WorldWideScience

Sample records for one-dimensional material synthesis

  1. Geometric Shape Regulation and Noncovalent Synthesis of One-Dimensional Organic Luminescent Nano-/Micro-Materials.

    Science.gov (United States)

    Song, Xiaoxian; Zhang, Zuolun; Zhang, Shoufeng; Wei, Jinbei; Ye, Kaiqi; Liu, Yu; Marder, Todd B; Wang, Yue

    2017-08-03

    Noncovalent synthesis of one-dimensional (1D) organic nano-/micro-materials with controllable geometric shapes or morphologies and special luminescent and electronic properties is one of the greatest challenges in modern chemistry and material science. Control of noncovalent interactions is fundamental for realizing desired 1D structures and crucial for understanding the functions of these interactions. Here, a series of thiophene-fused phenazines composed of a halogen-substituted π-conjugated plate and a pair of flexible side chains is presented, which displays halogen-dependent 1D self-assemblies. Luminescent 1D twisted wires, straight rods, and zigzag wires, respectively, can be generated in sequence when the halogen atoms are varied from the lightest F to the heaviest I. It was demonstrated that halogen-dependent anisotropic noncovalent interactions and mirror-symmetrical crystallization dominated the 1D-assembly behaviors of this class of molecules. The methodology developed in this study provides a potential strategy for constructing 1D organic materials with unique optoelectronic functions.

  2. Synthesis of one-dimensional metal-containing insulated molecular wire with versatile properties directed toward molecular electronics materials.

    Science.gov (United States)

    Masai, Hiroshi; Terao, Jun; Seki, Shu; Nakashima, Shigeto; Kiguchi, Manabu; Okoshi, Kento; Fujihara, Tetsuaki; Tsuji, Yasushi

    2014-02-05

    We report, herein, the design, synthesis, and properties of new materials directed toward molecular electronics. A transition metal-containing insulated molecular wire was synthesized through the coordination polymerization of a Ru(II) porphyrin with an insulated bridging ligand of well-defined structure. The wire displayed not only high linearity and rigidity, but also high intramolecular charge mobility. Owing to the unique properties of the coordination bond, the interconversion between the monomer and polymer states was realized under a carbon monoxide atmosphere or UV irradiation. The results demonstrated a high potential of the metal-containing insulated molecular wire for applications in molecular electronics.

  3. On the anomalies in gold nanoparticles prepared by micelle nanolithography and their impact on one-dimensional material synthesis. Role of substrate, size effects and impurity

    Energy Technology Data Exchange (ETDEWEB)

    Mbenkum, B.N.

    2007-07-23

    The synthesis of one-dimensional (1-D) inorganic semiconductor materials such as nanotubes and silicon (Si) nanowires is usually achieved by catalyst nanoparticlemediated synthetic routes. Despite the well-established nature of this technique, problems such as low temperature synthesis and adequate control of catalyst nanoparticle diameter in order to control 1-D material diameter still prevail. Additionally, the expansion of this technology from crystalline to cheaper substrates such as glass remains demanding. This work employs a previously established selfassembly route to produce controlled spatial distribution of substrate anchored small diameter gold nanoparticles with controlled size. This enabled successful synthesis of Si 1-D structures with controlled diameters less than 20 nm. Low temperature synthesis due to enhanced catalytic activity was achieved via introduction of impurity by treatment of gold nanoparticles in different plasma environments. This enabled Si 1-D structure growth on Si, SiO{sub x}/Si and borosilicate glass substrates at 320 C. Substrate-induced stress affected Si diffusion at the gold nanoparticle determining whether Si nanowires or nanotubes were grown. These results are of technological relevance because low temperature synthesis provides an economical approach and controlled diameter enhances material functionality. Additionally, exploiting substrate-induced stress to influence Si diffusion in nanoparticles provides an alternate route to tuning Si 1-D structure. (orig.)

  4. Synthesis of One Dimensional Li2MoO4 Nanostructures and Their Electrochemical Performance as Anode Materials for Lithium-ion Batteries

    International Nuclear Information System (INIS)

    Liu, Xudong; Zhao, Yanming; Dong, Youzhong; Fan, Qinghua; Kuang, Quan; Liang, Zhiyong; Lin, Xinghao; Han, Wei; Li, Qidong; Wen, Mingming

    2015-01-01

    Highlights: • One dimensional Li 2 MoO 4 nanostructures including nanorods and nanotubes have been successfully fabricated via a simple sol-gel method firstly. • Possible crystal formation mechanisms are proposed for these one dimensional Li 2 MoO 4 nanostructures. • These one dimensional Li 2 MoO 4 nanostructure electrode materials present outstanding rate abilities and cycle capabilities in electrochemical performance compared to the carbon-free powder sample when evaluated as anode materials for Lithium-ion batteries. • The carbon-coated Li 2 MoO 4 nanotube electrode improves the charging/discharging capacities of graphite even after applying 60 cycles at very high current density. - Abstract: One dimensional Li 2 MoO 4 nanostructures including nanorods and nanotubes have been successfully fabricated via a simple sol-gel method adding Li 2 CO 3 and MoO 3 powders into distilled water with citric acid as an assistant agent and carbon source. Our experimental results show that the formation of the one dimensional nanostructure morphology is evaporation and crystallization process with self-adjusting into a rod-like hexagonal cross-section structure, while the citric acid played an important role during the formation of Li 2 MoO 4 nanotubes under the acidic environment by capping, stabilizing the {1010} facet of Li 2 MoO 4 structure and controlling the concentration of H + (pH value) of the aqueous solution. Finally, basic electrochemical performance of these one dimensional Li 2 MoO 4 nanostructures including nanorods and nanotubes evaluated as anode materials for lithium-ion batteries (LIBs) are discussed, for comparison, the properties of carbon-free powder sample synthesized by solid-state reaction are also displayed. Experimental results show that different morphology and carbon-coating on the surface have an important influence on electrochemical performance

  5. Versatile hydrothermal synthesis of one-dimensional composite structures

    Science.gov (United States)

    Luo, Yonglan

    2008-12-01

    In this paper we report on a versatile hydrothermal approach developed to fabricate one-dimensional (1D) composite structures. Sulfur and selenium formed liquid and adsorbed onto microrods as droplets and subsequently reacted with metallic ion in solution to produce nanoparticles-decorated composite microrods. 1D composites including ZnO/CdS, ZnO/MnS, ZnO/CuS, ZnO/CdSe, and FeOOH/CdS were successfully made using this hydrothermal strategy and the growth mechanism was also discussed. This hydrothermal strategy is simple and green, and can be extended to the synthesis of various 1D composite structures. Moreover, the interaction between the shell nanoparticles and the one-dimensional nanomaterials were confirmed by photoluminescence investigation of ZnO/CdS.

  6. Resonance Raman spectroscopy in one-dimensional carbon materials

    Directory of Open Access Journals (Sweden)

    Dresselhaus Mildred S.

    2006-01-01

    Full Text Available Brazil has played an important role in the development and use of resonance Raman spectroscopy as a powerful characterization tool for materials science. Here we present a short history of Raman scattering research in Brazil, highlighting the important contributions to the field coming from Brazilian researchers in the past. Next we discuss recent and important contributions where Brazil has become a worldwide leader, that is on the physics of quasi-one dimensional carbon nanotubes. We conclude this article by presenting results from a very recent resonance Raman study of exciting new materials, that are strictly one-dimensional carbon chains formed by the heat treatment of very pure double-wall carbon nanotube samples.

  7. Facile synthesis of one-dimensional hollow Sb2O3@TiO2 composites as anode materials for lithium ion batteries

    Science.gov (United States)

    Wang, Zhaomin; Cheng, Yong; Li, Qian; Chang, Limin; Wang, Limin

    2018-06-01

    Metallic Sb is deemed as a promising anode material for lithium ion batteries (LIBs) due to its flat voltage platform and high security. Nevertheless, the limited capacity restricts its large-scale application. Therefore, a simple and effective method to explore novel antimony trioxide with high capacity used as anode material for LIBs is imperative. In this work, we report a facile and efficient strategy to fabricate 1D hollow Sb2O3@TiO2 composites by using the Kirkendall effect. When used as an anode material for LIBs, the optimal Sb2O3@TiO2 composite displays a high reversible discharge capacity of 593 mAh g-1 at a current density of 100 mA g-1 after 100 cycles and a relatively superior discharge capacity of 439 mAh g-1 at a current density of 500 mA g-1 even after 600 cycles. In addition, a reversible discharge capacity of 334 mAh g-1 can also be obtained even at a current density of 2000 mA g-1. The excellent cycling stability and rate performance of the Sb2O3@TiO2 composite can be attributed to the synergistic effect of TiO2 shell and hollow structure of Sb2O3, both of which can effectively buffer the volume expansion and maintain the integrity of the electrode during the repeated charge-discharge cycles.

  8. Bioinspired one-dimensional materials for directional liquid transport.

    Science.gov (United States)

    Ju, Jie; Zheng, Yongmei; Jiang, Lei

    2014-08-19

    One-dimensional materials (1D) capable of transporting liquid droplets directionally, such as spider silks and cactus spines, have recently been gathering scientists' attention due to their potential applications in microfluidics, textile dyeing, filtration, and smog removal. This remarkable property comes from the arrangement of the micro- and nanostructures on these organisms' surfaces, which have inspired chemists to develop methods to prepare surfaces with similar directional liquid transport ability. In this Account, we report our recent progress in understanding how this directional transport works, as well our advances in the design and fabrication of bioinspired 1D materials capable of transporting liquid droplets directionally. To begin, we first discuss some basic theories on droplet directional movement. Then, we discuss the mechanism of directional transport of water droplets on natural spider silks. Upon contact with water droplets, the spider silk undergoes what is known as a wet-rebuilt, which forms periodic spindle-knots and joints. We found that the resulting gradient of Laplace pressure and surface free energy between the spindle-knots and joints account for the cooperative driving forces to transport water droplets directionally. Next, we discuss the directional transport of water droplets on desert cactus. The integration of multilevel structures of the cactus and the resulting integration of multiple functions together allow the cactus spine to transport water droplets continuously from tip to base. Based on our studies of natural spider silks and cactus spines, we have prepared a series of artificial spider silks (A-SSs) and artificial cactus spines (A-CSs) with various methods. By changing the surface roughness and chemical compositions of the artificial spider silks' spindle-knots, or by introducing stimulus-responsive molecules, such as thermal-responsive and photoresponsive molecules, onto the spindle-knots, we can reversibly manipulate

  9. One dimensional coordination polymers: Synthesis, crystal structures and spectroscopic properties

    Science.gov (United States)

    Karaağaç, Dursun; Kürkçüoğlu, Güneş Süheyla; Şenyel, Mustafa; Şahin, Onur

    2016-11-01

    Two new one dimensional (1D) cyanide complexes, namely [M(4-aepy)2(H2O)2][Pt(CN)4], (4-aepy = 4-(2-aminoethyl)pyridine M = Cu(II) (1) or Zn(II) (2)), have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The crystallographic analyses reveal that 1 and 2 are isomorphous and isostructural, and crystallize in the monoclinic system and C2 space group. The Pt(II) ions are coordinated by four cyanide-carbon atoms in the square-planar geometry and the [Pt(CN)4]2- ions act as a counter ion. The M(II) ions display an N4O2 coordination sphere with a distorted octahedral geometry, the nitrogen donors belonging to four molecules of the organic 4-aepy that act as unidentate ligands and two oxygen atoms from aqua ligands. The crystal structures of 1 and 2 are similar each other and linked via intermolecular hydrogen bonding, Pt⋯π interactions to form 3D supramolecular network. Vibration assignments of all the observed bands are given and the spectral features also supported to the crystal structures of the complexes.

  10. One-dimensional energy flow model for poroelastic material

    International Nuclear Information System (INIS)

    Kim, Jung Soo; Kang, Yeon June

    2009-01-01

    This paper presents a one-dimensional energy flow model to investigate the energy behavior for poroelastic media coupled with acoustical media. The proposed energy flow model is expressed by an independent energy governing equation that is classified into each wave component propagating in poroelastic media. The energy governing equation is derived using the General Energetic Method (GEM). To facilitate a comparison with the classical solution based on the conventional displacement-base formulation, approximate solutions of energy density and intensity are obtained. Furthermore, the limitations and usability of the proposed energy flow model for poroelastic media are described.

  11. Synthesis and integration of one-dimensional nanostructures for chemical gas sensing applications

    Science.gov (United States)

    Parthangal, Prahalad Madhavan

    The need for improved measurement technology for the detection and monitoring of gases has increased tremendously for maintenance of domestic and industrial health and safety, environmental surveys, national security, food-processing, medical diagnostics and various other industrial applications. Among the several varieties of gas sensors available in the market, solid-state sensors are the most popular owing to their excellent sensitivity, ruggedness, versatility and low cost. Semiconducting metal oxides such as tin oxide (SnO2), zinc oxide (ZnO), and tungsten oxide (WO3) are routinely employed as active materials in these sensors. Since their performance is directly linked to the exposed surface area of the sensing material, one-dimensional nanostructures possessing very high surface to volume ratios are attractive candidates for designing the next generation of sensors. Such nano-sensors also enable miniaturization thereby reducing power consumption. The key to achieve success in one-dimensional nanotechnologies lies in assembly. While synthesis techniques and capabilities continue to expand rapidly, progress in controlled assembly has been sluggish due to numerous technical challenges. In this doctoral thesis work, synthesis and characterization of various one-dimensional nanostructures including nanotubes of SnO2, and nanowires of WO3 and ZnO, as well as their direct integration into miniature sensor platforms called microhotplates have been demonstrated. The key highlights of this research include devising elegant strategies for growing metal oxide nanotubes using carbon nanotubes as templates, substantially reducing process temperatures to enable growth of WO3 nanowires on microhotplates, and successfully fabricating a ZnO nanowire array based sensor using a hybrid nanowire-nanoparticle assembly approach. In every process, the gas-sensing properties of one-dimensional nanostructures were observed to be far superior in comparison with thin films of the same

  12. Phononic crystals with one-dimensional defect as sensor materials

    Science.gov (United States)

    Aly, Arafa H.; Mehaney, Ahmed

    2017-09-01

    Recently, sensor technology has attracted great attention in many fields due to its importance in many engineering applications. In the present work, we introduce a study using the innovative properties of phononic crystals in enhancing a new type of sensors based on the intensity of transmitted frequencies inside the phononic band gaps. Based on the transfer matrix method and Bloch theory, the expressions of the reflection coefficient and dispersion relation are presented. Firstly, the influences of filling fraction ratio and the angle of incidence on the band gap width are discussed. Secondly, the localization of waves inside band gaps is discussed by enhancing the properties of the defected phononic crystal. Compared to the periodic structure, localization modes involved within the band structure of phononic crystals with one and two defect layers are presented and compared. Trapped localized modes can be detected easily and provide more information about defected structures. Such method could increase the knowledge of manufacturing defects by measuring the intensity of propagated waves in the resonant cavities and waveguides. Moreover, several factors enhance the role of the defect layer on the transmission properties of defected phononic crystals are presented. The acoustic band gap can be used to detect or sense the type of liquids filling the defect layer. The liquids make specific resonant modes through the phononic band gaps that related to the properties of each liquid. The frequency where the maximum resonant modes occur is correlated to material properties and allows to determine several parameters such as the type of an unknown material.

  13. Facile Synthesis and Tensile Behavior of TiO2 One-Dimensional Nanostructures

    Directory of Open Access Journals (Sweden)

    Li Shu-you

    2009-01-01

    Full Text Available Abstract High-yield synthesis of TiO2 one-dimensional (1D nanostructures was realized by a simple annealing of Ni-coated Ti grids in an argon atmosphere at 950 °C and 760 torr. The as-synthesized 1D nanostructures were single crystalline rutile TiO2 with the preferred growth direction close to [210]. The growth of these nanostructures was enhanced by using catalytic materials, higher reaction temperature, and longer reaction time. Nanoscale tensile testing performed on individual 1D nanostructures showed that the nanostructures appeared to fracture in a brittle manner. The measured Young’s modulus and fracture strength are ~56.3 and 1.4 GPa, respectively.

  14. Synthesis and applications of one-dimensional nano-structured polyaniline: An overview

    International Nuclear Information System (INIS)

    Zhang Donghua; Wang Yangyong

    2006-01-01

    This paper summarizes and reviews the various synthesizing approaches of one-dimensional nano-structured polyaniline (PANI) and several potential applications of the nanomaterial. The synthesizing approaches can be generally categorized into template synthesis and non-template synthesis according to whether template(s), hard (physical template) or soft (chemical template), is (are) used or not. However, though the various approaches established, preparation of one-dimensional nano-structured PANI with controllable morphologies and sizes, especially well oriented arrays on a large scale is still a major challenge. Furthermore, the formation mechanisms of the nanostructures are still unclear. On the other hand, one-dimensional nano-structured PANI exhibits high surface area, high conductivity, as well as controllable chemical/physical properties and good environmental stability, rendering the nanomaterial promising candidate for application ranging from sensors, energy storage and flash welding to digital nonvolatile memory

  15. Synthesis, Characterization and Applications of One-Dimensional Metal Oxide Nanostructures

    Science.gov (United States)

    Santulli, Alexander

    Nanomaterials have been of keen research interest, owing to their exciting and unique properties (e.g. optical, magnetic, electronic, and mechanical). These properties allow nanomaterials to have many applications in areas of medicine, alternative energy, catalysis, and information storage. In particular, one-dimensional (1D) nanomaterials are highly advantageous, owing to the inherent anisotropic nature, which allows for effective transport and study of properties on the nanoscale. More specifically, 1D metal oxide nanomaterials are of particular interest, owing to their high thermal and chemical stability, as well as their intriguing optical, electronic, and magnetic properties. Herein, we will investigate the synthesis and characterization of vanadium oxide, lithium niobate and chromium oxide. We will explore the methodologies utilized for the synthesis of these materials, as well as the overall properties of these unique nanomaterials. Furthermore, we will explore the application of titanium dioxide nanomaterials as the electron transport layer in dye sensitized solar cells (DSSCs), with an emphasis on the effect of the nanoscale morphology on the overall device efficiency.

  16. One-Dimensional SnO2 Nano structures: Synthesis and Applications

    International Nuclear Information System (INIS)

    Pan, J.; Shen, H.; Mathur, S.; Pan, J.

    2012-01-01

    Nano scale semiconducting materials such as quantum dots (0-dimensional) and one-dimensional (1D) structures, like nano wires, nano belts, and nano tubes, have gained tremendous attention within the past decade. Among the variety of 1D nano structures, tin oxide (SnO 2 ) semiconducting nano structures are particularly interesting because of their promising applications in optoelectronic and electronic devices due to both good conductivity and transparence in the visible region. This article provides a comprehensive review of the recent research activities that focus on the rational synthesis and unique applications of 1D SnO 2 nano structures and their optical and electrical properties. We begin with the rational design and synthesis of 1D SnO 2 nano structures, such as nano tubes, nano wires, nano belts, and some heterogeneous nano structures, and then highlight a range of applications (e.g., gas sensor, lithium-ion batteries, and nano photonics) associated with them. Finally, the review is concluded with some perspectives with respect to future research on 1D SnO 2 nano structures

  17. One dimensional Si/Sn - based nanowires and nanotubes for lithium-ion energy storage materials

    KAUST Repository

    Choi, Nam-Soon; Yao, Yan; Cui, Yi; Cho, Jaephil

    2011-01-01

    There has been tremendous interest in using nanomaterials for advanced Li-ion battery electrodes, particularly to increase the energy density by using high specific capacity materials. Recently, it was demonstrated that one dimensional (1D) Si

  18. One dimensional Si/Sn - based nanowires and nanotubes for lithium-ion energy storage materials

    KAUST Repository

    Choi, Nam-Soon

    2011-01-01

    There has been tremendous interest in using nanomaterials for advanced Li-ion battery electrodes, particularly to increase the energy density by using high specific capacity materials. Recently, it was demonstrated that one dimensional (1D) Si/Sn nanowires (NWs) and nanotubes (NTs) have great potential to achieve high energy density as well as long cycle life for the next generation of advanced energy storage applications. In this feature article, we review recent progress on Si-based NWs and NTs as high capacity anode materials. Fundamental understanding and future challenges on one dimensional nanostructured anode are also discussed. © 2010 The Royal Society of Chemistry.

  19. One-dimensional CuO nanowire: synthesis, electrical, and optoelectronic devices application

    Science.gov (United States)

    Luo, Lin-Bao; Wang, Xian-He; Xie, Chao; Li, Zhong-Jun; Lu, Rui; Yang, Xiao-Bao; Lu, Jian

    2014-11-01

    In this work, we presented a surface mechanical attrition treatment (SMAT)-assisted approach to the synthesis of one-dimensional copper oxide nanowires (CuO NWs) for nanodevices applications. The as-prepared CuO NWs have diameter and the length of 50 ~ 200 nm and 5 ~ 20 μm, respectively, with a preferential growth orientation along [1 [InlineEquation not available: see fulltext.] 0] direction. Interestingly, nanofield-effect transistor (nanoFET) based on individual CuO NW exhibited typical p-type electrical conduction, with a hole mobility of 0.129 cm2V-1 s-1 and hole concentration of 1.34 × 1018 cm-3, respectively. According to first-principle calculations, such a p-type electrical conduction behavior was related to the oxygen vacancies in CuO NWs. What is more, the CuO NW device was sensitive to visible light illumination with peak sensitivity at 600 nm. The responsitivity, conductive gain, and detectivity are estimated to be 2.0 × 102 A W-1, 3.95 × 102 and 6.38 × 1011 cm Hz1/2 W-1, respectively, which are better than the devices composed of other materials. Further study showed that nanophotodetectors assembled on flexible polyethylene terephthalate (PET) substrate can work under different bending conditions with good reproducibility. The totality of the above results suggests that the present CuO NWs are potential building blocks for assembling high-performance optoelectronic devices.

  20. Chiral-nematic liquid crystals as one dimensional photonic materials in optical sensors

    NARCIS (Netherlands)

    Mulder, D.J.; Schenning, A.P.H.J.; Bastiaansen, C.W.M.

    2014-01-01

    Current developments in the field of thermotropic chiral-nematic liquid crystals as sensors are discussed. These one dimensional photonic materials are based on low molecular weight liquid crystals and chiral-nematic polymeric networks. For both low molecular weight LCs and polymer networks,

  1. Study on the Reflection Spectra of One Dimensional Plasma Photonic Crystals Having Exponentially Graded Materials

    International Nuclear Information System (INIS)

    Prasad, S.; Singh, Vivek; Singh, A. K.

    2013-01-01

    The transfer matrix method is used to study the effect of the permittivity profile on the reflectivity of a one dimensional plasma photonic crystal having exponentially graded material. The analysis shows that the proposed structure works as a perfect mirror within a certain frequency range. These frequency ranges can be completely controlled by the permittivity profile of a graded dielectric layer. As expected we observed that these frequency ranges are also controlled by plasma parameters. (plasma technology)

  2. Analysis and synthesis of one-dimensional magneto-photonic crystals using coupled mode theory

    Energy Technology Data Exchange (ETDEWEB)

    Saghirzadeh Darki, Behnam, E-mail: b.saghirzadeh@ec.iut.ac.ir; Nezhad, Abolghasem Zeidaabadi; Firouzeh, Zaker Hossein

    2017-03-15

    We utilize our previously developed temporal coupled mode approach to investigate the performance of one-dimensional magneto-photonic crystals (MPCs). We analytically demonstrate that a double-defect MPC provides adequate degrees of freedom to design a structure for arbitrary transmittance and Faraday rotation. By using our developed analytic approach along with the numerical transfer matrix method, we present a procedure for the synthesis of an MPC to generate any desired transmittance and Faraday rotation in possible ranges. However it is seen that only discrete values of transmittance and Faraday rotation are practically obtainable. To remedy this problem along with having short structures, we introduce a class of MPC heterostructures which are combinations of stacks with high and low optical contrast ratios.

  3. Wave propagation inside one-dimensional photonic crystals with single-negative materials

    International Nuclear Information System (INIS)

    Wang Ligang; Chen Hong; Zhu Shiyao

    2006-01-01

    The propagation of light waves in one-dimensional photonic crystals (1DPCs) composed of alternating layers of two kinds of single-negative materials is investigated theoretically. The phase velocity is negative when the frequency of the light wave is smaller than the certain critical frequency ω cr , while the Poynting vector is always positive. At normal incidence, such 1DPCs may act as equivalent left-handed materials. At the inclined incidence, the effective wave vectors inside such 1DPCs do refract negatively, while the effective energy flows do not refract negatively. Therefore, at the inclined incidence, the 1DPCs are not equivalent to the left-handed materials

  4. Green's functions of one-dimensional quasicrystal bi-material with piezoelectric effect

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Liangliang [College of Engineering, China Agricultural University, Beijing 100083 (China); Sinomatech Wind Power Blade Co., Ltd, Beijing 100092 (China); Wu, Di [College of Engineering, China Agricultural University, Beijing 100083 (China); Xu, Wenshuai [College of Science, China Agricultural University, Beijing 100083 (China); Yang, Lianzhi [Civil and Environmental Engineering School, University of Science and Technology Beijing, Beijing 100083 (China); Ricoeur, Andreas; Wang, Zhibin [Institute of Mechanics, University of Kassel, 34125 Kassel (Germany); Gao, Yang, E-mail: gaoyangg@gmail.com [College of Science, China Agricultural University, Beijing 100083 (China)

    2016-09-16

    Based on the Stroh formalism of one-dimensional quasicrystals with piezoelectric effect, the problems of an infinite plane composed of two different quasicrystal half-planes are taken into account. The solutions of the internal and interfacial Green's functions of quasicrystal bi-material are obtained. Moreover, numerical examples are analyzed for a quasicrystal bi-material subjected to line forces or line dislocations, showing the contour maps of the coupled fields. The impacts of changing material constants on the coupled field components are investigated. - Highlights: • Green's functions of 1D piezoelectric quasicrystal bi-material are studied. • The coupled fields subjected to line forces or line dislocations are obtained. • Mechanical behavior under the effect of different material constants is researched.

  5. One-dimensional nanostructured materials for lithium-ion battery and supercapacitor electrodes

    Science.gov (United States)

    Chan, Candace Kay

    The need for improved electrochemical storage devices has necessitated research on new and advanced electrode materials. One-dimensional nanomaterials such as nanowires, nanotubes, and nanoribbons, can provide a unique opportunity to engineer electrochemical devices to have improved electronic and ionic conductivity as well as electrochemical and structural transformations. Silicon and germanium nanowires (NWs) were studied as negative electrode materials for lithiumion batteries because of their ability to alloy with large amounts of lithium, leading to 4-10 times higher specific capacities than the graphite standard. These nanowires could be grown vertically off of metallic current collector substrates using the gold-catalyzed vapor-liquid-solid synthesis. Electrochemical measurements of the SiNWs showed that capacities greater than 3,500 mAh/g could be obtained for tens of cycles, while hundreds of cycles could be obtained at lower capacities. As opposed to bulk Si, the SiNWs were observed to maintain their morphology during cycling and did not pulverize due to the large volume changes. Detailed TEM and XRD characterization showed that the SiNWs became amorphous during the first lithiation (charge) and formed a two-phase region between crystalline Si and amorphous Li xSi. Afterwards, the SiNWs remained amorphous and subsequent reaction was through a single-phase cycling of amorphous Si. The good cycling behavior compared to bulk and micron-sized Si particles was attributed to the nanowire morphology and electrode design. The surface chemistry and solid-electrolyte interphase (SEI) were studied using XPS as a function of charge and discharge potential. The common reduction productions expected in the electrolyte (1 M LiPF6 in 1:1 EC/DEC) were observed, with the main component being Li2CO3. The morphology of the SEI was found to change at different potentials, indicating a dynamic process involving deposition, dissolution, and re-deposition on the SiNWs. Longterm

  6. Photonic band structures in one-dimensional photonic crystals containing Dirac materials

    International Nuclear Information System (INIS)

    Wang, Lin; Wang, Li-Gang

    2015-01-01

    We have investigated the band structures of one-dimensional photonic crystals (1DPCs) composed of Dirac materials and ordinary dielectric media. It is found that there exist an omnidirectional passing band and a kind of special band, which result from the interaction of the evanescent and propagating waves. Due to the interface effect and strong dispersion, the electromagnetic fields inside the special bands are strongly enhanced. It is also shown that the properties of these bands are invariant upon the lattice constant but sensitive to the resonant conditions

  7. Synthesis, structure and magnetic properties of the one-dimensional bimetallic oxide [Cu(terpy)Mo2O7

    International Nuclear Information System (INIS)

    Burkholder, Eric; Gabriel Armatas, N.; Golub, Vladimir; O'Connor, Charles J.; Zubieta, Jon

    2005-01-01

    The hydrothermal reaction of Cu(CH 3 CO 2 ) 2 .H 2 O, Na 2 MoO 4 and terpyridine at 140 deg. C for 48 h yields [Cu(terpy)Mo 2 O 7 ] (1), a bimetallic one-dimensional oxide. The structure consists of ruffled chains of edge- and corner-sharing {MoO 5 } square pyramids, decorated with {CuN 3 O 2 } '4+1' axially distorted square pyramids. The Cu(II) polyhedra are disposed so as to produce an alternating pattern of Cu-Cu distances across the {Mo 2 O 2 } rhombi of the chain of 6.25 and 6.82 A. This structural feature is reflected in the magnetic properties which are characteristic of a dimer rather than a linear chain, consistent with an alternating antiferromagnetic Heisenberg chain. -- Graphical abstract: Hydrothermal synthesis provided the one-dimensional bimetallic oxide [Cu(terpy)Mo 2 O 7 ], a material consisting of a zig-zag {Mo 2 O 7 } n 2 n - chain, decorated with {Cu(terpy)} 2+ groups exhibiting alternating short-long Cu-Cu distances between copper sites

  8. Solitons and polarons in quasi-one dimensional conducting polymers and related materials

    International Nuclear Information System (INIS)

    Campbell, D.K.

    1983-01-01

    In recent years it has become increasingly appreciated that fundamentally nonlinear excitations - solitons - play an essential role in an incredible variety of natural systems. These solitons, which frequently exhibit remarkable stability under interactions and perturbations, often dominate the transport, response, or structural properties of the systems in which they occur. In this article, we present an introduction to the solitons that occur in quasi-one-dimensional conducting polymers (synmetals) and related systems. The relevance of this subject to molecular electronic devices is twofold. First, many of these materials have molecular structures similar to possible prototype molecular switches. Second, to understand in detail how a molecular electronic device could work, it is essential to have a broad perspective on the nature of possible excitations in a variety of natural and synthetic molecular materials. 51 references

  9. Controlled synthesis and photocatalytic investigation of different-shaped one-dimensional titanic acid nanomaterials

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qiuye [State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); The Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 10080 (China); Key Laboratory of Special Functional Materials, Henan University, KaiFeng 475001 (China); Lu, Gongxuan [State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2008-10-15

    Different-shaped one-dimensional (1D) titanic acid nanomaterials (TANs) were prepared by hydrothermal synthesis. By changing the reaction temperature (120, 170 and 200 C), three kinds of 1D TAN, short-nanotubes (SNT), long-nanotubes (LNT), and nanorods (NR), were obtained. The obtained TANs were characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), and solid-stated diffuse reflectance UV-vis spectra (UV-vis DRS) techniques. Based on these 1D TAN, Eosin Y-sensitized Pt-loaded TAN were prepared by the in situ impregnation and photo-reduction method. Their photocatalytic activity for hydrogen generation was evaluated in triethanolamine (TEOA) aqueous solution under visible light irradiation ({lambda} {>=} 420 nm). The results indicated that the morphology difference led to a significant variation of photocatalytic performance for hydrogen generation, with the activity order as follows: Eosin Y-sensitized Pt-loaded LNT > Eosin Y-sensitized Pt-loaded NR > Eosin Y-sensitized Pt-loaded SNT. The experimental conditions for photocatalytic hydrogen generation such as Pt loading content, the mass ratio of Eosin Y to TAN, and so on, were optimized. As a result, the highest apparent quantum yields of hydrogen generation for Eosin Y-sensitized Pt-loaded SNT, LNT, and NR were 6.65, 17.36, and 15.04%, respectively. The stability of these photocatalysts and the reaction mechanism of the photocatalytic hydrogen generation are also discussed in detail. (author)

  10. Controlled synthesis and photocatalytic investigation of different-shaped one-dimensional titanic acid nanomaterials

    Science.gov (United States)

    Li, Qiuye; Lu, Gongxuan

    Different-shaped one-dimensional (1D) titanic acid nanomaterials (TANs) were prepared by hydrothermal synthesis. By changing the reaction temperature (120, 170 and 200 °C), three kinds of 1D TAN, short-nanotubes (SNT), long-nanotubes (LNT), and nanorods (NR), were obtained. The obtained TANs were characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), and solid-stated diffuse reflectance UV-vis spectra (UV-vis DRS) techniques. Based on these 1D TAN, Eosin Y-sensitized Pt-loaded TAN were prepared by the in situ impregnation and photo-reduction method. Their photocatalytic activity for hydrogen generation was evaluated in triethanolamine (TEOA) aqueous solution under visible light irradiation (λ ≥ 420 nm). The results indicated that the morphology difference led to a significant variation of photocatalytic performance for hydrogen generation, with the activity order as follows: Eosin Y-sensitized Pt-loaded LNT > Eosin Y-sensitized Pt-loaded NR > Eosin Y-sensitized Pt-loaded SNT. The experimental conditions for photocatalytic hydrogen generation such as Pt loading content, the mass ratio of Eosin Y to TAN, and so on, were optimized. As a result, the highest apparent quantum yields of hydrogen generation for Eosin Y-sensitized Pt-loaded SNT, LNT, and NR were 6.65, 17.36, and 15.04%, respectively. The stability of these photocatalysts and the reaction mechanism of the photocatalytic hydrogen generation are also discussed in detail.

  11. One-dimensional motion of a material with a strain theshold

    Directory of Open Access Journals (Sweden)

    A. Farina

    2007-12-01

    Full Text Available We consider the one-dimensional shearing motion of a material exhibiting elastic behaviour when the stress is below some threshold. The threshold represents a limit to the deformability, i.e. no further deformation can occur on increasing the stress. The mathematical formulation leads to a free boundary problem for the wave equation, whose structure depends on whether the stress (and the velocity are continuous across the propagating interface for the strain threshold .Local existence and uniqueness are proved for the continuous case (in which the interface propagation is subsonic. Some explicit solutions are calculated for another case (with a supersonic interface. It is shown that the model with strain threshold is never the limit of hyperelastic systems.

  12. Broadband one-dimensional photonic crystal wave plate containing single-negative materials.

    Science.gov (United States)

    Chen, Yihang

    2010-09-13

    The properties of the phase shift of wave reflected from one-dimensional photonic crystals consisting of periodic layers of single-negative (permittivity- or permeability-negative) materials are demonstrated. As the incident angle increases, the reflection phase shift of TE wave decreases, while that of TM wave increases. The phase shifts of both polarized waves vary smoothly as the frequency changes across the photonic crystal stop band. Consequently, the difference between the phase shift of TE and that of TM wave could remain constant in a rather wide frequency range inside the stop band. These properties are useful to design wave plate or retarder which can be used in wide spectral band. In addition, a broadband photonic crystal quarter-wave plate is proposed.

  13. Assessing one-dimensional diffusion in nanoporous materials from transient concentration profiles

    International Nuclear Information System (INIS)

    Heinke, Lars; Kaerger, Joerg

    2008-01-01

    The use of interference microscopy has enabled the direct observation of transient concentration profiles generated by intracrystalline transport diffusion in nanoporous materials. The thus accessible intracrystalline concentration profiles contain a wealth of information which cannot be deduced by any macroscopic method. In this paper, we illustrate five different ways for determining the concentration-dependent diffusivity in one-dimensional systems and two for the surface permeability. These methods are discussed by application to concentration profiles evolving during the uptake of methanol by the zeolite ferrierite and of methanol by the metal organic framework (MOF) manganese(II) formate. We show that the diffusivity can be calculated most precisely by means of Fick's 1st law. As the circumstances permit, Boltzmann's integration method also yields very precise results. Furthermore, we present a simple procedure that enables the estimation of the influence of the surface barrier on the overall uptake process by plotting the boundary concentration versus the overall uptake

  14. Propagation of acoustic waves in a one-dimensional macroscopically inhomogeneous poroelastic material.

    Science.gov (United States)

    Gautier, G; Kelders, L; Groby, J P; Dazel, O; De Ryck, L; Leclaire, P

    2011-09-01

    Wave propagation in macroscopically inhomogeneous porous materials has received much attention in recent years. The wave equation, derived from the alternative formulation of Biot's theory of 1962, was reduced and solved recently in the case of rigid frame inhomogeneous porous materials. This paper focuses on the solution of the full wave equation in which the acoustic and the elastic properties of the poroelastic material vary in one-dimension. The reflection coefficient of a one-dimensional macroscopically inhomogeneous porous material on a rigid backing is obtained numerically using the state vector (or the so-called Stroh) formalism and Peano series. This coefficient can then be used to straightforwardly calculate the scattered field. To validate the method of resolution, results obtained by the present method are compared to those calculated by the classical transfer matrix method at both normal and oblique incidence and to experimental measurements at normal incidence for a known two-layers porous material, considered as a single inhomogeneous layer. Finally, discussion about the absorption coefficient for various inhomogeneity profiles gives further perspectives. © 2011 Acoustical Society of America

  15. Asymmetric noncovalent synthesis of self-assembled one-dimensional stacks by a chiral supramolecular auxiliary approach

    NARCIS (Netherlands)

    George, S.J.; Tomovic, Z.; Averbeke, Van B.; Beljonne, D.; Lazzaroni, R.; Schenning, A.P.H.J.; Meijer, E.W.

    2012-01-01

    Stereoselective noncovalent synthesis of one-dimensional helical self-assembled stacks of achiral oligo(p-phenylenevinylene) ureidotriazine (AOPV3) monomers is obtained by a chiral supramolecular auxiliary approach. The racemic mixture of helical stacks of achiral AOPV3 molecules is converted into

  16. One-dimensional titania nanostructures: Synthesis and applications in dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hao [Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials and Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062 (China); State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Guo, Zhiguang, E-mail: zguo@licp.cas.cn [Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials and Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062 (China); State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Wang, Shimin [Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials and Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062 (China); Liu, Weimin [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2014-05-02

    One-dimensional (1D) titania (TiO{sub 2}) in the form of nanorods, nanowires, nanobelts and nanotubes have attracted much attention due to their unique physical, chemical and optical properties enabling extraordinary performance in biomedicine, sensors, energy storage, solar cells and photocatalysis. In this review, we mainly focus on synthetic methods for 1D TiO{sub 2} nanostructures and the applications of 1D TiO{sub 2} nanostructures in dye-sensitized solar cells (DSCs). Traditional nanoparticle-based DSCs have numerous grain boundaries and surface defects, which increase the charge recombination from photoanode to electrolyte. 1D TiO{sub 2} nanostructures can provide direct and rapid electron transport to the electron collecting electrode, indicating a promising choice for DSCs. We divide the applications of 1D TiO{sub 2} nanostructures in DSCs into four parts, that is, 1D TiO{sub 2} nanostructures only, 1D TiO{sub 2} nanostructure/nanoparticle composites, branched 1D TiO{sub 2} nanostructures, and 1D TiO{sub 2} nanostructures combined with other materials. This work will provide guidance for preparing 1D TiO{sub 2} nanostructures, and using them as photoanodes in efficient DSCs. - Graphical abstract: 1D TiO{sub 2} nanostructures which can provide direct and rapid pathways for electron transport have promising applications in dye-sensitized solar cells (DSCs). The synthetic methods and applications of 1D TiO{sub 2} nanostructures in DSCs are summarized in this review article.

  17. One-dimensional scanning of moisture in heated porous building materials with NMR.

    Science.gov (United States)

    van der Heijden, G H A; Huinink, H P; Pel, L; Kopinga, K

    2011-02-01

    In this paper we present a new dedicated NMR setup which is capable of measuring one-dimensional moisture profiles in heated porous materials. The setup, which is placed in the bore of a 1.5 T whole-body scanner, is capable of reaching temperatures up to 500 °C. Moisture and temperature profiles can be measured quasi simultaneously with a typical time resolution of 2-5 min. A methodology is introduced for correcting temperature effects on NMR measurements at these elevated temperatures. The corrections are based on the Curie law for paramagnetism and the observed temperature dependence of the relaxation mechanisms occurring in porous materials. Both these corrections are used to obtain a moisture content profile from the raw NMR signal profile. To illustrate the methodology, a one-sided heating experiment of concrete with a moisture content in equilibrium with 97% RH is presented. This kind of heating experiment is of particular interest in the research on fire spalling of concrete, since it directly reveals the moisture and heat transport occurring inside the concrete. The obtained moisture profiles reveal a moisture peak building up behind the boiling front, resulting in a saturated layer. To our knowledge the direct proof of the formation of a moisture peak and subsequent moisture clogging has not been reported before. Copyright © 2010 Elsevier Inc. All rights reserved.

  18. Debris flow analysis with a one dimensional dynamic run-out model that incorporates entrained material

    Science.gov (United States)

    Luna, Byron Quan; Remaître, Alexandre; van Asch, Theo; Malet, Jean-Philippe; van Westen, Cees

    2010-05-01

    Estimating the magnitude and the intensity of rapid landslides like debris flows is fundamental to evaluate quantitatively the hazard in a specific location. Intensity varies through the travelled course of the flow and can be described by physical features such as deposited volume, velocities, height of the flow, impact forces and pressures. Dynamic run-out models are able to characterize the distribution of the material, its intensity and define the zone where the elements will experience an impact. These models can provide valuable inputs for vulnerability and risk calculations. However, most dynamic run-out models assume a constant volume during the motion of the flow, ignoring the important role of material entrained along its path. Consequently, they neglect that the increase of volume enhances the mobility of the flow and can significantly influence the size of the potential impact area. An appropriate erosion mechanism needs to be established in the analyses of debris flows that will improve the results of dynamic modeling and consequently the quantitative evaluation of risk. The objective is to present and test a simple 1D debris flow model with a material entrainment concept based on limit equilibrium considerations and the generation of excess pore water pressure through undrained loading of the in situ bed material. The debris flow propagation model is based on a one dimensional finite difference solution of a depth-averaged form of the Navier-Stokes equations of fluid motions. The flow is treated as a laminar one phase material, which behavior is controlled by a visco-plastic Coulomb-Bingham rheology. The model parameters are evaluated and the model performance is tested on a debris flow event that occurred in 2003 in the Faucon torrent (Southern French Alps).

  19. Analysis of distances between inclusions in finite one-dimensional binary stochastic materials

    International Nuclear Information System (INIS)

    Griesheimer, D. P.; Millman, D. L.

    2009-01-01

    In this paper we develop a statistical distribution for the number of inclusions present in a one-dimensional binary stochastic material of a finite length. From this distribution, an analytic solution for the expected number of inclusions present in a given problem is derived. For cases where the analytical solution for the expected number of inclusions is prohibitively expensive to compute, a simple, empirically-derived, approximation for the expected value is presented. A series of numerical experiments are used to bound the error of this approximation over the domain of interest. Finally, the above approximations are used to develop a methodology for determining the distribution of distances between adjacent inclusions in the material, subject to known problem conditions including: the total length of the problem, the length of each inclusion, and the expected volume fraction of inclusions in the problem. The new method is shown to be equivalent to the use of the infinite medium nearest neighbor distribution with an effective volume fraction to account for the finite nature of the material. Numerical results are presented for a wide range of problem parameters, in order to demonstrate the accuracy of this method and identify conditions where the method breaks down. In general, the technique is observed to produce excellent results (absolute error less than 1 10-6) for problems with inclusion volume fractions less than 0.8 and a ratio of problem length to inclusion length greater than 25. For problems that do not fall into this category, the accuracy of the method is shown to be dependent on the particular combination of these parameters. A brief discussion of the relevance of this method for Monte Carlo chord length sampling algorithms is also provided. (authors)

  20. Synthesis and Application of One-Dimensional La(OH3 Nanostructures: An Overview

    Directory of Open Access Journals (Sweden)

    Xiang Xiao

    2014-01-01

    Full Text Available One-dimensional (1D semiconductor nanomaterials are of particular importance owing to their unique properties and potential applications. This review attempts to provide a comprehensive introduction of 1D La(OH3 nanostructures including nanowires, nanoneedles, nanobelts, and nanorods. Firstly, various strategies developed to fabricate the 1D La(OH3 nanostructures are discussed, such as precipitation and composite-hydroxide-mediated, hydrothermal, and solvothermal methods, accompanying the description of the corresponding growth mechanisms. Then, the unique properties such as novel physical properties of 1D La(OH3 nanostructures resulting from their unique electronic structures and numerous transition modes involving the 4f shells of these ions are represented in detail. Also, the wide applications in photocatalyst, capacitors, and photoluminescence based on the unique properties are discussed. Finally, the paper ends with a summary and some perspectives on the challenges and new directions in this emerging area.

  1. One dimensional CuO nanocrystals synthesis by electrical explosion: A study on structural, optical and electronic properties

    Energy Technology Data Exchange (ETDEWEB)

    Krishnan, Shutesh, E-mail: shutesh.k@onsemi.com [Department of Mechanical Engineering University of Malaya, 50603 Kuala Lumpur (Malaysia); ON Semiconductor Package Innovation and Development Center, 70450 Seremban (Malaysia); Haseeb, A.S.M.A.; Johan, Mohd Rafie [Department of Mechanical Engineering University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-02-15

    Highlights: • One-dimensional CuO nanoflakes were synthesized by novel wire explosion technique. • A physical synthesis method capable of producing high aspect ratio (1:16) nanocrystals. • Most energy efficient and eco-friendly synthesis of low-dimensional transition metal oxide nanocrystals. -- Abstract: One-dimensional (1D) copper oxide (CuO) nanocrystals were synthesized using a novel wire explosion in de-ionized (DI) water without any chemical additives. Highly crystalline 1D CuO nanocrystals with 1:16 aspect ratio were successfully synthesized using this technique. The chemical nature and physical structure of the nanocrystals were controlled by simply modulating the exploding medium temperature. The results showed that nanocrystals produced at explosion temperatures 65 °C and 95 °C are pure CuO with optical band-gap energy of 2.38 eV. High Resolution Transmission Electron Microscope analysis (HRTEM) indicates that the CuO nanocrystals are with growth in [1{sup ¯}11] and [1 1 1] directions. The epitaxial crystal growth kinetics of the 1D nanostructure by aggregation was discussed. The incorporation of microstructural features like edge dislocations and porosity in the growth mechanism was examined. X-ray photoelectron spectroscopy (XPS) characterization indicates the formation of high purity CuO nanocrystals with valence state +2. This study provides an energy efficient and eco-friendly synthesis method of 1D transition metal oxide nanocrystals for electronic applications.

  2. One dimensional CuO nanocrystals synthesis by electrical explosion: A study on structural, optical and electronic properties

    International Nuclear Information System (INIS)

    Krishnan, Shutesh; Haseeb, A.S.M.A.; Johan, Mohd Rafie

    2014-01-01

    Highlights: • One-dimensional CuO nanoflakes were synthesized by novel wire explosion technique. • A physical synthesis method capable of producing high aspect ratio (1:16) nanocrystals. • Most energy efficient and eco-friendly synthesis of low-dimensional transition metal oxide nanocrystals. -- Abstract: One-dimensional (1D) copper oxide (CuO) nanocrystals were synthesized using a novel wire explosion in de-ionized (DI) water without any chemical additives. Highly crystalline 1D CuO nanocrystals with 1:16 aspect ratio were successfully synthesized using this technique. The chemical nature and physical structure of the nanocrystals were controlled by simply modulating the exploding medium temperature. The results showed that nanocrystals produced at explosion temperatures 65 °C and 95 °C are pure CuO with optical band-gap energy of 2.38 eV. High Resolution Transmission Electron Microscope analysis (HRTEM) indicates that the CuO nanocrystals are with growth in [1 ¯ 11] and [1 1 1] directions. The epitaxial crystal growth kinetics of the 1D nanostructure by aggregation was discussed. The incorporation of microstructural features like edge dislocations and porosity in the growth mechanism was examined. X-ray photoelectron spectroscopy (XPS) characterization indicates the formation of high purity CuO nanocrystals with valence state +2. This study provides an energy efficient and eco-friendly synthesis method of 1D transition metal oxide nanocrystals for electronic applications

  3. Sensitivity analysis explains quasi-one-dimensional current transport in two-dimensional materials

    DEFF Research Database (Denmark)

    Boll, Mads; Lotz, Mikkel Rønne; Hansen, Ole

    2014-01-01

    We demonstrate that the quasi-one-dimensional (1D) current transport, experimentally observed in graphene as measured by a collinear four-point probe in two electrode configurations A and B, can be interpreted using the sensitivity functions of the two electrode configurations (configurations...... A and B represents different pairs of electrodes chosen for current sources and potential measurements). The measured sheet resistance in a four-point probe measurement is averaged over an area determined by the sensitivity function. For a two-dimensional conductor, the sensitivity functions for electrode...... configurations A and B are different. But when the current is forced to flow through a percolation network, e.g., graphene with high density of extended defects, the two sensitivity functions become identical. This is equivalent to a four-point measurement on a line resistor, hence quasi-1D transport...

  4. A one-dimensional material transfer model for HECTR version 1.5

    International Nuclear Information System (INIS)

    Geller, A.S.; Wong, C.C.

    1991-08-01

    HECTR (Hydrogen Event Containment Transient Response) is a lumped-parameter computer code developed for calculating the pressure-temperature response to combustion in a nuclear power plant containment building. The code uses a control-volume approach and subscale models to simulate the mass, momentum, and energy transfer occurring in the containment during a loss-of-collant-accident (LOCA). This document describes one-dimensional subscale models for mass and momentum transfer, and the modifications to the code required to implement them. Two problems were analyzed: the first corresponding to a standard problem studied with previous HECTR versions, the second to experiments. The performance of the revised code relative to previous HECTR version is discussed as is the ability of the code to model the experiments. 8 refs., 5 figs., 3 tabs

  5. Facile hydrothermal synthesis of one-dimensional nanostructured α-MnO2 for supercapacitors

    Science.gov (United States)

    Wei, Hongmei; Wang, Jinxing; Yang, Shengwei; Zhang, Yangyang; Li, Tengfei; Zhao, Shuoqing

    2016-09-01

    α-MnO2 recently becomes a promising candidate of electrode materials for high effective supercapacitors in which it possesses of unique structure of 2×2 tunnels that can provide more electrons and ions diffusion paths. In this work, different morphologies MnO2 with α-phase crystalline structure have been prepared via a one-step facile hydrothermal method by adding various reagents. Compositions, microstructures and morphologies of these as-synthesized materials were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) and electrochemical properties of α-MnO2 electrodes were studied by the cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS) in 1 M Na2SO4 aqueous solution. The specific capacitance of nanowires were 158 F g-1 while the specific capacitance of nanorods were 106 F g-1 at current density of 4 A g-1, and improved performance of the wire-like electrode material was probably ascribed to the larger specific surface area that can provide relatively more active sites for high capacity. Meanwhile, both the nanowires and nanorods of MnO2 presented fine cycle stability after continuous multiple charge/discharge times.

  6. ONE-DIMENSIONAL PLASMONIC NANO-PHOTOCATALYSTS: SYNTHESIS, CHARACTERIZATION AND PHOTOCATALYTIC ACTIVITY

    Energy Technology Data Exchange (ETDEWEB)

    Murph, S.

    2011-08-14

    This study describes a simple two-step approach to coat gold nanorods with a silica/titania shell. Gold nanorods with an aspect ratio of 2.5 (L = 48 {+-} 2 and d = 19 {+-} 1) are synthesized by a silver-seed mediated growth approach according to our previously reported procedure (Hunyadi Murph ACS Symposium Series, Volume 1064, Chapter 8, 2011, 127-163 and reference herein). Gold nanorods are grown on pre-formed gold nano-seeds in the presence of surfactant, cetyltrimethylammonium bromide (CTAB), and a small amount of silver ions. A bifunctional linker molecule which has a thiol group at one end and a silane group at the other is used to derivatize gold nanorods. The silane group is subsequently reacted with both sodium silicate and titanium isopropoxide to a silica/titania shell around the gold nanorods. By fine tuning the reaction conditions, the silica/titania shell thickness can be controlled from {approx}5 to {approx}40nm. The resulting nanomaterials are stable, amenable to scale up and can be isolated without core aggregation or decomposition. These new materials have been characterized by scanning electron microscopy, energy dispersive X-ray analysis, UV-Vis spectroscopy and dynamic light scattering analysis. Photocatalytic activity of Au-silica/titania nanomaterials under visible and UV illumination is measured via degradation of a model dye, methyl orange (MO) under visible and UV illumination. The results indicate a 3 fold improvement in the photocatalytic decomposition rate of MO under visible illumination vs. UV illumination.

  7. Study of microwave drying of wet materials based on one-dimensional two-phase model

    Science.gov (United States)

    Salomatov, Vl V.; Karelin, V. A.

    2017-11-01

    Currently, microwave is one of the most interesting ways to conduct drying of dielectric materials, in particular coal. In this paper, two processes were considered - heating and drying. The temperature field of the coal semi-mass in the heating mode is found analytically strictly with the use of integral transformations. The drying process is formulated as a nonlinear Stephen problem with a moving boundary of the liquid-vapor phase transformation. The temperature distribution, speed and drying time in this mode are determined approximately analytically. Parametric analysis of the influence of the material and boundary conditions on the dynamics of warming up and drying is revealed.

  8. Large-scale one-dimensional Bi x O y I z nanostructures: synthesis, characterization, and photocatalytic applications

    Science.gov (United States)

    Liu, Chaohong; Zhang, Dun

    2015-03-01

    The performances of Bi x O y I z photofunctional materials are very sensitive to their composition and microstructures; however, the morphology evolution and crystallization process of one-dimensional Bi x O y I z nanostructures, the roles of experimental factors, and related reaction mechanisms remain poorly understood. In this work, large-scale one-dimensional Bi x O y I z nanostructures were fabricated using simple inorganic iodine source. By combing the results of X-ray diffraction and scanning electron microscope, the effect of volume ratios of water and ethanol, concentration of NaOH, and reaction time on the morphologies and crystal phases of Bi x O y I z were elaborated. On the basis of characterizations, a possible process for the growth of Bi5O7I nanobelts was proposed. The optical performances of Bi x O y I z nanostructures were evaluated by ultraviolet-visible-near infrared diffuse reflectance spectra as well as photocatalytic degradation of organic dye and corrosive bacteria. The as-prepared Bi5O7I/Bi2O2CO3/BiOI composite showed excellent photocatalytic activity over malachite green under visible light irradiation, which was deduced closely related to its heterojunction structures.

  9. Thermo-elastic Green's functions for an infinite bi-material of one-dimensional hexagonal quasi-crystals

    International Nuclear Information System (INIS)

    Li, P.D.; Li, X.Y.; Zheng, R.F.

    2013-01-01

    This Letter is concerned with thermo-elastic fundamental solutions of an infinite space, which is composed of two half-infinite bodies of different one-dimensional hexagonal quasi-crystals. A point thermal source is embedded in a half-space. The interface can be either perfectly bonded or smoothly contacted. On the basis of the newly developed general solution, the temperature-induced elastic field in full space is explicitly presented in terms of elementary functions. The interactions among the temperature, phonon and phason fields are revealed. The present work can play an important role in constructing farther analytical solutions for crack, inclusion and dislocation problems. -- Highlights: ► Green's functions are constructed in terms of 10 quasi-harmonic functions. ► Thermo-elastic field of a 1D hexagonal QC bi-material body is expressed explicitly. ► Both perfectly bonded and smoothly contacted interfaces are considered

  10. Comparison of one-dimensional probabilistic finite element method with direct numerical simulation of dynamically loaded heterogeneous materials

    Science.gov (United States)

    Robbins, Joshua; Voth, Thomas

    2011-06-01

    Material response to dynamic loading is often dominated by microstructure such as grain topology, porosity, inclusions, and defects; however, many models rely on assumptions of homogeneity. We use the probabilistic finite element method (WK Liu, IJNME, 1986) to introduce local uncertainty to account for material heterogeneity. The PFEM uses statistical information about the local material response (i.e., its expectation, coefficient of variation, and autocorrelation) drawn from knowledge of the microstructure, single crystal behavior, and direct numerical simulation (DNS) to determine the expectation and covariance of the system response (velocity, strain, stress, etc). This approach is compared to resolved grain-scale simulations of the equivalent system. The microstructures used for the DNS are produced using Monte Carlo simulations of grain growth, and a sufficient number of realizations are computed to ensure a meaningful comparison. Finally, comments are made regarding the suitability of one-dimensional PFEM for modeling material heterogeneity. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  11. Binder-free cobalt phosphate one-dimensional nanograsses as ultrahigh-performance cathode material for hybrid supercapacitor applications

    Science.gov (United States)

    Sankar, K. Vijaya; Lee, S. C.; Seo, Y.; Ray, C.; Liu, S.; Kundu, A.; Jun, S. C.

