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Sample records for olefin drilling fluid

  1. Reduced abrasion drilling fluid

    NARCIS (Netherlands)

    2010-01-01

    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  2. Reduced abrasion drilling fluid

    NARCIS (Netherlands)

    2012-01-01

    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  3. Optimizing drilling performance using a selected drilling fluid

    Science.gov (United States)

    Judzis, Arnis [Salt Lake City, UT; Black, Alan D [Coral Springs, FL; Green, Sidney J [Salt Lake City, UT; Robertson, Homer A [West Jordan, UT; Bland, Ronald G [Houston, TX; Curry, David Alexander [The Woodlands, TX; Ledgerwood, III, Leroy W.

    2011-04-19

    To improve drilling performance, a drilling fluid is selected based on one or more criteria and to have at least one target characteristic. Drilling equipment is used to drill a wellbore, and the selected drilling fluid is provided into the wellbore during drilling with the drilling equipment. The at least one target characteristic of the drilling fluid includes an ability of the drilling fluid to penetrate into formation cuttings during drilling to weaken the formation cuttings.

  4. Inverted emulsion drilling fluid

    Energy Technology Data Exchange (ETDEWEB)

    Ana, I; Astanei, E; Mireanu, G; Orosz, M; Popescu, F; Vasile, I

    1979-07-28

    The subject of the invention is the method of obtaining inverted drilling fluid which is required during stripping of a productive bed and ending of a well where difficulties develop during drilling of the argillaceous rock. Example: in a reservoir with capacity 30 m/sup 3/, 10 m/sup 3/ of diesel fuel are added. A total of 1000 kg of emulsifier are added to the diesel fuel consisting of: 85 mass% of a mixture of sodium and potassium salts of fatty acids, residues of fatty acids or naphthene acids with high molecular weight taken in proportion of 10:90; 5 mass% of a mixture of polymers with hydrophilic-hydrophobic properties obtained by mixing 75 mass% of polyethylene oxide with molecular weight 10,000 and 25 mass% of propylene oxide with molecular weight 15,000, and 10 mass% of salt on alkaline earth metal (preferably calcium chloride). The mixture is mixed into complete dissolving. Then 1200 kg of filtering accelerator are added obtained from concentrated sulfuric acid serving for sulfur oxidation, asphalt substance with softening temperature 85-104/sup 0/C and fatty acids C/sub 10/-C/sub 20/ taken in a proportion of 23.70 and 7 mass% The mixture obtained in this manner is neutralized by adding calcium hydroxide and equal quantities of alumina and activated bentonite clay in a concentration of 1-10 mass%, more preferably 5 mass% in relation to the initial mixture. The obtained mass is mixed until complete dispersion, after which 200 kg of organophilic clay are added obtained from bentonite of the type montmorillonite of sodium by processing with derivate obtained from amine of the type of the quaternary base of ammonium salt, and agent of hydrophobization of the type of fatty alcohols, fatty acids, nonion surfactants of the block-polymer type. After complete dispersion of the organophilic clay, 100 kg of stabilizer of emulsion of the surfactant type was added with molecular weight of 250010,000, more preferably 5000, in concentration of 0.1-5.0 mass%, more

  5. Effects of drilling fluids on marine organisms

    International Nuclear Information System (INIS)

    Parrish, P.R.; Duke, T.W.

    1990-01-01

    This paper reports on drilling fluids, also called drilling muds, which are essential to drilling processes in the exploration and production of oil and gas from the U.S. Outer Continental Shelf (OCS). These fluids are usually discharged from drilling platforms into surrounding waters of the OCS and are regulated by the U.S. Environmental Protection Agency (EPA). In a program carried out by the EPA Environmental research Laboratory at Gulf Breeze, Florida, diverse marine species as well as microbiotic and macrobiotic communities were studied. Drilling fluids were toxic to marine organisms in certain concentrations and exposure regimes. Furthermore, the fluids adversely affected the benthos physically by burying them or by altering the substrates. Toxicity of the drilling-fluid components, used drilling fluids from active Gulf of Mexico sites, and laboratory-prepared drilling fluids varied considerably. for example 96-h LC 50 s were from 25 μ liter -1 to > 1500 μl liter -1 for clams, larval lobsters, mysids, and grass shrimp. In most instances, mortality was significantly (α = 0.05) correlated with the diesel-oil content of the fluids collected from the Gulf of Mexico. Data and model simulations suggest a rapid dilution of drilling fluids released into OCS waters, resulting in concentrations below the acute-effect concentration for the water column organisms tested

  6. Drilling Fluids Using Multiwall Carbon Nanotube (MWCNT

    Directory of Open Access Journals (Sweden)

    Mostafa Sedaghatzadeh

    2012-11-01

    Full Text Available Designing drilling fluids for drilling in deep gas reservoirs and geothermal wells is a major challenge. Cooling drilling fluids and preparing stable mud with high thermal conductivity are of great concern. Drilling nanofluids, i.e. a low fraction of carbon nanotube (CNT well dispersed in mud, may enhance the mixture thermal conductivity compared to the base fluids. Thus, they are potentially useful for advanced designing high temperature and high pressure (HTHP drilling fluids. In the present study, the impacts of CNT volume fraction, ball milling time, functionalization, temperature, and dispersion quality (by means of scanning electron microscopy, SEM on the thermal and rheological properties of water-based mud are experimentally investigated. The thermal conductivities of the nano-based drilling fluid are measured with a transient hot wire method. The experimental results show that the thermal conductivity of the water-based drilling fluid is enhanced by 23.2% in the presence of 1 vol% functionalized CNT at room temperature; it increases by 31.8% by raising the mud temperature to 50 °C. Furthermore, significant improvements are seen in the rheological properties—such as yield point, filtration properties, and annular viscosity—of the CNTmodified drilling fluid compared to the base mud, which pushes forward their future development.

  7. HORIZONTAL WELL DRILL-IN FLUIDS

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    1998-12-01

    Full Text Available Main objective of horizontal driling is to place a drain-hole for a long distance within the pay zone to enhance productivity or injectivity. In drilling horizontal wells, more serious problems appear than in drilling vertical wells. These problems are: poor hole cleaning, excessive torque and drag, hole filling, pipe stucking, wellbore instability, loss of circulation, formation damage, poor cement job, and difficulties at logging jobs. From that reason, successful drilling and production of horizontal well depends largely on the fluid used during drilling and completion phases. Several new fluids, that fulfill some or all of required properties (hole cleaning, cutting suspension, good lubrication, and relative low formation damage, are presented in this paper.

  8. Tragacanth gum: an effective oil well drilling fluid additive

    Energy Technology Data Exchange (ETDEWEB)

    Mahto, V.; Sharma, V. [Indian School of Mines, Dhanbad (India). Department of Petroleum Engineering

    2005-02-15

    The low penetration rate, excessive torque and drag, poor hole cleaning and formation damage are major impediments in drilling oil and gas well. These have a major impact on drilling efficiency and well economics. Keeping these in mind, an attempt was made to design a water based drilling fluid system using Indian bentonite clays and tragacanth gum. The effect of tragacanth gum on rheological behavior of three different Indian bentonite water suspensions was studied and a drilling fluid system was developed. The filtrates of these drilling fluids were subjected to formation damage study on the field core using Ruska Liquid Permeameter. The laboratory investigation furnishes that tragacanth gum acts as a good viscosifier and fluid loss control agent. The drilling fluid filtrate also has less effect on formation damage. (author)

  9. The impact of environmental regulations on drilling fluid technology

    International Nuclear Information System (INIS)

    Clark, R.K.

    1994-01-01

    A multitude of new drilling fluid products, systems, and treatment processes have been developed in recent years in response to increasingly stringent environmental regulations. Many fluid additives and systems that once played a major role in the drilling industry are little used today or are no longer available. New water-base mud systems are approaching the performance levels typical of conventional oil-base muds, levels largely achieved by the new synthetic-base fluids. However, these new drilling fluids do not have the adverse environmental impact associated with oil-base systems when waste fluids and cuttings are discarded. 65 refs., 3 tabs

  10. Optimum fluid design for drilling and cementing a well drilled with coil tubing technology

    Energy Technology Data Exchange (ETDEWEB)

    Swendsen, O.; Saasen, A.; Vassoy, B. [Statoil (Norway); Skogen, E.; Mackin, F.; Normann, S. H.

    1998-12-31

    The strategy, design and drilling fluid and cementing operations in the first two wells drilled with coil tubing technology in the Gullfaks field in the Tampen Spur Area of the Norwegian sector of the North Sea are discussed. The drilling fluid use was a solids-free potassium formate/polymer brine-based fluid with a density of 1,50-1.56 g/cc, with flow properties characterized by very low fluid loss due to high extensional viscosity, a low viscosity at all shear rates, and a low degree of shear-thinning. The low viscous drilling fluid is considered to have been the major contributing factor in achieving excellent hole cleaning, no differential sticking, successful setting of cement kick-off plugs, problem-free running of the liner, and excellent zonal isolation when cementing the liner. These experiences led the authors to conclude that it is possible to formulate a brine-based solids-free drilling fluid with low viscosity and fluid loss properties for most formation pressure regimes, and that such a drilling fluid is well suited to drilling highly deviated slim hole wells where hole cleaning and differential sticking present special challenges. 12 refs., 2 tabs., 3 figs.

  11. 30 CFR 250.458 - What quantities of drilling fluids are required?

    Science.gov (United States)

    2010-07-01

    ... OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations... the daily inventories of drilling fluid and drilling fluid materials, including weight materials and... drilling fluid material to maintain well control, you must suspend drilling operations. [68 FR 8423, Feb...

  12. Means and Method for Measurement of Drilling Fluid Properties

    Science.gov (United States)

    Lysyannikov, A.; Kondrashov, P.; Pavlova, P.

    2016-06-01

    The paper addresses the problem on creation of a new design of the device for determining rheological parameters of drilling fluids and the basic requirements which it must meet. The key quantitative parameters that define the developed device are provided. The algorithm of determining the coefficient of the yield point from the rheological Shvedov- Bingam model at a relative speed of rotation of glasses from the investigated drilling fluid of 300 and 600 rpm is presented.

  13. Optimization of surfactant application for synthetic drilling fluid; Otimizacao da aplicacao de emulsificante em fluidos de perfuracao sinteticos

    Energy Technology Data Exchange (ETDEWEB)

    Arruda, Jefferson Teixeira [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Santos, Telma Pitanga; Medeiros, Ana Catarina da Rocha; Garcia, Rosangela Balaban [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Lab. de Pesquisa em Petroleo

    2008-07-01

    The most common synthetic drilling fluids are made of polymerized olefins, paraffin and esters, which have absence of aromatics hydrocarbons and biodegradability as advantages. These fluids have good performance during the drilling operations (high thermal stability) and have low toxicity. Nevertheless, their big disadvantage is the high cost, which limits their use. One of the biggest challenges in working with synthetic fluids is the control of water/oil emulsion stability, being the surfactant the main agent responsible for keeping this stability between both phases of the fluid. The water/oil and oil/water emulsion is defined by the chemical nature of the surfactant. The emulsions can be changed from oil/water to water/oil and vice versa by many mechanisms, such as temperature variation, addition of another surfactant and alteration of the disperse phase volumetric percentage. The aim of this work was the optimization of synthetic drilling fluids formulations by using commercial surfactants. The optimized formulations showed similar rheological properties. After aging at high temperature (300 deg F), some tendency to migration of oil phase in both fluids was observed. This result was associated to the fluid's viscosity. However, the formulations showed high electrical stability, indicating formation of stable emulsions. The HTHP filtration volumes were small. (author)

  14. Rheological behavior of drilling fluids under low temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Lomba, Rosana F.T.; Sa, Carlos H.M. de; Brandao, Edimir M. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas]. E-mails: rlomba, chsa, edimir@cenpes.petrobras.com.br

    2000-07-01

    The so-called solid-free fluids represent a good alternative to drill through productive zones. These drill-in fluids are known to be non-damaging to the formation and their formulation comprise polymers, salts and acid soluble solids. Xanthan gum is widely used as viscosifier and modified starch as fluid loss control additive. The salts most commonly used are sodium chloride and potassium chloride, although the use of organic salt brines has been increasing lately. Sized calcium carbonate is used as bridging material, when the situation requires. The low temperatures encountered during deep water drilling demand the knowledge of fluid rheology at this temperature range. The rheological behavior of drill-in fluids at temperatures as low as 5 deg C was experimentally evaluated. Special attention was given to the low shear rate behavior of the fluids. A methodology was developed to come up with correlations to calculate shear stress variations with temperature. The developed correlations do not depend on a previous choice of a rheological model. The results will be incorporated in a numerical simulator to account for temperature effects on well bore cleaning later on. (author)

  15. Polyethylene glycol drilling fluid for drilling in marine gas hydrates-bearing sediments: an experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, G.; Liu, T.; Ning, F.; Tu, Y.; Zhang, L.; Yu, Y.; Kuang, L. [China University of Geosciences, Faculty of Engineering, Wuhan (China)

    2011-07-01

    Shale inhibition, low-temperature performance, the ability to prevent calcium and magnesium-ion pollution, and hydrate inhibition of polyethylene glycol drilling fluid were each tested with conventional drilling-fluid test equipment and an experimental gas-hydrate integrated simulation system developed by our laboratory. The results of these tests show that drilling fluid with a formulation of artificial seawater, 3% bentonite, 0.3% Na{sub 2}CO{sub 3}, 10% polyethylene glycol, 20% NaCl, 4% SMP-2, 1% LV-PAC, 0.5% NaOH and 1% PVP K-90 performs well in shale swelling and gas hydrate inhibition. It also shows satisfactory rheological properties and lubrication at temperature ranges from -8 {sup o}C to 15 {sup o}C. The PVP K-90, a kinetic hydrate inhibitor, can effectively inhibit gas hydrate aggregations at a dose of 1 wt%. This finding demonstrates that a drilling fluid with a high addition of NaCl and a low addition of PVP K-90 is suitable for drilling in natural marine gas-hydrate-bearing sediments. (authors)

  16. Polyethylene Glycol Drilling Fluid for Drilling in Marine Gas Hydrates-Bearing Sediments: An Experimental Study

    Directory of Open Access Journals (Sweden)

    Lixin Kuang

    2011-01-01

    Full Text Available Shale inhibition, low-temperature performance, the ability to prevent calcium and magnesium-ion pollution, and hydrate inhibition of polyethylene glycol drilling fluid were each tested with conventional drilling-fluid test equipment and an experimental gas-hydrate integrated simulation system developed by our laboratory. The results of these tests show that drilling fluid with a formulation of artificial seawater, 3% bentonite, 0.3% Na2CO3, 10% polyethylene glycol, 20% NaCl, 4% SMP-2, 1% LV-PAC, 0.5% NaOH and 1% PVP K-90 performs well in shale swelling and gas hydrate inhibition. It also shows satisfactory rheological properties and lubrication at temperature ranges from −8 °C to 15 °C. The PVP K-90, a kinetic hydrate inhibitor, can effectively inhibit gas hydrate aggregations at a dose of 1 wt%. This finding demonstrates that a drilling fluid with a high addition of NaCl and a low addition of PVP K-90 is suitable for drilling in natural marine gas-hydrate-bearing sediments.

  17. Maximizing light olefins production in fluid catalytic cracking (FCC) units; Maximizacao de olefinas leves em unidades de craqueamento catalitico fluido

    Energy Technology Data Exchange (ETDEWEB)

    Pimenta, Ricardo D.M.; Pinho, Andrea de Rezende [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The Fluid Catalytic Cracking (FCC) process is widely spread over the ten PETROBRAS refineries in its thirteen industrial units. The importance of the FCC process resides on its high gasoline output, being the main supplier of this important product to the system. Additionally, FCC process is the main source of light hydrocarbons in the LPG range, including light olefins. The increasing demand for ethylene, propylene and butylenes was encouraging to concentrate the research efforts on studies about alternatives for the traditional FCC process. In the present work, the proposals from main licensors (UOP, KBR, Stone and Webster) for a light-olefins-driven FCC process (Petrochemical FCC) will be compared. Furthermore, the catalytic route for light olefins production in FCC units is also described. An additive based on ZSM- 5 zeolite, which is produced following a PETROBRAS proprietary technology, is being largely applied into the catalyst inventories of all FCC units. An analysis of different scenarios was performed to estimate the maximum potential of light olefins production from the highest possible ZSM-5 additive usage. More specifically for the case of ethylene, which production is also boosted by the same type of additive, studies are being conducted with the objective of recovering it from a C2 stream using specific units to do the splitting (UPGR). The search for increasing light olefins production in the refining processes is in line with PETROBRAS strategic plan which targeted for the company a more intense activity in the Brazilian petrochemical market (author)

  18. A wash fluid for drilling into a field

    Energy Technology Data Exchange (ETDEWEB)

    Belyakov, V M; Badzhurak, R F; Koptelova, Ye K; Rogovoy, V K; Sapozhnikov, N G

    1979-01-18

    A wash fluid is proposed, used in drilling wells in water and a content of 3-5% by weight starch products. To speed up destruction of the starch products, to the fluid are added amylolytic enzymes in the amount of 0.01-0.1 percent by weight of the starch products' weight. To lower the use of starch products, up to 3% clay can be added to the fluid. The wash fluid is prepared directly at the work site. Dry powder of modified starch is mixed with cold water until a colloidal solution is obtained. Such a wash fluid preserves the required structural-mechanical properties for 3-5 days, which ensures prompt drilling into the waterbearing layer and installation of the filter. Then, during the work process, 5-6 hours before the moment required for lowering the viscosity, to the wash fluid is added the amylolytic enzyme; under its influence, the starch molecules split up, and the viscosity drops sharply. Using this wash fluid enables a reduction in well construction times from the beginning of drilling to the end of development of the water-bearing layer, and a rise in outputs and well service lives by reducing sedimentation of the water-bearing formation and elimination of down times during work required while waiting for destruction of the starch wash fluid under natural conditions.

  19. Simulated behavior of drilling fluid discharges off Southern California

    International Nuclear Information System (INIS)

    Brandsma, M.G.; Kolpack, R.L.; Dickey, T.D.; Balcom, B.J.

    1990-01-01

    This paper focuses on the computer-simulated short-term behavior of drilling-fluid solids from the time of release to initial deposition on the ocean bottom. The geographic areas of primary interest were the Santa Barbara Channel and Point Conception regions off southern California. Simulations (53) were conducted for water depths ranging from 30 to 750 m. Oceanographic parameters for several representative oceanic conditions were obtained from available field measurements in the area. Characteristics of representative drilling-fluid solids were formulated from information supplied by several offshore operators and by laboratory analyses of samples

  20. Clay-based geothermal drilling fluids

    Energy Technology Data Exchange (ETDEWEB)

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  1. Framework for a comparative environmental assessment of drilling fluids

    Energy Technology Data Exchange (ETDEWEB)

    Meinhold, A.F.

    1998-11-01

    During the drilling of an oil or gas well, drilling fluid (or mud) is used to maintain well control and to remove drill cuttings from the hole. In response to effluent limitation guidelines promulgated by the US Environmental Protection Agency (EPA) for discharge of drilling wastes offshore, alternatives to water and oil-based muds have been developed. These synthetic-based muds (SBMs) are more efficient than water-based muds (WBMs) for drilling difficult and complex formation intervals and have lower toxicity and smaller environmental impacts than diesel or conventional mineral oil-based muds (OBMs). A third category of drilling fluids, derived from petroleum and called enhanced mineral oils (EMOs), also have these advantages over the traditionally used OBMs and WBMs. EPA recognizes that SBMs and EMOs are new classes of drilling fluids, but their regulatory status is unclear. To address this uncertainty, EPA is following an innovative presumptive rulemaking process that will develop final regulations for SBM discharges offshore in less than three years. This report develops a framework for a comparative risk assessment for the discharge of SBMs and EMOs, to help support a risk-based, integrated approach to regulatory decision making. The framework will help identify potential impacts and benefits associated with the use of SBMs, EMOs, WBMs, and OBMs; identify areas where additional data are needed; and support early decision-making in the absence of complete data. As additional data becomes available, the framework can support a full quantitative comparative assessment. Detailed data are provided to support a comparative assessment in the areas of occupational and public health impacts.

  2. Purification of drilling fluids by vibration-settling tanks

    Energy Technology Data Exchange (ETDEWEB)

    Bulatov, A.I.; Prokopov, L.I.; Proselkov, Yu.M.; Reznichenko, I.N.; Skvortsov, D.S.; Volkov, A.P.

    1982-01-01

    Results are presented of studies done by the authors of a prototype of a new tool for cleaning a drilling fluid, a vibration settling tank. It is indicated that the vibration settling tank has many advantages over the most advanced vibration screens VS-1. This makes it possible to recommend development and broad industrial testing of this apparatus.

  3. Drilling fluid base oil biodegradation potential of a soil ...

    African Journals Online (AJOL)

    Staphylococcus sp. isolated from oil-contaminated soil was grown in 1% drilling fluid base oil, HDF- 2000, as a sole source of carbon and energy. The organism has strong affinity for the substrate, growing at the rate of 0.16 h-1. It uses adherence and emulsification as mechanisms for oil uptake. In a nutrient-rich marine ...

  4. 30 CFR 250.457 - What equipment is required to monitor drilling fluids?

    Science.gov (United States)

    2010-07-01

    ... monitor the drilling fluid returns. The indicator may be located in the drilling fluid-logging compartment... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What equipment is required to monitor drilling... OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations...

  5. AN EXPERIMENTAL STUDY OF CUTTING FLUID EFFECTS IN DRILLING. (R825370C057)

    Science.gov (United States)

    Experiments were designed and conducted on aluminum alloys and gray cast iron to determine the function of cutting fluid in drilling. The variables examined included speed, feed, hole depth, tool and workpiece material, cutting fluid condition, workpiece temperatures and drill...

  6. Control of chemical usage in drilling fluid formulations to minimize discharge to the environment

    International Nuclear Information System (INIS)

    Geehan, T.; Forbes, D.M.; Moore, D.J.

    1991-01-01

    A reduction in the environmental footprint from drilling operations can best be addressed by minimizing the sources of that footprint. One of the principal sources of possible environmental damage is drilling fluid and drill solid discharge. The toxicity as measured by acute and/or sub-chronic testing regimes depends on the composition of the drilling fluid/drill solids slurry. The trend within the drilling fluids industry has been to direct its attention to finding drilling fluid products which alone and in combination are considered to be non-toxic as determined by required testing procedures. This paper goes on to describe a parallel approach in which the total volume of chemicals discharged (whether considered toxic or benign) is reduced. Both approaches can be considered complimentary. The reduction in volume/mass of discharge is achieved by increased monitoring of both drilling fluid properties, composition and solids control operational efficiency. Additionally the increased monitoring allows less complicated formulations to be used to produce the desired drilling fluid properties; as specified by the mud programme. The need for more complete rigsite monitoring packages, will become more important as oilbased muds are replaced by waterbased mud for difficult drilling situations with stricter environmental regulations on discharge of drilling waste. The paper also outlines how the optimization of the drilling fluid operation was linked to a reduction in drilling fluid costs at the same time maintaining drilling efficiency

  7. Offshore disposal of oil-based drilling fluid waste

    International Nuclear Information System (INIS)

    Malachosky, E.; Shannon, B.E.; Jackson, J.E.

    1991-01-01

    Offshore drilling operations in the Gulf of Mexico may use oil-based drilling fluids to mitigate drilling problems. The result is the generation of a significant quantity of oily cuttings and mud. The transportation of this waste for onshore disposal is a concern from a standpoint of both personnel safety and potential environmental impact. A process for preparing a slurry of this waste and the subsequent disposal of the slurry through annular pumping has been put into use by ARCO Oil and Gas Company. The disposal technique has been approved by the Minerals Management Service (MMS). The slurried waste is displaced down a casing annulus into a permeable zone at a depth below the surface casing setting depth. The annular disposal includes all cuttings and waste oil mud generated during drilling with oil-based fluids. This disposal technique negates the need for cuttings storage on the platform, transportation to shore, and the environmental effects of onshore surface disposal. The paper describes the environmental and safety concerns with onshore disposal, the benefits of annular disposal, and the equipment and process used for the preparation and pumping of the slurry

  8. Agarwood Waste as A New Fluid Loss Control Agent in Water-based Drilling Fluid

    Directory of Open Access Journals (Sweden)

    Azlinda Azizi

    2013-10-01

    Full Text Available Normal 0 false false false IN X-NONE X-NONE MicrosoftInternetExplorer4 Agarwood has been used widely in various ways, including traditional medicine and art. The usage of agarwood has grown broader in modern times include in therapeutic medicines and perfumery. In this paper the agarwood waste has been explored to be used as a fluid loss control agent to control fluid loss without affecting the drilling fluid rheological properties which are density, pH, viscosity, yield point and gel strength. Agarwood waste was used as an additive in the drilling fluid system due to its unique characteristic. Rheological and filtration measurements were performed on the formulated water-based drilling fluid. Formulations of a base solution of fresh water, sodium hydroxide, bentonite, barite, and xanthan gum were presented. The performance of the agarwood waste as the fluid loss control agent was compared with based fluid formulation and water-based drilling fluid with treating with conventional fluid loss control agent (starch. The filtrate volume of drilling fluid with agarwood waste was about 13 ml while for drilling fluid with conventional fluid loss control agent, starch gave 12 ml of filtrate volume after undergoing filtration test by using LPLT filter press. The performance of drilling fluid with agarwood was efficient as drilling fluid with starch. /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso

  9. Control and particles distribution in drilling fluids while drilling; Controle e distribuicao de particulas em fluidos de perfuracao enquanto perfurando

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Luiz Augusto dos [PETROBRAS, XX (Brazil). Dept. de Perfuracao. Div. de Fluidos de Perfuracao

    1988-12-31

    Factors contributing both directly and indirectly to formation damage are discussed, including plugging by solids disseminated in drilling fluids, filtrations, spurt loss, and cake deposition. (author) 6 refs., 12 figs., 4 tabs.

  10. Numerical modelling of cuttings transport in horizontal wells using conventional drilling fluids

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y.; Bjorndalen, E.; Kuru, E. [Alberta Univ., Edmonton, AB (Canada)

    2004-07-01

    Some of the problems associated with poor wellbore cleaning include high drag or torque, slower rate of penetration, formation fractures and difficulty in wellbore steering. Some of the factors that affect cuttings transport include drilling fluid velocity, inclination angle, drilling fluid viscosity and drilling rate. The general practice is to stop drilling when necessary to clean boreholes with viscous pills, pipe rotation or drilling fluid circulation. It is important to predict when drilling should be stopped for remedial wellbore cleaning. This can be accomplished with a transient cuttings transport model which can improve drilling hydraulics, particularly in long horizontal well sections and extended reach (ERD) wells. This paper presents a newly developed 1-dimensional transient mechanistic model of cuttings transport with conventional (incompressible) drilling fluids in horizontal wells. The numerically solved model predicts the height of cutting beds as a function of different drilling operational parameters such as fluid flow rate and rheological characteristics, drilling rates, wellbore geometry and drillpipe eccentricity. Sensitivity analysis has demonstrated the effects of these parameters on the efficiency of solids transport. The proposed model can be used in the creation of computer programs designed to optimize drilling fluid rheology and flow rates for horizontal well drilling. 29 refs., 3 tabs., 12 figs.

  11. Graphene nanoplatelets as high-performance filtration control material in water-based drilling fluids

    Science.gov (United States)

    Ridha, Syahrir; Ibrahim, Arif; Shahari, Radzi; Fonna, Syarizal

    2018-05-01

    The main objective of this work is to evaluate the effectiveness of graphene nanoplatelets (GNP) as filtration control materials in water based drilling fluids. Three (3) general samples of water based drilling fluids were prepared including basic potassium chloride (KCl) drilling fluids, nanosilica (NS) drilling fluids and GNP drilling fluids. Several concentrations of NS and GNP were dispersed in controlled formulations of water based drilling fluids. Standard API filtration tests were carried out for comparison purposes as well as High Temperature High Pressure (HTHP) filtration tests at 150 °F (∼66 °C), 250 °F (∼121 °C) and 350 °F (∼177 °C) at a fixed 500 (∼3.45MPa) psi to study the filtration trend as a function of temperature. Mud cake samples from several tests were selectively chosen and analyzed under Field Emission Scanning Electron Microscope (FESEM) for its morphology. Results from this work show that nanoparticle concentrations play a factor in filtration ability of colloid materials in water based drilling fluids when studied at elevated temperature. Low temperature filtration, however, shows only small differences in volume in all the drilling fluid samples. 0.1 ppb concentrations of GNP reduced the fluid loss of 350 °F by 4.6 mL as compared to the similar concentration of NS drilling fluids.

  12. Polymer Drilling Fluid with Micron-Grade Cenosphere for Deep Coal Seam

    Directory of Open Access Journals (Sweden)

    Peng Xu

    2015-01-01

    Full Text Available Traditional shallow coal seam uses clean water, solid-free system, and foam system as drilling fluid, while they are not suitable for deep coal seam drilling due to mismatching density, insufficient bearing capacity, and poor reservoir protection effect. According to the existing problems of drilling fluid, micron-grade cenosphere with high bearing capacity and ultralow true density is selected as density regulator; it, together with polymer “XC + CMC” and some other auxiliary agents, is jointly used to build micron-grade polymer drilling fluid with cenosphere which is suitable for deep coal seam. Basic performance test shows that the drilling fluid has good rheological property, low filtration loss, good density adjustability, shear thinning, and thixotropy; besides, drilling fluid flow is in line with the power law rheological model. Compared with traditional drilling fluid, dispersion stability basically does not change within 26 h; settlement stability evaluated with two methods only shows a small amount of change; permeability recovery rate evaluated with Qinshui Basin deep coal seam core exceeds 80%. Polymer drilling fluid with cenosphere provides a new thought to solve the problem of drilling fluid density and pressure for deep coal seam drilling and also effectively improves the performance of reservoir protection ability.

  13. Method and apparatus for determining fluid circulation conditions in well drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Gehrig, G.F.; Speers, J.M.

    1986-09-09

    A system is described for monitoring the delta flow-rate of drilling fluid in the course of circulating drilling fluid through a well from a drilling rig, comprising: an inflow flowmeter adapted for establishing a first signal representing the rate at which drilling fluid is injected into the well from the drilling rig; an outflow flowmeter adapted for establishing a second signal representing the rate at which drilling fluid is returned to the drilling rig from the well; and a signal processing system adapted for receiving the first and second signals and calculating a third signal representing the filtered difference between the first and second signals, the signal processing system being adapted to repeatedly update the degree of filtering applied in calculating the third signal in accordance with a relation serving to increase the degree of filtering in response to an increase in the magnitude of the cyclical variations in the rate at which drilling fluid is returned to the drilling rig and to decrease the degree of filtering in response to a decrease in the magnitude of the cyclical variations in the rate at which drilling fluid is returned to the drilling rig.

  14. Rheological and filtration characteristics of drilling fluids enhanced by nanoparticles with selected additives: an experimental study

    Directory of Open Access Journals (Sweden)

    Nima Mohamadian

    2018-05-01

    Full Text Available The suspension properties of drilling fluids containing pure and polymer-treated (partially-hydrolyzed polyacrylamide (PHPA or Xanthan gum clay nanoparticles are compared withthose of a conventional water-and-bentonite-based drilling fluid, used as the referencesample. Additionally, the mud weight, plastic viscosity, apparent viscosity, yield point, primary and secondary gelatinization properties, pH, and filtration properties of the various drilling fluids studied are also measured and compared. The performance of each drilling fluid type is evaluated with respect in terms of its ability to reduce mud cake thickness and fluid loss thereby inhibiting differential-pipe-sticking. For that scenario, the mud-cake thickness is varied, and the filtration properties of the drilling fluids are measured as an indicator of potential well-diameter reduction, caused by mud cake, adjacent to permeable formations. The novel results show that nanoparticles do significantly enhance the rheological and filtration characteristics of drilling fluids. A pure-clay-nanoparticle suspension, without any additives, reduced fluid loss to about 42% and reduced mud cake thickness to 30% compared to the reference sample. The xanthan-gum-treated-clay-nanoparticle drilling fluid showed good fluid loss control and reduced fluid loss by 61% compared to the reference sample. The presence of nanofluids also leads to reduced mud-cake thicknesses, directly mitigating the risks of differential pipe sticking.

  15. Effect of drilling fluids on permeability of uranium sandstone. Report of Investigations/1984

    International Nuclear Information System (INIS)

    Ahlness, J.K.; Johnson, D.I.; Tweeton, D.R.

    1984-01-01

    The Bureau of Mines conducted laboratory and field experiments to determine the amount of permeability reduction in uranium sandstone after its exposure to different drilling fluids. Seven polymer and two bentonite fluids were laboratory-tested in their clean condition, and six polymer fluids were tested with simulated drill cuttings added. Sandstone cores cut from samples collected at an open pit uranium mine were the test medium. The clean fluid that resulted in the least permeability reduction was an hydroxyethyl cellulose polymer fluid. The greatest permeability reduction of the clean polymers came from a shale-inhibiting synthetic polymer. Six polymer fluids were tested with simulated drill cuttings added to represent field use. The least permeability reduction was obtained from a multi-polymer blend fluid. A field experiment was performed to compare how two polymer fluids affect formation permeability when used for drilling in situ uranium leaching wells

  16. Selective-placement burial of drilling fluids: 2. Effects on buffalograss and fourwing saltbrush

    International Nuclear Information System (INIS)

    McFarland, M.L.; Hartmann, S.; Ueckert, D.N.; Hons, F.M.

    1992-01-01

    Surface disposal of spent drilling fluids used in petroleum and natural gas exploration causes surface soil contamination that severely inhibits secondary plant succession and artificial revegetation efforts. Selective-placement burial was evaluated at two locations in western Texas for on-site disposal of drilling fluids in arid and semiarid regions. Establishment, yield, and chemical composition of fourwing saltbrush [Atriplex canescens (Pursh Nutt.)] and buffalograss [Buchloe dactyloides (Nutt.) Engelm.] transplants on undisturbed soils and on plots with spent drilling fluids and cuttings buried 30, 90 (with and without a 30-cm coarse limestone capillary barrier) and 150 cm were compared. Survival of both species was 97 to 100% 17 months after planting on plots with buried drilling wastes. Canopy cover and aboveground biomass of fourwing saltbrush were greater over buried drilling wastes than on untreated plots, whereas canopy cover and aboveground biomass of buffalograss were not affected by the treatments. Significant increases in Na, M, and Mg concentrations in buffalograss after 17 months on plots with drilling fluids buried 30 cm deep at one location indicated plant uptake of some drilling fluid constituents. Elevated Zn concentrations in fourwing saltbush indicated that a portion of the Zn in the drilling fluids was available for plant uptake, while no evidence of plant accumulation of Ba, Cr, Cu, or Ni from drilling fluids was detected

  17. Phospholipids Polysaccharide and Its Application as Inhibitive Drilling Fluid Additive

    Science.gov (United States)

    Gu, Xue-Fan; Hu, Wei-Min; Zhang, Fan; Du, Wei-Chao; Zhang, Qiang; Zhang, Jie; Zhang, Yong-Ming; Chen, Gang

    2018-03-01

    For the improvement of solubility and the performance of the sample that derived plant polysaccharide(SJ) in drilling fluid based on water, which was improved by phosphoric esterification with phospholipids reagent. The conditions of the reaction were discussed by orthogonal ways in four factors and three levels, and the optimization of handling approaches were found out: With pH=12 at the temperature of 80°C, the mass ratio between phospholipids agent and SJ is 0.1g/1g. The viscosity about the system added by sulfonated SJ (SJP) was extremely increased and below 120°, rheological properties had a slight change. The inhibitive ability of SJP is assessed by the mud ball immersing tests and clay-swelling experiments, that is apparently better than SJ and even 4wt% KCl in free water.

  18. WETTABILITY AND PREDICTION OF OIL RECOVERY FROM RESERVOIRS DEVELOPED WITH MODERN DRILLING AND COMPLETION FLUIDS

    Energy Technology Data Exchange (ETDEWEB)

    Jill S. Buckley; Norman R. Morrow

    2004-05-01

    We report on progress in three areas. In part one, the wetting effects of synthetic base oils are reported. Part two reports progress in understanding the effects of surfactants of known chemical structures, and part three integrates the results from surface and core tests that show the wetting effects of commercial surfactant products used in synthetic and traditional oil-based drilling fluids. An important difference between synthetic and traditional oil-based muds (SBM and OBM, respectively) is the elimination of aromatics from the base oil to meet environmental regulations. The base oils used include dearomatized mineral oils, linear alpha-olefins, internal olefins, and esters. We show in part one that all of these materials except the esters can, at sufficiently high concentrations, destabilize asphaltenes. The effects of asphaltenes on wetting are in part related to their stability. Although asphaltenes have some tendency to adsorb on solid surfaces from a good solvent, that tendency can be much increased near the onset of asphaltene instability. Tests in Berea sandstone cores demonstrate wetting alteration toward less water-wet conditions that occurs when a crude oil is displaced by paraffinic and olefinic SBM base oils, whereas exposure to the ester products has little effect on wetting properties of the cores. Microscopic observations with atomic forces microscopy (AFM) and macroscopic contact angle measurements have been used in part 2 to explore the effects on wetting of mica surfaces using oil-soluble polyethoxylated amine surfactants with varying hydrocarbon chain lengths and extent of ethoxylation. In the absence of water, only weak adsorption occurs. Much stronger, pH-dependent adsorption was observed when water was present. Varying hydrocarbon chain length had little or no effect on adsorption, whereas varying extent of ethoxylation had a much more significant impact, reducing contact angles at nearly all conditions tested. Preequilibration of

  19. EFFECTS OF PROPERTIES POLYMERIC ADDITIVES IN RHEOLOGIC AND DRILLING FLUIDS

    Directory of Open Access Journals (Sweden)

    Danielly Vieira de Lucena

    2014-03-01

    Full Text Available The influence of carboxymethylcellulose, CMC (filtrate reducer and xanthan gum (viscosifier in plastic and apparent viscosity at yield strength and the volume of filtrate in the composition of drilling fluids based on water was investigated based on statistical design. Five formulations consist of a range of concentrations used commercially were utilized in the design of the experiment. The formulations were prepared in accordance with company standards Petrobras. Regression models were calculated and correlated with the properties of the compositions. The relevance and validation of the models were confirmed by statistical analysis. The design can be applied to statistically optimize the mud properties considering the addition of CMC and xanthan gum, and to provide a better understanding of the influence of additives on the properties of polymer-based fluid system water. From the study it was observed that the values of the rheological properties vary with the concentration of additives, increasing with increasing concentration of the same, and that the concentration of the additives caused a decline of parameter values filtration.

  20. Performance of Partially-Hydrolyzed Polyacrylamide in Water Based Drilling Fluids

    Directory of Open Access Journals (Sweden)

    Ali Reza Nasiri*

    2013-05-01

    Full Text Available Fluid properties with constant improvement in efficiency have been noticeable as important criteria in drilling operation. The main drilling fluid properties highly depend on utilization of new polymers with high efficiency in drilling fluid composition. In this paper, the performance of a new polymer, called partially hydrolyzed polyacrylamide polymer (PHPA, is studied which has recently entered the drilling fluids industry in Iran. Hence viscosity property, fluid loss control and shale inhibition of this polymer have been evaluated based on an international standard method of API-13-I by considering the drilling and operational priorities of thecountry. Then the thermal effect, salt contaminants such as sodium chloride, calcium chloride, magnesium chloride and pH tolerance effect as major pollution indicators are also investigated in relation to polymeric fluid properties. The results obtained by the tests show that furthermore polymer PHPA increases rheological properties (apparent viscosity, plastic fluidity and yield point and it plays important role in increases in fluid loss. This polymer has also demonstrated acceptable resistance toward sodium chloride contaminants, but its efficiency decreases toward calcium and magnesium ion contaminants. The thermal tests show that polymer PHPA has high thermal stability up to 150°C. This polymer improves shale inhibition property and by encapsulation mechanism prevents dispersion of shale cuttings into the drilling fluid system as it stops any changes in fluid properties which will finally results inwellbore stability.

  1. Anti-collapse mechanism of CBM fuzzy-ball drilling fluid

    Directory of Open Access Journals (Sweden)

    Lihui Zheng

    2016-03-01

    Full Text Available Although fuzzy-ball drilling fluid has been successfully applied in CBM well drilling, it is necessary to study its anti-collapse mechanism so that adjustable coalbed sealing effects, controllable sealing strength, rational sealing cost and controllable reservoir damage degree can be realized. In this paper, laboratory measurement was performed on the uniaxial compressive strength of the plungers of No. 3 coalbed in the Qinshui Basin and the inlet pressure of Ø38 mm coal plunger displacement. The strengths of coal plungers were tested and compared after 2% potassium chloride solution, low-solids polymer drilling fluid and fuzzy-ball drilling fluid were injected into the coal plungers respectively. It is shown that coal strength rises by 38.46% after the fuzzy-ball drilling fluid is injected (in three groups; and that no fuzzy-ball drilling fluid is lost at the displacement pressures of 20.73 and 21.46 MPa, nor 2% potassium chloride solution is leaked at such pressures of 24.79 and 25.64 MPa after the plunger was sealed by the fuzzy-ball drilling fluid. This indicates that the fuzzy-ball drilling fluid can increase the formation resistance to fluid. Indoor microscopic observation was conducted on the sealing process of the fuzzy-ball drilling fluid in sand packs with coal cuttings of three grain sizes (60–80, 80–100 and 100–120 mesh. It is shown that the leakage pathways of different sizes are sealed by the vesicles in the form of accumulation, stretch and blockage. And there are vesicles at the inlet ends of the flowing pathways in the shape of beaded blanket. The impact force of drilling tools on the sidewalls is absorbed by the vesicles due to their elasticity and tenacity, so the sidewall instability caused by drilling tools is relieved. It is concluded that the main anti-collapse mechanisms of the CBM fuzzy-ball drilling fluid are to raise the coal strength, increase the formation resistance to fluid, and buffer the impact of

  2. New possibilities of developing formulas for flushing drilling fluids

    Energy Technology Data Exchange (ETDEWEB)

    Beregi, I; Dobozy, G; Szornyi, I

    1982-01-01

    The problem of preventing cave-in of the walls of boreholes can be effectively and economically solved only with a broad assortment of flushing fluids (FF) of the corresponding quality. In order to search for inexpensive and simple methods of preparing and formulas of FF which have good stabilizing properties, the authors conducted laboratory studies. It is indicated that this goal can be reached by three methods: 1) improvement in the properties by traditional (based on gypsum and lime) FF by additives (for example, chloride, acetate and potassium dihydrophosphate); 2) production of FF of the limestone type based on new theoretical concepts regarding the mechanism of their effect, and 3) by using as the FF ammonium-containing chemical compounds (for example, diammonium hydrophosphate). The studied FF were tested under field conditions and yielded positive results. It was established that different specific conditions of the wells make it necessary to systematically study clays and marls in the drilling zone in order to select the most effective and economical for the given conditions of FF. This will permit the maximum use of local raw material and selection of the simplest method of preparing FF.

  3. Drilling fluid technologies : what goes in must come out

    International Nuclear Information System (INIS)

    Polczer, S.

    1998-01-01

    The treatment of drilling wastes contaminated with invert drilling muds was discussed. The tight emulsion properties which make invert drilling muds useful are the same properties that make their disposal so difficult. Potential long-term liability associated with inverts is another reason for reluctance to use these products. Inverts are toxic and highly mobile in the environment, and must therefore be handled with care. Often the costs associated with their disposal are greater than their potential benefits. Petro-Canada Lubricants has formulated a new, non-diesel based product called Drill Mud Oil HT40N which completely eliminates toxic aromatic molecules. It is composed of 98 per cent plus of cyclic and branched isoparaffins with an average carbon number of C16. The level of polynuclear aromatics is reduced to parts per billion levels. Drill Mud Oil HT40N was being used at Hibernia until an even newer product, IPAR3 synthetic drill mud oil, was developed exclusively for offshore use. Drill Mud Oil HT40N is less prone to flash fires, is odourless and is more likely to be used in places such as the Western Canada Sedimentary Basin. Drill Mud Oil HT40N works almost exactly the same as a diesel-based drill mud oil but has many advantages in terms of safety and ease of disposal, particularly in landfarming operations. Drill Mud Oil HT40N does not irritate the skin or release toxic fumes. The cost of Drill Mud Oil HT40N is higher than conventional diesel-based drilling muds. 2 figs

  4. The effect of gas and fluid flows on nonlinear lateral vibrations of rotating drill strings

    Science.gov (United States)

    Khajiyeva, Lelya; Kudaibergenov, Askar; Kudaibergenov, Askat

    2018-06-01

    In this work we develop nonlinear mathematical models describing coupled lateral vibrations of a rotating drill string under the effect of external supersonic gas and internal fluid flows. An axial compressive load and a torque also affect the drill string. The mathematical models are derived by the use of Novozhilov's nonlinear theory of elasticity with implementation of Hamilton's variation principle. Expressions for the gas flow pressure are determined according to the piston theory. The fluid flow is considered as added mass inside the curved tube of the drill string. Using an algorithm developed in the Mathematica computation program on the basis of the Galerkin approach and the stiffness switching method the numerical solution of the obtained approximate differential equations is found. Influences of the external loads, drill string angular speed of rotation, parameters of the gas and fluid flows on the drill string vibrations are shown.

  5. A field application of nanoparticle-based invert emulsion drilling fluids

    Energy Technology Data Exchange (ETDEWEB)

    Borisov, Alexey S.; Husein, Maen, E-mail: mhusein@ucalgary.ca [University of Calgary, Department of Chemical & Petroleum Engineering (Canada); Hareland, Geir [Oklahoma State University, Department of Chemical Engineering (United States)

    2015-08-15

    Application of nanotechnology in drilling fluids for the oil and gas industry has been a focus of several recent studies. A process for the in situ synthesis of nanoparticles (NPs) into drilling fluids has been developed previously in our group and showed that calcium-based NPs (CNPs) and iron-based NPs (INPs), respectively, with concentrations of 0.5–2.0 wt% can dramatically improve filtration properties of commercial drilling fluids in a laboratory environment. In this work, a modified process for the emulsion-based synthesis of NPs on a 20 m{sup 3} volume and its subsequent full-scale field testing are presented. Comparison between NP carrier fluids prepared under controlled environment in the laboratory and those prepared on a large scale in a mixing facility revealed very little variation in the main characteristics of the drilling fluid; including the size of the solid constituents. Transmission electron microscopy photographs suggest an average CNP particle size in the carrier fluid of 51 ± 11 nm. Results from the full-scale field test showed that total mud losses while drilling with CNP-based invert emulsion were on average 27 % lower than in the case of conventional fluids. This loss prevention falls within the range observed in the laboratory.

  6. Performance of the mineral blended ester oil-based drilling fluid systems

    Energy Technology Data Exchange (ETDEWEB)

    Ismail, A.R.; Kamis, A.; Foo, K.S. [University Teknologi (Malaysia)

    2001-06-01

    A study was conducted in which the properties of ester oil-based drilling fluid systems were examined using a blended mixture of ester and synthetic mineral oil. Biodegradable invert emulsion ester-based fluids are preferred over mineral oil-based drilling fluids for environmental reasons, but they tend to cause alkaline hydrolysis resulting in solidification of the drilling fluid systems. The drilling fluid examined here consisted of Malaysian palm oil ester derivatives (methyl laureate ester or isopropyl laureate ester) blended with commercially available synthetic mineral oil. This mineral oil was added to reduce the problem of alkaline hydrolysis. This mixture, however, was found to be unstable and could not solve the problem at high temperature. The isopropyl laureate and mineral oil blended system was more stable towards the hydrolysis process up to 250 degrees F. In order to enhance the performance of an invert emulsion drilling fluid system, it was recommended that brine water content of the fluid system be lowered. 3 refs., 2 figs.

  7. The application of SEM in analyzing the damage to the petroleum reservoirs caused by drilling fluids

    International Nuclear Information System (INIS)

    Abdul Razak Ismail

    1996-01-01

    An experimental study has been conducted to analyze the damage to the potential oil and gas reservoirs due to the invasion of drilling fluid during drilling operation. Two types of rock samples representing low and high permeability were used to stimulate the petroleum reservoirs. Sea water based drilling fluids were used in this study. Detail observations to the rock samples were analyzed using scanning electron microscope (SEM). The results of both permeability restoration and SEM observation showed that severe permeability impairments were obtained for high permeability rock. These results indicate that the relative size of the barite particles and the pore size distribution and characteristics of the formation play an important role in determining the damage caused by the drilling fluids

  8. Waste drilling-fluid-utilising microorganisms in a tropical mangrove swamp oilfield location

    International Nuclear Information System (INIS)

    Benka-Coker, M.O.; Olumagin, A.

    1995-01-01

    Waste drilling-fluid-utilising microorganisms were isolated from drilling-mud cuttings, soil and creek water from a mangrove swamp oilfield location in the Delta area of Nigeria using waste drilling-fluid as the substrate. Eighteen bacterial isolates obtained were identified as species of Staphylococcus, Acinetobacter, Alcaligenes, Serratia, Clostridium, Enterobacter, Klebsiella, Nocardia, Bacillus, Actinomyces, Micrococcus and Pseudomonas, while the genera of fungi isolated were Penicillium, Cladosporium and Fusarium. Even though drilling-fluid-utilising genera were in higher numbers in the soil than in the two other sources examined, the percentages of the total heterotrophic bacteria that utilised waste drilling-fluid were 6.02 in the drilling-mud cuttings, 0.83 in creek water and 0.42 in soil. The screen tests for biodegradation potential of the bacterial isolates showed that, even though all the isolates were able to degrade and utilise the waste fluid for growth, species of Alcaligenes and Micrococcus were more active degraders of the waste. The significance of the results in environmental management in oil-producing areas of Nigeria is discussed. (Author)

  9. Waste drilling-fluid-utilising microorganisms in a tropical mangrove swamp oilfield location

    Energy Technology Data Exchange (ETDEWEB)

    Benka-Coker, M.O.; Olumagin, A. [Benin Univ. (Nigeria). Dept. of Microbiology

    1995-12-31

    Waste drilling-fluid-utilising microorganisms were isolated from drilling-mud cuttings, soil and creek water from a mangrove swamp oilfield location in the Delta area of Nigeria using waste drilling-fluid as the substrate. Eighteen bacterial isolates obtained were identified as species of Staphylococcus, Acinetobacter, Alcaligenes, Serratia, Clostridium, Enterobacter, Klebsiella, Nocardia, Bacillus, Actinomyces, Micrococcus and Pseudomonas, while the genera of fungi isolated were Penicillium, Cladosporium and Fusarium. Even though drilling-fluid-utilising genera were in higher numbers in the soil than in the two other sources examined, the percentages of the total heterotrophic bacteria that utilised waste drilling-fluid were 6.02 in the drilling-mud cuttings, 0.83 in creek water and 0.42 in soil. The screen tests for biodegradation potential of the bacterial isolates showed that, even though all the isolates were able to degrade and utilise the waste fluid for growth, species of Alcaligenes and Micrococcus were more active degraders of the waste. The significance of the results in environmental management in oil-producing areas of Nigeria is discussed. (Author)

  10. New generation of membrane efficient water-based drilling fluids: pragmatic and cost-effective solutions to borehole stability problems

    Energy Technology Data Exchange (ETDEWEB)

    Tare, U.A. [Haliburton, Calgary, AB (Canada); Mody, F.K. [Shell International E and P Inc., Calgary, AB (Canada); Tan, C.P. [CSIRO Petroleum, Kensington, WA (Australia)

    2002-06-01

    Drilling and completion operations in shales often suffer as a result of wellbore instability. Mechanical failure of the rock around a wellbore is the primary cause of shale instability. This process can be exacerbated by physico-chemical interactions between drilling fluids and shales. Water-based drilling fluids are used more and more due to environmental awareness that becomes more prevalent. Wellbore instability problems can however result from an improper application of water-based drilling fluids in those cases where drilling occurs in sensitive clay-rich formations. To meet the requirements of the petroleum industry, considerable collaborative efforts were expanded in the development of innovative environmentally acceptable water-based drilling fluids. In this paper, the authors describe the process that leads to the development of these drilling fluids. It is possible to achieve shale stability through an osmotic outflow of pore fluid and prevention/minimization of mud pressure penetration, as laboratory experiments on shale samples under realistic downhole conditions exposed to these drilling fluids prove. High membrane efficiencies, in excess of 80 per cent, were generated by this new generation of membrane efficient water-based drilling fluids. Drilling objectives resulting from an improved application of water-based drilling fluids are made possible by a fundamental understanding of the main drilling fluid-shale interaction mechanisms for shale stability and the application of experimental data to field conditions. The authors indicate that the achievement of trouble-free drilling of shales and notable reductions in non-productive time is accomplished by following the practical guidelines included in this paper for maintaining shale stability with the new generation of water-based drilling fluids. 8 refs., 2 tabs., 4 figs.

  11. Development of drilling fluids based on polysaccharides and natural minerals

    Directory of Open Access Journals (Sweden)

    Zhanar Nurakhmetova

    2016-03-01

    Full Text Available The technology of oil well drilling in complex geological conditions by applying the drilling muds based on the polysaccharides – gellan, xanthan and their mixture which potentially possess a good flocculation properties and the ability to reversible sol-gel transition in dependence of temperature and concentration of low molecular weight cations in water has been justified in this work. For the preparation of drilling muds, gellan and xanthan were used, these polymers were obtained from biomass by an aerobic fermentation using microorganisms Sphingomonas elodea and Xanthomonas campestris. Bentonite was used as a natural mineral. Physical and chemical characteristics of aqueous and aqueous-salt solutions of natural polysaccharide gellan including: density, intrinsic and effective viscosity, static shear stress, dynamic shear stress, sedimentation stability and other parameters were determined while varying polymer compositions and concentrations, ionic strength of the solution, nature of low molecular weight salts, concentration of dispersion phase, pH of the medium and temperature.

  12. Synthetic-based fluid replacement: excellent drilling efficiency and imaging evaluation achieved with inhibitive water-based fluid

    Energy Technology Data Exchange (ETDEWEB)

    Mendonca, Ricardo; Fernandez, Jovan Andrade [PETROBRAS, Rio de Janeiro, RJ (Brazil); Anderson, Tom; Loureiro, Mario; Pereira, Alex; Shah, Fayyaz [Halliburton Baroid, Aracaju, SE (Brazil)

    2004-07-01

    The highly reactive Calumbi shale is encountered in wells drilled by PETROBRAS in the Sergipe area. Normally an invert emulsion fluid would be used. However, the ability to run high resolution imaging logs was crucial to determining the potential of the offshore Sergipe fields, and these tools work best in water-based fluids. PETROBRAS selected a new high performance water-based fluid (WBF) to drill the Poco 3-GA-73-SES well. The fluid selection was based on the results of X-ray diffraction, dispersion/erosion and linear swell meter testing of Calumbi formation samples. The new WBF incorporates a unique polymer chemistry that can provide shale inhibition very similar to that achieved with an invert emulsion fluid, without sacrificing drilling performance. The polymeric additives can effectively flocculate and encapsulate colloidal drill solids so that they can be easily removed mechanically. The polymers also help prevent hole erosion and bit balling. After the high-performance WBF was used, the following results were obtained on the Poco 3- GA-73-SES well: 805 m drilled in 65 hr (12.65 m/hr) in a single bit run; trips completed with minimal use of the pumps or back reaming, considered exceptional for a WBF while drilling the Calumbi shale; imaging logs run successfully with no delays or obstructions while tripping or logging; the average hole diameter was 8.63-in. per the caliper log for the 8 1/2-in. section; no accretion on the bit or drill string observed; no flow line plugging or shaker screen blinding. (author)

  13. Combined Effect of Pressure and Temperature on the Viscous Behaviour of All-Oil Drilling Fluids

    Directory of Open Access Journals (Sweden)

    Hermoso J.

    2014-12-01

    Full Text Available The overall objective of this research was to study the combined influence of pressure and temperature on the complex viscous behaviour of two oil-based drilling fluids. The oil-based fluids were formulated by dispersing selected organobentonites in mineral oil, using a high-shear mixer, at room temperature. Drilling fluid viscous flow characterization was performed with a controlled-stress rheometer, using both conventional coaxial cylinder and non-conventional geometries for High Pressure/High Temperature (HPHT measurements. The rheological data obtained confirm that a helical ribbon geometry is a very useful tool to characterise the complex viscous flow behaviour of these fluids under extreme conditions. The different viscous flow behaviours encountered for both all-oil drilling fluids, as a function of temperature, are related to changes in polymer-oil pair solvency and oil viscosity. Hence, the resulting structures have been principally attributed to changes in the effective volume fraction of disperse phase due to thermally induced processes. Bingham’s and Herschel-Bulkley’s models describe the rheological properties of these drilling fluids, at different pressures and temperatures, fairly well. It was found that Herschel-Bulkley’s model fits much better B34-based oil drilling fluid viscous flow behaviour under HPHT conditions. Yield stress values increase linearly with pressure in the range of temperature studied. The pressure influence on yielding behaviour has been associated with the compression effect of different resulting organoclay microstructures. A factorial WLF-Barus model fitted the combined effect of temperature and pressure on the plastic viscosity of both drilling fluids fairly well, being this effect mainly influenced by the piezo-viscous properties of the continuous phase.

  14. Development and evaluation of a meter for measuring return line fluid flow rates during drilling

    Energy Technology Data Exchange (ETDEWEB)

    Loeppke, G.E.; Schafer, D.M.; Glowka, D.A.; Scott, D.D.; Wernig, M.D. (Sandia National Labs., Albuquerque, NM (United States)); Wright, E.K. (Ktech Corp., Albuquerque, NM (United States))

    1992-06-01

    The most costly problem routinely encountered in geothermal drilling is lost circulation, which occurs when drilling fluid is lost to the formation rather than circulating back to the surface. The successful and economical treatment of lost circulation requires the accurate measurement of drilling fluid flow rate both into and out of the well. This report documents the development of a meter for measuring drilling fluid outflow rates in the return line of a drilling rig. The meter employs a rolling counterbalanced float that rides on the surface of the fluid in the return line. The angle of the float pivot arm is sensed with a pendulum potentiometer, and the height of the float is calculated from this measurement. The float height is closely related to the fluid height and, therefore, the flow rate in the line. The prototype rolling float meter was extensively tested under laboratory conditions in the Wellbore Hydraulics Flow Facility; results from these tests were used in the design of the field prototype rolling float meter. The field prototype meter was tested under actual drilling conditions in August and September 1991 at the Long Valley Exploratory Well near Mammoth Lakes, Ca. In addition, the performance of several other commercially available inflow and outflow meters was evaluated in the field. The tested inflow meters included conventional pump stroke counters, rotary pump speed counters, magnetic flowmeters, and an ultrasonic Doppler flowmeter. On the return flow line, a standard paddlemeter, an acoustic level meter, and the prototype rolling float meter were evaluated for measuring drilling fluid outflow rates.

  15. A Comprehensive Prediction Model of Hydraulic Extended-Reach Limit Considering the Allowable Range of Drilling Fluid Flow Rate in Horizontal Drilling.

    Science.gov (United States)

    Li, Xin; Gao, Deli; Chen, Xuyue

    2017-06-08

    Hydraulic extended-reach limit (HERL) model of horizontal extended-reach well (ERW) can predict the maximum measured depth (MMD) of the horizontal ERW. The HERL refers to the well's MMD when drilling fluid cannot be normally circulated by drilling pump. Previous model analyzed the following two constraint conditions, drilling pump rated pressure and rated power. However, effects of the allowable range of drilling fluid flow rate (Q min  ≤ Q ≤ Q max ) were not considered. In this study, three cases of HERL model are proposed according to the relationship between allowable range of drilling fluid flow rate and rated flow rate of drilling pump (Q r ). A horizontal ERW is analyzed to predict its HERL, especially its horizontal-section limit (L h ). Results show that when Q min  ≤ Q r  ≤ Q max (Case I), L h depends both on horizontal-section limit based on rated pump pressure (L h1 ) and horizontal-section limit based on rated pump power (L h2 ); when Q min  drilling fluid flow rate, while L h2 keeps decreasing as the drilling fluid flow rate increases. The comprehensive model provides a more accurate prediction on HERL.

  16. WETTABILITY AND PREDICTION OF OIL RECOVERY FROM RESERVOIRS DEVELOPED WITH MODERN DRILLING AND COMPLETION FLUIDS

    Energy Technology Data Exchange (ETDEWEB)

    Jill S. Buckley; Norman R. Morrow

    2006-01-01

    The objectives of this project are: (1) to improve understanding of the wettability alteration of mixed-wet rocks that results from contact with the components of synthetic oil-based drilling and completion fluids formulated to meet the needs of arctic drilling; (2) to investigate cleaning methods to reverse the wettability alteration of mixed-wet cores caused by contact with these SBM components; and (3) to develop new approaches to restoration of wetting that will permit the use of cores drilled with SBM formulations for valid studies of reservoir properties.

  17. Hydrodynamics of the Fluid Filtrate on Drilling-In

    Science.gov (United States)

    Abbasov, É. M.; Agaeva, N. A.

    2014-01-01

    The volume of the liquid penetrating into the formation after drilling-in has been determined on the basis of theoretical investigations. The dynamics of change in the bottom-hole pressure has been determined in this process. It has been shown that because of the water hammer, the bottom-hole pressure can be doubled in the presence of large fractures and pores closer to the well-bottom zone.

  18. Well successfully drilled with high performance water-based fluid: Santos Basins, offshore Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Fornasier, Frank C.; Luzardo, Juan P. [Halliburton Company, Houston, TX (United States); Bishnoi, M.L. [Oil and Natural Gas Corporation Ltda. (ONGC), Dehradun (India)

    2012-07-01

    Santos Basin is a 352,260 square kilometers (136,010 sq mi) offshore pre-salt basin. It is located in the South Atlantic Ocean, some 300 kilometers (190 mi) South East of Sao Paulo, Brazil. One of the largest Brazilian sedimentary basins, it is the site of several recent significant oil fields, including Tupi and Jupiter. The criteria for drilling fluid selection is based upon the following factors: maximum cost efficiency, environmental friendliness, optimum borehole stability, and ease of use. The recommended drilling fluid formulation takes into consideration the experience gained during the drilling of wells in the Santos Basin area. The operator wanted to use a high-performance water-based fluid (HPWBF) that could provide shale inhibition, wellbore stability, lubricity and improved rate of penetration (ROP) as an alternative to synthetic-based drilling fluids to present value in terms of economics and environmental friendliness. The HPWBF consists of three synergistic products: a hydration suppressant, a dispersion suppressant, and an accretion suppressant. The system is formulated based on customized solutions for managing the clay reactivity. High logistics costs require drilling fluids that can be prepared with sea water and discharged to the sea without environmental impact. The HPWBF is a clay-free system designed for maximum shale inhibition in highly reactive formations. The system can provide wellbore stability, high rates of penetration, and acceptable rheological properties over a wide range of temperatures, with the added benefit of allowing cuttings discharge based upon water base environmental restrictions. Since no oil is used in the formulation, the HPWBF eliminates the need for cuttings processing and monitoring equipment, and exceeds the environmental requirements by achieving an LC50 value of 345,478.22 ppm in comparison with the minimum requirement (LC50 > 30,000 ppm in 96 hr), permitting use and discharge to the sea. The HPWBF selected

  19. Towards the design of new and improved drilling fluid additives using molecular dynamics simulations

    International Nuclear Information System (INIS)

    Anderson, Richard L.; Greenwel, H. Christopher; Suter, James L.; Coveney, Peter V.; Jarvis, Rebecca M.

