WorldWideScience

Sample records for off-gas treatment technologies

  1. Technology of off-gas treatment for liquid-fed ceramic melters

    Energy Technology Data Exchange (ETDEWEB)

    Scott, P.A.; Goles, R.W.; Peters, R.D.

    1985-05-01

    The technology for treating off gas from liquid-fed ceramic melters (LFCMs) has been under development at the Pacific Northwest Laboratory since 1977. This report presents the off-gas technology as developed at PNL and by others to establish a benchmark of development and to identify technical issues. Tests conducted on simulated (nonradioactive) wastes have provided data that allow estimation of melter off-gas composition for a given waste. Mechanisms controlling volatilization of radionuclides and noxious gases are postulated, and correlations between melter operation and emissions are presented. This report is directed to those familiar with LFCM operation. Off-gas treatment systems always require primary quench scrubbers, aerosol scrubbers, and final particulate filters. Depending on the composition of the off gas, equipment for removal of ruthenium, iodine, tritium, and noxious gases may also be needed. Nitrogen oxides are the most common noxious gases requiring treatment, and can be controlled by aqueous absorption or catalytic conversion with ammonia. High efficiency particulate air (HEPA) filters should be used for final filtration. The design criteria needed for an off-gas system can be derived from emission regulations and composition of the melter feed. Conservative values for melter off-gas composition can be specified by statistical treatment of reported off-gas data. Statistical evaluation can also be used to predict the frequency and magnitude of normal surge events that occur in the melter. 44 refs., 28 figs., 17 tabs.

  2. FY-2001 Accomplishments in Off-gas Treatment Technology Development

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, Douglas William

    2001-09-01

    This report summarizes the efforts funded by the Tank Focus Area to investigate nitrogen oxide (NOx) destruction (a.k.a. deNOx) technologies and off-gas scrubber system designs. The primary deNOx technologies that were considered are staged combustion (a.k.a. NOx reburning), selective catalytic reduction, selective non-catalytic reduction, and steam reformation. After engineering studies and a team evaluation were completed, selective catalytic reduction and staged combustion were considered the most likely candidate technologies to be deployed in a sodium-bearing waste vitrification facility. The outcome of the team evaluation factored heavily in the establishing a baseline configuration for off-gas and secondary waste treatment systems.

  3. Interim report on testing of off-gas treatment technologies for abatement of atmospheric emissions of chlorinated volatile organic compounds

    International Nuclear Information System (INIS)

    Haselow, J.S.; Jarosch, T.R.; Rossabi, J.; Burdick, S.; Lombard, K.

    1993-12-01

    The purpose of this report is to briefly summarize the results to date of the off-gas treatment program for atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program is part of the Department of Energy's Office of Technology Development's Integrated Demonstration for Treatment of Organics in Soil and Water at a Non-Arid Site. The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed. That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment program would complement the Integrated Demonstration not only because off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the US to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate systematic and unbiased evaluation of the emerging technologies

  4. Treatment of off-gas from radioactive waste incinerators

    International Nuclear Information System (INIS)

    1989-01-01

    An effective process reducing volume of radioactive wastes is incineration of combustible wastes. Appropriate design of the off-gas treatment system is necessary to ensure that any releases of airborne radionuclides into the environment are kept below acceptable limits. In many cases, the off-gas system must be designed to accommodate chemical constituents in the gas stream. The purpose of this publication is to provide the most up-to-date information regarding off-gas treatment as well as an account of some of the developments so as to aid users in the selection of an integrated system for a particular application. The choice of incinerator/off-gas system combination depends on the wastes to be treated, as well as other factors, such as regulatory requirements. Current problems and development needs are discussed. Following comprehensive discussions of the various factors affecting a choice, various incinerator and off-gas treatment systems are recommended for the various types of wastes that may be treated: low PVC content solid, high PVC content solid, organic liquid and resins. The economics or costs of the off-gas system and an evaluation of the overall cost effectiveness of incineration or direct burial is not discussed in detail. This publication is specifically directed toward technical aspects and addresses: incineration types and origin, sources and characteristics of off-gas streams; descriptions of available technologies for off-gas treatment; basic component design requirements and component description; operational experience of plants in active operation and their current practices; legal aspects and safety requirements; remaining problems to be solved and development trends in plant design and component structure. This report seeks to broaden and enhance the understanding of the developed technology and to indicate areas where improvements can be made by further research and development. 110 refs

  5. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    International Nuclear Information System (INIS)

    Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

    1995-01-01

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development's VOC's in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry

  6. Test results from the GA Technologies engineering-scale off-gas treatment system

    International Nuclear Information System (INIS)

    Jensen, D.D.; Olguin, L.J.; Wilbourn, R.G.

    1985-01-01

    Test results are available from the GA Technologies (GA) off-gas treatment facilities using gas streams from both the graphite fuel element burner system and from the spent fuel dissolver. The off-gas system is part of a pilot plant for development of processes for treating spent fuel from high temperature gas-cooled reactors (HTGRs). One method for reducing the volume of HTGR fuel prior to reprocessing or spent fuel storage is to crush and burn the graphite fuel elements. The burner off-gas (BOG) contains radioactive components, principally H-3, C-14, Kr-85, I-129, and Rn-220, as well as chemical forms such as CO 2 , CO, O 2 , and SO 2 . The BOG system employs components designed to remove these constituents. Test results are reported for the iodine and SO 2 adsorbers and the CO/HT oxidizer. Integrated testing of major BOG system components confirmed the performance of units evaluated in individual tests. Design decontamination and conversion factors were maintained for up to 72 h. In a reprocessing flowsheet, the solid product from the burners is dissolved in nitric or Thorex acid. The dissolver off-gas (DOG) contains radioactive components H-3, Kr-85, I-129, Rn-220 plus chemical forms such as nitrogen oxides (NO/sub x/). In the pilot-scale system iodine is removed from the DOG by adsorption. Tests of iodine removal have been conducted using either silver-exchanged mordenite (AgZ) or AgNO 3 -impregnated silica gel (AC-6120). Although each sorbent performed well in the presence of NO/sub x/, the silica gel adsorbent proved more efficient in silver utilization and, thus, more cost effective

  7. Off-gas treatment carbon footprint calculator : form and function

    Energy Technology Data Exchange (ETDEWEB)

    Kessell, L. [Good EarthKeeping Organization Inc., Corona, CA (United States); Squire, J.; Crosby, K. [Haley and Aldrich Inc., Boston, MA (United States)

    2008-07-01

    Carbon footprinting is the measurement of the impact on the environment in terms of the amount of greenhouse gases produced, measured in units of carbon dioxide released directly and indirectly by an individual, organization, process, event or product. This presentation discussed an off-gas treatment carbon footprint calculator. The presentation provided a review of off-gas treatment technologies and presented a carbon footprint model. The model included: form and function; parameters; assumptions; calculations; and off-gas treatment applications. Parameters of the model included greenhouse gases listed in the Kyoto Protocol to the United Nations Framework Convention on Climate Change, such as carbon dioxide, methane, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons, and perfluorocarbons. Assumptions of the model included stationary combustion emissions; mobile combustion emissions; indirect emissions; physical or chemical processing emissions; fugitive emissions; and de minimus emissions. The presentation also examined resource conservation and discussed three greenhouse gas footprint case studies. It was concluded that the model involved a calculator with standard calculations with clearly defined assumptions with boundaries. tabs., figs.

  8. High-level waste vitrification off-gas cleanup technology

    International Nuclear Information System (INIS)

    Hanson, M.S.

    1980-01-01

    This brief overview is intended to be a basis for discussion of needs and problems existing in the off-gas clean-up technology. A variety of types of waste form and processes are being developed in the United States and abroad. A description of many of the processes can be found in the Technical Alternative Documents (TAD). Concurrently, off-gas processing systems are being developed with most of the processes. An extensive review of methodology as well as decontamination factors can be found in the literature. Since it is generally agreed that the most advanced solidification process is vitrification, discussion here centers about the off-gas problems related to vitrification. With a number of waste soldification facilities around the world in operation, it can be shown that present technology can satisfy the present requirement for off-gas control. However, a number of areas within the technology base show potential for improvement. Fundamental as well as verification studies are needed to obtain the improvements

  9. Treatment of off-gas from lagoon sludge thermal decomposition

    International Nuclear Information System (INIS)

    Hwang, D. S.; Oh, J. H.; Choi, Y. D.; Hwang, S. T.; Park, J. H.; Ga, M. J.

    2005-01-01

    Korea Atomic Energy Research Institute (KAERI) has launched a decommissioning program of the uranium conversion plant in 2001. The treatment of the sludge waste, which was generated during the operation of the plant and stored in the lagoon, is one of the most important tasks in the decommissioning program of the plant. The major compounds of the lagoon sludge are ammonium nitrate, sodium nitrate, calcium nitrate, calcium carbonate, and uranium compounds. The minor compounds are iron, magnesium, aluminum, silicon and phosphorus. A treatment process of the sludge was developed as figure 1 based on the results of the sludge characteristics and the developed treatment technologies. A treatment of off-gas evolved from the nitrate salts thermal decomposition is one of the important process. Off-gas treatment by using a selective catalytic reduction (SCR) method was investigated in this study

  10. Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment

    International Nuclear Information System (INIS)

    Nick Soelberg

    2005-01-01

    Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost

  11. Biological off-gas treatment: let's make things better

    NARCIS (Netherlands)

    Groenestijn, J.W. van

    1998-01-01

    Biological off-gas treatment is the most effective cleaning method for many off-gases which contain low concentration of pollutants (<5 g/m3). The world market share in off-gas treatment is a few percent. Potential buyers are reserved because of existing biofilter quality differences and lack of

  12. Off-gas treatment system Process Experimental Pilot Plant (PREPP) k-t evaluation

    International Nuclear Information System (INIS)

    Hedahl, T.G.; Cargo, C.H.; Ayers, A.L.

    1982-06-01

    The scope of work for this task involves a systems' evaluation, using the Kepner-Tregoe (K-T) decision analysis methodology, of off-gas treatment alternatives for a Process Experimental Pilot Plant (PREPP). Two basic systems were evaluated: (1) a wet treatment system using a quencher and scrubber system; and (2) a dry treatment system using a spray dryer and baghouse arrangement. Both systems would neutralize acidic off-gases (HCL and SO 2 ) and remove radioactive particulates prior to release to the environment. The K-T analysis results provided a numerical comparison of the two basic off-gas treatments systems for PREPP. The overall ratings for the two systems differ by only 7%. The closeness of the evaluation indicates that either system is capable of treating the off-gases from PREPP. Based on the analysis, the wet treatment system design is slightly more favorable for PREPP. Technology development, expected operability, total costs, and safety aspects were determined to be more advantageous for the wet system design. Support technology was the only major category that appears less favorable for using the wet off-gas system for PREPP. When considering the two criteria considered most important for PREPP (capital cost and major accident prevention - both rated 10), the wet treatment system received maximum ratings. Space constraints placed on the design by the existing TAN-607 building configuration also are more easily met by the wet system design. Lastly, the level of development for the wet system indicates more applicable experience for nuclear waste processing

  13. Microwave off-gas treatment apparatus and process

    Science.gov (United States)

    Schulz, Rebecca L.; Clark, David E.; Wicks, George G.

    2003-01-01

    The invention discloses a microwave off-gas system in which microwave energy is used to treat gaseous waste. A treatment chamber is used to remediate off-gases from an emission source by passing the off-gases through a susceptor matrix, the matrix being exposed to microwave radiation. The microwave radiation and elevated temperatures within the combustion chamber provide for significant reductions in the qualitative and quantitative emissions of the gas waste stream.

  14. Computer simulation of the off gas treatment process for the KEPCO pilot vitrification plant

    International Nuclear Information System (INIS)

    Kim, Hey Suk; Maeng, Sung Jun; Lee, Myung Chan

    1999-01-01

    Vitrification technology for treatment of low and intermediate radioactive wastes can remarkably reduce waste volume to about one twentieth of the initial volume as they are collected and converted into a very stable form. Therefore, it can minimize environmental impact when the vitrified waste is disposed of. But an off gas treatment system is necessary to apply this technology because air pollutants and radioisotopes are generated like those of other conventional incinerators during thermal oxidation process at high temperature. KEPCO designed and installed a pilot scale vitrification plant to demonstrate the feasibility of the vitrification process and then to make a conceptual design for a commercial vitrification facility. The purpose of this study was to simulate the off gas treatment system(OGTS) in order optimize the operating conditions. Mass balance and temperature profile in the off gas treatment system were simulated for different combinations of combustible wastes by computer simulation code named OGTS code and removal efficiency of each process was also calculated with change of design parameters. The OGTS code saved efforts,time and capital because scale and configuration of the system could be easily changed. The simulation result of the pilot scale off gas process as well as pilot tests will be of great use in the future for a design of the commercial vitrification facility. (author)

  15. Removal of CO2 in closed loop off-gas treatment systems

    International Nuclear Information System (INIS)

    Clemens, M.K.; Nelson, P.A.; Swift, W.M.

    1994-01-01

    A closed loop test system has been installed at Argonne National Laboratory (ANL) to demonstrate off-gas treatment, absorption, and purification systems to be used for incineration and vitrification of hazardous and mixed waste. Closed loop systems can virtually eliminate the potential for release of hazardous or toxic materials to the atmosphere during both normal and upset conditions. In initial tests, a 250,000 Btu/h (75 kW thermal) combustor was operated in an open loop to produce a combustion product gas. The CO 2 in these tests was removed by reaction with a fluidized bed of time to produce CaCO 3 . Subsequently, recirculation system was installed to allow closed loop operation with the addition of oxygen to the recycle stream to support combustion. Commercially marketed technologies for removal of CO 2 can be adapted for use on closed loop incineration systems. The paper also describes the Absorbent Solution Treatment (AST) process, based on modifications to commercially demonstrated gas purification technologies. In this process, a side loop system is added to the main loop for removing CO 2 in scrubbing towers using aqueous-based CO 2 absorbents. The remaining gas is returned to the incinerator with oxygen addition. The absorbent is regenerated by driving off the CO 2 and water vapor, which are released to the atmosphere. Contaminants are either recycled for further treatment or form precipitates which are removed during the purification and regeneration process. There are no direct releases of gases or particulates to the environment. The CO 2 and water vapor go through two changes of state before release, effectively separating these combustion products from contaminants released during incineration. The AST process can accept a wide range of waste streams. The system may be retrofitted to existing Facilities or included in the designs for new installations

  16. Off-gas considerations for a vitrification plant in the republic of Korea

    International Nuclear Information System (INIS)

    Chun, Ung Kyung; Park, Jong Kil; Yang, Kyung Hwa; Song, Myung Jae

    1997-01-01

    The Republic of Korea is in the process of preparing for its first ever vitrification plant to handle low and intermediate-level radioactive waste from her pressurized water reactors (PWRs). KEPRI, in coordination with her partners, will design, construct, and erect a pilot plant using data from the orientation tests. The pilot plant will be the basis for the development of the final objective, the establishment of an industrial scale vitrification installation in the Republic of Korea. Throughout these projects, the major goal is to minimize the harmful effects of the final waste form to the environment. The gaseous effluents emissions from the facility will need to be managed to meet the environmental regulations concerning gaseous releases into the environment of the Republic of Korea. The focus of this paper is on the considerations for the treatment of the off-gas for a low and intermediate-level radioactive waste treatment vitrification installation in the Republic of Korea. Off-gas considerations will span a wide-range of areas such as waste characteristics, thermal treatment systems, off-gas regulations, off-gas characteristics, assessment of air pollution control devices, systems assessments, numerical modelling, economics etc. Off-gas regulations in Korea are becoming tighter and will likely change from year to year. In terms of both off-gas treatment equipment performance and public protection, the amount and nature (e.g. chemical behavior and morphology) of the species are important. The emissions may be classified as toxic metals, radionuclides, hydrocarbons, particulate matter, and acid gases. Air pollution control technologies are generally classified as wet or dry technologies covering over 40 different air pollution control devices (APCDs) with varying removal efficiencies for the different types of off-gas. In general, the state of the art systems for vitrification technologies incorporate the basic functions such as further oxidation of products

  17. Off-gas processing method in reprocessing plant

    International Nuclear Information System (INIS)

    Kobayashi, Yoshihiro; Seki, Eiji.

    1990-01-01

    Off-gases containing a radioactive Kr gas generated in a nuclear fuel reprocessing plant are at first sent to a Kr gas separator. Then, the radioactive Kr gas extracted there is introduced to a Kr gas fixing device. A pretreatment and a post-treatment are applied by using a non-radioactive clean inert gas except for the Kr gas as a purge gas. If the radioactive Kr gas is contained in the off-gases discharged from the Kr gas fixing device after applying the post-treatment, the off gases are returned to the Kr gas separator. Accordingly, in a case where the radioactive Kr gas is contained in the off-gases discharged from the Kr gas fixing device, it is not necessary to apply the fixing treatment to all of the off gases. In view of the above, increase of the amount of processing gases can be suppressed and the radioactive Kr gas can be fixed efficiently and economically. (I.N.)

  18. Safety evaluation of BWR off-gas treatment systems

    International Nuclear Information System (INIS)

    Schultz, R.J.; Schmitt, R.C.

    1975-01-01

    Some of the results of a safety evaluation performed on current generic types of BWR off-gas treatment systems including cooled and ambient temperature adsorber beds and cryogenics are presented. The evaluation covered the four generic types of off-gas systems and the systems of five major vendors. This study was part of original work performed under AEC contract for the Directorate of Regulatory Standards. The analysis techniques employed for the safety evaluation of these systems include: Fault Tree Analysis; FMECA (Failure Mode Effects and Criticality Analysis); general system comparisons, contaminant, system control, and design adequacy evaluations; and resultant Off-Site Dose Calculations. The salient areas presented are some of the potential problem areas, the approach that industry has taken to mitigate or design against potential upset conditions, and areas where possible deficiencies still exist. Potential problem areas discussed include hydrogen detonation, hydrogen release to equipment areas, operator/automatic control interface, and needed engineering evaluation to insure safe system operation. Of the systems reviewed, most were in the category of advanced or improved over that commonly in use today, and a conclusion from the study was that these systems offer excellent potential for noble gas control for BWR power plants where more stringent controls may be specified -- now or in the future. (U.S.)

  19. Study of plasma off-gas treatment from spent ion exchange resin pyrolysis.

    Science.gov (United States)

    Castro, Hernán Ariel; Luca, Vittorio; Bianchi, Hugo Luis

    2017-03-23

    Polystyrene divinylbenzene-based ion exchange resins are employed extensively within nuclear power plants (NPPs) and research reactors for purification and chemical control of the cooling water system. To maintain the highest possible water quality, the resins are regularly replaced as they become contaminated with a range of isotopes derived from compromised fuel elements as well as corrosion and activation products including 14 C, 60 Co, 90 Sr, 129 I, and 137 Cs. Such spent resins constitute a major proportion (in volume terms) of the solid radioactive waste generated by the nuclear industry. Several treatment and conditioning techniques have been developed with a view toward reducing the spent resin volume and generating a stable waste product suitable for long-term storage and disposal. Between them, pyrolysis emerges as an attractive option. Previous work of our group suggests that the pyrolysis treatment of the resins at low temperatures between 300 and 350 °C resulted in a stable waste product with a significant volume reduction (>50%) and characteristics suitable for long-term storage and/or disposal. However, another important issue to take into account is the complexity of the off-gas generated during the process and the different technical alternatives for its conditioning. Ongoing work addresses the characterization of the ion exchange resin treatment's off-gas. Additionally, the application of plasma technology for the treatment of the off-gas current was studied as an alternative to more conventional processes utilizing oil- or gas-fired post-combustion chambers operating at temperatures in excess of 1000 °C. A laboratory-scale flow reactor, using inductively coupled plasma, operating under sub-atmospheric conditions was developed. Fundamental experiments using model compounds have been performed, demonstrating a high destruction and removal ratio (>99.99%) for different reaction media, at low reactor temperatures and moderate power consumption

  20. Treatment of off-gas evolved from thermal decomposition of sludge waste

    International Nuclear Information System (INIS)

    Doo-Seong Hwang; Yun-Dong Choi; Gyeong-Hwan Jeong; Jei-Kwon Moon

    2013-01-01

    Korea Atomic Energy Research Institute (KAERI) started a decommissioning program of a uranium conversion plant. The treatment of the sludge waste, which was generated during the operation of the plant, is one of the most important tasks in the decommissioning program of the plant. The major compounds of sludge waste are nitrate salts and uranium. The sludge waste is denitrated by thermal decomposition. The treatment of off-gas evolved from the thermal decomposition of nitrate salts in the sludge waste is investigated. The nitrate salts in the sludge were decomposed in two steps: the first decomposition is due to the ammonium nitrate, and the second is due to the sodium and calcium nitrate and calcium carbonate. The components of off-gas from the decomposition of ammonium nitrate at low temperature are NH 3 , N 2 O, NO 2 , and NO. In addition, the components from the decomposition of sodium and calcium nitrate at high temperature are NO 2 and NO. Off-gas from the thermal decomposition is treated by the catalytic oxidation of ammonia and selective catalytic reduction (SCR). Ammonia is converted into nitrogen oxides through the oxidation catalyst and all nitrogen oxides are removed by SCR treatment besides nitrous oxide, which is greenhouse gas. An additional process is needed to remove nitrous oxide, and the feeding rate of ammonia in SCR should be controlled properly for evolved nitrogen oxides. (author)

  1. Off-gas treatment and characterization for a radioactive in situ vitrification test

    International Nuclear Information System (INIS)

    Oma, K.H.; Timmerman, C.L.

    1985-01-01

    Effluents released to the off gas during the in situ vitrification (ISV) of a test site have been characterized. The site consisted of a 19 L waste package of soil containing 600 nCi/g transuranic and 30,000 nCi/g mixed fission products surrounded by uncontaminated soil. Radioactive isotopes present in the package were 241 Am, /sup 238/239/Pu, 137 Cs, 106 Ru, 90 Sr, and 60 Co. The ISV process melted the waste package and surrounding soil and immobilized the radionuclides in place, producing a durable, 8.6 metric ton glass and crystalline monolith. The test successfully demonstrated that the process provides containment of radioactive material. No release to the environment was detected during processing or cooldown. Due to the high temperatures during processing, some gases were released into the off-gas hood that was placed over the test site. The hood was maintained at a light negative pressure to contain any volatile or entrained material during processing. Gases passed from the hood to an off-gas treatment system where they were treated using a venturi-ejector scrubber, a tandem nozzle gas cleaner scrubber followed by a condenser, heater, and two stages of HEPA filters. The off-gas treatment system is located in the semi-trailer to allow transport of the process to other potential test sites. Retention of all radionuclides by the vitrified zone was greater than 99%. Soil-to-off-gas decontamination factors (DFs) for transuranic elements averaged greater than 4000 and for fission products, DFs ranged from 130 for 137 Cs to 3100 for 90 Sr

  2. Selective Trapping of Volatile Fission Products with an Off-Gas Treatment System

    Energy Technology Data Exchange (ETDEWEB)

    B.R. Westphal; J.J. Park; J.M. Shin; G.I. Park; K.J. Bateman; D.L. Wahlquist

    2008-07-01

    A head-end processing step, termed DEOX for its emphasis on decladding via oxidation, is being developed for the treatment of spent oxide fuel by pyroprocessing techniques. The head-end step employs high temperatures to oxidize UO2 to U3O8 resulting in the separation of fuel from cladding and the removal of volatile fission products. Development of the head-end step is being performed in collaboration with the Korean Atomic Energy Research Institute (KAERI) through an International Nuclear Energy Research Initiative. Following the initial experimentation for the removal of volatile fission products, an off-gas treatment system was designed in conjunction with KAERI to collect specific fission gases. The primary volatile species targeted for trapping were iodine, technetium, and cesium. Each species is intended to be collected in distinct zones of the off-gas system and within those zones, on individual filters. Separation of the volatile off-gases is achieved thermally as well as chemically given the composition of the filter media. A description of the filter media and a basis for its selection will be given along with the collection mechanisms and design considerations. In addition, results from testing with the off-gas treatment system will be presented.

  3. Incineration and flue gas treatment technologies

    International Nuclear Information System (INIS)

    1997-01-01

    The proceedings are presented of an international symposium on Incineration and Flue Gas Treatment Technologies, held at Sheffield University in July 1997. Papers from each of the six sessions cover the behaviour of particles in incinerator clean-up systems, pollution control technologies, the environmental performance of furnaces and incinerators, controlling nitrogen oxide emissions, separation processes during flue gas treatment and regulatory issues relating to these industrial processes. (UK)

  4. Off-gas treatment and characterization for a radioactive in situ vitrification test

    International Nuclear Information System (INIS)

    Oma, K.H.; Timmerman, C.L.

    1984-08-01

    Effluents released to the off gas during the in situ vitrification (ISV) of a test site have been characterized by Pacific Northwest Laboratory. The site consisted of a 19 L waste package of soil containing 600 nCi/g transuranic and 30,000 nCi/g mixed fission products surrounded by uncontaminated soil. Radioactive isotopes present in the package were 241 Am, 238 / 239 Pu, 137 Cs, 106 Ru, 90 Sr, and 60 Co. The ISV process melted the waste package and surrounding soil and immobilized the radionuclides in place, producing a durable, 8.6 metric ton glass and crystalline monolith. The test successfully demonstrated that the process provides containment of radioactive material. No release to the environment was detected during processing of cooldown. Due to the high temperature during processing, some gases were released into the off-gas hood that was over the test site. The hood was maintained at a slight negative pressure to contain any volatile or entrained material during processing. Gases passed from the hood to an off-gas treatment system where they were treated using a venturi-ejector scrubber, a tandem nozzle gas cleaner scrubber followed by a condenser, heater, and two stages of HEPA filters. The off-gas treatment system is located in the semi-trailer to allow transport of the process to other potential test sites. Retention of all radionuclides by the vitrified zone was greater than 99%. Soil-to-off-gas decontamination factors (DFs) for transuranic elements averaged greater than 4000 and for fission products, DFs ranged from 130 for 137 Cs to 3100 for 90 Sr. 7 references, 15 figures, 4 tables

  5. Treatment Of Mercury Target Off-Gas At SNS

    International Nuclear Information System (INIS)

    DeVore, Joe R.; Freeman, David W.

    2007-01-01

    The Spallation Neutron Source (SNS) is the first operational spallation source to use liquid Mercury as a target material. This paper describes the treatment system to remove volatile spallation products from a Helium purge stream that emanates from the Mercury target and adjustments made to achieve design goals in response to phenomena experienced during initial operations. The Helium stream is treated to remove volatile spallation products prior to environmental release because of its activity level as these accumulate in the gas space in the Mercury Loop. Unanticipated local dose rates were noted in treatment system components during low power startup. Gamma scanning of these components identified the presence of nineteen noble gas isotopes and their daughters, indicating that the doses resulted from noble gas sorption. Treatment of this equipment with stable Xenon greatly reduced but did not eliminate these. Significant moisture was also encountered in the system, resulting in the plugging of the system cold trap. Changes to some of the system equipment were required together with moisture elimination from components to which moisture was sorbed. Necessary re-configuration of Mercury pump components presented additional requirements and system control changes to accommodate system operation at reduced pressure. The Off-Gas Treatment System has been successfully operated since April, 2006. System availability and removal effectiveness have been high. Operational issues occurring during the first year of operation have been resolved.

  6. Technology survey for real-time monitoring of plutonium in a vitrifier off-gas system

    International Nuclear Information System (INIS)

    Berg, J.M.; Veirs, D.K.

    1996-01-01

    We surveyed several promising measurement technologies for the real-time monitoring of plutonium in a vitrifier off-gas system. The vitrifier is being developed by Westinghouse Savannah River Corp. and will be used to demonstrate vitrification of plutonium dissolved in nitric acid for fissile material disposition. The risk of developing a criticality hazard in the off-gas processing equipment can be managed by using available measurement technologies. We identified several potential technologies and methods for detecting plutonium that are sensitive enough to detect the accumulation of a mass sufficient to form a criticality hazard. We recommend gross alpha-monitoring technologies as the most promising option for Westinghouse Savannah River Corp. to consider because that option appears to require the least additional development. We also recommend further consideration for several other technologies because they offer specific advantages and because gross alpha-monitoring could prove unsuitable when tested for this specific application

  7. Canadian development program for off-gas management in nuclear facilities

    International Nuclear Information System (INIS)

    Sridhar, T.S.

    1983-01-01

    The Canadian program for the development and evaluation of processes and technology for the separation and containment of radioactive species in off-gases is directed towards the following specific aspects: 1) assessment of available treatment technology and evaluation of future clean-up requirements; 2) development and engineering evaluation, under realistic conditions, of promising new processes that would be inherently simpler and safer; and 3) specification of off-gas emission control systems for future nuclear facilities based on the most favourable technology. The program is being carried out by Atomic Energy of Canada Limited in collaboration with the electrical utility, Ontario Hydro, and selected Canadian universities. A brief description is presented of methods for removing tritium and carbon-14 from the moderator systems of CANDU power reactors, methods for removing iodine from the off-gases of a molybdenum-99 production facility at the Chalk River Nuclear Laboratories, and procedures for monitoring the off-gas effluent composition in the Thorium Fuel Reprocessing Experiment (TFRE) facility at the Whiteshell Nuclear Research Establishment

  8. An assessment of off-gas treatment technologies for application to thermal treatment of Department of Energy wastes

    International Nuclear Information System (INIS)

    Dalton, J.D.; Gillins, R.L.; Harris, T.L.; Wollerman, A.L.

    1992-09-01

    The purpose of this report is to describe available air pollution control technologies for pollutants generated by thermal treatment of DOE wastes. A basic process for selecting air pollution control devices is summarized. Types of air pollutants generated by thermal treatment units are described, as well as the factors that influence the types and quantities of pollutants generated. This report also reviews applicable regulatory emission requirements. A listing of available and emerging air pollution control technologies and a brief introduction to the basic engineering principles involved in collecting each of the pollutants are presented. Section 7 of this report contains two types of evaluations for air pollution control devices. First, comparative evaluations of individual technologies are presented, based upon criteria generally relevant to DOE facilities. Using this evaluation system, the spray dryer absorber received the highest rating for acid-gas removal; high-efficiency particulate air (HEPA) filters received the highest rating for particulate removal; activated carbon adsorption received the highest rating for the removal of both toxic metals and residual hydrocarbons; and selective catalytic reduction received the highest rating for nitrogen oxide abatement. Also evaluated in Sect. 7 is the expected performance of different types of pollution control systems on two hypothetical waste streams. The waste streams were defined based upon typical DOE wastes and thermal treatment technologies. Section 8 presents conclusions for this report. Two appendixes are included with this report. The first appendix contains a brief description of all the technologies evaluated and the second lists of some of the vendors for each of the technologies that was evaluated

  9. Airborne waste management technology applicable for use in reprocessing plants for control of iodine and other off-gas constituents

    International Nuclear Information System (INIS)

    Jubin, R.T.

    1988-02-01

    Extensive work in the area of iodine removal from reprocessing plant off-gas streams using various types of solid sorbent materials has been conducted worldwide over the past two decades. This work has focused on the use of carbon filters, primarily for power plant applications. More recently, the use of silver-containing sorbents has been the subject of considerable research. The most recent work in the United States has addressed the use of silver-exchanged faujasites and mordenites. The chemical reactions of iodine with silver on the sorbent are not well defined, but it is generally believed that chemisorbed iodides and iodates are formed. The process for iodine recovery generally involves passage of the iodine-laden gas stream through a packed bed of the adsorbent material preheated to a temperature of about 150/degree/C. Most iodine removal system designs utilizing silver-containing solid sorbents assume only a 30 to 50% silver utilization. Based on laboratory tests, potentially 60 to 70% of the silver contained in the sorbents can be reacted with iodine. To overcome the high cost of silver associated with these materials, various approaches have been explored. Among these are the regeneration of the silver-containing sorbent by stripping the iodine and trapping the iodine on a sorbent that has undergone only partial silver exchange and is capable of attaining a much higher silver utilization. This summary report describes the US work in regeneration of iodine-loaded solid sorbent material. In addition, the report discusses the broader subject of plant off-gas treatment including system design. The off-gas technologies to recovery No/sub x/ and to recover and dispose of Kr, 14 C, and I are described as to their impacts on the design of an integrated off-gas system. The effect of ventilation philosophy for the reprocessing plant is discussed as an integral part of the overall treatment philosophy of the plant off-gas. 103 refs., 5 figs., 8 tabs

  10. Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system.

    Science.gov (United States)

    Suetens, T; Guo, M; Van Acker, K; Blanpain, B

    2015-04-28

    To better understand the phenomena of ZnFe2O4 spinel formation in electric arc furnace dust, the dust was characterized with particle size analysis, X-ray fluorescence (XRF), electron backscatter diffraction (EBSD), and electron probe micro-analysis (EPMA). Different ZnFe2O4 formation reaction extents were observed for iron oxide particles with different particle sizes. ZnO particles were present as both individual particles and aggregated on the surface of larger particles. Also, the slag particles found in the off-gas were shown not to react with the zinc vapor. After confirming the presence of a ZnFe2O4 formation reaction, the thermodynamic feasibility of in-process separation - a new electric arc furnace dust treatment technology - was reevaluated. The large air intake and the presence of iron oxide particles in the off-gas were included into the thermodynamic calculations. The formation of the stable ZnFe2O4 spinel phase was shown to be thermodynamically favorable in current electric arc furnace off-gas ducts conditions even before reaching the post combustion chamber. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. R and D for an off-gas treatment system for a slagging pyrolysis radioactive waste incinerator. Final report for Phase I

    International Nuclear Information System (INIS)

    Christian, J.D.; Kirstein, B.E.; Pence, D.T.

    1978-01-01

    Preliminary evaluations were made of off-gas treatment needs for a slagging pyrolysis incinerator (SPI) of Andco--Torrax design for the treatment of radioactive waste at the INEL. Approximate decontamination factors (DFs) for particulates of 10 7 and for volatilized radionuclides of 10 3 will be required across the off-gas system. If lead is present in the waste at concentrations greater than 25-to-120 g/metric ton, volatilized lead will result in formation of substantial deposits in the off-gas system and regenerative towers. A review was made of radioactive incinerator development. Particulate and volatile component removal mechanisms and devices were reviewed. Three off-gas treatment systems were proposed for the SPI which will provide DFs for particulates of 10 8 . 9 figures, 7 tables

  12. Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system

    International Nuclear Information System (INIS)

    Suetens, T.; Guo, M.; Van Acker, K.; Blanpain, B.

    2015-01-01

    Highlights: • EAF dust was characterized with particle size analysis, XRF, and EPMA. • Slag particles showed no sign of reaction with Zn vapor. • Fe 2 O 3 particles showed different degrees of reaction based on their size. • The thermodynamic stability of Zn vapor in EAF off-gas ducts was reevaluated. • In presence of Fe 2 O 3 , Zn vapor reacts to form ZnFe 2 O 4 and ZnO. - Abstract: To better understand the phenomena of ZnFe 2 O 4 spinel formation in electric arc furnace dust, the dust was characterized with particle size analysis, X-ray fluorescence (XRF), electron backscatter diffraction (EBSD), and electron probe micro-analysis (EPMA). Different ZnFe 2 O 4 formation reaction extents were observed for iron oxide particles with different particle sizes. ZnO particles were present as both individual particles and aggregated on the surface of larger particles. Also, the slag particles found in the off-gas were shown not to react with the zinc vapor. After confirming the presence of a ZnFe 2 O 4 formation reaction, the thermodynamic feasibility of in-process separation – a new electric arc furnace dust treatment technology – was reevaluated. The large air intake and the presence of iron oxide particles in the off-gas were included into the thermodynamic calculations. The formation of the stable ZnFe 2 O 4 spinel phase was shown to be thermodynamically favorable in current electric arc furnace off-gas ducts conditions even before reaching the post combustion chamber

  13. Development of the preparation technology of macroporous sorbent for industrial off-gas treatment including 14C

    International Nuclear Information System (INIS)

    Cho, Il Hoon; Cho, Young Hyun; Park, Guen Il; Kim, In Tae; Kim, June Hyung; Ahn, Byung Kil

    2001-01-01

    For environmental and health effects due to increasing levels of pollution in the atmosphere, it is necessary to develop environmentally sound technologies for the treatment of greenhouse gases (CO 2 , CH 4 , CFC, etc.) and acid gases (SOx, NOx, etc.). Specifically, advanced technology for CO 2 capturing is currently one of the most important environmental issues in worldwide. 14 CO 2 , specially which has been gradually emerging issue in the nuclear facilities, is generated about 330 ppm from the CANDU (Canadian Deuterium Uranium Reactor) nuclear power plant and the DUPIC (Direct Use of spent PWR fuel in CANDU reactors) process which is the process of spent fuel treatment. For this purpose, it is necessary to develop the most efficient treatment technology of CO 2 capture by various lime materials in semi- or dry process, it should be also considering a removal performance, waste recycling and safety of disposal. In order to develop a highly active slaked lime as a sorbent for CO 2 and high temperature desulfurization, macroporous slaked lime is necessarily prepared by modified swelling process and equipment, which was developed under carrying out this project. And also for the optimal removal process of off-gases the removal performance tests of various sorbents and the effects of relative humidity and bed depth on the removal capacity must be considered

  14. Trends in the design and operation of off-gas cleaning systems in nuclear facilities

    International Nuclear Information System (INIS)

    First, M.W.

    1980-01-01

    Trends in the design and operation of off-gas cleaning systems in nuclear facilities reflect the normal development by manufacturers of new and improved equipment and the demand for more safety, greater reliability, and higher collection efficiency as an aftermath of the well publicized accident at Three Mile Island. The latter event has to be viewed as a watershed in the history of off-gas treatment requirements for nuclear facilities. It is too soon to predict what these will be with any degree of assurance but it seems reasonable to expect greatly increased interest in containment venting systems for light water and LMFBR nuclear power reactors and more stringent regulatory requirements for auxiliary off-gas cleaning systems. Although chemical and waste handling plants share few characteristics with reactors other than the presence of radioactive materials, often in large amounts, tighter requirements for handling reactor off-gases will surely be transferred to other kinds of nuclear facilities without delay. Currently employed nuclear off-gas cleaning technology was largely developed and applied during the decade of the 1950s. It is regrettable that the most efficient and most economical off-gas treatment systems do not always yield the best waste forms for storage or disposal. It is even more regrettable that waste management has ceased to be solely a technical matter but has been transformed instead into a highly charged political posture of major importance in many western nations. Little reinforcement has been provided by detailed studies of off-gas treatment equipment failures that show that approximately 13% of over 9000 licensee event reports to the United States Nuclear Regulatory Commission pertained to failures in ventilating and cleaning systems and their monitoring instruments

  15. Membrane System for the Recovery of Volatile Organic Compounds from Remediation Off-Gases. Innovative Technology Summary Report

    International Nuclear Information System (INIS)

    2001-01-01

    Membrane Technology and Research, Inc.'s (MTR's) membrane-based off-gas treatment technology separates the organic components from the off-gas stream, producing a VOC-free air stream that can be discharged or recycled to the gas-generating process. The membrane system produces a constant, high-quality air discharge stream irrespective of the feed-air composition. The system also produces a concentrated liquid VOC stream for disposal. Any water vapor present in the off-gas is removed as condensed dischargeable water. Benefits: Applicable to a broad range of off-gas generating sources. Target streams are off-gas from soil remediation by in situ vacuum extraction or air and steam sparging, and soil vitrification Suitable for remote sites: systems require minimal site preparation, little operator attention once installed, electrical power but no other utilities, and no expendable chemicals Minimizes waste volume: dischargeable air and water are produced, and VOCs removed from the feed gas ar e concentrated into a condensed liquid. No other waste streams result Treats off-gases containing both flammable and nonflammable and chlorinated and nonchlorinated VOCs Cost competitive with other technologies in the VOC concentration range 100-1,000 ppm and offers significant cost reduction at higher VOC concentrations Systems are easily moved and transported to new sites with a minimum of refurbishing or modification Generates no air emissions, minimizing permitting issues and speeding up the start of a clean-up operation Technology: Removal of VOCs from air streams with membranes is a relatively new technology

  16. Test results from the GA technologies engineering-scale off-gas treatment system

    International Nuclear Information System (INIS)

    Jensen, D.D.; Olguin, L.J.; Wilbourn, R.G.

    1984-06-01

    One method for reducing the volume of HTGR fuel prior to reprocessing or spent fuel storage is to crush and burn the graphite fuel elements. The burner off-gas (BOG) contains radioactive components, principally H-3, C-14, Kr-85, I-129, and Rn-220, as well as chemical forms such as CO 2 , CO, O 2 , and SO 2 . The BOG system employs components designed to remove these constitutents. Test results are reported for the iodine and SO 2 adsorbers and the CO/HT oxidizer. Silver-based iodine adsorbents were found to catalyze the premature conversion of CO to CO 2 . Subsequent tests showed that iodine removal could not be performed downstream of the CO/HT oxidizer since iodine in the BOG system rapidly deactivated the Pt-coated alumina CO catalyst. Lead-exchanged zeolite (PbX) was found to be an acceptable alternative for removing iodine from BOG without CO conversion. Intermittent and steady-state tests of the pilot-plant SO 2 removal unit containing sodium-exchanged zeolite (NaX) demonstrated that decontamination factors greater than or equal to 100 could be maintained for up to 50 h. In a reprocessing flowsheet, the solid product from the burners is dissolved in nitric or Thorex acid. The dissolver off-gas (DOG) contains radioactive components H-3, Kr-85, I-129, Rn-220 plus chemical forms such as nitrogen oxides (NO/sub x/). In the pilot-scale system at GA, iodine is removed from the DOG by adsorption. Tests of iodine removal have been conducted using either silver-exchanged mordenite (AgZ) or AgNO 3 -impregnated silica gel (AC-6120). Although each sorbent performed well in the presence of NO/sub x/, the silica gel adsorbent proved more efficient in silver utilization and, thus, more cost effective

  17. Protection and safety functions of different off-gas treatment systems in radioactive waste incineration

    International Nuclear Information System (INIS)

    Caramelle, D.; Chevalier, G.; Chevalier, G.

    1986-01-01

    Gaseous effluent cleaning installations are designed to protect workmen and environment and must be efficient enough to guarantee that the amounts of gases and dusts emitted by a furnace operating normally or accidentally are at an acceptable level in the atmosphere on the incinerator site. The process equipments necessary to operations and the monitoring devices must be reliable. The main risk in normal operation is occupational exposure close to the radioactive products accumulation points. The accidental risks are mainly related to an outage of the off-gas cleaning or a tightness failure with radioactive products dissemination resulting from either internal perturbation (filter tear, exhauster failure, ...) or external incident (electricity cut-off, furnace disarrangements, fire or explosion inside the incinerator). In view of these risks, it is interesting to examine the safety and protection functions of different components of off-gas treatment systems

  18. Systematic selection of off-gas treatment at the Savannah River Site

    International Nuclear Information System (INIS)

    McKillip, S.T.; Rehder, T.E.

    1992-01-01

    At the Savannah River Site (SRS), from 1958--1985, effluent waste from the reactor fuel and target rod fabrication area (M-Area) was discharged to a settling basin. In 1981, monitoring wells detected groundwater contamination, specifically trichloroethylene and tetrachloroethylene, in the immediate vicinity of the basin. Under the auspices of Resource Conservation and Recovery Act (RCRA) the M-Area contamination must be addressed by a corrective action program until the volatile organic compound (VOC) concentrations reach Drinking Water Standards. This was initiated in 1985 with startup of a full-scale pump-and-treat air stripper system. Recently, remediation efforts have focused on vacuum extraction to treat vadose zone contamination not addressed by the original recovery wells, and additional pump-and-treat systems to achieve hydraulic control of the plume. Regulatory requirements allowed for discharge of VOCs to the atmosphere when the original remediation system was installed; however, 1990 amendments to the Clean Air Act will eventually require treatment of VOC contaminated air prior to discharge. This has ramifications to systems currently being design, as well as the existing systems. In response to the 1990 Clean Air Act amendments, SRS initiated a study to assess commercially available off-gas treatment technologies. These included carbon adsorption, thermal incineration, catalytic oxidation, absorption, condensation, and UV/peroxide destruction, and xenon flashlamp. Criteria used to evaluate the technologies were the thirty (30) year life cycle cost, permitting considerations, and manpower requirements. The study concluded that catalytic oxidation provided the most desirable combination of these elements

  19. Cryogenic system for collecting noble gases from boiling water reactor off-gas

    International Nuclear Information System (INIS)

    Schmauch, G.E.

    1973-01-01

    In boiling water reactors, noncondensible gases are expelled from the main condenser. This off-gas stream is composed largely of radiolytic hydrogen and oxygen, air in-leakage, and traces of fission product krypton and xenon. In the Air Products' treatment system, the stoichiometric hydrogen and oxygen are reacted to form water in a catalytic recombiner. The design of the catalytic recombiner is an extension of industrial gas technology developed for purification of argon and helium. The off-gas after the recombiner is processed by cryogenic air-separation technology. The gas is compressed, passed into a reversing heat exchanger where water vapor and carbon dioxide are frozen out, further cooled, and expanded into a distillation column where refrigeration is provided by addition of liquid nitrogen. More than 99.99 percent of the krypton and essentially 100 percent of the xenon entering the column are accumulated in the column bottoms. Every three to six months, the noble-gas concentrate accumulated in the column bottom is removed as liquid, vaporized, diluted with steam, mixed with hydrogen in slight excess of oxygen content, and fed to a small recombiner where all the oxygen reacts to form water. The resulting gas stream, containing from 20 to 40 percent noble gases, is compressed into small storage cylinders for indefinite retention or for decay of all fission gases except krypton-85, followed by subsequent release under controlled conditions and favorable meteorology. This treatment system is based on proven technology that is practiced throughout the industrial gas industry. Only the presence of radioactive materials in the process stream and the application in a nuclear power plant environment are new. Adaptations to meet these new conditions can be made without sacrificing performance, reliability, or safety

  20. Development of the preparation technology of macroporous sorbent for industrial off-gas treatment including {sup 14}C

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Il Hoon; Cho, Young Hyun; Park, Guen Il; Kim, In Tae; Kim, June Hyung; Ahn, Byung Kil

    2001-01-01

    For environmental and health effects due to increasing levels of pollution in the atmosphere, it is necessary to develop environmentally sound technologies for the treatment of greenhouse gases (CO{sub 2}, CH{sub 4}, CFC, etc.) and acid gases (SOx, NOx, etc.). Specifically, advanced technology for CO{sub 2} capturing is currently one of the most important environmental issues in worldwide. {sup 14}CO{sub 2}, specially which has been gradually emerging issue in the nuclear facilities, is generated about 330 ppm from the CANDU (Canadian Deuterium Uranium Reactor) nuclear power plant and the DUPIC (Direct Use of spent PWR fuel in CANDU reactors) process which is the process of spent fuel treatment. For this purpose, it is necessary to develop the most efficient treatment technology of CO{sub 2} capture by various lime materials in semi- or dry process, it should be also considering a removal performance, waste recycling and safety of disposal. In order to develop a highly active slaked lime as a sorbent for CO{sub 2} and high temperature desulfurization, macroporous slaked lime is necessarily prepared by modified swelling process and equipment, which was developed under carrying out this project. And also for the optimal removal process of off-gases the removal performance tests of various sorbents and the effects of relative humidity and bed depth on the removal capacity must be considered.

  1. A plasma process controlled emissions off-gas demonstration

    International Nuclear Information System (INIS)

    Battleson, D.; Kujawa, S.T.; Leatherman, G.

    1995-01-01

    Thermal technologies are currently identified as playing an important role in the treatment of many DOE waste streams, and emissions from these processes will be scrutinized by the public, regulators, and stakeholders. For some time, there has been a hesitancy by the public to accept thermal treatment of radioactive contaminated waste because of the emissions from these processes. While the technology for treatment of emissions from these processes is well established, it is not possible to provide the public complete assurance that the system will be in compliance with air quality regulations 100% of the operating time in relation to allowing noncompliant emissions to exit the system. Because of the possibility of noncompliant emissions and the public's concern over thermal treatment systems, it has been decided that the concept of a completely controlled emissions off-gas system should be developed and implemented on Department of Energy (DOE) thermal treatment systems. While the law of conservation of mass precludes a completely closed cycle system, it is possible to apply the complete control concept to emissions

  2. Test results in the treatment of HTR reprocessing off-gas

    International Nuclear Information System (INIS)

    Barnert-Wiemer, H.; Bendick, B.; Juergens, B.; Nafissi, A.; Vygen, H.; Krill, W.

    1983-01-01

    The AKUT II-facility (throughput 10 m 3 /h, STP) for the clean up of the burner off-gas has been tested with synthetic off-gas and with off-gas from cold burner tests. The results are reported. During dissolution of the burner ash in nitric acid an off-gas is formed whose main component is air and which, besides the gaseous fission products, contains NO/sub x/. Before the separation of the gaseous fission products NO/sub x/ and/or O 2 are removed by reaction with H 2 or NH 3 . For these reactions catalysts were used. Because of the known disadvantages of catalytic systems, like reduction in efficiency by poisoning or thermal influence, the alternative method of thermal, flameless reduction was tested. The reactions were carried out in a stainless steel and a quartz reactor. Throughput, reaction temperature, O 2 -, NO/sub x/-, H 2 -, and NH 3 -concentrations respectively were varied. The goal of these tests was to remove O 2 and NO/sub x/ to below 1 ppM behind the reactor and NH 3 to below the detection limit of 50 ppM. It was found that at a reaction temperature of 750 0 C in the stainless steel reactor these goals can be reached for both H 2 and NH 3 as reducing agents. In the quartz reactor only the O 2 -H 2 -reaction takes place. Obviously stainless steel acts as a catalyst for all other reactions

  3. Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, Kathryn M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, Charles A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Crawford, Charles L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Wilmarth, William R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-01-21

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task seeks to examine the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also

  4. Emission of gaseous organic pollutants and flue gas treatment technology

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Sun, Y.

    2007-01-01

    Gaseous organic pollutants are emitted into atmosphere from various sources, creating a threat to the environment and man. New, economical technologies are needed for flue gas treatment. Emission sources of pollutants are reviewed and different treatment technologies are discussed in this report. (authors)

  5. Purification technology for flue/off gases using electron beams

    International Nuclear Information System (INIS)

    Kojima, Takuji

    2004-01-01

    The present paper describes research and development on purification technology using electron beams for flue/off gases containing pollutants: removal of sulfate oxide and nitrogen oxide from flue gases of coal/oil combustion power plants, decomposition of dioxins in waste incineration flue gas, and decomposition/removal of toxic volatile organic compounds from off gas. (author)

  6. Gas-Solid Reaction Properties of Fluorine Compounds and Solid Adsorbents for Off-Gas Treatment from Semiconductor Facility

    Directory of Open Access Journals (Sweden)

    Shinji Yasui

    2012-01-01

    Full Text Available We have been developing a new dry-type off-gas treatment system for recycling fluorine from perfluoro compounds present in off-gases from the semiconductor industry. The feature of this system is to adsorb the fluorine compounds in the exhaust gases from the decomposition furnace by using two types of solid adsorbents: the calcium carbonate in the upper layer adsorbs HF and converts it to CaF2, and the sodium bicarbonate in the lower layer adsorbs HF and SiF4 and converts them to Na2SiF6. This paper describes the fluorine compound adsorption properties of both the solid adsorbents—calcium carbonate and the sodium compound—for the optimal design of the fixation furnace. An analysis of the gas-solid reaction rate was performed from the experimental results of the breakthrough curve by using a fixed-bed reaction model, and the reaction rate constants and adsorption capacity were obtained for achieving an optimal process design.

  7. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    International Nuclear Information System (INIS)

    Vance, R.F.

    1991-12-01

    The West Valley Demonstration project was established by an act of Congress in 1980 to solidify the high level radioactive liquid wastes produced from operation of the Western New York Nuclear Services Center from 1966 to 1972. The waste will be solidified as borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems

  8. Formation of the ZnFe{sub 2}O{sub 4} phase in an electric arc furnace off-gas treatment system

    Energy Technology Data Exchange (ETDEWEB)

    Suetens, T., E-mail: thomas.suetens@mtm.kuleuven.be; Guo, M., E-mail: muxing.guo@mtm.kuleuven.be; Van Acker, K., E-mail: karel.vanacker@lrd.kuleuven.be; Blanpain, B., E-mail: bart.blanpain@mtm.kuleuven.be

    2015-04-28

    Highlights: • EAF dust was characterized with particle size analysis, XRF, and EPMA. • Slag particles showed no sign of reaction with Zn vapor. • Fe{sub 2}O{sub 3} particles showed different degrees of reaction based on their size. • The thermodynamic stability of Zn vapor in EAF off-gas ducts was reevaluated. • In presence of Fe{sub 2}O{sub 3}, Zn vapor reacts to form ZnFe{sub 2}O{sub 4} and ZnO. - Abstract: To better understand the phenomena of ZnFe{sub 2}O{sub 4} spinel formation in electric arc furnace dust, the dust was characterized with particle size analysis, X-ray fluorescence (XRF), electron backscatter diffraction (EBSD), and electron probe micro-analysis (EPMA). Different ZnFe{sub 2}O{sub 4} formation reaction extents were observed for iron oxide particles with different particle sizes. ZnO particles were present as both individual particles and aggregated on the surface of larger particles. Also, the slag particles found in the off-gas were shown not to react with the zinc vapor. After confirming the presence of a ZnFe{sub 2}O{sub 4} formation reaction, the thermodynamic feasibility of in-process separation – a new electric arc furnace dust treatment technology – was reevaluated. The large air intake and the presence of iron oxide particles in the off-gas were included into the thermodynamic calculations. The formation of the stable ZnFe{sub 2}O{sub 4} spinel phase was shown to be thermodynamically favorable in current electric arc furnace off-gas ducts conditions even before reaching the post combustion chamber.

  9. State of the art of membrane technology for treatment of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Donno, S. De

    1997-11-01

    This topic has been selected in accordance with a general interest expressed by the Gas Industry. Membranes technology is achieving industrial success in many operations for selective fluids separation. In the specific area of natural gas treatment, membranes are viewed as a technological breakthrough in the coming years despite the fact that the real entity of their potential advantage on conventional technologies has still to be clarified. Aim of this report has been an overview of the overall potentiality and present limits of the use of membranes in natural gas treatment with emphasis on requirements and conditions which could enable established applications of membranes in short to medium terms. This Committee report is based on recent literature and on the opinions of gas companies active and/or interest in technology development of membranes for naturla gas. (au) 27 refs.

  10. LABORATORY OPTIMIZATION TESTS OF TECHNETIUM DECONTAMINATION OF HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE OFF-GAS CONDENSATE SIMULANT

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, K.; Nash, C.; McCabe, D.

    2014-09-29

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also

  11. Development of high performance catalyst for off-gas treatment system in BWR

    International Nuclear Information System (INIS)

    Kawasaki, Toru; Kawabe, Kenichi; Maeda, Kiyomitsu; Matsubara, Hirofumi; Aizawa, Motohiro; Iizuka, Hidehiro; Kumagai, Naoki

    2011-01-01

    A high performance catalyst for off-gas treatment system in boiling water reactor (BWR) has been developed. The hydrogen concentration in the outlets of off-gas recombiners increased at several BWR plants in Japan. These phenomena were caused by deactivation of catalysts for the recombiners, and we assumed two types of deactivation mechanisms. The first cause was an increase of the amount of boehmite in the catalyst support due to alternation of the manufacturing process. The other cause was catalysts being poisoned by cyclic siloxanes that were introduced from the silicone sealant used in the upstream of the off-gas recombiners. The catalysts were manufactured by Pt adhering on alumina support. The conventional catalyst (CAT-A) used the aqueous solution of the chloroplatinic acid for adhesion of Pt. A dechlorination process by autoclave was applied to prevent the equipment at the downstream of the recombiners from stress corrosion cracking, but this process caused the support material to transform into boehmite. The boehmite-rich catalysts were deactivated more easily by organic silicon than gamma alumina-rich catalysts. Therefore, the CAT-A was replaced at many Japanese BWR plants by the improved catalyst (CAT-B), and their support was transformed into more stable gamma alumina by heating at 500degC. However, the siloxanes keep being detected in the off-gas though the source of siloxane had been removed and there still remain possibilities to deactivate the catalysts. Therefore, we have been developing high performance catalyst (CAT-C) that has higher activity and durability against poisoning. We investigated the properties of CAT-C by performance tests and instrumental analyses. The dependency of thermal output of nuclear reactor, and durability against siloxane poisoning were investigated. We found that CAT-C showed higher performance and better properties than CAT-B did. Moreover, we have been developing a modeling method to evaluate the hydrogen recombination

  12. Development of electron beam flue gas treatment technology

    International Nuclear Information System (INIS)

    Tanaka, T.

    1995-01-01

    The electron beam flue gas treatment technology is expected to bring many advantages such as the simultaneous reduction of SO x and NO x emissions, a dry process without waste water, valuable fertilizer byproducts, etc. In order to verify the feasibility and performances of the process, a practical application test is carried out with a pilot plant which treats the actual flue gas from a coal-fired boiler. Results are presented. 4 figs., 2 tabs

  13. Sorption Modeling and Verification for Off-Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Tavlarides, Lawrence [Syracuse Univ., NY (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Gabitto, Jorge [Prairie View Texas A& M; DePaoli, David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-12-20

    This project was successfully executed to provide valuable adsorption data and improve a comprehensive model developed in previous work by the authors. Data obtained were used in an integrated computer program to predict the behavior of adsorption columns. The model is supported by experimental data and has been shown to predict capture of off gas similar to that evolving during the reprocessing of nuclear waste. The computer program structure contains (a) equilibrium models of off-gases with the adsorbate; (b) mass-transfer models to describe off-gas mass transfer to a particle, diffusion through the pores of the particle, and adsorption on the active sites of the particle; and (c) incorporation of these models into fixed bed adsorption modeling, which includes advection through the bed. These models are being connected with the MOOSE (Multiphysics Object-Oriented Simulation Environment) software developed at the Idaho National Laboratory through DGOSPREY (Discontinuous Galerkin Off-gas SeParation and REcoverY) computer codes developed in this project. Experiments for iodine and water adsorption have been conducted on reduced silver mordenite (Ag0Z) for single layered particles. Adsorption apparatuses have been constructed to execute these experiments over a useful range of conditions for temperatures ranging from ambient to 250°C and water dew points ranging from -69 to 19°C. Experimental results were analyzed to determine mass transfer and diffusion of these gases into the particles and to determine which models best describe the single and binary component mass transfer and diffusion processes. The experimental results were also used to demonstrate the capabilities of the comprehensive models developed to predict single-particle adsorption and transients of the adsorption-desorption processes in fixed beds. Models for adsorption and mass transfer have been developed to mathematically describe adsorption kinetics and transport via diffusion and advection

  14. Analysis of Off Gas From Disintegration Process of Graphite Matrix by Electrochemical Method

    International Nuclear Information System (INIS)

    Tian Lifang; Wen Mingfen; Chen Jing

    2010-01-01

    Using electrochemical method with salt solutions as electrolyte, some gaseous substances (off gas) would be generated during the disintegration of graphite from high-temperature gas-cooled reactor fuel elements. The off gas is determined to be composed of H 2 , O 2 , N 2 , CO 2 and NO x by gas chromatography. Only about 1.5% graphite matrix is oxidized to CO 2 . Compared to the direct burning-graphite method, less off gas,especially CO 2 , is generated in the disintegration process of graphite by electrochemical method and the treatment of off gas becomes much easier. (authors)

  15. Design of off-gas and air cleaning systems at nuclear power plants

    International Nuclear Information System (INIS)

    1987-01-01

    The primary purpose of this report is to describe the current design of air and process off-gas cleaning technologies used in nuclear power plants (NPPs). Because of the large inventory of fission products that are produced in the fuel (i.e. in the range of 5x10 19 Bq per GW(e)·a) and the highly restrictive airborne radionuclide release limits being established by Member States, air and process off-gas cleaning technologies are constantly being improved to provide higher airborne radionuclide recovery efficiencies and a smaller probability of malfunction. For various technologies considered an attempt has been made to provide the following information: (a) Process description in terms of principles of off-gas and air cleaning, operating parameters and system performance; (b) Design for normal and accident situations; (c) Design of components with regard to construction materials, size, shape and geometry of the system, resistance to chemical and physical degradation from the operational environment, safety and quality assurance requirements

  16. Adsorption Model for Off-Gas Separation

    Energy Technology Data Exchange (ETDEWEB)

    Veronica J. Rutledge

    2011-03-01

    The absence of industrial scale nuclear fuel reprocessing in the U.S. has precluded the necessary driver for developing the advanced simulation capability now prevalent in so many other countries. Thus, it is essential to model complex series of unit operations to simulate, understand, and predict inherent transient behavior and feedback loops. A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes will provide substantial cost savings and many technical benefits. The specific fuel cycle separation process discussed in this report is the off-gas treatment system. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed in gPROMS software. Inputs include gas stream constituents, sorbent, and column properties, equilibrium and kinetic data, and inlet conditions. It models dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions for a multiple component gas stream. The simulation outputs component concentrations along the column length as a function of time from which the breakthrough data is obtained. It also outputs temperature along the column length as a function of time and pressure drop along the column length. Experimental data will be input into the adsorption model to develop a model specific for iodine adsorption on silver mordenite as well as model(s) specific for krypton and xenon adsorption. The model will be validated with experimental breakthrough curves. Another future off-gas modeling goal is to develop a model for the unit operation absorption. The off-gas models will be made available via the server or web for evaluation by customers.