    2018-01-01

    One-dimensional (1D) nanostructure exhibits excellent electrochemical performance because of their unique physico-chemical properties like fast electron transfer, good rate capability, and cyclic stability. In the present study, Co3(PO4)2 1D nanograsses are grown on Ni foam using a simple and eco-friendly hydrothermal technique with different reaction times. The open space with uniform nanograsses displays a high areal capacitance, rate capability, energy density, and cyclic stability due to the nanostructure enhancing fast ion and material interactions. Ex-situ microscope images confirm the dependence of structural stability on the reaction time, and the nanograsses promoted ion interaction through material. Further, the reproducibility of the electrochemical performance confirms the binder-free Co3(PO4)2 1D nanograsses to be a suitable high-performance cathode material for application to hybrid supercapacitor. Finally, the assembled hybrid supercapacitor exhibits a high energy density (26.66 Wh kg-1 at 750 W kg-1) and longer lifetimes (80% retained capacitance after 6000 cycles). Our results suggests that the Co3(PO4)2 1D nanograss design have a great promise for application to hybrid supercapacitor.

  12. Recent advances in organic one-dimensional composite materials: design, construction, and photonic elements for information processing.

    Science.gov (United States)

    Yan, Yongli; Zhang, Chuang; Yao, Jiannian; Zhao, Yong Sheng

    2013-07-19

    Many recent activities in the use of one-dimensional nanostructures as photonic elements for optical information processing are explained by huge advantages that photonic circuits possess over traditional silicon-based electronic ones in bandwidth, heat dissipation, and resistance to electromagnetic wave interference. Organic materials are a promising candidate to support these optical-related applications, as they combine the properties of plastics with broad spectral tunability, high optical cross-section, easy fabrication, as well as low cost. Their outstanding compatibility allows organic composite structures which are made of two or more kinds of materials combined together, showing great superiority to single-component materials due to the introduced interactions among multiple constituents, such as energy transfer, electron transfer, exciton coupling, etc. The easy processability of organic 1D crystalline heterostructures enables a fine topological control of both composition and geometry, which offsets the intrinsic deficiencies of individual material. At the same time, the strong exciton-photon coupling and exciton-exciton interaction impart the excellent confinement of photons in organic microstructures, thus light can be manipulated according to our intention to realize specific functions. These collective properties indicate a potential utility of organic heterogeneous material for miniaturized photonic circuitry. Herein, focus is given on recent advances of 1D organic crystalline heterostructures, with special emphasis on the novel design, controllable construction, diverse performance, as well as wide applications in isolated photonic elements for integration. It is proposed that the highly coupled, hybrid optical networks would be an important material basis towards the creation of on-chip optical information processing. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. The prevalent synthesis of one-dimensional noble metal nanostructures based on sulfonated polyaniline at room temperature

    International Nuclear Information System (INIS)

    Xia Youyi

    2011-01-01

    We describe a prevalent method of synthesizing one-dimensional (1D) noble metal nanostructures (silver nanobelts and palladium nanowires) by treatment of corresponding noble metal ions only in the presence of the conductive sulfonated polyaniline without using any other reducing agents or energies. The results show that the sulfonated polyaniline provides the dual reductant and “soft template” roles to promoting noble metal ions to form shape-controlled 1D noble metal nanostructures in high yield. The employed approach may also shed some light on the preparation of other noble metal nanostructure by using conductive polymer.

  14. A new one-dimensional compound: Synthesis and structure of InNb3(Se2)6

    International Nuclear Information System (INIS)

    Deng Shuiquan; Zhuang Honghui; Huang Jinshun; Huang Jingling

    1993-01-01

    The new one-dimensional compound, indium niobium selenide, was synthesized by high-temperature solid-state reactions. The structure is composed of [Nb 3 (Se 2 ) 6 ] ∞ chains running along the c axis with In atoms intercalated between these chains. All the Nb atoms have rectangular antiprismatic coordination environments. All the Se atoms in the structure are in the form of Se 2 dimers with Se-Se distances of 2.325(2) and 2.356(2) A. (orig.)

  15. Highly conducting one-dimensional solids

    CERN Document Server

    Evrard, Roger; Doren, Victor

    1979-01-01

    Although the problem of a metal in one dimension has long been known to solid-state physicists, it was not until the synthesis of real one-dimensional or quasi-one-dimensional systems that this subject began to attract considerable attention. This has been due in part to the search for high­ temperature superconductivity and the possibility of reaching this goal with quasi-one-dimensional substances. A period of intense activity began in 1973 with the report of a measurement of an apparently divergent conduc­ tivity peak in TfF-TCNQ. Since then a great deal has been learned about quasi-one-dimensional conductors. The emphasis now has shifted from trying to find materials of very high conductivity to the many interesting problems of physics and chemistry involved. But many questions remain open and are still under active investigation. This book gives a review of the experimental as well as theoretical progress made in this field over the last years. All the chapters have been written by scientists who have ...

  16. Facile synthesis of α-MnO2 one-dimensional (1D) nanostructure and energy storage ability studies

    International Nuclear Information System (INIS)

    Yousefi, Taher; Golikand, Ahmad Nozad; Hossein Mashhadizadeh, Mohammad; Aghazadeh, Mustafa

    2012-01-01

    The dense manganese oxide nanorods with an extremely narrow distribution are synthesized at a low temperature using first cathodic electrodeposition subsequently heat treatment. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that the nanorods have bar shapes, and their average diameter is less than 50 nm. The Fourier transform infrared (FT-IR) study, the selected area electron diffraction (SAED) pattern in TEM images and the X-ray diffraction (XRD) result show that the nanorods are α-MnO 2 single crystal. The results of N 2 adsorption–desorption analysis indicate that the BET surface area of the α-MnO 2 nanorods is 93 m 2 g −1 . By recording the potential–time curve during the electrodeposition process, it is revealed that water reduction reaction has a major role in the electrogeneration of base at the cathode surface under the applied electrochemical conditions. Finally, based on the H 2 bubbling on the cathode surface, the mechanism of the formation and the growth of α-MnO 2 nanorods are proposed and discussed. For the electrochemical supercapacitor application, electrochemically prepared α-MnO 2 is found to be stable for a large number of cycles with high specific capacitance, 338 F g −1 at a scan rate of 10 mV s −1 . Finally, the charge–discharge mechanism is discussed. - Graphical abstract: Highlights: ► New nanostructures of MnO 2 is synthesized by simple method of cathodicelectrodeposition. ► The product has unique one-dimensional morphology with average diameter size of 50 nm. ► The experiment conditions (temperature, current density) has not been reported. ► The one-nanostructures obtained without using of hard template or surfactant.

  17. Bi-substituted iron garnet films for one-dimensional magneto-photonic crystals: Synthesis and properties

    International Nuclear Information System (INIS)

    Shaposhnikov, A.N.; Karavainikov, A.V.; Prokopov, A.R.; Berzhansky, V.N.; Salyuk, O.Y.

    2012-01-01

    Graphical abstract: Faraday hysteresis loops for Bi 1.0 Y 0.5 Gd 1.5 Fe 4.2 Al 0.8 O 12 film on glass-ceramic substrate (a), Bi 2.8 Y 0.2 Fe 5 O 12 film on gallium–gadolinium garnet (b) and for glass-ceramic/SiO 2 /Bi 1.0 Y 0.5 Gd 1.5 Fe 4.2 Al 0.8 O 12 /Bi 2.8 Y 0.2 Fe 5 O 12 structure (c). Highlights: ► Bismuth-substituted iron garnet films as magneto-optical layers in magneto-photonic crystals. ► It is impossible to crystallize the films with high Bi content on amorphous substrates. ► The crystallization of the films can be achieved by their deposition on buffer layer with low bismuth content. -- Abstract: The crystallization processes in Bi 2.8 Y 0.2 Fe 5 O 12 , Bi 2.5 Gd 0.5 Fe 3.8 Al 1.2 O 12 , Bi 1.5 Gd 1.5 Fe 4.5 Al 0.5 O 12 and Bi 1.0 Y 0.5 Gd 1.5 Fe 4.2 Al 0.8 O 12 garnet films deposited by reactive ion beam sputtering on (1 1 1) gadolinium–gallium garnet substrates, optical glass-ceramic and SiO 2 films have been studied. Films were annealed at low pressure in oxygen atmosphere and in the air. The possibility of preparation of crystalline garnet films with high concentration of bismuth on the SiO 2 films using a buffer layer with low concentration of Bi has been shown. This allows to produce one-dimensional magneto-photonic crystals with high effective Faraday rotation (several tens of°/μm for the visible optical spectrum).

  18. Bi-substituted iron garnet films for one-dimensional magneto-photonic crystals: Synthesis and properties

    Energy Technology Data Exchange (ETDEWEB)

    Shaposhnikov, A.N.; Karavainikov, A.V.; Prokopov, A.R.; Berzhansky, V.N. [Taurida National V.I. Vernadsky University, Vernadsky Av., 4, 95007 Simferopol (Ukraine); Salyuk, O.Y., E-mail: olga-saliuk@yandex.ru [Institute of Magnetizm NASU and MESU, 36-B Vernadsky Blvd., 03142 Kiev (Ukraine)

    2012-06-15

    Graphical abstract: Faraday hysteresis loops for Bi{sub 1.0}Y{sub 0.5}Gd{sub 1.5}Fe{sub 4.2}Al{sub 0.8}O{sub 12} film on glass-ceramic substrate (a), Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12} film on gallium–gadolinium garnet (b) and for glass-ceramic/SiO{sub 2}/Bi{sub 1.0}Y{sub 0.5}Gd{sub 1.5}Fe{sub 4.2}Al{sub 0.8}O{sub 12}/Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12} structure (c). Highlights: ► Bismuth-substituted iron garnet films as magneto-optical layers in magneto-photonic crystals. ► It is impossible to crystallize the films with high Bi content on amorphous substrates. ► The crystallization of the films can be achieved by their deposition on buffer layer with low bismuth content. -- Abstract: The crystallization processes in Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12}, Bi{sub 2.5}Gd{sub 0.5}Fe{sub 3.8}Al{sub 1.2}O{sub 12}, Bi{sub 1.5}Gd{sub 1.5}Fe{sub 4.5}Al{sub 0.5}O{sub 12} and Bi{sub 1.0}Y{sub 0.5}Gd{sub 1.5}Fe{sub 4.2}Al{sub 0.8}O{sub 12} garnet films deposited by reactive ion beam sputtering on (1 1 1) gadolinium–gallium garnet substrates, optical glass-ceramic and SiO{sub 2} films have been studied. Films were annealed at low pressure in oxygen atmosphere and in the air. The possibility of preparation of crystalline garnet films with high concentration of bismuth on the SiO{sub 2} films using a buffer layer with low concentration of Bi has been shown. This allows to produce one-dimensional magneto-photonic crystals with high effective Faraday rotation (several tens of°/μm for the visible optical spectrum).

  19. Synthesis of one-dimensional copper sulfide nanorods as high-performance anode in lithium ion batteries.

    Science.gov (United States)

    Li, Xue; He, Xinyi; Shi, Chunmei; Liu, Bo; Zhang, Yiyong; Wu, Shunqing; Zhu, Zizong; Zhao, Jinbao

    2014-12-01

    Nanorod-like CuS and Cu2 S have been fabricated by a hydrothermal approach without using any surfactant and template. The electrochemical behavior of CuS and Cu2 S nanorod anodes for lithium-ion batteries reveal that they exhibit stable lithium-ion insertion/extraction reversibility and outstanding rate capability. Both of the electrodes exhibit excellent capacity retentions irrespective of the rate used, even at a high current density of 3200 mA g(-1) . More than 370 mAh g(-1) can be retained for the CuS electrode and 260 mAh g(-1) for the Cu2 S electrode at the high current rate. After 100 cycles at 100 mA g(-1) , the obtained CuS and Cu2 S electrodes show discharge capacities of 472 and 313 mAh g(-1) with retentions of 92% and 96%, respectively. Together with the simplicity of fabrication and good electrochemical properties, CuS and Cu2 S nanorods are promising anode materials for practical use the next-generation lithium-ion batteries. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. The phonon-polariton spectrum of one-dimensional Rudin-Shapiro photonic superlattices with uniaxial polar materials

    Science.gov (United States)

    Gómez-Urrea, H. A.; Duque, C. A.; Mora-Ramos, M. E.

    2015-11-01

    The properties of the optical-phonon-associated polaritonic modes that appear under oblique light incidence in 1D superlattices made of photonic materials are studied. The investigated systems result from the periodic repetition of quasiregular Rudin-Shapiro (RS) multilayer units. It is assume that the structure consists of both passive non-dispersive layers of constant refraction index and active layers of uniaxial polar materials. In particular, we consider III-V wurtzite nitrides. The optical axis of these polaritonic materials is taken along the growth direction. Maxwell equations are solved using the transfer matrix technique for all admissible values of the incidence angle.

  1. Comb-like optical transmission spectra generated from one-dimensional two-segment-connected two-material waveguide networks optimized by genetic algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yu [MOE Key Laboratory of Laser Life Science and Institute of Laser Life Science, College of Biophotonics, South China Normal University, Guangzhou 510631 (China); Yang, Xiangbo, E-mail: xbyang@scnu.edu.cn [MOE Key Laboratory of Laser Life Science and Institute of Laser Life Science, College of Biophotonics, South China Normal University, Guangzhou 510631 (China); School of Physical Education and Sports Science, South China Normal University, Guangzhou 510006 (China); Lu, Jian; Zhang, Guogang [MOE Key Laboratory of Laser Life Science and Institute of Laser Life Science, College of Biophotonics, South China Normal University, Guangzhou 510631 (China); Liu, Chengyi Timon [School of Physical Education and Sports Science, South China Normal University, Guangzhou 510006 (China)

    2014-03-01

    In this Letter, a one-dimensional (1D) two-segment-connected two-material waveguide network (TSCTMWN) is designed to produce comb-like frequency passbands, where each waveguide segment is composed of normal and anomalous dispersion materials and the length ratio of sub-waveguide segments is optimized by genetic algorithm (GA). It is found that 66 comb-like frequency passbands are created in the second frequency unit, maximal relative width difference of which is less than 2×10{sup −5}. It may be useful for the designing of dense wavelength division multiplexings (DWDMs) and multi-channel filters, etc., and provide new applications for GA.

  2. Glovebox-contained forty-millimeter gun system for the study of one-dimensional shock waves in toxic materials

    International Nuclear Information System (INIS)

    Honodel, C.A.

    1975-01-01

    A new gun system is being constructed at the Lawrence Livermore Laboratory for studies of the behavior of toxic materials under shock-loaded conditions. Due to the extreme toxicity of some materials, such as plutonium, the entire gun system must be enclosed in gloveboxes. Some of the experimental requirements that affected the design of the system, various diagnostic techniques that will be employed with the system, and some details of the final design that is presently under assembly are presented

  3. Facile Synthesis of Quasi-One-Dimensional Au/PtAu Heterojunction Nanotubes and Their Application as Catalysts in an Oxygen-Reduction Reaction.

    Science.gov (United States)

    Cai, Kai; Liu, Jiawei; Zhang, Huan; Huang, Zhao; Lu, Zhicheng; Foda, Mohamed F; Li, Tingting; Han, Heyou

    2015-05-11

    An intermediate-template-directed method has been developed for the synthesis of quasi-one-dimensional Au/PtAu heterojunction nanotubes by the heterogeneous nucleation and growth of Au on Te/Pt core-shell nanostructures in aqueous solution. The synthesized porous Au/PtAu bimetallic nanotubes (PABNTs) consist of porous tubular framework and attached Au nanoparticles (AuNPs). The reaction intermediates played an important role in the preparation, which fabricated the framework and provided a localized reducing agent for the reduction of the Au and Pt precursors. The Pt7 Au PABNTs showed higher electrocatalytic activity and durability in the oxygen-reduction reaction (ORR) in 0.1 M HClO4 than porous Pt nanotubes (PtNTs) and commercially available Pt/C. The mass activity of PABNTs was 218 % that of commercial Pt/C after an accelerated durability test. This study demonstrates the potential of PABNTs as highly efficient electrocatalysts. In addition, this method provides a facile strategy for the synthesis of desirable hetero-nanostructures with controlled size and shape by utilizing an intermediate template. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Facile solvothermal synthesis of abnormal growth of one-dimensional ZnO nanostructures by ring-opening reaction of polyvinylpyrrolidone

    Energy Technology Data Exchange (ETDEWEB)

    Xu, G., E-mail: gxu@alum.imr.ac.cn; Wang, X.L.; Liu, G.Z.

    2015-02-28

    Graphical abstract: - Highlights: • Facile solvothermal synthesis of ZnO nanostructures in super high alkaline alcoholic condition. • The exact role and chemical transformations of PVP in solvothermal synthesis of ZnO nanostructures was revealed. • Mechanism of abnormal growth of ZnO nanopyramids was proposed based on ring-opening reaction of PVP. - Abstract: Abnormal growth of one-dimensional (1-D) ZnO nanostructures (NSs) have been accomplished with the assistance of polyvinylpyrrolidone (PVP) under a super high alkaline alcoholic solvothermal condition. The products were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and proton nuclear magnetic resonance ({sup 1}H NMR) spectroscopy. The effect of synthetic conditions, such as reaction temperature and the addition of PVP, on the morphologies of ZnO products were investigated. The results show that PVP molecules had the significant role in the transformation of morphologies of ZnO NSs ranging from nanorods, nanoparticles to pyramids, as well as flower-like assembly features. The possible growth mechanism of ZnO pyramids was proposed based on ring-opening reaction of PVP.

  5. Quasi-one-dimensional nanostructured cobalt (Co) intercalated vanadium oxide (V{sub 2}O{sub 5}): Peroxovanadate sol gel synthesis and structural study

    Energy Technology Data Exchange (ETDEWEB)

    Langie da Silva, Douglas, E-mail: douglas.langie@ufpel.edu.br [Departamento de Física, Universidade Federal de Pelotas, Caixa Postal 354, Pelotas 96010-900 (Brazil); Moreira, Eduardo Ceretta [Laboratório de Espectroscopia, Universidade Federal do Pampa, Campus Bagé, Bagé 96400-970 (Brazil); Dias, Fábio Teixeira; Neves Vieira, Valdemar das [Departamento de Física, Universidade Federal de Pelotas, Caixa Postal 354, Pelotas 96010-900 (Brazil); Brandt, Iuri Stefani; Cas Viegas, Alexandre da; Pasa, André Avelino [Laboratório de Filmes Finos e Superfícies, Universidade Federal de Santa Catarina, Caixa Postal 476, Florianópolis 88.040-900 (Brazil)

    2015-01-15

    Nanostructured cobalt vanadium oxide (V{sub 2}O{sub 5}) xerogels spread onto crystalline Si substrates were synthesized via peroxovanadate sol gel route. The resulting products were characterized by distinct experimental techniques. The surface morphology and the nanostructure of xerogels correlate with Co concentration. The decrease of the structural coherence length is followed by the formation of a loose network of nanopores when the concentration of intercalated species was greater than 4 at% of Co. The efficiency of the synthesis route also drops with the increase of Co concentration. The interaction between the Co(OH{sub 2}){sub 6}{sup 2+} cations and the (H{sub 2}V{sub 10}O{sub 28}){sup 4−} anions during the synthesis was suggested as a possible explanation for the incomplete condensation of the V{sub 2}O{sub 5} gel. Finally the experimental results points for the intercalation of Co between the bilayers of the V{sub 2}O{sub 5}. In this scenario two possible preferential occupation sites for the metallic atoms in the framework of the xerogel were proposed. - Graphical abstract: Quasi-one-dimensional nanostructured cobalt (Co) intercalated vanadium oxide (V{sub 2}O{sub 5}) nanoribbons synthesized by peroxovanadate sol gel route. - Highlights: • Nanostructured cobalt V{sub 2}O{sub 5} gel spread onto c{sub S}i were synthesized via peroxovanadate sol gel route. • The micro and nanostructure correlates with the cobalt content. • The efficiency of the synthesis route shows to be also dependent of Co content. • The experimental results points for the intercalation of Co between the bilayers of the V{sub 2}O{sub 5} xerogel.

  6. One dimensional model for polytypes

    International Nuclear Information System (INIS)

    Rosato, A.

    1979-01-01

    The general expression for the dispersion relation for a polyatomic one dimensional crystal obtained by the Laplace Transform Method is applied to materials with the fcc and hcp structures, both consisting of close-packed planes of atoms with the stacking sequence of plane ABC/ABC... and AB/AB... respectively. The expression is also applied to polytypes, that is materials caracterized by a stacking sequence with longer repeat unit. The effective mass is cast in a condensed form useful for further calculations. The results from this simple model are only qualitative. (Author) [pt

  7. Hydrothermal synthesis and characterization of a two-dimensional piperazinium cobalt–zinc phosphate via a metastable one-dimensional phase

    International Nuclear Information System (INIS)

    Torre-Fernández, Laura; Khainakova, Olena A.; Espina, Aránzazu; Amghouz, Zakariae; Khainakov, Sergei A.; Alfonso, Belén F.; Blanco, Jesús A.; García, José R.; García-Granda, Santiago

    2015-01-01

    A two-dimensional piperazinium cobalt–zinc phosphate, formulated as (C 4 N 2 H 12 ) 1.5 (Co 0.6 Zn 0.4 ) 2 (HPO 4 ) 2 (PO 4 )·H 2 O (2D), was synthesized under hydrothermal conditions. The crystal structure was determined using single-crystal X-ray diffraction data (monoclinic P2 1 /c, a=8.1165(3) Å, b=26.2301(10) Å, c=8.3595(4) Å, and β=110.930(5)°) and the hydrogen atom positions were optimized by DFT calculations. A single-crystal corresponding to one-dimensional metastable phase, (C 4 N 2 H 12 )Co 0.3 Zn 0.7 (HPO 4 ) 2 ·H 2 O (1D), was also isolated and the crystal structure was determined (monoclinic P2 1 /c, a=8.9120(6) Å, b=14.0290(1) Å, c=12.2494(5) Å, and β=130.884(6)°). The bulk was characterized by chemical (C–H–N) analysis, powder X-ray diffraction (PXRD), powder X-ray thermodiffractometry (HT-XRD), transmission electron microscopy (STEM(DF)-EDX and EFTEM), and thermal analysis (TG/SDTA-MS), including activation energy data of its thermal decomposition. The magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Graphical abstract: Hydrothermal synthesis and structural characterization of a two-dimensional piperazinium cobalt–zinc phosphate, (C 4 N 2 H 12 ) 1.5 (Co 0.6 Zn 0.4 ) 2 (HPO 4 ) 2 (PO 4 )·H 2 O (2D), have been reported. The crystal structure of a one-dimensional piperazinium cobalt–zinc phosphate, (C 4 N 2 H 12 )Co 0.3 Zn 0.7 (HPO 4 ) 2 ·H 2 O (1D) a metastable phase during the hydrothermal synthesis, was also determined. The thermal behavior of 2D compound is strongly dependent on the selected heating rate and the magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Highlights: • A 2D piperazinium cobalt–zinc phosphate has been synthesized and characterized. • Crystal structure of 1D metastable phase was also determined. • Thermal behavior of 2D compound is strongly dependent on the selected heating rate. • Magnetic

  8. A review on one dimensional perovskite nanocrystals for piezoelectric applications

    Directory of Open Access Journals (Sweden)

    Li-Qian Cheng

    2016-03-01

    Full Text Available In recent years, one-dimensional piezoelectric nanomaterials have become a research topic of interest because of their special morphology and excellent piezoelectric properties. This article presents a short review on one dimensional perovskite piezoelectric materials in different systems including Pb(Zr,TiO3, BaTiO3 and (K,NaNbO3 (KNN. We emphasize KNN as a promising lead-free piezoelectric compound with a high Curie temperature and high piezoelectric properties and describe its synthesis and characterization. In particular, details are presented for nanoscale piezoelectricity characterization of a single KNN nanocrystal by piezoresponse force microscopy. Finally, this review describes recent progress in applications based on one dimensional piezoelectric nanostructures with a focus on energy harvesting composite materials.

  9. One-dimensional nanomaterials for energy storage

    Science.gov (United States)

    Chen, Cheng; Fan, Yuqi; Gu, Jianhang; Wu, Liming; Passerini, Stefano; Mai, Liqiang

    2018-03-01

    The search for higher energy density, safer, and longer cycling-life energy storage systems is progressing quickly. One-dimensional (1D) nanomaterials have a large length-to-diameter ratio, resulting in their unique electrical, mechanical, magnetic and chemical properties, and have wide applications as electrode materials in different systems. This article reviews the latest hot topics in applying 1D nanomaterials, covering both their synthesis and their applications. 1D nanomaterials can be grouped into the categories: carbon, silicon, metal oxides, and conducting polymers, and we structure our discussion accordingly. Then, we survey the unique properties and application of 1D nanomaterials in batteries and supercapacitors, and provide comments on the progress and advantages of those systems, paving the way for a better understanding of employing 1D nanomaterials for energy storage.

  10. One-Dimensionality and Whiteness

    Science.gov (United States)

    Calderon, Dolores

    2006-01-01

    This article is a theoretical discussion that links Marcuse's concept of one-dimensional society and the Great Refusal with critical race theory in order to achieve a more robust interrogation of whiteness. The author argues that in the context of the United States, the one-dimensionality that Marcuse condemns in "One-Dimensional Man" is best…

  11. Hydrothermal synthesis and characterization of a two-dimensional piperazinium cobalt–zinc phosphate via a metastable one-dimensional phase

    Energy Technology Data Exchange (ETDEWEB)

    Torre-Fernández, Laura; Khainakova, Olena A. [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo-CINN, 33006 Oviedo (Spain); Espina, Aránzazu [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Amghouz, Zakariae, E-mail: amghouz.uo@uniovi.es [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Khainakov, Sergei A. [Servicios Científico Técnicos, Universidad de Oviedo, 33006 Oviedo (Spain); Alfonso, Belén F.; Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, 33007 Oviedo (Spain); García, José R.; García-Granda, Santiago [Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, Universidad de Oviedo-CINN, 33006 Oviedo (Spain)

    2015-05-15

    A two-dimensional piperazinium cobalt–zinc phosphate, formulated as (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), was synthesized under hydrothermal conditions. The crystal structure was determined using single-crystal X-ray diffraction data (monoclinic P2{sub 1}/c, a=8.1165(3) Å, b=26.2301(10) Å, c=8.3595(4) Å, and β=110.930(5)°) and the hydrogen atom positions were optimized by DFT calculations. A single-crystal corresponding to one-dimensional metastable phase, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D), was also isolated and the crystal structure was determined (monoclinic P2{sub 1}/c, a=8.9120(6) Å, b=14.0290(1) Å, c=12.2494(5) Å, and β=130.884(6)°). The bulk was characterized by chemical (C–H–N) analysis, powder X-ray diffraction (PXRD), powder X-ray thermodiffractometry (HT-XRD), transmission electron microscopy (STEM(DF)-EDX and EFTEM), and thermal analysis (TG/SDTA-MS), including activation energy data of its thermal decomposition. The magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Graphical abstract: Hydrothermal synthesis and structural characterization of a two-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12}){sub 1.5}(Co{sub 0.6}Zn{sub 0.4}){sub 2}(HPO{sub 4}){sub 2}(PO{sub 4})·H{sub 2}O (2D), have been reported. The crystal structure of a one-dimensional piperazinium cobalt–zinc phosphate, (C{sub 4}N{sub 2}H{sub 12})Co{sub 0.3}Zn{sub 0.7}(HPO{sub 4}){sub 2}·H{sub 2}O (1D) a metastable phase during the hydrothermal synthesis, was also determined. The thermal behavior of 2D compound is strongly dependent on the selected heating rate and the magnetic susceptibility and magnetization measurements show no magnetic ordering down to 4 K. - Highlights: • A 2D piperazinium cobalt–zinc phosphate has been synthesized and characterized. • Crystal

  12. Controlled size and one-dimensional growth

    Indian Academy of Sciences (India)

    875–881. c Indian Academy of Sciences. Synthesis of azamacrocycle stabilized palladium nanoparticles: Controlled size and one-dimensional growth. JEYARAMAN ATHILAKSHMI and DILLIP KUMAR CHAND. ∗. Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India e-mail: dillip@iitm.ac.

  13. Synthesis of an S T = 7 [Mn 3 ] Mixed-Valence Complex Based on 1,3-Propanediol Ligand Derivatives and Its One-Dimensional Assemblies

    KAUST Repository

    Huang, Jian

    2013-10-07

    Controlled organization of high-spin complexes and single-molecule magnets is a great challenge in molecular magnetism in order to study the effect of the intercomplex magnetic interactions on the intrinsic properties of a given magnetic object. In this work, a new ST = 7 trinuclear mixed-valence Mn complex, [MnIIIMnII 2(LA) 2(Br)4(CH3OH)6] ·Br· (CH3OH)1.5·(H2O)0.5 (1), is reported using a pyridinium-functionalized 1,3-propanediol ligand (H 2LABr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)pyridinium bromide). Using azido anions as bridging ligands and different pyridinium-functionalized 1,3-propanediol ligands (H2LBBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-4-picolinium bromide; H 2LCBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-3,5- lutidinium bromide), the linear [MnIIIMnII 2L2X4]+ building block has been assembled into one-dimensional coordination networks: [MnIIIMn II 2(LA)2(Br)4(CH 3OH)4(N3)]·((C2H 5)2O)1.25 (2∞), [MnIIIMn II 2(LB)2(Br)4(C 2H5OH)(CH3OH)(H2O) 2(N3)]·(H2O)0.25 (3∞), and [MnIIIMnII 2(LC) 2(Cl)3.8(Br)0.2(C2H 5OH)3(CH3OH)(N3)] (4∞). The syntheses, characterization, crystal structures, and magnetic properties of these new [Mn3]-based materials are reported. © 2013 American Chemical Society.

  14. Design and realization of one-dimensional double hetero-structure photonic crystals for infrared-radar stealth-compatible materials applications

    International Nuclear Information System (INIS)

    Wang, Zhixun; Cheng, Yongzhi; Nie, Yan; Wang, Xian; Gong, Rongzhou

    2014-01-01

    In this paper, a new type one-dimensional (1D) double hetero-structure composite photonic crystal (CPC) for infrared-radar stealth-compatible materials applications was proposed and studied numerically and experimentally. First, based on transfer matrix method of thin-film optical theory, the propagation characteristics of the proposed structure comprising a stack of different alternating micrometer-thick layers of germanium and zinc sulfide were investigated numerically. Calculation results exhibit that this 1D single hetero-structure PC could achieve a flat high reflectivity gradually with increasing the number of the alternating media layers in a single broadband range. Then, based on principles of distributed Bragg reflector micro-cavity, a 1D double hetero-structure CPC comprising four PCs with thickness of 0.797 μm, 0.592 μm, 1.480 μm, and 2.114 μm, respectively, was proposed. Calculation results exhibit that this CPC could achieve a high reflectance of greater than 0.99 in the wavelength ranges of 3–5 μm and 8–14 μm and agreed well with experiment. Further experiments exhibit that the infrared emissivity of the proposed CPC is as low as 0.073 and 0.042 in the wavelength ranges of 3–5 μm and 8–12 μm, respectively. In addition, the proposed CPC can be used to construct infrared-radar stealth-compatible materials due to its high transmittance in radar wave band

  15. Design and realization of one-dimensional double hetero-structure photonic crystals for infrared-radar stealth-compatible materials applications

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhixun; Cheng, Yongzhi, E-mail: cyz0715@126.com; Nie, Yan; Wang, Xian; Gong, Rongzhou, E-mail: rzhgong@mail.hust.edu.cn [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-08-07

    In this paper, a new type one-dimensional (1D) double hetero-structure composite photonic crystal (CPC) for infrared-radar stealth-compatible materials applications was proposed and studied numerically and experimentally. First, based on transfer matrix method of thin-film optical theory, the propagation characteristics of the proposed structure comprising a stack of different alternating micrometer-thick layers of germanium and zinc sulfide were investigated numerically. Calculation results exhibit that this 1D single hetero-structure PC could achieve a flat high reflectivity gradually with increasing the number of the alternating media layers in a single broadband range. Then, based on principles of distributed Bragg reflector micro-cavity, a 1D double hetero-structure CPC comprising four PCs with thickness of 0.797 μm, 0.592 μm, 1.480 μm, and 2.114 μm, respectively, was proposed. Calculation results exhibit that this CPC could achieve a high reflectance of greater than 0.99 in the wavelength ranges of 3–5 μm and 8–14 μm and agreed well with experiment. Further experiments exhibit that the infrared emissivity of the proposed CPC is as low as 0.073 and 0.042 in the wavelength ranges of 3–5 μm and 8–12 μm, respectively. In addition, the proposed CPC can be used to construct infrared-radar stealth-compatible materials due to its high transmittance in radar wave band.

  16. Synthesis, characterization, and anomalous dielectric and conductivity performance of one-dimensional (bdaH)InSe2 (bda = 1,4-butanediamine)

    International Nuclear Information System (INIS)

    Du, Ke-Zhao; Hu, Wan-Biao; Hu, Bing; Guan, Xiang-Feng; Huang, Xiao-Ying

    2011-01-01

    Graphical abstract: Anomalous dielectric and conductivity performance have been observed in the organic-containing indium selenide (bdaH)InSe 2 , which are attributed to the water molecules existing in the crystal boundary rather than phase transition. Highlights: → The title compound is the first example of organic-containing one-dimensional indium selenide. → The anomalous dielectric peak is attributed to water molecules in crystal boundary. → The inorganic and organic components of the title compound are connected via hydrogen bonding to form a supramolecular three-dimensional network. -- Abstract: A new indium selenide, namely (bdaH)InSe 2 (1) (bda = 1,4-butanediamine) has been solvothermally synthesized and structurally characterized. It belongs to the non-centrosymmetric space group Fdd2. Its structure features an infinite one-dimensional anionic chain of [InSe 2 ] n n- with monoprotonated [bdaH] + as charge compensating cation. The organic [bdaH] + cations are joined into a supramolecular one-dimensional chain via N-H...N hydrogen bonding, which further interacts with the inorganic chain via N-H...Se and C-H...Se hydrogen bonding, forming a supramolecular three-dimensional network. Based on such a well-defined structure, the thermal stability, optical, conductivity, and dielectric properties were systematically investigated, showing that dielectric constant, as well as conductivity, had a hump at about 95 o C, which could be attributed to water molecules in the crystal boundary.

  17. Three Cyanide-Bridged One-Dimensional Single Chain Co"I"I"I-Mn"I"I Complexes: Rational Design, Synthesis, Crystal Structures and Magnetic Properties

    International Nuclear Information System (INIS)

    Zhang, Daopeng; Zhao, Zengdian; Wang, Ping; Chen, Xia

    2012-01-01

    Two pyridinecarboxamide dicyanidecobalt(III) building blocks and two mononuclear seven-coordinated macrocycle manganese(II) compounds have been rationally selected to assemble cyanide-bridged heterobimetallic complexes, resulting in three cyanide-bridged Co"I"I"I-Mn"I"I complexes. Single X-ray diffraction analysis show that these complexes {[Mn(L"1)][Co(bpb)]}ClO_4·CH_3OH·0.5H_2O (1), {[Mn(L"2)][Co(bpb)]}ClO_4·0.5CH_3OH (2) and {[Mn(L"1)][Cobpmb]}ClO_4·H_2O (3) (L"1 = 3,6-diazaoctane-1,8-diamine, L"2 = 3,6-dioxaoctano-1,8- diamine: bpb"2"- = 1,2-bis(pyridine-2-carboxamido)benzenate, bpmb"2"- = 1,2-bis(pyridine-2-carboxamido)-4- methyl-benzenate) all present predictable one-dimensional single chain structures. The molecular structures of these one-dimensional complexes consists of alternating units of [Mn(L)]"2"+ (L = L"1 or L"2) and [Co(L')(CN)_2]"- (L' = bpb"2"-, or bpmb"2"-), forming a cyanide-bridged cationic polymeric chain with free ClO_4"- as the balance anion. The coordination geometry of manganese(II) ion in the three one-dimensional complexes is a slightly distorted pentagonal-bipyrimidal with two cyanide nitrogen atoms at the trans positions and N_5 or N_3O_2 coordinating mode at the equatorial plane from ligand L"1 or L"2. Investigation over magnetic properties of these complexes reveals that the very weak magnetic coupling between neighboring Mn(II) ions connected by the diamagnetic dicyanidecobalt(III) building block. A best-fit to the magnetic susceptibility of complex 1 leads to the magnetic coupling constants J = .0.084(3) cm"-"1

  18. Synthesis, characterization, and anomalous dielectric and conductivity performance of one-dimensional (bdaH)InSe{sub 2} (bda = 1,4-butanediamine)

    Energy Technology Data Exchange (ETDEWEB)

    Du, Ke-Zhao; Hu, Wan-Biao [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100049 (China); Hu, Bing; Guan, Xiang-Feng [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Huang, Xiao-Ying, E-mail: xyhuang@fjirsm.ac.cn [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

    2011-11-15

    Graphical abstract: Anomalous dielectric and conductivity performance have been observed in the organic-containing indium selenide (bdaH)InSe{sub 2}, which are attributed to the water molecules existing in the crystal boundary rather than phase transition. Highlights: {yields} The title compound is the first example of organic-containing one-dimensional indium selenide. {yields} The anomalous dielectric peak is attributed to water molecules in crystal boundary. {yields} The inorganic and organic components of the title compound are connected via hydrogen bonding to form a supramolecular three-dimensional network. -- Abstract: A new indium selenide, namely (bdaH)InSe{sub 2} (1) (bda = 1,4-butanediamine) has been solvothermally synthesized and structurally characterized. It belongs to the non-centrosymmetric space group Fdd2. Its structure features an infinite one-dimensional anionic chain of [InSe{sub 2}]{sub n}{sup n-} with monoprotonated [bdaH]{sup +} as charge compensating cation. The organic [bdaH]{sup +} cations are joined into a supramolecular one-dimensional chain via N-H...N hydrogen bonding, which further interacts with the inorganic chain via N-H...Se and C-H...Se hydrogen bonding, forming a supramolecular three-dimensional network. Based on such a well-defined structure, the thermal stability, optical, conductivity, and dielectric properties were systematically investigated, showing that dielectric constant, as well as conductivity, had a hump at about 95 {sup o}C, which could be attributed to water molecules in the crystal boundary.

  19. Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts.

    Science.gov (United States)

    Fu, Shaofang; Zhu, Chengzhou; Song, Junhua; Engelhard, Mark H; Xia, Haibing; Du, Dan; Lin, Yuehe

    2016-12-28

    Rational design and construction of Pt-based porous nanostructures with large mesopores have triggered significant considerations because of their high surface area and more efficient mass transport. Hydrochloric acid-induced kinetically controlled reduction of metal precursors in the presence of soft template F-127 and hard template tellurium nanowires has been successfully demonstrated to construct one-dimensional hierarchical porous PtCu alloy nanostructures with large mesopores. Moreover, the electrochemical experiments demonstrated that the PtCu hierarchically porous nanostructures synthesized under optimized conditions exhibit enhanced electrocatalytic performance for oxygen reduction reaction in acid media.

  20. Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Shaofang; Zhu, Chengzhou; Song, Junhua; Engelhard, Mark H.; Xia, Haibing; Du, Dan; Lin, Yuehe

    2016-12-28

    Rational design and construction of Pt-based porous nanostructures with large mesopores have triggered significant considerations because of their high surface area and more efficient mass transport. Hydrochloric acid-induced kinetic reduction of metal precursors in the presence of soft template F-127 and hard template tellurium nanowires has been successfully demonstrated to construct one-dimensional hierarchical porous PtCu alloy nanostructures with large mesopores. Moreover, the electrochemical experiments demonstrated that the resultant PtCu hierarchically porous nanostructures with optimized composition exhibit enhanced electrocatalytic performance for oxygen reduction reaction.

  1. Facile synthesis and enhanced magnetic, photocatalytic properties of one-dimensional Ag@Fe{sub 3}O{sub 4}-TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Jia, Xiaohua, E-mail: xhjia2003@126.com [School of Environment and Safety Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013 (China); Dai, Rongrong; Lian, Dandan; Han, Song [School of Environment and Safety Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013 (China); Wu, Xiangyang, E-mail: wuxy@ujs.edu.cn [School of Environment and Safety Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013 (China); Song, Haojie [Institute of Polymer Materials, School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2017-01-15

    Highlights: • One-dimensional triple heterostructure Ag@Fe{sub 3}O{sub 4}-TiO{sub 2} was successfully achieved by a facile co-precipitation and chemical-solution-deposition process method. • One-dimensional triple heterostructure Ag@Fe{sub 3}O{sub 4}-TiO{sub 2} exhibited enhanced photocatalytic properties and can be easily recovered by an extemal magnetic field. • The mechanisms for the enhanced photocatalytic effect of the heterostructure were discussed. - Abstract: Fe{sub 3}O{sub 4}-TiO{sub 2} heterostructures were synthesized through co-precipitation method based on TiO{sub 2} nanobelts. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), vibration sample magnetometry (VSM) were used to characterize the heterostructure nanocomposites. The results of XRD proved that the TiO{sub 2} nanobelt was anatase which was the most suitable crystal form for photocatalysis. SEM and TEM analysis indicated that Fe{sub 3}O{sub 4} nanoparticles were adhere to TiO{sub 2} nanobelts which have one-dimensional structure with 100–200 nm in width. The VSM measurements showed that the photocatalyst can be easily recovered by an extemal magnetic field. X-ray photoelectron spectroscopy (XPS) of Ag@Fe{sub 3}O{sub 4}-TiO{sub 2} nanocomposites studies confirm that Ag is in Ag{sup 0} state. Finally, the photodegradation of rhodamine B (RhB) by the obtained magnetic photocatalyst was investigated via UV–vis absorption spectra. The photocatalytic activity of the composites was observed to be lower compared to bare TiO{sub 2} due to the higher degree of recombination reactions after combined with Fe{sub 3}O{sub 4} nanoparticles. After coated the composite of 15% Fe{sub 3}O{sub 4}-TiO{sub 2} with Ag, the new nanocomposite of Ag@Fe{sub 3}O{sub 4}-TiO{sub 2} can be easily recovered after photocatalysis by an extemal magnetic field and showed enhanced photocatalytic activity. The mechanisms for the exhibited enhanced photocatalytic effect of

  2. Sol-hydrothermal synthesis and optical properties of Eu3+, Tb(3+)-codoped one-dimensional strontium germanate full color nano-phosphors.

    Science.gov (United States)

    Lin, Liangwu; Sun, Xinyuan; Jiang, Yao; He, Yuehui

    2013-12-21

    Novel near-UV and blue excited Eu(3+), Tb(3+)-codoped one dimensional strontium germanate full-color nano-phosphors have been successfully synthesized by a simple sol-hydrothermal method. The morphologies, internal structures, chemical constitution and optical properties of the resulting samples were characterized using FE-SEM, TEM, HRTEM, EDS, XRD, FTIR, XPS, PL and PLE spectroscopy and luminescence decay curves. The results suggested that the obtained Eu(3+), Tb(3+)-codoped strontium germanate nanowires are single crystal nanowires with a diameter ranging from 10 to 80 nm, average diameter of around 30 nm and the length ranging from tens to hundreds micrometers. The results of PL and PLE spectra indicated that the Eu(3+), Tb(3+)-codoped single crystal strontium germanate nanowires showed an intensive blue, blue-green, green, orange and red or green, orange and red light emission under excitation at 350-380 nm and 485 nm, respectively, which may attributed to the coexistent Eu(3+), Eu(2+) and Tb(3+) ions, and the defects located in the strontium germanate nanowires. A possible mechanism of energy transfer among the host, Eu(3+) and Tb(3+) ions was proposed. White-emission can be realized in a single-phase strontium germanate nanowire host by codoping with Tb(3+) and Eu(3+) ions. The Eu(3+), Tb(3+)-codoped one-dimensional strontium germanate full-color nano-phosphors have superior stability under electron bombardment. Because of their strong PL intensity, good CIE chromaticity and stability, the novel 1D strontium germanate full-color nano-phosphors have potential applications in W-LEDs.

  3. One-dimensional isothermal multicomponent diffusion-reaction model and its application to methanol synthesis over commercial Cu-based catalyst

    Directory of Open Access Journals (Sweden)

    Lei Kun

    2015-03-01

    Full Text Available The present work was a study on global reaction rate of methanol synthesis. We measured experimentally the global reaction rate in the internal recycle gradientless reactor over catalyst SC309. The diffusion-reaction model of methanol synthesis was suggested. For model we chose the hydrogenation of CO and CO2 as key reaction. CO and CO2 were key components in our model. The internal diffusion effectiveness factors of CO and CO2 in the catalyst were calculated by the numerical integration. A comparison with the experiment showed that all the absolute values of the relative error were less than 10%. The simulation results showed that decreasing reaction temperature and catalyst diameter were conducive to reduce the influence of the internal diffusion on the methanol synthesis.

  4. Controllable one-pot synthesis of various one-dimensional Bi2S3 nanostructures and their enhanced visible-light-driven photocatalytic reduction of Cr(VI)

    International Nuclear Information System (INIS)

    Hu, Enlai; Gao, Xuehui; Etogo, Atangana; Xie, Yunlong; Zhong, Yijun; Hu, Yong

    2014-01-01

    Highlights: • 1D Bi 2 S 3 nanostructures were prepared by a facile ethanol-assisted one-pot reaction. • The size and morphology of the products can be conveniently varied. • The sulfur source plays a crucial role in determining the morphologies of products. • 1D Bi 2 S 3 nanostructures exhibit enhanced photocatalytic reduction of Cr(VI). • Bi 2 S 3 nanowires exhibit the highest photoreduction activity among three samples. - Abstract: One-dimensional (1D) Bi 2 S 3 nanostructures with various morphologies, including nanowires, nanorods, and nanotubes, have been successfully synthesized through a facile ethanol-assisted one-pot reaction. It is found that the size, morphology and structure of the products can be conveniently varied or controlled by simply adjusting the volume ratio of ethanol and water in the reaction system. Further experimental results indicate that sulfur source also plays the other crucial role in determining the product morphology. The synthetic strategy developed in this work is highly efficient in producing 1D Bi 2 S 3 nanostructures with high quality and large quantity. Photocatalysis experiments show the as-prepared 1D Bi 2 S 3 nanostructures possess significantly enhanced photocatalytic reduction of Cr(VI) when exposed to visible light irradiation. Especially, Bi 2 S 3 nanowires exhibit the highest photocatalytic activity and can be used repeatedly after washed with dilute HCl

  5. Myth and One-Dimensionality

    Directory of Open Access Journals (Sweden)

    William Hansen

    2017-12-01

    Full Text Available A striking difference between the folk-narrative genres of legend and folktale is how the human characters respond to supernatural, otherworldly, or uncanny beings such as ghosts, gods, dwarves, giants, trolls, talking animals, witches, and fairies. In legend the human actors respond with fear and awe, whereas in folktale they treat such beings as if they were ordinary and unremarkable. Since folktale humans treat all characters as belonging to a single realm, folklorists have described the world of the folktale as one-dimensional, in contrast to the two-dimensionality of the legend. The present investigation examines dimensionality in the third major genre of folk narrative: myth. Using the Greek and Hebrew myths of primordial paradise as sample narratives, the present essay finds—surprisingly—that the humans in these stories respond to the otherworldly one-dimensionally, as folktale characters do, and suggests an explanation for their behavior that is peculiar to the world of myth.

  6. One dimensional reactor core model

    International Nuclear Information System (INIS)

    Kostadinov, V.; Stritar, A.; Radovo, M.; Mavko, B.

    1984-01-01

    The one dimensional model of neutron dynamic in reactor core was developed. The core was divided in several axial nodes. The one group neutron diffusion equation for each node is solved. Feedback affects of fuel and water temperatures is calculated. The influence of xenon, boron and control rods is included in cross section calculations for each node. The system of equations is solved implicitly. The model is used in basic principle Training Simulator of NPP Krsko. (author)

  7. Solvothermal synthesis and characterisation of new one-dimensional indium and gallium sulphides: [C1N4H26]0.5[InS2] and [C1N4H26]0.5[GaS2

    International Nuclear Information System (INIS)

    Vaqueiro, Paz

    2006-01-01

    Two new main group metal sulphides, [C 1 N 4 H 26 ] 0.5 [InS 2 ] (1) and [C 1 N 4 H 26 ] 0.5 [GaS 2 ] (2) have been prepared solvothermally in the presence of 1,4-bis(3-aminopropyl)piperazine and their crystal structures determined by single-crystal X-ray diffraction. Both compounds are isostructural and crystallise in the monoclinic space group P2 1 /n (Z=4), with a=6.5628(5), b=11.2008(9), c=12.6611(9) A and β=94.410(4) o (wR=0.035) for compound (1) and a=6.1094(5), b=11.2469(9), c=12.7064(10) A and β=94.313(4) o (wR=0.021) for compound (2). The structure of [C 1 N 4 H 26 ] 0.5 [MS 2 ] (M=In,Ga) consists of one-dimensional [MS 2 ] - chains which run parallel to the crystallographic a axis and are separated by diprotonated amine molecules. These materials represent the first example of solvothermally prepared one-dimensional gallium and indium sulphides. -- Graphical abstract: [C 1 N 4 H 26 ] 0.5 [InS 2 ] and [C 1 N 4 H 26 ] 0.5 [GaS 2 ], prepared under solvothermal conditions, consist of one-dimensional [MS 2 ] - chains separated by diprotonated 1,4-bis(3-aminopropyl)piperazine molecules

  8. Accurate treatment of material interface dynamics in the calculation of one-dimensional two-phase flows by the integral method of characteristics

    International Nuclear Information System (INIS)

    Shin, Y.W.; Wiedermann, A.H.

    1984-01-01

    Accurate numerical methods for treating the junction and boundary conditions needed in the transient two-phase flows of a piping network were published earlier by us; the same methods are used to formulate the treatment of the material interface as a moving boundary. The method formulated is used in a computer program to calculate sample problems designed to test the numerical methods as to their ability and the accuracy limits for calculation of the transient two-phase flows in the piping network downstream of a PWR pressurizer. Independent exact analytical solutions for the sample problems are used as the basis of a critical evaluation of the proposed numerical methods. The evaluation revealed that the proposed boundary scheme indeed generates very accurate numerical results. However, in some extreme flow conditions, numerical difficulties were experienced that eventually led to numerical instability. This paper discusses further a special technique to overcome the difficulty

  9. The one-dimensional extended Bose–Hubbard model

    Indian Academy of Sciences (India)

    Unknown

    method to obtain the zero-temperature phase diagram of the one-dimensional, extended ... Progress in this field has been driven by an interplay between ... superconductor-insulator transition in thin films of superconducting materials like bis-.

  10. Bi[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2}){sub x}F (x=1 and 2): New one-dimensional Bi-coordination materials-Reversible hydration and topotactic decomposition to {alpha}-Bi{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Hye Rim [Department of Chemistry Education, Chung-Ang University, Seoul 156-756 (Korea, Republic of); Lee, Dong Woo [Department of Chemistry, Chung-Ang University, Seoul 156-756 (Korea, Republic of); Ok, Kang Min, E-mail: kmok@cau.ac.kr [Department of Chemistry, Chung-Ang University, Seoul 156-756 (Korea, Republic of)

    2012-03-15

    Two one-dimensional bismuth-coordination materials, Bi[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2}){sub x}F (x=1 and 2), have been synthesized by hydrothermal reactions using Bi{sub 2}O{sub 3}, 2,6-NC{sub 5}H{sub 3}(CO{sub 2}H){sub 2}, HF, and water at 180 Degree-Sign C. Structures of the two materials were determined by single-crystal X-ray diffraction. Although they have different crystal structures, both Bi-organic materials shared a common structural motif, a one-dimensional chain structure consisting of Bi{sup 3+} cations and pyridine dicarboxylate linkers. Detailed structural analyses include infrared spectroscopy, thermogravimetric analysis, and reversible hydration reactions for the coordinated water molecules were reported. Also, thermal decomposition of the rod-shaped Bi[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F single crystals at 800 Degree-Sign C led to {alpha}-Bi{sub 2}O{sub 3} that maintained the same morphology of the original crystals. - Graphical abstract: Calcination of the Bi[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F single crystals at 800 Degree-Sign C results in the {alpha}-Bi{sub 2}O{sub 3} rods that maintain the original morphology of the crystals. Highlights: Black-Right-Pointing-Pointer Synthesis of one-dimensional chain Bi-organic frameworks. Black-Right-Pointing-Pointer Reversible hydration reactions of Bi[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F. Black-Right-Pointing-Pointer Topotactic decomposition maintaining the same morphology of the original crystals.

  11. Basic physics of one-dimensional metals

    International Nuclear Information System (INIS)

    Emery, V.J.

    1976-01-01

    Largely nonmathematical qualitative lectures are given on the basic physics of nearly one-dimensional conductors. The main emphasis is placed on the properties of a purely one-dimensional electron gas. The effects of a real system having interchain coupling, impurities, a compressible lattice, lattice distortions and phonon anomalies are discussed

  12. Essentials of inorganic materials synthesis

    CERN Document Server

    Rao, C N R

    2015-01-01

    This compact handbook describes all the important methods of synthesis employed today for synthesizing inorganic materials. Some features: Focuses on modern inorganic materials with applications in nanotechnology, energy materials, and sustainability Synthesis is a crucial component of materials science and technology; this book provides a simple introduction as well as an updated description of methods Written in a very simple style, providing references to the literature to get details of the methods of preparation when required

  13. One-dimensional organic lead halide perovskites with efficient bluish white-light emission

    Science.gov (United States)

    Yuan, Zhao; Zhou, Chenkun; Tian, Yu; Shu, Yu; Messier, Joshua; Wang, Jamie C.; van de Burgt, Lambertus J.; Kountouriotis, Konstantinos; Xin, Yan; Holt, Ethan; Schanze, Kirk; Clark, Ronald; Siegrist, Theo; Ma, Biwu

    2017-01-01

    Organic-inorganic hybrid metal halide perovskites, an emerging class of solution processable photoactive materials, welcome a new member with a one-dimensional structure. Herein we report the synthesis, crystal structure and photophysical properties of one-dimensional organic lead bromide perovskites, C4N2H14PbBr4, in which the edge sharing octahedral lead bromide chains [PbBr4 2-]∞ are surrounded by the organic cations C4N2H14 2+ to form the bulk assembly of core-shell quantum wires. This unique one-dimensional structure enables strong quantum confinement with the formation of self-trapped excited states that give efficient bluish white-light emissions with photoluminescence quantum efficiencies of approximately 20% for the bulk single crystals and 12% for the microscale crystals. This work verifies once again that one-dimensional systems are favourable for exciton self-trapping to produce highly efficient below-gap broadband luminescence, and opens up a new route towards superior light emitters based on bulk quantum materials.

  14. One-Dimensional Czedli-Type Islands

    Science.gov (United States)

    Horvath, Eszter K.; Mader, Attila; Tepavcevic, Andreja

    2011-01-01

    The notion of an island has surfaced in recent algebra and coding theory research. Discrete versions provide interesting combinatorial problems. This paper presents the one-dimensional case with finitely many heights, a topic convenient for student research.

  15. Analytical solution of one dimensional temporally dependent ...

    African Journals Online (AJOL)

    user

    transfer of heat in fluids, flow through porous media, and the spread of ... In present paper, advection-dispersion equation is considered one dimensional longitudinal initially solute free semi- .... free. Thus initial and boundary conditions for eq.

  16. Factorizations of one-dimensional classical systems

    International Nuclear Information System (INIS)

    Kuru, Senguel; Negro, Javier

    2008-01-01

    A class of one-dimensional classical systems is characterized from an algebraic point of view. The Hamiltonians of these systems are factorized in terms of two functions that together with the Hamiltonian itself close a Poisson algebra. These two functions lead directly to two time-dependent integrals of motion from which the phase motions are derived algebraically. The systems so obtained constitute the classical analogues of the well known factorizable one-dimensional quantum mechanical systems

  17. One-dimensional photonic crystal design

    International Nuclear Information System (INIS)

    Mee, Cornelis van der; Contu, Pietro; Pintus, Paolo

    2010-01-01

    In this article we present a method to determine the band spectrum, band gaps, and discrete energy levels, of a one-dimensional photonic crystal with localized impurities. For one-dimensional crystals with piecewise constant refractive indices we develop an algorithm to recover the refractive index distribution from the period map. Finally, we derive the relationship between the period map and the scattering matrix containing the information on the localized modes.

  18. One dimensional benchmark calculations using diffusion theory

    International Nuclear Information System (INIS)

    Ustun, G.; Turgut, M.H.

