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Sample records for oli binary blends

  1. Hyperbolic tangent variational approximation for interfacial profiles of binary polymer blends

    International Nuclear Information System (INIS)

    Lifschitz, M.; Freed, K.F.; Tang, H.

    1995-01-01

    Contemporary theories of binary polymer blend interfaces incorporate such features of real polymer blends as compressibility, local correlations, monomer structure, etc. However, these theories require complicated numerical schemes, and their solutions often cannot be interpreted in a physically clear fashion. We develop a variational formalism for computing interfacial properties of binary polymer blends based on a hyperbolic tangent representation for the interfaces. While such an analysis is straightforward in the incompressible limit, the extension to compressible binary blends requires two distinct width parameters and nontrivial analysis. When the profile width parameters are chosen to minimize the excess free energy of a phase separated binary blend, then the interfacial properties computed from our simplified interfacial theory closely match those computed with the much more sophisticated (and computationally intensive) treatments. Significant attention is devoted to describing the interfacial properties of blends in the regime intermediate between the strong and the weak segregation limits as well as to extrapolating between these limits. The extension of the square gradient theory to the Tang--Freed quartic approximation provides a more precise definition of the weak segregation limit, but the treatment is found to overestimate both the interfacial tension and width in the strong segregation limit. The width parameters for the different components of a strongly asymmetric compressible blend vary to a lesser extent than an asymptotic analysis in the bulk suggests. This finding indicates that the central portion of the profile contributes the most in the minimization of the excess free energy with respect to the variational width parameters. copyright 1995 American Institute of Physics

  2. Thermophysical properties of binary blends of cyclohexane with some esters

    Directory of Open Access Journals (Sweden)

    Pradhan Rajendra

    2017-01-01

    Full Text Available From the densities (ρ and viscosities (η measured for three binary blends consisting of methyl acetate (MA, ethyl acetate (EA and methyl salicylate (MS over the entire composition range with cyclohexane (CH at 298.15–318.15 K under atmospheric pressure, the excess molar volumes (VEm and excess viscosities (ηE were derived. In addition, the excess isentropic compressibilities (KEs excess intermolecular free lengths (LEf and excess molar refractions (R Em were derived from measured ultrasonic speeds of sound (u and refractive indices (nD for the binary blends at 298.15 K. Various derived properties are discussed in terms of molecular interactions and structural effects. Partial molar volumes ( 0 Vm,1 and 0 Vm,2 and excess partial molar volumes ( 0,E Vm,1 and 0,E Vm,2 at infinite dilution are also discussed in terms of volume changes in the blends. Furthermore, the excess molar volumes (V Em and viscosities (η of the blends were correlated with the Prigogine–Flory–Paterson (PFP theory and the Peng–Robinson Equation of State (PR-EOS.

  3. Characterization of interfaces in Binary and Ternary Polymer Blends by Positron Lifetime Spectroscopy

    Science.gov (United States)

    Ranganathaiah, C.

    2015-06-01

    A miscible blend is a single-phase system with compact packing of the polymeric chains/segments due configuration/conformational changes upon blending. Differential Scanning Calorimetry (DSC) is the most employed method to ascertain whether the blend is miscible or immiscible. Positron Lifetime Spectroscopy (PLS) has been employed in recent times to study miscibility properties of polymer blends by monitoring the ortho-Positronium annihilation lifetimes as function of composition. However, just free volume monitoring and the DSC methods fail to provide the composition dependent miscibility of blends. To overcome this limitation, an alternative approach based on hydrodynamic interactions has been developed to derive this information using the same o-Ps lifetime measurements. This has led to the development of a new method of measuring composition dependent miscibility level in binary and ternary polymer blends. Further, the new method also provides interface characteristics for immiscible blends. The interactions between the blend components has a direct bearing on the strength of adhesion at the interface and hence the hydrodynamic interaction. Understanding the characteristic of interfaces which decides the miscibility level of the blend and their end applications is made easy by the present method. The efficacy of the present method is demonstrated for few binary and ternary blends.

  4. A Bi-Band Binary Mask Based Land-Use Change Detection Using Landsat 8 OLI Imagery

    Directory of Open Access Journals (Sweden)

    Xian Li

    2017-03-01

    Full Text Available Land use and cover change (LUCC is important for the global biogeochemical cycle and ecosystem. This paper introduced a change detection method based on a bi-band binary mask and an improved fuzzy c-means algorithm to research the LUCC. First, the bi-band binary mask approach with the core concept being the correlation coefficients between bands from different images are used to locate target areas with a likelihood of having changed areas. Second, the improved fuzzy c-means (FCM algorithm was used to execute classification on the target areas. This improved algorithm used distances to the Voronoi cell of the cluster instead of the Euclidean distance to the cluster center in the calculation of membership, and some other improvements were also used to decrease the loops and save time. Third, the post classification comparison was executed to get more accurate change information. As references, change detection using univariate band binary mask and NDVI binary mask were executed. The change detection methods were applied to Landsat 8 OLI images acquired in 2013 and 2015 to map LUCC in Chengwu, north China. The accuracy assessment was executed on classification results and change detection results. The overall accuracy of classification results of the improved FCM is 95.70% and the standard FCM is 84.40%. The average accuracy of change detection results using bi-band mask is 88.92%, using NDVI mask is 81.95%, and using univariate band binary mask is 56.01%. The result of the bi-band mask change detection shows that the change from farmland to built land is the main change type in the study area: total area is 9.03 km2. The developed method in the current study can be an effective approach to evaluate the LUCC and the results helpful for the land policy makers.

  5. Full-color tuning in binary polymer:perovskite nanocrystals organic-inorganic hybrid blends

    Science.gov (United States)

    Perulli, A.; Balena, A.; Fernandez, M.; Nedelcu, G.; Cretí, A.; Kovalenko, M. V.; Lomascolo, M.; Anni, M.

    2018-04-01

    The excellent optical and electronic properties of metal halide perovskites recently proposed these materials as interesting active materials for optoelectronic applications. In particular, the high color purity of perovskite colloidal nanocrystals (NCs) had recently motivated their exploration as active materials for light emitting diodes with tunable emission across the visible range. In this work, we investigated the emission properties of binary blends of conjugated polymers and perovskite NCs. We demonstrate that the emission color of the blends is determined by the superposition of the component photoluminescence spectra, allowing color tuning by acting on the blend relative composition. The use of two different polymers, two different perovskite NCs, and different blend compositions is exploited to tune the blend color in the blue-green, yellow-red, and blue-red ranges, including white light generation.

  6. An Investigation of Viscosities, Calorific Values and Densities of Binary Biofuel Blends

    Directory of Open Access Journals (Sweden)

    Che Mat Sharzali

    2017-01-01

    Full Text Available Straight vegetable oil (SVO biofuel is a promising alternative to petroleum diesel fuel primarily due to its comparable physical properties to that of petroleum diesel fuel. However, the relatively higher viscosity of SVO limits its direct application in diesel engine. To resolve this issue, binary biofuel blends was introduced in this study to reduce the viscosity of SVO. In this work, a novel biofuel namely Melaleuca Cajuputi oil (MCO was used and blended with refined palm oil (RPO. A total of four blends with the mixing ratios of 20%, 40%, 50% and 60% of MCO were prepared. Various key properties of dynamic viscosity, calorific value and density of the blends were measured and benchmarked against the biodiesel standards based on ASTM D6751. It was found that viscosity and density of the blends decreased with the increase of MCO fraction. Meanwhile, the calorific value of the blends increased linearly as the MCO fraction increased. The blend of 40RPO60MCO was found to have comparable key properties of viscosity, calorific value and density to those of petroleum diesel fuel and ASTM D6751 standard.

  7. Distribution of short block copolymer chains in Binary Blends of Block Copolymers Having Hydrogen Bonding

    Science.gov (United States)

    Kwak, Jongheon; Han, Sunghyun; Kim, Jin Kon

    2014-03-01

    A binary mixture of two block copolymers whose blocks are capable of forming the hydrogen bonding allows one to obtain various microdomains that could not be expected for neat block copolymer. For instance, the binary blend of symmetric polystyrene-block-poly(2-vinylpyridine) copolymer (PS-b-P2VP) and polystyrene-block-polyhydroxystyrene copolymer (PS-b-PHS) blends where the hydrogen bonding occurred between P2VP and PHS showed hexagonally packed (HEX) cylindrical and body centered cubic (BCC) spherical microdomains. To know the exact location of short block copolymer chains at the interface, we synthesized deuterated polystyrene-block-polyhydroxystyrene copolymer (dPS-b-PHS) and prepared a binary mixture with PS-b-P2VP. We investigate, via small angle X-ray scattering (SAXS) and neutron reflectivity (NR), the exact location of shorter dPS block chain near the interface of the microdomains.

  8. Effects of Electron Beam Irradiation on Binary Polyamide-6 Blends with Metallocene Copolymers

    International Nuclear Information System (INIS)

    Rosales, C.

    2006-01-01

    A versatile way to produce new materials with high Izod impact strength and reduced heat deformations is the irradiation of compatibilized blends. The effect of electron beam irradiation and different types of dispersed phase grafted copolymers on thermal and mechanical properties, and SEM morphology of polyamide-6 (PA-6) blends were investigated. Two metallocene copolymers (mEPDM and mPOE) grafted in-situ with maleic anhydride and two commercial maleated copolymers (EPDM-g-MA and mEPR-g-MA) were employed in binary blends with PA6 as matrix. The blends were prepared by extrusion with a composition of 80 wt. % of PA-6. The influence of the radical or functional groups generated in the grafting and the irradiation processes (25, 50, 100 and 200 kGy) was found by ATR-FTIR. The blends exhibited the characteristic thermal behavior of immiscible systems. All compatibilizers employed influenced the melting and crystallization behavior of the blend components without irradiation and an improvement in interface adhesion was clearly observed by SEM micrographs. The sizes of the dispersed phase in the non-irradiated reactive blends were in agreement with the viscosity ratios of the blend components. High toughness materials were obtained with ethylene-polypropylene-diene (mEPDM) grafted copolymers without significant variations in their thermal properties and Izod impact strength at room temperature and -30 degree with the irradiation doses. However, the toughness of the blends with grafted metallocene polyethylenes was affected by the irradiation doses employed. Therefore, the gel content and tensile properties of the samples depended on the chain scission, crosslinking and/or grafting reactions of the blend components

  9. Development of OLI+S Entry Decision Model for Construction Firms in International Markets

    Directory of Open Access Journals (Sweden)

    Che Maznah Binti Mat Isa

    2017-12-01

    Full Text Available The paper aims to provide a holistic approach to address how construction firms make decisions covering all three domains (location, timing and mode across country, market, firm and project factors within the Ownership, Locational and Internalisation plus Specialty (OLI+S paradigm. Questionnaires were administered to 62 project managers based on a sampling frame provided by the Construction Industry Development Board Malaysia. The findings provide empirical and theoretical insights on how the OLI+S model addresses firms’ entry decisions to penetrate international markets. It suggests that the ownership-entry decision factors focus on firms’ internal transferable advantages. The locational-entry decision factors emphasise attractiveness of certain locations where firms decided to invest and operate. The internalisation– entry decision factors emphasise the extent to which firms were able to manipulate their internal competitive assets (firm’s resources and capabilities. Finally, the specialty-entry decision factors emphasise on firms’ competency in project management and specialist expertise to handle complex projects based on their previous project experience. An example of construction firms’ unique characteristics, namely, specialty advantages based on the original Dunning’s OLI eclectic paradigm has been adopted. The established OLI+S entry decision model could be investigated to further refine other related internationalisation theory.

  10. Combined impact of branching and unsaturation on the autoignition of binary blends in a motored engine

    KAUST Repository

    Kang, Dongil

    2014-11-20

    The impact of a branched and unsaturated compound (diisobutylene) mixed with simple hydrocarbons such as n-heptane and isooctane in binary blends on the autoignition behavior were investigated in a modified cooperative fuel research (CFR) engine at an equivlanece ratio of 0.5 and intake temperature of 120 °C. From this test condition, a homogeneous charge of fuel and intake air can be achieved. The test fuels were prepared by addition of 5-20 vol % diisobutylene into n-heptane and isooctane. The engine compression ratio (CR) was gradually increased from the lowest point to the point where significant high temperature heat release (HTHR) was observed, and this point is also referred to as the critical compression ratio (CCR). Heat release analysis showed that each n-heptane blend had a noticeable low temperature heat release (LTHR), which was not observed in the isooctane blends. The gradual addition of diisobutylene into each primary reference fuel contributed to retarded high temperature heat release in these binary blends, increasing the in-cylinder temperature and decreasing formation of CO. The 15 and 20 vol % blends of diisobutylene in isooctane were not able to reach high temperature heat release in the CFR engine system under these test conditions. The fundamental ignition behavior such as CCR and calculated % LTHR show the impact of the presence of the C-C double bond on ignition reactivity. Species concentration profiles obtained in condensed products from the engine exhaust were measured via gas chromatrography-mass spectrometry and -flame ionization detector. The major intermediate species for each blend were captured at a compression ratio selected just before the high temperature heat release was observed. Most intermediate species were derived from n-heptane and isooctane, while diisobutylene rarely participated in forming any major species, with the exception of the formation of 4,4-dimethyl-2-pentanone. Addition of diisobutylene exhibited opposite

  11. Combined impact of branching and unsaturation on the autoignition of binary blends in a motored engine

    KAUST Repository

    Kang, Dongil; Kirby, Stephen R.; Agudelo, John Ramiro; Lapuerta, Magí n; Al-Qurashi, Khalid; Boehman, André Louis

    2014-01-01

    The impact of a branched and unsaturated compound (diisobutylene) mixed with simple hydrocarbons such as n-heptane and isooctane in binary blends on the autoignition behavior were investigated in a modified cooperative fuel research (CFR) engine at an equivlanece ratio of 0.5 and intake temperature of 120 °C. From this test condition, a homogeneous charge of fuel and intake air can be achieved. The test fuels were prepared by addition of 5-20 vol % diisobutylene into n-heptane and isooctane. The engine compression ratio (CR) was gradually increased from the lowest point to the point where significant high temperature heat release (HTHR) was observed, and this point is also referred to as the critical compression ratio (CCR). Heat release analysis showed that each n-heptane blend had a noticeable low temperature heat release (LTHR), which was not observed in the isooctane blends. The gradual addition of diisobutylene into each primary reference fuel contributed to retarded high temperature heat release in these binary blends, increasing the in-cylinder temperature and decreasing formation of CO. The 15 and 20 vol % blends of diisobutylene in isooctane were not able to reach high temperature heat release in the CFR engine system under these test conditions. The fundamental ignition behavior such as CCR and calculated % LTHR show the impact of the presence of the C-C double bond on ignition reactivity. Species concentration profiles obtained in condensed products from the engine exhaust were measured via gas chromatrography-mass spectrometry and -flame ionization detector. The major intermediate species for each blend were captured at a compression ratio selected just before the high temperature heat release was observed. Most intermediate species were derived from n-heptane and isooctane, while diisobutylene rarely participated in forming any major species, with the exception of the formation of 4,4-dimethyl-2-pentanone. Addition of diisobutylene exhibited opposite

  12. Complex Macrophase-Separated Nanostructure Induced by Microphase Separation in Binary Blends of Lamellar Diblock Copolymer Thin Films

    DEFF Research Database (Denmark)

    Zhang, Jianqi; Posselt, Dorthe; Smilgies, Detlef-M.

    2014-01-01

    The nanostructures of thin films spin-coated from binary blends of compositionally symmetric polystyrene-b-polybutadiene (PS-b-PB) diblock copolymer having different molar masses are investigated by means of atomic force microscopy (AFM) and grazing-incidence small-angle X-ray scattering (GISAXS)...

  13. Morphology development in immiscible polymer blends

    NARCIS (Netherlands)

    Cardinaels, R.M.; Moldenaers, P.; Guo, Qipeng

    This chapter discusses the morphology development of immiscible binary polymer blends. It first describes morphology development in droplet-matrix structures, the dynamics of fibrillar structures and cocontinuous structures. The chapter then considers binary immiscible polymer blends, such systems

  14. Binary blend Nanoparticles with defined morphology

    International Nuclear Information System (INIS)

    Ghazy, O.A.H.

    2008-01-01

    The word blend in linguistics means a word formed from two parts of two words. In polymer science polymer blends means polymer mixtures, a class of materials analogues to the metal alloys. Blending of polymers is a simple and economic way to create new materials meeting specific desired properties. The other alternative is to synthesize such materials eventually facing the organic chemistry design difficulties. The low entropy of mixing polymers makes the process thermodynamically unfavorable, unless there are some specific interactions between the mixed polymers. As a result, in thermal equilibrium typically a phase separation between the blend components takes place. The main challenge facing the blending of polymers is the control of the length scale of the phase separation. One of the most important applications, where the control of the phase separation is crucial for the performance is the organic solar cells. In organic solar cells a blend of an electron donating polymer and electron accepting one is formed. The dimensions of the phase separation between the two polymers should be in the range of the exciton diffusion length [1-3] (in semiconductors, exciton diffusion length is the average distance traveled by the electron-hole pair before recombination). Only under this condition the charge transfer at the interface between the two polymer layers can take place and the solar cell performs efficiently. The thin polymer blend layers for such applications are commonly deposited by spin coating from solution containing both polymers. The morphology of the thin layer prepared in this way is highly influenced by the preparation conditions such as the surface properties of the substrate, the solvent from which the blend was deposited, the temperature, and the annealing temperature [4-9]. Therefore controlling the length scale of phase separation in layers casted or spin coated from solutions is difficult and is a matter of trials and errors. Recently a novel

  15. Study of flame combustion of off-design binary coal blends in steam boilers

    Science.gov (United States)

    Kapustyanskii, A. A.

    2017-07-01

    Changes in the structure of the fuel consumption by the thermal power stations of Ukraine caused by failure in supplying anthracite from the Donets Basin are analyzed and the major tasks of maintaining the functioning of the coal industry are formulated. The possibility of using, in the near future, the flame combustion of off-design solid fuels in the power boilers of the thermal power plants and combined heat and power plants is studied. The article presents results of expert tests of the TPP-210A and TP-15 boilers under flame combustion of mixtures of anthracites, lean coal, and the coal from the RSA in various combinations. When combusting, such mixtures have higher values of the combustibles yield and the ash fusibility temperature. The existence of the synergetic effect in the flame combustion of binary coal blends with different degrees of metamorphism is discussed. A number of top-priority measures have been worked out that allow for switching over the boilers designed to be fired with anthracite to using blends of coals of different ranks. Zoned thermal analysis of the TP-15 boiler furnace was performed for numerical investigation of the temperature distribution between the furnace chamber zones and exploration of the possibility of the liquid slag disposal and the temperature conditions for realization of this process. A positive result was achieved by combusting anthracite culm (AC), the coal from the RSA, and their mixtures with lean coal within the entire range of the working loads of the boilers in question. The problems of normalization of the liquid slag flow were also successfully solved without closing the slag notch. The results obtained by balance experiments suggest that the characteristics of the flame combustion of a binary blend, i.e., the temperature conditions in the furnace, the support flame values, and the degree of the fuel burnout, are similar to the characteristics of the flame of the coal with a higher reactive capacity, which

  16. Phase Behavior of Binary Blends of AB+AC Block Copolymers with compatible B and C blocks

    Science.gov (United States)

    Pryamitsyn, Victor; Ganesan, Venkat

    2012-02-01

    Recently the experimental studies of phase behavior of binary blends of PS-b-P2VP and PS-b-PHS demonstrated an interesting effect: blends of symmetric PS-b-P2VP and shorter symmetric (PS-b-PHS) formed cylindrical HEX and spherical BCC phases, while each pure component formed lamellas. The miscibility of P2VP and PHS is caused by the hydrogen bonding between P2VP and PHS,which can be described as a negative Flory ?-parameter between P2VP and PHS. We developed a theory of the microphase segregation of AB+AC blends of diblock copolymers based on strong stretching theory. The main result of our theory is that in the copolymer brush-like layer formed by longer B chain and shorter C chains, the attraction between B and shorter C chains causes relative stretching of short C chains and compression of longer B chains. The latter manifests in an excessive bending force towards the grafting surface (BC|AA interface). Such bending force causes a transition from a symmetric lamella phase to a HEX cylinder or BCC spherical phases with the BC phase being a ``matrix'' component. In a blend of asymmetric BCC sphere forming copolymers (where B and C segments are the minor components), such bending force may unfold BCC spherical phase to a HEX cylinder phase, or even highly uneven lamella phases.

  17. "Oli vahinko, et kaikki onnistu niin hyvin. Urheilulukio oli täydellinen urheilijan polku mulle." : hiihtäjien kokemuksia 2000-luvun urheilulukioista

    OpenAIRE

    Saarinen, Milla

    2016-01-01

    Milla Saarinen (2016). ”Oli vahinko, et kaikki onnistu niin hyvin. Urheilulukio oli täydellinen urheilijan polku mulle.” Hiihtäjien kokemuksia 2000-luvun urheilulukiosta. Pro gradu-tutkielma. Liikuntakasvatuksen laitos, liikuntapedagogiikka. Jyväskylän yliopisto, 132 s. Tutkimuksen tarkoituksena oli tutkia hiihtäjien kokemuksia urheilulukion käymisestä, siellä opiskelemisesta ja urheilemisesta. Tavoitteena oli myös selvittää, miten urheilulukioiden toi-mintaa voisi kehittää entistä parem...

  18. Binary blend of carbon dioxide and fluoro ethane as working fluid in transcritical heat pump systems

    Directory of Open Access Journals (Sweden)

    Zhang Xian-Ping

    2015-01-01

    Full Text Available As an eco-friendly working fluid, carbon dioxide or R744 is expected to substitute for the existing working fluids used in heat pump systems. It is, however, challenged by the much higher heat rejection pressure in transcritical cycle compared with the traditional subcritical cycle using freons. There exists a worldwide tendency to utilize blend refrigerants as alternatives. Therefore, a new binary blend R744/R161 in this research is proposed in order to decrease the heat rejection pressure. Meanwhile, on mixing R744 with R161, the flammability and explosivity of R161 can be suppressed because of the extinguishing effect of R744. A transcritical thermodynamic model is developed, and then the system performances of heat pump using R744/R161 blend are investigated and compared with those of pure R744 system under the same operation conditions. The variations of heat rejection pressure, heating coefficient of performance, unit volumetric heating capacity, discharge temperature of compressor and the mass fraction of R744/R161 are researched. The results show that R744/R161 mixture can reduce the heat rejection pressure of transcritical heat pump system.

  19. Preparation of PLLA/PMMA and PLLA/PS binary blend nanoparticles by incorporation of PLLA in methyl methacrylate or styrene miniemulsion homopolymerization

    Directory of Open Access Journals (Sweden)

    Luana Becker Peres

    2015-02-01

    Full Text Available Miniemulsion homopolymerization reactions of methyl methacrylate (MMA and styrene (STY using poly(L-lactide as co-stabilizer were carried out in order to prepare poly(L-lactide/poly(methyl methacrylate (PLLA/PMMA and poly(L-lactide/polystyrene (PLLA/PS binary blend nanoparticles. The effect of PLLA concentration on methyl methacrylate (MMA and styrene (STY homopolymerization reactions was evaluated. It was found that the incorporation of PLLA resulted on acceleration of MMA and STY homopolymerization reactions and led to a molar mass increase of up to 70% for PS in PLLA/PS blend nanoparticles in relation to those prepared without PLLA, which can be attributed to an increase of reaction loci viscosity (gel effect. PLLA also acted as an efficient co-stabilizer, since it was able to retard diffusional degradation of droplets when no other kind of co-stabilizer was used. Two isolated Tgs were found in both PLLA/PMMA and PLLA/PS blend nanoparticles which can be associated to blend immiscibility. TEM images corroborate these results, suggesting that immiscible PLLA/PMMA and PLLA/PS blend nanoparticles could be formed with two segregated phases and core-shell morphology.

  20. Morphological, rheological and mechanical characterization of polypropylene nanocomposite blends.

    Science.gov (United States)

    Rosales, C; Contreras, V; Matos, M; Perera, R; Villarreal, N; García-López, D; Pastor, J M

    2008-04-01

    In the present work, the effectiveness of styrene/ethylene-butylene/styrene rubbers grafted with maleic anhydride (MA) and a metallocene polyethylene (mPE) as toughening materials in binary and ternary blends with polypropylene and its nanocomposite as continuous phases was evaluated in terms of transmission electron microscopy (TEM), scanning electron microscopy (SEM), oscillatory shear flow and dynamic mechanical thermal analysis (DMA). The flexural modulus and heat distortion temperature values were determined as well. A metallocene polyethylene and a polyamide-6 were used as dispersed phases in these binary and ternary blends produced via melt blending in a corotating twin-screw extruder. Results showed that the compatibilized blends prepared without clay are tougher than those prepared with the nanocomposite of PP as the matrix phase and no significant changes in shear viscosity, melt elasticity, flexural or storage moduli and heat distortion temperature values were observed between them. However, the binary blend with a nanocomposite of PP as matrix and metallocene polyethylene phase exhibited better toughness, lower shear viscosity, flexural modulus, and heat distortion temperature values than that prepared with polyamide-6 as dispersed phase. These results are related to the degree of clay dispersion in the PP and to the type of morphology developed in the different blends.

  1. Kui suur oli "Suur Oktoober 1917" / David Vseviov

    Index Scriptorium Estoniae

    Vseviov, David, 1949-

    2009-01-01

    Kuivõrd oli Oktoobrirevolutsioon paratamatu? Vassili Šulginist, kes jagas seisukohta revolutsiooni paratamatusest. Kas Lenini saabumine pealinna Saksamaaga peetava sõja ajal vihavaenlaste plommitud vagunis oli saksa luure plaan? Oktoobrirevolutsiooni sarnasusest Prantsuse revolutsiooniga. Oktoobrirevolutsiooni vaimu kestmisest tänapäeval

  2. Laboratory Evaluation of Synthetic Blends of l-(+)-Lactic Acid, Ammonia, and Ketones As Potential Attractants For Aedes aegypti.

    Science.gov (United States)

    Venkatesh, P M; Sen, A

    2017-12-01

    Attraction of Aedes aegypti to various binary, trinary, and quaternary blends of lactic acid and ketones with or without ammonia was studied using a dual choice olfactometer. A dose dependent attraction was observed in cases of single compounds where cyclopentanone attracted the highest percentage (36.9 ± 1.8%) of Ae. aegypti when tested alone. No significant difference was observed between the attraction levels of trinary and binary blends of lactic acid and acetone or butanone when tested against clear air. However, in competitive bioassays, the trinary blend of lactic acid, acetone, and butanone was significantly preferred over binary blends of individual compounds ( P lactic acid. However, acetylacetone acted as an attraction inhibitor when blended with other compounds. Cyclopentanone was attractive, but enhancement of attraction was not observed when blended with other components. Addition of ammonia to binary or trinary blends of lactic acid, acetone, and/or butanone did not increase the attraction significantly. In competitive bioassays, the blends containing ammonia were significantly preferred over the blends lacking ammonia ( P lactic acid, ammonia, acetone, and butanone was most attractive (65 ± 1.5%) and preferred blend of all other combinations.

  3. Synchrotron SAXS studies on morphology formation in a binary blend of poly(ε-caprolactone) homopolymer and poly(ε-caprolactone)-block-polybutadiene copolymer

    International Nuclear Information System (INIS)

    Akaba, Michiaki; Nojima, Shuichi

    2005-01-01

    The process of morphology formation in a binary blend of poly(ε-caprolactone) homopolymer (PCL) and poly(ε-caprolactone)-block-polybutadiene copolymer (PCL-b-PB) has been investigated by synchrotron small-angle X-ray scattering (SR-SAXS). This blend shows an UCST-type phase separation and the crystallization of PCL chains (i.e., PCL and PCL blocks in PCL-b-PB) at a same temperature range, so that these two factors may work simultaneously to yield a complicated morphology formation. When the weight fraction of PCL (φ PCL ) is small (φ PCL PCL > 0.8), the blend can directly be quenched into crystallization temperatures without passing through the UCST region. Time-resolved SAXS curves in this case show that overall morphology formation is driven by the crystallization of PCL chains, where a crystallized PCL region always coexists with a crystallized PCL-b-PB region and the volume ratio of two regions is constant throughout. (author)

  4. Film-forming properties of castor oil polyol ester blends in elastohydrodynamic conditions

    Science.gov (United States)

    The viscosities and elastohydrodynamic (EHD) film thickness properties of binary blends of castor oil with polyol esters were determined experimentally. Predicted blend viscosity was calculated from the viscosity of the pure blend components. Measured viscosity values were closer to the values pre...

  5. Invloed van minerale olie op de bestrijding van Phytophthora infestans in pootaardappelen

    NARCIS (Netherlands)

    Spits, H.G.; Bus, C.B.

    2003-01-01

    De invloed van toevoeging van olie aan een fungicide op de werking van het fungicide is afhankelijk van het gebruikte fungicide. Gezamenlijk spuiten van olie en Aviso DF, Curzate M en mogelijk ook Acrobat, verhoogt de curatieve werking van deze fungiciden. Gezamenlijk spuiten van olie en Aviso DF,

  6. A study on the combustion behaviour of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, F.; Fuente, E.; Arenillas, A.; Pis, J.J. [Instituto Nacional del Carbon, Oviedo (Spain)

    1999-07-01

    Combustion behaviour of four coals of varying rank and their binary blends was studied using temperature programmed combustion tests, and thermogravimetric analysis. Characteristic parameters could not be predicted from the weight percentage of individual coals in the blend. 6 refs., 4 figs., 1 tab.

  7. RELATIONSHIP BETWEEN FLASH POINTS OF SOME BINARY ...

    African Journals Online (AJOL)

    B. S. Chandravanshi

    Miscellaneous binary blends containing solvent neutral-150 (SN-150), ... viscosity, the flash point test has always been a standard part of a lubricant's specification. ... between structure and flash points of organic compounds [5-12] and fuels [13, 14]. ... in binary mixtures, the gaps between flash points would be high enough.

  8. Tailoring the mechanical and biodegradable properties of binary blends of biomedical thermoplastic elastomer.

    Science.gov (United States)

    Ang, Hui Ying; Chan, Jingni; Toong, Daniel; Venkatraman, Subbu S; Chia, Sing Joo; Huang, Ying Ying

    2018-03-01

    Blending polymers with complementary properties capitalizes on the inherent advantages of both components, making it possible to tailor the behaviour of the resultant material. A polymer blend consisting of an elastomer and thermoplastic can help to improve the mechanical integrity of the system without compromising on its processibility. A series of blends of biodegradable Poly(L-lactide-co-ɛ-caprolactone) (PLC) and Poly-(l,l-lactide-co-glycolic acid) (PLLGA), and PLC with Poly-(d,l-lactide-co-glycolic acid) (PDLLGA) were evaluated as a potential material for a biodegradable vesicourethral connector device. Based on the Tg of the blends, PLC/PLLGA formed an immiscible mixture while PLC/PDLLGA resulted in a compatible blend. The results showed that with the blending of PLC, the failure mode of PLLGA and PDLLGA changed from brittle to ductile fracture, with an significant decreas in tensile modulus and strength. SEM images demonstrated the different blend morphologies of different compositions during degradation. Gel Permeation Chromatography (GPC) and mechanical characterization revealed the degradation behaviour of the blends in this order (fastest to slowest): PDLLGA and PLC/PDLLGA blends > PLLGA and PLC/PLLGA blends > PLC. The PLC/PLLGA (70:30) blend was recommended as a suitable for the vesicourethral connector device application, highlighting the tailoring of blends to achieve a desired mechanical performance. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Landsat 9 OLI 2 focal plane subsystem: design, performance, and status

    Science.gov (United States)

    Malone, Kevin J.; Schrein, Ronald J.; Bradley, M. Scott; Irwin, Ronda; Berdanier, Barry; Donley, Eric

    2017-09-01

    The Landsat 9 mission will continue the legacy of Earth remote sensing that started in 1972. The Operational Land Imager 2 (OLI 2) is one of two instruments on the Landsat 9 satellite. The OLI 2 instrument is essentially a copy of the OLI instrument flying on Landsat 8. A key element of the OLI 2 instrument is the focal plane subsystem, or FPS, which consists of the focal plane array (FPA), the focal plane electronics (FPE) box, and low-thermal conductivity cables. This paper presents design details of the OLI 2 FPS. The FPA contains 14 critically-aligned focal plane modules (FPM). Each module contains 6 visible/near-IR (VNIR) detector arrays and three short-wave infrared (SWIR) arrays. A complex multi-spectral optical filter is contained in each module. Redundant pixels for each array provide exceptional operability. Spare detector modules from OLI were recharacterized after six years of storage. Radiometric test results are presented and compared with data recorded in 2010. Thermal, optical, mechanical and structural features of the FPA will be described. Special attention is paid to the thermal design of the FPA since thermal stability is crucial to ensuring low-noise and low-drift operation of the detectors which operate at -63°C. The OLI 2 FPE provides power, timing, and control to the focal plane modules. It also digitizes the video data and formats it for the solid-state recorder. Design improvements to the FPA-FPE cables will be discussed and characterization data will be presented. The paper will conclude with the status of the flight hardware assembly and testing.

  10. Differential regulation of fatty acid biosynthesis in two Chlorella species in response to nitrate treatments and the potential of binary blending microalgae oils for biodiesel application.

    Science.gov (United States)

    Cha, Thye San; Chen, Jian Woon; Goh, Eng Giap; Aziz, Ahmad; Loh, Saw Hong

    2011-11-01

    This study was undertaken to investigate the effects of different nitrate concentrations in culture medium on oil content and fatty acid composition of Chlorella vulgaris (UMT-M1) and Chlorella sorokiniana (KS-MB2). Results showed that both species produced significant higher (pdifferentially regulated fatty acid accumulation patterns in response to nitrate treatments at early stationary growth phase. Their potential use for biodiesel application could be enhanced by exploring the concept of binary blending of the two microalgae oils using developed mathematical equations to calculate the oil mass blending ratio and simultaneously estimated the weight percentage (wt.%) of desirable fatty acid compositions. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Concentration fluctuations in miscible polymer blends: Influence of temperature and chain rigidity

    International Nuclear Information System (INIS)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-01-01

    In contrast to binary mixtures of small molecule fluids, homogeneous polymer blends exhibit relatively large concentration fluctuations that can strongly affect the transport properties of these complex fluids over wide ranges of temperatures and compositions. The spatial scale and intensity of these compositional fluctuations are studied by applying Kirkwood-Buff theory to model blends of linear semiflexible polymer chains with upper critical solution temperatures. The requisite quantities for determining the Kirkwood-Buff integrals are generated from the lattice cluster theory for the thermodynamics of the blend and from the generalization of the random phase approximation to compressible polymer mixtures. We explore how the scale and intensity of composition fluctuations in binary blends vary with the reduced temperature τ ≡ (T − T c )/T (where T c is the critical temperature) and with the asymmetry in the rigidities of the components. Knowledge of these variations is crucial for understanding the dynamics of materials fabricated from polymer blends, and evidence supporting these expectations is briefly discussed

  12. S&P: meie kohus oli USA riigireitingut alandada / Heiki Suurkask

    Index Scriptorium Estoniae

    Suurkask, Heiki, 1972-

    2011-01-01

    Standard & Poor´s langetas USA reitingut tasemelt AAA tasemeni AA+. Agentuuri esindaja sõnul oli reitingu alandamine nende kohustus, sest nende arvates oli USA senine reiting liiga kõrge. Hiina nõuab, et USA hakkaks oma võlaprobleemiga tegelema. AAA reiting on nüüd vaid 15 riigil või territooriumil maailmas

  13. Modelling of NO formation in the combustion of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    Arenillas, A.; Backreedy, R.I.; Jones, J.M.; Pis, J.J.; Pourkashanian, M.; Rubiera, F.; Williams, A. [CSIC, Instituto Nacional del Carbon, Oviedo (Spain)

    2002-03-01

    Coal blending is becoming of increasing importance in power stations firing pulverised coal as a result of increasing competition, stricter emission legislation and is an attractive way of improving plant economic and combustion performance. Presently, the two general methods used by power station operators to assess or predict the performance of an unknown coal blend to be fired in power station boilers are by the use of experimental large scale rig tests or correlation indices derived from experience of firing other coal blends in the power station environment. The first is expensive and the second is of doubtful accuracy in some cases. This paper evaluates the application of mathematical modelling of the combustion of a series of binary coal blends in the test situation of a drop tube reactor to predict the NO emissions and degree of char burnout. Its applicability to low NOx burners used in power stations is discussed and it is concluded that present mathematical coal combustion models are not developed sufficiently to enable an adequate description of the binary blends and the physical and chemical processes, which may include interactions, during combustion of the blend. This means that accurate predictions cannot be made. 20 refs., 4 figs., 5 tabs.

  14. Preparation and characterization of tragacanth-locust bean gum edible blend films.

    Science.gov (United States)

    Mostafavi, Fatemeh Sadat; Kadkhodaee, Rassoul; Emadzadeh, Bahareh; Koocheki, Arash

    2016-03-30

    The present work introduces the structure and physicomechanical properties of a novel blend film made from binary solutions of gum tragacanth (GT) and locust bean gum (LBG) at different mixing ratios. Apparent viscosities and surface tensions of individual and blend gum solutions were also investigated. The viscosity data indicated that there was a distinct synergism between the two gums at all mixing ratios. FTIR spectra showed the existence of noncovalent intermolecular interactions between gums. The surface tensions of binary solutions were significantly lower than those of individual gums which is advantageous for coating applications. All films had homogenous and smooth surface morphology and their transparency, water vapour barrier and mechanical properties were improved by incorporating LBG in blend. The results of this study suggest that GT-LBG blend film, owing to its desirable properties, has the potential to be used as a new degradable food packaging material. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Ocean Color Measurements from Landsat-8 OLI using SeaDAS

    Science.gov (United States)

    Franz, Bryan Alden; Bailey, Sean W.; Kuring, Norman; Werdell, P. Jeremy

    2014-01-01

    The Operational Land Imager (OLI) is a multi-spectral radiometer hosted on the recently launched Landsat-8 satellite. OLI includes a suite of relatively narrow spectral bands at 30-meter spatial resolution in the visible to shortwave infrared that make it a potential tool for ocean color radiometry: measurement of the reflected spectral radiance upwelling from beneath the ocean surface that carries information on the biogeochemical constituents of the upper ocean euphotic zone. To evaluate the potential of OLI to measure ocean color, processing support was implemented in SeaDAS, which is an open-source software package distributed by NASA for processing, analysis, and display of ocean remote sensing measurements from a variety of satellite-based multi-spectral radiometers. Here we describe the implementation of OLI processing capabilities within SeaDAS, including support for various methods of atmospheric correction to remove the effects of atmospheric scattering and absorption and retrieve the spectral remote-sensing reflectance (Rrs; sr exp 1). The quality of the retrieved Rrs imagery will be assessed, as will the derived water column constituents such as the concentration of the phytoplankton pigment chlorophyll a.

  16. Olie skaber fred i Sudan

    DEFF Research Database (Denmark)

    Laugesen, Henrik

    Sydsudan forventes formelt at erklære sin uafhængighed den 9. juli 2011. Men hvad sker der, når Sudan nu deles i Nordsudan og Sydsudan? Oliekilderne ligger i Sydsudan, men den helt nødvendige infrastruktur der skal transformere olie til dollars har man i nord. Da op imod 90% af Sydsudans indtægter...

  17. Blends of polyester ionomers with polar polymers: Interactions, reactions, and compatibilization

    Science.gov (United States)

    Boykin, Timothy Lamar

    The compatibility of amorphous and semicrystalline polyester ionomers with various polar polymers (i.e., polyesters and polyamides) has been investigated for their potential use as minor component compatibilizers. The degree of compatibility (i.e., ranging from incompatible to miscible) between the polyester ionomers and the polar polymers was determined by evaluating the effect of blend composition on the melting behavior and phase behavior of binary blends. In addition, the origin of compatibility and/or incompatibility for each of the binary blends (i.e., polyamide/ionomer and polyester/ionomer) was determined by evaluating blends prepared by both solution and melt mixed methods. Subsequent to investigation of the binary blends, the effect of polyester ionomer addition on the compatibility of polyamide/polyester blends was investigated by evaluating the mechanical properties and phase morphology of ionomer compatibilized polyamide/polyester blends. Polyester ionomers (amorphous and semicrystalline) were shown to exhibit a high degree of compatibility (even miscibility) with polyamides, such as nylon 6,6 (N66). Compatibility was attributed to specific interactions between the metal counterion of the polyester ionomer and the amide groups of N66. The degree of compatibility (or miscibility) was shown to be dependent on the counterion type of the ionomer, with the highest degree exhibited by blends containing the divalent form of the polyester ionomers. Although polyester ionomers were shown to exhibit incompatibility with both poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT), increasing the time of melt processing significantly enhanced the compatibility of the polyester ionomers with both PET and PBT. The observed enhancement in compatibility was attributed to ester-ester interchange between the polyester blend components, which was confirmed by NMR spectroscopy. The addition of polyester ionomers as a minor component compatibilizer (i

  18. The pseudo-binary mercury chalcogenide alloy HgSe sub 0 sub . sub 7 S sub 0 sub . sub 3 at high pressure: a mechanism for the zinc blende to cinnabar reconstructive phase transition

    CERN Document Server

    Kozlenko, D P; Ehm, L; Hull, S; Savenko, B N; Shchennikov, V V; Voronin, V I

    2003-01-01

    The structure of the pseudo-binary mercury chalcogenide alloy HgSe sub 0 sub . sub 7 S sub 0 sub . sub 3 has been studied by x-ray and neutron powder diffraction at pressures up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal cinnabar structure was observed at P approx 1 GPa. A phenomenological model of this reconstructive phase transition based on a displacement mechanism is proposed. Analysis of the geometrical relationship between the zinc blende and the cinnabar phases has shown that the possible order parameter for the zinc blende-cinnabar structural transformation is the spontaneous strain e sub 4. This assignment agrees with the previously observed high pressure behaviour of the elastic constants of some mercury chalcogenides.

  19. Theory of polymer blends

    International Nuclear Information System (INIS)

    Curro, J.G.; Schweizer, K.S.

    1989-01-01

    We have recently developed a new theoretical approach to the study of polymer liquids. The theory is based on the ''reference interaction site model'' (RISM theory) of Chandler and Andersen, which has been successful in describing the structure of small molecule liquids. We have recently extended our polymer RISM theory to the case of polymer blends. In the present investigation we have applied this theory to two special binary blends: (1) the athermal mixture where we isolate structural effects, and (2) the isotopic mixture in which structurally identical polymer chains interact with dissimilar attractive interactions. By studying these two special cases we are able to obtain insights into the molecular factors which control the miscibility in polymer mixtures. 18 refs., 2 figs

  20. Flexible and strong ternary blends of poly(vinyl chloride), poly(butylene adipate)and nanoparticle-plasticizers

    OpenAIRE

    Yin, Bo; Hakkarainen, Minna

    2013-01-01

    Multiple property enhancement was achieved for ternary blends of PVC, poly(butylene adipate) (PBA) plasticizer and PBA-grafted nanofillers as compared to ternary blends with untreated nanofillers. The blends with surface modified halloysite, kaolin or silicon dioxide nanofillers all exhibited higher stress at break and higher strain at break as compared to the corresponding composites with untreated nanoparticles. The strain at break was similar or improved compared to binary PVC/PBA blends. ...

  1. Blends of caprolactam/caprolactone copolymers and chlorinated polymers

    NARCIS (Netherlands)

    Alberda van Ekenstein, G.O.R.; Deuring, H.; ten Brinke, G.; Ellis, T.S.

    The phase behaviour of blends of chlorinated polyethylene, polyvinyl chloride (PVC) and chlorinated PVC with random copolymers of caprolactone and caprolactam has been investigated and the results correlated with a binary interaction model. The known miscibility of polycaprolactone in the

  2. Modification of combustion behaviour and NO emissions by coal blending

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, Fernando; Arenillas, Ana; Arias, Borja; Pis, Jose J. [Department of Energy and Environment, Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain)

    2002-06-20

    Combustion profiles determined by TGA and experiments in a laminar entrained flow reactor (EFR) were used in this work to assess the relative combustion reactivities of different rank coals and their binary coal blends. The combustion behaviour of coal blends in TGA was greatly influenced by coal rank and the proportion of each component in the blend. Higher volatile coals exerted more influence in the low-temperature region and less reactive coals in the char combustion zone. The results in the EFR indicated that coal blends burnout and NO emissions show additivity in the case of similar nature coals. When one of the components was a high-rank coal, the burnout of the blend exhibited, in some cases, positive synergistic effects, while a clear deviation from linearity was found in NO emissions.

  3. Positron annihilation lifetime study of interfaces in ternary polymer blends

    International Nuclear Information System (INIS)

    Meghala, D; Ramya, P; Pasang, T; Raj, J M; Ranganathaiah, C; Williams, J F

    2013-01-01

    A new method based on positron lifetime spectroscopy is developed to characterize individual interfaces in ternary polymer blends and hence determine the composition dependent miscibility level. The method owes its origin to the Kirkwood-Risemann-Zimm (KRZ) model for the evaluation of the hydrodynamic interaction parameters (α ij ) which was used successfully for a binary blend with a single interface. The model was revised for the present work for ternary polymer blends to account for three interfaces. The efficacy of this method is shown for two ternary blends namely poly(styrene-co-acrylonitrile)/poly (ethylene-co-vinylacetate)/poly(vinyl chloride) (SAN/EVA/PVC) and polycaprolactone /poly(styrene-co-acrylonitrile)/poly(vinyl chloride) (PCL/SAN/PVC) at different compositions. An effective hydrodynamic interaction parameter, α eff , was introduced to predict the overall miscibility of ternary blends.

  4. Blair oli ikkagi seotud Kelly nime lekitamisega / Maris Lillak

    Index Scriptorium Estoniae

    Lillak, Maris, 1970-

    2003-01-01

    Suurbritannia kaitseministeeriumi relvaeksperdi David Kelly surmaga seotud asjaolusid uuriv Huttoni komisjon selgitas, et peaminister Tony Blair oli kohtumisel, kus otsustati relvaeksperdi nime avalikustamine

  5. Miscibility of polymer blends with engineering models

    DEFF Research Database (Denmark)

    Vassilis, Harismiadis; van Bergen, A. R. D.; Goncalves, Ana Saraiva

    1996-01-01

    compared. The van der Waals equation of state was recently shown to accurately correlate and predict vapor-liquid and liquid-liquid equilibria for binary polymer/solvent solutions. In this work, it is demonstrated that it correlates the upper critical solution behavior of polymer blends with excellent...... accuracy using the usual mixing and combining rules and a single temperature- and composition-independent binary interaction parameter. This interaction parameter can be predicted via a generalized expression that uses only the pure component equation-of-state parameters. Using this generalized expression...

  6. Controlling the Solidification of Organic Photovoltaic Blends with Nucleating Agents

    KAUST Repository

    Nekuda Malik, Jennifer A.; Treat, Neil D.; Abdelsamie, Maged; Yu, Liyang; Li, Ruipeng; Smilgies, Detlef-M.; Amassian, Aram; Hawker, Craig J.; Chabinyc, Michael L.; Stingelin, Natalie

    2014-01-01

    Blending fullerenes with a donor polymer for the fabrication of organic solar cells often leads to at least partial vitrification of one, if not both, components. For prototypical poly(3-hexylthiophene):fullerene blend, we show that the addition of a commercial nucleating agent, di(3,4-dimethyl benzylidene)sorbitol, to such binary blends accelerates the crystallization of the donor, resulting in an increase in its degree of crystallinity in as-cast structures. This allows manipulation of the extent of intermixing/ phase separation of the donor and acceptor directly from solution, offering a tool to improve device characteristics such as power conversion efficiency.

  7. Controlling the Solidification of Organic Photovoltaic Blends with Nucleating Agents

    KAUST Repository

    Nekuda Malik, Jennifer A.

    2014-11-20

    Blending fullerenes with a donor polymer for the fabrication of organic solar cells often leads to at least partial vitrification of one, if not both, components. For prototypical poly(3-hexylthiophene):fullerene blend, we show that the addition of a commercial nucleating agent, di(3,4-dimethyl benzylidene)sorbitol, to such binary blends accelerates the crystallization of the donor, resulting in an increase in its degree of crystallinity in as-cast structures. This allows manipulation of the extent of intermixing/ phase separation of the donor and acceptor directly from solution, offering a tool to improve device characteristics such as power conversion efficiency.

  8. Production of silk sericin/silk fibroin blend nanofibers

    Directory of Open Access Journals (Sweden)

    Zhang Xianhua

    2011-01-01

    Full Text Available Abstract Silk sericin (SS/silk fibroin (SF blend nanofibers have been produced by electrospinning in a binary SS/SF trifluoroacetic acid (TFA solution system, which was prepared by mixing 20 wt.% SS TFA solution and 10 wt.% SF TFA solution to give different compositions. The diameters of the SS/SF nanofibers ranged from 33 to 837 nm, and they showed a round cross section. The surface of the SS/SF nanofibers was smooth, and the fibers possessed a bead-free structure. The average diameters of the SS/SF (75/25, 50/50, and 25/75 blend nanofibers were much thicker than that of SS and SF nanofibers. The SS/SF (100/0, 75/25, and 50/50 blend nanofibers were easily dissolved in water, while the SS/SF (25/75 and 0/100 blend nanofibers could not be completely dissolved in water. The SS/SF blend nanofibers could not be completely dissolved in methanol. The SS/SF blend nanofibers were characterized by Fourier transform infrared (FTIR spectroscopy, differential scanning calorimetry, and differential thermal analysis. FTIR showed that the SS/SF blend nanofibers possessed a random coil conformation and ß-sheet structure.

  9. MICROENCAPSULATION OF TURMERIC OLEORESIN IN BINARY AND TERNARY BLENDS OF GUM ARABIC, MALTODEXTRIN AND MODIFIED STARCH

    Directory of Open Access Journals (Sweden)

    Diana Maria Cano-Higuita

    2015-04-01

    Full Text Available Spray-drying is a suitable method to obtain microencapsulated active substances in the powdered form, resulting in powders with improved protection against environmental factors as well as with higher solubility in water, as in the case of turmeric oleoresin. The present study investigated the spray-drying process of turmeric oleoresin microencapsulated with binary and ternary mixtures of different wall materials: gum Arabic, maltodextrin, and modified corn starch. A statistical simplex centroid experimental design was used considering the encapsulation efficiency, curcumin retention, process yield, water content, solubility, and particle morphology as the analyzed responses. Wall matrices containing higher proportions of modified starch and gum Arabic resulted in higher encapsulation efficiency and curcumin retention, whereas the process yield and water content increased with higher proportions of maltodextrin and gum Arabic, respectively. Regression models of the responses were obtained using a surface response method (ANOVA way, showing statistical values of R2 > 0.790. Also, mean analysis was carried out by Tukey's test, permitting to observe some statistical differences between the blends

  10. Topological and morphological analysis of gamma rays irradiated chitosan-poly (vinyl alcohol) blends using atomic force microscopy

    International Nuclear Information System (INIS)

    Bhatt, Rinkesh; Bisen, D.S.; Bajpai, R.; Bajpai, A.K.

    2017-01-01

    In the present communication, binary blends of poly (vinyl alcohol) (PVA) and chitosan (CS) were prepared by solution cast method and the roughness parameters of PVA, native CS and CS-PVA blend films were determined using atomic force microscopy (AFM). Moreover, the changes in the morphology of the samples were also investigated after irradiation of gamma rays at absorbed dose of 1 Mrad and 10 Mrad for the scanning areas of 5×5 µm 2 , 10×10 µm 2 and 20×20 µm 2 . Amplitude, statistical and spatial parameters, including line, 3D and 2D image profiles of the experimental surfaces were examined and compared to un-irradiated samples. For gamma irradiated CS-PVA blends the larger waviness over the surface was found as compared to un-irradiated CS-PVA blends but the values of average roughness for both the films were found almost same. The coefficient of skewness was positive for gamma irradiated CS-PVA blends which revealed the presence of more peaks than valleys on the blend surfaces. - Highlights: • Binary polymer blends of chitosan and PVA were prepared. • Irradiation by gamma rays exhibited a significant change in surface morphology. • Various topographical and morphological parameters were investigated. • The prepared irradiated blends may find biomedical applications.

  11. Preparation of poly(3-hydroxybutyrate)/carboxymethyl cellulose acetate butyrate blends using gel formation

    International Nuclear Information System (INIS)

    Gomes, A.L.; Rodrigues, G.V.; Goncalves, M.C.

    2009-01-01

    This study investigates poly(3-hydroxybutyrate) (PHB) gel formation with a binary combination of solvents and its use on the preparation of PHB and carboxymethyl cellulose acetate butyrate (CMCAB) blends. The gel preparation method was compared to a precipitation method followed by hot pressing. The results from DSC and X-ray diffractions showed that both methodologies produced blends with very similar thermal properties and crystallization behavior. Scanning electron microscopy indicated better homogeneity in gel formation blends. Apart from this, the gel formation methodology provided new ways to prepare immiscible blends with the advantage of using friendlier solvents. (author)

  12. Lugu mehest, kes oli iseenda naine / Kaja Roomets

    Index Scriptorium Estoniae

    Roomets, Kaja

    2008-01-01

    Doug Wrighti "Ma olen iseenda naine" Endla teatris, lavastaja Tiit Palu. Esietendus 27. juunil. Lisaks saksa päritolu transvestiidist Charlotte von Mahlsdofist (1928-2002) : "Charlotte oli fenomen" ja Kati Murutari ning Raivo Järvi arvamus : "Mis tunde esietenduselt kaasa saite?"

  13. Changes on the Solid Fat Content of Palm Oil/ Sunflower Oil Blends via Inter esterification

    International Nuclear Information System (INIS)

    Suria Ramli; Azwani Mohd Lazim; Siti Aishah Hasbullah

    2013-01-01

    Physicochemical characteristics of binary blends containing refined-deodorized-bleached palm oil (RBDPO) and sunflower oil (SFO) were studied before and after chemical inter esterification at different temperature (110 degree Celsius (CIE1) and 80 degree Celsius (CIE2)) using sodium methoxide as catalyst. Thirty-three samples with different ratios were analyzed for triacylglycerol (TAG) composition, fatty acid composition (FAC) and solid fat content (SFC) profile. Upon CIE, extensive rearrangements of fatty acids among triacylglycerol (TAG) were seen. Generally, CIE not induced enormous changes in the TAG compositions of ratio 8:2 and 5:5 of RBDPO:SFO blends. However, CIE induced enormous changes in the TAG compositions of the 9:1, 7:3, 6:4, 4:6, 3:7, 2:8 and 1:9 blends, which some of the TAGs were increasing while the other decreasing. These changes in TAG profiles resulted in some changes in the physical properties (especially SFC) of the blends. Generally, the SFC of inter esterified blend were decreased after CIE1 and increased after CIE2, except for sample 10:0, 8:2, 7:3, 5:5 and 9:1 which were decreased after CIE1 and CIE2. As a conclusion, CIE1 and CIE2 successfully changed the physicochemical characteristics of the binary blends. (author)

  14. Thermal profiles, crystallization behaviors and microstructure of diacylglycerol-enriched palm oil blends with diacylglycerol-enriched palm olein.

    Science.gov (United States)

    Xu, Yayuan; Zhao, Xiaoqing; Wang, Qiang; Peng, Zhen; Dong, Cao

    2016-07-01

    To elucidate the possible interaction mechanisms between DAG-enriched oils, this study investigated how mixtures of DAG-enriched palm-based oils influenced the phase behavior, thermal properties, crystallization behaviors and the microstructure in binary fat blends. DAG-enriched palm oil (PO-DAGE) was blended with DAG-enriched palm olein (POL-DAGE) in various percentages (0%, 10%, 30%, 50%, 70%, 90%, 100%). Based on the observation of iso-solid diagram and phase diagram, the binary mixture of PO-DAGE/POL-DAGE showed a better compatibility in comparison with their corresponding original blends. DSC thermal profiles exhibited that the melting and crystallization properties of PO-DAGE/POL-DAGE were distinctively different from corresponding original blends. Crystallization kinetics revealed that PO-DAGE/POL-DAGE blends displayed a rather high crystallization rate and exhibited no spherulitic crystal growth. From the results of polarized light micrographs, PO-DAGE/POL-DAGE blends showed more dense structure with very small needle-like crystals than PO/POL. X-ray diffraction evaluation revealed when POL-DAGE was added in high contents to PO-DAGE, above 30%, β-polymorph dominated, and the mount of β' forms crystals was decreasing. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. APLIKASI METODE KHUN-TUCKER DALAM PENJUALAN OLI MOBIL (Studi Kasus : PT. Anugrah Mitra Dewata

    Directory of Open Access Journals (Sweden)

    Ni Made Asih

    2012-11-01

    Full Text Available Aplikasikan Metode Khun-Tucker dalam kasus penjualan oli mobil padaPT. Anugrah Mitra Dewata merupakan salah satu kasus optimasi bersyarat, untukmengetahui oli apa yang harus diproduksi oleh perusahaan, agar mencapai keuntunganmaksimal dan nilai-nilai ekstrim yang akan diperoleh, yang nantinya berperandalam menentukan tingkat keuntungan yang diperoleh perusahaan. Metode Khun-Tucker ini dapat dipergunakan untuk mencari solusi optimal dari suatu fungsi tanpamemandang sifat apakah linier atau nonlinier. Dalam proses pengerjaannya MetodeKhun-Tucker secara esensial melibatkan langkah-langkah yang sama seperti halnyaMerode Lagrange, yaitu: Membentuk Lagrangian untuk dapat menghitungtitik-titik kritisnya, mencari semua solusi (x; , dan menghitung nilai f(x. Dalamproses pencarian semua solusi x dan nya dibantu dengan menggunakan programMATLAB. Hasil penelitian menunjukkan pada caturwulan I dengan memproduksioli SMO HP sebanyak 587 liter diperoleh keuntungan maksimal perusahaansebesar Rp 19.837.000 . Untuk caturwulan II dengan memproduksi oli SMO HPPLUS sebanyak 776 liter diperoleh keuntungan maksimal perusahaan sebesar Rp20.112.000. Untuk caturwulan III dengan memproduksi oli SMO HP sebanyak 470liter diperoleh keuntungan maksimal perusahaan sebesar Rp 20.029.000.

  16. "Se Pupuperhe-laulu oli kiva" : musiikki lapsen kasvun ja kehityksen tukena varhaiskasvatuksessa

    OpenAIRE

    Järvinen, Sari

    2016-01-01

    Opinnäytetyön tarkoituksena oli lisätä tietoa musiikin käyttömahdollisuuksista varhaiskasvatuksessa lasten kasvun ja kehityksen tukemisen välineenä. Tavoitteena oli luoda opas varhaiskasvattajille, josta he voivat tarpeen mukaan ottaa käyttöön valmiita menetelmiä. Oppaan menetelmät pyrin valitsemaan niin, että ne olisivat helppoja toteuttaa eikä vaatisi suuria esivalmisteluja. Opinnäytetyön toiminnallinen osuus koostui viidestä toimintatuokiosta, joissa testasin oppaan me...

  17. Exciplex dynamics in a conjugated polymer blend of MDMO-PPV and PCNEPV

    NARCIS (Netherlands)

    Offermans, T.; Hal, van P.A.; Koetse, M.M.; Meskers, S.C.J.; Janssen, R.A.J.; Kafafi, Z.H.

    2005-01-01

    The photophysical properties of a solution processed blend of two semiconducting polymers with electron donating and electron accepting properties, respectively, as used in polymer photovoltaic devices have been investigated. In the binary mixture of

  18. Non-isothermal crystallization of PET/PLA blends

    International Nuclear Information System (INIS)

    Chen, Huipeng; Pyda, Marek; Cebe, Peggy

    2009-01-01

    Binary blends of poly(ethylene terephthalate) with poly(lactic acid), PET/PLA, were studied by differential scanning calorimetry and X-ray scattering. The PET/PLA blends, prepared by solution casting, were found to be miscible in the melt over the entire composition range. Both quenched amorphous and semicrystalline blends exhibit a single, composition dependent glass transition temperature. We report the non-isothermal crystallization of (a) PET, with and without the presence of PLA crystals and (b) PLA, with and without the presence of PET crystals. PET can crystallize in all blends, regardless of whether PLA is amorphous or crystalline, and degree of crystallinity of PET decreases as PLA content increases. In contrast, PLA crystallization is strongly affected by the mobility of the PET fraction. When PET is wholly amorphous, PLA can crystallize even in 70/30 blends, albeit weakly. But when PET is crystalline, PLA cannot crystallize when its own content drops below 0.90. These different behaviors may possibly be related to the tendency of each polymer to form constrained chains, i.e., to form the rigid amorphous fraction, or RAF. PET is capable of forming a large amount of RAF, whereas relatively smaller amount of RAF forms in PLA. Like the crystals, the rigid amorphous fraction of one polymer component may inhibit the growth of crystals of the other blend partner.

  19. Alguses oli: Arvo Pärdi juubelikuu algas etendusega Noblessi valukojas

    Index Scriptorium Estoniae

    2010-01-01

    Tõnu Kaljuste ja Peeter Jalaka lavastusest "Alguses oli", lavastuse aluseks Arvo Pärdi teosed "In Principio" ja "Miserere", 17. augustil Noblesse valukojas toimunud etendusest, muusikaline juht Tõnu Kaljuste

  20. Assessment of The trophic state and Chlorophyll-a concentrations using Landsat OLI in Karaoun reservoir, Lebanon

    Directory of Open Access Journals (Sweden)

    Ali Fadel

    2016-12-01

    Full Text Available Fadel, A., Faour G. and Slim K. 2016. Assessment of the trophic state and chlorophyll-a concentrations using Landsat OLI in Karaoun reservoir, Lebanon. Lebanese Science Journal, 17(2: 130-145. Harmful algal blooms have become a worldwide environmental problem. A regular and cost-effective monitoring of these blooms is highly needed by lakes managers. Satellite remote sensing imagery like Landsat Operational Land Imager (OLI can be used to assess and monitor chlorophyll-a in water bodies over large areas in a cost-effective way. In this study, the accuracy of Landsat OLI to estimate chlorophyll-a was examined. Four field campaigns and cloud free images of Landsat OLI with 30 m resolution (01 May 2013, 21 August 2013, 10 July 2015, and 11 August 2015 were used in this study to determine the accuracy of Landsat OLI in estimating chlorophyll-a in a 12 km2 freshwater body, Karaoun reservoir. After atmospheric correction of these images, reflectance of single and multiple band combinations were compared to field chlorophyll-a data. Results of field campaigns showed that the trophic state of Karaoun reservoir is still eutrophic to hypereutrophic with high nutrient concentration and low phytoplankton biodiversity, dominated by cyanobacteria species, Microcystis aeruginosa and Aphanizomenon ovalisporum. On single band level, the in situ chlorophyll-a measurement correlated best with band 5 (0.85 - 0.88 µm, with R=0.75 and R2=0.57. Highest correlation (R=0.84 and R2=0.72 was obtained using band combination, B2:B4 band ratio multiplied by B5. Results indicated that Landsat OLI can be used effectively to determine chlorophyll-a concentration in lakes and reservoirs. We recommend the application of Landsat OLI as a satisfactory and cost effective method for monitoring chlorophyll-a in other lakes through-out the world

  1. Generation of Length Distribution, Length Diagram, Fibrogram, and Statistical Characteristics by Weight of Cotton Blends

    Directory of Open Access Journals (Sweden)

    B. Azzouz

    2007-01-01

    Full Text Available The textile fibre mixture as a multicomponent blend of variable fibres imposes regarding the proper method to predict the characteristics of the final blend. The length diagram and the fibrogram of cotton are generated. Then the length distribution, the length diagram, and the fibrogram of a blend of different categories of cotton are determined. The length distributions by weight of five different categories of cotton (Egyptian, USA (Pima, Brazilian, USA (Upland, and Uzbekistani are measured by AFIS. From these distributions, the length distribution, the length diagram, and the fibrogram by weight of four binary blends are expressed. The length parameters of these cotton blends are calculated and their variations are plotted against the mass fraction x of one component in the blend .These calculated parameters are compared to those of real blends. Finally, the selection of the optimal blends using the linear programming method, based on the hypothesis that the cotton blend parameters vary linearly in function of the components rations, is proved insufficient.

