-01

    The loading of AgI into the cages of zeolites LTA and FAU was performed by vapor-phase adsorption. The successful incorporation of AgI clusters into the cages was confirmed by optical absorption spectra and X-ray powder diffraction patterns. Large blue shifts of the absorption edges were observed in the spectra of adsorbed AgI to both zeolites, compared with the lowest excited state of AgI in the bulk. The present observation of the shift implies that a strong quantum confinement in the photoexcited state of AgI occurs, which leads to the conclusion that AgI clusters have been formed in the cages. In the X-ray powder diffraction pattern of AgI-loaded LTA, superlattice reflection peaks are observed which cannot be assigned either to the reflection of LTA or the AgI in the bulk.

  20. Optical constants and fitted transmittance spectra of varies thickness of polycrystalline ZnSe thin films in terms of spectroscopic ellipsometry

    Energy Technology Data Exchange (ETDEWEB)

    Shaaban, E.R., E-mail: esam_ramadan2008@yahoo.com [Physics Department, Faculty of Science, Al-Azhar University, Assiut 71542 (Egypt)

    2013-06-25

    Highlights: ► Different thicknesses of ZnSe films were prepared. ► The microstructure parameters of the films have been determined. ► Spectroscopic ellipsometry parameters were analyzed to determine the optical constants. ► Transmittance spectra has been simulated using Murmann’s exact equation. -- Abstract: Different thickness of Zinc selenide (ZnSe) thin films were deposited onto glass substrates by the thermal evaporation technique. Their structural characteristics were studied by X-ray diffraction (XRD). The microstructure parameters, crystallite size and microstrain were calculated. The optical constants (n, k) and film thicknesses of ZnSe thin films were obtained by fitting the ellipsometric parameters (ψ and Δ) data using three layer model systems in the wavelength range 300–1100 nm. It is found that the refractive index, n increases with the increase of the film thickness. The possible optical transition in these films is found to be allowed direct transitions. The optical energy gap increase with increasing the film thickness in a narrow range. The experimental transmittances spectrum can be fitted in terms Murmann’s exact equation using the modeled thickness and optical constants obtained spectroscopic ellipsometry model.

  1. Link between optical spectra, crystal-field parameters, and local environments of Eu3+ ions in Eu2O3-doped sodium disilicate glass

    Science.gov (United States)

    Qin, T.; Mountjoy, G.; Afify, N. D.; Reid, M. F.; Yeung, Y. Y.; Speghini, A.; Bettinelli, M.

    2011-09-01

    Rare-earth-doped glasses are key materials for optical technology due to the luminescent properties of 4fn ions. The crystal-field model describes the effect of local environment on transitions between 4f electrons. We present a detailed modeling study of the optical spectra of sodium disilicate glass, 33Na2O·67SiO2, doped with 0.2% and 1.0 mol% Eu2O3. This study uses very large molecular dynamics models with up to 100 Eu3+ ions, the superposition model for covalent and overlap effects on crystal-field parameters, and realistic values for homogeneous linewidth broadening. The simulated spectra are in reasonable agreement with experiment. The trends in 7FJ energy levels across different Eu3+ ion sites have been examined and a very detailed analysis is presented that looks at how features of the spectra are related to features of the local environment of Eu3+ ions. Increasing the crystal-field strength Stotal causes the 7F0 energy level to decrease and causes the splitting of 7FJ manifolds to increase, and this is due to increasing mixing of 4f wave functions. To a reasonable approximation the crystal-field strength components Sk depend on angular positions of ligands independently of distances to ligands. The former are seen to be more significant in determining Sk, which are closely related to the rotationally invariant bond-orientational order parameters Qk. The values of S2 are approximately linear in Q2, and the values of Q2 are higher for fivefold than sixfold coordinated rare-earth ions. These results can be of importance for efforts to enhance the local environment of rare-earth ions in oxide glasses for optical applications.

  2. Thermal bleaching of optical absorption and photoluminescence spectra of γ-irradiated CaF_2:Dy:Pb:Na single crystals

    Institute of Scientific and Technical Information of China (English)

    S.M.; Moses; Kennedy

    2010-01-01

    The variation of the optical absorption (OA) and photoluminescence (PL) spectra with temperature was studied on γ-irradiated CaF2:Dy:Pb:Na single crystals. The OA spectrum showed bands around 2.05, 3.20, 3.82 and 6.20 eV which could be attributed to different sodium associated (SA) colour centres (CCs) such as MNa and RA+ . Heating the crystal indicated the annihilation and formation of different SACCs. The excitation spectrum for the characteristic Dy3+ emission at 2.14 eV immediately after irradiation was...

  3. First-principles calculation of optical absorption spectra in conjugated polymers: Role of electron-hole interaction

    Energy Technology Data Exchange (ETDEWEB)

    Rohlfing, Michael; Tiago, M.L.; Louie, Steven G.

    2000-03-20

    Experimental and theoretical studies have shown that excitonic effects play an important role in the optical properties of conjugated polymers. The optical absorption spectrum of trans-polyacetylene, for example, can be understood as completely dominated by the formation of exciton bound states. We review a recently developed first-principles method for computing the excitonic effects and optical spectrum, with no adjustable parameters. This theory is used to study the absorption spectrum of two conjugated polymers: trans-polyacetylene and poly-phenylene-vinylene(PPV).

  4. On the evaluation of optical parameters of a thin semiconductor film from transmission spectra, and application to GaN films

    Science.gov (United States)

    Šantić, B.; Scholz, F.

    2008-10-01

    The analysis of the optical transmission spectra of semiconductor thin films on a transparent substrate is revisited. A new equation for the optical transmission is derived. Based on this equation and on the spacing of the interference pattern, a method is described and analyzed in detail for the determination of the film thickness, refractive index and absorption coefficient. As a notable feature, small values of the absorption coefficient can be determined as a fitting parameter at all wavelengths, regardless of strong interference. The method is compared to the frequently encountered envelope method of Manifacier et al and Swanepoel. The suitability of the method is illustrated on two GaN thin films grown on sapphire. Below the band gap, the index of refraction of GaN can be described by the equation n(λ(nm)) = 2.19 + 2.57(λ - 345)-1/2.

  5. Direct observation of the superconducting energy-gap opening in the optical conductivity spectra of LuNi{sub 2}B{sub 2}C

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Theo; Pronin, A.V.; Stehr, D.; Wosnitza, J. [Hochfeld-Magnetlabor Dresden (HLD) and Institute of Ion Beam Physics and Materials Research, HZ Dresden-Rossendorf, 01314 Dresden (Germany); Niemeier, T.; Holzapfel, B. [IFW Dresden, Leibniz Institute for Solid State and Materials Research (Germany)

    2012-07-01

    At frequencies between 100 GHz and 2.5 THz, we have accurately measured the complex transmission coefficient of LuNi{sub 2}B{sub 2}C films on MgO substrates using two different setups: a time-domain terahertz spectrometer and a setup based on backward-wave oscillators. For the first time, the development of the superconducting energy gap is directly observed in the optical spectra. From the measured data, we have calculated the optical conductivity and the penetration depth. We have compared the results with the BCS theory, and found an additional absorption at low frequencies. The origin of this absorption may be related to the complex gap structure of the compound with possible nodes. Theoretical calculations are currently under way.

  6. Effects of multi-context information recorded at different regions in holographic polymer-dispersed liquid crystal on optical reconfiguration

    Science.gov (United States)

    Ogiwara, Akifumi; Watanabe, Minoru

    2016-08-01

    A holographic polymer-dispersed liquid crystal (HPDLC) memory to record multi-context information for an optically reconfigurable gate array is formed by constructing a laser illumination system to implement successive laser exposures at different small regions in a glass cell filled with LC composites. The context pattern arrangements for circuit information are designed in a 3 × 3 in.2 photomask by electron beam lithography, and they are recorded as laser interference patterns at nine regions separated in an HPDLC sample by a laser interferometer composed of movable pinhole and photomask plates placed on motorized stages. The multi-context information reconstructed from the different regions in the HPDLC is written to a photodiode array in a gate-array VLSI by switching only the position of laser irradiation using the displacement of the pinhole plate under the control of a personal computer (PC). The effects of multi-context information recorded at different regions in the HPDLC on optical reconfiguration are discussed in terms of the optical system composed of ORGA VLSI and HPDLC memory. The internal structures in the HPDLC memory formed by multi-context recording are investigated by scanning electron microscopy (SEM) observation, and the configurations composed of LC and polymer phases are revealed at various regions in the HPDLC memory.

  7. Polarized IR reflectance spectra of the monoclinic single crystal K2Ni(SO4)2.6H2O: dispersion analysis, dielectric and optical properties.

    Science.gov (United States)

    Ivanovski, Vladimir; Mayerhöfer, Thomas G; Popp, Jürgen; Petrusevski, Vladimir M

    2008-02-01

    Polarized IR reflectance spectra of K2Ni(SO4)2.6H2O single crystal (belonging to the group of Tutton salts) were recorded at near-normal incidence. From the dispersion analysis performed on the spectra recorded from the ac crystal plane, mode parameters: transversal frequency, oscillator strength, attenuation constant and the orientation of the transition moment were determined. The polarized spectrum along the b crystallographic axis was also recorded and a dispersion analysis performed. Comparison between the spectroscopically obtained transition moment directions with those obtained from the structure data for various modes is discussed. All dielectric tensor component values were obtained for the whole mid-IR frequency range. Also, the real and the imaginary parts of the complex indexes of refraction for the waves with wave vector in the direction of the b crystallographic axis and in the ac plane (when the direction of the electric vector is oriented along the b axis) were found as functions of frequency.

  8. Write-once optical disk system measuring 300 mm using high-density, pit-edge recording.

    Science.gov (United States)

    Maeda, T; Saito, A; Sugiyama, H; Arai, S; Shigematsu, K

    1995-08-01

    To meet the requirement for a second-generation digital optical disk with a larger capacity and a higher speed, the new 300-mm, write-once optical disk system described here uses pit-edge recording and the modified-constant-angular-velocity method [Maeda et al., Trans. IEICE E74, 951 (1991)]. New techniques that can use these methods together and are suitable for interchangeability-data composition and independent detection of the leading and trailing edges-have resulted in the most reliable data-storage system ever produced, we believe. The concept of this system, the characteristics of the new techniques, and the optimization of system performance are described.

  9. Abundances of disk and bulge giants from high-resolution optical spectra. I. O, Mg, Ca, and Ti in the solar neighborhood and Kepler field samples

    Science.gov (United States)

    Jönsson, H.; Ryde, N.; Nordlander, T.; Pehlivan Rhodin, A.; Hartman, H.; Jönsson, P.; Eriksson, K.

    2017-02-01

    Context. The Galactic bulge is an intriguing and significant part of our Galaxy, but it is hard to observe because it is both distant and covered by dust in the disk. Therefore, there are not many high-resolution optical spectra of bulge stars with large wavelength coverage, whose determined abundances can be compared with nearby, similarly analyzed stellar samples. Aims: We aim to determine the diagnostically important alpha elements of a sample of bulge giants using high-resolution optical spectra with large wavelength coverage. The abundances found are compared to similarly derived abundances from similar spectra of similar stars in the local thin and thick disks. In this first paper we focus on the solar neighborhood reference sample. Methods: We used spectral synthesis to derive the stellar parameters as well as the elemental abundances of both the local and bulge samples of giants. We took special care to benchmark our method of determining stellar parameters against independent measurements of effective temperatures from angular diameter measurements and surface gravities from asteroseismology. Results: In this first paper we present the method used to determine the stellar parameters and elemental abundances, evaluate them, and present the results for our local disk sample of 291 giants. Conclusions: When comparing our determined spectroscopic temperatures to those derived from angular diameter measurements, we reproduce these with a systematic difference of +10 K and a standard deviation of 53 K. The spectroscopic gravities reproduce those determined from asteroseismology with a systematic offset of +0.10 dex and a standard deviation of 0.12 dex. When it comes to the abundance trends, our sample of local disk giants closely follows trends found in other works analyzing solar neighborhood dwarfs, showing that the much brighter giant stars are as good abundance probes as the often used dwarfs. Based on observations made with the Nordic Optical Telescope

  10. Effects of structure distortion on optical phonon properties of crystalline beta-BaTeMo{sub 2}O{sub 9}—A novel nonlinear optical material: Infrared and Raman spectra as well as first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, S. T.; Huang, Y.; Qiu, W. Y.; Li, Y. L.; He, S. M.; Zhang, B., E-mail: bozhang@mail.sitp.ac.cn, E-mail: xschen@mail.sitp.ac.cn, E-mail: luwei@mail.sitp.ac.cn; Chen, X. S., E-mail: bozhang@mail.sitp.ac.cn, E-mail: xschen@mail.sitp.ac.cn, E-mail: luwei@mail.sitp.ac.cn; Lu, W., E-mail: bozhang@mail.sitp.ac.cn, E-mail: xschen@mail.sitp.ac.cn, E-mail: luwei@mail.sitp.ac.cn [National Lab for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, 500 Yu Tian Road, Shanghai 200083 (China); Zhang, J. J.; Tao, X. T. [State Key Laboratory of Crystal Materials, Shangdong University, 27 South Shanda Road, Jinan, Shangdong 250100 (China)

    2013-12-21

    The infrared dielectric property of monoclinic BaTeMo{sub 2}O{sub 9} single crystals is studied by polarized IR reflectance spectra from 20 to 1800 cm{sup −1}. Based on the modified Lorentz model, the frequencies, strengths, and dampings of TO modes as well as the orientations of the dipole momenta are determined, agreeing well with Raman spectra and results from First-principles calculation. The observed modes are visually assigned to the specific atoms' motions in the primitive cell based on the theory calculations. A large shift of the internal modes of the anion groups relative to free anion co-ordination polyhedra is observed, which can be used to indicate the distortions of co-ordination polyhedra related to the nonlinear optical properties. Further, the experimental results of the strengths of the oscillators support the elimination and splitting of degenerate modes in free regular polyhedrons. These results offer a way to evaluate the nonlinear optical properties by use of traditional IR reflectivity spectra.

  11. Effects of structure distortion on optical phonon properties of crystalline beta-BaTeMo2O9—A novel nonlinear optical material: Infrared and Raman spectra as well as first-principles calculations

    Science.gov (United States)

    Zhou, S. T.; Huang, Y.; Qiu, W. Y.; Li, Y. L.; He, S. M.; Zhang, J. J.; Zhang, B.; Chen, X. S.; Tao, X. T.; Lu, W.

    2013-12-01

    The infrared dielectric property of monoclinic BaTeMo2O9 single crystals is studied by polarized IR reflectance spectra from 20 to 1800 cm-1. Based on the modified Lorentz model, the frequencies, strengths, and dampings of TO modes as well as the orientations of the dipole momenta are determined, agreeing well with Raman spectra and results from First-principles calculation. The observed modes are visually assigned to the specific atoms' motions in the primitive cell based on the theory calculations. A large shift of the internal modes of the anion groups relative to free anion co-ordination polyhedra is observed, which can be used to indicate the distortions of co-ordination polyhedra related to the nonlinear optical properties. Further, the experimental results of the strengths of the oscillators support the elimination and splitting of degenerate modes in free regular polyhedrons. These results offer a way to evaluate the nonlinear optical properties by use of traditional IR reflectivity spectra.

  12. X-rays from the jet in 3C 273 clues from the radio-optical spectra

    CERN Document Server

    Jester, S; Meisenheimer, K; Perley, R

    2002-01-01

    Using new deep VLA and HST observations of the large-scale jet in 3C273 matched to 0.3" resolution, we have detected excess near-ultraviolet emission (300 nm) above a synchrotron cutoff spectrum accounting for the emission from radio through optical (3.6 cm - 620 nm). This necessitates a two-component model for the emission. The radio-optical-X-ray spectral energy distributions suggest a common origin for the UV excess and the X-rays from the jet.

  13. Local domains of motor cortical activity revealed by fiber-optic calcium recordings in behaving nonhuman primates

    Science.gov (United States)

    Adelsberger, Helmuth; Zainos, Antonio; Alvarez, Manuel; Romo, Ranulfo; Konnerth, Arthur

    2014-01-01

    Brain mapping experiments involving electrical microstimulation indicate that the primary motor cortex (M1) directly regulates muscle contraction and thereby controls specific movements. Possibly, M1 contains a small circuit “map” of the body that is formed by discrete local networks that code for specific movements. Alternatively, movements may be controlled by distributed, larger-scale overlapping circuits. Because of technical limitations, it remained unclear how movement-determining circuits are organized in M1. Here we introduce a method that allows the functional mapping of small local neuronal circuits in awake behaving nonhuman primates. For this purpose, we combined optic-fiber–based calcium recordings of neuronal activity and cortical microstimulation. The method requires targeted bulk loading of synthetic calcium indicators (e.g., OGB-1 AM) for the staining of neuronal microdomains. The tip of a thin (200 µm) optical fiber can detect the coherent activity of a small cluster of neurons, but is insensitive to the asynchronous activity of individual cells. By combining such optical recordings with microstimulation at two well-separated sites of M1, we demonstrate that local cortical activity was tightly associated with distinct and stereotypical simple movements. Increasing stimulation intensity increased both the amplitude of the movements and the level of neuronal activity. Importantly, the activity remained local, without invading the recording domain of the second optical fiber. Furthermore, there was clear response specificity at the two recording sites in a trained behavioral task. Thus, the results provide support for movement control in M1 by local neuronal clusters that are organized in discrete cortical domains. PMID:24344287

  14. Optical Absorption Spectra and Electronic Properties of Symmetric and Asymmetric Squaraine Dyes for Use in DSSC Solar Cells: DFT and TD-DFT Studies

    Directory of Open Access Journals (Sweden)

    Reda M. El-Shishtawy

    2016-04-01

    Full Text Available The electronic absorption spectra, ground-state geometries and electronic structures of symmetric and asymmetric squaraine dyes (SQD1–SQD4 were investigated using density functional theory (DFT and time-dependent (TD-DFT density functional theory at the B3LYP/6-311++G** level. The calculated ground-state geometries reveal pronounced conjugation in these dyes. Long-range corrected time dependent density functionals Perdew, Burke and Ernzerhof (PBE, PBE1PBE (PBE0, and the exchange functional of Tao, Perdew, Staroverov, and Scuseria (TPSSh with 6-311++G** basis set were employed to examine optical absorption properties. In an extensive comparison between the optical data and DFT benchmark calculations, the BEP functional with 6-311++G** basis set was found to be the most appropriate in describing the electronic absorption spectra. The calculated energy values of lowest unoccupied molecular orbitals (LUMO were 3.41, 3.19, 3.38 and 3.23 eV for SQD1, SQD2, SQD3, and SQD4, respectively. These values lie above the LUMO energy (−4.26 eV of the conduction band of TiO2 nanoparticles indicating possible electron injection from the excited dyes to the conduction band of the TiO2 in dye-sensitized solar cells (DSSCs. Also, aromaticity computation for these dyes are in good agreement with the data obtained optically and geometrically with SQD4 as the highest aromatic structure. Based on the optimized molecular geometries, relative positions of the frontier orbitals, and the absorption maxima, we propose that these dyes are suitable components of photovoltaic DSSC devices.

  15. Optical Absorption Spectra and Electronic Properties of Symmetric and Asymmetric Squaraine Dyes for Use in DSSC Solar Cells: DFT and TD-DFT Studies.

    Science.gov (United States)

    El-Shishtawy, Reda M; Elroby, Shaaban A; Asiri, Abdullah M; Müllen, Klaus

    2016-04-01

    The electronic absorption spectra, ground-state geometries and electronic structures of symmetric and asymmetric squaraine dyes (SQD1-SQD4) were investigated using density functional theory (DFT) and time-dependent (TD-DFT) density functional theory at the B3LYP/6-311++G** level. The calculated ground-state geometries reveal pronounced conjugation in these dyes. Long-range corrected time dependent density functionals Perdew, Burke and Ernzerhof (PBE, PBE1PBE (PBE0)), and the exchange functional of Tao, Perdew, Staroverov, and Scuseria (TPSSh) with 6-311++G** basis set were employed to examine optical absorption properties. In an extensive comparison between the optical data and DFT benchmark calculations, the BEP functional with 6-311++G** basis set was found to be the most appropriate in describing the electronic absorption spectra. The calculated energy values of lowest unoccupied molecular orbitals (LUMO) were 3.41, 3.19, 3.38 and 3.23 eV for SQD1, SQD2, SQD3, and SQD4, respectively. These values lie above the LUMO energy (-4.26 eV) of the conduction band of TiO₂ nanoparticles indicating possible electron injection from the excited dyes to the conduction band of the TiO₂ in dye-sensitized solar cells (DSSCs). Also, aromaticity computation for these dyes are in good agreement with the data obtained optically and geometrically with SQD4 as the highest aromatic structure. Based on the optimized molecular geometries, relative positions of the frontier orbitals, and the absorption maxima, we propose that these dyes are suitable components of photovoltaic DSSC devices.

  16. Studies of the molecular geometry, vibrational spectra, frontier molecular orbital, nonlinear optical and thermodynamics properties of aceclofenac by quantum chemical calculations.

    Science.gov (United States)

    Suresh, S; Gunasekaran, S; Srinivasan, S

    2014-05-05

    The solid phase FT-IR and FT-Raman spectra of 2-[2-[2-[(2,6-dichlorophenyl)amino]phenyl]acetyl] oxyacetic acid (Aceclofenac) have been recorded in the region 4000-400 and 4000-100 cm(-1) respectively. The optimized molecular geometry and fundamental vibrational frequencies are interpreted with the aid of structure optimizations and normal coordinate force field calculations based on density functional theory (DFT) method and a comparative study between Hartree Fork (HF) method 6-311++G(d,p) level basis set. The calculated harmonic vibrational frequencies were scaled and have been compared with experimental by obtained FT-IR and FT-Raman spectra. A detailed interpretation of the vibrational spectra of this compound has been made on the basis of the calculated potential energy distribution (PED). The time dependent DFT method employed to study its absorption energy and oscillator strength. The linear polarizability (α) and the first order hyper polarizability (β) values of the investigated molecule have been computed. The electronic properties, such as HOMO and LUMO energies, molecular electrostatic potential (MESP) were also performed. Stability of the molecule arising from hyper conjugative interaction, charge delocalization has been analyzed using natural bond orbital (NBO) analysis.

  17. Surface enhanced Raman spectra of the organic nonlinear optic material: Methyl 3-(4-methoxy phenyl)prop-2-enoate

    Indian Academy of Sciences (India)

    D Sajan; I Hubert Joe; V S Jayakumar; Jacek Zaleski

    2008-07-01

    The surface geometry of methyl 3-(4-methoxy phenyl)prop-2-enoate molecule was studied by analysis of the SERS spectra adsorbed on silver colloid surfaces. For a reliable analysis of the SERS spectrum, we also performed density functional theoretical calculations. The absence of a C-H stretching vibrations and the observed C-H out-of-plane bending modes suggest that the MMP molecule may be adsorbed in a flat on orientation to the surface. The SERS spectral studies predict a tilted orientation of ethylenic bridge with respect to the phenyl ring.

  18. The X-ray spectra of optically selected Seyfert 2 galaxies. Are there any Sy2 galaxies with no absorption?

    CERN Document Server

    Pappa, A; Stewart, G C; Zezas, A L

    2001-01-01

    We present an X-ray spectral analysis of a sample of 8 bona-fide Seyfert 2 galaxies, selected on the basis of their high $[OIII]\\lambda5007$ flux, from the Ho et al. (1997) spectroscopic sample of nearby galaxies. We find that, in general, the X-ray spectra of our Seyfert 2 galaxies are complex, with some our objects having spectra different from the 'typical' spectrum of X-ray selected Seyfert 2 galaxies. Two (NGC3147 and NGC4698) show no evidence for intrinsic absorption. We suggest this is due to the fact that when the torus suppresses the intrinsic medium and hard energy flux, underlying emission from the host galaxy, originating in circumnuclear starbursts, and scattering from warm absorbers contributes in these energy bands more significantly. Our asca data alone cannot discriminate whether low absorption objects are Compton-thick AGN with a strong scattered component or lack an obscuring torus. The most striking example of our low absorption Seyfert 2 is NGC4698. Its spectrum could be explained by eith...

  19. Lowest excited states and optical absorption spectra of donor–acceptor copolymers for organic photovoltaics: a new picture emerging from tuned long-range corrected density functionals

    KAUST Repository

    Pandey, Laxman

    2012-01-01

    Polymers with low optical gaps are of importance to the organic photovoltaics community due to their potential for harnessing a large portion of the solar energy spectrum. The combination along their backbones of electron-rich and electron-deficient fragments contributes to the presence of low-lying excited states that are expected to display significant charge-transfer character. While conventional hybrid functionals are known to provide unsatisfactory results for charge-transfer excitations at the time-dependent DFT level, long-range corrected (LRC) functionals have been reported to give improved descriptions in a number of systems. Here, we use such LRC functionals, considering both tuned and default range-separation parameters, to characterize the absorption spectra of low-optical-gap systems of interest. Our results indicate that tuned LRC functionals lead to simulated optical-absorption properties in good agreement with experimental data. Importantly, the lowest-lying excited states (excitons) are shown to present a much more localized nature than initially anticipated. © 2012 the Owner Societies.

  20. Lowest excited states and optical absorption spectra of donor-acceptor copolymers for organic photovoltaics: a new picture emerging from tuned long-range corrected density functionals.