    2010-01-01

    During exploration for oil and gas, a technical drilling fluid is used to lubricate the drill bit, maintain hydrostatic pressure, transmit sensor readings, remove rock cuttings and inhibit swelling of unstable clay based reactive shale formations. Increasing environmental awareness and resulting legislation has led to the search for new, improved biodegradable drilling fluid components. In the case of additives for clay swelling inhibition, an understanding of how existing effective additives interact with clays must be gained to allow the design of improved molecules. Owing to the disordered nature and nano scope dimension of the interlayer pores of clay minerals, computer simulations have become an increasingly useful tool for studying clay-swelling inhibitor interactions. In this work we briefly review the history of the development of technical drilling fluids, the environmental impact of drilling fluids and the use of computer simulations to study the interactions between clay minerals and swelling inhibitors. We report on results from some recent large-scale molecular dynamics simulation studies on low molecular weight water-soluble macromolecular inhibitor molecules. The structure and interactions of poly(propylene oxide)-diamine, poly(ethylene glycol) and poly(ethylene oxide)-diacrylate inhibitor molecules with montmorillonite clay are studied. (author)

  20. Experimental and modeling hydraulic studies of foam drilling fluid flowing through vertical smooth pipes

    Directory of Open Access Journals (Sweden)

    Amit Saxena

    2017-06-01

    Full Text Available Foam has emerged as an efficient drilling fluid for the drilling of low pressure, fractured and matured reservoirs because of its the ability to reduce formation damage, fluid loss, differential sticking etc. However the compressible nature along with its complicated rheology has made its implementation a multifaceted task. Knowledge of the hydrodynamic behavior of drilling fluid within the borehole is the key behind successful implementation of drilling job. However, little effort has been made to develop the hydrodynamic models for the foam flowing with cuttings through pipes of variable diameter. In the present study, hydrodynamics of the foam fluid was investigated through the vertical smooth pipes of different pipe diameters, with variable foam properties in a flow loop system. Effect of cutting loading on pressure drop was also studied. Thus, the present investigation estimates the differential pressure loss across the pipe. The flow loop permits foam flow through 25.4 mm, 38.1 mm and 50.8 mm diameter pipes. The smaller diameter pipes are used to replicate the annular spaces between the drill string and wellbore. The developed model determines the pressure loss along the pipe and the results are compared with a number of existing models. The developed model is able to predict the experimental results more accurately.

  1. Field test to assess the effects of drilling fluids on groundwater chemistry collected from Columbia River basalts

    International Nuclear Information System (INIS)

    Graham, D.L.; Bryce, R.W.; Halko, D.J.

    1984-03-01

    The Basalt Waste Isolation Project has used water-based drilling fluids in borehole construction. Fluids begin as a mixture of Columbia River water and bentonite. Other compounds such as organic polymers, soda ash, and chromium lignosulfonate are added to attain desired fluid characteristics. A field test was conducted to assess the effects of these fluids on basaltic groundwater chemistry. A one-month hydrochemistry baseline was established for a single interlow zone in borehole DC-14. Following baseline data collection, approximately 40,000 liters of drilling fluid were injected into the interflow. Samples were collected and analyzed for anions, cations, stable and radioactive isotopes, dissolved gases, and three specific drilling fluid tracers (i.e., tritium, fluorescein, and total organic carbon), for a period of one year following injection. Nearly 8.0 million liters of fluid were removed since initiation of the test. Test results demonstrated that drilling fluid tracers are useful indicators of how well drilling fluids have been removed from a borehole. Constituents such as Na + , SO 4 -2 , and all carbon species showed increases in concentration, whereas species such as Cl - , F - , and Si demonstrated a substantial decrease in concentration as a consequence of drilling fluid injection. Stable isotope ratios of oxygen and hydrogen were insensitive to relatively small amounts ( 14 C was significantly affected by the introduction of ''live'' carbon as a result of drilling fluid injection. 8 refs., 7 figs., 2 tabs

  2. Evaluation on the Presence of Nano Silver Particle in Improving a Conventional Water-based Drilling Fluid

    Science.gov (United States)

    Husin, H.; Ahmad, N.; Jamil, N.; Chyuan, O. H.; Roslan, A.

    2018-05-01

    Worldwide demand in oil and gas energy consumption has been driving many of oil and gas companies to explore new oil and gas resource field in an ultra-deep water environment. As deeper well is drilled, more problems and challenges are expected. The successful of drilling operation is highly dependent on properties of drilling fluids. As a way to operate drilling in challenging and extreme surroundings, nanotechnology with their unique properties is employed. Due to unique physicochemical, electrical, thermal, hydrodynamic properties and exceptional interaction potential of nanomaterials, nanoparticles are considered to be the most promising material of choice for smart fluid design for oil and gas field application. Throughout this paper, the effect of nano silver particle in improving a conventional water based drilling fluid was evaluated. Results showed that nano silver gave a significant improvement to the conventional water based drilling fluid in terms of its rheological properties and filtration test performance.

  3. Synthesis of high-temperature viscosity stabilizer used in drilling fluid

    Science.gov (United States)

    Zhang, Yanna; Luo, Huaidong; Shi, Libao; Huang, Hongjun

    2018-02-01

    Abstract For a well performance drilling fluid, when it operates in deep wells under high temperature, the most important property required is the thermal stability. The drilling fluid properties under high temperature can be controlled by proper selection of viscosity stabilizer, which can capture oxygen to protect polymer agent in the drilling fluid. In this paper a viscosity stabilizer PB-854 is described, which was synthesized by 4-phenoxybutyl bromide, paraformaldehyde, and phloroglucinol using etherification method and condensation reaction. We studied the effect of catalyst dosage, temperature, time, and stirring rate on the synthetic yield. Under this condition: molar ratio of 2-tert-Butylphenol, paraformaldehyde and phloroglucinol of 2:1:2.5, reacting temperature of 100 °C, stirring rate of 100 r min-1, and mass content of catalyst of 15 %, char yield of 5-bromine-3-tert-butyl salicylaldehyde reached 86 %. Under this condition: molar ratio of 5-bromine-3-tert-butyl salicylaldehyde and phloroglucinol of 4, reacting temperature of 60 °C, reacting time of 30 min, volume content of sulphuric acid of 80 %, char yield of the target product viscosity stabilizer PB-854 is 86%. Finally, in this paper, infrared spectroscopy is adopted to analyse the structure of the synthetic product PB-854.The improvement in the stability of drilling fluid was further shown after adding the viscosity stabilizer in the common polymer drilling fluid under high temperature conditions of 120 °C ˜ 180 °C. The results show significant change in terms of fluid stability in the presence of this new stabilizer as it provides better stability.

  4. Risk to water wells of pathogens in drilling fluids[Section 7 : reviewed literature added November 2009

    Energy Technology Data Exchange (ETDEWEB)

    Abiola, A.T. [Olds College, Olds, AB (Canada); Ryan, C. [Calgary Univ., AB (Canada)

    2009-10-15

    Public concern regarding the presence of pathogens in surface waters used in drilling fluids and their potential impact on groundwater and water wells has increased in recent years. This report addressed those concerns. The most common sources of water for drilling fluids include dugouts, sloughs, small creeks and beaver dams. The Energy Resources Conservation Board commissioned a study to examine the abundance of pathogens in surface waters and to evaluate whether pathogens in surface waters that are used in drilling fluids have the ability to survive in or be transported through groundwater. The report was written for the general public and represents a professional opinion based on an extensive review of literature and professional experience. It described the risk to well water of pathogens in drilling fluids; pathogens in well water; and fate of pathogens in drilling fluids. The key findings of the report were that the subsurface of the earth presents a hostile environment to surface water pathogens. In addition to pathogen introduction from drilling fluid, pathogens can be introduced through animal waste, sewage and industrial or agricultural waste. Typically, the types of pathogens found in Alberta surface waters are not likely to survive the salt levels found in nontoxic drilling fluids. Pathogen transport into the subsurface is unlikely, even over shorter distances, because of the low infiltration distance of drilling fluids from the wellbore. 142 refs.

  5. High-tech hammer : BBJ Tools transforms the traditional fluid hammer into a revolutionary drilling tool

    Energy Technology Data Exchange (ETDEWEB)

    Byfield, M.

    2010-12-15

    This article described BBJ Tools' patent-pending fluid hammer that enhances drilling rate of penetration. The technology was awarded the 2010 winner for best drilling technology for a company with fewer than 100 employees. The fluid hammer features several improvements in terms of maintaining drill-bit integrity, steering ability, and operating flexibility. The hammer incorporates a positive displacement motor and adjustable housing that uniquely allow the driller to steer the drill bit. The fluid hammer works with both polycrystalline diamond compact bits and roller cones. The unique weight-to-bit-transfer design allows the operator to have diversified percussion control. More weight on the bit results in more force, and hammering stops when weight is taken off the bit. The major components of the mud motor are incorporated into the fluid hammer, allowing the tool to compete in every application in which a mud motor is used. The percussion mechanism transmits left-hand reactive torque to the housing. The rate of penetration is substantially better than other similar tools on the market. 2 figs.

  6. 30 CFR 250.459 - What are the safety requirements for drilling fluid-handling areas?

    Science.gov (United States)

    2010-07-01

    ... addition: (1) If natural means provide adequate ventilation, then a mechanical ventilation system is not... areas where adequate ventilation is provided by natural means. You must test and recalibrate gas... install and maintain a ventilation system and gas monitors. Drilling fluid-handling areas must have the...

  7. A novel enzyme-based acidizing system: Matrix acidizing and drilling fluid damage removal

    Energy Technology Data Exchange (ETDEWEB)

    Harris, R.E.; McKay, D.M. [Cleansorb Limited, Surrey (United Kingdom); Moses, V. [King`s College, London (United Kingdom)

    1995-12-31

    A novel acidizing process is used to increase the permeability of carbonate rock cores in the laboratory and to remove drilling fluid damage from cores and wafers. Field results show the benefits of the technology as applied both to injector and producer wells.

  8. Economic Viability of the Use of Local Pseudo-Oils for Drilling Fluid ...

    African Journals Online (AJOL)

    Michael O. Mensah

    2015-12-02

    Dec 2, 2015 ... Applications” Journal of Petroleum and Gas. Engineering, Vol. 6(4) ... productive, onshore horizontal wells in India. (Sawyer et al. ... fewer effects on benthic communities than the early generation oil ... Home-Cooking Oil (XB1000). Drilling fluids ..... mining and microbial mineral recovery and environmental.

  9. Selective-placement burial of drilling fluids: 1. Effects on soil chemical properties

    International Nuclear Information System (INIS)

    McFarland, M.L.; Hartmann, S.; Ueckert, D.N.; Hons, F.M.

    1992-01-01

    Burial of spent drilling fluids used in petroleum and natural gas exploration was evaluated for reducing soil contamination caused by conventional, surface disposal of these wastes on arid and semiarid rangelands. Simulated reserve pits at two locations provided burial depths of 30, 90 (with and without a 30-cm capillary barrier of coarse limestone), and 150 cm below the surface, with sequential replacement of stockpiled subsoil and topsoil. The drilling fluids contained extremely high concentrations of soluble salts, with Na and Cl being the dominant soluble ions. Upward migration of contaminants was evaluated over a 20-month period. Soluble salts migrated upward 15 to 30 cm into the overlying soil, and salt movement appeared to be governed to a greater extent by diffusive rather than convective flow mechanisms. Capillary barriers of coarse limestone effectively reduced salt movement at one of the two sites. Sodium, Ca, and Cl were the dominant mobile ions. Exchangeable Na percentages did not increase in soil increments > 15 cm above buried drilling wastes. Barium, Cr, Cu, Ni, and Zn in drilling fluids did not migrate into overlying soil. Movement of contaminants was similar where fourwing saltbush [Atriplex canescens (Pursh) Nutt.], a deep-rooted shrub, and buffalograss [Buchloe dactyloides (Nutt.) Engelm], a shallow-rooted grass, were used for revegetation

  10. Drilling fluids and lost circulation in hot-dry-rock geothermal wells at Fenton Hill

    Energy Technology Data Exchange (ETDEWEB)

    Nuckols, E.B.; Miles, D.; Laney, R.; Polk, G.; Friddle, H.; Simpson, G.

    1981-01-01

    Geothermal hot dry rock drilling at Fenton Hill in northern New Mexico encountered problems of catastrophic lost circulation in cavernous areas of limestones in the Sandia Formation, severe corrosion due to temperatures of up to 320/sup 0/C, and torque problems caused by 35/sup 0/ hole angle and the abrasiveness of Precambrian crystalline rock. The use of polymeric flocculated bentonite fluid, clear water, fibrous material, dry drilling, oxygen scavengers, a biodegradable lubricant mixture of modified triglicerides and alcohol, and maintenance of a high pH, were some of the approaches taken toward solving these problems.

  11. Evaluation of saponite and saponite/sepiolite fluids for geothermal drilling

    Energy Technology Data Exchange (ETDEWEB)

    Guven, N.; Panfil, D.J.; Carney, L.L. (Texas Tech Univ., Lubbock, TX (USA). Dept. of Geosciences)

    1991-02-01

    The rheology and other properties of drilling fluids containing saponite and a saponite-sepiolite mixture as the main vicosifier have been systematically evaluated in the temperature range of 300-600{degree}F under appropriate confining pressures up to 16,000 psi. Saponite represents the magnesium analog of the clay mineral montmorillonite, which is the main constituent in conventional bentonite-based fluids. The fluid with 6% saponite exhibits a prominent viscosity enhancement at temperatures above 250{degree}F. This viscosity enhancement is easily controlled by salts and hydroxides of Na and K. The addition of Na-polyacrylates (low- and high-molecular weight polymers) eliminates the viscosity anomaly of pure saponite fluids. These polymers also increase the filtration control of saponite. The anomalous viscosity enhancement of saponite is significantly reduced by the addition of sepiolite (a clay mineral with a fibrous morphology). 12 refs., 31 figs., 26 tabs.

  12. Method and apparatus for monitoring fluid flow between a borehole and the surrounding formations in the course of drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Evans, J. L.; Gehrig, G. F.; Speers, J. M.

    1985-11-19

    A method and apparatus for establishing the rate at which fluid is transferred between a borehole and the surrounding formations in the course of moving drill string upward or downward in the borehole. A bell nipple is situated at the upper portion of the borehole. While tripping, drilling fluid is circulated into the borehole and exits through an outflow port in the bell nipple. The level of drilling fluid is maintained constant at the outflow port. Meters are provided to measure inflow and outflow rates. Circuitry is provided to establish the volume rate at which the amount of drill string within the borehole changes. The outputs of the meters and rate establishing means are summed to establish the compensated rate at which fluid is transferred between the formations and the borehole. This compensated rate is compared to an alarm limit. An alarm is activated if the compensated rate exceeds the alarm limit.

  13. Computerized tomography with X-rays: an instrument in the analysis physico-chemical between formations and drilling fluids interactions

    International Nuclear Information System (INIS)

    Coelho, Marcus Vinicius Cavalcante

    1998-01-01

    In this study it is demonstrated the applicability of the Computerized Tomography technique with x-rays to evaluate the reactivity degree between various drilling fluids and argillaceous sediments (Shales and Sandstones). The research has been conducted in the Rock-Fluid Interaction Pressure Simulator (RFIPS), where the possible physico-chemical alterations can be observed through successive tomography images, which are obtained during the flow of the fluid through the samples. In addition, it was noticed the formation of mud cake in Berea Sandstones samples in the RFIPS, though the Computerized Tomography with X-rays, when utilizing drilling fluids weighted with the baryte. (author)

  14. Experimental study of improved rheology and lubricity of drilling fluids enhanced with nano-particles

    Science.gov (United States)

    Bég, O. Anwar; Espinoza, D. E. Sanchez; Kadir, Ali; Shamshuddin, MD.; Sohail, Ayesha

    2018-04-01

    An experimental study of the rheology and lubricity properties of a drilling fluid is reported, motivated by applications in highly deviated and extended reach wells. Recent developments in nanofluids have identified that the judicious injection of nano-particles into working drilling fluids may resolve a number of issues including borehole instability, lost circulation, torque and drag, pipe sticking problems, bit balling and reduction in drilling speed. The aim of this article is, therefore, to evaluate the rheological characteristics and lubricity of different nano-particles in water-based mud, with the potential to reduce costs via a decrease in drag and torque during the construction of highly deviated and ERD wells. Extensive results are presented for percentage in torque variation and coefficient of friction before and after aging. Rheology is evaluated via apparent viscosity, plastic viscosity and gel strength variation before and after aging for water-based muds (WBM). Results are included for silica and titanium nano-particles at different concentrations. These properties were measured before and after aging the mud samples at 80 °C during 16 h at static conditions. The best performance was shown with titanium nano-particles at a concentration of 0.60% (w/w) before aging.

  15. Water and clay based drilling fluids for oil wells; Fluidos hidroargilosos para perfuracao de pocos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, R.C.A. de; Amorim, L.V.; Santana, L.N. de L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)], e-mail: nalealves@hotmail.com

    2008-07-01

    In the onshore drilling of wells are commonly used aqueous fluids containing bentonite clays. However, to perform their functions generally there is the necessity of additives to drilling fluids, like viscositying, filtered reducer and lubricant. Thus, this work aims to develop water and clay base drilling fluids with low solid text, and with polymeric and lubricants additives. Were studied a sample of industrialized sodium bentonite clays, three polymeric compounds in the ternary form and a sample of lubricant, in different concentrations. Were determined the flow curves, the apparent and plastic viscosities, the yield limit and gel force in Fann 35A viscometer, the filtered volume in API filter-press and the lubricity coefficient in Ofite lubricimeter. The results showed that the fluid had pseudoplastic behavior, the polymeric additives adjusts their rheological properties and filtration and the addition of 1% of lubricant is sufficient to improve the lubricity of fluids. (author)

  16. THE APPLICATION OF LASERS IN MEASUREMENT OF FLUID FLOW THROUGH DRILLING BIT NOZZLES

    Directory of Open Access Journals (Sweden)

    Radenko Drakulić

    1993-12-01

    Full Text Available Two optical methods based on laser and video technology and digital signal and image processing techniques - Laser Doppler velocimetry (LDV and Particle image velocimetry (PIV were applied in highly accurate fluid flow measurement. Their application in jet velocity measurement of flows through drilling bit nozzles is presented. The role of nozzles in drilling technology together with procedures and tests performed on their optimization are reviewed. In addition, some experimental results for circular nozzle obtained both with LDV and PIV are elaborated. The experimental set-up and the testing procedure arc briefly discussed, as well as potential improvements in the design. Possible other applications of LDV and PIV in the domain of petroleum engineering are suggested (the paper is published in Croatian.

  17. Adsorption of dispersing polyelectrolytes: stabilization of drilling fluids; Adsorption de polyelectrolytes dispersants: stabilisation des fluides de forage

    Energy Technology Data Exchange (ETDEWEB)

    Balastre, M.

    1999-11-10

    Instabilities of concentrated colloidal suspensions are a source of many industrial problems, as in drilling fluid formulations where aggregation and severe settling phenomena can occur. Low molecular weight polyelectrolyte dispersants are used to solve these problems, but their optimal use requires a better understanding of the phenomena that are involved. After materials characterization, adsorption mechanisms of two anionic polyelectrolytes (PANa, PSSNa) on a soluble substrate model, barium sulfate powder are studied. Barium sulfate is the principal additive used to adapt the density of drilling fluids. A simple model allows us to propose a distribution of the microscopic species at the interface. Presence of divalent ions induces the formation of a strong complex with the polyelectrolyte. Adsorption and electro-kinetic data are presented and exchange equilibrium are examined in relation with the surface uptake. The binding mechanism and the surface speciation of the polymer groups are deduced from the ion exchange analysis. The macroscopic behavior of suspensions on different conditions (volume fraction, ionic strength, dispersant concentration) is studied by settling and rheological measurements. The macroscopic properties are connected to structural aspects, and we show that dispersing effects are mostly related to electro-steric repulsion. The dispersion state depends on two principal factors adsorbed amounts and adsorbed layer properties, especially the excess charge, and the molecules conformation. (author)

  18. Development and application of ZM-2 drilling fluid density adjustment mixing device

    Directory of Open Access Journals (Sweden)

    Zongming Lei

    2015-01-01

    Full Text Available High-pressure shallow (gas/water flow is often hidden in the deepwater seabed, so penetrating shallow flow in drilling without BOP will be highly risky. In this case, the conventional well killing method to balance the formation pressure with back pressure generated by well head equipment is no longer suitable. Based on the analysis of structural characteristics of domestic and foreign multi-phase mixing systems, a ZM-2 drilling fluid density adjustment mixing device with independent intellectual property right was developed according to the principles of dynamic well killing. The device is mainly composed of a throttle valve, a high-precision electromagnetic flowmeter, a mixer, dumbbell-shaped nozzles, connecting pipes and other components. Fixed on the mixer are three inlets to fill heavy mud, seawater and additives. Opposed jetting is adopted to realize rapid and uniform mixing of fluids with different densities. A laboratory test was conducted to work out the relationship between throttle opening and injection flow rate and establish a linear relationship between killing fluid density and heavy mud flow. The results of field test conducted in the Nanhai No.8 drill ship showed that the mixing device was stable in operation and excellent in mixing performance. The density difference of ingredient mixture could be controlled within 0.05 g/cm3 after the mixture flowed out of the mixing chamber of the mixer of about 0.3 m long, so such high precision can meet the requirement of dynamic well killing.

  19. Evaluation des fluides de forage HP/HT pour forages profonds Evaluation of Hp/Ht Drilling Fluid Formulations for Deep Drilling

    Directory of Open Access Journals (Sweden)

    Argillier J. F.

    2006-11-01

    nombre de boues à base d'eau. Les résultats font apparaître que la nature des composants de la formulation exerce une forte influence sur le comportement de la boue dans des conditions difficiles. Le choix approprié d'additifs, tels que viscosifiants et réducteurs de filtrat, peut limiter les risques inhérents aux conditions de forage difficiles. Deep well drilling require the development of drilling fluid formulations adapted to high formation temperatures : a major cause of problems is the thermal degradation of chemical additives used in water based formulations that often occurs while drilling high temperature wells. Such a degradation can lead to strong variations in rheological and filtration characteristics and loss of properties. Moreover, even if no degradation of components occurs, the viscosity of hydrosoluble polymer solutions commonly used in fluid formulations strongly decreases as temperature increases above 60°C (150°F. Another cause of problems that arise at high temperature when using water based muds is the gelation of clays used in the formulation. This induces a deep increase in formulation viscosity and pressure drop, in particular when setting back in operation. Different methodologies have been developed for studying the behaviour of water based muds under high pressure/high temperature conditions. They include:(1 laboratory scale experiments such as anaerobic stability of polymer solutions, rheological behaviour of clay suspensions under high pressure/high temperature conditions thus simulating gelification properties of clays at high temperature;studying drilling fluids under realistic bottom hole conditions that are temperatures up to 180°C (380°F, pressures up to 500 bar and shear rates up to 10,000 s to the power of (-1. Using this methodology different water based muds have been tested. The results show that the nature of the constituents used in the water based formulation strongly influences the mud behaviour under harsh

  20. Temperature and Pressure Effects on Drilling Fluid Rheology and ECD in Very Deep Wells

    Energy Technology Data Exchange (ETDEWEB)

    Rommetveit, R.; Bjoerkvoll, K.S.

    1997-12-31

    The rheological properties of drilling fluids are usually approximated to be independent of pressure and temperature. In many cases this is a good approximation. However, for wells with small margins between pore and fracture pressure, careful evaluations and analysis of the effects of temperature and pressure on well bore hydraulics and kick probability are needed. In this publication the effects of pressure and temperature are discussed and described for typical HPHT (High Pressure High Temperature) wells. Laboratory measurements show that rheology is very pressure and temperature dependent. The practical implications of these observations are illustrated through a series of calculations with an advanced pressure and temperature simulator. 10 refs., 15 figs.

  1. Use of hypane to treat drilling fluids at fields of the Tyumen Oblast

    Energy Technology Data Exchange (ETDEWEB)

    Radyuk, M I; Gur' yevskikh, T S; Kozubovskiy, A I

    1980-01-01

    It is recommended that hypane be used during drilling as the conductor (in concentration 0.10-0.25%) to increase viscosity of the argillaceous suspensions and reduce the consumption of clay powder, and also to obtain liquids and reduce density of fluids (in a quantity of 0.5-1.0%) in combination with purification and dilution. Hypane is used starting with depths where intensive enrichment of the circulating liquid with the argillaceous phase stops and the section is more stable (1800-2000 m for the central Ob region).

  2. A New Calculation Method of Dynamic Kill Fluid Density Variation during Deep Water Drilling

    Directory of Open Access Journals (Sweden)

    Honghai Fan

    2017-01-01

    Full Text Available There are plenty of uncertainties and enormous challenges in deep water drilling due to complicated shallow flow and deep strata of high temperature and pressure. This paper investigates density of dynamic kill fluid and optimum density during the kill operation process in which dynamic kill process can be divided into two stages, that is, dynamic stable stage and static stable stage. The dynamic kill fluid consists of a single liquid phase and different solid phases. In addition, liquid phase is a mixture of water and oil. Therefore, a new method in calculating the temperature and pressure field of deep water wellbore is proposed. The paper calculates the changing trend of kill fluid density under different temperature and pressure by means of superposition method, nonlinear regression, and segment processing technique. By employing the improved model of kill fluid density, deep water kill operation in a well is investigated. By comparison, the calculated density results are in line with the field data. The model proposed in this paper proves to be satisfactory in optimizing dynamic kill operations to ensure the safety in deep water.

  3. Towards the design of new and improved drilling fluid additives using molecular dynamics simulations

    Directory of Open Access Journals (Sweden)

    Richard L. Anderson

    2010-03-01

    Full Text Available During exploration for oil and gas, a technical drilling fluid is used to lubricate the drill bit, maintain hydrostatic pressure, transmit sensor readings, remove rock cuttings and inhibit swelling of unstable clay based reactive shale formations. Increasing environmental awareness and resulting legislation has led to the search for new, improved biodegradable drilling fluid components. In the case of additives for clay swelling inhibition, an understanding of how existing effective additives interact with clays must be gained to allow the design of improved molecules. Owing to the disordered nature and nanoscopic dimension of the interlayer pores of clay minerals, computer simulations have become an increasingly useful tool for studying clay-swelling inhibitor interactions. In this work we briefly review the history of the development of technical drilling fluids, the environmental impact of drilling fluids and the use of computer simulations to study the interactions between clay minerals and swelling inhibitors. We report on results from some recent large-scale molecular dynamics simulation studies on low molecular weight water-soluble macromolecular inhibitor molecules. The structure and interactions of poly(propylene oxide-diamine, poly(ethylene glycol and poly(ethylene oxide-diacrylate inhibitor molecules with montmorillonite clay are studied.Durante a exploração de óleo e gás um fluido de perfuração é usado para lubrificar 'bit' da perfuradora, manter a pressão hidrostática, transmitir sensores de leitura, remover resíduos da rocha e inibir o inchamento da argila instável baseada nas formações dos folhelhos. O aumento das preocupações ambientais bem como a legislação resultante levou à procura de novos fluidos de perfuração com componentes biodegradáveis. No caso dos aditivos para inibir o inchamento das argilas o entendimento das interações entre os aditivos e as argilas tem que ser adquirido para permitir o

  4. Damage evaluation on oil-based drill-in fluids for ultra-deep fractured tight sandstone gas reservoirs

    Directory of Open Access Journals (Sweden)

    Jinzhi Zhu

    2017-07-01

    Full Text Available In order to explore the damage mechanisms and improve the method to evaluate and optimize the performance of formation damage control of oil-based drill-in fluids, this paper took an ultra-deep fractured tight gas reservoir in piedmont configuration, located in the Cretaceous Bashijiqike Fm of the Tarim Basin, as an example. First, evaluation experiments were conducted on the filtrate invasion, the dynamic damage of oil-based drill-in fluids and the loading capacity of filter cakes. Meanwhile, the evaluating methods were optimized for the formation damage control effect of oil-based drill-in fluids in laboratory: pre-processing drill-in fluids before grading analysis; using the dynamic damage method to simulate the damage process for evaluating the percentage of regained permeability; and evaluating the loading capacity of filter cakes. The experimental results show that (1 oil phase trapping damage and solid phase invasion are the main formation damage types; (2 the damage degree of filtrate is the strongest on the matrix; and (3 the dynamic damage degree of oil-based drill-in fluids reaches medium strong to strong on fractures and filter cakes show a good sealing capacity for the fractures less than 100 μm. In conclusion, the filter cakes' loading capacity should be first guaranteed, and both percentage of regained permeability and liquid trapping damage degree should be both considered in the oil-based drill-in fluids prepared for those ultra-deep fractured tight sandstone gas reservoirs.

  5. Environmental implications of release of oil-based drilling fluids and oily cuttings into waters of the Canadian northwest Atlantic

    Energy Technology Data Exchange (ETDEWEB)

    Barchard, W.W.; Doe, K.G.; Mahon, S.D.; Moores, R.B.; Osborne, J.M.; Parker, W.R.

    1986-01-01

    In 1982, the Environmental Protection Service became aware that companies conducting petroleum exploration in the waters of eastern Canada would request permission to use and discharge oil-based drilling fluids and/or drill cuttings contaminated with oil-based drilling fluids. It was determined from an evaluation of North Sea data that aspects of the toxicity of oil-based drilling fluids should be evaluated using techniques applicable to Canadian marine conditions. Although it is unlikely that permission will be granted to dispose of whole oil-based muds into the ocean, whole mud formulations were tested as a close approximation to the mixture which would adhere to discharged drilling cuttings. Test organisms were exposed to whole muds as an approximation of the worst possible exposure regime. Static bioassays (96-hour) were conducted using threespine stickleback (Gasterosteus aculeatus). In general, high pH and the inclusion of certain emulsifiers seemed to contribute greatly to the lethality of the whole muds. Diesel oil-based muds were more acutely toxic than those formulated with alternate base oils which were virtually non-acutely toxic. Acute, sublethal and long-term studies were also conducted only on drill cuttings contaminated with alternate base oil muds. These more closely reflect proposed discharge strategies. Although 96-hour exposures resulted in no mortality, longer-term exposures (four to thirty-two days) resulted in significant behavioural changes and/or mortality to Macoma balthica, Strongylocentrotus droebachiensis, larval Homarus americanus and Nephthys caeca. The results suggest that use of alternate oil-based drilling fluids will have an effect on the marine environment intermediate between water-based muds and diesel oil-based muds. 73 refs., 6 figs., 18 tabs.

  6. Drilling unit

    Energy Technology Data Exchange (ETDEWEB)

    Umanchik, N P; Demin, A V; Khrustalev, N N; Linnik, G N; Lovchev, S V; Rozin, M M; Sidorov, R V; Sokolov, S I; Tsaregradskiy, Yu P

    1981-01-01

    A drilling unit is proposed which includes a hydraulic lifter, hydraulic multiple-cylinder pump with valve distribution and sectional drilling pump with separators of the working and flushing fluid. In order to reduce metal consumption and the overall dimensions of the drilling unit, the working cavity of each cylinder of the hydraulic multiple-cylinder pump is equipped with suction and injection valves and is hydraulically connected to the working cavity by one of the sections of the drilling pump.

  7. A Transient Analytical Model for Predicting Wellbore/Reservoir Temperature and Stresses during Drilling with Fluid Circulation

    Directory of Open Access Journals (Sweden)

    Bisheng Wu

    2017-12-01

    Full Text Available Accurate characterization of heat transfer in a wellbore during drilling, which includes fluid circulation, is important for wellbore stability analysis. In this work, a pseudo-3D model is developed to simultaneously calculate the heat exchange between the flowing fluid and the surrounding media (drill pipe and rock formation and the in-plane thermoelastic stresses. The cold drilling fluid descends through the drill pipe at constant injection rates and returns to the ground surface via the annulus. The fluid circulation will decrease the wellbore bottom temperature and reduce the near-wellbore high compressive stress, potentially leading to tensile fracturing of the well. The governing equations for the coupled heat transfer stress problem are formulated to ensure that the most important parameters are taken into account. The wellbore is subject to a non-hydrostatic in situ far-field stress field. In modeling heat exchange between fluid and surrounding media, the heat transfer coefficients are dependent on fluid properties and flow behavior. Analytical solutions in the Laplace space are obtained for the temperatures of the fluid in both the drill pipe and annulus and for the temperature and stress changes in the formation. The numerical results in the time domain are obtained by using an efficient inversion approach. In particular, the near-well stresses are compared for the cases with fixed and time-dependent cooling wellbore conditions. This comparison indicates that the using a fixed temperature wellbore conditions may over-estimate or under-estimate the bottom-hole stress change, potentially leading to wellbore stability problems.

  8. Casing drilling

    Energy Technology Data Exchange (ETDEWEB)

    Heenan, D. [Tesco Corp., Calgary, AB (Canada)

    2003-07-01

    This paper reviewed the experience that Tesco has gained by drilling several wells using only casings as the drill stem. Tesco has manufactured a mobile and compact hydraulic drilling rig called the Casing Drilling {sup TM} system. The system could be very effective and efficient for exploration and development of coalbed methane (CBM) reserves which typically require extensive coring. Continuous coring while drilling ahead, along wire line retrieval, can offer time savings and quick core recovery of large diameter core which is typically required for exploration core desorption tests. The proposed system may also have the potential to core or drill typically tight gas sands or underbalanced wells with air or foam. This would reduce drilling fluid damage while simultaneously finding gas. Compared to conventional drill pipes, Casing Drilling {sup TM} could also be effective with water production from shallow sands because of the smaller annual clearance which requires less air volumes to lift any produced water. 9 figs.

  9. Health hazard evaluation report HETA 92-0361-2343, M-I Drilling Fluids, Greybull, Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Van Gilder, T.J.; Robinson, L.

    1993-08-01

    In response to a request from the state epidemiologist in Wyoming, an investigation was begun of two cases of acute, febrile hepatitis in employees of M-I Drilling Fluids (SIC-1459), Greybull, Wyoming. The two cases of hepatitis were caused by Coxiella-burnetii, the rickettsia which causes Q-fever. A survey of 39 workers using a self-administered questionnaire and a blood test revealed seven workers with serologic evidence of infection. Three showed evidence of recent infection and four showed evidence of past infection. The major risk factor identified through the questionnaire data was sheep ownership. Risk factors suggestive of either recent or past infection included working outdoors, operating heavy equipment, and hunting.

  10. Effect of Nitric Acid on the Low Fluorescing Performance of Drilling Fluid Lubricant Based Animal and Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Feng-shan Zhou

    2013-01-01

    Full Text Available After synthesis of mixed fatty acid triethanolamine ester surfactant based on animal and vegetable mixed oils, the reaction solution was added into 4% (wt/wt liquid nitric acid or 9% (wt/wt solid nitric acid as eliminating fluorescent agent continuing to react from 1 to 2 hours. The low fluorescence lubricant named E167 for drilling fluid was prepared, in which maximum fluorescence intensity (Fmax was less than 10 in three-dimensional fluorescence spectra of excitation wavelength range. When the E167 was added into fresh water based drilling fluid at the dosage of 0.5% (wt/wt, the sticking coefficient reduced rate (ΔKf is 78% and the extreme pressure (E-P friction coefficient reduced rate (Δf is 79%. In the case of 4% brine mud with 0.5% (wt/wt E167 in it, the ΔKf and Δf are 75% and 62%, respectively. After the hot rolling ageing test 180°C × 16 h with the E167 was added into fresh water based drilling fluid at the dosage of 1% (wt/wt, the ΔKf and Δf are greater than 70%, which shows a much better lubrication properties of strong resistance to high temperature. The fresh water based drilling fluid which contains 1% (wt/wt E167 is almost nonfoaming even after hot rolling ageing 120°C × 16 h.

  11. Soil and plant response to used potassium silicate drilling fluid application.

    Science.gov (United States)

    Yao, Linjun; Anne Naeth, M

    2015-10-01

    Use of drilling waste generated from the oil and gas industry for land reclamation has potential to be a practical and economical means to improve soil fertility and to decrease landfills. A four month greenhouse experiment with common barley (Hordeum vulgare L.) on three different textured soils was conducted to determine soil and plant response to incorporated or sprayed potassium silicate drilling fluid (PSDF). Two PSDF types (used once, used twice) were applied at six rates (10, 20, 30, 40, 60, 120m(3)ha(-1)) as twelve PSDF amendments plus a control (non PSDF). Effects of PSDF amendment on plant properties were significant, and varied through physiological growth stages. Barley emergence and below ground biomass were greater with used once than used twice PSDF at the same application rate in clay loam soil. Used twice PSDF at highest rates significantly increased barley above ground biomass relative to the control in loam and sand soil. All PSDF treatments significantly increased available potassium relative to the control in all three soils. Soil electrical conductivity and sodium adsorption ratio increased with PSDF addition, but not to levels detrimental to barley. Soil quality rated fair to poor with PSDF amendments in clay loam, and reduced plant performance at the highest rate, suggesting a threshold beyond which conditions are compromised with PSDF utilization. PSDF application method did not significantly affect plant and soil responses. This initial greenhouse research demonstrates that PSDF has potential as a soil amendment for reclamation, with consideration of soil properties and plant species tolerances to determine PSDF types and rates to be used. Copyright © 2015 Elsevier Inc. All rights reserved.

  12. Development of new additive for drilling fluid from the partial hydrophobization N,N,N-trimethyl chitosan (TMC)

    International Nuclear Information System (INIS)

    Carmo, Thacyla C. do; Lopes, Grazielle; Silva, Joaquim F.M. da; Nascimento, Regina S.V.

    2009-01-01

    N,N,N-trimethyl chitosan (TMC) hydrophobically modified can act as an excellent additive for drilling fluids water based, working as inhibitor of reactive shales and rheological modifiers. The cationic chitosan was obtained by reaction of chitosan with CH 3 I in N-methyl-2-pyrrolidone to obtain the TMC and chitosan was also hydrophobically modified with palmitoil chloride to get Quit P. Through another route, Quit P was modified to obtain the cationic TMCP. The derivatives were characterized by FT-IR and 1 HNMR spectrophotometry allowing the calculation of the degree of quaternization of the TMC. The rheology tests showed that the system with TMCP presented pseudo plastic behavior, while the system with TMC behaved as a Newtonian fluid. The results indicated that TMCP can act as rheology modifier for water-based drilling fluids. (author)

  13. Drilling trends in the nineties

    International Nuclear Information System (INIS)

    1993-01-01

    At a conference on various aspects of well drilling in the 1990s, papers were presented on drilling waste management, well completion and workovers, drilling fluids, drilling rig equipment and design, drilling mechanics, drill stem testing and materials, cementing, business management, health and safety, environmental issues, and directional drilling technology. Separate abstracts have been prepared for 46 papers from this conference

  14. Water drilling fluids: evaluation of lubricity and clay swelling control; Fluidos de perfuracao a base de agua: avaliacao de lubricidade e controle de inchamento de argilas

    Energy Technology Data Exchange (ETDEWEB)

    Felix, Thiago de Freitas; Arruda, Jefferson Teixeira; Medeiros, Ana Catarina; Garcia, Rosangela Balaban [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    During the oil well drilling, drilling fluids are used in order to transport the cuttings until the surface. This fluid is also responsible for the mechanical sustentation of the well walls, the control of undesirable production of fluids in the formation, the lubricity and the cooling of the bit. The drilling fluids based on water are extensively applied due to their lower cost, thermal stability, biodegradability, easiness of pumping and treatment, resulting in smaller environmental impacts. However, some situations, such as hydrophilic shale drilling, request the use of additives to avoid the hydration of them and, consequently, the tool imprisonment or migration (filtration) of the drilling fluids into the rock. The goal of this work was to develop and test formulations of water-base drilling fluids with high capacity of inhibition of clay swelling and lubricity, obtaining drillings with larger penetration rate and calipers without enlargements. The results showed that the appropriate combination of commonly used commercial products can promote the obtaining of fluids with equal or better performance than those used by world companies. (author)

  15. Effects of waste drilling fluid on bacterial isolates from a mangrove swamp oilfield location in the Niger delta of Nigeria

    International Nuclear Information System (INIS)

    Benka-Coker, M.O.; Olumagin, A.

    1996-01-01

    Four bacteria strains isolated from a mangrove swamp oilfield location in the Niger Delta of Nigeria were cultured aerobically in the presence of 1.0% waste drilling fluid, to determine the effect of the waste on their growth. A 2-h lag phase of growth was produced by the waste in cultures of Micrococcus and Pseudomonas species, while the waste increased the lag phases of Alcaligenes and Staphylococcus species to 4 h. The exponential phase of growth of Pseudomonas sp. was depressed by the waste drilling fluid but fluid stimulated the exponential phases of Micrococcus and Alcaligenes spp. There was enhancement of the growth rate of Alcaligenes and Micrococcus spp. while those of Staphylococcus and Pseudonomas spp. were decreased. The depressed growth rates of Staphylococcus and Pseudonomas spp. in the presence of the waste drilling fluid might lead to a decrease in their contribution to the removal of the waste from the environment during spillage or disposal and, therefore, may result in an accumulation of the waste in the environment. (author)

  16. Effects of waste drilling fluid on bacterial isolates from a mangrove swamp oilfield location in the Niger delta of Nigeria

    Energy Technology Data Exchange (ETDEWEB)

    Benka-Coker, M.O.; Olumagin, A. [Benin Univ. (Nigeria). Dept. of Microbiology

    1996-03-01

    Four bacteria strains isolated from a mangrove swamp oilfield location in the Niger Delta of Nigeria were cultured aerobically in the presence of 1.0% waste drilling fluid, to determine the effect of the waste on their growth. A 2-h lag phase of growth was produced by the waste in cultures of Micrococcus and Pseudomonas species, while the waste increased the lag phases of Alcaligenes and Staphylococcus species to 4 h. The exponential phase of growth of Pseudomonas sp. was depressed by the waste drilling fluid but fluid stimulated the exponential phases of Micrococcus and Alcaligenes spp. There was enhancement of the growth rate of Alcaligenes and Micrococcus spp. while those of Staphylococcus and Pseudonomas spp. were decreased. The depressed growth rates of Staphylococcus and Pseudonomas spp. in the presence of the waste drilling fluid might lead to a decrease in their contribution to the removal of the waste from the environment during spillage or disposal and, therefore, may result in an accumulation of the waste in the environment. (author)

  17. The fluid–solid coupling analysis of screw conveyor in drilling fluid centrifuge based on ANSYS

    Directory of Open Access Journals (Sweden)

    Hongbin Liu

    2015-09-01

    Full Text Available In the centrifugal separations of drilling fluid, screw conveyor is a critical component to push and separate the sediment. The work performance and structural parameters of conveyor are immediately related to the production capability, the working life and the separating effect of the centrifuge. The existing researches always use the theoretical calculation of the approximate loads to analyze the strength of conveyor, and it cannot reflect the stress situations accurately. In order to ensure the precise mastery of the working performance, this article obtained pressure distribution under working conditions from CFX evaluation and gained equivalent stress and deformation under several load conditions by using the ANSYS Workbench platform to check the strength of conveyor. The results showed that the influence of centrifugal hydraulic pressure was less than that of centrifugal force on the strength and deformation of conveyor. Besides, the maximum equivalent stress occurred at the inside of the feed opening, while the maximum deformation occurred at the conveyor blade edge of taper extremity. Furthermore, whether considered the feed opening or not, the computing model had a great influence on the analysis results, and the simplified loads had a great influence on the deformation analysis results. The methods and results from this article can provide reference for the design and the improvement of screw conveyor.

  18. LABORATORY EVALUATION OF CALCIUM CARBONATE PARTICLE SIZE SELECTION FOR DRILL-IN FLUIDS

    OpenAIRE

    Nediljka Gaurina-Međimurec

    2002-01-01

    The technological development in horizontal, re-entry and multilateral wells require drilling and completion the reservoir sections of a well including as little damage as possible. The trends towards open hole completion places additional emphasis on formation damage avoidance. One of critical factors in avoiding formation damage during drilling is obtaining surface bridging on the formation face with minimum indepth solids penetration. In case of overbalanced drilling, this can be donme by ...

  19. Purification of bentonitics of the city Cubati-PB to obtaining organoclays for use in oil-based drilling fluids

    International Nuclear Information System (INIS)

    Costa, J.M.R.; Vitorino, I.J.F.; Silva, I.A.; Neves, G.A.; Ferreira, H.C.

    2011-01-01

    In Boa Vista, PB, are located deposits of bentonite clays commonly used in the preparation of drilling fluids. The disorderly exploitation of the deposits of Boa Vista is causing the depletion of these clays, which will cause a very serious problem for the national oil industry. This work aims to characterize new deposits of bentonite clays Cubati, PB, for the development of organoclay from its refining using a hydrocyclone for use in oil based drilling fluids. The characterization of samples of the clays was performed through the techniques: AG, XRD, EDX, TGA and DTA. The characterization is typical of bentonite for the purification process was determined the best configuration of the hydrocyclone, and the environment organic diesel fuel, the best affinity was obtained with clays organophilizated with surfactant Praepagen WB. (author)

  20. Study of smectite clays of the city Pedra Lavrada - PB for use in water-based drilling fluids

    International Nuclear Information System (INIS)

    Silva, I.A. da; Costa, J.M.R.; Cardoso, M.A.F.; Neves, G.A.; Ferreira, H.C.

    2011-01-01

    Paraiba has large reserves of bentonite clays, with the largest deposits in Boa Vista, PB. Recently new deposits were discovered in the cities of Cubati and Pedra Lavrada-PB, creating great expectations for further expansion of reserves for industrial production. The aim of this work is the study of smectite clays from the city of Pedra Lavrada, PB for use in drilling fluids water based. The characterization was made by the diffraction of laser (AG), thermogravimetric and differential thermal analysis (TGA and DTA), chemical composition by X-ray fluorescence (EDX), X-ray diffraction (XRD), exchange capacity of cations (ECC) and surface area (SA). The results obtained so far showed that the samples presented at its mineral composition smectite, kaolinite and quartz. In relation to rheological properties showed that the bentonite clay sample Dark presents promising features for use in water based drilling fluids. (author)

  1. Organophilization of bentonite clays with non-ionic surfactants aiming their use in drilling fluids base oil

    International Nuclear Information System (INIS)

    Silva, I.A.; Costa, J.M.R.; Neves, G.A.; Ferreira, H.C.; Ferreira, H.S.

    2010-01-01

    The use of nonionic surfactants has been replacing the traditional ionic surfactants among others by its high potential for resistance to thermal degradation. This work aims at the development of organoclay by the addition of nonionic surfactants for use in drilling fluids for oil wells based oil. The bentonite clay was organophilized and then characterized by X-ray diffraction and swelling Foster, seeking the most appropriate choice of surfactant to liquid organic dispersing media: ester, diesel and paraffin. With the obtained dispersions were measured apparent viscosities and plastic. The results showed that incorporation of surfactants used in the clay interlayer spacing increased significantly and that the dispersions showed rheological properties within the specifications of PETROBRAS, for the use of organophilic clays in drilling fluids in a non-aqueous base. (author)

  2. Laboratory exposures of invertebrate and vertebrate species to concentrations of IA-35 (Petro-Canada) drill mud fluid, production water, and Hibernia mud cuttings

    Energy Technology Data Exchange (ETDEWEB)

    Payne, J.; Fancey, L.; Andrews, C.; Meade, J.; Power, F.; Veinot, G. [Department of Fisheries and Oceans, St. John' s, NF (Canada). Science Branch; Lee, K. [Department of Fisheries and Oceans, Mont-Joli, PQ (Canada). Maurice Lamontagne Inst.; Cook, A. [Environment Canada, Moncton, NB (Canada). Environmental Quality Laboratory

    2001-04-01

    The authors studied the short term effects on brine shrimp nauplii (Artemia franciscana), capelin larvae (Mallotus villosus), marine copepods (Calanus finmarchicus), juvenile yellowtail flounder (Limanda ferruginea) and ctenophores (Pleurobrachius pileus) of synthetic drill mud fluid, produced water and drill mud cuttings. In this report, they presented the data collected, including data on the water solubility of Petro-Canada drill mud fluid IA-35 and metal analysis of production water from the Sable Island Offshore Exploration Project. Low acute toxicity potential for drill mud fluid, production water and Hibernia drill cuttings for the species and life stages tested were revealed. The hypothesis to the effect that wastes pose very little or no risk of an acute toxic nature to the marine environment were reinforced by the results from this study. 5 refs., 25 tabs.

  3. The multiphase flow system used in exploiting depleted reservoirs: water-based Micro-bubble drilling fluid

    International Nuclear Information System (INIS)

    Zheng Lihui; He Xiaoqing; Wang Xiangchun; Fu Lixia

    2009-01-01

    Water-based micro-bubble drilling fluid, which is used to exploit depleted reservoirs, is a complicated multiphase flow system that is composed of gas, water, oil, polymer, surfactants and solids. The gas phase is separate from bulk water by two layers and three membranes. They are 'surface tension reducing membrane', 'high viscosity layer', 'high viscosity fixing membrane', 'compatibility enhancing membrane' and 'concentration transition layer of liner high polymer (LHP) and surfactants' from every gas phase centre to the bulk water. 'Surface tension reducing membrane', 'high viscosity layer' and 'high viscosity fixing membrane' bond closely to pack air forming 'air-bag', 'compatibility enhancing membrane' and 'concentration transition layer of LHP and surfactants' absorb outside 'air-bag' to form 'incompact zone'. From another point of view, 'air-bag' and 'incompact zone' compose micro-bubble. Dynamic changes of 'incompact zone' enable micro-bubble to exist lonely or aggregate together, and lead the whole fluid, which can wet both hydrophilic and hydrophobic surface, to possess very high viscosity at an extremely low shear rate but to possess good fluidity at a higher shear rate. When the water-based micro-bubble drilling fluid encounters leakage zones, it will automatically regulate the sizes and shapes of the bubbles according to the slot width of fracture, the height of cavern as well as the aperture of openings, or seal them by making use of high viscosity of the system at a very low shear rate. Measurements of the rheological parameters indicate that water-based micro-bubble drilling fluid has very high plastic viscosity, yield point, initial gel, final gel and high ratio of yield point and plastic viscosity. All of these properties make the multiphase flow system meet the requirements of petroleum drilling industry. Research on interface between gas and bulk water of this multiphase flow system can provide us with information of synthesizing effective

  4. New high-performance, water-based fluid benefits Santos basin operations with excellent inhibition and drilling efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Tom; West, Gary [Halliburton Baroid, Santos, SP (Brazil)

    2004-07-01

    For decades drilling fluids companies have been striving to create a water-based fluid (WBF) that yields performance similar to that of an invert emulsion in the areas of hole stability, rate of penetration (ROP) and lubricity. The HYDRO-GUARD system is a new highly inhibitive WBF that can yield drilling performance approaching that of an invert emulsion system. The new system uses a new combination of polymeric additives designed to inhibit reactive clays, minimize colloidal solids buildup, and produce a lubricious, gauge wellbore. This paper compares the field performance of the HYDRO-GUARD system on two recent Santos Basin wells drilled to over 5,000 m with the performance of synthetic-based fluids (SBF) used historically in the same area. Bottom hole temperatures (BHT) on these wells exceeded 315 deg F (157 deg C). Performance measures such as hole cleaning, penetration rates, hole stability, and torque and drag will be reviewed as well as general system benefits. (author)

  5. Preparation of fluidized catalytic cracking slurry oil-in-water emulsion as anti-collapse agent for drilling fluids

    Directory of Open Access Journals (Sweden)

    Zhengqiang Xiong

    2016-12-01

    Full Text Available Fluidized catalytic cracking slurry oil-in-water emulsion (FCCSE was prepared by using interfacial complexes generation method that was simple and versatile. The critical factors influencing the sample preparation process were optimized, for instance, the optimum value of the mixed hydrophile-lipophile balance of compound emulsifier was 11.36, the content of compound emulsifier was 4 wt%, the emulsification temperature was 75 °C, the agitation speed was 200 rpm, and the emulsification time was 30–45 min. The performance as a drilling fluid additive was also investigated with respect to rheological properties, filtration loss and inhibition of FCCSE. Experimental results showed that FCCSE was favorable to inhibiting clay expansion and dispersion and reducing fluid loss. Furthermore, it had good compatibility with other additives and did not affect the rheological properties of drilling fluids. FCCSE exhibited better performance than the available emulsified asphalt. It has a promising application as anti-collapse agent in petroleum and natural gas drilling.

  6. Evaluation of low toxicity mineral oil base drilling fluids; Avaliacao de fluidos de perfuracao a base de oleo mineral de baixa toxidez

    Energy Technology Data Exchange (ETDEWEB)

    Ponte, Ielton Frederico da [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

    1989-12-31

    In order to introduce low toxicity mineral oil base drilling fluids in Brazil, we carried out a series with a low aromatic content basic oil for lubricants, produced by PETROBRAS: the Lubrax Industrial OB-9 (Lubind OB-9). This oil, as well as its mixture with aviation kerosene to reduce viscosity, was found adequate for use in drilling fluids together with other national products developed by companies that supply additives for drilling fluids in Brazil. We present the results of laboratory tests with systems of four different manufacturers, one of which was chosen for initial field tests. These tests, which were carried out at the Miranga and Bu River Fields, in the Drilling District of Bahia, produced satisfactory results. We anticipate the use of these fluids in other areas where the company operates. (author) 2 refs., 3 tabs.

  7. Evaluation of low toxicity mineral oil base drilling fluids; Avaliacao de fluidos de perfuracao a base de oleo mineral de baixa toxidez

    Energy Technology Data Exchange (ETDEWEB)

    Ponte, Ielton Frederico da [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

    1990-12-31

    In order to introduce low toxicity mineral oil base drilling fluids in Brazil, we carried out a series with a low aromatic content basic oil for lubricants, produced by PETROBRAS: the Lubrax Industrial OB-9 (Lubind OB-9). This oil, as well as its mixture with aviation kerosene to reduce viscosity, was found adequate for use in drilling fluids together with other national products developed by companies that supply additives for drilling fluids in Brazil. We present the results of laboratory tests with systems of four different manufacturers, one of which was chosen for initial field tests. These tests, which were carried out at the Miranga and Bu River Fields, in the Drilling District of Bahia, produced satisfactory results. We anticipate the use of these fluids in other areas where the company operates. (author) 2 refs., 3 tabs.

  8. Validation and comparison of two sampling methods to assess dermal exposure to drilling fluids and crude oil.

    Science.gov (United States)

    Galea, Karen S; McGonagle, Carolyn; Sleeuwenhoek, Anne; Todd, David; Jiménez, Araceli Sánchez

    2014-06-01

    Dermal exposure to drilling fluids and crude oil is an exposure route of concern. However, there have been no published studies describing sampling methods or reporting dermal exposure measurements. We describe a study that aimed to evaluate a wipe sampling method to assess dermal exposure to an oil-based drilling fluid and crude oil, as well as to investigate the feasibility of using an interception cotton glove sampler for exposure on the hands/wrists. A direct comparison of the wipe and interception methods was also completed using pigs' trotters as a surrogate for human skin and a direct surface contact exposure scenario. Overall, acceptable recovery and sampling efficiencies were reported for both methods, and both methods had satisfactory storage stability at 1 and 7 days, although there appeared to be some loss over 14 days. The methods' comparison study revealed significantly higher removal of both fluids from the metal surface with the glove samples compared with the wipe samples (on average 2.5 times higher). Both evaluated sampling methods were found to be suitable for assessing dermal exposure to oil-based drilling fluids and crude oil; however, the comparison study clearly illustrates that glove samplers may overestimate the amount of fluid transferred to the skin. Further comparison of the two dermal sampling methods using additional exposure situations such as immersion or deposition, as well as a field evaluation, is warranted to confirm their appropriateness and suitability in the working environment. © The Author 2014. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

  9. Evaluation of differential risk of arrest of drilling and polymeric fluids; Avaliacao do risco de prisao diferencial de fluidos de perfuracao hidroargilosos e polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Sarmento, L.R.B.; Lira, D.S.; Nascimento, R.C.A.M.; Amorim, L.V. [Universidadde Federal de Campina Grande (UFCG), PB (Brazil)], Email: ligia_rafa@hotmail.com

    2010-07-01

    This work evaluates the risk of differential sticking (DS) of clay and water based drilling fluids, before and after adding polymer and lubricant additives, and polymeric fluids. From the results, it was concluded that the addition of lubricant to the clay and water based fluids reduces the torque necessary to free the pipes that are stuck by differential pressure, as for the polymeric fluids presented the lowest filtration losses, cake thickness, differential sticking coefficient and DS risk. (author)

  10. Improvement in the Performance of Potato Starch Used in the Water-Based Drilling Fluid via Its Chemical Modification by Grafting Copolymerization

    Directory of Open Access Journals (Sweden)

    M. Abdollahi

    2013-01-01

    Full Text Available Increasing the thermal stability and resistance to bacterial attack (bioresistance of the potato starch used in the water-based drilling fluid is the aim of this work. Four types of potato starch grafted with acrylamide and a mixture of each one with acrylic acid, 2-acrylamido-2-methyl-1-propane sulfuric acid and itaconic acid were synthesized by manganese (IV-induced redox system at the suitable concentrations of initiator and monomer(s. FTIR spectroscopy was used to verify the grafting of monomers onto the starch. The effect of grafted starches on the rheological and fluid loss properties before and after aging of the water-based drilling fluid prepared with fresh water, 4% saline and the South applied method were investigated. The results showed that temperature and aging of fluid enhance the rheological and fluid loss control properties of water-based drilling fluids prepared in the presence of grafted starches. In other words, grafted starches are stable against thermal degradation and can be used in the formulation of water-based drilling fluids for drilling of deep wells.

  11. Water base drilling fluids for high-angle wells; Fluidos a base de agua para perfuracao de pocos com elevada inclinacao

    Energy Technology Data Exchange (ETDEWEB)

    Passarelli, Rui [PETROBRAS, Rio de Janeiro (Brazil). Dept. de Perfuracao. Div. de Fluidos de Perfuracao; Lomba, Rosana Fatima T [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

    1990-12-31

    Horizontal drilling has experimented a large increase in last years. In Brazil, two horizontal wells were drilled in Fazenda Belem and Carmopolis Fields. The first one reached a final measured depth of 1128 m and the horizontal length was 533 m. The drilling fluid program was elaborated after a large number of laboratory tests, in order to get a composition that best fitted the drilling requirements, mainly the desirable lubricity. The idea of using a water-base fluid instead of an oil-based, known as more suitable in this case, arose because the Company is interested in drilling this kind of well offshore, in deep water, where the use of oil-base muds is forbidden. Different compositions of water base muds were developed and tested in laboratory and the results led to low-solids salt fluids having a lubricant in its composition. The lubricity coefficients of these fluids are similar to those obtained with oil-base muds. 9-FZB-446D-CE well was drilled with the chosen fluid and high values of torque and drag were not registered, being the operation a total success. (author) 10 tabs.

  12. Water base drilling fluids for high-angle wells; Fluidos a base de agua para perfuracao de pocos com elevada inclinacao

    Energy Technology Data Exchange (ETDEWEB)

    Passarelli, Rui [PETROBRAS, Rio de Janeiro (Brazil). Dept. de Perfuracao. Div. de Fluidos de Perfuracao; Lomba, Rosana Fatima T. [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

    1989-12-31

    Horizontal drilling has experimented a large increase in last years. In Brazil, two horizontal wells were drilled in Fazenda Belem and Carmopolis Fields. The first one reached a final measured depth of 1128 m and the horizontal length was 533 m. The drilling fluid program was elaborated after a large number of laboratory tests, in order to get a composition that best fitted the drilling requirements, mainly the desirable lubricity. The idea of using a water-base fluid instead of an oil-based, known as more suitable in this case, arose because the Company is interested in drilling this kind of well offshore, in deep water, where the use of oil-base muds is forbidden. Different compositions of water base muds were developed and tested in laboratory and the results led to low-solids salt fluids having a lubricant in its composition. The lubricity coefficients of these fluids are similar to those obtained with oil-base muds. 9-FZB-446D-CE well was drilled with the chosen fluid and high values of torque and drag were not registered, being the operation a total success. (author) 10 tabs.

  13. Effect of a synthetic drilling fluid (IPAR) on antioxidant enzymes and peroxisome proliferation in the American lobster, Homarsus americanus

    Energy Technology Data Exchange (ETDEWEB)

    Hamoutene, D.; Payne, J.F.; Andrews, C.; Wells, J.; Guiney, J.

    2004-07-01

    The acute, sublethal toxicity of a synthetic paraffinic drilling fluid (IPAR) was examined in this study which exposed 2 sets of 14 lobsters to the substance. Synthetic-based muds (SBMs) make up the fluid component of drilling muds along with water-based muds (WBMs) and oil-based muds (OBMs). Although SBMs are proposed to replace OBMs, little is known about their environmental impact. IPAR, an ultra-pure isoalkane with no aromatics or sulphur compounds, is currently used in the Newfoundland offshore. This study examined the effect of IPAR on benthic crustacean because most of the wastes discharged from drilling platforms sediment quickly and the impact is greatest on benthic animals. The lobsters were injected with 1 mL of IPAR every 3 days, to a maximum of 5 mL. They were also exposed to very high levels of the fluid, which would not be expected under field conditions. Different aspects of lipid and protein metabolism were monitored along with the effect of IPAR on peroxisome proliferations and various serum and organ enzymes. The study showed that even at the high dose administered to the lobsters, the isoalkane mixture had no influence on peroxisome proliferation. Increased amounts of protein was found in claw muscles, but no increase was observed in gills, hepatopancreas or heart, suggesting no adverse impact of IPAR. A slight increase was also noted in serum aminotransferases. The study results are in agreement with the hypothesis that IPAR has little or no ecotoxicological potential. 32 refs., 3 tabs., 2 figs.

  14. Effect of a synthetic drilling fluid (IPAR) on antioxidant enzymes and peroxisome proliferation in the American lobster, Homarsus americanus

    International Nuclear Information System (INIS)

    Hamoutene, D.; Payne, J.F.; Andrews, C.; Wells, J.; Guiney, J.

    2004-01-01

    The acute, sublethal toxicity of a synthetic paraffinic drilling fluid (IPAR) was examined in this study which exposed 2 sets of 14 lobsters to the substance. Synthetic-based muds (SBMs) make up the fluid component of drilling muds along with water-based muds (WBMs) and oil-based muds (OBMs). Although SBMs are proposed to replace OBMs, little is known about their environmental impact. IPAR, an ultra-pure isoalkane with no aromatics or sulphur compounds, is currently used in the Newfoundland offshore. This study examined the effect of IPAR on benthic crustacean because most of the wastes discharged from drilling platforms sediment quickly and the impact is greatest on benthic animals. The lobsters were injected with 1 mL of IPAR every 3 days, to a maximum of 5 mL. They were also exposed to very high levels of the fluid, which would not be expected under field conditions. Different aspects of lipid and protein metabolism were monitored along with the effect of IPAR on peroxisome proliferations and various serum and organ enzymes. The study showed that even at the high dose administered to the lobsters, the isoalkane mixture had no influence on peroxisome proliferation. Increased amounts of protein was found in claw muscles, but no increase was observed in gills, hepatopancreas or heart, suggesting no adverse impact of IPAR. A slight increase was also noted in serum aminotransferases. The study results are in agreement with the hypothesis that IPAR has little or no ecotoxicological potential. 32 refs., 3 tabs., 2 figs

  15. Disposal of drilling fluids and solids generated from water-based systems in Alberta

    International Nuclear Information System (INIS)

    Parenteau, S.E.