  17. Sorption Modeling and Verification for Off-Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Tavlarides, Lawrence L. [Syracuse Univ., NY (United States); Lin, Ronghong [Syracuse Univ., NY (United States); Nan, Yue [Syracuse Univ., NY (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Ladshaw, Austin [Georgia Inst. of Technology, Atlanta, GA (United States); Sharma, Ketki [Georgia Inst. of Technology, Atlanta, GA (United States); Gabitto, Jorge [Prairie View A & M Univ., Prairie View, TX (United States); DePaoli, David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-29

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  18. Sorption Modeling and Verification for Off-Gas Treatment

    International Nuclear Information System (INIS)

    Tavlarides, Lawrence L.; Lin, Ronghong; Nan, Yue; Yiacoumi, Sotira; Tsouris, Costas; Ladshaw, Austin; Sharma, Ketki; Gabitto, Jorge; DePaoli, David

    2015-01-01

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  19. Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the New Copper Smelter RTB Bor

    Directory of Open Access Journals (Sweden)

    Dragana Ivšić-Bajčeta

    2013-09-01

    Full Text Available The previous inadequate treatment of off-gas in RTB Bor in Serbia has resulted in serious pollution of the environment and the possibly high losses of copper through the effluent flows. The project of New Copper Smelter RTB Bor, besides the new flash smelting furnace (FSF and the reconstruction of Pierce-Smith converter (PSC, includes more effective effluent treatment. Paper presents an analysis of the new FSF and PSC off-gas treatment, determination of copper losses throughout generated wastewaters and discussion of its possible valorization. Assumptions about the solubility of metals phases present in the FSF and PSC off-gas, obtained by the treatment process simulation, were compared with the leaching results of flue dusts. Determined wastewaters characteristics indicate that the PSC flow is significantly richer in copper, mostly present in insoluble metallic/sulfide form, while the FSF flow has low concentration of copper in the form of completely soluble oxide/sulfate. The possible scenario for the copper valorization, considering arsenic and lead as limiting factors, is the separation of the FSF and PSC flows, return of the metallic/sulfide solid phase to the smelting process and recovery from the sulfate/oxide liquid phase.

  20. Detection device for off-gas system accidents

    International Nuclear Information System (INIS)

    Kubota, Ryuji; Tsuruoka, Ryozo; Yamanari, Shozo.

    1984-01-01

    Purpose: To rapidly isolate the off-gas system by detecting the off-gas system failure accident in a short time. Constitution: Radiation monitors are disposed to ducts connecting an exhaust gas area and an air conditioning system as a portion of a turbine building. The ducts are disposed independently such that they ventilate only the atmosphere in the exhaust gas area and do not mix the atmosphere in the turbine building. Since radioactivity issued upon off-gas accidents to the exhaust gas area is sucked to the duct, it can be detected by radiation detection monitors in a short time after the accident. Further, since the operator judges it as the off-gas system accident, the off-gas system can be isolated in a short time after the accident. (Moriyama, K.)

  1. Organic Iodine Adsorption by AgZ under Prototypical Vessel Off-Gas Conditions

    International Nuclear Information System (INIS)

    Bruffey, Stephanie H.; Jubin, Robert Thomas; Jordan, J. A.

    2016-01-01

    U.S. regulations will require the removal of 129 I from the off-gas streams of any used nuclear fuel (UNF) reprocessing plant prior to discharge of the off-gas to the environment. Multiple off-gas streams within a UNF reprocessing plant combine prior to release, and each of these streams contains some amount of iodine. For an aqueous UNF reprocessing plant, these streams include the dissolver off-gas, the cell off-gas, the vessel off-gas (VOG), the waste off-gas and the shear off-gas. To achieve regulatory compliance, treatment of multiple off-gas streams within the plant must be performed. Preliminary studies have been completed on the adsorption of I 2 onto silver mordenite (AgZ) from prototypical VOG streams. The study reported that AgZ did adsorb I 2 from a prototypical VOG stream, but process upsets resulted in an uneven feed stream concentration. The experiments described in this document both improve the characterization of I 2 adsorption by AgZ from dilute gas streams and further extend it to include characterization of the adsorption of organic iodides (in the form of CH 3 I) onto AgZ under prototypical VOG conditions. The design of this extended duration testing was such that information about the rate of adsorption, the penetration of the iodine species, and the effect of sorbent aging on iodine removal in VOG conditions could be inferred.

  2. Organic Iodine Adsorption by AgZ under Prototypical Vessel Off-Gas Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jordan, J. A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-09-30

    U.S. regulations will require the removal of 129I from the off-gas streams of any used nuclear fuel (UNF) reprocessing plant prior to discharge of the off-gas to the environment. Multiple off-gas streams within a UNF reprocessing plant combine prior to release, and each of these streams contains some amount of iodine. For an aqueous UNF reprocessing plant, these streams include the dissolver off-gas, the cell off-gas, the vessel off-gas (VOG), the waste off-gas and the shear off-gas. To achieve regulatory compliance, treatment of multiple off-gas streams within the plant must be performed. Preliminary studies have been completed on the adsorption of I2 onto silver mordenite (AgZ) from prototypical VOG streams. The study reported that AgZ did adsorb I2 from a prototypical VOG stream, but process upsets resulted in an uneven feed stream concentration. The experiments described in this document both improve the characterization of I2 adsorption by AgZ from dilute gas streams and further extend it to include characterization of the adsorption of organic iodides (in the form of CH3I) onto AgZ under prototypical VOG conditions. The design of this extended duration testing was such that information about the rate of adsorption, the penetration of the iodine species, and the effect of sorbent aging on iodine removal in VOG conditions could be inferred.

  3. Radioactive Dry Process Material Treatment Technology Development

    Energy Technology Data Exchange (ETDEWEB)

    Park, J. J.; Hung, I. H.; Kim, K. K. (and others)

    2007-06-15

    The project 'Radioactive Dry Process Material Treatment Technology Development' aims to be normal operation for the experiments at DUPIC fuel development facility (DFDF) and safe operation of the facility through the technology developments such as remote operation, maintenance and pair of the facility, treatment of various high level process wastes and trapping of volatile process gases. DUPIC Fuel Development Facility (DFDF) can accommodate highly active nuclear materials, and now it is for fabrication of the oxide fuel by dry process characterizing the proliferation resistance. During the second stage from march 2005 to February 2007, we carried out technology development of the remote maintenance and the DFDF's safe operation, development of treatment technology for process off-gas, and development of treatment technology for PWR cladding hull and the results was described in this report.

  4. Methods of Off-Gas Flammability Control for DWPF Melter Off-Gas System at Savannah River Site

    International Nuclear Information System (INIS)

    Choi, A.S.; Iverson, D.C.

    1996-01-01

    Several key operating variables affecting off-gas flammability in a slurry-fed radioactive waste glass melter are discussed, and the methods used to prevent potential off-gas flammability are presented. Two models have played a central role in developing such methods. The first model attempts to describe the chemical events occurring during the calcining and melting steps using a multistage thermodynamic equilibrium approach, and it calculates the compositions of glass and calcine gases. Volatile feed components and calcine gases are fed to the second model which then predicts the process dynamics of the entire melter off-gas system including off-gas flammability under both steady state and various transient operating conditions. Results of recent simulation runs are also compared with available data

  5. Dissolution off-gases at the marcoule pilot facility: Iodine trapping and off-gas characterization unit

    International Nuclear Information System (INIS)

    Pouyat, D.; Vignau, B.; Roux, J.P.

    1993-01-01

    The Marcoule Pilot Reprocessing Facility (APM) reprocesses spent fuel from light water reactors and fast breeder reactors. A batch dissolution process is used with an annual throughput capacity of 5 metric tons. The off-gas treatment unit is described together with its characterization laboratory in order to highlight the functions and potential of the facilities. The objectives are consistent with the Marcoule site policy regarding diminished iodine release and investigation of the off-gas treatment process. The equipment used to meet these objectives is described from a functional standpoint. The facility implements measurement techniques to allow continuous quantitative measurements of nitrogen oxides, oxygen, iodine and krypton, as well as continuous monitoring of the demister inlet flow by γ spectrometry. Sorbents used for iodine trapping may be tested over a wide range of operating conditions (temperature, flow rate, iodine concentration) with representative dissolution off-gases. An X-ray and γ counting system is used to assess the activity of the adsorbed radionuclides, notably 129 I

  6. A review of treatment technologies for MTBE

    International Nuclear Information System (INIS)

    Bass, D.

    1995-01-01

    Available treatment technologies for methyl tertiary butyl ether (MTBE) contamination in soil, groundwater, and recovered groundwater are reviewed and assessed. MTBE contamination is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more soluble and more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Treatment of MTBE is complicated by its Henry's constant, which is lower than most other gasoline constituents. Furthermore, evidence of biodegradability of MTBE is mixed, and MTBE does not degrade rapidly abiotically. Groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater, often successfully because of its high aqueous solubility. Air sparging/soil vapor extraction is also successfully employed to treat MTBE, but its effectiveness is reduced by the low Henry's constant of MTBE. Sparging and other aerobic bioremediation approaches are hampered by the poor biodegradability of MTBE. Oxidation technologies, such as ozone injection, hold promise for rapid in situ remediation of MTBE. Treatment of recovered groundwater contaminated with MTBE is also problematic. MTBE adsorbs poorly to granular activated carbon; advanced oxidation processes are effective on MTBE, but entail high capital and operating costs; bioreactors are of questionable effectiveness on MTBE. Air stripping is usually the most cost-effective treatment technology for MTBE so long as the off gas from the air stripper can be discharged without treatment. However, off gas treatment is expensive, so groundwater is sometimes heated to reduce the requirement for stripping air

  7. Laboratory optimization tests of technetium decontamination of Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, Kathryn M.L. [Savannah River Site (SRS), Aiken, SC (United States); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States)

    2015-11-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable simplified operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  8. Off-gas control project

    International Nuclear Information System (INIS)

    Torgerson, D.F.; Smith, I.M.

    1978-06-01

    A program to develop and study off-gas abatement techniques has recently been initiated at Whiteshell Nuclear Research Establishment (WNRE). This report provides information on the properties and expected behaviour of reprocessing plant off-gases, and outlines the experimental program to be undertaken. (author)

  9. New progress in wastewater treatment technology for standard-reaching discharge in sour gas fields

    Directory of Open Access Journals (Sweden)

    Jie Yang

    2018-02-01

    Full Text Available Gas field water is generally characterized by complex contaminant components and high salinity. Its proper treatment has always been the great concern in the field of environmental protection of oil & gas fields. In this paper, the wastewater from a gas field in the Sichuan Basin with high salinity and more contaminants (e.g. sulfides was treated as a case study for the standard-reaching discharge. Lab experiments were carried out to analyze the adaptability and effectiveness of coagulation–desulfurization composite treatment technology, chemical oxidation based ammonia nitrogen removal technology and cryogenic multi-efficacy distillation technology in the treatment of wastewater in this field. The results show that the removal rate of sulfides and oils is over 90% if polymeric ferric sulfate (PFS is taken as the coagulant combined with TS-1 desulfurization agent. Besides, the removal rate of ammonia nitrogen is over 96% if CA-1 is taken as the oxidant. Finally, after the gas field water is treated by means of cryogenic three-efficacy distillation technology, chloride concentration of distilled water is below 150 mg/L and CODcr concentration is less than 60 mg/L. It is concluded that after the whole process treatment, the main contaminant indicators of wastewater in this case study can satisfy the grade one standard specified in the Integrated Wastewater Discharge Standard (GB 8978–1996 and the chloride concentration can meet the requirement of the Standards for Irrigation Water Quality (GB 5084–2005. To sum up, the above mentioned composite technologies are efficient to the wastewater treatment in sour gas fields. Keywords: Sulfide-bearing gas field water, Coagulation, Desulfurization, Chemical oxidation, Standard discharge, Ammonia nitrogen, Chloride, Cryogenic multi-efficacy distillation, Sichuan Basin

  10. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Vance, R.F. [West Valley Nuclear Services Co., Inc., NY (United States)

    1995-02-01

    The West Valley Demonstration Project was established by Public Law 96-368, the {open_quotes}West Valley Demonstration Project Act, {close_quotes} on October 1, l980. Under this act, Congress directed the Department of Energy to carry out a high level radioactive waste management demonstration project at the Western New York Nuclear Service Center in West Valley, New York. The purpose of this project is to demonstrate solidification techniques which can be used for preparing high level radioactive waste for disposal. In addition to developing this technology, the West Valley Demonstration Project Act directs the Department of Energy to: (1) develop containers suitable for permanent disposal of the high level waste; (2) transport the solidified high level waste to a Federal repository; (3) dispose of low level and transuranic waste produced under the project; and (4) decontaminate and decommission the facilities and materials associated with project activities and the storage tanks originally used to store the liquid high level radioactive waste. The process of vitrification will be used to solidify the high level radioactive liquid wastes into borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems which are used in the vitrification process.

  11. Development of membrane moisture separator for BWR off-gas system

    International Nuclear Information System (INIS)

    Ogata, H.; Kawamura, S.; Kumasaka, M.; Nishikubo, M.

    2001-01-01

    In BWR plant off-gas treatment systems, dehumidifiers are used to maintain noble gas adsorption efficiency in the first half of the charcoal hold-up units. From the perspective of simplifying and reducing the cost of such a dehumidification system, Japanese BWR utilities and plant fabricators have been developing a dehumidification system employing moisture separation membrane of the type already proven in fields such as medical instrumentation and precision measuring apparatus. The first part of this development involved laboratory testing to simulate the conditions found in an actual off-gas system, the results of which demonstrated satisfactory results in terms of moisture separation capability and membrane durability, and suggested favorable prospects for application in actual off-gas systems. Further, in-plant testing to verify moisture separation capability and membrane durability in the presence of actual gases is currently underway, with results so far suggesting that the system is capable of obtaining good moisture separation capability. (author)

  12. The development and design of the off-gas treatment system for the thermal oxide reprocessing plant (THORP) at Sellafield

    International Nuclear Information System (INIS)

    Hudson, P.I.; Buckley, C.P.; Miller, W.W.

    1995-01-01

    British Nuclear Fuels completed construction of its Thermal Oxide Reprocessing Plant (THORP) at Sellafield in 1992, at a cost of 1,850M. After Government and Regulatory approval, active commissioning was initiated on 17 January 1994. From the outset, the need to protect the workforce, the public and the environment in general from the plant's discharges was clearly recognised. The design intent was to limit radiation exposure of members of the general public to As Low as Reasonably Practicable. Furthermore no member of the most highly exposed group should receive an annual dose exceeding 50 microsieverts from either the aerial or marine discharge routes. This paper describes how the design intent has been met with respect to aerial discharges. It outlines the development programme which was undertaken to address the more demanding aspects of the performance specification. This ranged from small-scale experiments with irradiated fuel to inactive pilot plant trials and full-scale plant measurements. The resulting information was then used, with the aid of mathematical models, in the design of an off-gas treatment system which could achieve the overall goal. The principal species requiring treatment in the THORP off-gas system are iodine-129, carbon-14, nitrogen oxides (NOx), fuel dust particles and aerosols containing plutonium or mixed fission products. The paper describes the combination of abatement equipment used in different parts of the plant, including counter-current absorption columns, electrostatic precipitators, dehumidifiers and High Efficiency Particulate Air filters. Because a number of separate off-gas streams are combined before discharge, special depression control systems were developed which have already proved successful during plant commissioning. BNFL is confident that the detailed attention given to the development and design phases of the THORP off-gas system will ensure good performance when the plant moves into fully radioactive operation

  13. The development and design of the off-gas treatment system for the thermal oxide reprocessing plant (THORP) at Sellafield

    Energy Technology Data Exchange (ETDEWEB)

    Hudson, P.I. [British Nuclear Fuels, Sellafield (United Kingdom); Buckley, C.P.; Miller, W.W. [British Nuclear Fuels, Risley (United Kingdom)

    1995-02-01

    British Nuclear Fuels completed construction of its Thermal Oxide Reprocessing Plant (THORP) at Sellafield in 1992, at a cost of 1,850M. After Government and Regulatory approval, active commissioning was initiated on 17 January 1994. From the outset, the need to protect the workforce, the public and the environment in general from the plant`s discharges was clearly recognised. The design intent was to limit radiation exposure of members of the general public to As Low as Reasonably Practicable. Furthermore no member of the most highly exposed group should receive an annual dose exceeding 50 microsieverts from either the aerial or marine discharge routes. This paper describes how the design intent has been met with respect to aerial discharges. It outlines the development programme which was undertaken to address the more demanding aspects of the performance specification. This ranged from small-scale experiments with irradiated fuel to inactive pilot plant trials and full-scale plant measurements. The resulting information was then used, with the aid of mathematical models, in the design of an off-gas treatment system which could achieve the overall goal. The principal species requiring treatment in the THORP off-gas system are iodine-129, carbon-14, nitrogen oxides (NOx), fuel dust particles and aerosols containing plutonium or mixed fission products. The paper describes the combination of abatement equipment used in different parts of the plant, including counter-current absorption columns, electrostatic precipitators, dehumidifiers and High Efficiency Particulate Air filters. Because a number of separate off-gas streams are combined before discharge, special depression control systems were developed which have already proved successful during plant commissioning. BNFL is confident that the detailed attention given to the development and design phases of the THORP off-gas system will ensure good performance when the plant moves into fully radioactive operation.

  14. Concept of off-gas purification in reprocessing plants

    International Nuclear Information System (INIS)

    Henrich, E.; von Ammon, R.

    1986-01-01

    Concepts and individual processes for the off-gas purification in reprocessing plants are described which are suited to achieve a better retention of the gaseous and volatile radionuclides 129 I, 85 Kr, 14 C, and tritium. Improved and new process steps have been developed to the cold pilot plant scale. Essential individual process steps are an efficient iodine desorption from the dissolver solution, improved and new off-gas scrubs with nitric acid, a cryogenic as well as a selective absorption process for rare gas recovery plus the required prepurification steps and a process for the continuous and pressure-free fixation and storage of krypton in a metal matrix. Individual facilities have been selected and combined to investigate integrated dissolver off-gas systems. Advanced concepts based on a process using low flows and loads of all off-gas streams including the cell ventilation off-gas are briefly discussed

  15. Off-gas adsorption model and simulation - OSPREY

    Energy Technology Data Exchange (ETDEWEB)

    Rutledge, V.J. [Idaho National Laboratory, P. O. Box 1625, Idaho Falls, ID (United States)

    2013-07-01

    A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes is expected to provide substantial cost savings and many technical benefits. To support this capability, a modeling effort focused on the off-gas treatment system of a used nuclear fuel recycling facility is in progress. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed within Multi-physics Object Oriented Simulation Environment (MOOSE) developed at the Idaho National Laboratory (INL). Off-gas Separation and Recovery (OSPREY) models the adsorption of offgas constituents for dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions. Inputs to the model include gas composition, sorbent and column properties, equilibrium and kinetic data, and inlet conditions. The simulation outputs component concentrations along the column length as a function of time from which breakthrough data can be obtained. The breakthrough data can be used to determine bed capacity, which in turn can be used to size columns. In addition to concentration data, the model predicts temperature along the column length as a function of time and pressure drop along the column length. A description of the OSPREY model, results from krypton adsorption modeling and plans for modeling the behavior of iodine, xenon, and tritium will be discussed. (author)

  16. Efficient particulate scrubber for glass melter off-gas

    International Nuclear Information System (INIS)

    Wright, G.T.

    1983-01-01

    Operation of joule-heated, continuous slurry-fed melters has demonstrated that off-gas aerosols are generated by entrainment of feed slurry and vaporization of volatile species from the melt. Effective off-gas stream decontamination for these aerosols can be obtained by utilizing a suitably designed and operated wet scrubber system. Results are presented for performance tests conducted with an air aspirating-type venturi scrubber processing a simulated melter off-gas aerosol. Mass overall removal efficiencies ranged from 99.5 to 99.8%. Details of the testing program and applications for melter off-gas system design are discussed

  17. An investigation of gas separation membranes for reduction of thermal treatment emissions

    International Nuclear Information System (INIS)

    Stull, D.M.; Logsdon, B.W.

    1994-01-01

    Gas permeable membranes were evaluated for possible use as air pollution control devices on a fluidized bed catalytic incineration unit. The unit is a candidate technology for treatment of certain mixed hazardous and radioactive wastes at the Rocky Flats Plant. Cellulose acetate and polyimide membranes were tested to determine the permeance of typical off-gas components such as carbon dioxide, nitrogen, and oxygen. Multi-component permeation studies included gas mixtures containing light hydrocarbons. Experiments were also conducted to discover information about potential membrane degradation in the presence of organic compounds

  18. Electron-beam flue-gas treatment system

    International Nuclear Information System (INIS)

    Aoki, Sinji; Suzuki, Ryoji

    1994-01-01

    The damage of forests in the world due to acid rain has become serious problems, and the development of high efficiency and economical desulfurization and denitration technologies for combustion exhaust gas has been desired. Japan leads the world in exhaust gas treatment technology. The conventional technologies have been the desulfurization by lime gypsum process and the denitration by ammonia catalytic reduction process. The solution by entirely new concept is the electron beam treatment technology for exhaust gas. This technology is a dry process without drain, and does not require catalyst. The byproduct from this technology was approved as a fertilizer. The electron beam treatment technology is called EBA (electron beam with ammonia). The exhaust gas treatment technology by electron beam process is constituted by the cooling of exhaust gas, ammonia addition, electron beam irradiation and the separation of byproduct. The features of the technology are the simultaneous removal of sulfur and nitrogen oxides, dry process, the facilities are simple and the operation is easy, easy following to load variation and the utilization of byproduct. The reaction mechanism of desulfurization and denitration, the course of development, the electron beam generator, and the verifying test are reported. (K.I.)

  19. Laboratory Optimization Tests of Technetium Decontamination of Hanford Waste Treatment Plant Direct Feed Low Activity Waste Melter Off-Gas Condensate Simulant

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-12-23

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  20. Thermal treatment and competing technologies for remediation of MGP (manufactured gas plant) sites

    International Nuclear Information System (INIS)

    McGowan, T.F.; Greer, B.A.; Lawless, M.

    1995-01-01

    More than 1,500 MGP (manufactured gas plant) sites exist throughout the US. Many are contaminated with coal tar from coal-fueled gas works which produced ''town gas'' from the mid-1800s through the 1950s. Virtually all old US cities have such sites. Most are in downtown areas, as they were installed for central distribution of manufactured gas. While a few sites are CERCLA/Superfund, most are not. However, the contaminants and methods used for remediation are similar to those used for Superfund cleanups of coal tar contamination from wood-treating and coke oven facilities. Clean-up of sites is triggered by property transfers and re-development as well as releases to the environment--in particular, via ground water migration. This paper describes recent experience with high capacity/low cost thermal desorption process for this waste. It also reviews competing non-thermal technology, such as bio-treatment, capping, recycling, and dig and haul. Cost data are provided for all technologies, and a case study for thermal treatment is also presented

  1. Laboratory Optimization Tests of Decontamination of Cs, Sr, and Actinides from Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-01-06

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also substantially decrease the LAW vitrification mission duration and quantity of glass waste.

  2. Development of treatment technologies of the processing of U.S. Department of Energy mixed waste

    International Nuclear Information System (INIS)

    Backus, P.M.; Berry, J.B.; Coyle, G.J. Jr.; Lurk, P.; Wolf, S.M.

    1994-01-01

    Waste contaminated with chemically hazardous and radioactive species is defined as mixed waste. Significant technology development has been conducted for separate treatment of hazardous and radioactive waste, but technology development addressing mixed-waste treatment has been limited. In response to the need for a comprehensive and consistent approach to mixed-waste technology development, the Office of Technology Development of the US Department of Energy (DOE) has established the Mixed Waste Integrated Program. The program is identifying and evaluating treatment technologies to treat present and estimated future mixed wastes at DOE sites. The status of the technical initiatives in chemical/physical treatment, waste destruction/stabilization technology, off-gas treatment, and final waste form production/assessment is described in this paper

  3. Off-gas system data summary for the ninth run of the large slurry fed melter

    International Nuclear Information System (INIS)

    Colven, W.P.

    1983-01-01

    The ninth melter campaign successfully demonstrated extended operation of both melter and off-gas systems. Two critical problem areas associated with the handling of melter off-gases were resolved leading to firm definition of the DWPF Off-Gas Treatment System. These two concerns, wet scrubber decontamination efficiency and the reduction of solids deposition at the off-gas line entrance, were the primary focus of off-gas system studies during the 63-day run (LSFM-9). The Hydro-Sonic Scrubber was confirmed to be the superior candidate for wet scrubbing by outperforming all other scrubbers tested at the Equipment Test Facility (ETF). The two stage, steam-driven scrubber achieved consistent decontamination factors for cesium exceeding the required DWPF flowsheet DF of 50. As a result, the device was selected as the reference wet scrubber for the DWPF. The Off-Gas Film Cooling device continued to show promising results for reducing three accumulation of solid deposits at the entrance to the off-gas line. In addition, a rotating wire brush cleaning device provided easy and efficient removal of deposits which had accumulated. The combination of the two has adequately resolved the deposit accumulation problem and both devices have been incorporated in the DWPF design

  4. Development of silver impregnated alumina for iodine separation from off-gas streams

    Energy Technology Data Exchange (ETDEWEB)

    Funabashi, Kiyomi; Fukasawa, Tetsuo; Kikuchi, Makoto [Energy Research Laboratory, Hitachi (Japan)] [and others

    1995-02-01

    An inorganic iodine adsorbent, silver impregnated alumina (AgA), has been developed to separate iodine effectively from off-gas streams of nuclear facilities and to decrease the volume of waste (spent adsorbent). Iodine removal efficiency was improved at relatively high humidity by using alumina carrier with two different pore diameters. Waste volume reduction was achieved by impregnating relatively large amounts of silver into the alumina pores. The developed adsorbent was tested first with simulated off-gas streams under various experimental conditions and finally with actual off-gas streams of the Karlsruhe reprocessing plant. The decontamination factor (DF) was about 100 with the AgA bed depth of 2cm at 70% relative humidity, which was a DF one order higher than that when AgA with one pore size was used. Iodine adsorption capacity was checked by passing excess iodine into the AgA bed. Values were about 0.12 and 0.35 g-I/cm`-AgA bed for 10 and 24wt% silver impregnated AgA, respectively. The results obtained in this study demonstrated the applicability of the developed AgA to the off-gas treatment system of nuclear facilities.

  5. Treatment of the off-gas stream from the HTR reprocessing head-end

    International Nuclear Information System (INIS)

    Barnert-Wiemer, H.; Juergens, B.; Vijgen, H.

    1985-01-01

    The AKUT II-facility (nominal throughput 10 m 3 /h, STP) for the clean-up of the burner off-gas has been operated for 20 cold runs in parallel to the JUPITER reprocessing head-end. Two of these runs were continuous operation tests with a duration of 50 and 80 hours, respectively. The facility met or exceeded all design specifications. In a further test series the distillation column alone was run with pure CO 2 and two- and three-component gas mixtures to determine the flooding curves and the stage height (HETP)

  6. Off-gas recirculation system for nuclear reactors

    International Nuclear Information System (INIS)

    Eppler, M.; Lade, H.J.

    1975-01-01

    According to the invention, it is suggested to provide a buffer vessel in the ring main of the off-gas recirculation system for off-gases of a nuclear reactor to which all chambers or vessels which may contain radioactively contaminated gases are connected, within the connection line to outside air. This is to prevent the immediate release of an appreciable amount of gas to the outside air due to pressure variations conditioned by the sequence of operations - e.g. on the filling of the coolant storage. After the improvement, the released gas may be reduced to the amount of gas corresponding to the leakage gas flow entering the ring mains system. (TK) [de

  7. Recovery of krypton-85 from dissolver off-gas streams

    International Nuclear Information System (INIS)

    Law, J.P.; Lamb, K.M.

    1988-01-01

    The Rare Gas Plant at the Idaho Chemical Processing Plant Recovers fission product krypton and xenon from dissolver off gas streams. Recently the system was upgraded to allow processing of hydrogen rich dissolver off-gas streams. A trickle bed hydrogen recombiner was installed and tested. The Rare Gas Plant can now safely process gas streams containing up to 80% hydrogen

  8. Burner and dissolver off-gas treatment in HTR fuel reprocessing

    International Nuclear Information System (INIS)

    Barnert-Wiemer, H.; Heidendael, M.; Kirchner, H.; Merz, E.; Schroeder, G.; Vygen, H.

    1979-01-01

    In the reprocessing of HTR fuel, essentially all of the gaseous fission products are released during the heat-end tratment, which includes burning of the graphite matrix and dissolving of the heavy metallic residues in THOREX reagent. Three facilities for off-gas cleaning are described, the status of the facility development and test results are reported. Hot tests with a continuous dissolver for HTR-type fuel (throughput 2 kg HM/d) with a closed helium purge loop have been carried out. Preliminary results of these experiments are reported

  9. MEMBRANE SYSTEM FOR RECOVERY OF VOLATILE ORGANIC COMPOUNDS FROM REMEDIATION OFF-GASES

    International Nuclear Information System (INIS)

    Wijmans, J.G.

    2003-01-01

    In situ vacuum extraction, air or steam sparging, and vitrification are widely used to remediate soil contaminated with volatile organic compounds (VOCs). All of these processes produce a VOC-laden air stream from which the VOC must be removed before the air can be discharged or recycled to the generating process. Treatment of these off-gases is often a major portion of the cost of the remediation project. Currently, carbon adsorption and catalytic incineration are the most common methods of treating these gas streams. Membrane Technology and Research, Inc. (MTR) proposed an alternative treatment technology based on selective membranes that separate the organic components from the gas stream, producing a VOC-free air stream. This technology can be applied to off-gases produced by various remediation activities and the systems can be skid-mounted and automated for easy transportation and unattended operation. The target performance for the membrane systems is to produce clean air (less than 10 ppmv VOC) for discharge or recycle, dischargeable water (less than 1 ppmw VOC), and a concentrated liquid VOC phase. This report contains the results obtained during Phase II of a two-phase project. In Phase I, laboratory experiments were carried out to demonstrate the feasibility of the proposed approach. In the subsequent Phase II project, a demonstration system was built and operated at the McClellan Air Force Base near Sacramento, California. The membrane system was fed with off-gas from a Soil Vacuum Extraction (SVE) system. The work performed in Phase II demonstrated that the membrane system can reduce the VOC concentration in remediation off-gas to 10 ppmv, while producing a concentrated VOC phase and dischargeable water containing less than 1 ppmw VOC. However, the tests showed that the presence of 1 to 3% carbon dioxide in the SVE off-gas reduced the treatment capacity of the system by a factor of three to four. In an economic analysis, treatment costs of the membrane

  10. Financing gas plants using off balance sheet structures

    International Nuclear Information System (INIS)

    Best, R.J.; Malcolm, V.

    1999-01-01

    A means by which to finance oil and gas facilities using off balance sheet structures was presented. Off balance sheet facility financing means the sale by an oil and gas producer of a processing and/or transportation facility to a financial intermediary, who under a Management Agreement, appoints the producer as the operator of the facility. The financial intermediary charges a fixed processing fee to the producer and all the benefits and upside of ownership are retained by the producer. This paper deals specifically with a flexible off balance sheet facility financing structure that can be used to make effective use of discretionary capital which is committed to gas processing and to the construction of new gas processing facilities. Off balance sheet financing is an attractive alternative method of ownership that frees up capital that is locked into the facilities while allowing the producer to retain strategic control of the processing facility

  11. Bench scale experiments for the remediation of Hanford Waste Treatment Plant low activity waste melter off-gas condensate

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, Kathryn M.L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Poirier, Michael [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-08-11

    The Low Activity Waste (LAW) vitrification facility at the Hanford Waste Treatment and Immobilization Plant (WTP) will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The plan for disposition of this stream during baseline operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. The primary reason to recycle this stream is so that the semi-volatile 99Tc isotope eventually becomes incorporated into the glass. This stream also contains non-radioactive salt components that are problematic in the melter, so diversion of this stream to another process would eliminate recycling of these salts and would enable simplified operation of the LAW melter and the Pretreatment Facilities. This diversion from recycling this stream within WTP would have the effect of decreasing the LAW vitrification mission duration and quantity of glass waste. The concept being tested here involves removing the 99Tc so that the decontaminated aqueous stream, with the problematic salts, can be disposed elsewhere.

  12. ISOLDE Off-line Gas Leak Upgrade

    CERN Document Server

    Nielsen, Kristoffer Bested

    2017-01-01

    This study investigates gas injection system of the ISOLDE Off-line separator. A quadrupole mass spectrometer is used to analysis the composition of the gas. Based on these measurements a contamination of the injected gas is found and a system upgrade is purposed. Furthermore a calibration of the leak rate of the leak valve is made.

  13. Assessment of potential greenhouse gas mitigation of available household solid waste treatment technologies

    Directory of Open Access Journals (Sweden)

    Hoang Minh Giang

    2013-11-01

    Full Text Available Current household solid waste treatment practices in most cities in Vietnam caused a great amount of direct greenhouse gas (GHG emissions. Available solid waste treatment technologies should be seriously taken  into consideration as a wedge of GHG mitigation in waste sector base on presently Vietnamese economic conditions. This study aim to evaluate the potential amount of GHG mitigation from current domestic solid waste treatment technologies in Vietnam including landfills and composting from various management scenarios. In oder to use Tier 2 model of IPCC 2006 for GHG estimation from landfills, an analysis on current household solid waste management system of the city was obtained by using material flow analysis approach. A case study in Hanoi, the capital city of Vietnam was carried out in this research. As a result, there was a reduced of over 70% of the amount of CH4 emissions and  up to 53% of total GHG saving (CO2-eq from avoiding organic waste to landfill. In addition, applying an energy recovery from LFG system to available landfills would lead to aproximately 75% of GHG saved compare to current emission of waste sector.Doi: http://dx.doi.org/10.12777/wastech.1.1.10-16Citation: Giang, H.M.,Luong, N.D., and Huong, L.T.M.2013. Assessment of potential greenhouse gas mitigation of available household solid waste treatment technologies. . Waste Technology 1(1:6-9. Doi: http://dx.doi.org/10.12777/wastech.1.1.10-16

  14. Adsorptive separation of NOsub(x) from dissolver off-gas

    International Nuclear Information System (INIS)

    Ringel, H.

    1984-06-01

    After precleaning the dissolver off-gas contains, besides the noble gases Xe and Kr, about 0.5 vol.% each of NOsub(x) and H 2 O. For the removal of these NOsub(x) and H 2 O residues to below 1 ppm, an adsorptive gas cleaning process has been developed and tested on a lab-scale. For the process, an acid resistant molecular sieve was selected and its properties investigated with respect to application; e.g. the dependence of the adsorption capacity on temperature, gas composition and face velocity. By the operation of a lab-scale facility with 400 Nl/h continuous off-gas throughput the suitability of the adsorption process has been demonstrated for off-gas cleaning and recycling of the separated NO 2 and H 2 O to the dissolver. (orig.) [de

  15. A state-of-the-art report on the off-gas treatment technology generated from the nuclear facilities

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Won Zin; Lee, Hoo Geun; Park, Geun Il; Choi, Byung Seon; Lee, Kee Won; Cho, Il Hoon; Kim, Jung Kook; Park, Hyun Soo

    1997-10-01

    This state-of-the-art report describes various technologies for offgas treatment. It provides comprehensive treatment technologies of the extensive subject such as particulates, radioactive iodine, carbon dioxide, Kr/Xe and Cs/Ru. This report also incorporates the wastes generation and its characteristics as well as the historical and current management practices. A number of review articles by experts in various area of concern and some of the removal systems that have been designed for power plants and, particularly, for spent fuel reusing plants are also involved. As a result, it can be drawn that the drying processes for offgas treatment have much benefits in standpoints of simplicity, economy, disposal safety and resource reuse rather than the wet processes. (author). 226 refs., 38 tabs., 44 figs

  16. Technology strategy for gas technologies; Technology Target Areas; TTA8 Gas Technology

    Energy Technology Data Exchange (ETDEWEB)

    2008-07-01

    TTA8 - Gas technologies points out the various routes Norway can follow to capitalise on the vast resources of natural gas that will be produced in the years to come by developing a strong technology and competence platform. A broad view is taken for the value creation having as basis the continued gas export from NCS to Europe, but also a strong focus on development of gas resources in other parts of the world. The latter can also be seen as part of international positioning for upstream resources and does also include involvements in projects, and export of technology and products. The TTA has structured the analysis into 3 main areas: Gas transport and processing (pipeline, LNG, other); Gas conversion to fuels, chemicals and materials; CO{sub 2} management. In this report, for each of these areas, scenarios based on a gap analysis are presented. One of the key goals has been to identify pacing and emerging technologies for the next 20 years. Based on this, technologies have been mapped according to importance for future competitiveness and technology ambitions. This also includes primary funding responsibilities (public and/or industry). The road map below reflects the key issues in the proposed strategy. The base level of the figure explains areas that will have to be pursued to maintain Norway's role as a key gas and gas technology provider. The second layer represents near term options and possibilities with a reasonable risk profile that could further enhance the Norwegian position given the resources and drive to further develop this industry. As the top layer we have selected some of our 'dreams', what we may achieve if a progressive approach is followed with a strongly innovation based policy. It is acknowledged by the TTA that Norway cannot be a leading technology player in all aspects of the gas value chain. For some technologies we should be an active player and developer, whilst for other technologies we should become a competent buyer and user. This

  17. Technology strategy for gas technologies; Technology Target Areas; TTA8 Gas Technology

    Energy Technology Data Exchange (ETDEWEB)

    2008-07-01

    TTA8 - Gas technologies points out the various routes Norway can follow to capitalise on the vast resources of natural gas that will be produced in the years to come by developing a strong technology and competence platform. A broad view is taken for the value creation having as basis the continued gas export from NCS to Europe, but also a strong focus on development of gas resources in other parts of the world. The latter can also be seen as part of international positioning for upstream resources and does also include involvements in projects, and export of technology and products. The TTA has structured the analysis into 3 main areas: Gas transport and processing (pipeline, LNG, other); Gas conversion to fuels, chemicals and materials; CO{sub 2} management. In this report, for each of these areas, scenarios based on a gap analysis are presented. One of the key goals has been to identify pacing and emerging technologies for the next 20 years. Based on this, technologies have been mapped according to importance for future competitiveness and technology ambitions. This also includes primary funding responsibilities (public and/or industry). The road map below reflects the key issues in the proposed strategy. The base level of the figure explains areas that will have to be pursued to maintain Norway's role as a key gas and gas technology provider. The second layer represents near term options and possibilities with a reasonable risk profile that could further enhance the Norwegian position given the resources and drive to further develop this industry. As the top layer we have selected some of our 'dreams', what we may achieve if a progressive approach is followed with a strongly innovation based policy. It is acknowledged by the TTA that Norway cannot be a leading technology player in all aspects of the gas value chain. For some technologies we should be an active player and developer, whilst for other technologies we should become a competent buyer

  18. Vermont Yankee advanced off-gas system (AOG)

    International Nuclear Information System (INIS)

    Littlefield, P.S.; Miller, S.R.; DerHagopian, H.

    1975-01-01

    Early in 1971 the Vermont Yankee Nuclear Power Corporation decided to modify the existing off-gas delay system to reduce the release of noble gas isotopes from its boiling water reactor. This modification included a subsystem for recombining the radiolytic hydrogen and oxygen from the reactor and a series of adsorber tanks filled with activated carbon to delay the noble gas isotopes from the condenser air ejectors. The off-gas system and its operating history from initial operation in November 1973 to the present time are described. Data are also presented on the measured dynamic adsorption coefficient of the ambient carbon subsystem. Laboratory adsorption tests were conducted on the carbon prior to AOG startup and the results are compared with the effective coefficients obtained under operating conditions. (U.S.)

  19. Method for treating a nuclear process off-gas stream

    International Nuclear Information System (INIS)

    Pence, D.T.; Chou, C.-C.

    1981-01-01

    A method is described for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. The method involves a sequence of adsorption and desorption steps which are specified. Particular reference is made to the separation of xenon and krypton from the off-gas stream, and to the use of silver-exchanged mordenite as the adsorbent. (U.K.)

  20. Thermal treatment and non-thermal technologies for remediation of manufactured gas plant sites

    International Nuclear Information System (INIS)

    McGowan, T.F.; Greer, B.A.; Lawless, M.

    1996-01-01

    More than 1,500 manufactured gas plant (MGP) sites exist throughout the US. Many are contaminated with coal tar from coal-fueled gas works which produced town gas from the mid-1800s through the 1950s. Virtually all old US cities have such sites. Most are in downtown areas as they were installed for central distribution of manufactured gas. While a few sites are CERCLA/Superfund, most are not. However, the contaminants and methods used for remediation are similar to those used for Superfund clean-ups of coal tar contamination from wood-treating and coke oven facilities. Clean-up of sites is triggered by regulatory pressure, property transfers and re-development as well as releases to the environment--in particular, via groundwater migration. Due to utility de-regulation, site clean-ups may also be triggered by sale of a utility or of a specific utility site to other utilities. Utilities have used two approaches in dealing with their MGP sites. The first is do nothing and hope for the best. History suggests that, sooner or later, these sites become a bigger problem via a release, citizen lawsuit or regulatory/public service commission intervention. The second, far better approach is to define the problem now and make plans /for waste treatment or immobilization. This paper describes recent experience with a high capacity/low cost thermal desorption process for this waste and reviews non-thermal technology, such as bio-treatment, capping, recycling, and dig and haul. Cost data are provided for all technologies, and a case study for thermal treatment is also presented

  1. Development of off-gas filters for reprocessing plants. Development and construction of an off-gas filter system for large reprocessing plants. Off-gas section of the resolver test stand of the IHCh

    International Nuclear Information System (INIS)

    Furrer, J.; Kaempffer, R.; Wilhelm, J.G.; Pfauter, C.; Jannakos, K.; Apenberg, W.; Lange, W.; Mendel, W.; Potgeter, G.; Zabel, G.

    1976-01-01

    The test of the highly impregnated iodine sorption material AC 6,120 was continued in the laboratory under simulated conditions of a 1,500 t/a uranium reprocessing plant. The influence of NO in nitrogen as the carrier gas on the removal efficiency of the sorption material has been especially examined. Several experiments on the removal efficiency of iodine sorption by the material AC 6,120 were carried out in the original off-gas of the French processing plant SAP Marcoule while the filter system was installed on the one side directly behind the dissolver and on the other side behind the iodine desorption columm. The first iodine filter developed at LAF II was installed in the off-gas line of the dissolver in the Karlsruhe reprocessing plant. The filter system for the dissolver off-gas handling test rig of the IHCh was specified and ordered with an engineering firm. The conception of the prototype off-gas filter system was selected and a lock and transport system allowing to replace filters was designed and subjected for testing. Five alternative solutions were set up in order to find the appropriate filter concept. The method of selection based on the evaluation of performance criteria. According to the selected solution a filter drum was designed and constructed. The lock of the filter system has been designed and realized. Preliminary tests have been made. (orig.) [de

  2. In situ gas treatment technology demonstration test plan

    International Nuclear Information System (INIS)

    Thornton, E.C.; Miller, R.D.

    1996-01-01

    This document defines the objectives and requirements associated with undertaking a field demonstration of an in situ gas treatment appoach to remediation chromate-contaminated soil. The major tasks presented in this plan include the design and development of the surface gas treatment system, performance of permitting activities, and completion of site preparation and field testing activities

  3. Development of electron beam flue gas treatment technology

    International Nuclear Information System (INIS)

    Tokunaga, Okihiro; Namba, Hideki; Tanaka, Tadashi; Ogura, Yoshimi; Doi, Yoshitake; Aoki, Shinji; Izutsu, Masahiro.

    1995-01-01

    Smoke treatment system making use of electron beam irradiation made it possible to simultaneously eliminate SOx and NOn from exhaust gas. The fundamental study of the system was started in the seventies and at present, its application in practical use is under way. A pilot plant for the smoke treatment system was constructed in cooperation of Chubu Electric Power Company, Inc., Japan Atomic Energy Research Institute and Ebara Corporation and several tests with the actual exhaust gas were conducted during the period, Oct. 1992-Dec. 1993 and the treatment efficiency and the control capacity of this system was confirmed to be so high as the conventional systems and many engineering data were obtained. A high treatment efficiency (>94% for desulfurization and >80% for denitrification) was obtainable by choosing the optimum irradiation amount of electron beam and the optimum temperature of gas to treat. And this system was found superior from a financial aspect to the conventional smoke treatment system. (M.N.)

  4. Preface: Workshop on Off-Grid Technology Systems

    Science.gov (United States)

    Alonso-Marroquin, Fernando

    2017-06-01

    Off-grid houses are dwellings that do not rely on water supply, sewer, or electrical power grid, and are able to operate independently of all public utility services. These houses are ideal for remote communities or population suffering natural or human-made disasters. Our aim is to develop compact and affordable off-grid technologies by integrating high-end nano-engineering with systems that imitates natural biological processes. The key areas of focus in the workshop were: solar energy harvesting using nanotechnology, wind energy harvesting from vertical-axis wind turbines, supercapacitors energy storage systems, treatment of greywater, and green roofs to achieve air comfort.

  5. Olefin recovery from FCC off-gas can pay off

    International Nuclear Information System (INIS)

    Brahn, M.G.

    1992-01-01

    This paper reports on olefins recovery from refinery FCC offgas streams which offers an attractive cash flow from olefins from a tail-gas stream that has typically been consumed as refinery fuel. Such recovery schemes can be employed in refineries or olefins plants, and can be tailored to fit individual requirements. Mobil Chemical Co. has operated such a dephlegmator-based off-gas recovery unit at its Beaumont, Tex., olefin plant since 1987. It reported that the project was paid out within 11 months of initial start-up

  6. Technology for commercial radioactive waste management

    International Nuclear Information System (INIS)

    1979-05-01

    Conceptual processes and facilities for treating gaseous and various transuranium (TRU) wastes produced during the past fission portion of the light water reactor fuel cycle are described in volume 2. The goal of the treatment process for TRU wastes and for long-lived radionuclides removed from the gaseous waste streams is to convert these wastes to stable products suitable for placement in geologic isolation repositories. The treatment concepts are based on available technology. They do not necessarily represent an optimum design but are representative of what could be achieved with current technology. In actual applications it is reasonable to expect that there could be some improvement over these concepts that might be reflected in either lower costs or lower environmental impacts or both. These conceptual descriptions do provide a reasonable basis for cost analysis and for development of estimates of environmental impacts. The waste treatment technologies considered here include: high-level waste solidification, packaging of fuel residue, failed equipment and noncombustible waste treatment, general trash and combustible waste treatment, degraded solvent treatment, dilute aqueous waste pretreatment, immobilization of wet and solid wastes, off-gas particle removal systems, fuel reprocessing plant dissolver off-gas treatment, process off-gas treatment, and fuel reprocessing plant atmospheric protection system

  7. Radon depletion in xenon boil-off gas

    Energy Technology Data Exchange (ETDEWEB)

    Bruenner, S.; Cichon, D.; Lindemann, S.; Undagoitia, T.M.; Simgen, H. [Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany)

    2017-03-15

    An important background in detectors using liquid xenon for rare event searches arises from the decays of radon and its daughters. We report for the first time a reduction of {sup 222}Rn in the gas phase above a liquid xenon reservoir. We show a reduction factor of >or similar 4 for the {sup 222}Rn concentration in boil-off xenon gas compared to the radon enriched liquid phase. A semiconductor-based α-detector and miniaturized proportional counters are used to detect the radon. As the radon depletion in the boil-off gas is understood as a single-stage distillation process, this result establishes the suitability of cryogenic distillation to separate radon from xenon down to the 10{sup -15} mol/mol level. (orig.)

  8. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    Energy Technology Data Exchange (ETDEWEB)

    Adamson, Duane J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, Charles A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Crawford, Charles L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Wilmarth, William R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-01-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

  9. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    International Nuclear Information System (INIS)

    Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

    2014-01-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

  10. Development of thermal conditioning technology for alpha-contaminated wastes

    International Nuclear Information System (INIS)

    Kim, Joon Hyung; Kim, H. Y.; Kim, J. G.

    2001-04-01

    To develop a thermal conditioning technology for alpha-contaminated wastes, which are presumed to generate from pyrochemical processing of spent fuel, research on the three different fields have been performed; incineration, off-gas treatment, and vitrification/cementation technology. Through the assessment on the amount of alpha-contaminated waste and incineration characterises, an oxygen-enriched incineration process, which can greatly reduce the off-gas volume, was developed by our own technology. Trial burn test with paper waste resulted in a reduction of off-gas volume by 3.5. A study on the behavior and adsorption of nuclides/heavy metals at high-temperature was performed to develop an efficient removal technology. Off-gas treatment technologies for radioiodine at high-temperature and 14 CO 2 , acidic gases, and radioactive gaseous wastes such as Xe/Kr at room temperature were established. As a part of development of high-level waste solidification technology, manufacture of high-frequency induction melter, fabrication and characterization of base-glass media fabricated with spent HEPA filter medium, and development of titanate ceramic material as a precursor of SYNROC by a self-combustion method were performed. To develop alpha-contaminated waste solidification technology, a process to convert periodontal in the cement matrix to calcite with SuperCritical Carbon Dioxide (SCCD) was manufactured. The SCCD treatment enhanced the physicochemical properties of cement matrices, which increase the long-term integrity of cement waste forms during transportation and storage

  11. Method for treating a nuclear process off-gas stream

    International Nuclear Information System (INIS)

    Pence, D.T.; Chou, C.C.

    1984-01-01

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO /SUB x/ , hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140 0 to -160 0 C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140 0 to -160 0 C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton

  12. Method for treating a nuclear process off-gas stream

    Science.gov (United States)

    Pence, Dallas T.; Chou, Chun-Chao

    1984-01-01

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  13. Fatigue life analysis of cracked gas receiver of emergency cut-off system in gas gathering station

    Science.gov (United States)

    Hu, Junzhi; Zhou, Jiyong; Li, Siyuan

    2017-06-01

    Small-scale air compressor and gas receiver are used as the driving gas of the emergency cut-off system in gas gathering station. Operation of block valve is ensured by starting and stopping compressor automatically. The frequent start-stop of compressor and the pressure fluctuation pose a threat to the service life of gas receiver, and then affect normal operation of the emergency cut-off system and security of gas gathering station. In this paper, the fatigue life of a pressure vessel with axial semi-elliptical surface crack in the inner wall is analyzed under the varying pressure by means of the theory of fracture mechanics. The influences of the amplitude of pressure fluctuation and the initial crack size on the residual life of gas receiver are discussed. It provides a basis for setting the working parameters of gas receiver of emergency cut-off system and determining the maintenance cycle.

  14. DWPF Melter Off-Gas Flammability Assessment for Sludge Batch 9

    Energy Technology Data Exchange (ETDEWEB)

    Choi, A. S. [Savannah River Site (SRS), Aiken, SC (United States)

    2016-07-11

    The slurry feed to the Defense Waste Processing Facility (DWPF) melter contains several organic carbon species that decompose in the cold cap and produce flammable gases that could accumulate in the off-gas system and create potential flammability hazard. To mitigate such a hazard, DWPF has implemented a strategy to impose the Technical Safety Requirement (TSR) limits on all key operating variables affecting off-gas flammability and operate the melter within those limits using both hardwired/software interlocks and administrative controls. The operating variables that are currently being controlled include; (1) total organic carbon (TOC), (2) air purges for combustion and dilution, (3) melter vapor space temperature, and (4) feed rate. The safety basis limits for these operating variables are determined using two computer models, 4-stage cold cap and Melter Off-Gas (MOG) dynamics models, under the baseline upset scenario - a surge in off-gas flow due to the inherent cold cap instabilities in the slurry-fed melter.

  15. Carbon dioxide-krypton separation and radon removal from nuclear-fuel-reprocessing off-gas streams

    International Nuclear Information System (INIS)

    Hirsch, P.M.; Higuchi, K.Y.; Abraham, L.

    1982-07-01

    General Atomic Company (GA) is conducting pilot-plant-scale tests that simulate the treatment of radioactive and other noxious volatile and gaseous constituents of off-gas streams from nuclear reprocessing plants. This paper reports the results of engineering-scale tests performed on the CO 2 /krypton separation and radon holdup/decay subsystems of the GA integrated off-gas treatment system. Separation of CO 2 from krypton-containing gas streams is necessary to facilitate subsequent waste processing and krypton storage. Molecular sieve 5A achieved this separation in dissolver off-gas streams containing relatively low krypton and CO 2 concentrations and in krypton-rich product streams from processes such as the krypton absorption in liquid carbon dioxide (KALC) process. The CO 2 /krypton separation unit is a 30.5-cm-diameter x 1.8-m-long column containing molecular sieve 5A. The loading capacity for CO 2 was determined for gas mixtures containing 250 ppM to 2.2% CO 2 and 170 to 750 ppM krypton in either N 2 or air. Gas streams rich in CO 2 were diluted with N 2 to reduce the temperature rise from the heat of adsorption, which would otherwise affect loading capacity. The effluent CO 2 concentration prior to breakthrough was less than 10 ppM, and the adsorption capacity for krypton was negligible. Krypton was monitored on-line with a time-of-flight mass spectrometer and its concentration determined quantitatively by a method of continuous analysis, i.e., selected-ion monitoring. Radon-220 was treated by holdup and decay on a column of synthetic H-mordenite. The Rn-220 concentration was monitored on-line with flow-through diffused-junction alpha detectors. Single-channel analyzers were utilized to isolate the 6.287-MeV alpha energy band characteristic of Rn-220 decay from energy bands due to daughter products

  16. Off-Gas Adsorption Model Capabilities and Recommendations

    Energy Technology Data Exchange (ETDEWEB)

    Lyon, Kevin L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Welty, Amy K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Law, Jack [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ladshaw, Austin [Georgia Inst. of Technology, Atlanta, GA (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-03-01

    Off-gas treatment is required to reduce emissions from aqueous fuel reprocessing. Evaluating the products of innovative gas adsorption research requires increased computational simulation capability to more effectively transition from fundamental research to operational design. Early modeling efforts produced the Off-Gas SeParation and REcoverY (OSPREY) model that, while efficient in terms of computation time, was of limited value for complex systems. However, the computational and programming lessons learned in development of the initial model were used to develop Discontinuous Galerkin OSPREY (DGOSPREY), a more effective model. Initial comparisons between OSPREY and DGOSPREY show that, while OSPREY does reasonably well to capture the initial breakthrough time, it displays far too much numerical dispersion to accurately capture the real shape of the breakthrough curves. DGOSPREY is a much better tool as it utilizes a more stable set of numerical methods. In addition, DGOSPREY has shown the capability to capture complex, multispecies adsorption behavior, while OSPREY currently only works for a single adsorbing species. This capability makes DGOSPREY ultimately a more practical tool for real world simulations involving many different gas species. While DGOSPREY has initially performed very well, there is still need for improvement. The current state of DGOSPREY does not include any micro-scale adsorption kinetics and therefore assumes instantaneous adsorption. This is a major source of error in predicting water vapor breakthrough because the kinetics of that adsorption mechanism is particularly slow. However, this deficiency can be remedied by building kinetic kernels into DGOSPREY. Another source of error in DGOSPREY stems from data gaps in single species, such as Kr and Xe, isotherms. Since isotherm data for each gas is currently available at a single temperature, the model is unable to predict adsorption at temperatures outside of the set of data currently

  17. Iodine Adsorption by Ag-Aerogel under Prototypical Vessel Off-Gas Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-08-01

    U.S. regulations will require the removal of 129I from the off-gas streams of any used nuclear fuel (UNF) reprocessing plant prior to discharge of the off-gas to the environment. The required plant decontamination factor for iodine will vary based on fuel burnup, cooling time, and other factors but is very likely to be >1000 and could be as high as 8000. Multiple off-gas streams within a UNF reprocessing plant combine prior to environmental release, and each of these streams contains some amount of iodine. To achieve the decontamination factors (DFs) that are likely to be required by regulations, iodine removal from the vessel off-gas will be necessary. The vessel off-gas contains iodine at very dilute concentrations (ppb levels), and will also contain water vapor. Iodine species present are likely to include both elemental and organic iodides. There will also be solvent vapors and volatile radiolysis products. The United States has considered the use of silver-based sorbents for removal of iodine from UNF off-gas streams, but little is known about the behavior of those sorbents at very dilute iodine concentrations. The purpose of this study was to expose silver-functionalized silica aerogel (AgAerogel) to a prototypical vessel off-gas stream containing 40 ppb methyl iodide to obtain information about organic iodine capture by silver-sorbents at very low iodine concentrations. The design of this extended duration testing was such that information about the rate of adsorption, the penetration of the iodine species, and the overall system DF could be obtained. Results show that CH3I penetrates into a AgAerogel sorbent bed to a depth of 3.9 cm under prototypical vessel off-gas conditions. An iodine loading of 22 mg I/g AgAerogel was observed in the first 0.3 cm of the bed. Of the iodine delivered to the system, 48% could not be accounted for, and future efforts will investigate this concern. Direct calculation of the decontamination factor is not

  18. Fiat Chrysler Application for Alternative Methodology for Off-Cycle Technology Credits: Engine and Transmission Warmup

    Science.gov (United States)

    FCA Group LLC request to the EPA regarding greenhouse gas, off-cycle CO2 credits for Active Engine Warm Up used in 2011-2013 model year vehicles and Active Transmission Warm Up Technologies used in 2013 model year vehicles.

  19. Evaluation of off-gas characteristics in vitrification process of ion-exchange resin

    International Nuclear Information System (INIS)

    Park, S. C.; Kim, H. S.; Yang, K. H.; Yun, C. H.; Hwang, T. W.; Shin, S. W.

    2001-01-01

    The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it's burning condition inside CCM. The calculated off-gas flow rate was 67.9 Nm 3 /h at the burning rate of 40 kg/h. And the composition of off-gas was evaluated as CO 2 (41.4%), Steam (40.0%), O 2 (13.3%), NO (3.6%), and SO 2 (1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3 Nm 3 /h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin. (author)

  20. Design report: An off gas trapping system for a voloxidizer in INL of US

    International Nuclear Information System (INIS)

    Jung, I. H.; Shin, J. M.; Park, J. J.; Park, G. I.; Lee, H. H.

    2006-09-01

    This reports on the 'Development of Voloxidation Process for Treatment of LWR Spent Fuel', and it is the second year since it has started from June 2004 as a tripartite cooperation project among KAERI(Korea Atomic Energy Research Institute), INL(Idaho National Laboratory) and ORNL(Oak Ridge National Laboratory). This report is described mainly for the Task B2 accomplished during the second project year. The Task B2 in proposal contains two sub-tasks. The first one is design of an off-gas treatment system for a voloxidizer to be used in HFEF of INL. For this, KAERI team developed the design of INL OTS (Off-gas Treatment System) for hot experiment in the HFEF. INL team modified and completed the design of the INL OTS. The second task is manufacturing and test operation of the INL OTS for a voloxidizer in the INL. Manufacturing of the OTS is accomplished by INL team with co-work of KAERI. KAERI provided four sets of trapping filters needed for conducting hot experiment in the INL HFEF

  1. Development of treatment technologies for the processing of US Department of Energy mixed waste

    International Nuclear Information System (INIS)

    Backus, P.M.; Berry, J.B.; Coyle, G.J.; Lurk, P.W.; Wolf, S.M.

    1993-01-01

    Waste contaminated with chemically hazardous and radioactive species is defined as mixed waste. Significant technology development has been conducted for separate treatment of hazardous and radioactive waste, but technology development addressing mixed-waste treatment has been limited. Management of mixed waste requires treatment which must meet the standards established by the US Environmental Protection Agency for the specific hazardous constituents while also providing adequate control of the radionuclides. Technology has not been developed, demonstrated, or tested to produce a low-risk final waste form specifically for mixed waste. Throughout the US Department of Energy (DOE) complex, mixed waste is a problem because definitive treatment standards have not been established and few disposal facilities are available. Treatment capability and capacity are also limited. Site-specific solutions to the management of mixed waste have been initiated; however, site-specific programs result in duplication of technology development between various sites. Significant progress is being made in developing technology for mixed waste under the Mixed Waste Integrated Program. The status of the technical initiatives in chemical/physical treatment, destruction/stabilization technology, off-gas treatment, and final waste form production/assessment is described in this paper

  2. Evaluation of Ruthenium Capture Methods for Tritium Pretreatment Off-Gas Streams

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, Barry B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Strachan, Denis M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-07-01

    In the reprocessing of used nuclear fuel, radioactive elements are released into various plant off-gas streams. While much research and development has focused on the abatement of the volatile nuclides 3H, 14C, 85Kr, and 129I, the potential release of semivolatile isotopes that could also report to the off-gas streams in a reprocessing facility has been examined. Ruthenium (as 106Ru) has been identified as one of the semivolatile nuclides requiring the greatest degree of abatement prior to discharging the plant off-gas to the environment.

