WorldWideScience

Sample records for oil field waters

  1. Oil field produced water discharges into wetlands in Wyoming

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Approximately 600 oil field produced water discharges are permitted in Wyoming by the State’s Department of Environmental Quality's (WDEQ) National Pollutant...

  2. An objective estimation of impurities in oil field stagnant waters

    Energy Technology Data Exchange (ETDEWEB)

    Abashev, R.G.; Runets, S.A.

    1984-01-01

    Studies and an analysis of published materials are used to establish the predominant role of the mechanical impurities of various origins covered by layers of the heavy components of petroleum products in reducing the injectivity of injection wells for injecting stagnant waters containing concretions. A method is proposed for determining the impurities in the oil field stagnant waters used for flooding; this method makes it possible to obtain more reliable results on the concentration of the concretions responsible in such conditions for the drop in the injectivity of the formation reservoirs. A comparative evaluation of the results from an analysis of the impurities determined by the existing method and the proposed method is given. This method is useful in oil field laboratories in the systematic quality control over injected waters.

  3. Developing High Water-cut Oil Fields Deeply to Enhance Their Oil Recovery

    Institute of Scientific and Technical Information of China (English)

    Han Dakuang

    1994-01-01

    @@ There are 283 developed oil fields in China onshore area by the end of 1993. Most of them are in the later development stage with high water cut. The overall average water cut in these oilfields reaches 80.4%.Some old ones, such as Shengtuo, Gudao and Zhengdong,which have been put on production since 60's or 70's, have a water cut of higher than 90%and are in the extra high water-cut development stage. The recovery factors of these oilfields in terms of the recoverable reserves, which is 63.1%on average and even higher than 80% in some old fields, are also high. A lot of field data show that the distribution of oil and water in the reservoir exhibits new features differing from that in the earlier development stage. Because of the serious interlayer and intralayer heterogeneity of non--marine sandbodies both horizontally and vertically, and the complicated structural features due to the cross cutting of numerous faults, the distribution of the remaining oil in the case of such high recovery and high water cut is in a very dispersed state forming a very complex picture just like the stars in the sky. However some regularities and some relatively abundant regions still exist.

  4. The value of offshore field experiments in oil spill technology development for Norwegian waters.

    Science.gov (United States)

    Faksness, Liv-Guri; Brandvik, Per Johan; Daling, Per S; Singsaas, Ivar; Sørstrøm, Stein Erik

    2016-10-15

    The blowout on the Ekofisk field in the North Sea in 1977 initiated R&D efforts in Norway focusing on improving oil spill contingency in general and more specifically on weathering processes and modeling drift and spreading of oil spills. Since 1978, approximately 40 experimental oil spills have been performed under controlled conditions in open and ice covered waters in Norway. The importance of these experimental oil spills for understanding oil spill behavior, development of oil spill and response models, and response technologies are discussed here. The large progress within oil spill R&D in Norway since the Ekofisk blowout has been possible through a combination of laboratory testing, basin studies, and experimental oil spills. However, it is the authors' recommendation that experimental oil spills still play an important role as a final validation for the extensive R&D presently going on in Norway, e.g. deep-water releases of oil and gas.

  5. Clear well physical water treatment technology for the oil field

    Energy Technology Data Exchange (ETDEWEB)

    Troncoso y Troncoso, Joao Ricardo [Weatherford Brazil, Rio de Janeiro, RJ (Brazil); Rzeznik, Lawrence; Parker, Wiley L. [Weatherford International, Houston, TX (United States)

    2008-07-01

    Deposits of various types are common problems associated with oil and gas production. Deposits of scale, paraffin can block tubing, cause pumps to stick and clog valves and chokes. The expense and widespread occurrence of deposition problems have resulted in the development of a variety of treatment options which have been marginally successful at best. This paper discusses a new and novel approach for controlling scale, paraffin using an electronic physical water treating device and results that have been achieved. This physical water treatment technology has been applied to oil and gas production wells which incorporate all forms of product lift. Units are now also being installed in several South American locations. This paper will discuss the results obtained from the use of these physical water treatment devices and discuss the criteria which are used to ascertain whether a particular well site's problems can be eased by use of these devices. These criteria will be discussed for both land based and offshore oil wells. (author)

  6. Petroleum, oil field waters, and authigenic mineral assemblages - Are they in metastable equilibrium in hydrocarbon reservoirs?

    Science.gov (United States)

    Helgeson, Harold C.; Knox, Annette M.; Owens, Christine E.; Shock, Everett L.

    1993-07-01

    The hypothesis that although the presence of carboxylic acids and carboxylate anions in oil field waters is commonly attributed to the thermal maturation of kerogen or bacterial degradation of hydrocarbons during water-washing of petroleum in relatively shallow reservoirs, they may have also been produced in deeper reservoirs by the hydrolysis of hydrocarbons in petroleum at the oil-water interface is tested. Calculations were carried out to determine the distribution of species with the minimum Gibbs free energy in overpressured oil field waters in the Texas Gulf Coast assuming metastable equilibrium among calcite, albite, and a representative spectrum of organic and inorganic aqueous species at reservoir temperatures and pressures. The hypothesis that homogeneous equilibrium obtains among carboxylate and carbonate species in oil field waters is confirmed.

  7. Low-field NMR determinations of the properties of heavy oils and water-in-oil emulsions.

    Science.gov (United States)

    LaTorraca, G A; Dunn, K J; Webber, P R; Carlson, R M

    1998-01-01

    Low-field (magnetic resonance (NMR) well-logging measurements are beginning to be used to obtain estimates of oil viscosity in situ. To build an interpretive capability, we made laboratory T1 and T2 relaxation measurements on a suite of high-density, high-viscosity crude oils. These measurements were also used to estimate oil viscosity and water fraction from T1 and T2 measurements on stable, water-in-oil emulsions. High-density, high-viscosity oils have components that relax faster than can be measured by nuclear magnetic resonance logging tools. This requires corrections to T2 logging measurements for accurate estimates of oil saturation and porosity.

  8. Water management in Siri oil field in Iran: A comprehensive case study

    Energy Technology Data Exchange (ETDEWEB)

    Masoudi, Zahedzadeh M.; Abbasian, Ataei A.; Shokrollahzadeh, S.; Raadmehr, M.

    2006-03-15

    Successful water management and dealing with produced water is a crucial part of any oil and gas production scenarios. This paper investigates the role of comprehensive study in water management and produced water re-injection in an Iranian offshore oil field. Appropriate method can be chosen by taking into account various effective parameters such as reservoir properties, laboratory experiment, and learning from already done projects and etc. In this work, produced water reinjection in Siri oil field in Iran has been investigated by examining the effective parameters including reservoir characterization such as permeability, porosity, petrophysical properties as well as performing relevant laboratory experiments and reservoir parameters like aquifer support and carbonated rock reservoir issues. Finally, it was concluded that comprehensive study together with proper laboratory investigation has a significant effect in success of produced water re-injection process. (author) (tk)

  9. Short chain aliphatic acid anions in oil field waters and their contribution to the measured alkalinity

    Science.gov (United States)

    Willey, L.M.; Kharaka, Y.K.; Presser, T.S.; Rapp, J.B.; Barnes, I.

    1975-01-01

    High alkalinity values found in some formation waters from Kettleman North Dome oil field are due chiefly to acetate and propionate ions, with some contribution from higher molecular weight organic acid ions. Some of these waters contain no detectable bicarbonate alkalinity. For waters such as these, high supersaturation with respect to calcite will be incorrectly indicated by thermodynamic calculations based upon carbonate concentrations inferred from traditional alkalinity measurements. ?? 1975.

  10. Quantitative calculation of GOR of complex oil-gas-water systems with logging data: A case study of the Yingdong Oil/Gas Field in the Qaidam Basin

    OpenAIRE

    2014-01-01

    In the Yingdong Oil/Gas Field of the Qaidam Basin, multiple suites of oil-gas-water systems overlie each other vertically, making it difficult to accurately identify oil layers from gas layers and calculate gas-oil ratio (GOR). Therefore, formation testing and production data, together with conventional logging, NMR and mud logging data were integrated to quantitatively calculate GOR. To tell oil layers from gas layers, conventional logging makes use of the excavation effect of compensated ne...

  11. Simulation of phase separation with large component ratio for oil-in-water emulsion in ultrasound field.

    Science.gov (United States)

    Wang, Heping; Li, Xiaoguang; Li, Yanggui; Geng, Xingguo

    2017-05-01

    This paper presents an exploration for separation of oil-in-water and coalescence of oil droplets in ultrasound field via lattice Boltzmann method. Simulations were conducted by the ultrasound traveling and standing waves to enhance oil separation and trap oil droplets. The focus was to the effect of ultrasound irradiation on oil-in-water emulsion properties in the standing wave field, such as oil drop radius, morphology and growth kinetics of phase separation. Ultrasound fields were applied to irradiate the oil-in-water emulsion for getting flocculation of the oil droplets in 420kHz case, and larger dispersed oil droplets and continuous phases in 2MHz and 10MHz cases, respectively. The separated phases started to rise along the direction of sound propagation after several periods. The rising rate of the flocks was significantly greater in ultrasound case than that of oil droplets in the original emulsion, indicating that ultrasound irradiation caused a rapid increase of oil droplet quantity in the progress of the separation. The separation degree was also significantly improved with increasing frequency or irradiation time. The dataset was rearranged for growth kinetics of ultrasonic phase separation in a plot by spherically averaged structure factor and the ratio of oil and emulsion phases. The analyses recovered the two different temporal regimes: the spinodal decomposition and domain growth stages, which further quantified the morphology results. These numerical results provide guidance for setting the optimum condition for the separation of oil-in-water emulsion in the ultrasound field.

  12. Computational Flow Dynamic Simulation of Micro Flow Field Characteristics Drainage Device Used in the Process of Oil-Water Separation

    Directory of Open Access Journals (Sweden)

    Guangya Jin

    2017-01-01

    Full Text Available Aqueous crude oil often contains large amounts of produced water and heavy sediment, which seriously threats the safety of crude oil storage and transportation. Therefore, the proper design of crude oil tank drainage device is prerequisite for efficient purification of aqueous crude oil. In this work, the composition and physicochemical properties of crude oil samples were tested under the actual conditions encountered. Based on these data, an appropriate crude oil tank drainage device was developed using the principle of floating ball and multiphase flow. In addition, the flow field characteristics in the device were simulated and the contours and streamtraces of velocity magnitude at different nine moments were obtained. Meanwhile, the improvement of flow field characteristics after the addition of grids in crude oil tank drainage device was validated. These findings provide insights into the development of effective selection methods and serve as important references for oil-water separation process.

  13. Biological treatment process for removing petroleum hydrocarbons from oil field produced waters

    Energy Technology Data Exchange (ETDEWEB)

    Tellez, G.; Khandan, N.

    1995-12-31

    The feasibility of removing petroleum hydrocarbons from oil fields produced waters using biological treatment was evaluated under laboratory and field conditions. Based on previous laboratory studies, a field-scale prototype system was designed and operated over a period of four months. Two different sources of produced waters were tested in this field study under various continuous flow rates ranging from 375 1/D to 1,800 1/D. One source of produced water was an open storage pit; the other, a closed storage tank. The TDS concentrations of these sources exceeded 50,000 mg/l; total n-alkanes exceeded 100 mg/l; total petroleum hydrocarbons exceeded 125 mg/l; and total BTEX exceeded 3 mg/l. Removals of total n-alkanes, total petroleum hydrocarbons, and BTEX remained consistently high over 99%. During these tests, the energy costs averaged $0.20/bbl at 12 bbl/D.

  14. Water-in-oil emulsification in a non-uniform alternating electric field

    Science.gov (United States)

    Choi, Suhwan; Saveliev, Alexei

    2015-11-01

    The emulsification of a water microdroplet placed in castor oil was performed using a non-uniform alternating electric field formed in the pin-to-plate geometry. A non-uniform electric field of ~40 kV/mm alternating with a frequency of 6.7 kHz was generated near the pin electrode. The applied frequency exceeded charge relaxation frequency of castor oil (0.3 Hz) and was below charge relaxation frequency of deionized water (7.8 kHz) used in the experiments. The emulsification process was captured with a CCD camera. The emulsification process started with entrainment of the water droplet in the high electric filed region near the pin electrode under the dielectrophoretic force. Upon touching the pin, the microdroplet was disintegrated in numerous channels and secondary droplets. The process continued by entrainment of secondary droplets and continuous size reduction. Three droplet breakup mechanisms were identified: drop elongation and capillary breakup, ac electrospraying of individual droplets, chain and bridge formation and decay. The quasi-steady narrow size distribution of emulsified water droplets with diameters close to 1 μm was formed after a few minutes. The generated emulsion was confined near the needle electrode due to the dielectrophoretic force. The emulsion had a well-defined boundary with a shape resembling a pendant drop suspended on the pin electrode.

  15. Water scaling in the North Sea oil and gas fields and scale prediction: An overview

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, M.

    1996-12-31

    Water-scaling is a common and major production chemistry problem in the North Sea oil and gas fields and scale prediction has been an important means to assess the potential and extent of scale deposition. This paper presents an overview of sulphate and carbonate scaling problems in the North Sea and a review of several widely used and commercially available scale prediction software. In the paper, the water chemistries and scale types and severities are discussed relative of the geographical distribution of the fields in the North Sea. The theories behind scale prediction are then briefly described. Five scale or geochemical models are presented and various definitions of saturation index are compared and correlated. Views are the expressed on how to predict scale precipitation under some extreme conditions such as that encountered in HPHT reservoirs. 15 refs., 7 figs., 9 tabs.

  16. Inactivation of Bacteria in Oil Field Injected Water by a Pulsed Plasma Discharge Process

    Science.gov (United States)

    Xin, Qing; Li, Zhongjian; Lei, Lecheng; Yang, Bin

    2016-09-01

    Pulsed plasma discharge was employed to inactivate bacteria in the injection water for an oil field. The effects of water conductivity and initial concentration of bacteria on elimination efficiency were investigated in the batch and continuous flow modes. It was demonstrated that Fe2+ contained in injection water could enhance the elimination efficiency greatly. The addition of reducing agent glutathione (GSH) indicated that active radicals generated by pulsed plasma discharges played an important role in the inactivation of bacteria. Moreover, it was found that the microbial inactivation process for both batch and continuous flow mode well fitted the model based on the Weibull's survival function. supported by Zhejiang Province Welfare Technology Applied Research Project of China (No. 2014C31137), National Natural Science Foundation of China (Nos. 21436007 and U1462201), and the Fundamental Research Funds for the Central Universities of China (No. 2015QNA4032)

  17. Effect of injecting cold water on oil-output of the beds of the Uzen' field

    Energy Technology Data Exchange (ETDEWEB)

    Borisov, Yu.P.; Kil' dibekova, L.I.; Rozenberg, M.D.; Safronov, S.V.; Teslyuk, Ye.V.

    1979-01-01

    At the Uzen' field, 254 million m/sup 3/ of cold water were injected into the oil area with average temperature 15-16/sup 0/C. This resulted in cooling of the rock-collectors on the order of 538.4 million m/sup 3/ and decrease in oil output by 9.4% as compared to injection of only hot water.

  18. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery - Mattoon Oil Field, Illinois. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, M. [American Oil Recovery, Inc., Decatur, IL (United States)

    1995-09-01

    Phase I results of a C0{sub 2}-assisted oil recovery demonstration project in selected Cypress Sandstone reservoirs at Mattoon Field, Illinois are reported. The design and scope of this project included C0{sub 2} injectvity testing in the Pinnell and Sawyer units, well stimulaton treatments with C0{sub 2} in the Strong unit and infill well drilling, completion and oil production. The field activities were supported by extensive C0{sub 2}-oil-water coreflood experiments, CO{sub 2} oil-phase interaction experiments, and integrated geologic modeling and reservoir simulations. The progress of the project was made public through presentations at an industry meeting and a DOEs contractors` symposium, through quarterly reports and one-to-one consultations with interested operators. Phase II of this project was not implemented. It would have been a water-alternating-gas (WAG) project of longer duration.

  19. Tilting oil-water contact in the chalk of Tyra Field as interpreted from capillary pressure data

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Rana, M.A.

    2010-01-01

    -trends from logs were compared with normalized water saturation depth-trends predicted from capillary pressure core data. The ten wells lie close to a SW–NE cross section of the field. For the gas–oil contact, a free contact measured in one well corresponds to a practically horizontal contact interpreted from......The Tyra Field in the central North Sea is located in Palaeogene and Upper Cretaceous chalk. It contains a natural gas zone underlain by an oil leg. Based on analysis of logs and core data from ten wells drilled prior to the field being put into production, normalized water saturation depth...... logging data in the remaining wells. A westerly dipping oil–water contact was found from logging data. Comparison of the depth-wise trends in normalized water saturation among the different wells indicates a regional pattern: in the western side of the field, the trends correspond to a situation...

  20. Redistribution of mobile surface charges of an oil droplet in water in applied electric field.

    Science.gov (United States)

    Li, Mengqi; Li, Dongqing

    2016-10-01

    Most researches on oil droplets immersed in aqueous solutions assume that the surface charges of oil droplets are, similar to that of solid particles, immobile and distributed uniformly under external electric field. However, the surface charges at the liquid-liquid interface are mobile and will redistribute under external electric field. This paper studies the redistribution of surface charges on an oil droplet under the influence of the external electrical field. Analytical expressions of the local zeta potential on the surface of an oil droplet after the charge redistribution in a uniform electrical field were derived. The effects of the initial zeta potential, droplet radius and strength of applied electric field on the surface charge redistribution were studied. In analogy to the mobile surface charges, the redistribution of Al2O3-passivated aluminum nanoparticles on the oil droplet surface was observed under applied electrical field. Experimental results showed that these nanoparticles moved and accumulated towards one side of the oil droplet under electric field. The redistribution of the nanoparticles is in qualitative agreement with the redistribution model of the mobile surface charges developed in this work.

  1. Enhanced oil recovery - nitrogen. Large fractures, water drive make Andector field a prime target

    Energy Technology Data Exchange (ETDEWEB)

    Wash, R.

    1982-03-01

    An immiscible nitrogen displacement project is expected to recover 973,928 bbl of tertiary oil from the Andector (Ellenburger) field in NW Ector County, Texas. Operated by Phillips Petroleum Co., the project began November 30, 1981, on the 1293-acre Embar lease in the south fault block of the Andector field, the highest of all Ellenburger fields in W. Texas in terms of cumulative production. (Total production as of January 1, 1981 was 151.2 million bbl). The nitrogen technique was chosen by Phillips due to the type of rock and the active water drive in this area. The aquifer is shared by several other Ellenburger fields in a 3-county area. The formation of interest is a highly fractured, vulgar, medium-to-fine-grained crystalline dolomite, fairly typical for the Ellenburger in W. Texas. It occurs between 7782 ft and 8835 ft. Overall porosity is 3.8%. Permeability is in the 2000-md range. At least 40% of the porosity is in solution cavities or vugs. The way in which nitrogen is used in the Ellenburger is discussed, along with the advantages and disadvantages of its use.

  2. Experimental and computational studies of water drops falling through model oil with surfactant and subjected to an electric field

    CERN Document Server

    Ervik, Åsmund; Munkejord, Svend Tollak; Müller, Bernhard

    2014-01-01

    The behaviour of a single sub-millimetre-size water drop falling through a viscous oil while subjected to an electric field is of fundamental importance to industrial applications such as crude oil electrocoalescers. Detailed studies, both experimental and computational, have been performed previously, but an often challenging issue has been the characterization of the fluids. As numerous authors have noted, it is very difficult to have a perfectly clean water-oil system even for very pure model oils, and the presence of trace chemicals may significantly alter the interface behaviour. In this work, we consider a well- characterized water-oil system where controlled amounts of a surface active agent (Span 80) have been added to the oil. This addition dominates any trace contaminants in the oil, such that the interface behaviour can also be well-characterized. We present the results of experiments and corresponding two-phase- flow simulations of a falling water drop covered in surfactant and subjected to a mono...

  3. Quantitative calculation of GOR of complex oil-gas-water systems with logging data: A case study of the Yingdong Oil/Gas Field in the Qaidam Basin

    Directory of Open Access Journals (Sweden)

    Sima Liqiang

    2014-12-01

    Full Text Available In the Yingdong Oil/Gas Field of the Qaidam Basin, multiple suites of oil-gas-water systems overlie each other vertically, making it difficult to accurately identify oil layers from gas layers and calculate gas-oil ratio (GOR. Therefore, formation testing and production data, together with conventional logging, NMR and mud logging data were integrated to quantitatively calculate GOR. To tell oil layers from gas layers, conventional logging makes use of the excavation effect of compensated neutron log, NMR makes use of the different relaxation mechanisms of light oil and natural gas in large pores, while mud logging makes use of star chart of gas components established based on available charts and mathematical statistics. In terms of the quantitative calculation of GOR, the area ratio of the star chart of gas components was first used in GOR calculation. The study shows that: (1 conventional logging data has a modest performance in distinguishing oil layers from gas layers due to the impacts of formation pressure, hydrogen index (HI, shale content, borehole conditions and invasion of drilling mud; (2 NMR is quite effective in telling oil layers from gas layers, but cannot be widely used due to its high cost; (3 by contrast, the star chart of gas components is the most effective in differentiating oil layers from gas layers; and (4 the GOR calculated by using the area ratio of star chart has been verified by various data such as formation testing data, production data and liquid production profile.

  4. Chemical comparison and acute toxicity of water accommodated fraction (WAF) of source and field collected Macondo oils from the Deepwater Horizon spill.

    Science.gov (United States)

    Faksness, Liv-Guri; Altin, Dag; Nordtug, Trond; Daling, Per S; Hansen, Bjørn Henrik

    2015-02-15

    Two Source oils and five field collected oil residues from the Deepwater Horizon incident were chemically characterized. Water accommodated fractions (WAFs) of the Source oils and two of the field-weathered oils were prepared to evaluate the impact of natural weathering on the chemical composition and the acute toxicity of the WAFs. Toxicity test species representing different tropic levels were used (the primary producer Skeletonema costatum (algae) and the herbivorous copepod Acartia tonsa). The results suggest that the potential for acute toxicity is higher in WAFs from non-weathered oils than WAFs from the field weathered oils. The Source oils contained a large fraction of soluble and bioavailable components (such as BTEX (benzene, toluene, ethyl benzene, xylenes) and naphthalene), whereas in the surface collected oils these components were depleted by dissolution into the water column as the oil rose to the surface and by evaporative loss after reaching the sea surface.

  5. Field induced anomalous spreading, oscillation, ejection, spinning, and breaking of oil droplets on a strongly slipping water surface.

    Science.gov (United States)

    Kumar, Sunny; Sarma, Bhaskarjyoti; Dasmahapatra, Ahsok Kumar; Dalal, Amaresh; Basu, Dipankar Narayan; Bandyopadhyay, Dipankar

    2017-07-01

    Application of an electric field on an oil droplet floating on the surface of a deionized water bath showed interesting motions such as spreading, oscillation, and ejection. The electric field was generated by connecting a pointed platinum cathode at the top of the oil droplet and a copper anode coated with polymer at the bottom of the water layer. The experimental setup mimicked a conventional electrowetting setup with the exception that the oil was spread on a soft and deformable water isolator. While at relatively lower field intensities we observed spreading of the droplet, at intermediate field intensities the droplet oscillated around the platinum cathode, before ejecting out at a speed as high as ∼5 body lengths per second at even stronger field intensities. The experiments suggested that when the electric field was ramped up abruptly to a particular voltage, any of the spreading, oscillation, or ejection motions of the droplet could be engendered at lower, intermediate and higher field intensities, respectively. However, when the field was ramped up progressively by increasing by a definite amount of voltage per unit time, all three aforementioned motions could be generated simultaneously with the increase in the field intensity. Interestingly, when the aforementioned setup was placed on a magnet, the droplet showed a rotational motion under the influence of the Lorentz force, which was generated because of the coupling of the weak leakage current with the externally applied magnetic field. The spreading, oscillation, ejection, and rotation of the droplet were found to be functions of the oil-water interfacial tension, viscosity, and size of the oil droplet. We developed simple theoretical models to explain the experimental results obtained. Importantly, rotating at a higher speed broke the droplet into a number of smaller ones, owing to the combined influence of the spreading due to the centripetal force and the shear at the oil-water interface. While

  6. Bioflocculant Produced by Klebsiella sp. MYC and Its Application in the Treatment of Oil-field Produced Water

    Institute of Scientific and Technical Information of China (English)

    YUE Lixi; MA Chunling; CHI Zhenming

    2006-01-01

    Seventy-nine strains of bioflocculant-producing bacteria were isolated from 3 activated sludge samples. Among them, strain MYC was found to have the highest and stable flocculating rate for both kaolin clay suspension and oil-field produced water. The bacterial strain was identified as Klebsiella sp. MYC according to its morphological and biochemical characteristics and 16SrDNA sequence. The optimal medium for bioflocculant production by this bacterial strain was composed of cane sugar 20gL 1, KH2PO4 2gL-1, K2HPO4 5gL-1, (NH4)2SO4 0.2gL-1, urea 0.5gL-1 and yeast extract 0.5gL 1, the initial pH being 5.5. When the suspension of kaolin clay was treated with0.5% of Klebsiella sp. MYC culture broth, the flocculating rate reached more than 90.0 % in the presence of 500 mg L-1 CaCl2, while the flocculating rate for oil-field produced water was near 80.0% in a pH range of 7.0 - 9.0 with the separation of oil and suspended particles from the oil-field produced water under similar conditions. The environm ent-friendly nature of the bioflocculant and high flocculating rate of the strain make the bioflocculant produced by Klebsiella sp. MYC an attractive bioflocculant in oil-field produced water treatment.

  7. Paleo-oil-Water Contact and Present-Day Gas-Water Contact:Implication for Evolution History of Puguang Gas Field,Sichuan Basin,China

    Institute of Scientific and Technical Information of China (English)

    Li Pingping; Zou Huayao; Zhang Yuanchun; Wang Cunwu; Zhang Xuefeng

    2008-01-01

    The Puguang (普光) gas field is the largest gas field found in marine carbonate in China.The Puguang gas field experienced complicated evolution history from paleo-oil pool to gas pool.The purpose of this article is to reveal the evolution history of Puguang gas field through systematic study on the relationship between paleo-oil-water contact (POWC) and present-day gas-water contact (PGWC).POWC was recognized by observing the change of relative content of residual solid bitumen in the cores,and PGWC was observed using log and drilling stem test data.Two types of relationship between POWC and PGWC were observed in the Puguang gas field:POWC is above PGWC,and POWC is below PGWC.The former is normal as oil cracking may cause gas-water contact to move downward.The latter can be interpreted by lateral gas re-migration and re-accumulation caused by changes in structural configuration.The relationship between POWC and PGWC suggests that during oil charge,the southwestern and northwestern parts of the Puguang gas field were structurally lower than the northeastern and southeastern parts.Thrusting from Xuefengshan (雪峰山) since Yanshanian movement and from Dabashan (大巴山) since Himalayan movement resulted in the relative uplift of the southwestern and northwestern parts of the Puguang structure,which significantly changed the structural configuration.Based on the paleo-structure discussed in this article,the most probable migration directions of paleo-oil were from the northwest to the southeast and from the southwest to the northeast.Consequently,the evolution history of the Puguang gas field can be divided into three stages,namely,oil charging (200-170 Ma),cracking oil to gas (155-120 Ma),and gas pool adjustment (1200-0Ma).

  8. Abandoned Texas oil fields

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  9. Effects of Operating Pressure on Energy-saving of Water Recycling Utilization with MVR system in Oil Extraction Fields

    OpenAIRE

    Li, Liansheng; Zhao, Yuanyang; Wang, Le; Xiao, Jun; Yang, Qichao; Liu, Guangbin; Tang, Bin

    2015-01-01

    One of the most effective methods for the extraction of crude oil with high viscosity is injecting high temperature water vapor to the oil well. To save water consumption and achieve zero discharge, it is needed to separate and purify the water, which is mixed with oil, mud and other impurities. In this paper, the mechanical vapor recompression (MVR) system is analyzed and the parameters for analysis are based on a demonstration project on water recycling utilization in the Karamay crude oil ...

  10. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  11. Aerobic biodegradation process of petroleum and pathway of main compounds in water flooding well of Dagang oil field.

    Science.gov (United States)

    Cai, Minmin; Yao, Jun; Yang, Huaijun; Wang, Ruixia; Masakorala, Kanaji

    2013-09-01

    Aerobic biodegradation of crude oil and its pathways were investigated via in vitro culture and GC-MS analysis in water flooding wells of Dagang oil field. The in vitro aerobic culture lasted 90 days when 99.0% of n-alkanes and 43.03-99.9% of PAHs were degraded and the biomarkers and their ratios were changed. The spectra of components in the residual oil showed the similar biodegradation between aerobic process of 90 days and degradation in reservoir which may last for some millions years, and the potential of serious aerobic biodegradation of petroleum in reservoir. 24 Metabolites compounds were separated and identified from aerobic culture, including fatty acid, naphthenic acid, aromatic carboxylic acid, unsaturated acid, alcohols, ketones and aldehydes. The pathways of alkanes and aromatics were proposed, which suggests that oxidation of hydrocarbon to organic acid is an important process in the aerobic biodegradation of petroleum. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Panorama of PetroChina Jidong Oil Field Company

    Institute of Scientific and Technical Information of China (English)

    XiaoLu

    2003-01-01

    As the old oil fields in East China are currently facing more and more pressure to keep their crude oil production stable in the past few years owing to the high water cut, PetroChina Jidong Oil Field has become a rising star in the country's oil and gas exploration and production sector. Jidong Oil Field

  13. Dynamic Variation of Land-use Types of the Constructed Wetland before and after Oil-field Water Irrigation Based on 3S Technology

    Institute of Scientific and Technical Information of China (English)

    CHEN; Ming-hui; ZHANG; Chen; HU; Yan; SU; Wei; DONG; De-ming

    2012-01-01

    [Objective] The study aimed at analyzing the dynamic variation of land-use types of the constructed wetland before and after oil-field water irrigation based on 3S technology. [Method] At semi-arid and arid areas in the west of Jilin Province, water resource balance between the amount of oil-field water supply and ecological water requirement in the constructed wetland irrigated by oil-field water during 2001-2010 was investigated firstly. Afterwards, based on 3S technology, the partition and dynamic variation of land-use types of the constructed wetland before and after oil-field water irrigation in 2001, 2006, 2008 and 2010 were analyzed. [Result] The annual ecological water requirement of the constructed wetland from 2003 to 2010 varied from 1.62×106 to 2.24×106 m3, and the annual amount of oil-field water supply in the region changed from 2.12×106 to 2.84×106 m3, which showed that the supply amount of oil-field water could meet the basic ecological water requirement of the constructed wetland. Meanwhile, compared with 2001, the areas of water region and paddy field in 2010 increased by 2.3 and 10.0 times, and the areas of forest and marsh rose by 40.15% and 29.5.0% respectively. [Conclusion] Water shortage and ecological environment problem of arid and semi-arid areas had been improved by oil-field water irrigation.

  14. Oil-material fractionation in Gulf deep water horizontal intrusion layer: Field data analysis with chemodynamic fate model for Macondo 252 oil spill.

    Science.gov (United States)

    Melvin, A T; Thibodeaux, L J; Parsons, A R; Overton, E; Valsaraj, K T; Nandakumar, K

    2016-04-15

    Among the discoveries of the Deepwater Horizon blowout was the so-called "sub-surface plume"; herein termed the "oil-trapping layer". Hydrocarbons were found positioned at ~1100-1300m with thickness ~100-150m and moving horizontally to the SW in a vertically stratified layer at the junction of the cold abyssal water and the permanent thermocline. This study focuses on its formation process and fate of the hydrocarbons within. The originality of this work to the field is two-fold, first it provides a conceptual framework which places layer origin in the context of a horizontal "intrusion" from the near-field, vertical, blow-out plume and second, it offers a theoretical model for the hydrocarbon chemicals within the horizontal layer as it moves far-afield. The model quantifies the oil-material fractionation process for the soluble and fine particle. The classical Box model, retrofitted with an internal gradient, the "G-Box", allows an approach that includes turbulent eddy diffusion coupled with droplet rise velocity and reactive decay to produce a simple, explicit, transparent, algebraic model with few parameters for the fate of the individual fractions. Computations show the soluble and smallest liquid droplets moving very slowly vertically through the layer appearing within the trapping layer at low concentration with high persistence. The larger droplets move-through this trapping zone quickly, attain high concentrations, and eventually form the sea surface slick. It impacts the field of oil spill engineering science by providing the conceptual idea and the algorithms for projecting the quantities and fractions of oil-material in a deep water, horizontal marine current being dispersed and moving far afield. In the field of oil spill modeling this work extends the current generation near-field plume source models to the far-field. The theory portrays the layer as an efficient oil-material trap. The model-forecasted concentration profiles for alkanes and aromatics

  15. Physicochemical methods for enhancing oil recovery from oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Altunina, L K; Kuvshinov, V A [Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, Tomsk (Russian Federation)

    2007-10-31

    Physicochemical methods for enhancing oil recovery from oil fields that are developed using water flooding and thermal steam treatment are considered. The results of pilot testing of processes based on these methods carried out at West Siberian and Chinese oil fields are analysed. The attention is focused on the processes that make use of surfactant blends and alkaline buffer solutions and thermotropic gel-forming systems.

  16. Physicochemical methods for enhancing oil recovery from oil fields

    Science.gov (United States)

    Altunina, L. K.; Kuvshinov, V. A.

    2007-10-01

    Physicochemical methods for enhancing oil recovery from oil fields that are developed using water flooding and thermal steam treatment are considered. The results of pilot testing of processes based on these methods carried out at West Siberian and Chinese oil fields are analysed. The attention is focused on the processes that make use of surfactant blends and alkaline buffer solutions and thermotropic gel-forming systems.

  17. Oil palm water use: calibration of a sap flux method and a field measurement scheme.

    Science.gov (United States)

    Niu, Furong; Röll, Alexander; Hardanto, Afik; Meijide, Ana; Köhler, Michael; Hendrayanto; Hölscher, Dirk

    2015-05-01

    Oil palm (Elaeis guineensis Jacq.) water use was assessed by sap flux density measurements with the aim to establish the method and derive water-use characteristics. Thermal dissipation probes were inserted into leaf petioles of mature oil palms. In the laboratory, we tested our set-up against gravimetric measurements and derived new parameters for the original calibration equation that are specific to oil palm petioles. In the lowlands of Jambi, Indonesia, in a 12-year-old monoculture plantation, 56 leaves on 10 palms were equipped with one sensor per leaf. A 10-fold variation in individual leaf water use among leaves was observed, but we did not find significant correlations to the variables trunk height and diameter, leaf azimuthal orientation, leaf inclination or estimated horizontal leaf shading. We thus took an un-stratified approach to determine an appropriate sampling design to estimate stand transpiration (Es, mm day(-1)) rates of oil palm. We used the relative standard error of the mean (SEn, %) as a measure for the potential estimation error of Es associated with sample size. It was 14% for a sample size of 13 leaves to determine the average leaf water use and four palms to determine the average number of leaves per palm. Increasing these sample sizes only led to minor further decreases of the SEn of Es. The observed 90-day average of Es was 1.1 mm day(-1) (error margin ± 0.2 mm day(-1)), which seems relatively low, but does not contradict Penman-Monteith-derived estimates of evapotranspiration. Examining the environmental drivers of Es on an intra-daily scale indicates an early, pre-noon maximum of Es rates (11 am) due to a very sensitive reaction of Es to increasing vapor pressure deficit in the morning. This early peak is followed by a steady decline of Es rates for the rest of the day, despite further rising levels of vapor pressure deficit and radiation; this results in pronounced hysteresis, particularly between Es and vapor pressure deficit.

  18. Oil field chemicals synergistic effects on the corrosion rate of L-80 steel in sea and formation waters

    Energy Technology Data Exchange (ETDEWEB)

    Al Hashem, A.; Carew, J. [Petroleum Research and Studies Center, Kuwait Institute for Scientific Research, P.O. Box 24885, 13109 Safat Kuwait (Kuwait); Al-Borno, A. [Charter Coating Service (2000) Ltd., no 6, 4604, 13 Street N.E., Calgary, AB T2E 6P1 (Canada)

    2004-07-01

    The corrosion rate of tubular grade L-80 carbon steel under downhole conditions of a northern oil field of Kuwait was investigated. This was done using the injection seawater, formation water and a 50:50 mixture of both waters in the presence of commercially available corrosion inhibitor, scale inhibitor, and biocide products separately and in combination with each other. The main objective of this study was to investigate the effect of the corrosion inhibitor and its interaction with the scale inhibitor and the biocide, as seen in the corrosion rate of L80 carbon steel. This was done using the manufacturers' recommended dosage levels of the corrosion inhibitor, scale inhibitor and biocide. The corrosion rates were measured by linear polarization. Tests were conducted using the rotating cylinder electrode method with rotational speeds of 1000 and 2000 rpm at 80 deg. C. The seawater results indicated that the corrosion-scale inhibitor and biocide-scale inhibitor combinations provided the best protection at both rotation speeds. In formation water, the effects of rotation speed were more apparent with higher corrosion rates of L-80 carbon steel accompanying higher shear forces. In the 50: 50 mix waters and the formation water, the corrosion-scale inhibitors-biocide combination provided the best protection at both rotational speeds under downhole conditions of a northern oil field of Kuwait. (authors)

  19. Optimization of Field Development Scheduling, East Unity Oil Field, Sudan

    Directory of Open Access Journals (Sweden)

    Tagwa A. Musa

    2005-01-01

    Full Text Available In order to improve the reservoir performance in East Unity oil field Sudan, the studies focused on characterization, modeling and simulation of the actual performance and future development. A model was constructed using a three-phase, three dimensional, black oil simulator (ECLIPSE. In this study a data from East Unity oil field Sudan started production at July 1999 was used to perform the optimal oil rate and designing the best location of the new operating wells. Cumulative oil production, oil production rate, Water cut and recovery factor were used as key criteria to see if adding new wells in the area under study are economic risk.

  20. Developing High Water-cut Oil Fields Deeply to Enhance Their Oil Recovery(Continued from page 14 in the third issure)

    Institute of Scientific and Technical Information of China (English)

    Han Dakuang

    1994-01-01

    @@ Development of new EOR techniques with tertiary production as a main technique As stated above, the ultimate recovery of conventional oil in our country is estimated to be 33.6%, i.e., about 66.4% of the oil reserves cannot be recovered by water injection and may only be targeted for tertiary oil recovery or for other types of new technologies.

  1. Water saturation on Albian carbonates reservoirs—ancient Brazilian oil fields

    Science.gov (United States)

    Castillo Vincentelli, Maria Gabriela; António Caceres Contreras, Sergio

    2016-12-01

    One of the main objectives for petroleum exploration is to quantify the reservoir’s oil in place; usually this process is based on a petrophysical evaluation that, among other parameters, the reservoir water saturation (S w) must be calculated, because it represents the main factor for determining hydrocarbon saturation (S h). Classical petrophysical analysis includes the use of the water saturation’s resistivity (R w) and two main constants (for Archie saturation), as well as cementation (m) and tortuosity (a); both of which are obtained from laboratory plug/cores measurements. However, in the case of ancient Albian carbonate reservoirs (Brazil), this kind of data is not available for a fully water saturated reservoir, and as a consequence, we proposed to apply a logarithmic graphic solution of the main Archie’s equations to determine these main factors using a linear regression based on wire logs. As result, an R w was confirmed at 127 Kppm of NaCl for Quissamã Formation, m  =  1.071 and a  =  0.87. Finally, the value of ‘m’ is more affected by the pore and size configuration, and the ‘a’ value appears to be a logical answer for carbonates reservoir with high porosity.

  2. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery: Mattoon Oil Field, Illinois. Third quarterly report, [July--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, M.R.

    1993-12-21

    The objectives of this project are to continue reservoir characterization of the Cypress Sandstone; to identify and map facies-defined waterflood units (FDWS); and to design and implement water-alternating-gas (WAG) oil recovery utilizing carbon dioxide (CO{sub 2}) The producibility problems are permeability variation and poor sweep efficiency. Part 1 of the project focuses on the development of computer-generated geological and reservoir simulation models that will be used to select sites for the demonstration and implementation of CO{sub 2} displacement programs in Part 2. Included in Part 1 is the site selection and drilling of an infill well, coring of the Cypress interval, and injectivity testing to gather information used to update the reservoir simulation model. Part 2 involves field implementation of WAG. Technology Transfer includes outreach activity such as seminars, workshops, and field trips.

  3. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery: Mattoon Oil Field, Illinois. Fourth quarterly report, [October 1, 1993--December 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, M.

    1994-01-25

    The objectives of this project are to continue reservoir characterization of the Cypress Sandstone; to identify and map fades-defined waterflood units (FDWS); and to design and Implement water-alternating-gas (WAG) oil recovery utilizing carbon dioxide (CO{sub 2}). The producibility problems are permeability variation and poor sweep efficiency. Phase 1 of the project focuses on the development of computer-generated geological and reservoir simulation models that will be used to select sites for the demonstration and implementation of CO{sub 2} displacement programs in Phase 2. Included in Phase 1 is the site selection and drilling of an infill well, coring of the Cypress interval, and injectivity testing to gather information used to update the reservoir simulation model. Phase 2 involves field implementation of WAG. Technology Transfer includes outreach activity such as seminars, workshops, and field trips. Technical progress for this quarter is described.

  4. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery: Mattoon Oil Field, Illinois. [Quarterly report], January--March 1994

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, M.R.

    1994-04-30

    The objectives of this project are to continue reservoir characterization of the Cypress Sandstone; to identify and map facies-defined waterflood units (FDWS); and to design and implement water-alternating-gas (WAG) oil recovery utilizing carbon dioxide (CO{sub 2}). The producibility problems are permeability variation and poor sweep efficiency. Phase 1 of the project focuses on the development of computer-generated geological and reservoir simulation models that will be used to select sites for the demonstration and implementation of CO{sub 2} displacement programs in Phase 2. Included in Phase 1 is the site selection and drilling of an infill well, coring of the Cypress internal and injectivity testing to gather information used to update the reservoir simulation model. Phase 2 involves field implementation of WAG. Technology Transfer includes outreach activity such as seminars, workshops, and field trips. Accomplishments for the past quarter are described.

  5. Seasonal variations of microbial community in a full scale oil field produced water treatment plant

    Directory of Open Access Journals (Sweden)

    Q. Xie

    2016-01-01

    Full Text Available This study investigated the microbial community in a full scale anaerobic baffled reactor and sequencing batch reactor system for oil-produced water treatment in summer and winter. The community structures of fungi and bacteria were analyzed through polymerase chain reaction–denaturing gradient gel electrophoresis and Illumina high-throughput sequencing, respectively. Chemical oxygen demand effluent concentration achieved lower than 50 mg/L level after the system in both summer and winter, however, chemical oxygen demand removal rates after anaerobic baffled reactor treatment system were significant higher in summer than that in winter, which conformed to the microbial community diversity. Saccharomycotina, Fusarium, and Aspergillus were detected in both anaerobic baffled reactor and sequencing batch reactor during summer and winter. The fungal communities in anaerobic baffled reactor and sequencing batch reactor were shaped by seasons and treatment units, while there was no correlation between abundance of fungi and chemical oxygen demand removal rates. Compared to summer, the total amount of the dominant hydrocarbon degrading bacteria decreased by 10.2% in anaerobic baffled reactor, resulting in only around 23% of chemical oxygen demand was removed in winter. Although microbial community significantly varied in the three parallel sulfide reducing bacteria, the performance of these bioreactors had no significant difference between summer and winter.

  6. Separate Layer Production and Water Injection Technology Developed in Daqing Oil Field

    Institute of Scientific and Technical Information of China (English)

    Liu He

    2004-01-01

    @@ Effects of separate layer production and water injection With the improvement of geological research and development degree, the requirements to water injection are also higher than ever before. The development of water injection technology in Daqing oilfield experienced the following four stages: (1) Commingled water injection, (2)concentric water injection, (3) eccentric water injection, and (4) integrated water injection.Through the above improvements, the development technology improved quickly.

  7. Estimation of VOC emissions from produced-water treatment ponds in Uintah Basin oil and gas field using modeling techniques

    Science.gov (United States)

    Tran, H.; Mansfield, M. L.; Lyman, S. N.; O'Neil, T.; Jones, C. P.

    2015-12-01

    Emissions from produced-water treatment ponds are poorly characterized sources in oil and gas emission inventories that play a critical role in studying elevated winter ozone events in the Uintah Basin, Utah, U.S. Information gaps include un-quantified amounts and compositions of gases emitted from these facilities. The emitted gases are often known as volatile organic compounds (VOCs) which, beside nitrogen oxides (NOX), are major precursors for ozone formation in the near-surface layer. Field measurement campaigns using the flux-chamber technique have been performed to measure VOC emissions from a limited number of produced water ponds in the Uintah Basin of eastern Utah. Although the flux chamber provides accurate measurements at the point of sampling, it covers just a limited area of the ponds and is prone to altering environmental conditions (e.g., temperature, pressure). This fact raises the need to validate flux chamber measurements. In this study, we apply an inverse-dispersion modeling technique with evacuated canister sampling to validate the flux-chamber measurements. This modeling technique applies an initial and arbitrary emission rate to estimate pollutant concentrations at pre-defined receptors, and adjusts the emission rate until the estimated pollutant concentrations approximates measured concentrations at the receptors. The derived emission rates are then compared with flux-chamber measurements and differences are analyzed. Additionally, we investigate the applicability of the WATER9 wastewater emission model for the estimation of VOC emissions from produced-water ponds in the Uintah Basin. WATER9 estimates the emission of each gas based on properties of the gas, its concentration in the waste water, and the characteristics of the influent and treatment units. Results of VOC emission estimations using inverse-dispersion and WATER9 modeling techniques will be reported.

  8. Increase in extractable oil reserves through injection of steam and hot water in the Kelebiya Yug oil field

    Energy Technology Data Exchange (ETDEWEB)

    Gobos, Z.; Csizmazia, P.; Kuhn, T.; Voll, L.

    1984-01-01

    A plan is described for injecting steam and hot water, its method, technology of working, surface technological equipment and an analysis is made of the economicalness of the process from the viewpoint of the national economy.

  9. Tarim Oil Field Company Oil Output Exceeds 5 Million Tons

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    PetroChina Tarim Oil Field Company (Tarim Oil Field), located in the hinterland of Takelamagan Desert in Northwest Xinjiang Autonomous Region,produced 5.006 million tons of crude oil in 2002,ranking it as the sixth largest onshore oil field in China. This is the first time Tarim Oil Field has topped 5 million tons for its crude production.

  10. A road damage and life-cycle greenhouse gas comparison of trucking and pipeline water delivery systems for hydraulically fractured oil and gas field development in Colorado.

    Science.gov (United States)

    Duthu, Ray C; Bradley, Thomas H

    2017-01-01

    The process of hydraulic fracturing for recovery of oil and natural gas uses large amounts of fresh water and produces a comparable amount of wastewater, much of which is typically transported by truck. Truck transport of water is an expensive and energy-intensive process with significant external costs including roads damages, and pollution. The integrated development plan (IDP) is the industry nomenclature for an integrated oil and gas infrastructure system incorporating pipeline-based transport of water and wastewater, centralized water treatment, and high rates of wastewater recycling. These IDP have been proposed as an alternative to truck transport systems so as to mitigate many of the economic and environmental problems associated with natural gas production, but the economic and environmental performance of these systems have not been analyzed to date. This study presents a quantification of lifecycle greenhouse gas (GHG) emissions and road damages of a generic oil and gas field, and of an oil and gas development sited in the Denver-Julesburg basin in the northern Colorado region of the US. Results demonstrate that a reduction in economic and environmental externalities can be derived from the development of these IDP-based pipeline water transportation systems. IDPs have marginal utility in reducing GHG emissions and road damage when they are used to replace in-field water transport, but can reduce GHG emissions and road damage by factors of as much as 6 and 7 respectively, when used to replace fresh water transport and waste-disposal routes for exemplar Northern Colorado oil and gas fields.

  11. Characteristics of operation and possible oil recovery from the sixth formation of Arlansk oil field. [USSR

    Energy Technology Data Exchange (ETDEWEB)

    Viktorov, P.F.; Teterev, I.G.

    1970-01-01

    This field is characterized by complex geological variations, high viscosity oil (16 to 39 cp), and extreme heterogeneity. The field has been under a peripheral waterflood for 10 yr, however even at high water-cut (50 to 75%), only 40% of the reserve has been recovered. The high water-cut results from premature water breakthrough in high-permeability zones and from water coning. As cumulative oil recovery increases, water production increases exponentially. Oil recovery can be increased only 3 to 4%, by increasing the removal of fluids from wells. Consideration is being given to use of hot water and high-pressure gas to increase oil recovery.

  12. Methods for collection and analysis of geopressured geothermal and oil field waters

    Science.gov (United States)

    Lico, Michael S.; Kharaka, Yousif K.; Carothers, William W.; Wright, Victoria A.

    1982-01-01

    Present methods are described for the collection, preservation, and chemical analysis of waters produced from geopressured geothermal and petroleum wells. Detailed procedures for collection include precautions and equipment necessary to ensure that the sample is representative of the water produced. Procedures for sample preservation include filtration, acidification, dilution for silica, methyl isobutyl ketone (MIBK) extraction of aluminum, addition of potassium permanganate to preserve mercury, and precipitation of carbonate species as strontium carbonate for stable carbon isotopes and total dissolved carbonate analysis. Characteristics determined at the well site are sulfide, pH, ammonia, and conductivity. Laboratory procedures are given for the analysis of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium, iron, manganese, zinc, lead, aluminum, .and mercury by atomic absorption and flame emission spectroscopy. Chloride is determined by silver nitrate titration and fluoride by ion-specific electrode. Bromide and iodide concentrations are determined by the hypochlorite oxidation method. Sulfate is analyzed by titration using barium chloride with thorin indicator after pretreatment with alumina. Boron and silica are determined colorimetrically by the carmine and molybdate-blue methods, respectively. Aliphatic acid anions (C2 through C5) are determined by gas chromatography after separation and concentration in a chloroform-butanol mixture.

  13. Oil and gas field database

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young In; Han, Jung Kuy [Korea Institute of Geology Mining and Materials, Taejon (Korea)

    1998-12-01

    As agreed by the Second Meeting of the Expert Group of Minerals and Energy Exploration and Development in Seoul, Korea, 'The Construction of Database on the Oil and Gas Fields in the APEC Region' is now under way as a GEMEED database project for 1998. This project is supported by Korean government funds and the cooperation of GEMEED colleagues and experts. During this year, we have constructed the home page menu (topics) and added the data items on the oil and gas field. These items include name of field, discovery year, depth, the number of wells, average production (b/d), cumulative production, and API gravity. The web site shows the total number of oil and gas fields in the APEC region is 47,201. The number of oil and gas fields by member economics are shown in the table. World oil and gas statistics including reserve, production consumption, and trade information were added to the database for the users convenience. (author). 13 refs., tabs., figs.

  14. The influence of strong electric fields on the DC conductivity of the composite cellulose, insulating oil, and water nanoparticles

    Science.gov (United States)

    Kierczyński, Konrad; Żukowski, Paweł

    2016-12-01

    The paper presents investigated the dependencies of DC conductivity electrical pressboard impregnated insolating oil of moisture content and electric field strength. The studies were conducted for measuring temperature in the range of 20 °C to 80 °C and the electric field intensity in the range of 10 kV/m to 1000 kV/m. With approximate waveforms in double logarithmic coordinates conductivity depending on the intensity of the electric field exponential function determined coefficients of determination R2. The value of this ratio is close to unity, which provides high accuracy measurements of conductivity and the exact stability and temperature measurements. It was found that changes in the electric field intensity will decrease the activation energy of conductivity of about 0.01 eV, thus increasing the DC conductivity of about 1.5 times.

  15. Methanogenic Oil Degradation in the Dagang Oil Field

    Science.gov (United States)

    Jiménez, Núria; Cai, Minmin; Straaten, Nontje; Yao, Jun; Richnow, Hans Hermann; Krüger, Martin

    2014-05-01

    Anaerobic biodegradation is one of the main in situ oil transformation processes in subsurface oil reservoirs. Recent studies have provided evidence of biodegradation of residual oil constituents under methanogenic conditions. Methane, like other biogenic gases, may contribute to reduce the viscosity of oil and enhance its flow characteristics (making it more available) but it can also be used as a energy source. So the aim of the present study was to provide reliable information on in situ biotransformation of oil under methanogenic conditions, and to assess the feasibility of implementing a MEOR strategy at this site. For this reason, chemical and isotopic analyses of injection and production fluids of the Dagang oil field (Hebei province, China) were performed. Microbial abundances were assessed by qPCR, and clone libraries were performed to study the diversity. In addition, microcosms with either oil or 13C-labelled hydrocarbons were inoculated with injection or production waters to characterize microbial processes in vitro. Geochemical and isotopic data were consistent with in situ biogenic methane production linked to aliphatic and aromatic hydrocarbon degradation: GC-MS profiles of petroleum samples were nearly devoid of n-alkanes, linear alkylbenzenes, and alkyltoluenes, and light PAH, confirming that Dagang oil is mostly highly weathered. In addition, carbon and hydrogen isotopic signatures of methane (δ13CCH4 and δDCH4, respectively), and the bulk isotopic discrimination (Δδ13C) between methane and CO2 (between 32 and 65 ) were in accordance with previously reported values for methane formation during hydrocarbon degradation. Furthermore, methane-producing Archaea and hydrocarbon-degrading Bacteria were abundant in produced oil-water samples. On the other hand, our laboratory degradation experiments revealed that autochthonous microbiota are capable of significantly degrade oil within several months, with biodegradation patterns resembling those

  16. State and prospects of using equipment for simultaneous-separate production of oil and separate injection of water in the Uzen Field

    Energy Technology Data Exchange (ETDEWEB)

    Orzhanov, T.K.; Teslyuk, E.V.; Dyusenbaev, I.D.

    1967-08-01

    The Uzen Field consists of several producing strata spaced closely together. The most economical way of developing this field is to use multiple completions in both oil-producing and in water-injection wells. In this way the hydrodynamic characteristics of each formation can be harnessed for maximum economic gain. The authors describe and show in schematic drawings several basic multiple completion arrangements. The basic element in each arrangement is a packer, which isolates one stratum from another. The basic operating principle of each multiple completion shown in this article appears to follow conventional principles.

  17. Comparative study of using Water-Based mud containing Multiwall Carbon Nanotubes versus Oil-Based mud in HPHT fields

    Directory of Open Access Journals (Sweden)

    M.I. Abduo

    2016-12-01

    Full Text Available Water-Based mud (WBM and Oil-Based mud (OBM are the most common drilling fluids currently used and both have several characteristics that qualify them for High Pressure High Temperature (HPHT purposes. This paper compares the different characteristics of WBM containing Multiwall Carbon Nanotubes (MWCNTs and OBM to help decide the most suitable mud type for HPHT drilling by considering mud properties through several laboratory tests to generate some engineering guidelines. The tests were formulated at temperatures from 120 °F up to 500 °F and pressures from 14.7 psi to 25,000 psi. The comparison will mainly consider the rheological properties of the two mud types and will also take into account the environmental feasibility of using them. The results showing that the Water-Based offers a more environmental friendly choice yet some of additives that are used to enhance its performance at (HPHT conditions, such as (MWCNTs, thus it is necessary to develop new formulas for (HPHT Water-Based muds that could act like Oil-Based mud but cause less harm to the environment.

  18. Progress of Corrosion Inhibitor for Oil Field Injection Water%油气田注水缓蚀剂研究进展

    Institute of Scientific and Technical Information of China (English)

    杨鹏辉; 张宇翔; 任香梅; 李霆; 杨江

    2014-01-01

    油气田注水缓蚀剂主要以有机吸附膜型缓蚀剂为主,介绍了油气田注水常用的吸附膜型缓蚀剂及其在油气田中的应用和研究进展,对咪唑啉类缓蚀剂的应用做了重点阐述,指出了吸附膜型缓蚀剂的发展方向。%The current state and progress of film -forming corrosion inhibitor for oil -gas field injection water was described.Research on the development of imidazoline corrosion inhibitor in oil -gas field was highlighted.Developing direction of corrosion inhibitor was pointed out.

  19. Application of 'BIPI' tests employing natural and artificial tracers in water flooded oil fields of the Neuquina Basin (Argentine)

    Energy Technology Data Exchange (ETDEWEB)

    Somaruga, C. [Comahue Univ., Engineering Dept., Neuquen (Argentina); Gazzera, C.; Wouterlood, C. [Petrolera Perez Companc SA. Area Entre Lomas., Neuquen (Argentina)

    2001-07-01

    A methodology to determine the origin and distribution of bottom water in an oil producing well influenced by several injectors in waterflooding projects is presented. This methodology is complementary of inter-well tracer tests and salinity records analysis and was denominated BIPI (brief interruptions of producing-injecting wells) test. It requires the closing of a well (injector or producer) during a short time and its later re-opening. The original flow pattern in the surroundings of the tested producing well is affected while the well is closed. So the water coming from a dominant injector can move forward invading areas of a layer that have been previously occupied by other waters. Once the well is re-opened, if there is a tracer concentration contrast between the waters, a concentration change is registered. The concentration change was measured and also its recurrence in waters produced during inter-well tracer tests and during waterflooding that are employing different injection water from the formation one. Also it was determined the original flow distribution in the surrounding of the producing well by means of a simple balance of tracer mass. It is presented and analyze here the results from tests that were performed in an oil field of the Neuquina Basin. They allowed to visualizing the current condition of the bottom water flow as well as to make predictions on future performance. (authors)

  20. Separation kinetics of an oil-in-water emulsion under enhanced gravity

    NARCIS (Netherlands)

    Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

    2012-01-01

    The breakup of crude oil emulsions to produce clean oil and water phases is an important task in crude oil processing. We have investigated the demulsification kinetics of a model oil-in-water emulsion in a centrifugal field to mimic the forces acting on emulsion droplets in oil/water separators

  1. Molecular- and cultivation-based analyses of microbial communities in oil field water and in microcosms amended with nitrate to control H{sub 2}S production

    Energy Technology Data Exchange (ETDEWEB)

    Kumaraswamy, Raji; Ebert, Sara; Fedorak, Phillip M.; Foght, Julia M. [Alberta Univ., Edmonton, AB (Canada). Biological Sciences; Gray, Murray R. [Alberta Univ., Edmonton, AB (Canada). Chemical and Materials Engineering

    2011-03-15

    Nitrate injection into oil fields is an alternative to biocide addition for controlling sulfide production ('souring') caused by sulfate-reducing bacteria (SRB). This study examined the suitability of several cultivation-dependent and cultivation-independent methods to assess potential microbial activities (sulfidogenesis and nitrate reduction) and the impact of nitrate amendment on oil field microbiota. Microcosms containing produced waters from two Western Canadian oil fields exhibited sulfidogenesis that was inhibited by nitrate amendment. Most probable number (MPN) and fluorescent in situ hybridization (FISH) analyses of uncultivated produced waters showed low cell numbers ({<=}10{sup 3} MPN/ml) dominated by SRB (>95% relative abundance). MPN analysis also detected nitrate-reducing sulfide-oxidizing bacteria (NRSOB) and heterotrophic nitrate-reducing bacteria (HNRB) at numbers too low to be detected by FISH or denaturing gradient gel electrophoresis (DGGE). In microcosms containing produced water fortified with sulfate, near-stoichiometric concentrations of sulfide were produced. FISH analyses of the microcosms after 55 days of incubation revealed that Gammaproteobacteria increased from undetectable levels to 5-20% abundance, resulting in a decreased proportion of Deltaproteobacteria (50-60% abundance). DGGE analysis confirmed the presence of Delta- and Gammaproteobacteria and also detected Bacteroidetes. When sulfate-fortified produced waters were amended with nitrate, sulfidogenesis was inhibited and Deltaproteobacteria decreased to levels undetectable by FISH, with a concomitant increase in Gammaproteobacteria from below detection to 50-60% abundance. DGGE analysis of these microcosms yielded sequences of Gamma- and Epsilonproteobacteria related to presumptive HNRB and NRSOB (Halomonas, Marinobacterium, Marinobacter, Pseudomonas and Arcobacter), thus supporting chemical data indicating that nitrate-reducing bacteria out-compete SRB when nitrate is

  2. 热水洗法处理油田油泥技术的研究%Treatment of Oily Sludge in Oil Field With Hot Water Washing

    Institute of Scientific and Technical Information of China (English)

    赵阳; 戴跃玲; 李晓鸥; 李东胜; 秦永航

    2011-01-01

    采用热水洗法,对辽河油田油泥进行净化处理.通过筛选、对比,确定最佳实验助剂,分别考察了浆化液中助剂质量分数、液固比、浆化时间、温度、搅拌速度等实验条件对油的回收率的影响.通过实验确定最佳操作条件,当助剂质量分数为4%、清洗时间为25 min、清洗温度为60℃、液固比为4:1、搅拌速度在200 r/min的情况下处理一次油泥,油的回收率可达94.29%左右;浆化液可循环使用,分离出来的原油经处理后可回收利用.%The Oil Sludge of Liaohe oil field was cleaned and treated by hot water. The optimum reagent was selected by comparison, and the effect of experimental conditions (including the concentration of reagent, mass ratio of liquid to soil,stirring rate, slurry time and temperature) on oil yield were studied; and the best experimental conditions are obtained as follows: reagent concentration 4%, slurry time 25 min, slurry temperature 60 ℃, mass ratio of liquid to soil 4: 1 and stirring rate 200 r/min. Under these conditions, Oil yield can reach 94.29 % after treating oil sludge once. The slurry solution can be recycled; the crude oil separated can be recycled after treatment.

  3. Produced water management - clean and safe oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  4. Modeling and Analysis of Magnetic Nanoparticles Injection in Water-Oil Two-Phase Flow in Porous Media under Magnetic Field Effect

    KAUST Repository

    El-Amin, Mohamed

    2017-08-28

    In this paper, the magnetic nanoparticles are injected into a water-oil, two-phase system under the influence of an external permanent magnetic field. We lay down the mathematical model and provide a set of numerical exercises of hypothetical cases to show how an external magnetic field can influence the transport of nanoparticles in the proposed two-phase system in porous media. We treat the water-nanoparticles suspension as a miscible mixture, whereas it is immiscible with the oil phase. The magnetization properties, the density, and the viscosity of the ferrofluids are obtained based on mixture theory relationships. In the mathematical model, the phase pressure contains additional term to account for the extra pressures due to fluid magnetization effect and the magnetostrictive effect. As a proof of concept, the proposed model is applied on a countercurrent imbibition flow system in which both the displacing and the displaced fluids move in opposite directions. Physical variables, including waternanoparticles suspension saturation, nanoparticles concentration, and pore wall/throat concentrations of deposited nanoparticles, are investigated under the influence of the magnetic field. Two different locations of the magnet are studied numerically, and variations in permeability and porosity are considered.

  5. Offshore conversion of associated gas to synthetic crude oil: An economic option for deep water and marginal fields

    Energy Technology Data Exchange (ETDEWEB)

    Antia, D.D.J.; Seddon, D.