    Science.gov (United States)

    Pandey, Laxman; Doiron, Curtis; Sears, John S; Brédas, Jean-Luc

    2012-11-01

    Polymers with low optical gaps are of importance to the organic photovoltaics community due to their potential for harnessing a large portion of the solar energy spectrum. The combination along their backbones of electron-rich and electron-deficient fragments contributes to the presence of low-lying excited states that are expected to display significant charge-transfer character. While conventional hybrid functionals are known to provide unsatisfactory results for charge-transfer excitations at the time-dependent DFT level, long-range corrected (LRC) functionals have been reported to give improved descriptions in a number of systems. Here, we use such LRC functionals, considering both tuned and default range-separation parameters, to characterize the absorption spectra of low-optical-gap systems of interest. Our results indicate that tuned LRC functionals lead to simulated optical-absorption properties in good agreement with experimental data. Importantly, the lowest-lying excited states (excitons) are shown to present a much more localized nature than initially anticipated.

  1. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: extending the predictions to different years and different sites

    Science.gov (United States)

    Reggente, Matteo; Dillner, Ann M.; Takahama, Satoshi

    2016-02-01

    Organic carbon (OC) and elemental carbon (EC) are major components of atmospheric particulate matter (PM), which has been associated with increased morbidity and mortality, climate change, and reduced visibility. Typically OC and EC concentrations are measured using thermal-optical methods such as thermal-optical reflectance (TOR) from samples collected on quartz filters. In this work, we estimate TOR OC and EC using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE Teflon) filters using partial least square regression (PLSR) calibrated to TOR OC and EC measurements for a wide range of samples. The proposed method can be integrated with analysis of routinely collected PTFE filter samples that, in addition to OC and EC concentrations, can concurrently provide information regarding the functional group composition of the organic aerosol. We have used the FT-IR absorbance spectra and TOR OC and EC concentrations collected in the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network (USA). We used 526 samples collected in 2011 at seven sites to calibrate the models, and more than 2000 samples collected in 2013 at 17 sites to test the models. Samples from six sites are present both in the calibration and test sets. The calibrations produce accurate predictions both for samples collected at the same six sites present in the calibration set (R2 = 0.97 and R2 = 0.95 for OC and EC respectively), and for samples from 9 of the 11 sites not included in the calibration set (R2 = 0.96 and R2 = 0.91 for OC and EC respectively). Samples collected at the other two sites require a different calibration model to achieve accurate predictions. We also propose a method to anticipate the prediction error; we calculate the squared Mahalanobis distance in the feature space (scores determined by PLSR) between new spectra and spectra in the calibration set. The squared Mahalanobis distance provides a crude method for assessing the

  2. Microexplosion Recording in Spin-Coated Polymer Films Including ZnO Nanoparticles for Three-Dimensional Optical Memory

    Science.gov (United States)

    Shiono, Teruhiro; Yamamoto, Hiroaki; Nishino, Seiji

    2004-07-01

    As a microexplosion recording material, we propose polymer films including ZnO nanoparticles (ZnO polyester composite) for write-once multilayered recording media. These media with the ZnO composite material can be fabricated by a spin-coating method and can be read at the violet wavelength of 0.405 μm. By the electromagnetic analysis of diffraction loss, we clarified the pit design and the optical performance for void formation recording. From the results of experiments performed using three kinds of mode-locked pulsed lasers (pulse widths of 150 fs, 16 ps and 6 ns), with a clear reflection microscope image of submicrometer pits, the microexplosion sensitivity was confirmed to be greatly improved by 14, 38 and 50 times, respectively.

  3. Structure-Related Optical Fingerprints in the Absorption Spectra of Colloidal Quantum Dots: Random Alloy vs. Core/Shell Systems

    CERN Document Server

    Mourad, Daniel

    2016-01-01

    We argue that the experimentally easily accessible optical absorption spectrum can often be used to distinguish between a random alloy phase and a stoichiometrically equivalent core/shell realization of ensembles of monodisperse colloidal semiconductor quantum dots without the need for more advanced structural characterization tools. Our proof-of-concept is performed by conceptually straightforward exact-disorder tight-binding calculations. The underlying stochastical tight-binding scheme only parametrizes bulk band structure properties and does not employ additional free parameters to calculate the optical absorption spectrum, which is an easily accessible experimental property. The method is applied to selected realizations of type-I Cd(Se,S) and type-II (Zn,Cd)(Se,S) alloyed quantum dots with an underlying zincblende crystal structure and the corresponding core/shell counterparts.

  4. A reverse Monte Carlo method for deriving optical constants of solids from reflection electron energy-loss spectroscopy spectra

    Energy Technology Data Exchange (ETDEWEB)

    Da, B.; Sun, Y.; Ding, Z. J. [Hefei National Laboratory for Physical Sciences at Microscale and Department of Physics, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People' s Republic of China (China); Mao, S. F. [School of Nuclear Science and Technology, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People' s Republic of China (China); Zhang, Z. M. [Centre of Physical Experiments, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, People' s Republic of China (China); Jin, H.; Yoshikawa, H.; Tanuma, S. [Advanced Surface Chemical Analysis Group, National Institute for Materials Science, 1-2-1 Sengen Tsukuba, Ibaraki 305-0047 (Japan)

    2013-06-07

    A reverse Monte Carlo (RMC) method is developed to obtain the energy loss function (ELF) and optical constants from a measured reflection electron energy-loss spectroscopy (REELS) spectrum by an iterative Monte Carlo (MC) simulation procedure. The method combines the simulated annealing method, i.e., a Markov chain Monte Carlo (MCMC) sampling of oscillator parameters, surface and bulk excitation weighting factors, and band gap energy, with a conventional MC simulation of electron interaction with solids, which acts as a single step of MCMC sampling in this RMC method. To examine the reliability of this method, we have verified that the output data of the dielectric function are essentially independent of the initial values of the trial parameters, which is a basic property of a MCMC method. The optical constants derived for SiO{sub 2} in the energy loss range of 8-90 eV are in good agreement with other available data, and relevant bulk ELFs are checked by oscillator strength-sum and perfect-screening-sum rules. Our results show that the dielectric function can be obtained by the RMC method even with a wide range of initial trial parameters. The RMC method is thus a general and effective method for determining the optical properties of solids from REELS measurements.

  5. A reverse Monte Carlo method for deriving optical constants of solids from reflection electron energy-loss spectroscopy spectra

    Science.gov (United States)

    Da, B.; Sun, Y.; Mao, S. F.; Zhang, Z. M.; Jin, H.; Yoshikawa, H.; Tanuma, S.; Ding, Z. J.

    2013-06-01

    A reverse Monte Carlo (RMC) method is developed to obtain the energy loss function (ELF) and optical constants from a measured reflection electron energy-loss spectroscopy (REELS) spectrum by an iterative Monte Carlo (MC) simulation procedure. The method combines the simulated annealing method, i.e., a Markov chain Monte Carlo (MCMC) sampling of oscillator parameters, surface and bulk excitation weighting factors, and band gap energy, with a conventional MC simulation of electron interaction with solids, which acts as a single step of MCMC sampling in this RMC method. To examine the reliability of this method, we have verified that the output data of the dielectric function are essentially independent of the initial values of the trial parameters, which is a basic property of a MCMC method. The optical constants derived for SiO2 in the energy loss range of 8-90 eV are in good agreement with other available data, and relevant bulk ELFs are checked by oscillator strength-sum and perfect-screening-sum rules. Our results show that the dielectric function can be obtained by the RMC method even with a wide range of initial trial parameters. The RMC method is thus a general and effective method for determining the optical properties of solids from REELS measurements.

  6. Optical absorption and photoluminescence spectra of the ordered defect compound CuIn{sub 3}Te{sub 5}

    Energy Technology Data Exchange (ETDEWEB)

    Rincon, C [Centro de Estudios de Semiconductores, Departamento de Fisica Facultad de Ciencias, Universidad de Los Andes, Apartado, Postal No 1, La Hechicera Merida 5101 (Venezuela); Wasim, S M [Centro de Estudios de Semiconductores, Departamento de Fisica Facultad de Ciencias, Universidad de Los Andes, Apartado, Postal No 1, La Hechicera Merida 5101 (Venezuela); Marin, G [Centro de Estudios de Semiconductores, Departamento de Fisica Facultad de Ciencias, Universidad de Los Andes, Apartado, Postal No 1, La Hechicera Merida 5101 (Venezuela); Delgado, J M [Centro Nacional de Difraccion de Rayos-X, Facultad de Ciencias, Universidad de Los Andes, Apartado, Postal No 40, La Hechicera, Merida 5101 (Venezuela); Petroff, P M [Materials Department, University of California, Santa Barbara, CA 93106 (United States)

    2003-05-21

    The optical properties of the ordered defect compound CuIn{sub 3}Te{sub 5} which crystallizes in a chalcopyrite-related structure have been studied by absorption and photoluminescence (PL) techniques. Optical absorption measurements show that the band gap energy E{sub G} varies from 1.078 to 1.040 eV between 10 and 300 K. It is found that the variation of E{sub G} with temperature is mainly due to the contribution of optical phonons with a characteristic energy of about 16 meV. The PL measurements, carried out between 4 and 100 K with laser excitation intensities in the range from 1 to 400 mW, reveal that the main PL band is due to a donor-acceptor recombination between donor and acceptor defect levels that have activation energies of 60 and 30 meV, respectively. These donor and acceptor states are tentatively assigned as originating from indium atoms on copper sites and copper vacancies, respectively.

  7. A New Theoretical Library of High-resolution Stellar Spectra for UV-Optical Population Synthesis Models

    Science.gov (United States)

    Bertone, E.; Rodriguez-Merino, L.; Chavez, M.; Buzzoni, A.

    2003-06-01

    We present a new theoretical library of stellar spectra covering the wavelength interval from 850 to 7000 Å. The library consists of two datasets, one including the far UV-blue spectral region from 850 to 4750 Å at inverse spectral resolution R = 50000, and the latter spanning the range 3500-7000 Å at R = 500000. Both sets are based on the SYNTHE series of codes developed by R.L. Kurucz. For its comprehensive range of physical parameters (i.e. T[eff], logg and [M/H]) and higher spectral resolution, this is the most advanced spectral library currently available in the literature, and could profitably be used for population synthesis models and abundance studies of single stars.

  8. Modeling optical properties of polymer-solvent complexes: the chloroform influence on the P3HT and N2200 absorption spectra.

    Science.gov (United States)

    Dias Ledo, Rodrigo Maia; Leal, Luciano Almeida; de Brito Silva, Patrick Pascoal; da Cunha, Wiliam Ferreira; de Souza, Leonardo Evaristo; Almeida Fonseca, Antonio Luciano; Ceschin, Artemis Marti; da Silva Filho, Demétrio Antonio; Ribeiro Junior, Luiz Antonio

    2017-02-01

    The optical properties of polymer/solvent systems composed by the polymers P3HT and PolyeraActivInk N2200 under the present of chloroform as solvent are experimentally and theoretically investigated using UV-Vis spectroscopy, molecular dynamics (MD), and density functional theory (DFT) calculations. The study is focused on obtaining the theoretical methodologies that properly describes the experimentally obtained absorption spectra of polymer-solvent complexes. In order to investigate the solvent influence, two different approaches are taken into account: the solvation shell method (SSM) and the polarizable continuum model (PCM). Our findings shown that SSM simulations, which combine MD and DFT calculations, are in good agreement with the experimental data. Moreover, it is obtained that simulations in the framework of PCM do not provide a fair description of the real system. Importantly, these results may pave the way for better descriptions of some optoelectronic properties of interest in polymer/solvent systems. Graphical Abstract ᅟ.

  9. Microwave Power Spectra of Stimulated Phonon Emission and Spatio-Temporal Structures in an Optical-Wavelengths Acoustic Laser (Paramagnetic Phaser)

    CERN Document Server

    Makovetskii, D N

    2012-01-01

    A problem of self-organized motions in solid-state nonequilibrium media has been studied experimentally using methods of quantum acoustics. Generalized Poincare cross-sections of microwave power spectra (MPS) have been obtained in an optical-wavelengths acoustic laser (paramagnetic phaser) based on ruby crystal. Considerable narrowing of MPS and their autowave-like superslow motion have been observed under conditions of periodical pump modulation beyond the region of the phaser relaxation resonance. Some preliminar experimental results of this work were published in: Solid State Communications, Vol.90, No.8, P.501 (1994). An interpretation of the experimental data see arXiv:1101.0482v1 ; arXiv:cond-mat/0410460v1 ; arXiv:cond-mat/0303188v1 .

  10. Photoluminescence spectra of an optically pumped erbium-doped micro-cavity with SiO{sub 2}/TiO{sub 2} distributed Bragg reflectors

    Energy Technology Data Exchange (ETDEWEB)

    Boucher, Yann G., E-mail: boucher@enib.f [ENIB/RESO, CS 73862, F-29238 Brest cedex 3 (France); Chiasera, Alessandro, E-mail: achiaser@science.unitn.i [CNR-IFN, CSMFO, Via alla Cascata 56/C, I-38050 Povo (Trento) (Italy); Ferrari, Maurizio [CNR-IFN, CSMFO, Via alla Cascata 56/C, I-38050 Povo (Trento) (Italy); Righini, Giancarlo C., E-mail: direttore.dmd@cnr.i [CNR, Department of Materials and Devices, I-00185 Roma, and Nello Carrara Institute of Applied Physics, I-50019 Sesto Fiorentino (Florence) (Italy)

    2009-12-15

    We investigate the spectral properties of an optically pumped micro-cavity made of a half-wavelength erbium-doped SiO{sub 2} layer sandwiched between two six-period SiO{sub 2}/TiO{sub 2} distributed Bragg reflectors. The structure, grown by the rf-sputtering technique, is characterised by its transmittance and photoluminescence (PL) spectra. The pump laser operates at {lambda}{sub P}=514.5 nm under optimized oblique incidence. Extended (3x3) transfer matrix formalism including sources leads to an analytical description of the spectral and angular properties of the emitted field, for both states of polarization. As expected, a pronounced enhancement of the PL emission around the cavity resonance is observed.

  11. Observation of an excess at 30 GeV in the opposite sign di-muon spectra of ${\\rm Z} \\to b\\overline{ b} + {\\rm X}$ events recorded by the ALEPH experiment at LEP

    CERN Document Server

    Heister, Arno

    2016-01-01

    The re-analysis of the archived data recorded at the ${\\rm Z}^{0}$ resonance by the ALEPH experiment at LEP during the years 1992-1995 shows an excess in the opposite sign di-muon mass spectra at 30.40 GeV in events containing b quarks. The excess has a natural width of 1.78 GeV. A compatible but smaller excess is visible in the opposite di-electron mass spectrum as well.

  12. Magneto-optical Kerr spectra and magnetic properties of Co-substituted M-type strontium ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Liu Xiansong, E-mail: xiansongliu@ahu.edu.cn [Engineering Technology Research Center of Magnetic Materials, Anhui Province, School of Physics and Materials Science, Anhui University, Hefei 230039 (China); Fernandez-Garcia, Lucia [Centro de Investigacion en Nanomateriales y Nanotecnologia (CINN), Consejo superior de Investigaciones Cientificas (CSIC) - Universidad de Oviedo UO - Principado de Asturias, Parque Tecnologico de Asturias, 33428 Llanera, Asturias (Spain); Hu Feng; Zhu Deru [Engineering Technology Research Center of Magnetic Materials, Anhui Province, School of Physics and Materials Science, Anhui University, Hefei 230039 (China); Suarez, Marta; Menendez, Jose Luis [Centro de Investigacion en Nanomateriales y Nanotecnologia (CINN), Consejo superior de Investigaciones Cientificas (CSIC) - Universidad de Oviedo UO - Principado de Asturias, Parque Tecnologico de Asturias, 33428 Llanera, Asturias (Spain)

    2012-04-16

    Highlights: Black-Right-Pointing-Pointer Prepare single phase ferrites by substituted with Co{sup 2+}. Black-Right-Pointing-Pointer The magnetic properties were remarkably modified. Black-Right-Pointing-Pointer A very noticeable Kerr activity was obtained for the Co-substituted ferrites. - Abstract: M-type strontium ferrites SrFe{sub 12-x}Co{sub x}O{sub 19} (x = 0, 0.05, 0.10, 0.15, 0.20) were prepared by the conventional ceramic technology. The structure, magnetic properties and magneto-optical Kerr activity of the samples were investigated by X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and magneto-optical ellipsometry, respectively. X-ray diffraction showed that all the samples were single phase ferrites. The magnetic properties, especially the coercive field, were remarkably modified due to the substitution of cobalt. Most importantly, a noticeable Kerr activity was demonstrated in the Co-substituted M-type strontium ferrites with x = 0.20.

  13. An observation of further splitting of the new fine-structure in magneto-optical spectra of CuO

    Science.gov (United States)

    Masumi, Taizo; Imanaka, Yasutaka; Takehana, Kanji; Yamaguchi, Hiroyuki; Kido, Giyuu

    2001-04-01

    Regarding CuO first in 1998 (Masumi et al., J. Phys. Soc. Japan 67 (1998) 67), we reported an observation of the new fine structures near the optical absorption edge below 90 K. They consist of two sharp peaks A and B at EA=1.57511 eV and EB=1.58097 eV, respectively, at T=7 K. Two peaks emerge only below 90 K and their integrated intensity remarkably grows below 90 and 60 K. Here, we have started a magneto-optical study to seek further natures of these fine structures in the absorption edge of CuO by applying high magnetic fields up to B=25 T with a resolution of δE=1.24 meV, Δ ν=1 cm -1. Peaks A and B exhibit rather little variations up to 10 T. Above 12 T, however, there starts to emerge a potential splitting in the peak A, whereas peak B simply indicates a broadening. Finally, we clearly recognize new finer structures due to splitting in peak A at B=25 T. These results reveal a possibility of an existence of further peculiar magnetic characters in CuO even at lower temperature side besides the antiferromagnetic transitions at TN1=213 K and TN2=230 K.

  14. Polar interface and surface optical vibration spectra in multi-layer wurtzite quantum wires:transfer matrix method

    Institute of Scientific and Technical Information of China (English)

    Zhang Li

    2006-01-01

    The polar interface optical (IO) and surface optical (SO) phonon modes and the corresponding Frohlich electronphonon-interaction Hamiltonian in a freestanding multi-layer wurtzite cylindrical quantum wire (QWR) are derived and studied by employing the transfer matrix method in the dielectric continuum approximation and Loudon's uniaxial crystal model. A numerical calculation of a freestanding wurtzite GaN/AlN QWR is performed. The results reveal that for a relatively large azimuthal quantum number m or wave-number kz in the free z-direction, there exist two branches of IO phonon modes localized at the interface, and only one branch of SO mode localized at the surface in the system.The degenerating behaviours of the IO and SO phonon modes in the wurtzite QWR have also been clearly observed for a smallkz or m. The limiting frequency properties of the IO and SO modes for large kz and m have been explained reasonably from the mathematical and physical viewpoints. The calculations of electron-phonon coupling functions show that the high-frequency IO phonon branch and SO mode play a more important role in the electron-phonon interaction.

  15. Synthesis and optical storage properties of a thiophene-based holographic recording

    DEFF Research Database (Denmark)

    Matharu, Avtar; Jeeva, S.; Huddleston, P.R.;

    2007-01-01

    The results of the fabrication and optical data storage characteristics of a novel azothiophene polyester 9 for potential holographic storage are reported. The polyester is derived from an azothiophene diol 1 and diphenyl phthalate 8 via in vacuo melt transesterification. Inclusion of a 5-methoxy-2......-thienyl moiety generates a trans pi-pi* transition centered close to 405 nm. An investigation of the optical data storage characteristics of a solution cast film of azopolyester with a thickness of 65 mm is summarised. The optical anisotropy induced by a 532 nm frequency doubled YAG laser and probed...... at a wavelength of 633 nm outside the absorption band with a polarimeter reveals a very high induced anisotropy of 7 rad ( laser intensity, 250 mW cm(-2)). The calculated birefringence of the film is 0.02 per micron. Maximum anisotropy is reached after approximately 70 s of irradiation. The induced anisotropy...

  16. Optical recording in functional polymer nanocomposites by multi-beam interference holography

    Science.gov (United States)

    Zhuk, Dmitrij; Burunkova, Julia; Kalabin, Viacheslav; Csarnovics, Istvan; Kokenyesi, Sandor

    2017-05-01

    Our investigations relate to the development of new polymer nanocomposite materials and technologies for fabrication of photonic elements like gratings, integrated elements, photonic crystals. The goal of the present work was the development and application of the multi-beam interference method for one step, direct formation of 1-, 2- or even 3D photonic structures in functional acrylate nanocomposites, which contain SiO2 and Au nanoparticles and which are sensitized to blue and green laser illumination. The presence of gold nanoparticles and possibility to excite plasmonic effects can essentially influence the polymerization processes and the spatial redistribution of nanoparticles in the nanocomposite during the recording. This way surface and volume phase reliefs can be recorded. It is essential, that no additional treatments of the material after the recording are necessary and the elements possess high transparency, are stable after some relaxation time. New functionalities can be provided to the recorded structures if luminescent materials are added to such materials.

  17. Modelling telluric line spectra in the optical and infrared with an application to VLT/X-Shooter spectr

    CERN Document Server

    Rudolf, N; Schneider, P C; Schmitt, J H M M

    2016-01-01

    Earth's atmosphere imprints a large number of telluric absorption and emission lines on astronomical spectra, especially in the near infrared, that need to be removed before analysing the affected wavelength regions. These lines are typically removed by comparison to A- or B-type stars used as telluric standards that themselves have strong hydrogen lines, which complicates the removal of telluric lines. We have developed a method to circumvent that problem. For our IDL software package tellrem we used a recent approach to model telluric absorption features with the line-by-line radiative transfer model (LBLRTM). The broad wavelength coverage of the X-Shooter at VLT allows us to expand their technique by determining the abundances of the most important telluric molecules H2O, O2, CO2, and CH4 from sufficiently isolated line groups. For individual observations we construct a telluric absorption model for most of the spectral range that is used to remove the telluric absorption from the object spectrum. We remov...

  18. Long-term variability of the optical spectra of NGC 4151: I. Light curves and flux correlations

    CERN Document Server

    Shapovalova, A I; Collin, S; Burenkov, A N; Chavushyan, V H; Bochkarev, N G; Benitz, E; Dultzin-Hacyan, D; Kovacevic, A; Borisov, N; Carrasco, L; Leon-Tavares, J; Mercado, A; Valdés, J R; Vlasuyk, V V; Zhdanova, V E

    2008-01-01

    Results of a long-term spectral monitoring of the active galactic nucleus of NGC 4151 are presented (11 years, from 1996 to 2006). High quality spectra (S/N>50 in the continuum near Halpha and Hbeta) were obtained in the spectral range ~4000 to 7500 \\AA, with a resolution between 5 and 15 A, using the 6-m and the 1-m SAO's telescopes (Russia), the GHAO's 2.1-m telescope (Cananea, Mexico), and the OAN-SPM's 2.1-m telescope (San-Pedro, Mexico). The observed fluxes of the Halpha, Hbeta, Hgamma and HeII emission lines and of the continuum at the observed wavelength 5117 A, were corrected for the position angle, the seeing and the aperture effects. We found that the continuum and line fluxes varied strongly (up to a factor 6) during the monitoring period. The emission was maximum in 1996-1998, and there were two minima, in 2001 and in 2005. The Halpha, Hgamma and He II fluxes were well correlated with the Hbeta flux. We considered three characteristic periods during which the Hbeta and Halpha profiles were similar...

  19. Analysis of Co-spatial UV-optical HST/STIS Spectra of Planetary Nebula NGC 3242

    Science.gov (United States)

    Miller, Timothy R.; Henry, Richard B. C.; Balick, Bruce; Kwitter, Karen B.; Dufour, Reginald J.; Shaw, Richard A.; Corradi, Romano L. M.

    2016-10-01

    This project sought to consider two important aspects of the planetary nebula NGC 3242 using new long-slit HST/STIS spectra. First, we investigated whether this object is chemically homogeneous by spatially dividing the slit into different regions and calculating the abundances of each region. The major result is that the elements of He, C, O, and Ne are chemically homogeneous within uncertainties across the regions probed, implying that the stellar outflow was well-mixed. Second, we constrained the stellar properties using photoionization models computed by CLOUDY and tested the effects of three different density profiles on these parameters. The three profiles tested were a constant density profile, a Gaussian density profile, and a Gaussian with a power-law density profile. The temperature and luminosity were not affected significantly by the choice of density structure. The values for the stellar temperature and luminosity from our best-fit model are {89.7}-4.7+7.3 kK and log(L/L ⊙) = {3.36}-0.22+0.28, respectively. Comparing to evolutionary models on an HR diagram, this corresponds to an initial and final mass of {0.95}-0.09+0.35{M}⊙ and {0.56}-0.01+0.01{M}⊙ , respectively. Based on observations with the NASA/ESA Hubble Space Telescope obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Incorporated, under NASA contract NAS5-26555.

  20. A time-dependent density functional theory (TDDFT) interpretation of the optical spectra of zinc phthalocyanine π-cation and π-anion radicals1

    National Research Council Canada - National Science Library

    Ricciardi, Giampaolo; Rosa, Angela

    2009-01-01

    ...-anion radical prove to be in excellent agreement with the solution spectra and generally in line with deconvolution analyses of solution absorption and magnetic circular dichroism (MCD) spectra...