    1999-01-01

    The different disposal options for drilling wastes as outlined in Guide 50 of the Alberta Energy and Utilities Board (EUB) are discussed. Guide 50 provides for the cost effective and environmentally sound disposal of drilling waste generated in Alberta. Each disposal option of the guide is reviewed and common methods of operation are outlined. Relative costs, environmental suitability and liability issues associated with each option are described. Issues regarding overall disposal considerations, on-site and off-site disposal options, hydrocarbon contamination, salt contaminated waste, toxic waste, and documentation of waste disposal outlined. Some recent programs which have been in the trial phase for a few years are also addressed

  16. Helium measurements of pore fluids obtained from the San Andreas Fault Observatory at Depth (SAFOD, USA) drill cores

    Science.gov (United States)

    Ali, S.; Stute, M.; Torgersen, T.; Winckler, G.; Kennedy, B. M.

    2011-02-01

    4He accumulated in fluids is a well established geochemical tracer used to study crustal fluid dynamics. Direct fluid samples are not always collectable; therefore, a method to extract rare gases from matrix fluids of whole rocks by diffusion has been adapted. Helium was measured on matrix fluids extracted from sandstones and mudstones recovered during the San Andreas Fault Observatory at Depth (SAFOD) drilling in California, USA. Samples were typically collected as subcores or from drillcore fragments. Helium concentration and isotope ratios were measured 4-6 times on each sample, and indicate a bulk 4He diffusion coefficient of 3.5 ± 1.3 × 10-8 cm2 s-1 at 21°C, compared to previously published diffusion coefficients of 1.2 × 10-18 cm2 s-1 (21°C) to 3.0 × 10-15 cm2 s-1 (150°C) in the sands and clays. Correcting the diffusion coefficient of 4Hewater for matrix porosity (˜3%) and tortuosity (˜6-13) produces effective diffusion coefficients of 1 × 10-8 cm2 s-1 (21°C) and 1 × 10-7 (120°C), effectively isolating pore fluid 4He from the 4He contained in the rock matrix. Model calculations indicate that <6% of helium initially dissolved in pore fluids was lost during the sampling process. Complete and quantitative extraction of the pore fluids provide minimum in situ porosity values for sandstones 2.8 ± 0.4% (SD, n = 4) and mudstones 3.1 ± 0.8% (SD, n = 4).

  17. Performance evaluation of NEEM oil and HONGE Oil as cutting fluid in drilling operation of mild steel

    Science.gov (United States)

    Jyothi, P. N.; Susmitha, M.; Sharan, P.

    2017-04-01

    Cutting fluids are used in machining industries for improving tool life, reducing work piece and thermal deformation, improving surface finish and flushing away chips from the cutting zone. Although the application of cutting fluids increases the tool life and Machining efficiency, but it has many major problems related to environmental impacts and health hazards along with recycling & disposal. These problems gave provision for the introduction of mineral, vegetable and animal oils. These oils play an important role in improving various machining properties, including corrosion protection, lubricity, antibacterial protection, even emulsibility and chemical stability. Compared to mineral oils, vegetable oils in general possess high viscosity index, high flash point, high lubricity and low evaporative losses. Vegetable oils can be edible or non-edible oils and Various researchers have proved that edible vegetable oils viz., palm oil, coconut oil, canola oil, soya bean oil can be effectively used as eco-friendly cutting fluid in machining operations. But in present situations harnessing edible oils for lubricants formation restricts the use due to increased demands of growing population worldwide and availability. In the present work, Non-edible vegetable oil like Neem and Honge are been used as cutting fluid for drilling of Mild steel and its effect on cutting temperature, hardness and surface roughness are been investigated. Results obtained are compared with SAE 20W40 (petroleum based cutting fluid)and dry cutting condition.

  18. USE OF DRILLING FLUIDS IN MONITORING WELL NETWORK INSTALLATION: LANL AND OPEN DISCUSSION

    Science.gov (United States)

    Personnel at the EPA Ground Water and Ecosystems Restoration Division (GWERD) were requested by EPA Region 6 to provide a technical analysis of the impacts of well drilling practices implemented at the Los Alamos National Laboratory (LANL) as part of the development of their grou...

  19. Effects of vegetable-based cutting fluids on the wear in drilling

    Indian Academy of Sciences (India)

    2016-08-26

    Aug 26, 2016 ... In this study, performances of three VBCFs developed from crude sunflower oil, refined sunflower oil, refined canola oil and commercial semi-synthetic cutting fluid are compared in terms of tool wear, thrust force and surface roughness during drilling of AISI 304 austenitic stainless steel with HSSE tool.

  20. Restart of circulation of gelled drilling fluids; Estudo do inicio da recirculacao de fluidos de perfuracao gelificados

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Gabriel M. de [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Rocha, Leandro L.V. da; Franco, Admilson T.; Negrao, Cezar O.R. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Programa de Pos Graduacao em Engenharia Mecanica e de Materiais; Martins, Andre L. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    This paper describes a mathematical model that simulates the start-up flow of gelled drilling fluids in annular spaces with the purpose to predict pressure peaks at the beginning of the flow. The model comprises the one-dimensional conservation equations of mass and momentum, which are discretized by Finite Volume Method. Fully implicit and up-wind discretization schemes are used and the resultant algebraic equations are solved iteratively by developing a FORTRAN algorithm. The model has the potentiality to be easily adapted to a flow inside a tube. Cases studies are conducted to evaluate the temporal variation of velocity and pressure fields inside both the annular space and a tube. One observed that increasing fluid compressibility or viscosity leads to a reduction of the pressure peaks. (author)

  1. Drilling fluids formulation with cationic hydro-soluble polymers as inhibitors reactive shales; Formulacao de fluidos de perfuracao contendo polimeros cationicos hidrossoluveis como inibidores de formacoes reativas

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Carlos Eduardo C. de; Nascimento, Regina Sandra V. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Inst. de Quimica; Sa, Carlos Henrique [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    Poly(diallyldimethylammonium chloride), having different molecular weight, and a copolymer with acrylamide were evaluated as shale inhibitor additive for water based drilling fluid, as well as the compatibility of these polycations with others additives present in the drilling fluid and the testing results for these fluids were compared with those for formulations with commercial cationic polymers from drilling fluids additives suppliers. The ability of the polymers and KCl systems in inhibiting the clay's dispersion were evaluated with hot rolling tests. The others additives, like viscosifier and fluid loss control agent, had their added amount systematically optimized by rheological and filtration tests. All cationic polymers and the electrolyte were able to inhibit the swelling and dispersion of clay and the results showed a synergistic increase in clay inhibition for the combination of polymer and KCl over either additive alone. The results suggested that greater polymer adsorption, implies in lower content of water in clays and better inhibition of swelling and dispersion of the clay. The polycations were compatible with the other additives in drilling fluids and the fluids formulated with these polymers were able to inhibit efficiently the dispersion and disintegration of clay and to keep the cuttings and barite in suspension. (author)

  2. The Preparation and Performances of Self-Dispersed Nanomicron Emulsified Wax Solid Lubricant Ewax for Drilling Fluids

    Directory of Open Access Journals (Sweden)

    Feng-shan Zhou

    2014-01-01

    Full Text Available An oil-in-water nanomicron wax emulsion with oil phase content 45 wt% was prepared by using the emulsifying method of surfactant-in-oil. The optimum prepared condition is 85°C, 20 min, and 5 wt% complex emulsifiers. Then the abovementioned nanomicron emulsifying wax was immersed into a special water-soluble polymer in a certain percentage by the semidry technology. At last, a solidified self-dispersed nanomicron emulsified wax named as Ewax, a kind of solid lubricant for water based drilling fluid, was obtained after dried in the special soluble polymer containing emulsifying wax in low temperature. It is shown that the adhesion coefficient reduced rate (ΔKf is 73.5% and the extreme pressure (E-P friction coefficient reduced rate (Δf is 77.6% when the produced Ewax sample was added to fresh water based drilling fluid at dosage 1.0 wt%. In comparison with other normal similar liquid products, Ewax not only has better performances of lubrication, filtration loss control property, heat resistance, and tolerance to salt and is environmentally friendly, but also can solve the problems of freezing in the winter and poor storage stability of liquid wax emulsion in oilfield applications.

  3. Investigation of Shear-Thinning Behavior on Film Thickness and Friction Coefficient of Polyalphaolefin Base Fluids With Varying Olefin Copolymer Content

    Energy Technology Data Exchange (ETDEWEB)

    Zolper, Thomas J.; He, Yifeng; Delferro, Massimiliano; Shiller, Paul; Doll, Gary; LotfizadehDehkordi, Babak; Ren, Ning; Lockwood, Frances; Marks, Tobin J.; Chung, Yip-Wah; Greco, Aaron; Erdemir, Ali; Wang, Qian

    2016-08-11

    This study investigates the rheological properties, elastohydrodynamic (EHD) film-forming capability, and friction coefficients of low molecular mass poly-alpha-olefin (PAO) base stocks with varying contents of high molecular mass olefin copolymers (OCPs) to assess their shear stability and their potential for energy-efficient lubrication. Several PAO-OCP mixtures were blended in order to examine the relationship between their additive content and tribological performance. Gel permeation chromatography (GPC) and nuclear magnetic resonance (NMR) spectroscopy were used to characterize the molecular masses and structures, respectively. Density, viscosity, EHD film thickness, and friction were measured at 303 K, 348 K, and 398 K. Film thickness and friction were studied at entrainment speeds relevant to the boundary, mixed, and full-film lubrication regimes. The PAO-OCP mixtures underwent temporary shear-thinning resulting in decreases in film thickness and hydrodynamic friction. These results demonstrate that the shear characteristics of PAO-OCP mixtures can be tuned with the OCP content and provide insight into the effects of additives on EHD characteristics.

  4. Water and clay based drilling fluids: rheologic, filtration and lubricity behavior; Fluidos hidroargilosos: comportamento reologico, de filtracao e lubricidade

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Luciana V.; Pereira, Melquesedek S.; Ferreira, Heber C. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    The aim of this work is to provide continuity for UFCG studies presenting results of rheological, filtration and the lubricity behaviors obtained with fluids prepared with bentonite clays from Paraiba, in binary compositions, after treatment with lubricants agents. It was selected two samples of bentonite clays and four lubricants (Lub 1, Lub 2, Lub 3 and Lub 4). The results showed that: depending on the composition, the drilling fluids presented bingham and pseudo plastic rheological behaviors, and with the additives bingham behavior; among the rheological and filtration properties evaluated, the apparent viscosity, yield limiting and the water loss are the have changes with the addition of lubricants; the values of the lubricity coefficient (LC) of fluids without additives were next of 0.50, independent of the composition of the bentonite clay mixture; after addition of the lubricants, the LC of fluids reduced for values next to 0,11, independent of its concentration and lubricants the best-performing are the Lub 2 and Lub 4. (author)

  5. EXECUTIVE SUMMARY OF STATE DATA RELATED TO ABANDONED CENTRALIZED AND COMMERCIAL DRILLING-FLUID DISPOSAL SITES IN LOUISIANA, NEW MEXICO, OKLAHOMA, AND TEXAS

    Energy Technology Data Exchange (ETDEWEB)

    H. Seay Nance

    2003-03-01

    This 2003 Spring Semi-Annual Report contains a summary of the Final Technical Report being prepared for the Soil Remediation Requirements at Commercial and Centralized Drilling-Fluid Disposal (CCDD) Sites project funded by the United States Department of Energy under DOE Award No. DE-AC26-99BC15225. The summary describes (1) the objectives of the investigation, (2) a rationale and methodology of the investigation, (3) sources of data, assessment of data quality, and data availability, (4) examples of well documented centralized and commercial drilling-fluid disposal (CCDD) sites and other sites where drilling fluid was disposed of, and (5) examples of abandoned sites and measures undertaken for their assessment and remediation. The report also includes most of the figures, tables, and appendices that will be included in the final report.

  6. Induction of Fish Biomarkers by Synthetic-Based Drilling Muds

    Science.gov (United States)

    Gagnon, Marthe Monique; Bakhtyar, Sajida

    2013-01-01

    The study investigated the effects of chronic exposure of pink snapper (Pagrus auratus Forster), to synthetic based drilling muds (SBMs). Fish were exposed to three mud systems comprised of three different types of synthetic based fluids (SBFs): an ester (E), an isomerized olefin (IO) and linear alpha olefin (LAO). Condition factor (CF), liver somatic index (LSI), hepatic detoxification (EROD activity), biliary metabolites, DNA damage and stress proteins (HSP-70) were determined. Exposure to E caused biologically significant effects by increasing CF and LSI, and triggered biliary metabolite accumulation. While ester-based SBFs have a rapid biodegradation rate in the environment, they caused the most pronounced effects on fish health. IO induced EROD activity and biliary metabolites and LAO induced EROD activity and stress protein levels. The results demonstrate that while acute toxicity of SBMs is generally low, chronic exposure to weathering cutting piles has the potential to affect fish health. The study illustrates the advantages of the Western Australian government case-by-case approach to drilling fluid management, and highlights the importance of considering the receiving environment in the selection of SBMs. PMID:23894492

  7. Development of the Breitbrunn/Eggstaett natural gas deposit: Drilling of the 8 1/2 inch horizontal boreholes with drill-in fluid; Ausbau des Erdgasspeichers Breitbrunn/Eggstaett, hier: Bohren der 8 1/2{sup ''}-Horizontalstrecken mit Drill-in-Fluid

    Energy Technology Data Exchange (ETDEWEB)

    Neufeld, A.; Jakschies, R. [RWE-DEA Aktiengesellschaft fuer Mineraloel und Chemie, Hamburg (Germany); Gankin, V. [Baroid Drilling Fluids GmbH, Celle (Germany)

    2001-07-01

    During the second stage of development of the project, six horizontal boreholes of 584-960 m were drilled at a depth of about 2000 m using the drill-in fluid technique. Details are presented. It was found that extremely high differential pressures will pose no problem provided that the drilling technology and flushing system are well matched. [German] Waehrend der 2. Baustufe des Projektes Erdgasspeicher Breitbrunn/Eggstaett sind in Teufe von ca. 2000 m sechs Bohrungen mit Horizontalstrecken von 584-960 m in den bis ca. 3 MPa (30 bar) druckabgesenkten Speichergesteinen C und D abgeteuft worden. Die Gesamtabweichung vom Ansatzpunkt auf der Sammellokation betraegt bis zu 2 518 m. Die Horizontalstrecken sind mit Hilfe eines auf die Formation abgestimmten fluessigen Spuelungssystems, dem sogenannten Drill-in-Fluid, gebohrt. Hauptaugenmerk galt bei dieser Spuelung dem Aufbau eines extrem duennen, impermeablem Filterkuchens mit niedrigem Reibungsfaktor. Die im Bereich der 9 5/8{sup ''}-Rohrtour in den Bohrstrang integrierten Torque-Reducer und dem Spuelungssystem zugefuehrtes Schmlermittel trugen zu einer erheblichen Reduzierung der Reibkraefte bei. Durch Einbau von Non-Hanging Anti-Sticking-Stabilisatoren in den Bohrstrang ist die Gefahr des Festwerdens zusaetzlich minimiert. Der Einsatz von LWD Geosteering Equipment und begleitende mikropalaeontologische Untersuchungen ermoeglichten eine optimale Orientierung der abzuteufenden Strecken. Die Erfahrungen von insgesamt 6 Breitbrunn-Bohrungen belegen, dass extrem hohe Differenzdruecke kein Problem fuer das erfolgreiche Abteufen einer Bohrung sein muessen, wenn Bohrtechnik und Spuelungssystem sorgfaeltig aufeinander abgestimmt werden. (orig.)

  8. Evaluation of drilling fluids flow regime in annular sections; Avaliacao do regime de escoamento de fluidos de perfuracao em secoes anulares

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Maria das Gracas Pena [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Setor de Tecnologia de Perfuracao

    1990-12-31

    The determination of the transition zone between the laminar and turbulent flow regimes of particular importance in optimizing the hydraulics of drilling operations. The principal advantage which laminar flow in the annular space has in drilling operations in the avoidance of wall enlargement (wash-outs), maintaining formation integrity as much as possible. On the other hand, a lower-energy regime such as laminar flow does not provide the same cuttings-carrying capacity as that obtained when the drilling fluid is in turbulent flow. However, to be able to optimize the hydraulics it is necessary to have determined, among other parameters, the transition zone, in order to maximize the drilling rate while obtaining the hole clear of cuttings and maintaining the hole diameter constant over the whole of the section drilled. This paper presents, based on experimental results obtained on the SHS physical simulator, the transition zone expressed through the critical Reynolds numbers and those for low stable turbulence of various drilling fluids tested over the temperature range of 25-80 deg C. (author) 20 refs., 7 figs., 4 tabs.

  9. Evaluation of the aging of polymeric drilling fluids to oil wells; Avaliacao do envelhecimento de fluidos de perfuracao polimericos para pocos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Farias, K.V.; Amorim, L.V. [Universidade Federal de Campina Grande, PB (Brazil). Unidade Academica de Engenharia Mecanica, UAEM/CCT - UFCG], e-mail: kassie@dem.ufcg.edu.br; Leite, R.S. [Universidade Federal de Campina Grande, PB (Brazil). Graduacao Engenharia de Materiais; Lira, H.L. [Universidade Federal de Campina Grande, PB (Brazil). Unidade Academica de Engenharia de Materiais, UAEMa/ CCT - UFCG

    2010-07-01

    The aim of this work is to evaluate the aging of polymeric drilling fluids to oil wells, from the rheological, filtration and lubricity properties in the temperatures 100 degree F ({approx} 38 degree C) and 150 degree F ({approx} 66 degree C). The results had been compared with a standard fluid used for the oil industry and had evidenced that the polymeric fluids had presented good thermal stability, presenting a small reduction in the rheological properties and better values of lubricity coefficient that a reference fluid. (author)

  10. Effects of non-aqueous fluids-associated drill cuttings discharge on shelf break macrobenthic communities in the Campos Basin, Brazil.

    Science.gov (United States)

    Santos, Maria Fernanda L; Silva, Janete; Fachel, Jandyra M G; Pulgati, Fernando H

    2010-08-01

    This paper assesses the effects of non-aqueous fluids (NAF)-associated drill cuttings discharge on shelf break macrobenthic communities in the Campos Basin, off the southeast Brazilian coast, Rio de Janeiro State. Samples were taken with a 0.25-m2 box corer from surrounding two oil and gas wells on three monitoring cruises: before drilling, three months after drilling, and 22 months after drilling. Statistical methodologies used Bayesian geostatistical and analysis of variance models to evaluate the effects of the NAF-associated drill cuttings discharge and to define the impact area. The results indicated that marked variations were not observed in the number of families between cruises, though there were changes in the fauna composition. The changes seen in biological descriptors in both control and background situation areas were not considered significant, showing a temporal homogeneity in means. The impact area presented changes in biological descriptors of communities and trophic structure during the three cruises and such changes were correlated to chemical and physical variables related to the drilling activities, as a result of the mix of drill cuttings and sediment and the anoxic conditions established in the substrate. In that area, three months after drilling, a decrease in diversity and an increase in density, motile deposit-feeders and Pol/Crp ratio, and dominance of opportunistic organisms, such as the capitellid Capitella sp., were observed and, 22 months after drilling, an increase of diversity, reduction of dominance of capitellid polychaete, changes in the fauna composition, and a dominance of opportunistic burrowing and tube-building organisms were observed, indicating an ecological succession process.

  11. Olefin Autoxidation in Flow

    OpenAIRE

    Neuenschwander Ulrich; Jensen Klavs F.

    2014-01-01

    Handling hazardous multiphase reactions in flow brings not only safety advantages but also significantly improved performance due to better mass transfer characteristics. In this paper we present a continuous microreactor setup capable of performing olefin autoxidations with O2 under solvent free and catalyst free conditions. Owing to the transparent reactor design consumption of O2 can be visually followed and exhaustion of the gas bubbles marks a clear end point along the channel length coo...

  12. Drilling technologies in hydrogeological survey

    OpenAIRE

    Vorlíček, Petr

    2014-01-01

    This work deals with the drilling technologies used in hydrogeology. The main aim of the work is to explore types of drilling technologies used at hydrogeological drilling wells and modern technologies that could potentially be used in the future. The work also summarizes a historical development of drilling techniques, a drilling process procedure, information obtained from boreholes and the most common types of drilling fluids.

  13. Study of methane solubility in oil base used in oil base drilling fluid; Estudo da solubilidade de metano em base oleo utilizada em fluido de perfuracao base oleo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Carolina Teixeira da; Mariolani, Jose Ricardo Lenzi [Universidade Estadual de Campinas, SP (Brazil); Ribeiro, Paulo Roberto; Lomba, Rosana Fatima Teixeira; Bonet, Euclides Jose

    2004-07-01

    During drilling a well, it is necessary to prevent and control high pressurized zones because while drilling on those zones, could occur a kick if the formation pressure were higher then downhole pressure, allowing the entering of undesirables fluids from the formation to the wellbore. If the well is not controlled this kick could became a blowout, generating damages to the environment, to the equipment and the human life. When drilling using oil-based mud, the concern related to the well control would be higher due the gas solubility in the mud, which could make it hard to detect the kick, especially in deep and ultra deep waters. In this work we have studied the interaction between methane and organic liquids used in drilling fluids, and the measurement and analysis of the thermodynamic properties of those gas liquid mixtures. There have been measured parameters like the oil formation volume factor (FVF{sub o}), bubble pressure, solubility (Rs) and the density of the saturated liquid in function of methane mole fraction and temperature. The results have shown that the gas solubility, at downhole conditions and during kick circulation, is a factor very important to the safety during well drilling in deep and ultra deep waters. (author)

  14. Optimization of organo clay production for applications in based oil drilling fluid; Otimizacao do processo de organofilizacao para aplicacoes em fluidos de perfuracao base oleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Heber S; Martins, Alice B; Costa, Danubia L. da; Ferreira, Heber C; Neves, Gelmires de A; Melo, Tomas J.A. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Teixeira Neto, Erico [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil)

    2008-07-01

    The organophilic clays are widely used as an agent dispersed in the composition of oil based drilling fluids. The organophilic clays are gotten from bentonite clays treated, in watery way, with ionic surfactants, that are adsorbed in the surface of interlayer of the clays, re-covered them with a organic layer. A fundamental stage of production of the organophilic clays is the dispersion of bentonite clays, in way that variables like: speed of agitation, temperature and time of cure, influences directly in plastic and apparent viscosities of these dispersions, together with other variables of organophilization process, like, temperature and time of cure of organophilization, has direct influence in efficiency of the organophilization process. This work considers a study of these variable, using bentonite clays: Brasgel PA{sup R} and Cloisite Na{sup +R}, treated with the ionic surfactant Praepagem WB{sup R}. The organophilic clays gotten had been characterized by rays X diffraction, Foster's swelling, and the results were compared with the commercial organophilic clay VG-69{sup R}, industrially treated with ionic surfactant. Viscosities plastic and apparent of the dispersions had been measured in the midst of organic dispersant diesel oil used to obtain the oil based drilling fluids. Preliminary results of Foster's swelling and preparation of fluids show that the clays have affinity with the means liquid organic dispersants, and the fluids meet specifications of PETROBRAS (N-22581-1997 and N-2259 to 1997) for use in the of diesel oil based drilling fluids. (author)

  15. High performance nature of biodegradable polymeric nanocomposites for oil-well drilling fluids

    Directory of Open Access Journals (Sweden)

    Tarek M. Madkour

    2016-06-01

    Full Text Available Multi-walled carbon nanotube (MWCNT and graphene nanoplatelet reinforced thermoplastic poly(lactic acid (PLA biodegradable nanocomposites were designed and prepared using solution casting techniques. The prepared biodegradable polymers are expected to provide an environmentally friendly alternative to petroleum-based polymers. Both nanocomposite systems exhibited better thermal stability and improved mechanical performance over the unreinforced polymer exhibiting excellent strength and degradability. The addition of graphene nanofiller in varied amounts was aimed to enhance the thermal and mechanical properties of the nanocomposites even further and incorporate the outstanding characteristics of graphene nanoplatelets into the nanocomposites. The polymeric nanocomposites showed also superior advantages for oil drilling relevances, automotive lubricating purposes, membrane technology and food packaging. Scanning electron microscopy images indicated a homogeneous dispersion of the nanofiller within the polymeric matrix at low filler loadings and a cluster formation at higher loadings that could be responsible for the polymeric matrix movement restrictions. The enthalpy of mixing (the polymer and the nanofiller measured could explain the cause of the repulsive interactions between the nanoparticles and the polymeric chains, which created an additional excluded volume that the polymeric segments were restricted to occupy, thus forcing the conformational characteristics of the polymeric chains to deviate away from those of the bulk chains. The prepared polymeric nano composites (poly lactic acid carbon nano tube and poly lactic acid graphene nanoplatelets were utilized in the formulation of oil-base mud as a viscosifier. The rheological, filtration properties and electrical stability of the oil based mud formulation with the new polymeric nanocomposite were studied and the result compared to the oil-based mud formulation with commercial viscosifier.

  16. Emulsifiers performance on the stability of the drilling fluid base biodiesel; Desempenho de emulsificantes sobre a estabilidade de fluido de perfuracao a base de biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Giselle P.; Costa, Marta [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    This work was prepared six (6) formulations of biodiesel based drilling fluids. Three formulations in the proportion oil-water 70/30 and other three in 60/40, just varying the employed surfactants: new product derived the citric acid (developed at our laboratory) and two other commercial surfactants. After production the fluids, It was analyzed them performance of the products through rheological properties to 135 deg F , filtrate volume in HPHT to 500 psi and to 200 deg F, electric stability to 135 deg F and phase separation during seven days of rest. The rheological analyses allowed to determine the behavior every fluids, though flow curves. Those fluids presented same behavior of the fluids used in oil field (Binghamianos). The laboratory tests demonstrated that new surfactant reduced the filtrated volume and provided mechanics and thermic stability. (author)

  17. Olefin metathesis in air

    Directory of Open Access Journals (Sweden)

    Lorenzo Piola

    2015-10-01

    Full Text Available Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more stable and yet more functional group tolerant. This review summarizes the major developments concerning catalytic systems directed towards water and air tolerance.

  18. Comparison of the effects of drilling fluid on macrobenthic invertebrates associated with the seagrass, Thalassia testudinum, in the laboratory and field

    International Nuclear Information System (INIS)

    Weber, D.E.; Flemer, D.A.; Bundick, C.M.

    1992-01-01

    The structure of a macrobenthic invertebrate community associated with the seagrass, Thalassia testudinum, was evaluated under laboratory and field conditions. The research focused on: (1) the effects of pollution stress from a representative drilling fluid used in offshore oil and gas operations, and (2) a comparison of responses of the seagrass-invertebrate community in the laboratory and field. The numbers of macrobenthic invertebrates were suppressed by drilling fluid at both exposure periods in the laboratory, but inhibitory effects were absent in the field. Invertebrate densities in the field were similar among control and treated plots, and were much lower than densities occurring in the laboratory control. In most instances, species richness values were similar in the field and laboratory at the end of each 6 and 12 week period

  19. Recovery Act. Sub-Soil Gas and Fluid Inclusion Exploration and Slim Well Drilling, Pumpernickel Valley, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Fairbank, Brian D. [Nevada Geothermal Power Company, Las Vegas, NV (United States)

    2015-03-27

    Nevada Geothermal Power Company (NGP) was awarded DOE Award DE-EE0002834 in January 2010 to conduct sub-soil gas and fluid inclusion studies and slim well drilling at its Black Warrior Project (now known as North Valley) in Washoe and Churchill Counties, Nevada. The project was designed to apply highly detailed, precise, low-cost subsoil and down-hole gas geochemistry methods from the oil and gas industry to identify upflow zone drilling targets in an undeveloped geothermal prospect. NGP ran into multiple institutional barriers with the Black Warrior project relating to property access and extensive cultural survey requirement. NGP requested that the award be transferred to NGP’s Pumpernickel Valley project, due to the timing delay in obtaining permits, along with additional over-budget costs required. Project planning and permit applications were developed for both the original Black Warrior location and at Pumpernickel. This included obtaining proposals from contractors able to conduct required environmental and cultural surveying, designing the two-meter probe survey methodology and locations, and submitting Notices of Intent and liaising with the Bureau of Land Management to have the two-meter probe work approved. The award had an expiry date of April 30, 2013; however, due to the initial project delays at Black Warrior, and the move of the project from Black Warrior to Pumpernickel, NGP requested that the award deadline be extended. DOE was amenable to this, and worked with NGP to extend the deadline. However, following the loss of the Blue Mountain geothermal power plant in Nevada, NGP’s board of directors changed the company’s mandate to one of cash preservation. NGP was unable to move forward with field work on the Pumpernickel property, or any of its other properties, until additional funding was secured. NGP worked to bring in a project partner to form a joint venture on the property, or to buy the property. This was unsuccessful, and NGP notified

  20. Isobutane/olefin-alkylation

    Energy Technology Data Exchange (ETDEWEB)

    Waitkamp, J.; Maixner, S.

    1983-11-01

    Isobutane/olefin-alkylation - technology and reaction mechanism of a refinery process for production of high octane gasoline components: The alkylation of i-butane with olefins, especially with butenes, is a process for the conversion of light byproducts of a catalytic cracker to high quality gasoline components. Alkylate is a complex mixture of i-paraffins containing 5 to ca. 12 carbon atoms. Due to their octane numbers the four trimethylpentane isomers are the most desirable product components. Indeed, under optimum process conditions these isomers are the main products. Presently, alkylation capacity in the western world amounts to more than 40x10/sup 6/ t/a. Most units are located in the USA. Two liquid-phase processes using sulfuric acid and hydrofluoric acid, respectively, are of commercial importance. At present, there is a definite trend towards HF-alkylation. The reaction mechanism which proceeds via carbocations, is extremely complex. It is composed of a great variety of individual steps. Modern mechanistic concepts are discussed.

  1. Methodology to predict friction pressure drop in drilling fluid flows; Metodologia para previsao de perdas de carga em escoamentos de fluidos de perfuracao

    Energy Technology Data Exchange (ETDEWEB)

    Scheid, Claudia Miriam; Calcada, Luis Americo [Universidade Federal Rural do Rio de Janeiro (UFRRJ). Departamento de Engenharia Quimica (Brazil)], e-mails: scheid@ufrrj.br, calcada@ufrrj.br; Rocha, Daniele Cristine [Centro de Pesquisas da Petrobras (CENPES). Engenharia Basica de Abastecimento - Gas e Energia (Brazil)], e-mail: drocha@petrobras.com.br; Aranha, Pedro Esteves [Centro de Pesquisas da Petrobras (CENPES). Gerencia de Perfuracao e Completacao de Pocos (Brazil)], e-mail: pearanha@petrobras.com.br; Aragao, Atila Fernando Lima [E and P Construcao de Pocos Maritimos. Gerencia de Tecnologia de Fluidos (Brazil)], e-mail: atila_aragao@petrobras.com.br

    2009-12-15

    An extensive experimental study is detailed to evaluate the friction pressure drop resulting from the flow through pipe and annular sections, accessories such as tool joints, bit jets and stabilizers of four different drilling fluids used in deep water operations. After a data analysis process, it was possible to compile a set of equations to predict relevant hydraulic friction pressure loss calculations, such as: hydraulic diameter for annular flows, friction factors for pipe and annular turbulent flows and discharge coefficients for accessories. (author)

  2. Evaluation of the rheological behavior of drilling fluids in annular flow conditions; Avaliacao do comportamento reologico de fluidos de perfuracao no escoamento anular

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Maria das Gracas Pena; Martins, Andre Leibsohn; Oliveira, Antonio Augusto Junqueira de [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

    1988-12-31

    The rheological behavior of drilling fluids during annular flow in a physical simulator well (Surface Hydraulic System - SHS)was investigated. Measurement of volumetric flow and pressure drop the 10-meter simulator well was used to assess applicability of the Bingham, power Law, Casson, and Herschell-Bulkley models to the annular flow of water and oil-based fluids under different temperatures. Additionally, under different pre-set deformation ranges, SHS-observed behavior was compared with behavior observed using the traditional Fann VG 35 A viscometer. (author) 8 refs., 21 figs., 15 tabs.

  3. Study of formation and stability conditions of gas hydrates in drilling fluids; Etude des conditions de formation et de stabilite des hydrates de gaz dans les fluides de forage

    Energy Technology Data Exchange (ETDEWEB)

    Kharrat, M.

    2004-10-15

    Drilling fluids are complex media, in which solid particles are in suspension in a water-in-oil emulsion. The formation of gas hydrates in these fluids during off shore drilling operations has been suspected to be the cause of serious accidents. The purpose of this thesis is the study of the formation conditions as well as the stability of gas hydrates in complex fluids containing water-in-oil emulsions. The technique of high-pressure differential scanning calorimetry was used to characterise the conditions of hydrates formation and dissociation. Special attention has first been given to the validation of thermodynamic measurements in homogeneous solutions, in the pressure range 4 to 12 Mpa; the results were found to be in good agreement with literature data, as well as with modelling results. The method was then applied to water-in-oil emulsion, used as a model for real drilling fluids. It was proven that thermodynamics of hydrate stability are not significantly influenced by the state of dispersion of the water phase. On the other hand, the kinetics of formation and the amount of hydrates formed are highly increased by the dispersion. Applying the technique to real drilling fluids confirmed the results obtained in emulsions. Results interpretation allowed giving a representation of the process of hydrate formation in emulsion. Empirical modelling was developed to compute the stability limits of methane hydrate in the presence of various inhibitors, at pressures ranging from ambient to 70 MPa. Isobaric phase diagrams were constructed, that allow predicting the inhibiting efficiency of sodium chloride and calcium chloride at constant pressure, from 0,25 to 70 MPa. (author)

  4. Optimization of organo clay production for applications in based oil drilling fluid; Otimizacao do processo de organofilizacao para aplicacoes em fluidos de perfuracao base oleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Heber S.; Martins, Alice B.; Costa, Danubia L. da; Ferreira, Heber C.; Neves, Gelmires de A.; Melo, Tomas J.A. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Teixeira Neto, Erico [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil)

    2008-07-01

    The organophilic clays are widely used as an agent dispersed in the composition of oil based drilling fluids. The organophilic clays are gotten from bentonite clays treated, in watery way, with ionic surfactants, that are adsorbed in the surface of interlayer of the clays, re-covered them with a organic layer. A fundamental stage of production of the organophilic clays is the dispersion of bentonite clays, in way that variables like: speed of agitation, temperature and time of cure, influences directly in plastic and apparent viscosities of these dispersions, together with other variables of organophilization process, like, temperature and time of cure of organophilization, has direct influence in efficiency of the organophilization process. This work considers a study of these variable, using bentonite clays: Brasgel PA{sup R} and Cloisite Na{sup +R}, treated with the ionic surfactant Praepagem WB{sup R}. The organophilic clays gotten had been characterized by rays X diffraction, Foster's swelling, and the results were compared with the commercial organophilic clay VG-69{sup R}, industrially treated with ionic surfactant. Viscosities plastic and apparent of the dispersions had been measured in the midst of organic dispersant diesel oil used to obtain the oil based drilling fluids. Preliminary results of Foster's swelling and preparation of fluids show that the clays have affinity with the means liquid organic dispersants, and the fluids meet specifications of PETROBRAS (N-22581-1997 and N-2259 to 1997) for use in the of diesel oil based drilling fluids. (author)

  5. Olefin metathesis and metathesis polymerization

    CERN Document Server

    Ivin, K J

    1997-01-01

    This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis. Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials scien...

  6. Horizontal drilling under Lake Erie

    Energy Technology Data Exchange (ETDEWEB)

    Meller, R.

    2001-07-01

    Drilling oil wells under Lake Erie calls for horizontal drilling wells to be drilled from shore out into the pay-zone under the lake. The nature and characteristics of horizontal wells as compared to vertical wells are explored. Considerations that have to be taken into account in drilling horizontal wells are explained (the degree of curvature, drilling fluid quality, geosteering in the pay-zone, steering instrumentation, measurements while drilling (MWD), logging while drilling (LWD)). The concept and reasons for extended reach wells are outlined, along with characteristic features of multilateral wells.

  7. Modeling pellet impact drilling process

    Science.gov (United States)

    Kovalyov, A. V.; Ryabchikov, S. Ya; Isaev, Ye D.; Ulyanova, O. S.

    2016-03-01

    The paper describes pellet impact drilling which could be used to increase the drilling speed and the rate of penetration when drilling hard rocks. Pellet impact drilling implies rock destruction by metal pellets with high kinetic energy in the immediate vicinity of the earth formation encountered. The pellets are circulated in the bottom hole by a high velocity fluid jet, which is the principle component of the ejector pellet impact drill bit. The experiments conducted has allowed modeling the process of pellet impact drilling, which creates the scientific and methodological basis for engineering design of drilling operations under different geo-technical conditions.

  8. Metylcyclohexane conversion to light olefins

    Directory of Open Access Journals (Sweden)

    SCOFIELD C.F.

    1998-01-01

    Full Text Available This study consists in the evaluation of the catalytic properties of zeolites with different structures in the conversion of methylcyclohexane to light olefins. Results obtained suggest that the steric constrictions of the catalysts used play an important role in hydrogen transfer reactions. Higher selectivities for light olefins (C3= and C4= were observed for zeolites having more closed structures, like MFI and ferrerite, when compared to those having more open ones, like beta, omega and faujasite.

  9. Metylcyclohexane conversion to light olefins

    OpenAIRE

    SCOFIELD, C.F.; BENAZZI, E.; CAUFFRIEZ, H.; MARCILLY, C.

    1998-01-01

    This study consists in the evaluation of the catalytic properties of zeolites with different structures in the conversion of methylcyclohexane to light olefins. Results obtained suggest that the steric constrictions of the catalysts used play an important role in hydrogen transfer reactions. Higher selectivities for light olefins (C3= and C4=) were observed for zeolites having more closed structures, like MFI and ferrerite, when compared to those having more open ones, like beta, omega and fa...

  10. Water-based inhibitive drilling fluids for oil wells: preliminary study; Fluidos aquosos inibidos para perfuracao de pocos de petroleo: estudo preliminar

    Energy Technology Data Exchange (ETDEWEB)

    Farias, Kassie V.; Amorim, Luciana V.; Silva, Aline R.V.; Ferreira, Heber C. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    The aim of this work is to do formulations of water-based inhibitive drilling fluids and to evaluate their rheologic, filtration and lubrication properties and the degree of swell of clays. It was studied eight formulations containing the following additives: viscosity, filtered reducer, controlling of pH, hydratable clays inhibitors, anti-foamy, bactericide, lubricant and sealant. The fluids were prepared according to the field practice that consists of adding to water the additives under constant agitation. After 24 h resting, it was carried out a study of the rheologic behavior, in a Fann 35 A viscosimeter, and of the filtration properties in a Fann press-filter and of lubricity in a Ofite Lubricity tester through the determination of the flow curves, apparent and plastic viscosities, yield limit, gel force, filtered volume, filter-cake thickness and lubricity coefficient. It was also been essays to evaluate the capacity of inhibition of clay with the chemical inhibitors isolated and in set. The results had proven that the presence of inhibitor of clay in drilling fluids has great importance and promotes the inhibition of the swell of clay in all concentrations studied and amongst the formulations developed, six had presented performance next to the fluid Standard. (author)

  11. Advanced Drilling through Diagnostics-White-Drilling

    International Nuclear Information System (INIS)

    FINGER, JOHN T.; GLOWKA, DAVID ANTHONY; LIVESAY, BILLY JOE; MANSURE, ARTHUR J.; PRAIRIE, MICHAEL R.

    1999-01-01

    A high-speed data link that would provide dramatically faster communication from downhole instruments to the surface and back again has the potential to revolutionize deep drilling for geothermal resources through Diagnostics-While-Drilling (DWD). Many aspects of the drilling process would significantly improve if downhole and surface data were acquired and processed in real-time at the surface, and used to guide the drilling operation. Such a closed-loop, driller-in-the-loop DWD system, would complete the loop between information and control, and greatly improve the performance of drilling systems. The main focus of this program is to demonstrate the value of real-time data for improving drilling. While high-rate transfer of down-hole data to the surface has been accomplished before, insufficient emphasis has been placed on utilization of the data to tune the drilling process to demonstrate the true merit of the concept. Consequently, there has been a lack of incentive on the part of industry to develop a simple, low-cost, effective high-speed data link. Demonstration of the benefits of DWD based on a high-speed data link will convince the drilling industry and stimulate the flow of private resources into the development of an economical high-speed data link for geothermal drilling applications. Such a downhole communication system would then make possible the development of surface data acquisition and expert systems that would greatly enhance drilling operations. Further, it would foster the development of downhole equipment that could be controlled from the surface to improve hole trajectory and drilling performance. Real-time data that would benefit drilling performance include: bit accelerations for use in controlling bit bounce and improving rock penetration rates and bit life; downhole fluid pressures for use in the management of drilling hydraulics and improved diagnosis of lost circulation and gas kicks; hole trajectory for use in reducing directional

  12. Hydrate formation in drilling fluids: prevention and countering; Formacao de hidratos em fluidos de perfuracao: prevencao e controle

    Energy Technology Data Exchange (ETDEWEB)

    Villas Boas, Mario Barbosa [PETROBRAS, Macae, RJ (Brazil). Distrito de Perfuracao do Sudeste. Setor de Fluidos de Perfuracao

    1988-12-31

    The possibility of hydrates forming during deep water well drilling is analyzed under conditions typical of the state of Rio de Janeiro`s coastal ocean bed. Relying on an extensive review of technical literature, an effort has been made to ascertain the conditions which favor the occurrence of such hydrates in gas-contaminated water-based drilling muds. Based on this study, methods are proposed for preventing and countering this problem. (author) 58 refs., 10 figs.

  13. Evaluation of glycerol derivative as emulsifier for oil based drilling fluids; Avaliacao de derivados de glicerina como emulsificante para fluidos de perfuracao de base oleo

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Susan A. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Escola de Quimica; Cavalcanti, Milena Y.; Rodrigues Junior, Jorge; Lachter, Elizabeth R.; Nascimento, Regina Sandra V. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Inst. de Quimica

    2008-07-01

    In view of the growing search for new applications for the surplus glycerine of biodiesel production, the use of a glycerine derivative as emulsifier in oil based muds is proposed in this work. Glycerine monooleate was synthesized through esterification reaction, and characterized by NMR{sup 13}C. Its applicability as emulsifier was verified through electric stability tests performed on inverted phase drilling fluids. The obtained results were compared with two formulations containing different emulsifiers (sorbitol monooleate and trimethylolpropane monooleate). It was also evaluated the rheological properties of the formulated fluids through standard tests. It was verified that the fluid that contained the glycerine derivative showed considerably better electric stability results than the other systems. It also presented rheological properties similar to the ones shown by the system that contained the commercial emulsifier (sorbitol monooleate). Thus, it was found that glycerine monooleate is a potential substitute to the currently emulsifiers (author)

  14. An assessment of surface mud system design options for minimizing the health, safety, and environmental impact concerns associated with drilling fluids

    International Nuclear Information System (INIS)

    Minton, R.C.; Bailey, M.G.

    1991-01-01

    In this paper a drilling fluid surface system design concept is proposed that resolves the Environmental, occupational hygiene and safety issues associated with conventional designs. Automation of the chemical handling and dosing system is the central element of the concept which, when fully integrated into the system, permits a significant reduction in the surface volume requirements. This, in turn, results in weight and capital cost savings, offsetting the cost of the processing and treatment plant, and a smaller overall footprint for the system. Adoption of the design philosophy results in a safe, healthy working environment in which all of the waste streams are managed so as to minimize the overall environmental impact of the drilling process

  15. Stability of cracked naphthas from thermal and catalytic processes and their additive response. Part II. Composition and effect of olefinic structures

    Energy Technology Data Exchange (ETDEWEB)

    Nagpal, J.M.; Joshi, G.C.; Rastogi, S.N. [Indian Institute of Petroleum, Dehradun (India)

    1995-05-01

    Olefinic concentrates were separated from two naphthas, one from fluid catalytic cracking (FCC) and one thermal crackate, using column chromatography. The composition and structure of the olefins were determined by a combination of analytical techniques. FCC naphthas contain relatively higher levels of conjugated dienes. The monoolefins are highly branched. The thermal crackates have higher levels of {alpha}-olefins and abound in mono-, di-, tri- and conjugated cyclic olefins. Stability tests on these olefinic concentrates blended in low-S,N straight-run naphtha showed that cyclic olefins are very active gum formers. Representative commercial antioxidants (hindered phenols and phenylenediamines) both gave good responses to different olefin concentrate test blends. Hindered phenols had a marginally better effect. 14 refs., 5 figs., 3 tabs.

  16. Hydride Olefin complexes of tantalum and niobium

    NARCIS (Netherlands)

    Klazinga, Aan Hendrik

    1979-01-01

    This thesis describes investigations on low-valent tantalum and niobium hydride and alkyl complexes, particularly the dicyclopentadienyl tantalum hydride olefin complexes Cp2Ta(H)L (L=olefin). ... Zie: Summary

  17. Fluid inclusion from drill hole DW-5, Hohi geothermal area, Japan: Evidence of boiling and procedure for estimating CO2 content

    Science.gov (United States)

    Sasada, M.; Roedder, E.; Belkin, H.E.

    1986-01-01

    Fluid inclusion studies have been used to derive a model for fluid evolution in the Hohi geothermal area, Japan. Six types of fluid inclusions are found in quartz obtained from the drill core of DW-5 hole. They are: (I) primary liquid-rich with evidence of boiling; (II) primary liquid-rich without evidence of boiling; (III) primary vapor-rich (assumed to have been formed by boiling); (IV) secondary liquid-rich with evidence of boiling; (V) secondary liquid-rich without evidence of boiling; (VI) secondary vapor-rich (assumed to have been formed by boiling). Homogenization temperatures (Th) range between 196 and 347??C and the final melting point of ice (Tm) between -0.2 and -4.3??C. The CO2 content was estimated semiquantitatively to be between 0 and 0.39 wt. % based on the bubble behavior on crushing. NaCl equivalent solid solute salinity of fluid inclusions was determined as being between 0 and 6.8 wt. % after minor correction for CO2 content. Fluid inclusions in quartz provide a record of geothermal activity of early boiling and later cooling. The CO2 contents and homogenization temperatures of fluid inclusions with evidence of boiling generally increase with depth; these changes, and NaCl equivalent solid solute salinity of the fluid can be explained by an adiabatic boiling model for a CO2-bearing low-salinity fluid. Some high-salinity inclusions without CO2 are presumed to have formed by a local boiling process due to a temperature increase or a pressure decrease. The liquid-rich primary and secondary inclusions without evidence of boiling formed during the cooling process. The salinity and CO2 content of these inclusions are lower than those in the boiling fluid at the early stage, probably as a result of admixture with groundwater. ?? 1986.

  18. Experimental determination of wellbore diameter and shape (4D imaging of wellbore) by using ultrasonic caliper within different fluids for real-time drilling application

    Energy Technology Data Exchange (ETDEWEB)

    Elahifar, Behzad; Esmaeili, Abdolali; Thonhauser, Gerhard [Montanuniversitaet Leoben (Austria); Fruhwirth, Rudolf K. [TDE Thonhauser Data Engineering GmbH, Leoben (Austria)

    2013-03-15

    Drilling programs continue to push into new and more complicated environments. As a result, accurate measurement, interpretation and analysis of drilling data in real time are becoming more critical. One of the key measurement devices for drilling, cementing and formation evaluation is the borehole caliper. An ultrasonic sensor caliper tool is thereby a key measurement device for determining the borehole diameter in MWD or LWD tools. Another use of ultrasonic caliper tools is to offer a method for calculating borehole volumes. Real-time application of ultrasonic caliper tools can also support the early detection of borehole instability. This paper describes the experiments related to the accuracy of the ultrasonic sensor for measuring wellbore diameter by performing the tests in different fluids, comparing the results and determining the weak points of the sensor for detecting echoes. In addition the wellbore profiles were simulated and the simulated results were compared with the recorded data. Different tests related to the position of the caliper tool inside the wellbore were performed as well as the evaluation of the accuracy of the ultrasonic sensor by simulating dog-legs and latches. (orig.)

  19. Direct Wittig Olefination of Alcohols.

    Science.gov (United States)

    Li, Qiang-Qiang; Shah, Zaher; Qu, Jian-Ping; Kang, Yan-Biao

    2018-01-05

    A base-promoted transition metal-free approach to substituted alkenes using alcohols under aerobic conditions using air as the inexpensive and clean oxidant is described. Aldehydes are relatively difficult to handle compared to corresponding alcohols due to their volatility and penchant to polymerize and autoxidize. Wittig ylides are easily oxidized to aldehydes and consequently form homo-olefination products. By the strategy of simultaneously in situ generation of ylides and aldehydes, for the first time, alcohols are directly transferred to olefins with no need of prepreparation of either aldehydes or ylides. Thus, the di/monocontrollable olefination of diols is accomplished. This synthetically practical method has been applied in the gram-scale synthesis of pharmaceuticals, such as DMU-212 and resveratrol from alcohols.

  20. Development of high performance drilling fluids from national products: part I; Desenvolvimento de fluidos de perfuracao de alto desempenho a partir de produtos nacionais: parte I

    Energy Technology Data Exchange (ETDEWEB)

    Farias, Kassie V.; Amorim, Luciana V. [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Agencia Nacional do Petroleo (ANP), Brasilia, DF (Brazil). Programa de Recursos Humanos; Lira, Helio L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2008-07-01

    This work has a main objective to develop formulations of high performance water-based drilling fluids composed of national additives and evaluate their rheologic, filtration and lubrication behavior. It was developed ten formulations containing the following additives: viscosity, filtered reducer, controlling of pH, hydra table clays inhibitors, anti foamy, bactericide, lubricant and sealant. The fluids were prepared according to the field practice that consists of adding to water the additives under constant agitation. After 24 h resting, it was carried out a study of the rheologic behavior, in a Fann 35 A viscosimeter, and of the filtration properties in a Fann press-filter and of lubricity in a Ofite lubricimeter through the determination of the flow curves, apparent and plastic viscosities, yield limit, gel force, filtered volume, filter-cake thickness and lubricity coefficient. The results obtained were very promising, with properties close to the standard. (author)

  1. Drilling mortar

    Energy Technology Data Exchange (ETDEWEB)

    Theodorescu, V; Ditulescu, E

    1979-01-30

    A method is proposed for producing stable drilling mortar from drilled rock which makes it possible to stabilize the walls of the borehole and to maintain producing horizons of oil and gas wells in an undisturbed state. The proposed drilling mortar includes 5-12 wt.-% dry modified calcium lignosulfonate in the form of a solution containing about 30% dry matter with the addition of 0.1 wt.-% anti-foaming agent consisting of C/sub 19/-C/sub 20/ alcohol dissolved in a light petroleum product; cream of milk with about 10 wt.-% Ca(OH)/sub 2/ in a quantity sufficient for reducing the pH value of the ions down to 10.5; sodium chloride in amounts from 5 mg to 100 ml (aqueous phase); ordinarily used agents for ensuring the necessary density, viscosity, and filterability. For example, the preparation of the drilling fluid begins with the processing under laboratory conditions of lignosulfonic pulp obtained in the production of yeast fodder with the following characteristics: specific density, 1.15 kgf/dm/sup 3/; water content, 67% (according to the Dean and Stark method); pH 4.0. In the vessel is placed 1000 cm/sup 3/ lignosulfonic pulp containing 33% dry matter, and the pulp is heated to 90-95/sup 0/C by means of a water bath. To the heated pulp 33 cm/sup 3/ formic acid at a 40-% concentration is added by mixing. The specific temperature of the pulp is maintained in the constant mixing process for two hours. Then the cream of milk containing 10 wt.-% Ca(OH)/sub 2/ is added to raise the pH to 10.5. The cooled product is calcium lignosulfonate. To produce a stable form of the drilling mortar, 750 g clay and 10 g trass gel are added to a vessel containing 1500 cm/sup 3/ fresh water by means of mixing. The resulting dispersed mass remains at rest for 12 hours for purposes of hydration. Then 2 g of an anti-foaming agent dissolved in 6 cm/sup 3/ benzene is introduced to 1000 cm/sup 3/ modified calcium lignosulfonate produced by the above method.

  2. Gum forming olefinic precursors in motor gasoline: a model compound study

    Energy Technology Data Exchange (ETDEWEB)

    Nagpal, J.M.; Joshi, G.C.; Singh, J.; Rastogi, S.N. (Indian Institute of Petroleum, Dehradun (India))

    1994-01-01

    The source of the cracked components in motor gasoline are generally (Fluid Catalytic Cracking) FCC and thermal cracking naphthas incorporated in the gasoline pool. The FCC olefins are predominant in isostructures, while thermal cracking naphthas obtained from visbreaking and coking operations contain substantial amounts of cyclic structures. The contribution of various olefinic structures present in these naphthas are likely to vary. The gum forming tendencies of different types of olefinic structures have been studied by taking model compounds in a known sample matrix through potential gum measurements under accelerated test conditions. Peroxide number values have also been determined on aged sample. Cyclic and dicyclic structures have been found to contribute maximum, towards gum formation tendencies. Branching generally increases the gum formation. However, position of branching plays an important role besides the double bond. Synergistic effects of dienes with straight chain and branched olefins have also been studied. 11 refs., 10 figs., 2 tabs.

  3. Influence of non-edible vegetable based oil as cutting fluid on chip, surface roughness and cutting force during drilling operation of Mild Steel

    Science.gov (United States)

    Susmitha, M.; Sharan, P.; Jyothi, P. N.

    2016-09-01

    Friction between work piece-cutting tool-chip generates heat in the machining zone. The heat generated reduces the tool life, increases surface roughness and decreases the dimensional sensitiveness of work material. This can be overcome by using cutting fluids during machining. They are used to provide lubrication and cooling effects between cutting tool and work piece and cutting tool and chip during machining operation. As a result, important benefits would be achieved such longer tool life, easy chip flow and higher machining quality in the machining processes. Non-edible vegetable oils have received considerable research attention in the last decades owing to their remarkable improved tribological characteristics and due to increasing attention to environmental issues, have driven the lubricant industry toward eco friendly products from renewable sources. In the present work, different non-edible vegetable oils are used as cutting fluid during drilling of Mild steel work piece. Non-edible vegetable oils, used are Karanja oil (Honge), Neem oil and blend of these two oils. The effect of these cutting fluids on chip formation, surface roughness and cutting force are investigated and the results obtained are compared with results obtained with petroleum based cutting fluids and dry conditions.

  4. CENSUS AND STATISTICAL CHARACTERIZATION OF SOIL AND WATER QUALITY AT ABANDONED AND OTHER CENTRALIZED AND COMMERCIAL DRILLING-FLUID DISPOSAL SITES IN LOUISIANA, NEW MEXICO, OKLAHOMA, AND TEXAS

    Energy Technology Data Exchange (ETDEWEB)

    Alan R. Dutton; H. Seay Nance

    2003-06-01

    Commercial and centralized drilling-fluid disposal (CCDD) sites receive a portion of spent drilling fluids for disposal from oil and gas exploration and production (E&P) operations. Many older and some abandoned sites may have operated under less stringent regulations than are currently enforced. This study provides a census, compilation, and summary of information on active, inactive, and abandoned CCDD sites in Louisiana, New Mexico, Oklahoma, and Texas, intended as a basis for supporting State-funded assessment and remediation of abandoned sites. Closure of abandoned CCDD sites is within the jurisdiction of State regulatory agencies. Sources of data used in this study on abandoned CCDD sites mainly are permit files at State regulatory agencies. Active and inactive sites were included because data on abandoned sites are sparse. Onsite reserve pits at individual wells for disposal of spent drilling fluid are not part of this study. Of 287 CCDD sites in the four States for which we compiled data, 34 had been abandoned whereas 54 were active and 199 were inactive as of January 2002. Most were disposal-pit facilities; five percent were land treatment facilities. A typical disposal-pit facility has fewer than 3 disposal pits or cells, which have a median size of approximately 2 acres each. Data from well-documented sites may be used to predict some conditions at abandoned sites; older abandoned sites might have outlier concentrations for some metal and organic constituents. Groundwater at a significant number of sites had an average chloride concentration that exceeded nonactionable secondary drinking water standard of 250 mg/L, or a total dissolved solids content of >10,000 mg/L, the limiting definition for underground sources of drinking water source, or both. Background data were lacking, however, so we did not determine whether these concentrations in groundwater reflected site operations. Site remediation has not been found necessary to date for most abandoned

  5. Effects of calcination and activation conditions on ordered mesoporous carbon supported iron catalysts for production of lower olefins from synthesis gas

    NARCIS (Netherlands)

    Oschatz, M; van Deelen, T W; Weber, J L; Lamme, W S; Wang, G; Goderis, B; Verkinderen, O; Dugulan, A I; de Jong, K P

    2016-01-01

    Lower C2–C4 olefins are important commodity chemicals usually produced by steam cracking of naphtha or fluid catalytic cracking of vacuum gas oil. The Fischer–Tropsch synthesis of lower olefins (FTO) with iron-based catalysts uses synthesis gas as an alternative feedstock. Nanostructured carbon

  6. Synthetic lubricants based on copolymers of n-butyl methacrylate and α-olefins

    Directory of Open Access Journals (Sweden)

    Đakov Tatjana A.

    2002-01-01

    Full Text Available Synthetic fluids obtained by the copolymerization of α -olefins with alkyl esters of unsaturated carboxylic acids have a unique combination of properties of non-polar poly-a-olefins (PAOs and polar esters in a single molecule. These compounds are characterized by superior thermal, oxidative and hydrolytic stability, miscibility with mineral and synthetic base oils solubility of additives and neutral elastomer behavior. Depending on the molar masses and comonomer ratios in the copolymer molecule, synthetic fluids with a wide range of properties are obtained. These compounds are valuable components in lubricating oil formulations for different applications.

  7. Rh(III)-catalyzed olefination of N-sulfonyl imines: synthesis of ortho-olefinated benzaldehydes.

    Science.gov (United States)

    Zhang, Tao; Wu, Lamei; Li, Xingwei

    2013-12-20

    Rh(III)-catalyzed olefination of N-sulfonyl imines using acrylates and styrenes has been achieved for the synthesis of ortho-olefinated benaldehydes. This reaction proceeds via a chelation assisted C-H olefination/in situ hydrolysis process.

  8. A Promising Material by Using Residue Waste from Bisphenol A Manufacturing to Prepare Fluid-Loss-Control Additive in Oil Well Drilling Fluid

    Directory of Open Access Journals (Sweden)

    Zhi-Lei Zhang

    2013-01-01

    Full Text Available The residues mixture from Bisphenol A manufacturing process was analyzed. Fourier transform infrared (FTIR spectroscopy, gas chromatography-mass spectrometry (GC-MS, and nuclear magnetic resonance (NMR were used to characterize the residues. The results indicated that the residues were complex mixture of several molecules. 3-(2-Hydroxyphenyl-1,1,3-trimethyl-2,3-dihydro-1H-inden-5-ol and phenol were the main components of the residues. The technical feasibility of using it as phenol replacement in fluid-loss-control additive production was also investigated. The fluid-loss-control capacity of the novel additive was systematically investigated. It was discovered that the well fluid-loss performance of the prepared additive can be achieved, especially at high temperature.

  9. HYDRATE CORE DRILLING TESTS

    Energy Technology Data Exchange (ETDEWEB)

    John H. Cohen; Thomas E. Williams; Ali G. Kadaster; Bill V. Liddell

    2002-11-01

    The ''Methane Hydrate Production from Alaskan Permafrost'' project is a three-year endeavor being conducted by Maurer Technology Inc. (MTI), Noble, and Anadarko Petroleum, in partnership with the U.S. DOE National Energy Technology Laboratory (NETL). The project's goal is to build on previous and ongoing R&D in the area of onshore hydrate deposition. The project team plans to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope includes drilling and coring one well on Anadarko leases in FY 2003 during the winter drilling season. A specially built on-site core analysis laboratory will be used to determine some of the physical characteristics of the hydrates and surrounding rock. Prior to going to the field, the project team designed and conducted a controlled series of coring tests for simulating coring of hydrate formations. A variety of equipment and procedures were tested and modified to develop a practical solution for this special application. This Topical Report summarizes these coring tests. A special facility was designed and installed at MTI's Drilling Research Center (DRC) in Houston and used to conduct coring tests. Equipment and procedures were tested by cutting cores from frozen mixtures of sand and water supported by casing and designed to simulate hydrate formations. Tests were conducted with chilled drilling fluids. Tests showed that frozen core can be washed out and reduced in size by the action of the drilling fluid. Washing of the core by the drilling fluid caused a reduction in core diameter, making core recovery very difficult (if not impossible). One successful solution was to drill the last 6 inches of core dry (without fluid circulation). These tests demonstrated that it will be difficult to capture core when drilling in permafrost or hydrates without implementing certain safeguards. Among the coring tests was a simulated hydrate

  10. Trends in hydraulic fracturing distributions and treatment fluids, additives, proppants, and water volumes applied to wells drilled in the United States from 1947 through 2010: data analysis and comparison to the literature

    Science.gov (United States)

    Gallegos, Tanya J.; Varela, Brian A.

    2015-01-01

    Hydraulic fracturing is presently the primary stimulation technique for oil and gas production in low-permeability, unconventional reservoirs. Comprehensive, published, and publicly available information regarding the extent, location, and character of hydraulic fracturing in the United States is scarce. This national spatial and temporal analysis of data on nearly 1 million hydraulically fractured wells and 1.8 million fracturing treatment records from 1947 through 2010 (aggregated in Data Series 868) is used to identify hydraulic fracturing trends in drilling methods and use of proppants, treatment fluids, additives, and water in the United States. These trends are compared to the literature in an effort to establish a common understanding of the differences in drilling methods, treatment fluids, and chemical additives and of how the newer technology has affected the water use volumes and areal distribution of hydraulic fracturing. Historically, Texas has had the highest number of records of hydraulic fracturing treatments and associated wells in the United States documented in the datasets described herein. Water-intensive horizontal/directional drilling has also increased from 6 percent of new hydraulically fractured wells drilled in the United States in 2000 to 42 percent of new wells drilled in 2010. Increases in horizontal drilling also coincided with the emergence of water-based “slick water” fracturing fluids. As such, the most current hydraulic fracturing materials and methods are notably different from those used in previous decades and have contributed to the development of previously inaccessible unconventional oil and gas production target areas, namely in shale and tight-sand reservoirs. Publicly available derivative datasets and locations developed from these analyses are described.