    1986-01-01

    This is a comparative study by using different one dimensional diffusion codes which are available at our Nuclear Engineering Department. Some modifications have been made in the used codes to fit the problems. One of the codes, DIFFUSE, solves the neutron diffusion equation in slab, cylindrical and spherical geometries by using 'Forward elimination- Backward substitution' technique. DIFFUSE code calculates criticality, critical dimensions and critical material concentrations and adjoint fluxes as well. It is used for the space and energy dependent neutron flux distribution. The whole scattering matrix can be used if desired. Normalisation of the relative flux distributions to the reactor power, plotting of the flux distributions and leakage terms for the other two dimensions have been added. Some modifications also have been made for the code output. Two Benchmark problems have been calculated with the modified version and the results are compared with BBD code which is available at our department and uses same techniques of calculation. Agreements are quite good in results such as k-eff and the flux distributions for the two cases studies. (author)

  19. One-dimensional Gromov minimal filling problem

    International Nuclear Information System (INIS)

    Ivanov, Alexandr O; Tuzhilin, Alexey A

    2012-01-01

    The paper is devoted to a new branch in the theory of one-dimensional variational problems with branching extremals, the investigation of one-dimensional minimal fillings introduced by the authors. On the one hand, this problem is a one-dimensional version of a generalization of Gromov's minimal fillings problem to the case of stratified manifolds. On the other hand, this problem is interesting in itself and also can be considered as a generalization of another classical problem, the Steiner problem on the construction of a shortest network connecting a given set of terminals. Besides the statement of the problem, we discuss several properties of the minimal fillings and state several conjectures. Bibliography: 38 titles.

  20. Absorption in one-dimensional metallic-dielectric photonic crystals

    International Nuclear Information System (INIS)

    Yu Junfei; Shen Yifeng; Liu Xiaohan; Fu Rongtang; Zi Jian; Zhu Zhiqiang

    2004-01-01

    We show theoretically that the absorption of one-dimensional metallic-dielectric photonic crystals can be enhanced considerably over the corresponding constituent metal. By properly choosing the structural and material parameters, the absorption of one-dimensional metallic-dielectric photonic crystals can be enhanced by one order of magnitude in the visible and in the near infrared regions. It is found that the absorptance of such photonic crystals increases with increasing number of periods. Rules on how to obtain a absorption enhancement in a certain frequency range are discussed. (letter to the editor)

  1. Simulation of the diffraction pattern of one dimensional quasicrystal ...

    African Journals Online (AJOL)

    The effects of the variation of atomic spacing ratio of a one dimensional quasicrystal material are investigated. The work involves the use of the solid state simulation code, Laue written by Silsbee and Drager. We are able to observe the general features of the diffraction pattern by a quasicrystal. In addition, it has been found ...

  2. Sounds in one-dimensional superfluid helium

    International Nuclear Information System (INIS)

    Um, C.I.; Kahng, W.H.; Whang, E.H.; Hong, S.K.; Oh, H.G.; George, T.F.

    1989-01-01

    The temperature variations of first-, second-, and third-sound velocity and attenuation coefficients in one-dimensional superfluid helium are evaluated explicitly for very low temperatures and frequencies (ω/sub s/tau 2 , and the ratio of second sound to first sound becomes unity as the temperature decreases to absolute zero

  3. QUASI-ONE DIMENSIONAL CLASSICAL FLUIDS

    Directory of Open Access Journals (Sweden)

    J.K.Percus

    2003-01-01

    Full Text Available We study the equilibrium statistical mechanics of simple fluids in narrow pores. A systematic expansion is made about a one-dimensional limit of this system. It starts with a density functional, constructed from projected densities, which depends upon projected one and two-body potentials. The nature of higher order corrections is discussed.

  4. Remarks for one-dimensional fractional equations

    Directory of Open Access Journals (Sweden)

    Massimiliano Ferrara

    2014-01-01

    Full Text Available In this paper we study a class of one-dimensional Dirichlet boundary value problems involving the Caputo fractional derivatives. The existence of infinitely many solutions for this equations is obtained by exploiting a recent abstract result. Concrete examples of applications are presented.

  5. GITTAM program for numerical simulation of one-dimensional targets TIS. Part 2

    International Nuclear Information System (INIS)

    Arpishkin, Yu.P.; Basko, M.M.; Sokolovskij, M.V.

    1989-01-01

    A finite-difference algorithm for numeric solution of a system of one-dimensional hydrodynamics equation with heat conductivity, radiation diffusion and thermonuclear combustion is considered. The algorithm presented allows one to simulate one-dimensional thermonuclear targets for heavy-ion synthesis (HIS), irradiated with heavy ion beams. A brief description of a complex of GITTAM programs in which finite-difference algorithm for one-dimensional thermonuclear HIS target simulation is used, is given. 5 refs.; 3 figs

  6. Ferroic materials synthesis and applications

    CERN Document Server

    Virk, Hardev Singh

    2015-01-01

    Ferroics is the generic name given to the study of ferromagnets, ferroelectrics, and ferroelastics. The basis of this study is to understand the large changes in physical characteristics that occur over a very narrow temperature range. In recent years, a new class of ferroic materials has been attracting increased interest. These multiferroics exhibit more than one ferroic property simultaneously in a single phase. The present volume: ""Ferroic Materials: Synthesis and Applications"" has ten Chapters, spread over areas as diverse as Magnetic Oxide Nanomaterials, Ferrites Synthesis, Hexaferrite

  7. Realization of Configurable One-Dimensional Reflectarray

    Science.gov (United States)

    2017-08-31

    experiments show strong signatures of beam steering that are dependent upon graphene doping. This seed grant has allowed our team to establish the essential...based, one-dimensional reflectarrays. Several immediate improvements to the device design and process flow are essential to suppress specular...beam steering that are dependent upon graphene doping. This seed grant has allowed our team to establish the essential operating procedures (i.e

  8. One-dimensional plasma simulation studies

    International Nuclear Information System (INIS)

    Friberg, Ari; Virtamo, Jorma

    1976-01-01

    Some basic plasma phenomena are studied by a one-dimensional electrostatic simulation code. A brief description of the code and its application to a test problem is given. The experiments carried out include Landau damping of an excited wave, particle retardation by smoothed field and beam-plasma instability. In each case, the set-up of the experiment is described and the results are compared with theoretical predictions. In the theoretical discussions, the oscillatory behaviour found in the Landau damping experiment is explained, an explicit formula for the particle retardation rate is derived and a rudimentary picture of the beam-plasma instability in terms of quasilinear theory is given. (author)

  9. Solitons in one-dimensional antiferromagnetic chains

    International Nuclear Information System (INIS)

    Pires, A.S.T.; Talim, S.L.; Costa, B.V.

    1989-01-01

    We study the quantum-statistical mechanics, at low temperatures, of a one-dimensional antiferromagnetic Heisenberg model with two anisotropies. In the weak-coupling limit we determine the temperature dependences of the soliton energy and the soliton density. We have found that the leading correction to the sine-Gordon (SG) expression for the soliton density and the quantum soliton energy comes from the out-of-plane magnon mode, not present in the pure SG model. We also show that when an external magnetic field is applied, the chain supports a new type of kink, where the sublattices rotate in opposite directions

  10. One-dimensional hypersonic phononic crystals.

    Science.gov (United States)

    Gomopoulos, N; Maschke, D; Koh, C Y; Thomas, E L; Tremel, W; Butt, H-J; Fytas, G

    2010-03-10

    We report experimental observation of a normal incidence phononic band gap in one-dimensional periodic (SiO(2)/poly(methyl methacrylate)) multilayer film at gigahertz frequencies using Brillouin spectroscopy. The band gap to midgap ratio of 0.30 occurs for elastic wave propagation along the periodicity direction, whereas for inplane propagation the system displays an effective medium behavior. The phononic properties are well captured by numerical simulations. The porosity in the silica layers presents a structural scaffold for the introduction of secondary active media for potential coupling between phonons and other excitations, such as photons and electrons.

  11. Quasi-one-dimensional intermittent flux behavior in superconducting films

    OpenAIRE

    Qviller, A. J.; Yurchenko, V. V.; Galperin, Y. M.; Vestgården, J. I.; Mozhaev, Peter; Hansen, Jørn Bindslev; Johansen, T. H.

    2012-01-01

    Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa_{2}Cu_{3}O_{7-δ} deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. As the applied field is gradually increased, magneto-optical imaging reveals that flux penetrates via numerous quasi-one-dimensional jumps. The distribution of flux avalanche sizes follows a ...

  12. Specificities of one-dimensional dissipative magnetohydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Popov, P. V., E-mail: popov.pv@mipt.ru [National Research Center Kurchatov Institute (Russian Federation)

    2016-11-15

    One-dimensional dynamics of a plane slab of cold (β ≪ 1) isothermal plasma accelerated by a magnetic field is studied in terms of the MHD equations with a finite constant conductivity. The passage to the limit β → 0 is analyzed in detail. It is shown that, at β = 0, the character of the solution depends substantially on the boundary condition for the electric field at the inner plasma boundary. The relationship between the boundary condition for the pressure at β > 0 and the conditions for the electric field at β = 0 is found. The stability of the solution against one-dimensional longitudinal perturbations is analyzed. It is shown that, in the limit β → 0, the stationary solution is unstable if the time during which the acoustic wave propagates across the slab is longer than the time of magnetic field diffusion. The growth rate and threshold of instability are determined, and results of numerical simulation of its nonlinear stage are presented.

  13. One-Dimensional Modelling of Internal Ballistics

    Science.gov (United States)

    Monreal-González, G.; Otón-Martínez, R. A.; Velasco, F. J. S.; García-Cascáles, J. R.; Ramírez-Fernández, F. J.

    2017-10-01

    A one-dimensional model is introduced in this paper for problems of internal ballistics involving solid propellant combustion. First, the work presents the physical approach and equations adopted. Closure relationships accounting for the physical phenomena taking place during combustion (interfacial friction, interfacial heat transfer, combustion) are deeply discussed. Secondly, the numerical method proposed is presented. Finally, numerical results provided by this code (UXGun) are compared with results of experimental tests and with the outcome from a well-known zero-dimensional code. The model provides successful results in firing tests of artillery guns, predicting with good accuracy the maximum pressure in the chamber and muzzle velocity what highlights its capabilities as prediction/design tool for internal ballistics.

  14. Stability model for one-dimensional FRCs

    International Nuclear Information System (INIS)

    Schwarzmeier, J.L.; Hewitt, T.G.; Lewis, H.R.; Seyler, C.E.; Symon, K.R.

    1982-01-01

    The subject of transport near the separatrix in FRC devices is important for determining the performance to be expected from an FRC reactor or from FRC experiments. A computer code was constructed for studying the micro-stability properties of FRCs near the separatrix as a first step in obtaining quasilinear transport coefficients that can be used in a transport code. We consider collisionless ions and electrons, without an expansion in powers of a parameter, like the electron or ion gyroradius, and we approximate the equilibrium with an infinitely long axially and translationally symmetric equilibrium. Thus, in our equilibria, there are only an axial magnetic field and a radial electric field. Our equilibria are collisionless, two-species, diffuse-profile, one-dimensional, theta-pinch equilibria. We allow the possibility that there be a magnetic field null in order to be able to model FRC devices more realistically

  15. One-Dimensional Photonic Crystal Superprisms

    Science.gov (United States)

    Ting, David

    2005-01-01

    Theoretical calculations indicate that it should be possible for one-dimensional (1D) photonic crystals (see figure) to exhibit giant dispersions known as the superprism effect. Previously, three-dimensional (3D) photonic crystal superprisms have demonstrated strong wavelength dispersion - about 500 times that of conventional prisms and diffraction gratings. Unlike diffraction gratings, superprisms do not exhibit zero-order transmission or higher-order diffraction, thereby eliminating cross-talk problems. However, the fabrication of these 3D photonic crystals requires complex electron-beam substrate patterning and multilayer thin-film sputtering processes. The proposed 1D superprism is much simpler in structural complexity and, therefore, easier to design and fabricate. Like their 3D counterparts, the 1D superprisms can exhibit giant dispersions over small spectral bands that can be tailored by judicious structure design and tuned by varying incident beam direction. Potential applications include miniature gas-sensing devices.

  16. One dimensional systems with singular perturbations

    International Nuclear Information System (INIS)

    Alvarez, J J; Gadella, M; Nieto, L M; Glasser, L M; Lara, L P

    2011-01-01

    This paper discusses some one dimensional quantum models with singular perturbations. Eventually, a mass discontinuity is added at the points that support the singular perturbations. The simplest model includes an attractive singular potential with a mass jump both located at the origin. We study the form of the only bound state. Another model exhibits a hard core at the origin plus one or more repulsive deltas with mass jumps at the points supporting these deltas. We study the location and the multiplicity of these resonances for the case of one or two deltas and settle the basis for a generalization. Finally, we consider the harmonic oscillator and the infinite square well plus a singular potential at the origin. We see how the energy of bound states is affected by the singular perturbation.

  17. Cohesive motion in one-dimensional flocking

    International Nuclear Information System (INIS)

    Dossetti, V

    2012-01-01

    A one-dimensional rule-based model for flocking, which combines velocity alignment and long-range centering interactions, is presented and studied. The induced cohesion in the collective motion of the self-propelled agents leads to unique group behavior that contrasts with previous studies. Our results show that the largest cluster of particles, in the condensed states, develops a mean velocity slower than the preferred one in the absence of noise. For strong noise, the system also develops a non-vanishing mean velocity, alternating its direction of motion stochastically. This allows us to address the directional switching phenomenon. The effects of different sources of stochasticity on the system are also discussed. (paper)

  18. Quasi-One-Dimensional Intermittent Flux Behavior in Superconducting Films

    Directory of Open Access Journals (Sweden)

    A. J. Qviller

    2012-01-01

    Full Text Available Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa_{2}Cu_{3}O_{7-δ} deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. As the applied field is gradually increased, magneto-optical imaging reveals that flux penetrates via numerous quasi-one-dimensional jumps. The distribution of flux avalanche sizes follows a power law, and data collapse is obtained by finite-size scaling, with the depth of the flux front used as crossover length. The intermittent behavior shows no threshold value in the applied field, in contrast to conventional flux jumping. The results strongly suggest that the quasi-one-dimensional flux jumps are of a different nature than the thermomagnetic dendritic (branching avalanches that are commonly found in superconducting films.

  19. Solitons in one-dimensional charge density wave systems

    International Nuclear Information System (INIS)

    Su, W.P.

    1981-01-01

    Theoretical research on one dimensional charge density wave systems is outlined. A simple coupled electron-photon Hamiltonian is studied including a Green's function approach, molecular dynamics, and Monte Carlo path integral method. As in superconductivity, the nonperturbative nature of the system makes the physical ground states and low energy excitations drastically different from the bare electrons and phonons. Solitons carry quantum numbers which are entirely different from those of the bare electrons and holes. The fractional charge character of the solitons is an example of this fact. Solitons are conveniently generated by doping material with donors or acceptors or by photon absorption. Most predictions of the theory are in qualitative agreement with experiments. The one dimensional charge density wave system has potential technological importance and a possible role in uncovering phenomena which might have implications in relativistic field theory and elementary particle physics

  20. Structural studies of precursor and partially oxidized conducting complexes. 19. Synthesis and crystal structure of Cs2[Pt(CN)4]Cl/sub 0.30, the first anhydrous one-dimensional tetracyanoplatinate chloride complex

    International Nuclear Information System (INIS)

    Brown, R.K.; Williams, J.M.

    1978-01-01

    The preparation and single-crystal x-ray structural characterization of a new, partially oxidized tetracyanoplatinate (POTCP), Cs 2 [Pt(CN) 4 ]Cl/sub 0.30/, CsCP(Cl), has been carried out. This one-dimensional conducting salt crystallizes with four formula units in the tetragonal unit cell I4/mcm, with cell constants a = 13.176 (2) A, c = 5.718 (1) A, and V = 992.7 A 3 . A total of 3112 observed data were averaged to yield 427 independent reflections. The structure was solved by standard heavy-atom methods and was refined by full-matrix least squares to a final R(F 0 2 ) = 0.045 and R/sub w/(F 0 2 ) = 0.059. Pertinent structural features include perfectly linear chains of Pt atoms with Pt-Pt separations crystallographically constrained to a value of (c/2) = 2.859 (2) A and interchain Pt-Pt distances of 9.317 A. Separations between the Cs + and Cl - ions are significantly shorter than the sum of the ionic radii. A discussion of these unusually short interionic distances and the absence of hydration as determined from the structural study and themogravimetric analyses is given. 2 figures, 2 tables

  1. Lateral shift in one-dimensional quasiperiodic chiral photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    Da, Jian, E-mail: dajian521@sina.com [Department of Information Engineering, Huaian Senior Vocational and Technical School, Feiyao road, Huaian 223005, Jiangsu Province (China); Mo, Qi, E-mail: moqiyueyang@163.com [School of Software, Yunnan University, Cuihu Bai Road, Kunming City, Yunnan Province 650091 (China); Cheng, Yaokun [Department of Information Engineering, Huaian Senior Vocational and Technical School, Feiyao road, Huaian 223005, Jiangsu Province (China); Liu, Taixiang [Taishan Vocational College of Nursing, Shandong Province 271000 (China)

    2015-02-01

    We investigate the lateral shift of a one-dimensional quasiperiodic photonic crystal consisting of chiral and conventional dielectric materials. The effect of structural irregularity on lateral shift is evaluated by stationary-phase approach. Our results show that the lateral shift can be modulated by varying the structural irregularity in quasiperiodic structure. Besides, the position of peak in lateral shift spectrum stays sensitive to the chiral factor of chiral materials. In comparison with that of periodic structure, quasiperiodic structure provides an extra degree of freedom to manipulate the lateral shift.

  2. Few quantum particles on one dimensional lattices

    International Nuclear Information System (INIS)

    Valiente Cifuentes, Manuel

    2010-01-01

    There is currently a great interest in the physics of degenerate quantum gases and low-energy few-body scattering due to the recent experimental advances in manipulation of ultracold atoms by light. In particular, almost perfect periodic potentials, called optical lattices, can be generated. The lattice spacing is fixed by the wavelength of the laser field employed and the angle betwen the pair of laser beams; the lattice depth, defining the magnitude of the different band gaps, is tunable within a large interval of values. This flexibility permits the exploration of different regimes, ranging from the ''free-electron'' picture, modified by the effective mass for shallow optical lattices, to the tight-binding regime of a very deep periodic potential. In the latter case, effective single-band theories, widely used in condensed matter physics, can be implemented with unprecedent accuracy. The tunability of the lattice depth is nowadays complemented by the use of magnetic Feshbach resonances which, at very low temperatures, can vary the relevant atom-atom scattering properties at will. Moreover, optical lattices loaded with gases of effectively reduced dimensionality are experimentally accessible. This is especially important for one spatial dimension, since most of the exactly solvable models in many-body quantum mechanics deal with particles on a line; therefore, experiments with one-dimensional gases serve as a testing ground for many old and new theories which were regarded as purely academic not so long ago. The physics of few quantum particles on a one-dimensional lattice is the topic of this thesis. Most of the results are obtained in the tight-binding approximation, which is amenable to exact numerical or analytical treatment. For the two-body problem, theoretical methods for calculating the stationary scattering and bound states are developed. These are used to obtain, in closed form, the two-particle solutions of both the Hubbard and extended Hubbard models

  3. Few quantum particles on one dimensional lattices

    Energy Technology Data Exchange (ETDEWEB)

    Valiente Cifuentes, Manuel

    2010-06-18

    There is currently a great interest in the physics of degenerate quantum gases and low-energy few-body scattering due to the recent experimental advances in manipulation of ultracold atoms by light. In particular, almost perfect periodic potentials, called optical lattices, can be generated. The lattice spacing is fixed by the wavelength of the laser field employed and the angle betwen the pair of laser beams; the lattice depth, defining the magnitude of the different band gaps, is tunable within a large interval of values. This flexibility permits the exploration of different regimes, ranging from the ''free-electron'' picture, modified by the effective mass for shallow optical lattices, to the tight-binding regime of a very deep periodic potential. In the latter case, effective single-band theories, widely used in condensed matter physics, can be implemented with unprecedent accuracy. The tunability of the lattice depth is nowadays complemented by the use of magnetic Feshbach resonances which, at very low temperatures, can vary the relevant atom-atom scattering properties at will. Moreover, optical lattices loaded with gases of effectively reduced dimensionality are experimentally accessible. This is especially important for one spatial dimension, since most of the exactly solvable models in many-body quantum mechanics deal with particles on a line; therefore, experiments with one-dimensional gases serve as a testing ground for many old and new theories which were regarded as purely academic not so long ago. The physics of few quantum particles on a one-dimensional lattice is the topic of this thesis. Most of the results are obtained in the tight-binding approximation, which is amenable to exact numerical or analytical treatment. For the two-body problem, theoretical methods for calculating the stationary scattering and bound states are developed. These are used to obtain, in closed form, the two-particle solutions of both the Hubbard and

  4. One-dimensional model of inertial pumping

    Science.gov (United States)

    Kornilovitch, Pavel E.; Govyadinov, Alexander N.; Markel, David P.; Torniainen, Erik D.

    2013-02-01

    A one-dimensional model of inertial pumping is introduced and solved. The pump is driven by a high-pressure vapor bubble generated by a microheater positioned asymmetrically in a microchannel. The bubble is approximated as a short-term impulse delivered to the two fluidic columns inside the channel. Fluid dynamics is described by a Newton-like equation with a variable mass, but without the mass derivative term. Because of smaller inertia, the short column refills the channel faster and accumulates a larger mechanical momentum. After bubble collapse the total fluid momentum is nonzero, resulting in a net flow. Two different versions of the model are analyzed in detail, analytically and numerically. In the symmetrical model, the pressure at the channel-reservoir connection plane is assumed constant, whereas in the asymmetrical model it is reduced by a Bernoulli term. For low and intermediate vapor bubble pressures, both models predict the existence of an optimal microheater location. The predicted net flow in the asymmetrical model is smaller by a factor of about 2. For unphysically large vapor pressures, the asymmetrical model predicts saturation of the effect, while in the symmetrical model net flow increases indefinitely. Pumping is reduced by nonzero viscosity, but to a different degree depending on the microheater location.

  5. Diffusiophoresis in one-dimensional solute gradients

    Energy Technology Data Exchange (ETDEWEB)

    Ault, Jesse T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Warren, Patrick B. [Unilever R& D Port Sunlight, Bebington (United Kingdom); Shin, Sangwoo [Univ. of Hawaii at Manoa, Honolulu, HI (United States); Stone, Howard A. [Princeton Univ., Princeton, NJ (United States)

    2017-11-06

    Here, the diffusiophoretic motion of suspended colloidal particles under one-dimensional solute gradients is solved using numerical and analytical techniques. Similarity solutions are developed for the injection and withdrawal dynamics of particles into semi-infinite pores. Furthermore, a method of characteristics formulation of the diffusion-free particle transport model is presented and integrated to realize particle trajectories. Analytical solutions are presented for the limit of small particle diffusiophoretic mobility Γp relative to the solute diffusivity Ds for particle motions in both semi-infinite and finite domains. Results confirm the build up of local maxima and minima in the propagating particle front dynamics. The method of characteristics is shown to successfully predict particle motions and the position of the particle front, although it fails to accurately predict suspended particle concentrations in the vicinity of sharp gradients, such as at the particle front peak seen in some injection cases, where particle diffusion inevitably plays an important role. Results inform the design of applications in which the use of applied solute gradients can greatly enhance particle injection into and withdrawal from pores.

  6. Diffusiophoresis in one-dimensional solute gradients

    International Nuclear Information System (INIS)

    Ault, Jesse T.; Warren, Patrick B.; Shin, Sangwoo; Stone, Howard A.

    2017-01-01

    Here, the diffusiophoretic motion of suspended colloidal particles under one-dimensional solute gradients is solved using numerical and analytical techniques. Similarity solutions are developed for the injection and withdrawal dynamics of particles into semi-infinite pores. Furthermore, a method of characteristics formulation of the diffusion-free particle transport model is presented and integrated to realize particle trajectories. Analytical solutions are presented for the limit of small particle diffusiophoretic mobility Γ p relative to the solute diffusivity D s for particle motions in both semi-infinite and finite domains. Results confirm the build up of local maxima and minima in the propagating particle front dynamics. The method of characteristics is shown to successfully predict particle motions and the position of the particle front, although it fails to accurately predict suspended particle concentrations in the vicinity of sharp gradients, such as at the particle front peak seen in some injection cases, where particle diffusion inevitably plays an important role. Results inform the design of applications in which the use of applied solute gradients can greatly enhance particle injection into and withdrawal from pores.

  7. One-Dimensional Time to Explosion (Thermal Sensitivity) of ANPZ

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hust, G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McClelland, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Gresshoff, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2014-11-12

    Incidents caused by fire and combat operations can heat energetic materials that may lead to thermal explosion and result in structural damage and casualty. Some explosives may thermally explode at fairly low temperatures (< 100 C) and the violence from thermal explosion may cause a significant damage. Thus it is important to understand the response of energetic materials to thermal insults. The One Dimensional Time to Explosion (ODTX) system at the Lawrence Livermore National Laboratory has been used for decades to measure times to explosion, threshold thermal explosion temperature, and determine kinetic parameters of energetic materials. Samples of different configurations (pressed part, powder, paste, and liquid) can be tested in the system. The ODTX testing can also provide useful data for assessing the thermal explosion violence of energetic materials. This report summarizes the recent ODTX experimental data and modeling results for 2,6-diamino-3,5-dintropyrazine (ANPZ).

  8. One-dimensional low spatial frequency LIPSS with rotating orientation on fused silica

    Energy Technology Data Exchange (ETDEWEB)

    Schwarz, Simon, E-mail: simon.schwarz@h-ab.de; Rung, Stefan; Hellmann, Ralf

    2017-07-31

    Highlights: • Generation of one-dimensional low spatial frequency LIPSS on transparent material. • Varying the angle of incidence results in a rotation of the one-dimensional LSFL. • Rotation angle of LSFL decreases with increasing the applied fluence. • Orientation of the LSFL is mirror-inverted when reversing the scanning direction. - Abstract: We report on the generation of one-dimensional low spatial frequency LIPSS on transparent material. The influence of the applied laser fluence and angle of incidence on the periodicity, orientation and quality of the one-dimensional low spatial frequency LIPSS is investigated, facilitating the generation of highly uniform LIPSS alongside a line. Most strikingly, however, we observe a previously unreported effect of a pronounced rotation of the one-dimensional low spatial frequency LIPSS for varying angle of incidence upon inclined laser irradiation.

  9. One-Dimensional TiO2 Nanostructures as Photoanodes for Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Jie Qu

    2013-01-01

    Full Text Available Titanium dioxide (TiO2 is star materials due to its remarkable optical and electronic properties, resulting in various applications, especially in the fields of dye-sensitized solar cells (DSSCs. Photoanode is the most important part of the DSSCs, which help to adsorb dye molecules and transport the injected electrons. The size, structure, and morphology of TiO2 photoanode have been found to show significant influence on the photovoltaic performance of DSSCs. In this paper, we briefly summarize the synthesis and properties of one-dimensional (1D TiO2 nanomaterials (bare 1D TiO2 nanomaterial and 1D hierarchical TiO2 and their photovoltaic performance in DSSCs.

  10. MARCUSE’S ONE-DIMENSIONAL SOCIETY IN ONE-DIMENSIONAL MAN

    Directory of Open Access Journals (Sweden)

    MILOS RASTOVIC

    2013-05-01

    Full Text Available Nowadays, Marcuse’s main book One-Dimensional Man is almost obsolete, or rather passé. However, there are reasons to renew the reading of his book because of “the crisis of capitalism,” and the prevailing framework of technological domination in “advanced industrial society” in which we live today. “The new forms of control” in “advanced industrial societies” have replaced traditional methods of political and economic administration. The dominant structural element of “advanced industrial society” has become a technical and scientific apparatus of production and distribution of technology and administrative practice based on application of impersonal rules by a hierarchy of associating authorities. Technology has been liberated from the control of particular interests, and it has become the factor of domination in itself. Technological domination stems from the technical development of the productive apparatus that reproduces its ability into all spheres of social life (cultural, political, and economic. Based upon this consideration, in this paper, I will examine Marcuse’s ideas of “the new forms of control,” which creates a one–dimensional society. Marcuse’s fundamental thesis in One-Dimensional Man is that technological rationality is the most dominant factor in an “advanced industrial society,” which unites two earlier opposing forces of dissent: the bourgeoisie and the proletariat.

  11. Qualities of Wigner function and its applications to one-dimensional infinite potential and one-dimensional harmonic oscillator

    International Nuclear Information System (INIS)

    Xu Hao; Shi Tianjun

    2011-01-01

    In this article,the qualities of Wigner function and the corresponding stationary perturbation theory are introduced and applied to one-dimensional infinite potential well and one-dimensional harmonic oscillator, and then the particular Wigner function of one-dimensional infinite potential well is specified and a special constriction effect in its pure state Wigner function is discovered, to which,simultaneously, a detailed and reasonable explanation is elaborated from the perspective of uncertainty principle. Ultimately, the amendment of Wigner function and energy of one-dimensional infinite potential well and one-dimensional harmonic oscillator under perturbation are calculated according to stationary phase space perturbation theory. (authors)

  12. An Angular Leakage Correction for Modeling a Hemisphere, Using One-Dimensional Spherical Coordinates

    International Nuclear Information System (INIS)

    Schwinkendorf, K.N.; Eberle, C.S.

    2003-01-01

    A radially dependent, angular leakage correction was applied to a one-dimensional, multigroup neutron diffusion theory computer code to accurately model hemispherical geometry. This method allows the analyst to model hemispherical geometry, important in nuclear criticality safety analyses, with one-dimensional computer codes, which execute very quickly. Rapid turnaround times for scoping studies thus may be realized. This method uses an approach analogous to an axial leakage correction in a one-dimensional cylinder calculation. The two-dimensional Laplace operator was preserved in spherical geometry using a leakage correction proportional to 1/r 2 , which was folded into the one-dimensional spherical calculation on a mesh-by-mesh basis. Hemispherical geometry is of interest to criticality safety because of its similarity to piles of spilled fissile material and accumulations of fissile material in process containers. A hemisphere also provides a more realistic calculational model for spilled fissile material than does a sphere

  13. One-dimensional rigid film acoustic metamaterials

    Science.gov (United States)

    Ma, Fuyin; Wu, Jiu Hui; Huang, Meng

    2015-11-01

    We have designed a 1D film-type acoustic metamaterial structure consisting of several polymer films directly stacked on each other. It is experimentally revealed that the mass density law can be broken by such structures in the low frequency range. By comparing the sound transmission loss (STL) curves of structures with different numbers of cycles, materials and incident sound directions, several physical properties of the 1D film-type acoustic metamaterial are revealed, which consist of cyclical effects, surface effects and orientation effects. It is suggested that the excellent low frequency sound insulation capacity is influenced by both the cycle number and the stiffness of the film surface. Meanwhile, the surface effect plays a dominant role among these physical properties. Due to the surface acoustic property, for structures with a particular combination form, the STL dominated by the cyclical effects may reach saturation with increasing number of construction periods. Moreover, in some cases, the sound insulation ability is diverse for different sound incidence directions. This kind of 1D film-type periodic structure with these special physical properties provides a new concept for the regulation of sound waves.

  14. One-dimensional rigid film acoustic metamaterials

    International Nuclear Information System (INIS)

    Ma, Fuyin; Wu, Jiu Hui; Huang, Meng

    2015-01-01

    We have designed a 1D film-type acoustic metamaterial structure consisting of several polymer films directly stacked on each other. It is experimentally revealed that the mass density law can be broken by such structures in the low frequency range. By comparing the sound transmission loss (STL) curves of structures with different numbers of cycles, materials and incident sound directions, several physical properties of the 1D film-type acoustic metamaterial are revealed, which consist of cyclical effects, surface effects and orientation effects. It is suggested that the excellent low frequency sound insulation capacity is influenced by both the cycle number and the stiffness of the film surface. Meanwhile, the surface effect plays a dominant role among these physical properties. Due to the surface acoustic property, for structures with a particular combination form, the STL dominated by the cyclical effects may reach saturation with increasing number of construction periods. Moreover, in some cases, the sound insulation ability is diverse for different sound incidence directions. This kind of 1D film-type periodic structure with these special physical properties provides a new concept for the regulation of sound waves. (paper)

  15. Lateral shifting in one dimensional chiral photonic crystal

    International Nuclear Information System (INIS)

    You Yuan; Chen Changyuan

    2012-01-01

    We report the lateral shifts of the transmitted waves in a one dimensional chiral photonic crystal by using the stationary-phase approach. It is revealed that two kinds of lateral shifts are observed due to the existence of cross coupling in chiral materials, which is different from what has been observed in previous non-chiral photonic crystals. Unlike the chiral slab, the positions of lateral shift peaks are closely related to the band edges of band gap characteristics of periodic structure and lateral shifts can be positive as well as negative. Besides, the lateral shifts show a strong dependence on the chiral factor, which varies the lateral shift peaks in both magnitudes and positions. These features are desirable for future device applications.

  16. Magnons in one-dimensional k-component Fibonacci structures

    Energy Technology Data Exchange (ETDEWEB)

    Costa, C. H., E-mail: carloshocosta@hotmail.com [Departamento de Física Teórica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Escola de Ciências e Tecnologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Vasconcelos, M. S. [Escola de Ciências e Tecnologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil)

    2014-05-07

    We have studied the magnon transmission through of one-dimensional magnonic k-component Fibonacci structures, where k different materials are arranged in accordance with the following substitution rule: S{sub n}{sup (k)}=S{sub n−1}{sup (k)}S{sub n−k}{sup (k)} (n≥k=0,1,2,…), where S{sub n}{sup (k)} is the nth stage of the sequence. The calculations were carried out in exchange dominated regime within the framework of the Heisenberg model and taking into account the RPA approximation. We have considered multilayers composed of simple cubic spin-S Heisenberg ferromagnets, and, by using the powerful transfer-matrix method, the spin wave transmission is obtained. It is demonstrated that the transmission coefficient has a rich and interesting magnonic pass- and stop-bands structures, which depends on the frequency of magnons and the k values.

  17. One-dimensional thermodynamical model for poling of ferroelectric ceramics

    International Nuclear Information System (INIS)

    Bassiouny, E.

    1990-11-01

    In this work, we use a model developed to deduce a one-dimensional model for the description of the poling of ferroelectric ceramics. This is built within the scheme of the thermodynamical theory of internal variables. The model produces both plastic and electric hysteresis effects in the form of ''plasticity'', i.e., rate-independent evolution equations for the plastic strain, and the residual electric polarization and both mechanical and electric hardenings. The influence of stresses on ferroelectric hysteresis loops through piezoelectricity and electrostriction is a natural outcome of this model. Some simple experimental methods for the determination of the material coefficients of the considered ceramics are suggested. (author). 21 refs, 3 figs

  18. NMR relaxation rate in quasi one-dimensional antiferromagnets

    Science.gov (United States)

    Capponi, Sylvain; Dupont, Maxime; Laflorencie, Nicolas; Sengupta, Pinaki; Shao, Hui; Sandvik, Anders W.

    We compare results of different numerical approaches to compute the NMR relaxation rate 1 /T1 in quasi one-dimensional (1d) antiferromagnets. In the purely 1d regime, recent numerical simulations using DMRG have provided the full crossover behavior from classical regime at high temperature to universal Tomonaga-Luttinger liquid at low-energy (in the gapless case) or activated behavior (in the gapped case). For quasi 1d models, we can use mean-field approaches to reduce the problem to a 1d one that can be studied using DMRG. But in some cases, we can also simulate the full microscopic model using quantum Monte-Carlo techniques. This allows to compute dynamical correlations in imaginary time and we will discuss recent advances to perform stochastic analytic continuation to get real frequency spectra. Finally, we connect our results to experiments on various quasi 1d materials.

  19. Lateral shifting in one dimensional chiral photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    You Yuan, E-mail: yctcyouyuan@163.com [School of Physics and Electronics, Yancheng Teachers University, Yancheng, 224002 Jiangsu (China); Chen Changyuan [School of Physics and Electronics, Yancheng Teachers University, Yancheng, 224002 Jiangsu (China)

    2012-07-01

    We report the lateral shifts of the transmitted waves in a one dimensional chiral photonic crystal by using the stationary-phase approach. It is revealed that two kinds of lateral shifts are observed due to the existence of cross coupling in chiral materials, which is different from what has been observed in previous non-chiral photonic crystals. Unlike the chiral slab, the positions of lateral shift peaks are closely related to the band edges of band gap characteristics of periodic structure and lateral shifts can be positive as well as negative. Besides, the lateral shifts show a strong dependence on the chiral factor, which varies the lateral shift peaks in both magnitudes and positions. These features are desirable for future device applications.

  20. Analytical models of optical response in one-dimensional semiconductors

    International Nuclear Information System (INIS)

    Pedersen, Thomas Garm

    2015-01-01

    The quantum mechanical description of the optical properties of crystalline materials typically requires extensive numerical computation. Including excitonic and non-perturbative field effects adds to the complexity. In one dimension, however, the analysis simplifies and optical spectra can be computed exactly. In this paper, we apply the Wannier exciton formalism to derive analytical expressions for the optical response in four cases of increasing complexity. Thus, we start from free carriers and, in turn, switch on electrostatic fields and electron–hole attraction and, finally, analyze the combined influence of these effects. In addition, the optical response of impurity-localized excitons is discussed. - Highlights: • Optical response of one-dimensional semiconductors including excitons. • Analytical model of excitonic Franz–Keldysh effect. • Computation of optical response of impurity-localized excitons

  1. Synthesis and magnetic properties of one-dimensional metal ...

    Indian Academy of Sciences (India)

    Unknown

    metrically by EDTA titration after removing organic ... acid. The compounds gave satisfactory C and H values. (table 1). The water content was determined by heating a known .... [CuNi(OX)2(H2O)4] shows a base peak at m/z = 205 due.

  2. Synthesis and processing of nanostructured materials

    International Nuclear Information System (INIS)

    Siegel, R.W.

    1992-12-01

    Significant and growing interest is being exhibited in the novel and enhanced properties of nanostructured materials. These materials, with their constituent phase or grain structures modulated on a length scale less than 100 nm, are artificially synthesized by a wide variety of physical, chemical, and mechanical methods. In this NATO Advanced Study Institute, where mechanical behavior is emphasized, nanostructured materials with modulation dimensionalities from one (multilayers) to three (nanophase materials) are mainly considered. No attempt is made in this review to cover in detail all of the diverse methods available for the synthesis of nanostructured materials. Rather, the basic principles involved in their synthesis are discussed in terms of the special properties sought using examples of particular synthesis and processing methodologies. Some examples of the property changes that can result from one of these methods, cluster assembly of nanophase materials, are presented

  3. Study of one dimensional magnetic system via field theory

    International Nuclear Information System (INIS)

    Talim, S.L.

    1988-04-01

    We present a study of one-dimensional magnetic system using field theory methods. We studied the discreteness effects in a classical anisotropic one dimensional antiferromagnet in an external magnetic field. It is shown that for TMMC, at the temperatures and magnetic fields where most experiments have been done, the corrections are small and can be neglected. (author)

  4. GITTAM program for numerical simulation of one-dimensional targets TIS. Part 3

    International Nuclear Information System (INIS)

    Basko, M.M.; Sokolovskij, M.V.

    1989-01-01

    Results of testing calculations according to GITTAM program, developed for numeric simulation of one-dimensional thermonuclear targets of heavy-ion synthesis are presented. Finite-difference method for solving a system of one-dimensional hydrodynamics equations with heat conductivity, radiation diffusion and thermonuclear combustion is used in the GITTAM program. In the tests presented, based on simple automodel solutions, adiabatic motion as well as distribution of shock, thermal and radial waves in gas with simple polytron state equation is investigated. 3 refs.; 6 figs

  5. Stepwise Nanopore Evolution in One-Dimensional Nanostructures

    KAUST Repository

    Choi, Jang Wook

    2010-04-14

    We report that established simple lithium (Li) ion battery cycles can be used to produce nanopores inside various useful one-dimensional (1D) nanostructures such as zinc oxide, silicon, and silver nanowires. Moreover, porosities of these 1D nanomaterials can be controlled in a stepwise manner by the number of Li-battery cycles. Subsequent pore characterization at the end of each cycle allows us to obtain detailed snapshots of the distinct pore evolution properties in each material due to their different atomic diffusion rates and types of chemical bonds. Also, this stepwise characterization led us to the first observation of pore size increases during cycling, which can be interpreted as a similar phenomenon to Ostwald ripening in analogous nanoparticle cases. Finally, we take advantage of the unique combination of nanoporosity and 1D materials and demonstrate nanoporous silicon nanowires (poSiNWs) as excellent supercapacitor (SC) electrodes in high power operations compared to existing devices with activated carbon. © 2010 American Chemical Society.

  6. RETRAN-02 one-dimensional kinetics model: a review

    International Nuclear Information System (INIS)

    Gose, G.C.; McClure, J.A.

    1986-01-01

    RETRAN-02 is a modular code system that has been designed for one-dimensional, transient thermal-hydraulics analysis. In RETRAN-02, core power behavior may be treated using a one-dimensional reactor kinetics model. This model allows the user to investigate the interaction of time- and space-dependent effects in the reactor core on overall system behavior for specific LWR operational transients. The purpose of this paper is to review the recent analysis and development activities related to the one dimensional kinetics model in RETRAN-02

  7. Plasma properties of quasi-one-dimensional ring

    CERN Document Server

    Shmelev, G M

    2001-01-01

    The plasma properties of the quasi-one-dimensional ring in the threshold cases of low and high frequencies, corresponding to the plasma oscillations and dielectric relaxation are studied within the frames of the classical approach. The plasma oscillations spectrum and the electron dielectric relaxation frequency in the quasi-one-dimensional ring are calculated. The plasmons spectrum equidistance is identified. It is shown , that in contrast to the three-dimensional case there takes place the dielectric relaxation dispersion, wherefrom there follows the possibility of studying the carriers distribution in the quasi-one-dimensional rings through the method of the dielectric relaxation spectroscopy

  8. Combinatorial synthesis of ceramic materials

    Science.gov (United States)

    Lauf, Robert J.; Walls, Claudia A.; Boatner, Lynn A.

    2006-11-14

    A combinatorial library includes a gelcast substrate defining a plurality of cavities in at least one surface thereof; and a plurality of gelcast test materials in the cavities, at least two of the test materials differing from the substrate in at least one compositional characteristic, the two test materials differing from each other in at least one compositional characteristic.

  9. Explicit Solutions for One-Dimensional Mean-Field Games

    KAUST Repository

    Prazeres, Mariana

    2017-01-01

    In this thesis, we consider stationary one-dimensional mean-field games (MFGs) with or without congestion. Our aim is to understand the qualitative features of these games through the analysis of explicit solutions. We are particularly interested

  10. Negative differential resistance in a one-dimensional molecular wire ...

    Indian Academy of Sciences (India)

    voltage characteristics of a one-dimensional molecular wire with odd number of ... lem, although interesting both from a fundamental point of view and in terms of ..... SKP acknowledges the DST, Government of India, for financial support.

  11. Radiation synthesis of materials and compounds

    CERN Document Server

    Kharisov, Boris Ildusovich; Ortiz Méndez, Ubaldo

    2013-01-01

    Researchers and engineers working in nuclear laboratories, nuclear electric plants, and elsewhere in the radiochemical industries need a comprehensive handbook describing all possible radiation-chemistry interactions between irradiation and materials, the preparation of materials under distinct radiation types, the possibility of damage of materials under irradiation, and more. Radiation nanotechnology is still practically an undeveloped field, except for some achievements in the fabrication of metallic nanoparticles under ionizing flows. Radiation Synthesis of Materials and Compounds presents the state of the art of the synthesis of materials, composites, and chemical compounds, and describes methods based on the use of ionizing radiation. It is devoted to the preparation of various types of materials (including nanomaterials) and chemical compounds using ionizing radiation (alpha particles, beta particles, gamma rays, x-rays, and neutron, proton, and ion beams). The book presents contributions from leaders ...

  12. One-dimensional reactor kinetics model for RETRAN

    International Nuclear Information System (INIS)

    Gose, G.C.; Peterson, C.E.; Ellis, N.L.; McClure, J.A.

    1981-01-01

    This paper describes a one-dimensional spatial neutron kinetics model that was developed for the RETRAN code. The RETRAN -01 code has a point kinetics model to describe the reactor core behavior during thermal-hydraulic transients. A one-dimensional neutronics model has been developed for RETRAN-02. The ability to account for flux shape changes will permit an improved representation of the thermal and hydraulic feedback effects for many operational transients. 19 refs

  13. One dimensional Bosons: From Condensed Matter Systems to Ultracold Gases

    OpenAIRE

    Cazalilla, M. A.; Citro, R.; Giamarchi, T.; Orignac, E.; Rigol, M.

    2011-01-01

    The physics of one-dimensional interacting bosonic systems is reviewed. Beginning with results from exactly solvable models and computational approaches, the concept of bosonic Tomonaga-Luttinger liquids relevant for one-dimensional Bose fluids is introduced, and compared with Bose-Einstein condensates existing in dimensions higher than one. The effects of various perturbations on the Tomonaga-Luttinger liquid state are discussed as well as extensions to multicomponent and out of equilibrium ...

  14. One dimensional models of excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Duclos, P.; Pedersen, Thomas Garm

    Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable.......Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable....

  15. One-Dimensional Hetero-Nanostructures for Rechargeable Batteries.

    Science.gov (United States)

    Mai, Liqiang; Sheng, Jinzhi; Xu, Lin; Tan, Shuangshuang; Meng, Jiashen

    2018-04-17

    Rechargeable batteries are regarded as one of the most practical electrochemical energy storage devices that are able to convert and store the electrical energy generated from renewable resources, and they function as the key power sources for electric vehicles and portable electronics. The ultimate goals for electrochemical energy storage devices are high power and energy density, long lifetime, and high safety. To achieve the above goals, researchers have tried to apply various morphologies of nanomaterials as the electrodes to enhance the electrochemical performance. Among them, one-dimensional (1D) materials show unique superiorities, such as cross-linked structures for external stress buffering and large draw ratios for internal stress dispersion. However, a homogeneous single-component electrode material can hardly have the characteristics of high electronic/ionic conductivity and high stability in the electrochemical environment simultaneously. Therefore, designing well-defined functional 1D hetero-nanostructures that combine the advantages and overcome the limitations of different electrochemically active materials is of great significance. This Account summarizes fabrication strategies for 1D hetero-nanostructures, including nucleation and growth, deposition, and melt-casting and electrospinning. Besides, the chemical principles for each strategy are discussed. The nucleation and growth strategy is suitable for growing and constructing 1D hetero-nanostructures of partial transition metal compounds, and the experimental conditions for this strategy are relatively accessible. Deposition is a reliable strategy to synthesize 1D hetero-nanostructures by decorating functional layers on 1D substrate materials, on the condition that the preobtained substrate materials must be stable in the following deposition process. The melt-casting strategy, in which 1D hetero-nanostructures are synthesizes via a melting and molding process, is also widely used. Additionally

  16. One-Dimensional Electron Transport Layers for Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Ujwal K. Thakur

    2017-04-01

    Full Text Available The electron diffusion length (Ln is smaller than the hole diffusion length (Lp in many halide perovskite semiconductors meaning that the use of ordered one-dimensional (1D structures such as nanowires (NWs and nanotubes (NTs as electron transport layers (ETLs is a promising method of achieving high performance halide perovskite solar cells (HPSCs. ETLs consisting of oriented and aligned NWs and NTs offer the potential not merely for improved directional charge transport but also for the enhanced absorption of incoming light and thermodynamically efficient management of photogenerated carrier populations. The ordered architecture of NW/NT arrays affords superior infiltration of a deposited material making them ideal for use in HPSCs. Photoconversion efficiencies (PCEs as high as 18% have been demonstrated for HPSCs using 1D ETLs. Despite the advantages of 1D ETLs, there are still challenges that need to be overcome to achieve even higher PCEs, such as better methods to eliminate or passivate surface traps, improved understanding of the hetero-interface and optimization of the morphology (i.e., length, diameter, and spacing of NWs/NTs. This review introduces the general considerations of ETLs for HPSCs, deposition techniques used, and the current research and challenges in the field of 1D ETLs for perovskite solar cells.

  17. One-dimensional two-phase thermal hydraulics (ENSTA course)

    International Nuclear Information System (INIS)

    Olive, J.

    1995-11-01

    This course is part of the ENSTA 3rd year thermal hydraulics program (nuclear power option). Its purpose is to provide the theoretical basis and main physical notions pertaining to two-phase flow, mainly focussed on water-steam flows. The introduction describes the physical specificities of these flows, emphasizing their complexity. The mathematical bases are then presented (partial derivative equations), leading to a one-dimensional type, simplified description. Balances drawn up for a pipe length volume are used to introduce the mass conservation. motion and energy equations for each phase. Various postulates used to simplify two-phase models are presented, culminating in homogeneous model definitions and equations, several common examples of which are given. The model is then applied to the calculation of pressure drops in two-phase flows. This involves presenting the models most frequently used to represent pressure drops by friction or due to pipe irregularities, without giving details (numerical values of parameters). This chapter terminates with a brief description of static and dynamic instabilities in two-phase flows. Finally, heat transfer conditions frequently encountered in liquid-steam flows are described, still in the context of a 1D model. This chapter notably includes reference to under-saturated boiling conditions and the various forms of DNB. The empirical heat transfer laws are not discussed in detail. Additional material is appended, some of which is in the form of corrected exercises. (author). 6 appends

  18. Transmission properties of one-dimensional ternary plasma photonic crystals

    International Nuclear Information System (INIS)

    Shiveshwari, Laxmi; Awasthi, S. K.

    2015-01-01

    Omnidirectional photonic band gaps (PBGs) are found in one-dimensional ternary plasma photonic crystals (PPC) composed of single negative metamaterials. The band characteristics and transmission properties are investigated through the transfer matrix method. We show that the proposed structure can trap light in three-dimensional space due to the elimination of Brewster's angle transmission resonance allowing the existence of complete PBG. The results are discussed in terms of incident angle, layer thickness, dielectric constant of the dielectric material, and number of unit cells (N) for TE and TM polarizations. It is seen that PBG characteristics is apparent even in an N ≥ 2 system, which is weakly sensitive to the incident angle and completely insensitive to the polarization. Finite PPC could be used for multichannel transmission filter without introducing any defect in the geometry. We show that the locations of the multichannel transmission peaks are in the allowed band of the infinite structure. The structure can work as a single or multichannel filter by varying the number of unit cells. Binary PPC can also work as a polarization sensitive tunable filter

  19. Transmission properties of one-dimensional ternary plasma photonic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Shiveshwari, Laxmi [Department of Physics, K. B. Womens' s College, Hazaribagh 825 301 (India); Awasthi, S. K. [Department of Physics and Material Science and Engineering, Jaypee Institute of Information Technology, Noida 201 304 (India)

    2015-09-15

    Omnidirectional photonic band gaps (PBGs) are found in one-dimensional ternary plasma photonic crystals (PPC) composed of single negative metamaterials. The band characteristics and transmission properties are investigated through the transfer matrix method. We show that the proposed structure can trap light in three-dimensional space due to the elimination of Brewster's angle transmission resonance allowing the existence of complete PBG. The results are discussed in terms of incident angle, layer thickness, dielectric constant of the dielectric material, and number of unit cells (N) for TE and TM polarizations. It is seen that PBG characteristics is apparent even in an N ≥ 2 system, which is weakly sensitive to the incident angle and completely insensitive to the polarization. Finite PPC could be used for multichannel transmission filter without introducing any defect in the geometry. We show that the locations of the multichannel transmission peaks are in the allowed band of the infinite structure. The structure can work as a single or multichannel filter by varying the number of unit cells. Binary PPC can also work as a polarization sensitive tunable filter.

  20. One-Dimensional Electron Transport Layers for Perovskite Solar Cells

    Science.gov (United States)

    Thakur, Ujwal K.; Kisslinger, Ryan; Shankar, Karthik

    2017-01-01

    The electron diffusion length (Ln) is smaller than the hole diffusion length (Lp) in many halide perovskite semiconductors meaning that the use of ordered one-dimensional (1D) structures such as nanowires (NWs) and nanotubes (NTs) as electron transport layers (ETLs) is a promising method of achieving high performance halide perovskite solar cells (HPSCs). ETLs consisting of oriented and aligned NWs and NTs offer the potential not merely for improved directional charge transport but also for the enhanced absorption of incoming light and thermodynamically efficient management of photogenerated carrier populations. The ordered architecture of NW/NT arrays affords superior infiltration of a deposited material making them ideal for use in HPSCs. Photoconversion efficiencies (PCEs) as high as 18% have been demonstrated for HPSCs using 1D ETLs. Despite the advantages of 1D ETLs, there are still challenges that need to be overcome to achieve even higher PCEs, such as better methods to eliminate or passivate surface traps, improved understanding of the hetero-interface and optimization of the morphology (i.e., length, diameter, and spacing of NWs/NTs). This review introduces the general considerations of ETLs for HPSCs, deposition techniques used, and the current research and challenges in the field of 1D ETLs for perovskite solar cells. PMID:28468280

  1. Interfacial Thermal Transport via One-Dimensional Atomic Junction Model

    Directory of Open Access Journals (Sweden)

    Guohuan Xiong

    2018-03-01

    Full Text Available In modern information technology, as integration density increases rapidly and the dimension of materials reduces to nanoscale, interfacial thermal transport (ITT has attracted widespread attention of scientists. This review introduces the latest theoretical development in ITT through one-dimensional (1D atomic junction model to address the thermal transport across an interface. With full consideration of the atomic structures in interfaces, people can apply the 1D atomic junction model to investigate many properties of ITT, such as interfacial (Kapitza resistance, nonlinear interface, interfacial rectification, and phonon interference, and so on. For the ballistic ITT, both the scattering boundary method (SBM and the non-equilibrium Green’s function (NEGF method can be applied, which are exact since atomic details of actual interfaces are considered. For interfacial coupling case, explicit analytical expression of transmission coefficient can be obtained and it is found that the thermal conductance maximizes at certain interfacial coupling (harmonic mean of the spring constants of the two leads and the transmission coefficient is not a monotonic decreasing function of phonon frequency. With nonlinear interaction—phonon–phonon interaction or electron–phonon interaction at interface, the NEGF method provides an efficient way to study the ITT. It is found that at weak linear interfacial coupling, the nonlinearity can improve the ITT, but it depresses the ITT in the case of strong-linear coupling. In addition, the nonlinear interfacial coupling can induce thermal rectification effect. For interfacial materials case which can be simulated by a two-junction atomic chain, phonons show interference effect, and an optimized thermal coupler can be obtained by tuning its spring constant and atomic mass.

  2. Strong chaos in one-dimensional quantum system

    International Nuclear Information System (INIS)

    Yang, C.-D.; Wei, C.-H.

    2008-01-01

    According to the Poincare-Bendixson theorem, a minimum of three autonomous equations is required to exhibit deterministic chaos. Because a one-dimensional quantum system is described by only two autonomous equations using de Broglie-Bohm's trajectory interpretation, chaos in one-dimensional quantum systems has long been considered impossible. We will prove in this paper that chaos phenomenon does exist in one-dimensional quantum systems, if the domain of quantum motions is extended to complex space by noting that the quantum world is actually characterized by a four-dimensional complex spacetime according to the E (∞) theory. Furthermore, we point out that the interaction between the real and imaginary parts of complex trajectories produces a new chaos phenomenon unique to quantum systems, called strong chaos, which describes the situation that quantum trajectories may emerge and diverge spontaneously without any perturbation in the initial position

  3. One-dimensional models of excitons in carbon nanotubes

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Duclos, Pierre; Pedersen, Thomas Garm

    2004-01-01

    Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one-dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable.......Excitons in carbon nanotubes may be modeled by two oppositely charged particles living on the surface of a cylinder. We derive three one-dimensional effective Hamiltonians which become exact as the radius of the cylinder vanishes. Two of them are solvable....

  4. Synthesis and characterization of innovative insulation materials

    Directory of Open Access Journals (Sweden)

    Skaropoulou Aggeliki

    2018-01-01

    Full Text Available Insulation elements are distinguished in inorganic fibrous and organic foamed materials. Foamed insulation materials are of great acceptance and use, but their major disadvantage is their flammability. In case of fire, they tend to transmit the flame producing toxic gases. In this paper, the synthesis and characterization of innovative inorganic insulation materials with properties competitive to commercial is presented. Their synthesis involves the mixing of inorganic raw material and water with reinforcing agent or/and foaming agent leading to the formation of a gel. Depending on raw materials nature, the insulation material is produced by freeze drying or ambient drying techniques of the gel. The raw material used are chemically benign and abundantly available materials, or industrial by-products and the final products are non-toxic and, in some cases, non-flammable. Their density and thermal conductivity was measured and found 0.02-0.06 g/cm3 and 0.03-0.04 W/mK, respectively.

  5. One-Dimensional Finite Elements An Introduction to the FE Method

    CERN Document Server

    Öchsner, Andreas

    2013-01-01

     This textbook presents finite element methods using exclusively  one-dimensional elements. The aim is to present the complex methodology in  an easily understandable but mathematically correct fashion. The approach of  one-dimensional elements enables the reader to focus on the understanding of  the principles of basic and advanced mechanical problems. The reader easily  understands the assumptions and limitations of mechanical modeling as well  as the underlying physics without struggling with complex mathematics. But  although the description is easy it remains scientifically correct.   The approach using only one-dimensional elements covers not only standard  problems but allows also for advanced topics like plasticity or the  mechanics of composite materials. Many examples illustrate the concepts and  problems at the end of every chapter help to familiarize with the topics.