  2. Compatibilizing Bulk Polymer Blends by Using Organoclays

    Science.gov (United States)

    Si, Mayu; Gersappe, Dilip; Zhang, Wenhua; Ade, Harald; Rafailovich, Miriam; Sokolov, Jonathan; Rudomen, Gregory; Schwartz, Bradley; Fisher, Robert

    2004-03-01

    We investigated the compatiblizing performance of organoclays on melt mixed binary and tertiary polymer blends, such as, PS/PMMA, PC/SAN, PS/PMMA/PVC and PS/PMMA/PE. These polymer blends were characterized by TEM, STXM, DSC and DMA. TEM and STXM photographs show that the addition of organoclays into polymer blends drastically reduces the average domain size of the component phases. And the organoclay goes to the interfacial region between the different polymers and effectively slows down the domain size increasing during high temperature annealing. DMA and DSC results show the effect of organoclays on the mechanical properties and glass transitions temperature, which indicates the compatibilization on the molecular level. The generalized compatibilization induced by the nanoscale fillers for blends can be explained in terms of mean field models where the reduction of interfacial tension induced by in-situ grafting is counterbalanced by the increased bending energy due to the rigidity of the filler. This in turn can be shown to be a function of the degree of exfoliation, aspect ratio, and polymer filler interactions. Supported by NSF funded MRSEC at Stony Brook

  3. Transport en afbraak van olie in bodem en grondwater

    NARCIS (Netherlands)

    Begeman, E.; Gestel, van C.A.M.

    1978-01-01

    De bestrijding van olieverontreiniging in de bodem is vooral voor dezedrinkwaterbedrijven erg belangrijk. Het verkrijgen van inzicht in het transport van olie in de bodem is van belang om de verspreiding van een eventuele vervuiling te kunnen voorspellen, zodat de bestrijding effectiever kan worden

  4. Assessment of the Trophic State and Chlorophyll-A Concentrations using Landsat OLI in Karaoun Reservoir Lebanon

    International Nuclear Information System (INIS)

    Fadel, A.; Faour, GH.; Slim, K.

    2016-01-01

    Harmful algal blooms have become a worldwide environmental problem. A regular and cost -effective monitoring of these blooms is highly needed by lakes managers. Satellite remote sensing imagery like Landsat Operational Land Imager (OLI) can be used to assess and monitor chlorophyll-a in water bodies over large areas in a cost-effective way. In this study, the accuracy of Landsat OLI to estimate chlorophyll-a was examined. Four field campaigns and cloud free images of Landsat OLI with 30 m resolution (01 May 2013, 21 August 2013, 10 July 2015, and 11 August 2015) were used in this study to determine the accuracy of Landsat OLI in estimating chlorophyll-a in a 12 km2 fresh water body, Karaoun reservoir. After atmospheric correction of these images, reflectance of single and multiple band combinations were compared to field chlorophyll-a data. Results of field campaigns showed that the trophic state of Karaoun reservoir is still eutrophic to hypereutrophic withhigh nutrient concentration andlow phytoplankton biodiversity, dominatedby cyanobacteria species, Microcystis aeruginosa and Aphanizomenon ovalisporum. On single band level, the n situ chlorophyll-a measurement correlated best with band 5 (0.85 -0.88 μm), with R=0.75 and R2=0.57.Highest correlation (R=0.84 and R2=0.72) was obtained using band combination, B2:B4 band ratio multiplied by B5. Results indicated that Landsat OLI can be used effectively to determine chlorophyll-a concentration in lakes and reservoirs. We recommend the application of Landsat OLI as a satisfactory and cost effective method for monitoring chlorophyll-a in other lakes through-out the world. (author)

  5. Pressure and temperature effects in homopolymer blends and diblock copolymers

    DEFF Research Database (Denmark)

    Frielinghaus, H.; Schwahn, D.; Mortensen, K.

    1997-01-01

    Thermal composition fluctuations in a homogeneous binary polymer blend and in a diblock copolymer were measured by small-angle neutron scattering as a function of temperature and pressure. The experimental data were analyzed with theoretical expressions, including the important effect of thermal...... fluctuations. Phase boundaries, the Flory-Huggins interaction parameter and the Ginzburg number were obtained. The packing of the molecules changes with pressure. Therefore, the degree of thermal fluctuation as a function of packing and temperature was studied. While in polymer blends packing leads, in some...... respects, to a universal behaviour, such behaviour is not found in diblock copolymers. It is shown that the Ginzburg number decreases with pressure sensitively in blends, while it is constant in diblock copolymers. The Ginzburg number is an estimation of the transition between the universality classes...

  6. Two related lithium calixarene complexes, [p-tert-butylcalix[4]arene(OMe)(OH)2(OLi)](2).4MeCN and {p-tert-butylcalix[4]arene(OH)2(OLi)[OLi(NCMe)2]}(2).8MeCN, determined using synchrotron radiation.

    Science.gov (United States)

    Lee, Darren S; Elsegood, Mark R J; Redshaw, Carl; Zhan, Shuzhong

    2009-08-01

    The crystal structures of acetonitrile solvates of two related lithium calixarene complexes have been determined by low-temperature single-crystal X-ray diffraction using synchrotron radiation. Bis(mu-5,11,17,23-tetra-tert-butyl-26,28-dihydroxy-25-methoxy-27-oxidocalix[4]arene)dilithium(I) acetonitrile tetrasolvate, [Li2(C45H57O4)2].4C2H3N or [p-tert-butylcalix[4]arene(OMe)(OH)2(OLi)](2).4MeCN, (I), crystallizes with the complex across a centre of symmetry and with four molecules of unbound acetonitrile of crystallization per complex. Tetraacetonitrilebis(mu-5,11,17,23-tetra-tert-butyl-26,28-dihydroxy-25,27-dioxidocalix[4]arene)tetralithium(I) acetonitrile octasolvate, [Li4(C44H54O4)2(C2H3N)4].8C2H3N or {p-tert-butylcalix[4]arene(OH)2(OLi)[OLi(NCMe)2]}(2).8MeCN, (II), also crystallizes with the complex lying across a centre of symmetry and contains eight molecules of unbound acetonitrile per complex plus four more directly bound to two of the lithium ions, two on each ion. The cores of both complexes are partially supported by O-H...O hydrogen bonds. The methoxy methyl groups in (I) prevent the binding of any more than two Li+ ions, while the corresponding two O-atom sites in (II) bind an extra Li(+) ion each, making four in total. The calixarene cone adopts an undistorted cone conformation in (I), but an elliptical one in (II).

  7. Hemingway oli KGB, filmistaar Errol Flynn natside agent? / Tõnis Erilaid

    Index Scriptorium Estoniae

    Erilaid, Tõnis, 1943-

    2009-01-01

    John Earl Haynes, Harvey Klehr ja Alexander Vassiliev väidavad oma raamatus "Spies : The Rise and Fall of the KGB in America", et Ernest Hemingway oli 1940ndail aastail KGB ning Errol Flynn 1930ndatel aastatel natside agent

  8. Effect of the grinding behaviour of coal blends on coal utilisation for combustion

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, F.; Arenillas, A.; Fuente, E.; Pis, J.J. [Inst. Nacional del Carbon, CSIC, Oviedo (Spain); Miles, N. [School of Chemical, Environmental and Mining Engineering, Nottingham Univ. (United Kingdom)

    1999-11-01

    Grinding of a high volatile bituminous coal was performed in three comminution devices: Raymond Mill (RM), Rolls Crusher (RC) and Ball Mill (BM). The pulverised samples were sieved to obtain four particle size fractions, and temperature-programmed combustion (TPC) was used for the evaluation of their combustion behaviour. In addition, three coals of different hardness and rank were mixed in various proportions in order to compare the combustibility characteristics of the binary coal blends with those of the individual coals. The effect of coal blending on grindability was also studied. It was found that grindability was non-additive especially when coals of very different hardgrove grindability index (HGI) were blended. The combustion studies also suggested that there exists an interaction between individual coals when they are burnt as a blend. (orig.)

  9. Supertoughened renewable PLA reactive multiphase blends system: phase morphology and performance.

    Science.gov (United States)

    Zhang, Kunyu; Nagarajan, Vidhya; Misra, Manjusri; Mohanty, Amar K

    2014-08-13

    Multiphase blends of poly(lactic acid) (PLA), ethylene-methyl acrylate-glycidyl methacrylate (EMA-GMA) terpolymer, and a series of renewable poly(ether-b-amide) elastomeric copolymer (PEBA) were fabricated through reactive melt blending in an effort to improve the toughness of the PLA. Supertoughened PLA blend showing impact strength of ∼500 J/m with partial break impact behavior was achieved at an optimized blending ratio of 70 wt % PLA, 20 wt % EMA-GMA, and 10 wt % PEBA. Miscibility and thermal behavior of the binary blends PLA/PEBA and PLA/EMA-GMA, and the multiphase blends were also investigated through differential scanning calorimetric (DSC) and dynamic mechanical analysis (DMA). Phase morphology and fracture surface morphology of the blends were studied through scanning electron microscopy (SEM) and atomic force microscopy (AFM) to understand the strong corelation between the morphology and its significant effect on imparting tremendous improvement in toughness. A unique "multiple stacked structure" with partial encapsulation of EMA-GMA and PEBA minor phases was observed for the PLA/EMA-GMA/PEBA (70/20/10) revealing the importance of particular blend composition in enhancing the toughness. Toughening mechanism behind the supertoughened PLA blends have been established by studying the impact fractured surface morphology at different zones of fracture. Synergistic effect of good interfacial adhesion and interfacial cavitations followed by massive shear yielding of the matrix was believed to contribute to the enormous toughening effect observed in these multiphase blends.

  10. Tough Blends of Polylactide and Castor Oil

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A. (UMM)

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  11. Tough blends of polylactide and castor oil.

    Science.gov (United States)

    Robertson, Megan L; Paxton, Jessica M; Hillmyer, Marc A

    2011-09-01

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of l-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized-an order of magnitude larger than that of neat PLLA.

  12. Study of the Transformations of Micro/Nano-crystalline Acetaminophen Polymorphs in Drug-Polymer Binary Mixtures.

    Science.gov (United States)

    Maniruzzaman, Mohammed; Lam, Matthew; Molina, Carlos; Nokhodchi, Ali

    2017-07-01

    This study elucidates the physical properties of sono-crystallised micro/nano-sized acetaminophen/paracetamol (PMOL) and monitors its possible transformation from polymorphic form I (monoclinic) to form II (orthorhombic). Hydrophilic Plasdone® S630 copovidone (S630), N-vinyl-2-pyrrolidone and vinyl acetate copolymer, and methacrylate-based cationic copolymer, Eudragit® EPO (EPO), were used as polymeric carriers to prepare drug/polymer binary mixtures. Commercially available PMOL was crystallised under ultra sound sonication to produce micro/nano-sized (0.2-10 microns) crystals in monoclinic form. Homogeneous binary blends of drug-polymer mixtures at various drug concentrations were obtained via a thorough mixing. The analysis conducted via the single X-ray crystallography determined the detailed structure of the crystallised PMOL in its monoclinic form. The solid state and the morphology analyses of the PMOL in the binary blends evaluated via differential scanning calorimetry (DSC), modulated temperature DSC (MTDSC), scanning electron microscopy (SEM) and hot stage microscopy (HSM) revealed the crystalline existence of the drug within the amorphous polymeric matrices. The application of temperature controlled X-ray diffraction (VTXRPD) to study the polymorphism of PMOL showed that the most stable form I (monoclinic) was altered to its less stable form II (orthorhombic) at high temperature (>112°C) in the binary blends regardless of the drug amount. Thus, VTXRD was used as a useful tool to monitor polymorphic transformations of crystalline drug (e.g. PMOL) to assess their thermal stability in terms of pharmaceutical product development and research.

  13. Improvements to the Ontology-based Metadata Portal for Unified Semantics (OlyMPUS)

    Science.gov (United States)

    Linsinbigler, M. A.; Gleason, J. L.; Huffer, E.

    2016-12-01

    The Ontology-based Metadata Portal for Unified Semantics (OlyMPUS), funded by the NASA Earth Science Technology Office Advanced Information Systems Technology program, is an end-to-end system designed to support Earth Science data consumers and data providers, enabling the latter to register data sets and provision them with the semantically rich metadata that drives the Ontology-Driven Interactive Search Environment for Earth Sciences (ODISEES). OlyMPUS complements the ODISEES' data discovery system with an intelligent tool to enable data producers to auto-generate semantically enhanced metadata and upload it to the metadata repository that drives ODISEES. Like ODISEES, the OlyMPUS metadata provisioning tool leverages robust semantics, a NoSQL database and query engine, an automated reasoning engine that performs first- and second-order deductive inferencing, and uses a controlled vocabulary to support data interoperability and automated analytics. The ODISEES data discovery portal leverages this metadata to provide a seamless data discovery and access experience for data consumers who are interested in comparing and contrasting the multiple Earth science data products available across NASA data centers. Olympus will support scientists' services and tools for performing complex analyses and identifying correlations and non-obvious relationships across all types of Earth System phenomena using the full spectrum of NASA Earth Science data available. By providing an intelligent discovery portal that supplies users - both human users and machines - with detailed information about data products, their contents and their structure, ODISEES will reduce the level of effort required to identify and prepare large volumes of data for analysis. This poster will explain how OlyMPUS leverages deductive reasoning and other technologies to create an integrated environment for generating and exploiting semantically rich metadata.

  14. RAČUNALNIŠTVO V OBLAKU IN PRIMERI PRESKUSOV GOOGLE APPS. V OSNOVNI ŠOLI

    OpenAIRE

    Krapež, Domen

    2013-01-01

    Diplomska naloga obravnava računalništvo v oblaku in primere preskusov Google Apps v osnovni šoli na konkretnih primerih. Za potrebe naloge so podrobno opisane storitve, Gmail, Google Calendar, Google Docs ter Google Drive. V eksperimentalnem delu naloge je bila izvedena analiza uporabe Google Apps pred in po uporabi aplikacije v osnovni šoli. Rezultati vprašalnika so pokazali, da je pot do uspešne integracije novih tehnologij še dolga ter da mora izobraževanje kadrov potekati postopoma. R...

  15. Alguses oli HELI ja PÄRT, siis Jalaka LAVASTUS / Riina Luik

    Index Scriptorium Estoniae

    Luik, Riina, 1962-

    2010-01-01

    Tõnu Kaljuste ja Peeter Jalaka lavastusest "Alguses oli", lavastuse aluseks Arvo Pärdi teosed "In Principio" ja "Miserere", 17. augustil Noblesse valukojas toimunud etendusest, muusikaline juht Tõnu Kaljuste. Arvo Pärdi pidunädalate ürituste loetelu

  16. a Preliminary Investigation on Comparison and Transformation of SENTINEL-2 MSI and Landsat 8 Oli

    Science.gov (United States)

    Chen, F.; Lou, S.; Fan, Q.; Li, J.; Wang, C.; Claverie, M.

    2018-05-01

    A PRELIMINARY INVESTIGATION ON COMPARISON AND TRANSFORMATION OF SENTINEL-2 MSI AND LANDSAT 8 OLI Timely and accurate earth observation with short revisit interval is usually necessary, especially for emergency response. Currently, several new generation sensors provided with similar channel characteristics have been operated onboard different satellite platforms, including Sentinel-2 and Landsat 8. Joint use of the observations by different sensors offers an opportunity to meet the demands for emergency requirements. For example, through the combination of Landsat and Sentinel-2 data, the land can be observed every 2-3 days at medium spatial resolution. However, differences are expected in radiometric values (e.g., channel reflectance) of the corresponding channels between two sensors. Spectral response function (SRF) is taken as an important aspect of sensor settings. Accordingly, between-sensor differences due to SRFs variation need to be quantified and compensated. The comparison of SRFs shows difference (more or less) in channel settings between Sentinel-2 Multi-Spectral Instrument (MSI) and Landsat 8 Operational Land Imager (OLI). Effect of the difference in SRF on corresponding values between MSI and OLI was investigated, mainly in terms of channel reflectance and several derived spectral indices. Spectra samples from ASTER Spectral Library Version 2.0 and Hyperion data archives were used in obtaining channel reflectance simulation of MSI and OLI. Preliminary results show that MSI and OLI are well comparable in several channels with small relative discrepancy (model is not ensured when the target belongs to another spectra collection. If an improper transformation model is selected, the between-sensor discrepancy will even largely increase. In conclusion, improvement in between-sensor consistency is possibly a challenge, through linear transformation based on model(s) generated from other spectra collections.

  17. Highly toughened polypropylene/ethylene–propylene-diene monomer/zinc dimethacrylate ternary blends prepared via peroxide-induced dynamic vulcanization

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yukun, E-mail: cyk@scut.edu.cn [The Key Laboratory of Polymer Processing Engineering, Ministry of Education, South China University of Technology, Guangzhou 510640 (China); School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640 (China); Xu, Chuanhui [College of Material Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Cao, Liming [The Key Laboratory of Polymer Processing Engineering, Ministry of Education, South China University of Technology, Guangzhou 510640 (China); School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640 (China); Cao, Xiaodong [College of Material Science and Engineering, South China University of Technology, Guangzhou 510640 (China)

    2013-02-15

    Polypropylene (PP)/ethylene–propylene-diene monomer (EPDM)/zinc dimethacrylate (ZDMA) blends with remarkable toughness and extensibility were successfully prepared via peroxide dynamical vulcanization. A unique structure with the EPDM particles surrounded by a transition zone containing numerous polymerized ZDMA (PZDMA) nano-particles was observed for the first time by using transmission electron microscopy (TEM) examination, which contributed to the dramatically increase of Izod impact strength. Dynamic mechanical analysis (DMA) confirmed that the possible PZDMA graft products resulted from peroxide dynamical vulcanization improved the compatibility between EPDM and PP phases. The specific morphology of the PP/EPDM/ZDMA blends indicated that ZDMA can lead to size reduction and good distribution uniformity of the crosslinked rubber particles and the increase of adhesion between PP matrix and EPDM phases during deformation. The synergic effect of the increase in the effective volume of the EPDM phase, the improved compatibility and adhesion between EPDM and PP phases and the deformation of those fine rubber particles is believed to result in the remarkable high toughness and extensibility of the PP/EPDM/ZDMA blends. Particularly for the PP/EPDM ratio of 70/30, the PP/EPDM/ZDMA (70/30/9, w/w/w) ternary blends with the Izod impact strength nearly 2 times higher than PP/EPDM (70/30, w/w) binary blends and 15–20 times higher than PP are achieved; besides, the elongation at break of PP/EPDM/ZDMA ternary blends is 4–5 times higher than that of PP/EPDM binary blends. - Highlights: ► ZDMA largely toughen peroxide dynamically vulcanized PP/EPDM blend. ► PZDMA graft products improved the compatibility and adhesion between EPDM and PP. ► Size reduction and good distribution uniformity of crosslinked rubber particles.

  18. Highly toughened polypropylene/ethylene–propylene-diene monomer/zinc dimethacrylate ternary blends prepared via peroxide-induced dynamic vulcanization

    International Nuclear Information System (INIS)

    Chen, Yukun; Xu, Chuanhui; Cao, Liming; Cao, Xiaodong

    2013-01-01

    Polypropylene (PP)/ethylene–propylene-diene monomer (EPDM)/zinc dimethacrylate (ZDMA) blends with remarkable toughness and extensibility were successfully prepared via peroxide dynamical vulcanization. A unique structure with the EPDM particles surrounded by a transition zone containing numerous polymerized ZDMA (PZDMA) nano-particles was observed for the first time by using transmission electron microscopy (TEM) examination, which contributed to the dramatically increase of Izod impact strength. Dynamic mechanical analysis (DMA) confirmed that the possible PZDMA graft products resulted from peroxide dynamical vulcanization improved the compatibility between EPDM and PP phases. The specific morphology of the PP/EPDM/ZDMA blends indicated that ZDMA can lead to size reduction and good distribution uniformity of the crosslinked rubber particles and the increase of adhesion between PP matrix and EPDM phases during deformation. The synergic effect of the increase in the effective volume of the EPDM phase, the improved compatibility and adhesion between EPDM and PP phases and the deformation of those fine rubber particles is believed to result in the remarkable high toughness and extensibility of the PP/EPDM/ZDMA blends. Particularly for the PP/EPDM ratio of 70/30, the PP/EPDM/ZDMA (70/30/9, w/w/w) ternary blends with the Izod impact strength nearly 2 times higher than PP/EPDM (70/30, w/w) binary blends and 15–20 times higher than PP are achieved; besides, the elongation at break of PP/EPDM/ZDMA ternary blends is 4–5 times higher than that of PP/EPDM binary blends. - Highlights: ► ZDMA largely toughen peroxide dynamically vulcanized PP/EPDM blend. ► PZDMA graft products improved the compatibility and adhesion between EPDM and PP. ► Size reduction and good distribution uniformity of crosslinked rubber particles

  19. Landsat 8 Operational Land Imager (OLI)_Thermal Infared Sensor (TIRS) V1

    Data.gov (United States)

    National Aeronautics and Space Administration — Abstract:The Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) are instruments onboard the Landsat 8 satellite, which was launched in February of...

  20. Component dynamics in polymer blends a combined QENS and dielectric spectroscopy investigation

    CERN Document Server

    Hofmann, S; Arbe, A; Colmenero, J; Faragó, B

    2002-01-01

    The individual dynamics of the two constituents of a binary polymer blend was studied by means of quasielastic neutron scattering and dielectric spectroscopy (DS). The combination of neutron spin-echo and backscattering techniques allowed us to cover the complete crossover from entropy-driven chain dynamics on mesoscopic scales to the alpha relaxation on local length scales. The observed blending effects on the respective relaxation times suggest a purely dynamic origin of the dynamic heterogeneity in polymer blends at temperatures well above the glass-transition temperature without the need to assume local phase separation. In contrast, the results from DS experiments towards much lower temperatures indicate systematic deviations of the segmental dynamics in the blend from its mean-field-like behavior at high temperatures. This additionally increases the dynamic heterogeneity in the segmental dynamics of the two components in the mixture. In the case of the chain dynamics, no similar effect could be observed...

  1. Miscibility Studies on Polymer Blends Modified with Phytochemicals

    Science.gov (United States)

    Chandrasekaran, Neelakandan; Kyu, Thein

    2009-03-01

    The miscibility studies related to an amorphous poly(amide)/poly(vinyl pyrrolidone) [PA/PVP] blend with a crystalline phytochemical called ``Mangiferin'' is presented. Phytochemicals are plant derived chemicals which intrinsically possess multiple salubrious properties that are associated with prevention of diseases such as cancer, diabetes, cardiovascular disease, and hypertension. Incorporation of phytochemicals into polymers has shown to have very promising applications in wound healing, drug delivery, etc. The morphology of these materials is crucial to applications like hemodialysis, which is governed by thermodynamics and kinetics of the phase separation process. Hence, miscibility studies of PA/PVP blends with and without mangiferin have been carried out using dimethyl sulfoxide as a common solvent. Differential scanning calorimetry studies revealed that the binary PA/PVP blends were completely miscible at all compositions. However, the addition of mangiferin has led to liquid-liquid phase separation and liquid-solid phase transition in a composition dependent manner. Fourier transformed infrared spectroscopy was undertaken to determine specific interaction between the polymer constituents and the role of possible hydrogen bonding among three constituents will be discussed.

  2. Film-thickness dependence of structure formation in ultra-thin polymer blend films

    CERN Document Server

    Gutmann, J S; Stamm, M

    2002-01-01

    We investigated the film-thickness dependence of structure formation in ultra-thin polymer blend films prepared from solution. As a model system we used binary blends of statistical poly(styrene-co-p-bromostyrene) copolymers of different degrees of bromination. Ultra-thin-film samples differing in miscibility and film thickness were prepared via spin coating of common toluene solutions onto silicon (100) substrates. The resulting morphologies were investigated with scanning force microscopy, reflectometry and grazing-incidence scattering techniques using both X-rays and neutrons in order to obtain a picture of the sample structure at and below the sample surface. (orig.)

  3. Oral sustained release tablets of zidovudine using binary blends of natural and synthetic polymers.

    Science.gov (United States)

    Emeje, Martins; Olaleye, Olajide; Isimi, Christiana; Fortunak, Joseph; Byrn, Stephen; Kunle, Olobayo; Ofoefule, Sabinus

    2010-01-01

    Oral sustained release matrix tablets of zidovudine (ZDV) were prepared using different types, proportions and blends of carbopol 71G (C71) and a plant gum obtained from Abelmoschus esculentus (AEG). The effect of various formulation factors like polymer proportion, polymer type and pH of the dissolution medium on the in vitro release of the drug was studied, using the half change technique, in 900 ml of dissolution medium, at 100 rpm. Release kinetics were analyzed using Zero-order, Higuchi's square-root and Ritger-Peppas' empirical equations. In vitro release performance as revealed by the time taken for 70% of the drug to be released (t70%), showed that the release rate decreased with increase in polymer proportion. Matrix tablets containing 10 and 20% AEG were found to exhibit immediate-release characteristics. Matrix tablets containing 30% AEG showed t70% value of 204 min and extended the release up to 5 h, while matrix tablets containing 30% carbopol showed t70% value of 234 min and extended the release up to 6 h. Three blends of AEG and C71 at the ratio of 1:2, 2:1 and 1:3 showed t70% values of 132, 312 and 102 min respectively and extended the release up to 8 h. Mathematical analysis of the release kinetics indicated that the nature of drug release from the matrix tablets followed Fickian and anomalous release. Drug release from matrix tablets of zidovudine containing blends of AEG and C71 demonstrates the advantage of blending a natural and synthetic polymer over single polymer use.

  4. Analysis of Coastline Extraction from Landsat-8 OLI Imagery

    Directory of Open Access Journals (Sweden)

    Yaolin Liu

    2017-10-01

    Full Text Available Coastline extraction is a fundamental work for coastal resource management, coastal environmental protection and coastal sustainable development. Due to the free access and long-term record, Landsat series images have the potential to be used for coastline extraction. However, dynamic features of different types of coastlines (e.g., rocky, sandy, artificial, caused by sea level fluctuation from tidal, storm and reclamation, make it difficult to be accurately extracted with coarse spatial resolution, e.g., 30 m, of Landsat images. To access this problem, we analyze the performance of coastline extraction by integrating downscaling, pansharpening and water index approaches in increasing the accuracy of coastline extraction from the latest Landsat-8 Operational Land Imager (OLI imagery. In order to prove the availability of the proposed method, we designed three strategies: (1 Strategy 1 uses the traditional water index method to extract coastline directly from original 30 m Landsat-8 OLI multispectral (MS image; (2 Strategy 2 extracts coastlines from 15 m fused MS images generated by integrating 15 m panchromatic (PAN band and 30 m MS image with ten pansharpening algorithms; (3 Strategy 3 first downscales the PAN band to a finer spatial resolution (e.g., 7.5 m band, and then extracts coastlines from pansharpened MS images generated by integrating downscaled spatial resolution PAN band and 30 m MS image with ten pansharpening algorithms. Using the coastline extracted from ZiYuan-3 (ZY-3 5.8 m MS image as reference, accuracies of coastlines extracted from MS images in three strategies were validated visually and quantitatively. The results show that, compared with coastline extracted directly from 30 m Landsat-8 MS image (strategy 1, strategy 3 achieves the best accuracies with optimal mean net shoreline movement (MNSM of −2.54 m and optimal mean absolute difference (MAD of 11.26 m, followed by coastlines extracted in strategy 2 with optimal MNSM

  5. Identification of Water Bodies in a Landsat 8 OLI Image Using a J48 Decision Tree.

    Science.gov (United States)

    Acharya, Tri Dev; Lee, Dong Ha; Yang, In Tae; Lee, Jae Kang

    2016-07-12

    Water bodies are essential to humans and other forms of life. Identification of water bodies can be useful in various ways, including estimation of water availability, demarcation of flooded regions, change detection, and so on. In past decades, Landsat satellite sensors have been used for land use classification and water body identification. Due to the introduction of a New Operational Land Imager (OLI) sensor on Landsat 8 with a high spectral resolution and improved signal-to-noise ratio, the quality of imagery sensed by Landsat 8 has improved, enabling better characterization of land cover and increased data size. Therefore, it is necessary to explore the most appropriate and practical water identification methods that take advantage of the improved image quality and use the fewest inputs based on the original OLI bands. The objective of the study is to explore the potential of a J48 decision tree (JDT) in identifying water bodies using reflectance bands from Landsat 8 OLI imagery. J48 is an open-source decision tree. The test site for the study is in the Northern Han River Basin, which is located in Gangwon province, Korea. Training data with individual bands were used to develop the JDT model and later applied to the whole study area. The performance of the model was statistically analysed using the kappa statistic and area under the curve (AUC). The results were compared with five other known water identification methods using a confusion matrix and related statistics. Almost all the methods showed high accuracy, and the JDT was successfully applied to the OLI image using only four bands, where the new additional deep blue band of OLI was found to have the third highest information gain. Thus, the JDT can be a good method for water body identification based on images with improved resolution and increased size.

  6. Veerenni asumi süda oli Lutheri vabrik / Robert Nerman

    Index Scriptorium Estoniae

    Nerman, Robert, 1946-2015

    2008-01-01

    Tallinna kesklinnas Pärnu maantee, Tallinn-Narva raudtee ja Siselinna kalmistu vahel asuva piirkonna ajaloost. Lutheri puidutööstuse rajamisest. Hooned projekteeris arhitekt Erwin Bernhard. Juugendstiilis rahvamaja arhitektid olid Herman Gesellius, Armas Lindgren ja Eliel Saarinen. Keskhaigla töötajatele Herne tänavale rajatud elamute ning Tallinna Ühisgümnaasiumi hoone arhitekt oli Herbert Johanson

  7. Fullerene alloy formation and the benefits for efficient printing of ternary blend organic solar cells

    DEFF Research Database (Denmark)

    Angmo, Dechan; Bjerring, Morten; Nielsen, Niels Chr.

    2015-01-01

    behaving as pseudo-binary mixtures due to alloying of the fullerene components. This finding has vast implications for the understanding of polymer–fullerene mixtures and quite certainly also their application in organic solar cells where performance hinges critically on the blend behaviour which is also...

  8. Dynamics and order-disorder transitions in bidisperse diblock copolymer blends

    International Nuclear Information System (INIS)

    Wang Yueqiang; Li Xuan; Tang Ping; Yang Yuliang

    2011-01-01

    We employ the dynamic extension of self-consistent field theory (DSCFT) to study dynamics and order-disorder transitions (ODT) in AB diblock copolymer binary mixtures of two different monodisperse chain lengths by imitating the dynamic storage modulus G' corresponding to any given morphology in the oscillatory shear measurements. The different polydispersity index (PDI) is introduced by binary blending AB diblock copolymers with variations in chain lengths and chain number fractions. The simulation results show that the increase of polydispersity in the minority or symmetric block introduces a decrease in the segregation strength at the ODT, (χN) ODT , whereas the increase of polydispersity in the majority block results in a decrease, then increase and final decrease again in (χN) ODT . To the best of our knowledge, our DSCFT simulations, for the first time, predict an increase in (χN) ODT with the PDI in the majority block, which produces the experimental results. The simulations by previous SCFT, which generally speaking, is capable of describing equilibrium morphologies, however, contradict the experimental data. The polydispersity acquired by properly tuning the chain lengths and number fractions of binary diblock copolymer blends should be a convenient and efficient way to control the microphase separation strength at the ODT. -- Research highlights: → Order-disorder transition in AB diblock copolymer mixtures is investigated using DSCFT. → Microphase separation strength at the ODT increases with PDI in the majority block. → Microphase separation strength at the ODT decreases with PDI in the minority block. → Introduction of polydispersity is efficient to control microphase separation strength at the ODT.

  9. The durability of concrete containing a high-level of fly ash or a ternary blend of supplementary cementing materials

    Science.gov (United States)

    Gilbert, Christine M.

    The research for this study was conducted in two distinct phases as follows: Phase 1: The objective was to determine the effect of fly ash on the carbonation of concrete. The specimens made for this phase of the study were larger in size than those normally used in carbonation studies and were are meant to more accurately reflect real field conditions. The results from early age carbonation testing indicate that the larger size specimens do not have a measured depth of carbonation as great as that of the smaller specimens typically used in carbonation studies at the same age and under the same conditions. Phase 2: The objective was to evaluate the performance of ternary concrete mixes containing a ternary cement blend consisting of Portland cement, slag and Type C fly ash. It was found that concrete mixtures containing the fly ash with the lower calcium (CaO) content (in binary or ternary blends) provided superior durability performance and resistance to ASR compared to that of the fly ash with the higher CaO content. Ternary blends (regardless of the CaO content of the fly ash) provided better overall durability performance than binary blends of cementing materials or the control.

  10. "Alguses oli tema üksinda, sest oli küll..." : [luuletused] / Kabir ; tlk. Doris Kareva

    Index Scriptorium Estoniae

    Kabir

    2006-01-01

    Sisu: "Alguses oli tema üksinda, sest oli küll..." ; "Kõik loodud on Kõiksuse poolt..." ; "Otsid Sa mind?..." ; "Kabir oma meele puhtaks..." ; "Pole pühades järvedes midagi muud peale vee..." ; "Otsisin kelme ja kõveraid..." ; "Ütle, vend, mida küll teha..." ; "Mis kurja on teinud su juuksed..." ; "Ära tõuse, et minna õue vaatama lilli..." ; "Sinu sünd inimesena on küps vili..." ; "Öö saatsid sa magades mööda..." ; "Pole ma hindu..." ; "Ma vaatan sind..." ; "Veskikivisid vaadeldes ; "Nähes aednikku lähenemas, õhkasid pungad..." ; "Tasa, tasa tõtta, mu meel..." ; "Ära kurvasta..." ; "Imetlusväärne on teemant..." ; "Kuula, sõber, see keha on Tema lüüra..." ; "Nagu seemnes varjul on õli..." ; "Olgugi ookean leekides..." ; "Tilka, mis lahustub meres..." ; "Jõgi ja lained on üks..." ; "Kes sa oled ja kust oled tulnud?..." ; "Kaovad kuningad, kauneimad kuningannad..." ; "Rohkem kui midagi muud..." ; "Lihalik, surelik tantsib selle ees..." ; "Väike rubiin, mida igaüks ihkab..." ; "Mine heade juurde, kus Armastatugi elab..." ; "Eksitus sulgeb väravad..." ; "Keelilt vallandub helisid..." ; "Kõik algab lahusoleku valust..." ; "Ärka, sõber! Miks ikka veel magad?..." ; "Kuu on mu kehas, kuid ise ma seda ei näe..." ; "Miks oled nii kärsitu, süda?..." ; "Kellele kuulub see flööt..." ; "Kui raske on Külalist kohata!..." ; "Kandetool toodi minule järgi mu isakoju..." ; "Siia ilma sündides nutsid..." ; "Oh mu süda! Ei jõudnud sa tundma õppida..." ; "Õige kulunud on sinu rüü..." ; "Õhkõrn on see õhuke rüü..." ; "Lipp, mida keegi ei näe..." ; "Oh otsija, lihtne liit lähim on südamele..." ; "Õhtu varjud on sügavaks saanud..." ; "Kuis saakski katkeda armastus me kahe vahel..." ; "Luik, tahaksin, et mulle räägiksid kõik oma loo..." ; "Kuhu ihaled küll, minu süda?..." ; "Ei lakka Lõpmatu flöödiheli..." ; "Mida näed, seda pole...". Autori kohta eluloolisi andmeid lk. 11

  11. How Chain Intermixing Dictates the Polymorphism of PVDF in Poly(vinylidene fluoride/Polymethylmethacrylate Binary System during Recrystallization: A Comparative Study on Core–Shell Particles and Latex Blend

    Directory of Open Access Journals (Sweden)

    Yue Li

    2017-09-01

    Full Text Available In the past few decades, Poly(vinylidene fluoride/Polymethylmethacrylate (PVDF/PMMA binary blend has attracted substantial attention in the scientific community due to possible intriguing mechanical, optical and ferroelectric properties that are closely related to its multiple crystal structures/phases. However, the effect of PMMA phase on the polymorphism of PVDF, especially the relationship between miscibility and polymorphism, remains an open question and is not yet fully understood. In this work, three series of particle blends with varied levels of miscibility between PVDF and PMMA were prepared via seeded emulsion polymerization: PVDF–PMMA core–shell particle (PVDF@PMMA with high miscibility; PVDF/PMMA latex blend with modest miscibility; and PVDF@c–PMMA (crosslinked PMMA core–shell particle with negligible miscibility. The difference in miscibility, and the corresponding morphology and polymorphism were systematically studied to correlate the PMMA/PVDF miscibility with PVDF polymorphism. It is of interest to observe that the formation of polar β/γ phase during melt crystallization could be governed in two ways: dipole–dipole interaction and fast crystallization. For PVDF@PMMA and PVDF/PMMA systems, in which fast crystallization was unlikely triggered, higher content of β/γ phase, and intense suppression of crystallization temperature and capacity were observed in PVDF@PMMA, because high miscibility favored a higher intensity of overall dipole–dipole interaction and a longer interaction time. For PVDF@c–PMMA system, after a complete coverage of PVDF seeds by PMMA shells, nearly pure β/γ phase was obtained owing to the fast homogeneous nucleation. This is the first report that high miscibility between PVDF and PMMA could favor the formation of β/γ phase.

  12. Ultraporous interweaving electrospun microfibers from PCL-PEO binary blends and their cellular response

    DEFF Research Database (Denmark)

    Chen, Menglin; Li, Yanfang; Besenbacher, Flemming

    2015-01-01

    from a blend of polycaprolactone (PCL) and polyethylene oxide (PEO) in a DCM-DMF mixed solution when the ratio between each component reached a threshold and when the electrospinning parameters were delicately controlled. We further investigated their influence on cell infiltration and colonization...

  13. Exhaust gas emissions and mutagenic effects of modern diesel fuels, GTL, biodiesel and biodiesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Munack, Axel; Ruschel, Yvonne; Schroeder, Olaf [Federal Research Institute for Rural Areas, Forestry and Fisheries, Braunschweig (Germany)], E-mail: axel.munack@vti.bund.de; Krahl, Juergen [Coburg Univ. of Applied Sciences (Germany); Buenger, Juergen [University of Bochum (Germany)

    2008-07-01

    Biodiesel can be used alone (B100) or blended with petroleum diesel in any proportion. The most popular biodiesel blend in the U.S.A. is B20 (20% biodiesel, 80% diesel fuel), which can be used for Energy Policy Act of 1992 (EPAct) compliance. In the European Union, the use of biofuel blends is recommended and was introduced by federal regulations in several countries. In Germany, biodiesel is currently blended as B5 (5% biodiesel) to common diesel fuel. In 2008, B7 plus three percent hydrotreated vegetable oil (HVO) as well is intended to become mandatory in Germany. To investigate the influence of blends on the emissions and possible health effects, we performed a series of studies with several engines (Euro 0, III and IV) measuring regulated and non-regulated exhaust compounds and determining their mutagenic effects. Emissions of blends showed an approximate linear dependence on the blend composition, in particular when regulated emissions are considered. However, a negative effect of blends was observed with respect to mutagenicity of the exhaust gas emissions. In detail, a maximum of the mutagenic potency was found in the range of B20. From this point of view, B20 must be considered as a critical blend, in case diesel fuel and biodiesel are used as binary mixtures. (author)

  14. Degradation behavior of polymer blend of isotactic polypropylenes with and without unsaturated chain end group

    International Nuclear Information System (INIS)

    Nakatani, Hisayuki; Kurniawan, Dodik; Taniike, Toshiaki; Terano, Minoru

    2008-01-01

    In this work, the relationship between the unsaturated chain end group content and the thermal oxidative degradation rate was systematically studied with binary polymer blends of isotactic polypropylene (iPP) with and without the unsaturated chain end group. The iPPs with and without the unsaturated chain end group were synthesized by a metallocene catalyst in the absence of hydrogen and by a Ziegler catalyst in the presence of one, respectively. The thermal oxidative degradation rate of the binary iPP blends was estimated from the molecular weight and the apparent activation energy (ΔE), which were obtained through size exclusion chromatography (SEC) and thermogravimetric analysis (TGA) measurements, respectively. These values exhibited a negative correlation against the mole content of the unsaturated chain end group. The thermal oxidative degradation rate apparently depends on the content of the unsaturated chain end group. This tendency suggests that the unsaturated chain end acts as a radical initiator of the iPP degradation reaction.

  15. Chain confinement, phase transitions, and lamellar structure in semicrystalline polymers, polymer blends and polymer nanocomposites

    Science.gov (United States)

    Chen, Huipeng

    Recent studies suggest that there are three phase fractions in semicrystalline polymers, the crystalline, the mobile amorphous and the rigid amorphous phases. Due to the distinct properties of the rigid amorphous fraction, RAF, it has been investigated for more than twenty years. In this thesis, a general method using quasi-isothermal temperature-modulated differential scaning calorimetry, DSC, is provided for the first time to obtain the temperature dependent RAF and the other two fractions, crystalline fraction and mobile amorphous fraction, MAF. For poly(ethylene terephthalate), PET, our results show RAF was vitrified during quasi-isothermal cooling after crystallization had been completed and became totally devitrified during quasi-isothermal heating before the start of melting. Several years after people initially discovered the existence of RAF, another issue arose relating to the physical location of RAF and mobile amorphous fraction, MAF, within a lamellar stack model. Two very different models to describe the location of RAF were proposed. In the Heterogeneous Stack Model, HET, RAF is located outside the lamellar stacks. In the Homogeneous Stack Model, HSM, RAF was located inside the lamellar stacks. To determine the lamellar structure of semicrystalline polymers comprising three phase, a general method is given in this thesis by using a combination of the DSC and small angle X-ray scattering, SAXS techniques. It has been applied to Nylon 6, isotactic polystyrene, iPS, and PET. It was found for all of these materials, the HSM model is correct to describe the lamellar structure. In addition to the determination of lamellar structures, this method can also provide the exact fraction of MAF inside and outside lamellar stacks for binary polymer blends. For binary polymer blends, MAF, normally is located partially inside and partially outside the lamellar stacks. However, the quantification of the MAF inside and outside the lamellar stacks has now been provided

  16. Alguses oli Arvo Pärdi muusika ja siis tulid Jalakas ja videokunstnikud / Tiiu Laks

    Index Scriptorium Estoniae

    Laks, Tiiu, 1984-

    2010-01-01

    Tõnu Kaljuste ja Peeter Jalaka lavastusest "Alguses oli", lavastuse aluseks Arvo Pärdi teosed "In Principio" ja "Miserere", 17. augustil Noblesse valukojas toimunud etendusest, muusikaline juht Tõnu Kaljuste

  17. A PRELIMINARY INVESTIGATION ON COMPARISON AND TRANSFORMATION OF SENTINEL-2 MSI AND LANDSAT 8 OLI

    Directory of Open Access Journals (Sweden)

    F. Chen

    2018-05-01

    Full Text Available A PRELIMINARY INVESTIGATION ON COMPARISON AND TRANSFORMATION OF SENTINEL-2 MSI AND LANDSAT 8 OLI Timely and accurate earth observation with short revisit interval is usually necessary, especially for emergency response. Currently, several new generation sensors provided with similar channel characteristics have been operated onboard different satellite platforms, including Sentinel-2 and Landsat 8. Joint use of the observations by different sensors offers an opportunity to meet the demands for emergency requirements. For example, through the combination of Landsat and Sentinel-2 data, the land can be observed every 2–3 days at medium spatial resolution. However, differences are expected in radiometric values (e.g., channel reflectance of the corresponding channels between two sensors. Spectral response function (SRF is taken as an important aspect of sensor settings. Accordingly, between-sensor differences due to SRFs variation need to be quantified and compensated. The comparison of SRFs shows difference (more or less in channel settings between Sentinel-2 Multi-Spectral Instrument (MSI and Landsat 8 Operational Land Imager (OLI. Effect of the difference in SRF on corresponding values between MSI and OLI was investigated, mainly in terms of channel reflectance and several derived spectral indices. Spectra samples from ASTER Spectral Library Version 2.0 and Hyperion data archives were used in obtaining channel reflectance simulation of MSI and OLI. Preliminary results show that MSI and OLI are well comparable in several channels with small relative discrepancy (< 5 %, including the Costal Aerosol channel, a NIR (855–875 nm channel, the SWIR channels, and the Cirrus channel. Meanwhile, for channels covering Blue, Green, Red, and NIR (785–900 nm, the between-sensor differences are significantly presented. Compared with the difference in reflectance of each individual channel, the difference in derived spectral index is more

  18. OlyMPUS - The Ontology-based Metadata Portal for Unified Semantics

    Science.gov (United States)

    Huffer, E.; Gleason, J. L.

    2015-12-01

    The Ontology-based Metadata Portal for Unified Semantics (OlyMPUS), funded by the NASA Earth Science Technology Office Advanced Information Systems Technology program, is an end-to-end system designed to support data consumers and data providers, enabling the latter to register their data sets and provision them with the semantically rich metadata that drives the Ontology-Driven Interactive Search Environment for Earth Sciences (ODISEES). OlyMPUS leverages the semantics and reasoning capabilities of ODISEES to provide data producers with a semi-automated interface for producing the semantically rich metadata needed to support ODISEES' data discovery and access services. It integrates the ODISEES metadata search system with multiple NASA data delivery tools to enable data consumers to create customized data sets for download to their computers, or for NASA Advanced Supercomputing (NAS) facility registered users, directly to NAS storage resources for access by applications running on NAS supercomputers. A core function of NASA's Earth Science Division is research and analysis that uses the full spectrum of data products available in NASA archives. Scientists need to perform complex analyses that identify correlations and non-obvious relationships across all types of Earth System phenomena. Comprehensive analytics are hindered, however, by the fact that many Earth science data products are disparate and hard to synthesize. Variations in how data are collected, processed, gridded, and stored, create challenges for data interoperability and synthesis, which are exacerbated by the sheer volume of available data. Robust, semantically rich metadata can support tools for data discovery and facilitate machine-to-machine transactions with services such as data subsetting, regridding, and reformatting. Such capabilities are critical to enabling the research activities integral to NASA's strategic plans. However, as metadata requirements increase and competing standards emerge

  19. Dynamic mechanical analysis of binary and ternary polymer blends based on nylon copolymer/EPDM rubber and EPM grafted maleic anhydride compatibilizer

    Directory of Open Access Journals (Sweden)

    2007-10-01

    Full Text Available The dynamic mechanical properties such as storage modulus, loss modulus and damping properties of blends of nylon copolymer (PA6,66 with ethylene propylene diene (EPDM rubber was investigated with special reference to the effect of blend ratio and compatibilisation over a temperature range –100°C to 150°C at different frequencies. The effect of change in the composition of the polymer blends on tanδ was studied to understand the extent of polymer miscibility and damping characteristics. The loss tangent curve of the blends exhibited two transition peaks, corresponding to the glass transition temperature (Tg of individual components indicating incompatibility of the blend systems. The morphology of the blends has been examined by using scanning electron microscopy. The Arrhenius relationship was used to calculate the activation energy for the glass transition of the blends. Finally, attempts have been made to compare the experimental data with theoretical models.

  20. Predicting the composition of red wine blends using an array of multicomponent Peptide-based sensors.

    Science.gov (United States)

    Ghanem, Eman; Hopfer, Helene; Navarro, Andrea; Ritzer, Maxwell S; Mahmood, Lina; Fredell, Morgan; Cubley, Ashley; Bolen, Jessica; Fattah, Rabia; Teasdale, Katherine; Lieu, Linh; Chua, Tedmund; Marini, Federico; Heymann, Hildegarde; Anslyn, Eric V

    2015-05-20

    Differential sensing using synthetic receptors as mimics of the mammalian senses of taste and smell is a powerful approach for the analysis of complex mixtures. Herein, we report on the effectiveness of a cross-reactive, supramolecular, peptide-based sensing array in differentiating and predicting the composition of red wine blends. Fifteen blends of Cabernet Sauvignon, Merlot and Cabernet Franc, in addition to the mono varietals, were used in this investigation. Linear Discriminant Analysis (LDA) showed a clear differentiation of blends based on tannin concentration and composition where certain mono varietals like Cabernet Sauvignon seemed to contribute less to the overall characteristics of the blend. Partial Least Squares (PLS) Regression and cross validation were used to build a predictive model for the responses of the receptors to eleven binary blends and the three mono varietals. The optimized model was later used to predict the percentage of each mono varietal in an independent test set composted of four tri-blends with a 15% average error. A partial least square regression model using the mouth-feel and taste descriptive sensory attributes of the wine blends revealed a strong correlation of the receptors to perceived astringency, which is indicative of selective binding to polyphenols in wine.

  1. Predicting the Composition of Red Wine Blends Using an Array of Multicomponent Peptide-Based Sensors

    Directory of Open Access Journals (Sweden)

    Eman Ghanem

    2015-05-01

    Full Text Available Differential sensing using synthetic receptors as mimics of the mammalian senses of taste and smell is a powerful approach for the analysis of complex mixtures. Herein, we report on the effectiveness of a cross-reactive, supramolecular, peptide-based sensing array in differentiating and predicting the composition of red wine blends. Fifteen blends of Cabernet Sauvignon, Merlot and Cabernet Franc, in addition to the mono varietals, were used in this investigation. Linear Discriminant Analysis (LDA showed a clear differentiation of blends based on tannin concentration and composition where certain mono varietals like Cabernet Sauvignon seemed to contribute less to the overall characteristics of the blend. Partial Least Squares (PLS Regression and cross validation were used to build a predictive model for the responses of the receptors to eleven binary blends and the three mono varietals. The optimized model was later used to predict the percentage of each mono varietal in an independent test set composted of four tri-blends with a 15% average error. A partial least square regression model using the mouth-feel and taste descriptive sensory attributes of the wine blends revealed a strong correlation of the receptors to perceived astringency, which is indicative of selective binding to polyphenols in wine.

  2. Topological and morphological analysis of gamma rays irradiated chitosan-poly (vinyl alcohol) blends using atomic force microscopy

    Science.gov (United States)

    Bhatt, Rinkesh; Bisen, D. S.; Bajpai, R.; Bajpai, A. K.

    2017-04-01

    In the present communication, binary blends of poly (vinyl alcohol) (PVA) and chitosan (CS) were prepared by solution cast method and the roughness parameters of PVA, native CS and CS-PVA blend films were determined using atomic force microscopy (AFM). Moreover, the changes in the morphology of the samples were also investigated after irradiation of gamma rays at absorbed dose of 1 Mrad and 10 Mrad for the scanning areas of 5×5 μm2, 10×10 μm2 and 20×20 μm2. Amplitude, statistical and spatial parameters, including line, 3D and 2D image profiles of the experimental surfaces were examined and compared to un-irradiated samples. For gamma irradiated CS-PVA blends the larger waviness over the surface was found as compared to un-irradiated CS-PVA blends but the values of average roughness for both the films were found almost same. The coefficient of skewness was positive for gamma irradiated CS-PVA blends which revealed the presence of more peaks than valleys on the blend surfaces.

  3. Influence of non-covalent modification of multiwalled carbon nanotubes on the crystallization behaviour of binary blends of polypropylene and polyamide 6.

    Science.gov (United States)

    Mukhopadhyay, Nabaneeta; Panwar, Ajay S; Kumar, Gulshan; Samajdar, I; Bhattacharyya, Arup R

    2015-02-14

    Blends of polypropylene (PP) and polyamide 6 (PA6) with multiwalled carbon nanotubes (MWNTs) were prepared using different processing strategies in a twin-screw micro-compounder. The effect of MWNTs on the crystallization behaviour of the PP phase and the PA6 phase of the blend has been investigated through non-isothermal crystallization studies by differential scanning calorimetric analysis. Furthermore, the effect of the addition of the compatibilizer (PP-g-MA) and the modification of MWNTs (m-MWNTs) with a non-covalent organic modifier (Li-salt of 6 amino hexanoic acid, Li-AHA) has also been studied in context to the crystallization behaviour of the PP and PA6 phase in the blend. The crystallization studies have indicated a significant increase in bulk crystallization temperature of the PP phase in the blend in the presence of MWNTs. Moreover, the formation of 'trans-lamellar crystalline' structure consisting of PA6 'trans-crystalline lamellae' on MWNTs surface was facilitated in the case of blends prepared via 'protocol 2' as compared to the corresponding blends prepared via 'protocol 1'. Wide angle X-ray diffraction analysis has showed the existence of a β-polymorph of the PP phase due to incorporation of the PA6 phase in the blend. Addition of MWNTs in the blends has facilitated further β-crystalline structure formation of the PP phase. In the presence of m-MWNTs, a higher β-fraction was observed in the PP phase as compared to the blend with pristine MWNTs. Addition of PP-g-MA has suppressed the β-phase formation in the PP phase in the blend. X-ray bulk texture analysis revealed that incorporation of PA6 as well as pristine/modified MWNTs has influenced the extent of orientation of the PP chains towards specific crystalline planes in various blend compositions of PP and PA6.

  4. Exciplex dynamics in a blend of π-conjugated polymers with electron donating and accepting properties: MDMO-PPV and PCNEPV

    NARCIS (Netherlands)

    Offermans, T.; Hal, van P.A.; Meskers, S.C.J.; Koetse, M.M.; Janssen, R.A.J.

    2005-01-01

    The photophysical properties of a solution processed blend of two semiconducting polymers with electron donating and electron accepting properties, respectively, as used in polymer photovoltaic devices have been investigated. We show that in the binary mixture of

  5. The blending and segregation of coal for the U.K. industrial market

    Energy Technology Data Exchange (ETDEWEB)

    McGlinchey, D.; Jones, M.G.; Marjanovic, P. [Glasgow Caledonian Univ. (United Kingdom). Dept. of Physical Sciences

    1999-09-01

    The two most common methods of 'blending' industrial coals is either by use of feeder belts discharging onto a central conveyor belt, or by a compartment hopper discharging onto a common belt. These two methodologies were shown to give very similar levels of variance in the proportioning of component coals, over a wide range of discharge conditions. Limited work suggested that belt sampling from the end of the belt gave similar results to the stopped belt and frame technique. The segregation found in heaps formed from binary mixtures of coals was quantified by various statistical methods. These results demonstrated that very high levels of segregation can be expected in almost any heap formed when material is discharged from the belt in either of the two 'blending' methods described above. This can reasonably be expected to be a major factor in the inconsistent supply of a specified blend to a consumer. (orig.)

  6. Ühendpartei Res Publica tiib oli häältekogumisel Isamaast pisut edukam

    Index Scriptorium Estoniae

    2007-01-01

    Ühenderakonna Res Publica tiiva kandidaadid said Riigikogu valimistel umbes tuhat häält rohkem kui Isamaaliidu tiiva kandidaadid, samas oli IRL-i valimisnimekirjas Res Publica tiiva kandidaate ka mõne inimese võrra rohkem. Isamaaliidu edukaimad hääletoojad

  7. Oriënterend onderzoek naar de mogelijkheid om met behulp van NIRS het gehalte aan olie en y-linoleenzuur in teunisbloemzaad te bepalen

    NARCIS (Netherlands)

    Munsteren, van A.J.; Frankhuizen, R.; Veen, van der N.G.

    1987-01-01

    Nagaan of met behulp van NIRS het gehalte aan olie en y-linoleenzuur in teunisbloemzaad voldoende nauwkeurig te bepalen is. Van 21 monsters teunisbloemzaad zijn met behulp van verschillende rekenmethoden correlatieberekeningen uitgevoerd tussen de chemisch bepaalde gehalten aan olie en

  8. Ternary Blend Composed of Two Organic Donors and One Acceptor for Active Layer of High-Performance Organic Solar Cells.

    Science.gov (United States)

    Lee, Jong Won; Choi, Yoon Suk; Ahn, Hyungju; Jo, Won Ho

    2016-05-04

    Ternary blends composed of two donor absorbers with complementary absorptions provide an opportunity to enhance the short-circuit current and thus the power conversion efficiency (PCE) of organic solar cells. In addition to complementary absorption of two donors, ternary blends may exhibit favorable morphology for high-performance solar cells when one chooses properly the donor pair. For this purpose, we develop a ternary blend with two donors (diketopyrrolopyrrole-based polymer (PTDPP2T) and small molecule ((TDPP)2Ph)) and one acceptor (PC71BM). The solar cell made of a ternary blend with 10 wt % (TDPP)2Ph exhibits higher PCE of 7.49% as compared with the solar cells with binary blends, PTDPP2T:PC71BM (6.58%) and (TDPP)2Ph:PC71BM (3.21%). The higher PCE of the ternary blend solar cell is attributed mainly to complementary absorption of two donors. However, a further increase in (TDPP)2Ph content in the ternary blend (>10 wt %) decreases the PCE. The ternary blend with 10 wt % (TDPP)2Ph exhibits well-developed morphology with narrow-sized fibrils while the blend with 15 wt % (TDPP)2Ph shows phase separation with large-sized domains, demonstrating that the phase morphology and compatibility of ternary blend are important factors to achieve a high-performance solar cell made of ternary blends.

  9. Studies of PVC/ENR blends: blend compositions

    International Nuclear Information System (INIS)

    Chantara Thevy Ratnam; Khairul Zaman Mohd Dahlan; Nasir, M.; Baharin, A.

    2002-01-01

    Blends of poly(vinyl chloride/epoxidized natural rubber (PVC/ENR) were prepared by using Bra bender Plasticorder at compositions ranging from 0-100% PVC. They were blended at 150 degree C mixing temperature, 50 rpm rotor speed and 10 minutes mixing time. The blends were characterized for tensile strength , elongation at break, glass transition temperatures and Fourier transform infra red spectroscopy (FTIR). Results revealed that as the PVC content increases the blend behaviour changes from elastomeric to glassy. However the blends found to be compatible at all compositions. (Author)

  10. Phase boundary in compatible and incompatible polymer blends studied by micro indentation test and microscopic observations

    International Nuclear Information System (INIS)

    Mina, M. F.; Akhtar, F.; Haque, M.E.

    2003-10-01

    The phase boundary of incompatible polymer blends such as poly (methyl methacrylate) (PMMA)/natural rubber (NR) and polyestyrene (PS)/NR as well as compatible blends such as PMMA/NR/epoxidizer NR (compatibilizer) and PS/NR/styrene-butadiene-styrene (SBS) block copolymer (compatibilizer) was studied by means of microhardness (H) technique and microscopy. Solution grown films of neat PMMA, PS and blended films of PMMA/NR, PS/NR, PMMA/NR/ENR and PS/NR/SBS were cast using a common solvent (toluene). While the neat PMMA and PS provide constant hardness values of 178 and 173 MPa, respectively, the binary (incompatible) and the ternary (compatible) blends show a conspicuous H-decrease (PMMA/NR=140 MPa, PS/NR=167 MPa, PMMA/NR/ENR=109 MPa and PS/NR/SBS=127 MPa). Scanning electron microscopy and optical microscopy reveal clear difference of the phase boundary of compatible (smooth boundary) and incompatible (sharp boundary) blends. Besides, the compatibilizer blends are characterised by the thinnest phase boundary (30 μm), which is found about 60 μm in the incompatible blends, showing a final hardness value that demonstrates the compatibilizer to be smoothly distributed in the interface between the two blend components. Results highlight that microindentation technique, in combination with microscopic observations, is a sensitive tool for studying the breadth and quality of the interphase boundary in non- or compatibilized polymer blends and other inhomogeneous materials. (author)

  11. Application of a radioactive sourced semi portable X-ray spectrometer to the solution of binary mix compositions

    International Nuclear Information System (INIS)

    Butcher, B.M.

    1988-01-01

    In many cases it is far more economically viable to transport individual constituents to a blending plant and produce a series of custom made products than to manufacture at site. This situation exists in many heavy chemical industries or on large building sites. In the cement industry inter-mixed or interground blends containing slag, fly ash, or limestone are produced. These mixes are designed to enhance certain physical properties and to reduce costs. This paper summarises experience of the application of portable isotope source X-ray analysers in achieving quality control of binary mixes

  12. Interstitial micelles in binary blends of A B A triblock copolymers and homopolymers

    Science.gov (United States)

    Wołoszczuk, S.; Banaszak, M.

    2018-01-01

    We investigate triblock-homopolymer blends of types A1BA2/A and A1BA2/B, using a lattice Monte Carlo method. While the simulated triblock chains are compositionally symmetric in terms of the A-to-B volume ratio, the A1 block is significantly shorter than the A2 block. For the pure A1BA2 melt and the A1BA2 solutions in selective solvent the phase behavior is relatively well known, including existence and stability of the interstitial micelles which were discovered in previous Monte Carlo simulations. In this paper we study the stability of the interstitial micelles as a function of triblock volume fraction in selective homopolymers of either type A or type B, using two significantly different homopolymer chain lengths. We found that adding selective homopolymer of type A shifts the stability of the interstitial micelles into significantly higher temperatures. We also obtained, via self-assembly, intriguing new nanostructures which can be identified as ordered truncated octahedra. Finally, we established that the phase behavior of the triblock-homopolymer blends depends relatively weakly on the chain length of the added homopolymer.

  13. Observations of crystallization and melting in poly(ethylene oxide)/poly(methyl methacrylate) blends by hot-stage atomic-force microscopy

    NARCIS (Netherlands)

    Pearce, R.; Vancso, Gyula J.

    1998-01-01

    The binary blend of poly(ethylene oxide)/atactic poly(methyl methacrylate) is examined using hot-stage atomic-force microscopy (AFM) in conjunction with differential scanning calorimetry and optical microscopy. It was found possible to follow in real time the melting process, which reveals itself to

  14. Strategies for cell manipulation and skeletal tissue engineering using high-throughput polymer blend formulation and microarray techniques.

    Science.gov (United States)

    Khan, Ferdous; Tare, Rahul S; Kanczler, Janos M; Oreffo, Richard O C; Bradley, Mark

    2010-03-01

    A combination of high-throughput material formulation and microarray techniques were synergistically applied for the efficient analysis of the biological functionality of 135 binary polymer blends. This allowed the identification of cell-compatible biopolymers permissive for human skeletal stem cell growth in both in vitro and in vivo applications. The blended polymeric materials were developed from commercially available, inexpensive and well characterised biodegradable polymers, which on their own lacked both the structural requirements of a scaffold material and, critically, the ability to facilitate cell growth. Blends identified here proved excellent templates for cell attachment, and in addition, a number of blends displayed remarkable bone-like architecture and facilitated bone regeneration by providing 3D biomimetic scaffolds for skeletal cell growth and osteogenic differentiation. This study demonstrates a unique strategy to generate and identify innovative materials with widespread application in cell biology as well as offering a new reparative platform strategy applicable to skeletal tissues. Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  15. LDPE/PHB blends filled with castor oil cake

    Science.gov (United States)

    Burlein, Gustavo A.; Rocha, Marisa C. G.

    2015-05-01

    The response surface methodology (RSM) is a collection of mathematical techniques useful for developing, improving and optimizing process. In this study, RSM technique was applied to evaluate the effect of the components proportion on the mechanical properties of low density polyethylene (LDPE)/ poly (3-hydroxy-butyrate) (PHB) blends filled with castor oil cake (CC). The blends were prepared by melt mixing in a twin screw extruder. Low density polyethylene, poly (3-hydroxy-butyrate) and castor oil pressed cake were represented by the input variables designated as LDPE, PHB and CC, respectively. As it was desirable to consider the largest LDPE content in the ternary system, the components of the mixture were subjected to the following constraints: 0.7 ≤ LDPE ≤ 1.0, 0≤ PHB≤0.3 e 0 ≤ CC ≤0.3. The mechanical properties of the different mixtures were determined by conventional ASTM tests and were evaluated through analysis of variance performed by the Minitab software. Some polynomial equations were tested in order to describe the mechanical behavior of the samples. The quadratic model in pseudo components was selected for describing the tensile behavior because it was the most efficient from a statistical point of view (p-value ≤ 0.05; coefficient of determination (r2) close to 1 and variation inflation factor (VIF) values PHB or CC. The tensile strength values of binary mixtures of LDPE lie in the range from 8.9 to 10 MPa. As some commercial grades of LDPE have mechanical strength in this range, it may be inferred that the addition of a certain amount of PHB or CC to LDPE may be considered as a possibility for obtaining LDPE based materials with increased susceptibility to biodegradation. The cubic model in pseudo components was selected for describe the flexural strength of the samples because it was the most adequate from a statistical point of view. However, the linear model in pseudo components was the most efficient to describe the flexural modulus

  16. Landsat-8/OLI images has the potential to estimate the CDOM absorption coefficient in tropical inland water

    Science.gov (United States)

    Alcantara, E.; Bernardo, N.