  11. Development of new additive for drilling fluid from the partial hydrophobization N,N,N-trimethyl chitosan (TMC); Desenvolvimento de novos aditivos para fluidos de perfuracao a partir da hidrofobizacao parcial da N,N,N trimetilquitosana (TMQ)

    Energy Technology Data Exchange (ETDEWEB)

    Carmo, Thacyla C. do; Lopes, Grazielle; Silva, Joaquim F.M. da; Nascimento, Regina S.V., E-mail: cycyla@hotmail.co [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Polo de Xistoquimica

    2009-07-01

    N,N,N-trimethyl chitosan (TMC) hydrophobically modified can act as an excellent additive for drilling fluids water based, working as inhibitor of reactive shales and rheological modifiers. The cationic chitosan was obtained by reaction of chitosan with CH{sub 3}I in N-methyl-2-pyrrolidone to obtain the TMC and chitosan was also hydrophobically modified with palmitoil chloride to get Quit P. Through another route, Quit P was modified to obtain the cationic TMCP. The derivatives were characterized by FT-IR and {sup 1}HNMR spectrophotometry allowing the calculation of the degree of quaternization of the TMC. The rheology tests showed that the system with TMCP presented pseudo plastic behavior, while the system with TMC behaved as a Newtonian fluid. The results indicated that TMCP can act as rheology modifier for water-based drilling fluids. (author)

  12. Aerated drilling cutting transport analysis in geothermal well

    Science.gov (United States)

    Wakhyudin, Aris; Setiawan, Deni; Dwi Marjuan, Oscar

    2017-12-01

    Aeratad drilling widely used for geothermal drilling especially when drilled into predicted production zone. Aerated drilling give better performance on preventing lost circulation problem, improving rate of penetration, and avoiding drilling fluid invasion to productive zone. While well is drilled, cutting is produced and should be carried to surface by drilling fluid. Hole problem, especially pipe sticking will occur while the cutting is not lifted properly to surface. The problem will effect on drilling schedule; non-productive time finally result more cost to be spent. Geothermal formation has different characteristic comparing oil and gas formation. Geothermal mainly has igneous rock while oil and gas mostly sedimentary rock. In same depth, formation pressure in geothermal well commonly lower than oil and gas well while formation temperature geothermal well is higher. While aerated drilling is applied in geothermal well, Igneous rock density has higher density than sedimentary rock and aerated drilling fluid is lighter than water based mud hence minimum velocity requirement to transport cutting is larger than in oil/gas well drilling. Temperature and pressure also has impact on drilling fluid (aerated) density. High temperature in geothermal well decrease drilling fluid density hence the effect of pressure and temperature also considered. In this paper, Aerated drilling cutting transport performance on geothermal well will be analysed due to different rock and drilling fluid density. Additionally, temperature and pressure effect on drilling fluid density also presented to merge.

  13. Prediction of properties of new halogenated olefins using two group contribution approaches

    DEFF Research Database (Denmark)

    Montagud, Maria E. Mondejar; Cignitti, Stefano; Abildskov, Jens

    2017-01-01

    The increasingly restrictive regulations for substances with high ozone depletion and global warming potentials are driving the search for new sustainable fluids with low environmental impact. Recent research works have pointed out the great potential of fluorine- and chlorine-based olefins as re...

  14. Evaluation of some natural water-insoluble cellulosic material as lost circulation control additives in water-based drilling fluid

    Directory of Open Access Journals (Sweden)

    Ahmed Mohamed Alsabagh

    2015-12-01

    In this work, three natural water-insoluble cellulosic materials; peanut hulls, bagasse and sawdust were investigated as lost circulation control materials. One hundred and eight different LCM samples made of various materials were tested with mud. The experiments were conducted in a permeability plugging apparatus (PPA at a differential pressure of 100 psi and 300 psi, using 10, 60 and 90 ceramic discs. The performance of each LCM sample was determined based on the amount of spurt loss and total fluid loss of the mud according to the American Petroleum Institute (API standard. The obtained results showed that, the amount of the fluid loss depends on the LCM material, concentration and size distribution, testing results show that, the peanut gives the best results among the bagasse and sawdust, especially fine size which exhibited better results in the filtration characteristics due to the better filling properties of this size. Peanut hulls, bagasse and sawdust show a slight effect on the rheological properties of the mud. The results were discussed on light of particle size distribution.

  15. New Trends in Olefin Production

    Directory of Open Access Journals (Sweden)

    Ismaël Amghizar

    2017-04-01

    Full Text Available Most olefins (e.g., ethylene and propylene will continue to be produced through steam cracking (SC of hydrocarbons in the coming decade. In an uncertain commodity market, the chemical industry is investing very little in alternative technologies and feedstocks because of their current lack of economic viability, despite decreasing crude oil reserves and the recognition of global warming. In this perspective, some of the most promising alternatives are compared with the conventional SC process, and the major bottlenecks of each of the competing processes are highlighted. These technologies emerge especially from the abundance of cheap propane, ethane, and methane from shale gas and stranded gas. From an economic point of view, methane is an interesting starting material, if chemicals can be produced from it. The huge availability of crude oil and the expected substantial decline in the demand for fuels imply that the future for proven technologies such as Fischer-Tropsch synthesis (FTS or methanol to gasoline is not bright. The abundance of cheap ethane and the large availability of crude oil, on the other hand, have caused the SC industry to shift to these two extremes, making room for the on-purpose production of light olefins, such as by the catalytic dehydrogenation of propane.

  16. Buffer fluid

    Energy Technology Data Exchange (ETDEWEB)

    Mirzadzhanzade, A Kh; Dedusanko, G Ya; Dinaburg, L S; Markov, Yu M; Rasizade, Ya N; Rozov, V N; Sherstnev, N M

    1979-08-30

    A drilling fluid is suggested for separating the drilling and plugging fluids which contains as the base increased solution of polyacrylamide and additive. In order to increase the viscoelastic properties of the liquid with simultaneous decrease in the periods of its fabrication, the solution contains as an additive dry bentonite clay. In cases of the use of a buffer fluid under conditions of negative temperatures, it is necessary to add to it table salt or ethylene glycol.

  17. Alkylation of isobutane with light olefins: Yields of alkylates for different olefins

    Energy Technology Data Exchange (ETDEWEB)

    Albright, L.F. [Purdue Univ., West Lafayette, IN (United States); Kranz, K.E.; Masters, K.R. [STRATCO, Inc., Leawood, KS (United States)

    1993-12-01

    For alkylation of isobutane with C{sub 3}-C{sub 5} olefins using sulfuric acid as the catalyst, the yields of alkylates with different olefins are compared as the operating conditions are changed. The results of recent pilot plant experiments with propylene, C{sub 4} olefins, and C{sub 5} olefins permit such comparisons. The yields expressed as weight of alkylate produced per 100 wt of olefin consumed varied from about 201:100 to 220:100. Weight ratios of the isobutane consumed per olefin consumed vary from about 101:100 to 120:100. differences of yield values are explained by the changes in the overall chemistry. The procedure employed to calculate yields with good accuracy is based on the analysis of the alkylate and the amount of conjunct polymers produced. Based on literature data, yields are also reported for alkylations using HF as the catalyst.

  18. Production of olefins from bioethanol. Catalysts, mechanism

    Directory of Open Access Journals (Sweden)

    Kusman Dossumov

    2012-12-01

    Full Text Available This review describes methods of catalytic obtaining from bioethanol of valuable industrial products – olefins, particularly ethylene. Аmong olefins, ethylene is the most popular key raw material of petrochemical synthesis. The scope of appllication of ethylene is almost unlimited in petrochemical products: polyethylene, ethylbenzene, styrene, ethylene dichloride, vinyl chloride etc. It also examines catalysts for the production of olefins and their properties. The most promising and commercially advantageous process of ethylene production by catalytic dehydration of ethanol on catalysts based on modified alumina. And this review discusses the mechanisms of catalytic conversion of ethanol to ethylene.

  19. Bayesian spatial modeling applied to environmental monitoring due to the use of different drilling fluids in the maritime exploration activity; Modelagem espacial Bayesiana aplicada ao monitoramento ambiental decorrente do uso de diferentes fluidos de perfuracao na atividade exploratoria maritima

    Energy Technology Data Exchange (ETDEWEB)

    Pulgati, Fernando H. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Lab. de Modelagem de Bacias (LAB2M); Zouain, Ricardo N.A. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Inst. de Geociencias. Centro de Estudos de Geologia Costeira e Oceanica; Fachel, Jandyra M.G. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Inst. de Matematica; Landau, Luiz [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Lab. de Metodos Computacionais em Engenharia (LAMCE)

    2004-07-01

    Controlling and monitoring environmental researches have accompanied the development of offshore exploration drill activities aimed at finding oil and gas reserves, as there has been an increase in the environmental demands and restrictions. Three stages of the drilling process were isolated and the effects of different fluids were measured using Bayesian spatial models. The probable impact of the use of non-aqueous fluid (NAF) was measured through changes observed in sea sediments in three different occasions: previous to the activity, one (1) month after the end of the activity, and one (1) year after the end of the activity. BACI (Before-After Control Impact) design, which allows the control of temporal and spatial variation components, was chosen. (author)

  20. PDVSA INTEVEP Technologies in oil well drilling

    International Nuclear Information System (INIS)

    Bolivar, C.; Rafael, A.; Davila, Manuel A.

    1998-01-01

    The orimulsion, the generation of catalytic technologies and the development of HDH (process which transform heavy crudes in light crudes), are examples of some of the well known technologies developed by PDVSA INTEVEP. But the drilling oil wells technologies developed by the same entreprise, even though are very important, are less known all around the world. This document describes some products developed through those technologies: THIXOGAS T M which is an antimigratory aditive; INTEFLOW T M which is a fluid for drilling, complementation and rehabilitation of oil drills; INTERCAB T M which is an aditive for fluids in drilling; orimatita which is a denser for drilling fluids; CARBOLIG T M which is an aditive for drilling fluids; and many other products and technologies in development, impacted considerably the venezuelan economy by preserving the environment and saving quite an important amount of money in 1997 (Bs. 3.000 M M)

  1. Alternative Test Method for Olefins in Gasoline

    Science.gov (United States)

    This action proposes to allow for an additional alternative test method for olefins in gasoline, ASTM D6550-05. The allowance of this additional alternative test method will provide more flexibility to the regulated industry.

  2. Myoglobin-Catalyzed Olefination of Aldehydes.

    Science.gov (United States)

    Tyagi, Vikas; Fasan, Rudi

    2016-02-12

    The olefination of aldehydes constitutes a most valuable and widely adopted strategy for constructing carbon-carbon double bonds in organic chemistry. While various synthetic methods have been made available for this purpose, no biocatalysts are known to mediate this transformation. Reported herein is that engineered myoglobin variants can catalyze the olefination of aldehydes in the presence of α-diazoesters with high catalytic efficiency (up to 4,900 turnovers) and excellent E diastereoselectivity (92-99.9 % de). This transformation could be applied to the olefination of a variety of substituted benzaldehydes and heteroaromatic aldehydes, also in combination with different alkyl α-diazoacetate reagents. This work provides a first example of biocatalytic aldehyde olefination and extends the spectrum of synthetically valuable chemical transformations accessible using metalloprotein-based catalysts. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. (Z)-Selective Takai olefination of salicylaldehydes.

    Science.gov (United States)

    Geddis, Stephen M; Hagerman, Caroline E; Galloway, Warren R J D; Sore, Hannah F; Goodman, Jonathan M; Spring, David R

    2017-01-01

    The Takai olefination (or Takai reaction) is a method for the conversion of aldehydes to vinyl iodides, and has seen widespread implementation in organic synthesis. The reaction is usually noted for its high ( E )-selectivity; however, herein we report the highly ( Z )-selective Takai olefination of salicylaldehyde derivatives. Systematic screening of related substrates led to the identification of key factors responsible for this surprising inversion of selectivity, and enabled the development of a modified mechanistic model to rationalise these observations.

  4. Direct catalytic olefination of alcohols with sulfones.

    Science.gov (United States)

    Srimani, Dipankar; Leitus, Gregory; Ben-David, Yehoshoa; Milstein, David

    2014-10-06

    The synthesis of terminal, as well as internal, olefins was achieved by the one-step olefination of alcohols with sulfones catalyzed by a ruthenium pincer complex. Furthermore, performing the reaction with dimethyl sulfone under mild hydrogen pressure provides a direct route for the replacement of alcohol hydroxy groups by methyl groups in one step. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Drilling reorganizes

    Science.gov (United States)

    Richman, Barbara T.

    As the first in a proposed series of steps that would move scientific ocean drilling from its own niche within the National Science Foundation's (NSF) Directorate for Astronomical, Atmospheric, Earth, and Ocean Sciences (AAEO) into the agency's Division of Ocean Sciences, Grant Gross, division director, has been appointed acting director of the Office of Scientific Ocean Drilling (OSOD). Gross will retain the directorship of the division, which also is part of AAEO. Allen M. Shinn, Jr., OSOD director for nearly 2 years, has been reassigned effective July 10 to a position in NSF's Office of Planning and Resource Management.The move aims to tie drilling operations more closely to the science with which it is associated, Gross said. This first step is an organizational response to the current leaning toward using a commercial drilling vessel as the drilling platform, he said. Before the market for such commercial drill ships opened (Eos, February 22, 1983, p . 73), other ship options for scientific ocean drilling included refurbishing the aging Glomar Challenger or renovating, at great expense, the Glomar Explorer. A possible next step in the reorganization is to make OSOD the third section within the Ocean Sciences Division. Currently, the division is divided into the Oceanographic Facilities and Support Section and the Ocean Sciences Research Section.

  6. Numerical Modeling of Foam Drilling Hydraulics

    Directory of Open Access Journals (Sweden)

    Ozcan Baris

    2007-12-01

    Full Text Available The use of foam as a drilling fluid was developed to meet a special set of conditions under which other common drilling fluids had failed. Foam drilling is defined as the process of making boreholes by utilizing foam as the circulating fluid. When compared with conventional drilling, underbalanced or foam drilling has several advantages. These advantages include: avoidance of lost circulation problems, minimizing damage to pay zones, higher penetration rates and bit life. Foams are usually characterized by the quality, the ratio of the volume of gas, and the total foam volume. Obtaining dependable pressure profiles for aerated (gasified fluids and foam is more difficult than for single phase fluids, since in the former ones the drilling mud contains a gas phase that is entrained within the fluid system. The primary goal of this study is to expand the knowledge-base of the hydrodynamic phenomena that occur in a foam drilling operation. In order to gain a better understanding of foam drilling operations, a hydrodynamic model is developed and run at different operating conditions. For this purpose, the flow of foam through the drilling system is modeled by invoking the basic principles of continuum mechanics and thermodynamics. The model was designed to allow gas and liquid flow at desired volumetric flow rates through the drillstring and annulus. Parametric studies are conducted in order to identify the most influential variables in the hydrodynamic modeling of foam flow.

  7. Hydrogen sulfide removal in water-based drilling fluid by metal oxide nanoparticle and ZnO/TiO2 nanocomposite

    Science.gov (United States)

    Salehi Morgani, M.; Saboori, R.; Sabbaghi, S.

    2017-07-01

    Advanced approaches to the application of nanomaterials for environmental studies, such as waste-water treatment and pollution removal/adsorption, have been considered in recent decades. In this research, hydrogen sulfide removal from water-based drilling fluid by ZnO and TiO2 nanoparticles and a ZnO/TiO2 nanocomposite was studied experimentally. The ZnO and TiO2 nanoparticles were synthesized by sedimentation and the sol-gel method. A sol-chemical was employed to synthesize the ZnO/TiO2 nanocomposite. X-ray diffraction, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface analysis, inductively coupled plasma mass spectrometry (ICP), dynamic light scattering (DLS) and Fourier transform infrared spectroscopy were used to characterize the produced ZnO and TiO2 nanoparticles, and the ZnO/TiO2 nanocomposite. The results showed that the concentration of hydrogen sulfide decreased from 800 ppm to about 250 ppm (about 70% removal) and less than 150 ppm (more than 80% removal) using the TiO2 and ZnO nanoparticles with a 0.67 wt% concentration, respectively. Hydrogen sulfide removal using the ZnO/TiO2 nanocomposite with a 0.67 wt% showed the highest value of removal in comparison with the TiO2 and ZnO nanoparticles. The hydrogen sulfide level was lowered from 800 ppm to less than 5 ppm (99% removal) by the nanocomposite.

  8. Reduced abrasion drilling fluid = Reduced abrasion drilling fluid

    NARCIS (Netherlands)

    2010-01-01

    Se propoersiona un fluido de perforación de abarsividad reducida y un método de perforación de un hoyo en formaciones subterráneas haciendo circular un fluido de perforación de abrasividad reducida a través de este. El fluido de abarsividad reducida comprende un fluido de perforación, un primer

  9. Deep drilling KLX 02. Drilling and documentation of a 1700 m deep borehole at Laxemar, Sweden

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, O [VBB VIAK AB, Malmoe (Sweden)

    1994-08-01

    In this report the preparation and execution of the deep core drilling KLX 02 is described. The hole was drilled with the wireline methods, NQ dimension (diameter 76 mm), to a final depth of 1700.5 m. Prior to core drilling a diameter 215 mm pilot hole was pre drilled to 200 m with controlled hammer drilling (DTH). In this hole casing and air-lift equipment was installed with the aim to support the circulation of drilling fluid. During core drilling there was a measurement of major drilling parameters and drilling fluid in and out of hole. As a fluid tracer uranine was used. Each 300 m of core drilling air-lift pump tests were performed. After completion a flow-meter log was run to finalize the project phase. It can be concluded that both the pre drilling and core drilling methods used proved to be successful. No severe technical problem occurred. However, potential risks have been pointed at in the report. The air-lift system functioned only partly and has to be modified for further use. Also the technique for monitoring of drilling parameters needs improvement as does the method for air-lift pump tests with packer. The organisation model for planning and realization functioned satisfactory and can be recommended for similar future projects. 9 refs, numerous tabs and figs.

  10. Deep drilling KLX 02. Drilling and documentation of a 1700 m deep borehole at Laxemar, Sweden

    International Nuclear Information System (INIS)

    Andersson, O.

    1994-08-01

    In this report the preparation and execution of the deep core drilling KLX 02 is described. The hole was drilled with the wireline methods, NQ dimension (diameter 76 mm), to a final depth of 1700.5 m. Prior to core drilling a diameter 215 mm pilot hole was pre drilled to 200 m with controlled hammer drilling (DTH). In this hole casing and air-lift equipment was installed with the aim to support the circulation of drilling fluid. During core drilling there was a measurement of major drilling parameters and drilling fluid in and out of hole. As a fluid tracer uranine was used. Each 300 m of core drilling air-lift pump tests were performed. After completion a flow-meter log was run to finalize the project phase. It can be concluded that both the pre drilling and core drilling methods used proved to be successful. No severe technical problem occurred. However, potential risks have been pointed at in the report. The air-lift system functioned only partly and has to be modified for further use. Also the technique for monitoring of drilling parameters needs improvement as does the method for air-lift pump tests with packer. The organisation model for planning and realization functioned satisfactory and can be recommended for similar future projects. 9 refs, numerous tabs and figs

  11. Computerized tomography with X-rays: an instrument in the analysis physico-chemical between formations and drilling fluids interactions; Tomografia computadorizada com raios-X: uma ferramenta na analise das interacoes fisico-quimicas entre as formacoes rochosas e fluidos de perfuracao

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Marcus Vinicius Cavalcante

    1998-12-31

    In this study it is demonstrated the applicability of the Computerized Tomography technique with x-rays to evaluate the reactivity degree between various drilling fluids and argillaceous sediments (Shales and Sandstones). The research has been conducted in the Rock-Fluid Interaction Pressure Simulator (RFIPS), where the possible physico-chemical alterations can be observed through successive tomography images, which are obtained during the flow of the fluid through the samples. In addition, it was noticed the formation of mud cake in Berea Sandstones samples in the RFIPS, though the Computerized Tomography with X-rays, when utilizing drilling fluids weighted with the baryte. (author) 35 refs., 38 figs., 5 tabs.

  12. Computerized tomography with X-rays: an instrument in the analysis physico-chemical between formations and drilling fluids interactions; Tomografia computadorizada com raios-X: uma ferramenta na analise das interacoes fisico-quimicas entre as formacoes rochosas e fluidos de perfuracao

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Marcus Vinicius Cavalcante

    1999-12-31

    In this study it is demonstrated the applicability of the Computerized Tomography technique with x-rays to evaluate the reactivity degree between various drilling fluids and argillaceous sediments (Shales and Sandstones). The research has been conducted in the Rock-Fluid Interaction Pressure Simulator (RFIPS), where the possible physico-chemical alterations can be observed through successive tomography images, which are obtained during the flow of the fluid through the samples. In addition, it was noticed the formation of mud cake in Berea Sandstones samples in the RFIPS, though the Computerized Tomography with X-rays, when utilizing drilling fluids weighted with the baryte. (author) 35 refs., 38 figs., 5 tabs.

  13. The Marskhod Egyptian Drill Project

    Science.gov (United States)

    Shaltout, M. A. M.

    We describe a possible participation of Egypt in a future Mars rover Mission. It was suggested that Egypt participate through involvement in the design, building and testing of a drill to obtain sub-surface samples. The Space Research Institute of the Russian Academy of Sciences (IKI), formally invited the Egyptian Ministry of Scientific Research to study the concept for potential use on the Russian Mars 2001 Mission. As one of the objectives of the Marskhod mission was the analysis of sub-surface samples, a drilling mechanism in the payload would be essential. The Egyptian expertise in drill development is associated with the archaeological exploration of the Pyramids. A sophisticated drilling system perforated limestone to a depth of 2 m without the use of lubricants or cooling fluids that might have contaminated the Pit's environment. This experience could have been applied to a drill development Mars 2001 mission, which was unfortunately canceled due to economic problems.

  14. Desenvolvimento de fluidos aquosos com bentonita para perfuração de poços de petróleo onshore Development of aqueous fluids with bentonite clay for drilling of onshore oil wells

    Directory of Open Access Journals (Sweden)

    R. C. A. M Nascimento

    2010-06-01

    Full Text Available Devido aos grandes desafios encontrados na perfuração de poços, há a necessidade de se desenvolver fluidos com propriedades adequadas e capazes de atender todas as exigências da perfuração, como elevada capacidade de carreamento de sólidos e alta lubricidade, como também fluidos ambientalmente corretos. O grau de impacto dos fluidos de perfuração no meio ambiente depende especialmente do tipo de fluido utilizado, se de base aquosa, oleosa, sintética ou mesmo de base ar. Portanto, é de fundamental importância o desenvolvimento de fluidos com características específicas em cada etapa da perfuração. Sendo assim, este trabalho objetivou o desenvolvimento de fluidos aquosos, com baixo teor de sólidos e propriedades reológicas, de filtração e lubricidade adequadas à perfuração de poços de petróleo onshore. Os fluidos foram formulados utilizando em sua composição bentonita sódica industrializada, aditivos poliméricos e lubrificantes, em diferentes concentrações. O estudo reológico, de filtração e lubricidade mostrou que os fluidos apresentam comportamento pseudoplástico e que os aditivos selecionados desempenham com êxito suas funções de modificadores reológicos, redutores de filtrado e agente lubrificante. Além disto, ficou evidenciada a necessidade de aditivos lubrificantes em fluidos aquosos contendo argila bentonítica e polímeros. A adição de 1% de lubrificante no fluido é suficiente para adequar a capacidade lubrificante dos fluidos.Due to challenges encountered in drilling wells, there is a need to develop fluids that have properties suitable and able to meet all the requirements of drilling, such as, high capacity for carrying of solid and high lubricity. Besides that, they need to be environmentally friend. The degree of impact of drilling fluids in the environment depends on the type of fluid used, if water or oil or synthetic or air based. It is therefore of fundamental importance to develop

  15. Methods to ensure optimal off-bottom and drill bit distance under pellet impact drilling

    Science.gov (United States)

    Kovalyov, A. V.; Isaev, Ye D.; Vagapov, A. R.; Urnish, V. V.; Ulyanova, O. S.

    2016-09-01

    The paper describes pellet impact drilling which could be used to increase the drilling speed and the rate of penetration when drilling hard rock for various purposes. Pellet impact drilling implies rock destruction by metal pellets with high kinetic energy in the immediate vicinity of the earth formation encountered. The pellets are circulated in the bottom hole by a high velocity fluid jet, which is the principle component of the ejector pellet impact drill bit. The paper presents the survey of methods ensuring an optimal off-bottom and a drill bit distance. The analysis of methods shows that the issue is topical and requires further research.

  16. Synthesis of Fluoroolefins via Julia-Kocienski Olefination

    OpenAIRE

    Zajc, Barbara; Kumar, Rakesh

    2010-01-01

    The Julia-Kocienski olefination provides a versatile platform for the synthesis of fluorovinyl compounds. This review describes our efforts as well as those of others in the synthesis of various fluorinated aryl and heteroaryl sulfones and their utility as olefination reagents for the modular assembly of fluoroalkenes. Where data is available, the influence of the fluorine atom on the reactivity of the olefination reagents and the stereochemical outcome of the olefination are described.

  17. Synthesis of Fluoroolefins via Julia-Kocienski Olefination.

    Science.gov (United States)

    Zajc, Barbara; Kumar, Rakesh

    2010-01-01

    The Julia-Kocienski olefination provides a versatile platform for the synthesis of fluorovinyl compounds. This review describes our efforts as well as those of others in the synthesis of various fluorinated aryl and heteroaryl sulfones and their utility as olefination reagents for the modular assembly of fluoroalkenes. Where data is available, the influence of the fluorine atom on the reactivity of the olefination reagents and the stereochemical outcome of the olefination are described.

  18. Evaluation of polymers of different degrees viscosities as additives for drilling fluids for oil well; Avaliacao de polimeros de diferentes graus de viscosidades como aditivos para fluidos de perfuracao de pocos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Farias, K.V.; Amorim, L.V.; Silva, A.V. [Universidade Federal de Campina Grande (DEMa/UFCG), PB (Brazil); Lira, H.L. [Universidade Federal de Campina Grande (CCT/UFCG), PB (Brazil). Centro de Ciencias e Tecnologia. Unidade Academica de Engenharia de Materiais], e-mail: kassiefarias@gmail.com

    2008-07-01

    The objective of this work is to study the polymers influence of different degrees of viscosity, used as viscositying and filtered reducer additives, in the rheological, filtration and lubricity properties of drilling fluids for oil wells. Were determined the rheological behavior, the apparent and plastic viscosities, the yield limit and gel force, the filtered volume and the lubricity coefficient in accordance with API standard. The fluids showed pseudoplastic behavior with properties close to the standard fluid; the increase of viscositying and filtered reducer concentrations lead to the increase of rheological properties and the filtered reducer values, from the concentration of 3,5g/350mL of water it acted as viscositying, increasing the values of apparent and plastic viscosities, yield limit and gel force, being 3,0g/350mL of water the adequate concentration of this additive, promoting better results of rheological and filtration properties. (author)

  19. Catalytic olefin polymerization with early transition metal compounds

    NARCIS (Netherlands)

    Eshuis, Johan Jan Willem

    1991-01-01

    The catalysis of organic reactions by soluble metal complexes has become a major tool in synthesis, both in the laboratory and in the chemical industry. Processes catalyzed by transition metal complexes include carbonylation, olefin polymerization, olefin addition, olefin oxidation and alkane and

  20. Olefin copolymerization using atom transfer radical polymerization (ATRP)

    NARCIS (Netherlands)

    Venkatesh, R.; Klumperman, B.

    2003-01-01

    Olefin copolymers of alpha-olefins with polar monomers with various architectures remain an ultimate goal in polyolefin engineering. The present paper is a more detailed study on the copolymn. of alpha-olefins (1-octene) with acrylates (Me acrylate). Comparison of reaction kinetics between free

  1. Gamma radiolysis of 3-methylpentane. Effect of added olefins on the formation of C12-olefins

    International Nuclear Information System (INIS)

    Laet, M. de; Tilquin, B.

    1991-01-01

    Contributions of congruent (parent derived) olefins to the formation of unsaturated heavy products (C 12 H 24 ) are investigated. Effects of dose or of olefinic additives on the G yield values are studied by capillary gas chromatography. The dose dependence is explained by transfer of positive charge to congruent olefins (C 6 H 12 ) even though their concentrations build up linearly with dose. γ Irradiation of 3-methylpentane containing pentenes or butenes (0.2-2 mol %) provides good examples of transfer of energy, however the results are unexpected. C-H scission in the radiolysis of solid 3-methylpentane is also reviewed. (author)

  2. Relation between structure and properties of modified starches. Application to the formulation of non-polluting drilling fluids; Relation structure/proprietes d'amidons modifies. Application a la formulation de fluides de forage non polluants

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, I.

    1999-12-06

    Starch is a polymeric carbohydrate derivative with anhydro-glucose units and is extracted from the tissues of certain plants. In its native form, starch granule is non soluble in cold water and therefore most applications need a cooking period in the presence of an excess of water. The cooking treatment is therefore associated with large changes in viscosity. Overall, starch suspensions properties are strongly influenced by starch botanical origins, shearing and heating conditions under which they are prepared. Their properties can be modulated though chemical modifications depending on their uses in the petroleum industry. This study focuses on the relations between structure and physico-chemical, rheological and filtration properties of modified starches. These starches are originated from native potato, i. e. hydroxy-propyl and/or crosslinked starches above or below the gelatinization temperature. The samples were characterised in terms of swelling capacity, average granule size distribution and molecular weight. Microscopic methods were used to investigate starch structure. Relations were established between the rheological properties and the physico-chemical parameters. These properties are governed by the deformability and rigidity parameters as a function of the concentration. The best samples were then chosen and were submitted to the high temperature (140 deg. C - 160 deg. C), high shearing (16000 tr/ mn) and salinity (CaCl{sub 2}, 1M). The physico-chemical and rheological studies showed that the starch system which is crosslinked below the gelatinization temperature is more resistant that the samples crosslinked above the gelatinization temperature. Then, a drilling fluid formulation was investigated. The filtration results evidenced an increase of the cake permeability in the presence of starch particles but the good stability of these samples permits their uses for high temperature. Thus, non crosslinked / crosslinked starch mixtures were investigated

  3. Relation between structure and properties of modified starches. Application to the formulation of non-polluting drilling fluids; Relation structure/proprietes d'amidons modifies. Application a la formulation de fluides de forage non polluants

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, I

    1999-12-06

    Starch is a polymeric carbohydrate derivative with anhydro-glucose units and is extracted from the tissues of certain plants. In its native form, starch granule is non soluble in cold water and therefore most applications need a cooking period in the presence of an excess of water. The cooking treatment is therefore associated with large changes in viscosity. Overall, starch suspensions properties are strongly influenced by starch botanical origins, shearing and heating conditions under which they are prepared. Their properties can be modulated though chemical modifications depending on their uses in the petroleum industry. This study focuses on the relations between structure and physico-chemical, rheological and filtration properties of modified starches. These starches are originated from native potato, i. e. hydroxy-propyl and/or crosslinked starches above or below the gelatinization temperature. The samples were characterised in terms of swelling capacity, average granule size distribution and molecular weight. Microscopic methods were used to investigate starch structure. Relations were established between the rheological properties and the physico-chemical parameters. These properties are governed by the deformability and rigidity parameters as a function of the concentration. The best samples were then chosen and were submitted to the high temperature (140 deg. C - 160 deg. C), high shearing (16000 tr/ mn) and salinity (CaCl{sub 2}, 1M). The physico-chemical and rheological studies showed that the starch system which is crosslinked below the gelatinization temperature is more resistant that the samples crosslinked above the gelatinization temperature. Then, a drilling fluid formulation was investigated. The filtration results evidenced an increase of the cake permeability in the presence of starch particles but the good stability of these samples permits their uses for high temperature. Thus, non crosslinked / crosslinked starch mixtures were investigated

  4. Semi-industrial production of organo clays to use in base oil drilling fluid; Producao em escala piloto de argilas organofilicas visando uso em fluidos de perfuracao base oleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Heber S.; Martins, Alice B.; Costa, Danubia L. da; Ferreira, Heber C.; Neves, Gelmires de A.; Melo, Tomas J.A. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Teixeira Neto, Erico [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil)

    2008-07-01

    The drilling fluids are essential to the operations of exploration of oil. The organoclays are widely used in the composition of the oil based drilling fluids and raw materials are of high value added. These clays can be obtained, traditionally, from bentonitic clay treated, in water, with ionic surfactants, however, non-ionic surfactants can be adsorbed on the surface of interlamelar bentonitic clay, naturally hydrophilic, making them organophilic. A pilot plant for production of organoclays was mounted in the Recycling Laboratory / UFCG. The bentonitic clay imported Cloisite Na{sup +R} was treated with a non-ionic surfactant in levels of 40, 50 and 60% in scale and bench-scale pilot. The commercial organoclay VG-69{sup R} was used as a standard for comparison of results. The clay obtained were characterized by X-ray diffraction, and Foster's swelling. The oil based fluids were prepared in accordance with the standards of PETROBRAS (N-22581 1997 and N-2259, 1997). Tests show that the characterization of organoclays have obtained intercalation of non-ionic surfactant with great expansion of layers of clay, with interlayer distances more significant than the clay trade, both on clay obtained in the laboratory scale as in clays obtained by pilot scale, with results very similar for both methods. It appears that it is possible the pilot-scale production of organoclays with equivalent quality produced in the laboratory scale and quality compatible with the clay used commercially. (author)

  5. Drilling rig

    Energy Technology Data Exchange (ETDEWEB)

    Galiopa, A A; Yegorov, E K

    1981-01-04

    A drilling rig is proposed which contains a tower, lifter in the form of n infinite chain, and mobile rotator with holding device connected to the chain, and pipe holder. In order to accelerate the auxiliary operations to move the drilling string and unloaded rotator, the rotator is equipped with a clamp with means for transverse connection of it to both branches of the chain, while the pipe holders equipped with a clamp with means of connecting it to one of the branches of the chain.

  6. Drilling mud

    Energy Technology Data Exchange (ETDEWEB)

    Rusayev, A A; Bibikov, K V; Simonenkov, I D; Surkova, K I

    1982-01-01

    Drilling mud is proposed which contains clay, water, water output reducer, pH regulator, viscosity reducer and hydrogen sulfide absorber. In order to improve the absorbing capacity of the drilling mud with pH 8-11 and simultaneously preservation of the technological properties of the mud, it contains as the absorber of hydrogen sulfide pyrite cinders with the following ratio of components, % by mass: clay 5.0-35.0; water output reducer 0.2-2.0; pH regulator 0.05-0.25; viscosity reducer 0.1-1.0; pyrite cinders 0.5-4.0; water--the rest.

  7. Olefin metathesis in nano-sized systems

    Directory of Open Access Journals (Sweden)

    Denise Méry

    2011-01-01

    Full Text Available The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade. Two subjects are presented and discussed: (i The catalysis of olefin metathesis by dendritic nano-catalysts via either covalent attachment (ROMP or, more usefully, dendrimer encapsulation – ring closing metathesis (RCM, cross metathesis (CM, enyne metathesis reactions (EYM – for reactions in water without a co-solvent and (ii construction and functionalization of dendrimers by CM reactions.

  8. (Z-Selective Takai olefination of salicylaldehydes

    Directory of Open Access Journals (Sweden)

    Stephen M. Geddis

    2017-02-01

    Full Text Available The Takai olefination (or Takai reaction is a method for the conversion of aldehydes to vinyl iodides, and has seen widespread implementation in organic synthesis. The reaction is usually noted for its high (E-selectivity; however, herein we report the highly (Z-selective Takai olefination of salicylaldehyde derivatives. Systematic screening of related substrates led to the identification of key factors responsible for this surprising inversion of selectivity, and enabled the development of a modified mechanistic model to rationalise these observations.

  9. The FCC process as a producer of light olefins

    International Nuclear Information System (INIS)

    Yung, K.Y.; Yanik, S.; O'Connor, P.; Pouwels, C.

    1992-01-01

    To reduce emissions from the gasoline engine, aromatics content and vapor pressure of the motor gasoline pool will be reduced and a minimum amount of oxygen will be mandated. This reformulation will limit the application of high octane components like benzene, toluene and butanes and will require the use of oxygenates. To compensate for the loss in octane, the use of alkylate and, of course also oxygenates will grow. The Fluid Catalytic Cracking Unit is, as producer of (olefinic) propanes, butanes and pentanes, an important feedstock producer for alkylate and oxygenate producing process. Hence, process adjustments and FCC catalyst formations to increase the yield of above desirable light products are of prime importance and will be dealt with in this paper

  10. Olefin Recovery from Chemical Industry Waste Streams

    Energy Technology Data Exchange (ETDEWEB)

    A.R. Da Costa; R. Daniels; A. Jariwala; Z. He; A. Morisato; I. Pinnau; J.G. Wijmans

    2003-11-21

    The objective of this project was to develop a membrane process to separate olefins from paraffins in waste gas streams as an alternative to flaring or distillation. Flaring these streams wastes their chemical feedstock value; distillation is energy and capital cost intensive, particularly for small waste streams.

  11. Cyclic olefin copolymer-silica nanocomposites foams

    Czech Academy of Sciences Publication Activity Database

    Pegoretti, A.; Dorigato, A.; Biani, A.; Šlouf, Miroslav

    2016-01-01

    Roč. 51, č. 8 (2016), s. 3907-3916 ISSN 0022-2461 R&D Projects: GA MŠk(CZ) LO1507 Institutional support: RVO:61389013 Keywords : cyclic olefin copolymer * nanocomposites * silica Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.599, year: 2016

  12. Synthesis of pterostilbene by Julie Olefination

    Science.gov (United States)

    A simple, stereoselective route for the synthesis of the biologically active compounds trans-pterostilbene and tetramethoxy stilbene from the readily available starting materials 3,5-dimethoxy benzyl alcohol and 4-hydroxy benzaldehyde was developed using Julia olefination as a key reaction....

  13. Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process

    International Nuclear Information System (INIS)

    Xiang, Dong; Qian, Yu; Man, Yi; Yang, Siyu

    2014-01-01

    Highlights: • Present the opportunities and challenges of coal-to-olefins (CTO) development. • Conduct a techno-economic analysis on CTO compared with oil-to-olefins (OTO). • Suggest approaches for improving energy efficiency and economic performance of CTO. • Analyze effects of plant scale, feedstock price, CO 2 tax on CTO and OTO. - Abstract: Olefins are one of the most important oil derivatives widely used in industry. To reduce the dependence of olefins industry on oil, China is increasing the production of olefins from alternative energy resources, especially from coal. This study is concerned with the opportunities and obstacles of coal-to-olefins development, and focuses on making an overall techno-economic analysis of a coal-to-olefins plant with the capacity of 0.7 Mt/a olefins. Comparison is made with a 1.5 Mt/a oil-to-olefins plant based on three criteria including energy efficiency, capital investment, and product cost. It was found that the coal-based olefins process show prominent advantage in product cost because of the low price of its feedstock. However, it suffers from the limitations of higher capital investment, lower energy efficiency, and higher emissions. The effects of production scale, raw material price, and carbon tax were varied for the two production routes, and thus the operational regions were found for the coal-to-olefins process to be competitive

  14. Progress in reducing the environmental impacts of offshore drilling wastes

    International Nuclear Information System (INIS)

    Flemming, D; Candler, J.E.

    2002-01-01

    Full text:Over the past several years, great progress has been made in understanding and reducing the environmental impacts of offshore drilling wastes. Our understanding of sea floor impacts has been helped along by new environmental assessment tools such us computer modeling of sea floor deposition of drilling discharges, sediment profile imaging, and in situ sediment toxicity bioassays. To further reduce environmental impacts, new pollution prevention technologies have been developed that can shrink the environmental footprint of offshore drilling. These technologies reduce the total amount of drilling wastes discharged and include cuttings dryers and centrifuges that can reduce the drilling fluid content of drill cuttings to below 10 percent. In conclusion, the oil and gas industry is adopting more environmentally compatible drilling fluids, new environmental assessment tools and pollution prevention technologies that dramatically reduce the amount of drilling wastes discharged. Together, all of these elements have the potential to reduce environmental impacts of offshore drilling

  15. Drilling mud

    Energy Technology Data Exchange (ETDEWEB)

    Babets, M A; Nechayev, N D; Vinogradova, G P

    1982-01-01

    A drilling mud is proposed which contains clay, alkali, water and stabilizer reagent. It is distinguished by the fact that in order to improve the viscosity and static shear stress, the stabilizer reagent contained is composted solid general wastes with the following ratio of components (% by weight): clay 10-15, alkali 0.1-0.2; composted solid general wastes 2-5; water--the rest.

  16. Bucket drill

    Energy Technology Data Exchange (ETDEWEB)

    Bezverkhiy, V.M.; Nabokov, I.M.; Podoksik, D.Z.; Sadovskiy, S.S.; Shanyukevich, V.A.

    1983-01-01

    The bucket drill including a cylindrical housing with bottom, ground intake windows and cutting knives is hinged to the housing, the mechanism of rotation of the cutting knives including rods connected by the cutter knives, and drive shaft is distinguished by the fact that in order to improve the effectiveness of drilling by automatic change in the angle of cutting depending on the strength of the drillable rock, the drill is equipped with elastic elements and cap with annular slits in which there are elastic elements. The mechanism of rotation of the cutting knives is equipped with levers hinged to the housing, pins with shaft and rocker arm. The rods are made with a slit and from one end are rigidly connected to the cutting knives, and from the other end to the levers by means of pins which are arranged in slits of the rod with the possibility of movement. The upper ends of the levers are installed with the possibility of movement in the pins whose shafts are arranged with the possibility of rotation in the rocker arm rigidly connected to the drive shaft. The drive shaft is equipped with cantilevers installed in the cap with the possibility of rotation and interaction with the elastic elements.

  17. High Temperature 300°C Directional Drilling System

    Energy Technology Data Exchange (ETDEWEB)

    Chatterjee, Kamalesh [Baker Hughes Oilfield Operations, Houston, TX (United States); Aaron, Dick [Baker Hughes Oilfield Operations, Houston, TX (United States); Macpherson, John [Baker Hughes Oilfield Operations, Houston, TX (United States)

    2015-07-31

    Many countries around the world, including the USA, have untapped geothermal energy potential. Enhanced Geothermal Systems (EGS) technology is needed to economically utilize this resource. Temperatures in some EGS reservoirs can exceed 300°C. To effectively utilize EGS resources, an array of injector and production wells must be accurately placed in the formation fracture network. This requires a high temperature directional drilling system. Most commercial services for directional drilling systems are rated for 175°C while geothermal wells require operation at much higher temperatures. Two U.S. Department of Energy (DOE) Geothermal Technologies Program (GTP) projects have been initiated to develop a 300°C capable directional drilling system, the first developing a drill bit, directional motor, and drilling fluid, and the second adding navigation and telemetry systems. This report is for the first project, “High Temperature 300°C Directional Drilling System, including drill bit, directional motor and drilling fluid, for enhanced geothermal systems,” award number DE-EE0002782. The drilling system consists of a drill bit, a directional motor, and drilling fluid. The DOE deliverables are three prototype drilling systems. We have developed three drilling motors; we have developed four roller-cone and five Kymera® bits; and finally, we have developed a 300°C stable drilling fluid, along with a lubricant additive for the metal-to-metal motor. Metal-to-metal directional motors require coatings to the rotor and stator for wear and corrosion resistance, and this coating research has been a significant part of the project. The drill bits performed well in the drill bit simulator test, and the complete drilling system has been tested drilling granite at Baker Hughes’ Experimental Test Facility in Oklahoma. The metal-to-metal motor was additionally subjected to a flow loop test in Baker Hughes’ Celle Technology Center in Germany, where it ran for more than 100

  18. Coiled tubing drilling with supercritical carbon dioxide

    Science.gov (United States)

    Kolle , Jack J.

    2002-01-01

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  19. Synthesis of polyisoprene and its evaluation as reducer of flow loss temperature of paraffinic drilling fluid; Sintese de poliisopreno e sua avaliacao como redutor da temperatura de perda de fluidez de fluido de perfuracao parafinico

    Energy Technology Data Exchange (ETDEWEB)

    Palermo, Luiz Carlos; Pires, Renata V.; Sant' Anna, Monica; Cardoso, Jaciene J.F.; Lucas, Elizabete F. [Universidade Federal do Rio de Janeiro/ Instituto de Macromoleculas/ Laboratorio de Macromoleculas e Coloides na Industria de Petroleo, Rio de Janeiro, RJ (Brazil)], e-mail: luizpalermo@ima.ufrj.br

    2011-07-01

    N-paraffin fluids are widely used in drilling oil wells. However, under low temperature, such as those found in deep water, they lose their ability to flow due to solidification of paraffins. In order to keep the fluid flowing, isoparaffins are added to fluids. Nevertheless, the safety of the process is affected, due to its low flash point, especially during the storage in platforms offshore. This paper aims to obtain polymeric additives that can reduce the flow loss temperature of the n-paraffin fluid, replacing the isoparaffin, without affecting its rheological properties. So, oligomers/polymers based on isoprene were synthesized and the rheological behavior of the products and their mixtures with n-paraffin, as a function of decreasing temperature, was evaluated. Products from chemical degradation of natural rubber (NR) were also evaluated. The results showed that samples presenting relatively low molar mass, about 5,000 g/mol, exhibited good performance. When obtaining product by polymerization, a chain transfer agent must be used. (author)

  20. Study of the stability of sugar Ester and its application potential with additives in the drilling fluids; Estudo da estabilidade do ester de acucar e sua potencial aplicacao como aditivo em fluido de perfuracao

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, Suzan I.G.; Costa, Marta; Macedo, Sinara P.N. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    This work describe the enzymatic synthesis of the glucose ester starting from fatty acid, using protease Bacillus subtilis as biologic catalyst. The efficiency of ester has determined through the surface tension analyses in different pH (2-12), temperature (25-100 deg C) and salinity (50-115 g/L of NaCl). For a better understanding as for the applicability of the ester of sugar in drilling fluids, it was done necessary to know the values of interfacial tension of the oil/water; in that analysis, the mineral oil was investigated as oily phase and, as aqueous phase, biosurfactant solution. The results of interfacial tension of the water/oil and biosurfactant /oil they allowed to quantify us the influence of the benefactor's front to an organic phase, because the same made a significant reduction the interfacial tension of 26,0725 mN/m (water/oil) or 1,7527 mN/m (biosurfactant aqueous solution/oil). D-glucose ester was shown stable in different concentrations of NaCl, pH and temperature, and efficient in the reduction of the superficial tension of the water (of 72 mN/m for 28 mN/m). Preliminary test reveal that the ricinoleoil of D-glucose presents functionality as lubricant for drilling fluids to the base water. In the studied formulations, the obtained composition reduces the coefficient of lubricity of 0,20 for 0,04 and it stabilizes the fluid, reducing the volume of the filtrate of 5,0 mL for 3,4 mL. (author)

  1. ResonantSonic drilling. Innovative technology summary report

    International Nuclear Information System (INIS)

    1995-04-01

    The technology of ResonantSonic drilling is described. This technique has been demonstrated and deployed as an innovative tool to access the subsurface for installation of monitoring and/or remediation wells and for collection of subsurface materials for environmental restoration applications. The technology uses no drilling fluids, is safe and can be used to drill slant holes

  2. Drilling mud

    Energy Technology Data Exchange (ETDEWEB)

    Baranovskiy, V D; Brintsev, A I; Gusev, V G; Katenev, Ye P; Pokhorenko, I V

    1979-10-25

    A drilling mud is proposed, which contains a dispersion medium, a dispersion phase, for instance, clay, a stabilizer reagent, for instance, carboxymethylcellulose and a weighter. In order to reduce the viscosity and to increase the stability of the mud it contains as the dispersion medium a 75% aqueous solution of the L-7 reagent. To increase the salt resistance of the mud, it additionally contains sodium chloride in a volume of 4.04.5 percent by weight, and to regulate the alkalinity, it additionally contains sodium hydroxide in a volume of 1.1 to 1.3 percent by weight.

  3. Catalytic olefin polymerization with early transition metal compounds

    OpenAIRE

    Eshuis, Johan Jan Willem

    1991-01-01

    The catalysis of organic reactions by soluble metal complexes has become a major tool in synthesis, both in the laboratory and in the chemical industry. Processes catalyzed by transition metal complexes include carbonylation, olefin polymerization, olefin addition, olefin oxidation and alkane and arene oxidation. Traditionally, heterogeneous catalysts have been used for the production of large-scale commodity chemicals such as methanol and ammonia and in the production of high octane gasoline...

  4. Conversion of olefins to liquid motor fuels

    Science.gov (United States)

    Rabo, Jule A.; Coughlin, Peter K.

    1988-01-01

    Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

  5. Thermal 18F atom addition to olefins

    International Nuclear Information System (INIS)

    Rogers, P.J.M.

    1986-01-01

    The addition of thermal 18 F atoms to olefins was investigated using various substrate molecules. The 18 F atoms were produced by the 19 F(n,2n) 18 F nuclear reaction with >10 5 eV of energy which is removed by multiple collisions with SF 6 molecules before reaction occurs with an olefin. By varying the SF 6 /substrate mole ratio it was demonstrated that the fraction of non-thermal reactions is dependent upon the frequency of non-reactive energy reducing collisions with SF 6 . The rate constants for addition and abstraction reactions with propene, cis-1-chloropropene and trans-1-chloropropene were determined. The substitution of a C1 atom for the olefinic H atom in the C 1 position does not affect the rate of 18 F bond formation but it changes the orientation of attack. The 18 F atom prefers the terminal carbon-in propene and propene-d 6 by a factor of 1.35 while the preference is less than 0.5 for the terminal carbon in cis-1-chloropropene and trans-1-chloropropene. The addition of 18 F atoms to olefins creates vibrationally excited fluoroalkyl radicals which can either decompose or stabilize by collision with another molecule. The rate constants for decomposition of excited CH 3 CHCHC1F radicals formed by 18 F addition to cis-1-chloropropene and trans-1-chloropropene are competitive with C 1 -C 2 bond rotation. The 18 F atoms add to the parent molecule with retention of geometry and a memory of the geometry persists as demonstrated by the cis-1-fluoropropene/trans-1-fluoropropene decomposition product ratio

  6. Application of MRIL-WD (Magnetic Resonance Imaging Logging While Drilling) for irreducible water saturation, total reservoir, free-fluid, bound-fluid porosity measurements and its value for the petrophysical analysis of RT/RM data from the Shah Deniz well

    Science.gov (United States)

    Amirov, Elnur

    2016-04-01

    Sperry-Sun (Sperry Drilling Services) is the leader in MWD/LWD reliability, has developed the industry's first LWD NMR/MRIL-WD (nuclear magnetic resonance) tool. The MRIL-WD (magnetic resonance imaging logging-while-drilling) service directly measures the T1 component of hydrogen in subsurface rock units while drilling to obtain total reservoir porosity and to dissect the observed total porosity into its respective components of free fluid and bound fluid porosity. These T1 data are used to secure accurate total, free-fluid, capillary-bound water, and clay-bound water porosity of the reservoir sections which can be drilled in the several Runs. Over the last decade, results from Magnetic Resonance Imaging logs (NMR) have added significant value to petrophysical analysis and understanding by providing total, free-fluid and bound-fluid porosities, combined with fluid typing capabilities. With MRIL-WD very valuable Real-Time or Recorded Memory data/information is now available during or shortly after the drilling operation (formation properties measurement can be taken right after a drill bit penetration), while trip in and trip out as well. A key point in utilizing MRIL in an LWD environment is motion-tolerant measurements. Recent MRIL-WD logging runs from the Shah Deniz wells located in the Khazarian-Caspian Sea of the Azerbaijan Republic helped to delineate and assess hydrocarbon bearing zones. Acquired results demonstrate how MRIL data can be acquired while-drilling and provide reliable/high quality measurements. Magnetic Resonance Imaging logs at some developments wells have become a cornerstone in formation evaluation and petrophysical understanding. By providing total, free-fluid, and bound-fluid porosities together with fluid typing, MRIL results have significantly added to the assessment of reservoirs. In order to reduce NPT (Non-Productive Time) and save the rig operations time, there is always the desire to obtain logging results as soon as possible

  7. Olefin recovery from FCC off-gas can pay off

    International Nuclear Information System (INIS)

    Brahn, M.G.

    1992-01-01

    This paper reports on olefins recovery from refinery FCC offgas streams which offers an attractive cash flow from olefins from a tail-gas stream that has typically been consumed as refinery fuel. Such recovery schemes can be employed in refineries or olefins plants, and can be tailored to fit individual requirements. Mobil Chemical Co. has operated such a dephlegmator-based off-gas recovery unit at its Beaumont, Tex., olefin plant since 1987. It reported that the project was paid out within 11 months of initial start-up

  8. Rhodium-catalyzed regioselective olefination directed by a carboxylic group.

    Science.gov (United States)

    Mochida, Satoshi; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro

    2011-05-06

    The ortho-olefination of benzoic acids can be achieved effectively through rhodium-catalyzed oxidative coupling with alkenes. The carboxylic group is readily removable to allow ortho-olefination/decarboxylation in one pot. α,β-Unsaturated carboxylic acids such as methacrylic acid also undergo the olefination at the β-position. Under the rhodium catalysis, the cine-olefination of heteroarene carboxylic acids such as thiophene-2-carboxylic acid proceeds smoothly accompanied by decarboxylation to selectively produce the corresponding vinylheteroarene derivatives. © 2011 American Chemical Society

  9. The olefin metathesis reaction: reorganization and cyclization of organic compounds

    International Nuclear Information System (INIS)

    Frederico, Daniel; Brocksom, Ursula; Brocksom, Timothy John

    2005-01-01

    The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene. This reaction has found extensive application in the last ten years with the development of the Grubbs and Schrock catalysts, in total synthesis of complex organic molecules, as opposed to the very important use in the petrochemical industry with relatively simple molecules. This review intends to trace a historical and mechanistic pathway from industry to academy, before illustrating the more recent advances. (author)

  10. Application of Zeolitic Additives in the Fluid Catalytic Cracking (FCC

    Directory of Open Access Journals (Sweden)

    A. Nemati Kharat

    2013-06-01

    Full Text Available Current article describes application of zeolites in fluid catalytic cracking (FCC. The use of several zeolitic additives for the production light olefins and reduction of pollutants is described. Application of zeolites as fluid catalytic cracking (FCC catalysts and additives due to the presence of active acid sites in the zeolite framework  increase the formation of desired cracking products (i.e., olefin and branched products  in the FCC unit.

  11. Alternative routes to olefins. Chances and challenges

    Energy Technology Data Exchange (ETDEWEB)

    Meiswinkel, A.; Delhomme, C.; Ponceau, M. [Linde AG, Pullach (Germany)

    2013-11-01

    In the future, conventional raw materials which are used for the production of olefins will get shorter and more expensive and alternative raw materials and production routes will gain importance. Natural gas, coal, shale oil or bio-mass are potential sources for the production of olefins, especially ethylene and propylene, as major base chemicals. Several potential production routes were already developed in the past, but cost, energy and environmental considerations might make these unattractive or unfeasible in comparison to traditional processes (e.g. steam cracking). Other processes such as methanol to olefins processes were successfully developed and first commercial units are running. In addition, combination of traditional processes (e.g. coal/biomass gasification, Fischer-Tropsch and steam cracking) might enable new pathways. Besides, dehydration of ethanol is opening direct routes from biomass to 'green' ethylene. However, for these 'bio-routes', feedstock availability and potential land use conflict with food production (sugar cane, wheat,..) still need to be evaluated. finally, new oxidative routes, including processes such as oxidative coupling of methane or oxidative dehydrogenation, are still at an early development stage but present potential for future industrial applications. (orig.) (Published in summary form only)

  12. Use of organoclays obtained with nonionic surfactants for drilling fluids base organic; O uso de argilas organofilicas obtidas com tensoativo nao-ionico para fluidos de perfuracao base organica

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, F.K.A. [Universidade Federal de Campina Grande (UATEC/UFCG), PB (Brazil). Unidade Academica de Tecnologia do Desenvolvimento], e-mail: kegealves@ufcg.edu.br; Neves, G.A.; Ferreira, H.C.; Silva, A.L. [Universidade Federal de Campina Grande (UFCG/UAEMa), PB (Brazil). Unidade Academica de Engenharia de Materiais; Campos, L.F.A. [Departamento de Engenharia de Materiais, DEMat/CCT/UFPB, PB (Brazil)

    2010-07-01

    This paper aims to use the compositions of organo clays obtained with nonionic surfactant for drilling fluids organic base containing additives, emulsifiers, brine, activator, reducer filtered, adensante and evaluate their rheological, filtration and electrical stability. Were studied through the mixture delineament, ten compositions of organo clays, and its performance is evaluated by means of the rheological behavior (flow curves, GI, GF, VA, VP and LE) and the tests recommended by API (PE, EE and VF). The results were compared with the standard PETROBRAS and showed that among the developed compositions, two compositions showed promising that met most of the properties and use the clay of inferior quality (Bofe and Verde-lodo) in greater quantity and minimum clay Chocolate UBM, considered the best clay in the region mines Boa Vista, PB. (author)

  13. Dewatering cuts drilling mud and disposal costs

    International Nuclear Information System (INIS)

    West, G.; Pharis, B.

    1991-01-01

    This paper reports on rig site dewatering of drilling fluids with recycling of processed water that can help an operator to comply with environmental rules by reducing volumes of waste and reducing long term liabilities. It can also reduce disposal costs and provide a cleaner drill site overall. Rig site dewatering is the process of injecting coagulants or flocculating chemicals into the mud entering a large clarifying centrifuge. This coagulates the fine, drilled particles allowing them to be separated from the fluid which can then be handled separately. Most of the environmental concerns during the 1980s involved hazardous materials and toxic wastes. Drilling fluids, many of which are chemically benign, have escaped many of the difficult-to-comply-with rules and regulations. During the 1990s, however, operators may be required to submit a written plan for liquid waste reduction for even nonhazardous materials. Many states and local agencies may institute total bans on oil field wastes. Drilling rigs typically produce about 1 bbl of liquid waste for every 1 ft of hole drilled. Thus, a typical drilling operation can produce a large quantity of waste

  14. Surface-enhanced light olefin yields during steam cracking

    NARCIS (Netherlands)

    Golombok, M.; Kornegoor, M.; Brink, van den P.; Dierickx, J.; Grotenbreg, R.

    2000-01-01

    Various papers have shown enhanced olefin yields during steam cracking when a catalytic surface is introduced. Our studies reveal that increased light olefin yields during catalytic steam cracking are mainly due to a surface volume effect and not to a traditional catalytic effect. Augmentation of

  15. Alkylation of isobutane with light olefins catalyzed by zeolite beta

    NARCIS (Netherlands)

    Nivarthy, G.S.; Feller, A.P.; Seshan, Kulathuiyer; Lercher, J.A.

    2000-01-01

    Alkylation of isobutane with ethene and propene was studied over an H-BEA catalyst in a well-stirred reactor. Under similar conditions of space velocity and paraffin-to-olefin feed ratio, lower initial olefin conversions were observed with ethene or propene than those reported earlier for butene.

  16. Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates.

    Science.gov (United States)

    Chary, Bathoju Chandra; Kim, Sunggak

    2013-09-25

    Rhodium(iii)-catalyzed C-H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamide directing group.

  17. An evaluation of calculation procedures affecting the constituent factors of equivalent circulating density for drilling hydraulics

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, William J

    1997-12-31

    This Dr. ing. thesis covers a study of drilling hydraulics offshore. The purpose of drilling hydraulics is to provide information about downhole pressure, suitable surface pump rates, the quality of hole cleaning and optimum tripping speeds during drilling operations. Main fields covered are drilling hydraulics, fluid characterisation, pressure losses, and equivalent circulating density. 197 refs., 23 figs., 22 tabs.

  18. 30 CFR 250.414 - What must my drilling prognosis include?

    Science.gov (United States)

    2010-07-01

    ...) Projected plans for logging; (c) Planned safe drilling margin between proposed drilling fluid weights and... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What must my drilling prognosis include? 250... OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations...

  19. An evaluation of calculation procedures affecting the constituent factors of equivalent circulating density for drilling hydraulics

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, William J.

    1996-12-31

    This Dr. ing. thesis covers a study of drilling hydraulics offshore. The purpose of drilling hydraulics is to provide information about downhole pressure, suitable surface pump rates, the quality of hole cleaning and optimum tripping speeds during drilling operations. Main fields covered are drilling hydraulics, fluid characterisation, pressure losses, and equivalent circulating density. 197 refs., 23 figs., 22 tabs.

  20. Carbonyl-Olefin Exchange Reaction: Present State and Outlook

    Science.gov (United States)

    Kalinova, Radostina; Jossifov, Christo

    The carbonyl-olefin exchange reaction (COER) is a new reaction between carbonyl group and olefin double bond, which has a formal similarity with the olefin metathesis (OM) - one carbon atom in the latter is replaced with an oxygen atom. Till now the new reaction is performed successfully only when the two functional groups (carbonyl group and olefin double bond) are in one molecule and are conjugated. The α, β-unsaturated carbonyl compounds (substituted propenones) are the compounds with such a structure. They polymerize giving substituted polyacetylenes. The chain propagation step of this polymerization is in fact the COER. The question arises: is it possible the COER to take place when the two functional groups are not in one molecule and are not conjugated, and could this reaction became an alternative of the existing carbonyl olefination reactions?

  1. Hydraulics calculation in drilling simulator

    Science.gov (United States)

    Malyugin, Aleksey A.; Kazunin, Dmitry V.

    2018-05-01

    The modeling of drilling hydraulics in the simulator system is discussed. This model is based on the previously developed quasi-steady model of an incompressible fluid flow. The model simulates the operation of all parts of the hydraulic drilling system. Based on the principles of creating a common hydraulic model, a set of new elements for well hydraulics was developed. It includes elements that correspond to the in-drillstring and annular space. There are elements controlling the inflow from the reservoir into the well and simulating the lift of gas along the annulus. New elements of the hydrosystem take into account the changing geometry of the well, loss in the bit, characteristics of the fluids including viscoplasticity. There is an opportunity specify the complications, the main one of which is gas, oil and water inflow. Correct work of models in cases of complications makes it possible to work out various methods for their elimination. The coefficients of the model are adjusted on the basis of incomplete experimental data provided by operators of drilling platforms. At the end of the article the results of modeling the elimination of gas inflow by a continuous method are presented. The values displayed in the simulator (drill pipe pressure, annulus pressure, input and output flow rates) are in good agreement with the experimental data. This exercise took one hour, which is less than the time on a real rig with the same configuration of equipment and well.

  2. Newberry exploratory slimhole: Drilling and testing

    Energy Technology Data Exchange (ETDEWEB)

    Finger, J.T.; Jacobson, R.D.; Hickox, C.E.

    1997-11-01

    During July--November, 1995, Sandia National Laboratories, in cooperation with CE Exploration, drilled a 5,360 feet exploratory slimhole (3.895 inch diameter) in the Newberry Known Geothermal Resource Area (KGRA) near Bend, Oregon. This well was part of Sandia`s program to evaluate slimholes as a geothermal exploration tool. During and after drilling the authors performed numerous temperature logs, and at the completion of drilling attempted to perform injection tests. In addition to these measurements, the well`s data set includes: over 4,000 feet of continuous core (with detailed log); daily drilling reports from Sandia and from drilling contractor personnel; daily drilling fluid record; and comparative data from other wells drilled in the Newberry KGRA. This report contains: (1) a narrative account of the drilling and testing, (2) a description of equipment used, (3) a brief geologic description of the formation drilled, (4) a summary and preliminary interpretation of the data, and (5) recommendations for future work.