    1995-12-31

    A low cost modular Fischer Tropsch gas conversion approach which can add value to associated gas in both deep water and marginal fields is described. The process is suitable for location on vessels (FPSO`s), jackups, platforms and semisubmersibles. It can economically convert >1 to >200 MMCF/D to syncrude. The modules can be used to: Strip value from gas prior to injection; Remove a reinjection or flaring requirement; Reduce carbon dioxide emissions from the field. Conversion ratios depend on the catalyst and process configuration used. They range from 70-->170 Bbls/MMCF.

  6. Oil dehydration using hydrodynamic effects and electrical fields

    Energy Technology Data Exchange (ETDEWEB)

    Skipin, V.S.; Cherepnin, V.V.; Didenko, V.I.

    1980-01-01

    This article examines the influence of hydrodynamic effects and electrical fields upon the water content of commercial oil. It is demonstrated that increasing the period of contact of the emulsion with a reagent and a unit for emulsive perturbation and reagent transfer, leads to a dosage reduction with a resulting high-quality of oil.

  7. Determination of levels of naturally occurring radioactive materials in lagoon samples containing produced water from the Minagish oil field in the state of Kuwait

    Science.gov (United States)

    Shams, H. M.; Bradley, D. A.; Regan, P. H.

    2017-08-01

    An evaluation of the activity concentration (Ac) associated with naturally occurring radioactive materials has been undertaken as part of a systematic study to provide a radiological map of the ground materials from a produced wastewater lagoon located in the Minagish oil field in the south west of the State of Kuwait. This lagoon contains material from the discharge of produced water which is a by-product of oil production in the region. Samples of surface materials have been collected, prepared and placed into sealed, Marinelli beakers for a full gamma-ray spectrometric analysis using a high-resolution, low-background, high-purity germanium detection system. This short conference paper presents a summary of results for an initial selection of sixteen surface samples from the edges of the Minagish oil lagoon which have been analysed to obtain Ac values for members of the 226Ra (214Bi and 214Pb) and 232Th (228Ac, 212Pb and 208Tl) decay chains and for 40K. These are compared with other studies for the same geographical region.

  8. Chinese Oil Giants Eye Canadian Oil Fields

    Institute of Scientific and Technical Information of China (English)

    Miao Bin

    2005-01-01

    @@ SinoCanada, a subsidiary of Sinopec International Petroleum Exploration and Development Corporation, and Canada-based Synenco Energy Inc announced on May 31 that they have inked a series of agreements to launch a joint venture for common development of the oil sand project located in Athabasca region of Northeast Canada's Alberta Province. Based on the agreements, Sinopec will pay 105 million Canadian dollars (US$84 million) for a stake in Canada's Northern Lights oil sands project while Synenco owns the remaining 60 percent share,and will operate the project as the managing partner.

  9. Evolution of the Moxizhuang Oil Field, Central Junggar Basin, Northwest China

    Institute of Scientific and Technical Information of China (English)

    Zou Huayao; Zhang Yuanchun; Liu Jianzhang; Shi Jiannan

    2008-01-01

    Current oil saturation in the Moxizhuang (莫西庄) Oil Field in central Janggar (准噶尔) basin was evaluated by logging interpretation and measured on core samples, and the paleo-oil saturation in both the pay zones and water zones was investigated by graln-containing-oil inclusion (GOI) analysis.The pay zones in this field have low oil saturation and display low resistivity and small contrast between pay zones and water zones, and are classified as low-porosity, low oil saturation, and low resistivity reservoirs. Both the current low oil-saturation pay zones and the water zones above 4 365 m have high GOI values (up to 38%), suggesting high paleo-oil saturation. The significant difference between current oil saturation from both logging interpretation and core sample measurement and paleo-oil saturation indicated by GOI analysis suggests that this low oil-saturation field evolved from a high oil-saturation pool. Lateral re-migration and spill of formally trapped oil owing to changes in structural configuration since Neogene was the most plausible mechanism for oil loss in the Moxizhuang Oil Field.The combined effects of differential accumulation in the charge phase and the differential re-migration and spill of accumulated oil in Neogene are responsible for the complicated correlation between residual oil saturation and porosity/permeability of the reservoir sandstones and the distribution of low oil-saturation pay zones and paleo-oil zones (current water zones).

  10. Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions.

    Directory of Open Access Journals (Sweden)

    Ryan A Ortega

    Full Text Available Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric.

  11. Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions

    Science.gov (United States)

    Carter, Erin S.; Ortega, Albert E.

    2016-01-01

    Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric. PMID:27411088

  12. Research on Dispersed Oil Droplets Breakage and Emulsification in the Dynamic Oil and Water Hydrocyclone

    Directory of Open Access Journals (Sweden)

    Guangdong Guo

    2013-08-01

    Full Text Available Oil and water dynamic hydrocyclone is one type of facilities that separate two phases or multiple phases applied widely in the fields such as food processing, environmental protection, biological pharmacy, petroleum and chemistry. The dispersed oil droplets in the dynamic oil and water hydrocyclone were often broken into small drops by shear force, which decreased the separation efficiency of dynamic oil-water hydrocyclone greatly. To avoid the breakage of the oil droplets, the turbulence field and the velocity field of the dynamic hydrocyclone were studied by the software of Fluent to analyze the main reason that led to breakage of oil droplets. Results indicated that the deformation of oil droplets was caused by the viscous shear force; the breakage of oil droplets was caused by the Reynolds shear stress and the local pressure fluctuations. The main area that the drops were prone to breakup of the dynamic hydrocyclone is that the rotating grating nearby, the wall boundary layer of the drum and center axis of the drum. Finally, the breakage of oil droplets and emulsification of oil and water in the dynamic hydrocyclone were verified by the experiments.

  13. Oil and Gas Field Locations, Geographic NAD83, LDNR (2007) [oil_gas_fields_LDNR_2007

    Data.gov (United States)

    Louisiana Geographic Information Center — This GIS layer consists of oil and gas field approximate center point locations (approximately 1,800). Oil and gas fields not assigned a center point by the DNR...

  14. Understanding the Impact of Open-Framework Conglomerates on Water-Oil Displacements: Victor Interval of the Ivishak Reservoir, Prudhoe Bay Field, Alaska

    CERN Document Server

    Gershenzon, Naum I; Ritzi, Robert W; Dominic, David F

    2014-01-01

    The Victor Unit of the Ivishak Formation in the Prudhoe Bay Oilfield is characterized by high net-to-gross fluvial sandstones and conglomerates. The highest permeability is found within sets of cross-strata of open-framework conglomerate (OFC). They are preserved within unit bar deposits and assemblages of unit bar deposits within compound (braid) bar deposits. They are thief zones limiting enhanced oil recovery. We incorporate recent research that has quantified important attributes of their sedimentary architecture within preserved deposits. We use high-resolution models to demonstrate the fundamental aspects of their control on oil production rate, water breakthrough time, and spatial and temporal distribution of residual oil saturation. We found that when the pressure gradient is oriented perpendicular to the paleoflow direction, the total oil production and the water breakthrough time are larger, and remaining oil saturation is smaller, than when it is oriented parallel to paleoflow. The pressure differe...

  15. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    mechanisms. The ion specific interaction between fines and polar fractions of crude oil at the oil-water interface has been less explored. In this study the relative affinity between different ions and the oil surface was determined. The experiments prove the importance of Ca2+, SO42-, and HPO42- ions...... emulsion formation at 0.05 mol/1. The amount of emulsion formation showed significant dependency on the type of acid doped in oil. Experiments demonstrate that the brine solution can alter the micro forces at the oil-water interface, and this ion specific interaction leads to oil emulsion formation......The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed...

  16. Development of a centrifugal in-line separator for oil-water flows

    NARCIS (Netherlands)

    Slot, J.J.

    2013-01-01

    The world energy consumption will increase in the next decades. However, many aging oil fields are showing a steady decline in oil production. And they are producing increasing amounts of water, making the separation of the oil from the oil-water mixture an important processing step. In-line separa

  17. Oil flow in deep waters: comparative study between light oils and heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Andreolli, Ivanilto [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2009-12-19

    Ultra deeper waters fields are being exploited due to technological development. Under this scenario, the flow design is accomplished through pipelines subjected to low temperature and high pressure. Moreover, these flow lines are usually long causing a fast fluid cooling, which may affect flow assurance in some cases. Problems during topsides production plant's restart might occur if the oil is viscous and even in steady state a significant different behavior can be noticed, if compared to a less viscous oil. A comparison between light and heavy oil through a case study with the objective to show some heavy oil flow particularities is the purpose of this paper. Permanent and transient analyses for a specific geometry are presented. The results showed that thermal and proper viscosity modeling are required for heavy oil flow, differently from that of light oil flow, due to the exponential viscosity dependence to temperature and because the predominant laminar regime. In addition, on heavier and heavier oil flow systems, it is essential to consider exportation system's restart. (author)

  18. Microbial consortia in Oman oil fields: a possible use in enhanced oil recovery.

    Science.gov (United States)

    Al-Bahry, Saif N; Elshafie, Abdulkader E; Al-Wahaibi, Yahya M; Al-Bemani, Ali S; Joshi, Sanket J; Al-Maaini, Ratiba A; Al-Alawi, Wafa J; Sugai, Yuichi; Al-Mandhari, Mussalam

    2013-01-01

    Microbial enhanced oil recovery (MEOR) is one of the most economical and efficient methods for extending the life of production wells in a declining reservoir. Microbial consortia from Wafra oil wells and Suwaihat production water, Al-Wusta region, Oman were screened. Microbial consortia in brine samples were identified using denaturing gradient gel electrophoresis and 16S rRNA gene sequences. The detected microbial consortia of Wafra oil wells were completely different from microbial consortia of Suwaihat formation water. A total of 33 genera and 58 species were identified in Wafra oil wells and Suwaihat production water. All of the identified microbial genera were first reported in Oman, with Caminicella sporogenes for the first time reported from oil fields. Most of the identified microorganisms were found to be anaerobic, thermophilic, and halophilic, and produced biogases, biosolvants, and biosurfactants as by-products, which may be good candidates for MEOR.

  19. Identification of water-soluble heavy crude oil organic-acids, bases, and neutrals by electrospray ionization and field desorption ionization fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Stanford, Lateefah A; Kim, Sunghwan; Klein, Geoffrey C; Smith, Donald F; Rodgers, Ryan P; Marshall, Alan G

    2007-04-15

    We identify water-soluble (23 degrees C) crude oil NSO nonvolatile acidic, basic, and neutral crude oil hydrocarbons by negative-ion ESI and continuous flow FD FT-ICR MS at an average mass resolving power, m/deltam50% = 550,000. Of the 7000+ singly charged acidic species identified in South American crude oil, surprisingly, many are water-soluble, and much more so in pure water than in seawater. The truncated m/z distributions for water-soluble components exhibit preferential molecular weight, size, and heteroatom class influences on hydrocarbon solubility. Acidic water-soluble heteroatomic classes detected at >1% relative abundance include O, O2, O3, O4, OS, O2S, O3S, O4S, NO2, NO3, and NO4. Parent oil class abundance does not directly relate to abundance in the water-soluble fraction. Acidic oxygen-containing classes are most prevalent in the water-solubles, whereas acidic nitrogen-containing species are least soluble. In contrast to acidic nitrogen-containing heteroatomic classes, basic nitrogen classes are water-soluble. Water-soluble heteroatomic basic classes detected at >1% relative abundance include N, NO, NO2, NS, NS2, NOS, NO2S, N2, N2O, N2O2, OS, O2S, and O2S2.

  20. Combustion of Coal/Oil/Water Slurries

    Science.gov (United States)

    Kushida, R. O.

    1982-01-01

    Proposed test setup would measure combustion performance of new fuels by rapidly heating a droplet of coal/oil/water mixture and recording resulting explosion. Such mixtures are being considered as petroleum substitutes in oil-fired furnaces.

  1. Microbial response to nitrate treatment in offshore oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Boedtker, Gunhild

    2009-07-01

    North Sea oil reservoirs are often injected with deaerated sea water in order to enhance oil recovery. The high sulphate content of sea water combined with the anoxic conditions stimulates growth of sulphate-reducing bacteria (SRB) in the water injection system and the reservoir. SRB produce the highly toxic and corrosive gas hydrogen sulphide (HZS) during anaerobic respiration with sulphate. Accumulation of HZS leads to corrosion and reservoir souring, which may result in reduced gas quality, separation problems and increased maintenance costs. Biocides have traditionally been used to prevent SRB activity in North Sea oil fields. During the last decade, however, the environmentally sound method of nitrate treatment has replaced biocides on several fields. The method is based on shifting the microbial activity from sulphate reduction to nitrate reduction by introducing nitrate as an alternative electron acceptor for anaerobic respiration. Results presented in the current thesis show that nitrate treatment has resulted in long-term inhibition of SRB activity and a reduction in corrosion of up to 40% in sea water injection systems at the Veslefrikk and Gullfaks oil fields. Molecular analysis (PCR-DGGE) of pipeline biofilm from Veslefrikk showed that sulphide-oxidizing nitrate-reducing bacteria (NR-SOB) constituted the major metabolic group during nitrate treatment, and that the bacterial community composition remained stable during years. Reduction in sulphide produced from the Gullfaks field showed that nitrate treatment was effective also at reservoir level. Analysis of back flowed injection water from a nitrate-treated Statfjord reservoir showed that heterotrophic nitrate-reducing bacteria (hNRB) constituted the major metabolic group, and that the in situ HZS level was 10 fold lower than experienced during biocides treatment and 100 fold lower than experienced during produced water reinjection (PWRI). At the Norne oil field oxic sea water is injected along with

  2. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery -- Mattoon Oil Field, Illinois. First quarterly technical progress report, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, M.R.

    1993-05-24

    For work during the first quarter of 1993, American Oil Recovery, Inc. targeted completion of the following specific objectives: Convene meetings of Mattoon Project subcontractors in order to plan and coordinate Project activities. Confirm organizational arrangements and plans for implementation of Mattoon Project. Complete most work on detailed analysis of reservoir geology of productive leases in the Mattoon Project. Identify first Facies Defined Subunit for initial injectivity testing to be commenced near the beginning of the second quarter. Identify additional Facies Defined Subunits for injectivity testing and characterization during the second and third quarters. Award subcontract to the Illinois State Geological Survey and commence work on preparation of a geostatistical model (STRATAMODEL) of more than 100 wells on 1,000 acres within the Mattoon Project Area. Obtain oil samples from wells in the identified Facies Subunit for reservoir rock, fluid, and CO{sub 2} compatibility testing by the Illinois State Geological Survey. Design CO{sub 2} injection pumps and injection monitoring equipment configuration. Obtain bids for required pumps and diesel motor. Accomplishments for this quarter are reported.

  3. Field study of heavy oil viscosity reduction for production transport

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, J.; Annichiariccom, G.; Montanez, M. [Ecopetrol S.A. (Venezuela); Faust, M.; Weathers, T. [Nalco Energy Services (Colombia); Parra, R. [Nalco de Colombia Ltda. (Colombia)

    2011-07-01

    In the heavy oil industry, production and transportation are expensive processes requiring complex equipment and procedures. The main issue with heavy crude oil is its high viscosity. A method using naphtha injection was developed to dilute the fluids and aid in water separation, but this method is expensive and raises safety issues. To reduce naphtha consumption, Ecopetrol and Nalco Energy Services developed a new dispersion technology. This paper presents this technology and the results of its field trial in the Chichimene oil field. Key production indicators were monitored to determine how effective the emulsion method was in enhancing production. Results showed no negative effect on the separation facility or oil and water quality while reducing by 75% the injection of diluent. This paper presents a dispersion technology which successfully reduced the need for naphtha and thus reduced production costs.

  4. Preliminary results of field mapping of methane plumes offshore of Coal Oil Point, California with a RESON 7125 multibeam sonar in water-column mode

    Science.gov (United States)

    Finlayson, D. P.; Hatcher, G.; Lorenson, T. D.; Greinert, J.; Maillard, E.; Weirathmueller, M.; Leifer, I.

    2010-12-01

    From June 17 - 23 2010, the U. S. Geological Survey (USGS) in collaboration with the Bureau of Ocean Energy Management Regulation and Enforcement(BOEMRE), the Royal Netherlands Institute for Sea Research (NIOZ) , RESON Inc. and the University of California, Santa Barbara(UCSB) conducted a comprehensive marine-seep gas-plume mapping study offshore of Coal Oil Point, California. The ultimate goal of the experiment is to quantify the amount of methane emitted from natural seeps using multibeam sonar, with results calibrated using field measurements of aqueous and atmospheric methane in the seep fields. Success will lead to better estimates of natural marine methane contributions to the global methane budget. We mapped selected seeps, some twice, with a pole-mounted RESON 7125 multibeam with a 10-degree forward rake. Other equipment included a Benthos Stingray ROV equipped with high-definition video cameras and in situ gas sampling apparatus, Niskin bottles for water column sampling of dissolved methane, and a Picarro G1301 cavity ringdown spectrometer for mapping atmospheric methane concentrations. This paper focuses primarily on the data reduction and data visualization strategies employed while processing the more than 1.2 TB of raw water column data collected by the multibeam system over several high-output oil and gas seep areas. Water depths ranged from about 30 to 80m. Turnkey software solutions for processing these data are currently unavailable so most of the processing code was developed in-house by the USGS. The main challenge in processing the sonar water-column data is ray-tracing the large volume of data, with each ping containing more than 4500 times as many samples as a conventional multibeam ping. We employed two strategies to make processing tractable on conventional workstations: (1) decimate the raw data based on desired output resolution before ray-tracing; and (2) design the ray-tracing program to run in parallel on multi-core workstations

  5. Experimental Research on the Reusing & Recycling Technology of Oil Extraction Wastewater Treatment in Oil Field

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    How to use water resource effectively is an important problem in developing industry. Three combined processes which are composed of oil separator+de-emulsification flocculation+sand filtration (SDF), oil separator +hydrolytic acidification+SBR (SAS) and oil separator+de-emulsification flocculation +SBR (SDS) are conducted in laboratory-scale experiment to treat oil extraction wastewater for an oil-field. The experimental results show that the removal rate of COD(chemistry oxygen demand) and oil treated by SDF process are 85% and 95% respectively, the residual oil in effluent can meet the discharge standard, but the residual COD can not. The removal rate of COD and BOD (biological oxygen demand) of the SAS effluent are 85% and 90% respectively, the BOD can meet but the COD can not meet discharge standard. So the further treatment is required in the process. The SDS effluent with removal rate of 95% and 90% are obtained for COD and BOD respectively, which can completely meet the national standards of oil wastewater discharge and refilling (China). The experimental result shows that oil extraction wastewater has turned into water resource after being treated by SDS.

  6. Cleaning of Oil Fouling with Water Enabled by Zwitterionic Polyelectrolyte Coatings: Overcoming the Imperative Challenge of Oil-Water Separation Membranes.

    Science.gov (United States)

    He, Ke; Duan, Haoran; Chen, George Y; Liu, Xiaokong; Yang, Wensheng; Wang, Dayang

    2015-09-22

    Herein we report a self-cleaning coating derived from zwitterionic poly(2-methacryloyloxylethyl phosphorylcholine) (PMPC) brushes grafted on a solid substrate. The PMPC surface not only exhibits complete oil repellency in a water-wetted state (i.e., underwater superoleophobicity), but also allows effective cleaning of oil fouled on dry surfaces by water alone. The PMPC surface was compared with typical underwater superoleophobic surfaces realized with the aid of surface roughening by applying hydrophilic nanostructures and those realized by applying smooth hydrophilic polyelectrolyte multilayers. We show that underwater superoleophobicity of a surface is not sufficient to enable water to clean up oil fouling on a dry surface, because the latter circumstance demands the surface to be able to strongly bond water not only in its pristine state but also in an oil-wetted state. The PMPC surface is unique with its described self-cleaning performance because the zwitterionic phosphorylcholine groups exhibit exceptional binding affinity to water even when they are already wetted by oil. Further, we show that applying this PMPC coating onto steel meshes produces oil-water separation membranes that are resilient to oil contamination with simply water rinsing. Consequently, we provide an effective solution to the oil contamination issue on the oil-water separation membranes, which is an imperative challenge in this field. Thanks to the self-cleaning effect of the PMPC surface, PMPC-coated steel meshes can not only separate oil from oil-water mixtures in a water-wetted state, but also can lift oil out from oil-water mixtures even in a dry state, which is a very promising technology for practical oil-spill remediation. In contrast, we show that oil contamination on conventional hydrophilic oil-water separation membranes would permanently induce the loss of oil-water separation function, and thus they have to be always used in a completely water-wetted state, which significantly

  7. Field performance of a premium heating oil

    Energy Technology Data Exchange (ETDEWEB)

    Santa, T. [Santa Fuels, Inc., Bridgeport, CT (United States); Jetter, S.M. [Mobil Oil R & D Corp., Paulsboro, NJ (United States)

    1996-07-01

    As part of our ongoing research to provide quality improvements to heating oil, Mobil Oil together with Santa Fuel, Inc., conducted a field trial to investigate the performance of a new premium heating oil. This premium heating oil contains an additive system designed to minimize sludge related problems in the fuel delivery system of residential home heating systems. The additive used was similar to others reported at this and earlier BNL conferences, but was further developed to enhance its performance in oil heat systems. The premium heating oil was bulk additized and delivered to a subset of the customer base. Fuel related, unscheduled service calls were monitored in this test area, as well as in a similar baseline area that did not receive the premium heating oil. Overall, the premium fuel provided a 45% reduction in the occurrence of fuel related, unscheduled service calls as compared to the baseline area. Within this population, there was a reduction of 38% in systems with 275 gallon tanks, and 55% in systems that had >275 gallon tanks showing that the additive is effective in the various configurations of residential oil heat systems. In addition, photographic documentation collected at two accounts supported this improvement by clearly showing that the equipment remained cleaner with the premium heating oil than with regular heating oil. Based on these results, a full marketing trial of this new product has been initiated by Mobil and Santa Fuel, Inc., during the 1995-1996 heating season.

  8. Cleaning method of the oil field wastewater treatment by UF process

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    This article introduces experiments and researches of polysulphone ultrafiltration membrane' s effect on oil field polluted water and approaches renewing oil field polluted water and approaches renewing of membrane' s flux by different detergents and cleaning method. Good result has been achieved by doing experiments and the renewal rate of membrane is over 90%.

  9. Origin and evolution of formation water at the Jujo-Tecominoacan oil reservoir, Gulf of Mexico. Part 2: Isotopic and field-production evidence for fluid connectivity

    Energy Technology Data Exchange (ETDEWEB)

    Birkle, Peter, E-mail: birkle@iie.org.mx [Instituto de Investigaciones Electricas (IIE), Gerencia de Geotermia, Cuernavaca 62490, Morelos (Mexico); Garcia, Bernardo Martinez; Milland Padron, Carlos M. [PEMEX Exploracion y Produccion, Region Sur, Activo Integral Bellota-Jujo, Diseno de Explotacion, Cardenas, Tabasco (Mexico); Eglington, Bruce M. [Saskatchewan Isotope Laboratory, University of Saskatchewan, Saskatoon, Canada SK S7N 5E2 (Canada)

    2009-04-15

    The chemical and isotopic characterization of formation water from 18 oil production wells, extracted from 5200 to 6100 m b.s.l. at the Jujo-Tecominoacan carbonate reservoir in SE-Mexico, and interpretations of historical production records, were undertaken to determine the origin and hydraulic behavior of deep groundwater systems. The infiltration of surface water during Late Pleistocene to Early Holocene time is suggested by {sup 14}C-concentrations from 2.15 to 31.86 pmC, and by {sup 87}Sr/{sup 86}Sr-ratios for high-salinity formation water (0.70923-0.70927) that are close to the composition of Holocene to modern seawater. Prior to infiltration, the super-evaporation of seawater reached maximum TDS concentrations of 385 g/L, with lowest {delta}{sup 18}O values characterizing the most hypersaline samples. Minor deviations of formation water and dolomite host rocks from modern and Jurassic {sup 87}Sr/{sup 86}Sr-seawater composition, respectively, suggest ongoing water-rock interaction, and partial isotopic equilibration between both phases. The abundance of {sup 14}C in all sampled formation water, {sup 87}Sr/{sup 86}Sr-ratios for high-salinity water close to Holocene - present seawater composition, a water salinity distribution that is independent of historic water-cut, and a total water extraction volume of 2.037 MMm{sup 3} (1/83-4/07) excludes a connate, oil-leg origin for the produced water of the Jurassic-Cretaceous mudstone-dolomite sequence. Temporal fluctuations of water chemistry in production intervals, the accelerated migration of water fronts from the reservoir flanks, and isotopic mixing trends between sampled wells confirms the existence of free aquifer water below oil horizons. Vertical and lateral hydraulic mobility has probably been accelerated by petroleum extraction. The combination of interpreting historical fluctuations of salinity and water percentage in production wells with chemical-isotopic analysis of formation water resulted in a

  10. Status of a study of the thermal regime of Uzen field and the effect of cold water injection in pattern flooding on the development of and oil production from the pay zones

    Energy Technology Data Exchange (ETDEWEB)

    Utebaev, S.U.; Smolnikov, N.V.; Yuferov, Yu.K.; Teslyuk, E.V.; Ilyaev, V.I.

    1968-11-01

    The crude oil in the Uzen field contains up to 26% paraffin, and paraffin deposition begins at +62/sup 0/ + 3/sup 0/C. Massive paraffin deposition occurs at 45/sup 0/ to 50/sup 0/C, and at 30/sup 0/C the oil congeals. Reservoir temperature is 65/sup 0/C. Because reservoir temperature is close to paraffin deposition temperature, great concern was felt in injecting cold water into the reservoir. A test program was conducted to determine the effect of cold water (15/sup 0/ to 25/sup 0/C) injection on reservoir behavior. This study showed that: (1) cold water rapidly lowered bottom-hole temperature in 1,400 m wells from 65/sup 0/ to 20/sup 0/C; (2) after cold water injection was stopped, bottom-hole temperature increased slowly; (3) the cold water decreased reservoir temperature in an observation well, 115 m distant from the water injection well; and (4) the cold water did not reduce the water intake rates of injection wells. These observations are backed by geophysical data. Plans are in progress to test hot water (100/sup 0/C) injection at this field.

  11. Challenges of Membrane Filtration for Produced Water Treatment in Offshore Oil & Gas Production

    DEFF Research Database (Denmark)

    Jepsen, Kasper Lund; Hansen, Leif; Mai, Christian

    2016-01-01

    Tremendous amount of produced water are discharged into the sea from offshore oil & gas installations. Along with every barrel of oil three barrels of water are produced and this is only worsen as the fields mature. Enhanced oil recovery (EOR) is employed to increase production, as a part of EOR...

  12. Tar mats and residual oil distribution in a giant oil field offshore Abu Dhabi

    Energy Technology Data Exchange (ETDEWEB)

    Carpentier, Bernard [Institut Francais du Petrole and 4 Av. de Bois Preau, 92852 Rueil-Malmaison Cedex (France); Arab, Hani [ZADCO P.O. Box 46808, Abu Dhabi(United Arab Emirates); Pluchery, Eric; Chautru, Jean-Marc [Beicip-Franlab 232, Av. Napoleon Bonaparte, BP 213, 92502 Rueil-Malmaison Cedex (France)

    2007-09-15

    This paper describes how geochemical data (Rock Eval analysis, SARA composition) combined with wireline log interpretation allows for the recognition of the distribution and continuity of bitumens in a main reservoir of an offshore giant field in Abu Dhabi. The integration of new geochemical data with data and field information provided by the oil company ZADCO allows for the recognition of two types of bitumen rich levels in the main reservoir of the field: (a) one corresponding to bitumen rich main reservoir intervals associated with high resistivity and high oil saturation, these intervals can be called 'tar mats', (b) the other corresponding to low oil saturated intervals, and can be classified as 'heavy residual oil'. In terms of lateral and vertical distribution, the tar mats are found at the crestal area of the Present-day structure and are located at the base of the reservoir unit above a tight limestone which plays a role of being a vertical permeability barrier. The tar mats seem to be independent of the Present-day OWC and are not related to biodegradation processes. The heavy residual oil is mainly located in the Northeast and the Southeast parts of the field and close to the OWC but it is also present all around the field except (1) in the west, in the area of the spill point and (2) in the Northwest area where direct contact between mobile oil and water is detected. Study of the structural evolution demonstrates that a tilting of the field began at Dammam age time (Eocene). The tilting of the structure led to a reduction of the structural closure in the West followed by the leakage of part of the originally trapped oil. Numerical modeling of such a geological scenario leads to a distribution of fluids (water, movable oil and residual oil) very close to the one observed at Present-day time in the field. This modeling allows a prediction of the extension and distribution of the residual heavy oil within the studied reservoir and can

  13. Quantification of the recovered oil and water fractions during water flooding laboratory experiments

    DEFF Research Database (Denmark)

    Katika, Konstantina; Halim, Amalia Yunita; Shapiro, Alexander

    2015-01-01

    During core flooding experiments where water is injected in residual oil saturated core plugs, the fluids are often produced in small amounts. Oil and water come out of the core and are collected in glass vials using a fraction collector. Quantification of these fluids is often difficult since th...... the volume might be less than a few microliters. In this study, we approach the determination of the oil volumes in flooding effluents using predetermined amounts of the North Sea oil with synthetic seawater. The UV/visible spectroscopy method and low-field NMR spectrometry are compared...... for this determination, and an account of advantages and disadvantages of each method is given. Both methods are reproducible with high accuracy. The NMR method was capable of direct quantification of both oil and water fractions, while the UV/visible spectroscopy quantifies only the oil fraction using a standard curve....

  14. Composition and placement process for oil field chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Cantu, L.A.; Yost, M.E.

    1991-01-22

    This patent describes a process for the continuous release of an oil field chemical within a subterranean hydrocarbon bearing formation or wellbore penetrating such formation. It comprises placing the oil field chemical in a polymeric microcapsule; dispersing such polymeric microcapsules; introducing the wellbore fluid containing the microcapsules into a well bore or subterranean formation through a wellbore; then allowing water and temperature at formation conditions to degrade; continuously releasing the chemical from the degraded microcapsules. This patent describes a composition comprising an oil field chemical incorporated in a polymeric microcapsule comprising the condensation product of hydroxyacetic acid monomer or hydroxyacetic acid co-condensed with up to 15 percent by weight of other hydroxy-, carboxylic acid-, or hydroxycarboxylic acid- containing moieties. The product has a number average molecular weight of from about 200 to about 4000.

  15. A field laboratory for improved oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrandt, A.F.; McDonald, J.; Claridge, E.; Killough, J.

    1992-09-01

    The purpose of Annex III of the Memorandum of Understanding, undertaken by the Houston Petroleum Research Center at the University of Houston, was to develop a field laboratory for research in improved oil recovery using a Gulf Coast reservoir in Texas. The participants: (1) make a field site selection and conducted a high resolution seismic survey in the demonstration field, (2) obtained characteristics of the reservoir (3) developed an evaluation of local flood efficiency in different parts of the demonstration reservoir, (4) used diverse methodology to evaluate the potential recovery of the remaining oil in the test reservoir, (5) developed cross-well seismic tomography, and (6) will transfer the learned technologies to oil operators through publication and workshops. This abstract is an overview of these tasks.

  16. Microbial ecology of oil fields : introduction to the symposium

    Energy Technology Data Exchange (ETDEWEB)

    Voordouw, G. [Calgary Univ., AB (Canada). Dept. of Biology

    2000-07-01

    A brief synopsis was presented of how and why microbiology has become a topic of large interest in the petroleum industry to increase the volume and reduce the costs of production. Organic acids are formed when organic material is buried and oil is being formed. Subsurface waters having high concentration of these acids contain sulfate-reducing bacteria (SRB) which cause problems such as anaerobic, microbially influenced corrosion and souring. New nucleic acid hybridization technologies are being used to identify the SRB and sulfide-oxidizing bacteria (SOB) active in these processes. Oil fields can be injected with nitrate to overcome microbial souring. Some oil field bacteria use hydrocarbons as electron donors for their metabolism, but when oxygen is absent, either Fe{sup 3}, sulfate or nitrate is needed as an electron acceptor. Degradation of alkylbenzenes under iron-reducing, denitrifying and sulfate-reducing conditions has been established and the anaerobic respiration of alkanes has also been demonstrated. Sulfate-reducing, alkylbenzene or alkane oxidizers are the dominant organisms in storage tanks. Another important reason why microbiology has played a key role in fields where oil is produced by water injection, is the fact that resident or introduced bacteria can be successfully used for microbial enhanced oil recovery (EOR) by blocking the path of lease resistance.

  17. Utilization of carbon steel with one per cent of chromium in water injection wells equipment in oil fields; Utilizacao de aco carbono com 1 por cento de cromo em equipamentos de pocos de injecao de agua em campos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Coutinho, A.; Barbosa, B. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Exploracao e Producao; Joia, C.; Andrade, C. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas; Silva, Julio M. [Vallourec e Mannesmann do Brasil, Rio de Janeiro, RJ (Brazil)

    2000-07-01

    In order to produce oil in some oil reservoirs of Campos Fields, water has to be injected in the reservoir just to keep the pressure and not to decrease the production rate. Water injection wells are used and carbon steel is the material that it is widely used due to its lower price. Water treatment has therefore to be carried out in off-shore platforms to maintain corrosion rates controlled. Dissolved oxygen content is the most important variable specified. It has to be kept below 10 ppb to allow the specified equipment, pipeline and tubing life to be reached. In this work the effect of 1% Cr addition to the chemical composition of carbon steel to the corrosion rate is evaluated, as well as the effects of oxygen content, the temperature and the speed flow. (author)

  18. Integrated field modelling[Oil and gas fields

    Energy Technology Data Exchange (ETDEWEB)

    Nazarian, Bamshad

    2002-07-01

    This research project studies the feasibility of developing and applying an integrated field simulator to simulate the production performance of an entire oil or gas field. It integrates the performance of the reservoir, the wells, the chokes, the gathering system, the surface processing facilities and whenever applicable, gas and water injection systems. The approach adopted for developing the integrated simulator is to couple existing commercial reservoir and process simulators using available linking technologies. The simulators are dynamically linked and customised into a single hybrid application that benefits from the concept of open software architecture. The integrated field simulator is linked to an optimisation routine developed based on the genetic algorithm search strategies. This enables optimisation of the system at field level, from the reservoir to the process. Modelling the wells and the gathering network is achieved by customising the process simulator. This study demonstrated that the integrated simulation improves current capabilities to simulate the performance of the entire field and optimise its design. This is achieved by evaluating design options including spread and layout of the wells and gathering system, processing alternatives, reservoir development schemes and production strategies. Effectiveness of the integrated simulator is demonstrated and tested through several field-level case studies that discuss and investigate technical problems relevant to offshore field development. The case studies cover topics such as process optimisation, optimum tie-in of satellite wells into existing process facilities, optimal well location and field layout assessment of a high pressure high temperature deepwater oil field. Case study results confirm the viability of the total field simulator by demonstrating that the field performance simulation and optimal design were obtained in an automated process with treasonable computation time. No significant

  19. Integrated field modelling[Oil and gas fields

    Energy Technology Data Exchange (ETDEWEB)

    Nazarian, Bamshad

    2002-07-01

    This research project studies the feasibility of developing and applying an integrated field simulator to simulate the production performance of an entire oil or gas field. It integrates the performance of the reservoir, the wells, the chokes, the gathering system, the surface processing facilities and whenever applicable, gas and water injection systems. The approach adopted for developing the integrated simulator is to couple existing commercial reservoir and process simulators using available linking technologies. The simulators are dynamically linked and customised into a single hybrid application that benefits from the concept of open software architecture. The integrated field simulator is linked to an optimisation routine developed based on the genetic algorithm search strategies. This enables optimisation of the system at field level, from the reservoir to the process. Modelling the wells and the gathering network is achieved by customising the process simulator. This study demonstrated that the integrated simulation improves current capabilities to simulate the performance of the entire field and optimise its design. This is achieved by evaluating design options including spread and layout of the wells and gathering system, processing alternatives, reservoir development schemes and production strategies. Effectiveness of the integrated simulator is demonstrated and tested through several field-level case studies that discuss and investigate technical problems relevant to offshore field development. The case studies cover topics such as process optimisation, optimum tie-in of satellite wells into existing process facilities, optimal well location and field layout assessment of a high pressure high temperature deepwater oil field. Case study results confirm the viability of the total field simulator by demonstrating that the field performance simulation and optimal design were obtained in an automated process with treasonable computation time. No significant

  20. Intisar ''D'' Oil Field, Libya

    Energy Technology Data Exchange (ETDEWEB)

    Brady, T.J.; Campbell, N.D.J.; Maher, C.E.

    1979-01-01

    The Intisar D Reef Oil Field was discovered by Occidental in Oct. 1967; the discovery well tested 75,000 bpod. The prospect was based on reflection seismic data, which indicated the presence of an isolated reef. The Intisar D Reef is roughly circular in plan and approximately 5 km in diameter. Its maximum thickness is 1262 ft (385 m). The reef is coral and algal with grain- and mud-supported biomicrites. The reef was full to spill point with a maximum oil column of 955 ft (291 m). The 40 API gravity oil has a paraffinic base and is low in sulfur. Cumulative oil production as of Sept. 30, 1978, totaled 777 million bbl ultimate recovery efficiency is expected to appraoch 75%. No pressure support was expected. Supplemental recovery operations that were begun early include pressure maintenance by both water and gas injection. The reservoir pressure is now maintained at the 4000-psi level, high enough for miscible gas displacement.

  1. Application Research of Subsea Technologies in Deep Water Oil/Gas Field%世界深水油气田水下技术应用研究

    Institute of Scientific and Technical Information of China (English)

    李怀印; 党学博

    2016-01-01

    水下技术是深水油气开发的重要发展方向。随着技术的进步,越来越多的水下技术和装备成功应用于海上油气田开发。深入分析了水下技术应用的8个典型油气田,包括Tordis、 Sno⁃hvit、 BC-10( Parque das Conchas)、 Cascade⁃Chinook、 Perdido、 King、 Ormen Lange 和 Tyrihans,重点总结了这些油气田采用的水下技术的特点及应用效果。这些成功开发的油气田在水下技术方面的开创性技术与应用效果,对我国海工技术方面的科研和生产具有重要的启示意义。%Subsea Technology is a major development direction of deepwater oil and gas development Withtechnical progress, more and more subsea technologies and equipment are successfully used for development of off⁃shore oil and gas fields In⁃depth analysis has been conducted on eight typical oil and gas fields for application ofsubsea technologies, including Tordis, Snohvit, BC - 10 (Parque das Conchas), Cascade⁃Chinook, Perdido,King, Ormen Lange and Tyrihans Great attention has been paid to summarizing subsea technology characteristicsand application effects Groundbreaking technology and application effects of these successfully developed oil andgas fields in subsea technologies have the important enlightenment significance on the offshore engineering technolo⁃gy research and application in China.

  2. A field pilot-scale study of biological treatment of heavy oil-produced water by biological filter with airlift aeration and hydrolytic acidification system.

    Science.gov (United States)

    Zhang, Min; Wang, Junming; Zhang, Zhongzhi; Song, Zhaozheng; Zhang, Zhenjia; Zhang, Beiyu; Zhang, Guangqing; Wu, Wei-Min

    2016-03-01

    Heavy oil-produced water (HOPW) is a by-product during heavy oil exploitation and can cause serious environmental pollution if discharged without adequate treatment. Commercial biochemical treatment units are important parts of HOPW treatment processes, but many are not in stable operation because of the toxic and refractory substances, salt, present. Therefore, pilot-scale experiments were conducted to evaluate the performance of hydrolytic acidification-biological filter with airlift aeration (HA-BFAA), a novel HOPW treatment system. Four strains isolated from oily sludge were used for bioaugmentation to enhance the biodegradation of organic pollutants. The isolated bacteria were evaluated using 3-day biochemical oxygen demand, oil, dodecyl benzene sulfonic acid, and chemical oxygen demand (COD) removals as evaluation indices. Bioaugmentation enhanced the COD removal by 43.5 mg/L under a volume load of 0.249 kg COD/m(3) day and hydraulic retention time of 33.6 h. The effluent COD was 70.9 mg/L and the corresponding COD removal was 75.0 %. The optimum volumetric air-to-water ratio was below 10. The removal ratios of the total extractable organic pollutants, alkanes, and poly-aromatic hydrocarbons were 71.1, 94.4, and 94.0 %, respectively. Results demonstrated that HA-BFAA was an excellent HOPW treatment system.

  3. Wettability testing of unconsolidated oil sands using low field NMR technology

    Energy Technology Data Exchange (ETDEWEB)

    Ji, X.; Kantzas, A.; Bryan, J. [University of Calgary/TIPM Laboratory (Canada)

    2011-07-01

    In an oil field it is important to understand wettability within the reservoir as it has an important impact on several parameters. However it is difficult to measure wettability in oil sands since conventional Amott/USBM testing cannot be applied. The aim of this paper is to develop protocols to assess wettability from NMR spectra in heavy oil reservoirs. Research was conducted on water wet and oil wet conditions; 3 sets of experiments were carried out with oil phases of different viscosity. Results showed that the signal from oil is insensitive to the location of the oil when viscosity increases but that water relaxation times are linked to the presence of water so water peak shifts can be used to determine different wettability states. This study determined that using water phase NMR relaxation presents several advantages to extract wettability information in unconsolidated sand systems and a technique was developed to interpret wettability.

  4. Apparatus for performing oil field laser operations

    Energy Technology Data Exchange (ETDEWEB)

    Zediker, Mark S.; Land, Mark S.; Rinzler, Charles C.; Faircloth, Brian O.; Koblick, Yeshaya; Moxley, Joel F.

    2017-01-03

    A system, apparatus and methods for delivering high power laser energy to perform laser operations in oil fields and to form a borehole deep into the earth using laser energy. A laser downhole assembly for the delivery of high power laser energy to surfaces and areas in a borehole, which assembly may have laser optics and a fluid path.

  5. The Lennox oil and gas field

    Energy Technology Data Exchange (ETDEWEB)

    Haig, D.B.; Pickering, S.C.; Probert, R. [BHP Petroleum Ltd., London (United Kingdom)

    1997-12-31

    The Lennox oil and gas field is located in Block 110/15 of the East Irish Sea, approximately 10 km west of Southport, Lancashire. The field was discovered in 1992 with well 110/15-6 drilled by the P791 BHP group. The Lennox structure is a rollover anticline in Permo-Triassic sediments formed in the hanging wall of the Formby Point Fault. The reservoir comprises the Triassic Sherwood Sandstone Group, and is characterized by excellent permeability aeolian and fluvial sandstones. The structure is sealed by the overlying shales and evaporites of the Mercia Mudstone Group. To date four wells have been drilled on the Lennox Field and have delineated a free gas cap in communication with a constant thickness oil rim. The hydrocarbons have been sourced from Namurian Holywell shales and reflect complex migration into the Lennox structure. Reservoir studies indicate likely hydrocarbons-in-place of 463 BCF of gas and 218 MMBO of oil. Development approval for the Lennox Field was granted in 1993 with production due to commence in late 1995 from a series of horizontal oil producers. (author)

  6. Water management in the oil sands industry

    Energy Technology Data Exchange (ETDEWEB)

    Pauls, R. [Syncrude Canada Ltd., Fort McMurray, AB (Canada)

    2004-07-01

    Water management issues at Alberta's 4 oil sand deposits were discussed. The 4 deposits include the Peace River, Athabasca, Wabasca and Cold Lake deposits, with the Athabasca deposit being the largest and the only surface-mineable deposit. Large quantities of water are needed to extract bitumen from oil sands. This paper addressed water volume withdrawal from the Athabasca River, the primary source of water for the surface-mining oil sands industry. It also addressed Muskeg River watershed integrity, quality of water withdrawn from reclaimed landscapes, groundwater contamination, and ecological viability of end-pit lakes. Currently, half of Syncrude's oil sand is transported from mine to extraction plant by conveyor belts. The other half is pipelined as a warm water slurry. By 2005, all transport will be by pipeline. The oil sand is mixed with hot water, steam and surfactants to condition it for extraction. Seventy-nine per cent of the water used by Syncrude is recycled water and the remainder comes from the Athabasca River. Syncrude diverts 2.5 to 3 barrels of water from the Athabasca River for every barrel of oil produced. This paper discussed the in-stream flow needs of the Athabasca River based on protection of aquatic ecosystems. Flow needs are addressed by the Cumulative Effects Management Association (CEMA). The paper states that the proportion of annual flow withdrawn from the Athabasca River is too low to have a significant impact on aquatic systems, but the main concern lies in water use during low flow periods, typically during the winter months. Developers will likely come under pressure to develop off-site reservoirs to store water for use during these low-flow periods. tabs., figs.

  7. Zeta potential in oil-water-carbonate systems and its impact on oil recovery during controlled salinity water-flooding

    Science.gov (United States)

    Jackson, Matthew D.; Al-Mahrouqi, Dawoud; Vinogradov, Jan

    2016-11-01

    Laboratory experiments and field trials have shown that oil recovery from carbonate reservoirs can be increased by modifying the brine composition injected during recovery in a process termed controlled salinity water-flooding (CSW). However, CSW remains poorly understood and there is no method to predict the optimum CSW composition. This work demonstrates for the first time that improved oil recovery (IOR) during CSW is strongly correlated to changes in zeta potential at both the mineral-water and oil-water interfaces. We report experiments in which IOR during CSW occurs only when the change in brine composition induces a repulsive electrostatic force between the oil-brine and mineral-brine interfaces. The polarity of the zeta potential at both interfaces must be determined when designing the optimum CSW composition. A new experimental method is presented that allows this. Results also show for the first time that the zeta potential at the oil-water interface may be positive at conditions relevant to carbonate reservoirs. A key challenge for any model of CSW is to explain why IOR is not always observed. Here we suggest that failures using the conventional (dilution) approach to CSW may have been caused by a positively charged oil-water interface that had not been identified.

  8. Crude Production Tops 2 Million Tons at Qinghai Oil Field

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    @@ The crude oil output of Qinghai Oil Field in Qaidam basin of the northwestern China's Qinghai Province topped two million tons at the end of 2000.This is the first time that the annual crude oil output of the oilfield has exceeded two millions, according to Huang Ligong, general manager of Qinghai Oil Field under PetroChina.

  9. 油田采出水中溶解性气体的腐蚀与防护%Corrosion and Protection of Dissolved Gases in Produced Water from Oil Field

    Institute of Scientific and Technical Information of China (English)

    曲虎; 马梓涵; 管善峰; 杨向平

    2011-01-01

    油田采出水中含有H2S,CO2和O2等溶解性气体,是造成采出水及注水系统管道腐蚀的重要因素.在此对溶解气体的腐蚀机理及防护措施进行介绍,现行控制油田采出水中溶解性气体腐蚀的方法主要是化学方法,包括污水缓蚀技术和污水水质改性技术,化学方法效果明显但也有其缺点.目前还没有专门针对油田采出水中溶解气体的去除工艺,通过对电解、脱气膜、超重力和气提工艺进行分析,发现气提工艺是去除油田采出水中溶解性气体的一种可行工艺.%The dissolved gases such as carbon dioxide,hydrogen sulphide and oxygen which are dissolved in produced water from oil field is the important factor for the corrosion of pipelines in produced water and injection water. The corrosion mechanism and protective measures were introduced in the paper. The principal measures of retarding corrosion are chemical methods, including corrosion inhibition and modification of wastewater which have obvious effect, but some drawbacks as well. There is no special technology to remove the dissolved gases from produced water in oil field at present.The technologies of electrolysis, degassing membrane, high gravity and gas stripping were discussed, and the gas stripping was considered to be the feasible technology to remove the dissolved gases from produced water in oil field.

  10. Oil sands mining water use and management

    Energy Technology Data Exchange (ETDEWEB)

    Bender, M.; Long, D.; Fitch, M. [Golder Associates Ltd., Calgary, AB (Canada)

    2010-07-01

    There are currently 4 bitumen mining operations operating along the Athabasca River in northern Alberta. This paper presented details of the water licences, historical water use, present water use, and future plans for water management in relation to oil sands mining operations. The study was based on work currently conducted for the Oil Sands Developers Group (OSDG) and Canadian Association of Petroleum Producers (CAPP), as well as on mine site water balance analyses for proposed mines in the region. Typical mine site water balances were discussed, and water use rates for the mining operations were reviewed. The new Athabasca River water management framework may require that mines provide additional water storage or delayed reclamation of mine areas in order to offset water losses during winter low-flow periods. New regulations may also reduce the requirement for make-up water. The study also noted that release criteria are still being developed for on-site water within closed-loop mine operations. The oil sands industry will need to balance various factors related to water use in the future. 5 refs., 3 figs.

  11. Oil field experiments of microbial improved oil recovery in Vyngapour, West Siberia, Russia

    Energy Technology Data Exchange (ETDEWEB)

    Murygina, V.P.; Mats, A.A.; Arinbasarov, M.U.; Salamov, Z.Z.; Cherkasov, A.B.

    1995-12-31

    Experiments on microbial improved oil recovery (MIOR) have been performed in the Vyngapour oil field in West Siberia for two years. Now, the product of some producing wells of the Vyngapour oil field is 98-99% water cut. The operation of such wells approaches an economic limit. The nutritious composition containing local industry wastes and sources of nitrogen, phosphorus and potassium was pumped into an injection well on the pilot area. This method is called {open_quotes}nutritional flooding.{close_quotes} The mechanism of nutritional flooding is based on intensification of biosynthesis of oil-displacing metabolites by indigenous bacteria and bacteria from food industry wastes in the stratum. 272.5 m{sup 3} of nutritious composition was introduced into the reservoir during the summer of 1993, and 450 m3 of nutritious composition-in 1994. The positive effect of the injections in 1993 showed up in 2-2.5 months and reached its maximum in 7 months after the injections were stopped. By July 1, 1994, 2,268.6 tons of oil was produced over the base variant, and the simultaneous water extraction reduced by 33,902 m{sup 3} as compared with the base variant. The injections in 1994 were carried out on the same pilot area.

  12. Reserve growth of the world's giant oil fields

    Science.gov (United States)

    Klett, T.R.; Schmoker, J.W.

    2005-01-01

    Analysis of estimated total recoverable oil volume (field size) of 186 well-known giant oil fields of the world (>0.5 billion bbl of oil, discovered prior to 1981), exclusive of the United States and Canada, demonstrates general increases in field sizes through time. Field sizes were analyzed as a group and within subgroups of the Organization of Petroleum Exporting Countries (OPEC) and non-OPEC countries. From 1981 through 1996, the estimated volume of oil in the 186 fields for which adequate data were available increased from 617 billion to 777 billion bbl of oil (26%). Processes other than new field discoveries added an estimated 160 billion bbl of oil to known reserves in this subset of the world's oil fields. Although methods for estimating field sizes vary among countries, estimated sizes of the giant oil fields of the world increased, probably for many of the same reasons that estimated sizes of oil fields in the United States increased over the same time period. Estimated volumes in OPEC fields increased from a total of 550 billion to 668 billion bbl of oil and volumes in non-OPEC fields increased from 67 billion to 109 billion bbl of oil. In terms of percent change, non-OPEC field sizes increased more than OPEC field sizes (63% versus 22%). The changes in estimated total recoverable oil volumes that occurred within three 5-year increments between 1981 and 1996 were all positive. Between 1981 and 1986, the increase in estimated total recoverable oil volume within the 186 giant oil fields was 11 billion bbl of oil; between 1986 and 1991, the increase was 120 billion bbl of oil; and between 1991 and 1996, the increase was 29 billion bbl of oil. Fields in both OPEC and non-OPEC countries followed trends of substantial reserve growth.

  13. Venezuelan oil field revival bids won

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-29

    This paper reports that four private sector companies or combines will operate inactive oil fields in Venezuela under state owned Petroleos de Venezuela's marginal field reactivation program. The award of operating contract to winning bidders marks the first time private companies will be allowed to produce crude oil in Venezuela since nationalization of the industry in 1976. Winning bidders have committed a total of $720 million in investments to the program during the 1990s. Current plans call for drilling 670 appraisals and development wells, conducting 250 workovers and well repairs, and conducting about 2,9000 line km of seismic surveys. Venezuela's energy ministry is targeting a production level of 90,000 b/d by the end of the decade from the reactivated fields.

  14. Characterization of water-in-crude oil emulsions in oil spill response

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The formation of water-in-crude oil emulsions occurs when crude oils are spilled into sea. The water-in-crude oil emulsionssignificantly change the properties of the spilled crude oils and in turn influence the choices made relating to oil spill countermeasures. Thewater-in-crude oil emulsions were characterized using various techniques in this study. The environmental scanning electron microscopyobservation of water droplets in the emulsions is also presented. It is a powerful tool in emulsion observations.

  15. Oil Spill Field Trial at Sea: Measurements of Benzene Exposure.

    Science.gov (United States)

    Gjesteland, Ingrid; Hollund, Bjørg Eli; Kirkeleit, Jorunn; Daling, Per; Bråtveit, Magne

    2017-07-01

    Characterize personal exposure to airborne hydrocarbons, particularly carcinogenic benzene, during spill of two different fresh crude oils at sea. The study included 22 participants taking part in an «oil on water» field trial in the North Sea. Two types of fresh crude oils (light and heavy) were released six times over two consecutive days followed by different oil spill response methods. The participants were distributed on five boats; three open sampling boats (A, B, and C), one release ship (RS), and one oil recovery (OR) vessel. Assumed personal exposure was assessed a priori, assuming high exposure downwind and close to the oil slick (sampling boats), low exposure further downwind (100-200 m) and upwind from the oil slick (main deck of RS and OR vessel), and background exposure indoors (bridge of RS/OR vessel). Continuous measurements of total volatile organic compounds in isobutylene equivalents were performed with photoionization detectors placed in all five boats. Full-shift personal exposure to benzene, toluene, ethylbenzene, xylenes, naphthalene, and n-hexane was measured with passive thermal desorption tubes. Personal measurements of benzene, averaged over the respective sample duration, on Day 1 showed that participants in the sampling boats (A, B, and C) located downwind and close to the oil slick were highest exposed (0.14-0.59 ppm), followed by participants on the RS main deck (0.02-0.10 ppm) and on the bridge (0.004-0.03 ppm). On Day 2, participants in sampling boat A had high benzene exposure (0.87-1.52 ppm) compared to participants in sampling boat B (0.01-0.02 ppm), on the ships (0.06-0.10 ppm), and on the bridge (0.004-0.01 ppm). Overall, the participants in the sampling boats had the highest exposure to all of the compounds measured. The light crude oil yielded a five times higher concentration of total volatile organic compounds in air in the sampling boats (max 510 ppm) than the heavy crude oil (max 100 ppm) but rapidly declined to

  16. Viscosity of oil and water mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Corlett, A.E.; Hall, A.R.W. [National Engineering Laboratory, Glasgow (United Kingdom)

    1999-07-01

    A study was performed to investigate the apparent viscosity of oil and water mixtures using the pressure loss along a horizontal pipe. Water fractions between 100% to 5% were examined at three flow velocities and three temperatures. Four combinations of crude oil and saline solution were used. Tests found that the mixture viscosity exhibited a peak at the position of phase inversion. The value of this maximum viscosity depended upon the temperature and fluid combination used, but not the velocity. Physical properties of the fluids were important factors in the viscosity/water fraction behaviour. (author)

  17. Ultrasonic splitting of oil-in-water emulsions

    DEFF Research Database (Denmark)

    Hald, Jens; König, Ralf; Benes, Ewald

    1999-01-01

    Standing resonant ultrasonic wave fields can be utilized for liquid–liquid separation of the dispersed particles and the fluid caused by the acoustic radiation pressure and the induced particle agglomeration or coagulation/coalescence process. For the splitting of oil-in-water emulsions...... emulsion samples have been investigated. The quality of the ultrasonic-induced particle separation/coagulation process is characterized by physical–chemical analysis of the separated oil- and water phase and by determining the change of the particle size distribution of the initial emulsion due...... of up to 24 W/cm2 into the sonication volume. The chosen resonance frequency is kept stable by automatic frequency control utilizing the maximum true power criterion. Physically and chemically well-defined low and high density pure laboratory and also industrially used cooling-lubricating oil-in-water...

  18. The calming effect of oil on water

    Science.gov (United States)

    Behroozi, Peter; Cordray, Kimberly; Griffin, William; Behroozi, Feredoon

    2007-05-01

    The calming effect of oil on water has been known since ancient times. Benjamin Franklin was the first to investigate the effect, but the underlying mechanism for this striking phenomenon remains elusive. We used a miniature laser interferometer to measure the amplitude of surface waves to a resolution of ±5nm, making it possible to determine the effect of an oil monolayer on the attenuation of capillary waves and the surface dilational modulus of the monolayer. We present attenuation data on pure water, water covered by olive oil, water covered by a fatty acid, and a water-acetone mixture for comparison. From the attenuation data at frequencies between 251 and 551Hz, we conclude that the calming effect of oil on surface waves is principally due to the dissipation of wave energy caused by the Gibbs surface elasticity of the monolayer, with only a secondary contribution from the reduction in surface tension. Our data also indicate that the surface-dilational viscosity of the oil monolayer is negligible and plays an insignificant role in calming the waves.

  19. Emulsifier for water-in-oil emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Weete, J.D.; Griffith, G.L.

    1990-07-24

    This patent describes a water-in-oil emulsion. It comprises: a continuous oil phase, a discontinuous aqueous phase, and an emulsion stabilizing amount of a thermally altered lecithin composition which has been prepare by heating lecithin at a temperature in the range of from about 100{degrees}C, to about 250{degrees}C, for a period of time ranging from about 15 to about 480 minutes.

  20. Radium content of oil- and gas-field produced waters in the northern Appalachian Basin (USA)—Summary and discussion of data

    Science.gov (United States)

    Rowan, E.L.; Engle, M.A.; Kirby, C.S.; Kraemer, T.F.

    2011-01-01

    Radium activity data for waters co-produced with oil and gas in New York and Pennsylvania have been compiled from publicly available sources and are presented together with new data for six wells, including one time series. When available, total dissolved solids (TDS), and gross alpha and gross beta particle activities also were compiled. Data from the 1990s and earlier are from sandstone and limestone oil/gas reservoirs of Cambrian-Mississippian age; however, the recent data are almost exclusively from the Middle Devonian Marcellus Shale. The Marcellus Shale represents a vast resource of natural gas the size and significance of which have only recently been recognized. Exploitation of the Marcellus involves hydraulic fracturing of the shale to release tightly held gas. Analyses of the water produced with the gas commonly show elevated levels of salinity and radium. Similarities and differences in radium data from reservoirs of different ages and lithologies are discussed. The range of radium activities for samples from the Marcellus Shale (less than detection to 18,000 picocuries per liter (pCi/L)) overlaps the range for non-Marcellus reservoirs (less than detection to 6,700 pCi/L), and the median values are 2,460 pCi/L and 734 pCi/L, respectively. A positive correlation between the logs of TDS and radium activity can be demonstrated for the entire dataset, and controlling for this TDS dependence, Marcellus shale produced water samples contain statistically more radium than non-Marcellus samples. The radium isotopic ratio, Ra-228/Ra-226, in samples from the Marcellus Shale is generally less than 0.3, distinctly lower than the median values from other reservoirs. This ratio may serve as an indicator of the provenance or reservoir source of radium in samples of uncertain origin.

  1. The Linguado, Carapeba, Vermelho, and Marimba giant oil fields, Campos basin, offshore Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Stank, C.V.; Esteves, F.R.; Martins, C.C.; Cruz, W.M.; Da Silva Barroso, A.; Horschutz, P.M.C. (Petrobras, Rio de Janeiro (Brazil))

    1990-09-01

    About 40 hydrocarbon accumulations have been discovered in the Campos basin in the period 1978-1984, including four giant fields in shallow to moderate water depths. The Linguado oil field is located on the extreme south of the producing area of the Campos basin. The pool was discovered in May 1978. The reservoir rocks occur between 1,700 and 3,000 m, and are constituted by fractured Neocomian basalts, Barremian pelecypod coquinas, Albian oolitic calcarenites, and, secondarily, by some Cretaceous turbidite sandstones. The main reservoir is formed by coquinas, which contain 76% of the total recoverable oil volume estimated at 104.6 million bbl. The field is located on a regional high and the accumulation is strongly controlled by stratigraphic and diagenetic factors. High-quality oil is produced through a floating producing system (FPS), and the cumulative oil production amounts to 63.8 million bbl. The Carapeba and Vermelho oil fields are situated in the northern limit of the Campos basin producing area and, together with the smaller Pargo field, make up the so-called Northeast Pole of Campos basin. Carapeba field was discovered in February 1982, and has an estimated recoverable oil volume of 127.8 million bbl. Production comes mainly from two Upper Cretaceous turbidite sandstone reservoirs. The Vermelho field in December 1982, and its main reservoir is formed by a massive Eocene turbidite sandstone. The estimated recoverable oil volume amounts to 119.7 million bbl. Both Carapeba and Vermelho fields are structural traps associated with the development of subtle anticlines caused by salt movements. The fields are gradually being put on stream through five fixed platforms installed in water depths ranging from 70 to 90 m. The Marimba field, discovered in March 1984, drilled in a water depth of 383 m, is considered the first deep-water oil strike in the Campos basin. The field has an estimated recoverable oil volume of 115 million bbl of good-quality oil.

  2. Geology of the Tambaredjo oil field, Suriname

    Energy Technology Data Exchange (ETDEWEB)

    Dronkert, H. (Delft Univ. of Technology (Netherlands)); Wong, T.E. (Geological Survey of the Netherlands, Haarlem (Netherlands))

    1993-02-01

    After the initial discovery in the sixties of oil below the coastal plain of Suriname (S. America), the State Oil Company of Suriname started production of the unique Tambaredjo field in 1982. The heavy, biodegraded oil (14-16[degrees] API) is produced under compaction drive, from the Paleocene T-sand (average thickness 5 m) at a depth of about 300 m. More than 300 wells have been drilled in an area of about 200 km[sup 2]. High resolution seismics makes it possible to correlate units down to 2 m thick. This dense network of bore holes is very suitable for geological correlations and 3D modeling. The T-sand reservoir consists of angular, medium to coarse grained unconsolidated sands with interfingering clays and lignites. The sands are deposited on a well cemented erosional Cretaceous basement. The reservoir is sealed by locally continuous clays. The oil is trapped in structural highs created by syn-sedimentary rejuvenated basement faults. The depositional environment of the T-sand ranges from fluviatile to deltaic. Frequent avulsion and synsedimentary faulting created a highly compartmented reservoir. Although interconnectedness of the sand bodies is high, clay smears and silting out of the edges confine reservoir compartments. The best genetic sand units such as channel fills or mouth bar deposits hardly correlate over more than a few hundred meters. The Tambaredjo oil field offers an unique opportunity to study the detailed sedimentology and petroleum geology of a fluvio-deltaic transitional realm on the passive margin along the Guiana coast.