    2016-12-01

    Colored dissolved organic matter (CDOM) is the most abundant dissolved organic matter (DOM) in many natural waters and can affect the water quality, such as the light penetration and the thermal properties of water system. So the objective of this letter was to estimate the colored dissolved organic matter (CDOM) absorption coefficient at 440 nm, aCDOM(440), in Barra Bonita Reservoir (São Paulo State, Brazil) using OLI/Landsat-8 images. For this two field campaigns were conducted in May and October 2014. During the field campaigns remote sensing reflectance (Rrs) were measured using a TriOS hyperspectral radiometer. Water samples were collected and analyzed to obtain the aCDOM(440). To predict the aCDOM(440) from Rrs at two key wavelengths (650 and 480 nm) were regressed against laboratory derived aCDOM(440) values. The validation using in situ data of aCDOM(440) algorithm indicated a goodness of fit, R2 = 0.70, with a root-mean-square error (RMSE) of 10.65%. The developed algorithm was applied to the OLI/Lansat-8 images. Distribution maps were created with OLI/Landsat-8 images based on the adjusted algorithm.

  17. Blend or not to blend: a study investigating faculty members perceptions of blended teaching

    Directory of Open Access Journals (Sweden)

    Mehmet A Ocak

    2010-12-01

    Full Text Available This study examined faculty members’ perceptions of blended teaching from several perspectives. A total of 73 faculty members in Turkish Higher Education context participated in the study by completing an online survey that combined quantitative and qualitative approaches. Based on a data analysis, the faculty members’ perceptions were sorted into six categories: (a satisfaction with blended teaching, (b perceived impact on the role of the faculty, (c perceived impact on student learning, (d perceived impact on student motivation, (e advantages of blended teaching, and (f disadvantages of blended teaching. Findings indicated that faculty members were likely to agree that blended teaching provides a high degree of satisfaction and that it requires more time and commitment from the faculty. The faculty members perceived that blended teaching improves student learning and, to some extent, improves motivation. The faculty members also emphasized the importance of institutional support and the use of technology to mitigate student problems. This study presents these faculty members’ perceptions, which are helpful for those planning to implement a blended teaching approach, and makes suggestions for trouble-shooting and taking advantage of the opportunities in a blended environment successfully.

  18. Equilibrating high-molecular-weight symmetric and miscible polymer blends with hierarchical back-mapping

    Science.gov (United States)

    Ohkuma, Takahiro; Kremer, Kurt; Daoulas, Kostas

    2018-05-01

    Understanding properties of polymer alloys with computer simulations frequently requires equilibration of samples comprised of microscopically described long molecules. We present the extension of an efficient hierarchical backmapping strategy, initially developed for homopolymer melts, to equilibrate high-molecular-weight binary blends. These mixtures present significant interest for practical applications and fundamental polymer physics. In our approach, the blend is coarse-grained into models representing polymers as chains of soft blobs. Each blob stands for a subchain with N b microscopic monomers. A hierarchy of blob-based models with different resolution is obtained by varying N b. First the model with the largest N b is used to obtain an equilibrated blend. This configuration is sequentially fine-grained, reinserting at each step the degrees of freedom of the next in the hierarchy blob-based model. Once the blob-based description is sufficiently detailed, the microscopic monomers are reinserted. The hard excluded volume is recovered through a push-off procedure and the sample is re-equilibrated with molecular dynamics (MD), requiring relaxation on the order of the entanglement time. For the initial method development we focus on miscible blends described on microscopic level through a generic bead-spring model, which reproduces hard excluded volume, strong covalent bonds, and realistic liquid density. The blended homopolymers are symmetric with respect to molecular architecture and liquid structure. To parameterize the blob-based models and validate equilibration of backmapped samples, we obtain reference data from independent hybrid simulations combining MD and identity exchange Monte Carlo moves, taking advantage of the symmetry of the blends. The potential of the backmapping strategy is demonstrated by equilibrating blend samples with different degree of miscibility, containing 500 chains with 1000 monomers each. Equilibration is verified by comparing

  19. Auto-Ignition of Iso-Stoichiometric Blends of Gasoline-Ethanol-Methanol (GEM) in SI, HCCI and CI Combustion Modes

    KAUST Repository

    Waqas, Muhammad

    2017-03-28

    Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol. A constant RON/HCCI fuel number/derived Research octane number property was observed in all three combustion modes for high RON fuels, but for low RON fuels, the iso-stoichiometric blending rule for constant octane number did not appear to be valid. The chemical composition and octane number of the base fuel also influenced the behavior of the GEM blends under different conditions.

  20. Auto-Ignition of Iso-Stoichiometric Blends of Gasoline-Ethanol-Methanol (GEM) in SI, HCCI and CI Combustion Modes

    KAUST Repository

    Waqas, Muhammad; Naser, Nimal; Sarathy, Mani; Feijs, Jeroen; Morganti, Kai; Nyrenstedt, Gustav; Johansson, Bengt

    2017-01-01

    Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol. A constant RON/HCCI fuel number/derived Research octane number property was observed in all three combustion modes for high RON fuels, but for low RON fuels, the iso-stoichiometric blending rule for constant octane number did not appear to be valid. The chemical composition and octane number of the base fuel also influenced the behavior of the GEM blends under different conditions.

  1. Strong increase of profits from oil and natural gas exploitation; Sterke stijging van opbrengsten uit olie- en gaswinning

    Energy Technology Data Exchange (ETDEWEB)

    Graveland, C.; Veldhuizen, E.; Schenau, S.; Van den Bergen, D. [Centraal Breau voor de Statistiek, Voorburg/Heerlen (Netherlands)

    2008-08-15

    The amount of oil and natural gas reserves in the Netherlands decreases, although the value of the reserves has increased considerably. The profits are used by the Dutch government in the form of so-called natural gas benefits. [Dutch] De omvang van de Nederlandse olie- en gasreserves daalt gestaag. Desondanks is de waarde van de resterende aardolie- en aardgasreserves flink toegenomen. Dit wordt grotendeels verklaard doordat de winning van olie en gas steeds meer opbrengt. De hogere opbrengsten komen vooral ten goede aan de overheid in de vorm van aardgasbaten, maar ook de winningsbedrijven profiteren er van.

  2. Effect of temperature gradient on liquid-liquid phase separation in a polyolefin blend.

    Science.gov (United States)

    Jiang, Hua; Dou, Nannan; Fan, Guoqiang; Yang, Zhaohui; Zhang, Xiaohua

    2013-09-28

    We have investigated experimentally the structure formation processes during phase separation via spinodal decomposition above and below the spinodal line in a binary polymer blend system exposed to in-plane stationary thermal gradients using phase contrast optical microscopy and temperature gradient hot stage. Below the spinodal line there is a coupling of concentration fluctuations and thermal gradient imposed by the temperature gradient hot stage. Also under the thermal gradient annealing phase-separated domains grow faster compared with the system under homogeneous temperature annealing on a zero-gradient or a conventional hot stage. We suggest that the in-plane thermal gradient accelerates phase separation through the enhancement in concentration fluctuations in the early and intermediate stages of spinodal decomposition. In a thermal gradient field, the strength of concentration fluctuation close to the critical point (above the spinodal line) is strong enough to induce phase separation even in one-phase regime of the phase diagram. In the presence of a temperature gradient the equilibrium phase diagrams are no longer valid, and the systems with an upper critical solution temperature can be quenched into phase separation by applying the stationary temperature gradient. The in-plane temperature gradient drives enhanced concentration fluctuations in a binary polymer blend system above and below the spinodal line.

  3. Evaluating the capability of Landsat 8 OLI and SPOT 6 for discriminating invasive alien species in the African Savanna landscape

    Science.gov (United States)

    Kganyago, Mahlatse; Odindi, John; Adjorlolo, Clement; Mhangara, Paidamoyo

    2018-05-01

    Globally, there is paucity of accurate information on the spatial distribution and patch sizes of Invasive Alien Plants (IAPs) species. Such information is needed to aid optimisation of control mechanisms to prevent further spread of IAPs and minimize their impacts. Recent studies have shown the capability of very high spatial (management. In this study medium and high resolution datasets from Landsat Operational Land Imager (OLI) and SPOT 6 sensors respectively, were evaluated for mapping the distribution and patch sizes of IAP, Parthenium hysterophorus in the savannah landscapes of KwaZulu-Natal, South Africa. Support Vector Machines (SVM) classifier was used for classification of both datasets. Results indicated that SPOT 6 had a higher overall accuracy (86%) than OLI (83%) in mapping P. hysterophorus. The study found larger distributions and patch sizes in OLI than in SPOT 6 as a result of possible P. hysterophorus expansion due to temporal differences between images and coarser pixels were insufficient to delineate gaps inside larger patches. On the other hand, SPOT 6 showed better capabilities of delineating gaps and boundaries of patches, hence had better estimates of distribution and patch sizes. Overall, the study showed that OLI may be suitable for mapping well-established patches for the purpose of large scale monitoring, while SPOT 6 can be used for mapping small patches and prioritising them for eradication to prevent further spread at a landscape scale.

  4. OGLE-2015-BLG-0479LA,B: BINARY GRAVITATIONAL MICROLENS CHARACTERIZED BY SIMULTANEOUS GROUND-BASED AND SPACE-BASED OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Han, C. [Department of Physics, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Udalski, A.; Szymański, M. K.; Soszyński, I.; Skowron, J.; Mróz, P.; Poleski, R. [Warsaw University Observatory, Al. Ujazdowskie 4, 00-478 Warszawa (Poland); Gould, A.; Zhu, Wei; Fausnaugh, M.; Gaudi, B. S.; Wibking, B. [Department of Astronomy, Ohio State University, 140 W. 18th Avenue, Columbus, OH 43210 (United States); Street, R. A. [School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); Yee, J. C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Beichman, C.; Novati, S. Calchi [NASA Exoplanet Science Institute, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Bryden, C.; Henderson, Calen B.; Shvartzvald, Y. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Carey, S. [Spitzer Science Center, MS 220-6, California Institute of Technology, Pasadena, CA (United States); Collaboration: (The Spitzer Microlensing Team; (The OGLE Collaboration; (The RoboNet collaboration; (The MiNDSTEp Consortium; (The μ FUN Collaboration; and others

    2016-09-01

    We present a combined analysis of the observations of the gravitational microlensing event OGLE-2015-BLG-0479 taken both from the ground and by the Spitzer Space Telescope . The light curves seen from the ground and from space exhibit a time offset of ∼13 days between the caustic spikes, indicating that the relative lens-source positions seen from the two places are displaced by parallax effects. From modeling the light curves, we measure the space-based microlens parallax. Combined with the angular Einstein radius measured by analyzing the caustic crossings, we determine the mass and distance of the lens. We find that the lens is a binary composed of two G-type stars with masses of ∼1.0 M {sub ⊙} and ∼0.9 M {sub ⊙} located at a distance of ∼3 kpc. In addition, we are able to constrain the complete orbital parameters of the lens thanks to the precise measurement of the microlens parallax derived from the joint analysis. In contrast to the binary event OGLE-2014-BLG-1050, which was also observed by Spitzer, we find that the interpretation of OGLE-2015-BLG-0479 does not suffer from the degeneracy between (±, ±) and (±, ∓) solutions, confirming that the four-fold parallax degeneracy in single-lens events collapses into the two-fold degeneracy for the general case of binary-lens events. The location of the blend in the color–magnitude diagram is consistent with the lens properties, suggesting that the blend is the lens itself. The blend is bright enough for spectroscopy and thus this possibility can be checked from future follow-up observations.

  5. Phase-Resolved Spectroscopy of the Low-Mass X-ray Binary V801 Ara

    Science.gov (United States)

    Brauer, Kaley; Vrtilek, Saeqa Dil; Peris, Charith; McCollough, Michael

    2018-06-01

    We present phase-resolved optical spectra of the low mass X-ray binary system V801 Ara. The spectra, obtained in 2014 with IMACS on the Magellan/Baade telescope at Las Campanas Observatory, cover the full binary orbit of 3.8 hours. They contain strong emission features allowing us to map the emission of Hα, Hβ, He II λ4686, and the Bowen blend at λ4640. The radial velocity curves of the Bowen blend shows significantly stronger modulation at the orbital period than Hα as expected for the former originating on the secondary with the latter consistent with emission dominated by the disk. Our tomograms of Hα and Hβ are the most detailed studies of these lines for V801 to date and they clearly detect the accretion disk. The Hβ emission extends to higher velocities than Hα, suggesting emission from closer to the neutron star and differentiating temperature variance in the accretion disk for the first time. The center of the accretion disk appears offset from the center-of-mass of the neutron star as has been seen in several other X-ray binaries. This is often interpreted to imply disk eccentricity. Our tomograms do not show strong evidence for a hot spot at the point where the accretion stream hits the disk. This could imply a reduced accretion rate or could be due to the spot being drowned out by bright accretion flow around it. There is enhanced emission further along the disk, however, which implies gas stream interaction downstream of the hot spot.

  6. Topology and Shape Control for Assemblies of Block Copolymer Blends in Solution

    KAUST Repository

    Moreno Chaparro, Nicolas; Nunes, Suzana Pereira; Peinemann, Klaus-Viktor; Calo, Victor M.

    2015-01-01

    We study binary blends of asymmetric diblock copolymers (AB/AC) in selective solvents with a mesoscale model. We investigate the morphological transitions induced by the concentration of the AC block copolymer and the difference in molecular weight between the AB and AC copolymers, when segments B and C exhibit hydrogen-bonding interactions. To the best of our knowledge, this is the first work modeling mixtures of block copolymers with large differences in molecular weight. The coassembly mechanism localizes the AC molecules at the interface of A and B domains and induces the swelling of the B-rich domains. The coil size of the large molecular weight block copolymer depends only on the concentration of the short block copolymer (AC or AB), regardless of the B–C interactions. However, the B–C interactions control the morphological transitions that occur in these blends.

  7. Topology and Shape Control for Assemblies of Block Copolymer Blends in Solution

    KAUST Repository

    Moreno Chaparro, Nicolas

    2015-10-27

    We study binary blends of asymmetric diblock copolymers (AB/AC) in selective solvents with a mesoscale model. We investigate the morphological transitions induced by the concentration of the AC block copolymer and the difference in molecular weight between the AB and AC copolymers, when segments B and C exhibit hydrogen-bonding interactions. To the best of our knowledge, this is the first work modeling mixtures of block copolymers with large differences in molecular weight. The coassembly mechanism localizes the AC molecules at the interface of A and B domains and induces the swelling of the B-rich domains. The coil size of the large molecular weight block copolymer depends only on the concentration of the short block copolymer (AC or AB), regardless of the B–C interactions. However, the B–C interactions control the morphological transitions that occur in these blends.

  8. Predicted bond length variation in wurtzite and zinc-blende InGaN and AlGaN alloys

    International Nuclear Information System (INIS)

    Mattila, T.; Zunger, A.

    1999-01-01

    Valence force field simulations utilizing large supercells are used to investigate the bond lengths in wurtzite and zinc-blende In x Ga 1-x N and Al x Ga 1-x N random alloys. We find that (i) while the first-neighbor cation endash anion shell is split into two distinct values in both wurtzite and zinc-blende alloys (R Ga-N 1 ≠R In-N 1 ), the second-neighbor cation endash anion bonds are equal (R Ga-N 2 =R In-N 2 ). (ii) The second-neighbor cation endash anion bonds exhibit a crucial difference between wurtzite and zinc-blende binary structures: in wurtzite we find two bond distances which differ in length by 13% while in the zinc-blende structure there is only one bond length. This splitting is preserved in the alloy, and acts as a fingerprint, distinguishing the wurtzite from the zinc-blende structure. (iii) The small splitting of the first-neighbor cation endash anion bonds in the wurtzite structure due to nonideal c/a ratio is preserved in the alloy, but is obscured by the bond length broadening. (iv) The cation endash cation bond lengths exhibit three distinct values in the alloy (Ga endash Ga, Ga endash In, and In endash In), while the anion endash anion bonds are split into two values corresponding to N endash Ga endash N and N endash In endash N. (v) The cation endash related splitting of the bonds and alloy broadening are considerably larger in InGaN alloy than in AlGaN alloy due to larger mismatch between the binary compounds. (vi) The calculated first-neighbor cation endash anion and cation endash cation bond lengths in In x Ga 1-x N alloy are in good agreement with the available experimental data. The remaining bond lengths are provided as predictions. In particular, the predicted splitting for the second-neighbor cation endash anion bonds in the wurtzite structure awaits experimental testing. copyright 1999 American Institute of Physics

  9. Study of component distribution in pharmaceutical binary powder mixtures by near infrared chemical imaging

    Directory of Open Access Journals (Sweden)

    Manel Bautista

    2012-12-01

    Full Text Available Near infrared chemical imaging (NIR-CI has recently emerged as an effective technique for extracting spatial information from pharmaceutical products in an expeditious, non-destructive and non-invasive manner. These features have turned it into a useful tool for controlling various steps in drug production processes. Imaging techniques provide a vast amount of both spatial and spectral information that can be acquired in a very short time. Such a huge amount of data requires the use of efficient and fast methods to extract the relevant information. Chemometric methods have proved especially useful for this purpose. In this study, we assessed the usefulness of the correlation coefficient (CC between the spectra of samples, the pure spectra of the active pharmaceutical ingredient (API and we assessed the excipients to check for correct ingredient distribution in pharmaceutical binary preparations blended in the laboratory. Visual information about pharmaceutical component distribution can be obtained by using the CC. The performance of this model construction methodology for binary samples was compared with other various common multivariate methods including partial least squares, multivariate curve resolution and classical least squares. Based on the results, correlation coefficients are a powerful tool for the rapid assessment of correct component distribution and for quantitative analysis of pharmaceutical binary formulations. For samples of three or more components it has been shown that if the objective is only to determine uniformity of blending, then the CC image map is very good for this, and easy and fast to compute.

  10. Production and characterization of thermoplastic cassava starch, functionalized poly(lactic acid), and their reactive compatibilized blends

    Science.gov (United States)

    Detyothin, Sukeewan

    degree of grafted MA, and increasing MA content retarded the reduction of Mn during processing. However, the Mn of PLA-g-MA during storage decreased more rapidly with a high content of MA. TSE screw speed had an impact on the Mn with the maximum value predicted at 20 rpm. PLA-g-MA compounds differing in Mn and/or grafted MA content were used as reactive polymers with TPCS (to produce binary blends) and as reactive compatibilizers (to produce ternary blends of PLA/TPCS/PLA-g-MA) with TPCS content of 30 wt% using a TSE. As a result of maleation, PLA-g-MA had a higher grafted MA content with a lower Mn, and higher PI. The interaction of anhydride groups from PLA-g-MA and hydroxyl groups from TPCS was found by FTIR. The reactive binary blends exhibited a change in thermal stability, decrease of Tcc, the presence of double melting peaks, and an increase of the Tgs of glycerol and starch. The higher the grafted MA content and/or the higher Mn of the PLA- g-MA used, the better were the distribution and smaller the TPCS domains obtained in the blends. The highest elongation at break was achieved when 30 wt% TPCS was blended with 70 wt% of PLA having 0.1 wt% of grafted MA and Mn of PLA-g-MA with a 45 kDa. Finally, the optimum PLA-g-MA was determined by using the results from PLA-g-MA RSM design and the reactive blending.

  11. CONSOLIDATION AND COMPACTION OF POWDER MIXTURES .3. BINARY-MIXTURES OF DIFFERENT PARTICLE-SIZE FRACTIONS OF DIFFERENT TYPES OF CRYSTALLINE LACTOSE

    NARCIS (Netherlands)

    RIEPMA, KA; ZUURMAN, K; BOLHUIS, GK; DEBOER, AH; LERK, CF

    1992-01-01

    Tablets were compacted from a coarse fraction (250-315 mum), a fine fraction (32-45 mum) and from binary blends of a coarse and a fine fraction of different types of crystalline lactose. The results showed differences in consolidation and compaction between the granular lactose types, i.e.,

  12. Blended learning

    DEFF Research Database (Denmark)

    Dau, Susanne

    2016-01-01

    Blended Learning has been implemented, evaluated and researched for the last decades within different educational areas and levels. Blended learning has been coupled with different epistemological understandings and learning theories, but the fundamental character and dimensions of learning...... in blended learning are still insufficient. Moreover, blended learning is a misleading concept described as learning, despite the fact that it fundamentally is an instructional and didactic approach (Oliver & Trigwell, 2005) addressing the learning environment (Inglis, Palipoana, Trenhom & Ward, 2011......) instead of the learning processes behind. Much of the existing research within the field seems to miss this perspective. The consequence is a lack of acknowledgement of the driven forces behind the context and the instructional design limiting the knowledge foundation of learning in blended learning. Thus...

  13. Morphology in binary blends of poly(vinyl methyl ether) and epsilon-caprolactone-trimethylene carbonate diblock copolymer

    NARCIS (Netherlands)

    Luyten, MC; Bogels, EJF; vanEkenstein, GORA; tenBrinke, G; Bras, W; Komanschek, BE; Ryan, AJ

    The morphology of symmetric diblock copolymer of epsilon-caprolactone (PCL) and trimethylene carbonate (PTMC), in blends with poly(vinyl methyl ether) (PVME) is investigated with (modulated) differential scanning calorimetry (d.s.c.), time resolved small angle (SAXS) and wide angle (WAXS) X-ray

  14. Morphology in binary blends of poly(vinyl methyl ether) and ε-caprolactone-trimethylene carbonate diblock copolymer

    NARCIS (Netherlands)

    Luyten, M.C.; Bögels, E.J.F.; Alberda van Ekenstein, G.O.R.; Brinke, G. ten; Bras, W.; Komanschek, B.E.; Ryan, A.J.

    1997-01-01

    The morphology of symmetric diblock copolymer of ε-caprolactone (PCL) and trimethylene carbonate (PTMC), in blends with poly(vinyl methyl ether) (PVME) is investigated with (modulated) differential scanning calorimetry (d.s.c.), time resolved small angle (SAXS) and wide angle (WAXS) X-ray

  15. Reverse indentation size effects in gamma irradiated blood compatible blend films of chitosan-poly (vinyl alcohol) for possible medical applications

    Energy Technology Data Exchange (ETDEWEB)

    Bisen, D.S. [Department of Post Graduate Studies and Research in Physics, Rani Durgawati University, Jabalpur, M.P. 482002 (India); Bhatt, Rinkesh [Department of Physics, Global Engineering College, Jabalpur, M.P. 482001 (India); Bajpai, A.K., E-mail: akbmrl@yahoo.co.in [Department of Chemistry, Bose Memorial Research Lab., Govt. Auto. Model Science College, Jabalpur 482002, M.P. (India); Bajpai, R. [Department of Post Graduate Studies and Research in Physics, Rani Durgawati University, Jabalpur, M.P. 482002 (India); Katare, R. [Department of Physics, Government Model Science College, Jabalpur, M.P. 482001 (India)

    2017-02-01

    In the present work binary blends of polyvinyl alcohol (PVA) and chitosan (CS) were prepared by solution cast method and characterized by analytical methods like FTIR, XRD and SEM for seeking structural and morphological information. The blends were exposed to gamma radiation and evaluated for their improved mechanical strength. It was found that the tensile strength and microhardness increased after irradiation of CS-PVA films. Plastic effect due to absorption of water molecules and scissoring effect due to gamma irradiation were found to decrease the softness or increase the microhardness of the blends. Improved mechanical properties were attributed to intermolecular and intramolecular hydrogen bonds and adhesive nature of the blends also. The blends were also investigated for water intake behavior and in vitro blood compatibility property on the basis of certain in vitro tests like protein adsorption, haemolysis and blood clot formation on the un-irradiated and irradiated blend samples. The increased % swelling with time could be assigned to the fact that increasing water content facilitates the phase separation process within the blend which results in advancement in interstitial nano-void spaces which are occupied by water molecules. The blood compatibility results showed that when the amount of CS was varied from 0.5% to 2%, the amount of blood clot and percent haemolysis decreased while the protein adsorption increased with increasing CS content of the blend films. - Highlights: • Fully crosslinked blends of PVA and chitosan have been prepared. • Blends were irradiated with gamma radiations to enhance blood compatibility. • Mechanical properties were evaluated and effect of irradiation was examined. • The blood compatibility of blends was also determined.

  16. Reverse indentation size effects in gamma irradiated blood compatible blend films of chitosan-poly (vinyl alcohol) for possible medical applications

    International Nuclear Information System (INIS)

    Bisen, D.S.; Bhatt, Rinkesh; Bajpai, A.K.; Bajpai, R.; Katare, R.

    2017-01-01

    In the present work binary blends of polyvinyl alcohol (PVA) and chitosan (CS) were prepared by solution cast method and characterized by analytical methods like FTIR, XRD and SEM for seeking structural and morphological information. The blends were exposed to gamma radiation and evaluated for their improved mechanical strength. It was found that the tensile strength and microhardness increased after irradiation of CS-PVA films. Plastic effect due to absorption of water molecules and scissoring effect due to gamma irradiation were found to decrease the softness or increase the microhardness of the blends. Improved mechanical properties were attributed to intermolecular and intramolecular hydrogen bonds and adhesive nature of the blends also. The blends were also investigated for water intake behavior and in vitro blood compatibility property on the basis of certain in vitro tests like protein adsorption, haemolysis and blood clot formation on the un-irradiated and irradiated blend samples. The increased % swelling with time could be assigned to the fact that increasing water content facilitates the phase separation process within the blend which results in advancement in interstitial nano-void spaces which are occupied by water molecules. The blood compatibility results showed that when the amount of CS was varied from 0.5% to 2%, the amount of blood clot and percent haemolysis decreased while the protein adsorption increased with increasing CS content of the blend films. - Highlights: • Fully crosslinked blends of PVA and chitosan have been prepared. • Blends were irradiated with gamma radiations to enhance blood compatibility. • Mechanical properties were evaluated and effect of irradiation was examined. • The blood compatibility of blends was also determined.

  17. Performance, emission and combustion analysis of a compression ignition engine using biofuel blends

    Directory of Open Access Journals (Sweden)

    Ors Ilker

    2017-01-01

    Full Text Available This study aimed to investigate the effects on performance, emission, and combustion characteristics of adding biodiesel and bioethanol to diesel fuel. Diesel fuel and blend fuels were tested in a water-cooled compression ignition engine with direct injection. Test results showed that brake specific fuel consumption and volumetric efficiency increased by about 30.6% and 3.7%, respectively, with the addition of bioethanol to binary blend fuels. The results of the blend fuel’s combustion analysis were similar to the diesel fuel’s results. Bioethanol increased maximal in-cylinder pressure compared to biodiesel and diesel fuel at both 1400 rpm and 2800 rpm. Emissions of CO increased by an amount of about 80% for fuels containing a high level of bioethanol when compared to CO emissions for diesel fuel. Using biodiesel, NO emissions increased by an average of 31.3%, HC emissions decreased by an average of 39.25%, and smoke opacity decreased by an average of 6.5% when compared with diesel fuel. In addition, when using bioethanol, NO emissions and smoke opacity decreased by 55% and 17% on average, respectively, and HC emissions increased by an average of 53% compared with diesel fuel.

  18. Supporting School Leaders in Blended Learning with Blended Learning

    Science.gov (United States)

    Acree, Lauren; Gibson, Theresa; Mangum, Nancy; Wolf, Mary Ann; Kellogg, Shaun; Branon, Suzanne

    2017-01-01

    This study provides a mixed-methods case-study design evaluation of the Leadership in Blended Learning (LBL) program. The LBL program uses blended approaches, including face-to-face and online, to prepare school leaders to implement blended learning initiatives in their schools. This evaluation found that the program designers effectively…

  19. A Structural Study of the Pseudo-Binary Mercury Chalcogenide Alloy HgSe_{0.7}S_{0.3} at High Pressure

    CERN Document Server

    Kozlenko, D P; Ehm, L; Knorr, K; Hull, S; Shchennikov, V V; Voronin, V I

    2002-01-01

    The structure of the pseudo-binary mercury chalcogenide alloy HgSe_{0.7}S_{0.3} has been studied by means of X-ray and neutron powder diffraction at pressure up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal cinnabar structure was observed at P{\\sim}1 GPa. The obtained structural parameters were used for the analysis of the geometrical relationship between the zinc blende and the cinnabar phases. The zinc blende-cinnabar phase transition is discussed in the framework of Landau theory of the phase transitions. It was found that the possible order parameter for the structural transformation is the spontaneous strain e_{4}. This assignment agrees with previously observed high pressure behaviour of the elastic constants of other mercury chalcogenides.

  20. A structural study of the pseudo-binary mercury chalcogenide alloy HgSe0.7S0.3 at high pressure

    International Nuclear Information System (INIS)

    Kozlenko, D.P.; Savenko, B.N.; Ehm, L.; Knorr, K.; Hull, S.; Shchennikov, V.V.; Voronin, V.I.

    2002-01-01

    The structure of the pseudo-binary mercury chalcogenide alloy HgSe 0.7 S 0.3 has been studied by means of X-ray and neutron powder diffraction at pressure up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal cinnabar structure was observed at P∼1 GPa. The obtained structural parameters were used for the analysis of the geometrical relationship between the zinc blende and the cinnabar phases. The zinc blende-cinnabar phase transition is discussed in the framework of the Landau theory of phase transitions. It was found that the possible order parameter for the structural transformation is the spontaneous strain e 4 . This assignment agrees with previously observed high pressure behaviour of the elastic constants of other mercury chalcogenides

  1. Blended Learning

    OpenAIRE

    Bauerová, Andrea

    2013-01-01

    This thesis is focused on a new approach of education called blended learning. The history and developement of Blended Learning is described in the first part. Then the methods and tools of Blended Learning are evaluated and compared to the traditional methods of education. At the final part an efficient developement of the educational programs is emphasized.

  2. Rheological, mechanical and morphological properties of poly(methyl methacrylate/poly(ethylene terephthalate blend with dual reactive interfacial compatibilization

    Directory of Open Access Journals (Sweden)

    Juciklécia da Silva Reinaldo

    2015-10-01

    Full Text Available Abstract In this work, the rheological, mechanical and morphological behavior of immiscible blend poly (methyl methacrylate with elastomeric particles (PMMAelast and post-consumer poly (ethylene terephthalate (PET with and without the use of the interfacial compatibilizer poly (methyl methacrylate-co-glycidyl methacrylate-co-ethyl acrylate (MGE was studied. The significant increase in torque presented in rheological analyses has shown a indication of chemical reactions between the epoxy group of MGE with end groups of PET chains and also with the elastomeric phase of PMMAelast. The increased concentration of PET yielded an increase in maximum strength and elasticity modulus and a decrease in elongation at break. The PMMAelast/PET binary blend (50/50 wt% and PMMAelast/PET/MGE compatibilized blend (65/30/5 wt% showed pronounced results in elongation at break compared to PMMAelast, whereas, in the first results were due to the evidence of a co-continuous morphological structure and in the second, due to the efficiency of the dual reactive interfacial compatibilization of PMMAelast/PET blends. Scanning electron microscopy (SEM and transmission electron microscopy (TEM analyses showed that PMMAelast/PET/MGE blends exhibit complex phase morphology due to the presence of elastomeric particles in the PMMAelast copolymer and in the use of MGE terpolymer.

  3. Raimond Valgre noorem vend - kes ta oli? : Kuno-Enn Valgre (30.05.1918-02.03.1987) / Valdur Ohmann

    Index Scriptorium Estoniae

    Ohmann, Valdur, 1958-

    2011-01-01

    Vastukäivad andmed ärgitasid uurima, kes õigupoolest oli Valgre noorem vend. Kõige ehedamalt annab Enn Valgre sõjaaegse käekäigu edasi ülekuulamisprotokoll 11. novembrist 1944. Ülekuulamisprotokolli tekst

  4. Misturas binárias e ternárias de gorduras hidrogenadas e óleo de soja Binary and ternary blends of hydrogenated fats and soybean oil

    Directory of Open Access Journals (Sweden)

    Ilka Sumiyoshi SIMÕES

    1997-12-01

    interactions. Compared with traditional techniques, designed experimentation saves both time and resources, and identify "true"optimums. The designed strategy allows determination of effects of individual variables or interactions between them. The objective of this study was to investigate the interactions that occur in binary and ternary mixtures of two hydrogenated fats (FATGILL PF38 and FATGILL PF42 and soybean oil, by analyzing their physical and chemical properties. A ten-run designed was used, corresponding to 3 individual samples, 3 binary blends and 4 ternary blends. The samples were analysed for fatty acid composition, iodine and saponification values, softening and melting points, kinematic viscosity, hardness and consistency. A special cubic multiple regression model was applied to some analytical data. The results showed that the three components interactions were not significative. Hardness only depended on hydrogenated fat FATGILL PF42. In another way, viscosity was dependent on the three components and melting and softening points were dependent on hydrogenated fats. The negative coefficients for hardness showed an antagonic effect, typical of eutectic interactions of fats. Contour lines were indicated by triangular diagrams. A perfect mixing model was attested for viscosity and softening and melting points.

  5. Evaluation of combustion, performance, and emissions of optimum palm–coconut blend in turbocharged and non-turbocharged conditions of a diesel engine

    International Nuclear Information System (INIS)

    Arbab, M.I.; Varman, M.; Masjuki, H.H.; Kalam, M.A.; Imtenan, S.; Sajjad, H.; Rizwanul Fattah, I.M.

    2015-01-01

    Highlights: • Properties limitation of biodiesel has been overcome using multiple biodiesel blends. • New biodiesel was developed using biodiesel–biodiesel optimum blend. • Engine performance and emission was tested with the newly developed biodiesels. • New biodiesels showed better engine performance than other tested fuels. - Abstract: Fossil fuel depletion, global warming with rapid changes in climate, and increases in oil prices have motivated scientists to search for alternative fuel. Biodiesel can be an effective solution despite some limitations, such as poor fuel properties and engine performance. From this perspective, experiments were carried out to improve fuel properties and engine performance by using a binary blend of palm and coconut biodiesel at an optimized ratio. MATLAB optimization tool was used to determine this blend ratio. A new biodiesel was developed and represented by PC (optimum blend of palm and coconut biodiesel). Engine performance and emission were tested under a full load at variable speed condition by using a 20% blend of each biodiesel with petroleum diesel, and the results were compared with petroleum diesel under both turbocharged and non-turbocharged conditions. PC20 (blend of 20% PC biodiesel and 80% petroleum diesel) showed the highest engine power with lower brake-specific fuel consumption than the other tested fuels in the presence of a turbocharger. The emissions of PC20 were lower than those of all other tested fuels. The experimental analysis reveals that PC showed superior performance and emission over palm biodiesel blend

  6. Unmasking the hidden NGTS-3Ab: a hot Jupiter in an unresolved binary system

    Science.gov (United States)

    Günther, Maximilian N.; Queloz, Didier; Gillen, Edward; Delrez, Laetitia; Bouchy, François; McCormac, James; Smalley, Barry; Almleaky, Yaseen; Armstrong, David J.; Bayliss, Daniel; Burdanov, Artem; Burleigh, Matthew; Cabrera, Juan; Casewell, Sarah L.; Cooke, Benjamin F.; Csizmadia, Szilárd; Ducrot, Elsa; Eigmüller, Philipp; Erikson, Anders; Gänsicke, Boris T.; Gibson, Neale P.; Gillon, Michaël; Goad, Michael R.; Jehin, Emmanuël; Jenkins, James S.; Louden, Tom; Moyano, Maximiliano; Murray, Catriona; Pollacco, Don; Poppenhaeger, Katja; Rauer, Heike; Raynard, Liam; Smith, Alexis M. S.; Sohy, Sandrine; Thompson, Samantha J.; Udry, Stéphane; Watson, Christopher A.; West, Richard G.; Wheatley, Peter J.

    2018-05-01

    We present the discovery of NGTS-3Ab, a hot Jupiter found transiting the primary star of an unresolved binary system. We develop a joint analysis of multi-colour photometry, centroids, radial velocity (RV) cross-correlation function (CCF) profiles and their bisector inverse slopes (BIS) to disentangle this three-body system. Data from the Next Generation Transit Survey (NGTS), SPECULOOS and HARPS are analysed and modelled with our new BLENDFITTER software. We find that the binary consists of NGTS-3A (G6V-dwarf) and NGTS-3B (K1V-dwarf) at 5") and are prone to contamination by blended objects. With TESS on the horizon, it is pivotal for the candidate vetting to incorporate all available follow-up information from multi-colour photometry and RV CCF profiles.

  7. Relations between blended learning possibilities and teachers' approaches to blended learning

    DEFF Research Database (Denmark)

    Stenalt, Maria Hvid; Nielsen, Tobias Alsted; Bager-Elsborg, Anna

    Higher Education has embraced blended learning as a way of enhancing quality in teaching and helping students to learn. This presentation addresses relations between blended learning possiblities presented to teachers in a teacher training project and teachers’ approaches to blended learning. We...... suggest that in order to identify the level of impact of integrating technologies in teaching and learning, we need to understand the factors influencing approaches to design of courses for blended contexts. Participants in the teacher training project come from the Department of Law at Aarhus University......: • Optain locally-embedded knowledge about blended learning • Develop opportunities for law students to receive (more) feedback • Comply with strategic aims The results so far suggest that teachers provide a disciplinary perspective on the key dimensions of blended learning, which influences...

  8. Evaluation of Chitosan-Microcrystalline Cellulose Blends as Direct Compression Excipients

    Directory of Open Access Journals (Sweden)

    Emmanuel O. Olorunsola

    2017-01-01

    Full Text Available This study was aimed at evaluating chitosan-microcrystalline cellulose blends as direct compression excipients. Crab shell chitosan, α-lactose monohydrate, and microcrystalline cellulose powders were characterized. Blends of the microcrystalline cellulose and chitosan in ratios 9 : 1, 4 : 1, 2 : 1, and 1 : 1 as direct compression excipients were made to constitute 60% of metronidazole tablets. Similar tablets containing blends of the microcrystalline cellulose and α-lactose monohydrate as well as those containing pure microcrystalline cellulose were also produced. The compact density, tensile strength, porosity, disintegration time, and dissolution rate of tablets were determined. Chitosan had higher moisture content (7.66% and higher moisture sorption capacity (1.33% compared to microcrystalline cellulose and lactose. It also showed better flow properties (Carr’s index of 18.9% and Hausner’s ratio of 1.23. Compact density of tablets increased but tensile strength decreased with increase in the proportion of chitosan in the binary mixtures. In contrast to lactose, the disintegration time increased and the dissolution rate decreased with increase in the proportion of chitosan. This study has shown that chitosan promotes flowability of powder mix and rapid disintegration of tablet. However, incorporation of equal proportions of microcrystalline cellulose and chitosan leads to production of extended-release tablet. Therefore, chitosan promotes tablet disintegration at low concentration and enables extended-release at higher concentration.

  9. Blended Learning

    NARCIS (Netherlands)

    Van der Baaren, John

    2009-01-01

    Van der Baaren, J. (2009). Blended Learning. Presentation given at the Mini symposium 'Blended Learning the way to go?'. November, 5, 2009, The Hague, The Netherlands: Netherlands Defence Academy (NDLA).

  10. Radiometric Cross-Calibration of GAOFEN-1 Wfv Cameras with LANDSAT-8 Oli and Modis Sensors Based on Radiation and Geometry Matching

    Science.gov (United States)

    Li, J.; Wu, Z.; Wei, X.; Zhang, Y.; Feng, F.; Guo, F.

    2018-04-01

    Cross-calibration has the advantages of high precision, low resource requirements and simple implementation. It has been widely used in recent years. The four wide-field-of-view (WFV) cameras on-board Gaofen-1 satellite provide high spatial resolution and wide combined coverage (4 × 200 km) without onboard calibration. In this paper, the four-band radiometric cross-calibration coefficients of WFV1 camera were obtained based on radiation and geometry matching taking Landsat 8 OLI (Operational Land Imager) sensor as reference. Scale Invariant Feature Transform (SIFT) feature detection method and distance and included angle weighting method were introduced to correct misregistration of WFV-OLI image pair. The radiative transfer model was used to eliminate difference between OLI sensor and WFV1 camera through the spectral match factor (SMF). The near-infrared band of WFV1 camera encompasses water vapor absorption bands, thus a Look Up Table (LUT) for SMF varies from water vapor amount is established to estimate the water vapor effects. The surface synchronization experiment was designed to verify the reliability of the cross-calibration coefficients, which seem to perform better than the official coefficients claimed by the China Centre for Resources Satellite Data and Application (CCRSDA).

  11. Two Nucleolar Proteins, GDP1 and OLI2, Function As Ribosome Biogenesis Factors and Are Preferentially Involved in Promotion of Leaf Cell Proliferation without Strongly Affecting Leaf Adaxial–Abaxial Patterning in Arabidopsis thaliana

    Directory of Open Access Journals (Sweden)

    Koji Kojima

    2018-01-01

    Full Text Available Leaf abaxial–adaxial patterning is dependent on the mutual repression of leaf polarity genes expressed either adaxially or abaxially. In Arabidopsis thaliana, this process is strongly affected by mutations in ribosomal protein genes and in ribosome biogenesis genes in a sensitized genetic background, such as asymmetric leaves2 (as2. Most ribosome-related mutants by themselves do not show leaf abaxialization, and one of their typical phenotypes is the formation of pointed rather than rounded leaves. In this study, we characterized two ribosome-related mutants to understand how ribosome biogenesis is linked to several aspects of leaf development. Previously, we isolated oligocellula2 (oli2 which exhibits the pointed-leaf phenotype and has a cell proliferation defect. OLI2 encodes a homolog of Nop2 in Saccharomyces cerevisiae, a ribosome biogenesis factor involved in pre-60S subunit maturation. In this study, we found another pointed-leaf mutant that carries a mutation in a gene encoding an uncharacterized protein with a G-patch domain. Similar to oli2, this mutant, named g-patch domain protein1 (gdp1, has a reduced number of leaf cells. In addition, gdp1 oli2 double mutants showed a strong genetic interaction such that they synergistically impaired cell proliferation in leaves and produced markedly larger cells. On the other hand, they showed additive phenotypes when combined with several known ribosomal protein mutants. Furthermore, these mutants have a defect in pre-rRNA processing. GDP1 and OLI2 are strongly expressed in tissues with high cell proliferation activity, and GDP1-GFP and GFP-OLI2 are localized in the nucleolus. These results suggest that OLI2 and GDP1 are involved in ribosome biogenesis. We then examined the effects of gdp1 and oli2 on adaxial–abaxial patterning by crossing them with as2. Interestingly, neither gdp1 nor oli2 strongly enhanced the leaf polarity defect of as2. Similar results were obtained with as2 gdp1 oli2

  12. Study of lamellar structure and crystallization behavior of poly(butylene terephthalate (PBT) in PBT/ABS and PBT/ABS/MMA-GMA blends using DSC, SAXS and DMTA

    International Nuclear Information System (INIS)

    Mantovani, Gerson L.; Pessan, Luiz A.; Hage, Elias; Torriani, Iris L.

    2001-01-01

    The effects of processing conditions and blend composition in the crystallization behaviour and lamellar structure of poly(butylene terephthalate) (PBT) in blends with acrylonitrile-butadiene-styrene copolymer (ABS) were studied. Differential scanning calorimetry (DSC), small-angle X-ray scattering (SAXS) and dynamic mechanical thermal analysis (DMTA) were used to observe those effects. Addition of reactive acrylic compatibilizer to the PBT/ABS blends has promoted an increase in the heat of crystallization of the related blends. The Long Period (L), obtained from the peak in the Lorentz-corrected SAXS pattern, was used to observe the effect in the lamellar structure of PBT phase in the blends. The results were in good agreement with the calculated values from de correlation function and the values of L do not show a significant dependence with the PBT mass fraction, either in the binary blends (PBT/ABS) or in the compatibilized blends. A slight but clear increase of the long period (from 3 to 5 angstrom) is noted for the systems injection molded at 240 deg C when compared to the ones molded at 260 deg C, although PBT crystallinity in the blends does not change significantly with blend composition or processing conditions. DMTA curves show a slight shift in the temperature of the tan δ main peaks for both PBT and ABS phases in the compatibilized blends, thereby indicating changes in the degree of miscibility or interaction between phases of those blends. Changes in the compatibilized blends miscibility may be responsible by the effects in the crystallization behaviour and lamellar structure of the PBT/ABS blends. (author)

  13. Study of lamellar structure and crystallization behavior of poly(butylene terephthalate (PBT) in PBT/ABS and PBT/ABS/MMA-GMA blends using DSC, SAXS and DMTA

    Energy Technology Data Exchange (ETDEWEB)

    Mantovani, Gerson L.; Pessan, Luiz A.; Hage, Elias [Sao Carlos Univ., SP (Brazil). Dept. de Engenharia de Materiais]. E-mail: elias@power.ufscar.br; Plivelic, Tomas S. [Laboratorio Nacional de Luz Sincrotron (LNLS), Campinas, SP (Brazil); Torriani, Iris L. [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica Gleb Wataghin

    2001-07-01

    The effects of processing conditions and blend composition in the crystallization behaviour and lamellar structure of poly(butylene terephthalate) (PBT) in blends with acrylonitrile-butadiene-styrene copolymer (ABS) were studied. Differential scanning calorimetry (DSC), small-angle X-ray scattering (SAXS) and dynamic mechanical thermal analysis (DMTA) were used to observe those effects. Addition of reactive acrylic compatibilizer to the PBT/ABS blends has promoted an increase in the heat of crystallization of the related blends. The Long Period (L), obtained from the peak in the Lorentz-corrected SAXS pattern, was used to observe the effect in the lamellar structure of PBT phase in the blends. The results were in good agreement with the calculated values from de correlation function and the values of L do not show a significant dependence with the PBT mass fraction, either in the binary blends (PBT/ABS) or in the compatibilized blends. A slight but clear increase of the long period (from 3 to 5 angstrom) is noted for the systems injection molded at 240 deg C when compared to the ones molded at 260 deg C, although PBT crystallinity in the blends does not change significantly with blend composition or processing conditions. DMTA curves show a slight shift in the temperature of the tan {delta} main peaks for both PBT and ABS phases in the compatibilized blends, thereby indicating changes in the degree of miscibility or interaction between phases of those blends. Changes in the compatibilized blends miscibility may be responsible by the effects in the crystallization behaviour and lamellar structure of the PBT/ABS blends. (author)

  14. Polymer blends

    Energy Technology Data Exchange (ETDEWEB)

    Allen, Scott D.; Naik, Sanjeev

    2017-08-22

    The present invention provides, among other things, extruded blends of aliphatic polycarbonates and polyolefins. In one aspect, provided blends comprise aliphatic polycarbonates such as poly(propylene carbonate) and a lesser amount of a crystalline or semicrystalline polymer. In certain embodiments, provided blends are characterized in that they exhibit unexpected improvements in their elongation properties. In another aspect, the invention provides methods of making such materials and applications of the materials in applications such as the manufacture of consumer packaging materials.

  15. Interacting binaries

    International Nuclear Information System (INIS)

    Eggleton, P.P.; Pringle, J.E.

    1985-01-01

    This volume contains 15 review articles in the field of binary stars. The subjects reviewed span considerably, from the shortest period of interacting binaries to the longest, symbiotic stars. Also included are articles on Algols, X-ray binaries and Wolf-Rayet stars (single and binary). Contents: Preface. List of Participants. Activity of Contact Binary Systems. Wolf-Rayet Stars and Binarity. Symbiotic Stars. Massive X-ray Binaries. Stars that go Hump in the Night: The SU UMa Stars. Interacting Binaries - Summing Up

  16. Blended learning

    DEFF Research Database (Denmark)

    Staugaard, Hans Jørgen

    2012-01-01

    Forsøg på at indkredse begrebet blended learning i forbindelse med forberedelsen af projekt FlexVid.......Forsøg på at indkredse begrebet blended learning i forbindelse med forberedelsen af projekt FlexVid....

  17. The True Ultracool Binary Fraction Using Spectral Binaries

    Science.gov (United States)

    Bardalez Gagliuffi, Daniella; Burgasser, Adam J.; Schmidt, Sarah J.; Gagné, Jonathan; Faherty, Jacqueline K.; Cruz, Kelle; Gelino, Chris

    2018-01-01

    Brown dwarfs bridge the gap between stars and giant planets. While the essential mechanisms governing their formation are not well constrained, binary statistics are a direct outcome of the formation process, and thus provide a means to test formation theories. Observational constraints on the brown dwarf binary fraction place it at 10 ‑ 20%, dominated by imaging studies (85% of systems) with the most common separation at 4 AU. This coincides with the resolution limit of state-of-the-art imaging techniques, suggesting that the binary fraction is underestimated. We have developed a separation-independent method to identify and characterize tightly-separated (dwarfs as spectral binaries by identifying traces of methane in the spectra of late-M and early-L dwarfs. Imaging follow-up of 17 spectral binaries yielded 3 (18%) resolved systems, corroborating the observed binary fraction, but 5 (29%) known binaries were missed, reinforcing the hypothesis that the short-separation systems are undercounted. In order to find the true binary fraction of brown dwarfs, we have compiled a volume-limited, spectroscopic sample of M7-L5 dwarfs and searched for T dwarf companions. In the 25 pc volume, 4 candidates were found, three of which are already confirmed, leading to a spectral binary fraction of 0.95 ± 0.50%, albeit for a specific combination of spectral types. To extract the true binary fraction and determine the biases of the spectral binary method, we have produced a binary population simulation based on different assumptions of the mass function, age distribution, evolutionary models and mass ratio distribution. Applying the correction fraction resulting from this method to the observed spectral binary fraction yields a true binary fraction of 27 ± 4%, which is roughly within 1σ of the binary fraction obtained from high resolution imaging studies, radial velocity and astrometric monitoring. This method can be extended to identify giant planet companions to young brown

  18. Samenstelling van de vluchtige olie van Origanum vulgare L. ssp. vulgare gedurende de ontwikkeling van de plant

    NARCIS (Netherlands)

    Maarse, Henk

    1971-01-01

    INLEIDING EN DOEL VAN HET ONDERZOEK Vele onderzoekers hebben de laatste jaren de vorming van de verbindingen in vluchtige olien van planten bestudeerd door het bepalen van de verandering in de samenstelling van de vluchtige olie tijdens de groei van de plant. Lemli (68) wees als eerste op de

  19. A cloud shadow detection method combined with cloud height iteration and spectral analysis for Landsat 8 OLI data

    Science.gov (United States)

    Sun, Lin; Liu, Xinyan; Yang, Yikun; Chen, TingTing; Wang, Quan; Zhou, Xueying

    2018-04-01

    Although enhanced over prior Landsat instruments, Landsat 8 OLI can obtain very high cloud detection precisions, but for the detection of cloud shadows, it still faces great challenges. Geometry-based cloud shadow detection methods are considered the most effective and are being improved constantly. The Function of Mask (Fmask) cloud shadow detection method is one of the most representative geometry-based methods that has been used for cloud shadow detection with Landsat 8 OLI. However, the Fmask method estimates cloud height employing fixed temperature rates, which are highly uncertain, and errors of large area cloud shadow detection can be caused by errors in estimations of cloud height. This article improves the geometry-based cloud shadow detection method for Landsat OLI from the following two aspects. (1) Cloud height no longer depends on the brightness temperature of the thermal infrared band but uses a possible dynamic range from 200 m to 12,000 m. In this case, cloud shadow is not a specific location but a possible range. Further analysis was carried out in the possible range based on the spectrum to determine cloud shadow location. This effectively avoids the cloud shadow leakage caused by the error in the height determination of a cloud. (2) Object-based and pixel spectral analyses are combined to detect cloud shadows, which can realize cloud shadow detection from two aspects of target scale and pixel scale. Based on the analysis of the spectral differences between the cloud shadow and typical ground objects, the best cloud shadow detection bands of Landsat 8 OLI were determined. The combined use of spectrum and shape can effectively improve the detection precision of cloud shadows produced by thin clouds. Several cloud shadow detection experiments were carried out, and the results were verified by the results of artificial recognition. The results of these experiments indicated that this method can identify cloud shadows in different regions with correct

  20. D'Monte : rünnaku ajend oli koostöö Ameerikaga / Darryl D'Monte ; interv, Ülle Toode

    Index Scriptorium Estoniae

    D'Monte, Darryl

    2008-01-01

    India ajakirjanik vastab küsimustele, mis oli Mumbai terrorirünnaku poliitiline taust, kes olukorrast kasu lõikab, miks peaminister Manmohan Singh teatas esmalt, et rünnak tuli väljastpoolt ja mida peaks India valitsus probleemi lahendamiseks ette võtma

  1. A mathematical model for predicting glucose levels in critically-ill patients: the PIGnOLI model

    Directory of Open Access Journals (Sweden)

    Zhongheng Zhang

    2015-06-01

    Full Text Available Background and Objectives. Glycemic control is of paramount importance in the intensive care unit. Presently, several BG control algorithms have been developed for clinical trials, but they are mostly based on experts’ opinion and consensus. There are no validated models predicting how glucose levels will change after initiating of insulin infusion in critically ill patients. The study aimed to develop an equation for initial insulin dose setting.Methods. A large critical care database was employed for the study. Linear regression model fitting was employed. Retested blood glucose was used as the independent variable. Insulin rate was forced into the model. Multivariable fractional polynomials and interaction terms were used to explore the complex relationships among covariates. The overall fit of the model was examined by using residuals and adjusted R-squared values. Regression diagnostics were used to explore the influence of outliers on the model.Main Results. A total of 6,487 ICU admissions requiring insulin pump therapy were identified. The dataset was randomly split into two subsets at 7 to 3 ratio. The initial model comprised fractional polynomials and interactions terms. However, this model was not stable by excluding several outliers. I fitted a simple linear model without interaction. The selected prediction model (Predicting Glucose Levels in ICU, PIGnOLI included variables of initial blood glucose, insulin rate, PO volume, total parental nutrition, body mass index (BMI, lactate, congestive heart failure, renal failure, liver disease, time interval of BS recheck, dextrose rate. Insulin rate was significantly associated with blood glucose reduction (coefficient: −0.52, 95% CI [−1.03, −0.01]. The parsimonious model was well validated with the validation subset, with an adjusted R-squared value of 0.8259.Conclusion. The study developed the PIGnOLI model for the initial insulin dose setting. Furthermore, experimental study is

  2. Polystyrene/Hyperbranched Polyester Blends and Reactive Polystyrene/Hyperbranched Polyester Blends

    National Research Council Canada - National Science Library

    Mulkern, Thomas

    1999-01-01

    .... In this work, the incorporation of HBPs in thermoplastic blends was investigated. Several volume fractions of hydroxyl functionalized hyperbranched polyesters were melt blended with nonreactive polystyrene (PS...

  3. The population of single and binary white dwarfs of the Galactic bulge

    Science.gov (United States)

    Torres, S.; García-Berro, E.; Cojocaru, R.; Calamida, A.

    2018-05-01

    Recent Hubble Space Telescope observations have unveiled the white dwarf cooling sequence of the Galactic bulge. Although the degenerate sequence can be well fitted employing the most up-to-date theoretical cooling sequences, observations show a systematic excess of red objects that cannot be explained by the theoretical models of single carbon-oxygen white dwarfs of the appropriate masses. Here, we present a population synthesis study of the white dwarf cooling sequence of the Galactic bulge that takes into account the populations of both single white dwarfs and binary systems containing at least one white dwarf. These calculations incorporate state-of-the-art cooling sequences for white dwarfs with hydrogen-rich and hydrogen-deficient atmospheres, for both white dwarfs with carbon-oxygen and helium cores, and also take into account detailed prescriptions of the evolutionary history of binary systems. Our Monte Carlo simulator also incorporates all the known observational biases. This allows us to model with a high degree of realism the white dwarf population of the Galactic bulge. We find that the observed excess of red stars can be partially attributed to white dwarf plus main sequence binaries, and to cataclysmic variables or dwarf novae. Our best fit is obtained with a higher binary fraction and an initial mass function slope steeper than standard values, as well as with the inclusion of differential reddening and blending. Our results also show that the possible contribution of double degenerate systems or young and thick-discbulge stars is negligible.

  4. Monitoring water quality in a hypereutrophic reservoir using Landsat ETM+ and OLI sensors: how transferable are the water quality algorithms?

    Science.gov (United States)

    Deutsch, Eliza S; Alameddine, Ibrahim; El-Fadel, Mutasem

    2018-02-15

    The launch of the Landsat 8 in February 2013 extended the life of the Landsat program to over 40 years, increasing the value of using Landsat to monitor long-term changes in the water quality of small lakes and reservoirs, particularly in poorly monitored freshwater systems. Landsat-based water quality hindcasting often incorporate several Landsat sensors in an effort to increase the temporal range of observations; yet the transferability of water quality algorithms across sensors remains poorly examined. In this study, several empirical algorithms were developed to quantify chlorophyll-a, total suspended matter (TSM), and Secchi disk depth (SDD) from surface reflectance measured by Landsat 7 ETM+ and Landsat 8 OLI sensors. Sensor-specific multiple linear regression models were developed by correlating in situ water quality measurements collected from a semi-arid eutrophic reservoir with band ratios from Landsat ETM+ and OLI sensors, along with ancillary data (water temperature and seasonality) representing ecological patterns in algae growth. Overall, ETM+-based models outperformed (adjusted R 2 chlorophyll-a = 0.70, TSM = 0.81, SDD = 0.81) their OLI counterparts (adjusted R 2 chlorophyll-a = 0.50, TSM = 0.58, SDD = 0.63). Inter-sensor differences were most apparent for algorithms utilizing the Blue spectral band. The inclusion of water temperature and seasonality improved the power of TSM and SDD models.

  5. Half-metallicity and ferromagnetism of TcX (X=C, Si and Ge) in zinc blende structure

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yong [College of Science, Yanshan University, Qinhuangdao 066004 (China); Physics Department, Brock University, St. Catharines, ON, Canada L2S 3A1 (Canada); Xing, Yue [College of Science, Yanshan University, Qinhuangdao 066004 (China); Bose, S.K., E-mail: sbose@brocku.ca [Physics Department, Brock University, St. Catharines, ON, Canada L2S 3A1 (Canada); Zhao, Yong-Hong [Department of Physics, Sichuan Normal University, Chengdu 610068 (China)

    2013-02-15

    We report results of a first-principles density-functional study of three binary transition-metal compounds TcX (X=C, Si and Ge) in the hypothetical cubic zinc blende (ZB) structure. Our calculations are based on the full potential linear augmented plane wave (FP-LAPW) plus local orbitals method, together with generalized gradient approximation for the exchange-correlation potential. Half-metallic (HM) ferromagnetism is observed in these binary compounds for their optimized cell volumes. In the HM state, these compounds possess an integer magnetic moment (1.000{mu}{sub B}) per formula unit, which is one of the important characteristics of half-metallic ferromagnets (HMFs). The ferromagnetic (FM) state is found to be stable for ZB TcC, TcSi and TcGe against the nonmagnetic (NM) and antiferromagnetic (AFM) states. Calculations show that half-metallicity can be maintained for a wide range of lattice constants in these binary compounds. Density functional calculations of exchange interactions and the Curie temperatures reveal similar trends for the three compounds with respect to the lattice parameter. These compounds are compatible with the traditional semiconductors, and could be useful in spin-electronics and other applications. The most important aspect of this work is to explore the possibility of not only magnetism, but HM ferromagnetism in compounds involving NM elements and 4d transition element Tc. - Highlights: Black-Right-Pointing-Pointer We study magnetism of the compounds TcSi, TcC, and TcGe. Black-Right-Pointing-Pointer These compounds, with nonmagnetic constituents, are found to be ferromagnetic. Black-Right-Pointing-Pointer They show robust half-metallicity in zinc blende structure. Black-Right-Pointing-Pointer Estimated Curie temperatures suggest that synthesis of these compounds is worth pursuing.

  6. Learning to assign binary weights to binary descriptor

    Science.gov (United States)

    Huang, Zhoudi; Wei, Zhenzhong; Zhang, Guangjun

    2016-10-01

    Constructing robust binary local feature descriptors are receiving increasing interest due to their binary nature, which can enable fast processing while requiring significantly less memory than their floating-point competitors. To bridge the performance gap between the binary and floating-point descriptors without increasing the computational cost of computing and matching, optimal binary weights are learning to assign to binary descriptor for considering each bit might contribute differently to the distinctiveness and robustness. Technically, a large-scale regularized optimization method is applied to learn float weights for each bit of the binary descriptor. Furthermore, binary approximation for the float weights is performed by utilizing an efficient alternatively greedy strategy, which can significantly improve the discriminative power while preserve fast matching advantage. Extensive experimental results on two challenging datasets (Brown dataset and Oxford dataset) demonstrate the effectiveness and efficiency of the proposed method.

  7. Modification of HDPE by γ ray radiation in oxygen atmosphere and blend with PA6

    International Nuclear Information System (INIS)

    Ding Yunsheng; Shi Tiejun; Zhang Zhicheng; Hu Keliang

    2002-01-01

    A study on the oxidation of high density polyethylene (HDPE) by γ ray irradiation in oxygen atmosphere has been made. The influence of irradiated time on the oxidation has been investigated with the help of Fourier Transform Infrared-Photoacoustics Spectroscopy (FTIR-PAS). Results of FTIR-PAS show after irradiation groups like -C=O, -O-C-O-, O=C-O- were introduced into the HDPE. Although the γ ray has powerful penetrability, the oxidation mainly takes place on the surface of HDPE. after 4 h irradiation in oxygen (dose rate 66 Gy/min.), -C=O is the main group which was introduced into the surface of HDPE. Lengthening the irradiation process makes the pre-produced oxidized section in HDPE surface continue their reactions to yield some oxidation products with the structures of -O-C-O-, O=C-O- and so on. FTIR shows there are reactions or week interaction like hydrogen bond between the irradiated HDPE and PA6 in the binary blends, this is helpful to increase the compatibility of the phase of HDPE and polyamide-6 (PA6) in the blend. Scanning Electron Microscope (SEM) result shows that the interface between HDPE matrix and PA6 domains is much clear and smoother in 0γHDPE/PA6 blends than in 4γHDPE/PA6 and 7γHDPE/PA6 blends. These suggested the miscibility of PA6 and HDPE was improved after HDPE irradiating in oxygen by γ ray radiation

  8. Profiling Student Behaviour in a Blended Course: Closing the Gap Between Blended Teaching and Blended Learning

    NARCIS (Netherlands)

    Bos, Nynke; Brand-Gruwel, Saskia

    2018-01-01

    Blended learning is often associated with student-oriented learning in which students have varying degrees of control over their learning process. However, the current notion of blended learning is often a teacher- oriented approach in which the teacher identifies the used learning technologies and

  9. Binary Linear-Time Erasure Decoding for Non-Binary LDPC codes

    OpenAIRE

    Savin, Valentin

    2009-01-01

    In this paper, we first introduce the extended binary representation of non-binary codes, which corresponds to a covering graph of the bipartite graph associated with the non-binary code. Then we show that non-binary codewords correspond to binary codewords of the extended representation that further satisfy some simplex-constraint: that is, bits lying over the same symbol-node of the non-binary graph must form a codeword of a simplex code. Applied to the binary erasure channel, this descript...

  10. Effect of blending temperature on the mechanical properties of PVC/ENR blend upon irradiation

    International Nuclear Information System (INIS)

    Chantara Thevy Ratnam; Khairul Zaman Mohd Dahlan; Nasir, M.; Baharin, A.

    2000-01-01

    Poly (vinyl chloride) / epoxidized natural rubber blends were prepared with a Brabender plasticorder at 140, 150, 160, 170 and 180 degree C mixing temperatures. They were mixed at 50 rpm rotor speed for 10 min. The blends were irradiated with doses ranging from 0-200 kGy. Changes in tensile strength, modulus at 100% elongation, gel fraction and damping properties (tan δ) of the blends with increasing mixing temperatures and irradiation doses were investigated. In general, it was observed that the mixing temperature is important in maximizing the positive effect of irradiation. Results revealed that a readily miscible blend enjoy maximum benefit from irradiation meanwhile irradiation impart miscibility to a partially miscible PVC/ENR blend. The enhancement in blend properties is believed to be attributed by the irradiation-induced crosslinking along with irradiation-induced interaction between the polymers. The radiation-induced degradation found to be prominent at higher doses for blend that has undergone excessive thermal degradation. However evidence did not reveal the specific nature of radiation-induced reaction responsible for the improved interactions of the blends. (author)

  11. Four W Ursae Majoris contact binaries in the old galactic cluster NGC 188

    International Nuclear Information System (INIS)

    Baliunas, S.L.; Guinan, E.F.