  3. Catalytic Cracking of Triglyceride-Rich Biomass toward Lower Olefins over a Nano-ZSM-5/SBA-15 Analog Composite

    Directory of Open Access Journals (Sweden)

    Xuan Hoan Vu

    2015-10-01

    Full Text Available The catalytic cracking of triglyceride-rich biomass toward C2–C4 olefins was evaluated over a hierarchically textured nano-ZSM-5/SBA-15 analog composite (ZSC-24 under fluid catalytic cracking (FCC conditions. The experiments were performed on a fully automated Single-Receiver Short-Contact-Time Microactivity Test unit (SR-SCT-MAT, Grace Davison at 550 °C and different catalyst-to-oil mass ratios (0–1.2 g∙g−1. The ZSC-24 catalyst is very effective for transformation of triglycerides to valuable hydrocarbons, particularly lower olefins. The selectivity to C2–C4 olefins is remarkably high (>90% throughout the investigated catalyst-to-oil ratio range. The superior catalytic performance of the ZSC-24 catalyst can be attributed to the combination of its medium acid site amount and improved molecular transport provided by the bimodal pore system, which effectively suppresses the secondary reactions of primarily formed lower olefins.

  4. Study of rock-drilling fluid interactions that contribute for the borehole instability; Estudo das interacoes rocha-fluido de perfuracao que contribuem para a instabilidade dos pocos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Correa, Cleysson C.; Nascimento, Regina S.V. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Inst. de Quimica; Sa, Carlos H. de [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    In this work it was developed a new three points flexural mechanical test submersed for the simultaneous evaluation of the mechanical and chemical nature processes involved in the rock/drilling fluid interactions, which contribute for the borehole instability. The utilized fluids were air, mineral oil, distilled water and water solutions of non hydrolized polyacrylamide, poly(diallyldimethylammonium chloride) with different molecular weights, and the copolymer with acrylamide. Cuttings rolling tests were utilized to help in the understanding of the mechanisms involved in the shale's inhibition process. The results suggest that shale/polymer interactions are responsible for the shale's mechanical resistance, since the quantity of water and total carbon content of the shales were the same, after the test, independently of the inhibitor used. The results also suggest that the shale instability depends on the amount of adsorbed water, since independently of the inhibitor utilized, the quantity of adsorbed water was the same as that obtained with the shale/water system. (author)

  5. Avoiding pollution in scientific ocean drilling

    International Nuclear Information System (INIS)

    Francis, T.J.G.

    1999-01-01

    Scientific ocean drilling has been carried out in the world's oceans since the nineteen sixties. From 1968-83 the Deep Sea Drilling Project (DSDP), managed by the Scripps Institution of Oceanography in California under a contract with the US National Science Foundation, employed the drilling vessel Glomar Challenger for this purpose. In January 1985 the Ocean Drilling Program (GDP), operated by Texas A and M University, began operations with the drillship JOIDES Resolution which continue to this day. The principal funding agency remains the US National Science Foundation, but since its inception GDP has been an international program and currently receives financial support from 21 countries. The ODP operates globally and, as with DSDP before it, drills without a riser or blowout preventer in a wide range of geological environments. Water depths at GDP drill sites have ranged from 38 m to 5969 m, but are typically within the range 1000-5000 m. Depths of penetration at GDP drill sites, while generally less than 1000 m, have ranged up to 2111 m below the sea floor. The drilling fluid is seawater, although occasional slugs of mud are circulated to clean or condition the hole. Thus drilling is carried out without well control, i.e. without the ability to control pressures within the well. Because of the absence of well control, it is vital to ensure that the drillship does not drill into an accumulation of oil or gas. Drilling into a charged reservoir and causing oil or gas to escape into the marine environment is recognised as the main pollution hazard in scientific ocean drilling

  6. CASING DRILLING TECHNOLOGY

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2005-12-01

    Full Text Available Casing drilling is an alternative option to conventional drilling and uses standard oilfield casing instead of drillstring. This technology is one of the greatest developments in drilling operations. Casing drilling involves drilling and casing a well simultaneously. In casing driling process, downhole tools can be retrieved, through the casing on wire-line, meaning tool recovery or replacement of tools can take minutes versus hours under conventional methods. This process employs wireline-retrievable tools and a drill-lock assembly, permitting bit and BHA changes, coring, electrical logging and even directional or horizontal drilling. Once the casing point is reached, the casing is cemented in place without tripping pipe.

  7. Cutting and drill fluids destruction by electro-coagulation: a new technological option. Eliminacion de fluidos de corte y taladrinas por electrocoagulacion: una nueva alternativa tecnologia

    Energy Technology Data Exchange (ETDEWEB)

    Alava, J.I.; Ipinaza, E.; Ortiz de Urbina, G.; Mugica, J.C.; Yurramendi, L.; Labarta, C.; Solazabal, R. (Centro Tecnologico de Materiales, San Sebastian (Spain))

    1994-01-01

    With the aim of comparison between incoming technologies, that use electro coagulation as a method for cutting fluids elimination, some restricted conditions have been selected that, equalized the feature of different electro technologies. It has been also specifically selected, those treatments, that are starting-up in the industrial environment. The comparison shows the efficiency of the destruction of organic compounds (until 98%) and equalized his environmental advantages and disadvantages. (Author) 10 refs. (Author)

  8. Rhodium(I) catalysis in olefin photoreactions

    International Nuclear Information System (INIS)

    Salomon, R.G.; El Sanadi, N.

    1975-01-01

    The photorearrangement (254 nm) of 1,5-cyclooctadiene (1) in the presence of rhodium(I) chloride to give 1,4-cyclooctadiene (4) was found by deuterium labeling to involve an intramolecular [1,3] shift of hydrogen. A rate-determining cleavage of an allylic C--H bond is indicated by a deuterium isotope effect, k/sub H//k/sub D/ = 1.55 +- 0.03 for the 1 → 4 rearrangement. The acyclic 1,5-diene, 3,3-dimethyl-1,5-hexadiene (8), rearranges in the presence of rhodium(I) chloride upon uv irradiation (254 nm) to give cis-3,3-dimethyl-1,4-hexadiene (10) and the trans isomer 11 in a 1:4 ratio, respectively. This observation supports a mechanism for the photorearrangement of olefins catalyzed by rhodium(I) involving an initial photodissociation of one of two rhodium(I) coordinated carbon-carbon double bonds. This results in an increase in the coordinative unsaturation of rhodium(I) and enhances the proclivity of this d/sub s/ metal atom toward oxidative addition of an allylic C--H bond. A eta 3 -allylrhodium hydride intermediate then gives rearranged olefin by reductive elimination. Lastly, a novel photochemical, rhodium(I) catalyzed hydrogen transfer is reported which gives cyclooctene (7) from cyclooctadienes under unprecedentedly mild conditions. (auth)

  9. A method for producing lower olefins

    Energy Technology Data Exchange (ETDEWEB)

    Lemayev, N.V.; Grigorovich, V.A.; Isayev, V.A.; Liakumovich, A.G.; Mitrofanov, A.I.; Orekhov, A.I.; Trifonov, S.V.; Vernov, P.A.

    1983-01-01

    In the known method for producing lower olefins by pyrolysis of a hydrocarbon raw material in the presence of an initiator which contains ammonia, in order to increase the output of the target products, morpholine or piperidine are additionally introduced into the initiator in a volume of 0.00001 to 0.1 percent each, converted for the raw material. The compounds to be added may be introduced into the pyrolysis zone by dissolving them in the hydrocarbon raw material or in water, which forms vapors with dilution of the raw material being subjected to pyrolysis. The increase in the outputs of the lower olefins in the process through the use of additives may be explained by the synergistic effect of the mixture of ammonia, morpholine and piperidine used. With benzine pyrolysis without the additives the output of ethylene is 24.1 percent; in comparable conditions with additives of ammonia or morpholine alone, or of piperidine alone, the outputs are 24.0, 26.2 and 25.8 percent, respectively. With the joint presence of ammonia and piperidine, the output of ethylene reaches 27.2 percent and with the addition of ammonia and morpholine, it reaches 27.4 percent.

  10. Microbial community stratification controlled by the subseafloor fluid flow and geothermal gradient at the Iheya North hydrothermal field in the Mid-Okinawa Trough (Integrated Ocean Drilling Program Expedition 331).

    Science.gov (United States)

    Yanagawa, Katsunori; Breuker, Anja; Schippers, Axel; Nishizawa, Manabu; Ijiri, Akira; Hirai, Miho; Takaki, Yoshihiro; Sunamura, Michinari; Urabe, Tetsuro; Nunoura, Takuro; Takai, Ken

    2014-10-01

    The impacts of lithologic structure and geothermal gradient on subseafloor microbial communities were investigated at a marginal site of the Iheya North hydrothermal field in the Mid-Okinawa Trough. Subsurface marine sediments composed of hemipelagic muds and volcaniclastic deposits were recovered through a depth of 151 m below the seafloor at site C0017 during Integrated Ocean Drilling Program Expedition 331. Microbial communities inferred from 16S rRNA gene clone sequencing in low-temperature hemipelagic sediments were mainly composed of members of the Chloroflexi and deep-sea archaeal group. In contrast, 16S rRNA gene sequences of marine group I Thaumarchaeota dominated the microbial phylotype communities in the coarse-grained pumiceous gravels interbedded between the hemipelagic sediments. Based on the physical properties of sediments such as temperature and permeability, the porewater chemistry, and the microbial phylotype compositions, the shift in the physical properties of the sediments is suggested to induce a potential subseafloor recharging flow of oxygenated seawater in the permeable zone, leading to the generation of variable chemical environments and microbial communities in the subseafloor habitats. In addition, the deepest section of sediments under high-temperature conditions (∼90°C) harbored the sequences of an uncultivated archaeal lineage of hot water crenarchaeotic group IV that may be associated with the high-temperature hydrothermal fluid flow. These results indicate that the subseafloor microbial community compositions and functions at the marginal site of the hydrothermal field are highly affected by the complex fluid flow structure, such as recharging seawater and underlying hydrothermal fluids, coupled with the lithologic transition of sediments. Copyright © 2014, American Society for Microbiology. All Rights Reserved.

  11. Production and use of light olefins. Preprints of the conference

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, S.; Buzzoni, R.; Leitner, W.; Lercher, J.A.; Lichtscheidl, J.; Nees, F.; Santacesaria, E. (eds.)

    2009-07-01

    Within the conference of the German Society for Petroleum and Coal Science and Technology e.V. (Hamburg, Federal Republic of Germany) in Berlin (Federal Republic of Germany) at 28th to 30th September, 2009, the following lectures were held: (1) Steamcracking - State of the Art (H. Zimmermann); (2) Diversify Feedstock Options to Olefin Production (Q. Ling et al.); (3) Syngas to lower olefins (E. Schwab et al.); (4) STAR process registered for the on-purpose production of propylene (K. Bueker); (5) The catalytic activity of zinc oxide supported on aerosil for C-H activation of light alkanes (S. Arndt et al.); (6) Novel catalytic approaches for the oxidative dehydrogenation of ethane (D. Hartmann); (7) A comparison of the active sites structures of homogeneous and heterogeneous olefin polymerisation catalysts (A. Zecchina); (8) Catalytic strategies in metathesis (C. Coperet); (9) Multi-technology integrated production and consumption of olefins (J. Popp et al.); (10) Olefin oligomerization for the production of fuels and petrochemicals (H. Olivier-Bourbigou et al.); (11) Dieselization of the world - How to increase diesel yield in a refinery (A. Dueker); (12) Isomerization of butenes: LyondellBasell's Isomplus technology development (T. Zak et al.); (13) Valuable products from butadiene, carbon dioxide and further base chemicals (A. Behr); (14) The partial oxidation of propene to propylene oxide using N{sub 2}O as an oxidant (T. Thoemmes); (15) Alternative feedstocks for olefin production: What role will ethanol play? (B.R. Maughon); (16) Production of light olefins from renewable resources - The effect of deoxygenation degree on yields of light olefins (D. Kubicka et al.); (17) Recovery of low olefins from refinery offgases (M. Bender).

  12. Radioactive tracer system to indicate drill bit wear or failure

    International Nuclear Information System (INIS)

    Fries, B.A.

    1975-01-01

    A radioactive tracer system for indicating drill bit wear or failure utilizing radioactive krypton 85 in clathrate form, in the form of water-soluble kryptonates, or dissolved grease, is described. Preferably the radioactive krypton is placed so that when drill bit wear or failure occurs, the radioactive krypton 85 is relased and effectively becomes diffused in the circulating drilling fluid. At the surface, the radioactive krypton 85 gas is separated from the circulating drilling fluid by gas-mud separating means and is transported as a gas to a counting chamber where an accurate radioactivity count of beta rays released from the krypton is obtained. (Patent Office Record)

  13. SAXS observation of structural evolution of heated olefin

    International Nuclear Information System (INIS)

    Sun Minhua; Mou Hongchen; Wang Yuxi; Li Demin; Wang Aiping; Ma Congxiao; Cheng Weidong; Wang Dan; Liu Jia

    2007-01-01

    Structural evolution of olefin during its heating process was observed with SAXS method at Beijing Synchrotron Radiation Facility. The mean square fluctuation of electron density increased from 468.5 nm -2 at 22 degree C to 2416 nm -2 at 100 degree C, while the electronic gyration radius decreased from 11.61 nm at 22 degree C to 11.16 nm at 100 degree C. Therefore, the olefin softens as a result of the increased thermal motion of the molecules, rather than the shrinking size of fundamental structural units of olefin. (authors)

  14. Reactions of dihydridotetrakis(triphenylphosphine)ruthenium(II) with olefins and isolation of new ruthenium-olefin complexes

    International Nuclear Information System (INIS)

    Komiya, Sanshiro; Yamamoto, Akio

    1976-01-01

    Dihydridotetrakis(triphenylphosphine)ruthenium (II), RuH 2 (PPh 3 ) 4 , reacts with olefins (ethylene, propylene, stylene and butadiene) to give olefin-coordinated complexes of the type, Ru(olefin)(PPh 3 ) 3 and equimolar amounts of their hydrogenation products per mol of the dihydride complex. The olefin coordinated with ruthenium can be exchanged with other olefins. Olefin-coordinated complexes easily react with molecular hydrogen to afford tetrahydridotris(triphenylphosphine)ruthenium, RuH 4 (PPh 3 ) 3 , releasing alkane at room temperature, Under hydrogen atmosphere catalytic hydrogenation of the olefins smoothly takes place with RuH 2 (PPh 3 ) 4 . (Ethylene)tris(triphenylphosphine)ruthenium(0) reacts with methyl iodide to give propylene and a trace of butadiene along with methane, ethylene, and small amounts of ethane and butenes. The formation of propylene suggests that oxidative addition involving cleavage of the C-H bond of ethylene to ruthenium giving a hydridovinyl complex may be taking place. Reactions of Ru(C 2 H 4 )(PPh 3 ) 3 with methyl-d 3 iodide and ethyl iodide, and of Ru(C 3 H 6 )(PPh 3 ) 3 with methyl iodide were examined to test the generality of this type of reaction. The reaction of Ru(C 2 H 4 )(PPh 3 ) 3 with CD 3 I released CD 4 and CD 2 H 2 together with CD 3 H suggesting the involvement of α-hydrogen abstraction. (auth.)

  15. Percolation experiments to determine fluid-matrix interaction (with particular regard to pretreatment of the drill core); Kerndurchstroemungsversuche zur Ermittlung von Fluid-Matrix-Wechselwirkungen (unter besonderer Beruecksichtigung der Kernvorbehandlung)

    Energy Technology Data Exchange (ETDEWEB)

    Martin, M; Seibt, A [TU Bergakademie Freiberg (Germany). Inst. fuer Bohrtechnik und Fluidbergbau; Hoth, P [GeoForschungsZentrum Potsdam (Germany)

    1997-12-01

    The injection of fluids into sandstone reservoirs leads to interactions between these waters, the reservoir rocks, and the formation fluids. Estimations about possible permeability reducing processes caused by these interactions are therefore of great importance for the exploitation of sandstone aquifers as geothermal reservoirs. Percolation experiments under in situ conditions with core samples from North German geothermal boreholes were done in order to investigate these fluid-rock interactions. (orig./AKF) [Deutsch] Die Injektion von Fluiden in Aquiferspeicher fuehrt zu Wechselwirkungen zwischen dem Speichergestein, den Formationsfluiden und den injizierten Loesungen. Fuer die Bewirtschaftung der Speicher sind insbesondere Kenntnisse ueber moegliche Permeabilitaetsreduzierungen durch diese Wechselwirkungen von Bedeutung. Mit Hilfe von Kern-Durchstroemungsexperimenten, durchgefuehrt unter lagerstaettenaehnlichen Bedingungen mit Original- bzw. modifizierten Fluiden, wurde daher das Durchstroemungsverhalten von unterschiedlich ausgebildeten Reservoirsandsteinen aus norddeutschen Geothermiebohrungen untersucht. (orig./AKF)

  16. Robotic Planetary Drill Tests

    Science.gov (United States)

    Glass, Brian J.; Thompson, S.; Paulsen, G.

    2010-01-01

    Several proposed or planned planetary science missions to Mars and other Solar System bodies over the next decade require subsurface access by drilling. This paper discusses the problems of remote robotic drilling, an automation and control architecture based loosely on observed human behaviors in drilling on Earth, and an overview of robotic drilling field test results using this architecture since 2005. Both rotary-drag and rotary-percussive drills are targeted. A hybrid diagnostic approach incorporates heuristics, model-based reasoning and vibration monitoring with neural nets. Ongoing work leads to flight-ready drilling software.

  17. Cobalt catalyzed hydroesterification of a wide range of olefins

    Energy Technology Data Exchange (ETDEWEB)

    Van Rensburg, H.; Hanton, M.; Tooze, R.P.; Foster, D.F. [Sasol Technology UK, St Andrews (United Kingdom)

    2011-07-01

    Petrochemical raw materials are an essential raw material for the production of detergents with a substantial portion of synthetic fatty alcohols being produced via hydroformylation of oil or coal derived olefins. Carbonylation processes other than hydroformylation have to date not been commercially employed for the production of fatty esters or alcohols. In this document we highlight the opportunities of converting olefins to esters using cobalt catalyzed alkoxycarbonylation. This process is highly versatile and applicable to a wide range of olefins, linear or branched, alpha or internal in combination with virtually any chain length primary or secondary alcohol allowing the synthesis of a diverse array of compounds such as ester ethoxylated surfactants, methyl branched detergents, lubricants and alkyl propanoates. Furthermore, alkoxycarbonylation of a broad olefin/paraffin hydrocarbon range could be used to produce the corresponding broad cut detergent alcohols. (orig.)

  18. Olefin Metathesis in Peptidomimetics, Dynamic Combinatorial Chemistry, and Molecular Imprinting

    National Research Council Canada - National Science Library

    Low, Tammy K

    2006-01-01

    .... Our research goals consisted of employing olefin metathesis in the synthesis of peptidomimetics, and studying the feasibility of this method in dynamic combinatorial chemistry and molecular imprinting of nerve agents...

  19. Olefin copolymerization via reversible addition-fragmentation chain transfer

    NARCIS (Netherlands)

    Venkatesh, R.; Staal, B.B.P.; Klumperman, B.

    2004-01-01

    Successful statistical copolymn. of an a-olefin (1-octene) with an acrylate (Bu acrylate, BA) and with a methacrylate (Me methacrylate, MMA), employing reversible addn.-fragmentation chain transfer (RAFT) mediated polymn. has been accomplished

  20. Direct observation of OH production from the ozonolysis of olefins

    Science.gov (United States)

    Donahue, Neil M.; Kroll, Jesse H.; Anderson, James G.; Demerjian, Kenneth L.

    Ozone olefin reactions may be a significant source of OH in the urban atmosphere, but current evidence for OH production is indirect and contested. We report the first direct observation of OH radicals from the reaction of ozone with a series of olefins (ethene, isoprene, trans-2-butene and 2,3 dimethyl-2-butene) in 4-6 torr of nitrogen. Using LIF to directly observe the steady-state of OH produced by the initial ozone-olefin reaction and subsequently destroyed by the OH-olefin reaction, we are able to establish OH yields broadly consistent with indirect values. The identification of the OH is unequivocal, and there is no indication that it is produced by a secondary process. To support these observations, we present a complete ab-initio potential energy surface for the O3-ethene reaction, extending from the reactants to available products.

  1. Olefins and chemical regulation in Europe: REACH.

    Science.gov (United States)

    Penman, Mike; Banton, Marcy; Erler, Steffen; Moore, Nigel; Semmler, Klaus

    2015-11-05

    REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) is the European Union's chemical regulation for the management of risk to human health and the environment (European Chemicals Agency, 2006). This regulation entered into force in June 2007 and required manufacturers and importers to register substances produced in annual quantities of 1000 tonnes or more by December 2010, with further deadlines for lower tonnages in 2013 and 2018. Depending on the type of registration, required information included the substance's identification, the hazards of the substance, the potential exposure arising from the manufacture or import, the identified uses of the substance, and the operational conditions and risk management measures applied or recommended to downstream users. Among the content developed to support this information were Derived No-Effect Levels or Derived Minimal Effect Levels (DNELs/DMELs) for human health hazard assessment, Predicted No Effect Concentrations (PNECs) for environmental hazard assessment, and exposure scenarios for exposure and risk assessment. Once registered, substances may undergo evaluation by the European Chemicals Agency (ECHA) or Member State authorities and be subject to requests for additional information or testing as well as additional risk reduction measures. To manage the REACH registration and related activities for the European olefins and aromatics industry, the Lower Olefins and Aromatics REACH Consortium was formed in 2008 with administrative and technical support provided by Penman Consulting. A total of 135 substances are managed by this group including 26 individual chemical registrations (e.g. benzene, 1,3-butadiene) and 13 categories consisting of 5-26 substances. This presentation will describe the content of selected registrations prepared for 2010 in addition to the significant post-2010 activities. Beyond REACH, content of the registrations may also be relevant to other European activities, for

  2. Study for increasing micro-drill reliability by vibrating drilling

    International Nuclear Information System (INIS)

    Yang Zhaojun; Li Wei; Chen Yanhong; Wang Lijiang

    1998-01-01

    A study for increasing micro-drill reliability by vibrating drilling is described. Under the experimental conditions of this study it is observed, from reliability testing and the fitting of a life-distribution function, that the lives of micro-drills under ordinary drilling follow the log-normal distribution and the lives of micro-drills under vibrating drilling follow the Weibull distribution. Calculations for reliability analysis show that vibrating drilling can increase the lives of micro-drills and correspondingly reduce the scatter of drill lives. Therefore, vibrating drilling increases the reliability of micro-drills

  3. Olefin Metathesis in Peptidomimetics, Dynamic Combinatorial Chemistry, and Molecular Imprinting

    Science.gov (United States)

    2006-08-01

    organic, and biochemistry, lectured in chemistry of weapons, and researched on ionic liquids and nucleic acid derivatives. She discovered her joy of...Products from oligomerization of the dimer scaffold or olefin isomerization are excluded from these projected numbers.97,98 The number of...Figure 3-8). This is excluding any olefin isomerization products or oligomerization of the cyclic scaffold. If stereoisomers are considered, then

  4. The Hans Tausen drill

    DEFF Research Database (Denmark)

    Johnsen, Sigfus Johann; Dahl-Jensen, Dorthe; Steffensen, Jørgen Peder

    2007-01-01

    In the mid-1990s, excellent results from the GRIP and GISP2 deep drilling projects in Greenland opened up funding for continued ice-coring efforts in Antarctica (EPICA) and Greenland (NorthGRIP). The Glaciology Group of the Niels Bohr Institute, University of Copenhagen, was assigned the task...... of providing drilling capability for these projects, as it had done for the GRIP project. The group decided to further simplify existing deep drill designs for better reliability and ease of handling. The drill design decided upon was successfully tested on Hans Tausen Ice Cap, Peary Land, Greenland, in 1995....... The 5.0 m long Hans Tausen (HT) drill was a prototype for the ~11 m long EPICA and NorthGRIP versions of the drill which were mechanically identical to the HT drill except for a much longer core barrel and chips chamber. These drills could deliver up to 4 m long ice cores after some design improvements...

  5. Accounting for the temperature conditions during deep prospecting hole drilling

    Energy Technology Data Exchange (ETDEWEB)

    Shcherban, A N; Cheniak, V P; Zolotarenko, U P

    1977-01-01

    A methodology is described for calculating and controlling the temperature in inclined holes in order to establish a non-steady-state heat exchange between the medium circulating in the hole, and the construction components and rock. In order to verify the proposed methodology, the temperature of the drilling fluid is measured directly during the drilling process using a specially-designed automatic device which is lowered into the hole with the drilling string and turned on automatically at a given depth. This device makes it possible to record the drilling fluid temperature on magnetic tape, and convert the sensor signals arriving from the drilling string and the annular space. A comparison of calculation and experimental data confirmed the sufficiently high accuracy of the methods for predicting the thermal conditions in drilling deep prospecting holes.

  6. South African drilling

    International Nuclear Information System (INIS)

    Anon.

    1984-01-01

    According to the president of the South African Drilling Association, the drilling industry is meeting head-on the challenges created by the worldwide recession. The paper is a synopsis of several of the papers presented at the SADA symposium and a look at several mining-related drilling projects in South Africa. These papers include grouting techniques, the use of impregnated bits in hard rock drilling, tunnel boring for mines, surveying improvement methods and the use of explosives to increase groundwater yield

  7. Mud pressure simulation on large horizontal directional drilling

    Energy Technology Data Exchange (ETDEWEB)

    Placido, Rafael R.; Avesani Neto, Jose O.; Martins, Pedro R.R.; Rocha, Ronaldo [Instituto de Pesquisas Tecnologicas do Estado de Sao Paulo (IPT), Sao Paulo, SP (Brazil)

    2009-07-01

    Horizontal Directional Drilling (HDD) is being extensively used in Brazil for installation of oil and gas pipelines. This trenchless technology is currently used in crossings of water bodies, environmental sensitive areas, densely populated areas, areas prone to mass movement and anywhere the traditional technology is not suitable because of the risks. One of the unwanted effects of HDD is collapsing of the soil surrounding the bore-hole, leading to loss of fluid. This can result in problems such as reducing the drilling efficiency, ground heave, structures damage, fluid infiltration and other environmental problems. This paper presents four simulations of down-hole fluid pressures which represents two different geometrical characteristics of the drilling and two different soils. The results showed that greater depths are needed in longer drillings to avoid ground rupture. Thus the end section of the drilling often represents the critical stage. (author)

  8. Rh(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides using activated and unactivated alkenes.

    Science.gov (United States)

    Li, Xuting; Gong, Xue; Zhao, Miao; Song, Guoyong; Deng, Jian; Li, Xingwei

    2011-11-04

    Rhodium(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides has been achieved at the peri position. Three categories of olefins have been successfully applied. Activated olefins reacted to afford five-membered azacycles as a result of oxidative olefination-hydroamination. Unactivated olefins reacted to give the olefination product. 2-fold oxidative C-C and C-N coupling was achieved for allylbenzenes. © 2011 American Chemical Society

  9. Numerical analysis of wellbore instability in gas hydrate formation during deep-water drilling

    Science.gov (United States)

    Zhang, Huaiwen; Cheng, Yuanfang; Li, Qingchao; Yan, Chuanliang; Han, Xiuting

    2018-02-01

    Gas hydrate formation may be encountered during deep-water drilling because of the large amount and wide distribution of gas hydrates under the shallow seabed of the South China Sea. Hydrates are extremely sensitive to temperature and pressure changes, and drilling through gas hydrate formation may cause dissociation of hydrates, accompanied by changes in wellbore temperatures, pore pressures, and stress states, thereby leading to wellbore plastic yield and wellbore instability. Considering the coupling effect of seepage of drilling fluid into gas hydrate formation, heat conduction between drilling fluid and formation, hydrate dissociation, and transformation of the formation framework, this study established a multi-field coupling mathematical model of the wellbore in the hydrate formation. Furthermore, the influences of drilling fluid temperatures, densities, and soaking time on the instability of hydrate formation were calculated and analyzed. Results show that the greater the temperature difference between the drilling fluid and hydrate formation is, the faster the hydrate dissociates, the wider the plastic dissociation range is, and the greater the failure width becomes. When the temperature difference is greater than 7°C, the maximum rate of plastic deformation around the wellbore is more than 10%, which is along the direction of the minimum horizontal in-situ stress and associated with instability and damage on the surrounding rock. The hydrate dissociation is insensitive to the variation of drilling fluid density, thereby implying that the change of the density of drilling fluids has a minimal effect on the hydrate dissociation. Drilling fluids that are absorbed into the hydrate formation result in fast dissociation at the initial stage. As time elapses, the hydrate dissociation slows down, but the risk of wellbore instability is aggravated due to the prolonged submersion in drilling fluids. For the sake of the stability of the wellbore in deep

  10. Synthesis of interlocked molecules by olefin metathesis

    Science.gov (United States)

    Clark, Paul Gregory

    A large body of work in the Grubbs group has focused on the development of functional-group tolerant ruthenium alkylidene catalysts that perform a number of olefin metathesis reactions. These catalysts have seen application in a wide range of fields, including classic total synthesis as well as polymer and materials chemistry. One particular family of compounds, interlocked molecules, has benefitted greatly from these advances in catalyst stability and activity. This thesis describes several elusive and challenging interlocked architectures whose syntheses have been realized through the utilization of different types of ruthenium-catalyzed olefin metathesis reactions. Ring-closing olefin metathesis has enabled the synthesis of a [c2]daisy-chain dimer with the ammonium binding site near the cap of the dimer. A deprotonated DCD possessing such a structural attribute will more forcefully seek to restore coordinating interactions upon reprotonation, enhancing its utility as a synthetic molecular actuator. Dimer functionalization facilitated incorporation into linear polymers, with a 48% size increase of an unbound, extended analogue of the polymer demonstrating slippage of the dimer units. Ongoing work is directed at further materials studies, in particular, exploring the synthesis of macroscopic networks containing the DCD units and analyzing the correlation between molecular-scale extension-contraction manipulations and resulting macro-scale changes. A "clipping" approach to a polycatenated cyclic polymer, a structure that resembles a molecular "charm bracelet", has been described. The use of ring-opening metathesis polymerization of a carbamate monomer in the presence of a chain transfer agent allowed for the synthesis of a linear polymer that was subsequently functionalized and cyclized to the corresponding cyclic analogue. This cyclic polymer was characterized through a variety of techniques, and subjected to further functionalization reactions, affording a cyclic

  11. Method and apparatus for jet-assisted drilling or cutting

    Science.gov (United States)

    Summers, David Archibold; Woelk, Klaus Hubert; Oglesby, Kenneth Doyle; Galecki, Grzegorz

    2012-09-04

    An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.

  12. Investigating Created Properties of Nanoparticles Based Drilling Mud

    Science.gov (United States)

    Ghasemi, Nahid; Mirzaee, Mojtaba; Aghayari, Reza; Maddah, Heydar

    2018-05-01

    The success of drilling operations is heavily dependent on the drilling fluid. Drilling fluids cool down and lubricate the drill bit, remove cuttings, prevent formation damage, suspend cuttings and also cake off the permeable formation, thus retarding the passage of fluid into the formation. Typical micro or macro sized loss circulation materials (LCM) show limited success, especially in formations dominated by micropores, due to their relatively large sizes. Due to unique characteristics of nanoparticles such as their size and high surface area to volume ratio, they play an effective role in solving problems associated with the drilling fluid. In this study, we investigate the effect of adding Al2O3 and TiO2 nanoparticles into the drilling mud. Al2O3 and TiO2 nanoparticles were used in 20 and 60 nm of size and 0.05 wt% in concentration. Investigating the effects of temperature and pressure has shown that an increase in temperature can reduce the drilling mud rheological properties such as plastic viscosity, while an increase in pressure can enhance these properties. Also, the effects of pressure in high temperatures were less than those in low temperatures. Studying the effects of adding nanoparticles has shown that they can reduce the drilling mud rheological properties. Moreover, they can increase gel strength, reduce capillary suction time and decrease formation damage.

  13. Drilling contracts and incentives

    International Nuclear Information System (INIS)

    Osmundsen, Petter; Sorenes, Terje; Toft, Anders

    2008-01-01

    Shortages of rigs and personnel have encouraged discussion of designing incentive contracts in the drilling sector. However, for the drilling contracts, there are not a large variety of contract types in use. This article describes and analyses incentives for drilling contractors. These are directly represented by the compensation formats utilised in the present and in the consecutive drilling contracts. Indirectly, incentives are also provided by the evaluation criteria that oil companies use for awarding drilling assignments. Changes in contract format pose a number of relevant questions relating to resource management, and the article takes an in-depth look at some of these. Do evaluation criteria for awarding drilling assignments encourage the development of new technology and solutions? How will a stronger focus on drilling efficiency influence reservoir utilisation?

  14. A method for producing light olefines

    Energy Technology Data Exchange (ETDEWEB)

    Kavada, N.; Katsuno, K.

    1982-11-04

    A method is proposed for producing light olefins from MeOH in the presence of a catalyst (Kt), a crystalline silicate which includes silicon, an alkaline and or alkaline earth metal, titanium(4+) and phosphorus(5+), whose composition is described by the formula p(019 plus or minus 0.3)M2/mO with pZ4/nO2 with SiO2, where M is the alkaline or alkaline earth metal, Z = titanium(4+) or phosphorus(5+), m is the valency of the metal, n is the valency of Z and O is less than p is less than or equal to 0.1. A high selectivity of MeOH to C2 to C4 olefins is achieved in the presence of the catalyst. Silicon powder, silica gel, colloidal silicon, liquid glass or silicates of alkaline metals in a ratio of SiO2 to M2O of 1 to 5 is used as the source of the first component. Hydroxides or silicates of potassium and sodium (best sodium) and nitrates or chlorides of alkaline earth metals (best calcium) are used as the source of the second component. Water soluble compounds of titanium(4+) (best Ti(SO4)2, TiBr4 and TiI4) and phosphorus(5+) (best H3PO4, Na3PO4) are used as the source of the third component. Heterocyclic compounds (best morpholine, oxazolidine and their derivatives, which are taken in a molar ratio of crystallization agent to SiO2 of 0.01 to 50 (best at 0.1 to 10), are used as the crystallization agent (ArK). The catalyst is prepared through heating in an autoclave at a temperature of 80 to 300 degrees (best at 120 to 200 degrees) at atmospheric pressure for 10 to 50 hours with mixing of the mixture of the three components, water and the crystallization agent. The forming crystalline product is cooled, poured off, washed with water, dried for several hours at a temperature of at least 100 degrees and roasted in air for 2 to 48 hours at 300 to 700 degrees.

  15. Proceedings of the DGMK-Conference 'Creating value from light olefins - production and conversion'. Authors' manuscripts

    Energy Technology Data Exchange (ETDEWEB)

    Emig, G; Kraemer, H J; Weitkamp, J [eds.

    2001-07-01

    Main topics of the conference were: production of light olefin by steamcracking and catalytic cracking processes, catalysts, methanol to olefin processes, oxidative dehydrogenation, partial oxidation, selective oxidation of alkanes with various catalysts. (uke)

  16. Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis

    KAUST Repository

    Dong, G.; Teo, P.; Wickens, Z. K.; Grubbs, R. H.

    2011-01-01

    Alcohol synthesis is critical to the chemical and pharmaceutical industries. The addition of water across olefins to form primary alcohols (anti-Markovnikov olefin hydration) would be a broadly useful reaction but has largely proven elusive

  17. Caractérisation rhéologique et modélisation structurelle des systèmes argile-polymère. Application aux fluides de forage Rheometry and Structural Modelling of Clay-Polymer Systems. Application to Drilling Fluids

    Directory of Open Access Journals (Sweden)

    Cartalos U.

    2006-12-01

    Full Text Available Le comportement rhéologique des systèmes argile-polymère couramment utilisés dans les formulations des fluides de forage est examiné dans cet article. Un protocole d'essai adapté à leur nature thixotrope qui permet d'effectuer des mesures reproductibles est mis au point. Les propriétés intrinsèques du matériau sont ainsi déterminées sur toute la gamme de sollicitations : du comportement solide aux faibles déformations au comportement fluide aux taux de déformations intenses. Il est montré que ces systèmes sont caractérisés par des temps de restructuration longs, par des rhéogrammes en régime permanent présentant un minimum de contrainte et par des dépassements importants de la contrainte lors des essais transitoires. Ces effets peuvent être complètement masqués par des procédures d'essai préconisés par les normes en vigueur dans le forage. Une loi de comportement structurelle récente qui relie les propriétés thixotropes et viscoélastiques du matériau aux mécanismes de création et de rupture des flocs peut reproduire l'ensemble des phénomènes observés. Sa capacité de décrire le changement de structure au sein du fluide sous écoulement ou au repos et les variations associées de la contrainte permet d'envisager une meilleure modélisation de l'hydraulique du forage. The rheological behaviour of clay-polymer systems that are currently used in the formulation of drilling fluids was studied. A specific experimental procedure was used to account for thixotropic effects and obtain, thus, reproducible results. In this way it was possible to determine intrinsic properties in the whole range, from solid behaviour below the yield stress to liquid behaviour at very high shear. These systems are shown to be characterised by very long time scales of structure recovery, by the existence of a minimum shear stress in the steady state flow curve and by important stress overshoots in transient flows. These effects can be

  18. The degradation of 14C-labelled drilling chemicals in a simulated seabed study

    International Nuclear Information System (INIS)

    Eriksen, D.O.; Songe, P.; Schaanning, M.T.

    2003-01-01

    In an experiment, which lasted nine months, real sea bed sections and naturally occurring sediment dwelling organisms have been used to study the decomposition of today's 'green' chemicals, i.e. drilling mud chemicals comprising a-olefins or esters made from fatty acid extracted from fish. Both types have been shown to be degraded at aerobic conditions at sea bed. However, the fate of the alcoholic part of the ester has been unknown, as was the rate of degradation of the olefin. Both olefin and alcohol were labelled with 14 C at the C1 atom. The results show that the ester hydrolyses quickly and after a lag phase the alcohol is oxidised, while the olefin degrades more slowly. 133 Ba-labelled baryte was used as a bioturbidity marker. The measurements, i.e. scanned sediment columns, show very little bioturbation in the boxes where oil-contaminated sediment was present whereas the control boxes showed more activity from the sediment dwelling organisms down to the depth of the contaminated layer. (author)

  19. System and method for damping vibration in a drill string

    Science.gov (United States)

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E; Perry, Carl Allison

    2014-03-04

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  20. Reactivity of olefin and allyl ligands in π-complexes of metals

    International Nuclear Information System (INIS)

    Kukushkin, Yu.N.

    1987-01-01

    The data on reactivity of olefin and allyl ligands in transition metal (Ru, W) π-complexes, published up to 1984 are presented. Metal ion coordination of olefins causes their appreciable reactivity change. Transformations of π-olefin ligands into σ-alkyl ones, interaction of π-complexes with oxygen nucleophilic reagents, amines, halogenides and pseudohalogenides are considered

  1. Palladium(II)-catalyzed ortho-olefination of arenes applying sulfoxides as remote directing groups.

    Science.gov (United States)

    Wang, Binjie; Shen, Chuang; Yao, Jinzhong; Yin, Hong; Zhang, Yuhong

    2014-01-03

    A novel palladium-catalyzed ortho-C(sp(2))-H olefination protocol has been developed by the use of sulfoxide as the directing group. Importantly, relatively remote coordination can be accessed to achieve the ortho olefination of benzyl, 2-arylethyl, and 3-arylpropenyl sulfoxide substrates, and the olefinated sulfoxide can be easily transformed to other functionalities.

  2. Kinetically based NMR method of measuring blending octane number of olefins

    NARCIS (Netherlands)

    Golombok, M.; Bruijn, J.; Morley, C.

    1995-01-01

    Olefins are highly nonlinear octane blenders so that standard GC analyses are poor predictors of blend quality. Engine rating is the only way of measuring olefin octane number nonlinearity. It is thus not possible to rapidly assess the quality of the product obtained from an olefin-producing

  3. Quality in drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, E; Gervais, I [Sedco Forex Jacintoport Facility, Channelview, TX (United States); Le Moign, Y; Pangarkar, S; Stibbs, B [Sedco Forex, Montrouge (France); McMorran, P [Sedco Forex, Pau (France); Nordquist, E [Dubai Petroleum Company, Dubai (United Arab Emirates); Pittman, T [Sedco Forex, Perth (Australia); Schindler, H [Sedco Forex, Dubai (United Arab Emirates); Scott, P [Woodside Offshore Petroleum Pty. Ltd., Perth (Australia)

    1997-12-31

    Driven by cost and profitability pressures, quality has taken on new meaning and importance in the oil field during the past decade. In drilling operations, new initiatives have led to cooperative team efforts between operators and drilling contractors to enhance quality. In this article examples are given of how one drilling contractor, by adopting a quality culture, is reaping major benefits for its clients as well as its employees. 22 figs., 19 refs.

  4. Quality in drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, E.; Gervais, I. [Sedco Forex Jacintoport Facility, Channelview, TX (United States); Le Moign, Y.; Pangarkar, S.; Stibbs, B. [Sedco Forex, Montrouge (France); McMorran, P. [Sedco Forex, Pau (France); Nordquist, E. [Dubai Petroleum Company, Dubai (United Arab Emirates); Pittman, T. [Sedco Forex, Perth (Australia); Schindler, H. [Sedco Forex, Dubai (United Arab Emirates); Scott, P. [Woodside Offshore Petroleum Pty. Ltd., Perth (Australia)

    1996-12-31

    Driven by cost and profitability pressures, quality has taken on new meaning and importance in the oil field during the past decade. In drilling operations, new initiatives have led to cooperative team efforts between operators and drilling contractors to enhance quality. In this article examples are given of how one drilling contractor, by adopting a quality culture, is reaping major benefits for its clients as well as its employees. 22 figs., 19 refs.

  5. Optimization of bridging agents size distribution for drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Waldmann, Alex; Andrade, Alex Rodrigues de; Pires Junior, Idvard Jose; Martins, Andre Leibsohn [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)]. E-mails: awaldmann@petrobras.com.br; andradear.gorceix@petrobras.com.br; idvard.gorceix@petrobras.com.br; aleibsohn@petrobras.com.br

    2008-07-01

    The conventional drilling technique is based on positive hydrostatic pressure against well walls to prevent inflows of native fluids into the well. Such inflows can cause security problems for the team well and to probe. As the differential pressure of the well to reservoir is always positive, the filtrate of the fluid tends to invade the reservoir rock. Minimize the invasion of drilling fluid is a relevant theme in the oil wells drilling operations. In the design of drilling fluid, a common practice in the industry is the addition of bridging agents in the composition of the fluid to form a cake of low permeability at well walls and hence restrict the invasive process. The choice of drilling fluid requires the optimization of the concentration, shape and size distribution of particles. The ability of the fluid to prevent the invasion is usually evaluated in laboratory tests through filtration in porous media consolidated. This paper presents a description of the methods available in the literature for optimization of the formulation of bridging agents to drill-in fluids, predicting the pore throat from data psychotherapy, and a sensitivity analysis of the main operational parameters. The analysis is based on experimental results of the impact of the size distribution and concentration of bridging agents in the filtration process of drill-in fluids through porous media submitted to various different differential of pressure. The final objective is to develop a software for use of PETROBRAS, which may relate different types and concentrations of bridging agents with the properties of the reservoir to minimize the invasion. (author)

  6. New findings for the use of NMR- and computer tomography for gauging the potential of drilling fluids to cause damage to rocks; Neue Erkenntnisse bei der Anwendung von NMR- und Computertomografie-Methoden im Rahmen der Bewertung des Traegerschaedigungspotentiales von Bohrfluessigkeiten

    Energy Technology Data Exchange (ETDEWEB)

    Zwaag, C. van der [Reservoir Labs. AS, Trondheim (Norway); Stallmach, F. [Univ. Leipzig (Germany). Fakultaet fuer Physik und Geowissenschaften; Hanssen, J.E. [MI/Anchor Drilling Fluids AS, Stavanger (Norway); Soergaard, E. [Norsk Hydro AS, Bergen (Norway); Toennesen, R. [Saga Petroleum ASA, Stavanger (Norway)

    1998-12-31

    Polyanionic cellulose, xanthane and ppolyglycole are standard additives for water-based drilling fluids. These are added to drilling liquids to control water loss, provide viscosity and inhibit slating. Filtration losses, which are unavoidable when drilling, cause scavenging polymers to penetrate the area around the drilled hole. This causes a number of different reactions with the surrounding rocks and may ultimately have a permanent influence on the flow conditions of hydrocarbons. The study mentioned above aimed at determining the damage potential of these additives. [Deutsch] Polyanionische Cellulose, Xanthan und Polyglykol sind uebliche Zusatzstoffe von wasserbasischen Bohrspuelungen. Diese werden Bohrfluessigkeiten zur Wasserverlustkontrolle, zur Viskositaetsbildung und zur Schieferinhibierung zugesetzt. Die beim Bohrprozess unvermeidlichen Filtrationsverluste fuehren dazu, dass Spuelungspolymere beim Bohren in den Bohrlochnahbereich eindringen. Die Beschaffenheit dieser Stoffe fuehrt nach dem Eindringen zu unterschiedlichen Reaktionen mit dem Traegergestein. Diese koennen letzten Endes einen dauerhaften Einfluss auf die Zuflussbedingungen von Kohlenwasserstoffen haben. Das Ziel der vorliegenden Studie war es, das Traegerschaedigungspotential der obengenannten Spuelungszusaetze zu charakterisieren. (orig.)

  7. Ionic liquids for separation of olefin-paraffin mixtures

    Science.gov (United States)

    Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

    2013-09-17

    The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  8. Allene or alkyne treatment of olefin conversion catalysts

    International Nuclear Information System (INIS)

    Banks, R.L.

    1986-01-01

    This patent describes a disproportionation process which comprises contacting at least one olefin from the group consisting of: acyclic mono- and polyenes having at least 3 up to 10 carbon atoms per molecule, and cycloalkyl and aryl derivatives thereof; cyclic mono- and polyenes having at least 4 to 10 carbon atoms per molecule, and alkyl and aryl derivatives thereof; mixtures of two or more of the above olefins; and mixtures of ethylene with one or more of the above olefins capable of undergoing disproportionation with a tungsten oxide on silica disproportionation catalyst system under disproportionation conditions, the improvement comprising contacting the catalyst with an activating amount of at least one alkyne conforming to the formula: R-C=C-R wherein each R is independently H or a C/sub 1/-C/sub 6/ carbon radical per mole of tungsten oxide

  9. Synthetic and mechanistic aspects of titanium-mediated carbonyl olefinations

    Energy Technology Data Exchange (ETDEWEB)

    Petasis, N.A.; Staszewski, J.P.; Hu, Yong-Han; Lu, Shao-Po [Univ. of Southern California, Los Angeles, CA (United States)

    1995-12-31

    A new method for the olefination of carbonyl compounds with dimethyl titanocene, and other related bishydrocarbyl titanocene derivatives has been recently developed in the author`s laboratories. This process is experimentally convenient and works with various types of carbonyl compounds, including aldehydes, ketones, esters, lactones, carbonates, anhydrides, amides, imides, lactams, thioesters, selenoesters, and acylsilanes. More recent studies have focused on the scope and utility of this reaction, including mechanistic studies and synthetic applications. In addition to varying the reaction conditions, the authors have examined several mixed titanocene derivatives and have found ways for carrying out this type of olefination at room temperature, such as the use of tris(trimethylsilyl) titanacyclobutene. The authors have also employed this reaction in the modification of carbohydrates and cyclobutenediones. This olefination was also followed-up with subsequent transformations to produce carbocycles and heterocycles, including tetrahydrofurans and tetrahydropyrans.

  10. Olefination reactions of phosphorus-stabilized carbon nucleophiles.

    Science.gov (United States)

    Gu, Yonghong; Tian, Shi-Kai

    2012-01-01

    A range of phosphorus-stabilized carbon nucleophiles have been employed for alkene synthesis with high chemo-, regio-, and stereoselectivity. The Wittig, Horner-Wadsworth-Emmons, Horner-Wittig, and Evans-Akiba reactions utilize phosphonium-, phosphonate-, phosphine oxide-, and pentacoordinated phosphorane-stabilized carbanions as nucleophiles, respectively, to undergo olefination with aldehydes or ketones, and each of these transformations has its own advantages and limitations. Modifying the structures of these nucleophiles along with optimizing reaction conditions results in the formation of a wide variety of polysubstituted alkenes in a highly stereoselective manner. The olefination of imines with phosphonium ylides has recently emerged as a useful approach to tune the stereoselectivity for alkene synthesis. This review focuses on recent advances in the stereoselective olefination of phosphorus-stabilized carbon nucleophiles.

  11. Comparing Ru and Fe-catalyzed olefin metathesis

    KAUST Repository

    Poater, Albert; Chaitanya Vummaleti, Sai Vikrama; Pump, Eva; Cavallo, Luigi

    2014-01-01

    Density functional theory calculations have been used to explore the potential of Fe-based complexes with an N-heterocyclic carbene ligand, as olefin metathesis catalysts. Apart from a less endothermic reaction energy profile, a small reduction in the predicted upper energy barriers (≈ 2 kcal mol -1) is calculated in the Fe catalyzed profile with respect to the Ru catalysed profile. Overall, this study indicates that Fe-based catalysts have the potential to be very effective olefin metathesis catalysts. This journal is © the Partner Organisations 2014.

  12. Methylenation of perfluoroalkyl ketones using a Peterson olefination approach.

    Science.gov (United States)

    Hamlin, Trevor A; Kelly, Christopher B; Cywar, Robin M; Leadbeater, Nicholas E

    2014-02-07

    An operationally simple, inexpensive, and rapid route for the olefination of a wide array of trifluoromethyl ketones to yield 3,3,3-trifluoromethylpropenes is reported. Using a Peterson olefination approach, the reaction gives good to excellent yields of the alkene products and can be performed without purification of the β-hydroxysilyl intermediate. The reaction can be extended to other perfluoroalkyl substituents and is easily scaled up. The alkenes prepared can be readily transformed into a variety of other perfluoroalkyl-containing compounds.

  13. Silver-Catalyzed Aldehyde Olefination Using Siloxy Alkynes.

    Science.gov (United States)

    Sun, Jianwei; Keller, Valerie A; Meyer, S Todd; Kozmin, Sergey A

    2010-03-20

    We describe the development of a silver-catalyzed carbonyl olefination employing electron rich siloxy alkynes. This process constitutes an efficient synthesis of trisubstituted unsaturated esters, and represents an alternative to the widely utilized Horner-Wadsworth-Emmons reaction. Excellent diastereoselectivities are observed for a range of aldehydes using either 1-siloxy-1-propyne or 1-siloxy-1-hexyne. This mild catalytic process also enables chemoselective olefination of aldehydes in the presence of either ester or ketone functionality. Furthermore, since no by-products are generated, this catalytic process is perfectly suited for development of sequential reactions that can be carried out in a single flask.

  14. Electrochemistry for biofuel generation: transformation of fatty acids and triglycerides to diesel-like olefin/ether mixtures and olefins.

    Science.gov (United States)

    dos Santos, Tatiane R; Harnisch, Falk; Nilges, Peter; Schröder, Uwe

    2015-03-01

    Electroorganic synthesis can be exploited for the production of biofuels from fatty acids and triglycerides. With Coulomb efficiencies (CE) of up to 50 %, the electrochemical decarboxylation of fatty acids in methanolic and ethanolic solutions leads to the formation of diesel-like olefin/ether mixtures. Triglycerides can be directly converted in aqueous solutions by using sonoelectrochemistry, with olefins as the main products (with a CE of more than 20 %). The latter reaction, however, is terminated at around 50 % substrate conversion by the produced side-product glycerol. An energy analysis shows that the electrochemical olefin synthesis can be an energetically competitive, sustainable, and--in comparison with established processes--economically feasible alternative for the exploitation of fats and oils for biofuel production. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Drilling bits for deep drilling and process for their manufacture

    Energy Technology Data Exchange (ETDEWEB)

    Rhode, H.; Juergens, R.; Feenstra, R.; Busking, B.E.

    1978-11-30

    The invention concerns a drilling head or a drilling bit for use in deep drilling in underground formations and particularly concerns a drilling bit with a drilling bit body, which has a shank and a hollow space, which is connected with a duct extending through the shank. The drilling bit body has several separate cutting elements for removing material from the floor of a borehole and hydraulic devices for cooling and/or cleaning the cutting elements are provided.

  16. Casing drilling TM : a viable technology for coal bed methane?

    Energy Technology Data Exchange (ETDEWEB)

    Madell, G.; Muqeem, M. [Tesco Corp., Calgary, AB (Canada)

    2001-07-01

    This paper highlighted the experience that Tesco has gained by drilling more than 30 wells using only casings as the drill stem, suggesting that such technology could be advantageous for Coal Bed Methane (CBM) exploration and development. Tesco has manufactured a mobile and compact hydraulic drilling rig that is ideal to meet the great demand for CBM development in Canada. The Casing Drilling TM system, when used in conjunction with the drilling rig, could be very effective and efficient for exploration and development of CBM reserves which typically require extensive coring. Continuous coring while drilling ahead and wire line retrieval can offer time savings and quick core recovery of large diameter core required for exploration core desorption tests. The proposed system may also have the potential to core or drill typically tight gas sands or coal beds under balanced with air or foam. This would reduce drilling fluid damage while finding gas at the same time. Compared to conventional drill pipes, Casing Drilling TM could also be effective with water production from shallow sands because of the smaller annual clearance which requires less air volumes to lift any produced water. 8 refs., 3 tabs., 9 figs.

  17. Geothermal drilling and completion technology development program. Quarterly progress report, January-March 1980

    Energy Technology Data Exchange (ETDEWEB)

    Varnado, S.G. (ed.)

    1980-04-01

    The progress, status, and results of ongoing Research and Development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods. Advanced drilling systems are also under development. The goals of the program are to develop the technology required to reduce well costs by 25% by 1983 and by 50% by 1987.

  18. Geothermal drilling and completion technology development program. Annual progress report, October 1979-September 1980

    Energy Technology Data Exchange (ETDEWEB)

    Varnado, S.G. (ed.)

    1980-11-01

    The progress, status, and results of ongoing research and development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods. Advanced drilling systems are also under development. The goals of the program are to develop the technology required to reduce well costs by 25% by 1983 and by 50% by 1987.

  19. Drilling contract issues

    International Nuclear Information System (INIS)

    Davison, G.B.; Worden, D.R.; Borbridge, G.K.D.

    1997-01-01

    Some selected issues which are facing both operators and contractors in drilling for oil and gas, such as the allocation of risk by contract and by statute and the implementation of new technologies, were discussed. There are three varieties of written drilling contracts used in Canada: (1) day work and meterage contracts, (2) master drilling agreements, and (3) contracts that are used in construction projects that do not specifically relate to drilling. Issues relevant to the contractual allocation of risk, to implementing new drilling technologies, to reconciling contract and statute liability, and the formation of strategic alliances for mutual benefit, and the factors contributing to the success of such alliances were explored. 12 refs

  20. P(O)R2-Directed Enantioselective C-H Olefination toward Chiral Atropoisomeric Phosphine-Olefin Compounds.

    Science.gov (United States)

    Li, Shi-Xia; Ma, Yan-Na; Yang, Shang-Dong

    2017-04-07

    An effective synthesis of chiral atropoisomeric biaryl phosphine-olefin compounds via palladium-catalyzed enantioselective C-H olefination has been developed for the first time. The reactions are operationally simple, tolerate wide functional groups, and have a good ee value. Notably, P(O)R 2 not only acts as the directing group to direct C-H activation in order to make a useful ligand but also serves to facilitate composition of the product in a useful manner in this transformation.

  1. Fluid sampling tool

    Science.gov (United States)

    Garcia, A.R.; Johnston, R.G.; Martinez, R.K.

    1999-05-25

    A fluid sampling tool is described for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall. 6 figs.

  2. Fluid sampling tool

    Science.gov (United States)

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    1999-05-25

    A fluid sampling tool for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall.

  3. Specific features of well logging of boreholes drilled on electrical nonconducting solutions

    International Nuclear Information System (INIS)

    Ruchkin, A.F.; Fomenko, V.G.

    1978-01-01

    Methods for identification of permeable strata and determination of their porosity and oil-gas saturation using standard combination of geophysical investigations in the boreholes drilled with nonaqueous and inert drilling fluids are considered. Geophysical combination consists of the methods indications of which are independent on electrical conductivity of drilling fluids. They are all modifications of radioactivity logging (gamma logging, neutron logging, neutron-gamma logging, gamma-gamma logging, pulsed neutron logging, nuclear-magnetic logging), acoustic logging and thermal logging

  4. SALTON SEA SCIENTIFIC DRILLING PROJECT: SCIENTIFIC PROGRAM.

    Science.gov (United States)

    Sass, J.H.; Elders, W.A.

    1986-01-01

    The Salton Sea Scientific Drilling Project, was spudded on 24 October 1985, and reached a total depth of 10,564 ft. (3. 2 km) on 17 March 1986. There followed a period of logging, a flow test, and downhole scientific measurements. The scientific goals were integrated smoothly with the engineering and economic objectives of the program and the ideal of 'science driving the drill' in continental scientific drilling projects was achieved in large measure. The principal scientific goals of the project were to study the physical and chemical processes involved in an active, magmatically driven hydrothermal system. To facilitate these studies, high priority was attached to four areas of sample and data collection, namely: (1) core and cuttings, (2) formation fluids, (3) geophysical logging, and (4) downhole physical measurements, particularly temperatures and pressures.

  5. Capturing of the monoterpene olefin limonene produced in Saccharomyces cerevisiae

    NARCIS (Netherlands)

    Jongedijk, E.J.; Cankar, K.; Ranzijn, J.; Krol, van der A.R.; Bouwmeester, H.J.; Beekwilder, M.J.

    2015-01-01

    Monoterpene olefins such as limonene are plant compounds with applications as flavouring and fragrance agents, as solvents and potentially also in polymer and fuel chemistry. We engineered baker's yeast Saccharomyces cerevisiae to express a (-)-limonene synthase from Perilla frutescens and a

  6. Methanol conversion to lower olefins over RHO type zeolite

    KAUST Repository

    Masih, Dilshad; Imai, Hiroyuki; Yokoi, Toshiyuki; Kondo, Junkonomura; Tatsumi, Takashi

    2013-01-01

    Eight-membered ring small-pore zeolite of RHO-type topology has been synthesized, characterized and tested for methanol-to-olefin (MTO) reaction. The zeolite was hydrothermally crystallized from the gel with Si/Al ratio of 5.0. It showed a high BET

  7. Ozonolysis of Model Olefins-Efficiency of Antiozonants

    NARCIS (Netherlands)

    Huntink, N.M.; Datta, Rabin; Talma, Auke; Noordermeer, Jacobus W.M.

    2006-01-01

    In this study, the efficiency of several potential long lasting antiozonants was studied by ozonolysis of model olefins. 2-Methyl-2-pentene was selected as a model for natural rubber (NR) and 5-phenyl-2-hexene as a model for styrene butadiene rubber (SBR). A comparison was made between the

  8. The asymmetric Schrock olefin metathesis catalysts. A computational study

    NARCIS (Netherlands)

    Goumans, T.P.M.; Ehlers, A.W.; Lammertsma, K.

    2005-01-01

    The mechanism of the transition metal catalyzed olefin metathesis reaction with the Schrock catalyst is investigated with pure (BP86) and hybrid (B3LYP) density functional theory. On the free-energy surface there is no adduct between ethylene and model catalyst (MeO)

  9. Mesoporous molecular sieves as advanced supports for olefin metathesis catalysts

    Czech Academy of Sciences Publication Activity Database

    Balcar, Hynek; Čejka, Jiří

    2013-01-01

    Roč. 257, 21-22 (2013), s. 3107-3124 ISSN 0010-8545 R&D Projects: GA AV ČR IAA400400805; GA ČR GBP106/12/G015 Institutional support: RVO:61388955 Keywords : Olefin metathesis * mesoporous molecular sieves * Heterogeneous catalysts Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 12.098, year: 2013

  10. Catalytic polymerization of olefins in supercritical carbon dioxide

    NARCIS (Netherlands)

    Kemmere, M.F.; Vries, de T.J.; Keurentjes, J.T.F.

    2004-01-01

    A novel process is being developed for the catalytic polymerization of olefins in supercritical carbon dioxide (sc CO2), for which potential applications will mainly be in the production of EPDM and other elastomers. For this purpose, the Brookhart catalyst has been tested for the homopolymerization

  11. Radiation-induced copolymerization of hexafluoroacetone with α-olefins

    International Nuclear Information System (INIS)

    Matsuda, O.; Watanabe, S.; Okamoto, J.; Machi, S.; Tabata, Y.

    1977-01-01

    The copolymerization of hexafluoroacetone with higher α-olefins above butene, such as 1-pentene (I), 1-hexene (II), 1-octene (III), 2-methyl-1-butene (IV), 2-methyl-1-pentene (V), 3-methyl-1-butene (VI), and 4-methyl-1-pentene (VII) was studied at relatively low temperatures by γ-ray irradiation. Copolymerization of II, IV, V, and VII with hexafluoroacetone was found to scarcely take place at -78 0 C in bulk, but the addition of trichlorotrifluoroethane in amounts to yield equimolar mixtures resulted in conversion of 15.7 percent for IV and of 2.1 to 4.0 percent for the other α-olefins. Higher conversion of V at -78 0 C than at 0 0 C suggest that copolymerization may take place via an ionic mechanism. The effects of various additives on the copolymerization are reported. Infrared spectral studies indicated that the double bond of the α-olefins is opened to form a polymer. The C--O double bond of the hexafluoroacetone and the α-olefin double bond are opened to form the copolymer

  12. Optical fibre Bragg grating recorded in TOPAS cyclic olefin copolymer

    DEFF Research Database (Denmark)

    Johnson, I.P.; Yuan, Scott Wu; Stefani, Alessio

    2011-01-01

    A report is presented on the inscription of a fibre Bragg grating into a microstructured polymer optical fibre fabricated from TOPAS cyclic olefin copolymer. This material offers two important advantages over poly (methyl methacrylate), which up to now has formed the basis for polymer fibre Bragg...

  13. Olefination of carbonyl compounds: modern and classical methods

    Energy Technology Data Exchange (ETDEWEB)

    Korotchenko, V N; Nenajdenko, Valentine G; Balenkova, Elizabeth S [Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow (Russian Federation); Shastin, Aleksey V [Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region (Russian Federation)

    2004-10-31

    The published data on the methods for alkene synthesis by olefination of carbonyl compounds are generalised and systematised. The main attention is given to the use of transition metals and organoelement compounds. The review covers the data on both classical and newly developed methods that are little known to chemists at large.

  14. Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols.

    Science.gov (United States)

    Chakraborty, Subrata; Das, Uttam Kumar; Ben-David, Yehoshoa; Milstein, David

    2017-08-30

    Catalytic α-olefination of nitriles using primary alcohols, via dehydrogenative coupling of alcohols with nitriles, is presented. The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), in the absence of any additives, base, or hydrogen acceptor, liberating dihydrogen and water as the only byproducts.