  3. Off-highway vehicle technology roadmap.; TOPICAL

    International Nuclear Information System (INIS)

    NONE

    2002-01-01

    The off-highway sector is under increasing pressure to reduce operating costs (including fuel costs) and to reduce emissions. Recognizing this, the Society of Automotive Engineers and the U.S. Department of Energy (DOE) convened a workshop in April 2001 (ANL 2001) to (1) determine the interest of the off-highway sector (consisting of agriculture, construction, surface mining, inland marine) in crafting a shared vision of off-highway, heavy machines of the future and (2) identify critical research and development (R and D) needs for minimizing off-highway vehicle emissions while cost-effectively maintaining or enhancing system performance. The workshop also enabled government and industry participants to exchange information. During the workshop, it became clear that the challenges facing the heavy, surface-based off-highway sector can be addressed in three major machine categories: (1) engine/aftertreatment and fuels/lubes, (2) machine systems, and (3) thermal management. Working groups convened to address these topical areas. The status of off-highway technologies was determined, critical technical barriers to achieving future emission standards were identified, and strategies and technologies for reducing fuel consumption were discussed. Priority areas for R and D were identified. Given the apparent success of the discussions at the workshop, several participants from industry agreed to help in the formation of a joint industry/government ''roadmap'' team. The U.S. Department of Energy's Office of Heavy Vehicle Technologies has an extensive role in researching ways to make heavy-duty trucks and trains more efficient, with respect to both fuel usage and air emissions. The workshop participants felt that a joint industry/government research program that addresses the unique needs of the off-highway sector would complement the current research program for highway vehicles. With industry expertise, in-kind contributions, and federal government funding (coupled with

  4. Development of a 'wet' variant of electron beam gas treatment technology adapted to economic and technological conditions of developing countries to remove NOx, SO2 and particulates from flue gas and produce fertilizers

    International Nuclear Information System (INIS)

    Fainchtein, O.L.; Piotrovskiy, V.V.; Savenkov, A.S.; Smirnov, I.K.; Salimov, R.A.

    1998-01-01

    The Institute Energostal with its co-authors has carried out real gas tests of the EB flue gas treatment technology at a 1000 m 3 /h experimental installation at Lipetsk Metallurgical Plant (Lipetsk, Russia), including agricultural tests to utilize the by-product. On the basis of the results obtained, a ''wet'' variant of the EB technology has been developed. A conceptual, basic and working design was engineered for a 100,000 m 3 /h EB demonstration unit at Slavyanskaya Power Plant (Donbass, Ukraine). In a ''wet'' variant of the technology, the following problems are believed to be harmoniously solved: reduction of power consumption for irradiation due to heterogenous reactions based on the so-called droplet mechanism, efficiency and reliability of collecting ammonia salts by wet dust catchers, wet granulation of the by-product using traditional equipment. A ''wet'' variant of the EB technology has a low capital cost and requires less floor area. Therefore, despite all its disadvantages typical for any wet method of gas purification, the ''wet'' EB technology can find its application in developing countries with low levels of economy. In many countries of this type, in particular, in the countries of the former Soviet Union, wet methods of gas treatment and fertilizer granulation are still widely used. As a matter of fact, it is a conventionally ''wet'' method (hence the inverted commas), since no waste water is discharged into the environment

  5. Technology spin-offs generation – a multicase study

    Directory of Open Access Journals (Sweden)

    Jonas Mendes Constante

    2014-05-01

    Full Text Available The objective of this study is to understand how small businesses can innovate through the generation of technological spin-offs, identifying motivations, influences and barriers to achieving this phenomenon. Through a qualitative and exploratory study, we analyzed four cases of technological spin-offs in Santa Catarina State. We collected data through field observations, historical data and semi-structured interviews. The main reasons found for spin-offs creation were: diversification and to complement the value chain of the parent company and to ensure greater focus for a specific technology. The main barrier was lack of capital. Government initiatives to support the creation of new businesses, coupled with the organizational culture open to entrepreneurship and investment in R&D, contributed to the development of spin-offs analyzed. This work contributes to the understanding that small and medium-sized technology-based companies are a source of technological spin-offs and can benefit from the occurrence of this process.

  6. Mixed Waste Integrated Program -- Problem-oriented technology development

    International Nuclear Information System (INIS)

    Hart, P.W.; Wolf, S.W.; Berry, J.B.

    1994-01-01

    The Mixed Waste Integrated Program (MWIP) is responding to the need for DOE mixed waste treatment technologies that meet these dual regulatory requirements. MWIP is developing emerging and innovative treatment technologies to determine process feasibility. Technology demonstrations will be used to determine whether processes are superior to existing technologies in reducing risk, minimizing life-cycle cost, and improving process performance. Technology development is ongoing in technical areas required to process mixed waste: materials handling, chemical/physical treatment, waste destruction, off-gas treatment, final forms, and process monitoring/control. MWIP is currently developing a suite of technologies to process heterogeneous waste. One robust process is the fixed-hearth plasma-arc process that is being developed to treat a wide variety of contaminated materials with minimal characterization. Additional processes encompass steam reforming, including treatment of waste under the debris rule. Advanced off-gas systems are also being developed. Vitrification technologies are being demonstrated for the treatment of homogeneous wastes such as incinerator ash and sludge. An alternative to conventional evaporation for liquid removal--freeze crystallization--is being investigated. Since mercury is present in numerous waste streams, mercury removal technologies are being developed

  7. Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443

    Energy Technology Data Exchange (ETDEWEB)

    Ramsey, William G.; Esparza, Brian P. [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)

    2013-07-01

    Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

  8. Fabrication of ATALANTE Dissolver Off-Gas Sorbent-Based Capture System

    Energy Technology Data Exchange (ETDEWEB)

    Walker, Jr., Joseph Franklin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-30

    A small sorbent-based capture system was designed that could be placed in the off-gas line from the fuel dissolver in the ATALANTE hot cells with minimal modifications to the ATALANTE dissolver off-gas system. Discussions with personnel from the ATALANTE facility provided guidance that was used for the design. All components for this system have been specified, procured, and received on site at Oak Ridge National Laboratory (ORNL), meeting the April 30, 2015, milestone for completing the fabrication of the ATALANTE dissolver off-gas capture system. This system will be tested at ORNL to verify operation and to ensure that all design requirements for ATALANTE are met. Modifications to the system will be made, as indicated by the testing, before the system is shipped to ATALANTE for installation in the hot cell facility.

  9. Modelling of EAF off-gas post combustion in dedusting systems using CFD methods

    Energy Technology Data Exchange (ETDEWEB)

    Tang, X.; Kirschen, M.; Pfeifer, H. [Inst. for Industrial Furnaces and Heat Engineering in Metallurgy, RWTH Aachen, Aachen (Germany); Abel, M. [VAI-Fuchs GmbH, Willstaett (Germany)

    2003-04-01

    To comply with the increasingly strict environmental regulations, the poisonous off-gas species, e.g. carbon monoxide (CO), produced in the electric arc furnace (EAF) must be treated in the dedusting system. In this work, gas flow patterns of the off-gas post combustion in three different dedusting system units were simulated with a computational fluid dynamics (CFD) code: (1) post combustion in a horizontal off-gas duct, (2) post combustion in a water cooled post combustion chamber without additional energy supply (no gas or air/oxygen injectors) and (3) post combustion in a post combustion chamber with additional energy input (gas, air injectors and ignition burner, case study of VAI-Fuchs GmbH). All computational results are illustrated with gas velocity, temperature distribution and chemical species concentration fields for the above three cases. In case 1, the effect of different false air volume flow rates at the gap between EAF elbow and exhaust gas duct on the external post combustion of the off-gas was investigated. For case 2, the computed temperature and chemical composition (CO, CO{sub 2} and O{sub 2}) of the off-gas at the post chamber exit are in good agreement with additional measurements. Various operating conditions for case 3 have been studied, including different EAF off-gas temperatures and compositions, i. e. CO content, in order to optimize oxygen and burner gas flow rates. Residence time distributions in the external post combustion chambers have been calculated for cases 2 and 3. Derived temperature fields of the water cooled walls yield valuable information on thermally stressed parts of post combustion units. The results obtained in this work may also gain insight to future investigation of combustion of volatile organic components (VOC) or formation of nitrogen oxide (NO{sub x}) and permit the optimization of the operation and design of the off-gas dedusting system units. (orig.)

  10. Simulation of gas turbines operating in off-design condition

    Energy Technology Data Exchange (ETDEWEB)

    Walter, Arnaldo [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mail: walter@fem.unicamp.br

    2000-07-01

    In many countries thermal power plants based on gas turbines have been the main option for new investment into the electric system due to their relatively high efficiency and low capital cost. Cogeneration systems based on gas turbines have also been an important option for the electric industry. Feasibility studies of power plants based on gas turbine should consider the effect of atmospheric conditions and part-load operation on the machine performance. Doing this, an off-design procedure is required. A G T off-design simulation procedure is described in this paper. Ruston R M was used to validate the simulation procedure that, general sense, presents deviations lower than 2.5% in comparison to manufacturer's data. (author)

  11. Design, Fabrication, and Shakeout Testing of ATALANTE Dissolver Off-Gas Sorbent-Based Capture System

    International Nuclear Information System (INIS)

    Walker Jr, Joseph Franklin; Jubin, Robert Thomas; Jordan, Jacob A.; Bruffey, Stephanie H.

    2015-01-01

    A sorbent-based capture system designed for integration into the existing dissolver off-gas (DOG) treatment system at the ATelier Alpha et Laboratoires pour ANalyses, Transuraniens et Etudes de retraitement (ATALANTE) facility has been successfully designed and fabricated and has undergone shakeout testing. Discussions with personnel from the ATALANTE facility provided guidance that was used for the design. All components for this system were specified, procured, and received on site at Oak Ridge National Laboratory (ORNL). The system was then fabricated and tested at ORNL to verify operation. Shakeout testing resulted in a simplified system. This system should be easily installed into the existing facility and should be straightforward to operate during future experimental testing. All parts were selected to be compatible with ATALANTE power supplies, space requirements, and the existing DOG treatment system. Additionally, the system was demonstrated to meet all of four design requirements. These include (1) a dissolver off-gas flow rate of ?100 L/h (1.67 L/min), (2) an external temperature of ?50°C for all system components placed in the hot cell, (3) a sorbent bed temperature of ~150°C, and (4) a gas temperature of ~150°C upon entry into the sorbent bed. The system will be ready for shipment and installation in the existing DOG treatment system at ATALANTE in FY 2016.

  12. Development and demonstration of treatment technologies for the processing of US Department of Energy mixed waste

    International Nuclear Information System (INIS)

    Berry, J.B.; Bloom, G.A.; Kuchynka, D.J.

    1994-01-01

    Mixed waste is defined as waste contaminated with chemically hazardous (governed by the Resource Conservation and Recovery Act) and radioactive species [governed by US Department of Energy (DOE) orders]. The Mixed Waste Integrated Program (MWIP) is responding to the need for DOE mixed waste treatment technologies that meet these dual regulatory requirements. MWIP is developing emerging and innovative treatment technologies to determine process feasibility. Technology demonstrations will be used to determine whether processes are superior to existing technologies in reducing risk, minimizing life-cycle cost, and improving process performance. The Program also provides a forum for stakeholder and customer involvement in the technology development process. MWIP is composed of six technical areas that support a mixed-waste treatment system: (1) systems analysis, (2) materials handling, (3) chemical/physical separation, (4) waste destruction and stabilization, (5) off-gas treatment, and (6) final waste form stabilization. The status of the technical initiatives and the current research, development, and demonstration in each of these areas is described in this paper

  13. Exhaust gas treatment by electron beam irradiation

    International Nuclear Information System (INIS)

    Shibamura, Yokichi; Suda, Shoichi; Kobayashi, Toshiki

    1991-01-01

    Among global environmental problems, atmospheric pollution has been discussed since relatively old days, and various countermeasures have been taken, but recently in connection with acid rain, the efficient and economical treatment technology is demanded. As the denitration and desulfurization technology for the exhaust gas from the combustion of fossil fuel, the incineration of city trash and internal combustion engines, three is the treatment method by electron beam irradiation. By irradiating electron beam to exhaust gas, nitrogen oxides and sulfur oxides are oxidized to nitric acid and sulfuric acid, and by promoting the neutralization of these acids with injected alkali, harmless salts are recovered. This method has the merit that nitrogen oxides and surfur oxides can be removed efficiently with a single system. In this report, as for the exhaust gas treatment by electron beam irradiation, its principle, features, and the present status of research and development are described, and in particular, the research on the recent exhaust gas treatment in city trash incineration is introduced. This treatment method is a dry process, accordingly, waste water disposal is unnecessary. The reaction products are utilized as fertilizer, and waste is not produced. (K.I.)

  14. Proposed Strategies for DWPF Melter Off-Gas Surge Control

    International Nuclear Information System (INIS)

    CHOI, ALEXANDERS.

    2004-01-01

    Off-gas surging is inherent to the operation of slurry-fed melters. Although the melter design and the feed chemistry are both known to significantly affect off-gas surging, the frequency and intensity of surges are in essence unpredictable. In typical off-gas surges, both condensable and non condensable flows spike simultaneously. Condensable or steam surges have been observed to occur as the boiling water layer occasionally falls into the crevices of the cold cap or flows over the edges of the cold cap, thereby coming in contact with the melt surface. The resulting steam surges can pressurize the melter considerably and, therefore, are responsible for the bulk of pressure transients that propagate throughout the off-gas system. The non condensable surges occur as the calcine gases that have been accumulating within the cold cap finally build up enough pressure to be released through the temporary openings of the cold cap. The analysis of off-gas data has shown that over 90 of the gas released during a surge is due to steam.1 Therefore, it is essential to have a large inventory of water in the cold cap for any significant pressure spikes to occur. With the Melter 2 vapor space temperature typically running at 720C, the water layer in the cold cap will quickly evaporate once the feeding stops, and the potential for any large pressure spikes should practically cease to exist. The analysis also showed that large pressure spikes well above 2 inches H2O cannot occur under the steam surge scenarios described above. More severe conditions should prevail and one such condition would be that the feed materials form a mound with a growing lake on top, while the melt below remains very fluidic due to its low viscosity, thus resulting in greater movements both in the lateral as well as vertical directions. Once the mound begins to grow, its rate should accelerate, since the heat transfer rate to the upper regions of the cold cap is inversely proportional to the cold cap

  15. Radioactive contamination monitoring device for off-gas in ventilation system

    International Nuclear Information System (INIS)

    Osaki, Masahiko; Watabe, Atsushi; Kaneko, Itaru; Kubokoya, Takashi.

    1990-01-01

    In a conventional method of detecting leakage for primary coolants, radioactive iodine in off-gases was detected while going up the off-gas system. As an event resulting in abnormality to radioactive rare gas level, leakage of water, leakage in cleanup system-recycling system, leakage in main steams and leakage from wastes processing system are considered. An off-gas system to be measured is selectively sampled by a sample changer in order to measure radioactive rare gases in the off-gases, and sample gases are introduced to detect radioactivity. Detection signals are received for analysis and quantitative determination, the result of the analysis is diagnosed and the presence or absence of abnormality in an object to be measured is determined. Subsequently, an abnormality alarm and the result of the analysis are outputted. Since the radioactive rare gases are chemically inactive, they are neither combined with other materials nor deposited to wall surfaces. Abnormality can be easily detected by always monitoring a composition pattern and a radioactivity level. (N.H.)

  16. In-place testing of off-gas iodine filters

    International Nuclear Information System (INIS)

    Duce, S.W.; Tkachyk, J.W.; Motes, B.G.

    1980-01-01

    At the Idaho National Engineering Laboratory, both charcoal and silver zeolite (AgX) filters are used for radioactive iodine off-gas cleanup of reactor systems. These filters are used in facilities which are conducting research in the areas of reactor fuel failure, reactor fuel inspection, and loss of fluids from reactor vessels. Iodine retention efficiency testing of these filters is dictated by prudent safety practices and regulatory guidelines. A procedure for determining iodine off-gas filter efficiency in-place has been developed and tested on both AgX and charcoal filters. The procedure involves establishing sample points upstream and downstream of the filter to be tested. A step-by-step approach for filter efficiency testing is presented

  17. Separation of krypton from dissolver off-gas of a reprocessing plant using preparative gas chromatography

    International Nuclear Information System (INIS)

    Matoni, M.

    1984-02-01

    Kr-85 can be separated from the pre-purified purge air in the final processing step of the purification phase for dissolver off-gases of a reprocessing plant with the aid of preparative gas chromatography. Activated carbon adsorbers in combination with helium as carrier gas permits maximum gas mixture through-flow. A separation temperature of 30 0 C is considered optimal. An adsorbent volume of 40 dm 3 is necessary for processing the residual gas flow of 2.5 Nm 3 /h; the adsorbent is divided between 2 columns linked in series each of which are 2 m long with an internal diameter of 100 mm. The helium flow required is five times greater than the off-gas flow. The degree of purity for krypton is greater than 90% for a decontamination factor of greater than 1000. (orig./HP) [de

  18. Plasma processes including electron beam for off-gases purification

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Witman, S.; Licki, J.

    2011-01-01

    Complete text of publication follows. Non-thermal plasma technologies based on different methods of plasma generation are being applied for ozone generation for different applications, waste water and off-gases treatment. Plasmas create reactive species, in particular ions, radicals or other reactive compounds, which can decompose pollutant molecules, organic particulate matter or soot. Electron beam flue gas treatment is another plasma-based technology which has been successfully demonstrated on industrial scale coal fired power plants. High efficiency of SO 2 (> 95%) and NO x (> 70%) has been obtained and industrial plant applying this process has been built in Poland. The further investigations carried out all over the world have illustrated that the process can be applied for poly-aromatic hydrocarbons (PAH) destruction as well, and just recently research laboratories in the US and South Korea have reported in the feasibility of the process for mercury removal from the flue gas. The recent studies concern a new type of accelerators implementation in the industrial scale, application of the process in the high sulfur oil fired boilers and Diesel off - gases purification. The treatment of the flue gases with the high NOx concentration is a special challenge for the technology since the main energy consumption (and applied accelerators power) is related to this pollutant content in the processed off gases. The pulse beams and scavenger application can be a solution to reduce investment and operational costs. The further development of the technology is directly connected with high power accelerators development. Acknowledgement: The R and D activities are supported by the European Regional Development Found in the frame of the project PlasTEP 'Dissemination and fostering of plasma based technological innovation for environment protection in the Baltic Sea Region'.

  19. Air ionization as a control technology for off-gas emissions of volatile organic compounds.

    Science.gov (United States)

    Kim, Ki-Hyun; Szulejko, Jan E; Kumar, Pawan; Kwon, Eilhann E; Adelodun, Adedeji A; Reddy, Police Anil Kumar

    2017-06-01

    High energy electron-impact ionizers have found applications mainly in industry to reduce off-gas emissions from waste gas streams at low cost and high efficiency because of their ability to oxidize many airborne organic pollutants (e.g., volatile organic compounds (VOCs)) to CO 2 and H 2 O. Applications of air ionizers in indoor air quality management are limited due to poor removal efficiency and production of noxious side products, e.g., ozone (O 3 ). In this paper, we provide a critical evaluation of the pollutant removal performance of air ionizing system through comprehensive review of the literature. In particular, we focus on removal of VOCs and odorants. We also discuss the generation of unwanted air ionization byproducts such as O 3 , NOx, and VOC oxidation intermediates that limit the use of air-ionizers in indoor air quality management. Copyright © 2017. Published by Elsevier Ltd.

  20. Regulatory off-gas analysis from the evaporation of Hanford simulated waste spiked with organic compounds.

    Science.gov (United States)

    Saito, Hiroshi H; Calloway, T Bond; Ferrara, Daro M; Choi, Alexander S; White, Thomas L; Gibson, Luther V; Burdette, Mark A

    2004-10-01

    After strontium/transuranics removal by precipitation followed by cesium/technetium removal by ion exchange, the remaining low-activity waste in the Hanford River Protection Project Waste Treatment Plant is to be concentrated by evaporation before being mixed with glass formers and vitrified. To provide a technical basis to permit the waste treatment facility, a relatively organic-rich Hanford Tank 241-AN-107 waste simulant was spiked with 14 target volatile, semi-volatile, and pesticide compounds and evaporated under vacuum in a bench-scale natural circulation evaporator fitted with an industrial stack off-gas sampler at the Savannah River National Laboratory. An evaporator material balance for the target organics was calculated by combining liquid stream mass and analytical data with off-gas emissions estimates obtained using U.S. Environmental Protection Agency (EPA) SW-846 Methods. Volatile and light semi-volatile organic compounds (1 mm Hg vapor pressure) in the waste simulant were found to largely exit through the condenser vent, while heavier semi-volatiles and pesticides generally remain in the evaporator concentrate. An OLI Environmental Simulation Program (licensed by OLI Systems, Inc.) evaporator model successfully predicted operating conditions and the experimental distribution of the fed target organics exiting in the concentrate, condensate, and off-gas streams, with the exception of a few semi-volatile and pesticide compounds. Comparison with Henry's Law predictions suggests the OLI Environmental Simulation Program model is constrained by available literature data.

  1. Modular design of a reprocessing plant dissolver off-gas system. Variations, flexibility and stage of development

    International Nuclear Information System (INIS)

    Henrich, E.; Huefner, R.

    1984-01-01

    Simple and economic control of the volatile radionuclides in a reprocessing plant requires two equally important prerequisites: suitable processing in the plant head-end and reliable operation of the dissolver off-gas (DOG) purification system. A small number of DOG purification modules was selected from various alternatives. The major selection criteria are removal efficiency, simplicity, convenient operating conditions and flexibility that provide compatibility with other off-gas treatment steps, subsequent waste treatment and different processing modes in the head-end. The behaviour of noxious materials was investigated in nitric acid off-gas scrubbers of different design and for a wide range of operating modes and conditions. A concentration range of nitric acid from very dilute to hyperazeotropic concentrations and a temperature range from -55 deg. C to above room temperature as well as the use of hydrogen peroxide were studied on an engineering scale. Nitrous gases and iodine can be removed to the trace level at special operating modes. Aerosol and iodine filters are discussed briefly. A selective absorption process using CF 2 Cl 2 solvent for noble gas and 14 C removal was developed on a laboratory scale. It operates at low temperatures and atmospheric pressure. Xe and Kr were separated using two absorption columns. Pilot-plant scale noble gas scrubbers are under construction and are being integrated into the existing test facility. A series of process steps has been chosen for integrated process demonstration runs on an engineering scale. The integrated DOG system consists of several scrubbers and filters operating at atmospheric pressure. The temperature decreases stepwise, without producing large changes in the opposite direction, providing compatibility within the process train

  2. Design of off-gas cleaning systems for high-level waste vitrification

    International Nuclear Information System (INIS)

    Hanson, M.S.; Kaser, J.D.

    1976-01-01

    High-level wastes are generally nitric acid solutions. Vitrification converts the nitrate salts to oxides, forming nitrogen oxides (NO/sub x/) as a by-product. These NO/sub x/ releases can be controlled by nitric acid recovery or by conversion of the NO/sub x/ to an acceptable species for release, such as N 2 O or N 2 . The off-gas system must also be capable of controlling any fission products which may be voltatilized in appreciable quantities and may be controlled in the off-gas system by absorption or adsorption. Whichever method is used, the recovered fission products must somehow be converted to a safe disposal form. Proposed off-gas systems are described, and areas requiring research and development are discussed

  3. Electron beam application in gas waste treatment in China

    International Nuclear Information System (INIS)

    Wu Haifeng

    2003-01-01

    In the most recent decade, electron beam waste treatment technology attracted serious attention from environment policymaker and industrial leaders in power industry in China. Starting in middle of 1980's, Chinese research institute began experiment of electron beam treatment on flue gas. By the end of 2000, two 10,000 cubic meters per hour small scale electron beam gas purifying station were established in Sichuang province and Beijing. Several electron beam gas purifying demonstration projects are under construction. With robust economy and strong energy demand, needless to say, in near future, electron beam gas purifying technology will have a bright prospect in China. (author)

  4. Case study of manufactured gas plant site remediations using thermal desorption

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, R.G.; Hayes, T.; Slimon, K.F.; Unites, D. [Southern California Gas Company, Los Angeles, CA (United States)

    1995-12-31

    Southern California Gas Company (SoCal Gas) has recently remediated five of its former manufactured gas plant (MGP) sites using on-site and off-site thermal desorption. This technology has proven effective in the treatment of PAH-contaminated soils with widely variable concentrations. At two of the five sites, MGP-contaminated materials were excavated and thermally treated on site. At the other sites, MGP-contaminated materials were excavated and transported directly to an off-site thermal desorber. Much of the production was of oil-gas, giving lampblack contamination, but some coal tar was also present.

  5. Electron beam treatment technology for exhaust gas for preventing acid rain

    International Nuclear Information System (INIS)

    Aoki, Shinji

    1990-01-01

    Recently, accompanying the increase of the use of fossil fuel, the damage due to acid rain such as withering of trees and extinction of fishes and shells has occurred worldwide, and it has become a serious problem. The sulfur oxides and nitrogen oxides contained in exhaust gas are oxidized by the action of sunbeam to become sulfuric acid and nitric acid mists, which fall in the form of rain. Acid rain is closely related to the use of the coal containing high sulfur, and it hinders the use of coal which is rich energy source. In order to simplify the processing system for boiler exhaust gas and to reduce waste water and wastes, Ebara Corp. developed the dry simultaneous desulfurizing and denitrating technology utilizing electron beam in cooperation with Japan Atomic Energy Research Institute. The flow chart of the system applied to the exhaust gas treatment in a coal-fired thermal power station is shown. The mechanism of desulfurization and denitration, and the features of this system are described. The demonstration plant was constructed in a coal-fired thermal power station in Indianapolis, Indiana, USA, and the trial operation was completed in July, 1987. The test results are reported. (K.I.)

  6. Technical development of graphite waste treatment in NUPEC

    International Nuclear Information System (INIS)

    Saishu, S.; Inoue, T.

    2001-01-01

    In Japan, Tokai Power Station, which is a Gas Cooled Reactor and uses graphite as moderator, ceased operation at the end of March in 1998 and it is planned to transfer to decommissioning stage. In this decommissioning stage it is very important to be able to treat and dispose the graphite waste in order to carry out the decommissioning safely and economically. NUPEC has been developing the graphite treatment and disposal technology since 1997 and we introduce the outline of the technical development. For the technology on high density packing into disposal container, the high density packing method and the assessment method on nuclide leaching characteristics were developed, and the cementing test for graphite powder by using Tokai spare graphite was performed and the hydrophobic characteristics between graphite and cement was grasped and the accelerator candidature for affinity was selected. From the view point of economical treatment, the incinerating technology was selected as candidature, and the methods for incinerating graphite and treating off gas are developed. The method of collecting C-14 in off gas was selected for reducing the off gas radiation level. The applicability of actual graphite treatment technology was considered from the view point of safety, economics and preparation of technical standard; the technical theme appeared, the developing planning items were established, and the detailed and actual scale tests will be carried out according to the planning. (author)

  7. Development and demonstration of treatment technologies for the processing of US Department of Energy Mixed Waste

    International Nuclear Information System (INIS)

    Bloom, G.A.; Berry, J.B.

    1994-01-01

    Mixed waste is defined as ''waste contaminated with chemically hazardous and radioactive species.'' The Mixed Waste Integrated Program (MWIP) was established in response to the need for a unified, DOE complexwide solution to issues of mixed waste treatment that meets regulatory requirements. MWIP is developing treatment technologies that reduce risk, minimize life-cycle cost, and improve process performance as compared to existing technologies. Treatment for waste streams for which no current technology exists, and suitable waste forms for disposal, will be provided to improve operations of the DOE Office of Waste Management. MWIP is composed of six technical areas within a mixed-waste treatment system: (1) systems analysis, (2) materials handling, (3) chemical/physical separation, (4) waste destruction and stabilization, (5) off-gas treatment, and (6) final waste form stabilization. The status of the technical initiatives and the current research, development, and demonstration in each of these areas are described in this paper

  8. Process for off-gas particulate removal and apparatus therefor

    International Nuclear Information System (INIS)

    Carl, D.E.

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel's wall in the form of a ''wavy film,'' while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs

  9. FINAL REPORT REGULATORY OFF GAS EMISSIONS TESTING ON THE DM1200 MELTER SYSTEM USING HLW AND LAW SIMULANTS VSL-05R5830-1 REV 0 10/31/05

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The operational requirements for the River Protection Project - Waste Treatment Plant (RPP-WTP) Low Activity Waste (LAW) and High Level Waste (HLW) melter systems, together with the feed constituents, impose a number of challenges to the off-gas treatment system. The system must be robust from the standpoints of operational reliability and minimization of maintenance. The system must effectively control and remove a wide range of solid particulate matter, acid mists and gases, and organic constituents (including those arising from products of incomplete combustion of sugar and organics in the feed) to concentration levels below those imposed by regulatory requirements. The baseline design for the RPP-WTP LAW primary off-gas system includes a submerged bed scrubber (SBS), a wet electrostatic precipitator (WESP), and a high efficiency particulate air (HEPA) filter. The secondary off-gas system includes a sulfur-impregnated activated carbon bed (AC-S), a thermal catalytic oxidizer (TCO), a single-stage selective catalytic reduction NOx treatment system (SCR), and a packed-bed caustic scrubber (PBS). The baseline design for the RPP-WTP HLW primary off-gas system includes an SBS, a WESP, a high efficiency mist eliminator (HEME), and a HEPA filter. The HLW secondary off-gas system includes a sulfur-impregnated activated carbon bed, a silver mordenite bed, a TCO, and a single-stage SCR. The one-third scale HLW DM1200 Pilot Melter installed at the Vitreous State Laboratory (VSL) was equipped with a prototypical off-gas train to meet the needs for testing and confirmation of the performance of the baseline off-gas system design. Various modifications have been made to the DM1200 system as the details of the WTP design have evolved, including the installation of a silver mordenite column and an AC-S column for testing on a slipstream of the off-gas flow; the installation of a full-flow AC-S bed for the present tests was completed prior to initiation of testing. The DM1200

  10. [Segmental cut-off bridge and local floating technology for the treatment of ossification of ligamentum flavum in thoracic spine].

    Science.gov (United States)

    Liang, Wei-dong; Zhang, Jian; Sheng, Wei-bin

    2013-10-08

    To explore the efficacy and safety of segmental cut-off bridge and local floating technology for the treatment of ossification of ligamentum flavum (OLF) in thoracic spine. Retrospective study was performed in 98 patients with thoracic OLF who under went operation. There was 56 males and 42 females with an average age of 45.8 (35-73) years. The average duration of onset was 17 (3-51) months. The main clinical symptoms were numbness and paraesthesia (n = 90), lower limb weakness and walking trouble (n = 46), positive pyramidal tract signs (n = 33) and sphincter function obstacle (n = 9). OLF was screened and diagnosed by radiology, magnetic resonance imaging (MRI), computed tomography (CT) or CT myelography (CTM). A total of 142 OLF nidus were spotted. The lesions involved single segment (n = 32), double segments (n = 56), three segments (n = 6) and ≥ four segments (n = 4). And the locations were at upper thoracic segment (T1-4) (n = 34), middle thoracic segment (T5-8) (n = 23) and lower thoracic segment (T9-12) (n = 42). The OLF nidus were removed by local floating technology oft windowing at cephalic and caudal ends and a cut-off bridge at both sides of involved segments. Pre- and post-operative Japanese Orthopedic Association (JOA) scores and Epstein grades were recorded to evaluate the outcomes. The mean loss volume of blood was 320 ml and operative duration 155 min. All cases recovered independent activities. The mean follow-up period was 28 (13-48) months. The mean preoperative JOA score was 4.3 (1-8) points and the mean postoperative JOA score 9.7 (5-11) points. The recovery rate was 78.8%. According to Epstein grade, the excellent and good rate was 86.7%. As a common cause of thoracic spinal cord compression, OLF should be operated as early as possible. Based upon clinical and imaging findings, the application of segmental cut-off bridge and local floating technology is both safe and efficacious in the treatment of OLF in thoracic spine.

  11. Gas utilization technologies

    International Nuclear Information System (INIS)

    Biljetina, R.

    1994-01-01

    One of the constant challenges facing the research community is the identification of technology needs 5 to 15 years from now. A look back into history indicates that the forces driving natural gas research have changed from decade to decade. In the 1970s research was driven by concerns for adequate supply; in the 1980s research was aimed at creating new markets for natural gas. What then are the driving forces for the 1990s? Recent reports from the natural gas industry have helped define a new direction driven primarily by market demand for natural gas. A study prepared by the Interstate Natural Gas Association of America Foundation entitled ''Survey of Natural Research, Development, and Demonstration RD ampersand D Priorities'' indicated that in the 1990s the highest research priority should be for natural gas utilization and that technology development efforts should not only address efficiency and cost, but environmental and regulatory issues as well. This study and others, such as the report by the American Gas Association (A.G.A.) entitled ''Strategic Vision for Natural Gas Through the Year 2000,'' clearly identify the market sectors driving today's technology development needs. The biggest driver is the power generation market followed by the industrial, transportation, appliance, and gas cooling markets. This is best illustrated by the GRI 1994 Baseline Projection on market growth in various sectors between the year 1992 and 2010. This paper highlights some of the recent technology developments in each one of these sectors

  12. REMEDIATION OF MTBE FROM DRINKING WATER: AIR STRIPPING FOLLOWED BY OFF-GAS ADSORPTION

    Science.gov (United States)

    The widespread use of methyl tertiary butyl ether (MTBE) as an oxygenate in gasoline has resulted in the contamination of a large number of ground and surface water sources. Even though air stripping has been proven to be an effective treatment technology for MTBE removal, off-ga...

  13. The Technology Endowments of Spin-off Companies

    OpenAIRE

    E. VAN DE VELDE; B. CLARYSSE; M. WRIGHT

    2008-01-01

    Innovative start-ups, including spin-offs from universities and companies, play a vital role in the development and growth of emerging, high-technology industries. Research attention has traditionally focused on the links between demographic, educational, psychological and financial influences on start-up activity and growth. The extent to which the characteristics of technology inherited from the parent, important for spin-offs, helps explain post start-up performance has been neglected. We ...

  14. High power electron accelerators for flue gas treatment

    International Nuclear Information System (INIS)

    Zimek, Z.

    2011-01-01

    Flue gas treatment process based on electron beam application for SO 2 and NO x removal was successfully demonstrated in number of laboratories, pilot plants and industrial demonstration facilities. The industrial scale application of an electron beam process for flue gas treatment requires accelerators modules with a beam power 100-500 kW and electron energy range 0.8-1.5 MeV. The most important accelerator parameters for successful flue gas radiation technology implementation are related to accelerator reliability/availability, electrical efficiency and accelerator price. Experience gained in high power accelerators exploitation in flue gas treatment industrial demonstration facility was described and high power accelerator constructions have been reviewed. (author)

  15. Waste Isolation Pilot Plant: Alcove Gas Barrier trade-off study

    International Nuclear Information System (INIS)

    Lin, M.S.; Van Sambeek, L.L.

    1992-07-01

    A modified Kepner-Tregoe method was used for a trade-off study of Alcove Gas Barrier (AGB) concepts for the Waste Isolation Pilot Plant. The AGB is a gas-constraining seal to be constructed in an alcove entrance drift. In this trade-off study, evaluation criteria were first selected. Then these criteria were classified as to their importance to the task, assigning a weighting value to each aspect. Eleven conceptual design alternatives were developed based on geometrical/geological considerations, construction materials, constructibility, and other relevant factors and evaluated

  16. I-129, Kr-85, C-14 and NO/sub x/ removal from spent fuel dissolver off-gas at atmospheric pressure and at reduced off-gas flow

    International Nuclear Information System (INIS)

    Henrich, E.; Huefner, R.

    1981-01-01

    A dissolver off-gas (DOG) system suitable for a LWR, FBR or HTR spent fuel reprocessing plant is described, incorporating the following features: (1) the DOG flow is reduced to a reasonably small volume, using fumeless dissolution conditions, by maintaining high concentrations, the retention procedures are simplified and accompanied by an economic reduction of the equipment size; (2) all process operations are conducted at atmospheric or subatmospheric pressure, including noble gas removal by selective absorption, without using high temperature processes; (3) all processes, except HEPA filtering, are continuous and do not accumulate large amounts of waste nuclides, the DOG process sequence is mutually compatible with itself and with processing in the headend, showing on-line redundancy for the removal of the most radiotoxic nuclides; and (4) the DOG system only deviates slightly from proven technology. The stage of development and relevant results are given both for a lab. scale and a pilot plant scale

  17. Treatment of wastewaters from manufactured gas plants

    Energy Technology Data Exchange (ETDEWEB)

    Cocheci, V.; Bogatu, C.; Radovan, C. [Technical University of Timisoara, Timisoara (Romania)

    1995-12-31

    The treatment of wastewaters with high concentrations of organic compounds often represents a difficult problem. In some cases, for the destruction and removal of toxic compounds using processes like biological and chemical oxidation were proposed. Wastewaters from manufactured gas plants contain high concentrations of organic pollutants and ammonia. In this paper a technology for the treatment of these wastewaters is proposed. The experiments were realized with wastewaters from two Romanian manufactured gas plants. The process consists of the following steps: polycondensation-settling-stripping-biological treatment-electrocoagulation-electrochemical oxidation, or chemical oxidation. 6 refs., 4 tabs.

  18. High power electron accelerators for flue gas treatment

    Energy Technology Data Exchange (ETDEWEB)

    Zimek, Z. [Institute of Nuclear Chemistry and Technology, Warsaw (Poland)

    2011-07-01

    Flue gas treatment process based on electron beam application for SO{sub 2} and NO{sub x} removal was successfully demonstrated in number of laboratories, pilot plants and industrial demonstration facilities. The industrial scale application of an electron beam process for flue gas treatment requires accelerators modules with a beam power 100-500 kW and electron energy range 0.8-1.5 MeV. The most important accelerator parameters for successful flue gas radiation technology implementation are related to accelerator reliability/availability, electrical efficiency and accelerator price. Experience gained in high power accelerators exploitation in flue gas treatment industrial demonstration facility was described and high power accelerator constructions have been reviewed. (author)

  19. Development of filters for exhaust air or off-gas cleaning

    International Nuclear Information System (INIS)

    Wilhelm, J.

    1988-01-01

    The activities of the 'Laboratorium fuer Aerosolphysik und Filtertechnik II' of the 'Kernforschungszentrum Karlsruhe' concentrate on the development of filters to be used for cleaning nuclear and conventional exhaust air and off-gas. Originally, these techniques were intended to be applied in nuclear facilities only. Their application for conventional gas purification, however, has led to a reorientation of research and development projects. By way of example, it is reported about the use of the multi-way sorption filter for radioiodine removal in nuclear power plants and following flue-gas purification in heating power plants as well as for off-gas cleaning in chemical industry. The improvement of HEPA filters and the development of metal fibre filters has led to components which can be used in the range of high humidity and moisture as well as at high temperatures and an increased differential pressure. The experience obtained in the field of high-efficiency filtering of nuclear airborne particles is made use of during the investigations concerning the removal of particles of conventional pollutants in the submicron range. A technique of radioiodine removal and an improved removal of airborne particles has been developed for use in the future reprocessing plant. Thus, a maximum removal efficiency can be achieved and an optimum waste management is made possible. It is reported about the components obtained as a result of these activities and their use for off-gas cleaning in the Wackersdorf reprocessing plant (WAW). (orig.) [de

  20. Continuous chemical cold traps for reprocessing off-gas purification

    International Nuclear Information System (INIS)

    Henrich, E.; Bauder, U.; Steinhardt, H.J.; Bumiller, W.

    1985-01-01

    Absorption of nitrogen oxides and iodine from simulated reprocessing plant off-gas streams has been studied using nitric acid and nitric acid/hydrogen peroxide mixtures at low temperatures. The experiments were carried out at the laboratory and on the engineering scale. The pilot plant scale column has 0.8 m diameter and 16 absorption plates at 0.2 m spacing. Cooling coils on the plates allow operating temperatures down to -60 0 C. The NO concentration in the feed gas usually has been 1% by volume and the flow rate 4-32 m 3 (STP) per hour. The iodine behavior has been studied using I-123 tracer. Results of the study are presented. The chemistry of the processes and the advantages and disadvantages in correlation to the various applications for an off-gas purification in a reprocessing plant are compared and discussed. The processes are compatible with the PUREX process and do not produce additional waste

  1. Comparison of alternative flue gas dry treatment technologies in waste-to-energy processes.

    Science.gov (United States)

    Dal Pozzo, Alessandro; Antonioni, Giacomo; Guglielmi, Daniele; Stramigioli, Carlo; Cozzani, Valerio

    2016-05-01

    Acid gases such as HCl and SO2 are harmful both for human health and ecosystem integrity, hence their removal is a key step of the flue gas treatment of Waste-to-Energy (WtE) plants. Methods based on the injection of dry sorbents are among the Best Available Techniques for acid gas removal. In particular, systems based on double reaction and filtration stages represent nowadays an effective technology for emission control. The aim of the present study is the simulation of a reference two-stage (2S) dry treatment system performance and its comparison to three benchmarking alternatives based on single stage sodium bicarbonate injection. A modelling procedure was applied in order to identify the optimal operating configuration of the 2S system for different reference waste compositions, and to determine the total annual cost of operation. Taking into account both operating and capital costs, the 2S system appears the most cost-effective solution for medium to high chlorine content wastes. A Monte Carlo sensitivity analysis was carried out to assess the robustness of the results. Copyright © 2016. Published by Elsevier Ltd.

  2. Enhancing energy recovery in the steel industry: Matching continuous charge with off-gas variability smoothing

    International Nuclear Information System (INIS)

    Dal Magro, Fabio; Meneghetti, Antonella; Nardin, Gioacchino; Savino, Stefano

    2015-01-01

    Highlights: • A system based on phase change material is inserted into the off-gas-line of a continuous charge electric arc furnace. • The off-gas temperature profile after scrap preheating is smoothed. • A heat transfer fluid through phase change material containers allows to control overheating issues. • The smoothed off-gas profiles enable efficient downstream power generation. • The recovery system investment cost is decreased due to lower sizes of components. - Abstract: In order to allow an efficient energy recovery from off-gas in the steel industry, the high variability of heat flow should be managed. A temperature smoothing device based on phase change materials at high temperatures is inserted into the off-gas line of a continuous charge electric arc furnace process with scrap preheating. To address overheating issues, a heat transfer fluid flowing through containers is introduced and selected by developing an analytical model. The performance of the smoothing system is analyzed by thermo-fluid dynamic simulations. The reduced maximum temperature of off-gas allows to reduce the size and investment cost of the downstream energy recovery system, while the increased minimum temperature enhances the steam turbine load factor, thus increasing its utilization. Benefits on environmental issues due to dioxins generation are also gained

  3. Treatment of Gas

    Science.gov (United States)

    ... Funding IFFGD Symposium reports Industry Council Contact Us Treatment of Gas You are here: Home Symptoms & Causes Intestinal Gas ... Controlling Intestinal Gas Foods That May Cause Gas Treatment of Gas Tips on Controlling Gas Adapted from IFFGD Publication # ...

  4. Technoeconomic Optimization of Waste Heat Driven Forward Osmosis for Flue Gas Desulfurization Wastewater Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Gingerich, Daniel B [Carnegie Mellon Univ., Pittsburgh, PA (United States); Bartholomew, Timothy V [Carnegie Mellon Univ., Pittsburgh, PA (United States); Mauter, Meagan S [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2017-06-26

    With the Environmental Protection Agency’s recent Effluent Limitation Guidelines for Steam Electric Generators, power plants are having to install and operate new wastewater technologies. Many plants are evaluating desalination technologies as possible compliance options. However, the desalination technologies under review that can reduce wastewater volume or treat to a zero-liquid discharges standard have a significant energy penalty to the plant. Waste heat, available from the exhaust gas or cooling water from coal-fired power plants, offers an opportunity to drive wastewater treatment using thermal desalination technologies. One such technology is forward osmosis (FO). Forward osmosis utilizes an osmotic pressure gradient to passively pull water from a saline or wastewater stream across a semi-permeable membrane and into a more concentrated draw solution. This diluted draw solution is then fed into a distillation column, where the addition of low temperature waste heat can drive the separation to produce a reconcentrated draw solution and treated water for internal plant reuse. The use of low-temperature waste heat decouples water treatment from electricity production and eliminates the link between reducing water pollution and increasing air emissions from auxiliary electricity generation. In order to evaluate the feasibility of waste heat driven FO, we first build a model of an FO system for flue gas desulfurization (FGD) wastewater treatment at coal-fired power plants. This model includes the FO membrane module, the distillation column for draw solution recovery, and waste heat recovery from the exhaust gas. We then add a costing model to account for capital and operating costs of the forward osmosis system. We use this techno-economic model to optimize waste heat driven FO for the treatment of FGD wastewater. We apply this model to three case studies: the National Energy Technology Laboratory (NETL) 550 MW model coal fired power plant without carbon

  5. Technology and products of gas companies; Gas gaisha no Technology and Products

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-06-10

    This paper presents the latest technology and products of gas companies. `Newly developed gas table for one-push automatic fish broiling` of Tokyo Gas Co. `Catalytic technology for decomposing dioxin generated by incinerator to make it harmless` of Osaka Gas Co. `Newly developed strong and kindly shower head` of Tokyo Gas Co. By laying fish on a sensor in a grill and appropriately setting upper and lower heating levers, user can skillfully broil fish only by pushing an ignition button. A temperature sensor attached to the center of a grill catches a change in surface temperature of fish, and automatically sets an appropriate broiling time according to the kind and volume of fish. A finish buzzer and automatic extinction mechanism are prepared. The technology decomposes dioxin in exhaust gas of incinerators to make it harmless. The catalyst is prepared by dispersing noble metal or oxide of several angstroms into activated carbon fibers. The shower head can switch hot water power by a control handle

  6. Multi-level computational chemistry study on hydrogen recombination catalyst of off-gas treatment system

    International Nuclear Information System (INIS)

    Hatakeyama, Nozomu; Ise, Mariko; Inaba, Kenji

    2011-01-01

    In order to reveal the deactivation mechanism of the hydrogen recombination catalyst of off-gas treatment system, we investigate by using multi-level computational chemistry simulation methods. The recombiner apparatus is modeled by the numerical mesh system in the axial coordinates, and unsteady, advection and reaction rate equations are solved by using a finite difference method. The chemical reactions are formulated to represent adsorption-desorption of hydrogen and oxygen on Pt catalyst, and time developments of the coverage factors of Pt are solved numerically. The computational simulations successfully reproduce the very similar behaviors observed by experiments, such as increasing of the inversion rates of H 2 to H 2 O, the temperatures distributions along the flow direction, dependencies of experimental condition, and so on. Thus Pt poisoning is considered to cause the deactivation of the hydrogen recombination catalyst. To clarify the poisoning mechanism, the molecular level simulation is applied to the system of Pt on boehmite attacked by a cyclic siloxane which has been detected by experiments and considered as one of poisoning spices. The simulation shows ring-opening reaction of the cyclic siloxane on Pt, then attachment of two ends of the chain-like siloxane to Pt and boehmite, respectively, and that finally the recombination reaction is prevented. This may be the first study to find out the detailed dynamical mechanism of hydrogen recombination catalyst poisoning with cyclic siloxane. (author)

  7. [Evaluation of treatment technology of odor pollution source in petrochemical industry].

    Science.gov (United States)

    Mu, Gui-Qin; Sui, Li-Hua; Guo, Ya-Feng; Ma, Chuan-Jun; Yang, Wen-Yu; Gao, Yang

    2013-12-01

    Using an environmental technology assessment system, we put forward the evaluation index system for treatment technology of the typical odor pollution sources in the petroleum refining process, which has been applied in the assessment of the industrial technology. And then the best available techniques are selected for emissions of gas refinery sewage treatment plant, headspace gas of acidic water jars, headspace gas of cold coke jugs/intermediate oil tank/dirty oil tank, exhaust of oxidative sweetening, and vapors of loading and unloading oil.

  8. Design and operation of off-gas cleaning systems at high level liquid waste conditioning facilities

    International Nuclear Information System (INIS)

    1988-01-01

    The immobilization of high level liquid wastes from the reprocessing of irradiated nuclear fuels is of great interest and serious efforts are being undertaken to find a satisfactory technical solution. Volatilization of fission product elements during immobilization poses the potential for the release of radioactive substances to the environment and necessitates effective off-gas cleaning systems. This report describes typical off-gas cleaning systems used in the most advanced high level liquid waste immobilization plants and considers most of the equipment and components which can be used for the efficient retention of the aerosols and volatile contaminants. In the case of a nuclear facility consisting of several different facilities, release limits are generally prescribed for the nuclear facility as a whole. Since high level liquid waste conditioning (calcination, vitrification, etc.) facilities are usually located at fuel reprocessing sites (where the majority of the high level liquid wastes originates), the off-gas cleaning system should be designed so that the airborne radioactivity discharge of the whole site, including the emission of the waste conditioning facility, can be kept below the permitted limits. This report deals with the sources and composition of different kinds of high level liquid wastes and describes briefly the main high level liquid waste solidification processes examining the sources and characteristics of the off-gas contaminants to be retained by the off-gas cleaning system. The equipment and components of typical off-gas systems used in the most advanced (large pilot or industrial scale) high level liquid waste solidification plants are described. Safety considerations for the design and safe operation of the off-gas systems are discussed. 60 refs, 31 figs, 17 tabs

  9. Design of a boil-off natural gas reliquefaction control system for LNG carriers

    International Nuclear Information System (INIS)

    Shin, Younggy; Lee, Yoon Pyo

    2009-01-01

    Onboard boil-off gas (BOG) reliquefaction is a new technology that liquefies BOG and returns it to the cargo tanks instead of burning it off during a voyage. For the commercial development of this technology, an object-oriented dynamic simulation is presented which facilitates the design of the plant and control system for the thermal process. A reliquefaction process based on the reverse Brayton cycle has been designed, and its static thermodynamic states at the design BOG load are presented. To make the cycle work for any BOG load, an idea was sought that would achieve a heat balance with the work extracted by the expander. Dynamic simulations were conducted for all operating modes, including start-up and idle. It was found that the expander exit temperature is the key process variable for control and that the process control works successfully when three actuators are activated in three different BOG load regimes. The study also shows that control of the separator pressure to keep the vapor fraction at the throttle valve exit as low as possible is an efficient method for purging nitrogen from BOG

  10. Development and testing of prototype alpha waste incinerator off-gas systems

    International Nuclear Information System (INIS)

    Freed, E.J.; Becker, G.W.

    1982-01-01

    A test program is in progress at Savannah River Laboratory (SRL) to confirm and develop incinerator design technology for an SRP production Alpha Waste Incinerator (AWI) to be built in the mid-1980's. The Incinerator Components Test Facility (ICTF) is a full-scale (5 kg/h), electrically heated, controlled-air prototype incinerator built to burn nonradioactive solid waste. The incinerator has been operating successfully at SRL since March 1979 and has met or exceeded all design criteria. During the first 1-1/2 years of operation, liquid scrubbers were used to remove particulates and hydrochloric acid from the incinerator exhaust gases. A dry off-gas system is currently being tested to provide data to Savannah River Plant's proposed AWI

  11. Mathematical modelling of heat transfer in dedusting plants and comparison to off-gas measurements at electric arc furnaces

    International Nuclear Information System (INIS)

    Kirschen, Marcus; Velikorodov, Viktor; Pfeifer, Herbert

    2006-01-01

    A mathematical simulation tool is presented in order to model enthalpy flow rates of off-gas and heat transfer of cooling systems at dedusting plants in electric steel making sites. The flexibility of the simulation tool is based on a user-defined series of modular units that describe elementary units of industrial dedusting systems, e.g. water-cooled hot gas duct, air injector, drop-out box, mixing chamber, post-combustion chamber, filter, etc. Results of simulation were checked with measurements at industrial electric steel making plants in order to validate the models for turbulence, heat transfer and chemical reaction kinetics. Comparison between computed and measured gas temperature and composition yield excellent agreement. The simulation tool is used to calculate off-gas temperature and volume flow rate, where off-gas measurements are very difficult to apply due to high gas temperatures and high dust load. Heat transfer from the off-gas to the cooling system was calculated in detail for a pressurised hot water EAF cooling system in order to investigate the impact of the cooling system and the dedusting plant operation on the energy sinks of the electric arc furnace. It is shown that optimum efficiency of post-combustion of EAF off-gas in the water-cooled hot gas duct requires continuous off-gas analysis. Common operation parameters of EAF dedusting systems do not consider the non-steady-state of the EAF off-gas emission efficiently

  12. Mathematical modelling of heat transfer in dedusting plants and comparison to off-gas measurements at electric arc furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Kirschen, Marcus [Institute for Industrial Furnaces and Heat Engineering, RWTH Aachen, Kopernikusstrasse 16, 52074 Aachen (Germany)]. E-mail: kirschen@iob.rwth-aachen.de; Velikorodov, Viktor [Institute for Industrial Furnaces and Heat Engineering, RWTH Aachen, Kopernikusstrasse 16, 52074 Aachen (Germany); Pfeifer, Herbert [Institute for Industrial Furnaces and Heat Engineering, RWTH Aachen, Kopernikusstrasse 16, 52074 Aachen (Germany)

    2006-11-15

    A mathematical simulation tool is presented in order to model enthalpy flow rates of off-gas and heat transfer of cooling systems at dedusting plants in electric steel making sites. The flexibility of the simulation tool is based on a user-defined series of modular units that describe elementary units of industrial dedusting systems, e.g. water-cooled hot gas duct, air injector, drop-out box, mixing chamber, post-combustion chamber, filter, etc. Results of simulation were checked with measurements at industrial electric steel making plants in order to validate the models for turbulence, heat transfer and chemical reaction kinetics. Comparison between computed and measured gas temperature and composition yield excellent agreement. The simulation tool is used to calculate off-gas temperature and volume flow rate, where off-gas measurements are very difficult to apply due to high gas temperatures and high dust load. Heat transfer from the off-gas to the cooling system was calculated in detail for a pressurised hot water EAF cooling system in order to investigate the impact of the cooling system and the dedusting plant operation on the energy sinks of the electric arc furnace. It is shown that optimum efficiency of post-combustion of EAF off-gas in the water-cooled hot gas duct requires continuous off-gas analysis. Common operation parameters of EAF dedusting systems do not consider the non-steady-state of the EAF off-gas emission efficiently.

  13. The academic spin-offs as technology transfer way

    International Nuclear Information System (INIS)

    Gomez Gras, J. M.; Mira Solves, I.; Verdu Jover, A. J.; Sancho Azuar, J.

    2007-01-01

    One of the technology transfer mechanisms used by universities that has risen more interest in the last decade is the formation of academic spin-off, firms specifically created for the commercial exploitation of technology derived from research results. In the current paper we review the typologies and the development process of this kind of firms, as well as we propose a model that groups the conditioning factors of spin-off activity in the internal university environment. (Author) 92 refs

  14. The Air-Carbon-Water Synergies and Trade-Offs in China's Natural Gas Industry

    Science.gov (United States)

    Qin, Yue

    China's coal-dominated energy structure is partly responsible for its domestic air pollution, local water stress, and the global climate change. Primarily to tackle the haze issue, China has been actively promoting a nationwide coal to natural gas end-use switch. My dissertation focuses on evaluating the air quality, carbon, and water impacts and their interactions in China's natural gas industry. Chapter 2 assesses the lifecycle climate performance of China's shale gas in comparison to coal based on stage-level energy consumption and methane leakage rates. I find the mean lifecycle carbon footprint of shale gas is about 30-50% lower than that of coal under both 20 year and 100 year global warming potentials (GWP20 and GWP100). However, primarily due to large uncertainties in methane leakage, the lifecycle carbon footprint of shale gas in China could be 15-60% higher than that of coal across sectors under GWP20. Chapter 3 evaluates the air quality, human health, and the climate impacts of China's coal-based synthetic natural gas (SNG) development. Based on earlier 2020 SNG production targets, I conduct an integrated assessment to identify production technologies and end-use applications that will bring as large air quality and health benefits as possible while keeping carbon penalties as small as possible. I find that, due to inefficient and uncontrolled coal combustion in households, allocating currently available SNG to the residential sector proves to be the best SNG allocation option. Chapter 4 compares the air quality, carbon, and water impacts of China's six major gas sources under three end-use substitution scenarios, which are focused on maximizing air pollutant emission reductions, CO 2 emission reductions, and water stress index (WSI)-weighted water consumption reductions, respectively. I find striking national air-carbon/water trade-offs due to SNG, which also significantly increases water demands and carbon emissions in regions already suffering from

  15. Sustainable recycling technologies for Solar PV off-grid system

    Science.gov (United States)

    Uppal, Bhavesh; Tamboli, Adish; Wubhayavedantapuram, Nandan

    2017-11-01

    Policy makers throughout the world have accepted climate change as a repercussion of fossil fuel exploitation. This has led the governments to integrate renewable energy streams in their national energy mix. PV off-grid Systems have been at the forefront of this transition because of their permanently increasing efficiency and cost effectiveness. These systems are expected to produce large amount of different waste streams at the end of their lifetime. It is important that these waste streams should be recycled because of the lack of available resources. Our study found that separate researches have been carried out to increase the efficiencies of recycling of individual PV system components but there is a lack of a comprehensive methodical research which details efficient and sustainable recycling processes for the entire PV off-grid system. This paper reviews the current and future recycling technologies for PV off-grid systems and presents a scheme of the most sustainable recycling technologies which have the potential for adoption. Full Recovery End-of-Life Photovoltaic (FRELP) recycling technology can offer opportunities to sustainably recycle crystalline silicon PV modules. Electro-hydrometallurgical process & Vacuum technologies can be used for recovering lead from lead acid batteries with a high recovery rate. The metals in the WEEE can be recycled by using a combination of biometallurgical technology, vacuum metallurgical technology and other advanced metallurgical technologies (utrasonical, mechano-chemical technology) while the plastic components can be effectively recycled without separation by using compatibilizers. All these advanced technologies when used in combination with each other provide sustainable recycling options for growing PV off-grid systems waste. These promising technologies still need further improvement and require proper integration techniques before implementation.

  16. Fluidized-bed calcination of LWR fuel-reprocessing HLLW: requirements and potential for off-gas cleanup

    International Nuclear Information System (INIS)

    Schindler, R.E.

    1979-01-01

    Fluidized-bed solidification (calcination) was developed on a pilot scale for a variety of simulated LWR high-level liquid-waste (HLLW) and blended high-level and intermediate-level liquid-waste (ILLW) compositions. It has also been demonstrated with ICPP fuel-reprocessing waste since 1963 in the Waste Calcining Facility (WCF) at gross feed rates of 5 to 12 m 3 /day. A fluidized-bed calciner produces a relatively large volume of off-gas. A calciner solidifying 6 m 3 /day of liquid waste would generate about 13 standard m 3 /min of off-gas containing 10 to 20 g of entrained solids per standard m 3 of off-gas. Use of an off-gas system similar to that of the WCF could provide an overall process decontamination factor for particulates of about 2 x 10 10 . A potential advantage of fluidized-bed calcination over other solidification methods is the ability to control ruthenium volatilization from the calciner at less than 0.01% by calcining at 500 0 C or above. Use of an off-gas system similar to that of the WCF would provide an overall process decontamination factor for volatile ruthenium of greater than 1.6 x 10 7

  17. Innovation, technology transfer and development: the spin-off companies

    Directory of Open Access Journals (Sweden)

    Teodoro Valente

    2014-05-01

    Full Text Available The article starts from the identification of the reasons why Italy is less prone to technology transfer than other countries, and indicates some key issues for the diffusion of technological innovations and the development of human capital. In particular, technology transfer is not a generic form of exploitation of outcome of the research, it involves specific actions that have impact on economic production, such as the patenting and the creation of new companies (spin-offs. The author discusses the various forms of spin-offs of university research, the evolution of the phenomenon in the structures of the uni- versities, the stages of development of a spin-off company and the current fund- ing arrangements and to be promoted.

  18. Japan’s experience of flue gas treatment by electron beams

    International Nuclear Information System (INIS)

    Machi, S.

    2011-01-01

    The electron beam flue gas treatment technology was invented in Japan in 1970's. The paper presents the outlook of the Japanese activities on the development and present state of EBFGT technology. (author)

  19. Japan’s experience of flue gas treatment by electron beams

    Energy Technology Data Exchange (ETDEWEB)

    Machi, S.

    2011-07-01

    The electron beam flue gas treatment technology was invented in Japan in 1970's. The paper presents the outlook of the Japanese activities on the development and present state of EBFGT technology. (author)

  20. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems

    International Nuclear Information System (INIS)

    Soelberg, Nick; Enneking, Joe

    2011-01-01

    Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (radioactive and hazardous) wastes. Test programs performed in recent years have shown that mercury in off-gas streams from processes that treat radioactive wastes can be controlled using fixed beds of activated sulfur-impregnated carbon, to levels low enough to comply with air emission regulations such as the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. Carbon bed hot spots or fires have occurred several times during these tests, and also during a remediation of tanks that contained mixed waste. Hot spots occur when localized areas in a carbon bed become heated to temperatures where oxidation occurs. This heating typically occurs due to heat of absorption of gas species onto the carbon, but it can also be caused through external means such as external heaters used to heat the carbon bed vessel. Hot spots, if not promptly mitigated, can grow into bed fires. Carbon bed hot spots and fires must be avoided in processes that treat radioactive and mixed waste. Hot spots are detected by (a) monitoring in-bed and bed outlet gas temperatures, and (b) more important, monitoring of bed outlet gas CO concentrations. Hot spots are mitigated by (a) designing for appropriate in-bed gas velocity, for avoiding gas flow maldistribution, and for sufficient but not excessive bed depth, (b) appropriate monitoring and control of gas and bed temperatures and compositions, and (c) prompt implementation of corrective actions if bed hot spots are detected. Corrective actions must be implemented quickly if bed hot spots are detected, using a graded approach and sequence starting with corrective actions that are simple, quick, cause the least impact to the process, and are easiest to recover from.