    1984-01-01

    The authors calculated the cross-correlation coefficients between the spectra of the contact binaries and slowly-rotating template stars of approximately the same color in NGC 188 (stars I-32 and I-33). From the cross-correlation coefficients they measured the radial velocities of the W UMa stars near the expected phase of velocity crossing with respect to the two other cluster stars. The velocities of the W UMa systems are consistent with cluster membership. In three of the systems, the spectra were obtained at phases where individual stellar components were resolved. Two Gaussians were fit simultaneously to the most significant portion of the blended cross-correlation peaks. The mass ratios of these three systems were determined by assuming that the velocity of the center of mass is equal to the mean radial velocity of the two cluster reference stars. The mass ratios in these three systems suggest the binaries are similar to other short-period, field W UMa systems designated W-type

  12. Blending Words Found In Social Media

    Directory of Open Access Journals (Sweden)

    Giyatmi Giyatmi

    2017-12-01

    Full Text Available There are many new words from the social media such as Netizen, Trentop, and Delcon. Those words include in blending. Blending is one of word formations combining two clipped words to form a brand new word. The researchers are interested in analyzing blend words used in the social media such as Instagram, Twitter, Facebook, and Blackberry Messenger. This research aims at (1 finding blend words used in the social media (2 describing kinds of blend words used in social media (3 describing the process of blend word formation used in the social media. This research uses some theories dealing with definition of blending and kinds of blending. This research belongs to descriptive qualitative research. Data of the research are English blend words used in social media. Data sources of this research are websites consisting of some English words used in social media and some social media users as the informant. Techniques of data collecting in this research are observation and simak catat. Observation is by observing some websites consisting of some English words used in social media. Simak catat is done by taking some notes on the data and encoding in symbols such as No/Blend words/Kinds of Blending. The researchers use source triangulation to check the data from the researchers with the informant and theory triangulation to determine kinds of blending and blend word formation in social media. There are115 data of blend words. Those data consists of 65 data of Instagram, 47 data of Twitter, 1 datum of Facebook, and 2 data of Blackberry Messenger. There are 2 types of blending used in social media;108 data of blending with clipping and 7 data of blending with overlapping. There are 10 ways of blend word formation found in this research.

  13. Design Principles for the Blend in Blended Learning: A Collective Case Study

    Science.gov (United States)

    Lai, Ming; Lam, Kwok Man; Lim, Cher Ping

    2016-01-01

    This paper reports on a collective case study of three blended courses taught by different instructors in a higher education institution, with the purpose of identifying the different types of blend and how the blend supports student learning. Based on the instructors' and students' interviews, and document analysis of course outlines, two major…

  14. Comparison of hyperspectral transformation accuracies of multispectral Landsat TM, ETM+, OLI and EO-1 ALI images for detecting minerals in a geothermal prospect area

    Science.gov (United States)

    Hoang, Nguyen Tien; Koike, Katsuaki

    2018-03-01

    Hyperspectral remote sensing generally provides more detailed spectral information and greater accuracy than multispectral remote sensing for identification of surface materials. However, there have been no hyperspectral imagers that cover the entire Earth surface. This lack points to a need for producing pseudo-hyperspectral imagery by hyperspectral transformation from multispectral images. We have recently developed such a method, a Pseudo-Hyperspectral Image Transformation Algorithm (PHITA), which transforms Landsat 7 ETM+ images into pseudo-EO-1 Hyperion images using multiple linear regression models of ETM+ and Hyperion band reflectance data. This study extends the PHITA to transform TM, OLI, and EO-1 ALI sensor images into pseudo-Hyperion images. By choosing a part of the Fish Lake Valley geothermal prospect area in the western United States for study, the pseudo-Hyperion images produced from the TM, ETM+, OLI, and ALI images by PHITA were confirmed to be applicable to mineral mapping. Using a reference map as the truth, three main minerals (muscovite and chlorite mixture, opal, and calcite) were identified with high overall accuracies from the pseudo-images (> 95% and > 42% for excluding and including unclassified pixels, respectively). The highest accuracy was obtained from the ALI image, followed by ETM+, TM, and OLI images in descending order. The TM, OLI, and ALI images can be alternatives to ETM+ imagery for the hyperspectral transformation that aids the production of pseudo-Hyperion images for areas without high-quality ETM+ images because of scan line corrector failure, and for long-term global monitoring of land surfaces.

  15. Binary effectivity rules

    DEFF Research Database (Denmark)

    Keiding, Hans; Peleg, Bezalel

    2006-01-01

    is binary if it is rationalized by an acyclic binary relation. The foregoing result motivates our definition of a binary effectivity rule as the effectivity rule of some binary SCR. A binary SCR is regular if it satisfies unanimity, monotonicity, and independence of infeasible alternatives. A binary...

  16. Subpixel Inundation Mapping Using Landsat-8 OLI and UAV Data for a Wetland Region on the Zoige Plateau, China

    Directory of Open Access Journals (Sweden)

    Haoming Xia

    2017-01-01

    Full Text Available Wetland inundation is crucial to the survival and prosperity of fauna and flora communities in wetland ecosystems. Even small changes in surface inundation may result in a substantial impact on the wetland ecosystem characteristics and function. This study presented a novel method for wetland inundation mapping at a subpixel scale in a typical wetland region on the Zoige Plateau, northeast Tibetan Plateau, China, by combining use of an unmanned aerial vehicle (UAV and Landsat-8 Operational Land Imager (OLI data. A reference subpixel inundation percentage (SIP map at a Landsat-8 OLI 30 m pixel scale was first generated using high resolution UAV data (0.16 m. The reference SIP map and Landsat-8 OLI imagery were then used to develop SIP estimation models using three different retrieval methods (Linear spectral unmixing (LSU, Artificial neural networks (ANN, and Regression tree (RT. Based on observations from 2014, the estimation results indicated that the estimation model developed with RT method could provide the best fitting results for the mapping wetland SIP (R2 = 0.933, RMSE = 8.73% compared to the other two methods. The proposed model with RT method was validated with observations from 2013, and the estimated SIP was highly correlated with the reference SIP, with an R2 of 0.986 and an RMSE of 9.84%. This study highlighted the value of high resolution UAV data and globally and freely available Landsat data in combination with the developed approach for monitoring finely gradual inundation change patterns in wetland ecosystems.

  17. Blended acquisition with dispersed source arrays

    NARCIS (Netherlands)

    Berkhout, A.J.

    2012-01-01

    Blended source arrays are historically configured with equal source units, such as broadband vibrators (land) and broadband air-gun arrays (marine). I refer to this concept as homogeneous blending. I have proposed to extend the blending concept to inhomogeneous blending, meaning that a blended

  18. Blended Learning

    Science.gov (United States)

    Imbriale, Ryan

    2013-01-01

    Teachers always have been and always will be the essential element in the classroom. They can create magic inside four walls, but they have never been able to create learning environments outside the classroom like they can today, thanks to blended learning. Blended learning allows students and teachers to break free of the isolation of the…

  19. Apparatus for blending small particles

    International Nuclear Information System (INIS)

    Bradley, R.A.; Reese, C.R.; Sease, J.D.

    1975-01-01

    An apparatus is described for blending small particles and uniformly loading the blended particles in a receptacle. Measured volumes of various particles are simultaneously fed into a funnel to accomplish radial blending and then directed onto the apex of a conical splitter which collects the blended particles in a multiplicity of equal subvolumes. Thereafter the apparatus sequentially discharges the subvolumes for loading in a receptacle. A system for blending nuclear fuel particles and loading them into fuel rod molds is described in a preferred embodiment

  20. Contribution made by multivariate curve resolution applied to gel permeation chromatography-Fourier transform infrared data for an in-depth characterization of styrene-butadiene rubber blends.

    Science.gov (United States)

    Ruckebusch, C; Vilmin, F; Coste, N; Huvenne, J P

    2008-07-01

    We evaluate the contribution made by multivariate curve resolution-alternating least squares (MCR-ALS) for resolving gel permeation chromatography-Fourier transform infrared (GPC-FT-IR) data collected on butadiene rubber (BR) and styrene butadiene rubber (SBR) blends in order to access in-depth knowledge of polymers along the molecular weight distribution (MWD). In the BR-SBR case, individual polymers differ in chemical composition but share almost the same MWD. Principal component analysis (PCA) gives a general overview of the data structure and attests to the feasibility of modeling blends as a binary system. MCR-ALS is then performed. It allows resolving the chromatographic coelution and validates the chosen methodology. For SBR-SBR blends, the problem is more challenging since the individual elastomers present the same chemical composition. Rank deficiency is detected from the PCA data structure analysis. MCR-ALS is thus performed on column-wise augmented matrices. It brings very useful insight into the composition of the analyzed blends. In particular, a weak change in the composition of individual SBR in the MWD's lowest mass region is revealed.

  1. Radiation-modified blends of the basis of polyethylene terephthalate and polypropylene

    International Nuclear Information System (INIS)

    Mery-Meri, R.; Revyakin, O.; Zicans, J.

    2000-01-01

    The binary composite systems on the basis of post-consumer poly-(ethylene terephthalate) and polypropylene have been investigated. Mechanical properties of the compositions were studied in detail in order to expand the application possibilities of tested binary composites. Structural changes of the poly (ethylene terephthalate) / polypropylene blends depending on the concentration of the components were investigated also. Additionally, the optimum processing conditions were established. Particular attention was paid to study the influence of the ionizing γ-radiation on the structural and mechanical properties of the composition systems tested. The magnitude of the adsorbed dose od γ-radiation was established to affect differently the structure of poly(ethylene terephalate) and polypropylene. At small absorbed doses (50 kGy) crosslinking of the polymer was observed for both poly(ethylene terephthalate) and polypropylene resulting in the increase of some mechanical properties of pure materials as well of their compositions, whereas the absorbed dose of 300 kGy caused the destruction of the tested materials. It is important to mention that the rate of radiation-chemical destruction of polypropylene is higher than poly(ethylene terephthalate) destruction rate. (author)

  2. Phase Behavior of Diblock Copolymer–Homopolymer Ternary Blends: Congruent First-Order Lamellar–Disorder Transition

    Energy Technology Data Exchange (ETDEWEB)

    Hickey, Robert J.; Gillard, Timothy M.; Irwin, Matthew T.; Morse, David C.; Lodge, Timothy P.; Bates, Frank S. (UMM)

    2016-10-13

    We have established the existence of a line of congruent first-order lamellar-to-disorder (LAM–DIS) transitions when appropriate amounts of poly(cyclohexylethylene) (C) and poly(ethylene) (E) homopolymers are mixed with a corresponding compositionally symmetric CE diblock copolymer. The line of congruent transitions, or the congruent isopleth, terminates at the bicontinuous microemulsion (BμE) channel, and its trajectory appears to be influenced by the critical composition of the C/E binary homopolymer blend. Blends satisfying congruency undergo a direct LAM–DIS transition without passing through a two-phase region. We present complementary optical transmission, small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and dynamic mechanical spectroscopy (DMS) results that establish the phase behavior at constant copolymer volume fraction and varying C/E homopolymer volume ratios. Adjacent to the congruent composition at constant copolymer volume fraction, the lamellar and disordered phases are separated by two-phase coexistence windows, which converge, along with the line of congruent transitions, at an overall composition in the phase prism coincident with the BμE channel. Hexagonal and cubic (double gyroid) phases occur at higher diblock copolymer concentrations for asymmetric amounts of C and E homopolymers. These results establish a quantitative method for identifying the detailed phase behavior of ternary diblock copolymer–homopolymer blends, especially in the vicinity of the BμE.

  3. Investigation of diesel-ethanol blended fuel properties with palm methyl ester as co-solvent and blends enhancer

    Directory of Open Access Journals (Sweden)

    Mat Taib Norhidayah

    2017-01-01

    Full Text Available Diesel engine is known as the most efficient engine with high efficiency and power but always reported as high fuel emission. Malaysia National Automotive Policy (NAP was targeting to improve competitive regional focusing on green technology development in reducing the emission of the engine. Therefore, ethanol was introduced to reduce the emission of the engine and while increasing its performance, Palm methyl ester was introduced as blend enhancer to improve engine performance and improve diesel-ethanol blends stability. This paper aimed to study the characteristics of the blends and to prove the ability of palm-methyl-ester as co-solvent in ethanol-diesel blends. Stability and thermophysical test were carried out for different fuel compositions. The stability of diesel-ethanol blended was proved to be improved with the addition of PME at the longer period and the stability of the blends changed depending on temperature and ethanol content. Density and viscosity of diesel-ethanol-PME blends also give higher result than diesel-ethanol blends and it's proved that PME is able to increase density and viscosity of blends. Besides, heating value of the blends also increases with the increasing PME in diesel-ethanol blends.

  4. Largely enhanced dielectric properties of carbon nanotubes/polyvinylidene fluoride binary nanocomposites by loading a few boron nitride nanosheets

    International Nuclear Information System (INIS)

    Yang, Minhao; Zhao, Hang; He, Delong; Bai, Jinbo

    2016-01-01

    The ternary nanocomposites of boron nitride nanosheets (BNNSs)/carbon nanotubes (CNTs)/polyvinylidene fluoride (PVDF) are fabricated via a combination of solution casting and extrusion-injection processes. The effects of BNNSs on the electrical conductivity, dielectric behavior, and microstructure changes of CNTs/PVDF binary nanocomposites are systematically investigated. A low percolation value (f_c) for the CNTs/PVDF binary system is obtained due to the integration of solution and melting blending procedures. Two kinds of CNTs/PVDF binary systems with various CNTs contents (f_C_N_T_s) as the matrix are discussed. The results reveal that compared with CNTs/PVDF binary systems at the same f_C_N_T_s, the ternary BNNSs/CNTs/PVDF nanocomposites exhibit largely enhanced dielectric properties due to the improvement of the CNTs dispersion state and the conductive network. The dielectric constant of CNTs/PVDF binary nanocomposite with 6 vol. % CNTs (f_C_N_T_s   f_c), it displays a 43.32% improvement from 1325 to 1899 after the addition of 3 vol. % BNNSs. The presence of BNNSs facilitates the formation of the denser conductive network. Meanwhile, the ternary BNNSs/CNTs/PVDF systems exhibit a low dielectric loss. The adjustable dielectric properties could be obtained by employing the ternary systems due to the microstructure changes of nanocomposites.

  5. Optical absorption and thermoluminescence in Mg O, Mg O:Ni and Mg O:Li irradiated at room temperature

    International Nuclear Information System (INIS)

    Delgado, L.

    1984-01-01

    Optical absorption and thermoluminescence (TL) studies in Mg O, Mg O:Ni and Mg O:Li irradiated at room temperature are presented. In pure Mg O the thermal annihilation of Fe3+ by recombination with thermally released electrons at ∼ 90 and 175 degree centigree and the V center annealing by hole release up to 100 degree centigree cause the observed glow peaks at these temperatures. The TL excitation spectrum shows two maxima at 245 nm (electron center) and 288 nm (Fe3+). In Mg O:Ni X irradiation induces Fe 2 + →- Fe 3 + and Ni 2 + → Ni 3 + oxidations. Two TL emission bands centered at 110 degree centigree (red) and 80 o C (green) are assigned to electron release and their recombination at Fe 3 + and Ni 3 + respectively. In Mg O:Li two TL emission bands, one blue (430 nm) and the other red (730 nm) with excitation maxima at 245 nm (electron center) and 200 nm (hole center) respectively are observed. No V-center formation was detected in both Ni and Li doped samples. (Author) 42 refs

  6. Radiometric Non-Uniformity Characterization and Correction of Landsat 8 OLI Using Earth Imagery-Based Techniques

    Directory of Open Access Journals (Sweden)

    Frank Pesta

    2014-12-01

    Full Text Available Landsat 8 is the first satellite in the Landsat mission to acquire spectral imagery of the Earth using pushbroom sensor instruments. As a result, there are almost 70,000 unique detectors on the Operational Land Imager (OLI alone to monitor. Due to minute variations in manufacturing and temporal degradation, every detector will exhibit a different behavior when exposed to uniform radiance, causing a noticeable striping artifact in collected imagery. Solar collects using the OLI’s on-board solar diffuser panels are the primary method of characterizing detector level non-uniformity. This paper reports on an approach for using a side-slither maneuver to estimate relative detector gains within each individual focal plane module (FPM in the OLI. A method to characterize cirrus band detector-level non-uniformity using deep convective clouds (DCCs is also presented. These approaches are discussed, and then, correction results are compared with the diffuser-based method. Detector relative gain stability is assessed using the side-slither technique. Side-slither relative gains were found to correct streaking in test imagery with quality comparable to diffuser-based gains (within 0.005% for VNIR/PAN; 0.01% for SWIR and identified a 0.5% temporal drift over a year. The DCC technique provided relative gains that visually decreased striping over the operational calibration in many images.

  7. A structural study of the pseudo-binary mercury chalcogenide alloy HgSe sub 0 sub . sub 7 S sub 0 sub . sub 3 at high pressure

    CERN Document Server

    Kozlenko, D P; Hull, S; Knorr, K; Savenko, B N; Shchennikov, V V; Voronin, V I

    2002-01-01

    The structure of the pseudo-binary mercury chalcogenide alloy HgSe sub 0 sub . sub 7 S sub 0 sub . sub 3 has been studied by means of X-ray and neutron powder diffraction at pressure up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal cinnabar structure was observed at P approx 1 GPa. The obtained structural parameters were used for the analysis of the geometrical relationship between the zinc blende and the cinnabar phases. The zinc blende-cinnabar phase transition is discussed in the framework of the Landau theory of phase transitions. It was found that the possible order parameter for the structural transformation is the spontaneous strain e sub 4. This assignment agrees with previously observed high pressure behaviour of the elastic constants of other mercury chalcogenides

  8. Radiation effect on PVC/ENR blends

    International Nuclear Information System (INIS)

    Chantara Thevy Ratnam; Khairul Zaman Mohd Dahlan

    1997-01-01

    The effect of irradiation on the physical properties of Polyvinyl Chloride / Epoxidised Natural Rubber Blends (PVC/ENR blends) were investigated. The enhancement in tensile strength, elongation at break, hardness and aging properties of the blends have confirmed the positive effect of irradiation on the blends. It is evident from gel fraction and infra red spectroscopic studies that the blends of PVC and ENR cross-linked upon irradiation. The results also revealed that at any blend composition, the enhancement in properties depend on irradiation dose which controls the degree of radiation induced cross-linking. In an attempt to maximize the constructive effect of irradiation, the influence of various additives such as stabilizers, radiation sensitizers, fillers and processing aids on the blend properties were studied. The changes in blend properties upon irradiation with the presents of above additives were also presented in this paper

  9. Blending into the mix

    Energy Technology Data Exchange (ETDEWEB)

    Adams, R.G.; Gibb, W.H.; Majid, K.A. [Power Technology (United Kingdom)

    1999-07-01

    Successful coal blending requires finding a careful balance between fuel costs and plant performance. A recent study of a Malaysian power plant shows how the utility (Tenaga Nasional Berhad (TNB)) could reduce fuel costs while avoiding boiler operating problems normally associated with firing low-grade coals. TNB`s Kaper 2220 MW power station in Selangor needed an improved method of coal blending for two new 500 MW units and for two existing 300 MW units. UK`s Power Technology was commissioned to identify what coal blends the boiler could tolerate. A Coal Quality Impact Model (CQIM) analysis of the effect of different coals and coal blends on combustion performance and economics, and a performance analysis of coal yard handling facility was made to determine whether the accuracy of the required blend could be achieved (using a Coal Handling Simulation, CHAS, software package). The CQIM study showed that the proportion of cheaper coals could be increased from 20% to 50% provided each shipment was adequately sampled. The CHAS study showed that use of a flat back reclaimer or modifications to the dry coal stove would allow accurate blending. 5 figs., 1 tab.

  10. Decentralized Blended Acquisition

    NARCIS (Netherlands)

    Berkhout, A.J.

    2013-01-01

    The concept of blending and deblending is reviewed, making use of traditional and dispersed source arrays. The network concept of distributed blended acquisition is introduced. A million-trace robot system is proposed, illustrating that decentralization may bring about a revolution in the way we

  11. Blended Learning: enabling Higher Education Reform

    Directory of Open Access Journals (Sweden)

    Kathleen Matheos

    2018-01-01

    Full Text Available Blended learning research and practice have been areas of growth for two decades in Canada, with over 95% of Canadian higher education institutions involved in some form of blended learning. Despite strong evidence based research and practice blended learning, for the most part, has remained at sidelined in Canadian universities. The article argues the need for blended learning to situate itself within the timely and crucial Higher Education Reform (HER agenda. By aligning the affordances of blended learning with the components of HER, blended learning can clearly serve as an enabler for HER.

  12. Influence of SEBS-MA and SBS compatibilizers on properties and morphology of blends of polystyrene/rubber residue (SBRr from the footwear industry

    Directory of Open Access Journals (Sweden)

    Carlos Bruno Barreto Luna

    Full Text Available Abstract The reuse of rubber waste is very important today, both to reduce the harmful effects on the environment, and to reduce the cost of new material development. Considering that most of the studies reported in literature refer to the reuse of tire waste, this article aims to evaluate the influence of styrene-butadiene-styrene (SBS and styrene-(ethylene-butylene-styrene grafted with maleic anhydride (SEBS-MA compatibilizers on the blend performance of polystyrene (PS/styrene-butadiene rubber residue (SBRr, which come from the footwear industry. The blends were prepared in a co-rotating twin screw extruder and then were molded by injection. They were analyzed by impact and tensile tests, heat deflection temperature (HDT, ductile-brittle transition temperature, dynamic mechanical thermal analysis (DMTA and transmission electron microscopy (TEM. The results evidenced that the use of any of the compatibilizers on the PS/SBRr blend significantly increased the impact strength, while the tensile properties and HDT were lower when compared to the polymer matrix. The ductile-brittle transition temperature remains at approximately 25°C range for all the blends. In general, it has been proved that the SBS was the most effective compatibilization process in the PS/SBRr system. The DMTA test shows the presence of two distinct temperature peaks. The morphologies obtained by TEM of binary and ternary blends were quite different and typical of immiscible blend. The results show a good perspective regarding the use of industrial waste (SBRr, since it may enhance a material that would be discarded.

  13. Rein Veidemann: meil oli valida - nüüd või mitte kunagi / Rein Veidemann ; küsitles Tõnu Prei

    Index Scriptorium Estoniae

    Veidemann, Rein, 1946-

    2007-01-01

    Intervjuu Rein Veidemanniga, kes oli üks 1991.a. augustiputši päevil Eesti iseseisvust kinnitava otsuse poolt hääletanud 69 rahvasaadikust. Ülemnõukogu 20. augusti otsust peab ta sama tähtsaks kui Eesti Vabariigi väljakuulutamist 1918. aastal

  14. Physico-chemical properties of blends of palm olein with other vegetable oils

    Directory of Open Access Journals (Sweden)

    Mobin Siddique, Bazlul

    2010-12-01

    Full Text Available Palm oil (olein was blended with other edible oils for the enhancement of its market acceptability in terms of melting point depression and shelf life. The physico-chemical properties like viscosity, density, melting behavior, peroxide value (PV, saponification value (SV and iodine value (IV of four different binary blends with four vegetable oils were evaluated. Palm olein was found to be more stable against rancidity than the other oils. For the stability against oxidation and melting point depression the palm olein-canola (PO/CO blend was found to be better than the others. The Differential Scanning Calorimeter (DSC thermogram of the melting behavior of the blends traces some new polymorphs of the triglyceride. This study will help the oil producing industry to find out the most economically viable oil blends for cooking purposes, with maximum nutrition as well as desirable physico-chemical properties.

    Aceite de palma (oleína fue mezclada con otros aceites comestibles para aumentar su aceptabilidad en el mercado en términos de descenso del punto de fusión y mejora de su almacenamiento. Las propiedades físico-químicas tales como viscosidad, densidad, comportamiento en la fusión, valor de peróxidos (PV, valor de saponificación (SV e índice de yodo (IV de cuatro diferentes mezclas binarias con cuatro aceites vegetales fueron evaluadas. La oleína de palma fue más estable frente a la rancidez que otros aceites. En la estabilidad frente la oxidación y el descenso del punto de fusión, la mezcla de oleína de palma/canola (PO/CO fue mejor que las otras. Los termogramas del calorímetro diferencial de barrido (DSC referidos al comportamiento de fusión de las mezclas indican algunos nuevos polimorfismos de los triglicéridos. Este estudio podría ayudar a las empresas que elaboran aceites a encontrar los aceites económicamente más viables para cocinar, con buenas propiedades nutricionales, así como con unas propiedades f

  15. 7 CFR 989.16 - Blend.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Blend. 989.16 Section 989.16 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Marketing Agreements and... CALIFORNIA Order Regulating Handling Definitions § 989.16 Blend. Blend means to mix or commingle raisins. ...

  16. Effect of Blending on the Composition and Acceptability of Blends of ...

    African Journals Online (AJOL)

    However the blend was found deficient in lysine, leucine, iso-leucine and phenylalanine when compared with the FAO recommendations for infants. Increased levels of pigeon pea in the blend also resulted in significant increases in potassium, phosphorus, sodium, magnesium and calcium. Similarly, increased levels of ...

  17. Mapping paddy rice planting area in rice-wetland coexistent areas through analysis of Landsat 8 OLI and MODIS images.

    Science.gov (United States)

    Zhou, Yuting; Xiao, Xiangming; Qin, Yuanwei; Dong, Jinwei; Zhang, Geli; Kou, Weili; Jin, Cui; Wang, Jie; Li, Xiangping

    2016-04-01

    Accurate and up-to-date information on the spatial distribution of paddy rice fields is necessary for the studies of trace gas emissions, water source management, and food security. The phenology-based paddy rice mapping algorithm, which identifies the unique flooding stage of paddy rice, has been widely used. However, identification and mapping of paddy rice in rice-wetland coexistent areas is still a challenging task. In this study, we found that the flooding/transplanting periods of paddy rice and natural wetlands were different. The natural wetlands flood earlier and have a shorter duration than paddy rice in the Panjin Plain, a temperate region in China. We used this asynchronous flooding stage to extract the paddy rice planting area from the rice-wetland coexistent area. MODIS Land Surface Temperature (LST) data was used to derive the temperature-defined plant growing season. Landsat 8 OLI imagery was used to detect the flooding signal and then paddy rice was extracted using the difference in flooding stages between paddy rice and natural wetlands. The resultant paddy rice map was evaluated with in-situ ground-truth data and Google Earth images. The estimated overall accuracy and Kappa coefficient were 95% and 0.90, respectively. The spatial pattern of OLI-derived paddy rice map agrees well with the paddy rice layer from the National Land Cover Dataset from 2010 (NLCD-2010). The differences between Rice Landsat and Rice NLCD are in the range of ±20% for most 1-km grid cell. The results of this study demonstrate the potential of the phenology-based paddy rice mapping algorithm, via integrating MODIS and Landsat 8 OLI images, to map paddy rice fields in complex landscapes of paddy rice and natural wetland in the temperate region.

  18. Morphology stabilization of heterogeneous blends

    International Nuclear Information System (INIS)

    1980-01-01

    A heterogeneous elastomer blend is described, consisting of at least two elastomer components which are cross-linkable by irradiation and having a stabilized morphology formed by subjecting the blend to high energy radiation to a point from below to slightly above the gel dose of the blend. (author)

  19. Locally restricted blending of Blobtrees

    NARCIS (Netherlands)

    Groot, de Erwin; Wyvill, B.; Wetering, van de H.M.M.

    2009-01-01

    Blobtrees are volume representations particularly useful for models which require smooth blending. When blending is applied to two or more Blobtree models, extra volume will be created in between the two surfaces to form a smooth connection. Although it is easy to apply blending, it is hard to

  20. Performance of Blended Learning in University Teaching:

    Directory of Open Access Journals (Sweden)

    Michael Reiss

    2010-07-01

    Full Text Available Blended learning as a combination of classroom teaching and e-learning has become a widely represented standard in employee and management development of companies. The exploratory survey “Blended Learning@University” conducted in 2008 investigated the integration of blended learning in higher education. The results of the survey show that the majority of participating academic teachers use blended learning in single courses, but not as a program of study and thus do not exploit the core performance potential of blended learning. According to the study, the main driver of blended learning performance is its embeddedness in higher education. Integrated blended programs of study deliver the best results. In blended learning, learning infrastructure (in terms of software, culture, skills, funding, content providing, etc. does not play the role of a performance driver but serves as an enabler for blended learning.

  1. Development of cookies made with cocoyam, fermented sorghum and germinated pigeon pea flour blends using response surface methodology.

    Science.gov (United States)

    Okpala, Laura C; Okoli, Eric C

    2014-10-01

    Cookies were produced from blends of cocoyam, fermented sorghum and germinated pigeon pea flours. The study was carried out to evaluate the effects of varying the proportions of these components on the sensory and protein quality of the cookies. The sensory attributes studied were colour, taste, texture, crispness and general acceptability while the protein quality indices were biological value (BV) and net protein utilization (NPU). Mixture response surface methodology was used to model the sensory and protein quality with single, binary and ternary combinations of germinated pigeon pea, fermented sorghum and cocoyam flours. Results showed that BV and NPU of most of the cookies were above minimum acceptable levels. With the exception of cookies containing high levels of pigeon pea flour, cookies had acceptable sensory scores. Increase in pigeon pea flour resulted in increase in the BV and NPU. Regression equations suggested that the ternary blends produced the highest increase in all the sensory attributes (with the exception of colour).

  2. Prediction of the viscosity of lubricating oil blends at any temperature

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, R.M.; Bernardo, M.I.; Fernandez, A.M.; Folgueras, M.B. [University of Oviedo, Oveido (Spain). Dept. of Energy

    1996-04-01

    This paper discusses a method of predicting the viscosity of multicomponent base lubricating oil mixtures based on Andrade`s equation. The kinematic viscosity of three types of base lubricating oils and their binary and ternary mixtures were measured at different temperatures and the parameters of Andrade`s equation were calculated. The results obtained indicate that the Andrade parameters vary linearly with the mixture composition. From these linear equations, generalized mixing equations are derived which confirm the experimental results. By application of the mixing equations, a simple method is obtained for prediction of the viscosity of oil blends at any temperature from viscosity-temperature data of the oil components. The calculated viscosities gave an average absolute deviation of 10% over the temperature range 20-100{degree}C. 8 refs., 3 figs., 4 tabs.

  3. Blended Learning over Two Decades

    Science.gov (United States)

    Zhonggen, Yu; Yuexiu, Zhejiang

    2015-01-01

    The 21st century has witnessed vast amounts of research into blended learning since the conception of online learning formed the possibility of blended learning in the early 1990s. The theme of this paper is blended learning in mainstream disciplinary communities. In particular, the paper reports on findings from the last two decades which looked…

  4. Evaporation characteristics of ETBE-blended gasoline.

    Science.gov (United States)

    Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

    2015-04-28

    To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were developed. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. Evaporation characteristics of ETBE-blended gasoline

    International Nuclear Information System (INIS)

    Okamoto, Katsuhiro; Hiramatsu, Muneyuki; Hino, Tomonori; Otake, Takuma; Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi

    2015-01-01

    Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

  6. Evaporation characteristics of ETBE-blended gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, Katsuhiro, E-mail: okamoto@nrips.go.jp [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan); Hiramatsu, Muneyuki [Yamanashi Prefectural Police H.Q., 312-4 Kubonakajima, Isawa-cho, Usui, Yamanashi 406-0036 (Japan); Hino, Tomonori; Otake, Takuma [Metropolitan Police Department, 2-1-1 Kasumigaseki, Chiyoda-ku, Tokyo 100-8929 (Japan); Okamoto, Takashi; Miyamoto, Hiroki; Honma, Masakatsu; Watanabe, Norimichi [National Research Institute of Police Science, 6-3-1 Kashiwanoha, Kashiwa, Chiba 277-0882 (Japan)

    2015-04-28

    Highlights: • We chose 8-component hydrocarbon mixture as a model gasoline, and defined the molar mass of gasoline. • We proposed an evaporation model assuming a 2-component mixture of gasoline and ETBE. • We predicted the change in the vapor pressure of ETBE-blended gasoline by evaporation. • The vapor pressures were measured and compared as a means of verifying the model. • We presented the method for predicting flash points of the ETBE-blended gasoline. - Abstract: To reduce greenhouse gas emissions, which contribute to global warming, production of gasoline blended with ethyl tert-buthyl ether (ETBE) is increasing annually. The flash point of ETBE is higher than that of gasoline, and blending ETBE into gasoline will change the flash point and the vapor pressure. Therefore, it is expected that the fire hazard caused by ETBE-blended gasoline would differ from that caused by normal gasoline. The aim of this study was to acquire the knowledge required for estimating the fire hazard of ETBE-blended gasoline. Supposing that ETBE-blended gasoline was a two-component mixture of gasoline and ETBE, we developed a prediction model that describes the vapor pressure and flash point of ETBE-blended gasoline in an arbitrary ETBE blending ratio. We chose 8-component hydrocarbon mixture as a model gasoline, and defined the relation between molar mass of gasoline and mass loss fraction. We measured the changes in the vapor pressure and flash point of gasoline by blending ETBE and evaporation, and compared the predicted values with the measured values in order to verify the prediction model. The calculated values of vapor pressures and flash points corresponded well to the measured values. Thus, we confirmed that the change in the evaporation characteristics of ETBE-blended gasoline by evaporation could be predicted by the proposed model. Furthermore, the vapor pressure constants of ETBE-blended gasoline were obtained by the model, and then the distillation curves were

  7. AKRO/SF: Blend System

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Blend was the system used by the NMFS Alaska Regional Office to monitor groundfish catch from 1991 until 2002. The Blend system combined data from industry...

  8. A multicharge ion source (Supernanogan) for the OLIS facility at ISAC/TRIUMF.

    Science.gov (United States)

    Jayamanna, K; Wight, G; Gallop, D; Dube, R; Jovicic, V; Laforge, C; Marchetto, M; Leross, M; Louie, D; Laplante, R; Laxdal, R; McDonald, M; Wiebe, G J; Wang, V; Yan, F

    2010-02-01

    The Off-Line Ion Source (OLIS) [K. Jayamanna, D. Yuan, T. Kuo, M. MacDonald, P. Schmor, and G. Dutto, Rev. Sci. Instrum. 67, 1061 (1996); K. Jayamanna, Rev. Sci. Instrum. 79, 02711 (2008)] facility consists of a high voltage terminal containing a microwave cusp ion source, either a surface ion source or a hybrid surface-arc discharge ion source [K. Jayamanna and C. Vockenhuber, Rev. Sci. Instrum. 79, 02C712 (2008)], and an electrostatic switch that allows the selection of any one of the sources without mechanical intervention. These sources provide a variety of +1 beams up to mass 30 for Isotope Separator and ACcelerator (ISAC) [R. E. Laxdal, Nucl. Instrum. Methods Phys. Res. B 204, 400 (2003)] experiments, commissioning the accelerators, setting up the radioactive experiments, and for tuning the beam lines. The radio frequency quadrupole (RFQ) [M. Marchetto, Z. T. Ang, K. Jayamanna, R. E. Laxdal, A. Mitra, and V. Zvyagintsev, Eur. Phys. J. Spec. Top. 150, 241 (2005)] injector accelerator is a constant velocity machine designed to accept only 2 keV/u and the source extraction energy is limited to 60 kV. Further stripping is then needed downstream of the RFQ to inject the beam into the drift tube linac [M. Marchetto, Z. T. Ang, K. Jayamanna, R. E. Laxdal, A. Mitra, and V. Zvyagintsev, Eur. Phys. J. Spec. Top. 150, 241 (2005)] accelerator that requires A/q up to 6. Base on this constraints a multicharge ion source capable to deliver beams above mass 30 with A/q up to 6 was needed in order to reach full capability of the ISAC facility. A Supernanogan [C. Bieth et al., Nucleonika 48, S93 (2003)] multicharge ion source was then purchased from Pantechnik and was installed in the OLIS terminal. Commissioning and performance of the Supernanogan with some results such as emittance dependence of the charge states as well as charge state efficiencies are presented.

  9. Phosphoric acid doped membranes based on Nafion®, PBI and their blends – Membrane preparation, characterization and steam electrolysis testing

    DEFF Research Database (Denmark)

    Aili, David; Hansen, Martin Kalmar; Pan, Chao

    2011-01-01

    Proton exchange membrane steam electrolysis at temperatures above 100 °C has several advantages from thermodynamic, kinetic and engineering points of view. A key material for this technology is the high temperature proton exchange membrane. In this work a novel procedure for preparation of Nafion......® and polybenzimidazole blend membranes was developed. Homogeneous binary membranes covering the whole composition range were prepared and characterized with respect to chemical and physiochemical properties such as water uptake, phosphoric acid doping, oxidative stability, mechanical strength and proton conductivity...

  10. Binary Polymer Brushes of Strongly Immiscible Polymers.

    Science.gov (United States)

    Chu, Elza; Babar, Tashnia; Bruist, Michael F; Sidorenko, Alexander

    2015-06-17

    The phenomenon of microphase separation is an example of self-assembly in soft matter and has been observed in block copolymers (BCPs) and similar materials (i.e., supramolecular assemblies (SMAs) and homo/block copolymer blends (HBCs)). In this study, we use microphase separation to construct responsive polymer brushes that collapse to generate periodic surfaces. This is achieved by a chemical reaction between the minor block (10%, poly(4-vinylpyridine)) of the block copolymer and a substrate. The major block of polystyrene (PS) forms mosaic-like arrays of grafted patches that are 10-20 nm in size. Depending on the nature of the assembly (SMA, HBC, or neat BCP) and annealing method (exposure to vapors of different solvents or heating above the glass transition temperature), a range of "mosaic" brushes with different parameters can be obtained. Successive grafting of a secondary polymer (polyacrylamide, PAAm) results in the fabrication of binary polymer brushes (BPBs). Upon being exposed to specific selective solvents, BPBs may adopt different conformations. The surface tension and adhesion of the binary brush are governed by the polymer occupying the top stratum. The "mosaic" brush approach allows for a combination of strongly immiscible polymers in one brush. This facilitates substantial contrast in the surface properties upon switching, previously only possible for substrates composed of predetermined nanostructures. We also demonstrate a possible application of such PS/PAAm brushes in a tunable bioadhesion-bioadhesive (PS on top) or nonbioadhesive (PAAm on top) surface as revealed by Escherichia coli bacterial seeding.

  11. Entanglement in miscible blends

    Science.gov (United States)

    Watanabe, Hiroshi

    2010-03-01

    The entanglement length Le of polymer chains (corresponding to the entanglement molecular weight Me) is not an intrinsic material parameter but changes with the interaction with surrounding chains. For miscible blends of cis-polyisoprene (PI) and poly(tert-butyl styrene) (PtBS), changes of Le on blending was examined. It turned out that the Le averaged over the number fractions of the Kuhn segments of the components (PI and PtBS) satisfactorily describes the viscoelastic behavior of pseudo-monodisperse blends in which the terminal relaxation time is the same for PI and PtBS.

  12. Miscibility evolution of polycarbonate/polystyrene blends during compounding

    DEFF Research Database (Denmark)

    Chuai, Chengzhi; Almdal, Kristoffer; Johannsen, Ib

    2002-01-01

    The miscibility evolution of polycarbonate/polystyrene (PC/PS) blends during the compounding process in three blending methods of industrial relevance, namely melt blending, remelt blending in a twin-screw extruder and third melt blending in an injection molding machine, was investigated...... polymer in the other. The observed solubility strongly depends on blend composition and blending method. The T-g measurements showed maximum mutual solubility around 50/50 composition. The miscibility of PC/PS blended after the third stage (melt injection molding) was higher than that after the first...... by measuring their glass transition temperatures (T-g) and their specific heat increment (DeltaC(p)). Differential scanning calorimetry (DSC) was used to examine nine blend compositions. Shifts in glass transition temperature (T-g) of the two phases in melt-mixed PC/PS blends suggest partial miscibility of one...

  13. Effects of Blended-Cement Paste Chemical Composition Changes on Some Strength Gains of Blended-Mortars

    Science.gov (United States)

    Kirgiz, Mehmet Serkan

    2014-01-01

    Effects of chemical compositions changes of blended-cement pastes (BCPCCC) on some strength gains of blended cement mortars (BCMSG) were monitored in order to gain a better understanding for developments of hydration and strength of blended cements. Blended cements (BC) were prepared by blending of 5% gypsum and 6%, 20%, 21%, and 35% marble powder (MP) or 6%, 20%, 21%, and 35% brick powder (BP) for CEMI42.5N cement clinker and grinding these portions in ball mill at 30 (min). Pastes and mortars, containing the MP-BC and the BP-BC and the reference cement (RC) and tap water and standard mortar sand, were also mixed and they were cured within water until testing. Experiments included chemical compositions of pastes and compressive strengths (CS) and flexural strengths (FS) of mortars were determined at 7th-day, 28th-day, and 90th-day according to TS EN 196-2 and TS EN 196-1 present standards. Experimental results indicated that ups and downs of silica oxide (SiO2), sodium oxide (Na2O), and alkali at MP-BCPCC and continuously rising movement of silica oxide (SiO2) at BP-BCPCC positively influenced CS and FS of blended cement mortars (BCM) in comparison with reference mortars (RM) at whole cure days as MP up to 6% or BP up to 35% was blended for cement. PMID:24587737

  14. Effects of Blended-Cement Paste Chemical Composition Changes on Some Strength Gains of Blended-Mortars

    Directory of Open Access Journals (Sweden)

    Mehmet Serkan Kirgiz

    2014-01-01

    Full Text Available Effects of chemical compositions changes of blended-cement pastes (BCPCCC on some strength gains of blended cement mortars (BCMSG were monitored in order to gain a better understanding for developments of hydration and strength of blended cements. Blended cements (BC were prepared by blending of 5% gypsum and 6%, 20%, 21%, and 35% marble powder (MP or 6%, 20%, 21%, and 35% brick powder (BP for CEMI42.5N cement clinker and grinding these portions in ball mill at 30 (min. Pastes and mortars, containing the MP-BC and the BP-BC and the reference cement (RC and tap water and standard mortar sand, were also mixed and they were cured within water until testing. Experiments included chemical compositions of pastes and compressive strengths (CS and flexural strengths (FS of mortars were determined at 7th-day, 28th-day, and 90th-day according to TS EN 196-2 and TS EN 196-1 present standards. Experimental results indicated that ups and downs of silica oxide (SiO2, sodium oxide (Na2O, and alkali at MP-BCPCC and continuously rising movement of silica oxide (SiO2 at BP-BCPCC positively influenced CS and FS of blended cement mortars (BCM in comparison with reference mortars (RM at whole cure days as MP up to 6% or BP up to 35% was blended for cement.

  15. Introducing blended e-learning course design

    DEFF Research Database (Denmark)

    Gyamfi, Samuel Adu; Ryberg, Thomas

    2012-01-01

    In the face of diminishing education budgets in higher education, blended learning has been found to be a viable and effective approach to deliver high-quality, up-to-date, on-demand solutions to developing cross-curricular skills of undergraduates. However, research has also shown that blended...... learning solutions do not often live up to the potential of the approach or fail to produce the intended results because the students are not always equipped to handle the technical, psychological and organisational challenges of blended learning approaches. This project surveyed seventy-five first year...... the students’ e-readiness for an implementation of a blend-ed course design....

  16. Pulsars in binary systems: probing binary stellar evolution and general relativity.

    Science.gov (United States)

    Stairs, Ingrid H

    2004-04-23

    Radio pulsars in binary orbits often have short millisecond spin periods as a result of mass transfer from their companion stars. They therefore act as very precise, stable, moving clocks that allow us to investigate a large set of otherwise inaccessible astrophysical problems. The orbital parameters derived from high-precision binary pulsar timing provide constraints on binary evolution, characteristics of the binary pulsar population, and the masses of neutron stars with different mass-transfer histories. These binary systems also test gravitational theories, setting strong limits on deviations from general relativity. Surveys for new pulsars yield new binary systems that increase our understanding of all these fields and may open up whole new areas of physics, as most spectacularly evidenced by the recent discovery of an extremely relativistic double-pulsar system.

  17. Coalescence in PLA-PBAT blends under shear flow: Effects of blend preparation and PLA molecular weight

    Energy Technology Data Exchange (ETDEWEB)

    Nofar, M. [Center for High Performance Polymer and Composite Systems (CREPEC), Chemical Engineering Department, Polytechnique Montreal, Montreal, Quebec H3T 1J4, Canada and CREPEC, Department of Chemical Engineering, McGill University, Montreal, Quebec H3A 2B2 (Canada); Heuzey, M. C.; Carreau, P. J., E-mail: pierre.carreau@polymtl.ca [Center for High Performance Polymer and Composite Systems (CREPEC), Chemical Engineering Department, Polytechnique Montreal, Montreal, Quebec H3T 1J4 (Canada); Kamal, M. R. [CREPEC, Department of Chemical Engineering, McGill University, Montreal, Quebec H3A 2B2 (Canada); Randall, J. [NatureWorks LLC, 15305 Minnetonka Boulevard, Minnetonka, Minnesota 55345 (United States)

    2016-07-15

    Blends containing 75 wt. % of an amorphous polylactide (PLA) with two different molecular weights and 25 wt. % of a poly[(butylene adipate)-co-terephthalate] (PBAT) were prepared using either a Brabender batch mixer or a twin-screw extruder. These compounds were selected because blending PLA with PBAT can overcome various drawbacks of PLA such as its brittleness and processability limitations. In this study, we investigated the effects of varying the molecular weight of the PLA matrix and of two different mixing processes on the blend morphology and, further, on droplet coalescence during shearing. The rheological properties of these blends were investigated and the interfacial properties were analyzed using the Palierne emulsion model. Droplet coalescence was investigated by applying shear flows of 0.05 and 0.20 s{sup −1} at a fixed strain of 60. Subsequently, small amplitude oscillatory shear tests were conducted to investigate changes in the viscoelastic properties. The morphology of the blends was also examined using scanning electron microscope (SEM) micrographs. It was observed that the PBAT droplets were much smaller when twin-screw extrusion was used for the blend preparation. Shearing at 0.05 s{sup −1} induced significant droplet coalescence in all blends, but coalescence and changes in the viscoelastic properties were much more pronounced for the PLA-PBAT blend based on a lower molecular weight PLA. The viscoelastic responses were also somehow affected by the thermal degradation of the PLA matrix during the experiments.

  18. Coalescence in PLA-PBAT blends under shear flow: Effects of blend preparation and PLA molecular weight

    International Nuclear Information System (INIS)

    Nofar, M.; Heuzey, M. C.; Carreau, P. J.; Kamal, M. R.; Randall, J.

    2016-01-01

    Blends containing 75 wt. % of an amorphous polylactide (PLA) with two different molecular weights and 25 wt. % of a poly[(butylene adipate)-co-terephthalate] (PBAT) were prepared using either a Brabender batch mixer or a twin-screw extruder. These compounds were selected because blending PLA with PBAT can overcome various drawbacks of PLA such as its brittleness and processability limitations. In this study, we investigated the effects of varying the molecular weight of the PLA matrix and of two different mixing processes on the blend morphology and, further, on droplet coalescence during shearing. The rheological properties of these blends were investigated and the interfacial properties were analyzed using the Palierne emulsion model. Droplet coalescence was investigated by applying shear flows of 0.05 and 0.20 s"−"1 at a fixed strain of 60. Subsequently, small amplitude oscillatory shear tests were conducted to investigate changes in the viscoelastic properties. The morphology of the blends was also examined using scanning electron microscope (SEM) micrographs. It was observed that the PBAT droplets were much smaller when twin-screw extrusion was used for the blend preparation. Shearing at 0.05 s"−"1 induced significant droplet coalescence in all blends, but coalescence and changes in the viscoelastic properties were much more pronounced for the PLA-PBAT blend based on a lower molecular weight PLA. The viscoelastic responses were also somehow affected by the thermal degradation of the PLA matrix during the experiments.

  19. Morphology Evolution of Polycarbonate-Polystyrene Blends During Compounding

    DEFF Research Database (Denmark)

    Chuai, Chengzhi; Almdal, Kristoffer; Johannsen, Ib

    2001-01-01

    The morphology evolution of polycarbonate-polystyrene (PC/PS) blends during the compounding process in three blending methods of industrial relevance, namely melt blending, re-melt blending in a twin-screw extruder and tri-melt blending in an injection-moulding machine, was investigated using......-empirical model. The results show that the formation of co-continuous morphology strongly depends on blend composition and melt blending method, whereas the model prediction for phase inversion deviates from the experimental values. Further, we found that the initial mechanism of morphology evolution involves...... scanning electron microscopy (SEM) Co examine nine blend compositions. Blends were prepared at compositions where phase inversion was expected to occur according to model predictions. The experimental results were compared to the values of the point of phase inversion calculated with the semi...

  20. Organic non-volatile memories from ferroelectric phase separated blends

    Science.gov (United States)

    Asadi, Kamal; de Leeuw, Dago; de Boer, Bert; Blom, Paul

    2009-03-01

    Ferroelectric polarisation is an attractive physical property for non-volatile binary switching. The functionality of the targeted memory should be based on resistive switching. Conductivity and ferroelectricity however cannot be tuned independently. The challenge is to develop a storage medium in which the favourable properties of ferroelectrics such as bistability and non-volatility can be combined with the beneficial properties provided by semiconductors such as conductivity and rectification. In this contribution we present an integrated solution by blending semiconducting and ferroelectric polymers into phase separated networks. The polarisation field of the ferroelectric modulates the injection barrier at the semiconductor--metal contact. This combination allows for solution-processed non-volatile memory arrays with a simple cross-bar architecture that can be read-out non-destructively. Based on this general concept a non-volatile, reversible switchable Schottky diode with relatively fast programming time of shorter than 100 microseconds, long information retention time of longer than 10^ days, and high programming cycle endurance with non-destructive read-out is demonstrated.

  1. Blended Learning Design

    DEFF Research Database (Denmark)

    Pedersen, Lise

    2015-01-01

    University College Lillebaelt has decided that 30 percent of all educational elements must be generated as blended learning by the end of the year 2015 as part of a modernization addressing following educational needs: 1. Blended learning can help match the expectations of the future students who...... learning. 4. Blended learning can contribute to supporting and improving efficiency of educational efforts. This can for instance be done through programmes for several classes by using video conferencing, allocating traditional face to face teaching to synchronous and asynchronous study activities produce...... digital materials which can be employed didactically and reused by the teachers. This can also mean that the particular competencies which teaches have in Svendborg can be used at other locations in UCL and disseminated to a larger group of students without further costs. Educational Innovation...

  2. Blended Learning: How Teachers Balance the Blend of Online and Classroom Components

    Science.gov (United States)

    Jeffrey, Lynn M.; Milne, John; Suddaby, Gordon

    2014-01-01

    Despite teacher resistance to the use of technology in education, blended learning has increased rapidly, driven by evidence of its advantages over either online or classroom teaching alone. However, blended learning courses still fail to maximize the benefits this format offers. Much research has been conducted on various aspects of this problem,…

  3. Trojan Binaries

    Science.gov (United States)

    Noll, K. S.

    2017-12-01

    The Jupiter Trojans, in the context of giant planet migration models, can be thought of as an extension of the small body populations found beyond Neptune in the Kuiper Belt. Binaries are a distinctive feature of small body populations in the Kuiper Belt with an especially high fraction apparent among the brightest Cold Classicals. The binary fraction, relative sizes, and separations in the dynamically excited populations (Scattered, Resonant) reflects processes that may have eroded a more abundant initial population. This trend continues in the Centaurs and Trojans where few binaries have been found. We review new evidence including a third resolved Trojan binary and lightcurve studies to understand how the Trojans are related to the small body populations that originated in the outer protoplanetary disk.

  4. Thin films of polymer blends deposited by matrix-assisted pulsed laser evaporation: Effects of blending ratios

    International Nuclear Information System (INIS)

    Paun, Irina Alexandra; Ion, Valentin; Moldovan, Antoniu; Dinescu, Maria

    2011-01-01

    In this work, we show successful use of matrix-assisted pulsed laser evaporation (MAPLE) for obtaining thin films of PEG:PLGA blends, in the view of their use for controlled drug delivery. In particular, we investigate the influence of the blending ratios on the characteristics of the films. We show that the roughness of the polymeric films is affected by the ratio of each polymer within the blend. In addition, we perform Fourier transformed infrared spectroscopy (FTIR) measurements and we find that the intensities ratios of the infrared absorption bands of the two polymers are consistent with the blending ratios. Finally, we assess the optical constants of the polymeric films by spectroscopic ellipsometry (SE). We point out that the blending ratios exert an influence on the optical characteristics of the films and we validate the SE results by atomic force microscopy and UV-vis spectrophotometry. In all, we stress that the ratios in which the two polymers are blended have significant impact on the morphology, chemical structure and optical characteristics of the polymeric films deposited by MAPLE.

  5. Emissions characteristics of higher alcohol/gasoline blends

    International Nuclear Information System (INIS)

    Gautam, M.; Martin, D.W.; Carder, D.

    2000-01-01

    An experimental investigation was conducted to determine the emissions characteristics of higher alcohols and gasoline (UTG96) blends. While lower alcohols (methanol and ethanol) have been used in blends with gasoline, very little work has been done or reported on higher alcohols (propanol, butanol and pentanol). Comparisons of emissions and fuel characteristics between higher alcohol/gasoline blends and neat gasoline were made to determine the advantages and disadvantages of blending higher alcohols with gasoline. All tests were conducted on a single-cylinder Waukesha Cooperative Fuel Research engine operating at steady state conditions and stoichiometric air-fuel (A/F) ratio. Emissions test were conducted at the optimum spark timing-knock limiting compression ratio combination for the particular blend being tested. The cycle emission [mass per unit time (g/h)] of CO, CO 2 and organic matter hydrocarbon equivalent (OMHCE) from the higher alcohol/gasoline blends were very similar to those from neat gasoline. Cycle emissions of NO x from the blends were higher than those from neat gasoline. However, for all the emissions species considered, the brake specific emissions (g/kW h) were significantly lower for the higher alcohol/gasoline blends than for neat gasoline. This was because the blends had greater resistance to knock and allowed higher compression ratios, which increased engine power output. The contribution of alcohols and aldehydes to the overall OMHCE emissions was found to be minimal. Cycle fuel consumption (g/h) of higher alcohol/gasoline blends was slightly higher than with neat gasoline due to the lower stoichiometric A/F ratios required by the blends. However, the brake specific fuel consumption (g/kW h) for the blends was significantly lower than that for neat gasoline. (Author)

  6. Improvement of PET surface hydrophilicity and roughness through blending

    Energy Technology Data Exchange (ETDEWEB)

    Kolahchi, Ahmad Rezaei; Ajji, Abdellah; Carreau, Pierre J. [CREPEC, Chemical Engineering Department, Polytechnique Montreal, 2500 chemin de Polytechnique, Quebec, Montreal (Canada)

    2015-05-22

    Controlling the adhesion of the polymer surface is a key issue in surface science, since polymers have been a commonly used material for many years. The surface modification in this study includes two different aspects. One is to enhance the hydrophilicity and the other is to create the roughness on the PET film surface. In this study we developed a novel and simple approach to modify polyethylene terephthalate (PET) film surface through polymer blending in twin-screw extruder. One example described in the study uses polyethylene glycol (PEG) in polyethylene terephthalate (PET) host to modify a PET film surface. Low content of polystyrene (PS) as a third component was used in the system to increase the rate of migration of PEG to the surface of the film. Surface enrichment of PEG was observed at the polymer/air interface of the polymer film containing PET-PEG-PS whereas for the PET-PEG binary blend more PEG was distributed within the bulk of the sample. Furthermore, a novel method to create roughness at the PET film surface was proposed. In order to roughen the surface of PET film, a small amount of PKHH phenoxy resin to change PS/PET interfacial tension was used. The compatibility effect of PKHH causes the formation of smaller PS droplets, which were able to migrate more easily through PET matrix. Consequently, resulting in a locally elevated concentration of PS near the surface of the film. The local concentration of PS eventually reached a level where a co-continuous morphology occurred, resulting in theinstabilities on the surface of the film.

  7. 40 CFR 80.82 - Butane blending.

    Science.gov (United States)

    2010-07-01

    ... FUELS AND FUEL ADDITIVES Reformulated Gasoline § 80.82 Butane blending. A refiner for any refinery that produces gasoline by blending butane with conventional gasoline or reformulated gasoline or RBOB may meet... paragraph (b)(1) of this section, the refiner may: (i) Blend the butane with conventional gasoline, or...

  8. Development of high-performance blended cements

    Science.gov (United States)

    Wu, Zichao

    2000-10-01

    This thesis presents the development of high-performance blended cements from industrial by-products. To overcome the low-early strength of blended cements, several chemicals were studied as the activators for cement hydration. Sodium sulfate was discovered as the best activator. The blending proportions were optimized by Taguchi experimental design. The optimized blended cements containing up to 80% fly ash performed better than Type I cement in strength development and durability. Maintaining a constant cement content, concrete produced from the optimized blended cements had equal or higher strength and higher durability than that produced from Type I cement alone. The key for the activation mechanism was the reaction between added SO4 2- and Ca2+ dissolved from cement hydration products.

  9. Pemodelan Dan Analisis Pengaruh Variasi Oli dan Diameter Orifice terhadap Gaya Redam Shock Absorber Dan Respon Dinamis Sepeda Motor Yamaha Jupiter Z 2008

    Directory of Open Access Journals (Sweden)

    Newanda Asa Wahid

    2017-03-01

    Full Text Available Sepeda motor merupakan moda transportasi yang paling banyak diminati oleh masyarakat Indonesia. Dalam hal kenyamanan, maka komponen sepeda motor yang berperan penting adalah sistem suspensi. Sistem suspensi berfungsi menyerap getaran berlebih akibat profil permukaan jalan, sehingga meningkatkan kenyamanan dan keamanan. Oleh karena itu, perlu dilakukan penelitian untuk mendapatkan sistem suspensi yang terbaik. Dalam tugas akhir ini dilakukan pemodelan dan analisis pengaruh perubahan parameter sistem suspensi sepeda motor Yamaha Jupiter Z 2008 khususnya pada komponen monotube hydraulic shock absorber yang didasarkan pada pemodelan setengah kendaraan. Parameter yang divariasikan adalah tipe oli dan diameter orifice, dimana terdapat 5 macam tipe oli dengan rentang nilai massa jenis (ρ sebesar 845 – 874 kg/m3, dan viskositas (ν sebesar 11,3 – 46 mm2/s, sementara untuk diameter orifice yaitu saat kompresi (Docomp sebesar 1,2 – 1,5 mm, saat ekspansi (Doexp sebesar 0,8 – 1 mm. Input yang digunakan pada simulasi adalah input sinusoidal dan input bump modified. Dari penelitian ini didapatkan hasil bahwa sistem suspensi modifikasi monotube hydraulic shock absorber yang menghasilkan gaya redam optimal memiliki nilai parameter viskositas kinematis oli 46 mm2/s, massa jenis oli 845 kg/m3, diameter orifice kompresi 0,00135 m, dan diameter orifice ekspansi 0,0009 m. Nilai gaya redam optimal yang dihasilkan sistem suspensi modifikasi adalah sebesar 1171,3 N, lebih tinggi hingga 546,44 N dibandingkan dengan gaya redam sistem supensi asli yang bernilai 624,86 N pada frekuensi 2 Hz. Pada sistem setengah kendaraan motor dengan penggunaan sistem suspensi asli maupun modifikasi, untuk input bump, respon kendaraan dan penumpang mencapai steady state kurang dari 2 detik dan 5 detik, sedangkan untuk input sinusoidal responnya mencapai steady state kurang dari 2 detik dan 3 detik. Penggunaan suspensi asli maupun modifikasi menghasilkan nilai perpindahan RMS yang

  10. Testing the Binary Black Hole Nature of a Compact Binary Coalescence.

    Science.gov (United States)

    Krishnendu, N V; Arun, K G; Mishra, Chandra Kant

    2017-09-01

    We propose a novel method to test the binary black hole nature of compact binaries detectable by gravitational wave (GW) interferometers and, hence, constrain the parameter space of other exotic compact objects. The spirit of the test lies in the "no-hair" conjecture for black holes where all properties of a Kerr black hole are characterized by its mass and spin. The method relies on observationally measuring the quadrupole moments of the compact binary constituents induced due to their spins. If the compact object is a Kerr black hole (BH), its quadrupole moment is expressible solely in terms of its mass and spin. Otherwise, the quadrupole moment can depend on additional parameters (such as the equation of state of the object). The higher order spin effects in phase and amplitude of a gravitational waveform, which explicitly contains the spin-induced quadrupole moments of compact objects, hence, uniquely encode the nature of the compact binary. Thus, we argue that an independent measurement of the spin-induced quadrupole moment of the compact binaries from GW observations can provide a unique way to distinguish binary BH systems from binaries consisting of exotic compact objects.

  11. Phase behavior of binary polybutadiene copolymer mixtures as an example of weakly interacting polymers

    CERN Document Server

    Schwahn, D

    2002-01-01

    Binary blends of statistical polybutadiene copolymers of different vinyl content and molar volume were explored by small-angle neutron scattering. These samples represent the most simple class of statistical copolymer mixtures. In spite of this simplicity, changes in vinyl content, molar volume, and deuterium and hydrogen content of the chains give rise to strong effects; phase separation occurs from minus 230 C to more than plus 200 C and can even reverse from an enthalpically driven one at low temperatures to an entropically driven one at high temperatures. The entropic and enthalpic terms of the Flory-Huggins parameter as determined from the experiment are in excellent agreement with lattice cluster theory calculations. (orig.)

  12. THE COMBUSTION CHARACTERISTICS OF LIGNITE BLENDS

    Institute of Scientific and Technical Information of China (English)

    Cheng Jun; Zhou Junhu; Cao Xinyu; Cen Kefa

    2000-01-01

    The combustion characteristics of lignite blends were studied with a thermogravimetric analyzer (t.g.a.), at constant heating rate.The characteristic temperatures were determined from the burning profiles.It was found that the characteristic times of combustion reaction moved forward, the ignition temperature dropped and the burnout efficiency slightly changed when blending lignites.The characteristic parameters of blends could not be predicted as a linear function of the average values of the individual lignites.when blending with less reactive coal, the ignition and burnout characteristics of lignite turned worse.

  13. Neutral wetting brush layers for block copolymer thin films using homopolymer blends processed at high temperatures

    International Nuclear Information System (INIS)

    Ceresoli, M; Palermo, M; Ferrarese Lupi, F; Seguini, G; Perego, M; Zuccheri, G; Phadatare, S D; Antonioli, D; Gianotti, V; Sparnacci, K; Laus, M

    2015-01-01

    Binary homopolymer blends of two hydroxyl-terminated polystyrene (PS-OH) and polymethylmethacrylate (PMMA-OH) homopolymers (Mn ∼ 16000 g mol"−"1) were grafted on SiO_2 substrates by high-temperature (T > 150 °C), short-time (t < 600 s) thermal treatments. The resulting brush layer was tested to screen preferential interactions of the SiO_2 substrate with the different symmetric and asymmetric PS-b-PMMA block copolymers deposited on top of the grafted molecules. By properly adjusting the blend composition and the processing parameters, an efficient surface neutralization path was identified, enabling the formation, in the block copolymer film, of homogeneous textures of lamellae or cylinders perpendicularly oriented with respect to the substrate. A critical interplay between the phase segregation of the homopolymer blends and their grafting process on the SiO_2 was observed. In fact, the polar SiO_2 is preferential for the PMMA-rich phase that forms a homogeneous layer on the substrate, while the PS-rich phase is located at the polymer-air interface. During the thermal treatment, phase segregation and grafting proceed simultaneously. Complete wetting of the PS rich phase on the PMMA rich phase leads to the formation of a PS/PMMA bilayer. In this case, the progressive diffusion of PS chains toward the polymer-SiO_2 interface during the thermal treatment allows tuning of the brush layer composition. (paper)

  14. Binary Masking & Speech Intelligibility

    DEFF Research Database (Denmark)

    Boldt, Jesper

    The purpose of this thesis is to examine how binary masking can be used to increase intelligibility in situations where hearing impaired listeners have difficulties understanding what is being said. The major part of the experiments carried out in this thesis can be categorized as either experime......The purpose of this thesis is to examine how binary masking can be used to increase intelligibility in situations where hearing impaired listeners have difficulties understanding what is being said. The major part of the experiments carried out in this thesis can be categorized as either...... experiments under ideal conditions or as experiments under more realistic conditions useful for real-life applications such as hearing aids. In the experiments under ideal conditions, the previously defined ideal binary mask is evaluated using hearing impaired listeners, and a novel binary mask -- the target...... binary mask -- is introduced. The target binary mask shows the same substantial increase in intelligibility as the ideal binary mask and is proposed as a new reference for binary masking. In the category of real-life applications, two new methods are proposed: a method for estimation of the ideal binary...