  15. Olefination of carbonyl compounds: modern and classical methods

    Science.gov (United States)

    Korotchenko, V. N.; Nenajdenko, Valentine G.; Balenkova, Elizabeth S.; Shastin, Aleksey V.

    2004-10-01

    The published data on the methods for alkene synthesis by olefination of carbonyl compounds are generalised and systematised. The main attention is given to the use of transition metals and organoelement compounds. The review covers the data on both classical and newly developed methods that are little known to chemists at large.

  16. Access to Functionalized Steroid Side Chains via Modified Julia Olefination

    Science.gov (United States)

    Izgu, Enver Cagri; Burns, Aaron C.; Hoye, Thomas R.

    2011-01-01

    Various functionalized steroidal side chains were conveniently accessed by a modified Julia olefination strategy using a common sulfone donor and an appropriate α-branched aldehyde acceptor. For the coupling of these hindered classes of reaction partners (and in contrast to typically observed trends), the benzothiazolyl(BT)-sulfone anion gave superior outcomes compared to the phenyltetrazolyl(PT)-sulfone anion. PMID:21244047

  17. Taking aim : particle impact drilling targets ROP gains

    Energy Technology Data Exchange (ETDEWEB)

    Mahoney, J.

    2005-11-01

    Details of a new drilling technique developed by Particle Drilling Technologies Inc. were presented. Particle impact drilling uses buckshot-like steel particles entrained with ordinary drilling mud that are accelerated through a specially-designed drill bit to bombard hard-rock formations at rapid-fire velocities of up to 4 million times a minute. Conventional drill bits rely on mechanical energy from some 50,000 pounds of weight on bit and torque to break or fracture the formation, whereas particle impact drilling relies on hydraulic energy to blast the steel particles from the bit's jetting nozzles in order to repeatedly fracture the formation. It was suggested that the new technology will accelerate the drilling process. Tests have shown that the new device out-performs conventional bits in hard formations by utilizing the hydraulics of the rig to drill with particles. In field tests, drilling was 4 times faster than conventional methods. It was anticipated that the bit will be up to 150 per cent faster in softer rock formations. In order to avoid clogging, the system uses a shot trap to remove the steel balls, which are roughly one-tenth of an inch in diameter, from the drilling fluid before it enters the shale shaker. The shot is recycled after each well. During drilling, mud circulation must be continuous for the system to work. If the system can't circulate cleanly out of a hole, there is a disruption in the process and drilling fluid may move up the annulus at 350 feet per minute when it leaves bottomhole. It was suggested that circulation issues can be resolved by increasing mud viscosity. A less than optimal performance during a recent test at Catoosa was attributed to a lack of control over drilling fluid parameters and to the use of an overly-large well casing. It was concluded that the new system will likely greatly reduce the number of days it takes to drill a well. 2 figs.

  18. A vision for drilling

    Energy Technology Data Exchange (ETDEWEB)

    Millheim, K. [Montanuniversitaet Leoben (Austria)

    1995-12-31

    The future of drilling lies in its relationship with the oil and gas industry. This paper examines how the future of drilling is seen from the view point of the exploration manager, the drilling contractor, the drilling engineer and the company president or managing director. The various pressures on the oil and gas industry are examined, such as environmental issues, alternative energy sources, and the price of oil which determines how companies are run. Exploration activity is driven by the price of oil and gas. The development of wells with multiple horizontal wells or multiple horizontal wells with tributaries will reduce the cost of exploration. Companies will rely less and less on reservoir simulation and more on cheap well-bores, multi-lateral well-bores and will exploit oil that could not be exploited before. The cost of exploratory drilling will need to be kept down so that in the future the industry will get better at economically finding fields at the 10 million to 20 million barrel range that would not have been possible before. The future is expected to see drilling contractors tunnelling, making sewerage lines and drilling 10,000 foot wells with purpose built rigs. Franchising will become a feature of the industry as will the use of databases to answer key technical questions. Offshore platforms will be built to be moveable and disposable. The industry is capable of solving problems, meeting challenges and making ideas work, providing much hope for the future. 10 figs., 1 photo.

  19. Drilling cost analysis

    International Nuclear Information System (INIS)

    Anand, A.B.

    1992-01-01

    Drilling assumes greater importance in present day uranium exploration which emphasizes to explore more areas on the basis of conceptual model than merely on surface anomalies. But drilling is as costly as it is important and consumes a major share (50% to 60%) of the exploration budget. As such the cost of drilling has great bearing on the exploration strategy as well as on the overall cost of the project. Therefore, understanding the cost analysis is very much important when planning or intensifying an exploration programme. This not only helps in controlling the current operations but also in planning the budgetary provisions for future operations. Also, if the work is entrusted to a private party, knowledge of in-house cost analysis helps in fixing the rates of drilling in different formations and areas to be drilled. Under this topic, various factors that contribute to the cost of drilling per meter as well as ways to minimize the drilling cost for better economic evaluation of mineral deposits are discussed. (author)

  20. Drilling for scientific purpose

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Shoichi

    1987-09-01

    Drilling for scientific purpose is a process of conducting geophysical exploration at deep underground and drilling for collecting crust samples directly. This is because earth science has advanced to get a good understanding about the top of the crust and has shifted its main interest to the lower layer of the crust in land regions. The on-land drilling plan in Japan has just started, and the planned drilling spots are areas around the Minami River, Hidaka Mts., kinds of the Mesozoic and Cenozoic granite in outside zone, the extension of Japan Sea, Ogasawara Is., Minami-Tori Is., and active volcanos. The paper also outlines the present situation of on-land drilling in the world, focusing on the SG-3rd super-deep well SG-3 on the Kola Peninsula, USSR, Satori SG-1st well SG-1 in Azerbaidzhan S.S.R, V.S.S.R, Sweden's wells, Cyprus' wells, Bayearn well Plan in West Germany, and Salton Sea Scientific Drilling Program in the U.S. At its end, the paper explains the present situation and the future theme of the Japanese drilling technique and points out the necessity of developing equipment, and techniques. (14 figs, 5 tabs, 26 refs)

  1. Drilling and well technology

    Energy Technology Data Exchange (ETDEWEB)

    Milheim, K. [Mining University Leoben Institute for Drilling Technology, (Austria)

    1996-12-31

    Over a billion dollars a year is lost by exploration and production companies drilling wells because of the lack of learn curve management (LMC) practices. This paper presents the importance of the LMC concept, what it is, why LMC has not yet been recognized as a major initiative for improving drilling cost performance. The paper discusses the different types of planning, problems with implementation of plans, the use and misuse of drilling results and data bases, and the lack of post analysis practices. The major point of the paper is to show the massive savings that can be achieved by valuing LMC, learning LMC and successfully implementing LMC. . 2 refs., 5 figs.

  2. Evaluate the action of polymeric additives in protect and recover water and bentonite clay based drilling fluids contaminated by degradation agents; Analise da acao de aditivos polimericos na protecao e recuperacao de fluidos de perfuracao base agua e bentonita contaminados por sais

    Energy Technology Data Exchange (ETDEWEB)

    Campos, L.F.A.; Ferreira, H.S.; Amorim, L.V.; Franca, K.B.; Ferreira, H.C. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    The aim of this paper is study influences of electrolytes and cellulose polymers on rheological and water loss properties of dispersions of bentonite compositions. Evaluate the action of degradation additives CaSO{sub 4}, MgCl{sub 2} and CaCl{sub 2} and polymeric additives to protect and recover water and clay based. The results show a negative effect of degradation additives the rheological and water loss properties of drilling fluids. The cellulose polymers can be successfully applied to protect and recover of the rheological properties and water loss of the dispersions contaminated. (author)

  3. Evaluation of an air drilling cuttings containment system

    Energy Technology Data Exchange (ETDEWEB)

    Westmoreland, J.

    1994-04-01

    Drilling at hazardous waste sites for environmental remediation or monitoring requires containment of all drilling fluids and cuttings to protect personnel and the environment. At many sites, air drilling techniques have advantages over other drilling methods, requiring effective filtering and containment of the return air/cuttings stream. A study of. current containment methods indicated improvements could be made in the filtering of radionuclides and volatile organic compounds, and in equipment like alarms, instrumentation or pressure safety features. Sandia National Laboratories, Dept. 61 11 Environmental Drilling Projects Group, initiated this work to address these concerns. A look at the industry showed that asbestos abatement equipment could be adapted for containment and filtration of air drilling returns. An industry manufacturer was selected to build a prototype machine. The machine was leased and put through a six-month testing and evaluation period at Sandia National Laboratories. Various materials were vacuumed and filtered with the machine during this time. In addition, it was used in an actual air drive drilling operation. Results of these tests indicate that the vacuum/filter unit will meet or exceed our drilling requirements. This vacuum/filter unit could be employed at a hazardous waste site or any site where drilling operations require cuttings and air containment.

  4. Humvee Armor Plate Drilling

    National Research Council Canada - National Science Library

    2004-01-01

    When drilling holes in hard steel plate used in up-armor kits for Humvee light trucks, the Anniston Army Depot, Anniston, Alabama, requested the assistance of the National Center for Defense Manufacturing and Machining (NCDMM...

  5. FORMATE-BASED FLUIDS: FORMULATION AND APPLICATION

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2008-12-01

    Full Text Available Formate-based fluids has been successfully used in over hunders HPHT well operations since they introduced in field practice. They have many advantages when compared with conventional HPHT drilling and completion fluids such as: minimal formation damage, maintenance of additve properties at high temperatures, reduced hydraulic flow resistance, low potential for differential sticking, naturally lubricating, very low corrosion rates, biodegradable and pose little risk to the environment etc. Formate-based fluids can be applied during deep slim hole drilling, shale drilling, reservoir drilling, salt and gas hydrate formations drilling. The laboratory research was carried out to evaluate the rheological behavior of formate-based fluids as a function of temperature. Formate-based fluids were formulated using potassium formate brine, xanthan polymer, PAC, starch and calcium carbonate. Experimental results show that potassium formate improves the thermal stability of polymers.

  6. Drilling rig mast

    Energy Technology Data Exchange (ETDEWEB)

    Bulgakov, E.S.; Barashkov, V.A.; Lebedev, A.I.; Panin, N.M.; Sirotkin, N.V.

    1981-01-07

    A drilling rig mast is proposed that contains a portal with a carrier shaft hinged to it and struts with stays. In order to decrease the time expended in the assembly and dessembly of the drilling rig, the portal is constructed from mobile and immobile parts that are connected together by a ball pivot; the immobile section of the portal has a T-shaped recess for directing the mobile section.

  7. Making Safe Surgery Affordable: Design of a Surgical Drill Cover System for Scale.

    Science.gov (United States)

    Buchan, Lawrence L; Black, Marianne S; Cancilla, Michael A; Huisman, Elise S; Kooyman, Jeremy J R; Nelson, Scott C; OʼHara, Nathan N; OʼBrien, Peter J; Blachut, Piotr A

    2015-10-01

    Many surgeons in low-resource settings do not have access to safe, affordable, or reliable surgical drilling tools. Surgeons often resort to nonsterile hardware drills because they are affordable, robust, and efficient, but they are impossible to sterilize using steam. A promising alternative is to use a Drill Cover system (a sterilizable fabric bag plus surgical chuck adapter) so that a nonsterile hardware drill can be used safely for surgical bone drilling. Our objective was to design a safe, effective, affordable Drill Cover system for scale in low-resource settings. We designed our device based on feedback from users at Mulago Hospital (Kampala, Uganda) and focused on 3 main aspects. First, the design included a sealed barrier between the surgical field and hardware drill that withstands pressurized fluid. Second, the selected hardware drill had a maximum speed of 1050 rpm to match common surgical drills and reduce risk of necrosis. Third, the fabric cover was optimized for ease of assembly while maintaining a sterile technique. Furthermore, with the Drill Cover approach, multiple Drill Covers can be provided with a single battery-powered drill in a "kit," so that the drill can be used in back-to-back surgeries without requiring immediate sterilization. The Drill Cover design presented here provides a proof-of-concept for a product that can be commercialized, produced at scale, and used in low-resource settings globally to improve access to safe surgery.

  8. Characterization of drilling waste from shale gas exploration in Central and Eastern Poland.

    Science.gov (United States)

    Mikos-Szymańska, Marzena; Rusek, Piotr; Borowik, Krzysztof; Rolewicz, Maciej; Bogusz, Paulina; Gluzińska, Joanna

    2018-05-28

    The purpose of this research was to determine and evaluate the chemical properties of drilling waste from five well sites in Central and Eastern Poland. It was found that spent drilling fluids can contain high values of nickel and mercury (270 and 8.77 mg kg -1 , respectively) and can exceed the maximum permissible limits recommended by the EC regulations for safety of soils (75 mg kg -1 for nickel and 1.5 mg kg -1 for mercury). The heavy metal concentrations in the studied drill cuttings did not exceed the maximum permissible limits recommended by the EC regulation. Drilling wastes contain macroelements (e.g., calcium, magnesium, and potassium) as well as trace elements (e.g., copper, iron, zinc, and manganese) that are essential for the plant growth. It was stated that water extracts of drilling fluids and drill cuttings, according to anions presence, had not any specific constituents of concern based on FAO irrigation guidelines, the USEPA WQC, and toxicity values. X-ray diffraction analysis was used to understand the structure and texture of waste drilling fluid solids and drill cuttings. Analysis of the mineralogical character of drilling fluid solids revealed that they contained calcite, quartz, muscovite, sylvite, barite, dolomite, and orthoclase. Drill cuttings contained calcite quartz, muscovite, barite, dolomite, and barium chloride.

  9. Well drilling by rotary percussive drill above ground

    International Nuclear Information System (INIS)

    Sabatier, G.

    1987-01-01

    Originally, the Well Drilling Section of Cogema used only the diamond core drilling technique. The appearance of independent rotation for compressed air rock drills has led to the use and to the development of this drilling system, as a drill core is not indispensable, when the material of the search is radioactive. During the last few years, hydraulic drills have replaced the compressed air drills and have resulted in a very marked improvement: - of the penetration rates; - of the depth achieved. The Well Drilling Section of Cogema has to drill about 400 km per year with rock drills above ground and holds also the record for depth achieved with this technique, i.e. 400 m in granite. In France, the costs of these types of drilling are for the same depth of the order of one-quarter of the core drilling and half of the drilling with a down-the-hole drill. Cogema has greatly developed the types of well logging which now permits the extension of this type of drilling to the search for other materials than uranium [fr

  10. A Fast Inspection of Tool Electrode and Drilling Depth in EDM Drilling by Detection Line Algorithm.

    Science.gov (United States)

    Huang, Kuo-Yi

    2008-08-21

    The purpose of this study was to develop a novel measurement method using a machine vision system. Besides using image processing techniques, the proposed system employs a detection line algorithm that detects the tool electrode length and drilling depth of a workpiece accurately and effectively. Different boundaries of areas on the tool electrode are defined: a baseline between base and normal areas, a ND-line between normal and drilling areas (accumulating carbon area), and a DD-line between drilling area and dielectric fluid droplet on the electrode tip. Accordingly, image processing techniques are employed to extract a tool electrode image, and the centroid, eigenvector, and principle axis of the tool electrode are determined. The developed detection line algorithm (DLA) is then used to detect the baseline, ND-line, and DD-line along the direction of the principle axis. Finally, the tool electrode length and drilling depth of the workpiece are estimated via detected baseline, ND-line, and DD-line. Experimental results show good accuracy and efficiency in estimation of the tool electrode length and drilling depth under different conditions. Hence, this research may provide a reference for industrial application in EDM drilling measurement.

  11. Slim hole drilling and testing strategies

    Science.gov (United States)

    Nielson, Dennis L.; Garg, Sabodh K.; Goranson, Colin

    2017-12-01

    The financial and geologic advantages of drilling slim holes instead of large production wells in the early stages of geothermal reservoir assessment has been understood for many years. However, the practice has not been fully embraced by geothermal developers. We believe that the reason for this is that there is a poor understanding of testing and reservoir analysis that can be conducted in slim holes. In addition to reservoir engineering information, coring through the cap rock and into the reservoir provides important data for designing subsequent production well drilling and completion. Core drilling requires significantly less mud volume than conventional rotary drilling, and it is typically not necessary to cure lost circulation zones (LCZ). LCZs should be tested by either production or injection methods as they are encountered. The testing methodologies are similar to those conducted on large-diameter wells; although produced and/or injected fluid volumes are much less. Pressure, temperature and spinner (PTS) surveys in slim holes under static conditions can used to characterize temperature and pressure distribution in the geothermal reservoir. In many cases it is possible to discharge slim holes and obtain fluid samples to delineate the geochemical properties of the reservoir fluid. Also in the latter case, drawdown and buildup data obtained using a downhole pressure tool can be employed to determine formation transmissivity and well properties. Even if it proves difficult to discharge a slim hole, an injection test can be performed to obtain formation transmissivity. Given the discharge (or injection) data from a slimhole, discharge properties of a large-diameter well can be inferred using wellbore modeling. Finally, slim hole data (pressure, temperature, transmissivity, fluid properties) together with reservoir simulation can help predict the ability of the geothermal reservoir to sustain power production.

  12. Potential environmental benefits from regulatory consideration of synthetic drilling muds

    International Nuclear Information System (INIS)

    Burke, C.J.; Veil, J.A.

    1995-02-01

    When drilling exploration and production wells for oil and gas, drillers use specialized drilling fluids, referred to as muds, to help maintain well control and to remove drill cuttings from the hole. Historically, either water-based muds (WBMs) or oil-based muds (OBMs) have been used for offshore wells. Recently, in response to US Environmental Protection Agency (EPA) regulations and drilling-waste discharge requirements imposed by North Sea nations, the drilling industry has developed several types of synthetic-based muds (SBMs) that combine the desirable operating qualities of OBMs with the lower toxicity and environmental impact qualities of WBMs. This report describes the operational, environmental, and economic features of all three types of muds and discusses potential EPA regulatory barriers to wider use of SBMs

  13. Drilling and testing hot, high-pressure wells

    Energy Technology Data Exchange (ETDEWEB)

    MacAndrew, R. (Ranger Oil Ltd, Aberdeen (United Kingdom)); Parry, N. (Phillips Petroleum Company United Kingdom Ltd, Aberdeen (United Kingdom)); Prieur, J.M. (Conoco UK Ltd, Aberdeen (United Kingdom)); Wiggelman, J. (Shell UK Exploration and Production, Aberdeen (United Kingdom)); Diggins, E. (Brunei Shell Petroleum (Brunei Darussalam)); Guicheney, P. (Sedco Forex, Montrouge (France)); Cameron, D.; Stewart, A. (Dowell Schlumberger, Aberdeen (United Kingdom))

    Meticulous planning and careful control of operations are needed to safely drill and test high-temperature, high-pressure (HTHP) wells. Techniques, employed in the Central Graben in the UK sector of the North Sea, where about 50 HTHP wells have been drilled, are examined. Three main areas of activity are covered in this comprehensive review: drilling safety, casing and cementation, and testing. The three issues at the heart of HTHP drilling safety are kick prevention, kick detection and well control. Kicks are influxes of reservoir fluid into the well. Test equipment and operations are divided into three sections: downhole, subsea and surface. Also details are given of how this North Sea experience has been used to help plan a jackup rig modification for hot, high-pressure drilling off Brunei. 16 figs., 32 refs.

  14. Reactions of rhodium(I) carbonyl chloride with olefins

    International Nuclear Information System (INIS)

    Varshavskii, Yu.S.; Kiseleva, N.V.; Cherkasova, T.G.; Buzina, N.A.; Bresler, L.S.

    1987-01-01

    The reactions of [Rh(CO) 2 Cl] 2 (Y 0 ) with cyclooctene and several other olefins (1-heptene, 1-hexene, ethylene, and cyclohexene) have been studied by IR and 13 C NMR spectroscopy. The main reaction products are the binuclear complexes Rh 2 L(CO) 3 Cl 2 (Y 1 ) and [RhL(CO)Cl] 2 (Y 2 ), where L denotes the olefin. The extent of replacement of the carbonyl groups depends on the nature of the olefin and the conditions under which the reaction is carried out (the L:Rh ratio and the removal of CO from the reaction sphere). The liquid olefins form the following series according to their ability to replace the carbonyl groups: C 8 H 14 > C 7 H 14 , C 6 H 12 > C 6 H 10 . In the presence of an excess of C 8 H 14 , Y 2 disproportionates with the formation of a dicarbonyl product, which presumably corresponds to the formula Rh(C 8 H 14 ) 2 (CO) 2 Cl (a pentacoordinate complex with a trigonal-bipyramidal structure). The 13 C signal in the NMR spectrum of a solution of Y 2 in C 8 H 14 is a singlet with σ( 13 C) 180.3 ppm, which is an indication of the rapid exchange of the carbonyl groups. Rapid exchange of the CO ligands is also observed in solutions of Y 0 in the olefins (with the exception of C 6 H 10 ). For example, the 13 C signal in the spectrum of a solution of Y 0 in C 8 H 14 is a singlet with σ( 13 C) 179.8 ppm. The spectrum of Y 0 in C 6 H 10 is a doublet with σ( 13 C) = 178.5 ppm and 1 J(CRh) = 76.3 Hz. A scheme for the interaction of Y 0 with olefins based on the conception of the trans antagonism of π-acceptor ligands has been proposed

  15. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis

    Science.gov (United States)

    Schrodi, Yann [Agoura Hills, CA

    2011-11-29

    This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II) ##STR00001## wherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.

  16. Ternary catalyst-olefin-hydroperoxide complexes and their contribution to epoxidation

    International Nuclear Information System (INIS)

    Svitych, R.B.; Rzhevskaya, N.N.; Buchachenko, A.L.; Yablonskij, O.P.; Petukhov, A.A.; Belyaev, V.A.

    1976-01-01

    Electron and NMR spectroscopy have been used for studying the complex formation of catalysts (Mo 5+ , Mn 2+ , Co 2+ ) in double and triple systems: metal-olefin and metal-olefin-hydroperoxide. It has been established that ions of metals form complexes with olefins in the first sphere. The formation has been proved of ternary complexes metal-olefin-hydroperoxide. The structure of the complexes has been proposed with olefins in the first and hydroperoxide in the second sphere of the metal ion. The structure explains known kinetic regularities of epoxydation and the mechanism of the formation of final products, oxide and alcohol. It has been shown that the best catalysts for epoxydation of olefins with hydroperoxides must be the compounds of the metals with an electron state of ion d 0 [ru

  17. A latent ruthenium based olefin metathesis catalyst with a sterically demanding NHC ligand

    KAUST Repository

    Leitgeb, Anita; Abbas, Mudassar E.; Fischer, Roland C.; Poater, Albert; Cavallo, Luigi; Slugovc, Christian

    2012-01-01

    An olefin metathesis catalyst featuring a SIPr NHC and an ester chelating carbene ligand is introduced. In contrast to its previously published SIMes analogue, only the trans dichloro configurated isomer was obtained. The two counterparts are tested in various olefin metathesis reactions, revealing a striking superiority of the new complex in the cross metathesis of olefins with methyl vinyl ketone allowing for full conversion with only 500 ppm catalyst loading. © 2012 The Royal Society of Chemistry.

  18. Pd(II)-Catalyzed Olefination of sp3 C–H Bonds

    Science.gov (United States)

    Wasa, Masayuki; Engle, Keary M.; Yu, Jin-Quan

    2010-01-01

    The first Pd(II)-catalyzed sp3 C–H olefination reaction has been developed using N-arylamide directing groups. Following olefination, the resulting intermediates were found to undergo rapid 1,4-addition to give the corresponding γ lactams. Notably, this method was effective with substrates containing α-hydrogen atoms and could be applied to effect methylene C–H olefination of cyclopropane substrates. PMID:20187642

  19. Direct olefination of fluorinated benzothiadiazoles: a new entry to optoelectronic materials.

    Science.gov (United States)

    Xiao, Yu-Lan; Zhang, Bo; He, Chun-Yang; Zhang, Xingang

    2014-04-14

    Fluorinated olefin-containing benzothiadiazoles have important applications in optoelectronic materials. Herein, we reported the direct olefination of fluorinated benzothiadiazoles, as catalyzed by palladium. The reaction proceeds under mild reaction conditions and shows high functional-group compatibility. A preliminary study of the properties of the resulting symmetrical and unsymmetrical olefin-containing fluorinated benzothiadiazoles in red-light-emitting dyes has also been conducted. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. The activation mechanism of Fe-based olefin metathesis catalysts

    KAUST Repository

    Poater, Albert

    2014-08-01

    Density functional theory calculations have been used to describe the first turnover for olefin metathesis reaction of a homogenous Fe-based catalyst bearing a N-heterocyclic carbene ligand with methoxyethene as a substrate. Equal to conventional Ru-based catalysts, the activation of its Fe congener occurs through a dissociative mechanism, however with a more exothermic reaction energy profile. Predicted upper energy barriers were calculated to be on average ∼2 kcal/mol more beneficial for Fe catalyzed metathesis. Overall, this present computational study emphasises on advantages of Fe-based metathesis and gives a potential recipe for the design of an efficient Fe-based olefin metathesis catalysts. © 2014 Elsevier B.V.

  1. The activation mechanism of Fe-based olefin metathesis catalysts

    KAUST Repository

    Poater, Albert; Pump, Eva; Vummaleti, Sai V. C.; Cavallo, Luigi

    2014-01-01

    Density functional theory calculations have been used to describe the first turnover for olefin metathesis reaction of a homogenous Fe-based catalyst bearing a N-heterocyclic carbene ligand with methoxyethene as a substrate. Equal to conventional Ru-based catalysts, the activation of its Fe congener occurs through a dissociative mechanism, however with a more exothermic reaction energy profile. Predicted upper energy barriers were calculated to be on average ∼2 kcal/mol more beneficial for Fe catalyzed metathesis. Overall, this present computational study emphasises on advantages of Fe-based metathesis and gives a potential recipe for the design of an efficient Fe-based olefin metathesis catalysts. © 2014 Elsevier B.V.

  2. Methanol conversion to lower olefins over RHO type zeolite

    KAUST Repository

    Masih, Dilshad

    2013-07-01

    Eight-membered ring small-pore zeolite of RHO-type topology has been synthesized, characterized and tested for methanol-to-olefin (MTO) reaction. The zeolite was hydrothermally crystallized from the gel with Si/Al ratio of 5.0. It showed a high BET specific surface area (812 m2 g-1), micropore volume (0.429 cm3 g-1), and acid amount (2.53 mmol g-1). Scanning electron microscopy observations showed small crystallites of about 1 μm. The zeolite was active for MTO reaction with 100% methanol conversions at 623-723 K, whereas selectivity to lower olefins changed with time. © 2013 Elsevier B.V.

  3. Methyltrioxorhenium as catalyst of a novel aldehyde olefination

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, W.A. (Technische Univ. Muenchen, Garching (Germany). Anorganisch-Chemisches Inst.); Wang Mei (Academia Sinica, Dalian Inst. of Chemical Physics (China))

    1991-12-01

    From aldehydes or cyclic ketones, diazoalkanes, and teritiary phosphanes, olefins may be prepared with MTO as catalyst. In particular, diazoacetates and -malonates (R{sup 2}, R{sup 3} = H, CO{sub 2}Et, or 2 x CO{sub 2}Me) can be transformed into olefins with aliphatic and aromatic aldehydes (R{sup 1} = iPr, trans-PhCH=CH, Ph, 4-NO{sub 2}C{sub 6}H{sub 4}, etc.). Readily accessible starting materials, easy handling, mild reaction conditions, and good yields characterize the new synthesis method. (R' = Ph, 3-C{sub 6}H{sub 4}SO{sub 3}Na, nBu.) (orig.).

  4. A three-membered ring approach to carbonyl olefination.

    Science.gov (United States)

    Niyomchon, Supaporn; Oppedisano, Alberto; Aillard, Paul; Maulide, Nuno

    2017-10-23

    The carbon-carbon double bond, with its diverse and multifaceted reactivity, occupies a prominent position in organic synthesis. Although a variety of simple alkenes are readily available, the mild and chemoselective introduction of a unit of unsaturation into a functionalized organic molecule remains an ongoing area of research, and the olefination of carbonyl compounds is a cornerstone of such approaches. Here we show the direct olefination of hydrazones via the intermediacy of three-membered ring species generated by addition of sulfoxonium ylides, departing from the general dogma of alkenes synthesis from carbonyls. Moreover, the mild reaction conditions and operational simplicity of the transformation render the methodology appealing from a practical point of view.

  5. Evacuation drill at CMS

    CERN Multimedia

    Niels Dupont-Sagorin and Christoph Schaefer

    2012-01-01

    Training personnel, including evacuation guides and shifters, checking procedures, improving collaboration with the CERN Fire Brigade: the first real-life evacuation drill at CMS took place on Friday 3 February from 12p.m. to 3p.m. in the two caverns located at Point 5 of the LHC.   CERN personnel during the evacuation drill at CMS. Evacuation drills are required by law and have to be organized periodically in all areas of CERN, both above and below ground. The last drill at CMS, which took place in June 2007, revealed some desiderata, most notably the need for a public address system. With this equipment in place, it is now possible to broadcast audio messages from the CMS control room to the underground areas.   The CMS Technical Coordination Team and the GLIMOS have focused particularly on preparing collaborators for emergency situations by providing training and organizing regular safety drills with the HSE Unit and the CERN Fire Brigade. This Friday, the practical traini...

  6. Decarbonisation of olefin processes using biomass pyrolysis oil

    International Nuclear Information System (INIS)

    Sharifzadeh, M.; Wang, L.; Shah, N.

    2015-01-01

    Highlights: • Decarbonization of olefin processes using biomass pyrolysis oil was proposed. • The decarbonization is based on integrated catalytic processing of bio-oil. • The retrofitted process features significant economic and environmental advantages. - Abstract: An imperative step toward decarbonisation of current industrial processes is to substitute their petroleum-derived feedstocks with biomass and biomass-derived feedstocks. For decarbonisation of the petrochemical industry, integrated catalytic processing of biomass pyrolysis oil (also known as bio-oil) is an enabling technology. This is because, under certain conditions, the reaction products form a mixture consisting of olefins and aromatics, which are very similar to the products of naphtha hydro-cracking in the conventional olefin processes. These synergies suggest that the catalytic bio-oil upgrading reactors can be seamlessly integrated to the subsequent separation network with minimal retrofitting costs. In addition, the integrated catalytic processing provides a high degree of flexibility for optimization of different products in response to market fluctuations. With the aim of assessing the techno-economic viability of this pathway, five scenarios in which different fractions of bio-oil (water soluble/water insoluble) were processed with different degrees of hydrogenation were studied in the present research. The results showed that such a retrofit is not only economically viable, but also provides a high degree of flexibility to the process, and contributes to decarbonisation of olefin infrastructures. Up to 44% reductions in greenhouse gas emissions were observed in several scenarios. In addition, it was shown that hydrogen prices lower than 6 $/kg will result in bio-based chemicals which are cheaper than equivalent petrochemicals. Alternatively, for higher hydrogen prices, it is possible to reform the water insoluble phase of bio-oil and produce bio-based chemicals, cheaper than

  7. Surface science of single-site heterogeneous olefin polymerization catalysts

    OpenAIRE

    Kim, Seong H.; Somorjai, Gabor A.

    2006-01-01

    This article reviews the surface science of the heterogeneous olefin polymerization catalysts. The specific focus is on how to prepare and characterize stereochemically specific heterogeneous model catalysts for the Ziegler–Natta polymerization. Under clean, ultra-high vacuum conditions, low-energy electron irradiation during the chemical vapor deposition of model Ziegler–Natta catalysts can be used to create a “single-site” catalyst film with a surface structure that produces only isotactic ...

  8. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    Science.gov (United States)

    Ginosar, Daniel M.; Fox, Robert V.; Kong, Peter C.

    2000-01-01

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  9. Retrofit with membrane the Paraffin/Olefin separation

    Energy Technology Data Exchange (ETDEWEB)

    Motelica, A.; Bruinsma, O.S.L.; Kreiter, R.; Den Exter, M.J.; Vente, J.F. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2012-10-15

    Olefins, such as ethylene, propylene, and butadiene, are among the most produced intermediates in petrochemical industry. They are produced from a wide range of hydrocarbon feedstocks (ethane, propane, butane, naphtha, gas oil) via a cracking process. The last step in this process is the separation of olefins from other hydrocarbons, which is traditionally performed with distillation. As the physicochemical properties, such as volatility and boiling point, of the compounds are very similar, the purification becomes capital and energy intensive. For example, the top of an ethylene/ethane distillation column needs to be chilled to -30C and this requires large amount of electric energy consumption. The separation of butadiene from the C4-fraction is performed with the aid of an additional solvent. This solvent has to be regenerated at the cost of additional high temperature steam. To overcome these separation disadvantages of olefin/paraffin separation, different separation methods have been investigated and proposed in recent years. Suggested options are based on better heat integration of the overall process, or on novel separation systems such as Heat Integrated Distillation Columns, membrane separation, adsorption-desorption systems or on hybrid separation methods, for example, distillation combined with membrane separation.

  10. Composição de argilas organofílicas obtida com tensoativo não-iônico para fluidos de perfuração base orgânica Compositions of organoclays obtained with nonionic surfactant for organic base drilling fluids

    Directory of Open Access Journals (Sweden)

    F. K. A. Sousa

    2011-06-01

    Full Text Available Este trabalho tem como objetivo o estudo do efeito da composição de misturas de argilas bentoníticas organofílicas na reologia de fluidos de perfuração base orgânica. As composições foram estudadas por meio de delineamento de misturas, viscosidade aparente, plástica e limite de escoamento e dos testes recomendados pelo Instituto Americano de Petróleo, API (peso específico, estabilidade elétrica e volume de filtrado. Os resultados foram comparados aos obtidos com fluido padrão utilizado pela Petrobrás. Dentre as composições desenvolvidas, duas apresentaram potencial de utilização em fluidos de perfuração base orgânica, atendendo a maioria das propriedades. Foram desenvolvidas composições contendo as argilas de qualidade "inferior" (Bofe e verde-lodo em maior quantidade e o mínimo da argila Chocolate UBM, considerada como a melhor argila da região das minas de Boa Vista, PB, para uso em fluidos de perfuração.This paper aims to study the effect of compositions of bentonite organoclays for drilling fluids containing organic base. The compositions were studied using the mixture design of experiment methodology and their performance evaluated by rheological behavior (flow curves, the initial gel, final gel apparent viscosity, plastic, and flow limit and the tests recommended by API (specific gravity, electrical stability and filtrate volume. Results were compared to those obtained with standard fluid used by Petrobrás. The results showed that among the developed compositions, two compositions showed promising potential for use in organic drilling fluids, achieving most of the limits of the normalization. Compositions containing high amount of low quality clays (Bofe and verde-lodo and a minimum of high quality clay (Chocolate of the mines of Boa Vista PB were developed for using in drilling fluids operation.

  11. Mars Drilling Status

    Science.gov (United States)

    Mandell, Humboldt, C., Jr.

    2002-01-01

    This slide presentation reviews the current status of work to explore Mars beneath the surface of planet. One of the objective of this work is to enable further exploration of Mars by humans. One of the requirements for this is to find water on Mars. The presences of water is critical for Human Exploration and a permanent presence on Mars. If water is present beneath the surface it is the best chance of finding life on Mars. The presentation includes a timeline showing the robotic missions, those that have already been on Mars, and planned missions, an explanation of why do we want to drill on Mars, and some of the challenges, Also include are reviews of a missions that would drill 200 and 4,000 to 6,000 meters into the Martian bedrock, and a overview description of the drill. There is a view of some places where we have hopes of finding water.

  12. Life cycle assessment of energy consumption and GHG emissions of olefins production from alternative resources in China

    International Nuclear Information System (INIS)

    Xiang, Dong; Yang, Siyu; Li, Xiuxi; Qian, Yu

    2015-01-01

    Highlights: • Conduct a life cycle energy use and GHG emissions of olefins production processes. • Analyse effects of carbon capture and efficiency on alternative olefins production. • Analyse life cycle performance of Chinese olefins industry in three key periods. • Present the advantages and challenges of alternative olefins routes. - Abstract: Olefins are important platform chemicals widely used in industry. In terms of the short supply of oil resources, natural gas and coal are two significant alternative feedstocks. In this paper, energy consumption and GHG emissions of olefins production are analysed with life cycle assessment methods. Results showed the energy consumption and GHG emissions of natural gas-to-olefins are roughly equivalent to those of oil-to-olefins, while coal-to-olefins suffers from higher energy consumption and serious GHG emissions, including 5793 kg eq. CO 2 /t olefins of direct emissions and 5714 kg eq. CO 2 /t olefins of indirect emissions. To address the problem, the effect of carbon capture on coal-to-olefins is investigated. In comprehensive consideration of energy utilization, environmental impact, and economic benefit, the coal-to-olefins with 80% CO 2 capture of the direct emissions is found to be an appropriate choice. With this carbon capture configuration, the direct emissions of the coal-to-olefins are reduced to 1161 kg eq. CO 2 /t olefins. However, the indirect emissions are still not captured, which should be strictly monitored and significantly reduced. Finally, a scenario analysis is conducted to estimate resource utilization and GHG emissions of olefins production of China in 2020. Several suggestions are also proposed for policy making on the sustainable development of olefins industry

  13. Ultrasonically assisted drilling of rocks

    Science.gov (United States)

    Mikhailova, N. V.; Onawumi, P. Y.; Roy, A.; Silberschmidt, V. V.

    2018-05-01

    Conventional drilling of rocks can generate significant damage in the drilled material; a material layer is often split off a back surface of a sample during drilling, negatively affecting its strength. To improve finish quality, ultrasonically assisted drilling (UAD) was employed in two rocks - sandstone and marble. Damage areas in both materials were reduced in UAD when compared to conventional drilling. Reductions in a thrust force and a torque reduction were observed only for UAD in marble; ultrasonic assistance in sandstone drilling did not result in improvements in this regard.

  14. Rotary core drills

    Energy Technology Data Exchange (ETDEWEB)

    1967-11-30

    The design of a rotary core drill is described. Primary consideration is given to the following component parts of the drill: the inner and outer tube, the core bit, an adapter, and the core lifter. The adapter has the form of a downward-converging sleeve and is mounted to the lower end of the inner tube. The lifter, extending from the adapter, is split along each side so that it can be held open to permit movement of a core. It is possible to grip a core by allowing the lifter to assume a closed position.

  15. Drilling comparison in "warm ice" and drill design comparison

    DEFF Research Database (Denmark)

    Augustin, L.; Motoyama, H.; Wilhelms, F.

    2007-01-01

    For the deep ice-core drilling community, the 2005/06 Antarctic season was an exciting and fruitful one. In three different Antarctic locations, Dome Fuji, EPICA DML and Vostok, deep drillings approached bedrock (the ice-water interface in the case of Vostok), emulating what had previously been...... achieved at NorthGRIP, Greenland, (summer 2003 and 2004) and at EPICA Dome C2, Antarctica (season 2004/05). For the first time in ice-core drilling history, three different types of drill (KEMS, JARE and EPICA) simultaneously reached the depth of 'warm ice' under high pressure. After excellent progress...... at each site, the drilling rate dropped and the drilling teams had to deal with refrozen ice on cutters and drill heads. Drills have different limits and perform differently. In this comparative study, we examine depth, pressure, temperature, pump flow and cutting speed. Finally, we compare a few...

  16. Advanced Seismic While Drilling System

    Energy Technology Data Exchange (ETDEWEB)

    Robert Radtke; John Fontenot; David Glowka; Robert Stokes; Jeffery Sutherland; Ron Evans; Jim Musser

    2008-06-30

    A breakthrough has been discovered for controlling seismic sources to generate selectable low frequencies. Conventional seismic sources, including sparkers, rotary mechanical, hydraulic, air guns, and explosives, by their very nature produce high-frequencies. This is counter to the need for long signal transmission through rock. The patent pending SeismicPULSER{trademark} methodology has been developed for controlling otherwise high-frequency seismic sources to generate selectable low-frequency peak spectra applicable to many seismic applications. Specifically, we have demonstrated the application of a low-frequency sparker source which can be incorporated into a drill bit for Drill Bit Seismic While Drilling (SWD). To create the methodology of a controllable low-frequency sparker seismic source, it was necessary to learn how to maximize sparker efficiencies to couple to, and transmit through, rock with the study of sparker designs and mechanisms for (a) coupling the sparker-generated gas bubble expansion and contraction to the rock, (b) the effects of fluid properties and dynamics, (c) linear and non-linear acoustics, and (d) imparted force directionality. After extensive seismic modeling, the design of high-efficiency sparkers, laboratory high frequency sparker testing, and field tests were performed at the University of Texas Devine seismic test site. The conclusion of the field test was that extremely high power levels would be required to have the range required for deep, 15,000+ ft, high-temperature, high-pressure (HTHP) wells. Thereafter, more modeling and laboratory testing led to the discovery of a method to control a sparker that could generate low frequencies required for deep wells. The low frequency sparker was successfully tested at the Department of Energy Rocky Mountain Oilfield Test Center (DOE RMOTC) field test site in Casper, Wyoming. An 8-in diameter by 26-ft long SeismicPULSER{trademark} drill string tool was designed and manufactured by TII

  17. Drill Sergeant Candidate Transformation

    Science.gov (United States)

    2009-02-01

    leadership styles of NCOs entering Drill Sergeant School (DSS). ARI also developed and administered a prototype DS Assessment Battery to assess...preferred leadership styles . DSS training increases both the degree to which the DSC feels obligated to and identifies with the Army. DSS training...4 TABLE 3. PREFERRED LEADERSHIP STYLES DEFINITIONS .............................................6 TABLE 4. DSC CHANGE IN

  18. Measurement Space Drill Support

    Science.gov (United States)

    2015-08-30

    II) H-47 Block II (I) *H-47 Block II (II) AVN FVL Att (I) * AVN FVL Att (II) TRAC- MTRY F2025B Logistic Flow MS Drill Support FY15 Research...does not have to use other AVN /ground assets to cover the area, freeing these assets to perform other missions and potentially enhancing the

  19. Palladium-Catalyzed ortho-Olefination of Phenyl Acetic and Phenyl Propylacetic Esters via C-H Bond Activation.

    Science.gov (United States)

    Hu, Jundie; Guan, Mingyu; Han, Jian; Huang, Zhi-Bin; Shi, Da-Qing; Zhao, Yingsheng

    2015-08-21

    A highly regioselective palladium-catalyzed ester-directed ortho-olefination of phenyl acetic and propionic esters with olefins via C-H bond activation has been developed. A wide variety of phenyl acetic and propionic esters were tolerated in this transformation, affording the corresponding olefinated aromatic compounds. The ortho-olefination of heterocyclic acetic and propionic esters also took place smoothly giving the products in good yields, thus proving the potential utility of this protocol in synthetic chemistry.

  20. Sandia's Geothermal Advanced Drill Rig Instrumentation Assists Critical Oil and Gas Drilling Operation

    International Nuclear Information System (INIS)

    Staller, George E.; Whitlow, Gary

    1999-01-01

    about 30 days. Several other Sandia instruments being developed for geothermal drilling are also being evaluated during this operation, Successful performance of these instruments on this important drilling job will reinforce our efforts to commercialize this technology for the geothermal and oil and gas drilling industries. Sandia's Rolling Float Meter was developed through the Lost Circulation Technology Program sponsored by the U. S. Department of Energy, Office of Geothermal Technologies. It monitors drilling fluid returns to rapidly detect loss of circulation during geothermal drilling. Lost circulation is particularly prevalent in geothermal wells, and can add as much as 10% to the total cost of drilling the well. Consequently, rapid detection and treatment of lost circulation is necessary for cost- effective geothermal drilling. Sandia has been evaluating and demonstrating the capabilities of the RFM to the geothermal industry for several years. In addition to lost circulation, the RFM is also useful for accurately detecting well kicks. Contacts have been made with mud logging companies that are involved with both geothermal and oil and gas drilling operations

  1. 76 FR 5319 - Regulation of Fuel and Fuel Additives: Alternative Test Method for Olefins in Gasoline

    Science.gov (United States)

    2011-01-31

    ... Regulation of Fuel and Fuel Additives: Alternative Test Method for Olefins in Gasoline AGENCY: Environmental... gasoline. This proposed rule will provide flexibility to the regulated community by allowing an additional... A. Alternative Test Method for Olefins in Gasoline III. Statutory and Executive Order Reviews A...

  2. 76 FR 65382 - Regulation of Fuel and Fuel Additives: Alternative Test Method for Olefins in Gasoline

    Science.gov (United States)

    2011-10-21

    ... Regulation of Fuel and Fuel Additives: Alternative Test Method for Olefins in Gasoline AGENCY: Environmental... gasoline. This final rule will provide flexibility to the regulated community by allowing an additional... Method for Olefins in Gasoline III. Statutory and Executive Order Reviews A. Executive Order 12866...

  3. Oxidative cracking of n-hexane: a catalytic pathway to olefins

    NARCIS (Netherlands)

    Boyadjian, C.A.

    2010-01-01

    Steam cracking, the major, current existing route for light olefin production, is the most energy consuming process in the chemical industry. The need for an energy efficient processes, urged substantial research work for the development of new catalytic technologies for light olefin production.

  4. Pd(II)-Catalyzed Enantioselective C-H Olefination of Diphenylacetic Acids

    Science.gov (United States)

    Shi, Bing-Feng; Zhang, Yang-Hui; Lam, Jonathan K.; Wang, Dong-Hui; Yu, Jin-Quan

    2009-01-01

    Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of mono-protected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate. PMID:20017549

  5. Rhodium-Catalyzed Regioselective C7-Olefination of Indazoles Using an N-Amide Directing Group.

    Science.gov (United States)

    Guo, Lei; Chen, Yanyu; Zhang, Rong; Peng, Qiujun; Xu, Lanting; Pan, Xianhua

    2017-02-01

    A rhodium-catalyzed regioselective C-H olefination of indazole is described. This protocol relies on the use of an efficient and removable N,N-diisopropylcarbamoyl directing group, which offers facile access to C7-olefinated indazoles with high regioselectivity, ample substrate scope and broad functional group tolerance. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Redox-Neutral Rh(III)-Catalyzed Olefination of Carboxamides with Trifluoromethyl Allylic Carbonate.

    Science.gov (United States)

    Park, Jihye; Han, Sangil; Jeon, Mijin; Mishra, Neeraj Kumar; Lee, Seok-Yong; Lee, Jong Suk; Kwak, Jong Hwan; Um, Sung Hee; Kim, In Su

    2016-11-18

    The rhodium(III)-catalyzed olefination of various carboxamides with α-CF 3 -substituted allylic carbonate is described. This reaction provides direct access to linear CF 3 -allyl frameworks with complete trans-selectivity. In particular, a rhodium catalyst provided Heck-type γ-CF 3 -allylation products via the β-O-elimination of rhodacycle intermediate and subsequent olefin migration process.

  7. Drilling mud and cement slurry rheology manual

    Energy Technology Data Exchange (ETDEWEB)

    This book is not primarily concerned with theory. Its basic approach is practical. It has attempted to present a logical treatment which will be easy to apply in practice. As a result, certain computing methods were omitted, and precision sometimes has to be sacrificed to simplicity. However, no apology is made for the use of such approximations; in fact, any attempt at rigor would be doomed to failure, in view of the many inherent factors which do not lend themselves to quantitative treatment. Chapter 1: deals with fundamental concepts. Chapter 2: refers to the general principles involved in determining rheological parameters of drilling fluids and cement slurries. Chapter 3: relates to practical methods for using the results obtained in the first two Chapters, in units employed on the worksite. It is primarily intended for technicians called upon to make ''hydraulic'' computations during drilling. Chapter 4: contains several examples.

  8. Adsorption heats of olefins on supported MoO3/Al2O3 catalists

    International Nuclear Information System (INIS)

    Grinev, V.E.; Madden, M.; Khalit, V.A.; Aptekar', E.L.; Aldag, A.; Krylov, O.V.

    1983-01-01

    Adsorption heats of C 2 H 4 , C 3 H 6 and C 4 H 8 on supported MoO 3 /Al 2 O 3 catalysts containing 6, 10 and 15 wt. % of MoO 3 at 25, 77 and 195 deg are determimed. Adsorption heat of an olefin increases with a growing length of its carbonic chain. The number of adsorbed olefin molecules grows with an increase in the MoO 3 concentration, while initial adsorption heats decrease. The number of adsorbed olefins is proportional to mean rate of molybdenum reduction in catalysts. Adsorption heats of oxygen on the surface of the catalysts with preliminarily adsorbed olefins are determined. It is shown that adsorption of oxygen and olefins proceeeds both on the same and on different centres of the surface. Mechanisms of surface interactions are discussed

  9. Drilling subsurface wellbores with cutting structures

    Science.gov (United States)

    Mansure, Arthur James; Guimerans, Rosalvina Ramona

    2010-11-30

    A system for forming a wellbore includes a drill tubular. A drill bit is coupled to the drill tubular. One or more cutting structures are coupled to the drill tubular above the drill bit. The cutting structures remove at least a portion of formation that extends into the wellbore formed by the drill bit.

  10. Improving Coolant Effectiveness through Drill Design Optimization in Gundrilling

    Science.gov (United States)

    Woon, K. S.; Tnay, G. L.; Rahman, M.

    2018-05-01

    Effective coolant application is essential to prevent thermo-mechanical failures of gun drills. This paper presents a novel study that enhances coolant effectiveness in evacuating chips from the cutting zone using a computational fluid dynamic (CFD) method. Drag coefficients and transport behaviour over a wide range of Reynold numbers were first established through a series of vertical drop tests. With these, a CFD model was then developed and calibrated with a set of horizontal drilling tests. Using this CFD model, critical drill geometries that lead to poor chip evacuation including the nose grind contour, coolant hole configuration and shoulder dub-off angle in commercial gun drills are identified. From this study, a new design that consists a 20° inner edge, 15° outer edge, 0° shoulder dub-off and kidney-shaped coolant channel is proposed and experimentally proven to be more superior than all other commercial designs.

  11. The development of Canadian leadership in horizontal drilling technology

    Energy Technology Data Exchange (ETDEWEB)

    Hawkins, J R

    1989-01-01

    Horizontal wells are of increasing interest in the oil and gas industry, as is evident from the increase in the numbers of such wells being drilled. Horizontal well technology is used to improve production rates, notably in low permeability formations; to capture reserves if a reservoir is not economic using non-horizontal wells; to manage breakthrough of sweep fluids and increase sweep efficiency; and to extend the areal reach from a single surface location, especially in offshore production. The types of horizontal wells, differentiated on the basis of how quickly the well becomes horizontal, are briefly outlined and a short history of horizontal wells is presented. Canadian accomplishments in this field are then described, including steerable drilling systems, measurement-while-drilling systems, management of hole drag and torque, and well completion techniques. About 25 horizontal wells are forecast to be drilled in Canada in 1989, indicating the favorable future of this technology. 2 figs., 5 tabs.

  12. Synthesis of thermoplastic poly(ester-olefin elastomers

    Directory of Open Access Journals (Sweden)

    Tanasijević Branka

    2004-01-01

    Full Text Available A series of thermoplastic poly(ester-olefin elastomers, based on poly(ethylene-stat-butylene, HO-PEB-OH, as the soft segment and poly (butylene terephthalate, PBT, as the hard segment, were synthesized by a catalyzed transesterification reaction in solution. The incorporation of soft hydrogenated poly(butadiene segments into the copolyester backbone was accomplished by the polycondensation of α, ω-dihydroxyl telechelic HO-PEB-OH, (PEB Mn = 3092 g/mol with 1,4-butanediol (BD and dimethyl terephthalate (DMT in the presence of a 50 wt-% high boiling solvent i.e., 1,2,4-trichlorobenzene. The molar ratio of the starting comonomers was selected to result in a constant hard to soft weight ratio of 60:40. The synthesis was optimized in terms of both the concentration of catalyst, tetra-n-butyl-titanate (Ti(OBu4, and stabilizer, N,N'-diphenyl-p-phenylenediamine (DPPD, as well as the reaction time. It was found that the optimal catalyst concentration (Ti(OBu4 for the synthesis of these thermoplastic elastomers was 1.0 mmol/mol ester and the optimal DPPD concentration was 1.0 wt-%. The extent of the reaction was followed by measuring the inherent viscosity of the reaction mixture. The effectiveness of the incorporation of the soft segments into the copolymer chains was proved by Soxhlet extraction with chloroform. The molecular structures, composition and the size of the synthesized poly(ester-butylenes were verified by 1H NMR spectroscopy, viscometry of dilute solutions and the complex dynamic melt viscosity. The thermal properties of poly(ester-olefins were investigated by differential scanning calorimetry (DSC. The degree of crystallinity was also determined by DSC. The thermal and thermo-oxidative stability were investigated by thermogravimetric analysis (TGA. The rheological properties of poly(ester-olefins were investigated by dynamic mechanical spectroscopy in the melt and solid state.

  13. Deep-Time drilling in the Australian Archean: the Agouron Institute geobiological drilling project. (Invited)

    Science.gov (United States)

    Buick, R.

    2010-12-01

    The Agouron Institute has sponsored deep-time drilling across the South African Archean-Proterozoic boundary, investigating the rise of oxygen over an onshore-offshore environmental transect. It is now supporting a drilling program in the Australian Archean of the Pilbara Craton, addressing a similar theme but with the added goal of resolving controversy over the age and origin of hydrocarbon biomarker molecules in ancient kerogenous shales. As these have been claimed to provide evidence for the evolution of oxygenic photosynthesis long before the rise of atmospheric oxygen to persistently high levels during the ~2.3 Ga “Great Oxidation Event”, their syngenesis with their host shales is thus of critical importance for the interpretation of Earth’s early oxygenation history. During the first drilling season, 3 holes were drilled using techniques and equipment to minimize organic geochemical contamination (new drill-string components cleaned before drilling potentially biomarker-bearing rocks, pre-contamination of drilling fluid with a synthetic organic compound of similar geochemical characteristics to biomarkers, sterile cutting and storage of samples immediately upon retrieval from the core-barrel). The initial hole was a blank control for organic geochemistry, drilled into rocks too metamorphosed to retain biomarker molecules. These rocks, cherts, carbonates and pelites of the 3.52 Ga Coucal Formation, Coonterunah Group, have been metamorphosed to upper greenschist facies at temperatures near 500°C and so should have had any ancient soluble hydrocarbons destroyed. However, because they contain both carbonate and organic carbon, these rocks can instead provide isotopic information about the earliest evolution of biological metabolism as they possess residues of both the reactant and product sides of the carbon-fixation reaction. The second hole sampled an on-shore section of carbonates and kerogenous shales in the ~2.65 Ga Carawine Dolomite and Lewin Shale

  14. Transmissive Olefination Route to Putative “Morinol I” Lignans

    Science.gov (United States)

    Yao, Lihua; Pitta, Bhaskar; Ravikumar, P. C.; Purzycki, Matthew; Fleming, Fraser F.

    2012-01-01

    A series of morinol-type lignans were rapidly assembled using a Grignard-based transmissive olefination. In combination with palladium-catalyzed arylations, the strategy provides stereoselective access to (7Z, 7′E), (7E, 7′E), (7E, 7′Z) morinol diastereomers and the (7Z, 8′E) and (7E, 8′E) conjugated analogs. Critical for the E/Z-stereoselectivity is a new, general method for converting alkenenitriles to alkenemethanols that circumvents the enal E/Z isomerization commonly encountered during conventional i-Bu2AlH reduction. PMID:22432777

  15. Radiation chemical addition of dimethylformamide to α-olefins

    International Nuclear Information System (INIS)

    Dederichs, B.; Saus, A.; Lennertz, A.M.

    1977-10-01

    With n-hexene-1, n-octene-1 and n-decene-1 the radiation-initiated addition of demethyl formamide to α-olefins is described for the fist time. N,N-dimethyl alkane carbonic acid amides and N-methyl-N-alkyl formamides are formed in a ratio of about 50:50. The addition reaction is investigated in depencence of a solvent, of the ratio of the reaction, temperature, reaction time and dose rate. Mechanistic considerations are performed by radiolysis experiments of dimethyl formamide. (orig.) [de

  16. High Temperature Piezoelectric Drill

    Science.gov (United States)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom

    2012-01-01

    Venus is one of the planets in the solar systems that are considered for potential future exploration missions. It has extreme environment where the average temperature is 460 deg C and its ambient pressure is about 90 atm. Since the existing actuation technology cannot maintain functionality under the harsh conditions of Venus, it is a challenge to perform sampling and other tasks that require the use of moving parts. Specifically, the currently available electromagnetic actuators are limited in their ability to produce sufficiently high stroke, torque, or force. In contrast, advances in developing electro-mechanical materials (such as piezoelectric and electrostrictive) have enabled potential actuation capabilities that can be used to support such missions. Taking advantage of these materials, we developed a piezoelectric actuated drill that operates at the temperature range up to 500 deg C and the mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) configuration. The detailed results of our study are presented in this paper

  17. Offset drilling obligations

    International Nuclear Information System (INIS)

    Boyd, K.D.; Kalmakoff, J.J.

    1998-01-01

    A review of the 'offset well' clause found in freehold and Crown natural gas and petroleum leases was presented. The objective was to provide lessors and lessees with a clear understanding of the rights and obligations associated with offset wells. It was noted that offset well obligations vary according to the form of lease used, the type of offsetting well, the regulatory regime and the geophysical characteristics of the producing formation. Some suggestions were made as to how current versions of the offset well clause can be amended to overcome some of the problems encountered in applying the clause to an offset horizontal well that has been drilled on adjoining lands. Failure to resolve the new issues presented by horizontal drilling technology in terms of documentation, which records respective rights and obligations on the basis of generally accepted principles, will result in large numbers of conflicts and unnecessary litigation. 144 refs., 1 fig

  18. Ecotoxicological testing of performance fluids

    International Nuclear Information System (INIS)

    Kallqvist, T.

    1990-05-01

    The report deals with a project comprising the testing of drilling fluids concerning ecotoxicology, biological degradation, and toxicity. Two types of drilling fluids were tested for toxic effects on marine algae and biological degradability. A fluid based on mineral oil was readily degradable (98% DOC removal in 28 days) while an ether based oil degraded more slowly (56% DOC removal in 28 days). The toxicity of both fluids was tested after emulsification of the oils in water and separating the oil and water phase after equilibration. The EC 50 values obtained with this approach were 8.15 g/l for the oil based fluid and 116 g/l for the ether fluid. 9 figs., 8 tabs

  19. DALI - drilling advisor with logic interpretations: methodological issues for designing underbalanced drilling operations. Improving efficiency using case-based reasonic

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Gustavo A.; Velazquez C, David [Mexican Oil Institute, Mexico DF (Mexico)

    2004-07-01

    A system that applies a method of knowledge-intensive case-based reasoning, for repair and prevention of unwanted events in the domain of offshore oil well drilling, has been developed in cooperation with an oil company. From several reoccurring problems during oil well drilling the problem of 'lost circulation', i.e. loss of circulating drilling fluid into the geological formation, was picked out as a pilot problem. An extensive general knowledge model was developed for the domain of oil well drilling. Different cases were created on the basis of information from one Mexican Gulf operator. When the completed CBR-system was tested against a new case, cases with descending similarity were selected by the tool. In an informal evaluation, the two best fitting cases proved to give the operator valuable advise on how to go about solving the new case (author)

  20. Separation of Olefin/Paraffin Mixtures with Carrier Facilitated Membrane Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Merkel, T.C.; Blanc, R.; Zeid, J.; Suwarlim, A.; Firat, B.; Wijmans, H.; Asaro, M. (SRI); Greene, M.(Lummus)

    2007-03-12

    This document describes the results of a DOE funded joint effort of Membrane Technology and Research Inc. (MTR), SRI International (SRI), and ABB Lummus (ABB) to develop facilitated transport membranes for olefin/paraffin separations. Currently, olefin/paraffin separation is done by distillation—an extremely energy-intensive process because of the low relative volatilities of olefins and paraffins. If facilitated transport membranes could be successfully commercialized, the potential energy savings achievable with this membrane technology are estimated to be 48 trillion Btu per year by the year 2020. We discovered in this work that silver salt-based facilitated transport membranes are not stable even in the presence of ideal olefin/paraffin mixtures. This decline in membrane performance appears to be caused by a previously unrecognized phenomenon that we have named olefin conditioning. As the name implies, this mechanism of performance degradation becomes operative once a membrane starts permeating olefins. This project is the first study to identify olefin conditioning as a significant factor impacting the performance of facilitated olefin transport membranes. To date, we have not identified an effective strategy to mitigate the impact of olefin conditioning. other than running at low temperatures or with low olefin feed pressures. In our opinion, this issue must be addressed before further development of facilitated olefin transport membranes can proceed. In addition to olefin conditioning, traditional carrier poisoning challenges must also be overcome. Light, hydrogen, hydrogen sulfide, and acetylene exposure adversely affect membrane performance through unwanted reaction with silver ions. Harsh poisoning tests with these species showed useful membrane lifetimes of only one week. These tests demonstrate a need to improve the stability of the olefin complexing agent to develop membranes with lifetimes satisfactory for commercial application. A successful effort

  1. Development of drilling foams for geothermal applications

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, W.J.; Remont, L.J.; Rehm, W.A.; Chenevert, M.E.

    1980-01-01

    The use of foam drilling fluids in geothermal applications is addressed. A description of foams - what they are, how they are used, their properties, equipment required to use them, the advantages and disadvantages of foams, etc. - is presented. Geothermal applications are discussed. Results of industry interviews presented indicate significant potential for foams, but also indicate significant technical problems to be solved to achieve this potential. Testing procedures and results of tests on representative foams provide a basis for work to develop high-temperature foams.

  2. Hydroxycarbonylation of olefins and alcohols in ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Lapidus, A.L.; Eliseev, O.L.; Bondarenko, T.N.; Stepin, N.N. [Russian Academy of Sciences, Moscow (Russian Federation). N.D. Zelinsky Institute of Organic Chemistry

    2006-07-01

    Palladium-catalysed hydroxycarbonylation of olefins and alcohols proceeds in ionic liquid media. Terminal and internal olefins, cyclohexene, styrene, methanol, ethanol, n-butanol, cyclohexanol, benzyl alcohol and 1-phenylethanol were tested as substrates for the reaction. A number of molten salts were applied as a reaction medium and tetrabutylammonium bromide (m.p. 103 C) seemed to be the best. Carbon monoxide pressure of 2 MPa and reaction temperature of 110 C are suitable conditions to furnish the reaction in 2 hours in the presence of palladium acetate as a precursor. Triphenylphosphine added as a ligand reduces reaction rate. The critical role of counter anion in molten salt was also recognised. Yield of acids decreased in the order: Br{sup -} > Cl{sup -} > BF{sub 4} {approx}PF{sub 6}{sup -}. A two-route reaction scheme is proposed to explain the regularities of styrene and 1-phenylethanol hydroxycarbonylation. The catalytic system can be used repeatedly by simple extraction of products with diethyl ether. Nine cycles were carried out without loss of activity. (orig.)