  1. Connectorization of fibre Bragg grating sensors recorded in microstructured polymer optical fibre

    DEFF Research Database (Denmark)

    Abang, A.; Saez-Rodriguez, D.; Nielsen, Kristian

    2013-01-01

    We describe te production and characterization of FC/PC connectorised fibre Bragg grating sensors in polymer fibre. Sensors were recorded in few-moded and single mode microstructured fibre composed of poly (methyl methacrylate).......We describe te production and characterization of FC/PC connectorised fibre Bragg grating sensors in polymer fibre. Sensors were recorded in few-moded and single mode microstructured fibre composed of poly (methyl methacrylate)....

  2. THEORETICAL RESEARCH OF THE OPTICAL SPECTRA AND EPR PARAMETERS FOR Cs2NaYCl6:Dy3+ CRYSTAL

    Science.gov (United States)

    Dong, Hui-Ning; Dong, Meng-Ran; Li, Jin-Jin; Li, Deng-Feng; Zhang, Yi

    2013-09-01

    The calculated EPR parameters are in reasonable agreement with the observed values. The important material Cs2NaYCl6 doped with rare earth ions have received much attention because of its excellent optical and magnetic properties. Based on the superposition model, in this paper the crystal field energy levels, the electron paramagnetic resonance parameters g factors of Dy3+ and hyperfine structure constants of 161Dy3+ and 163Dy3+ isotopes in Cs2NaYCl6 crystal are studied by diagonalizing the 42 × 42 energy matrix. In the calculations, the contributions of various admixtures and interactions such as the J-mixing, the mixtures among the states with the same J-value, and the covalence are all considered. The calculated results are in reasonable agreement with the observed values. The results are discussed.

  3. Thomson develops new optical reader, digital switching system: Gigadisc reader recorder

    Science.gov (United States)

    Levy, D.

    1984-01-01

    A digital optical disk, newly developed by Thomson of France, is announced. The disk, which has a greatly enhanced data storage capacity, is capable of capturing a leading position in information processing and business communications systems by overtaking the share of the market now held by the flexible magnetic disk. A marketing strategy is presented.

  4. Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye

    Science.gov (United States)

    Cambiasso, Javier; Garate, Hernan; D'Accorso, Norma; Ledesma, Silvia; Goyanes, Silvia

    2015-11-01

    A novel photoaddressable copolymer with low glass transition temperature was synthesised and its optical properties were studied. The photoresponsive material was obtained from chemical modification of a poly(styrene-co-acrylic acid) copolymer. A holographic polarization grating was recorded in the material and was monitored by measuring its diffraction efficiency. It is shown that the holographic grating stored in the material is highly stable in time, despite the fact that the polymer glass transition temperature is near room temperature. This stability is a consequence of electrostatic interactions between the azo-groups and the carboxylic substituent group of the main polymer chain.

  5. Optical gain spectra of 1.55 μm GaAs/GaN.58yAs1-1.58yBiy/GaAs single quantum well

    Science.gov (United States)

    Guizani, I.; Bilel, C.; Habchi, M. M.; Rebey, A.

    2017-02-01

    The optical gain spectra of doped lattice-matched GaNAsBi-based single quantum well (SQW) was theoretically investigated using a (16 × 16) band anti-crossing (BAC) model combined with self-consistent calculation. For the sake of comparison, we computed the optical gain of both (i-n-i) and (i-p-i) doped well types in GaAs/GaNAsBi/GaAs quantum structure. The highest obtained material gain Gmax was 1.2 ×104 cm-1 for (i-n-i) type doped with N2Dd = 2.5 ×1012 cm-2 . We proposed investigating the p-i-n type structure to enhance the optical performance of GaAs/GaNAsBi/GaAs SQW. The Bi composition was optimized in order to obtain Te 1 - h 1 = 1.55 μ m . The effect of well width on optical gain spectra was also discussed.

  6. Multi-mirror imaging optics for low-loss transport of divergent neutron beams and tailored wavelength spectra

    CERN Document Server

    Zimmer, Oliver

    2016-01-01

    A neutron optical transport system is proposed which comprises nested short elliptical mirrors located halfway between two common focal points M and M'. It images cold neutrons from a diverging beam or a source with finite size at M by single reflections onto a spot of similar size at M'. Direct view onto the neutron source is blocked by a central absorber with little impact on the transported solid angle. Geometric neutron losses due to source size can be kept small using modern supermirrors and distances M-M' of a few tens of metres. Very short flat mirrors can be used in practical implementations. Transport with a minimum of reflections remedies losses due to multiple reflections that are common in long elliptical neutron guides. Moreover, well-defined reflection angles lead to new possibilities for enhancing the spectral quality of primary beams, such as clear-cut discrimination of short neutron wavelengths or beam monochromation using bandpass supermirrors. Multi-mirror imaging systems may thus complemen...

  7. [A simple highly sensitive recording microspectrophotometer].

    Science.gov (United States)

    Govardovskiĭ, V I; Zueva, L V

    1988-04-01

    A design of the recording microspectrophotometer is described. The instrument possesses an absolutely flat base line and quantum-noise limited detection threshold. Two principal elements of the design are the "jumping" stage, and the logarithmic amplifier with the phase-sensitive detector which converts the photomultiplier output into the optical density signal. The performance of the instrument is illustrated by the recordings of visual pigment spectra in single photoreceptors.

  8. Circular polarization intrinsic optical signal recording of stimulus-evoked neural activity.

    Science.gov (United States)

    Lu, Rong-Wen; Zhang, Qiu-Xiang; Yao, Xin-Cheng

    2011-05-15

    Linear polarization intrinsic optical signal (LP-IOS) measurement can provide sensitive detection of neural activities in stimulus-activated neural tissues. However, the LP-IOS magnitude and signal-to-noise ratio (SNR) are highly correlated with the nerve orientation relative to the polarization plane of the incident light. Because of the complexity of orientation dependency, LP-IOS optimization and outcome interpretation are time consuming and complicated. In this study, we demonstrate the feasibility of circular polarization intrinsic optical signal (CP-IOS) measurement. Our theoretical modeling and experimental investigation indicate that CP-IOS magnitude and SNR are independent from the nerve orientation. Therefore, CP-IOS promises a practical method for polarization IOS imaging of complex neural systems.

  9. Restocking the optical designers' toolbox for next-generation wearable displays (Presentation Recording)

    Science.gov (United States)

    Kress, Bernard C.

    2015-09-01

    Three years ago, industry and consumers learned that there was more to Head Mounted Displays (HMDs) than the long-lasting but steady market for defense or the market for gadget video player headsets: the first versions of Smart Glasses were introduced to the public. Since then, most major consumer electronics companies unveiled their own versions of Connected Glasses, Smart Glasses or Smart Eyewear, AR (Augmented Reality) and VR (Virtual Reality) headsets. This rush resulted in the build-up of a formidable zoo of optical technologies, each claiming to be best suited for the task on hand. Today, the question is not so much anymore "will the Smart Glass market happen?" but rather "which optical technologies will be best fitted for the various declinations of the existing wearable display market," one of the main declination being the Smart Glasses market.

  10. Optical nanoscopy to reveal structural and functional properties of liver cells (Presentation Recording)

    Science.gov (United States)

    McCourt, Peter; Huser, Thomas R.; Sørensen, Karen K.; Øie, Cristina I.; Mönkemöller, Viola; Ahluwalia, Balpreet S.

    2015-08-01

    The advent of optical nanoscopy has provided an opportunity to study fundamental properties of nanoscale biological functions, such as liver sinusoidal endothelial cells (LSEC) and their fenestrations. The fenestrations are nano-pores (50-200 nm) on the LSEC plasma membrane that allow free passage of molecules through cells. The fenestrated LSEC also hase a voracious appetite for waste molecules, viruses and nanoparticles. LSEC daily remove huge amounts of waste, nanoparticles and virus from the blood. Pharmaceuticals also need to pass through these fenestrations to be activated (e.g. cholesterol reducing statins) or detoxified by hepatocytes. And, when we age, our LSEC fenestrations become smaller and fewer. Today, we study these cells and structures using either conventional light microscopy on living cells, or high-resolution (but static) methods such as transmission and scanning electron microscopy on fixed (i.e. dead) tissue. Such methods, while very powerful, yield no real time information about the uptake of virus or nanoparticles, nor any information about fenestration dynamics. Therefore, to study LS-SEC, we are now using optical nanoscopy methods, and developing our own, to map their functions in 4 dimensions. Attaining this goal will shed new light on the cell biology of the liver and how it keeps us alive. This paper describes the challenges of studying LS-SEC with light microscopy, as well as current and potential solutions to this challenge using optical nanoscopy.

  11. Mechanochemical synthesis of Ni(OH){sub 2} and the decomposition to NiO nanoparticles: Thermodynamic and optical spectra

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Aidong [School of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Li, Xiaoyu; Zhou, Zheng [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China); Ouyang, Jing, E-mail: jingouyang@csu.edu.cn [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China); Yang, Huaming, E-mail: hmyang@csu.edu.cn [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China)

    2014-07-05

    Highlights: • Mechanochemical route is efficient to prepare NiO nanoparticles. • Thermodynamic in the formation procedure is carefully investigated. • Size of the NiO nanoparticles can be easily controlled by changing heat temperature. - Abstract: Nickel hydroxide (Ni(OH){sub 2}) was prepared through a mechanochemical route using simple manual milling. NiO nanoparticles were obtained through subsequent calcinations. X-ray diffraction (XRD), differential thermal analysis and thermal gravimetric (DTA/TG), transmission electronic microscopy (TEM), Fourier transforming infrared spectroscopy (FTIR) and ultraviolet to visible spectroscopy (UV–vis) were adopted to characterize the structural, morphological, and optical properties of the obtained NiO products. Intensive study to the DTA curves of the Ni(OH){sub 2} precursor was conducted to understand the thermal behavior and derive the activation energy, for which the Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose methods were introduced and were applied respectively. The average activation energy required to de-composite the Ni(OH){sub 2} precursor in ambient condition was 117.8 kJ/mol, which determined that the decomposition is controlled by the chemical reaction. NiO with cubic shape was obtained. Size of the products increased from 8.3 nm at 350 °C to 43.4 nm at 600 °C. Carbonates were found to co-exist with the product, which were generated in the preparing procedures. Band gap energy of the NiO was in the range of 3.30 ± 0.11 eV, which have no obvious relationship with the preparing conditions.

  12. Co/Pt and Co/Pd multilayers as a new class of magneto-optical recording materials

    Science.gov (United States)

    Zeper, W. B.; Greidanus, Franciscus J. A. M.; van Kesteren, H. W.; Jacobs, Ben A. J.; Spruit, J. H. M.; Carcia, Peter F.

    1990-08-01

    In this paper we give an overview of the magnetic and magneto-optical properties of Co/Pt and, to a less extent, Co/Pd multilayers as optimized for magneto-optical storage applications. The Co layers should be very thin, i.e. about 4 A , and the Pt layers about 10-20 A to achieve a 100 % remanent layer with perpendicular magnetic anisotropy and high coercivity (80-100 kA/m). Furthermore, the hysteresis loop becomes rectangular for total film thicknesses below about 20 nm. We measured the optical properties as a function of the wavelength of the light and calculated the figure of merit at three wavelengths (820, 633 and 410 nm) for various disk structures. Optimal figures of merit are obtained for film thicknesses below 20 nm, i.e. thicknesses that are optimum for the magnetic properties. The figure of merit at A. = 820 am for Co/Pt is comparable to that of GdTbFe and increases towards shorter wavelengths which favor higher-density recording. We discuss the recording performance using Lorentz images of the written domain patterns. Very regularly shaped domains can be written at normal writing conditions, i.e. at a laser power of 5-10 mW and fields of 25 kA/m. The highest carrier-to-noise ratio measured for Co/Pt is 51 dB (375 kHz carrier, 1.4 m/s, 10 kHz bandwidth). Aging experiments in dry oxygen-nitrogen atmosphere showed that Co/Pt multilayers are chemically stable up to 1 50 °C . Finally, no change in carrier-to-noise ratio is observed for Co/Pt multilayers with a Curie temperature below 300 °C after 2x104 write/read/erase cycles.

  13. Optical recording of neuronal activity with a genetically-encoded calcium indicator in anesthetized and freely moving mice

    Directory of Open Access Journals (Sweden)

    Henry Lütcke

    2010-04-01

    Full Text Available Fluorescent calcium (Ca2+ indicator proteins (FCIPs are promising tools for functional imaging of cellular activity in living animals. However, they have still not reached their full potential for in vivo imaging of neuronal activity due to limitations in expression levels, dynamic range, and sensitivity for reporting action potentials. Here, we report that viral expression of the ratiometric Ca2+ sensor yellow cameleon 3.60 (YC3.60 in pyramidal neurons of mouse barrel cortex enables in vivo measurement of neuronal activity with high dynamic range and sensitivity across multiple spatial scales. By combining juxtacellular recordings and two-photon imaging in vitro and in vivo, we demonstrate that YC3.60 can resolve single action potential (AP-evoked Ca2+ transients and reliably reports bursts of APs with negligible saturation. Spontaneous and whisker-evoked Ca2+ transients were detected in individual apical dendrites and somata as well as in local neuronal populations. Moreover, bulk measurements using wide-field imaging or fiber-optics revealed sensory-evoked YC3.60 signals in large areas of the barrel field. Fiber-optic recordings in particular enabled measurements in awake, freely moving mice and revealed complex Ca2+ dynamics, possibly reflecting different behavior-related brain states. Viral expression of YC3.60 - in combination with various optical techniques - thus opens a multitude of opportunities for functional studies of the neural basis of animal behavior, from dendrites to the levels of local and large-scale neuronal populations.

  14. Depth Profile of Optically Recorded Patterns in Light-Sensitive Liquid Crystal Elastomers

    CERN Document Server

    Gregorc, Marko; Domenici, Valentina; Ambrožič, Gabriela; Drevenšek-Olenik, Irena; Fally, Martin; Čopič, Martin

    2011-01-01

    We investigated nonlinear absorption and photobleaching processes in a liquid crystal elastomer (LCE) doped with light-sensitive azobenzene moiety. A conventional one-dimensional holographic grating was recorded in the material with the use of two crossed UV laser beams and the angular dependence of the diffraction efficiency in the vicinity of the Bragg peak was analyzed. These measurements gave information on the depth to which trans to cis isomerisation had progressed into the sample as a function of the UV irradiation time. Using a numerical model that takes into account the propagation of writing beams and rate equations for the local concentration of the absorbing trans conformer, we computed the expected spatial distribution of the trans and cis conformers and the shape of the corresponding Bragg diffraction peak for different irradiation doses. Due to residual absorption of the cis conformers the depth of the recording progresses logarithmically with time and is limited by the thermal relaxation from ...

  15. Application of non-invasive optical monitoring methodologies to follow and record painting cleaning processes

    Science.gov (United States)

    Fontana, R.; Dal Fovo, A.; Striova, J.; Pezzati, L.; Pampaloni, E.; Raffaelli, M.; Barucci, M.

    2015-11-01

    The cleaning of painted artworks, i.e. the critical operation whereby materials are selectively removed from a painted surface by partial thinning or complete elimination of varnish, is one of the most debated conservation operations, being an irreversible process, which may result in chromatic and morphological variations in the painted surface. Due to ageing, the upper layer is subject to darkening and yellowing because of blanching and fading from ultraviolet exposure, dust deposition, and overpainted layers due, for instance, to restoration interventions. This degradation can either alter the original appearance of painting polychromy or cause mechanical failure of the finishes. To address these adverse conditions, a process of examination and analysis is critical to the definition and interpretation of the varnish layer. When investigating the ageing process of old paintings, it is of great importance to obtain insight into the painting technique as practiced in the past, and the first step in gaining this knowledge is, to a large extent, based on the study of the varnish film. An effective control of the process and objective evaluation of its outcome requires therefore instrumental/analytical support. The present study illustrates the successful application of non-invasive optical techniques—such as colorimetry, multispectral reflectography, laser scanning micro-profilometry, and optical coherence tomography—to the monitoring of an Italian fourteenth-century painting cleaning process. Results presented here confirm that optical techniques play a pivotal role in artwork diagnostics, especially with regard to conservation operations, while also indicating their validity when applied to the monitoring of the cleaning process.

  16. A spectrograph for studying pulsed infrared laser spectra

    Energy Technology Data Exchange (ETDEWEB)

    Gorlin, G.B.; Filippov, V.N.; Komissarova, I.I.; Ostrobskii, U.I.; Ostrovskaya, G.V.; Paritskii, L.G.; Shevova, E.N.

    1982-01-01

    A spectrograph used to record the pulsed infrared spectra in a wavelength range which exceeds the sensitivity limits of standard photographic materials is described. The spectrograph is built using a standard scheme with mirror optics (f = 60 centimeters) and a diffraction grating 50 lines per millimeter. The recording process involves exposing the photomaterial to a pulsed emission source which is synchronized with a reference infrared emission source created using a purple relief photomaterial. The recording sensitivity is 10exp-2 joules per square centimeter. An interlaced pulsed CO2 laser emission spectrum is derived using the spectrograph.

  17. DREXONTM Optical Memory Media For Laser Recording And Archival Data Storage

    Science.gov (United States)

    Drexler, J.

    1981-06-01

    The objective of this paper is to present the concept, description, and characteristics of a new class of direct-read-after-write (DRAW) reflective laser recording material which has been given the tradename DREXONTM. Information is recorded by thermal melting of the media surface. The material consists of an organic film containing dispersed metal particles which have such a high volume concentration that the surface has a mirrorlike appearance. However, the particles do not touch one another; and, therefore, the surface is electrically nonconductive. When recording, the laser-beam energy is absorbed by the metal particles, which rise in temperature and cause melting of the organic film at temperatures in the range of 200°C. This melting creates spots of low reflectivity in a field of high reflectivity. The metal particles do not melt since their melting temperature is much highter than that of the underlying organic film. It is possible that one version of the media could achieve archival life of a hundred years. This version comprises three ingredients, all of which have rated archival lives of hundreds of years: (1) cross-linked, photographic-quality gelatin, (2) filamentary silver crystals, and (3) spheroidal silver crystals. This archival version of the media is produced from special, fine-grained silver-halide emulsions.

  18. Optical spectra of the silicon-terminated carbon chain radicals SiC{sub n}H (n = 3,4,5)

    Energy Technology Data Exchange (ETDEWEB)

    Kokkin, D. L.; Reilly, N. J.; McCarthy, M. C., E-mail: mccarthy@cfa.harvard.edu [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States); School of Engineering and Applied Sciences, Harvard University, 29 Oxford St., Cambridge, Massachusetts 02138 (United States); Fortenberry, R. C.; Crawford, T. D. [Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2014-07-28

    The gas-phase optical spectra of three silicon-terminated carbon chain radicals, SiC{sub n}H (n = 3 − 5), formed in a jet-cooled discharge of silane and acetylene, have been investigated by resonant two-color two-photon ionization and laser-induced fluorescence/dispersed fluorescence. Analysis of the spectra was facilitated by calculations performed using equation-of-motion coupled cluster methods. For SiC{sub 3}H and SiC{sub 5}H, the observed transitions are well-described as excitations from a {sup 2}Π ground state to a {sup 2}Σ state, in which vibronic coupling, likely involving a higher-lying Π state with a very large predicted f-value (close to unity), is persistent. The lowest {sup 2}Σ states of both species are characterized by a rare silicon triple bond, which was identified previously [T. C. Smith, H. Y. Li, D. J. Clouthier, C. T. Kingston, and A. J. Merer, J. Chem. Phys. 112, 3662 (2000)] in the lowest {sup 2}Σ state of SiCH. Although a strong Π − Π transition is predicted for SiC{sub 4}H, the observed spectrum near 505 nm more likely corresponds to excitation to a relatively dark Σ state which is vibronically coupled to a nearby Π state. In contrast to the chains with an odd number of carbon atoms, which exhibit relatively sharp spectral features and lifetimes in the 10–100 ns range, SiC{sub 4}H shows intrinsically broadened spectral features consistent with a ∼100 fs lifetime, and a subsequent long-lived decay (>50 μs) which we ascribe to mixing with a nearby quartet state arising from the same electronic configuration. The spin-orbit coupling constants for both SiC{sub 3}H and SiC{sub 5}H radicals were determined to be approximately 64 cm{sup −1}, similar to that of SiCH (69.8 cm{sup −1}), suggesting that the unpaired electron in these species is localized on the silicon atom. Motivated by the new optical work, the rotational spectrum of linear SiC{sub 3}H was detected by cavity Fourier-transform microwave spectroscopy in

  19. Development and characterization of thermally stable electro-optic polymers and devices (Presentation Recording)

    Science.gov (United States)

    Otomo, Akira; Aoki, Isao; Yamada, Chiyumi; Yamada, Toshiki

    2015-10-01

    Electro-optic (EO) polymers are key materials for next generation optical communications not only in wide area network but also in local area and storage area network because EO polymer modulator can be operated at fast speed more than 100 GHz with low energy consumption and can be miniaturized in combination with silicon photonics. In practical applications, thermal stability is one of the important issues to be considered for developing EO polymers. Since EO activity of the polymer is proportional to dipole orientation factor of the EO moieties, electric field assisted poling around glass transition temperature (Tg) of the polymer is necessary. However, the poled order of the molecules relaxes gradually at finite temperature, and then EO activity decreases after long period of time. We have successfully developed thermally stable EO polymers that have high-Tg up to 180 °C. They show excellent thermal stability with the Telcordia thermal test. Thermal stability is also characterized by thermally stimulated depolarization current (TSDC) measurement. Analyzing the TSDC, we can estimate the activation energy and relaxation time of polarization at any temperature. We will discuss thermal stability of the high-Tg EO polymers and devices.

  20. Dust aerosol, clouds, and the atmospheric optical depth record over 5 Mars years of the Mars Exploration Rover mission

    CERN Document Server

    Lemmon, Mark T; Bell, James F; Smith, Michael D; Cantor, Bruce A; Smith, Peter H

    2014-01-01

    Dust aerosol plays a fundamental role in the behavior and evolution of the Martian atmosphere. The first five Mars years of Mars Exploration Rover data provide an unprecedented record of the dust load at two sites. This record is useful for characterization of the atmosphere at the sites and as ground truth for orbital observations. Atmospheric extinction optical depths have been derived from solar images after calibration and correction for time-varying dust that has accumulated on the camera windows. The record includes local, regional, and globally extensive dust storms. Comparison with contemporaneous thermal infrared data suggests significant variation in the size of the dust aerosols, with a 1 {\\mu}m effective radius during northern summer and a 2 {\\mu}m effective radius at the onset of a dust lifting event. The solar longitude (LS) 20-136{\\deg} period is also characterized by the presence of cirriform clouds at the Opportunity site, especially near LS=50 and 115{\\deg}. In addition to water ice clouds, ...

  1. Dust Aerosol, Clouds, and the Atmospheric Optical Depth Record over 5 Mars Years of the Mars Exploration Rover Mission

    Science.gov (United States)

    Lemmon, Mark T.; Wolff, Michael J.; Bell, James F., III; Smith, Michael D.; Cantor, Bruce A.; Smith, Peter H.

    2014-01-01

    Dust aerosol plays a fundamental role in the behavior and evolution of the Martian atmosphere. The first five Mars years of Mars Exploration Rover data provide an unprecedented record of the dust load at two sites. This record is useful for characterization of the atmosphere at the sites and as ground truth for orbital observations. Atmospheric extinction optical depths have been derived from solar images after calibration and correction for time-varying dust that has accumulated on the camera windows. The record includes local, regional, and globally extensive dust storms. Comparison with contemporaneous thermal infrared data suggests significant variation in the size of the dust aerosols, with a 1 micrometer effective radius during northern summer and a 2 micrometer effective radius at the onset of a dust lifting event. The solar longitude (L (sub s)) 20-136 degrees period is also characterized by the presence of cirriform clouds at the Opportunity site, especially near LS = 50 and 115 degrees. In addition to water ice clouds, a water ice haze may also be present, and carbon dioxide clouds may be present early in the season. Variations in dust opacity are important to the energy balance of each site, and work with seasonal variations in insolation to control dust devil frequency at the Spirit site.

  2. Ultrafast chirped optical waveform recording using referenced heterodyning and a time microscope

    Science.gov (United States)

    Bennett, Corey Vincent

    2010-06-15

    A new technique for capturing both the amplitude and phase of an optical waveform is presented. This technique can capture signals with many THz of bandwidths in a single shot (e.g., temporal resolution of about 44 fs), or be operated repetitively at a high rate. That is, each temporal window (or frame) is captured single shot, in real time, but the process may be run repeatedly or single-shot. This invention expands upon previous work in temporal imaging by adding heterodyning, which can be self-referenced for improved precision and stability, to convert frequency chirp (the second derivative of phase with respect to time) into a time varying intensity modulation. By also including a variety of possible demultiplexing techniques, this process is scalable to recoding continuous signals.

  3. Ultrafast chirped optical waveform recorder using referenced heterodyning and a time microscope

    Science.gov (United States)

    Bennett, Corey Vincent [Livermore, CA

    2011-11-22

    A new technique for capturing both the amplitude and phase of an optical waveform is presented. This technique can capture signals with many THz of bandwidths in a single shot (e.g., temporal resolution of about 44 fs), or be operated repetitively at a high rate. That is, each temporal window (or frame) is captured single shot, in real time, but the process may be run repeatedly or single-shot. This invention expands upon previous work in temporal imaging by adding heterodyning, which can be self-referenced for improved precision and stability, to convert frequency chirp (the second derivative of phase with respect to time) into a time varying intensity modulation. By also including a variety of possible demultiplexing techniques, this process is scalable to recoding continuous signals.

  4. Effects of higher order aberrations on beam shape in an optical recording system

    Science.gov (United States)

    Wang, Mark S.; Milster, Tom D.