  1. Sustainable recycling technologies for Solar PV off-grid system

    Directory of Open Access Journals (Sweden)

    Uppal Bhavesh

    2017-01-01

    Full Text Available Policy makers throughout the world have accepted climate change as a repercussion of fossil fuel exploitation. This has led the governments to integrate renewable energy streams in their national energy mix. PV off-grid Systems have been at the forefront of this transition because of their permanently increasing efficiency and cost effectiveness. These systems are expected to produce large amount of different waste streams at the end of their lifetime. It is important that these waste streams should be recycled because of the lack of available resources. Our study found that separate researches have been carried out to increase the efficiencies of recycling of individual PV system components but there is a lack of a comprehensive methodical research which details efficient and sustainable recycling processes for the entire PV off-grid system. This paper reviews the current and future recycling technologies for PV off-grid systems and presents a scheme of the most sustainable recycling technologies which have the potential for adoption. Full Recovery End-of-Life Photovoltaic (FRELP recycling technology can offer opportunities to sustainably recycle crystalline silicon PV modules. Electro-hydrometallurgical process & Vacuum technologies can be used for recovering lead from lead acid batteries with a high recovery rate. The metals in the WEEE can be recycled by using a combination of biometallurgical technology, vacuum metallurgical technology and other advanced metallurgical technologies (utrasonical, mechano-chemical technology while the plastic components can be effectively recycled without separation by using compatibilizers. All these advanced technologies when used in combination with each other provide sustainable recycling options for growing PV off-grid systems waste. These promising technologies still need further improvement and require proper integration techniques before implementation.

  2. Design and cost estimate for the SRL integrated hot off gas facility using selective adsorption

    International Nuclear Information System (INIS)

    Pence, D.T.; Kirstein, B.E.

    1981-07-01

    Based on the results of an engineering-scale demonstration program, a design and cost estimate were performed for a 25-m 3 /h (15-ft 3 /min) capacity pilot plant demonstration system using selective adsorption technology for installation at the Integrated Hot Off Gas Facility at the Savannah River Plant. The design includes provisions for the destruction of NO/sub x/ and the concentration and removal of radioisotopes of ruthenium, iodine-129, tritiated water vapor, carbon-14 contaminated carbon dioxide, and krypton-85. The nobel gases are separated by the use of selective adsorption on mordenite-type zeolites. The theory of noble gas adsorption on zeolites is essentially the same as that for the adsorption of noble gases on activated charcoals. Considerable detail is provided regarding the application of the theory to adsorbent bed designs and operation. The design is based on a comprehensive material balance and appropriate heat transfer calculations. Details are provided on techniques and procedures used for heating, cooling, and desorbing the adsorbent columns. Analyses are also given regarding component and arrangement selection and includes discussions on alternative arrangements. The estimated equipment costs for the described treatment system is about $1,400,000. The cost estimate includes a detailed equipment list of all the major component items in the design. Related technical issues and estimated system performance are also discussed

  3. Design and cost estimate for the SRL integrated hot off gas facility using selective adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Pence, D T; Kirstein, B E

    1981-07-01

    Based on the results of an engineering-scale demonstration program, a design and cost estimate were performed for a 25-m/sup 3//h (15-ft/sup 3//min) capacity pilot plant demonstration system using selective adsorption technology for installation at the Integrated Hot Off Gas Facility at the Savannah River Plant. The design includes provisions for the destruction of NO/sub x/ and the concentration and removal of radioisotopes of ruthenium, iodine-129, tritiated water vapor, carbon-14 contaminated carbon dioxide, and krypton-85. The nobel gases are separated by the use of selective adsorption on mordenite-type zeolites. The theory of noble gas adsorption on zeolites is essentially the same as that for the adsorption of noble gases on activated charcoals. Considerable detail is provided regarding the application of the theory to adsorbent bed designs and operation. The design is based on a comprehensive material balance and appropriate heat transfer calculations. Details are provided on techniques and procedures used for heating, cooling, and desorbing the adsorbent columns. Analyses are also given regarding component and arrangement selection and includes discussions on alternative arrangements. The estimated equipment costs for the described treatment system is about $1,400,000. The cost estimate includes a detailed equipment list of all the major component items in the design. Related technical issues and estimated system performance are also discussed.

  4. Development of the ReuseTechnology for Radioactive Waste from Nuclear Fuel Cycle - Development of the off-gas treatment technology

    International Nuclear Information System (INIS)

    Oh, Won Zin; Lee, H. K.; Park, G. I.; Cho, I. H.; Choi, B. S.; Lee, K. W.; Jeong, M. S.

    1998-09-01

    Treatment technologies for noble gases and semi-volatile gases generated from nuclear fuel cycle process were evaluated, and the optimal process was selected based on process simplicity and safety of disposal. Evaluation of the adsorption capacity of methyl iodine on AgX(silver-impregnated zeolite) and AgS(silver-impregnated silica gel) at the temperature of 80-300 deg C was carried out, and adsorption performances of AgX and AgS were compared with that of activated carbon. CO 2 removal capacity using soda lime, activated carbon and 13X was investigated, and effect of relative humidity was identified. A preparation method of granular calcium hydroxide as a CO-2 removal sorbent using oyster-shells was characterized. This study involves the comparison of the adsorption capacities of Kr on natural or synthetic zeolites and activated carbon at high concentration and an analysis of humidity effect on water adsorption of natural-zeolite. It also was carried out that performance tests for reuse of activated carbon through desorption and re-impregnation process of TEDA/KI impregnated carbon as a removal sorbent for organic radio iodines. (author). 132 refs., 17 tabs., 29 figs

  5. Formation rate of ammonium nitrate in the off-gas line of SRAT and SME in DWPF

    International Nuclear Information System (INIS)

    Lee, L.

    1992-01-01

    A mathematical model for the formation rate of ammonium nitrate in the off-gas line of the Sludge Receipt and Adjustment Tank (SRAT) and the Slurry Mixed Evaporator (SME) in DWPF has been developed. The formation rate of ammonium nitrate in the off-gas line depends on pH, temperature, volume and total concentration of ammonia and ammonium ion. Based on a typical SRAT and SME cycle in DWPF, this model predicts the SRAT contributes about 50 lbs of ammonium nitrate while SME contributes about 60 lbs of ammonium nitrate to the off-gas line

  6. Technologic spin-off from CNEA's activities

    International Nuclear Information System (INIS)

    Belinco, Cesar G.

    2001-01-01

    An analysis is made of the spin-off of technology from the nuclear activities in Argentina. Several examples are mentioned in fields such as material sciences, non-destructive testing, forensic research, space activities, instrumentation as well as in environmental studies

  7. Pulmonary hemodynamics and gas exchange in off pump coronary artery bypass grafting.

    Science.gov (United States)

    Vedin, Jenny; Jensen, Ulf; Ericsson, Anders; Samuelsson, Sten; Vaage, Jarle

    2005-10-01

    To investigate the influence of cardiopulmonary bypass on pulmonary hemodynamics and gas exchange. Low risk patients admitted for elective coronary artery bypass grafting were randomized to either on (n=25) or off pump (n=25) surgery. Central hemodynamics, gas exchange, and venous admixture were studied during and up to 20 h after surgery. There was no difference in pulmonary vascular resistance index (P=0.16), right ventricular stroke work index (P>0.2), mean pulmonary artery pressure (P>0.2) or pulmonary capillary wedge pressure (P>0.2) between groups. Soon after surgery there was a tendency towards higher cardiac index (P=0.07) in the off pump group. Arterial oxygen tension (P>0.2), hematocrit (P>0.2), venous admixture (P>0.2), and arterial-venous oxygen content difference (P=0.12) did not differ between groups. This prospective, randomized study showed no difference in pulmonary hemodynamics, pulmonary gas exchange, and venous admixture, in low risk patients undergoing off pump compared to on pump coronary artery bypass surgery.

  8. Cervical Precancer Treatment in Low- and Middle-Income Countries: A Technology Overview

    Directory of Open Access Journals (Sweden)

    Mauricio Maza

    2017-08-01

    Full Text Available Cervical cancer is the fourth leading cause of cancer-related death in women worldwide, with 90% of cases occurring in low- and middle-income countries (LMICs. There has been a global effort to increase access to affordable screening in these settings; however, a corresponding increase in availability of effective and inexpensive treatment modalities for ablating or excising precancerous lesions is also needed to decrease mortality. This article reviews the current landscape of available and developing technologies for treatment of cervical precancer in LMICs. At present, the standard treatment of most precancerous lesions in LMICs is gas-based cryotherapy. This low-cost, effective technology is an expedient treatment in many areas; however, obtaining and transporting gas is often difficult, and unwieldy gas tanks are not conducive to mobile health campaigns. There are several promising ablative technologies in development that are gasless or require less gas than conventional cryotherapy. Although further evaluation of the efficacy and cost-effectiveness is needed, several of these technologies are safe and can now be implemented in LMICs. Nonsurgical therapies, such as therapeutic vaccines, antivirals, and topical applications, are also promising, but most remain in early-stage trials. The establishment of evidence-based standardized protocols for available treatments and the development and introduction of novel technologies are necessary steps in overcoming barriers to treatment in LMICs and decreasing the global burden of cervical cancer. Guidance from WHO on emerging treatment technologies is also needed.

  9. A model for utilizing industrial off-gas to support microalgae cultivation for biodiesel in cold climates

    International Nuclear Information System (INIS)

    Laamanen, Corey A.; Shang, Helen; Ross, Gregory M.; Scott, John A.

    2014-01-01

    Highlights: • Development of a model to assess process-coupled algae production in cold climates. • Algae growth temperatures in open tanks can be maintained with industrial off-gas. • Indirect and direct heat application from industrial off-gasses are assessed. • CO 2 -rich off-gas can be bubbled into algae tanks to provide a carbon source. • A nickel smelter’s off-gas is used to demonstrate how waste heat can be repurposed. - Abstract: Lipids produced by microalgae are a promising biofuel feedstock. However, as most commercial mass production of microalgae is in open raceway ponds it is generally considered only a practical option in regions where year-round ambient temperatures remain above 15 °C. To address this issue it has been proposed to couple microalgae production with industries that produce large amounts of waste heat and carbon dioxide (CO 2 ). The CO 2 would provide a carbon source for the microalgae and the waste heat would allow year-round cultivation to be extended to regions that experience seasonal ambient temperatures well below 15 °C. To demonstrate this concept, a dynamic model has been constructed that predicts the impact on algal pond temperature from both bubbled-in off-gas and heat indirectly recovered from off-gas. Simulations were carried out for a variety of global locations using the quantity off-gas and waste energy from a smelter’s operations to determine the volume of microalgae that could be maintained above 15 °C. The results demonstrate the feasibility of year-round microalgae production in climates with relatively cold winter seasons

  10. LFCM [liquid-fed eramic melter] emission and off-gas system performance for feed component cesium

    International Nuclear Information System (INIS)

    Goles, R.W.; Andersen, C.M.

    1986-09-01

    Except for volatile off-gas effluents, overall adequacy of the liquid-fed ceramic melter (LFCM) system depends most upon its effectiveness in dealing with cesium. However, the mechanism responsible for melter cesium losses has proved insensitive to many LFCM operating and processing conditions. As a result, variations in inleakage, plenum temperature, feeding rate and waste loading do not significantly influence melter cesium performance. Feed composition, specifically halogen content, is the only processing variable that has had a significant effect. Due to the submicron nature of LFCM-generated aerosols, melter disengagement design features are not expected to be particularly effective in reducing cesium emission rates. For the same reason, the cesium performance of conventional quench scrubbers is quite low, being dependent only upon the magnitude of melter entrainment losses. Although a deep bed washable filter has been effective in removing submicron aerosols from the process exhaust, high performance has only been achieved under dry operating conditions. The melter's idling state does not appear to place additional demands upon the off-gas treatment system

  11. International survey on gas technology organizations

    International Nuclear Information System (INIS)

    1994-11-01

    The International Survey on Gas Technology Organizations has been prepared by the IEA International Centre for Gas Technology Information. 172 companies and R and D Institutions from 41 countries have contributed to the survey. The objective of the Survey is to develop an overview of identified organizations active in the development of new gas technology. As a quick reference guide the survey offers you short descriptions of a number of the most important organizations within gas technology on a world wide basis. Many R and D institutions around the world are working with topics of relevance to the gas industry. New gas technology draws on many different scientific and technical disciplines. This first issue of the survey includes only a part of the numerous organizations and institutions active within the development of new technology of relevance to the gas industry. The preparation of this survey has been a first step in the development of the information activities of the Centre. The information regarding organizations with R and D activities of relevance to the gas industry will continuously be expanded and updated for internal use in the Centre and will also be available to external users. The Centre plans to establish on-line access to these update versions during 1995. (EG)

  12. Off gas condenser performance modelling

    International Nuclear Information System (INIS)

    Cains, P.W.; Hills, K.M.; Waring, S.; Pratchett, A.G.

    1989-12-01

    A suite of three programmes has been developed to model the ruthenium decontamination performance of a vitrification plant off-gas condenser. The stages of the model are: condensation of water vapour, NO x absorption in the condensate, RuO 4 absorption in the condensate. Juxtaposition of these stages gives a package that may be run on an IBM-compatible desktop PC. Experimental work indicates that the criterion [HNO 2 ] > 10 [RuO 4 ] used to determine RuO 4 destruction in solution is probably realistic under condenser conditions. Vapour pressures of RuO 4 over aqueous solutions at 70 o -90 o C are slightly lower than the values given by extrapolating the ln K p vs. T -1 relation derived from lower temperature data. (author)

  13. Advanced sulfur control concepts for hot gas desulfurization technology

    International Nuclear Information System (INIS)

    1998-01-01

    The objective of this project is to develop a hot-gas desulfurization process scheme for control of H 2 S in HTHP coal gas that can be more simply and economically integrated with known regenerable sorbents in DOE/METC-sponsored work than current leading hot-gas desulfurization technologies. In addition to being more economical, the process scheme to be developed must yield an elemental sulfur byproduct. The Direct Sulfur Recovery Process (DSRP), a leading process for producing an elemental sulfur byproduct in hot-gas desulfurization systems, incurs a coal gas use penalty, because coal gas is required to reduce the SO 2 in regeneration off-gas to elemental sulfur. Alternative regeneration schemes, which avoid coal gas use and produce elemental sulfur, will be evaluated. These include (i) regeneration of sulfided sorbent using SO 2 ; (ii) partial oxidation of sulfided sorbent in an O 2 starved environment; and (iii) regeneration of sulfided sorbent using steam to produce H 2 S followed by direct oxidation of H 2 S to elemental sulfur. Known regenerable sorbents will be modified to improve the feasibility of the above alternative regeneration approaches. Performance characteristics of the modified sorbents and processes will be obtained through lab- and bench-scale testing. Technical and economic evaluation of the most promising processes concept(s) will be carried out

  14. Absorption process for removing krypton from the off-gas of an LMFBR fuel reprocessing plant

    International Nuclear Information System (INIS)

    Stephenson, M.J.; Dunthorn, D.I.; Reed, W.D.; Pashley, J.H.

    1975-01-01

    The Oak Ridge Gaseous Diffusion Plant selective absorption process for the collection and recovery of krypton and xenon is being further developed to demonstrate, on a pilot scale, a fluorocarbon-based process for removing krypton from the off-gas of an LMFBR fuel reprocessing plant. The new ORGDP selective absorption pilot plant consists of a primary absorption-stripping operation and all peripheral equipment required for feed gas preparation, process solvent recovery, process solvent purification, and krypton product purification. The new plant is designed to achieve krypton decontamination factors in excess of 10 3 with product concentration factors greater than 10 4 while processing a feed gas containing typical quantities of common reprocessing plant off-gas impurities, including oxygen, carbon dioxide, nitrogen oxides, water, xenon, iodine, and methyl iodide. Installation and shakedown of the facility were completed and some short-term tests were conducted early this year. The first operating campaign using a simulated reprocessing plant off-gas feed is now underway. The current program objective is to demonstrate continuous process operability and performance for extended periods of time while processing the simulated ''dirty'' feed. This year's activity will be devoted to routine off-gas processing with little or no deliberate system perturbations. Future work will involve the study of the system behavior under feed perturbations and various plant disturbances. (U.S.)

  15. Fiscal 2000 achievement report. Development of technologies for waste treatment and recycling (Development of technologies for appropriate treatment of air bags); 2000 nendo haikibutsu recycle kanren gijutsu kaihatsu seika hokokusho. Air bag tekisei shori gijutsu no kaihatsu nado

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    A centralized treatment process respecting environmental protection and safety for unused air bags aboard disused automobiles is developed. In concrete terms, a heating facility owned by Daicel Chemical Industries, Ltd., is used, which includes an apparatus for examining exhaust gas dioxins and an exhaust gas treatment apparatus and, with this facility, studies are made for appropriately treating waste gas and waste water to be generated when air bag modules undergo centralized heating. Endeavors in fiscal 2000 center about (1) the development of waste gas treatment technologies, (2) development of waste water treatment technologies, (3) chemical analysis of waste water sludge, dusts and air bag residues, and (4) the study of appropriate treatment of non-azide air bag modules. As to the development of exhaust gas treatment technology, it was proved that the exhaust gas treatment system consisting of secondary incineration furnace, exhaust gas cooling tower and bag filter worked effectively. (NEDO)

  16. Spin-off technologies developed through nuclear activities

    International Nuclear Information System (INIS)

    1993-01-01

    Given the changing role of government research establishments and the interest in maximizing return on capital and intellectual investment, determining the best way to apply or ''spin-off'' technologies from the nuclear field into other industrial and commercial sectors is of increasing concern. This study by the OECD Nuclear Energy Agency draws on expertise from numerous countries to determine what the spin-offs are, where they come from, and how they can best be fostered. It looks both at the results and process of spin-offs, and helps decision-makers in government and project leaders and managers in industry to maximize their benefits. (author)

  17. Evaluation technology for burnup and generated amount of plutonium by measurement of Xenon isotopic ratio in dissolver off-gas at reprocessing facility (Joint research)

    International Nuclear Information System (INIS)

    Okano, Masanori; Kuno, Takehiko; Shirouzu, Hidetomo; Yamada, Keiji; Sakai, Toshio; Takahashi, Ichiro; Charlton, William S.; Wells, Cyndi A.; Hemberger, Philip H.

    2006-12-01

    The amount of Pu in the spent fuel was evaluated from Xe isotopic ratio in off-gas in reprocessing facility, is related to burnup. Six batches of dissolver off-gas (DOG) at spent fuel dissolution process were sampled from the main stack in Tokai Reprocessing Plant (TRP) during BWR fuel (approx. 30GWD/MTU) reprocessing campaign. Xenon isotopic ratio was determined with Gas Chromatography/Mass Spectrometry. Burnup and generated amount of Pu were evaluated with Noble Gas Environmental Monitoring Application code (NOVA), developed by Los Alamos National Laboratory. Inferred burnup evaluated by Xe isotopic measurements and NOVA were in good agreement with those of the declared burnup in the range from -3.8% to 7.1%. Also, the inferred amount of Pu in spent fuel was in good agreed with those of the declared amount of Pu calculated by ORIGEN code in the range from -0.9% to 4.7%. The evaluation technique is applicable for both burnup credit to achieve efficient criticality safety control and a new measurement method for safeguards inspection. (author)

  18. International Center for Gas Technology Information

    International Nuclear Information System (INIS)

    Gad, L.H.

    1993-01-01

    Based on an acknowledgement of the growing importance of natural gas, a number of European countries, USA, Japan and the Russian Federation have worked together in order to establish a common center of information on natural gas technology under the auspices of the International Energy Agency. Centers were to be established in Washington and in Denmark. The centers will concern themselves with establishing an international information center for gas technology, effecting natural gas technology transfer between global regions, carrying out analytical studies on the energy market and the development of technology within the field of natural gas. The structure of the decision-making processes that will be employed is explained in addition to the organization and economy. The centers should build up a global information network between the relevant countries, their gas companies, institutions etc. (AB)

  19. Gas Storage Technology Consortium

    Energy Technology Data Exchange (ETDEWEB)

    Joel Morrison; Elizabeth Wood; Barbara Robuck

    2010-09-30

    The EMS Energy Institute at The Pennsylvania State University (Penn State) has managed the Gas Storage Technology Consortium (GSTC) since its inception in 2003. The GSTC infrastructure provided a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. The GSTC received base funding from the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) Oil & Natural Gas Supply Program. The GSTC base funds were highly leveraged with industry funding for individual projects. Since its inception, the GSTC has engaged 67 members. The GSTC membership base was diverse, coming from 19 states, the District of Columbia, and Canada. The membership was comprised of natural gas storage field operators, service companies, industry consultants, industry trade organizations, and academia. The GSTC organized and hosted a total of 18 meetings since 2003. Of these, 8 meetings were held to review, discuss, and select proposals submitted for funding consideration. The GSTC reviewed a total of 75 proposals and committed co-funding to support 31 industry-driven projects. The GSTC committed co-funding to 41.3% of the proposals that it received and reviewed. The 31 projects had a total project value of $6,203,071 of which the GSTC committed $3,205,978 in co-funding. The committed GSTC project funding represented an average program cost share of 51.7%. Project applicants provided an average program cost share of 48.3%. In addition to the GSTC co-funding, the consortium provided the domestic natural gas storage industry with a technology transfer and outreach infrastructure. The technology transfer and outreach were conducted by having project mentoring teams and a GSTC website, and by working closely with the Pipeline Research Council International (PRCI) to

  20. Adequate Measuring Technology and System of Fission Gas release Behavior from Voloxidation Process

    International Nuclear Information System (INIS)

    Park, Geun Il; Park, J. J.; Jung, I. H.; Shin, J. M.; Yang, M. S.; Song, K. C.

    2006-09-01

    Based on the published literature and an understanding of available hot cell technologies, more accurate measuring methods for each volatile fission product released from voloxidation process were reviewed and selected. The conceptual design of an apparatus for measuring volatile and/or semi-volatile fission products released from spent fuel was prepared. It was identified that on-line measurement techniques can be applied for gamma-emitting fission products, and off-line measurement such as chemical/or neutron activation analysis can applied for analyzing beta-emitting fission gases. Collection methods using appropriate material or solutions were selected to measure the release fraction of beta-emitting gaseous fission products at IMEF M6 hot cell. Especially, the on-line gamma-ray counting system for monitoring of 85Kr and the off-line measuring system of 14C was established. On-line measuring system for obtaining removal ratios of the semi-volatile fission products, mainly gamma-emitting fission products such as Cs, Ru etc., was also developed at IMEF M6 hot cell which was based on by measuring fuel inventory before and after the voloxidation test through gamma measuring technique. The development of this measurement system may enable basic information to be obtained to support design of the off-gas treatment system for the voloxidation process at INL, USA

  1. Multi-objective optimisation of wastewater treatment plant control to reduce greenhouse gas emissions.

    Science.gov (United States)

    Sweetapple, Christine; Fu, Guangtao; Butler, David

    2014-05-15

    This study investigates the potential of control strategy optimisation for the reduction of operational greenhouse gas emissions from wastewater treatment in a cost-effective manner, and demonstrates that significant improvements can be realised. A multi-objective evolutionary algorithm, NSGA-II, is used to derive sets of Pareto optimal operational and control parameter values for an activated sludge wastewater treatment plant, with objectives including minimisation of greenhouse gas emissions, operational costs and effluent pollutant concentrations, subject to legislative compliance. Different problem formulations are explored, to identify the most effective approach to emissions reduction, and the sets of optimal solutions enable identification of trade-offs between conflicting objectives. It is found that multi-objective optimisation can facilitate a significant reduction in greenhouse gas emissions without the need for plant redesign or modification of the control strategy layout, but there are trade-offs to consider: most importantly, if operational costs are not to be increased, reduction of greenhouse gas emissions is likely to incur an increase in effluent ammonia and total nitrogen concentrations. Design of control strategies for a high effluent quality and low costs alone is likely to result in an inadvertent increase in greenhouse gas emissions, so it is of key importance that effects on emissions are considered in control strategy development and optimisation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Options for cleaning up subsurface contamination at Alberta sour gas plants

    International Nuclear Information System (INIS)

    Hardisty, P.; Dabrowski, T.L.

    1992-01-01

    At the conclusion of two major phases of a study on subsurface treatment technologies for Alberta sour gas plants, a candidate site was selected for a remediation technologies demonstration project. The plant has an extensive groundwater monitoring network in place, monitoring records for a period exceeding 10 years, ten recovery wells with aquifer test data and four reinjection wells. Hydrogeological exploration determined the presence and delineated a plume of free phase natural gas condensate. Aquifer remediation efforts at the site began in 1990 with the installation of recovery wells. Recovered groundwater was treated using a pilot scale air stripping system with pretreatment for iron, manganese and hardness. Dual pump system, water depression and free product skimmers were installed in the wells and tested. The nature and extent of contamination, study methodology, technology-dependent criteria, assessment of technology, and conceptual design are discussed for the three demonstration projects selected, which are enhanced soil vapour extraction with off-gas treatment, pump-and-treat with soil vapour extraction, biological treatment and air sparging, and treatment of dissolved process chemicals by advanced oxidation. 5 refs., 1 fig., 1 tab

  3. Unregulated greenhouse gas and ammonia emissions from current technology heavy-duty vehicles.

    Science.gov (United States)

    Thiruvengadam, Arvind; Besch, Marc; Carder, Daniel; Oshinuga, Adewale; Pasek, Randall; Hogo, Henry; Gautam, Mridul

    2016-11-01

    The study presents the measurement of carbonyl, BTEX (benzene, toluene, ethyl benzene, and xylene), ammonia, elemental/organic carbon (EC/OC), and greenhouse gas emissions from modern heavy-duty diesel and natural gas vehicles. Vehicles from different vocations that included goods movement, refuse trucks, and transit buses were tested on driving cycles representative of their duty cycle. The natural gas vehicle technologies included the stoichiometric engine platform equipped with a three-way catalyst and a diesel-like dual-fuel high-pressure direct-injection technology equipped with a diesel particulate filter (DPF) and a selective catalytic reduction (SCR). The diesel vehicles were equipped with a DPF and SCR. Results of the study show that the BTEX emissions were below detection limits for both diesel and natural gas vehicles, while carbonyl emissions were observed during cold start and low-temperature operations of the natural gas vehicles. Ammonia emissions of about 1 g/mile were observed from the stoichiometric natural gas vehicles equipped with TWC over all the driving cycles. The tailpipe GWP of the stoichiometric natural gas goods movement application was 7% lower than DPF and SCR equipped diesel. In the case of a refuse truck application the stoichiometric natural gas engine exhibited 22% lower GWP than a diesel vehicle. Tailpipe methane emissions contribute to less than 6% of the total GHG emissions. Modern heavy-duty diesel and natural gas engines are equipped with multiple after-treatment systems and complex control strategies aimed at meeting both the performance standards for the end user and meeting stringent U.S. Environmental Protection Agency (EPA) emissions regulation. Compared to older technology diesel and natural gas engines, modern engines and after-treatment technology have reduced unregulated emissions to levels close to detection limits. However, brief periods of inefficiencies related to low exhaust thermal energy have been shown to

  4. The development of radioactive waste treatment technology(IV)

    International Nuclear Information System (INIS)

    Kim, Joon Hyung; Ahan, Byung Gil; Kim, Jeong Guk; Yim, Sung Paal

    1992-03-01

    A full-scale silicon carbide filter (flanged candle type) was made by using an oxide ceramic binder. From the results of filtration test, the manufactured SiC filter was comparable to foreign commercial filters. But the composite type filter with a thin fiber layer on its surface showed more excellent filtration performance than granular bed filter. It is expected that large hysterisis of sintering binder on heating and cooling process would cause a problem in high temperature application. From the results, the development of composite type filter and a study on sintering binder must be continued. Such study results could be utilized for the off-gas treatment of radioactive waste treatment process and general industry. And it will be used as a basic data for solid/gas separation process. (Author)

  5. Optical technologies applied alongside on-site and remote approaches for climate gas emission quantification at a wastewater treatment plant

    DEFF Research Database (Denmark)

    Samuelsson, Jerker; Delre, Antonio; Tumlin, Susanne

    2018-01-01

    Plant-integrated and on-site gas emissions were quantified from a Swedish wastewater treatment plant by applying several optical analytical techniques and measurement methods. Plant-integrated CH4 emission rates, measured using mobile ground-based remote sensing methods, varied between 28.5 and 33.......5 kg CH4 h−1, corresponding to an average emission factor of 5.9% as kg CH4 (kg CH4production) −1, whereas N2O emissions varied between 4.0 and 6.4 kg h−1, corresponding to an average emission factor of 1.5% as kg N2O-N (kg TN influent) −1. Plant-integrated NH3 emissions were around 0.4 kg h−1...... quantifications were approximately two-thirds of the plant-integrated emission quantifications, which may be explained by the different timeframes of the approaches and that not all emission sources were identified during on-site investigation. Off-site gas emission quantifications, using ground-based remote...

  6. Thinning of Inner Retinal Layers after Vitrectomy with Silicone Oil versus Gas Endotamponade in Eyes with Macula-Off Retinal Detachment.

    Science.gov (United States)

    Purtskhvanidze, Konstantine; Hillenkamp, Jost; Tode, Jan; Junge, Olaf; Hedderich, Jürgen; Roider, Johann; Treumer, Felix

    2017-01-01

    To evaluate retinal layer thickness with optical coherence tomography (OCT) in eyes with macula-off retinal detachment after silicone oil (SiO) or gas endotamponade. Cross-sectional study of 40 eyes with macula-off rhegmatogenous retinal detachment that underwent vitrectomy. 20 eyes received SiO tamponade and 20 matched eyes received gas. 33 healthy fellow eyes served as controls. Macular spectral domain OCT was performed with automated layer detection in the 5 inner subfields of the Early Treatment Diabetic Retinopathy Study (ETDRS) map. Comparing the SiO group with the gas group, the ganglion cell layer showed a significant thinning in all fields of the inner ring of the ETDRS map, the inner plexiform layer in the nasal, superior and temporal quadrants, and the outer plexiform layer in the nasal quadrant. Inner retinal layers in the fovea/parafovea were significantly thinner in the SiO group. Prospective studies are warranted to further elucidate possible retinal adverse effects of SiO tamponade. © 2017 S. Karger AG, Basel.

  7. Off-gas characteristics of defense waste vitrification using liquid-fed Joule-heated ceramic melters

    International Nuclear Information System (INIS)

    Goles, R.W.; Sevigny, G.J.

    1983-09-01

    Off-gas and effluent characterization studies have been established as part of a PNL Liquid-Fed Ceramic Melter development program supporting the Savannah River Laboratory Defense Waste Processing Facility (SRL-DWPF). The objectives of these studies were to characterize the gaseous and airborne emission properties of liquid-fed joule-heated melters as a function of melter operational parameters and feed composition. All areas of off-gas interest and concern including effluent characterization, emission control, flow rate behavior and corrosion effects have been studied using alkaline and formic-acid based feed compositions. In addition, the behavioral patterns of gaseous emissions, the characteristics of melter-generated aerosols and the nature and magnitude of melter effluent losses have been established under a variety of feeding conditions with and without the use of auxiliary plenum heaters. The results of these studies have shown that particulate emissions are responsible for most radiologically important melter effluent losses. Melter-generated gases have been found to be potentially flammable as well as corrosive. Hydrogen and carbon monoxide present the greatest flammability hazard of the combustibles produced. Melter emissions of acidic volatile compounds of sulfur and the halogens have been responsible for extensive corrosion observed in melter plenums and in associated off-gas lines and processing equipment. The use of auxiliary plenum heating has had little effect upon melter off-gas characteristics other than reducing the concentrations of combustibles

  8. Materials performance in off-gas systems containing iodine

    International Nuclear Information System (INIS)

    Beavers, J.A.; Berry, W.E.; Griess, J.C.

    1981-11-01

    During the reprocessing of spent reactor fuel elements, iodine is released to gas streams from which it is ultimately removed by conversion to nonvolatile iodic acid. Under some conditions iodine can produce severe corrosion in off-gas lines; in this study these conditions were established. Iron- and nickel-based alloys containing more than 6% molybdenum, such as Hastelloy G (7%), Inconel 625 (9%), and Hastelloy C-276 (16%), as well as titanium and zirconium, remained free of attack under all conditions tested. When the other materials, notably the austenitic stainless steels, were exposed to gas streams containing even only low concentrations of iodine and water vapors at 25 and 40 0 C, a highly corrosive, brownish-green liquid formed on their surfaces. In the complete absence of water vapor, the iodine-containing liquid did not form and all materials remained unaffected. The liquid that formed had a low pH (usually 2 inhibited attack

  9. Off-Gas Analysis During the Vitrification of Hanford Radioactive Waste Samples

    International Nuclear Information System (INIS)

    Ha, B.C.; Ferrara, D.M.; Crawford, C.L.; Choi, A.S.; Bibler, N.E.

    1998-01-01

    This paper describes the off-gas analysis of samples collected during the radioactive vitrification experiments. Production and characterization of the Hanford waste-containing LAW and HAW glasses are presented in related reports from this conference

  10. Technology spin-offs from the magnetic fusion energy program

    International Nuclear Information System (INIS)

    1982-05-01

    A description is given of 138 possible spin-offs from the magnetic fusion program. The spin-offs cover the following areas: (1) superconducting magnets, (2) materials technology, (3) vacuum systems, (4) high frequency and high power rf, (5) electronics, (6) plasma diagnostics, (7) computers, and (8) particle beams

  11. Removal of carbon dioxide in reprocessing spent nuclear fuel off gas by adsorption

    International Nuclear Information System (INIS)

    Fukumatsu, Teruki; Munakata, Kenzo; Tanaka, Kenji; Yamatsuki, Satoshi; Nishikawa, Masabumi

    1998-01-01

    The off gas produced by reprocessing spent nuclear fuel includes various radioactivities and these nuclei should be removed. In particular, 14 C mainly released as the form of carbon dioxide is one of the most required gaseous radioactivities to be removed because it has long a half-life. One of the methods to remove gaseous nuclei is the use of adsorption technique. The off gas contains water vapor which influences adsorption process of carbon dioxide. In this report, behavior of adsorption of carbon dioxide on various adsorbent and influence on adsorption behavior of carbon dioxide by containing water vapor are discussed. (author)

  12. Technological substitution options for controlling greenhouse gas emissions

    International Nuclear Information System (INIS)

    Barbier, E.B.; Burgess, J.C.; Pearce, D.W.

    1991-01-01

    This chapter is concerned with technological options for greenhouse gas substitution. The authors interpret the term substitution to exclude energy conservation/efficiency measures, investments in afforestation (sinks), and greenhouse gas removal or abatement technologies. Their working definition of greenhouse gas substitution includes (1) replacement technologies, for example, substituting a greenhouse gas technology with a nongreenhouse gas technology; and (2) reduction technologies, for example, substituting a greenhouse gas technology with an alternative technology that reduces greenhouse gas emissions. Essentially, replacement technologies involve 100 percent reduction in CO 2 ; reduction technologies involve a partial reduction in CO 2 . Of the man-made sources of greenhouse gases, energy is the most important and is expected to contribute to at least half of the global warming effect in the near future. The majority of this impact is from fossil fuel combustion as a source of carbon dioxide (CO 2 ), although fossil fuels also contribute significantly to methane (CH 4 ), to nitrous oxide (N 2 O), and to low-level ozone (O 3 ) through production of various nitrogen gases (NO x ) and carbon monoxide (CO). This study analyzes the available greenhouse gas substitutions and their costs. The authors concentrate particularly on substitutions for fossil-fuel combustion and CFC production and consumption. They conclude by summarizing the potential for greenhouse gas substitution, the cost-effectiveness of the various options and the design of incentives for substitution

  13. Studies in the dissolver off-gas system for a spent FBR fuel reprocessing plant

    International Nuclear Information System (INIS)

    Heinrich, E.; Huefner, R.; Weirich, F.

    1982-01-01

    Investigations of possible modifications of the process steps of a dissolver off-gas (DOG) system for a spent FBR fuel reprocessing plant are reported. The following operations are discussed: iodine removal from the fuel solution; behaviour of NOsub(x) and iodine in nitric acid off-gas scrubbers at different temperatures and nitric acid concentrations; iodine desorption from the scrub acid; selective absorption of noble gases in refrigerant-12; cold traps. The combination of suitable procedures to produce a total DOG system is described. (U.K.)

  14. Pilot test of flue gas treatment by electron beam

    International Nuclear Information System (INIS)

    Tokunaga, Okihiro

    1995-01-01

    The development of the technology of the desulfurization and denitration for flue gas by using electron beam was started in Japan in 1970s, and since then, the development research for putting it to practical use and the basic research on the subjects which must be resolved for promoting the practical use have been advanced. Based on these results, the verifying test using a pilot scale plant was carried out from 1991 to 1994 for the treatment of coal-burning flue gas, municipal waste-burning flue gas and highway tunnel exhaust gas. The operation of the pilot plant was already finished, and the conceptual design of a practical scale plant based on the results and the assessment of the economical efficiency were performed. As for the coal-burning flue gas treatment by using electron beam, the basic test, the pilot test and the conceptual design of a practical scale plant and the assessment of the economical efficiency are reported. As for the municipal waste-burning flue gas treatment by using electron beam, the basic test and the pilot test are reported. Also the pilot test on the denitration of exhaust gas in highway tunnels in reported. In Poland, the pilot test on the treatment of flue gas in coal-burning thermal power stations is carried out. In Germany, the technical development for cleaning the air contaminated by volatile organic compounds by electron beam irradiation is advanced. (K.I.)

  15. New technological developments in gas processing

    International Nuclear Information System (INIS)

    Draper, R.C.

    1996-01-01

    The changes that the natural gas industry has undergone over the last few years was discussed. Low natural gas prices forced companies to react to their high reserves replacements costs. They were forced to downsize and undergo major restructuring because they were losing money due to high operating costs; the future for natural gas prices looked pessimistic. The changes have led to a new kind of business practice, namely 'partnering with third party processor', mid-stream companies known as aggregators, to build and operate facilities as part of a move towards cost effective improvements for gas producers. Besides reducing capital and operating costs, the producer under this arrangements can dedicate his capital to finding new gas which is the basis of growth. Recent technological changes in the gas processing industry were also touched upon. These included enhanced technologies such as increased liquid hydrocarbon recovery, segregation of C3+ and C5+, installation of gas separation membrane systems, small sulphur plants, acid gas injection and selective or mixed solvents. Details of some of these technologies were described. 2 refs., 2 figs

  16. A hybrid plasma-chemical system for high-NOx flue gas treatment

    Science.gov (United States)

    Chmielewski, Andrzej G.; Zwolińska, Ewa; Licki, Janusz; Sun, Yongxia; Zimek, Zbigniew; Bułka, Sylwester

    2018-03-01

    The reduction of high concentrations of NOx and SO2 from simulated flue gas has been studied. Our aim was to optimise energy consumption for NOx and SO2 removal from off-gases from a diesel generator using heavy fuel oil. A hybrid process: electron beam (EB) plasma and wet scrubber has been applied. A much higher efficiency of NOx and SO2 removal was achieved in comparison to dry, ammonia free, electron beam flue gas treatment (EBFGT). A recorded removal from a concentration of 1500 ppm NOx reached 49% at a low dose of 6.5 kGy, while only 2% NOx was removed at the same dose if EB only was applied. For SO2, removal efficiency at a dose of 6.5 kGy increased from 15% (EB only) to 84% when sea water was used as a wet scrubber agent for 700 ppm SO2. The results of this study indicate that EB combined with wet scrubber is a very promising technology to be applied for removal of high concentrations of NOx and SO2 emitted from diesel engines operated e.g. on cargo ships, which are the main sources of SO2 and NOx pollution along their navigation routes.

  17. Gas-fired electric power generating technologies

    International Nuclear Information System (INIS)

    1994-09-01

    The workshop that was held in Madrid 25-27 May 1994 included participation by experts from 16 countries. They represented such diverse fields and disciplines as technology, governmental regulation, economics, and environment. Thus, the participants provided an excellent cross section of key areas and a diversity of viewpoints. At the workshop, a broad range of topics regarding gas-fired electric power generation was discussed. These included political, regulatory and financial issues as well as more specific technical questions regarding the environment, energy efficiency, advanced generation technologies and the status of competitive developments. Important technological advances in gas-based power and CHP technologies have already been achieved including higher energy efficiency and lower emissions, with further improvements expected in the near future. Advanced technology trends include: (a) The use of gas technology to reduce emissions from existing coal-fired power plants. (b) The wide-spread application of combined-cycle gas turbines in new power plants and the growing use of aero-derivative gas turbines in CHP applications. (c) Phosphoric acid fuel cells that are being introduced commercially. Their market penetration will grow over the next 10 years. The next generation of fuel cells (solid oxide and molten carbonate) is expected to enter the market around the year 2000. (EG)

  18. Installation of laboratory scale flue gas treatment system at ALURTRON, MINT

    International Nuclear Information System (INIS)

    Siti A'iasah Hashim; Khairul Zaman Dahlan; Zulkafli Ghazali; Khomsaton Abu Bakar, Ayub Muhamad

    2002-01-01

    A laboratory scale test rig to treat simulated flue gas using electron beam technology was installed at the Alurtron EB-irradiation center, MINT. The experiment test rig was proposed as a result of a feasibility studies conducted jointly by IAEA, MINT and TNB Research in 1997. The test rig system consisted of several components, among other, diesel generator, gas analyzers and spray cooler. The installation was completed and commissioned in October 2001. Results from the commissioning test runs and subsequent experimental work showed that the efficiency of the gas treatment is high. It was proven that electron beam technology might be applied in the treatment of air pollutants. This paper describes the design and work function of the individual major components as well as the full system function. Results from the initial experimental works are also presented. (Author)

  19. Selective absorption pilot plant for decontamination of fuel reprocessing plant off-gas

    Energy Technology Data Exchange (ETDEWEB)

    Stephenson, M.J.; Eby, R.S.; Huffstetler, V.C.

    1977-10-01

    A fluorocarbon-based selective absorption process for removing krypton-85, carbon-14, and radon-222 from the off-gas of conventional light water and advanced reactor fuel reprocessing plants is being developed at the Oak Ridge Gaseous Diffusion Plant in conjunction with fuel recycle work at the Oak Ridge National Laboratory and at the Savannah River Laboratory. The process is characterized by an especially high tolerance for many other reprocessing plant off-gas components. This report presents detailed drawings and descriptions of the second generation development pilot plant as it has evolved after three years of operation. The test facility is designed on the basis of removing 99% of the feed gas krypton and 99.9% of the carbon and radon, and can handle a nominal 15 scfm (425 slm) of contaminated gas at pressures from 100 to 600 psig (7.0 to 42.2 kg/cm/sup 2/) and temperatures from minus 45 to plus 25/sup 0/F (-43 to -4/sup 0/C). Part of the development program is devoted to identifying flowsheet options and simplifications that lead to an even more economical and reliable process. Two of these applicative flowsheets are discussed.

  20. Vanadium redox flow batteries to reach greenhouse gas emissions targets in an off-grid configuration

    International Nuclear Information System (INIS)

    Arbabzadeh, Maryam; Johnson, Jeremiah X.; De Kleine, Robert; Keoleian, Gregory A.

    2015-01-01

    Highlights: • We assess energy storage role in reaching emissions targets in an off-grid model. • The energy storage technology is vanadium redox flow battery (VRFB). • We evaluate life cycle GHG emissions and total cost of delivered electricity. • Generation mixes are optimized to meet emissions targets at the minimum cost. • For this model, integrating VRFB is economical to reach very low emissions targets. - Abstract: Energy storage may serve as a solution to the integration challenges of high penetrations of wind, helping to reduce curtailment, provide system balancing services, and reduce emissions. This study determines the minimum cost configuration of vanadium redox flow batteries (VRFB), wind turbines, and natural gas reciprocating engines in an off-grid model. A life cycle assessment (LCA) model is developed to determine the system configuration needed to achieve a variety of CO 2 -eq emissions targets. The relationship between total system costs and life cycle emissions are used to optimize the generation mixes to achieve emissions targets at the least cost and determine when VRFBs are preferable over wind curtailment. Different greenhouse gas (GHG) emissions targets are defined for the off-grid system and the minimum cost resource configuration is determined to meet those targets. This approach determines when the use of VRFBs is more cost effective than wind curtailment in reaching GHG emissions targets. The research demonstrates that while incorporating energy storage consistently reduces life cycle carbon emissions, it is not cost effective to reduce curtailment except under very low emission targets (190 g of CO2-eq/kW h and less for the examined system). This suggests that “overbuilding” wind is a more viable option to reduce life cycle emissions for all but the most ambitious carbon mitigation targets. The findings show that adding VRFB as energy storage could be economically preferable only when wind curtailment exceeds 66% for the

  1. Overview of flue gas treatment in Brazil

    International Nuclear Information System (INIS)

    Calvo, W.A.P.; Duarte, C.L.; Omi, N.M.; Poli, D.C.R.; Lima, W.

    2011-01-01

    The coal mines in Brazil are primarily located in southern part areas. The total coal reserves are approximately 32.8 billions tons, 89% of which are located in Rio Grande do Sul state. The Brazilian agriculture potentiality is very high, mainly due to the availability of flat land and the existence of industrial capacity to supply the main fertilizers needs. Electron beam flue gas treatment process ensures simultaneous removal of SO 2 and NO X from flue gases by single process, requiring no additional wastewater treatment system and can produce useful nitrogen fertilizer consisting of ammonium sulfate (NH 4 ) 2 SO 4 and ammonium nitrate NH 4 NO 3 as by-products. During the TC Project BRA/8/021 - Pilot Plant for Electron Beam Purification of Flue Gas supported by IAEA (1995-1996), a laboratory facility for electron beam flue gas treatment was set at IPEN. In 1997, an official request from Brazilian Government, Ministry of Science & Technology (MCT) and IPEN was made for the Japan Consulting Institute (JCI) to prepare feasibility studies of air pollution control by electron beam flue gas treatment in three power generation companies. These companies are responsible for the power generation, the transmission and the supply of electricity to Brazil: Jorge Lacerda – Eletrosul Centrais Eletricas do Sul do Brasil S.A., Presidente Medici – Companhia Estadual de Energia Eletrica (CEEE) and Piratininga – AES Eletropaulo Thermal Power Plants. (author)

  2. Overview of flue gas treatment in Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Calvo, W. A.P.; Duarte, C. L.; Omi, N. M. [National Nuclear Energy Commission (CNEN), Institute for Nuclear and Energy Research (IPEN), Radiation Technology Center - CTR, Sao Paulo (Brazil); Poli, D. C.R.; Lima, W. [National Nuclear Energy Commission (CNEN), Institute for Nuclear and Energy Research (IPEN), Cyclotron Accelerator Center - CAC, Sao Paulo (Brazil)

    2011-07-01

    The coal mines in Brazil are primarily located in southern part areas. The total coal reserves are approximately 32.8 billions tons, 89% of which are located in Rio Grande do Sul state. The Brazilian agriculture potentiality is very high, mainly due to the availability of flat land and the existence of industrial capacity to supply the main fertilizers needs. Electron beam flue gas treatment process ensures simultaneous removal of SO{sub 2} and NO{sub X} from flue gases by single process, requiring no additional wastewater treatment system and can produce useful nitrogen fertilizer consisting of ammonium sulfate (NH{sub 4}){sub 2}SO{sub 4} and ammonium nitrate NH{sub 4}NO{sub 3} as by-products. During the TC Project BRA/8/021 - Pilot Plant for Electron Beam Purification of Flue Gas supported by IAEA (1995-1996), a laboratory facility for electron beam flue gas treatment was set at IPEN. In 1997, an official request from Brazilian Government, Ministry of Science & Technology (MCT) and IPEN was made for the Japan Consulting Institute (JCI) to prepare feasibility studies of air pollution control by electron beam flue gas treatment in three power generation companies. These companies are responsible for the power generation, the transmission and the supply of electricity to Brazil: Jorge Lacerda – Eletrosul Centrais Eletricas do Sul do Brasil S.A., Presidente Medici – Companhia Estadual de Energia Eletrica (CEEE) and Piratininga – AES Eletropaulo Thermal Power Plants. (author)

  3. Air and gas cleaning technology for nuclear applications

    International Nuclear Information System (INIS)

    First, M.W.

    1986-01-01

    All large-scale uses of radioactive materials require rigid control of off-gases and generated aerosols. Nuclear air and gas cleaning technology has answered the need from the days of the Manhattan Project to the present with a variety of devices. The one with the longest and most noteworthy service is the HEPA (high efficiency particulate air) filter that originally was referred to as an absolute filter in recognition of its extraordinary particle retention characteristics. Activated-charcoal adsorbers have been employed worldwide for retention of volatile radioiodine in molecular and combined forms and, less frequently, for retention of radioactive noble gases. HEPA filters and activated -charcoal adsorbers are often used with auxiliary devices that serve to extend their effective service life or significantly improve collection efficiency under unfavorable operating conditions. Use of both air cleaning devices and their auxiliaries figure prominently in atomic energy, disposal of high- and low-level nuclear wastes, and in the production of fissile materials. The peaceful uses of nuclear energy would be impossible without these, or equivalent, air- and gas-cleaning devices

  4. Separation of the fission product noble gases krypton and xenon from dissolver off-gas in reprocessing HTGR-fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bohnenstingl, J.; Djoa, S. H.; Laser, M.; Mastera, S.; Merz, E.; Morschl, P.

    1976-04-15

    This paper describes a process developed for the retainment and separation of volatile (3H, 129 +131I) and gaseous (85Kr, Xe) fission products from the off-gas produced during dissolution of HTGR-fuel. To prevent unnecessary dilution of liberated noble gases by surrounding atmosphere, a helium purge-gas cycle is applied to enable a coarse fractionating of krypton and xenon by cold-trapping at about 80 deg K after precleaning the gas stream. The process consists of the following steps: deposition of droplets and solid aerosols; chemisorption of iodine on silver impregnated silica gel; catalytic removal of nitrogen oxides and oxygen; drying of the process gas stream; final filtering of abraded solids; deposition of xenon in solid form at 80 deg K and low subpressure; deposition of krypton in solid form at 80 deg K after compression to about 6 bar; decontamination of 85krypton-containing xenon by batch distillation for eventual industrial utilization; and removal of nitrogen and argon enrichment during continuous operation in the purge-gas stream by inleaking air with charcoal. A continuously operating dissolver vessel, closed to the surrounding atmosphere, yields a very high content of noble gases, e.g., 0.35 vol % krypton and 2.0 vol % xenon. The presented off-gas treatment unit is operated in cold runs with 1/3 of the full capacity and can treat about 1 m3 STP/h helium, corresponding to a quantity of about 10,000 MW(e) HTGR-fuel reprocessing plant.

  5. Separation of the fission product noble gases krypton and xenon from dissolver off-gas in reprocessing HTGR-fuel

    International Nuclear Information System (INIS)

    Bohnenstingl, J.; Djoa, S.H.; Laser, M.; Mastera, S.; Merz, E.; Morschl, P.

    1976-01-01

    This paper describes a process developed for the retainment and separation of volatile ( 3 H, 129+131 I) and gaseous ( 85 Kr, Xe) fission products from the off-gas produced during dissolution of HTGR-fuel. To prevent unnecessary dilution of liberated noble gases by surrounding atmosphere, a helium purge-gas cycle is applied to enable a coarse fractionating of krypton and xenon by cold-trapping at about 80 0 K after precleaning the gas stream. The process consists of the following steps: deposition of droplets and solid aerosols; chemisorption of iodine on silver impregnated silica gel; catalytic removal of nitrogen oxides and oxygen; drying of the process gas stream; final filtering of abraded solids; deposition of xenon in solid form at 80 0 K and low subpressure; deposition of krypton in solid form at 80 0 K after compression to about 6 bar; decontamination of 85 Kr-containing xenon by batch distillation for eventual industrial utilization; and removal of nitrogen and argon enrichment during continuous operation in the purge-gas stream by inleaking air with charcoal. A continuously operating dissolver vessel, closed to the surrounding atmosphere, yields a very high content of noble gases, i.e., 0.35 vol % krypton and 2.0 vol % xenon. The presented off-gas treatment unit is operated in cold runs with 1 / 3 of the full capacity and can treat about 1 m 3 STP/h helium, corresponding to a quantity of about 10,000 MW/sub e/ HTGR-fuel reprocessing plant

  6. Dosimetry for combustion flue gas treatment with electron beam

    Energy Technology Data Exchange (ETDEWEB)

    Mehta, K.; Bułka, S.; Sun, Y. [Institute of Nuclear Chemistry and Technology, Warsaw (Poland)

    2011-07-01

    The electron beam treatment of flue gas is one of the new technologies. There are several reasons for carrying out dosimetry at various phases of the project as understanding the process and optimizing the equipment, for process control and for troubleshooting in case of malfunction etc. The main challenge in measuring dose for flue gas applications is that the medium being irradiated is gaseous. Two general approaches for dose measurements are: adding/placing some dosimeters in the reaction vessel (gas) and using the components of the gas itself as a dosimeter. Various techniques and methods have been tried which are discussed in this paper. (author)

  7. Advanced ultrasonic technology for natural gas measurement

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-11-15

    In recent years, due to rising environmental and safety concerns, increasing commodity prices, and operational inefficiencies, a paradigm shift has been taking place with respect to gas measurement. The price of natural gas depends on the location, time of the year, and type of consumer. There is wide uncertainty associated with an orifice meter. This paper presents the use of advanced ultrasonic technology for the measurement of natural gas. For many years, multi-path ultrasonic meters with intelligent sensor technology have been used for gas measurement. This paper gives the various applications of ultrasonic technology along with their advantages and a draws a comparison with orifice meters. From the study it can be concluded that extensive advances in the use of ultrasonic technology for gas measurement have widened the areas of application and that varying frequencies combined with sealed transducer designs make it possible to measure atmospheric and sour gas in custody transfer process control and flaring accurately.

  8. Handwriting on the power plant wall: flue gas treatment

    Energy Technology Data Exchange (ETDEWEB)

    Troupe, J.S.

    1979-08-01

    This paper reviews the present state of flue gas treatment technology. Describes the operation of four basic types of devices used by electric utilities:- mechanical dust collectors, electrostatic precipitators, wet scrubbers and fabric filters. Considers their reliability and cost, and outlines possible future trends.

  9. Dynamic performance of a combined gas turbine and air bottoming cycle plant for off-shore applications

    DEFF Research Database (Denmark)

    Benato, Alberto; Pierobon, Leonardo; Haglind, Fredrik

    2014-01-01

    and a combined gas turbine coupled with an air bottoming cycle plant. The case study is the Draugen off-shore oil and gas platform, located in the North Sea, Norway. The normal electricity demand is 19 MW, currently covered by two gas turbines generating each 50% of the power demand, while the third turbine......When the Norwegian government introduced the CO2 tax for hydrocarbon fuels, the challenge became to improve the performance of off-shore power systems. An oil and gas platform typically operates on an island (stand-alone system) and the power demand is covered by two or more gas turbines. In order...... to improve the plant performance, a bottoming cycle unit can be added to the gas turbine topping module, thus constituting a combined cycle plant. This paper aims at developing and testing the numerical model simulating the part-load and dynamic behavior of a novel power system, composed of two gas turbines...

  10. Gas-to-liquid technologies: India's perspective

    International Nuclear Information System (INIS)

    Reddy Keshav, Tirupati; Basu, S.

    2007-01-01

    Gas-to-liquid (GTL) technologies are capable of converting gas to clean, useful liquid hydrocarbons and thus suitable for addressing problems of remote gas utilization, increase in crude oil price, depletion of fossil fuel and environmental pollution. The Indian state of Tripura is considered to be the richest province with 26 billion cubic meters of gas reserves. Neighboring country Myanmar has huge gas reserves but these reserves remain unutilized mainly because of land-locked situation. GTL is a well developed and proven technology and it is an important option for moving natural gas to the market place. GTL options include not only the well-known production of Fischer-Tropsch synthesis liquids but also the production of oxygen containing fuels, fuel additives and chemicals, such as methanol and DME. An alternative, promising option to convert surplus gas is the direct route of methane conversion, which is more energy efficient than the indirect route since it bypasses the energy intensive endothermic steam reforming step of syngas formation. On-site conversion to liquid products of commercial importance using direct route would make transportation of these natural deposits much more economical and practical. In this paper an attempt has been made to review recent developments in syngas technologies, direct routes of methane conversion into useful liquids, and status of both existing and future developments in GTL industry around the world. Finally challenges in GTL technology are discussed. (author)

  11. Assessing the impacts of changes in treatment technology on energy and greenhouse gas balances for organic waste and wastewater treatment using historical data.

    Science.gov (United States)

    Poulsen, Tjalfe G; Hansen, Jens Aage

    2009-11-01

    Historical data on organic waste and wastewater treatment during the period of 1970-2020 were used to assess the impact of treatment on energy and greenhouse gas (GHG) balances. The assessment included the waste fractions: Sewage sludge, food waste, yard waste and other organic waste (paper, plastic, etc.). Data were collected from Aalborg, a municipality located in Northern Denmark. During the period from 1970-2005, Aalborg Municipality has changed its waste treatment strategy from landfilling of all wastes toward composting of yard waste and incineration with combined heat and power production from the remaining organic municipal waste. Wastewater treatment has changed from direct discharge of untreated wastewater to full organic matter and nutrient (N, P) removal combined with anaerobic digestion of the sludge for biogas production with power and heat generation. These changes in treatment technology have resulted in the waste and wastewater treatment systems in Aalborg progressing from being net consumers of energy and net emitters of GHG, to becoming net producers of energy and net savers of GHG emissions (due to substitution of fossil fuels elsewhere). If it is assumed that the organic waste quantity and composition is the same in 1970 and 2005, the technology change over this time period has resulted in a progression from a net annual GHG emission of 200 kg CO( 2)-eq. capita(-1) in 1970 to a net saving of 170 kg CO(2)-eq. capita(-1) in 2005 for management of urban organic wastes.

  12. Specialists' meeting on gas-cooled reactor fuel development and spent fuel treatment

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-07-01

    Topics covered during the 'Specialists' meeting on gas-cooled reactor fuel development and spent fuel treatment' were as follows: Selection of constructions and materials, fuel element development concepts; Fabrication of spherical coated fuel particles and fuel element on their base; investigation of fuel properties; Spent fuel treatment and storage; Head-end processing of HTGR fuel elements; investigation of HTGR fuel regeneration process; applicability of gas-fluorine technology of regeneration of spent HTGR fuel elements.

  13. Specialists' meeting on gas-cooled reactor fuel development and spent fuel treatment

    International Nuclear Information System (INIS)

    1985-01-01

    Topics covered during the 'Specialists' meeting on gas-cooled reactor fuel development and spent fuel treatment' were as follows: Selection of constructions and materials, fuel element development concepts; Fabrication of spherical coated fuel particles and fuel element on their base; investigation of fuel properties; Spent fuel treatment and storage; Head-end processing of HTGR fuel elements; investigation of HTGR fuel regeneration process; applicability of gas-fluorine technology of regeneration of spent HTGR fuel elements

  14. Non-mine technology of hydrocarbon resources production at complex development of gas and coal deposits

    International Nuclear Information System (INIS)

    Saginov, A.S.; Adilov, K.N.; Akhmetbekov, Sh.U.

    1997-01-01

    Non-mine technology of coal gas seams exploitation is new geological technological method of complex exploitation of coal gas deposits. The method allows sequentially to extract hydrocarbon resources in technological aggregative-mobile condensed states. According to natural methane content in seams the technology includes: methane extraction from sorption volume where it is bounded up with coal; gas output intensification of coal is due to structural changes of substance at the cost of physico-chemical treatment of seam; increase of seam permeability by the methods of active physical and physico-chemical actions on coal seam (hydro-uncovering, pneumatic hydro action etc.). Pilot testing shows efficiency of well mastering with help of depth pumps. In this case works of action of pumping out of operating liquid and gas extraction from coal seam are integrated

  15. International Seminar on Gasification 2009 - Biomass Gasification, Gas Clean-up and Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    2009-10-15

    During the seminar international and national experts gave presentations concerning Biomass gasification, Gas cleaning and gas treatment; and Strategy and policy issues. The presentations give an overview of the current status and what to be expected in terms of development, industrial interest and commercialization of different biomass gasification routes. The following PPT presentations are reproduced in the report: Black Liquor Gasification (Chemrec AB.); Gasification and Alternative Feedstocks for the Production of Synfuels and 2nd Generation Biofuels (Lurgi GmbH); Commercial Scale BtL Production on the Verge of Becoming Reality (Choren Industries GmbH.); Up-draft Biomass Gasification (Babcock and Wilcox Voelund A/S); Heterogeneous Biomass Residues and the Catalytic Synthesis of Alcohols (Enerkem); Status of the GoBiGas-project (Goeteborg Energi AB.); On-going Gasification Activities in Spain (University of Zaragoza,); Biomass Gasification Research in Italy (University of Perugia.); RDandD Needs and Recommendations for the Commercialization of High-efficient Bio-SNG (Energy Research Centre of the Netherlands.); Cleaning and Usage of Product Gas from Biomass Steam Gasification (Vienna University of Technology); Biomass Gasification and Catalytic Tar Cracking Process Development (Research Triangle Institute); Syngas Cleaning with Catalytic Tar Reforming (Franhofer UMSICHT); Biomass Gas Cleaning and Utilization - The Topsoee Perspective (Haldor Topsoee A/S); OLGA Tar Removal Technology (Dahlman); Bio-SNG - Strategy and Activities within E.ON (E.ON Ruhrgas AG); Strategy and Gasification Activities within Sweden (Swedish Energy Agency); 20 TWh/year Biomethane (Swedish Gas Association)

  16. Navigating environmental, economic, and technological trade-offs in the design and operation of submerged anaerobic membrane bioreactors (AnMBRs)

    KAUST Repository

    Pretel, R.