  3. Interaction Mechanism of Oil-in-Water Emulsions with Asphaltenes Determined Using Droplet Probe AFM.

    Science.gov (United States)

    Shi, Chen; Zhang, Ling; Xie, Lei; Lu, Xi; Liu, Qingxia; Mantilla, Cesar A; van den Berg, Frans G A; Zeng, Hongbo

    2016-03-15

    Emulsions with interface-active components at the oil/water interface have long been of fundamental and practical interest in many fields. In this work, the interaction forces between two oil droplets in water in the absence/presence of asphaltenes were directly measured using droplet probe atomic force microscopy (AFM) and analyzed using a theoretical model based on Reynolds lubrication theory and the augmented Young-Laplace equation by including the effects of disjoining pressure. It was revealed that the interaction forces measured between two pristine oil droplets (i.e., toluene) could be well described by the classical Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, while an additional steric interaction should be included in the presence of asphaltenes in the oil. The surface interaction and the stability of oil droplets in aqueous solution were demonstrated to be significantly influenced by the asphaltenes concentration in oil, salt concentration, pH, and presence of divalent ions (Ca(2+)) in water. Adsorbed asphaltenes at the oil/water interface led to more negative surface potential of the oil/water interface and also induced steric repulsion between oil droplets, inhibiting the drop coalescence and stabilizing the oil-in-water emulsion. Lower pH of aqueous solution could lead to less negative surface potential and weaken the repulsion between oil droplets. Addition of divalent ions (Ca(2+)) was found to disrupt the protecting effects of adsorbed asphaltenes at oil/water interface and induce coalescence of oil droplets. Our results provide a useful methodology for quantifying the interaction forces and investigating the properties of asphaltenes at the oil/water interfaces and provide insights into the stabilization mechanism of oil-in-water emulsions due to asphaltenes in oil production and water treatment.

  4. 曝气生物滤池处理石油采出水的动力学特性研究%Kinetic Performance of Oil-field Produced Water Treatment by Biological Aerated Filter

    Institute of Scientific and Technical Information of China (English)

    苏德林; 王建龙; 刘凯文; 周定

    2007-01-01

    The biological aerated filter (BAF) was used to treat the oil-field produced water. The removal efficiency for oil, COD, BOD and suspended solids (SS) was 76.3%-80.3%, 31.6%-57.9%, 86.3%-96.3% and 76.4%-82.7%, respectively when the hydraulic loading rates varied from 0.6m·h-1 to 1.4m·h-1. The greatest part of removal, for example more than 80% of COD removal, occurred on the top 100cm of the media in BAF. The kinetic performance of BAF indicated that the relationship of BOD removal efficiency with the hydraulic loading rates in biological aerated filters could be described by cr/ci=1-exp(-2.44/L0.59). This equation could be used to predict the BOD removal efficiency at different hydraulic loading rates.

  5. Estimation of Reserves of Tula Horizon Oil Deposits of Severo-Yurmanskoye Field, Perm Kray

    Directory of Open Access Journals (Sweden)

    V I Nabiullin

    2015-09-01

    Full Text Available This article presents an estimation of reserves of the Tula horizon oil-bearing layers Tl2-a and Tl2-b at the Severo-Yurmanskoye oil field. Research was carried out in order to prospect the unestimated oil reserves at the previously drilled but not commercially producing areas of Perm kray. The opportunity of reserve calculation for this oil field was provided by the sufficient oil encroachment rate achieved during testing of Tula horizon layers in the borehole 174, reliable mapping of oil-bearing horizons using seismic and borehole data, existence of updated stratigraphic information, results of study of uniformity of oil-bearing layers throughout the area of the Severo-Yurmanskoye oil field, reliable estimate of the position of water-oil contact, defining the effective oil-bearing thickness of oil-bearing layers using results of borehole geophysical survey, study of lithological composition and reservoir  properties, study of physical and chemical properties of oil in borehole and in laboratory, and reliability of statistical evaluation of oil recovery factor.

  6. Treatment of waste waters in oil fields by a new technology-MDIF; Tratamento de aguas de descarte em campos produtores de petroleo atraves de nova tecnologia-MDIF

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes Junior, W.E.; Paulo, J.B.A. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica. Programa de Pos-graduacao em Engenharia Quimica]. E-mail: jbosco@eq.ufrn.br; Rolim, T.A.; Chiavenato, M.C.; Lima, A.F. [PETROBRAS, RN/CE (Brazil). Unidade de Negocios

    2004-07-01

    Mixer-settlers are usual equipment for phase separation in liquid-liquid systems. They consist of a mixer and a settling chambers. The critical point of this equipment is the length of the settling chamber. This characteristic is specially relevant where space is limited in lay-out of an industrial plant, for example, in an off-shore platform for oil exploration. An alternative to solve this problem is done by means of 'The Method of Separation by Phase Inversion' which is the base of operation of a new design of mixer-settler named MDIF. The equipment has hybrid characteristics between conventional mixer-settler and extraction columns. This equipment has been used to treat waste waters coming from production oil fields. The laboratory prototype showed an efficiency of separation up to 96% on treating waste waters with oil in a concentration of 100 to 1500 mg/L and total flow of 100 L/h. The effluent on exit of MDIF has approached 20 mg/L of oil (Resolucao CONAMA N. 20). A prototype in a semi-industrial scale of MDIF was designed to operate in real industrial conditions. A hundred times factor of scale laboratory/field was used. In this work a Statistical Experimental Design is carried out to laboratory conditions to get a model to predict the influence of operational variables as: total flow, organic/aqueous ratio on a volumetric basis and speed of agitation into mixer chamber upon efficiency of separation. These data are essential to perform the scale-up of the equipment. (author)

  7. Ultrasonic method for measuring water holdup of low velocity and high-water-cut oil-water two-phase flow

    Science.gov (United States)

    Zhao, An; Han, Yun-Feng; Ren, Ying-Yu; Zhai, Lu-Sheng; in, Ning-De

    2016-03-01

    Oil reservoirs with low permeability and porosity that are in the middle and late exploitation periods in China's onshore oil fields are mostly in the high-water-cut production stage. This stage is associated with severely non-uniform local-velocity flow profiles and dispersed-phase concentration (of oil droplets) in oil-water two-phase flow, which makes it difficult to measure water holdup in oil wells. In this study, we use an ultrasonic method based on a transmission-type sensor in oil-water two-phase flow to measure water holdup in low-velocity and high water-cut conditions. First, we optimize the excitation frequency of the ultrasonic sensor by calculating the sensitivity of the ultrasonic field using the finite element method for multiphysics coupling. Then we calculate the change trend of sound pressure level attenuation ratio with the increase in oil holdup to verify the feasibility of the employed diameter for the ultrasonic sensor. Based on the results, we then investigate the effects of oil-droplet diameter and distribution on the ultrasonic field. To further understand the measurement characteristics of the ultrasonic sensor, we perform a flow loop test on vertical upward oil-water two-phase flow and measure the responses of the optimized ultrasonic sensor. The results show that the ultrasonic sensor yields poor resolution for a dispersed oil slug in water flow (D OS/W flow), but the resolution is favorable for dispersed oil in water flow (D O/W flow) and very fine dispersed oil in water flow (VFD O/W flow). This research demonstrates the potential application of a pulsed-transmission ultrasonic method for measuring the fraction of individual components in oil-water two-phase flow with a low mixture velocity and high water cut.

  8. Oil and gas field code master list, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-16

    This document contains data collected through October 1993 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service.

  9. Conversion of Crude Oil to Methane by a Microbial Consortium Enriched From Oil Reservoir Production Waters

    Directory of Open Access Journals (Sweden)

    Carolina eBerdugo-Clavijo

    2014-05-01

    Full Text Available The methanogenic biodegradation of crude oil is an important process occurring in petroleum reservoirs and other oil-containing environments such as contaminated aquifers. In this process, syntrophic bacteria degrade hydrocarbon substrates to products such as acetate, and/or H2 and CO2 that are then used by methanogens to produce methane in a thermodynamically dependent manner. We enriched a methanogenic crude oil-degrading consortium from production waters sampled from a low temperature heavy oil reservoir. Alkylsuccinates indicative of fumarate addition to C5 and C6 n-alkanes were identified in the culture (above levels found in controls, corresponding to the detection of an alkyl succinate synthase gene (assA in the culture. In addition, the enrichment culture was tested for its ability to produce methane from residual oil in a sandstone-packed column system simulating a mature field. Methane production rates of up 5.8 μmol CH4/g of oil/day were measured in the column system. Amounts of produced methane were in relatively good agreement with hydrocarbon loss showing depletion of more than 50% of saturate and aromatic hydrocarbons. Microbial community analysis revealed that the enrichment culture was dominated by members of the genus Smithella, Methanosaeta, and Methanoculleus. However, a shift in microbial community occurred following incubation of the enrichment in the sandstone columns. Here, Methanobacterium sp. were most abundant, as were bacterial members of the genus Pseudomonas and other known biofilm forming organisms. Our findings show that microorganisms enriched from petroleum reservoir waters can bioconvert crude oil components to methane both planktonically and in sandstone-packed columns as test systems. Further, the results suggest that different organisms may contribute to oil biodegradation within different phases (e.g., planktonic versus sessile within a subsurface crude oil reservoir.

  10. The Application of BP Neural Network In Oil-Field

    Directory of Open Access Journals (Sweden)

    Pei-Ying ZHANG

    2013-09-01

    Full Text Available Aiming at the situation that many techniques of production performance analysis acquire lots of data and are expensive considering the computational and human resources, and their applications are limited, this paper puts forward a new method to analyze the production performance of oil-field based on the BP neural network. It builds a dataset with some available measured data such as well logs and production history, then, builds a field-wide production model by neural network technique, a model will be used to predict. The technique is verified, which shows that the predicted results are consistent with the maximum error of rate of oil production lower than 7% and maximum error of rate of water production lower than 5%, having certain application and research value.  

  11. A new Experimental Rig for Oil Burning on Water

    DEFF Research Database (Denmark)

    Brogaard, Nicholas L.; Sørensen, Martin X.; Fritt-Rasmussen, Janne;

    2014-01-01

    A new experimental apparatus, the Crude Oil Flammability Apparatus (COFA), has been developed to study in-situ burning of crude and pure oils spilled on water in a controlled laboratory environment with large water-to-oil ratios. The parameters and phenomena studied for an asphaltic crude oil...

  12. Bird Mortality in Oil Field Wastewater Disposal Facilities

    Science.gov (United States)

    Ramirez, Pedro

    2010-11-01

    Commercial and centralized oilfield wastewater disposal facilities (COWDFs) are used in the Western United States for the disposal of formation water produced from oil and natural gas wells. In Colorado, New Mexico, Utah, and Wyoming, COWDFs use large evaporation ponds to dispose of the wastewater. Birds are attracted to these large evaporation ponds which, if not managed properly, can cause wildlife mortality. The U.S. Fish and Wildlife Service (USFWS) and the U.S. Environmental Protection Agency (EPA) conducted 154 field inspections of 28 COWDFs in Wyoming from March 1998 through September 2008 and documented mortality of birds and other wildlife in 9 COWDFs. Of 269 bird carcasses recovered from COWDFs, grebes (Family Podicipedidae) and waterfowl (Anatidae) were the most frequent casualties. Most mortalities were attributed to oil on evaporation ponds, but sodium toxicity and surfactants were the suspected causes of mortality at three COWDFs. Although the oil industry and state and federal regulators have made much progress in reducing bird mortality in oil and gas production facilities, significant mortality incidents continue in COWDFs, particularly older facilities permitted in the early 1980’s. Inadequate operation and management of these COWDFs generally results in the discharge of oil into the large evaporation ponds which poses a risk for birds and other wildlife.

  13. Influence of fat crystals in the oil phase on stability of oil-in-water emulsions

    NARCIS (Netherlands)

    Boekel, van M.A.J.S.

    1980-01-01

    Coalescence at rest and during flow was studied in emulsions of paraffin oil in water with several surfactants and with crystals of solid paraffin or tristearate in the oil phase. Solid fat in the oil phase was estimated by pulsed nuclear magnetic resonance. Without crystals, oil-in-water emulsions

  14. Deep water invasions in oil fields of the gulf of Mexico: a challenge for the application of environmental isotopes; Invasiones de aguas profundas en yacimientos petroleros del golfo de Mexico: un reto para la aplicacion de isotopos ambientales

    Energy Technology Data Exchange (ETDEWEB)

    Birkle, Peter [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2001-07-01

    It was verified the use of environmental isotopes as a useful method to improve the efficiency of the present exploitation in oil fields of the Gulf of Mexico. In general, the stable isotopes like deuterium, 18 O, 13 C, 37 Cl, 87 Sr and 34 S, support in questions on the origin of waters, its quality, the geochemistry evolution, recharge processes, interaction water-rock, origin of the salinity and contamination processes, whereas the radioactive isotopes (Tritium, 14 C, 36 I and 129 I) provide information on the time of circulation, the origin and the age of underground waters. Since year 1998, the Gerencia de Geotermia of the Instituto de Investigaciones Electricas is making investigation projects in the oil fields of the Actives of Production Luna, Pol-Chuc, Chilpilla-Colomo (all of them in the state of Tabasco) and Cactus-Sitio Grande (Chiapas) in the South Region of PEMEX Exploration and Production (PEP). As primary target of these studies hidrogeological models were developed on the migration and circulation of the fluids in the oil fields with the purpose of limiting the water invasion in producing wells and to increase the crude oil production. [Spanish] Se comprobo el uso de los isotopos ambientales como un metodo util para mejorar la eficiencia de la explotacion actual en yacimientos petroleros del golfo de Mexico. En general, los isotopos estables como deuterio, 18 O, 13 C, 37 Cl, 87 Sr y 34 S, apoyan en cuestiones sobre el origen de las aguas, su calidad, la evolucion geoquimica, procesos de recarga, interaccion agua-roca, origen de la salinidad y procesos de contaminacion, mientras que los isotopos radiactivos (Tritio, 14 C, 36 l Y 129 I) proporcionan informacion sobre el tiempo de circulacion, el origen y la edad de las aguas subterraneas. Desde el ano 1998, la Gerencia de Geotermia del Instituto de Investigaciones Electricas esta realizando proyectos de investigacion en los campos petroleros de los activos de Produccion Luna, Pol-Chuc, Chilpilla

  15. A new nano-engineered hierarchical membrane for concurrent removal of surfactant and oil from oil-in-water nanoemulsion

    Science.gov (United States)

    Qin, Detao; Liu, Zhaoyang; Bai, Hongwei; Sun, Darren Delai; Song, Xiaoxiao

    2016-04-01

    Surfactant stabilized oil-in-water nanoemulsions pose a severe threat to both the environment and human health. Recent development of membrane filtration technology has enabled efficient oil removal from oil/water nanoemulsion, however, the concurrent removal of surfactant and oil remains unsolved because the existing filtration membranes still suffer from low surfactant removal rate and serious surfactant-induced fouling issue. In this study, to realize the concurrent removal of surfactant and oil from nanoemulsion, a novel hierarchically-structured membrane is designed with a nanostructured selective layer on top of a microstructured support layer. The physical and chemical properties of the overall membrane, including wettability, surface roughness, electric charge, thickness and structures, are delicately tailored through a nano-engineered fabrication process, that is, graphene oxide (GO) nanosheet assisted phase inversion coupled with surface functionalization. Compared with the membrane fabricated by conventional phase inversion, this novel membrane has four times higher water flux, significantly higher rejections of both oil (~99.9%) and surfactant (as high as 93.5%), and two thirds lower fouling ratio when treating surfactant stabilized oil-in-water nanoemulsion. Due to its excellent performances and facile fabrication process, this nano-engineered membrane is expected to have wide practical applications in the oil/water separation fields of environmental protection and water purification.

  16. A MODEL FOR PREDICTING PHASE INVERSION IN OIL-WATER TWO-PHASE PIPE FLOW

    Institute of Scientific and Technical Information of China (English)

    GONG Jing; LI Qing-ping; YAO Hai-yuan; YU Da

    2006-01-01

    Experiments of phase inversion characteristics for horizontal oil-water two-phase flow in a stainless steel pipe loop (25.7 mm inner diameter,52 m long) are conducted. A new viewpoint is brought forward about the process of phase inversion in oil-water two-phase pipe flow. Using the relations between the total free energies of the pre-inversion and post-inversion dispersions, a model for predicting phase inversion in oil-water two-phase pipe flow has been developed that considers the characteristics of pipe flow. This model is compared against other models with relevant data of phase inversion in oil-water two-phase pipe flow. Results indicate that this model is better than other models in terms of calculation precision and applicability. The model is useful for guiding the design for optimal performance and safety in the operation of oil-water two-phase pipe flow in oil fields.

  17. Field observations of artificial sand and oil agglomerates

    Science.gov (United States)

    Dalyander, Patricia (Soupy); Long, Joseph W.; Plant, Nathaniel G.; McLaughlin, Molly R.; Mickey, Rangley C.

    2015-01-01

    Oil that comes into the surf zone following spills, such as occurred during the 2010 Deepwater Horizon (DWH) blowout, can mix with local sediment to form heavier-than-water sand and oil agglomerates (SOAs), at times in the form of mats a few centimeters thick and tens of meters long. Smaller agglomerates that form in situ or pieces that break off of larger mats, sometimes referred to as surface residual balls (SRBs), range in size from sand-sized grains to patty-shaped pieces several centimeters (cm) in diameter. These mobile SOAs can cause beach oiling for extended periods following the spill, on the scale of years as in the case of DWH. Limited research, including a prior effort by the U.S. Geological Survey (USGS) investigating SOA mobility, alongshore transport, and seafloor interaction using numerical model output, focused on the physical dynamics of SOAs. To address this data gap, we constructed artificial sand and oil agglomerates (aSOAs) with sand and paraffin wax to mimic the size and density of genuine SOAs. These aSOAs were deployed in the nearshore off the coast of St. Petersburg, Florida, during a field experiment to investigate their movement and seafloor interaction. This report presents the methodology for constructing aSOAs and describes the field experiment. Data acquired during the field campaign, including videos and images of aSOA movement in the nearshore (1.5-meter and 0.5-meter water depth) and in the swash zone, are also presented in this report.

  18. Destruction of secondary water-oil emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Abashev, R.G.; Isayev, M.G.; Nikolayeva, T.M.; Zheryakova, N.I.

    1984-01-01

    The article advances a number of requirements for the object, methods and means of destroying secondary water-oil emulsions (WOE) which currently cannot be recovered. By using the latest advances in science: chemistry of oil and surfactants, physicochemical surface phenomena, physical mechanics of dispersed systems, hydrodynamics and engineering chemistry jointly with the fundamentals of economics, efficient solutions are indicated for stabilization of the composition and property of WOE, and their destruction in a stationary technological process. A flowsheet is established for the recommended technology.

  19. Dielectric Properties of Flocculated Water-in-Oil Emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Skodvin, T.

    1995-12-31

    When an offshore oil field is near completion, water occupies a large fraction of the available pore volume. Thus, in collecting the oil and gas reserves, one has to deal with a high co-production of either formation- or injected water. This doctoral thesis focuses on the effect of water-in-oil emulsions on the dielectric properties, in particular the effect of flocculation. Various dielectric models are applied to obtain methods for qualitative and quantitative characterization of the flocculated state. Permittivity and measurement of dielectric properties are discussed as a basis for the interpretation of the dielectric properties of the emulsions. Various flocculation models are presented. It is concluded that the dielectric properties of water-in-oil emulsions are strongly influenced by continuously ongoing processes in the system. Because of flocculation and sedimentation the traditional dielectric mixture models cannot satisfactorily predict the dielectric behaviour. The experimentally obtained permittivities for the emulsions can be reproduced by including flocculation in the models and treating the floc aggregates as spheroids or subsystems with dielectric properties given by the degree of flocculation. The models discussed have difficulties reproducing the complete frequency behaviour found experimentally. This is probably because the dielectric relaxation may be influenced by processes not included in the models, such as the effects of dipolar or multipolar interactions between the droplets. For further research it is recommended that rheological and dielectric measurements be combined. 227 refs., 61 figs., 16 tabs.

  20. Accounting for the waterless period of oil production in calculations on oil field production design

    Energy Technology Data Exchange (ETDEWEB)

    Aminov, M.F.; Butorin, O.I.

    1981-01-01

    Formulae on the dynamics of oil and liquid from a methodology developed by the Tatar Scientific-Research and Design Institute for the Oil Industry are adjusted, accounting for the waterless period in oil production. It is demonstrated that the process of accounting for the waterless period in oil production leads to a more accurate prediction of the engineering parameters for mining and oil field.

  1. Models of optimal technology for removing oil by secondary methods of developing highly viscous oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Jewulski, J.

    1982-01-01

    This paper presents research on developing several methods of optimal technology for removing oil in highly viscous oil fields from the following wells: Lubno-3, Kharklova-Gvaretstvo 154 and Vetzhno (heavy oil). The problem connected with preparing the displacement fluids, with special emphasis on the authors patented technology for producing micellar solutions are discussed. The studies of dislocation fluids (including modified ones) were conducted at 3 temperatures: 293, 308, and 323/sup 0/K and with and without micellar solutions. The tests were used to idetify static regressive models of oil removal from oil fields. The model is satisfactorily accurate in predicting the amount of oil yield by using various secondary methods. Practical conclusions are reached based on an analysis of the studies. These conclusions provide the basis for industrial tests to increase the effectiveness of waterflooding highly viscous oil fields. They can also be used to develop old (gased) oil fields, an advantage considering the current fuel-energy situation.

  2. 40 CFR 63.686 - Standards: Oil-water and organic-water separators.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Standards: Oil-water and organic-water... Operations § 63.686 Standards: Oil-water and organic-water separators. (a) The provisions of this section apply to the control of air emissions from oil-water separators and organic-water separators for...

  3. Assessment of microorganisms from Indonesian Oil Fields

    Energy Technology Data Exchange (ETDEWEB)

    Kadarwati, S.; Udiharto, M.; Rahman, M.; Jasjfi, E.; Legowo, E.H. [Research and Development Centre for Oil and Gas Technology LEMIGAS, Jakarta Selatan (Indonesia)

    1995-12-31

    Petroleum resources have been the mainstay of the national development in Indonesia. However, resources are being depleted after over a century of exploitation, while the demand continues to grow with the rapid economic development of the country. In facing the problem, EOR has been applied in Indonesia, such as the steamflooding project in Duri field, but a more energy efficient technology would be preferable. Therefore, MEOR has been recommended as a promising solution. Our study, aimed at finding indigenous microorganisms which can be developed for application in MEOR, has isolated microbes from some oil fields of Indonesia. These microorganisms have been identified, their activities studied, and the effects of their metabolisms examined. This paper describes the research carried out by LEMIGAS in this respect, giving details on the methods of sampling, incubation, identification, and activation of the microbes as well as tests on the effects of their metabolites, with particular attention to those with potential for application in MEOR.

  4. Water injection in various fields of Argentina

    Energy Technology Data Exchange (ETDEWEB)

    1969-10-01

    Two successful pilot flood tests conducted in the Argentine oil fields have been sufficiently successful to indicate to Yacimientos Petroliferos Fiscales (YPF) that many other fields having similar reservoir characteristics would respond well to waterflooding. In 1966, YPF contracted with companies specializing in secondary recovery to make a study of these 4 reservoirs: Canadon Leon, in Santa Cruz, to the south of Comodoro Rivadavia; Barrancas South, in Mendoza; and El Sauce and Cerro Bandera, both in Neuquen (as indicated on the base map). These studies revealed which of the formations were most likely to respond to water injection. For Canadon Leon and Barrancas, pilot operations were recommended, while for the others, water injection on a large scale was recommended. The scheme of large-scale waterflooding for Cerro Bandera (Neuquen) and El Sauce (Neuquen) is illustrated. In Canadon Leon and Barrancas alone, secondary recovery is expected to increase the oil recovery to around 3,500,000 bbl; of this total 1,327,282 is primary and 2,190,000 is secondary recovery. Tabular data show the anticipated results of water injection in the 4 studied fields.

  5. Application of Lean Tools in the Oil Field Safety Management

    Directory of Open Access Journals (Sweden)

    Jinze Song

    2016-11-01

    Full Text Available Current safety management in oil fields is in low efficiency and data from DOE indicated that the injury rate in the oil and gas field was greater than those for all the other U.S. industries. The paperintroduced lean concepts and tools to the safety management in oil fields. In theresearch, a new safety management methodology has been set up. The study also compared the current safety management and the new safety management which was built up by lean concepts. In addition, several lean tools have been modified to make them fit and work better in oil fields.

  6. Studies on water-in-oil products from crude oils and petroleum products.

    Science.gov (United States)

    Fingas, Merv; Fieldhouse, Ben

    2012-02-01

    Water-in-oil mixtures such as emulsions, often form and complicate oil spill countermeasures. The formation of water-in-oil mixtures was studied using more than 300 crude oils and petroleum products. Water-in-oil types were characterized by resolution of water at 1 and 7 days, and some after 1 year. Rheology measurements were carried out at the same intervals. The objective of this laboratory study was to characterize the formed water-in-oil products and relate these properties to starting oil properties. Analysis of the starting oil properties of these water-in-oil types shows that the existence of each type relates to the starting oil viscosity and its asphaltene and resin contents. This confirms that water-in-oil emulsification is a result of physical stabilization by oil viscosity and chemical stabilization by asphaltenes and resins. This stabilization is illustrated using simple graphical techniques. Four water-in-oil types exist: stable, unstable, meso-stable and entrained. Each of these has distinct physical properties. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. A new Experimental Rig for Oil Burning on Water

    DEFF Research Database (Denmark)

    Brogaard, Nicholas L.; Sørensen, Martin X.; Fritt-Rasmussen, Janne

    2014-01-01

    A new experimental apparatus, the Crude Oil Flammability Apparatus (COFA), has been developed to study in-situ burning of crude and pure oils spilled on water in a controlled laboratory environment with large water-to-oil ratios. The parameters and phenomena studied for an asphaltic crude oil...... was heated. Similar results were found regarding the flame height which reached a steady flame height. The pure fuels, n-Octane and dodecane, produced a much higher steady flame height than the crude oil, however they did not reach boilover, though dodecane showed boilover tendencies. Theoretical predictions...... of in-situ burning as an alternative response technique for oil spills on water....

  8. Discrimination of fish oil and mineral oil slicks on sea water

    Science.gov (United States)

    Mac Dowall, J.

    1969-01-01

    Fish oil and mineral oil slicks on sea water can be discriminated by their different spreading characteristics and by their reflectivities and color variations over a range of wavelengths. Reflectivities of oil and oil films are determined using a duel beam reflectance apparatus.

  9. Drag Reduction in Oil-water Flows

    OpenAIRE

    Edomwonyi-Otu, L. C.

    2015-01-01

    Liquid-liquid flows occur in many chemical and process industries including the petroleum industry where crude oil and its derivatives are transported over long distances often in mixtures with water. Depending on flow conditions and pipe geometry different flow patterns can appear ranging from fully separated to dispersed ones. The addition of small amounts of some polymeric materials to one of the phases has been found to change the flow patterns and their boundaries and reduce the friction...

  10. 黄原胶/AMPS/膨润土制备油田堵水剂的研究%Synthesis of Xanthan Gum/AMPS/Bentonite Composite Water Plugging Agent for Oil Field

    Institute of Scientific and Technical Information of China (English)

    李辉; 李宇剑

    2011-01-01

    通过水溶液法制备了一种黄原胶/2-丙烯酰胺基-2-甲基丙磺酸(AMPS)/膨润土三元复合型油田堵水剂,考察了2-丙烯酰胺基-2-甲基丙磺酸、膨润土、交联剂以及引发剂质量分数等因素对堵水剂吸水率的影响,测试了不同温度下堵水剂的吸水倍率和保水值,研究了堵水剂对不同质量分数NaCl溶液的吸水性能.结果表明,最佳的制备工艺:膨润土的质量分数为15%,AMPS的质量分数为3%,交联剂的的质量分数为2%,引发剂的质量分数为2.5%,在60℃的温度下反应4h,在最佳工艺下,环境温度20℃时,堵水剂的吸去离子水的倍率最高达到1 677 g/g,吸质量分数0.9%NaCl溶液的倍率为165 g/g;环境温度80℃的高温下仍保持着1 590 g/g的吸水倍率,12 h后仍能保水20%以上,具有良好的热稳定性和耐盐性.%Xanthan gum(XG)/2 - acrylamido - 2 - methylpropanesulfonic acid (AMPS)/bentonite composite water plugging agent for oil field was synthesized by aqueous solution polymerization. Effect of the amount of AMPS, bentonite, crosslinking agent and initiator on waterabsorption capacity of water shutoff agent were investigated. Waterabsorbency and water retaining rate of the water shutoff agent at different temperature were tested. NaCl concentration on waterabsorption capacity of water shutoff agent were researched. The results show that the optimum process conditions were obtained as follows; ω(bentonite) is 15%, ω( AMPS) is 3% , ω(crosslinking agent) is 2%, ω(initiator) is 2. 5% , and reaction temperature is 40 ℃ for 4 hours. Under the optimum technological conditions, with the environmental temperature of 20 ℃ , waterabsorbency for deionized water and 0. 9% NaCl solution of the water plugging agent for oil field are respectively 1 677 g/g, 165 g/g. With the environmental temperature of 80 ℃, waterabsorbency for deionized water of the water plugging agent for oil field are respectively 1 590 g/g, within 12 h

  11. Saudi Aramco: Oil to a Thirsty Market - International Cooperation Brings New Oil Field on Quickly

    Energy Technology Data Exchange (ETDEWEB)

    Al-Ajmi, Ali

    2007-07-01

    In response to high oil demand in 2004, Saudi Aramco committed to build facilities for the 500,000 BOPD Khursaniyah Oil Field in only 34 months from the start of preliminary engineering to startup. The project schedule was six months faster than any previous project, in the most resource competitive market the oil business has ever seen. The execution of this project required a new contract strategy, novel engineering and construction methods, and international cooperation from EPC firms and manufacturers. The project is also building a new one billion SCF per day gas plant receiving gas from five different sources with varying pressure and H2S content, along with huge water supply and injection facilities, oil gathering lines, and product distribution lines. To execute the project in this short time frame, a temporary construction city for 30,000 men has been constructed in the desert. This city has workers from all over 30 countries, speaking more than 15 languages, all focused on achieving one goal - on time completion of the most complex project ever done in Saudi Arabia. The paper will focus on the unique challenges of managing a city of this size that lasts for only 24 months. (auth)

  12. Saudi Aramco: Oil to a Thirsty Market - International Cooperation Brings New Oil Field on Quickly

    Energy Technology Data Exchange (ETDEWEB)

    Al-Ajmi, Ali

    2007-07-01

    In response to high oil demand in 2004, Saudi Aramco committed to build facilities for the 500,000 BOPD Khursaniyah Oil Field in only 34 months from the start of preliminary engineering to startup. The project schedule was six months faster than any previous project, in the most resource competitive market the oil business has ever seen. The execution of this project required a new contract strategy, novel engineering and construction methods, and international cooperation from EPC firms and manufacturers. The project is also building a new one billion SCF per day gas plant receiving gas from five different sources with varying pressure and H2S content, along with huge water supply and injection facilities, oil gathering lines, and product distribution lines. To execute the project in this short time frame, a temporary construction city for 30,000 men has been constructed in the desert. This city has workers from all over 30 countries, speaking more than 15 languages, all focused on achieving one goal - on time completion of the most complex project ever done in Saudi Arabia. The paper will focus on the unique challenges of managing a city of this size that lasts for only 24 months. (auth)

  13. The analysis of repeated failures of pipelines in Kal'chinskoe oil field

    Science.gov (United States)

    Shavlov, E. N.; Brusnik, O. V.; Lukjanov, V. G.

    2016-09-01

    The paper presents the chemical analysis of oilfield water and hydraulic analysis of the liquid flow in Kal'chinskoe oil field pipeline that allow detecting the causes of the internal corrosion processes. The inhibitor protection is suggested to reduce the corrosion rate in the pipelines of Kal'chinskoe oil field. Based on the analysis of the pipeline failures, it is suggested to replace steel pipes by fiberglass pipes.

  14. Assessment of potential increased oil production by polymer-waterflood in northern and southern mid-continent oil fields. Progress report for the quarter ending December 31, 1978

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    Six tasks are reported on: geological and engineering study of the DOE-Kewanee polymer-augmented waterflood, review of polymer injection program in this field, evaluation of results of polymer-augmented waterflood in this field, review of geological and engineering characteristics of oil fields now in waterflood as candidates for polymer augmentation, review of fields currently under primary production, and determination of ranges of future increased oil production from the polymer-water process in the project area.

  15. Numerical Study of Water Control with Downhole Oil-Water Separation Technology

    Directory of Open Access Journals (Sweden)

    Yin Khor Yin

    2014-07-01

    Full Text Available The maturing oil fields with increasing water production can pose a challenging produced water handling and disposal issues. This paper presents a numerical study of a motorless hydrocyclone to enhance understanding of the downhole oil-water separation. The turbulence of fluid flow is obtained using K-ε Realizable Turbulence model for complex swirl dominated flow, while the interface between hydrocarbon and water is described using the Discrete Phase model. In this approach, factors which contribute to the hydrocyclone separation instability were discussed. Discussion is then extended to the relationship of residence time with pressure difference between overflow and underflow. These pressure differences are able to relate to pressure condition for high water cut well which require downhole separation.

  16. New Method of Online Measurement of Oil and Suspended Material Concentration In Flowing Waste Water

    Science.gov (United States)

    Liao, Hongwei; Xu, Guobing; Xu, Xinqiang; Zhou, Fangde

    2007-06-01

    At present, the most of the measurements of oil and suspended material concentration in waste water measuring are not online surveys. A new method of online measurement of oil and suspended material concentration in flowing waste water is presented. The room experiments and field tests showed that it is suitable to waste water treatment on line. After sampling, It needed to measure immediately the concentration in first time. Then let sample to be in still in 10 - 20 seconds. After that the bulk concentration was measured in second time. Because of the suspended solids having heavy density, they would be dropped from waster water. During ultrasonic operation, emulsify the oil in waster water, the oil and suspended solid would be depart. After that the third time measurement was done. In thus way the concentrations of oil and suspended solids can be measured. At present there are two on-site equipments operating in the Changqing oilfield, and the results are pretty well.

  17. Rheological properties of crude oils in Yaregskoye and Yaraktinskoye oil fields

    Science.gov (United States)

    Manzhai, V. N.; Le Grand Monkam Monkam, Clovis; Terre, D. A.

    2016-09-01

    Rotary viscometer tests of crude oil with a high content of resins and asphaltenes (Yaregskoye oil field) and crude oil with high paraffin content (Yaraktinskoye oil field) have been conducted. The typical flow curves for these oil types have been plotted. It has been detected that these oils are non-Newtonian fluids, viscosity of which is dependent on shear rate. Based on Arrhenius-Eyring equation, calculations of viscous flow activation energy and complex structural unit (CSU) sizes have been performed. It has been stated that there is a tenfold reduction in CSU size in asphaltic crude oil with the increase in shear rate in a rotary viscometer, while particle size in paraffinic crude oil does not essentially change under the same hydrodynamic conditions.

  18. Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature.

    Science.gov (United States)

    Wang, Ben; Liang, Weixin; Guo, Zhiguang; Liu, Weimin

    2015-01-07

    Oil spills and industrial organic pollutants have induced severe water pollution and threatened every species in the ecological system. To deal with oily water, special wettability stimulated materials have been developed over the past decade to separate oil-and-water mixtures. Basically, synergy between the surface chemical composition and surface topography are commonly known as the key factors to realize the opposite wettability to oils and water and dominate the selective wetting or absorption of oils/water. In this review, we mainly focus on the development of materials with either super-lyophobicity or super-lyophilicity properties in oil/water separation applications where they can be classified into four kinds as follows (in terms of the surface wettability of water and oils): (i) superhydrophobic and superoleophilic materials, (ii) superhydrophilic and under water superoleophobic materials, (iii) superhydrophilic and superoleophobic materials, and (iv) smart oil/water separation materials with switchable wettability. These materials have already been applied to the separation of oil-and-water mixtures: from simple oil/water layered mixtures to oil/water emulsions (including oil-in-water emulsions and water-in-oil emulsions), and from non-intelligent materials to intelligent materials. Moreover, they also exhibit high absorption capacity or separation efficiency and selectivity, simple and fast separation/absorption ability, excellent recyclability, economical efficiency and outstanding durability under harsh conditions. Then, related theories are proposed to understand the physical mechanisms that occur during the oil/water separation process. Finally, some challenges and promising breakthroughs in this field are also discussed. It is expected that special wettability stimulated oil/water separation materials can achieve industrial scale production and be put into use for oil spills and industrial oily wastewater treatment in the near future.

  19. Oil and Gas Field Code Master List 1990

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-04

    This is the ninth annual edition of the Energy Information Administration's (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1990 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. There are 54,963 field records in this year's Oil and Gas Field Code Master List (FCML). This amounts to 467 more than in last year's report. As it is maintained by EIA, the Master List includes: Field records for each state and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides;field records for each alias field name; fields crossing state boundaries that may be assigned different names by the respective state naming authorities.

  20. Bioinspired oil strider floating at the oil/water interface supported by huge superoleophobic force.

    Science.gov (United States)

    Liu, Xueli; Gao, Jun; Xue, Zhongxin; Chen, Li; Lin, Ling; Jiang, Lei; Wang, Shutao

    2012-06-26

    Oil pollution to aquatic devices, especially to those oil-cleaning devices and equipment-repairing robots during oil spill accidents, has drawn great attention and remains an urgent problem to be resolved. Developing devices that can move freely in an oil/water system without contamination from oil has both scientific and practical importance. In nature, the insect water strider can float on water by utilizing the superhydrophobic supporting force received by its legs. Inspired by this unique floating phenomenon, in this article, we designed a model device named "oil strider" that could float stably at the oil/water interface without contamination by oil. The floating capability of the oil strider originated from the huge underwater superoleophobic supporting force its "legs" received. We prepared the micro/nanohierarchical structured copper-oxide-coated copper wires, acting as the artificial legs of oil strider, by a simple base-corrosion process. The surface structures and hydrophilic chemical components of the coatings on copper wires induced the huge superoleophobic force at the oil/water interface, to support the oil strider from sinking into the oil. Experimental results and theoretical analysis demonstrate that this supporting force is mainly composed of three parts: the buoyancy force, the curvature force, and the deformation force. We anticipate that this artificial oil strider will provide a guide for the design of smart aquatic devices that can move freely in an oil/water system with excellent oil repellent capability, and be helpful in practical situations such as oil handling and oil spill cleanup.

  1. Experimental study of flow patterns and pressure drops of heavy oil-water-gas vertical flow

    Institute of Scientific and Technical Information of China (English)

    LIU Xi-mao; ZHONG Hai-quan; LI Ying-chuan; LIU Zhong-neng; WANG Qi

    2014-01-01

    A stainless steel apparatus of 18.5 m high and 0.05 m in inner diameter is developed, with the heavy oil from Lukeqin Xinjiang oil field as the test medium, to carry out the orthogonal experiments for the interactions between heavy oil-water and heavy oil-water-gas. With the aid of observation windows, the pressure drop signal can be collected and the general multiple flow patterns of heavy oil-water-gas can be observed, including the bubble, slug, churn and annular ones. Compared with the conventional oil, the bubble flows are identified in three specific flow patterns which are the dispersed bubble (DB), the bubble gas-bubble heavy oil go(B-B), and the bubble gas-intermittent heavy oilgo(B-I). The slug flows are identified in two specific flow patterns which are the intermittent gas-bubble heavy oilgo(I-B)and the intermittent gas-intermittent heavy oilgo(I-I). Compared with the observa- tions in the heavy oil-water experiment, it is found that the conventional models can not accurately predict the pressure gradient. And it is not water but heavy oil and water mixed phase that is in contact with the tube wall. So, based on the principle of the energy con- servation and the kinematic wave theory, a new method is proposed to calculate the frictional pressure gradient. Furthermore, with the new friction gradient calculation method and a due consideration of the flow characteristics of the heavy oil-water-gas high speed flow, a new model is built to predict the heavy oil-water-gas pressure gradient. The predictions are compared with the experiment data and the field data. The accuracy of the predictions shows the rationality and the applicability of the new model.

  2. Infrared polarimetric sensing of oil on water

    Science.gov (United States)

    Chenault, David B.; Vaden, Justin P.; Mitchell, Douglas A.; DeMicco, Erik D.

    2016-10-01

    Infrared polarimetry is an emerging sensing modality that offers the potential for significantly enhanced contrast in situations where conventional thermal imaging falls short. Polarimetric imagery leverages the different polarization signatures that result from material differences, surface roughness quality, and geometry that are frequently different from those features that lead to thermal signatures. Imaging of the polarization in a scene can lead to enhanced understanding, particularly when materials in a scene are at thermal equilibrium. Polaris Sensor Technologies has measured the polarization signatures of oil on water in a number of different scenarios and has shown significant improvement in detection through the contrast improvement offered by polarimetry. The sensing improvement offers the promise of automated detection of oil spills and leaks for routine monitoring and accidents with the added benefit of being able to continue monitoring at night. In this paper, we describe the instrumentation, and the results of several measurement exercises in both controlled and uncontrolled conditions.

  3. Identifying Oil, Oil-water and Water Reservoirs by the Method of Grey Poly-category

    Institute of Scientific and Technical Information of China (English)

    Lu Huangsheng

    1994-01-01

    @@ Grey Poly-category is a branch of Grey System belonging to System Theory. According to the System Theory, a fully determinable figure is called White Figure, a fully undeterminable figure is called Black Figure, and the figure between them is called Grey Figure. On the same principle, a fully determinable system,a fully undeterminable, and a partial determinable and partial undeterminable system are called White, Black and Grey System respectively. For the oil, oil-water and water reservoirs, each type of reservoirs has its different log response values. These values are grey figures, not a fixed figure, and then, the system made of the figures is a Grey System.

  4. Development and characterization of ultra lightweight, highly selective, filter media for oil-water mixtures

    Science.gov (United States)

    Baghernejad, Lida

    Emulsions formed by oil-water mixtures can cause serious issues at different stages of crude oil production, produced water remediation, and oil spills. Efficient, cost-effective processes for separation of oil--water emulsions or dispersions are critical and highly desirable. Filters are among the most common means employed to separate oil-water emulsions into their corresponding components. To conduct single step gravity-based or centrifugal separation of oil--water mixtures into their pure phase, it is essential that the filter be hydrophilic and oleophobic both in air and water. The filter medium should also have high surface porosity, which affects the rate of permeation of one phase. It should be stable at operating temperatures and pressures and be resistant to degradation by chemicals in the feed stream. Favorable oil rejection characteristics, resistance to fouling by organic and inorganic foulants and low cost of production are also important. The goal of this project is to develop ultra-lightweight filters that are durable, highly porous and able to selectively separate oil-water mixtures, from non-woven cellulose based materials by electrospinning. Since electrospinning is a cost-effective, scalable method that can be used to fabricate filters with very thin nanoscale fibers and nano-dimension pores, and cellulose is a very cheap and abundant ingredient, these filters may be considered as novel tools for efficient, cost-effective separation of oil-water emulsions in industry. Currently there is a growing demand for highly porous selective filters for oil-water mixtures in the petroleum industry. These filters are beneficial to both manufacturers and consumers. This research focuses on the development and characterization of the new filter material and evaluation of its suitability for oil-water separation in the field.

  5. Sustainable water management in Alberta's oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Byers, Bill; Usher, Robyn; Roach, Andrea [CH2M HILL, Englewood, CO (United States); Lambert, Gord; Kotecha, Prit [Suncor Energy Inc., Calgary (Canada)

    2012-07-01

    The Canadian Association of Petroleum Producers forecast published in 2011 predicts that oil production from oil sands will increase by 50% in the next 3 years and double by 2020. This rate of growth will result in significant pressure on water resources; water use per barrel of oil sands production is comparable to other energy resources - about 2.5 barrels of fresh water per barrel of oil produced are used by mining operations and 0.5 barrels by in-situ operations. Suncor Energy Inc. (Suncor) was the first company to develop the oil sands in northern Alberta and holds one of the largest oil sands positions in Canada. In 2010, Suncor announced plans to increase production to more than 1 million barrels of oil equivalent per day by 2020, which it plans to achieve through oil sands production growth of approximately 10% per year. Because water supply and potential impacts to water quality are critical to its future growth, in 2010-2011 Suncor conducted a risk assessment to identify water-related business risks related to its northern Alberta operations. The assessment identified more than 20 high level business risks in strategic water risk areas including water supply, water reuse, storm water management, groundwater, waste management and river water return. The risk assessment results prompted development of a strategic roadmap to guide water stewardship across Suncor's regional operations. The roadmap describes goals, objectives, and specific activities for each of six key water risk areas, and informs prioritization and selection of prospective water management activities. Suncor is not only exploring water within its own boundaries, but is also collaborating with other oil sands producers to explore ways of integrating its water systems through industry consortia; Suncor is a member of the Oil Sands Leadership Initiative and of the recently formed Canadian Oil Sands Innovation Alliance, among others. (author)

  6. Field testing the prototype BNL fan-atomized oil burner

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, R.; Celebi, Y. [Brookhaven National Lab., Upton, NY (United States)

    1995-04-01

    BNL has developed a new oil burner design referred to as the Fan Atomized burner System. The primary objective of the field study was to evaluate and demonstrate the reliable operation of the Fan Atomized Burner. The secondary objective was to establish and validate the ability of a low firing rate burner (0.3-0.4 gph) to fully satisfy the heating and domestic hot water load demands of an average household in a climate zone with over 5,000 heating-degree-days. The field activity was also used to evaluate the practicality of side-wall venting with the Fan Atomized Burner with a low stack temperature (300F) and illustrate the potential for very high efficiency with an integrated heating system approach based on the Fan Atomized Burner.

  7. Treatment of Oil & Gas Produced Water.

    Energy Technology Data Exchange (ETDEWEB)

    Dwyer, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-02-01

    Production of oil and gas reserves in the New Mexico Four Corners Region results in large volumes of "produced water". The common method for handling the produced water from well production is re-injection in regulatory permitted salt water disposal wells. This is expensive (%7E $5/bbl.) and does not recycle water, an ever increasingly valuable commodity. Previously, Sandia National Laboratories and several NM small business tested pressure driven membrane-filtration techniques to remove the high TDS (total dissolved solids) from a Four Corners Coal Bed Methane produced water. Treatment effectiveness was less than optimal due to problems with pre-treatment. Inadequate pre-treatment allowed hydrocarbons, wax and biological growth to foul the membranes. Recently, an innovative pre-treatment scheme using ozone and hydrogen peroxide was pilot tested. Results showed complete removal of hydrocarbons and the majority of organic constituents from a gas well production water. ACKNOWLEDGEMENTS This report was made possible through funding from the New Mexico Small Business Administration (NMSBA) Program at Sandia National Laboratories. Special thanks to Juan Martinez and Genaro Montoya for guidance and support from project inception to completion. Also, special thanks to Frank McDonald, the small businesses team POC, for laying the ground work for the entire project; Teresa McCown, the gas well owner and very knowledgeable- fantastic site host; Lea and Tim Phillips for their tremendous knowledge and passion in the oil & gas industry.; and Frank Miller and Steve Addleman for providing a pilot scale version of their proprietary process to facilitate the pilot testing.

  8. Molecular dynamics study of water molecule diffusion in oil-paper insulation materials

    Science.gov (United States)

    Liao, Rui-Jin; Zhu, Meng-Zhao; Yang, Li-Jun; Zhou, Xin; Gong, Chun-Yan

    2011-03-01

    Moisture is an important factor that influences the safe operation of transformers. In this study, molecular dynamics was employed to investigate the diffusion behavior of water molecules in the oil-paper insulation materials of transformers. Two oil-cellulose models were built. In the first model, water molecules were initially distributed in oil, and in the second model, water molecules were distributed in cellulose. The non-bonding energies of interaction between water molecules and oil, and between water molecules and cellulose, were calculated by the Dreiding force field. The interaction energy was found to play a dominant role in influencing the equilibrium distribution of water molecules. The radial direction functions of water molecules toward oil and cellulose indicate that the hydrogen bonds between water molecules and cellulose are sufficiently strong to withstand the operating temperature of the transformer. Mean-square displacement analysis of water molecules diffusion suggests that water molecules initially distributed in oil showed anisotropic diffusion; they tended to diffuse toward cellulose. Water molecules initially distributed in cellulose diffused isotropically. This study provides a theoretical contribution for improvements in online monitoring of water in transformers, and for subsequent research on new insulation materials.

  9. Interfacial properties of dissolved crude oil components in produced water

    OpenAIRE

    Eftekhardadkhah, Mona

    2013-01-01

    Produced water is a mixture of water trapped in underground formations and injection water that is brought to the surface along with oil or gas. In general, produced water is a mixture of dispersed oil in water (o/w), dissolved organic compounds (including hydrocarbons), residual concentration of chemical additives from the production line, heavy metals, dissolved minerals and suspended solids.In the year 2011, 131 million m3 of produced water were discharged on the Norwegian Continental Shel...

  10. Predicting for thermodynamic instabilities in water/oil/surfactant microemulsions: A mesoscopic modelling approach

    Energy Technology Data Exchange (ETDEWEB)

    Duvail, Magali, E-mail: magali.duvail@icsm.fr; Zemb, Thomas; Dufrêche, Jean-François [Institut de Chimie Séparative de Marcoule (ICSM), UMR 5257, CEA-CNRS-Université Montpellier 2-ENSCM, Site de Marcoule, Bâtiment 426, BP 17171, F-30207 Bagnols-sur-Cèze Cedex (France); Arleth, Lise [Niels Bohr Institute, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark)

    2014-04-28

    The thermodynamics and structural properties of flexible and rigid nonionic water/oil/surfactant microemulsions have been investigated using a two level-cut Gaussian random field method based on the Helfrich formalism. Ternary stability diagrams and scattering spectra have been calculated for different surfactant rigidities and spontaneous curvatures. A more important contribution of the Gaussian elastic constants compared to the bending one is observed on the ternary stability diagrams. Furthermore, influence of the spontaneous curvature of the surfactant points out a displacement of the instability domains which corresponds to the difference between the spontaneous and effective curvatures. We enlighten that a continuous transition from a connected water in oil droplets to a frustrated locally lamellar (oil in water in oil droplets) microstructure is found to occur when increasing the temperature for an oil-rich microemulsion. This continuous transition translated in a shift in the scattering functions, points out that the phase inversion phenomenon occurs by a coalescence of the water droplets.

  11. Transporting of a Cell-Sized Phospholipid Vesicle Across Water/Oil Interface

    CERN Document Server

    Hase, M; Hamada, T; Yoshikawa, K; Hase, Masahiko; Yamada, Ayako; Hamada, Tsutomu; Yoshikawa, Kenichi

    2006-01-01

    When a cell-sized water droplet, with a diameter of several tens of micro meter, is placed in oil containing phospholipids, a stable cell-sized vesicle is spontaneously formed as a water-in-oil phospholipid emulsion (W/O CE) with a phospholipid monolayer. We transferred the lipid vesicle thus formed in the oil phase to the water phase across the water/oil interface by micromanipulation, which suggests that the vesicle is transformed from a phospholipid monolayer as W/O CE into a bilayer. The lipid vesicle can then be transported back into the oil phase. This novel experimental procedure may be a useful tool for creating a model cellular system, which, together with a microreactor, is applicable as a micrometer-scale biochemical reaction field.

  12. Effect of Substrate-Water Interaction on the Wetting Behavior in Water-Oil and Substrate-Water-Oil Systems

    Institute of Scientific and Technical Information of China (English)

    Yuan Yin-quan; Zou Xian-wu; Jin Zhun-zhi

    2003-01-01

    The effects of the substrate-water interaction on the wetting behavior in water-oil and surfactant-water-oil systems confined by one substrate which has the preferential interaction to one species of particles have been investigated by using the free energy analysis and discontinuous molecular dynamic simulations. As the preferential interaction between the substrate and water particles varies from small repulsion to large attraction, the partial drying, partial wetting and complete wetting state are observed in sequence. In addition, the wetting behavior of surfactant aqueous solution on the substrate is not only dependent on the interaction, but also limited by the maximum equilibrium concentration of surfactants at the interface.

  13. Effect of Substrate-Water Interaction on the Wetting Behavior in Water-Oil and Substrate-Water-Oil Systems

    Institute of Scientific and Technical Information of China (English)

    YuanYin-quan; ZouXian-wu; JinZhun-zhi

    2003-01-01

    The effects of the substrate-water interaction on the wetting behavior in water-oil and surfactant-water-oil systerns confined by one substrate which has the preferential interaction to one species of particles have been investigated by using the free energy analysis and discontinuous molecular dynamic simulations. As the preferential interaction between the substrate and water particles varies from small repulsion to large attraction, the partial drying, partial wetting and complete wetting state are observed in sequence. In addition, the wetting behavior of surfactant aqueous solution on the substrate is not only dependent on the interaction, but also limited by the maximum equilibrium concentration of surfactants at the interface.

  14. The feasibility of pneumatic and water spray barriers as fireproof oil slick containment devices

    Energy Technology Data Exchange (ETDEWEB)

    Comfort, G.; Menon, B.; Purves, W.

    An Artec Canada, Ltd., project assessed the feasibility of using submerged pneumatic barriers and elevated water spray barriers to retain and concentrate a floating oil slick. Maximum wave, wind, and current conditions at which the barriers were able to operate as oil slick containment devices were measured. Various fluid flow rates and barrier configurations were tested. An examination of data and available literature indicate that, in terms of oil slick containment, the water spray barrier is superior to the pneumatic barrier. The construction and field testing of a prototype water spray barrier system should be initiated. (2 diagrams, 7 graphs, 3 tables)

  15. Coreflood assay using extremophile microorganisms for recovery of heavy oil in Mexican oil fields.

    Science.gov (United States)

    Castorena-Cortés, Gladys; Roldán-Carrillo, Teresa; Reyes-Avila, Jesús; Zapata-Peñasco, Icoquih; Mayol-Castillo, Martha; Olguín-Lora, Patricia

    2012-10-01

    A considerable portion of oil reserves in Mexico corresponds to heavy oils. This feature makes it more difficult to recover the remaining oil in the reservoir after extraction with conventional techniques. Microbial enhanced oil recovery (MEOR) has been considered as a promising technique to further increase oil recovery, but its application has been developed mainly with light oils; therefore, more research is required for heavy oil. In this study, the recovery of Mexican heavy oil (11.1°API and viscosity 32,906 mPa s) in a coreflood experiment was evaluated using the extremophile mixed culture A7, which was isolated from a Mexican oil field. Culture A7 includes fermentative, thermophilic, and anaerobic microorganisms. The experiments included waterflooding and MEOR stages, and were carried out under reservoir conditions (70°C and 9.65 MPa). MEOR consisted of injections of nutrients and microorganisms followed by confinement periods. In the MEOR stages, the mixed culture A7 produced surface-active agents (surface tension reduction 27 mN m⁻¹), solvents (ethanol, 1738 mg L⁻¹), acids (693 mg L⁻¹), and gases, and also degraded heavy hydrocarbon fractions in an extreme environment. The interactions of these metabolites with the oil, as well as the bioconversion of heavy oil fractions to lighter fractions (increased alkanes in the C₈-C₃₀ range), were the mechanisms responsible for the mobility and recovery of heavy oil from the porous media. Oil recovery by MEOR was 19.48% of the residual oil in the core after waterflooding. These results show that MEOR is a potential alternative to heavy oil recovery in Mexican oil fields. Copyright © 2012 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

  16. Horizontal one-dimensional redistribution of oil and water with hysteresis due to oil entrapment

    NARCIS (Netherlands)

    M.I.J. van Dijke; S.E.A.T.M. van der Zee

    1998-01-01

    textabstractRedistribution of oil and water in a long horizontal column, including oil entrapment by water, is described by a nonlinear diffusion problem with a spatially varying diffusion coefficient. This problem admits a similarity solution that was found previously for redistribution of water

  17. Evolution of Hydrodynamic Field, Oil-Gas Migration and Accumulation in Songliao Basin, China

    Institute of Scientific and Technical Information of China (English)

    楼章华; 朱蓉; 金爱民; 孙毛明; 蔡希源; 迟元林

    2004-01-01

    The oil-gas migration and accumulation in the Songliao Basin were analyzed in the view of fluid dynamics by the authors. The key point of fluid dynamics is hydrodynamics. Oil-gas migration and accumulation are related closely with formation and evolution of hydrodynamic field. Based on abundant data, initial formation pressure and other parameters, such as water head were studied. They can be used to understand the present distribution of hydrodynamic field and its hydrochemical features. Generally, the hydrodynamic field in the basin is obviously asymmetrical. In its north and east part, there are the areas of centripetal flow caused by topographic relief when meteoric water permeate downwards. Its south part is an evaporation-concentration area. The central depression is an area of centrifugal flow driven by sediment compaction and its cross-formational flow area. Only at the basin margin and in the local uplifted and denudated area are the meteoric water permeating downwards areas. The centrifugal flow driven by sediment compaction is the main dynamic factor that induces oil-gas migration and accumulation and its formation period corresponding to the main stage of oil-gas migration and accumulation. Moreover, the evolution of hydrodynamic field has the cyclic property, which results in phased oil-gas migration by stages, and further dominates the terraced annular oil and gas distribution, concentric with their corresponding sags.

  18. Basic results of oil field experiments which justify the development of oil and gas formations using CO2 in Hungary

    Energy Technology Data Exchange (ETDEWEB)

    Nemeth, E.

    1984-01-01

    An oil field experiment begun in 1969 and conducted in the 1970s in the K-2 collector of the Budafa deposit is the basis for developing the deposits of oil and gas of Budafa and Lovasi by secondary and tertiary methods using CO2. The condition of the formation at the onset of pumping in the carbon dioxide is briefly described. The results of the experiment are confirmed by the substantial increase and improvement in the daily flow rates of wells and the oil extraction factor. The mechanism of displacement is analyzed, along with the factors which effect the results, and their value. The question about the role of clay minerals in the CO2, oil, water and rock system is examined along with methods for regulating the rate of pumping gas and the withdrawal rate.

  19. Feasibility evaluation of downhole oil/water separator (DOWS) technology.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Langhus, B. G.; Belieu, S.

    1999-01-31

    The largest volume waste stream associated with oil and gas production is produced water. A survey conducted by the American Petroleum Institute estimated that 20.9 billion barrels of produced water were disposed of in 1985 (Wakim 1987). Of this total, 91% was disposed of through disposal wells or was injected for enhanced oil recovery projects. Treatment and disposal of produced water represents a significant cost for operators. A relatively new technology, downhole oil/water separators (DOWS), has been developed to reduce the cost of handling produced water. DOWS separate oil and gas from produced water at the bottom of the well and reinject some of the produced water into another formation or another horizon within the same formation, while the oil and gas are pumped to the surface. Since much of the produced water is not pumped to the surface, treated, and pumped from the surface back into a deep formation, the cost of handling produced water is greatly reduced. When DOWS are used, additional oil may be recovered as well. In cases where surface processing or disposal capacity is a limiting factor for further production within a field, the use of DOWS to dispose of some of the produced water can allow additional production within that field. Simultaneous injection using DOWS minimizes the opportunity for contamination of underground sources of drinking water (USDWs) through leaks in tubing and casing during the injection process. This report uses the acronym 'DOWS' although the technology may also be referred to as DHOWS or as dual injection and lifting systems (DIALS). Simultaneous injection using DOWS has the potential to profoundly influence the domestic oil industry. The technology has been shown to work in limited oil field applications in the United States and Canada. Several technical papers describing DOWS have been presented at oil and gas industry conferences, but for the most part, the information on the DOWS technology has not been widely

  20. Can Oil Float Completely Submerged in Water?

    CERN Document Server

    Nath, Saurabh; Chatterjee, Souvick

    2013-01-01

    Droplet formation in a system of two or more immiscible fluids is a celebrated topic of research in the fluid mechanics community. In this work, we propose an innovative phenomenon where oil when injected drop-wise into a pool of water moves towards the air-water interface where it floats in a fully submerged condition. The configuration, however, is not stable and a slight perturbation to the system causes the droplet to burst and float in partially submerged condition. The droplet contour is analyzed using edge detection. Temporal variation of a characteristic length of the droplet is analyzed using MATLAB image processing. The constraint of small Bond Number established the assumption of lubrication regime in the thin gap. A brief theoretical formulation also showed the temporal variation of the gap thickness

  1. Supercritical water oxidation of oil-based drill cuttings.

    Science.gov (United States)

    Chen, Zhong; Chen, Zeliang; Yin, Fengjun; Wang, Guangwei; Chen, Hongzhen; He, Chunlan; Xu, Yuanjian

    2017-03-09

    Oil-based drill cuttings (OBDC) are a typical hazardous solid waste that arises from drilling operations in oil and gas fields. The supercritical water oxidation (SCWO) of OBDC was comprehensively investigated in a batch reactor under the conditions of various oxygen coefficients (OC, 1.5-3.5), temperatures (T, 400-500°C) and reaction times (t, 0.5-10min). Preheating experiments indicated that most of the organic compounds in the initial OBDC sample were distributed within gaseous, oil, aqueous and solid phases, with no more than 9.8% of organic compounds converted into inorganic carbon. All tested variables, i.e., OC, T and t, positively affect the transformation of carbon compounds from the oil and solid phases to the aqueous phase and, ultimately, to CO2. Carbon monoxide is the primary stable intermediate. The total organic carbon (TOC) removal efficiency can reach up to 89.2% within 10min at 500°C. Analysis of the reaction pathways suggests both homogeneous and heterogeneous reactions exist in the reactor. The homogeneous reaction is a typical SCWO reaction that is governed by a free radical mechanism, and the heterogeneous reaction is dominated by mass transfer. The information obtained in this study is useful for further investigation and development of hydrothermal treatment procedures for OBDC.

  2. [Pollution hazard for water bodies at oil production].

    Science.gov (United States)

    Zholdakova, Z I; Beliaeva, N I

    2015-01-01

    In the paper there have been summarizes the concepts of the danger of the pollution ofwater bodies in oil production (the most dangerous are reagents used in the drilling, drilling waste, oil and petrochemicals, oil biodestructors. There was shown the danger of the spread of oil pollution. New indices, presenting a hazard during drilling and oil production have been substantiated The tasks aimed to the improvement of the standards and methods of the control of the water pollution by oil, as well as of the documents regulating the conditions of environmental protection during the drilling have been conceived.

  3. Oil biodegradation. Water droplets in oil are microhabitats for microbial life.

    Science.gov (United States)

    Meckenstock, Rainer U; von Netzer, Frederick; Stumpp, Christine; Lueders, Tillmann; Himmelberg, Anne M; Hertkorn, Norbert; Schmitt-Kopplin, Philipp; Harir, Mourad; Hosein, Riad; Haque, Shirin; Schulze-Makuch, Dirk

    2014-08-08

    Anaerobic microbial degradation of hydrocarbons, typically occurring at the oil-water transition zone, influences the quality of oil reservoirs. In Pitch Lake, Trinidad and Tobago--the world's largest asphalt lake--we found that microorganisms are metabolically active in minuscule water droplets (1 to 3 microliters) entrapped in oil. Pyrotag sequencing of individual droplet microbiomes revealed complex methanogenic microbial communities actively degrading the oil into a diverse range of metabolites, as shown by nuclear magnetic resonance and Fourier transform ion cyclotron resonance mass spectrometry. High salinity and water-stable isotopes of the droplets indicate a deep subsurface origin. The 13.5% water content and the large surface area of the droplets represent an underestimated potential for biodegradation of oil away from the oil-water transition zone. Copyright © 2014, American Association for the Advancement of Science.