    1992-01-01

    An unexpected irradiance pattern in the detector plane of an optical data storage system was observed. Through wavefront measurement and scalar diffraction modeling, it was discovered that the energy redistribution is due to residual third-order and fifth-order spherical aberration of the objective lens and cover-plate assembly. The amount of residual aberration is small, and the beam focused on the disk would be considered diffraction limited by several criteria. Since the detector is not in the focal plane, even this small amount of aberration has a significant effect on the energy distribution. We show that the energy redistribution can adversely affect focus error signals, which are responsible for maintaining sub-micron spot diameters on the spinning disk.

  5. RECORDING AND MODELLING OF MONUMENTS' INTERIOR SPACE USING RANGE AND OPTICAL SENSORS

    Directory of Open Access Journals (Sweden)

    C. Georgiadis

    2016-06-01

    Full Text Available Three dimensional modelling of artefacts and building interiors is a highly active research field in our days. Several techniques are being utilized to perform such a task, spanning from traditional surveying techniques and photogrammetry to structured light scanners, laser scanners and so on. New technological advancements in both hardware and software create new recording techniques, tools and approaches. In this paper we present a new recording and modelling approach based on the SwissRanger SR4000 range camera coupled with a Canon 400D dSLR camera. The hardware component of our approach consists of a fixed base, which encloses the range and SLR cameras. The two sensors are fully calibrated and registered to each other thus we were able to produce colorized point clouds acquired from the range camera. In this paper we present the initial design and calibration of the system along with experimental data regarding the accuracy of the proposed approach. We are also providing results regarding the modelling of interior spaces and artefacts accompanied with accuracy tests from other modelling approaches based on photogrammetry and laser scanning.

  6. Recording and Modelling of MONUMENTS' Interior Space Using Range and Optical Sensors

    Science.gov (United States)

    Georgiadis, Charalampos; Patias, Petros; Tsioukas, Vasilios

    2016-06-01

    Three dimensional modelling of artefacts and building interiors is a highly active research field in our days. Several techniques are being utilized to perform such a task, spanning from traditional surveying techniques and photogrammetry to structured light scanners, laser scanners and so on. New technological advancements in both hardware and software create new recording techniques, tools and approaches. In this paper we present a new recording and modelling approach based on the SwissRanger SR4000 range camera coupled with a Canon 400D dSLR camera. The hardware component of our approach consists of a fixed base, which encloses the range and SLR cameras. The two sensors are fully calibrated and registered to each other thus we were able to produce colorized point clouds acquired from the range camera. In this paper we present the initial design and calibration of the system along with experimental data regarding the accuracy of the proposed approach. We are also providing results regarding the modelling of interior spaces and artefacts accompanied with accuracy tests from other modelling approaches based on photogrammetry and laser scanning.

  7. Effect of metal nanoparticles on energy spectra and optical properties of peripheral light-harvesting LH2 complexes from photosynthetic bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Goliney, I.Yu., E-mail: igoliney@kinr.kiev.ua [Institute for Nuclear Research, National Academy of Science of Ukraine, 47 Nauki pr., 03680 Kyiv (Ukraine); Sugakov, V.I. [Institute for Nuclear Research, National Academy of Science of Ukraine, 47 Nauki pr., 03680 Kyiv (Ukraine); Valkunas, L. [Center for Physical Sciences and Technology, Savanoriu Ave. 231, 02300 Vilnius (Lithuania); Department of Theoretical Physics, Vilnius University, Sauletekio 9, Build. 3, 10222 Vilnius (Lithuania); Vertsimakha, G.V. [Institute for Nuclear Research, National Academy of Science of Ukraine, 47 Nauki pr., 03680 Kyiv (Ukraine)

    2012-08-24

    Highlights: Black-Right-Pointing-Pointer Excitons of light-harvesting complexes (LH2) hybridize with plasmon modes. Black-Right-Pointing-Pointer Light absorption of LH2 is enhanced by a metal nanoparticle. Black-Right-Pointing-Pointer Using nanoshells allows reaching resonance between molecular and plasmons. Black-Right-Pointing-Pointer Metal nanoparticles introduce additional channel of excitation decay. Black-Right-Pointing-Pointer Light-harvesting may gain from the proper positioning of nanoshells. -- Abstract: The paper explores the theoretical possibility of affecting optical spectra and the quantum yield of the energy transfer in the peripheral light-harvesting complexes (LH2) from photosynthetic bacteria by placing a metal nanoparticle or a nanoshell nearby. An increased probability of the excitonic transition in the LH2 arises due to the borrowing of the oscillator strength from surface plasmons of the metal particle or the nanoshell. While both absorption and quenching of the excitations increase in the vicinity to a metal nanoparticle, having opposite effects, the total yield of the excitation transfer to reaction centers is shown to grow in the certain range of parameters.

  8. Measurement of magic-wavelength optical dipole trap by using the laser-induced fluorescence spectra of trapped single cesium atoms

    Science.gov (United States)

    Liu, Bei; Jin, Gang; Sun, Rui; He, Jun; Wang, Junmin

    2017-07-01

    Based on the multi-level model, we have calculated light shifts for Zeeman states of hyperfine levels of cesium (Cs) 6S1/2 ground state and 6P3/2 excited state.The magic-wavelength linearly-polarized optical dipole trap (ODT) for Cs 6S1/2 F=4, mF=+4 - 6P3/2 F'=5, mF=+5 transition is experimentally constructed and characterized by using the laser-induced fluorescence spectra of trapped single Cs atoms. The magic wavelength is 937.7 nm which produces almost the same light shift for 6S1/2 F=4, mF=+4 ground state and 6P3/2 F'=5, mF=+5 excited state with linearly-polarized ODT laser beam. Compared to undisturbed Cs 6S1/2 F=4, mF=+4 - 6P3/2 F'=5, mF=+5 transition frequency in free space, the differential light shift is less than 0.7 MHz in a linearly-polarized 937.7 nm ODT, which is less than 1.2% of the trap depth. We also discussed influence of the trap depth and the bias magnetic field on the measurement results.

  9. Study of amplitude frequency spectra of the compound action potentials recorded from normal and M. leprae infected mice using Fourier series analysis.

    Science.gov (United States)

    Vidyasagar, P B; Lokhandwalla, M N; Damle, P S

    1986-01-01

    Compound action potentials recorded from normal and M. leprae infected mice sciatic nerves were analysed in frequency domain using Fourier Series Analysis. Changes in myelinated fibre potentials were detected as early as 2nd post-inoculation month. This technique could be further developed to aid in early diagnosis of leprosy.

  10. A 1500 yr record of North Atlantic storm activity based on optically dated relict beach scarps

    Science.gov (United States)

    Buynevich, Ilya V.; Fitzgerald, Duncan M.; Goble, Ronald J.

    2007-06-01

    Understanding of long-term dynamics of intense coastal storms is important for determining the frequency and impact of these events on sandy coasts. We use optically stimulated luminescence (OSL) dates on relict scarps within a prograded barrier sequence to reconstruct the chronology of large-magnitude erosional events in the western Gulf of Maine. OSL dates obtained on quartz-rich sediments immediately overlying relict scarps indicate severe beach erosion and retreat due to erosional events ca. 1550, 390, 290, and 150 cal yr B.P. Our data provide new evidence of increased storm activity (most likely frequency and/or intensity of extratropical storms) during the past 500 yr, which was preceded by a relatively calm period lasting ˜1000 yr. The width of the coastal sequence preserved between successive paleoscarps shows strong correlation with the time interval elapsed between storms. Our findings indicate that diagnostic geophysical and sedimentological signatures of severe erosional events offer new opportunities for assessing the impact and timing of major storms along sandy coasts.

  11. Real-Time Growth Control of Ge-Sb-Te Multilayer Film as Optical Recording Media by In Situ Ellipsometry

    Science.gov (United States)

    An, Sung Hyuck; Kim, Jong Hyouk; Li, Xuezhe; Kim, Sang Jun; Kim, Sang Youl

    2004-09-01

    Using an in situ ellipsometer, we monitored the thin film growth curve of optical recording media in real time. Utilizing the complex refractive indices of Ge2Sb2Te5 and ZnS-SiO2 obtained from the analysis of spectroscopic ellipsometry data, we calculated the growth curves of ellipsometric constants vs thickness. By comparing the calculated growth curve of ellipsometric constants with the measured one, and by analyzing the effect of the density variation of the Ge2Sb2Te5 recording layer on ellipsometric constants, we precisely monitored the growth rate of Ge2Sb2Te5 and ZnS-SiO2 films, respectively, and eventually controlled the whole growth process of a multilayer sample made of Ge2Sb2Te5 and ZnS-SiO2 films. The accurate thickness control using in situ ellipsometry was verified through the analysis of the deposited multilayer sample using an ex situ spectroscopic ellipsometer.

  12. Stochastic thermodynamics with a Brownian particle in an optical trap (Presentation Recording)

    Science.gov (United States)

    Martinez, Ignacio A.; Roldán, Édgar; Dinis, Luis; Mestres, Pau; Parrondo, Juan M. R.; Rica, Raúl A.

    2015-08-01

    Stochastic thermodynamics [1,2] is a recently developed framework to deal with the thermodynamics at the microscope, where thermal fluctuations strongly influence their behaviour. Typical such systems are colloids and biomolecules or cells. These thermal fluctuations do not only lead to Brownian motion, but to a continuous and unavoidable heat exchange between the suspending medium and the particles, leading to a very interesting phenomenology. In order to explore such phenomenology and to test theoretical results obtained from stochastic thermodynamics, we developed an "experimental simulator" of thermodynamic devices in the microscale with an optically trapped bead that is subject to an external noise that mimics a controllable thermal bath. The noise is applied by means of electric fields acting on the charge of the trapped particle. In this talk, I will present some of the results we obtained with this simulator, demonstrating excellent control over the effective temperature of the system and a control parameter. This allows us to perform a variety of equilibrium and non-equilibrium thermodynamic processes [3-5]. In particular, we were able to realize microadiabatic processes, where no heat is exchanged on average between the particle and the medium [6]. This achievement allowed us to implement a Carnot microengine as a concatenation of isothermal and adiabatic processes [7], whose theoretical study is playing a key role in the foundations of stochastic thermodynamics. References [1] K Sekimoto; Lecture Notes in Physics (Springer, Berlin, 2010), Vol. 799. [2] U Seifert; Rep. Prog. Phys. 75 (2012) 126001 [3] IA Martínez, E Roldan, JMR Parrondo, D Petrov; Phys. Rev. E 87 (2013) 032159 [4] É Roldán, IA Martínez, L Dinis, RA Rica; Appl. Phys. Lett. 104 (2014) 234103 [5] P Mestres, IA Martinez, A Ortiz-Ambriz, RA Rica, E Roldan; Phys. Rev. E 90 (2014) 032116 [6] IA Martínez, E Roldan, L Dinis, D Petrov, RA Rica; Phys. Rev. Lett. (2015) In press [7] IA Martinez

  13. Inequality spectra

    Science.gov (United States)

    Eliazar, Iddo

    2017-03-01

    Inequality indices are widely applied in economics and in the social sciences as quantitative measures of the socioeconomic inequality of human societies. The application of inequality indices extends to size-distributions at large, where these indices can be used as general gauges of statistical heterogeneity. Moreover, as inequality indices are plentiful, arrays of such indices facilitate high-detail quantification of statistical heterogeneity. In this paper we elevate from arrays of inequality indices to inequality spectra: continuums of inequality indices that are parameterized by a single control parameter. We present a general methodology of constructing Lorenz-based inequality spectra, apply the general methodology to establish four sets of inequality spectra, investigate the properties of these sets, and show how these sets generalize known inequality gauges such as: the Gini index, the extended Gini index, the Rényi index, and hill curves.

  14. X-ray diffraction, X-ray photoelectron spectra, crystal structure, and optical properties of centrosymmetric strontium borate Sr2B16O26.

    Science.gov (United States)

    Reshak, Ali Hussain; Auluck, S; Kityk, I V; Chen, Xuean

    2009-07-09

    We report results of X-ray diffraction (XRD) and valence band X- ray photoelectron (VB-XPS) spectra for strontium borate Sr(2)B(16)O(26). The X-ray structural analysis shows that the single crystals of Sr(2)B(16)O(26) crystallize in the monoclinic space group P2(1)/c with a = 8.408(1) A, b = 16.672(1) A, c = 13.901(2) A, beta = 106.33(1) degrees , and Z = 4. The crystal structure consists of a 3D network of the complex borate anion [B(16)O(20)O(12/2)](4-), formed by 12 BO(3) triangles and four BO(4) tetrahedra, which can be viewed as three linked [B(3)O(3)O(4/2)](-) triborate groups bonded to one pentaborate [B(5)O(6)O(4/2)](-) group and two BO(3) triangles. Using this structure, we have performed theoretical calculations using the all-electron full potential linearized augmented plane wave (FP-LAPW) method for the band structure, density of states, electron charge density, and the frequency-dependent optical properties. Our experimental VB-XPS of Sr(2)B(16)O(26) is compared with results of our FP-LAPW calculations. Our calculations show that the valence band maximum (VBM) and conduction band minimum (CBM) are located at Gamma of the Brillouin zone (BZ) resulting in a direct energy gap of about 5.31 eV. Our measured VB-XPS show reasonable agreement with our calculated total density of states for the valence band that is attributed to the use of the full potential method.

  15. Assessment of the coherent potential approximation for the absorption spectra of a one-dimensional Frenkel exciton system with a Gaussian distribution of fluctuations in the optical transition frequency

    Science.gov (United States)

    Boukahil, A.; Avgin, I.; Huber, D. L.

    2015-01-01

    We investigate the accuracy of the coherent potential approximation (CPA) for the optical absorption spectra of a one-dimensional Frenkel exciton system with nearest-neighbor interactions and a Gaussian distribution of fluctuations in the optical transition frequency (diagonal Gaussian disorder). Our earlier studies have established that the CPA gives highly accurate results for the integral of the density of states of this system. In this paper we compare the CPA results for the normalized optical absorption with the finite-array calculations of Schreiber and Toyozawa and Schreiber for the same model. It is found that the CPA results for the absorption are in good agreement with their findings. It is pointed out that an expansion of the density of states in terms of the eigenstates of the ideal (no disorder) array contains a term proportional to the normalized absorption. Since the density of states is accurately approximated by the CPA, the presence of this term explains the success of the CPA in reproducing the absorption spectra. Our findings support the use of the Gaussian disorder model to interpret the absorption spectra of one and quasi-one dimensional exciton systems.

  16. Predicting ambient aerosol thermal-optical reflectance (TOR measurements from infrared spectra: extending the predictions to different years and different sites

    Directory of Open Access Journals (Sweden)

    M. Reggente

    2015-11-01

    We also propose a method to anticipate the prediction error: we calculate the squared Mahalanobis distance in the feature space (scores determined by PLSR between new spectra and spectra in the calibration set. The squared Mahalanobis distance provides a crude method for assessing the magnitude of mean error when applying a calibration model to a new set of samples.

  17. Automatic recognition of T and teleseismic P waves by statistical analysis of their spectra: An application to continuous records of moored hydrophones

    Science.gov (United States)

    Sukhovich, Alexey; Irisson, Jean-Olivier; Perrot, Julie; Nolet, Guust

    2014-08-01

    A network of moored hydrophones is an effective way of monitoring seismicity of oceanic ridges since it allows detection and localization of underwater events by recording generated T waves. The high cost of ship time necessitates long periods (normally a year) of autonomous functioning of the hydrophones, which results in very large data sets. The preliminary but indispensable part of the data analysis consists of identifying all T wave signals. This process is extremely time consuming if it is done by a human operator who visually examines the entire database. We propose a new method for automatic signal discrimination based on the Gradient Boosted Decision Trees technique that uses the distribution of signal spectral power among different frequency bands as the discriminating characteristic. We have applied this method to automatically identify the types of acoustic signals in data collected by two moored hydrophones in the North Atlantic. We show that the method is capable of efficiently resolving the signals of seismic origin with a small percentage of wrong identifications and missed events: 1.2% and 0.5% for T waves and 14.5% and 2.8% for teleseismic P waves, respectively. In addition, good identification rates for signals of other types (iceberg and ship generated) are obtained. Our results indicate that the method can be successfully applied to automate the analysis of other (not necessarily acoustic) databases provided that enough information is available to describe statistical properties of the signals to be identified.

  18. Effects of systemic administration of the essential oil of bergamot (BEO) on gross behaviour and EEG power spectra recorded from the rat hippocampus and cerebral cortex.

    Science.gov (United States)

    Rombolà, Laura; Corasaniti, Maria Tiziana; Rotiroti, Domenicantonio; Tassorelli, Cristina; Sakurada, Shinobu; Bagetta, G; Morrone, Luigi Antonio

    2009-01-01

    Bergamot (Citrus bergamia Risso et Poiteau) is a citrus fruit growing almost exclusively in the South of Italy. Its essential oil is obtained by cold pressing of the epicarp and, partly, of the mesocarp of the fresh fruit. Although this phytocomplex has been used for centuries, reputedly effectively, as a traditional medicine, there is very little verified scientific evidence to support this use. This paper reports original data on the systemic effects of the essential oil of bergamot (BEO) on gross behaviour and EEG activity recorded from the hippocampus and cerebral cortex of the rat. The Fast Fourier Transformation (FFT) was used to analyse and quantify the energy in single frequency bands of the EEG spectrum. The results obtained indicate that systemic administration of increasing volumes of BEO produces dose-dependent increases in locomotor and exploratory activity that correlate with a predominant increase in the energy in the faster frequency bands of the EEG spectrum. These data contribute to our understanding of the neurobiological profile of BEO.

  19. Using radiative transfer models to study the atmospheric water vapor content and to eliminate telluric lines from high-resolution optical spectra

    CERN Document Server

    Gardini, A; Pérez, E; Quesada, J A; Funke, B

    2012-01-01

    The Radiative Transfer Model (RTM) and the retrieval algorithm, incorporated in the SCIATRAN 2.2 software package developed at the Institute of Remote Sensing/Institute of Enviromental Physics of Bremen University (Germany), allows to simulate, among other things, radiance/irradiance spectra in the 2400-24 000 {\\AA} range. In this work we present applications of RTM to two case studies. In the first case the RTM was used to simulate direct solar irradiance spectra, with different water vapor amounts, for the study of the water vapor content in the atmosphere above Sierra Nevada Observatory. Simulated spectra were compared with those measured with a spectrometer operating in the 8000-10 000 {\\AA} range. In the second case the RTM was used to generate telluric model spectra to subtract the atmospheric contribution and correct high-resolution stellar spectra from atmospheric water vapor and oxygen lines. The results of both studies are discussed.

  20. In vivo application of an optical segment tracking approach for bone loading regimes recording in humans: a reliability study.

    Science.gov (United States)

    Yang, Peng-Fei; Sanno, Maximilian; Ganse, Bergita; Koy, Timmo; Brüggemann, Gert-Peter; Müller, Lars Peter; Rittweger, Jörn

    2014-08-01

    This paper demonstrates an optical segment tracking (OST) approach for assessing the in vivo bone loading regimes in humans. The relative movement between retro-reflective marker clusters affixed to the tibia cortex by bone screws was tracked and expressed as tibia loading regimes in terms of segment deformation. Stable in vivo fixation of bone screws was tested by assessing the resonance frequency of the screw-marker structure and the relative marker position changes after hopping and jumping. Tibia deformation was recorded during squatting exercises to demonstrate the reliability of the OST approach. Results indicated that the resonance frequencies remain unchanged prior to and after all exercises. The changes of Cardan angle between marker clusters induced by the exercises were rather minor, maximally 0.06°. The reproducibility of the deformation angles during squatting remained small (0.04°/m-0.65°/m). Most importantly, all surgical and testing procedures were well tolerated. The OST method promises to bring more insights of the mechanical loading acting on bone than in the past.

  1. Crystallization studies on phase-change optical recording media by use of a two-dimensional periodic mark array.

    Science.gov (United States)

    Xun, X; Erwin, J K; Bletscher, W; Choi, J; Kallenbach, S; Mansuripur, M

    2001-12-10

    We present the results of crystallization studies in thin-film samples of amorphous and crystalline Ge(x)Sb(y)Te(z). The experiments, conducted at moderately elevated temperatures, are based on measurements of the first-order diffraction efficiency from a two-dimensional periodic array of recorded marks. When the samples are slowly heated above room temperature, changes in the efficiencies of various diffracted orders give information about the on-going crystallization process within the sample. Two different compositions of the GeSbTe alloy are used in these experiments. Measurements on Ge(2)Sb(2.3)Te(5) films show crystallization dominated by nucleation. For the Sb-rich eutectic composition Ge-(SbTe), crystallization is found to be dominated by growth from crystalline boundaries. We also show that crystalline marks written by relatively high-power laser pulses are different in their optical properties from the regions crystallized by slow heating of the sample to moderate temperatures.

  2. LO-TO splittings, effective charges and interactions in electro-optic meta-nitroaniline crystal as studied by polarized IR reflection and transmission spectra

    Science.gov (United States)

    Szostak, M. M.; Le Calvé, N.; Romain, F.; Pasquier, B.

    1994-10-01

    The polarized IR reflection spectra of the meta-nitroaniline ( m-NA) single crystal along the a, b and c crystallographic axes as well as the b and c polarized transmission spectra have been measured in the 100-400 cm -1 region. The LO-TO splitting values have been calculated from the reflection spectra by fitting them with the four parameter dielectric function. The dipole moment derivatives, relevant to dynamic effective charges, of the vibrations have also been calculated and used to check the applicability of the oriented gas model (OGM) to reflection spectra. The discrepancies from the OGM have been discussed in terms of vibronic couplings, weak hydrogen bondings (HB) and intramolecular charge transfer.

  3. Power spectra of currents off Bombay

    Digital Repository Service at National Institute of Oceanography (India)

    Varkey, M.J.

    Current measurements were carried out using a recording current meter across the continental shelf off Bombay, Maharashtra, India at 4 stations from an anchored ship. Power spectra were computed for selected lengths of records. Spectral energy...

  4. Satellite Ocean Color Data Merging Using a Bio-optical model: A Path for Earth Science Data Records ?

    Science.gov (United States)

    Maritorena, S.; Siegel, D. A.; Hembise Fanton D'Andon, O.; Mangin, A.; Frew, J.; Nelson, N.

    2009-12-01

    The characteristics and benefits of ocean color merged data sets created using a semi-analytical model and the normalized water-leaving radiance observations from the SeaWiFS, MODIS-AQUA and MERIS ocean color missions are presented. Merged data products are coalesced from multiple mission observations into a single data product with better spatial and temporal coverage than the individual missions. Using the data from SeaWiFS, MODIS-AQUA and MERIS for the 2002-2009 time period, the average daily coverage of a merged product is ~25% of the world ocean which is nearly twice that of any single mission’s observations. The frequency at which a particular area is sampled from space is also greatly improved in merged data as some areas can be sampled as frequently as 64% of the time (in days). The merged data are validated through matchup analyses and by comparing them to the data sets obtained from individual missions. Further, a complete error budget was developed which accounts for uncertainty associated with input water-leaving radiances, the bio-optical model and uncertainty estimates for the output products (i.e. the chlorophyll concentration, the combined dissolved and detrital absorption coefficient and the particulate backscattering coefficient). These merged products and their uncertainties at each pixel were developed within the NASA MEASURES (http://wiki.icess.ucsb.edu/measures/index.php/Main_Page) and ESA GlobColour (http://www.globcolour.info/) projects and are available to the scientific community. The merging approach has many potential benefits for the creation of Earth Science Data Records from satellite ocean color observations.

  5. Reaching record-low β* at the CERN Large Hadron Collider using a novel scheme of collimator settings and optics

    Science.gov (United States)

    Bruce, R.; Bracco, C.; De Maria, R.; Giovannozzi, M.; Mereghetti, A.; Mirarchi, D.; Redaelli, S.; Quaranta, E.; Salvachua, B.

    2017-03-01

    The Large Hadron Collider (LHC) at CERN is built to collide intense proton beams with an unprecedented energy of 7 TeV. The design stored energy per beam of 362 MJ makes the LHC beams highly destructive, so that any beam losses risk to cause quenches of superconducting magnets or damage to accelerator components. Collimators are installed to protect the machine and they define a minimum normalized aperture, below which no other element is allowed. This imposes a limit on the achievable luminosity, since when squeezing β* (the β-function at the collision point) to smaller values for increased luminosity, the β-function in the final focusing system increases. This leads to a smaller normalized aperture that risks to go below the allowed collimation aperture. In the first run of the LHC, this was the main limitation on β*, which was constrained to values above the design specification. In this article, we show through theoretical and experimental studies how tighter collimator openings and a new optics with specific phase-advance constraints allows a β* as small as 40 cm, a factor 2 smaller than β*=80 cm used in 2015 and significantly below the design value β*=55 cm, in spite of a lower beam energy. The proposed configuration with β*=40 cm has been successfully put into operation and has been used throughout 2016 as the LHC baseline. The decrease in β* compared to 2015 has been an essential contribution to reaching and surpassing, in 2016, the LHC design luminosity for the first time, and to accumulating a record-high integrated luminosity of around 40 fb-1 in one year, in spite of using less bunches than in the design.

  6. Optics

    CERN Document Server

    Fincham, W H A

    2013-01-01

    Optics: Ninth Edition Optics: Ninth Edition covers the work necessary for the specialization in such subjects as ophthalmic optics, optical instruments and lens design. The text includes topics such as the propagation and behavior of light; reflection and refraction - their laws and how different media affect them; lenses - thick and thin, cylindrical and subcylindrical; photometry; dispersion and color; interference; and polarization. Also included are topics such as diffraction and holography; the limitation of beams in optical systems and its effects; and lens systems. The book is recommen

  7. Star formation history and chemical enrichment in the early Universe: clues from the rest-optical and rest-UV spectra of z~2-3 star-forming galaxies in the Keck Baryonic Structure Survey

    Science.gov (United States)

    Strom, Allison L.