  3. Direct, enantioselective α-alkylation of aldehydes using simple olefins.

    Science.gov (United States)

    Capacci, Andrew G; Malinowski, Justin T; McAlpine, Neil J; Kuhne, Jerome; MacMillan, David W C

    2017-11-01

    Although the α-alkylation of ketones has already been established, the analogous reaction using aldehyde substrates has proven surprisingly elusive. Despite the structural similarities between the two classes of compounds, the sensitivity and unique reactivity of the aldehyde functionality has typically required activated substrates or specialized additives. Here, we show that the synergistic merger of three catalytic processes-photoredox, enamine and hydrogen-atom transfer (HAT) catalysis-enables an enantioselective α-aldehyde alkylation reaction that employs simple olefins as coupling partners. Chiral imidazolidinones or prolinols, in combination with a thiophenol, iridium photoredox catalyst and visible light, have been successfully used in a triple catalytic process that is temporally sequenced to deliver a new hydrogen and electron-borrowing mechanism. This multicatalytic process enables both intra- and intermolecular aldehyde α-methylene coupling with olefins to construct both cyclic and acyclic products, respectively. With respect to atom and step-economy ideals, this stereoselective process allows the production of high-value molecules from feedstock chemicals in one step while consuming only photons.

  4. Gas phase reactions of nitrogen oxides with olefins

    Energy Technology Data Exchange (ETDEWEB)

    Altshuller, A P; Cohen, I

    1961-01-01

    The nature of the condensation products formed in the gas phase reactions of nitrogen dioxide and nitric oxide with pentene-1, 2-methylbutene-2, and 2-methylbutadiene-1,3 was investigated. The reactants were combined at partial pressures in the range of 0.1 to 2.5 mm with the total pressure at one atmosphere. The products were determined by infrared and ultraviolet spectroscopy and colorimetry. The condensates included primary and secondary nitro compounds and alkyl nitrates. Strong hydroxyl and single bond carbon to oxygen stretching vibrations indicate the presence of either nitroalcohols or simple aliphatic alcohols formed through oxidation reactions. Carbonyl stretching frequencies observable in some of the reactions support the conclusion that a portion of the reactants disappear by oxidation rather than by nitration processes. The available results do not indicate the presence of appreciable amounts of tert.-nitro compounds, conjugated nitro-olefins, or gem-dinitro-alkanes. The reactivities of the olefins with the nitrogen oxides are in the decreasing order: 2-methyl-butadiene-1,3, 2-methylbutene-2, pentene-1. 20 references.

  5. How much life is left in your olefin unit

    International Nuclear Information System (INIS)

    Baas, J.; Warner, R.

    1992-01-01

    Highly attractive economics in the olefin industry has justified increasing capacity via plant expansion and using aging olefin units beyond expected limitations. If these existing units are to operate well beyond their design life, what type of analysis and information is necessary to make this decision? What technologies or methods should be used for continued safe and controlled operation of these not so new units. This paper reports that the plant's mechanical integrity is the focal point of this analysis and decision-making method. Plant life expectancy study (PLES) looks at an operating plant's mechanical integrity from several vantage points. Four basic principles, such as plant history, process upsets and operating records, assessment of plant fires, and how to conduct records, assessment of plant fires, and how to conduct inspection and testing, provide the basis of how well a plant has been operated and maintained. Furthermore, the analysis includes a critical component inventory. These items address additional potential-failure causes, such as creep, fatigue, toughness, corrosion, erosion and carburization/oxidation

  6. Exploring thermal anisotropy of cortical bone using temperature measurements in drilling.

    Science.gov (United States)

    Alam, Khurshid

    2016-05-12

    Bone drilling is widely used in orthopaedics for fracture treatment, reconstructive surgery and bone biopsy. Heat generation in bone drilling can cause rise in bone temperature resulting in prolonged healing time or loosening of fixation. The purpose of this study was to investigate thermal anisotropy of bone by measuring the level of temperature in bone drilling with and without cooling conditions in two anatomical directions. Drilling tests were performed on bovine cortical bone. A total of fifteen specimens were used to obtain data for statistical analysis. Temperature near the cutting zone was measured in two anatomical directions. i.e. along the longitudinal and circumferential direction. Temperature distribution was also found in the two prescribed directions. Analysis of variance (ANOVA) was used to identify significant drilling parameter affecting bone temperature. Drilling speed, feed rate and drill size were found influential parameters affecting bone temperature. Higher drilling speed, feed rate, and large drill size were found to cause elevated temperature in bone. Much lower temperature was measured in bone when cooling fluid was supplied to the drilling region. Experimental results revealed lower temperatures in the circumferential direction compared to the longitudinal direction. Thermal anisotropy for heat transport was found in the bone. This study recommends lower drilling speed and feed rate and cooling for controlling rise in bone temperature.

  7. New drilling optimization technologies make drilling more efficient

    Energy Technology Data Exchange (ETDEWEB)

    Chen, D.C.-K. [Halliburton Energy Services, Calgary, AB (Canada). Sperry Division

    2004-07-01

    Several new technologies have been adopted by the upstream petroleum industry in the past two decades in order to optimize drilling operations and improve drilling efficiency. Since financial returns from an oil and gas investment strongly depend on drilling costs, it is important to reduce non-productive time due to stuck pipes, lost circulation, hole cleaning and well bore stability problems. The most notable new technologies are the use of computer-based instrumentation and data acquisition systems, integrated rig site systems and networks, and Measurement-While-Drilling and Logging-While-Drilling (MWD/LWD) systems. Drilling optimization should include solutions for drillstring integrity, hydraulics management and wellbore integrity. New drilling optimization methods emphasize information management and real-time decision making. A recent study for drilling in shallow water in the Gulf of Mexico demonstrates that trouble time accounts for 25 per cent of rig time. This translates to about $1.5 MM U.S. per well. A reduction in trouble time could result in significant cost savings for the industry. This paper presents a case study on vibration prevention to demonstrate how the drilling industry has benefited from new technologies. 13 refs., 10 figs.

  8. Importance of drill string assembly swivel in horizontal drilling

    Directory of Open Access Journals (Sweden)

    Edmund Tasak

    2006-10-01

    Full Text Available A part of the drill string – the swivel (rotational connector – accomplishes an important task in the horizontal drilling. Its malfunctioning makes it impossible to draw in ( install large diameter and length pipelines. The causes of the connector break-down during the horizontal drilling are investigated in the paper. The drilling has been made for twenty inches gas pipeline installation during reaming operations. A trouble was encountered making good work conditions of a system consisting of the drilling machine drill string reamer swivel tube shield of Cardan joint and the gas pipeline 500 m long. In this case, the swivel brokes down and the planned operation was not finished. The assessment of improper drilling conditions, selection of operation system components, and drilling parameters and the insufficient technological supervising have created an excessive risk of failure. A proper application of technical analysis would considerably decrease the hazard of failure which cause large costs, delays and decrease of confidence to the drilling contractor and pipeline installation.

  9. Techno-economic analysis and comparison of coal based olefins processes

    International Nuclear Information System (INIS)

    Xiang, Dong; Yang, Siyu; Qian, Yu

    2016-01-01

    Highlights: • The coal based Fischer–Tropsch-to-olefins (CFTO) process is proposed and analyzed. • The CFTO suffers from lower energy efficiency and serious CO 2 emissions. • Approaches for improving techno-economic performance of the CFTO are obtained. - Abstract: Traditional olefins production is heavily dependent on oil. In the background of the scarcity of oil and richness of coal in China, olefins production from coal has been attracting more attention of the chemical process industry. The first coal based methanol-to-olefins (CMTO) plant has been commercialized in China. For shorter process route and lower capital cost, Fischer–Fropsch has been put forward in the last few years. The coal based Fischer–Tropsch-to-olefins (CFTO) process is designed in this paper and then its techno-economic and environmental performance was detailed studied in this paper, in comparison with the CMTO. Results show that at the present olefins selectivity, the CFTO suffers from relative lower energy efficiency and higher CO 2 emissions. In economic aspect, the capital investment and product cost of the CFTO are roughly equivalent to that of the CMTO. Although the conversion route of the CFTO is shorter, its techno-economic performance is still inferior to that of the CMTO. It is also found that increase of olefins selectivity by cracking oil or decrease of CO 2 selectivity by improving catalyst could significantly improve the performance of the CFTO.

  10. An evaluation of flowmeters for the detection of kicks and lost circulation during drilling

    Energy Technology Data Exchange (ETDEWEB)

    Schafer, D.M.; Loeppke, G.E.; Glowka, D.A.; Scott, D.D. (Sandia National Labs., Albuquerque, NM (United States)); Wright, K.E. (Ktech Corp., Albuquerque, NM (United States))

    1991-01-01

    An independent evaluation of current industry standard and state-of-the-art drilling fluid inflow and outflow meters was conducted during the drilling of a geothermal exploratory well. Four different types of fluid inflow meters and three different types of fluid outflow meters were tested and evaluated during actual drilling operations. The tested drilling fluid inflow meters included conventional pump stroke counters, rotary pump speed counters, magnetic flow meters, and a Doppler ultrasonic flow meter. On the return flow line, a standard paddle meter, an acoustic level meter, and a prototype rolling float meter were evaluated to measure drilling fluid outflow rates. The prototype outflow meter utilizes a rolling float which rides on the surface of the flow thereby measuring the fluid height in the pipe. Both the prototype meter and the conventional paddle meter were also extensively tested under a variety of drilling conditions in a full-scale laboratory test facility. The meters were evaluated and compared on the basis of reliability and accuracy, and the results are presented in the paper.

  11. Salton Sea Scientific Drilling Project: A summary of drilling and engineering activities and scientific results

    Energy Technology Data Exchange (ETDEWEB)

    Ross, H.P.; Forsgren, C.K. (eds.)

    1992-04-01

    The Salton Sea Scientific g Project (SSSDP) completed the first major well in the United States Continental Scientific Drilling Program. The well (State 2-14) was drilled to 10,W ft (3,220 m) in the Salton Sea Geothermal Field in California's Imperial Valley, to permit scientific study of a deep, high-temperature portion of an active geothermal system. The program was designed to investigate, through drilling and testing, the subsurface thermal, chemical, and mineralogical environments of this geothermal area. Extensive samples and data, including cores, cuttings, geothermal fluids and gases, and geophysical logs, were collected for future scientific analysis, interpretation, and publication. Short duration flow tests were conducted on reservoirs at a depth of approximately 6,120 ft (1,865 m) and at 10,136 ft (3,089 m). This report summarizes all major activities of the SSSDP, from project inception in the fall of 1984 through brine-pond cleanup and site restoration, ending in February 1989. This report presents a balanced summary of drilling, coring, logging, and flow-test operations, and a brief summary of technical and scientific results. Frequent reference is made to original records, data, and publication of results. The report also reviews the proposed versus the final well design, and operational summaries, such as the bit record, the casing and cementing program, and the coring program. Summaries are and the results of three flow tests. Several teamed during the project.

  12. Drill string gas data

    Energy Technology Data Exchange (ETDEWEB)

    Siciliano, E.R.

    1998-05-12

    Data and supporting documentation were compiled and analyzed for 26 cases of gas grab samples taken during waste-tank core sampling activities between September 1, 1995 and December 31, 1997. These cases were tested against specific criteria to reduce uncertainties associated with in-tank sampling location and conditions. Of the 26 possible cases, 16 qualified as drill-string grab samples most likely to represent recently released waste gases. The data from these 16 ``confirmed`` cases were adjusted to remove non-waste gas contributions from core-sampling activities (argon or nitrogen purge), the atmospheric background, and laboratory sampler preparation (helium). The procedure for subtracting atmospheric, laboratory, and argon purge gases was unambiguous. No reliable method for determining the exact amount of nitrogen purge gas was established. Thus, the final set of ``Adjusted`` drill string gas data for the 6 nitrogen-purged cases had a greater degree of uncertainty than the final results for the 10 argon-purged cases. Including the appropriate amounts of uncertainty, this final set of data was added to the set of high-quality results from the Retained Gas Sampler (RGS), and good agreement was found for the N{sub 2}, H{sub 2}, and N{sub 2}O mole fractions sampled from common tanks. These results indicate that under favorable sampling conditions, Drill-String (DS) grab samples can provide reasonably accurate information about the dominant species of released gas. One conclusion from this set of total gas data is that the distribution of the H{sub 2} mole fractions is bimodal in shape, with an upper bound of 78%.

  13. Drilling string lifter

    Energy Technology Data Exchange (ETDEWEB)

    Shakhobalov, A B; Galiopa, A A; Ponomarev, G V; Ushakov, A M

    1981-04-28

    A drilling string lifter is suggested which includes a rotating tower installed on a fixed base, hydraulic cylinder and pipe-clamping assembly connected through a chain gear to the drive motor. In order to simplify the design of the hydraulic lifter, the drive motor is installed on a fixed base so that the axis of the outlet shaft of the drive motor coincides with the axis of rotation of the tower. In addition, the axis of rotation of the tower is made in the form of a tubular element, and the outlet shaft of the drive motor is ranged between the tubular element.

  14. In vivo and in vitro olefin cyclopropanation catalyzed by heme enzymes

    Science.gov (United States)

    Coelho, Pedro S; Brustad, Eric M; Arnold, Frances H; Wang, Zhan; Lewis, Jared C

    2015-03-31

    The present invention provides methods for catalyzing the conversion of an olefin to any compound containing one or more cyclopropane functional groups using heme enzymes. In certain aspects, the present invention provides a method for producing a cyclopropanation product comprising providing an olefinic substrate, a diazo reagent, and a heme enzyme; and admixing the components in a reaction for a time sufficient to produce a cyclopropanation product. In other aspects, the present invention provides heme enzymes including variants and fragments thereof that are capable of carrying out in vivo and in vitro olefin cyclopropanation reactions. Expression vectors and host cells expressing the heme enzymes are also provided by the present invention.

  15. Atmosphere-Controlled Chemoselectivity: Rhodium-Catalyzed Alkylation and Olefination of Alkylnitriles with Alcohols.

    Science.gov (United States)

    Li, Junjun; Liu, Yuxuan; Tang, Weijun; Xue, Dong; Li, Chaoqun; Xiao, Jianliang; Wang, Chao

    2017-10-17

    The chemoselective alkylation and olefination of alkylnitriles with alcohols have been developed by simply controlling the reaction atmosphere. A binuclear rhodium complex catalyzes the alkylation reaction under argon through a hydrogen-borrowing pathway and the olefination reaction under oxygen through aerobic dehydrogenation. Broad substrate scope is demonstrated, permitting the synthesis of some important organic building blocks. Mechanistic studies suggest that the alkylation product may be formed through conjugate reduction of an alkene intermediate by a rhodium hydride, whereas the formation of olefin product may be due to the oxidation of the rhodium hydride complex with molecular oxygen. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Ligand-Enabled γ-C(sp(3))-H Olefination of Amines: En Route to Pyrrolidines.

    Science.gov (United States)

    Jiang, Heng; He, Jian; Liu, Tao; Yu, Jin-Quan

    2016-02-17

    Pd(II)-catalyzed olefination of γ-C(sp(3))-H bonds of triflyl (Tf) and 4-nitrobenzenesulfonyl (Ns) protected amines is achieved. Subsequent aza-Wacker oxidative cyclization or conjugate addition of the olefinated intermediates provides a variety of C-2 alkylated pyrrolidines. Three pyridine- and quinoline-based ligands are developed to match different classes of amine substrates, demonstrating a rare example of ligand-enabled C(sp(3))-H olefination reactions. The use of Ns protecting group to direct C(sp(3))-H activation of alkyl amines is also a significant step toward practical C-H functionalizations of alkyl amines.

  17. Stereoselective synthesis of hydroxy stilbenoids and styrenes by atom-efficient olefination with thiophthalides.

    Science.gov (United States)

    Mitra, Prithiba; Shome, Brateen; De, Saroj Ranjan; Sarkar, Anindya; Mal, Dipakranjan

    2012-04-14

    The synthesis of stilbenoids and styryl carboxylic acids is accomplished with high E-stereoselectivity by olefination of aldehydes with thiophthalides under basic conditions. The olefination is highly atom-efficient as it only loses elemental sulfur during the reaction. This olefination, in conjunction with retro Kolbe-Schmitt reaction, allows facile synthesis of E-hydroxystilbenoids with minimal employment of protecting groups. This study also discloses two important findings: formation of i) 4-methylsulfanyl isocoumarins and ii) an 2-arylindenone. This journal is © The Royal Society of Chemistry 2012

  18. Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis

    KAUST Repository

    Dong, G.

    2011-09-15

    Alcohol synthesis is critical to the chemical and pharmaceutical industries. The addition of water across olefins to form primary alcohols (anti-Markovnikov olefin hydration) would be a broadly useful reaction but has largely proven elusive; an indirect hydroboration/oxidation sequence requiring stoichiometric borane and oxidant is currently the most practical methodology. Here, we report a more direct approach with the use of a triple relay catalysis system that couples palladium-catalyzed oxidation, acid-catalyzed hydrolysis, and ruthenium-catalyzed reduction cycles. Aryl-substituted terminal olefins are converted to primary alcohols by net reaction with water in good yield and excellent regioselectivity.

  19. Quality, health and environment system integrated application in the processes of drilling, completion and work over fluids and waste management in the exploration and production activities; Aplicacao do sistema de gestao integrada de qualidade, saude, meio ambiente e seguranca nos processos de fluidos de perfuracao, completacao, workover e gerenciamento de residuos nas atividades de E e P

    Energy Technology Data Exchange (ETDEWEB)

    Franca Filho, Jose; Chio, Alessandra F.; Sa, Carlos M. de [M-I Swaco do Brasil - Comercio, Servicos e Mineracao Ltda., Mossoro, RN (Brazil). Quality, Health, Safety and Environmental

    2004-07-01

    This paper describes the strategy developed by M-I SWACO Brasil for identification of the need for implementation and management of a system that in an integrated way attended to the requirements of Quality, Health, Environment and Safety in the processes of drilling, completion and work over fluids and waste management in the E and P activities involving all steps, from planning to execution of the projects. The Integrated Management System was based on requirements of the international standards ISO 9001:2000, ISO 14001:1996 and OHSAS 18001:1999 and on internal corporate requirements as the HSE Management System. The conception of IMS is associated to a preventive posture, with the identification, evaluation and control of environmental and occupational risks, as well as the compliance to the products quality requirements and services related to the processes of fluids and waste management, with a systemic vision in that all those segments were managed in a integrated way. The system propitiated a better management of the processes and of the aspects of Quality, Health, Environment and Safety, increasing the awareness and the proactive attitude with the commitment of all levels of the company, adding value in the services and products, being a differentiation factor for customers, suppliers and community. (author)

  20. Étude des interactions mécaniques et physico-chimiques entre les argiles et les fluides de forage. Application à l'argile de Boom (Belgique A Study O the Mechanical and Physicochemical Interactions Between the Clay Materials and the Drilling Fluids. Application to the Boom Clay (Belgium

    Directory of Open Access Journals (Sweden)

    Tshibangu J. P.

    2006-11-01

    pour sa disponibilité et, d'autre part, pour la grande quantité d'informations disponibles sur ce matériau. General ConsiderationsThis work deals with problems encountered regarding the stability of wells drilled in the clay material formations with water based muds. In fact, clays or shales have a property of taking water, thus causing the instability of wells either because of the swelling of some mineral species, or because the supporting pressure is suppressed by modification of the pore pressure. The aim here is to experimentally emphasize the principal mechanisms driving the phenomenon of instability, and to try to quantify the importance of these mechanisms in order to include them in calculation models. The behaviour of a shale put in contact of a water based fluid depends on its initial water activity and on the composition of the fluid. According to the situation, the shale will take or expel water, with a consequence of swelling or shrinkage. Three factors play an important role in the water activity of shales :- The electrostatic interaction which is related to the cation exchange. This mechanism consists in a cation passing from the solution to the surface of a layer and an interlayer cation of the clay doing the opposite path. Clay materials are characterized by the Cation Exchange Capacity or CEC;- The salt concentration which is related to the osmotic phenomenon. If a shale, and especially a montmorillonite, is put in contact with a pure solvent, in addition of the ion hydration, the solvent will be taken by the shale in order to dilute the high ionic concentration of that shale. This last mechanism is macroscopically expressed by a difference of osmotic pressure between the external solvent and the pore fluid of the shale. If we consider the case in which the solvent is pure water the osmotic pressure is expressed by equation (2 in which awi is the water activity of the shale and vw the partial molar volume of water (we suppose here that this vw has

  1. Olefin polymerization from single site catalysts confined within porous media

    Science.gov (United States)

    Kasi, Rajeswari M.

    Single Site Catalysts (SSCs) have been utilized for olefin polymerization. Altering the metal-ligand architecture in the SSCs, polyolefin properties can be enhanced in a rational manner. This influence of the ligands in the SSC on the property of polyolefins prepared can be referred to as the primary ligand influence. Extending this understanding and subsequent control of the metal-ligand framework to the interaction of SSCs within organic and inorganic supports is vital for the synthesis of polyolefins with tailored properties. The motivation behind this thesis was to explore the support influence on the reactivity of the SSC tethered to a support matrix during ethylene homo and copolymerization. In order to address this question of the support influence on the final polyolefin properties, synthetic routes to covalently bind SSCs on different matrices have been explored. Two distinct supported SSCs have been used to prepare branched polyethylenes. Branched polyethylenes can be prepared by either copolymerization (ethylene and alpha-olefin) or oligomerization/copolymerization processes (ethylene and in situ generated alpha-olefin). Synthetic routes to prepare precursor catalysts to Constrained Geometry Catalysts (CGCs) by silyl elimination chemistry have been developed (Chapter 2). Efficient synthetic protocols to assemble CGCs on aminomethylpolysytrene matrices (Chapter 3) and amine-functionalized mesoporous silica (Chapter 4) are also reported. These supported catalysts, with appropriate cocatalysts have been used to prepare ethylene homo and copolymers, the polymer thermal properties and microstructures were analyzed by various analytical techniques. Branched polyethylenes (LLDPE) can be prepared by copolymerization chemistry. It has been observed is that the influence of the support is seen in the production of lower crystalline forms of high density polyethylene (HDPE, 20--50% crystalline), while homogeneous polymerization of analogous soluble CGCs afford HDPE

  2. 30 CFR 57.7052 - Drilling positions.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Drilling positions. 57.7052 Section 57.7052... SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Drilling and Rotary Jet Piercing Drilling-Surface and Underground § 57.7052 Drilling positions. Persons shall not drill...

  3. 30 CFR 56.7052 - Drilling positions.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Drilling positions. 56.7052 Section 56.7052... SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Drilling and Rotary Jet Piercing Drilling § 56.7052 Drilling positions. Persons shall not drill from— (a) Positions which hinder...

  4. Control procedure for well drilling operations

    Energy Technology Data Exchange (ETDEWEB)

    Bourdon, J C

    1988-09-09

    A control procedure of rotary drilling operations is proposed. It uses the Drill off test. The drill-off test permits to determine the rock drill speed variation as a function of the wright applied on the top of the pipe. We can deduce from that a rock drill wear parameter. The method permits to prevent a rupture and its grave economic consequences.

  5. 30 CFR 33.34 - Drilling test.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Drilling test. 33.34 Section 33.34 Mineral... MINING PRODUCTS DUST COLLECTORS FOR USE IN CONNECTION WITH ROCK DRILLING IN COAL MINES Test Requirements § 33.34 Drilling test. (a) A drilling test shall consist of drilling a set of 10 test holes, without...

  6. DEVELOPMENT AND TESTING OF UNDERBALANCED DRILLING PRODUCTS. Final Report, Oct 1995 - July 2001

    Energy Technology Data Exchange (ETDEWEB)

    William C. Maurer; William J. McDonald; Thomas E. Williams; John H. Cohen

    2001-07-01

    Underbalanced drilling is experiencing growth at a rate that rivals that of horizontal drilling in the mid-1980s and coiled-tubing drilling in the 1990s. Problems remain, however, for applying underbalanced drilling in a wider range of geological settings and drilling environments. This report addresses developments under this DOE project to develop products aimed at overcoming these problems. During Phase I of the DOE project, market analyses showed that up to 12,000 wells per year (i.e., 30% of all wells) will be drilled underbalanced in the U.S.A. within the next ten years. A user-friendly foam fluid hydraulics model (FOAM) was developed for a PC Windows environment during Phase I. FOAM predicts circulating pressures and flow characteristics of foam fluids used in underbalanced drilling operations. FOAM is based on the best available mathematical models, and was validated through comparison to existing models, laboratory test data and field data. This model does not handle two-phase flow or air and mist drilling where the foam quality is above 0.97. This FOAM model was greatly expanded during Phase II including adding an improved foam rheological model and a ''matching'' feature that allows the model to be field calibrated. During Phase I, a lightweight drilling fluid was developed that uses hollow glass spheres (HGS) to reduce the density of the mud to less than that of water. HGS fluids have several advantages over aerated fluids, including they are incompressible, they reduce corrosion and vibration problems, they allow the use of mud-pulse MWD tools, and they eliminate high compressor and nitrogen costs. Phase II tests showed that HGS significantly reduce formation damage with water-based drilling and completion fluids and thereby potentially can increase oil and gas production in wells drilled with water-based fluids. Extensive rheological testing was conducted with HGS drilling and completion fluids during Phase II. These tests showed

  7. Activity plan: Directional drilling and environmental measurements while drilling

    International Nuclear Information System (INIS)

    Myers, D.A.

    1998-01-01

    This activity plan describes the testing of directional drilling combined with environmental measurements while drilling at two Hanford Site locations. A cold test is to be conducted at the 105A Mock Tank Leak Facility in the 200 East Area. A hot test is proposed to be run at the 216-B-8 tile field north of the 241-B Tank Farm in 200 East Area. Criteria to judge the success, partial success or failure of various aspects of the test are included. The TWRS program is assessing the potential for use of directional drilling because of an identified need to interrogate the vadose zone beneath the single-shell tanks. Because every precaution must be taken to assure that investigation activities do not violate the integrity of the tanks, control of the drill bit and ability to follow a predetermined drill path are of utmost importance and are being tested

  8. Design and Exploitation Problems of Drill String in Directional Drilling

    Directory of Open Access Journals (Sweden)

    Bednarz Stanislaw

    2004-09-01

    Full Text Available Drill string design for directional drilling requires accounting for a number of factors. First, types and expected values of loads should be determined. Then, elements of the drill string should be so selected as to enable realization of the plan at specified loads. Some of additional factors, e. g. purchase, exploitation cost, geological conditions in the bore-hole, washing of the bore-hole, stability, trajectory, rig parameters, accuracy of gauges, pumps parameters remain in conflict. Drill pipes are made of rolled pipes, upset and welded with tool joints to 9,5 m long; the shorter ones can be made of hot forged rods. Exploitation requirements, being a result of practical experience supported by theoretical and laboratory analyses should be a part of syllabuses of technical staff educational programs. Apart from designing the string, it is also vital to lower the risk of a drilling failure. The significance of these aspects seems to be unquestionable.

  9. A new drilling method-Earthworm-like vibration drilling.

    Science.gov (United States)

    Wang, Peng; Ni, Hongjian; Wang, Ruihe

    2018-01-01

    The load transfer difficulty caused by borehole wall friction severely limits the penetration rate and extended-reach limit of complex structural wells. A new friction reduction technology termed "earthworm-like drilling" is proposed in this paper to improve the load transfer of complex structural wells. A mathematical model based on a "soft-string" model is developed and solved. The results show that earthworm-like drilling is more effective than single-point vibration drilling. The amplitude and frequency of the pulse pressure and the installation position of the shakers have a substantial impact on friction reduction and load transfer. An optimization model based on the projection gradient method is developed and used to optimize the position of three shakers in a horizontal well. The results verify the feasibility and advantages of earthworm-like drilling, and establish a solid theoretical foundation for its application in oil field drilling.

  10. Case drilling - an innovative approach to reducing drilling costs

    Energy Technology Data Exchange (ETDEWEB)

    Madell, G.; Tessari, R. M. [Tesco Corp., Calgary, AB (Canada); Warren, T. [Tesco Drilling Technology, Calgary, AB (Canada)

    1999-11-01

    Casing drilling is introduced as a new drilling technique that uses standard oil field casing to simultaneously drill and case the well. The technology includes both rig and downhole equipment, customized to function effectively as an integrated drilling system. This paper describes the testing program designed to identify and overcome technical challenges. Although not fully optimized, it appears that the system is functional. Test results indicate the need for improvements in the pump down cement float equipment and the tools and procedures for drilling up the cement plugs. The pump down latch and retrieval system also needs to be further developed and tested for high angle directional applications. Cost savings in the range of 10 to 15 per cent are expected for trouble-free wells. By eliminating the cost of unscheduled events encountered in troublesome wells, cost savings may reach as high as 30 per cent. 3 refs., 7 figs.

  11. Activity plan: Directional drilling and environmental measurements while drilling

    Energy Technology Data Exchange (ETDEWEB)

    Myers, D.A.

    1998-07-16

    This activity plan describes the testing of directional drilling combined with environmental measurements while drilling at two Hanford Site locations. A cold test is to be conducted at the 105A Mock Tank Leak Facility in the 200 East Area. A hot test is proposed to be run at the 216-B-8 tile field north of the 241-B Tank Farm in 200 East Area. Criteria to judge the success, partial success or failure of various aspects of the test are included. The TWRS program is assessing the potential for use of directional drilling because of an identified need to interrogate the vadose zone beneath the single-shell tanks. Because every precaution must be taken to assure that investigation activities do not violate the integrity of the tanks, control of the drill bit and ability to follow a predetermined drill path are of utmost importance and are being tested.

  12. Production of jet fuel range paraffins by low temperature polymerization of gaseous light olefins using ionic liquid

    International Nuclear Information System (INIS)

    Jiang, Peiwen; Wu, Xiaoping; Zhu, Lijuan; Jin, Feng; Liu, Junxu; Xia, Tongyan; Wang, Tiejun; Li, Quanxin

    2016-01-01

    Graphical abstract: A novel catalytic transformation of light olefins into jet fuel range iso-paraffins by the low-temperature olefin polymerizations under atmospheric conditions. - Highlights: • A novel transformation of light olefins to jet fuel range paraffins was demonstrated. • The synthetic fuels can be produced by atmospheric olefin polymerizations. • C 8 –C 15 iso-paraffins from light olefins was achieved with a selectivity of 80.6%. - Abstract: This work demonstrated a novel catalytic transformation of gaseous olefins into jet fuel range iso-paraffins by the low-temperature olefin polymerizations under atmospheric conditions. The production of the desired C 8 –C 15 iso-paraffins with the selectivity of 80.6 C mol% was achieved by the room-temperature polymerizations of gaseous light olefins using the [BMIM] Al 2 Cl 7 ionic liquid. The influences of the reaction conditions on the olefinic polymerizations were investigated in detail. The properties of hydrocarbons in the synthetic fuels were determined by the GC–MS analyses combined with 1 H NMR, and 13 C NMR analyses. The formation of C 8 –C 15 hydrocarbons from gaseous light olefins was illustrated by the identified products and the functional groups. This transformation potentially provides a useful avenue for the production of the most important components of iso-paraffins required in jet fuels.

  13. Advanced Mud System for Microhole Coiled Tubing Drilling

    Energy Technology Data Exchange (ETDEWEB)

    Kenneth Oglesby

    2008-12-01

    An advanced mud system was designed and key components were built that augment a coiled tubing drilling (CTD) rig that is designed specifically to drill microholes (less than 4-inch diameter) with advanced drilling techniques. The mud system was tailored to the hydraulics of the hole geometries and rig characteristics required for microholes and is capable of mixing and circulating mud and removing solids while being self contained and having zero discharge capability. Key components of this system are two modified triplex mud pumps (High Pressure Slurry Pumps) for advanced Abrasive Slurry Jetting (ASJ) and a modified Gas-Liquid-Solid (GLS) Separator for well control, flow return and initial processing. The system developed also includes an additional component of an advanced version of ASJ which allows cutting through most all materials encountered in oil and gas wells including steel, cement, and all rock types. It includes new fluids and new ASJ nozzles. The jetting mechanism does not require rotation of the bottom hole assembly or drill string, which is essential for use with Coiled Tubing (CT). It also has low reactive forces acting on the CT and generates cuttings small enough to be easily cleaned from the well bore, which is important in horizontal drilling. These cutting and mud processing components and capabilities compliment the concepts put forth by DOE for microhole coiled tubing drilling (MHTCTD) and should help insure the reality of drilling small diameter holes quickly and inexpensively with a minimal environmental footprint and that is efficient, compact and portable. Other components (site liners, sump and transfer pumps, stacked shakers, filter membranes, etc.. ) of the overall mud system were identified as readily available in industry and will not be purchased until we are ready to drill a specific well.

  14. Registration and processing of acoustic signal in rock drilling

    Directory of Open Access Journals (Sweden)

    Futó Jozef

    2002-03-01

    Full Text Available For the determination of an effective rock disintegration for a given tool and rock type it is needed to define an optimal disintegration regime. Optimisation of the disintegration process by drilling denotes the finding out an appropriate couple of input parameters of disintegration, i.e. the thrust and revolutions for a quasi-equal rock environment. The disintegration process can be optimised to reach the maximum immediate drilling rate, to reach the minimum specific disintegration energy or to reach the maximum ratio of immediate drilling rate and specific disintegration energy. For the determination of the optimal thrust and revolutions it is needed to monitor the disintegration process. Monitoring of the disintegration process in real conditions is complicated by unfavourable factors, such as the presence of water, dust, vibrations etc. Following our present experience in the monitoring of drilling or full-profile driving, we try to replace the monitoring of input values by monitoring of the scanned acoustic signal. This method of monitoring can extend the optimisation of disintegration process in the technical practice. Its advantage consists in the registration of one acoustic signal by an appropriate microphone. Monitoring of acoustic signal is used also in monitoring of metal machining by milling and turning jobs. The research results of scanning of the acoustic signal in machining of metals are encouraging. Acoustic signal can be processed by different statistical parameters. The paper decribes some results of monitoring of the acoustic signal in rock disintegration on the drilling stand of the Institute of Geotechnics SAS in Košice. The acoustic signal has been registered and processed in no-load run of electric motor, in no-load run of electric motor with a drilling fluid, and in the Ruskov andesite drilling. Registration and processing of the acoustic signal is solved as a part of the research grant task within the basic research

  15. Radiation-chemical alkylation of olefines with adamantane

    International Nuclear Information System (INIS)

    Podkhalyuzin, A.T.; Vikulin, V.V.; Morozov, V.A.; Nazarova, M.P.; Vereshchinskii, I.V.

    1977-01-01

    Radiation-chemical alkylation of C 2 to C 4 olefines with adamantane was studied in gas phase at temperatures 270 to 430 0 C. The main reaction product is monoalkyladamantane. The reaction proceeds by a free radical chain mechanism. The effective activation energy is of the order of 8 to 10 kcal/mole. Thermal alkylation was carried out for comparison and the contribution of the thermal component to the radiation-thermal process was estimated. Liquid phase alkylation of hexafluoropropylene with adamantane was studied in the presence of solvents. Under various conditions mono- and di-substituted adamantanes are produced containing fluorine in end groups. These compounds were converted to corresponding fluoroalkenyladamantanes by dehydrofluorination. The kinetic parameters were calculated and physical-chemical data concerning some of the resulting products were determined. (author)

  16. New unit for sulfuric acid alkylation of isobutane by olefins

    Energy Technology Data Exchange (ETDEWEB)

    Khadzhiev, S.N.; Baiburskii, V.L.; Deineko, P.S.; Gruzdev, A.S.; Tagavov, I.T.

    1987-01-01

    The authors describe and illustrate a sulfuric acid alkylation unit with a horizontal contact. As a result of the use of this design solution, the isobutane/olefin ratio is 10/1 in comparison with 4/1 to 5/1 in the other types of units, namely vertical reactors and cascade tank reactors. The unit was designed to process the butane-butylene cut (BBC) and part of the propane-propylene cut (PPC) from the G-43-107 cat cracker. The unit design includes provisions for controlled caustic washing of the feed and dehydration in an electric field. The authors present the basic data obtained in the three months of unit operation after startup, in comparison with the operating indexes of a sulfuric acid alkylation unit.

  17. Control procedure for fluid kicks in hydrocarbons wells

    Energy Technology Data Exchange (ETDEWEB)

    Gavignet, A

    1989-02-10

    This invention is a control procedure of the fluids inflows coming from an underground formation during a drill. These inflows happen when a drill reaches a permeable area containing a high pressure fluid. The latter will engulf into the well which may cause a catastrophic eruption, if nothing is done. Therefore is it necessary to know as soon as possible the physical nature of the fluids inflows. The proposed method consists in calculating the fluids characteristic through the measure of the pressures and debits of injection and return of the drilling mud.

  18. Delta flow: An accurate, reliable system for detecting kicks and loss of circulation during drilling

    Energy Technology Data Exchange (ETDEWEB)

    Speers, J.M.; Gehrig, G.F.

    1987-12-01

    A system to monitor drilling-fluid flow rate has been developed that detects kicks and lost returns in floating, fixed-platform, and land-base drilling operations. The system uses flowmeters that monitor the flow rates of drilling fluids entering the borehole through the standpipe and leaving the well through the return flowline. These readings are processed in a computer-based, data-acquisition system to form a filtered delta-flow signal that identified the occurrence of downhole fluid gains or losses. The system is designed to trip an alarm when a gain or loss exceeds 25 gal/min (1.6 dm/sup 3//s), even in a floating drilling environment. This sensitivity will generally keep gains or losses to less than 5 bbl (0.8 m/sup 3/).

  19. Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds

    KAUST Repository

    Rouen, Mathieu; Queval, Pierre; Borre, Etienne; Falivene, Laura; Poater, Albert; Berthod, Mikael; Hugues, Francois; Cavallo, Luigi; Basle, Olivier; Olivier-Bourbigou, Helene; Mauduit, Marc

    2016-01-01

    The search for a low-cost process for the valorization of linear alpha-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear alpha-olefins to longer internal linear olefins with high selectivity (>99%) under neat conditions at low loadings (50 ppm) and without the need of expensive additives. This robust catalytic process allowed us to efficiently and selectively re-equilibrate the naphtha fraction (C-5-C-8) of a Fischer-Tropsch feed derived from non petroleum resources to a higher-value product range (C-9-C-14), useful as detergent and plasticizer precursors.

  20. Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins with N-Sulfonyl 1,2,3-Triazoles

    Science.gov (United States)

    Chuprakov, Stepan; Kwok, Sen Wai; Zhang, Li; Lercher, Lukas; Fokin, Valery V.

    2009-01-01

    N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield. PMID:19928917

  1. Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds

    KAUST Repository

    Rouen, Mathieu

    2016-10-14

    The search for a low-cost process for the valorization of linear alpha-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear alpha-olefins to longer internal linear olefins with high selectivity (>99%) under neat conditions at low loadings (50 ppm) and without the need of expensive additives. This robust catalytic process allowed us to efficiently and selectively re-equilibrate the naphtha fraction (C-5-C-8) of a Fischer-Tropsch feed derived from non petroleum resources to a higher-value product range (C-9-C-14), useful as detergent and plasticizer precursors.

  2. Esterase-sensitive sulfur dioxide prodrugs inspired by modified Julia olefination.

    Science.gov (United States)

    Wang, Wenyi; Wang, Binghe

    2017-09-12

    Sulfur dioxide (SO 2 ) is an endogenously produced gaseous molecule, and is emerging as a potential gasotransmitter. Herein, we describe the first series of esterase-sensitive prodrugs inspired by modified Julia olefination as SO 2 donors.

  3. Palladium-catalyzed aryl C-H olefination with unactivated, aliphatic alkenes.

    Science.gov (United States)

    Deb, Arghya; Bag, Sukdev; Kancherla, Rajesh; Maiti, Debabrata

    2014-10-01

    Palladium-catalyzed coupling between aryl halides and alkenes (Mizoroki-Heck reaction) is one of the most popular reactions for synthesizing complex organic molecules. The limited availability, problematic synthesis, and higher cost of aryl halide precursors (or their equivalents) have encouraged exploration of direct olefination of aryl carbon-hydrogen (C-H) bonds (Fujiwara-Moritani reaction). Despite significant progress, the restricted substrate scope, in particular noncompliance of unactivated aliphatic olefins, has discouraged the use of this greener alternative. Overcoming this serious limitation, we report here a palladium-catalyzed chelation-assisted ortho C-H bond olefination of phenylacetic acid derivatives with unactivated, aliphatic alkenes in good to excellent yields with high regio- and stereoselectivities. The versatility of this operationally simple method has been demonstrated through drug diversification and sequential C-H olefination for synthesizing divinylbenzene derivatives.

  4. Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins

    Science.gov (United States)

    Hu, Jiefeng; Wang, Minyan; Pu, Xinghui; Shi, Zhuangzhi

    2017-05-01

    Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products, pharmaceuticals and manmade materials. Converting the normally highly stable aliphatic amides into olefins directly is a challenging task. Here we show that a Ni/NHC-catalytic system has been established for decarbonylative elimination of aliphatic amides to generate various olefins via C-N and C-C bond cleavage. This study not only overcomes the acyl C-N bond activation in aliphatic amides, but also encompasses distinct chemical advances on a new type of elimination reaction called retro-hydroamidocarbonylation. This transformation shows good functional group compatibility and can serve as a powerful synthetic tool for late-stage olefination of amide groups in complex compounds.

  5. Extreme ultraviolet (EUV) degradation of poly(olefin sulfone)s: Towards applications as EUV photoresists

    International Nuclear Information System (INIS)

    Lawrie, Kirsten; Blakey, Idriss; Blinco, James; Gronheid, Roel; Jack, Kevin; Pollentier, Ivan; Leeson, Michael J.; Younkin, Todd R.; Whittaker, Andrew K.

    2011-01-01

    Poly(olefin sulfone)s, formed by the reaction of sulfur dioxide (SO 2 ) and an olefin, are known to be highly susceptible to degradation by radiation and thus have been identified as candidate materials for chain scission-based extreme ultraviolet lithography (EUVL) resist materials. In order to investigate this further, the synthesis and characterisation of two poly(olefin sulfone)s namely poly(1-pentene sulfone) (PPS) and poly(2-methyl-1-pentene sulfone) (PMPS), was achieved and the two materials were evaluated for possible chain scission EUVL resist applications. It was found that both materials possess high sensitivities to EUV photons; however; the rates of outgassing were extremely high. The only observed degradation products were found to be SO 2 and the respective olefin suggesting that depolymerisation takes place under irradiation in a vacuum environment. In addition to depolymerisation, a concurrent conversion of SO 2 moieties to a sulfide phase was observed using XPS.

  6. Structure and dynamics of olefin radical cation aggregates. Time-resolved fluorescence detected magnetic resonance

    International Nuclear Information System (INIS)

    Desrosiers, M.F.; Trifunac, A.D.

    1986-01-01

    The time-resolved EPR spectra and thus the structure and dynamics of transient hydrocarbon radical cations are obtained by the pulse radiolysis-fluorescence detected magnetic resonance (FDMR) technique. Here the authors report the observation of short-lived radical cations from olefins. FDMR-EPR spectra of radical cations from tetramethylethylene and cyclohexadiene are illustrated. The olefin radical cations, FDMR spectra are concentration-dependent, since dimerization with neutral molecules takes place at higher (>10 -2 M) olefin concentration. Rate constants for the dimerization reaction are derived and the effect of solvent viscosity on aggregate formation is demonstrated. By monitoring the further reactions of dimer cations the authors have obtained EPR evidence for previously unobserved higher-order (multimer) radical cation aggregates of olefins. 16 references, 5 figures

  7. Capturing of the monoterpene olefin limonene produced in Saccharomyces cerevisiae.

    Science.gov (United States)

    Jongedijk, Esmer; Cankar, Katarina; Ranzijn, Jorn; van der Krol, Sander; Bouwmeester, Harro; Beekwilder, Jules

    2015-01-01

    Monoterpene olefins such as limonene are plant compounds with applications as flavouring and fragrance agents, as solvents and potentially also in polymer and fuel chemistry. We engineered baker's yeast Saccharomyces cerevisiae to express a (-)-limonene synthase from Perilla frutescens and a (+)-limonene synthase from Citrus limon. Both proteins were expressed either with their native plastid targeting signal or in a truncated form in which the plastidial sorting signal was removed. The yeast host strain for expression was AE9 K197G, which expresses a mutant Erg20 enzyme. This enzyme catalyses the formation of geranyl diphosphate, which is the precursor for monoterpenes. Several methods were tested to capture limonene produced by the yeast. Extraction from the culture medium by pentane, or by the addition of CaCl2 followed by solid-phase micro-extraction, did not lead to detectable limonene, indicating that limonene is rapidly lost from the culture medium. Volatile terpenes such as limonene may also be trapped in a dodecane phase added to the medium during fermentation. This method resulted in recovery of 0.028 mg/l (+)-limonene and 0.060 mg/l (-)-limonene in strains using the truncated Citrus and Perilla synthases, respectively. Trapping the headspace during culture of the limonene synthase-expressing strains resulted in higher titres, at 0.12 mg/l (+)-limonene and 0.49 mg/l (-)-limonene. These results show that the volatile properties of the olefins produced require specific methods for efficient recovery of these molecules from biotechnological production systems. Copyright © 2014 John Wiley & Sons, Ltd.

  8. Reinforcement and Drill by Microcomputer.

    Science.gov (United States)

    Balajthy, Ernest

    1984-01-01

    Points out why drill work has a role in the language arts classroom, explores the possibilities of using a microcomputer to give children drill work, and discusses the characteristics of a good software program, along with faults found in many software programs. (FL)

  9. High cost for drilling ships

    International Nuclear Information System (INIS)

    Hooghiemstra, J.

    2007-01-01

    Prices for the rent of a drilling ship are very high. Per day the rent is 1% of the price for building such a ship, and those prices have risen as well. Still, it is attractive for oil companies to rent a drilling ship [nl

  10. Drill pipe bridge plug

    International Nuclear Information System (INIS)

    Winslow, D.W.; Brisco, D.P.

    1991-01-01

    This patent describes a method of stopping flow of fluid up through a pipe bore of a pipe string in a well. It comprises: lowering a bridge plug apparatus on a work string into the pipe string to a position where the pipe bore is to be closed; communicating the pipe bore below a packer of the bridge plug apparatus through the bridge plug apparatus with a low pressure zone above the packer to permit the fluid to flow up through the bridge plug apparatus; engaging the bridge plug apparatus with an internal upset of the pipe string; while the fluid is flowing up through the bridge plug apparatus, pulling upward on the work string and the bridge plug apparatus and thereby sealing the packer against the pipe bore; isolating the pipe bore below the packer from the low pressure zone above the packer and thereby stopping flow of the fluid up through the pipe bore; disconnecting the work string from the bridge plug apparatus; and maintaining the bridge plug apparatus in engagement with the internal upset and sealed against the pipe bore due to an upward pressure differential applied to the bridge plug apparatus by the fluid contained therebelow

  11. Pd(II/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

    Directory of Open Access Journals (Sweden)

    Yasutaka Ishii

    2010-03-01

    Full Text Available The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc2/molybdovanadophosphoric acid (HPMoV as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.

  12. An Improved Protocol for the Aldehyde Olefination Reaction Using (bmim ( as Reaction Medium

    Directory of Open Access Journals (Sweden)

    Vivek Srivastava

    2013-01-01

    Full Text Available [Ru(CODCl2]/CuCl2·2H2O/LiCl catalytic system works efficiently in ionic liquid media for aldehyde olefination reaction. It offers good yield and selectivity with the added advantage of 5 times recyclability for [Ru(CODCl2] /CuCl2·2H2O/LiCl catalytic system. We also successfully reduced the reaction time from 12 hours to 9 hours for the aldehyde olefination reaction.

  13. Stereoselective Wittig Olefination as a Macrocyclization Tool. Synthesis of Large Carbazolophanes.

    Science.gov (United States)

    Myśliwiec, Damian; Lis, Tadeusz; Gregoliński, Janusz; Stępień, Marcin

    2015-06-19

    Z-Selective Wittig olefination was applied to the synthesis of large carbazolophanes containing up to eight heteroaromatic subunits. A number of strategies were devised and tested, showing that cyclooligomerization yields can be significantly improved by using one-component schemes involving heterobifunctional reactants. [4]- and [6]Carbazolophanes were characterized in the solid state, revealing compact, highly folded structures. Electronic and steric effects of substitution and chain length on the Wittig olefination rates and Z-selectivities were explored theoretically using DFT calculations.

  14. Ligand-Promoted C(sp(3) )-H Olefination en Route to Multi-functionalized Pyrazoles.

    Science.gov (United States)

    Yang, Weibo; Ye, Shengqing; Schmidt, Yvonne; Stamos, Dean; Yu, Jin-Quan

    2016-05-17

    A Pd-catalyzed/N-heterocycle-directed C(sp(3) )-H olefination has been developed. The monoprotected amino acid ligand (MPAA) is found to significantly promote Pd-catalyzed C(sp(3) )-H olefination for the first time. Cu(OAc)2 instead of Ag(+) salts are used as the terminal oxidant. This reaction provides a useful method for the synthesis of alkylated pyrazoles. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. On the nature of the olefination reaction involving ditungsten hexaalkoxides and aldehydes or ketones

    Energy Technology Data Exchange (ETDEWEB)

    Chisholm, M.H.; Huffman, J.C.; Lucas, E.A.; Sousa, A.; Streib, W.E. [Indiana Univ., Bloomington, IN (United States)

    1992-03-25

    Reductive coupling of aldehydes and ketones to olefins under the action of ditungsten hexaalkoxides was investigated. In these reactions, reductive cleavage of the aldehyde or ketone carbonyl is followed by formation of the olefinic C-C bond and breaking of the carbonyl C-O bond of the second aldehyde or ketone. Observations concerning the initial C-O bond cleavage and subsequent C-C bond formation are presented. 10 refs., 4 figs.

  16. Palladium catalyzed selective distal C-H olefination of biaryl systems.

    Science.gov (United States)

    Maity, Soham; Hoque, Ehtasimul; Dhawa, Uttam; Maiti, Debabrata

    2016-11-29

    Palladium catalyzed selective distal C-H activation with nitrile based templates has been of significant research interest in recent times. In this report, we disclose the distal C-H olefination of biphenyl systems with high regio- and stereo-selectivity and useful synthetic yields. The utility of this method has been demonstrated through its wide olefin scope, its operation at the gram scale and the easy removal/recovery of the directing group.

  17. Ultrasonic rotary-hammer drill

    Science.gov (United States)

    Bar-Cohen, Yoseph (Inventor); Badescu, Mircea (Inventor); Sherrit, Stewart (Inventor); Bao, Xiaoqi (Inventor); Kassab, Steve (Inventor)

    2010-01-01

    A mechanism for drilling or coring by a combination of sonic hammering and rotation. The drill includes a hammering section with a set of preload weights mounted atop a hammering actuator and an axial passage through the hammering section. In addition, a rotary section includes a motor coupled to a drive shaft that traverses the axial passage through the hammering section. A drill bit is coupled to the drive shaft for drilling by a combination of sonic hammering and rotation. The drill bit includes a fluted shaft leading to a distal crown cutter with teeth. The bit penetrates sampled media by repeated hammering action. In addition, the bit is rotated. As it rotates the fluted bit carries powdered cuttings helically upward along the side of the bit to the surface.

  18. Drilling waste makes concrete

    International Nuclear Information System (INIS)

    Rosfjord, A.

    1993-01-01

    The article deals with a method of drilling waste reclamation by utilizing the converted oil-containing cuttings from the North Sea in the concrete production in Norway. The oil content is to be removed in an incineration process by heating the cuttings to about 800 o C. The output capacity from the exhaust gas water cooling system is 7500 kW/hour, and is to be used in different industrial heating processes. The remaining content of pollutants in the cleaned exhaust gas outlet corresponds to the required limits with the exception of SO 2 and HCl. In addition, an exhaust gas washing plant is to be installed in the near future designed for the further reduction of pollutants by 90%. The converted raw materials are used as a supplement for lessening the demand of sand and cement in the production of concrete-made pipes. 1 fig

  19. Hospital preparation and drills

    International Nuclear Information System (INIS)

    Marshall, J.C.; Mettler, F.A. Jr.

    1990-01-01

    The authors discuss how effective management of radiation accidents requires a large amount of preparation and thought. In addition, training of the staff is absolutely essential. This is best accomplished through annual drills, but also may be accomplished through the use of videotapes. The critical points to be remembered in the handling of such accidents and in writing the procedures is that treatment of non-radiation-related injuries and medical stabilization are paramount. The second point is that it is important to be able to distinguish between a patient who has been irradiated from an external radiation source and one who is contaminated with radioactive materials. The handling of these two types of accidents is entirely different and this distinction needs to be made early. All of the items outlined in this chapter concern the care of the severely injured and radioactively contaminated

  20. Drillings at Veitsivaara in Hyrynsalmi

    International Nuclear Information System (INIS)

    Hinkkanen, H.; Oehberg, A.

    1990-04-01

    According to Governmen's decision in principle Teollisuuden Voima Oy is obliged to make bedrock investigations for the final disposal of the spent fuel produced by its power plant in Olkiluoto. Areas in Kuhmo, Hyrynsalmi, Sievi, Konginkangas and Olkiluoto were selected for the preliminary site investigations to be carried out during years 1987-1992. In Veitsivaara, Hyrynsalmi the investigation program was started in April 1987. During years 1987-1988 a deep borehole (1002 m) and 4 and 500 m deep additional boreholes were core drilled in the area. Various parameters were measured from the flushing water during the drilling. Corelogging included collecting detailed data of fractures and determining the weathering degree and petrographical properties. Rock mechanical properties, uniaxial compressive strength, Young's modulus and Poisso's ratio were measured from core samples. The flushing water needed in the drillings was pumped from 100 m deep borehole wells drilled with down-the-hole method in the vicinity of the borehole. The water was labeled with 2 tracers before use. About 75 m deep hole was percussion drilled near the borehole KR1. The spreading of the flushing water in the upper part of bedrock and the quality off the ground of the groundwater were studied by taking watersamples from the hole. 30 vertical holes were core drilled down to the depth of 10 m in bedrock with a light drilling unit. Drilling was carried out in order to determine the thickness of the overburden, to investigate the geophysical anomaly sources and to support geological mapping in areas covered with overburden. Groundwater hydraulics is one of the main subjects during the preliminary site investigation phase. For that reason 7 multilevel piezometers were installed on the site to monitore hydraulic head in 3 levels in the uppermost part of bedrock. The work consisted of borehole drillings to the depth of 100 m, geophysical borehole loggings and installation of piezometers. In addition

  1. Zeolitic imidazolate frameworks with optimized pore structure for olefin/paraffin-separation

    Energy Technology Data Exchange (ETDEWEB)

    Paula, C.; Boehme, U.; Hartmann, M. [Erlangen-Nuernberg Univ. (Germany). Erlangen Catalysis Resource Center

    2013-11-01

    In the chemical industry, the largest part of energy is spent on separation processes such as the separation of olefin/paraffin mixtures from steam cracker effluents by low-temperature rectification. A suitable alternative to this energy and cost intensive process is separation by selective adsorption with suitable microporous adsorbent. In this work, different ZIFs (Zeolitic Imidazolate Frameworks) have been explored with respect to their separation of olefins and paraffins. The studied materials (e.g. ZIF-8 (SOD-Topology), ZIF-71 (RHO-Topology)) were selected because of their low diameter of the largest pore entrance (0.29 to 4.2 nm) which is close to the kinetic diameter of the C{sub 2} to C{sub 4} olefins and paraffins under study. In contrast to other MOF- or zeolite-based adsorbents, in ZIF-8 and ZIF-71, the paraffin is preferentially adsorbed, which is evident from the single-component adsorption isotherms at different temperature. In the corresponding mixture breakthrough curves, the olefin breaks through first and the alkane even displaces the olefin from the pores. Thus, ZIF-8 and ZIF-71 are interesting candidates for the envisaged paraffin/olefin separation. Whether the observed separation behavior is due to the structural properties of the studied ZIFs or a consequence of peculiar chemical properties is subject to further studies. (orig.) (Published in summary form only)

  2. Olefins-selective asymmetric carbon molecular sieve hollow fiber membranes for hybrid membrane-distillation processes for olefin/paraffin separations

    KAUST Repository

    Xu, Liren

    2012-12-01

    In this paper, the development of asymmetric carbon molecular sieve (CMS) hollow fiber membranes and advanced processes for olefin/paraffin separations based on the CMS membranes are reported. Membrane-based olefin/paraffin separations have been pursued extensively over the past decades. CMS membranes are promising to exceed the performance upper bound of polymer materials and have demonstrated excellent stability for gas separations. Previously, a substructure collapse phenomenon was found in Matrimid ® precursor derived CMS fiber. To overcome the permeance loss due to the increased separation layer thickness, 6FDA-DAM and 6FDA/BPDA-DAM precursors were selected as potential new precursors for carbon membrane formation. Defect-free asymmetric 6FDA-DAM and 6FDA/BPDA-DAM hollow fibers were successfully fabricated from a dry-jet/wet-quench spinning process. Polymer rigidity, glass-rubber transition and asymmetric morphology were correlated. CMS hollow fiber membranes produced from 6FDA-polymer precursors showed significant improvement in permeance for ethylene/ethane and propylene/propane separations. Further studies revealed that the CMS membranes are olefins-selective, which means the membranes are able to effectively separate olefins (ethylene and propylene) from paraffins (ethane and propane). This unique feature of CMS materials enables advanced hybrid membrane-distillation process designs. By using the olefins-selective membranes, these new processes may provide advantages over previously proposed retrofitting concepts. Further applications of the membranes are explored for hydrocarbons processes. Significant energy savings and even reduced footprint may be achieved in olefins production units. © 2012 Elsevier B.V.

  3. Effect of Steam Deactivation Severity of ZSM-5 Additives on LPG Olefins Production in the FCC Process.

    Science.gov (United States)

    Gusev, Andrey A; Psarras, Antonios C; Triantafyllidis, Konstantinos S; Lappas, Angelos A; Diddams, Paul A

    2017-10-21

    ZSM-5-containing catalytic additives are widely used in oil refineries to boost light olefin production and improve gasoline octanes in the Fluid Catalytic Cracking (FCC) process. Under the hydrothermal conditions present in the FCC regenerator (typically >700 °C and >8% steam), FCC catalysts and additives are subject to deactivation. Zeolites (e.g., Rare Earth USY in the base catalyst and ZSM-5 in Olefins boosting additives) are prone to dealumination and partial structural collapse, thereby losing activity, micropore surface area, and undergoing changes in selectivity. Fresh catalyst and additives are added at appropriate respective levels to the FCC unit on a daily basis to maintain overall targeted steady-state (equilibrated) activity and selectivity. To mimic this process under accelerated laboratory conditions, a commercial P/ZSM-5 additive was hydrothermally equilibrated via a steaming process at two temperatures: 788 °C and 815 °C to simulate moderate and more severe equilibration industrial conditions, respectively. n -Dodecane was used as probe molecule and feed for micro-activity cracking testing at 560 °C to determine the activity and product selectivity of fresh and equilibrated P-doped ZSM-5 additives. The fresh/calcined P/ZSM-5 additive was very active in C 12 cracking while steaming limited its activity, i.e., at catalyst-to-feed (C/F) ratio of 1, about 70% and 30% conversion was obtained with the fresh and steamed additives, respectively. A greater activity drop was observed upon increasing the hydrothermal deactivation severity due to gradual decrease of total acidity and microporosity of the additives. However, this change in severity did not result in any selectivity changes for the LPG (liquefied petroleum gas) olefins as the nature (Brønsted-to-Lewis ratio) of the acid/active sites was not significantly altered upon steaming. Steam deactivation of ZSM-5 had also no significant effect on aromatics formation which was enhanced at higher

  4. Effect of Steam Deactivation Severity of ZSM-5 Additives on LPG Olefins Production in the FCC Process

    Directory of Open Access Journals (Sweden)

    Andrey A. Gusev

    2017-10-01

    Full Text Available ZSM-5-containing catalytic additives are widely used in oil refineries to boost light olefin production and improve gasoline octanes in the Fluid Catalytic Cracking (FCC process. Under the hydrothermal conditions present in the FCC regenerator (typically >700 °C and >8% steam, FCC catalysts and additives are subject to deactivation. Zeolites (e.g., Rare Earth USY in the base catalyst and ZSM-5 in Olefins boosting additives are prone to dealumination and partial structural collapse, thereby losing activity, micropore surface area, and undergoing changes in selectivity. Fresh catalyst and additives are added at appropriate respective levels to the FCC unit on a daily basis to maintain overall targeted steady-state (equilibrated activity and selectivity. To mimic this process under accelerated laboratory conditions, a commercial P/ZSM-5 additive was hydrothermally equilibrated via a steaming process at two temperatures: 788 °C and 815 °C to simulate moderate and more severe equilibration industrial conditions, respectively. n-Dodecane was used as probe molecule and feed for micro-activity cracking testing at 560 °C to determine the activity and product selectivity of fresh and equilibrated P-doped ZSM-5 additives. The fresh/calcined P/ZSM-5 additive was very active in C12 cracking while steaming limited its activity, i.e., at catalyst-to-feed (C/F ratio of 1, about 70% and 30% conversion was obtained with the fresh and steamed additives, respectively. A greater activity drop was observed upon increasing the hydrothermal deactivation severity due to gradual decrease of total acidity and microporosity of the additives. However, this change in severity did not result in any selectivity changes for the LPG (liquefied petroleum gas olefins as the nature (Brønsted-to-Lewis ratio of the acid/active sites was not significantly altered upon steaming. Steam deactivation of ZSM-5 had also no significant effect on aromatics formation which was enhanced at

  5. Organofilização de argilas bentoníticas com tensoativos não- iônicos visando seu uso em fluidos de perfuração base óleo Nonionic surfactants organophilization bentonite clays aiming their use in oil base drilling fluids

    Directory of Open Access Journals (Sweden)

    I. A. Silva

    2012-09-01

    Full Text Available O uso de tensoativos não iônicos vem substituindo os tradicionais tensoativos iônicos dentre outros motivos pelo seu elevado potencial de resistência a degradação térmica. Assim, este trabalho tem por objetivo o desenvolvimento de argilas organofílicas através da incorporação de tensoativos não iônicos visando seu uso em fluidos de perfuração de poços de petróleo base óleo. Argilas bentoníticas natural, industrializadas e organofilizadas foram caracterizadas por análise química, difração de raios X e análises térmicas. Após a organofilização foi realizado o inchamento de Foster, visando a escolha dos tensoativos mais adequados aos meios líquidos orgânicos dispersantes: éster, diesel e parafina. Com as dispersões obtidas foram determinadas as propriedades reológicas através de viscosidades aparente e plástica. Os resultados evidenciaram que as argilas organofilicas apresentaram um aumento do espaçamento interlamelar e que as dispersões apresentaram propriedades reológicas dentro das especificações da Petrobrás, para uso como argilas organofílicas em fluidos de perfuração em base óleo.The nonionic surfactants use is replacing the traditional ionic surfactants among other reasons because of its high resistance to thermal degradation potential. This work aims the organoclays development through the nonionic surfactants incorporation in order to oil base drilling fluids use. The natural bentonite clay, and industrialized organophilizated were characterized by chemical analysis, X-ray diffraction and thermal analysis. After, the clay organophilization was performed by Foster swelling, seeking the most appropriate choice of surfactants to the liquid media organic dispersants, ester, paraffin and diesel. With the obtained dispersions were determined by plastic and apparent viscosities the rheological properties. The results showed that organoclays increase in the interlayer spacing and that the dispersions

  6. Microgravity Drill and Anchor System

    Science.gov (United States)

    Parness, Aaron; Frost, Matthew A.; King, Jonathan P.