  4. Genomic and genotoxic responses to controlled weathered-oil exposures confirm and extend field studies on impacts of the Deepwater Horizon oil spill on native killifish.

    Directory of Open Access Journals (Sweden)

    Whitney Pilcher

    Full Text Available To understand the ecotoxicological impacts of the Deepwater Horizon oil spill, field studies provide a context for ecological realism but laboratory-based studies offer power for connecting biological effects with specific causes. As a complement to field studies, we characterized genome-wide gene expression responses of Gulf killifish (Fundulus grandis to oil-contaminated waters in controlled laboratory exposures. Transcriptional responses to the highest concentrations of oiled water in the laboratory were predictive of field-observed responses that coincided with the timing and location of major oiling. The transcriptional response to the low concentration (∼ 10-fold lower than the high concentration was distinct from the high concentration and was not predictive of major oiling in the field. The high concentration response was characterized by activation of the molecular signaling pathway that facilitates oil metabolism and oil toxicity. The high concentration also induced DNA damage. The low concentration invoked expression of genes that may support a compensatory response, including genes associated with regulation of transcription, cell cycle progression, RNA processing, DNA damage, and apoptosis. We conclude that the gene expression response detected in the field was a robust indicator of exposure to the toxic components of contaminating oil, that animals in the field were exposed to relatively high concentrations that are especially damaging to early life stages, and that such exposures can damage DNA.

  5. Combustion of oil on water: an experimental program

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-02-01

    This study determined how well crude and fuel oils burn on water. Objectives were: (1) to measure the burning rates for several oils; (2) to determine whether adding heat improves the oils' combustibility; (3) to identify the conditions necessary to ignite fuels known to be difficult to ignite on ocean waters (e.g., diesel and Bunker C fuel oils); and (4) to evaluate the accuracy of an oil-burning model proposed by Thompson, Dawson, and Goodier (1979). Observations were made about how weathering and the thickness of the oil layer affect the combustion of crude and fuel oils. Nine oils commonly transported on the world's major waterways were tested. Burns were first conducted in Oklahoma under warm-weather conditions (approx. 30/sup 0/C) and later in Ohio under cold-weather conditions (approx. 0/sup 0/C to 10/sup 0/C).

  6. In-situ combustion test on outcrops in Kramai oil field

    Energy Technology Data Exchange (ETDEWEB)

    Lang, S.

    1982-01-01

    An in-situ combustion test was performed in Kramai oil field, located in the northwestern border of the Zhungerer Basin, China. The main objectives of the test were to investigate directly the reservoir geology, the petrophysical properties of the reservoir rock, and the flow properties of oil, gas and water within the reservoir. The paper describes the test procedure, including the well pattern, the test pit, operation and inspection techniques, etc., and presents a general discussion of the results obtained.

  7. Oil and Gas field code master list 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    This is the fourteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1995 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the US. The Field Code Index, a listing of all field names and the States in which they occur, ordered by field code, has been removed from this year`s publications to reduce printing and postage costs. Complete copies (including the Field Code Index) will be available on the EIA CD-ROM and the EIA World-Wide Web Site. Future editions of the complete Master List will be available on CD-ROM and other electronic media. There are 57,400 field records in this year`s Oil and Gas Field Code Master List. As it is maintained by EIA, the Master List includes the following: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (see definition of alias below); and fields crossing State boundaries that may be assigned different names by the respective State naming authorities. Taking into consideration the double-counting of fields under such circumstances, EIA identifies 46,312 distinct fields in the US as of October 1995. This count includes fields that no longer produce oil or gas, and 383 fields used in whole or in part for oil or gas Storage. 11 figs., 6 tabs.

  8. Summary of field trials in 1964-69 in Rangoon, Burma, of organophosphorus larvicides and oils against Culex pipiens fatigens larvae in polluted water.

    Science.gov (United States)

    Self, L S; Tun, M M

    1970-01-01

    In tests in Rangoon, Burma, of the larvicidal activity of various organophosphorus compounds against C. p. fatigans, it was found that the activity usually lasted much longer in septic tanks and pit latrines than in open drains. Dursban, Abate, fenthion and several other emulsifiable concentrates caused high larval mortality at a concentration of 0.05 ppm but 0.5 ppm was normally required to obtain a minimum of 1-2 weeks of complete larval control. For the desired residual activity, dosages about 40-400 times the laboratory LC(95) values were normally required, depending on the compound used.The most effective formulation was Dursban emulsifiable concentrate, which, at a concentration of 0.5 ppm, was effective for 3, 7 and 12 weeks in concrete drains, pit latrines and septic tanks, respectively. Petroleum oils applied at rates of 25-40 US gal/ac (approx. 237 l/ha-380 l/ha) and a pyrethrum derivative at a concentration of 1.0 ppm were toxic to larvae but not highly residual. Some emulsifiable-concentrate/oil mixtures appeared to be outstandingly effective, although inconsistent results also occurred. Granular formulations were normally less effective than the emulsifiable concentrates.

  9. Assessment of remaining recoverable oil in selected major oil fields of the Permian Basin, Texas and New Mexico

    Science.gov (United States)

    Tennyson, Marilyn E.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Klett, Timothy R.; Verma, Mahendra K.; Ryder, Robert T.; Attanasi, E.D.; Freeman, P.A.; Le, Phoung A.

    2012-01-01

    The U.S. Geological Survey (USGS) recently completed an estimate of technically recoverable, conventional oil in selected oil fields in the Permian Basin in west Texas and southeastern New Mexico. The mean total volume of potential additional oil resources that might be added using improved oil-recovery technologies was estimated to be about 2.7 billion barrels of oil.

  10. Performance of Surfactant Methyl Ester Sulphonate solution for Oil Well Stimulation in reservoir sandstone TJ Field

    Science.gov (United States)

    Eris, F. R.; Hambali, E.; Suryani, A.; Permadi, P.

    2017-05-01

    Asphaltene, paraffin, wax and sludge deposition, emulsion and water blocking are kinds ofprocess that results in a reduction of the fluid flow from the reservoir into formation which causes a decrease of oil wells productivity. Oil well Stimulation can be used as an alternative to solve oil well problems. Oil well stimulation technique requires applying of surfactant. Sodium Methyl Ester Sulphonate (SMES) of palm oil is an anionic surfactant derived from renewable natural resource that environmental friendly is one of potential surfactant types that can be used in oil well stimulation. This study was aimed at formulation SMES as well stimulation agent that can identify phase transitions to phase behavior in a brine-surfactant-oil system and altered the wettability of rock sandstone and limestone. Performance of SMES solution tested by thermal stability test, phase behavioral examination and rocks wettability test. The results showed that SMES solution (SMES 5% + xylene 5% in the diesel with addition of 1% NaCl at TJformation water and SMES 5% + xylene 5% in methyl ester with the addition of NaCl 1% in the TJ formation water) are surfactant that can maintain thermal stability, can mostly altered the wettability toward water-wet in sandstone reservoir, TJ Field.

  11. Anaerobic thermophilic bacteria isolated from a Venezuelan oil field and its potential use in microbial improved oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Trebbau, G.; Fernandez, B.; Marin, A. [INTEVEP S.A., Caracas (Venezuela)

    1995-12-31

    The objective of this work is to determine the ability of indigenous bacteria from a Venezuelan oil field to grow under reservoir conditions inside a porous media, and to produce metabolites capable of recovering residual crude oil. For this purpose, samples of formation waters from a central-eastern Venezuelan oil reservoir were enriched with different carbon sources and a mineral basal media. Formation water was used as a source of trace metals. The enrichments obtained were incubated at reservoir temperature (71{degrees}C), reservoir pressure (1,200 psi), and under anaerobic conditions for both outside and inside porous media (Berea core). Growth and metabolic activity was followed outside porous media by measuring absorbance at 660 nm, increases in pressure, and decreases in pH. Inside porous media bacterial activity was determined by visual examination of the produced waters (gas bubbles and bacterial cells). All the carbohydrates tested outside porous media showed good growth at reservoir conditions. The pH was lowered, gases such as CO{sub 2} and CH{sub 4} were identified by GC. Surface tension was lowered in some enrichments by 30% when compared to controls. Growth was decreased inside porous media, but gases were produced and helped displace oil. In addition, 10% residual oil was recovered from the Berea core. Mathematical modeling was applied to the laboratory coreflood experiment to evaluate the reproducibility of the results obtained.

  12. Ignitability of crude oil and its oil-in-water products at arctic temperature.

    Science.gov (United States)

    Ranellone, Raymond T; Tukaew, Panyawat; Shi, Xiaochuan; Rangwala, Ali S

    2017-02-15

    A novel platform and procedure were developed to characterize the ignitability of Alaska North Slope (ANS) crude oil and its water-in-oil products with water content up to 60% at low temperatures (-20-0°C). Time to ignition, critical heat flux, in-depth temperature profiles were investigated. It was observed that a cold boundary and consequent low oil temperature increased the thermal inertia of the oil/mixture and consequently the time to sustained ignition also increased. As the water content in the ANS water-in-oil mixture increased, the critical heat flux for ignition was found to increase. This is mainly because of an increase in the thermal conductivity of the mixture with the addition of saltwater. The results of the study can be used towards design of ignition strategies and technologies for in situ burning of oil spills in cold climates such as the Arctic.

  13. Coalescence dynamic analysis of water droplets in oil in electric field%电场作用下油水乳化液中水滴的聚合动力学分析

    Institute of Scientific and Technical Information of China (English)

    张军; 张园春; 陈智杰; 何宏舟; 杨绍辉; 李晖

    2016-01-01

    In order to reveal the characteristics of the droplet coalescence in electric demulsification process, an experiment on electric coalescence between 2 adjacent water droplets in oil in a uniform electric field is conducted. The uniform electric field is generated by 2 parallel plate electrodes. One electrode is connected to the electrostatic voltage generator and the other is grounded. Test medium is sunflower oil as well as water. The viscosity and the density for sunflower oil are 0.085 Pa·s and 892 kg/m3, respectively. The density and the surface tension for water are 998 kg/m3 and 0.069 N/m, respectively. Different electrostatic voltage can be applied by electrostatic voltage generator to the electrode so that the desired electric field strength can be obtained. In experiment, an MD55 type microscopic camera, which was made by Guangzhou Mingmei Optoelectronic Technology Co., Ltd., is used to record the positions and shapes of droplets under different time and different electric field strengths. The effect of electric field strength on droplet movement and deformation is analyzed based on the obtained experiment data. Furthermore, considering droplet deformation, the equations of droplet motion are established according to electric dipole model. By means of the droplet motion equations, the electric coalescence process between 2 adjacent droplets is numerically simulated. A typical Runge-Kutta algorithm is adopted in simulation and the time step is 0.000 2 s. Through the simulation, the distances between 2 adjacent water droplets under different time and different electric field strengths are obtained, and they are used to analyze the effects of medium physical properties, droplet size as well as electric field strength on droplet coalescence efficiency. The simulating and experimental results show that the prediction of the present model on the evolution of the distance between 2 droplets is basically consistent with the experiment, and the average relative

  14. A genome probe survey of the microbial community in oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Voordouw, G.; Telang, A. [Calgary Univ., AB (Canada). Dept. of Biology

    2000-07-01

    Reverse sample genome probing (RSGP) was conducted in water injected oil fields in Western Canada in order to analyze the microbial community in the fields to identify different bacteria responsible for microbially influenced corrosion (MIC) or souring. Oil fields of moderate temperature and salinity have an anaerobic microbial community consisting of sulfate-reducing bacteria (SRB), sulfide-oxidizing bacteria (SOB) and heterotrophic bacteria. The RSGP revealed that selected SRB are enhanced at metal surfaces and can therefore contribute to corrosion. Some of the SRB were found to be insensitive to biocides that are used in the field. RSGP also showed that injection of nitrate, instead of sulfate, leads to a marked increase of Campylobacter sp., which gets its energy from the oxidation of sulfide by nitrate. It was concluded that RSGP is a useful tool to monitor the effects of chemical stresses on the oil field microbial community. 13 refs., 2 figs.

  15. Rangely Oil Field Perch Survey, 2001-2004

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Data are the results of raptor perch surveys conducted monthly from August 2001 - July 2004 along a standardized survey route in the Rangely Oil Field (ROF),...

  16. The determination of water in crude oil and transformer oil reference materials.

    Science.gov (United States)

    Margolis, Sam A; Hagwood, Charles

    2003-05-01

    The measurement of the amount of water in oils is of significant economic importance to the industrial community, particularly to the electric power and crude oil industries. The amount of water in transformer oils is critical to their normal function and the amount of water in crude oils affects the cost of the crude oil at the well head, the pipeline, and the refinery. Water in oil Certified Reference Materials (CRM) are essential for the accurate calibration of instruments that are used by these industries. Three NIST Standard Reference Materials (SRMs) have been prepared for this purpose. The water in these oils has been measured by both coulometric and volumetric Karl Fischer methods. The compounds (such as sulfur compounds) that interfere with the Karl Fischer reaction (interfering substances) and inflate the values for water by also reacting with iodine have been measured coulometrically. The measured water content of Reference Material (RM) 8506a Transformer Oil is 12.1+/-1.9 mg kg(-1) (plus an additional 6.2+/-0.9 mg kg(-1) of interfering substances). The measured water content of SRM 2722 Sweet Crude Oil, is 99+/-6 mg kg(-1) (plus an additional 5+/-2 mg kg(-1) of interfering substances). The measured water content of SRM 2721 Sour Crude Oil, is 134+/-18 mg kg(-1) plus an additional 807+/-43 mg kg(-1) of interfering substances. Interlaboratory studies conducted with these oil samples (using SRM 2890, water saturated 1-octanol, as a calibrant) are reported. Some of the possible sources of bias in these measurements were identified, These include: improperly calibrated instruments, inability to measure the calibrant accurately, Karl Fischer reagent selection, and volatilization of the interfering substances in SRM 2721.

  17. Hydraulic Systems with Tap Water versus Bio-oils

    DEFF Research Database (Denmark)

    Conrad, Finn

    1997-01-01

    Deals with the advantages of using pure tap water hydraulics versus bio-oils for suiteable applications. Focus is in particular on food processing industry.......Deals with the advantages of using pure tap water hydraulics versus bio-oils for suiteable applications. Focus is in particular on food processing industry....

  18. Absorption of water and lubricating oils into porous nylon

    Science.gov (United States)

    Bertrand, P. A.

    1995-01-01

    Oil and water absorption from air into sintered porous nylon can be described by infiltration into the pores of the material. This process can be modeled by a diffusion-like mechanism. For water absorption, we find a formal diffusion coefficient of 1.5 x 10(exp -4)sq cm/min when the nylon is initially dry. The diffusion coefficient is 4 x 10(exp -6)sq cm/min when the nylon is oil-impregnated prior to air exposure. In a 52% RH atmosphere, dry nylon absorbs 3% w/w water, and oil-impregnated nylon absorbs 0.6% w/w water. For oil absorption there are three steps: (1) surface absorption and infiltration into (2) larger and (3) smaller pores. Surface absorption is too fast to be measured in these experiments. The diffusion coefficient for the second step is 6 x 10(exp -4)sq cm/min for SRG-60 oil into dry nylon and 4 x 10(exp -4)sq cm/min for air-equilibrated nylon. The diffusion coefficient for the third step is about 1 x 10(exp -6)sq cm/min for both cases. The total amount of oil absorbed is 31% w/w. The interaction between water and nylon is not as strong as that between water and cotton-phenolic: oil can replace water, and only a small amount of water can enter previously oil-impregnated nylon.

  19. Experiments in which oil, water and colloidal particles meet

    NARCIS (Netherlands)

    Elbers, N.A.

    2015-01-01

    In this thesis, the results are reported of experimental studies in which oil, water and colloidal particles meet. Colloidal particles are particles that have at least one characteristic length scale in the range between a few nanometers (nm) and several micrometers (μm). Mixtures of oil and water,

  20. Trip Report-Produced-Water Field Testing

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, Enid J. [Los Alamos National Laboratory

    2012-05-25

    Los Alamos National Laboratory (LANL) conducted field testing of a produced-water pretreatment apparatus with assistance from faculty at the Texas A&M University (TAMU) protein separation sciences laboratory located on the TAMU main campus. The following report details all of the logistics surrounding the testing. The purpose of the test was to use a new, commercially-available filter media housing containing modified zeolite (surfactant-modified zeolite or SMZ) porous medium for use in pretreatment of oil and gas produced water (PW) and frac-flowback waters. The SMZ was tested previously in October, 2010 in a lab-constructed configuration ('old multicolumn system'), and performed well for removal of benzene, toluene, ethylbenzene, and xylenes (BTEX) from PW. However, a less-expensive, modular configuration is needed for field use. A modular system will allow the field operator to add or subtract SMZ filters as needed to accommodate site specific conditions, and to swap out used filters easily in a multi-unit system. This test demonstrated the use of a commercial filter housing with a simple flow modification and packed with SMZ for removing BTEX from a PW source in College Station, Texas. The system will be tested in June 2012 at a field site in Pennsylvania for treating frac-flowback waters. The goals of this test are: (1) to determine sorption efficiency of BTEX in the new configuration; and (2) to observe the range of flow rates, backpressures, and total volume treated at a given flow rate.

  1. In-Situ Burning of Crude Oil on Water

    DEFF Research Database (Denmark)

    van Gelderen, Laurens

    in the small scale water basin. Boilovers were also observed during the burning of a heavy crude oil with a substantial light fraction without a water layer, however, which suggests that water is not essential for boilover occurrence. Further studies are required to determine the conditions under which......The fire dynamics and fire chemistry of in-situ burning of crude oil on water was studied in order to improve predictions on the suitability of this oil spill response method. For this purpose, several operational parameters were studied to determine the factors that control the burning efficiency...... of in-situ burning, i.e. the amount of oil (in wt%) removed from the water surface by the burning process. The burning efficiency is the main parameter for expressing the oil removal effectiveness of in-situ burning as response method and is thus relevant for suitability predictions of in-situ burning...

  2. Recent Development of Advanced Materials with Special Wettability for Selective Oil/Water Separation.

    Science.gov (United States)

    Ma, Qinglang; Cheng, Hongfei; Fane, Anthony G; Wang, Rong; Zhang, Hua

    2016-04-27

    The increasing number of oil spill accidents have a catastrophic impact on our aquatic environment. Recently, special wettable materials used for the oil/water separation have received significant research attention. Due to their opposing affinities towards water and oil, i.e., hydrophobic and oleophilic, or hydrophilic and oleophobic, such materials can be used to remove only one phase from the oil/water mixture, and simultaneously repel the other phase, thus achieving selective oil/water separation. Moreover, the synergistic effect between the surface chemistry and surface architecture can further promote the superwetting behavior, resulting in the improved separation efficiency. Here, recently developed materials with special wettability for selective oil/water separation are summarized and discussed. These materials can be categorized based on their oil/water separating mechanisms, i.e., filtration and absorption. In each section, representative studies will be highlighted, with emphasis on the materials wetting properties and innovative aspects. Finally, challenges and future research directions in this emerging and promising research field will be briefly described. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Largest US oil and gas fields, August 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-06

    The Largest US Oil and Gas Fields is a technical report and part of an Energy Information Administration (EIA) series presenting distributions of US crude oil and natural gas resources, developed using field-level data collected by EIA`s annual survey of oil and gas proved reserves. The series` objective is to provide useful information beyond that routinely presented in the EIA annual report on crude oil and natural gas reserves. These special reports also will provide oil and gas resource analysts with a fuller understanding of the nature of US crude oil and natural gas occurrence, both at the macro level and with respect to the specific subjects addressed. The series` approach is to integrate EIA`s crude oil and natural gas survey data with related data obtained from other authoritative sources, and then to present illustrations and analyses of interest to a broad spectrum of energy information users ranging from the general public to oil and gas industry personnel.

  4. Laboratory and field observations of stress-wave induced changes in oil flow behavior

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, P. M. (Peter M.); Majer, Ernest Luther; Wooden, W. (William); Daley, T. M. (Thomas M.)

    2001-01-01

    We present recent results of laboratory and field experiments designed to validate and quantify the phenomenon of seismically enhanced oil production in marginal reservoirs. Controlled laboratory experiments were performed where mechanical stress oscillations at 100 Hz or less were applied to sandstone cores while flowing oil and/or brine at constant flow rates. Steady-state flow and simulated flooding experiments indicated that stress stimulation causes significant changes in the ability of one fluid to displace the other and on the preference that the rock has for trapping one fluid over the other. For Berea sandstone, which is highly water wet, stress stimulation caused oil production to be impeded during water floods and caused the bulk fluid pressure drop across the core to increase during steady-state simultaneous flow of oil and brine. A possible explanation of these observations is that stimulation caused the core to become more oil wet. Field stimulation tests on producing reservoirs at Lost Hills, California were performed using a downhole fluid pressure pulsation device. Stimulation was applied in one well for 50 days total during July - November 2000. Two groups of producing wells were monitored for changes in oil cut and oil production during the test. A control group of 26 wells displayed an oil-cut increase of 29% and an oil production increase of 26% which are clearly correlated with the stimulation treatment. A larger group of 60 wells showed 11% oil-cut and 17v0 production increases. Similar increases were observed during the October 1999 Hector Mine earthquake, magnitude 7.1, in the Mojave Desert about 230 miles from Lost Hills. Downhole seismic monitoring of the stimulation wavefield is being used to help quantify the frequency range and energy threshold required for effective production enhancement.

  5. Shengli Oil Fields: Today and Tomorrow

    Institute of Scientific and Technical Information of China (English)

    Lu Renjie

    1996-01-01

    @@ Shengli oil area lies in the Yellow River Delta, in the north of Shandong Province bordering the Bohai Bay. The area is scattered over 28 counties, covering 37 000 square kilom eters. The main part of exploration and exploitation is located on both sides of the Yellow River estuary within the territory of Dongying City.

  6. Restructuring Raises Revenue of Liaohe Oil Field

    Institute of Scientific and Technical Information of China (English)

    Xiao Qiuju

    2002-01-01

    @@ Liaohe Petroleum Exploration Bureau, as a Stateowned oil giant company in Northeast China's Liaoning Province, has made significant progress in the nationwide drive o restructure State-owned enterprises. Once plagued by excessive laborers and backward production equipment, the bureau has adopted a series of effective measures on human resource management, market expansion and technology renovation.

  7. Microencapsulation using an oil-in-water-in-air 'dry water emulsion'.

    Science.gov (United States)

    Carter, Benjamin O; Weaver, Jonathan V M; Wang, Weixing; Spiller, David G; Adams, Dave J; Cooper, Andrew I

    2011-08-07

    We describe the first example of a tri-phasic oil-in-water-in-air 'dry water emulsion'. The method combines highly stable oil-in-water emulsions prepared using branched copolymer surfactants, with aqueous droplet encapsulation using 'dry water' technology.

  8. Strategies for Efficient Microfiltration of Oil-in-Water Emulsions

    Science.gov (United States)

    Darvishzadeh, Tohid; Priezjev, Nikolai

    2011-11-01

    This study addresses the issue of the separation of oil droplets from water for oil spill mitigation and produced water treatment. The effective separation of oil-in-water dispersions involves high flux of water through a membrane and, at the same time, high rejection rate of oil droplets, while avoiding membrane fouling. In this study, the effects of transmembrane pressure and crossflow velocity on rejection of oil droplets by pores of different cross-section are investigated numerically by solving the Navier-Stokes equation. We found that in the absence of crossflow, the critical transmembrane pressure, which is required for the oil droplet entry into a circular pore of given surface hydrophobicity, agrees well with analytical predictions based on the Young-Laplace equation. With increasing crossflow velocity, the shape of the oil droplet residing at the pore entrance is elongated along the flow and the critical pressure increases. In the case of pores with an elliptical cross-section, the water flux through the membrane is enhanced, in agreement with simple analytical considerations. The results of the numerical simulations are used to outline strategies for the experimental design of porous filters for oil spill remediation and produced water treatment applications.

  9. Oil and gas field code master list 1994

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    This is the thirteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1994 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. The master field name spellings and codes are to be used by respondents when filing the following Department of Energy (DOE) forms: Form EIA-23, {open_quotes}Annual Survey of Domestic Oil and Gas Reserves,{close_quotes} filed by oil and gas well operators (field codes are required from larger operators only); Forms FERC 8 and EIA-191, {open_quotes}Underground Gas Storage Report,{close_quotes} filed by natural gas producers and distributors who operate underground natural gas storage facilities. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service, 5285 Port Royal Road, Springfield, Virginia 22161, (703) 487-4650. In order for the Master List to be useful, it must be accurate and remain current. To accomplish this, EIA constantly reviews and revises this list. The EIA welcomes all comments, corrections, and additions to the Master List. All such information should be given to the EIA Field Code Coordinator at (214) 953-1858. EIA gratefully acknowledges the assistance provides by numerous State organizations and trade associations in verifying the existence of fields and their official nomenclature.

  10. A water and hydrocarbon emulsion for extracting residual oil

    Energy Technology Data Exchange (ETDEWEB)

    Verderevskiy, Yu.L.; Abramzon, A.A.; Gusev, V.I.; Kulikov, Yu.M.; Petrov, A.G.; Starosud, A.N.; Tavrin, A.Ye.; Zheranin, V.L.

    1984-01-01

    The purpose of the invention is to improve the oil displacing properties of the composition in conditions of high mineralization of the stratum waters and to reduce the cost of the emulsion. To do this, the water and hydrocarbon emulsion for extracting residual oil, which includes water, liquid hydrocarbons, water and oil soluble surfacants (PAV), contains oxyethylated alkylphenol of the OP-10 type as the water soluble surfacant and contains oxytehylated alkylphenol of the OP-4 type as the oil soluble surfacant in the following component relationship (percent by mass): oxyethylated alkylphenol of the OP-4 type, 3.9 to 5.5; oxyethylated alkylphenol of the OP-10 type, 0.1 to 0.2; liquid hydrocargon, 40 to 41 and water, the remainder.

  11. 膜法水处理技术在油田生产中的应用分析%Analysis of membrane technology for water treatment in oil field production

    Institute of Scientific and Technical Information of China (English)

    周阳

    2012-01-01

      As its complex components,the effect of traditional crafts in oil-field produced water treatment is not so good. The membrane technology has been widely studied and applied for its high efficiency,simple operation but low in maintenance and reagent consumption .Percolate of the ultrafiltration membrane, combined with ultrasonic and other technologies, can meet the requirements of re-injection.%  油田采出水的污染成分较为复杂,常规方法的处理效果有限。目前针对此类的研究较多,膜法水处理技术因其高效、用药量少、操作简单、运行维护费用低等优势而被广泛研究与应用。其中,超滤膜与超声波等多种工艺相结合的方式在处理油田采出水时取得了较好的效果,可满足回注用水的基本要求

  12. Synthesis of highly hydrophobic floating magnetic polymer nanocomposites for the removal of oils from water surface

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Mudan, E-mail: chenmudan@163.com [National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology, Nanjing 210094 (China); Jiang, Wei, E-mail: climentjw@126.com [National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology, Nanjing 210094 (China); Wang, Fenghe [Department of Environmental Science and Engineering, Nanjing Normal University, Nanjing 210023 (China); Shen, Ping; Ma, Peichang; Gu, Junjun; Mao, Jianyu; Li, Fengsheng [National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2013-12-01

    The removal of organic contaminants, particularly oil spills from water surface is of great technological importance for environmental protection. In this article, we present a novel, economic and environment-friendly core–shell composite material based on magnetic hollow Fe{sub 3}O{sub 4} nanoparticles (MNPs) that was fabricated by two-step process, which can fast and efficiently separate oils from water surface under a magnetic field. The magnetic Fe{sub 3}O{sub 4} nanoparticles (MNPs) were coated with a polystyrene layer successfully to form water-repellent and oil-absorbing surfaces, which could float on water and selectively absorb lubricating oil up to 3 times of the particles’ weight while completely repelling water. More importantly, the oils could be readily removed from the surfaces of nanocomposites by a simple treatment and the nanocomposites still kept highly hydrophobic and superoleophilic characteristics, so the nanocomposites have an excellent recyclability in the oil-absorbent capacity. Several techniques such as transmission electron microscope (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA) were used in the characterization of the materials. In addition, magnetic force and oils removal capability tests were also performed. It will open up a potential and broad application in wastewater treatment.

  13. Synthesis of highly hydrophobic floating magnetic polymer nanocomposites for the removal of oils from water surface

    Science.gov (United States)

    Chen, Mudan; Jiang, Wei; Wang, Fenghe; Shen, Ping; Ma, Peichang; Gu, Junjun; Mao, Jianyu; Li, Fengsheng

    2013-12-01

    The removal of organic contaminants, particularly oil spills from water surface is of great technological importance for environmental protection. In this article, we present a novel, economic and environment-friendly core-shell composite material based on magnetic hollow Fe3O4 nanoparticles (MNPs) that was fabricated by two-step process, which can fast and efficiently separate oils from water surface under a magnetic field. The magnetic Fe3O4 nanoparticles (MNPs) were coated with a polystyrene layer successfully to form water-repellent and oil-absorbing surfaces, which could float on water and selectively absorb lubricating oil up to 3 times of the particles’ weight while completely repelling water. More importantly, the oils could be readily removed from the surfaces of nanocomposites by a simple treatment and the nanocomposites still kept highly hydrophobic and superoleophilic characteristics, so the nanocomposites have an excellent recyclability in the oil-absorbent capacity. Several techniques such as transmission electron microscope (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA) were used in the characterization of the materials. In addition, magnetic force and oils removal capability tests were also performed. It will open up a potential and broad application in wastewater treatment.

  14. Recent developments in reservoir engineering and their impact on oil and gas field development

    Energy Technology Data Exchange (ETDEWEB)

    Davies, R.H.; Niko, H. [Shell Internationale Petroleum Maatschappij BV, Den Haag (Netherlands)

    1996-12-31

    With much of the reservoir engineering development activities prior to 1986 being directed to new processes such as EOR, reservoir engineering of today has, like the other petroleum engineering disciplines, become part of an integrated effort to extract the maximum amount of oil from a reservoir. We will discuss some of the new developments in reservoir engineering which had a real impact on oil field operations in Shell and on the working practices of the individual reservoir engineers. Examples of recent advances in reservoir engineering are: (1) progress in the field of measuring residual oil saturations to water under representative conditions which will enable a more realistic assessment of trapped/bypassed oil in water floods such as those in large North Sea fields; (2) improved understanding of the production behaviour of horizontal wells based on analytical and numerical modelling which led to successful applications in Gabon and Oman; (3) advances in our understanding of production in naturally fractured reservoirs which provided the basis for a unique field experiment in the Natih Field in Oman; (4) understanding of the mechanism of fracturing in water injection wells, a process which has large cost-saving potential. The one factor largely responsible for the change in working practices of individual reservoir engineers is the availability of modern integrated IT technology. (author)

  15. Oil and gas field code master list 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The Oil and Gas Field Code Master List 1997 is the sixteenth annual listing of all identified oil and gas fields in the US. It is updated with field information collected through October 1997. The purpose of this publication is to provide unique, standardized codes for identification of domestic fields. Use of these field codes fosters consistency of field identification by government and industry. As a result of their widespread adoption they have in effect become a national standard. The use of field names and codes listed in this publication is required on survey forms and other reports regarding field-specific data collected by EIA. There are 58,366 field records in this year`s FCML, 437 more than last year. The FCML includes: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (definition of alias is listed); fields crossing State boundaries that may be assigned different names by the respective State naming authorities. This report also contains an Invalid Field Record List of 4 records that have been removed from the FCML since last year`s report. These records were found to be either technically incorrect or to represent field names which were never recognized by State naming authorities.

  16. Infrared Spectroscopy of Bilberry Extract Water-in-Oil Emulsions: Sensing the Water-Oil Interface

    Directory of Open Access Journals (Sweden)

    Johannes Kiefer

    2016-04-01

    Full Text Available Water-in-oil (w/o emulsions are of great interest in many areas of the life sciences, including food technology, bioprocess engineering, and pharmaceuticals. Such emulsions are complex multi-component systems and the molecular mechanisms which lead to a stable emulsion are yet to be fully understood. In this work, attenuated total reflection (ATR infrared (IR spectroscopy is applied to a series of w/o emulsions of an aqueous anthocyanin-rich bilberry extract dispersed in a medium chain triglyceride (MCT oil phase. The content of the emulsifier polyglycerin-polyricinoleat (PGPR has been varied systematically in order to investigate whether or not its concentration has an impact on the molecular stabilization mechanisms. The molecular stabilization is accessed by a careful analysis of the IR spectrum, where changes in the vibrational frequencies and signal strengths indicate alterations of the molecular environment at the water/oil interface. The results suggest that adding emulsifier in excess of 1% by weight does not lead to an enhanced stabilization of the emulsion.

  17. Infrared Spectroscopy of Bilberry Extract Water-in-Oil Emulsions: Sensing the Water-Oil Interface.

    Science.gov (United States)

    Kiefer, Johannes; Frank, Kerstin; Zehentbauer, Florian M; Schuchmann, Heike P

    2016-04-14

    Water-in-oil (w/o) emulsions are of great interest in many areas of the life sciences, including food technology, bioprocess engineering, and pharmaceuticals. Such emulsions are complex multi-component systems and the molecular mechanisms which lead to a stable emulsion are yet to be fully understood. In this work, attenuated total reflection (ATR) infrared (IR) spectroscopy is applied to a series of w/o emulsions of an aqueous anthocyanin-rich bilberry extract dispersed in a medium chain triglyceride (MCT) oil phase. The content of the emulsifier polyglycerin-polyricinoleat (PGPR) has been varied systematically in order to investigate whether or not its concentration has an impact on the molecular stabilization mechanisms. The molecular stabilization is accessed by a careful analysis of the IR spectrum, where changes in the vibrational frequencies and signal strengths indicate alterations of the molecular environment at the water/oil interface. The results suggest that adding emulsifier in excess of 1% by weight does not lead to an enhanced stabilization of the emulsion.

  18. Microbiological treatment of oil mill waste waters

    Directory of Open Access Journals (Sweden)

    Ranalli, A.

    1992-02-01

    Full Text Available Experiments of the biological treatment of the oil mill waste waters, deriving from continuous system, have been carried out with selected mutant ferments, adapted to rather forced toxic conditions. The commercial microbio formulations SNKD, LLMO and PSBIO have been utilized; the last two are liquid suspensions, constituted by living micro-organisms that, in contrast to those frozen or lyophilized, do not need be revitalized before their use and became completely active in short time. The experiments with the SNKD biological preparation were carried out both on filtered oil mill outflows (type A with an initial COD of approximately 43 g/l and on waste water dephenolized by Caro-acid (type B with a COD equal to 30 g/l. The experiments with LLMO and PSBIO complexes were conduced both on oil mill outflows filtered and diluted (ratio 1:0.5 with an initial COD equal to 44 g/l (type C, and on waste water that were filtered and preventatively subjected to a cryogenic treatment (type D, with an initial COD of approximately 22 g/l. The residual COD with the microbio formulation SNKD, was about 15 g/l (type A and 5 g/l (type B; with the PSBIO It was about 7 g/l (type C and 1.5 g/l (type D; with the microbio formulation LLMO it resulted in 6 g/l (type C and 1.3 g/l (type D.

    Han sido efectuadas pruebas de tratamiento biológico de alpechines, provenientes de sistemas continuos, con fermentos seleccionados adaptados a condiciones de toxicidad muy elevadas. Han sido utilizadas las formulaciones microbianas SNKD, LLMO y PSBIO; las dos últimas son suspensiones líquidas, constituidas por microorganismos vivos, los cuales a diferencia de los liofilizados o congelados, no deben ser revitalizados antes del uso; estos tienen una fase «lag» más breve y entran antes en completa actividad. Las pruebas con la preparación biológica SNKD han sido efectuadas en los alpechines filtrados (tipo A con DQO inicial alrededor de 43 g/l, y también con alpech

  19. The Finite Element Analysis for a Mini-Conductance Probe in Horizontal Oil-Water Two-Phase Flow

    Directory of Open Access Journals (Sweden)

    Weihang Kong

    2016-08-01

    Full Text Available Oil-water two-phase flow is widespread in petroleum industry processes. The study of oil-water two-phase flow in horizontal pipes and the liquid holdup measurement of oil-water two-phase flow are of great importance for the optimization of the oil production process. This paper presents a novel sensor, i.e., a mini-conductance probe (MCP for measuring pure-water phase conductivity of oil-water segregated flow in horizontal pipes. The MCP solves the difficult problem of obtaining the pure-water correction for water holdup measurements by using a ring-shaped conductivity water-cut meter (RSCWCM. Firstly, using the finite element method (FEM, the spatial sensitivity field of the MCP is investigated and the optimized MCP geometry structure is determined in terms of the characteristic parameters. Then, the responses of the MCP for the oil-water segregated flow are calculated, and it is found that the MCP has better stability and sensitivity to the variation of water-layer thickness in the condition of high water holdup and low flow velocity. Finally, the static experiments for the oil-water segregated flow were carried out and a novel calibration method for pure-water phase conductivity measurements was presented. The validity of the pure-water phase conductivity measurement with segregated flow in horizontal pipes was verified by experimental results.

  20. The Finite Element Analysis for a Mini-Conductance Probe in Horizontal Oil-Water Two-Phase Flow.

    Science.gov (United States)

    Kong, Weihang; Kong, Lingfu; Li, Lei; Liu, Xingbin; Xie, Ronghua; Li, Jun; Tang, Haitao

    2016-08-24

    Oil-water two-phase flow is widespread in petroleum industry processes. The study of oil-water two-phase flow in horizontal pipes and the liquid holdup measurement of oil-water two-phase flow are of great importance for the optimization of the oil production process. This paper presents a novel sensor, i.e., a mini-conductance probe (MCP) for measuring pure-water phase conductivity of oil-water segregated flow in horizontal pipes. The MCP solves the difficult problem of obtaining the pure-water correction for water holdup measurements by using a ring-shaped conductivity water-cut meter (RSCWCM). Firstly, using the finite element method (FEM), the spatial sensitivity field of the MCP is investigated and the optimized MCP geometry structure is determined in terms of the characteristic parameters. Then, the responses of the MCP for the oil-water segregated flow are calculated, and it is found that the MCP has better stability and sensitivity to the variation of water-layer thickness in the condition of high water holdup and low flow velocity. Finally, the static experiments for the oil-water segregated flow were carried out and a novel calibration method for pure-water phase conductivity measurements was presented. The validity of the pure-water phase conductivity measurement with segregated flow in horizontal pipes was verified by experimental results.

  1. Soils and waste water purification from oil products using combined methods under the North conditions.

    Science.gov (United States)

    Evdokimova, Galina A; Gershenkop, Alexander Sh; Mozgova, Natalia P; Myazin, Vladimir A; Fokina, Nadejda V

    2012-01-01

    Oil and gas production and transportation in Russia is increasingly moving to the north regions. Such regions are characterized by relatively low self-purification capacity of the natural environments from the contaminants due to slow character of the energy exchange and mass transfer processes. Off-shore field development in the Barents Sea and oil product transportation can result in contamination, as confirmed by the national and international practice of the developed oil and gas regions. The research aims at development of the soil bioremediation methods and industrial waste water purification contaminated by oil products in the north-western region of Russia. The dynamics of oil products carry-over have been investigated under the field model experiments in podzolic soils: gas condensate, diesel fuel and mazut from oil and the plants were selected for phyto-remediation of contaminated soils under high north latitudes. It is shown that soil purification from light hydrocarbons takes place during one vegetation period. In three months of the vegetation period the gas condensate was completely removed from the soil, diesel fuel - almost completely (more than 90%). Residual amounts of heavy hydrocarbons were traced, even 1.5 later. The following plants that were highly resistant to the oil product contamination were recommended for bioremediation: Phalaroides arundinacea, Festuca pratensis, Phleum pratense, Leymus arenarius. There has been developed and patented the combined method of treatment of waste water contaminated with hydrocarbons based on inorganic coagulants and local oil-oxidizing bacteria.

  2. Effect of water regime on the growth, flower yield, essential oil and proline contents of Calendula officinalis

    Directory of Open Access Journals (Sweden)

    SAMI ALI METWALLY

    2013-11-01

    Full Text Available Metwally SA,Khalid KA, Abou-Leila BH. 2013. Effect of water regime on the growth, flower yield, essential oil and proline contents of Calendula officinalis. Nusantara Bioscience 5: 63-67. The effects of water regime on the growth, content of essential oil and proline of Calendula officinalis L. plants were investigated. Water regimes of 75% of field water capacity increased certain growth characters [i.e. plant height (cm, leaf area (cm2, flower diameter (cm and spike stem diameter] and vase life (day. Water regime promoted the accumulation of essential oil content and its main components as well as proline contents.

  3. Souring in low-temperature surface facilities of two high-temperature Argentinian oil fields.

    Science.gov (United States)

    Agrawal, Akhil; An, Dongshan; Cavallaro, Adriana; Voordouw, Gerrit

    2014-09-01

    Produced waters from the Barrancas and Chihuido de la Salina (CHLS) fields in Argentina had higher concentrations of sulfate than were found in the injection waters, suggesting that the formation waters in these reservoirs had a high sulfate concentration and that sulfate-reducing bacteria were inactive downhole. Incubation of produced waters with produced oil gave rapid reduction of sulfate to sulfide (souring) at 37 °C, some at 60 °C, but none at 80 °C. Alkylbenzenes and alkanes served as electron donor, especially in incubations with CHLS oil. Dilution with water to decrease the ionic strength or addition of inorganic phosphate did not increase souring at 37 or 60 °C. These results indicate that souring in these reservoirs is limited by the reservoir temperature (80 °C for the Barrancas and 65-70 °C for the CHLS field) and that souring may accelerate in surface facilities where the oil-water mixture cools. As a result, significant sulfide concentrations are present in these surface facilities. The activity and presence of chemolithotrophic Gammaproteobacteria of the genus Thiomicrospira, which represented 85% of the microbial community in a water plant in the Barrancas field, indicated reoxidation of sulfide and sulfur to sulfate. The presence of these bacteria offers potential for souring control by microbial oxidation in aboveground facilities, provided that formation of corrosive sulfur can be avoided.

  4. Calibration of Mineralization Degree for Dynamic Pure-water Measurement in Horizontal Oil-water Two-phase Flow

    Science.gov (United States)

    Kong, Weihang; Li, Lei; Kong, Lingfu; Liu, Xingbin

    2016-08-01

    In order to solve the problem of dynamic pure-water electrical conductivity measurement in the process of calculating water content of oil-water two-phase flow of production profile logging in horizontal wells, a six-group local-conductance probe (SGLCP) is proposed to measure dynamic pure-water electrical conductivity in horizontal oil-water two-phase flow. The structures of conductance sensors which include the SGLCP and ring-shaped conductance probe (RSCP) are analyzed by using the finite-element method (FEM). In the process of simulation, the electric field distribution generated by the SGLCP and RSCP are investigated, and the responses of the measuring electrodes are calculated under the different values of the water resistivity. The static experiments of the SGLCP and RSCP under different mineralization degrees in horizontal oil-water two-phase flow are carried out. Results of simulation and experiments demonstrate a nice linearity between the SGLCP and RSCP under different mineralization degrees. The SGLCP has also a good adaptability to stratified flow, stratified flow with mixing at the interface and dispersion of oil in water and water flow. The validity and feasibility of pure-water electrical conductivity measurement with the designed SGLCP under different mineralization degrees are verified by experimental results.

  5. Mitigation of Oil in Water Column: Concept Development

    Science.gov (United States)

    2016-06-01

    Project No. 4702 7. Author(s) Alexander Balsley, Dr. Michele Fitzpatrick, Peter A. Tebeau 8. Performing Report No. RDC UDI # 1291 9...of Mexico . Figure A-4. Sorbent pom-poms from the Detroit River 1996. Figure A-5. Vessel-Submerged Oil Recovery System. Mitigation of Oil in... Mexico Droplets from chemical and possibly natural dispersion. None Mitigation of Oil in Water Column: Concept Development B-2 UNCLAS//Public

  6. Oil spill dispersants. Risk assessment for Swedish waters

    Energy Technology Data Exchange (ETDEWEB)

    Lindgren, C.; Lager, H.; Fejes, J.

    2001-12-01

    IVL has compiled a list of the international usage of oil spill dispersants and presents the technical limitations with the use of such agents as well as the biological effects of these chemical products. IVL, has also conducted an analysis of the pros and cons to using dispersants against oil spills in waters and has applied this with a risk assessment of chemical methods to combat oil spills in the Kattegat and Skagerrak and the Baltic Sea.

  7. Oil palm and the emission of greenhouse gasses- from field measurements in Indonesia

    Science.gov (United States)

    Rahman, Niharika; Bruun, Thilde Bech; Giller, Ken E.; Magid, Jakob; van de Ven, Gerrie; de Neergaard, Andreas

    2017-04-01

    Palm oil from the oil palm (Elaeis guianensis) has in recent years become the world's most important vegetable oil. The increasing demand for palm oil has led to expansion of oil palm plantations, which has caused environmental controversies associated with carbon losses and the use of large amounts of mineral fertilizers. Efforts to increase sustainability of oil palm cultivation, include recycling of oil-mill residues and pruning's, but with this comes increased potential for methane emission from the plantations. Until now no field-based data on greenhouse gas emissions from oil palm plantations have been reported. Here for the first time we present data from a long term (360 days) field trial in Bah Lias Research Station, North Sumatra, Indonesia on greenhouse gas emissions from an oil palm plantation with various treatments of recycled oil palm waste products, fertilizers and simulated rainfall. The first experiment was conducted over a full year (dry + wet season) with mineral fertilizer treatments including urea and ammonium sulphate, and organic fertilizer treatments constituting: empty fruit bunches (EFB), enriched mulch (EFB + palm oil mill effluent (POME) ) and pruned oil palm fronds (OPF). Treatment doses represent the current management in Indonesian plantations and the higher doses that are expected in the imminent future. For the organic treatments several methods of application (applied in inter-rows, piles, patches or bands) were evaluated. The second experiment investigated effects of soil water saturation on GHG emissions through adding 25 mm simulated rainfall per day for 21 days. Each palm tree received 1 kg of N fertilizer as urea or ammonium sulphate and enriched mulch. The gas fluxes in the fields was measured by a large static-chamber (1.8 m x 1.2 m) method and CH4 and N2O concentrations were determined using gas chromatographs. We found that emissions were significantly affected by the type and dose of mineral fertilizers. Application of

  8. Verifying a Simplified Fuel Oil Flow Field Measurement Protocol

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, H.; Dentz, J.; Doty, C.

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  9. Verifying a Simplified Fuel Oil Field Measurement Protocol

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, Hugh [Advanced Residential Integrated Energy Solutions Collaborative (ARIES), New York, NY (United States); Dentz, Jordan [Advanced Residential Integrated Energy Solutions Collaborative (ARIES), New York, NY (United States); Doty, Chris [Advanced Residential Integrated Energy Solutions Collaborative (ARIES), New York, NY (United States)

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  10. Reserve Growth in Oil Fields of West Siberian Basin, Russia

    Science.gov (United States)

    Verma, Mahendra K.; Ulmishek, Gregory F.

    2006-01-01

    Although reserve (or field) growth has proven to be an important factor contributing to new reserves in mature petroleum basins, it is still a poorly understood phenomenon. Limited studies show that the magnitude of reserve growth is controlled by several major factors, including (1) the reserve booking and reporting requirements in each country, (2) improvements in reservoir characterization and simulation, (3) application of enhanced oil recovery techniques, and (4) the discovery of new and extensions of known pools in discovered fields. Various combinations of these factors can affect the estimates of proven reserves in particular fields and may dictate repeated estimations of reserves during a field's life. This study explores the reserve growth in the 42 largest oil fields in the West Siberian Basin, which contain about 55 percent of the basin's total oil reserves. The West Siberian Basin occupies a vast swampy plain between the Ural Mountains and the Yenisey River, and extends offshore into the Kara Sea; it is the richest petroleum province in Russia. About 600 oil and gas fields with original reserves of 144 billion barrels of oil (BBO) and more than 1,200 trillion cubic feet of gas (TCFG) have been discovered. The principal oil reserves and most of the oil fields are in the southern half of the basin, whereas the northern half contains mainly gas reserves. Sedimentary strata in the basin consist of Upper Triassic through Tertiary clastic rocks. Most oil is produced from Neocomian (Lower Cretaceous) marine to deltaic sandstone reservoirs, although substantial oil reserves are also in the marine Upper Jurassic and continental to paralic Lower to Middle Jurassic sequences. The majority of oil fields are in structural traps, which are gentle, platform-type anticlines with closures ranging from several tens of meters to as much as 150 meters (490 feet). Fields producing from stratigraphic traps are generally smaller except for the giant Talin field which

  11. Geochemical Specific Characters of the Oil and the Origin of the Oil and Gas Fields

    Science.gov (United States)

    Gottikh, Rimma; Pisotskiy, Bogdan; Plotnikova, Irina

    2010-05-01

    It is generally assumed that the fluid regime of the basement of ancient platforms is not associated with that of the sedimentary cover. This assumption is mainly due to the substantial time gap between the formation of the crystalline and sedimentary rocks as well as the evolutionary differences between the thermal regime of the interior and the redox potentials of fluid systems. The presence of loosely aggregated zones filled with salt-water solutions, oil or gas in the upper basement is explained by downward fluid flows from sedimentary rocks through tectonic faults into the disintegrated crystalline rocks. The formation of such zones is believed to be due to the crustal stratification due to Earth's pulsation, periodic variations of its rotational rate, hydrogenic deconsolidation, burial of the post-Early Proterozoic disintegration zones, etc. This pattern suggests that the matter and energy exchange between the Earth's spheres in the late stages of the platform development could only take place with the help of magmatic melts and the associated fluids during the tectonomagmatic cycles of the Earth's crust transformation. Gas and liquid hydrocarbon components mainly occur in crystalline basement rocks of ancient platforms penetrated to a depth of more than 3000 m due to deep degassing processes. The traces of the upward migration of fluids are sealed in the geological sequence, including the sedimentary cover, within secondary inclusions of rocks and minerals. The fluids are complex, reduced, multicomponent systems that transport lithophilous, chalcophilous and siderophilous elements. The presence of microelements in the bituminous phase of inclusions indicates that metals mainly occur in the complexes containing organic ligands. During the evolution of the fluid systems under new pressure and temperature conditions, low-solubility substances were separated out of the fluid to form hard bitumen, and the lighter components migrated into the overlying fractured

  12. Spatial variations of hydrocarbon contamination and soil properties in oil exploring fields across China.

    Science.gov (United States)

    Liang, Yuting; Zhang, Xu; Wang, Jian; Li, Guanghe

    2012-11-30

    Successful site remediation is critically based on a comprehensive understanding of distribution of contaminants, soil physico-chemical and microbial properties in oil contaminated sites. One hundred and ten topsoils were sampled from seven typical oil fields in different geoclimate regions across north to south China to investigate the spatial variances of oil contaminations and soil parameters. Oil concentrations and compositions, soil geochemical properties and microbial populations were analyzed and statistic analysis methods were used to analyze the spatial pattern of soil variables. The results indicated that oil contaminations were serious in most oil exploring areas in China, especially with high levels of polycyclic aromatic hydrocarbons (PAHs) from petrogenic origin. Ordination analyses indicated a relatively distinct spatial pattern that all soil samples grouped mainly by geographic locations, instead of distributing along contamination or other geochemical variable gradient. Microbial populations were found to be statistically positively correlated with soil nitrogen, phosphorus and water content, and negatively correlated with salt pH and soluble salts (Phydrocarbon-contaminated fields across large spatial scales, which is important for the environmental protection and further remediation in oil contaminated sites according to local conditions. Copyright © 2012 Elsevier B.V. All rights reserved.

  13. Process and economic model of in-field heavy oil upgrading using aqueous pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Thorsness, C. B., LLNL

    1997-01-21

    A process and economic model for aqueous pyrolysis in-field upgrading of heavy oil has been developed. The model has been constructed using the ASPEN PLUS chemical process simulator. The process features cracking of heavy oil at moderate temperatures in the presence of water to increase oil quality and thus the value of the oil. Calculations with the model indicate that for a 464 Mg/day (3,000 bbl/day) process, which increases the oil API gravity of the processed oil from 13.5{degree} to 22.4{degree}, the required value increase of the oil would need to be at least $2.80/Mg{center_dot}{degree}API($0.40/bbl{center_dot}{degree}API) to make the process economically attractive. This level of upgrading has been demonstrated in preliminary experiments with candidate catalysts. For improved catalysts capable of having the coke make and increasing the pyrolysis rate, a required price increase for the oil as low as $1.34/Mg{center_dot}{degree}API ($0.21/bbl{center_dot}{degree}API)has been calculated.

  14. Correlation of source rocks and oils in the Sespe oil field, Ventura County, California

    Energy Technology Data Exchange (ETDEWEB)

    Lillis, P.G. (Geological Survey, Lakewood, CO (United States)); Clark, M.S. (Colorado School of Mines, Golden (United States))

    1991-02-01

    The Sespe oil field in the central Ventura basin produces low sulfur (< 1%), intermediate gravity (23-32{degree} API) oil from Middle Eocene to Lower Miocene reservoirs in the upper plate of the San Cayetano thrust. Previous studies proposed the Eocene Cozy Dell, Matilija, and Juncal formations in the San Cayetano overthrust as the source rocks. Alternatively, the oils could be derived from the Miocene Monterey Formation in the subthrust. Gas chromatography and gas chromatography/mass spectrometry data are used to characterize and correlate the Sespe oils from comparison with bitumen extracts of the possible source rocks. The oils have pristane/phytane ratios of 1.3-1.6, bisnorhopane/hopane ratios of about 0.2, and relatively low amounts of diasteranes, oleanane, and C{sub 29} steranes. These data indicate that all of the oils belong to the same family and that variations in the API gravity are due to the degree of biodegradation. In addition, the sterane and triterpane distributions imply that the source organic matter is derived from marine phytoplankton and bacteria with a minor contribution from land plants. The Sespe oils do not correlate with the upper plate Eocene source rocks but correlate fairly well with the upper plate Eocene source rocks. Thus, a subthrust source is proposed. However, the Sespe oils have higher gravity and lower sulfur content than typical Monterey oils. The low sulfur content may result from the higher iron content, due to terrigenous input, of the Sespe field source rocks relative to other Monterey source rocks. Alternatively, the Sespe oils were expelled from the Monterey Formation at relatively high levels of thermal maturity.

  15. Deepwater oil and gas field development in South China Sea

    Institute of Scientific and Technical Information of China (English)

    Zhang Dagang; Wybro Pieter; Kang Yongtian

    2013-01-01

    This paper focuses on potential development models of future oil and gas exploration in South China Sea.A detailed study of current development models worldwide is performed through some examples of industry installed/ongoing projects and major technical issues encountered during these practice.Key technologies are discussed for the success of field development.Some of the technologies and field development experience can be used for South China Sea project.Several models are studied in field development for different scenarios,including marginal field,large oil field and gas field.With the massive investment activities,continued improved technologies,and rapidly growing pool of professionals,the offshore industry in China will soon encounter a golden period.

  16. Alkanes in shrimp from the Buccaneer Oil Field

    Energy Technology Data Exchange (ETDEWEB)

    Middleditch, B.S.; Basile, B.; Chang, E.S.

    1982-07-01

    A total of 36 samples of shrimp were examined from the region of the Buccaneer oil field, eighteen of which were representatives of the commercial species Penaeus aztecus and the rest were various other species: Penaeus duorarum (pink shrimp), Trachypenaeus duorarum (sugar shrimp), Squilla empusa (mantis shrimp), and Sicyonia dorsalis (chevron shrimp). The alkanes and deuteriated alkanes were completely separated by GC, so a mass spectrometer was not required for their detection and quantitation. To confirm the identities of individual compounds, however, some samples were examined by combined gas chromatography-mass spectrometry. Results show that only thirteen of the forty shrimp collected from the region of the Buccaneer oil field contained petroleum alkanes, and the majority of these were obtained from trawls immediately adjacent to the production platforms. It appears that shrimp caught in the region of the Buccaneer oil field are not appreciably tainted with hydrocarbons discharged from the production platforms. (JMT)

  17. Cumulative impacts of oil fields on northern alaskan landscapes.

    Science.gov (United States)

    Walker, D A; Webber, P J; Binnian, E F; Everett, K R; Lederer, N D; Nordstrand, E A; Walker, M D

    1987-11-06

    Proposed further developments on Alaska's Arctic Coastal Plain raise questions about cumulative effects on arctic tundra ecosystems of development of multiple large oil fields. Maps of historical changes to the Prudhoe Bay Oil Field show indirect impacts can lag behind planned developments by many years and the total area eventually disturbed can greatly exceed the planned area of construction. For example, in the wettest parts of the oil field (flat thaw-lake plains), flooding and thermokarst covered more than twice the area directly affected by roads and other construction activities. Protecting critical wildlife habitat is the central issue for cumulative impact analysis in northern Alaska. Comprehensive landscape planning with the use of geographic information system technology and detailed geobotanical maps can help identify and protect areas of high wildlife use.

  18. A field laboratory for improved oil recovery. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrandt, A.F.; McDonald, J.; Claridge, E.; Killough, J.

    1992-09-01

    The purpose of Annex III of the Memorandum of Understanding, undertaken by the Houston Petroleum Research Center at the University of Houston, was to develop a field laboratory for research in improved oil recovery using a Gulf Coast reservoir in Texas. The participants: (1) make a field site selection and conducted a high resolution seismic survey in the demonstration field, (2) obtained characteristics of the reservoir (3) developed an evaluation of local flood efficiency in different parts of the demonstration reservoir, (4) used diverse methodology to evaluate the potential recovery of the remaining oil in the test reservoir, (5) developed cross-well seismic tomography, and (6) will transfer the learned technologies to oil operators through publication and workshops. This abstract is an overview of these tasks.

  19. Nonlinear Dynamic Characteristics of Oil-in-Water Emulsions

    Science.gov (United States)

    Yin, Zhaoqi; Han, Yunfeng; Ren, Yingyu; Yang, Qiuyi; Jin, Ningde

    2016-08-01

    In this article, the nonlinear dynamic characteristics of oil-in-water emulsions under the addition of surfactant were experimentally investigated. Firstly, based on the vertical upward oil-water two-phase flow experiment in 20 mm inner diameter (ID) testing pipe, dynamic response signals of oil-in-water emulsions were recorded using vertical multiple electrode array (VMEA) sensor. Afterwards, the recurrence plot (RP) algorithm and multi-scale weighted complexity entropy causality plane (MS-WCECP) were employed to analyse the nonlinear characteristics of the signals. The results show that the certainty is decreasing and the randomness is increasing with the increment of surfactant concentration. This article provides a novel method for revealing the nonlinear dynamic characteristics, complexity, and randomness of oil-in-water emulsions with experimental measurement signals.

  20. Protonated Melamine Sponge for Effective Oil/Water Separation

    Science.gov (United States)

    Wang, Chih-Feng; Huang, Hsiang-Ching; Chen, Liang-Ting

    2015-09-01

    In this study, we fabricated a superhydrophilic and underwater superoleophobic protonated melamine sponge for effective separation of water-rich immiscible oil/water mixtures with extremely high separation efficiency. This protonated melamine sponge exhibited excellent antifouling properties and could be used to separate oil/water mixtures continuously for up to 12 h without any increase in the oil content in filtrate. Moreover, our compressed protonated melamine sponge could separate both surfactant-free and -stabilized oil-in-water emulsions with high separation efficiencies. The high performance of this protonated melamine sponge and its efficient, energy- and cost-effective preparation suggest that it has great potential for use in practical applications.

  1. Produced Water Treatment for Beneficial Use: Emulsified Oil Removal

    NARCIS (Netherlands)

    Waisi, B.I.H.

    2016-01-01

    The development of novel carbon material, high accessible surface area, interconnected porosity, and stable nanofiber nonwoven media for emulsified oil droplets separation from oily wastewater, in particular for oilfields produced water treatment, is discussed in this thesis. Firstly, the quantity

  2. Water footprints of products of oil palm plantations and palm oil mills in Thailand.

    Science.gov (United States)

    Suttayakul, Phetrada; H-Kittikun, Aran; Suksaroj, Chaisri; Mungkalasiri, Jitti; Wisansuwannakorn, Ruthairat; Musikavong, Charongpun

    2016-01-15

    The water footprint (WF) of fresh fruit bunches (FFBs) from oil palm plantations and crude palm oil (CPO) from palm oil mills in southern and eastern Thailand were determined over 25 years. Climatic conditions, soil characteristics, and the characteristics of oil palm growth were considered. The WF of FFBs was 1063 m(3)/ton (t) on average. Green, blue, and grey waters comprised of 68, 18, and 14% of total WF, respectively. The oil palm plantations in Thailand required smaller amounts of indirect blue water. The average WF for producing a ton of CPO of seven mills was 5083 m(3). Most of the waters used in the mills originated from indirect green, blue and grey waters from the plantations. The direct blue water used in the mills had less impact on the total WF, lower than 1% of the total WF. Average percentages of green, blue, and grey waters of 69, 16, and 15% of total WF were determined for the mills, respectively. The water deprivation of the FFBs and CPO ranged from 0.73-12.9 and 3.44-58.3 m(3)H2Oeq/t, respectively. In 2013, the CPO production in Thailand including green, blue, and grey waters from plantation and blue water from mills required 11,343 million m(3) water. If the oil palm variety Suratthani 7 is used in the plantation, it would increase the yield from 15.2 to 22.8 t FFBs/ha-year and decrease the WF to 888 m(3)/t FFBs. The average value of the oil extraction rate (OER) of mills was 18.1%. With an increase in the OER of 1%, a reduction of the WF of 250 m(3)/t CPO or 5.1% of total WF could be obtained.