    2015-12-01

    © 2015 Elsevier Ltd. Anaerobic membrane bioreactors (AnMBRs) enable energy recovery from wastewater while simultaneously achieving high levels of treatment. The objective of this study was to elucidate how detailed design and operational decisions of submerged AnMBRs influence the technological, environmental, and economic sustainability of the system across its life cycle. Specific design and operational decisions evaluated included: solids retention time (SRT), mixed liquor suspended solids (MLSS) concentration, sludge recycling ratio (r), flux (J), and specific gas demand per membrane area (SGD). The possibility of methane recovery (both as biogas and as soluble methane in reactor effluent) and bioenergy production, nutrient recovery, and final destination of the sludge (land application, landfill, or incineration) were also evaluated. The implications of these design and operational decisions were characterized by leveraging a quantitative sustainable design (QSD) framework which integrated steady-state performance modeling across seasonal temperatures (using pilot-scale experimental data and the simulating software DESASS), life cycle cost (LCC) analysis, and life cycle assessment (LCA). Sensitivity and uncertainty analyses were used to characterize the relative importance of individual design decisions, and to navigate trade-offs across environmental, economic, and technological criteria. Based on this analysis, there are design and operational conditions under which submerged AnMBRs could be net energy positive and contribute to the pursuit of carbon negative wastewater treatment.

  17. Shallow gas charged sediments off the Indian west coast: Genesis and distribution

    Digital Repository Service at National Institute of Oceanography (India)

    Mazumdar, A.; Peketi, A.; Dewangan, P.; Badesab, F.K.; Ramprasad, T; Ramana, M.V.; Patil, D.J.; Dayal, A.M.

    Geophysical and geochemical surveys were carried out off Goa, central west coast of India, to understand the genesis and distribution of shallow gases in marine sediments. Shallow gas charged sediments within the water depths of approx. 15 to 40 m...

  18. Coupled Thermo-Hydro-Mechanical-Chemical Modeling of Water Leak-Off Process during Hydraulic Fracturing in Shale Gas Reservoirs

    Directory of Open Access Journals (Sweden)

    Fei Wang

    2017-11-01

    Full Text Available The water leak-off during hydraulic fracturing in shale gas reservoirs is a complicated transport behavior involving thermal (T, hydrodynamic (H, mechanical (M and chemical (C processes. Although many leak-off models have been published, none of the models fully coupled the transient fluid flow modeling with heat transfer, chemical-potential equilibrium and natural-fracture dilation phenomena. In this paper, a coupled thermo-hydro-mechanical-chemical (THMC model based on non-equilibrium thermodynamics, hydrodynamics, thermo-poroelastic rock mechanics, and non-isothermal chemical-potential equations is presented to simulate the water leak-off process in shale gas reservoirs. The THMC model takes into account a triple-porosity medium, which includes hydraulic fractures, natural fractures and shale matrix. The leak-off simulation with the THMC model involves all the important processes in this triple-porosity medium, including: (1 water transport driven by hydraulic, capillary, chemical and thermal osmotic convections; (2 gas transport induced by both hydraulic pressure driven convection and adsorption; (3 heat transport driven by thermal convection and conduction; and (4 natural-fracture dilation considered as a thermo-poroelastic rock deformation. The fluid and heat transport, coupled with rock deformation, are described by a set of partial differential equations resulting from the conservation of mass, momentum, and energy. The semi-implicit finite-difference algorithm is proposed to solve these equations. The evolution of pressure, temperature, saturation and salinity profiles of hydraulic fractures, natural fractures and matrix is calculated, revealing the multi-field coupled water leak-off process in shale gas reservoirs. The influences of hydraulic pressure, natural-fracture dilation, chemical osmosis and thermal osmosis on water leak-off are investigated. Results from this study are expected to provide a better understanding of the

  19. A laser-based sensor for measurement of off-gas composition and temperature in basic oxygen steelmaking

    International Nuclear Information System (INIS)

    Ottesen, D.; Allendorf, S.; Ludowise, P.; Hardesty, D.; Miller, T.; Goldstein, D.; Smith, C.; Bonin, M.

    1999-01-01

    We are developing an optical sensor for process control in basic oxygen steelmaking. The sensor measures gas temperature and relative CO/CO 2 concentration ratios in the furnace off-gas by transmitting the laser probe beam directly above the furnace lip and below the exhaust hood during oxygen blowing. Dynamic off-gas information is being evaluated for optimizing variables such as lance height, oxygen flow, post-combustion control, and prediction of final melt-carbon content. The non-invasive nature of the optical sensor renders it robust and relatively maintenance-free. Additional potential applications of the method are process control for electric arc furnace and bottom-blown oxygen steelmaking processes. (author)

  20. Mining run-off gets a treatment

    International Nuclear Information System (INIS)

    Pichon, Max

    2013-01-01

    Full text: Engineering company GHD has implemented an innovative multi- barrier storm water treatment system for a major milling company at the Port of Townsville. The technology economically filters stormwater and is effective for a broad range of contaminants including oil, grease, soluble nutrients and heavy metals. GHD's industrial water and coal seam gas business development leader, Kostas Athanasiadis, created StormDMT, a configuration of inexpensive filter media in a cartridge that cost-effectively removes heavy metals and other dissolved contaminants. He said there was growing recognition of the need to protect receiving waterways and to address water scarcity through measures such as stormwater harvesting. “However, there are few stormwater treatment technologies currently available to effectively and economically remove these contaminants both in particulate and soluble forms, to desirable levels,” he said. GHD carried out a trial at the site in collaboration with the client's engineering, environmental and operational teams. The filter exceeded anticipated performance and the client has adopted a site-wide solution based on the technology. The StormDMT stormwater filter system design incorporates a filtering system (cartridge or other types of filtering configurations) that contains a combination of filter media, including polypropylene flakes to remove oil and grease and particulate-bound contaminants. It also features a zeolite named clinoptilolite to remove positive charged dissolved contaminants such as heavy metals and ammonium nitrogen. Clinoptilolite has been chemically conditioned to maximise its operational ion exchange capacity. Finally, laterite removes negative charged contaminants such as phosphate, nitrate and arsenic as well as heavy metals that have broken through the clinotpilolite layer. One of the key advantages of the StormDMT technology is the low discharge levels it is capable of achieving or dissolved nutrients and

  1. Pilot plant development for adsorptive krypton separation from dissolver off-gas

    International Nuclear Information System (INIS)

    Ringel, H.; Printz, R.

    1987-01-01

    In view of hot cell application a separation process was investigated for the retention of Kr-85 from gaseous effluents. In the flow sheet only adsorption beds are applied. The most efficient process scheme is adsorption of the noble gas on activated charcoal and thereafter separation of the coadsorbed gas species like N 2 , O 2 , Xe and CO 2 from the krypton by gas chromatography. Adsorption is at normal pressure and low temperatures of up to -160 0 C, whereas desorption is at elevated temperatures and under helium purge. Influences on the process operation like off-gas composition, adsorption temperatures and adsorbent are experimentally investigated, as well as the behavior of trace impurities in the adsorption columns. On the basis of pilot plant operation the main components for a full scale facility are being designed

  2. Gas technology, environment and added value

    International Nuclear Information System (INIS)

    2002-01-01

    This report is an official evaluation of the various aspects of new, environmentally friendly ways of using gas in Norway, including hydrogen and gas power with carbon dioxide deposition. The objective of the evaluation is to prepare for increased engagement by Norwegian technological and research institutions in the development of environmentally friendly gas technology, in cooperation with other countries, and to give Norway a strong international position in this field. This objective is based on the political goal that a greater part of Norway's natural gas resources should be used at home (rather than being exported), and in agreement with Norway's international environmental commitments

  3. Shale Gas Technology. White Paper

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    Shale gas is extracted using horizontal drilling and hydraulic fracturing or 'fracking'. None of which are particularly new technologies or shale gas specific. In this white paper attention is paid to Horizontal drilling; Hydraulic fracturing or 'frackin'; Other 'unconventionals'; and Costs.

  4. Treatment of reactive process wastewater with high-level ammonia by blow-off method

    International Nuclear Information System (INIS)

    Chen Xiaotong; Quan Ying; Wang Yang; Fu Genna; Liu Bing; Tang Yaping

    2012-01-01

    The ceramic UO 2 kernels for nuclear fuel elements of high temperature gas cooled reactors were prepared through sol-gel process with uranyl nitrate, which produces process wastewater containing high-level ammonia and uranium. The blow-off method on a bench scale was investigated to remove ammonia from reactive wastewater. Under the optimized operating conditions, the ammonia can be removed by more than 95%, with little reactive uranium distilled. The effects of pH, heating temperature and stripping time were studied. Static tests with ion-exchange resin indicate that ammonia removal treatment increases uranium accumulation in anion exchange resin. (authors)

  5. Meet the biologists: Sour gas treatment uses biology rather than chemistry to clean things up

    Energy Technology Data Exchange (ETDEWEB)

    Budd, G.

    2003-03-01

    Basic elements of the new bio-desulfurization technology are described. The new process uses the commonly occurring bacterium, Thiobacillus, rather than chemical means to remove hydrogen sulfide from natural gas. Development of the process began some ten years ago in the Netherlands as a means to clean sewage water and purify water for beer. The application of removing hydrogen sulfide from natural gas evolved upon discovery that the process was able to convert hydrogen sulfide to sulfur. Key to the bio-desulfurization process is the Thiobacillus bacterium, which unlike other plant forms, relies on chemosynthesis (instead of photosynthesis) of hydrogen sulfide, oxygen and carbon dioxide for its energy requirements. The technology has applications in refineries as well as in gas processing plants. It is well suited for use in Canada where operations tend to be on the small scale (less than 50 tonnes per day). The portable unit can be moved to another location when production at a given well drops off.

  6. Advanced Hydraulic Fracturing Technology for Unconventional Tight Gas Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Holditch; A. Daniel Hill; D. Zhu

    2007-06-19

    The objectives of this project are to develop and test new techniques for creating extensive, conductive hydraulic fractures in unconventional tight gas reservoirs by statistically assessing the productivity achieved in hundreds of field treatments with a variety of current fracturing practices ranging from 'water fracs' to conventional gel fracture treatments; by laboratory measurements of the conductivity created with high rate proppant fracturing using an entirely new conductivity test - the 'dynamic fracture conductivity test'; and by developing design models to implement the optimal fracture treatments determined from the field assessment and the laboratory measurements. One of the tasks of this project is to create an 'advisor' or expert system for completion, production and stimulation of tight gas reservoirs. A central part of this study is an extensive survey of the productivity of hundreds of tight gas wells that have been hydraulically fractured. We have been doing an extensive literature search of the SPE eLibrary, DOE, Gas Technology Institute (GTI), Bureau of Economic Geology and IHS Energy, for publicly available technical reports about procedures of drilling, completion and production of the tight gas wells. We have downloaded numerous papers and read and summarized the information to build a database that will contain field treatment data, organized by geographic location, and hydraulic fracture treatment design data, organized by the treatment type. We have conducted experimental study on 'dynamic fracture conductivity' created when proppant slurries are pumped into hydraulic fractures in tight gas sands. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially; we pump proppant/frac fluid slurries into a fracture cell, dynamically placing the proppant just as it occurs in the field. From such tests, we expect to gain new insights into some of the critical

  7. Dry Refabrication Technology Development of Spent Nuclear Fuel

    International Nuclear Information System (INIS)

    Lee, Jung Won; Park, G. I.; Park, C. J.

    2010-04-01

    Key technical data on advanced nuclear fuel cycle technology development for the spent fuel recycling have been produced in this study. In the frame work of DUPIC, dry process oxide products fabrication, hot cell experimental data for decladding, powdering and oxide product fabrication from low and high burnup spent fuel have been produced, basic technology for fabrication of spent fuel standard material has been developed, and remote modulated welding equipment has been designed and fabricated. In the area of advanced pre-treatment process development, a rotary-type oxidizer and spherical particle fabrication process were developed by using SIMFUEL and off-gas treatment technology and zircalloy tube treatment technology were studied. In the area of the property characteristics of dry process products, fabrication technology of simulated dry process products was established and property models were developed based on reproducible property measurement data

  8. Spin-transfer torque magnetoresistive random-access memory technologies for normally off computing (invited)

    International Nuclear Information System (INIS)

    Ando, K.; Yuasa, S.; Fujita, S.; Ito, J.; Yoda, H.; Suzuki, Y.; Nakatani, Y.; Miyazaki, T.

    2014-01-01

    Most parts of present computer systems are made of volatile devices, and the power to supply them to avoid information loss causes huge energy losses. We can eliminate this meaningless energy loss by utilizing the non-volatile function of advanced spin-transfer torque magnetoresistive random-access memory (STT-MRAM) technology and create a new type of computer, i.e., normally off computers. Critical tasks to achieve normally off computers are implementations of STT-MRAM technologies in the main memory and low-level cache memories. STT-MRAM technology for applications to the main memory has been successfully developed by using perpendicular STT-MRAMs, and faster STT-MRAM technologies for applications to the cache memory are now being developed. The present status of STT-MRAMs and challenges that remain for normally off computers are discussed

  9. Shale Gas Technology. White Paper

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    Shale gas is extracted using horizontal drilling and hydraulic fracturing or 'fracking'. None of which are particularly new technologies or shale gas specific. In this white paper attention is paid to Horizontal drilling; Hydraulic fracturing or 'frackin'; Other 'unconventionals'; and Costs.

  10. Evolving markets and new end use gas technologies

    International Nuclear Information System (INIS)

    Overall, J.

    1995-01-01

    End use gas technologies, and products for residential, commercial, and industrial uses were reviewed, and markets and market drivers needed for end use technologies in the different types of markets were summarized. The range of end use technologies included: gas fireplaces, combination heating/water heating systems, integrated appliance such as heating/ventilation units, gas cooling, and space cooling for commercial markets. The present and future status of each product market was discussed. Growing markets such as cogeneration, and gas turbine technology also received attention, along with regulatory and environmental concerns. The need to be knowledgeable about current market drivers and to introduce new ones, and the evolution of technology were emphasized as means by which the industry will continue to be able to exert a decisive influence on the direction of these markets

  11. A Novel Boil-Off Gas Re-Liquefaction Using a Spray Recondenser for Liquefied Natural-Gas Bunkering Operations

    Directory of Open Access Journals (Sweden)

    Jiheon Ryu

    2016-11-01

    Full Text Available This study presents the design of a novel boil-off gas (BOG re-liquefaction technology using a BOG recondenser system. The BOG recondenser system targets the liquefied natural gas (LNG bunkering operation, in which the BOG phase transition occurs in a pressure vessel instead of a heat exchanger. The BOG that is generated during LNG bunkering operation is characterized as an intermittent flow with various peak loads. The system was designed to temporarily store the transient BOG inflow, condense it with subcooled LNG and store the condensed liquid. The superiority of the system was verified by comparing it with the most extensively employed conventional re-liquefaction system in terms of consumption energy and via an exergy analysis. Static simulations were conducted for three compositions; the results indicated that the proposed system provided 0 to 6.9% higher efficiencies. The exergy analysis indicates that the useful work of the conventional system is 24.9%, and the useful work of the proposed system is 26.0%. Process dynamic simulations of six cases were also performed to verify the behaviour of the BOG recondenser system. The results show that the pressure of the holdup in the recondenser vessel increased during the BOG inflow mode and decreased during the initialization mode. The maximum pressure of one of the bunkering cases was 3.45 bar. The system encountered a challenge during repetitive operations due to overpressurizing of the BOG recondenser vessel.

  12. Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment

    Energy Technology Data Exchange (ETDEWEB)

    R. T. Jubin; D. M. Strachan; N. R. Soelberg

    2013-09-01

    Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

  13. The development of mobile melt-dilute technology for the treatment of former Soviet Union research reactor fuel

    International Nuclear Information System (INIS)

    Sell, D.A.; Howden, E.A.; Allen, K.J.; Marsden, K.; Westphal, B.R.; Peacock, H.B.; Iyer, N.C.; Fisher, D.L.; Adams, T.M.; Sindelar, R.L.

    2004-01-01

    United States Government funded national security nuclear non-proliferation projects have historically focused on power reactor spent fuel assemblies that contain weapons usable materials. More recently concern and emphasis have been focused on the spent fuel located at the many research reactor facilities spread throughout the Former Soviet Union. The need exists for a mobile system that can be deployed at these research reactors for the purpose of ensuring that the nuclear materials cannot be used for weapons development. On-site application of the Mobile Melt-Dilute (MMD) process offers an economical method for converting weapons usable Former Soviet Union high enriched uranium research reactor fuel to a safe and secure low enriched uranium ingot. The process will generate little waste and will be performed in a sealed canister that will contain all off-gas products generated during the melting process, eliminating the need for an off-gas treatment system. The process is modular, reusable, and readily portable to a desired reactor site or storage location. The storage canisters containing the melted ingot can be configured for compatibility with the fuel storage technologies currently available or returned to Russia for reprocessing under the Russian Research Reactor Fuel Return Program. The objective of the MMD Project is to develop the mobile melt and dilute technology in preparation for active deployment at Russian built and fueled research reactors. The project has just completed conceptual design and is beginning proof of principle experiments and integrated prototype design of the furnace and canister. (authors)

  14. Data quality objectives summary report for the 105-N monolith off-gas issue

    International Nuclear Information System (INIS)

    Pisarcik, D.J.

    1997-01-01

    The 105-N Basin hardware waste with radiation exposure rates high enough to make above-water handling and packaging impractical has been designated high exposure rate hardware (HERH) waste. This material, consisting primarily of irradiated reactor components, is packaged underwater for subsequent disposal as a grout-encapsulated solid monolith. The third HERH waste package that was created (Monolith No. 3) was not immediately removed from the basin because of administrative delays. During a routine facility walkdown, Monolith No. 3 was observed to be emitting bubbles. Mass spectroscopic analysis of a gas sample from Monolith No. 3 indicated that the gas was 85.2% hydrogen along with a trace of fission gases (stable isotopes of xenon). Gamma energy analysis of a gas sample from Monolith No. 3 also identified trace quantities of 85 Kr. The monolith off-gas Data Quality Objective (DQO) process concluded the following: Monolith No. 3 and similar monoliths can be safely transported following installation of spacers between the lids of the L3-181 transport cask to vent the hydrogen gas; The 85 Kr does not challenge personnel or environmental safety; Fumaroles in the surface of gassing monoliths renders them incompatible with Hanford Site Solid Waste Acceptance Criteria requirements unless placed in a qualified high integrity container overpack; and Gassing monoliths do meet Environmental Restoration Disposal Facility Waste Acceptance Criteria requirements. This DQO Summary Report is both an account of the Monolith Off-Gas DQO Process and a means of documenting the concurrence of each of the stakeholder organizations

  15. An overview on exploration and environmental impact of unconventional gas sources and treatment options for produced water.

    Science.gov (United States)

    Silva, Tânia L S; Morales-Torres, Sergio; Castro-Silva, Sérgio; Figueiredo, José L; Silva, Adrián M T

    2017-09-15

    Rising global energy demands associated to unbalanced allocation of water resources highlight the importance of water management solutions for the gas industry. Advanced drilling, completion and stimulation techniques for gas extraction, allow more economical access to unconventional gas reserves. This stimulated a shale gas revolution, besides tight gas and coalbed methane, also causing escalating water handling challenges in order to avoid a major impact on the environment. Hydraulic fracturing allied to horizontal drilling is gaining higher relevance in the exploration of unconventional gas reserves, but a large amount of wastewater (known as "produced water") is generated. Its variable chemical composition and flow rates, together with more severe regulations and public concern, have promoted the development of solutions for the treatment and reuse of such produced water. This work intends to provide an overview on the exploration and subsequent environmental implications of unconventional gas sources, as well as the technologies for treatment of produced water, describing the main results and drawbacks, together with some cost estimates. In particular, the growing volumes of produced water from shale gas plays are creating an interesting market opportunity for water technology and service providers. Membrane-based technologies (membrane distillation, forward osmosis, membrane bioreactors and pervaporation) and advanced oxidation processes (ozonation, Fenton, photocatalysis) are claimed to be adequate treatment solutions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Design and operational experience with the off-gas cleaning system of the Seibersdorf incinerator plant

    International Nuclear Information System (INIS)

    Patek, P.

    1982-05-01

    After a description of the design and the construction principles of the incinerator building, the furnace and its attached auxilary devices are explained. The incinerator is layed out for low level wastes. It has a vertical furnace, operates with discontinuous feeding for trashes with heat-values between 600 and 10000 kcal/kg waste. The maximum throughput ammounts 40 kg/h. The purification of the off-gas is guaranteed by a multistage filter system: 2 stages with ceramic candles, an electrostatic filter and a HEPA-filter system. The control of the off-gas cleaning is carried out by a stack instrumentation, consisting of an aerosol-, gas-, iodine- and tritium-monitor; the building is surveilled by doserate- and aerosolmonitors. Finally the experiences of the first year of operation and the main problems in running the plant are described. (Author) [de

  17. Design and operational experience with the off-gas cleaning system of the Seibersdorf incinerator plant

    International Nuclear Information System (INIS)

    Patek, P.R.M.

    1983-01-01

    After a description of the design and the construction principles of the incinerator building, the furnace and its attached auxiliary devices are explained. The incinerator is layed out for low level wastes. It has a vertical furnace, operates with discontinuous feeding for trashes with heat-values between 600 and 10,000 kcal/kg waste. The maximum throughput amounts to 40 kg/h. The purification of the off-gas is guaranteed by a multistage filter system: 2 stages with ceramic candles, an electrostatic filter and a HEPA-filter system. The control of the off-gas cleaning is carried out by a stack instrumentation, consisting of an aerosol-, gas-, iodine- and tritium-monitor; the building is surveyed by doserate and aerosolmonitors. Finally the experiences of the first year of operation and the main problems in running the plant are described. (author)

  18. Online gas composition estimation in solid oxide fuel cell systems with anode off-gas recycle configuration

    Science.gov (United States)

    Dolenc, B.; Vrečko, D.; Juričić, Ð.; Pohjoranta, A.; Pianese, C.

    2017-03-01

    Degradation and poisoning of solid oxide fuel cell (SOFC) stacks are continuously shortening the lifespan of SOFC systems. Poisoning mechanisms, such as carbon deposition, form a coating layer, hence rapidly decreasing the efficiency of the fuel cells. Gas composition of inlet gases is known to have great impact on the rate of coke formation. Therefore, monitoring of these variables can be of great benefit for overall management of SOFCs. Although measuring the gas composition of the gas stream is feasible, it is too costly for commercial applications. This paper proposes three distinct approaches for the design of gas composition estimators of an SOFC system in anode off-gas recycle configuration which are (i.) accurate, and (ii.) easy to implement on a programmable logic controller. Firstly, a classical approach is briefly revisited and problems related to implementation complexity are discussed. Secondly, the model is simplified and adapted for easy implementation. Further, an alternative data-driven approach for gas composition estimation is developed. Finally, a hybrid estimator employing experimental data and 1st-principles is proposed. Despite the structural simplicity of the estimators, the experimental validation shows a high precision for all of the approaches. Experimental validation is performed on a 10 kW SOFC system.

  19. In situ vitrification: An innovative thermal treatment technology

    International Nuclear Information System (INIS)

    Fitzpatrick, V.F.; Timmerman, C.L.; Buelt, J.L.

    1987-03-01

    In situ vitrification is a thermal treatment process that converts contaminated soil into a chemically inert, stable glass and crystalline product. A square array of four electrodes are inserted into the ground to the desired treatment depth. Because the soil is not electrically conductive once the moisture has been driven off, a conductive mixture of flaked graphite and glass frit is placed among the electrodes to act as the starter path. An electrical potential is applied to the electrodes, which establishes an electrical current in the starter path. The resultant power heats the starter path and surrounding soil up to 3600 0 F, well above the initial melting temperature or fusion temperature of soils. The normal fusion temperature of soil ranges between 2000 and 2500 0 F. The graphite starter path is eventually consumed by oxidation, and the current is transferred to the molten soil, which is now electrically conductive. As the vitrified zone grows, it incorporates nonvolatile elements and destroys organic components by pyrolysis. The pyrolyzed byproducts migrate to the surface of the vitrified zone, where they combust in the presence of oxygen. A hood placed over the processing area provides confinement for the combustion gases, and the gases are drawn into the off-gas treatment system

  20. An Exploration of Mercury Soils Treatment Technologies for the Y-12 Plant - 13217

    International Nuclear Information System (INIS)

    Wrapp, John; Julius, Jonathon; Browning, Debbie; Kane, Michael; Whaley, Katherine; Estes, Chuck; Witzeman, John

    2013-01-01

    There are a number of areas at the Y-12 National Security Complex (Y-12) that have been contaminated with mercury due to historical mercury use and storage. Remediation of these areas is expected to generate large volumes of waste that are Resource Conservation and Recovery Act (RCRA) characteristically hazardous. These soils will require treatment to meet RCRA Land Disposal Restrictions (LDR) prior to disposal. URS - CH2M Oak Ridge LLC (UCOR) performed a feasibility assessment to evaluate on-site and off-site options for the treatment and disposal of mercury-contaminated soil from the Y-12 Site. The focus of the feasibility assessment was on treatment for disposal at the Environmental Management Waste Management Facility (EMWMF) located on the Oak Ridge Reservation. A two-phase approach was used in the evaluation process of treatment technologies. Phase 1 involved the selection of three vendors to perform treatability studies using their stabilization treatment technology on actual Y-12 soil. Phase II involved a team of waste management specialists performing an in-depth literature review of all available treatment technologies for treating mercury contaminated soil using the following evaluation criteria: effectiveness, feasibility of implementation, and cost. The result of the treatability study and the literature review revealed several viable on-site and off-site treatment options. This paper presents the methodology used by the team in the evaluation of technologies especially as related to EMWMF waste acceptance criteria, the results of the physical treatability studies, and a regulatory analysis for obtaining regulator approval for the treatment/disposal at the EMWMF. (authors)

  1. An Exploration of Mercury Soils Treatment Technologies for the Y-12 Plant - 13217

    Energy Technology Data Exchange (ETDEWEB)

    Wrapp, John [UCOR, P.O. Box 4699, Oak Ridge, TN 37831 (United States); Julius, Jonathon [DOE Oak Ridge (United States); Browning, Debbie [Strata-G, LLC, 2027 Castaic Lane, Knoxville, TN, 37932 (United States); Kane, Michael [RSI, P.O. Box 4699, Oak Ridge, TN 37831 (United States); Whaley, Katherine [RSI, P.O. Box 4699, Oak Ridge, TN 37831 (United States); Estes, Chuck [EnergySolutions, P.O. Box 4699, Oak Ridge, TN 37831 (United States); Witzeman, John [RSI, P.O. Box 4699, Oak Ridge, TN, 37831 (United States)

    2013-07-01

    There are a number of areas at the Y-12 National Security Complex (Y-12) that have been contaminated with mercury due to historical mercury use and storage. Remediation of these areas is expected to generate large volumes of waste that are Resource Conservation and Recovery Act (RCRA) characteristically hazardous. These soils will require treatment to meet RCRA Land Disposal Restrictions (LDR) prior to disposal. URS - CH2M Oak Ridge LLC (UCOR) performed a feasibility assessment to evaluate on-site and off-site options for the treatment and disposal of mercury-contaminated soil from the Y-12 Site. The focus of the feasibility assessment was on treatment for disposal at the Environmental Management Waste Management Facility (EMWMF) located on the Oak Ridge Reservation. A two-phase approach was used in the evaluation process of treatment technologies. Phase 1 involved the selection of three vendors to perform treatability studies using their stabilization treatment technology on actual Y-12 soil. Phase II involved a team of waste management specialists performing an in-depth literature review of all available treatment technologies for treating mercury contaminated soil using the following evaluation criteria: effectiveness, feasibility of implementation, and cost. The result of the treatability study and the literature review revealed several viable on-site and off-site treatment options. This paper presents the methodology used by the team in the evaluation of technologies especially as related to EMWMF waste acceptance criteria, the results of the physical treatability studies, and a regulatory analysis for obtaining regulator approval for the treatment/disposal at the EMWMF. (authors)

  2. Plasma technology for waste treatment

    International Nuclear Information System (INIS)

    Cohn, D.R.

    1995-01-01

    Improved environmental cleanup technology is needed to meet demanding goals for remediation and treatment of future waste streams. Plasma technology has unique features which could provide advantages of reduced secondary waste, lower cost, and onsite treatment for a wide variety of applications. Plasma technology can provide highly controllable processing without the need for combustion heating. It can be used to provide high temperature processing (∼10,000 degrees C). Plasma technology can also be employed for low temperature processing (down to room temperature range) through selective plasma chemistry. A graphite electrode arc plasma furnace at MIT has been used to investigate high temperature processing of simulated solid waste for Department of Energy environmental cleanup applications. Stable, non-leachable glass has been produced. To ensure reliable operation and to meet environmental objectives, new process diagnostics have been developed to measure furnace temperature and to determine metals emissions in the gaseous effluent. Selective plasma destruction of dilute concentrations of hazardous compounds in gaseous waste streams has been investigated using electron beam generated plasmas. Selective destruction makes it possible to treat the gas steam at relatively low temperatures in the 30-300 degrees C range. On-line infrared measurements have been used in feedback operation to maximize efficiency and ensure desired performance. Plasma technology and associated process diagnostics will be used in future studies of a wide range of waste streams

  3. Investigation of variable compositions on the removal of technetium from Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, Kathryn M. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Pareizs, John M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-03-29

    The Low Activity Waste (LAW) vitrification facility at the Hanford Waste Treatment and Immobilization Plant (WTP) will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the offgas system. The plan for disposition of this stream during baseline operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. The primary reason to recycle this stream is so that the semi-volatile 99Tc isotope eventually becomes incorporated into the glass. This stream also contains non-radioactive salt components that are problematic in the melter, so diversion of this stream to another process would eliminate recycling of these salts and would enable simplified operation of the LAW melter and the Pretreatment Facilities. This diversion from recycling this stream within WTP would have the effect of decreasing the LAW vitrification mission duration and quantity of glass waste. The concept being tested here involves removing the 99Tc so that the decontaminated aqueous stream, with the problematic salts, can be disposed elsewhere.

  4. Gas Turbines: ''low NOx'' technologies at EGT

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    For more than 15 years, European Gas Turbines (EGT - GEC Alsthom Group) has gained an important know-how culture and can use its rich feedback experience in the domain of gas turbine emissions. The EGT gas turbine units equipped with denitrogenation technologies cover the 4 to 226 MW power range and cumulate more than 1.7 hours of functioning in the different existing installations in the world. This paper describes the economical and environmental interests of gas turbines for power production and the combustion technologies developed by EGT to reduce the NOx emissions. The selective catalytic reduction technique is the only available secondary technique with can allow NOx and CO emissions lower than 10 ppm. Other technologies involving diluent injection (water, water-fuel mixture, vapor..) are also described and were developed in several countries to reduce the emission of these pollutants. (J.S.)

  5. Natural gas technology

    International Nuclear Information System (INIS)

    Todaro, J.M.; Herbert, J.H.

    1997-01-01

    This presentation is devoted to a discussion regarding current and planned US fossil energy research and development for fiscal years 1996, 1997 and 1998. The principal focus of research in the immediate future will be: clean coal fuels, natural gas and oil exploration and production, especially reservoir life extension, advanced drilling completion and stimulation systems, advanced diagnostics and imaging systems, environmental compliance in technology development, regulatory streamlining and risk assessment. Program goals to 2010 were summarized as: increasing domestic oil and gas recovery; increasing recoverable reserves; decreasing cumulative industry environmental compliance costs; increasing revenues to the federal government; saving jobs in the U.S

  6. Advanced oxidation technology for H2S odor gas using non-thermal plasma

    Science.gov (United States)

    Tao, ZHU; Ruonan, WANG; Wenjing, BIAN; Yang, CHEN; Weidong, JING

    2018-05-01

    Non-thermal plasma technology is a new type of odor treatment processing. We deal with H2S from waste gas emission using non-thermal plasma generated by dielectric barrier discharge. On the basis of two criteria, removal efficiency and absolute removal amount, we deeply investigate the changes in electrical parameters and process parameters, and the reaction process of the influence of ozone on H2S gas removal. The experimental results show that H2S removal efficiency is proportional to the voltage, frequency, power, residence time and energy efficiency, while it is inversely proportional to the initial concentration of H2S gas, and ozone concentration. This study lays the foundations of non-thermal plasma technology for further commercial application.

  7. Advances in HTGR spent fuel treatment technology

    International Nuclear Information System (INIS)

    Holder, N.D.; Lessig, W.S.

    1984-08-01

    GA Technologies, Inc. has been investigating the burning of spent reactor graphite under Department of Energy sponsorship since 1969. Several deep fluidized bed burners have been used at the GA pilot plant to develop graphite burning techniques for both spent fuel recovery and volume reduction for waste disposal. Since 1982 this technology has been extended to include more efficient circulating bed burners. This paper includes updates on high-temperature gas-cooled reactor fuel cycle options and current results of spent fuel treatment testing for fluidized and advanced circulating bed burners

  8. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    Energy Technology Data Exchange (ETDEWEB)

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

    2014-01-07

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion

  9. Dynamic performance of power generation systems for off-shore oil and gas platforms

    DEFF Research Database (Denmark)

    Pierobon, Leonardo; Breuhaus, Peter; Haglind, Fredrik

    2014-01-01

    %) arises on the prediction of the rotational speed of the high pressure shaft, while the largest deviation (average relative error ~20%) occurs in the evaluation of the pressure at the outlet of the low pressure turbine. As waste heat recovery units (e.g. organic Rankine cycles) are likely...... to be implemented in future off-shore platforms, the proposed model may serve in the design phase for a preliminary assessment of the dynamic response of the power generation system and to evaluate if requirements such as minimum and maximum frequency during transient operation and the recovery time are satisfied......On off-shore oil and gas platforms two or more gas turbines typically support the electrical demand on site by operating as a stand-alone (island) power system. As reliability and availability are major concerns during operation, the dynamic performance of the power generation system becomes...

  10. Design and Implementation of Energized Fracture Treatment in Tight Gas Sands

    Energy Technology Data Exchange (ETDEWEB)

    Mukul Sharma; Kyle Friehauf

    2009-12-31

    , the minimum CO{sub 2} gas quality (volume % of gas) recommended is 30% for moderate differences between fracture and reservoir pressures (2900 psi reservoir, 5300 psi fracture). The minimum quality is reduced to 20% when the difference between pressures is larger, resulting in additional gas expansion in the invaded zone. Inlet fluid temperature, flow rate, and base viscosity did not have a large impact on fracture production. Finally, every stage of the fracturing treatment should be energized with a gas component to ensure high gas saturation in the invaded zone. A second, more general, sensitivity study was conducted. Simulations show that CO{sub 2} outperforms N{sub 2} as a fluid component because it has higher solubility in water at fracturing temperatures and pressures. In fact, all gas components with higher solubility in water will increase the fluid's ability to reduce damage in the invaded zone. Adding methanol to the fracturing solution can increase the solubility of CO{sub 2}. N{sub 2} should only be used if the gas leaks-off either during the creation of the fracture or during closure, resulting in gas going into the invaded zone. Experimental data is needed to determine if the gas phase leaks-off during the creation of the fracture. Simulations show that the bubbles in a fluid traveling across the face of a porous medium are not likely to attach to the surface of the rock, the filter cake, or penetrate far into the porous medium. In summary, this research has created the first compositional fracturing simulator, a useful tool to aid in energized fracture design. We have made several important and original conclusions about the best practices when using energized fluids in tight gas sands. The models and tools presented here may be used in the future to predict behavior of any multi-phase or multi-component fracturing fluid system.

  11. Low Carbon Technology Options for the Natural Gas ...

    Science.gov (United States)

    The ultimate goal of this task is to perform environmental and economic analysis of natural gas based power production technologies (different routes) to investigate and evaluate strategies for reducing emissions from the power sector. It is a broad research area. Initially, the research will be focused on the preliminary analyses of hydrogen fuel based power production technologies utilizing hydrogen fuel in a large size, heavy-duty gas turbines in integrated reformer combined cycle (IRCC) and integrated gasification combined cycle (IGCC) for electric power generation. The research will be expanded step-by-step to include other advanced (e.g., Net Power, a potentially transformative technology utilizing a high efficiency CO2 conversion cycle (Allam cycle), and chemical looping etc.) pre-combustion and post-combustion technologies applied to natural gas, other fossil fuels (coal and heavy oil) and biomass/biofuel based on findings. Screening analysis is already under development and data for the analysis is being processed. The immediate action on this task include preliminary economic and environmental analysis of power production technologies applied to natural gas. Data for catalytic reforming technology to produce hydrogen from natural gas is being collected and compiled on Microsoft Excel. The model will be expanded for exploring and comparing various technologies scenarios to meet our goal. The primary focus of this study is to: 1) understand the chemic

  12. Mathematical modeling of non-stationary gas flow in gas pipeline

    Science.gov (United States)

    Fetisov, V. G.; Nikolaev, A. K.; Lykov, Y. V.; Duchnevich, L. N.

    2018-03-01

    An analysis of the operation of the gas transportation system shows that for a considerable part of time pipelines operate in an unsettled regime of gas movement. Its pressure and flow rate vary along the length of pipeline and over time as a result of uneven consumption and selection, switching on and off compressor units, shutting off stop valves, emergence of emergency leaks. The operational management of such regimes is associated with difficulty of reconciling the operating modes of individual sections of gas pipeline with each other, as well as with compressor stations. Determining the grounds that cause change in the operating mode of the pipeline system and revealing patterns of these changes determine the choice of its parameters. Therefore, knowledge of the laws of changing the main technological parameters of gas pumping through pipelines in conditions of non-stationary motion is of great importance for practice.

  13. EB technology for the purification of flue gases

    International Nuclear Information System (INIS)

    Kojima, Takuji

    2003-01-01

    Sulfur oxides and nitrogen oxides in flue gas from coal-combustion boilers in power plants, dioxins in flue gas from municipal waste incineration facilities and toxic volatile organic compounds (VOCs) in off-gas from painting or cleaning factories are among air pollutants for which emission is regulated by a law in Japan. Electron beam is the effective and easy controllable radiation source for treatment of these flue gases. This report describes outline of the results so far obtained at JAERI on electron beam treatment of flue gas. The removal performance higher than 90% at 10 kGy for flue gas containing 800 ppm SOx and 225 ppm NOx were achieved and being applied to real-scale power plants in Poland and China with expectation of cost reduction of 20% compared to conventional plants. Decomposition of dioxins in flue gas from solid waste incinerators is another project. Using an accelerator of 300 keV and 40 mA for treatment of real incineration gas at 200degC, we obtain 90% decomposition of dioxins at 15 kGy irradiation. Expansion of these flue gas purification technologies combined with low-energy electron accelerators is expected. (S. Ohno)

  14. Technological innovations to development remote gas reserves: gas-to-liquids; Inovacoes tecnologicas no desenvolvimento de reservas remotas de gas natural: gas-to-liquids

    Energy Technology Data Exchange (ETDEWEB)

    Maculan, Berenice D. [Agencia Nacional do Petroleo, Gas Natural e Biocombustiveis (ANP), Rio de Janeiro, RJ (Brazil); Falabella, Eduardo [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    The GTL - gas to liquids technology was born in Germany, after the 20's with the goal to product liquid fuel from coal to supply the bellicose and domestic demand. The grow of the petroleum industry lead the world to the forgiveness of the GTL technology, except in South Africa. In the last two decades the number of news natural gas reserves and the perspectives of the increase demand from natural gas for the next 20 years change this scenario. Nearly 60% of this reserves are calling stranded or remote, meaning reserves which can't produce with conventional technologies (logistics and economics barriers). So, the oil and gas industry restart to analyze the economics and applicability of the GTL technology. The competitively and applicability of this technology were evaluated and compared to the traditional way of natural gas transport, as well as the solidification of the new environmental rules and the creation of niche to this kind of fuel - the cleans ones - seams the cause of this changes in the oil and gas industries. Which began to adjust to all this news rules and conditions, as show in the sum of investments in R and D area. So, is in this new scenario that the reappear of GTL technology is consider has a technological innovation. (author)

  15. Technological process of a multi-purpose radwaste incineration system

    International Nuclear Information System (INIS)

    Wang Peiyi; Zhou Lianquan; Ma Mingxie; Qiu Mingcai; Yang Liguo; Li Xiaohai; Zhang Xiaobin; Lu Xiaowu; Dong Jingling; Wang Xujin; Li Chuanlian; Yang Baomin

    2002-01-01

    The author introduces the technological process of a multi-purpose radwaste incineration system. It is composed of three parts: pretreatment, incinerating and clean up of off-gas. The waste that may be treated include combustible solid waste, spent resins and oils. Technological routes of the system is pyrolysis incinerating for solid waste, spray incinerating for spent oils, combination of dry-dust removing and wet adsorption for cleaning up off-gas

  16. Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

  17. Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis

    International Nuclear Information System (INIS)

    1994-01-01

    The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates

  18. Development of exhaust gas treatment technologies for environment protection

    International Nuclear Information System (INIS)

    David, E.; Stefanescu, I.; Stanciu, V.; Niculescu, V.; Sandru, C.; Armeanu, A.; Bucura, F.; Sisu, C.

    2006-01-01

    Full text: The emission of carbon dioxide (CO 2 ) and other pollutants which result from burning fossil fuels has been identified as the major contributor to global warming and climate change. However, for the immediate term over the next 10 - 20 years at least, the world will continue to rely on fossil fuels as the source of primary energy. The challenge for the fossil fuel industry is to find cost-effective solutions that will reduce the release of CO 2 and other pollutants into the atmosphere. The focus of this paper is on the ability to treat the exhaust gas from fossil fuel power plants in order to capture and store the CO 2 and remove other pollutants such as SO x and NO x which are released in the atmosphere. In summary, capture/separation costs represent the largest financial impediment for this types of plants. Hence, efficient, cost-effective capture/separation technologies will need to be developed in order to allow their large-scale use. (authors)

  19. Tail gas treatment of SEWGS technology. Literature review on CO2 and H2S separation

    Energy Technology Data Exchange (ETDEWEB)

    Fabbri, E.N.; Van Dijk, H.A.J. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2011-12-15

    This literature review is the result of an investigation of the most important way to remove sulphur for the last decades. We will discuss Claus and Claus tail gas process options to solve the problem. Next to solutions which come from membranes, direct oxidation catalysis, from acid gas removal technology, sorbent technology, and liquid oxidation. Each field will be described and explained to understand in which way it could be suitable to separate CO2 and H2S and reach our goals with regard to CO2 transport and storage conditions. Finally, the target of this work will be to propose some interesting and promising solutions in view of future experiments.

  20. Leak detection technologies for oil and gas pipelines; Tecnologias para deteccao e localizacao de vazamento em dutos de oleo e ou gas

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Julio R. [MTT Aselco Automacao Ltda., Sao Paulo, SP (Brazil)

    2005-07-01

    Two concepts are available for leak detection in oil and/or gas pipelines: On-line leak detection system and off-line leak detection technique. The off-line leak detection technique is, usually, portable and does net configure a 'system'. This technique includes hydro-test, acoustic emission of high frequency, tracer of chemical substances, ultrasonic flow meter (UT), thermographic infra-red mapping, electromagnetic offset registration, etc. Since most of those methods requests stop of the system or depend on direct and detailed inspection of the whole monitored piping they are limited to the off-line inspection. In the current days there are only two technologies applied to detect and locate leaks on-line: The acoustic Leak Detection System and the modeling of computerized simulation also called as RTM (Real Time Modeling), RTTM or Mass Balance. There are still other techniques in the market, as acoustic emission, pressure analysis (PPA) beyond other rough techniques, without good results. Even some of these techniques are working without success, they are still used to accomplish with government standards. (author)

  1. The gas turbine: Present technology and future developments

    International Nuclear Information System (INIS)

    Minghetti, E.

    1997-03-01

    The gas turbine is the most widely used prime mover all over the world for either power generation or mechanical drive applications. The above fact is due to the recent great improvements that have been done especially in terms of efficiency, availability and reliability. The future for gas turbine technological development looks very promising. In fact, although tremendous growth has already taken place, there is still the potential for dramatic improvements in performance. Compared with the competitive prime movers (conventional steam power plants and reciprocating piston engines) the gas turbine technology is younger and still following a strong growth curve. The coming decades will witness the continued increasing in turbine inlet temperature, the development of new materials and refrigeration systems and the commercialization of inter cooled system and steam cooled turbines. With the very soon introduction of the G and H technology, expected single and combined cycle efficiencies for heavy duty machines are respectively 40% and 60%, while maintaining 'single digit' levels in pollutant emissions. In this report are given wide information on gas turbine present technology (Thermodynamics, features, design, performances, emission control, applications) and are discussed the main lines for the future developments. Finally are presented the research and technological development activities on gas turbine of Italian National Agency for new Technology Energy and the Environment Energy Department

  2. Sustainable development: the contributions of gas technology

    International Nuclear Information System (INIS)

    Cappe, D.; Buchet, P.; Muller, T.; Millet, B.

    2007-01-01

    The aim of this workshop was to debate the following questions in relation with sustainable development: what are the contributions of gas technology to the short- and medium-term mastery of demand in residential, tertiary and industry markets? What are the efficient applications of gas technology and what are the energy saving potentialities by type of market? Three participants present their experience in this domain. (J.S.)

  3. Statistical methods to monitor the West Valley off-gas system

    International Nuclear Information System (INIS)

    Eggett, D.L.

    1990-01-01

    This paper reports on the of-gas system for the ceramic melter operated at the West Valley Demonstration Project at West Valley, NY, monitored during melter operation. A one-at-a-time method of monitoring the parameters of the off-gas system is not statistically sound. Therefore, multivariate statistical methods appropriate for the monitoring of many correlated parameters will be used. Monitoring a large number of parameters increases the probability of a false out-of-control signal. If the parameters being monitored are statistically independent, the control limits can be easily adjusted to obtain the desired probability of a false out-of-control signal. The principal component (PC) scores have desirable statistical properties when the original variables are distributed as multivariate normals. Two statistics derived from the PC scores and used to form multivariate control charts are outlined and their distributional properties reviewed

  4. Critique of Hanford Waste Vitrification Plant off-gas sampling requirements

    International Nuclear Information System (INIS)

    Goles, R.W.

    1996-03-01

    Off-gas sampling and monitoring activities needed to support operations safety, process control, waste form qualification, and environmental protection requirements of the Hanford Waste Vitrification Plant (HWVP) have been evaluated. The locations of necessary sampling sites have been identified on the basis of plant requirements, and the applicability of Defense Waste Processing Facility (DWPF) reference sampling equipment to these HWVP requirements has been assessed for all sampling sites. Equipment deficiencies, if present, have been described and the bases for modifications and/or alternative approaches have been developed

  5. Utilization of Common Automotive Three-Way NOx Reduction Catalyst for Managing Off- Gas from Thermal Treatment of High-Nitrate Waste - 13094

    International Nuclear Information System (INIS)

    Foster, Adam L.; Ki Song, P.E.

    2013-01-01

    Studsvik's Thermal Organic Reduction (THOR) steam reforming process has been tested and proven to effectively treat radioactive and hazardous wastes streams with high nitrate contents to produce dry, stable mineral products, while providing high conversion (>98%) of nitrates and nitrites directly to nitrogen gas. However, increased NO x reduction may be desired for some waste streams under certain regulatory frameworks. In order to enhance the NO x reduction performance of the THOR process, a common Three-Way catalytic NO x reduction unit was installed in the process gas piping of a recently completed Engineering Scale Technology Demonstration (ESTD). The catalytic DeNO x unit was located downstream of the main THOR process vessel, and it was designed to catalyze the reduction of residual NO x to nitrogen gas via the oxidation of the hydrogen, carbon monoxide, and volatile organic compounds that are inherent to the THOR process gas. There was no need for auxiliary injection of a reducing gas, such as ammonia. The unit consisted of four monolith type catalyst sections positioned in series with a gas mixing section located between each catalyst section. The process gas was monitored for NO x concentration upstream and downstream of the catalytic DeNO x unit. Conversion efficiencies ranged from 91% to 97% across the catalytic unit, depending on the composition of the inlet gas. Higher concentrations of hydrogen and carbon monoxide in the THOR process gas increased the NO x reduction capability of the catalytic DeNO x unit. The NO x destruction performance of THOR process in combination with the Three-Way catalytic unit resulted in overall system NO x reduction efficiencies of greater than 99.9% with an average NO x reduction efficiency of 99.94% for the entire demonstration program. This allowed the NO x concentration in the ESTD exhaust gas to be maintained at less than 40 parts per million (ppm), dry basis with an average concentration of approximately 17 ppm, dry

  6. Conventional Oil and Gas Technologies. IEA ETSAP technology brief P01

    Energy Technology Data Exchange (ETDEWEB)

    Seljom, Pernille [IFE (Norway)], E-mail: pernille.seljom@ife.no

    2010-05-15

    This technology brief on conventional oil and gas technologies is part of a series produced by the IEA ETSAP agreement called the energy technology data source (E-Tech-DS). The E-Tech-DS series consists of a number of 5-10 page technology briefs similar to the IEA Energy Technology Essentials. Based on the data collected for the models that the Energy Technology Systems Analysis Programme (ETSAP) is known for, ETSAP also prepares technology briefs, called E-TechDS. The E-TechDS briefs are standardized presentations of basic information (process, status, performance, costs, potential, and barriers) for key energy technology clusters. Each brief includes an overview of the technology, charts and graphs, and a summary data table, and usually ending with some key references and further information. The E TechDS briefs are intended to offer essential, reliable and quantitative information to energy analysts, experts, policymakers, investors and media from both developed and developing countries. This specific brief focuses on the state of oil and gas exploration, development, and production/recovery technologies.

  7. Strategic implications of gas to liquids technology for the natural gas industry

    International Nuclear Information System (INIS)

    Russell, B. J.

    1998-01-01

    A new and economical gas to liquids (GTL) technology is described that promises to substantially increase industry's ability to exploit many trillions of cubic feet of largely unmarketable reserves of natural gas. The technology turns the gas into a form that overcomes prohibitive transportation costs, avoids long-term, high-risk, take-or-pay contracts, and helps satisfy the demand for cleaner liquid products. Widespread application of GTL technology is credited with having the power to ease the burden on every segment of the petroleum industry, from exploration through petrochemicals, and into allied industries such as electric power generation. It is claimed that in situations where GTL is the only economic option, it will create an entirely new set of opportunities. Among these are the monetization of known stranded gas and the early development of remote gas discoveries or of oil discoveries associated with gas. It will cause a re-evaluation of exploration strategies by upgrading gas prospects in remote locations and new investment options to countries with shut-in gas or heavy oil or tar sand reserves. The monetization of associated gas when reinjection is no longer needed or desired could occur. Extensive applications offshore and adjacent to coastal reserves and multiple options for refiners facing heavier, higher-sulfur crude slates are possible. The outlook for Syntroleum's version of the GTL process, and the 'grant-back' provisions of Syntroleum's license agreements with companies such as Texaco, ARCO, Marathon, Criterion Catalyst, Catalytica, and ABB, giving each licensee access to the improvements of the other licencees, and the joint development agreements with these companies, were also discussed. 6 refs

  8. Assessment of off-design performance of a small-scale combined cooling and power system using an alternative operating strategy for gas turbine

    International Nuclear Information System (INIS)

    Han, Wei; Chen, Qiang; Lin, Ru-mou; Jin, Hong-guang

    2015-01-01

    Highlights: • We develop an off-design model for a CCP system driven by gas turbine. • An alternative operating strategy is proposed to improve the system performance. • Off-design performance of the combined cooling and power system (CCP) is enhanced. • Effects of both the different operating strategy are analyzed and compared. • Performance enhancement mechanism of the proposed operating strategy is presented. - Abstract: A small-scale combined cooling and power (CCP) system usually serves district air conditioning apart from power generation purposes. The typical system consists of a gas turbine and an exhaust gas-fired absorption refrigerator. The surplus heat of the gas turbine is recovered to generate cooling energy. In this way, the CCP system has a high overall efficiency at the design point. However, the CCP system usually runs under off-design conditions because the users’ demand varies frequently. The operating strategy of the gas turbine will affect the thermodynamic performance of itself and the entire CCP system. The operating strategies for gas turbines include the reducing turbine inlet temperature (TIT) and the compressor inlet air throttling (IAT). A CCP system, consisting of an OPRA gas turbine and a double effects absorption refrigerator, is investigated to identify the effects of different operating strategies. The CCP system is simulated based on the partial-load model of gas turbine and absorption refrigerator. The off-design performance of the CCP system is compared under different operating strategies. The results show that the IAT strategy is the better one. At 50% rated power output of the gas turbine, the IAT operating strategy can increase overall system efficiency by 10% compared with the TIT strategy. In general, the IAT operating strategy is suited for other gas turbines. However, the benefits of IAT should be investigated in the future, when different gas turbine is adopted. This study may provide a new operating

  9. Evaluation of the HEPA filter in-place test method in a corrosive off-gas environment

    International Nuclear Information System (INIS)

    Murphy, L.P.; Wong, M.A.; Girton, R.C.

    1978-01-01

    Experiments were performed to determine if the combined effects of temperature, humidity, and oxides of nitrogen (NO/sub x/) hinder the in-place testing of high-efficiency particulate air (HEPA) filters used for cleaning the off-gas from a nuclear waste solidification facility. The laboratory system that was designed to simulate the process off-gas contained two HEPA filters in series with sample ports before each filter and after the filter bank. The system also included a reaction bomb for partial conversion of NO to NO 2 . Instrumentation measured stream flow, humidity, NO/sub x/ concentration, and temperature. Comparison measurements of the DOP concentrations were made by a forward light-scattering photometer and a single particle intra-cavity laser particle spectrometer. Experimental conditions could be varied, but maximum system capabilities were 95% relative humidity, 90 0 C, and 10,000 ppM of NO/sub x/. A 2 3 factorial experimental design was used for the test program. This design determined the main effects of each factor plus the interactions of the factors in combination. The results indicated that water vapor and NO/sub x/ interfere with the conventional photometer measurements. Suggested modifications that include a unique sample dryer are described to correct the interferences. The laser particle spectrometer appears to be an acceptable instrument for measurements under adverse off-gas conditions

  10. Development of a treatment technology for diluting highly enriched AL-based DOE spent nuclear fuel: principles and practices

    International Nuclear Information System (INIS)

    Adams, T.M.; Duncan, A.J.; Peacock, H.B.; Fisher, D.L.

    2001-01-01

    The Savannah River Site is the U.S. Department of Energy's preferred site for return and treatment of all aluminum-base, spent, research and test reactor fuel assemblies. There are over 20,000 spent fuel assemblies now stored in different countries around the world, and by 2035 many will be returned to SRS for treatment and interim storage. Interim storage canisters at SRS will be sent to a Mined Geologic Repository for long-term geologic storage. Laboratory and plant layout of a full-scale process for irradiated fuel has been completed. Tests of the off gas absorption system have been initiated using both surrogate and irradiated RERTR mini fuel plates. An pilot-scale L-Area Experimental Facility (LEF) is planned to validate induction furnace operations, remote handling, and the off gas system for trapping volatile elements under plant operating conditions. (authors)

  11. AKUT: a process for the separation of aerosols, krypton, and tritium from burner off-gas in HTR-fuel reprocessing

    International Nuclear Information System (INIS)

    Laser, M.; Barnert-Wiemer, H.; Beaujean, H.; Merz, E.; Vygen, H.

    1975-01-01

    The AKUT process consists of the following process steps: (1) aerosol retention by an electrostatic separator followed by HEPA filters, (2) oxidation of CO with O 2 or reaction of excess O 2 with CO, respectively, (3) compression, (4) scrubbing and/or liquefaction, (5) separation of krypton by distillation, and (6) separation of tritiated water and iodine by adsorption or chemical reaction. Liquefied off-gas with low permanent gas content resulting from graphite burning with oxygen may be distilled at ambient temperature. Off-gas with higher permanent gas content from burning with oxygen enriched air must be processed at lower temperature. The ambient temperature flow sheet is preferable from an economic as well as safety point of view. (U.S.)

  12. Gas and energy technology 2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-05-15

    Norway has a long tradition as an energy producing nation. No other country administers equally large quantities of energy compared to the number of inhabitants. Norway faces great challenges concerning the ambitions of utilizing natural gas power and living up to its Kyoto protocol pledges. Tekna would like to contribute to increased knowledge about natural gas and energy, its possibilities and technical challenges. Topics treated include carrying and employing natural gas, aspects of technology, energy and environment, hydrogen as energy carrier, as well as other energy alternatives, CO{sub 2} capture and the value chain connected to it.

  13. Cleanable sintered metal filters in hot off-gas systems

    International Nuclear Information System (INIS)

    Schurr, G.A.

    1981-01-01

    Filters with sintered metal elements, arranged as tube bundles with backflush air cleaning, are the equivalent of bag filters for high-temperature, harsh environments. They are virtually the only alternative for high-temperature off-gas systems where a renewable, highly efficient particle trap is required. Tests were conducted which show that the sintered metal elements installed in a filter system provide effective powder collection in high-temperature atmospheres over thousands of cleaning cycles. Such a sintered metal filter system is now installed on the experimental defense waste calciner at the Savannah River Laboratory. The experimental results included in this paper were used as the basis for its design

  14. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    Energy Technology Data Exchange (ETDEWEB)

    Reigel, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  15. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    Energy Technology Data Exchange (ETDEWEB)

    Reigel, M. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  16. Two-stage thermal/nonthermal waste treatment process

    International Nuclear Information System (INIS)

    Rosocha, L.A.; Anderson, G.K.; Coogan, J.J.; Kang, M.; Tennant, R.A.; Wantuck, P.J.

    1993-01-01

    An innovative waste treatment technology is being developed in Los Alamos to address the destruction of hazardous organic wastes. The technology described in this report uses two stages: a packed bed reactor (PBR) in the first stage to volatilize and/or combust liquid organics and a silent discharge plasma (SDP) reactor to remove entrained hazardous compounds in the off-gas to even lower levels. We have constructed pre-pilot-scale PBR-SDP apparatus and tested the two stages separately and in combined modes. These tests are described in the report

  17. ECOLOGY SAFETY TECHNOLOGIES OF UNCONVENTIONAL OIL RESERVES RECOVERY FOR SUSTAINABLE OIL AND GAS INDUSTRY DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Viacheslav Zyrin

    2016-09-01

    Full Text Available The problem of effective technology for heavy oil recovery nowadays has a great importance, because of worsening geological conditions of the developed deposits, decreasing recovery factor, increasing the part of heavy oil. For the future sustainable development of oil producing industry the involved technologies must require energy effectiveness and ecological safety. The paper proves the enhanced oil recovery methods necessity for heavy oil deposits, highlighted thermal technologies as the most effective. But traditional thermal treatment technologies is a source of air pollutant emission, such as CO, NO etc. The calculation of emissions for traditional steam generator is provided. Besides, the paper shows the effectiveness of electrical enhanced oil recovery methods. The advantages of associated gas as a fuel for cogeneration plants is shown. The main approaches to implementation of carbon dioxide sequestration technologies in the oil and gas industry of Russia are defined. Conceptual view of СО2-EOR technologies potential within the context of sustainable development of oil and gas industry are presented. On the basis of the conducted research a number of scientific research and practical areas of the CCS technology development are revealed.

  18. Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

    Science.gov (United States)

    Siemer, Darryl D.; Lewis, Leroy C.

    1990-01-01

    A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

  19. Gas-Fired Distributed Energy Resource Technology Characterizations

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, L.; Hedman, B.; Knowles, D.; Freedman, S. I.; Woods, R.; Schweizer, T.

    2003-11-01

    The U. S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) is directing substantial programs in the development and encouragement of new energy technologies. Among them are renewable energy and distributed energy resource technologies. As part of its ongoing effort to document the status and potential of these technologies, DOE EERE directed the National Renewable Energy Laboratory to lead an effort to develop and publish Distributed Energy Technology Characterizations (TCs) that would provide both the department and energy community with a consistent and objective set of cost and performance data in prospective electric-power generation applications in the United States. Toward that goal, DOE/EERE - joined by the Electric Power Research Institute (EPRI) - published the Renewable Energy Technology Characterizations in December 1997.As a follow-up, DOE EERE - joined by the Gas Research Institute - is now publishing this document, Gas-Fired Distributed Energy Resource Technology Characterizations.