  15. Structural characterization of HDPE/LLDPE blend-based nano composites obtained by different blending sequence

    International Nuclear Information System (INIS)

    Passador, Fabio R.; Ruvolo Filho, Adhemar; Pessan, Luiz A.

    2011-01-01

    The blending sequence affects the morphology formation of the nanocomposites. In this work, the blending sequences were explored to determine its influence in the rheological behavior of HDPE/LLDPE/OMMT nanocomposites. The nanocomposites were obtained by melt-intercalation using a mixture of LLDPE-g-MA and HDPE-g-MA as compatibilizer system in a torque rheometer at 180 deg C and five blending sequences were studied. The materials structures were characterized by wide angle X-ray diffraction (WAXD) and by rheological properties. The nanoclay's addition increased the shear viscosity at low shear rates, changing the behavior of HDPE/LLDPE matrix to a Bingham model behavior with an apparent yield stress. Intense interactions were obtained for the blending sequence where LLDPE and/or LLDPE-g-MA were first reinforced with organoclay since the intercalation process occurs preferentially in the amorphous phase. (author)

  16. Interacting binary stars

    CERN Document Server

    Sahade, Jorge; Ter Haar, D

    1978-01-01

    Interacting Binary Stars deals with the development, ideas, and problems in the study of interacting binary stars. The book consolidates the information that is scattered over many publications and papers and gives an account of important discoveries with relevant historical background. Chapters are devoted to the presentation and discussion of the different facets of the field, such as historical account of the development in the field of study of binary stars; the Roche equipotential surfaces; methods and techniques in space astronomy; and enumeration of binary star systems that are studied

  17. Integrating Data of ASTER and Landsat-8 OLI (AO for Hydrothermal Alteration Mineral Mapping in Duolong Porphyry Cu-Au Deposit, Tibetan Plateau, China

    Directory of Open Access Journals (Sweden)

    Tingbin Zhang

    2016-10-01

    Full Text Available One of the most important characteristics of porphyry copper deposits (PCDs is the type and distribution pattern of alteration zones which can be used for screening and recognizing these deposits. Hydrothermal alteration minerals with diagnostic spectral absorption properties in the visible and near-infrared (VNIR through the shortwave infrared (SWIR regions can be identified by multispectral and hyperspectral remote sensing data. Six Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER bands in SWIR have been shown to be effective in the mapping of Al-OH, Fe-OH, Mg-OH group minerals. The five VNIR bands of Landsat-8 (L8 Operational Land Imager (OLI are useful for discriminating ferric iron alteration minerals. In the absence of complete hyperspectral coverage area, an opportunity, however, exists to integrate ASTER and L8-OLI (AO to compensate each other’s shortcomings in covering area for mineral mapping. This study examines the potential of AO data in mineral mapping in an arid area of the Duolong porphyry Cu-Au deposit(Tibetan Plateau in China by using spectral analysis techniques. Results show the following conclusions: (1 Combination of ASTER and L8-OLI data (AO has more mineral information content than either alone; (2 The Duolong PCD alteration zones of phyllic, argillic and propylitic zones are mapped using ASTER SWIR bands and the iron-bearing mineral information is best mapped using AO VNIR bands; (3 The multispectral integration data of AO can provide a compensatory data of ASTER VNIR bands for iron-bearing mineral mapping in the arid and semi-arid areas.

  18. Assessment of environmentally friendly fuel emissions from in-use vehicle exhaust: low-blend iso-stoichiometric GEM mixture as example.

    Science.gov (United States)

    Schifter, Isaac; Díaz-Gutiérrez, Luis; Rodríguez-Lara, René; González-Macías, Carmen; González-Macías, Uriel

    2017-05-01

    Gasoline-ethanol-methanol fuel blends were formulated with the same stoichiometric air-to-fuel ratio and volumetric energy concentration as any binary ethanol-gasoline blend. When the stoichiometric blends operated in a vehicle, the time period, injector voltage, and pressure for each fuel injection event in the engine corresponded to a given stoichiometric air-to-fuel ratio, and the load was essentially constant. Three low oxygen content iso-stoichiometric ternary gasoline-ethanol-methanol fuel blends were prepared, and the properties were compared with regular-type fuel without added oxygen. One of the ternary fuels was tested using a fleet of in-use vehicles for15 weeks and compared to neat gasoline without oxygenated compounds as a reference. Only a small number of publications have compared these ternary fuels in the same engine, and little data exist on the performance and emissions of in-use spark-ignition engines. The total hydrocarbon emissions observed was similar in both fuels, in addition to the calculated ozone forming potential of the tailpipe and evaporative emissions. In ozone non-attainment areas, the original purpose for oxygenate gasolines was to decrease carbon monoxide emissions. The results suggest that the strategy is less effective than expected because there still exist a great number of vehicles that have suffered the progressive deterioration of emissions and do not react to oxygenation, while new vehicles are equipped with sophisticated air/fuel control systems, and oxygenation does not improve combustion because the systems adjust the stoichiometric point, making it insensitive to the origin of the added excess oxygen (fuel or excess air). Graphical abstract Low level ternary blend of gasoline-ethanol-methanol were prepared with the same stoichiometric air-fuel ratio and volumetric energy concentration, based on the volumetric energy density of the pre-blended components. Exhaust and evaporative emissions was compared with a blend

  19. Full Ionisation In Binary-Binary Encounters With Small Positive Energies

    Science.gov (United States)

    Sweatman, W. L.

    2006-08-01

    Interactions between binary stars and single stars and binary stars and other binary stars play a key role in the dynamics of a dense stellar system. Energy can be transferred between the internal dynamics of a binary and the larger scale dynamics of the interacting objects. Binaries can be destroyed and created by the interaction. In a binary-binary encounter, full ionisation occurs when both of the binary stars are destroyed in the interaction to create four single stars. This is only possible when the total energy of the system is positive. For very small energies the probability of this occurring is very low and it tends towards zero as the total energy tends towards zero. Here the case is considered for which all the stars have equal masses. An asymptotic power law is predicted relating the probability of full ionisation with the total energy when this latter quantity is small. The exponent, which is approximately 2.31, is compared with the results from numerical scattering experiments. The theoretical approach taken is similar to one used previously in the three-body problem. It makes use of the fact that the most dramatic changes in scale and energies of a few-body system occur when its components pass near to a central configuration. The position, and number, of these configurations is not known for the general four-body problem, however, with equal masses there are known to be exactly five different cases. Separate consideration and comparison of the properties of orbits close to each of these five central configurations enables the prediction of the form of the cross-section for full ionisation for the case of small positive total energy. This is the relation between total energy and the probability of total ionisation described above.

  20. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. I. S-TYPE BINARIES

    Energy Technology Data Exchange (ETDEWEB)

    Kaltenegger, Lisa [MPIA, Koenigstuhl 17, D-69117 Heidelberg (Germany); Haghighipour, Nader, E-mail: kaltenegger@mpia.de [Institute for Astronomy and NASA Astrobiology Institute, University of Hawaii-Manoa, Honolulu, HI 96822 (United States)

    2013-11-10

    We have developed a comprehensive methodology for calculating the boundaries of the habitable zone (HZ) of planet-hosting S-type binary star systems. Our approach is general and takes into account the contribution of both stars to the location and extent of the binary HZ with different stellar spectral types. We have studied how the binary eccentricity and stellar energy distribution affect the extent of the HZ. Results indicate that in binaries where the combination of mass-ratio and orbital eccentricity allows planet formation around a star of the system to proceed successfully, the effect of a less luminous secondary on the location of the primary's HZ is generally negligible. However, when the secondary is more luminous, it can influence the extent of the HZ. We present the details of the derivations of our methodology and discuss its application to the binary HZ around the primary and secondary main-sequence stars of an FF, MM, and FM binary, as well as two known planet-hosting binaries α Cen AB and HD 196886.

  1. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. I. S-TYPE BINARIES

    International Nuclear Information System (INIS)

    Kaltenegger, Lisa; Haghighipour, Nader

    2013-01-01

    We have developed a comprehensive methodology for calculating the boundaries of the habitable zone (HZ) of planet-hosting S-type binary star systems. Our approach is general and takes into account the contribution of both stars to the location and extent of the binary HZ with different stellar spectral types. We have studied how the binary eccentricity and stellar energy distribution affect the extent of the HZ. Results indicate that in binaries where the combination of mass-ratio and orbital eccentricity allows planet formation around a star of the system to proceed successfully, the effect of a less luminous secondary on the location of the primary's HZ is generally negligible. However, when the secondary is more luminous, it can influence the extent of the HZ. We present the details of the derivations of our methodology and discuss its application to the binary HZ around the primary and secondary main-sequence stars of an FF, MM, and FM binary, as well as two known planet-hosting binaries α Cen AB and HD 196886

  2. Polyethylene/hydrophilic polymer blends for biomedical applications.

    Science.gov (United States)

    Brynda, E; Houska, M; Novikova, S P; Dobrova, N B

    1987-01-01

    Polyethylene blends with poly(2-hydroxyethyl methacrylate) [poly(HEMA)] or poly(2,3-dihydroxypropyl methacrylate) [poly(DHPMA)] were prepared by swelling polyethylene with HEMA or 2,3-epoxypropyl methacrylate (EPMA) and by polymerization of the respective monomers. Poly(EPMA) in blends was hydrolysed to poly(DHPMA) with acetic acid. The blends had similar surface and bulk compositions. Swelling with water and surface wettability were proportional to the content of the hydrophilic component; at the same content the polyethylene/poly(DHPMA) blends appeared more hydrophilic than those of polyethylene/poly(HEMA). Thrombus formation in contact with blood examined ex vivo and in vivo was considerably slower on the blends than on unmodified polyethylene. The tests indicated optima in composition; the best biological response was achieved with the blends containing about 14% poly(HEMA) or 16% poly(DHPMA).

  3. HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation.

  4. HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal

    International Nuclear Information System (INIS)

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation

  5. HEU to LEU conversion and blending facility: UNH blending alternative to produce LEU oxide for disposal

    International Nuclear Information System (INIS)

    1995-09-01

    The United States Department of Energy (DOE) is examining options for the disposition of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. Disposition is a process of use or disposal of material that results in the material being converted to a form that is substantially and inherently more proliferation-resistant than is the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. This report provides data to be used in the environmental impact analysis for the uranyl nitrate hexahydrate blending option to produce oxide for disposal. This the Conversion and Blending Facility (CBF) alternative will have two missions (1) convert HEU materials into HEU uranyl nitrate (UNH) and (2) blend the HEU uranyl nitrate with depleted and natural assay uranyl nitrate to produce an oxide that can be stored until an acceptable disposal approach is available. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal

  6. HEU to LEU conversion and blending facility: UNH blending alternative to produce LEU oxide for disposal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The United States Department of Energy (DOE) is examining options for the disposition of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. Disposition is a process of use or disposal of material that results in the material being converted to a form that is substantially and inherently more proliferation-resistant than is the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. This report provides data to be used in the environmental impact analysis for the uranyl nitrate hexahydrate blending option to produce oxide for disposal. This the Conversion and Blending Facility (CBF) alternative will have two missions (1) convert HEU materials into HEU uranyl nitrate (UNH) and (2) blend the HEU uranyl nitrate with depleted and natural assay uranyl nitrate to produce an oxide that can be stored until an acceptable disposal approach is available. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

  7. OLI/ESP Modeling Of The Semi-Integrated Pilot Plant For Estimate Of Campaigns I-IV Simulant Volumes

    International Nuclear Information System (INIS)

    CARL, BARNES

    2004-01-01

    Four SIPP campaigns have been planned to investigate the effect of recycle streams on the RPP-WTP pretreatment process such as the filter flux rate and other areas of interest. This document describes OLI/ESP modeling work done in support of the planning and operation of the SIPP. An existing OLI/ESP steady-state model was expanded to represent the pretreatment system through to the TLP evaporator for the LAW train and the washed sludge for the HLW train. The model was used to investigate alternative operating scenarios, determine the optimum volumetric waste feed ratio of AP-101 to AY-102, and, for each campaign, estimate the simulant and input recycle volumes corresponding to the target glass production rates of 6MT/day HLW glass and 80MT/day LAW glass and scaled to the target of 140L of Campaign I washed sludge. It was designed to quickly achieve steady state and simulation results indicate this was accomplished by Campaign IV. The alternative operating scenarios modeled differed only in the point at which the AP-101 and AY-102 waste feed streams were introduced to the process. The results showed no difference in the production rate between the scenarios. Therefore, for these specific waste feeds the process should be operated to maximize the energy efficiency and minimize scaling in the evaporator by feeding the AY-102 waste feed to the ultra-filtration feed prep tank, bypassing the waste feed evaporator

  8. Interacting binaries

    CERN Document Server

    Shore, S N; van den Heuvel, EPJ

    1994-01-01

    This volume contains lecture notes presented at the 22nd Advanced Course of the Swiss Society for Astrophysics and Astronomy. The contributors deal with symbiotic stars, cataclysmic variables, massive binaries and X-ray binaries, in an attempt to provide a better understanding of stellar evolution.

  9. Viscoelastic properties of PLA/PCL blends compatibilized with different methods

    Science.gov (United States)

    Shin, Boo Young; Han, Do Hung

    2017-11-01

    The aim of this study was to observe changes in the viscoelastic properties of PLA/PCL (80/20) blends produced using different compatibilization methods. Reactive extrusion and high-energy radiation methods were used for blend compatibilization. Storage and loss moduli, complex viscosity, transient stress relaxation modulus, and tan δ of blends were analyzed and blend morphologies were examined. All compatibilized PLA/PCL blends had smaller dispersed particle sizes than the non-compatibilized blend, and well compatibilized blends had finer morphologies than poorly compatibilized blends. Viscoelastic properties differentiated well compatibilized and poorly compatibilized blends. Well compatibilized blends had higher storage and loss moduli and complex viscosities than those calculated by the log-additive mixing rule due to strong interfacial adhesion, whereas poorly compatibilized blends showed negative deviations due to weak interfacial adhesion. Moreover, well compatibilized blends had much slower stress relaxation than poorly compatibilized blends and didn't show tan δ plateau region caused by slippage at the interface between continuous and dispersed phases.

  10. Mechanical properties of irradiated rubber-blends

    International Nuclear Information System (INIS)

    Nasr, G.M.; Madani, M.

    2005-01-01

    A study has been made on blend ratios of natural rubber (NR) and acrylonitrile butadiene rubber (NBR) that are loaded with general purpose furnace (GPE) carbon black and irradiated at different gamma radiation doses. It was fount that the mechanical properties of such blend are highly affected by γ- irradiation dose and the composition ratios of its constituents. The elongation at break for blends was found to increase slightly with increasing NBR loafing which is mainly due to the stiffness of blending matrix formation between NR and GPF carbon black particles. The hysteresis loss, extension ratio and shape factor have been calculated for the different un-irradiated and irradiated samples

  11. Face-to-Face Activities in Blended Learning

    DEFF Research Database (Denmark)

    Kjærgaard, Annemette

    While blended learning combines online and face-to-face teaching, research on blended learning has primarily focused on the role of technology and the opportunities it creates for engaging students. Less focus has been put on face-to-face activities in blended learning. This paper argues...... that it is not only the online activities in blended learning that provide new opportunities for rethinking pedagogy in higher education, it is also imperative to reconsider the face-to-face activities when part of the learning is provided online. Based on a review of blended learning in business and management...... education, we identify what forms of teaching and learning are suggested to take place face-to-face when other activities are moved online. We draw from the Community of Inquiry framework to analyze how face-to-face activities contribute to a blended learning pedagogy and discuss the implications...

  12. BLENDED LEARNING STRATEGY IN TEACHER TRAINING PROGRAMS

    Directory of Open Access Journals (Sweden)

    Marian F. Byrka

    2017-12-01

    Full Text Available The article examines the implementation of blended learning strategy in teacher training programs as an innovation in online learning. The blended learning idea comes from blending elements which use online technology with more traditional face-to-face teaching in the same course. The article analyses teacher training programs offered by Chernivtsi Regional Institute of Postgraduate Pedagogical Education. Additional data were gathered through a questionnaire administered to teachers who attended training courses. The characteristics of blended learning strategy, its benefits and limitations for teacher training are supported by a review of literature. The article closes with the comparison of curriculum components (content delivery, learner activities, materials, and required competences between traditional and blended learning teacher training programs. Having obvious benefits in teacher training programs, the implementation of blended learning strategy sets some additional requirements to a learner, as well as to course instructors and lectors.

  13. Eclipsing binaries in open clusters

    DEFF Research Database (Denmark)

    Southworth, John; Clausen, J.V.

    2006-01-01

    Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August......Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August...

  14. 27 CFR 24.213 - Heavy bodied blending wine.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Heavy bodied blending wine..., DEPARTMENT OF THE TREASURY LIQUORS WINE Production of Other Than Standard Wine § 24.213 Heavy bodied blending wine. Heavy bodied blending wine is wine made for blending purposes from grapes or other fruit without...

  15. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. II. P-TYPE BINARIES

    International Nuclear Information System (INIS)

    Haghighipour, Nader; Kaltenegger, Lisa

    2013-01-01

    We have developed a comprehensive methodology for calculating the circumbinary habitable zone (HZ) in planet-hosting P-type binary star systems. We present a general formalism for determining the contribution of each star of the binary to the total flux received at the top of the atmosphere of an Earth-like planet and use the Sun's HZ to calculate the inner and outer boundaries of the HZ around a binary star system. We apply our calculations to the Kepler's currently known circumbinary planetary systems and show the combined stellar flux that determines the boundaries of their HZs. We also show that the HZ in P-type systems is dynamic and, depending on the luminosity of the binary stars, their spectral types, and the binary eccentricity, its boundaries vary as the stars of the binary undergo their orbital motion. We present the details of our calculations and discuss the implications of the results

  16. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. II. P-TYPE BINARIES

    Energy Technology Data Exchange (ETDEWEB)

    Haghighipour, Nader [Institute for Astronomy and NASA Astrobiology Institute, University of Hawaii-Manoa, Honolulu, HI 96822 (United States); Kaltenegger, Lisa [MPIA, Koenigstuhl 17, Heidelberg, D-69117 (Germany)

    2013-11-10

    We have developed a comprehensive methodology for calculating the circumbinary habitable zone (HZ) in planet-hosting P-type binary star systems. We present a general formalism for determining the contribution of each star of the binary to the total flux received at the top of the atmosphere of an Earth-like planet and use the Sun's HZ to calculate the inner and outer boundaries of the HZ around a binary star system. We apply our calculations to the Kepler's currently known circumbinary planetary systems and show the combined stellar flux that determines the boundaries of their HZs. We also show that the HZ in P-type systems is dynamic and, depending on the luminosity of the binary stars, their spectral types, and the binary eccentricity, its boundaries vary as the stars of the binary undergo their orbital motion. We present the details of our calculations and discuss the implications of the results.

  17. [Blending powdered antineoplastic medicine in disposable ointment container].

    Science.gov (United States)

    Miyazaki, Yasunori; Uchino, Tomonobu; Kagawa, Yoshiyuki

    2014-01-01

    On dispensing powdered antineoplastic medicines, it is important to prevent cross-contamination and environmental exposure. Recently, we developed a method for blending powdered medicine in a disposable ointment container using a planetary centrifugal mixer. The disposable container prevents cross-contamination. In addition, environmental exposure associated with washing the apparatus does not arise because no blending blade is used. In this study, we aimed to confirm the uniformity of the mixture and weight loss of medicine in the blending procedure. We blended colored lactose powder with Leukerin(®) or Mablin(®) powders using the new method and the ordinary pestle and mortar method. Then, the blending state was monitored using image analysis. Blending variables, such as the blending ratio (1:9-9:1), container size (35-125 mL), and charging rate (20-50%) in the container were also investigated under the operational conditions of 500 rpm and 50 s. At a 20% charging rate in a 35 mL container, the blending precision of the mixtures was not influenced by the blending ratio, and was less than 6.08%, indicating homogeneity. With an increase in the charging rate, however, the blending precision decreased. The possible amount of both mixtures rose to about 17 g with a 20% charging rate in a 125 mL container. Furthermore, weight loss of medicines with this method was smaller than that with the pestle and mortar method, suggesting that this method is safer for pharmacists. In conclusion, we have established a precise and safe method for blending powdered medicines in pharmacies.

  18. The Optimum Blend: Affordances and Challenges of Blended Learning For Students

    Directory of Open Access Journals (Sweden)

    Nuray Gedik

    2012-03-01

    Full Text Available The purpose of this study was to elicit students’ perceptions regarding the most facilitative and most challenging features (affordances and barriers in a blended course design. Following the phenomenological approach of qualitative inquiry, data were collected from ten undergraduate students who had experiences in a blended learning environment. Data were collected from the students’ weekly reşection papers, interviews with students, and documents, and analyzed by structurally and texturally describing the resulting experiences and perceptions. The findings of the study indicate that used together, online and face-to-face course structures offer several opportunities and challenges for students. The participating students mentioned interaction and communication opportunities, increased motivation, increased opportunities to voice their opinions, and reinforcement of learning as the affordances in the blended learning environment. The barriers included increased workload, cultural and technical barriers, and the inter-dependence of the two environments. Implications and suggestions are offered for instructors in higher education settings

  19. The Optimum Blend: Affordances and Challenges of Blended Learning For Students

    Directory of Open Access Journals (Sweden)

    Nuray Gedik

    2012-07-01

    Full Text Available The purpose of this study was to elicit students’ perceptions regarding the most facilitative and most challenging features (affordances and barriers in a blended course design. Following the phenomenological approach of qualitative inquiry, data were collected from ten undergraduate students who had experiences in a blended learning environment. Data were collected from the students’ weekly reflection papers, interviews with students, and documents, and analyzed by structurally and texturally describing the resulting experiences and perceptions. The findings of the study indicate that used together, online and face-to-face course structures offer several opportunities and challenges for students. The participating students mentioned interaction and communication opportunities, increased motivation, increased opportunities to voice their opinions, and reinforcement of learning as the affordances in the blended learning environment. The barriers included increased workload, cultural and technical barriers, and the inter-dependence of the two environments. Implications and suggestions are offered for instructors in higher education settings.

  20. Wavelet and Blend maps for texture synthesis

    OpenAIRE

    Du Jin-Lian; Wang Song; Meng Xianhai

    2011-01-01

    blending is now a popular technology for large realtime texture synthesis .Nevertheless, creating blend map during rendering is time and computation consuming work. In this paper, we exploited a method to create a kind of blend tile which can be tile together seamlessly. Note that blend map is in fact a kind of image, which is Markov Random Field, contains multiresolution signals, while wavelet is a powerful way to process multiresolution signals, we use wavelet to process the traditional ble...

  1. Silk fibroin/pullulan blend films: Preparation and characterization

    Energy Technology Data Exchange (ETDEWEB)

    Shivananda, C. S.; Rao, B. Lakshmeesha; Madhukumar, R.; Asha, S. [Department of Studies in Physics, Mangalore University, Mangalagangotri – 574 199 (India); Sarojini, B. K. [Department of Industrial Chemistry, Mangalore University, Mangalagangotri, Mangalore –574 199 (India); Somashekhar, R. [Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore – 570 006 (India); Sangappa, Y., E-mail: syhalabhavi@yahoo.co.in [Department of Studies in Physics, Mangalore University, Mangalagangotri – 574 199 (India); School of Material Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332 (United States)

    2016-05-23

    In this work silk fibroin/pullulan blend films have been prepared by solution casting method. The blend films were examined for structural, and thermal properties using X-ray diffraction (XRD), thermogravimatric (TGA) and differential scanning calorimetry (DSC) analysis. The XRD results indicate that with the introduction of pullulan, the interaction between SF and pullulan in the blend films induced the conformation transition of SF films and amorphous phase increases with increasing pullulan ratio. The thermal properties of the blend films were improved significantly in the blend films.

  2. Correspondence Theory and Phonological Blending in French

    Directory of Open Access Journals (Sweden)

    Lee Scott

    2014-07-01

    Full Text Available Though less productive than rival word-formation processes like compounding and affixation, blending is still a rich source of neologisms in French. Despite this productivity, however, blends are often seen by scholars as unpredictable, uninteresting, or both. This analysis picks up where recent studies of blending have left off, using Correspondence Theory and a bundle of segmental constraints to deal with this phenomenon as it pertains to French. More specifically, it shows that blending is the result of a single output standing in correspondence with two or more other outputs, and that we do not need to refer to prosodic information, which is crucial in accounts of blending in languages with lexical stress like English, to account for the process in French. The analysis also differs from previous studies in that it locates blending exclusively within the phonology, leaving its morphological and semantic characteristics to be handled by other processes in the grammar.

  3. Blended working: for whom it may (not work.

    Directory of Open Access Journals (Sweden)

    Nico W Van Yperen

    Full Text Available Similarly to related developments such as blended learning and blended care, blended working is a pervasive and booming trend in modern societies. Blended working combines on-site and off-site working in an optimal way to improve workers' and organizations' outcomes. In this paper, we examine the degree to which workers feel that the two defining features of blended working (i.e., time-independent working and location-independent working enhance their own functioning in their jobs. Blended working, enabled through the continuing advance and improvement of high-tech ICT software, devices, and infrastructure, may be considered beneficial for workers' perceived effectiveness because it increases their job autonomy. However, because blended working may have downsides as well, it is important to know for whom blended working may (not work. As hypothesized, in a sample of 348 workers (51.7% women, representing a wide range of occupations and organizations, we found that the perceived personal effectiveness of blended working was contingent upon workers' psychological need strength. Specifically, the perceived effectiveness of both time-independent working and location-independent working was positively related to individuals' need for autonomy at work, and negatively related to their need for relatedness and need for structure at work.

  4. Moisture sorption and thermal characteristics of polyaramide blend fabrics

    OpenAIRE

    Genç, Gözde; Alp, Burcu; Balköse, Devrim; Ülkü, Semra; Cireli, Aysun

    2006-01-01

    Four types of fabrics woven from various polyaramid fibers of Nomex and Kevlar blends were characterized by morphology, XRD, elemental analysis, thermal analysis, and moisture adsorption isotherms. The blends consisted of Polybenzimidazole/ Kevlar blend (40% FBI and 60% Kevlar®), Nomex Delta A (blend of 60% Kevlar and 40% Nomex®), Nomex Delta T (blend of 75% Nomex, 23% Kevlar, and 2% P140 antistatic fiber), and Nomex III (fabric with a 95/5 blend of Nomex and Kevlar) containing 1% steel fiber...

  5. Close binary stars

    International Nuclear Information System (INIS)

    Larsson-Leander, G.

    1979-01-01

    Studies of close binary stars are being persued more vigorously than ever, with about 3000 research papers and notes pertaining to the field being published during the triennium 1976-1978. Many major advances and spectacular discoveries were made, mostly due to increased observational efficiency and precision, especially in the X-ray, radio, and ultraviolet domains. Progress reports are presented in the following areas: observational techniques, methods of analyzing light curves, observational data, physical data, structure and models of close binaries, statistical investigations, and origin and evolution of close binaries. Reports from the Coordinates Programs Committee, the Committee for Extra-Terrestrial Observations and the Working Group on RS CVn binaries are included. (Auth./C.F.)

  6. Using Blended Teaching to Teach Blended Learning: Lessons Learned from Pre-Service Teachers in an Instructional Methods Course

    Science.gov (United States)

    Shand, Kristen; Farrelly, Susan Glassett

    2017-01-01

    In this study, we explore the design and delivery of a blended social studies teaching methods course to examine the elements of the blended design that pre-service teachers found most constructive. In focus groups at the completion of the course, pre-service teachers were asked to reflect on their experience in the blended course, identify the…

  7. Massive Black Hole Binary Evolution

    Directory of Open Access Journals (Sweden)

    Merritt David

    2005-11-01

    Full Text Available Coalescence of binary supermassive black holes (SBHs would constitute the strongest sources of gravitational waves to be observed by LISA. While the formation of binary SBHs during galaxy mergers is almost inevitable, coalescence requires that the separation between binary components first drop by a few orders of magnitude, due presumably to interaction of the binary with stars and gas in a galactic nucleus. This article reviews the observational evidence for binary SBHs and discusses how they would evolve. No completely convincing case of a bound, binary SBH has yet been found, although a handful of systems (e.g. interacting galaxies; remnants of galaxy mergers are now believed to contain two SBHs at projected separations of <~ 1kpc. N-body studies of binary evolution in gas-free galaxies have reached large enough particle numbers to reproduce the slow, “diffusive” refilling of the binary’s loss cone that is believed to characterize binary evolution in real galactic nuclei. While some of the results of these simulations - e.g. the binary hardening rate and eccentricity evolution - are strongly N-dependent, others - e.g. the “damage” inflicted by the binary on the nucleus - are not. Luminous early-type galaxies often exhibit depleted cores with masses of ~ 1-2 times the mass of their nuclear SBHs, consistent with the predictions of the binary model. Studies of the interaction of massive binaries with gas are still in their infancy, although much progress is expected in the near future. Binary coalescence has a large influence on the spins of SBHs, even for mass ratios as extreme as 10:1, and evidence of spin-flips may have been observed.

  8. LENRA as compatibilizer in NR/HDPE blends

    International Nuclear Information System (INIS)

    Dahlan Mohd; Mahathir Mohamed

    2006-01-01

    Polymer blends of 60/40 NR/RDPE were prepared using Brabender PL2000 Plasticorder with 60 g capacity. The blends were added with radiation-sensitive natural rubber (NR)-based compatibilizer, known as LENRA. They were irradiated with electron-beam radiation at various doses. The efficacy of the compatibilizer was monitored by measuring various properties of the blends such as physical and dynamic mechanical properties including morphological studies by electron microscopic technique. Early results show that the addition of LENRA improves the properties of the TPNR blends. (Author)

  9. Blended learning within an undergraduate exercise physiology laboratory.

    Science.gov (United States)

    Elmer, Steven J; Carter, Kathryn R; Armga, Austin J; Carter, Jason R

    2016-03-01

    In physiological education, blended course formats (integration of face-to-face and online instruction) can facilitate increased student learning, performance, and satisfaction in classroom settings. There is limited evidence on the effectiveness of using blending course formats in laboratory settings. We evaluated the impact of blended learning on student performance and perceptions in an undergraduate exercise physiology laboratory. Using a randomized, crossover design, four laboratory topics were delivered in either a blended or traditional format. For blended laboratories, content was offloaded to self-paced video demonstrations (∼15 min). Laboratory section 1 (n = 16) completed blended laboratories for 1) neuromuscular power and 2) blood lactate, whereas section 2 (n = 17) completed blended laboratories for 1) maximal O2 consumption and 2) muscle electromyography. Both sections completed the same assignments (scored in a blinded manner using a standardized rubric) and practicum exams (evaluated by two independent investigators). Pre- and postcourse surveys were used to assess student perceptions. Most students (∼79%) watched videos for both blended laboratories. Assignment scores did not differ between blended and traditional laboratories (P = 0.62) or between sections (P = 0.91). Practicum scores did not differ between sections (both P > 0.05). At the end of the course, students' perceived value of the blended format increased (P learning key foundational content through video demonstrations before class greatly enhanced their learning of course material compared with a preassigned reading (94% vs. 78%, P Blended exercise physiology laboratories provided an alternative method for delivering content that was favorably perceived by students and did not compromise student performance. Copyright © 2016 The American Physiological Society.

  10. A Phase Blending Study on Rubber Blends Based on the Solubility Preference of Curatives

    NARCIS (Netherlands)

    Guo, R.; Talma, Auke; Datta, Rabin; Dierkes, Wilma K.; Noordermeer, Jacobus W.M.

    2009-01-01

    Using previously obtained data on the solubilities of curatives in SBR, EPDM and in NBR, different mixing procedures were performed on 50/50 SBR/EPDM and NBR/EPDM blends. In contrast to a previous phase-mixing study, the curatives were added to separate phases before final blending, in an attempt to

  11. Blended Learning: An Innovative Approach

    Science.gov (United States)

    Lalima; Dangwal, Kiran Lata

    2017-01-01

    Blended learning is an innovative concept that embraces the advantages of both traditional teaching in the classroom and ICT supported learning including both offline learning and online learning. It has scope for collaborative learning; constructive learning and computer assisted learning (CAI). Blended learning needs rigorous efforts, right…

  12. "Parasta oli, että työntekijä vaivautui tulemaan meille asti, monta kertaa." : Kokemuksia ratkaisukeskeisestä neuropsykiatrisesta valmennuksesta

    OpenAIRE

    Isomettä, Jenni

    2012-01-01

    Opinnäytetyön aihe nousi esiin Tampereen kaupungin lasten ja nuorten terveyspalveluiden OSMO-hankkeesta. Työelämätaho oli vakuuttunut tämänkaltaisen työn tarpeellisuudesta. OSMO-lyhenne tulee sanoista osaamisverkostoista monimuotoinen tuki lasten ja nuorten kehitysympäristöihin. Opinnäytetyössä kartoitettiin Tampereen kaupungin OSMO-hankkeen ratkaisukeskeiseen neuropsykiatriseen valmennukseen osallistuneiden kokemuksia valmennuksesta. Opinnäytetyössä selvitettiin, mitä he ovat kokeneet valmen...

  13. LENRA as compatibilizer in NR/HDPE blends

    International Nuclear Information System (INIS)

    Mahathir Mohamed; Dahlan Mohd

    2004-01-01

    Polymer blends of 60/40 NR/HDPE were prepared using Brabender PL2000 plasticorder with 60g capacity. The blends were added with radiation sensitive natural rubber (NR)-based compatibilizer, known as LENRA. They were irradiated in air with electron beam radiation at various doses. The efficacy of the compatibilizer was monitored by measuring various properties of the blends such as physical and dynamic mechanical properties including morphological studies by electron microscopic technique. Early results show that the addition of LENRA improves the properties of the TPNR blends. (Author)

  14. Performance evaluation of gamma irradiated SiR-EPDM blends

    Energy Technology Data Exchange (ETDEWEB)

    Deepalaxmi, R., E-mail: deepalaxmivaithi@gmail.com; Rajini, V.

    2014-07-01

    Highlights: • The effects of gamma irradiation on SiR-EPDM blend are examined. • Cross-linking reaction is dominant in blends C, D and E, due to higher EPDM content. • The tensile strength and hardness of blend E is improved by gamma irradiation. • The blend C and EPDM rich blends (D, E) are found to have superior performance. • Among C, D and E, suitable blend can be selected for a particular NPP application. - Abstract: Cable insulation materials (CIM) should perform their safety functions throughout their installed life in nuclear power plants (NPP). The CIM will be exposed to gamma irradiation at the installed locations. In order to forecast long-term performance of CIM, the short time accelerated testing was carried out. Due to its good mechanical strength, ethylene propylene diene monomer (EPDM) is widely used as CIM. Silicone rubber (SiR) is used in high temperature environments, due to its good di-electric properties/hydrophobicity. The blending of these two polymers may result in the improvement in their specific properties. This paper analyses the effects of gamma irradiation on the five different compositions (90-10; 70-30; 50-50; 30-70; 10-90) of SiR-EPDM blends. The blends were exposed to four different doses (25 Mrad, 100 Mrad, 200 Mrad and 250 Mrad) of gamma irradiation. The electrical and mechanical parameters like volume resistivity (VRY), surface resistivity (SRY), tensile strength (TS), elongation at break (EB), hardness (H) of the virgin and gamma irradiated blends were determined as per ASTM/IEC standards. The nature of degradation was investigated using Fourier transform infrared spectroscopy (FTIR). The simultaneous occurrence of cross-linking and chain scission is found to be the mechanism for ageing in SiR-EPDM blends. The electrical parameters such as volume resistivity and surface resistivity of all the blends are found to improve for all doses of gamma irradiation. To validate the influence of cross-linking reaction of the Si

  15. Blended Learning: A Dangerous Idea?

    Science.gov (United States)

    Moskal, Patsy; Dziuban, Charles; Hartman, Joel

    2013-01-01

    The authors make the case that implementation of a successful blended learning program requires alignment of institutional, faculty, and student goals. Reliable and robust infrastructure must be in place to support students and faculty. Continuous evaluation can effectively track the impact of blended learning on students, faculty, and the…

  16. Empowering Learners through Blended Learning

    Science.gov (United States)

    Owston, Ron

    2018-01-01

    Blended learning appears to facilitate learner empowerment more readily than either face-to-face or fully online courses. This contention is supported by a review of literature on the affordances of blended learning that support Thomas and Velthouse's (1990) four conditions of empowerment: choice, meaningfulness, competence, and impact. Blended…

  17. The Basics of Blended Instruction

    Science.gov (United States)

    Tucker, Catlin R.

    2013-01-01

    Even though many of teachers do not have technology-rich classrooms, the rapidly evolving education landscape increasingly requires them to incorporate technology to customize student learning. Blended learning, with its mix of technology and traditional face-to-face instruction, is a great approach. Blended learning combines classroom learning…

  18. The Art of Blending: Benefits and Challenges of a Blended Course for Preservice Teachers

    Science.gov (United States)

    Shand, Kristen; Farrelly, Susan Glassett

    2018-01-01

    In this study, we explore the design and delivery of a blended social studies teaching methods course according to principles and core attributes of blended course design. In a survey at the end of the course, pre-service teachers were asked to reflect on their experience in the course, and identify the benefits and challenges of the blended…

  19. Tank 21 and Tank 24 Blend and Feed Study: Blending Times, Settling Times, and Transfers

    International Nuclear Information System (INIS)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-01-01

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 (micro)m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion ( 60 days) settling times in Tank 21.

  20. Study of the refractive index of gasoline+alcohol pseudo-binary mixtures

    Directory of Open Access Journals (Sweden)

    Nita Irina

    2017-02-01

    Full Text Available The properties of gasoline change as a result of blending with a bioalcohol, affecting the behavior of the pseudo-binary system. The aim of this paper is to present experimental data of the refractive index for pseudobinary mixtures of a reformate gasoline with ethanol, isopropanol and n-butanol over the entire composition range and for temperature ranging from 293.15 K to 313.15 K. The accuracy of different equations to predict the refractive index of the mixtures was tested. The best prediction accuracy (the lower AAD corresponded to Eykman and Lorentz-Lorenz mixing rules. A logarithmic equation proposed to correlate the refractive index with composition and temperature of gasoline+alcohol mixtures showed a good accuracy (the absolute average deviation AAD < 0.052%. The deviations in refractive index for investigated systems are negative over the entire composition range and at all investigated temperatures.

  1. Silk fibroin membranes from solvent-crystallized silk fibroin/gelatin blends: Effects of blend and solvent composition

    Energy Technology Data Exchange (ETDEWEB)

    Gil, Eun S. [Fiber and Polymer Science Program, North Carolina State University, Raleigh, NC 27695 (United States); Frankowski, David J. [Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, NC 27695 (United States); Hudson, Samuel M. [Fiber and Polymer Science Program, North Carolina State University, Raleigh, NC 27695 (United States); Spontak, Richard J. [Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, NC 27695 (United States) and Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695 (United States)]. E-mail: Rich_Spontak@ncsu.edu

    2007-04-15

    Protein membranes have been prepared by mixing gelatin (G) with Bombyx mori silk fibroin (SF) and using aqueous methanol (MeOH) to induce SF crystallization. Amorphous blends of these polymers appear quasi-homogeneous, as discerned from visual observation, electron microscopy and Fourier-transform infrared (FTIR) spectroscopy. Upon subsequent exposure to aqueous MeOH, SF undergoes a conformational change from random-coil to {beta}-sheet. This transformation occurs in pure SF, as well as in each of the G/SF blends, as discerned from FTIR spectroscopy and thermal calorimetry. The influence of MeOH-induced SF crystallization on structure and property development has been measured as functions of blend and solvent composition. By preserving a support scaffold above the G helix-to-coil transition temperature, the formation of crystalline SF networks in G/SF blends can be used to stabilize G-based hydrogels or generate SF membranes for biomaterial, pharmaceutical and gas-separation purposes. The present study not only examines the properties of G/SF blends before and after SF crystallization, but also establishes the foundation for future research into thermally-responsive G/SF bioconjugates.

  2. NESDIS Blended Rain Rate (RR) Products

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The blended Rain Rate (RR) product is derived from multiple sensors/satellites. The blended products were merged from polar-orbiting and geostationary satellite...

  3. Efficient Approach for Improving the Performance of Nonhalogenated Green Solvent-Processed Polymer Solar Cells via Ternary-Blend Strategy.

    Science.gov (United States)

    Kranthiraja, Kakaraparthi; Aryal, Um Kanta; Sree, Vijaya Gopalan; Gunasekar, Kumarasamy; Lee, Changyeon; Kim, Minseok; Kim, Bumjoon J; Song, Myungkwan; Jin, Sung-Ho

    2018-04-10

    The ternary-blend approach has the potential to enhance the power conversion efficiencies (PCEs) of polymer solar cells (PSCs) by providing complementary absorption and efficient charge generation. Unfortunately, most PSCs are processed with toxic halogenated solvents, which are harmful to human health and the environment. Herein, we report the addition of a nonfullerene electron acceptor 3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3- d:2',3'- d']- s-indaceno[1,2- b:5,6- b']dithiophene (ITIC) to a binary blend (poly[4,8-bis(2-(4-(2-ethylhexyloxy)3-fluorophenyl)-5-thienyl)benzo[1,2- b:4,5- b']dithiophene- alt-1,3-bis(4-octylthien-2-yl)-5-(2-ethylhexyl)thieno[3,4- c]pyrrole-4,6-dione] (P1):[6,6]-phenyl-C 71 -butyric acid methyl ester (PC 71 BM), PCE = 8.07%) to produce an efficient nonhalogenated green solvent-processed ternary PSC system with a high PCE of 10.11%. The estimated wetting coefficient value (0.086) for the ternary blend suggests that ITIC could be located at the P1:PC 71 BM interface, resulting in efficient charge generation and charge transport. In addition, the improved current density, sustained open-circuit voltage and PCE of the optimized ternary PSCs were highly correlated with their better external quantum efficiency response and flat-band potential value obtained from the Mott-Schottky analysis. In addition, the ternary PSCs also showed excellent ambient stability over 720 h. Therefore, our results demonstrate the combination of fullerene and nonfullerene acceptors in ternary blend as an efficient approach to improve the performance of eco-friendly solvent-processed PSCs with long-term stability.

  4. Novel bio-based and biodegradable polymer blends

    Science.gov (United States)

    Yang, Shengzhe

    Most plastic materials, including high performance thermoplastics and thermosets are produced entirely from petroleum-based products. The volatility of the natural oil markets and the increasing cost of petroleum have led to a push to reduce the dependence on petroleum products. Together with an increase in environmental awareness, this has promoted the use of alternative, biorenewable, environmentally-friendly products, such as biomass. The growing interest in replacing petroleum-based products by inexpensive, renewable, natural materials is important for sustainable development into the future and will have a significant impact on the polymer industry and the environment. This thesis involved characterization and development of two series of novel bio-based polymer blends, namely polyhydroxyalkanoate (PHA)/polyamide (PA) and poly(lactic acid) (PLA)/soy protein. Blends with different concentrations and compatible microstructures were prepared using twin-screw extruder. For PHA/PA blends, the poor mechanical properties of PHA improved significantly with an excellent combination of strength, stiffness and toughness by adding PA. Furthermore, the effect of blending on the viscoelastic properties has been investigated using small-amplitude oscillatory shear flow experiments as a function of blend composition and angular frequency. The elastic shear modulus (G‧) and complex viscosity of the blends increased significantly with increasing the concentration of PHA. Blending PLA with soy protein aims at reducing production cost, as well as accelerating the biodegradation rate in soil medium. In this work, the mechanical, thermal and morphological properties of the blends were investigated using dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile tests.

  5. The processing of blend words in naming and sentence reading.

    Science.gov (United States)

    Johnson, Rebecca L; Slate, Sarah Rose; Teevan, Allison R; Juhasz, Barbara J

    2018-04-01

    Research exploring the processing of morphologically complex words, such as compound words, has found that they are decomposed into their constituent parts during processing. Although much is known about the processing of compound words, very little is known about the processing of lexicalised blend words, which are created from parts of two words, often with phoneme overlap (e.g., brunch). In the current study, blends were matched with non-blend words on a variety of lexical characteristics, and blend processing was examined using two tasks: a naming task and an eye-tracking task that recorded eye movements during reading. Results showed that blend words were processed more slowly than non-blend control words in both tasks. Blend words led to longer reaction times in naming and longer processing times on several eye movement measures compared to non-blend words. This was especially true for blends that were long, rated low in word familiarity, but were easily recognisable as blends.

  6. Evaluation of non-linear blending in dual-energy computed tomography

    International Nuclear Information System (INIS)

    Holmes, David R.; Fletcher, Joel G.; Apel, Anja; Huprich, James E.; Siddiki, Hassan; Hough, David M.; Schmidt, Bernhard; Flohr, Thomas G.; Robb, Richard; McCollough, Cynthia; Wittmer, Michael; Eusemann, Christian

    2008-01-01

    Dual-energy CT scanning has significant potential for disease identification and classification. However, it dramatically increases the amount of data collected and therefore impacts the clinical workflow. One way to simplify image review is to fuse CT datasets of different tube energies into a unique blended dataset with desirable properties. A non-linear blending method based on a modified sigmoid function was compared to a standard 0.3 linear blending method. The methods were evaluated in both a liver phantom and patient study. The liver phantom contained six syringes of known CT contrast which were placed in a bovine liver. After scanning at multiple tube currents (45, 55, 65, 75, 85, 95, 105, and 115 mAs for the 140-kV tube), the datasets were blended using both methods. A contrast-to-noise (CNR) measure was calculated for each syringe. In addition, all eight scans were normalized using the effective dose and statistically compared. In the patient study, 45 dual-energy CT scans were retrospectively mixed using the 0.3 linear blending and modified sigmoid blending functions. The scans were compared visually by two radiologists. For the 15, 45, and 64 HU syringes, the non-linear blended images exhibited similar CNR to the linear blended images; however, for the 79, 116, and 145 HU syringes, the non-linear blended images consistently had a higher CNR across dose settings. The radiologists qualitatively preferred the non-linear blended images of the phantom. In the patient study, the radiologists preferred non-linear blending in 31 of 45 cases with a strong preference in bowel and liver cases. Non-linear blending of dual energy data can provide an improvement in CNR over linear blending and is accompanied by a visual preference for non-linear blended images. Further study on selection of blending parameters and lesion conspicuity in non-linear blended images is being pursued

  7. Classifying K-12 Blended Learning

    Science.gov (United States)

    Staker, Heather; Horn, Michael B.

    2012-01-01

    The growth of online learning in the K-12 sector is occurring both remotely through virtual schools and on campuses through blended learning. In emerging fields, definitions are important because they create a shared language that enables people to talk about the new phenomena. The blended-learning taxonomy and definitions presented in this paper…

  8. Modified Optimization Water Index (mowi) for LANDSAT-8 Oli/tirs

    Science.gov (United States)

    Moradi, M.; Sahebi, M.; Shokri, M.

    2017-09-01

    Water is one of the most important resources that essential need for human life. Due to population growth and increasing need of human to water, proper management of water resources will be one of the serious challenges of next decades. Remote sensing data is the best way to the management of water resources due time and cost effectiveness over a greater range of temporal and spatial scales. Between many kinds of satellite data, from SAR to optic or from high resolution to low resolution, Landsat imagery is more interesting data for water detection and management of earth surface water. Landsat8 OLI/TIRS is the newest version of Landsat satellite series. In this paper, we investigated the full spectral potential of Landsat8 for water detection. It is developed many kinds of methods for this purpose that index based methods have some advantages than other methods. Pervious indices just use a limited number of spectral band. In this paper, Modified Optimization Water Index (MOWI) defined by consideration of a linear combination of bands that each coefficient of bands calculated by particle swarm algorithm. The result shows that modified optimization water index (MOWI) has a proper performance on different condition like cloud, cloud shadow and mountain shadow.

  9. Radiation crosslinking of polymer blends

    International Nuclear Information System (INIS)

    Spenadel, L.

    1979-01-01

    Rocked by the one-two punch of rising energy costs and tougher pollution controls, a growing number of companies are looking to radiation crosslinking as a cheaper, cleaner alternative to heat and costly chemical crosslinking agents such as peroxides. With the development of larger, more powerful electron beam machines it is now possible to irradiate parts as thick as 400 mils in a single pass. Two application areas which have been investigated at our laboratory are the electron beam processing of thermoplastic elastomeric automotive parts and EPDM electrical insulation. This paper covers work carried out to develop the necessary technology base for the radiation crosslinking of ethylene propylene/polyolefin blends. Initial results indicate that EP/PE blends of electrical insulation quality cross-link quite readily when irradiated. On the other hand, EP/PP blends developed for automotive fascia require the addition of crosslinking monomers such as trimethylol propane trimethacrylate in order for crosslinking to predominate over chain scission. Crosslinking EP/PP blends improve mar resistance, flexural set and deformation at elevated temperatures. These are all key properties for automotive fascia. (author)

  10. Radiation processing of thermoplastic starch by blending aromatic additives: Effect of blend composition and radiation parameters

    Science.gov (United States)

    Khandal, Dhriti; Mikus, Pierre-Yves; Dole, Patrice; Coqueret, Xavier

    2013-03-01

    This paper reports on the effects of electron beam (EB) irradiation on poly α-1,4-glucose oligomers (maltodextrins) in the presence of water and of various aromatic additives, as model blends for gaining a better understanding at a molecular level the modifications occurring in amorphous starch-lignin blends submitted to ionizing irradiation for improving the properties of this type of bio-based thermoplastic material. A series of aromatic compounds, namely p-methoxy benzyl alcohol, benzene dimethanol, cinnamyl alcohol and some related carboxylic acids namely cinnamic acid, coumaric acid, and ferulic acid, was thus studied for assessing the ability of each additive to counteract chain scission of the polysaccharide and induce interchain covalent linkages. Gel formation in EB-irradiated blends comprising of maltodextrin was shown to be dependent on three main factors: the type of aromatic additive, presence of glycerol, and irradiation dose. The chain scission versus grafting phenomenon as a function of blend composition and dose were studied using Size Exclusion Chromatography by determining the changes in molecular weight distribution (MWD) from Refractive Index (RI) chromatograms and the presence of aromatic grafts onto the maltodextrin chains from UV chromatograms. The occurrence of crosslinking was quantified by gel fraction measurements allowing for ranking the cross-linking efficiency of the additives. When applying the method to destructurized starch blends, gel formation was also shown to be strongly affected by the moisture content of the sample submitted to irradiation. The results demonstrate the possibility to tune the reactivity of tailored blend for minimizing chain degradation and control the degree of cross-linking.

  11. The fate of close encounters between binary stars and binary supermassive black holes

    Science.gov (United States)

    Wang, Yi-Han; Leigh, Nathan; Yuan, Ye-Fei; Perna, Rosalba

    2018-04-01

    The evolution of main-sequence binaries that reside in the Galactic Centre can be heavily influenced by the central supermassive black hole (SMBH). Due to these perturbative effects, the stellar binaries in dense environments are likely to experience mergers, collisions, or ejections through secular and/or non-secular interactions. More direct interactions with the central SMBH are thought to produce hypervelocity stars (HVSs) and tidal disruption events (TDEs). In this paper, we use N-body simulations to study the dynamics of stellar binaries orbiting a central SMBH primary with an outer SMBH secondary orbiting this inner triple. The effects of the secondary SMBH on the event rates of HVSs, TDEs, and stellar mergers are investigated, as a function of the SMBH-SMBH binary mass ratio. Our numerical experiments reveal that, relative to the isolated SMBH case, the TDE and HVS rates are enhanced for, respectively, the smallest and largest mass ratio SMBH-SMBH binaries. This suggests that the observed event rates of TDEs and HVSs have the potential to serve as a diagnostic of the mass ratio of a central SMBH-SMBH binary. The presence of a secondary SMBH also allows for the creation of hypervelocity binaries. Observations of these systems could thus constrain the presence of a secondary SMBH in the Galactic Centre.

  12. Characterization of polycaprolactone and starch blends for potential ...

    African Journals Online (AJOL)

    Thermally blending starch and polycaprolactone with the compatibilizer methylenediphenyl diisocyanate (MDI) distributed in the polyester phase had been previously confirmed to enhance the mechanical properties and interface between the two phases of the blends. In this study, blends of polycaprolactone with various ...

  13. Solving a binary puzzle

    NARCIS (Netherlands)

    Utomo, P.H.; Makarim, R.H.

    2017-01-01

    A Binary puzzle is a Sudoku-like puzzle with values in each cell taken from the set {0,1} {0,1}. Let n≥4 be an even integer, a solved binary puzzle is an n×n binary array that satisfies the following conditions: (1) no three consecutive ones and no three consecutive zeros in each row and each

  14. Blending effects on coal burnout and NO emissions

    Energy Technology Data Exchange (ETDEWEB)

    B. Arias; R. Backreedy; A. Arenillas; J.M. Jones; F. Rubiera; M. Pourkashanian; A. Williams; J.J. Pis [Instituto Nacional del Carbon, CSIC Oviedo (Spain)

    2003-07-01

    In this work, the combustion behaviour of individual coals of different rank and their blends was evaluated. The study was focused on burnout and NO emissions during blend combustion. Preliminary combustion tests of the coals and their blends were carried out in a thermogravimetric analyser (TGA). Some characteristic temperatures were obtained to evaluate the combustibility of the samples. These temperatures indicate an improvement in the combustibility of the less reactive coal when it is blended. An entrained flow reactor (EFR) was employed to study the behaviour of the samples at high heating rates and short residence times. Burnout and NO emissions were measured during EFR combustion tests. In some blends the results can be predicted from the weighted average of the values of the individual coals. However, other blends show an increase, from the averaged values, in burnout and especially in NO emissions. 14 refs., 10 figs., 3 tabs.

  15. BLENDED LEARNING COURSE FOR FUTURE PRIMARY SCHOOL TEACHERS IMPLEMENTATION

    Directory of Open Access Journals (Sweden)

    Vira V. Kotkova

    2017-09-01

    Full Text Available Ukrainian and foreign scientists’ views on the essence of blended learning are analyzed in the article. The author's definition of a blended learning course is presented. The process of such course designing is described according to target, motivational, substantive, operational and diagnostic components. Both the structure of the blended learning course implementation as well as students’ educational-cognitive activity distribution between classroom learning and distance course are shown. The problems for students, teachers, and educational institutions of blended courses effective implementation are summarized. Students’ academic performance of three years study is analyzed. The results of students’ questioning to determine their perception of blended learning course are described according to the following categories: the effectiveness of blended course, evaluation objectivity, motivation to study, the use of plagiarism in studies, understanding of blended learning course.

  16. Synthesis of geopolymer from biomass-coal ash blends

    Science.gov (United States)

    Samadhi, Tjokorde Walmiki; Wulandari, Winny; Prasetyo, Muhammad Iqbal; Fernando, Muhammad Rizki; Purbasari, Aprilina

    2017-09-01

    Geopolymer is an environmentally attractive Portland cement substitute, owing to its lower carbon footprint and its ability to consume various aluminosilicate waste materials as its precursors. This work describes the development of geopolymer formulation based on biomass-coal ash blends, which is predicted to be the prevalent type of waste when biomass-based thermal energy production becomes mainstream in Indonesia. The ash blends contain an ASTM Class F coal fly ash (FA), rice husk ash (RHA), and coconut shell ash (CSA). A mixture of Na2SiO3 and concentrated KOH is used as the activator solution. A preliminary experiment identified the appropriate activator/ash mass ratio to be 2.0, while the activator Na2SiO3/KOH ratio varies from 0.8 to 2.0 with increasing ash blend Si/Al ratio. Both non-blended FA and CSA are able to produce geopolymer mortars with 7-day compressive strength exceeding the Indonesian national SNI 15-2049-2004 standard minimum value of 2.0 MPa stipulated for Portland cement mortars. Ash blends have to be formulated with a maximum RHA content of approximately 50 %-mass to yield satisfactory 7-day strength. No optimum ash blend composition is identified within the simplex ternary ash blend compositional region. The strength decreases with Si/Al ratio of the ash blends due to increasing amount of unreacted silicate raw materials at the end of the geopolymer hardening period. Overall, it is confirmed that CSA and blended RHA are feasible raw materials for geopolymer production..

  17. Enzymatic degradation of polycaprolactone–gelatin blend

    International Nuclear Information System (INIS)

    Banerjee, Aditi; Chatterjee, Kaushik; Madras, Giridhar

    2015-01-01

    Blends of polycaprolactone (PCL), a synthetic polymer and gelatin, natural polymer offer a optimal combination of strength, water wettability and cytocompatibility for use as a resorbable biomaterial. The enzymatic degradation of PCL, gelatin and PCL–gelatin blended films was studied in the presence of lipase (Novozym 435, immobilized) and lysozyme. Novozym 435 degraded the PCL films whereas lysozyme degraded the gelatin. Though Novozym 435 and lysozyme individually could degrade PCL–gelatin blended films, the combination of these enzymes showed the highest degradation of these blended films. Moreover, the enzymatic degradation was much faster when fresh enzymes were added at regular intervals. The changes in physico-chemical properties of polymer films due to degradation were studied by scanning electron microscopy, Fourier transform infrared spectroscopy and differential scanning calorimetry. These results have important implications for designing resorbable biomedical implants. (paper)

  18. EVA reactive blending with Si–H terminated polysiloxane by carbonyl hydrosilylation reaction: From compatibilised blends to crosslinking networks

    International Nuclear Information System (INIS)

    Bonnet, J.; Bounor-Legaré, V.; Alcouffe, P.; Cassagnau, P.

    2012-01-01

    A new and original method based on carbonyl hydrosilylation was developed to prepare ethylene-vinyl acetate (EVA)/polysiloxane polymer blends. This focused on the addition of hydrogenosilane groups (SiH) from polysiloxane to the carbonyl groups of EVA. The influence of the nature of the polysiloxane on blend properties was investigated by rheology and scanning electron microscopy. Mixing of a low viscosity polysiloxane with a high viscosity EVA matrix produced a two-phase morphology. The occurrence of the hydrosilylation reaction at the EVA/polysiloxane interface promoted a homogenisation of the blend depending on the molar ratio SiH/vinyl acetate groups, [SiH]/[VA], and the viscosity ratio of the blend. Two distinct behaviours were observed. The formation of a crosslinked network under shear was obtained for a low viscosity ratio between polysiloxane and EVA (λ polysiloxane/EVA = 4.0 × 10 −6 ) with a high concentration of SiH groups ([SiH]/[VA] = 0.5), while the formation of a compatibilised blend was observed for high molar mass polysiloxanes (Mn > 15,000 g mol −1 ) with a low concentration of SiH ([SiH]/[VA] −3 ). -- Highlights: ► Carbonyl hydrosilylation reaction was found to enhance EVA/polysiloxane immiscible blends. ► EVA crosslinking was obtained with a low molar mass polysiloxane. ► EVA compatibilisation was obtained with a high molar mass polysiloxane. ► Shear rate was found to improve the hydrosilylation reaction at the interface. ► A two-phase morphology of the blends was observed after reaction with fine polysiloxane nodules.

  19. BioBlend.objects: metacomputing with Galaxy.

    Science.gov (United States)

    Leo, Simone; Pireddu, Luca; Cuccuru, Gianmauro; Lianas, Luca; Soranzo, Nicola; Afgan, Enis; Zanetti, Gianluigi

    2014-10-01

    BioBlend.objects is a new component of the BioBlend package, adding an object-oriented interface for the Galaxy REST-based application programming interface. It improves support for metacomputing on Galaxy entities by providing higher-level functionality and allowing users to more easily create programs to explore, query and create Galaxy datasets and workflows. BioBlend.objects is available online at https://github.com/afgane/bioblend. The new object-oriented API is implemented by the galaxy/objects subpackage. © The Author 2014. Published by Oxford University Press.

  20. Game innovation through conceptual blending

    DEFF Research Database (Denmark)

    Möring, Sebastian Martin

    In  this  paper  I  wish  to  apply implications of  the  Conceptual  Blending  Theory  to  computer  games.  I  will  analyze  chosen  examples  and  discuss  them  as  a  result  of  video  game  innovation  made  possible  through  "conceptual  blending."  Conceptual  blending  links  at  least.......,  Hell.  The  purpose  of  my  approach  is  not  so  much  to  validate  the  ideas  of  conceptual  blending  theory  through  another  field  of  examples  (computer  games)  but  to  name  and analyze characteristics of the mentioned games with the  help of a given method.......  integration  network  consisting  of  at  least  two  input  spaces,  a  generic  space  and  a  blended  space  as  well  as  its  governing  principles  consisting  of  composition,  completion,  and  elaboration.  With  the  help  of  these  instruments  I  analyze computer  games like  Tuper  Tario  Tros...

  1. A study of coal-solid waste blend reactivity

    Directory of Open Access Journals (Sweden)

    Nayibe Guerrero

    2008-05-01

    Full Text Available The Flynn-Wall-Ozawa method was used for analysing coal-solid waste blend reactivity in an oxidising atmosphere. The presence of biomass strongly affected coal combustion kinetics when the blend contained more than 30% of it. Activation energy values (evaluated by different blends were 28.7495 kJ/mol for 0% biomass, 31.3915 kJ/mol for 30% biomass, 39.0365 kJ/mol for 50% biomass, 102.431 kJ/mol for 70% biomass and 107.8075 kJ/mol for 100% biomass; these values were close to those reported in the literature. First-order kinetics correlated the data ve-ry well for the 100% coal sample and the blend having 30% biomass and 70% coal. Eighth-order kinetics were more suitable for correlating the experimental data for the 70% biomass-30% coal blend and the 100% biomass sample. Combustion was done without previous pyrolysis of the blends; however segregation of phenomena could be appre-ciated. This seems to indicate that combustion and devolatilisation are independent processes which should be taken into account when building equipment using these kinds of blend.

  2. Radiation effects on the immiscible polymer blend of nylon1010 and high-impact polystyrene (HIPS) I: Gel/dose curves, mathematical expectation theorem and thermal behaviour

    International Nuclear Information System (INIS)

    Dong, W.; Zhang, W.; Chen, G.; Liu, J.

    2000-01-01

    This paper studies the radiation properties of the immiscible blend of nylon1010 and HIPS. The gel fraction increased with increasing radiation dose. The network was found mostly in nylon1010, the networks were also found in both nylon1010 and HIPS when the dose reaches 0.85 MGy or more. We used the equation and the modified Zhang-Sun-Qian equation to simulate the relationship with the dose and the sol fraction. The latter equation fits well with these polymer blends and the relationship used by it showed better linearity than the one by the equation. We also studied the conditions of formation of the network by the mathematical expectation theorem for the binary system. Thermal properties of polymer blend were observed by DSC curves. The crystallization temperature decreases with increasing dose because the cross-linking reaction inhibited the crystallization procession and destroyed the crystals. The melting temperature also reduced with increasing radiation dose. The dual melting peak gradually shifted to single peak and the high melting peak disappeared at high radiation dose. However, the radiation-induced crystallization was observed by the heat of fusion increasing at low radiation dose. On the other hand, the crystal will be damaged by radiation. A similar conclusion may be drawn by the DSC traces when the polymer blends were crystallized. When the radiation dose increases, the heat of fusion reduces dramatically and so does the heat of crystallization. (author)

  3. Blended Learning as Transformational Institutional Learning

    Science.gov (United States)

    VanDerLinden, Kim

    2014-01-01

    This chapter reviews institutional approaches to blended learning and the ways in which institutions support faculty in the intentional redesign of courses to produce optimal learning. The chapter positions blended learning as a strategic opportunity to engage in organizational learning.