  3. MATHEMATICAL MODEL OF PURIFICATION PROCESS OF OIL CONTAMINATED WATERS

    Directory of Open Access Journals (Sweden)

    С. Бойченко

    2012-04-01

    Full Text Available Sorption properties of carbonic sorbents on natural raw materials for purification of waste waters frompetroleum products are investigated. Temperature influence on sumption properties of sorbents on naturalraw materials to increase the purification degree of water ecosystem is studied. Mathematical model ofpurification process of oil contaminated waters is developed

  4. MATHEMATICAL MODEL OF PURIFICATION PROCESS OF OIL CONTAMINATED WATERS

    OpenAIRE

    С. Бойченко; Кучер, О.; Л. Павлюх

    2012-01-01

    Sorption properties of carbonic sorbents on natural raw materials for purification of waste waters frompetroleum products are investigated. Temperature influence on sumption properties of sorbents on naturalraw materials to increase the purification degree of water ecosystem is studied. Mathematical model ofpurification process of oil contaminated waters is developed

  5. Measuring marine oil spill extent by Markov Random Fields

    Science.gov (United States)

    Moctezuma, Miguel; Parmiggiani, Flavio; Lopez Lopez, Ludwin

    2014-10-01

    The Deepwater Horizon oil spill of the Gulf of Mexico in the spring of 2010 was the largest accidental marine oil spill in the history of the petroleum industry. An immediate request, after the accident, was to detect the oil slick and to measure its extent: SAR images were the obvious tool to be employed for the task. This paper presents a processing scheme based on Markov Random Fields (MRF) theory. MRF theory describes the global information by probability terms involving local neighborhood representations of the SAR backscatter data. The random degradation introduced by speckle noise is dealt with a pre-processing stage which applies a nonlinear diffusion filter. Spatial context attributes are structured by the Bayes equation derived from a Maximum-A-Posteriori (MAP) estimation. The probability terms define an objective function of a MRF model whose goal is to detect contours and fine structures. The markovian segmentation problem is solved with a numerical optimization method. The scheme was applied to an Envisat/ASAR image over the Gulf of Mexico of May 9, 2010, when the oil spill was already fully developed. The final result was obtained with 51 recursion cycles, where, at each step, the segmentation consists of a 3-class label field (open sea and two oil slick thicknesses). Both the MRF model and the parameters of the stochastic optimization procedure will be provided, together with the area measurement of the two kinds of oil slick.

  6. PRESERVATION OF AVOCADO OIL WITH ELECTRIC FIELD TREATMENT

    OpenAIRE

    J.A. Ariza-Ortega; E. Ramírez-Moreno; M.E. Ramos-Cassellis; J. Díaz-Reyes

    2014-01-01

    The aim of this study was to analyze the effect of different conditions of electric field (voltage 3 kV cm-1, 60 Hz, 10 and 180 s; 720 Hz, 10 and 180 s) as method on preservation up to 365 days on oil extracted of the avocado pulp. Unsaturated fatty acid oxidation in crude avocado oil was analyzed by Fourier transform infrared spectroscopy technique in the mid infrared region and by quality parameters (acidity, peroxide and iodine). The electric field caused minimal changes on unsaturated fat...

  7. Water Flooding Development and Enhanced Oil Recovery of Daqing Oilfields

    Institute of Scientific and Technical Information of China (English)

    Cao Zefu; Yue Dengtai; Rong Jiashu

    1997-01-01

    @@ The Daqing oil region consists of typical sand oilfields formed by a large inland shallow water lake basin and riverdelta. It is characterized by multiple reservoirs, extreme heterogeneity, and insufficient natural oil reservoir energy. A comparatively long period of high stable yield and high efficiency recovery was achieved in the initial stage of development through the use of the hydraulic pressure drive technique, which manually injected water to maintain formation pressure.

  8. Application of bio-huff-`n`-puff technology at Jilin oil field

    Energy Technology Data Exchange (ETDEWEB)

    Xiu-Yuan Wang; Yan-Fed Xue; Gang Dai; Ling Zhao [Institute of Microbiology, Beijing (China)] [and others

    1995-12-31

    An enriched culture 48, capable of adapting to the reservoir conditions and fermenting molasses to produce gas and acid, was used as an inoculum for bio- huff-`n`-puff tests at Fuyu oil area of Jilin oil field. The production well was injected with water containing 4-6% (v/v) molasses and inoculum, and then shut in. After 15-21 days, the well was placed back in operation. A total of 44 wells were treated, of which only two wells showed no effects. The daily oil production of treated wells increased by 33.3-733.3%. Up to the end of 1994, the oil production was increased by 204 tons per well on average. Results obtained from various types of production wells were discussed.

  9. Chemical Equilibrium and Mineral Saturation in Waters from Oil Wells of the Activo Luna Field, Tabasco, Mexico; Equilibrio quimico y grado de saturacion de minerales en aguas de pozos petroleros de Activo Luna, Tabasco, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Barragan R, Rosa Maria; Arellano G, Victor M.; Portugal M, Enrique; Torres R, Vicente [Instituto de Investigaciones Electricas (Mexico); Torres Alvarado, Ignacio [Universidad Nacional Autonoma de Mexico (Mexico); Ascencio C, Fernando; Martinez A; Ana E [Petroleos Mexicanos (Mexico)

    2001-09-01

    Chemical equilibrium of formation waters from seven oil wells of the Activo Luna field (Tabasco, Mexico) was modelled. Saturation indices of characteristic hydrothermal minerals were calculated at ambient and reservoir conditions in order to predict scaling potential of deep and surface installations. The salinity of waters was found to be in the range from 43,000 (well Escuintle 2) to 250,000 (well Lune 3B) mg/kg as total dissolved solids. The water samples were classified as sodium-chioride type. Ionic strength for the solutions was found to be between 0.75 and 6.5. Activity coefficients were estimated by virial (Pitzer equations) methods using the GEOCHEMIST WORKENCH (GWB) software. Minerals such as anhydrite, halite, alunite, fluorite and barite were found to be supersaturated at reservoir conditions. A solid scale sample obtained from well Luna-3B was analysed. Analysis indicate the presence of calcite, anhydrite, fluorite and sphalerite which suggest the occurrence of temperatures of at least 180 Celcius degrees with acidic conditions and high chemical corrosion potential. [Spanish] Se modelo el equilibrio quimico de aguas de formacion producidas por siete pozos petroleros pertenecientes al Activo Luna, en el estado de Tabasco, Mexico, se calcularon los indices de saturacion de minerales caracteristicos tanto en las condiciones ambiente como en las de yacimiento, con el proposito de apoyar el control de incrustaciones en las instalaciones superficiales y profundas. La salinidad de las salmueras se encontro en el rango de 43,000 (pozos Escuintle 2) a 250,000 (pozos Luna 3B) mg/kg de solidos disueltos totales y las muestras se clasificaron como del tipo clorurado-sodico. La fuerza ionica de las soluciones varia entre 0.75 y 6.5 molar, por lo que los coeficientes de actividad de la modelacion de equilibrio quimico se estimaron por metodos viriales empleando las ecuaciones de Pitzer mediante el programa GEOCHEMIST WORKBENCH (GWB). Minerales como anhidrita, halita

  10. The Terra Nova oil field development

    Energy Technology Data Exchange (ETDEWEB)

    Bruce, G.C. [Petro-Canada, Inc., St. John' s, NF (Canada)

    2001-07-01

    Before expanding on the development of the Terra Nova oilfield, the author discussed the overall business strategy of Petro-Canada and identified where the Terra Nova and offshore Newfoundland oil have their place within this strategy. The principal basins and oilfields offshore Newfoundland were reviewed, then the emphasis shifted to rest on the Terra Nova development project. A whole range of topics were brought up, including the Floating Production, Storage and Offloading (FPSO) facility, the modules layout, the FPSO located at Bull Arm, and the floating production systems. The physical environment of the Grand Banks was highlighted, and the next few sections were devoted to the Terra Nova FPSO, FPSO and drill centres, the Turret General Arrangement, and Spider buoy including the disconnect/reconnect. The last four sections dealt with the animation of riser movement, the wellhead protection animation, Henry Goodrich, and operations readiness.

  11. Energy fluxes in oil palm plantations as affected by water storage in the trunk

    Science.gov (United States)

    Meijide, Ana; Röll, Alexander; Fan, Yuanchao; Herbst, Mathias; Niu, Furong; Tiedemann, Frank; June, Tania; Rauf, Abdul; Hölscher, Dirk; Knohl, Alexander

    2017-04-01

    Oil palm is increasingly expanding, particularly in Indonesia, but information on water and energy fluxes in oil palm plantations is still very limited and on how those are affected by environmental conditions or oil palm age. Using the eddy covariance technique, we studied turbulent fluxes of sensible (H) and latent (LE) heat and gross primary production (GPP) for 8 months each in a young oil palm plantation (1-year old) and subsequently in a mature plantation (12-year old) in Jambi Province, Sumatra, Indonesia. We measured transpiration (T) simultaneously using a sap flux technique. The energy budget was dominated by LE in both plantations, particularly in the mature one, where it represented up to 70% of the available energy. In the young oil palm plantation, evapotranspiration (ET) was significantly reduced and H fluxes were higher. This affected the Bowen ratio, defined as the ratio of H and LE, which was higher in the 1-year old plantation (0.67±0.33), where it remained constant during the day, than in the mature plantation (0.14±0.09), where it varied considerably over the day, suggesting that water accumulated inside the canopy. Using the Community Land Model (CLM), a process based land surface model that has been adapted to oil palm functional traits (i.e. CLM-Palm), we investigated the contribution of different water sources to the measured fluxes. CLM-Palm differentiates leaf and stem surfaces in modelling water interception and is therefore able to diagnose the fraction of dry leaves that contribute to T and the wet fraction of all vegetation surfaces (leaf and stem) that contributes to evaporation. Results from our simulations strengthen our hypothesis of significant contribution of canopy evaporation to ET. As observed in the field, water accumulates inside the canopy in the mature plantation in oil palm trunk surfaces including epiphytes, creating water reservoirs in the trunk, which potentially contribute to ET when they evaporate. The decoupling

  12. 电感耦合等离子体发射光谱法测定油田水中的硼%Determination of Boron in Oil Field Water by Inductively Coupled Plasma-Atomic Emission Spectrometry

    Institute of Scientific and Technical Information of China (English)

    宋继芳

    2012-01-01

    样品经硝酸酸化、滤膜过滤处理后,用电感耦合等离子体发射光谱法直接测定其中硼的含量.通过正交实验优选仪器参数和分析谱线,在选定的波长208.959nm下,对样品稀释倍数和介质酸种类进行选择,结果表明,硼含量低于10mg/L的样品不用稀释,高于10mg/L的样品一般稀释20倍,介质选用硝酸可使测定结果更加准确.对油田水中共存的7种主要金属元素进行了干扰试验,样品中存在20mg/L的Sr、Ba、Fe,50mg/L的Mg、Ca,100mg/L的K,200mg/L的Na对待测元素的测定没有影响.选取油田水样品进行加标回收试验,方法平均回收率为95.3%~102.0%,精密度(RSD,n=11)为0.43%~0.92%,检出限为0.0020mg/L.方法简便、快速,结果令人满意,与姜黄素分光光度法比较,克服了分析流程长、使用试剂较多且不易操作的不足.%Boron in oil field water has been directly determined by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) after sample were treated with nitric acid and filtrated. This method overcomes the problems of spectrophotometry such as long analysis flow, more reagent and difficulty in controlling the chemical procedure. The working parameters and the spectral line were optimized by orthogonal tests. The dilute multiple and acid medium were analyzed using the selected 208.959 nm frequency. The results show that it is not necessary to dilute the sample when the content of B is less than 10 mg/L, and the dilution factor is 20 when B is greater than 10 mg/L. The selected HNO3 as the acid medium, improved the accuracy of the results. The interference tests were carried out for 7 major metals in oil field water. 20 mg/L Sr, Ba and Fe, 50 mg/L Mg and Ca, 100 mg/L K and 200 mg/L Na have no interference for the measurements of the target element. The detection limit of boron was 0.0020 mg/L and the recoveries ranged from 95.3% to 102.0% with a precision in the range of 0.43% - 0.92% ( RSD, n = 11

  13. Numerical simulation and structural optimization of the inclined oil/water separator.

    Directory of Open Access Journals (Sweden)

    Liqiong Chen

    Full Text Available Improving the separation efficiency of the inclined oil/water separator, a new type of gravity separation equipment, is of great importance. In order to obtain a comprehensive understanding of the internal flow field of the separation process of oil and water within this separator, a numerical simulation based on Euler multiphase flow analysis and the realizable k-ε two equation turbulence model was executed using Fluent software. The optimal value ranges of the separator's various structural parameters used in the numerical simulation were selected through orthogonal array experiments. A field experiment on the separator was conducted with optimized structural parameters in order to validate the reliability of the numerical simulation results. The research results indicated that the horizontal position of the dispenser, the hole number, and the diameter had significant effects on the oil/water separation efficiency, and that the longitudinal position of the dispenser and the position of the weir plate had insignificant effects on the oil/water separation efficiency. The optimal structural parameters obtained through the orthogonal array experiments resulted in an oil/water separation efficiency of up to 95%, which was 4.996% greater than that realized by the original structural parameters.

  14. Numerical simulation and structural optimization of the inclined oil/water separator.

    Science.gov (United States)

    Chen, Liqiong; Wu, Shijuan; Lu, Hongfang; Huang, Kun; Zhao, Lijie

    2015-01-01

    Improving the separation efficiency of the inclined oil/water separator, a new type of gravity separation equipment, is of great importance. In order to obtain a comprehensive understanding of the internal flow field of the separation process of oil and water within this separator, a numerical simulation based on Euler multiphase flow analysis and the realizable k-ε two equation turbulence model was executed using Fluent software. The optimal value ranges of the separator's various structural parameters used in the numerical simulation were selected through orthogonal array experiments. A field experiment on the separator was conducted with optimized structural parameters in order to validate the reliability of the numerical simulation results. The research results indicated that the horizontal position of the dispenser, the hole number, and the diameter had significant effects on the oil/water separation efficiency, and that the longitudinal position of the dispenser and the position of the weir plate had insignificant effects on the oil/water separation efficiency. The optimal structural parameters obtained through the orthogonal array experiments resulted in an oil/water separation efficiency of up to 95%, which was 4.996% greater than that realized by the original structural parameters.

  15. Stabilized oil production conditions in the development equilibrium of a water-flooding reservoir

    Directory of Open Access Journals (Sweden)

    Renshi Nie

    2016-12-01

    Full Text Available Water injection can compensate for pressure depletion of production. This paper firstly investigated into the equilibrium issue among water influx, water injection and production. Equilibrium principle was elaborated through deduction of equilibrium equation and presentation of equilibrium curves with an “equilibrium point”. Influences of artificial controllable factors (e.g. well ratio of injection to production and total well number on equilibrium were particularly analyzed using field data. It was found that the influences were mainly reflected as the location move of equilibrium point with factor change. Then reservoir pressure maintenance level was especially introduced to reveal the variation law of liquid rate and oil rate with the rising of water cut. It was also found that, even if reservoir pressure kept constant, oil rate still inevitably declined. However, in the field, a stabilized oil rate was always pursued for development efficiency. Therefore, the equilibrium issue of stabilized oil production was studied deeply through probing into some effective measures to realize oil rate stability after the increase of water cut for the example reservoir. Successful example application indicated that the integrated approach was very practical and feasible, and hence could be used to the other similar reservoir.

  16. Effective strategies for development of thermal heavy oil field facilities

    Energy Technology Data Exchange (ETDEWEB)

    Davis, Ken; Lehnert-Thiel, Gunter [IMV Projects (Canada)

    2011-07-01

    In thermal heavy oil, a significant part of the capital has to be invested in field facilities and therefore strategies have to be implemented to optimize these costs. Field facilities consist of pipelines, earthworks and production pads whose purpose is to connect an oilsands reservoir to a central processing facility. This paper, presented by IMV Projects, a leading company in the thermal heavy oil field, highlights strategies to manage field facility lifecycle cost. Upfront planning should be done and the development of field facilities should be thought of as a long term infrastructure program rather than a stand-alone project. In addition, templates should be developed to save money and repeatability should be implemented to obtain a better prediction of the program's costs. The strategies presented herein allow major savings over the program's life by implementing an improved schedule and allowing refinements all along the program's course.

  17. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes

  18. The influence of magnetic fields on crude oils viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Jose L.; Bombard, Antonio J. F. [Universidade Federal de Itajuba (UNIFEI), Itajuba, MG (Brazil). Instituto de Ciencias Exatas. Lab. de Reologia

    2009-07-01

    The crystallization of paraffin causes serious problems in the process of transportation of petroleum. This phenomenon increases the crude oil viscosity and implies an organic resin accumulation on pipeline wall, resulting in a reduced flux area or totally blocked pipes. One of the most challenging tasks for pipeline maintenance is solving this problem at low cost. Therefore, a method that inhibits the crystallization of paraffin and reduces the viscosity of crude oil could have many useful applications within the petroleum industry. Recent studies showed that magnetic fields reduce the Wax Appearance Temperature (WAT) and the viscosity of paraffin-based crude oil. For better understanding of this discovery, a series of tests was performed. This paper will show the influence of a DC magnetic field on rheological proprieties of three crude oils with different paraffin concentrations: a crude oil sample with 11 % p/p of paraffin concentration (sample 1); a crude oil sample with 6 % p/p of paraffin concentration (sample 2); a mixture of paraffin plus light crude oil with a total of 11 % p/p of paraffin concentration. These samples were placed in an electromagnet that generates a magnetic field of 1.3 Tesla. The samples' temperatures were conditioned around their Wax Appearance Temperature (WAT), and they were exposed to the field. As the viscosity of crude oil is very sensitive to the changes in temperature, it was ensured that the temperature has remained constant throughout the process. The sample 1 revealed a considerable reduction of viscosity: its original viscosity was 66 cP before magnetic field exposure, after that its viscosity was reduced to 39 cP. The other samples showed the same viscosity, before and after the magnetic field exposure. Since the samples 1 and 3 have the same paraffin concentrations, the viscosity reduction is not due only to the presence of paraffin; there must be other factors responsible for the interaction of sample 1 with the

  19. An experimental study on the motion of water droplets in oil under ultrasonic irradiation.

    Science.gov (United States)

    Luo, Xiaoming; He, Limin; Wang, Hongping; Yan, Haipeng; Qin, Yahua

    2016-01-01

    The motion of a single water droplet in oil under ultrasonic irradiation is investigated with high-speed photography in this paper. First, we described the trajectory of water droplet in oil under ultrasonic irradiation. Results indicate that in acoustic field the motion of water droplet subjected to intermittent positive and negative ultrasonic pressure shows obvious quasi-sinusoidal oscillation. Afterwards, the influence of major parameters on the motion characteristics of water droplet was studied, such as acoustic intensity, ultrasonic frequency, continuous phase viscosity, interfacial tension, and droplet diameter, etc. It is found that when the acoustic intensity and frequency are 4.89 W cm(-2) and 20 kHz respectively, which are the critical conditions, the droplet varying from 250 to 300 μm in lower viscous oil has the largest oscillation amplitude and highest oscillation frequency.

  20. Increased Oil Recovery from Mature Oil Fields Using Gelled Polymer Treatments

    Energy Technology Data Exchange (ETDEWEB)

    Willhite, G.P.; Green, D.W.; McCool, S.

    2001-03-28

    Gelled polymer treatments were applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report is aimed at reducing barriers to the widespread use of these treatments by developing methods to predict gel behavior during placement in matrix rock and fractures, determining the persistence of permeability reduction after gel placement, and by developing methods to design production well treatments to control water production. Procedures were developed to determine the weight-average molecular weight and average size of polyacrylamide samples in aqueous solutions. Sample preparation techniques were key to achieving reproducible results.

  1. Stable highly hydrophobic and oleophilic meshes for oil water separation

    Science.gov (United States)

    Wang, Qingjun; Cui, Zhe; Xiao, Yi; Chen, Qingmin

    2007-09-01

    This paper describes a simple method for fabricating both highly hydrophobic and oleophilic meshes by coating thin fluoro-containing films. The static contact angle of such meshes is greater than 150° for water, and close to 0° for kerosene, xylene and toluene. These meshes can separate water from oil effectively without resorting to any extra power or chemical agent. Moreover, they exhibited stable water resisting, anti-chemical erosion and anti-hot aging properties. It promises as a candidate for the separation of oil and water.

  2. Layered double hydroxide functionalized textile for effective oil/water separation and selective oil adsorption.

    Science.gov (United States)

    Liu, Xiaojuan; Ge, Lei; Li, Wei; Wang, Xiuzhong; Li, Feng

    2015-01-14

    The removal of oil and organic pollutants from water is highly desired due to frequent oil spill accidents, as well as the increase of industrial oily wastewater. Here, superhydrophobic and superoleophilic textile has been successfully prepared for the application of effective oil/water separation and selective oil adsorption. This textile was fabricated by functionalizing the commercial textile with layered double hydroxide (LDH) microcrystals and low surface energy molecules. The LDH microcrystals were immobilized on the microfibers of the textile through an in situ growth method, and they formed a nestlike microstructure. The combination of the hierarchical structure and the low surface energy molecules made the textile superhydrophobic and superoleophilic. Further experiments demonstrated that the as-prepared textile not only can be applied as effective membrane materials for the separation of oil and water mixtures with high separation efficiency (>97%), but also can be used as a bag for the selective oil adsorption from water. Thus, such superhydrophobic and superoleophilic textile is a very promising material for the application of oil spill cleanup and industrial oily wastewater treatment.

  3. Electrostatic Enhancement of Coalescence of Oil Droplets (in Nanometer Scale) in Water Emulsion

    Institute of Scientific and Technical Information of China (English)

    HOSSEINI M; SHAHAVI M.H.

    2012-01-01

    Oil droplets in nanometer scale which are dispersed in water cannot be separated easily. An attractive technique is carried out by electrical phenomena to demulsify oil in water emulsion. In this research, non-uniform electric field or dielectrophoresis (DEP) is applied to remove sunflower oil (which is dispersed in the water). Effectsof temperature, time and voltage (using AC-electric field) were considered to get the highest DEP-force (Fdi) and the best results. The oil particles sizes with average of approximately 76 nm have been shown using a ZetaSizer Nano ZS, Model ZEN 1600 (Malvem Instrument Ltd.). The maximum separation efficiency of 85% is obtained at the optimum temperature of 38 ℃ and voltage of 3000 V.

  4. Tar Creek study, Sargent oil field, Santa Clara County, California

    Science.gov (United States)

    Wagner, David L.; Fedasko, Bill; Carnahan, J.R.; Brunetti, Ross; Magoon, Leslie B.; Lillis, Paul G.; Lorenson, T.D.; Stanley, Richard G.

    2002-01-01

    Field work in the Tar Creek area of Sargent oil field was performed June 26 to 28, 2000. The Santa Clara County study area is located in Sections, 30, 31, and 32, Township 11 South, Range 4 East, M.D.B&M; and in Sections 25 and 36, Township 11 South, Range 3 East, M.D.B.&M., north and south of Tar Creek, west of Highway 101. The work was a cooperative effort of the California Department of Conservation's Division of Oil, Gas, and Geothermal Resources (DOGGR), California Geological Survey (CGS), and the United States Geological Survey (USGS). The purpose of the project was to map the stratigraphy and geologic structure (David Wagner, CGS); sample oil for age dating (Les Magoon, USGS); and search for undocumented wells plus conduct a GPS survey of the area (Bill Fedasko, J.P. Carnahan, and Ross Brunetti, DOGGR)

  5. One-Step Coating toward Multifunctional Applications: Oil/Water Mixtures and Emulsions Separation and Contaminants Adsorption.

    Science.gov (United States)

    Cao, Yingze; Liu, Na; Zhang, Weifeng; Feng, Lin; Wei, Yen

    2016-02-10

    Here, a method that can simultaneously separate oil/water mixtures and remove water-soluble contaminants has been developed. Various substrates with different pore size were coated by polydopamine and polyethylenepolyamine codeposition films. The as-prepared materials were superhydrophilic and under-water superoleophobic. The materials can separate a range of different oil/water mixtures (including immiscible oil/water mixtures and surfactant-stabilized emulsions) in a single unit operation, with >99.6% separation efficiency and high fluxes. Copper ion and methyl blue can be effectively absorbed from water when it permeates through the materials. This method can be applied on organic and inorganic substrates and used in preparing large-scale product. Therefore, the simple and facile method has excellent potential in practical application and creates a new field for oil/water separation materials with multifunctional applications.

  6. Distribution of Complex Chemicals in Oil-Water Systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad

    . In order to inhibit gas hydrate formation in subsea pipelines monoethylene glycol (MEG) and methanol are injected in large amounts. It is important to know the distribution of these chemicals in oil and water systems for economical operation of a production facility and to evaluate their impact on marine...... life. Furthermore distribution of chemicals is important information for downstream processing of oil and gas. The purpose of this project is the experimental measurement and the thermodynamic modeling of distribution of these complex chemicals in oil-water systems. Traditionally distribution...... and limited information about the molecular structure of production chemicals the correlation could only be obtained for few families like alcohols, glycols and alkanolamines with varying degree of reliability. In order to develop a thermodynamic model for the distribution of chemicals in oil-water systems...

  7. INCREASED OIL RECOVERY FROM MATURE OIL FIELDS USING GELLED POLYMER TREATMENTS

    Energy Technology Data Exchange (ETDEWEB)

    G.P. Willhite; D.W. Green; C.S. McCool

    2003-05-01

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a three-year research program aimed at reducing barriers to the widespread use of gelled polymer treatments by (1) developing methods to predict gel behavior during placement in matrix rock and fractures, (2) determining the persistence of permeability reduction after gel placement, and (3) developing methods to design production well treatments to control water production. The work focused on the gel system composed of polyacrylamide and chromium acetate. The molar mass of the polymer was about six million. Chromium(III) acetate reacted and formed crosslinks between polymer molecules. The crosslinked polymer molecules, or pre-gel aggregates, combine and grow to eventually form a 3-dimensional gel. A fundamental study to characterize the formation and growth of pre-gel aggregates was conducted. Two methods, flow field-flow fractionation (FFFF) and multi-angle laser light scattering (MALLS) were used. Studies using FFFF were inconclusive. Data taken using MALLS showed that at the gel time the average molar mass of gel aggregates increased by a factor of about three while the average size increase was approximately 50%. Increased acetate concentration in the gelant increases the gel time. The in situ performance of an added-acetate system was investigated to determine the applicability for in-depth treatments. Increased acetate concentrations delayed the development of increased flow resistance during gelant injection in short sandpacks. The development of increased flow resistance (in situ gelation) was extended from 2 to 34 days by increasing the acetate-to-chromium ratio from 38 to 153. In situ gelation occurred at a time that was approximately 22% of the bulk gelation time. When carbonate rocks are treated with gel, chromium retention in the rock may limit in

  8. Biogeographic patterns of microbial communities from different oil-contaminated fields in China

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Yuting; Li, Guanghe [School of Environment, Tsinghua University (China); Zhou, Ji zhong [Institute for Environmental Genomics, Department of Botany and Microbiology, University of Oklahoma (United States)], email: jzhou@ou.edu

    2011-07-01

    Some striking biological challenges of the 21st century include linking biodiversity to ecosystem functions, information scaling, and linking genomics to ecology. This paper discusses the biogeographic patterns of microbial communities from various oil-contaminated fields in China. Two kinds of high throughput approaches are used, open format and closed format. Key differences between them are outlined. The GeoChip, or functional gene array (FGA) approach is presented. This is a high throughput tool for linking community structure to functions. Its main advantages are its high resolution and detecting functions. This approach was applied to soils, bioreactors and ground waters, among others. Issues related to specificity, sensitivity and quantification are listed. An overview of the microarray analysis is given. This is applied to the BP oil spill. 100 samples were chosen from representative oil fields to study the biogeographic patterns of microbial communities in China. The complete study is presented with the results.

  9. Characteristics of enriched cultures for bio-huff-`n`-puff tests at Jilin oil field

    Energy Technology Data Exchange (ETDEWEB)

    Xiu-Yuan Wang; Gang Dai; Yan-Fen Xue; Shu-Hua Xie [Institute of Microbiology, Beijing (China)] [and others

    1995-12-31

    Three enriched cultures (48, 15a, and 26a), selected from more than 80 soil and water samples, could grow anaerobically in the presence of crude oil at 30{degrees}C and could ferment molasses to gases and organic acids. Oil recovery by culture 48 in the laboratory model experiment was enhanced by 25.2% over the original reserves and by 53.7% over the residual reserves. Enriched culture 48 was composed of at least 4 species belonging to the genera Eubacterium, Fusobacterium, and Bacteroides. This enriched culture was used as inoculum for MEOR field trials at Jilin oil field with satisfactory results. The importance of the role of these isolates in EOR was confirmed by their presence and behavior in the fluids produced from the microbiologically treated reservoir.

  10. IMPACT OF OIL FIELD EXPLOITATION ON ECO-ENVIRONMENT OF THE DAQING LAKES

    Institute of Scientific and Technical Information of China (English)

    YU Shao-peng; LU Jin-fu; SUN Guang-you

    2003-01-01

    The Daqing lakes are located in the region with sub-humid continental monsoon climate. Through histori-cal comparison of the environment before and after oil field exploitation in the area, the paper analyses the impact of oilfield exploitation on the eco-environment of the lakes, including the impact of diversion works, drainage works, exploita-tion and utilization of groundwater, dropped crude oil and petrochemical wastewater on the lakes water body. The analy-sis shows that oil field exploitation caused serious pollution to soil in the lakes area and deterioration of the e-co-environment. The impact became more evident with passage of time, and the intensity varied with areas, gettingmore serious from west to east, which meant that the eastern part of the lakes were influenced much more seriously by thehuman activities. To improve the eco-environment of the Daqing lakes and make them sustainable utilization, the effec-tive protection measures should be taken.

  11. Features of mixing micellar muds with oil and water in their influence on efficiency of oil displacement

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Y.; Lu, G.

    1982-01-01

    An experimental study was made of the process of mixing micellar muds (MM) and different composition with oil and water (a total of 150 samples), and also the influence of this mixing on the efficient displacement of oil with the use of MM to increase oil output. It has been indicated that the process of mixing MM with oil and water can be examined as a process of diffusion. It is described by the second law of Fick. In this case the coefficient of diffusion depends on the concentration of salt in water: with an increase in concentration of salt in water, the coefficient of diffusion of MM in water is diminished, and in oil increases. In addition, the coefficient of diffusion depends on the viscosity of MM, and is higher if the initial concentration of the diffused substance is high. It was found that in the process of mixing MM with oil in water, emulsification of dilution and selected emulsification and MM of different compositions can be divided into four types: does not emulsify in oil and water; does not emulsify in oil, but emulsifies in water; emulsifies in oil but does not emulsify in water, and emulsifies in oil and water. It was established that of the aforementioned four types of MM, type one has the highest effective displacement of oil. Injection initially of MM of type two, and then type 3 results in even higher efficiency of oil displacement.

  12. Surfactant controlled switching of water-in-oil wetting behaviour of porous silica films grown at oil-water interfaces

    Indian Academy of Sciences (India)

    Manish M Kulkarni; Rajdip Bandyopadhyaya; Ashutosh Sharma

    2008-11-01

    Selective permeation of oil and water across a porous medium, as in oil recovery operations, depends on the preferential wetting properties of the porous medium. We show a profound influence of surfactants in wetting of porous media and thus demonstrate a new route for the control of water-in-oil wetting of porous substrates by changing the concentration of surfactants in an aqueous sub-phase below the substrate. This strategy is employed to engineer partial reversible wetting transitions on a porous silica film. The film itself is grown and stabilized on a flat, macroscopic interface between an oil phase and an aqueous sub-phase. On increasing the surfactant (CTAB) concentration in the sub-phase, contact angle of a water drop (placed on the oil side of the film) changes from 140° to 16° in 25 min by diffusion of the surfactant across the porous film. On further replacement of the sub-phase with pure water, diffusion of the surfactant from the water drop back to the sub-phase was slower, increasing the contact angle in the process from 16° to 90° in 2 h. Wettability control by a cationic surfactant (CTAB) was found to be much faster (6 deg/min) than that offered by an anionic surfactant, SDS (0.05 deg/min). Switching of the surface wettability due to the surfactant diffusion may have implications in oil-water separation, chemical bed reactors and microfluidic devices.

  13. Simultaneous extraction of oil- and water-soluble phase from sunflower seeds with subcritical water.

    Science.gov (United States)

    Ravber, Matej; Knez, Željko; Škerget, Mojca

    2015-01-01

    In this study, the subcritical water extraction is proposed as an alternative and greener processing method for simultaneous removal of oil- and water-soluble phase from sunflower seeds. Extraction kinetics were studied at different temperatures and material/solvent ratios in a batch extractor. Degree of hydrothermal degradation of oils was observed by analysing amount of formed free fatty acids and their antioxidant capacities. Results were compared to oils obtained by conventional methods. Water soluble extracts were analysed for total proteins, carbohydrates and phenolics and some single products of hydrothermal degradation. Highest amount of oil was obtained at 130 °C at a material/solvent ratio of 1/20 g/mL after 30 min of extraction. For all obtained oils minimal degree of hydrothermal degradation could be identified. High antioxidant capacities of oil samples could be observed. Water soluble extracts were degraded at temperatures ≥100 °C, producing various products of hydrothermal degradation.

  14. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  15. Microbial diversity of a high salinity oil field

    Energy Technology Data Exchange (ETDEWEB)

    Neria, I.; Gales, G.; Alazard, D.; Ollivier, B.; Borgomano, J.; Joulian, C.

    2009-07-01

    This work is a preliminary study to investigate the microbial diversity of an onshore oil field. It aim to compare results obtained from molecular methods, physicochemical analyses and cultivation. A core of 1150 m depth sediments ( in situ T=45 degree centigrade) was collected and immediately frozen with liquid nitrogen prior to further investigation. Macroscopic and Scanning Electron Microscopy analyses were performed. (Author)

  16. Seismic techniques of enhanced oil recovery: experimental and field results

    Energy Technology Data Exchange (ETDEWEB)

    Kuznetsov, O.L.; Simkin, E.M.; Chilingar, G.V.; Gorfunkel, M.V.; Robertson, J.O. Jr.

    2002-09-15

    Application of secondary and tertiary oil recovery techniques during late field development stages usually yields poor results. The reasons are principally due to the low efficiency of these technologies, probably because the gravity and capillary forces are not properly considered. Improved efficiency for hydrocarbon recovery produced by seismic vibration is discussed. (author)

  17. Environmental Protection of Oil and Gas Fields 1997 Subscriptions Welcome

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    @@ ENTIRONMENTAL PROTECTION OF OIL AND GAS FIELDS is a scientific and technical periodical in Chinese with abstracts in English. jointly operated by China Petroleum Planning and Engineering Institute and Technical Supervision, Safety and Environmental Protection Bureau, CNPC and publicly distributed at home and abroad.

  18. Oil-in-water emulsification using confined impinging jets.

    Science.gov (United States)

    Siddiqui, Shad W; Norton, Ian T

    2012-07-01

    A confined impinging jet mixing device has been used to investigate the continuous sunflower oil/water emulsification process under turbulent flow conditions with oil contents between 5% (v/v) and 10% (v/v). Various emulsifiers (Tween20, Span80, Whey Protein, Lecithin and Sodium Dodecylsulphate) varying in molecular weights have been studied. Mean droplet sizes varied with the emulsifiers used and smallest droplets were obtained under fully turbulent flow regime, i.e. at the highest jet flow rate and highest jet Reynolds Number conditions. Sodium Dodecylsulfate (SDS) produced droplets in the range of 3.8 μm while 6 μm droplets were obtained with Whey Protein. Similar droplet sizes were obtained under fully turbulent flow conditions (610 mL/min; Reynolds Number=13,000) for oil content varying between 5% (v/v) and 10% (v/v). To investigate the smallest droplet size possible in the device, the emulsion was passed through the geometry multiple times. Multi-pass emulsification resulted in reduction in droplet size indicating that longer residence in the flow field under high shear condition allowed for breakage of droplets as well as the time for the emulsifier to stabilize the newly formed droplets, decreasing the impact of coalescence. This was confirmed by timescale analysis of the involved process steps for the droplet data obtained via experiments. Dependence of mean droplet size on the o/w interfacial tension and peak energy dissipation was also investigated. Copyright © 2012 Elsevier Inc. All rights reserved.

  19. The experience of arranging a back-up oil well group using the seventh bed at the Zhetybai field as an example

    Energy Technology Data Exchange (ETDEWEB)

    Lysenko, V.D.; Ermekov, A.K.; Leibin, E.L.; Savvin, K.F.; Vaslavskii, A.F.

    1981-01-01

    A method is proposed for arranging a back-up series of oil wells using the oil pool of the eighth bed located at the Zhetybai field, which has an underlying layer of water, as an example. Using a record of tapped and remaining oil reserves together with maps of existing isopachs, which were drafted accounting for the rising velocities of the water-oil contact at various sections in the bed, the placement of oil wells at one section or another of the bed is calculated. The number of oil wells is substantiated using a record of the remaining oil reserves together with a proposed oil yield standard for a single oil well.

  20. Policy Analysis of Water Availability and Use Issues for Domestic Oil Shale and Oil Sands Development

    Energy Technology Data Exchange (ETDEWEB)

    Ruple, John; Keiter, Robert

    2010-12-31

    Oil shale and oil sands resources located within the intermountain west represent a vast, and as of yet, commercially untapped source of energy. Development will require water, and demand for scarce water resources stands at the front of a long list of barriers to commercialization. Water requirements and the consequences of commercial development will depend on the number, size, and location of facilities, as well as the technologies employed to develop these unconventional fuels. While the details remain unclear, the implication is not – unconventional fuel development will increase demand for water in an arid region where demand for water often exceeds supply. Water demands in excess of supplies have long been the norm in the west, and for more than a century water has been apportioned on a first-come, first-served basis. Unconventional fuel developers who have not already secured water rights stand at the back of a long line and will need to obtain water from willing water purveyors. However, uncertainty regarding the nature and extent of some senior water claims combine with indeterminate interstate river management to cast a cloud over water resource allocation and management. Quantitative and qualitative water requirements associated with Endangered Species protection also stand as barriers to significant water development, and complex water quality regulations will apply to unconventional fuel development. Legal and political decisions can give shape to an indeterminate landscape. Settlement of Northern Ute reserved rights claims would help clarify the worth of existing water rights and viability of alternative sources of supply. Interstate apportionment of the White River would go a long way towards resolving water availability in downstream Utah. And energy policy clarification will help determine the role oil shale and oil sands will play in our nation’s future.

  1. Policy Analysis of Water Availability and Use Issues for Domestic Oil Shale and Oil Sands Development

    Energy Technology Data Exchange (ETDEWEB)

    Ruple, John [Univ. of Utah, Salt Lake City, UT (United States); Keiter, Robert [Univ. of Utah, Salt Lake City, UT (United States)

    2010-03-01

    Oil shale and oil sands resources located within the intermountain west represent a vast, and as of yet, commercially untapped source of energy. Development will require water, and demand for scarce water resources stands at the front of a long list of barriers to commercialization. Water requirements and the consequences of commercial development will depend on the number, size, and location of facilities, as well as the technologies employed to develop these unconventional fuels. While the details remain unclear, the implication is not – unconventional fuel development will increase demand for water in an arid region where demand for water often exceeds supply. Water demands in excess of supplies have long been the norm in the west, and for more than a century water has been apportioned on a first-come, first-served basis. Unconventional fuel developers who have not already secured water rights stand at the back of a long line and will need to obtain water from willing water purveyors. However, uncertainty regarding the nature and extent of some senior water claims combine with indeterminate interstate river management to cast a cloud over water resource allocation and management. Quantitative and qualitative water requirements associated with Endangered Species protection also stand as barriers to significant water development, and complex water quality regulations will apply to unconventional fuel development. Legal and political decisions can give shape to an indeterminate landscape. Settlement of Northern Ute reserved rights claims would help clarify the worth of existing water rights and viability of alternative sources of supply. Interstate apportionment of the White River would go a long way towards resolving water availability in downstream Utah. And energy policy clarification will help determine the role oil shale and oil sands will play in our nation’s future.

  2. Oil capture from a water surface by a falling sphere

    Science.gov (United States)

    Smolka, Linda; McLaughlin, Clare; Witelski, Thomas

    2015-11-01

    When a spherical particle is dropped from rest into an oil lens that floats on top of a water surface, a portion of the oil adheres to the sphere. Once the sphere comes to rest at the subsurface, the oil forms a pendant drop that remains attached in equilibrium to the sphere effectively removing oil from the water surface. Best fit solutions of the Laplace equation to experimental profiles are used to investigate the parameter dependence of the radius of curvature and the filling and contact angles at the three-phase contact line of the pendant drop for spheres with different wetting properties, densities and radii. The volume of oil captured by a sphere increases with a sphere's mass and diameter. However, lighter and smaller spheres capture more oil relative to their own volume than do heavier and larger spheres (scaling with the sphere mass ~M - 0 . 544) and are thus more efficient at removing oil from a water surface. The authors wish to acknowledge the support of the National Science Foundation Grant Nos. DMS-0707755 and DMS-0968252.

  3. Efficacy of experimental Newcastle disease water-in-oil oil-emulsion vaccines formulated from squalane and squalene.

    Science.gov (United States)

    Stone, H D; Xie, Z X

    1990-01-01

    Water-in-oil inactivated Newcastle disease oil-emulsion vaccines were formulated with the terpene oils squalane or squalene, or mixtures thereof, and injected into 4-week-old broilers. Vaccine efficacy based on hemagglutination-inhibition (HI) titers was comparable to that of control mineral oil vaccines. Tissue reaction to intramuscular injection of the terpene oil emulsion vaccines was greatly reduced 3 weeks post-vaccination compared with that of mineral oil-based vaccine. Viscosity of the terpene oil vaccines was satisfactory but increased three to four times that of mineral oil vaccine when the antigen phase volume increased from 5% to 20%.

  4. DEVELOPMENT OF POLYMER GEL SYSTEMS TO IMPROVE VOLUMETRIC SWEEP AND REDUCE PRODUCING WATER/OIL RATIOS

    Energy Technology Data Exchange (ETDEWEB)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Rajeev Jain; Tuan Nguyen

    2003-11-01

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of the first year of a three-year research program that is aimed at the understanding of the chemistry of gelation and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work has focused on a widely-applied system in field applications, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. The initial reaction between chromium acetate and one polymer is referred to as the uptake reaction. The uptake reaction was studied as functions of chromium and polymer concentrations and pH values. Experimental data were regressed to determine a rate equation that describes the uptake reaction of chromium by polyacrylamide. Pre-gel aggregates form and grow as the reactions between chromium acetate and polyacrylamide proceed. A statistical model that describes the growth of pre-gel aggregates was developed using the theory of branching processes. The model gives molecular weight averages that are expressed as functions of the conversion of the reactive sites on chromium acetate or on the polymer molecule. Results of the application of the model correlate well with experimental data of viscosity and weight-average molecular weight and gives insights into the gelation process. A third study addresses the flow of water and oil in rock material after a gel treatment. Previous works have shown that gel treatments usually reduce the permeability to water to a greater extent than the permeability to oil is reduced. This phenomenon is referred to as disproportionate permeability reduction (DPR). Flow experiments were conducted to determine the effect of polymer and chromium concentrations on

  5. The Use of Demulsifiers for Separating Water from Anthracene Oil

    Directory of Open Access Journals (Sweden)

    Zečević, N.

    2008-03-01

    increasing aromaticity. It is also used for determination of the Bureau of Mines Correlation Index (BMCI,2 which is obtained either from density and midboiling point, or from density andviscosity for those feedstocks which cannot be distilled completely. This index is used by the carbon black industry as an important criteria for feedstock evaluation.The sulphur fraction in feedstocks should not exceed w = 2.5 ·10–2, because a higher content greatly affects the quality of carbon black, pollutes the atmosphere, and accelerates corrosion of the facility. The maximum sulphur content in the typical hydrocarbon feedstock is w = 1.2 · 10–2.3. A very important factor of hydrocarbon feedstock is the fraction of alkaline earth metals, especially sodium and potassium. The maximum sodium fraction may be w = 20·10–6, while the maximum potassium fraction is w = 2·10 –6.The maximum fraction of asphalthenes is w = 15 ·10–2. Asphalthenes, determined as pentane-insoluble matter, provide indications concerning the possibility of grit formation. Another very important factor is the temperature range of distillation, which should be low enough, because the hydrocarbon feedstock must evaporize before entering the hot region of the reactor. The viscosity, the pour point, and for safety reasons, the flash point determines the handling properties and storage conditions of the feedstock.In addition, the water fraction in the hydrocarbon feedstock is one of the most important factors. The water fraction in hydrocarbon feedstock influences the handling properties of the same. The maximum water fraction in hydrocarbon feedstock may be w = 2.0·10–2, and desirably below w = 1.0·10–2. A higher water fraction represent a considerable impact on the financial construction. Also, it is very difficult to manipulate such feedstock, especially unloading, and in the production of oil-furnace carbon black. Namely, every water fraction higher than w = 2.0·10–2 in the hydrocarbon feedstock

  6. Selection of potential cold water marine species for testing of oil dispersants, and chemically dispersed oil

    Energy Technology Data Exchange (ETDEWEB)

    Perkins, R.A. [Alaska Univ., Fairbanks, AK (United States). Dept. of Civil and Environmental Engineering

    2000-07-01

    A study regarding marine species for toxicity testing for Alaska conditions was presented and the potential adverse impacts of a large marine oil spill in cold water were discussed with the objective to determine if the spill should be treated by the use of oil dispersants. Without dispersion, the oil can pollute marine epifauna and can deposit on beaches. The decision to apply dispersants to a marine oil spill requires knowledge of the toxicity of the undispersed oil to pelagic marine life occurring via natural dispersion as opposed to the toxicity of the oil-dispersant mixture. Most standard toxicity tests apply to warm water species. This paper discussed the need to have a standard test species relevant to Alaska waters for toxicity testing. In this study, toxicity testing was done according to the methods of the Chemical Response to Oil Spills : Ecological Effects Research Forum (CROSERF). The testing included capturing adult species in the winter and holding them until larval hatching. Toxicity testing was completed in a narrow time frame before hatching ceased. Many chemical samples were tested. Topsmelt, urchins, shellfish, mysids, copepods, pink salmon fry, and tidepool sculpin were considered by the author to be the most useful for certain types of toxicity testing. 29 refs.

  7. Oil palm plantation effects on water quality in Kalimantan, Indonesia

    Science.gov (United States)

    Carlson, K. M.; Curran, L. M.

    2011-12-01

    Global demand for palm oil has stimulated a 7-fold increase in oil palm (Elaeis guineensis) plantation area in Indonesia since 1990. Expansion will continue as Indonesia plans to double current production by 2020. Oil palm fertilizers, effluent from oil palm mills, and erosion from land clearing and roads threaten river water quality near plantations. These rivers provide essential ecosystem services including water for drinking, cooking, and washing. Robust empirical measurements of plantation expansion impacts on water resources are necessary to discern the effects of agribusiness on local livelihoods and ecosystems. In Ketapang District, West Kalimantan, Indonesian Borneo, we evaluated the effects of land cover change on water quality by assessing water chemistry in streams draining four end-member watersheds ( ~600-1900 ha watershed-1): Logged forest, mixed agro-forest dominated by rubber and upland rice fallows, young oil palm forest (0-5 years), and old oil palm forest (10-15 years). To assess land cover change, we used CLASLite software to derive fractional cover from a time series (1989-2008) of Landsat data. Nearest neighbor classification and post-classification change detection yielded classes including primary forest, logged forest, secondary forest regrowth, smallholder agriculture, and oil palm. Stream water quality (temperature, dissolved oxygen, turbidity, optical chlorphyll, and pH) and quantity (discharge) were quantified with the YSI 6600-V2 sonde. The sonde was deployed in each stream for month-long intervals 2-3 times from 2009-2010. Such extended deployment captures episodic events such as intense storms and allows examination of interdiel dynamics by sampling continuously and at high frequency, every 10 minutes. We find that across the Ketapang District study region (~12,000 km2), oil palm has cleared mostly forests (49%) and agroforests (39%). What are the impacts of such land cover changes on water quality? Compared to forests and

  8. Microbial enhanced heavy crude oil recovery through biodegradation using bacterial isolates from an Omani oil field.

    Science.gov (United States)

    Al-Sayegh, Abdullah; Al-Wahaibi, Yahya; Al-Bahry, Saif; Elshafie, Abdulkadir; Al-Bemani, Ali; Joshi, Sanket

    2015-09-16

    Biodegradation is a cheap and environmentally friendly process that could breakdown and utilizes heavy crude oil (HCO) resources. Numerous bacteria are able to grow using hydrocarbons as a carbon source; however, bacteria that are able to grow using HCO hydrocarbons are limited. In this study, HCO degrading bacteria were isolated from an Omani heavy crude oil field. They were then identified and assessed for their biodegradation and biotransformation abilities under aerobic and anaerobic conditions. Bacteria were grown in five different minimum salts media. The isolates were identified by MALDI biotyper and 16S rRNA sequencing. The nucleotide sequences were submitted to GenBank (NCBI) database. The bacteria were identified as Bacillus subtilis and B. licheniformis. To assess microbial growth and biodegradation of HCO by well-assay on agar plates, samples were collected at different intervals. The HCO biodegradation and biotransformation were determined using GC-FID, which showed direct correlation of microbial growth with an increased biotransformation of light hydrocarbons (C12 and C14). Among the isolates, B. licheniformis AS5 was the most efficient isolate in biodegradation and biotransformation of the HCO. Therefore, isolate AS5 was used for heavy crude oil recovery experiments, in core flooding experiments using Berea core plugs, where an additional 16 % of oil initially in place was recovered. This is the first report from Oman for bacteria isolated from an oil field that were able to degrade and transform HCO to lighter components, illustrating the potential use in HCO recovery. The data suggested that biodegradation and biotransformation processes may lead to additional oil recovery from heavy oil fields, if bacteria are grown in suitable medium under optimum growth conditions.

  9. Risk assessment and remediation suggestion of impacted soil by produced water associated with oil production.

    Science.gov (United States)

    Abdol Hamid, Hashim R; Kassim, Walid M S; El Hishir, Abdulah; El-Jawashi, Salem A S

    2008-10-01

    Produced water is water trapped in underground formations that is brought to the surface along with oil or gas production. Oilfield impacted soil is the most common environmental problem associated with oil production. The produced water associated with oil-production contaminates the soil and causes the outright death of plants, and the subsequent erosion of topsoil. Also, impacted soil serves to contaminate surface waters and shallow aquifers. This paper is intended to provide an approach for full characterization of contaminated soil by produced water, by means of analysis of both the produced water and the impacted soil using several recommended analytical techniques and then identify and assay the main constituents that cause contamination of the soil. Gialo-59 oilfield (29N, 21E), Libya, has been chosen as the case study of this work. The field has a long history of petroleum production since 1959, where about 300,000 bbl of produced water be discharged into open pit. Test samples of contaminated soil were collected from one of the disposal pits. Samples of produced water were collected from different points throughout the oil production process, and the analyses were carried out at the labs of Libyan Petroleum Institute, Tripoli, Libya. The results are compared with the local environmental limiting constituents in order to prepare for a plan of soil remediation. The results showed that the main constituents (pollutants) that impact the soil are salts and hydrocarbon compounds. Accordingly; an action of soil remediation has been proposed to remove the salts and degradation of hydrocarbons.

  10. [Near infrared spectroscopy study on water content in turbine oil].

    Science.gov (United States)

    Chen, Bin; Liu, Ge; Zhang, Xian-Ming

    2013-11-01

    Near infrared (NIR) spectroscopy combined with successive projections algorithm (SPA) was investigated for determination of water content in turbine oil. Through the 57 samples of different water content in turbine oil scanned applying near infrared (NIR) spectroscopy, with the water content in the turbine oil of 0-0.156%, different pretreatment methods such as the original spectra, first derivative spectra and differential polynomial least squares fitting algorithm Savitzky-Golay (SG), and successive projections algorithm (SPA) were applied for the extraction of effective wavelengths, the correlation coefficient (R) and root mean square error (RMSE) were used as the model evaluation indices, accordingly water content in turbine oil was investigated. The results indicated that the original spectra with different water content in turbine oil were pretreated by the performance of first derivative + SG pretreatments, then the selected effective wavelengths were used as the inputs of least square support vector machine (LS-SVM). A total of 16 variables selected by SPA were employed to construct the model of SPA and least square support vector machine (SPA-LS-SVM). There is 9 as The correlation coefficient was 0.975 9 and the root of mean square error of validation set was 2.655 8 x 10(-3) using the model, and it is feasible to determine the water content in oil using near infrared spectroscopy and SPA-LS-SVM, and an excellent prediction precision was obtained. This study supplied a new and alternative approach to the further application of near infrared spectroscopy in on-line monitoring of contamination such as water content in oil.

  11. Femtosecond laser ablated durable superhydrophobic PTFE films with micro-through-holes for oil/water separation: Separating oil from water and corrosive solutions

    Science.gov (United States)

    Yong, Jiale; Fang, Yao; Chen, Feng; Huo, Jinglan; Yang, Qing; Bian, Hao; Du, Guangqing; Hou, Xun

    2016-12-01

    Separating the mixture of water and oil by the superhydrophobic porous materials has attracted increasing research interests; however, the surface microstructures and chemical composition of those materials are easily destroyed in a harsh environment, resulting in materials losing the superhydrophobicity as well as the oil/water separation function. In this paper, a kind of rough microstructures was formed on polytetrafluoroethylene (PTFE) sheet by femtosecond laser treatment. The rough surfaces showed durable superhydrophobicity and ultralow water adhesion even after storing in various harsh environment for a long time, including strong acid, strong alkali, and high temperature. A micro-through-holes array was further generated on the rough superhydrophobic PTFE film by a subsequent mechanical drilling process. The resultant sample was successfully applied in the field of oil/water separation due to the inverse superhydrophobicity and superoleophilicity. The designed separation system is also very efficient to separate the mixtures of oil and corrosive acid/alkali solutions, exhibiting the strong potential for practical application.

  12. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a

  13. Partition and water/oil adsorption of some surfactants.

    Science.gov (United States)

    Tadmouri, Rawad; Zedde, Chantal; Routaboul, Corinne; Micheau, Jean-Claude; Pimienta, Véronique

    2008-10-02

    Adsorption isotherms have been determined at the water/oil interface for five biphasic systems involving surfactants (non-ionic and ionic) present in both phases at partition equilibrium. The systems studied were polyoxyethylene(23)lauryl ether (Brij35) in water/hexane and four ionic surfactants, hexadecyltrimethylammonium bromide (CTAB), and a series of three tetraalkylammonium dodecylsulfate (TEADS, TPADS, and TBADS) in water/CH 2Cl 2. Interfacial tension measurements performed at the water/air and water/oil interfaces provided all the necessary information for the determination of the adsorption parameters by taking partition into account. These measurements also allowed the comparison of the adsorption properties at both interfaces which showed an increase of the adsorption equilibrium constant and a decrease of the maximum surface concentration at the water/oil interface compared to water/air. The values of the critical aggregation concentration showed, in all cases, that only the surfactant dissolved in the aqueous phase contribute to the decrease of the water/oil interfacial tension. In the case of the four ionic surfactants, the critical aggregation concentration obtained in biphasic conditions were lowered because of the formation of mixed surfactant-CH 2Cl 2 aggregates.

  14. Protection of broiler breeders by an inactivated combined water-in-oil-in-water viral vaccine.

    Science.gov (United States)

    Bidin, Z; Cajavec, S; Sladić, D; Ergotić, N; Cizelj, A; Pokrić, B

    1998-01-01

    A four-component vaccine, prepared by combining the single vaccines, contains subunits of Newcastle disease and infectious bronchitis viruses, as well as whole inactivated infectious bursal disease and egg drop syndrome viruses. The vaccine is prepared in the form of a low-viscosity water-in-oil-in-water emulsion with low mineral oil content. Heavy breeders were vaccinated at the age of 20 weeks by intramuscular administration of 0.5 ml vaccine/bird in an experiment carried out under field conditions, involving 5000 female and 450 male parents. The birds had previously been vaccinated with live vaccines according to an obligatory field vaccination programme. Vaccination with the WOWE vaccine near the point of lay elicited serological responses protecting both the parents and their progeny. Each of the antigens administered in the four-component vaccine was as effective as the respective single component vaccine. The mortality, recorded during the 31-week experimental period, was 6.2%. Mortality and morbidity were not triggered by viruses against which vaccination was carried out. Egg production was not affected by the vaccination and was 170.2 eggs per hen during the 28-week production period.

  15. Experimental Investigation on Dilation Mechanisms of Land-Facies Karamay Oil Sand Reservoirs under Water Injection

    Science.gov (United States)

    Lin, Botao; Jin, Yan; Pang, Huiwen; Cerato, Amy B.

    2016-04-01

    The success of steam-assisted gravity drainage (SAGD) is strongly dependent on the formation of a homogeneous and highly permeable zone in the land-facies Karamay oil sand reservoirs. To accomplish this, hydraulic fracturing is applied through controlled water injection to a pair of horizontal wells to create a dilation zone between the dual wells. The mechanical response of the reservoirs during this injection process, however, has remained unclear for the land-facies oil sand that has a loosely packed structure. This research conducted triaxial, permeability and scanning electron microscopy (SEM) tests on the field-collected oil sand samples. The tests evaluated the influences of the field temperature, confining stress and injection pressure on the dilation mechanisms as shear dilation and tensile parting during injection. To account for petrophysical heterogeneity, five reservoir rocks including regular oil sand, mud-rich oil sand, bitumen-rich oil sand, mudstone and sandstone were investigated. It was found that the permeability evolution in the oil sand samples subjected to shear dilation closely followed the porosity and microcrack evolutions in the shear bands. In contrast, the mudstone and sandstone samples developed distinct shear planes, which formed preferred permeation paths. Tensile parting expanded the pore space and increased the permeability of all the samples in various degrees. Based on this analysis, it is concluded that the range of injection propagation in the pay zone determines the overall quality of hydraulic fracturing, while the injection pressure must be carefully controlled. A region in a reservoir has little dilation upon injection if it remains unsaturated. Moreover, a cooling of the injected water can strengthen the dilation potential of a reservoir. Finally, it is suggested that the numerical modeling of water injection in the Karamay oil sand reservoirs must take into account the volumetric plastic strain in hydrostatic loading.

  16. Observed oil and gas field size distributions: A consequence of the discovery process and prices of oil and gas

    Science.gov (United States)

    Drew, L.J.; Attanasi, E.D.; Schuenemeyer, J.H.

    1988-01-01

    If observed oil and gas field size distributions are obtained by random samplings, the fitted distributions should approximate that of the parent population of oil and gas fields. However, empirical evidence strongly suggests that larger fields tend to be discovered earlier in the discovery process than they would be by random sampling. Economic factors also can limit the number of small fields that are developed and reported. This paper examines observed size distributions in state and federal waters of offshore Texas. Results of the analysis demonstrate how the shape of the observable size distributions change with significant hydrocarbon price changes. Comparison of state and federal observed size distributions in the offshore area shows how production cost differences also affect the shape of the observed size distribution. Methods for modifying the discovery rate estimation procedures when economic factors significantly affect the discovery sequence are presented. A primary conclusion of the analysis is that, because hydrocarbon price changes can significantly affect the observed discovery size distribution, one should not be confident about inferring the form and specific parameters of the parent field size distribution from the observed distributions. ?? 1988 International Association for Mathematical Geology.

  17. Upgrading of crude algal bio-oil in supercritical water.

    Science.gov (United States)

    Duan, Peigao; Savage, Phillip E

    2011-01-01

    We determined the influence of a Pt/C catalyst, high-pressure H2, and pH on the upgrading of a crude algal bio-oil in supercritical water (SCW). The SCW treatment led to a product oil with a higher heating value (∼42 MJ/kg) and lower acid number than the crude bio-oil. The product oil was also lower in O and N and essentially free of sulfur. Including the Pt/C catalyst in the reactor led to a freely flowing liquid product oil with a high abundance of hydrocarbons. Overall, many of the properties of the upgraded oil obtained from catalytic treatment in SCW are similar to those of hydrocarbon fuels derived from fossil fuel resources. Thus, this work shows that the crude bio-oil from hydrothermal liquefaction of a microalga can be effectively upgraded in supercritical water in the presence of a Pt/C catalyst. Copyright © 2010 Elsevier Ltd. All rights reserved.

  18. Texture optimization of water-in-oil emulsions.

    Science.gov (United States)

    Lemaitre-Aghazarian, V; Piccerelle, P; Reynier, J P; Joachim, J; Phan-Tan-Luu, R; Sergent, M

    2004-01-01

    The aim of this research is to demonstrate the effect of variations in certain parameters of the oily phase (OP) in water-in-oil (W/O) emulsions on rheological and texture properties of finished products. The formulated emulsions were selected according to an optimal experimental procedure. The applied variations were nature of the OP, its volume fraction, the hydrophilic-lipophilic balance (HLB) value, and the surfactant proportion. Results are presented for the followed tests carried out on the emulsions: texture analysis, rheology, and particle size analysis. The oils used in the study were sweet almond oil, liquid paraffin, maize oil, cyclomethicone, dimethicone, and wheat germ oil. The resulting data demonstrate a notable influence of the volume fraction oil on hardness, viscosity, adhesiveness, and cohesiveness of W/O emulsions. Emulsion hardness and viscosity increased as the OP percentage increased; this effect being even more pronounced for the vegetable oils. In contrast, emulsion adhesiveness and cohesiveness decreased as the volume fraction oil increased. The HLB value of the surfactant mixture of the emulsion also influenced hardness, adhesiveness, and elasticity, increasing or decreasing as HLB value did.

  19. Agroecological practices in oil palm plantations: examples from the field

    Directory of Open Access Journals (Sweden)

    Bessou Cécile

    2017-05-01

    Full Text Available Palm oil is nowadays the first vegetable oil consumed worldwide. Given the world population growth and the increasing demand in fat for food and fuel, the increase in oil palm production is expected to continue. It is thus important to find ways of reducing the ecological impact of oil palm plantations at both the agroecosystem and the mill supply area levels, by improving agricultural practices and land uses. This is where agroecology can play a very critical role. The present article gathers short stories on agroecological practices currently taking place in oil palm plantations in South-East Asia. Such stories notably highlight the importance of the various palm co-products and how appropriate recycling strategies can allow for reducing external inputs to both the field and the mill. Besides limiting environmental impacts thanks to such savings, several co-products used as organic amendments can even help to maintain or enhance soil quality. Other stories explored agroecological practices developed for biological controls. Although integrated pest management has been applied in palm plantations for a long time, the underlying mechanisms are still not fully deciphered and practices still need to be improved. More knowledge is needed in order to better account for the holistic role of biodiversity and arbitrate trade-offs between practices and ecosystem services, at both plantation and landscape levels.

  20. Reservoir engineering optimized techniques and applications research in initial development stage of a super shallow sea marginal oil field : Development case of Chengdao Oil Field in Bohai Bay, China

    Energy Technology Data Exchange (ETDEWEB)

    Yu, D.; Ren, Y.; Zhou, Y.; Wang, D. [Shengli Oil field Inc. (China). SINOPEC Corp.

    2002-06-01

    One of the greatest Chinese neritic marginal oil fields is the Chengdao oil field, located north of Dongying City, Shandong Province, China in the southern part of Bohai Bay. The depth of the seawater is less than 15 metres, even though the field lies 5 kilometres from shore. It falls in the category of super shallow sea marginal oil field, due to a number of reasons: peculiar geographical location, abominable environment and climate, complex reservoir characteristics and high economic risk of exploration and development. The major oil-bearing series of the Chengdao oil field is upper Guantao sandstones. The establishment of a three-dimensional conceptual model and static model in initial development stage were completed using Log-Constrained Seismic Inversion technique combined with three-dimensional visual geological model establishment technique. The optimization and determination of reservoir engineering technical limits, namely development scheme, well pattern and spacing, timing of water injection, water injection scheme and injection-to-production ratio was accomplished with the application of geostatistics, numerical simulation and economic evaluation techniques. For the period 1996-2001, the cumulative oil productivity of upper Guantao reservoir in pure natural energy development increased substantially. The results were presented in this paper. 3 refs., 6 tabs., 13 figs.