  6. Approximate characteristics for one-dimensional two-phase flows

    International Nuclear Information System (INIS)

    Sarayloo, A.; Peddleson, J.

    1985-01-01

    An approximate method for determining the characteristics associated with one-dimensional particulate two-phase flow models is presented. The method is based on iteration and is valid for small particulate volume fractions. The method is applied to several special cases involving incompressible particles suspended in a gas. The influences of certain changes in the physical model are investigated

  7. Correlation Functions of the One-Dimensional Attractive Bose Gas

    International Nuclear Information System (INIS)

    Calabrese, Pasquale; Caux, Jean-Sebastien

    2007-01-01

    The zero-temperature correlation functions of the one-dimensional attractive Bose gas with a delta-function interaction are calculated analytically for any value of the interaction parameter and number of particles, directly from the integrability of the model. We point out a number of interesting features, including zero recoil energy for a large number of particles, analogous to the Moessbauer effect

  8. Analytical solutions of one-dimensional advection–diffusion

    Indian Academy of Sciences (India)

    Analytical solutions are obtained for one-dimensional advection –diffusion equation with variable coefficients in a longitudinal finite initially solute free domain,for two dispersion problems.In the first one,temporally dependent solute dispersion along uniform flow in homogeneous domain is studied.In the second problem the ...

  9. Underwater striling engine design with modified one-dimensional model

    Directory of Open Access Journals (Sweden)

    Daijin Li

    2015-05-01

    Full Text Available Stirling engines are regarded as an efficient and promising power system for underwater devices. Currently, many researches on one-dimensional model is used to evaluate thermodynamic performance of Stirling engine, but in which there are still some aspects which cannot be modeled with proper mathematical models such as mechanical loss or auxiliary power. In this paper, a four-cylinder double-acting Stirling engine for Unmanned Underwater Vehicles (UUVs is discussed. And a one-dimensional model incorporated with empirical equations of mechanical loss and auxiliary power obtained from experiments is derived while referring to the Stirling engine computer model of National Aeronautics and Space Administration (NASA. The P-40 Stirling engine with sufficient testing results from NASA is utilized to validate the accuracy of this one-dimensional model. It shows that the maximum error of output power of theoretical analysis results is less than 18% over testing results, and the maximum error of input power is no more than 9%. Finally, a Stirling engine for UUVs is designed with Schmidt analysis method and the modified one-dimensional model, and the results indicate this designed engine is capable of showing desired output power.

  10. Quantitative hyperbolicity estimates in one-dimensional dynamics

    International Nuclear Information System (INIS)

    Day, S; Kokubu, H; Pilarczyk, P; Luzzatto, S; Mischaikow, K; Oka, H

    2008-01-01

    We develop a rigorous computational method for estimating the Lyapunov exponents in uniformly expanding regions of the phase space for one-dimensional maps. Our method uses rigorous numerics and graph algorithms to provide results that are mathematically meaningful and can be achieved in an efficient way

  11. Quasi-one-dimensional scattering in a discrete model

    DEFF Research Database (Denmark)

    Valiente, Manuel; Mølmer, Klaus

    2011-01-01

    We study quasi-one-dimensional scattering of one and two particles with short-range interactions on a discrete lattice model in two dimensions. One of the directions is tightly confined by an arbitrary trapping potential. We obtain the collisional properties of these systems both at finite and zero...

  12. Structure Variation from One-Dimensional Chain to Three ...

    Indian Academy of Sciences (India)

    WEN-XUAN LI, XIAO-MIN GU, WEN-LI ZHANG and LIANG NI. School of Chemistry ... Compound 1 possesses one-dimensional chain structure, and expands into ..... sis of fine chemicals and pharmaceuticals.30 The results were summarized ...

  13. Current-Voltage Characteristics of Quasi-One-Dimensional Superconductors

    DEFF Research Database (Denmark)

    Vodolazov, D.Y.; Peeters, F.M.; Piraux, L.

    2003-01-01

    The current-voltage (I-V) characteristics of quasi-one-dimensional superconductors were discussed. The I-V characteristics exhibited an unusual S behavior. The dynamics of superconducting condensate and the existence of two different critical currents resulted in such an unusual behavior....

  14. Diffusive transport in a one dimensional disordered potential involving correlations

    International Nuclear Information System (INIS)

    Monthus, C.; Paris-6 Univ., 75

    1995-03-01

    Transport properties of one dimensional Brownian diffusion under the influence of a quenched random force, distributed as a two-level Poisson process is discussed. Large time scaling laws of the position of the Brownian particle, and the probability distribution of the stationary flux going through a sample between two prescribed concentrations are studied. (author) 14 refs.; 3 figs

  15. Appropriateness of one-dimensional calculations for repository analysis

    International Nuclear Information System (INIS)

    Eaton, R.R.

    1994-01-01

    This paper brings into focus the results of numerous studies that have addressed issues associated with the validity of assumptions which are used to justify reducing the dimensionality of numerical calculations of water flow through Yucca Mountain, NV. It is shown that in many cases, one-dimensional modeling is more rigorous than previously assumed

  16. One-dimensional position readout from microchannel plates

    International Nuclear Information System (INIS)

    Connell, K.A.; Przybylski, M.M.

    1982-01-01

    The development of a one-dimensional position readout system with microchannel plates, is described, for heavy ion detectors for use in a particle time-of-flight telescope and as a position sensitive device in front of an ionisation counter at the Nuclear Structure Facility. (U.K.)

  17. Lekhnitskii's formalism of one-dimensional quasicrystals and its ...

    Indian Academy of Sciences (India)

    To illustrate its utility, the generalized Lekhnitskii's formal- ism is used to analyse the coupled phonon and phason fields in an infinite quasicrystal medium con- taining an elliptic rigid inclusion. Keywords. Generalized Lekhnitskii's formalism; one-dimensional quasicrystals; plane problems; elliptic inclusion. PACS Nos 61.44.

  18. Backward scattering in the one-dimensional Fermi gas

    International Nuclear Information System (INIS)

    Apostol, M.

    1980-05-01

    The Ward identity is derived for non-relativistic fermions with two-body spin-independent interaction. Using this identity for the one-dimensional Fermi gas with backward scattering the equations of the perturbation theory are solved for the effective interaction and the collective excitations of the particle density fluctuations are obtained. (author)

  19. Monte Carlo investigation of the one-dimensional Potts model

    International Nuclear Information System (INIS)

    Karma, A.S.; Nolan, M.J.

    1983-01-01

    Monte Carlo results are presented for a variety of one-dimensional dynamical q-state Potts models. Our calculations confirm the expected universal value z = 2 for the dynamic scaling exponent. Our results also indicate that an increase in q at fixed correlation length drives the dynamics into the scaling regime

  20. State reconstruction of one-dimensional wave packets

    Science.gov (United States)

    Krähmer, D. S.; Leonhardt, U.

    1997-12-01

    We review and analyze the method [U. Leonhardt, M.G. Raymer: Phys. Rev. Lett. 76, 1985 (1996)] for quantum-state reconstruction of one-dimensional non-relativistic wave packets from position observations. We illuminate the theoretical background of the technique and show how to extend the procedure to the continuous part of the spectrum.

  1. One-dimensional autonomous systems and dissipative systems

    International Nuclear Information System (INIS)

    Lopez, G.

    1996-01-01

    The Lagrangian and the Generalized Linear Momentum are given in terms of a constant of motion for a one-dimensional autonomous system. The possibility of having an explicit Hamiltonian expression is also analyzed. The approach is applied to some dissipative systems. Copyright copyright 1996 Academic Press, Inc

  2. Quantum transport in strongly interacting one-dimensional nanostructures

    NARCIS (Netherlands)

    Agundez, R.R.

    2015-01-01

    In this thesis we study quantum transport in several one-dimensional systems with strong electronic interactions. The first chapter contains an introduction to the concepts treated throughout this thesis, such as the Aharonov-Bohm effect, the Kondo effect, the Fano effect and quantum state transfer.

  3. Statistics of resonances in one-dimensional continuous systems

    Indian Academy of Sciences (India)

    Vol. 73, No. 3. — journal of. September 2009 physics pp. 565–572. Statistics of resonances in one-dimensional continuous systems. JOSHUA FEINBERG. Physics Department, University of Haifa at Oranim, Tivon 36006, Israel ..... relativistic quantum mechanics (Israel Program for Scientific Translations, Jerusalem,. 1969).

  4. Statistical mechanics of quantum one-dimensional damped harmonic oscillator

    International Nuclear Information System (INIS)

    Borges, E.N.M.; Borges, O.N.; Ribeiro, L.A.A.

    1985-01-01

    We calculate the thermal correlation functions of the one-dimensional damped harmonic oscillator in contact with a reservoir, in an exact form by applying Green's function method. In this way the thermal fluctuations are incorporated in the Caldirola-Kanai Hamiltonian

  5. Anomalous heat conduction in a one-dimensional ideal gas.

    Science.gov (United States)

    Casati, Giulio; Prosen, Tomaz

    2003-01-01

    We provide firm convincing evidence that the energy transport in a one-dimensional gas of elastically colliding free particles of unequal masses is anomalous, i.e., the Fourier law does not hold. Our conclusions are confirmed by a theoretical and numerical analysis based on a Green-Kubo-type approach specialized to momentum-conserving lattices.

  6. Relativistic band gaps in one-dimensional disordered systems

    International Nuclear Information System (INIS)

    Clerk, G.J.; McKellar, B.H.J.

    1992-01-01

    Conditions for the existence of band gaps in a one-dimensional disordered array of δ-function potentials possessing short range order are developed in a relativistic framework. Both Lorentz vector and scalar type potentials are treated. The relationship between the energy gaps and the transmission properties of the array are also discussed. 20 refs., 2 figs

  7. The electromagnetic Brillouin precursor in one-dimensional photonic crystals

    NARCIS (Netherlands)

    Uitham, R.; Hoenders, B. J.

    2008-01-01

    We have calculated the electromagnetic Brillouin precursor that arises in a one-dimensional photonic crystal that consists of two homogeneous slabs which each have a single electron resonance. This forerunner is compared with the Brillouin precursor that arises in a homogeneous double-electron

  8. On the quantisation of one-dimensional bags

    International Nuclear Information System (INIS)

    Fairley, G.T.; Squires, E.J.

    1976-01-01

    The quantisation of one-dimensional MIT bags by expanding the fields as a sum of classical modes and truncating the series after the first term is discussed. The lowest states of a bag in a world containing two scalar quark fields are obtained. Problems associated with the zero-point oscillations of the field are discussed. (Auth.)

  9. The appropriateness of one-dimensional Yucca Mountain hydrologic calculations

    International Nuclear Information System (INIS)

    Eaton, R.R.

    1993-07-01

    This report brings into focus the results of numerous studies that have addressed issues associated with the validity of assumptions which are used to justify reducing the dimensionality of numerical calculations of water flow through Yucca Mountain, NV. it is shown that, in many cases, one-dimensional modeling is more rigorous than previously assumed

  10. Light propagation in one-dimensional porous silicon complex systems

    NARCIS (Netherlands)

    Oton, C.J.; Dal Negro, L.; Gaburro, Z.; Pavesi, L.; Johnson, P.J.; Lagendijk, Aart; Wiersma, D.S.

    2003-01-01

    We discuss the optical properties of one-dimensional complex dielectric systems, in particular the time-resolved transmission through thick porous silicon quasiperiodic multi-layers. Both in numerical calculations and experiments we find dramatic distortion effects, i.e. pulse stretching and

  11. Analytical approach for collective diffusion: one-dimensional heterogeneous lattice

    Czech Academy of Sciences Publication Activity Database

    Tarasenko, Alexander

    2016-01-01

    Roč. 144, č. 14 (2016), 1-11, č. článku 144105. ISSN 0021-9606 Institutional support: RVO:68378271 Keywords : diffusion * Monte Carlo simulations * one-dimensional heterogeneous lattice Subject RIV: BE - Theoretical Physics Impact factor: 2.965, year: 2016

  12. Approximate Approaches to the One-Dimensional Finite Potential Well

    Science.gov (United States)

    Singh, Shilpi; Pathak, Praveen; Singh, Vijay A.

    2011-01-01

    The one-dimensional finite well is a textbook problem. We propose approximate approaches to obtain the energy levels of the well. The finite well is also encountered in semiconductor heterostructures where the carrier mass inside the well (m[subscript i]) is taken to be distinct from mass outside (m[subscript o]). A relevant parameter is the mass…

  13. Toward precise solution of one-dimensional velocity inverse problems

    International Nuclear Information System (INIS)

    Gray, S.; Hagin, F.

    1980-01-01

    A family of one-dimensional inverse problems are considered with the goal of reconstructing velocity profiles to reasonably high accuracy. The travel-time variable change is used together with an iteration scheme to produce an effective algorithm for computation. Under modest assumptions the scheme is shown to be convergent

  14. Hydrothermal synthesis of cathode materials

    Science.gov (United States)

    Chen, Jiajun; Wang, Shijun; Whittingham, M. Stanley

    A number of cathodes are being considered for the next generation of lithium ion batteries to replace the expensive LiCoO 2 presently used. Besides the layered oxides, such as LiNi yMn yCo 1-2 yO 2, a leading candidate is lithium iron phosphate with the olivine structure. Although this material is inherently low cost, a manufacturing process that produces electrochemically active LiFePO 4 at a low cost is also required. Hydrothermal reactions are one such possibility. A number of pure phosphates have been prepared using this technique, including LiFePO 4, LiMnPO 4 and LiCoPO 4; this method has also successfully produced mixed metal phosphates, such as LiFe 0.33Mn 0.33Co 0.33PO 4. Ascorbic acid was found to be better than hydrazine or sugar at preventing the formation of ferric ions in aqueous media. When conductive carbons are added to the reaction medium excellent electrochemical behavior is observed.

  15. Bound states of Dipolar Bosons in One-dimensional Systems

    DEFF Research Database (Denmark)

    G. Volosniev, A.; R. Armstrong, J.; V. Fedorov, D.

    2013-01-01

    that in the weakly-coupled limit the inter-tube interaction is similar to a zero-range term with a suitable rescaled strength. This allows us to address the corresponding many-body physics of the system by constructing a model where bound chains with one molecule in each tube are the effective degrees of freedom......We consider one-dimensional tubes containing bosonic polar molecules. The long-range dipole-dipole interactions act both within a single tube and between different tubes. We consider arbitrary values of the externally aligned dipole moments with respect to the symmetry axis of the tubes. The few....... This model can be mapped onto one-dimensional Hamiltonians for which exact solutions are known....

  16. Applications of one-dimensional models in simplified inelastic analyses

    International Nuclear Information System (INIS)

    Kamal, S.A.; Chern, J.M.; Pai, D.H.

    1980-01-01

    This paper presents an approximate inelastic analysis based on geometric simplification with emphasis on its applicability, modeling, and the method of defining the loading conditions. Two problems are investigated: a one-dimensional axisymmetric model of generalized plane strain thick-walled cylinder is applied to the primary sodium inlet nozzle of the Clinch River Breeder Reactor Intermediate Heat Exchanger (CRBRP-IHX), and a finite cylindrical shell is used to simulate the branch shell forging (Y) junction. The results are then compared with the available detailed inelastic analyses under cyclic loading conditions in terms of creep and fatigue damages and inelastic ratchetting strains per the ASME Code Case N-47 requirements. In both problems, the one-dimensional simulation is able to trace the detailed stress-strain response. The quantitative comparison is good for the nozzle, but less satisfactory for the Y junction. Refinements are suggested to further improve the simulation

  17. Thermal conductivity in one-dimensional nonlinear systems

    Science.gov (United States)

    Politi, Antonio; Giardinà, Cristian; Livi, Roberto; Vassalli, Massimo

    2000-03-01

    Thermal conducitivity of one-dimensional nonlinear systems typically diverges in the thermodynamic limit, whenever the momentum is conserved (i.e. in the absence of interactions with an external substrate). Evidence comes from detailed studies of Fermi-Pasta-Ulam and diatomic Toda chains. Here, we discuss the first example of a one-dimensional system obeying Fourier law : a chain of coupled rotators. Numerical estimates of the thermal conductivity obtained by simulating a chain in contact with two thermal baths at different temperatures are found to be consistent with those ones based on linear response theory. The dynamics of the Fourier modes provides direct evidence of energy diffusion. The finiteness of the conductivity is traced back to the occurrence of phase-jumps. Our conclusions are confirmed by the analysis of two variants of the rotator model.

  18. Thermoelectric properties of one-dimensional graphene antidot arrays

    International Nuclear Information System (INIS)

    Yan, Yonghong; Liang, Qi-Feng; Zhao, Hui; Wu, Chang-Qin; Li, Baowen

    2012-01-01

    We investigate the thermoelectric properties of one-dimensional (1D) graphene antidot arrays by nonequilibrium Green's function method. We show that by introducing antidots to the pristine graphene nanoribbon the thermal conductance can be reduced greatly while keeping the power factor still high, thus leading to an enhanced thermoelectric figure of merit (ZT). Our numerical results indicate that ZT values of 1D antidot graphene arrays can be up to unity, which means the 1D graphene antidot arrays may be promising for thermoelectric applications. -- Highlights: ► We study thermoelectric properties of one-dimensional (1D) graphene antidot arrays. ► Thermoelectric figure of merit (ZT) of 1D antidot arrays can exceed unity. ► ZT of 1D antidot arrays is larger than that of two-dimensional arrays.

  19. Scattering theory for one-dimensional step potentials

    International Nuclear Information System (INIS)

    Ruijsenaars, S.N.M.; Bongaarts, P.J.M.

    1977-01-01

    The scattering theory is treated for the one-dimensional Dirac equation with potentials that are bounded, measurable, real-valued functions on the real line, having constant values, not necessarily the same, on the left and on the right side of a compact interval. Such potentials appear in the Klein paradox. It is shown that appropriately modified wave operators exist and that the corresponding S-operator is unitary. The connection between time-dependent scattering theory and time-independent scattering theory in terms of incoming and outgoing plane wave solutions is established and some further properties are proved. All results and their proofs have a straightforward translation to the one-dimensional Schroedinger equation with the same class of step potentials

  20. State switching kinetics for quasi-one-dimensional nanosystems: Effects of Finite length and irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Petukhov, B. V., E-mail: petukhov@ns.crys.ras.ru [Russian Academy of Sciences, Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” (Russian Federation)

    2017-01-15

    The state switching in an extended quasi-one-dimensional material is modeled by the stochastic formation of local new-state nuclei and their subsequent growth along the system axis. An analytical approach is developed to describe the influence of defects, dividing a sample into an ensemble of finite-length segments, on its state switching kinetics. As applied to magnetic systems, the method makes it possible to calculate magnetization curves for different defect concentrations and parameters of material.

  1. Synthesis, Properties, and Applications of Low-Dimensional Carbon-Related Nano materials

    International Nuclear Information System (INIS)

    Mostofizadeh, A.; Li, Y.; Song, B.; Huang, Y.; Mostofizadeh, A.

    2011-01-01

    In recent years, many theoretical and experimental studies have been carried out to develop one of the most interesting aspects of the science and nano technology which is called carbon-related nano materials. The goal of this paper is to provide a review of some of the most exciting and important developments in the synthesis, properties, and applications of low-dimensional carbon nano materials. Carbon nano materials are formed in various structural features using several different processing methods. The synthesis techniques used to produce specific kinds of low-dimensional carbon nano materials such as zero-dimensional carbon nano materials (including fullerene, carbon-encapsulated metal nanoparticles, nano diamond, and onion-like carbons), one-dimensional carbon nano materials (including carbon nano fibers and carbon nano tubes), and two-dimensional carbon nano materials (including graphene and carbon nano walls) are discussed in this paper. Subsequently, the paper deals with an overview of the properties of the mainly important products as well as some important applications and the future outlooks of these advanced nano materials.

  2. Impurity modes in the one-dimensional XXZ Heisenberg model

    International Nuclear Information System (INIS)

    Sousa, J.M.; Leite, R.V.; Landim, R.R.; Costa Filho, R.N.

    2014-01-01

    A Green's function formalism is used to calculate the energy of impurity modes associated with one and/or two magnetic impurities in the one-dimensional Heisenberg XXZ magnetic chain. The system can be tuned from the Heisenberg to the Ising model varying a parameter λ. A numerical study is performed showing two types of localized modes (s and p). The modes depend on λ and the degeneracy of the acoustic modes is broken.

  3. UNICIN - an one-dimensional computer code for reactor kinetics

    International Nuclear Information System (INIS)

    Rosa, M.A.P.; Alcantara, H.G. de; Nair, R.P.K.

    1984-01-01

    A program for the solution of the time- and space-dependent multigroup diffusion equations and the delayed-neutron precursors concentration equations in one dimensional geometries by the weighted residual method is described. The discretized equations are solved through an iterative procedure with convergence accelerated by the over-relaxation method. The system is perturbed through the variation of the nuclide concentrations in specified regions. Two feedback effects are included, namely, the temperature and the burnup. (Author) [pt

  4. Nonlinear acoustic wave propagating in one-dimensional layered system

    International Nuclear Information System (INIS)

    Yun, Y.; Miao, G.Q.; Zhang, P.; Huang, K.; Wei, R.J.

    2005-01-01

    The propagation of finite-amplitude plane sound in one-dimensional layered media is studied by the extended method of transfer matrix formalism. For the periodic layered system consisting of two alternate types of liquid, the energy distribution and the phase vectors of the interface vibration are computed and analyzed. It is found that in the pass-band, the second harmonic of sound wave can propagate with the characteristic modulation

  5. The analysis of one-dimensional reactor kinetics benchmark computations

    International Nuclear Information System (INIS)

    Sidell, J.

    1975-11-01

    During March 1973 the European American Committee on Reactor Physics proposed a series of simple one-dimensional reactor kinetics problems, with the intention of comparing the relative efficiencies of the numerical methods employed in various codes, which are currently in use in many national laboratories. This report reviews the contributions submitted to this benchmark exercise and attempts to assess the relative merits and drawbacks of the various theoretical and computer methods. (author)

  6. Heat transfer in a one-dimensional mixed convection loop

    International Nuclear Information System (INIS)

    Kim, Min Joon; Lee, Yong Bum; Kim, Yong Kyun; Kim, Jong Man; Nam, Ho Yun

    1999-01-01

    Effects of non-uniform heating in the core and additional forced circulation during decay heat removal operation are studied with a simplified mixed convection loop. The heat transfer coefficient is calculated analytically and measured experimentally. The analytic solution obtained from a one-dimensional heat equation is found to agree well with the experimental results. The effects of the non-uniform heating and the forced circulation are discussed

  7. Energy in one-dimensional linear waves in a string

    International Nuclear Information System (INIS)

    Burko, Lior M

    2010-01-01

    We consider the energy density and energy transfer in small amplitude, one-dimensional waves on a string and find that the common expressions used in textbooks for the introductory physics with calculus course give wrong results for some cases, including standing waves. We discuss the origin of the problem, and how it can be corrected in a way appropriate for the introductory calculus-based physics course. (letters and comments)

  8. Variational iteration method for one dimensional nonlinear thermoelasticity

    International Nuclear Information System (INIS)

    Sweilam, N.H.; Khader, M.M.

    2007-01-01

    This paper applies the variational iteration method to solve the Cauchy problem arising in one dimensional nonlinear thermoelasticity. The advantage of this method is to overcome the difficulty of calculation of Adomian's polynomials in the Adomian's decomposition method. The numerical results of this method are compared with the exact solution of an artificial model to show the efficiency of the method. The approximate solutions show that the variational iteration method is a powerful mathematical tool for solving nonlinear problems

  9. Localization in a one-dimensional spatially correlated random potential

    International Nuclear Information System (INIS)

    Kasner, M.; Weller, W.

    1986-01-01

    The motion of an electron in a random one-dimensional spatially correlated potential is investigated. The spatial correlation is generated by a Markov chain. It is shown that the influence of the spatial correlation can be described by means of oscillating vertices usually neglected in the Berezinskii diagram technique. Correlation mainly leads to an increase of the localization length in comparison with an uncorrelated potential. However, there is a region of the parameter, where the localization decreases. (author)

  10. ONE-DIMENSIONAL AND TWO-DIMENSIONAL LEADERSHIP STYLES

    OpenAIRE

    Nikola Stefanović

    2007-01-01

    In order to motivate their group members to perform certain tasks, leaders use different leadership styles. These styles are based on leaders' backgrounds, knowledge, values, experiences, and expectations. The one-dimensional styles, used by many world leaders, are autocratic and democratic styles. These styles lie on the two opposite sides of the leadership spectrum. In order to precisely define the leadership styles on the spectrum between the autocratic leadership style and the democratic ...

  11. Correlation functions of one-dimensional bosons at low temperature

    Energy Technology Data Exchange (ETDEWEB)

    Kozlowski, K.K. [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Maillet, J.M. [CNRS, ENS Lyon (France). Lab. de Physique; Slavnov, N.A. [Steklov Mathematical Institute, Moscow (Russian Federation)

    2010-12-15

    We consider the low-temperature limit of the long-distance asymptotic behavior of the finite temperature density-density correlation function in the one-dimensional Bose gas derived recently in the algebraic Bethe Ansatz framework. Our results confirm the predictions based on the Luttinger liquid and conformal field theory approaches. We also demonstrate that the amplitudes arising in this asymptotic expansion at low-temperature coincide with the amplitudes associated with the so-called critical form factors. (orig.)

  12. Graphene-based one-dimensional photonic crystal

    OpenAIRE

    Berman, Oleg L.; Kezerashvili, Roman Ya.

    2011-01-01

    A novel type of one-dimensional (1D) photonic crystal formed by the array of periodically located stacks of alternating graphene and dielectric stripes embedded into a background dielectric medium is proposed. The wave equation for the electromagnetic wave propagating in such structure solved in the framework of the Kronig-Penney model. The frequency band structure of 1D graphene-based photonic crystal is obtained analytically as a function of the filling factor and the thickness of the diele...

  13. Negative Refraction Angular Characterization in One-Dimensional Photonic Crystals

    OpenAIRE

    Lugo, Jesus Eduardo; Doti, Rafael; Faubert, Jocelyn

    2011-01-01

    Background Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity de...

  14. Majorana fermion exchange in strictly one dimensional structures

    OpenAIRE

    Chiu, Ching-Kai; Vazifeh, M. M.; Franz, M.

    2014-01-01

    It is generally thought that adiabatic exchange of two identical particles is impossible in one spatial dimension. Here we describe a simple protocol that permits adiabatic exchange of two Majorana fermions in a one-dimensional topological superconductor wire. The exchange relies on the concept of "Majorana shuttle" whereby a $\\pi$ domain wall in the superconducting order parameter which hosts a pair of ancillary Majoranas delivers one zero mode across the wire while the other one tunnels in ...

  15. On a class of one-dimensional random walks

    NARCIS (Netherlands)

    O.J. Boxma (Onno); V.I. Lotov

    1995-01-01

    textabstractnoindent This paper studies a one-dimensional Markov chain ${X_n,n=0,1,dots$ that satisfies the recurrence relation $X_n = max(0, X_{n-1 + eta_n^{(m) )$ if $X_{n-1 =m leq a$; for $X_{n-1 > a$ it satisfies the same relation with $eta_n^{(m)$ replaced by $xi_n$. Here ${ eta_n^{(m) $ and ${

  16. Theory of the one-dimensional forest-fire model

    International Nuclear Information System (INIS)

    Paczuski, M.; Bak, P.

    1993-01-01

    Turbulent cascade processes are studied in terms of a one-dimensional forest-fire model. A hier- archy of steady-state equations for the forests and the holes between them is constructed and solved within a mean-field closure scheme. The exact hole distribution function is found to be N H (s)=4N/[s(s+1)(s+2)], where N is the number of forests

  17. Shock compression synthesis of hard materials

    Energy Technology Data Exchange (ETDEWEB)

    Willson, C.G. [Univ. of Texas, Austin, TX (United States). Dept. of Chemistry

    1999-03-01

    The purpose of this research was to adapt the high explosives technology that was developed in conjunction with nuclear weapons programs to subjecting materials to ultra-high pressures and to explore the utility of this technique for the synthesis of hard materials. The research was conducted in collaboration with researchers at the University of Texas, Texas Tech University and Pantex (Mason and Hanger Corp.). The group designed, modeled, built, and tested a new device that allows quantitative recovery of grams of material that have been subjected to unprecedented pressures. The modeling work was done at Texas Tech and Pantex. The metal parts and material samples were made at the University of Texas, and Pantex machined the explosives, assembled the devices and conducted the detonations. Sample characterization was carried out at the University of Texas and Texas Tech.

  18. Quantum logic using correlated one-dimensional quantum walks

    Science.gov (United States)

    Lahini, Yoav; Steinbrecher, Gregory R.; Bookatz, Adam D.; Englund, Dirk

    2018-01-01

    Quantum Walks are unitary processes describing the evolution of an initially localized wavefunction on a lattice potential. The complexity of the dynamics increases significantly when several indistinguishable quantum walkers propagate on the same lattice simultaneously, as these develop non-trivial spatial correlations that depend on the particle's quantum statistics, mutual interactions, initial positions, and the lattice potential. We show that even in the simplest case of a quantum walk on a one dimensional graph, these correlations can be shaped to yield a complete set of compact quantum logic operations. We provide detailed recipes for implementing quantum logic on one-dimensional quantum walks in two general cases. For non-interacting bosons—such as photons in waveguide lattices—we find high-fidelity probabilistic quantum gates that could be integrated into linear optics quantum computation schemes. For interacting quantum-walkers on a one-dimensional lattice—a situation that has recently been demonstrated using ultra-cold atoms—we find deterministic logic operations that are universal for quantum information processing. The suggested implementation requires minimal resources and a level of control that is within reach using recently demonstrated techniques. Further work is required to address error-correction.

  19. Quasi-one-dimensional metals on semiconductor surfaces with defects

    International Nuclear Information System (INIS)

    Hasegawa, Shuji

    2010-01-01

    Several examples are known in which massive arrays of metal atomic chains are formed on semiconductor surfaces that show quasi-one-dimensional metallic electronic structures. In this review, Au chains on Si(557) and Si(553) surfaces, and In chains on Si(111) surfaces, are introduced and discussed with regard to the physical properties determined by experimental data from scanning tunneling microscopy (STM), angle-resolved photoemission spectroscopy (ARPES) and electrical conductivity measurements. They show quasi-one-dimensional Fermi surfaces and parabolic band dispersion along the chains. All of them are known from STM and ARPES to exhibit metal-insulator transitions by cooling and charge-density-wave formation due to Peierls instability of the metallic chains. The electrical conductivity, however, reveals the metal-insulator transition only on the less-defective surfaces (Si(553)-Au and Si(111)-In), but not on a more-defective surface (Si(557)-Au). The latter shows an insulating character over the whole temperature range. Compared with the electronic structure (Fermi surfaces and band dispersions), the transport property is more sensitive to the defects. With an increase in defect density, the conductivity only along the metal atomic chains was significantly reduced, showing that atomic-scale point defects decisively interrupt the electrical transport along the atomic chains and hide the intrinsic property of transport in quasi-one-dimensional systems.

  20. Gravitational anomalies and one-dimensional behavior of black holes

    Energy Technology Data Exchange (ETDEWEB)

    Majhi, Bibhas Ranjan [Indian Institute of Technology Guwahati, Department of Physics, Guwahati, Assam (India)

    2015-12-15

    It has been pointed out by Bekenstein and Mayo that the behavior of the black hole's entropy or information flow is similar to information flow through one-dimensional channel. Here I analyze the same issue with the use of gravitational anomalies. The rate of the entropy change (S) and the power (P) of the Hawking emission are calculated from the relevant components of the anomalous stress tensor under the Unruh vacuum condition. I show that the dependence of S on the power is S ∝ P{sup 1/2}, which is identical to that for the information flow in a one-dimensional system. This is established by using the (1+1)-dimensional gravitational anomalies first. Then the fact is further bolstered by considering the (1+3)-dimensional gravitational anomalies. It is found that, in the former case, the proportionality constant is exactly identical to the one-dimensional situation, known as Pendry's formula, while in the latter situation its value decreases. (orig.)

  1. One-dimensional crystal with a complex periodic potential

    International Nuclear Information System (INIS)

    Boyd, John K.

    2001-01-01

    A one-dimensional crystal model is constructed with a complex periodic potential. A wave function solution for the crystal model is derived without relying on Bloch functions. The new wave function solution of this model is shown to correspond to the solution for the probability amplitude of a two-level system. The energy discriminant is evaluated using an analytic formula derived from the probability amplitude solution, and based on an expansion parameter related to the energy and potential amplitude. From the wave function energy discriminant the crystal band structure is derived and related to standard energy bands and gaps. It is also shown that several of the properties of the two-level system apply to the one-dimensional crystal model. The two-level system solution which evolves in time is shown to manifest as a spatial configuration of the one-dimensional crystal model. The sensitivity of the wave function probability density is interpreted in the context of the new solution. The spatial configuration of the wave function, and the appearance of a long wavelength in the wave function probability density is explained in terms of the properties of Bessel functions

  2. The use of one-dimensional Niobate to improve MgH{sub 2} hydrogen sorption

    Energy Technology Data Exchange (ETDEWEB)

    Brum, M.C., E-mail: mbrum@metalmat.ufrj.br; Conceição, M.O.T. da; Jardim, P.M.; Santos, D.S. dos

    2014-12-05

    Highlights: • The 1-D Niobate W and Niobate C catalysts were synthesized. • The composites MgH{sub 2} + 5 wt.% catalysts were obtained by 20 min of mechanical milling. • The synthesized wired-like material 1-D Niobate W showed to be a promising catalyst. • A desorption capacity of 6.0 wt.%. of H{sub 2} was attained in 10 min with MgH{sub 2} + 5 wt.% 1-D Niobate W. - Abstract: A study was performed on the hydrogen absorption/desorption properties of MgH{sub 2} with the addition of Niobates synthesized by hydrothermal treatment of Nb{sub 2}O{sub 5} in 10 M NaOH. Scanning Electron Microscopy (SEM) and X-ray diffraction (XRD) were used to evaluate their synthesis and show the morphological and crystallographic differences between Nb{sub 2}O{sub 5} used as a precursor and the Niobates produced, the one-dimensional wired type, 1-D Niobate W and the cuboid one, Niobate C. The ball milling of MgH{sub 2} with the Niobates was performed within only 20 min and afterwards the Differential Scanning Calorimetry (DSC) examination of MgH{sub 2} + 1-D Niobate W and MgH{sub 2} + Niobate C showed the shifting of the peaks for both composites in comparison to pure MgH{sub 2}. The influence of the two different types of Niobates and also the Nb{sub 2}O{sub 5} on the hydrogen absorption/desorption capacity was evaluated at 350 °C. The higher absorption and desorption values were attained by the MgH{sub 2} + 5 wt.% 1-D Niobate W composite, reaching, in 10 min, approximately 5.0 wt.% and 6.0 wt.%, respectively. The possible mechanism involved in such property improvement upon adding niobium based catalysts with different morphology and structure was discussed.

  3. Projection multiplex recording of computer-synthesised one-dimensional Fourier holograms for holographic memory systems: mathematical and experimental modelling

    Energy Technology Data Exchange (ETDEWEB)

    Betin, A Yu; Bobrinev, V I; Verenikina, N M; Donchenko, S S; Odinokov, S B [Research Institute ' Radiotronics and Laser Engineering' , Bauman Moscow State Technical University, Moscow (Russian Federation); Evtikhiev, N N; Zlokazov, E Yu; Starikov, S N; Starikov, R S [National Reseach Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow (Russian Federation)

    2015-08-31

    A multiplex method of recording computer-synthesised one-dimensional Fourier holograms intended for holographic memory devices is proposed. The method potentially allows increasing the recording density in the previously proposed holographic memory system based on the computer synthesis and projection recording of data page holograms. (holographic memory)

  4. Nanostructural evolution from nanosheets to one-dimensional nanoparticles for manganese oxide

    International Nuclear Information System (INIS)

    Pan, Hongmei; Kong, Xingang; Wen, Puhong; Kitayama, Tomonori; Feng, Qi

    2012-01-01

    Highlights: ► Nanosheets were transformed to other one-dimensional nanoparticles. ► Nanofibers, nanotubes, nanoribbons, and nanobelts were obtained. ► Nanoparticle morphology can be controlled with organic amines. ► Organic amines act as morphology directing agent. -- Abstract: This paper introduces a novel hydrothermal soft chemical synthesis process for manganese oxide nanostructured particles using two-dimensional manganese oxide nanosheets as precursor. In this process, a birnessite-type manganese oxide with a layered structure was exfoliated into its elementary layer nanosheets, and then the nanosheets were hydrothermally treated to transform the two-dimensional morphology of the nanosheets to one-dimensional nanoparticles. The manganese oxide nanofibers, nanotubes, nanobelts, nanoribbons, and fabric-ribbon-like particles constructed from nanofibers or nanobelts were obtained using this hydrothermal soft chemical process. The nanostructural evolution from the two-dimensional nanosheets to the one-dimensional nanoparticles was characterized by XRD, SEM, TEM, and TG-DTA analysis. The morphology and nanostructure of the products are strongly dependent on the molecular dimension of organic amine cations added in the reaction system. The organic amine cations act as a morphology directing agent in the nanostructural evolution process.

  5. Integrability of the one dimensional Schrödinger equation

    Science.gov (United States)

    Combot, Thierry

    2018-02-01

    We present a definition of integrability for the one-dimensional Schrödinger equation, which encompasses all known integrable systems, i.e., systems for which the spectrum can be explicitly computed. For this, we introduce the class of rigid functions, built as Liouvillian functions, but containing all solutions of rigid differential operators in the sense of Katz, and a notion of natural of boundary conditions. We then make a complete classification of rational integrable potentials. Many new integrable cases are found, some of them physically interesting.

  6. Inversion of reflection for the one-dimensional Dirac equation

    International Nuclear Information System (INIS)

    Clerk, G.L.; Davies, A.J.

    1991-01-01

    It is a general result of one-dimensional non-relativistic quantum mechanics that the coefficient of reflection (reflected flux) is the same irrespective of the direction of traversing a potential barrier, a result that is independent of the barrier shape. In this note, the authors consider the transmission coefficient instead, and derive a strong result, namely that the transmission amplitude is independent of the direction of barrier traversal. That is, the transmission amplitude has the same complex phase as well as being unchanged in magnitude by changing the barrier around. This process was called inversion of reflection. 2 refs

  7. Two-dimensional beam profiles and one-dimensional projections

    Science.gov (United States)

    Findlay, D. J. S.; Jones, B.; Adams, D. J.

    2018-05-01

    One-dimensional projections of improved two-dimensional representations of transverse profiles of particle beams are proposed for fitting to data from harp-type monitors measuring beam profiles on particle accelerators. Composite distributions, with tails smoothly matched on to a central (inverted) parabola, are shown to give noticeably better fits than single gaussian and single parabolic distributions to data from harp-type beam profile monitors all along the proton beam transport lines to the two target stations on the ISIS Spallation Neutron Source. Some implications for inferring beam current densities on the beam axis are noted.

  8. Optical Tamm states in one-dimensional magnetophotonic structures.

    Science.gov (United States)

    Goto, T; Dorofeenko, A V; Merzlikin, A M; Baryshev, A V; Vinogradov, A P; Inoue, M; Lisyansky, A A; Granovsky, A B

    2008-09-12

    We demonstrate the existence of a spectrally narrow localized surface state, the so-called optical Tamm state, at the interface between one-dimensional magnetophotonic and nonmagnetic photonic crystals. The state is spectrally located inside the photonic band gaps of each of the photonic crystals comprising this magnetophotonic structure. This state is associated with a sharp transmission peak through the sample and is responsible for the substantial enhancement of the Faraday rotation for the corresponding wavelength. The experimental results are in excellent agreement with the theoretical predictions.

  9. Exactly integrable analogue of a one-dimensional gravitating system

    International Nuclear Information System (INIS)

    Miller, Bruce N.; Yawn, Kenneth R.; Maier, Bill

    2005-01-01

    Exchange symmetry in acceleration partitions the configuration space of an N particle one-dimensional gravitational system (OGS) into N! equivalent cells. We take advantage of the resulting small angular separation between the forces in neighboring cells to construct a related integrable version of the system that takes the form of a central force problem in N-1 dimensions. The properties of the latter, including the construction of trajectories and possible continuum limits, are developed. Dynamical simulation is employed to compare the two models. For some initial conditions, excellent agreement is observed

  10. Acoustic and electronic properties of one-dimensional quasicrystals

    International Nuclear Information System (INIS)

    Nori, F.; Rodriguez, J.P.

    1986-01-01

    We study the acoustic and electronic properties of one-dimensional quasicrystals. Both numerical (nonperturbative) and analytical (perturbative) results are shown. The phonon and electronic spectra exhibit a self-similar hierarchy of gaps and many localized states in the gaps. We study quasiperiodic structures with any number of layers and several types of boundary conditions. We discuss the connection between our phonon model and recent experiments on quasiperiodic GaAs-AlAs superlattices. We predict the existence of many gap states localized at the surfaces

  11. Hidden symmetries in one-dimensional quantum Hamiltonians

    International Nuclear Information System (INIS)

    Curado, E.M.F.; Rego-Monteiro, M.A.; Nazareno, H.N.

    2000-11-01

    We construct a Heisenberg-like algebra for the one dimensional infinite square-well potential in quantum mechanics. The number-type and ladder operators are realized in terms of physical operators of the system as in the harmonic oscillator algebra. These physical operators are obtained with the help of variables used in a recently developed non commutative differential calculus. This square-well algebra is an example of an algebra in large class of generalized Heisenberg algebras recently constructed. This class of algebras also contains q-oscillators as a particular case. We also show here how this general algebra can address hidden symmetries present in several quantum systems. (author)

  12. Quantum quench in an atomic one-dimensional Ising chain.

    Science.gov (United States)

    Meinert, F; Mark, M J; Kirilov, E; Lauber, K; Weinmann, P; Daley, A J; Nägerl, H-C

    2013-08-02

    We study nonequilibrium dynamics for an ensemble of tilted one-dimensional atomic Bose-Hubbard chains after a sudden quench to the vicinity of the transition point of the Ising paramagnetic to antiferromagnetic quantum phase transition. The quench results in coherent oscillations for the orientation of effective Ising spins, detected via oscillations in the number of doubly occupied lattice sites. We characterize the quench by varying the system parameters. We report significant modification of the tunneling rate induced by interactions and show clear evidence for collective effects in the oscillatory response.

  13. Chemical potential of one-dimensional simple harmonic oscillators

    International Nuclear Information System (INIS)

    Mungan, Carl E

    2009-01-01

    Expressions for the chemical potential of an Einstein solid, and of ideal Fermi and Bose gases in an external one-dimensional oscillatory trap, are calculated by two different methods and are all found to share the same functional form. These derivations are easier than traditional textbook calculations for an ideal gas in an infinite three-dimensional square well. Furthermore, the results indicate some important features of chemical potential that could promote student learning in an introductory course in statistical mechanics at the undergraduate level.

  14. Peierls' instability in a one-dimensional potentially metallic solid

    International Nuclear Information System (INIS)

    Valladares, A.A.; Cetina, E.A.; Sansores, L.E.

    1980-01-01

    The Peierls instability of one-dimensional potentially metallic lithium solid is investigated in the Hueckel and SCF approximations. In the Hueckel approximation Esub(F) is a monotonic increasing function of the displacement of every other atom of the lattice, whereas in the SCF approximation, where the filling of the bands is considered, Esub(F) shows the minimum predicted by Peierls. The energy gap (for the arrangement that minimizes Esub(F)) is 4.5 eV, indicating that this solid is an insulator. (author)

  15. One-dimensional radionuclide transport under time-varying conditions

    International Nuclear Information System (INIS)

    Gelbard, F.; Olague, N.E.; Longsine, D.E.

    1990-01-01

    This paper discusses new analytical and numerical solutions presented for one-dimensional radionuclide transport under time-varying fluid-flow conditions including radioactive decay. The analytical solution assumes that all radionuclides have identical retardation factors, and is limited to instantaneous releases. The numerical solution does not have these limitations, but is tested against the limiting case given for the analytical solution. Reasonable agreement between the two solutions was found. Examples are given for the transport of a three-member radionuclide chain transported over distances and flow rates comparable to those reported for Yucca Mountain, the proposed disposal site for high-level nuclear waste

  16. One-dimensional nonlinear inverse heat conduction technique

    International Nuclear Information System (INIS)

    Hills, R.G.; Hensel, E.C. Jr.

    1986-01-01

    The one-dimensional nonlinear problem of heat conduction is considered. A noniterative space-marching finite-difference algorithm is developed to estimate the surface temperature and heat flux from temperature measurements at subsurface locations. The trade-off between resolution and variance of the estimates of the surface conditions is discussed quantitatively. The inverse algorithm is stabilized through the use of digital filters applied recursively. The effect of the filters on the resolution and variance of the surface estimates is quantified. Results are presented which indicate that the technique is capable of handling noisy measurement data

  17. The quantum flux in quasis one-dimensional conductors

    International Nuclear Information System (INIS)

    Ventura, J.

    1989-01-01

    A method is presented which quantizes electromagnetic fluxes directly in flux space. It is based on the commutation law [φ B , φ E ] = i, where φ B is the magnetic flux, and φ E the longitudinal electric flux of a quasi one-dimensional conductor. The relevance of such a method for the description of the quantized Hall plateaus is discussed. In a second step, the polarization electric flux is introduced, together with a method for quantization of hybrid variables formed with pure electromagnetic fluxes plus electronic variables. (author) [pt

  18. Evaluation of one dimensional analytical models for vegetation canopies

    Science.gov (United States)

    Goel, Narendra S.; Kuusk, Andres

    1992-01-01

    The SAIL model for one-dimensional homogeneous vegetation canopies has been modified to include the specular reflectance and hot spot effects. This modified model and the Nilson-Kuusk model are evaluated by comparing the reflectances given by them against those given by a radiosity-based computer model, Diana, for a set of canopies, characterized by different leaf area index (LAI) and leaf angle distribution (LAD). It is shown that for homogeneous canopies, the analytical models are generally quite accurate in the visible region, but not in the infrared region. For architecturally realistic heterogeneous canopies of the type found in nature, these models fall short. These shortcomings are quantified.

  19. ONE-DIMENSIONAL AND TWO-DIMENSIONAL LEADERSHIP STYLES

    Directory of Open Access Journals (Sweden)

    Nikola Stefanović

    2007-06-01

    Full Text Available In order to motivate their group members to perform certain tasks, leaders use different leadership styles. These styles are based on leaders' backgrounds, knowledge, values, experiences, and expectations. The one-dimensional styles, used by many world leaders, are autocratic and democratic styles. These styles lie on the two opposite sides of the leadership spectrum. In order to precisely define the leadership styles on the spectrum between the autocratic leadership style and the democratic leadership style, leadership theory researchers use two dimensional matrices. The two-dimensional matrices define leadership styles on the basis of different parameters. By using these parameters, one can identify two-dimensional styles.

  20. Generalized entropy decay rates of one-dimensional maps

    International Nuclear Information System (INIS)

    Csordas, A.; Szepfalusy, P.

    1988-01-01

    A series of entropies, approaching the order-q Renyi's entropies when the length of orbits tends to infinity, is considered. Their scaling form is determined for chaotic one-dimensional maps. For the characteristic relaxation time a general expression is derived, and it is shown to be closely related to the eigenvalues of a generalized Frobenius-Perron operator. The case of intermittent maps is also considered, and the spectrum of relaxation time is found to reflect the phase transition at q = 1. Results of numerical experiments are also presented

  1. Entanglement entropy and complexity for one-dimensional holographic superconductors

    Science.gov (United States)

    Kord Zangeneh, Mahdi; Ong, Yen Chin; Wang, Bin

    2017-08-01

    Holographic superconductor is an important arena for holography, as it allows concrete calculations to further understand the dictionary between bulk physics and boundary physics. An important quantity of recent interest is the holographic complexity. Conflicting claims had been made in the literature concerning the behavior of holographic complexity during phase transition. We clarify this issue by performing a numerical study on one-dimensional holographic superconductor. Our investigation shows that holographic complexity does not behave in the same way as holographic entanglement entropy. Nevertheless, the universal terms of both quantities are finite and reflect the phase transition at the same critical temperature.

  2. Fragmented one dimensional man / El hombre unidimensional fragmentado

    Directory of Open Access Journals (Sweden)

    Juan Antonio Rodríguez del Pino

    2013-10-01

    Full Text Available Paraphrase the title of the famous essay by Herbert Marcuse, since the image has traditionally been generated of man, masculinity, has been one-dimensional. I mean, the man was characterized by traits and behaviors established and entrenched since ancient time, considering all other distinguishing signs as mere deviations from the normative improper. But observe that this undeniable reality, as analyzed various researchers through what has come to be called Men's studies, has proven to be a fallacy difficult to maintain throughout history and today turns into fallacious and ineffective against changes in our current existing corporate models.

  3. One-dimensional neutron imager for the Sandia Z facility.

    Science.gov (United States)

    Fittinghoff, David N; Bower, Dan E; Hollaway, James R; Jacoby, Barry A; Weiss, Paul B; Buckles, Robert A; Sammons, Timothy J; McPherson, Leroy A; Ruiz, Carlos L; Chandler, Gordon A; Torres, José A; Leeper, Ramon J; Cooper, Gary W; Nelson, Alan J

    2008-10-01

    A multiinstitution collaboration is developing a neutron imaging system for the Sandia Z facility. The initial system design is for slit aperture imaging system capable of obtaining a one-dimensional image of a 2.45 MeV source producing 5x10(12) neutrons with a resolution of 320 microm along the axial dimension of the plasma, but the design being developed can be modified for two-dimensional imaging and imaging of DT neutrons with other resolutions. This system will allow us to understand the spatial production of neutrons in the plasmas produced at the Z facility.

  4. One-dimensional computational modeling on nuclear reactor problems

    International Nuclear Information System (INIS)

    Alves Filho, Hermes; Baptista, Josue Costa; Trindade, Luiz Fernando Santos; Heringer, Juan Diego dos Santos

    2013-01-01

    In this article, we present a computational modeling, which gives us a dynamic view of some applications of Nuclear Engineering, specifically in the power distribution and the effective multiplication factor (keff) calculations. We work with one-dimensional problems of deterministic neutron transport theory, with the linearized Boltzmann equation in the discrete ordinates (SN) formulation, independent of time, with isotropic scattering and then built a software (Simulator) for modeling computational problems used in a typical calculations. The program used in the implementation of the simulator was Matlab, version 7.0. (author)

  5. Ordering phase transition in the one-dimensional Axelrod model

    Science.gov (United States)

    Vilone, D.; Vespignani, A.; Castellano, C.

    2002-12-01

    We study the one-dimensional behavior of a cellular automaton aimed at the description of the formation and evolution of cultural domains. The model exhibits a non-equilibrium transition between a phase with all the system sharing the same culture and a disordered phase of coexisting regions with different cultural features. Depending on the initial distribution of the disorder the transition occurs at different values of the model parameters. This phenomenology is qualitatively captured by a mean-field approach, which maps the dynamics into a multi-species reaction-diffusion problem.

  6. One-Dimensional Rydberg Gas in a Magnetoelectric Trap

    International Nuclear Information System (INIS)

    Mayle, Michael; Hezel, Bernd; Lesanovsky, Igor; Schmelcher, Peter

    2007-01-01

    We study the quantum properties of Rydberg atoms in a magnetic Ioffe-Pritchard trap which is superimposed by a homogeneous electric field. Trapped Rydberg atoms can be created in long-lived electronic states exhibiting a permanent electric dipole moment of several hundred Debye. The resulting dipole-dipole interaction in conjunction with the radial confinement is demonstrated to give rise to an effectively one-dimensional ultracold Rydberg gas with a macroscopic interparticle distance. We derive analytical expressions for the electric dipole moment and the required linear density of Rydberg atoms

  7. One-dimensional inverse problems of mathematical physics

    CERN Document Server

    Lavrent'ev, M M; Yakhno, V G; Schulenberger, J R

    1986-01-01

    This monograph deals with the inverse problems of determining a variable coefficient and right side for hyperbolic and parabolic equations on the basis of known solutions at fixed points of space for all times. The problems are one-dimensional in nature since the desired coefficient of the equation is a function of only one coordinate, while the desired right side is a function only of time. The authors use methods based on the spectral theory of ordinary differential operators of second order and also methods which make it possible to reduce the investigation of the inverse problems to the in

  8. A tetrahedrally coordinated cobalt(II) aminophosphonate containing one-dimensional channels

    International Nuclear Information System (INIS)

    Gemmill, William R.; Smith, Mark D.; Reisner, Barbara A.

    2005-01-01

    A tetrahedrally coordinated cobalt(II) phosphonate, Co(O 3 PCH 2 CH 2 NH 2 ), has been synthesized using hydrothermal techniques. X-ray diffraction indicates that this material is a three-dimensional open framework with rings aligned along a single axis forming infinite one-dimensional channels. The framework decomposes just above 400 deg. C. Magnetic susceptibility data are consistent with weak antiferromagnetic ordering at low temperatures

  9. Hydrogen peroxide stabilization in one-dimensional flow columns

    Science.gov (United States)

    Schmidt, Jeremy T.; Ahmad, Mushtaque; Teel, Amy L.; Watts, Richard J.

    2011-09-01

    Rapid hydrogen peroxide decomposition is the primary limitation of catalyzed H 2O 2 propagations in situ chemical oxidation (CHP ISCO) remediation of the subsurface. Two stabilizers of hydrogen peroxide, citrate and phytate, were investigated for their effectiveness in one-dimensional columns of iron oxide-coated and manganese oxide-coated sand. Hydrogen peroxide (5%) with and without 25 mM citrate or phytate was applied to the columns and samples were collected at 8 ports spaced 13 cm apart. Citrate was not an effective stabilizer for hydrogen peroxide in iron-coated sand; however, phytate was highly effective, increasing hydrogen peroxide residuals two orders of magnitude over unstabilized hydrogen peroxide. Both citrate and phytate were effective stabilizers for manganese-coated sand, increasing hydrogen peroxide residuals by four-fold over unstabilized hydrogen peroxide. Phytate and citrate did not degrade and were not retarded in the sand columns; furthermore, the addition of the stabilizers increased column flow rates relative to unstabilized columns. These results demonstrate that citrate and phytate are effective stabilizers of hydrogen peroxide under the dynamic conditions of one-dimensional columns, and suggest that citrate and phytate can be added to hydrogen peroxide before injection to the subsurface as an effective means for increasing the radius of influence of CHP ISCO.

  10. Stopping time of a one-dimensional bounded quantum walk

    International Nuclear Information System (INIS)

    Luo Hao; Zhang Peng; Zhan Xiang; Xue Peng

    2016-01-01

    The stopping time of a one-dimensional bounded classical random walk (RW) is defined as the number of steps taken by a random walker to arrive at a fixed boundary for the first time. A quantum walk (QW) is a non-trivial generalization of RW, and has attracted a great deal of interest from researchers working in quantum physics and quantum information. In this paper, we develop a method to calculate the stopping time for a one-dimensional QW. Using our method, we further compare the properties of stopping time for QW and RW. We find that the mean value of the stopping time is the same for both of these problems. However, for short times, the probability for a walker performing a QW to arrive at the boundary is larger than that for a RW. This means that, although the mean stopping time of a quantum and classical walker are the same, the quantum walker has a greater probability of arriving at the boundary earlier than the classical walker. (paper)

  11. One-Dimensional Forward–Forward Mean-Field Games

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Diogo A., E-mail: diogo.gomes@kaust.edu.sa; Nurbekyan, Levon; Sedjro, Marc [King Abdullah University of Science and Technology (KAUST), CEMSE Division (Saudi Arabia)

    2016-12-15

    While the general theory for the terminal-initial value problem for mean-field games (MFGs) has achieved a substantial progress, the corresponding forward–forward problem is still poorly understood—even in the one-dimensional setting. Here, we consider one-dimensional forward–forward MFGs, study the existence of solutions and their long-time convergence. First, we discuss the relation between these models and systems of conservation laws. In particular, we identify new conserved quantities and study some qualitative properties of these systems. Next, we introduce a class of wave-like equations that are equivalent to forward–forward MFGs, and we derive a novel formulation as a system of conservation laws. For first-order logarithmic forward–forward MFG, we establish the existence of a global solution. Then, we consider a class of explicit solutions and show the existence of shocks. Finally, we examine parabolic forward–forward MFGs and establish the long-time convergence of the solutions.

  12. Bjorken flow in one-dimensional relativistic magnetohydrodynamics with magnetization

    Science.gov (United States)

    Pu, Shi; Roy, Victor; Rezzolla, Luciano; Rischke, Dirk H.