    2017-01-01

    Galaxies at the peak of cosmic star formation (z~2-3) exhibit significantly higher star formation rates and gas fractions at fixed stellar mass than nearby galaxies. These z~2-3 galaxies are also distinct in terms of their nebular spectra, reflecting important differences not only in the physical conditions of their interstellar medium (e.g., electron density and gas-phase metallicity), but also in the details of their massive stellar populations, especially their ionizing radiation fields. Jointly observing galaxies' HII regions, at rest-UV and rest-optical wavelengths, and massive stars, at rest-UV wavelengths, is central to constructing a framework for understanding the differences between z~2-3 and z~0 star-forming galaxies and for self-consistently explaining the trends observed in the high-redshift population. My thesis is based on data from the Keck Baryonic Structure Survey (KBSS), which uniquely combines observations of individual galaxies in these two bandpasses. In total, the near-infrared component of the KBSS includes spectra of >700 z~2-3 galaxies obtained with Keck/MOSFIRE. I will present these results along with a detailed analysis of the full rest-optical (3600-7000 Ang) nebular spectra of ~400 galaxies, showing that high-redshift galaxies exhibit uniformly high degrees of ionization and excitation with respect to most z~0 galaxies. Combined with observations of the same galaxies' rest-UV spectra (obtained with Keck/LRIS) and photoionization model predictions, these results suggest that the disparity arises from differences in the shape of the ionizing radiation field at fixed gas-phase oxygen abundance, most likely due to the effects of Fe-poor massive binary stars. My comprehensive spectroscopic study of an unprecedentedly large sample of z~2-3 galaxies offers compelling evidence that the distinct chemical abundance patterns observed in these galaxies are the result of systematic differences in their star formation histories.

  8. Three-dimensional structure of CA1 pyramidal cells in rat hippocampus——Optical recording of LSM and computer simulation of fractal structure

    Institute of Scientific and Technical Information of China (English)

    冯春华; 刘力; 刘守忠; 宁红; 孙海坚; 郭爱克

    1995-01-01

    The optical recording of three-dimensional(3-D)reconstruction of CA1 pyramidal cells wasderived from the studies on the CA1 region of the hippocampus in adult male Wistar rats.The recordingwas produced by the Confocal Laser Scan Microscope(LSM-10).The attemption was to outline themorphological neural network of CA1 pyramidal cells organization,following the trail of axo-dendritic connec-tions in 3-D spatial distributions among neurons.The fractal structure of neurons with their dendritic andaxonal trees using fractal algorithm was noticed,and 2—18 simulated cells were obtained using PC-486 comput-er.The simulational cells are similar in morphology to the natural CA1 hippocampal pyramidal cells.There-fore,the exploitation of an advanced neurohistological research technique combining optical recording of theLSM-10 and computer simulation of fractal structure can provide the quantitative fractal structural basis forchaosic dynamics of brain.

  9. Optics

    CERN Document Server

    Fincham, W H A

    2013-01-01

    Optics: Eighth Edition covers the work necessary for the specialization in such subjects as ophthalmic optics, optical instruments and lens design. The text includes topics such as the propagation and behavior of light; reflection and refraction - their laws and how different media affect them; lenses - thick and thin, cylindrical and subcylindrical; photometry; dispersion and color; interference; and polarization. Also included are topics such as diffraction and holography; the limitation of beams in optical systems and its effects; and lens systems. The book is recommended for engineering st

  10. Echelle spectra of SN2014J from the Apache Point Observatory 3.5m telescope, UT January 27 and January 30, 2014

    Science.gov (United States)

    Ritchey, Adam M.; Welty, Daniel E.; Dahlstrom, Julie A.; York, Donald G.

    2014-02-01

    Optical spectra of SN2014J were recorded with the ARC echelle spectrograph at Apache Point Observatory, at approximately UT Jan. 27.2 (7 spectra, 8400 s) and UT Jan. 30.4, (6 spectra, 7200s), through thin clouds in seeing averaging 1.0 arcsec. The resolving power is 31,500. Useful interstellar spectra were obtained from 3850A to 9000A; estimated S/N values (photon counts only) near 6563A are 500 on Jan 27 and 400 on Jan 30, and about 1/3 those values at Ca II 3933A.

  11. Rapid, nondestructive estimation of surface polymer layer thickness using attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy and synthetic spectra derived from optical principles.

    Science.gov (United States)

    Weinstock, B André; Guiney, Linda M; Loose, Christopher

    2012-11-01

    We have developed a rapid, nondestructive analytical method that estimates the thickness of a surface polymer layer with high precision but unknown accuracy using a single attenuated total reflection Fourier transform infrared (ATR FT-IR) measurement. Because the method is rapid, nondestructive, and requires no sample preparation, it is ideal as a process analytical technique. Prior to implementation, the ATR FT-IR spectrum of the substrate layer pure component and the ATR FT-IR and real refractive index spectra of the surface layer pure component must be known. From these three input spectra a synthetic mid-infrared spectral matrix of surface layers 0 nm to 10,000 nm thick on substrate is created de novo. A minimum statistical distance match between a process sample's ATR FT-IR spectrum and the synthetic spectral matrix provides the thickness of that sample. We show that this method can be used to successfully estimate the thickness of polysulfobetaine surface modification, a hydrated polymeric surface layer covalently bonded onto a polyetherurethane substrate. A database of 1850 sample spectra was examined. Spectrochemical matrix-effect unknowns, such as the nonuniform and molecularly novel polysulfobetaine-polyetherurethane interface, were found to be minimal. A partial least squares regression analysis of the database spectra versus their thicknesses as calculated by the method described yielded an estimate of precision of ±52 nm.

  12. Temperature effects on quasi-isolated conjugated polymers as revealed by temperature-dependent optical spectra of 16-mer oligothiophene diluted in a sold matrix.

    Science.gov (United States)

    Kanemoto, Katsuichi; Akai, Ichiro; Sugisaki, Mitsuru; Hashimoto, Hideki; Karasawa, Tsutomu; Negishi, Nobukazu; Aso, Yoshio

    2009-06-21

    Temperature dependences (4-300 K) of photoluminescence (PL) and absorption spectra of 16-mer oligothiophene (16 T) extremely diluted in polypropylene (PP) have been investigated in order to clarify temperature effects on quasi-isolated conjugated polymers. The PL and absorption spectra are found to blueshift with increasing temperature. The reason for the blueshift is discussed by comparing models based on the refractive index of the solvent (PP) and on the thermal conformational change of 16 T. The blueshift is concluded to result from the thermal conformational change. Time-resolved PL spectra show a redshift of PL band following photoexcitation (spectral migration). The amount of the migration is shown to increase with increasing temperature. The increased migration is concluded to be due to the thermal conformational change. The temperature dependence of the effective conjugation length (ECL) of 16 T is calculated for the absorption and PL transitions. The calculation suggests that ECL is reduced at room temperature to two-thirds of the intrinsic chain length. The activation energy of the conformational change is estimated to be 22.4 meV from the temperature dependence of ECL. We demonstrate that the steady-state PL spectra are well reproduced by simple Franck-Condon analyses using a single Huang-Ryes factor over a wide temperature range. The analyses reveal features of temperature dependence in important spectral parameters such as the Stokes shift, linewidth, and Huang-Ryes factor.

  13. Quasiparticle and excitonic effects in the optical spectra of diamond, SiC, Si, GaP, GaAs, InP, and AlN

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, P.H.; Seino, K.; Schmidt, W.G.; Furthmueller, J.; Bechstedt, F. [Institut fuer Festkoerpertheorie und -optik, Friedrich-Schiller-Universitaet, Max-Wien-Platz 1, 07743 Jena (Germany)

    2005-11-01

    We demonstrate the potential of recently developed electronic-structure methods for the calculation of the optical properties of solids. As prototypical examples semiconductors crystallizing in diamond or zinc-blende structure are studied. The many-body effects are fully taken into account by a solution of the combined Dyson and Bethe-Salpeter equations. We show that an initial-value formulation of the polarization function allows for an efficient numerical calculation of the optical susceptibility. The effect of the renormalization of electrons and holes to quasiparticles is shown for both the band structure and the optical spectrum. In addition, excitonic effects are identified to remarkably influence the optical absorption. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  14. On the importance of image formation optics in the design of infrared spectroscopic imaging systems.

    Science.gov (United States)

    Mayerich, David; van Dijk, Thomas; Walsh, Michael J; Schulmerich, Matthew V; Carney, P Scott; Bhargava, Rohit

    2014-08-21

    Infrared spectroscopic imaging provides micron-scale spatial resolution with molecular contrast. While recent work demonstrates that sample morphology affects the recorded spectrum, considerably less attention has been focused on the effects of the optics, including the condenser and objective. This analysis is extremely important, since it will be possible to understand effects on recorded data and provides insight for reducing optical effects through rigorous microscope design. Here, we present a theoretical description and experimental results that demonstrate the effects of commonly-employed cassegranian optics on recorded spectra. We first combine an explicit model of image formation and a method for quantifying and visualizing the deviations in recorded spectra as a function of microscope optics. We then verify these simulations with measurements obtained from spatially heterogeneous samples. The deviation of the computed spectrum from the ideal case is quantified via a map which we call a deviation map. The deviation map is obtained as a function of optical elements by systematic simulations. Examination of deviation maps demonstrates that the optimal optical configuration for minimal deviation is contrary to prevailing practice in which throughput is maximized for an instrument without a sample. This report should be helpful for understanding recorded spectra as a function of the optics, the analytical limits of recorded data determined by the optical design, and potential routes for optimization of imaging systems.

  15. Spectra from 2.5-15 {mu}m of tissue phantom materials, optical clearing agents and ex vivo human skin: implications for depth profiling of human skin

    Energy Technology Data Exchange (ETDEWEB)

    Viator, John A [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA (United States); Choi, Bernard [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA (United States); Peavy, George M [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA (United States); Kimel, Sol [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA (United States); Nelson, J Stuart [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA (United States)

    2003-01-21

    Infrared measurements have been used to profile or image biological tissue, including human skin. Usually, analysis of such measurements has assumed that infrared absorption is due to water and collagen. Such an assumption may be reasonable for soft tissue, but introduction of exogenous agents into skin or the measurement of tissue phantoms has raised the question of their infrared absorption spectrum. We used Fourier transform infrared spectroscopy in attenuated total reflection mode to measure the infrared absorption spectra, in the range of 2-15 {mu}m, of water, polyacrylamide, Intralipid, collagen gels, four hyperosmotic clearing agents (glycerol, 1,3-butylene glycol, trimethylolpropane, Topicare{sup TM}), and ex vivo human stratum corneum and dermis. The absorption spectra of the phantom materials were similar to that of water, although additional structure was noted in the range of 6-10 {mu}m. The absorption spectra of the clearing agents were more complex, with molecular absorption bands dominating between 6 and 12 {mu}m. Dermis was similar to water, with collagen structure evident in the 6-10 {mu}m range. Stratum corneum had a significantly lower absorption than dermis due to a lower content of water. These results suggest that the assumption of water-dominated absorption in the 2.5-6 {mu}m range is valid. At longer wavelengths, clearing agent absorption spectra differ significantly from the water spectrum. This spectral information can be used in pulsed photothermal radiometry or utilized in the interpretation of reconstructions in which a constant {mu}{sub ir} is used. In such cases, overestimating {mu}{sub ir} will underestimate chromophore depth and vice versa, although the effect is dependent on actual chromophore depth. (note)

  16. Recovery of surface reflectance spectra and evaluation of the optical depth of aerosols in the near-IR using a Monte-Carlo approach: Application to the OMEGA observations of high latitude regions of Mars

    CERN Document Server

    Vincendon, Mathieu; Poulet, François; Bibring, Jean-Pierre; Gondet, Brigitte; 10.1029/2006JE002845

    2011-01-01

    We present a model of radiative transfer through atmospheric particles based on Monte Carlo methods. This model can be used to analyze and remove the contribution of aerosols in remote sensing observations. We have developed a method to quantify the contribution of atmospheric dust in near-IR spectra of the Martian surface obtained by the OMEGA imaging spectrometer on board Mars Express. Using observations in the nadir pointing mode with significant differences in solar incidence angles, we can infer the optical depth of atmospheric dust, and we can retrieve the surface reflectance spectra free of aerosol contribution. Martian airborne dust properties are discussed and constrained from previous studies and OMEGA data. We have tested our method on a region at 90{\\deg}E and 77{\\deg}N extensively covered by OMEGA, where significant variations of the albedo of ice patches in the visible have been reported. The consistency between reflectance spectra of ice-covered and ice-free regions recovered at different incid...

  17. Copper(II) and nickel(II) complexes of tetradentate Schiff base ligand: UV-Vis and FT-IR spectra and DFT calculation of electronic, vibrational and nonlinear optical properties

    Science.gov (United States)

    Zarei, Seyed Amir; Khaledian, Donya; Akhtari, Keivan; Hassanzadeh, Keyumars

    2015-11-01

    The experimental fourier transform infrared (FT-IR) and ultraviolet-visible (UV-Vis) spectra of copper(II) and nickel(II) complexes of the deprotonated tetradentate Schiff base ligand N,N‧-bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine (H2L) are compared with their corresponding theoretical ones. The applied theoretical method is based on the density functional theory and time-dependent density functional theory at the UPBE0/PBE0 levels using Def2-TZVP basis set. The computational optimised geometric parameters of the complexes are in good agreement with their corresponding experimental data. The FT-IR and UV-Vis spectra of the complexes were reproduced on the basis of their optimised structures. The vibrational assignments of some fundamental modes of the complexes are performed. The highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) energies are calculated. The analyses of the calculated electronic absorption spectra of the complexes are carried out to elucidate the electronic transitions assignments and their characters. Second-order nonlinear optical property of the complexes is evaluated by the above-mentioned theoretical method that implies much greater values for the complexes in comparison with the corresponding value of urea.

  18. Millimeter-wave optical double resonance schemes for rapid assignment of perturbed spectra, with applications to the C{sup ~} {sup 1}B{sub 2} state of SO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Park, G. Barratt, E-mail: barratt@mit.edu, E-mail: barratt.park@gmail.com; Womack, Caroline C.; Jiang, Jun; Field, Robert W., E-mail: rwfield@mit.edu [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Whitehill, Andrew R.; Ono, Shuhei [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-04-14

    Millimeter-wave detected, millimeter-wave optical double resonance (mmODR) spectroscopy is a powerful tool for the analysis of dense, complicated regions in the optical spectra of small molecules. The availability of cavity-free microwave and millimeter wave spectrometers with frequency-agile generation and detection of radiation (required for chirped-pulse Fourier-transform spectroscopy) opens up new schemes for double resonance experiments. We demonstrate a multiplexed population labeling scheme for rapid acquisition of double resonance spectra, probing multiple rotational transitions simultaneously. We also demonstrate a millimeter-wave implementation of the coherence-converted population transfer scheme for background-free mmODR, which provides a ∼10-fold sensitivity improvement over the population labeling scheme. We analyze perturbations in the C{sup ~} state of SO{sub 2}, and we rotationally assign a b{sub 2} vibrational level at 45 328 cm{sup −1} that borrows intensity via a c-axis Coriolis interaction. We also demonstrate the effectiveness of our multiplexed mmODR scheme for rapid acquisition and assignment of three predissociated vibrational levels of the C{sup ~} state of SO{sub 2} between 46 800 and 47 650 cm{sup −1}.

  19. Optical and FT Infrared Absorption Spectra of 3d Transition Metal Ions Doped in NaF-CaF2-B2O3 Glass and Effects of Gamma Irradiation

    Directory of Open Access Journals (Sweden)

    F. H. A. Elbatal

    2014-01-01

    Full Text Available Combined optical and FTIR spectroscopy has been employed to investigate the undoped NaF-CaF2-B2O3 glass together with samples containing 0.2% dopant of 3d TM ions before and after gamma irradiation. The optical spectrum of the undoped glass reveals strong UV absorption with two peaks which are related to unavoidable trace iron impurity within the raw materials. Upon gamma irradiation, an induced visible broad band centered at 500 nm is resolved and is related to B-O hole center or nonbridging oxygen hole center. TMs-doped samples exhibit characteristic absorption due to each respective TM ion but with faint colors. Gamma irradiation of TMs-doped samples reveals the same induced visible band at 500–510 nm in most samples except CuO and Cr2O3-doped glasses. Infrared absorption spectra reveal characteristic vibrational bands due to triangular and tetrahedral borate groups. The introduction of NaF and CaF2 modifies the borate network forming BO3F tetrahedra. The introduction of 3d TMs as dopants did not make any obvious changes in the FTIR spectra due to their low content (0.2%. Gamma irradiation causes only minor variations in the intensities of the characteristic IR borate bands while the bands at about 1640 cm−1 and 3450 cm−1 reveal distinct growth in most samples.

  20. FT-IR reflection spectra of single crystals: resolving phonons of different symmetry without using polarised radiation

    Directory of Open Access Journals (Sweden)

    METODIJA NAJDOSKI

    2000-07-01

    Full Text Available Fourier-transform infrared (FT-IR reflection spectra, asquired at nearnormal incidence, were recorded from single crystals belonging to six crystal systems: CsCr(SO42.12H2O (alum, cubic, K2CuCl2·2H2O (Mitscherlichite, tetragonal, CaCO3 (calcite, hexagonal, KHSO4 (mercallite, orthorhombic, CaSO4·2H2O (gypsum, monoclinic and CuSO4·5H2O (chalcantite, triclinic. The acquired IR reflection spectra were further transformed into absorption spectra, employing the Kramers-Kronig transformation. Except for the cubic alums, the spectra strongly depend on the crystal face from which they were recorded; this is a consequence of anisotropy. Phonons of a given symmetry (E-species, in tetragonal/hexagonal and B-species, in monoclinic crystals may be resolved without using a polariser. The spectrum may be simplified in the case of an orthorhombic crystal, as well. The longitudinal-optical (LO and transversal-optical (TO mode frequencies were calculated in the case of optically isotropic and the simplified spectra of optically uniaxial crystals.

  1. Discovery of periodic modulations in the optical spectra of galaxies, possibly due to ultra-rapid light bursts from their massive central black hole

    CERN Document Server

    Borra, Ermanno F

    2013-01-01

    A Fourier transform analysis of 2.5 million spectra in the SDSS survey was carried out to detect periodic modulations contained in their intensity versus frequency spectrum. A statistically significant signal was found for 223 galaxies while the spectra of 0.9 million galaxies were observed. A plot of the periods as a function of redshift clearly shows that the effect is real without any doubt, because they are quantized at two base periods that increase with redshift in two very tight parallel linear relations. I suggest that it could be caused by light bursts separated by times of the order of 10-13 seconds because it was the original reason for searching for the spectral periodicity but other causes may be possible. As another possible cause, I investigate the hypothesis that the modulation is generated by the Fourier transform of spectral lines, concluding that it is not valid. Although the light bursts suggestion implies absurdly high temperatures, it is supported by the fact that the Crab pulsar also ha...

  2. K band SINFONI spectra of two $z \\sim 5$ SMGs: upper limits to the un-obscured star formation from [O II] optical emission line searches

    CERN Document Server

    Couto, Guilherme S; López, Javier Piqueras; Storchi-Bergmann, Thaisa; Arribas, Santiago

    2016-01-01

    We present deep SINFONI K band integral field spectra of two submillimeter (SMG) galaxy systems: BR 1202-0725 and J1000+0234, at $z=4.69$ and $4.55$ respectively. Spectra extracted for each object in the two systems do not show any signature of the [O II]$\\lambda\\lambda$3726,29\\AA$\\,$ emission-lines, placing upper flux limits of $3.9$ and $2.5 \\times 10^{-18}\\,$${\\rm erg\\,s^{-1}\\,\\,cm^{-2} \\,}$ for BR 1202-0725 and J1000+0234, respectively. Using the relation between the star formation rate (SFR) and the luminosity of the [O II] doublet from Kennicutt (1998), we estimate unobscured SFR upper limits of $\\sim$ $10-15\\,\\rm M_\\odot\\,yr^{-1} \\,$ and $\\sim$ $30-40\\,\\rm M_\\odot\\,yr^{-1} \\,$ for the objects of the two systems, respectively. For the SMGs, these values are at least two orders of magnitude lower than those derived from SED and IR luminosities. The differences on the SFR values would correspond to internal extinction of, at least, $3.4 - 4.9$ and $2.1 - 3.6$ mag in the visual for BR 1202-0725 and J1000+0...

  3. Optical spectra of 5 new Be/X-ray Binaries in the Small Magellanic Cloud and the link of the supergiant B[e] star LHA 115-S 18 with an X-ray source

    CERN Document Server

    Maravelias, Grigoris; Antoniou, Vallia; Hatzidimitriou, Despoina

    2013-01-01

    The Small Magellanic Cloud (SMC) is well known to harbor a large number of High-Mass X-ray Binaries (HMXBs). The identification of their optical counterparts provides information on the nature of the donor stars and can help to constrain the parameters of these systems and their evolution. We obtained optical spectra for a number of HMXBs identified in previous Chandra and XMM-Newton surveys of the SMC using the AAOmega/2dF fiber-fed spectrograph at the Anglo-Australian Telescope. We find 5 new Be/X-ray binaries (BeXRBs; including a tentative one), by identifying the spectral type of their optical counterparts, and we confirm the spectral classification of an additional 15 known BeXRBs. We compared the spectral types, orbital periods, and eccentricities of the BeXRB populations in the SMC and the Milky Way and we find marginal evidence for difference between the spectral type distributions, but no statistically significant differences for the orbital periods and the eccentricities. Moreover, our search reveal...

  4. Studies of the defect structure from the calculations of optical and electron paramagnetic resonance spectra for Ni2+ centre in -LiIO3 crystal

    Indian Academy of Sciences (India)

    Feng Wen-Lin; Zheng Wen-Chen

    2008-09-01

    By calculating the optical spectrum band positions and EPR parameters ( factors, ∥, ⊥ and zero-field splitting ) by diagonalizing the complete energy matrix of 3d8 ions in trigonal symmetry, the defect structure of Ni2+ centre in -LiIO3 crystal is studied. It is found that to reach the good fits of optical and EPR data between calculation and experiment, the Ni2+ ion should shift by ≈ 0.298 Å along C3 -axis and the O2− ions between the Ni2+ ion and Li+ vacancy (Li) should be displaced away from the Li by ≈ 0.097 Å because of the electrostatic interaction. The results are discussed.

  5. Environmental Screening Effects in 2D Materials: Renormalization of the Bandgap, Electronic Structure, and Optical Spectra of Few-Layer Black Phosphorus.

    Science.gov (United States)

    Qiu, Diana Y; da Jornada, Felipe H; Louie, Steven G

    2017-08-09

    Few-layer black phosphorus has recently emerged as a promising 2D semiconductor, notable for its widely tunable bandgap, highly anisotropic properties, and theoretically predicted large exciton binding energies. To avoid degradation, it has become common practice to encapsulate black phosphorus devices. It is generally assumed that this encapsulation does not qualitatively affect their optical properties. Here, we show that the contrary is true. We have performed ab initio GW and GW plus Bethe-Salpeter equation (GW-BSE) calculations to determine the quasiparticle (QP) band structure and optical spectrum of one-layer (1L) through four-layer (4L) black phosphorus, with and without encapsulation between hexagonal boron nitride and sapphire. We show that black phosphorus is exceptionally sensitive to environmental screening. Encapsulation reduces the exciton binding energy in 1L by as much as 70% and completely eliminates the presence of a bound exciton in the 4L structure. The reduction in the exciton binding energies is offset by a similarly large renormalization of the QP bandgap so that the optical gap remains nearly unchanged, but the nature of the excited states and the qualitative features of the absorption spectrum change dramatically.

  6. Dual optical recordings for action potentials and calcium handling in induced pluripotent stem cell models of cardiac arrhythmias using genetically encoded fluorescent indicators.

    Science.gov (United States)

    Song, LouJin; Awari, Daniel W; Han, Elizabeth Y; Uche-Anya, Eugenia; Park, Seon-Hye E; Yabe, Yoko A; Chung, Wendy K; Yazawa, Masayuki

    2015-05-01

    Reprogramming of human somatic cells to pluripotency has been used to investigate disease mechanisms and to identify potential therapeutics. However, the methods used for reprogramming, in vitro differentiation, and phenotyping are still complicated, expensive, and time-consuming. To address the limitations, we first optimized a protocol for reprogramming of human fibroblasts and keratinocytes into pluripotency using single lipofection and the episomal vectors in a 24-well plate format. This method allowed us to generate multiple lines of integration-free and feeder-free induced pluripotent stem cells (iPSCs) from seven patients with cardiac diseases and three controls. Second, we differentiated human iPSCs derived from patients with Timothy syndrome into cardiomyocytes using a monolayer differentiation method. We found that Timothy syndrome cardiomyocytes showed slower, irregular contractions and abnormal calcium handling compared with the controls. The results are consistent with previous reports using a retroviral method for reprogramming and an embryoid body-based method for cardiac differentiation. Third, we developed an efficient approach for recording the action potentials and calcium transients simultaneously in control and patient cardiomyocytes using genetically encoded fluorescent indicators, ArcLight and R-GECO1. The dual optical recordings enabled us to observe prolonged action potentials and abnormal calcium handling in Timothy syndrome cardiomyocytes. We confirmed that roscovitine rescued the phenotypes in Timothy syndrome cardiomyocytes and that these findings were consistent with previous studies using conventional electrophysiological recordings and calcium imaging with dyes. The approaches using our optimized methods and dual optical recordings will improve iPSC applicability for disease modeling to investigate mechanisms underlying cardiac arrhythmias and to test potential therapeutics.