  1. Rain Drops and Oil Slicks: Impact of Water Droplets on a Surface Oil Layer

    Science.gov (United States)

    Murphy, David; Morra, David; Katz, Joseph

    2013-11-01

    Petroleum spills in aquatic environments form oil slicks on the water surface. These slicks, the thickness of which ranges from microns to several millimeters, negatively impact the natural environment and economic resources. While dispersion of these slicks as small droplets by breaking waves has long been investigated, the dispersive power of another environmental flow, rainfall, has not been considered. The impact of a water drop on a floating layer of immiscible fluid introduces a challenging flow physics problem. Our experimental observations examine processes occurring when falling water droplets impact on floating layers of sweet petroleum crude oil of various thicknesses and dispersant concentrations. The latter alter the surface tension by orders of magnitude. Impact events recorded at high-speed, using UV light to cause oil fluorescence, show the expected formation of modified multiphase Worthington jets, air cavities, as well as breakup of the slicks into clouds of oil droplets and oil-coated bubbles. The latter rise back to the surface and pop. Results include droplet size and spatial distributions as a function of rainfall momentum, oil properties, and processes involved. Sponsored by Gulf of Mexico Research Initiative (GoMRI).

  2. Development and Prospects for Energy Saving Technology in Oil & Gas Fields, China

    Institute of Scientific and Technical Information of China (English)

    Chen Youwang; Yu Jiqing; Lin Ran; Zhu Yingru; Liu Feijun

    2010-01-01

    @@ Current state of energy saving technology in China's oil and gas fields System optimization To optimize the oil-gas field surface engineering system is critical to improve the efficiency of oil and gas field system.To adapt to the changes in development of old oil and gas fields, all oilfields are adjusted and reconstructed;a set of optimized and simplified modes and technical measures are developed.

  3. Clay-oil droplet suspensions in electric fields

    Science.gov (United States)

    Rozynek, Zbigniew; Fossum, Jon Otto; Kjerstad, Knut; Mikkelsen, Alexander; Castberg, Rene

    2012-02-01

    Silicone oil droplets containing synthetic smectite clay submerged in immiscible organic oil have been studied by observing clay particle movement and oil circulation when an electric field is applied. Results show how electric field strength, dielectric and electrorheological properties as well as electrohydrodynamics determine the fluid flow and clay particle formation. In a presence of the DC electric fields the clay particles formed a ribbon-like structure onto the inner surface of the droplet. The structure consists of short chain-like clay elements orienting parallel to the electric field direction. It is suggested that a combination of two phenomena, namely the induced viscous flow (electrohydrodynamic effect) and the polarization of the clay particles (dielectric effect), contribute to the ribbon-like structure formation. -/abstract- References [1] G. Taylor, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 291 (1966) 159--166. [2] J. R. Melcher and G. I. Taylor, Annual Review of Fluid Mechanics 1 (1969) 111--146. [3] H. Sato, N. Kaji, T. Mochizuki, and Y. H. Mori, Physics of Fluids 18 (2006) 127101. [4] D. A. Saville, Annual Review of Fluid Mechanics 29 (1997) 27--64. [5] J. O. Fossum, Y. M'eheust, K. P. S. Parmar, K. D. Knudsen, K. J. Måløy, and D. M. Fonseca Europhysics Letters 74

  4. Oil Recovery Enhancement from Fractured, Low Permeability Reservoirs. [Carbonated Water

    Science.gov (United States)

    Poston, S. W.

    1991-01-01

    The results of the investigative efforts for this jointly funded DOE-State of Texas research project achieved during the 1990-1991 year may be summarized as follows: Geological Characterization - Detailed maps of the development and hierarchical nature the fracture system exhibited by Austin Chalk outcrops were prepared. The results of these efforts were directly applied to the development of production decline type curves applicable to a dual-fracture-matrix flow system. Analysis of production records obtained from Austin Chalk operators illustrated the utility of these type curves to determine relative fracture/matrix contributions and extent. Well-log response in Austin Chalk wells has been shown to be a reliable indicator of organic maturity. Shear-wave splitting concepts were used to estimate fracture orientations from Vertical Seismic Profile, VSP data. Several programs were written to facilitate analysis of the data. The results of these efforts indicated fractures could be detected with VSP seismic methods. Development of the EOR Imbibition Process - Laboratory displacement as well as Magnetic Resonance Imaging, MRI and Computed Tomography, CT imaging studies have shown the carbonated water-imbibition displacement process significantly accelerates and increases recovery from oil saturated, low permeability rocks. Field Tests - Two operators amenable to conducting a carbonated water flood test on an Austin Chalk well have been identified. Feasibility studies are presently underway.

  5. Olive oil waste waters: Controlled fermentation and materials recovery

    Energy Technology Data Exchange (ETDEWEB)

    Federici, F.; Montedoro, G.F.; Pozzi, V. (Tuscia Univ., Viterbo (Italy). Detp. di Agrobiologia e Agrochimica Perugia Univ. (Italy). Ist. di Industrie Agrarie UNIECO s.c.r.l., Reggio Emilia (Italy))

    Land and water pollution due to waste water and oils deriving from the processing of olives to produce oil represents a serious environmental problem for Spain, Italy and Greece. This paper reports and discusses the results (time dependent enzyme activity) of performance tests on an innovative fermentation process to be used in olive oil waste water anaerobic digestion. An outline is then given of a demonstration depolymerization/materials recovery (including polyphenols, enzymes, etc.) process scheme based on the the tested fermentation method. The fermentation process tests involved the use of an albidus yeast in an Applikon bench scale experimental device. Process parameters were varied to determine optimum fermentation conditions. The European Communities sponsored one cubic meter/day demonstration plant utilizes a preliminary treatment process based on the use of gelatin, bentonite and polyclar.

  6. Real-time oil-saturation monitoring in rock cores with low-field NMR.

    Science.gov (United States)

    Mitchell, J; Howe, A M; Clarke, A

    2015-07-01

    Nuclear magnetic resonance (NMR) provides a powerful suite of tools for studying oil in reservoir core plugs at the laboratory scale. Low-field magnets are preferred for well-log calibration and to minimize magnetic-susceptibility-induced internal gradients in the porous medium. We demonstrate that careful data processing, combined with prior knowledge of the sample properties, enables real-time acquisition and interpretation of saturation state (relative amount of oil and water in the pores of a rock). Robust discrimination of oil and brine is achieved with diffusion weighting. We use this real-time analysis to monitor the forced displacement of oil from porous materials (sintered glass beads and sandstones) and to generate capillary desaturation curves. The real-time output enables in situ modification of the flood protocol and accurate control of the saturation state prior to the acquisition of standard NMR core analysis data, such as diffusion-relaxation correlations. Although applications to oil recovery and core analysis are demonstrated, the implementation highlights the general practicality of low-field NMR as an inline sensor for real-time industrial process control.

  7. [Mineral oil drinking water pollution accident in Slavonski Brod, Croatia].

    Science.gov (United States)

    Medverec Knežević, Zvonimira; Nadih, Martina; Josipović, Renata; Grgić, Ivanka; Cvitković, Ante

    2011-12-01

    On 21 September 2008, heavy oil penetrated the drinking water supply in Slavonski Brod, Croatia. The accident was caused by the damage of heat exchange units in hot water supply. The system was polluted until the beginning of November, when the pipeline was treated with BIS O 2700 detergent and rinsed with water. Meanwhile, water samples were taken for chemical analysis using spectrometric and titrimetric methods and for microbiological analysis using membrane filtration and total plate count. Mineral oils were determined with infrared spectroscopy. Of the 192 samples taken for mineral oil analysis, 55 were above the maximally allowed concentration (MAC). Five samples were taken for polycyclic aromatic hydrocarbon (PAH), benzene, toluene, ethylbenzene, and xylene analysis (BTEX), but none was above MAC. Epidemiologists conducted a survey about health symptoms among the residents affected by the accident. Thirty-six complained of symptoms such as diarrhoea, stomach cramps, vomiting, rash, eye burning, chills, and gastric disorders.This is the first reported case of drinking water pollution with mineral oil in Slavonski Brod and the accident has raised a number of issues, starting from poor water supply maintenance to glitches in the management of emergencies such as this.

  8. Third One-million-ton Oil Field in Junggar Basin Will Come into Being

    Institute of Scientific and Technical Information of China (English)

    Tian Jun; Li Songguo

    2002-01-01

    @@ PetroChina Xinjiang Oil FieldCompany is accelerating its efforts for construction of the third 1-million-ton oil field in Junggar basin - Luliang oil field located in the hinterland of the basin, which was found in 2000.

  9. Detection of olive oil adulteration by low-field NMR relaxometry and UV-Vis spectroscopy upon mixing olive oil with various edible oils

    Directory of Open Access Journals (Sweden)

    S. Ok

    2017-03-01

    Full Text Available Adulteration of olive oil using unhealthy substitutes is considered a threat for public health. Low-field (LF proton (1H nuclear magnetic resonance (NMR relaxometry and ultra-violet (UV visible spectroscopy are used to detect adulteration of olive oil. Three different olive oil with different oleoyl acyl contents were mixed with almond, castor, corn, and sesame oils with three volumetric ratios, respectively. In addition, Arbequina olive oil was mixed with canola, flax, grape seed, peanut, soybean, and sunflower seed oils with three volumetric ratios. Transverse magnetization relaxation time (T2 curves were fitted with bi-exponential decaying functions. T2 times of each mixture of olive oils and castor oils, and olive oils and corn oils changed systematically as a function of volumetric ratio. To detect the adulteration in the mixtures with almond and sesame oils, both LF 1H NMR relaxometry and UV-Vis spectroscopy were needed, where UV-Vis-spectroscopy detected the adulteration qualitatively. In the mixtures of Arbequina olive oil and flax, peanut, soybean, and sunflower seed oils, both T21 and T22 values became longer systematically as the content of the olive oil was decreased. The unique UV-Vis maximum absorbance of flax oil at 320.0 nm shows the adulteration of olive oil qualitatively.

  10. Closed Process of Shale Oil Recovery from Circulating Washing Water by Hydrocyclones

    Directory of Open Access Journals (Sweden)

    Yuan Huang

    2016-12-01

    Full Text Available The conventional oil recovery system in the Fushun oil shale retorting plant has a low oil recovery rate. A large quantity of fresh water is used in the system, thereby consuming a considerable amount of water and energy, as well as polluting the environment. This study aims to develop a closed process of shale oil recovery from the circulating washing water for the Fushun oil shale retorting plant. The process would increase oil yield and result in clean production. In this process, oil/water hydrocyclone groups were applied to decrease the oil content in circulating water and to simultaneously increase oil yield. The oil sludge was removed by the solid/liquid hydrocyclone groups effectively, thereby proving the smooth operation of the devices and pipes. As a result, the oil recovery rate has increased by 5.3 %, which corresponds to 230 tonnes a month.

  11. Novel Downhole Electromagnetic Flowmeter for Oil-Water Two-Phase Flow in High-Water-Cut Oil-Producing Wells

    Directory of Open Access Journals (Sweden)

    Yanjun Wang

    2016-10-01

    Full Text Available First, the measuring principle, the weight function, and the magnetic field of the novel downhole inserted electromagnetic flowmeter (EMF are described. Second, the basic design of the EMF is described. Third, the dynamic experiments of two EMFs in oil-water two-phase flow are carried out. The experimental errors are analyzed in detail. The experimental results show that the maximum absolute value of the full-scale errors is better than 5%, the total flowrate is 5–60 m3/d, and the water-cut is higher than 60%. The maximum absolute value of the full-scale errors is better than 7%, the total flowrate is 2–60 m3/d, and the water-cut is higher than 70%. Finally, onsite experiments in high-water-cut oil-producing wells are conducted, and the possible reasons for the errors in the onsite experiments are analyzed. It is found that the EMF can provide an effective technology for measuring downhole oil-water two-phase flow.

  12. Study on the New Grinding Fluids of Oils on Water

    Institute of Scientific and Technical Information of China (English)

    魏源迁; 钱怡; 中村隆; 松原十三生

    2003-01-01

    To fulfill a zero-emission in the process of grinding and thoroughly eliminate the influences of the conventional grinding fluids on the eco-environment as well as save up electric energy and reduce in production costs, the new grinding fluids of botanic oils on water were developed, in which a lot of tiny water droplets attached with micro oil films were blown to the machining area by a compressing air-jet so good as to produce lubricating and cooling roles.In this study, grinding performances of the new fluids were investigated by comparison to the conventional ones such as emulsion on the plane NC grinder.

  13. Preliminary Prioritization of California Oil and Gas Fields for Regional Groundwater Monitoring Based on Intensity of Petroleum Resource Development and Proximity to Groundwater Resources

    Science.gov (United States)

    Davis, T. A.; Landon, M. K.; Bennett, G.

    2016-12-01

    The California State Water Resources Control Board is collaborating with the U.S. Geological Survey to implement a Regional Monitoring Program (RMP) to assess where and to what degree groundwater resources may be at risk of contamination from oil and gas development activities including stimulation, well integrity issues, produced water ponds, and underground injection. A key issue in the implementation of the RMP is that the state has 487 onshore oil fields covering 8,785 square kilometers but detailed characterization work can only be done in a few oil fields annually. The first step in the RMP is to prioritize fields using available data that indicate potential risk to groundwater from oil and gas development, including vertical proximity of groundwater and oil/gas resources, density of petroleum and water wells, and volume of water injected in oil fields. This study compiled data for these factors, computed summary metrics for each oil field, analyzed statewide distributions of summary metrics, used those distributions to define relative categories of potential risk for each factor, and combined these into an overall priority ranking. Aggregated results categorized 22% (107 fields) of the total number of onshore oil and gas fields in California as high priority, 23% as moderate priority, and 55% as low priority. On an area-weighted basis, 41% of the fields ranked high, 30% moderate, and 29% low, highlighting that larger fields tend to have higher potential risk because of greater intensity of development, sometimes coupled with closer proximity to groundwater. More than half of the fields ranked as high priority were located in the southern Central Valley or the Los Angeles Basin. The prioritization does not represent an assessment of groundwater risk from oil and gas development; rather, such assessments are planned to follow based on detailed analysis of data from the RMP near the oil fields selected for study in the future.

  14. Effects of Interactions Among Surfactants,Water and Oil on Equilibrium Configuration of Surfactant-Water-Oil Systems

    Institute of Scientific and Technical Information of China (English)

    YUAN Yin-quan; SUN Zhi-bo; XIE Yun; ZOU Xian-wu

    2004-01-01

    The distribution and configuration of surfactants at interface in surfactant-water-oil systems have been investigated using discontinuous molecular dynamic simulations. There exists a certain equilibrium concentration of surfactants at interface for the systems with certain interactions among surfactant, water and oil. The interface length and equilibrium morphology of the systems are dependent on the equilibrium concentration of surfactants at interface and the total amount of surfactants. The interaction strengths among surfactant, water and oil determine the equilibrium concentration of surfactants at interface. Three typical configurations of surfactants at interface have been observed: ① surfactant molecules are perpendicular to the interface and arranged closely; ② perpendicular to the interface and arranged at interval of two particles; ③ lie down in the interface partly.

  15. Active oil-water interfaces: buckling and deformation of oil drops by bacteria

    Science.gov (United States)

    Juarez, Gabriel; Stocker, Roman

    2014-11-01

    Bacteria are unicellular organisms that seek nutrients and energy for growth, division, and self-propulsion. Bacteria are also natural colloidal particles that attach and self-assemble at liquid-liquid interfaces. Here, we present experimental results on active oil-water interfaces that spontaneously form when bacteria accumulate or grow on the interface. Using phase-contrast and fluorescence microscopy, we simultaneously observed the dynamics of adsorbed Alcanivorax bacteria and the oil-water interface within microfluidic devices. We find that, by growing and dividing, adsorbed bacteria form a jammed monolayer of cells that encapsulates the entire oil drop. As bacteria continue to grow at the interface, the drop buckles and the interface undergoes strong deformations. The bacteria act to stabilize non-equilibrium shapes of the oil-phase such wrinkling and tubulation. In addition to presenting a natural example of a living interface, these findings shape our understanding of microbial degradation of oil and may have important repercussions on engineering interventions for oil bioremediation.

  16. Eco-Friendly Superwetting Material for Highly Effective Separations of Oil/Water Mixtures and Oil-in-Water Emulsions

    Science.gov (United States)

    Wang, Chih-Feng; Yang, Sheng-Yi; Kuo, Shiao-Wei

    2017-01-01

    Because the treatment of oily wastewater, generated from many industrial processes, has become an increasing environmental concern, the search continues for simple, inexpensive, eco-friendly, and readily scalable processes for fabricating novel materials capable of effective oil/water separation. In this study we prepared an eco-friendly superhydrophilic and underwater superoleophobic polyvinylpyrrolidone (PVP)-modified cotton that mediated extremely efficient separations of mixtures of oil/water and oil/corrosive solutions. This PVP-modified cotton exhibited excellent antifouling properties and could be used to separate oil/water mixtures continuously for up to 20 h. Moreover, the compressed PVP-modified cotton could separate both surfactant-free and -stabilized oil-in-water emulsions with fluxes of up to 23,500 L m−2 h−1 bar−1—a level one to two orders of magnitude higher than that possible when using traditional ultrafiltration membranes having similar rejection properties. The high performance of our PVP-modified cotton and its green, low-energy, cost-effective preparation suggest its great potential for practical applications. PMID:28216617

  17. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  18. Oil sand process-affected water treatment using coke adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Gamal El-Din, M.; Pourrezaei, P.; Chelme-Ayala, P.; Zubot, W. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering

    2010-07-01

    Oil sands operations generate an array of oil sands process-affected water (OSPW) that will eventually be released to the environment. This water must be evaluated within conventional and advanced water treatment technologies. Water management strategies propose options for increased reuse and recycling of water from settling ponds, as well as safe discharge. This presentation outlined the typical composition of OSPW. Constituents of concern in OSPW include suspended solids, hydrocarbons, salts, ammonia, trace metals, and dissolved organics such as naphthenic acids (NAs). Petroleum coke is one of the by-products generated from bitumen extraction in the oil sands industry and can be used as one of the possible treatment processes for the removal of organic compounds found in OSPW. Activated carbon adsorption is an effective process, able to adsorb organic substances such as oils, radioactive compounds, petroleum hydrocarbons, poly aromatic hydrocarbons and various halogenated compounds. The objectives of this study were to evaluate the production of activated carbon from petroleum coke using steam as the activation media; to determine the factors affecting the absorption of NAs; and to evaluate the activated coke adsorption capacity for the reduction of NAs and dissolved organic carbons present in OSPW. It was concluded that petroleum non-activated coke has the ability to decrease COD, alkalinity, and NA concentration. tabs., figs.

  19. Bioinspired materials for water supply and management: water collection, water purification and separation of water from oil.

    Science.gov (United States)

    Brown, Philip S; Bhushan, Bharat

    2016-08-06

    Access to a safe supply of water is a human right. However, with growing populations, global warming and contamination due to human activity, it is one that is increasingly under threat. It is hoped that nature can inspire the creation of materials to aid in the supply and management of water, from water collection and purification to water source clean-up and rehabilitation from oil contamination. Many species thrive in even the driest places, with some surviving on water harvested from fog. By studying these species, new materials can be developed to provide a source of fresh water from fog for communities across the globe. The vast majority of water on the Earth is in the oceans. However, current desalination processes are energy-intensive. Systems in our own bodies have evolved to transport water efficiently while blocking other molecules and ions. Inspiration can be taken from such to improve the efficiency of desalination and help purify water containing other contaminants. Finally, oil contamination of water from spills or the fracking technique can be a devastating environmental disaster. By studying how natural surfaces interact with liquids, new techniques can be developed to clean up oil spills and further protect our most precious resource.This article is part of the themed issue 'Bioinspired hierarchically structured surfaces for green science'. © 2016 The Author(s).

  20. Development and Field Test of New Oil-in-Water Wax Remover%新型水包油清蜡剂的研制及现场试验

    Institute of Scientific and Technical Information of China (English)

    展转盈; 倪军

    2015-01-01

    The effect of wax remover is critical for wax removing of oil wells. For the high toxicity, flammability, low wax dissolution rate and other shortcomings of commonly used wax removers, we developed a new type of oil-in-water wax re-mover in lab and tested in oilfields. We made experiment plans about the influence of different additives and their content on wax removing efficiency in oil-in-water wax removers, and determined the best formula consisting of 55% mixed organic solvent, 17% compound surfactant, 10% hexanol, 2% sodium chloride, 3. 5% sodium formate and water. Performance pa-rameters showed that the new wax remover was superior to conventional oil-based one. Test results of two groups of wells in-dicated that the load of a single well pumping unit could be reduced by 25. 07% and 48. 01% respectively after being added into oil-in-water wax remover, 20% and 33% higher than that of adjacent wells with conventional wax remover. The load was reduced remarkably and the application results were good. The new wax remover featured in high wax dissolution effi-ciency, low cost, good environmental protection, and broad prospect for application.%清蜡剂的效果对油井清蜡作业至关重要, 针对现阶段常用清蜡剂毒性大、 易燃、 溶蜡效率低等缺点, 通过室内实验研制了一种新型水包油型清蜡剂, 并在油田进行了试验. 制订了水包油型清蜡剂中不同添加剂及其含量对清蜡效率影响的实验方案, 分析确定最佳配方为55%混合有机溶剂、 17%混合型表面活性剂、 10%正己醇、 2%氯化钠、 3. 5%甲酸盐加重剂及水. 多项性能参数表明, 该清蜡剂性能明显优于常规油基清蜡剂. 两组矿场对比试验井的试验结果表明, 加入水包油型清蜡剂的单井抽油机载荷量分别降低25. 07%和48. 01%, 较加入常规清蜡剂的邻井分别高出20个百分点和33个百分点, 载荷量降低明显,应用效果良好. 该新型清蜡剂溶蜡效率高、

  1. Chitosan microspheres applied for removal of oil from produced water in the oil industry

    Directory of Open Access Journals (Sweden)

    Izabel Cristina da Silva Grem

    2013-01-01

    Full Text Available The discharge of oily wastewaters in the environment is steadily increasing, causing serious damages. Among various treatment methods, adsorption is generally considered the most appropriate, since it can remove both organic and inorganic pollutants. Adsorption using low-cost alternative biopolymers for removal of contaminants from wastewater has been widely investigated. In this context, chitosan has been drawing particular attention because, among its many applications, it can be used in the treatment of aqueous effluents. In this study, microspheres were prepared by reticulation of chitosan with sodium triphosphate (STP and studied for the treatment of water containing crude oil. The microspheres were regular and had surface pores. These microspheres were packed in treatment columns and their ability to remove oil was measured with a fluorometer, by the difference in the oil concentration before and after passing through the column. The microspheres that presented porosity about 80 % were highly efficient in oil removal, with rates above 90%.

  2. Continental Shelf Freshwater Water Resources and Enhanced Oil Recovery By Low Salinity Water Flooding

    Science.gov (United States)

    Person, M. A.; Morrow, N.; Wilson, J. L.

    2014-12-01

    This study investigates the prospects of utilizing offshore freshwater in continental shelf oil production. Petroleum engineers have recently shown that tertiary water floods using freshwater can enhance oil recovery by as much as 18% (Morrow and Buckley, 2011). Hydrogeologists recently estimated that up to 5x105 km3of fresh to brackish water are sequestered in shallow ( world (Post et al., 2013). Most of the offshore freshwater was emplaced during the Pleistocene during periods of sea level low stands and when ice sheets over ran passive margins at high latitudes. We have analyzed a series of continental shelf cross sections from around the world estimating the average freshwater volume emplaced with distance offshore. We compare the distribution of fresh-brackish water with distance from the coastline to oil platform locations in order to assess the economic viability of this energy-water nexus. We also discuss a project that is currently underway within the North Sea (Clair Ridge) to field validate this concept. We present a series of variable-density groundwater flow and solute transport simulations that are intended to assess how long freshwater resources could be produced in an offshore environment using horizontal drilling technologies before seawater invades the well. We considered a 100m thick freshwater reservoir sandwiched between two 200-300m thick confining units. We pumped the horizontal well at a rate of 5.4 m3/day (1 gpm per meter of well). The resulting drawdown was less than 5 m at the well head (r=0.15 m). For a 1000 m long horizontal well, this resulted in the production of 5455 m3/day of fresh water (over 34,000 barrels per day). Concentrations increased at the wellhead by about 5000 mg/l after 20 years of continuous pumping using a reservoir permeability of 10-13 m2. This simulation demonstrates that where freshwater is available it is likely that it can be produced in commercially viable quantities to support tertiary water floods.

  3. Assessment of Alaska's North Slope Oil Field Capacity to Sequester CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Umekwe, Pascal, E-mail: wpascals@gmail.com [Baker Hughes (United States); Mongrain, Joanna, E-mail: Joanna.Mongrain@shell.com [Shell International Exploration and Production Co (United States); Ahmadi, Mohabbat, E-mail: mahmadi@alaska.edu [University of Alaska Fairbanks, Petroleum Engineering Department (United States); Hanks, Catherine, E-mail: chanks@gi.alaska.edu [University of Alaska Fairbanks, Geophysical Institute (United States)

    2013-03-15

    The capacity of 21 major fields containing more than 95% of the North Slope of Alaska's oil were investigated for CO{sub 2} storage by injecting CO{sub 2} as an enhanced oil recovery (EOR) agent. These fields meet the criteria for the application of miscible and immiscible CO{sub 2}-EOR methods and contain about 40 billion barrels of oil after primary and secondary recovery. Volumetric calculations from this study indicate that these fields have a static storage capacity of 3 billion metric tons of CO{sub 2}, assuming 100% oil recovery, re-pressurizing the fields to pre-fracturing pressure and applying a 50% capacity reduction to compensate for heterogeneity and for water invasion from the underlying aquifer. A ranking produced from this study, mainly controlled by field size and fracture gradient, identifies Prudhoe, Kuparuk, and West Sak as possessing the largest storage capacities under a 20% safety factor on pressures applied during storage to avoid over-pressurization, fracturing, and gas leakage. Simulation studies were conducted using CO{sub 2} Prophet to determine the amount of oil technically recoverable and CO{sub 2} gas storage possible during this process. Fields were categorized as miscible, partially miscible, and immiscible based on the miscibility of CO{sub 2} with their oil. Seven sample fields were selected across these categories for simulation studies comparing pure CO{sub 2} and water-alternating-gas injection. Results showed that the top two fields in each category for recovery and CO{sub 2} storage were Alpine and Point McIntyre (miscible), Prudhoe and Kuparuk (partially miscible), and West Sak and Lisburne (immiscible). The study concludes that 5 billion metric tons of CO{sub 2} can be stored while recovering 14.2 billion barrels of the remaining oil.

  4. Exposures and cancer incidence near oil fields in the Amazon basin of Ecuador

    OpenAIRE

    San, S.; Armstrong, B; Cordoba, J.; Stephens, C.

    2001-01-01

    OBJECTIVES—To examine environmental exposure and incidence and mortality of cancer in the village of San Carlos surrounded by oil fields in the Amazon basin of Ecuador.
METHODS—Water samples of the local streams were analyzed for total petroleum hydrocarbons (TPHs). A preliminary list of potential cancer cases from 1989 to 1998 was prepared. Cases were compared with expected numbers of cancer morbidity and mortality registrations from a Quito reference population.
RESULTS—Water analysis showe...

  5. Rock mechanics related to Jurassic underburden at Valdemar oil field

    DEFF Research Database (Denmark)

    Foged, Niels

    1999-01-01

    The presented study is a part of the Danish Energy Research project PRIORITY - Imroved Oil Recovery and Productivity from Lower Cretaceous Carbonates.It considers a multi-disciplinary study of the Jurassic shale underlying the Valdemar structure and gives a status of the on-going research work.......It has been initiated as a feasibility study of the North Jens-1 core 12 taken in the top Jurassic clay shale as a test specimens for integrated petrological, mineralogical and rock mechanical studies. Following topics are studied:(1) Pore pressure generation due to conversion of organic matter...... and deformation properties of the clay shale using the actual core material or outcrop equivalents.(3) Flushing mechanisms for oil and gas from source rocks due to possibly very high pore water pressure creating unstable conditions in deeply burried sedimentsThere seems to be a need for integrating the knowledge...

  6. Viscosity of water-in-oil emulsions. Variation with temperature and water volume fraction

    Energy Technology Data Exchange (ETDEWEB)

    Farah, Marco A.; Caldas, Jorge Navaes [Petroleo Brasileiro S.A., Rua General Canabarro, 500, Maracana, Rio, CEP 2057-900 (Brazil); Oliveira, Roberto C. [Petroleo Brasileiro S.A., Cenpes, Cidade Universitaria (Brazil); Rajagopal, Krishnaswamy [LATCA-Laboratorio de Termodinamica e Cinetica Aplicada-Escola de Quimica, Departamento de Engenharia Quimica, Universidade Federal do Rio de Janeiro, UFRJ, Cidade Universitaria, C.P. 68452, CEP 21949-900, Rio de Janeiro (Brazil)

    2005-09-15

    Water-in-oil emulsions are important in the petroleum industry in production operations, where the water content of the emulsion can be as high as 60% in volume, also in petroleum refining operations where generally the water content is low. The effective viscosity of water-in-oil emulsions depends mainly on the volume fraction of dispersed phase and temperature, along with several minor effects, such as shear rate, average droplet size, droplet size distribution, viscosity and density of oil. Using six different crude oils, the effective viscosities of several synthetic water-in-oil emulsions are measured at atmospheric pressure using a dynamic viscosimeter for different shear rates, temperatures and volume fractions of the dispersed phase. The ASTM equation, method D-341, for describing viscosity as a function of temperature is extended to include the variation of dispersed phase volume fraction. The proposed equation gives good correlation between the measured viscosities of water-in-oil emulsions as a function of temperature and the volume fraction of water.

  7. Spontaneous charging and crystallization of water droplets in oil

    NARCIS (Netherlands)

    de Graaf, J.; Zwanikken, J.W.; Bier, Markus; Baarsma, Arjen; Oloumi, Yasha; Spelt, Mischa; van Roij, R.H.H.G.

    2008-01-01

    We study the spontaneous charging and the crystallization of spherical micron-sized water-droplets dispersed in oil by numerically solving, within a Poisson-Boltzmann theory in the geometry of a spherical cell, for the density profiles of the cations and anions in the system. We take into account

  8. Synthesis of hydroxytyrosyl alkyl ethers from olive oil waste waters

    OpenAIRE

    Juan Fernández-Bolaños; Mariana Trujillo; Guillermo Rodríguez; Raquel Mateos; Gema Pereira-Caro; Andrés Madrona; Espartero, José L.

    2009-01-01

    The preparation of a new type of derivatives of the naturally occurring antioxidant hydroxytyrosol is reported. Hydroxytyrosyl alkyl ethers were obtained in high yield by a three-step procedure starting from hydroxytyrosol isolated from olive oil waste waters. Preliminary results obtained by the Rancimat method have shown that these derivatives retain the high protective capacity of free hydroxytyrosol.

  9. Synthesis of Hydroxytyrosyl Alkyl Ethers from Olive Oil Waste Waters

    Directory of Open Access Journals (Sweden)

    Juan Fernández-Bolaños

    2009-05-01

    Full Text Available The preparation of a new type of derivatives of the naturally occurring antioxidant hydroxytyrosol is reported. Hydroxytyrosyl alkyl ethers were obtained in high yield by a three-step procedure starting from hydroxytyrosol isolated from olive oil waste waters. Preliminary results obtained by the Rancimat method have shown that these derivatives retain the high protective capacity of free hydroxytyrosol.

  10. Formulation and stability of topical water in oil emulsion containing ...

    African Journals Online (AJOL)

    Purpose: To formulate the water in oil (W/O) emulsion of corn silk (CS) extract and to evaluate its ... physical stability of the formulation was evaluated by monitoring these parameters over a period .... level of significance adopted was p < 0.05.

  11. Produced water treatment for beneficial use: emulsified oil removal

    NARCIS (Netherlands)

    Waisi, Basma

    2016-01-01

    The development of novel carbon material, high accessible surface area, interconnected porosity, and stable nanofiber nonwoven media for emulsified oil droplets separation from oily wastewater, in particular for oilfields produced water treatment, is discussed in this thesis. Firstly, the quantity a

  12. Produced water treatment for beneficial use: emulsified oil removal

    NARCIS (Netherlands)

    Waisi, B.I.H.

    2016-01-01

    The development of novel carbon material, high accessible surface area, interconnected porosity, and stable nanofiber nonwoven media for emulsified oil droplets separation from oily wastewater, in particular for oilfields produced water treatment, is discussed in this thesis. Firstly, the quantity a

  13. Electrospraying of water in oil emulsions for thin film coating

    NARCIS (Netherlands)

    Khan, M.K.I.; Maan, A.A.; Schutyser, M.A.I.; Schroën, C.G.P.H.; Boom, R.M.

    2013-01-01

    Electrospraying of water-in-oil emulsions was investigated to produce thin edible barriers. A reproducible model surface was used, namely cellulose membranes of which permeability is well-established. PGPR-based emulsions were stable during electrospraying and produced a fine stable jet spray; emuls

  14. Factors governing partial coalescence in oil-in-water emulsions

    NARCIS (Netherlands)

    Fredrick, E.; Walstra, P.; Dewettinck, K.

    2010-01-01

    The consequences of the instability mechanism partial coalescence in oil-in-water food emulsions show a discrepancy. On the one hand, it needs to be avoided in order to achieve an extended shelf life in food products like sauces, creams and several milk products. On the other hand, during the manufa

  15. Factors governing partial coalescence in oil-in-water emulsions

    NARCIS (Netherlands)

    Fredrick, E.; Walstra, P.; Dewettinck, K.

    2010-01-01

    The consequences of the instability mechanism partial coalescence in oil-in-water food emulsions show a discrepancy. On the one hand, it needs to be avoided in order to achieve an extended shelf life in food products like sauces, creams and several milk products. On the other hand, during the

  16. Structure and dynamics of water molecules confined in triglyceride oils.

    Science.gov (United States)

    Groot, Carien C M; Velikov, Krassimir P; Bakker, Huib J

    2016-10-26

    Though it is commonly known that a small amount of water can be present in triglyceride oil, a molecular picture of how water molecules organize in the oil phase is lacking. We investigate the hydrogen-bond configuration and dynamics of water in triacetin, tributyrin and trioctanoin using linear infrared and time-resolved two-dimensional infrared (2DIR) spectroscopy of the water hydroxyl stretch vibration. We identify water molecules with a single strong hydrogen bond to the triglyceride, water molecules with two weaker hydrogen bonds to the triglycerides, and water clusters. These species do not interconvert on the 20 ps timescale of the experiment, as evidenced by the absence of cross-peaks in the 2DIR spectrum. The vibrational response of water molecules with a single strong hydrogen bond to the triglyceride depends strongly on the excitation frequency, revealing the presence of different subspecies of singly-bound water molecules that correspond to different hydrogen-bond locations. In contrast, the water molecules with two weaker hydrogen bonds to the triglyceride correspond to a single, specific hydrogen-bond configuration; these molecules likely bridge the carbonyl groups of adjacent triglyceride molecules, which can have considerable influence on liquid triglyceride properties.

  17. Appraisal of oil-water separation in field by injection of demulsifier through gas-lift line; Avaliacao da separacao agua-oleo em campo injetando desemulsificante atraves da linha de gas-lift

    Energy Technology Data Exchange (ETDEWEB)

    Ramalho, Joao Batista Vianey da Silva [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas. Setor de Pesquisa, Desenvolvimento e Engenharia]. E-mail: jramalho@cenpes.petrobras.com.br

    2001-12-01

    During the petroleum dehydrating process, the use of demulsifiers is fundamental in the coalescing of emulsions formed in field from the produced petroleum and water. Injection of demulsifiers should be performed the most upstream possible of the processing plant, not only to allow better product performance but to avoid the formation of smaller water drops, due to shearing during flowing of production. Herein presented are the test results of the d emulsifier's performances in field, injected through the gas-lift line of petroleum producing wells. The results showed water removal in the three-phase separator, even when operating in low processing temperature and low liquid residence time inside vessel. (author)

  18. Case Studies of Water Shut-Off Treatments in Oil and Gas Production Wells

    National Research Council Canada - National Science Library

    Sławomir Falkowicz; Stanisław Dubiel; Renata Cicha-Szot

    2012-01-01

      Case Studies of Water Shut-Off Treatments in Oil and Gas Production Wells In this study some of the experimental results of water shut-off treatments in oil and gas production wells were presented...

  19. OPTIMIZATION OF DEMULSIFIER FORMULATION FOR SEPARATION OF WATER FROM CRUDE OIL EMULSIONS

    National Research Council Canada - National Science Library

    Hajivand, P; Vaziri, A

    2015-01-01

    Abstract In this study, various water-soluble and oil-soluble demulsifiers were selected for separation of water from crude oil emulsions and their productivity measured using the Bottle-test method at 70...

  20. Successful strategies for water management in the oil sands region

    Energy Technology Data Exchange (ETDEWEB)

    Smith, J.; Baker, M. [Shell Canada Ltd., Calgary, AB (Canada). Oil Sands Division

    2004-07-01

    Since large quantities of water are required for oil sand mining, water withdrawals from rivers located near oil sand mining facilities may increase. This paper referred to the water-based extraction process at the Muskeg River Mine operated by Albian Sands Energy. Although water is recycled and reused as much as possible, drought conditions in Alberta have raised concerns about the potential increased rates of water withdrawal during seasonal low flow periods. Measures have been taken to manage river withdrawals and ensure sustainability of aquatic resources. A committee has been established under the Cumulative Environmental Management Association (CEMA) to develop a management system for the Athabasca River. The committee includes stakeholders from federal and provincial governments, First Nations, non-government groups and industry. This paper describes the challenges facing oil sands developers in the region with particular emphasis on the role that the newly developed management system called 'Instream Flow Needs', will have on the cumulative water withdrawal from the Athabasca River. 9 figs.

  1. Influence of pumpkin seed oil in continuous phase on droplet size and stability of water-in-oil emulsions

    Directory of Open Access Journals (Sweden)

    Nikolovski Branislava G.

    2011-01-01

    Full Text Available The aim of this work was to contribute to the optimized production of water-in-oil emulsions with pumpkin seed oil in the oil phase using a high-speed homogenizer. Pumpkin seed oil is a valuable natural source of essential fatty acids and biologically active micronutrients that contribute to its nutritive value and medical uses, and reduce interfacial tension between water and the oil phases. Therefore, pumpkin seed oil can be considered as a prosperous oil phase whose use can possibly decrease the amount of some emulsifier that is normally involved in every emulsification process. A central composite rotatable experimental design was implemented to analyze the impact of the contents of polyglycerol polyricinoleate and pumpkin seed oil in the continuous phase, as well as water phase content in the emulsion on droplet size distribution and the response surface methodology was used to obtain optimal conditions for water-in-oil emulsion preparation. Mean size diameter of water droplets was in a range from 400 to 850 nm, with mean peak width of 100 to 220 nm, respectively. The influence of all three investigated factors on the emulsification was determined. Additionally, the emulsions prepared with pumpkin seed oil showed a higher stability during the storage time compared to the emulsions with sunflower oil.

  2. Selective separation of oil and water with mesh membranes by capillarity

    KAUST Repository

    Yu, Yuanlie

    2016-05-29

    The separation of oil and water from wastewater generated in the oil-production industries, as well as in frequent oil spillage events, is important in mitigating severe environmental and ecological damage. Additionally, a wide arrange of industrial processes require oils or fats to be removed from aqueous systems. The immiscibility of oil and water allows for the wettability of solid surfaces to be engineered to achieve the separation of oil and water through capillarity. Mesh membranes with extreme, selective wettability can efficiently remove oil or water from oil/water mixtures through a simple filtration process using gravity. A wide range of different types of mesh membranes have been successfully rendered with extreme wettability and applied to oil/water separation in the laboratory. These mesh materials have typically shown good durability, stability as well as reusability, which makes them promising candidates for an ever widening range of practical applications. © 2016 Elsevier B.V.

  3. Selective separation of oil and water with mesh membranes by capillarity.

    Science.gov (United States)

    Yu, Yuanlie; Chen, Hua; Liu, Yun; Craig, Vincent S J; Lai, Zhiping

    2016-09-01

    The separation of oil and water from wastewater generated in the oil-production industries, as well as in frequent oil spillage events, is important in mitigating severe environmental and ecological damage. Additionally, a wide arrange of industrial processes require oils or fats to be removed from aqueous systems. The immiscibility of oil and water allows for the wettability of solid surfaces to be engineered to achieve the separation of oil and water through capillarity. Mesh membranes with extreme, selective wettability can efficiently remove oil or water from oil/water mixtures through a simple filtration process using gravity. A wide range of different types of mesh membranes have been successfully rendered with extreme wettability and applied to oil/water separation in the laboratory. These mesh materials have typically shown good durability, stability as well as reusability, which makes them promising candidates for an ever widening range of practical applications.

  4. The value of flexibility in offshore oil field development projects

    Energy Technology Data Exchange (ETDEWEB)

    Lund, Morten Wattengaard

    1997-12-31

    Offshore oil field development projects often face substantial uncertainties and the operator`s ability to take corrective actions is very important. The main objective of this thesis was to identify the value of flexibility in such projects. Estimates obtained from exploratory wells can be dependent through common information. The effect of stochastic dependence was illustrated by an analytical model, where the dependence was expressed in terms of correlation between estimate errors. It was found that a high degree of correlation might distort the benefit of additional exploration. A prototype that covered the major phases of the project was developed to study the value of flexibility. The prototype was a Markov decision process, solved by stochastic dynamic programming. Based on discussions with Norwegian oil companies, three uncertain variables were addressed: the reservoir volume, the well rate, and the oil price. Simple descriptions were used to mimic the uncertainty. The reservoir was thus depicted as a tank model, and the well rate and oil prices were assumed to follow Markov processes. Flexibility was restricted to managerial as opposed to financial flexibility. Application of the prototype to a case study, based on an ongoing field development, showed that flexibility might be of considerable value to the project. In particular, capacity flexibility and initiation flexibility were identified as important aspects of the development. The results also emphasized the importance of a joint assessment, as the values of different flexibility types are not additive. In conclusion, the proposed model motivates further development of the decision support system presently available. Future decision making should therefore be made within a framework that gives consideration to flexibility. 129 refs., 46 figs., 23 tabs.

  5. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    Energy Technology Data Exchange (ETDEWEB)

    Lynn E. Katz; E.J. Sullivan; R.S. Bowman

    2000-10-31

    Whereas most water produced from onshore oil and gas operations is disposed via reinjection, some waters, such as those from offshore production platforms, coastal production, and some onshore wells, must be treated to remove organic constituents before the water is discharged. Current methods for reducing residual free phases and dissolved organic carbon are not always fully effective in meeting regulatory limits. In addition, cost, space requirements, and ease of use are important factors in any treatment system. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. This research will use laboratory batch and column studies to design a field system that will be used to treat produced waters to reduce dissolved and free-phase organic constituents. The system will be designed to operate simply and to have low operating costs. Methods for regeneration of the spent zeolite will also be tested, as will the treatment system at a field production site in the final project task. Research over the past six months has focused on the method development, batch adsorption studies to demonstrate removal of target organic constituents, and the selection of a likely test site and characterization of produced waters from the site. Current contacts for selection, and ultimately, testing of example oil field waters include Phillips Petroleum Corp. (offshore location, Gulf of Mexico); MCA Petroleum Corporation in Flatonia, Texas; Amoco production in Farmington, New Mexico; and the New Mexico Bureau of Mines and Mineral Resources (mining operators for coal bed waters from the Farmington area). Water from Phillips Petroleum was received in August and analyzed at the University of Texas. These waters are being used in the laboratory to evaluate interactions between oil field waters and the SMZ. A site visit to MCA Petroleum operations was undertaken on October 12, 2000, and the analyses of samples taken

  6. NUTRIENT CONTENT IN SUNFLOWERS IRRIGATED WITH OIL EXPLORATION WATER

    Directory of Open Access Journals (Sweden)

    ADERVAN FERNANDES SOUSA

    2016-01-01

    Full Text Available Irrigation using produced water, which is generated during crude oil and gas recovery and treated by the exploration industry, could be an option for irrigated agriculture in semiarid regions. To determine the viability of this option, the effects of this treated water on the nutritional status of plants should be assessed. For this purpose, we examined the nutritional changes in sunflowers after they were irrigated with oil - produced water and the effects of this water on plant biomass and seed production. The sunflower cultivar BRS 321 was grown for three crop cycles in areas irrigated with filtered produced water (FPW, reverse osmosis - treated produced water (OPW, or ground water (GW. At the end of each cycle, roots, shoots, and seeds were collected to examine their nutrient concentrations. Produced water irrigation affected nutrient accumulation in the sunflower plants. OPW irrigation promoted the accumulation of Ca, Na, N, P, and Mg. FPW irrigation favored the accumulation of Na in both roots and shoots, and biomass and seed production were negatively affected. The Na in the shoots of plants irrigated with FPW increased throughout the three crop cycles. Under controlled conditions, it is possible to reuse reverse osmosis - treated produced water in agriculture. However, more long - term research is needed to understand its cumulative effects on the chemical and biological properties of the soil and crop production.

  7. Mapping three-dimensional oil distribution with π-EPI MRI measurements at low magnetic field

    Science.gov (United States)

    Li, Ming; Xiao, Dan; Romero-Zerón, Laura; Marica, Florea; MacMillan, Bryce; Balcom, Bruce J.

    2016-08-01

    Magnetic resonance imaging (MRI) is a robust tool to image oil saturation distribution in rock cores during oil displacement processes. However, a lengthy measurement time for 3D measurements at low magnetic field can hinder monitoring the displacement. 1D and 2D MRI measurements are instead often undertaken to monitor the oil displacement since they are faster. However, 1D and 2D images may not completely reflect the oil distribution in heterogeneous rock cores. In this work, a high-speed 3D MRI technique, π Echo Planar Imaging (π-EPI), was employed at 0.2 T to monitor oil displacement. Centric scan interleaved sampling with view sharing in k-t space was employed to improve the temporal resolution of the π-EPI measurements. A D2O brine was employed to distinguish the hydrocarbon and water phases. A relatively homogenous glass bead pack and a heterogeneous Spynie core plug were employed to show different oil displacement behaviors. High quality 3D images were acquired with π-EPI MRI measurements. Fluid quantification with π-EPI compared favorably with FID, CPMG, 1D-DHK-SPRITE, 3D Fast Spin Echo (FSE) and 3D Conical SPRITE measurements. π-EPI greatly reduced the gradient duty cycle and improved sensitivity, compared to FSE and Conical SPRITE measurements, enabling dynamic monitoring of oil displacement processes. For core plug samples with sufficiently long lived T2, T2∗, π-EPI is an ideal method for rapid 3D saturation imaging.

  8. Bacterial Swimming at Air/Water and Oil/Water Interfaces

    Science.gov (United States)

    Morse, Michael; Huang, Athena; Li, Guanglai; Tang, Jay

    2012-02-01

    The microbes inhabiting the planet over billions of years have adapted to diverse physical environments of water, soil, and interfaces between water and either solid or air. Following recent studies on bacterial swimming and accumulation near solid surfaces, we turn our attention to the behavior of Caulobacter crescentus, a singly flagellated bacterium, at water/air and water/oil interfaces. The latter is motivated by relevance to microbial degradation of crude oil in light of the recent oil spill in the Gulf of Mexico. Our ongoing study suggests that Caulobacter swarmer cells tend to get physically trapped at both water/air and water/oil interfaces, accumulating at the surface to a greater degree than boundary confinement properties like that of solid surfaces would predict. At the water/air interface, swimmers move in tight circles at half the speed of swimmers in the bulk fluid. At the water/oil interface, swimming circles are even tighter with further reduced swimming speed. We report experimental data and present preliminary analysis of the findings based on low Reynolds number hydrodynamics, the known surface tension, and surface viscosity at the interface. The analysis will help determine properties of the bacterium such as their surface charge and hydrophobicity.

  9. Data on the physical characterization of oil in water emulsions

    Directory of Open Access Journals (Sweden)

    Aldana L. Zalazar

    2016-12-01

    Full Text Available This article contains experimental data and images for the physical characterization of oil in water emulsions. Mentioned data are related to the research article “Effect of stabilizers, oil level and structure on the growth of Zygosaccharomyces bailii and on physical stability of model systems simulating acid sauces” (A.L. Zalazar, M.F. Gliemmo, C.A. Campos, 2016 [1]. Physical characterization of emulsions was performed through the evaluation of Span and Specific Surface Area (SSA determined by light scattering using a Mastersizer. Furthermore, microscopy images were recorded by confocal scanning laser microscopy (CSLM. The latter are presented to collaborate in the analysis of emulsion microstructure.

  10. Data on the physical characterization of oil in water emulsions.

    Science.gov (United States)

    Zalazar, Aldana L; Gliemmo, María F; Campos, Carmen A

    2016-12-01

    This article contains experimental data and images for the physical characterization of oil in water emulsions. Mentioned data are related to the research article "Effect of stabilizers, oil level and structure on the growth of Zygosaccharomyces bailii and on physical stability of model systems simulating acid sauces" (A.L. Zalazar, M.F. Gliemmo, C.A. Campos, 2016) [1]. Physical characterization of emulsions was performed through the evaluation of Span and Specific Surface Area (SSA) determined by light scattering using a Mastersizer. Furthermore, microscopy images were recorded by confocal scanning laser microscopy (CSLM). The latter are presented to collaborate in the analysis of emulsion microstructure.

  11. Oil Spill Adsorption Capacity of Activated Carbon Tablets from Corncobs in Simulated Oil-Water Mixture

    Directory of Open Access Journals (Sweden)

    Rhonalyn V. Maulion

    2015-12-01

    Full Text Available Oil spill in bodies of water is one of severe environmental problems that is facing all over the country and in the world. Since oil is an integral part of the economy, increasing trend for its demand and transport of has led to a great treat in the surface water. One of the promising techniques in the removal of the oil spills in water bodies is adsorption using activated carbon form waste material such as corn cobs. The purpose of this study is to determine the adsorption capacity of activated carbon tablets derived from corncobs in the removal of oil. The properties of activated carbon produced have a pH of 7.0, bulk density of 0.26 g//cm3 , average pore size of 45nm, particle size of 18% at 60 mesh and 39% at 80 mesh, iodine number of 1370 mg/g and surface area of 1205 g/m2. The amount of bentonite clay as binder (15%,20%,30%, number of ACT (1,2,3 and time of contact(30,60,90 mins has been varied to determine the optimum condition where the activated carbon will have the best adsorption capacity in the removal of oil. Results showed that at 15% binder, 60 mins contact time and 3 tablets of activated carbon is the optimum condition which give a percentage adsorption of 22.82% of oil. Experimental data also showed that a Langmuir isotherm was the best fit isotherm for adsorption of ACT.

  12. 40 CFR 63.137 - Process wastewater provisions-oil-water separators.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Process wastewater provisions-oil-water... Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and Wastewater § 63.137 Process wastewater provisions—oil-water separators. (a) For each oil-water separator that receives, manages, or...

  13. 75 FR 76742 - Detecting Oil Leaks From Vessels Into the Water

    Science.gov (United States)

    2010-12-09

    ... SECURITY Coast Guard Detecting Oil Leaks From Vessels Into the Water AGENCY: Coast Guard, DHS. ACTION... seeks information about the current state of technology to detect loss of oil into the water. DATES... about the current state of technology to detect loss of oil into the water. All information...

  14. Analysis of method of polarization surveying of water surface oil pollution

    Science.gov (United States)

    Zhukov, B. S.

    1979-01-01

    A method of polarization surveying of oil films on the water surface is analyzed. Model calculations of contrasted oil and water obtained with different orientations of the analyzer are discussed. The model depends on the spectral range, water transparency and oil film, and the selection of observational direction.

  15. A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

    NARCIS (Netherlands)

    Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

    2011-01-01

    The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend

  16. A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

    NARCIS (Netherlands)

    Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

    2011-01-01

    The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend o

  17. Electrospun nanofibrous materials: a versatile medium for effective oil/water separation

    Directory of Open Access Journals (Sweden)

    Xianfeng Wang

    2016-09-01

    Full Text Available The separation of oil and water is a worldwide challenge due to the ever-increasing amount of oily industrial wastewater and polluted oceanic waters, as well as the increasing frequency of oil spill accidents. As the leader of advanced fibrous materials, electrospun nanofibers combine the properties of tunable wettability, large surface area, high porosity, good connectivity, fine flexibility, and ease of scalable synthesis from various materials (polymer, ceramic, carbon, etc., and they hold great potential for many emerging environmental applications, including the separation of oily wastewater. In this review, the recent progress in the design and fabrication of electrospun nanofibrous materials with tunable surface wettability for oil/water separation applications is summarized and highlighted. This review covers the research and development starting from the design concepts and the synthesis of nanofibrous sorbents, nanofibrous membranes, and nanofibrous aerogels for effective oil/water separation. The review concludes with a brief forecast of challenges and future directions in this rapidly expanding field.

  18. Effect of interaction heterogeneity on colloidal arrangements at a curved oil-water interface.

    Science.gov (United States)

    Lee, Mina; Lee, Daeyeon; Park, Bum Jun

    2015-01-14

    We report the unique arrangement behaviour of colloidal particles at a curved oil-water interface. Particles trapped at a centrosymmetrically curved oil-water interface, formed by placing an oil lens at a neat air-water interface, organize into diverse arrangement structures due to electrostatic repulsion under the gravitational field. To reveal a possible mechanism behind the observed diversity, we investigate the interactions between pairs of particles at the curved oil-water interface. The magnitude of electrostatic repulsive interactions between pairs of particles is determined by minimizing the total potential of the particle pairs. We show that the pair interactions are quite heterogeneous, following a Gamma distribution. Using the experimentally determined pair potential and the heterogeneity in the potential as input parameters for Monte Carlo simulations, we show that such interaction heterogeneity affects the particle arrangements at the curved interface and results in an observed diversity in the particle arrangement structures. We believe that this work prompts further experimental and simulation studies to extensively understand hierarchical relations from small scale measurements (e.g., pair interactions and heterogeneity) to bulk scale properties (e.g., microstructure and interfacial rheology).

  19. Map Service Showing Geology, Oil and Gas Fields, and Geologic Provinces of Europe including Turkey

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digitally compiled map includes geology, oil and gas fields, and geologic provinces of Europe. The oil and gas map is part of a worldwide series released on...

  20. Map Service Showing Geology, Oil and Gas Fields, and Geologic Provinces of South America

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digitally compiled map includes geology, oil and gas fields, and geologic provinces of South America. The oil and gas map is part of a worldwide series released...

  1. Oil sands water withdrawal challenges and the Athabasca River

    Energy Technology Data Exchange (ETDEWEB)

    Smith, J.; Baker, M. [Shell Canada Ltd., Calgary, AB (Canada). Calgary Research Centre

    2003-07-01

    Drought conditions in Alberta have raised concerns regarding water withdrawal from the Athabasca River for oil sands development projects in the Regional Municipality of Wood Buffalo in Northeastern Alberta. In particular, concerns have been raised about the potential increased rates of water withdrawal during seasonal low flow periods. A committee has been established under the Cumulative Environmental Management Association (CEMA) to develop a management system for the Athabasca River. The committee includes stakeholders from federal and provincial governments, First Nations, non-government groups and industry. This paper describes the challenges facing oil sands developers in the region with particular emphasis on the role that the newly developed management system called 'Instream Flow Needs', will have on the cumulative water withdrawal from the Athabasca River. tabs., figs.

  2. Delineating Concealed Faults within Cogdell Oil Field via Earthquake Detection

    Science.gov (United States)

    Aiken, C.; Walter, J. I.; Brudzinski, M.; Skoumal, R.; Savvaidis, A.; Frohlich, C.; Borgfeldt, T.; Dotray, P.

    2016-12-01

    Cogdell oil field, located within the Permian Basin of western Texas, has experienced several earthquakes ranging from magnitude 1.7 to 4.6, most of which were recorded since 2006. Using the Earthscope USArray, Gan and Frohlich [2013] relocated some of these events and found a positive correlation in the timing of increased earthquake activity and increased CO2 injection volume. However, focal depths of these earthquakes are unknown due to 70 km station spacing of the USArray. Accurate focal depths as well as new detections can delineate subsurface faults and establish whether earthquakes are occurring in the shallow sediments or in the deeper basement. To delineate subsurface fault(s) in this region, we first detect earthquakes not currently listed in the USGS catalog by applying continuous waveform-template matching algorithms to multiple seismic data sets. We utilize seismic data spanning the time frame of 2006 to 2016 - which includes data from the U.S. Geological Survey Global Seismographic Network, the USArray, and the Sweetwater, TX broadband and nodal array located 20-40 km away. The catalog of earthquakes enhanced by template matching reveals events that were well recorded by the large-N Sweetwater array, so we are experimenting with strategies for optimizing template matching using different configurations of many stations. Since earthquake activity in the Cogdell oil field is on-going (a magnitude 2.6 occurred on May 29, 2016), a temporary deployment of TexNet seismometers has been planned for the immediate vicinity of Cogdell oil field in August 2016. Results on focal depths and detection of small magnitude events are pending this small local network deployment.

  3. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    Energy Technology Data Exchange (ETDEWEB)

    Lynn E. Katz; R.S. Bowman; E.J. Sullivan

    2003-11-01

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of

  4. Premium performance heating oil - Part 2, Field trial results

    Energy Technology Data Exchange (ETDEWEB)

    Jetter, S.M.; Hoskin, D.; McClintock, W.R. [Mobil Oil Corp., Paulsboro, NJ (United States)] [and others

    1996-07-01

    Limited field trial results of a heating oil additive package developed to minimize unscheduled maintenance indicate that it achieves its goal of keeping heating oil systems cleaner. The multifunctional additive package was developed to provide improved fuel oxidation stability, improved corrosion protection, and dispersency. This combination of performance benefits was chosen because we believed it would retard the formation of sludge, as well as allow sludge already present to be carried through the system without fouling the fuel system components (dispersency should keep sludge particles small so they pass through the filtering system). Since many unscheduled maintenance calls are linked to fouling of the fuel filtering system, the overall goal of this technology is to reduce these maintenance calls. Photographic evidence shows that the additive package not only reduces the amount of sludge formed, but even removes existing sludge from filters and pump strainers. This {open_quotes}clean-up{close_quotes} performance is provided trouble free: we found no indication that nozzle/burner performance was impaired by dispersing sludge from filters and pump strainers. Qualitative assessments from specific accounts that used the premium heating oil also show marked reductions in unscheduled maintenance.

  5. Quality of underground water and hydro-geological situation caused by oil exploitation in the area of Kikinda

    Directory of Open Access Journals (Sweden)

    Pašić Milana

    2010-01-01

    Full Text Available Numerous oil fields were discovered in the area of North Banat and its regional centre, the city of Kikinda. These oil fields were explored and exploited in the second half of the XX century. Oil rigs in the area of the city zone can endanger the environment, as well as the quality of life of the citizens. In order to discover the presence of polycyclic aromatic hydrocarbon we have applied GC/MSD technique, whereas we have applied GC/MSD Purge and trap. technique to discover the presence of aromatic hydrocarbon. Chemical analyses of water samples from the area of Kikinda did nit prove that underground water was polluted with oil. .

  6. Recovery of Palm Oil and Valuable Material from Oil Palm Empty Fruit Bunch by Sub-critical Water.

    Science.gov (United States)

    Ahmad Kurnin, Nor Azrin; Shah Ismail, Mohd Halim; Yoshida, Hiroyuki; Izhar, Shamsul

    2016-01-01

    Oil palm empty fruit bunch (EFB) is one of the solid wastes produced in huge volume by palm oil mill. Whilst it still contains valuable oil, approximately 22.6 million tons is generated annually and treated as solid waste. In this work, sub-critical water (sub-cw) was used to extract oil, sugar and tar from spikelet of EFB. The spikelet was treated with sub-cw between 180-280°C and a reaction time of 2 and 5 minutes. The highest yield of oil was 0.075 g-oil/g-dry EFB, obtained at 240°C and reaction time of 5 minutes. Astonishingly, oil that was extracted through this method was 84.5% of that obtained through Soxhlet method using hexane. Yield of oil extracted was strongly affected by the reaction temperature and time. Higher reaction temperature induces the dielectric constant of water towards the non-polar properties of solvent; thus increases the oil extraction capability. Meanwhile, the highest yield of sugar was 0.20 g-sugar/g-dry EFB obtained at 220°C. At this temperature, the ion product of water is high enough to enable maximum sub-critical water hydrolysis reaction. This study showed that oil and other valuable material can be recovered using water at sub-critical condition, and most attractive without the use of harmful organic solvent.

  7. Mercury concentrations in urine of amerindian populations near oil fields in the peruvian and ecuadorian amazon.

    Science.gov (United States)

    Webb, Jena; Coomes, Oliver T; Ross, Nancy; Mergler, Donna

    2016-11-01

    Mercury is a global contaminant with toxic, persistent effects on human health. Petroleum extraction is an important source of elemental mercury; little is known about human exposure levels near oil fields in the Amazon basin. To characterize mercury levels in people living near oil production sites in the Peruvian and Ecuadorian Amazon, controlling for fish consumption, occupation, source of water and socio-demographic characteristics. Analyze mercury levels in urine samples using cold vapour atomic fluorescence spectrometry from 76 indigenous men and women in eight riverine communities situated near oil wells or pipelines. Subjects answered a questionnaire soliciting socio-demographic, occupational and dietary information. Data were analyzed using multiple linear regression modeling. The mean value of U-Hg was 2.61μg/g creatinine (95% CI: 2.14-3.08), with 7% of the sample recording values above the global background standard suggested by The World Health Organization (5μg/g creatinine). Women who used water from a surface source had two and a half times the amount of mercury in their urine (mean=3.70μg/g creatinine, 95% CI: 2.26-5.15) compared with women who used other water sources (mean =1.39μg/g creatinine, 95% CI: 0.51-2.25). Men who were involved in an oil clean-up operation had twice as much mercury in their urine (mean =3.07μg/g creatinine, 95% CI: 1.97-4.16) as did those who worked on other tasks (mean =1.56μg/g creatinine, 95% CI: 1.48-2.65). Mercury levels were not associated with the number of fish meals per week. Indigenous peoples of the Peruvian and Ecuadorian Amazon living near oil production sites generally had urine mercury levels within the global background standard suggested by the World Health Organization. Increased levels of mercury in urine were detected for men involved in oil spill remediation and for women who relied on surface water for household needs. These findings signal the need for strict safety measures to limit the amount

  8. Gas injection may have triggered earthquakes in the Cogdell oil field, Texas.

    Science.gov (United States)

    Gan, Wei; Frohlich, Cliff

    2013-11-19

    Between 1957 and 1982, water flooding was conducted to improve petroleum production in the Cogdell oil field north of Snyder, TX, and a contemporary analysis concluded this induced earthquakes that occurred between 1975 and 1982. The National Earthquake Information Center detected no further activity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. To investigate these earthquakes, we analyzed data recorded by six temporary seismograph stations deployed by the USArray program, and identified 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocation with a double-difference method shows that most earthquakes occurred within several northeast-southwest-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified faults. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Water injection cannot explain the 2006-2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957-1982 period. However, since 2004 significant volumes of gases including supercritical CO2 have been injected into the Cogdell field. The timing of gas injection suggests it may have contributed to triggering the recent seismic activity. If so, this represents an instance where gas injection has triggered earthquakes having magnitudes 3 and larger. Further modeling studies may help evaluate recent assertions suggesting significant risks accompany large-scale carbon capture and storage as a strategy for managing climate change.