  20. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    2000-01-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2)TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2)TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  1. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    1999-01-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2)TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2)TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  2. Linking environment-productivity trade-offs and correlated uncertainties: Greenhouse gas emissions and crop productivity in paddy rice production systems

    International Nuclear Information System (INIS)

    Hayashi, Kiyotada; Nagumo, Yoshifumi; Domoto, Akiko

    2016-01-01

    In comparative life cycle assessments of agricultural production systems, analyses of both the trade-offs between environmental impacts and crop productivity and of the uncertainties specific to agriculture such as fluctuations in greenhouse gas (GHG) emissions and crop yields are crucial. However, these two issues are usually analyzed separately. In this paper, we present a framework to link trade-off and uncertainty analyses; correlated uncertainties are integrated into environment-productivity trade-off analyses. We compared three rice production systems in Japan: a system using a pelletized, nitrogen-concentrated organic fertilizer made from poultry manure using closed-air composting techniques (high-N system), a system using a conventional organic fertilizer made from poultry manure using open-air composting techniques (low-N system), and a system using a chemical compound fertilizer (conventional system). We focused on two important sources of uncertainties in paddy rice cultivation—methane emissions from paddy fields and crop yields. We found trade-offs between the conventional and high-N systems and the low-N system and the existence of positively correlated uncertainties in the conventional and high-N systems. We concluded that our framework is effective in recommending the high-N system compared with the low-N system, although the performance of the former is almost the same as the conventional system. - Highlights: • Correlated uncertainties were integrated into environment-productivity trade-offs. • Life cycle GHG emissions and crop yields were analyzed using field and survey data. • Three rice production systems using chemical or organic fertilizers were compared. • There were portfolio (insurance) effects in matured technologies. • Analysis of trade-offs and correlated uncertainties will be useful for decisions.

  3. Linking environment-productivity trade-offs and correlated uncertainties: Greenhouse gas emissions and crop productivity in paddy rice production systems

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Kiyotada, E-mail: hayashi@affrc.go.jp [Institute for Agro-Environmental Sciences, National Agriculture and Food Research Organization, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan); Nagumo, Yoshifumi [Crop Research Center, Niigata Agricultural Research Institute, 857 Nagakura-machi, Nagaoka, Niigata 940-0826 (Japan); Domoto, Akiko [Mie Prefecture Agricultural Research Institute, 530 Kawakita-cho, Ureshino, Matsusaka, Mie 515-2316 (Japan)

    2016-11-15

    In comparative life cycle assessments of agricultural production systems, analyses of both the trade-offs between environmental impacts and crop productivity and of the uncertainties specific to agriculture such as fluctuations in greenhouse gas (GHG) emissions and crop yields are crucial. However, these two issues are usually analyzed separately. In this paper, we present a framework to link trade-off and uncertainty analyses; correlated uncertainties are integrated into environment-productivity trade-off analyses. We compared three rice production systems in Japan: a system using a pelletized, nitrogen-concentrated organic fertilizer made from poultry manure using closed-air composting techniques (high-N system), a system using a conventional organic fertilizer made from poultry manure using open-air composting techniques (low-N system), and a system using a chemical compound fertilizer (conventional system). We focused on two important sources of uncertainties in paddy rice cultivation—methane emissions from paddy fields and crop yields. We found trade-offs between the conventional and high-N systems and the low-N system and the existence of positively correlated uncertainties in the conventional and high-N systems. We concluded that our framework is effective in recommending the high-N system compared with the low-N system, although the performance of the former is almost the same as the conventional system. - Highlights: • Correlated uncertainties were integrated into environment-productivity trade-offs. • Life cycle GHG emissions and crop yields were analyzed using field and survey data. • Three rice production systems using chemical or organic fertilizers were compared. • There were portfolio (insurance) effects in matured technologies. • Analysis of trade-offs and correlated uncertainties will be useful for decisions.

  4. Natural Gas

    OpenAIRE

    Bakar, Wan Azelee Wan Abu; Ali, Rusmidah

    2010-01-01

    Natural gas fuel is a green fuel and becoming very demanding because it is environmental safe and clean. Furthermore, this fuel emits lower levels of potentially harmful by-products into the atmosphere. Most of the explored crude natural gas is of sour gas and yet, very viable and cost effective technology is still need to be developed. Above all, methanation technology is considered a future potential treatment method for converting the sour natural gas to sweet natural gas.

  5. Thermoeconomic optimization of a cryogenic refrigeration cycle for re-liquefaction of the LNG boil-off gas

    Energy Technology Data Exchange (ETDEWEB)

    Sayyaadi, Hoseyn; Babaelahi, M. [Faculty of Mechanical Engineering-Energy Division, K.N. Toosi University of Technology, P.O. Box: 19395-1999, No. 15-19, Pardis Str., Mollasadra Ave., Vanak Sq., Tehran 1999 143344 (Iran)

    2010-09-15

    The development of the liquefaction process for the Liquefied Natural Gas (LNG) boil-off re-liquefaction plants will be addressed to provide an environmentally friendly and cost effective solution for the gas transportation. In this manner, onboard boil-off gas (BOG) re-liquefaction system as a cryogenic refrigeration cycle is utilized in order to re-liquefy the BOG and returns it to the cargo tanks instead of burning it. In this paper, a thermoeconomic optimization of the LNG-BOG liquefaction system is performed. A thermoeconomic model based on energy and exergy analyses and an economic model according to the total revenue requirement (TRR) are developed. Minimizing of the unit cost of the refrigeration effect as a product of BOG re-liquefaction plant is performed using the genetic algorithm. Results of thermoeconomic optimization are compared with corresponding features of the base case system. Finally, sensitivity of the total cost of the system product with respect to the variation of some operating parameters is studied. (author)

  6. Use of gas chromatography-mass spectrometry-olfactometry and a conventional flask test to identify off-flavor compounds generated from phenylalanine during chlorination of drinking water.

    Science.gov (United States)

    Matsushita, Taku; Sakuma, Miki; Tazawa, Shiori; Hatase, Taiki; Shirasaki, Nobutaka; Matsui, Yoshihiko

    2017-11-15

    Off-flavor in drinking water can be caused by transformation products (TPs) generated from organic compounds, such as amino acids, present during chlorination. However, the contributions of many of these TPs to overall off-flavor have not been quantified, mainly because the lack of appropriate chemical standards prevents sensory evaluation by means of a conventional flask test. In the present study, we used gas chromatography-mass spectrometry-olfactometry (GC-MS-O) to identify compounds responsible for the off-flavor generated by chlorination of an aqueous solution of the amino acid phenylalanine, and we propose a sensory evaluation procedure for quantification of the contributions of the identified TPs to the overall off-flavor, regardless of the availability of chemical standards of the TPs. GC-MS-O revealed that two TPs, N-chlorophenylacetaldimine and 2-chloro-2-phenylacetaldehyde, for which chemical standards are not commercially available, were the main components responsible for the off-flavor of the chlorinated solution. By using a sensory evaluation procedure involving a combination of GC-MS-O and a conventional flask test, we quantified the contributions of TPs to the overall off-flavor of the chlorinated solution. Approximately 60% of the off-flavor was attributable to free chlorine (13%), 2-chloro-2-phenylacetaldehyde (13%), trichloramine (12%) phenylacetaldehyde (11%) phenylacetonitrile (8%), and N-chlorophenylacetaldimine (2%). Treatment with powdered activated carbon (PAC) removed the off-flavor. Experiments with chlorination of 15 N-labeled phenylalanine suggested that PAC reductively decomposed trichloramine into N 2 gas and adsorbed all of the other identified TPs. Superfine PAC (median diameter, 0.7 μm) removed the off-flavor more rapidly than normal-size PAC (median diameter, 8.0 μm). Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Development of thermal conditioning technology for Alpha-containment wastes: Alpha-contaminated waste incineration technology

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Joon Hyung; Kim, Jeong Guk; Yang, Hee Chul; Choi, Byung Seon; Jeong, Myeong Soo

    1999-03-01

    As the first step of a 3-year project named 'development of alpha-contaminated waste incineration technology', the basic information and data were reviewed, while focusing on establishment of R and D direction to develop the final goal, self-supporting treatment of {alpha}- wastes that would be generated from domestic nuclear industries. The status on {alpha} waste incineration technology of advanced states was reviewed. A conceptual design for {alpha} waste incineration process was suggested. Besides, removal characteristics of volatile metals and radionuclides in a low-temperature dry off-gas system were investigated. Radiation dose assessments and some modification for the Demonstration-scale Incineration Plant (DSIP) at Korea Atomic Energy Research Institute (KAERI) were also done.

  8. Development of thermal conditioning technology for Alpha-containment wastes: Alpha-contaminated waste incineration technology

    International Nuclear Information System (INIS)

    Kim, Joon Hyung; Kim, Jeong Guk; Yang, Hee Chul; Choi, Byung Seon; Jeong, Myeong Soo

    1999-03-01

    As the first step of a 3-year project named 'development of alpha-contaminated waste incineration technology', the basic information and data were reviewed, while focusing on establishment of R and D direction to develop the final goal, self-supporting treatment of α- wastes that would be generated from domestic nuclear industries. The status on α waste incineration technology of advanced states was reviewed. A conceptual design for α waste incineration process was suggested. Besides, removal characteristics of volatile metals and radionuclides in a low-temperature dry off-gas system were investigated. Radiation dose assessments and some modification for the Demonstration-scale Incineration Plant (DSIP) at Korea Atomic Energy Research Institute (KAERI) were also done

  9. Corrosion in the off-gas system of a radioactive-waste incinerator

    International Nuclear Information System (INIS)

    Jenkins, C.F.; Peters, J.J.

    1987-01-01

    Corrosion in a low-level radioactive-waste incinerator off-gas system at the Department of Energy's Savannah River Plant is discussed. Severe corrosive attack and failure of an alloy 600 part exposed to high-temperature (>1000 0 C) gases was observed. Rapid attack of carbon steel components, and cracking of austenitic stainless steel parts also occurred at locations where lower gas temperatures and periodic condensate exposure occurred. Investigation showed HCl, SO 2 , SO 3 and phosphorus-oxides were present and contributed to the failures. Mechanisms of high-temperature failure include alloy separation and reactions with phosphorus. Coupons placed in the exhaust stream have provided information for selection of future materials of construction for system components. Several nickel- and iron-base alloys, and a stainless steel with an aluminum-diffusion coating were investigated

  10. Fabrication of remote steam atomized scrubbers for DWPF off-gas system

    International Nuclear Information System (INIS)

    Nielsen, M.G.; Lafferty, J.D.

    1988-01-01

    The defense waste processing facility (DWPF) is being constructed for the purpose of processing high-level waste from sludge to a vitrified borosilicate glass. In the operation of continuous slurry-fed melters, off-gas aerosols are created by entrainment of feed slurries and the vaporization of volatile species from the molten glass mixture. It is necessary to decontaminate these aerosols in order to minimize discharge of airborne radionuclide particulates. A steam atomized scrubber (SAS) has been developed for DWPF which utilizes a patented hydro- sonic system gas scrubbing method. The Hydro-Sonic System utilizes a steam aspirating-type venturi scrubber that requires very precise fabrication tolerances in order to obtain acceptable decontamination factors. In addition to the process-related tolerances, precision mounting and nozzle tolerances are required for remote service at DWPF

  11. Advanced Gas Storage Concepts: Technologies for the Future

    Energy Technology Data Exchange (ETDEWEB)

    Freeway, Katy (PB-KBB Inc.); Rogers, R.E. (Mississippi State University); DeVries, Kerry L.; Nieland, Joel D.; Ratigan, Joe L.; Mellegard, Kirby D. (RESPEC)

    2000-02-01

    This full text product includes: 1) A final technical report titled Advanced Underground Gas Storage Concepts, Refrigerated-Mined Cavern Storage and presentations from two technology transfer workshops held in 1998 in Houston, Texas, and Pittsburgh, Pennsylvania (both on the topic of Chilled Gas Storage in Mined Caverns); 2) A final technical report titled Natural Gas Hydrates Storage Project, Final Report 1 October 1997 - 31 May 1999; 3) A final technical report titled Natural Gas Hydrates Storage Project Phase II: Conceptual Design and Economic Study, Final Report 9 June - 10 October 1999; 4) A final technical report titled Commerical Potential of Natural Gas Storage in Lined Rock Caverns (LRC) and presentations from a DOE-sponsored workshop on Alternative Gas Storage Technologies, held Feb 17, 2000 in Pittsburgh, PA; and 5) Phase I and Phase II topical reports titled Feasibility Study for Lowering the Minimum Gas Pressure in Solution-Mined Caverns Based on Geomechanical Analyses of Creep-Induced Damage and Healing.

  12. Gas-fired power. IEA ETSAP technology brief E02

    Energy Technology Data Exchange (ETDEWEB)

    Seebregts, A.J. [Energy research Centre of the Netherlands (Netherlands)], E-mail: seebregts@ecn.nl

    2010-04-15

    This technology brief on gas-fired power is part of a series produced by the IEA called the energy technology data source (E-Tech-DS). The E-Tech-DS series consists of a number of 5-10 page technology briefs similar to the IEA Energy Technology Essentials. Based on the data collected for the models that the Energy Technology Systems Analysis Programme (ETSAP) is known for, ETSAP also prepares technology briefs, called E-TechDS. The E-TechDS briefs are standardized presentations of basic information (process, status, performance, costs, potential, and barriers) for key energy technology clusters. Each brief includes an overview of the technology, charts and graphs, and a summary data table, and usually ending with some key references and further information. The E TechDS briefs are intended to offer essential, reliable and quantitative information to energy analysts, experts, policymakers, investors and media from both developed and developing countries. This specific brief focuses on the state of combined-cycle gas turbines (CCGT). CCGT's have become the technology of choice for new gas-fired power plants since the 1990's.

  13. Pinch-off Scaling Law of Soap Bubbles

    Science.gov (United States)

    Davidson, John; Ryu, Sangjin

    2014-11-01

    Three common interfacial phenomena that occur daily are liquid drops in gas, gas bubbles in liquid and thin-film bubbles. One aspect that has been studied for these phenomena is the formation or pinch-off of the drop/bubble from the liquid/gas threads. In contrast to the formation of liquid drops in gas and gas bubbles in liquid, thin-film bubble pinch-off has not been well documented. Having thin-film interfaces may alter the pinch-off process due to the limiting factor of the film thickness. We observed the pinch-off of one common thin-film bubble, soap bubbles, in order to characterize its pinch-off behavior. We achieved this by constructing an experimental model replicating the process of a human producing soap bubbles. Using high-speed videography and image processing, we determined that the minimal neck radius scaled with the time left till pinch-off, and that the scaling law exponent was 2/3, similar to that of liquid drops in gas.

  14. Ceramics technology for advanced industrial gas turbines

    International Nuclear Information System (INIS)

    Anson, D.; Sheppard, W.J.; DeCorso, M.; Parks, W.J. Jr.

    1991-01-01

    Recent developments in the fabrication of high strength ceramic materials and in their application to automotive and aerospace gas turbine engines may lead also to significant improvements in the performance of industrial gas turbines. This paper presents a brief review of the improvements projected in a study initiated by the U.S. Department of Energy. The future costs of power generated by small gas turbines (up to 25 MW) are predicted, as well as the potential for fuel savings. Gas turbines in this size range are used extensively for gas compression and for cogeneration, as well as in a variety of more diverse applications. This paper includes results of analyses of the ways in which changes in gas turbine cost and performance are likely to affect market penetration. These results lead to predictions of future savings in U.S. fuel consumption in the industrial sector that would result. The paper also presents a brief overview of the scope of a suggested R and D program, with an appropriate schedule, which would provide a technical basis for achieving the projected results. Important parts of this program would cover ceramic design and fabrication technology, engine development and demonstration, and combustion technology

  15. Improvement of Cooling Technology through Atmosphere Gas Management

    Energy Technology Data Exchange (ETDEWEB)

    Renard, Michel; Dosogne, Edgaar; Crutzen, Jean Pierre; Raick, Jean Mare [DREVER INTERNATIONAL S.A., Liege (Belgium); Ji, Ma Jia; Jun, Lv; Zhi, Ma Bing [SHOUGANG Cold Rolling Mill Headquarter, Beijin (China)

    2009-12-15

    The production of advanced high strength steels requires the improvement of cooling technology. The use of high cooling rates allows relatively low levels of expensive alloying additions to ensure sufficient hardenability. In classical annealing and hot-dip galvanizing lines a mixing station is used to provide atmosphere gas containing 3-5% hydrogen and 97-95% nitrogen in the various sections of the furnace, including the rapid cooling section. Heat exchange enhancement in this cooling section can be insured by the increased hydrogen concentration. Driver international developed a patented improvement of cooling technology based on the following features: pure hydrogen gas is injected only in the rapid cooling section whereas the different sections of the furnace are supplied with pure nitrogen gas: the control of flows through atmosphere gas management allows to get high hydrogen concentration in cooling section and low hydrogen content in the other furnace zones. This cooling technology development insures higher cooling rates without additional expensive hydrogen gas consumption and without the use of complex sealing equipment between zones. In addition reduction in electrical energy consumption is obtained. This atmosphere control development can be combined with geometrical design improvements in order to get optimised cooling technology providing high cooling rates as well as reduced strip vibration amplitudes. Extensive validation of theoretical research has been conducted on industrial lines. New lines as well as existing lines, with limited modifications, can be equipped with this new development. Up to now this technology has successfully been implemented on 6 existing and 7 new lines in Europe and Asia.

  16. Introducing new technology in the gas industry

    International Nuclear Information System (INIS)

    Szilard, S.; Powrie, D.

    1995-01-01

    The approach taken by Consumer's Gas in the introduction of new products was described. The company's role in technology development in the last decade was summarized in the context of other industries' practices. New product experiences and the key factors for success were also revealed. A professionally managed New Product Introduction (NPI) process launched by Consumer Gas in 1994 was outlined. Its objectives were stated as (1) providing strong leadership; (2) a widely held sense of urgency; (3) customer orientation; (4) doing the 'up front homework'; (5) the importance of teamwork; (6) a formal new product process; and (7) a simple management structure. The need for keeping up with technological changes and customer trends, while inspiring others in the gas distribution business to act similarly, was emphasized

  17. Development of the krypton absorption in liquid carbon dioxide (KALC) process for HTGR off-gas reprocessing

    International Nuclear Information System (INIS)

    Glass, R.W.; Beaujean, H.W.R.; Cochran, H.D. Jr.; Haas, P.A.; Levins, D.M.; Woods, W.M.

    1975-01-01

    Reprocessing of High-Temperature Gas-Cooled Reactor (HTGR) fuel involves burning of the graphite-matrix elements to release the fuel for recovery purposes. The resulting off-gas is primarily CO 2 with residual amounts of N 2 , O 2 , and CO, together with fission products. Trace quantities of krypton-85 must be recovered in a concentrated form from the gas stream, but processes commonly employed for rare gas removal and concentration are not suitable for use with off-gas from graphite burning. The KALC (Krypton Absorption in Liquid CO 2 ) process employs liquid CO 2 as a volatile solvent for the krypton and is, therefore, uniquely suited to the task. Engineering development of the KALC process is currently under way at the Oak Ridge National Laboratory (ORNL) and the Oak Ridge Gaseous Diffusion Plant (ORGDP). The ORNL system is designed for close study of the individual separation operations involved in the KALC process, while the ORGDP system provides a complete pilot facility for demonstrating combined operations on a somewhat larger scale. Packed column performance and process control procedures have been of prime importance in the initial studies. Computer programs have been prepared to analyze and model operational performance of the KALC studies, and special sampling and in-line monitoring systems have been developed for use in the experimental facilities. (U.S.)

  18. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    Energy Technology Data Exchange (ETDEWEB)

    Chudnovsky, Yaroslav [Gas Technology Inst., Des Plaines, IL (United States); Kozlov, Aleksandr [Gas Technology Inst., Des Plaines, IL (United States)

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel

  19. Radioactive gas solidification treatment device

    International Nuclear Information System (INIS)

    Igarashi, Ryokichi; Watanabe, Yu; Seki, Eiji.

    1992-01-01

    In a radioactive gas solidification treatment device by using sputtering, spiral pipelines are disposed with a gap therebetween for cooling an ion injection electrode by passing cooling water during operation of the solidification treatment. During the operation of the solidification treatment, cooling water is passed in the pipelines to cool the ion injection electrode. During storage, a solidification vessel is cooled by natural heat dissipation from an exposed portion at the surface of the solidification vessel. Accordingly, after-heat of radioactive gas solidified in a metal accumulation layer can be removed efficiently, safely and economically to improve the reliability. (N.H.)

  20. Gas power plant with CO2 handling. A study of alternative technologies

    International Nuclear Information System (INIS)

    Bolland, Olav; Hagen, Roger I.; Maurstad, Ola; Tangen, Grethe; Juliussen, Olav; Svendsen, Hallvard

    2002-01-01

    The report documents a study which compares 12 different technologies for gas power plants with CO 2 handling. The additional costs in removing the CO 2 in connection with electricity production is calculated to at least 18-19 oere /kWh compared to conventional gas power production without CO 2 capture. The calculated extra costs are somewhat higher than previously published figures. The difference is mainly due to that the estimated costs for pipelines and injection system for CO 2 are higher than in other studies. The removal of CO 2 in connection with gas power production implies increased use of natural gas. The most developed technologies would lead to a procentual increase in the gas consumption per kWh electricity of 18-25%. Gas power plants based on the present technologies would have efficiencies in the size of 46-49%. The efficiency of power plants without CO 2 handling is supposed to be 58%. There is no foundation for pointing out a ''winner's' among the compared technologies in the study. The present available technologies excepted, there are no technology which stands out as better than the others from an economic viewpoint. Gas turbine with membrane based separation of oxygen from air (AZEP) has a potential for lower costs but implies challenging technological development and thence considerable technological risks. Two technologies, capture of carbon from natural gas previous to combustion and exhaust gas purification based on absorption, may be employed in 3 - 4 years. The other technologies require more development and maturing. Three of the technologies may be particularly interesting because hydrogen may be produced as a byproduct. Demonstration plant and choice of technology: 1) There is a limited need for demonstration plants with respect to technology development. 2) It is important for the technology development to be able to test various technologies in a laboratory or in a flexible pilot plant. 3) Many technologies and components may be

  1. Energy and Economic Trade Offs for Advanced Technology Subsonic Aircraft

    Science.gov (United States)

    Maddalon, D. V.; Wagner, R. D.

    1976-01-01

    Changes in future aircraft technology which conserve energy are studied, along with the effect of these changes on economic performance. Among the new technologies considered are laminar-flow control, composite materials with and without laminar-flow control, and advanced airfoils. Aircraft design features studied include high-aspect-ratio wings, thickness ratio, and range. Engine technology is held constant at the JT9D level. It is concluded that wing aspect ratios of future aircraft are likely to significantly increase as a result of new technology and the push of higher fuel prices. Composite materials may raise aspect radio to about 11 to 12 and practical laminar flow-control systems may further increase aspect ratio to 14 or more. Advanced technology provides significant reductions in aircraft take-off gross weight, energy consumption, and direct operating cost.

  2. A new in-gas-laser ionization and spectroscopy laboratory for off-line studies at KU Leuven

    International Nuclear Information System (INIS)

    Kudryavtsev, Yu.; Creemers, P.; Ferrer, R.; Granados, C.; Gaffney, L.P.; Huyse, M.; Mogilevskiy, E.; Raeder, S.; Sels, S.; Van den Bergh, P.; Van Duppen, P.; Zadvornaya, A.

    2016-01-01

    The in-gas laser ionization and spectroscopy (IGLIS) technique is used to produce and to investigate short-lived radioactive isotopes at on-line ion beam facilities. In this technique, the nuclear reaction products recoiling out of a thin target are thermalized and neutralized in a high-pressure noble gas, resonantly ionized by the laser beams in a two-step process, and then extracted from the ion source to be finally accelerated and mass separated. Resonant ionization of radioactive species in the supersonic gas jet ensures very high spectral resolution because of essential reduction of broadening mechanisms. To obtain the maximum efficiency and the best spectral resolution, properties of the supersonic jet and the laser beams must be optimized. To perform these studies a new off-line IGLIS laboratory, including a new high-repetition-rate laser system and a dedicated off-line mass separator, has been commissioned. In this article, the specifications of the different components necessary to achieve optimum conditions in laser-spectroscopy studies of radioactive beams using IGLIS are discussed and the results of simulations are presented.

  3. Environmental assessment of digestate treatment technologies using LCA methodology.

    Science.gov (United States)

    Vázquez-Rowe, Ian; Golkowska, Katarzyna; Lebuf, Viooltje; Vaneeckhaute, Céline; Michels, Evi; Meers, Erik; Benetto, Enrico; Koster, Daniel

    2015-09-01

    The production of biogas from energy crops, organic waste and manure has augmented considerably the amounts of digestate available in Flanders. This has pushed authorities to steadily introduce legislative changes to promote its use as a fertilising agent. There is limited arable land in Flanders, which entails that digestate has to compete with animal manure to be spread. This forces many anaerobic digestion plants to further treat digestate in such a way that it can either be exported or the nitrogen be removed. Nevertheless, the environmental impact of these treatment options is still widely unknown, as well as the influence of these impacts on the sustainability of Flemish anaerobic digestion plants in comparison to other regions where spreading of raw digestate is allowed. Despite important economic aspects that must be considered, the use of Life Cycle Assessment (LCA) is suggested in this study to identify the environmental impacts of spreading digestate directly as compared to four different treatment technologies. Results suggest relevant environmental gains when the digestate mix is treated using the examined conversion technologies prior to spreading, although important trade-offs between impact categories were observed and discussed. The promising results of digestate conversion technologies suggest that further LCA analyses should be performed to delve into, for instance, the appropriateness to shift to nutrient recovery technologies rather than digestate conversion treatments. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Clean coal technologies for gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Todd, D.M. [GE Industrial & Power Systems, Schenectady, NY (United States)

    1994-12-31

    The oil- and gas-fired turbine combined-cycle penetration of industrial and utility applications has escalated rapidly due to the lower cost, higher efficiency and demonstrated reliability of gas turbine equipment in combination with fuel economics. Gas turbine technology growth has renewed the interest in the use of coal and other solid fuels in combined cycles for electrical and thermal energy production to provide environmentally acceptable plants without extra cost. Four different types of systems utilizing the gas turbine advantages with solid fuel have been studied: direct coal combustion, combustor processing, fuel processing and indirect cycles. One of these, fuel processing (exemplified by coal gasification), is emerging as the superior process for broad scale commercialization at this time. Advances in gas turbine design, proven in operation above 200 MW, are establishing new levels of combined-cycle net plant efficiencies up to 55% and providing the potential for a significant shift to gas turbine solid fuel power plant technology. These new efficiencies can mitigate the losses involved in gasifying coal and other solid fuels, and economically provide the superior environmental performance required today. Based on demonstration of high baseload reliability for large combined cycles (98%) and the success of several demonstrations of Integrated Gasification Combined Cycle (IGCC) plants in the utility size range, it is apparent that many commercial IGCC plants will be sites in the late 1990s. This paper discusses different gas turbine systems for solid fuels while profiling available IGCC systems. The paper traces the IGCC option as it moved from the demonstration phase to the commercial phase and should now with planned future improvements, penetrate the solid fuel power generation market at a rapid pace.

  5. AlN/GaN heterostructures for normally-off transistors

    Energy Technology Data Exchange (ETDEWEB)

    Zhuravlev, K. S., E-mail: zhur@isp.nsc.ru; Malin, T. V.; Mansurov, V. G.; Tereshenko, O. E. [Russian Academy of Sciences, Rzhanov Institute of Semiconductor Physics, Siberian Branch (Russian Federation); Abgaryan, K. K.; Reviznikov, D. L. [Dorodnicyn Computing Centre of the Russian Academy of Sciences (Russian Federation); Zemlyakov, V. E.; Egorkin, V. I. [National Research University of Electronic Technology (MIET) (Russian Federation); Parnes, Ya. M.; Tikhomirov, V. G. [Joint Stock Company “Svetlana-Electronpribor” (Russian Federation); Prosvirin, I. P. [Russian Academy of Sciences, Boreskov Institute of Catalysis, Siberian Branch (Russian Federation)

    2017-03-15

    The structure of AlN/GaN heterostructures with an ultrathin AlN barrier is calculated for normally-off transistors. The molecular-beam epitaxy technology of in situ passivated SiN/AlN/GaN heterostructures with a two-dimensional electron gas is developed. Normally-off transistors with a maximum current density of ~1 A/mm, a saturation voltage of 1 V, a transconductance of 350 mS/mm, and a breakdown voltage of more than 60 V are demonstrated. Gate lag and drain lag effects are almost lacking in these transistors.

  6. Compressed Natural Gas Technology for Alternative Fuel Power Plants

    Science.gov (United States)

    Pujotomo, Isworo

    2018-02-01

    Gas has great potential to be converted into electrical energy. Indonesia has natural gas reserves up to 50 years in the future, but the optimization of the gas to be converted into electricity is low and unable to compete with coal. Gas is converted into electricity has low electrical efficiency (25%), and the raw materials are more expensive than coal. Steam from a lot of wasted gas turbine, thus the need for utilizing exhaust gas results from gas turbine units. Combined cycle technology (Gas and Steam Power Plant) be a solution to improve the efficiency of electricity. Among other Thermal Units, Steam Power Plant (Combined Cycle Power Plant) has a high electrical efficiency (45%). Weakness of the current Gas and Steam Power Plant peak burden still using fuel oil. Compressed Natural Gas (CNG) Technology may be used to accommodate the gas with little land use. CNG gas stored in the circumstances of great pressure up to 250 bar, in contrast to gas directly converted into electricity in a power plant only 27 bar pressure. Stored in CNG gas used as a fuel to replace load bearing peak. Lawyer System on CNG conversion as well as the power plant is generally only used compressed gas with greater pressure and a bit of land.

  7. New gas turbine technology 2012-2014 - Gas Turbine Developments

    Energy Technology Data Exchange (ETDEWEB)

    Genrup, Magnus; Thern, Marcus [LTH, Lund (Sweden)

    2013-03-15

    The last three years have certainly been a game changer with respect to combined cycle efficiency and operational flexibility. All major manufacturers are able to offer plants with efficiencies around 61 percent. Siemens has a TUV-certified performance of 60.75 percent at the Kraftwerke Ulrich Hartmann (formerly Irsching 4) site outside Berlin. The old paradigm that high performance meant advanced steam-cooled gas turbines and slow started bottoming cycles has definitely proven false. Both Siemens and General Electric are able to do a hot restart within 30 minutes to, more or less, full load. This is, by far, faster than possible with steam cooling and the only technology that is capable of meeting the future flexibility requirements due to high volatile renewable penetration. All major manufacturers have developed air-cooled engines for combined cycles with 61 percent efficiency. Steam cooling will most likely only be used for 1600 deg firing level since there will be an air shortage for both dry low emission combustion and turbine cooling. The increased combined cycle efficiency is a combination of better (or higher) performing gas turbines and improved bottoming cycles. The higher gas turbine performance has been achieved whilst maintaining a 60 deg high pressure admission temperature - hence the gain in combined cycle performance. The mentioned requirements of both high gas turbine performance and sufficient exhaust temperature, should impose both an increase in pressure ratio and increased firing level. The price level (2012) was on average 30-35 percent higher than the minimum level in 2004. The cost of ownership (or per produced unit of power) is strongly governed by the difference between the electricity and the fuel price. The importance of evaluating all factors (like degradation and de-icing operation) in the economic model cannot be stressed too much since it may have a profound impact on the analysis. The test code guarantee verification test is indeed

  8. RESOURCE SAVING TECHNOLOGICAL PROCESS OF LARGE-SIZE DIE THERMAL TREATMENT

    Directory of Open Access Journals (Sweden)

    L. A. Glazkov

    2009-01-01

    Full Text Available The given paper presents a development of a technological process pertaining to hardening large-size parts made of die steel. The proposed process applies a water-air mixture instead of a conventional hardening medium that is industrial oil.While developing this new technological process it has been necessary to solve the following problems: reduction of thermal treatment duration, reduction of power resource expense (natural gas and mineral oil, elimination of fire danger and increase of process ecological efficiency. 

  9. Shell launches its Claus off-gas desulfurization process

    Energy Technology Data Exchange (ETDEWEB)

    Groenendaal, W; van Meurs, H C.A.

    1972-01-01

    The Shell Flue Gas Desulfurization (SFGD) Process was developed for removal of sulfur oxides from flue gases originating from oil-fired boilers or furnaces. It can also be used to remove sulfur dioxide from Claus sulfur recovery tail gases if they are combined with boiler/furnace flue gases. For Claus tail gas only, the Shell Claus off-gas desulfurization process was developed. Claus unit operation and desulfurization by low temperature Claus processes and conversion/concentration processes are discussed. The new Shell process consists of a conversion/concentration process involving a reduction section and an amine absorption section. In the reduction section, all sulfur compounds and free sulfur are completely reduced to hydrogen sulfide with hydrogen, or hydrogen plus carbon monoxide, over a cobalt/molybdenum-on-alumina catalyst at a temperature of about 300/sup 0/C. Extensive bench scale studies on the reduction system have been carried out. A life test of more than 4000 hr showed a stable activity of the reduction catalyst, which means that in commercial units, very long catalyst lives can be expected. The commercial feasibility of the reduction section was further demonstrated in the Godorf refinery of Deutsche Shell AG. More than 80 absorption units using alkanolamine (AIDP) solutions have been installed. Bench scale studies of the ADIP absorption units were compared to commercial experience.The total capital investment of the new Shell process is 0.7, 2.0, and 3.2 $ times 10 to the 6th power for 100, 500, and 1000 tons of sulfur/sd capacity Claus units, respectively. The total operating costs for these units are, respectively, 610, 1930 and 3310 $/stream day. The capital investment corresponds to about 75% of the capital investment of the preceding Claus unit.

  10. Electron beam flue gas treatment. Research cooperation among JAERI, IAEA and INCT

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    The research co-operation is conducted among Japan Atomic Energy Research Institute (JAERI), International Atomic Energy Agency (IAEA) and Institute of Nuclear Chemistry and Technology in Poland (INCT) on Electron Beam Flue Gas Treatment from January 1993 to March 1997. The first phase of the cooperation was carried out for 3 years from January 1993 to March 1995. This cooperation was performed through information exchange meetings (Coordination Meetings), held in Takasaki and Warsaw, and experiments and discussions by exchange scientists. Many useful results were obtained on electron beam treatment of flue gas from coal-combustion heat generation plant in Kaweczyn within the frame work of the research co-operation. This report includes the main results of the tripartite research cooperation. (author)

  11. Creation of technological bases of struggle with generation of natural gas hydrates

    International Nuclear Information System (INIS)

    Asadov, M.M.; Alieva, S.A.

    2005-01-01

    Chemical technological access, permitting directed of intensify processes prevention of gas hydrates during motion of the gas-liquid current of natural gas in the borehole cavity of natural gas-borehole cavity have been engineered. Determined technological regimes of gas current conditioning, permitting create nonequilibrium state providing condition for reversible process

  12. Gas embolism: pathophysiology and treatment

    NARCIS (Netherlands)

    van Hulst, Robert A.; Klein, Jan; Lachmann, Burkhard

    2003-01-01

    Based on a literature search, an overview is presented of the pathophysiology of venous and arterial gas embolism in the experimental and clinical environment, as well as the relevance and aims of diagnostics and treatment of gas embolism. The review starts with a few historical observations and

  13. Silent Discharge Plasma Technology for the Treatment of Air Toxics and Other Applications

    Energy Technology Data Exchange (ETDEWEB)

    Rosocha, Louis A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Chase, Peter J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gross, Michael P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    1998-09-21

    Under this CRADA, the Los Alamos National Laboratory (LANL) and High Mesa Technologies, Inc. (HMT) carried out a joint project on the development of the silent discharge plasma (SDP) technology for the treatment of hazardous air pollutants and other hazardous or toxic chemicals. The project had two major components: a technology-demonstration part and a scale-up and commercialization part. In the first part, a small-scale, mobile SDP plasma processor, which was being developed under a CRADA with the Electric Power Research Institute (EPRI) was the mobile equipment was modified for higher capacity service and employed for an innovative remediation technologies demonstration on soil-vapor extraction off-gases at the McClellan Air Force Base near Sacramento, CA. The performance of the SDP system for the variety of volatile organic compounds (VOCs) encountered at the McClellan site was sufficiently promising to the project HMT and LANL worked together to formulate a scale-up strategy and commercialization/manufacturing plan, and to design a prototype scaled-up SDP unit. HMT and LANL are now in the final stages of completing a licensing agreement for the technology and HMT is in the process of raising funds to engineer and manufacture commercial prototype SDP equipment focused on stack-gas emissions control and environmental remediation. HMT, in collaboration with another Northern New Mexico business, Coyote Aerospace, has also been successful in receiving a Phase I Small Business Innovative Research (SBIR) award from the Army Research Office to develop, design, and construct a small non-thermal plasma reactor for laboratory studies ("Non-Thermal Plasma Reactor for Control of Fugitive Emissions of Toxic Gases")

  14. Gas situation in the world; Sekai no gas jijo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-04-10

    The Chinese Government intends to totally prohibit the combustion of coal as is in 2000 onward to deal with environmental problems. To attain the coal, however, it will have to develop technologies for high-efficiency coal utilization, coal pulverization for power generation, and power generation not dependent on coal. Qatar and India signed a letter confirming their intention to enhance cooperation in the oil and gas sectors. It is predicted that natural gas consumption in the United States will renew its maximum record in 1998. In the last half of this year, Venezuela will open its natural gas distribution and transportation sectors to foreign investors. Itohchu Oil Exploration Co., Ltd., operated by Itohchu Corporation for natural resources exploration, won the first success in a foreign capital-led trial drilling in the Caspian Sea off Azerbaijan. Six U.S. corporations plan to participitate in a project of constructing an LNG receiving base and distribution network in Lebanon. Norway is making efforts to increase its sale of gas to the British market despite there are great quantities of inexpensive gas in Britain. Britain will put off the complete liberalization of electric retailing scheduled to be effectuated in April this year until September. The investment in the oil and gas upstream sectors across the world in 1997 is found to be two times larger than that of 1990

  15. Gas hydrate dissociation off Svalbard induced by isostatic rebound rather than global warming.

    Science.gov (United States)

    Wallmann, Klaus; Riedel, M; Hong, W L; Patton, H; Hubbard, A; Pape, T; Hsu, C W; Schmidt, C; Johnson, J E; Torres, M E; Andreassen, K; Berndt, C; Bohrmann, G

    2018-01-08

    Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Here we show that sediment cores drilled off Prins Karls Foreland contain freshwater from dissociating hydrates. However, our modeling indicates that the observed pore water freshening began around 8 ka BP when the rate of isostatic uplift outpaced eustatic sea-level rise. The resultant local shallowing and lowering of hydrostatic pressure forced gas hydrate dissociation and dissolved chloride depletions consistent with our geochemical analysis. Hence, we propose that hydrate dissociation was triggered by postglacial isostatic rebound rather than anthropogenic warming. Furthermore, we show that methane fluxes from dissociating hydrates were considerably smaller than present methane seepage rates implying that gas hydrates were not a major source of methane to the oceans, but rather acted as a dynamic seal, regulating methane release from deep geological reservoirs.

  16. Realization of Timed Reliable Communication over Off-The-Shelf Wireless Technologies

    DEFF Research Database (Denmark)

    Malinowsky, B.; Groenbaek, Jesper; Schwefel, Hans-Peter

    2013-01-01

    Industrial and safety-critical applications pose strict requirements for timeliness and reliability for the communication solution. Thereby the use of off-the-shelf (OTS) wireless communication technologies can be attractive to achieve low cost and easy deployment. This paper presents and analyse...

  17. Commercial application of titania-supported hydrodesulfurization catalysts in the production of hydrogen using full-range FCC off-gas

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Shaohu [SINOPEC Wuhan Branch, Qingshan, Wuhan 430082 (China); Shen, Binglong; Qu, Lianglong [Beijing Haishunde Titanium Catalyst Co. Ltd., A-1 North East-Ring Road, Beijing Economic-Technological Development Area, Beijing 100176 (China)

    2004-11-24

    This paper provides an alternative for low-cost feed used for on-purpose hydrogen production. Full-range FCC off-gas was applied to steam-reforming process as feed after treating with hydrogenation and hydrodesulfurization catalysts. Commercial run results were reported with novel TiO{sub 2}-supported Mo-based catalysts, T205A-1 and T205. The processes of catalysts loading, sulfidation, start-up and long-term run were described in details. Long-term run showed that TiO{sub 2}-supported Mo catalysts have good low-temperature hydrogenation activity, excellent HDS activity, and outstanding stability. Use of FCC off-gas as feed for hydrogen production is quite promising and will increase margins for refiners today.

  18. The need for a change in the paradigm of entrepreneurship at universities: differences between innovative spin-offs and technology-based spin-offs

    Directory of Open Access Journals (Sweden)

    Enara Zarrabeitia

    2016-05-01

    Full Text Available This study seeks to analyse the main characteristics of and barriers to the growth and development of innovative university spin-offs (which originate mainly from the fields of social science and law and technology-based university spin-offs (which tend to originate from the experimental sciences, from technical studies and from health science. The idea is to examine whether there is a need to redirect university policies aimed in the field of entrepreneurship. The study is based on a sample of 40 university spin-offs originating from the University of the Basque Country (UPV/EHU. A questionnaire was sent to entrepreneurs identified with the aid of the persons in charge of the university programmes for creating businesses at the UPV/EHU. To determine the main differences between innovative and technology-based spin-offs, once the replies were received a bivariate or contingent analysis was applied to characterise the two types of business. The main barriers to growth and development encountered by the two types were then identified. The data analysed reveal significant differences between the two types of business, and a need for a change in the paradigm of university entrepreneurship.

  19. International perspective on energy recovery from landfill gas. A joint report of the IEA Bioenergy Programme and the IEA CADDET Renewable Energy Technologies Programme

    International Nuclear Information System (INIS)

    2000-02-01

    This report presents a review of the current status of energy recovery from landfill gas. Utilisation, collection and treatment technologies are examined, and ten case studies of landfill gas utilisation are given. Non-technical issues such as barrier to energy recovery from landfill gas, landfill gas generation, and landfill gas emissions are addressed, and recommendations are outlined. The potential market for landfill gas, and market opportunities are considered. Details of the objectives of the International Energy Agency (IEA), the IEA Bioenergy Programme, and the IEA CADDET Renewable Energy Technologies Programme are included in appendices. (UK)

  20. Gas Permeability Evolution Mechanism and Comprehensive Gas Drainage Technology for Thin Coal Seam Mining

    Directory of Open Access Journals (Sweden)

    Fangtian Wang

    2017-09-01

    Full Text Available A thin coal seam mined as a protective coal seam above a gas outburst coal seam plays a central role in decreasing the degree of stress placed on a protected seam, thus increasing gas permeability levels and desorption capacities to dramatically eliminate gas outburst risk for the protected seam. However, when multiple layers of coal seams are present, stress-relieved gas from adjacent coal seams can cause a gas explosion. Thus, the post-drainage of gas from fractured and de-stressed strata should be applied. Comprehensive studies of gas permeability evolution mechanisms and gas seepage rules of protected seams close to protective seams that occur during protective seam mining must be carried out. Based on the case of the LongWall (LW 23209 working face in the Hancheng coal mine, Shaanxi Province, this paper presents a seepage model developed through the FLAC3D software program (version 5.0, Itasca Consulting Group, Inc., Minneapolis, MI, USA from which gas flow characteristics can be reflected by changes in rock mass permeability. A method involving theoretical analysis and numerical simulation was used to analyze stress relief and gas permeability evolution mechanisms present during broken rock mass compaction in a goaf. This process occurs over a reasonable amount of extraction time and in appropriate locations for comprehensive gas extraction technologies. In using this comprehensive gas drainage technological tool, the safe and efficient co-extraction of thin coal seams and gas resources can be realized, thus creating a favorable environment for the safe mining of coal and gas outburst seams.

  1. Role of technology in future gas supply and demand

    International Nuclear Information System (INIS)

    Ban, S.D.

    1992-01-01

    This paper presents an outlook for natural gas production and consumption in the United States for the next 15 to 20 years. It discusses the impact of the new environmental laws and regulations on gas exploration and development, showing a marked decline in new resource development. The paper goes on to discuss new developments in technology which will be required to increase the efficiency of natural gas-fired systems to meet the decline in production, increased costs, and environmental restraints. The paper breaks these technology issues down into the transportation sector, the residential sector, the commercial sector, and the industry sector. The types of technology and systems needed to meet these new regulatory requirements while maintaining a cost-effective system is discussed under each sectorial analysis

  2. Gas Sorption, Diffusion and Permeation in a Polymer of Intrinsic Microporosity (PIM-7)

    KAUST Repository

    Alaslai, Nasser Y.

    2013-01-01

    consumption. Membrane technology is a relatively new separation process for natural gas purification with large growth potential, specifically for off-shore applications. The economics of any membrane separation process depend primarily on the intrinsic gas

  3. VOCs in Arid soils: Technology summary

    International Nuclear Information System (INIS)

    1994-02-01

    The Volatile Organic Compounds In Arid Soils Integrated Demonstration (VOC-Arid ID) focuses on technologies to clean up volatile organic compounds and associated contaminants in soil and groundwater at arid sites. The initial host site is the 200 West Area at DOE's Hanford site in southeastern Washington state. The primary VOC contaminant is carbon tetrachloride, in association with heavy metals and radionuclides. An estimated 580--920 metric tons of carbon tetrachloride were disposed of between 1955 and 1973, resulting in extensive soil and groundwater contamination. The VOC-Arid ID schedule has been divided into three phases of implementation. The phased approach provides for: rapid transfer of technologies to the Environmental Restoration (EM-40) programs once demonstrated; logical progression in the complexity of demonstrations based on improved understanding of the VOC problem; and leveraging of the host site EM-40 activities to reduce the overall cost of the demonstrations. During FY92 and FY93, the primary technology demonstrations within the ID were leveraged with an ongoing expedited response action at the Hanford 200 West Area, which is directed at vapor extraction of VOCs from the vadose (unsaturated) zone. Demonstration efforts are underway in the areas of subsurface characterization including: drilling and access improvements, off-gas and borehole monitoring of vadose zone VOC concentrations to aid in soil vapor extraction performance evaluation, and treatment of VOC-contaminated off-gas. These current demonstration efforts constitute Phase 1 of the ID and, because of the ongoing vadose zone ERA, can result in immediate transfer of successful technologies to EM-40

  4. Gas to fuel and chemicals: from technology to market

    International Nuclear Information System (INIS)

    2003-01-01

    The commercialization of natural gas reserves via synthesis to liquid products is a particularly active area of research which could permit this energy carrier to penetrate new markets. This study provides a global perspective of developments in this area, the technology and its economic and environmental implications, completed by a full review of current projects. A number of research centres as well as engineering companies and oil and gas companies are engaged in significant research programmes to improve the processes employed in the gas to liquids chain. This section provides a complete picture of the recent technology developments and the areas for potential future improvement.The research activities of each organisation and the process scheme employed are described.The implications of the major differences in the technologies are reviewed. Each step in the GTL chain-feed preparation, syngas production, the Fischer-Tropsch process and product work up is covered. The relationship between the products from the process and the technology employed is discussed. Aside from the technological aspects, the economics of the GTL process remains the major hurdle to be overcome if this technology is to be more widely utilized.The key parameters affecting the economics of GTL developments are the cost of natural gas, capital investments and the impact of economies of scale.The key driver for the oil and gas companies is to provide a way of commercializing natural gas reserves when other means, such as pipeline transportation or LNG, are not viable. This section provides a review of the costs and economics of the GTL chain taking into account the process configuration and resulting capital costs, the products produced, the effect of scale and other relevant factors.The aim is to provide an understanding of the economic factors affecting the GTL chain. Middle distillate fuels produced from the GTL process are sulphur and aromatics free and will be attractive for use in the

  5. Industrial plant for electron beam flue gas treatment

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Iller, E.; Tyminnski, B.; Zimek, Z; Ostapczuk, A.; Licki, J.

    2001-01-01

    The electron beam flue gas treatment technology was invented many years ago. Research on the process has been carried out in Japan, USA, Germany and Poland. However, the recent fidings, based on the experiments performed at pilot plant at Electric Power Station Kaweczyn, led to developments which made process mature just at the dawn of the XXI century. The process is being implemented in the full industrial scale at Electric Power Station Pomorzany (Dolna Odra EPS Group). Other developments are reported in Japan and after Nagoya's pilot plant experiments, an industrial plant has been built in China and another one is constructed in Japan. There are remarkable differences in technological and design solutions applied in all these installations. Developments achieved at EPS Kaweczyn pilot plant and INCT laboratory unit were the basis for the project realized at EPS Pomorzan

  6. Aerosol and iodine removal system for the dissolver off-gas in a large fuel reprocessing plant

    International Nuclear Information System (INIS)

    Furrer, J.; Wilhelm, J.G.; Jannakos, K.

    1979-01-01

    A newly developed filter combination for the dissolver off-gas in a reprocessing plant with a throughput of 1400 t/y of heavy metal is presented and single filter components are described. The design principle chosen provides for remote handling and direct disposal in waste drums of 200 l volume. The optimization of housings and filter units is studied on true scale components in the simulated dissolver off-gas of a test facility named PASSAT. This facility will be described. PASSAT will be also used for final testing of the SORPTEX process which is under development. Its concept is included in the paper. The design and function of the new multiway sorption filter providing for complete loading of the iodine sorption material and maintaining continuously high decontamznation factors will also be given. Removal efficiencies measured for aerosols and iodine in an existing reprocessing plant are indicated

  7. Shale gas technology innovation rate impact on economic Base Case – Scenario model benchmarks

    International Nuclear Information System (INIS)

    Weijermars, Ruud

    2015-01-01

    Highlights: • Cash flow models control which technology is affordable in emerging shale gas plays. • Impact of technology innovation on IRR can be as important as wellhead price hikes. • Cash flow models are useful for technology decisions that make shale gas plays economic. • The economic gap can be closed by appropriate technology innovation. - Abstract: Low gas wellhead prices in North America have put its shale gas industry under high competitive pressure. Rapid technology innovation can help companies to improve the economic performance of shale gas fields. Cash flow models are paramount for setting effective production and technology innovation targets to achieve positive returns on investment in all global shale gas plays. Future cash flow of a well (or cluster of wells) may either improve further or deteriorate, depending on: (1) the regional volatility in gas prices at the wellhead – which must pay for the gas resource extraction, and (2) the cost and effectiveness of the well technology used. Gas price is an externality and cannot be controlled by individual companies, but well technology cost can be reduced while improving production output. We assume two plausible scenarios for well technology innovation and model the return on investment while checking against sensitivity to gas price volatility. It appears well technology innovation – if paced fast enough – can fully redeem the negative impact of gas price decline on shale well profits, and the required rates are quantified in our sensitivity analysis

  8. Decommissioning Combustible Waste Treatment using Oxygen-Enriched Incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Min, Byungyoun; Lee, Yoonji; Yun, Gyoungsu; Lee, Kiwon; Moon, Jeikwon [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-05-15

    The aim of the paper is current status of treatment for the decommissioning combustible waste in KAERI and for the purpose of the volume reduction and clearance for decommissioning combustible wastes generated by the decommissioning projects. The incineration technology has been selected for the treatment of combustible wastes. About 34 tons of decommissioning combustible waste has been treated using Oxygen Enriched incineration. Temperature, pressure of major components, stack gas concentration, i. e., SOx, NOx, CO, CO{sub 2} and HCl, and the residual oxygen were measured. Measured major parameters during normal operation were sustained on a stable status within a criteria operation condition. Oxygen enriched air, 22vol. % (dry basis) was used for stable incineration. The volume reduction ratio has achieved about 1/117. The incineration with decommissioning radioactive combustible waste is possible with moderate oxygen enrichment of 22 vol.% (dry basis) into the supply air. The incineration facility operated quite smoothly through the analysis major critical parameters of off-gas. The pressure, off-gas flow and temperature of major components remained constant within the range specified. The measures gases and particulate materials in stack were considerably below the regulatory limits. The achieved volume reduction ratio through incineration is about 1/117.

  9. Micro-gas turbine performance optimization by off-design characteristics prediction

    Energy Technology Data Exchange (ETDEWEB)

    Asgari, M.B.; Pahlevanzadeh, H. [Power and Water University of Technology, Tehran (Iran, Islamic Republic of). Dept. of Mechanical Engineering

    2005-07-01

    Micro-gas turbines are increasingly seen as a good option for supplying distributed electric or combined heat and power (CHP) systems. Micro turbines operate on the same thermodynamic cycle as the Brayton cycle. Fresh air enters a compressor and air pressure increases isentropically and high-pressure air and fuel are mixed and burnt in the combustion chamber at constant pressure. During this process the flue gas expands to lower pressure and increase volume isentropically. In this study a model was developed using parameters obtained from the compressor and turbine. Ambient temperature and and pressure effects on micro-gas turbines were examined. Customer requirements were used as constraints on micro-gas turbine parameters. The computer software Matlab was used to study the effect of the surge margin on the behaviour of the engine. Optimum performance speeds were presented, and a marginal envelope was obtained at the optimal speed. Issues concerning fuel consumption, power output, and efficiency were considered. The principal results of the simulation presented an optimum region of operation rather than any single optimal point. It was suggested that further research is needed to study the influence of the heat exchanger on efficiency and development of a model of the power electronics so that the complete system can be simulated from power generation. It was noted that although operation of microturbines at high speeds of revolution causes more net power output, this affects the thermal efficiency of the system and fuel consumption is high. It was concluded that optimum operating conditions should be evaluated by satisfying the trade off between net power generated and fuel consumption, as well as the achievable efficiency. 8 refs., 12 figs.

  10. Off Grid Photovoltaic Wastewater Treatment and Management Lagoons

    Science.gov (United States)

    LaPlace, Lucas A.; Moody, Bridget D.

    2015-01-01

    The SSC wastewater treatment system is comprised of key components that require a constant source of electrical power or diesel fuel to effectively treat the wastewater. In alignment with the President's new Executive Order 13653, Planning for Federal Sustainability in the Next Decade, this project aims to transform the wastewater treatment system into a zero emissions operation by incorporating the advantages of an off grid, photovoltaic system. Feasibility of implementation will be based on an analytical evaluation of electrical data, fuel consumption, and site observations.

  11. Utilization of Common Automotive Three-Way NO{sub x} Reduction Catalyst for Managing Off- Gas from Thermal Treatment of High-Nitrate Waste - 13094

    Energy Technology Data Exchange (ETDEWEB)

    Foster, Adam L.; Ki Song, P.E. [Studsvik, Inc. 5605 Glenridge Drive Suite 705, Atlanta, GA 30342 (United States)

    2013-07-01

    Studsvik's Thermal Organic Reduction (THOR) steam reforming process has been tested and proven to effectively treat radioactive and hazardous wastes streams with high nitrate contents to produce dry, stable mineral products, while providing high conversion (>98%) of nitrates and nitrites directly to nitrogen gas. However, increased NO{sub x} reduction may be desired for some waste streams under certain regulatory frameworks. In order to enhance the NO{sub x} reduction performance of the THOR process, a common Three-Way catalytic NO{sub x} reduction unit was installed in the process gas piping of a recently completed Engineering Scale Technology Demonstration (ESTD). The catalytic DeNO{sub x} unit was located downstream of the main THOR process vessel, and it was designed to catalyze the reduction of residual NO{sub x} to nitrogen gas via the oxidation of the hydrogen, carbon monoxide, and volatile organic compounds that are inherent to the THOR process gas. There was no need for auxiliary injection of a reducing gas, such as ammonia. The unit consisted of four monolith type catalyst sections positioned in series with a gas mixing section located between each catalyst section. The process gas was monitored for NO{sub x} concentration upstream and downstream of the catalytic DeNO{sub x} unit. Conversion efficiencies ranged from 91% to 97% across the catalytic unit, depending on the composition of the inlet gas. Higher concentrations of hydrogen and carbon monoxide in the THOR process gas increased the NO{sub x} reduction capability of the catalytic DeNO{sub x} unit. The NO{sub x} destruction performance of THOR process in combination with the Three-Way catalytic unit resulted in overall system NO{sub x} reduction efficiencies of greater than 99.9% with an average NO{sub x} reduction efficiency of 99.94% for the entire demonstration program. This allowed the NO{sub x} concentration in the ESTD exhaust gas to be maintained at less than 40 parts per million (ppm

  12. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology

  13. Off-diagonal long-range order, cycle probabilities, and condensate fraction in the ideal Bose gas.

    Science.gov (United States)

    Chevallier, Maguelonne; Krauth, Werner

    2007-11-01

    We discuss the relationship between the cycle probabilities in the path-integral representation of the ideal Bose gas, off-diagonal long-range order, and Bose-Einstein condensation. Starting from the Landsberg recursion relation for the canonic partition function, we use elementary considerations to show that in a box of size L3 the sum of the cycle probabilities of length k>L2 equals the off-diagonal long-range order parameter in the thermodynamic limit. For arbitrary systems of ideal bosons, the integer derivative of the cycle probabilities is related to the probability of condensing k bosons. We use this relation to derive the precise form of the pik in the thermodynamic limit. We also determine the function pik for arbitrary systems. Furthermore, we use the cycle probabilities to compute the probability distribution of the maximum-length cycles both at T=0, where the ideal Bose gas reduces to the study of random permutations, and at finite temperature. We close with comments on the cycle probabilities in interacting Bose gases.

  14. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    1999-01-01

    The U.S. Department of Energy (DOE), Federal Energy Technology Center (FETC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2) TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2) TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown below: Sulfidation: Zn(sub 2) TiO(sub 4)+ 2H(sub 2)S(yields) 2ZnS+ TiO(sub 2)+ 2H(sub 2)O; Regeneration: 2ZnS+ TiO(sub 2)+ 3O(sub 2)(yields) Zn(sub 2) TiO(sub 4)+ 2SO(sub 2) The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  15. Study on Off-Design Steady State Performances of Helium Gas Turbo-compressor for HTGR-GT

    International Nuclear Information System (INIS)

    Qisen Ren; Xiaoyong Yang; Zhiyong Huang; Jie Wang

    2006-01-01

    The high temperature gas-cooled reactor (HTGR) coupled with direct gas turbine cycle is a promising concept in the future of nuclear power development. Both helium gas turbine and compressor are key components in the cycle. Under normal conditions, the mode of power adjustment is to control total helium mass in the primary loop using gas storage vessels. Meanwhile, thermal power of reactor core is regulated. This article analyzes off-design performances of helium gas turbine and compressors for high temperature gas-cooled reactor with gas turbine cycle (HTGR-GT) at steady state level of electric power adjustment. Moreover, performances of the cycle were simply discussed. Results show that the expansion ratio of turbine decreases as electric power reduces but the compression ratios of compressors increase, efficiencies of both turbine and compressors decrease to some extent. Thermal power does not vary consistently with electric power, the difference between these two powers increases as electric power reduces. As a result of much thermal energy dissipated in the temperature modulator set at core inlet, thermal efficiency of the cycle has a widely reduction under partial load conditions. (authors)

  16. Numerical modeling of plasma plume evolution against ambient background gas in laser blow off experiments

    International Nuclear Information System (INIS)

    Patel, Bhavesh G.; Das, Amita; Kaw, Predhiman; Singh, Rajesh; Kumar, Ajai

    2012-01-01

    Two dimensional numerical modelling based on simplified hydrodynamic evolution for an expanding plasma plume (created by laser blow off) against an ambient background gas has been carried out. A comparison with experimental observations shows that these simulations capture most features of the plasma plume expansion. The plume location and other gross features are reproduced as per the experimental observation in quantitative detail. The plume shape evolution and its dependence on the ambient background gas are in good qualitative agreement with the experiment. This suggests that a simplified hydrodynamic expansion model is adequate for the description of plasma plume expansion.

  17. New challenges in gas

    Energy Technology Data Exchange (ETDEWEB)

    Mandil, C. [Institut Francais du Petrole (IFP), 92 - Rueil-Malmaison (France); Chabrelie, M.F. [Cedigaz, 92 - Rueil Malmaison (France); Streicher, C. [Prosernat, 92 - Paris la Defense (France)] [and others

    2003-07-01

    New developments in the area of gas treatment will be to a large extent driven by the need to find appropriate solutions to the fundamental need of sustainable development. New gas treatment processes are developed with the aim to minimise contaminant emissions and meet most stringent environmental specifications. A new major challenge for the industry will be to implement new cost effective technologies for reducing CO{sub 2} emissions. Industry has also to minimise its costs, and therefore, in order to ensure at the same time a better protection of the environment and a better safety, it is necessary to innovate. The purpose of this seminar is precisely to identify better the innovations which are required in the area of gas treatment. These proceedings comprise 8 papers and a summary of the contributions to a round-table discussion dealing with the options for CO{sub 2} capture and sequestration. The presentations treat of: the future prospects for the gas industry (M.F. Chabrelie, Cedigaz); the solutions for offshore gas treatment (C. Streicher, Prosernat); gas treatment with membranes (H. Meyer, GTI); the Axens Multibed{sub TM} technology for natural gas treatment (G. Jochem, Axens); the potentials and applications for the Propure co-current contactors (F.P. Nilsen, ProPure); the production of very-sour and super-sour large gas reserves: the new challenges (F. Lallemand, TotalFinaElf); Hybrisol, a new gas treatment process for sour natural gases (F. Lecomte, IFP); and the conception and building of large acid-gas removal units (J. Castel, Technip-Coflexip). (J.S.)

  18. Bench-Scale Demonstration of Hot-Gas Desulfurization Technology

    International Nuclear Information System (INIS)

    Portzer, Jeffrey W.; Gangwal, Santosh K.