  7. Optical and Short-wavelength Recording Properties of Ag8In14Sb55Te23 Phase-change Films

    Institute of Scientific and Technical Information of China (English)

    LI Jinyan; HOU Lisong; GAN Fuxi

    2001-01-01

    The Ag-In-Sb-Te phase-change films were deposited on K9 glass substrates by RF magnetron sputtering technology with an Ag-In-Sb-Te alloy target. The spectral properties and short-wavelength optical storage properties of Ag8In13Sb55Te23 films were studied. X-ray diffraction results have indicated that the crystallization compounds include mainly AgSbTe2 with small amounts of Sb and AgInTe2. A comparatively large absorption has been observed in the visible wavelength range. The optical storage characteristics of Ag8In13Sb55Te23 thin films indicated that larger reflectivity contrast can be obtained at lower writing power and shorter writing pulse width.

  8. A Novel Approach to Obtain GeSbTe-Based High Speed Crystallizing Materials for Phase Change Optical Recording

    Science.gov (United States)

    2001-04-01

    UNCLASSIFIED Defense Technical Information Center Compilation Part Notice ADP012318 TITLE: A Novel Approach to Obtain GeSbTe -Based High Speed...UNCLASSIFIED Mat. Res. Soc. Symp. Proc. Vol. 674 © 2001 Materials Research Society A Novel Approach to Obtain GeSbTe -Based High Speed Crystallizing...fast crystallizing materials based on a conventional GeSbTe alloy for rewritable phase change optical data storage. By means of co-sputtering

  9. Reactor Neutrino Spectra

    OpenAIRE

    Hayes, A. C.; Vogel, Petr

    2016-01-01

    We present a review of the antineutrino spectra emitted from reactors. Knowledge of these spectra and their associated uncertainties is crucial for neutrino oscillation studies. The spectra used to date have been determined either by converting measured electron spectra to antineutrino spectra or by summing over all of the thousands of transitions that make up the spectra, using modern databases as input. The uncertainties in the subdominant corrections to β-decay plague both methods, and we ...

  10. Thermal annealing and UV irradiation effects on structure, morphology, photoluminescence and optical absorption spectra of EDTA-capped ZnS nanoparticles

    Science.gov (United States)

    Osman, M. A.; Othman, A. A.; El-Said, Waleed A.; Abd-Elrahim, A. G.; Abu-sehly, A. A.

    2016-02-01

    Monodispersed ZnS nanoparticles (NPs) were prepared by the chemical precipitation method. Thermally induced structural, morphological and optical changes have been investigated using x-ray diffraction, high-resolution transmission electron microscopy, optical absorption, photoluminescence (PL), and Fourier transform infrared and Raman spectroscopy. It was found that D increases with increasing annealing temperature (T a). The onset of the ZnS phase transition from cubic to hexagonal structure takes place at 400 °C, while cubic ZnS transforms into hexagonal ZnO via thermal oxidation in air at 600 °C. It is also noted that increasing T a results in the red shift of the optical band gap (E\\text{g}\\text{opt} ) and the thermal bleaching of exciton absorption. The PL spectrum of as-prepared ZnS nanopowder shows UV emission bands at 363 and 395 nm and blue and green emission at 438 and 515 nm, respectively. With increasing T a up to 500 °C, these bands were quenched and red-shifted. In addition, the UV irradiation effects on colloidal ZnS NPs were investigated. UV irradiation at a dose  <13 J cm-2 leads to a decrease in D, the blue shift of E\\text{g}\\text{opt} and the enhancement of PL intensity. This behavior was explained in terms of surface modification by photopolymerization, the formation of a ZnSO4 passivation layer, as well as the reduction of D by photocorrosion. At a UV irradiation dose  <13 J cm-2 both E\\text{g}\\text{opt} and D did not change and PL intensity was quenched, which were caused by the creation of nonradiative surface states by the photodegradation of the capping agent and photopassivated layer. The mechanism of the PL emission process in ZnS NPs was discussed and an energy band diagram was proposed.

  11. Absolute configuration of an axially chiral sulfonate determined from its optical rotatory dispersion, electronic circular dichroism, and vibrational circular dichroism spectra.

    Science.gov (United States)

    Covington, Cody L; Raghavan, Vijay; Smuts, Jonathan P; Armstrong, Daniel W; Polavarapu, Prasad L

    2017-11-01

    The absolute configuration (AC) of an axially chiral sulfonate (aCSO), 3,5-dimethyl-2-(naphthalen-1-yl)-6-(naphthalen-1-yl)benzenesulfonate (labeled as aCSO5), was investigated using optical rotatory dispersion (ORD), electronic circular dichroism (ECD), and vibrational circular dichroism (VCD) spectroscopies. All three methods led to the same conclusion and the AC of aCSO5 is reliably determined to be (-)-(aR, aR), or conversely (+)-(aS, aS). © 2017 Wiley Periodicals, Inc.

  12. OptoZIF Drive: a 3D printed implant and assembly tool package for neural recording and optical stimulation in freely moving mice

    Science.gov (United States)

    Freedman, David S.; Schroeder, Joseph B.; Telian, Gregory I.; Zhang, Zhengyang; Sunil, Smrithi; Ritt, Jason T.

    2016-12-01

    Objective. Behavioral neuroscience studies in freely moving rodents require small, light-weight implants to facilitate neural recording and stimulation. Our goal was to develop an integrated package of 3D printed parts and assembly aids for labs to rapidly fabricate, with minimal training, an implant that combines individually positionable microelectrodes, an optical fiber, zero insertion force (ZIF-clip) headstage connection, and secondary recording electrodes, e.g. for electromyography (EMG). Approach. Starting from previous implant designs that position recording electrodes using a control screw, we developed an implant where the main drive body, protective shell, and non-metal components of the microdrives are 3D printed in parallel. We compared alternative shapes and orientations of circuit boards for electrode connection to the headstage, in terms of their size, weight, and ease of wire insertion. We iteratively refined assembly methods, and integrated additional assembly aids into the 3D printed casing. Main results. We demonstrate the effectiveness of the OptoZIF Drive by performing real time optogenetic feedback in behaving mice. A novel feature of the OptoZIF Drive is its vertical circuit board, which facilities direct ZIF-clip connection. This feature requires angled insertion of an optical fiber that still can exit the drive from the center of a ring of recording electrodes. We designed an innovative 2-part protective shell that can be installed during the implant surgery to facilitate making additional connections to the circuit board. We use this feature to show that facial EMG in mice can be used as a control signal to lock stimulation to the animal’s motion, with stable EMG signal over several months. To decrease assembly time, reduce assembly errors, and improve repeatability, we fabricate assembly aids including a drive holder, a drill guide, an implant fixture for microelectode ‘pinning’, and a gold plating fixture. Significance. The

  13. A high-speed, reconfigurable, channel- and time-tagged photon arrival recording system for intensity-interferometry and quantum optics experiments

    Science.gov (United States)

    Girish, B. S.; Pandey, Deepak; Ramachandran, Hema

    2017-08-01

    We present a compact, inexpensive multichannel module, APODAS (Avalanche Photodiode Output Data Acquisition System), capable of detecting 0.8 billion photons per second and providing real-time recording on a computer hard-disk, of channel- and time-tagged information of the arrival of upto 0.4 billion photons per second. Built around a Virtex-5 Field Programmable Gate Array (FPGA) unit, APODAS offers a temporal resolution of 5 nanoseconds with zero deadtime in data acquisition, utilising an efficient scheme for time and channel tagging and employing Gigabit ethernet for the transfer of data. Analysis tools have been developed on a Linux platform for multi-fold coincidence studies and time-delayed intensity interferometry. As illustrative examples, the second-order intensity correlation function ( g 2) of light from two commonly used sources in quantum optics —a coherent laser source and a dilute atomic vapour emitting spontaneously, constituting a thermal source— are presented. With easy reconfigurability and with no restriction on the total record length, APODAS can be readily used for studies over various time scales. This is demonstrated by using APODAS to reveal Rabi oscillations on nanosecond time scales in the emission of ultracold atoms, on the one hand, and, on the other hand, to measure the second-order correlation function on the millisecond time scales from tailored light sources. The efficient and versatile performance of APODAS promises its utility in diverse fields, like quantum optics, quantum communication, nuclear physics, astrophysics and biology.

  14. Optical Spectra of Tm3+ -doped CdWO4 Crystal%Tm3+掺杂CdWO4单晶的发光特性

    Institute of Scientific and Technical Information of China (English)

    胡皓阳; 万云涛; 胡建旭; 夏海平; 张约品; 陈红兵

    2012-01-01

    用坩埚下降法生长获得了尺寸为φ25 mm×90 mm、Tm2O3初始掺杂摩尔分数为0.5%的CdWO4单晶.晶体的颜色由上部血红色逐渐加深至下部的黑褐色.对不同部位的晶体薄片进行800℃的氧化处理,测定了处理前后不同部位的吸收光谱和FTIR红外光谱.经氧气退火处理后,由于氧空位缺陷减少,晶体的颜色明显变淡.在吸收光谱中观测到421,684,805 nm的吸收带.其中421 nm的吸收峰随退火温度的升高而逐步减弱,经800℃处理后基本消失.在808 nm激光二极管激发下,观察到中心波长为1.5 μm和1.8 μm的荧光发射,分别对应于Tm3+的3H4→3 F4,3F4→3 H6的能级跃迁.%Tm3 + -doped CdWO4 single crystal with a size of ψ25 mm x 90 mm was grown by the Bridgman method. The raw mole fraction of Tm2O3 in crystal was 0.5%. The upper part of crystal grown at the final stage appears blood-red color, while the lower at the initial stage brown-blackness. The absorption and IR spectra of various parts of crystal before and after O2-annealing were characterized. The color of the crystal becomes weak after the crystal is treated at O2 atmosphere due to the reducing of oxygen vacant defect. The peaks of 421,684 and 805 nm were observed in the absorption spectra. The peak of 421 nm becomes weak gradually with the increase of annealing tempearture, and almost disappears after 800 ℃. The emission spectra of single crystal were also investigated under the excitation of 808 nm at room temperature. A strong emission band at 1. 50 μm and a weak band at 1. 80 μm were observed, which corresponding to the 3 H4 →3 F4 and 3F4→3H6 transitions of Tm3+ , respectively.

  15. Optical Properties of β-RDX Thin Films Deposited on Gold and Stainless Steel Substrates Calculated from Reflection-Absorption Infrared Spectra.

    Science.gov (United States)

    Ruiz-Caballero, José L; Aparicio-Bolaño, Joaquín A; Figueroa-Navedo, Amanda M; Pacheco-Londoño, Leonardo C; Hernandez-Rivera, Samuel P

    2017-08-01

    The optical properties for crystalline films of the highly energetic material (HEM) hexahydro-1,3,5-trinitro-s-triazine, which is also known as RDX, deposited on gold (Au) and stainless steel (SS) substrates are presented. RDX has two important stable conformational polymorphs at room temperature: α-RDX and β-RDX. The optical properties obtained in the present work correspond to thin film samples of predominantly β-RDX polymorph. The infrared spectroscopic intensities measured showed significant differences in the β-RDX crystalline films deposited on the two substrates with respect to the calculated real part of refractive index. The β-RDX/Au crystalline films have a high dynamic response, which is characterized by the asymmetric stretching mode of the axial nitro groups, whereas for the β-RDX/SS crystalline films, the dynamic response was mediated by the -N-NO2 symmetric stretch mode. This result provides an idea of how the electric field vector propagates through the β-RDX crystalline films deposited on the two substrates.

  16. Action spectra of zebrafish cone photoreceptors.

    Directory of Open Access Journals (Sweden)

    Duco Endeman

    Full Text Available Zebrafish is becoming an increasingly popular model in the field of visual neuroscience. Although the absorption spectra of its cone photopigments have been described, the cone action spectra were still unknown. In this study we report the action spectra of the four types of zebrafish cone photoreceptors, determined by measuring voltage responses upon light stimulation using whole cell patch clamp recordings. A generic template of photopigment absorption spectra was fit to the resulting action spectra in order to establish the maximum absorption wavelength, the A2-based photopigment contribution and the size of the β-wave of each cone-type. Although in general there is close correspondence between zebrafish cone action- and absorbance spectra, our data suggest that in the case of MWS- and LWS-cones there is appreciable contribution of A2-based photopigments and that the β-wave for these cones is smaller than expected based on the absorption spectra.

  17. Total ozone column, aerosol optical depth and precipitable water effects on solar erythemal ultraviolet radiation recorded in Malta.

    Science.gov (United States)

    Bilbao, Julia; Román, Roberto; Yousif, Charles; Mateos, David; Miguel, Argimiro

    2013-04-01

    The Universities of Malta and Valladolid (Spain) developed a measurement campaign, which took place in the Institute for Energy Technology in Marsaxlokk (Southern Malta) between May and October 2012, and it was supported by the Spanish government through the Project titled "Measurement campaign about Solar Radiation, Ozone, and Aerosol in the Mediterranean area" (with reference CGL2010-12140-E). This campaign provided the first ground-based measurements in Malta of erythemal radiation and UV index, which indicate the effectiveness of the sun exposure to produce sunburn on human skin. A wide variety of instruments was involved in the campaign, providing a complete atmospheric characterization. Data of erythemal radiation and UV index (from UVB-1 pyranometer), total shortwave radiaton (global and diffuse components from CM-6B pyranometers), and total ozone column, aerosol optical thickness, and precitable water column (from a Microtops-II sunphotometer) were available in the campaign. Ground-based and satellite instruments were used in the analysis, and several intercomparisons were carried out to validate remote sensing data. OMI, GOME, GOME-2, and MODIS instruments, which provide data of ozone, aerosol load and optical properties, were used to this end. The effects on solar radiation, ultraviolet and total shortwave ranges, of total ozone column, aerosol optical thickness and precipitable water column were obtained using radiation measurements at different fixed solar zenith angles. The empirical results shown a determinant role of the solar position, a negligible effect of ozone on total shortwave radiation, and a stronger attenuation provided by aerosol particles in the erythemal radiation. A variety of aerosol types from different sources (desert dust, biomass burning, continental, and maritime) reach Malta, in this campaign several dust events from the Sahara desert occurred and were analyzed establishing the air mass back-trajectories ending at Malta at

  18. An optical comparator for measuring two-dimensional polyacrylamide gel electrophoresis records using an on-line microcomputer.

    Science.gov (United States)

    Spragg, S P; Jones, M I; Hill, B J

    1983-03-01

    A comparator which makes it possible to compare two wet gels or photographic negatives or autoradiograms through a flickering light system has been built. The system consists of two special-purpose projectors which combine the images on a digitizing platform. When the lights are switched On and off out of phase, the positions of the common components remain unchanged, whereas those that are spatially displaced appear to jump from side to side and those present in one image but not the other switch on and off. This produces a flickering image in which differences are readily seen. Commercial camera lenses were used to construct the projectors and the overall specifications for the system are given. The coordinates of both the displaced components, as well as the selected standards from the two images, are digitized and entered automatically into an on-line microcomputer. By using an iterative procedure for collecting records from several superimposable records of the gel, it is possible to compensate for the lack of total reproducibility over the whole gels. These coordinates are then normalized and superimposed on a master map through a television display using a curser to adjust the coordinates. The whole procedure can be repeated for many gels using a common reference gel in the comparator, and the result is a set of normalized coordinates which can be plotted on a single map to provide a final record of the experiments.

  19. Analysis of the optical and magnetooptical spectra of non-Kramers Pr{sup 3+}(4f{sup 2}) in Y{sub 3}Al{sub 5}O{sub 12} complemented by crystal-field modelling

    Energy Technology Data Exchange (ETDEWEB)

    Valiev, Uygun V. [Faculty of Physics, National University of Uzbekistan, Vuzgorodok, Tashkent 100174 (Uzbekistan); Gruber, John B. [Department of Physics and Astronomy, The University of Texas at San Antonio, San Antonio, Texas 78249 (United States); Burdick, Gary W. [Department of Physics, Andrews University, Berrien Springs, MI 49104 (United States); Mukhammadiev, Anvar K. [Faculty of Physics, National University of Uzbekistan, Vuzgorodok, Tashkent 100174 (Uzbekistan); Fu, Dejun, E-mail: 592563827@qq.com [School of Physics and Technology, Wuhan University, 430072 Wuhan (China); Pelenovich, Vasiliy O. [School of Physics and Technology, Wuhan University, 430072 Wuhan (China)

    2014-01-15

    The spectra of the absorption, luminescence, magnetic circular dichroism (MCD) and magnetic circular polarization of luminescence (MCPL) in the praseodymium yttrium garnet aluminate Pr{sup 3+}:YAG have been studied within the visible and near ultraviolet (UV) spectral range for temperature T=90 K and 300 K. Analysis of the spectral and the temperature dependences of the magnetooptical and optical spectra has made it possible to identify the optical 4f→4f transitions occurring between the Stark sublevels of the {sup 1}D{sub 2}, {sup 3}P{sub 0} and {sup 3}H{sub 4} multiplets in Pr{sup 3+}:YAG. It has been shown that for Pr{sup 3+}:YAG in the MCD within the UV spectral range for the absorption bands due to allowed 4f→5d transitions, and also in the MCPL for the luminescence bands, respectively, due to forbidden 4f→4f transitions within the visible spectral range, a significant role is being played by the effect of quantum mechanical “mixing” of the states of the three lowest energy Stark singlets of the ground state {sup 3}H{sub 4} multiplet of the non-Kramers RE Pr{sup 3+} ion. A parameterized Hamiltonian defined to operate within the entire 4f{sup 2} ground electronic configuration of Pr{sup 3+} was used to model the experimental Stark levels, their irreducible representations (irreps) and wave functions. The crystal-field parameters were determined through use of a Monte-Carlo method in which nine independent crystal-field parameters, B{sub q}{sup k}, were given random starting values and optimized using standard least-squares fitting between calculated and experimental levels. The final fitting standard deviation between 61 calculated to experimental Stark levels is 18 cm{sup −1}. -- Highlights: • We concentrate on VUV-UV–vis spectroscopic properties of Pr,Ce:YSO crystal. • The polarized absorption bands for inter-configuration transitions of Ce{sup 3+} and Pr{sup 3+} were assigned. • Dependence of luminescence spectra of Pr,Ce:YSO on

  20. Anharmonicity of Zone-Center Optical Phonons: Raman Scattering Spectra of GaSe0.5S0.5 Layered Crystal

    Science.gov (United States)

    Gasanly, N. M.; Aydinli, A.; Aydinli, A.; Kocabaş, C.; Özkan, H.

    The temperature dependencies (10-300 K) of the eight Raman-active mode frequencies and linewidths in GaSe0.5S0.5 layered crystal have been measured in the frequency range from 10 to 320 cm-1. We observed softening and broadening of the optical phonon lines with increasing temperature. Comparison of the experimental data with the theories of the shift and broadening of the interlayer and intralayer phonon lines showed that the temperature dependencies can be explained by the contributions from thermal expansion, lattice anharmonicity and crystal disorder. The purely anharmonic contribution (phonon-phonon coupling) is found to be due to three-phonon processes. It was established that the effect of crystal disorder on the broadening of phonon lines is greater for GaSe0.5S0.5 than for binary compounds GaSe and GaS.

  1. The role of cathodic current in PEO of aluminum: Influence of cationic electrolyte composition on the transient current-voltage curves and the discharges optical emission spectra

    Science.gov (United States)

    Rogov, A. B.; Shayapov, V. R.

    2017-02-01

    In this paper, the influence of cationic electrolytes composition on electrical and optical responses of plasma electrolytic oxidation process of A1050 aluminum alloy under alternating polarization is considered. The electrolytes consist of 0.1 M boric acid with addition of one of the following hydroxides: LiOH, NaOH, KOH, tetraethylammonium hydroxide, Ca(OH)2 up to pH value 9.2. Coatings microstructure, elemental and phase compositions were studied by SEM, EDS and XRD. It was shown that the hysteresis of anodic current-voltage curve (specific feature of "Soft sparking" PEO) was clear observed in the presence of sodium and potassium cations. It was found that composition of microdischarges plasma is also affected by the nature of the cations. It was shown that there are a number of reciprocal processes, which take place under anodic and cathodic polarization.

  2. Correlation between optical emission spectra and the process parameters of a 915 MHz microwave plasma CVD reactor used for depositing polycrystalline diamond coatings

    Indian Academy of Sciences (India)

    Awadesh Kumar Mallik; Sandip Bysakh; Someswar Dutta; Debabrata Basu

    2014-08-01

    In this paper, the hydrogen and hydrogen-methane mixed plasma have been generated inside a 33 cm diameter quartz bell jar with a low power (9 KW) and lower frequency 915 MHz microwave plasma chemical vapor deposition system. The reactor is being used for growing polycrystalline diamond (PCD) over large area (100 mm). The generated plasma is diagnosed by in situ optical emission spectroscopy method with wave length ranging from 200 to 900 nm. The effects of microwave power, chamber pressure and gas concentration on plasma characteristics have been studied in this work. Within the optical range, Balmer H, H, C2swan band and CH lines have been detected at the wavelengths of 655.95, 485.7, 515.82 and 430.17 nm, respectively. It has been observed that for hydrogen plasma, the amount of transition from hydrogen atom inner shell 3 to 2 (H) is almost constant with increasing microwave (MW) power (from 2000 to 2800 W) and pressure (from 15 to 30 Torr) initially, after that it increases with further increase of MW power and pressure, whereas, the transition from 4 to 2 (H) is slowly increased with increasing MW power and pressure. For hydrogen-methane plasma, intensities of C2 swan band, i.e., the transitions from D$^3\\Pi_\\text{g}$ to A$^3\\Pi_{\\mu}$ energy levels, are also increased with the increasing microwave power and reactor pressure. It has been observed that the radicals present in the plasma are affected by variation of different reactor parameters like pressure, MW power, CH4 concentration, etc.

  3. Optical trapping of nanoparticles with significantly reduced laser powers by using counter-propagating beams (Presentation Recording)

    Science.gov (United States)

    Zhao, Chenglong; LeBrun, Thomas W.

    2015-08-01

    Gold nanoparticles (GNP) have wide applications ranging from nanoscale heating to cancer therapy and biological sensing. Optical trapping of GNPs as small as 18 nm has been successfully achieved with laser power as high as 855 mW, but such high powers can damage trapped particles (particularly biological systems) as well heat the fluid, thereby destabilizing the trap. In this article, we show that counter propagating beams (CPB) can successfully trap GNP with laser powers reduced by a factor of 50 compared to that with a single beam. The trapping position of a GNP inside a counter-propagating trap can be easily modulated by either changing the relative power or position of the two beams. Furthermore, we find that under our conditions while a single-beam most stably traps a single particle, the counter-propagating beam can more easily trap multiple particles. This (CPB) trap is compatible with the feedback control system we recently demonstrated to increase the trapping lifetimes of nanoparticles by more than an order of magnitude. Thus, we believe that the future development of advanced trapping techniques combining counter-propagating traps together with control systems should significantly extend the capabilities of optical manipulation of nanoparticles for prototyping and testing 3D nanodevices and bio-sensing.

  4. Parallel heterodyne detection of dynamic light scattering spectra from gold nanoparticles diffusing in viscous fluids

    CERN Document Server

    Atlan, Michael; Gross, Michel; Coppey-Moisan, Maite; 10.1364/OL.35.000787

    2010-01-01

    We developed a microscope intended to probe, using a parallel heterodyne receiver, the fluctuation spectrum of light quasi-elastically scattered by gold nanoparticles diffusing in viscous fluids. The cutoff frequencies of the recorded spectra scale up linearly with those expected from single scattering formalism in a wide range of dynamic viscosities (1 to 15 times water viscosity at room temperature). Our scheme enables ensemble-averaged optical fluctuations measurements over multispeckle recordings in low light, at temporal frequencies up to 10 kHz, with a 12 Hz framerate array detector.

  5. Phonon States and Dispersive Spectra of Polar Optical Phonons in Quasi-One-Dimensional Nanowires of Wurtzite ZnO and Zinc-Blend MgO Semiconductors*

    Institute of Scientific and Technical Information of China (English)

    ZHANG Li

    2011-01-01

    Within the framework of the macroscopic dielectric continuum model and Loudon's uniaxial crystal model,the phonon modes of a wurtzite/zinc-blende one-dimensional (ID) cylindrical nanowire (NW) are derived and studied.The analytical phonon states of phonon modes are given.It is found that there exist two types of polar phonon modes,i.e.interface optical (IO) phonon modes and the quasi-confined (QC) phonon modes existing in 1D wurtzite/zinc-blende NWs.Via the standard procedure of field quantization, the Frohlich electron-phonon interaction Hamiltonians are obtained.Numerical calculations of dispersive behavior of these phonon modes on a wurtzite/zinc-blende ZnO/MgO NW are performed.The frequency ranges of the I0 and QC phonon modes of the ZnO/MgO NWs are analyzed and discussed.It is found that the IO modes only exist in one frequency range, while QC modes may appear in three frequency ranges.The dispersive properties of the IO and QC modes on the free wave-number kz and the azimuthal quantum number m are discussed.The analytical Hamiltonians of electron-phonon interaction obtained here are quite useful for further investigating phonon influence on optoelectronics properties of wurtzite/zinc-blende 1D NW structures.