    2016-04-01

    We study the one-dimensional, longitudinally boost-invariant motion of an ideal fluid with infinite conductivity in the presence of a transverse magnetic field, i.e., in the ideal transverse magnetohydrodynamical limit. In an extension of our previous work Roy et al., [Phys. Lett. B 750, 45 (2015)], we consider the fluid to have a nonzero magnetization. First, we assume a constant magnetic susceptibility χm and consider an ultrarelativistic ideal gas equation of state. For a paramagnetic fluid (i.e., with χm>0 ), the decay of the energy density slows down since the fluid gains energy from the magnetic field. For a diamagnetic fluid (i.e., with χmlaw ˜τ-a, two distinct solutions can be found depending on the values of a and χm. Finally, we also solve the ideal magnetohydrodynamical equations for one-dimensional Bjorken flow with a temperature-dependent magnetic susceptibility and a realistic equation of state given by lattice-QCD data. We find that the temperature and energy density decay more slowly because of the nonvanishing magnetization. For values of the magnetic field typical for heavy-ion collisions, this effect is, however, rather small. It is only for magnetic fields about an order of magnitude larger than expected for heavy-ion collisions that the system is substantially reheated and the lifetime of the quark phase might be extended.

  13. One-Dimensional Forward–Forward Mean-Field Games

    KAUST Repository

    Gomes, Diogo A.; Nurbekyan, Levon; Sedjro, Marc

    2016-01-01

    While the general theory for the terminal-initial value problem for mean-field games (MFGs) has achieved a substantial progress, the corresponding forward–forward problem is still poorly understood—even in the one-dimensional setting. Here, we consider one-dimensional forward–forward MFGs, study the existence of solutions and their long-time convergence. First, we discuss the relation between these models and systems of conservation laws. In particular, we identify new conserved quantities and study some qualitative properties of these systems. Next, we introduce a class of wave-like equations that are equivalent to forward–forward MFGs, and we derive a novel formulation as a system of conservation laws. For first-order logarithmic forward–forward MFG, we establish the existence of a global solution. Then, we consider a class of explicit solutions and show the existence of shocks. Finally, we examine parabolic forward–forward MFGs and establish the long-time convergence of the solutions.

  14. One-Dimensional Forward–Forward Mean-Field Games

    KAUST Repository

    Gomes, Diogo A.

    2016-11-01

    While the general theory for the terminal-initial value problem for mean-field games (MFGs) has achieved a substantial progress, the corresponding forward–forward problem is still poorly understood—even in the one-dimensional setting. Here, we consider one-dimensional forward–forward MFGs, study the existence of solutions and their long-time convergence. First, we discuss the relation between these models and systems of conservation laws. In particular, we identify new conserved quantities and study some qualitative properties of these systems. Next, we introduce a class of wave-like equations that are equivalent to forward–forward MFGs, and we derive a novel formulation as a system of conservation laws. For first-order logarithmic forward–forward MFG, we establish the existence of a global solution. Then, we consider a class of explicit solutions and show the existence of shocks. Finally, we examine parabolic forward–forward MFGs and establish the long-time convergence of the solutions.

  15. Non-equilibrium dynamics of one-dimensional Bose gases

    International Nuclear Information System (INIS)

    Langen, T.

    2013-01-01

    Understanding the non-equilibrium dynamics of isolated quantum many-body systems is an open problem on vastly different energy, length, and time scales. Examples range from the dynamics of the early universe and heavy-ion collisions to the subtle coherence and transport properties in condensed matter physics. However, realizations of such quantum many-body systems, which are both well isolated from the environment and accessible to experimental study are scarce. This thesis presents a series of experiments with ultracold one-dimensional Bose gases. These gases combine a nearly perfect isolation from the environment with many well-established methods to manipulate and probe their quantum states. This makes them an ideal model system to explore the physics of quantum many body systems out of equilibrium. In the experiments, a well-defined non-equilibrium state is created by splitting a single one-dimensional gas coherently into two parts. The relaxation of this state is probed using matter-wave interferometry. The Observations reveal the emergence of a prethermalized steady state which differs strongly from thermal equilibrium. Such thermal-like states had previously been predicted for a large variety of systems, but never been observed directly. Studying the relaxation process in further detail shows that the thermal correlations of the prethermalized state emerge locally in their final form and propagate through the system in a light-cone-like evolution. This provides first experimental evidence for the local relaxation conjecture, which links relaxation processes in quantum many-body systems to the propagation of correlations. Furthermore, engineering the initial state of the evolution demonstrates that the prethermalized state is described by a generalized Gibbs ensemble, an observation which substantiates the importance of this ensemble as an extension of standard statistical mechanics. Finally, an experiment is presented, where pairs of gases with an atom

  16. Resonant scattering induced thermopower in one-dimensional disordered systems

    Science.gov (United States)

    Müller, Daniel; Smit, Wilbert J.; Sigrist, Manfred

    2015-05-01

    This study analyzes thermoelectric properties of a one-dimensional random conductor which shows localization effects and simultaneously includes resonant scatterers yielding sharp conductance resonances. These sharp features give rise to a distinct behavior of the Seebeck coefficient in finite systems and incorporate the degree of localization as a means to enhance thermoelectric performance, in principle. The model for noninteracting electrons is discussed within the Landauer-Büttiker formalism such that analytical treatment is possible for a wide range of properties, if a special averaging scheme is applied. The approximations in the averaging procedure are tested with numerical evaluations showing good qualitative agreement, with some limited quantitative disagreement. The validity of low-temperature Mott's formula is determined and a good approximation is developed for the intermediate temperature range. In both regimes the intricate interplay between Anderson localization due to disorder and conductance resonances of the disorder potential is analyzed.

  17. Testing of a one dimensional model for Field II calibration

    DEFF Research Database (Denmark)

    Bæk, David; Jensen, Jørgen Arendt; Willatzen, Morten

    2008-01-01

    Field II is a program for simulating ultrasound transducer fields. It is capable of calculating the emitted and pulse-echoed fields for both pulsed and continuous wave transducers. To make it fully calibrated a model of the transducer’s electro-mechanical impulse response must be included. We...... examine an adapted one dimensional transducer model originally proposed by Willatzen [9] to calibrate Field II. This model is modified to calculate the required impulse responses needed by Field II for a calibrated field pressure and external circuit current calculation. The testing has been performed...... to the calibrated Field II program for 1, 4, and 10 cycle excitations. Two parameter sets were applied for modeling, one real valued Pz27 parameter set, manufacturer supplied, and one complex valued parameter set found in literature, Alguer´o et al. [11]. The latter implicitly accounts for attenuation. Results show...

  18. One-dimensional reactor kinetics model for RETRAN

    International Nuclear Information System (INIS)

    Gose, G.C.; Peterson, C.E.; Ellis, N.L.; McClure, J.A.

    1981-01-01

    Previous versions of RETRAN have had only a point kinetics model to describe the reactor core behavior during thermal-hydraulic transients. The principal assumption in deriving the point kinetics model is that the neutron flux may be separated into a time-dependent amplitude funtion and a time-independent shape function. Certain types of transients cannot be correctly analyzed under this assumption, since proper definitions for core average quantities such as reactivity or lifetime include the inner product of the adjoint flux with the perturbed flux. A one-dimensional neutronics model has been included in a preliminary version of RETRAN-02. The ability to account for flux shape changes will permit an improved representation of the thermal and hydraulic feedback effects. This paper describes the neutronics model and discusses some of the analyses

  19. One-dimensional Ising model with multispin interactions

    Science.gov (United States)

    Turban, Loïc

    2016-09-01

    We study the spin-1/2 Ising chain with multispin interactions K involving the product of m successive spins, for general values of m. Using a change of spin variables the zero-field partition function of a finite chain is obtained for free and periodic boundary conditions and we calculate the two-spin correlation function. When placed in an external field H the system is shown to be self-dual. Using another change of spin variables the one-dimensional Ising model with multispin interactions in a field is mapped onto a zero-field rectangular Ising model with first-neighbour interactions K and H. The 2D system, with size m × N/m, has the topology of a cylinder with helical BC. In the thermodynamic limit N/m\\to ∞ , m\\to ∞ , a 2D critical singularity develops on the self-duality line, \\sinh 2K\\sinh 2H=1.

  20. Quasi one dimensional transport in individual electrospun composite nanofibers

    Energy Technology Data Exchange (ETDEWEB)

    Avnon, A., E-mail: avnon@phys.fu-berlin.de; Datsyuk, V.; Trotsenko, S. [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin (Germany); Wang, B.; Zhou, S. [Research Center of Microperipheric Technologies, Technische Universität Berlin, TiB4/2-1, Gustav-Meyer-Allee 25, 13355 Berlin (Germany); Grabbert, N.; Ngo, H.-D. [Microsystem Engineering (FB I), University of Applied Sciences, Wilhelminenhofstr. 74 (C 525), 12459 Berlin (Germany)

    2014-01-15

    We present results of transport measurements of individual suspended electrospun nanofibers Poly(methyl methacrylate)-multiwalled carbon nanotubes. The nanofiber is comprised of highly aligned consecutive multiwalled carbon nanotubes. We have confirmed that at the range temperature from room temperature down to ∼60 K, the conductance behaves as power-law of temperature with an exponent of α ∼ 2.9−10.2. The current also behaves as power law of voltage with an exponent of β ∼ 2.3−8.6. The power-law behavior is a footprint for one dimensional transport. The possible models of this confined system are discussed. Using the model of Luttinger liquid states in series, we calculated the exponent for tunneling into the bulk of a single multiwalled carbon nanotube α{sub bulk} ∼ 0.06 which agrees with theoretical predictions.

  1. One-dimensional disk model simulation for klystron design

    International Nuclear Information System (INIS)

    Yonezawa, H.; Okazaki, Y.

    1984-05-01

    In 1982, one of the authors (Okazaki), of Toshiba Corporation, wrote a one-dimensional, rigid-disk model computer program to serve as a reliable design tool for the 150 MW klystron development project. This is an introductory note for the users of this program. While reviewing the so-called disk programs presently available, hypotheses such as gridded interaction gaps, a linear relation between phase and position, and so on, were found. These hypotheses bring serious limitations and uncertainties into the computational results. JPNDISK was developed to eliminate these defects, to follow the equations of motion as rigorously as possible, and to obtain self-consistent solutions for the gap voltages and the electron motion. Although some inaccuracy may be present in the relativistic region, JPNDISK, in its present form, seems a most suitable tool for klystron design; it is both easy and inexpensive to use

  2. Probing the exchange statistics of one-dimensional anyon models

    Science.gov (United States)

    Greschner, Sebastian; Cardarelli, Lorenzo; Santos, Luis

    2018-05-01

    We propose feasible scenarios for revealing the modified exchange statistics in one-dimensional anyon models in optical lattices based on an extension of the multicolor lattice-depth modulation scheme introduced in [Phys. Rev. A 94, 023615 (2016), 10.1103/PhysRevA.94.023615]. We show that the fast modulation of a two-component fermionic lattice gas in the presence a magnetic field gradient, in combination with additional resonant microwave fields, allows for the quantum simulation of hardcore anyon models with periodic boundary conditions. Such a semisynthetic ring setup allows for realizing an interferometric arrangement sensitive to the anyonic statistics. Moreover, we show as well that simple expansion experiments may reveal the formation of anomalously bound pairs resulting from the anyonic exchange.

  3. One-dimensional reduction of viscous jets. II. Applications

    Science.gov (United States)

    Pitrou, Cyril

    2018-04-01

    In a companion paper [Phys. Rev. E 97, 043115 (2018), 10.1103/PhysRevE.97.043115], a formalism allowing to describe viscous fibers as one-dimensional objects was developed. We apply it to the special case of a viscous fluid torus. This allows to highlight the differences with the basic viscous string model and with its viscous rod model extension. In particular, an elliptic deformation of the torus section appears because of surface tension effects, and this cannot be described by viscous string nor viscous rod models. Furthermore, we study the Rayleigh-Plateau instability for periodic deformations around the perfect torus, and we show that the instability is not sufficient to lead to the torus breakup in several droplets before it collapses to a single spherical drop. Conversely, a rotating torus is dynamically attracted toward a stationary solution, around which the instability can develop freely and split the torus in multiple droplets.

  4. Dynamics of an impurity in a one-dimensional lattice

    International Nuclear Information System (INIS)

    Massel, F; Kantian, A; Giamarchi, T; Daley, A J; Törmä, P

    2013-01-01

    We study the non-equilibrium dynamics of an impurity in a harmonic trap that is kicked with a well-defined quasi-momentum, and interacts with a bath of free fermions or interacting bosons in a one-dimensional lattice configuration. Using numerical and analytical techniques we investigate the full dynamics beyond linear response, which allows us to quantitatively characterize states of the impurity in the bath for different parameter regimes. These vary from a tightly bound molecular state in a strongly interacting limit to a polaron (dressed impurity) and a free particle for weak interactions, with composite behaviour in the intermediate regime. These dynamics and different parameter regimes should be readily realizable in systems of cold atoms in optical lattices. (paper)

  5. The transmission probability method in one-dimensional cylindrical geometry

    International Nuclear Information System (INIS)

    Rubin, I.E.

    1983-01-01

    The collision probability method widely used in solving the problems of neutron transpopt in a reactor cell is reliable for simple cells with small number of zones. The increase of the number of zones and also taking into account the anisotropy of scattering greatly increase the scope of calculations. In order to reduce the time of calculation the transmission probability method is suggested to be used for flux calculation in one-dimensional cylindrical geometry taking into account the scattering anisotropy. The efficiency of the suggested method is verified using the one-group calculations for cylindrical cells. The use of the transmission probability method allows to present completely angular and spatial dependences is neutrons distributions without the increase in the scope of calculations. The method is especially effective in solving the multi-group problems

  6. Piezoelectric transducer vibrations in a one-dimensional approximation

    CERN Document Server

    Hilke, H J

    1973-01-01

    The theory of piezoelectric transducer vibrations, which may be treated as one-dimensional, is developed in detail for thin discs vibrating in a pure thickness extensional mode. An effort has been made to obtain relations of general validity, which include losses, and which are in a simple explicit form convenient for practical calculations. The behaviour of transducers is discussed with special attention to their characteristics at the two fundamental frequencies, the so-called parallel and series resonances. Several peculiarities occur when transducers are coupled to media with considerably different acoustic impedances. These peculiarities are discussed and illustrated by numerical results for quartz and PZT 4 piezoelectric discs radiating into water, air and liquid hydrogen. The application of the theory to different types of vibrations is briefly illustrated for thin bars vibrating longitudinally. Short discussions are included on compound transducer systems, and on the properties of thin discs as receiv...

  7. Experiment and simulation on one-dimensional plasma photonic crystals

    International Nuclear Information System (INIS)

    Zhang, Lin; Ouyang, Ji-Ting

    2014-01-01

    The transmission characteristics of microwaves passing through one-dimensional plasma photonic crystals (PPCs) have been investigated by experiment and simulation. The PPCs were formed by a series of discharge tubes filled with argon at 5 Torr that the plasma density in tubes can be varied by adjusting the discharge current. The transmittance of X-band microwaves through the crystal structure was measured under different discharge currents and geometrical parameters. The finite-different time-domain method was employed to analyze the detailed properties of the microwaves propagation. The results show that there exist bandgaps when the plasma is turned on. The properties of bandgaps depend on the plasma density and the geometrical parameters of the PPCs structure. The PPCs can perform as dynamical band-stop filter to control the transmission of microwaves within a wide frequency range

  8. SUSY-hierarchy of one-dimensional reflectionless potentials

    CERN Document Server

    Maydanyuk, Sergei P

    2004-01-01

    A class of one-dimensional reflectionless potentials, an absolute transparency of which is concerned with their belonging to one SUSY-hierarchy with a constant potential, is studied. An approach for determination of a general form of the reflectionless potential on the basis of construction of such a hierarchy by the recurrent method is proposed. A general form of interdependence between superpotentials with neighboring numbers of this hierarchy, opening a possibility to find new reflectionless potentials, have a simple analytical view and are expressed through finite number of elementary functions (unlike some reflectionless potentials, which are constructed on the basis of soliton solutions or are shape invariant in one or many steps with involving scaling of parameters, and are expressed through series), is obtained. An analysis of absolute transparency existence for the potential which has the inverse power dependence on space coordinate (and here tunneling is possible), i.e. which has the form $V(x) = \\p...

  9. Strongly-Refractive One-Dimensional Photonic Crystal Prisms

    Science.gov (United States)

    Ting, David Z. (Inventor)

    2004-01-01

    One-dimensional (1D) photonic crystal prisms can separate a beam of polychromatic electromagnetic waves into constituent wavelength components and can utilize unconventional refraction properties for wavelength dispersion over significant portions of an entire photonic band rather than just near the band edges outside the photonic band gaps. Using a ID photonic crystal simplifies the design and fabrication process and allows the use of larger feature sizes. The prism geometry broadens the useful wavelength range, enables better optical transmission, and exhibits angular dependence on wavelength with reduced non-linearity. The properties of the 1 D photonic crystal prism can be tuned by varying design parameters such as incidence angle, exit surface angle, and layer widths. The ID photonic crystal prism can be fabricated in a planar process, and can be used as optical integrated circuit elements.

  10. Well-posedness of one-dimensional Korteweg models

    Directory of Open Access Journals (Sweden)

    Sylvie Benzoni-Gavage

    2006-05-01

    Full Text Available We investigate the initial-value problem for one-dimensional compressible fluids endowed with internal capillarity. We focus on the isothermal inviscid case with variable capillarity. The resulting equations for the density and the velocity, consisting of the mass conservation law and the momentum conservation with Korteweg stress, are a system of third order nonlinear dispersive partial differential equations. Additionally, this system is Hamiltonian and admits travelling solutions, representing propagating phase boundaries with internal structure. By change of unknown, it roughly reduces to a quasilinear Schrodinger equation. This new formulation enables us to prove local well-posedness for smooth perturbations of travelling profiles and almost-global existence for small enough perturbations. A blow-up criterion is also derived.

  11. A Reduced Order, One Dimensional Model of Joint Response

    Energy Technology Data Exchange (ETDEWEB)

    DOHNER,JEFFREY L.

    2000-11-06

    As a joint is loaded, the tangent stiffness of the joint reduces due to slip at interfaces. This stiffness reduction continues until the direction of the applied load is reversed or the total interface slips. Total interface slippage in joints is called macro-slip. For joints not undergoing macro-slip, when load reversal occurs the tangent stiffness immediately rebounds to its maximum value. This occurs due to stiction effects at the interface. Thus, for periodic loads, a softening and rebound hardening cycle is produced which defines a hysteretic, energy absorbing trajectory. For many jointed sub-structures, this hysteretic trajectory can be approximated using simple polynomial representations. This allows for complex joint substructures to be represented using simple non-linear models. In this paper a simple one dimensional model is discussed.

  12. Capillary condensation in one-dimensional irregular confinement.

    Science.gov (United States)

    Handford, Thomas P; Pérez-Reche, Francisco J; Taraskin, Sergei N

    2013-07-01

    A lattice-gas model with heterogeneity is developed for the description of fluid condensation in finite sized one-dimensional pores of arbitrary shape. Mapping to the random-field Ising model allows an exact solution of the model to be obtained at zero-temperature, reproducing the experimentally observed dependence of the amount of fluid adsorbed in the pore on external pressure. It is demonstrated that the disorder controls the sorption for long pores and can result in H2-type hysteresis. Finite-temperature Metropolis dynamics simulations support analytical findings in the limit of low temperatures. The proposed framework is viewed as a fundamental building block of the theory of capillary condensation necessary for reliable structural analysis of complex porous media from adsorption-desorption data.

  13. Topologically protected states in one-dimensional systems

    CERN Document Server

    Fefferman, C L; Weinstein, M I

    2017-01-01

    The authors study a class of periodic Schrödinger operators, which in distinguished cases can be proved to have linear band-crossings or "Dirac points". They then show that the introduction of an "edge", via adiabatic modulation of these periodic potentials by a domain wall, results in the bifurcation of spatially localized "edge states". These bound states are associated with the topologically protected zero-energy mode of an asymptotic one-dimensional Dirac operator. The authors' model captures many aspects of the phenomenon of topologically protected edge states for two-dimensional bulk structures such as the honeycomb structure of graphene. The states the authors construct can be realized as highly robust TM-electromagnetic modes for a class of photonic waveguides with a phase-defect.

  14. Interacting Fermi gases in disordered one-dimensional lattices

    International Nuclear Information System (INIS)

    Xianlong, Gao; Polini, M.; Tosi, M. P.; Tanatar, B.

    2006-01-01

    Interacting two-component Fermi gases loaded in a one-dimensional (1D) lattice and subject to harmonic trapping exhibit intriguing compound phases in which fluid regions coexist with local Mott-insulator and/or band-insulator regions. Motivated by experiments on cold atoms inside disordered optical lattices, we present a theoretical study of the effects of a random potential on these ground-state phases. Within a density-functional scheme we show that disorder has two main effects: (i) it destroys the local insulating regions if it is sufficiently strong compared with the on-site atom-atom repulsion, and (ii) it induces an anomaly in the compressibility at low density from quenching of percolation

  15. A one-dimensional ice structure built from pentagons

    Science.gov (United States)

    Carrasco, Javier; Michaelides, Angelos

    2010-03-01

    Heterogeneous nucleation of water plays a key role in fields as diverse as atmospheric chemistry, astrophysics, and biology. Ice nucleation on metal surfaces offers an opportunity to watch this process unfold, providing a molecular-scale description at a well-defined, planar interface. We discuss a density-functional theory study on a metal surface specifically designed to understand such phenomena. Together with our colleges at the University of Liverpool, we found that the nanometer wide water-ice chains experimentally observed to nucleate and grow on Cu(110) are built from a face sharing arrangement of water pentagons [1]. The novel one-dimensional pentagon structure maximizes the water-metal bonding whilst simultaneously maintaining a strong hydrogen bonding network. These results reveal an unanticipated structural adaptability of water-ice films, demonstrating that the presence of the substrate can be sufficient to favor non-conventional structural units. [4pt] [1] J. Carrasco et al., Nature Mater. 8, 427 (2009).

  16. One-dimensional plasma photonic crystals with sinusoidal densities

    International Nuclear Information System (INIS)

    Qi, L.; Shang, L.; Zhang, S.

    2014-01-01

    Properties of electromagnetic waves with normal and oblique incidence have been studied for one-dimensional plasma layers with sinusoidal densities. Wave transmittance as a function of wave frequency exhibits photonic band gaps characteristic of photonic crystals. For periodic structures, increasing collision frequency is demonstrated to lead to greater absorption, increasing the modulation factor enlarges the gap width, and increasing incidence angle can change the gap locations of the two polarizations. If a defect layer is introduced by inserting a new plasma layer in the center, a defect mode may appear within the gap. Periodic number, collision frequency, and modulation factor can affect magnitude of the defect mode. The incidence angle enables the frequency to be tuned. Defect layer thickness affects both frequency and number of defect modes. These results may provide theoretical guidance in designing tunable narrow-band filters

  17. Hidden magnetism in periodically modulated one dimensional dipolar fermions

    Science.gov (United States)

    Fazzini, S.; Montorsi, A.; Roncaglia, M.; Barbiero, L.

    2017-12-01

    The experimental realization of time-dependent ultracold lattice systems has paved the way towards the implementation of new Hubbard-like Hamiltonians. We show that in a one-dimensional two-components lattice dipolar Fermi gas the competition between long range repulsion and correlated hopping induced by periodically modulated on-site interaction allows for the formation of hidden magnetic phases, with degenerate protected edge modes. The magnetism, characterized solely by string-like nonlocal order parameters, manifests in the charge and/or in the spin degrees of freedom. Such behavior is enlighten by employing Luttinger liquid theory and numerical methods. The range of parameters for which hidden magnetism is present can be reached by means of the currently available experimental setups and probes.

  18. Relativistic collective diffusion in one-dimensional systems

    Science.gov (United States)

    Lin, Gui-Wu; Lam, Yu-Yiu; Zheng, Dong-Qin; Zhong, Wei-Rong

    2018-05-01

    The relativistic collective diffusion in one-dimensional molecular system is investigated through nonequilibrium molecular dynamics with Monte Carlo methods. We have proposed the relationship among the speed, the temperature, the density distribution and the collective diffusion coefficient of particles in a relativistic moving system. It is found that the relativistic speed of the system has no effect on the temperature, but the collective diffusion coefficient decreases to zero as the velocity of the system approaches to the speed of light. The collective diffusion coefficient is modified as D‧ = D(1 ‑w2 c2 )3 2 for satisfying the relativistic circumstances. The present results may contribute to the understanding of the behavior of the particles transport diffusion in a high speed system, as well as enlighten the study of biological metabolism at relativistic high speed situation.

  19. Asymmetrically doped one-dimensional trans-polymers

    International Nuclear Information System (INIS)

    Caldas, Heron

    2009-01-01

    More than 30 years ago [H. Shirakawa, E.J. Louis, A.G. MacDiarmid, C.K. Chiang, A.J. Heeger, J. Chem. Soc. Chem. Comm. 578 (1977); S. Etemad, A.J. Heeger, Ann. Rev. Phys. Chem. 33 (1982) 443] it was discovered that doped trans-polyacetylene (CH) x , a one-dimensional (1D) conjugated polymer, exhibits electrical conductivity. In this work we show that an asymmetrically doped 1D trans-polymer has non-conventional properties, as compared to symmetrically doped systems. Depending on the level of asymmetry between the chemical potentials of the two involved fermionic species, the polymer can be in a partially or fully spin polarized state. Some possible experimental consequences of doped 1D trans-polymers used as 1D organic polarized conductors are discussed.

  20. Explicit Solutions for One-Dimensional Mean-Field Games

    KAUST Repository

    Prazeres, Mariana

    2017-04-05

    In this thesis, we consider stationary one-dimensional mean-field games (MFGs) with or without congestion. Our aim is to understand the qualitative features of these games through the analysis of explicit solutions. We are particularly interested in MFGs with a nonmonotonic behavior, which corresponds to situations where agents tend to aggregate. First, we derive the MFG equations from control theory. Then, we compute explicit solutions using the current formulation and examine their behavior. Finally, we represent the solutions and analyze the results. This thesis main contributions are the following: First, we develop the current method to solve MFG explicitly. Second, we analyze in detail non-monotonic MFGs and discover new phenomena: non-uniqueness, discontinuous solutions, empty regions and unhappiness traps. Finally, we address several regularization procedures and examine the stability of MFGs.

  1. Charge and spin separation in one-dimensional systems

    International Nuclear Information System (INIS)

    Balseiro, C.A.; Jagla, E.A.; Hallberg, K.

    1995-01-01

    In this article we discuss charge and spin separation and quantum interference in one-dimensional models. After a short introduction we briefly present the Hubbard and Luttinger models and discuss some of the known exact results. We study numerically the charge and spin separation in the Hubbard model. The time evolution of a wave packet is obtained and the charge and spin densities are evaluated for different times. The charge and spin wave packets propagate with different velocities. The results are interpreted in terms of the Bethe-ansatz solution. In section IV we study the effect of charge and spin separation on the quantum interference in a Aharonov-Bohm experiment. By calculating the one-particle propagators of the Luttinger model for a mesoscopic ring with a magnetic field we calculate the Aharonov-Bohm conductance. The conductance oscillates with the magnetic field with a characteristic frequency that depends on the charge and spin velocities. (author)

  2. One-dimensional central-force problem, including radiation reaction

    International Nuclear Information System (INIS)

    Kasher, J.C.

    1976-01-01

    Two equal masses of equal charge magnitude (either attractive or repulsive) are held a certain distance apart for their entire past history. AT t = 0 one of them is either started from rest or given an initial velocity toward or away from the other charge. When the Dirac radiation-reaction force is included in the force equation, our Taylor-series numerical calculations lead to two types of nonphysical results for both the attractive and repulsive cases. In the attractive case, the moving charge either stops and moves back out to infinity, or violates energy conservation as it nears collision with the fixed charge. For the repulsive charges, the moving particle either eventually approaches and collides with the fixed one, or violates energy conservation as it goes out to infinity. These results lead us to conclude that the Lorentz-Dirac equation is not valid for the one-dimensional central-force problem

  3. Periodic transmission peak splitting in one dimensional disordered photonic structures

    Science.gov (United States)

    Kriegel, Ilka; Scotognella, Francesco

    2016-08-01

    In the present paper we present ways to modulate the periodic transmission peaks arising in disordered one dimensional photonic structures with hundreds of layers. Disordered structures in which the optical length nd (n is the refractive index and d the layer thickness) is the same for each layer show regular peaks in their transmission spectra. A proper variation of the optical length of the layers leads to a splitting of the transmission peaks. Notably, the variation of the occurrence of high and low refractive index layers, gives a tool to tune also the width of the peaks. These results are of highest interest for optical application, such as light filtering, where the manifold of parameters allows a precise design of the spectral transmission ranges.

  4. Polyacene and a new class of quasi-one-dimensional conductors

    International Nuclear Information System (INIS)

    Kivelson, S.; Chapman, O.L.

    1983-01-01

    Most one-dimensional conductors are quite similar since the Fermi surface is a point and the electron energy dispersion relation near the Fermi surface is linear. It is pointed out that in polyacene the Fermi surface lies at the edge of the Brillouin zone, but that an accidental degeneracy between the valence and conduction bands makes it metallic nonetheless. The dispersion relation is therefore quadratic, and the density of states diverges at the Fermi surface. Thus, polyacene [(C 4 H 2 )/sub n/] and its possible derivatives represent a conceptually new class of quasi-one-dimensional conductors. Moreover, we find that this class of materials has the possibility of possessing interesting condensed phases including high-temperature superconductivity and ferromagnetism

  5. REVIEW One-Dimensional Dynamical Modeling of Earthquakes: A Review

    Directory of Open Access Journals (Sweden)

    Jeen-Hwa Wang

    2008-01-01

    Full Text Available Studies of the power-law relations of seismicity and earthquake source parameters based on the one-dimensional (1-D Burridge-Knopoff¡¦s (BK dynamical lattice model, especially those studies conducted by Taiwan¡¦s scientists, are reviewed in this article. In general, velocity- and/or state-dependent friction is considered to control faulting. A uniform distribution of breaking strengths (i.e., the static friction strength is taken into account in some studies, and inhomogeneous distributions in others. The scaling relations in these studies include: Omori¡¦s law, the magnitude-frequency or energy-frequency relation, the relation between source duration time and seismic moment, the relation between rupture length and seismic moment, the frequency-length relation, and the source power spectra. The main parameters of the one-dimensional (1-D Burridge-Knopoff¡¦s (BK dynamical lattice model include: the decreasing rate (r of dynamic friction strength with sliding velocity; the type and degree of heterogeneous distribution of the breaking strengths, the stiffness ratio (i.e., the ratio between the stiffness of the coil spring connecting two mass elements and that of the leaf spring linking a mass element and the moving plate; the frictional drop ratio of the minimum dynamic friction strength to the breaking strength; and the maximum breaking strength. For some authors, the distribution of the breaking strengths was considered to be a fractal function. Hence, the fractal dimension of such a distribution is also a significant parameter. Comparison between observed scaling laws and simulation results shows that the 1-D BK dynamical lattice model acceptably approaches fault dynamics.

  6. One-dimensional reduction of viscous jets. I. Theory

    Science.gov (United States)

    Pitrou, Cyril

    2018-04-01

    We build a general formalism to describe thin viscous jets as one-dimensional objects with an internal structure. We present in full generality the steps needed to describe the viscous jets around their central line, and we argue that the Taylor expansion of all fields around that line is conveniently expressed in terms of symmetric trace-free tensors living in the two dimensions of the fiber sections. We recover the standard results of axisymmetric jets and we report the first and second corrections to the lowest order description, also allowing for a rotational component around the axis of symmetry. When applied to generally curved fibers, the lowest order description corresponds to a viscous string model whose sections are circular. However, when including the first corrections, we find that curved jets generically develop elliptic sections. Several subtle effects imply that the first corrections cannot be described by a rod model since it amounts to selectively discard some corrections. However, in a fast rotating frame, we find that the dominant effects induced by inertial and Coriolis forces should be correctly described by rod models. For completeness, we also recover the constitutive relations for forces and torques in rod models and exhibit a missing term in the lowest order expression of viscous torque. Given that our method is based on tensors, the complexity of all computations has been beaten down by using an appropriate tensor algebra package such as xAct, allowing us to obtain a one-dimensional description of curved viscous jets with all the first order corrections consistently included. Finally, we find a description for straight fibers with elliptic sections as a special case of these results, and recover that ellipticity is dynamically damped by surface tension. An application to toroidal viscous fibers is presented in the companion paper [Pitrou, Phys. Rev. E 97, 043116 (2018), 10.1103/PhysRevE.97.043116].

  7. Synthesis of functional materials in combustion reactions

    Science.gov (United States)

    Zhuravlev, V. D.; Bamburov, V. G.; Ermakova, L. V.; Lobachevskaya, N. I.

    2015-12-01

    The conditions for obtaining oxide compounds in combustion reactions of nitrates of metals with organic chelating-reducing agents such as amino acids, urea, and polyvinyl alcohol are reviewed. Changing the nature of internal fuels and the reducing agent-to-oxidizing agent ratio makes possible to modify the thermal regime of the process, fractal dimensionality, morphology, and dispersion of synthesized functional materials. This method can be used to synthesize simple and complex oxides, composites, and metal powders, as well as ceramics and coatings. The possibilities of synthesis in combustion reactions are illustrated by examples of αand γ-Al2O3, YSZ composites, uranium oxides, nickel powder, NiO and NiO: YSZ composite, TiO2, and manganites, cobaltites, and aluminates of rare earth elements.

  8. Manufacturing Demonstration Facility: Low Temperature Materials Synthesis

    International Nuclear Information System (INIS)

    Graham, David E.; Moon, Ji-Won; Armstrong, Beth L.; Datskos, Panos G.; Duty, Chad E.; Gresback, Ryan; Ivanov, Ilia N.; Jacobs, Christopher B.; Jellison, Gerald Earle; Jang, Gyoung Gug; Joshi, Pooran C.; Jung, Hyunsung; Meyer, Harry M.; Phelps, Tommy

    2015-01-01

    The Manufacturing Demonstration Facility (MDF) low temperature materials synthesis project was established to demonstrate a scalable and sustainable process to produce nanoparticles (NPs) for advanced manufacturing. Previous methods to chemically synthesize NPs typically required expensive, high-purity inorganic chemical reagents, organic solvents and high temperatures. These processes were typically applied at small laboratory scales at yields sufficient for NP characterization, but insufficient to support roll-to-roll processing efforts or device fabrication. The new NanoFermentation processes described here operated at a low temperature (~60 C) in low-cost, aqueous media using bacteria that produce extracellular NPs with controlled size and elemental stoichiometry. Up-scaling activities successfully demonstrated high NP yields and quality in a 900-L pilot-scale reactor, establishing this NanoFermentation process as a competitive biomanufacturing strategy to produce NPs for advanced manufacturing of power electronics, solid-state lighting and sensors.

  9. Manufacturing Demonstration Facility: Low Temperature Materials Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Graham, David E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Moon, Ji-Won [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Armstrong, Beth L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Datskos, Panos G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Duty, Chad E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Gresback, Ryan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ivanov, Ilia N. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jacobs, Christopher B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jellison, Gerald Earle [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jang, Gyoung Gug [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Joshi, Pooran C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jung, Hyunsung [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Meyer, III, Harry M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Phelps, Tommy [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-06-30

    The Manufacturing Demonstration Facility (MDF) low temperature materials synthesis project was established to demonstrate a scalable and sustainable process to produce nanoparticles (NPs) for advanced manufacturing. Previous methods to chemically synthesize NPs typically required expensive, high-purity inorganic chemical reagents, organic solvents and high temperatures. These processes were typically applied at small laboratory scales at yields sufficient for NP characterization, but insufficient to support roll-to-roll processing efforts or device fabrication. The new NanoFermentation processes described here operated at a low temperature (~60 C) in low-cost, aqueous media using bacteria that produce extracellular NPs with controlled size and elemental stoichiometry. Up-scaling activities successfully demonstrated high NP yields and quality in a 900-L pilot-scale reactor, establishing this NanoFermentation process as a competitive biomanufacturing strategy to produce NPs for advanced manufacturing of power electronics, solid-state lighting and sensors.

  10. Nano materials Synthesis, Applications, and Toxicity 2012

    International Nuclear Information System (INIS)

    Nadagouda, M.N.; Lytle, D.A.; Speth, Th.F.; Dionysiou, D.D.; Mukhopadhyay, Sh.M.

    2013-01-01

    Nano technology presents new opportunities to create better materials and products. Nano materials find wide applications in catalysis, energy production, medicine, environmental remediation, automotive industry, and other sectors of our society. Nano material-containing products are already available globally and include automotive parts, defense application, drug delivery devices, coatings, computers, clothing, cosmetics, sports equipment, and medical devices. This special issue includes emerging advances in the field, with a special emphasis given to nano material synthesis and applications. There is an increasing interest in identifying magnetically separable catalysts for the degradation of wastewater. In this issue, A. Perumal et al. report an investigation of temperature-dependent magnetic properties and photo catalytic activity of CoFe 2 O 4 -Fe 3 O 4 magnetic nano composites (MNCs) synthesized by hydrothermal processes. These MNCs have saturation magnetization of 90 emu/g and coercivity (HC) of 530 Oe. The photo catalytic activity of the MNCs has been examined on the reduction of methyl orange (MO), a colored compound used in dyeing and printing textiles. The MNCs act as an excellent photo catalyst on the degradation of organic contaminants and degrade 93% of MO in 5 hours of UV irradiation. The photo catalytic activity of MNCs is attributed to remarkably high band gap energy and small particle size. Also, the MNCs with reproducible photo catalytic activity are easily separated from water media by applying an external magnetic field and they act as a promising catalyst for the remediation of textile wastewater. Microwaves can play an important role in orchestrating nano materials for a wide range of technological applications

  11. Machine-learned and codified synthesis parameters of oxide materials

    Science.gov (United States)

    Kim, Edward; Huang, Kevin; Tomala, Alex; Matthews, Sara; Strubell, Emma; Saunders, Adam; McCallum, Andrew; Olivetti, Elsa

    2017-09-01

    Predictive materials design has rapidly accelerated in recent years with the advent of large-scale resources, such as materials structure and property databases generated by ab initio computations. In the absence of analogous ab initio frameworks for materials synthesis, high-throughput and machine learning techniques have recently been harnessed to generate synthesis strategies for select materials of interest. Still, a community-accessible, autonomously-compiled synthesis planning resource which spans across materials systems has not yet been developed. In this work, we present a collection of aggregated synthesis parameters computed using the text contained within over 640,000 journal articles using state-of-the-art natural language processing and machine learning techniques. We provide a dataset of synthesis parameters, compiled autonomously across 30 different oxide systems, in a format optimized for planning novel syntheses of materials.

  12. Synthesis and evaluation of energetic materials

    Science.gov (United States)

    Santhosh, G.

    Over the years new generations of propellants and explosives are being developed. High performance and pollution prevention issues have become the subject of interest in recent years. Desired properties of these materials are a halogen-free, nitrogen and oxygen rich molecular composition with high density and a positive heat of formation. The dinitramide anion is a new oxy anion of nitrogen and forms salts with variety of metal, organic and inorganic cations. Particular interest is in ammonium dinitramide (ADN, NH4N(NO 2)2) which is a potentially useful energetic oxidizer. ADN is considered as one of the most promising substitutes for ammonium perchlorate (AP, NH4ClO4) in currently used composite propellants. It is unique among energetic materials in that it has no carbon or chlorine; its combustion products are not detrimental to the atmosphere. Unquestionable advantage of ADN over AP is the significant improvement in the performance of solid rocket motors by 5-15%. The present thesis is centered on the experimental results along with discussion of some of the most pertinent aspects related to the synthesis and characterization of few dinitramide salts. The chemistry, mechanism and kinetics of the formation of dinitramide salts by nitration of deactivated amines are investigated. The evaluation of the thermal and spectral properties along with the adsorption and thermal decomposition characteristics of the dinitramide salts are also explored in this thesis.

  13. BERMUDA-1DG: a one-dimensional photon transport code

    International Nuclear Information System (INIS)

    Suzuki, Tomoo; Hasegawa, Akira; Nakashima, Hiroshi; Kaneko, Kunio.

    1984-10-01

    A one-dimensional photon transport code BERMUDA-1DG has been developed for spherical and infinite slab geometries. The purpose of development is to equip the function of gamma rays calculation for the BERMUDA code system, which was developed by 1983 only for neutron transport calculation as a preliminary version. A group constants library has been prepared for 30 nuclides, and it now consists of the 36-group total cross sections and secondary gamma ray yields by the 120-group neutron flux. For the Compton scattering, group-angle transfer matrices are accurately obtained by integrating the Klein-Nishina formula taking into account the energy and scattering angle correlation. The pair production cross sections are now calculated in the code from atomic number and midenergy of each group. To obtain angular flux distribution, the transport equation is solved in the same way as in case of neutron, using the direct integration method in a multigroup model. Both of an independent gamma ray source problem and a neutron-gamma source problem are possible to be solved. This report is written as a user's manual with a brief description of the calculational method. (author)

  14. Spin glasses and algorithm benchmarks: A one-dimensional view

    International Nuclear Information System (INIS)

    Katzgraber, H G

    2008-01-01

    Spin glasses are paradigmatic models that deliver concepts relevant for a variety of systems. However, rigorous analytical results are difficult to obtain for spin-glass models, in particular for realistic short-range models. Therefore large-scale numerical simulations are the tool of choice. Concepts and algorithms derived from the study of spin glasses have been applied to diverse fields in computer science and physics. In this work a one-dimensional long-range spin-glass model with power-law interactions is discussed. The model has the advantage over conventional systems in that by tuning the power-law exponent of the interactions the effective space dimension can be changed thus effectively allowing the study of large high-dimensional spin-glass systems to address questions as diverse as the existence of an Almeida-Thouless line, ultrametricity and chaos in short range spin glasses. Furthermore, because the range of interactions can be changed, the model is a formidable test-bed for optimization algorithms

  15. One-dimensional transient radiative transfer by lattice Boltzmann method.

    Science.gov (United States)

    Zhang, Yong; Yi, Hongliang; Tan, Heping

    2013-10-21

    The lattice Boltzmann method (LBM) is extended to solve transient radiative transfer in one-dimensional slab containing scattering media subjected to a collimated short laser irradiation. By using a fully implicit backward differencing scheme to discretize the transient term in the radiative transfer equation, a new type of lattice structure is devised. The accuracy and computational efficiency of this algorithm are examined firstly. Afterwards, effects of the medium properties such as the extinction coefficient, the scattering albedo and the anisotropy factor, and the shapes of laser pulse on time-resolved signals of transmittance and reflectance are investigated. Results of the present method are found to compare very well with the data from the literature. For an oblique incidence, the LBM results in this paper are compared with those by Monte Carlo method generated by ourselves. In addition, transient radiative transfer in a two-Layer inhomogeneous media subjected to a short square pulse irradiation is investigated. At last, the LBM is further extended to study the transient radiative transfer in homogeneous medium with a refractive index discontinuity irradiated by the short pulse laser. Several trends on the time-resolved signals different from those for refractive index of 1 (i.e. refractive-index-matched boundary) are observed and analysed.

  16. Tunneling and resonant conductance in one-dimensional molecular structures

    International Nuclear Information System (INIS)

    Kozhushner, M.A.; Posvyanskii, V.S.; Oleynik, I.I.

    2005-01-01

    We present a theory of tunneling and resonant transitions in one-dimensional molecular systems which is based on Green's function theory of electron sub-barrier scattering off the structural units (or functional groups) of a molecular chain. We show that the many-electron effects are of paramount importance in electron transport and they are effectively treated using a formalism of sub-barrier scattering operators. The method which calculates the total scattering amplitude of the bridge molecule not only predicts the enhancement of the amplitude of tunneling transitions in course of tunneling electron transfer through onedimensional molecular structures but also allows us to interpret conductance mechanisms by calculating the bound energy spectrum of the tunneling electron, the energies being obtained as poles of the total scattering amplitude of the bridge molecule. We found that the resonant tunneling via bound states of the tunneling electron is the major mechanism of electron conductivity in relatively long organic molecules. The sub-barrier scattering technique naturally includes a description of tunneling in applied electric fields which allows us to calculate I-V curves at finite bias. The developed theory is applied to explain experimental findings such as bridge effect due to tunneling through organic molecules, and threshold versus Ohmic behavior of the conductance due to resonant electron transfer

  17. New Poisson–Boltzmann type equations: one-dimensional solutions

    International Nuclear Information System (INIS)

    Lee, Chiun-Chang; Lee, Hijin; Hyon, YunKyong; Lin, Tai-Chia; Liu, Chun

    2011-01-01

    The Poisson–Boltzmann (PB) equation is conventionally used to model the equilibrium of bulk ionic species in different media and solvents. In this paper we study a new Poisson–Boltzmann type (PB n ) equation with a small dielectric parameter ε 2 and non-local nonlinearity which takes into consideration the preservation of the total amount of each individual ion. This equation can be derived from the original Poisson–Nernst–Planck system. Under Robin-type boundary conditions with various coefficient scales, we demonstrate the asymptotic behaviours of one-dimensional solutions of PB n equations as the parameter ε approaches zero. In particular, we show that in case of electroneutrality, i.e. α = β, solutions of 1D PB n equations have a similar asymptotic behaviour as those of 1D PB equations. However, as α ≠ β (non-electroneutrality), solutions of 1D PB n equations may have blow-up behaviour which cannot be found in 1D PB equations. Such a difference between 1D PB and PB n equations can also be verified by numerical simulations

  18. Localization properties of one-dimensional electrified chains

    International Nuclear Information System (INIS)

    Ouasti, R.; Brezini, A.; Zekri, N.

    1993-08-01

    A Kronig-Penney model with a constant electric filed for a non-interacting electron is used to study the transmission properties of Anderson transition in one-dimensional (1-D) systems with disordered strengths of δ-function potentials. we examined the cases where the potential varies uniformly from O to W (barriers) or from -W to O (wells) for a given disorder W. Mainly, we observe unexpected abrupt transition at the points E + Fx = n 2 π 2 . However, these transitions are related to the small oscillations observed by Soukoulis et al. in the mixed case (wells and barriers). An interesting feature in the wells is that in the presence of a small field the states become more localized and the localization length decrease up to a minimum for a critical value F m . In the end, we have studied the effect of the disorder on the Anderson transition by the mean of the participation ratio and the localization length. (author). 27 refs, 6 figs

  19. SUSY-hierarchy of one-dimensional reflectionless potentials

    International Nuclear Information System (INIS)

    Maydanyuk, Sergei P.

    2005-01-01

    A class of one-dimensional reflectionless potentials is studied. It is found that all possible types of the reflectionless potentials can be combined into one SUSY-hierarchy with a constant potential. An approach for determination of a general form of the reflectionless potential on the basis of construction of such a hierarchy by the recurrent method is proposed. A general integral form of interdependence between superpotentials with neighboring numbers of this hierarchy, opening a possibility to find new reflectionless potentials, is found and has a simple analytical view. It is supposed that any possible type of the reflectionless potential can be expressed through finite number of elementary functions (unlike some presentations of the reflectionless potentials, which are constructed on the basis of soliton solutions or are shape invariant in one or many steps with involving scaling of parameters, and are expressed through series). An analysis of absolute transparency existence for the potential which has the inverse power dependence on space coordinate (and here tunneling is possible), i.e., which has the form V (x) = ± α/ vertical bar x-x 0 vertical bar n (where α and x 0 are constants, n is natural number), is fulfilled. It is shown that such a potential can be reflectionless at n = 2 only. A SUSY-hierarchy of the inverse power reflectionless potentials is constructed. Isospectral expansions of this hierarchy are analyzed

  20. Periodic solutions for one dimensional wave equation with bounded nonlinearity

    Science.gov (United States)

    Ji, Shuguan

    2018-05-01

    This paper is concerned with the periodic solutions for the one dimensional nonlinear wave equation with either constant or variable coefficients. The constant coefficient model corresponds to the classical wave equation, while the variable coefficient model arises from the forced vibrations of a nonhomogeneous string and the propagation of seismic waves in nonisotropic media. For finding the periodic solutions of variable coefficient wave equation, it is usually required that the coefficient u (x) satisfies ess infηu (x) > 0 with ηu (x) = 1/2 u″/u - 1/4 (u‧/u)2, which actually excludes the classical constant coefficient model. For the case ηu (x) = 0, it is indicated to remain an open problem by Barbu and Pavel (1997) [6]. In this work, for the periods having the form T = 2p-1/q (p , q are positive integers) and some types of boundary value conditions, we find some fundamental properties for the wave operator with either constant or variable coefficients. Based on these properties, we obtain the existence of periodic solutions when the nonlinearity is monotone and bounded. Such nonlinearity may cross multiple eigenvalues of the corresponding wave operator. In particular, we do not require the condition ess infηu (x) > 0.

  1. Integral Transport Theory in One-dimensional Geometries

    Energy Technology Data Exchange (ETDEWEB)

    Carlvik, I

    1966-06-15

    A method called DIT (Discrete Integral Transport) has been developed for the numerical solution of the transport equation in one-dimensional systems. The characteristic features of the method are Gaussian integration over the coordinate as described by Kobayashi and Nishihara, and a particular scheme for the calculation of matrix elements in annular and spherical geometry that has been used for collision probabilities in earlier Flurig programmes. The paper gives a general theory including such things as anisotropic scattering and multi-pole fluxes, and it gives a brief description of the Flurig scheme. Annular geometry is treated in some detail, and corresponding formulae are given for spherical and plane geometry. There are many similarities between DIT and the method of collision probabilities. DIT is in many cases faster, because for a certain accuracy in the fluxes DIT often needs fewer space points than the method of collision probabilities needs regions. Several computer codes using DIT, both one-group and multigroup, have been written. It is anticipated that experience gained in calculations with these codes will be reported in another paper.

  2. Quantum one dimensional spin systems. Disorder and impurities

    International Nuclear Information System (INIS)

    Brunel, V.

    1999-01-01

    This thesis presents three studies that are respectively the spin-1 disordered chain, the non magnetic impurities in the spin-1/2 chain and the reaction-diffusion process. The spin-1 chain of weak disorder is performed by the Abelian bosonization and the renormalization group. This allows to take into account the competition between the disorder and the interactions and predicts the effects of various spin-1 anisotropy chain phases under many different disorders. A second work uses the non magnetic impurities as local probes of the correlations in the spin-1/2 chain. When the impurities are connected to the chain boundary, the author predicts a temperature dependence of the relaxation rate (1/T) of the nuclear spin impurities, different from the case of these impurities connected to the whole chain. The last work deals with one dimensional reaction-diffusion problem. The Jordan-Wigner transformation allows to consider a fermionic field theory that critical exponents follow from the renormalization group. (A.L.B.)

  3. One-dimensional long-range percolation: A numerical study

    Science.gov (United States)

    Gori, G.; Michelangeli, M.; Defenu, N.; Trombettoni, A.

    2017-07-01

    In this paper we study bond percolation on a one-dimensional chain with power-law bond probability C /rd +σ , where r is the distance length between distinct sites and d =1 . We introduce and test an order-N Monte Carlo algorithm and we determine as a function of σ the critical value Cc at which percolation occurs. The critical exponents in the range 0 values for Cc are compared with a known exact bound, while the critical exponent ν is compared with results from mean-field theory, from an expansion around the point σ =1 and from the ɛ -expansion used with the introduction of a suitably defined effective dimension deff relating the long-range model with a short-range one in dimension deff. We finally present a formulation of our algorithm for bond percolation on general graphs, with order N efficiency on a large class of graphs including short-range percolation and translationally invariant long-range models in any spatial dimension d with σ >0 .

  4. Magnetic ordering in arrays of one-dimensional nanoparticle chains

    International Nuclear Information System (INIS)

    Serantes, D; Baldomir, D; Pereiro, M; Hernando, B; Prida, V M; Sanchez Llamazares, J L; Zhukov, A; Ilyn, M; Gonzalez, J

    2009-01-01

    The magnetic order in parallel-aligned one-dimensional (1D) chains of magnetic nanoparticles is studied using a Monte Carlo technique. If the easy anisotropy axes are collinear along the chains a macroscopic mean-field approach indicates antiferromagnetic (AFM) order even when no interparticle interactions are taken into account, which evidences that a mean-field treatment is inadequate for the study of the magnetic order in these highly anisotropic systems. From the direct microscopic analysis of the evolution of the magnetic moments, we observe spontaneous intra-chain ferromagnetic (FM)-type and inter-chain AFM-type ordering at low temperatures (although not completely regular) for the easy-axes collinear case, whereas a random distribution of the anisotropy axes leads to a sort of intra-chain AFM arrangement with no inter-chain regular order. When the magnetic anisotropy is neglected a perfectly regular intra-chain FM-like order is attained. Therefore it is shown that the magnetic anisotropy, and particularly the spatial distribution of the easy axes, is a key parameter governing the magnetic ordering type of 1D-nanoparticle chains.

  5. Validation and Comparison of One-Dimensional Ground Motion Methodologies

    International Nuclear Information System (INIS)

    B. Darragh; W. Silva; N. Gregor

    2006-01-01

    Both point- and finite-source stochastic one-dimensional ground motion models, coupled to vertically propagating equivalent-linear shear-wave site response models are validated using an extensive set of strong motion data as part of the Yucca Mountain Project. The validation and comparison exercises are presented entirely in terms of 5% damped pseudo absolute response spectra. The study consists of a quantitative analyses involving modeling nineteen well-recorded earthquakes, M 5.6 to 7.4 at over 600 sites. The sites range in distance from about 1 to about 200 km in the western US (460 km for central-eastern US). In general, this validation demonstrates that the stochastic point- and finite-source models produce accurate predictions of strong ground motions over the range of 0 to 100 km and for magnitudes M 5.0 to 7.4. The stochastic finite-source model appears to be broadband, producing near zero bias from about 0.3 Hz (low frequency limit of the analyses) to the high frequency limit of the data (100 and 25 Hz for response and Fourier amplitude spectra, respectively)

  6. Energy Current Cumulants in One-Dimensional Systems in Equilibrium

    Science.gov (United States)

    Dhar, Abhishek; Saito, Keiji; Roy, Anjan

    2018-06-01

    A recent theory based on fluctuating hydrodynamics predicts that one-dimensional interacting systems with particle, momentum, and energy conservation exhibit anomalous transport that falls into two main universality classes. The classification is based on behavior of equilibrium dynamical correlations of the conserved quantities. One class is characterized by sound modes with Kardar-Parisi-Zhang scaling, while the second class has diffusive sound modes. The heat mode follows Lévy statistics, with different exponents for the two classes. Here we consider heat current fluctuations in two specific systems, which are expected to be in the above two universality classes, namely, a hard particle gas with Hamiltonian dynamics and a harmonic chain with momentum conserving stochastic dynamics. Numerical simulations show completely different system-size dependence of current cumulants in these two systems. We explain this numerical observation using a phenomenological model of Lévy walkers with inputs from fluctuating hydrodynamics. This consistently explains the system-size dependence of heat current fluctuations. For the latter system, we derive the cumulant-generating function from a more microscopic theory, which also gives the same system-size dependence of cumulants.

  7. Electroconvection in one-dimensional liquid crystal cells

    Science.gov (United States)

    Huh, Jong-Hoon

    2018-04-01

    We investigate the alternating current (ac) -driven electroconvection (EC) in one-dimensional cells (1DCs) under the in-plane switching mode. In 1DCs, defect-free EC can be realized. In the presence and absence of external multiplicative noise, the features of traveling waves (TWs), such as their Hopf frequency fH and velocity, are examined in comparison with those of conventional two-dimensional cells (2DCs) accompanying defects of EC rolls. In particular, we show that the defects significantly contribute to the features of the TWs. Additionally, owing to the defect-free EC in the 1DCs, the effects of the ac and noise fields on the TW are clarified. The ac field linearly increases fH, independent of the ac frequency f . The noise increases fH monotonically, but fH does not vary below a characteristic noise intensity VN*. In addition, soliton-like waves and unfamiliar oscillation of EC vortices in 1DCs are observed, in contrast to the localized EC (called worms) and the oscillation of EC rolls in 2DCs.

  8. 17th century treatments of one-dimensional collisions

    International Nuclear Information System (INIS)

    Goehring, G.D.

    1975-01-01

    The issue of conservation in the collisions of bodies aroused considerable interest in the period of its initial investigation. Descartes asserted that the quantity of motion, the scalar product of the mass and speed, was the quantity that was conserved. Huygens, with the aid of his relativity of motion principle, recognized that it was not Descartes' scalar quantity that was conserved, but instead another scalar quality, the product of the mass and the square of the speed, whose total remained constant. Newton discovered that Descartes' quantity was conserved if considered a vector quantity, and thereby announced the principle of conservation of momentum. Leibniz recognized the conservation of Newton's momentum, and also the conservation of vis viva, the same scalar quantity that Huygens has earlier proposed. Although recognition of the immense importance of these principles had to await further developments in physics, the original formulation of these conservation principles, resulting from the analysis of one-dimensional collisions, was completed by the end of the 17th century. (U.K.)