    1997-01-01

    Prior to the current project, development of the DSRP was done in a laboratory setting, using synthetic gas mixtures to simulate the regeneration off-gas and coal gas feeds. The objective of the current work is to further the development of zinc titanate fluidized-bed desulfurization (ZTFBD) and the DSRP for hot-gas cleanup by testing with actual coal gas. The objectives of this project are to: (1) Develop and test an integrated, skid-mounted, bench-scale ZTFBD/DSRP reactor system with a slipstream of actual coal gas; (2) Test the bench-scale DSRP over an extended period with a slipstream of actual coal gas to quantify the degradation in performance, if any, caused by the trace contaminants present in coal gas (including heavy metals, chlorides, fluorides, and ammonia); (3) Expose the DSRP catalyst to actual coal gas for extended periods and then test its activity in a laboratory reactor to quantify the degradation in performance, if any, caused by static exposure to the trace contaminants in coal gas; (4) Design and fabricate a six-fold larger-scale DSRP reactor system for future slipstream testing; (5) Further develop the fluidized-bed DSRP to handle high concentrations (up to 14 percent) of SO 2 that are likely to be encountered when pure air is used for regeneration of desulfurization sorbents; and (6) Conduct extended field testing of the 6X DSRP reactor with actual coal gas and high concentrations of SO 2 . The accomplishment of the first three objectives--testing the DSRP with actual coal gas, integration with hot-gas desulfurization, and catalyst exposure testing--was described previously (Portzer and Gangwal, 1994, 1995; Portzer et al., 1996). This paper summarizes the results of previous work and describes the current activities and plans to accomplish the remaining objectives

  19. MOCVD waste gas treatment

    International Nuclear Information System (INIS)

    Geelen, A. van; Bink, P.H.M.; Giling, L.J.

    1993-01-01

    A large scale production of GaAs based solar cells with MOCVD will give rise to a considerable use of arsine. Therefore a gas treatment system is needed to convert the waste gases into less toxic compounds. In this study seven different gas treatment systems for MOCVD are compared by quantifying the environmental aspects. The systems are divided in wet systems, adsorption systems and thermal systems. The smallest amount of waste is produced by adsorption and thermal systems. Adsorption systems use the smallest amount of energy. The amount of primary materials used for the equipment varies per system. All systems are safe, but adsorption systems are simplest. At the moment, adsorption systems are probably the best choice from an environmental point of view. Nevertheless thermal systems have some potential advantages which make them interesting for the future

  20. Northern gas fields and NGH technology. A feasibility study to develop natural gas hydrate technology for the international gas markets; Nordlige gassfelt and NGH-teknologi. En studie av muligheter for utvikling av naturgasshydratteknologi for det internasjonale gassmarked

    Energy Technology Data Exchange (ETDEWEB)

    Ramsland, Trond Ragnvald; Loy, Erik F.; Doesen, Sturle

    1997-12-31

    Two natural gas fields have been studied for three different technological solutions using two different economic theories. The aim was to examine whether a new technology for transporting natural gas, Natural Gas Hydrates (NGH), can compete with the existing technologies pipeline and Liquefied Natural Gas (LNG). Natural gas can rarely be used immediately after production and the supply systems can be divided into four interrelated parts: 1) Exploration. 2) Development and production. 3) Transportation. 4) Distribution. The emphasis in the study is on production costs and transportation. Exploration is assumed carried out and thus viewed sunk cost. Distribution from landing point to consumers is not part of the study. Production can take place either onshore or offshore, the natural gas can be transported to the market either by pipeline or ship and the costs are becoming more important as the distance from the fields to the markets increase. Natural gas projects have long lead times and large capital requirements. New supplies will materialise then if there is confidence that demand for the gas exists at a profitable price. Therefore natural gas is generally sold on long term contracts. The conclusions are that economies of scale exist and that pipeline is the superior technology for high volumes but cannot compete for smaller volumes where the LNG technology has been the best alternative. However, the report concludes that the NGH can compete fully. The distance to the market where the natural gas is to be transported is crucial for choice of transportation mode. The shipping modes are superior for long transportation distances. NGH is superior to LNG also with regards to distance. Despite that the two economic models used for the evaluation have provided very different absolute project values, they have provided the same conclusions about the ranking of the different technologies. It is clear then that if NGH technology is developed further into a reliable and

  1. TO APPLICATION OF BIO-GAS UNITS: ORGANIZATIONAL AND TECHNOLOGICAL MODEL

    Directory of Open Access Journals (Sweden)

    Thuy Nga Nguyen

    2011-01-01

    Full Text Available Analysis of the published papers written by national and foreign researchers reveals that an increasing global energy deficit, exhaustion of  fossil organic and nuclear fuels, chemical and radio-active contamination of the environment are main reasons in favour of  thorough investigation  and wide introduction of non-conventional and renewable energy sources. Nowadays Vietnamese Institute of Energy Science has been developing the state-of-the-art bio-gas technologies on the  basis of application and modernization of Chinese and Dutch family-style technologies. The most rational technologies are combined ones which operate using various types of energy raw materials, for example, solar and bio-gas energy because usage of solar energy expands operational possibilities of the bio-gas system, ensures its operation within wide temperature range creating necessary parameters for the required technological task.

  2. Peer review panel summary report for technical determination of mixed waste incineration off-gas systems for Rocky Flats

    International Nuclear Information System (INIS)

    1992-01-01

    A Peer Review Panel was convened on September 15-17, 1992 in Boulder, Co. The members of this panel included representatives from DOE, EPA, and DOE contractors along with invited experts in the fields of air pollution control and waste incineration. The primary purpose of this review panel was to make a technical determination of a hold, test and release off gas capture system should be implemented in the proposed RF Pland mixed waste incineration system; or if a state of the art continuous air pollution control and monitoring system should be utilized as the sole off-gas control system. All of the evaluations by the panel were based upon the use of the fluidized bed unit proposed by Rocky Flats and cannot be generalized to other systems

  3. Off reactor testings. Technological engineering applicative research

    International Nuclear Information System (INIS)

    Doca, Cezar

    2001-01-01

    By the end of year 2000 over 400 nuclear electro-power units were operating world wide, summing up a 350,000 MW total capacity, with a total production of 2,300 TWh, representing 16% of the world's electricity production. Other 36 units, totalizing 28,000 MW, were in construction, while a manifest orientation towards nuclear power development was observed in principal Asian countries like China, India, Japan and Korea. In the same world's trend one find also Romania, the Cernavoda NPP Unit 1 generating electrical energy into the national system beginning with 2 December 1996. Recently, the commercial contract was completed for finishing the Cernavoda NPP Unit 2 and launching it into operation by the end of year 2004. An important role in developing the activity of research and technological engineering, as technical support for manufacturing the CANDU type nuclear fuel and supplying with equipment the Cernavoda units, was played by the Division 7 TAR of the INR Pitesti. Qualification testings were conducted for: - off-reactor CANDU type nuclear fuel; - FARE tools, pressure regulators, explosion proof panels; channel shutting, as well as functional testing for spare pushing facility as a first step in the frame of the qualification tests for the charging/discharging machine (MID) 4 and 5 endings. Testing facilities are described, as well as high pressure hot/cool loops, measuring chains, all of them fulfilling the requirements of quality assurance. The nuclear fuel off-reactor tests were carried out to determine: strength; endurance; impact, pressure fall and wear resistance. For Cernavoda NPP equipment testings were carried out for: the explosion proof panels, pressure regulators, behaviour to vibration and wear of the steam generation tubings, effects of vibration upon different electronic component, channel shutting (for Cernavoda Unit 2), MID operating at 300 and 500 cycles. A number of R and D programs were conducted in the frame of division 7 TAR of INR

  4. Carbon recovery by fermentation of CO-rich off gases - Turning steel mills into biorefineries.

    Science.gov (United States)

    Molitor, Bastian; Richter, Hanno; Martin, Michael E; Jensen, Rasmus O; Juminaga, Alex; Mihalcea, Christophe; Angenent, Largus T

    2016-09-01

    Technological solutions to reduce greenhouse gas (GHG) emissions from anthropogenic sources are required. Heavy industrial processes, such as steel making, contribute considerably to GHG emissions. Fermentation of carbon monoxide (CO)-rich off gases with wild-type acetogenic bacteria can be used to produce ethanol, acetate, and 2,3-butanediol, thereby, reducing the carbon footprint of heavy industries. Here, the processes for the production of ethanol from CO-rich off gases are discussed and a perspective on further routes towards an integrated biorefinery at a steel mill is given. Recent achievements in genetic engineering as well as integration of other biotechnology platforms to increase the product portfolio are summarized. Already, yields have been increased and the portfolio of products broadened. To develop a commercially viable process, however, the extraction from dilute product streams is a critical step and alternatives to distillation are discussed. Finally, another critical step is waste(water) treatment with the possibility to recover resources. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. The gas turbine: Present technology and future developments; La turbina a gas: Tecnologie attuali e gli sviluppi futuri

    Energy Technology Data Exchange (ETDEWEB)

    Minghetti, E [ENEA, Centro Ricerche Casaccia, Rome (Italy)

    1997-03-01

    The gas turbine is the most widely used prime mover all over the world for either power generation or mechanical drive applications. The above fact is due to the recent great improvements that have been done especially in terms of efficiency, availability and reliability. The future for gas turbine technological development looks very promising. In fact, although tremendous growth has already taken place, there is still the potential for dramatic improvements in performance. Compared with the competitive prime movers (conventional steam power plants and reciprocating piston engines) the gas turbine technology is younger and still following a strong growth curve. The coming decades will witness the continued increasing in turbine inlet temperature, the development of new materials and refrigeration systems and the commercialization of inter cooled system and steam cooled turbines. With the very soon introduction of the {sup G }and {sup H }technology, expected single and combined cycle efficiencies for heavy duty machines are respectively 40% and 60%, while maintaining single digit levels in pollutant emissions. In this report are given wide information on gas turbine present technology (Thermodynamics, features, design, performances, emission control, applications) and are discussed the main lines for the future developments. Finally are presented the research and technological development activities on gas turbine of Italian National Agency for new Technology Energy and the Environment Energy Department.

  6. Advanced technology for aero gas turbine components

    Energy Technology Data Exchange (ETDEWEB)

    1987-09-01

    The Symposium is aimed at highlighting the development of advanced components for new aero gas turbine propulsion systems in order to provide engineers and scientists with a forum to discuss recent progress in these technologies and to identify requirements for future research. Axial flow compressors, the operation of gas turbine engines in dust laden atmospheres, turbine engine design, blade cooling, unsteady gas flow through the stator and rotor of a turbomachine, gear systems for advanced turboprops, transonic blade design and the development of a plenum chamber burner system for an advanced VTOL engine are among the topics discussed.

  7. Gas To Liquids Technology: A Futuristic View

    Energy Technology Data Exchange (ETDEWEB)

    El Shamy, A A [Egyptian General Petroleum Corporation, Opr. Development Depart., P.O No. 11742, Cairo (Egypt); Zayed, A M [Egyptian General Petroleum Corporation, Quality Control Department, P.O No. 11742, Cairo (Egypt)

    2004-07-01

    Worldwide efforts aimed to the formulation of environment friendly diesel fuels able to meet the advanced fuel specifications of the 21 st century and able to meet the global demand on diesel fuels. Synthetically derived gas to-liquid (GTL) diesel fuel promises to meet these challenges and spearhead the way to the future. This technology will produce almost zero sulfur, high cetane, low aromatic diesel and naphtha which will be sold regionally and internationally. GTL fuel is cleaner than any conventional fuel which will help the environment. It can be used in conventional diesel engines to give reductions in emission levels. Construction of such technology will reduce the gap between production and consumption by maximizing the gross profitability of natural gas.

  8. Gas To Liquids Technology: A Futuristic View

    International Nuclear Information System (INIS)

    El Shamy, A.A; Zayed, A.M

    2004-01-01

    Worldwide efforts aimed to the formulation of environment friendly diesel fuels able to meet the advanced fuel specifications of the 21 st century and able to meet the global demand on diesel fuels. Synthetically derived gas to-liquid (GTL) diesel fuel promises to meet these challenges and spearhead the way to the future. This technology will produce almost zero sulfur, high cetane, low aromatic diesel and naphtha which will be sold regionally and internationally. GTL fuel is cleaner than any conventional fuel which will help the environment. It can be used in conventional diesel engines to give reductions in emission levels. Construction of such technology will reduce the gap between production and consumption by maximizing the gross profitability of natural gas

  9. Comparison of thermochemically calculated and measured dioxin contents in the off-gas of a sinter plant

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, P; Eriksson, G; Neuschuelz, D [Lehrstuhl fuer Theoretische Huettenkunde, Aachen (Germany)

    1998-12-31

    Polychlorinated dibenzo-p-dioxins and dibenzo-furans form a family of more than 200 compounds which are relatively stable in the biosphere and tend to accumulate in the human body. The tetra- to hexa-chlorinated dioxins and furans are considered highly toxic. To facilitate the assessment of the total toxicity of dioxin and furan mixtures, the estimated toxic effects of the individual compounds relative to the 2,3,7,8-tetrachloro-dibenzo-p-dioxin (TCDD) were introduced as Toxic Equivalent Factors which yield, when multiplied with the respective concentrations, the Toxic Equivalent (TE) of the mixture. Toxic dioxins and furans are unintentionally formed in a number of industrial combustion processes such as waste incineration and iron ore sintering, in the chemical industry and in household heating. To keep the emissions as low as possible, off-gas clearing systems for the collection of dioxins and furans are increasingly prescribed by the authorities. In addition, it appears desirable to select process conditions that are unfavourable for the formation of these compounds. A simulation of the relevant processes on the basis of thermodynamic data may be helpful in defining such process conditions. To simulate dioxin formation in the sintering process, all major gas-solid reactions taking place in the sinter bed must also be simulated. A sufficiently accurate reproduction of the off-gas compositions along the length of the sinter strand requires detailed assumptions concerning the relative amounts of `active` O{sub 2} as well as the distribution of reacting carbon and water over the strand length. From this basis, an equilibrium calculation for the gas/solid reactions at the sintering temperature of 1150 deg C and an equilibrium calculation restricted to the gas phase at 700 deg C produced values for the concentrations of the major off-gas constituents in very good agreement with the measured values. The further assumption that below 700 deg C all reactions are frozen

  10. Comparison of thermochemically calculated and measured dioxin contents in the off-gas of a sinter plant

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, P.; Eriksson, G.; Neuschuelz, D. [Lehrstuhl fuer Theoretische Huettenkunde, Aachen (Germany)

    1997-12-31

    Polychlorinated dibenzo-p-dioxins and dibenzo-furans form a family of more than 200 compounds which are relatively stable in the biosphere and tend to accumulate in the human body. The tetra- to hexa-chlorinated dioxins and furans are considered highly toxic. To facilitate the assessment of the total toxicity of dioxin and furan mixtures, the estimated toxic effects of the individual compounds relative to the 2,3,7,8-tetrachloro-dibenzo-p-dioxin (TCDD) were introduced as Toxic Equivalent Factors which yield, when multiplied with the respective concentrations, the Toxic Equivalent (TE) of the mixture. Toxic dioxins and furans are unintentionally formed in a number of industrial combustion processes such as waste incineration and iron ore sintering, in the chemical industry and in household heating. To keep the emissions as low as possible, off-gas clearing systems for the collection of dioxins and furans are increasingly prescribed by the authorities. In addition, it appears desirable to select process conditions that are unfavourable for the formation of these compounds. A simulation of the relevant processes on the basis of thermodynamic data may be helpful in defining such process conditions. To simulate dioxin formation in the sintering process, all major gas-solid reactions taking place in the sinter bed must also be simulated. A sufficiently accurate reproduction of the off-gas compositions along the length of the sinter strand requires detailed assumptions concerning the relative amounts of `active` O{sub 2} as well as the distribution of reacting carbon and water over the strand length. From this basis, an equilibrium calculation for the gas/solid reactions at the sintering temperature of 1150 deg C and an equilibrium calculation restricted to the gas phase at 700 deg C produced values for the concentrations of the major off-gas constituents in very good agreement with the measured values. The further assumption that below 700 deg C all reactions are frozen

  11. Future markets and technologies for natural gas vehicles; Futurs marches et technologies pour les vehicules au gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Allen, J. [Development Engineer, Lotus Engineering (United Kingdom); Carpenter, B. [Gas Applications, BG Technology (United Kingdom)

    2000-07-01

    Lotus Engineering and BG Technology recently collaborated on the conversion of the Lotus Elise for operation on natural gas. This paper considers the world-wide opportunities for natural gas as an automotive fuel by comparison with other fuels. It looks at how technology can be used to exploit this potential, by examining the special features of the gas fuelled Elise, and how other technologies such as hybrid vehicles and fuel cells can be expected to respond to this challenge in future. (authors)

  12. Eco-technology service station: the future of gas station; Posto eco-tecnologico: o posto do futuro

    Energy Technology Data Exchange (ETDEWEB)

    Moura, Newton R. [PETROBRAS, Rio de Janeiro, RJ (Brazil); Daher, Humberto Antonio S. [PETROBRAS Distribuidora, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    PETROBRAS Distribuidora and CENPES have a project to build an eco-technology service station at Ilha do Fundao, to know new technologies for vehicle fuelling, test of new vehicle natural gas compression system, and start projects with new fuels that are not available at Brazilian market. This service station concept shall be aligned with sustainability premise that are being established for both companies, that means, besides a technology focus, it shall have a social focus without any environment damage. PETROBRAS 'Board of Directors approved the expansion of PETROBRAS' Research and Development Center (CENPES) installations, including this service station construction. Some activities that will be developed at the service station are pointed out here: available of new natural gas compression system; micro-generation with micro turbine, fuel cell; and photo-voltaic cell technologies; hydrogen fuelling; oil-water system treatment; biodiesel fuelling. This station will have a show room opened to the public, with panels, videos and a CNG compressor in cut. (author)

  13. FMECA about pre-treatment system for purge gas of test blanket module in ITER

    International Nuclear Information System (INIS)

    Fu Wanfa; Luo Deli; Tang Tao

    2012-01-01

    The pre-treatment system for purge gas of TBM will be installed in Port Cell for installing TBM in ITER, the function of which includes filtering purge gas, removing HTO, cooling, and adjusting flow rate, etc. The purge gas treated will be conveyed into TES (Tritium Extraction System). The technological process and system components in pre-treatment system were introduced. Tritium releasing risk was regarded as failure criterion; failure mode, effects and criticality analysis (FMECA) were carried out and several weaknesses or failure mode in the system were found. Besides, risk priority number (RPN) and failure mode criticality were calculated. Finally, some design improvement measures and usage compensation measures were given. At last, four important potential failure modes were found out. The analysis will provide the design basis for reducing risk of excessive tritium releasing, which is also a useful assist for safety analysis about other tritium system. (authors)

  14. Electrospray-printed nanostructured graphene oxide gas sensors

    Science.gov (United States)

    Taylor, Anthony P.; Velásquez-García, Luis F.

    2015-12-01

    We report low-cost conductometric gas sensors that use an ultrathin film made of graphene oxide (GO) nanoflakes as transducing element. The devices were fabricated by lift-off metallization and near-room temperature, atmospheric pressure electrospray printing using a shadow mask. The sensors are sensitive to reactive gases at room temperature without requiring any post heat treatment, harsh chemical reduction, or doping with metal nanoparticles. The sensors’ response to humidity at atmospheric pressure tracks that of a commercial sensor, and is linear with changes in humidity in the 10%-60% relative humidity range while consuming recipes yielded nearly identical response characteristics, suggesting that intrinsic properties of the film control the sensing mechanism. The gas sensors successfully detected ammonia at concentrations down to 500 ppm (absolute partial pressure of ˜5 × 10-4 T) at ˜1 T pressure, room temperature conditions. The sensor technology can be used in a great variety of applications including air conditioning and sensing of reactive gas species in vacuum lines and abatement systems.

  15. GAS STORAGE TECHNOLOGY CONSORTIUM

    Energy Technology Data Exchange (ETDEWEB)

    Robert W. Watson

    2004-10-18

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with Phase 1B and encompasses the period July 1, 2004, through September 30, 2004. During this time period there were three main activities. First was the

  16. Analysis of Adsorbed Natural Gas Tank Technology

    Science.gov (United States)

    Knight, Ernest; Schultz, Conrad; Rash, Tyler; Dohnke, Elmar; Stalla, David; Gillespie, Andrew; Sweany, Mark; Seydel, Florian; Pfeifer, Peter

    With gasoline being an ever decreasing finite resource and with the desire to reduce humanity's carbon footprint, there has been an increasing focus on innovation of alternative fuel sources. Natural gas burns cleaner, is more abundant, and conforms to modern engines. However, storing compressed natural gas (CNG) requires large, heavy gas cylinders, which limits space and fuel efficiency. Adsorbed natural gas (ANG) technology allows for much greater fuel storage capacity and the ability to store the gas at a much lower pressure. Thus, ANG tanks are much more flexible in terms of their size, shape, and weight. Our ANG tank employs monolithic nanoporous activated carbon as its adsorbent material. Several different configurations of this Flat Panel Tank Assembly (FPTA) along with a Fuel Extraction System (FES) were examined to compare with the mass flow rate demands of an engine.

  17. Comparative analysis of monetizing technologies for the use of offshore natural gas; Analise comparativa das tecnologias embarcadas de aproveitamento de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Biruel Junior, Jose

    2008-09-15

    The growing world need for natural gas, the issue of offshore oil and associated gas exploration in regions constantly farther from the consumer market, and the law restrictions due to greenhouses gases emissions have stimulated the development of technologies intended to monetizing stranded gas reserves. In order to compare these technologies, a Multi Criteria Decision Analysis Methodology, based on fuzzy parameters, has been developed. The Methodology enables specialists to define analysis dimensions and criteria as well as to assign weight and ratings by means of linguistic variables, resulting in a general performance index for each technology. The Methodology has been applied in a case study to compare the floating technologies FCNG (Floating Compressed Natural Gas), FLNG (Floating Liquefied Natural Gas), FGTL (Floating Gas-to-Liquid) and FGTW (Floating Gas-to- Wire). The efficacy of the Methodology depends on the comprehensiveness and quality of the information provided. Therefore, this dissertation presents a study of these technologies, placing strong emphasis on the Technological Dimension. The Methodology allows for the identification of the drawbacks of each technology so as to especially conduct R and D efforts to improve their competitiveness. (author)

  18. Clean coal and heavy oil technologies for gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Todd, D.M. [GE Industrial & Power Systems, Schenectady, NY (United States)

    1994-12-31

    Global power generation markets have shown a steady penetration of GT/CC technology into oil and gas fired applications as the technology has matured. The lower cost, improved reliability and efficiency advantages of combined cycles can now be used to improve the cost of electricity and environmental acceptance of poor quality fuels such as coal, heavy oil, petroleum coke and waste products. Four different technologies have been proposed, including slagging combustors, Pressurized Fluidized Bed Combustion (PFBC), Externally Fired Combined Cycle (EFCC) and Integrated Gasification Combined Cycle (IGCC). Details of the technology for the three experimental technologies can be found in the appendix. IGCC is now a commercial technology. In the global marketplace, this shift is being demonstrated using various gasification technologies to produce a clean fuel for the combined cycle. Early plants in the 1980s demonstrated the technical/environmental features and suitability for power generation plants. Economics, however, were disappointing until the model F GT technologies were first used commercially in 1990. The economic break-through of matching F technology gas turbines with gasification was not apparent until 1993 when a number of projects were ordered for commercial operation in the mid-1990s. GE has started 10 new projects for operation before the year 2000. These applications utilize seven different gasification technologies to meet specific application needs. Early plants are utilizing low-cost fuels, such as heavy oil or petroleum coke, to provide economics in first-of-a-kind plants. Some special funding incentives have broadened the applications to include power-only coal plants. Next generation gas turbines projected for commercial applications after the year 2000 will contribute to another step change in technology. It is expected that the initial commercialization process will provide the basis for clear technology choices on future plants.

  19. Commercial LFCM vitrification technology. Quarterly progress report, October-December 1984

    Energy Technology Data Exchange (ETDEWEB)

    Burkholder, H.C.; Jarrett, J.H. (comps.)

    1985-07-01

    This report is the first in a series of quarterly reports compiled by the Nuclear Waste Treatment Program Office at Pacific Northwest Laboratory to document progress on commercial liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1985 is discussed: pretreatment systems, melting process chemistry, glass development and characterization, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, process/product modeling and control, and supporting studies. 33 figs., 12 tabs.

  20. An overview of aerospace gas turbine technology of relevance to the development of the automotive gas turbine engine

    Science.gov (United States)

    Evans, D. G.; Miller, T. J.

    1978-01-01

    The NASA-Lewis Research Center (LeRC) has conducted, and has sponsored with industry and universities, extensive research into many of the technology areas related to gas turbine propulsion systems. This aerospace-related technology has been developed at both the component and systems level, and may have significant potential for application to the automotive gas turbine engine. This paper summarizes this technology and lists the associated references. The technology areas are system steady-state and transient performance prediction techniques, compressor and turbine design and performance prediction programs and effects of geometry, combustor technology and advanced concepts, and ceramic coatings and materials technology.

  1. Evaluation of Mars CO2 Capture and Gas Separation Technologies

    Science.gov (United States)

    Muscatello, Anthony C.; Santiago-Maldonado, Edgardo; Gibson, Tracy; Devor, Robert; Captain, James

    2011-01-01

    Recent national policy statements have established that the ultimate destination of NASA's human exploration program is Mars. In Situ Resource Utilization (ISRU) is a key technology required to ,enable such missions and it is appropriate to review progress in this area and continue to advance the systems required to produce rocket propellant, oxygen, and other consumables on Mars using the carbon dioxide atmosphere and other potential resources. The Mars Atmospheric Capture and Gas separation project is selecting, developing, and demonstrating techniques to capture and purify Martian atmospheric gases for their utilization for the production of hydrocarbons, oxygen, and water in ISRU systems. Trace gases will be required to be separated from Martian atmospheric gases to provide pure CO2 to processing elements. In addition, other Martian gases, such as nitrogen and argon, occur in concentrations high enough to be useful as buffer gas and should be captured as well. To achieve these goals, highly efficient gas separation processes will be required. These gas separation techniques are also required across various areas within the ISRU project to support various consumable production processes. The development of innovative gas separation techniques will evaluate the current state-of-the-art for the gas separation required, with the objective to demonstrate and develop light-weight, low-power methods for gas separation. Gas separation requirements include, but are not limited to the selective separation of: (1) methane and water from unreacted carbon oxides (C02-CO) and hydrogen typical of a Sabatier-type process, (2) carbon oxides and water from unreacted hydrogen from a Reverse Water-Gas Shift process, (3)/carbon oxides from oxygen from a trash/waste processing reaction, and (4) helium from hydrogen or oxygen from a propellant scavenging process. Potential technologies for the separations include' freezers, selective membranes, selective solvents, polymeric sorbents

  2. Enrichment technology. Dependable vendor of gas centrifuges

    International Nuclear Information System (INIS)

    Anon.

    2011-01-01

    Enrichment Technology is an innovative, high-tech company that develops, manufactures and installs gas centrifuges for enriching uranium. In addition, Enrichment Technology designs enrichment plants that use gas centrifuge technology. This technology offers the most efficient and cost-effective method for enriching uranium yet: high-performance, safe technology that dominates the market with a global share of 45 percent. A determining factor in Enrichment Technology's success is its mission: supplying its customers with safe, reliable technology. Production of the centrifuges requires versatile know-how and collaboration between different departments as well as interdisciplinary teams at the various sites. More than 2000 operators at 8 sites in 5 countries contribute their individual knowledge and personal skills in order to produce this exceptional technology. The head office is in Beaconsfield near London and the operational headquarters are in Almelo in the Netherlands. There are other sites in Germany (Juelich und Gronau), Great Britain (Capenhurst) as well as project sites in the USA and France. Capenhurst is where experienced engineers design new enrichment plants and organise their construction. Centrifuge components are manufactured in Almelo and Juelich, while the pipework needed to connect up the centrifuges is produced at the site in Gronau. In Juelich, highly qualified scientists in interdisciplinary teams are continuously researching ways of improving the current centrifuges. Communication between specialists in the fields of chemistry, physics and engineering forms the basis for the company's success and the key to extending this leading position in the global enrichment market. (orig.)

  3. Role of stranded gas in increasing global gas supplies

    Science.gov (United States)

    Attanasi, E.D.; Freeman, P.A.

    2013-01-01

    This report synthesizes the findings of three regional studies in order to evaluate, at the global scale, the contribution that stranded gas resources can make to global natural gas supplies. Stranded gas, as defined for this study, is natural gas in discovered conventional gas and oil fields that is currently not commercially producible for either physical or economic reasons. The regional studies evaluated the cost of bringing the large volumes of undeveloped gas in stranded gas fields to selected markets. In particular, stranded gas fields of selected Atlantic Basin countries, north Africa, Russia, and central Asia are screened to determine whether the volumes are sufficient to meet Europe’s increasing demand for gas imports. Stranded gas fields in Russia, central Asia, Southeast Asia, and Australia are also screened to estimate development, production, and transport costs and corresponding gas volumes that could be supplied to Asian markets in China, India, Japan, and South Korea. The data and cost analysis presented here suggest that for the European market and the markets examined in Asia, the development of stranded gas provides a way to meet projected gas import demands for the 2020-to-2040 period. Although this is a reconnaissance-type appraisal, it is based on volumes of gas that are associated with individual identified fields. Individual field data were carefully examined. Some fields were not evaluated because current technology was insufficient or it appeared the gas was likely to be held off the export market. Most of the evaluated stranded gas can be produced and delivered to markets at costs comparable to historical prices. Moreover, the associated volumes of gas are sufficient to provide an interim supply while additional technologies are developed to unlock gas diffused in shale and hydrates or while countries transition to making a greater use of renewable energy sources.

  4. Preparation of environmental analyses for synfuel and unconventional gas technologies

    Energy Technology Data Exchange (ETDEWEB)

    Reed, R.M. (ed.)

    1982-09-01

    Government agencies that offer financial incentives to stimulate the commercialization of synfuel and unconventional gas technologies usually require an analysis of environmental impacts resulting from proposed projects. This report reviews potentially significant environmental issues associated with a selection of these technologies and presents guidance for developing information and preparing analyses to address these issues. The technologies considered are western oil shale, tar sand, coal liquefaction and gasification, peat, unconventional gas (western tight gas sands, eastern Devonian gas shales, methane from coal seams, and methane from geopressured aquifers), and fuel ethanol. Potentially significant issues are discussed under the general categories of land use, air quality, water use, water quality, biota, solid waste disposal, socioeconomics, and health and safety. The guidance provided in this report can be applied to preparation and/or review of proposals, environmental reports, environmental assessments, environmental impact statements, and other types of environmental analyses. The amount of detail required for any issue discussed must, by necessity, be determined on a case-by-case basis.

  5. Simultaneous stack-gas scrubbing and waste water treatment

    Science.gov (United States)

    Poradek, J. C.; Collins, D. D.

    1980-01-01

    Simultaneous treatment of wastewater and S02-laden stack gas make both treatments more efficient and economical. According to results of preliminary tests, solution generated by stack gas scrubbing cycle reduces bacterial content of wastewater. Both processess benefit by sharing concentrations of iron.

  6. Trapping technology for gaseous fission products from voloxidation process

    International Nuclear Information System (INIS)

    Shin, Jin Myeong; Park, J. J.; Park, G. I.; Jung, I. H.; Lee, H. H.; Kim, G. H.; Yang, M. S.

    2005-05-01

    The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, 14 C, Kr, Xe, I and 3 H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gas trapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and 14 C trapping unit. In case of I trapping unit, AgX is proposed. For Kr and Xe, adsorption on solid is proposed. SDBC (Styrene Divinyl Benzene Copolymer) is also proposed as a conversion media to HTO for 3 H. This report will be used as a useful means for analyzing the known trapping technologies and help selecting the appropriate trapping methods for trapping volatile and semi-volatile fission products, long-lived fission products, and major heat sources generated from a voloxidation process. It can also be used to design an off-gas treatment system

  7. Off-Gas Treatment: Evaluation of Nano-structured Sorbents for Selective Removal of Contaminants

    Energy Technology Data Exchange (ETDEWEB)

    Utgikar, Vivek; Aston, D. Eric; Sabharwall, Piyush

    2018-03-30

    Reprocessing of used nuclear fuel (UNF) is expected to play an important role for sustainable development of nuclear energy by increasing the energy extracted from the fuel and reducing the generation of the high level waste (HLW). However, aqueous reprocessing of UNF is accompanied by emission of off-gas streams containing radioactive nuclides including iodine, krypton, xenon, carbon, and tritium. Volatile iodine (129I), and krypton (85Kr) are long lived isotopes which have adverse effects on the environment as well as human health. Development of methods for the capture and long-term storage of radioactive gases is of crucial importance in order to manage their emissions that are anticipated to increase significantly with the growth of nuclear energy. For more than 70 years, porous solid sorbents have been in the forefront of radioactive contaminant removal due to promising results and their advantages such as high removal efficiency, low maintenance cost, simple equipment design and operation over other techniques. The research conducted in this project has focused on development of a novel nanostructured sorbent and its application for the capture of the above two contaminants of interest. Nanostructured carbon polyhedrons supported on Engelhard Titanosilicate-10 sorbent was synthesized using hydrothermal methods and subjected to structural and compositional characterization using various techniques including electron microscopy, Raman, x-ray diffraction and BET surface area analysis. Dynamic sorption experiments conducted using a flow-through column setup yielded information on the thermodynamics and kinetics of sorption in single-contaminant and multi-contaminant streams. Parameters varied in the study included carbon loading, temperature, contact time, contaminant concentration and humidity. The behavior of the system was modeled using models available in literature as well as development of a mass-transfer model from fundamental principles. Experimental

  8. The Mixed Waste Management Facility: Technology selection and implementation plan, Part 2, Support processes

    International Nuclear Information System (INIS)

    Streit, R.D.; Couture, S.A.

    1995-03-01

    The purpose of this document is to establish the foundation for the selection and implementation of technologies to be demonstrated in the Mixed Waste Management Facility, and to select the technologies for initial pilot-scale demonstration. Criteria are defined for judging demonstration technologies, and the framework for future technology selection is established. On the basis of these criteria, an initial suite of technologies was chosen, and the demonstration implementation scheme was developed. Part 1, previously released, addresses the selection of the primary processes. Part II addresses process support systems that are considered ''demonstration technologies.'' Other support technologies, e.g., facility off-gas, receiving and shipping, and water treatment, while part of the integrated demonstration, use best available commercial equipment and are not selected against the demonstration technology criteria

  9. Methane emissions from natural gas pipelines - current estimates, technologies and practices

    International Nuclear Information System (INIS)

    Lang, M.C.; Crook, L.

    1997-01-01

    Methane is the major component of natural gas. World-wide methane emissions from gas systems is estimated to be between 50 and 25 tera grams or about 5 percent of the world-wide total of anthropogenic methane emissions. Technologies and practices are described that are currently being used or are planned to be used in the US to both measure and/or reduce methane emissions from natural gas pipelines. One of the technologies that is described includes a high flow sampling instrument. One of the practices that is described is the current voluntary program conducted by the US Environmental Protection Agency called the Natural Gas Star program. This program supports research into best management practices, information sharing and technology transfer to promote methane emissions reductions profitably. (R.P.)

  10. On-site and off-site atmospheric PBDEs in an electronic dismantling workshop in south China: Gas-particle partitioning and human exposure assessment

    International Nuclear Information System (INIS)

    An Taicheng; Zhang Delin; Li Guiying; Mai Bixian; Fu Jiamo

    2011-01-01

    Gas samples and total suspended particle during work and off work time were investigated on-site and off-site electronic waste dismantling workshop (I- and O-EWDW), then compared with plastic recycling workshop (PRW) and waste incineration plant (WIP). TSP concentrations and total PBDE were 0.36-2.21 mg/m 3 and 27-2975 ng/m 3 at different workshops, respectively. BDE-47, -99, and -209 were major ΣPBDE congeners at I-EWDW and WIP, while BDE-209 was only dominant congener in PRW and control sites during work time and all sites during off work time. The gas-particle partitioning result was well correlated with the subcooled liquid vapor pressure for all samples, except for WIP and I-EDWD, at park during work time, and residential area during off work time. The predicted urban curve fitted well with measured φ values at O-DEWD during work time, whereas it was slightly overestimated or underestimated for others. Exposure assessment revealed the highest exposure site was I-EDWD. - Highlights: → On- and off-site atmospheric PBDEs was monitored in e-waste dismantling workshops in south China. → The gas-particle partitioning result was well correlated with the subcooled liquid vapor pressure for some samples. → Exposure assessment revealed that workers in I-EDWD were the highest exposure population. - The findings of this study may serve as a valuable reference for future risk assessment and environmental management in Guiyu, South China.

  11. Gas-cooled reactor technology: a bibliography

    International Nuclear Information System (INIS)

    Raleigh, H.D.

    1981-09-01

    Included are 3358 citations on gas-cooled reactor technology contained in the DOE Energy Data Base for the period January 1978 through June 1981. The citations include reports, journal articles, books, conference papers, patents, and monographs. Corporate, Personal Author, Subject, Contract Number, and Report Number Indexes are provided

  12. Evaluation of the performance of thermal diffusion column separating binary gas mixtures with continuous draw-off

    International Nuclear Information System (INIS)

    Kitamoto, Asashi; Shimizu, Masami; Takashima, Yoichi

    1977-01-01

    Advanced transport relations involving three column constants, H sup(σ), K sub(c)sup(σ) and K sub(d)sup(σ), are developed to describe the separation performance of a thermal diffusion column with continuous draw-off. These constants were related to some integral functions of velocity profile, temperature distribution, density of gas mixture and characteristic values of transport coefficients. The separation of binary gas mixture by this technique was so effective that three reasonable factors had to be introduced into the column constants in the theory. They are a circulation constant of natural convection, a definition of characteristic mean temperature and a definition of mean composition over the column. The separation performance and the column constants also varied with the distortion of velocity profile due to continuous draw-off from the top or the bottom of column. However, its effect was not large, compared with the other factors mentioned above. The theory presented here makes possible to estimate the separation performance of hot-wire type thermal diffusion column with high accuracy. (auth.)

  13. Technologies for direct production of flexible H2/CO synthesis gas

    International Nuclear Information System (INIS)

    Song Xueping; Guo Zhancheng

    2006-01-01

    The use of synthesis gas offers the opportunity to furnish a broad range of environmentally clean fuels and high value chemicals. However, synthesis gas manufacturing systems based on natural gas are capital intensive, and hence, there is great interest in technologies for cost effective synthesis gas production. Direct production of synthesis gas with flexible H 2 /CO ratio, which is in agreement with the stoichiometric ratios required by major synthesis gas based petrochemicals, can decrease the capital investment as well as the operating cost. Although CO 2 reforming and catalytic partial oxidation can directly produce desirable H 2 /CO synthesis gas, they are complicated and continued studies are necessary. In fact, direct production of flexible H 2 /CO synthesis gas can be obtained by optimizing the process schemes based on steam reforming and autothermal reforming as well as partial oxidation. This paper reviews the state of the art of the technologies

  14. Oxygen incineration process for treatment of alpha-contaminated wastes

    International Nuclear Information System (INIS)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, In Tae; Kim, Joon Hyung

    2001-07-01

    As a part of development of a treatment technology for burnable alpha-bearing (or -contaminated) wastes using an oxygen incineration process, which would be expected to produce in Korea, the off-gas volume and compositions were estimated form mass and heat balance, and then compared to those of a general air incineration process. A laboratory-scale oxygen incineration process, to investigate a burnable wastes from nuclear fuel fabricatin facility, was designed, constructed, and then operated. The use of oxygen instead of air in incineratin would result in reduction on off-gas product below one seventh theoretically. In addition, the trends on incineration and melting processes to treat the radioactive alpha-contaminated wastes, and the regulations and guide lines, related to design, construction, and operation of incineration process, were reviewed. Finallu, the domestic regulations related incineration, and the operation and maintenance manuals for oxy-fuel burner and oxygen incineration process were shown in appendixes

  15. Oxygen incineration process for treatment of alpha-contaminated wastes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, In Tae; Kim, Joon Hyung

    2001-07-01

    As a part of development of a treatment technology for burnable alpha-bearing (or -contaminated) wastes using an oxygen incineration process, which would be expected to produce in Korea, the off-gas volume and compositions were estimated form mass and heat balance, and then compared to those of a general air incineration process. A laboratory-scale oxygen incineration process, to investigate a burnable wastes from nuclear fuel fabricatin facility, was designed, constructed, and then operated. The use of oxygen instead of air in incineratin would result in reduction on off-gas product below one seventh theoretically. In addition, the trends on incineration and melting processes to treat the radioactive alpha-contaminated wastes, and the regulations and guide lines, related to design, construction, and operation of incineration process, were reviewed. Finallu, the domestic regulations related incineration, and the operation and maintenance manuals for oxy-fuel burner and oxygen incineration process were shown in appendixes.

  16. Optimising gas pipeline operation - factors to consider in selecting flow measurement technology; Gas flow measurement

    Energy Technology Data Exchange (ETDEWEB)

    Fromm, Frank

    2010-07-01

    Multipath ultrasonic transit-time flow meters (UFM) have been employed in the gas industries for many years. Since their inception in the early seventies, advancements in the technology have been made with regard to available configurations, electronics offered and sensor design. Today, UFMs have proven to be reliable, versatile and capable of meeting the demands of the gas markets. It is clear that various UFM technologies have different advantages with regards to design and application use, which ultimately makes one more appropriate than the other. (Author)

  17. Detection of Off-Flavor in Catfish Using a Conducting Polymer Electronic-Nose Technology

    Science.gov (United States)

    Wilson, Alphus D.; Oberle, Charisse S.; Oberle, Daniel F.

    2013-01-01

    The Aromascan A32S conducting polymer electronic nose was evaluated for the capability of detecting the presence of off-flavor malodorous compounds in catfish meat fillets to assess meat quality for potential merchantability. Sensor array outputs indicated that the aroma profiles of good-flavor (on-flavor) and off-flavor fillets were strongly different as confirmed by a Principal Component Analysis (PCA) and a Quality Factor value (QF > 7.9) indicating a significant difference at (P 90%) and with relatively low rates (≤5%) of unknown or indecisive determinations in three trials. This A32S e-nose instrument also was capable of detecting the incidence of mild off-flavor in fillets at levels lower than the threshold of human olfactory detection. Potential applications of e-nose technologies for pre- and post-harvest management of production and meat-quality downgrade problems associated with catfish off-flavor are discussed. PMID:24287526

  18. Detection of Off-Flavor in Catfish Using a Conducting Polymer Electronic-Nose Technology

    Directory of Open Access Journals (Sweden)

    Alphus D. Wilson

    2013-11-01

    Full Text Available The Aromascan A32S conducting polymer electronic nose was evaluated for the capability of detecting the presence of off-flavor malodorous compounds in catfish meat fillets to assess meat quality for potential merchantability. Sensor array outputs indicated that the aroma profiles of good-flavor (on-flavor and off-flavor fillets were strongly different as confirmed by a Principal Component Analysis (PCA and a Quality Factor value (QF > 7.9 indicating a significant difference at (P < 0.05. The A32S e-nose effectively discriminated between good-flavor and off-flavor catfish at high levels of accuracy (>90% and with relatively low rates (≤5% of unknown or indecisive determinations in three trials. This A32S e-nose instrument also was capable of detecting the incidence of mild off-flavor in fillets at levels lower than the threshold of human olfactory detection. Potential applications of e-nose technologies for pre- and post-harvest management of production and meat-quality downgrade problems associated with catfish off-flavor are discussed.

  19. DUV light source availability improvement via further enhancement of gas management technologies

    Science.gov (United States)

    Riggs, Daniel J.; O'Brien, Kevin; Brown, Daniel J. W.

    2011-04-01

    The continuous evolution of the semiconductor market necessitates ever-increasing improvements in DUV light source uptime as defined in the SEMI E10 standard. Cymer is developing technologies to exceed current and projected light source availability requirements via significant reduction in light source downtime. As an example, consider discharge chamber gas management functions which comprise a sizable portion of DUV light source downtime. Cymer's recent introduction of Gas Lifetime Extension (GLXTM) as a productivity improvement technology for its DUV lithography light sources has demonstrated noteworthy reduction in downtime. This has been achieved by reducing the frequency of full gas replenishment events from once per 100 million pulses to as low as once per 2 billion pulses. Cymer has continued to develop relevant technologies that target further reduction in downtime associated with light source gas management functions. Cymer's current subject is the development of technologies to reduce downtime associated with gas state optimization (e.g. total chamber gas pressure) and gas life duration. Current gas state optimization involves execution of a manual procedure at regular intervals throughout the lifetime of light source core components. Cymer aims to introduce a product enhancement - iGLXTM - that eliminates the need for the manual procedure and, further, achieves 4 billion pulse gas lives. Projections of uptime on DUV light sources indicate that downtime associated with gas management will be reduced by 70% when compared with GLX2. In addition to reducing downtime, iGLX reduces DUV light source cost of operation by constraining gas usage. Usage of fluorine rich Halogen gas mix has been reduced by 20% over GLX2.

  20. A Literature Survey to Identify Potentially Volatile Iodine-Bearing Species Present in Off-Gas Streams

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, S. H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Spencer, B. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Strachan, D. M. [Strata-G, Knoxville, TN (United States); Jubin, R. T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Soelberg, N. R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Riley, B. J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-06-30

    Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3H, 14C, 85Kr, and 129I. Of these, 129I has the longest half-life and potentially high biological impact. Accordingly, control of the release of 129I is most critical with respect to the regulations for the release of radioactive material in stack emissions. It is estimated that current EPA regulations (EPA 2010) would require any reprocessing plant in the United States to limit 129I release to less than 0.05 Ci/MTIHM for a typical fuel burnup of 55 gigawatt days per metric tonne (GWd/t) (Jubin 2011). The study of inorganic iodide in off-gas systems has been almost exclusively limited to I2 and the focus of organic iodide studies has been CH3I. In this document, we provide the results of an examination of publically available literature that is relevant to the presence and sources of both inorganic and organic iodine-bearing species in reprocessing plants. We especially focus on those that have the potential to be poorly sequestered with traditional capture methodologies. Based on the results of the literature survey and some limited thermodynamic modeling, the inorganic iodine species hypoiodous acid (HOI) and iodine monochloride (ICl) were identified as potentially low-sorbing iodine species that could present in off-gas systems. Organic species of interest included both short chain alkyl iodides such as methyl iodide (CH3I) and longer alkyl iodides up to iodododecane (C10H21I). It was found that fuel dissolution may provide conditions conducive to HOI formation and has been shown to result in volatile long-chain alkyl iodides, though these may not volatilize until later in the reprocessing sequence. Solvent extraction processes were found to be significant sources of various organic iodine-bearing species; formation of these

  1. Treatment of Oil & Gas Produced Water.

    Energy Technology Data Exchange (ETDEWEB)

    Dwyer, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-02-01

    Production of oil and gas reserves in the New Mexico Four Corners Region results in large volumes of "produced water". The common method for handling the produced water from well production is re-injection in regulatory permitted salt water disposal wells. This is expensive (%7E $5/bbl.) and does not recycle water, an ever increasingly valuable commodity. Previously, Sandia National Laboratories and several NM small business tested pressure driven membrane-filtration techniques to remove the high TDS (total dissolved solids) from a Four Corners Coal Bed Methane produced water. Treatment effectiveness was less than optimal due to problems with pre-treatment. Inadequate pre-treatment allowed hydrocarbons, wax and biological growth to foul the membranes. Recently, an innovative pre-treatment scheme using ozone and hydrogen peroxide was pilot tested. Results showed complete removal of hydrocarbons and the majority of organic constituents from a gas well production water. ACKNOWLEDGEMENTS This report was made possible through funding from the New Mexico Small Business Administration (NMSBA) Program at Sandia National Laboratories. Special thanks to Juan Martinez and Genaro Montoya for guidance and support from project inception to completion. Also, special thanks to Frank McDonald, the small businesses team POC, for laying the ground work for the entire project; Teresa McCown, the gas well owner and very knowledgeable- fantastic site host; Lea and Tim Phillips for their tremendous knowledge and passion in the oil & gas industry.; and Frank Miller and Steve Addleman for providing a pilot scale version of their proprietary process to facilitate the pilot testing.

  2. State of the art of technologies for remote detection of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-06-01

    There is an increasing awareness of the need to detect and survey gaseous fugitive emissions from production and distribution systems, industrial and energy processes, transportation systems for dangerous goods, leaks from landfill bodies,and from natural sources. Leaks may influence the function of production and distribution systems, or may be hazardous to human life or environment. It is important to be able to detect the leak source of gases,survey and quantify gaseous and fugitive emissions, and to visualise and map the spatial distribution of the gas plume. Most gases are not detectable by human sensor systems, and traditional surveying techniques and methods have poor accuracy, are labour intensive, and are normally not cost-efficient. Modern remote sensing techniques like high resolution thermography and powerful laser systems have opened up new possibilities to develop accurate, stable and cost-efficient handhold, land- mobile and airborne gas detection systems for a wide variety of applications. During the last decade research activities of remote gas detection have been performed in different high tech industrial countries round the world in order to meet the requests for remote gas detection technologies expressed by different civilian and military end users. In April 1996 a first meeting of a group of international researchers and end users was hold in Orlando, USA, in order to discuss the interest and the possibilities using passive and active remote sensing technologies for remote gas detection. The consensus of this meeting was that there is a need for highly sensitive and flexible remote gas detection techniques for detection of leaks from different gas sources, with ability to detect leak plumes at a sensitivity from 1-5 ppm and upwards, at an operating range from a few meters up to 500 m (1500 feet) or more, and with a geometric resolution from 1 mm{sup 2} for small scale surveying, up to 10-100 mm{sup 2} for large scale surveying. Furthermore

  3. Potential of the technology gas to liquids -GTL in Colombia

    International Nuclear Information System (INIS)

    Perez Angulo, Julio Cesar; Cabarcas Simancas, Manuel E; Archila Castro, Jesus; Tobias, Yamil Yubran

    2005-01-01

    Natural gas has a great potential because of the large reserves that currently exist at a worldwide level and because it is a cleaner source of energy than petroleum, but having the disadvantage of requiring high costs for its transportation. For this reason many alternatives have loomed for the development of reserves. Among these is the conversion of natural gas into synthetic ultra-clean fuels, called GTL, or gas-to-liquids. Through this process, Fischer-Tropsch for the production of diesel, naphtha and specialized products, which are used not only to effectively utilize natural gas reserves, but also, to cover at the need of more environmentally friendly fuels. This article will shed light on GTL technologies, presenting on a first instance an analysis of the different stages of the Fischer-Tropsch process, then the current status of this technology, afterwards the costs of investment and the necessary conditions for a project of this kind to be carried out and finally, and analysis of the applicability or projection for this technology in Colombia. Based on recent studies, it has been observed that is technology has surpassed its demonstrations stage and it is now at a maximum point of interest where companies like Sasol (the largest worldwide company in the area of synthetic carbon-based fuels), Chevron Texaco, Syntroleum, Exxon Mobil, Conoco Phillips, BP Rentech and shell. These companies have performed successful studies for the applicability of the Fischer-Tropsch technology at a large scale, and they will begin to build a number of large plants within the next few years, principally motivated by the low costs of gas and high prices of crude oil

  4. Options for Gas-to-Liquids Technology in Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, Eric Partridge

    1999-10-01

    The purposes of this work was to assess the effect of applying new technology to the economics of a proposed natural gas-to-liquids (GTL) plant, to evaluate the potential of a slower-paced, staged deployment of GTL technology, and to evaluate the effect of GTL placement of economics. Five scenarios were economically evaluated and compared: a no-major-gas-sales scenario, a gas-pipeline/LNG scenario, a fast-paced GTL development scenario, a slow-paced GTL development scenario, and a scenario which places the GTL plant in lower Alaska, instead of on the North Slope. Evaluations were completed using an after-tax discounted cash flow analysis. Results indicate that the slow-paced GTL scenario is the only one with a rate of return greater than 10 percent. The slow-paced GTL development would allow cost saving on subsequent expansions. These assumed savings, along with the lowering of the transportation tariff, combine to distinquish this option for marketing the North Slope gas from the other scenarios. Critical variables that need further consideration include the GTL plant cost, the GTL product premium, and operating and maintenance costs.

  5. Development of Micro-Pattern Gas Detectors Technologies

    CERN Multimedia

    Richer, J; Barsuk, S; Shah, M K; Catanesi, M G; Colaleo, A; Maggi, M; Loddo, F; Berardi, V; Bagliesi, M; Menon, G; Richter, R; Lahonde-hamdoun, C; Dris, M; Chechik, R; Ochi, A; Hartjes, F; Lopes, I M; Deshpande, A; Franz, A; Fiutowski, T A; Ferreira, A; Bastos de oliveira, C A; Miller, B W; Monrabal-capilla, F; Liubarsky, I; Plazas de pinzon, M C; Tsarfati, T; Voss, B J R; Carmona martinez, J M; Stocchi, A; Dinu, N; Semeniouk, I; Giebels, B; Marton, K; De leo, R; De lucia, E; Alviggi, M; Bellerive, A; Herten, L G; Zimmermann, S U; Giomataris, I; Peyaud, A; Schune, P; Delagnes, E; Delbart, A; Charles, G; Wang, W; Markou, A; Arazi, L; Cibinetto, G; Edo, Y; Neves, F F; Solovov, V; Stoll, S; Sampsonidis, D; Dabrowski, W; Mindur, B; Sauli, F; Calapez de albuquerque veloso, J F; Kahlaoui, N; Sharma, A; Zenker, K; Cebrian guajardo, S V; Luzon marco, G M; Guillaudin, O J H; Cornebise, P; Lounis, A; Bruel, P J; Laszlo, A; Mukerjee, K; Nappi, E; Nuzzo, S V; Bencivenni, G; Tessarotto, F; Levorato, S; Dixit, M S; Riallot, M; Jeanneau, F; Nizery, F G; Maltezos, S; Kyriakis, A; Lyashenko, A; Van der graaf, H; Ferreira marques, R; Alexa, C; Liyanage, N; Dehmelt, K; Hemmick, T K; Polychronakos, V; Cisbani, E; Garibaldi, F; Koperny, S Z; Das neves dias carramate, L F; Munoz-vidal, J; Gutierrez, R; Van stenis, M; Resnati, F; Lupberger, M; Desch, K K; Chefdeville, M; Vouters, G; Ranieri, A; Lami, S; Shekhtman, L; Dolgov, A; Bamberger, A; Landgraf, U; Kortner, O; Ferrero, A; Aune, S; Attie, D M; Bakas, G; Balossino, I; Tsigaridas, S; Surrow, B; Gnanvo, K A K; Feege, N M; Woody, C L; Bhattacharya, S; Capogni, M; Veenhof, R J; Tapan, I; Dangendorf, V; Monteiro bernades, C M; Castro serrato, H F; De oliveira, R; Ropelewski, L; Behnke, T; Boudry, V; Radicioni, E; Lai, A; Shemyakina, E; Giganon, A E; Titov, M; Papakrivopoulos, I; Komai, H; Van bakel, N A; Tchepel, V; Repond, J O; Li, Y; Kourkoumelis, C; Tzamarias, S; Majumdar, N; Kowalski, T; Da rocha azevedo, C D; Serra diaz cano, L; Alvarez puerta, V; Trabelsi, A; Riegler, W; Ketzer, B F; Rosemann, C G; Herrera munoz, D C; Drancourt, C; Mayet, F; Geerebaert, Y; De robertis, G; Felici, G; Scribano memoria, A; Cecchi, R; Dalla torre, S; Gregori, M; Buzulutskov, A; Schwegler, P; Sanchez nieto, F J; Colas, P M A; Gros, M; Neyret, D; Zito, M; Ferrer ribas, E; Breskin, A; Martoiu, V S; Purschke, M L; Loomba, D; Gasik, P J; Petridou, C; Kordas, K; Mukhopadhyay, S; Bucciantonio, M; Biagi, S F; Ji, X; Kanaki, K; Zavazieva, D; Capeans garrido, M D M; Schindler, H; Kaminski, J; Krautscheid, T; Lippmann, C; Arora, R; Dafni, T; Garcia irastorza, I; Puill, V; Wicek, F B; Burmistrov, L; Singh, K P; Kroha, H; Kunne, F; Alexopoulos, T; Daskalakis, G; Geralis, T; Bettoni, D; Heijhoff, K; Xiao, Z; Tzanakos, G; Leisos, A; Frullani, S; Sahin, O; Kalkan, Y; Giboni, K; Krieger, C; Breton, D R; Bhattacharyya, S; Abbrescia, M; Erriquez, O; Paticchio, V; Cardini, A; Aloisio, A; Turini, N; Bressan, A; Tikhonov, Y; Schumacher, M; Simon, F R; Nowak, S; Herlant, S; Chaus, A; Fanourakis, G; Bressler, S; Homma, Y; Timmermans, J; Fonte, P; Underwood, D G; Azmoun, B; Fassouliotis, D; Wiacek, P; Dos santos covita, D; Monteiro da silva, A L; Yahlali haddou, N; Marques ferreira dos santos, J; Domingues amaro, F

    The proposed R&D collaboration, RD51, aims at facilitating the development of advanced gas-avalanche detector technologies and associated electronic-readout systems, for applications in basic and applied research. Advances in particle physics have always been enabled by parallel advances in radiation-detector technology. Radiation detection and imaging with gas-avalanche detectors, capable of economically covering large detection volumes with a low material budget, have been playing an important role in many fields. Besides their widespread use in particle-physics and nuclear-physics experiments, gaseous detectors are employed in many other fields: astro-particle research and applications such as medical imaging, material science, and security inspection. While extensively employed at the LHC, RHIC, and other advanced HEP experiments, present gaseous detectors (wire-chambers, drift-tubes, resistive-plate chambers and others) have limitations which may prevent their use in future experiments. Present tec...

  6. MIxed Waste Integrated Program (MWIP): Technology summary

    International Nuclear Information System (INIS)

    1994-02-01

    The mission of the Mixed Waste Integrated Program (MWIP) is to develop and demonstrate innovative and emerging technologies for the treatment and management of DOE's mixed low-level wastes (MLLW) for use by its customers, the Office of Waste Operations (EM-30) and the Office of Environmental Restoration (EM-40). The primary goal of MWIP is to develop and demonstrate the treatment and disposal of actual mixed waste (MMLW and MTRU). The vitrification process and the plasma hearth process are scheduled for demonstration on actual radioactive waste in FY95 and FY96, respectively. This will be accomplished by sequential studies of lab-scale non-radioactive testing followed by bench-scale radioactive testing, followed by field-scale radioactive testing. Both processes create a highly durable final waste form that passes leachability requirements while destroying organics. Material handling technology, and off-gas requirements and capabilities for the plasma hearth process and the vitrification process will be established in parallel

  7. ‘Domesticating’ low carbon thermal technologies: Diversity, multiplicity and variability in older person, off grid households

    International Nuclear Information System (INIS)

    Wrapson, Wendy; Devine-Wright, Patrick

    2014-01-01

    The uptake of low carbon heating technologies forms an important part of government strategies to reduce carbon emissions. Yet our understanding of why such technologies are adopted and how they are engaged with post-adoption, particularly by older adults living in off-grid areas, is limited. Drawing on a contextualised, socio-technical approach to domestic heating, we present findings from 51 in-depth interviews with a sample of 17 older person households in the South West of England, with ages ranging from 60 to 89 years. Diverse and multiple configurations of heating devices and fuels were found that varied considerably, with some households using five different fuels. The design of the study ensured that approximately half the sample used some form of low carbon thermal technology, such as heat pumps and biomass boilers. Many factors were reported to influence the adoption of low carbon heating; environmental motives were not primary influences and the avoidance of financial risks associated with ‘peak oil’ was expressed. Low carbon thermal technologies were typically integrated into rather than replaced existing heating systems so that valued services provided by conventional technologies could be retained. Implications of the findings for policies to reduce carbon emissions, particularly in older adult, off-grid households, are discussed. - Highlights: • We interviewed 17 households with conventional/low carbon thermal technologies (LCTTs) in South West England. • Older adult, off grid households commonly use multiple, diverse and variable heating technologies and fuels. • Reducing fuel costs was a key reason for installing LCTTs. • LCTTs more commonly were integrated with, rather than replaced, conventional technologies. • Expected reductions in domestic carbon emissions due to LCTTs may not be realised

  8. Optimizing Geothermal Drilling: Oil and Gas Technology Transfer

    Energy Technology Data Exchange (ETDEWEB)

    Tilley, Mitch; Eustes, Alfred; Visser, Charles; Baker, Walt; Bolton, Dan; Bell, Jason; Nagandran, Uneshddarann; Quick, Ralph

    2015-01-26

    There is a significant amount of financial risk associated with geothermal drilling; however, there are opportunities to improve upon current practices and technologies used. The scope of this drilling operational study included 21 geothermal wells and 21 oil and gas wells. The goal was to determine a 'perfect well' using historical data to compare the best oil and gas well to the best geothermal well. Unfortunately, limitations encountered in the study included missing data (bit records, mud information, etc.), poor data collection, and difficult to ascertain handwriting. An online software database was used to format drilling data to IADC coded daily drilling reports and generate analysis figures. Six major issues have been found in geothermal drilling operations. These problems include lost circulation, rig/equipment selection, cementing, penetration rate, drilling program, and time management. As a result of these issues, geothermal drilling averages 56.4 days longer than drilling comparable oil and gas wells in the wells in this study. Roughly $13.9 million would be lost due to non-productive time in the 21 geothermal wells and only $1.3 million in the oil and gas wells, assuming a cost of $50,000 per day. Comparable events such as drilling the same sized hole, tripping in/out, cementing, and running the same size casing took substantially less time in the oil and gas wells. Geothermal wells were drilled using older and/or less advanced technology to depths less than 10,000 feet, while oil and gas wells reached 12,500 feet faster with purpose built rigs. A new approach is now underway that will optimize drilling programs throughout the drilling industry. It is the use of Mechanical Specific Energy (MSE) as a tool to realize efficient drilling processes. However, a work-flow must also be established in order for there to be an efficient drilling program. Potential improvements for current geothermal operations are: the use of electronic records, real

  9. Optimizing Geothermal Drilling: Oil and Gas Technology Transfer

    Energy Technology Data Exchange (ETDEWEB)

    Denninger, Kate; Eustes, Alfred; Visser, Charles; Baker, Walt; Bolton, Dan; Bell, Jason; Bell, Sean; Jacobs, Amelia; Nagandran, Uneshddarann; Tilley, Mitch; Quick, Ralph

    2015-09-02

    There is a significant amount of financial risk associated with geothermal drilling. This study of drilling operations seeks opportunities to improve upon current practices and technologies. The scope of this study included analyzing 21 geothermal wells and 21 oil and gas wells. The goal was to determine a 'Perfect Well' using historical data to compare the best oil and gas well to the best geothermal well. Unfortunately, limitations encountered in the study included missing data (bit records, mud information, etc.) and poor data collection practices An online software database was used to format drilling data to IADC coded daily drilling reports and generate figures for analysis. Six major issues have been found in geothermal drilling operations. These problems include lost circulation, rig/ equipment selection, cementing, penetration rate, drilling program, and time management. As a result of these issues, geothermal drilling averaged 56.4 days longer than drilling comparable oil and gas wells in the wells in this study. Roughly $13.9 million was spent on non-productive time in the 21 geothermal wells, compared with only $1.3 million in the oil and gas wells, assuming a cost of $50,000 per day. Comparable events such as drilling the same sized hole, tripping in/out, cementing, and running the same size casing took substantially less time in the oil and gas wells. Geothermal wells were drilled using older and/or less advanced technology to depths less than 10,000 feet, while oil and gas wells reached 12,500 feet faster with purpose built rigs. A new approach is now underway that will optimize drilling programs throughout the drilling industry using Mechanical Specific Energy (MSE) as a tool to realize efficient drilling processes. Potential improvements for current geothermal operations are: the use of electronic records, real time services, and official glossary terms to describe rig operations, and advanced drilling rigs/technology.