  9. Computational study of effect of water finger on ion transport through water-oil interface

    Science.gov (United States)

    Kikkawa, Nobuaki; Wang, Lingjian; Morita, Akihiro

    2016-07-01

    When an ion transports from water to oil through water-oil interface, it accompanies hydrated water molecules and transiently forms a chain of water, called "water finger." We thoroughly investigated the role of the water finger in chloride ion transport through water-dichloromethane interface by using molecular dynamics technique. We developed a proper coordinate w to describe the water finger structure and calculated the free energy landscape and the friction for the ion transport as a function of ion position z and the water finger coordinate w. It is clearly shown that the formation and break of water finger accompanies an activation barrier for the ion transport, which has been overlooked in the conventional free energy curve along the ion position z. The present analysis of the friction does not support the hypothesis of augmented local friction (reduced local diffusion coefficient) at the interface. These results mean that the experimentally observed rate constants of interfacial ion transfer are reduced from the diffusion-limited one because of the activation barrier associated to the water finger, not the anomalous local diffusion. We also found that the nascent ion just after the break of water finger has excessive hydration water than that in the oil phase.

  10. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  11. Bioinspired polydopamine particles-assisted construction of superhydrophobic surfaces for oil/water separation.

    Science.gov (United States)

    Shang, Bin; Wang, Yanbing; Peng, Bo; Deng, Ziwei

    2016-11-15

    simplicity and versatility of the direct mussel-inspired approach may facilitate the fast development of oil/water separation materials for applications in the field of water remediation, clean-up of oil spills and oil recovery. Copyright © 2016 Elsevier Inc. All rights reserved.

  12. Upwind finite difference method for miscible oil and water displacement problem with moving boundary values

    Institute of Scientific and Technical Information of China (English)

    Yi-rang YUAN; Chang-feng LI; Cheng-shun YANG; Yu-ji HAN

    2009-01-01

    The research of the miscible oil and water displacement problem with moving boundary values is of great value to the history of oil-gas transport and accumulation in the basin evolution as well as to the rational evaluation in prospecting and exploiting oil-gas resources. The mathematical model can be described as a coupled system of nonlinear partial differential equations with moving boundary values. For the two-dimensional bounded region, the upwind finite difference schemes are proposed. Some techniques, such as the calculus of variations, the change of variables, and the theory of a priori estimates, are used. The optimal order l2-norm estimates are derived for the errors in the approximate solutions. The research is important both theoretically and practically for the model analysis in the field, the model numerical method, and the software development.

  13. Novel preparation method for sustained-release PLGA microspheres using water-in-oil-in-hydrophilic-oil-in-water emulsion

    Directory of Open Access Journals (Sweden)

    Hong X

    2013-07-01

    Full Text Available Xiaoyun Hong,1,2,* Liangming Wei,3,* Liuqing Ma,2 Yinghui Chen,4 Zhenguo Liu,1 Weien Yuan2,* 1Department of Neurology, Xinhua Hospital affiliated to Shanghai JiaoTong University, School of Medicine, Shanghai, People's Republic of China; 2School of Pharmacy, Shanghai JiaoTong University, 3Key Laboratory for Thin Film and Microfabrication Technology, Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai JiaoTong University, Shanghai, People's Republic of China; 4Department of Neurology, Jinshan Hospital, Fudan University, Shanghai, People's Republic of China *These authors contributed equally to this work Abstract: An increasing number of drugs are needing improved formulations to optimize patient compliance because of their short half-lives in blood. Sustained-release formulations of drugs are often required for long-term efficacy, and microspheres are among the most popular ones. When drugs are encapsulated into microsphere formulations, different methods of preparation need to be used according to specific clinical requirements and the differing physicochemical characteristics of individual drugs. In this work, we developed a novel method for sustained-release drug delivery using a water-in-oil-in-hydrophilic oil-in-water (w/o/oh/w emulsion to encapsulate a drug into poly(lactic-co-glycolic acid (PLGA microspheres. Different effects were achieved by varying the proportions and concentrations of hydrophilic oil and PLGA. Scanning electron and optical microscopic images showed the surfaces of the microspheres to be smooth and that their morphology was spherical. Microspheres prepared using the w/o/oh/w emulsion were able to load protein efficiently and had sustained-release properties. These results indicate that the above-mentioned method might be useful for developing sustained-release microsphere formulations in the future. Keywords: protein, microspheres, water-in-oil-in-hydrophilic oil-in-water

  14. Water drop impact onto oil covered solid surfaces

    Science.gov (United States)

    Chen, Ningli; Chen, Huanchen; Amirfazli, Alidad

    2016-11-01

    Droplet impact onto an oily surface can be encountered routinely in industrial applications; e.g., in spray cooling. It is not clear from literature what impact an oil film may have on the impact process. In this work, water drop impact onto both hydrophobic (glass) and hydrophilic (OTS) substrates which were covered by oil films (silicone) of different thickness (5um-50um) and viscosity (5cst-100cst) were performed. The effects of drop impact velocity, film thickness, and viscosity of the oil film and wettability of the substrate were studied. Our results show that when the film viscosity and impact velocity is low, the water drop deformed into the usual disk shape after impact, and rebounded from the surface. Such rebound phenomena disappears, when the viscosity of oil becomes very large. With the increase of the impact velocity, crown and splashing appears in the spreading phase. The crown and splashing behavior appears more easily with the increase of film thickness and decrease of its viscosity. It was also found that the substrate wettability can only affect the impact process in cases which drop has a large Webber number (We = 594), and the film's viscosity and thickness are small. This work was support by National Natural Science Foundation of China and the Project Number is 51506084.

  15. Recovery of oil from oil-in-water emulsion using biopolymers by adsorptive method.

    Science.gov (United States)

    Elanchezhiyan, S Sd; Sivasurian, N; Meenakshi, Sankaran

    2014-09-01

    In the present study, it is aimed to identify, a low cost sorbent for the recovery of oil from oil-in-water emulsion using biopolymers such as chitin and chitosan. Chitin has the greater adsorption capacity than chitosan due to its hydrophobic nature. The characterizations of chitin and chitosan were done using FTIR, SEM, EDAX, XRD, TGA and DSC techniques. Under batch equilibrium mode, a systematic study was performed to optimize the various equilibrium parameters viz., contact time, pH, dosage, initial concentration of oil, and temperature. The adsorption process reached equilibrium at 40 min of contact time and the percentage removal of oil was found to be higher (90%) in the acidic medium. The Freundlich and Langmuir models were applied to describe the equilibrium isotherms and the isotherm constants were calculated. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were calculated to find out the nature of the sorption mechanism. The kinetic studies were investigated with reaction-based and diffusion-based models. The suitable mechanism for the removal of oil has been established.

  16. Novel Methodology for the Highly-Efficient Separation of Oil and Water (Briefing Charts)

    Science.gov (United States)

    2014-03-16

    Fabric Pure PEGDA Pure PEGDA 10% POSS 20% POSS 10% POSS 20% POSS Water Rapeseed oil Water Rapeseed oil PEGDA surface reconfiguration leads to...Briefing Charts 3. DATES COVERED (From - To) March 2014- April 2014 4. TITLE AND SUBTITLE Novel Methodology for the Highly-Efficient Separation of Oil and...distrib tion unlimited. Novel Methodology for the Highly- Efficient Separation of Oil and Water Joseph Mabry, Anish Tuteja, Andrew Guenthner, Josiah Reams

  17. Field Monitoring Protocol: Heat Pump Water Heaters

    Energy Technology Data Exchange (ETDEWEB)

    Sparn, B.; Earle, L.; Christensen, D.; Maguire, J.; Wilson, E.; Hancock, E.

    2013-02-01

    This document provides a standard field monitoring protocol for evaluating the installed performance of Heat Pump Water Heaters in residential buildings. The report is organized to be consistent with the chronology of field test planning and execution. Research questions are identified first, followed by a discussion of analysis methods, and then the details of measuring the required information are laid out. A field validation of the protocol at a house near the NREL campus is included for reference.

  18. Field Monitoring Protocol. Heat Pump Water Heaters

    Energy Technology Data Exchange (ETDEWEB)

    Sparn, B. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Earle, L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Christensen, D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Maguire, J. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Wilson, E. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hancock, C. E. [Mountain Energy Partnership, Longmont, CO (United States)

    2013-02-01

    This document provides a standard field monitoring protocol for evaluating the installed performance of Heat Pump Water Heaters in residential buildings. The report is organized to be consistent with the chronology of field test planning and execution. Research questions are identified first, followed by a discussion of analysis methods, and then the details of measuring the required information are laid out. A field validation of the protocol at a house near the NREL campus is included for reference.

  19. Disposal of NORM-Contaminated Oil Field Wastes in Salt Caverns

    Energy Technology Data Exchange (ETDEWEB)

    Blunt, D.L.; Elcock, D.; Smith, K.P.; Tomasko, D.; Viel, J.A.; and Williams, G.P.

    1999-01-21

    In 1995, the U.S. Department of Energy (DOE), Office of Fossil Energy, asked Argonne National Laboratory (Argonne) to conduct a preliminary technical and legal evaluation of disposing of nonhazardous oil field waste (NOW) into salt caverns. That study concluded that disposal of NOW into salt caverns is feasible and legal. If caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they can be a suitable means of disposing of NOW (Veil et al. 1996). Considering these findings and the increased U.S. interest in using salt caverns for NOW disposal, the Office of Fossil Energy asked Argonne to conduct further research on the cost of cavern disposal compared with the cost of more traditional NOW disposal methods and on preliminary identification and investigation of the risks associated with such disposal. The cost study (Veil 1997) found that disposal costs at the four permitted disposal caverns in the United States were comparable to or lower than the costs of other disposal facilities in the same geographic area. The risk study (Tomasko et al. 1997) estimated that both cancer and noncancer human health risks from drinking water that had been contaminated by releases of cavern contents were significantly lower than the accepted risk thresholds. Since 1992, DOE has funded Argonne to conduct a series of studies evaluating issues related to management and disposal of oil field wastes contaminated with naturally occurring radioactive material (NORM). Included among these studies were radiological dose assessments of several different NORM disposal options (Smith et al. 1996). In 1997, DOE asked Argonne to conduct additional analyses on waste disposal in salt caverns, except that this time the wastes to be evaluated would be those types of oil field wastes that are contaminated by NORM. This report describes these analyses. Throughout the remainder of this report, the term ''NORM waste'' is used to mean ''oil

  20. A many-body dissipative particle dynamics study of forced water-oil displacement in capillary.

    Science.gov (United States)

    Chen, Chen; Zhuang, Lin; Li, Xuefeng; Dong, Jinfeng; Lu, Juntao

    2012-01-17

    The forced water-oil displacement in capillary is a model that has important applications such as the groundwater remediation and the oil recovery. Whereas it is difficult for experimental studies to observe the displacement process in a capillary at nanoscale, the computational simulation is a unique approach in this regard. In the present work, the many-body dissipative particle dynamics (MDPD) method is employed to simulate the process of water-oil displacement in capillary with external force applied by a piston. As the property of all interfaces involved in this system can be manipulated independently, the dynamic displacement process is studied systematically under various conditions of distinct wettability of water in capillary and miscibility between water and oil as well as of different external forces. By analyzing the dependence of the starting force on the properties of water/capillary and water/oil interfaces, we find that there exist two different modes of the water-oil displacement. In the case of stronger water-oil interaction, the water particles cannot displace those oil particles sticking to the capillary wall, leaving a low oil recovery efficiency. To minimize the residual oil content in capillary, enhancing the wettability of water and reducing the external force will be beneficial. This simulation study provides microscopic insights into the water-oil displacement process in capillary and guiding information for relevant applications.

  1. Planning the sampling of a condensed-gas field with an oil fringe at the Benoi field

    Energy Technology Data Exchange (ETDEWEB)

    Siuniaev, Y.K.; Trubaev, V.L.

    1981-01-01

    In order to obtain data for determining gas, condensate and oil reserves, planning field development, and monitoring the operation of condensed gas wells in fields, a system of gas-hydrodynamic and specialized studies is developed.

  2. Case History of 3D Seismic Survey in Aershan Oil Field

    Institute of Scientific and Technical Information of China (English)

    Lu Yousheng

    1996-01-01

    @@ Aershan Oil Field is located at the eastern end of the Manite depression .in the northeastern part of Erlian basin of North China (Fig. 1). Three oilfields -Anan, Abei and Hanan - were discovered in the Erlian basin in the early 1980s using 2D seismic survey with a very dense 0.5 km ×0.5 km grid. However. difficulties were encountered in structural delineation and lateral reservoir prediction.partly due to low signal to noise ratio and resolution of 2D section, partly due to extensive lateral variations. In order to solve these problems, large- area 3D seismic survey was conducted in the late 1980s. 3D survey area is 80 km2.This survey accurately identified the details of reservoir structures, as well as located low-relief structures. Good results were also obtained in predicting lateral reservoir variations and ascertaining oil/water contacts and oilbearing areas.

  3. Characterization of Emulsions of Fish Oil and Water by Cryo Scanning Electron Microscopy

    DEFF Research Database (Denmark)

    Jensen, Louise Helene Søgaard; Horn, Anna Frisenfeldt; Jacobsen, Charlotte

    to the many double bonds. Emulsions of fish oil in water are potential candidates for a delivery system of fish oil to food products. It has been suggested that oxidation of oil-in-water emulsions is initiated at the interface between oil and water. It has also been proposed that oxidation is to some extent...... dependent on the ultra structure of the emulsion; including the size of oil droplets, their distribution and the thickness of the interface between oil and water. This interface is stabilized by macromolecules such as proteins, phospholipids and hydrocolloids. The main objective of this study...... is to characterize fish oil in water emulsions with respect to oil droplet size, distribution, and ultimately to view the structure and thickness of the interface layer. A freeze-fractured surface viewed at low temperatures under the scanning electron microscope is a promising strategy to reveal variations...

  4. Mineral-coated polymer membranes with superhydrophilicity and underwater superoleophobicity for effective oil/water separation.

    Science.gov (United States)

    Chen, Peng-Cheng; Xu, Zhi-Kang

    2013-09-27

    Oil-polluted water is a worldwide problem due to the increasing industrial oily wastewater and the frequent oil spill accidents. Here, we report a novel kind of superhydrophilic hybrid membranes for effective oil/water separation. They were prepared by depositing CaCO3-based mineral coating on PAA-grafted polypropylene microfiltration membranes. The rigid mineral-coating traps abundant water in aqueous environment and forms a robust hydrated layer on the membrane pore surface, thus endowing the membranes with underwater superoleophobicity. Under the drive of either gravity or external pressure, the hybrid membranes separate a range of oil/water mixtures effectively with high water flux (>2000 L m(-2) h(-1)), perfect oil/water separation efficiency (>99%), high oil breakthrough pressure (>140 kPa) and low oil fouling. The oil/water mixtures include not only free mixtures but also oil-in-water emulsions. Therefore, the mineral-coated membrane enables an efficient and energy-saving separation for various oil/water mixtures, showing attractive potential for practical oil/water separation.

  5. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  6. Selective retardation of perfume oil evaporation from oil-in-water emulsions stabilized by either surfactant or nanoparticles.

    Science.gov (United States)

    Binks, Bernard P; Fletcher, Paul D I; Holt, Benjamin L; Beaussoubre, Pascal; Wong, Kenneth

    2010-12-07

    We have used dynamic headspace analysis to investigate the evaporation rates of perfume oils from stirred oil-in-water emulsions into a flowing gas stream. We compare the behavior of an oil of low water solubility (limonene) and one of high water solubility (benzyl acetate). It is shown how the evaporation of an oil of low water solubility is selectively retarded and how the retardation effect depends on the oil volume fraction in the emulsion. We compare how the evaporation retardation depends on the nature of the adsorbed film stabilizing the emulsion. Surfactant films are less effective than adsorbed films of nanoparticles, and the retardation can be further enhanced by compression of the adsorbed nanoparticle films by preshrinking the emulsion drops.

  7. Methodology and some results of the multifaceted evaluation of ecological risk of maintenance of oil and gas fields

    Energy Technology Data Exchange (ETDEWEB)

    Vozuesensky, E.A. [Department of Engineering and Environmental Geology, Moscow State University (Russian Federation); Samarin, E.N. [Ditto (Russian Federation); Voznessenskaya, V.V. [A.N. Severtzov Institute of Ecology and Evolution RAS, Moscow (Russian Federation)

    2000-07-01

    An inter-disciplinary methodology to investigate pollution from maintenance of oil and gas fields and to explore potential impact of new ones has been developed and tested at three oil and gas fields in Western Siberia and Mid-Volga region with different duration of exploitation. The investigations focused on the impact of oil, its derivatives and other chemicals on human health and biocenoses. The research included combination of methods of environmental geology, geophysics, bioindication, cytogenetics and analytical chemistry and is based on the idea that reliable control of concentration, regularities of sorption and the complete tracing of oil pollution in the environment from the source of contamination through the soils, ground and surface water, soil biota and via the food chains to small mammals and birds are needed to assess ecological risk. It is anticipated that direct determination of oil and its derivatives concentration in soil and ground water can provide a basis to understand the results of bioindication. The obtained data revealed the main regularities of the pollutants migration in soils and ground waters, the most dangerous sources of their contamination and demonstrated the impact of gas torches on soils, vegetation and soil- dwelling animals using new reliable and independent indices. (orig.)

  8. Alkyl bicarbamates supramolecular organogelators with effective selective gelation and high oil recovery from oil/water mixtures.

    Science.gov (United States)

    Wang, Yongzhen; Wu, Songquan; Yan, Xingru; Ma, Tao; Shao, Lu; Liu, Yuyan; Guo, Zhanhu

    2017-01-01

    A series of alkyl bicarbamates supramolecular organogelators were synthesized with different structures and lengths of alkyl chains. The driving forces for the self-assembly of small molecules, including the intermolecular H bonding, π-π stacking and van der Waals interactions, played an important role in the formation of different 3D network structures, i.e., fibers, ribbons, sheets, and prisms. And a probable formation process of the gel networks was proposed. Furthermore, the phase-selective gelling performances were investigated for oil removal from aqueous solution. Interestingly, the gelling properties were found to be affected by the length and structure of alkyl chains, while some gelators with intermediate alkyl chain lengths could effectively gel all the tested oils from water surface within 15 min, such as Russian crude oil, diesel, gasoline, soybean oil, peanut oil, olive oil, cyclohexane, hexane and ethyl acetate. Advantageously, fast gelation, high rate of oil removal (>95%) and excellent oil retention rate (close to 100%) were realized in the recovery of oil spills from water surface. This kind of supramolecular gelators demonstrates good potential applications in the delivery or removal of organic pollution from oil/water mixtures.

  9. Molecular dynamics simulations of radon accumulation in water and oil

    Energy Technology Data Exchange (ETDEWEB)

    Pafong, Elvira; Drossel, Barbara [Institut fuer Festkoerperphysik, Technische Universitaet Darmstadt (Germany)

    2016-07-01

    Radon is a radioactive gas that can enter the human body from air or from ground water. Radon can accumulate to levels that considerably rise the risk of lung cancer while it is also known as a a treatment of various ailments, most notably rheumatoid arthritis. The accumulation of radon differs between tissues, with particularly high concentrations in fatty cells. In order to understand the mechanisms responsible for the different solubility of radon in water and fat, we perform molecular dynamics simulations of radon gas at ambient conditions in contact with a bulk material consisting either of water or oil. We evaluate the diffusion coefficient of radon in both media as well as the equilibrium concentration. The crucial point here is to understand the hydrophobic interaction between water and radon as compared to the dispersive interaction between radon and oil. Therefore, we artificially vary the water charges (i.e., the hydrophobicity) as well as the parameters of the van-der-Waals interaction.

  10. Water in soybean oil microemulsions as medium for electrochemical measurements

    Directory of Open Access Journals (Sweden)

    Mendonça Carla R. B.

    2003-01-01

    Full Text Available Microemulsions of water in soybean oil (w/o ME were prepared with sodium dodecyl sulfate (SDS as surfactant and amyl or isoamyl alcohol, as co-surfactants. Microemulsions containing 40.0% oil, 43.2% alcohol, 10.8% SDS and 6.0% water in weight, in the ratio 1:4 [SDS]:[alcohol] showed the highest thermodynamic stability. The aqueous droplet size and its diffusion coefficient Dw/o in the ME were determined through dynamic light scattering (DLS. Voltammetric measurements in the ME at a Pt disk ultramicroelectrode (ume evidenced the oxidation of both water and ferrocene (Fc, and the reduction of oleic acid. The Dw/o values calculated from the limiting current being lower than the ones obtained from DLS indicate that water oxidation probably requires diffusion towards the electrode of both the droplets and the water molecules from inside the droplets. The results show that electroanalytical determinations can be carried out in w/o ME.

  11. Determination of water in NIST reference material for mineral oils

    Science.gov (United States)

    Cedergren; Nordmark

    2000-07-15

    The accuracy of the reference concentrations of moisture in electrical insulating oil RM 8506 and lubricating oil RM 8507 (both of mineral type) and specified by the National Institute of Standards and Technology (NIST) as containing 39.7 and 76.8 ppm (w/w) water, respectively, has recently been the subject of debate in this journal. To shed some further light on this controversy, we report in this correspondence results for these oils obtained by two additional methods, one based on specially designed reagents for diaphragm-free Karl Fischer (KF) coulometry and the other based on the concept of stripping at elevated temperature/continuous KF coulometry. A positive interference effect was shown to take place for RM 8506 when the direct coulometric method was used. If the results are corrected for this, the values including six different procedures varied in the range 13.5-15.6 ppm (w/w). For RM 8507, all values were between 42.5 and 47.2 ppm (w/w), which means that the values recommended by NIST for both reference oils using volumetric titration are about twice as high as those obtained with the other techniques. A possible explanation for this discrepancy is presented.

  12. Superoleophillic electrospun polystrene/exofoliated graphite fibre for selective removal of crude oil from water

    Science.gov (United States)

    Alayande, S. Oluwagbemiga; Dare, Enock O.; Olorundare, F. O. Grace; Nkosi, D.; Msagati, Titus A. M.; Mamba, B. B.

    2016-04-01

    During oil spills, the aquatic environment is greatly endangered because oil floats on water making the penetration of sunlight difficult therefore primary productivity is compromised, birds and aquatic organisms are totally eliminated within a short period. It is therefore essential to remove the oil from the water bodies after the spillage. This work reports on the fabrication of oil loving electrospun polystyrene-exofoliated graphite fibre with hydrophobic and oleophillic surface properties. The fibre was applied for the selective adsorption of crude oil from simulated crude oil spillage on water. The maximum oil adsorption capacity of the EPS/EG was 1.15 kg/g in 20 min while the lowest oil adsorption capacity was 0.81 kg/g in 10 min. Cheap oil adsorbent was developed with superoleophillic and superhydrophobic properties.

  13. Toxicity of water-soluble fractions of biodiesel fuels derived from castor oil, palm oil, and waste cooking oil.

    Science.gov (United States)

    Leite, Maria Bernadete Neiva Lemos; de Araújo, Milena Maria Sampaio; Nascimento, Iracema Andrade; da Cruz, Andrea Cristina Santos; Pereira, Solange Andrade; do Nascimento, Núbia Costa

    2011-04-01

    Concerns over the sustained availability of fossil fuels and their impact on global warming and pollution have led to the search for fuels from renewable sources to address worldwide rising energy demands. Biodiesel is emerging as one of the possible solutions for the transport sector. It shows comparable engine performance to that of conventional diesel fuel, while reducing greenhouse gas emissions. However, the toxicity of products and effluents from the biodiesel industry has not yet been sufficiently investigated. Brazil has a very high potential as a biodiesel producer, in view of its climatic conditions and vast areas for cropland, with consequent environmental risks because of possible accidental biodiesel spillages into water bodies and runoff to coastal areas. This research determined the toxicity to two marine organisms of the water-soluble fractions (WSF) of three different biodiesel fuels obtained by methanol transesterification of castor oil (CO), palm oil (PO), and waste cooking oil (WCO). Microalgae and sea urchins were used as the test organisms, respectively, for culture-growth-inhibition and early-life-stage-toxicity tests. The toxicity levels of the analyzed biodiesel WSF showed the highest toxicity for the CO, followed by WCO and the PO. Methanol was the most prominent contaminant; concentrations increased over time in WSF samples stored up to 120 d. Copyright © 2010 SETAC.

  14. Water holdup measurement of oil-water two-phase flow in a horizontal well using a dual-circle conductance probe array

    Science.gov (United States)

    Xu, Lijun; Zhang, Wen; Cao, Zhang; Zhao, Jiayu; Xie, Ronghua; Liu, Xingbin; Hu, Jinhai

    2016-11-01

    This paper presents a minimum root-mean-square error (RMSE)-based method for a dual-circle conductance probe array to measure the water holdup of an oil-water two-phase flow in a horizontal oil well. The dual-circle conductance probe array consisting of 24 conductance probes, half of which are equidistantly distributed on a 34 mm radius inner circle and the other half on a 48 mm radius outer circle, is used to estimate the oil-water interface and hence the water holdup in the horizontal oil well. For the same water holdup, the number of probes immersed in water may vary with varying the azimuth angle due to the limited number of probes. The limited number of probes and unknown azimuth angle of the probe array in the oil well limit the measurement accuracy of the water holdup. In order to obtain a better water holdup estimate, a water holdup measurement method based on the minimum RMSE was proposed to decrease the effects of the limited number of probes and unknown azimuth angle of the probe array. To verify the proposed method, numerical simulations were carried out and compared with the commonly used equi-weight estimate method; results showed that the RMSE of the water holdup estimates obtained using the proposed method is smaller than that when using the equi-weight estimate method. Experiments were implemented in a 16 m long and 125 mm inner diameter horizontal pipe on an industrial-scale experimental multiphase flow setup in the Daqing Oil Field, China. The RMSEs of water holdup estimates obtained using the proposed and equi-weight estimate methods are 0.0632 and 0.0690, respectively, showing that the proposed method is better than the equi-weight estimate method.

  15. Effects of Watering and Nitrogen Fertilization on Yield and Water and Nitrogen Use Efficiency of Cropping Oil Sunflower

    Directory of Open Access Journals (Sweden)

    TAN Jian-xin

    2015-10-01

    Full Text Available The field experiment with split-plot design was conducted to study the effects of the interaction of water and nitrogen fertilization on the growth and yield of oil sunflower, water and nitrogen use efficiency of cropping oil sunflower. This experiment set three irrigation rate treatments, including high irrigation treatment (5 250 m3·hm-2, middle irrigation treatment (3 750 m3·hm-2, low irrigation treatment (2 250 m3·hm-2, and four nitrogen application rate treatments, covering no nitrogen fertilization treatment (0 kg·hm-2, low nitrogen application treatment (120 kg·hm-2, middle nitrogen application treatment (240 kg·hm-2 and high nitrogen application treatment (360 kg·hm-2. The results showed that the nitrogen absorption and nitrogen use efficiency of cropping oil sunflower increased as the irrigation rate increased. With the nitrogen application rate increased, the yield of cropping oil sunflower was increased when the nitrogen application rate was 0~240 kg·hm-2, but beyond the 240 kg·hm-2, there was no significant increase. With the irrigation rate increased, the water consumption amount of cropping oil sunflower increased all the time, but the water use efficiency increased first, and hen decreased. Besides there was no significant difference between 240 kg·hm-2 and 360 kg·hm-2 treatment. Under our experiment condition, during the cropping oil sunflower growth period, when the irrigation rate was 5 250 m3·hm-2 (high irrigation rate and the nitrogen ertilization was 360 m3·hm-2 (high nitrogen application rate, the yield of cropping oil sunflower was 3 598 kg·hm-2. When the irrigation rate was 3 750 m3·hm-2 (middle irrigation rate and the nitrogen fertilization was 240 m3·hm-2 (middle nitrogen application rate, the yield was 3 518 kg·hm-2, with the yield components similar with the high irrigation rate and high nitrogen application rate treatment. Considering various factors, middle irrigation rate and middle nitrogen

  16. Oil field waste disposal in salt caverns: An information website

    Energy Technology Data Exchange (ETDEWEB)

    Tomasko, D.; Veil, J. A.

    1999-12-10

    Argonne National Laboratory has completed the construction of a Website for the US Department of Energy (DOE) that provides detailed information on salt caverns and their use for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM). Specific topics in the Website include the following: descriptions of salt deposits and salt caverns within the US, salt cavern construction methods, potential types of wastes, waste emplacement, regulatory issues, costs, carcinogenic and noncarcinogenic human health risks associated with postulated cavern release scenarios, new information on cavern disposal (e.g., upcoming meetings, regulatory issues, etc.), other studies supported by the National Petroleum Technology Office (NPTO) (e.g., considerations of site location, cavern stability, development issues, and bedded salt characterization in the Midland Basin), and links to other associated Web sites. In addition, the Website allows downloadable access to reports prepared on the topic that were funded by DOE. Because of the large quantities of NOW and NORM wastes generated annually by the oil industry, information presented on this Website is particularly interesting and valuable to project managers, regulators, and concerned citizens.

  17. Detection of Virgin Olive Oil Adulteration Using Low Field Unilateral NMR

    Directory of Open Access Journals (Sweden)

    Zheng Xu

    2014-01-01

    Full Text Available The detection of adulteration in edible oils is a concern in the food industry, especially for the higher priced virgin olive oils. This article presents a low field unilateral nuclear magnetic resonance (NMR method for the detection of the adulteration of virgin olive oil that can be performed through sealed bottles providing a non-destructive screening technique. Adulterations of an extra virgin olive oil with different percentages of sunflower oil and red palm oil were measured with a commercial unilateral instrument, the profile NMR-Mouse. The NMR signal was processed using a 2-dimensional Inverse Laplace transformation to analyze the transverse relaxation and self-diffusion behaviors of different oils. The obtained results demonstrated the feasibility of detecting adulterations of olive oil with percentages of at least 10% of sunflower and red palm oils.

  18. Study of Plasma Treatment of Produced Water from Oil and Gas Exploration

    Science.gov (United States)

    Wright, Kamau

    mg/L of bicarbonate ions. Water with bicarbonate ion concentration approaching zero resulted in prevention of scale. To enhance this new plasma induced fouling mitigation method, a plasma arc-in-water reactor was re-engineered, using a ground electrode, and two high-voltage electrodes, to stretch the arc discharge in water and increase contact between plasma and water. Results of simultaneous effects were also collected, showing within 5 min, a 4-log reduction in both Sulfate Reducing Bacteria (SRB) and Acid Producing Bacteria (APB), bacteria that are characteristic of oil-field produced waters; as well as oxidation of organics, with degradation of visually observable organics within 3 minutes, and decrease of oil and grease from 40 mg/L to under 10 mg/L within one min. With an arc-in-water system utilizing a stretched arc, simultaneous effects were exhibited on fouling ability of produced water, inactivation of bacteria, and degradation of organics. Plasma discharges in water represent a unique option in the treatment of produced waters from oil and gas production. While the water softening capabilities of arc-in-water systems present a new method for fouling mitigation and remediation of scale in heat exchangers, the simultaneous effects, including oxidation of organics and inactivation of bacteria, may allow application of plasma to water, to satisfy treatment targets that allow for the reuse of such waters in oil and gas operations.

  19. Rock mechanics related to Jurassic underburden at Valdemar oil field

    DEFF Research Database (Denmark)

    Foged, Niels

    1999-01-01

    .It has been initiated as a feasibility study of the North Jens-1 core 12 taken in the top Jurassic clay shale as a test specimens for integrated petrological, mineralogical and rock mechanical studies. Following topics are studied:(1) Pore pressure generation due to conversion of organic matter...... and deformation properties of the clay shale using the actual core material or outcrop equivalents.(3) Flushing mechanisms for oil and gas from source rocks due to possibly very high pore water pressure creating unstable conditions in deeply burried sedimentsThere seems to be a need for integrating the knowledge...... in a number of geosciences to the benefit of common understanding of important reservoir mechanisms. Rock mechanics and geotechnical modelling might be key points for this understanding of reservoir geology and these may constitute a platform for future research in the maturing and migration from the Jurassic...

  20. Role of interfacial rheological properties in oil field chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Lakatos-Szabo, J.; Lakatos, I.; Kosztin, B.

    1996-12-31

    Interfacial rheological properties of different Hungarian crude oil/water systems were determined in wide temperature and shear rate range and in presence of inorganic electrolytes, tensides, alkaline materials and polymers. The detailed laboratory study definitely proved that the interfacial rheological properties are extremely sensitive parameters towards the chemical composition of inmiscible formation liquids. Comparison and interpretation of the interfacial rheological properties may contribute significantly to extension of the weaponry of the reservoir characterization, better understanding of the displacement mechanism, development of the more profitable EOR/IOR methods, intensification of the surface technologies, optimization of the pipeline transportation and improvement of the refinery operations. It was evidenced that the interfacial rheology is an efficient and powerful detection technique, which may enhance the knowledge on formation, structure, properties and behaviour of interfacial layers. 17 refs., 18 figs., 2 tabs.

  1. Elastomers in mud motors for oil field applications

    Energy Technology Data Exchange (ETDEWEB)

    Hendrik, J. [Baker Hughes INTEQ GmbH, Celle (Germany)

    1997-08-01

    Mud motors, the most frequently used downhole drilling motors in modern drilling systems, are described in their application and function. The elastomeric liner in a mud motor acts as a huge continuous seal. Important properties of elastomers such as chemical resistance, fatigue resistance, mechanical strength, abrasion resistance, bonding to steel and processability are discussed. Advantages and disadvantages of NBR, HNBR, FKM, TFEP, and EPDM elastomers for mud motor applications are briefly described. The importance of drilling fluids and their physical and chemical impact on motor elastomers are described. Drilling fluids are categorized in: oil based-, synthetic-, and water based. Results of compatibility tests in the different drilling muds of the presented categories demonstrate the complexity of elastomer development. Elastomers with an equally good performance in all drilling muds are not available. Future developments and improvements are directed towards higher chemical resistance at higher service temperatures. This will be possible only with improved elastomer-to-metal bonding, increased mechanical and better dynamic properties.

  2. Nonlinear analysis of gas-water/oil-water two-phase flow in complex networks

    CERN Document Server

    Gao, Zhong-Ke; Wang, Wen-Xu

    2014-01-01

    Understanding the dynamics of multi-phase flows has been a challenge in the fields of nonlinear dynamics and fluid mechanics. This chapter reviews our work on two-phase flow dynamics in combination with complex network theory. We systematically carried out gas-water/oil-water two-phase flow experiments for measuring the time series of flow signals which is studied in terms of the mapping from time series to complex networks. Three network mapping methods were proposed for the analysis and identification of flow patterns, i.e. Flow Pattern Complex Network (FPCN), Fluid Dynamic Complex Network (FDCN) and Fluid Structure Complex Network (FSCN). Through detecting the community structure of FPCN based on K-means clustering, distinct flow patterns can be successfully distinguished and identified. A number of FDCN’s under different flow conditions were constructed in order to reveal the dynamical characteristics of two-phase flows. The FDCNs exhibit universal power-law degree distributions. The power-law exponent ...

  3. Characteristics of Abnormal Pressure Systems and Their Responses of Fluid in Huatugou Oil Field, Qaidam Basin

    Institute of Scientific and Technical Information of China (English)

    CHEN Xiaozhi; XU Hao; TANG Dazhen; ZHANG Junfeng; HU Xiaolan; TAO Shu; CAI Yidong

    2009-01-01

    Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are discussed. The correlation between the pressure systems and hydrocarbon accumulation is addressed by analyzing the corresponding fluid characteristics. The results show that the Huatugou oil field as a whole has low formation pressure and low fluid energy; therefore, the hydrocarbons are hard to migrate, which facilitates the forming of primary reservoirs. The study reservoirs, located at the Xiayoushashan Formation (N_2~1) and the Shangganchaigou Formation (N_1) are relatively shallow and have medium porosity and low permeability. They are abnormal low-pressure reservoirs with an average formation pressure coefficient of 0.61 and 0.72 respectively. According to the pressure coefficient and geothermal anomaly, the N_1 and N_2~1 Formations belong to two independent temperature-pressure systems, and the former has slightly higher energy. The low-pressure compartments consist of a distal bar as the main body, prodeita mud as the top boundary, and shore and shallow lake mud or algal mound as the bottom boundary. They are vertically overlapped and horizontally paralleled. The formation water is abundant in the Cl~- ion and can be categorized as CaCl_2 type with high salinity, which indicates that the abnormal low-pressure compartments are in good sealing condition and beneficial for oil and gas accumulation and preservation.

  4. Simulations of a dielectrophoretic membrane filtration process for removal of water droplets from water-in-oil emulsions.

    Science.gov (United States)

    Molla, Shahnawaz H; Masliyah, Jacob H; Bhattacharjee, Subir

    2005-07-01

    A novel separation technique based on simultaneous application of AC dielectrophoresis and preferential transport through a semipermeable hydrophilic membrane is proposed for separation of small amounts of emulsified water droplets from a water-in-oil emulsion. Embedding an array of parallel microelectrodes on a membrane matrix, followed by application of an AC potential to these electrodes, can result in capturing the water droplets onto the membranes from the emulsion during a crossflow filtration process. The present paper describes the theoretical principles underlying such a process, and describes a simple mathematical framework based on trajectory analysis for assessing the separation efficiency of such a technique. The results indicate that superimposition of an AC dielectrophoretic field can significantly enhance the preferential transport of the emulsified water through the membrane in a crossflow filtration device. This can lead to a highly efficient continuous separation process for dilute emulsions.

  5. Determination of optimal parameters of purification water surface from oil and oil products by sorbent on the basis of worn automobile tires

    OpenAIRE

    YUSUBOV FAXRADDIN VALI; SHIXALIYEV КARAM SEYFI; ABDULLAYEVA МAYA YADIGAR

    2016-01-01

    The article describes an identification of optimal parameters for surface water purification from oil and oil products by sorbent based on worn automotive tires. In thus Optimal parameters for water surface purification from oil and oil products by sorbent have been found out on the basis of constructed regression model of the process.

  6. Analysis of the heavy oil production technology effectiveness using natural thermal convection with heat agent recirculation method in reservoirs with varying initial water saturation

    Science.gov (United States)

    Osnos, V. B.; Kuneevsky, V. V.; Larionov, V. M.; Saifullin, E. R.; Gainetdinov, A. V.; Vankov, Yu V.; Larionova, I. V.

    2017-01-01

    The method of natural thermal convection with heat agent recirculation (NTC HAR) in oil reservoirs is described. The analysis of the effectiveness of this method for oil reservoir heating with the values of water saturation from 0 to 0.5 units is conducted. As the test element Ashalchinskoye oil field is taken. CMG STARS software was used for calculations. Dynamics of cumulative production, recovery factor and specific energy consumption per 1 m3 of crude oil produced in the application of the heat exchanger with heat agent in cases of different initial water saturation are defined and presented as graphs.

  7. Versatile fabrication of magnetic carbon fiber aerogel applied for bidirectional oil-water separation

    Science.gov (United States)

    Li, Yong; Zhu, Xiaotao; Ge, Bo; Men, Xuehu; Li, Peilong; Zhang, Zhaozhu

    2015-09-01

    Fabricating functional materials that can solve environmental problems resulting from oil or organic solvent pollution is highly desired. However, expensive materials or complicated procedures and unidirectional oil-water separation hamper their applications. Herein, a magnetic superhydrophobic carbon fiber aerogel with high absorption capacity was developed by one-step pyrolysis of Fe(NO3)3-coated cotton in an argon atmosphere. The obtained aerogel can selectively collect oils from oil-polluted region by a magnet bar owing to its magnetic properties and achieves fast oil-water separation for its superhydrophobicity and superoleophilicity. Furthermore, the aerogel performs recyclable oil absorption capacity even after ten cycles of oil-water separation and bears organic solvent immersion. Importantly, the obtained aerogel turns to superhydrophilic and underwater superoleophobic after thermal treatment, allowing it as a promising and efficient material for bidirectional oil-water separation and organic contaminants removal.

  8. Oil slicks on water surface: Breakup, coalescence, and droplet formation under breaking waves.

    Science.gov (United States)

    Nissanka, Indrajith D; Yapa, Poojitha D

    2017-01-15

    The ability to calculate the oil droplet size distribution (DSD) and its dynamic behavior in the water column is important in oil spill modeling. Breaking waves disperse oil from a surface slick into the water column as droplets of varying sizes. Oil droplets undergo further breakup and coalescence in the water column due to the turbulence. Available models simulate oil DSD based on empirical/equilibrium equations. However, the oil DSD evolution due to subsequent droplet breakup and coalescence in the water column can be best represented by a dynamic population model. This paper develops a phenomenological model to calculate the oil DSD in wave breaking conditions and ocean turbulence and is based on droplet breakup and coalescence. Its results are compared with data from laboratory experiments that include different oil types, different weathering times, and different breaking wave heights. The model comparisons showed a good agreement with experimental data.

  9. Local and Global Impacts of Carbon Capture and Storage Combined with Enhanced Oil Recovery in Four Depleted Oil Fields, Kern County, California

    Science.gov (United States)

    Gillespie, J.; Jordan, P. D.; Goodell, J. A.; Harrington, K.; Jameson, S.

    2015-12-01

    Depleted oil reservoirs are attractive targets for geologic carbon storage (GCS) because they possess proven trapping mechanisms and large amounts of data pertaining to production and reservoir geometry. In addition, CO2 enhanced oil recovery (EOR) can improve recovery of the remaining oil at recovery factors of 6 to 20% of original oil in place in appropriate reservoirs. CO2 EOR increases the attractiveness of depleted oil and gas reservoirs as a starting point for CCS because the CO2 becomes a commodity that can be purchased by field operators for EOR purposes thereby offsetting the costs of CO2 capture at the power plant. In California, Kern County contains the largest oil reservoirs and produces 76% of California's oil. Most of the production at depths suitable for CCS combined with CO2 EOR comes from three reservoirs: the Vedder and Temblor formations and the Stevens Sandstone of the Monterey Formation. These formations were evaluated for GCS and CO2 EOR potential at the North and South Coles Levee (Stevens Sandstone), Greeley (Vedder) and McKittrick (Temblor) fields. CO2 EOR could be expected to produce an additional 150 million bbls of oil. The total storage space created by pre- and post-EOR fluid production for all three reservoirs is approximately 104 million metric tons (MMT). Large fixed sources in California produce 156 MMT/yr of CO2, and sources in Kern County produce 26 MMT/yr (WESTCARB, 2012). Therefore, the fields could store about four years of local large fixed source emissions and about two thirds of statewide emissions. However, from a global perspective, burning the additional oil produced by CO2 EOR would generate an additional 65 MMT of CO2 if not captured. This would result in a net reduction of greenhouse gas of only 39 MMT rather than the full 104 MMT. If the water produced along with the oil recovered during CO2 EOR operations is not reinjected into the reservoir, the storage space could be much higher.

  10. Geometric Seismic Attributes of Boca de Jaruco Oil Field

    Directory of Open Access Journals (Sweden)

    Yamicela Tamayo López

    2013-06-01

    Full Text Available This paper focuses in determining the Geometric Seismic Attributes in the central block of Mouth ofJaruco oil field to decrease the uncertainty in the structural design. The three dimensions seismic datacollected and depth migration processing results were used and was defined that the surface isassociated to the main reserve. A Geometric Attributes maps elaboration (Azimuth, Dip, Curvature andRoughness work flow was developed; and was able to determine structural elements, where traditionalseismic data were not always able to demonstrate a confinable image of the geological structure. Thisstructure includes three structures between 1122 and 1200 m in depth. The Azimuth Attribute differentiatesthe southern flank from the northern flank; and defined accurately the top of the structure. The DipAttribute indicates values of layers inclination between 5 and 30º, the structure top with lowers valuesand the flanks with higher values, mainly to the south. Curvature and Roughness attributes reveal theareas of faults or channels.

  11. Calculation of oil production performance of the large giant oil fields in the world: based upon oil fields depletion model; Yuden gentai model ni yoru sekai no ogata kyodai yuden no seisan kyodo ni kansuru ichishisan

    Energy Technology Data Exchange (ETDEWEB)

    Nomoto, S. [Japan Oil Development Co. Ltd., Tokyo (Japan); Fujita, K. [The University of Tokyo, Tokyo (Japan)

    1997-05-01

    Data for large giant oil fields with minable reserves of one billion barrels or more were accumulated to structure a new oil field depletion model and estimate production in each oil field. As a result of analyzing events recognized in large giant oil fields, necessity was made clear to correct the conventional oil depletion model. The newly proposed model changes definitions on the depletion period of time, depletion rate, build-up production (during a time period in which production rate increases) and production in a plateau (a time period in which production becomes constant). Two hundred and twenty-five large giant oil fields were classified into those in a depletion period, an initial development phase, and a plateau period. The following findings were obtained as a result of trial calculations using the new model: under an assumption of demand growth rate of 1.5%, oil field groups in the initial development phase will reach the plateau production in the year 2002, and oil fields in the depletion period will continue production decline, hence the production amount after that year will slow down. Because the oil field groups in the plateau period will shift into decline in 2014, the overall production will decrease. The year 2014 is about ten years later than the estimation given recently by Campbell. Undiscovered resources are outside these discussions. 11 refs., 9 figs., 2 tabs.

  12. Water-oil drainage dynamics in oil-wet random microfluidic porous media analogs

    CERN Document Server

    Xu, Wei; Neeves, Keith; Yin, Xiaolong

    2012-01-01

    Displacement experiments carried out in microfluidic porous media analogs show that reduced surface tension leads to a more stable displacement, opposite to the process in Hele-Shaw cells where surface tension stabilizes the displacement of a more viscous fluid by a less viscous fluid. In addition, geometry of porous media is observed to play an important role. Three random microfluidic porous media analogs were made to study water-oil drainage dynamics, featuring a pattern of randomly connected channels with a uniform width, a pattern with Gaussian channel width distribution, and a pattern with large isolated pores. The microfluidic chips fabricated using Polydimenthylsiloxane with glass covers have the internal surface treated by Trichlorosilane to achieve a uniform oil-wet condition. The aqueous phase displaces the oil phase, with a viscosity ratio of about 1:40 and a density ratio of 1:0.85. Videos 1-3 show water flooding processes. It is observed that both channel size distribution (Video 2) and heteroge...

  13. Novel Parallelized Electroporation by Electrostatic Manipulation of a Water-in-Oil Droplet as a Microreactor.

    Directory of Open Access Journals (Sweden)

    Hirofumi Kurita

    Full Text Available Electroporation is the most widely used transfection method for delivery of cell-impermeable molecules into cells. We developed a novel gene transfection method, water-in-oil (W/O droplet electroporation, using dielectric oil and an aqueous droplet containing mammalian cells and transgene DNA. When a liquid droplet suspended between a pair of electrodes in dielectric oil is exposed to a DC electric field, the droplet moves between the pair of electrodes periodically and droplet deformation occurs under the intense DC electric field. During electrostatic manipulation of the droplet, the local intense electric field and instantaneous short circuit via the droplet due to droplet deformation facilitate gene transfection. This method has several advantages over conventional transfection techniques, including co-transfection of multiple transgene DNAs into even as few as 103 cells, transfection into differentiated neural cells, and the capable establishment of stable cell lines. In addition, there have been improvements in W/O droplet electroporation electrodes for disposable 96-well plates making them suitable for concurrent performance without thermal loading by a DC electric field. This technique will lead to the development of cell transfection methods for novel regenerative medicine and gene therapy.

  14. An Experimental Study of Oil / Water Flow in Horizontal Pipes

    Energy Technology Data Exchange (ETDEWEB)

    Elseth, Geir

    2001-07-01

    The purpose of this thesis is to study the behaviour of the simultaneous flow of oil and water in horizontal pipes. In this connection, two test facilities are used. Both facilities have horizontal test sections with inner pipe diameters equal to 2 inches. The largest facility, called the model oil facility, has reservoirs of 1 m{sub 3} of each medium enabling flow rates as high as 30 m{sub 3}/h, which corresponds to mixture velocities as high as 3.35 m/s. The flow rates of oil and water can be varied individually producing different flow patterns according to variations in mixture velocity and input water cut. Two main classes of flows are seen, stratified and dispersed. In this facility, the main focus has been on stratified flows. Pressure drops and local phase fractions are measured for a large number of flow conditions. Among the instruments used are differential pressure transmitters and a traversing gamma densitometer, respectively. The flow patterns that appear are classified in flow pattern maps as functions of either mixture velocity and water cut or superficial velocities. From these experiments a smaller number of stratified flows are selected for studies of velocity and turbulence. A laser Doppler anemometer (LDA) is applied for these measurements in a transparent part of the test section. To be able to produce accurate measurements a partial refractive index matching procedure is used. The other facility, called the matched refractive index facility, has a 0.2 m{sub 3} reservoir enabling mainly dispersed flows. Mixture velocities range from 0.75 m/s to 3 m/s. The fluids in this facility are carefully selected to match the refractive index of the transparent part of the test section. A full refractive index matching procedure is carried out producing excellent optical conditions for velocity and turbulence studies by LDA. In addition, pressure drops and local phase fractions are measured. (author)

  15. Investigating New Innovations to Detect Small Salt-Water Fraction Component in Mineral Oil and Small Oil Fraction Component in Salt-Water Projects

    Directory of Open Access Journals (Sweden)

    E.R.R. Mucunguzi-Rugwebe

    2011-09-01

    Full Text Available The main purpose of this study is to present the key findings on the effects of small salt-water fraction component, β expressed in volume % per L on rotation are presented in the temperature range of 19.0 to 24.0ºC. It was found that rotations in oils with low boiling point known as light oils like Final diesel No. 2 were greater than the rotations which occurred in oils with high boiling point called heavy oils such as Esso diesel. Small oil fraction components, γs expressed in mL/L of salt water down to 10 ppm were detected. The greatest impact on rotation of these oils was found in light oils like Fina No. 2 diesel. At 40 ppm which is the oil content level below which the environment authority considers process water to be free from oil environmental hazards, the observed rotation angles were 23.2º for Esso, 36.7º for Nors Hydro AS, and 71.8º in Fina No. 2 diesel. It was observed that light oils molecules have drastic effect on optical properties of the mixture in which they exist. It was found that for all oils, oil fractions greater than 100 ppm, caused the medium to be optically dense. This technology has shown a very high potential of being used as an environmental monitor to detect oil fractions down to 10 ppm and the technique can use laser beam to control re-injected process water with oil fractions between 100-2000 ppm.

  16. An effective method to predict oil recovery in high water cut stage

    Institute of Scientific and Technical Information of China (English)

    刘志斌; 刘浩翰

    2015-01-01

    The water flooding characteristic curve method based on the traditional regression equation between the oil and water phase permeability ratio and the water saturation is inappropriate to predict the oil recovery in the high water cut stage. Hence, a new water flooding characteristic curve equation adapted to the high water cut stage is proposed to predict the oil recovery. The water drive phase permeability experiments show that the curve of the oil and water phase permeability ratio vs. the water saturation, in the semi-logarithmic coordinates, has a significantly lower bend after entering the high water cut stage, so the water flooding characteristic curve method based on the traditional regression equation between the oil and water phase permeability ratio and the water saturation is inappropriate to predict the oil recovery in the high water cut stage; therefore, a new water flooding characteristic curve equation based on a better relationship betweenln(kro/krw)andwS is urgently desirable to be established to effectively and reliably predict the oil recovery of a water drive reservoir adapted to a high water cut stage. In this paper, by carrying out the water drive phase permeability experiments, a new mathematical model between the oil and water phase permeability ratio and the water saturation is established,with the regression analysis method and an integration of the established model, the water flooding characteristic curve equation adapted to a high water cut stage is obtained. Using the new water flooding characteristic curve to predict the oil recovery of the GD3-block of the SL oilfield and the J09-block of the DG oilfield in China, results with high predicted accuracy are obtained.

  17. Changqing Becomes China's Second Largest Oil and Gas Field

    Institute of Scientific and Technical Information of China (English)

    Peng Xufeng

    2010-01-01

    @@ Realizing great-leap-forward growth of oil and gas reserves,production Changqing Oilfield has created miracles from rapid growth to great-leap-forward development when China's oil and gas output increased slowly.

  18. The influence on response of axial rotation of a six-group local-conductance probe in horizontal oil-water two-phase flow

    Science.gov (United States)

    Weihang, Kong; Lingfu, Kong; Lei, Li; Xingbin, Liu; Tao, Cui

    2017-06-01

    Water volume fraction is an important parameter of two-phase flow measurement, and it is an urgent task for accurate measurement in horizontal oil field development and optimization of oil production. The previous ring-shaped conductance water-cut meter cannot obtain the response values corresponding to the oil field water conductivity for oil-water two-phase flow in horizontal oil-producing wells characterized by low yield liquid, low velocity and high water cut. Hence, an inserted axisymmetric array structure sensor, i.e. a six-group local-conductance probe (SGLCP), is proposed in this paper. Firstly, the electric field distributions generated by the exciting electrodes of SGLCP are investigated by the finite element method (FEM), and the spatial sensitivity distributions of SGLCP are analyzed from the aspect of different separations between two electrodes and different axial rotation angles respectively. Secondly, the numerical simulation responses of SGLCP in horizontal segregated flow are calculated from the aspect of different water cut and heights of the water layer, respectively. Lastly, an SGLCP-based well logging instrument was developed, and experiments were carried out in a horizontal pipe with an inner diameter of 125 mm on the industrial-scale experimental multiphase flow setup in the Daqing Oilfield, China. In the experiments, the different oil-water two-phase flow, mineralization degree, temperature and pressure were tested. The results obtained from the simulation experiments and simulation well experiments demonstrate that the designed and developed SGLCP-based instrument still has a good response characteristic for measuring water conductivity under the different conditions mentioned above. The validity and reliability of obtaining the response values corresponding to the water conductivity through the designed and developed SGLCP-based instrument are verified by the experimental results. The significance of this work can provide an effective

  19. Characteristics of remaining oil viscosity in water-and polymer-flooding reservoirs in Daqing Oilfield

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The experimental analysis of 21 crude oil samples shows a good correlation between high molecular-weight hydrocarbon components (C 40+) and viscosity.Forty-four remaining oil samples extracted from oil sands of oilfield development coring wells were analyzed by high-temperature gas chromatography (HTGC),for the relative abundance of C 21-,C 21-C 40 and C 40+ hydrocarbons.The relationship between viscosity of crude oil and C 40+ (%) hydrocarbons abundance is used to expect the viscosity of remaining oil.The mobility characteristics of remaining oil,the properties of remaining oil,and the next displacement methods in reservoirs either water-flooded or polymer-flooded are studied with rock permeability,oil saturation of coring wells,etc.The experimental results show that the hydrocarbons composition,viscosity,and mobility of remaining oil from both polymer-flooding and water-flooding reservoirs are heterogeneous,especially the former.Relative abundance of C 21- and C 21-C 40 hydrocarbons in polymer-flooding reservoirs is lower than that of water-flooding,but with more abundance of C 40+ hydrocarbons.It is then suggested that polymer flooding must have driven more C 40- hydrocarbons out of reservoir,which resulted in relatively enriched C 40+,more viscous oils,and poorer mobility.Remaining oil in water-flooding reservoirs is dominated by moderate viscosity oil with some low viscosity oil,while polymer-flooding mainly contained moderate viscosity oil with some high viscosity oil.In each oilfield and reservoir,displacement methods of remaining oil,viscosity,and concentration by polymer-solution can be adjusted by current viscosity of remaining oil and mobility ratio in a favorable range.A new basis and methods are suggested for the further development and enhanced oil recovery of remaining oil.

  20. 高含水层段堵水技术--以高升油田高246块底水油藏为例%WATER SHUT TECHNOLOGY OF HIGH WATER BEARING SECTION ILLUSTRATED BY NO.246 BOTTOM WATER RESERVOIR OF GAOSHENG OIL FIELD

    Institute of Scientific and Technical Information of China (English)

    李鼎一

    2015-01-01

    The paper confirm the stepping water shut technology of high water reservoir section according to the research on waterexit features of No.246 lateral well, accompany with the deposit section and oil property, waterexit quality and section as well as the production conditons. The shutting materials and afflux technics are the most important process for water shutting technology.The liquid bridge plug with chemical airproof materials and abio-agent are successfully used in the shutting examination. Water shutting manner and agent dosage are confirmed durling well logging explain and liquid profile test.%通过对高246块水平井出水特点的研究,结合水平井储层物性、原油性质、出水水质、出水井段及生产情况,确定了高含水层段分段堵水工艺。堵水的关键技术是封堵材料和注入工艺。根据现有的堵水材料,进行筛选、复配和改性,试验成功了液体桥塞、化学封隔材料和无机堵水剂。利用测井解释和产液剖面测试结果,制定了堵水方式和堵剂的用量。并成功应用于现场,取得了明显的增油效果。

  1. Oil and Water Don't Mix: The Gulf Coast Oil Disaster as a Preschool Social Studies Lesson

    Science.gov (United States)

    Kruse, Tricia

    2010-01-01

    On April 20, 2010, an offshore oil-drilling platform exploded, spilling millions of gallons of oil into the gulf. From Louisiana to the Gulf Coast of Florida the effects are being felt by fisherman, shrimpers, dive charters, and other hardworking folks who depend on the water for their livelihood. But there is another population in these coastal…

  2. Oil and Water Don't Mix: The Gulf Coast Oil Disaster as a Preschool Social Studies Lesson

    Science.gov (United States)

    Kruse, Tricia

    2010-01-01

    On April 20, 2010, an offshore oil-drilling platform exploded, spilling millions of gallons of oil into the gulf. From Louisiana to the Gulf Coast of Florida the effects are being felt by fisherman, shrimpers, dive charters, and other hardworking folks who depend on the water for their livelihood. But there is another population in these coastal…

  3. Effect of Addition of Cosurfactant on the Phase Behaviour of Oil-in-water Aminosilicone Oil Microemulsion

    Institute of Scientific and Technical Information of China (English)

    Zheng Hong LUO; Xiao Li ZHAN; Peng Yong YU

    2004-01-01

    Stable and transparent aminosilicone oil microemulsion of the average particle size below 0.05 micron was prepared. The interaction of the aminosilicone oil, water, complex surfactants and cosurfactant was studied by part pseudoternary phase diagram. The effect of cosurfactants (such as alcohol) and the mechanism of its effect on the phase behaviour of the pseudoternary system were investigated.

  4. Antioxidant Activity of Potato Peel Extracts in a Fish-RapeseedOil Mixture and in Oil-in-Water Emulsions

    DEFF Research Database (Denmark)

    Farvin, Sabeena; Nielsen, Nina Skall; Jacobsen, Charlotte

    2010-01-01

    oil mixture and oil-in-water emulsions. Multiple antioxidant activity of the potato peel extracts was evident from in-vitro systems as they showed strong reducing power, radical scavenging ability, ferrous ion chelating activity and prevented oxidation in a liposome model system. The Sava variety...

  5. 利用反硝化技术解决油田水处理系统中硫化物问题的技术实践%Solving the problem of sulfide in oil field water treatment system by denitrification technology

    Institute of Scientific and Technical Information of China (English)

    陈忠喜; 冯英明

    2011-01-01

    In order to solve the problem resulting from the sulfide existing in oil field water treatment system, a kind of denitrification inhibitor which can not only remove the sulfide effectively, but also inhibit the activity of sulfate-reducing bacteria(SRB) was developed based on the microbiological research. The result of the field test showed that, when the inhibitor dosage was 85 mg/L, the sulfide content in oil system sedimentation tank could be reduced to an undetectable level; the oil removal rate could be increased by 32.7%, and thus the practical problems such as poor sedimentation effect of sedimentation tank and deterioration of influent water quality of wastewater treatment system were solved. It could be seen that, dosing inhibitor before the filtration could enhance the filtration efficiency, improve the influent water quality, and finally solve the problem of influent water quality exceeding the standard caused by serious pollution of filtration system.%为了解决油田水处理系统中硫化物给生产带来的实际问题,从微生物学角度开发了能够有效除硫控菌(SRB)的反硝化抑制剂.现场试验结果表明,抑制剂投加量为85 mg/L时,能够将油系统沉降罐中硫化物降至未检出水平,沉降罐的除油率提高32.7%,解决了现场沉降罐沉降效率差、废水系统来水水质恶化等实际问题;滤前投加抑制剂能够提高过滤效率,改善了注水水质,解决现场因过滤系统污染严重造成注水水质超标等实际问题.

  6. Argentina Hopes for A Big Payoff in Its Shale Oil Field Discovery

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    @@ Just east of Argentina's Andean foothills, an oil field called the Vaca Muerta, "dead cow" in English, has finally come to life.In May, the Argentine oil company YPF announced that it had found 150 million barrels of oil in the Patagonian field, and President Cristina Fernandez de Kirchner rushed onto national television to praise the discovery as something that could give new impetus to the country's long-stagnant economy.

  7. Lipid oxidation in fish oil enriched oil-in-water emulsions and cream cheese with pre-emulsified fish oil is affected differently by the emulsifier used

    DEFF Research Database (Denmark)

    Horn, Anna Frisenfeldt; Nielsen, Nina Skall; Andersen, Ulf

    will include results from studies on lipid oxidation in simple oil-in-water emulsions prepared with milk proteins alone or combinations of milk proteins and phospholipids. In addition, a study on fish oil enriched cream cheese will be presented. In this study, the cream cheese was enriched with either neat...... fish oil or a fish oil-in-water delivery emulsion prepared with whey protein isolate, sodium caseinate or a commercially available emulsifier that consisted of ~20% milk phospholipids and ~50% milk proteins. Results showed that simple emulsions prepared with a combination of milk proteins...... acids to foods invariably increases the risk of lipid oxidation. A possible strategy to avoid lipid oxidation and the consecutive development of unpleasant off-flavours is to protect the oil in a delivery emulsion in which the oil droplets are shielded from its possible pro-oxidative surroundings...

  8. Soil Water Balance Measurement in Field Scale

    Institute of Scientific and Technical Information of China (English)

    CHENZHI-XIONG

    1992-01-01

    A 5-year experiment on water balance has been conducted in a flat rainfed wheat field with an area of 66×100m2 in Fengqiu,Henan Province in China.Based on the analysis of semi-variance functions conducted with soil moisture samples taken from 77 nodes of a 10×10m2 grid,the soil moisture distribution in the field was structural with a temporal stability.According to the autocorrelation range of the semi-variance function,6 sites were selected for the determination of soil water conditions.The characteristic of probability density function of the differences of water storage in two sets of measurements showed that the distribution of these variables in the field was a normal one.The error in the estimation of the average of 5 random samples was 14% (α=0.10),and the errors of water consumption by wheat during the experiments were estimated to be 6-13%.Sime the experimental field was large enough to avoid any edge effect,the results obtained should tally with the actual situation.Yet the soil system was heterogeneous,so we must follow the principles of statistics and geostatistics when describing the system's status with the average of the samples.