  9. Negative refraction angular characterization in one-dimensional photonic crystals.

    Directory of Open Access Journals (Sweden)

    Jesus Eduardo Lugo

    2011-04-01

    Full Text Available Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity developed here. We also analytically derived the negative refraction correctness condition that gives the angular region where negative refraction occurs.By using standard photonic techniques we experimentally determined the relationship between incidence and negative refraction angles and found the negative refraction range by applying the correctness condition. In order to compare both theories with experimental results an output refraction correction was utilized. The correction uses Snell's law and an effective refractive index based on two effective dielectric constants. We found good agreement between experiment and both theories in the negative refraction zone.Since both theories and the experimental observations agreed well in the negative refraction region, we can use both negative refraction theories plus the output correction to predict negative refraction angles. This can be very useful from a practical point of view for space filtering applications such as a photonic demultiplexer or for sensing applications.

  10. Negative refraction angular characterization in one-dimensional photonic crystals.

    Science.gov (United States)

    Lugo, Jesus Eduardo; Doti, Rafael; Faubert, Jocelyn

    2011-04-06

    Photonic crystals are artificial structures that have periodic dielectric components with different refractive indices. Under certain conditions, they abnormally refract the light, a phenomenon called negative refraction. Here we experimentally characterize negative refraction in a one dimensional photonic crystal structure; near the low frequency edge of the fourth photonic bandgap. We compare the experimental results with current theory and a theory based on the group velocity developed here. We also analytically derived the negative refraction correctness condition that gives the angular region where negative refraction occurs. By using standard photonic techniques we experimentally determined the relationship between incidence and negative refraction angles and found the negative refraction range by applying the correctness condition. In order to compare both theories with experimental results an output refraction correction was utilized. The correction uses Snell's law and an effective refractive index based on two effective dielectric constants. We found good agreement between experiment and both theories in the negative refraction zone. Since both theories and the experimental observations agreed well in the negative refraction region, we can use both negative refraction theories plus the output correction to predict negative refraction angles. This can be very useful from a practical point of view for space filtering applications such as a photonic demultiplexer or for sensing applications.

  11. One-dimensional quantum walk with a moving boundary

    International Nuclear Information System (INIS)

    Kwek, Leong Chuan; Setiawan

    2011-01-01

    Quantum walks are interesting models with potential applications to quantum algorithms and physical processes such as photosynthesis. In this paper, we study two models of one-dimensional quantum walks, namely, quantum walks with a moving absorbing wall and quantum walks with one stationary and one moving absorbing wall. For the former, we calculate numerically the survival probability, the rate of change of average position, and the rate of change of standard deviation of the particle's position in the long time limit for different wall velocities. Moreover, we also study the asymptotic behavior and the dependence of the survival probability on the initial particle's state. While for the latter, we compute the absorption probability of the right stationary wall for different velocities and initial positions of the left wall boundary. The results for these two models are compared with those obtained for the classical model. The difference between the results obtained for the quantum and classical models can be attributed to the difference in the probability distributions.

  12. Numerical modelling of random walk one-dimensional diffusion

    International Nuclear Information System (INIS)

    Vamos, C.; Suciu, N.; Peculea, M.

    1996-01-01

    The evolution of a particle which moves on a discrete one-dimensional lattice, according to a random walk low, approximates better the diffusion process smaller the steps of the spatial lattice and time are. For a sufficiently large assembly of particles one can assume that their relative frequency at lattice knots approximates the distribution function of the diffusion process. This assumption has been tested by simulating on computer two analytical solutions of the diffusion equation: the Brownian motion and the steady state linear distribution. To evaluate quantitatively the similarity between the numerical and analytical solutions we have used a norm given by the absolute value of the difference of the two solutions. Also, a diffusion coefficient at any lattice knots and moment of time has been calculated, by using the numerical solution both from the diffusion equation and the particle flux given by Fick's low. The difference between diffusion coefficient of analytical solution and the spatial lattice mean coefficient of numerical solution constitutes another quantitative indication of the similarity of the two solutions. The results obtained show that the approximation depends first on the number of particles at each knot of the spatial lattice. In conclusion, the random walk is a microscopic process of the molecular dynamics type which permits simulations precision of the diffusion processes with given precision. The numerical method presented in this work may be useful both in the analysis of real experiments and for theoretical studies

  13. Fractal geometry in an expanding, one-dimensional, Newtonian universe.

    Science.gov (United States)

    Miller, Bruce N; Rouet, Jean-Louis; Le Guirriec, Emmanuel

    2007-09-01

    Observations of galaxies over large distances reveal the possibility of a fractal distribution of their positions. The source of fractal behavior is the lack of a length scale in the two body gravitational interaction. However, even with new, larger, sample sizes from recent surveys, it is difficult to extract information concerning fractal properties with confidence. Similarly, three-dimensional N-body simulations with a billion particles only provide a thousand particles per dimension, far too small for accurate conclusions. With one-dimensional models these limitations can be overcome by carrying out simulations with on the order of a quarter of a million particles without compromising the computation of the gravitational force. Here the multifractal properties of two of these models that incorporate different features of the dynamical equations governing the evolution of a matter dominated universe are compared. For each model at least two scaling regions are identified. By employing criteria from dynamical systems theory it is shown that only one of them can be geometrically significant. The results share important similarities with galaxy observations, such as hierarchical clustering and apparent bifractal geometry. They also provide insights concerning possible constraints on length and time scales for fractal structure. They clearly demonstrate that fractal geometry evolves in the mu (position, velocity) space. The observed patterns are simply a shadow (projection) of higher-dimensional structure.

  14. MARG1D: One dimensional outer region matching data code

    International Nuclear Information System (INIS)

    Tokuda, Shinji; Watanabe, Tomoko.

    1995-08-01

    A code MARG1D has been developed which computes outer region matching data of the one dimensional Newcomb equation. Matching data play an important role in the resistive (and non ideal) Magneto-hydrodynamic (MHD) stability analysis in a tokamak plasma. The MARG1D code computes matching data by using the boundary value method or by the eigenvalue method. Variational principles are derived for the problems to be solved and a finite element method is applied. Except for the case of marginal stability, the eigenvalue method is equivalent to the boundary value method. However, the eigenvalue method has the several advantages: it is a new method of ideal MHD stability analysis for which the marginally stable state can be identified, and it guarantees numerical stability in computing matching data close to marginal stability. We perform detailed numerical experiments for a model equation with analytical solutions and for the Newcomb equation in the m=1 mode theory. Numerical experiments show that MARG1D code gives the matching data with numerical stability and high accuracy. (author)

  15. One-dimensional magnetophotonic crystals with magnetooptical double layers

    International Nuclear Information System (INIS)

    Berzhansky, V. N.; Shaposhnikov, A. N.; Prokopov, A. R.; Karavainikov, A. V.; Mikhailova, T. V.; Lukienko, I. N.; Kharchenko, Yu. N.; Golub, V. O.; Salyuk, O. Yu.; Belotelov, V. I.

    2016-01-01

    One-dimensional magnetophotonic microcavity crystals with nongarnet dielectric mirrors are created and investigated. The defect layers in the magnetophotonic crystals are represented by two bismuth-substituted yttrium iron garnet Bi:YIG layers with various bismuth contents in order to achieve a high magnetooptical response of the crystals. The parameters of the magnetophotonic crystal layers are optimized by numerical solution of the Maxwell equations by the transfer matrix method to achieve high values of Faraday rotation angle Θ F and magnetooptical Q factor. The calculated and experimental data agree well with each other. The maximum values of Θ F =–20.6°, Q = 8.1° at a gain t = 16 are obtained for magnetophotonic crystals with m = 7 pairs of layers in Bragg mirrors, and the parameters obtained for crystals with m = 4 and t = 8.5 are Θ F =–12.5° and Q = 14.3°. It is shown that, together with all-garnet and multimicrocavities magnetophotonic crystals, such structures have high magnetooptical characteristics.

  16. One-dimensional magnetophotonic crystals with magnetooptical double layers

    Energy Technology Data Exchange (ETDEWEB)

    Berzhansky, V. N., E-mail: v.n.berzhansky@gmail.com; Shaposhnikov, A. N.; Prokopov, A. R.; Karavainikov, A. V.; Mikhailova, T. V. [V.I. Vernadsky Crimean Federal University (Russian Federation); Lukienko, I. N.; Kharchenko, Yu. N., E-mail: kharcenko@ilt.kharkov.ua [National Academy of Sciences of Ukraine, Verkin Institute for Low Temperature Physics and Engineering (Ukraine); Golub, V. O., E-mail: v-o-golub@yahoo.com; Salyuk, O. Yu. [National Academy of Sciences of Ukraine, Institute of Magnetism (Ukraine); Belotelov, V. I., E-mail: belotelov@physics.msu.ru [Russian Quantum Center (Russian Federation)

    2016-11-15

    One-dimensional magnetophotonic microcavity crystals with nongarnet dielectric mirrors are created and investigated. The defect layers in the magnetophotonic crystals are represented by two bismuth-substituted yttrium iron garnet Bi:YIG layers with various bismuth contents in order to achieve a high magnetooptical response of the crystals. The parameters of the magnetophotonic crystal layers are optimized by numerical solution of the Maxwell equations by the transfer matrix method to achieve high values of Faraday rotation angle Θ{sub F} and magnetooptical Q factor. The calculated and experimental data agree well with each other. The maximum values of Θ{sub F} =–20.6°, Q = 8.1° at a gain t = 16 are obtained for magnetophotonic crystals with m = 7 pairs of layers in Bragg mirrors, and the parameters obtained for crystals with m = 4 and t = 8.5 are Θ{sub F} =–12.5° and Q = 14.3°. It is shown that, together with all-garnet and multimicrocavities magnetophotonic crystals, such structures have high magnetooptical characteristics.

  17. Approximate approaches to the one-dimensional finite potential well

    International Nuclear Information System (INIS)

    Singh, Shilpi; Pathak, Praveen; Singh, Vijay A

    2011-01-01

    The one-dimensional finite well is a textbook problem. We propose approximate approaches to obtain the energy levels of the well. The finite well is also encountered in semiconductor heterostructures where the carrier mass inside the well (m i ) is taken to be distinct from mass outside (m o ). A relevant parameter is the mass discontinuity ratio β = m i /m o . To correctly account for the mass discontinuity, we apply the BenDaniel-Duke boundary condition. We obtain approximate solutions for two cases: when the well is shallow and when the well is deep. We compare the approximate results with the exact results and find that higher-order approximations are quite robust. For the shallow case, the approximate solution can be expressed in terms of a dimensionless parameter σ l = 2m o V 0 L 2 /ℎ 2 (or σ = β 2 σ l for the deep case). We show that the lowest-order results are related by a duality transform. We also discuss how the energy upscales with L (E∼1/L γ ) and obtain the exponent γ. Exponent γ → 2 when the well is sufficiently deep and β → 1. The ratio of the masses dictates the physics. Our presentation is pedagogical and should be useful to students on a first course on elementary quantum mechanics or low-dimensional semiconductors.

  18. Validation and Comparison of One-Dimensional Graound Motion Methodologies

    Energy Technology Data Exchange (ETDEWEB)

    B. Darragh; W. Silva; N. Gregor

    2006-06-28

    Both point- and finite-source stochastic one-dimensional ground motion models, coupled to vertically propagating equivalent-linear shear-wave site response models are validated using an extensive set of strong motion data as part of the Yucca Mountain Project. The validation and comparison exercises are presented entirely in terms of 5% damped pseudo absolute response spectra. The study consists of a quantitative analyses involving modeling nineteen well-recorded earthquakes, M 5.6 to 7.4 at over 600 sites. The sites range in distance from about 1 to about 200 km in the western US (460 km for central-eastern US). In general, this validation demonstrates that the stochastic point- and finite-source models produce accurate predictions of strong ground motions over the range of 0 to 100 km and for magnitudes M 5.0 to 7.4. The stochastic finite-source model appears to be broadband, producing near zero bias from about 0.3 Hz (low frequency limit of the analyses) to the high frequency limit of the data (100 and 25 Hz for response and Fourier amplitude spectra, respectively).

  19. Polynuclear and one-dimensional cyanide-bridged heterobimetallic ...

    Indian Academy of Sciences (India)

    JINGWEN SHI

    2018-02-07

    Feb 7, 2018 ... complexes: synthesis, crystal structures and magnetic properties. JINGWEN ... Introduction. In the recent past decades, many effective strategies have ..... organization of single molecule magnets on surfaces. Chem. Soc. Rev. ... Spin Crossover Coordination Polymer Cryst. Growth. Des. 17 2736. 17. Kaneko ...

  20. Shell-crossing in quasi-one-dimensional flow

    Science.gov (United States)

    Rampf, Cornelius; Frisch, Uriel

    2017-10-01

    Blow-up of solutions for the cosmological fluid equations, often dubbed shell-crossing or orbit crossing, denotes the breakdown of the single-stream regime of the cold-dark-matter fluid. At this instant, the velocity becomes multi-valued and the density singular. Shell-crossing is well understood in one dimension (1D), but not in higher dimensions. This paper is about quasi-one-dimensional (Q1D) flow that depends on all three coordinates but differs only slightly from a strictly 1D flow, thereby allowing a perturbative treatment of shell-crossing using the Euler-Poisson equations written in Lagrangian coordinates. The signature of shell-crossing is then just the vanishing of the Jacobian of the Lagrangian map, a regular perturbation problem. In essence, the problem of the first shell-crossing, which is highly singular in Eulerian coordinates, has been desingularized by switching to Lagrangian coordinates, and can then be handled by perturbation theory. Here, all-order recursion relations are obtained for the time-Taylor coefficients of the displacement field, and it is shown that the Taylor series has an infinite radius of convergence. This allows the determination of the time and location of the first shell-crossing, which is generically shown to be taking place earlier than for the unperturbed 1D flow. The time variable used for these statements is not the cosmic time t but the linear growth time τ ˜ t2/3. For simplicity, calculations are restricted to an Einstein-de Sitter universe in the Newtonian approximation, and tailored initial data are used. However it is straightforward to relax these limitations, if needed.

  1. Research on one-dimensional two-phase flow

    International Nuclear Information System (INIS)

    Adachi, Hiromichi

    1988-10-01

    In Part I the fundamental form of the hydrodynamic basic equations for a one-dimensional two-phase flow (two-fluid model) is described. Discussions are concentrated on the treatment of phase change inertial force terms in the equations of motion and the author's equations of motion which have a remarkable uniqueness on the following three points. (1) To express force balance of unit mass two-phase fluid instead of that of unit volume two-phase fluid. (2) To pick up the unit existing mass and the unit flowing mass as the unit mass of two-phase fluid. (3) To apply the kinetic energy principle instead of the momentum low in the evaluation of steady inertial force term. In these three, the item (1) is for excluding a part of momentum change or kinetic energy change due to mass change of the examined part of fluid, which is independent of force. The item (2) is not to introduce a phenomenological physical model into the evaluation of phase change inertial force term. And the item (3) is for correctly applying the momentum law taking into account the difference of representative velocities between the main flow fluid (vapor phase or liquid phase) and the phase change part of fluid. In Part II, characteristics of various kinds of high speed two-phase flow are clarified theoretically by the basic equations derived. It is demonstrated that the steam-water two-phase critical flow with violent flashing and the airwater two-phase critical flow without phase change can be described with fundamentally the same basic equations. Furthermore, by comparing the experimental data from the two-phase critical discharge test and the theoretical prediction, the two-phase discharge coefficient, C D , for large sharp-edged orifice is determined as the value which is not affected by the experimental facility characteristics, etc. (author)

  2. Fractal spectra in generalized Fibonacci one-dimensional magnonic quasicrystals

    Energy Technology Data Exchange (ETDEWEB)

    Costa, C.H.O. [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio grande do Norte, 59072-970 Natal-RN (Brazil); Vasconcelos, M.S., E-mail: manoelvasconcelos@yahoo.com.br [Escola de Ciencias e Tecnologia, Universidade Federal do Rio grande do Norte, 59072-970 Natal-RN (Brazil); Barbosa, P.H.R.; Barbosa Filho, F.F. [Departamento de Fisica, Universidade Federal do Piaui, 64049-550 Teresina-Pi (Brazil)

    2012-07-15

    In this work we carry out a theoretical analysis of the spectra of magnons in quasiperiodic magnonic crystals arranged in accordance with generalized Fibonacci sequences in the exchange regime, by using a model based on a transfer-matrix method together random-phase approximation (RPA). The generalized Fibonacci sequences are characterized by an irrational parameter {sigma}(p,q), which rules the physical properties of the system. We discussed the magnonic fractal spectra for first three generalizations, i.e., silver, bronze and nickel mean. By varying the generation number, we have found that the fragmentation process of allowed bands makes possible the emergence of new allowed magnonic bulk bands in spectra regions that were magnonic band gaps before, such as which occurs in doped semiconductor devices. This interesting property arises in one-dimensional magnonic quasicrystals fabricated in accordance to quasiperiodic sequences, without the need to introduce some deferent atomic layer or defect in the system. We also make a qualitative and quantitative investigations on these magnonic spectra by analyzing the distribution and magnitude of allowed bulk bands in function of the generalized Fibonacci number F{sub n} and as well as how they scale as a function of the number of generations of the sequences, respectively. - Highlights: Black-Right-Pointing-Pointer Quasiperiodic magnonic crystals are arranged in accordance with the generalized Fibonacci sequence. Black-Right-Pointing-Pointer Heisenberg model in exchange regime is applied. Black-Right-Pointing-Pointer We use a theoretical model based on a transfer-matrix method together random-phase approximation. Black-Right-Pointing-Pointer Fractal spectra are characterized. Black-Right-Pointing-Pointer We analyze the distribution of allowed bulk bands in function of the generalized Fibonacci number.

  3. One-Dimensional Contact Mode Interdigitated Center of Pressure Sensor (CMIPS)

    Science.gov (United States)

    Xu, Tian-Bing; Kang, Jinho; Park, Cheol; Harrison, Joycelyn S.; Guerreiro, Nelson M.; Hubbard, James E.

    2009-01-01

    A one dimensional contact mode interdigitated center of pressure sensor (CMIPS) has been developed. The experimental study demonstrated that the CMIPS has the capability to measure the overall pressure as well as the center of pressure in one dimension, simultaneously. A theoretical model for the CMIPS is established here based on the equivalent circuit of the configuration of the CMIPS as well as the material properties of the sensor. The experimental results match well with theoretical modeling predictions. A system mapped with two or more pieces of the CMIPS can be used to obtain information from the pressure distribution in multi-dimensions.

  4. Hierarchical one-dimensional ammonium nickel phosphate microrods for high-performance pseudocapacitors

    CSIR Research Space (South Africa)

    Raju, K

    2015-12-01

    Full Text Available :17629 | DOI: 10.1038/srep17629 www.nature.com/scientificreports Hierarchical One-Dimensional Ammonium Nickel Phosphate Microrods for High-Performance Pseudocapacitors Kumar Raju1 & Kenneth I. Ozoemena1,2 High-performance electrochemical capacitors... OPEN w w w . n a t u r e . c o m / s c i e n t i f i c r e p o r t s / 2S C I E N T I F I C REPORTS | 5:17629 | DOI: 10.1038/srep17629 Hierarchical 1-D and 2-D materials maximize the supercapacitive properties due to their unique ability to permit ion...

  5. Illusion optics via one-dimensional ultratransparent photonic crystals with shifted spatial dispersions.

    Science.gov (United States)

    Yao, Zhongqi; Luo, Jie; Lai, Yun

    2017-12-11

    In this work, we propose that one-dimensional ultratransparent dielectric photonic crystals with wide-angle impedance matching and shifted elliptical equal frequency contours are promising candidate materials for illusion optics. The shift of the equal frequency contour does not affect the refractive behaviors, but enables a new degree of freedom in phase modulation. With such ultratransparent photonic crystals, we demonstrate some applications in illusion optics, including creating illusions of a different-sized scatterer and a shifted source with opposite phase. Such ultratransparent dielectric photonic crystals may establish a feasible platform for illusion optics devices at optical frequencies.

  6. Observation of large photonic band gaps and defect modes in one-dimensional networked waveguides

    CERN Document Server

    Mir, A; Vasseur, J O; Djafari-Rouhani, B; Fettouhi, N; Boudouti, E H E; Dobrzynski, L; Zemmouri, J

    2003-01-01

    The photonic band structures and transmission spectra of serial loop structures (SLSs), made of loops pasted together with segments of finite length, are investigated experimentally and theoretically. These monomode structures, composed of one-dimensional dielectric materials, may exhibit large stop bands where the propagation of electromagnetic waves is forbidden. The width of these band gaps depends on the geometrical and compositional parameters of the structure and may be drastically increased in a tandem geometry made up of several successive SLSs which differ in their physical characteristics. These SLSs may have potential applications as ultrawide-band filters.

  7. Dispersion relation of electromagnetic waves in one-dimensional plasma photonic crystals

    International Nuclear Information System (INIS)

    Hojo, Hitoshi; Mase, Atsushi

    2004-01-01

    The dispersion relation of electromagnetic waves in one-dimensional plasma photonic crystals is studied. The plasma photonic crystal is a periodic array composed of alternating thin plasma and dielectric material. The dispersion relation is obtained by solving a Maxwell wave equation using a method analogous to Kronig-Penny's problem in quantum mechanics, and it is found that the frequency gap and cut-off appear in the dispersion relation. The frequency gap is shown to become larger with the increase of the plasma density as well as plasma width. (author)

  8. Some optical properties of one dimensional annular photonic crystal with plasma frequency

    Science.gov (United States)

    Pandeya, G. N.; Thapa, Khem B.

    2018-05-01

    This paper presents the reflection bands, photonic band gaps, of the one-dimensional annul photonic crystal (APC) containing double negative (DNG) metamaterials and air. The proposed annular structure consists of the alternate layers of dispersive DNG material and air immersed in free space. The reflectance properties of the APC by employing the transfer matrix method (TMM) in the cylindrical waves for TE polarization is studied theoretically. In addition of this, we have also studied the effect of plasma frequency on the reflection behavior of the considered annular structure.

  9. Temporal coupled mode analysis of one-dimensional magneto-photonic crystals with cavity structures

    Energy Technology Data Exchange (ETDEWEB)

    Saghirzadeh Darki, Behnam, E-mail: b.saghirzadeh@ec.iut.ac.ir; Zeidaabadi Nezhad, Abolghasem; Firouzeh, Zaker Hossein

    2016-12-01

    In this paper, we propose the time-dependent coupled mode analysis of one-dimensional magneto-photonic crystals including one, two or multiple defect layers. The performance of the structures, namely the total transmission, Faraday rotation and ellipticity, is obtained using the proposed method. The results of the developed analytic approach are verified by comparing them to the results of the exact numerical transfer matrix method. Unlike the widely used numerical method, our proposed analytic method seems promising for the synthesis as well as the analysis purposes. Moreover, the proposed method has not the restrictions of the previously examined analytic methods. - Highlights: • A time-dependent coupled mode analysis is proposed for the cavity-type 1D MPCs. • Analytical formalism is presented for the single, double and multiple-defect MPCs. • Transmission, Faraday rotation and ellipticity are gained using the proposed method. • The proposed analytic method has advantages over the previously examined methods.

  10. Hydrogen atom trapping in a self-organized one-dimensional dimer

    Directory of Open Access Journals (Sweden)

    Tsuyoshi Takami

    2014-09-01

    Full Text Available Metal–organic frameworks (MOFs have attracted widespread attention owing to their unusual structure and properties produced by their nanospaces. However, many MOFs possess the similar three-dimensional frameworks, limiting their structural variety and operating capacity for hydrogen storage under ambient conditions. Here we report the synthesis and structural characterization of a single-crystal one-dimensional dimer whose structure, operating capacity, and physical mechanism contrast with those of existing MOFs. The hydrogen storage capacity of 2.6 wt.% is comparable to the highest capacity achieved by existing MOFs at room temperature. This exceptional storage capacity is realized by self-organization during crystal growth using a weak base.

  11. Thermal conductivity engineering of bulk and one-dimensional Si-Ge nanoarchitectures.

    Science.gov (United States)

    Kandemir, Ali; Ozden, Ayberk; Cagin, Tahir; Sevik, Cem

    2017-01-01

    Various theoretical and experimental methods are utilized to investigate the thermal conductivity of nanostructured materials; this is a critical parameter to increase performance of thermoelectric devices. Among these methods, equilibrium molecular dynamics (EMD) is an accurate technique to predict lattice thermal conductivity. In this study, by means of systematic EMD simulations, thermal conductivity of bulk Si-Ge structures (pristine, alloy and superlattice) and their nanostructured one dimensional forms with square and circular cross-section geometries (asymmetric and symmetric) are calculated for different crystallographic directions. A comprehensive temperature analysis is evaluated for selected structures as well. The results show that one-dimensional structures are superior candidates in terms of their low lattice thermal conductivity and thermal conductivity tunability by nanostructuring, such as by diameter modulation, interface roughness, periodicity and number of interfaces. We find that thermal conductivity decreases with smaller diameters or cross section areas. Furthermore, interface roughness decreases thermal conductivity with a profound impact. Moreover, we predicted that there is a specific periodicity that gives minimum thermal conductivity in symmetric superlattice structures. The decreasing thermal conductivity is due to the reducing phonon movement in the system due to the effect of the number of interfaces that determine regimes of ballistic and wave transport phenomena. In some nanostructures, such as nanowire superlattices, thermal conductivity of the Si/Ge system can be reduced to nearly twice that of an amorphous silicon thermal conductivity. Additionally, it is found that one crystal orientation, [Formula: see text]100[Formula: see text], is better than the [Formula: see text]111[Formula: see text] crystal orientation in one-dimensional and bulk SiGe systems. Our results clearly point out the importance of lattice thermal conductivity

  12. Topo synthesis in the presence of microporous materials

    International Nuclear Information System (INIS)

    Meddour, L.; Hamidi, A.; Boudjellah-Nahnah, N.

    1997-02-01

    In the present work, we have done an amelioration of TOPO synthesis based on the PC13, with introducing the differents microporous materials in the synthesis mixture. The catalysts used are the Faujasite Y,ZSM-5, SAPO-11. From the results of this work, we estabilished that some catalyst are performed

  13. Kinetic Monte Carlo studies of the reaction kinetics of crystal defects that diffuse one-dimensionally with occasional transverse migration

    DEFF Research Database (Denmark)

    Heinisch, H.L.; Trinkaus, H.; Singh, Bachu Narain

    2007-01-01

    The reaction kinetics of the various species of mobile defects in irradiated materials are crucially dependent on the dimensionality of their migration. Sink strengths for one-dimensionally (1D) gliding interstitial loops undergoing occasional direction changes have been described analytically...

  14. Use of energetic ion beams in materials synthesis and processing

    International Nuclear Information System (INIS)

    Appleton, B.R.

    1992-01-01

    A brief review of the use energetic ion beams and related techniques for the synthesis, processing, and characterization of materials is presented. Selected opportunity areas are emphasized with examples, and references are provided for more extensive coverage. (author)

  15. Bi[NC5H3(CO2)2](OH2)xF (x=1 and 2): New one-dimensional Bi-coordination materials—Reversible hydration and topotactic decomposition to α-Bi2O3

    International Nuclear Information System (INIS)

    Jeon, Hye Rim; Lee, Dong Woo; Ok, Kang Min

    2012-01-01

    Two one-dimensional bismuth-coordination materials, Bi[NC 5 H 3 (CO 2 ) 2 ](OH 2 ) x F (x=1 and 2), have been synthesized by hydrothermal reactions using Bi 2 O 3 , 2,6-NC 5 H 3 (CO 2 H) 2 , HF, and water at 180 °C. Structures of the two materials were determined by single-crystal X-ray diffraction. Although they have different crystal structures, both Bi-organic materials shared a common structural motif, a one-dimensional chain structure consisting of Bi 3+ cations and pyridine dicarboxylate linkers. Detailed structural analyses include infrared spectroscopy, thermogravimetric analysis, and reversible hydration reactions for the coordinated water molecules were reported. Also, thermal decomposition of the rod-shaped Bi[NC 5 H 3 (CO 2 ) 2 ](OH 2 )F single crystals at 800 °C led to α-Bi 2 O 3 that maintained the same morphology of the original crystals. - Graphical abstract: Calcination of the Bi[NC 5 H 3 (CO 2 ) 2 ](OH 2 )F single crystals at 800 °C results in the α-Bi 2 O 3 rods that maintain the original morphology of the crystals. Highlights: ► Synthesis of one-dimensional chain Bi-organic frameworks. ► Reversible hydration reactions of Bi[NC 5 H 3 (CO 2 ) 2 ](OH 2 )F. ► Topotactic decomposition maintaining the same morphology of the original crystals.

  16. Role of open boundary conditions on the hysteretic behaviour of one-dimensional spin crossover nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Chiruta, Daniel [GEMaC, Université de Versailles Saint-Quentin-en-Yvelines, CNRS-UVSQ (UMR 8635), 78035 Versailles Cedex (France); Faculty of Electrical Engineering and Computer Science, Stefan cel Mare University, Suceava 720229 (Romania); Linares, Jorge, E-mail: jorge.linares@uvsq.fr, E-mail: miya@spin.phys.s.u-tokyo.ac.jp; Boukheddaden, Kamel [GEMaC, Université de Versailles Saint-Quentin-en-Yvelines, CNRS-UVSQ (UMR 8635), 78035 Versailles Cedex (France); Miyashita, Seiji, E-mail: jorge.linares@uvsq.fr, E-mail: miya@spin.phys.s.u-tokyo.ac.jp [Department of Physics, Graduate School of Science, University of Tokyo, Bunkyo-Ku, Tokyo (Japan); CREST, JST, 4-1-8 Honcho Kawaguchi, Saitama 332-0012 (Japan)

    2014-05-21

    In order to explain clearly the role of the open boundary conditions (OBCs) on phase transition in one dimensional system, we consider an Ising model with both short-range (J) and long-range (G) interactions, which has allowed us to study the cooperative nature of spin-crossover (SCO) materials at the nanometer scale. At this end, we developed a transfer-matrix method for one-dimensional (1D) SCO system with free boundary conditions, and we give numerical evidences for how the thermal spin transition curves vary as a function of the physical parameters (J, G) or an applied pressure. Moreover for OBCs case, we have derived the bulk, surface and finite-size contributions to the free energy and we have investigated the variation of these energies as function of J and system size. We have found that the surface free energy behaves like J〈σ〉{sup 2}, where 〈σ〉 is the average magnetization per site. Since the properties of the nanometric scale are dramatically influenced by the system's size (N), our analytical outcomes for the size dependence represent a step to achieve new characteristic of the future devices and also a way to find various novel properties which are absent in the bulk materials.

  17. Novel Method of Detecting Movement of the Interference Fringes Using One-Dimensional PSD

    Directory of Open Access Journals (Sweden)

    Qi Wang

    2015-06-01

    Full Text Available In this paper, a method of using a one-dimensional position-sensitive detector (PSD by replacing charge-coupled device (CCD to measure the movement of the interference fringes is presented first, and its feasibility is demonstrated through an experimental setup based on the principle of centroid detection. Firstly, the centroid position of the interference fringes in a fiber Mach-Zehnder (M-Z interferometer is solved in theory, showing it has a higher resolution and sensitivity. According to the physical characteristics and principles of PSD, a simulation of the interference fringe’s phase difference in fiber M-Z interferometers and PSD output is carried out. Comparing the simulation results with the relationship between phase differences and centroid positions in fiber M-Z interferometers, the conclusion that the output of interference fringes by PSD is still the centroid position is obtained. Based on massive measurements, the best resolution of the system is achieved with 5.15, 625 μm. Finally, the detection system is evaluated through setup error analysis and an ultra-narrow-band filter structure. The filter structure is configured with a one-dimensional photonic crystal containing positive and negative refraction material, which can eliminate background light in the PSD detection experiment. This detection system has a simple structure, good stability, high precision and easily performs remote measurements, which makes it potentially useful in material small deformation tests, refractivity measurements of optical media and optical wave front detection.

  18. Numerical solution of multigroup diffuse equations of one-dimensional geometry

    International Nuclear Information System (INIS)

    Pavelesku, M.; Adam, S.

    1975-01-01

    The one-dimensional diffuse theory is used for reactor physics calculations of fast reactors. Computer program based on the one-dimensional diffuse theory is speedy and not memory consuming. The algorithm is described for the three-zone fast reactor criticality computation in one-dimensional diffusion approximation. This algorithm is realised on IBM 370/135 computer. (I.T.)

  19. Combustion synthesis of inorganic materials; Muki zairyo no nensho gose

    Energy Technology Data Exchange (ETDEWEB)

    Oyanagi, M. [Ryukoku University, Kyoto (Japan)

    1999-11-01

    Combustion synthesis of porous titan carbide is outlined. In combustion synthesis, exothermic chain reaction, which is induced by igniting at one point of the simple substance mixture, propagates the combustion wave, and the compound is synthesized, which can be sintered by it. By this method, to this day intermetallic compounds, ceramics and high melting point composite materials have been synthesized, and synthetics can be made compact by adding pressure during or just after the reaction. Recently, applying the induction heating jointly, preheating before the reaction and heat treatment after the reaction can be controlled, accordingly, many high melting point inorganic compounds and composite materials can be made by combustion synthesis under pressure. (NEDO)

  20. Virtual screening of inorganic materials synthesis parameters with deep learning

    Science.gov (United States)

    Kim, Edward; Huang, Kevin; Jegelka, Stefanie; Olivetti, Elsa

    2017-12-01

    Virtual materials screening approaches have proliferated in the past decade, driven by rapid advances in first-principles computational techniques, and machine-learning algorithms. By comparison, computationally driven materials synthesis screening is still in its infancy, and is mired by the challenges of data sparsity and data scarcity: Synthesis routes exist in a sparse, high-dimensional parameter space that is difficult to optimize over directly, and, for some materials of interest, only scarce volumes of literature-reported syntheses are available. In this article, we present a framework for suggesting quantitative synthesis parameters and potential driving factors for synthesis outcomes. We use a variational autoencoder to compress sparse synthesis representations into a lower dimensional space, which is found to improve the performance of machine-learning tasks. To realize this screening framework even in cases where there are few literature data, we devise a novel data augmentation methodology that incorporates literature synthesis data from related materials systems. We apply this variational autoencoder framework to generate potential SrTiO3 synthesis parameter sets, propose driving factors for brookite TiO2 formation, and identify correlations between alkali-ion intercalation and MnO2 polymorph selection.

  1. Synthesis and catalytic applications of combined zeolitic/mesoporous materials

    Directory of Open Access Journals (Sweden)

    Jarian Vernimmen

    2011-11-01

    Full Text Available In the last decade, research concerning nanoporous siliceous materials has been focused on mesoporous materials with intrinsic zeolitic features. These materials are thought to be superior, because they are able to combine (i the enhanced diffusion and accessibility for larger molecules and viscous fluids typical of mesoporous materials with (ii the remarkable stability, catalytic activity and selectivity of zeolites. This review gives an overview of the state of the art concerning combined zeolitic/mesoporous materials. Focus is put on the synthesis and the applications of the combined zeolitic/mesoporous materials. The different synthesis approaches and formation mechanisms leading to these materials are comprehensively discussed and compared. Moreover, Ti-containing nanoporous materials as redox catalysts are discussed to illustrate a potential implementation of combined zeolitic/mesoporous materials.

  2. Lime Kiln Modeling. CFD and One-dimensional simulations

    Energy Technology Data Exchange (ETDEWEB)

    Svedin, Kristoffer; Ivarsson, Christofer; Lundborg, Rickard

    2009-03-15

    The incentives for burning alternative fuels in lime kilns are growing. An increasing demand on thorough investigations of alternative fuel impact on lime kiln performance have been recognized, and the purpose of this project has been to develop a lime kiln CFD model with the possibility to fire fuel oil and lignin. The second part of the project consists of three technical studies. Simulated data from a one-dimensional steady state program has been used to support theories on the impact of biofuels and lime mud dryness. The CFD simulations was carried out in the commercial code FLUENT. Due to difficulties with the convergence of the model the calcination reaction is not included. The model shows essential differences between the two fuels. Lignin gives a different flame shape and a longer flame length compared to fuel oil. Mainly this depends on how the fuel is fed into the combustion chamber and how much combustion air that is added as primary and secondary air. In the case of lignin combustion the required amount of air is more than in the fuel oil case. This generates more combustion gas and a different flow pattern is created. Based on the values from turbulent reaction rate for the different fuels an estimated flame length can be obtained. For fuel oil the combustion is very intense with a sharp peak in the beginning and a rapid decrease. For lignin the combustion starts not as intense as for the fuel oil case and has a smoother shape. The flame length appears to be approximately 2-3 meter longer for lignin than for fuel oil based on turbulent reaction rate in the computational simulations. The first technical study showed that there are many benefits of increasing dry solids content in the lime mud going into a kiln such as increased energy efficiency, reduced TRS, and reduced sodium in the kiln. However, data from operating kilns indicates that these benefits can be offset by increasing exit gas temperature that can limit kiln production capacity. Simulated

  3. One-dimensional diffusion model in an Inhomogeneous region

    CSIR Research Space (South Africa)

    Fedotov, I

    2006-01-01

    Full Text Available ) of these atoms. The enthalpy of formation of free atoms, ∆H, can vary between 50 and 300 kJ.mol-1. The ballast is heated by radiation from the walls of the atomizer, and its temperature, Tb(t), is given by the Stefan-Boltzmann equation [4...]: ( )ddt T t E c S V T t T tb b b b b b w b( ) ( ) ( )= −σ ρ 4 4 (6) where σ is the Stefan-Boltzmann constant, Eb is the emissivity of the ballast material, cb is the heat capacity of ballast material, ρb...

  4. Quasi-one-dimensional intermittent flux behavior in superconducting films

    DEFF Research Database (Denmark)

    Qviller, A. J.; Yurchenko, V. V.; Galperin, Y. M.

    2012-01-01

    Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa2Cu3O7-δ deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. ...

  5. Shear Stress in Nickel and Ni-60Co under One-Dimensional Shock Loading

    International Nuclear Information System (INIS)

    Workman, A.; Wallwork, A.; Meziere, Y. J. E.; Millett, J. C. F.; Bourne, N. K.

    2006-01-01

    The dynamic response of pure nickel (Ni), and its alloy, Ni-60Co (by weight %), has been investigated during one-dimensional shock loading. Few materials' properties are different and the only significantly altered feature is the reduced stacking fault energy (SFE) for the Ni-60Co. This paper considers the effect of this reduced SFE on the shear strength. Data (in terms of shock stress, particle velocity and shock velocity) are also presented. The influence on the shear stress, τ of cobalt additions in nickel are then investigated and presented. Results indicate that the lateral stress is increasing in both materials with the increasing impact stress. The shear stress was found to be higher in the nickel than in the Ni-60Co. The progressive decrease of the lateral stress noted during loading indicates a complex mechanism of deformation behind the shock front

  6. Microgravity Production of Nanoparticles of Novel Materials Using Plasma Synthesis

    Science.gov (United States)

    Frenklach, Michael; Fernandez-Pello, Carlos

    2001-01-01

    The research goal is to study the formation in reduced gravity of high quality nanoparticulate of novel materials using plasma synthesis. Particular emphasis will be placed on the production of powders of non-oxide materials like diamond, SiC, SiN, c-BN, etc. The objective of the study is to investigate the effect of gravity on plasma synthesis of these materials, and to determine how the microgravity synthesis can improve the quality and yield of the nanoparticles. It is expected that the reduced gravity will aid in the understanding of the controlling mechanisms of plasma synthesis, and will increase the yield, and quality of the synthesized powder. These materials have properties of interest in several industrial applications, such as high temperature load bearings or high speed metal machining. Furthermore, because of the nano-meter size of the particulate produced in this process, they have specific application in the fabrication of MEMS based combustion systems, and in the development and growth of nano-systems and nano-structures of these materials. These are rapidly advancing research areas, and there is a great need for high quality nanoparticles of different materials. One of the primary systems of interest in the project will be gas-phase synthesis of nanopowder of non-oxide materials.

  7. Orientation of One-Dimensional Silicon Polymer Films Studied by X-Ray Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    Md. Abdul Mannan

    2012-01-01

    Full Text Available Molecular orientations for thin films of one-dimensional silicon polymers grown by vacuum evaporation have been assigned by near-edge X-ray absorption fine structure (NEXAFS using linearly polarized synchrotron radiation. The polymer investigated was polydimethylsilane (PDMS which is the simplest stable silicon polymer, and one of the candidate materials for one-dimensional molecular wire. For PDMS films deposited on highly oriented pyrolytic graphite (HOPG, four resonance peaks have been identified in the Si K-edge NEXAFS spectra. Among these peaks, the intensities of the two peaks lower-energy at 1842.0 eV and 1843.2 eV were found to be strongly polarization dependent. The peaks are assigned to the resonance excitations from the Si 1s to σ∗ pyz and σ∗ px orbitals localized at the Si–C and Si–Si bonds, respectively. Quantitative evaluation of the polarization dependence of the NEXAFS spectra revealed that the molecules are self-assembled on HOPG surface, and the backbones of the PDMS are oriented nearly parallel to the surface. The observed orientation is opposite to the previously observed results for PDMS on the other surfaces such as oxide (indium tin oxide and metal (polycrystalline copper. The flat-lying feature of PDMS observed only on HOPG surface is attributed to the interaction between CH bonds in PDMS and π orbitals in HOPG surface.

  8. Thermoelectric Properties for a Suspended Microribbon of Quasi-One-Dimensional TiS3

    Science.gov (United States)

    Sakuma, Tasuku; Nishino, Shunsuke; Miyata, Masanobu; Koyano, Mikio

    2018-06-01

    Transition-metal trichalcogenides MX3 (M = Ti, Zr, Nb, Ta; X = S, Se) are well-known inorganic quasi-one-dimensional conductors. Among them, we have investigated the thermoelectric properties of titanium trisulfide TiS3 microribbon. The electrical resistivity ρ, thermal conductivity κ, and thermoelectric power S were measured using 3 ω method. The weight mean values were found to be ρ = 5 mω m and κ = 10 W K-1 m-1 along the one-dimensional direction ( b-axis) of the TiS3 microribbon. Combined with the thermoelectric power S = -530 μV K-1, the figure of merit was calculated as ZT = 0.0023. This efficiency is the same as that of randomly oriented bulk TiS3. We also estimated the anisotropy of σ and κ using the present results and those for randomly oriented bulk material. The obtained weak anisotropy for TiS3 is attributable to strong coupling between triangular columns consisting of TiS3 units. These experimental results are consistent with theoretical results obtained using density functional theory (DFT) calculations.

  9. Expectation-based approach for one-dimensional randomly disordered phononic crystals

    International Nuclear Information System (INIS)

    Wu, Feng; Gao, Qiang; Xu, Xiaoming; Zhong, Wanxie

    2014-01-01

    An expectation-based approach to the statistical theorem is proposed for the one-dimensional randomly disordered phononic crystal. In the proposed approach, the expectations of the random eigenstates of randomly disordered phononic crystals are investigated. In terms of the expectations of the random eigenstates, the wave propagation and localization phenomenon in the random phononic crystal could be understood in a statistical perspective. Using the proposed approach, it is proved that for a randomly disordered phononic crystal, the Bloch theorem holds in the perspective of expectation. A one-dimensional randomly disordered binary phononic crystal consisting of two materials with the random geometry size or random physical parameter is addressed by using the proposed approach. From the result, it can be observed that with the increase of the disorder degree, the localization of the expectations of the eigenstates is strengthened. The effect of the random disorder on the eigenstates at higher frequencies is more significant than that at lower frequencies. Furthermore, after introducing the random disorder into phononic crystals, some random divergent eigenstates are changed to localized eigenstates in expectation sense.

  10. Unexpected Magnetic Semiconductor Behavior in Zigzag Phosphorene Nanoribbons Driven by Half-Filled One Dimensional Band

    Science.gov (United States)

    Du, Yongping; Liu, Huimei; Xu, Bo; Sheng, Li; Yin, Jiang; Duan, Chun-Gang; Wan, Xiangang

    2015-01-01

    Phosphorene, as a novel two-dimensional material, has attracted a great interest due to its novel electronic structure. The pursuit of controlled magnetism in Phosphorene in particular has been persisting goal in this area. In this paper, an antiferromagnetic insulating state has been found in the zigzag phosphorene nanoribbons (ZPNRs) from the comprehensive density functional theory calculations. Comparing with other one-dimensional systems, the magnetism in ZPNRs display several surprising characteristics: (i) the magnetic moments are antiparallel arranged at each zigzag edge; (ii) the magnetism is quite stable in energy (about 29 meV/magnetic-ion) and the band gap is big (about 0.7 eV); (iii) the electronic and magnetic properties is almost independent on the width of nanoribbons; (iv) a moderate compressive strain will induce a magnetic to nonmagnetic as well as semiconductor to metal transition. All of these phenomena arise naturally due to one unique mechanism, namely the electronic instability induced by the half-filled one-dimensional bands which cross the Fermi level at around π/2a. The unusual electronic and magnetic properties in ZPNRs endow them possible potential for the applications in nanoelectronic devices. PMID:25747727

  11. Thermoelectric Properties for a Suspended Microribbon of Quasi-One-Dimensional TiS3

    Science.gov (United States)

    Sakuma, Tasuku; Nishino, Shunsuke; Miyata, Masanobu; Koyano, Mikio

    2018-02-01

    Transition-metal trichalcogenides MX3 (M = Ti, Zr, Nb, Ta; X = S, Se) are well-known inorganic quasi-one-dimensional conductors. Among them, we have investigated the thermoelectric properties of titanium trisulfide TiS3 microribbon. The electrical resistivity ρ, thermal conductivity κ, and thermoelectric power S were measured using 3ω method. The weight mean values were found to be ρ = 5 mω m and κ = 10 W K-1 m-1 along the one-dimensional direction (b-axis) of the TiS3 microribbon. Combined with the thermoelectric power S = -530 μV K-1, the figure of merit was calculated as ZT = 0.0023. This efficiency is the same as that of randomly oriented bulk TiS3. We also estimated the anisotropy of σ and κ using the present results and those for randomly oriented bulk material. The obtained weak anisotropy for TiS3 is attributable to strong coupling between triangular columns consisting of TiS3 units. These experimental results are consistent with theoretical results obtained using density functional theory (DFT) calculations.

  12. Generalized synthesis of periodic surfactant/inorganic composite materials

    NARCIS (Netherlands)

    Huo, Q.; Margolese, D.I.; Ciesla, U.; Feng, P.; Gier, T.E.; Sieger, P.; Leon, R.; Petroff, P.M.; Schüth, F.; Stucky, G.D.

    1994-01-01

    THE recent synthesis of silica-based mesoporous materials by the cooperative assembly of periodic inorganic and surfactant-based structures has attracted great interest because it extends the range of molecular-sieve materials into the very-large-pore regime. If the synthetic approach can be

  13. Optical Tamm states in one-dimensional superconducting photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    El Abouti, O. [LPMR, Département de Physique, Faculté des Sciences, Université Mohammed 1, 60000 Oujda (Morocco); El Boudouti, E. H. [LPMR, Département de Physique, Faculté des Sciences, Université Mohammed 1, 60000 Oujda (Morocco); IEMN, UMR-CNRS 8520, UFR de Physique, Université de Lille 1, 59655 Villeneuve d' Ascq (France); El Hassouani, Y. [ESIM, Département de Physique, Faculté des Sciences et Techniques, Université Moulay Ismail, Boutalamine BP 509, 52000 Errachidia (Morocco); Noual, A. [LPMR, Département de Physique, Faculté des Sciences, Université Mohammed 1, 60000 Oujda (Morocco); Ecole Normale Supérieur de Tétouan, Université Abdelmalek Essaadi, Tétouan (Morocco); Djafari-Rouhani, B. [IEMN, UMR-CNRS 8520, UFR de Physique, Université de Lille 1, 59655 Villeneuve d' Ascq (France)

    2016-08-15

    In this study, we investigate localized and resonant optical waves associated with a semi-infinite superlattice made out of superconductor-dielectric bilayers and terminated with a cap layer. Both transverse electric and transverse magnetic waves are considered. These surface modes are analogous to the so-called Tamm states associated with electronic states found at the surface of materials. The surface guided modes induced by the cap layer strongly depend on whether the superlattice ends with a superconductor or a dielectric layer, the thickness of the surface layer, the temperature of the superconductor layer as well as on the polarization of the waves. Different kinds of surface modes are found and their properties examined. These structures can be used to realize the highly sensitive photonic crystal sensors.

  14. Physics of zero- and one-dimensional nanoscopic systems

    CERN Document Server

    Maiti, Santanu; Chowdhury, Jayeeta

    2007-01-01

    In recent years submicron and nanoscale systems have featured strongly on the research agenda due to the technological progress and new physics that have emerged from studies of ultra-small systems. A fundamental understanding of basic physical phenomena on the mesoscopic and nanoscopic scales is required to exploit the technological potential offered by these exotic materials. The present book contains review-like chapters by some of the leading experts in the field, covering topics such as the Kondo effect, electron transport, disorder and quantum coherence with electron-electron interaction, persistent current, thermoelectric phenomena, etc. in quantum dots, quantum wires, carbon nanotubes and more. This book will be valuable to researchers and students in condensed matter physics.

  15. High Speed Water Sterilization Using One-Dimensional Nanostructures

    KAUST Repository

    Schoen, David T.; Schoen, Alia P.; Hu, Liangbing; Kim, Han Sun; Heilshorn, Sarah C.; Cui, Yi

    2010-01-01

    The removal of bacteria and other organisms from water is an extremely important process, not only for drinking and sanitation but also industrially as biofouling is a commonplace and serious problem. We here present a textile based multiscale device for the high speed electrical sterilization of water using silver nanowires, carbon nanotubes, and cotton. This approach, which combines several materials spanning three very different length scales with simple dying based fabrication, makes a gravity fed device operating at 100000 L/(h m2) which can inactivate >98% of bacteria with only several seconds of total incubation time. This excellent performance is enabled by the use of an electrical mechanism rather than size exclusion, while the very high surface area of the device coupled with large electric field concentrations near the silver nanowire tips allows for effective bacterial inactivation. © 2010 American Chemical Society.

  16. High Speed Water Sterilization Using One-Dimensional Nanostructures

    KAUST Repository

    Schoen, David T.

    2010-09-08

    The removal of bacteria and other organisms from water is an extremely important process, not only for drinking and sanitation but also industrially as biofouling is a commonplace and serious problem. We here present a textile based multiscale device for the high speed electrical sterilization of water using silver nanowires, carbon nanotubes, and cotton. This approach, which combines several materials spanning three very different length scales with simple dying based fabrication, makes a gravity fed device operating at 100000 L/(h m2) which can inactivate >98% of bacteria with only several seconds of total incubation time. This excellent performance is enabled by the use of an electrical mechanism rather than size exclusion, while the very high surface area of the device coupled with large electric field concentrations near the silver nanowire tips allows for effective bacterial inactivation. © 2010 American Chemical Society.

  17. Applying flow chemistry: methods, materials, and multistep synthesis.

    Science.gov (United States)

    McQuade, D Tyler; Seeberger, Peter H

    2013-07-05

    The synthesis of complex molecules requires control over both chemical reactivity and reaction conditions. While reactivity drives the majority of chemical discovery, advances in reaction condition control have accelerated method development/discovery. Recent tools include automated synthesizers and flow reactors. In this Synopsis, we describe how flow reactors have enabled chemical advances in our groups in the areas of single-stage reactions, materials synthesis, and multistep reactions. In each section, we detail the lessons learned and propose future directions.

  18. Cavitational synthesis of nanostructured inorganic materials for enhanced heterogeneous catalysis

    Science.gov (United States)

    Krausz, Ivo Michael

    The synthesis of nanostructured inorganic materials by hydrodynamic cavitation processing was investigated. The goal of this work was to develop a general synthesis technique for nanostructured materials with a control over crystallite size in the 1--20 nm range. Materials with crystallite sizes in this range have shown enhanced catalytic activity compared to materials with larger crystallite sizes. Several supported and unsupported inorganic materials were studied to understand the effects of cavitation on crystallite size. Cavitation processing of calcium fluoride resulted in more spherical particles, attached to one another by melted necks. This work produced the first evidence of shock wave heating of nanostructured materials by hydrodynamic cavitation processing. Hydrodynamic cavitation synthesis of various catalytic support materials indicated that their phase composition and purity could be controlled by adjustment of the processing parameters. Zirconia/alumina supports synthesized using hydro-dynamic cavitation and calcined to 1368 K retained a high purity cubic zirconia phase, whereas classically prepared samples showed a phase transformation to monoclinic zirconia. Similarly, the synthesis of alumina resulted in materials with varying Bohmite and Bayerite contents as a function of the process parameters. High temperature calcination resulted in stable alumina supports with varying amounts of delta-, and theta-alumina. Synthesis studies of palladium and silver showed modest variations in crystallite size as a function of cavitation process parameters. Calcination resulted in larger grain materials, indicating a disappearance of intergrain boundaries. Based on these results, a new synthesis method was studied involving controlled agglomeration of small silver crystallites by hydrodynamic cavitation processing, followed by deposition on alumina. The optimal pH, concentration, and processing time for controlling the silver crystallite size in the cavitation

  19. One-dimensional contaminant transport model for the design of soil-bentonite slurry walls

    International Nuclear Information System (INIS)

    Khandelwal, A.; Rabideau, A.; Su, J.

    1997-01-01

    A user oriented computer model (TRANS1D) was developed for application to the analysis and design of vertical soil-bentonite barriers. TRANS1D is a collection of analytical and numerical solutions to the one dimensional advective-dispersive-reactive (ADR) equation. The primary objective in developing TRANS1D was to enable the designer of a barrier system to evaluate the potential system performance with respect to contaminant transport, without performing difficult and time consuming field or laboratory experiments. Several issues related to model application are discussed, including identification of governing transport processes, specification of boundary conditions, and parameter estimation. Model predictions are compared with the results of laboratory column experiments conducted with soil bentonite barrier material under diffusion-dominated conditions. Good agreement between model calibrations and experimental results was noted, with calibrated diffusion coefficients for organic contaminants consistent with literature values

  20. Strongly correlated quasi-one-dimensional bands: Ground states, optical absorption, and phonons

    International Nuclear Information System (INIS)

    Campbell, D.K.; Gammel, J.T.; Loh, E.Y. Jr.

    1989-01-01

    Using the Lanczos method for exact diagonalization on systems up to 14 sites, combined with a novel ''phase randomization'' technique for extracting more information from these small systems, we investigate several aspects of the one-dimensional Peierls-Hubbard Hamiltonian, in the context of trans-polyacetylene: the dependence of the ground state dimerization on the strength of the electron-electron interactions, including the effects of ''off-diagonal'' Coulomb terms generally ignored in the Hubbard model; the phonon vibrational frequencies and dispersion relations, and the optical absorption properties, including the spectrum of absorptions as a function of photon energy. These three different observables provide considerable insight into the effects of electron-electron interactions on the properties of real materials and thus into the nature of strongly correlated electron systems. 29 refs., 11 figs

  1. Dynamical response of local magnons: single impurity limit in one dimensional magnets

    International Nuclear Information System (INIS)

    Koiller, B.; Rezende, S.M.

    1979-11-01

    The dynamic response of local magnon modes associated with a single impurity spin in one-dimensional ferro and antiferromagnetic insulators is studied theoretically with the use of a Green's function formulation solved exactly, by transfer matrix techniques, for zero temperature. The calculations are applied to the typical 1 - d ferromagnet CsNiF 3 and the antiferromagnet TMMC as functions of the impurity parameters in a way to allow the interpretation of possible future measurements of defect modes in these materials. The theory also explains qualitatively recent measurements in the three dimensional defect antiferromagnets FeF 2 : Mn 2+ , CoF 2 : Mn 2+ and FeF 2 : Co 2+ . (Author) [pt

  2. Stable one-dimensional periodic waves in Kerr-type saturable and quadratic nonlinear media

    International Nuclear Information System (INIS)

    Kartashov, Yaroslav V; Egorov, Alexey A; Vysloukh, Victor A; Torner, Lluis

    2004-01-01

    We review the latest progress and properties of the families of bright and dark one-dimensional periodic waves propagating in saturable Kerr-type and quadratic nonlinear media. We show how saturation of the nonlinear response results in the appearance of stability (instability) bands in a focusing (defocusing) medium, which is in sharp contrast with the properties of periodic waves in Kerr media. One of the key results discovered is the stabilization of multicolour periodic waves in quadratic media. In particular, dark-type waves are shown to be metastable, while bright-type waves are completely stable in a broad range of energy flows and material parameters. This yields the first known example of completely stable periodic wave patterns propagating in conservative uniform media supporting bright solitons. Such results open the way to the experimental observation of the corresponding self-sustained periodic wave patterns

  3. Geometrically distributed one-dimensional photonic crystals for light-reflection in all angles.

    Science.gov (United States)

    Alagappan, G; Wu, P

    2009-07-06

    We demonstrate that a series of one-dimensional photonic crystals made of any dielectric materials, with the periods are distributed in a geometrical progression of a common ratio, r rc (theta,P), where rc is a structural parameter that depends on the angle of incidence, theta, and polarization, P, is capable of blocking light of any spectral range. If an omni-directional reflection is desired for all polarizations and for all incident angles smaller than thetao, then r rc (theta(o),p), where p is the polarization with the electric field parallel to the plane of incidence. We present simple and formula like expressions for rc, width of the bandgap, and minimum number of photonic crystals to achieve a perfect light reflection.