  10. Improving the technology of purification of gas emissions petrochemical industries

    OpenAIRE

    USMANOVA R.R.; ZAIKOV G.E.

    2014-01-01

    The technology of cleaning of gas emissions flares in the production of synthetic rubber. Developed dynamic scrubber for scrubbing gas emissions. Complex studies served as the basis for the design of an air purification system of industrial premises. Purification of gas emissions before combustion in flares has significantly reduced air pollution by toxic substances.

  11. Gas phase adsorption technology for nitrogen isotope separation and its feasibility for highly enriched nitrogen gas production

    International Nuclear Information System (INIS)

    Inoue, Masaki; Asaga, Takeo

    2000-04-01

    Highly enriched nitrogen-15 gas is favorable to reduce radioactive carbon-14 production in reactor. The cost of highly enriched nitrogen-15 gas in mass production is one of the most important subject in nitride fuel option in 'Feasibility Study for FBR and Related Fuel Cycle'. In this work gas phase adsorption technology was verified to be applicable for nitrogen isotope separation and feasible to produce highly enriched nitrogen-15 gas in commercial. Nitrogen isotopes were separated while ammonia gas flows through sodium-A type zeolite column using pressure swing adsorption process. The isotopic ratio of eight samples were measured by high resolution mass spectrometry and Fourier transform microwave spectroscopy. Gas phase adsorption technology was verified to be applicable for nitrogen isotope separation, since the isotopic ratio of nitrogen-15 and nitrogen-14 in samples were more than six times as high as in natural. The cost of highly enriched nitrogen-15 gas in mass production were estimated by the factor method. It revealed that highly enriched nitrogen-15 gas could be supplied in a few hundred yen per gram in mass production. (author)

  12. Possible use of electron beam treatment for removal of SO2 in off-gases from copper smelters. Preliminary tests results

    International Nuclear Information System (INIS)

    Villanueva, L.; Ahumanda, L.; Chmielewski, A.; Zimek, A.; Budka, S.; Licki, J.

    1996-01-01

    The Chilean Nuclear Energy Commission is currently performing a previous feasibility study concerning possible utilization of electron-beam process for removal of SO 2 from different types of sulfurous streams from copper smelters. First part of the project was related to verify, in a experimental line at Institute of Nuclear Chemistry and Technology, INCT, Poland, the behaviour of the process for simulated off-gases with very high SO 2 content, between 5% to 15% by volume. Tests were performed at laboratory stage and with flowrate of 5 Nm 3 /hr, using an ILU-6 electron accelerator, with the following results: High removal efficiencies of SO 2 , up to 90% were achieved for simulated off-gases containing up to 15% of SO 2 ; Required dose was in the range 5 to 8 kGy; Big influence of NH 3 stoichiometry and gas humidity on SO 2 removal efficiency; Rapid generation of sub-micron solid by-product, in great amount, that causes deposits on ducts and filtration units. This work presents the experimental results and discuss is technical projections in the field of interest. (author)

  13. Dynawave froth scrubbing technology

    International Nuclear Information System (INIS)

    McLean, J.E.

    1989-01-01

    The DynaWave family of scrubbers was developed and patented by DuPont in the 1970's and is used extensively within the company. Because the technology was treated as confidential, information about the scrubbers was not published outside of DuPont. In 1986 Monsanto Enviro-Chem was asked to install a Reverse Jet scrubber at DuPont's Burnside spent acid recovery pant to replace an aging spray humidifying tower. Enviro-Chem was impressed with the technology and entered into a licensing agreement with DuPont in late 1987. This paper addresses the application of DynaWave froth scrubbing technology to metallurgical plant process and effluent gas streams. Froth scrubber design principles an sampling results from pilot plant trails on fluid bed roaster off-gas are presented

  14. Development of a technique for the efficiency calibration of a HPGe detector for the off gas samples of a nuclear reactor

    International Nuclear Information System (INIS)

    Singh, Sarbjit; Agarwal, Chhavi; Ramaswami, A.; Manchanda, V.K.

    2007-01-01

    Regular monitoring of off gases released to the environment from a nuclear reactor is mandatory. The gaseous fission products are estimated by gamma ray spectrometry using a HPGe detector coupled to a multichannel analyser. In view of the lack of availability of gaseous fission products standards, an indirect method based on the charcoal absorption technique was developed for the efficiency calibration of HPGe detector system using 133B a and 152E u standards. The known activities of 133B a and 152E u are uniformly distributed in a vial having activated charcoal and counted on the HPGe detector system at liquid nitrogen temperature to determine the gamma ray efficiency for the vial having activated charcoal. The ratio of the gamma ray efficiencies of off gas present in the normal vial and the vial having activated charcoal at liquid nitrogen temperature are used to determine the gamma ray efficiency of off gas present in the normal vial. (author)

  15. Parametric economic analysis of natural gas reburn technologies. Topical report, June 1991-June 1992

    International Nuclear Information System (INIS)

    Bluestein, J.

    1992-06-01

    The report presents a parametric economic analysis of natural gas reburn technologies used for control of nitrogen oxides emissions in coal-fired utility boilers. It is a competitive assessment of the economics of gas reburn performed in the context of regulatory requirements and competing conventional technologies. The reburn technologies examined are basic gas reburn, reburn with sorbent injection and advanced gas reburn. The analysis determined the levelized costs of these technologies in $/ton of NOx removed with respect to a gas-coal price differential in $/MMBtu of energy input. For those niches in which reburn was less economical, a breakeven capital cost analysis was carried out to determine the R ampersand D goals which would make reburn more cost competitive

  16. Role of technology in the U. K. gas industry. past, present, future

    Energy Technology Data Exchange (ETDEWEB)

    Evans, J W

    1979-06-01

    A discussion covers the beginning of public gas supply in the U.K.; the production of gas during coal combustion and the oil era; the development of LNG transport technology; the development of the Dent processes for producing gases from hydrocarbon feedstocks including the Catalytic Rich Gas and the Gas Recycle Hydrogenation processes; the growth of the natural gas transmission and distribution industry; the organization and functions of the British Gas Corp. Research and Development Division and Scientific Services; the various technological innovations being used in the transmission, distribution, domestic and industrial utilization sectors of the gas industry; the various efforts leading to the development of a commercial SNG process, based on the Lurgi coal gasifier operated under slagging conditions, that can handle a wide range of coals; and the outlook for future gas supply and demand, a hydrogen economy-based gas industry, and new developments affecting gas transmission and distribution, conservation and utilization.

  17. Oil and natural gas technology review-lubrication and lubricants

    Energy Technology Data Exchange (ETDEWEB)

    Moos, J

    1966-01-01

    A summary is presented of the advances made during 1967 in the following areas: production and transmission of natural gas; geosciences; drilling and production technology; secondary recovery; transportation by tanker, pipelines, and tank cars; storage; planning of refineries; control and automation; cracking and gasification of crude oil; separation and hydrogenation processes; petrochemicals; combustion technology; fuels and additives; air and water pollution control; production of lubricants; lubrication with mist, gas, and vapors; hydraulic fluids; lubricant additives; oxidation and aging of oils; greases; solid lubricants; bearings; machining; friction and wear; and changes in materials of construction. (220 refs.)

  18. Technologies applied to wells producing gas in Bolivia; Tecnologias aplicadas aos pocos produtores de gas em Bolivia

    Energy Technology Data Exchange (ETDEWEB)

    Nobrega, Fernando R.B. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil); Carrillo, Marco A.; Barrerro, Dennys A. [PETROBRAS Bolivia S.A., La Paz (Bolivia)

    2012-07-01

    The This paper seeks to highlight the engineering, lessons learned and topics for improvement of the technologies used in gas wells drilled between November 2008 and October 2011 in an environment of Bolivian' subandino. Among technologies employed and commented hereunder has the drilling gas reservoirs in near balance using a dual phase fluid, with nitrogen; carrying out multilateral wells equipped with intelligent completion in such environment; as well as other technologies presented herein. This document was prepared on drilling operations performed in SAL-15, SAL-17, SBLSBL- 7 and SBL-8, comprising the period from November 2008 to October 2011. (author)

  19. Modeling The Impact Of Elevated Mercury In Defense Waste Processing Facility Melter Feed On The Melter Off-Gas System - Preliminary Report

    International Nuclear Information System (INIS)

    Zamecnik, J.; Choi, A.

    2009-01-01

    The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that come in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter off-gas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl 2 , and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg 2 Cl 2 ) to HgCl 2 with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of

  20. Adequate technologies for wireless real-time dose rate monitoring for off-site emergency management

    International Nuclear Information System (INIS)

    Dielmann, R.; Buerkin, W.

    2003-01-01

    Full text: What are the requirements for off-site gamma dose rate monitoring systems? What are the pros and cons of available communication technologies? This report gives an overview of modern communication techniques and their applicability for reliable real-time data acquisition as basis for off-site nuclear emergency management. The results of three years operating experience with a wireless gamma dose rate monitoring system, installed around the NPPs of KURSK, KALININ and BALAKOVA (Russia) in the year 2000, are shown. (author)

  1. The future for electrocoagulation as a localised water treatment technology.

    Science.gov (United States)

    Holt, Peter K; Barton, Geoffrey W; Mitchell, Cynthia A

    2005-04-01

    Electrocoagulation is an electrochemical method of treating polluted water whereby sacrificial anodes corrode to release active coagulant precursors (usually aluminium or iron cations) into solution. Accompanying electrolytic reactions evolve gas (usually as hydrogen bubbles) at the cathode. Electrocoagulation has a long history as a water treatment technology having been employed to remove a wide range of pollutants. However electrocoagulation has never become accepted as a 'mainstream' water treatment technology. The lack of a systematic approach to electrocoagulation reactor design/operation and the issue of electrode reliability (particularly passivation of the electrodes over time) have limited its implementation. However recent technical improvements combined with a growing need for small-scale decentralised water treatment facilities have led to a re-evaluation of electrocoagulation. Starting with a review of electrocoagulation reactor design/operation, this article examines and identifies a conceptual framework for electrocoagulation that focuses on the interactions between electrochemistry, coagulation and flotation. In addition detailed experimental data are provided from a batch reactor system removing suspended solids together with a mathematical analysis based on the 'white water' model for the dissolved air flotation process. Current density is identified as the key operational parameter influencing which pollutant removal mechanism dominates. The conclusion is drawn that electrocoagulation has a future as a decentralised water treatment technology. A conceptual framework is presented for future research directed towards a more mechanistic understanding of the process.

  2. Development of Laser-Polarized Noble Gas Magnetic Resonance Imaging (MRI) Technology

    Science.gov (United States)

    Walsworth, Ronald L.

    2004-01-01

    We are developing technology for laser-polarized noble gas nuclear magnetic resonance (NMR), with the aim of enabling it as a novel biomedical imaging tool for ground-based and eventually space-based application. This emerging multidisciplinary technology enables high-resolution gas-space magnetic resonance imaging (MRI)-e.g., of lung ventilation, perfusion, and gas-exchange. In addition, laser-polarized noble gases (3He and 1BXe) do not require a large magnetic field for sensitive NMR detection, opening the door to practical MRI with novel, open-access magnet designs at very low magnetic fields (and hence in confined spaces). We are pursuing two specific aims in this technology development program. The first aim is to develop an open-access, low-field (less than 0.01 T) instrument for MRI studies of human gas inhalation as a function of subject orientation, and the second aim is to develop functional imaging of the lung using laser-polarized He-3 and Xe-129.

  3. Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions.

    Science.gov (United States)

    Shaffer, Devin L; Arias Chavez, Laura H; Ben-Sasson, Moshe; Romero-Vargas Castrillón, Santiago; Yip, Ngai Yin; Elimelech, Menachem

    2013-09-03

    In the rapidly developing shale gas industry, managing produced water is a major challenge for maintaining the profitability of shale gas extraction while protecting public health and the environment. We review the current state of practice for produced water management across the United States and discuss the interrelated regulatory, infrastructure, and economic drivers for produced water reuse. Within this framework, we examine the Marcellus shale play, a region in the eastern United States where produced water is currently reused without desalination. In the Marcellus region, and in other shale plays worldwide with similar constraints, contraction of current reuse opportunities within the shale gas industry and growing restrictions on produced water disposal will provide strong incentives for produced water desalination for reuse outside the industry. The most challenging scenarios for the selection of desalination for reuse over other management strategies will be those involving high-salinity produced water, which must be desalinated with thermal separation processes. We explore desalination technologies for treatment of high-salinity shale gas produced water, and we critically review mechanical vapor compression (MVC), membrane distillation (MD), and forward osmosis (FO) as the technologies best suited for desalination of high-salinity produced water for reuse outside the shale gas industry. The advantages and challenges of applying MVC, MD, and FO technologies to produced water desalination are discussed, and directions for future research and development are identified. We find that desalination for reuse of produced water is technically feasible and can be economically relevant. However, because produced water management is primarily an economic decision, expanding desalination for reuse is dependent on process and material improvements to reduce capital and operating costs.

  4. Problems of technology and corrosion in sodium coolant and cover gas

    International Nuclear Information System (INIS)

    Kuenstler, K.; Ullmann, H.

    1977-07-01

    The meeting encloses the following themes: (i) Reactions in the system sodium-steel-cover gas (ii) Corrosion behaviour of structural and cladding materials (iii) Determination of impurities in sodium and cover gas (iv) Technology of sodium and cover gas (v) Testing equipments (vi) Safety problems

  5. Remedial technology for contaminated natural gas dehydrator sites

    International Nuclear Information System (INIS)

    Prosen, B.J.; Korreck, W.M.; Armstrong, J.M.

    1991-01-01

    Ground water and soil contamination at many of Michigan's oil and gas well sites has been attributed to natural gas dehydration processes. Since water was once thought to be the only by-product from the dehydration process, condensate from the process was discharged directly to the ground for several years. This condensate was later found to contain benzene, toluene, ethyl-benzene, and xylenes (BTEX), and the process of discharging condensate to the ground was stopped. Many oil and gas well sites had become impacted from the process during this time. Although condensate is no longer discharged to the ground, soil and water contamination still remains at many of these sites. In the last few years, the Michigan Department of Natural Resources has targeted over 90 well sites for assessment of contamination associated with gas dehydration. The results of many of these assessments indicate that soil and ground water have been impacted, and the State of Michigan has mandated cleanup of these sites. Remedial technologies which have been used to contain and/or clean up the sites include excavation and product removal, soil venting, purge and treat, and enhanced biodegradation. This paper is a discussion of the technology, implementation, and results from each of these methods

  6. Improvement of melter off-gas design for commercial HALW vitrification facility

    Energy Technology Data Exchange (ETDEWEB)

    Ohno, A.; Kitamura, M.; Yamanaka, T. [Ishikawajima-Harima Heavy Industries Co., Ltd., Yokohama (Japan); Yoshioka, M.; Endo, N.; Asano, N. [Japan Nuclear Cycle Development Institute, Ibaraki (Japan)

    2001-07-01

    The Japan commercial reprocessing plant is now under construction, and it will commence the operation in 2005. The High Active Liquid Waste (HALW) generated at the plant is treated into glass product at the vitrification facility using the Liquid Fed Joule-Heated Ceramic Melter (LFCM). The characteristic of the LFCM is that the HALW is fed directly onto the molten glass surface with the glass forming material. This process was developed by the Japan Nuclear Cycle Development Institute (JNC). The JNC process was first applied to the Tokai Vitrification Facility (TVF), which is a pilot scale plant having about 1/6 capacity of the commercial facility. The TVF has been in operation since 1995. During the operation, the rapid increase of the differential pressure between the melter plenum and the dust scrubber was observed. This phenomenon is harmful to the long-term continuous operation of TVF. And, it is also anticipated that the same phenomenon will occur in commercial vitrification facility. In order to solve this problem, the countermeasures were studied and developed. Through the study on the deposit growing mechanism, it was probable that the rapid increased differential pressure was attributed to the condensation of meta-boric acid at the outlet of the air-film cooler slits. And, the heating and the humidification of purge air were judged to be effective as the countermeasures to suppress the condensation. On the other hand, the water injection into melter off-gas pipe was found to be very effective to reduce the differential pressure as the results of the various tests. The deposit adhered on the inner surface of the off-gas pipe was almost washed out. And, it was also demonstrated that the system was superior to other systems by virtue of its simplicity and stability. In order to apply the system to the commercial scale plant, the scale-up tests were conducted at JNC mock-up facility using the acrylic model. (author)

  7. Improvement of melter off-gas design for commercial HALW vitrification facility

    International Nuclear Information System (INIS)

    Ohno, A.; Kitamura, M.; Yamanaka, T.; Yoshioka, M.; Endo, N.; Asano, N.

    2001-01-01

    The Japan commercial reprocessing plant is now under construction, and it will commence the operation in 2005. The High Active Liquid Waste (HALW) generated at the plant is treated into glass product at the vitrification facility using the Liquid Fed Joule-Heated Ceramic Melter (LFCM). The characteristic of the LFCM is that the HALW is fed directly onto the molten glass surface with the glass forming material. This process was developed by the Japan Nuclear Cycle Development Institute (JNC). The JNC process was first applied to the Tokai Vitrification Facility (TVF), which is a pilot scale plant having about 1/6 capacity of the commercial facility. The TVF has been in operation since 1995. During the operation, the rapid increase of the differential pressure between the melter plenum and the dust scrubber was observed. This phenomenon is harmful to the long-term continuous operation of TVF. And, it is also anticipated that the same phenomenon will occur in commercial vitrification facility. In order to solve this problem, the countermeasures were studied and developed. Through the study on the deposit growing mechanism, it was probable that the rapid increased differential pressure was attributed to the condensation of meta-boric acid at the outlet of the air-film cooler slits. And, the heating and the humidification of purge air were judged to be effective as the countermeasures to suppress the condensation. On the other hand, the water injection into melter off-gas pipe was found to be very effective to reduce the differential pressure as the results of the various tests. The deposit adhered on the inner surface of the off-gas pipe was almost washed out. And, it was also demonstrated that the system was superior to other systems by virtue of its simplicity and stability. In order to apply the system to the commercial scale plant, the scale-up tests were conducted at JNC mock-up facility using the acrylic model. (author)

  8. Energy positive domestic wastewater treatment: the roles of anaerobic and phototrophic technologies.

    Science.gov (United States)

    Shoener, B D; Bradley, I M; Cusick, R D; Guest, J S

    2014-05-01

    The negative energy balance of wastewater treatment could be reversed if anaerobic technologies were implemented for organic carbon oxidation and phototrophic technologies were utilized for nutrient recovery. To characterize the potential for energy positive wastewater treatment by anaerobic and phototrophic biotechnologies we performed a comprehensive literature review and analysis, focusing on energy production (as kJ per capita per day and as kJ m(-3) of wastewater treated), energy consumption, and treatment efficacy. Anaerobic technologies included in this review were the anaerobic baffled reactor (ABR), anaerobic membrane bioreactor (AnMBR), anaerobic fluidized bed reactor (AFB), upflow anaerobic sludge blanket (UASB), anaerobic sequencing batch reactor (ASBR), microbial electrolysis cell (MEC), and microbial fuel cell (MFC). Phototrophic technologies included were the high rate algal pond (HRAP), photobioreactor (PBR), stirred tank reactor, waste stabilization pond (WSP), and algal turf scrubber (ATS). Average energy recovery efficiencies for anaerobic technologies ranged from 1.6% (MFC) to 47.5% (ABR). When including typical percent chemical oxygen demand (COD) removals by each technology, this range would equate to roughly 40-1200 kJ per capita per day or 110-3300 kJ m(-3) of treated wastewater. The average bioenergy feedstock production by phototrophic technologies ranged from 1200-4700 kJ per capita per day or 3400-13 000 kJ m(-3) (exceeding anaerobic technologies and, at times, the energetic content of the influent organic carbon), with usable energy production dependent upon downstream conversion to fuels. Energy consumption analysis showed that energy positive anaerobic wastewater treatment by emerging technologies would require significant reductions of parasitic losses from mechanical mixing and gas sparging. Technology targets and critical barriers for energy-producing technologies are identified, and the role of integrated anaerobic and

  9. Energy positive domestic wastewater treatment: the roles of anaerobic and phototrophic technologies

    KAUST Repository

    Shoener, B. D.

    2014-01-01

    The negative energy balance of wastewater treatment could be reversed if anaerobic technologies were implemented for organic carbon oxidation and phototrophic technologies were utilized for nutrient recovery. To characterize the potential for energy positive wastewater treatment by anaerobic and phototrophic biotechnologies we performed a comprehensive literature review and analysis, focusing on energy production (as kJ per capita per day and as kJ m-3 of wastewater treated), energy consumption, and treatment efficacy. Anaerobic technologies included in this review were the anaerobic baffled reactor (ABR), anaerobic membrane bioreactor (AnMBR), anaerobic fluidized bed reactor (AFB), upflow anaerobic sludge blanket (UASB), anaerobic sequencing batch reactor (ASBR), microbial electrolysis cell (MEC), and microbial fuel cell (MFC). Phototrophic technologies included were the high rate algal pond (HRAP), photobioreactor (PBR), stirred tank reactor, waste stabilization pond (WSP), and algal turf scrubber (ATS). Average energy recovery efficiencies for anaerobic technologies ranged from 1.6% (MFC) to 47.5% (ABR). When including typical percent chemical oxygen demand (COD) removals by each technology, this range would equate to roughly 40-1200 kJ per capita per day or 110-3300 kJ m-3 of treated wastewater. The average bioenergy feedstock production by phototrophic technologies ranged from 1200-4700 kJ per capita per day or 3400-13000 kJ m-3 (exceeding anaerobic technologies and, at times, the energetic content of the influent organic carbon), with usable energy production dependent upon downstream conversion to fuels. Energy consumption analysis showed that energy positive anaerobic wastewater treatment by emerging technologies would require significant reductions of parasitic losses from mechanical mixing and gas sparging. Technology targets and critical barriers for energy-producing technologies are identified, and the role of integrated anaerobic and phototrophic

  10. Exhaust gas aftertreatment with online burner; Abgasnachbehandlung mit Online-Brenner

    Energy Technology Data Exchange (ETDEWEB)

    Rembor, Hans-Joerg; Bischler, Thomas [Huss Technologies GmbH, Nuernberg (Germany)

    2010-09-15

    In order to fulfil continuously tightened emission standards, modern Diesel engines for on and off road have to meet demands of catalytic exhaust gas aftertreatment with their thermomanagement. With an online burner from Huss Technologies, even with low load duty cycles, catalytic exhaust gas aftertreatment is possible. Diesel engine development can therefore be redirected again more on efficiency enhancement and other direct customer demands. (orig.)

  11. Electrospray-printed nanostructured graphene oxide gas sensors

    International Nuclear Information System (INIS)

    Taylor, Anthony P; Velásquez-García, Luis F

    2015-01-01

    We report low-cost conductometric gas sensors that use an ultrathin film made of graphene oxide (GO) nanoflakes as transducing element. The devices were fabricated by lift-off metallization and near-room temperature, atmospheric pressure electrospray printing using a shadow mask. The sensors are sensitive to reactive gases at room temperature without requiring any post heat treatment, harsh chemical reduction, or doping with metal nanoparticles. The sensors’ response to humidity at atmospheric pressure tracks that of a commercial sensor, and is linear with changes in humidity in the 10%–60% relative humidity range while consuming <6 μW. Devices with GO layers printed by different deposition recipes yielded nearly identical response characteristics, suggesting that intrinsic properties of the film control the sensing mechanism. The gas sensors successfully detected ammonia at concentrations down to 500 ppm (absolute partial pressure of ∼5 × 10"−"4 T) at ∼1 T pressure, room temperature conditions. The sensor technology can be used in a great variety of applications including air conditioning and sensing of reactive gas species in vacuum lines and abatement systems. (paper)

  12. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    Energy Technology Data Exchange (ETDEWEB)

    Sayavur Bakhtiyarov

    2008-02-29

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define

  13. Critic to the science and technology activities in the CTPETRO, Brazil, natural gas sector (National Plan of Science end Technology of the Petroleum and Natural Gas Sector); Critica as atividades de C and T na area de gas natural do CTPETRO (Plano Nacional de Ciencia e Tecnologia do Setor de Petroleo e Gas Natural)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Edmilson Moutinho dos; Faga, Murilo Tadeu Wenerck [Sao Paulo Univ., SP (Brazil). Inst. de Eletrotecnica e Energia. Grupo de Energia]. E-mails: edsantos@iee.usp.br; Poulallion, Paul; Correa Neto, Vicente [SINDE - Sinergia e Desenvolvimento S/C Ltda., Rio de Janeiro, RJ (Brazil)

    2002-07-01

    This paper performs an evaluation of the science and technology activities for the natural gas area at the CTPETRO - National Plan of Science and Technology for the Petroleum and Natural Gas Sector. The paper discuss the insufficiency of the present technological efforts in Brazil, aiming the increasing of the natural gas participation in the brazilian energy matrix. The work shows the great distance among those efforts and the national policy for the natural gas. Last, the paper discusses the necessity of a review in the science and technology activities in the gas sector, and makes some considerations on the great potential in the gas industry for employment generation, for new business and the increasing in the national competitiveness.

  14. Trapping technology for gaseous fission products from voloxidation process

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jin Myeong; Park, J. J.; Park, G. I.; Jung, I. H.; Lee, H. H.; Kim, G. H.; Yang, M. S

    2005-05-15

    The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, {sup 14}C, Kr, Xe, I and {sup 3}H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gas trapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and {sup 14}C trapping unit. In case of I trapping unit, AgX is proposed. For Kr and Xe, adsorption on solid is proposed. SDBC (Styrene Divinyl Benzene Copolymer) is also proposed as a conversion media to HTO for {sup 3}H. This report will be used as a useful means for analyzing the known trapping technologies and help selecting the appropriate trapping methods for trapping volatile and semi-volatile fission products, long-lived fission products, and major heat sources generated from a voloxidation process. It can also be used to design an off-gas treatment system.

  15. Applications of the gas chromatography in the nuclear science and technology

    International Nuclear Information System (INIS)

    Gasco Sanchez, L.

    1972-01-01

    This paper is a review on the applications of the gas chromatography in the nuclear science and technology published up to December 1971. Its contents has been classified under the following heads; I) Radiogaschromatography, II) Isotope separation, III) Preparation of labelled molecules, IV) Nuclear fuel cycle, V) Nuclear reactor technology, VI) Irradiation chemistry, VIl) Separation of me tal compounds in gas phase, VIII) Applications of the gas chromatography carried out at the Junta de Energia Nuclear, Spain. Arapter VIII only includes the investigations carried out from January 1969 to December 1971. Previous investigations in this field has been published elsewhere. (Author)

  16. Preliminary exploitation of industrial facility for flue gas treatment

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Zimek, Z.; Iller, E.; Tyminski, B.; Licki, J.

    2001-01-01

    Full text: High emission of SO 2 and NO x in the process of fossil fuel combustion creates a major world environmental problem. Poland which uses for energy production mainly pit and brown coal produces these pollutants as well. The certain amount of SO 2 and slightly less NO x pollutants is introduced into the atmosphere. 1/2 of SO 2 and 1/3 NO x pollution is contributed by heat and electricity generating boilers. The biggest sources of pollution are located in south west side of Poland and are connected with industrial centers but over 45% of the total 802 and 69% of NO x pollutants distributed over polish territory come from external sources. The laboratory facility for flue gas treatment radiation technology was organized in Institute of Nuclear Chemistry and Technology at Warsaw at the end of 80s. Soon after the pilot plant for flue gas treatment with electron beam has been installed at Power Plant Kaweczyn near Warsaw. The flow capacity trough those installations was respectively 400 and 20000 Nm /h. Three new elements have been introduced to the construction of the radiation chamber in Polish pilot installation. Those are: cascade double stage irradiation, longitudinal irradiation, (beam scanned along the chamber axis) and the air blow under the chamber window with the purpose to create air curtain separating the window from the flue gases causing corrosion. Three different system for filtration aid has been constructed and tested: bag filter, gravel bead filter and electrostatic precipitator. The pilot plant installation was used to establish the optimal parameters of industrial facility: optimizing of the process parameters leading to reduction of energy with high efficiency of SO 2 and NO x removal; selecting and testing filter devices and filtration process; developing of the monitoring and control systems at industrial plant for flue gas cleaning, preparation of the design for industrial scale facility. The positive results of the tests performed on

  17. Enrichment technology. Dependable vendor of gas centrifuges; Enrichment Technology. Zuverlaessiger Lieferant von Gaszentrifugen

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2011-10-15

    Enrichment Technology is an innovative, high-tech company that develops, manufactures and installs gas centrifuges for enriching uranium. In addition, Enrichment Technology designs enrichment plants that use gas centrifuge technology. This technology offers the most efficient and cost-effective method for enriching uranium yet: high-performance, safe technology that dominates the market with a global share of 45 percent. A determining factor in Enrichment Technology's success is its mission: supplying its customers with safe, reliable technology. Production of the centrifuges requires versatile know-how and collaboration between different departments as well as interdisciplinary teams at the various sites. More than 2000 operators at 8 sites in 5 countries contribute their individual knowledge and personal skills in order to produce this exceptional technology. The head office is in Beaconsfield near London and the operational headquarters are in Almelo in the Netherlands. There are other sites in Germany (Juelich und Gronau), Great Britain (Capenhurst) as well as project sites in the USA and France. Capenhurst is where experienced engineers design new enrichment plants and organise their construction. Centrifuge components are manufactured in Almelo and Juelich, while the pipework needed to connect up the centrifuges is produced at the site in Gronau. In Juelich, highly qualified scientists in interdisciplinary teams are continuously researching ways of improving the current centrifuges. Communication between specialists in the fields of chemistry, physics and engineering forms the basis for the company's success and the key to extending this leading position in the global enrichment market. (orig.)

  18. Prospects for natural gas in Europe. Market potential, political intervention and technological options

    International Nuclear Information System (INIS)

    Kabelitz, K.R.

    1997-01-01

    The potential market demand, the emerging fundamental political intervention in the European gas and electricity markets and the technological options available will give the gas industry in Europe a different appearance at the beginning of the 21. century. One of the key questions is: will the political intervention and technological options and innovations assist and promote the realisation of market potential? At the moment, it cannot be stated definitely whether the currently available technological options will allow the significant cost reductions hoped for in the entire gas chain to become reality in good time. Under these circumstances, a major mismatch would emerge between the market potential predicted for natural gas in Europe and the actual market development. (R.P.)

  19. Fifth DOE symposium on enhanced oil and gas recovery and improved drilling technology. Volume 3. Gas and drilling

    Energy Technology Data Exchange (ETDEWEB)

    Linville, B. [ed.

    1979-01-01

    Volume 3 contains papers from the sessions on natural gas supporting research, western gas sands project, drilling technology, and environmental effects. Individuals were processed for inclusion in the Energy Data Base.

  20. Oxygen enrichment incineration

    International Nuclear Information System (INIS)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, Joon Hyung

    2000-10-01

    Oxygen enriched combustion technology has recently been used in waste incineration. To apply the oxygen enrichment on alpha-bearing waste incineration, which is being developed, a state-of-an-art review has been performed. The use of oxygen or oxygen-enriched air instead of air in incineration would result in increase of combustion efficiency and capacity, and reduction of off-gas product. Especially, the off-gas could be reduced below a quarter, which might reduce off-gas treatment facilities, and also increase an efficiency of off-gas treatment. However, the use of oxygen might also lead to local overheating and high nitrogen oxides (NOx) formation. To overcome these problems, an application of low NOx oxy-fuel burner and recycling of a part of off-gas to combustion chamber have been suggested

  1. Oxygen enrichment incineration

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, Joon Hyung

    2000-10-01

    Oxygen enriched combustion technology has recently been used in waste incineration. To apply the oxygen enrichment on alpha-bearing waste incineration, which is being developed, a state-of-an-art review has been performed. The use of oxygen or oxygen-enriched air instead of air in incineration would result in increase of combustion efficiency and capacity, and reduction of off-gas product. Especially, the off-gas could be reduced below a quarter, which might reduce off-gas treatment facilities, and also increase an efficiency of off-gas treatment. However, the use of oxygen might also lead to local overheating and high nitrogen oxides (NOx) formation. To overcome these problems, an application of low NOx oxy-fuel burner and recycling of a part of off-gas to combustion chamber have been suggested.

  2. Secondary Waste Considerations for Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center FY-2001 Status Report

    International Nuclear Information System (INIS)

    Herbst, A.K.; Kirkham, R.J.; Losinski, S.J.

    2002-01-01

    The Idaho Nuclear Technology and Engineering Center (INTEC) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes from the melter off-gas clean up systems. Projected secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates

  3. Secondary Waste Considerations for Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center FY-2001 Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Herbst, A.K.; Kirkham, R.J.; Losinski, S.J.

    2002-09-26

    The Idaho Nuclear Technology and Engineering Center (INTEC) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes from the melter off-gas clean up systems. Projected secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  4. Technologic spin-off from CNEA's activities; Tecnologias derivadas de las actividades de la CNEA

    Energy Technology Data Exchange (ETDEWEB)

    Belinco, Cesar G [Comision Nacional de Energia Atomica, General San Martin (Argentina). Centro Atomico Constituyentes

    2001-07-01

    An analysis is made of the spin-off of technology from the nuclear activities in Argentina. Several examples are mentioned in fields such as material sciences, non-destructive testing, forensic research, space activities, instrumentation as well as in environmental studies.

  5. Numerical simulation and field test study of desulfurization wastewater evaporation treatment through flue gas.

    Science.gov (United States)

    Deng, Jia-Jia; Pan, Liang-Ming; Chen, De-Qi; Dong, Yu-Quan; Wang, Cheng-Mu; Liu, Hang; Kang, Mei-Qiang

    2014-01-01

    Aimed at cost saving and pollution reduction, a novel desulfurization wastewater evaporation treatment system (DWETS) for handling wet flue gas desulfurization (WFGD) wastewater of a coal-fired power plant was studied. The system's advantages include simple process, and less investment and space. The feasibility of this system has been proven and the appropriate position and number of nozzles, the spray droplet size and flue gas temperature limitation have been obtained by computational fluid dynamics (CFD) simulation. The simulation results show that a longer duct, smaller diameter and higher flue gas temperature could help to increase the evaporation rate. The optimal DWETS design of Shangdu plant is 100 μm droplet sprayed by two nozzles located at the long duct when the flue gas temperature is 130 °C. Field tests were carried out based on the simulation results. The effects of running DWETS on the downstream devices have been studied. The results show that DWETS has a positive impact on ash removal efficiency and does not have any negative impact on the electrostatic precipitator (ESP), flue gas heat exchanger and WFGD. The pH values of the slurry of WFGD slightly increase when the DWETS is running. The simulation and field test of the DWETS show that it is a feasible future technology for desulfurization wastewater treatment.

  6. Off-gas chemistry study of melter feed by Springborn Laboratories

    International Nuclear Information System (INIS)

    Crow, K.R.

    1985-01-01

    The purpose of the off-gas chemistry study of melter feed samples was to support and help substantiate glass melter thermochemistry models developed for the DWPF. Both sludge-only and sludge-precipitate feed samples were analyzed. Each slurry sample was pyrolyzed at temperatures from 150 to 1000 0 C in air and inert atmospheres, and the head space products were analyzed by chromatographic and mass spectrometric methods. Thermogravimetric, differential scanning calorimetric and Fourier transform infrared analyses were also performed on each sample. There were no unusually high exothermic reactions that would be cause for concern in the DWPF melter. Results for two types of sludge-precipitate feed were compared. One type contained simulated precipitate hydrolysis aqueous (PHA) product as fed to the SCM-2 melter. The second type contained PHA from the lab-scale acid hydrolysis reactor in 677-T. A major difference between the two types was a small, but distinct, presence of higher aromatics in gas from feed with reactor-produced PHA. This feed also evolved more CO and CO 2 than feed with simulated PHA at high pyrolytic temperatures (>750 0 C). Recent analyses have identified the higher boiling aromatics in reactor-produced PHA as primarily diphenylamine and p-terphenyl. These compounds will be included in future PHA simulations that are fed to research melters. Under an inert atmosphere, benzene and phenol were the two most abundant organics evolved during pyrolysis of sludge-precipitate feed

  7. Calculation and Designing of Up-to-Date Gas-Flame Plants for Metal Heating and Heat Treatment

    Directory of Open Access Journals (Sweden)

    V. I. Тimoshpolsky

    2008-01-01

    Full Text Available An analysis of development trends in the CIS machine-building industry and current status of the heating and heat treatment furnaces of main machine-building enterprises of the Republic of Belarus as of the 1st quarter of 2008 is given in the paper.The paper presents the most efficient engineering solutions from technological and economic point of view that concern calculation and designing of up-to-date gas-flame plants which are to be applied for modernization of the current heating and heat treatment furnaces of the machine-building enterprises in the Republic of Belarus.A thermo-technical calculation of main indices of the up-to-date gas-flame plant has been carried out in the paper.

  8. Analysis of Sustainable Technologies for Acid Gas Removal

    OpenAIRE

    Dal Pozzo, Alessandro

    2017-01-01

    Acid gases, such as sulphur dioxide and hydrogen halides and – in a broad sense – carbon dioxide, are typical pollutants generated by combustion processes. Their removal by means of solid sorbents represent an efficient and cost-effective approach in dry acid gas treatment systems for waste incineration flue gas, while for CO2 capture the process is exploratively studied as a promising alternative to amine scrubbing. The present study addressed both aspects. In waste incineration flue gas ...

  9. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Pena, Federico [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    1997-10-01

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  10. The comparison of greenhouse gas emissions in sewage treatment plants with different treatment processes.

    Science.gov (United States)

    Masuda, Shuhei; Sano, Itsumi; Hojo, Toshimasa; Li, Yu-You; Nishimura, Osamu

    2018-02-01

    Greenhouse gas emissions from different sewage treatment plants: oxidation ditch process, double-circulated anoxic-oxic process and anoxic-oxic process were evaluated based on the survey. The methane and nitrous oxide characteristics were discussed based on the gaseous and dissolved gas profiles. As a result, it was found that methane was produced in the sewer pipes and the primary sedimentation tank. Additionally, a ventilation system would promote the gasification of dissolved methane in the first treatment units. Nitrous oxide was produced and emitted in oxic tanks with nitrite accumulation inside the sewage treatment plant. A certain amount of nitrous oxide was also discharged as dissolved gas through the effluent water. If the amount of dissolved nitrous oxide discharge is not included, 7-14% of total nitrous oxide emission would be overlooked. Based on the greenhouse gas calculation, electrical consumption and the N 2 O emission from incineration process were major sources in all the plants. For greenhouse gas reduction, oxidation ditch process has an advantage over the other advanced systems due to lower energy consumption, sludge production, and nitrogen removal without gas stripping. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Gas Sensors Based on Molecular Imprinting Technology.

    Science.gov (United States)

    Zhang, Yumin; Zhang, Jin; Liu, Qingju

    2017-07-04

    Molecular imprinting technology (MIT); often described as a method of designing a material to remember a target molecular structure (template); is a technique for the creation of molecularly imprinted polymers (MIPs) with custom-made binding sites complementary to the target molecules in shape; size and functional groups. MIT has been successfully applied to analyze; separate and detect macromolecular organic compounds. Furthermore; it has been increasingly applied in assays of biological macromolecules. Owing to its unique features of structure specificity; predictability; recognition and universal application; there has been exploration of the possible application of MIPs in the field of highly selective gas sensors. In this present study; we outline the recent advances in gas sensors based on MIT; classify and introduce the existing molecularly imprinted gas sensors; summarize their advantages and disadvantages; and analyze further research directions.

  12. Enhancement of energy performance in a boil-off gas re-liquefaction system of LNG carriers using ejectors

    International Nuclear Information System (INIS)

    Tan, Hongbo; Zhao, Qingxuan; Sun, Nannan; Li, Yanzhong

    2016-01-01

    Highlights: • An ejector-enhanced LNG boil-off gas (BOG) re-liquefaction system is proposed. • The new system has an improvement of 28% in COP over the existing system. • The specific energy consumption of the new system is reduced to 0.59 kW h/kg(BOG). • The power consumption of 754.1 kW is saved in the case study. - Abstract: An ejector-enhanced Liquefied Natural Gas (LNG) boil-off gas (BOG) re-liquefaction system is proposed to improve the energy efficiency of the existing system. In the new system, two ejectors are respectively used to reduce the energy loss in the expansion of the pressurized BOG and inject a part of fuel BOG into the compression system, and a recuperator is employed to recover the cold energy of the BOG exited from LNG tank. The performance improvement of the proposed system is analysed on the basis of the simulation in Aspen HYSYS. In the case of the re-liquefaction capacity of 4557.6 kg/h, the coefficient of performance (COP) and exergy efficiency can be increased by 28%, and the specific energy consumption (SEC) reduced from 0.756 to 0.59 kW h/kg(BOG) compared to the conventional BOG re-liquefaction system. Correspondingly, the power consumption of 754.1 kW is saved. This means that applying ejectors can effectively improve the energy efficiency of the existing BOG re-liquefaction system for LNG carriers.

  13. Quantifying women's stated benefit-risk trade-off preferences for IBS treatment outcomes.

    Science.gov (United States)

    Johnson, F Reed; Hauber, A Brett; Ozdemir, Semra; Lynd, Larry

    2010-01-01

    The Food and Drug Administration, currently, is exploring quantitative benefit-risk methods to support regulatory decision-making. A scientifically valid method for assessing patients' benefit-risk trade-off preferences is needed to compare risks and benefits in a common metric. The study aims to quantify the maximum acceptable risk (MAR) of treatment-related adverse events (AEs) that women with diarrhea-predominant irritable bowel syndrome (IBS) are willing to accept in exchange for symptom relief. A stated-choice survey was used to elicit trade-off preferences among constructed treatment profiles, each defined by symptom severity and treatment-related AEs. Symptom attributes included frequency of abdominal pain and discomfort, frequency of diarrhea, and frequency of urgency. AE attributes included frequency of mild-to-moderate constipation and the risk of four possible serious AEs. A Web-enabled survey was administered to 589 female US residents at least 18 years of age with a self-reported diagnosis of diarrhea-predominant IBS. Preference weights and MAR were estimated using mixed-logit methods. SUBJECTS were willing to accept higher risks of serious AEs in return for treatments offering better symptom control. For an improvement from the lowest to the highest of four benefit levels, subjects were willing to tolerate a 2.65% increase in impacted-bowel risk, but only a 1.34% increase in perforated-bowel risk. Variation in MARs across AE types is consistent with the relative seriousness of the AEs. Stated-preference methods offer a scientifically valid approach to quantifying benefit-risk trade-off preferences that can be used to inform regulatory decision-making.

  14. Evaluating the income and employment impacts of gas cooling technologies

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, P.J. [Oak Ridge National Lab., TN (United States); Laitner, S.

    1995-03-01

    The purpose of this study is to estimate the potential employment and income benefits of the emerging market for gas cooling products. The emphasis here is on exports because that is the major opportunity for the U.S. heating, ventilating, and air-conditioning (HVAC) industry. But domestic markets are also important and considered here because without a significant domestic market, it is unlikely that the plant investments, jobs, and income associated with gas cooling exports would be retained within the United States. The prospects for significant gas cooling exports appear promising for a variety of reasons. There is an expanding need for cooling in the developing world, natural gas is widely available, electric infrastructures are over-stressed in many areas, and the cost of building new gas infrastructure is modest compared to the cost of new electric infrastructure. Global gas cooling competition is currently limited, with Japanese and U.S. companies, and their foreign business partners, the only product sources. U.S. manufacturers of HVAC products are well positioned to compete globally, and are already one of the faster growing goods-exporting sectors of the U.S. economy. Net HVAC exports grew by over 800 percent from 1987 to 1992 and currently exceed $2.6 billion annually (ARI 1994). Net gas cooling job and income creation are estimated using an economic input-output model to compare a reference case to a gas cooling scenario. The reference case reflects current policies, practices, and trends with respect to conventional electric cooling technologies. The gas cooling scenario examines the impact of accelerated use of natural gas cooling technologies here and abroad.

  15. The role of technology in unlocking the possibilities of shale gas

    CSIR Research Space (South Africa)

    Heydenrich, PR

    2017-10-01

    Full Text Available expelled from the Shale during burial and maturation and so it can be targeted without regard to structural closure. In some cases, a topseal (tight rock) is required Conventional System: Requires trap, or closure Unconventional System: Does... 2. Production of Shale Gas requires: ● Drilling technology capable of horizontal/geosteered well targeting (up to 3000m horizontal length is common) ● Completions technology to optimise the extraction of gas from the formation: ● Temporary...

  16. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2003-04-30

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. Networking opportunities that occur with a Houston Headquarters (HQ) location are increasing name awareness. Focused efforts by Executive Director Don Duttlinger to interact with large independents, national service companies and some majors are continuing to supplement the support base of the medium to smaller industry participants around the country. PTTC is now involved in many of the technology-related activities that occur in high oil and natural gas activity areas. Access to technology remains the driving force for those who do not have in-house research and development capabilities and look to the PTTC to provide services and options for increased efficiency.

  17. The development of radwaste in cineration technology (1)

    International Nuclear Information System (INIS)

    Park, Hun Hwee; Kim, Joon Hyung; Seo, Yong Chil; Kim, In Tae; Ahn, Byung Gil; Yang, Hee Chul; Won, Dong Yeon; Lee, Jae Chun; Kim, Chan Joong

    1988-04-01

    In order to establish a schedule to develope the incineration technology with feasibility, we summarized the recently published reports of the state of the arts and feasibility studies on it. After comparison study between incineration and compaction, we suggested that the combustible wastes should be incinerated and the incombustible wastes should be compacted by a supercompactor. The status of utilization of incineration for industrial and municipal wastes in Korea was surveyed and the applicability of these techniques to incineration of radwastes were evaluated and resulted to be good. Finally, a long-term plan to utilize the incineration technology up to the commercialization was established on the basis of the above data and feasibility. An experimental incineration process with a capacity of 5 kg plastic wastes per hour was designed by the research team and constructed by several machinery industries of the country to study the incineration characteristics and test the performance of each filter unit in the off-gas system. This process consists of waste pretreatment system, incinerator, off-gas treatment system, and measurement and control system. This process was constructed and performed test-operation with feeding some shredded wastes. The actual experiments will be done in 1988. Under the final goal of developing a SiC filter tube which could be used in the incineration process, a SiC sample with a proper binder was fabricated. The attempts to fabricate a bigger tube and to find out the best fabricating condition will be continued. (Author)

  18. Commercial sector gas cooling technology frontier and market share analysis

    International Nuclear Information System (INIS)

    Pine, G.D.; Mac Donald, J.M.; McLain, H.A.

    1990-01-01

    This paper describes a method, developed for the Gas Research Institute of the United States, that can assist planning for commercial sector natural gas cooling systems R and D. These systems are higher in first cost than conventional electric chillers. Yet, engine-driven chiller designs exist which are currently competitive in U.S. markets typified by high electricity or demand charges. Section II describes a scenario analysis approach used to develop and test the method. Section III defines the technology frontier, a conceptual tool for identifying new designs with sales potential. Section IV describes a discrete choice method for predicting market shares of technologies with sales potential. Section V shows how the method predicts operating parameter, cost, and/or performance goals for technologies without current sales potential (or for enhancing a frontier technology's sales potential). Section VI concludes with an illustrative example for the Chicago office building retrofit market

  19. Impacts of imports, government policy and technology on future natural gas supply

    International Nuclear Information System (INIS)

    Allison, E.

    2009-01-01

    This presentation discussed the impacts of imports, government policy and technology on future natural gas supply. Specifically, it discussed projections of natural gas supply and demand; the potential impact of imports on United States natural gas supply; the potential impacts of government policy on natural gas supply and demand; and the impact of technological innovations on natural gas supply such as coalbed methane and methane hydrate. Specific government policies that were examined included the American Recovery and Reinvestment Act of 2009; the American Clean Energy and Security Act of 2009; and the Clean Energy Jobs and American Power Act of 2009. It was concluded that the United States demand for natural gas will expand and that the impact of pending clean energy legislation is unclear. In addition, each potential future resource will face constraints and new resources may come on line in the next 20 years. figs.

  20. Quantification of greenhouse gas (GHG) emissions from wastewater treatment plants using a ground-based remote sensing approach

    Science.gov (United States)

    Delre, Antonio; Mønster, Jacob; Scheutz, Charlotte

    2016-04-01

    The direct release of nitrous oxide (N2O) and methane (CH4) from wastewater treatment plants (WWTP) is important because it contributes to the global greenhouse gases (GHGs) release and strongly effects the WWTP carbon footprint. Biological nitrogen removal technologies could increase the direct emission of N2O (IPCC, 2006), while CH4 losses are of environmental, economic and safety concern. Currently, reporting of N2O and CH4 emissions from WWTPs are performed mainly using methods suggested by IPCC which are not site specific (IPCC, 2006). The dynamic tracer dispersion method (TDM), a ground based remote sensing approach implemented at DTU Environment, was demonstrated to be a novel and successful tool for full-scale CH4 and N2O quantification from WWTPs. The method combines a controlled release of tracer gas from the facility with concentration measurements downwind of the plant (Mønster et al., 2014; Yoshida et al., 2014). TDM in general is based on the assumption that a tracer gas released at an emission source, in this case a WWTP, disperses into the atmosphere in the same way as the GHG emitted from process units. Since the ratio of their concentrations remains constant along their atmospheric dispersion, the GHG emission rate can be calculated using the following expression when the tracer gas release rate is known: EGHG=Qtr*(CGHG/Ctr)*(MWGHG/MWtr) EGHG is the GHG emission in mass per time, Qtr is the tracer release in mass per time, CGHG and Ctr are the concentrations measured downwind in parts per billion subtracted of their background values and integrated over the whole plume, and MWGHG and MWtr are the molar weights of GHG and tracer gas respectively (Mønster et al. 2014). In this study, acetylene (C2H2) was used as tracer. Downwind plume concentrations were measured driving along transects with two cavity ring down spectrometers (Yoshida et al., 2014). TDM was successfully applied in different seasons at several Scandinavian WWTPs characterized by

  1. LCA and economic evaluation of landfill leachate and gas technologies.

    Science.gov (United States)

    Damgaard, Anders; Manfredi, Simone; Merrild, Hanna; Stensøe, Steen; Christensen, Thomas H

    2011-07-01

    Landfills receiving a mix of waste, including organics, have developed dramatically over the last 3-4 decades; from open dumps to engineered facilities with extensive controls on leachate and gas. The conventional municipal landfill will in most climates produce a highly contaminated leachate and a significant amount of landfill gas. Leachate controls may include bottom liners and leachate collection systems as well as leachate treatment prior to discharge to surface water. Gas controls may include oxidizing top covers, gas collection systems with flares or gas utilization systems for production of electricity and heat. The importance of leachate and gas control measures in reducing the overall environmental impact from a conventional landfill was assessed by life-cycle-assessment (LCA). The direct cost for the measures were also estimated providing a basis for assessing which measures are the most cost-effective in reducing the impact from a conventional landfill. This was done by modeling landfills ranging from a simple open dump to highly engineered conventional landfills with energy recovery in form of heat or electricity. The modeling was done in the waste LCA model EASEWASTE. The results showed drastic improvements for most impact categories. Global warming went from an impact of 0.1 person equivalent (PE) for the dump to -0.05 PE for the best design. Similar improvements were found for photochemical ozone formation (0.02 PE to 0.002 PE) and stratospheric ozone formation (0.04 PE to 0.001 PE). For the toxic and spoiled groundwater impact categories the trend is not as clear. The reason for this was that the load to the environment shifted as more technologies were used. For the dump landfill the main impacts were impacts for spoiled groundwater due to lack of leachate collection, 2.3 PE down to 0.4 PE when leachate is collected. However, at the same time, leachate collection causes a slight increase in eco-toxicity and human toxicity via water (0.007 E to 0

  2. The recovery of waste and off-gas in Large Combustion Plants subject to IPPC National Permit in Italy.

    Science.gov (United States)

    Di Marco, Giuseppe; Manuzzi, Raffaella

    2018-03-01

    The recovery of off-gas, waste, and biomass in Large Combustion Plants for energy production gives the opportunity to recycle waste and by-products and to recover materials produced in agricultural and industrial activities. The paper illustrates the Italian situation regarding the production of energy from off-gas, biomass, and waste in Large Combustion Plants subject to Integrated Pollution Prevention and Control (IPPC) National Permit. Moreover, it focuses on the 4 Italian Large Combustion Plants producing energy from biomass and waste. For these ones it illustrates the specific issues related to and provides a description of the solutions adopted in the 4 Italian plants. Given that air emission performance is the most relevant aspect of this kind of plants, the paper specifically focuses and reports results about this subject. In particular, in Italy among 113 LCPs subject to IPPC National Permit we have found that 4 plants use as fuel waste (i.e. solid or liquid biomasses and Solid Recovered Fuels), or a mixture of waste and traditional fuels (co-combustion of Solid Recovered Fuels and coal), and that 11 plants use as fuel off-gases listed in Annex X (i.e. Refinery Fuel Gas, Syngas, and gases produced in iron and steel industries). Moreover, there are 2 IPPC chemical plants that recovery energy from different off-gases not listed in Annex X. Regarding the 4 LCPs that produce energy from waste combustion or co-combustion, we find that they take into account all the specific issues related to this kind of plants (i.e. detailed waste characterization, waste acceptance procedures, waste handling and storage, waste pretreatment and emissions to air), and adopt solutions that are best available techniques to prevent pollution. Moreover for one of these plants, the only one for which we have a significant set of monitoring data because it obtained the IPPC National Permit in 2008, we find that energy efficiency and air emissions of the principal pollutants are in

  3. Fiscal 2000 survey report. Survey of long-term energy technology strategy and the like (Survey of natural gas technology trend); 2000 nendo choki energy gijutsu senryaku nadoni kansuru chosa hokokusho. Choki energy gijutsu senryaku chosa (tennen gas gijutsu doko chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In search of new technical tasks involving the supply, transportation, and utilization of natural gas, a survey is conducted of the trend of natural gas supply and demand, trend of development of related technologies, and their impact on the market. After natural gas matters are outlined and definition and classification are established, investigations are conducted into natural gas production and the trend of new natural gas consuming countries supposedly to affect the natural gas supply and demand situation. Taken up as relevant technologies are cogeneration, natural gas powered automobiles, fuel cells, GTL (gas to liquid) technology, and micro gas turbines. These technologies are examined from the viewpoints of environmentally-friendliness and energy conservation feature, and then tasks to discharge are proposed in the fields of technology development, operation, and fuel. For natural gas powered automobiles, vehicular performance improvement and the conformability and standardization of high-pressure parts and components are taken up in the field of technology development, and the introduction and augmentation of quick fillers for natural gas and increase in the number of natural gas supply stations are taken up in the field of operation. Concerning fuel cells, in the field of fuels to be fed to the same, technologies of hydrogen storage and of refining and reforming of oil based fuels are taken up. (NEDO)

  4. Gas treatment processes for keeping the environment of nuclear plants free from gas-borne activity

    International Nuclear Information System (INIS)

    Schiller, H.

    1977-01-01

    The separation processes in gas treatment steps for the decontamination of circuit or offgas streams are described and their practicability is evaluated. Examples of the effectiveness of gas separation plants for keeping the environment within and without nuclear plants free from harmful gas-borne activity are presented. (orig.) [de

  5. An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale

    Energy Technology Data Exchange (ETDEWEB)

    Matthew Bruff; Ned Godshall; Karen Evans

    2011-04-30

    This Final Scientific/ Technical Report submitted with respect to Project DE-FE0000833 titled 'An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale' in support of final reporting requirements. This final report contains a compilation of previous reports with the most current data in order to produce one final complete document. The goal of this research was to provide an integrated approach aimed at addressing the increasing water resource challenges between natural gas production and other water stakeholders in shale gas basins. The objective was to demonstrate that the AltelaRain{reg_sign} technology could be successfully deployed in the Marcellus Shale Basin to treat frac flow-back water. That objective has been successfully met.

  6. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM-PRELIMINARY REPORT

    Energy Technology Data Exchange (ETDEWEB)

    Zamecnik, J.; Choi, A.

    2010-08-18

    chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly

  7. H_2 production by the steam reforming of excess boil off gas on LNG vessels

    International Nuclear Information System (INIS)

    Fernández, Ignacio Arias; Gómez, Manuel Romero; Gómez, Javier Romero; López-González, Luis M.

    2017-01-01

    Highlights: • BOG excess in LNG vessels is burned in the GCU without energy use. • The gas management plants need to be improved to increase efficiency. • BOG excess in LNG vessels is used for H_2 production by steam reforming. • The availability of different fuels increases the versatility of the ship. - Abstract: The gas management system onboard LNG (Liquid Natural Gas) vessels is crucial, since the exploitation of the BOG (Boil Off Gas) produced is of utmost importance for the overall efficiency of the plant. At present, LNG ships with no reliquefaction plant consume the BOG generated in the engines, and the excess is burned in the GCU (Gas Combustion Unit) without any energy use. The need to improve the gas management system, therefore, is evident. This paper proposes hydrogen production through a steam reforming plant, using the excess BOG as raw material and thus avoiding it being burned in the GCU. To test the feasibility of integrating the plant, an actual study of the gas management process on an LNG vessel with 4SDF (4 Stroke Dual Fuel) propulsion and with no reliquefaction plant was conducted, along with a thermodynamic simulation of the reforming plant. With the proposed gas management system, the vessel disposes of different fuels, including H_2, a clean fuel with zero ozone-depleting emissions. The availability of H_2 on board in areas with strict anti-pollution regulations, such as ECAs (Emission Control Area), means that the vessel may be navigated without using fossil fuels which generate CO_2 and SO_X emissions. Moreover, while at port, Cold Ironing is avoided, which entails high costs. Thus it is demonstrated that the installation of a reforming plant is both energetically viable and provides greater versatility to the ship.

  8. Improved of Natural Gas Storage with Adsorbed Natural Gas (ANG) Technology Using Activated Carbon from Plastic Waste Polyethylene Terepthalate

    Science.gov (United States)

    Yuliusman; Nasruddin; Sanal, A.; Bernama, A.; Haris, F.; Hardhi, M.

    2017-07-01

    Indonesia imports high amount of Fuel Oil. Although Indonesia has abundant amount of natural gas reserve, the obstacle lies within the process of natural gas storage itself. In order to create a safe repository, the ANG (Adsorbed Natural Gas) technology is planned. ANG technology in itself has been researched much to manufacture PET-based activated carbon for natural gas storage, but ANG still has several drawbacks. This study begins with making preparations for the equipment and materials that will be used, by characterizing the natural gas, measuring the empty volume, and degassing. The next step will be to examine the adsorption process. The maximum storage capacity obtained in this study for a temperature of 27°C and pressure of 35 bar is 0.0586 kg/kg, while for the desorption process, a maximum value for desorption efficiency was obtained on 35°C temperature with a value of 73.39%.

  9. RedeGasEnergia and associated technologies with industrial mark