  6. Metallicity of M dwarfs IV. A high-precision [Fe/H] and Teff technique from high-resolution optical spectra for M dwarfs

    CERN Document Server

    Neves, V; Santos, N C; Delfosse, X; Forveille, T; Allard, F; Udry, S

    2014-01-01

    Aims. In this work we develop a technique to obtain high precision determinations of both metallicity and effective temperature of M dwarfs in the optical. Methods. A new method is presented that makes use of the information of 4104 lines in the 530-690 nm spectral region. It consists in the measurement of pseudo equivalent widths and their correlation with established scales of [Fe/H] and $T_{eff}$. Results. Our technique achieves a $rms$ of 0.08$\\pm$0.01 for [Fe/H], 91$\\pm$13 K for $T_{eff}$, and is valid in the (-0.85, 0.26 dex), (2800, 4100 K), and (M0.0, M5.0) intervals for [Fe/H], $T_{eff}$ and spectral type respectively. We also calculated the RMSE$_{V}$ which estimates uncertainties of the order of 0.12 dex for the metallicity and of 293 K for the effective temperature. The technique has an activity limit and should only be used for stars with $\\log{L_{H_{\\alpha}}/L_{bol}} < -4.0$. Our method is available online at \\url{http://www.astro.up.pt/resources/mcal}.

  7. Directional spectra of ocean waves from microwave backscatter: A physical optics solution with application to the short-pulse and two-frequency measurement techniques

    Science.gov (United States)

    Jackson, F. C.

    1979-01-01

    Two simple microwave radar techniques that are potentially capable of providing routine satellite measurements of the directional spectrum of ocean waves were developed. One technique, the short pulse technique, makes use of very short pulses to resolve ocean surface wave contrast features in the range direction; the other technique, the two frequency correlation technique makes use of coherency in the transmitted waveform to detect the large ocean wave contrast modulation as a beat or mixing frequency in the power backscattered at two closely separated microwave frequencies. A frequency domain analysis of the short pulse and two frequency systems shows that the two measurement systems are essentially duals; they each operate on the generalized (three frequency) fourth-order statistical moment of the surface transfer function in different, but symmetrical ways, and they both measure the same directional contrast modulation spectrum. A three dimensional physical optics solution for the fourth-order moment was obtained for backscatter in the near vertical, specular regime, assuming Gaussian surface statistics.

  8. Effect of Annealing Temperature on the Optical Spectra of CdS Thin Films Deposited at Low Solution Concentrations by Chemical Bath Deposition (CBD Technique

    Directory of Open Access Journals (Sweden)

    Zahid Rizwan

    2011-02-01

    Full Text Available Two different concentrations of CdCl2 and (NH22CS were used to prepare CdS thin films, to be deposited on glass substrate by chemical bath deposition (CBD technique. CdCl2 (0.000312 M and 0.000625 M was employed as a source of Cd2+ while (NH22CS (0.00125 M and 0.000625 M for S2− at a constant bath temperature of 70 °C. Adhesion of the deposited films was found to be very good for all the solution concentrations of both reagents. The films were air-annealed at a temperature between 200 °C to 360 °C for one hour. The minimum thickness was observed to be 33.6 nm for film annealed at 320 °C. XRD analyses reveal that the films were cubic along with peaks of hexagonal phase for all film samples. The crystallite size of the films decreased from 41.4 nm to 7.4 nm with the increase of annealing temperature for the CdCl2 (0.000312 M. Optical energy band gap (Eg, Urbach energy (Eu and absorption coefficient (α have been calculated from the transmission spectral data. These parameters have been discussed as a function of annealing temperature and solution concentration. The best transmission (about 97% was obtained for the air-annealed films at higher temperature at CdCl2 (0.000312 M.

  9. Effect of annealing temperature on the optical spectra of CdS thin films deposited at low solution concentrations by Chemical Bath Deposition (CBD) Technique.

    Science.gov (United States)

    Rizwan, Zahid; Zakaria, Azmi; Mohd Ghazali, Mohd Sabri; Jafari, Atefeh; Din, Fasih Ud; Zamiri, Reza

    2011-02-22

    Two different concentrations of CdCl(2) and (NH(2))(2)CS were used to prepare CdS thin films, to be deposited on glass substrate by chemical bath deposition (CBD) technique. CdCl(2) (0.000312 M and 0.000625 M) was employed as a source of Cd(2+) while (NH(2))(2)CS (0.00125 M and 0.000625 M) for S(2-) at a constant bath temperature of 70 °C. Adhesion of the deposited films was found to be very good for all the solution concentrations of both reagents. The films were air-annealed at a temperature between 200 °C to 360 °C for one hour. The minimum thickness was observed to be 33.6 nm for film annealed at 320 °C. XRD analyses reveal that the films were cubic along with peaks of hexagonal phase for all film samples. The crystallite size of the films decreased from 41.4 nm to 7.4 nm with the increase of annealing temperature for the CdCl(2) (0.000312 M). Optical energy band gap (E(g)), Urbach energy (E(u)) and absorption coefficient (α) have been calculated from the transmission spectral data. These parameters have been discussed as a function of annealing temperature and solution concentration. The best transmission (about 97%) was obtained for the air-annealed films at higher temperature at CdCl(2) (0.000312 M).

  10. Shipboard Sunphotometer Measurements of Aerosol Optical Depth Spectra and Columnar Water Vapor During ACE-2 and Comparison with Selected Land, Ship, Aircraft, and Satellite Measurements

    Science.gov (United States)

    Livingston, John M.; Kapustin, Vladimir N.; Schmid, Beat; Russell, Philip B.; Quinn, Patricia K.; Bates, Timothy S.; Durkee, Philip A.; Smith, Peter J.; Freudenthaler, Volker; Wiegner, Matthias; Covert, Dave S.; Gasso, Santiago; Hegg, Dean; Collins, Donald R.; Flagan, Richard C.; Seinfeld, John H.; Vitale, Vito; Tomasi, Claudio

    2000-01-01

    Analyses of aerosol optical depth (AOD) and colurnmn water vapor (CWV) measurements acquired with NASA Ames Research Center's 6-channel Airborne Tracking Sunphotometer (AATS-6) operated aboard the R/V Professor Vodyanitskiy during the 2nd Aerosol Characterization Experiment (ACE-2) are discussed. Data are compared with various in situ and remote measurements for selected cases. The focus is on 10 July, when the Pelican airplane flew within 70 km of the ship near the time of a NOAA-14/AVHRR satellite overpass and AOD measurements with the 14-channel Ames Airborne Tracking Sunphotometer (AATS-14) above the marine boundary layer (MBL) permitted calculation of AOD within the MBL from the AATS-6 measurements. A detailed column closure test is performed for MBL AOD on 10 July by comparing the AATS-6 MBL AODs with corresponding values calculated by combining shipboard particle size distribution measurements with models of hygroscopic growth and radiosonde humidity profiles (plus assumptions on the vertical profile of the dry particle size distribution and composition). Large differences (30-80% in the mid-visible) between measured and reconstructed AODs are obtained, in large part because of the high sensitivity of the closure methodology to hygroscopic growth models, which vary considerably and have not been validated over the necessary range of particle size/composition distributions. The wavelength dependence of AATS-6 AODs is compared with the corresponding dependence of aerosol extinction calculated from shipboard measurements of aerosol size distribution and of total scattering mearured by a shipboard integrating nephelometer for several days. Results are highly variable, illustrating further the great difficulty of deriving column values from point measurements. AATS-6 CWV values are shown to agree well with corresponding values derived from radiosonde measurements during 8 soundings on 7 days and also with values calculated from measurements taken on 10 July with

  11. Polarised Raman and infrared spectral analysis of L-alanine oxalate (C5H9NO6)--a non-linear optical single crystal.

    Science.gov (United States)

    Krishnakumar, V; Nagalakshmi, R

    2006-06-01

    L-alanine oxalate (C5H9NO6), a promising material for effective frequency conversion, was grown by standard slow evaporation technique. Solubility studies were carried out at different temperatures. Unambiguous assignments of fundamental modes of various molecular groups were made from the recorded infrared and polarised Raman spectra. The non-linear optical property has been confirmed from the optical transmission and fluorescence spectra.

  12. Magnetic anisotropy and spin reorientation effects in Gd/Fe and Gd/(FeCo) multilayers for high density magneto-optical recording

    Science.gov (United States)

    Stavrou, E.; Sbiaa, R.; Suzuki, T.; Knappmann, S.; Röll, K.

    2000-05-01

    We have investigated the anisotropy behavior and temperature dependent changes of the magnetic anisotropy in Gd/Fe and Gd/(FeCo) multilayers. The spin reorientation effects are very important for the super resolution readout in new methods for high-density magneto-optical recording. Gd/(Fe, Co) multilayered films are a good alternative to the common Gd(Fe, Co) alloy films, because the magnetic anisotropy and also spin reorientation effects can be comfortably adjusted by varying the interface and volume anisotropy components and the composition using experimental parameters such as the periodicity λ=tGd+tTM [tGd,tTM: the sublayer thicknesses of the Gd and transition metal Fe, FeCo (TM)] and the ratio of the sublayer thicknesses tGd/tTM. We have found the mechanisms for spin reorientation, which are explained qualitatively with a new model.

  13. 基于透射光谱确定溅射Al2O3薄膜的光学常数%Determination of the optical constants of the magnetron sputtered aluminum oxide films from the transmission spectra

    Institute of Scientific and Technical Information of China (English)

    廖国进; 骆红; 闫绍峰; 戴晓春; 陈明

    2011-01-01

    By combining Swanepoel's theory and the Wemple-DiDomenico dispersion model, a simple method was established to determine the optical contants of the magnetron sputtered aluminum oxide films directly from the corresponding transmission spectra. The results showed that the magnetron sputtered aluminum oxide films exhibit the optical characteristics of high refractive index of 1. 566-1.76 ( at 550 nm), negligible absorption in spectral region of 4001100 nm, as well as the direct band gap of about 3.91-4. 2 eV. And the specific values of the optical constants strongly depend on the annealing temperature , which is one of the important technological parameters for the magnetron sputtered aluminum oxide films. Moreover, in the weak and medium absorption spectral regions, the calculated values of refractive indices are in satisfactory agreement with the results derived from the high-resolution Tek3000 film - characterization system, indicating the reliability and feasibility of the method in determining the optical constants of Al2O3films.%基于反应磁控溅射Al2O3薄膜的紫外一可见一近红外透射实验光谱,采用Swanepoel方法结合Wemple-DiDomenico色散模型,方便地导出了Al2O3薄膜在200-1100 nm波长范围内的光学常数,包括折射率、色散常数、膜层厚度、吸收系数及能量带隙.研究发现反应磁控溅射Al2O3薄膜具有高折射率(1.556-1.76,测试波长为550nm)、低吸收和直接能量带隙(3.91-4.20 eV)等光学特性,而且其光学常数对薄膜制备过程中的重要工艺参数--膜层后处理温度表现出强烈的依赖性.此外,在膜层的弱吸收和中等吸收光谱区域内,计算得到的折射率色散曲线与分光光度法的测试结果基本符合,说明本实验中所建立的计算方法在确定反应磁控溅射Al2O3薄膜光学常数方面的可靠性.

  14. The high resolution vacuum ultraviolet absorption spectra of the group VI dihydrides and deuterides Rydberg series

    CERN Document Server

    Mayhew, C A

    1984-01-01

    The high resolution absorption spectra of the important group VI dihydrides and deuterides in the vacuum ultraviolet below, and up to, their first ionisation potentials are presented. These spectra were recorded using synchrotron radiation as the background light source in conjunction with a 3m normal incidence vacuum spectrograph, equipped with holographic gratings. Due to the nature of the originating orbital for the majority of optical transitions in the VUV well developed Rydberg series are observed. One particular series can be followed up to fairly high n, so that accurate values of the first ionisation potential are determined. The identifications of the Rydberg series are made from arguments relating to their oscillator strengths, quantum defects, symmetries and from comparisons with the spectra of the corresponding united atoms i.e. the inert gases. Examples of the symmetry assignments for Rydberg series from rotational band contour analyses of the lower Rydberg members for the H sub 2 S, H sub 2 Se ...

  15. General Notes on Processes and Their Spectra

    Directory of Open Access Journals (Sweden)

    Gustav Cepciansky

    2012-01-01

    Full Text Available The frequency spectrum performs one of the main characteristics of a process. The aim of the paper is to show the coherence between the process and its own spectrum and how the behaviour and properties of a process itself can be deduced from its spectrum. Processes are categorized and general principles of their spectra calculation and recognition are given. The main stress is put on power spectra of electric and optic signals, as they also perform a kind of processes. These spectra can be directly measured, observed and examined by means of spectral analyzers and they are very important characteristics which can not be omitted at transmission techniques in telecommunication technologies. Further, the paper also deals with non electric processes, mainly with processes and spectra at mass servicing and how these spectra can be utilised in praxis.

  16. Conductivity and optical spectra of Pr sub 1 sub - sub x Y sub x Ba sub 2 Cu sub 3 O sub y (x=0, 0.5 and 1.0)

    CERN Document Server

    Kakinuma, K; Fueki, K

    1999-01-01

    In order to clarify the electronic structure of High-T sub c superconducting oxide, we measured the oxygen-nonstoichiometry, conductivity at temperatures, up to 12000 K, and the optical spectra for three kinds of oxides, YBa sub 2 Cu sub 3 O sub y , (Pr sub 0 sub . sub 5 Y sub 0 sub . sub 5)Ba sub 2 Cu sub 3 O sub y , and PrBa sub 2 Cu sub 3 O sub y. No difference was found in oxygen nonstoichiometry. At high temperature, we detected a conductivity minimum (sigma sub m sub i sub n) in the Log sub 1 sub 0 sigma-log sub 1 sub 0 Po sub 2 plot at constant temperature. From the slope of the Arrhenius plot for sigma sub m sub i sub n , the CT gap was 1.37, 1.32 and 1.21 eV for YBa sub 2 Cu sub 3 O sub y , (Pr sub 0 sub . sub 5 Y sub 0 sub . sub 5)Ba sub 2 Cu sub 3 O sub y , and PrBa sub 2 Cu sub 3 O sub y respectively. The energy gap (DELTA E) between the acceptor level and the top of the valence band was calculated from the slope of the Arrhenius plot for p-type conductivity. The DELTA E for the superconducting YB...

  17. Reactor Neutrino Spectra

    CERN Document Server

    Hayes, A C

    2016-01-01

    We present a review of the antineutrino spectra emitted from reactors. Knowledge of these and their associated uncertainties are crucial for neutrino oscillation studies. The spectra used to-date have been determined by either conversion of measured electron spectra to antineutrino spectra or by summing over all of the thousands of transitions that makeup the spectra using modern databases as input. The uncertainties in the subdominant corrections to beta-decay plague both methods, and we provide estimates of these uncertainties. Improving on current knowledge of the antineutrino spectra from reactors will require new experiments. Such experiments would also address the so-called reactor neutrino anomaly and the possible origin of the shoulder observed in the antineutrino spectra measured in recent high-statistics reactor neutrino experiments.

  18. Thermal Emission and Albedo Spectra of Super Earths with Flat Transmission Spectra

    CERN Document Server

    Morley, Caroline V; Marley, Mark S; Zahnle, Kevin; Line, Michael; Kempton, Eliza; Lewis, Nikole; Cahoy, Kerri

    2015-01-01

    Planets larger than Earth and smaller than Neptune are some of the most numerous in the galaxy, but observational efforts to understand this population have proved challenging because optically thick clouds or hazes at high altitudes obscure molecular features (Kreidberg et al. 2014b). We present models of super Earths that include thick clouds and hazes and predict their transmission, thermal emission, and reflected light spectra. Very thick, lofted clouds of salts or sulfides in high metallicity (1000x solar) atmospheres create featureless transmission spectra in the near-infrared. Photochemical hazes with a range of particle sizes also create featureless transmission spectra at lower metallicities. Cloudy thermal emission spectra have muted features more like blackbodies, and hazy thermal emission spectra have emission features caused by an inversion layer at altitudes where the haze forms. Close analysis of reflected light from warm (~400-800 K) planets can distinguish cloudy spectra, which have moderate ...

  19. POLLUX : a database of synthetic stellar spectra

    CERN Document Server

    Palacios, A; Josselin, E; Martins, F; Plez, B; Belmas, M; Lebre, A

    2010-01-01

    Synthetic spectra are needed to determine fundamental stellar and wind parameters of all types of stars. They are also used for the construction of theoretical spectral libraries helpful for stellar population synthesis. Therefore, a database of theoretical spectra is required to allow rapid and quantitative comparisons to spectroscopic data. We provide such a database offering an unprecedented coverage of the entire Hertzsprung-Russell diagram. We present the POLLUX database of synthetic stellar spectra. For objects with Teff 25 000 K). Their spectra are computed with CMF_FLUX. Both high resolution (R>150 000) optical spectra in the range 3 000 to 12 000 A and spectral energy distributions extending from the UV to near--IR ranges are presented. These spectra cover the HR diagram at solar metallicity. We propose a wide variety of synthetic spectra for various types of stars in a format that is compliant with the Virtual Observatory standards. A user--friendly web interface allows an easy selection of spectra...

  20. Decomposition of spectra using maximum autocorrelation factors

    DEFF Research Database (Denmark)

    Larsen, Rasmus

    2001-01-01

    into classification or regression type analyses. A featured method for low dimensional representation of multivariate datasets is Hotellings principal components transform. We will extend the use of principal components analysis incorporating new information into the algorithm. This new information consists......This paper addresses the problem of generating a low dimensional representation of the variation present in a set of spectra, e.g. reflection spectra recorded from a series of objects. The resulting low dimensional description may subseque ntly be input through variable selection schemes...... Fourier decomposition these new variables are located in frequency as well as well wavelength. The proposed algorithm is tested on 100 samples of NIR spectra of wheat....

  1. Relationships between columnar aerosol optical properties and surface particulate matter observations in north-central Spain from long-term records (2003–2011

    Directory of Open Access Journals (Sweden)

    Y. S. Bennouna

    2014-06-01

    Full Text Available This work examines the relationships between Aerosol Optical Depth (AOD and Particulate Matter (PMX parameters, based on long records (2003–2011 of two nearby sites from the AERONET and EMEP networks in the north-central area of Spain. The climatological annual cycle of PM10 and PM2.5 present a bimodality which might be partly due to desert dust intrusions, a pattern which does not appear in the annual cycle of the AOD. In the case of the AOD, this bimodality is likely to be masked because of the poor sampling of sunphotometer data as compared to PMX (67% of days against 90%, and this fact stresses the necessity of long-term observations. In monthly series, significant interannual variations are observed and most extrema coincide, however the bimodal shape remains relatively stable for PMX. Significant and consistent trends were found for both datasets likely associated to a decrease of desert dust apportionment until 2009. PM10 and AOD daily data are moderately correlated (0.56, a correlation improving for monthly means (0.70. In the case of strong desert dust events day-to-day correlation is not systematic, therefore an extensive analysis on PMX, fine-PM ratio, AOD and associated Ångström exponent (α is carried out.

  2. Simultaneous optical recording in multiple cells by digital holographic microscopy of chloride current associated to activation of the ligand-gated chloride channel GABA(A) receptor.

    Science.gov (United States)

    Jourdain, Pascal; Boss, Daniel; Rappaz, Benjamin; Moratal, Corinne; Hernandez, Maria-Clemencia; Depeursinge, Christian; Magistretti, Pierre Julius; Marquet, Pierre

    2012-01-01

    Chloride channels represent a group of targets for major clinical indications. However, molecular screening for chloride channel modulators has proven to be difficult and time-consuming as approaches essentially rely on the use of fluorescent dyes or invasive patch-clamp techniques which do not lend themselves to the screening of large sets of compounds. To address this problem, we have developed a non-invasive optical method, based on digital holographic microcopy (DHM), allowing monitoring of ion channel activity without using any electrode or fluorescent dye. To illustrate this approach, GABA(A) mediated chloride currents have been monitored with DHM. Practically, we show that DHM can non-invasively provide the quantitative determination of transmembrane chloride fluxes mediated by the activation of chloride channels associated with GABA(A) receptors. Indeed through an original algorithm, chloride currents elicited by application of appropriate agonists of the GABA(A) receptor can be derived from the quantitative phase signal recorded with DHM. Finally, chloride currents can be determined and pharmacologically characterized non-invasively simultaneously on a large cellular sampling by DHM.

  3. Simultaneous optical recording in multiple cells by digital holographic microscopy of chloride current associated to activation of the ligand-gated chloride channel GABA(A receptor.

    Directory of Open Access Journals (Sweden)

    Pascal Jourdain

    Full Text Available Chloride channels represent a group of targets for major clinical indications. However, molecular screening for chloride channel modulators has proven to be difficult and time-consuming as approaches essentially rely on the use of fluorescent dyes or invasive patch-clamp techniques which do not lend themselves to the screening of large sets of compounds. To address this problem, we have developed a non-invasive optical method, based on digital holographic microcopy (DHM, allowing monitoring of ion channel activity without using any electrode or fluorescent dye. To illustrate this approach, GABA(A mediated chloride currents have been monitored with DHM. Practically, we show that DHM can non-invasively provide the quantitative determination of transmembrane chloride fluxes mediated by the activation of chloride channels associated with GABA(A receptors. Indeed through an original algorithm, chloride currents elicited by application of appropriate agonists of the GABA(A receptor can be derived from the quantitative phase signal recorded with DHM. Finally, chloride currents can be determined and pharmacologically characterized non-invasively simultaneously on a large cellular sampling by DHM.

  4. An improved holographic recording medium

    Science.gov (United States)

    Gange, R. A.

    1973-01-01

    Solid, linear chain hydrocarbons with molecular weight ranging from about 300 to 2000 can serve as long-lived recording medium in optical memory system. Suitable recording hydrocarbons include microcrystalline waxes and low molecular weight polymers or ethylene.

  5. RF magnetron sputtered (BiDy)3(FeGa)5O12:Bi2O3 composite garnet-oxide materials possessing record magneto-optic quality in the visible spectral region.

    Science.gov (United States)

    Vasiliev, Mikhail; Alam, Mohammad Nur-E; Kotov, Viacheslav A; Alameh, Kamal; Belotelov, Vladimir I; Burkov, Vladimir I; Zvezdin, Anatoly K

    2009-10-26

    Bismuth-substituted iron garnets are considered to be the most promising magneto-optical materials because of their excellent optical transparency and very high magneto-optical figures of merit in the near-infrared spectral region. However, the practical application of garnets in the visible and short-wavelength infrared parts of spectrum is currently limited, due to their very high optical absorption (especially in sputtered films) in these spectral regions. In this paper, we identify the likely source of excess absorption observed in sputtered garnet films in comparison with epitaxial layers and demonstrate (Bi,Dy)(3)(Fe,Ga)(5)O(12): Bi(2)O(3) composites possessing record MO quality in the visible region.

  6. Hologram recording tubes

    Science.gov (United States)

    Rajchman, J. H.

    1973-01-01

    Optical memories allow extremely large numbers of bits to be stored and recalled in a matter of microseconds. Two recording tubes, similar to conventional image-converting tubes, but having a soft-glass surface on which hologram is recorded, do not degrade under repeated hologram read/write cycles.

  7. Multivariate analysis of endometrial tissue fluorescence spectra

    Science.gov (United States)

    Vaitkuviene, Aurelija; Auksorius, E.; Fuchs, D.; Gavriushin, V.

    2002-10-01

    Background and Objective: The detailed multivariate analysis of endometrial tissue fluorescence spectra was done. Spectra underlying features and classification algorithm were analyzed. An effort has been made to determine the importance of neopterin component in endometrial premalignization. Study Design/Materials and Methods: Biomedical tissue fluorescence was measured by excitation with the Nd YAG laser third harmonic. Multivariate analysis techniques were used to analyze fluorescence spectra. Biomedical optics group at Vilnius University analyzed the neopterin substance supplied by the Institute of Medical Chemistry and Biochemistry of Innsbruck University. Results: Seven statistically significant spectral compounds were found. The classification algorithm classifying samples to histopathological categories was developed and resulted in sensitivity of 80% and specificity 93% for malignant vs. hyperplastic and normal. Conclusions: Fluorescence spectra could be classified with high accuracy. Spectral variation underlying features can be extracted. Neopterin component might play an important role in endometrial hyperplasia development.

  8. Optical properties of lead–tellurite glasses doped with samarium trioxide

    Indian Academy of Sciences (India)

    B Eraiah

    2010-08-01

    The optical properties of a new family of Sm2O3–(40–)PbO–60TeO2 glasses are investigated. The optical absorption spectra were recorded at room temperature in the UV-visible region. From the absorption edge studies, the values of optical bandgap energies have been evaluated. The refractive index, molar refraction and polarizability of oxide ions have been calculated by using Lorentz–Lorentz relations. The non-linear variations of the above optical parameters are discussed with respect to samarium concentration.