  4. Spallation in NiTi under One-Dimensional Shock Loading

    International Nuclear Information System (INIS)

    Wallwork, A.; Workman, A.; Meziere, Y. J. E.; Millett, J. C. F.; Bourne, N. K.

    2006-01-01

    The dynamic response of the shape memory alloy NiTi has been of interest to a number of investigators because it displays a shape memory effect. The dynamic tensile (spall) strength of this material is measured under one-dimensional shock loading. The loading stress pulse length and impact stress were varied to a peak stress of 15 GPa. The pull back stress (σpbs) was found to increase with the applied pulse length. This suggests that the dynamic tensile strength is dependent upon the generation of a deformation micro structure that evolves behind the shock front. In contrast, increasing stress levels result in a near-constant pull back stress, although at the lowest applied stress, spallation did not occur

  5. Longitudinal and Lateral Stress Measurements in NiTi under One-Dimensional Shock Loading

    International Nuclear Information System (INIS)

    Meziere, Y. J. E.; Millett, J. C. F.; Bourne, N. K.; Wallwork, A.; Workman, A.

    2006-01-01

    This paper investigates the influence of the impact stress on the magnitude of the shear stress under one-dimensional shock loading. The shear stress is calculated from the measured longitudinal and the lateral stresses. New data in terms of shock stress, particle velocity and shock velocity has been gathered. Results indicate that the lateral stress has a positive dependence on the impact stress. A general decrease of the lateral stress was also observed immediately after the impact, while the longitudinal stress remains constant for the duration of the pulse length. This suggests that the shear strength increases behind the shock front. This decrease had been found to reach a constant value for the specimens impacted at lower stress. A complex mechanism of deformation behind the shock front during loading was thus reveals. This limit, related to the inflexion point noted on the Hugoniot (Us-up), seems to be an effect of the martensitic phase transformation undergoes by the material

  6. Wave propagation in one-dimensional solid-fluid quasi-periodic and aperiodic phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Chen Ali, E-mail: alchen@bjtu.edu.cn [Institute of Engineering Mechanics, Beijing Jiaotong University, Beijing 100044 (China); Wang Yuesheng [Institute of Engineering Mechanics, Beijing Jiaotong University, Beijing 100044 (China); Zhang Chuanzeng [Department of Civil Engineering, University of Siegen, D-57068 Siegen (Germany)

    2012-02-01

    The propagation of the elastic waves in one-dimensional (1D) solid-fluid quasi-periodic phononic crystals is studied by employing the concept of the localization factor, which is calculated by the transfer matrix method. The solid-fluid interaction effect at the interfaces between the solid and the fluid components is considered. For comparison, the periodic systems and aperiodic Thue-Morse sequence are also analyzed in this paper. The splitting phenomenon of the pass bands and bandgaps are discussed for these 1D solid-fluid systems. At last the influences of the material impedance ratios on the band structures of the 1D solid-fluid quasi-periodic phononic crystals arranged as Fibonacci sequence are discussed.

  7. Spinons, Solitons, and Breathers in Quasi-One-Dimensional Magnets

    Science.gov (United States)

    Broholm, Collin

    2006-03-01

    By scattering neutrons from coordination polymer magnets, we contrast the effects of a uniform and a staggered magnetic field on the quantum critical state of a spin-1/2 chain. In a partially magnetized state of copper pyrazine dinitrate (CuPzN) we find bounded spectral continua indicating that neutrons scatter from spin-1/2 quasi-particle pairs [1]. The complex boundaries including an incommensurate soft spot result from a field induced shift in the Fermi points for these quasi-particles. The measurements indicate that the magnetized state of CuPzN remains quantum critical. Copper benzoate [2] and CuCl2^.2(dimethylsulfoxide) (CDC) [3] differ from CuPzN in that there are two spins per unit cell along the spin chain. Rather than continuous spectra, we find resolution limited gapped excitations when these materials are subject to high fields. So with two spins per unit cell, an applied field can drive the spin-1/2 chain away from criticality. The explanation for this effect was provided by Affleck and Oshikawa. The alternating coordination environment induces a transverse staggered field and spinon binding. The quantum sine-Gordon model is the relevant low energy field theory and it predicts soliton and breather excitations at specific energies and wave vectors that we compare to the experiments. We shall also compare a complete measurement of the dynamic spin correlation function for CDC in a field to exact diagonalization results for a spin-1/2 chain with a staggered and uniform magnetic field [4]. [1] M. B. Stone, D. H. Reich, C. Broholm, K. Lefmann, C. Rischel, C. P. Landee, and M. M. Turnbull, Phys. Rev. Lett. 91, 037205 (2003). [2] M. Kenzelmann, Y. Chien, C. Broholm, D. H. Reich, and Y. Qiu, Phys. Rev. Lett. 93, 017204 (2004). [3] D. C. Dender, P. R. Hammar, Daniel H. Reich, C. Broholm, and G. Aeppli, Phys. Rev. Lett. 79, 1750 (1997). [4] M. Kenzelmann, C. D. Batista, Y. Chen, C. Broholm, D. H. Reich, S. Park, and Y. Qiu, Phys. Rev. B 71, 094411 (2005).

  8. Data Mining for New Two- and One-Dimensional Weakly Bonded Solids and Lattice-Commensurate Heterostructures.

    Science.gov (United States)

    Cheon, Gowoon; Duerloo, Karel-Alexander N; Sendek, Austin D; Porter, Chase; Chen, Yuan; Reed, Evan J

    2017-03-08

    Layered materials held together by weak interactions including van der Waals forces, such as graphite, have attracted interest for both technological applications and fundamental physics in their layered form and as an isolated single-layer. Only a few dozen single-layer van der Waals solids have been subject to considerable research focus, although there are likely to be many more that could have superior properties. To identify a broad spectrum of layered materials, we present a novel data mining algorithm that determines the dimensionality of weakly bonded subcomponents based on the atomic positions of bulk, three-dimensional crystal structures. By applying this algorithm to the Materials Project database of over 50,000 inorganic crystals, we identify 1173 two-dimensional layered materials and 487 materials that consist of weakly bonded one-dimensional molecular chains. This is an order of magnitude increase in the number of identified materials with most materials not known as two- or one-dimensional materials. Moreover, we discover 98 weakly bonded heterostructures of two-dimensional and one-dimensional subcomponents that are found within bulk materials, opening new possibilities for much-studied assembly of van der Waals heterostructures. Chemical families of materials, band gaps, and point groups for the materials identified in this work are presented. Point group and piezoelectricity in layered materials are also evaluated in single-layer forms. Three hundred and twenty-five of these materials are expected to have piezoelectric monolayers with a variety of forms of the piezoelectric tensor. This work significantly extends the scope of potential low-dimensional weakly bonded solids to be investigated.

  9. SYNTHESIS OF VISCOELASTIC MATERIAL MODELS (SCHEMES

    Directory of Open Access Journals (Sweden)

    V. Bogomolov

    2014-10-01

    Full Text Available The principles of structural viscoelastic schemes construction for materials with linear viscoelastic properties in accordance with the given experimental data on creep tests are analyzed. It is shown that there can be only four types of materials with linear visco-elastic properties.

  10. Propagating gene expression fronts in a one-dimensional coupled system of artificial cells

    Science.gov (United States)

    Tayar, Alexandra M.; Karzbrun, Eyal; Noireaux, Vincent; Bar-Ziv, Roy H.

    2015-12-01

    Living systems employ front propagation and spatiotemporal patterns encoded in biochemical reactions for communication, self-organization and computation. Emulating such dynamics in minimal systems is important for understanding physical principles in living cells and in vitro. Here, we report a one-dimensional array of DNA compartments in a silicon chip as a coupled system of artificial cells, offering the means to implement reaction-diffusion dynamics by integrated genetic circuits and chip geometry. Using a bistable circuit we programmed a front of protein synthesis propagating in the array as a cascade of signal amplification and short-range diffusion. The front velocity is maximal at a saddle-node bifurcation from a bistable regime with travelling fronts to a monostable regime that is spatially homogeneous. Near the bifurcation the system exhibits large variability between compartments, providing a possible mechanism for population diversity. This demonstrates that on-chip integrated gene circuits are dynamical systems driving spatiotemporal patterns, cellular variability and symmetry breaking.

  11. Fracture analysis of one-dimensional hexagonal quasicrystals: Researches of a finite dimension rectangular plate by boundary collocation method

    Energy Technology Data Exchange (ETDEWEB)

    Jiaxing, Cheng; Dongfa, Sheng [Southwest Forestry University, Yunnan (China)

    2017-05-15

    As an important supplement and development to crystallography, the applications about quasicrystal materials have played a core role in many fields, such as manufacturing and the space industry. Due to the sensitivity of quasicrystals to defects, the research on the fracture problem of quasicrystals has attracted a great deal of attention. We present a boundary collocation method to research fracture problems for a finite dimension rectangular one-dimensional hexagonal quasicrystal plate. Because mode I and mode II problems for one- dimensional hexagonal quasicrystals are like that for the classical elastic materials, only the anti-plane problem is discussed in this paper. The correctness of the present numerical method is verified through a comparison of the present results and the existing results. And then, the size effects on stress field, stress intensity factor and energy release rate are discussed in detail. The obtained results can provide valuable references for the fracture behavior of quasicrystals.

  12. Ion Implantation and Synthesis of Materials

    CERN Document Server

    Nastasi, Michael

    2006-01-01

    Ion implantation is one of the key processing steps in silicon integrated circuit technology. Some integrated circuits require up to 17 implantation steps and circuits are seldom processed with less than 10 implantation steps. Controlled doping at controlled depths is an essential feature of implantation. Ion beam processing can also be used to improve corrosion resistance, to harden surfaces, to reduce wear and, in general, to improve materials properties. This book presents the physics and materials science of ion implantation and ion beam modification of materials. It covers ion-solid interactions used to predict ion ranges, ion straggling and lattice disorder. Also treated are shallow-junction formation and slicing silicon with hydrogen ion beams. Topics important for materials modification, such as ion-beam mixing, stresses, and sputtering, are also described.

  13. Synthesis and design of silicide intermetallic materials

    Energy Technology Data Exchange (ETDEWEB)

    Petrovic, J.J.; Castro, R.G.; Butt, D.P. [Los Alamos National Lab., NM (United States)] [and others

    1997-04-01

    The overall objective of this program is to develop structural silicide-based materials with optimum combinations of elevated temperature strength/creep resistance, low temperature fracture toughness, and high temperature oxidation and corrosion resistance for applications of importance to the U.S. processing industry. A further objective is to develop silicide-based prototype industrial components. The ultimate aim of the program is to work with industry to transfer the structural silicide materials technology to the private sector in order to promote international competitiveness in the area of advanced high temperature materials and important applications in major energy-intensive U.S. processing industries. The program presently has a number of developing industrial connections, including a CRADA with Schuller International Inc. targeted at the area of MoSi{sub 2}-based high temperature materials and components for fiberglass melting and processing applications. The authors are also developing an interaction with the Institute of Gas Technology (IGT) to develop silicides for high temperature radiant gas burner applications, for the glass and other industries. Current experimental emphasis is on the development and characterization of MoSi{sub 2}-Si{sub 3}N{sub 4} and MoSi{sub 2}-SiC composites, the plasma spraying of MoSi{sub 2}-based materials, and the joining of MoSi{sub 2} materials to metals.

  14. One-dimensional calculation of flow branching using the method of characteristics

    International Nuclear Information System (INIS)

    Meier, R.W.; Gido, R.G.

    1978-05-01

    In one-dimensional flow systems, the flow often branches, such as at a tee or manifold. The study develops a formulation for calculating the flow through branch points with one-dimensional method of characteristics equations. The resultant equations were verified by comparison with experimental measurements

  15. One-dimensional treatment of polyatomic crystals by the Laplace transform method

    International Nuclear Information System (INIS)

    Rosato, A.; Santana, P.H.A.

    1976-01-01

    The one dimensional periodic potential problem is solved using the Laplace transform method and a condensed expression for the relation E x k and effective mass for one electron in a polyatomic structure is determined. Applications related to the effect of the asymmetry of the potential upon the one dimensional band structure are discussed [pt

  16. An analytical one-dimensional model for predicting waste package performance

    International Nuclear Information System (INIS)

    Relyea, J.F.; Wood, M.I.

    1984-01-01

    A method for allocating waste package performance requirements among waste package components with regard to radionuclide isolation has been developed. Modification or change in this approach can be expected as the understanding of radionuclide behavior in the waste package improves. Thus, the performance requirements derived in this document are preliminary and subject to change. However, this kind of analysis is a useful starting point. It has also proved useful for identifying a small group of radionuclides which should be emphasized in a laboratory experimental program designed to characterize the behavior of specific radionuclides in the waste package environment. A simple one-dimensional, two media transport model has been derived and used to calculate radionuclide transport from the waste form-packing material interface of the waste package into the host rock. Cumulative release over 10,000 years, maximum yearly releases and release rates at the packing material-host rock interface were evaluated on a radionuclide-by radionuclide basis. The major parameters controlling radionuclide release were found to be: radionuclide solubility, porosity of the rock, isotopic ratio of the radionuclide and surface area of the waste form-packing material interface. 15 refs., 2 figs., 16 tabs

  17. Analysis of cutoff frequency in a one-dimensional superconductor-metamaterial photonic crystal

    International Nuclear Information System (INIS)

    Aly, Arafa H; Aghajamali, Alireza; Elsayed, Hussein A.; Mobarak, Mohamed

    2016-01-01

    Highlights: • Our results show that the appearance of the cutoff frequency, below which the incident electromagnetic waves cannot propagate in the structure. We demonstrate that the cutoff frequency shows an upward trend as the thickness of the superconductor layer as well as the thickness of the metamaterial increase. • The cutoff frequency can be tuned by the operating temperature. Our structures are good candidates for many optical devices such as optical filters, switches, temperature controlled optical shutter, and among photoelectronic applications in gigahertz. - Abstract: In this paper, using the two-fluid model and the characteristic matrix method, we investigate the transmission characteristics of the one-dimensional photonic crystal. Our structure composed of the layers of low-temperature superconductor material (NbN) and double-negative metamaterial. We target studying the effect of many parameters such as the thickness of the superconductor material, the thickness of the metamaterial layer, and the operating temperature. We show that the cut-off frequency can be tuned efficiently by the operating temperature as well as the thicknesses of the constituent materials.

  18. Synthesis and chemistry of elemental 2D materials

    Energy Technology Data Exchange (ETDEWEB)

    Mannix, Andrew J.; Kiraly, Brian; Hersam, Mark C.; Guisinger, Nathan P.

    2017-01-25

    2D materials have attracted considerable attention in the past decade for their superlative physical properties. These materials consist of atomically thin sheets exhibiting covalent in-plane bonding and weak interlayer and layer-substrate bonding. Following the example of graphene, most emerging 2D materials are derived from structures that can be isolated from bulk phases of layered materials, which form a limited library for new materials discovery. Entirely synthetic 2D materials provide access to a greater range of properties through the choice of constituent elements and substrates. Of particular interest are elemental 2D materials, because they provide the most chemically tractable case for synthetic exploration. In this Review, we explore the progress made in the synthesis and chemistry of synthetic elemental 2D materials, and offer perspectives and challenges for the future of this emerging field.

  19. Battery Materials Synthesis | Transportation Research | NREL

    Science.gov (United States)

    thin-film. NREL's development of inexpensive, high-energy-density electrode materials is challenging introduction of metal oxide and hybrid inorganic-organic surface modification via atomic layer deposition has method for applying conformal thin film coatings to highly textured surfaces. These coatings have been

  20. Synthesis of thin films and materials utilizing a gaseous catalyst

    Science.gov (United States)

    Morse, Daniel E; Schwenzer, Birgit; Gomm, John R; Roth, Kristian M; Heiken, Brandon; Brutchey, Richard

    2013-10-29

    A method for the fabrication of nanostructured semiconducting, photoconductive, photovoltaic, optoelectronic and electrical battery thin films and materials at low temperature, with no molecular template and no organic contaminants. High-quality metal oxide semiconductor, photovoltaic and optoelectronic materials can be fabricated with nanometer-scale dimensions and high dopant densities through the use of low-temperature biologically inspired synthesis routes, without the use of any biological or biochemical templates.

  1. Surface-confined [2 + 2] cycloaddition towards one-dimensional polymers featuring cyclobutadiene units

    NARCIS (Netherlands)

    Tran, Bay V.; Pham, Tuan Anh; Grunst, Michael; Kivala, Milan; Stöhr, Meike

    2017-01-01

    Surface-confined synthesis has been offering a wide range of opportunities for the construction of novel molecular nanostructures. Exploring new types of on-surface coupling reactions is considered essential for being able to deliberately tune the materials properties. Here, we report on the

  2. A versatile single molecular precursor for the synthesis of layered oxide cathode materials for Li-ion batteries.

    Science.gov (United States)

    Li, Maofan; Liu, Jiajie; Liu, Tongchao; Zhang, Mingjian; Pan, Feng

    2018-02-01

    A carbonyl-bridged single molecular precursor LiTM(acac) 3 [transition metal (TM) = cobalt/manganese/nickel (Co/Mn/Ni), acac = acetylacetone], featuring a one-dimensional chain structure, was designed and applied to achieve the layered oxide cathode materials: LiTMO 2 (TM = Ni/Mn/Co, NMC). As examples, layered oxides, primary LiCoO 2 , binary LiNi 0.8 Co 0.2 O 2 and ternary LiNi 0.5 Mn 0.3 Co 0.2 O 2 were successfully prepared to be used as cathode materials. When they are applied to lithium-ion batteries (LIBs), all exhibit good electrochemical performance because of their unique morphology and great uniformity of element distribution. This versatile precursor is predicted to accommodate many other metal cations, such as aluminum (Al 3+ ), iron (Fe 2+ ), and sodium (Na + ), because of the flexibility of organic ligand, which not only facilitates the doping-modification of the NMC system, but also enables synthesis of Na-ion layered oxides. This opens a new direction of research for the synthesis of high-performance layered oxide cathode materials for LIBs.

  3. Synthesis of functional materials by radiation

    International Nuclear Information System (INIS)

    Nho, Young Chang; Kim, Ki Yup; Kang, Phil Hyun and others

    2000-04-01

    The radiation can induce chemical reaction to modify polymer under even the solid condition or in the low temperature. Therefore, the radiation processing is used as the means to develop the high functional polymer and new material which is impossible by chemical process. The radiation grafting process has the advantage to endow the adsorption function to the existing materials such as polymer membrane, fabric, non-fabric, non-woven fabric and film. Radiation crosslinking is effected with no pressure and is performed at low temperatures. Thus, temperature sensitive additives can be used in radiation crosslinking. The radiation crosslinking and grafting can be easily adjusted and is easily reproducible by controlling the radiation dose. The finished product contains no residuals of substances required to initiate the chemical crosslinking and grafting which can restrict the application possibilities, or can increase the failure rate. In these studies, radiation grafting and crosslinking were used to develop the toxic gas adsorbent, blood compatible polymer, acetabular cup of artificial joint, urokinase adsorbent, hydrogel, hollow fiber membrane adsorbing the heavy metals, and battery separator membrane. Because cable in nuclear power plant is directly related to safe operation, the life assessment of the cable system is an important issue. To assess the degradation and life time of cable is complicated owing to the various types and the different formulation of cable. In order to make an estimate the long term degradation occurring in a material, it is necessary to carry out the accelerated aging studies and to establish the appropriate test method to characterize the degradation. These studies are aimed at the evaluation technique on radiation degradation of polymer material and applying these results to nuclear equipment qualification

  4. Synthesis of functional materials by radiation

    Energy Technology Data Exchange (ETDEWEB)

    Nho, Young Chang; Kim, Ki Yup; Kang, Phil Hyun and others

    2000-04-01

    The radiation can induce chemical reaction to modify polymer under even the solid condition or in the low temperature. Therefore, the radiation processing is used as the means to develop the high functional polymer and new material which is impossible by chemical process. The radiation grafting process has the advantage to endow the adsorption function to the existing materials such as polymer membrane, fabric, non-fabric, non-woven fabric and film. Radiation crosslinking is effected with no pressure and is performed at low temperatures. Thus, temperature sensitive additives can be used in radiation crosslinking. The radiation crosslinking and grafting can be easily adjusted and is easily reproducible by controlling the radiation dose. The finished product contains no residuals of substances required to initiate the chemical crosslinking and grafting which can restrict the application possibilities, or can increase the failure rate. In these studies, radiation grafting and crosslinking were used to develop the toxic gas adsorbent, blood compatible polymer, acetabular cup of artificial joint, urokinase adsorbent, hydrogel, hollow fiber membrane adsorbing the heavy metals, and battery separator membrane. Because cable in nuclear power plant is directly related to safe operation, the life assessment of the cable system is an important issue. To assess the degradation and life time of cable is complicated owing to the various types and the different formulation of cable. In order to make an estimate the long term degradation occurring in a material, it is necessary to carry out the accelerated aging studies and to establish the appropriate test method to characterize the degradation. These studies are aimed at the evaluation technique on radiation degradation of polymer material and applying these results to nuclear equipment qualification.

  5. A phase change processor method for solving a one-dimensional phase change problem with convection boundary

    Energy Technology Data Exchange (ETDEWEB)

    Halawa, E.; Saman, W.; Bruno, F. [Institute for Sustainable Systems and Technologies, School of Advanced Manufacturing and Mechanical Engineering, University of South Australia, Mawson Lakes SA 5095 (Australia)

    2010-08-15

    A simple yet accurate iterative method for solving a one-dimensional phase change problem with convection boundary is described. The one-dimensional model takes into account the variation in the wall temperature along the direction of the flow as well as the sensible heat during preheating/pre-cooling of the phase change material (PCM). The mathematical derivation of convective boundary conditions has been integrated into a phase change processor (PCP) algorithm that solves the liquid fraction and temperature of the nodes. The algorithm is based on the heat balance at each node as it undergoes heating or cooling which inevitably involves phase change. The paper presents the model and its experimental validation. (author)

  6. Invert 1.0: A program for solving the nonlinear inverse heat conduction problem for one-dimensional solids

    International Nuclear Information System (INIS)

    Snider, D.M.

    1981-02-01

    INVERT 1.0 is a digital computer program written in FORTRAN IV which calculates the surface heat flux of a one-dimensional solid using an interior-measured temperature and a physical description of the solid. By using two interior-measured temperatures, INVERT 1.0 can provide a solution for the heat flux at two surfaces, the heat flux at a boundary and the time dependent power, or the heat flux at a boundary and the time varying thermal conductivity of a material composing the solid. The analytical solution to inversion problem is described for the one-dimensional cylinder, sphere, or rectangular slab. The program structure, input instructions, and sample problems demonstrating the accuracy of the solution technique are included

  7. Method to map one-dimensional electronic wave function by using multiple Brillouin zone angle resolved photoemission

    Directory of Open Access Journals (Sweden)

    Dong-Wook Lee

    2010-10-01

    Full Text Available Angle resolved photoemission spectroscopy (ARPES is a powerful tool to investigate electronic structures in solids and has been widely used in studying various materials. The electronic structure information by ARPES is obtained in the momentum space. However, in the case of one-dimensional system, we here show that we extract the real space information from ARPES data taken over multiple Brillouin zones (BZs. Intensities in the multiple BZs are proportional to the photoemission matrix element which contains information on the coefficient of the Bloch wave function. It is shown that the Bloch wave function coefficients can be extracted from ARPES data, which allows us to construct the real space wave function. As a test, we use ARPES data from proto-typical one-dimensional system SrCuO2 and construct the real space wave function.

  8. Topology determines force distributions in one-dimensional random spring networks

    Science.gov (United States)

    Heidemann, Knut M.; Sageman-Furnas, Andrew O.; Sharma, Abhinav; Rehfeldt, Florian; Schmidt, Christoph F.; Wardetzky, Max

    2018-02-01

    Networks of elastic fibers are ubiquitous in biological systems and often provide mechanical stability to cells and tissues. Fiber-reinforced materials are also common in technology. An important characteristic of such materials is their resistance to failure under load. Rupture occurs when fibers break under excessive force and when that failure propagates. Therefore, it is crucial to understand force distributions. Force distributions within such networks are typically highly inhomogeneous and are not well understood. Here we construct a simple one-dimensional model system with periodic boundary conditions by randomly placing linear springs on a circle. We consider ensembles of such networks that consist of N nodes and have an average degree of connectivity z but vary in topology. Using a graph-theoretical approach that accounts for the full topology of each network in the ensemble, we show that, surprisingly, the force distributions can be fully characterized in terms of the parameters (N ,z ) . Despite the universal properties of such (N ,z ) ensembles, our analysis further reveals that a classical mean-field approach fails to capture force distributions correctly. We demonstrate that network topology is a crucial determinant of force distributions in elastic spring networks.

  9. Perspective: Toward "synthesis by design": Exploring atomic correlations during inorganic materials synthesis

    Science.gov (United States)

    Soderholm, L.; Mitchell, J. F.

    2016-05-01

    Synthesis of inorganic extended solids is a critical starting point from which real-world functional materials and their consequent technologies originate. However, unlike the rich mechanistic foundation of organic synthesis, with its underlying rules of assembly (e.g., functional groups and their reactivities), the synthesis of inorganic materials lacks an underpinning of such robust organizing principles. In the latter case, any such rules must account for the diversity of chemical species and bonding motifs inherent to inorganic materials and the potential impact of mass transport on kinetics, among other considerations. Without such assembly rules, there is less understanding, less predictive power, and ultimately less control of properties. Despite such hurdles, developing a mechanistic understanding for synthesis of inorganic extended solids would dramatically impact the range of new material discoveries and resulting new functionalities, warranting a broad call to explore what is possible. Here we discuss our recent approaches toward a mechanistic framework for the synthesis of bulk inorganic extended solids, in which either embryonic atomic correlations or fully developed phases in solutions or melts can be identified and tracked during product selection and crystallization. The approach hinges on the application of high-energy x-rays, with their penetrating power and large Q-range, to explore reaction pathways in situ. We illustrate this process using two examples: directed assembly of Zr clusters in aqueous solution and total phase awareness during crystallization from K-Cu-S melts. These examples provide a glimpse of what we see as a larger vision, in which large scale simulations, data-driven science, and in situ studies of atomic correlations combine to accelerate materials discovery and synthesis, based on the assembly of well-defined, prenucleated atomic correlations.

  10. Comment on "Calculations for the one-dimensional soft Coulomb problem and the hard Coulomb limit".

    Science.gov (United States)

    Carrillo-Bernal, M A; Núñez-Yépez, H N; Salas-Brito, A L; Solis, Didier A

    2015-02-01

    In the referred paper, the authors use a numerical method for solving ordinary differential equations and a softened Coulomb potential -1/√[x(2)+β(2)] to study the one-dimensional Coulomb problem by approaching the parameter β to zero. We note that even though their numerical findings in the soft potential scenario are correct, their conclusions do not extend to the one-dimensional Coulomb problem (β=0). Their claims regarding the possible existence of an even ground state with energy -∞ with a Dirac-δ eigenfunction and of well-defined parity eigenfunctions in the one-dimensional hydrogen atom are questioned.

  11. Synthesis, Properties and Mineralogy of Important Inorganic Materials

    DEFF Research Database (Denmark)

    Warner, Terence Edwin

    chosen so as to illustrate the large variety of physico-chemical properties encountered in inorganic materials, and to provide practical experience covering a wide range of preparative methods, with an emphasis on high-temperature techniques. The majority of the materials described in the book relate...... in extending their repertoire of teaching material into the realms of high-temperature synthesis. It is also of interest to professional chemists, physicists, materials scientists and technologists, ceramicists, mineralogists, geologists, geochemists, archaeologists, metallurgists, engineers, and non......-specialists, who are interested in learning more about how technological ceramic materials and artificial minerals are made. Finally, the author assumes that the reader is familiar with the basic principles and concepts of materials chemistry (or at least has access to such knowledge), such as; thermodynamic...

  12. SYNTHESIS AND CHARACTERIZATION OF ADVANCED MAGNETIC MATERIALS

    Energy Technology Data Exchange (ETDEWEB)

    Monica Sorescu

    2004-09-22

    The work described in this grant report was focused mainly on the properties of novel magnetic intermetallics. In the first project, we synthesized several 2:17 intermetallic compounds, namely Nd{sub 2}Fe{sub 15}Si{sub 2}, Nd{sub 2}Fe{sub 15}Al{sub 2}, Nd{sub 2}Fe{sub 15}SiAl and Nd{sub 2}Fe{sub 15}SiMn, as well as several 1:12 intermetallic compounds, such as NdFe{sub 10}Si{sub 2}, NdFe{sub 10}Al{sub 2}, NdFe{sub 10}SiAl and NdFe{sub 10}MnAl. In the second project, seven compositions of Nd{sub x}Fe{sub 100-x-y}B{sub y} ribbons were prepared by a melt spinning method with Nd and B content increasing from 7.3 and 3.6 to 11 and 6, respectively. The alloys were annealed under optimized conditions to obtain a composite material consisting of the hard magnetic Nd{sub 2}Fe{sub 14}B and soft magnetic {alpha}-Fe phases, typical of a spring magnet structure. In the third project, intermetallic compounds of the type Zr{sub 1}Cr{sub 1}Fe{sub 1}T{sub 0.8} with T = Al, Co and Fe were subjected to hydrogenation. In the fourth project, we performed three crucial experiments. In the first experiment, we subjected a mixture of Fe{sub 3}O{sub 4} and Fe (80-20 wt %) to mechanochemical activation by high-energy ball milling, for time periods ranging from 0.5 to 14 hours. In the second experiment, we ball-milled Fe{sub 3}O{sub 4}:Co{sup 2+} (x = 0.1) for time intervals between 2.5 and 17.5 hours. Finally, we exposed a mixture of Fe{sub 3}O{sub 4} and Co (80-20 wt %) to mechanochemical activation for time periods ranging from 0.5 to 10 hours. In all cases, the structural and magnetic properties of the systems involved were elucidated by X-ray diffraction (XRD), Moessbauer spectroscopy and hysteresis loop measurements. The four projects resulted in four papers, which were published in Intermetallics, IEEE Transactions on Magnetics, Journal of Materials Science Letters and Materials Chemistry and Physics. The contributions reveal for the first time in literature the effect of

  13. Synthesis and Materials Design for Heteroanion Compounds

    Science.gov (United States)

    Machida, K.

    2011-02-01

    Oxynitride phosphors, SrSi2O2N2:Eu2+ were synthesized through a conventional solid state reaction between Sr2SiO4:Eu2+ precursor and Si3N4 by using NH4Cl flux, and their luminescence properties were characterized from a viewpoint of the ionic and covalent bond natures as the "heteroanion compound" containing O2- and N3- anions. The structural framework of host lattice is constructed by covalently bonded layers of SiON3 units, suggesting that the rearrangement of O2- and N3- anions effectively takes place between isolated SiO44-anions of the Sr2SiO4:Eu2+ precursor and SiN4 units of the Si3N4 raw material. Furthermore, the layered structure consisting of (Si2O2N2)n2n- polyanions as tightly connected by Si-N-Si covalent bonds depresses the lattice vibration of Sr(Eu)-O or Si-O bond, so that the temperature quenching effect is lowered to give the intense emission for LED-based illumination lamps.

  14. Synthesis and Materials Design for Heteroanion Compounds

    International Nuclear Information System (INIS)

    Machida, K

    2011-01-01

    Oxynitride phosphors, SrSi 2 O 2 N 2 :Eu 2+ were synthesized through a conventional solid state reaction between Sr 2 SiO 4 :Eu 2+ precursor and Si 3 N 4 by using NH 4 Cl flux, and their luminescence properties were characterized from a viewpoint of the ionic and covalent bond natures as the 'heteroanion compound' containing O 2- and N 3- anions. The structural framework of host lattice is constructed by covalently bonded layers of SiON 3 units, suggesting that the rearrangement of O 2- and N 3- anions effectively takes place between isolated SiO4 4- anions of the Sr 2 SiO 4 :Eu 2+ precursor and SiN 4 units of the Si 3 N 4 raw material. Furthermore, the layered structure consisting of (Si 2 O 2 N 2 )n 2n- polyanions as tightly connected by Si-N-Si covalent bonds depresses the lattice vibration of Sr(Eu)-O or Si-O bond, so that the temperature quenching effect is lowered to give the intense emission for LED-based illumination lamps.

  15. Synthesis of Zeolite Materials for Noble Gas Separation

    International Nuclear Information System (INIS)

    Achey, R.; Rivera, O.; Wellons, M.; Hunter, D.

    2017-01-01

    Microporous zeolite adsorbent materials are widely used as a medium for separating gases. Adsorbent gas separation systems can run at ambient temperature and require minimal pressure to flow the input gas stream across the adsorbent bed. This allows for low energy consumption relative to other types of separation systems. Specific zeolites also have a high capacity and selectivity for the gases of interest, leading to compact and efficient separation systems. These characteristics are particularly advantageous for the application of signatures detection for non-proliferation, which often requires portable systems with low power draw. Savannah River National Laboratory currently is the leader in using zeolites for noble gas sampling for non-proliferation detection platforms. However, there is a constant customer need for improved sampling capabilities. Development of improved zeolite materials will lead to improved sampling technology. Microwave-assisted and conventional hydrothermal synthesis have been used to make a variety of zeolites tailored for noble gas separation. Materials characterization data collected in this project has been used to help guide the synthesis of improved zeolite materials. Candidate materials have been down-selected based on highest available surface area, maximum overall capacity for gas adsorption and highest selectivity. The creation of improved adsorbent materials initiated in this project will lead to development of more compact, efficient and effective noble gas collectors and concentrators. The work performed in this project will be used as a foundation for funding proposals for further material development as well as possible industrial applications.

  16. Synthesis of Zeolite Materials for Noble Gas Separation

    Energy Technology Data Exchange (ETDEWEB)

    Achey, R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Rivera, O. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Wellons, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hunter, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-10-02

    Microporous zeolite adsorbent materials are widely used as a medium for separating gases. Adsorbent gas separation systems can run at ambient temperature and require minimal pressure to flow the input gas stream across the adsorbent bed. This allows for low energy consumption relative to other types of separation systems. Specific zeolites also have a high capacity and selectivity for the gases of interest, leading to compact and efficient separation systems. These characteristics are particularly advantageous for the application of signatures detection for non-proliferation, which often requires portable systems with low power draw. Savannah River National Laboratory currently is the leader in using zeolites for noble gas sampling for non-proliferation detection platforms. However, there is a constant customer need for improved sampling capabilities. Development of improved zeolite materials will lead to improved sampling technology. Microwave-assisted and conventional hydrothermal synthesis have been used to make a variety of zeolites tailored for noble gas separation. Materials characterization data collected in this project has been used to help guide the synthesis of improved zeolite materials. Candidate materials have been down-selected based on highest available surface area, maximum overall capacity for gas adsorption and highest selectivity. The creation of improved adsorbent materials initiated in this project will lead to development of more compact, efficient and effective noble gas collectors and concentrators. The work performed in this project will be used as a foundation for funding proposals for further material development as well as possible industrial applications.

  17. Synthesis of material microporous using raw materials alternative as a source of silica and alumina

    International Nuclear Information System (INIS)

    Santos, E.A.; Silva, T.L.

    2014-01-01

    Synthetic zeolites have important properties of a technological viewpoint. Thus, this work aims at the use of natural raw materials such as kaolin waste and wood ash in order to produce these microporous materials. The starting materials were characterized by X-ray diffraction (XRD) and spectroscopy, X-ray fluorescence (XRF); the phases formed as synthesis products were identified by XRD and gravimetric and differential thermal analysis (DTA/TG). Hydrothermal synthesis took place by mixing the raw materials in stoichiometrically calculated batches with NaOH (3M) at 90 °C and time of 6, 20, 24 and 48 hours. The results show the formation of phases of type zeolite A and sodalite, demonstrating the raw materials be an efficient and low cost alternative to producing microporous materials. (author)

  18. Prediction of inorganic superconductors with quasi-one-dimensional crystal structure

    International Nuclear Information System (INIS)

    Volkova, L M; Marinin, D V

    2013-01-01

    Models of superconductors having a quasi-one-dimensional crystal structure based on the convoluted into a tube Ginzburg sandwich, which comprises a layered dielectric–metal–dielectric structure, have been suggested. The critical crystal chemistry parameters of the Ginzburg sandwich determining the possibility of the emergence of superconductivity and the T c value in layered high-T c cuprates, which could have the same functions in quasi-one-dimensional fragments (sandwich-type tubes), have been examined. The crystal structures of known low-temperature superconductors, in which one can mark out similar quasi-one-dimensional fragments, have been analyzed. Five compounds with quasi-one-dimensional structures, which can be considered as potential parents of new superconductor families, possibly with high transition temperatures, have been suggested. The methods of doping and modification of these compounds are provided. (paper)

  19. Critical exponents in the transition to chaos in one-dimensional ...

    Indian Academy of Sciences (India)

    The transition from periodic to chaotic behavior in one-dimensional discrete dynamical systems .... consider the reverse sequence from µb to µ∞, a ... at which the change from one scaling region to another takes place, with the higher order. 12.

  20. Neutron and photon (light) scattering on solitons in the quasi-one-dimensional magnetics

    CERN Document Server

    Abdulloev, K O

    1999-01-01

    The general expression we have found earlier for the dynamics form-factor is used to analyse experiments on the neutron and photon (light) scattering by the gas of solitons in quasi-one-dimensional magnetics (Authors)

  1. Explicit solutions of one-dimensional, first-order, stationary mean-field games with congestion

    KAUST Repository

    Gomes, Diogo A.; Nurbekyan, Levon; Prazeres, Mariana

    2017-01-01

    Here, we consider one-dimensional first-order stationary mean-field games with congestion. These games arise when crowds face difficulty moving in high-density regions. We look at both monotone decreasing and increasing interactions and construct

  2. Solutions stability of one-dimensional parametric superconducting magnetic levitation model analysis by the first approximation

    International Nuclear Information System (INIS)

    Shvets', D.V.

    2009-01-01

    By the first approximation analyzing stability conditions of unperturbed solution of one-dimensional dynamic model with magnetic interaction between two superconducting rings obtained. The stability region in the frozen magnetic flux parameters space was constructed.

  3. Wave Transformation Over Reefs: Evaluation of One-Dimensional Numerical Models

    National Research Council Canada - National Science Library

    Demirbilek, Zeki; Nwogu, Okey G; Ward, Donald L; Sanchez, Alejandro

    2009-01-01

    Three one-dimensional (1D) numerical wave models are evaluated for wave transformation over reefs and estimates of wave setup, runup, and ponding levels in an island setting where the beach is fronted by fringing reef and lagoons...

  4. On symmetry reduction and exact solutions of the linear one-dimensional Schroedinger equation

    International Nuclear Information System (INIS)

    Barannik, L.L.

    1996-01-01

    Symmetry reduction of the Schroedinger equation with potential is carried out on subalgebras of the Lie algebra which is the direct sum of the special Galilei algebra and one-dimensional algebra. Some new exact solutions are obtained

  5. Ultra-refractive and extended-range one-dimensional photonic crystal superprisms

    Science.gov (United States)

    Ting, D. Z. Y.

    2003-01-01

    We describe theoretical analysis and design of one-dimensional photonic crystal prisms. We found that inside the photonic crystal, for frequencies near the band edges, light propagation direction is extremely sensitive to the variations in wavelength and incident angle.

  6. One-Dimensional Tunable Photonic-Crystal IR Filter, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — MetroLaser proposes to design and develop an innovative narrowband tunable IR filter based on the properties of a one-dimensional photonic crystal structure with a...

  7. One-Dimensional Tunable Photonic-Crystal IR Filter, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — MetroLaser proposes to design and develop an innovative narrowband tunable IR filter based on the properties of a one-dimensional photonic crystal structure with a...

  8. A Large Class of Exact Solutions to the One-Dimensional Schrodinger Equation

    Science.gov (United States)

    Karaoglu, Bekir

    2007-01-01

    A remarkable property of a large class of functions is exploited to generate exact solutions to the one-dimensional Schrodinger equation. The method is simple and easy to implement. (Contains 1 table and 1 figure.)

  9. One- and Two- Magnon Excitations in a One-Dimensional Antiferromagnet in a Magnetic Field

    DEFF Research Database (Denmark)

    Heilmann, I.U.; Kjems, Jørgen; Endoh, Y.

    1981-01-01

    We have carried out a comprehensive experimental and theoretical study of the inelastic scattering in the one-dimensional near-Heisenberg antiferromagnet (CD3)4NMnCl3 (TMMC) at low temperatures, 0.3...

  10. Solute transport with periodic input point source in one-dimensional ...

    African Journals Online (AJOL)

    JOY

    groundwater flow velocity is considered proportional to multiple of temporal function and ζ th ... One-dimensional solute transport through porous media with or without .... solute free. ... the periodic concentration at source of the boundary i.e.,. 0.

  11. Spin-zero sound in one- and quasi-one-dimensional 3He

    International Nuclear Information System (INIS)

    Hernandez, E.S.

    2002-01-01

    The zero sound spectrum of fluid 3 He confined to a cylindrical shell is examined for configurations characterizing strictly one-dimensional and quasi-one-dimensional regimes. It is shown that the restricted dimensionality makes room to the possibility of spin-zero sound for the attractive particle-hole interaction of liquid helium. This fact can be related to the suppression of phase instabilities and thermodynamic phase transitions in one dimension

  12. One-Dimensional Creativity: A Marcusean Critique of Work and Play in the Video Game Industry

    Directory of Open Access Journals (Sweden)

    Ergin Bulut

    2018-06-01

    Full Text Available Creativity is at the heart of the video game industry. Industry professionals, especially those producing blockbuster games for the triple-A market, speak fondly of their creative labour practices, flexible work schedules, and playful workplaces. However, a cursory glance at major triple-A franchises reveals the persistence of sequel game production and a homogeneity in genres and narratives. Herbert Marcuse’s critique of one-dimensionality may help to account for this discrepancy between the workers’ creative aspirations and the dominant homogeneity in game aesthetics. What I call ‘one-dimensional creativity’ defines the essence of triple-A game production. In the name of extolling the pleasure principle at work, one-dimensional creativity eliminates the reality principle, but only superficially. One-dimensional creativity gives game developers the opportunity to express themselves, but it is still framed by a particular technological rationality that prioritises profits over experimental art. One-dimensional creativity negates potential forms of creativity that might emerge outside the industry’s hit-driven logics. Conceptually, ‘one-dimensional creativity’ renders visible the instrumentalisation of play and the conservative design principles of triple-A game production – a production that is heavily structured with technological performance, better graphics, interactivity, and speed. Multi-dimensional video game production and aesthetics, the opposite of one-dimensional creativity, is emerging from the DIY game production scene, which is more invested in game narratives and aesthetics outside the dominant logics of one-dimensionality in triple-A game production.

  13. Effective one-dimensionality of universal ac hopping conduction in the extreme disorder limit

    DEFF Research Database (Denmark)

    Dyre, Jeppe; Schrøder, Thomas

    1996-01-01

    A phenomenological picture of ac hopping in the symmetric hopping model (regular lattice, equal site energies, random energy barriers) is proposed according to which conduction in the extreme disorder limit is dominated by essentially one-dimensional "percolation paths." Modeling a percolation path...... as strictly one dimensional with a sharp jump rate cutoff leads to an expression for the universal ac conductivity that fits computer simulations in two and three dimensions better than the effective medium approximation....

  14. Simulation and detection of massive Dirac fermions with cold atoms in one-dimensional optical lattice

    Energy Technology Data Exchange (ETDEWEB)

    Yu Yafei, E-mail: yfyuks@hotmail.com [Laboratory of Nanophotonic Functional Materials and Devices, LQIT and SIPSE, South China Normal University, Guangzhou 510006 (China); Shan Chuanjia [Laboratory of Nanophotonic Functional Materials and Devices, LQIT and SIPSE, South China Normal University, Guangzhou 510006 (China); College of Physics and Electronic Science, Hubei Normal University, Huangshi 435002 (China); Mei Feng; Zhang Zhiming [Laboratory of Nanophotonic Functional Materials and Devices, LQIT and SIPSE, South China Normal University, Guangzhou 510006 (China)

    2012-09-15

    We propose a simple but feasible experimental scheme to simulate and detect Dirac fermions with cold atoms trapped in one-dimensional optical lattice. In our scheme, through tuning the laser intensity, the one-dimensional optical lattice can have two sites in each unit cell and the atoms around the low energy behave as massive Dirac fermions. Furthermore, we show that these relativistic quasiparticles can be detected experimentally by using atomic density profile measurements and Bragg scattering.

  15. Experimental investigation of photonic band gap in one-dimensional photonic crystals with metamaterials

    International Nuclear Information System (INIS)

    Chen, Yihang; Wang, Xinggang; Yong, Zehui; Zhang, Yunjuan; Chen, Zefeng; He, Lianxing; Lee, P.F.; Chan, Helen L.W.; Leung, Chi Wah; Wang, Yu

    2012-01-01

    Composite right/left-handed transmission lines with lumped element series capacitors and shunt inductors are used to experimentally realize the one-dimensional photonic crystals composed of single-negative metamaterials. The simulated and experimental results show that a special photonic band gap corresponding to zero-effective-phase (zero-φ eff ) may appear in the microwave regime. In contrast to the Bragg gap, by changing the length ratio of the two component materials, the width and depth of the zero-φ eff gap can be conveniently adjusted while keeping the center frequency constant. Furthermore, the zero-φ eff gap vanishes when both the phase-matching and impedance-matching conditions are satisfied simultaneously. These transmission line structures provide a good way for realizing microwave devices based on the zero-φ eff gap. -- Highlights: ► 1D photonic crystals with metamaterials were investigated experimentally. ► Both Bragg gap and zero-φ eff gap were observed in the microwave regime. ► The width and depth of the zero-φ eff gap were experimentally adjusted. ► Zero-φ eff gap was observed to be close when two match conditions were satisfied.

  16. Experimental investigation of photonic band gap in one-dimensional photonic crystals with metamaterials

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yihang, E-mail: eon.chen@yahoo.com.cn [Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hong Kong (China); Laboratory of Quantum Information Technology, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou (China); Wang, Xinggang [Laboratory of Quantum Information Technology, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou (China); Yong, Zehui; Zhang, Yunjuan [Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hong Kong (China); Chen, Zefeng [Laboratory of Quantum Information Technology, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou (China); He, Lianxing; Lee, P.F.; Chan, Helen L.W.; Leung, Chi Wah [Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hong Kong (China); Wang, Yu, E-mail: apywang@inet.polyu.edu.hk [Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hong Kong (China)

    2012-03-19

    Composite right/left-handed transmission lines with lumped element series capacitors and shunt inductors are used to experimentally realize the one-dimensional photonic crystals composed of single-negative metamaterials. The simulated and experimental results show that a special photonic band gap corresponding to zero-effective-phase (zero-φ{sub eff}) may appear in the microwave regime. In contrast to the Bragg gap, by changing the length ratio of the two component materials, the width and depth of the zero-φ{sub eff} gap can be conveniently adjusted while keeping the center frequency constant. Furthermore, the zero-φ{sub eff} gap vanishes when both the phase-matching and impedance-matching conditions are satisfied simultaneously. These transmission line structures provide a good way for realizing microwave devices based on the zero-φ{sub eff} gap. -- Highlights: ► 1D photonic crystals with metamaterials were investigated experimentally. ► Both Bragg gap and zero-φ{sub eff} gap were observed in the microwave regime. ► The width and depth of the zero-φ{sub eff} gap were experimentally adjusted. ► Zero-φ{sub eff} gap was observed to be close when two match conditions were satisfied.

  17. One-dimensional thermal response modeling of a transuranic foamed overpack system to a fire

    International Nuclear Information System (INIS)

    Suchsland, K.E.; Kwong, K.C.; Fretter, E.F.; Boyd, R.D.; Auerbach, I.; Yoshimura, H.R.

    1980-01-01

    Procedures have been established for modeling the thermal response of TRU container walls (TRUPACT) exposed to a fire environment. The effort included simulation testing and thermal modeling of the wall material. In this study, both testing and modeling were directed at determining a one-dimensional thermal model for undamaged polyurethane foam. The foam was assumed to exist in a nonoxidizing environment and was exposed to an almost step change in surface temperature. Results indicate that if the TRU waste container wall includes a polyurethane foam (64 kg/m 3 density) of thickness greater than 20 cm and the wall is otherwise undamaged, there will be no change in the waste content temperature where the container is subjected to a surface temperature as high as 1333 K for times less than 3600 s. Further improvements are needed in the thermal model to include transpiration, better estimates of the temperature-dependent thermal conductivity, effects of damaged wall structure and radiation absorption effects for the charged foam. 10 figures

  18. Schottky nanocontact of one-dimensional semiconductor nanostructures probed by using conductive atomic force microscopy

    Science.gov (United States)

    Lee, Jung Ah; Rok Lim, Young; Jung, Chan Su; Choi, Jun Hee; Im, Hyung Soon; Park, Kidong; Park, Jeunghee; Kim, Gyu Tae

    2016-10-01

    To develop the advanced electronic devices, the surface/interface of each component must be carefully considered. Here, we investigate the electrical properties of metal-semiconductor nanoscale junction using conductive atomic force microscopy (C-AFM). Single-crystalline CdS, CdSe, and ZnO one-dimensional nanostructures are synthesized via chemical vapor transport, and individual nanobelts (or nanowires) are used to fabricate nanojunction electrodes. The current-voltage (I -V) curves are obtained by placing a C-AFM metal (PtIr) tip as a movable contact on the nanobelt (or nanowire), and often exhibit a resistive switching behavior that is rationalized by the Schottky (high resistance state) and ohmic (low resistance state) contacts between the metal and semiconductor. We obtain the Schottky barrier height and the ideality factor through fitting analysis of the I-V curves. The present nanojunction devices exhibit a lower Schottky barrier height and a higher ideality factor than those of the bulk materials, which is consistent with the findings of previous works on nanostructures. It is shown that C-AFM is a powerful tool for characterization of the Schottky contact of conducting channels between semiconductor nanostructures and metal electrodes.

  19. Edge state preparation in a one-dimensional lattice by quantum Lyapunov control

    International Nuclear Information System (INIS)

    Zhao, X L; Shi, Z C; Qin, M; Yi, X X

    2017-01-01

    Quantum Lyapunov control uses a feedback control methodology to determine control fields applied to control quantum systems in an open-loop way. In this work, we employ two Lyapunov control schemes to prepare an edge state for a fermionic chain consisting of cold atoms loaded in an optical lattice. Such a chain can be described by the Harper model. Corresponding to the two schemes, two types of quantum Lyapunov functions are considered. The results show that both the schemes are effective at preparing the edge state within a wide range of parameters. We found that the edge state can be prepared with high fidelity even if there are moderate fluctuations of on-site or hopping potentials. Both control schemes can be extended to similar chains (3 m + d , d = 2) of different lengths. Since a regular amplitude control field is easier to apply in practice, an amplitude-modulated control field is used to replace the unmodulated one. Such control approaches provide tools to explore the edge states of one-dimensional topological materials. (paper)

  20. A Comprehensive Review of Semiconductor Ultraviolet Photodetectors: From Thin Film to One-Dimensional Nanostructures

    Directory of Open Access Journals (Sweden)

    Liwen Sang

    2013-08-01

    Full Text Available Ultraviolet (UV photodetectors have drawn extensive attention owing to their applications in industrial, environmental and even biological fields. Compared to UV-enhanced Si photodetectors, a new generation of wide bandgap semiconductors, such as (Al, In GaN, diamond, and SiC, have the advantages of high responsivity, high thermal stability, robust radiation hardness and high response speed. On the other hand, one-dimensional (1D nanostructure semiconductors with a wide bandgap, such as β-Ga2O3, GaN, ZnO, or other metal-oxide nanostructures, also show their potential for high-efficiency UV photodetection. In some cases such as flame detection, high-temperature thermally stable detectors with high performance are required. This article provides a comprehensive review on the state-of-the-art research activities in the UV photodetection field, including not only semiconductor thin films, but also 1D nanostructured materials, which are attracting more and more attention in the detection field. A special focus is given on the thermal stability of the developed devices, which is one of the key characteristics for the real applications.

  1. Dynamics in a one-dimensional ferrogel model: relaxation, pairing, shock-wave propagation.

    Science.gov (United States)

    Goh, Segun; Menzel, Andreas M; Löwen, Hartmut

    2018-05-23

    Ferrogels are smart soft materials, consisting of a polymeric network and embedded magnetic particles. Novel phenomena, such as the variation of the overall mechanical properties by external magnetic fields, emerge consequently. However, the dynamic behavior of ferrogels remains largely unveiled. In this paper, we consider a one-dimensional chain consisting of magnetic dipoles and elastic springs between them as a simple model for ferrogels. The model is evaluated by corresponding simulations. To probe the dynamics theoretically, we investigate a continuum limit of the energy governing the system and the corresponding equation of motion. We provide general classification scenarios for the dynamics, elucidating the touching/detachment dynamics of the magnetic particles along the chain. In particular, it is verified in certain cases that the long-time relaxation corresponds to solutions of shock-wave propagation, while formations of particle pairs underlie the initial stage of the dynamics. We expect that these results will provide insight into the understanding of the dynamics of more realistic models with randomness in parameters and time-dependent magnetic fields.

  2. Photonic band gap properties of one-dimensional Thue-Morse all-dielectric photonic quasicrystal

    Science.gov (United States)

    Yue, Chenxi; Tan, Wei; Liu, Jianjun

    2018-05-01

    In this paper, the photonic band gap (PBG) properties of one-dimensional (1D) Thue-Morse photonic quasicrystal (PQC) S4 structure are theoretically investigated by using transfer matrix method in Bragg condition. The effects of the center wavelength, relative permittivity and incident angle on PBG properties are elaborately analyzed. Numerical results reveal that, in the case of normal incidence, the symmetry and periodicity properties of the photonic band structure are presented. As the center wavelength increases, the PBG center frequency and PBG width decrease while the photonic band structure is always symmetrical about the central frequency and the photonic band structure repeats periodically in the expanding observation frequency range. With the decrease of relative permittivity contrast, the PBG width and the relative PBG width gradually decreases until PBG disappears while the symmetry of the photonic band structure always exists. In the case of oblique incidence, as the incident angle increases, multiple narrow PBGs gradually merge into a wide PBG for the TE mode while for the TM mode, the number of PBG continuously decreases and eventually disappears, i.e., multiple narrow PBGs become a wide passband for the TM mode. The research results will provide a reference for the choice of the material, the incident angle for the PBG properties and its applications of 1D Thue-Morse PQC.

  3. Investigating Recombination and Charge Carrier Dynamics in a One-Dimensional Nanopillared Perovskite Absorber.

    Science.gov (United States)

    Kwon, Hyeok-Chan; Yang, Wooseok; Lee, Daehee; Ahn, Jihoon; Lee, Eunsong; Ma, Sunihl; Kim, Kyungmi; Yun, Seong-Cheol; Moon, Jooho

    2018-05-22

    Organometal halide perovskite materials have become an exciting research topic as manifested by intense development of thin film solar cells. Although high-performance solar-cell-based planar and mesoscopic configurations have been reported, one-dimensional (1-D) nanostructured perovskite solar cells are rarely investigated despite their expected promising optoelectrical properties, such as enhanced charge transport/extraction. Herein, we have analyzed the 1-D nanostructure effects of organometal halide perovskite (CH 3 NH 3 PbI 3- x Cl x ) on recombination and charge carrier dynamics by utilizing a nanoporous anodized alumina oxide scaffold to fabricate a vertically aligned 1-D nanopillared array with controllable diameters. It was observed that the 1-D perovskite exhibits faster charge transport/extraction characteristics, lower defect density, and lower bulk resistance than the planar counterpart. As the aspect ratio increases in the 1-D structures, in addition, the charge transport/extraction rate is enhanced and the resistance further decreases. However, when the aspect ratio reaches 6.67 (diameter ∼30 nm), the recombination rate is aggravated due to high interface-to-volume ratio-induced defect generation. To obtain the full benefits of 1-D perovskite nanostructuring, our study provides a design rule to choose the appropriate aspect ratio of 1-D perovskite structures for improved photovoltaic and other optoelectrical applications.

  4. Facile synthesis of one dimensional ZnO nanostructures for DSSC applications

    International Nuclear Information System (INIS)

    Marimuthu, T.; Anandhan, N.