  4. The oligodendroglial precursor cell line Oli-neu represents a cell culture system to examine functional expression of the mouse gap junction gene connexin29 (Cx29

    Directory of Open Access Journals (Sweden)

    Goran Christoph Söhl

    2013-06-01

    Full Text Available The potential gap junction forming mouse connexin29 (Cx29 protein is concomitantly expressed with connexin32 (Cx32 in peripheral myelin forming Schwann cells and together with both Cx32 and connexin47 (Cx47 in oligodendrocytes of the CNS. To study the genomic structure and functional expression of Cx29, either primary cells or cell culture systems might be selected, from which the latter are easier to cultivate. Both structure and expression of Cx29 is still not fully understood. In the mouse sciatic nerve, brain and the oligodendroglial precursor cell line Oli-neu the Cx29 gene is processed in two transcript isoforms both harbouring a unique reading frame. In contrast to Cx32 and Cx47, only Cx29 protein is abundantly expressed in undifferentiated as well as differentiated Oli-neu cells but the absence of Etbr dye transfer after microinjection concealed the function of Cx29 mediated gap junction communication between those cells. Although HeLa cells stably transfected with Cx29 or Cx29-eGFP neither demonstrated any permeability for Lucifer yellow nor for neurobiotin, blocking of Etbr uptake from the media by gap junction blockers does suppose a role of Cx29 in hemi-channel function. Thus, we conclude that, due to its high abundance of Cx29 expression and its reproducible culture conditions, the oligodendroglial precursor cell line Oli-neu might constitute an appropriate cell culture system to study molecular mechanisms or putative extracellular stimuli to functionally open Cx29 channels or hemi-channels.

  5. Blended Learning within an Undergraduate Exercise Physiology Laboratory

    Science.gov (United States)

    Elmer, Steven J.; Carter, Kathryn R.; Armga, Austin J.; Carter, Jason R.

    2016-01-01

    In physiological education, blended course formats (integration of face-to-face and online instruction) can facilitate increased student learning, performance, and satisfaction in classroom settings. There is limited evidence on the effectiveness of using blending course formats in laboratory settings. We evaluated the impact of blended learning…

  6. Potential Application of ENR/EPDM Blends

    Directory of Open Access Journals (Sweden)

    B.L. Chan

    2017-06-01

    Full Text Available Since the process and conversion of natural rubber into epoxidized natural rubber (ENR was discovered and patented by I. R. Gelling of the Malaysian Rubber Product Research Association  (or now known as the Tun Razak laboratory, Brickendonbury, Hertford, in the United Kingdom, there are more than 10 000 technical and technological papers cited in the internet. Information on ENR is available, not only in the the English language but also other languages like Chinese, Malay, French, Thai and even German languages are used. NR is the most versatile and reactive rubber/elastomer. It is an advanced natural rubber which could be potentially used as a starting material for the development of other rubbers, modifie elastomers, for grafting, plastic-based materials and also thermoplastic rubbers. Its reactivity is dependent on its epoxy groups, the opening of its ring structure, and also the subsequent structures of carboxylic groups and the in-situ side-chains “carbon – carbon” double bonds (> C = C <. In some instances, up to 65% epoxidation of NR is possible and achieved for more oil resistance. For these reasons, there are many new and advanced materials which have been formed and developed in the last two decades. Among them, some of the recent research work is listed here. Apart from studies of compounding the ENR itself and its potential uses, there are many rubber-rubber blends and ENR rubber-plastics blends, some of the studies cited are “uses of new and advanced chemicals”  and synthetic rubbers:  ENR/NBR, ENR/PVC, ENR/polylactic acid blends, ENR/copolyester blends, ENR/Copolyamide Blends, ENR/poly (vinylidene fluorideblends, ENR/Carbon Nanotubes with co-agent Trimethylol Propane Triacrylate, ENR /recycled silicon materials, and ENR/copolymer of n-butyl acrylate/butyl methacrylate “grafted”. Each of these blends has its own characteristics in terms of processing, enhancement of processing like safety, scorch, oil and water

  7. Teaching of anatomical sciences: A blended learning approach.

    Science.gov (United States)

    Khalil, Mohammed K; Abdel Meguid, Eiman M; Elkhider, Ihsan A

    2018-04-01

    Blended learning is the integration of different learning approaches, new technologies, and activities that combine traditional face-to-face teaching methods with authentic online methodologies. Although advances in educational technology have helped to expand the selection of different pedagogies, the teaching of anatomical sciences has been challenged by implementation difficulties and other limitations. These challenges are reported to include lack of time, costs, and lack of qualified teachers. Easy access to online information and advances in technology make it possible to resolve these limitations by adopting blended learning approaches. Blended learning strategies have been shown to improve students' academic performance, motivation, attitude, and satisfaction, and to provide convenient and flexible learning. Implementation of blended learning strategies has also proved cost effective. This article provides a theoretical foundation for blended learning and proposes a validated framework for the design of blended learning activities in the teaching and learning of anatomical sciences. Clin. Anat. 31:323-329, 2018. © 2018 Wiley Periodicals, Inc. © 2018 Wiley Periodicals, Inc.

  8. Polymer blends of polylactic acid (PLA) and polybutylene succinate-adipate

    Science.gov (United States)

    Ma, Wenguang

    A series of blends consisting of polylactic acid (PLA) and aliphatic succinate polyester (BionolleRTM #3000) had been prepared and investigated. The results of mechanical property investigations showed that using 20 wt% Bionolle#3000 can significantly increase the toughness of PLA. BionolleRTM #3000 also reduces the physical aging rate of PLA so blends remain tough longer. Conversely, the stiffness of BionolleRTM #3000 can be significantly increased by blending in PLA. DMA and DSC results show that PLA/BionolleRTM 3000 blends are not thermodynamically miscible, but are compatible blends. Studies have also been performed to determine the amount and rate of aerobic biodegradation of PLA/aliphatic succinate polyester blends in biologically active composting, enzymatic, and soil environments. The changes in molecular weight, molecular structure and thermal properties in the composting environment were also studied by GPC, NMR and DSC analyses. The research results showed BionolleRTM #3000 had a high degradation rate, while PLA had a low degradation rate. PLA/BionolleRTM #3000 blends had moderate degradation rates that increased with BionolleRTM #3000 content. The melt flow behavior of PLA/BionolleRTM #3000 blends has been studied by capillary rheometry. The relationship of the blends' viscosity with their composition, shear stress, shear rate, and temperature has been investigated. Power law index and activation energy of PLA, BionolleRTM #3000 and their blends have been calculated. The experimental and theoretical data can let us understand the processability of PLA/BionolleRTM #3000 blends. A scanning electron microscope (SEM) was used to investigate the morphological structure of the PLA/BionolleRTM #3000 blends. Micrographs of the samples made from different methods (blown film, extrudate and compression molding sheet) were taken; their differences in morphology were compared. For comparison, the micrographs of blend PLA/BionolleRTM #6000 was also studied. The

  9. Finding a balance in dimensions of blended learning

    NARCIS (Netherlands)

    Verkroost, M.; Meijerink, L.; Lintsen, H.W.; Veen, W.

    2008-01-01

    This article is a formative evaluation of a course in which a blended learning environment was created and a good balance in dimensions of blended learning was sought. Blended learning is defined as the total mix of pedagogical methods, using a combination of different learning strategies, both with

  10. NOx emissions and combustibility characteristics of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, F.; Arenillas, A.; Arias, B.; Pis, J.J. [CSIC, Instituto Nacional del Carbon, Oviedo (Spain). Dept. of Energy and Environment

    2001-07-01

    In this work, a series of coals with different origin and rank were blended and several aspects of the resultant blends were studied. This included determination of the grindability of individual coals and blends by means of the Hardgrove Grindability Index (HGI), and temperature programmed combustion test, which were carried out in a thermogravimetric analyser (TG) coupled to a quadruple mass spectrometer (MS) for evolved gas analysis. Special attention was paid to the combustibility parameters and the NO emissions during blends combustion. It was found that while some coal blends present interaction between the individual coals, others do not. This behaviour was assumed to be due to the differences in coal structure and functional groups composition. 18 refs., 11 figs., 2 tabs.

  11. On The compatibility and dynamic vulcanization of Pom/Nbr blends

    International Nuclear Information System (INIS)

    Mortezaee, M.; Naveed Family, M.H.; Mehrabzadeh, M.

    2001-01-01

    Polymer blends based on polyacetal butadiene rubber were prepared by melt blending technique. The mixing parameters such ad temperature, time and speed of mixing were varied to obtain a wide range of properties. The mixing parameters were optimized by evaluating the mechanical properties of the blend over a wide range of mixing conditions. The morphology of the blend indicated a two-phase structure. This study describes an attempt to improve the tensile strength of Pom/Nbr blends by means of compatibility and dynamic vulcanization. A commercial compatibility, maleic anhydride (Ma), has been used to control the phase morphology of the blend system. Dicumyl peroxide is used to dynamically vulcanize the Nbr elastomer in the blend. The tensile strength of the compatibility systems showed improvement. Dynamic vulcanization raises elastic recovery and tensile modulus of the blends, but the elongation at break decreases

  12. Relativistic Binaries in Globular Clusters

    Directory of Open Access Journals (Sweden)

    Matthew J. Benacquista

    2013-03-01

    Full Text Available Galactic globular clusters are old, dense star systems typically containing 10^4 – 10^6 stars. As an old population of stars, globular clusters contain many collapsed and degenerate objects. As a dense population of stars, globular clusters are the scene of many interesting close dynamical interactions between stars. These dynamical interactions can alter the evolution of individual stars and can produce tight binary systems containing one or two compact objects. In this review, we discuss theoretical models of globular cluster evolution and binary evolution, techniques for simulating this evolution that leads to relativistic binaries, and current and possible future observational evidence for this population. Our discussion of globular cluster evolution will focus on the processes that boost the production of tight binary systems and the subsequent interaction of these binaries that can alter the properties of both bodies and can lead to exotic objects. Direct N-body integrations and Fokker–Planck simulations of the evolution of globular clusters that incorporate tidal interactions and lead to predictions of relativistic binary populations are also discussed. We discuss the current observational evidence for cataclysmic variables, millisecond pulsars, and low-mass X-ray binaries as well as possible future detection of relativistic binaries with gravitational radiation.

  13. Evaluation of the ignition behaviour of coals and blends

    Energy Technology Data Exchange (ETDEWEB)

    J. Faundez; F. Rubiera; X. Garcia; A. Arenillas; A.L. Gordon; J.J. Pis [CSIC, Instituto Nacional del Carbon, Oviedo (Spain). Department of Energy and Environment

    2003-07-01

    An experimental study about ignition of coals and blends was carried out by using an entrained flow reactor (EFR) with continuous feed. Seven coals of varying rank, from subbituminous to semianthracite, were tested and evolving gases (O{sub 2}, CO, CO{sub 2}, NO) were measured. The ignition temperature was evaluated from the evolution profiles of these gases, and correlated inversely to the reactivity of coals, as reflected by increasing values of ignition temperatures in the sequence subbituminous, high volatile bituminous, low volatile bituminous and semianthracite coals. Mechanism of ignition varied from an heterogeneous mechanism (for subbituminous, low volatile bituminous and semianthracite coals) to an homogeneous mechanism (for high volatile bituminous coal). Experiments with coal blends showed that if a low volatile bituminous coal is blended with a high volatile bituminous coal, the latter determines the value of the ignition temperature and ignition mechanism of the blend, when its percentage in the blend is 50% or higher. For blends of subbituminous and high volatile bituminous coals, the ignition mechanism of the blend is determined by the ignition mechanism of the coal with a higher content in the blend. 12 refs., 9 figs., 1 tab.

  14. Mapping Soil Salinity/Sodicity by using Landsat OLI Imagery and PLSR Algorithm over Semiarid West Jilin Province, China

    Science.gov (United States)

    Liu, Mingyue; Du, Baojia; Zhang, Bai

    2018-01-01

    Soil salinity and sodicity can significantly reduce the value and the productivity of affected lands, posing degradation, and threats to sustainable development of natural resources on earth. This research attempted to map soil salinity/sodicity via disentangling the relationships between Landsat 8 Operational Land Imager (OLI) imagery and in-situ measurements (EC, pH) over the west Jilin of China. We established the retrieval models for soil salinity and sodicity using Partial Least Square Regression (PLSR). Spatial distribution of the soils that were subjected to hybridized salinity and sodicity (HSS) was obtained by overlay analysis using maps of soil salinity and sodicity in geographical information system (GIS) environment. We analyzed the severity and occurring sizes of soil salinity, sodicity, and HSS with regard to specified soil types and land cover. Results indicated that the models’ accuracy was improved by combining the reflectance bands and spectral indices that were mathematically transformed. Therefore, our results stipulated that the OLI imagery and PLSR method applied to mapping soil salinity and sodicity in the region. The mapping results revealed that the areas of soil salinity, sodicity, and HSS were 1.61 × 106 hm2, 1.46 × 106 hm2, and 1.36 × 106 hm2, respectively. Also, the occurring area of moderate and intensive sodicity was larger than that of salinity. This research may underpin efficiently mapping regional salinity/sodicity occurrences, understanding the linkages between spectral reflectance and ground measurements of soil salinity and sodicity, and provide tools for soil salinity monitoring and the sustainable utilization of land resources. PMID:29614727

  15. Skewed Binary Search Trees

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Moruz, Gabriel

    2006-01-01

    It is well-known that to minimize the number of comparisons a binary search tree should be perfectly balanced. Previous work has shown that a dominating factor over the running time for a search is the number of cache faults performed, and that an appropriate memory layout of a binary search tree...... can reduce the number of cache faults by several hundred percent. Motivated by the fact that during a search branching to the left or right at a node does not necessarily have the same cost, e.g. because of branch prediction schemes, we in this paper study the class of skewed binary search trees....... For all nodes in a skewed binary search tree the ratio between the size of the left subtree and the size of the tree is a fixed constant (a ratio of 1/2 gives perfect balanced trees). In this paper we present an experimental study of various memory layouts of static skewed binary search trees, where each...

  16. Design of Sustainable Blended Products using an Integrated Methodology

    DEFF Research Database (Denmark)

    Yunus, Nor Alafiza Binti; Gernaey, Krist; Woodley, John

    2013-01-01

    This paper presents a systematic methodology for designing blended products consisting of three stages; product design, process identification and experimental verification. The product design stage is considered in this paper. The objective of this stage is to screen and select suitable chemicals...... to be used as building blocks in the mixture design, and then to propose the blend formulations that fulfill the desired product attributes. The result is a set of blends that match the constraints, the compositions, values of the target properties and information about their miscibility. The methodology has...... been applied to design several blended products. A case study on design of blended lubricants is highlighted. The objective is to identify blended products that satisfy the product attributes with at least similar or better performance compared to conventional products....

  17. Dual Energy Computed Tomography to Evaluate Hepatocellular Carcinoma Treated with Transcatheter Arterial Chemo-Embolization: Comparison between the Linear Blending and Nonlinear Moidal Blending Methods

    International Nuclear Information System (INIS)

    Shin, Sang Soo; Kim, Hyeong Wook; Lee, Daun; Kang, Heoung Keun; Kim, Jin Woong; Heo, Suk Hee; Jeong, Yong Yeon; Seon, Hyun Ju

    2012-01-01

    To compare the linear blending image with the nonlinear moidal blending image using dual energy CT for the evaluation of the viable portion of hepatocellular carcinoma (HCC) after transcatheter arterial chemoembolization (TACE). One-hundred and twenty three HCC patients incompletely treated after TACE were enrolled in this study. The dual energy mode (80 kVp and Sn140 kVp) was only applied in the late arterial phase scanning. A paired t-test was used to compare the lesion-to-liver contrast-to-noise ratio (CNR) and the image noise between the two blending images. Lesion conspicuity, image sharpness, image noise and the overall image quality between the two blending images were compared using the Wilcoxon matched-pair signed-ranks test. The lesion-to-liver CNR was significantly higher on the moidal blending image (5.6 ± 3.2) than on the linear blending image (2.7 ± 1.6) (p < 0.001). The image noise was significantly lower on the moidal blending image (10.9 ± 3.5) than on the linear blending image (17.5 ± 5.5) (p < 0.001). The lesion conspicuity and overall image quality were significantly better on the moidal blending image for both reviewers (p < 0.001). However, with respect to image sharpness, the linear blending image was significantly better for both reviewers (p < 0.01). The nonlinear moidal blending image of dual energy CT showed an increased lesion-to-liver CNR, decreased noise and improved overall image quality for the evaluation of the viable portion of HCC after TACE.

  18. Binary optics: Trends and limitations

    Science.gov (United States)

    Farn, Michael W.; Veldkamp, Wilfrid B.

    1993-01-01

    We describe the current state of binary optics, addressing both the technology and the industry (i.e., marketplace). With respect to the technology, the two dominant aspects are optical design methods and fabrication capabilities, with the optical design problem being limited by human innovation in the search for new applications and the fabrication issue being limited by the availability of resources required to improve fabrication capabilities. With respect to the industry, the current marketplace does not favor binary optics as a separate product line and so we expect that companies whose primary purpose is the production of binary optics will not represent the bulk of binary optics production. Rather, binary optics' more natural role is as an enabling technology - a technology which will directly result in a competitive advantage in a company's other business areas - and so we expect that the majority of binary optics will be produced for internal use.

  19. Preparation of LDPE/LNR Blend Via Emulsion Dispersion

    International Nuclear Information System (INIS)

    Rusli Daik; Yee Lee Ching

    2007-01-01

    Low density polyethylene (LDPE)/ liquid natural rubber (LNR) blends with the composition of 100LDPE/ 0LNR, 70LDPE/ 30LNR, 60LDPE/ 40LNR and 40LDPE/ 60LNR were prepared via dispersion of LDPE and LNR emulsion. LNR was obtained via photochemical sensitization of natural rubber (NR). Emulsion of LNR was prepared by using sodium dodecyl sulfate (SDS) and 1-hexanol as the emulsifier and co- emulsifier respectively. Emulsion of LDPE was prepared in the same way by using LDPE solution in carbon tetrachloride, SDS and 1-hexanol. LDPE/ LNR blends were prepared via mixing of LNR and LDPE emulsions. Mechanical properties of the blends were analyzed by tensile, hardness and impact test. Optimum mechanical properties were observed for composite with composition of 60LDPE/ 40LNR that showed the maximum value of stress and strain. The glass transition temperature, T g , of the blends as obtained from differential scanning calorimetric (DSC) showed that the blends were homogeneous. Morphology study by using scanning electron microscopy (SEM) also indicates the homogeneity of LDPE/ LNR blends produced. (author)

  20. Preparation and Characterization of Keratin/Alginate Blend Microparticles

    Directory of Open Access Journals (Sweden)

    Yaowalak Srisuwan

    2018-01-01

    Full Text Available The water-in-oil (W/O emulsification-diffusion method was used for construction of keratin (Ker, alginate (Alg, and Ker/Alg blend microparticles. The Ker, Alg, and Ker/Alg blend solutions were used as the water phase, while ethyl acetate was used as the oil phase. Firstly, different concentrations of Ker solution was used to find suitable content. 1.6% w/v Ker solution was blended with the same concentration of the Alg solution for further microparticle construction. Results from scanning electron microscope analysis show that the microparticles have different shapes: spherical, bowl-like, porous, and hollow, with several sizes depending on the blend ratio. FTIR and TG analyses indicated that the secondary structure and thermal stability of the microparticles were influenced by the Ker/Alg blend ratio. The interaction between functional groups of keratin and alginate was the main factor for both β-sheet structure and Td,max values of the microparticles. The results suggested that Ker/Alg blend microparticles might be applied in many fields by varying the Ker/Alg ratio.

  1. Relationships between surface coverage ratio and powder mechanics of binary adhesive mixtures for dry powder inhalers.

    Science.gov (United States)

    Rudén, Jonas; Frenning, Göran; Bramer, Tobias; Thalberg, Kyrre; Alderborn, Göran

    2018-04-25

    The aim of this paper was to study relationships between the content of fine particles and the powder mechanics of binary adhesive mixtures and link these relationships to the blend state. Mixtures with increasing amounts of fine particles (increasing surface coverage ratios (SCR)) were prepared using Lactopress SD as carrier and micro particles of lactose as fines (2.7 µm). Indicators of unsettled bulk density, compressibility and flowability were derived and the blend state was visually examined by imaging. The powder properties studied showed relationships to the SCR characterised by stages. At low SCR, the fine particles predominantly gathered in cavities of the carriers, giving increased bulk density and unchanged or improved flow. Thereafter, increased SCR gave a deposition of particles at the enveloped carrier surface with a gradually more irregular adhesion layer leading to a reduced bulk density and a step-wise reduced flowability. The mechanics of the mixtures at a certain stage were dependent on the structure and the dynamics of the adhesion layer and transitions between the stages were controlled by the evolution of the adhesion layer. It is advisable to use techniques based on different types of flow in order to comprehensively study the mechanics of adhesive mixtures. Copyright © 2018 Elsevier B.V. All rights reserved.

  2. Dipeptide-based polyphosphazene and polyester blends for bone tissue engineering.

    Science.gov (United States)

    Deng, Meng; Nair, Lakshmi S; Nukavarapu, Syam P; Jiang, Tao; Kanner, William A; Li, Xudong; Kumbar, Sangamesh G; Weikel, Arlin L; Krogman, Nicholas R; Allcock, Harry R; Laurencin, Cato T

    2010-06-01

    Polyphosphazene-polyester blends are attractive materials for bone tissue engineering applications due to their controllable degradation pattern with non-toxic and neutral pH degradation products. In our ongoing quest for an ideal completely miscible polyphosphazene-polyester blend system, we report synthesis and characterization of a mixed-substituent biodegradable polyphosphazene poly[(glycine ethyl glycinato)(1)(phenyl phenoxy)(1)phosphazene] (PNGEG/PhPh) and its blends with a polyester. Two dipeptide-based blends namely 25:75 (Matrix1) and 50:50 (Matrix2) were produced at two different weight ratios of PNGEG/PhPh to poly(lactic acid-glycolic acid) (PLAGA). Blend miscibility was confirmed by differential scanning calorimetry, Fourier transform infrared spectroscopy, and scanning electron microscopy. Both blends resulted in higher tensile modulus and strength than the polyester. The blends showed a degradation rate in the order of Matrix2PLAGA in phosphate buffered saline at 37 degrees C over 12 weeks. Significantly higher pH values of degradation media were observed for blends compared to PLAGA confirming the neutralization of PLAGA acidic degradation by polyphosphazene hydrolysis products. The blend components PLAGA and polyphosphazene exhibited a similar degradation pattern as characterized by the molecular weight loss. Furthermore, blends demonstrated significantly higher osteoblast growth rates compared to PLAGA while maintaining osteoblast phenotype over a 21-day culture. Both blends demonstrated improved biocompatibility in a rat subcutaneous implantation model compared to PLAGA over 12 weeks. (c) 2010 Elsevier Ltd. All rights reserved.

  3. Blended Learning Opportunities in Ukrainian IT Public Education

    Science.gov (United States)

    Szimkovics, Tamás

    2017-01-01

    Based on previous surveys the usage of ICT and blended learning is at a low level in Ukraine. To catch up with the European average, it is important to familiarize the students and teachers with blended learning in the secondary school. The information technology classes provide the best opportunity to introduce the blended learning, because they…

  4. Multiscattering illumination in blended acquisition design

    NARCIS (Netherlands)

    Berkhout, A.J.; Blacquière, G.; Verschuur, D.J.

    2010-01-01

    In traditional seismic surveys the firing time between shots is such that the records do not interfere in time. However, in the concept of blending the records do overlap, allowing much denser and wider geometries in an economic way. The blending parameters are the locations of the involved sources

  5. Blended Learning in Vocational Education: Teachers' Conceptions of Blended Learning and Their Approaches to Teaching and Design

    Science.gov (United States)

    Bliuc, Ana-Maria; Casey, Grant; Bachfischer, Agnieszka; Goodyear, Peter; Ellis, Robert A.

    2012-01-01

    This paper presents research exploring teachers' experiences of using blended learning in vocational education. Teachers involved in designing and teaching using blended learning from a major Australian vocational education provider participated in the study. They received open-ended questionnaires asking to describe their conceptions of blended…

  6. Blended Learning in Action: A Practical Guide toward Sustainable Change

    Science.gov (United States)

    Tucker, Catlin R.; Wycoff, Tiffany; Green, Jason T.

    2017-01-01

    Blended learning has the power to reinvent education, but transitioning to a blended model is challenging. Blended learning requires a fundamentally new approach to learning as well as a new skillset for both teachers and school leaders. Loaded with research, examples, and resources, "Blended Learning in Action" demonstrates the…

  7. A drop penetration method to measure powder blend wettability.

    Science.gov (United States)

    Wang, Yifan; Liu, Zhanjie; Muzzio, Fernando; Drazer, German; Callegari, Gerardo

    2018-03-01

    Water wettability of pharmaceutical blends affects important quality attributes of final products. We investigate the wetting properties of a pharmaceutical blend lubricated with Magnesium Stearate (MgSt) as a function of the mechanical shear strain applied to the blend. We measure the penetration dynamics of sessile drops deposited on slightly compressed powder beds. We consider a blend composed of 9% Acetaminophen 90% Lactose and 1% MgSt by weight. Comparing the penetration time of water and a reference liquid Polydimethylsiloxane (silicon oil) we obtain an effective cosine of the contact angle with water, based on a recently developed drop penetration method. We repeat the experiments for blends exposed to increasing levels of shear strain and demonstrate a significant decrease in water wettability (decrease in the cosine of the contact angle). The results are consistent with the development of a hydrophobic film coating the powder particles as a result of the increased shear strain. Finally, we show that, as expected dissolution times increase with the level of shear strain. Therefore, the proposed drop penetration method could be used to directly assess the state of lubrication of a pharmaceutical blend and act as a quality control on powder blend attributes before the blend is tableted. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Chitosan-Based Polymer Blends: Current Status and applications

    International Nuclear Information System (INIS)

    Hefian, E.A.E.; Nasef, M.M.

    2014-01-01

    This paper reviews the latest developments in chitosan-based blends and their potential applications in various fields. Various blends together with other derivatives, such as composites and graft copolymers, have been developed to overcome chitosans disadvantages, including poor mechanical properties and to improve its functionality towards specific applications. The progress made in blending chitosan with synthetic and natural polymers is presented. The versatility and unique characteristics, such as hydrophilicity, film-forming ability, biodegradability, biocompatibility, antibacterial activity and non-toxicity of chitosan has contributed to the successful development of various blends for medical, pharmaceutical, agricultural and environmental applications. (author)

  9. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid

  10. Shape memory behaviour of radiation-crosslinked PCL/PMVS blends

    International Nuclear Information System (INIS)

    Zhu Guangming; Xu Shuogui; Wang Jinhua; Zhang Longbin

    2006-01-01

    The performance and radiation crosslinking of polycaprolactone (PCL) and polymethylvinylsiloxane (PMVS) blends has been investigated. Radiation crosslinking of PCL/PMVS blends followed the Charlesby-Pinner equation, and PMVS promoted the radiation crosslinking of the blends. As the concentration of PMVS increased, the gelation dose and the ratio of degradation to crosslinking (p 0 /q 0 ) decreased and the efficiency of radiation crosslinking increased. The elastic modulus below the melting point of PCL of radiation-crosslinked PCL/PMVS blends decreased with the increase of PMVS, and increased above the melting point. The crosslinked PCL/PMVS blends exhibited excellent shape memory effects, and the ratios of deformation to recovery were more than 95%

  11. Black holes in binary stars

    NARCIS (Netherlands)

    Wijers, R.A.M.J.

    1996-01-01

    Introduction Distinguishing neutron stars and black holes Optical companions and dynamical masses X-ray signatures of the nature of a compact object Structure and evolution of black-hole binaries High-mass black-hole binaries Low-mass black-hole binaries Low-mass black holes Formation of black holes

  12. Coevolution of Binaries and Circumbinary Gaseous Disks

    Science.gov (United States)

    Fleming, David; Quinn, Thomas R.

    2018-04-01

    The recent discoveries of circumbinary planets by Kepler raise questions for contemporary planet formation models. Understanding how these planets form requires characterizing their formation environment, the circumbinary protoplanetary disk, and how the disk and binary interact. The central binary excites resonances in the surrounding protoplanetary disk that drive evolution in both the binary orbital elements and in the disk. To probe how these interactions impact both binary eccentricity and disk structure evolution, we ran N-body smooth particle hydrodynamics (SPH) simulations of gaseous protoplanetary disks surrounding binaries based on Kepler 38 for 10^4 binary orbital periods for several initial binary eccentricities. We find that nearly circular binaries weakly couple to the disk via a parametric instability and excite disk eccentricity growth. Eccentric binaries strongly couple to the disk causing eccentricity growth for both the disk and binary. Disks around sufficiently eccentric binaries strongly couple to the disk and develop an m = 1 spiral wave launched from the 1:3 eccentric outer Lindblad resonance (EOLR). This wave corresponds to an alignment of gas particle longitude of periastrons. We find that in all simulations, the binary semi-major axis decays due to dissipation from the viscous disk.

  13. Method to blend separator powders

    Science.gov (United States)

    Guidotti, Ronald A.; Andazola, Arthur H.; Reinhardt, Frederick W.

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  14. BINARY CEPHEIDS: SEPARATIONS AND MASS RATIOS IN 5 M ☉ BINARIES

    International Nuclear Information System (INIS)

    Evans, Nancy Remage; Karovska, Margarita; Tingle, Evan; Bond, Howard E.; Schaefer, Gail H.; Mason, Brian D.

    2013-01-01

    Deriving the distribution of binary parameters for a particular class of stars over the full range of orbital separations usually requires the combination of results from many different observing techniques (radial velocities, interferometry, astrometry, photometry, direct imaging), each with selection biases. However, Cepheids—cool, evolved stars of ∼5 M ☉ —are a special case because ultraviolet (UV) spectra will immediately reveal any companion star hotter than early type A, regardless of the orbital separation. We have used International Ultraviolet Explorer UV spectra of a complete sample of all 76 Cepheids brighter than V = 8 to create a list of all 18 Cepheids with companions more massive than 2.0 M ☉ . Orbital periods of many of these binaries are available from radial-velocity studies, or can be estimated for longer-period systems from detected velocity variability. In an imaging survey with the Hubble Space Telescope Wide Field Camera 3, we resolved three of the companions (those of η Aql, S Nor, and V659 Cen), allowing us to make estimates of the periods out to the long-period end of the distribution. Combining these separations with orbital data in the literature, we derive an unbiased distribution of binary separations, orbital periods, and mass ratios. The distribution of orbital periods shows that the 5 M ☉ binaries have systematically shorter periods than do 1 M ☉ stars. Our data also suggest that the distribution of mass ratios depends on both binary separation and system multiplicity. The distribution of mass ratios as a function of orbital separation, however, does not depend on whether a system is a binary or a triple

  15. Study of PP/Polybutene Blends Modified by Gamma Irradiation and HMS-PP/Polybutene Blends

    International Nuclear Information System (INIS)

    Lugao, A. B.

    2006-01-01

    The polypropylene (PP) has been applied to a wide range of production due to its various excellent properties such as cheapness, high stiffness, chemical resistance, no environmental pollution when incinerated, low specific density and good mechanical properties. However, PP is a linear polymer which exhibits low melt strength. One of the effective approaches to achieve high melt strength (HMS) is to add chain branches onto backbone polymers. High melt strength polypropylene (HMS-PP) has been recently developed and introduced in the market by the major international polypropylene producers. As a consequence different methods have been applied to modify polypropylenes by chain branches. The technology obtained by IPEN together with EMBRARAD and BRASKEM comprises chain branches added onto backbone species using gamma radiation, which is generated from a Co 6 0 source. Such radiation is very convenient in order to improve polymer materials by grafting, crosslinking and degradation. Another important approach to the development of polymer materials is based on the combination of different polymers into a new product having some of the desired properties of each component. In this work, gamma irradiation technique was used to induce chemical changes in commercial polypropylene (HMS-PP) that was after blended with polybutene and in polypropylene/polybutene blends. The samples were irradiated with a 60 C o source at doses of 12,5 and 20kGy in the presence of acetylene. It was investigated how the two different routes of blends processing can modify their properties. Indeed the results from melt flow, gel fraction and rheology reveal the influence of the process route in the blends properties. Effects on the elongation at break and break strength were observed by the results of mechanical tests. The results from rheology demonstrated an increase in melt strength and drawability of the blends

  16. Blended learning in health education: three case studies.

    Science.gov (United States)

    de Jong, Nynke; Savin-Baden, Maggi; Cunningham, Anne Marie; Verstegen, Daniëlle M L

    2014-09-01

    Blended learning in which online education is combined with face-to-face education is especially useful for (future) health care professionals who need to keep up-to-date. Blended learning can make learning more efficient, for instance by removing barriers of time and distance. In the past distance-based learning activities have often been associated with traditional delivery-based methods, individual learning and limited contact. The central question in this paper is: can blended learning be active and collaborative? Three cases of blended, active and collaborative learning are presented. In case 1 a virtual classroom is used to realize online problem-based learning (PBL). In case 2 PBL cases are presented in Second Life, a 3D immersive virtual world. In case 3 discussion forums, blogs and wikis were used. In all cases face-to-face meetings were also organized. Evaluation results of the three cases clearly show that active, collaborative learning at a distance is possible. Blended learning enables the use of novel instructional methods and student-centred education. The three cases employ different educational methods, thus illustrating diverse possibilities and a variety of learning activities in blended learning. Interaction and communication rules, the role of the teacher, careful selection of collaboration tools and technical preparation should be considered when designing and implementing blended learning.

  17. Quantification of rice bran oil in oil blends

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, R.; Sharma, H. K.; Sengar, G.

    2012-11-01

    Blends consisting of physically refined rice bran oil (PRBO): sunflower oil (SnF) and PRBO: safflower oil (SAF) in different proportions were analyzed for various physicochemical parameters. The quantification of pure rice bran oil in the blended oils was carried out using different methods including gas chromatographic, HPLC, ultrasonic velocity and methods based on physico-chemical parameters. The physicochemical parameters such as ultrasonic velocity, relative association and acoustic impedance at 2 MHz, iodine value, palmitic acid content and oryzanol content reflected significant changes with increased proportions of PRBO in the blended oils. These parameters were selected as dependent parameters and % PRBO proportion was selected as independent parameters. The study revealed that regression equations based on the oryzanol content, palmitic acid composition, ultrasonic velocity, relative association, acoustic impedance, and iodine value can be used for the quantification of rice bran oil in blended oils. The rice bran oil can easily be quantified in the blended oils based on the oryzanol content by HPLC even at a 1% level. The palmitic acid content in blended oils can also be used as an indicator to quantify rice bran oil at or above the 20% level in blended oils whereas the method based on ultrasonic velocity, acoustic impedance and relative association showed initial promise in the quantification of rice bran oil. (Author) 23 refs.

  18. Structuring of Interface-Modified Polymer Blends

    DEFF Research Database (Denmark)

    Lyngaae-Jørgensen, Jørgen

    1999-01-01

    The paper treats the case where blends of polystyrene (PS), poly (dimethylsiloxane) (PDMS) and a diblock copolymer of PS and PDMS are used as model materials. This modelsystem is predicted to be "stable" in discrete blends in simple shear flow. Stable in the sence that the block copolymer can not...

  19. Spectral properties of binary asteroids

    Science.gov (United States)

    Pajuelo, Myriam; Birlan, Mirel; Carry, Benoît; DeMeo, Francesca E.; Binzel, Richard P.; Berthier, Jérôme

    2018-04-01

    We present the first attempt to characterize the distribution of taxonomic class among the population of binary asteroids (15% of all small asteroids). For that, an analysis of 0.8-2.5{μ m} near-infrared spectra obtained with the SpeX instrument on the NASA/IRTF is presented. Taxonomic class and meteorite analog is determined for each target, increasing the sample of binary asteroids with known taxonomy by 21%. Most binary systems are bound in the S-, X-, and C- classes, followed by Q and V-types. The rate of binary systems in each taxonomic class agrees within uncertainty with the background population of small near-Earth objects and inner main belt asteroids, but for the C-types which are under-represented among binaries.

  20. Modification of polymer blends by irradiation

    International Nuclear Information System (INIS)

    Zuchowska, D.; Zagorski, Z.P.

    1999-01-01

    Modification of polymers, especially of polyolefin-elastomer blends (e. g. ethylene/propylene/diene terpolymer, ethylene propylene copolymer, ethylene/vinyl acetate copolymer etc.), by irradiation with a beam of fast electrons is discussed. Irradiation of polymer blends usually results in enhanced interactions between the constituents, caused among other things, by grafting induced at the polymer interphase. As a result, mechanical properties are affected to an extent depending on the proportion and type of constituent polymers, stabilizer content and radiation dose. Breaking strength (σ) relative elongation at break (ε) and melt flow rate (MFR), were examined for a triblock styrene/butadiene/styrene (SBS) copolymer, polypropylene (PP), and a PP-SBS blend (50:50 by wt.). In PP, the content of the crystal phase was determined. Irradiation was found to make SBS crosslink, as a result, σ rose by 25% and ε remained unaffected. PP was found to become degraded upon irradiation (MFR rose as much as 16 times), thereby σ and ε decreased considerably. In pure PP, the content of the crystal phase was found to increase. The variations of σ and ε in the irradiated PP-SBS blend follow a tendency similar to that in the SBS copolymer examined. This fact suggests the SBS copolymer to have a decisive effect on the macroscopic properties of the PP-SBS blend. (author)

  1. A blending rule for octane numbers of PRFs and TPRFs with ethanol

    KAUST Repository

    AlRamadan, Abdullah S.; Sarathy, Mani; Khurshid, Muneeb; Badra, Jihad

    2016-01-01

    -gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates blends may enable a better understanding of ethanol blending with complex multi-component gasoline fuels. This study presents a blending rule

  2. Teaching Parametric Urban Design in a Blended Learning Format

    DEFF Research Database (Denmark)

    Steinø, Nicolai

    2015-01-01

    On the basis of a theoretical discussion of the concept of blended learning, this paper presents the pre- paration, execution and evaluation of a 5 ECTS blended learning course on parametric urban design for a group of some 50 BSc students of architecture and design at Aalborg university...... and curriculum develop- ment, and di culties to nd time for research. Despite the general consensus that developing online/blended learning courses requires both technical support, complex software installations, and substantial preparation time, it is shown that free web ser- vices and low-tech adaptations...... of traditional teaching assets are su cient to get started with blended learning with only little extra e ort. While the pilot blended learning course which provided the insights for this paper has room for impro- vement, it represents a decent rst shot at developing blended learning courses for higher education...

  3. Optimization of the octane response of gasoline/ethanol blends

    KAUST Repository

    Badra, Jihad; AlRamadan, Abdullah S.; Sarathy, Mani

    2017-01-01

    The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

  4. Optimization of the octane response of gasoline/ethanol blends

    KAUST Repository

    Badra, Jihad

    2017-07-04

    The octane responses of gasoline/ethanol mixtures are not well understood because of the unidentified intermolecular interactions in such blends. In general, when ethanol is blended with gasoline, the Research Octane Number (RON) and the Motor Octane Number (MON) non-linearly increase or decrease, and the non-linearity is determined by the composition of the base gasoline and the amount of added ethanol. The complexity of commercial gasolines, comprising of hundreds of different components, makes it challenging to understand ethanol-gasoline synergistic/antagonistic blending effects. Understanding ethanol blending effects with simpler gasoline surrogates is critical to acquire knowledge about ethanol blending with complex multi-component gasoline fuels. In this study, the octane numbers (ON) of ethanol blends with five relevant gasoline surrogate molecules were measured. The molecules investigated in this study include: n-pentane, iso-pentane, 1,2,4-trimethylbenzene, cyclopentane and 1-hexene. These new measurements along with the available data of n-heptane, iso-octane, toluene, various primary reference fuels (PRF) and toluene primary reference fuels (TPRF) with ethanol are used to develop a blending rule for the octane response (RON and MON) of multi-component blends with ethanol. In addition, new ON data are collected for six Fuels for Advanced Combustion Engine (FACE) with ethanol. The relatively simple volume based model successfully predicts the octane numbers (ON) of the various ethanol/PRF and ethanol/TPRF blends with the majority of predictions being within the ASTM D2699 (RON) and D2700 (MON) reproducibility limits. The model is also successfully validated against the ON of the FACE gasolines blended with ethanol with the majority of predictions being within the reproducibility limits. Finally, insights into the possible causes of the synergistic and antagonistic effects of different molecules with ethanol are provided.

  5. Chemical and Enzymatic Hydrolysis of Polyurethane/Polylactide Blends

    Directory of Open Access Journals (Sweden)

    Joanna Brzeska

    2015-01-01

    Full Text Available Polyether-esterurethanes containing synthetic poly[(R,S-3-hydroxybutyrate] (R,S-PHB and polyoxytetramethylenediol in soft segments and polyesterurethanes with poly(ε-caprolactone and poly[(R,S-3-hydroxybutyrate] were blended with poly([D,L]-lactide (PLA. The products were tested in terms of their oil and water absorption. Oil sorption tests of polyether-esterurethane revealed their higher response in comparison to polyesterurethanes. Blending of polyether-esterurethanes with PLA caused the increase of oil sorption. The highest water sorption was observed for blends of polyether-esterurethane, obtained with 10% of R,S-PHB in soft segments. The samples mass of polyurethanes and their blends were almost not changed after incubation in phosphate buffer and trypsin and lipase solutions. Nevertheless the molecular weight of polymers was significantly reduced after degradation. It was especially visible in case of incubation of samples in phosphate buffer what suggested the chemical hydrolysis of polymer chains. The changes of surface of polyurethanes and their blends, after incubation in both enzymatic solutions, indicated on enzymatic degradation, which had been started despite the lack of mass lost. Polyurethanes and their blends, contained more R,S-PHB in soft segments, were degraded faster.

  6. A blend of Sodium Humate/SLES/Herbal Oils

    Directory of Open Access Journals (Sweden)

    Yeliz Akyiğit

    2013-08-01

    Full Text Available A blend of sodium humate (SH with anionic surfactants such as sodium lauryl ether sulfate (SLES was prepared by solution mixing at medium of herbal oils at 25, 50 and 75°C. Its miscibility studies were carried out by using physical techniques over an extended range of concentration and composition in buffer solution. In addition, to ascertain the state of miscibility of the blends, they were investigated by using UV-visible spectrophotometer and Fourier transform infrared (FTIR. These values revealed that the blend is miscible when the sodium humate content is more than %60 in the blend at all temperatures. There were no important differences in the characteristics of the blends at different temperatures.It was thought that the mechanism ofthe complex formation is realized by making strong intermolecular interaction like hydrogen bonds between the carbonyl groups in humic acid and hydroxyl groups in fatty acids.

  7. Calibration sets selection strategy for the construction of robust PLS models for prediction of biodiesel/diesel blends physico-chemical properties using NIR spectroscopy

    Science.gov (United States)

    Palou, Anna; Miró, Aira; Blanco, Marcelo; Larraz, Rafael; Gómez, José Francisco; Martínez, Teresa; González, Josep Maria; Alcalà, Manel

    2017-06-01

    Even when the feasibility of using near infrared (NIR) spectroscopy combined with partial least squares (PLS) regression for prediction of physico-chemical properties of biodiesel/diesel blends has been widely demonstrated, inclusion in the calibration sets of the whole variability of diesel samples from diverse production origins still remains as an important challenge when constructing the models. This work presents a useful strategy for the systematic selection of calibration sets of samples of biodiesel/diesel blends from diverse origins, based on a binary code, principal components analysis (PCA) and the Kennard-Stones algorithm. Results show that using this methodology the models can keep their robustness over time. PLS calculations have been done using a specialized chemometric software as well as the software of the NIR instrument installed in plant, and both produced RMSEP under reproducibility values of the reference methods. The models have been proved for on-line simultaneous determination of seven properties: density, cetane index, fatty acid methyl esters (FAME) content, cloud point, boiling point at 95% of recovery, flash point and sulphur.

  8. Photonic polymer-blend structures and method for making

    Science.gov (United States)

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  9. Blending Study For SRR Salt Disposition Integration: Tank 50H Scale-Modeling And Computer-Modeling For Blending Pump Design, Phase 2

    International Nuclear Information System (INIS)

    Leishear, R.; Poirier, M.; Fowley, M.

    2011-01-01

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where 300,000-800,000 gallons of salt solution will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. Blending requires the miscible salt solutions from potentially multiple source tanks per batch to be well mixed without disturbing settled sludge solids that may be present in a Blend Tank. Disturbing solids may be problematic both from a feed quality perspective as well as from a process safety perspective where hydrogen release from the sludge is a potential flammability concern. To develop the necessary technical basis for the design and operation of blending equipment, Savannah River National Laboratory (SRNL) completed scaled blending and transfer pump tests and computational fluid dynamics (CFD) modeling. A 94 inch diameter pilot-scale blending tank, including tank internals such as the blending pump, transfer pump, removable cooling coils, and center column, were used in this research. The test tank represents a 1/10.85 scaled version of an 85 foot diameter, Type IIIA, nuclear waste tank that may be typical of Blend Tanks used in SDI. Specifically, Tank 50 was selected as the tank to be modeled per the SRR, Project Engineering Manager. SRNL blending tests investigated various fixed position, non-rotating, dual nozzle pump designs, including a blending pump model provided by the blend pump vendor, Curtiss Wright (CW). Primary research goals were to assess blending times and to evaluate incipient sludge disturbance for waste tanks. Incipient sludge disturbance was defined by SRR and SRNL as minor blending of settled sludge from the tank bottom into suspension due to blending pump operation, where

  10. BLENDING STUDY FOR SRR SALT DISPOSITION INTEGRATION: TANK 50H SCALE-MODELING AND COMPUTER-MODELING FOR BLENDING PUMP DESIGN, PHASE 2

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, R.; Poirier, M.; Fowley, M.

    2011-05-26

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where 300,000-800,000 gallons of salt solution will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. Blending requires the miscible salt solutions from potentially multiple source tanks per batch to be well mixed without disturbing settled sludge solids that may be present in a Blend Tank. Disturbing solids may be problematic both from a feed quality perspective as well as from a process safety perspective where hydrogen release from the sludge is a potential flammability concern. To develop the necessary technical basis for the design and operation of blending equipment, Savannah River National Laboratory (SRNL) completed scaled blending and transfer pump tests and computational fluid dynamics (CFD) modeling. A 94 inch diameter pilot-scale blending tank, including tank internals such as the blending pump, transfer pump, removable cooling coils, and center column, were used in this research. The test tank represents a 1/10.85 scaled version of an 85 foot diameter, Type IIIA, nuclear waste tank that may be typical of Blend Tanks used in SDI. Specifically, Tank 50 was selected as the tank to be modeled per the SRR, Project Engineering Manager. SRNL blending tests investigated various fixed position, non-rotating, dual nozzle pump designs, including a blending pump model provided by the blend pump vendor, Curtiss Wright (CW). Primary research goals were to assess blending times and to evaluate incipient sludge disturbance for waste tanks. Incipient sludge disturbance was defined by SRR and SRNL as minor blending of settled sludge from the tank bottom into suspension due to blending pump operation, where

  11. Improving Curriculum through Blended Learning Pedagogy

    Science.gov (United States)

    Darojat, Ojat

    2016-01-01

    This paper is a study of blended learning pedagogy in open and distance learning (ODL), involving two universities in Southeast Asia, STOU Thailand and UT Indonesia. The purpose of this study is to understand the issues related to the implementation of blended-learning pedagogy. Qualitative case study was employed to optimize my understanding of…

  12. CURING AND MECHANICAL PROPERTIES OF CHLOROSULPHONATED POLYETHYLENE RUBBER BLEND

    Directory of Open Access Journals (Sweden)

    Jaroslava Budinski-Simendić

    2011-09-01

    Full Text Available In this paper, the curing and mechanical properties of two series of prepared blends, i.e., chlorosulphonated polyethylene (CSM/isobutylene-co-isoprene (IIR rubber blends and chlorosulphonated polyethylene (CSM/chlorinated isobutylene-co-isoprene (CIIR rubber blends were carried out. Blends were prepared using a two-roll mill at a temperature of 40-50 °C. The curing was assessed using a Monsanto oscillating disc rheometer R-100. The process of vulcanization accelerated sulfur of pure rubbers and their blends was carried out in an electrically heated laboratory hydraulic press under a pressure of about 4 MPa and 160 °C. The stress-strain experiments were performed using a tensile tester machine (Zwick 1425. Results indicate that the scorch time, ts2, and optimum cure time, tc90, increase with increasing CSM content in both blends. The value of modulus at 100 and 300% elongation and tensile strength increases with increasing CSM content, whereas elongation at break shows a decreasing trend. The enhancement in mechanical properties was supported by data of crosslink density in these samples obtained from swelling measurement and scanning electron microscopy studies of the rubber blends fractured surfaces

  13. Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

    KAUST Repository

    Al-Khodaier, Mohannad

    2017-03-28

    Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

  14. Evaluation of Anti-Knock Quality of Dicyclopentadiene-Gasoline Blends

    KAUST Repository

    Al-Khodaier, Mohannad; Bhavani Shankar, Vijai Shankar; Waqas, Muhammad; Naser, Nimal; Sarathy, Mani; Johansson, Bengt

    2017-01-01

    Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes. The synergistic blending nature of DCPD was apparent and appeared to be greater than that of ethanol. The data presented suggests that DCPD has the potential to be a high octane blending component in gasoline; one which can substitute alkylates, isomerates, reformates, and oxygenates.

  15. Binary Cepheids: Separations and Mass Ratios in 5 M ⊙ Binaries

    Science.gov (United States)

    Evans, Nancy Evans; Bond, Howard E.; Schaefer, Gail H.; Mason, Brian D.; Karovska, Margarita; Tingle, Evan

    2013-10-01

    Deriving the distribution of binary parameters for a particular class of stars over the full range of orbital separations usually requires the combination of results from many different observing techniques (radial velocities, interferometry, astrometry, photometry, direct imaging), each with selection biases. However, Cepheids—cool, evolved stars of ~5 M ⊙—are a special case because ultraviolet (UV) spectra will immediately reveal any companion star hotter than early type A, regardless of the orbital separation. We have used International Ultraviolet Explorer UV spectra of a complete sample of all 76 Cepheids brighter than V = 8 to create a list of all 18 Cepheids with companions more massive than 2.0 M ⊙. Orbital periods of many of these binaries are available from radial-velocity studies, or can be estimated for longer-period systems from detected velocity variability. In an imaging survey with the Hubble Space Telescope Wide Field Camera 3, we resolved three of the companions (those of η Aql, S Nor, and V659 Cen), allowing us to make estimates of the periods out to the long-period end of the distribution. Combining these separations with orbital data in the literature, we derive an unbiased distribution of binary separations, orbital periods, and mass ratios. The distribution of orbital periods shows that the 5 M ⊙ binaries have systematically shorter periods than do 1 M ⊙ stars. Our data also suggest that the distribution of mass ratios depends on both binary separation and system multiplicity. The distribution of mass ratios as a function of orbital separation, however, does not depend on whether a system is a binary or a triple. Based in part on observations made with the NASA/ESA Hubble Space Telescope, obtained by the Space Telescope Science Institute. STScI is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-26555.

  16. An investigation on radiation crosslinked foam of LDPE/EVA blends

    International Nuclear Information System (INIS)

    Siqin Dalai; Chen Wenxiu

    1995-01-01

    LDPE/EVA blend, irradiated by γ-ray then expansed by heat as a foam material, the EVA content in LDPE/EVA blend was benefited to form gelation. The gel fraction on irradiated LDPE/EVA blend increased with the increasing of its EVA content in a given dose. The gel fraction values of LDPE/EVA blend with 30% EVA content were higher than those of other blends in a same given dose, its gel fraction value was 1.7 times as those values of LDPE without EVA. The gel fractions on LDPE/EVA blend were increased with dose in oxygen, in air and in nitrogen, the formation of gel was limited by oxygen. The oxidation products on foam of LDPE/EVA blend were observed in nitrogen, in air and in oxygen by FTIR spectra. The LDPE/EVA blend system has no protection effect from oxidation comparison with the LDPE system without EVA which has less oxidation product than those without EVA in a same given gel fraction. The gel fraction on foam of LDPE/EVA blend around 25-35%, dose 25 ± 5kGy, irradiated by γ-ray in air or in nitrogen, with higher expansion ratio (19), smaller cell diameter (0.175mm), lower apparent density (0.042g/cm 3 ), higher tensile strength (0.40MPa) and longer elongation at break (290-360%) on foam of LDPE/EVA blend were selected. It was opitimum condition for application in this systems. The relations among gel fraction on LDPE/EVA blend, expansion ratio, apparent density, average cell diameter and mechanical properties of foamed sheet were discussed. (author)

  17. Spectroscopic studies of O-type binaries. IV. HD 165052 and Hd 167771

    International Nuclear Information System (INIS)

    Morrison, N.D.; Conti, P.S.

    1978-01-01

    HD 165052, O6.5 V, and HD 167771, 07.5 III ((f)), are double-lined binaries with periods of six and four days, respectively, and velocity semiamplitudes near 100 km s -1 . In our spectroscopic orbital analysis, we investigated the effect of correcting the measured radial velocities for pair blending. The derived velocity amplitudes are increased by roughly 7%, and hence the minimum masses increase by 20%--255. The raw data lead to minimum masses, m sin 3 i, between 2 and 3 mD/sub sun/. Since normal O stars are thought to have masses greater than 20 m/sub sun/, the orbits must be highly inclined to the line of sight. From the luminosities and effective temperatures we derived stellar radii. For HD 167771, the requirement that neither component over fill it Roche lobe implies that each has a mass in the neighborhood of 30m/sub sun/ or larger

  18. The formation of eccentric compact binary inspirals and the role of gravitational wave emission in binary-single stellar encounters

    International Nuclear Information System (INIS)

    Samsing, Johan; MacLeod, Morgan; Ramirez-Ruiz, Enrico

    2014-01-01

    The inspiral and merger of eccentric binaries leads to gravitational waveforms distinct from those generated by circularly merging binaries. Dynamical environments can assemble binaries with high eccentricity and peak frequencies within the LIGO band. In this paper, we study binary-single stellar scatterings occurring in dense stellar systems as a source of eccentrically inspiraling binaries. Many interactions between compact binaries and single objects are characterized by chaotic resonances in which the binary-single system undergoes many exchanges before reaching a final state. During these chaotic resonances, a pair of objects has a non-negligible probability of experiencing a very close passage. Significant orbital energy and angular momentum are carried away from the system by gravitational wave (GW) radiation in these close passages, and in some cases this implies an inspiral time shorter than the orbital period of the bound third body. We derive the cross section for such dynamical inspiral outcomes through analytical arguments and through numerical scattering experiments including GW losses. We show that the cross section for dynamical inspirals grows with increasing target binary semi-major axis a and that for equal-mass binaries it scales as a 2/7 . Thus, we expect wide target binaries to predominantly contribute to the production of these relativistic outcomes. We estimate that eccentric inspirals account for approximately 1% of dynamically assembled non-eccentric merging binaries. While these events are rare, we show that binary-single scatterings are a more effective formation channel than single-single captures for the production of eccentrically inspiraling binaries, even given modest binary fractions.

  19. Neural networks applied to characterize blends containing refined and extra virgin olive oils.

    Science.gov (United States)

    Aroca-Santos, Regina; Cancilla, John C; Pariente, Enrique S; Torrecilla, José S

    2016-12-01

    The identification and quantification of binary blends of refined olive oil with four different extra virgin olive oil (EVOO) varietals (Picual, Cornicabra, Hojiblanca and Arbequina) was carried out with a simple method based on combining visible spectroscopy and non-linear artificial neural networks (ANNs). The data obtained from the spectroscopic analysis was treated and prepared to be used as independent variables for a multilayer perceptron (MLP) model. The model was able to perfectly classify the EVOO varietal (100% identification rate), whereas the error for the quantification of EVOO in the mixtures containing between 0% and 20% of refined olive oil, in terms of the mean prediction error (MPE), was 2.14%. These results turn visible spectroscopy and MLP models into a trustworthy, user-friendly, low-cost technique which can be implemented on-line to characterize olive oil mixtures containing refined olive oil and EVOOs. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. A systematic methodology for design of tailor-made blended products

    DEFF Research Database (Denmark)

    Yunus, Nor Alafiza Binti; Gernaey, Krist; Woodley, John

    2014-01-01

    A systematic methodology for design of tailor-made blended products has been developed. In tailor-made blended products, one identifies the product needs and matches them by blending different chemicals. The systematic methodology has four main tasks. First, the design problem is defined: the pro......, the methodology is highlighted through two case studies involving gasoline blends and lubricant base oils....

  1. Quantifying biomass consumption and carbon release from the California Rim fire by integrating airborne LiDAR and Landsat OLI data.

    Science.gov (United States)

    Garcia, Mariano; Saatchi, Sassan; Casas, Angeles; Koltunov, Alexander; Ustin, Susan; Ramirez, Carlos; Garcia-Gutierrez, Jorge; Balzter, Heiko

    2017-02-01

    Quantifying biomass consumption and carbon release is critical to understanding the role of fires in the carbon cycle and air quality. We present a methodology to estimate the biomass consumed and the carbon released by the California Rim fire by integrating postfire airborne LiDAR and multitemporal Landsat Operational Land Imager (OLI) imagery. First, a support vector regression (SVR) model was trained to estimate the aboveground biomass (AGB) from LiDAR-derived metrics over the unburned area. The selected model estimated AGB with an R 2 of 0.82 and RMSE of 59.98 Mg/ha. Second, LiDAR-based biomass estimates were extrapolated to the entire area before and after the fire, using Landsat OLI reflectance bands, Normalized Difference Infrared Index, and the elevation derived from LiDAR data. The extrapolation was performed using SVR models that resulted in R 2 of 0.73 and 0.79 and RMSE of 87.18 (Mg/ha) and 75.43 (Mg/ha) for the postfire and prefire images, respectively. After removing bias from the AGB extrapolations using a linear relationship between estimated and observed values, we estimated the biomass consumption from postfire LiDAR and prefire Landsat maps to be 6.58 ± 0.03 Tg (10 12  g), which translate into 12.06 ± 0.06 Tg CO2 e released to the atmosphere, equivalent to the annual emissions of 2.57 million cars.

  2. Critical Success Factor for Implementing Vocational Blended Learning

    Science.gov (United States)

    Dewi, K. C.; Ciptayani, P. I.; Surjono, H. D.; Priyanto

    2018-01-01

    Blended learning provides many benefits to the flexibility of time, place and situation constraints. The research’s objectives was describing the factors that determine the successful implementation of blended learning in vocational higher education. The research used a qualitative approach, data collected through observations and interviews by questionnare based on the CSFs indicators refers to TAM and Kliger. Data analysis was inductive method. The result provided an illustration that the success of vocational blended learning implementation was largely determined by the selection of instructional models that are inline with learning achievement target. The effectiveness of blended learning required the existence of policy support, readiness of IT infrastructure. Changing lecturer’s culture by utilizing ICT can also encourage the accelerated process of successful implementation. It can concluded that determinant factor of successful implementation of blended learning in vocational education is determined by teacher’s ability in mastering the pedagogical knowledge of designing instructional models.

  3. N-Bit Binary Resistor

    Science.gov (United States)

    Tcheng, Ping

    1989-01-01

    Binary resistors in series tailored to precise value of resistance. Desired value of resistance obtained by cutting appropriate traces across resistors. Multibit, binary-based, adjustable resistor with high resolution used in many applications where precise resistance required.

  4. HEU to LEU conversion and blending facility: Oxide blending alternative to produce LEU oxide for commercial use

    International Nuclear Information System (INIS)

    1995-09-01

    The United States Department of Energy (DOE) is examining options for the disposition of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. Disposition is a process of use or disposal of material that results in the material being converted to a form that is substantially and inherently more proliferation-resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. This document provides data to be used in the environmental impact analysis for the oxide blending HEU disposition option. This option provides for a yearly HEU throughput of 1 0 metric tons (MT) of uranium metal with an average U235 assay of 50% blended with 165 MT of natural assay triuranium octoxide (U 3 O 8 ) per year to produce 177 MT of 4% U235 assay U 3 O 8 , for LWR fuel. Since HEU exists in a variety of forms and not necessarily in the form to be blended, worst case scenarios for preprocessing prior to blending will be assumed for HEU feed streams

  5. Performance and emission characteristics of double biodiesel blends with diesel

    Directory of Open Access Journals (Sweden)

    Kuthalingam Arun Balasubramanian

    2013-01-01

    Full Text Available Recent research on biodiesel focused on performance of single biodiesel and its blends with diesel. The present work aims to investigate the possibilities of the application of mixtures of two biodiesel and its blends with diesel as a fuel for diesel engines. The combinations of Pongamia pinnata biodiesel, Mustard oil biodiesel along with diesel (PMD and combinations of Cotton seed biodiesel, Pongamia pinnata biodiesel along with diesel (CPD are taken for the experimental analysis. Experiments are conducted using a single cylinder direct-injection diesel engine with different loads at rated 3000 rpm. The engine characteristics of the two sets of double biodiesel blends are compared. For the maximum load, the value of Specific Fuel consumption and thermal efficiency of CPD-1 blend (10:10:80 is close to the diesel values. CPD blends give better engine characteristics than PMD blends. The blends of CPD are suitable alternative fuel for diesel in stationary/agricultural diesel engines.

  6. A robust quantitative near infrared modeling approach for blend monitoring.

    Science.gov (United States)

    Mohan, Shikhar; Momose, Wataru; Katz, Jeffrey M; Hossain, Md Nayeem; Velez, Natasha; Drennen, James K; Anderson, Carl A

    2018-01-30

    This study demonstrates a material sparing Near-Infrared modeling approach for powder blend monitoring. In this new approach, gram scale powder mixtures are subjected to compression loads to simulate the effect of scale using an Instron universal testing system. Models prepared by the new method development approach (small-scale method) and by a traditional method development (blender-scale method) were compared by simultaneously monitoring a 1kg batch size blend run. Both models demonstrated similar model performance. The small-scale method strategy significantly reduces the total resources expended to develop Near-Infrared calibration models for on-line blend monitoring. Further, this development approach does not require the actual equipment (i.e., blender) to which the method will be applied, only a similar optical interface. Thus, a robust on-line blend monitoring method can be fully developed before any large-scale blending experiment is viable, allowing the blend method to be used during scale-up and blend development trials. Copyright © 2017. Published by Elsevier B.V.

  7. Lifecycle optimized ethanol-gasoline blends for turbocharged engines

    KAUST Repository

    Zhang, Bo

    2016-08-16

    This study presents a lifecycle (well-to-wheel) analysis to determine the CO2 emissions associated with ethanol blended gasoline in optimized turbocharged engines. This study provides a more accurate assessment on the best-achievable CO2 emission of ethanol blended gasoline mixtures in future engines. The optimal fuel blend (lowest CO2 emitting fuel) is identified. A range of gasoline fuels is studied, containing different ethanol volume percentages (E0–E40), research octane numbers (RON, 92–105), and octane sensitivities (8.5–15.5). Sugarcane-based and cellulosic ethanol-blended gasolines are shown to be effective in reducing lifecycle CO2 emission, while corn-based ethanol is not as effective. A refinery simulation of production emission was utilized, and combined with vehicle fuel consumption modeling to determine the lifecycle CO2 emissions associated with ethanol-blended gasoline in turbocharged engines. The critical parameters studied, and related to blended fuel lifecycle CO2 emissions, are ethanol content, research octane number, and octane sensitivity. The lowest-emitting blended fuel had an ethanol content of 32 vol%, RON of 105, and octane sensitivity of 15.5; resulting in a CO2 reduction of 7.1%, compared to the reference gasoline fuel and engine technology. The advantage of ethanol addition is greatest on a per unit basis at low concentrations. Finally, this study shows that engine-downsizing technology can yield an additional CO2 reduction of up to 25.5% in a two-stage downsized turbocharged engine burning the optimum sugarcane-based fuel blend. The social cost savings in the USA, from the CO2 reduction, is estimated to be as much as $187 billion/year. © 2016 Elsevier Ltd

  8. Characterization of herbal powder blends homogeneity using near-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Wenlong Li

    2014-11-01

    Full Text Available Homogeneity of powder blend is essential to obtain uniform contents for the tablets and capsules. Near-infrared (NIR spectroscopy with fiber-optic probe was used as an on-line technique for monitoring the homogeneity of pharmaceutical blend during the blending process instead of the traditional techniques, such as high performance liquid chromatograph (HPLC method. In this paper NIRS with a SabIR diffuse reflectance fiber-optic probe was used to monitor the blending process of coptis powder and lactose (excipient with different contents, and further qualitative methods, like similarity, moving block of standard deviation and mean square were used for calculation purposes with the collected spectra after the pretreatment of multiplicative signal correction (MSC and second derivative. Correlation spectrum was used for the wavelength selection. Four different coptis were blended with lactose separately to validate the proposed method, and the blending process of "liu wei di huang" pill was also simulated in bottles to verify this method on multiple herbal blends. The overall results suggest that NIRS is a simple, effective and noninvasive technique can be successfully applied to the determination of homogeneity in the herbal blend.