  9. Action spectra again?

    Science.gov (United States)

    Coohill, T P

    1991-11-01

    Action spectroscopy has a long history and is of central importance to photobiological studies. Action spectra were among the first assays to point to chlorophyll as the molecule most responsible for plant growth and to DNA as the genetic material. It is useful to construct action spectra early in the investigation of new areas of photobiological research in an attempt to determine the wavelength limits of the radiation region causing the studied response. But due to the severe absorption of ultraviolet (UV) radiation by biological samples, UV action spectra were first limited to small cells (bacteria and fungi). Advances in techniques (e.g. single cell culture) and analysis allowed accurate action spectra to be reported even for mammalian cells. But precise analytical action spectra are often difficult to obtain when large, pigmented, or groups of cells are investigated. Here some action spectra are limited in interpretation and merely supply a wavelength vs effect curve. When polychromatic sources are employed, the interpretation of action spectra is even more complex and formidable. But such polychromatic action spectra can be more directly related to ambient responses. Since precise action spectra usually require the completion of a relatively large number of careful experiments using somewhat sophisticated equipment over a range of at least six wavelengths, they are often not pursued. But they remain central to the elucidation of the effect being studied. The worldwide community has agreed that stratospheric ozone is depleting, with the possibility of a consequent rise in the amount of UV-B (290-320 nm) reaching the earth's surface. It is therefore essential that new action spectra be completed for UV-B effects on a large variety of responses of human, animal, and aquatic plant systems. Combining these action spectra with the known amounts of UV-B reaching the biosphere can give rise to solar UV effectiveness spectra that, in turn, can give rise to estimates

  10. Highly Functional TNTs with Superb Photocatalytic, Optical, and Electronic Performance Achieving Record PV Efficiency of 10.1% for 1D-Based DSSCs.

    Science.gov (United States)

    Qadir, Muhammad Bilal; Li, Yuewen; Sahito, Iftikhar Ali; Arbab, Alvira Ayoub; Sun, Kyung Chul; Mengal, Naveed; Memon, Anam Ali; Jeong, Sung Hoon

    2016-09-01

    Different nanostructures of TiO2 play an important role in the photocatalytic and photoelectronic applications. TiO2 nanotubes (TNTs) have received increasing attention for these applications due to their unique physicochemical properties. Focusing on highly functional TNTs (HF-TNTs) for photocatalytic and photoelectronic applications, this study describes the facile hydrothermal synthesis of HF-TNTs by using commercial and cheaper materials for cost-effective manufacturing. To prove the functionality and applicability, these TNTs are used as scattering structure in dye-sensitized solar cells (DSSCs). Photocatalytic, optical, Brunauer-Emmett-Teller (BET), electrochemical impedance spectrum, incident-photon-to-current efficiency, and intensity-modulated photocurrent spectroscopy/intensity-modulated photovoltage spectroscopy characterizations are proving the functionality of HF-TNTs for DSSCs. HF-TNTs show 50% higher photocatalytic degradation rate and also 68% higher dye loading ability than conventional TNTs (C-TNTs). The DSSCs having HF-TNT and its composite-based multifunctional overlayer show effective light absorption, outstanding light scattering, lower interfacial resistance, longer electron lifetime, rapid electron transfer, and improved diffusion length, and consequently, J SC , quantum efficiency, and record photoconversion efficiency of 10.1% using commercial N-719 dye is achieved, for 1D-based DSSCs. These new and highly functional TNTs will be a concrete fundamental background toward the development of more functional applications in fuel cells, dye-sensitized solar cells, Li-ion batteries, photocatalysis process, ion-exchange/adsorption process, and photoelectrochemical devices. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. The effect of substrate temperature on the optical properties of polycrystalline Sb 2O 3 thin films

    Science.gov (United States)

    Tigau, N.; Ciupina, V.; Prodan, G.

    2005-04-01

    Polycrystalline antimony trioxide (Sb 2O 3) thin films with a thickness of 800 nm, deposited on glass substrates at different temperature ranges 300-573 K, were optically characterized. The optical parameters such as refractive index, n, absorption coefficient, α, and optical band gap, Eg, were determined using the transmission spectra recorded in the range of 300-1400 nm and simple calculations based on Swanepoel's method including interference effect induced by multiple internal reflections in the substrate/thin film system. The effect of substrate temperature on the optical properties of Sb 2O 3 thin films has been studied. It was found that both refractive index and absorption coefficient depend markedly on the substrate temperature. The optical band gap energies and the corresponding allowed direct transitions have been determined from the absorption spectra. The correlations between optical parameters and the change in structure of the Sb 2O 3 thin films are discussed.

  12. Dynamic Radio Spectra from two Fireballs

    CERN Document Server

    Obenberger, K S; Lin, C S; Dowell, J; Schinzel, F K; Stovall, K

    2015-01-01

    We present dynamic spectra from the LWA1 telescope of two large meteors (fireballs) observed to emit between 37 and 54 MHz. These spectra show the first ever recorded broadband measurements of this newly discovered VHF emission. The spectra show that the emission is smooth and steep, getting very bright at lower frequencies. We suggest that this signal is possibly emission of Langmuir waves and that these waves could be excited by a weak electron beam within the trail. The spectra of one fireball displays broadband temporal frequency sweeps. We suggest that these sweeps are evidence of individual expanding clumps of emitting plasma. While some of these proposed clumps may have formed at the very beginning of the fireball event, others must have formed seconds after the initial event.

  13. Hot NH3 Spectra for Astrophysical Applications

    CERN Document Server

    Hargreaves, R J; Bernath, P F

    2011-01-01

    We present line lists for ammonia (NH$_{3}$) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for twelve temperatures (300 -- 1300$^{\\circ}$C in 100$^{\\circ}$C intervals and 1370$^{\\circ}$C) and each line list covers the 740 -- 2100 cm$^{-1}$ range, which includes the majority of the $\

  14. Title: Near-UV behaviour of observed TNO reflectance spectra

    Science.gov (United States)

    Seccull, Tom; Fraser, Wesley Cristopher; Izawa, Matthew; Brown, Michael E.

    2016-10-01

    Observed spectra provide the best diagnostics of the surface compositions of Trans-Neptunian Objects (TNOs). We have observed the spectra of 7 TNOs, from across almost the full range of dynamical classes, using the VLT's X-Shooter spectrograph. Compared to the 5 targets in our sample which exhibit linear spectra in the UV-optical range, two of of our targets show highly unusual spectral behaviour, whereby their reflectance decreases sharply at wavelengths below ~440nm. Those same objects exhibit typically unremarkable spectra in the optical and near-IR spectral regions. In these regions where available, our observed spectra of the targets are in agreement with spectra or photometry available in the literature. Using a different solar analogue to produce our reflectance spectra does not remove the UV decrease exhibited by the two targets. Further, it appears that neither reducing the spectra with different pipelines, nor using drastically different parameters in those pipelines changes this general behaviour. Based on laboratory spectra of complex hydrocarbons it is plausible that the near-UV behaviour is the result of a surface coating of organic substances on the TNOs which exhibit it. The spectra of organics are also consistent in having a general red slope similar to that observed in the spectra of many TNOs. While laboratory spectra of some silicate substances also show a decrease in reflectance in the near-UV spectral region that is in principle consistent with our observations, those silicates do not exhibit a red slope consistent with our optical spectra. Hence, the hypothesis that silicates are present seems less likely than the hypothesis that this UV decrease is due to the presence of organics on the surfaces of these objects.

  15. Raman Spectra of Glasses

    Science.gov (United States)

    1986-11-30

    17), Raman spectra, plus a , . theoretical treatment of the data, f complex fluorozirconate 14 I anions in ZBLAN glasses and melts (16), and...based ZBLAN glasses ) 17. ICORS (International Conference on Raman Spectroscopy) Proceedings, London, England. Conferencf 5-9 Sep 88. (Molten silica...RESEARCH FINAL REPORT DTIC CONTRACT N00014-81-K-0501 &JELECTE 1 MAY 81 -- 30 NOV 86 EJJAN041989 V "RAMAN SPECTRA OF GLASSES " 0 During the five years of the

  16. Observation of changes in ion beam induced luminescence spectra from organics during focused microbeam irradiation

    Science.gov (United States)

    Kada, Wataru; Kawabata, Shunsuke; Satoh, Takahiro; Sakai, Makoto; Parajuli, Raj Kumar; Yamada, Naoto; Koka, Masashi; Miura, Kenta; Hanaizumi, Osamu; Kamiya, Tomihiro

    2017-08-01

    Continuous measurement of ion beam induced luminescence (IBIL) spectra was demonstrated with organic targets of nicotinamide adenine dinucleotide (NADH), tryptophan, riboflavin, and a polycyclic aromatic hydrocarbon (PAH), which are typically used as markers of biological contaminants in airborne particles. A 3 MeV external proton microbeam from a single-ended accelerator at QST/Takasaki was used to probe for changes in the IBIL spectrum using micro-optics sharing a focal point with the microprobe. We find that the decay of IBIL spectra from NADH and riboflavin varied by target organic species. Moreover, new peaks in the IBIL spectrum were recorded by continuous IBIL spectroscopy from the PAH target after destruction of a peak originally obtained in the initial measurement. These results suggest that IBIL monitoring can detect changes in the chemical composition of organics under focused beam irradiation.

  17. The optical properties of bismuth germanium oxide single crystals

    Directory of Open Access Journals (Sweden)

    ANDREJA VALCIC

    2000-09-01

    Full Text Available Bi12GeO20 single crystals were grown by the Czochralski technique. Suitable polishing and etching solutions were determined. Reflection spectra were recorded in the wave numbers range 20–5000 cm–1, and compared with the spectra of Bi12SiO20 single crystals to study the position of the phonon modes. The optical constants of the Bi12GeO20 single crystals were obtained using Kramers-Kronig analysis. The obtained results are dicussed and compared with published data.

  18. Mid-infrared continuous wave cavity ring down spectroscopy of molecular ions using an optical parametric oscillator

    NARCIS (Netherlands)

    Verbraak, H.; Ngai, A.K.Y.; Persijn, S.T.; Harren, F.J.M.; Linnartz, H.

    2007-01-01

    A sensitive infrared detection scheme is presented in which continuous wave cavity ring down spectroscopy is used to record rovibrational spectra of molecular ions in direct absorption through supersonically expanding planar plasma. A cw optical parametric oscillator is used as a light source and

  19. Applied optics and optical engineering v.9

    CERN Document Server

    Shannon, Robert

    1983-01-01

    Applied Optics and Optical Engineering, Volume IX covers the theories and applications of optics and optical engineering. The book discusses the basic algorithms for optical engineering; diffraction gratings, ruled and holographic; and recording and reading of information on optical disks. The text also describes the perfect point spread function; the multiple aperture telescope diffraction images; and the displays and simulators. Ophthalmic optics, as well as the canonical and real-space coordinates used in the theory of image formation are also encompassed. Optical engineers and students tak

  20. Optical properties of lead–bismuth cuprous glasses

    Indian Academy of Sciences (India)

    P T Deshmukh; D K Burghate; V S Deogaonkar; S P Yawale; S V Pakade

    2003-10-01

    The optical transmission and absorption spectra in UV–VIS were recorded in the wavelength range 350–800 nm for different glass compositions in the system (CuO)(PbO)50–(Bi2O3)50 ( = 2.5, 5.0, 7.5, 10.0, 12.5, 15.0, 20.0). Absorption coefficient (), optical energy gap (opt), refractive index (D), optical dielectric constant ($\\varepsilon_{\\infty}^{′}$), measure of extent of band tailing ( ), constant () and ratio of carrier concentration to the effective mass (/*) have been reported. The effects of compositions of glasses on these parameters have been discussed. It has been indicated that a small compositional modification of the glasses lead to an important change in all the optical properties including non-linear behaviour. The optical parameters were found to be almost the same for different glasses in the same family.

  1. Catalogue of Radionuclide Low-Energy Electron Spectra (LEES)

    CERN Document Server

    Vylov, T D; Kovalik, A; Yakushev, E A; Mahmoud, M; Novgorodov, A F; Lebedev, N A; Filossofov, D V; Briançon, C; Walen, R J; Coursol, N F; Minkova, A; Petev, P; Dragoun, O; Brabec, V; Inoyatov, A

    2003-01-01

    More than 100 of apparatus low-energy electron spectra from radionuclides with Z=24-95 are collected in the presented LEES Catalogue. These spectra have been recorded in systematical investigations of Auger and internal conversion electrons with the ESA-50 electrostatic spectrometer during past 20 years.

  2. Vibrational spectra of the two hydrates of strontium oxalate.

    Science.gov (United States)

    D'Antonio, Maria C; Torres, María M; Palacios, Daniel; González-Baró, Ana C; Baran, Enrique J

    2015-02-25

    The infrared and Raman spectra of the two hydrates of strontium oxalate, SrC2O4⋅H2O and SrC2O4⋅2H2O, were recorded and discussed on the basis of their structural peculiarities and in comparison with the spectra of the related calcium oxalates and other previously investigated metallic oxalates.

  3. Anisotropy Spectra for Enantiomeric Differentiation of Biomolecular Building Blocks

    DEFF Research Database (Denmark)

    Evans, Amanda C.; Meinert, Cornelia; Bredehoft, Jan H.;

    2013-01-01

    light. This chapter will: (1) present the theory and configuration of anisotropy spectroscopy; (2) explain experimentally recorded anisotropy spectra of selected chiral biomolecules such as amino acids; and (3) discuss the relevance of these spectra for the investigation of the origin of the molecular...

  4. Synthetic spectra: a tool for correlation spectroscopy.

    Science.gov (United States)

    Sinclair, M B; Butler, M A; Ricco, A J; Senturia, S D

    1997-05-20

    We show that computer-generated diffractive optical elements can be used to synthesize the infrared spectra of important compounds, and we describe a modified phase-retrieval algorithm useful for the design of elements of this type. In particular, we present the results of calculations of diffractive elements that are capable of synthesizing portions of the infrared spectra of gaseous hydrogen fluoride (HF) and trichloroethylene (TCE). Further, we propose a new type of correlation spectrometer that uses these diffractive elements rather than reference cells for the production of reference spectra. Storage of a large number of diffractive elements, each producing a synthetic spectrum corresponding to a different target compound, in compact-disk-like format will allow a spectrometer of this type to rapidly determine the composition of unknown samples. Other advantages of the proposed correlation spectrometer are also discussed.

  5. Spectra and strains

    CERN Document Server

    Golyshev, V

    2008-01-01

    This is a blend of two informal reports on the activities of the seminar on Galois representations and mirror symmetry given at the Conference on classification problems and mirror duality at the Steklov Institute, in March 2006, and at the Seminar on Algebra, Geometry and Physics at MPI, in November 2007. We assess where we are on the issue of the spectra of Fano varieties, and state problems. We introduce higher dimensional irreducible analogues of dessins, the low ramified sheaves, and hypothesize that Fano spectra relate to their geometric conductors. We give a recipe to a physicist.

  6. Records Management

    Data.gov (United States)

    U.S. Environmental Protection Agency — All Federal Agencies are required to prescribe an appropriate records maintenance program so that complete records are filed or otherwise preserved, records can be...

  7. Room-Temperature Coherent Optical Phonon in 2D Electronic Spectra of CH3NH3PbI3 Perovskite as a Possible Cooling Bottleneck

    Energy Technology Data Exchange (ETDEWEB)

    Monahan, Daniele M. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States); Guo, Liang [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States); Lin, Jia [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States); Dou, Letian [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States); Yang, Peidong [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States); Fleming, Graham R. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Inst. at Berkeley, Berkeley, CA (United States)

    2017-06-29

    A hot phonon bottleneck may be responsible for slow hot carrier cooling in methylammonium lead iodide hybrid perovskite, creating the potential for more efficient hot carrier photovoltaics. In room-temperature 2D electronic spectra near the band edge, we observe in this paper amplitude oscillations due to a remarkably long lived 0.9 THz coherent phonon population at room temperature. This phonon (or set of phonons) is assigned to angular distortions of the Pb–I lattice, not coupled to cation rotations. The strong coupling between the electronic transition and the 0.9 THz mode(s), together with relative isolation from other phonon modes, makes it likely to cause a phonon bottleneck. Finally, the pump frequency resolution of the 2D spectra also enables independent observation of photoinduced absorptions and bleaches independently and confirms that features due to band gap renormalization are longer-lived than in transient absorption spectra.

  8. Atomic Spectra Database (ASD)

    Science.gov (United States)

    SRD 78 NIST Atomic Spectra Database (ASD) (Web, free access)   This database provides access and search capability for NIST critically evaluated data on atomic energy levels, wavelengths, and transition probabilities that are reasonably up-to-date. The NIST Atomic Spectroscopy Data Center has carried out these critical compilations.

  9. Relativistic Spectra of Hot Black-Hole Winds

    CERN Document Server

    Sumitomo, Naoko; Fukue, Jun; Watarai, Kenya

    2009-01-01

    We examine hybrid thermal-nonthermal synchrotron spectra from a spherically symmetric, optically-thin wind, taking into account the relativistic effect. In the relativistic flow from the central object, due to the relativistic beaming effect, the observed spectra often shift towards high frequency and high intensity directions. In the optically thin outflows, however, we find that the intensity of the observed spectra decreases compared with that of the emitted ones, although the peak frequency shifts towards the high frequency direction. This is because in the optically thin outflows we can see the far side flows that go away from the observer. We thus carefully consider optically thin relativistic flows around a black hole such as Sgr A$^*$.

  10. An analysis of ultraviolet spectra of Extreme Helium Stars and new clues to their origins

    CERN Document Server

    Pandey, G; Jeffery, C S; Rao, N K; Pandey, Gajendra; Lambert, David L.

    2006-01-01

    Abundances of about 18 elements including the heavy elements Y and Zr are determined from Hubble Space Telescope Space Telescope Imaging Spectrograph ultraviolet spectra of seven extreme helium stars (EHes): LSE 78, BD+10 2179, V1920 Cyg, HD 124448, PV Tel, LS IV -1 2, and FQ Aqr. New optical spectra of the three stars -- BD+10 2179, V1920 Cyg, and HD 124448 were analysed. The abundance analyses is done using LTE line formation and LTE model atmospheres especially constructed for these EHe stars. The stellar parameters derived from an EHe's UV spectrum are in satisfactory agreement with those derived from its optical spectrum. Adopted abundances for the seven EHes are from a combination of the UV and optical analyses. Published results for an additional ten EHes provide abundances obtained in a nearly uniform manner for a total of 17 EHes, the largest sample on record. The initial metallicity of an EHe is indicated by the abundance of elements from Al to Ni; Fe is adopted to be the representative of initial m...

  11. Synthetic infrared spectra.

    Science.gov (United States)

    Sinclair, M B; Butler, M A; Kravitz, S H; Zubrzycki, W J; Ricco, A J

    1997-07-01

    We have designed, microfabricated, and characterized a diffractive optical element that reproduces the infrared spectrum of HF from 3600 to 4300 cm(-1) . The reflection-mode diffractive optic consists of 4096 lines, each 4.5mum wide, at 16 discrete depths relative to the substrate from 0 to 1.2 mum and was fabricated upon a silicon wafer by anisotropic reactive ion-beam etching in a four-mask-level process. We envisage the use of diffractive optical elements of this type as the basis for a new class of miniaturized, remote chemical sensor systems based on correlation spectroscopy.

  12. Optical Coherence and Quantum Optics

    CERN Document Server

    Mandel, Leonard

    1995-01-01

    This book presents a systematic account of optical coherence theory within the framework of classical optics, as applied to such topics as radiation from sources of different states of coherence, foundations of radiometry, effects of source coherence on the spectra of radiated fields, coherence theory of laser modes, and scattering of partially coherent light by random media. The book starts with a full mathematical introduction to the subject area and each chapter concludes with a set of exercises. The authors are renowned scientists and have made substantial contributions to many of the topi

  13. Direct recovery of fluctuation spectra from tomographic shear spectra

    Science.gov (United States)

    Mezzetti, Marino; Bonometto, Silvio A.; Casarini, Luciano; Murante, Giuseppe

    2012-06-01

    Forthcoming experiments will enable us to determine high precision tomographic shear spectra. Matter density fluctuation spectra, at various z, should then be recovered from them, in order to constrain the model and determine the DE state equation. Available analytical expressions, however, do the opposite, enabling us to derive shear spectra from fluctuation spectra. Here we find the inverse expression, yielding density fluctuation spectra from observational tomographic shear spectra. The procedure involves SVD techniques for matrix inversion. We show in detail how the approach works and provide a few examples.

  14. Cross Ripples and Wave Directional Spectra

    Science.gov (United States)

    Cheel, R. A.; Hay, A. E.

    2006-12-01

    Cross ripples are a 3-dimensional bed state composed of two sets of ripples with different orientations: one set of smaller wavelength (4-10 cm) ripples residing within the troughs of a larger wavelength (30-50 cm) set. Cross ripples occur at intermediate wave energies. In contrast, at slightly higher energies the bed undergoes a transition to a highly 2-dimensional linear transition rippled state. In this study, the characteristics of the wave directional spectra during the occurrences of these 2- and 3-dimensional bed states are compared. The rotary fanbeam sonar record from SandyDuck97 shows that cross ripples and linear transition ripples occurred in approximately 11% and 42% of the sonar images respectively. Wave directional spectra are calculated with the Iterative Maximum Likelihood Method from collocated measurements of pressure and horizontal velocity. Using the sonar record and wave directional spectra the correlation between bimodal wave directional spectra and the occurrence of the two distinct ripple types is examined and compared. Since ripple crest alignment is typically orthogonal to the direction of wave propagation, one possible creation mechanism for cross ripples is a bidirectional wave field. We find that bimodality of the wave spectrum, neither in direction nor in frequency, is unique to the occurrence of cross ripples.

  15. Optical properties of 60B2O3–(40–)PbO–MCl2 and 50B2O3–(50–) PbO–MCl2 (M = Pb, Cd) glasses

    Indian Academy of Sciences (India)

    Shajo Sebastian; M Abdul Khadar

    2004-04-01

    Optical absorption and transmittance spectra of 60B2O3–(40–)PbO–MCl2 and 50B2O3–(50–) PbO–MCl2 (M = Pb, Cd) (10 ≤ ≤ 20) glasses of varying composition were recorded in the UV-visible region. Various optical parameters such as optical energy gap (opt), Urbach energy (e), refractive index (0), optical dielectric constant (∝), and ratio of carrier concentration to the effective mass (/*) were determined. The variation of optical energy gap with increase in the concentration of PbCl2 or CdCl2 is discussed.

  16. Rotational spectroscopy with an optical centrifuge

    CERN Document Server

    Korobenko, Aleksey; Hepburn, John W; Milner, Valery

    2013-01-01

    We demonstrate a new spectroscopic method for studying electronic transitions in molecules with extremely broad range of angular momentum. We employ an optical centrifuge to create narrow rotational wave packets in the ground electronic state of $^{16}$O$_2$. Using the technique of resonance-enhanced multi-photon ionization, we record the spectrum of multiple ro-vibrational transitions between $X^3\\Sigma_{g}^{-}$ and $C^3\\Pi_{g}$ electronic manifolds of oxygen. Direct control of rotational excitation, extending to rotational quantum numbers as high as $N\\gtrsim 120$, enables us to interpret the complex structure of rotational spectra of $C^3\\Pi_{g}$ beyond thermally accessible levels.

  17. Disk-averaged synthetic spectra of Mars

    Science.gov (United States)

    Tinetti, Giovanna; Meadows, Victoria S.; Crisp, David; Fong, William; Velusamy, Thangasamy; Snively, Heather

    2005-01-01

    The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

  18. Disk-averaged synthetic spectra of Mars

    Science.gov (United States)

    Tinetti, Giovanna; Meadows, Victoria S.; Crisp, David; Fong, William; Velusamy, Thangasamy; Snively, Heather

    2005-01-01

    The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

  19. Laser color recording unit

    Science.gov (United States)

    Jung, E.

    1984-05-01

    A color recording unit was designed for output and control of digitized picture data within computer controlled reproduction and picture processing systems. In order to get a color proof picture of high quality similar to a color print, together with reduced time and material consumption, a photographic color film material was exposed pixelwise by modulated laser beams of three wavelengths for red, green and blue light. Components of different manufacturers for lasers, acousto-optic modulators and polygon mirrors were tested, also different recording methods as (continuous tone mode or screened mode and with a drum or flatbed recording principle). Besides the application for the graphic arts - the proof recorder CPR 403 with continuous tone color recording with a drum scanner - such a color hardcopy peripheral unit with large picture formats and high resolution can be used in medicine, communication, and satellite picture processing.

  20. Crystal structure and optical spectra of LiLa{sub 9}(SiO{sub 4}){sub 6}O{sub 2} crystals activated with Er{sup 3+}

    Energy Technology Data Exchange (ETDEWEB)

    Bettinelli, Marco [Dipartimento Scientifico e Tecnologico, University of Verona and INSTM, UdR Verona, Ca Vignal, Strada Le Grazie 15, 37134 Verona (Italy)], E-mail: marco.bettinelli@univr.it; Speghini, Adolfo [Dipartimento di Scienze, Tecnologie e Mercati della Vite e de Vino, University of Verona and INSTM, Villa Lebrecht, San Floriano, 37029 Verona (Italy); Falcomer, Daniele [Dipartimento Scientifico e Tecnologico, University of Verona and INSTM, UdR Verona, Ca Vignal, Strada Le Grazie 15, 37134 Verona (Italy); Cavalli, Enrico; Calestani, Gianluca [Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Universita di Parma, Viale G. P. Usberti 17/a, 43100 Parma (Italy); Quintanilla, Marta; Cantelar, Eugenio; Cusso, Fernando [Departamento de Fisica de los Materiales, Facultad de Ciencias, Universidad Autonoma de Madrid, Madrid 28049 (Spain)

    2008-05-15

    LiLa{sub 9}(SiO{sub 4}){sub 6}O{sub 2} (LLS) crystals activated with Er{sup 3+} have been grown by the flux growth method. Their apatite structure has been characterized by single-crystal X-ray diffraction. The absorption and emission spectra have been measured in the visible and NIR regions. They are affected by a significant inhomogeneous broadening making these crystals interesting active media for tunable solid-state laser operation.