    2016-01-01

    Development of zinc oxide (ZnO) nanostructure based third generation dye sensitized solar cell is interesting compared to conventional silicon solar cells. ZnO nanostructured thin films were electrochemically deposited onto fluorine doped tin oxide (FTO) glass substrate. The effect of ethylene-diamine-tetra-acetic acid (EDTA) on structural, morphological and optical properties is investigated using X-ray diffraction (XRD) meter, field emission scanning electron microscope (FE-SEM) and micro Raman spectroscopy. XRD patterns reveal that the prepared nanostructures are hexagonal wutrzite structures with (101) plane orientation, the nanostructure prepared using EDTA exhibits better crystallinity. FE-SEM images illustrate that the morphological changes are observed from nanorod structure to cauliflower like structure as EDTA is added. Micro Raman spectra predict that cauliflower like structure possesses a higher crystalline nature with less atomic defects compared to nanorod structures. Dye sensitized solar cell (DSSC) is constructed for the optimized cauliflower structure, and open circuit voltage, short circuit density, fill factor and efficiency are estimated from the J-V curve.

  5. Facile synthesis of one dimensional ZnO nanostructures for DSSC applications

    Energy Technology Data Exchange (ETDEWEB)

    Marimuthu, T.; Anandhan, N., E-mail: anandhan-kn@rediffmail.com [Advanced Materials and Thin Film Physics Lab, School of Physics, Alagappa University, Karaikudi – 630 003, India. (India)

    2016-05-06

    Development of zinc oxide (ZnO) nanostructure based third generation dye sensitized solar cell is interesting compared to conventional silicon solar cells. ZnO nanostructured thin films were electrochemically deposited onto fluorine doped tin oxide (FTO) glass substrate. The effect of ethylene-diamine-tetra-acetic acid (EDTA) on structural, morphological and optical properties is investigated using X-ray diffraction (XRD) meter, field emission scanning electron microscope (FE-SEM) and micro Raman spectroscopy. XRD patterns reveal that the prepared nanostructures are hexagonal wutrzite structures with (101) plane orientation, the nanostructure prepared using EDTA exhibits better crystallinity. FE-SEM images illustrate that the morphological changes are observed from nanorod structure to cauliflower like structure as EDTA is added. Micro Raman spectra predict that cauliflower like structure possesses a higher crystalline nature with less atomic defects compared to nanorod structures. Dye sensitized solar cell (DSSC) is constructed for the optimized cauliflower structure, and open circuit voltage, short circuit density, fill factor and efficiency are estimated from the J-V curve.

  6. Cermet materials prepared by combustion synthesis and metal infiltration

    Science.gov (United States)

    Holt, Joseph B.; Dunmead, Stephen D.; Halverson, Danny C.; Landingham, Richard L.

    1991-01-01

    Ceramic-metal composites (cermets) are made by a combination of self-propagating high temperature combustion synthesis and molten metal infiltration. Solid-gas, solid-solid and solid-liquid reactions of a powder compact produce a porous ceramic body which is infiltrated by molten metal to produce a composite body of higher density. AlN-Al and many other materials can be produced.

  7. Nanoporous ionic organic networks: from synthesis to materials applications

    OpenAIRE

    Sun, Jian-Ke; Antonietti, Markus; Yuan, Jiayin

    2016-01-01

    The past decade has witnessed rapid progress in the synthesis of nanoporous organic networks or polymer frameworks for various potential applications. Generally speaking, functionalization of porous networks to add extra properties and enhance materials performance could be achieved either during the pore formation (thus a concurrent approach) or by post-synthetic modification (a sequential approach). Nanoporous organic networks which include ion pairs bound in a covalent manner are of specia...

  8. Radiation synthesis of the nano-scale materials

    Energy Technology Data Exchange (ETDEWEB)

    Yonghong, Ni; Zhicheng, Zhang; Xuewu, Ge; Xiangling, Xu [Department of Applied Chemistry, Univ. of Science and Technology of China, Hefei (China)

    2000-03-01

    Some recent research jobs on fabricating the nano-scale materials via {gamma}-irradiation in our laboratory are simply summarized in this paper. The main contents contain four aspects: (1) the preparation of metal alloy - powders; (2) the fabrication of polymer -metal nano-composites in aqueous solution, micro-emulsion and emulsion systems; (3) the synthesis of metal sulfide nano-particles and (4) the preparation of the ordered nano-structure materials. The corresponding preparation processes are also simply described. (author)

  9. Radiation synthesis of the nano-scale materials

    International Nuclear Information System (INIS)

    Ni Yonghong; Zhang Zhicheng; Ge Xuewu; Xu Xiangling

    2000-01-01

    Some recent research jobs on fabricating the nano-scale materials via γ-irradiation in our laboratory are simply summarized in this paper. The main contents contain four aspects: (1) the preparation of metal alloy - powders; (2) the fabrication of polymer -metal nano-composites in aqueous solution, micro-emulsion and emulsion systems; (3) the synthesis of metal sulfide nano-particles and (4) the preparation of the ordered nano-structure materials. The corresponding preparation processes are also simply described. (author)

  10. One-dimensional carbon nanotube@barium titanate@polyaniline multiheterostructures for microwave absorbing application

    Science.gov (United States)

    Ni, Qing-Qing; Zhu, Yao-Feng; Yu, Lu-Jun; Fu, Ya-Qin

    2015-04-01

    Multiple-phase nanocomposites filled with carbon nanotubes (CNTs) have been developed for their significant potential in microwave attenuation. The introduction of other phases onto the CNTs to achieve CNT-based heterostructures has been proposed to obtain absorbing materials with enhanced microwave absorption properties and broadband frequency due to their different loss mechanisms. The existence of polyaniline (PANI) as a coating with controllable electrical conductivity can lead to well-matched impedance. In this work, a one-dimensional CNT@BaTiO3@PANI heterostructure composite was fabricated. The fabrication processes involved coating of an acid-modified CNT with BaTiO3 (CNT@BaTiO3) through a sol-gel technique followed by combustion and the formation of CNT@BaTiO3@PANI nanohybrids by in situ polymerization of an aniline monomer in the presence of CNT@BaTiO3, using ammonium persulfate as an oxidant and HCl as a dopant. The as-synthesized CNT@BaTiO3@PANI composites with heterostructures were confirmed by various morphological and structural characterization techniques, as well as conductivity and microwave absorption properties. The measured electromagnetic parameters showed that the CNT@BaTiO3@PANI composites exhibited excellent microwave absorption properties. The minimum reflection loss of the CNT@BaTiO3@PANI composites with 20 wt % loadings in paraffin wax reached -28.9 dB (approximately 99.87% absorption) at 10.7 GHz with a thickness of 3 mm, and a frequency bandwidth less than -20 dB was achieved from 10 to 15 GHz. This work demonstrated that the CNT@BaTiO3@PANI heterostructure composite can be potentially useful in electromagnetic stealth materials, sensors, and electronic devices.

  11. One-Dimensional Vanadium Dioxide Nanostructures for Room Temperature Hydrogen Sensors

    Directory of Open Access Journals (Sweden)

    Aline Simo

    2015-06-01

    Full Text Available In relation to hydrogen (H2 economy in general and gas sensing in particular, an extensive set of one dimensional (1-D nano-scaled oxide materials are being investigated as ideal candidates for potential gas sensing applications. This is correlated to their set of singular surface characteristics, shape anisotropy and readiness for integrated devices. Nanostructures of well- established gas sensing materials such as Tin Oxide (SnO2, Zinc Oxide (ZnO, Indium (III Oxide (In2O3, and Tungsten Trioxide (WO3 have shown higher sensitivity and gas selectivity, quicker response, faster time recovery, as well as an enhanced capability to detect gases at low concentrations. While the overall sensing characteristics of these so called 1-D nanomaterials are superior, they are efficient at high temperature; generally above 200 0C. This operational impediment results in device complexities in integration that limit their technological applications, specifically in their miniaturized arrangements. Unfortunately, for room temperature applications, there is a necessity to dope the above mentioned nano-scaled oxides with noble metals such as Platinum (Pt, Palladium (Pd, Gold (Au, Ruthenium (Ru. This comes at a cost. This communication reports, for the first time, on the room temperature enhanced H2 sensing properties of a specific phase of pure Vanadium Dioxide (VO2 phase A in their nanobelt form. The relatively observed large H2 room temperature sensing in this Mott type specific oxide seems to reach values as low as 14 ppm H2 which makes it an ideal gas sensing in H2 fuelled systems.

  12. Visualizing One-Dimensional Electronic States and their Scattering in Semi-conducting Nanowires

    Science.gov (United States)

    Beidenkopf, Haim; Reiner, Jonathan; Norris, Andrew; Nayak, Abhay Kumar; Avraham, Nurit; Shtrikman, Hadas

    One-dimensional electronic systems constitute a fascinating playground for the emergence of exotic electronic effects and phases, within and beyond the Tomonaga-Luttinger liquid paradigm. More recently topological superconductivity and Majorana modes were added to that long list of phenomena. We report scanning tunneling microscopy and spectroscopy measurements conducted on pristine, epitaxialy grown InAs nanowires. We resolve the 1D electronic band structure manifested both via Van-Hove singularities in the local density-of-states, as well as by the quasi-particle interference patterns, induced by scattering from surface impurities. By studying the scattering of the one-dimensional electronic states off various scatterers, including crystallographic defects and the nanowire end, we identify new one-dimensional relaxation regimes and yet unexplored effects of interactions. Some of these may bear implications on the topological superconducting state and Majorana modes therein. The authors acknowledge support from the Israeli Science Foundation (ISF).

  13. Method and apparatus for the electro-optic convolution of a one-dimensional signal

    International Nuclear Information System (INIS)

    1979-01-01

    Procedure for the electro-optic convolution of a signal and a filter function, whereby the one dimensional electro-optical signal would be portrayed as a line along which the clarity varies and whereby filter function is determined by one or more masks, whilst after each mask is placed a light detector, with which the light passing through the masks may be detected, whilst a one-dimensional portrayal of the signal along the masks will be developed, characterised in that a one dimensional portrayal of the signal, with the aid of an optical system in a direction across the line, will be enlarged, and that this enlarged signal in the direction of the line along the masks will be affected which the masks closing fields will contain, which are either fully transparent or are fully non-transparent. (Auth.)

  14. Quantum phase transitions in matrix product states of one-dimensional spin-1 chains

    International Nuclear Information System (INIS)

    Zhu Jingmin

    2014-01-01

    We present a new model of quantum phase transitions in matrix product systems of one-dimensional spin-1 chains and study the phases coexistence phenomenon. We find that in the thermodynamic limit the proposed system has three different quantum phases and by adjusting the control parameters we are able to realize any phase, any two phases equal coexistence and the three phases equal coexistence. At every critical point the physical quantities including the entanglement are not discontinuous and the matrix product system has long-range correlation and N-spin maximal entanglement. We believe that our work is helpful for having a comprehensive understanding of quantum phase transitions in matrix product states of one-dimensional spin chains and of certain directive significance to the preparation and control of one-dimensional spin lattice models with stable coherence and N-spin maximal entanglement. (author)

  15. Quantum interference of ballistic carriers in one-dimensional semiconductor rings

    International Nuclear Information System (INIS)

    Bagraev, N.T.; Buravlev, A.D.; Klyachkin, L.E.; Malyarenko, A.M.; Ivanov, V.K.; Rykov, S.A.; Shelykh, I.A.

    2000-01-01

    Quantum interference of ballistic carriers has been studied for the first time, using one-dimensional rings formed by quantum wire pairs in self-assembled silicon quantum wells. Energy dependencies of the transmission coefficient is calculated as a function of the length and modulation of the quantum wire pairs separated by a unified drain-source system or the quantum point contacts. The quantum conductance is predicted to be increased by a factor of four using the unified drain-source system as a result of the quantum interference. Theoretical dependencies are revealed by the quantum conductance oscillations created by the deviations of both the drain-source voltage and external magnetic field inside the silicon one-dimensional rings. The results obtained put forward a basis to create the Aharonov-Bohm interferometer using the silicon one-dimensional ring [ru

  16. One dimensional neutron kinetics in the TRAC-BF1 code

    International Nuclear Information System (INIS)

    Weaver, W.L. III; Wagner, K.C.

    1987-01-01

    The TRAC-BWR code development program at the Idaho National Engineering Laboratory is developing a version of the TRAC code for the U.S. Nuclear Regulatory Commission (USNRC) to provide a best-estimate analysis capability for the simulation of postulated accidents in boiling water reactor (BWR) power systems and related experimental facilities. Recent development efforts in the TRAC-BWR program have focused on improving the computational efficiency through the incorporation of a hybrid Courant- limit-violating numerical solution scheme in the one-dimensional component models and on improving code accuracy through the development of a one-dimensional neutron kinetics model. Many other improvements have been incorporated into TRAC-BWR to improve code portability, accuracy, efficiency, and maintainability. This paper will describe the one- dimensional neutron kinetics model, the generation of the required input data for this model, and present results of the first calculations using the model

  17. Quantum Solitons and Localized Modes in a One-Dimensional Lattice Chain with Nonlinear Substrate Potential

    International Nuclear Information System (INIS)

    Li Dejun; Mi Xianwu; Deng Ke; Tang Yi

    2006-01-01

    In the classical lattice theory, solitons and localized modes can exist in many one-dimensional nonlinear lattice chains, however, in the quantum lattice theory, whether quantum solitons and localized modes can exist or not in the one-dimensional lattice chains is an interesting problem. By using the number state method and the Hartree approximation combined with the method of multiple scales, we investigate quantum solitons and localized modes in a one-dimensional lattice chain with the nonlinear substrate potential. It is shown that quantum solitons do exist in this nonlinear lattice chain, and at the boundary of the phonon Brillouin zone, quantum solitons become quantum localized modes, phonons are pinned to the lattice of the vicinity at the central position j = j 0 .

  18. A one-dimensional plasma and impurity transport model for reversed field pinches

    International Nuclear Information System (INIS)

    Veerasingam, R.

    1991-11-01

    In this thesis a one-dimensional (1-D) plasma and impurity transport model is developed to address issues related to impurity behavior in Reversed Field Pinch (RFP) fusion plasmas. A coronal non-equilibrium model is used for impurities. The impurity model is incorporated into an existing one dimensional plasma transport model creating a multi-species plasma transport model which treats the plasma and impurity evolution self-consistently. Neutral deuterium particles are treated using a one-dimensional (slab) model of neutral transport. The resulting mode, RFPBI, is then applied to existing RFP devices such as ZT-40M and MST, and also to examine steady state behavior of ZTH based on the design parameters. A parallel algorithm for the impurity transport equations is implemented and tested to determine speedup and efficiency

  19. The one-dimensional Gross-Pitaevskii equation and its some excitation states

    Energy Technology Data Exchange (ETDEWEB)

    Prayitno, T. B., E-mail: trunk-002@yahoo.com [Physics Department, Faculty of Mathematics and Natural Science, Universitas Negeri Jakarta, Jl. Pemuda Rawamangun no. 10, Jakarta, 13220 (Indonesia)

    2015-04-16

    We have derived some excitation states of the one-dimensional Gross-Pitaevskii equation coupled by the gravitational potential. The methods that we have used here are taken by pursuing the recent work of Kivshar et. al. by considering the equation as a macroscopic quantum oscillator. To obtain the states, we have made the appropriate transformation to reduce the three-dimensional Gross-Pitaevskii equation into the one-dimensional Gross-Pitaevskii equation and applying the time-independent perturbation theory in the general solution of the one-dimensional Gross-Pitaevskii equation as a linear superposition of the normalized eigenfunctions of the Schrödinger equation for the harmonic oscillator potential. Moreover, we also impose the condition by assuming that some terms in the equation should be so small in order to preserve the use of the perturbation method.

  20. Equilibrium charge distribution on a finite straight one-dimensional wire

    Science.gov (United States)

    Batle, Josep; Ciftja, Orion; Abdalla, Soliman; Elhoseny, Mohamed; Alkhambashi, Majid; Farouk, Ahmed

    2017-09-01

    The electrostatic properties of uniformly charged regular bodies are prominently discussed on college-level electromagnetism courses. However, one of the most basic problems of electrostatics that deals with how a continuous charge distribution reaches equilibrium is rarely mentioned at this level. In this work we revisit the problem of equilibrium charge distribution on a straight one-dimensional (1D) wire with finite length. The majority of existing treatments in the literature deal with the 1D wire as a limiting case of a higher-dimensional structure that can be treated analytically for a Coulomb interaction potential between point charges. Surprisingly, different models (for instance, an ellipsoid or a cylinder model) may lead to different results, thus there is even some ambiguity on whether the problem is well-posed. In this work we adopt a different approach where we do not start with any higher-dimensional body that reduces to a 1D wire in the appropriate limit. Instead, our starting point is the obvious one, a finite straight 1D wire that contains charge. However, the new tweak in the model is the assumption that point charges interact with each other via a non-Coulomb power-law interaction potential. This potential is well-behaved, allows exact analytical results and approaches the standard Coulomb interaction potential as a limit. The results originating from this approach suggest that the equilibrium charge distribution for a finite straight 1D wire is a uniform charge density when the power-law interaction potential approaches the Coulomb interaction potential as a suitable limit. We contrast such a finding to results obtained using a different regularised logarithmic interaction potential which allows exact treatment in 1D. The present self-contained material may be of interest to instructors teaching electromagnetism as well as students who will discover that simple-looking problems may sometimes pose important scientific challenges.

  1. Equilibrium charge distribution on a finite straight one-dimensional wire

    International Nuclear Information System (INIS)

    Batle, Josep; Ciftja, Orion; Abdalla, Soliman; Elhoseny, Mohamed; Farouk, Ahmed; Alkhambashi, Majid

    2017-01-01

    The electrostatic properties of uniformly charged regular bodies are prominently discussed on college-level electromagnetism courses. However, one of the most basic problems of electrostatics that deals with how a continuous charge distribution reaches equilibrium is rarely mentioned at this level. In this work we revisit the problem of equilibrium charge distribution on a straight one-dimensional (1D) wire with finite length. The majority of existing treatments in the literature deal with the 1D wire as a limiting case of a higher-dimensional structure that can be treated analytically for a Coulomb interaction potential between point charges. Surprisingly, different models (for instance, an ellipsoid or a cylinder model) may lead to different results, thus there is even some ambiguity on whether the problem is well-posed. In this work we adopt a different approach where we do not start with any higher-dimensional body that reduces to a 1D wire in the appropriate limit. Instead, our starting point is the obvious one, a finite straight 1D wire that contains charge. However, the new tweak in the model is the assumption that point charges interact with each other via a non-Coulomb power-law interaction potential. This potential is well-behaved, allows exact analytical results and approaches the standard Coulomb interaction potential as a limit. The results originating from this approach suggest that the equilibrium charge distribution for a finite straight 1D wire is a uniform charge density when the power-law interaction potential approaches the Coulomb interaction potential as a suitable limit. We contrast such a finding to results obtained using a different regularised logarithmic interaction potential which allows exact treatment in 1D. The present self-contained material may be of interest to instructors teaching electromagnetism as well as students who will discover that simple-looking problems may sometimes pose important scientific challenges. (paper)

  2. Pseudo-One-Dimensional Magnonic Crystals for High-Frequency Nanoscale Devices

    Science.gov (United States)

    Banerjee, Chandrima; Choudhury, Samiran; Sinha, Jaivardhan; Barman, Anjan

    2017-07-01

    The synthetic magnonic crystals (i.e., periodic composites consisting of different magnetic materials) form one fascinating class of emerging research field, which aims to command the process and flow of information by means of spin waves, such as in magnonic waveguides. One of the intriguing features of magnonic crystals is the presence and tunability of band gaps in the spin-wave spectrum, where the high attenuation of the frequency bands can be utilized for frequency-dependent control on the spin waves. However, to find a feasible way of band tuning in terms of a realistic integrated device is still a challenge. Here, we introduce an array of asymmetric saw-tooth-shaped width-modulated nanoscale ferromagnetic waveguides forming a pseudo-one-dimensional magnonic crystal. The frequency dispersion of collective modes measured by the Brillouin light-scattering technique is compared with the band diagram obtained by numerically solving the eigenvalue problem derived from the linearized Landau-Lifshitz magnetic torque equation. We find that the magnonic band-gap width, position, and the slope of dispersion curves are controllable by changing the angle between the spin-wave propagation channel and the magnetic field. The calculated profiles of the dynamic magnetization reveal that the corrugation at the lateral boundary of the waveguide effectively engineers the edge modes, which forms the basis of the interactive control in magnonic circuits. The results represent a prospective direction towards managing the internal field distribution as well as the dispersion properties, which find potential applications in dynamic spin-wave filters and magnonic waveguides in the gigahertz frequency range.

  3. Exploring arrays of vertical one-dimensional nanostructures for cellular investigations

    International Nuclear Information System (INIS)

    Bonde, Sara; Buch-Månson, Nina; Rostgaard, Katrine R; Andersen, Tor Kristian; Berthing, Trine; Martinez, Karen L

    2014-01-01

    The endeavor of exploiting arrays of vertical one-dimensional (1D) nanostructures (NSs) for cellular applications has recently been experiencing a pronounced surge of activity. The interest is rooted in the intrinsic properties of high-aspect-ratio NSs. With a height comparable to a mammalian cell, and a diameter 100–1000 times smaller, NSs should intuitively reach far into a cell and, due to their small diameter, do so without compromising cell health. Single NSs would thus be expedient for measuring and modifying cell response. Further organization of these structures into arrays can provide up-scaled and detailed spatiotemporal information on cell activity, an achievement that would entail a massive leap forward in disease understanding and drug discovery. Numerous proofs-of-principle published recently have expanded the large toolbox that is currently being established in this rapidly advancing field of research. Encouragingly, despite the diversity of NS platforms and experimental conditions used thus far, general trends and conclusions from combining cells with NSs are beginning to crystallize. This review covers the broad spectrum of NS materials and dimensions used; the observed cellular responses with specific focus on adhesion, morphology, viability, proliferation, and migration; compares the different approaches used in the field to provide NSs with the often crucial cytosolic access; covers the progress toward biological applications; and finally, envisions the future of this technology. By maintaining the impressive rate and quality of recent progress, it is conceivable that the use of vertical 1D NSs may soon be established as a superior choice over other current techniques, with all the further benefits that may entail. (topical review)

  4. Revealing origin of quasi-one dimensional current transport in defect rich two dimensional materials

    DEFF Research Database (Denmark)

    Lotz, Mikkel Rønne; Boll, Mads; Hansen, Ole

    2014-01-01

    to a non-uniform current flow characteristic of lower dimensionality. In this work, simulations based on a finite element method together with a Monte Carlo approach are used to establish the transition from 2D to quasi-1D current transport, when applying a micro four-point probe to measure on 2D...... conductors with an increasing amount of line-shaped defects. Clear 2D and 1D signatures are observed at low and high defect densities, respectively, and current density plots reveal the presence of current channels or branches in defect configurations yielding 1D current transport. A strong correlation...

  5. One-dimensional tunable photonic crystals with spin crossover material for the terahertz range

    Czech Academy of Sciences Publication Activity Database

    Mounaix, P.; Freysz, E.; Degert, J.; Daro, N.; Létard, J.-F.; Kužel, Petr; Vigneras, V.; Oyenhart, L.

    2006-01-01

    Roč. 89, č. 17 (2006), 174105/1-174105/3 ISSN 0003-6951 R&D Projects: GA MŠk LC512 Institutional research plan: CEZ:AV0Z10100520 Keywords : terahertz * spin crossover * Bragg filter Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.977, year: 2006

  6. Revealing origin of quasi-one dimensional current transport in defect rich two dimensional materials

    International Nuclear Information System (INIS)

    Lotz, Mikkel R.; Boll, Mads; Bøggild, Peter; Petersen, Dirch H.; Hansen, Ole; Kjær, Daniel

    2014-01-01

    The presence of defects in graphene have for a long time been recognized as a bottleneck for its utilization in electronic and mechanical devices. We recently showed that micro four-point probes may be used to evaluate if a graphene film is truly 2D or if defects in proximity of the probe will lead to a non-uniform current flow characteristic of lower dimensionality. In this work, simulations based on a finite element method together with a Monte Carlo approach are used to establish the transition from 2D to quasi-1D current transport, when applying a micro four-point probe to measure on 2D conductors with an increasing amount of line-shaped defects. Clear 2D and 1D signatures are observed at low and high defect densities, respectively, and current density plots reveal the presence of current channels or branches in defect configurations yielding 1D current transport. A strong correlation is found between the density filling factor and the simulation yield, the fraction of cases with 1D transport and the mean sheet conductance. The upper transition limit is shown to agree with the percolation threshold for sticks. Finally, the conductance of a square sample evaluated with macroscopic edge contacts is compared to the micro four-point probe conductance measurements and we find that the micro four-point probe tends to measure a slightly higher conductance in samples containing defects

  7. Study of Growth Kinetics in One Dimensional and Two Dimensional ZnO Nanostructures

    Science.gov (United States)

    Yin, Xin

    Because of the merits arising from the unique geometry, nanostructure materials have been an essential class of materials, which have shown great potentials in the fields of electronics, photonics, and biology. With various nanostructures being intensively investigated and successfully complemented into device applications, there has been one increasing demand to the investigation of the growth mechanism devoted to the controlled nanostructure synthesis. Motivated by this situation, this thesis is focused on the fundamental understanding of the nanostructure growth. Specifically, by taking zinc oxide as an example material, through controlling the basic driving force, that is, the supersaturation, I have rationally designed and synthesized various of nanostructures, and further applied the classical layer-by-layer growth mechanism to the understanding on the formation of these nanostructures, they are, the convex-plate-capped nanowires, the concave-plate-capped nanowires, the facet evolution at the tip of the nanowires, and the ultrathin 2D nanosheets.

  8. Apparent destruction of superconductivity in the disordered one-dimensional limit

    International Nuclear Information System (INIS)

    Graybeal, J.M.; Mankiewich, P.M.; Dynes, R.C.; Beasley, M.R.

    1987-01-01

    We present the results of a model-system study of the competition between superconductivity and disorder in narrow superconducting wires. As one moves from the two-dimensional regime toward the one-dimensional limit, large and systematic reductions in the superconducting transition temperature are obtained. The observed behavior extrapolates to the total destruction of superconductivity in the disordered one-dimensional limit. Our findings are in clear disagreement with a recent theoretical treatment. In addition, the superconducting fluctuations appear to be modified by disorder for the narrowest samples

  9. Optimally localized Wannier functions for quasi one-dimensional nonperiodic insulators

    DEFF Research Database (Denmark)

    Cornean, Horia; Nenciu, A.; Nenciu, Gheorghe

    2008-01-01

    It is proved that for general, not necessarily periodic, quasi one-dimensional systems the band position operator corresponding to an isolated part of the energy spectrum has discrete spectrum and its eigenfunctions have the same spatial localization as the corresponding spectral projection....... As a consequence, an eigenbasis of the band position operator provides a basis of optimally localized (generalized) Wannier functions for quasi one-dimensional systems, and this proves the strong Marzari-Vanderbilt conjecture. If the system has some translation symmetries (e.g. usual translations, screw...

  10. Optimally localized Wannier functions for quasi one-dimensional nonperiodic insulators

    DEFF Research Database (Denmark)

    Cornean, Horia; Nenciu, A.; Nenciu, Gheorghe

    It is proved that for general, not necessarily periodic quasi one dimensional systems, the band position operator corresponding to an isolated part of the energy spectrum has discrete spectrum and its eigenfunctions have the same spatial localization as the corresponding spectral projection....... As a consequence, an eigenbasis of the band position operator provides a basis of optimally localized (generalized) Wannier functions for quasi one dimensional systems. If the system has some translation symmetries (e.g. usual translations, screw transformations), they are "inherited" bythe Wannier basis....

  11. Von Neumann Entropy of an Electron in One-Dimensional Determined Potentials

    Institute of Scientific and Technical Information of China (English)

    GONG Long-Yan; TONG Pei-Qing

    2005-01-01

    @@ By using the measure of von Neumann entropy, we numerically investigate quantum entanglement of an electronmoving in the one-dimensional Harper model and in the one-dimensional slowly varying potential model. Thedelocalized and localized eigenstates can be distinguished by von Neumann entropy of the individual eigenstates.There are drastic decreases in yon Neumann entropy of the individual eigenstates at mobility edges. In the curveof the spectrum averaged yon Neumann entropy as a function of potential parameter λ, a sharp transition existsat the metal-insulator transition point λc = 2. It is found that the yon Neumann entropy is a good quantity toreflect localization and metal-insulator transition.

  12. Longitudinal and spin Hall conductance of a one-dimensional Aharonov-Bohm ring

    International Nuclear Information System (INIS)

    Moca, Catalin Pascu; Marinescu, D C

    2006-01-01

    The longitudinal and spin Hall conductances of an electron gas with Rashba-Dresselhaus spin-orbit interaction, confined to a quasi-one-dimensional Aharonov-Bohm ring, are studied as functions of disorder and magnetic flux. The system is mapped onto a one-dimensional virtual lattice and is described, in a tight binding approximation, by a Hamiltonian that depends parametrically on the nearest neighbour hopping integral t, the Rashba spin-orbit coupling V R , the Dresselhaus spin-orbit coupling V D and an Anderson-like, on-site disorder energy strength W. Numerical results are obtained within a spin dependent Landauer-Buettiker formalism

  13. On the conductivity of a one-dimensional system of interacting fermions in a random potential

    International Nuclear Information System (INIS)

    Apel, W.

    1981-01-01

    A one-dimensional system of interacting fermions in an external potential is studied. The problem was for this purpose transformed to two classical models of statistical mechanics in two dimensions in which occasionally results were found in complementary ranges of the interaction constants of the fermion system. The conductivity appeared as a simple correlation function in both classical models. It was shown that the interaction in a one-dimensional polluted fermion system can cause an isolator-metal transition. (orig./HSI) [de

  14. Pseudo-Random Sequences Generated by a Class of One-Dimensional Smooth Map

    Science.gov (United States)

    Wang, Xing-Yuan; Qin, Xue; Xie, Yi-Xin

    2011-08-01

    We extend a class of a one-dimensional smooth map. We make sure that for each desired interval of the parameter the map's Lyapunov exponent is positive. Then we propose a novel parameter perturbation method based on the good property of the extended one-dimensional smooth map. We perturb the parameter r in each iteration by the real number xi generated by the iteration. The auto-correlation function and NIST statistical test suite are taken to illustrate the method's randomness finally. We provide an application of this method in image encryption. Experiments show that the pseudo-random sequences are suitable for this application.

  15. Pseudo-Random Sequences Generated by a Class of One-Dimensional Smooth Map

    International Nuclear Information System (INIS)

    Wang Xing-Yuan; Qin Xue; Xie Yi-Xin

    2011-01-01

    We extend a class of a one-dimensional smooth map. We make sure that for each desired interval of the parameter the map's Lyapunov exponent is positive. Then we propose a novel parameter perturbation method based on the good property of the extended one-dimensional smooth map. We perturb the parameter r in each iteration by the real number x i generated by the iteration. The auto-correlation function and NIST statistical test suite are taken to illustrate the method's randomness finally. We provide an application of this method in image encryption. Experiments show that the pseudo-random sequences are suitable for this application. (general)

  16. Generalized space-charge limited current and virtual cathode behaviors in one-dimensional drift space

    International Nuclear Information System (INIS)

    Yang, Zhanfeng; Liu, Guozhi; Shao, Hao; Chen, Changhua; Sun, Jun

    2013-01-01

    This paper reports the space-charge limited current (SLC) and virtual cathode behaviors in one-dimensional grounded drift space. A simple general analytical solution and an approximate solution for the planar diode are given. Through a semi-analytical method, a general solution for SLC in one-dimensional drift space is obtained. The behaviors of virtual cathode in the drift space, including dominant frequency, electron transit time, position, and transmitted current, are yielded analytically. The relationship between the frequency of the virtual cathode oscillation and the injected current presented may explain previously reported numerical works. Results are significant in facilitating estimations and further analytical studies

  17. Metal-insulator transition in one-dimensional lattices with chaotic energy sequences

    International Nuclear Information System (INIS)

    Pinto, R.A.; Rodriguez, M.; Gonzalez, J.A.; Medina, E.

    2005-01-01

    We study electronic transport through a one-dimensional array of sites by using a tight binding Hamiltonian, whose site-energies are drawn from a chaotic sequence. The correlation degree between these energies is controlled by a parameter regulating the dynamic Lyapunov exponent measuring the degree of chaos. We observe the effect of chaotic sequences on the localization length, conductance, conductance distribution and wave function, finding evidence of a metal-insulator transition (MIT) at a critical degree of chaos. The one-dimensional metallic phase is characterized by a Gaussian conductance distribution and exhibits a peculiar non-selfaveraging

  18. On the effect of memory in one-dimensional K=4 automata on networks

    Science.gov (United States)

    Alonso-Sanz, Ramón; Cárdenas, Juan Pablo

    2008-12-01

    The effect of implementing memory in cells of one-dimensional CA, and on nodes of various types of automata on networks with increasing degrees of random rewiring is studied in this article, paying particular attention to the case of four inputs. As a rule, memory induces a moderation in the rate of changing nodes and in the damage spreading, albeit in the latter case memory turns out to be ineffective in the control of the damage as the wiring network moves away from the ordered structure that features proper one-dimensional CA. This article complements the previous work done in the two-dimensional context.

  19. Hopping transport and electrical conductivity in one-dimensional systems with off-diagonal disorder

    International Nuclear Information System (INIS)

    Ma Songshan; Xu Hui; Li Yanfeng; Song Zhaoquan

    2007-01-01

    In this paper, we present a model to describe hopping transport and electrical conductivity of one-dimensional systems with off-diagonal disorder, in which electrons are transported via hopping between localized states. We find that off-diagonal disorder leads to delocalization and drastically enhances the electrical conductivity of systems. The model also quantitatively explains the temperature and electrical field dependence of the conductivity in one-dimensional systems with off-diagonal disorder. In addition, we also show the dependence of the conductivity on the strength of off-diagonal disorder

  20. Metal-insulator transition in one-dimensional lattices with chaotic energy sequences

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, R.A. [Laboratorio de Fisica Estadistica, Centro de Fisica, Instituto Venezolano de Investigaciones Cientificas, Apartado 21827, Caracas 1020-A (Venezuela)]. E-mail: ripinto@ivic.ve; Rodriguez, M. [Laboratorio de Fisica Estadistica, Centro de Fisica, Instituto Venezolano de Investigaciones Cientificas, Apartado 21827, Caracas 1020-A (Venezuela); Gonzalez, J.A. [Laboratorio de Fisica Computacional, Centro de Fisica, Instituto Venezolano de Investigaciones Cientificas, Apartado 21827, Caracas 1020-A (Venezuela); Medina, E. [Laboratorio de Fisica Estadistica, Centro de Fisica, Instituto Venezolano de Investigaciones Cientificas, Apartado 21827, Caracas 1020-A (Venezuela)

    2005-06-20

    We study electronic transport through a one-dimensional array of sites by using a tight binding Hamiltonian, whose site-energies are drawn from a chaotic sequence. The correlation degree between these energies is controlled by a parameter regulating the dynamic Lyapunov exponent measuring the degree of chaos. We observe the effect of chaotic sequences on the localization length, conductance, conductance distribution and wave function, finding evidence of a metal-insulator transition (MIT) at a critical degree of chaos. The one-dimensional metallic phase is characterized by a Gaussian conductance distribution and exhibits a peculiar non-selfaveraging.

  1. An Auxiliary Equation for the Bellman Equation in a One-Dimensional Ergodic Control

    International Nuclear Information System (INIS)

    Fujita, Y.

    2001-01-01

    In this paper we consider the Bellman equation in a one-dimensional ergodic control. Our aim is to show the existence and the uniqueness of its solution under general assumptions. For this purpose we introduce an auxiliary equation whose solution gives the invariant measure of the diffusion corresponding to an optimal control. Using this solution, we construct a solution to the Bellman equation. Our method of using this auxiliary equation has two advantages in the one-dimensional case. First, we can solve the Bellman equation under general assumptions. Second, this auxiliary equation gives an optimal Markov control explicitly in many examples

  2. Strictly local one-dimensional topological quantum error correction with symmetry-constrained cellular automata

    Directory of Open Access Journals (Sweden)

    Nicolai Lang, Hans Peter Büchler

    2018-01-01

    Full Text Available Active quantum error correction on topological codes is one of the most promising routes to long-term qubit storage. In view of future applications, the scalability of the used decoding algorithms in physical implementations is crucial. In this work, we focus on the one-dimensional Majorana chain and construct a strictly local decoder based on a self-dual cellular automaton. We study numerically and analytically its performance and exploit these results to contrive a scalable decoder with exponentially growing decoherence times in the presence of noise. Our results pave the way for scalable and modular designs of actively corrected one-dimensional topological quantum memories.

  3. Quasi-exact solvability of the one-dimensional Holstein model

    International Nuclear Information System (INIS)

    Pan Feng; Dai Lianrong; Draayer, J P

    2006-01-01

    The one-dimensional Holstein model of spinless fermions interacting with dispersionless phonons is solved by using a Bethe ansatz in analogue to that for the one-dimensional spinless Fermi-Hubbard model. Excitation energies and the corresponding wavefunctions of the model are determined by a set of partial differential equations. It is shown that the model is, at least, quasi-exactly solvable for the two-site case, when the phonon frequency, the electron-phonon coupling strength and the hopping integral satisfy certain relations. As examples, some quasi-exact solutions of the model for the two-site case are derived. (letter to the editor)

  4. Wave packet fractional revivals in a one-dimensional Rydberg atom

    International Nuclear Information System (INIS)

    Veilande, Rita; Bersons, Imants

    2007-01-01

    We investigate many characteristic features of revival and fractional revival phenomena via derived analytic expressions for an autocorrelation function of a one-dimensional Rydberg atom with weighting probabilities modelled by a Gaussian or a Lorentzian distribution. The fractional revival phenomenon in the ionization probabilities of a one-dimensional Rydberg atom irradiated by two short half-cycle pulses is also studied. When many states are involved in the formation of the wave packet, the revival is lower and broader than the initial wave packet and the fractional revivals overlap and disappear with time

  5. Accurate correlation energies in one-dimensional systems from small system-adapted basis functions

    Science.gov (United States)

    Baker, Thomas E.; Burke, Kieron; White, Steven R.

    2018-02-01

    We propose a general method for constructing system-dependent basis functions for correlated quantum calculations. Our construction combines features from several traditional approaches: plane waves, localized basis functions, and wavelets. In a one-dimensional mimic of Coulomb systems, it requires only 2-3 basis functions per electron to achieve high accuracy, and reproduces the natural orbitals. We illustrate its effectiveness for molecular energy curves and chains of many one-dimensional atoms. We discuss the promise and challenges for realistic quantum chemical calculations.

  6. Quantum quenches to the attractive one-dimensional Bose gas: exact results

    Directory of Open Access Journals (Sweden)

    Lorenzo Piroli, Pasquale Calabrese, Fabian H. L. Essler

    2016-09-01

    Full Text Available We study quantum quenches to the one-dimensional Bose gas with attractive interactions in the case when the initial state is an ideal one-dimensional Bose condensate. We focus on properties of the stationary state reached at late times after the quench. This displays a finite density of multi-particle bound states, whose rapidity distribution is determined exactly by means of the quench action method. We discuss the relevance of the multi-particle bound states for the physical properties of the system, computing in particular the stationary value of the local pair correlation function $g_2$.

  7. Synthesis and self-assembly of complex hollow materials

    KAUST Repository

    Zeng, Hua Chun

    2011-01-01

    Hollow materials with interiors or voids and pores are a class of lightweight nanostructured matters that promise many future technological applications, and they have received significant research attention in recent years. On the basis of well-known physicochemical phenomena and principles, for example, several solution-based protocols have been developed for the general preparation of these complex materials under mild reaction conditions. This article is thus a short introductory review on the synthetic aspects of this field of development. The synthetic methodologies can be broadly divided into three major categories: (i) template-assisted synthesis, (ii) self-assembly with primary building blocks, and (iii) induced matter relocations. In most cases, both synthesis and self-assembly are involved in the above processes. Further combinations of these methodologies appear to be very important, as they will allow one to prepare functional materials at a higher level of complexity and precision. The synthetic strategies are introduced through some simple case studies with schematic illustrations. Salient features of the methods developed have been summarized, and some urgent issues of this field have also been indicated. © 2011 The Royal Society of Chemistry.

  8. Synthesis of microporous material faujasite-type from kaolin waste

    International Nuclear Information System (INIS)

    Hildebrando, E.A.; Valenzuela-Diaz, F.R.; Angelica, R.S.; Neves, R.F.

    2010-01-01

    Zeolite with structure faujasite was synthesized using kaolin waste from kaolin processing industries for paper coating as predominant source of silicon and aluminum; the starting material was characterized by XRF, XRD, DTA/TG, SEM, and products obtained by XRD and SEM. Synthesis in hydrothermal conditions occurred on autoclave and time-temperature effects, as well as the relationship Si/Al were considered. The results show that the methodology developed with the waste of calcined kaolin reacting at 90 deg C for 20 hours in an alkaline medium, in the presence of an additional source of silica was obtained zeolite Y as single phase present in the product. (author)

  9. Nanocrystalline functional materials and nanocomposites synthesis through aerosol routes

    Directory of Open Access Journals (Sweden)

    Milošević Olivera B.

    2003-01-01

    Full Text Available This paper represents the results of the design of functional nanocrystalline powders and nanocomposites using chemical reactions in aerosols. The process involves ultrasonic aerosol formation (mist generators with the resonant frequencies of 800 kHz, 1.7 and 2.5 MHz from precursor salt solutions and control over the aerosol decomposition in a high-temperature tubular flow reactor. During decomposition, the aerosol droplets undergo evaporation/drying, precipitation and thermolysis in a single-step process. Consequently, spherical, solid, agglomerate-free submicronic particles are obtained. The particle morphology, revealed as a composite structure consisting of primary crystallites smaller than 20 nm was analysed by several methods (XRD, DSC/DTA, SEM, TEM and discussed in terms of precursor chemistry and process parameters. Following the initial attempts, a more detailed aspect of nanocrystalline particle synthesis was demonstrated for the case of nanocomposites based on ZnO-MeO (MeO=Bi Cr+, suitable for electronic applications, as well as an yttrium-aluminum base complex system, suitable for phosphorus applications. The results imply that parts of the material structure responsible for different functional behaviour appear through in situ aerosol synthesis by processes of intraparticle agglomeration, reaction and sintering in the last synthesis stage.

  10. Exchange correlation effects on plasmons and on charge-density wave instability in narrow-band quasi-one-dimensional metals

    International Nuclear Information System (INIS)

    Nobile, A.; Tosatti, E.

    1979-05-01

    The coexistence of tight-binding and exchange-correlation effects inside each chain of a model quasi-one-dimensional metal, on both plasmon and charge density wave properties have been studied. The results, while in qualitative agreement with other treatments of the problem at long wavelengths, indicate a strong tendency for plasmons to turn into excitons at larger momenta, and to exhibit an ''excitonic'' charge-density wave instability at k approximately 2ksub(F). The nature of the plasmon branches and of the excitonic charge distortion is examined. Relevance to existing quasi-one-dimensional materials is also discussed. (author)

  11. An interpolatory ansatz captures the physics of one-dimensional confined Fermi systems

    DEFF Research Database (Denmark)

    Andersen, Molte Emil Strange; Salami Dehkharghani, Amin; Volosniev, A. G.

    2016-01-01

    beyond the Bethe ansatz and bosonisation allow us to predict the behaviour of one-dimensional confined systems with strong short-range interactions, and new experiments with cold atomic Fermi gases have already confirmed these theories. Here we demonstrate that a simple linear combination of the strongly...

  12. Polaritonic normal-mode splitting and light localization in a one-dimensional nanoguide

    NARCIS (Netherlands)

    Haakh, Harald R.; Faez, Sanli; Sandoghdar, Vahid

    2016-01-01

    We theoretically investigate the interaction of light and a collection of emitters in a subwavelength one-dimensional medium (nanoguide), where enhanced emitter-photon coupling leads to efficient multiple scattering of photons. We show that the spectrum of the transmitted light undergoes normal-mode

  13. Semi-analytical Study of a One-dimensional Contaminant Flow in a ...

    African Journals Online (AJOL)

    ADOWIE PERE

    ABSTRACT: The Bubnov-Galerkin weighted residual method was used to solve a one- dimensional contaminant flow problem in this paper. The governing equation of the contaminant flow, which is characterized by advection, dispersion and adsorption was discretized and solved to obtain the semi-analytical solution.

  14. Simple One-Dimensional Quantum-Mechanical Model for a Particle Attached to a Surface

    Science.gov (United States)

    Fernandez, Francisco M.

    2010-01-01

    We present a simple one-dimensional quantum-mechanical model for a particle attached to a surface. It leads to the Schrodinger equation for a harmonic oscillator bounded on one side that we solve in terms of Weber functions and discuss the behaviour of the eigenvalues and eigenfunctions. We derive the virial theorem and other exact relationships…

  15. One-dimensional metallic edge states in MoS2

    DEFF Research Database (Denmark)

    Bollinger, Mikkel; Lauritsen, J.V.; Jacobsen, Karsten Wedel

    2001-01-01

    By the use of density functional calculations it is shown that the edges of a two-dimensional slab of insulating MoS2 exhibit several metallic states. These edge states can be viewed as one-dimensional conducting wires, and we show that they can be observed directly using scanning tunneling...

  16. A computationally exact method of Dawson's model for hole dynamics of one-dimensional plasma

    International Nuclear Information System (INIS)

    Kitahara, Kazuo; Tanno, Kohki; Takada, Toshio; Hatori, Tadatsugu; Urata, Kazuhiro; Irie, Haruyuki; Nambu, Mitsuhiro; Saeki, Kohichi.

    1990-01-01

    We show a simple but computationally exact solution of the one-dimensional plasma model, so-called 'Dawson's model'. Using this solution, we can describe the evolution of the plasma and find the relative stabilization of a big hole after the instability of two streams. (author)

  17. Well-posedness for one-dimensional anisotropic Cahn-Hilliard and Allen-Cahn systems

    Directory of Open Access Journals (Sweden)

    Ahmad Makki

    2015-01-01

    Full Text Available Our aim is to prove the existence and uniqueness of solutions for one-dimensional Cahn-Hilliard and Allen-Cahn type equations based on a modification of the Ginzburg-Landau free energy proposed in [8]. In particular, the free energy contains an additional term called Willmore regularization and takes into account strong anisotropy effects.

  18. The exact solution to the one-dimensional Poisson–Boltzmann equation with asymmetric boundary conditions

    DEFF Research Database (Denmark)

    Johannessen, Kim

    2014-01-01

    The exact solution to the one-dimensional Poisson–Boltzmann equation with asymmetric boundary conditions can be expressed in terms of the Jacobi elliptic functions. The boundary conditions determine the modulus of the Jacobi elliptic functions. The boundary conditions can not be solved analytically...

  19. PAD: a one-dimensional, coupled neutronic-thermodynamic-hydrodynamic computer code

    International Nuclear Information System (INIS)

    Peterson, D.M.; Stratton, W.R.; McLaughlin, T.P.

    1976-12-01

    Theoretical and numerical foundations, utilization guide, sample problems, and program listing and glossary are given for the PAD computer code which describes dynamic systems with interactive neutronics, thermodynamics, and hydrodynamics in one-dimensional spherical, cylindrical, and planar geometries. The code has been applied to prompt critical excursions in various fissioning systems (solution, metal, LMFBR, etc.) as well as to nonfissioning systems

  20. Critical exponents in the transition to chaos in one-dimensional

    Indian Academy of Sciences (India)

    We report the numerically evaluated critical exponents associated with the scaling of generalized fractal dimensions during the transition from order to chaos. The analysis is carried out in detail in the context of unimodal and bimodal maps representing typical one-dimensional discrete dynamical systems. The behavior of ...

  1. A Simple Proof of the Theorem Concerning Optimality in a One-Dimensional Ergodic Control Problem

    International Nuclear Information System (INIS)

    Fujita, Y.

    2000-01-01

    We give a simple proof of the theorem concerning optimality in a one-dimensional ergodic control problem. We characterize the optimal control in the class of all Markov controls. Our proof is probabilistic and does not need to solve the corresponding Bellman equation. This simplifies the proof

  2. Surface characterization and surface electronic structure of organic quasi-one-dimensional charge transfer salts

    DEFF Research Database (Denmark)

    Sing, M.; Schwingenschlögl, U.; Claessen, R.

    2003-01-01

    We have thoroughly characterized the surfaces of the organic charge-transfer salts TTF-TCNQ and (TMTSF)(2)PF6 which are generally acknowledged as prototypical examples of one-dimensional conductors. In particular x-ray-induced photoemission spectroscopy turns out to be a valuable nondestructive...

  3. Theory of coherent time-dependent transport in one-dimensional multiband semiconductor super-lattices

    DEFF Research Database (Denmark)

    Rotvig, J.; Smith, H.; Jauho, Antti-Pekka

    1996-01-01

    We present an analytical study of one-dimensional semiconductor superlattices in external electric fields, which may be time dependent. A number of general results for the (quasi)energies and eigenstates are derived. An equation of motion for the density matrix is obtained for a two-band model...

  4. A one-dimensional heat transfer model for parallel-plate thermoacoustic heat exchangers

    NARCIS (Netherlands)

    de Jong, Anne; Wijnant, Ysbrand H.; de Boer, Andries

    2014-01-01

    A one-dimensional (1D) laminar oscillating flow heat transfer model is derived and applied to parallel-plate thermoacoustic heat exchangers. The model can be used to estimate the heat transfer from the solid wall to the acoustic medium, which is required for the heat input/output of thermoacoustic

  5. One-dimensional magnetohydrodynamic calculations of a hydrogen-gas puff

    International Nuclear Information System (INIS)

    Maxon, S.; Nielsen, P.D.

    1981-01-01

    A one-dimensional Lagrangian calculation of the implosion of a hydrogen gas puff is presented. At maximum compression, 60% of the mass is located in a density spike .5 mm off the axis with a half width of 40 μm. The temperature on axis reaches 200 eV

  6. Peierls instability and superconductivity in substitutionally disordered pseudo one-dimensional conductors

    International Nuclear Information System (INIS)

    Zhang, L.

    1981-08-01

    With coherent potential approximation method the effect of the substitutional disorder in the pseudo one-dimensional conductors on the Peierls transition temperature (Tsub(p)) and superconductive transition temperature (Tsub(c)) has been calculated. The favourable condition for searching for somewhat high Tsub(c) superconductors in these systems has been discussed. (author)

  7. Theory of superfluidity and drag force in the one-dimensional Bose gas

    NARCIS (Netherlands)

    Cherny, A.Y.; Caux, J.-S.; Brand, J.

    2012-01-01

    The one-dimensional Bose gas is an unusual superfluid. In contrast to higher spatial dimensions, the existence of non-classical rotational inertia is not directly linked to the dissipationless motion of infinitesimal impurities. Recently, experimental tests with ultracold atoms have begun and

  8. Spectroscopy of photonic band gaps in mesoporous one-dimensional photonic crystals based on aluminum oxide

    International Nuclear Information System (INIS)

    Gorelik, V.S.; Voinov, Yu.P.; Shchavlev, V.V.; Bi, Dongxue; Shang, Guo Liang; Fei, Guang Tao

    2017-01-01

    Mesoporous one-dimensional photonic crystals based on aluminum oxide have been synthesized by electrochemical etching method. Reflection spectra of the obtained mesoporous samples in a wide spectral range that covers several band gaps are presented. Microscopic parameters of photonic crystals are calculated and corresponding reflection spectra for the first six band gaps are presented.

  9. A novel one-dimensional chain built of vanadyl ions and pyrazine-2,5-dicarboxylate

    NARCIS (Netherlands)

    Lankelma, M.; de Boer, J.; Ferbinteanu, M.; Dantas Ramos, A.L.; Tanasa, R.; Rothenberg, G.; Tanase, S.

    2015-01-01

    We present a new coordination polymer, {[VO(pzdc)(H2O)(2)] H2O}(n), built from vanadyl and pyrazine-2,5-dicarboxylate (pzdc) ions. It consists of a one-dimensional chain of vanadyl ions linked by pzdc ions. The carboxylate groups show monodentate coordination, while the pyrazine ring is present both

  10. Derivation of Ginzburg-Landau theory for a one-dimensional system with contact interaction

    DEFF Research Database (Denmark)

    Frank, Rupert; Hanizl, Christian; Seiringer, Robert

    2013-01-01

    In a recent paper we give the first rigorous derivation of the celebrated Ginzburg-Landau (GL) theory, starting from the microscopic Bardeen-Cooper-Schrieffer (BCS) model. Here we present our results in the simplified case of a one-dimensional system of particles interacting via a delta-potential....

  11. An inverse problem for a one-dimensional time-fractional diffusion problem

    KAUST Repository

    Jin, Bangti; Rundell, William

    2012-01-01

    We study an inverse problem of recovering a spatially varying potential term in a one-dimensional time-fractional diffusion equation from the flux measurements taken at a single fixed time corresponding to a given set of input sources. The unique

  12. Stimulated wave of polarization in a one-dimensional Ising chain

    International Nuclear Information System (INIS)

    Lee, Jae-Seung; Khitrin, A.K.

    2005-01-01

    It is demonstrated that in a one-dimensional Ising chain with nearest-neighbor interactions, irradiated by a weak resonant transverse field, a stimulated wave of flipped spins can be triggered by a flip of a single spin. This analytically solvable model illustrates mechanisms of quantum amplification and quantum measurement

  13. ANAUSN - a one-dimensional multigroup SN transport theory module for the AUS reactor neutronics system

    International Nuclear Information System (INIS)

    Clancy, B.E.

    1982-05-01

    ANAUSN is a general purpose, one-dimensional discrete ordinate transport theory program which has access to AUS datapools. Fixed source, reactivity and a variety of criticality search calculations can be performed. The program can be operated as a module in the AUS scheme or as a stand-alone program

  14. Regularized integrable version of the one-dimensional quantum sine-Gordon model

    International Nuclear Information System (INIS)

    Japaridze, G.I.; Nersesyan, A.A.; Wiegmann, P.B.

    1983-01-01

    The authors derive a regularized exactly solvable version of the one-dimensional quantum sine-Gordon model proceeding from the exact solution of the U(1)-symmetric Thirring model. The ground state and the excitation spectrum are obtained in the region ν 2 < 8π. (Auth.)

  15. Observation of Zero-Dimensional States in a One-Dimensional Electron Interferometer

    NARCIS (Netherlands)

    Wees, B.J. van; Kouwenhoven, L.P.; Harmans, C.J.P.M.; Williamson, J.G.; Timmering, C.E.; Broekaart, M.E.I.; Foxon, C.T.; Harris, J.J.

    1989-01-01

    We have studied the electron transport in a one-dimensional electron interferometer. It consists of a disk-shaped two-dimensional electron gas, to which quantum point contacts are attached. Discrete zero-dimensional states are formed due to constructive interference of electron waves traveling along

  16. Effects of interaction imbalance in a strongly repulsive one-dimensional Bose gas

    DEFF Research Database (Denmark)

    Barfknecht, Rafael Emilio; Zinner, Nikolaj Thomas; Foerster, Angela

    2018-01-01

    We calculate the spatial distributions and the dynamics of a few-body two-component strongly interacting Bose gas confined to an effectively one-dimensional trapping potential. We describe the densities for each component in the trap for different interaction and population imbalances. We calculate...

  17. Suggested Courseware for the Non-Calculus Physics Student: Measurement, Vectors, and One-Dimensional Motion.

    Science.gov (United States)

    Mahoney, Joyce; And Others

    1988-01-01

    Evaluates 16 commercially available courseware packages covering topics for introductory physics. Discusses the price, sub-topics, program type, interaction, time, calculus required, graphics, and comments of each program. Recommends two packages in measurement and vectors, and one-dimensional motion respectively. (YP)

  18. Friedel oscillations in one-dimensional metals: From Luttinger's theorem to the Luttinger liquid

    International Nuclear Information System (INIS)

    Vieira, Daniel; Freire, Henrique J.P.; Campo, V.L.; Capelle, K.

    2008-01-01

    Charge density and magnetization density profiles of one-dimensional metals are investigated by two complementary many-body methods: numerically exact (Lanczos) diagonalization, and the Bethe-Ansatz local-density approximation with and without a simple self-interaction correction. Depending on the magnetization of the system, local approximations reproduce different Fourier components of the exact Friedel oscillations

  19. One-dimensional simulation of a stirling three-stage pulse-tube refrigerator

    NARCIS (Netherlands)

    Etaati, M.A.; Mattheij, R.M.M.; Tijsseling, A.S.; Waele, de A.T.A.M.

    2009-01-01

    A one-dimensional mathematical model is derived for a three-stage pulse-tube refrigerator (PTR) that is based on the conservation laws and the ideal gas law. The three-stage PTR is regarded as three separate single-stage PTRs that are coupled via proper junction conditions. At the junctions there

  20. One-dimensional simulation of a Stirling three-stage pulse-tube refrigerator

    NARCIS (Netherlands)

    Etaati, M.A.; Mattheij, R.M.M.; Tijsseling, A.S.; Waele, de A.T.A.M.

    2009-01-01

    A one-dimensional mathematical model is derived for a three-stage pulse-tube refrigerator (PTR) that is based on the conservation laws and the ideal gas law. The three-stage PTR is regarded as three separate single-stage PTRs that are coupled via proper junction conditions. At the junctions there