    2013-01-01

    This work is a method to drill into a rock surface regardless of the gravitational field or orientation. The required weight-on-bit (WOB) is supplied by a self-contained anchoring mechanism. The system includes a rotary percussive coring drill, forming a complete sampling instrument usable by robot or human. This method of in situ sample acquisition using micro - spine anchoring technology enables several NASA mission concepts not currently possible with existing technology, including sampling from consolidated rock on asteroids, providing a bolt network for astronauts visiting a near-Earth asteroid, and sampling from the ceilings or vertical walls of lava tubes and cliff faces on Mars. One of the most fundamental parameters of drilling is the WOB; essentially, the load applied to the bit that allows it to cut, creating a reaction force normal to the surface. In every drilling application, there is a minimum WOB that must be maintained for the system to function properly. In microgravity (asteroids and comets), even a small WOB could not be supported conventionally by the weight of the robot or astronaut. An anchoring mechanism would be needed to resist the reactions, or the robot or astronaut would push themselves off the surface and into space. The ability of the system to anchor itself to a surface creates potential applications that reach beyond use in low gravity. The use of these anchoring mechanisms as end effectors on climbing robots has the potential of vastly expanding the scope of what is considered accessible terrain. Further, because the drill is supported by its own anchor rather than by a robotic arm, the workspace is not constrained by the reach of such an arm. Yet, if the drill is on a robotic arm, it has the benefit of not reflecting the forces of drilling back to the arm s joints. Combining the drill with the anchoring feet will create a highly mobile, highly stable, and highly reliable system. The drilling system s anchor uses hundreds of

  7. Sequential meta-C-H olefination of synthetically versatile benzyl silanes: effective synthesis of meta-olefinated toluene, benzaldehyde and benzyl alcohols.

    Science.gov (United States)

    Patra, Tuhin; Watile, Rahul; Agasti, Soumitra; Naveen, Togati; Maiti, Debabrata

    2016-02-04

    Tremendous progress has been made towards ortho-selective C-H functionalization in the last three decades. However, the activation of distal C-H bonds and their functionalization has remained fairly underdeveloped. Herein, we report sequential meta-C-H functionalization by performing selective mono-olefination and bis-olefination with late stage modification of the C-Si as well as Si-O bonds. Temporary silyl connection was found to be advantageous due to its easy installation, easy removal and wide synthetic diversification.

  8. Trace elements in a North Sea drill core

    DEFF Research Database (Denmark)

    Kunzendorf, Helmar; Gwozdz, R.; Svendsen, N.

    1986-01-01

    , V, Sr, Dy, Mg, Ti, Ba and Eu. The major elements Ca and Al could be related to petrophysical parameters, particularly Al which shows a correlation with the silicification/argillaceous content. Na (and Cl) has a low content in the hydrocarbon-bearing section of the drill core suggesting that the pore......Chalk samples, systematically taken along a drill core from one of the hydrocarbon producing fields of the North Sea (Tyra field), were analysed by a neutron activation technique involving measurement of radioisotopes with relatively short half-lives. Elements determined include Na, Al, Cl, Ca, Mn...... space is filled mainly by hydrocarbons. A significant decrease of Mn with depth probably suggests diagenesis of chalk prior to, or with, hydrocarbon emplacement. Investigations of drilling fluids and cuttings reveal a strong contamination of the latter, mainly by Ba. Chalk data from comparable onshore...

  9. Environmental control technology in petroleum drilling and production

    International Nuclear Information System (INIS)

    Wojtanowicz, A.K.

    1997-01-01

    Environmental control technology (ECT) is process integrated and relates mainly to pollution prevention and risk assessment. Mechanisms of environmental impact in petroleum drilling, well completion and production, include the generation of waste, induction of toxicity or the creation of pathways for pollutant migration. The identification and evaluation of these mechanisms constitute two parts of the scope of ECT. A third part is the development of new techniques to comply with environmental requirements without prejudicing productivity. The basic concepts of the ECT approach are presented in this chapter. The approach is then used to analyse oilfield drilling and production processes. Environmental control components developed in these technologies are described. These include: the control of the volume and toxicity of drilling fluids; source separation technology in produced water cleaning; subsurface injection of oilfield waste slurries; containment technology in the integrity of petroleum wells; subsurface reduction of produced water; oilfield pit closure technology. (37 figures; 26 tables; 227 references) (UK)

  10. Dynamic Analysis procedure for fluid kicks in hydrocarbon wells

    Energy Technology Data Exchange (ETDEWEB)

    Gavignet, A

    1989-02-10

    A method for analyzing fluid kicks in wells during drilling, in order to assess the risk of a blowout, is presented. An automatic data acquisition and processing system is used to analyze pressure data from transient flow regimes of the drill slurries to determine the nature of the fluid in the borehole (gas, liquid, mixture). The method can be used even if the fluid flowing into the borehole is in an horizontal section of the well.

  11. Drilling miniature holes, Part III

    Energy Technology Data Exchange (ETDEWEB)

    Gillespie, L.K.

    1978-07-01

    Miniature components for precision electromechanical mechanisms such as switches, timers, and actuators typically require a number of small holes. Because of the precision required, the workpiece materials, and the geometry of the parts, most of these holes must be produced by conventional drilling techniques. The use of such techniques is tedious and often requires considerable trial and error to prevent drill breakage, minimize hole mislocation and variations in hole diameter. This study of eight commercial drill designs revealed that printed circuit board drills produced better locational and size repeatability than did other drills when centerdrilling was not used. Boring holes 1 mm in dia, or less, as a general rule did not improve hole location in brass or stainless steel. Hole locations of patterns of 0.66-mm holes can be maintained within 25.4-..mu..m diametral positional tolerance if setup misalignments can be eliminated. Size tolerances of +- 3.8 ..mu..m can be maintained under some conditions when drilling flat plates. While these levels of precision are possible with existing off-the-shelf drills, they may not be practical in many cases.

  12. Drillings at Kivetty in Konginkangas

    International Nuclear Information System (INIS)

    Hinkkanen, H.; Oehberg, A.

    1990-05-01

    According to Government's decision in principle Teollisuuden Voima Oy is obliged to make bedrock investigations for the final disposal of the spent fuel produced by its power plant in Olkiluoto. Areas in Kuhmo, Hyrynsalmi, Sievi, Konginkangas and Olkiluoto were selected for the preliminary site investigations to be carried out during years 1987-1992. In Kivetty, Konginkangas the investigation program was started in spring 1988. During years 1988-1989 a deep borehole (1019 m) and 4 about 500 m deep additional boreholes were core drilled in the area. The structure of the holes makes it possible to carry out many investigations in the holes. Various parameters were measured from the flushing water during the drilling. Corelogging included collecting detailed data of fractures and determining the weathering degree and petrographical properties. Rock mechanical properties, uniaxial compressive strength, Young's modulus and Poisson's ratio were measured from core samples. The flushing water needed in the drillings was pumped from 100 m deep borehole wells drilled with down-the-hole method in the vicinity of the borehole. The water was labeled with 2 tracers before use. 30 vertical holes were core drilled down to the depth of 10 m in bedrock with a light drilling unit. Drilling was carried out in order to determine the thickness of the overburden to investigate the geophysical anomaly sources and to support geological mapping in areas covered with overburden. Groundwater hydraulics is one of the main subjects during the preliminary site investigation phase. For that reason 7 multilevel piezometers were installed on the site to monitore hydraulic head in 3 levels in the uppermost part of bedrock. The work consisted of borehole drillings to the depth of 100 m, geophysical borehole loggings and installation of piezometers. In addition about 65 shotholes were drilled for VSP-, tubewave and seismic measurements

  13. Drillings at Syyry in Sievi

    International Nuclear Information System (INIS)

    Hinkkanen, H.; Oehberg, A.

    1990-10-01

    According to Government's decision in principle Teollisuuden Voima Oy is obliged to make bedrock investigations for the final disposal of the spent fuel produced by its power plant in Olkiluoto. Areas in Kuhmo, Hyrynsalmi, Sievi, Konginkangas and Olkiluoto were selected for the preliminary site investigations to be carried out during years 1987-1992. In Syyry, Sievi the investigation program was started in spring 1988. During years 1988-1989 a deep borehole (1022 m) and 4 about 500-700 m deep additional boreholes were core drilled in the area. The structure of the holes makes it possible to carry out many investigations in the holes. Various parameters were measured from the flushing water during the drilling. Corelogging included collecting detailed data of fractures and determining the weathering degree and petrographical properties. Rock mechanical properties, uniaxial compressive strength, Young's modulus and Poisson's ratio were measured from core samples. The flushing water needed in the drillings was pumped from 100 m deep borehole wells drilled with down-the-hole method in the vicinity of the borehole. The water was labeled with 2 tracers before use. 35 vertical holes were core drilled down to the depth of 10-20 m in bedrock with a light drilling unit. Drilling was carried out in order to determine the thickness of the overburden, to investigate the geophysical anomaly sources and to support geological mapping in areas covered with overburden. Groundwater hydraulics is one of the main subjects during the preliminary site investigation phase. For that reason 7 multilevel piezometers were installed on the site to monitore hydraulic head in 3 levels in the uppermost part of bedrock. The work consisted of borehole drillings to the depth of 100 m, geophysical borehole loggings and installation of piezometers. In addition about 85 shotholes were drilled for VSP-, tubewave and seismic measurements

  14. A new drilling method—Earthworm-like vibration drilling

    Science.gov (United States)

    Wang, Peng; Wang, Ruihe

    2018-01-01

    The load transfer difficulty caused by borehole wall friction severely limits the penetration rate and extended-reach limit of complex structural wells. A new friction reduction technology termed “earthworm-like drilling” is proposed in this paper to improve the load transfer of complex structural wells. A mathematical model based on a “soft-string” model is developed and solved. The results show that earthworm-like drilling is more effective than single-point vibration drilling. The amplitude and frequency of the pulse pressure and the installation position of the shakers have a substantial impact on friction reduction and load transfer. An optimization model based on the projection gradient method is developed and used to optimize the position of three shakers in a horizontal well. The results verify the feasibility and advantages of earthworm-like drilling, and establish a solid theoretical foundation for its application in oil field drilling. PMID:29641615

  15. Determination of thermodynamic affinities of various polar olefins as hydride, hydrogen atom, and electron acceptors in acetonitrile.

    Science.gov (United States)

    Cao, Ying; Zhang, Song-Chen; Zhang, Min; Shen, Guang-Bin; Zhu, Xiao-Qing

    2013-07-19

    A series of 69 polar olefins with various typical structures (X) were synthesized and the thermodynamic affinities (defined in terms of the molar enthalpy changes or the standard redox potentials in this work) of the polar olefins obtaining hydride anions, hydrogen atoms, and electrons, the thermodynamic affinities of the radical anions of the polar olefins (X(•-)) obtaining protons and hydrogen atoms, and the thermodynamic affinities of the hydrogen adducts of the polar olefins (XH(•)) obtaining electrons in acetonitrile were determined using titration calorimetry and electrochemical methods. The pure C═C π-bond heterolytic and homolytic dissociation energies of the polar olefins (X) in acetonitrile and the pure C═C π-bond homolytic dissociation energies of the radical anions of the polar olefins (X(•-)) in acetonitrile were estimated. The remote substituent effects on the six thermodynamic affinities of the polar olefins and their related reaction intermediates were examined using the Hammett linear free-energy relationships; the results show that the Hammett linear free-energy relationships all hold in the six chemical and electrochemical processes. The information disclosed in this work could not only supply a gap of the chemical thermodynamics of olefins as one class of very important organic unsaturated compounds but also strongly promote the fast development of the chemistry and applications of olefins.

  16. Oman Drilling Project Phase I Borehole Geophysical Survey

    Science.gov (United States)

    Matter, J. M.; Pezard, P. A.; Henry, G.; Brun, L.; Célérier, B.; Lods, G.; Robert, P.; Benchikh, A. M.; Al Shukaili, M.; Al Qassabi, A.

    2017-12-01

    The Oman Drilling Project (OmanDP) drilled six holes at six sites in the Samail ophiolite in the southern Samail and Tayin massifs. 1500-m of igneous and metamorphic rocks were recovered at four sites (GT1, GT2, GT3 and BT1) using wireline diamond core drilling and drill cuttings at two sites (BA1, BA2) using air rotary drilling, respectively. OmanDP is an international collaboration supported by the International Continental Scientific Drilling Program, the Deep Carbon Observatory, NSF, NASA, IODP, JAMSTEC, and the European, Japanese, German and Swiss Science Foundations, and with in-kind support in Oman from Ministry of Regional Municipalities and Water Resources, Public Authority of Mining, Sultan Qaboos University and the German University of Technology. A comprehensive borehole geophysical survey was conducted in all the OmanDP Phase I boreholes shortly after drilling in April 2017. Following geophysical wireline logs, using slim-hole borehole logging equipment provided and run by the Centre National De La Recherche Scientifique (CNRS) and the Université de Montpellier/ Géosciences Montpellier, and logging trucks from the Ministry of Regional Municipalities and Water Resources, were collected in most of the holes: electrical resistivity (dual laterolog resistivity, LLd and LLs), spectral gamma ray (K, U, and Th contents), magnetic susceptibility, total natural gamma ray, full waveform sonic (Vp and Vs), acoustic borehole wall imaging, optical borehole wall imaging, borehole fluid parameters (pressure, temperature, electrical conductivity, dissolved oxygen, pH, redox potential, non-polarized spontaneous electrical potential), and caliper (borehole diameter). In addition, spinner flowmeter (downhole fluid flow rate along borehole axis) and heatpulse flow meter logs (dowhole fluid flow rate along borehole axis) were collected in BA1 to characterize downhole fluid flow rates along borehole axis. Unfortuantely, only incomplete wireline logs are available for

  17. GEO-ECOLOGICAL PROBLEMS OF DRILLING WASTE DISPOSAL IN THE YAMAL PENINSULA

    Directory of Open Access Journals (Sweden)

    Oreshkin Dmitrij Vladimirovich

    2012-10-01

    Full Text Available Crude oil and gas fields are located in remote areas known for their severe geological and climatic conditions that are aggravated by the presence of the paleocrystic frozen rock. Borehole drilling causes generation of the substantial amount of drilling waste. The sludge weighs millions of tons. Any rock is to remain frozen at any drilling site in the Yamal peninsula. Semifluid drilling waste occupies extensive areas around drilling sites; they prevent development of the surface infrastructure, they interfere with the work of drilling technicians and contribute to hazardous working conditions, they are a challenge to the local ecology. The above factors produce a negative impact on the environment and prevent sustainable development of the region. For example, disposal of drilling waste at condensed gas fields operated in the Yamal peninsula represents a substantial problem. Drilling waste contains drilling fluid used in the process of borehole drilling. It was discovered in the course of the preliminary research that drilling fluids were composite suspensions that contained bentonite, heavy spar, caustic soda, dilutants, and polymers. It was found out that the sludge was composed of silica, calcite, dolomite, aragonite, magnesite, some feldspars, heavy spar, gypsum and anhydrite, micas, hydromicas, clay minerals. Projections provided in the paper say that pre-neutralized sludge may be used in the manufacturing of building materials, such as bricks, claydite, small-size building units, etc. The authors argue that further research of the sludge elements and microstructure, as well as its chemical, mineral, granulometric and X-ray phase analyses need to be performed.

  18. The rates measurement of methane hydrate formation and dissociation using micro-drilling system application for gas hydrate exploration

    Energy Technology Data Exchange (ETDEWEB)

    Bin Dou [Engineering Faculty, China Univ. of Geosciences, Wuhan (China)]|[Inst. of Petroleum Engineering, Technology Univ. of Clausthal (Germany); Reinicke, K.M. [Inst. of Petroleum Engineering, Technology Univ. of Clausthal (Germany); Guosheng Jiang; Xiang Wu; Fulong Ning [Engineering Faculty, China Univ. of Geosciences, Wuhan (China)

    2006-07-01

    When drilling through gas hydrate bearing formations, the energy supplied by virtue of the drilling process may lead to a destabilization of the hydrates surrounding the wellbore. Therefore, as the number of oil and gas fields being development in deepwater and onshore arctic environments increases, greater emphasis should be placed on quantifying the risks, gas hydrates pose to drilling operations. The qualification of these risks requires a comprehensive understanding of gas hydrate-formation and dissociation as a result of drilling induced processes. To develop the required understanding of gas hydrat formation and dissociation, the authors conducted laboratory experiments by using a micro-drilling system, to study the dissociation rates of methane hydrates contained in a tank reactor. The test facility used is a development of China University of Geosciences. The rates of methane hydrate formation and dissociation in the tank reactor were measured at steady-state conditions at pressures ranging from 0.1 to 25 MPa and temperatures ranging from -5 to 20 C. The experimental results show that the rate of hydrate formation is strongly influenced by the fluid system used to form the hydrates, pressure and temperature, with the influence of the temperature on methane hydrate dissociation being stronger than that of the pressure. Drilling speed, drilling fluids and hydrate dissociation inhibitors were also shown to influence hydrate dissociation rate. The derived results have been used to predict hydrate drilling stability for several drilling fluid systems.

  19. Obtenção de argilas organofílicas purificadas através de tensoativos iônicos e não iônicos visando uso em fluidos de perfuração base óleo Getting purified organoclays by ionic and non-ionic surfactant aiming use in oil based drilling fluids

    Directory of Open Access Journals (Sweden)

    J. M. R. Costa

    2012-12-01

    Full Text Available Em perfurações de petróleo sensíveis ao contato com água, torna-se necessária a utilização de fluidos de perfuração base óleo. Nestes casos, utilizam-se argilas organofílicas, que são obtidas a partir de argilas bentoníticas purificadas e tratadas com a adição de tensoativos. A utilização do hidrociclone pode representar uma ferramenta eficiente e de custo acessível para purificar argilas naturais em escala industrial. Este trabalho tem por objetivo estudar a purificação de argilas bentoníticas utilizando-se um hidrociclone, visando o desenvolvimento de argilas organofílicas para uso em fluidos de perfuração base óleo. As caracterizações das amostras das argilas estudadas - Brasgel PA e Chocolate - foram efetuadas por meio das técnicas: análise granulométrica por difração de laser, difração de raios X (DRX e análise química por fluorescência de raios X. A caracterização das argilas organofílicas obtidas foi efetuada por meio dos seguintes métodos: DRX e por uma modificação do inchamento de Foster. Os resultados mostram que o processo de purificação foi eficiente na redução de impurezas presentes na bentonita e que a argila organofílica purificada tratada com Praepagen WB e Imidazolina Oléica Vegetal apresenta valores de inchamento de Foster em éster, óleo diesel e parafina superiores aos obtidos com argilas organofílicas sem purificação (natural, e evidenciando maior afinidade com o tensoativo Praepagen WB.Oil drilling in sensitive contact with water, becomes required the use of oil base drilling fluids. In these cases, organoclays are used, which are made from clay bentonite purified and treated with surfactants addition. The use of the hydrocyclone can be a effective tool and affordable for purifying clays in industrial scale. This work aims to study the purification of clays bentonite using a hydrocyclone, aiming to develop organoclays for use in oil base drilling fluids. The

  20. Case study : environmental considerations of horizontal directional drills

    International Nuclear Information System (INIS)

    Slade, D.A.

    2000-01-01

    A pipeline construction project by Enbridge Pipelines (Toledo) Inc. which relied on horizontal directional drilling (HDD) techniques to install the pipe was analyzed with particular focus on the environmental benefits and risks of using directional drills compared to open cut installation. The construction of the 35-mile, 16-inch crude petroleum pipeline from Stockbridge to Freedom Junction in Michigan involved the use of 11 separate directional drills to cross through wetlands, streams and state recreational areas. The role that HDD played in route selection and environmental permit considerations was discussed along with some of the problems encountered with directional drilling. A successful HDD program must have adequate geotechnical information to properly design and plan the crossings. It was recommended that geotechnical borings should be conducted every 300 to 500 feet across the HDD alignment. It was also recommended that a frac-out contingency plan should be developed and to be prepared for the temporary shut down of the HDD rig if a frac-out occurs. Frac-outs must be investigated, contained and any released fluid should be removed. Some recommendations from past experiences were also presented as a guide for future planning of pipeline projects that include HDD techniques, particularly in wetland areas. Appendix A to this presentation included a contingency plan for illustrative purposes only. The plan was developed for the above project and was included as an example only. It described the planning, prevention and control measures to minimize impacts resulting from inadvertent spill of drilling mud during directional drilling in wetlands. It also included a drilling mud 'Containment, Response and Notification Plan' to be implemented as determined by the contractor under the supervision of Enbridge Pipelines (Toledo) Inc. 5 refs., 2 tabs., 1 fig., 1 appendix

  1. A drilling rig tower

    Energy Technology Data Exchange (ETDEWEB)

    Mironov, A.A.; Barashkov, V.A.; Bulgakov, E.S.; Kuldoshin, I.P.; Lebedev, A.I.; Papin, N.M.; Rebrik, B.M.; Sirotkin, N.V.

    1981-05-23

    Presentation is made of a drilling rig tower, comprising a gantry, a support shaft with a bracing strut and drawings out, and turn buckles. In order to increase the reliability of the tower in operation, to decrease the over all dimensions in a transport position, and to decrease the amount of time taken to transfer the tower from an operational position into a transportable one, and vice versa, the tower is equipped with a rotary frame made in the form of a triangular prism, whose lateral edges are connected by hinges: the first one with the lower part of the support shaft, the second with the gantry, and the third one to the upper part of the support shaft by means of the drawings out. The large boundary of the rotary frame is connected by a hinge to the support shaft by means of a bracing strut, which is equipped with a slide block connected to it by a hinge, and the rotary frame has a guide for the slide block reinforced to it on the large boundary. Besides this, the lateral edge of the rotary frame is connected to the gantry by means of turn buckles.

  2. Chemical monitoring of mud products on drilled cuttings

    International Nuclear Information System (INIS)

    Hughes, T.L.; Jones, T.G.J.; Tomkins, P.G.; Gilmour, A.; Houwen, O.H.; Sanders, M.

    1991-01-01

    An increasing area of concern for offshore drilling practices in the environmental impact of discharged drilled cuttings contaminated with drilling fluids. The standard retort analysis is of limited accuracy and chemical specificity. Anticipating future requirements for a more complete accounting of mud chemicals discharged to the environment, we present here results for chemical monitoring using a modern comprehensive chemical analysis technique. Fourier transform infrared (FT-IR) spectrometry. In this paper description is given of sampling methods found to be practical and the main calibration requirements are discussed. The techniques developed in the course of this work give a good mineralogical breakdown of mud solids (commercial and drilled solids) in addition to the environmentally relevant measurements relating to mud on cuttings. The possibility of using the new technique for the rigsite monitoring of drilling cuttings is demonstrated. Cuttings samples simultaneously from the flow line, shaker screen, desilter and mud cleaner were analyzed. It is found that mud polymers and other organic additives can be measured with sufficient accuracy to measure the removal of mud products by discharged cuttings. The technique is also applicable to quantify the losses of oil-based mud on cuttings. Field testing has shown that the instrumentation used in sufficiently robust and simple to use for rig-site application

  3. An experimental system for coiled tubing partial underbalanced drilling (CT-PUBD) technique

    Science.gov (United States)

    Shi, H. Z.; Ji, Z. S.; Zhao, H. Q.; Chen, Z. L.; Zhang, H. Z.

    2018-05-01

    To improve the rate of penetration (ROP) in hard formations, a new high-speed drilling technique called Coiled Tubing Partial Underbalanced Drilling (CT-PUBD) is proposed. This method uses a rotary packer to realize an underbalanced condition near the bit by creating a micro-annulus and an overbalanced condition at the main part of the annulus. A new full-scale laboratory experimental system is designed and set up to study the hydraulic characteristics and drilling performance of this method. The system is composed of a drilling system, circulation system, and monitor system, including three key devices, namely, cuttings discharge device, rotary packer, and backflow device. The experimental results showed that the pressure loss increased linearly with the flow rate of the drilling fluid. The high drilling speed of CT-PUBD proved it a better drilling method than the conventional drilling. The experimental system may provide a fundamental basis for the research of CT-PUBD, and the results proved that this new method is feasible in enhancing ROP and guaranteeing the drilling safety.

  4. hf alkylation in the 1980's: the role of isobutane/olefin ratio

    Energy Technology Data Exchange (ETDEWEB)

    Hutson, T. Jr.

    1978-08-01

    Research devoted to maximizing no-lead octane numbers in motor fuel is reported. Results of the studies are the basis for the following conclusions: 1. Isobutane alkylate made from either propylene, butene-2, or C/sub 3/--C/sub 4/ mixed olefins is a low sensitivity, high motor octane product. Typically, C/sub 3/--C/sub 4/ mixed olefin alkylate has a clear motor octane number of about 92.2 and a clear Research octane number of about 93.5. 2. In separate studies with propylene, butene-2 and C/sub 3/--C/sub 4/ mixed olefins, increasing the isobutane-to-olefin ratio suppressed the formation of high molecular weight residue, indicating a substantial reduction in the role of olefin polymerization to large ions. The overall result of increasing ratio was an improvement in selectivity to high-octane components in the alkylate. 3. When alkylating isobutane with propylene, increasing the ratio resulted in a decrease in the concentration of C/sub 7/-fraction (primary product) and an increase in the C/sub 8/-fraction (from chain initiation and subsequent hydrogen transfer). At the same time, the production of chain-termination-product propane also increased. 4. When alkylating isobutane with C/sub 3/--C/sub 4/ mixed olefins, increasing the ratio showed the same trend obtained in separate alkylation tests with propylene and butene-2. As the ratio increased, the concentration of C/sub 7/-fraction (primary propylene--isobutane product) decreased and the concentration of C/sub 8/-fraction increased markedly. Thus, increasing isobutane-to-olefin ratio exerted a strong effect on alkylate quality in the area of about 5 to 1 to 20 to 1; this effect diminished at ratios 20:1.

  5. Drilling a borehole for LEP

    CERN Multimedia

    1981-01-01

    Boreholes were drilled along the earlier proposed line of the LEP tunnel under the Jura to find out the conditions likely to be encountered during the construction of the LEP tunnel (Annual Report 1981 p. 106, Fig. 10).

  6. Computed tomography of drill cores

    International Nuclear Information System (INIS)

    Taylor, T.

    1985-08-01

    A preliminary computed tomography evaluation of drill cores of granite and sandstone has generated geologically significant data. Density variations as small as 4 percent and fractures as narrow as 0.1 mm were easily detected

  7. Geothermal drilling in Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez A., Bernardo

    1982-08-10

    The number of characteristics of the different wells that have been drilled in the Cerro Prieto geothermal field to date enable one to summarize the basic factors in the applied technology, draw some conclusions, improve systems and procedures, and define some problems that have not yet been satisfactorily solved, although the existing solution is the best now available. For all practical purposes, the 100 wells drilled in the three areas or blocks into which the Cerro Prieto field has been divided have been completed. Both exploratory and production wells have been drilled; problems of partial or total lack of control have made it necessary to abandon some of these wells, since they were unsafe to keep in production or even to be used for observation and/or study. The wells and their type, the type of constructed wells and the accumulative meters that have been drilled for such wells are summarized.

  8. Optimization of Mud Hammer Drilling Performance--A Program to Benchmark the Viability of Advanced Mud Hammer Drilling

    Energy Technology Data Exchange (ETDEWEB)

    Arnis Judzis

    2006-03-01

    Operators continue to look for ways to improve hard rock drilling performance through emerging technologies. A consortium of Department of Energy, operator and industry participants put together an effort to test and optimize mud driven fluid hammers as one emerging technology that has shown promise to increase penetration rates in hard rock. The thrust of this program has been to test and record the performance of fluid hammers in full scale test conditions including, hard formations at simulated depth, high density/high solids drilling muds, and realistic fluid power levels. This paper details the testing and results of testing two 7 3/4 inch diameter mud hammers with 8 1/2 inch hammer bits. A Novatek MHN5 and an SDS Digger FH185 mud hammer were tested with several bit types, with performance being compared to a conventional (IADC Code 537) tricone bit. These tools functionally operated in all of the simulated downhole environments. The performance was in the range of the baseline ticone or better at lower borehole pressures, but at higher borehole pressures the performance was in the lower range or below that of the baseline tricone bit. A new drilling mode was observed, while operating the MHN5 mud hammer. This mode was noticed as the weight on bit (WOB) was in transition from low to high applied load. During this new ''transition drilling mode'', performance was substantially improved and in some cases outperformed the tricone bit. Improvements were noted for the SDS tool while drilling with a more aggressive bit design. Future work includes the optimization of these or the next generation tools for operating in higher density and higher borehole pressure conditions and improving bit design and technology based on the knowledge gained from this test program.

  9. Cleaning fluid emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Prikryl, J; Kotyza, R; Krulikovsky, J; Mjartan, V; Valisova, I

    1981-09-15

    Composition of cleaning fluid emulsion are presented for drilling small diameter wells in clay soils, at high drill bit rotation velocity. The emulsions have lubricating properties and the abilty to improve stability of the drilled soil. The given fluids have a high fatty acid content with 12-24 carbon atoms in a single molecule, with a predominance of resinous acids 1-5% in mass, and having been emulsified in water or clay suspension without additives, or in a clay suspension with high-molecular polymer additives (glycobate cellulose compounds and/or polysaccharides, and/or their derivatives) in an amount of 0.1-3% per mass; thinning agents - huminite or lignite compounds in the amount of 0.01 to 0.5% in mass; weighting material - barite or lime 0.01 to 50% per mass; medium stabilizers - organic poly-electrolyte with polyacrylate in the amount of 0.05 to 2% in mass, or alkaline chloride/alkaline-ground metals 1-10% per mass. A cleaning emulsion fluid was prepared in the laboratory according to the given method. Add 3 kg tall oil to a solution of 1 kg K/sub 2/CO/sub 3/ per 100 l of water. Dynamic viscosity was equal to 1.4 x 10-/sup 3/ Pa/s. When drilling in compacted clay soils, when the emulsions require improved stability, it is necessary to add the maximum amount of tall oil whose molecules are absorbed by the clay soil and increase its durability.

  10. Superhot Drilling in Iceland, the Experience of the Iceland Deep Drilling Project.

    Science.gov (United States)

    Elders, W. A.; Friðleifsson, G. Ó.; Zierenberg, R. A.; Fowler, A. P.

    2017-12-01

    The Iceland Deep Drilling Project aims to improve geothermal economics by producing supercritical fluids (www.iddp.is). Supercritical wells could yield an order of magnitude more usable energy than that from conventional geothermal wells because of higher enthalpy and enhanced flow properties. In 2009, the IDDP-1 well failed to reach supercritical conditions in the Krafla caldera in NE Iceland, after encountering rhyolite magma at only 2.1 km depth. The completed geothermal well became the world's hottest and produced superheated steam with a wellhead temperature of 452°C and flow sufficient to generate 35 MWe. The IDDP next moved SW to the Reykjanes Peninsula, the landward extension of the Mid-Atlantic Ridge, where it is possible to study an analog of the roots of a black smoker. Reykjanes is unique among Icelandic geothermal systems in being recharged by seawater, which has a critical point of 406°C at 298 bars. Drilling began by deepening an existing 2.5 km deep production well to 3 km depth, and then angling it towards the main upflow zone of the system, for a total slant depth of 4,659 m. Total circulation losses were encountered below 3 km that could not be cured by lost circulation materials or by multiple cement jobs. Accordingly, drilling continued to total depth without return of drill cuttings. We attempted 13 core runs below 3 km depth, only half of which recovered core. The cores are basalts and dolerites with alteration ranging from lower greenschist facies to lower amphibolite facies, suggesting formation temperatures >450°C. After the end of drilling in January 2017, following only six days of heating, supercritical conditions (426°C at 340 bars) were measured in the well at a depth of 4.5 km. The well has not yet been allowed to equilibrate to full in situ temperature. A perforated liner was inserted to 4,570 m, depth to facilitate temperature cycling to enhance permeability at depth through thermal cracking. In 2018 this will be followed by a

  11. Synthesis of engineering designs of drilling facilities

    Science.gov (United States)

    Porozhsky, K.

    2018-03-01

    The article sets forth key principles of engineering of drilling equipment based on successive analysis of the goals of the production method, technologies of its implementation and conditions of mineral mining using a new approach to systematization of drilling methods. Potential advancement in the technologies and equipment of drilling is illustrated in terms of oil-well drilling.

  12. Device for storing drilling pipes

    Energy Technology Data Exchange (ETDEWEB)

    Kolasinski, A; Wedrychowicz, J

    1981-02-16

    The patented device contains a profiled arch 14 (see figure) installed in the upper part of the drilling rig 15. On base 16 of the drilling unit, there is bin 1 which is installed on frame 2 to which it is hinge connected with the help of pin 3. On the other side, the bin rests on rollers 4 which are attached to lever 5 of lifting mechanism 6. Bin 1 is a series of parallel-arranged guides rigidly connected by transverse beams. Frame 2 contains the collapsible support 10. During operation of the device, the hydraulic lifter 6 with the help of frame 5 and rollers 4 lifts bin 1 with drilling pipes installed on it, giving it an angle of 4/sup 0/ in relation to the plane of frame 2. The collapsible support 10 is installed in a vertical position and holds bin 1. This position of bin 1 is the most suitable for movement of the vertically installed drilling pipes on the guides. The distinguishing feature of the patented device is the possibility of convenient arrangement of the drilling pipes on the guides of bin 1. Because of this, the time spent on lifting and lowering the drill apparatus is considerably reduced.

  13. You say you want a revolution: casing drilling targets 30 per cent well-cost saving

    Energy Technology Data Exchange (ETDEWEB)

    Polczer, S.; Marsters, S.

    1999-10-01

    Casing drilling is a new method of drilling that eliminates drill strings by using standard casing to simultaneously drill and case wells. Tesco Corporation of Calgary acquired patent rights to casing drilling technology in 1995. The company now offers a conversion kit for existing drill rigs as well a new compact casing drilling rig for shallow markets. The single derrick will be rated at 1,500 meters, but initially it will be used to drill 700-800 meter gas wells in southeast Alberta. Some cost savings will be realized at these shallow depths, but the real cost saving advantages will be realized on deep holes. In the meantime, improvements are planned to the cutting structures of the under-rimming bit to increase safety and withstand higher torque loads. It will be also necessary to adapt techniques such as directional drilling and logging to the casing drilling conveyance mechanism which has been only partially successful thus far, especially in the retrieving mode. Another challenge already met, involved ensuring that casing could be run in high-compression loads without damage to connections. Despite these problems, the system attracted considerable attention with several international companies placing orders for immediate delivery. Another system, this one developed by Sperry-Sun Drilling Services and known as a 'casing while drilling' (CWD) system, is strictly a downhole assembly and is targeted for offshore use and deeper vertical holes. This system is currently being tested in two commercial operations in offshore Indonesia for Unocal Corporation. Despite numerous problems to fill casing with fluid during connections, penetration rates of 300-400 feet per hour were achieved.

  14. Proceedings of the DGMK-Conference 'Creating value from light olefins - production and conversion'. Authors' manuscripts

    Energy Technology Data Exchange (ETDEWEB)

    Emig, G.; Kraemer, H.J.; Weitkamp, J. (eds.)

    2001-07-01

    Main topics of the conference were: production of light olefin by steamcracking and catalytic cracking processes, catalysts, methanol to olefin processes, oxidative dehydrogenation, partial oxidation, selective oxidation of alkanes with various catalysts. (uke)

  15. Drilling a better pair : new technologies in SAGD directional drilling

    Energy Technology Data Exchange (ETDEWEB)

    Zimmer, C.; Richter, D. [Statoil Canada Ltd., Calgary, AB (Canada); Person, J.; Tilley, J.; Bittar, M. [Halliburton Energy Services, Calgary, AB (Canada)

    2010-07-01

    The Leismer Demonstration Project (LDP) is the first of 8 proposed major steam assisted gravity drainage (SAGD) projects for Statoil's Kai Kos Dehseh (KKD) asset in the Athabasca oil sands deposit. The bitumen resources are expected to produce approximately 2.2 billion barrels of oil over approximately 35 years with a peak production of 220,000 bbl/day. To date, 23 well pairs have been drilled on 4 drilling pads. The precise placement of well pairs is among the most important factors in a successful SAGD drilling program. The producer well must be placed in relation to the reservoir boundaries. It must also be accurately twinned with the injector well. A strong focus on technological innovation is needed in order to deliver on these high expectations in unconsolidated formations, such as the McMurray oil sands. Lateral SAGD pairs are often drilled with conventional steerable mud motors and logging-while-drilling (LWD) resistivity measurements, but this combination imposes certain limitations in terms of wellbore quality and placement. Several industry firsts were successfully implemented at the Statoil LDP, including a combination of the newest and most cutting-edge directional, measurement, and LWD technology. The keystone of these industry firsts was the use of a soft formation modified, point-the-bit rotary steerable system (RSS), used on 20 horizontal wells. The RRS was combined with an ultra deep azimuthal resistivity sensor to provide precise geosteering along the bottom bed boundary in the producer wells, resulting in improved reservoir capture and reservoir characterization. This paper described the new drilling system and its impact on the progressive future of directional drilling in SAGD. 8 refs., 1 tab., 22 figs.

  16. (Electro)Mechanical Properties of Olefinic Block Copolymers

    Science.gov (United States)

    Spontak, Richard

    2014-03-01

    Conventional styrenic triblock copolymers (SBCs) swollen with a midblock-selective oil have been previously shown to exhibit excellent electromechanical properties as dielectric elastomers. In this class of electroactive polymers, compliant electrodes applied as active areas to opposing surfaces of an elastomer attract each other, and thus compress the elastomer due to the onset of a Maxwell stress, upon application of an external electric field. This isochoric process is accompanied by an increase in lateral area, which yields the electroactuation strain (measuring beyond 300% in SBC systems). Performance parameters such as the Maxwell stress, transverse strain, dielectric breakdown, energy density and electromechanical efficiency are determined directly from the applied electric field and resulting electroactuation strain. In this study, the same principle used to evaluate SBC systems is extended to olefinic block copolymers (OBCs), which can be described as randomly-coupled multiblock copolymers that consist of crystallizable polyethylene hard segments and rubbery poly(ethylene-co-octene) soft segments. Considerations governing the development of a methodology to fabricate electroresponsive OBC systems are first discussed for several OBCs differing in composition and bulk properties. Evidence of electroactuation in selectively-solvated OBC systems is presented and performance metrics measured therefrom are quantitatively compared with dielectric elastomers derived from SBC and related materials.

  17. Separation of products of alkylation of isobutane by olefins

    Energy Technology Data Exchange (ETDEWEB)

    Ward, J.

    1979-03-15

    The alkylation (A1) of isobutane (I) by propylene, butylene and amylenes is carried out at 24-52 degrees, pressure sufficient to maintain the liquid phase, and a molar ratio of I to olefins (O1) 10:1-15:1. The bulk ratio of catalysts to hydrocarbons in the reaction zone was 0.5:1-10:1; when using HF-K-T as the catalysts, it should contain less than 5 percent water and greater than or equal to 65 percent titrated HF. The hydrocarbon products (UP) from the alkylation zone are added after separating the catalyst in a fractionation tower; distillation is carried out at 38-49 degrees and 1.03-1.3 NPa. The head fraction containing I and less than 50 molar percent C3H8 and also fraction I at the point below the input side of the UP which contains less than 8 molar percent C3H8 and fraction n-C4H10 at the point below the point of discharge of fraction I is drained from the tower. The alkylate is discharged at the bottom of the tower. According to the patent the tower operates at low pressure. This improves relative volatility of individual components and reduces heat consumption. The best results are obtained when a head fraction or the concentration C3H8 approximately 25 molar percent is discharged.

  18. Catalyst compositions useful for olefin isomerization and disproportionation

    International Nuclear Information System (INIS)

    Drake, C.A.

    1987-01-01

    A process is described for the double bond isomerization of an aliphatic olefinic hydrocarbon feed which comprises contacting the feed under isomerization conditions with a catalyst prepared by: (a) impregnating an alumina support having a surface area of at least 200 m/sup 2//g and a pore volume of at least 0.45 cm/sup 3//g with: 1 up to 20 wt. % of at least one magnesium compound convertible to the oxide, based on the weight of support and calculated as the metal; 0 up to 5 wt. % of at least one alkali metal compound convertible to the oxide, based on the weight of support and calculated as the metal; and 0 up to 5 wt. % of at least one zirconium compound convertible to the oxide, based on the weight of support and calculated as the metal; and (b) heating the alumina support impregnated in accordance with step (a) in an oxygen-containing atmosphere under conditions suitable to convert at least a portion of the magnesium, alkali metal, and zirconium compounds to the oxide form

  19. Treatment of oil-contaminated drill cuttings using supercritical carbon dioxide (SC CO2)

    International Nuclear Information System (INIS)

    Odusanya, O.O.; Guigard, S.E.

    2002-01-01

    New treatment technologies are currently being investigated for the treatment of oil-contaminated drill cuttings generated during drilling for oil and gas. Supercritical Fluid Extraction (SFE) is a promising technology that could effectively treat these contaminated drill cuttings. The objectives of this work were therefore to investigate the application of SFE to oil-contaminated drill cuttings treatment and to determine the optimal extraction conditions to remove the oil from these cuttings. Preliminary extractions indicate that SFE with carbon dioxide (CO 2 ) can effectively remove oil from oil-contaminated drill cuttings. Extraction efficiencies calculated based on Total Petroleum Hydrocarbon (TPH) content were greater than 76% for the cuttings and extraction conditions tested in this work. The preliminary results indicate a trend of increasing extraction efficiencies with increasing temperature and pressure although more data is required to confirm this trend. Additional work will focus on performing additional extractions to determine the optimum extraction conditions. (author)

  20. Study on the effect of innovative leaching solvent on the oil removal for oily drilling cuttings

    Science.gov (United States)

    Li, Long; Ma, Cha; Hao, Weiwei; Li, Mu; Huang, Zhao; Liu, Yushuang

    2018-02-01

    A new type of leaching solvent for oily drilling cuttings was developed, and the effect of leaching solvent on the oil removal for oily cuttings was investigated. The results indicated that the leaching solvent had good capacity of oil removal for oily cuttings, and the oil content of treated cuttings is less than 0.6%. The leaching solvent could be separated from the oil phase through distillation, and the recyclable solvent could be reused to treat other cuttings. Moreover, oil resources adsorbed on the oily cuttings could be recycled and reused to prepare new drilling fluids, so the drilling cost could be reduced greatly. As a result, the leaching solvent could treat the oily cuttings effectively, and recycle and reuse oil resources, and thus produce great economic benefits. It can play an essential role in safe drilling jobs and improvement of drilling efficiency in the future.

  1. Modeling of hydrologic perturbations during reverse circulation drilling: 1, System and model description

    International Nuclear Information System (INIS)

    Sagar, B.; Connelly, M.P.; Long, P.E.

    1988-05-01

    The Hanford site located in southeastern Washington state was under consideration for the location of a high-level nuclear waste repository. As a part of site investigation, a borehole of depth > 3000 ft was drilled using reverse circulation drilling technique with water as the drilling fluid. After completion of drilling, seven piezometers were to be installed in the borehole with their lower ends at different depths to measure equilibrated hydraulic heads and aquifer response during future pumping tests. The hydrologic perturbations caused during the drilling, clean up, and piezometer installation process were of primary concern. A numerical model was used to predict these perturbations and determine efficiency of borehole cleanup. It was found that the boundary condition at the borehole was the most difficult to model. 9 refs., 5 figs

  2. Influence of plasma shock wave on the morphology of laser drilling in different environments

    Science.gov (United States)

    Zhai, Zhaoyang; Wang, Wenjun; Mei, Xuesong; Wang, Kedian; Yang, Huizhu

    2017-05-01

    Nanosecond pulse laser was used to study nickel-based alloy drilling and compare processing results of microholes in air environment and water environment. Through analysis and comparison, it's found that environmental medium had obvious influence on morphology of laser drilling. High-speed camera was used to shoot plasma morphology during laser drilling process, theoretical formula was used to calculate boundary dimension of plasma and shock wave velocity, and finally parameters were substituted into computational fluid dynamics simulation software to obtain solutions. Obtained analysis results could intuitively explain different morphological features and forming reasons between laser drilling in air environment and water environment in the experiment from angle of plasma shock waves. By comparing simulation results and experimental results, it could help to get an understanding of formation mechanism of microhole morphology, thus providing basis for further improving process optimization of laser drilling quality.

  3. Ferroacryl mud for drilling deep bore holes

    Energy Technology Data Exchange (ETDEWEB)

    Lisyanskiy, V I; Chepiga, V I; Devydenko, V N

    1982-01-01

    The composition, technology of production and control of the parameters of a ferroacyl (FAR) mud for drilling for prospecting holes in the Donets-Basin are developed. The mud consists of Chasov Yal clay (150-160 kg), hypane (40 1), iron sulfate (1kg) and water (approximately 1 m/sup 3/). The mud exhibits the following parameters: density 1.05 -1.1 g/cm/sup 3/, viscosity 20-21 s; water yield 3-5 cm/sup 3/; crust 0.5 mm. Compared to existing flushing fluids based on hypane the FAR contains fewer components and the cost of the materials is considerably less. It features very high flocculating properties.

  4. Rotary steerable motor system for underground drilling

    Science.gov (United States)

    Turner, William E [Durham, CT; Perry, Carl A [Middletown, CT; Wassell, Mark E [Kingwood, TX; Barbely, Jason R [Middletown, CT; Burgess, Daniel E [Middletown, CT; Cobern, Martin E [Cheshire, CT

    2008-06-24

    A preferred embodiment of a system for rotating and guiding a drill bit in an underground bore includes a drilling motor and a drive shaft coupled to drilling motor so that drill bit can be rotated by the drilling motor. The system further includes a guidance module having an actuating arm movable between an extended position wherein the actuating arm can contact a surface of the bore and thereby exert a force on the housing of the guidance module, and a retracted position.

  5. Radiation degradation of poly(olefin sulphone)s - Fundamental research to practical applications

    International Nuclear Information System (INIS)

    Bowden, M.J.; O'Donnell, J.H.

    1985-01-01

    The degradation of poly(olefin sulphone)s by high energy radiation, particularly by γ-rays and electron beams, provides an example of the application of fundamental science to high technology industry. Scientific interest in the radiation degradation of these polymers was first aroused by the discovery that they underwent highly specific bond scission in the backbone chain as the primary result of absorption of high energy radiation and in fact they were the first polymers in which such an effect had been demonstrated. This conclusion was initially based mainly on evidence from electron spin resonance spectroscopy and was subsequently verified by studies of molecular weight changes. These studies showed that the poly(olefin sulphone)s not only degraded by main chain scission but were also among the most radiation-sensitive polymers known. The extremely high sensitivity of poly(olefin sulphone)s to radiation-induced main-chain scission has found application in the field of microelectronics. Electron beam writing on poly(olefin sulphone) films is used to produce lithographic masks for the manufacture of integrated circuits on silicon wafers. Poly(1-butene sulphone) (PBS) is currently used in the production of a substantial proportion of the masks for the industry. The fundamental aspects of the radiation degradation of poly(olefin sulphone)s and the practical applications to high technology are reviewed. (author)

  6. Optimization of catalytic glycerol steam reforming to light olefins using Cu/ZSM-5 catalyst

    International Nuclear Information System (INIS)

    Zakaria, Z.Y.; Amin, N.A.S.; Linnekoski, J.

    2014-01-01

    Highlights: • Glycerol steam reforming to light olefin using Cu/ZSM-5 process was optimized. • Response surface methodology and multi-objective genetic algorithm were employed. • Second order polynomial model produced adequately fitted experimental data. • Thermodynamic study inferred high temperature requirement for ethylene formation. • Turn-over-frequency at optimized responses is higher than the non-optimized process. - Abstract: Response surface methodology (RSM) and multi-objective genetic algorithm was employed to optimize the process parameters for catalytic conversion of glycerol, a byproduct from biodiesel production, to light olefins using Cu/ZSM-5 catalyst. The effects of operating temperature, weight hourly space velocity (WHSV) and glycerol concentration on light olefins selectivity and yield were observed. Experimental results revealed the data adequately fitted into a second-order polynomial model. The linear temperature and quadratic WHSV terms gave significant effect on both responses. Optimization of both the responses indicated that temperature favouring high light olefin formation lied beyond the experimental design range. The trend in the temperature profile concurred commensurately with the thermodynamic analysis. Multi-objective genetic algorithm was performed to attain a single set of processing parameters that could produce both the highest light olefin selectivity and yield. The turn-over-frequency (TOF) of the optimized responses demonstrated a slightly higher value than the one which was not optimized. Combination of RSM, multi-objective response and thermodynamic is useful to determine the process optimal operating conditions for industrial applications

  7. Direct Olefination of Alcohols with Sulfones by Using Heterogeneous Platinum Catalysts.

    Science.gov (United States)

    Siddiki, S M A Hakim; Touchy, Abeda Sultana; Kon, Kenichi; Shimizu, Ken-Ichi

    2016-04-18

    Carbon-supported Pt nanoparticles (Pt/C) were found to be effective heterogeneous catalysts for the direct Julia olefination of alcohols in the presence of sulfones and KOtBu under oxidant-free conditions. Primary alcohols, including aryl, aliphatic, allyl, and heterocyclic alcohols, underwent olefination with dimethyl sulfone and aryl alkyl sulfones to give terminal and internal olefins, respectively. Secondary alcohols underwent methylenation with dimethyl sulfone. Under 2.5 bar H2, the same reaction system was effective for the transformation of alcohol OH groups to alkyl groups. Structural and mechanistic studies of the terminal olefination system suggested that Pt(0) sites on the Pt metal particles are responsible for the rate-limiting dehydrogenation of alcohols and that KOtBu may deprotonate the sulfone reagent. The Pt/C catalyst was reusable after the olefination, and this method showed a higher turnover number (TON) and a wider substrate scope than previously reported methods, which demonstrates the high catalytic efficiency of the present method. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Diagnostic System of Drill Condition in Laminated Chipboard Drilling Process

    Directory of Open Access Journals (Sweden)

    Swiderski Bartosz

    2017-01-01

    Full Text Available The paper presents an on-line automatic system for recognition of the drill condition in a laminated chipboard drilling process. Two states of the drill are considered: the sharp enough (still able to drill holes acceptable for processing quality and worn out (excessive drill wear, not satisfactory from the quality point of view of the process. The automatic system requires defining the diagnostic features, which are used as the input attributes to the classifier. The features have been generated from 5 registered signals: feed force, cutting torque, noise, vibration and acoustic emission. The statistical parameters defined on the basis of the auto regression model of these signals have been used as the diagnostic features. The sequential step-wise feature selection is applied for choosing the most discriminative set of features. The final step of recognition is done by support vector machine classifier working in leave one out mode. The results of numerical experiments have confirmed good quality of the proposed diagnostic system.

  9. An Investigation for Disposal of Drill Cuttings into Unconsolidated Sandstones and Clayey Sands

    Energy Technology Data Exchange (ETDEWEB)

    Mese, Ali; Dvorkin, Jack; Shillinglaw, John

    2000-09-11

    This project include experimental data and a set of models for relating elastic moduli/porosity/texture and static-to-dynamic moduli to strength and failure relationships for unconsolidated sands and clayey sands. The results of the project should provide the industry with a basis for wider use of oil base drilling fluids in water sensitive formations by implementing drill cutting injection into existing wells at abandoned formations and controlling fracture geometry to prevent ground water contamination.

  10. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins%动植物油生产清洁燃料和低碳烯烃的替代加工工艺

    Institute of Scientific and Technical Information of China (English)

    田华; 李春义; 杨朝合; 山红红

    2008-01-01

    Since the production cost of biodiesel is now the main hurdle limiting their applicability in some areas, catalytic cracking reactions represent an alternative route to utilization of vegetable oils and animal fats. Hence, catalytic transformation of oils and fats was carried out in a laboratory-scale two-stage riser fluid catalytic cracking (TSRFCC) unit in this work. The results show that oils and fats can be used as FCC feed singly or co-feeding with vacuum gas oil (VGO), which can give high yield (by mass) of liquefied petroleum gas (LPG), C2-C4 olefins, for example 45% LPG, 47% C2-C4 olefins, and 77.6% total liquid yield produced with palm oil cracking. Co-feeding with VGO gives a high yield of LPG (39.1%) and propylene (18.1%). And oxygen element content is very low (about 0.5%) in liquid products, hence, oxygen is removed in the form of H2O, CO and CO2. At the same time, high concentration of aromatics (C7-C9 aromatics predominantly) in the gasoline fraction is obtained after TSRFCC reaction of palm oil, as a result of large amount of hydrogen-transfer, cyclization and aromatization reactions. Additionally, most of properties of produced gasoline and diesel oil fuel meet the requirements of national standards, containing little sulfur. So TSRFCC technology is thought to be an alternative processing technology leading to production of clean fuels and light olefins.

  11. Use of water in aiding olefin/paraffin (liquid + liquid) extraction via complexation with a silver bis(trifluoromethylsulfonyl)imide salt

    International Nuclear Information System (INIS)

    Wang, Yu; Thompson, Jillian; Zhou, Jingjing; Goodrich, Peter; Atilhan, Mert; Pensado, Alfonso S.; Kirchner, Barbara; Rooney, David; Jacquemin, Johan; Khraisheh, Majeda

    2014-01-01

    Highlights: • Silver-based ILs used as olefin extracting agents for olefin/paraffin mixtures. • Each extraction process is based on the olefin complexation and solvation. • The presence of water influences positively each extraction process. • Each extraction process was evaluated by DFT calculations, NMR, IR and Raman. • LLE data were then correlated by using the UNIQUAC model. - Abstract: This paper describes the extraction of C 5 –C 8 linear α-olefins from olefin/paraffin mixtures of the same carbon number via a reversible complexation with a silver salt (silver bis(trifluoromethylsulfonyl)imide, Ag[Tf 2 N]) to form room temperature ionic liquids [Ag(olefin) x ][Tf 2 N]. From the experimental (liquid + liquid) equilibrium data for the olefin/paraffin mixtures and Ag[Tf 2 N], 1-pentene showed the best separation performance while C 7 and C 8 olefins could only be separated from the corresponding mixtures on addition of water which also improves the selectivity at lower carbon numbers like the C 5 and C 6 , for example. Using infrared and Raman spectroscopy of the complex and Ag[Tf 2 N] saturated by olefin, the mechanism of the extraction was found to be based on both chemical complexation and the physical solubility of the olefin in the ionic liquid ([Ag(olefin) x ][Tf 2 N]). These experiments further support the use of such extraction techniques for the separation of olefins from paraffins

  12. Rh(iii)-catalyzed C-H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant.

    Science.gov (United States)

    Lu, Yi; Wang, Huai-Wei; Spangler, Jillian E; Chen, Kai; Cui, Pei-Pei; Zhao, Yue; Sun, Wei-Yin; Yu, Jin-Quan

    2015-03-01

    The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(iii)-catalyzed C-H activation reaction. The use of an N -pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant.

  13. (E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases.

    Science.gov (United States)

    Yao, Chuan-Zhi; Li, Qiang-Qiang; Wang, Mei-Mei; Ning, Xiao-Shan; Kang, Yan-Biao

    2015-05-04

    An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly (E)-selective internal olefins.

  14. Modern Shale Gas Horizontal Drilling: Review of Best Practices for Exploration Phase Planning and Execution

    Institute of Scientific and Technical Information of China (English)

    Nathaniel Harding; Stephen Smith; John Shelton; Mike D. Bumaman

    2009-01-01

    The challenging characteristics of shale formations often require horizontal drilling to economically develop their potential. While every shale gas play is unique, there are several best practices for the proper planning and execution of a horizontal well. In planning a horizontal well, the optimal method and technology for building inclination and extending the lateral section must be determined. Properly specified logging-while-drilling tools are essential to keep the wellbore within the target formation. Planning must also focus on casing design. Doing so will help ensure stability and enable reliable and productive completions. Shales pose a challenge for these elements of well planning due to their thin strata and potentially low mechanical competence when foreign fluids are introduced. Once a plan is developed, executing it is even more important to prove a viable exploration program. Fast, efficient drilling with wellbore control and minimal torque and drag should be the priority. This may be achieved by focusing on fluid hydraulics and rheology and bottom hole assembly. Managed pressure drilling (MPD) will help fast drilling, well control and stability. If MPD can be combined with new generation rotary steerable systems that allow the drill string to maintain rotation, impressive efficiencies are possible. Modern drilling parameter analysis represents the newest opportunity for executing shale gas horizontal wells. A method for ROP analysis to improve operational parameters and equipment selection is also proposed.

  15. Numerical investigation of the prospects of high energy laser in drilling oil and gas wells

    International Nuclear Information System (INIS)

    Agha, K.R.; Belhaj, H.A.; Mustafiz, S.; Islam, M.R.; Bjorndalen, N.

    2004-01-01

    Rotary drilling is the primary method used to reach oil and gas formations that was developed over a century ago. Many problems persist with this method, including downtime due to dull bits, the lack of precise vertical or horizontal wells and formation fluid leakage during drilling due to the lack of a seal around the hole. Laser drilling is a new technology that has been proposed as a method to eliminate the current problems while drilling and provide a less expensive alternative to conventional methods. This paper discussed the development of a numerical model based on the fundamental heat transfer and fluid flow phenomena including conduction, melting and vaporization responsible for material removal by laser drilling process. The paper addressed the thermal process involved in laser drilling of sandstone and limestone rocks as well as aluminum and mild steel. The paper outlined the parametric study and discussed the design considerations for a field application. Economical and environmental impacts were also included. It was concluded that more experimental investigation is needed to fully understand the laser operation and to enhance the integrity of the numerical models. In addition, it was concluded that field equipment must be designed to meet the changes in drilling requirements. 19 refs., 10 figs

  16. Flushing wells during drilling in rocks with negative temperature

    Energy Technology Data Exchange (ETDEWEB)

    Badalov, S S

    1982-01-01

    Results are examined of experimental studies of cavern formation in loose sands cemented by ice. The new data obtained make it possible to have a substantiated plan for the indicators of the flushing fluid and its chemical treatment. Results are presented of studies of argillaceous solutions chemically treated and untreated, as well as water and diesel fuel. Comparison of the findings with the technological indicators of the argillaceous solutions indicated that with an increase in viscosity of the solution and its content of clay powder, the rates of ice destruction diminish. It was established that with a rise in viscosity, there is also an intensification of the ice destruction rate, if the rise in viscosity is accompanied by increase in water-output of the flushing fluid. It is namely the water-output of the flushing fluid which is one of the universal indicators for the suitability of the flushing fluid for drilling under the examined conditions.

  17. Estudo da reologia e espessura do reboco de fluidos de perfuração: influência de dispersantes e umectante aniônicos Study of rheology and filter-cake thickness of drilling fluids: influence of anionic dispersants and surfactant

    Directory of Open Access Journals (Sweden)

    K. V. Farias

    2006-12-01

    Full Text Available Este trabalho teve como objetivo avaliar a influência de aditivos dispersantes e umectante aniônicos nas viscosidades aparente (VA e plástica (VP, no volume de filtrado (VF e na espessura do reboco (ER de fluidos de perfuração á base de água e argila bentonítica. Os fluidos foram preparados com 4,86% em massa de argila bentonítica e os aditivos estudados nas concentrações de 0,025 g a 0,300 g/24,3 g de argila seca para os dispersantes e de 0,005 g a 0,300 g/24,3 g de argila seca para o umectante aniônico. Os resultados mostraram que a espessura do reboco foi significativamente reduzida pela presença do umectante aniônico, sem, contudo, alterar as taxas de filtração dos fluidos estudados. Como era esperado, observou-se a redução nos valores de VA e VP após a aditivação dos fluidos com os aditivos dispersantes. Além disso, a mudança brusca nos valores de VA, VP e ER dos fluidos aditivados com o umectante aniônico na concentração de 0,100 g/24,3 g de argila seca evidenciou que esta é muito provavelmente a concentração micelar crítica deste aditivo.The aim of this work is to evaluate the influence of dispersants additives and anionic surfactants in the apparent viscosity (AV, plastic viscosity (PV, water loss (WL and filter-cake thickness (FT of the water based drilling fluids with bentonite clay. The fluids were prepared with 4.86 wt % of bentonite clay and the additives studied in the concentrations of 0.025 g to 0.300 g/24.3 g of dry clay for the dispersants and 0.005 g to 0.300 g/24.3 g of dry clay for the anionic surfactant. The results had shown the filter-cake thickness was significantly reduced by the presence of the anionic surfactant, without, however, to modify the taxes of filtration of studied fluids. As it was waited, it was observed the reduction in the values of AV and PV after treating the fluids with dispersants addictives. Also, the abrupt change in the values of AV, PV and FT of fluids treated with

  18. Comparative toxicity of various ozonized olefins to bacteria suspended in air

    Energy Technology Data Exchange (ETDEWEB)

    Dark, P A; Nash, T

    1970-01-01

    Air containing olefin vapor was treated with known amounts of ozone simulating natural concentrations. The bactericidal effect of the mixture was tested using microthreads sprayed with washed cultures of Escherichia coli var. communis or Micrococcus albus, aerosol strain. With 20 different olefins a wide range of activity was found, those in which the double bond formed part of a ring being the most bactericidal; gasoline vapor was about as active as the average open-chain olefin. The two organisms behaved similarly at the experimental relative humidity of 80%. The estimated amount of bactericidal substance present was only about one hundreth of that required to give the same kill with a 'conventional' air disinfectant; a simple physical explanation is proposed for this enhanced effect.

  19. A comprehensive study of olefin metathesis catalyzed by Ru-based catalysts

    KAUST Repository

    Poater, Albert

    2015-09-29

    During a Ru-catalyzed reaction of an olefin with an alkylidene moiety that leads to a metallacycle intermediate, the cis insertion of the olefin can occur from two different directions, namely side and bottom with respect to the phosphine or N-heterocyclic ligand (NHC), depending on the first or second generation Grubbs catalyst. Here, DFT calculations unravel to which extent the bottom coordination of olefins with respect is favored over the side coordination through screening a wide range of catalysts, including first and second generation Grubbs catalysts as well as the subsequent Hoveyda derivatives. The equilibrium between bottom and side coordination is influenced by sterics, electronics, and polarity of the solvent. The side attack is favored for sterically less demanding NHC and/or alkylidene ligands. Moreover the generation of a 14-electron species is also discussed, with either pyridine or phosphine ligands to dissociate.

  20. A comprehensive study of olefin metathesis catalyzed by Ru-based catalysts

    KAUST Repository

    Poater, Albert; Cavallo, Luigi

    2015-01-01

    During a Ru-catalyzed reaction of an olefin with an alkylidene moiety that leads to a metallacycle intermediate, the cis insertion of the olefin can occur from two different directions, namely side and bottom with respect to the phosphine or N-heterocyclic ligand (NHC), depending on the first or second generation Grubbs catalyst. Here, DFT calculations unravel to which extent the bottom coordination of olefins with respect is favored over the side coordination through screening a wide range of catalysts, including first and second generation Grubbs catalysts as well as the subsequent Hoveyda derivatives. The equilibrium between bottom and side coordination is influenced by sterics, electronics, and polarity of the solvent. The side attack is favored for sterically less demanding NHC and/or alkylidene ligands. Moreover the generation of a 14-electron species is also discussed, with either pyridine or phosphine ligands to dissociate.