  9. Some properties of spectral binary stars

    International Nuclear Information System (INIS)

    Krajcheva, Z.T.; Popova, E.I.; Tutukov, A.V.; Yungel'son, L.R.; AN SSSR, Moscow. Astronomicheskij Sovet)

    1978-01-01

    Statistical investigations of spectra binary stars are carried out. Binary systems consisting of main sequence stars are considered. For 826 binary stars masses of components, ratios of component masses, semiaxes of orbits and orbital angular momenta are calculated. The distributions of these parameters and their correlations are analyzed. The dependences of statistical properties of spectral binary stars on their origin and evolution are discussed

  10. Transitioning to Blended Learning: Understanding Student and Faculty Perceptions

    Science.gov (United States)

    Napier, Nannette P.; Dekhane, Sonal; Smith, Stella

    2011-01-01

    This paper describes the conversion of an introductory computing course to the blended learning model at a small, public liberal arts college. Blended learning significantly reduces face-to-face instruction by incorporating rich, online learning experiences. To assess the impact of blended learning on students, survey data was collected at the…

  11. On the crystallization behavior of syndiotactic-b-atactic polystyrene stereodiblock copolymers, atactic/syndiotactic polystyrene blends, and aPS/sPS blends modified with sPS-b-aPS

    Energy Technology Data Exchange (ETDEWEB)

    Annunziata, Liana, E-mail: liana.annunziatta@univ-rennes1.fr [Organométalliques et Catalyse, UMR 6226 Sciences Chimiques CNRS, Université de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); Monasse, Bernard, E-mail: bernard.monasse@mines-paristech.fr [Mines-ParisTech, CEMEF, Centre de Mise en Forme des Matériaux, UMR CNRS 7635, Sophia Antipolis (France); Rizzo, Paola; Guerra, Gaetano [Dipartimento di Chimica e Biologia, Università degli studi di Salerno, Via Ponte don Melillo, I-84084 Fisciano, SA (Italy); Duc, Michel [Total Petrochemicals Research Feluy, Zone Industrielle Feluy C, B-7181 Seneffe (Belgium); Carpentier, Jean-François, E-mail: jean-francois.carpentier@univ-rennes1.fr [Organométalliques et Catalyse, UMR 6226 Sciences Chimiques CNRS, Université de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

    2013-09-16

    Crystallization and morphological features of syndiotactic-b-atactic polystyrene stereodiblock copolymers (sPS-b-aPS), atactic/syndiotactic polystyrene blends (aPS/sPS), and aPS/sPS blends modified with sPS-b-aPS, with different compositions in aPS and sPS, have been investigated using differential scanning calorimetry (DSC), polarized light optical microscopy (POM) and wide angle X-ray diffraction (WAXRD) techniques. For comparative purposes, the properties of parent pristine sPS samples were also studied. WAXRD analyses revealed for all the samples, independently from their composition (aPS/sPS ratio) and structure (blends, block copolymers, blends modified with block copolymers), the same polymorphic β form of sPS. The molecular weight of aPS and sPS showed opposite effects on the crystallization of 50:50 aPS/sPS blends: the lower the molecular weight of aPS, the slower the crystallization while the lower the molecular weight of sPS, the faster the crystallization. DSC studies performed under both isothermal and non-isothermal conditions, independently confirmed by POM studies, led to a clear trend for the crystallization rate at a given sPS/aPS ratio (ca. 50:50 and 20:80): sPS homopolymers > sPS-b-aPS block copolymers ∼sPS/aPS blends modified with sPS-b-aPS copolymers > sPS/aPS blends. Interestingly, sPS-b-aPS block copolymers not only crystallized faster than blends, but also affected positively the crystallization behavior of blends. At 50:50 sPS/aPS ratio, blends (Blend-2), block copolymers (Cop-1) and blends modified with block copolymers (Blend-2-mod) crystallized via spherulitic crystalline growth controlled by an interfacial process. In all cases, an instantaneous nucleation was observed. The density of nuclei in block copolymers (160,000−190,000 nuclei mm{sup −3}) was always higher than that in blends and modified blends (30,000−60,000 nuclei mm{sup −3}), even for quite different sPS/aPS ratio. At 20:80 sPS/aPS ratio, the block copolymers

  12. A Novel Method of Extraction of Blend Component Structure from SANS Measurements of Homopolymer Bimodal Blends.

    Science.gov (United States)

    Smerdova, Olga; Graham, Richard S; Gasser, Urs; Hutchings, Lian R; De Focatiis, Davide S A

    2014-05-01

    A new method is presented for the extraction of single-chain form factors and interchain interference functions from a range of small-angle neutron scattering (SANS) experiments on bimodal homopolymer blends. The method requires a minimum of three blends, made up of hydrogenated and deuterated components with matched degree of polymerization at two different chain lengths, but with carefully varying deuteration levels. The method is validated through an experimental study on polystyrene homopolymer bimodal blends with [Formula: see text]. By fitting Debye functions to the structure factors, it is shown that there is good agreement between the molar mass of the components obtained from SANS and from chromatography. The extraction method also enables, for the first time, interchain scattering functions to be produced for scattering between chains of different lengths. [Formula: see text].

  13. Effect of irradiation on the prevulcanized latex/low nitrosamines latex blends

    Energy Technology Data Exchange (ETDEWEB)

    Ibrahim, Pairu; Zin, Wan Manshol Wan [Malaysian Nuclear Agency, 43000 kajang, Selangor (Malaysia); Daik, Rusli [Faculty of Science and Technology, Universiti Kebangsaan Malaysia,43600 bangi, Selangor (Malaysia)

    2015-09-25

    Radiation Prevulcanized Natural Rubber Latex (RVNRL) was blended with Low Nitrosamines Latex (LNL) at different composition ratio. Methyl Metachrylate (MMA) was added for grafting onto the blended latex. Blended latex was subjected to gamma irradiation at various doses up to 8kGy. The mechanical properties and FTIR analysis were investigated as a function of the blended composition and irradiation dose. It was found that blending at specific ratio and gamma irradiation at specific dose led to significant improvement on the properties of the latex. The optimum mechanical properties was attained at a total blending ratio of 70% RVNRL and 30% of LNL.

  14. Linear polarizers based on oriented polymer blends

    NARCIS (Netherlands)

    Jagt, H.J.B.; Dirix, Y.J.L.; Hikmet, R.A.M.; Bastiaansen, C.W.M.

    1998-01-01

    Linear sheet polarizers based on the anisotropic scattering of light by drawn polymer blends are introduced here. The proper selection of materials and processing conditions for the production of large-area, flexible films of phase-segregated polymer blends suitable for polarization applications are

  15. Effect of noise in blending and deblending

    NARCIS (Netherlands)

    Berkhout, A.J.; Blacquière, G.

    2013-01-01

    If simultaneous shooting is carried out by incoherent source arrays, being the condition of blended acquisition, the deblending process generates shot records with a very low residual interference (blending noise). We found, theoretically and numerically, that deblended shot records had a better

  16. Improvement of biodiesel methanol blends

    Directory of Open Access Journals (Sweden)

    Y. Datta Bharadwaz

    2016-06-01

    Full Text Available The main objective of this work was to improve the performance of biodiesel–methanol blends in a VCR engine by using optimized engine parameters. For optimization of the engine, operational parameters such as compression ratio, fuel blend, and load are taken as factors, whereas performance parameters such as brake thermal efficiency (Bth and brake specific fuel consumption (Bsfc and emission parameters such as carbon monoxide (CO, unburnt hydrocarbons (HC, Nitric oxides (NOx and smoke are taken as responses. Experimentation is carried out as per the design of experiments of the response surface methodology. Optimization of engine operational parameters is carried out using Derringers Desirability approach. From the results obtained it is inferred that the VCR engine has maximum performance and minimum emissions at 18 compression ratio, 5% fuel blend and at 9.03 kg of load. At this optimized operating conditions of the engine the responses such as brake thermal efficiency, brake specific fuel consumption, carbon monoxide, unburnt hydrocarbons, nitric oxide, and smoke are found to be 31.95%, 0.37 kg/kW h, 0.036%, 5 ppm, 531.23 ppm and 15.35% respectively. It is finally observed from the mathematical models and experimental data that biodiesel methanol blends have maximum efficiency and minimum emissions at optimized engine parameters.

  17. effect of effect of blend ratio on blend ratio on characteristics

    African Journals Online (AJOL)

    User

    properties, cassava-soybean composite, wheat, bread, blend ratio ... dily growing population, an in eating and ... thermodynamic variables can produce an effect on .... these conditions. ..... Ragaee, S. et al., Pasting properties of starch and.

  18. Improved Mechanical Properties of Compatibilized Polypropylene/Polyamide-12 Blends

    Directory of Open Access Journals (Sweden)

    Nora Aranburu

    2015-01-01

    Full Text Available Compatibilized blends of polypropylene (PP and polyamide-12 (PA12 as a second component were obtained by direct injection molding having first added 20% maleic anhydride-modified copolymer (PP-g-MA to the PP, which produced partially grafted PP (gPP. A nucleating effect of the PA12 took place on the cooling crystallization of the gPP, and a second crystallization peak of the gPP appeared in the PA12-rich blends, indicating changes in the crystalline morphology. There was a slight drop in the PA12 crystallinity of the compatible blends, whereas the crystallinity of the gPP increased significantly in the PA12-rich blends. The overall reduction in the dispersed phase particle size together with the clear increase in ductility when gPP was used instead of PP proved that compatibilization occurred. Young’s modulus of the blends showed synergistic behavior. This is proposed to be both due to a change in the crystalline morphology of the blends on the one hand and, on the other, in the PA12-rich blends, to the clear increase in the crystallinity of the gPP phase, which may, in turn, have been responsible for the increase in its continuity and its contribution to the modulus.

  19. Microlensing Binaries Discovered through High-magnification Channel

    DEFF Research Database (Denmark)

    Shin, I.-G.; Choi, J.-Y.; Park, S.-Y.

    2012-01-01

    Microlensing can provide a useful tool to probe binary distributions down to low-mass limits of binary companions. In this paper, we analyze the light curves of eight binary-lensing events detected through the channel of high-magnification events during the seasons from 2007 to 2010. The perturba......Microlensing can provide a useful tool to probe binary distributions down to low-mass limits of binary companions. In this paper, we analyze the light curves of eight binary-lensing events detected through the channel of high-magnification events during the seasons from 2007 to 2010...

  20. Blended e-learning Design: Discussion of Cultural Issues

    OpenAIRE

    Ahmed A Al-Hunaiyyan; Salah AL-Sharhan; Nabeel Al-Huwail

    2008-01-01

    Blended e-learning is becoming an educational issue especially with the new development of e-learning technology and globalization. Educators as the question: can we design these systems to accommodate different cultural groups and various learning strategies. This paper addresses some design issues when selecting a blended e-learning approach; it discusses some cultural elements that affect the design of blended e-learning. The paper also explores issues related to learning design, then emph...

  1. PAIRWISE BLENDING OF HIGH LEVEL WASTE

    International Nuclear Information System (INIS)

    CERTA, P.J.

    2006-01-01

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending

  2. Performance analysis and binary working fluid selection of combined flash-binary geothermal cycle

    International Nuclear Information System (INIS)

    Zeyghami, Mehdi

    2015-01-01

    Performance of the combined flash-binary geothermal power cycle for geofluid temperatures between 150 and 250 °C is studied. A thermodynamic model is developed, and the suitable binary working fluids for different geofluid temperatures are identified from a list of thirty working fluid candidates, consisting environmental friendly refrigerants and hydrocarbons. The overall system exergy destruction and Vapor Expansion Ratio across the binary cycle turbine are selected as key performance indicators. The results show that for low-temperature heat sources using refrigerants as binary working fluids result in higher overall cycle efficiency and for medium and high-temperature resources, hydrocarbons are more suitable. For combined flash-binary cycle, secondary working fluids; R-152a, Butane and Cis-butane show the best performances at geofluid temperatures 150, 200 and 250 °C respectively. The overall second law efficiency is calculated as high as 0.48, 0.55 and 0.58 for geofluid temperatures equal 150, 200 and 250 °C respectively. The flash separator pressure found to has important effects on cycle operation and performance. Separator pressure dictates the work production share of steam and binary parts of the system. And there is an optimal separator pressure at which overall exergy destruction of the cycle achieves its minimum value. - Highlights: • Performance of the combined flash-binary geothermal cycle is investigated. • Thirty different fluids are screened to find the most suitable ORC working fluid. • Optimum cycle operation conditions presented for geofluids between 150 °C and 250 °C. • Refrigerants are more suitable for the ORC at geothermal sources temperature ≤200 °C. • Hydrocarbons are more suitable for the ORC at geothermal sources temperature >200 °C

  3. BINARY CEPHEIDS: SEPARATIONS AND MASS RATIOS IN 5 M {sub ☉} BINARIES

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Nancy Remage; Karovska, Margarita; Tingle, Evan [Smithsonian Astrophysical Observatory, MS 4, 60 Garden Street, Cambridge, MA 02138 (United States); Bond, Howard E. [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Schaefer, Gail H. [The CHARA Array, Georgia State University, P.O. Box 3965, Atlanta, GA 30302-3965 (United States); Mason, Brian D., E-mail: nevans@cfa.harvard.edu, E-mail: heb11@psu.edu, E-mail: schaefer@chara-array.org [US Naval Observatory, 3450 Massachusetts Avenue, NW, Washington, DC 20392-5420 (United States)

    2013-10-01

    Deriving the distribution of binary parameters for a particular class of stars over the full range of orbital separations usually requires the combination of results from many different observing techniques (radial velocities, interferometry, astrometry, photometry, direct imaging), each with selection biases. However, Cepheids—cool, evolved stars of ∼5 M {sub ☉}—are a special case because ultraviolet (UV) spectra will immediately reveal any companion star hotter than early type A, regardless of the orbital separation. We have used International Ultraviolet Explorer UV spectra of a complete sample of all 76 Cepheids brighter than V = 8 to create a list of all 18 Cepheids with companions more massive than 2.0 M {sub ☉}. Orbital periods of many of these binaries are available from radial-velocity studies, or can be estimated for longer-period systems from detected velocity variability. In an imaging survey with the Hubble Space Telescope Wide Field Camera 3, we resolved three of the companions (those of η Aql, S Nor, and V659 Cen), allowing us to make estimates of the periods out to the long-period end of the distribution. Combining these separations with orbital data in the literature, we derive an unbiased distribution of binary separations, orbital periods, and mass ratios. The distribution of orbital periods shows that the 5 M {sub ☉} binaries have systematically shorter periods than do 1 M {sub ☉} stars. Our data also suggest that the distribution of mass ratios depends on both binary separation and system multiplicity. The distribution of mass ratios as a function of orbital separation, however, does not depend on whether a system is a binary or a triple.

  4. Synthesizing optimal waste blends

    International Nuclear Information System (INIS)

    Narayan, V.; Diwekar, W.M.; Hoza, M.

    1996-01-01

    Vitrification of tank wastes to form glass is a technique that will be used for the disposal of high-level waste at Hanford. Process and storage economics show that minimizing the total number of glass logs produced is the key to keeping cost as low as possible. The amount of glass produced can be reduced by blending of the wastes. The optimal way to combine the tanks to minimize the vole of glass can be determined from a discrete blend calculation. However, this problem results in a combinatorial explosion as the number of tanks increases. Moreover, the property constraints make this problem highly nonconvex where many algorithms get trapped in local minima. In this paper the authors examine the use of different combinatorial optimization approaches to solve this problem. A two-stage approach using a combination of simulated annealing and nonlinear programming (NLP) is developed. The results of different methods such as the heuristics approach based on human knowledge and judgment, the mixed integer nonlinear programming (MINLP) approach with GAMS, and branch and bound with lower bound derived from the structure of the given blending problem are compared with this coupled simulated annealing and NLP approach

  5. Blended Learning or E-learning?

    OpenAIRE

    Tayebinik, Maryam; Puteh, Marlia

    2013-01-01

    ICT or Information and Communication Technology has pervaded the fields of education.In recent years the term e-learning has emerged as a result of the integration of ICT in the education fields. Following the application this technology into teaching, some pitfalls have been identified and this have led to the Blended learning phenomenon.However the preference on this new method has been debated quite extensively.The aim of this paper is to investigate the advantages of blended learning over...

  6. Properties, performance, and applications of biofuel blends: a review

    Directory of Open Access Journals (Sweden)

    Husam Al-Mashhadani

    2017-08-01

    Full Text Available Biofuels such as ethanol and biodiesel derived from living plants or animal matter can be used directly in their neat forms or as blends with their fossil counterparts in internal combustion engines. Although the properties and performance of neat biofuels have been extensively reported, this is not the case for many blends. The purpose of this review is to analyze different forms of biofuel blends that are under research and development comparing their utility and performance in the two primary classes of engines, i.e., spark ignition and compression ignition engines. The fuel properties, performance and emission characteristics, advantages and disadvantages of various fuel blends are compared and discussed. The analysis reveals certain blends possess better overall fuel properties and yield better overall performance than the neat or fossil forms.

  7. The Literature Landscape of Blended Learning in Higher Education: The Need for Better Understanding of Academic Blended Practice

    Science.gov (United States)

    Torrisi-Steele, Geraldine; Drew, Steve

    2013-01-01

    If we are to realise the potential of blended learning in higher education, then further research into academic practice and relevant academic development is essential. Our review of literature on blended learning in higher education reveals an interesting scholarship landscape which, when described in detail, pointedly directs attention to the…

  8. Phase Behavior, Thermal Stability and Rheological Properties of PPEK/PC Blends

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Phase behavior, thermal stability and rheological properties of the blends of poly(phthalazinone ether ketone) (PPEK)with bisphenol-A polycarbonate (PC) prepared by solution coprecipitation were studied using differential scanning calorimetry (DSC), Frourier-Transform IR spectroscopy (FT-IR), thermogravimetric analysis (TGA) and capillary rheometer. The DSC results indicated that PPEK/PC blends are almost immiscible in full compositions. FT-IR investigation showed that there were no apparent specific interactions between the constituent polymers. The blends keep excellent thermal stability and the addition of PC degrades the thermal stability of blends to some degree. The thermal degradation processes of the blends are much similar to that of PC. The studies on rheological properties of blends show that blending PPEK with PC is beneficial to reducing the melt viscosity and improving the appearance of PPEK.

  9. Dissipative binary collisions

    International Nuclear Information System (INIS)

    Aboufirassi, M; Angelique, J.C.; Bizard, G.; Bougault, R.; Brou, R.; Buta, A.; Colin, J.; Cussol, D.; Durand, D.; Genoux-Lubain, A.; Horn, D.; Kerambrun, A.; Laville, J.L.; Le Brun, C.; Lecolley, J.F.; Lefebvres, F.; Lopez, O.; Louvel, M.; Meslin, C.; Metivier, V.; Nakagawa, T.; Peter, J.; Popescu, R.; Regimbart, R.; Steckmeyer, J.C.; Tamain, B.; Vient, E.; Wieloch, A.; Yuasa-Nakagawa, K.

    1998-01-01

    The binary character of the heavy ion collisions at intermediate energies in the exit channel has been observed under 30 MeV/n in medium and heavy systems. Measurements in light systems at energies approaching ∼ 100 MeV/nucleon as well as in very heavy systems have allowed to extend considerably the investigations of this binary process. Thus, the study of the Pb + Au system showed that the complete charge events indicated two distinct sources: the quasi-projectile and the quasi-target. The characteristics of these two sources are rather well reproduced by a trajectory computation which takes into account the Coulomb and nuclear forces and the friction appearing from the projectile-target interaction. The Wilczynski diagram is used to probe the correlation between the kinetic energy quenching and the deflecting angle. In case of the system Pb + Au at 29 MeV/nucleon the diagram indicate dissipative binary collisions typical for low energies. This binary aspect was also detected in the systems Xe + Ag at 44 MeV/nucleon, 36 Ar + 27 Al and 64 Zn + nat Ti. Thus, it was possible to reconstruct the quasi-projectile and to study its mass and excitation energy evolution as a function of the impact parameter. The dissipative binary collisions represent for the systems and energies under considerations the main contribution to the cross section. This does not implies that there are not other processes; particularly, the more or less complete fusion is also observed but with a low cross section which decreases with the increase of bombardment energy. More exclusive measurements with the INDRA detector on quasi-symmetric systems as Ar + KCl and Xe + Sn seem to confirm the importance of the binary collisions. The two source reconstruction of the Xe + Sn data at 50 MeV/nucleon reproduces the same behaviour as that observed in the system Pb + Au at 29 MeV/nucleon

  10. Phosphor blends for high-CRI fluorescent lamps

    Science.gov (United States)

    Setlur, Anant Achyut [Niskayuna, NY; Srivastava, Alok Mani [Niskayuna, NY; Comanzo, Holly Ann [Niskayuna, NY; Manivannan, Venkatesan [Clifton Park, NY; Beers, William Winder [Chesterland, OH; Toth, Katalin [Pomaz, HU; Balazs, Laszlo D [Budapest, HU

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  11. Contact Binaries on Their Way Towards Merging

    Science.gov (United States)

    Gazeas, K.

    2015-07-01

    Contact binaries are the most frequently observed type of eclipsing star system. They are small, cool, low-mass binaries belonging to a relatively old stellar population. They follow certain empirical relationships that closely connect a number of physical parameters with each other, largely because of constraints coming from the Roche geometry. As a result, contact binaries provide an excellent test of stellar evolution, specifically for stellar merger scenarios. Observing campaigns by many authors have led to the cataloging of thousands of contact binaries and enabled statistical studies of many of their properties. A large number of contact binaries have been found to exhibit extraordinary behavior, requiring follow-up observations to study their peculiarities in detail. For example, a doubly-eclipsing quadruple system consisting of a contact binary and a detached binary is a highly constrained system offering an excellent laboratory to test evolutionary theories for binaries. A new observing project was initiated at the University of Athens in 2012 in order to investigate the possible lower limit for the orbital period of binary systems before coalescence, prior to merging.

  12. Permutation Entropy for Random Binary Sequences

    Directory of Open Access Journals (Sweden)

    Lingfeng Liu

    2015-12-01

    Full Text Available In this paper, we generalize the permutation entropy (PE measure to binary sequences, which is based on Shannon’s entropy, and theoretically analyze this measure for random binary sequences. We deduce the theoretical value of PE for random binary sequences, which can be used to measure the randomness of binary sequences. We also reveal the relationship between this PE measure with other randomness measures, such as Shannon’s entropy and Lempel–Ziv complexity. The results show that PE is consistent with these two measures. Furthermore, we use PE as one of the randomness measures to evaluate the randomness of chaotic binary sequences.

  13. Performance Testing of Diesel Engine using Cardanol-Kerosene oil blend

    Directory of Open Access Journals (Sweden)

    Ravindra

    2018-01-01

    Full Text Available Awareness of environmental pollution and fossil fuel depletion has necessitated the use of biofuels in engines which have a relatively cleaner emissions. Cardanol is a biofuel, abundantly available in India, which is a by-product of cashew processing industries. In this study performance of raw Cardanol blended with kerosene has been tested in diesel engine. Volumetric blend BK30 (30% kerosene and 70% Cardanol has been used for the test. The properties like flash point, viscosity and calorific value of the blend have been determined. The test was carried out in four stroke diesel engine connected with an eddy current dynamometer. Performance of the engine has been analysed by finding the brake specific fuel consumption (BSFC and brake thermal efficiency (BTE. The results showed that the brake thermal efficiency of the blend is 29.87%, with less CO and smoke emission compared to diesel. The results were also compared with the performance of Cardanol diesel blend and Cardanol camphor oil blend, which were already tested in diesel engines by other researchers. Earlier research work reveals that the blend of 30% camphor oil and 70% Cardanol performs very closer to diesel fuel with a thermal efficiency of 29.1%. Similarly, higher brake thermal efficiency was obtained for 20% Cardanol and 80% diesel blend.

  14. Ignition characteristics of coal blends in an entrained flow furnace

    Energy Technology Data Exchange (ETDEWEB)

    J. Faundez; B. Arias; F. Rubiera; A. Arenillas; X. Garcia; A.L. Gordon; J.J. Pis [Universidad de Concepcion, Concepcion (Chile)

    2007-09-15

    Ignition tests were carried out on blends of three coals of different rank - subbituminous, high volatile and low volatile bituminous - in two entrained flow reactors. The ignition temperatures were determined from the gas evolution profiles (CO, CO{sub 2}, NO, O{sub 2}), while the mechanism of ignition was elucidated from these profiles and corroborated by high-speed video recording. Under the experimental conditions of high carbon loading, clear interactive effects were observed for all the blends. Ignition of the lower rank coals (subbituminous, high volatile bituminous) enhanced the ignition of the higher rank coal (low volatile bituminous) in the blends. The ignition temperatures of the blends of the low rank coals (subbituminous-high volatile bituminous) were additive. However, for the rest of the blends the ignition temperatures were always closer to the lower rank coal in the blend. 21 refs., 8 figs.

  15. Physico-Chemical, Microbiological Profiles of Blends of Tea and ...

    African Journals Online (AJOL)

    Sample of tea obtained from Mambilla, Nigeria highland was blended with mistletoe - a known medicinal parasitic plant of cocoa. The ratios of the blends were Tea(T)/Mistletoe (M) 90:10 10:90, 75:25, 25:75, and 50:50 while ordinary tea and mistletoes served as control samples. Chemical analyses of blends were done ...

  16. Property Analysis of Ethanol--Natural Gasoline--BOB Blends to Make Flex Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Alleman, Teresa L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Yanowitz, Janet [Ecoengineering, Inc., Sharonville, OH (United States)

    2016-11-01

    Ten natural gasolines were analyzed for a wide range of properties, including Reid vapor pressure (RVP), benzene, sulfur, distillation, stability, metals, and aromatic content, to determine their quality. Benzene and sulfur content were sufficiently low in all but one of the samples that they could be blended without further upgrading. Four of these samples were selected to blend with blendstock for oxygenate blending (BOB) and ethanol to produce E51, E70, and E83 blends, targeting 7.8 and 9.0-psi finished fuels. The volume of each component in the blend was estimated using the Reddy model, with the assumption that the BOB and natural gasoline blend linearly and behave as a single component in the model calculations. Results show that the Reddy model adequately predicts the RVP of the finished blend for E51 and E70, but significantly underpredicts the RVP of E83 blends by nearly 2 psi. It is hypothesized that the underprediction is a function of the very low aromatic content of the E83 blends, even compared to the E51 and E70 blends.

  17. Solution processed ternary blend nano-composite charge regulation layer to enhance inverted OLED performances

    Science.gov (United States)

    Kaçar, Rifat; Mucur, Selin Pıravadılı; Yıldız, Fikret; Dabak, Salih; Tekin, Emine

    2018-04-01

    Inverted bottom-emission organic light emitting diodes (IBOLEDs) have attracted increasing attention due to their exceptional air stability and applications in active-matrix displays. For gaining high IBOLED device efficiencies, it is crucial to develop an effective strategy to make the bottom electrode easy for charge injection and transport. Charge selectivity, blocking the carrier flow towards the unfavourable side, plays an important role in determining charge carrier balance and accordingly radiative recombination efficiency. It is therefore highly desirable to functionalize an interfacial layer which will perform many different tasks simultaneously. Here, we contribute to the hole-blocking ability of the zinc oxide/polyethyleneimine (ZnO:PEI) nano-composite (NC) interlayer with the intention of increasing the OLED device efficiency. With this purpose in mind, a small amount of 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene (TPBi) was added as a hole-blocking molecule into the binary blend of ZnO and PEI solution. The device with a ternary ZnO:PEI:TPBi NC interlayer achieved a maximum current efficiency of 38.20 cd A-1 and a power efficiency of 34.29 lm W-1 with a luminance of 123 200 cd m-2, which are high performance parameters for inverted device architecture. The direct comparisons of device performances incorporating ZnO only, ZnO/PEI bilayers, and ZnO:PEI binary NC counterparts were also performed, which shed light on the origin of device performance enhancement.

  18. Intermediate Ethanol Blends Catalyst Durability Program

    Energy Technology Data Exchange (ETDEWEB)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  19. Binary Systems and the Initial Mass Function

    Science.gov (United States)

    Malkov, O. Yu.

    2017-07-01

    In the present paper we discuss advantages and disadvantages of binary stars, which are important for star formation history determination. We show that to make definite conclusions of the initial mass function shape, it is necessary to study binary population well enough to correct the luminosity function for unresolved binaries; to construct the mass-luminosity relation based on wide binaries data, and to separate observational mass functions of primaries, of secondaries, and of unresolved binaries.

  20. Accuracy of binary black hole waveform models for aligned-spin binaries

    Science.gov (United States)

    Kumar, Prayush; Chu, Tony; Fong, Heather; Pfeiffer, Harald P.; Boyle, Michael; Hemberger, Daniel A.; Kidder, Lawrence E.; Scheel, Mark A.; Szilagyi, Bela

    2016-05-01

    Coalescing binary black holes are among the primary science targets for second generation ground-based gravitational wave detectors. Reliable gravitational waveform models are central to detection of such systems and subsequent parameter estimation. This paper performs a comprehensive analysis of the accuracy of recent waveform models for binary black holes with aligned spins, utilizing a new set of 84 high-accuracy numerical relativity simulations. Our analysis covers comparable mass binaries (mass-ratio 1 ≤q ≤3 ), and samples independently both black hole spins up to a dimensionless spin magnitude of 0.9 for equal-mass binaries and 0.85 for unequal mass binaries. Furthermore, we focus on the high-mass regime (total mass ≳50 M⊙ ). The two most recent waveform models considered (PhenomD and SEOBNRv2) both perform very well for signal detection, losing less than 0.5% of the recoverable signal-to-noise ratio ρ , except that SEOBNRv2's efficiency drops slightly for both black hole spins aligned at large magnitude. For parameter estimation, modeling inaccuracies of the SEOBNRv2 model are found to be smaller than systematic uncertainties for moderately strong GW events up to roughly ρ ≲15 . PhenomD's modeling errors are found to be smaller than SEOBNRv2's, and are generally irrelevant for ρ ≲20 . Both models' accuracy deteriorates with increased mass ratio, and when at least one black hole spin is large and aligned. The SEOBNRv2 model shows a pronounced disagreement with the numerical relativity simulation in the merger phase, for unequal masses and simultaneously both black hole spins very large and aligned. Two older waveform models (PhenomC and SEOBNRv1) are found to be distinctly less accurate than the more recent PhenomD and SEOBNRv2 models. Finally, we quantify the bias expected from all four waveform models during parameter estimation for several recovered binary parameters: chirp mass, mass ratio, and effective spin.

  1. Radial Velocities of 41 Kepler Eclipsing Binaries

    Science.gov (United States)

    Matson, Rachel A.; Gies, Douglas R.; Guo, Zhao; Williams, Stephen J.

    2017-12-01

    Eclipsing binaries are vital for directly determining stellar parameters without reliance on models or scaling relations. Spectroscopically derived parameters of detached and semi-detached binaries allow us to determine component masses that can inform theories of stellar and binary evolution. Here we present moderate resolution ground-based spectra of stars in close binary systems with and without (detected) tertiary companions observed by NASA’s Kepler mission and analyzed for eclipse timing variations. We obtain radial velocities and spectroscopic orbits for five single-lined and 35 double-lined systems, and confirm one false positive eclipsing binary. For the double-lined spectroscopic binaries, we also determine individual component masses and examine the mass ratio {M}2/{M}1 distribution, which is dominated by binaries with like-mass pairs and semi-detached classical Algol systems that have undergone mass transfer. Finally, we constrain the mass of the tertiary component for five double-lined binaries with previously detected companions.

  2. Model for blended learning i de tekniske uddannelser

    DEFF Research Database (Denmark)

    Ringtved, Ulla Lunde; Leth, Lilli-Ann Thomsen; Olsen, Frank

    2012-01-01

    Anvendelse af blended learning i de tekniske uddannelser i UCN med udgangspunkt i bygningskonstruktøruddannelsen......Anvendelse af blended learning i de tekniske uddannelser i UCN med udgangspunkt i bygningskonstruktøruddannelsen...

  3. Utilization of waste expanded polystyrene: Blends with silica-filled natural rubber

    International Nuclear Information System (INIS)

    Sekharan, Renju Vaikathusseril; Abraham, Beena Thattekatt; Thachil, Eby Thomas

    2012-01-01

    Highlights: ► Tensile strength of the silica filled blend is comparable with silica filled NR. ► Modulus and compression set were the best for compatibilized NR/EPS blends. ► Tear strength has increased by 25% for compatibilized blends. ► A 5% waste EPS can be incorporated into NR compounds as a waste management measure. -- Abstract: Expanded polystyrene (EPS) constitutes a considerable part of thermoplastic waste in the environment in terms of volume. In this study, this waste material has been utilized for blending with silica-reinforced natural rubber (NR). The NR/EPS (35/5) blends were prepared by melt mixing in a Brabender Plasticorder. Since NR and EPS are incompatible and immiscible a method has been devised to improve compatibility. For this, EPS and NR were initially grafted with maleic anhydride (MA) using dicumyl peroxide (DCP) to give a graft copolymer. Grafting was confirmed by Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy. This grafted blend was subsequently blended with more of NR during mill compounding. Morphological studies using Scanning Electron Microscopy (SEM) showed better dispersion of EPS in the compatibilized blend compared to the noncompatibilized blend. By this technique, the tensile strength, elongation at break, modulus, tear strength, compression set and hardness of the blend were found to be either at par with or better than that of virgin silica filled NR compound. It is also noted that the thermal properties of the blends are equivalent with that of virgin NR. The study establishes the potential of this method for utilising waste EPS.

  4. Mechanical and thermal properties of physically-blended-plastic films

    International Nuclear Information System (INIS)

    Abu Issa, M. S.

    1983-10-01

    Low density polyethylene (LDPE) and isotactic polypropylene (PP) blend were produced in film form and were characterized by a number of techniques such as wide-angle x-ray diffraction (WAXD), differential thermal analysis (DTA), scanning electron microscopy (SEM), and instron tensile testing. Results of WAXD and DTA showed conclusively that the two components in the blend are incompatible. SEM micrographs indicated that the 60/40 and 40/60 PP/PE blends show approximately fine homogeneous dispersion of the minor component into the matrix of the major component. The mechanical properties of the blend films improved with respect to the PE homo polymer. The improvement was more remarkable with the increase of the PP component in the blend. Results obtained in this work were explained in terms of crystallinity and the crystallite orientation. 28 refs., 29 figs., 5 tabs. (A.M.H.)

  5. Perception of blended learning inventory (POBLI) - development and validation

    DEFF Research Database (Denmark)

    Lassesen, Berit; Rossen, Dorte Sidelmann; Stenalt, Maria Hvid

    and explore how the use of blended learning affects teachers’ approaches to teaching and students’ approaches to learning in higher education. So far, there has been relatively limited research on approaches to teaching in blended learning (González 2010; Lameras et al., 2012). In one study, Ellis et al....... In order to identify appropriate uses of blended learning in Higher Education and to enable the tailoring of teaching approaches to the different needs of an increasingly diverse student body, more knowledge is needed on how to integrate blended learning in educational settings and how best to address...... a new strategic focus on 'Educational IT’ with the purpose of strengthening teaching and learning through use of online interactions. Some of the major challenges in the development of this strategy include how to, identify rationales for using blended learning, stimulate pedagogical reflections...

  6. Planets in Binary Star Systems

    CERN Document Server

    Haghighipour, Nader

    2010-01-01

    The discovery of extrasolar planets over the past decade has had major impacts on our understanding of the formation and dynamical evolution of planetary systems. There are features and characteristics unseen in our solar system and unexplainable by the current theories of planet formation and dynamics. Among these new surprises is the discovery of planets in binary and multiple-star systems. The discovery of such "binary-planetary" systems has confronted astrodynamicists with many new challenges, and has led them to re-examine the theories of planet formation and dynamics. Among these challenges are: How are planets formed in binary star systems? What would be the notion of habitability in such systems? Under what conditions can binary star systems have habitable planets? How will volatiles necessary for life appear on such planets? This volume seeks to gather the current research in the area of planets in binary and multistar systems and to familiarize readers with its associated theoretical and observation...

  7. HEU to LEU conversion and blending facility: Oxide blending alternative to produce LEU oxide for commercial use

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The United States Department of Energy (DOE) is examining options for the disposition of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. Disposition is a process of use or disposal of material that results in the material being converted to a form that is substantially and inherently more proliferation-resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. This document provides data to be used in the environmental impact analysis for the oxide blending HEU disposition option. This option provides for a yearly HEU throughput of 1 0 metric tons (MT) of uranium metal with an average U235 assay of 50% blended with 165 MT of natural assay triuranium octoxide (U{sub 3} O{sub 8}) per year to produce 177 MT of 4% U235 assay U{sub 3} O{sub 8}, for LWR fuel. Since HEU exists in a variety of forms and not necessarily in the form to be blended, worst case scenarios for preprocessing prior to blending will be assumed for HEU feed streams.

  8. An investigation on chloroprene-compatibilized acrylonitrile butadiene rubber/high density polyethylene blends.

    Science.gov (United States)

    Ahmed, Khalil

    2015-11-01

    Blends of acrylonitrile butadiene rubber/high density polyethylene (NBR/HDPE) compatibilized by Chloroprene rubber (CR) were prepared. A fixed quantity of industrial waste such as marble waste (MW, 40 phr) was also included. The effect of the blend ratio and CR on cure characteristics, mechanical and swelling properties of MW-filled NBR/HDPE blends was investigated. The results showed that the MW-filled NBR/HDPE blends revealed an increase in tensile strength, tear, modulus, hardness and cross-link density for increasing weight ratio of HDPE. The minimum torque (M L) and maximum torque (M H) of blends increased with increasing weight ratio of HDPE while scorch time (ts2) cure time (tc90), compression set and abrasion loss of blends decreased with increasing weight ratio of HDPE. The blends also showed a continuous reduction in elongation at break as well as swelling coefficient with increasing HDPE amount in blends. MW filled blends based on CR provided the most encouraging balance values of overall properties.

  9. An investigation on chloroprene-compatibilized acrylonitrile butadiene rubber/high density polyethylene blends

    Directory of Open Access Journals (Sweden)

    Khalil Ahmed

    2015-11-01

    Full Text Available Blends of acrylonitrile butadiene rubber/high density polyethylene (NBR/HDPE compatibilized by Chloroprene rubber (CR were prepared. A fixed quantity of industrial waste such as marble waste (MW, 40 phr was also included. The effect of the blend ratio and CR on cure characteristics, mechanical and swelling properties of MW-filled NBR/HDPE blends was investigated. The results showed that the MW-filled NBR/HDPE blends revealed an increase in tensile strength, tear, modulus, hardness and cross-link density for increasing weight ratio of HDPE. The minimum torque (ML and maximum torque (MH of blends increased with increasing weight ratio of HDPE while scorch time (ts2 cure time (tc90, compression set and abrasion loss of blends decreased with increasing weight ratio of HDPE. The blends also showed a continuous reduction in elongation at break as well as swelling coefficient with increasing HDPE amount in blends. MW filled blends based on CR provided the most encouraging balance values of overall properties.

  10. Mechanical Properties of Dynamically Vulcanized Thermoplastic Polyurethane (TPU/Polybutadiene Rubber (BR Blends

    Directory of Open Access Journals (Sweden)

    Ji-Hoo Kim

    2017-01-01

    Full Text Available To obtain thermoplastic polyurethane (TPU with low hardness, dynamically vulcanized TPU/polybutadiene rubber(BR(70/30 blends were prepared. The effect of dicumyl peroxide (DCP content and stabilizers on the tensile strength and elongation at break of the dynamically vulcanized blends was examined. The tensile strength and elongation at break of the dynamically vulcanized blends decrease with increasing content of DCP. The addition of optimal content of stabilizer leads to the improvement of tensile strength and elongation at break of the blends. Also, the effect of sulfur cure systems and accelerators on the tensile strength and elongation of the blends was investigated. The tensile strength and elongation at break of all the dynamically vulcanized TPU/BR (70/30 blends using 1-step processing are not higher than those of simple TPU/BR (70/30 blends. However, the tensile strength and elongation of the dynamically vulcanized blends prepared at 8 min (mixing time using 2-step processing are higher than those of the simple blends.

  11. A Study on Students’ Views On Blended Learning Environment

    Directory of Open Access Journals (Sweden)

    Meryem YILMAZ SOYLU

    2006-07-01

    Full Text Available In the 21st century, information and communication technologies (ICT have developed rapidly and influenced most of the fields and education as well. Then, ICT have offered a favorable environment for the development and use of various methods and tools. With the developments in technology, blended learning has gained considerable popularity in recent years. Together with the developments it brought along the description of particular forms of teaching with technology. Blended learning is defined simply as a learning environment that combines technology with face-to-face learning. In other words blended learning means using a variety of delivery methods to best meet the course objectives by combining face-to-face teaching in a traditional classroom with teaching online. This article examines students’ views on blended learning environment. The study was conducted on 64 students from Department of Computer Education and Instructional Technologies in 2005–2006 fall semester in Instructional Design and Authoring Languages in PC Environment at Hacettepe University. The results showed that the students enjoyed taking part in the blended learning environment. Students’ achievement levels and their frequency of participation to forum affected their views about blended learning environment. Face-to-face interaction in blended learning application had the highest score. This result demonstrated the importance of interaction and communication for the success of on-line learning.

  12. Theoretical studies of binaries in astrophysics

    Science.gov (United States)

    Dischler, Johann Sebastian

    This thesis introduces and summarizes four papers dealing with computer simulations of astrophysical processes involving binaries. The first part gives the rational and theoretical background to these papers. In paper I and II a statistical approach to studying eclipsing binaries is described. By using population synthesis models for binaries the probabilities for eclipses are calculated for different luminosity classes of binaries. These are compared with Hipparcos data and they agree well if one uses a standard input distribution for the orbit sizes. If one uses a random pairing model, where both companions are independently picked from an IMF, one finds too feclipsing binaries by an order of magnitude. In paper III we investigate a possible scenario for the origin of the stars observed close to the centre of our galaxy, called S stars. We propose that a cluster falls radially cowards the central black hole. The binaries within the cluster can then, if they have small impact parameters, be broken up by the black hole's tidal held and one of the components of the binary will be captured by the black hole. Paper IV investigates how the onset of mass transfer in eccentric binaries depends on the eccentricity. To do this we have developed a new two-phase SPH scheme where very light particles are at tire outer edge of our simulated star. This enables us to get a much better resolution of the very small mass that is transferred in close binaries. Our simulations show that the minimum required distance between the stars to have mass transfer decreases with the eccentricity.

  13. Meeting Diverse Learner Needs with Blended Learning

    Science.gov (United States)

    Owen, Hazel

    2010-01-01

    This article describes a 40-week Computer, Research Skills, and Projects (CRSP) blended learning course designed and implemented at Dubai Men's College. The learning employed a design using socio-constructivist principles in the blended approach to cater to the learning preferences of students. (Contains 2 figures and 1 footnote.)

  14. Effects of blending on the properties of diesel and palm biodiesel

    Science.gov (United States)

    Bukkarapu, Kiran Raj; Srinivas Rahul, T.; Kundla, Sivaji; Vishnu Vardhan, G.

    2018-03-01

    Palm biodiesel is blended to diesel in different volume percentages to improve certain properties. This would help in having a good understanding of the dependence of the diesel properties on the biodiesel proportion. The properties of interest in the present work are density, kinematic viscosity, flash point and fire point of the blends which are determined and compared to petrodiesel. It is observed that the kinematic viscosity and density of the diesel increase with the palm biodiesel proportion and it is not preferable. Blends with higher palm content possess higher flash point and fire point. Apparently, blending worsens the conditions and hence might be of no use when compared to diesel, but when compared to neat palm biodiesel, blending helped in pulling down the density, viscosity, fire point and flash point of the latter. Using regression analysis and the properties data of respective blends, correlations are developed to predict the properties of diesel and biodiesel blends known the percentage of biodiesel added to diesel, which are validated using biodiesel and diesel blends which are not used as an input to develop them.

  15. Thermoset Blends of an Epoxy Resin and Polydicyclopentadiene

    Energy Technology Data Exchange (ETDEWEB)

    Rohde, Brian J.; Le, Kim Mai; Krishnamoorti, Ramanan; Robertson, Megan L.

    2016-12-13

    The mechanical properties of two chemically distinct and complementary thermoset polymers were manipulated through development of thermoset blends. The thermoset blend system was composed of an anhydride-cured diglycidyl ether of bisphenol A (DGEBA)-based epoxy resin, contributing high tensile strength and modulus, and polydicyclopentadiene (PDCPD), which has a higher toughness and impact strength as compared to other thermoset polymers. Ultra-small-angle and small-angle X-ray scattering analysis explored the morphology of concurrently cured thermoset blends, revealing a macroscopically phase separated system with a surface fractal structure across blended systems of varying composition. The epoxy resin rich and PDCPD rich phases exhibited distinct glass transitions (Tg’s): the Tg observed at higher temperature was associated with the epoxy resin rich phase and was largely unaffected by the presence of PDCPD, whereas the PDCPD rich phase Tg systematically decreased with increasing epoxy resin content due to inhibition of dicyclopentadiene ring-opening metathesis polymerization. The mechanical properties of these phase-separated blends were in reasonable agreement with predictions by the rule of mixtures for the blend tensile strength, modulus, and fracture toughness. Scanning electron microscopy analysis of the tensile and fracture specimen fracture surfaces showed an increase in energy dissipation mechanisms, such as crazing, shear banding, and surface roughness, as the fraction of the more ductile component, PDPCD, increased. These results present a facile method to tune the mechanical properties of a toughened thermoset network, in which the high modulus and tensile strength of the epoxy resin can be largely retained at high epoxy resin content in the blend, while increasing the fracture toughness.

  16. Proton exchange membranes based on PVDF/SEBS blends

    Energy Technology Data Exchange (ETDEWEB)

    Mokrini, A.; Huneault, M.A. [Industrial Materials Institute, National Research Council of Canada, 75 de Mortagne Blvd., Boucherville, Que. (Canada J4B 6Y4)

    2006-03-09

    Proton-conductive polymer membranes are used as an electrolyte in the so-called proton exchange membrane fuel cells. Current commercially available membranes are perfluorosulfonic acid polymers, a class of high-cost ionomers. This paper examines the potential of polymer blends, namely those of styrene-(ethylene-butylene)-styrene block copolymer (SEBS) and polyvinylidene fluoride (PVDF), in the proton exchange membrane application. SEBS/PVDF blends were prepared by twin-screw extrusion and the membranes were formed by calendering. SEBS is a phase-segregated material where the polystyrene blocks can be selectively functionalized offering high ionic conductivity, while PVDF insures good dimensional stability and chemical resistance to the films. Proton conductivity of the films was obtained by solid-state grafting of sulfonic acid moieties. The obtained membranes were characterized in terms of conductivity, ionic exchange capacity and water uptake. In addition, the membranes were characterized in terms of morphology, microstructure and thermo-mechanical properties to establish the blends morphology-property relationships. Modification of interfacial properties between SEBS and PVDF was found to be a key to optimize the blends performance. Addition of a methyl methacrylate-butyl acrylate-methyl methacrylate block copolymer (MMA-BA-MMA) was found to compatibilize the blend by reducing the segregation scale and improving the blend homogeneity. Mechanical resistance of the membranes was also improved through the addition of this compatibilizer. As little as 2wt.% compatibilizer was sufficient for complete interfacial coverage and lead to improved mechanical properties. Compatibilized blend membranes also showed higher conductivities, 1.9x10{sup -2} to 5.5x10{sup -3}Scm{sup -1}, and improved water management. (author)

  17. Mining frequent binary expressions

    NARCIS (Netherlands)

    Calders, T.; Paredaens, J.; Kambayashi, Y.; Mohania, M.K.; Tjoa, A.M.

    2000-01-01

    In data mining, searching for frequent patterns is a common basic operation. It forms the basis of many interesting decision support processes. In this paper we present a new type of patterns, binary expressions. Based on the properties of a specified binary test, such as reflexivity, transitivity

  18. SYSTEM APPROACH TO THE BLENDED LEARNING

    Directory of Open Access Journals (Sweden)

    Vladimir Kukharenko

    2015-10-01

    Full Text Available Currently, much attention is paid to the development of learning sour cream – a combination of traditional and distance (30-70% of training. Such training is sometimes called hybrid and referred to disruptive technologies. Purpose – to show that the use of systemic campaign in blended learning provides a high quality of education, and the technology can be devastating. The subject of the study – blended learning, object of study – Mixed learning process. The analysis results show that the combined training increases the motivation of students, qualification of teachers, personalized learning process. At the same time there are no reliable methods of assessing the quality of education and training standards. It is important that blended learning strategy to support the institutional goals and had an effective organizational model for support.

  19. Phase Segregation in Polystyrene?Polylactide Blends

    Energy Technology Data Exchange (ETDEWEB)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  20. Survival of planets around shrinking stellar binaries.

    Science.gov (United States)

    Muñoz, Diego J; Lai, Dong

    2015-07-28

    The discovery of transiting circumbinary planets by the Kepler mission suggests that planets can form efficiently around binary stars. None of the stellar binaries currently known to host planets has a period shorter than 7 d, despite the large number of eclipsing binaries found in the Kepler target list with periods shorter than a few days. These compact binaries are believed to have evolved from wider orbits into their current configurations via the so-called Lidov-Kozai migration mechanism, in which gravitational perturbations from a distant tertiary companion induce large-amplitude eccentricity oscillations in the binary, followed by orbital decay and circularization due to tidal dissipation in the stars. Here we explore the orbital evolution of planets around binaries undergoing orbital decay by this mechanism. We show that planets may survive and become misaligned from their host binary, or may develop erratic behavior in eccentricity, resulting in their consumption by the stars or ejection from the system as the binary decays. Our results suggest that circumbinary planets around compact binaries could still exist, and we offer predictions as to what their orbital configurations should be like.

  1. Close-binary central stars of planetary nebulae

    International Nuclear Information System (INIS)

    Bond, H.E.; Grauer, A.D.

    1987-01-01

    Recent observations of PN central stars identified as binary systems are reviewed. The theoretical significance of binary central stars is discussed, and the characteristics of UU Sge, V 477 Lyr, MT Ser, LSS 2018, VW Pyx, and the central star of HFG 1 are briefly summarized. All of these binaries are shown to have periods less than 1 day, and it is estimated that about 10 percent of all binary central stars are close binaries. 27 references

  2. Bondi-Hoyle-Lyttleton Accretion onto Binaries

    Science.gov (United States)

    Antoni, Andrea; MacLeod, Morgan; Ramírez-Ruiz, Enrico

    2018-01-01

    Binary stars are not rare. While only close binary stars will eventually interact with one another, even the widest binary systems interact with their gaseous surroundings. The rates of accretion and the gaseous drag forces arising in these interactions are the key to understanding how these systems evolve. This poster examines accretion flows around a binary system moving supersonically through a background gas. We perform three-dimensional hydrodynamic simulations of Bondi-Hoyle-Lyttleton accretion using the adaptive mesh refinement code FLASH. We simulate a range of values of semi-major axis of the orbit relative to the gravitational focusing impact parameter of the pair. On large scales, gas is gravitationally focused by the center-of-mass of the binary, leading to dynamical friction drag and to the accretion of mass and momentum. On smaller scales, the orbital motion imprints itself on the gas. Notably, the magnitude and direction of the forces acting on the binary inherit this orbital dependence. The long-term evolution of the binary is determined by the timescales for accretion, slow down of the center-of-mass, and decay of the orbit. We use our simulations to measure these timescales and to establish a hierarchy between them. In general, our simulations indicate that binaries moving through gaseous media will slow down before the orbit decays.

  3. Structural characterization of Poly aniline blended with polyacrylamide

    International Nuclear Information System (INIS)

    Fayek, S.A.; El-Sayed, S.M.; Sayed, W.M.

    2007-01-01

    Poly aniline / polyacrylamide blends in presence of different catalysts were prepared. X-ray diffraction studies reveal that the samples produced are crystalline. Optical gap of the blend in the presence of NaCIO 4 used as a catalyst is greater than that in the presence of (NH 4 ) 2 S 2 O 8 as a catalyst. The structure of polyacrylamide (PAM) blended with poly aniline (PANI) were investigated by infrared spectroscopy, Grain size was identified using scanning electron microscopy [SEM

  4. Preparation and Characterization of Keratin/Alginate Blend Microparticles

    OpenAIRE

    Srisuwan, Yaowalak; Srihanam, Prasong

    2018-01-01

    The water-in-oil (W/O) emulsification-diffusion method was used for construction of keratin (Ker), alginate (Alg), and Ker/Alg blend microparticles. The Ker, Alg, and Ker/Alg blend solutions were used as the water phase, while ethyl acetate was used as the oil phase. Firstly, different concentrations of Ker solution was used to find suitable content. 1.6% w/v Ker solution was blended with the same concentration of the Alg solution for further microparticle construction. Results from scanning ...

  5. Flippin' Fluid Mechanics - Comparison of Blended Classroom vs. Traditional Lecture

    Science.gov (United States)

    Webster, D. R.; Kadel, R. S.; Newstetter, W. C.

    2017-11-01

    We conducted a study of student performance in and perceptions of a blended classroom delivery of a junior-level fluid mechanics course. In the blended pedagogy, students watch short on-line videos before class, participate in interactive in-class problem solving (in dyads), and complete individualized on-line quizzes weekly. Comparisons are made among four sections of the blended classroom delivery in the period of 2013-2017 to eleven sections delivered in a traditional lecture-style format by the same instructor in 2002-2012. The results reveal dramatic improvement in student engagement, perceptions, and achievement in the blended pedagogy. For instance, the withdrawal/fail/barely-passing (WFD) rate is significantly lower for the blended classroom (8.6% vs. 16.3%; p self-perception of how-much-learned, perception of the value of the course activities, and the overall effectiveness of the course and instructor in the blended classroom.

  6. Influence of biodiesel blending on physicochemical properties and importance of mathematical model for predicting the properties of biodiesel blend

    International Nuclear Information System (INIS)

    Wakil, M.A.; Kalam, M.A.; Masjuki, H.H.; Atabani, A.E.; Rizwanul Fattah, I.M.

    2015-01-01

    Highlights: • Short identification of selected biodiesel feedstock. • Review of physicochemical properties for blended biodiesel. • Mathematical model for predicting properties of various biodiesel blends. - Abstract: The growing demand for green world serves as one of the most significant challenges of modernization. Requirements like largest usage of energy for modern society as well as demand for friendly milieu create a deep concern in field of research. Biofuels are placed at the peak of the research arena for their underlying benefits as mentioned by multiple researches. Out of a number of vegetable oils, only a few are used commercially for biodiesel production. Due to various limitations of edible oil, non-edible oils are becoming a profitable choice. Till today, very little percentage of biodiesel is used successfully in engine. The research is still continuing for improving the biodiesel usage level. Recently, it is found that the blended biodiesel from more than one feedstock provides better performance in engine. This paper reviews the physicochemical properties of different biodiesel blends obtained from various feedstocks with a view to properly understand the fuel quality. Moreover, a short description of each feedstock is given along with graphical presentation of important properties for various blend percentages from B0 to B100. Finally, mathematical model is formed for predicting various properties of biodiesel blend with the help of different research data by using polynomial curve fitting method. The results obtained from a number of literature based on this work shows that the heating value of biodiesel is about 11% lower than diesel except coconut (14.5% lower) whereas kinematic viscosity is in the range of 4–5.4 mm 2 /s. Flash point of all biodiesels are more than 150 °C, except neem and coconut. Cold flow properties of calophyllum, palm, jatropha, moringa are inferior to others. This would help to determine important properties of

  7. X-ray blending device

    International Nuclear Information System (INIS)

    Manolov, S.S.; Donchev, I.D.; Paunchev, A.N.; Atanasov, A.B.; Kerin, T.P.

    1985-01-01

    The X-ray blending device comprises electric motors for vertical and horizontal blending plates, electrically connected with the output of the block for format voltages and mechanically connected with the measuring potentiometers' slides. The potentiometers are respectively connected with the data inputs of the block for format voltages, the control input of which is connected with the control block output in a mode of scanning. The data outputs of the format voltage block are connected through a buffer converter, a memory block and a decoder with the data inputs of the first and second digital-to-analog converters, the outputs of which are connected with the first inputs of the first and the second comparison circuits. The second inputs of the last are linked to the slides of the first and the second potentiometers and their inputs are connected with the data inputs of the first and the second combinational logic circuits. The output of the control block in a mode of scanning is connected with the first control inputs of the first and the second combinational logic circuits and with the control inputs of the memory block and the decoder. The second and the third control units of the first and the second combinational circuits are respectively linked with the outputs for a position determination of the vertical and horizontal blending plates from the control block in a mode of scanning. The outputs of the first and the second combinational logic circuits are respectively connected with the first and the second control bridge circuits, the control outputs of which are electrically connected with the first and the second electric motors for vertical and horizontal blending plates. 1 cl., 3 figs

  8. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    International Nuclear Information System (INIS)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-01-01

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H + ] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  9. Formation and Evolution of X-ray Binaries

    Science.gov (United States)

    Shao, Y.

    2017-07-01

    X-ray binaries are a class of binary systems, in which the accretor is a compact star (i.e., black hole, neutron star, or white dwarf). They are one of the most important objects in the universe, which can be used to study not only binary evolution but also accretion disks and compact stars. Statistical investigations of these binaries help to understand the formation and evolution of galaxies, and sometimes provide useful constraints on the cosmological models. The goal of this thesis is to investigate the formation and evolution processes of X-ray binaries including Be/X-ray binaries, low-mass X-ray binaries (LMXBs), ultraluminous X-ray sources (ULXs), and cataclysmic variables. In Chapter 1 we give a brief review on the basic knowledge of the binary evolution. In Chapter 2 we discuss the formation of Be stars through binary interaction. In this chapter we investigate the formation of Be stars resulting from mass transfer in binaries in the Galaxy. Using binary evolution and population synthesis calculations, we find that in Be/neutron star binaries the Be stars have a lower limit of mass ˜ 8 M⊙ if they are formed by a stable (i.e., without the occurrence of common envelope evolution) and nonconservative mass transfer. We demonstrate that the isolated Be stars may originate from both mergers of two main-sequence stars and disrupted Be binaries during the supernova explosions of the primary stars, but mergers seem to play a much more important role. Finally the fraction of Be stars produced by binary interactions in all B type stars can be as high as ˜ 13%-30% , implying that most of Be stars may result from binary interaction. In Chapter 3 we show the evolution of intermediate- and low-mass X-ray binaries (I/LMXBs) and the formation of millisecond pulsars. Comparing the calculated results with the observations of binary radio pulsars, we report the following results: (1) The allowed parameter space for forming binary pulsars in the initial orbital period

  10. Modelling binary data

    CERN Document Server

    Collett, David

    2002-01-01

    INTRODUCTION Some Examples The Scope of this Book Use of Statistical Software STATISTICAL INFERENCE FOR BINARY DATA The Binomial Distribution Inference about the Success Probability Comparison of Two Proportions Comparison of Two or More Proportions MODELS FOR BINARY AND BINOMIAL DATA Statistical Modelling Linear Models Methods of Estimation Fitting Linear Models to Binomial Data Models for Binomial Response Data The Linear Logistic Model Fitting the Linear Logistic Model to Binomial Data Goodness of Fit of a Linear Logistic Model Comparing Linear Logistic Models Linear Trend in Proportions Comparing Stimulus-Response Relationships Non-Convergence and Overfitting Some other Goodness of Fit Statistics Strategy for Model Selection Predicting a Binary Response Probability BIOASSAY AND SOME OTHER APPLICATIONS The Tolerance Distribution Estimating an Effective Dose Relative Potency Natural Response Non-Linear Logistic Regression Models Applications of the Complementary Log-Log Model MODEL CHECKING Definition of Re...

  11. Sensitivity comparison of two L-alanine doped blends to different photon energies

    International Nuclear Information System (INIS)

    Chen, Felipe; Vega Ramirez, Jose; Nicolucci, Patricia; Baffa, Oswaldo

    2008-01-01

    Full text: Blends of L-alanine (85% weight proportion) with KI (10%) and with PbI 2 (10%), these last two compounds acting as dopants, and with PVA (5%) acting as binder, were prepared in water at 80 C degrees. A blend of pure L-alanine (95%) with PVA (5%) was also prepared. The three blends were irradiated with photon beams of different energies (120 kV, 60 Co and 10 MV) with a unique dose of 30 Gy to compare their sensitivities for those three energies. EPR spectra of the three irradiated blends were recorded in a K-Band spectrometer (24 GHz) taking aliquots of about 4 mg for each blend. The energy sensitivity of a blend was defined as the peak-to-peak amplitude of its EPR spectrum central line. For the 60 Co energy (1.25 MeV) the blends presented practically the same sensitivity indicating that the presence of the dopants does not affect the sensitivity of L-alanine. For 10 MV X-rays there was an increment (around 20% - 30 %) in sensitivity for the two L-alanine doped blends compared with the pure L-alanine blend (not doped). In the case of 120 kV X-rays, the blends ala+KI and ala+PbI 2 showed an increment of 10 and 20 times, respectively, more sensitivity than the pure L-alanine blend. It is concluded that the dopants KI and PbI 2 produce a great enhance of the L-alanine sensitivity to low-energy photons. For the same dopant's content (10%) in the blend, PbI 2 showed a better performance. These results encourage us to try to enhance the sensitivity of L-alanine even more increasing the dopant's content in the blend. Application of these L-alanine doped blends in the dosimetry in diagnostic radiology could be possible. (author)

  12. Poly(hydroxybutyrate)/cellulose acetate blend nanofiber scaffolds: Preparation, characterization and cytocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Zhijiang, Cai, E-mail: caizhijiang@hotmail.com [School of Textiles, Tianjin Polytechnic University, Tianjin 300387 (China); State Key Laboratory of Hollow Fiber Membrane Material and Processes, No 399 BingShuiXi Street, XiQing District, Tianjin, China, 300387 (China); Yi, Xu; Haizheng, Yang; Jia, Jianru; Liu, Yuanpei [School of Textiles, Tianjin Polytechnic University, Tianjin 300387 (China)

    2016-01-01

    Poly(hydroxybutyrate) (PHB)/cellulose acetate (CA) blend nanofiber scaffolds were fabricated by electrospinning using the blends of chloroform and DMF as solvent. The blend nanofiber scaffolds were characterized by SEM, FTIR, XRD, DSC, contact angle and tensile test. The blend nanofibers exhibited cylindrical, uniform, bead-free and random orientation with the diameter ranged from 80–680 nm. The scaffolds had very well interconnected porous fibrous network structure and large aspect surface areas. It was found that the presence of CA affected the crystallization of PHB due to formation of intermolecular hydrogen bonds, which restricted the preferential orientation of PHB molecules. The DSC result showed that the PHB and CA were miscible in the blend nanofiber. An increase in the glass transition temperature was observed with increasing CA content. Additionally, the mechanical properties of blend nanofiber scaffolds were largely influenced by the weight ratio of PHB/CA. The tensile strength, yield strength and elongation at break of the blend nanofiber scaffolds increased from 3.3 ± 0.35 MPa, 2.8 ± 0.26 MPa, and 8 ± 0.77% to 5.05 ± 0.52 MPa, 4.6 ± 0.82 MPa, and 17.6 ± 1.24% by increasing PHB content from 60% to 90%, respectively. The water contact angle of blend nanofiber scaffolds decreased about 50% from 112 ± 2.1° to 60 ± 0.75°. The biodegradability was evaluated by in vitro degradation test and the results revealed that the blend nanofiber scaffolds showed much higher degradation rates than the neat PHB. The cytocompatibility of the blend nanofiber scaffolds was preliminarily evaluated by cell adhesion studies. The cells incubated with PHB/CA blend nanofiber scaffold for 48 h were capable of forming cell adhesion and proliferation. It showed much better biocompatibility than pure PHB film. Thus, the prepared PHB/CA blend nanofiber scaffolds are bioactive and may be more suitable for cell proliferation suggesting that these scaffolds can be used for

  13. Preparing Teachers for Emerging Blended Learning Environments

    Science.gov (United States)

    Oliver, Kevin M.; Stallings, Dallas T.

    2014-01-01

    Blended learning environments that merge learning strategies, resources, and modes have been implemented in higher education settings for nearly two decades, and research has identified many positive effects. More recently, K-12 traditional and charter schools have begun to experiment with blended learning, but to date, research on the effects of…

  14. Blended Interaction Spaces for Collaborative Design

    DEFF Research Database (Denmark)

    Dalsgaard, Peter; Halskov, Kim; Klokmose, Clemens Nylandsted

    During the past five years, we have explored the use, potentials and challenges of Blended Interaction spaces. In addition, we have a long background in developing and exploring methods for collaborative design. In this workshop paper, we give an overview of our work and present our visions...... and ongoing research in developing Blended Interaction spaces for collaborative design. We then identify key themes and challenges pertinent for the workshop....