  9. An efficient thermotolerant and halophilic biosurfactant-producing bacterium isolated from Dagang oil field for MEOR application

    Science.gov (United States)

    Wu, Langping; Richnow, Hans; Yao, Jun; Jain, Anil

    2014-05-01

    Dagang Oil field (Petro China Company Limited) is one of the most productive oil fields in China. In this study, 34 biosurfactant-producing strains were isolated and cultured from petroleum reservoir of Dagang oil field, using haemolytic assay and the qualitative oil-displacement test. On the basis of 16S rDNA analysis, the isolates were closely related to the species in genus Pseudomonas, Staphylococcus and Bacillus. One of the isolates identified as Bacillus subtilis BS2 were selected for further study. This bacterium was able to produce a type of biosurfactant with excessive foam-forming properties at 37ºC as well as at higher temperature of 55ºC. The biosurfactant produced by the strain BS2 could reduce the surface tension of the culture broth from 70.87 mN/m to 28.97 mN/m after 8 days of incubation at 37ºC and to 36.15 mN/m after 20 days of incubation at 55ºC, respectively. The biosurfactant showed stability at high temperature (up to 120ºC), a wide range of pH (2 to 12) and salt concentrations (up to 12%) offering potential for biotechnology. Fourier transform infrared (FT-IR) spectrum of extracted biosurfactant tentatively characterized the produced biosurfactant as glycolipid derivative. Elemental analysis of the biosurfactant by energy dispersive X-ray spectroscopy (EDS) reveals that the biosurfactant was anionic in nature. 15 days of biodegradation of crude oil suggested a preferential usage of n-alkane upon microbial metabolism of BS2 as a carbon substrate and consequently also for the synthesis of biosurfactants. Core flood studies for oil release indicated 9.6% of additional oil recovery over water flooding at 37ºC and 7.2% of additional oil recovery at 55 ºC. Strain BS2 was characterized as an efficient biosurfactant-producing, thermotolerant and halophillic bacterium and has the potential for application for microbial enhanced oil recovery (MEOR) through water flooding in China's oil fields even in situ as adapted to reservoir chemistry and

  10. Enhanced Oil Recovery (EOR by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

    Directory of Open Access Journals (Sweden)

    Edwin A. Chukwudeme

    2009-09-01

    Full Text Available An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane, model oil (n-C10, SA, toluene and 0.35 wt % asphaltene and crude oil (10 wt % asphaltene obtained from the Middle East. Stearic acid (SA is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years it is shown that there is almost no difference between the recovered oils by water and CO2, after which (> 3 years oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO2 flooding of asphaltenic oil at combined temperatures and pressures of 50 °C/90 bar and 70 °C/120 bar (no significant difference between the two cases, about 1% compared to 80 °C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO2 flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure.

  11. Water-related Issues Affecting Conventional Oil and Gas Recovery and Potential Oil-Shale Development in the Uinta Basin, Utah

    Energy Technology Data Exchange (ETDEWEB)

    Berg, Michael Vanden; Anderson, Paul; Wallace, Janae; Morgan, Craig; Carney, Stephanie

    2012-04-30

    Saline water disposal is one of the most pressing issues with regard to increasing petroleum and natural gas production in the Uinta Basin of northeastern Utah. Conventional oil fields in the basin provide 69 percent of Utah?s total crude oil production and 71 percent of Utah?s total natural gas, the latter of which has increased 208% in the past 10 years. Along with hydrocarbons, wells in the Uinta Basin produce significant quantities of saline water ? nearly 4 million barrels of saline water per month in Uintah County and nearly 2 million barrels per month in Duchesne County. As hydrocarbon production increases, so does saline water production, creating an increased need for economic and environmentally responsible disposal plans. Current water disposal wells are near capacity, and permitting for new wells is being delayed because of a lack of technical data regarding potential disposal aquifers and questions concerning contamination of freshwater sources. Many companies are reluctantly resorting to evaporation ponds as a short-term solution, but these ponds have limited capacity, are prone to leakage, and pose potential risks to birds and other wildlife. Many Uinta Basin operators claim that oil and natural gas production cannot reach its full potential until a suitable, long-term saline water disposal solution is determined. The enclosed project was divided into three parts: 1) re-mapping the base of the moderately saline aquifer in the Uinta Basin, 2) creating a detailed geologic characterization of the Birds Nest aquifer, a potential reservoir for large-scale saline water disposal, and 3) collecting and analyzing water samples from the eastern Uinta Basin to establish baseline water quality. Part 1: Regulators currently stipulate that produced saline water must be disposed of into aquifers that already contain moderately saline water (water that averages at least 10,000 mg/L total dissolved solids). The UGS has re-mapped the moderately saline water boundary

  12. Coagulation-flocculation pretreatment of oil sands process affected water

    Energy Technology Data Exchange (ETDEWEB)

    Pourrezaei, P.; El-Din, M.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering

    2008-07-01

    This presentation addressed the issue of water use in the oil sands industry and efforts to use this limited resource more efficiently. Three wastewater treatment schemes for oil sands tailings ponds were proposed, notably primary, secondary and tertiary treatment. Primary treatment involves the removal of suspended solids using physical-chemical treatments. Secondary treatment involves the removal of dissolved solids and organics using chemical oxidation, ultrafiltration or nanofiltration. Tertiary treatment involves removal of residual organics/solids using biological activated carbon filtration, sand filtration or reverse osmosis. The composition of oil sands process water (OSPW) was also discussed with reference to suspended solids, salts, hydrocarbons, other dissolved organics (such as naphthenic acids and phenols), ammonia, inorganic compounds and trace elements. The conventional coagulation/flocculation process is essential in industrial wastewater treatment. It is cost effective, easy to operate and energy efficient. The process is used because small suspended and colloidal particles and dissolved constituents cannot be removed quickly by sedimentation. A chemical method must be used. Coagulation/flocculation brings small suspended and colloidal particles into contact so that they collide, stick and grow to a size that settles readily. Alum is the predominant and least expensive water treatment coagulant used for the coagulation/flocculation process. It provides positively charged ions to neutralize the negative charge of colloidal particles resulting in aggregation. It creates big settling flocs that enmesh colloids as it settles. The factors affecting the process include pH, chemical type, chemical concentration, rapid mixing intensity, slow mixing intensity and time. tabs., figs.

  13. A Field-Scale Simulation of the Reversible Nanoparticle Adsorption for Enhancing Oil Recovery Using Hydrophilic Nanofluids

    Science.gov (United States)

    Cao, Liyuan

    In order to develop and apply nanotechnology in oil industry, nanoparticles transport in porous media has been studied in the past few years. Theoretical modeling were carried out to evaluate nanoparticle mobility and investigate nanoparticle retention mechanism. In this study, a simulator based on Ju and Fan's mathematical model was used to study nanoparticles transport in porous media on a reservoir scale. The simulator was verified with two simulation software, Eclipse from Schlumberger and MNM1D (Micro- and Nanoparticle transport Model in porous media in 1D geometry) developed by Tosco et al. Different injection scenarios were simulated: continuous injection, slug injection, and postflush. The effect of injection time, injection rate, and slug size on oil recovery were studied. The result discovered that when nanofluids flooding is used after water flooding as tertiary recovery method, early nanofluids injection will lead to higher oil recovery, but with more nanoparticle loss. Higher injection rate of nanofluids could help improve the flooding efficiency, but not the ultimate oil recovery for field development. Also, it can cause more nanoparticle loss. Brine water postflush is recommended when doing nanoflooding. It can significantly improve the recovery of nanoparticles, and for a homogeneous or heterogeneous reservoir, oil recovery is better compared to water flooding.

  14. Environmental safety of underground injection of oil field brines in Louisiana

    Energy Technology Data Exchange (ETDEWEB)

    Conger, R.M.

    1986-09-01

    Louisiana contains almost 4000 brine injection wells that dispose an estimated 1 billion bbl of brine each year, making underground injection that state's most widely practiced method of oil field brine disposal. Louisiana has had no known contamination of a public water supply from underground brine injection; however, the magnitude of this activity presents a potential for contamination if proper disposal practices are not followed. Following the earliest discovery of oil, the petroleum industry has been improving methods to protect ground-water aquifers from underground injection. Although economic incentives spurred the earliest use of underground injection, the technology has progressed to become a method providing environmental safety to ground-water aquifers. Complex reservoir modeling, developed for use in secondary and enhanced recovery techniques, has been applied to simulate pressure effects and vertical migration potential for underground injection reservoirs. Conventional well designs that allow monitoring of well conditions have replaced older, unreliable designs. Improvements in wireline logging make it possible to test the isolation of injected brines from vertical movement along the well bore.

  15. Application of oil-field well log interpretation techniques to the Cerro Prieto Geothermal Field

    Energy Technology Data Exchange (ETDEWEB)

    Ershaghi, I.; Phillips, L.B.; Dougherty, E.L.; Handy, L.L.

    1979-10-01

    An example is presented of the application of oil-field techniques to the Cerro Prieto Field, Mexico. The lithology in this field (sand-shale lithology) is relatively similar to oil-field systems. The study was undertaken as a part of the first series of case studies supported by the Geothermal Log Interpretation Program (GLIP) of the US Department of Energy. The suites of logs for individual wells were far from complete. This was partly because of adverse borehole conditions but mostly because of unavailability of high-temperature tools. The most complete set of logs was a combination of Dual Induction Laterolog, Compensated Formation Density Gamma Ray, Compensated Neutron Log, and Saraband. Temperature data about the wells were sketchy, and the logs had been run under pre-cooled mud condition. A system of interpretation consisting of a combination of graphic and numerical studies was used to study the logs. From graphical studies, evidence of hydrothermal alteration may be established from the trend analysis of SP (self potential) and ILD (deep induction log). Furthermore, the cross plot techniques using data from density and neutron logs may help in establishing compaction as well as rock density profile with depth. In the numerical method, R/sub wa/ values from three different resistivity logs were computed and brought into agreement. From this approach, values of formation temperature and mud filtrate resistivity effective at the time of logging were established.

  16. IN-SITU STRESS FIELD AND GEOLOGICAL TECTONIC ANALYSIS AT HUANGDAO WATER-SEALED UNDERGROUND OIL CARVEN SITE%黄岛地下水封油库地应力场及地质构造作用分析

    Institute of Scientific and Technical Information of China (English)

    王章琼; 晏鄂川; 季惠斌

    2016-01-01

    初始地应力场对地下洞室围岩稳定性影响十分显著,但由于地质条件的复杂性,通过单一方法得到的地应力场可靠性不高.以黄岛地下水封洞库工程为例,分析了研究区区域地质构造背景及近场断裂构造;通过水压致裂法进行了地应力测试,得到最大主应力方向主要集中在 NWW 向,优势方向为N73°W;通过地质构造分析法分析了研究区地应力场,探讨了区域构造运动历史对研究区现今构造应力场的影响,认为最大主应力方向为 NW—NNW.构造分析法与水压致裂法所得最大主应力方向大致均为 NW,但存在一定偏差;主要原因可能是研究区地质构造复杂,受构造变形边界条件影响,派生的局部应力场发生偏转.这表明,在分析地应力场时应结合区域地质构造作用分析及实测地应力进行综合评价.研究结果对于地应力场的综合确定方法具有一定参考价值.%The initial in-situ stress field has significant influence on the stability of surrounding rock of underground carven.Nevertheless,the in-situ stress field result obtained by a single method is usually not of high reliability because of the complexity of geological conditions.This paper takes the Huangdao underground water-sealed cavern as example and analyzes its regional tectonic background and near-field faults.The in-situ stress field is tested by hydraulic fracturing method.The maximum principal stress is obtained.Its directions are is mainly oriented NWW.Its advantage direction is N73°W.The stress field of study area is analyzed by geological structure analysis method.The impact of regional tectonic history on present tectonic stress field of study area is discussed.It is found that the maximum principal stress direction is NW~NNW.The maximum principal stress directions obtained by construction analysis and hydraulic fracturing method are roughly NW.But there is a certain bias.The main reason is probably due to the

  17. Determining the oil-recovery coefficient for the developed part of the 4th gas-oil horizon in Anastasievsk-Troitskii field

    Energy Technology Data Exchange (ETDEWEB)

    Basin, Ya.N.; Konoplev, Yu.V.

    1971-01-01

    A special feature of the 4th gas-oil horizon is that it has a relatively small thickness (20 to 25 m), a huge gas cap (150 m thick), and an active bottom water drive. Production has to be regulated to prevent invasion of the oil zone by gas and water. In order to regulate production, geophysical methods were used to determine oil saturations. Position of the water-oil contact and of oil-gas contact were established with neutron gamma logs, neutron-neutron logs, and lateral logs. It was found that maximum displacement of oil by gas, and gas by oil occurred only near the initial gas-oil contact. The data indicated that about 72% of the oil in place is being recovered.

  18. Characterization and Alteration of Wettability States of Alaskan Reserviors to Improve Oil Recovery Efficiency (including the within-scope expansion based on Cyclic Water Injection - a pulsed waterflood for Enhanced Oil Recovery)

    Energy Technology Data Exchange (ETDEWEB)

    Abhijit Dandekar; Shirish Patil; Santanu Khataniar

    2008-12-31

    , cyclic water injection tests using high as well as low salinity were also conducted on several representative ANS core samples. These results indicate that less pore volume of water is required to recover the same amount of oil as compared with continuous water injection. Additionally, in cyclic water injection, oil is produced even during the idle time of water injection. It is understood that the injected brine front spreads/smears through the pores and displaces oil out uniformly rather than viscous fingering. The overall benefits of this project include increased oil production from existing Alaskan reservoirs. This conclusion is based on the performed experiments and results obtained on low-salinity water injection (including ANS lake water), vis-a-vis slightly altering the wetting conditions. Similarly, encouraging cyclic water-injection test results indicate that this method can help achieve residual oil saturation earlier than continuous water injection. If proved in field, this would be of great use, as more oil can be recovered through cyclic water injection for the same amount of water injected.

  19. Co-axial electrospun polystyrene/polyurethane fibres for oil collection from water surface

    Science.gov (United States)

    Lin, Jinyou; Tian, Feng; Shang, Yanwei; Wang, Fujun; Ding, Bin; Yu, Jianyong; Guo, Zhi

    2013-03-01

    The pollution arising from oil spills is a matter of great concern due to its damaging impacts on the ecological environment, which has created a tremendous need to find more efficient materials for oil spill cleanup. In this work, we reported a sorbent for oil soak-up from a water surface with a high sorption capacity, good selectivity, and excellent reusability based on the hydrophobic-oleophilic fibrous mats that were fabricated via co-axial electrospinning polystyrene (PS) solution as the shell solution and polyurethane (PU) solution as the core solution. The fine structures of as-prepared fibers were regulated by manipulating the spinning voltages, core solution concentrations, and solvent compositions in shell solutions, which were also characterized by field emission scanning electron microscopy, transmission electron microscopy, nitrogen adsorption method, and synchrotron radiation small-angle X-ray scattering. The effects of inter-fiber voids and intra-fiber porosity on oil sorption capacities were well studied. A comparison of oil sorption capacity for the single fiber with different porous structures was also investigated with the help of scanning transmission X-ray microscopy. The results showed that the sorption capacities of the as-prepared sorbent with regards to motor oil and sunflower seed oil can be 64.40 and 47.48 g g-1, respectively, approximately 2-3 times that of conventional polypropylene (PP) fibers for these two same oils. Even after five sorption cycles, a comparable oil sorption capacity with PP fibers was still maintained, exhibiting an excellent reusability. We believe that the composite PS-PU fibrous mats have a great potential application in wastewater treatment, oil accident remediation and environmental protection.The pollution arising from oil spills is a matter of great concern due to its damaging impacts on the ecological environment, which has created a tremendous need to find more efficient materials for oil spill cleanup. In

  20. Essentials of water systems design in the oil, gas, and chemical processing industries

    CERN Document Server

    Bahadori, Alireza; Boyd, Bill

    2013-01-01

    Essentials of Water Systems Design in the Oil, Gas and Chemical Processing Industries provides valuable insight for decision makers by outlining key technical considerations and requirements of four critical systems in industrial processing plants—water treatment systems, raw water and plant water systems, cooling water distribution and return systems, and fire water distribution and storage facilities. The authors identify the key technical issues and minimum requirements related to the process design and selection of various water supply systems used in the oil, gas, and chemical processing industries. This book is an ideal, multidisciplinary work for mechanical engineers, environmental scientists, and oil and gas process engineers.

  1. Contaminants, water quality, and wildlife mortality on oil production sites in western South Dakota. Interim report

    Energy Technology Data Exchange (ETDEWEB)

    Henry, C.J.; Ruelle, R.

    1993-04-01

    The objectives of the study were to evaluate oil pits and other hazards at oil production sites to (1) document the magnitude of wildlife mortality due to exposure to oil and other chemicals, (2) determine the physical and toxic effects of oil pit contents on wildlife, and (3) identify methods to prevent sublethal and lethal impacts to wildlife. Pits at oil production sites in Fall River and Harding Counties of western South Dakota were surveyed for wildlife carcasses by searching the shorelines and raking underwater around the pit edges in April, July, and October 1992. In July, composite water and sediment samples were collected from 26 pits, and analyzed for oil and grease. Bioassays were conducted with two life stages of Hyalella azteca and Daphnia magna to determine pit water toxicity. Seed germination tests were conducted using radish seeds exposed to pit water. Oil and poor water quality appeared to be the primary causes of pit liquid toxicity.

  2. Asphaltene and solids-stabilized water-in-oil emulsions

    Science.gov (United States)

    Sztukowski, Danuta M.

    Water-in-crude oil emulsions are a problem in crude oil production, transportation, and processing. Many of these emulsions are stabilized by asphaltenes and native oilfield solids adsorbed at the oil-water interface. Design of effective emulsion treatments is hampered because there is a lack of understanding of the role asphaltenes and solids play in stabilizing these emulsions. In this work, the structural, compositional and rheological properties of water/hydrocarbon interfaces were determined for model emulsions consisting of water, toluene, heptane, asphaltenes and native oilfield solids. The characteristics of the interface were related to the properties of asphaltenes and native solids. Emulsion stability was correlated to interfacial rheology. A combination of vapour pressure osmometry, interfacial tension and emulsion gravimetric studies indicated that asphaltenes initially adsorb at the interface as a monolayer of self-associated molecular aggregates. It was demonstrated why it is necessary to account for asphaltene self-association when interpreting interfacial measurements. The interfacial area of Athabasca asphaltenes was found to be approximately 1.5 nm2 and did not vary with concentration or asphaltene self-association. Hence, more self-associated asphaltenes simply formed a thicker monolayer. The interfacial monolayer observed in this work varied from 2 to 9 nm in thickness. The asphaltene monolayer was shown to adsorb reversibly only at short interface aging times. The film gradually reorganizes at the interface to form a rigid, irreversibly adsorbed network. The elastic and viscous moduli can be modeled using the Lucassen-van den Tempel (LVDT) model when the aging time is less than 10 minutes. An increase in film rigidity can be detected with an increase in the total elastic modulus. Increased film rigidity was shown to reduce the rate of coalescence in an emulsion and increase overall emulsion stability (reduce free water resolution). The rate of

  3. Secondary ferroan dolomite rhombs in oil reservoirs, Chadra Sands, Gialo field, Libya

    Energy Technology Data Exchange (ETDEWEB)

    Al-Shaieb, Z.; Shelton, J.W.

    1978-03-01

    Oil-productive, Oligocene Chadra sands in Gialo field, Libya, at depths of 600 to 750 m contain small dolomite rhombs. The rhombs are present as single crystals on detrital grains and as nonmosaic aggregates in pore space. The dolomite is calcium-rich and contains up to 10% iron but not measurable sodium or strontium. Total dissolved solids of produced interstitial water from the Chadra sand range from about 4,500 to 10,000 ppM. Introduction of fresh (meteoric) water into the Chadra sands, which were deposited in shallow-marine (shelf) environment, was responsible for formation of the dolomite rhombs. Iron in the dolomite rhombs was derived from alteration of galuconite.

  4. Low cost and conformal microwave water-cut sensor for optimizing oil production process

    KAUST Repository

    Karimi, Muhammad Akram

    2015-08-01

    novel reusable 3D-printed mask based fabrication was also successfully implemented, which would resemble screen printing if it were to be implemented in 3D. In order to verify the design’s applicability for the actual scenario of oil wells, where an oil/water mixture is flowing through the pipes, a basic flow loop was constructed in the IMPACT laboratory at KAUST. The dynamic measurements in the flow loop showed that the WC sensor design is also equally applicable for flowing mixtures. The proposed design is capable of sensing the WC with a fine resolution due to its wide sensing range, in the 80 – 190 MHz frequency band. The experimental results for these low cost and conformal WC sensors are promising, and further characterization and optimization of these sensors according to oil field conditions will enable their widespread use in the oil industry.

  5. Mineral-Coated Polymer Membranes with Superhydrophilicity and Underwater Superoleophobicity for Effective Oil/Water Separation

    OpenAIRE

    Peng-Cheng Chen; Zhi-Kang Xu

    2013-01-01

    Oil-polluted water is a worldwide problem due to the increasing industrial oily wastewater and the frequent oil spill accidents. Here, we report a novel kind of superhydrophilic hybrid membranes for effective oil/water separation. They were prepared by depositing CaCO3-based mineral coating on PAA-grafted polypropylene microfiltration membranes. The rigid mineral-coating traps abundant water in aqueous environment and forms a robust hydrated layer on the membrane pore surface, thus endowing t...

  6. Detecting oil sands process-affected waters in the Alberta oil sands region using synchronous fluorescence spectroscopy.

    Science.gov (United States)

    Kavanagh, Richard J; Burnison, B Kent; Frank, Richard A; Solomon, Keith R; Van Der Kraak, Glen

    2009-06-01

    Large volumes of oil sands process-affected waters (OSPW) are produced during the extraction of bitumen from oil sand. There are approximately 10(9) m(3) of OSPW currently being stored in settling basins on oil sands mining sites in Northern Alberta. Developers plan to create artificial lakes with OSPW and it is expected that this water may eventually enter the environment. This study was conducted in order to determine if synchronous fluorescence spectroscopy (SFS) could detect OSPW contamination in water systems. Water samples collected from ponds containing OSPW and selected sites in the Alberta oil sands region were evaluated using SFS with an offset value of 18 nm. OSPW ponds consistently displayed a minor peak at 282.5 nm and a broad major peak ranging between 320 and 340 nm. Water from reference sites within the oil sands region had little fluorescence at 282.5 nm but greater fluorescence beyond 345 nm. Naphthenic acids are the major toxic component of OSPW. Both a commercial naphthenic acid and a naphthenic acid extract prepared from OSPW had similar fluorescent spectra with peaks at 280 nm and 320 nm and minor shoulders at approximately 303 and 331 nm. The presence of aromatic acids closely associated with the naphthenic acids may be responsible for unique fluorescence at 320-340 nm. SFS is proposed to be a simple and fast method to monitor the release of OSPW into ground and surface waters in the oil sands region.

  7. Investigating electrokinetics application for in-situ inorganic oil field scale control

    Science.gov (United States)

    Hashaykeh, Manal A. I. Albadawi

    Oil well scale formation and deposition is an expensive problem and could be a nightmare for any production engineer if the rate of deposition is rapid as in the case of North Sea oil fields. Inorganic scales accumulate in surface and subsurface equipment causing a reduction in oil production and severe damage for production equipment. The major components of most oil field scale deposits are BaSO4, CaSO4 and SrSO4, which are formed due to incompatible mixing of reservoir formation water and sea water flooded in secondary enhanced oil recovery (EOR) processes. This work focuses on BaSO4 scale as it is one of the toughest scale components to be removed either by chemical means or mechanical means. Scale control methods usually involve complicated treatment using chemical dissolution methods as primary attempt and mechanical scrapping or jetting methods in case of failure of the chemical means. In this work, we devised a novel in-situ scale control method benefiting from the application of direct current (DC) which involves some of the electrokinetic (EK) phenomena. The applications of EK has been proved in our laboratories yielding high efficiency in capturing barium and separating it from sulfate before reaching the production well, thus preventing deposition in the production wellbore or wellbore formation. This objective was evaluated in our lab designed EK apparatus in three parts. In part-1, an 18.5 cm unconsolidated sand core was used which produced inconsistent results. This problem was overcome in part-2, where the porous media involved 46 cm consolidated sandcore. This also partly fulfilled the purpose of upscaling. In part-3, the porous media was extended to a 100 cm spatial distance between the injection and production wells. For all the experiments the reservoir models were made of 125 µm uniform sand particles and followed a final consolidation pressure of 30 psi. The EK-reservoir model contains 2 basic junctions; one of them injecting a 500 ppm SO4 2

  8. Operation history of hydraulic jet pump on teh Chengbei oil field, China. Chengbei yuden ni okeru haidororikku jet pump no shiyo jisseki

    Energy Technology Data Exchange (ETDEWEB)

    Terao, Yoshihiro; Takagi, Sunao

    1989-11-01

    Changbei oil field in China uses hydraulic jet pump(HJP) to cope with the increase of oil production and increase of water content in the oil field. This paper described the practical result. This pump makes high speed jet by driving fluid, and converts the dynamic energy to pressure energy by decelerating with a diffuser to push up oil. Wellheads damaged by sand friction or near the gas cap were removed. The production from March, 1988 to October increased at the rate of 114kl/day at total 8 wellheads. Heavy oil of API specific gravity of 16 degree could be proved. Since the separation of oil and water was inferior, so that the countermeasures were studied but the cause was not known. Troubles or failures of main body, nozzle and throat of HJP were not occurred. Any effect could not be found at a wellhead of water content exceeding 50 to 60% because only water production increased. Consequently, this process could result the increase of oil production with lower cost and without mechanical failures. 2 refs., 7 figs., 7 tabs.

  9. Natural oil slicks fuel surface water microbial activities in the northern Gulf of Mexico

    Science.gov (United States)

    Ziervogel, Kai; D'souza, Nigel; Sweet, Julia; Yan, Beizhan; Passow, Uta

    2014-01-01

    We conducted a series of roller tank incubations with surface seawater from the Green Canyon oil reservoir, northern Gulf of Mexico, amended with either a natural oil slick (GCS-oil) or pristine oil. The goal was to test whether bacterial activities of natural surface water communities facilitate the formation of oil-rich marine snow (oil snow). Although oil snow did not form during any of our experiments, we found specific bacterial metabolic responses to the addition of GCS-oil that profoundly affected carbon cycling within our 4-days incubations. Peptidase and β-glucosidase activities indicative of bacterial enzymatic hydrolysis of peptides and carbohydrates, respectively, were suppressed upon the addition of GCS-oil relative to the non-oil treatment, suggesting that ascending oil and gas initially inhibits bacterial metabolism in surface water. Biodegradation of physically dispersed GCS-oil components, indicated by the degradation of lower molecular weight n-alkanes as well as the rapid transformation of particulate oil-carbon (C: N >40) into the DOC pool, led to the production of carbohydrate- and peptide-rich degradation byproducts and bacterial metabolites such as transparent exopolymer particles (TEP). TEP formation was highest at day 4 in the presence of GCS-oil; in contrast, TEP levels in the non-oil treatment already peaked at day 2. Cell-specific enzymatic activities closely followed TEP concentrations in the presence and absence of GCS-oil. These results demonstrate that the formation of oil slicks and activities of oil-degrading bacteria result in a temporal offset of microbial cycling of organic matter, affecting food web interactions and carbon cycling in surface waters over cold seeps. PMID:24847314

  10. Natural oil slicks fuel surface water microbial activities in the northern Gulf of Mexico

    Directory of Open Access Journals (Sweden)

    Kai eZiervogel

    2014-05-01

    Full Text Available We conducted a series of roller tank incubations with surface seawater from the Green Canyon oil reservoir, northern Gulf of Mexico, amended with either a natural oil slick (GCS-oil or pristine oil. The goal was to test whether bacterial activities of natural surface water communities facilitate the formation of oil-rich marine snow (oil snow. Although oil snow did not form during any of our experiments, we found specific bacterial metabolic responses to the addition of GCS-oil that profoundly affected carbon cycling within our 4-days incubations. Peptidase and -glucosidase activities indicative of bacterial enzymatic hydrolysis of peptides and carbohydrates, respectively, were suppressed upon the addition of GCS-oil relative to the non-oil treatment, suggesting that ascending oil and gas initially inhibits bacterial metabolism in surface water. Biodegradation of physically dispersed GCS-oil components indicated by the degradation of lower molecular weight n-alkanes as well as the rapid transformation of particulate oil-carbon (C: N >40 into the DOC pool, led to the production of carbohydrate- and peptide-rich degradation byproducts and bacterial metabolites such as transparent exopolymer particles (TEP. TEP formation was highest at day 4 in the presence of GCS-oil; in contrast, TEP levels in the non-oil treatment already peaked at day 2. Cell-specific enzymatic activities closely followed TEP concentrations in the presence and absence of GCS-oil. These results demonstrate that the formation of oil slicks and activities of oil-degrading bacteria result in a temporal offset of microbial cycling of organic matter, affecting food web interactions and carbon cycling in surface waters over cold seeps.

  11. Factors governing partial coalescence in oil-in-water emulsions.

    Science.gov (United States)

    Fredrick, Eveline; Walstra, Pieter; Dewettinck, Koen

    2010-01-15

    The consequences of the instability mechanism partial coalescence in oil-in-water food emulsions show a discrepancy. On the one hand, it needs to be avoided in order to achieve an extended shelf life in food products like sauces, creams and several milk products. On the other hand, during the manufacturing of products like ice cream, butter and whipped toppings partial coalescence is required to achieve the desired product properties. It contributes to the structure formation, the physicochemical properties (stability, firmness,...) and the sensory perception, like fattiness and creaminess of the final food products. This review critically summarises the findings of partial coalescence in oil-in-water emulsions in order to provide insight in how to enhance and retard it. Next to the pioneering work, a large set of experimental results of more recent work is discussed. First, the general mechanism of partial coalescence is considered and a distinction is made between partial and 'true' coalescence. The main differences are: the required solid particles in the dispersed oil phase, the formation of irregular clusters and the increased aggregation rate. Second, the kinetics of partial coalescence is discussed. In more detail, potential parameters affecting the rate of partial coalescence are considered by means of the encounter frequency and capture efficiency of the fat globules. The flow conditions, the fat volume fraction and the physicochemical properties of continuous aqueous phase affect both the encounter frequency and capture efficiency while the actual temperature, temperature history and the composition and formulation of the emulsion mainly affect the capture efficiency.

  12. Geology and habitat of oil in Ras Budran field, Gulf of Suez, Egypt

    Energy Technology Data Exchange (ETDEWEB)

    Chowdhary, L.R.; Taha, S.

    1987-05-01

    Deminex discovered the Ras Budran oil field in 1978. Discovery well EE 85-1 was drilled in about 140 ft of water, 4 km off the Sinai coast of the Gulf of Suez. Appraisal drilling (EE 85-2, 3, and 4 wells) confirmed the presence of a major field with an estimated 700 million bbl oil in place. The field, developed from three wellhead platforms, went on production in April 1983. To date, 20 development wells have been drilled. The Ras Budran structure at the deepest mappable seismic reflector, top Kareem (middle Miocene), is a broad northeast-southwest-trending anticlinal feature striking nearly at right angles to the main Gulf of Suez trend. At pre-Miocene producing horizons, the structure is complex and consists of a northeast-dipping flank (14-15) broken into several blocks by faults and limited to the south and west by major bounding faults. Oil is produced from three units of Nubian sandstone at a depth of 11,000 to 12,000 ft. The lower unit of Paleozoic age averages 10% porosity and up to 200 md in -situ permeability. The wells completed in this unit produce up to 2000 BOPD. In contrast, the sands of the upper two units of Lower Cretaceous age have a 15-20% porosity and up to 700 md permeability. The wells completed in these units produce 6000-8000 BOPD. The Ras Budran structure was primarily formed during the intra-Rudeis tectonic phase (lower Miocene). Migration of oil for accumulation in Ras Budran started late in the upper Miocene or Pliocene when the Santonian Brown Limestone and the Eocene Thebes Formation, the main source beds in the Gulf, reached the threshold of oil generation at a burial depth of about 10,000 ft (3000 m). At these depths, the organic matter in the source beds have a transformation ratio (0.10 to 0.15), increased yields of C15 + soluble organic matter and C15 + saturated hydrocarbons, a vitrinite reflectance of 0.62%, and a TTI value of 15.

  13. Preparation of superhydrophobic/oleophilic copper mesh for oil-water separation

    Science.gov (United States)

    Cao, Huaijie; Gu, Wenhan; Fu, Jingyuan; Liu, Ying; Chen, Shougang

    2017-08-01

    A superhydrophobic and oleophilic copper mesh film with micro/nano hierarchical structures was prepared through facile electrodeposition and immersion processes. Contact angles of water and oil on the modified mesh were 152.4° and 12.6°, respectively. The modified mesh showed high oil-water separation efficiency (were above 90%) and rate with high oil flux of 4507 Lm-2 h-1. Results show that oil can pass through the coated mesh easily, whereas water was held on the modified mesh, which demonstrated that the coated films matched well with the requirements for effective separation of oil-water mixtures. Therefore, the coated mesh is a promising and effective membrane for separating oil-water mixtures.

  14. Stability of Concentrated Olive Oil-in-water Emulsion

    Institute of Scientific and Technical Information of China (English)

    TAN Hsiao-Wei; MISRAN Mi-sni

    2008-01-01

    The stability of olive oil-in-water(o/w)emulsion stabilized with sucrose fatty acid ester(SFAE)was evaluated through an accelerated ageing test.The stability of the emulsion in this study was examined by the appearance of any phase separation in the emulsion,mean droplet size and rbeological properties over one month.The effect of accelerated ageing at 45 μ on the emulsion rheological properties was investigated using an amplitude sweep test,a frequency sweep test and a viscometry test.The rheological properties of the emulsion were examined at the one day,one week and one month of storage time.Among the series of emulsions prepared,the emulsion with 2 :8 of water to oil ratio(by weight)is the most stable one,which did not show any of phase separation.The amplitude sweep result shows that there was no significant change of the critical strain of the emulsion throughout one month of storage time.The dynamic properties as well as the steady flow behavior of the emulsion also show no significant changes for over one month of storage time.The mean droplet size of the emulsion remained stable around 2.5 μn within the period of investigation.

  15. Separation mechanisms and fluid flow in oil/water separation

    Energy Technology Data Exchange (ETDEWEB)

    Celius, H.K.; Knudsen, B. [IKU Petroleumsforskning A/S, Trondheim (Norway); Hafskjold, B.; Hansen, E.W. [Selskapet for Industriell og Teknisk Forskning, Trondheim (Norway)

    1996-12-31

    This paper describes work aimed at physical and numerical modeling of separation rates of oil/water systems in order to establish better tools for design and operation of offshore operators. This work aims to integrate the chemical and physical phenomena behind coalescence and settling with those of fluid flow in the system, in order to develop tools for design and operational analysis of separation equipment. The work includes the development of a high pressure, bench-scale test rig to perform separation tests on live oil and water samples, and a rationale in the form of a computer code that can be used to interpret the test results and transform them to a form siutable for operational purposes. This involves a formulation of a mathematical description of the chemical and physical mechanisms behind the emulsification and separation process, and to establish a link to the hydrdynamic properties of the separator vessel. The Emucol computer program is used in the analysis. 12 refs., 5 figs.

  16. Computer simulation of nonstationary thermal fields in design and operation of northern oil and gas fields

    Energy Technology Data Exchange (ETDEWEB)

    Vaganova, N. A., E-mail: vna@imm.uran.ru [Institute of Mathematics and Mechanics of Ural Branch of Russian Academy of Sciences, Ekaterinburg (Russian Federation); Filimonov, M. Yu., E-mail: fmy@imm.uran.ru [Ural Federal University, Ekaterinburg, Russia and Institute of Mathematics and Mechanics of Ural Branch of Russian Academy of Sciences, Ekaterinburg (Russian Federation)

    2015-11-30

    A mathematical model, numerical algorithm and program code for simulation and long-term forecasting of changes in permafrost as a result of operation of a multiple well pad of northern oil and gas field are presented. In the model the most significant climatic and physical factors are taken into account such as solar radiation, determined by specific geographical location, heterogeneous structure of frozen soil, thermal stabilization of soil, possible insulation of the objects, seasonal fluctuations in air temperature, and freezing and thawing of the upper soil layer. Results of computing are presented.

  17. Recent Trends in Water Use and Production for California Oil Production.

    Science.gov (United States)

    Tiedeman, Kate; Yeh, Sonia; Scanlon, Bridget R; Teter, Jacob; Mishra, Gouri Shankar

    2016-07-19

    Recent droughts and concerns about water use for petroleum extraction renew the need to inventory water use for oil production. We quantified water volumes used and produced by conventional oil production and hydraulic fracturing (HF) in California. Despite a 25% decrease in conventional oil production from 1999 to 2012, total water use increased by 30% though much of that increase was derived from reuse of produced water. Produced water volumes increased by 50%, with increasing amounts disposed in unlined evaporation ponds or released to surface water. Overall freshwater use (constituting 1.2% of the state's nonagricultural water consumption) increased by 46% during this period due to increased freshwater-intensive tertiary oil production. HF has been practiced in California for more than 30 years, accounting for 1% of total oil production in 2012 from mostly directional and vertical wells. Water use intensity for HF wells in California averaged at 3.5 vol water/vol oil production in 2012 and 2.4 vol/vol in 2013, higher than the range from literature estimates and net water use intensity of conventional production (1.2 vol/vol in 2012). Increasing water use and disposal for oil production have important implications for water management and have potentially adverse health, environmental, and ecological impacts.

  18. Casing and tubing design for sour oil and gas field

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Y. [CCDC Drilling and Production Technology Research Inst., Guanghan (China). Drilling and Completion Research and Design Center; State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu (China); Lin, Y.; Shi, T.; Zhu, D. [State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu (China); Wang, Z.; You, X.; Zhang, G.; Liu, H. [CCDC Drilling and Production Technology Research Inst., Guanghan (China). Drilling and Completion Research and Design Center

    2009-07-01

    Environmental fractures are the main cause of casing and tubing yield failures in sour gas and oil wells. This paper discussed casing and tubing designs for high pressure high temperature (HPHT) environments containing hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and water wells. A fracture mechanics methods was used to establish yield design criterion for a conventional sulfur resistance casing T95 and a quasi-resistance casing C110. Sulfide stress corrosion (SSC) tests, A-uniaxial tensile tests, and double cantilever beam tests were conducted to determine the potential for failures caused by the unstable propagation of a pre-existing crack and failures caused by the initiation and stable growth of cracks. Elasto-plastic equations were developed to calculate the pressure at which a pipe will fail due to the propagation of a pre-existing sharp crack. Results of the tests indicated that the predictive fracture pressures for the C110 casing and tubing samples were lower than those observed for the T95 sample. 17 refs., 4 figs.

  19. The Geopolitics of Water and Oil in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    Throughout history, few nations have been as successful in leveraging their geographic location as Turkey. As the center of two of the most powerful civilizations of all time, the Byzantine and Ottoman Empires, Turkey was the bridge between East and West, a bustling center of trade and a strategic economic and political nexus between regions of the world. In addition to its geographic power, Turkey has historically possessed substantial water resources. Unlike many water parched areas of the Middle East, Turkey's water capacity has allowed it to grow large populations and build elaborate cities. In the modern era, Turkey once again has an opportunity to regain its historical role, as the state where today's geopolitics of energy coincides with Turkey's traditional geopolitics of water. Turkey's central location, this time not between East and West, but between producers and consumers of energy, gives it a central, geopolitical role in world affairs, both in oil and gas. Moreover, Turkey's water resources can be utilized to reinforce Turkey's strategic energy role in the region, by building a strategy of cooperation with water-poor countries from the Levant to the Arabian Peninsula. Throughout history, water and energy have been among the most fundamental resources of civilization, at the very base of Maslow's hierarchy of needs essential to fostering human growth and development for thousands of years. It is seldom appreciated how linked water and energy truly are. Producing, transferring, and supplying energy requires a significant amount of water, just as the extraction, purification, and even desalination of water requires a significant amount of energy. As both energy and water grow scarcer throughout the future, nations such as Turkey can gain considerable influence as a result of their geographic locations and natural endowments. Turkey can benefit from pipeline diplomacy, taking advantage of its geographical location to

  20. From water-in-oil to oil-in-water emulsions to optimize the production of fatty acids using ionic liquids in micellar systems.

    Science.gov (United States)

    Santos, Luísa D F; Coutinho, João A P; Ventura, Sónia P M

    2015-01-01

    Biocatalysis is nowadays considered as one of the most important tools in green chemistry. The elimination of multiple steps involved in some of the most complex chemical synthesis, reducing the amounts of wastes and hazards, thus increasing the reaction yields and decreasing the intrinsic costs, are the major advantages of biocatalysis. This work aims at improving the enzymatic hydrolysis of olive oil to produce valuable fatty acids through emulsion systems formed by long alkyl chain ionic liquids (ILs). The optimization of the emulsion and the best conditions to maximize the production of fatty acids were investigated. The stability of the emulsion was characterized considering the effect of several parameters, namely, the IL and its concentration and different water/olive oil volumetric ratios. ILs from the imidazolium and phosphonium families were evaluated. The results suggest that the ILs effect on the hydrolysis performance varies with the water concentration and the emulsion system formed, that is, water-in-oil or oil-in-water emulsion. Although at low water concentrations, the presence of ILs does not present any advantages for the hydrolysis reaction, at high water contents (in oil-in-water emulsions), the imidazolium-based IL acts as an enhancer of the lipase catalytic capacity, super-activating 1.8 times the enzyme, and consequently promoting the complete hydrolysis of the olive oil for the highest water contents [85% (v/v)].

  1. Synthesis and applications of vegetable oil-based fluorocarbon water repellent agents on cotton fabrics.

    Science.gov (United States)

    Zhao, Tao; Zheng, Junzhi; Sun, Gang

    2012-06-05

    Vegetable oil-based fluorocarbon water repellent agents were prepared by chemical modifications of different vegetable oils - soybean and linseed oils through several reactions, including saponification, acidification, acylation of vegetable oil and trans-esterification with 2,2,2-trifluoroethanol and 2,2,3,3-tetrafluoropropanol. The resulted fluorocarbon agents were then copolymerized with styrene. The structures of the vegetable oil based agents were characterized by FT-IR and NMR. By evaluating water contact angle and time of water disappearance on cotton fabrics, as well as whiteness and breaking strength of cotton fabrics that were treated by these agents, optimum fabric finishing conditions were explored. The cotton fabrics finished with the vegetable oil-based fluorocarbon agents showed excellent water repellency, while other properties of the cotton fabrics declined to certain level. The linseed oil-based tetrafluoropropanol water repellent agent displayed the highest water repellency among all modified oils. All the treated fabrics exhibited good durability of water repellency. The linseed oil-based tetrafluoropropanol water repellent agent demonstrated the best durability among all repellent agents. Copyright © 2012 Elsevier Ltd. All rights reserved.

  2. Remediation of floating, open water oil spills: Comparative efficacy of commercially available polypropylene sorbent booms

    Science.gov (United States)

    Schrader, Ed L.

    1991-03-01

    Several complex methods of remediation are applied to open water oil spills. Sorbing the liquid hydrocarbons with polypropylene booms is an effective and less complex means of treating such events. There are, however, a variety of commercially available booms which display different performances in sorbing different viscosity hydrocarbons. There is no acceptable A.S.T.M. protocol to evaluate these booms for performance efficiency in various weather and hydrocarbon viscosity scenarios. The current paper proposes such a protocol and evaluates the most commonly used sorbent products with the new test procedures. Nine specific performance criteria, based on actual field applications, are demonstrated.

  3. Intelligent systems in oil field development under uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, Marco A.C.; Vellasco, Marley M.B.R. (eds.) [PUC-Rio, Rio de Janeiro (Brazil). Dept. of Electrical Engineering

    2009-07-01

    Intelligent Systems use a range of methodologies for analysis, pre-processing, storage, organization, enhancing and mining of operational data, turning it into useful information and knowledge for decision makers in business enterprises. These intelligent technologies for decision support have been used with success by companies and organizations that are looking for competitive advantages whenever the issues on forecast, optimization, risks analysis, fraud detection, and decision under uncertainties are presented. Intelligent Systems (IS) offer to managers and decision makers the best solutions for complex applications, normally considered difficult, very restrictive or even impossible. The use of such techniques leads to a revolutionary process which has a significant impact in the business management strategy, by providing on time, correct information, ready to use. Computational intelligence techniques, especially genetic algorithms, genetic programming, neural networks, fuzzy logic and neuro-fuzzy as well as modern finance theories, such as real options theory, are here presented and exemplified in oil and gas exploitation and production. This book is addressed to executives and students, directly involved or interested in intelligent management in different fields. (orig.)

  4. Biodesulphurization Within Natural Gas in Oil and Gas Field

    Directory of Open Access Journals (Sweden)

    Sri Rahayu

    2010-10-01

    Full Text Available The presence of sulphur compounds in natural gas can interfere to the quality of natural gas. The decline of combustion gas capacity, metal instrument corrosion in gas piping, and the environmental pollution from gas emission can affect by their presence. Bio-filter is one of the methods  that selected to reduce sulphur content in natural gas. A lab scale study of hydrogen sulphide reduction in natural gas had conducted in oil and gas field using bio-filter method. The bio-filter system (±1 L volume contains an active carbon and thiosulphide medium as a substrate, Thiobacillus thioparus as a single culture of sulphur bacteria, and Thiobacillus thioparus with sludge as a mixed culture of sulphur bacteria. The study of hydrogen sulphide reduction was conducted with continuous flow line process. The gas flow rate approximately 1.5 L/min with a fluctuate presence of Hydrogen sulphide (approximately 40 - 70 mg/L. The bio-filter system contains active carbon, thiosulphide medium, and single culture of T. thioparus appear as a good filter for hydrogen sulphide reduction. During 24 hours, the hydrogen sulphide reduction obtains 93% to 16%. When  culture media added, the hydrogen sulphide reduction will increase almost 60% and then the reduction decrease to 4% after 20 hours. It is concluded that the bio-filter have potential to develop for sulphur reduction in natural gas.

  5. Application of oil-water discrimination technology in fractured reservoirs using the differences between fast and slow shear-waves

    Science.gov (United States)

    Luo, Cong; Li, Xiangyang; Huang, Guangtan

    2017-08-01

    Oil-water discrimination is of great significance in the design and adjustment of development projects in oil fields. For fractured reservoirs, based on anisotropic S-wave splitting information, it becomes possible to effectively solve such problems which are difficult to deal with in traditional longitudinal wave exploration, due to the similar bulk modulus and density of these two fluids. In this paper, by analyzing the anisotropic character of the Chapman model (2009 Geophysics 74 97-103), the velocity and reflection coefficient differences between the fast and slow S-wave caused by fluid substitution have been verified. Then, through a wave field response analysis of the theoretical model, we found that water saturation causes a longer time delay, a larger time delay gradient and a lower amplitude difference between the fast and slow S-wave, while the oil case corresponds to a lower time delay, a lower gradient and a higher amplitude difference. Therefore, a new class attribute has been proposed regarding the amplitude energy of the fast and slow shear wave, used for oil-water distinction. This new attribute, as well as that of the time delay gradient, were both applied to the 3D3C seismic data of carbonate fractured reservoirs in the Luojia area of the Shengli oil field in China. The results show that the predictions of the energy attributes are more consistent with the well information than the time delay gradient attribute, hence demonstrating the great advantages and potential of this new attribute in oil-water recognition.

  6. Hydraulic Fracturing of 403 Shallow Diatomite Wells in South Belridge Oil Field, Kern County, California, in 2014

    Science.gov (United States)

    Wynne, D. B.; Agusiegbe, V.

    2015-12-01

    We examine all 403 Hydraulic Fracture (HF) jobs performed by Aera Energy, LLC, in the South Belridge oil field, Kern County, CA in 2014. HFs in the South Belridge oil field are atypical amongst North American plays because the reservoir is shallow and produced via vertical wells. Our data set constitutes 88% of all HF jobs performed in CA oil fields in calendar-2014. The South Belridge field produces 11% of California's oil and the shallow HFs performed here differ from most HFs performed elsewhere. We discuss fracture modeling and methods and summary statistics, and modelled dimensions of fractures and their relationships to depth and reservoir properties. The 403 HFs were made in the diatomite-dominated Reef Ridge member of the Monterey Formation. The HFs began at an average depth of 1047 feet below ground (ft TVD) and extended an average of 626 ft vertically downward. The deepest initiation of HF was at 2380 ft and the shallowest cessation was at 639 ft TVD. The average HF was performed using 1488 BBL (62,496 gallons) of water. The HFs were performed in no more than 6 stages and nearly all were completed within one day. We (1) compare metrics of the South Belridge sample group with recent, larger "all-CA" and nationwide samples; and (2) conclude that if relationships of reservoir properties, well completion and HF are well understood, shallow diatomite HF may be optimized to enhance production while minimizing environmental impact.

  7. Effects of crossflow velocity and transmembrane pressure on microfiltration of oil-in-water emulsions

    CERN Document Server

    Darvishzadeh, Tohid

    2012-01-01

    This study addresses the issue of oil removal from water using hydrophilic porous membranes. The effective separation of oil-in-water dispersions involves high flux of water through the membrane and, at the same time, high rejection rate of the oil phase. The effects of transmembrane pressure and crossflow velocity on rejection of oil droplets and thin oil films by pores of different cross-section are investigated numerically by solving the Navier-Stokes equation. We found that in the absence of crossflow, the critical transmembrane pressure, which is required for the oil droplet entry into a circular pore of a given surface hydrophilicity, agrees well with analytical predictions based on the Young-Laplace equation. With increasing crossflow velocity, the shape of the oil droplet is strongly deformed near the pore entrance and the critical pressure of permeation increases. We determined numerically the phase diagram for the droplet rejection, permeation, and breakup depending of the transmembrane pressure and...

  8. Electropumping of water with rotating electric fields

    DEFF Research Database (Denmark)

    Hansen, Jesper Schmidt; De Luca, Sergio; Todd, Billy

    2013-01-01

    of the fluid. By selectively tuning the degree of hydrophobicity of the solid walls one can generate a net unidirectional flow. Our results for the linear streaming and angular velocities of the confined water are in general agreement with the extended hydrodynamical theory for this process, though also...... require some sort of direct intrusion into the nanofluidic system, and involve mechanical or electronic components. In this paper, we present the first nonequilibrium molecular dynamics results to demonstrate that non-intrusive electropumping of liquid water on the nanoscale can be performed by subtly...... exploiting the coupling of spin angular momentum to linear streaming momentum. A spatially uniform rotating electric field is applied to water molecules, which couples to their permanent electric dipole moments. The resulting molecular rotational momentum is converted into linear streaming momentum...

  9. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  10. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  11. Molecular dynamics simulation of adsorption of an oil-water-surfactant mixture on calcite surface

    Institute of Scientific and Technical Information of China (English)

    Lu Guiwu; Zhang Xuefen; Shao Changjin; Yang Hong

    2009-01-01

    An interface super molecular structure model for oil-water-surfactant mixture and calcite was established. By using a molecular dynamics method, the effects of rhamnolipid, sodium dodecyl benzene sulfonate and sodium hexadecyl sulfonate on the interface adsorption behavior of oil molecules were investigated. It was found that these three surfactants could reduce oil-calcite interface binding energy, and play a role of oil-displacing agent.

  12. PetroChina Licensed for Nation's Offshore Oil Fields Development

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ With the approval by the State Council - the Chinese Government, the Ministry of State and Resources formally authorized PetroChina, China's largest oil and gas producer, with the rights for oil and gas exploration and development in South China Sea on July 6.

  13. Exposures and cancer incidence near oil fields in the Amazon basin of Ecuador.

    Science.gov (United States)

    San Sebastián, M; Armstrong, B; Córdoba, J A; Stephens, C

    2001-08-01

    To examine environmental exposure and incidence and mortality of cancer in the village of San Carlos surrounded by oil fields in the Amazon basin of Ecuador. Water samples of the local streams were analyzed for total petroleum hydrocarbons (TPHs). A preliminary list of potential cancer cases from 1989 to 1998 was prepared. Cases were compared with expected numbers of cancer morbidity and mortality registrations from a Quito reference population. Water analysis showed severe exposure to TPHs by the residents. Ten patients with cancer were diagnosed while resident in the village of San Carlos. An overall excess for all types of cancer was found in the male population (8 observed v 3.5 expected) with a risk 2.26 times higher than expected (95% confidence interval (95% CI) 0.97 to 4.46). There was an overall excess of deaths for all types of cancer (6 v 1.6 expected) among the male population 3.6 times higher than the reference population (95% CI 1.31 to 7.81). The observed excess of cancer might be associated with the pollution of the environment by toxic contaminants coming from the oil production.

  14. Petrophysical evaluation of the hydrocarbon potential of the Lower Cretaceous Kharita clastics, North Qarun oil field, Western Desert, Egypt

    Science.gov (United States)

    Teama, Mostafa A.; Nabawy, Bassem S.

    2016-09-01

    Based on the available well log data of six wells chosen in the North Qarun oil field in the Western Desert of Egypt, the petrophysical evaluation for the Lower Cretaceous Kharita Formation was accomplished. The lithology of Kharita Formation was analyzed using the neutron porosity-density and the neutron porosity-gamma ray crossplots as well as the litho-saturation plot. The petrophysical parameters, include shale volume, effective porosity, water saturation and hydrocarbon pore volume, were determined and traced laterally in the studied field through the iso-parametric maps. The lithology crossplots of the studied wells show that the sandstone is the main lithology of the Kharita Formation intercalated with some calcareous shale. The cutoff values of shale volume, porosity and water saturation for the productive hydrocarbon pay zones are defined to be 40%, 10% and 50%, respectively, which were determined, based on the applied crossplots approach and their limits. The iso-parametric contour maps for the average reservoir parameters; such as net-pay thickness, average porosity, shale volume, water saturation and the hydrocarbon pore volume were illustrated. From the present study, it is found that the Kharita Formation in the North Qarun oil field has promising reservoir characteristics, particularly in the northwestern part of the study area, which is considered as a prospective area for oil accumulation.

  15. GWDC Solves World-class Drilling Bottleneck in Kenkijak Oil Field

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ The news that Greatwall Drilling Company Limited (GWDC) has drilled a well with the daily oil production of more than one thousand tons spread quickly when the Well H8010 of CNPC Aktobin Oil and Gas Shareholding Company (CNPC Aktobin) in Kenkijak Oil Field in Kazakhstan produced 1,170 tons on July 1, 2004; both the employees of GWDC and CNPC Aktobin could not hold their excited feeling and cheered at such encouraging news.

  16. Production of high quality water for oil sands application

    Energy Technology Data Exchange (ETDEWEB)

    Beaudette-Hodsman, C.; Macleod, B. [Pall Corp., Mississauga, ON (Canada); Venkatadri, R. [Pall Corp., East Hills, NY (United States)

    2008-10-15

    This paper described a pressurized microfiltration membrane system installed at an oil sands extraction site in Alberta. The system was designed to complement a reverse osmosis (RO) system installed at the site to produce the high quality feed water required by the system's boilers. Groundwater in the region exhibited moderate total suspended solids and high alkalinity and hardness levels, and the RO system required feed water with a silt density index of 3 or less. The conventional pretreatment system used at the site was slowing down production due to the severe fouling of the RO membranes. The new microfiltration system contained an automated PVDF hollow fiber microfiltration membrane system contained in a trailer. Suspended particles and bacteria were captured within the filter, and permeate was sent to the RO unit. Within 6 hours of being installed, the unit was producing water with SDI values in the range of 1.0 to 2.5. It was concluded that the microfiltration system performed reliably regardless of wide variations in feed water quality and flow rates. 3 refs., 1 tab., 8 figs.

  17. Effects of different mycorrhiza species on grain yield, nutrient uptake and oil content of sunflower under water stress

    Directory of Open Access Journals (Sweden)

    Mostafa Heidari

    2014-01-01

    Full Text Available The role of arbuscular mycorrhizal fungi in alleviating water stress is well documented. In order to study the effects of water stress and two different mycorrhiza species on grain yield, nutrient uptake and oil content of sunflower, a field experiment as split plot design with three replications was conducted in the Research Field Station, Zabol University, Zabol, Iran in 2011. Water stress treatments included control as 90% of field capacity (W1, 70% field capacity (W2 and 50% field capacity (W3 assigned to the main plots and two different mycorrhiza species, consisting of M1 = control (without any inoculation, M2 = Glumus mossea and M3 = Glumus etanicatum as sub plots. Results showed that by increasing water stress from control (W1 to W3 treatment, grain yield was significantly decreased. The reduction in the level of W3 was 15.05%. The content of potassium in seeds significantly decreased due to water stress but water stress upto W2 treatment increased the content of phosphorus, nitrogen and oil content of seeds. In between two species of mycorrhiza in sunflower plants, Glumus etanicatum had the highest effect on grain yield and these elements in seeds and increased both.

  18. Interactions of fines with base fractions of oil and its implication in smart water flooding

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    Migration of fines, and formation of oil emulsion have been independently observed during smart water flooding both have been suggested to play a vital role in enhanced oil recovery (EOR). But, the exact role of fines and the reason of emulsion formation are not well studied for carbonate reservo...... reservoirs. This study shows that addition of water and crude oil on calcite fines leads to formation of soluble oil emulsions in the water phase. Formation of these emulsions and its implication in EOR has been experimentally analyzed.......Migration of fines, and formation of oil emulsion have been independently observed during smart water flooding both have been suggested to play a vital role in enhanced oil recovery (EOR). But, the exact role of fines and the reason of emulsion formation are not well studied for carbonate...

  19. A multi-module microfluidic platform for continuous pre-concentration of water-soluble ions and separation of oil droplets from oil-in-water (O/W) emulsions using a DC-biased AC electrokinetic technique.

    Science.gov (United States)

    Das, Dhiman; Phan, Dinh-Tuan; Zhao, Yugang; Kang, Yuejun; Chan, Vincent; Yang, Chun

    2017-03-01

    A novel continuous flow microfluidic platform specifically designed for environmental monitoring of O/W emulsions during an aftermath of oil spills is reported herein. Ionized polycyclic aromatic hydrocarbons which are toxic are readily released from crude oil to the surrounding water phase through the smaller oil droplets with enhanced surface area. Hence, a multi-module microfluidic device is fabricated to form ion enrichment zones in the water phase of O/W emulsions for the ease of detection and to separate micron-sized oil droplets from the O/W emulsions. Fluorescein ions in the water phase are used to simulate the presence of these toxic ions in the O/W emulsion. A DC-biased AC electric field is employed in both modules. In the first module, a nanoporous Nafion membrane is used for activating the concentration polarization effect on the fluorescein ions, resulting in the formation of stable ion enrichment zones in the water phase of the emulsion. A 35.6% amplification of the fluorescent signal is achieved in the ion enrichment zone; corresponding to 100% enrichment of the fluorescent dye concentration. In this module, the main inlet is split into two channels by using a Y-junction so that there are two outlets for the oil droplets. The second module located downstream of the first module consists of two oil droplet entrapment zones at two outlets. By switching on the appropriate electrodes, either one of the two oil droplet entrapment zones can be activated and the droplets can be blocked in the corresponding outlet.

  20. Interactions of fines with base fractions of oil and its implication in smart water flooding

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    Migration of fines, and formation of oil emulsion have been independently observed during smart water flooding both have been suggested to play a vital role in enhanced oil recovery (EOR). But, the exact role of fines and the reason of emulsion formation are not well studied for carbonate...... reservoirs. This study shows that addition of water and crude oil on calcite fines leads to formation of soluble oil emulsions in the water phase. Formation of these emulsions and its implication in EOR has been experimentally analyzed....

  1. Costs for off-site disposal of nonhazardous oil field wastes: Salt caverns versus other disposal methods

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J.A.

    1997-09-01

    According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing states, the treatment and disposal methods they employ, and the amounts they charge. It also compares cavern disposal costs with the costs of other forms of waste disposal.

  2. Foamy oil flow : a laboratory curiosity or a real drive mechanism in field operations?

    Energy Technology Data Exchange (ETDEWEB)

    Maini, B.B. [Calgary Univ., AB (Canada)

    2006-07-01

    The exceptional performance of primary depletion in many Canadian and Venezuelan heavy oil reservoirs can be attributed to the mechanism of foamy oil flow. It is has been speculated that the solution gas released during depletion remains dispersed in the oil and flows towards the production well in the form of gas-in-oil dispersion. However, most laboratory studies of foamy-oil-flow reveal that the depletion rates required for generating dispersed flow are completely unrealistic in field operations. This study examined whether foamy oil flow is merely a laboratory aberration. The paper defines foamy oil flow and explains how it evolved. A brief review of Canadian field practices was presented along with observations from cold production of heavy oil. The pore-scale mechanisms involved and the interplay between capillary and viscous forces were also discussed along with the conditions under which dispersed flow is generated in field operations. The strengths and weaknesses of several mathematical models proposed for numerical simulation of foamy oil flow were described.

  3. Separation flow field and characteristics of oil-water two phases in tangential single and double entrance hydrocyclones%切向单双入口旋流器油-水两相分离流场及特性研究

    Institute of Scientific and Technical Information of China (English)

    王军; 戴海鹏; 姜胜辉; 陈宁

    2014-01-01

    运用雷诺应力模型(RSM)及两相流 MIXTURE 混合模型和 SIMPLEC 算法对切向单、双入口旋流器内的流场进行模拟分析。采用作图法描述了锥段中间截面处的切向速度、径向速度、湍动能及湍能耗散率,使内部复杂旋流流场的分析得以简化。模拟结果表明:单入口旋流器内流场具有不对称性,呈现偏心结构,双入口旋流器流场具有较好的对称性;油-水分离时,切向双入口旋流器中的分离效率为96%,高于单入口旋流器的94%,但同时增大了能量消耗。实验测试结果显示:流量为3 m3/ h 时的实际分离效率为90%,与模拟结果的平均误差为5%,处理流量相同时,采用切向双入口旋流器更能提高分离效率。%Reynolds stress model(RSM),two-phase flow mixture model and SIMPLEC algorithm are applied to the simulation of flow field in tangential single,double entrance hydrocyclones. The method describes the inter-mediate section cone tangential velocity,radial velocity,turbulent kinetic energy and turbulent energy dissipation rate,and makes the analysis of the internal complex swirling flow field simplified. The results show that the flow field in a hydrocyclone single entrance is asymmetric,having the eccentric structure;the flow field of double en-trance hydrocyclone has higher symmetry. The tangential separation efficiency of double entrance hydrocyclone for oil water separation is 96% ,higher than that of single entrance cyclone,which is 94% ,but energy consump-tion is increased at the same time. Experimental result shows that,when the flow rate is 3m3 / h,the actual sepa-ration efficiency is 90% ,and the average error of the simulation is 5% . For the same flow,the tangential double entrance hydrocyclone can improve the oil water separation efficiency.</