  15. Inkjet-Printed Organic Transistors Based on Organic Semiconductor/Insulating Polymer Blends.

    Science.gov (United States)

    Kwon, Yoon-Jung; Park, Yeong Don; Lee, Wi Hyoung

    2016-08-02

    Recent advances in inkjet-printed organic field-effect transistors (OFETs) based on organic semiconductor/insulating polymer blends are reviewed in this article. Organic semiconductor/insulating polymer blends are attractive ink candidates for enhancing the jetting properties, inducing uniform film morphologies, and/or controlling crystallization behaviors of organic semiconductors. Representative studies using soluble acene/insulating polymer blends as an inkjet-printed active layer in OFETs are introduced with special attention paid to the phase separation characteristics of such blended films. In addition, inkjet-printed semiconducting/insulating polymer blends for fabricating high performance printed OFETs are reviewed.

  16. HIGH SCHOOL STUDENTS’ VIEWS ON BLENDED LEARNING

    Directory of Open Access Journals (Sweden)

    Ibrahim Umit YAPICI,

    2012-08-01

    Full Text Available In this study, it is aimed to determine the high school students’ views on blended learning. The study was carried out in biology course for the lesson unit of “Classification of Living Things and Biodiversity” with 47 9th grade students attending Nevzat Ayaz Anatolian High School in the second term of the academic year of 2009-2010. The lessons were taught in a way appropriate to the blended learning model both via the Internet and on face-to-face basis. As the online dimension of the blended learning model, Moodle, a Learning Management System (LMS, was used. The application lasted 10 weeks. The scale of learners’ views on blended learning was applied and interviews were held to determine the views. As a result of the analysis of the scale, it was seen that their views were “highly” positive. The interviews held with the students revealed that the blended learning model provided students with various opportunities such as getting prepared for the lessons, reviewing the lessons as many times as wanted, reaching the subject-related materials without being dependent on time and place, testing oneself and communicating with the teacher and other students out of the school. The interviews also revealed that there were various problems though such as lack of Internet connection at home and problems experienced while playing the videos.

  17. Biocompatible electrospun polymer blends for biomedical applications.

    Science.gov (United States)

    Munj, Hrishikesh Ramesh; Nelson, M Tyler; Karandikar, Prathamesh Sadanand; Lannutti, John Joseph; Tomasko, David Lane

    2014-10-01

    Blends of natural and synthetic polymers have received considerable attention as biomaterials due to the potential to optimize both mechanical and bioactive properties. Electrospinning of biocompatible polymers is an efficient method producing biomimetic topographies suited to various applications. In the ultimate application, electrospun scaffolds must also incorporate drug/protein delivery for effective cell growth and tissue repair. This study explored the suitability of a ternary Polymethylmethacrylate-Polycaprolactone-gelatin blend in the preparation of electrospun scaffolds for biomedical applications. Tuning the blend composition allows control over scaffold mechanical properties and degradation rate. Significant improvements were observed in the mechanical properties of the blend compared with the individual components. In order to study drug delivery potential, triblends were impregnated with the model compound Rhodamine-B using sub/supercritical CO₂ infusion under benign conditions. Results show significantly distinct release profiles of the impregnated dye from the triblends. Specific factors such as porosity, degradation rate, stress relaxation, dye-polymer interactions, play key roles in impregnation and release. Each polymer component of the triblends shows distinct behavior during impregnation and release process. This affects the aforementioned factors and the release profiles of the dye. Careful control over blend composition and infusion conditions creates the flexibility needed to produce biocompatible electrospun scaffolds for a variety of biomedical applications. © 2014 Wiley Periodicals, Inc.

  18. Formation and evolution of compact binaries

    NARCIS (Netherlands)

    Sluijs, Marcel Vincent van der

    2006-01-01

    In this thesis we investigate the formation and evolution of compact binaries. Chapters 2 through 4 deal with the formation of luminous, ultra-compact X-ray binaries in globular clusters. We show that the proposed scenario of magnetic capture produces too few ultra-compact X-ray binaries to explain

  19. Organic non-volatile memories from ferroelectric phase-separated blends

    Science.gov (United States)

    Asadi, Kamal; de Leeuw, Dago M.; de Boer, Bert; Blom, Paul W. M.

    2008-07-01

    New non-volatile memories are being investigated to keep up with the organic-electronics road map. Ferroelectric polarization is an attractive physical property as the mechanism for non-volatile switching, because the two polarizations can be used as two binary levels. However, in ferroelectric capacitors the read-out of the polarization charge is destructive. The functionality of the targeted memory should be based on resistive switching. In inorganic ferroelectrics conductivity and ferroelectricity cannot be tuned independently. The challenge is to develop a storage medium in which the favourable properties of ferroelectrics such as bistability and non-volatility can be combined with the beneficial properties provided by semiconductors such as conductivity and rectification. Here we present an integrated solution by blending semiconducting and ferroelectric polymers into phase-separated networks. The polarization field of the ferroelectric modulates the injection barrier at the semiconductor-metal contact. The combination of ferroelectric bistability with (semi)conductivity and rectification allows for solution-processed non-volatile memory arrays with a simple cross-bar architecture that can be read out non-destructively. The concept of an electrically tunable injection barrier as presented here is general and can be applied to other electronic devices such as light-emitting diodes with an integrated on/off switch.

  20. The combustion of coal blends in a fluidised bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Boavida, Dulce; Abelha, Pedro; Gulyurtlu, Ibrahim; Cabrita, Isabel

    1999-07-01

    Combustion studies of five coals of different origin were carried out in a laboratory scale fluidised bed combustor. Five blends prepared by mixing two coals based on their petrological characterisation, in varying amounts, were selected to study the possibility of reduction NO{sub x}, N{sub 2}O and SO{sub 2} emissions. The results showed that some blends had the opposite behaviour concerning the release of NO{sub x} and SO{sub 2} in relation to parent coals, and the emissions were higher than expected. The N{sub 2}O amounts observed were, however, in almost all blends tested, lower than predicted values. With some blends, the mixing levels intended to reduce SO{sub 2} were not always found to correspond to those for simultaneous decrease of Nox. Most of the blends studied showed some evidence of interaction between them. Varying the proportion of the blend components was observed to alter the temperatures at which interactions were stronger.

  1. Oxidative stability of diacylglycerol oil and butter blends containing diacylglycerols

    DEFF Research Database (Denmark)

    Kristensen, Janni Brogaard; Nielsen, Nina Skall; Jacobsen, Charlotte

    2006-01-01

    Diacylglycerol (DAG) oils produced from sunflower oil and traditional sunflower oil were stored for 20 wk at 38 degrees C, and their oxidative stability was measured. Moreover, two butter blends were produced containing 40 wt-% DAG oil made from sunflower oil or rapeseed oil, respectively, as well...... as two control butter blends with sunflower oil or rapeseed oil. Their oxidative stability during storage at 5 degrees C for up to 12 wk was examined by similar means as for the pure oils. The storage study of the oils indicated that the DAG oil was oxidatively less stable as compared to sunflower oil......, but that they had similar sensory quality. Storage of the butter blends revealed that blends with the two types of rapeseed oil (triacylglycerol (TAG) or DAG oil) were oxidatively more stable than the blends containing oils from sunflower. There was no unambiguous indication of DAG butter blends having a different...

  2. Olivine-Based Blended Compounds as Positive Electrodes for Lithium Batteries

    Directory of Open Access Journals (Sweden)

    Christian M. Julien

    2016-05-01

    Full Text Available Blended cathode materials made by mixing LiFePO4 (LFP with LiMnPO4 (LMP or LiNi1/3Mn1/3Co1/3O2 (NMC that exhibit either high specific energy and high rate capability were investigated. The layered blend LMP–LFP and the physically mixed blend NMC–LFP are evaluated in terms of particle morphology and electrochemical performance. Results indicate that the LMP–LFP (66:33 blend has a better discharge rate than the LiMn1−yFeyPO4 with the same composition (y = 0.33, and NMC–LFP (70:30 delivers a remarkable stable capacity over 125 cycles. Finally, in situ voltage measurement methods were applied for the evaluation of the phase evolution of blended cathodes and gradual changes in cell behavior upon cycling. We also discuss through these examples the promising development of blends as future electrodes for new generations of Li-ion batteries.

  3. Blended Learning Versus Traditional Lecture in Introductory Nursing Pathophysiology Courses.

    Science.gov (United States)

    Blissitt, Andrea Marie

    2016-04-01

    Currently, many undergraduate nursing courses use blended-learning course formats with success; however, little evidence exists that supports the use of blended formats in introductory pathophysiology courses. The purpose of this study was to compare the scores on pre- and posttests and course satisfaction between traditional and blended course formats in an introductory nursing pathophysiology course. This study used a quantitative, quasi-experimental, nonrandomized control group, pretest-posttest design. Analysis of covariance compared pre- and posttest scores, and a t test for independent samples compared students' reported course satisfaction of the traditional and blended course formats. Results indicated that the differences in posttest scores were not statistically significant between groups. Students in the traditional group reported statistically significantly higher satisfaction ratings than students in the blended group. The results of this study support the need for further research of using blended learning in introductory pathophysiology courses in undergraduate baccalaureate nursing programs. Further investigation into how satisfaction is affected by course formats is needed. Copyright 2016, SLACK Incorporated.

  4. Design of tailor-made chemical blend using a decomposition-based computer-aided approach

    DEFF Research Database (Denmark)

    Yunus, Nor Alafiza; Gernaey, Krist; Manan, Z.A.

    2011-01-01

    Computer aided techniques form an efficient approach to solve chemical product design problems such as the design of blended liquid products (chemical blending). In chemical blending, one tries to find the best candidate, which satisfies the product targets defined in terms of desired product...... methodology for blended liquid products that identifies a set of feasible chemical blends. The blend design problem is formulated as a Mixed Integer Nonlinear Programming (MINLP) model where the objective is to find the optimal blended gasoline or diesel product subject to types of chemicals...... and their compositions and a set of desired target properties of the blended product as design constraints. This blend design problem is solved using a decomposition approach, which eliminates infeasible and/or redundant candidates gradually through a hierarchy of (property) model based constraints. This decomposition...

  5. Do stellar clusters form fewer binaries? Using moderate separation binaries to distinguish between nature and nurture

    Science.gov (United States)

    Reiter, Megan

    2017-08-01

    Fewer wide-separation binaries are found in dense stellar clusters than in looser stellar associations. It is therefore unclear whether feedback in clusters prevents the formation of multiple systems or dynamical interactions destroy them. Measuring the prevalence of close, bound binary systems provide a key test to distinguish between these possibilities. Systems with separations of 10-50 AU will survive interactions in the cluster environment, and therefore are more representative of the natal population of multiple systems. By fitting a double-star PSF, we will identify visual binaries in the Orion Nebula with separations as small as 0.03. At the distance of Orion, this corresponds to a physical separation of 12 AU, effectively closing the observational gap in the binary separation distribution left between known visual and spectroscopic binaries (>65 AU or PhD thesis.

  6. Enhancing Students' Language Skills through Blended Learning

    Science.gov (United States)

    Banditvilai, Choosri

    2016-01-01

    This paper presents a case study of using blended learning to enhance students' language skills and learner autonomy in an Asian university environment. Blended learning represents an educational environment for much of the world where computers and the Internet are readily available. It combines self-study with valuable face-to-face interaction…

  7. Blended Learning in Personalized Assistive Learning Environments

    Science.gov (United States)

    Marinagi, Catherine; Skourlas, Christos

    2013-01-01

    In this paper, the special needs/requirements of disabled students and cost-benefits for applying blended learning in Personalized Educational Learning Environments (PELE) in Higher Education are studied. The authors describe how blended learning can form an attractive and helpful framework for assisting Deaf and Hard-of-Hearing (D-HH) students to…

  8. Origin of very-short orbital-period binary systems

    International Nuclear Information System (INIS)

    Miyaji, S.

    1983-01-01

    Recent observations of four close binaries have established that there is a group of very-short orbital-period (VSOP) binaries whose orbital periods are less than 60 minutes. The VSOP binaries consist of both X-ray close binaries and cataclysmic variables. Their orbital periods are too short to have a main-sequence companion. However, four binaries, none of which belongs to any globular cluster, are too abundant to be explained by the capturing mechanism of a white dwarf. Therefore it seemed to be worthwhile to present an evolutionary scenario from an original binary system which can be applied for all VSOP binaries. (Auth.)

  9. Separation in 5 Msun Binaries

    Science.gov (United States)

    Evans, Nancy R.; Bond, H. E.; Schaefer, G.; Mason, B. D.; Karovska, M.; Tingle, E.

    2013-01-01

    Cepheids (5 Msun stars) provide an excellent sample for determining the binary properties of fairly massive stars. International Ultraviolet Explorer (IUE) observations of Cepheids brighter than 8th magnitude resulted in a list of ALL companions more massive than 2.0 Msun uniformly sensitive to all separations. Hubble Space Telescope Wide Field Camera 3 (WFC3) has resolved three of these binaries (Eta Aql, S Nor, and V659 Cen). Combining these separations with orbital data in the literature, we derive an unbiased distribution of binary separations for a sample of 18 Cepheids, and also a distribution of mass ratios. The distribution of orbital periods shows that the 5 Msun binaries prefer shorter periods than 1 Msun stars, reflecting differences in star formation processes.

  10. Astronomy of binary and multiple stars

    International Nuclear Information System (INIS)

    Tokovinin, A.A.

    1984-01-01

    Various types of binary stars and methods for their observation are described in a popular form. Some models of formation and evolution of binary and multiple star systems are presented. It is concluded that formation of binary and multiple stars is a regular stage in the process of star production

  11. A ROSAT Survey of Contact Binary Stars

    Science.gov (United States)

    Geske, M. T.; Gettel, S. J.; McKay, T. A.

    2006-01-01

    Contact binary stars are common variable stars that are all believed to emit relatively large fluxes of X-rays. In this work we combine a large new sample of contact binary stars derived from the ROTSE-I telescope with X-ray data from the ROSAT All Sky Survey (RASS) to estimate the X-ray volume emissivity of contact binary stars in the Galaxy. We obtained X-ray fluxes for 140 contact binaries from the RASS, as well as two additional stars observed by the XMM-Newton observatory. From these data we confirm the emission of X-rays from all contact binary systems, with typical luminosities of approximately 1.0×1030 ergs s-1. Combining calculated luminosities with an estimated contact binary space density, we find that contact binaries do not have strong enough X-ray emission to account for a significant portion of the Galactic X-ray background.

  12. Degradable polyphosphazene/poly(alpha-hydroxyester) blends: degradation studies.

    Science.gov (United States)

    Ambrosio, Archel M A; Allcock, Harry R; Katti, Dhirendra S; Laurencin, Cato T

    2002-04-01

    Biomaterials based on the polymers of lactic acid and glycolic acid and their copolymers are used or studied extensively as implantable devices for drug delivery, tissue engineering and other biomedical applications. Although these polymers have shown good biocompatibility, concerns have been raised regarding their acidic degradation products, which have important implications for long-term implantable systems. Therefore, we have designed a novel biodegradable polyphosphazene/poly(alpha-hydroxyester) blend whose degradation products are less acidic than those of the poly(alpha-hydroxyester) alone. In this study, the degradation characteristics of a blend of poly(lactide-co-glycolide) (50:50 PLAGA) and poly[(50% ethyl glycinato)(50% p-methylphenoxy) phosphazene] (PPHOS-EG50) were qualitatively and quantitatively determined with comparisons made to the parent polymers. Circular matrices (14mm diameter) of the PLAGA, PPHOS-EG50 and PLAGA-PPHOS-EG50 blend were degraded in non-buffered solutions (pH 7.4). The degraded polymers were characterized for percentage mass loss and molecular weight and the degradation medium was characterized for acid released in non-buffered solutions. The amounts of neutralizing base necessary to bring about neutral pH were measured for each polymer or polymer blend during degradation. The poly(phosphazene)/poly(lactide-co-glycolide) blend required significantly less neutralizing base in order to bring about neutral solution pH during the degradation period studied. The results indicated that the blend degraded at a rate intermediate to that of the parent polymers and that the degradation products of the polyphosphazene neutralized the acidic degradation products of PLAGA. Thus, results from these in vitro degradation studies suggest that the PLAGA-PPHOS-EG50 blend may provide a viable improvement to biomaterials based on acid-releasing organic polymers.

  13. "Comfort" as a Critical Success Factor in Blended Learning Courses

    Science.gov (United States)

    Futch, Linda S.; deNoyelles, Aimee; Thompson, Kelvin; Howard, Wendy

    2016-01-01

    There are substantial quantitative research and anecdotal reports on blended learning and blended learning courses. However, few research studies focus on what happens at the classroom level. This research study aims to consider the highly contextual environment of effective blended learning courses by identifying the strategies instructors use to…

  14. Student acceptance of blended learning in Nigeria: a case study of ...

    African Journals Online (AJOL)

    Student acceptance of blended learning in Nigeria: a case study of Landmark University. ... instrument and the acceptance of blended learning was tested using UTAUT model. ... Keywords: Blended learning, UTAUT, technology acceptance ...

  15. Students' experiences of blended learning across a range of postgraduate programmes.

    Science.gov (United States)

    Smyth, Siobhan; Houghton, Catherine; Cooney, Adeline; Casey, Dympna

    2012-05-01

    The article describes the students' experiences of taking a blended learning postgraduate programme in a school of nursing and midwifery. The indications to date are that blended learning as a pedagogical tool has the potential to contribute and improve nursing and midwifery practice and enhance student learning. Little is reported about the students' experiences to date. Focus groups were conducted with students in the first year of introducing blended learning. The two main themes that were identified from the data were (1) the benefits of blended learning and (2) the challenges to blended learning. The blended learning experience was received positively by the students. A significant finding that was not reported in previous research was that the online component meant little time away from study for the students suggesting that it was more invasive on their everyday life. It is envisaged that the outcomes of the study will assist educators who are considering delivering programmes through blended learning. It should provide guidance for further developments and improvements in using Virtual Learning Environment (VLE) and blended learning in nurse education. Copyright © 2011 Elsevier Ltd. All rights reserved.

  16. GALAXY ROTATION AND RAPID SUPERMASSIVE BINARY COALESCENCE

    Energy Technology Data Exchange (ETDEWEB)

    Holley-Bockelmann, Kelly [Vanderbilt University, Nashville, TN (United States); Khan, Fazeel Mahmood, E-mail: k.holley@vanderbilt.edu [Institute of Space Technology (IST), Islamabad (Pakistan)

    2015-09-10

    Galaxy mergers usher the supermassive black hole (SMBH) in each galaxy to the center of the potential, where they form an SMBH binary. The binary orbit shrinks by ejecting stars via three-body scattering, but ample work has shown that in spherical galaxy models, the binary separation stalls after ejecting all the stars in its loss cone—this is the well-known final parsec problem. However, it has been shown that SMBH binaries in non-spherical galactic nuclei harden at a nearly constant rate until reaching the gravitational wave regime. Here we use a suite of direct N-body simulations to follow SMBH binary evolution in both corotating and counterrotating flattened galaxy models. For N > 500 K, we find that the evolution of the SMBH binary is convergent and is independent of the particle number. Rotation in general increases the hardening rate of SMBH binaries even more effectively than galaxy geometry alone. SMBH binary hardening rates are similar for co- and counterrotating galaxies. In the corotating case, the center of mass of the SMBH binary settles into an orbit that is in corotation resonance with the background rotating model, and the coalescence time is roughly a few 100 Myr faster than a non-rotating flattened model. We find that counterrotation drives SMBHs to coalesce on a nearly radial orbit promptly after forming a hard binary. We discuss the implications for gravitational wave astronomy, hypervelocity star production, and the effect on the structure of the host galaxy.

  17. GALAXY ROTATION AND RAPID SUPERMASSIVE BINARY COALESCENCE

    International Nuclear Information System (INIS)

    Holley-Bockelmann, Kelly; Khan, Fazeel Mahmood

    2015-01-01

    Galaxy mergers usher the supermassive black hole (SMBH) in each galaxy to the center of the potential, where they form an SMBH binary. The binary orbit shrinks by ejecting stars via three-body scattering, but ample work has shown that in spherical galaxy models, the binary separation stalls after ejecting all the stars in its loss cone—this is the well-known final parsec problem. However, it has been shown that SMBH binaries in non-spherical galactic nuclei harden at a nearly constant rate until reaching the gravitational wave regime. Here we use a suite of direct N-body simulations to follow SMBH binary evolution in both corotating and counterrotating flattened galaxy models. For N > 500 K, we find that the evolution of the SMBH binary is convergent and is independent of the particle number. Rotation in general increases the hardening rate of SMBH binaries even more effectively than galaxy geometry alone. SMBH binary hardening rates are similar for co- and counterrotating galaxies. In the corotating case, the center of mass of the SMBH binary settles into an orbit that is in corotation resonance with the background rotating model, and the coalescence time is roughly a few 100 Myr faster than a non-rotating flattened model. We find that counterrotation drives SMBHs to coalesce on a nearly radial orbit promptly after forming a hard binary. We discuss the implications for gravitational wave astronomy, hypervelocity star production, and the effect on the structure of the host galaxy

  18. Blended learning experience in teacher education: the trainees´ perspective

    Directory of Open Access Journals (Sweden)

    Monika Černá

    2009-03-01

    Full Text Available The article deals with blended learning in the context of pre-graduate English language teacher education. Firstly, the concept of blended learning is defined, then, the attention is focused on the online component of a blend, namely on the issue of interpersonal interaction including the challenges, which learning through online networking poses. Finally, results of a small–scale research are provided to offer insights into teacher trainees´ perspective of the blended learning experience at the University of Pardubice, Czech Republic.

  19. Preparation and Properties of Polyhedral Oligosilsesquioxanes/Polymers Blends

    National Research Council Canada - National Science Library

    Blanski, Rusty

    2000-01-01

    ... (polycarbonate, SB rubber, etc.) resulting in a clear blend. We also report that aliphatic POSS compounds are also dispersible in high density polyethylene. The synthesis of POSS/polymer blends as well as some physical properties will be discussed.

  20. blend4php: a PHP API for galaxy.

    Science.gov (United States)

    Wytko, Connor; Soto, Brian; Ficklin, Stephen P

    2017-01-01

    Galaxy is a popular framework for execution of complex analytical pipelines typically for large data sets, and is a commonly used for (but not limited to) genomic, genetic and related biological analysis. It provides a web front-end and integrates with high performance computing resources. Here we report the development of the blend4php library that wraps Galaxy's RESTful API into a PHP-based library. PHP-based web applications can use blend4php to automate execution, monitoring and management of a remote Galaxy server, including its users, workflows, jobs and more. The blend4php library was specifically developed for the integration of Galaxy with Tripal, the open-source toolkit for the creation of online genomic and genetic web sites. However, it was designed as an independent library for use by any application, and is freely available under version 3 of the GNU Lesser General Public License (LPGL v3.0) at https://github.com/galaxyproject/blend4phpDatabase URL: https://github.com/galaxyproject/blend4php. © The Author(s) 2017. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  1. Hidden slow pulsars in binaries

    Science.gov (United States)

    Tavani, Marco; Brookshaw, Leigh

    1993-01-01

    The recent discovery of the binary containing the slow pulsar PSR 1718-19 orbiting around a low-mass companion star adds new light on the characteristics of binary pulsars. The properties of the radio eclipses of PSR 1718-19 are the most striking observational characteristics of this system. The surface of the companion star produces a mass outflow which leaves only a small 'window' in orbital phase for the detection of PSR 1718-19 around 400 MHz. At this observing frequency, PSR 1718-19 is clearly observable only for about 1 hr out of the total 6.2 hr orbital period. The aim of this Letter is twofold: (1) to model the hydrodynamical behavior of the eclipsing material from the companion star of PSR 1718-19 and (2) to argue that a population of binary slow pulsars might have escaped detection in pulsar surveys carried out at 400 MHz. The possible existence of a population of partially or totally hidden slow pulsars in binaries will have a strong impact on current theories of binary evolution of neutron stars.

  2. Evaluation of the compatibility induced by ionizing radiation on polymeric blends

    International Nuclear Information System (INIS)

    Pino, Eddy S.; Machado, Luci D.B.; Feitosa, Marcos A.F.; Giovedi, Claudia

    2011-01-01

    To produce new polymers is a costly and time consuming task. Therefore, the utilization of existing polymers in form of blends enables to obtain new polymeric materials at a competitive cost. In this sense, polymer blending has become a growing scientific and commercial development activity. In most of the cases, polymeric blends have immiscible components and this represents an unbecoming situation on blend design. For such immiscible blends, it is required the use of compatibilizers to gain properties advantage. Compatibilization process can be achieved by chemical handling using additives and heat. On the other hand, ionizing radiation induces compatibilization by free radicals, which improve the dispersion and adhesion of the blend phases, without use of chemical additives and at room temperature. In this work, a polyamide 6.6/low-density polyethylene 75/25% wt/wt composition blend was electron beam irradiated up to 250 kGy, and thereafter mechanical tests were carried out. Tensile measurements have shown that the strength at break increases, the elongation at break decreases, the resistance to impact decreases and hardness increases when the radiation dose increases. Since this mechanical behavior is due to cross-linking and to the radiation induced blend compatibilization, this compatibility was evaluated by the approach of the glass transition temperatures for both components using DMA measurements. The results have shown that the glass transition temperatures of the blend components got closer in 8 deg C in the irradiated sample, when compared to the glass transition temperature values obtained for non-irradiated blend. (author)

  3. Evaluation of the compatibility induced by ionizing radiation on polymeric blends

    Energy Technology Data Exchange (ETDEWEB)

    Pino, Eddy S.; Machado, Luci D.B., E-mail: lmachado@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Feitosa, Marcos A.F. [Centro Paula Souza, Faculdade de Tecnologia da Zona Leste, Sao Paulo, SP (Brazil); Giovedi, Claudia, E-mail: claudia.giovedi@ctmsp.mar.mil.b [Centro Tecnologico da Marinha em Sao Paulo (CTMSP), Sao Paulo, SP (Brazil). Dept. de Tecnologia de Reatores Nucleares

    2011-07-01

    To produce new polymers is a costly and time consuming task. Therefore, the utilization of existing polymers in form of blends enables to obtain new polymeric materials at a competitive cost. In this sense, polymer blending has become a growing scientific and commercial development activity. In most of the cases, polymeric blends have immiscible components and this represents an unbecoming situation on blend design. For such immiscible blends, it is required the use of compatibilizers to gain properties advantage. Compatibilization process can be achieved by chemical handling using additives and heat. On the other hand, ionizing radiation induces compatibilization by free radicals, which improve the dispersion and adhesion of the blend phases, without use of chemical additives and at room temperature. In this work, a polyamide 6.6/low-density polyethylene 75/25% wt/wt composition blend was electron beam irradiated up to 250 kGy, and thereafter mechanical tests were carried out. Tensile measurements have shown that the strength at break increases, the elongation at break decreases, the resistance to impact decreases and hardness increases when the radiation dose increases. Since this mechanical behavior is due to cross-linking and to the radiation induced blend compatibilization, this compatibility was evaluated by the approach of the glass transition temperatures for both components using DMA measurements. The results have shown that the glass transition temperatures of the blend components got closer in 8 deg C in the irradiated sample, when compared to the glass transition temperature values obtained for non-irradiated blend. (author)

  4. Morphology, thermal and mechanical properties of PVC/MMT nanocomposites prepared by solution blending and solution blending + melt compounding

    DEFF Research Database (Denmark)

    Madaleno, Liliana Andreia Oliveira; Schjødt-Thomsen, Jan; Pinto, José Cruz

    2010-01-01

    Two types of montmorillonite (MMT), natural sodium montmorillonite (Na-MMT) and organically modified montmorillonite (OMMT), in different amounts of 1, 2, 5, 10 and 25 phr (parts per hundred resin), were dispersed in rigid poly (vinyl chloride) by two different methods solution blending...... and solution blending + melt compounding The effects on morphology, thermal and mechanical properties of the PVC/MMT nanocomposites were studied by varying the amount of Na-MMT and OMMT in both methods SEM and XRD analysis revealed that possible intercalated and exfoliated structures were obtained in all...... prepared by solution blending + melt compounding method Experimental values for 1 and 2 phr are larger than the calculated values which directly suggest that the MMT particles are exfoliated (C) 2010 Elsevier Ltd All rights reserved...

  5. Blended Learning in International Nuclear Education

    Energy Technology Data Exchange (ETDEWEB)

    James, Z. [KEPCO International Nuclear Graduate School, Ulsan (Korea, Republic of)

    2012-03-15

    The spread of nuclear power ambitions beyond the few early-adopter nations requires more globalized education. Two of the learning problems specific to international education are the need for a common instructional language and different cultural styles of learning. Blended learning, a mix of personal interaction between teacher and impersonal computer-based learning, can solve these problems. The new KEPCO International Nuclear Graduate School outside Ulsan, Korea is investing heavily in blended learning.

  6. Blended Learning in International Nuclear Education

    International Nuclear Information System (INIS)

    James, Z.

    2012-01-01

    The spread of nuclear power ambitions beyond the few early-adopter nations requires more globalized education. Two of the learning problems specific to international education are the need for a common instructional language and different cultural styles of learning. Blended learning, a mix of personal interaction between teacher and impersonal computer-based learning, can solve these problems. The new KEPCO International Nuclear Graduate School outside Ulsan, Korea is investing heavily in blended learning

  7. Blended Refuge and Insect Resistance Management for Insecticidal Corn

    Science.gov (United States)

    Crespo, Andre L B; Pan, Zaiqi; Crain, Philip R; Thompson, Stephen D; Pilcher, Clinton D; Sethi, Amit

    2018-01-01

    Abstract In this review, we evaluate the intentional mixing or blending of insecticidal seed with refuge seed for managing resistance by insects to insecticidal corn (Zea mays). We first describe the pest biology and farming practices that will contribute to weighing trade-offs between using block refuges and blended refuges. Case studies are presented to demonstrate how the trade-offs will differ in different systems. We compare biological aspects of several abstract models to guide the reader through the history of modeling, which has played a key role in the promotion or denigration of blending in various scientific debates about insect resistance management for insecticidal crops. We conclude that the use of blended refuge should be considered on a case-by-case basis after evaluation of insect biology, environment, and farmer behavior. For Diabrotica virgifera virgifera, Ostrinia nubilalis, and Helicoverpa zea in the United States, blended refuge provides similar, if not longer, delays in the evolution of resistance compared to separate block refuges. PMID:29220481

  8. Evaluation of ternary blended cements for use in transportation concrete structures

    Science.gov (United States)

    Gilliland, Amanda Louise

    This thesis investigates the use of ternary blended cement concrete mixtures for transportation structures. The study documents technical properties of three concrete mixtures used in federally funded transportation projects in Utah, Kansas, and Michigan that used ternary blended cement concrete mixtures. Data were also collected from laboratory trial batches of ternary blended cement concrete mixtures with mixture designs similar to those of the field projects. The study presents the technical, economic, and environmental advantages of ternary blended cement mixtures. Different barriers of implementation for using ternary blended cement concrete mixtures in transportation projects are addressed. It was concluded that there are no technical, economic, or environmental barriers that exist when using most ternary blended cement concrete mixtures. The technical performance of the ternary blended concrete mixtures that were studied was always better than ordinary portland cement concrete mixtures. The ternary blended cements showed increased durability against chloride ion penetration, alkali silica reaction, and reaction to sulfates. These blends also had less linear shrinkage than ordinary portland cement concrete and met all strength requirements. The increased durability would likely reduce life cycle costs associated with concrete pavement and concrete bridge decks. The initial cost of ternary mixtures can be higher or lower than ordinary portland cement, depending on the supplementary cementitious materials used. Ternary blended cement concrete mixtures produce less carbon dioxide emissions than ordinary portland cement mixtures. This reduces the carbon footprint of construction projects. The barriers associated with implementing ternary blended cement concrete for transportation projects are not significant. Supplying fly ash returns any investment costs for the ready mix plant, including silos and other associated equipment. State specifications can make

  9. Perceptual biases for rhythm: The Mismatch Negativity latency indexes the privileged status of binary vs non-binary interval ratios.

    Science.gov (United States)

    Pablos Martin, X; Deltenre, P; Hoonhorst, I; Markessis, E; Rossion, B; Colin, C

    2007-12-01

    Rhythm perception appears to be non-linear as human subjects are better at discriminating, categorizing and reproducing rhythms containing binary vs non-binary (e.a. 1:2 vs 1:3) as well as metrical vs non-metrical (e.a. 1:2 vs 1:2.5) interval ratios. This study examined the representation of binary and non-binary interval ratios within the sensory memory, thus yielding a truly sensory, pre-motor, attention-independent neural representation of rhythmical intervals. Five interval ratios, one binary, flanked by four non-binary ones, were compared on the basis of the MMN they evoked when contrasted against a common standard interval. For all five intervals, the larger the contrast was, the larger the MMN amplitude was. The binary interval evoked a significantly much shorter (by at least 23 ms) MMN latency than the other intervals, whereas no latency difference was observed between the four non-binary intervals. These results show that the privileged perceptual status of binary rhythmical intervals is already present in the sensory representations found in echoic memory at an early, automatic, pre-perceptual and pre-motor level. MMN latency can be used to study rhythm perception at a truly sensory level, without any contribution from the motor system.

  10. Blended Learning and Student Engagement in an Urban High School

    Science.gov (United States)

    Johnson, Courtney

    2017-01-01

    A metropolitan school district wanted to understand blended learning as it existed in one of their high schools. Blended learning had been school-wide for four years, and district administrators wanted to know how students, teachers, and school administrators perceived blended learning and its impact on student engagement. This was a…

  11. Inkjet-Printed Organic Transistors Based on Organic Semiconductor/Insulating Polymer Blends

    Science.gov (United States)

    Kwon, Yoon-Jung; Park, Yeong Don; Lee, Wi Hyoung

    2016-01-01

    Recent advances in inkjet-printed organic field-effect transistors (OFETs) based on organic semiconductor/insulating polymer blends are reviewed in this article. Organic semiconductor/insulating polymer blends are attractive ink candidates for enhancing the jetting properties, inducing uniform film morphologies, and/or controlling crystallization behaviors of organic semiconductors. Representative studies using soluble acene/insulating polymer blends as an inkjet-printed active layer in OFETs are introduced with special attention paid to the phase separation characteristics of such blended films. In addition, inkjet-printed semiconducting/insulating polymer blends for fabricating high performance printed OFETs are reviewed. PMID:28773772

  12. Comparison of Model Reliabilities from Single-Step and Bivariate Blending Methods

    DEFF Research Database (Denmark)

    Taskinen, Matti; Mäntysaari, Esa; Lidauer, Martin

    2013-01-01

    Model based reliabilities in genetic evaluation are compared between three methods: animal model BLUP, single-step BLUP, and bivariate blending after genomic BLUP. The original bivariate blending is revised in this work to better account animal models. The study data is extracted from...... be calculated. Model reliabilities by the single-step and the bivariate blending methods were higher than by animal model due to genomic information. Compared to the single-step method, the bivariate blending method reliability estimates were, in general, lower. Computationally bivariate blending method was......, on the other hand, lighter than the single-step method....

  13. SECULAR EVOLUTION OF BINARIES NEAR MASSIVE BLACK HOLES: FORMATION OF COMPACT BINARIES, MERGER/COLLISION PRODUCTS AND G2-LIKE OBJECTS

    International Nuclear Information System (INIS)

    Prodan, Snezana; Antonini, Fabio; Perets, Hagai B.

    2015-01-01

    Here we discuss the evolution of binaries around massive black holes (MBHs) in nuclear stellar clusters. We focus on their secular evolution due to the perturbation by the MBHs, while simplistically accounting for their collisional evolution. Binaries with highly inclined orbits with respect to their orbits around MBHs are strongly affected by secular processes, which periodically change their eccentricities and inclinations (e.g., Kozai-Lidov cycles). During periapsis approach, dissipative processes such as tidal friction may become highly efficient, and may lead to shrinkage of a binary orbit and even to its merger. Binaries in this environment can therefore significantly change their orbital evolution due to the MBH third-body perturbative effects. Such orbital evolution may impinge on their later stellar evolution. Here we follow the secular dynamics of such binaries and its coupling to tidal evolution, as well as the stellar evolution of such binaries on longer timescales. We find that stellar binaries in the central parts of nuclear stellar clusters (NSCs) are highly likely to evolve into eccentric and/or short-period binaries, and become strongly interacting binaries either on the main sequence (at which point they may even merge), or through their later binary stellar evolution. The central parts of NSCs therefore catalyze the formation and evolution of strongly interacting binaries, and lead to the enhanced formation of blue stragglers, X-ray binaries, gravitational wave sources, and possible supernova progenitors. Induced mergers/collisions may also lead to the formation of G2-like cloud-like objects such as the one recently observed in the Galactic center

  14. Determination of the density and the viscosities of biodiesel-diesel fuel blends

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Ertan; Canakci, Mustafa [Department of Mechanical Education, Kocaeli University, 41380 Kocaeli (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Kocaeli (Turkey)

    2008-12-15

    In this study, commercially available two different diesel fuels were blended with the biodiesels produced from six different vegetable oils (sunflower, canola, soybean, cottonseed, corn oils and waste palm oil). The blends (B2, B5, B10, B20, B50 and B75) were prepared on a volume basis. The key fuel properties such as density and viscosities of the blends were measured by following ASTM test methods. Generalized equations for predicting the density and viscosities for the blends were given and a mixing equation, originally proposed by Arrhenius and described by Grunberg and Nissan, was used to predict the viscosities of the blends. For all blends, it was found that there is an excellent agreement between the measured and estimated values of the density and viscosities. According to the results, the density and viscosities of the blends increased with the increase of biodiesel concentration in the fuel blend. (author)

  15. Blended Identities: Identity Work, Equity and Marginalization in Blended Learning

    Science.gov (United States)

    Heikoop, Will

    2013-01-01

    This article is a theoretical study of the self-presentation strategies employed by higher education students online; it examines student identity work via profile information and avatars in a blended learning environment delivered through social networking sites and virtual worlds. It argues that students are faced with difficult choices when…

  16. Galactic binaries with eLISA

    OpenAIRE

    Nelemans, G.

    2013-01-01

    I review what eLISA will see from Galactic binaries -- double stars with orbital periods less than a few hours and white dwarf (or neutron star/black hole) components. I discuss the currently known binaries that are guaranteed (or verification) sources and explain why the expected total number of eLISA Galactic binaries is several thousand, even though there are large uncertainties in our knowledge of this population, in particular that of the interacting AM CVn systems. I very briefly sketch...

  17. Evaluation of relative radiometric correction techniques on Landsat 8 OLI sensor data

    Science.gov (United States)

    Novelli, Antonio; Caradonna, Grazia; Tarantino, Eufemia

    2016-08-01

    The quality of information derived from processed remotely sensed data may depend upon many factors, mostly related to the extent data acquisition is influenced by atmospheric conditions, topographic effects, sun angle and so on. The goal of radiometric corrections is to reduce such effects in order enhance the performance of change detection analysis. There are two approaches to radiometric correction: absolute and relative calibrations. Due to the large amount of free data products available, absolute radiometric calibration techniques may be time consuming and financially expensive because of the necessary inputs for absolute calibration models (often these data are not available and can be difficult to obtain). The relative approach to radiometric correction, known as relative radiometric normalization, is preferred with some research topics because no in situ ancillary data, at the time of satellite overpasses, are required. In this study we evaluated three well known relative radiometric correction techniques using two Landsat 8 - OLI scenes over a subset area of the Apulia Region (southern Italy): the IR-MAD (Iteratively Reweighted Multivariate Alteration Detection), the HM (Histogram Matching) and the DOS (Dark Object Subtraction). IR-MAD results were statistically assessed within a territory with an extremely heterogeneous landscape and all computations performed in a Matlab environment. The panchromatic and thermal bands were excluded from the comparisons.

  18. The origin of the RS CVn binaries

    International Nuclear Information System (INIS)

    Biermann, P.

    1976-01-01

    Six possible origins for the RS CVn binaries are considered based on the following possibilities. RS CVn binaries might now be either pre-main-sequence or post-main-sequence. A pre-main-sequence binary might not always have been a binary but might have resulted from fission of a rapidly rotating single pre-main-sequence star. The main-sequence counterparts might be either single stars or binaries. To decide which of the six origins is possible, the following observed data for the RS CVn binaries are considered: total mass, total angular momentum, lack of observed connection with regions of star formation, large space density, kinematical age, and the visual companion of WW Dra. In addition lifetimes and space densities of single stars and other types of binaries are considered. The only origin possible is that the RS CVn binaries are in a thermal phase following fission of a main-sequence single star. In this explanation the single star had a rapidly rotating core which became unstable due to the core contraction which made it begin to evolve off the main sequence. The present Be stars might be examples of such parent single stars. (Auth.)

  19. Change Spectroscopic, thermal and mechanical studies of PU/PVC blends

    Energy Technology Data Exchange (ETDEWEB)

    Hezma, A.M. [Spectroscopy Department, Physics Division, National Research Center, Giza (Egypt); Elashmawi, I.S. [Spectroscopy Department, Physics Division, National Research Center, Giza (Egypt); Physic Department, Faculty of Science, Taibah University, Al-Ula (Saudi Arabia); Rajeh, A., E-mail: a.rajeh88@yahoo.com [Physic Department, Faculty of Science, Amran University, Sa' dah (Yemen); Physics Department, Faculty of science, Mansoura University, Mansoura (Egypt); Kamal, Mustafa [Physics Department, Faculty of science, Mansoura University, Mansoura (Egypt)

    2016-08-15

    Blends of polyurethane (PU) and polyvinyl chloride (PVC) with different concentrations were prepared by casting method. The effects of PU on PVC blends was examined by Fourier transform-infrared (FTIR), Ultra-violet visible studies (UV/VIS.), X-ray diffraction (XRD), Thermogravimetric (TGA), Differential scanning calorimetry (DSC), and mechanical properties (stress–strain curve). The interaction between PU and PVC was examined by FT-IR through the absorbance of the N–H groups and was correlated to mechanical/thermal properties. Ultra-violet visible said that optical energy gap decrease with increasing concentration of PU. Differential scanning calorimetry results was observed a single glass transition temperature (T{sub g}) for blends this confirming existence miscibility within the blends. The causes for best thermal stability of some blends may be described by measurements of interactions between C=O groups of PU and the α-hydrogen of PVC or a dipole–dipole –C=O..Cl–C– interactions. Significant alterations in FTIR, X-ray and DSC examination shows an interactions between blends had good miscibility. X-ray shows some alterations in the intensity with additional PU. PU change the mechanical behavior of PVC through of the blends. When polyurethane content increase causes polyvinyl chloride tensile strength decreases and elongation at break increase.

  20. Blended Learning Educational Format for Third-Year Pediatrics Clinical Rotation.

    Science.gov (United States)

    Langenau, Erik E; Lee, Robert; Fults, Marci

    2017-04-01

    Traditional medical education is shifting to incorporate learning technologies and online educational activities with traditional face-to-face clinical instruction to engage students, especially at remote clinical training sites. To describe and evaluate the effectiveness of the blended learning format (combining online and face-to-face instruction) for third-year osteopathic medical students during their pediatric rotation. Third-year medical students who completed the 4-week clerkship in pediatrics during the 2014-2015 academic year were divided into a standard learning group and a blended learning group with online activities (discussion boards, blogs, virtual patient encounters, narrated video presentations, and online training modules). Comprehensive Osteopathic Medical Achievement Test scores and final course grades were compared between the standard learning and blended learning groups. Students in the blended learning group completed a postsurvey regarding their experiences. Of 264 third-year students who completed the 4-week clerkship in pediatrics during the 2014-2015 academic year, 78 (29.5%) participated in the blended learning supplement with online activities. Of 53 students who completed the postsurvey in the blended learning group, 44 (83.0%) agreed or strongly agreed that "The integration of e-learning and face-to-face learning helped me learn pediatrics." Open-ended comments supported this overall satisfaction with the course format; however, 26 of 100 comments reflected a desire to increase the amount of clinical exposure and face-to-face time with patients. No statistical differences were seen between the standard learning (n=186) and blended learning (n=78) groups with regard to Comprehensive Osteopathic Medical Achievement Test scores (P=.321). Compared with the standard learning group, more students in the blended learning group received a final course grade of honors (P=.015). Results of this study support the use of blended learning in a

  1. Extrudability and Consolidation of Blends between CGM and DDGS

    Directory of Open Access Journals (Sweden)

    C. J. R. Verbeek

    2016-01-01

    Full Text Available During the last decade, the global biofuels industry has experienced exponential growth. By-products such as high protein corn gluten meal (CGM and high fibre distillers dried grains with solubles (DDGS have grown in parallel. CGM has been shown to be suitable as a biopolymer; the high fibre content of DDGS reduces its effectiveness, although it is considerably cheaper. In this study, the processing behaviour of CGM and DDGS blends was evaluated and resulting extrudate properties were determined. Prior to processing, urea was used as a denaturant. DDGS : CGM ratios of 0, 33, 50, 66, and 100% were processed in a single screw extruder, which solely used dissipative heating. Blends containing DDGS were less uniformly consolidated and resulted in more dissipative heating. Blends showed multiple glass transitions, which is characteristic of mechanically compatible blends. Transmission electron microscopy revealed phase separation on a microscale, although distinct CGM or DDGS phases could not be identified. On a macroscale, optical microscopy suggested that CGM-rich blends were better consolidated, supported by visual observations of a more continuous extrudate formed during extrusion. Future work should aim to also characterize the mechanical properties of these blends to assess their suitability as either bioplastic feedstock or pelletized livestock feed.

  2. A Phenomenology of ‘Blending in’: Beyond Emotional Regulation

    Directory of Open Access Journals (Sweden)

    Katie Creighton

    2018-02-01

    Full Text Available The phenomenon of devaluing of self for adolescent girls has been highlighted in previous qualitative research in a US cultural context. Carol Gilligan and her colleagues have documented a loss of connection to self and loss of voice. ‘Blending in’ pertains to such a loss of connection and voice. ‘Blending in’ emerges from many aspects of 8 Irish females’ retrospective qualitative phenomenological accounts of their adolescent experiences. These features of blending in include: a dumbing down of intellectual ability in order to fit in, a desire to be hidden in the group to ‘fade into the background’, to not stand out as being different, fear of being labelled by others and fear of challenging others. Blending in gives phenomenological support to Gilligan’s (1990 accounts of silencing and loss of relation to self in adolescent girls, to a rendering of self as other. This phenomenological exploration is resonant also with de Beauvoir’s Second Sex and to a loss of capacity for introversion in Western culture, echoing Jung (1921. Blending in requires firmer addressing in social and emotional education (SEE, especially regarding challenge to self-management as emotional impulse and behaviour regulation. Self-management as blending in risks being a process of loss of voice and alienation of self.

  3. Durability of Gamma Irradiated Polymer Impregnated Blended Cement Pastes

    International Nuclear Information System (INIS)

    Khattab, M.M.; Abdel-Rahman, H.A.; Younes, M.M.

    2010-01-01

    This study is focusing on durability and performance of the neat blended cement paste as well as those of the polymer-impregnated paste towards seawater and various concentrations of magnesium sulfate solutions up to 6 months of curing. The neat blended cement paste is prepared by a partial substitution of ordinary Portland cement with 5% of active rice husk ash (RHA). These samples were cured under tap water for 7 days. Similar samples were impregnated with unsaturated polyester resin (UPE) and subjected to various doses of gamma rays ranging from 10 to 50 kGy. The results showed that the irradiated impregnated specimens gave higher values of compressive strength than the neat blended cement paste specimens. On immersing the neat blended cement specimens and polymer impregnated specimens especially that irradiated at 30 kGy in seawater and different concentrations of magnesium sulfate solutions up to 6 months of curing, the results showed that the polymer impregnated blended cement (OPC-RHA-UPE) paste have a good resistance towards aggressive media as compared to the neat blended cement (OPC-RHA) paste. The results also indicated that the sea water has a greater corrosive effect than the magnesium sulfate solutions. These results were confirmed by scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP)

  4. Evolution of dwarf binaries

    International Nuclear Information System (INIS)

    Tutukov, A.V.; Fedorova, A.V.; Yungel'son, L.R.

    1982-01-01

    The conditions of mass exchange in close binary systems with masses of components less or equal to one solar mass have been analysed for the case, when the system radiates gravitational waves. It has been shown that the mass exchange rate depends in a certain way on the mass ratio of components and on the mass of component that fills its inner critical lobe. The comparison of observed periods, masses of contact components, and mass exchange rates of observed cataclysmic binaries have led to the conclusion that the evolution of close binaries WZ Sge, OY Car, Z Cha, TT Ari, 2A 0311-227, and G 61-29 may be driven by the emission of gravitational waves [ru

  5. Preparation and Characterization of HPMC/PVP Blend Films Plasticized with Sorbitol

    OpenAIRE

    Somashekarappa, H.; Prakash, Y.; Hemalatha, K.; Demappa, T.; Somashekar, R.

    2013-01-01

    The aim of this present work is to investigate the effect of plasticizers like Sorbitol on microstructural and mechanical properties of hydroxypropyl methylcellulose (HPMC) and Polyvinylpyrrolidone (PVP) blend films. The pure blend and plasticized blend films were prepared by solution casting method and investigated using wide angle X-ray scattering (WAXS) method. WAXS analysis confirms that the plasticizers can enter into macromolecular blend structure and destroy the crystallinity of the f...

  6. HEU to LEU Conversion and Blending Facility: UF6 blending alternative to produce LEU UF6 for commercial use

    International Nuclear Information System (INIS)

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials; the nuclear material will be converted to a form more proliferation- resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. Five technologies for blending HEU will be assessed; blending as UF 6 to produce a UF 6 product for commercial use is one of them. This document provides data to be used in the environmental impact analysis for the UF 6 blending HEU disposition option. Resource needs, employment needs, waste and emissions from plant, hazards, accident scenarios, and intersite transportation are discussed

  7. Controlled release of tocopherols from polymer blend films

    Science.gov (United States)

    Obinata, Noe

    Controlled release packaging has great potential to increase storage stability of foods by releasing active compounds into foods continuously over time. However, a major limitation in development of this technology is the inability to control the release and provide rates useful for long term storage of foods. Better understanding of the factors affecting active compound release is needed to overcome this limitation. The objective of this research was to investigate the relationship between polymer composition, polymer processing method, polymer morphology, and release properties of active compounds, and to provide proof of principle that compound release is controlled by film morphology. A natural antioxidant, tocopherol was used as a model active compound because it is natural, effective, heat stable, and soluble in most packaging polymers. Polymer blend films were produced from combination of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE), polypropylene (PP), or polystyrene (PS) with 3000 ppm mixed tocopherols using conventional blending method and innovative blending method, smart blending with a novel mixer using chaotic advection. Film morphologies were visualized with scanning electron microscopy (SEM). Release of tocopherols into 95% ethanol as a food simulant was measured by UV/Visible spectrophotometry or HPLC, and diffusivity of tocopherols in the polymers was estimated from this data. Polymer composition (blend proportions) and processing methods have major effects on film morphology. Four different types of morphologies, dispersed, co-continuous, fiber, and multilayer structures were developed by either conventional extrusion or smart blending. With smart blending of fixed polymer compositions, different morphologies were progressively developed with fixed polymer composition as the number of rod rotations increased, providing a way to separate effects of polymer composition and morphology. The different morphologies

  8. Low-Temperature Miscibility of Ethanol-Gasoline-Water Blends in Flex Fuel Applications

    DEFF Research Database (Denmark)

    Johansen, T.; Schramm, Jesper

    2009-01-01

    The miscibility of blends of gasoline and hydrous ethanol was investigated experimentally at - 25 degrees C and - 2 degrees C. Furthermore, the maximum water content was found for ethanol in flex fuel blends. The results strongly indicate that blends containing ethanol with a water content above...... that of the ethanol/water azeotrope (4.4% water by mass) can be used as Flex Fuel blends together with gasoline at ambient temperatures of 25 degrees C and 2 degrees C, without phase separation occurring. Additionally, it was shown that the ethanol purity requirement of ethanol-rich flex fuel blends falls...... with increasing ethanol content in the gasoline-rich flex fuel blend....

  9. Massive binaries in the vicinity of Sgr A*

    Energy Technology Data Exchange (ETDEWEB)

    Pfuhl, O.; Gillessen, S.; Genzel, R.; Eisenhauer, F.; Fritz, T. K.; Ott, T. [Max-Planck-Institut für Extraterrestrische Physik, D-85748 Garching (Germany); Alexander, T. [Faculty of Physics, Weizmann Institute of Science, P.O. Box 26, Rehovot 76100 (Israel); Martins, F., E-mail: pfuhl@mpe.mpg.de [LUPM, Université Montpelier 2, CNRS, Place Eugéne Bataillon, F-34095, Montpellier (France)

    2014-02-20

    A long-term spectroscopic and photometric survey of the most luminous and massive stars in the vicinity of the supermassive black hole Sgr A* revealed two new binaries: a long-period Ofpe/WN9 binary, IRS 16NE, with a modest eccentricity of 0.3 and a period of 224 days, and an eclipsing Wolf-Rayet binary with a period of 2.3 days. Together with the already identified binary IRS 16SW, there are now three confirmed OB/WR binaries in the inner 0.2 pc of the Galactic center. Using radial velocity change upper limits, we were able to constrain the spectroscopic binary fraction in the Galactic center to F{sub SB}=0.30{sub −0.21}{sup +0.34} at a confidence level of 95%, a massive binary fraction close to that observed in dense clusters. The fraction of eclipsing binaries with photometric amplitudes Δm > 0.4 is F{sub EB}{sup GC}=3%±2%, which is consistent with local OB star clusters (F {sub EB} = 1%). Overall, the Galactic center binary fraction seems to be similar to the binary fraction in comparable young clusters.

  10. Experimental investigation on Performance and Emission Characteristics of J20, P20, N20 Biodiesel blends and Sound Characteristics of P20 Biodiesel blend Used in Single Cylinder Diesel Engine

    Science.gov (United States)

    rajasekar, R.; karthik, N.; Xavier, Goldwin

    2017-05-01

    Present work provides the effect of biodiesel blends and Sound Characteristics of P20 Biodiesel blend compared with Performance and emission Characteristics of diesel. Methods and analysis biodiesel blends was prepared by the Transesterification Process. Experiments were conducted in single cylinder constant speed direct injection diesel engine for various test fuels. Research is mainly focused on pongamia oil. It was observed that a 20% Pongamia oil blends and its properties were similar to diesel. The results showed that 20% Pongamia oil blends gave better performance, less in noise and emission compared with ester of Jatropha and neem oil blends. Hence Pongamia blends can be used in existing diesel engine without compromising the engine performance.

  11. EVOLUTION OF THE BINARY FRACTION IN DENSE STELLAR SYSTEMS

    International Nuclear Information System (INIS)

    Fregeau, John M.; Ivanova, Natalia; Rasio, Frederic A.

    2009-01-01

    Using our recently improved Monte Carlo evolution code, we study the evolution of the binary fraction in globular clusters. In agreement with previous N-body simulations, we find generally that the hard binary fraction in the core tends to increase with time over a range of initial cluster central densities for initial binary fractions ∼<90%. The dominant processes driving the evolution of the core binary fraction are mass segregation of binaries into the cluster core and preferential destruction of binaries there. On a global scale, these effects and the preferential tidal stripping of single stars tend to roughly balance, leading to overall cluster binary fractions that are roughly constant with time. Our findings suggest that the current hard binary fraction near the half-mass radius is a good indicator of the hard primordial binary fraction. However, the relationship between the true binary fraction and the fraction of main-sequence stars in binaries (which is typically what observers measure) is nonlinear and rather complicated. We also consider the importance of soft binaries, which not only modify the evolution of the binary fraction, but can also drastically change the evolution of the cluster as a whole. Finally, we briefly describe the recent addition of single and binary stellar evolution to our cluster evolution code.

  12. Reactive modification of polyesters and their blends

    Science.gov (United States)

    Wan, Chen

    2004-12-01

    As part of a broader research effort to investigate the chemical modification of polyesters by reactive processing a low molecular weight (MW) unsaturated polyester (UP) and a higher MW saturated polyester, polyethylene terephthalate (PET), alone or blended with polypropylene (PP) were melt processed in a batch mixer and continuous twin screw extruders. Modification was monitored by on-line rheology and the products were characterized primarily by off-line rheology, morphology and thermal analysis. Efforts were made to establish processing/property relationships and provide an insight of the accompanying structural changes. The overall response of the reactively modified systems was found to be strongly dependent on the component characteristics, blend composition, type and concentrations of reactive additives and processing conditions. The work concluded that UP can be effectively modified through reactive melt processing. Its melt viscosity and MW can be increased through chemical reactions between organic peroxides (POX) and chain unsaturation or between MgO and carboxyl/hydroxyl end groups. Reactive blending of PP/UP blends through peroxide modification gave finer and more uniform morphology than unreacted blends and at a given PP/UP weight ratio more thermoplastic elastomers-like rheological behavior. This is due to the continuously decreasing viscosity ratio of PP/UP towards unity by the competing reactions between POX and the blend components and formation of PP-UP copolymers which serve as in-situ compatibilizers to promote better interfacial adhesion. Kinetics of the competing reactions were analyzed through a developed model. In addition to POX concentration and mixing efficiency, rheology and morphology of UP/PP bends were significantly affected by the addition of inorganic and organic coagents. Addition of coagents such as a difunctional maleimide, MgO and/or an anhydride functionalized PP during reactive blending offers effective means for tailoring

  13. Blend for visual studio 2012 by example beginner's guide

    CERN Document Server

    Shukla, Abhishek

    2015-01-01

    This book is aimed at developers and designers who are new to Blend and looking to learn Blend, not just practically, but also conceptually. This book does not assume any knowledge about Blend on the part of developers; however, some experience in design or development might be useful in understanding the concepts faster, but this book explains everything very simply so that you are able to understand everything with little or no effort.

  14. Activity coefficients of solutes in binary solvents

    International Nuclear Information System (INIS)

    Gokcen, N.A.

    1982-01-01

    The activity coefficients in dilute ternary systems are discussed in detail by using the Margules equations. Analyses of some relevant data at high temperatures show that the sparingly dissolved solutes in binary solvents follow complex behavior even when the binary solvents are very nearly ideal. It is shown that the activity data on the solute or the binary system cannot permit computation of the remaining activities except for the regular solutions. It is also shown that a fourth-order equation is usually adequate in expressing the activity coefficient of a solute in binary solvents at high temperatures. When the activity data for a binary solvent are difficult to obtain in a certain range of composition, the activity data for a sparingly dissolved solute can be used to supplement determination of the binary activities

  15. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  16. Poly(3-hexylthiophene): TIPS-pentacene blends aiming transistor applications

    Energy Technology Data Exchange (ETDEWEB)

    Silva Ozório, Maiza da, E-mail: ozoriounesp@gmail.com; Nogueira, Gabriel Leonardo; Morais, Rogério Miranda; Silva Martin, Cibely da; Constantino, Carlos José Leopoldo; Alves, Neri

    2016-06-01

    Poly(3-hexylthiophene):6,13-bis(triisopropylsilylethynyl)-pentacene (P3HT:TP) blends with a ratio of 1:1 (wt/wt) were deposited via spin coating on anodized oxide (Al{sub 2}O{sub 3}). A phase separation of the compounds was observed, resulting in the formation of crystalline aggregates of TP molecules that segregate vertically on the surface. The form of segregation depends on the oxide surface treatment used. Spectroscopy analysis shows a higher molecular order of P3HT in the blend than for neat film and that TP molecules are also distributed in the polymeric matrix. Regarding the OFET characteristics, charge carrier mobilities of 1.2 × 10{sup −3} cm{sup 2} V{sup −1} s{sup −1} and 2.0 × 10{sup −3} cm{sup 2} V{sup −1} s{sup −1} were obtained from devices for untreated and (hexamethyldisilazane) HMDS-treated Al{sub 2}O{sub 3} gate dielectric, respectively. These results confirm that P3HT:TP blends have good potential as an active layer in organic field effect transistors (OFETs). - Highlights: • Phase separation occurs in the P3HT:TP blend. • The P3HT:TP blends form aggregates that segregate vertically to the surface. • The molecular order of the P3HT is higher for the blend than for the neat film. • Treatment of surface with HMDS influence in the formation of the aggregate • The P3HT:TP blends have great viability of using for application in transistors.

  17. Influence of compatibilizer on blends degradation during processing

    Directory of Open Access Journals (Sweden)

    Walter R. Waldman

    2013-01-01

    Full Text Available The thermomechanical degradation of blends made from polypropylene and polystyrene, with or without compatibilizer, was studied using an internal mixer coupled to a torque rheometer. The blends processed without compatibilizer presented regular and expected results regarding torque reduction, with evidence of chain scission. The blends processed with the block copolymer of styrene and butadiene, SBS, as a compatibilizer presented unchanged or less reduced variation on torque values during processing. The extraction of stabilizers from the compatibilizer before processing did not affect the results. The compatibilizer concentration in the blends was varied, with its influence still being observed in concentrations as low as 0.03 parts per hundred. Similar results were obtained in an experiment comparing the performance of a primary commercial anti-oxidant, Irganox 1076, and the compatibilizer SBS. Therefore, the compatibilizer can be considered as a processing aid agent with positive influence on avoiding thermomechanical degradation.

  18. Characterization of coal blends for effective utilization in thermal power plants

    International Nuclear Information System (INIS)

    Santhosh Raaj, S.; Arumugam, S.; Muthukrishnan, M.; Krishnamoorthy, S.; Anantharaman, N.

    2016-01-01

    Highlights: • This work will assist utilities to decide on the choice of coals for blending. • Conventional and advanced analytical techniques were used for characterization. • Fuel ratio, burnout profile, ash chemistry and carbon burnout are key factors. • Basic properties were additive while carbon burnout was non additive for the blends. - Abstract: This paper deals with the characterization of coal blends using various conventional and advanced analytical techniques. There has been an increasing trend in utilizing imported coals for power generation in India and utilities are resorting to blended coal firing for various reasons, both financially as well as technically. Characterization studies were carried out on 2 combinations of Indian and imported coal blends. Conventional characterization such as proximate and ultimate analysis and determination of calorific value were carried out for the raw coals and blends as per ASTM standards. Following this thermal and mineral analysis of the samples were carried out using thermo gravimetric analyzer (TGA), X-ray fluorescence spectrometer (XRF) and computer controlled scanning electron microscope (CCSEM). Combustion experiments were also conducted using drop tube furnace (DTF) to determine the burnout of the raw coals and blends. The selection of technically suitable coal combination for blending, based on these characterization studies, has been detailed.

  19. Learning Design Development for Blended Learning

    DEFF Research Database (Denmark)

    Hansen, Janne Saltoft

    Learning design development for blended learning We started implementing Blackboard at Aarhus University in 2013. At the Health Faculty Blackboard replaced AULA which was a LMS with functionality for file distribution and only a vague focus on learning tools. Most teachers therefore had...... no experiences with blended leaning and technology supported out-of-class activities. At the pedagogical unit at the Health faculty we wanted to follow the Blackboard implementation with pedagogical tools for learning design to evolve the pedagogical use of the system. We needed to make development of blended...... learning courses easier for the teachers and also ensure quality in the courses. This poster describes the process from development of the learning design to implementation of the learning design at the faculty: 1. How to place demands on a learning design-model and how to develop and use such a model. 2...

  20. Análise do desenvolvimento morfológico da blenda polimérica PBT/ABS durante as etapas de mistura por extrusão e moldagem por injeção Analysis of the morphological development of PBT/ABS blends during the extrusion and injection molding processes

    Directory of Open Access Journals (Sweden)

    Edson N. Ito

    2004-06-01

    electron microscopy (TEM. They were prepared by cryo-ultramicrotomy and the rubbery phase of the ABS contained in the blends was stained with osmium tetroxide (OsO4. A special function was established and is proposed to analyze the blend morphology trends through image analysis. In binary blends, the ABS phase showed better dispersion after the mixture passed through the extruder die. However, a coalescence phenomenon was observed during the next molding step. Compatibilized PBT/ABS blends showed better dispersion than binary blends, even after injection molding. The special function used to quantify the dispersion throughout the mixing and molding steps showed an excellent performance.